1203_BurkeCounty_GWMR_DIN28579_20161213

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

BURKE COUNTY
JOHNS RIVER WASTE MANAGEMENT FACILITY
C&D-OVER-MSW LANDFILL
PERMIT NO. 12-03

SECOND SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2016

MARCH 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1701.12

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Burke County – Johns River C&D Over MSW Landfill, Permit No. 12-03 March 2017
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Second Semiannual Water Quality Monitoring Report of 2016
Johns River Waste Management Facility – Permit No. 12-03
C&D-over-MSW Landfill
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
1.4 Groundwater Monitoring History .............................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................3 
2.1 Groundwater Monitoring Program ...........................................................................................3 
2.2 Surface Water Monitoring Program .........................................................................................6 
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016 ............................................6 
3.1 Field Work ................................................................................................................................6 
3.2 Laboratory Analysis and JOYCE Quality Control ...................................................................7 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................8 
4.1 Analytical Results for Inorganic Constituents ..........................................................................8 
4.2 Analytical Results for Organic Constituents ............................................................................8 
4.3 Statistical Analyses ...................................................................................................................9 
4.3.1 Statistical Methods and Background .................................................................................. 9 
4.3.2 Statistical Analyses of Inorganic Constituents ................................................................... 9 
4.4 Analytical Results for Surface Water .....................................................................................10 
5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) ..............10 
5.1 MNA Parameters and Biodegradation Screening Matrix .......................................................10 
5.2 Biochlor Modeling and Mass-Balance Assessment ...............................................................11 
5.3 Trend Analysis and Plume Stability .......................................................................................11 
6.0 HYDROGEOLOGICAL CONDITIONS ......................................................................11 
7.0 CONCLUSIONS ..............................................................................................................13 
8.0 REFERENCES .................................................................................................................13 
9.0 ACRONYMS ....................................................................................................................15 

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TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters (December 2016) Table 3 Quantified Detections of Groundwater Constituents (December 2016)
Table 4 Exceedances of Groundwater Standards (December 2016) Table 5 Statistical Background Analyses
Table 6 MNA Parameters (December 2016)
Table 7 Biodegradation Screening Matrix Table 8 Hydraulic Gradients and Groundwater Flow Velocities

Charts:
Chart 1 Benzene Concentrations vs. Time
Chart 2 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3 1,1-Dichloroethane Concentrations vs. Time
Chart 4 1,2-Dichloroethane Concentrations vs. Time
Chart 5 Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6 Trichloroethylene (TCE) Concentrations vs. Time
Chart 7 Vinyl Chloride Concentrations vs. Time
Chart 8 Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10 beta-BHC Concentrations vs. Time
Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Potentiometric Surface Map

Appendices:
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters
Appendix I Biochlor Modeling Input & Output

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1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The Johns River flows into the Catawba River near the southwest
corner of the landfill property.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

The unlined waste disposal unit consists of 28 acres in the southwest corner of the landfill
property. The municipal solid waste (MSW) landfill began operation in April 1988, but was
closed to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation governing MSW
Landfills units that were not designed with a base liner and leachate collection system. Burke
County has operated a permitted Construction and Demolition (C&D) disposal area on top of the
closed portions of the MSW landfill since 1998. A MSW transfer facility is located in the
eastern half of the property. In 2014, Phase 1A of the C&D expansion was constructed
northeast of the C&D over MSW landfill. Results of groundwater monitoring for Phase 1A will
be presented in a separate report. A site plan showing all the pertinent features of the facility is
provided in Drawing 1.

1.2 Site Geology
The Johns River Waste Management Facility is in close proximity to the Brevard Shear Zone,
and is underlain by highly metamorphosed rocks including gneiss, schist, as well as calc-silicate
rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is biotite-
muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The structures
within limited outcrops indicate that these rocks are complexly-folded, with attitudes that vary
from vertical to horizontal in most outcrops. The site regolith is typical of the inner piedmont
and consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick
and varies in thickness with topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

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1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF has been prepared in
accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC
13B §.1632 (Groundwater Sampling & Analysis Requirements) §.1633 (Detection Monitoring
Program), and §.1634 (Assessment Monitoring Program). The facility has operated under these
programs under the auspices the North Carolina Department of Environment and Natural
Resources (NCDENR), which is now the Department of Environmental Quality (NCDEQ). To
avoid confusion, NCDEQ will be used in reference to this department throughout this report
even in reference to past events or documents when it was the NCDENR.

The C&D over MSW landfill has been in the Assessment Monitoring Program since August
1995. In January 2000, Burke County submitted a Water Quality Assessment Report (WQAR),
for the landfill to the NCDEQ. The WQAR determined that the constituents-of-concern (COCs)
at the landfill were several volatile organic compounds (VOCs), specifically: benzene; 1,4-
dichlorobenzene; methylene chloride; tetrachloroethylene; and trichloroethylene.

The JRWMF entered the Corrective Action Program following the correspondence received
from the NCDEQ Solid Waste Section (SWS) dated August 18, 2003. An Assessment of
Corrective Measures (ACM) was submitted to NCDEQ in February 2005. A public meeting was
held on May 16, 2006 in order to receive public comments regarding the ACM as required by
NCSWMR §.1635 (d). A Corrective Action Plan (CAP) was submitted to NCDEQ in June 2008
and revised in November 2008. The CAP was approved by NCDEQ in a letter dated January 29,
2009. An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area.

1.4 Groundwater Monitoring History
 April 1988: Facility began operations as an MSW landfill.
 August 1995: Assessment Monitoring began.
 January 1998: Facility closed as an MSW landfill, but began operating a C&D landfill
on top of the former MSW landfill.
 January 2000: Water Quality Assessment Report (JOYCE, 2000).
 October 2004: Update on Water Quality Assessment Report (JOYCE, 2004).
 February 2005: Assessment of Corrective Measures (ACM) (JOYCE, 2005a) and
Quantitative Risk Assessment (JOYCE, 2005b).
 May 2006: Public Meeting for ACM.
 June 2008: Corrective Action Plan (CAP) submitted to NCDEQ-SWS.
 November 2008: CAP Revised per comments from NCDEQ-SWS & resubmitted.
 January 2009: CAP Approved by NCDEQ-SWS.
 June 2009: First Monitored Natural Attenuation (MNA) baseline sampling event.
 May 2011: First Corrective Action Evaluation Report (CAER).

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 April 2012: Alternate Source Demonstration (ASD) for iron and manganese approved
by NCDEQ.
 August 2013: Addendum to the CAP to add control of landfill gas as a remedy.
 April 2016: Second Corrective Action Evaluation Report (CAER).

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the C&D over MSW landfill is performed in accordance with
NCSWMR §.1634, the site’s Transition Plan (JOYCE, April 1994), and the sites Corrective
Action Monitoring Plan (CAMP) (Joyce, 2008) Groundwater samples are collected
semiannually and analyzed for constituents according to the sampling plan submitted to the SWS
on October 29, 1999. Following is a summary of the compliance monitoring wells and other
wells in the immediate vicinity of the landfill.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-8 9-15-87 not used - 39.5 Saprolite -
MW-9 8-31-94 Abandoned/
Former Bkgnd. - - - -
MW-10 9-02-94 Compliance Assessment 23.0 Saprolite Comp.
MW-11 9-02-94 Compliance/
Performance
Assessment/
Cor. Act. 43.0 Saprolite Comp., MNA*
MW-12 9-01-94 Compliance/
Performance
Assessment/
Cor. Act. 51.5 Bedrock Comp., MNA*
MW-13 8-31-94 Compliance Assessment 58.0 Bedrock Comp.
MW-14 6-07-96 not used - 21.5 Saprolite -
MW-15S 6-04-96 not used - 54.0 Saprolite -
MW-15D 6-04-96 not used -118.5 Bedrock -
MW-16S 3-08-99 Compliance/
Performance
Assessment/
Cor. Act. 20.0 Saprolite Comp., MNA*
MW-16D 3-10-99 Compliance Detection 120.0 Bedrock Comp.
MW-17 3-08-99 Not used/
Former Bkgnd. - 52.0 Bedrock -
MW-18 4-07-09 Sentinel** Corrective
Action 12.0 Alluvial Soil COCs, MNA*
MW-19 4-07-09 Sentinel** Corrective
Action 13.0 Alluvial Soil COCs, MNA*
MW-20 5-18-95
Former Bkgnd./
Phase 1A
Compliance
Assessment 67.0 Saprolite Comp.
MW-21 5-18-95 Background Assessment/
Cor. Act. 45.0 Saprolite Comp., MNA*
MW-36 5-08-11 Performance*** Corrective
Action 43.0 Bedrock COCs, LFG
MW-38 5-09-11
Phase 1A
Compliance/
Performance***
Corrective
Action 71.0 Bedrock COCs, LFG

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Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics
plus C&D parameters, as required for routine assessment or detection monitoring.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation Parameters: Temperature, pH, specific conductance, oxidation
reduction potential, dissolved oxygen, nitrate, sulfate, chloride, dissolved hydrogen, sulfide, alkalinity,
TOC, methane, ethane, ethene, volatile fatty acids, carbon dioxide, ferrous iron, and turbidity.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
* After the baseline period, the NCDEQ approved alternate frequencies for carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be monitored during both semiannual
events every third year.
** After the baseline period, sampling frequency for sentinel wells was changed to annual.
*** Performance wells (MW-36& MW-38) for the control of landfill gas remedy were added in the
August 2013 CAP Addendum. MW-38 is also a compliance well for Phase 1A.

The current compliance groundwater monitoring network at the facility consists of one
upgradient well (MW-21), and six downgradient wells (MW-10, MW-11, MW-12 MW-13,
MW-16S, and MW-16D). In March 1999, monitoring wells MW-16S and MW-16D were
installed as downgradient monitoring wells and well MW-17 was installed as a replacement for
upgradient background well MW-9. These wells were incorporated into the compliance
monitoring network during the second semiannual groundwater monitoring event of 2005 after
receiving approval from the SWS in a letter dated August 1, 2005. The letter also gave approval
to drop MW-9 from the compliance monitoring network. MW-9 was abandoned in July 2006.
There are several other monitoring wells at the facility (including MW-8, MW-14, MW-15S, and
MW-15D) and several piezometers that have been used in the past to collect groundwater data to
supplement the data from the compliance monitoring wells. Sentinel wells MW-18 and MW-19
were installed on April 7, 2009 in accordance with the facility’s Corrective Action Plan.

Due to organic detections in MW-17, a request was submitted in August 2010 to replace MW-17
with MW-20 as the facility background well. MW-20 (originally named PZ-4) was installed as a
piezometer in 1995 for site characterization. The NCDEQ-SWS requested that we sample both
MW-17 and MW-20 for the next 2 sampling events (November 2010 and June 2011), and then
submit a revised Water Quality Monitoring Plan to incorporate MW-20 into the compliance
network as the new background well. MW-20 served as the background well until August 2014
when the new Permit to Operate for Phase 1A C&D Landfill expansion was issued by the North
Carolina Department of Environment and Natural Resources. MW-20 was replaced by MW-21,
(formerly PZ-1). MW-21 will serve as the new background monitoring well for both Phase 1A
and the old C&D over MSW landfills. The former background well for the old C&D over MSW
landfill, MW-20, which is located side-gradient of and to the northeast of Phase 1A, will
continue to be sampled as a compliance well for Phase 1A.

The wells in assessment monitoring (MW-10, MW-11, MW-12, MW-13, MW-16S, and MW-20)
are analyzed for the NCSWMR Appendix I list of constituents plus additional detected Appendix
II constituents and additional required C&D parameters during the first semiannual event, and
for all constituents listed in NCSWMR Appendix II plus additional required C&D parameters
during the second semiannual monitoring event. Monitoring well MW-16D is analyzed for the

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NCSWMR Appendix I plus additional required C&D parameters list during both events.
Monitoring wells MW-11, MW-12, MW-16S, and MW-21 are also sampled for MNA
parameters during each sampling event.

In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. After reviewing the CAER, in a letter dated
July 12, 2011, the NCDEQ agreed to a reduced frequency for monitoring carbon dioxide, sulfide,
volatile fatty acids, ethane, and ethylene. These parameters will be sampled during both
semiannual sampling events every third year. The first and second semiannual events of 2016
are third year events sampling for the full MNA list.

A second CAER report for the facility dated April 2016 was submitted to DEQ concluding that
conditions at the landfill were relatively stable and corrective actions and monitoring were
adequate and would continue as they had been approved in The Corrective Action Monitoring
Plan (CAMP) for the facility. DEQ reviewed and approved the CAER as described in a letter
dated April 19, 2016.

The CAMP requires samples from sentinel wells MW-18 and MW-19 to be analyzed for the
facility’s Constituents of Concern (COC’s). The COC list included the following constituents in
2016:

 Benzene;
 1,4-Dichlorobenzene;
 Methylene chloride;
 Tetrachloroethylene (PCE);
 Trichloroethylene (TCE);
 1,1-Dichloroethane;
 1,2-Dichloroethane;
 Vinyl chloride.
 alpha-BHC
 beta-BHC

After the 2011 CAER, the NCDEQ agreed that sentinel wells MW-18 and MW-19 need only be
sampled annually. MW-18 and MW-19 were last sampled during the May 2016 event. During
future events, MW-18 and MW-19 will be monitored for the above COC list plus required MNA
parameters annually.

An addendum to the facility’s CAP was submitted to the NCDEQ in August 2013, adding
control of landfill gas as a remedy for groundwater impacts on the northeastern side of the
landfill between the old landfill and the new C&D expansion area. In accordance with the CAP
addendum, piezometers PZ-36 and PZ-38 were converted to permanent monitoring wells
MW-36 and MW-38 to act as performance wells for the control of LFG remedy. MW-36 and
MW-38 are to be sampled semiannually for the current VOC COC list, plus dissolved methane
and dissolved carbon dioxide. MW-38 is also a compliance well for the Phase 1A C&D landfill.

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2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the new Phase 1A expansion.
Surface water samples are analyzed for the NCSWMR Appendix I list of constituents plus
detected Appendix II constituents during both semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A
and east of sediment basin
SB-2A. Downstream of PZ-12.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the Johns River Waste Management
Facility. This inspection program involves field personnel making the following observations:
 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

On December 13-14, 2016, personnel from JOYCE visited Johns River Waste Management
Facility to purge and sample monitoring wells MW-10, MW-11, MW-12, MW-13, MW-16S,
MW-16D, MW-21, MW-36, and MW-38. Sentinel wells MW-18 and MW-19 were not sampled.
Surface monitoring points SMP-5, SMP-6, and SMP-7 were also sampled during the December
2016 event.

Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water
level indicator for all monitoring wells in the compliance network prior to purging. Current and
historical groundwater elevation data are presented in Table 1. Monitoring wells were purged
and sampled using disposable bailers. Measurements of temperature, pH, specific conductivity,
and turbidity were recorded in the site log book as well as on field data logs prior to purging,
after each purge volume, and during sampling. Field data logs for the December 2016 event are
provided in Appendix A. Field parameter data are presented in Table 2.

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Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),
 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers either immediately after purging or within 24
hours of the final purge volume. Immediately after collection, the samples were placed in a
laboratory-provided cooler and chilled with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and
recorded in the site log book. Immediately after sample collection, the samples were placed in a
laboratory-provided cooler and chilled on ice. Field data logs are provided in Appendix A.

3.2 Laboratory Analysis and JOYCE Quality Control
The December 2016 groundwater and surface water samples were submitted to Pace Analytical
Services, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. The
groundwater samples from the wells in assessment monitoring were analyzed for the NC
Appendix II, list of constituents, plus additional required C&D parameters. Groundwater from
MW-16D was analyzed for the NC Appendix I list of constituents plus additional required C&D
parameters. In addition, samples from corrective action wells were analyzed for the COC list
plus MNA or LFG parameters as described in Section 2.1. Surface water samples were analyzed
for the NC Appendix I list of constituents plus additional detected Appendix II constituents.
JOYCE requested a Level II data report for the final laboratory report. The samples were
received by the laboratory in good condition, properly preserved, and within required hold times.

In addition to samples collected for compliance monitoring at the Johns River Waste
Management Facility, a Field Blank was collected by JOYCE personnel as part of the December
2016 sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the same
parameters as the compliance wells in Assessment Monitoring and the Trip Blank was analyzed
for Appendix I list of constituents plus additional detected Appendix II volatile organic
compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,

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and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:

 General typographical errors;
 Correct analyses performed and within method-specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), NCDEQ-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
4.1 Analytical Results for Inorganic Constituents
Six inorganic constitutes were detected above the SWSL in one or more monitoring wells during
the December 2016 sampling event. Cobalt was detected above the GWPS in all wells except
MW-21. The cobalt detections were not above the calculated background concentrations (see
Section 4.3.2); and therefore do not constitute GPS exceedances. Iron and manganese were in
exceedance of the NC 2L standards in all compliance wells with the exception of iron in
monitoring well MW-16D. An ASD was approved for iron and manganese by NCDEQ on April
12, 2012; therefore, these are not considered exceedances.

Table 3 presents the constituents with quantified detections during the December 2016 sampling
event, and Table 4 presents a summary of the exceedances of groundwater standards. Both
tables include the results from data qualification and laboratory confirmation re-analysis. In
general, the inorganic detections and concentrations are consistent with historical data. Historical
data for inorganic constituents are summarized in Appendix D.

4.2 Analytical Results for Organic Constituents
Thirteen organic constituents were detected above the SWSL in one or more monitoring wells
during the December 2016 sampling event. Nine of these detections were above an NC 2L
Standard or GWPS and include benzene; 1,4-dichlorobenzene, 1,1-dichloroethane;
1,2-dichloroethane; methylene chloride; trichloroethene; tetrachloroethene; alpha-BHC; and
beta-BHC. Table 3 presents the constituents with quantified detections during the December
2016 sampling event, and Table 4 presents a summary of the exceedances of groundwater
standards. In general, the detections and concentrations are consistent with historical data.
Historical data for organic constituents in compliance wells are summarized in Appendix E, and
historical data for organic constituents in performance and sentinel wells are summarized in
Appendix F.

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4.3 Statistical Analyses
4.3.1 Statistical Methods and Background
MW-9 was the facility background well from 1994 until May 2005, when it was abandoned.
MW-17 was the facility background well from May 1999 until June 2011. Both MW-9 and
MW-17 were sampled between May 1998 and May 2005. Due to gas related impacts to MW-17,
MW-20 became the facility background well in December 2010. Both MW-17 and MW-20
were sampled between December 2010 and June 2011. With the opening of Phase 1A of the
C&D expansion in August 2014, MW-21 (formerly PZ-1) became the facility background well
and MW-20 became a compliance well for Phase 1A.

Facility background data used to evaluate the December 2015 groundwater monitoring data
include all data collected for wells MW-9, MW-17, and MW-20 from September 1994 through
the May 2014 event plus the October 2014 through December 2015 data from MW-21.
Alternatively, intrawell statistics may be used to evaluate the statistical background for a specific
well. Data used for intrawell statistics will use all available data for that well, excluding the last
eight sampling events.

The background data for inorganic constituents were evaluated using the Shapiro-Wilk Test,
Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-
Parametric Prediction Limits, and/or Poisson Prediction Limits as appropriate. Background data,
tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are
used, as appropriate based on the background data. The statistical test by which downgradient
data are compared to facility background data is based upon the nature of the data and the
number of data values that are below the laboratory limit of detection. All statistical tests are
evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed
tests.

4.3.2 Statistical Analyses of Inorganic Constituents
The inorganic constituents detected at quantifiable concentrations (excluding blank-qualified
data) above the North Carolina SWSL in downgradient monitoring wells in the December 2016
sampling event were barium, cobalt, iron, manganese, mercury and zinc. Since barium, mercury
and zinc were not detected in exceedance of NC2L/GWPS standards, there is no need to
calculate statistical background for these constituents. Iron and manganese were addressed in an
ASD approved by NCDEQ in April 2012; therefore, we do not consider them to be exceedances.

Interwell statistics were used to a determine background value of 90.7 µg/L for cobalt. Using
intrawell statistics for MW-10, excluding the eight most recent sampling events, yields a
background for MW-10 of 253 µg/L. A summary of the statistical analyses is presented in Table
5, and the detailed statistical analyses worksheets are included in Appendix C.

Since the background concentrations of cobalt are greater than their respective GWPS, we
request that the background values be considered the applicable GPS for these constituents per
rule .1634(g)(5) of the NCSWMR; therefore, there were no GPS exceedances for any inorganic
constituents.

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4.4 Analytical Results for Surface Water
Surface monitoring points SMP-5, SMP-6, and SMP-7 were sampled during the December 2016
event. There were no quantified detections above SWSL in any of the surface water samples.
The December 2016 surface water results are generally consistent with the historical data.
Current and historical surface water data can be found in Appendix G.

5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
5.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the June
2009 sampling event and continued through the November 2010 sampling event. The baseline
data were evaluated in a CAER dated May 2011. MNA parameter data were obtained for the
following wells: the site background well (MW-21); and downgradient compliance/performance
wells MW-11, MW-12, and MW-16S. MNA field parameters included temperature, pH, specific
conductance, oxidation-reduction potential (ORP), turbidity, dissolved oxygen, dissolved carbon
dioxide and ferrous iron. MNA laboratory parameters included dissolved hydrogen, alkalinity,
TOC, dissolved methane, nitrate, sulfate, and chloride. Table 6 summarizes the MNA data for
the December 2016 event, and historical MNA data are presented in Appendix H. Field data
logs and laboratory reports are included in Appendices A and B, respectively.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to
determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 20
indicates that there is adequate evidence for anaerobic natural attenuation, and a score greater
than 20 indicates that there is strong evidence that anaerobic natural attenuation is occurring.

MNA evaluation was performed based on the results from the December 2016 sampling event
for downgradient wells within the contaminant plume, compared where appropriate to the
background well (MW-21). The Biodegradation Screening Matrix is presented in Table 7 of this
report.

One difficulty in evaluation of the Screening Matrix is that the matrix assumes some compounds
(such as, but not limited to methane and vinyl chloride) are daughter products of biodegradation
within the plume; however, at a landfill we cannot eliminate the possibility that they may be
contaminants released directly from the landfill. If we include the scores for these potential
daughter products, our total score could be artificially high; on the other hand, if we exclude
them, the score might be artificially low. Table 7 presents scoring results both with and without
the questionable daughter product scores.

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The following table summarizes the scoring results from Table 7 for both options for interpreting
the data. The scores ranged from 14 (limited evidence of natural attenuation) to 30 (strong
evidence of natural attenuation). In reality, the best score is probably in the middle of this range,
indicating good evidence of natural attenuation.

DP = Points for possible daughter products.

5.2 Biochlor Modeling and Mass-Balance Assessment

Biochlor modeling is performed annually for this facility. It was performed on the May 2016
monitoring results that included the Sentinel Wells MW-18 and MW-19; therefore, no Biochlor
modeling was done for the December 2016 event.

5.3 Trend Analysis and Plume Stability
Charts 1-10 show the concentration of key constituents versus time for the wells MW-10,
MW-11, MW-12, MW-13, and MW-16S from the earliest recorded detections through December
2016. In general, most constituents in most wells show decreasing or stable trends, especially
over the last 3-5 years. One of the clearest long-term increasing trends is for benzene in MW-13;
however, the benzene trend appears to have stabilized in the last few years. 1,4-dichlorobenzene
also shows a clear upward trend in MW-13. MW-13 is located farther north (upgradient) than
the other downgradient wells and is representative of the central part of the plume, whereas
MW-11, MW-12, and MW-16S are located nearer the southern leading edge of the plume and
MW-10 is located near the western edge of the plume. The fact that the concentrations in the
central part of the plume appear to be stable or increasing while the concentrations near the
leading edge seem to be stable or decreasing supports the contention that natural attenuation is
adequately controlling the plume.

Alpha-BHC has had sporadic detections in MW-13 over the last few sampling events. There
appears to be a seasonal component to the data trend, with detections occurring in the fall or
winter. More recent detections of alpha-BHC were at lower concentrations than the initial
detection so that a decreasing trend can be discerned in MW-13. Beta-BHC had a confirmed
detection in MW-11 for the first time during the December 2015 event. There appears to be a
seasonal component to the pattern of detection of beta-BHC in MW-11, as well as the start of a
decreasing trend, but more data is necessary to make that determination.
6.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
Points Awarded
including DP
Points Awarded
excluding DP
Points Awarded
excluding HD 30 14

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variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River
to the south. A groundwater potentiometric surface map, developed from static water level data
obtained in December 2016, is presented as Drawing 1. The potentiometric surface map depicts
groundwater flow primarily to the south.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
sampling. The December 2016 and historical groundwater elevations are provided in Table 1.
The groundwater elevations were calculated relative to the surveyed measuring point (top of
casing) for each monitoring well. Horizontal groundwater gradients along representative flow
paths were estimated from the December 2016 groundwater contours shown on Drawing 1 and
calculated gradients and flow velocities are summarized in Table 8. Horizontal gradients across
the site ranged from 0.0360 to 0.0580 ft/ft, with an average of approximately 0.0495 ft/ft. This is
consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/ne, where V = average linear velocity, K = hydraulic
conductivity, i = horizontal hydraulic gradient, and ne = effective porosity. The mean of
hydraulic conductivities from slug-tests conducted in 1995 and 2015 (K = 3.28 ft/day) was used
in these calculations, along with an estimated effective porosity of ne = 0.40 (40%) for saprolite
based on laboratory porosities for soil samples from the site.

The estimated linear groundwater flow velocity under the facility ranged from 108-174 feet/year,
with an average flow velocity of approximately 148 feet/year for the site (Table 8), or 156
feet/year under the C&D-over-MSWLF cells based on flow lines i1 and i2 only. The modified
Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer,
which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions
such as are believed to exist at this site.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility.

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7.0 CONCLUSIONS
There were several organic constituents detected above the NC 2L Groundwater Standards at the
Johns River Landfill during the December 2016 sampling event. These results are generally
consistent with previous sampling events and are being addressed by the Corrective Action Plan
for the facility.

Evaluation of MNA data and trends of key constituents all indicate that natural attenuation is
actively occurring on the site and that it is adequately controlling the constituent plume.

Cobalt was detected above the GWPS; however it was not detected above the calculated
background concentrations; therefore, we request that the background be considered ground
water protection standards for cobalt per rule .1635 (g) of the NCSWMR. An ASD was
approved for iron and manganese by NCDEQ on April 12, 2012. The inorganic results from the
December 2016 monitoring event are consistent with historical data.

There were no organic or inorganic detections above the NC 2B Surface Water Standards for
surface water samples from the December 2016 sampling event.

The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on approval of the 2016 CAER by DEQ
and the analytical results from the December 2016 sampling event, The Johns River Solid Waste
Management Facility will remain in Assessment Monitoring and Corrective Action. The next
semiannual sampling event is scheduled for the second quarter of 2017.

8.0 REFERENCES
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constucted Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

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JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

North Carolina Department of Environmental Quality (NCDEQ), 1997. North Carolina Solid
Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NCDEQ, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

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USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD,EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by NCDEQ-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Dept. of Environment and Natural Resources (now the NCDEQ)
NCDEQ North Carolina Dept. of Environmental Quality (formerly the NCDENR)
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)

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O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDEQ-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters (December 2016)
Table 3 Quantified Detections of Groundwater Constituents (December
2016)
Table 4 Exceedances of Groundwater Standards (December 2016) Table 5 Statistical Background Analyses
Table 6 MNA Parameters (December 2016)
Table 7 Biodegradation Screening Matrix Table 8 Hydraulic Gradients and Groundwater Flow Velocities

TABLE 1: HISTORICAL GROUNDWATER ELEVATIONSMW-9 MW-17 MW-20 MW-21 MW-8 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-15D MW-16S MW-16D MW-18 MW-19 MW-36 MW-38TOC Elevation1145.97 1121.77 1115.04 1099.86 1072.55 1012.23 1028.58 1034.22 1059.40 1017.96 1069.04 1069.06 1007.67 1007.87 998.49 999.95 1099.52 1087.76Well Depth67.63 43.35 67.00 41.00 39.35 24.16 44.20 53.00 59.00 23.20 56.16 121.39 21.45 90.50 12.00 15.00 45.00 73.13Jul-951089.48 NI NM NM 1040.88 998.40 994.13 993.65 1009.67 NI NI NI NI NI NI NI NI NISep-951090.60 NI NM NM 1040.80 997.73 993.10 993.54 1008.88 NI NI NI NI NI NI NI NI NIOct-951090.32 NI NM NM 1041.16 998.75 994.38 994.32 1009.46 NI NI NI NI NI NI NI NI NIApr-961090.66 NI NM NM 1041.08 998.78 993.30 993.84 1010.40 NI NI NI NI NI NI NI NI NIJun-961089.40 NI NM NM 1040.78 998.41 992.80 994.50 1010.03 1007.01 1022.70 1023.38 NI NI NI NI NI NIDec-961087.28 NI NM NM NM NM NM 994.66 1009.17 1007.14 1021.30 1021.80 NI NI NI NI NI NIMay-971087.07 NI NM NM NM 998.66 993.04 993.54 1009.52 NM NM NM NI NI NI NI NI NINov-971091.49 NI NM NM NM 999.00 993.58 993.98 1010.40 NM NM NM NI NI NI NI NI NIMay-981090.97 NI NM NM NM 999.08 993.58 994.52 1011.57 NM NM NM NI NI NI NI NI NINov-981086.65 NI NM NM NM 998.66 992.83 993.42 1010.01 NM NM NM NI NI NI NI NI NIApr-991086.35 NM NM NM 1039.87 998.19 992.73 993.12 1009.40 NM 1023.26 1023.40 NM NM NI NI NI NIMay-991087.70 NM NM NM NM 998.98 1003.35 993.78 1010.54 NM NM NM NM NM NI NI NI NIOct-991085.87 1079.43 NM NM NM 998.84 992.86 993.43 1009.65 NM NM NM 992.15 993.94 NI NI NI NIMay-001085.09 1076.55 NM NM NM 999.38 993.71 994.01 1009.75 NM NM NM 992.59 994.09 NI NI NI NINov-001085.22 1076.60 NM NM NM 998.60 992.21 992.46 1008.89 NM NM NM 991.07 992.62 NI NI NI NIMay-011085.76 1077.06 NM NM NM 997.85 992.75 993.41 1009.62 NM NM NM 992.07 993.59 NI NI NI NINov-011085.84 1079.07 NM NM NM 998.43 992.22 992.90 1008.79 NM NM NM 991.36 992.84 NI NI NI NIMay-021086.29 1080.36 NM NM NM 998.58 992.83 993.48 1009.50 NM 1021.94 1022.30 992.02 993.47 NI NI NI NINov-021085.19 1079.71 NM NM NM 999.04 993.63 993.93 1009.24 NM 1021.25 1021.59 992.66 993.60 NI NI NI NIMay-031094.25 1092.35 NM NM NM 999.53 994.16 994.96 1012.95 NM NM NM 993.03 994.22 NI NI NI NINov-031089.49 1087.02 NM NM 1041.05 999.43 993.78 994.67 1011.60 1008.06 1027.08 1028.29 992.84 994.19 NI NI NI NIMay-041086.81 1082.54 NM NM 1040.28 999.22 993.25 993.85 1011.40 1007.96 1025.71 1026.59 992.18 993.87 NI NI NI NINov-041085.92 1080.38 NM NM NM 999.26 993.58 993.72 1010.78 NM NM NM 992.57 993.67 NI NI NI NIMay-051087.82 1083.35 NM NM NM 999.01 993.17 993.87 1011.26 NM NM NM 992.30 993.72 NI NI NI NINov-05AB 1082.66 NM NM NM 998.91 992.76 993.50 1010.59 NM NM NM 991.92 993.19 NI NI NI NI25-May-06AB 1081.13 NM NM NM 998.79 992.89 993.52 1010.48 NM NM NM 991.97 993.42 NI NI NI NI01-Nov-06AB 1081.19 NM NM NM 999.35 993.42 994.02 1010.58 1008.46 1023.28 NM 992.59 993.73 NI NI NI NI30-May-07AB 1083.42 NM NM NM 998.89 992.65 993.42 1010.80 NM NM NM 991.84 993.47 NI NI NI NI02-Aug-07AB NM NM NM NM NM NM NM NM NM NM NM NM 993.28 NI NI NI NI28-Nov-07AB 1077.85 NM NM NM 998.02 989.46 990.52 1009.01 NM NM NM 988.84 990.30 NI NI NI NI29-May-08AB 1078.52 NM NM NM 998.64 992.50 993.22 1010.02 NM NM NM 991.74 993.13 NI NI NI NI06-Nov-08AB 1078.77 NM NM NM 998.83 993.36 993.78 1009.10 NM NM NM 992.42 993.67 NI NI NI NI02-Jun-09AB 1083.33 NM NM NM 1000.63 994.17 994.86 1011.20 NM NM NM 993.89 994.70 993.48 994.75 NI NI16-Nov-09AB 1082.29 NM NM NM 999.60 994.43 994.98 1010.43 NM NM NM 993.53 1004.56 994.28 993.69 NI NILocationDowngradientBackgroundPerformanceSentinelBurke Co. - Johns River C+D-over-MSWLFPermit 12-03Page 1 of 2Joyce Engineering
TABLE 1: HISTORICAL GROUNDWATER ELEVATIONSMW-9 MW-17 MW-20 MW-21 MW-8 MW-10 MW-11 MW-12 MW-13 MW-14 MW-15S MW-15D MW-16S MW-16D MW-18 MW-19 MW-36 MW-38TOC Elevation1145.97 1121.77 1115.04 1099.86 1072.55 1012.23 1028.58 1034.22 1059.40 1017.96 1069.04 1069.06 1007.67 1007.87 998.49 999.95 1099.52 1087.76Well Depth67.63 43.35 67.00 41.00 39.35 24.16 44.20 53.00 59.00 23.20 56.16 121.39 21.45 90.50 12.00 15.00 45.00 73.13LocationDowngradientBackgroundPerformanceSentinel15-Jun-10AB 1084.81 NM NM NM 999.09 992.90 993.71 1011.32 NM NM NM 992.10 993.56 992.67 992.60 NI NI30-Nov-10AB 1079.76 1056.10 NM NM 999.24 993.14 993.56 1010.25 NM NM NM 992.25 992.90 992.14 992.13 NI NI01-Jun-11AB 1080.66 1053.93 NM NM 999.22 993.36 993.92 1010.62 NM NM NM 992.48 993.74 992.98 992.81 NM NM20-Dec-11AB 1077.47 1052.27 NM NM 999.27 993.66 994.00 1009.56 NM NM NM 992.67 993.88 NM NM NM NM30-May-12AB NM 1052.63 NM NM 1000.32 993.37 993.93 1009.52 NM NM NM 992.46 993.76 993.09 993.15 NM NM11-Dec-12AB NM 1053.51 NM NM 999.04 992.94 993.46 1009.52 NM NM NM 992.05 993.43 NM NM NM NM11-Jun-13AB NM 1055.80 NM NM 1001.25 996.39 996.60 1011.00 NM NM NM 995.47 996.51 NM NM NM NM28-Oct-13AB NM 1060.44 NM NM 999.42 993.13 993.80 1010.68 NM NM NM 992.55 993.72 993.63 992.95 NM NM06-May-14AB NM 1058.24 NM NM 999.71 990.63 994.22 1010.84 NM NM NM 992.73 994.02 993.31 993.17 1069.17 1042.1821-Oct-14AB NM 1056.42 1063.48 NM 999.49 993.93 994.27 1009.98 NM 1024.64 NM 992.97 994.40 NM NM 1066.52 1045.1821-May-15AB NM 1053.69 1062.18 NM 999.22 993.03 993.62 1010.18 NM 1025.17 NM 992.11 993.36 992.54 992.60 1066.03 1044.6808-Dec-15AB NM 1051.65 1061.71 NM 999.49 992.25 993.42 1009.64 NM 1025.19 NM 994.47 995.17 NM NM 1066.72 1046.2404-May-16AB NM 1056.81 1065.36 1041.51 998.98 993.73 993.22 1009.66 NM 1026.24 NM 992.97 994.42 992.74 993.45 1071.22 1044.9113-Dec-16AB NM 1051.66 1061.11 1041.18 998.88 992.90 993.47 1007.90 NM 1022.89 NM 992.08 993.42 NM NM 1065.99 1042.81 Notes:All elevations are in feet above mean sea level. NI = Monitoring well not yet installed. NM = Groundwater level not measured. AB = Monitoring well abandoned.Burke Co. - Johns River C+D-over-MSWLFPermit 12-03Page 2 of 2Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-10 pH 5.6 S.U. 12/13/2016
MW-10 Temperature 15.3 ºC 12/13/2016
MW-10 Turbidity 13.26 NTU 12/13/2016
MW-10 Conductivity 122.0 µS 12/13/2016
MW-10 Static Water Level 13.35 ft 12/13/2016
MW-10 Well Depth 24.16 ft 12/13/2016
MW-11 pH 6.05 S.U. 12/13/2016
MW-11 Temperature 14.9 ºC 12/13/2016
MW-11 Turbidity 9.48 NTU 12/13/2016
MW-11 ORP 29 mV 12/13/2016
MW-11 DO 5.11 mg/L 12/13/2016
MW-11 Ferrous Iron 5.2 mg/L 12/13/2016
MW-11 Conductivity 458 µS 12/13/2016
MW-11 Static Water Level 35.68 ft 12/13/2016
MW-11 Well Depth 44.20 ft 12/13/2016
MW-12 pH 6.22 S.U. 12/13/2016
MW-12 Temperature 14.9 ºC 12/13/2016
MW-12 Conductivity 198.0 µS 12/13/2016
MW-12 ORP 18.1 mV 12/13/2016
MW-12 DO 3.23 mg/L 12/13/2016
MW-12 Ferrous Iron 3.0 mg/L 12/13/2016
MW-12 Turbidity 10.2 NTU 12/13/2016
MW-12 Static Water Level 40.75 ft 12/13/2016
MW-12 Well Depth 53.00 ft 12/13/2016
MW-13 pH 4.87 S.U. 12/13/2016
MW-13 Temperature 14.7 ºC 12/13/2016
MW-13 Conductivity 42.0 µS 12/13/2016
MW-13 Turbidity 11.17 NTU 12/13/2016
MW-13 Static Water Level 51.50 ft 12/13/2016
MW-13 Well Depth 59.00 ft 12/13/2016
MW-16S pH 5.77 S.U. 12/13/2016
MW-16S Temperature 14.8 ºC 12/13/2016
MW-16S Conductivity 215.0 µS 12/13/2016
MW-16S Turbidity 9.7 NTU 12/13/2016
MW-16S ORP 70.9 mV 12/13/2016
MW-16S Ferrous Iron 2.2 mg/L 12/13/2016
MW-16S DO 2.07 mg/L 12/13/2016
MW-16S Static Water Level 15.59 ft 12/13/2016
MW-16S Well Depth 21.45 ft 12/13/2016
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
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Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-16D pH 8.88 S.U. 12/13/2016
MW-16D Temperature 14.6 ºC 12/13/2016
MW-16D Turbidity 15.05 NTU 12/13/2016
MW-16D Conductivity 103 µS 12/13/2016
MW-16D Static Water Level 14.45 ft 12/13/2016
MW-16D Well Depth 90.50 ft 12/13/2016
MW-15S pH 5.55 S.U. 12/13/2016
MW-15S Temperature 14.8 ºC 12/13/2016
MW-15S Turbidity 10.5 NTU 12/13/2016
MW-15S Conductivity 51 µS 12/13/2016
MW-15S Static Water Level 46.15 ft 12/13/2016
MW-15S Well Depth 58.27 ft 12/13/2016
MW-21 pH 5.17 S.U. 12/13/2016
MW-21 Temperature 14.4 ºC 12/13/2016
MW-21 Turbidity 12.63 NTU 12/13/2016
MW-21 Conductivity 115 µS 12/13/2016
MW-21 Dissolved Oxygen 5.41 mg/L 12/13/2016
MW-21 Oxygen Reduction Potential 180.4 mV 12/13/2016
MW-21 Ferrous Iron 0.5 mg/L 12/13/2016
MW-21 Static Water Level 38.75 ft 12/13/2016
MW-21 Well Depth 46.80 ft 12/13/2016
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
2 of 3
Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-36 pH 5.97 S.U. 12/13/2016
MW-36 Temperature 15.6 ºC 12/13/2016
MW-36 Turbidity 13.61 NTU 12/13/2016
MW-36 Conductivity 221 µS 12/13/2016
MW-36 Static Water Level 33.53 ft 12/13/2016
MW-36 Well Depth 45.58 ft 12/13/2016
MW-38 pH 6.78 S.U. 12/13/2016
MW-38 Temperature 14.3 ºC 12/13/2016
MW-38 Turbidity 9.2 NTU 12/13/2016
MW-38 Conductivity 33 µS 12/13/2016
MW-38 Static Water Level 32.80 ft 12/13/2016
MW-38 Well Depth 74.50 ft 12/13/2016
MW-35 pH 6.22 S.U. 12/13/2016
MW-35 Temperature 15.2 ºC 12/13/2016
MW-35 Turbidity 9.73 NTU 12/13/2016
MW-35 Conductivity 22 µS 12/13/2016
MW-35 Static Water Level 23.95 ft 12/13/2016
MW-35 Well Depth 39.05 ft 12/13/2016
SMP-5 pH 7.4 S.U. 12/13/2016
SMP-5 Temperature 11.5 ºC 12/13/2016
SMP-5 Conductivity 118.7 µS 12/13/2016
SMP-5 Turbidity 30.4 NTU 12/13/2016
SMP-6 pH 6.69 S.U. 12/13/2016
SMP-6 Temperature 10.7 ºC 12/13/2016
SMP-6 Conductivity 81 µS 12/13/2016
SMP-6 Turbidity 14.43 NTU 12/13/2016
SMP-7 pH 6.32 S.U. 12/13/2016
SMP-7 Temperature 8.9 ºC 12/13/2016
SMP-7 Conductivity 25 µS 12/13/2016
SMP-7 Turbidity 10.15 NTU 12/13/2016
Notes: ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
mV = millivolts
ft = feet
Verification (resample) event performed 2-04-2016 parameters included.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
3 of 3
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS OF GROUNDWATER CONSTITUENTS
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW10 Cobalt 93.2 µg/L 10 12/13/2016
1203-MW10 Iron 17,600 µg/L 300 12/13/2016
1203-MW10 Manganese 5,100 µg/L 50 12/13/2016
1203-MW10 Zinc 12.8 µg/L 10 12/13/2016
1203-MW10 Mercury 0.25 µg/L 0.2 12/13/2016
1203-MW10 Benzene 1.7 µg/L 1 12/13/2016
1203-MW10 cis-1,2-Dichloroethene 5.1 µg/L 5 12/13/2016
1203-MW10 Alkalinity, Total as CaCO3 35,700 µg/L NE 12/13/2016
1203-MW10 Total Dissolved Solids 73,000 µg/L NE 12/13/2016
1203-MW10 Chloride 9,040 µg/L NE 12/13/2016
1203-MW11 beta-BHC 0.12 µg/L 0.05 12/13/2016
1203-MW11 Barium 128 µg/L 100 12/13/2016
1203-MW11 Cobalt 52.4 µg/L 10 12/13/2016
1203-MW11 Iron 67,800 µg/L 300 12/13/2016
1203-MW11 Manganese 17,900 µg/L 50 12/13/2016
1203-MW11 Zinc 17.6 µg/L 10 12/13/2016
1203-MW11 1,4-Dichlorobenzene 10.5 µg/L 1 12/13/2016
1203-MW11 Benzene 2.3 µg/L 1 12/13/2016
1203-MW11 cis-1,2-Dichloroethene 5.7 µg/L 5 12/13/2016
1203-MW11 Alkalinity, Total as CaCO3 97,700 µg/L NE 12/13/2016
1203-MW11 Total Dissolved Solids 241,000 µg/L NE 12/13/2016
1203-MW11 Chloride 35,000 µg/L NE 12/13/2016
1203-MW12 Cobalt 70.6 µg/L 10 12/13/2016
1203-MW12 Iron 45,300 µg/L 300 12/13/2016
1203-MW12 Manganese 8,850 µg/L 50 12/13/2016
1203-MW12 1,1-Dichloroethane 27.4 µg/L 5 12/13/2016
1203-MW12 1,2-Dichloroethane 1.1 µg/L 1 12/13/2016
1203-MW12 1,4-Dichlorobenzene 4.7 µg/L 1 12/13/2016
1203-MW12 Benzene 2.8 µg/L 1 12/13/2016
1203-MW12 Trichloroethene 2.1 µg/L 1 12/13/2016
1203-MW12 cis-1,2-Dichloroethene 9.8 µg/L 5 12/13/2016
1203-MW12 Alkalinity, Total as CaCO3 54,100 µg/L NE 12/13/2016
1203-MW12 Total Dissolved Solids 133,000 µg/L NE 12/13/2016
1203-MW12 Chloride 7,650 µg/L NE 12/13/2016
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03 1 of 2
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS OF GROUNDWATER CONSTITUENTS
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW13 alpha-BHC 0.063 µg/L 0.05 12/13/2016
1203-MW13 Cobalt 58.8 µg/L 10 12/13/2016
1203-MW13 Iron 969 µg/L 300 12/13/2016
1203-MW13 Manganese 1,560 µg/L 50 12/13/2016
1203-MW13 Zinc 15.7 µg/L 10 12/13/2016
1203-MW13 1,1-Dichloroethane 26.4 µg/L 5 12/13/2016
1203-MW13 1,2-Dichloroethane 1.3 µg/L 1 12/13/2016
1203-MW13 1,4-Dichlorobenzene 13.9 µg/L 1 12/13/2016
1203-MW13 Benzene 14.5 µg/L 1 12/13/2016
1203-MW13 Ethylbenzene 3.0 µg/L 1 12/13/2016
1203-MW13 Methylene Chloride 41.8 µg/L 1 12/13/2016
1203-MW13 Tetrachloroethene 5.9 µg/L 1 12/13/2016
1203-MW13 Toluene 6.8 µg/L 1 12/13/2016
1203-MW13 Trichloroethene 9.9 µg/L 1 12/13/2016
1203-MW13 Xylene (Total)63.8 µg/L 5 12/13/2016
1203-MW13 cis-1,2-Dichloroethene 25.7 µg/L 5 12/13/2016
1203-MW13 Alkalinity, Total as CaCO3 9,380 µg/L NE 12/13/2016
1203-MW13 Chloride 1,810 µg/L NE 12/13/2016
1203-MW16D Manganese 122 µg/L 50 12/13/2016
1203-MW16D Alkalinity, Total as CaCO3 49,400 µg/L NE 12/13/2016
1203-MW16D Total Dissolved Solids 90,000 µg/L NE 12/13/2016
1203-MW16S Cobalt 28.1 µg/L 10 12/13/2016
1203-MW16S Iron 24,000 µg/L 300 12/13/2016
1203-MW16S Manganese 10,900 µg/L 50 12/13/2016
1203-MW16S Zinc 51.0 µg/L 10 12/13/2016
1203-MW16S 1,1-Dichloroethane 22.1 µg/L 5 12/13/2016
1203-MW16S 1,2-Dichloroethane 1.2 µg/L 1 12/13/2016
1203-MW16S 1,4-Dichlorobenzene 7.2 µg/L 1 12/13/2016
1203-MW16S Benzene 1.4 µg/L 1 12/13/2016
1203-MW16S cis-1,2-Dichloroethene 6.1 µg/L 5 12/13/2016
1203-MW16S Alkalinity, Total as CaCO3 72,100 µg/L NE 12/13/2016
1203-MW16S Total Dissolved Solids 131,000 µg/L NE 12/13/2016
1203-MW16S Chloride 9,280 µg/L NE 12/13/2016
Notes: µg/l = Micrograms per liter (parts per billion).
ND = Not detected.
J = Estimated concentration below the SWSL.
B = Blank-qualified detection (constituent detected in a field, trip, or method blank at a similar concentration).
SWSL = NC Solid Waste Section Reporting Limit.
NE = SWSL not established (Laboratory reporting limit used).
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03 2 of 2
Joyce Engineering
TABLE 4:
EXCEEDANCES OF GROUNDWATER STANDARDS
WELL ID PARAMETER RESULT UNITS SWSL
NC2L/
*GWPS/
**NC2B GPS COLLECT DATE
1203-MW10 Cobalt 93.2 µg/L 10 1* 253 12/13/2016
1203-MW10 Iron 17600 µg/L 300 300 ASD 12/13/2016
1203-MW10 Manganese 5100 µg/L 50 50 ASD 12/13/2016
1203-MW10 Benzene 1.7 µg/L 1 1 1 12/13/2016
1203-MW11 Cobalt 52.4 µg/L 10 1* 90.7 Bkg. 12/13/2016
1203-MW11 Iron 67800 µg/L 300 300 ASD 12/13/2016
1203-MW11 Manganese 17900 µg/L 50 50 ASD 12/13/2016
1203-MW11 beta-BHC 0.12 µg/L 0.05 0.019 0.050 12/13/2016
1203-MW11 1,4-Dichlorobenzene 10.5 µg/L 1 6 6 12/13/2016
1203-MW11 Benzene 2.3 µg/L 1 1 1 12/13/2016
1203-MW12 Cobalt 70.6 µg/L 10 1* 90.7 Bkg. 12/13/2016
1203-MW12 Iron 45300 µg/L 300 300 ASD 12/13/2016
1203-MW12 Manganese 8850 µg/L 50 50 ASD 12/13/2016
1203-MW12 1,1-Dichloroethane 27.4 µg/L 5 6 6 12/13/2016
1203-MW12 1,2-Dichloroethane 1.1 µg/L 1 0.4 1 12/13/2016
1203-MW12 Benzene 2.8 µg/L 1 1 1 12/13/2016
1203-MW13 Cobalt 58.8 µg/L 10 1* 90.7 Bkg. 12/13/2016
1203-MW13 Iron 969 µg/L 300 300 ASD 12/13/2016
1203-MW13 Manganese 1560 µg/L 50 50 ASD 12/13/2016
1203-MW13 alpha-BHC 0.063 µg/L 0.05 0.006 0.050 12/13/2016
1203-MW13 1,1-Dichloroethane 26.4 µg/L 5 6 6 12/13/2016
1203-MW13 1,2-Dichloroethane 1.3 µg/L 1 0.4 1 12/13/2016
1203-MW13 1,4-Dichlorobenzene 13.9 µg/L 1 6 6 12/13/2016
1203-MW13 Benzene 14.5 µg/L 1 1 1 12/13/2016
1203-MW13 Methylene Chloride 41.8 µg/L 1 5 5 12/13/2016
1203-MW13 Tetrachloroethene 5.9 µg/L 1 0.7 1 12/13/2016
1203-MW13 Trichloroethene 9.9 µg/L 1 3 3 12/13/2016
1203-MW16D Manganese 122 µg/L 50 50 ASD 12/13/2016
1203-MW16S Cobalt 28.1 µg/L 10 1* 90.7 Bkg. 12/13/2016
1203-MW16S Iron 24000 µg/L 300 300 ASD 12/13/2016
1203-MW16S Manganese 10900 µg/L 50 50 ASD 12/13/2016
1203-MW16S 1,1-Dichloroethane 22.1 µg/L 5 6 6 12/13/2016
1203-MW16S 1,2-Dichloroethane 1.2 µg/L 1 0.4 1 12/13/2016
1203-MW16S 1,4-Dichlorobenzene 7.2 µg/L 1 6 6 12/13/2016
1203-MW16S Benzene 1.4 µg/L 1 1 1 12/13/2016
Notes: µg/l = Micrograms per liter (parts per billion).
ND = Not detected.
SWSL = NC Solid Waste Section Reporting Limit.
NE = SWSL not established (Laboratory reporting limit used).
NC2L = Groundwater Protection Standard from 15A NCAC 2L.0202.
GWPS = NC SWS Groundwater Protection Standard for constituents with no lisated NC2L.
GPS = Groundwater Protection Standard as defind by 15 A NCAC 13B.1634.(g).
Bkg. = Indicates a Proposed GPS based on background (See Section 4.3 & Table 5).
GPS = SWSL if SWSL > listed NC2L or GWPS.
ASD = This constituent coverd by an approved Alternate Source Determination; therefore, it is not considered a GPS exceedance.
Bold Results are considered exceedances of the GPS.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Joyce Engineering
TABLE 5: STATISTICAL BACKGROUND ANALYSESAnalyte Data Distribution Statistical Method used to Establish BackgroundBackground (µg/L)SWSL (µg/L)NC2L or *GWPS (µg/L)Proposed GPS (µg/L)Sampling Result (Max.) (µg/L)GPS ExceedancesCobalt147% ND, Log-NormalUpper Tolerance Limit: Interwell90.7 10 1* 90.7 70.6 NoneCobalt20% ND, Log-NormalUpper Tolerance Limit: Intrawell (MW-10)253 10 1* 253 93.2 NoneNotes: SWSL = NC Solid Waste Section LimitsNC 2L = NC Groundwater Standards (15A NCAC 2L.0202)GWPS = Solid Waste Section Groundwater Protection Standards for Constituents with no NC 2L (indicated by *%ND = percentage of data that were non-detect (i.e., truncated).Only constituents with quantified detections above the SWSL in down-gradient wells are included in statistical analyses.GPS = Groundwater Protection Standard per 15A NCAC .1634(g) 1 Cobalt for all wells except MW-102 Cobalt for MW-10Sample Date: December 13, 2016Burke Co. - Johns River C+D-over-MSWLFPermit No. 12-03Joyce Engineering
TABLE 6: MNA Parameters UpgradientAnalyte/Parameter Date Units MW-21 MW-11 MW-12 MW-16S MW-18 MW-19Temperature (FP)12/13/2016oC14.4 14.9 14.9 14.8 NS NSpH (FP)12/13/2016 S.U. 5.176.056.225.77NSNSSpecific Conductance (FP)12/13/2016 µS/cm115458198215NSNSORP (FP)12/13/2016 mV 180.4 29.018.170.9NSNSTurbidity (FP)12/13/2016 ntu 12.63 9.48 10.20 9.70NSNSDissolved Oxygen (FP)12/13/2016 mg/l 5.415.113.232.07NSNSIron II (ferrous iron) (FP)12/13/2016 mg/l 0.505.23.02.2NSNSCarbon Dioxide 12/13/2016 mg/l 36.014.0220310NSNSNitrate12/13/2016 mg/l 0.210 J NDNDNDNSNSAlkalinity12/13/2016 mg/l 1.090 J 10645.677.6NSNSChloride12/13/2016 mg/l 1.330 30.300 10.700 8.240NSNSSulfate12/13/2016 mg/l ND 3.500 J 4.020 J 10.700 NSNSSulfide12/13/2016 mg/l NDNDNDNDNSNSMethane12/13/2016 mg/l ND 3.050 8.940 17.300 NSNSEthane + Ethene 12/13/2016 mg/l NDNDNDNDNSNSDissolved Hydrogen 12/13/2016 nM 1.92.01.51.3NSNSTOC12/13/2016 mg/l 0.70 J 4.03.73.6NSNSBTEX12/13/2016 mg/l ND 0.0023 0.0028 0.0017 NSNSVolatile Fatty Acids12/13/2016 mg/l NDNDNDNDNSNSNotes: (FP) = Field ParametermV = millivoltsND = Not DetectedS.U. = standard unitsJ = Estimated concentrationoC = degrees CelciusORP = Oxidation-Reduction Potential mS/cm = microsiemens per centimeterTOC = Total Organic Carbon mg/l = milligrams per liter (parts per million)BTEX = Total Benzene, Toluene, Ethylbenzene, Xylenes µg/l = micrograms per liter (parts per billion)DowngradientSentinelBurke Co. - Johns River C+D-over-MSWLFPermit 12-03Joyce Engineering
TABLE 7:
BIODEGRADATION SCREENING MATRIX
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 3 3
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide > 1 mg/L Reductive pathway possible 3 0 0
Methane < 0.5 mg/L Vinyl chloride oxidizes 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 3 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1
Potential < -100 mV Reductive pathway likely 2
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2 0 0
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0
be natural or anthropogenic
Temperature >20o C At T > 20
oC biochemical process is accelerated 10 0
Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 1 0
Alkalinity > 2x background Results from interaction between CO2 and 1 1 1
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0
Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE) --- Material released 0 0 0
Trichloroethene (TCE) --- Material released 0 0
--- Daughter product of PCE 2 2
Dichloroethenes (DCE) --- Material released 0 0
Daughter product of TCE 2 2
Dichloroethene, cis-1,2, --- Material released 0 0
--- Daughter product of trichlorethene 2 2
Vinyl Chloride (VC) --- Material released 0 0
--- Daughter product of DCE 2 2
1,1,1-Trichloroethane (TCA) --- Material released 0 0 0
1,1-Dichloroethane (DCA) --- Material released 0 0
Daughter product of TCA 2 2
Chloroethane --- Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 2 0
Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0
> 0.1 mg/L 3 0 0
Chloroform --- Material released 0 0 0
--- Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC) --- Material released 0 0 0
(Methylene Chloride) --- Daughter product of chloroform 2
Based on samples collected on December 13-14, 2016. Total Points Awarded : 30 14
mg/L = miligrams per liter
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = nanomolar it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes (Score based on MW-13 data).
NS (0) = Not sampled for this parameter, value in parenthsis is a score based on historical data.SCORE: Evid. of Nat. Atten.
< 5 inadequate
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's 6-14 limited
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 15-19 adequate
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents > 20 strong
in Groundwater, September 1988.
Burke Co. - Johns River C+D-over-MSWLF
Permit 12-03
1 of 1
Joyce Engineering
TABLE 8: HYDRAULIC GRADIENTS AND GROUNDWATER FLOW VELOCITIESGRADIENT CALCULATION SEGMENTFLOW LINE LENGTH (feet)FLOW DIRECTIONGROUNDWATER ELEVATION (feet)HORIZONTAL GRADIENT i (ft/ft)HYDRAULIC CONDUCTIVITY K (ft/day)EFFECTIVE POROSITY neLINEAR VELOCITY V (ft/year)10701020107010001070101010601030AVERAGE: 0.0495AVERAGE: 148.2Notes:Hydraulic conductivity (K=3.28 ft/day) is based on the arithmetric means of K from individual slug tests in saprolite wells at the facility.Effective Porosity (ne = 0.40) is assummed to be slightly less than the average laboratory porosity for site soil samples (saprolite) = 44% (0.44).Gradient segments are based on the December 2016 groundwater potentiometric surface map (see Drawing 1).V = Ki/ne; assumes homogeneous isotropic porous aquifer.December 13, 2016i1907SSW0.0551 3.28E+00 0.40 165.0146.5i31,035SSE0.0580 3.28E+00 0.40 173.5i21,430S0.0490 3.28E+00 0.40107.8i4833SE0.0360 3.28E+00 0.40Burke Co. - Johns River C+D-over-MSWLFPermit 12-03Joyce Engineering

CHARTS

Chart 1: Benzene Concentrations vs. Time
Chart 2: 1,4-Dichlorobenzene Concentrations vs. Time
Chart 3: 1,1-Dichloroethane Concentrations vs. Time
Chart 4: 1,2-Dichloroethane Concentrations vs. Time
Chart 5: Tetrachloroethylene (PCE) Concentrations vs. Time
Chart 6: Trichloroethylene (TCE) Concentrations vs. Time
Chart 7: Vinyl Chloride Concentrations vs. Time
Chart 8: Methylene Chloride Concentrations vs. Time
Chart 9 alpha-BHC Concentrations vs. Time
Chart 10: beta-BHC Concentrations vs. Time

Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering024681012141618May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 1:  Benzene Concentration vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineeirng0510152025May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 2:  1,4‐Dichlorobenzene Concentration vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering050100150200250300May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 3:  1,1‐Dichloroethane vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 4:  1,2‐Dichloroethane vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 5:  Tetrachloroethene vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering02468101214161820May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 6:  Trichloroethene vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering00.511.522.533.54May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 7:  Vinyl Chloride vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering0100200300400500600700800900May‐94Nov‐94May‐95Nov‐95May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 8:  Methylene Chloride vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03 Joyce Engineering00.020.040.060.080.10.120.140.160.180.2May‐96Nov‐96May‐97Nov‐97May‐98Nov‐98May‐99Nov‐99May‐00Nov‐00May‐01Nov‐01May‐02Nov‐02May‐03Nov‐03May‐04Nov‐04May‐05Nov‐05May‐06Nov‐06May‐07Nov‐07May‐08Nov‐08May‐09Nov‐09May‐10Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 9:  alpha‐BHC vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS
Johns River Landfill, Burke Co.Permit 12‐03Joyce Engineering00.050.10.150.20.250.30.35Nov‐10May‐11Nov‐11May‐12Nov‐12May‐13Nov‐13May‐14Nov‐14May‐15Nov‐15May‐16Nov‐16Concentration  (µg/l)Chart 10:  beta‐BHC vs. Time in Downgradient WellsMW‐10MW‐11MW‐12MW‐13MW‐16SGPS

FIGURE

Figure 1: Site Location Map

APPROXIMATE LOCATION
OF EXISTING LANDFILL
APPROXIMATE LOCATION
OF PROPERTY LINE
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
0
(FEET)
GRAPHIC SCALE
400020001000
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
PROJECT NO.
FIGURE NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
All rights reserved.
Ó Joyce Engineering, Inc.
SCALE
NC CORP LIC: C-0782
JOHN'S RIVER LANDFILL
BURKE COUNTY, NORTH CAROLINA
SITE LOCATION MAP
277
1
AS SHOWN
2017
ACE
RH
ACE
ACE
2017

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5SURFACE MONITORING POINT LOCATION AND IDENTIFICATIONNOT MEASUREDLEGENDPROPERTY LINEEXISTING ROADEXISTING 25' TOPOGRAPHIC CONTOUREXISTING 2' TOPOGRAPHIC CONTOURGROUNDWATER SURFACE CONTOUR [FEETABOVE MEAN SEA LEVEL (AMSL)]APPROXIMATE LIMITS OF WASTECENTERLINE OF STREAMGAS PROBE LOCATION AND IDENTIFICATIONPIEZOMETER LOCATION AND IDENTIFICATIONCOMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)(NM)GP10501020MW-131007.90PZ-9DGMP-3TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.STATIC WATER LEVELS WERE MEASURED ON DECEMBER 12, 2016.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN ANDEXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWNFIELD CONDITIONS.MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATINGGROUNDWATER CONTOURS.NOTESEXISTING 5' TOPOGRAPHIC CONTOUREXISTING 10' TOPOGRAPHIC CONTOUR1080T1TEMPORARY WELLAPPROXIMATE LOCATION OF SPRING HEAD1.2.3.4.5.JE-0020CONTROL POINT LOCATION AND IDENTIFICATIONSENTINEL WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)MW-18GROUNDWATER FLOW PATHWAY USED TOCALCULATE HYDRAULIC GRADIENTi1SEGMENT USED FOR GRADIENT CALCULATIONMW-9ABANDONED OR UNUSED MONITORING WELLiiiFLOW PATH LENGTH907 LF1,430 LF1,035 LF833 LFi1030102
01010102010101000100010101020103010401050 106010701080109011001110112011301140115011601150114011301120111011001090108011701080107010601050104010501040103010201010100010601050104010301020101010001070i1i2
i3i41060(ABANDONED)PZ-2S(ABANDONED)PZ-2D(NM)PZ-23(NM)PZ-15(NM)MW-22D1042.52MW-22S(NM)PZ-16D(NM)PZ-16S1017.19PZ-12(NM)PZ-27(NM)PZ-14(NM)PZ-13(ND)PZ-9D(NM)PZ-9S1007.90MW-13SMP-6993.47MW-12992.90MW-11993.47MW-16D992.08MW-16S998.88MW-10SMP-5(ABANDONED)MW-9(NM)MW-141022.89MW-15S(NM)MW-15D1041.18MW-8(NM)MW-1(FORMERLY PZ-4)MW-20NMMW-17SHOOTINGRANGEMULCHINGAREALOWER CREEKJOHNS RIVERCATAWBA R
IVER PROTECTED AREAWETLANDEXISTING TRAILAPPROX. LIMIT OFEXISTING WASTETRANSFER FACILITYBOUNDARYEXISTINGSEDIMENTBASINEXISTING C&DDISPOSAL AREACURRENT BACKGROUND WELLFORMER MW-18MW-19NMNM1056.66OFFICEANDGARAGE1040 1050 1070 1080 1090 11001060MW-381042.81MW-361065.99PZ-30S1046.32PZ-30DPZ-311057.01PZ-351039.441061.11MW-21 (FORMERLY PZ-1)BACKGROUND WELLCURRENT PHASE 1A LIMITSPROJECT NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
DATE REVISIONS AND RECORD OF ISSUE BYNO APPCKSCALE All rights reserved.
Ó Joyce Engineering, Inc.DRAWING NO.N:\Dwgs\Drawings-Current\BURKE\GW EVENT MAPS\GW-EVENT 12-16.DWG Layout=SHT 01
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]JOHNS RIVER, WASTE MANAGEMENT FACILITY
BURKE COUNTY, NORTH CAROLINA
20171AS NOTEDGROUNDWATER POTENTIOMETRIC SURFACE MAP
DECEMBER 12, 2016
PERMIT NO. 12-03
GE
RWH
VB
VB
01/25/170(FEET)GRAPHIC SCALE400200100

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Inorganic Groundwater Constituents
Appendix E Historical Detected Organic Groundwater Constituents
Appendix F Historical Detected Constituents in Performance & Sentinel Wells
Appendix G Historical Detected Surface Water Constituents
Appendix H Historical MNA Parameters
Appendix I Biochlor Modeling Input & Output

Appendix A

Field Data Logs

2inches13.35feet24.16feet10.81feet[DTB-DTW]1.7gallons________gallons5.1gallons5.1gallonsGallonsTimeTemp(°C)pH(s.u.)Cond.(j.tS)Turb.ORPDOInitials(NTU)(mV)(mgIL)0081415.85.631548.0498.72.40HS1.7081616.56.1232510.2145.11.81HS3.4081816.66.1133422.841.53.27HS5.1082016.56.1428618.7447.55.23HSBefore123015.35.6012213.2694.83.34HSSamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son 12/13/2016.L\?/,,tiSignature:Date:QA/QCSignOff:Date:12—i3-LDATE:12/13/2016JOYcE__________sr%Jc9ir’JsRIr’GROUNDWATERSAMPLING1LOGProjectName:BurkeCounty- JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-10Sampler(s):G.Eller/H.SeatonYe1lLocation:onroadtooldbarnonrightWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:11.00feet)/,,//7
DATE:12/13/2016JOYCEJGlrJERIrJGWellLocation:alongnerimeterroadWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:2inches35.68feet44.20feet8.52feet[DTB-DTW]1.3gallons=_____________gallons=3.9gallonsDate:Date:3.9gallonsGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-ilSampler(s):G.Eller/H.Seaton35.65feetGallonsTimeTemp(°C)DOCond.pH(s.u.)ORP(my)Turb.Initials(mg/L)QiSIcm)(NTU)0082815.42.974896.2435.96.79GE1.3083015.64.045416.3416.99.97GE2.6083215.42.135376.366.89.59GE3.9083415.53.195436.403.98.57GEBeforeSampling114514.95.1145$6.0529.09.48GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesin the40son12/13/2016.Fe2+:5.2mg/LSignature:_________________QA/QCSignOff:/f/7
Signature:QAIQCSignOff:__________________2inches40.75feet53.00feet12.25feet[DTB-DTW]=1.9gallons=_____________gallons=5.7gallons5.7gallonsDate:Date:JOYCE8rJcIr\jsERIr\JcDATE:12/13/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-12Sampler(s):G.EllenH.SeatonWellLocation:half-waydownslopeofbacksideoflandfill,betweenMW-li&MW-13WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163for4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:13.00feetGallonsTimeTemp(°C)DOCond.p11(s.u.)ORP(my)Turb.Initials(mg/L)(uS/cm)(NTU)0102614.80.692126.0113.012.10HS1.9102815.11.322126.047.446.2HS3.8103015.31.792126.108.165.0HS5.7103214.71.832136.1413.7138HSBeforeSampling141014.93.231986.2218.110.20GEFe2+:3.0mg/LComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaresinthe40son12/i3/2016.//?//7
DATE:12/13/2016JOYCE8I\JGIr\JSSRiC’JGProjectName:BurkeCounty-JohnsRiverWellID:MW-13WellLocation:downhillfromwastealongperimeterroadWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColunmThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163for4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmount Purged/Bailed:Purgedwith:DisposablebailerSampledwith:DisposablebailerDepthtoWaterbeforeSampling:2inches51.50feet59.00feet7.50feet[DTB-DTW]GallonsTimeTemp(°C)pH(s.u.)Cond.ORPDOTurb.Initials(iS/cm)(mV)(mg/L)(NTU)0104314.95.014495.71.726.21GE1.2104515.25.014098.22.299.65GE2.4104715.04.9838104.00.3313.0GE3.6104914.95.0038103.70.6023.7GEBefore144514.74.8742133.82.5811.17GESampling12rAiAJAJSignature:QAIQCSignOff:)(1.J*-2GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:00277.1701.12.02Sampler(s):G.Eller/H.Seaton=1.2gallons=______________gallons=3.6gallons3.6gallons51.90feetComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe40son12/13/2016._
_
___Date:Date:(72--(3—(C/71?//7
DATE:12/13/2016JOYCEEr\JGIc\I8Rlr\JGProjectName:BurkeCounty-JohnsRiverWellID:MW-i6flGROUNDWATERSAMPLINGLOGProjectNo.IlaskNo.:00277.1701.12.02Sampler(s):G.Flier/H.SeatonWellLocation:besideMW-16SWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163for4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:12-VoltSubmersiblePumpSampledwith:Disposable BailerDepthtoWaterbeforeSampling:Signature:t74i¼/Date:QA!QCSignOff:V-d-’Date:2inches14.45feet90.50feet76.05feet[DTB-DTW]=12.3gallons=______________gallons=36.9gallons36.9gallonsfeetGallonsTimeTemp(°C)p11(s.u.)Cond.DOORPTurb.Initials(j.tS/cm)(mg/L)(mY)(NTU)0093515.09.121050.88-436.74.83HS12.3094014.69.591110.91-361.17.20HS24.6094614.88.491081.44-201.38.54HS36.9095814.68.881031.60-31.215.05HSBeforeSampLing095$14.68.881031.60-31.215.05HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe40son12/13/2016.-///Z/
DATE:12/13/2016JOYCE_________Ef”JGU\J&R!I\JGGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-16SSampler(s):G.Eller/ H.SeatonWellLocation:downaccessroadalongriverDate:Date:2inches15.59feet21.45feet5.86feet[DTB-DTW]=0.9gallons=____________gallons=2.7gallons2.0gallonsWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:15.55feetGallonsTimeTemp(°C)DOCond.p11ORP(mV)Turb.Initials(mg/L)(uS/cm)(s.u.)(NTU)0100915.12.232246.18-52.710.29HS0.9101114.71.982046.06-42.29.38 HS1.8101314.92.322216.14-23.08.75HSDry2.0HSBeforeSampling133014.82.072155.7770.99.70HSFe2+:2.2m/L.Comments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son12/13/2016.___
__
_
_
_
_
_
_
_
___
__
_Signature:td_QA/QCSignOff:__________________/4//
Fe2+:0.5m/LProjectNo./TaskNo.:277.1701.12.02G.Eller/H.Seaton2inches38.75feet46.80feet8.05feet[DTB-DTW]=1.3gallons=_____________gallons=3.9gallons3.9aHonsSignature:J-q.Date:QA/QCSignOff:_________________Date:t2—r--tLDATE:12/13/2016DEVELOPMENTANDGROUNDWATERSAMPLINGLOGOfftheroadbythewesternoronertvboundary.unfromGP-1JOYCEGI(\J8RIrJProjectName:John’sRiver,BurkeCoWellID:MW-21Sampler(s):WellLocation:__________________________WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653forTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:38.76feetGallonsTimeTemp(°C)DOCond.pHORP(mV)Turb.Initials(mg/L)(pS/cm)(s.u.)(NTU)0080113.77.55192.34.56384.78.25GE1.3080314.06.98218.43.26381.570.6GE2.6080513.37.71120.44.92279.1175GE3.9080713.57.60119.24.93286.8200GEBeforeSampling124514.45.41115.05.17180.412.63HSComments(weatherconditions,odor,color,silt, etc.):inthe40son12/13/2016.Theweatherwassunnywithtemperatures
2inches33.53feet45.58feet12.05feet[DTB-DTW]=1.9gallons=____________gallons=5.7gallons5.7gallonsSignature:JifQA/QCSignOff:__________________Date:t2-HH—IcDate:JOYCE8r\JcIr\JSSRIr\JGDATE:12/14/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-36Sampler(s):H.Seaton/G.EllerProposedexpansionarea,downhillfromGP-2WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:-feetGallonsTimeTemp(°C)p11(s.u.)Cond.DOORPTurb.Initials(IIS/cm)(mg/L)(mV)(NTU)0110$15.55.852211.1938.06.04US1.9111015.85.882242.0430.78.28HS3.8111315.65.912322.8720.610.70HS5.7111615.65.972412.6813.913.61HSBeforeSampling111615.65.972412.6813.913.61USComments(weatherconditions,odor,color,silt,etc.):temnerafuresinthe 40son12/14/2016Theweatherwassunnywith
DATE:12/14/20162inches44.95feet74.50feet29.55feet[DTB-DTW]=4.8gallons=_____________gallons=14.4gallons14.4gallonsJOYCESI\JGIC’.JSSRIt’JGGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-38Sampler(s):H.Seaton/G.EllerProposedExpansionArea.SouthofPZ-36WellLocation:WellDiameter:Initial DepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:--feetGallonsTimeTemp(°C)pH(s.u.)Cond.DOORPTurb.Initials(.tS/cm)(mg/L)(mV)(NTU)0082015.26.384006.58-30.74.82GE4.8082415.16.224001.28-35.66.55GE9.6082815.36.625331.58-33.58.81GE14.4083415.16.705220.92-33.613.47GEBeforeSampling083415.16.705220.92 -33.613.47GEComments(weatherconditions,odor,color,silt, etc.):Theweatherwassunnywithtemoeraturesinthe40son12/14/2016.Signature:QAI
QC
Si
g
n
Off:__
__
_
__
_
__
_
__
__
_
__Date:Date:)//?/J7
DATE:12/14/2016JOYCE__________srJGIr\JsERIrJGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:SMP-5Sampler(s):G.Eller/H.SeatonLocation:downroadtoriver,rightatforkinroadbesidebarnfieldParameters:TimeofSampling:1320pH:7.40Temperature:11.5(°C)Conductivity:118.7(jiS/cm)Turbidity:30.4(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwasunnywithtemperaturesinthe40son12/14/2016.Signature:______________________________Date:—IQA/QCSignOff:AVDate://i/i7
DATE:12/14/2016JOYCE__________Ef\JGICJ8RIPJGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:$MP-6Sampler(s):G.Eller/H.$eatonLocation:downhillfrombetweenMW-12&MW-13tostreamFieldParameters:TimeofSampling:1145pH:6.69Temperature:10.7(°C)Conductivity:81(p.S/cm)Turbidity:14.43(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwassunnywithtemperaturesinthe40son12/14/2016.Date:12.riLfr(4.i
DATE:12/14/2016JOYCE__________IrJERIC’JGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:$MP-7Sampler(s):G.EllenH.SeatonLocation:UpstreamfromPZ-12FieldParameters:TimeofSampling:1005pH:6.32Temperature:8.9(°C)Conductivity:25(jiS/cm)Turbidity:10.15(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwassunnywithtemperaturesinthe40son12/14/2016.FIELDBLANK(1430I—Kf-tC1///7

Appendix B

Laboratory Analytical Reports

#=CL#
January 03, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323296
92323296
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE CO. JOHNS R BACKGROUND
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 46
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Page 2 of 46
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID Matrix Date Collected Date Received
92323296001 1203-MW21 Water 12/13/16 12:45 12/14/16 10:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Page 3 of 46
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323296001 1203-MW21 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 110 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 46
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323296001 1203-MW21
Barium 13.4J ug/L 12/23/16 06:15100EPA 6010
Copper 4.1J ug/L 12/23/16 06:1510.0EPA 6010
Iron 2020 ug/L 12/23/16 06:15300EPA 6010
Manganese 48.1J ug/L 12/23/16 06:1550.0EPA 6010
Vanadium 6.8J ug/L 12/23/16 06:1525.0EPA 6010
Alkalinity, Total as CaCO3 1190J ug/L 12/23/16 09:065000SM 2320B
Sulfate 1340J ug/L 12/17/16 21:06250000EPA 300.0
Chloride 1470 ug/L 12/29/16 16:141000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 23:09 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 23:09 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 23:09 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 23:09 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 23:09 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 23:09 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 23:09 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 23:09 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 23:09 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 23:09 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 23:09 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 23:09 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 23:09 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 23:09 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 23:09 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 23:09 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 23:09 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 23:09 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 23:09 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)80 %12/16/16 23:09 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)56 %12/16/16 23:09 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 20:10 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 20:10 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 20:10 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 20:10 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 20:10 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 20:10 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 20:10 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)45 %12/20/16 20:10 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 19:27 94-75-712/19/16 08:400.97 0.23 1
Dinoseb ND ug/L 12/21/16 19:27 88-85-712/19/16 08:400.19 0.059 1
2,4,5-T ND ug/L 12/21/16 19:27 93-76-512/19/16 08:400.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 19:27 93-72-112/19/16 08:400.20 0.050 1
Surrogates
2,4-DCAA (S)94 %12/21/16 19:27 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:22 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:15 7440-38-212/17/16 01:0010.0 2.5 1
Barium 13.4J ug/L 12/23/16 06:15 7440-39-312/17/16 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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Page 6 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 06:15 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:22 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:15 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:15 7440-48-412/17/16 01:0010.0 2.5 1
Copper 4.1J ug/L 12/23/16 06:15 7440-50-812/17/16 01:0010.0 2.5 1
Iron 2020 ug/L 12/23/16 06:15 7439-89-612/17/16 01:00300 25.0 1
Lead ND ug/L 12/23/16 21:22 7439-92-112/17/16 01:0010.0 2.5 1
Manganese 48.1J ug/L 12/23/16 06:15 7439-96-512/17/16 01:0050.0 2.5 1
Nickel ND ug/L 12/23/16 21:22 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:15 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:15 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:15 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:15 7440-31-512/17/16 01:00100 2.5 1
Vanadium 6.8J ug/L 12/23/16 06:15 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:15 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:49 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/23/16 11:30 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/23/16 11:30 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/23/16 11:30 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/23/16 11:30 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/23/16 11:30 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/23/16 11:30 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/23/16 11:30 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/23/16 11:30 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/23/16 11:30 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/23/16 11:30 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/23/16 11:30 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/23/16 11:30 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/23/16 11:30 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/23/16 11:30 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/23/16 11:30 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/23/16 11:30 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/23/16 11:30 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/23/16 11:30 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/23/16 11:30 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/23/16 11:30 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/23/16 11:30 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/23/16 11:30 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/23/16 11:30 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/23/16 11:30 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/23/16 11:30 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/23/16 11:30 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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Page 7 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/23/16 11:30 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/23/16 11:30 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/23/16 11:30 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/23/16 11:30 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/23/16 11:30 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/23/16 11:30 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/23/16 11:30 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/23/16 11:30 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/23/16 11:30 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/23/16 11:30 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/23/16 11:30 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/23/16 11:30 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/23/16 11:30 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/23/16 11:30 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/23/16 11:30 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/23/16 11:30 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/23/16 11:30 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/23/16 11:30 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/23/16 11:30 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/23/16 11:30 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/23/16 11:30 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/23/16 11:30 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/23/16 11:30 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/23/16 11:30 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/23/16 11:30 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/23/16 11:30 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/23/16 11:30 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/23/16 11:30 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/23/16 11:30 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/23/16 11:30 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/23/16 11:30 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/23/16 11:30 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/23/16 11:30 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/23/16 11:30 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/23/16 11:30 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/23/16 11:30 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/23/16 11:30 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/23/16 11:30 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/23/16 11:30 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/23/16 11:3012/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/23/16 11:30 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/23/16 11:30 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/23/16 11:30 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/23/16 11:30 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/23/16 11:30 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/23/16 11:30 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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[phone]
Page 8 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/23/16 11:30 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/23/16 11:30 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/23/16 11:30 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/23/16 11:30 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/23/16 11:30 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/23/16 11:30 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/23/16 11:30 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/23/16 11:30 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/23/16 11:30 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/23/16 11:30 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/23/16 11:30 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/23/16 11:30 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/23/16 11:30 126-68-112/20/16 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/23/16 11:30 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/23/16 11:30 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/23/16 11:30 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/23/16 11:30 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/23/16 11:30 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/23/16 11:30 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/23/16 11:3012/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/23/16 11:30 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/23/16 11:30 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/23/16 11:30 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/23/16 11:30 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/23/16 11:30 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/23/16 11:30 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/23/16 11:30 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/23/16 11:30 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/23/16 11:30 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/23/16 11:30 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/23/16 11:30 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/23/16 11:30 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)39 %12/23/16 11:30 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)37 %12/23/16 11:30 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)86 %12/23/16 11:30 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)18 %12/23/16 11:30 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)21 %12/23/16 11:30 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)60 %12/23/16 11:30 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 06:59 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 06:59 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 06:59 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 06:59 107-13-1200 1.9 1
Allyl chloride ND ug/L 12/16/16 06:59 107-05-110.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 9 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/16/16 06:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 06:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 06:59 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 06:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 06:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 06:59 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 06:59 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 06:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/16/16 06:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 06:59 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 06:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 06:59 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 06:59 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 06:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 06:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 06:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 06:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 06:59 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 06:59 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/16/16 06:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 06:59 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/16/16 06:59 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/16/16 06:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/16/16 06:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 06:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/16/16 06:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 06:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 06:59 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 06:59 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 06:59 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 06:59 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 06:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 06:59 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 06:59 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 06:59 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 06:59 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 06:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 06:59 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 06:59 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 06:59 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/16/16 06:59 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 06:59 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 06:59 108-10-1100 0.33 1
Naphthalene ND ug/L 12/16/16 06:59 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 06:59 107-12-0150 3.6 1
Styrene ND ug/L 12/16/16 06:59 100-42-51.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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Page 10 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 06:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 06:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 06:59 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 06:59 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 06:59 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 06:59 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 06:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 06:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/16/16 06:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 06:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 06:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 06:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 06:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 06:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/16/16 06:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 06:59 17060-07-070-130 1
Toluene-d8 (S)99 %12/16/16 06:59 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 1190J ug/L 12/23/16 09:065000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/18/16 20:1625000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:30 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1340J ug/L 12/17/16 21:06 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1470 ug/L 12/29/16 16:14 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:36 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340994
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891549
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/20/16 05:170.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891550LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991014
1891552
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 102 75-125103 2 252.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Iron ug/L ND 300 12/23/16 05:1125.0
Lead ug/L ND 10.0 12/23/16 05:112.5
Manganese ug/L ND 50.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Iron ug/L 44805000 90 80-120
Lead ug/L 426500 85 80-120
Manganese ug/L 442500 88 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Iron ug/L 5000 80 75-12584 5 255000ND4010 4220
Lead ug/L 500 99 75-125103 3 25500ND497 514
Manganese ug/L 500 79 75-12584 6 25500ND395 419
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386 411
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341133
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892566
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/15/16 23:350.33
1,1,1-Trichloroethane ug/L ND 1.0 12/15/16 23:350.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/15/16 23:350.40
1,1,2-Trichloroethane ug/L ND 1.0 12/15/16 23:350.29
1,1-Dichloroethane ug/L ND 5.0 12/15/16 23:350.32
1,1-Dichloroethene ug/L ND 5.0 12/15/16 23:350.56
1,1-Dichloropropene ug/L ND 5.0 12/15/16 23:350.49
1,2,3-Trichloropropane ug/L ND 1.0 12/15/16 23:350.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/15/16 23:350.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/15/16 23:352.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/15/16 23:350.27
1,2-Dichlorobenzene ug/L ND 5.0 12/15/16 23:350.30
1,2-Dichloroethane ug/L ND 1.0 12/15/16 23:350.24
1,2-Dichloropropane ug/L ND 1.0 12/15/16 23:350.27
1,3-Dichlorobenzene ug/L ND 5.0 12/15/16 23:350.24
1,3-Dichloropropane ug/L ND 1.0 12/15/16 23:350.28
1,4-Dichlorobenzene ug/L ND 1.0 12/15/16 23:350.33
2,2-Dichloropropane ug/L ND 15.0 12/15/16 23:350.13
2-Butanone (MEK)ug/L ND 100 12/15/16 23:350.96
2-Hexanone ug/L ND 50.0 12/15/16 23:350.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/15/16 23:350.33
Acetone ug/L ND 100 12/15/16 23:3510.0
Acetonitrile ug/L ND 55.0 12/15/16 23:352.2
Acrolein ug/L ND 53.0 12/15/16 23:351.6
Acrylonitrile ug/L ND 200 12/15/16 23:351.9
Allyl chloride ug/L ND 10.0 12/15/16 23:351.5
Benzene ug/L ND 1.0 12/15/16 23:350.25
Bromochloromethane ug/L ND 3.0 12/15/16 23:350.17
Bromodichloromethane ug/L ND 1.0 12/15/16 23:350.18
Bromoform ug/L ND 3.0 12/15/16 23:350.26
Bromomethane ug/L ND 10.0 12/15/16 23:350.29
Carbon disulfide ug/L ND 100 12/15/16 23:351.2
Carbon tetrachloride ug/L ND 1.0 12/15/16 23:350.25
Chlorobenzene ug/L ND 3.0 12/15/16 23:350.23
Chloroethane ug/L ND 10.0 12/15/16 23:350.54
Chloroform ug/L ND 5.0 12/15/16 23:350.14
Chloromethane ug/L ND 1.0 12/15/16 23:350.11
Chloroprene ug/L ND 20.0 12/15/16 23:350.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:350.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:350.13
Dibromochloromethane ug/L ND 3.0 12/15/16 23:350.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892566
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/15/16 23:350.21
Dichlorodifluoromethane ug/L ND 5.0 12/15/16 23:350.21
Ethyl methacrylate ug/L ND 10.0 12/15/16 23:350.20
Ethylbenzene ug/L ND 1.0 12/15/16 23:350.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/15/16 23:350.71
Iodomethane ug/L ND 10.0 12/15/16 23:350.32
Isobutanol ug/L ND 100 12/15/16 23:3535.0
Methacrylonitrile ug/L ND 100 12/15/16 23:350.93
Methyl methacrylate ug/L ND 30.0 12/15/16 23:352.0
Methylene Chloride ug/L ND 1.0 12/15/16 23:350.97
Naphthalene ug/L ND 10.0 12/15/16 23:350.24
Propionitrile ug/L ND 150 12/15/16 23:353.6
Styrene ug/L ND 1.0 12/15/16 23:350.26
Tetrachloroethene ug/L ND 1.0 12/15/16 23:350.46
Tetrahydrofuran ug/L ND 10.0 12/15/16 23:353.1
Toluene ug/L ND 1.0 12/15/16 23:350.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:350.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:350.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/15/16 23:351.0
Trichloroethene ug/L ND 1.0 12/15/16 23:350.47
Trichlorofluoromethane ug/L ND 1.0 12/15/16 23:350.20
Vinyl acetate ug/L ND 50.0 12/15/16 23:350.35
Vinyl chloride ug/L ND 1.0 12/15/16 23:350.62
Xylene (Total)ug/L ND 5.0 12/15/16 23:350.66
1,2-Dichloroethane-d4 (S)%101 70-130 12/15/16 23:35
4-Bromofluorobenzene (S)%95 70-130 12/15/16 23:35
Toluene-d8 (S)%101 70-130 12/15/16 23:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.550 93 80-125
1,1,1-Trichloroethane ug/L 48.950 98 71-129
1,1,2,2-Tetrachloroethane ug/L 47.750 95 79-124
1,1,2-Trichloroethane ug/L 48.650 97 85-125
1,1-Dichloroethane ug/L 51.750 103 73-126
1,1-Dichloroethene ug/L 54.350 109 66-135
1,1-Dichloropropene ug/L 52.950 106 74-135
1,2,3-Trichloropropane ug/L 46.150 92 75-130
1,2,4-Trichlorobenzene ug/L 48.850 98 75-134
1,2-Dibromo-3-chloropropane ug/L 46.450 93 71-133
1,2-Dibromoethane (EDB)ug/L 46.550 93 83-124
1,2-Dichlorobenzene ug/L 47.950 96 80-133
1,2-Dichloroethane ug/L 46.250 92 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 50.750 101 75-132
1,3-Dichlorobenzene ug/L 47.150 94 77-130
1,3-Dichloropropane ug/L 49.650 99 76-131
1,4-Dichlorobenzene ug/L 46.650 93 78-130
2,2-Dichloropropane ug/L 48.250 96 40-160
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 99.3J100 99 48-146
Acetonitrile ug/L 560500 112 62-150
Acrolein ug/L 327250 131 24-160
Acrylonitrile ug/L 280250 112 40-160
Allyl chloride ug/L 52.650 105 66-137
Benzene ug/L 50.450 101 80-125
Bromochloromethane ug/L 50.950 102 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 44.050 88 71-128
Bromomethane ug/L 43.350 87 40-160
Carbon disulfide ug/L 58.6J50 117 50-160
Carbon tetrachloride ug/L 44.950 90 69-131
Chlorobenzene ug/L 47.550 95 81-122
Chloroethane ug/L 52.950 106 39-148
Chloroform ug/L 49.050 98 73-127
Chloromethane ug/L 52.350 105 44-146
Chloroprene ug/L 50.850 102 75-145
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 49.150 98 72-132
Dibromochloromethane ug/L 47.050 94 78-125
Dibromomethane ug/L 45.150 90 82-120
Dichlorodifluoromethane ug/L 45.150 90 34-157
Ethyl methacrylate ug/L 51.850 104 82-121
Ethylbenzene ug/L 47.650 95 79-121
Hexachloro-1,3-butadiene ug/L 50.050 100 72-131
Iodomethane ug/L 100100 100 39-154
Isobutanol ug/L 9871000 99 34-160
Methacrylonitrile ug/L 519500 104 74-134
Methyl methacrylate ug/L 51.550 103 84-124
Methylene Chloride ug/L 51.650 103 64-133
Naphthalene ug/L 47.750 95 73-133
Propionitrile ug/L 535500 107 73-140
Styrene ug/L 48.350 97 84-126
Tetrachloroethene ug/L 42.750 85 78-122
Tetrahydrofuran ug/L 564500 113 69-148
Toluene ug/L 48.450 97 80-121
trans-1,2-Dichloroethene ug/L 54.150 108 71-127
trans-1,3-Dichloropropene ug/L 49.050 98 69-141
trans-1,4-Dichloro-2-butene ug/L 45.7J50 91 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 17 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 46.250 92 78-122
Trichlorofluoromethane ug/L 52.950 106 53-137
Vinyl acetate ug/L 109100 109 40-160
Vinyl chloride ug/L 44.450 89 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892568MATRIX SPIKE SAMPLE:
MSSpike
Result
92323289008
1,1,1,2-Tetrachloroethane ug/L 14.220 71 70-130ND
1,1,1-Trichloroethane ug/L 15.720 79 70-130ND
1,1,2,2-Tetrachloroethane ug/L 14.620 73 70-130ND
1,1,2-Trichloroethane ug/L 15.120 76 70-130ND
1,1-Dichloroethane ug/L 16.420 82 70-130ND
1,1-Dichloroethene ug/L 18.020 90 70-166ND
1,1-Dichloropropene ug/L 17.220 86 70-130ND
1,2,3-Trichloropropane ug/L 13.920 70 70-130ND
1,2,4-Trichlorobenzene ug/L 13.920 70 70-130ND
1,2-Dibromo-3-chloropropane ug/L 14.020 70 70-130ND
1,2-Dibromoethane (EDB)ug/L 14.220 71 70-130ND
1,2-Dichlorobenzene ug/L 14.720 74 70-130ND
1,2-Dichloroethane ug/L 15.020 75 70-130ND
1,2-Dichloropropane ug/L 16.320 82 70-130ND
1,3-Dichlorobenzene ug/L 14.820 74 70-130ND
1,3-Dichloropropane ug/L 15.220 76 70-130ND
1,4-Dichlorobenzene ug/L 14.820 74 70-130ND
2,2-Dichloropropane ug/L 14.0J20 70 70-130ND
2-Butanone (MEK)ug/L 32.2J40 80 70-130ND
2-Hexanone ug/L 30.3J40 76 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 30.6J40 77 70-130ND
Acetone ug/L 28.7J40 72 70-130ND
Acetonitrile ug/L 178200 89 70-130ND
Acrolein ug/L 88.0100 88 70-130ND
Acrylonitrile ug/L 86.0J100 86 70-130ND
Allyl chloride ug/L 16.620 83 70-130ND
Benzene ug/L 16.120 81 70-148ND
Bromochloromethane ug/L 15.720 78 70-130ND
Bromodichloromethane ug/L 15.220 76 70-130ND
Bromoform ug/L 13.2 M12066 70-130ND
Bromomethane ug/L 14.220 71 70-130ND
Carbon disulfide ug/L 19.4J20 97 70-130ND
Carbon tetrachloride ug/L 15.320 77 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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[phone]
Page 18 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892568MATRIX SPIKE SAMPLE:
MSSpike
Result
92323289008
Chlorobenzene ug/L 15.220 76 70-146ND
Chloroethane ug/L 18.120 90 70-130ND
Chloroform ug/L 16.420 82 70-130ND
Chloromethane ug/L 17.120 86 70-130ND
Chloroprene ug/L 16.7J20 83 70-130ND
cis-1,2-Dichloroethene ug/L 16.820 84 70-130ND
cis-1,3-Dichloropropene ug/L 14.220 71 70-130ND
Dibromochloromethane ug/L 14.020 70 70-130ND
Dibromomethane ug/L 14.420 72 70-130ND
Dichlorodifluoromethane ug/L 16.120 81 70-130ND
Ethyl methacrylate ug/L 15.120 75 70-130ND
Ethylbenzene ug/L 15.420 77 70-130ND
Hexachloro-1,3-butadiene ug/L 14.720 73 70-130ND
Iodomethane ug/L 29.340 73 70-130ND
Isobutanol ug/L 282400 70 70-130ND
Methacrylonitrile ug/L 164200 82 70-130ND
Methyl methacrylate ug/L 15.0J20 75 70-130ND
Methylene Chloride ug/L 15.720 78 70-130ND
Naphthalene ug/L 13.1 M12065 70-130ND
Propionitrile ug/L 168200 84 70-130ND
Styrene ug/L 14.720 73 70-130ND
Tetrachloroethene ug/L 14.120 71 70-130ND
Tetrahydrofuran ug/L 173200 87 70-130ND
Toluene ug/L 15.720 78 70-155ND
trans-1,2-Dichloroethene ug/L 17.520 87 70-130ND
trans-1,3-Dichloropropene ug/L 14.020 70 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.3J M12056 70-130ND
Trichloroethene ug/L 15.320 76 69-151ND
Trichlorofluoromethane ug/L 18.120 90 70-130ND
Vinyl acetate ug/L 24.6J M14061 70-130ND
Vinyl chloride ug/L 15.420 77 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 19 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%104 2101
4-Bromofluorobenzene (S)%95 095
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341110
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892410
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDE ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDT ug/L ND 0.10 12/16/16 12:470.050
Aldrin ug/L ND 0.050 12/16/16 12:470.050
alpha-BHC ug/L ND 0.050 12/16/16 12:470.050
beta-BHC ug/L ND 0.050 12/16/16 12:470.050
Chlordane (Technical)ug/L ND 0.50 12/16/16 12:470.20
delta-BHC ug/L ND 0.050 12/16/16 12:470.050
Dieldrin ug/L ND 0.075 12/16/16 12:470.050
Endosulfan I ug/L ND 0.10 12/16/16 12:470.050
Endosulfan II ug/L ND 0.10 12/16/16 12:470.050
Endosulfan sulfate ug/L ND 0.10 12/16/16 12:470.050
Endrin ug/L ND 0.10 12/16/16 12:470.050
Endrin aldehyde ug/L ND 0.10 12/16/16 12:470.050
gamma-BHC (Lindane)ug/L ND 0.050 12/16/16 12:470.050
Heptachlor ug/L ND 0.050 12/16/16 12:470.050
Heptachlor epoxide ug/L ND 0.075 12/16/16 12:470.050
Methoxychlor ug/L ND 1.0 12/16/16 12:470.15
Toxaphene ug/L ND 1.5 12/16/16 12:470.20
Decachlorobiphenyl (S)%108 20-130 12/16/16 12:47
Tetrachloro-m-xylene (S)%97 20-130 12/16/16 12:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.25.25 99 20-150
4,4'-DDE ug/L 0.23.25 92 20-150
4,4'-DDT ug/L 0.25.25 99 20-150
Aldrin ug/L 0.19.25 78 20-150
alpha-BHC ug/L 0.22.25 90 20-150
beta-BHC ug/L 0.24.25 96 20-150
delta-BHC ug/L 0.24.25 98 20-150
Dieldrin ug/L 0.24.25 96 20-150
Endosulfan I ug/L 0.25.25 102 20-150
Endosulfan II ug/L 0.26.25 107 20-150
Endosulfan sulfate ug/L 0.27.25 109 20-150
Endrin ug/L 0.27.25 108 20-150
Endrin aldehyde ug/L 0.24.25 96 20-150
gamma-BHC (Lindane)ug/L 0.23.25 91 20-150
Heptachlor ug/L 0.20.25 82 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 22 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 94 20-150
Methoxychlor ug/L 0.87J.74 117 20-150
Decachlorobiphenyl (S)%99 20-130
Tetrachloro-m-xylene (S)%89 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892412MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1892413
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 92 20-15087 6 30.5ND 0.46 0.43
4,4'-DDE ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
4,4'-DDT ug/L .5 93 20-15086 8 30.5ND 0.46 0.42
Aldrin ug/L .5 80 20-15083 4 30.5ND 0.39 0.41
alpha-BHC ug/L .5 88 20-15086 2 30.5ND 0.43 0.42
beta-BHC ug/L .5 96 20-15092 4 30.5ND 0.48 0.46
delta-BHC ug/L .5 102 20-15098 5 30.5ND 0.51 0.48
Dieldrin ug/L .5 89 20-15085 5 30.5ND 0.44 0.42
Endosulfan I ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
Endosulfan II ug/L .5 98 20-15095 4 30.5ND 0.49 0.47
Endosulfan sulfate ug/L .5 101 20-15096 5 30.5ND 0.50 0.48
Endrin ug/L .5 95 20-15090 5 30.5ND 0.47 0.45
Endrin aldehyde ug/L .5 82 20-15082 0 30.5ND 0.41 0.41
gamma-BHC (Lindane)ug/L .5 92 20-15088 4 30.5ND 0.45 0.44
Heptachlor ug/L .5 84 20-15082 2 30.5ND 0.42 0.41
Heptachlor epoxide ug/L .5 93 20-15089 5 30.5ND 0.46 0.44
Methoxychlor ug/L 1.5 105 20-15098 7 301.5ND 1.6J 1.5J
Decachlorobiphenyl (S)%45 20-13045
Tetrachloro-m-xylene (S)%84 20-13085
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341274
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893343
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/19/16 13:170.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/19/16 13:170.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/19/16 13:170.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/19/16 13:170.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/19/16 13:170.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/19/16 13:170.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/19/16 13:170.50
Decachlorobiphenyl (S)%92 10-132 12/19/16 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893344LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1893345
PCB-1016 (Aroclor 1016)ug/L 4.85 95 50-150904.5 6 30
PCB-1260 (Aroclor 1260)ug/L 5.55 111 50-1501035.1 8 30
Decachlorobiphenyl (S)%82 10-13279
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339306
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1820541
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/21/16 10:550.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/21/16 10:550.049
2,4-D ug/L ND 0.94 12/21/16 10:550.22
Dinoseb ug/L ND 0.19 12/21/16 10:550.057
2,4-DCAA (S)%86 39-139 12/21/16 10:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1820542LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 1.31.2 106 37-133
2,4,5-TP (Silvex)ug/L 1.01.2 87 53-134
2,4-D ug/L 6.16 102 35-124
Dinoseb ug/L 0.971.2 81 13-116
2,4-DCAA (S)%87 39-139
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1820630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1820631
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 118 37-133114 3 401.2ND 1.4 1.4
2,4,5-TP (Silvex)ug/L 1.2 99 53-13495 3 401.2ND 1.2 1.1
2,4-D ug/L 6 114 35-124111 1 406ND6.8 6.7
Dinoseb ug/L 1.2 89 13-11685 4 401.2ND 1.1 1.0
2,4-DCAA (S)%94 39-13993 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341825
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/22/16 10:331.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/22/16 10:331.1
1,3-Dinitrobenzene ug/L ND 20.0 12/22/16 10:331.5
1,4-Naphthoquinone ug/L ND 10.0 12/22/16 10:331.8
1-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/22/16 10:332.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/22/16 10:332.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/22/16 10:331.9
2,4-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.7
2,4-Dimethylphenol ug/L ND 10.0 12/22/16 10:332.2
2,4-Dinitrophenol ug/L ND 50.0 12/22/16 10:336.5
2,4-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.2
2,6-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.8
2,6-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.7
2-Acetylaminofluorene ug/L ND 20.0 12/22/16 10:330.84
2-Chloronaphthalene ug/L ND 10.0 12/22/16 10:332.2
2-Chlorophenol ug/L ND 10.0 12/22/16 10:331.5
2-Methylnaphthalene ug/L ND 10.0 12/22/16 10:330.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/22/16 10:331.7
2-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.98
2-Nitroaniline ug/L ND 50.0 12/22/16 10:332.8
2-Nitrophenol ug/L ND 10.0 12/22/16 10:331.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/22/16 10:331.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/22/16 10:331.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/22/16 10:332.1
3-Methylcholanthrene ug/L ND 10.0 12/22/16 10:330.82
3-Nitroaniline ug/L ND 50.0 12/22/16 10:332.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/22/16 10:331.7
4-Aminobiphenyl ug/L ND 20.0 12/22/16 10:330.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/22/16 10:331.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/22/16 10:334.2
4-Chloroaniline ug/L ND 20.0 12/22/16 10:333.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/22/16 10:332.1
4-Nitroaniline ug/L ND 20.0 12/22/16 10:332.5
4-Nitrophenol ug/L ND 50.0 12/22/16 10:335.8
5-Nitro-o-toluidine ug/L ND 10.0 12/22/16 10:331.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/22/16 10:330.77
Acenaphthene ug/L ND 10.0 12/22/16 10:330.25
Acenaphthylene ug/L ND 10.0 12/22/16 10:330.21
Acetophenone ug/L ND 10.0 12/22/16 10:332.0
Anthracene ug/L ND 10.0 12/22/16 10:330.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 26 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 12/22/16 10:330.33
Benzo(a)pyrene ug/L ND 10.0 12/22/16 10:330.30
Benzo(b)fluoranthene ug/L ND 10.0 12/22/16 10:330.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/22/16 10:330.38
Benzo(k)fluoranthene ug/L ND 10.0 12/22/16 10:330.43
Benzyl alcohol ug/L ND 20.0 12/22/16 10:333.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/22/16 10:331.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/22/16 10:331.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/22/16 10:330.85
Butylbenzylphthalate ug/L ND 10.0 12/22/16 10:330.75
Chlorobenzilate ug/L ND 10.0 12/22/16 10:330.72
Chrysene ug/L ND 10.0 12/22/16 10:330.21
Di-n-butylphthalate ug/L ND 10.0 12/22/16 10:331.1
Di-n-octylphthalate ug/L ND 10.0 12/22/16 10:330.86
Diallate ug/L ND 10.0 12/22/16 10:331.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/22/16 10:330.55
Dibenzofuran ug/L ND 10.0 12/22/16 10:331.8
Diethylphthalate ug/L ND 6000 12/22/16 10:331.3
Dimethoate ug/L ND 20.0 12/22/16 10:330.92
Dimethylphthalate ug/L ND 10.0 12/22/16 10:331.5
Diphenylamine ug/L ND 10.0 12/22/16 10:331.3
Disulfoton ug/L ND 10.0 12/22/16 10:331.4
Ethyl methanesulfonate ug/L ND 20.0 12/22/16 10:331.8
Famphur ug/L ND 20.0 12/22/16 10:331.7
Fluoranthene ug/L ND 10.0 12/22/16 10:330.21
Fluorene ug/L ND 10.0 12/22/16 10:330.21
Hexachlorobenzene ug/L ND 10.0 12/22/16 10:331.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/22/16 10:331.8
Hexachloroethane ug/L ND 10.0 12/22/16 10:331.5
Hexachloropropene ug/L ND 10.0 12/22/16 10:331.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/22/16 10:330.29
Isodrin ug/L ND 20.0 12/22/16 10:332.0
Isophorone ug/L ND 10.0 12/22/16 10:331.8
Isosafrole ug/L ND 10.0 12/22/16 10:331.8
Kepone ug/L ND 20.0 12/22/16 10:333.1
Methapyrilene ug/L ND 100 12/22/16 10:332.7
Methyl methanesulfonate ug/L ND 10.0 12/22/16 10:331.3
Methyl parathion ug/L ND 10.0 12/22/16 10:331.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/22/16 10:332.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/22/16 10:332.1
N-Nitrosodiethylamine ug/L ND 20.0 12/22/16 10:331.8
N-Nitrosodimethylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/22/16 10:331.8
N-Nitrosopiperidine ug/L ND 20.0 12/22/16 10:331.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
N-Nitrosopyrrolidine ug/L ND 10.0 12/22/16 10:332.5
Nitrobenzene ug/L ND 10.0 12/22/16 10:331.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/22/16 10:331.8
O-Toluidine ug/L ND 10.0 12/22/16 10:331.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/22/16 10:330.35
p-Phenylenediamine ug/L ND 10.0 12/22/16 10:330.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/22/16 10:331.1
Pentachlorobenzene ug/L ND 10.0 12/22/16 10:332.0
Pentachloronitrobenzene ug/L ND 20.0 12/22/16 10:331.0
Pentachlorophenol ug/L ND 25.0 12/22/16 10:332.3
Phenacetin ug/L ND 20.0 12/22/16 10:330.97
Phenanthrene ug/L ND 10.0 12/22/16 10:330.22
Phenol ug/L ND 10.0 12/22/16 10:331.7
Phorate ug/L ND 10.0 12/22/16 10:331.1
Pronamide ug/L ND 10.0 12/22/16 10:330.97
Pyrene ug/L ND 10.0 12/22/16 10:330.19
Safrole ug/L ND 10.0 12/22/16 10:331.5
Thionazin ug/L ND 20.0 12/22/16 10:331.2
2,4,6-Tribromophenol (S)%70 27-110 12/22/16 10:33
2-Fluorobiphenyl (S)%54 27-110 12/22/16 10:33
2-Fluorophenol (S)%26 12-110 12/22/16 10:33
Nitrobenzene-d5 (S)%50 21-110 12/22/16 10:33
Phenol-d6 (S)%23 10-110 12/22/16 10:33
Terphenyl-d14 (S)%71 31-107 12/22/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 33.650 67 16-129
1,3,5-Trinitrobenzene ug/L 43.250 86 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 37.450 75 31-120
1-Naphthalenamine ug/L 24.050 48 37-126
2,3,4,6-Tetrachlorophenol ug/L 56.550 113 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 41.050 82 42-120
2,4-Dichlorophenol ug/L 38.450 77 30-120
2,4-Dimethylphenol ug/L 38.750 77 29-111
2,4-Dinitrophenol ug/L 123250 49 19-132
2,4-Dinitrotoluene ug/L 42.350 85 58-128
2,6-Dichlorophenol ug/L 42.550 85 54-128
2,6-Dinitrotoluene ug/L 42.850 86 54-129
2-Acetylaminofluorene ug/L 43.750 87 81-160
2-Chloronaphthalene ug/L 41.150 82 43-117
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorophenol ug/L 36.050 72 37-120
2-Methylnaphthalene ug/L 37.550 75 33-120
2-Methylphenol(o-Cresol)ug/L 25.350 51 31-120
2-Naphthalenamine ug/L 36.650 73 41-136
2-Nitroaniline ug/L 68.5100 69 48-121
2-Nitrophenol ug/L 37.350 75 25-116
3&4-Methylphenol(m&p Cresol)ug/L 38.850 78 23-120
3,3'-Dichlorobenzidine ug/L 86.0250 34 10-154
3,3'-Dimethylbenzidine ug/L 62.6100 63 10-157
3-Methylcholanthrene ug/L 47.750 95 65-130
3-Nitroaniline ug/L 82.5100 83 43-115
4,6-Dinitro-2-methylphenol ug/L 89.5100 89 44-124
4-Aminobiphenyl ug/L 33.650 67 21-125
4-Bromophenylphenyl ether ug/L 37.950 76 34-113
4-Chloro-3-methylphenol ug/L 73.5100 73 31-110
4-Chloroaniline ug/L 67.3100 67 20-120
4-Chlorophenylphenyl ether ug/L 37.750 75 34-116
4-Nitroaniline ug/L 89.4100 89 46-128
4-Nitrophenol ug/L 76.4250 31 11-120
5-Nitro-o-toluidine ug/L 42.150 84 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.250 94 47-124
Acenaphthene ug/L 39.450 79 48-114
Acenaphthylene ug/L 40.750 81 48-112
Acetophenone ug/L 32.650 65 24-120
Anthracene ug/L 41.650 83 57-118
Benzo(a)anthracene ug/L 41.350 83 56-121
Benzo(a)pyrene ug/L 45.750 91 55-127
Benzo(b)fluoranthene ug/L 44.150 88 53-128
Benzo(g,h,i)perylene ug/L 45.950 92 54-125
Benzo(k)fluoranthene ug/L 46.850 94 51-123
Benzyl alcohol ug/L 57.5100 57 27-120
bis(2-Chloroethoxy)methane ug/L 35.650 71 32-120
bis(2-Chloroethyl) ether ug/L 36.450 73 33-111
bis(2-Ethylhexyl)phthalate ug/L 48.250 96 50-145
Butylbenzylphthalate ug/L 47.650 95 54-138
Chlorobenzilate ug/L 45.250 90 65-132
Chrysene ug/L 41.350 83 58-127
Di-n-butylphthalate ug/L 47.250 94 56-125
Di-n-octylphthalate ug/L 49.350 99 50-134
Diallate ug/L 48.250 96 47-123
Dibenz(a,h)anthracene ug/L 47.150 94 53-129
Dibenzofuran ug/L 39.650 79 45-120
Diethylphthalate ug/L 43.4J50 87 53-120
Dimethoate ug/L 50.850 102 57-139
Dimethylphthalate ug/L 41.150 82 55-116
Diphenylamine ug/L 42.350 85 42-120
Disulfoton ug/L 50.050 100 49-156
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Ethyl methanesulfonate ug/L 38.250 76 43-120
Famphur ug/L 45.6100 46 40-160
Fluoranthene ug/L 45.450 91 57-125
Fluorene ug/L 41.450 83 53-118
Hexachlorobenzene ug/L 39.850 80 49-116
Hexachlorocyclopentadiene ug/L 34.350 69 26-158
Hexachloroethane ug/L 29.350 59 30-114
Hexachloropropene ug/L 33.350 67 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.650 95 55-128
Isodrin ug/L 46.450 93 68-129
Isophorone ug/L 35.550 71 31-118
Isosafrole ug/L 32.650 65 48-107
Kepone ug/L 45.7100 46 10-124
Methapyrilene ug/L 51.7J50 103 40-160
Methyl methanesulfonate ug/L 25.350 51 25-114
Methyl parathion ug/L 51.750 103 58-137
N-Nitroso-di-n-butylamine ug/L 30.850 62 36-115
N-Nitroso-di-n-propylamine ug/L 38.050 76 32-119
N-Nitrosodiethylamine ug/L 38.250 76 47-115
N-Nitrosodimethylamine ug/L 24.850 50 13-120
N-Nitrosodiphenylamine ug/L 42.350 85 43-120
N-Nitrosomethylethylamine ug/L 33.450 67 39-120
N-Nitrosopiperidine ug/L 43.950 88 43-113
N-Nitrosopyrrolidine ug/L 35.650 71 32-110
Nitrobenzene ug/L 33.950 68 33-110
O,O,O-Triethylphosphorothioate ug/L 37.850 76 51-127
O-Toluidine ug/L 33.650 67 27-120
P-Dimethylaminoazobenzene ug/L 19.3100 19 10-120
p-Phenylenediamine ug/L 45.950 92 72-143
Parathion (Ethyl parathion)ug/L 50.750 101 56-140
Pentachlorobenzene ug/L 35.650 71 30-137
Pentachloronitrobenzene ug/L 49.950 100 70-124
Pentachlorophenol ug/L 89.3250 36 10-137
Phenacetin ug/L 46.650 93 60-130
Phenanthrene ug/L 41.150 82 57-117
Phenol ug/L 17.350 35 10-120
Phorate ug/L 51.650 103 55-126
Pronamide ug/L 51.550 103 75-124
Pyrene ug/L 39.350 79 55-122
Safrole ug/L 39.450 79 41-120
Thionazin ug/L 40.050 80 63-137
2,4,6-Tribromophenol (S)%43 27-110
2-Fluorobiphenyl (S)%36 27-110
2-Fluorophenol (S)%20 12-110
Nitrobenzene-d5 (S)%35 21-110
Phenol-d6 (S)%14 10-110
Terphenyl-d14 (S)%38 31-107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
1,2,4,5-Tetrachlorobenzene ug/L 33.050 66 50-150ND
1,3,5-Trinitrobenzene ug/L 48.950 98 50-150ND
1,3-Dinitrobenzene ug/L 40.450 81 50-150ND
1,4-Naphthoquinone ug/L 33.950 68 50-150ND
1-Naphthalenamine ug/L 23.3 M15047 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 38.450 77 50-150ND
2,4,5-Trichlorophenol ug/L 27.650 55 19-105ND
2,4,6-Trichlorophenol ug/L 25.050 50 13-108ND
2,4-Dichlorophenol ug/L 34.450 69 29-111ND
2,4-Dimethylphenol ug/L 36.750 73 21-103ND
2,4-Dinitrophenol ug/L 28.1J250 11 10-109ND
2,4-Dinitrotoluene ug/L 37.650 75 27-104ND
2,6-Dichlorophenol ug/L 33.350 67 50-150ND
2,6-Dinitrotoluene ug/L 41.750 83 28-101ND
2-Acetylaminofluorene ug/L 40.550 81 50-150ND
2-Chloronaphthalene ug/L 43.950 88 14-102ND
2-Chlorophenol ug/L 31.250 62 16-110ND
2-Methylnaphthalene ug/L 39.850 80 13-110ND
2-Methylphenol(o-Cresol)ug/L 22.650 45 19-110ND
2-Naphthalenamine ug/L 30.350 61 50-150ND
2-Nitroaniline ug/L 59.8100 60 26-103ND
2-Nitrophenol ug/L 33.350 67 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 47.650 95 20-110ND
3,3'-Dichlorobenzidine ug/L 82.5250 33 25-112ND
3,3'-Dimethylbenzidine ug/L 53.4100 53 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 75.3100 75 29-110ND
4,6-Dinitro-2-methylphenol ug/L 51.8100 52 10-117ND
4-Aminobiphenyl ug/L 34.950 70 50-150ND
4-Bromophenylphenyl ether ug/L 40.950 82 20-105ND
4-Chloro-3-methylphenol ug/L 64.1100 64 22-110ND
4-Chloroaniline ug/L 66.4100 66 20-100ND
4-Chlorophenylphenyl ether ug/L 41.850 84 19-102ND
4-Nitroaniline ug/L 99.6100 100 29-110ND
4-Nitrophenol ug/L 36.2J250 14 10-110ND
5-Nitro-o-toluidine ug/L 42.950 86 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 43.750 87 50-150ND
Acenaphthene ug/L 38.350 77 17-100ND
Acenaphthylene ug/L 39.650 79 21-100ND
Acetophenone ug/L 30.850 62 50-150ND
Anthracene ug/L 40.550 81 24-109ND
Benzo(a)anthracene ug/L 39.450 79 22-117ND
Benzo(a)pyrene ug/L 42.050 84 23-104ND
Benzo(b)fluoranthene ug/L 41.050 82 23-103ND
Benzo(g,h,i)perylene ug/L 42.350 85 18-111ND
Benzo(k)fluoranthene ug/L 42.750 85 22-113ND
Benzyl alcohol ug/L 48.7100 49 19-101ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
bis(2-Chloroethoxy)methane ug/L 32.350 65 22-110ND
bis(2-Chloroethyl) ether ug/L 33.950 68 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 42.550 85 23-102ND
Butylbenzylphthalate ug/L 41.950 84 25-110ND
Chlorobenzilate ug/L 42.450 84 50-150ND
Chrysene ug/L 39.850 80 23-115ND
Di-n-butylphthalate ug/L 44.150 88 26-110ND
Di-n-octylphthalate ug/L 43.850 88 22-110ND
Diallate ug/L 46.450 93 50-150ND
Dibenz(a,h)anthracene ug/L 41.250 82 21-112ND
Dibenzofuran ug/L 40.450 81 19-102ND
Diethylphthalate ug/L 39.2J50 78 29-110ND
Dimethoate ug/L 50.950 102 50-150ND
Dimethylphthalate ug/L 42.950 86 27-110ND
Diphenylamine ug/L 49.550 99 50-150ND
Disulfoton ug/L 41.050 82 50-150ND
Ethyl methanesulfonate ug/L 34.450 69 50-150ND
Famphur ug/L 51.1100 51 50-150ND
Fluoranthene ug/L 45.150 90 23-112ND
Fluorene ug/L 46.050 92 22-104ND
Hexachlorobenzene ug/L 42.750 85 21-116ND
Hexachlorocyclopentadiene ug/L 33.950 68 10-110ND
Hexachloroethane ug/L 29.550 59 10-110ND
Hexachloropropene ug/L 37.550 75 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 43.150 86 20-113ND
Isodrin ug/L 45.950 92 50-150ND
Isophorone ug/L 31.950 64 50-150ND
Isosafrole ug/L 31.950 64 50-150ND
Kepone ug/L 60.3100 60 50-150ND
Methapyrilene ug/L 46.8J50 94 50-150ND
Methyl methanesulfonate ug/L 26.950 54 50-150ND
Methyl parathion ug/L 46.350 93 50-150ND
N-Nitroso-di-n-butylamine ug/L 30.250 60 50-150ND
N-Nitroso-di-n-propylamine ug/L 32.750 65 21-105ND
N-Nitrosodiethylamine ug/L 43.250 86 50-150ND
N-Nitrosodimethylamine ug/L 23.050 46 10-110ND
N-Nitrosodiphenylamine ug/L 49.550 99 23-107ND
N-Nitrosomethylethylamine ug/L 31.950 64 50-150ND
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.050 62 50-150ND
Nitrobenzene ug/L 28.250 56 20-110ND
O,O,O-Triethylphosphorothioate ug/L 39.250 78 50-150ND
O-Toluidine ug/L 28.750 57 50-150ND
P-Dimethylaminoazobenzene ug/L 18.4 M110018 50-150ND
p-Phenylenediamine ug/L 43.850 88 50-150ND
Parathion (Ethyl parathion)ug/L 45.450 91 50-150ND
Pentachlorobenzene ug/L 34.750 69 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
Pentachloronitrobenzene ug/L 43.150 86 50-150ND
Pentachlorophenol ug/L 32.6250 13 10-118ND
Phenacetin ug/L 45.550 91 50-150ND
Phenanthrene ug/L 41.250 82 24-106ND
Phenol ug/L 14.750 29 12-110ND
Phorate ug/L 46.150 92 50-150ND
Pronamide ug/L 49.050 98 50-150ND
Pyrene ug/L 35.650 71 24-114ND
Safrole ug/L 40.950 82 50-150ND
Thionazin ug/L 42.550 85 50-150ND
2,4,6-Tribromophenol (S)%70 27-110
2-Fluorobiphenyl (S)%75 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%56 21-110
Phenol-d6 (S)%23 10-110
Terphenyl-d14 (S)%68 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%68 169
2-Fluorobiphenyl (S)%58 1165
2-Fluorophenol (S)%22 2227
Nitrobenzene-d5 (S)%51 654
Phenol-d6 (S)%15 1818
Terphenyl-d14 (S)%70 473
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342108
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898057
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/23/16 07:251000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898058LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4510050000 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898059MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323286001
1898060
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12096 1 25500001090J48600 49300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341433
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894510
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/18/16 20:1025000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894511LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 230000250000 92 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323216029
1894512SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 344000 0 5343 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323257005
1894513SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 130000 1 5131000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341249
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893118
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/16/16 13:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893119LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 520J500 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893120MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323296001
1893121
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 96 80-12096 0 10500ND492J 491J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893122MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323316010
1893123
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 92 80-12091 0 10500ND458J 457J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341402
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894399
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/17/16 17:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894400LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238003
1894402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011590-110110 2 102000026.5 mg/L 49500J 48400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1894404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 99 90-11094 5 10200002.1 mg/L 22000J 21000J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342770
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1901305
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 12/29/16 15:53500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1901306LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1970020000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901307MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991013
1901308
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000013490-110136 0 101000066.5 mg/L 79900 80000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901309MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1901310
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 98 90-110101 3 10100001.6 mg/L 11400 11700
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 46
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 46
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323296001 341110 3412291203-MW21 EPA 3510 EPA 8081
92323296001 341274 3414911203-MW21 EPA 3510 EPA 8082
92323296001 339306 3398961203-MW21 EPA 8151 EPA 8151
92323296001 341173 3415711203-MW21 EPA 3010A EPA 6010
92323296001 340994 3413841203-MW21 EPA 7470 EPA 7470
92323296001 341825 3421661203-MW21 EPA 3510 EPA 8270
92323296001 3411331203-MW21 EPA 8260
92323296001 3421081203-MW21 SM 2320B
92323296001 3414331203-MW21 SM 2540C
92323296001 3412491203-MW21 SM 4500-S2D
92323296001 3414021203-MW21 EPA 300.0
92323296001 3427701203-MW21 SM 4500-Cl-E
92323296001 3425331203-MW21 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 46
Page 44 of 46
Page 45 of 46
Page 46 of 46
#=CL#
January 24, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323257
92323257
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
JOHNS R. C&D/MSWLF-COMPL.
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Report revised 1/24/17 to report re-run EPA 6010 Thallium results for 1203-MW11 and 1203-MW12.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 1 of 78
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 78
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Lab ID Sample ID Matrix Date Collected Date Received
92323257001 1203-MW10 Water 12/13/16 12:30 12/14/16 10:24
92323257002 1203-MW11 Water 12/13/16 11:45 12/14/16 10:24
92323257003 1203-MW12 Water 12/13/16 14:10 12/14/16 10:24
92323257004 1203-MW13 Water 12/13/16 14:45 12/14/16 10:24
92323257005 1203-MW16S Water 12/13/16 13:30 12/14/16 10:24
92323257006 1203-MW16D Water 12/13/16 13:30 12/14/16 10:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 3 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323257001 1203-MW10 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
92323257002 1203-MW11 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
92323257003 1203-MW12 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 4 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
92323257004 1203-MW13 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
92323257005 1203-MW16S EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 111 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
92323257006 1203-MW16D EPA 6010 17 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323257001 1203-MW10
Arsenic 3.2J ug/L 12/23/16 01:5210.0EPA 6010
Barium 66.0J ug/L 12/23/16 19:23100EPA 6010
Cobalt 93.2 ug/L 12/23/16 01:5210.0EPA 6010
Iron 17600 ug/L 12/23/16 01:52300EPA 6010
Manganese 5100 ug/L 12/23/16 01:5250.0EPA 6010
Nickel 3.9J ug/L 12/23/16 19:2350.0EPA 6010
Thallium 5.3J ug/L 12/23/16 01:525.5EPA 6010
Zinc 12.8 ug/L 12/23/16 01:5210.0EPA 6010
Mercury 0.25 ug/L 12/20/16 05:020.20EPA 7470
Benzene 1.7 ug/L 12/15/16 23:521.0EPA 8260
Chlorobenzene 0.85J ug/L 12/15/16 23:523.0EPA 8260
1,4-Dichlorobenzene 0.89J ug/L 12/15/16 23:521.0EPA 8260
1,1-Dichloroethane 1.4J ug/L 12/15/16 23:525.0EPA 8260
cis-1,2-Dichloroethene 5.1 ug/L 12/15/16 23:525.0EPA 8260
Trichloroethene 0.52J ug/L 12/15/16 23:521.0EPA 8260
Alkalinity, Total as CaCO3 35700 ug/L 12/23/16 04:545000SM 2320B
Total Dissolved Solids 73000 ug/L 12/18/16 20:1325000SM 2540C
Sulfate 3220J ug/L 12/17/16 18:59250000EPA 300.0
Chloride 9040 ug/L 12/29/16 16:031000SM 4500-Cl-E
92323257002 1203-MW11
beta-BHC 0.12 ug/L 12/16/16 21:590.050EPA 8081
2,4,5-TP (Silvex)0.14J ug/L 12/21/16 20:270.20EPA 8151
Barium 128 ug/L 12/23/16 19:26100EPA 6010
Chromium 3.7J ug/L 12/23/16 01:5510.0EPA 6010
Cobalt 52.4 ug/L 12/23/16 01:5510.0EPA 6010
Iron 67800 ug/L 12/23/16 01:55300EPA 6010
Lead 3.5J ug/L 12/23/16 19:2610.0EPA 6010
Manganese 17900 ug/L 12/23/16 20:07500EPA 6010
Nickel 3.8J ug/L 12/23/16 19:2650.0EPA 6010
Thallium 5.1J ug/L 12/23/16 01:555.5EPA 6010
Zinc 17.6 ug/L 12/23/16 01:5510.0EPA 6010
Benzene 2.3 ug/L 12/16/16 00:091.0EPA 8260
Chlorobenzene 0.48J ug/L 12/16/16 00:093.0EPA 8260
1,2-Dichlorobenzene 0.32J ug/L 12/16/16 00:095.0EPA 8260
1,4-Dichlorobenzene 10.5 ug/L 12/16/16 00:091.0EPA 8260
1,1-Dichloroethane 3.0J ug/L 12/16/16 00:095.0EPA 8260
1,2-Dichloroethane 0.48J ug/L 12/16/16 00:091.0EPA 8260
cis-1,2-Dichloroethene 5.7 ug/L 12/16/16 00:095.0EPA 8260
Trichloroethene 0.56J ug/L 12/16/16 00:091.0EPA 8260
Alkalinity, Total as CaCO3 97700 ug/L 12/23/16 05:115000SM 2320B
Total Dissolved Solids 241000 ug/L 12/18/16 20:1425000SM 2540C
Sulfate 3500J ug/L 12/17/16 19:08250000EPA 300.0
Chloride 35000 ug/L 12/29/16 16:041000SM 4500-Cl-E
92323257003 1203-MW12
Barium 83.2J ug/L 12/23/16 19:29100EPA 6010
Chromium 4.4J ug/L 12/23/16 01:5810.0EPA 6010
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 6 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323257003 1203-MW12
Cobalt 70.6 ug/L 12/23/16 01:5810.0EPA 6010
Iron 45300 ug/L 12/23/16 01:58300EPA 6010
Lead 2.6J ug/L 12/23/16 19:2910.0EPA 6010
Manganese 8850 ug/L 12/23/16 01:5850.0EPA 6010
Nickel 29.7J ug/L 12/23/16 19:2950.0EPA 6010
Zinc 9.7J ug/L 12/23/16 01:5810.0EPA 6010
Benzene 2.8 ug/L 12/16/16 00:261.0EPA 8260
Chlorobenzene 0.63J ug/L 12/16/16 00:263.0EPA 8260
Chloroethane 3.0J ug/L 12/16/16 00:2610.0EPA 8260
1,4-Dichlorobenzene 4.7 ug/L 12/16/16 00:261.0EPA 8260
1,1-Dichloroethane 27.4 ug/L 12/16/16 00:265.0EPA 8260
1,2-Dichloroethane 1.1 ug/L 12/16/16 00:261.0EPA 8260
cis-1,2-Dichloroethene 9.8 ug/L 12/16/16 00:265.0EPA 8260
Trichloroethene 2.1 ug/L 12/16/16 00:261.0EPA 8260
Alkalinity, Total as CaCO3 54100 ug/L 12/23/16 05:325000SM 2320B
Total Dissolved Solids 133000 ug/L 12/18/16 20:1425000SM 2540C
Sulfate 4050J ug/L 12/17/16 19:17250000EPA 300.0
Chloride 7650 ug/L 12/29/16 16:051000SM 4500-Cl-E
92323257004 1203-MW13
alpha-BHC 0.063 ug/L 12/16/16 22:340.050EPA 8081
Barium 80.9J ug/L 12/23/16 19:33100EPA 6010
Cobalt 58.8 ug/L 12/23/16 02:1110.0EPA 6010
Iron 969 ug/L 12/23/16 02:11300EPA 6010
Manganese 1560 ug/L 12/23/16 02:1150.0EPA 6010
Nickel 3.8J ug/L 12/23/16 19:3350.0EPA 6010
Zinc 15.7 ug/L 12/23/16 02:1110.0EPA 6010
Mercury 0.15J ug/L 12/20/16 05:360.20EPA 7470
Benzene 14.5 ug/L 12/16/16 00:431.0EPA 8260
Chlorobenzene 0.96J ug/L 12/16/16 00:433.0EPA 8260
Chloroethane 1.2J ug/L 12/16/16 00:4310.0EPA 8260
1,2-Dichlorobenzene 0.67J ug/L 12/16/16 00:435.0EPA 8260
1,4-Dichlorobenzene 13.9 ug/L 12/16/16 00:431.0EPA 8260
Dichlorodifluoromethane 0.57J ug/L 12/16/16 00:435.0EPA 8260
1,1-Dichloroethane 26.4 ug/L 12/16/16 00:435.0EPA 8260
1,2-Dichloroethane 1.3 ug/L 12/16/16 00:431.0EPA 8260
cis-1,2-Dichloroethene 25.7 ug/L 12/16/16 00:435.0EPA 8260
Ethylbenzene 3.0 ug/L 12/16/16 00:431.0EPA 8260
Methylene Chloride 41.8 ug/L 12/16/16 00:431.0EPA 8260
Naphthalene 2.6J ug/L 12/16/16 00:4310.0EPA 8260
Tetrachloroethene 5.9 ug/L 12/16/16 00:431.0EPA 8260
Tetrahydrofuran 9.2J ug/L 12/16/16 00:4310.0EPA 8260
Toluene 6.8 ug/L 12/16/16 00:431.0EPA 8260
Trichloroethene 9.9 ug/L 12/16/16 00:431.0EPA 8260
Xylene (Total)63.8 ug/L 12/16/16 00:435.0EPA 8260
Alkalinity, Total as CaCO3 9380 ug/L 12/23/16 05:565000SM 2320B
Sulfate 1340J ug/L 12/17/16 19:26250000EPA 300.0
Chloride 1810 ug/L 12/29/16 16:061000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323257005 1203-MW16S
Barium 48.1J ug/L 12/23/16 19:45100EPA 6010
Cobalt 28.1 ug/L 12/23/16 02:1410.0EPA 6010
Iron 24000 ug/L 12/23/16 02:14300EPA 6010
Manganese 10900 ug/L 12/23/16 20:10500EPA 6010
Zinc 51.0 ug/L 12/23/16 02:1410.0EPA 6010
Benzene 1.4 ug/L 12/16/16 01:001.0EPA 8260
Chlorobenzene 0.69J ug/L 12/16/16 01:003.0EPA 8260
Chloroethane 1.7J ug/L 12/16/16 01:0010.0EPA 8260
Chloromethane 0.16J ug/L 12/16/16 01:001.0EPA 8260
1,4-Dichlorobenzene 7.2 ug/L 12/16/16 01:001.0EPA 8260
1,1-Dichloroethane 22.1 ug/L 12/16/16 01:005.0EPA 8260
1,2-Dichloroethane 1.2 ug/L 12/16/16 01:001.0EPA 8260
cis-1,2-Dichloroethene 6.1 ug/L 12/16/16 01:005.0EPA 8260
Toluene 0.28J ug/L 12/16/16 01:001.0EPA 8260
Trichloroethene 0.64J ug/L 12/16/16 01:001.0EPA 8260
Vinyl chloride 0.90J ug/L 12/16/16 01:001.0EPA 8260
Alkalinity, Total as CaCO3 72100 ug/L 12/23/16 06:135000SM 2320B
Total Dissolved Solids 131000 ug/L 12/18/16 20:1425000SM 2540C
Sulfate 1930J ug/L 12/17/16 19:35250000EPA 300.0
Chloride 9280 ug/L 12/29/16 16:071000SM 4500-Cl-E
92323257006 1203-MW16D
Arsenic 3.5J ug/L 12/23/16 02:1710.0EPA 6010
Barium 10J ug/L 12/23/16 19:48100EPA 6010
Iron 217J ug/L 12/23/16 02:17300EPA 6010
Manganese 122 ug/L 12/23/16 02:1750.0EPA 6010
Zinc 6.8J ug/L 12/23/16 02:1710.0EPA 6010
Alkalinity, Total as CaCO3 49400 ug/L 12/23/16 06:565000SM 2320B
Total Dissolved Solids 90000 ug/L 12/18/16 20:1525000SM 2540C
Sulfate 9850J ug/L 12/17/16 19:44250000EPA 300.0
Chloride 965J ug/L 12/29/16 16:081000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 8 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 21:42 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 21:42 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 21:42 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 21:42 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 21:42 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 21:42 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 21:42 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 21:42 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 21:42 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 21:42 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 21:42 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 21:42 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 21:42 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 21:42 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 21:42 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 21:42 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 21:42 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 21:42 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 21:42 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)64 %12/16/16 21:42 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)82 %12/16/16 21:42 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 18:31 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 18:31 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 18:31 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 18:31 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 18:31 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 18:31 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 18:31 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)54 %12/20/16 18:31 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 19:57 94-75-712/19/16 08:400.97 0.23 1
Dinoseb ND ug/L 12/21/16 19:57 88-85-712/19/16 08:400.19 0.059 1
2,4,5-T ND ug/L 12/21/16 19:57 93-76-512/19/16 08:400.20 0.043 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 19:57 93-72-112/19/16 08:400.20 0.051 1
Surrogates
2,4-DCAA (S)105 %12/21/16 19:57 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 01:52 7440-36-012/15/16 22:106.0 3.8 1
Arsenic 3.2J ug/L 12/23/16 01:52 7440-38-212/15/16 22:1010.0 2.5 1
Barium 66.0J ug/L 12/23/16 19:23 7440-39-312/15/16 22:10100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
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[phone]
Page 9 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 01:52 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:23 7440-43-912/15/16 22:101.0 0.50 1
Chromium ND ug/L 12/23/16 01:52 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt 93.2 ug/L 12/23/16 01:52 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 01:52 7440-50-812/15/16 22:1010.0 2.5 1
Iron 17600 ug/L 12/23/16 01:52 7439-89-612/15/16 22:10300 25.0 1
Lead ND ug/L 12/23/16 19:23 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 5100 ug/L 12/23/16 01:52 7439-96-512/15/16 22:1050.0 2.5 1
Nickel 3.9J ug/L 12/23/16 19:23 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 01:52 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 01:52 7440-22-412/15/16 22:1010.0 2.5 1
Thallium 5.3J ug/L 12/23/16 01:52 7440-28-012/15/16 22:105.5 5.0 1
Tin ND ug/L 12/23/16 01:52 7440-31-512/15/16 22:10100 2.5 1
Vanadium ND ug/L 12/23/16 01:52 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 12.8 ug/L 12/23/16 01:52 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.25 ug/L 12/20/16 05:02 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 14:27 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 14:27 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 14:27 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 14:27 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 14:27 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 14:27 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 14:27 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 14:27 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 14:27 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 14:27 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 14:27 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 14:27 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 14:27 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 14:27 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 14:27 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 14:27 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 14:27 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 14:27 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 14:27 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 14:27 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 14:27 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 14:27 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 14:27 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 14:27 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 14:27 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 14:27 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 14:27 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 14:27 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 14:27 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 14:27 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/22/16 14:27 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 14:27 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 14:27 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 14:27 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 14:27 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 14:27 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 14:27 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 14:27 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 14:27 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 14:27 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 14:27 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 14:27 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 14:27 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 14:27 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 14:27 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 14:27 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 14:27 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 14:27 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 14:27 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 14:27 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 14:27 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 14:27 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 14:27 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 14:27 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 14:27 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 14:27 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 14:27 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 14:27 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 14:27 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 14:27 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/22/16 14:27 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 14:27 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 14:27 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 14:27 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 14:27 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 14:2712/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 14:27 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 14:27 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 14:27 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 14:27 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 14:27 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 14:27 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 14:27 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 14:27 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 14:27 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 14:27 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 14:27 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 14:27 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 14:27 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 14:27 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 14:27 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 14:27 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 14:27 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 14:27 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 14:27 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 14:27 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 14:27 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 14:27 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 14:27 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 14:27 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 14:27 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 14:27 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 14:2712/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 14:27 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 14:27 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 14:27 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 14:27 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 14:27 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 14:27 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 14:27 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 14:27 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 14:27 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 14:27 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 14:27 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 14:27 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)30 %12/22/16 14:27 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)32 %12/22/16 14:27 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)51 %12/22/16 14:27 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)11 %12/22/16 14:27 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)17 %12/22/16 14:27 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)48 %12/22/16 14:27 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/15/16 23:52 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/15/16 23:52 75-05-855.0 2.2 1
Acrolein ND ug/L 12/15/16 23:52 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/15/16 23:52 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/15/16 23:52 107-05-110.0 1.5 1
Benzene 1.7 ug/L 12/15/16 23:52 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/15/16 23:52 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/15/16 23:52 75-27-41.0 0.18 1
Bromoform ND ug/L 12/15/16 23:52 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/15/16 23:52 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/15/16 23:52 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/15/16 23:52 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/15/16 23:52 56-23-51.0 0.25 1
Chlorobenzene 0.85J ug/L 12/15/16 23:52 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/15/16 23:52 75-00-310.0 0.54 1
Chloroform ND ug/L 12/15/16 23:52 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/15/16 23:52 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/15/16 23:52 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/15/16 23:52 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/15/16 23:52 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/15/16 23:52 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/15/16 23:52 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/15/16 23:52 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/15/16 23:52 541-73-15.0 0.24 1
1,4-Dichlorobenzene 0.89J ug/L 12/15/16 23:52 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/15/16 23:52 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/15/16 23:52 75-71-85.0 0.21 1
1,1-Dichloroethane 1.4J ug/L 12/15/16 23:52 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/15/16 23:52 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/15/16 23:52 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 5.1 ug/L 12/15/16 23:52 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/15/16 23:52 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/15/16 23:52 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/15/16 23:52 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/15/16 23:52 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/15/16 23:52 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/15/16 23:52 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/15/16 23:52 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/15/16 23:52 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/15/16 23:52 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/15/16 23:52 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/15/16 23:52 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/15/16 23:52 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/15/16 23:52 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/15/16 23:52 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/15/16 23:52 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/15/16 23:52 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/15/16 23:52 108-10-1100 0.33 1
Naphthalene ND ug/L 12/15/16 23:52 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/15/16 23:52 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW10 Lab ID: 92323257001 Collected: 12/13/16 12:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/15/16 23:52 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/15/16 23:52 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/15/16 23:52 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/15/16 23:52 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/15/16 23:52 109-99-910.0 3.1 1
Toluene ND ug/L 12/15/16 23:52 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/15/16 23:52 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/15/16 23:52 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/15/16 23:52 79-00-51.0 0.29 1
Trichloroethene 0.52J ug/L 12/15/16 23:52 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/15/16 23:52 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/15/16 23:52 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/15/16 23:52 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/15/16 23:52 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/15/16 23:52 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/15/16 23:52 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/15/16 23:52 17060-07-070-130 1
Toluene-d8 (S)100 %12/15/16 23:52 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 35700 ug/L 12/23/16 04:545000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 73000 ug/L 12/18/16 20:1325000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3220J ug/L 12/17/16 18:59 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 9040 ug/L 12/29/16 16:03 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:31 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 21:59 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 21:59 319-84-612/15/16 16:340.050 0.050 1
beta-BHC 0.12 ug/L 12/16/16 21:59 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 21:59 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 21:59 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 21:59 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 21:59 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 21:59 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 21:59 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 21:59 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 21:59 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 21:59 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 21:59 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 21:59 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 21:59 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 21:59 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 21:59 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 21:59 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 21:59 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)125 %12/16/16 21:59 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)70 %12/16/16 21:59 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 18:51 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 18:51 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 18:51 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 18:51 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 18:51 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 18:51 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 18:51 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)72 %12/20/16 18:51 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 20:27 94-75-712/19/16 08:400.97 0.23 1
Dinoseb ND ug/L 12/21/16 20:27 88-85-712/19/16 08:400.19 0.059 1
2,4,5-T ND ug/L 12/21/16 20:27 93-76-512/19/16 08:400.19 0.043 1
2,4,5-TP (Silvex)0.14J ug/L 12/21/16 20:27 93-72-112/19/16 08:400.20 0.050 1
Surrogates
2,4-DCAA (S)107 %12/21/16 20:27 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 01:55 7440-36-012/15/16 22:106.0 3.8 1
Arsenic ND ug/L 12/23/16 01:55 7440-38-212/15/16 22:1010.0 2.5 1
Barium 128 ug/L 12/23/16 19:26 7440-39-312/15/16 22:10100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 01:55 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:26 7440-43-912/15/16 22:101.0 0.50 1
Chromium 3.7J ug/L 12/23/16 01:55 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt 52.4 ug/L 12/23/16 01:55 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 01:55 7440-50-812/15/16 22:1010.0 2.5 1
Iron 67800 ug/L 12/23/16 01:55 7439-89-612/15/16 22:10300 25.0 1
Lead 3.5J ug/L 12/23/16 19:26 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 17900 ug/L 12/23/16 20:07 7439-96-512/15/16 22:10500 25.0 10
Nickel 3.8J ug/L 12/23/16 19:26 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 01:55 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 01:55 7440-22-412/15/16 22:1010.0 2.5 1
Thallium 5.1J ug/L 12/23/16 01:55 7440-28-012/15/16 22:105.5 5.0 1
Tin ND ug/L 12/23/16 01:55 7440-31-512/15/16 22:10100 2.5 1
Vanadium ND ug/L 12/23/16 01:55 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 17.6 ug/L 12/23/16 01:55 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:05 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/23/16 11:01 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/23/16 11:01 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/23/16 11:01 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/23/16 11:01 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/23/16 11:01 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/23/16 11:01 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/23/16 11:01 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/23/16 11:01 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/23/16 11:01 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/23/16 11:01 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/23/16 11:01 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/23/16 11:01 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/23/16 11:01 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/23/16 11:01 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/23/16 11:01 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/23/16 11:01 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/23/16 11:01 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/23/16 11:01 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/23/16 11:01 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/23/16 11:01 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/23/16 11:01 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/23/16 11:01 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/23/16 11:01 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/23/16 11:01 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/23/16 11:01 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/23/16 11:01 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/23/16 11:01 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/23/16 11:01 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/23/16 11:01 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/23/16 11:01 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/23/16 11:01 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/23/16 11:01 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/23/16 11:01 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/23/16 11:01 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/23/16 11:01 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/23/16 11:01 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/23/16 11:01 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/23/16 11:01 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/23/16 11:01 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/23/16 11:01 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/23/16 11:01 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/23/16 11:01 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/23/16 11:01 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/23/16 11:01 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/23/16 11:01 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/23/16 11:01 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/23/16 11:01 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/23/16 11:01 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/23/16 11:01 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/23/16 11:01 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/23/16 11:01 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/23/16 11:01 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/23/16 11:01 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/23/16 11:01 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/23/16 11:01 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/23/16 11:01 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/23/16 11:01 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/23/16 11:01 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/23/16 11:01 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/23/16 11:01 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/23/16 11:01 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/23/16 11:01 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/23/16 11:01 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/23/16 11:01 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/23/16 11:01 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/23/16 11:0112/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/23/16 11:01 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/23/16 11:01 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/23/16 11:01 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/23/16 11:01 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/23/16 11:01 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/23/16 11:01 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/23/16 11:01 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/23/16 11:01 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/23/16 11:01 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/23/16 11:01 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/23/16 11:01 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/23/16 11:01 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/23/16 11:01 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/23/16 11:01 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/23/16 11:01 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/23/16 11:01 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/23/16 11:01 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/23/16 11:01 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/23/16 11:01 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/23/16 11:01 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/23/16 11:01 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/23/16 11:01 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/23/16 11:01 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/23/16 11:01 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/23/16 11:01 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/23/16 11:01 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/23/16 11:0112/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/23/16 11:01 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/23/16 11:01 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/23/16 11:01 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/23/16 11:01 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/23/16 11:01 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/23/16 11:01 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/23/16 11:01 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/23/16 11:01 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/23/16 11:01 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/23/16 11:01 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/23/16 11:01 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/23/16 11:01 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)62 %12/23/16 11:01 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)71 %12/23/16 11:01 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)67 %12/23/16 11:01 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)25 %12/23/16 11:01 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)34 %12/23/16 11:01 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)90 %12/23/16 11:01 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 00:09 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 00:09 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 00:09 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 00:09 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/16/16 00:09 107-05-110.0 1.5 1
Benzene 2.3 ug/L 12/16/16 00:09 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 00:09 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 00:09 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 00:09 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 00:09 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 00:09 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 00:09 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 00:09 56-23-51.0 0.25 1
Chlorobenzene 0.48J ug/L 12/16/16 00:09 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 00:09 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 00:09 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 00:09 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 00:09 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 00:09 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 00:09 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 00:09 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 00:09 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.32J ug/L 12/16/16 00:09 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 00:09 541-73-15.0 0.24 1
1,4-Dichlorobenzene 10.5 ug/L 12/16/16 00:09 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 00:09 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/16/16 00:09 75-71-85.0 0.21 1
1,1-Dichloroethane 3.0J ug/L 12/16/16 00:09 75-34-35.0 0.32 1
1,2-Dichloroethane 0.48J ug/L 12/16/16 00:09 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 00:09 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 5.7 ug/L 12/16/16 00:09 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 00:09 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 00:09 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 00:09 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 00:09 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 00:09 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 00:09 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 00:09 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 00:09 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 00:09 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 00:09 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 00:09 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 00:09 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 00:09 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 00:09 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/16/16 00:09 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 00:09 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 00:09 108-10-1100 0.33 1
Naphthalene ND ug/L 12/16/16 00:09 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 00:09 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW11 Lab ID: 92323257002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/16/16 00:09 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 00:09 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 00:09 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 00:09 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 00:09 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 00:09 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 00:09 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 00:09 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 00:09 79-00-51.0 0.29 1
Trichloroethene 0.56J ug/L 12/16/16 00:09 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 00:09 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 00:09 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 00:09 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 00:09 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 00:09 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)92 %12/16/16 00:09 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 00:09 17060-07-070-130 1
Toluene-d8 (S)100 %12/16/16 00:09 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 97700 ug/L 12/23/16 05:115000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 241000 ug/L 12/18/16 20:1425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3500J ug/L 12/17/16 19:08 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 35000 ug/L 12/29/16 16:04 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:32 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 22:17 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 22:17 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 22:17 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 22:17 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 22:17 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 22:17 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 22:17 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 22:17 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 22:17 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 22:17 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 22:17 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 22:17 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 22:17 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 22:17 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 22:17 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 22:17 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 22:17 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 22:17 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 22:17 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)86 %12/16/16 22:17 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)41 %12/16/16 22:17 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 19:11 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 19:11 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 19:11 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 19:11 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 19:11 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 19:11 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 19:11 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)64 %12/20/16 19:11 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 20:57 94-75-712/19/16 08:400.97 0.23 1
Dinoseb ND ug/L 12/21/16 20:57 88-85-712/19/16 08:400.19 0.059 1
2,4,5-T ND ug/L 12/21/16 20:57 93-76-512/19/16 08:400.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 20:57 93-72-112/19/16 08:400.20 0.050 1
Surrogates
2,4-DCAA (S)102 %12/21/16 20:57 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 01:58 7440-36-012/15/16 22:106.0 3.8 1
Arsenic ND ug/L 12/23/16 01:58 7440-38-212/15/16 22:1010.0 2.5 1
Barium 83.2J ug/L 12/23/16 19:29 7440-39-312/15/16 22:10100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 01:58 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:29 7440-43-912/15/16 22:101.0 0.50 1
Chromium 4.4J ug/L 12/23/16 01:58 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt 70.6 ug/L 12/23/16 01:58 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 01:58 7440-50-812/15/16 22:1010.0 2.5 1
Iron 45300 ug/L 12/23/16 01:58 7439-89-612/15/16 22:10300 25.0 1
Lead 2.6J ug/L 12/23/16 19:29 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 8850 ug/L 12/23/16 01:58 7439-96-512/15/16 22:1050.0 2.5 1
Nickel 29.7J ug/L 12/23/16 19:29 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 01:58 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 01:58 7440-22-412/15/16 22:1010.0 2.5 1
Thallium ND ug/L 12/23/16 01:58 7440-28-012/15/16 22:105.5 5.0 1
Tin ND ug/L 12/23/16 01:58 7440-31-512/15/16 22:10100 2.5 1
Vanadium ND ug/L 12/23/16 01:58 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 9.7J ug/L 12/23/16 01:58 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:07 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 16:27 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 16:27 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 16:27 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 16:27 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 16:27 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 16:27 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 16:27 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 16:27 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 16:27 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 16:27 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 16:27 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 16:27 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 16:27 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 16:27 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 16:27 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 16:27 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 16:27 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 16:27 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 16:27 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 16:27 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 16:27 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 16:27 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 16:27 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 16:27 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 16:27 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 16:27 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 16:27 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 16:27 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 16:27 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 16:27 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/22/16 16:27 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 16:27 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 16:27 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 16:27 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 16:27 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 16:27 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 16:27 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 16:27 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 16:27 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 16:27 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 16:27 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 16:27 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 16:27 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 16:27 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 16:27 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 16:27 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 16:27 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 16:27 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 16:27 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 16:27 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 16:27 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 16:27 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 16:27 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 16:27 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 16:27 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 16:27 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 16:27 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 16:27 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 16:27 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 16:27 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/22/16 16:27 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 16:27 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 16:27 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 16:27 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 16:27 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 16:2712/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 16:27 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 16:27 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 16:27 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 16:27 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 16:27 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 16:27 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 16:27 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 16:27 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 16:27 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 16:27 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 16:27 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 16:27 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 16:27 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 16:27 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 16:27 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 16:27 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 16:27 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 16:27 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 16:27 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 16:27 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 16:27 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 16:27 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 16:27 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 16:27 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 16:27 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 16:27 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 16:2712/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 16:27 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 16:27 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 16:27 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 16:27 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 16:27 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 16:27 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 16:27 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 16:27 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 16:27 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 16:27 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 16:27 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 16:27 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)51 %12/22/16 16:27 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)60 %12/22/16 16:27 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)70 %12/22/16 16:27 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)19 %12/22/16 16:27 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)28 %12/22/16 16:27 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)79 %12/22/16 16:27 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 00:26 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 00:26 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 00:26 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 00:26 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
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[phone]
Page 24 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/16/16 00:26 107-05-110.0 1.5 1
Benzene 2.8 ug/L 12/16/16 00:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 00:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 00:26 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 00:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 00:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 00:26 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 00:26 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 00:26 56-23-51.0 0.25 1
Chlorobenzene 0.63J ug/L 12/16/16 00:26 108-90-73.0 0.23 1
Chloroethane 3.0J ug/L 12/16/16 00:26 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 00:26 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 00:26 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 00:26 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 00:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 00:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 00:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 00:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 00:26 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 00:26 541-73-15.0 0.24 1
1,4-Dichlorobenzene 4.7 ug/L 12/16/16 00:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 00:26 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/16/16 00:26 75-71-85.0 0.21 1
1,1-Dichloroethane 27.4 ug/L 12/16/16 00:26 75-34-35.0 0.32 1
1,2-Dichloroethane 1.1 ug/L 12/16/16 00:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 00:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 9.8 ug/L 12/16/16 00:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 00:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 00:26 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 00:26 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 00:26 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 00:26 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 00:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 00:26 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 00:26 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 00:26 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 00:26 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 00:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 00:26 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 00:26 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 00:26 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/16/16 00:26 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 00:26 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 00:26 108-10-1100 0.33 1
Naphthalene ND ug/L 12/16/16 00:26 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 00:26 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW12 Lab ID: 92323257003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/16/16 00:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 00:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 00:26 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 00:26 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 00:26 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 00:26 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 00:26 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 00:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 00:26 79-00-51.0 0.29 1
Trichloroethene 2.1 ug/L 12/16/16 00:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 00:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 00:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 00:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 00:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 00:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/16/16 00:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 00:26 17060-07-070-130 1
Toluene-d8 (S)101 %12/16/16 00:26 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 54100 ug/L 12/23/16 05:325000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 133000 ug/L 12/18/16 20:1425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 4050J ug/L 12/17/16 19:17 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 7650 ug/L 12/29/16 16:05 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:33 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 22:34 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC 0.063 ug/L 12/16/16 22:34 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 22:34 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 22:34 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 22:34 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 22:34 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 22:34 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 22:34 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 22:34 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 22:34 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 22:34 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 22:34 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 22:34 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 22:34 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 22:34 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 22:34 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 22:34 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 22:34 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 22:34 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)90 %12/16/16 22:34 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)40 %12/16/16 22:34 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 19:31 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 19:31 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 19:31 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 19:31 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 19:31 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 19:31 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 19:31 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)78 %12/20/16 19:31 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 21:27 94-75-712/19/16 08:400.98 0.23 1
Dinoseb ND ug/L 12/21/16 21:27 88-85-712/19/16 08:400.20 0.060 1
2,4,5-T ND ug/L 12/21/16 21:27 93-76-512/19/16 08:400.20 0.044 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 21:27 93-72-112/19/16 08:400.20 0.051 1
Surrogates
2,4-DCAA (S)90 %12/21/16 21:27 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 02:11 7440-36-012/15/16 22:106.0 3.8 1
Arsenic ND ug/L 12/23/16 02:11 7440-38-212/15/16 22:1010.0 2.5 1
Barium 80.9J ug/L 12/23/16 19:33 7440-39-312/15/16 22:10100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 02:11 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:33 7440-43-912/15/16 22:101.0 0.50 1
Chromium ND ug/L 12/23/16 02:11 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt 58.8 ug/L 12/23/16 02:11 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 02:11 7440-50-812/15/16 22:1010.0 2.5 1
Iron 969 ug/L 12/23/16 02:11 7439-89-612/15/16 22:10300 25.0 1
Lead ND ug/L 12/23/16 19:33 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 1560 ug/L 12/23/16 02:11 7439-96-512/15/16 22:1050.0 2.5 1
Nickel 3.8J ug/L 12/23/16 19:33 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 02:11 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 02:11 7440-22-412/15/16 22:1010.0 2.5 1
Thallium ND ug/L 12/23/16 02:11 7440-28-012/15/16 22:105.5 5.0 1
Tin ND ug/L 12/23/16 02:11 7440-31-512/15/16 22:10100 2.5 1
Vanadium ND ug/L 12/23/16 02:11 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 15.7 ug/L 12/23/16 02:11 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.15J ug/L 12/20/16 05:36 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 16:57 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 16:57 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 16:57 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 16:57 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 16:57 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 16:57 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 16:57 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 16:57 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 16:57 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 16:57 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 16:57 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 16:57 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 16:57 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 16:57 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 16:57 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 16:57 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 16:57 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 16:57 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 16:57 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 16:57 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 16:57 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 16:57 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 16:57 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 16:57 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 16:57 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 16:57 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 16:57 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 16:57 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 16:57 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 16:57 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/22/16 16:57 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 16:57 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 16:57 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 16:57 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 16:57 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 16:57 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 16:57 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 16:57 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 16:57 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 16:57 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 16:57 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 16:57 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 16:57 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 16:57 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 16:57 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 16:57 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 16:57 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 16:57 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 16:57 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 16:57 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 16:57 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 16:57 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 16:57 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 16:57 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 16:57 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 16:57 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 16:57 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 16:57 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 16:57 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 16:57 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/22/16 16:57 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 16:57 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 16:57 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 16:57 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 16:57 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 16:5712/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 16:57 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 16:57 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 16:57 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 16:57 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 16:57 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 16:57 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 16:57 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 16:57 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 16:57 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 16:57 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 16:57 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 16:57 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 16:57 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 16:57 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 16:57 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 16:57 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 16:57 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 16:57 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 16:57 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 16:57 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 16:57 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 16:57 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 16:57 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 16:57 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 16:57 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 16:57 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 16:5712/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 16:57 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 16:57 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 16:57 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 16:57 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 16:57 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 16:57 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 16:57 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 16:57 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 16:57 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 16:57 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 16:57 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 16:57 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)61 %12/22/16 16:57 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)66 %12/22/16 16:57 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)77 %12/22/16 16:57 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)21 %12/22/16 16:57 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)32 %12/22/16 16:57 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)80 %12/22/16 16:57 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 00:43 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 00:43 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 00:43 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 00:43 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/16/16 00:43 107-05-110.0 1.5 1
Benzene 14.5 ug/L 12/16/16 00:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 00:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 00:43 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 00:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 00:43 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 00:43 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 00:43 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 00:43 56-23-51.0 0.25 1
Chlorobenzene 0.96J ug/L 12/16/16 00:43 108-90-73.0 0.23 1
Chloroethane 1.2J ug/L 12/16/16 00:43 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 00:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 00:43 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 00:43 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 00:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 00:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 00:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 00:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.67J ug/L 12/16/16 00:43 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 00:43 541-73-15.0 0.24 1
1,4-Dichlorobenzene 13.9 ug/L 12/16/16 00:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 00:43 110-57-6100 1.0 1
Dichlorodifluoromethane 0.57J ug/L 12/16/16 00:43 75-71-85.0 0.21 1
1,1-Dichloroethane 26.4 ug/L 12/16/16 00:43 75-34-35.0 0.32 1
1,2-Dichloroethane 1.3 ug/L 12/16/16 00:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 00:43 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 25.7 ug/L 12/16/16 00:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 00:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 00:43 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 00:43 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 00:43 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 00:43 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 00:43 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 00:43 10061-02-61.0 0.26 1
Ethylbenzene 3.0 ug/L 12/16/16 00:43 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 00:43 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 00:43 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 00:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 00:43 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 00:43 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 00:43 126-98-7100 0.93 1
Methylene Chloride 41.8 ug/L 12/16/16 00:43 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 00:43 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 00:43 108-10-1100 0.33 1
Naphthalene 2.6J ug/L 12/16/16 00:43 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 00:43 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW13 Lab ID: 92323257004 Collected: 12/13/16 14:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/16/16 00:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 00:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 00:43 79-34-53.0 0.40 1
Tetrachloroethene 5.9 ug/L 12/16/16 00:43 127-18-41.0 0.46 1
Tetrahydrofuran 9.2J ug/L 12/16/16 00:43 109-99-910.0 3.1 1
Toluene 6.8 ug/L 12/16/16 00:43 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 00:43 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 00:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 00:43 79-00-51.0 0.29 1
Trichloroethene 9.9 ug/L 12/16/16 00:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 00:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 00:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 00:43 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 00:43 75-01-41.0 0.62 1
Xylene (Total)63.8 ug/L 12/16/16 00:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/16/16 00:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/16/16 00:43 17060-07-070-130 1
Toluene-d8 (S)99 %12/16/16 00:43 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 9380 ug/L 12/23/16 05:565000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/18/16 20:1425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1340J ug/L 12/17/16 19:26 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1810 ug/L 12/29/16 16:06 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:34 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 22:52 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 22:52 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 22:52 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 22:52 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 22:52 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 22:52 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 22:52 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 22:52 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 22:52 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 22:52 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 22:52 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 22:52 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 22:52 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 22:52 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 22:52 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 22:52 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 22:52 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 22:52 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 22:52 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)81 %12/16/16 22:52 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)53 %12/16/16 22:52 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 19:51 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 19:51 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 19:51 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 19:51 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 19:51 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 19:51 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 19:51 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)77 %12/20/16 19:51 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 21:58 94-75-712/19/16 08:400.99 0.24 1
Dinoseb ND ug/L 12/21/16 21:58 88-85-712/19/16 08:400.20 0.060 1
2,4,5-T ND ug/L 12/21/16 21:58 93-76-512/19/16 08:400.20 0.044 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 21:58 93-72-112/19/16 08:400.20 0.052 1
Surrogates
2,4-DCAA (S)100 %12/21/16 21:58 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 02:14 7440-36-012/15/16 22:106.0 3.8 1
Arsenic ND ug/L 12/23/16 02:14 7440-38-212/15/16 22:1010.0 2.5 1
Barium 48.1J ug/L 12/23/16 19:45 7440-39-312/15/16 22:10100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 02:14 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:45 7440-43-912/15/16 22:101.0 0.50 1
Chromium ND ug/L 12/23/16 02:14 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt 28.1 ug/L 12/23/16 02:14 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 02:14 7440-50-812/15/16 22:1010.0 2.5 1
Iron 24000 ug/L 12/23/16 02:14 7439-89-612/15/16 22:10300 25.0 1
Lead ND ug/L 12/23/16 19:45 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 10900 ug/L 12/23/16 20:10 7439-96-512/15/16 22:10500 25.0 10
Nickel ND ug/L 12/23/16 19:45 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 02:14 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 02:14 7440-22-412/15/16 22:1010.0 2.5 1
Thallium ND ug/L 12/23/16 02:14 7440-28-012/15/16 22:105.5 5.0 1
Tin ND ug/L 12/23/16 02:14 7440-31-512/15/16 22:10100 2.5 1
Vanadium ND ug/L 12/23/16 02:14 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 51.0 ug/L 12/23/16 02:14 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:38 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 17:26 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 17:26 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 17:26 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 17:26 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 17:26 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 17:26 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 17:26 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 17:26 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 17:26 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 17:26 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 17:26 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 17:26 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 17:26 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 17:26 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 17:26 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 17:26 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 17:26 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 17:26 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 17:26 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 17:26 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 17:26 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 17:26 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 17:26 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 17:26 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 17:26 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 17:26 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 17:26 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 17:26 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 17:26 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 17:26 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/22/16 17:26 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 17:26 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 17:26 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 17:26 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 17:26 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 17:26 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 17:26 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 17:26 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 17:26 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 17:26 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 17:26 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 17:26 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 17:26 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 17:26 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 17:26 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 17:26 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 17:26 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 17:26 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 17:26 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 17:26 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 17:26 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 17:26 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 17:26 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 17:26 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 17:26 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 17:26 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 17:26 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 17:26 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 17:26 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 17:26 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/22/16 17:26 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 17:26 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 17:26 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 17:26 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 17:26 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 17:2612/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 17:26 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 17:26 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 17:26 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 17:26 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 17:26 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 17:26 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 17:26 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 17:26 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 17:26 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 17:26 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 17:26 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 17:26 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 17:26 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 17:26 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 17:26 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 17:26 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 17:26 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 17:26 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 17:26 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 17:26 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 17:26 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 17:26 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 17:26 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 17:26 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 17:26 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 17:26 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 17:2612/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 17:26 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 17:26 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 17:26 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 17:26 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 17:26 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 17:26 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 17:26 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 17:26 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 17:26 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 17:26 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 17:26 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 17:26 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)63 %12/22/16 17:26 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)68 %12/22/16 17:26 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)75 %12/22/16 17:26 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)20 %12/22/16 17:26 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)31 %12/22/16 17:26 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)84 %12/22/16 17:26 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 01:00 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 01:00 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 01:00 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 01:00 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/16/16 01:00 107-05-110.0 1.5 1
Benzene 1.4 ug/L 12/16/16 01:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 01:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 01:00 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 01:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 01:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 01:00 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 01:00 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 01:00 56-23-51.0 0.25 1
Chlorobenzene 0.69J ug/L 12/16/16 01:00 108-90-73.0 0.23 1
Chloroethane 1.7J ug/L 12/16/16 01:00 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 01:00 67-66-35.0 0.14 1
Chloromethane 0.16J ug/L 12/16/16 01:00 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 01:00 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 01:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 01:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 01:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 01:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 01:00 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 01:00 541-73-15.0 0.24 1
1,4-Dichlorobenzene 7.2 ug/L 12/16/16 01:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 01:00 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/16/16 01:00 75-71-85.0 0.21 1
1,1-Dichloroethane 22.1 ug/L 12/16/16 01:00 75-34-35.0 0.32 1
1,2-Dichloroethane 1.2 ug/L 12/16/16 01:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 01:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 6.1 ug/L 12/16/16 01:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 01:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 01:00 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 01:00 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 01:00 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 01:00 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 01:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 01:00 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 01:00 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 01:00 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 01:00 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 01:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 01:00 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 01:00 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 01:00 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/16/16 01:00 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 01:00 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 01:00 108-10-1100 0.33 1
Naphthalene ND ug/L 12/16/16 01:00 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 01:00 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16S Lab ID: 92323257005 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/16/16 01:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 01:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 01:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 01:00 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 01:00 109-99-910.0 3.1 1
Toluene 0.28J ug/L 12/16/16 01:00 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 01:00 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 01:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 01:00 79-00-51.0 0.29 1
Trichloroethene 0.64J ug/L 12/16/16 01:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 01:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 01:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 01:00 108-05-450.0 0.35 1
Vinyl chloride 0.90J ug/L 12/16/16 01:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 01:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/16/16 01:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 01:00 17060-07-070-130 1
Toluene-d8 (S)100 %12/16/16 01:00 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 72100 ug/L 12/23/16 06:135000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 131000 ug/L 12/18/16 20:1425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1930J ug/L 12/17/16 19:35 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 9280 ug/L 12/29/16 16:07 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:35 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
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[phone]
Page 38 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16D Lab ID: 92323257006 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 02:17 7440-36-012/15/16 22:106.0 3.8 1
Arsenic 3.5J ug/L 12/23/16 02:17 7440-38-212/15/16 22:1010.0 2.5 1
Barium 10J ug/L 12/23/16 19:48 7440-39-312/15/16 22:10100 2.5 1
Beryllium ND ug/L 12/23/16 02:17 7440-41-712/15/16 22:101.0 0.50 1
Cadmium ND ug/L 12/23/16 19:48 7440-43-912/15/16 22:101.0 0.50 1
Chromium ND ug/L 12/23/16 02:17 7440-47-312/15/16 22:1010.0 2.5 1
Cobalt ND ug/L 12/23/16 02:17 7440-48-412/15/16 22:1010.0 2.5 1
Copper ND ug/L 12/23/16 02:17 7440-50-812/15/16 22:1010.0 2.5 1
Iron 217J ug/L 12/23/16 02:17 7439-89-612/15/16 22:10300 25.0 1
Lead ND ug/L 12/23/16 19:48 7439-92-112/15/16 22:1010.0 2.5 1
Manganese 122 ug/L 12/23/16 02:17 7439-96-512/15/16 22:1050.0 2.5 1
Nickel ND ug/L 12/23/16 19:48 7440-02-012/15/16 22:1050.0 2.5 1
Selenium ND ug/L 12/23/16 02:17 7782-49-212/15/16 22:1010.0 5.0 1
Silver ND ug/L 12/23/16 02:17 7440-22-412/15/16 22:1010.0 2.5 1
Thallium ND ug/L 12/23/16 02:17 7440-28-012/15/16 22:105.5 5.0 1
Vanadium ND ug/L 12/23/16 02:17 7440-62-212/15/16 22:1025.0 2.5 1
Zinc 6.8J ug/L 12/23/16 02:17 7440-66-612/15/16 22:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:47 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 01:17 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/16/16 01:17 107-13-1200 1.9 1
Benzene ND ug/L 12/16/16 01:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 01:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 01:17 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 01:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 01:17 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 01:17 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 01:17 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 01:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/16/16 01:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 01:17 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 01:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 01:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 01:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 01:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 01:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 01:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 01:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/16/16 01:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 01:17 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 12/16/16 01:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/16/16 01:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 01:17 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 39 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Sample: 1203-MW16D Lab ID: 92323257006 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/16/16 01:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 01:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 01:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 01:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 01:17 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 01:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/16/16 01:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 01:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/16/16 01:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 01:17 108-10-1100 0.33 1
Styrene ND ug/L 12/16/16 01:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 01:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 01:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 01:17 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 01:17 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 01:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/16/16 01:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 01:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/16/16 01:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 01:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 01:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 01:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 01:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 01:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)92 %12/16/16 01:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 01:17 17060-07-070-130 1
Toluene-d8 (S)99 %12/16/16 01:17 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 49400 ug/L 12/23/16 06:565000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 90000 ug/L 12/18/16 20:1525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 9850J ug/L 12/17/16 19:44 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 965J ug/L 12/29/16 16:08 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340993
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323257001, 92323257002, 92323257003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891545
Associated Lab Samples:92323257001, 92323257002, 92323257003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/20/16 04:010.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891546LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.72.5 108 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891547MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1891548
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 109 75-125117 7 252.5ND 2.8 3.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340994
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891549
Associated Lab Samples:92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/20/16 05:170.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891550LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991014
1891552
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 102 75-125103 2 252.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340971
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891486
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 01:033.8
Arsenic ug/L ND 10.0 12/23/16 01:032.5
Barium ug/L ND 100 12/23/16 01:032.5
Beryllium ug/L ND 1.0 12/23/16 01:030.50
Cadmium ug/L ND 1.0 12/23/16 01:030.50
Chromium ug/L ND 10.0 12/23/16 01:032.5
Cobalt ug/L ND 10.0 12/23/16 01:032.5
Copper ug/L ND 10.0 12/23/16 01:032.5
Iron ug/L ND 300 12/23/16 01:0325.0
Lead ug/L ND 10.0 12/23/16 01:032.5
Manganese ug/L ND 50.0 12/23/16 01:032.5
Nickel ug/L ND 50.0 12/23/16 18:342.5
Selenium ug/L ND 10.0 12/23/16 01:035.0
Silver ug/L ND 10.0 12/23/16 01:032.5
Thallium ug/L ND 5.5 12/23/16 01:035.0
Tin ug/L ND 100 12/23/16 01:032.5
Vanadium ug/L ND 25.0 12/23/16 01:032.5
Zinc ug/L ND 10.0 12/23/16 01:035.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891487LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 466500 93 80-120
Arsenic ug/L 467500 93 80-120
Barium ug/L 467500 93 80-120
Beryllium ug/L 484500 97 80-120
Cadmium ug/L 458500 92 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 471500 94 80-120
Copper ug/L 499500 100 80-120
Iron ug/L 48905000 98 80-120
Lead ug/L 460500 92 80-120
Manganese ug/L 479500 96 80-120
Nickel ug/L 489500 98 80-120
Selenium ug/L 478500 96 80-120
Silver ug/L 242250 97 80-120
Thallium ug/L 481500 96 80-120
Tin ug/L 467500 93 80-120
Vanadium ug/L 471500 94 80-120
Zinc ug/L 472500 94 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891488MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323137018
1891489
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 93 75-12593 0 25500ND465 467
Arsenic ug/L 500 94 75-12593 1 25500ND470 464
Barium ug/L 500 93 75-12592 1 25500ND465 461
Beryllium ug/L 500 98 75-12596 2 25500ND491 482
Cadmium ug/L 500 91 75-12590 1 25500ND453 451
Chromium ug/L 500 94 75-12594 0 25500ND470 470
Cobalt ug/L 500 94 75-12593 0 25500ND469 468
Copper ug/L 500 99 75-125100 0 25500ND498 499
Iron ug/L 5000 99 75-12597 2 255000ND4940 4840
Lead ug/L 500 92 75-12592 0 25500ND458 459
Manganese ug/L 500 96 75-12596 0 25500ND480 479
Nickel ug/L 500 98 75-12598 0 25500ND490 489
Selenium ug/L 500 95 75-12596 1 25500ND475 478
Silver ug/L 250 97 75-12597 0 25250ND242 242
Thallium ug/L 500 96 75-12597 1 255005.3J 484 490
Tin ug/L 500 93 75-12593 0 25500ND465 466
Vanadium ug/L 500 95 75-12594 0 25500ND473 472
Zinc ug/L 500 93 75-12594 0 25500ND471 471
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341130
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892549
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/15/16 23:170.33
1,1,1-Trichloroethane ug/L ND 1.0 12/15/16 23:170.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/15/16 23:170.40
1,1,2-Trichloroethane ug/L ND 1.0 12/15/16 23:170.29
1,1-Dichloroethane ug/L ND 5.0 12/15/16 23:170.32
1,1-Dichloroethene ug/L ND 5.0 12/15/16 23:170.56
1,1-Dichloropropene ug/L ND 5.0 12/15/16 23:170.49
1,2,3-Trichloropropane ug/L ND 1.0 12/15/16 23:170.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/15/16 23:170.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/15/16 23:172.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/15/16 23:170.27
1,2-Dichlorobenzene ug/L ND 5.0 12/15/16 23:170.30
1,2-Dichloroethane ug/L ND 1.0 12/15/16 23:170.24
1,2-Dichloropropane ug/L ND 1.0 12/15/16 23:170.27
1,3-Dichlorobenzene ug/L ND 5.0 12/15/16 23:170.24
1,3-Dichloropropane ug/L ND 1.0 12/15/16 23:170.28
1,4-Dichlorobenzene ug/L ND 1.0 12/15/16 23:170.33
2,2-Dichloropropane ug/L ND 15.0 12/15/16 23:170.13
2-Butanone (MEK)ug/L ND 100 12/15/16 23:170.96
2-Hexanone ug/L ND 50.0 12/15/16 23:170.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/15/16 23:170.33
Acetone ug/L ND 100 12/15/16 23:1710.0
Acetonitrile ug/L ND 55.0 12/15/16 23:172.2
Acrolein ug/L ND 53.0 12/15/16 23:171.6
Acrylonitrile ug/L ND 200 12/15/16 23:171.9
Allyl chloride ug/L ND 10.0 12/15/16 23:171.5
Benzene ug/L ND 1.0 12/15/16 23:170.25
Bromochloromethane ug/L ND 3.0 12/15/16 23:170.17
Bromodichloromethane ug/L ND 1.0 12/15/16 23:170.18
Bromoform ug/L ND 3.0 12/15/16 23:170.26
Bromomethane ug/L ND 10.0 12/15/16 23:170.29
Carbon disulfide ug/L ND 100 12/15/16 23:171.2
Carbon tetrachloride ug/L ND 1.0 12/15/16 23:170.25
Chlorobenzene ug/L ND 3.0 12/15/16 23:170.23
Chloroethane ug/L ND 10.0 12/15/16 23:170.54
Chloroform ug/L ND 5.0 12/15/16 23:170.14
Chloromethane ug/L ND 1.0 12/15/16 23:170.11
Chloroprene ug/L ND 20.0 12/15/16 23:170.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:170.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:170.13
Dibromochloromethane ug/L ND 3.0 12/15/16 23:170.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892549
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/15/16 23:170.21
Dichlorodifluoromethane ug/L ND 5.0 12/15/16 23:170.21
Ethyl methacrylate ug/L ND 10.0 12/15/16 23:170.20
Ethylbenzene ug/L ND 1.0 12/15/16 23:170.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/15/16 23:170.71
Iodomethane ug/L ND 10.0 12/15/16 23:170.32
Isobutanol ug/L ND 100 12/15/16 23:1735.0
Methacrylonitrile ug/L ND 100 12/15/16 23:170.93
Methyl methacrylate ug/L ND 30.0 12/15/16 23:172.0
Methylene Chloride ug/L ND 1.0 12/15/16 23:170.97
Naphthalene ug/L ND 10.0 12/15/16 23:170.24
Propionitrile ug/L ND 150 12/15/16 23:173.6
Styrene ug/L ND 1.0 12/15/16 23:170.26
Tetrachloroethene ug/L ND 1.0 12/15/16 23:170.46
Tetrahydrofuran ug/L ND 10.0 12/15/16 23:173.1
Toluene ug/L ND 1.0 12/15/16 23:170.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:170.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:170.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/15/16 23:171.0
Trichloroethene ug/L ND 1.0 12/15/16 23:170.47
Trichlorofluoromethane ug/L ND 1.0 12/15/16 23:170.20
Vinyl acetate ug/L ND 50.0 12/15/16 23:170.35
Vinyl chloride ug/L ND 1.0 12/15/16 23:170.62
Xylene (Total)ug/L ND 5.0 12/15/16 23:170.66
1,2-Dichloroethane-d4 (S)%100 70-130 12/15/16 23:17
4-Bromofluorobenzene (S)%94 70-130 12/15/16 23:17
Toluene-d8 (S)%101 70-130 12/15/16 23:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892550LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.950 94 80-125
1,1,1-Trichloroethane ug/L 48.450 97 71-129
1,1,2,2-Tetrachloroethane ug/L 50.150 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 51.750 103 73-126
1,1-Dichloroethene ug/L 54.150 108 66-135
1,1-Dichloropropene ug/L 53.150 106 74-135
1,2,3-Trichloropropane ug/L 48.250 96 75-130
1,2,4-Trichlorobenzene ug/L 49.250 98 75-134
1,2-Dibromo-3-chloropropane ug/L 48.750 97 71-133
1,2-Dibromoethane (EDB)ug/L 48.650 97 83-124
1,2-Dichlorobenzene ug/L 48.950 98 80-133
1,2-Dichloroethane ug/L 47.550 95 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892550LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 50.750 101 75-132
1,3-Dichlorobenzene ug/L 48.250 96 77-130
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 47.750 95 78-130
2,2-Dichloropropane ug/L 48.050 96 40-160
2-Butanone (MEK)ug/L 112100 112 61-144
2-Hexanone ug/L 111100 111 68-143
4-Methyl-2-pentanone (MIBK)ug/L 109100 109 72-135
Acetone ug/L 105100 105 48-146
Acetonitrile ug/L 618500 124 62-150
Acrolein ug/L 349250 140 24-160
Acrylonitrile ug/L 289250 115 40-160
Allyl chloride ug/L 52.250 104 66-137
Benzene ug/L 51.150 102 80-125
Bromochloromethane ug/L 51.250 102 71-125
Bromodichloromethane ug/L 49.550 99 78-124
Bromoform ug/L 46.050 92 71-128
Bromomethane ug/L 38.250 76 40-160
Carbon disulfide ug/L 58.7J50 117 50-160
Carbon tetrachloride ug/L 46.650 93 69-131
Chlorobenzene ug/L 48.150 96 81-122
Chloroethane ug/L 51.450 103 39-148
Chloroform ug/L 48.550 97 73-127
Chloromethane ug/L 52.050 104 44-146
Chloroprene ug/L 50.650 101 75-145
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.750 103 72-132
Dibromochloromethane ug/L 48.850 98 78-125
Dibromomethane ug/L 47.350 95 82-120
Dichlorodifluoromethane ug/L 45.650 91 34-157
Ethyl methacrylate ug/L 53.950 108 82-121
Ethylbenzene ug/L 48.150 96 79-121
Hexachloro-1,3-butadiene ug/L 49.750 99 72-131
Iodomethane ug/L 95.8100 96 39-154
Isobutanol ug/L 11201000 112 34-160
Methacrylonitrile ug/L 543500 109 74-134
Methyl methacrylate ug/L 55.050 110 84-124
Methylene Chloride ug/L 51.950 104 64-133
Naphthalene ug/L 49.350 99 73-133
Propionitrile ug/L 582500 116 73-140
Styrene ug/L 48.750 97 84-126
Tetrachloroethene ug/L 43.550 87 78-122
Tetrahydrofuran ug/L 603500 121 69-148
Toluene ug/L 48.650 97 80-121
trans-1,2-Dichloroethene ug/L 53.050 106 71-127
trans-1,3-Dichloropropene ug/L 51.650 103 69-141
trans-1,4-Dichloro-2-butene ug/L 47.0J50 94 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892550LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 47.150 94 78-122
Trichlorofluoromethane ug/L 52.850 106 53-137
Vinyl acetate ug/L 113100 113 40-160
Vinyl chloride ug/L 44.250 88 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892551MATRIX SPIKE SAMPLE:
MSSpike
Result
92323278004
1,1,1,2-Tetrachloroethane ug/L 16.120 80 70-130ND
1,1,1-Trichloroethane ug/L 17.520 88 70-130ND
1,1,2,2-Tetrachloroethane ug/L 16.520 82 70-130ND
1,1,2-Trichloroethane ug/L 16.720 84 70-130ND
1,1-Dichloroethane ug/L 19.120 95 70-130ND
1,1-Dichloroethene ug/L 20.320 101 70-166ND
1,1-Dichloropropene ug/L 19.320 97 70-130ND
1,2,3-Trichloropropane ug/L 16.220 81 70-130ND
1,2,4-Trichlorobenzene ug/L 15.320 76 70-130ND
1,2-Dibromo-3-chloropropane ug/L 15.520 77 70-130ND
1,2-Dibromoethane (EDB)ug/L 16.120 80 70-130ND
1,2-Dichlorobenzene ug/L 16.320 82 70-130ND
1,2-Dichloroethane ug/L 17.120 85 70-130ND
1,2-Dichloropropane ug/L 17.820 89 70-130ND
1,3-Dichlorobenzene ug/L 16.020 80 70-130ND
1,3-Dichloropropane ug/L 17.220 86 70-130ND
1,4-Dichlorobenzene ug/L 16.620 80 70-1300.60J
2,2-Dichloropropane ug/L 15.320 76 70-130ND
2-Butanone (MEK)ug/L 39.1J40 98 70-130ND
2-Hexanone ug/L 37.2J40 93 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 35.3J40 88 70-130ND
Acetone ug/L 37.5J40 94 70-130ND
Acetonitrile ug/L 216200 108 70-130ND
Acrolein ug/L 102100 102 70-130ND
Acrylonitrile ug/L 102J100 102 70-130ND
Allyl chloride ug/L 18.820 94 70-130ND
Benzene ug/L 18.120 90 70-148ND
Bromochloromethane ug/L 17.920 89 70-130ND
Bromodichloromethane ug/L 16.820 84 70-130ND
Bromoform ug/L 14.820 74 70-130ND
Bromomethane ug/L 15.220 76 70-130ND
Carbon disulfide ug/L 22.0J20 110 70-130ND
Carbon tetrachloride ug/L 16.820 84 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892551MATRIX SPIKE SAMPLE:
MSSpike
Result
92323278004
Chlorobenzene ug/L 16.920 85 70-146ND
Chloroethane ug/L 22.120 110 70-130ND
Chloroform ug/L 18.020 90 70-130ND
Chloromethane ug/L 19.420 97 70-130ND
Chloroprene ug/L 18.1J20 91 70-130ND
cis-1,2-Dichloroethene ug/L 23.520 92 70-1305.2
cis-1,3-Dichloropropene ug/L 15.920 80 70-130ND
Dibromochloromethane ug/L 15.820 79 70-130ND
Dibromomethane ug/L 15.920 80 70-130ND
Dichlorodifluoromethane ug/L 18.220 91 70-130ND
Ethyl methacrylate ug/L 17.120 85 70-130ND
Ethylbenzene ug/L 17.020 85 70-130ND
Hexachloro-1,3-butadiene ug/L 16.020 80 70-130ND
Iodomethane ug/L 33.140 83 70-130ND
Isobutanol ug/L 383400 96 70-130ND
Methacrylonitrile ug/L 190200 95 70-130ND
Methyl methacrylate ug/L 17.5J20 87 70-130ND
Methylene Chloride ug/L 17.820 89 70-130ND
Naphthalene ug/L 14.920 75 70-130ND
Propionitrile ug/L 203200 102 70-130ND
Styrene ug/L 16.420 82 70-130ND
Tetrachloroethene ug/L 15.320 77 70-130ND
Tetrahydrofuran ug/L 209200 105 70-130ND
Toluene ug/L 17.320 86 70-155ND
trans-1,2-Dichloroethene ug/L 19.620 98 70-130ND
trans-1,3-Dichloropropene ug/L 15.720 79 70-130ND
trans-1,4-Dichloro-2-butene ug/L 12.7J M12063 70-130ND
Trichloroethene ug/L 16.820 84 69-151ND
Trichlorofluoromethane ug/L 20.420 102 70-130ND
Vinyl acetate ug/L 29.2J40 73 70-130ND
Vinyl chloride ug/L 17.520 86 70-130ND
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323278005
1892552SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323278005
1892552SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 0.53J 300.51J
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 1.9J 4 301.9J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323278005
1892552SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%103 1102
4-Bromofluorobenzene (S)%94 292
Toluene-d8 (S)%99 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341110
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892410
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDE ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDT ug/L ND 0.10 12/16/16 12:470.050
Aldrin ug/L ND 0.050 12/16/16 12:470.050
alpha-BHC ug/L ND 0.050 12/16/16 12:470.050
beta-BHC ug/L ND 0.050 12/16/16 12:470.050
Chlordane (Technical)ug/L ND 0.50 12/16/16 12:470.20
delta-BHC ug/L ND 0.050 12/16/16 12:470.050
Dieldrin ug/L ND 0.075 12/16/16 12:470.050
Endosulfan I ug/L ND 0.10 12/16/16 12:470.050
Endosulfan II ug/L ND 0.10 12/16/16 12:470.050
Endosulfan sulfate ug/L ND 0.10 12/16/16 12:470.050
Endrin ug/L ND 0.10 12/16/16 12:470.050
Endrin aldehyde ug/L ND 0.10 12/16/16 12:470.050
gamma-BHC (Lindane)ug/L ND 0.050 12/16/16 12:470.050
Heptachlor ug/L ND 0.050 12/16/16 12:470.050
Heptachlor epoxide ug/L ND 0.075 12/16/16 12:470.050
Methoxychlor ug/L ND 1.0 12/16/16 12:470.15
Toxaphene ug/L ND 1.5 12/16/16 12:470.20
Decachlorobiphenyl (S)%108 20-130 12/16/16 12:47
Tetrachloro-m-xylene (S)%97 20-130 12/16/16 12:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.25.25 99 20-150
4,4'-DDE ug/L 0.23.25 92 20-150
4,4'-DDT ug/L 0.25.25 99 20-150
Aldrin ug/L 0.19.25 78 20-150
alpha-BHC ug/L 0.22.25 90 20-150
beta-BHC ug/L 0.24.25 96 20-150
delta-BHC ug/L 0.24.25 98 20-150
Dieldrin ug/L 0.24.25 96 20-150
Endosulfan I ug/L 0.25.25 102 20-150
Endosulfan II ug/L 0.26.25 107 20-150
Endosulfan sulfate ug/L 0.27.25 109 20-150
Endrin ug/L 0.27.25 108 20-150
Endrin aldehyde ug/L 0.24.25 96 20-150
gamma-BHC (Lindane)ug/L 0.23.25 91 20-150
Heptachlor ug/L 0.20.25 82 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 94 20-150
Methoxychlor ug/L 0.87J.74 117 20-150
Decachlorobiphenyl (S)%99 20-130
Tetrachloro-m-xylene (S)%89 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892412MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1892413
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 92 20-15087 6 30.5ND 0.46 0.43
4,4'-DDE ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
4,4'-DDT ug/L .5 93 20-15086 8 30.5ND 0.46 0.42
Aldrin ug/L .5 80 20-15083 4 30.5ND 0.39 0.41
alpha-BHC ug/L .5 88 20-15086 2 30.5ND 0.43 0.42
beta-BHC ug/L .5 96 20-15092 4 30.5ND 0.48 0.46
delta-BHC ug/L .5 102 20-15098 5 30.5ND 0.51 0.48
Dieldrin ug/L .5 89 20-15085 5 30.5ND 0.44 0.42
Endosulfan I ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
Endosulfan II ug/L .5 98 20-15095 4 30.5ND 0.49 0.47
Endosulfan sulfate ug/L .5 101 20-15096 5 30.5ND 0.50 0.48
Endrin ug/L .5 95 20-15090 5 30.5ND 0.47 0.45
Endrin aldehyde ug/L .5 82 20-15082 0 30.5ND 0.41 0.41
gamma-BHC (Lindane)ug/L .5 92 20-15088 4 30.5ND 0.45 0.44
Heptachlor ug/L .5 84 20-15082 2 30.5ND 0.42 0.41
Heptachlor epoxide ug/L .5 93 20-15089 5 30.5ND 0.46 0.44
Methoxychlor ug/L 1.5 105 20-15098 7 301.5ND 1.6J 1.5J
Decachlorobiphenyl (S)%45 20-13045
Tetrachloro-m-xylene (S)%84 20-13085
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341274
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893343
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/19/16 13:170.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/19/16 13:170.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/19/16 13:170.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/19/16 13:170.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/19/16 13:170.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/19/16 13:170.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/19/16 13:170.50
Decachlorobiphenyl (S)%92 10-132 12/19/16 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893344LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1893345
PCB-1016 (Aroclor 1016)ug/L 4.85 95 50-150904.5 6 30
PCB-1260 (Aroclor 1260)ug/L 5.55 111 50-1501035.1 8 30
Decachlorobiphenyl (S)%82 10-13279
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
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9800 Kincey Ave. Suite 100
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Page 54 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339306
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1820541
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/21/16 10:550.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/21/16 10:550.049
2,4-D ug/L ND 0.94 12/21/16 10:550.22
Dinoseb ug/L ND 0.19 12/21/16 10:550.057
2,4-DCAA (S)%86 39-139 12/21/16 10:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1820542LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 1.31.2 106 37-133
2,4,5-TP (Silvex)ug/L 1.01.2 87 53-134
2,4-D ug/L 6.16 102 35-124
Dinoseb ug/L 0.971.2 81 13-116
2,4-DCAA (S)%87 39-139
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1820630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1820631
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 118 37-133114 3 401.2ND 1.4 1.4
2,4,5-TP (Silvex)ug/L 1.2 99 53-13495 3 401.2ND 1.2 1.1
2,4-D ug/L 6 114 35-124111 1 406ND6.8 6.7
Dinoseb ug/L 1.2 89 13-11685 4 401.2ND 1.1 1.0
2,4-DCAA (S)%94 39-13993 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341825
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/22/16 10:331.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/22/16 10:331.1
1,3-Dinitrobenzene ug/L ND 20.0 12/22/16 10:331.5
1,4-Naphthoquinone ug/L ND 10.0 12/22/16 10:331.8
1-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.96
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 12/22/16 10:331.6
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/22/16 10:332.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/22/16 10:332.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/22/16 10:331.9
2,4-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.7
2,4-Dimethylphenol ug/L ND 10.0 12/22/16 10:332.2
2,4-Dinitrophenol ug/L ND 50.0 12/22/16 10:336.5
2,4-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.2
2,6-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.8
2,6-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.7
2-Acetylaminofluorene ug/L ND 20.0 12/22/16 10:330.84
2-Chloronaphthalene ug/L ND 10.0 12/22/16 10:332.2
2-Chlorophenol ug/L ND 10.0 12/22/16 10:331.5
2-Methylnaphthalene ug/L ND 10.0 12/22/16 10:330.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/22/16 10:331.7
2-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.98
2-Nitroaniline ug/L ND 50.0 12/22/16 10:332.8
2-Nitrophenol ug/L ND 10.0 12/22/16 10:331.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/22/16 10:331.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/22/16 10:331.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/22/16 10:332.1
3-Methylcholanthrene ug/L ND 10.0 12/22/16 10:330.82
3-Nitroaniline ug/L ND 50.0 12/22/16 10:332.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/22/16 10:331.7
4-Aminobiphenyl ug/L ND 20.0 12/22/16 10:330.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/22/16 10:331.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/22/16 10:334.2
4-Chloroaniline ug/L ND 20.0 12/22/16 10:333.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/22/16 10:332.1
4-Nitroaniline ug/L ND 20.0 12/22/16 10:332.5
4-Nitrophenol ug/L ND 50.0 12/22/16 10:335.8
5-Nitro-o-toluidine ug/L ND 10.0 12/22/16 10:331.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/22/16 10:330.77
Acenaphthene ug/L ND 10.0 12/22/16 10:330.25
Acenaphthylene ug/L ND 10.0 12/22/16 10:330.21
Acetophenone ug/L ND 10.0 12/22/16 10:332.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
Anthracene ug/L ND 10.0 12/22/16 10:330.14
Benzo(a)anthracene ug/L ND 10.0 12/22/16 10:330.33
Benzo(a)pyrene ug/L ND 10.0 12/22/16 10:330.30
Benzo(b)fluoranthene ug/L ND 10.0 12/22/16 10:330.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/22/16 10:330.38
Benzo(k)fluoranthene ug/L ND 10.0 12/22/16 10:330.43
Benzyl alcohol ug/L ND 20.0 12/22/16 10:333.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/22/16 10:331.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/22/16 10:331.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/22/16 10:330.85
Butylbenzylphthalate ug/L ND 10.0 12/22/16 10:330.75
Chlorobenzilate ug/L ND 10.0 12/22/16 10:330.72
Chrysene ug/L ND 10.0 12/22/16 10:330.21
Di-n-butylphthalate ug/L ND 10.0 12/22/16 10:331.1
Di-n-octylphthalate ug/L ND 10.0 12/22/16 10:330.86
Diallate ug/L ND 10.0 12/22/16 10:331.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/22/16 10:330.55
Dibenzofuran ug/L ND 10.0 12/22/16 10:331.8
Diethylphthalate ug/L ND 6000 12/22/16 10:331.3
Dimethoate ug/L ND 20.0 12/22/16 10:330.92
Dimethylphthalate ug/L ND 10.0 12/22/16 10:331.5
Diphenylamine ug/L ND 10.0 12/22/16 10:331.3
Disulfoton ug/L ND 10.0 12/22/16 10:331.4
Ethyl methanesulfonate ug/L ND 20.0 12/22/16 10:331.8
Famphur ug/L ND 20.0 12/22/16 10:331.7
Fluoranthene ug/L ND 10.0 12/22/16 10:330.21
Fluorene ug/L ND 10.0 12/22/16 10:330.21
Hexachlorobenzene ug/L ND 10.0 12/22/16 10:331.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/22/16 10:331.8
Hexachloroethane ug/L ND 10.0 12/22/16 10:331.5
Hexachloropropene ug/L ND 10.0 12/22/16 10:331.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/22/16 10:330.29
Isodrin ug/L ND 20.0 12/22/16 10:332.0
Isophorone ug/L ND 10.0 12/22/16 10:331.8
Isosafrole ug/L ND 10.0 12/22/16 10:331.8
Kepone ug/L ND 20.0 12/22/16 10:333.1
Methapyrilene ug/L ND 100 12/22/16 10:332.7
Methyl methanesulfonate ug/L ND 10.0 12/22/16 10:331.3
Methyl parathion ug/L ND 10.0 12/22/16 10:331.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/22/16 10:332.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/22/16 10:332.1
N-Nitrosodiethylamine ug/L ND 20.0 12/22/16 10:331.8
N-Nitrosodimethylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/22/16 10:331.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/22/16 10:331.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/22/16 10:332.5
Nitrobenzene ug/L ND 10.0 12/22/16 10:331.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/22/16 10:331.8
O-Toluidine ug/L ND 10.0 12/22/16 10:331.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/22/16 10:330.35
p-Phenylenediamine ug/L ND 10.0 12/22/16 10:330.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/22/16 10:331.1
Pentachlorobenzene ug/L ND 10.0 12/22/16 10:332.0
Pentachloronitrobenzene ug/L ND 20.0 12/22/16 10:331.0
Pentachlorophenol ug/L ND 25.0 12/22/16 10:332.3
Phenacetin ug/L ND 20.0 12/22/16 10:330.97
Phenanthrene ug/L ND 10.0 12/22/16 10:330.22
Phenol ug/L ND 10.0 12/22/16 10:331.7
Phorate ug/L ND 10.0 12/22/16 10:331.1
Pronamide ug/L ND 10.0 12/22/16 10:330.97
Pyrene ug/L ND 10.0 12/22/16 10:330.19
Safrole ug/L ND 10.0 12/22/16 10:331.5
Thionazin ug/L ND 20.0 12/22/16 10:331.2
2,4,6-Tribromophenol (S)%70 27-110 12/22/16 10:33
2-Fluorobiphenyl (S)%54 27-110 12/22/16 10:33
2-Fluorophenol (S)%26 12-110 12/22/16 10:33
Nitrobenzene-d5 (S)%50 21-110 12/22/16 10:33
Phenol-d6 (S)%23 10-110 12/22/16 10:33
Terphenyl-d14 (S)%71 31-107 12/22/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 33.650 67 16-129
1,3,5-Trinitrobenzene ug/L 43.250 86 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 37.450 75 31-120
1-Naphthalenamine ug/L 24.050 48 37-126
2,2'-Oxybis(1-chloropropane)ug/L 36.150 72 18-120
2,3,4,6-Tetrachlorophenol ug/L 56.550 113 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 41.050 82 42-120
2,4-Dichlorophenol ug/L 38.450 77 30-120
2,4-Dimethylphenol ug/L 38.750 77 29-111
2,4-Dinitrophenol ug/L 123250 49 19-132
2,4-Dinitrotoluene ug/L 42.350 85 58-128
2,6-Dichlorophenol ug/L 42.550 85 54-128
2,6-Dinitrotoluene ug/L 42.850 86 54-129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
2-Acetylaminofluorene ug/L 43.750 87 81-160
2-Chloronaphthalene ug/L 41.150 82 43-117
2-Chlorophenol ug/L 36.050 72 37-120
2-Methylnaphthalene ug/L 37.550 75 33-120
2-Methylphenol(o-Cresol)ug/L 25.350 51 31-120
2-Naphthalenamine ug/L 36.650 73 41-136
2-Nitroaniline ug/L 68.5100 69 48-121
2-Nitrophenol ug/L 37.350 75 25-116
3&4-Methylphenol(m&p Cresol)ug/L 38.850 78 23-120
3,3'-Dichlorobenzidine ug/L 86.0250 34 10-154
3,3'-Dimethylbenzidine ug/L 62.6100 63 10-157
3-Methylcholanthrene ug/L 47.750 95 65-130
3-Nitroaniline ug/L 82.5100 83 43-115
4,6-Dinitro-2-methylphenol ug/L 89.5100 89 44-124
4-Aminobiphenyl ug/L 33.650 67 21-125
4-Bromophenylphenyl ether ug/L 37.950 76 34-113
4-Chloro-3-methylphenol ug/L 73.5100 73 31-110
4-Chloroaniline ug/L 67.3100 67 20-120
4-Chlorophenylphenyl ether ug/L 37.750 75 34-116
4-Nitroaniline ug/L 89.4100 89 46-128
4-Nitrophenol ug/L 76.4250 31 11-120
5-Nitro-o-toluidine ug/L 42.150 84 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.250 94 47-124
Acenaphthene ug/L 39.450 79 48-114
Acenaphthylene ug/L 40.750 81 48-112
Acetophenone ug/L 32.650 65 24-120
Anthracene ug/L 41.650 83 57-118
Benzo(a)anthracene ug/L 41.350 83 56-121
Benzo(a)pyrene ug/L 45.750 91 55-127
Benzo(b)fluoranthene ug/L 44.150 88 53-128
Benzo(g,h,i)perylene ug/L 45.950 92 54-125
Benzo(k)fluoranthene ug/L 46.850 94 51-123
Benzyl alcohol ug/L 57.5100 57 27-120
bis(2-Chloroethoxy)methane ug/L 35.650 71 32-120
bis(2-Chloroethyl) ether ug/L 36.450 73 33-111
bis(2-Ethylhexyl)phthalate ug/L 48.250 96 50-145
Butylbenzylphthalate ug/L 47.650 95 54-138
Chlorobenzilate ug/L 45.250 90 65-132
Chrysene ug/L 41.350 83 58-127
Di-n-butylphthalate ug/L 47.250 94 56-125
Di-n-octylphthalate ug/L 49.350 99 50-134
Diallate ug/L 48.250 96 47-123
Dibenz(a,h)anthracene ug/L 47.150 94 53-129
Dibenzofuran ug/L 39.650 79 45-120
Diethylphthalate ug/L 43.4J50 87 53-120
Dimethoate ug/L 50.850 102 57-139
Dimethylphthalate ug/L 41.150 82 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 42.350 85 42-120
Disulfoton ug/L 50.050 100 49-156
Ethyl methanesulfonate ug/L 38.250 76 43-120
Famphur ug/L 45.6100 46 40-160
Fluoranthene ug/L 45.450 91 57-125
Fluorene ug/L 41.450 83 53-118
Hexachlorobenzene ug/L 39.850 80 49-116
Hexachlorocyclopentadiene ug/L 34.350 69 26-158
Hexachloroethane ug/L 29.350 59 30-114
Hexachloropropene ug/L 33.350 67 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.650 95 55-128
Isodrin ug/L 46.450 93 68-129
Isophorone ug/L 35.550 71 31-118
Isosafrole ug/L 32.650 65 48-107
Kepone ug/L 45.7100 46 10-124
Methapyrilene ug/L 51.7J50 103 40-160
Methyl methanesulfonate ug/L 25.350 51 25-114
Methyl parathion ug/L 51.750 103 58-137
N-Nitroso-di-n-butylamine ug/L 30.850 62 36-115
N-Nitroso-di-n-propylamine ug/L 38.050 76 32-119
N-Nitrosodiethylamine ug/L 38.250 76 47-115
N-Nitrosodimethylamine ug/L 24.850 50 13-120
N-Nitrosodiphenylamine ug/L 42.350 85 43-120
N-Nitrosomethylethylamine ug/L 33.450 67 39-120
N-Nitrosopiperidine ug/L 43.950 88 43-113
N-Nitrosopyrrolidine ug/L 35.650 71 32-110
Nitrobenzene ug/L 33.950 68 33-110
O,O,O-Triethylphosphorothioate ug/L 37.850 76 51-127
O-Toluidine ug/L 33.650 67 27-120
P-Dimethylaminoazobenzene ug/L 19.3100 19 10-120
p-Phenylenediamine ug/L 45.950 92 72-143
Parathion (Ethyl parathion)ug/L 50.750 101 56-140
Pentachlorobenzene ug/L 35.650 71 30-137
Pentachloronitrobenzene ug/L 49.950 100 70-124
Pentachlorophenol ug/L 89.3250 36 10-137
Phenacetin ug/L 46.650 93 60-130
Phenanthrene ug/L 41.150 82 57-117
Phenol ug/L 17.350 35 10-120
Phorate ug/L 51.650 103 55-126
Pronamide ug/L 51.550 103 75-124
Pyrene ug/L 39.350 79 55-122
Safrole ug/L 39.450 79 41-120
Thionazin ug/L 40.050 80 63-137
2,4,6-Tribromophenol (S)%43 27-110
2-Fluorobiphenyl (S)%36 27-110
2-Fluorophenol (S)%20 12-110
Nitrobenzene-d5 (S)%35 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%14 10-110
Terphenyl-d14 (S)%38 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
1,2,4,5-Tetrachlorobenzene ug/L 33.050 66 50-150ND
1,3,5-Trinitrobenzene ug/L 48.950 98 50-150ND
1,3-Dinitrobenzene ug/L 40.450 81 50-150ND
1,4-Naphthoquinone ug/L 33.950 68 50-150ND
1-Naphthalenamine ug/L 23.3 M15047 50-150ND
2,2'-Oxybis(1-chloropropane)ug/L 28.150 56 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 38.450 77 50-150ND
2,4,5-Trichlorophenol ug/L 27.650 55 19-105ND
2,4,6-Trichlorophenol ug/L 25.050 50 13-108ND
2,4-Dichlorophenol ug/L 34.450 69 29-111ND
2,4-Dimethylphenol ug/L 36.750 73 21-103ND
2,4-Dinitrophenol ug/L 28.1J250 11 10-109ND
2,4-Dinitrotoluene ug/L 37.650 75 27-104ND
2,6-Dichlorophenol ug/L 33.350 67 50-150ND
2,6-Dinitrotoluene ug/L 41.750 83 28-101ND
2-Acetylaminofluorene ug/L 40.550 81 50-150ND
2-Chloronaphthalene ug/L 43.950 88 14-102ND
2-Chlorophenol ug/L 31.250 62 16-110ND
2-Methylnaphthalene ug/L 39.850 80 13-110ND
2-Methylphenol(o-Cresol)ug/L 22.650 45 19-110ND
2-Naphthalenamine ug/L 30.350 61 50-150ND
2-Nitroaniline ug/L 59.8100 60 26-103ND
2-Nitrophenol ug/L 33.350 67 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 47.650 95 20-110ND
3,3'-Dichlorobenzidine ug/L 82.5250 33 25-112ND
3,3'-Dimethylbenzidine ug/L 53.4100 53 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 75.3100 75 29-110ND
4,6-Dinitro-2-methylphenol ug/L 51.8100 52 10-117ND
4-Aminobiphenyl ug/L 34.950 70 50-150ND
4-Bromophenylphenyl ether ug/L 40.950 82 20-105ND
4-Chloro-3-methylphenol ug/L 64.1100 64 22-110ND
4-Chloroaniline ug/L 66.4100 66 20-100ND
4-Chlorophenylphenyl ether ug/L 41.850 84 19-102ND
4-Nitroaniline ug/L 99.6100 100 29-110ND
4-Nitrophenol ug/L 36.2J250 14 10-110ND
5-Nitro-o-toluidine ug/L 42.950 86 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 43.750 87 50-150ND
Acenaphthene ug/L 38.350 77 17-100ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
Acenaphthylene ug/L 39.650 79 21-100ND
Acetophenone ug/L 30.850 62 50-150ND
Anthracene ug/L 40.550 81 24-109ND
Benzo(a)anthracene ug/L 39.450 79 22-117ND
Benzo(a)pyrene ug/L 42.050 84 23-104ND
Benzo(b)fluoranthene ug/L 41.050 82 23-103ND
Benzo(g,h,i)perylene ug/L 42.350 85 18-111ND
Benzo(k)fluoranthene ug/L 42.750 85 22-113ND
Benzyl alcohol ug/L 48.7100 49 19-101ND
bis(2-Chloroethoxy)methane ug/L 32.350 65 22-110ND
bis(2-Chloroethyl) ether ug/L 33.950 68 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 42.550 85 23-102ND
Butylbenzylphthalate ug/L 41.950 84 25-110ND
Chlorobenzilate ug/L 42.450 84 50-150ND
Chrysene ug/L 39.850 80 23-115ND
Di-n-butylphthalate ug/L 44.150 88 26-110ND
Di-n-octylphthalate ug/L 43.850 88 22-110ND
Diallate ug/L 46.450 93 50-150ND
Dibenz(a,h)anthracene ug/L 41.250 82 21-112ND
Dibenzofuran ug/L 40.450 81 19-102ND
Diethylphthalate ug/L 39.2J50 78 29-110ND
Dimethoate ug/L 50.950 102 50-150ND
Dimethylphthalate ug/L 42.950 86 27-110ND
Diphenylamine ug/L 49.550 99 50-150ND
Disulfoton ug/L 41.050 82 50-150ND
Ethyl methanesulfonate ug/L 34.450 69 50-150ND
Famphur ug/L 51.1100 51 50-150ND
Fluoranthene ug/L 45.150 90 23-112ND
Fluorene ug/L 46.050 92 22-104ND
Hexachlorobenzene ug/L 42.750 85 21-116ND
Hexachlorocyclopentadiene ug/L 33.950 68 10-110ND
Hexachloroethane ug/L 29.550 59 10-110ND
Hexachloropropene ug/L 37.550 75 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 43.150 86 20-113ND
Isodrin ug/L 45.950 92 50-150ND
Isophorone ug/L 31.950 64 50-150ND
Isosafrole ug/L 31.950 64 50-150ND
Kepone ug/L 60.3100 60 50-150ND
Methapyrilene ug/L 46.8J50 94 50-150ND
Methyl methanesulfonate ug/L 26.950 54 50-150ND
Methyl parathion ug/L 46.350 93 50-150ND
N-Nitroso-di-n-butylamine ug/L 30.250 60 50-150ND
N-Nitroso-di-n-propylamine ug/L 32.750 65 21-105ND
N-Nitrosodiethylamine ug/L 43.250 86 50-150ND
N-Nitrosodimethylamine ug/L 23.050 46 10-110ND
N-Nitrosodiphenylamine ug/L 49.550 99 23-107ND
N-Nitrosomethylethylamine ug/L 31.950 64 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.050 62 50-150ND
Nitrobenzene ug/L 28.250 56 20-110ND
O,O,O-Triethylphosphorothioate ug/L 39.250 78 50-150ND
O-Toluidine ug/L 28.750 57 50-150ND
P-Dimethylaminoazobenzene ug/L 18.4 M110018 50-150ND
p-Phenylenediamine ug/L 43.850 88 50-150ND
Parathion (Ethyl parathion)ug/L 45.450 91 50-150ND
Pentachlorobenzene ug/L 34.750 69 50-150ND
Pentachloronitrobenzene ug/L 43.150 86 50-150ND
Pentachlorophenol ug/L 32.6250 13 10-118ND
Phenacetin ug/L 45.550 91 50-150ND
Phenanthrene ug/L 41.250 82 24-106ND
Phenol ug/L 14.750 29 12-110ND
Phorate ug/L 46.150 92 50-150ND
Pronamide ug/L 49.050 98 50-150ND
Pyrene ug/L 35.650 71 24-114ND
Safrole ug/L 40.950 82 50-150ND
Thionazin ug/L 42.550 85 50-150ND
2,4,6-Tribromophenol (S)%70 27-110
2-Fluorobiphenyl (S)%75 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%56 21-110
Phenol-d6 (S)%23 10-110
Terphenyl-d14 (S)%68 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,2'-Oxybis(1-chloropropane)ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%68 169
2-Fluorobiphenyl (S)%58 1165
2-Fluorophenol (S)%22 2227
Nitrobenzene-d5 (S)%51 654
Phenol-d6 (S)%15 1818
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Terphenyl-d14 (S)%70 473
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341966
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897103
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/23/16 19:141000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897104LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4780050000 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1897105MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323122016
1897106
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 80-12098 0 255000096.7 mg/L 146000 146000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1897107MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238002
1897108
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 91 80-12091 0 2550000364 mg/L 410000 410000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341433
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894510
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/18/16 20:1025000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894511LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 230000250000 92 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323216029
1894512SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 344000 0 5343 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323257005
1894513SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 130000 1 5131000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341247
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893092
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/16/16 13:15100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893093LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 524J500 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893094MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323216024
1893095
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 87 80-12087 0 10500ND438J 436J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893096MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323216034
1893097
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 103 80-120102 1 10500ND513J 510J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341402
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894399
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/17/16 17:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894400LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238003
1894402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011590-110110 2 102000026.5 mg/L 49500J 48400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1894404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 99 90-11094 5 10200002.1 mg/L 22000J 21000J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342770
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1901305
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005, 92323257006
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 12/29/16 15:53500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1901306LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1970020000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901307MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991013
1901308
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000013490-110136 0 101000066.5 mg/L 79900 80000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901309MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1901310
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 98 90-110101 3 10100001.6 mg/L 11400 11700
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323257001, 92323257002, 92323257003, 92323257004, 92323257005
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
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Page 72 of 78
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323257001 341110 3412291203-MW10 EPA 3510 EPA 8081
92323257002 341110 3412291203-MW11 EPA 3510 EPA 8081
92323257003 341110 3412291203-MW12 EPA 3510 EPA 8081
92323257004 341110 3412291203-MW13 EPA 3510 EPA 8081
92323257005 341110 3412291203-MW16S EPA 3510 EPA 8081
92323257001 341274 3414911203-MW10 EPA 3510 EPA 8082
92323257002 341274 3414911203-MW11 EPA 3510 EPA 8082
92323257003 341274 3414911203-MW12 EPA 3510 EPA 8082
92323257004 341274 3414911203-MW13 EPA 3510 EPA 8082
92323257005 341274 3414911203-MW16S EPA 3510 EPA 8082
92323257001 339306 3398961203-MW10 EPA 8151 EPA 8151
92323257002 339306 3398961203-MW11 EPA 8151 EPA 8151
92323257003 339306 3398961203-MW12 EPA 8151 EPA 8151
92323257004 339306 3398961203-MW13 EPA 8151 EPA 8151
92323257005 339306 3398961203-MW16S EPA 8151 EPA 8151
92323257001 340971 3412201203-MW10 EPA 3010A EPA 6010
92323257002 340971 3412201203-MW11 EPA 3010A EPA 6010
92323257003 340971 3412201203-MW12 EPA 3010A EPA 6010
92323257004 340971 3412201203-MW13 EPA 3010A EPA 6010
92323257005 340971 3412201203-MW16S EPA 3010A EPA 6010
92323257006 340971 3412201203-MW16D EPA 3010A EPA 6010
92323257001 340993 3413831203-MW10 EPA 7470 EPA 7470
92323257002 340993 3413831203-MW11 EPA 7470 EPA 7470
92323257003 340993 3413831203-MW12 EPA 7470 EPA 7470
92323257004 340994 3413841203-MW13 EPA 7470 EPA 7470
92323257005 340994 3413841203-MW16S EPA 7470 EPA 7470
92323257006 340994 3413841203-MW16D EPA 7470 EPA 7470
92323257001 341825 3421661203-MW10 EPA 3510 EPA 8270
92323257002 341825 3421661203-MW11 EPA 3510 EPA 8270
92323257003 341825 3421661203-MW12 EPA 3510 EPA 8270
92323257004 341825 3421661203-MW13 EPA 3510 EPA 8270
92323257005 341825 3421661203-MW16S EPA 3510 EPA 8270
92323257001 3411301203-MW10 EPA 8260
92323257002 3411301203-MW11 EPA 8260
92323257003 3411301203-MW12 EPA 8260
92323257004 3411301203-MW13 EPA 8260
92323257005 3411301203-MW16S EPA 8260
92323257006 3411301203-MW16D EPA 8260
92323257001 3419661203-MW10 SM 2320B
92323257002 3419661203-MW11 SM 2320B
92323257003 3419661203-MW12 SM 2320B
92323257004 3419661203-MW13 SM 2320B
92323257005 3419661203-MW16S SM 2320B
92323257006 3419661203-MW16D SM 2320B
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 04:46 PM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323257
JOHNS R. C&D/MSWLF-COMPL.
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323257001 3414331203-MW10 SM 2540C
92323257002 3414331203-MW11 SM 2540C
92323257003 3414331203-MW12 SM 2540C
92323257004 3414331203-MW13 SM 2540C
92323257005 3414331203-MW16S SM 2540C
92323257006 3414331203-MW16D SM 2540C
92323257001 3412471203-MW10 SM 4500-S2D
92323257002 3412471203-MW11 SM 4500-S2D
92323257003 3412471203-MW12 SM 4500-S2D
92323257004 3412471203-MW13 SM 4500-S2D
92323257005 3412471203-MW16S SM 4500-S2D
92323257001 3414021203-MW10 EPA 300.0
92323257002 3414021203-MW11 EPA 300.0
92323257003 3414021203-MW12 EPA 300.0
92323257004 3414021203-MW13 EPA 300.0
92323257005 3414021203-MW16S EPA 300.0
92323257006 3414021203-MW16D EPA 300.0
92323257001 3427701203-MW10 SM 4500-Cl-E
92323257002 3427701203-MW11 SM 4500-Cl-E
92323257003 3427701203-MW12 SM 4500-Cl-E
92323257004 3427701203-MW13 SM 4500-Cl-E
92323257005 3427701203-MW16S SM 4500-Cl-E
92323257006 3427701203-MW16D SM 4500-Cl-E
92323257001 3425331203-MW10 SM 4500-CN-E
92323257002 3425331203-MW11 SM 4500-CN-E
92323257003 3425331203-MW12 SM 4500-CN-E
92323257004 3425331203-MW13 SM 4500-CN-E
92323257005 3425331203-MW16S SM 4500-CN-E
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Page 76 of 78
Page 77 of 78
Page 78 of 78
#=CL#
December 28, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323605
92323605
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Johns R. Add MW LFG
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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Page 1 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID Matrix Date Collected Date Received
92323605001 1203-MW15S Water 12/14/16 09:24 12/15/16 10:10
92323605002 1203-PZ12 Water 12/14/16 10:08 12/15/16 10:10
92323605003 1203-PZ30S Water 12/14/16 12:08 12/15/16 10:10
92323605004 1203-PZ31 Water 12/14/16 12:18 12/15/16 10:10
92323605005 1203-PZ35 Water 12/14/16 12:00 12/15/16 10:10
92323605006 1203-MW36 Water 12/14/16 11:16 12/15/16 10:10
92323605007 1203-MW38 Water 12/14/16 08:34 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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Page 3 of 36
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323605001 1203-MW15S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605002 1203-PZ12 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605003 1203-PZ30S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605004 1203-PZ31 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605005 1203-PZ35 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605006 1203-MW36 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605007 1203-MW38 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323605001 1203-MW15S
Methane 16700 ug/L 12/23/16 12:51 N2200RSK 175 Modified
Benzene 0.85J ug/L 12/21/16 18:431.0EPA 8260
1,4-Dichlorobenzene 0.73J ug/L 12/21/16 18:431.0EPA 8260
1,1-Dichloroethane 0.85J ug/L 12/21/16 18:435.0EPA 8260
Tetrachloroethene 1.4 ug/L 12/21/16 18:431.0EPA 8260
Trichloroethene 0.81J ug/L 12/21/16 18:431.0EPA 8260
92323605004 1203-PZ31
Methane 27.0 ug/L 12/22/16 17:06 N210.0RSK 175 Modified
92323605006 1203-MW36
Methane 32200 ug/L 12/23/16 12:35 N2400RSK 175 Modified
Benzene 5.5 ug/L 12/21/16 20:091.0EPA 8260
1,4-Dichlorobenzene 15.8 ug/L 12/21/16 20:091.0EPA 8260
1,1-Dichloroethane 4.4J ug/L 12/21/16 20:095.0EPA 8260
1,2-Dichloroethane 0.77J ug/L 12/21/16 20:091.0EPA 8260
92323605007 1203-MW38
Methane 15300 ug/L 12/23/16 11:01 N2100RSK 175 Modified
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW15S Lab ID: 92323605001 Collected: 12/14/16 09:24 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 16700 ug/L 12/23/16 12:51 74-82-8 N2200 200 20
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 0.85J ug/L 12/21/16 18:43 71-43-21.0 0.25 1
1,4-Dichlorobenzene 0.73J ug/L 12/21/16 18:43 106-46-71.0 0.33 1
1,1-Dichloroethane 0.85J ug/L 12/21/16 18:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 18:43 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 18:43 75-09-21.0 0.97 1
Tetrachloroethene 1.4 ug/L 12/21/16 18:43 127-18-41.0 0.46 1
Trichloroethene 0.81J ug/L 12/21/16 18:43 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 18:43 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 18:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 18:43 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 18:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ12 Lab ID: 92323605002 Collected: 12/14/16 10:08 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/23/16 12:19 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:00 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:00 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:00 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:00 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:00 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:00 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:00 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %12/21/16 19:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %12/21/16 19:00 17060-07-070-130 1
Toluene-d8 (S)97 %12/21/16 19:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ30S Lab ID: 92323605003 Collected: 12/14/16 12:08 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/22/16 16:51 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:18 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:18 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:18 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:18 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:18 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:18 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:18 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 19:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/21/16 19:18 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 19:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ31 Lab ID: 92323605004 Collected: 12/14/16 12:18 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 27.0 ug/L 12/22/16 17:06 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:35 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:35 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:35 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:35 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:35 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:35 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:35 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 19:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/21/16 19:35 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 19:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 9 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ35 Lab ID: 92323605005 Collected: 12/14/16 12:00 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/22/16 17:22 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:52 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:52 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:52 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:52 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:52 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:52 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:52 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:52 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 19:52 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/21/16 19:52 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 19:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW36 Lab ID: 92323605006 Collected: 12/14/16 11:16 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 32200 ug/L 12/23/16 12:35 74-82-8 N2400 400 40
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 5.5 ug/L 12/21/16 20:09 71-43-21.0 0.25 1
1,4-Dichlorobenzene 15.8 ug/L 12/21/16 20:09 106-46-71.0 0.33 1
1,1-Dichloroethane 4.4J ug/L 12/21/16 20:09 75-34-35.0 0.32 1
1,2-Dichloroethane 0.77J ug/L 12/21/16 20:09 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 20:09 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 20:09 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 20:09 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 20:09 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 20:09 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/21/16 20:09 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 20:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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[phone]
Page 11 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW38 Lab ID: 92323605007 Collected: 12/14/16 08:34 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 15300 ug/L 12/23/16 11:01 74-82-8 N2100 100 10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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[phone]
Page 12 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342220
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006, 92323605007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898651
Associated Lab Samples:92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006, 92323605007
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 N212/22/16 14:0410.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898652LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 376 N239695 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1898653MATRIX SPIKE SAMPLE:
MSSpike
Result
92324178004
Methane ug/L 449 N2396113 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92324178005
1898654SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 13 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342009
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897422
Associated Lab Samples:92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006
Matrix: Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 12/21/16 16:100.32
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:100.24
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:100.33
Benzene ug/L ND 1.0 12/21/16 16:100.25
Methylene Chloride ug/L ND 1.0 12/21/16 16:100.97
Tetrachloroethene ug/L ND 1.0 12/21/16 16:100.46
Trichloroethene ug/L ND 1.0 12/21/16 16:100.47
Vinyl chloride ug/L ND 1.0 12/21/16 16:100.62
1,2-Dichloroethane-d4 (S)%100 70-130 12/21/16 16:10
4-Bromofluorobenzene (S)%107 70-130 12/21/16 16:10
Toluene-d8 (S)%99 70-130 12/21/16 16:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897423LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 50.150 100 73-126
1,2-Dichloroethane ug/L 46.450 93 67-128
1,4-Dichlorobenzene ug/L 47.650 95 78-130
Benzene ug/L 52.250 104 80-125
Methylene Chloride ug/L 57.650 115 64-133
Tetrachloroethene ug/L 40.750 81 78-122
Trichloroethene ug/L 51.350 103 78-122
Vinyl chloride ug/L 37.150 74 58-137
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%88 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897424MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991018
1,1-Dichloroethane ug/L 17.620 83 70-1301.0
1,2-Dichloroethane ug/L 17.920 89 70-130ND
1,4-Dichlorobenzene ug/L 21.220 95 70-1302.1
Benzene ug/L 19.620 98 70-148ND
Methylene Chloride ug/L 16.020 80 70-130ND
Tetrachloroethene ug/L 17.020 79 70-1301.2
Trichloroethene ug/L 23.220 99 69-1513.3
Vinyl chloride ug/L 15.720 75 70-1300.71J
REPORT OF LABORATORY ANALYSIS
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Page 14 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897424MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991018
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%86 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991019
1897425SAMPLE DUPLICATE:
1,1-Dichloroethane ug/L 0.60J 300.57J
1,2-Dichloroethane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 0.86J 300.85J
Benzene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Tetrachloroethene ug/L 2.4 0 302.4
Trichloroethene ug/L 11.1 5 3010.6
Vinyl chloride ug/L 1.3 3 301.3
1,2-Dichloroethane-d4 (S)%101 0101
4-Bromofluorobenzene (S)%104 1105
Toluene-d8 (S)%97 299
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 15 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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Page 16 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323605001 3422201203-MW15S RSK 175 Modified
92323605002 3422201203-PZ12 RSK 175 Modified
92323605003 3422201203-PZ30S RSK 175 Modified
92323605004 3422201203-PZ31 RSK 175 Modified
92323605005 3422201203-PZ35 RSK 175 Modified
92323605006 3422201203-MW36 RSK 175 Modified
92323605007 3422201203-MW38 RSK 175 Modified
92323605001 3420091203-MW15S EPA 8260
92323605002 3420091203-PZ12 EPA 8260
92323605003 3420091203-PZ30S EPA 8260
92323605004 3420091203-PZ31 EPA 8260
92323605005 3420091203-PZ35 EPA 8260
92323605006 3420091203-MW36 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 17 of 36
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Page 36 of 36
#=CL#
January 10, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323286
92323286
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
JOHNS RIVER MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 40
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 40
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Lab ID Sample ID Matrix Date Collected Date Received
92323286001 1203-MW21 Water 12/13/16 12:45 12/14/16 10:24
92323286002 1203-MW11 Water 12/13/16 11:45 12/14/16 10:24
92323286003 1203-MW12 Water 12/13/16 14:10 12/14/16 10:24
92323286004 1203-MW16S Water 12/13/16 13:30 12/14/16 10:24
REPORT OF LABORATORY ANALYSIS
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Page 3 of 40
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323286001 1203-MW21 RSK 175 Modified 3 PASI-CWDV
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ADMN
SM 5310B 1 PASI-OAEM
92323286002 1203-MW11 RSK 175 Modified 3 PASI-CWDV
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ADMN
SM 5310B 1 PASI-OAEM
92323286003 1203-MW12 RSK 175 Modified 3 PASI-CWDV
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ADMN
SM 5310B 1 PASI-OAEM
92323286004 1203-MW16S RSK 175 Modified 3 PASI-CWDV
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ADMN
SM 5310B 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
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Page 4 of 40
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323286001 1203-MW21
Alkalinity, Total as CaCO3 1090J ug/L 12/23/16 07:445000SM 2320B
Nitrogen, Nitrate 210J ug/L 12/15/16 00:2810000EPA 353.2
Chloride 1330 ug/L 12/29/16 16:091000SM 4500-Cl-E
Total Organic Carbon 0.70J mg/L 01/09/17 18:471.0SM 5310B
92323286002 1203-MW11
Methane 3050 ug/L 12/23/16 12:04 N220.0RSK 175 Modified
Alkalinity, Total as CaCO3 106000 ug/L 12/23/16 08:125000SM 2320B
Sulfate 3500J ug/L 12/17/16 20:03250000EPA 300.0
Chloride 30300 ug/L 12/29/16 16:101000SM 4500-Cl-E
Total Organic Carbon 4.0 mg/L 01/09/17 23:201.0SM 5310B
92323286003 1203-MW12
Methane 8940 ug/L 12/23/16 11:17 N250.0RSK 175 Modified
Alkalinity, Total as CaCO3 45600 ug/L 12/23/16 08:245000SM 2320B
Sulfate 4020J ug/L 12/17/16 20:30250000EPA 300.0
Chloride 10700 ug/L 12/29/16 16:131000SM 4500-Cl-E
Total Organic Carbon 3.7 mg/L 01/09/17 19:411.0SM 5310B
92323286004 1203-MW16S
Methane 17300 ug/L 12/23/16 10:29 N2100RSK 175 Modified
Alkalinity, Total as CaCO3 77600 ug/L 12/23/16 08:345000SM 2320B
Sulfate 1700J ug/L 12/17/16 20:57250000EPA 300.0
Chloride 8240 ug/L 12/29/16 16:141000SM 4500-Cl-E
Total Organic Carbon 3.6 mg/L 01/09/17 19:281.0SM 5310B
REPORT OF LABORATORY ANALYSIS
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Page 5 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Sample: 1203-MW21 Lab ID: 92323286001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 12/22/16 15:20 74-84-0 N210.0 10.0 1
Ethene ND ug/L 12/22/16 15:20 74-85-1 N210.0 10.0 1
Methane ND ug/L 12/22/16 15:20 74-82-8 N210.0 10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 1090J ug/L 12/23/16 07:445000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 12/17/16 19:53 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 210J ug/L 12/15/16 00:2810000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1330 ug/L 12/29/16 16:09 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 0.70J mg/L 01/09/17 18:47 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Sample: 1203-MW11 Lab ID: 92323286002 Collected: 12/13/16 11:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 12/23/16 12:04 74-84-0 N220.0 20.0 2
Ethene ND ug/L 12/23/16 12:04 74-85-1 N220.0 20.0 2
Methane 3050 ug/L 12/23/16 12:04 74-82-8 N220.0 20.0 2
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 106000 ug/L 12/23/16 08:125000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3500J ug/L 12/17/16 20:03 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/15/16 00:2210000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 30300 ug/L 12/29/16 16:10 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 4.0 mg/L 01/09/17 23:20 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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Huntersville, NC 28078
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Page 7 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Sample: 1203-MW12 Lab ID: 92323286003 Collected: 12/13/16 14:10 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 12/23/16 11:17 74-84-0 N250.0 50.0 5
Ethene ND ug/L 12/23/16 11:17 74-85-1 N250.0 50.0 5
Methane 8940 ug/L 12/23/16 11:17 74-82-8 N250.0 50.0 5
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 45600 ug/L 12/23/16 08:245000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 4020J ug/L 12/17/16 20:30 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/15/16 00:3210000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 10700 ug/L 12/29/16 16:13 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 3.7 mg/L 01/09/17 19:41 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Sample: 1203-MW16S Lab ID: 92323286004 Collected: 12/13/16 13:30 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 12/23/16 10:29 74-84-0 N2100 100 10
Ethene ND ug/L 12/23/16 10:29 74-85-1 N2100 100 10
Methane 17300 ug/L 12/23/16 10:29 74-82-8 N2100 100 10
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 77600 ug/L 12/23/16 08:345000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:15 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1700J ug/L 12/17/16 20:57 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/15/16 00:3010000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 8240 ug/L 12/29/16 16:14 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 3.6 mg/L 01/09/17 19:28 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 9 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342220
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898651
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Ethane ug/L ND 10.0 N212/22/16 14:0410.0
Ethene ug/L ND 10.0 N212/22/16 14:0410.0
Methane ug/L ND 10.0 N212/22/16 14:0410.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898652LABORATORY CONTROL SAMPLE:
LCSSpike
Ethane ug/L 663 N2658101 70-130
Ethene ug/L 1110 N2112099 70-130
Methane ug/L 376 N239695 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1898653MATRIX SPIKE SAMPLE:
MSSpike
Result
92324178004
Ethane ug/L 892 M1,N2658135 70-130ND
Ethene ug/L 1100 N2112098 70-130ND
Methane ug/L 449 N2396113 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92324178005
1898654SAMPLE DUPLICATE:
Ethane ug/L ND N220ND
Ethene ug/L ND N220ND
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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Page 10 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342108
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898057
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/23/16 07:251000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898058LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4510050000 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898059MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323286001
1898060
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12096 1 25500001090J48600 49300
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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Page 11 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341247
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893092
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/16/16 13:15100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893093LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 524J500 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893094MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323216024
1893095
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 87 80-12087 0 10500ND438J 436J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893096MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323216034
1893097
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 103 80-120102 1 10500ND513J 510J
REPORT OF LABORATORY ANALYSIS
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Page 12 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341402
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894399
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/17/16 17:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894400LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238003
1894402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011590-110110 2 102000026.5 mg/L 49500J 48400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1894404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 99 90-11094 5 10200002.1 mg/L 22000J 21000J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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[phone]
Page 13 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340930
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891365
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 12/15/16 00:1310.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891366LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2340J2500 93 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891367MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238001
1891368
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 108 90-110107 0 1025006.2 mg/L 8900J 8880J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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[phone]
Page 14 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342770
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1901305
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 12/29/16 15:53500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1901306LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1970020000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901307MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991013
1901308
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000013490-110136 0 101000066.5 mg/L 79900 80000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901309MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1901310
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 98 90-110101 3 10100001.6 mg/L 11400 11700
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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[phone]
Page 15 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
343201
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92323286001, 92323286002, 92323286003, 92323286004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1841585
Associated Lab Samples:92323286001, 92323286002, 92323286003, 92323286004
Matrix: Water
AnalyzedMDL
Total Organic Carbon mg/L ND 1.0 01/09/17 18:200.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1841586LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon mg/L 20.820 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1841587MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323286001
1841588
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 20 106 80-120105 1 20200.70J 22.0 21.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1841589MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323502008
1841590
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 20 99 80-12098 1 2020ND19.9 19.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 05:11 PM
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Page 16 of 40
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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Page 17 of 40
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323286
JOHNS RIVER MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323286001 3422201203-MW21 RSK 175 Modified
92323286002 3422201203-MW11 RSK 175 Modified
92323286003 3422201203-MW12 RSK 175 Modified
92323286004 3422201203-MW16S RSK 175 Modified
92323286001 3421081203-MW21 SM 2320B
92323286002 3421081203-MW11 SM 2320B
92323286003 3421081203-MW12 SM 2320B
92323286004 3421081203-MW16S SM 2320B
92323286001 3412471203-MW21 SM 4500-S2D
92323286002 3412471203-MW11 SM 4500-S2D
92323286003 3412471203-MW12 SM 4500-S2D
92323286004 3412471203-MW16S SM 4500-S2D
92323286001 3414021203-MW21 EPA 300.0
92323286002 3414021203-MW11 EPA 300.0
92323286003 3414021203-MW12 EPA 300.0
92323286004 3414021203-MW16S EPA 300.0
92323286001 3409301203-MW21 EPA 353.2
92323286002 3409301203-MW11 EPA 353.2
92323286003 3409301203-MW12 EPA 353.2
92323286004 3409301203-MW16S EPA 353.2
92323286001 3427701203-MW21 SM 4500-Cl-E
92323286002 3427701203-MW11 SM 4500-Cl-E
92323286003 3427701203-MW12 SM 4500-Cl-E
92323286004 3427701203-MW16S SM 4500-Cl-E
92323286001 3432011203-MW21 SM 5310B
92323286002 3432011203-MW11 SM 5310B
92323286003 3432011203-MW12 SM 5310B
92323286004 3432011203-MW16S SM 5310B
REPORT OF LABORATORY ANALYSIS
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Page 18 of 40
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Page 40 of 40
#=CL#
December 27, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323615
92323615
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Johns R. Surface Water
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID Matrix Date Collected Date Received
92323615001 1203-SMP5 Water 12/14/16 13:20 12/15/16 10:10
92323615002 1203-SMP6 Water 12/14/16 11:45 12/15/16 10:10
92323615003 1203-SMP7 Water 12/14/16 10:05 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323615001 1203-SMP5 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
92323615002 1203-SMP6 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
92323615003 1203-SMP7 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
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Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323615001 1203-SMP5
Barium 44.7J ug/L 12/23/16 06:34100EPA 6010
Cobalt 5.9J ug/L 12/23/16 06:3410.0EPA 6010
92323615002 1203-SMP6
Barium 21.2J ug/L 12/23/16 06:37100EPA 6010
1,1-Dichloroethane 2.6J ug/L 12/17/16 03:115.0EPA 8260
cis-1,2-Dichloroethene 0.43J ug/L 12/17/16 03:115.0EPA 8260
Trichloroethene 0.52J ug/L 12/17/16 03:111.0EPA 8260
92323615003 1203-SMP7
Barium 17.5J ug/L 12/23/16 06:49100EPA 6010
Zinc 6.9J ug/L 12/23/16 06:4910.0EPA 6010
REPORT OF LABORATORY ANALYSIS
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Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP5 Lab ID: 92323615001 Collected: 12/14/16 13:20 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:23 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:23 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)89 %12/22/16 16:23 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)90 %12/22/16 16:23 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:50 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:34 7440-38-212/17/16 01:0010.0 2.5 1
Barium 44.7J ug/L 12/23/16 06:34 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:34 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:50 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:34 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt 5.9J ug/L 12/23/16 06:34 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:34 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 21:50 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:50 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:34 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:34 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:34 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:34 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:34 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:34 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:07 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 02:54 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 02:54 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 02:54 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 02:54 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 02:54 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 02:54 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 02:54 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 02:54 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 02:54 75-15-0 M1100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 02:54 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 02:54 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 02:54 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 02:54 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 02:54 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 02:54 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 02:54 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 02:54 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 02:54 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP5 Lab ID: 92323615001 Collected: 12/14/16 13:20 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 02:54 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 02:54 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 02:54 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 02:54 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/17/16 02:54 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 02:54 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 02:54 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/17/16 02:54 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 02:54 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 02:54 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 02:54 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 02:54 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 02:54 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 02:54 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 02:54 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 02:54 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 02:54 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 02:54 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 02:54 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 02:54 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 02:54 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 02:54 109-99-9 M110.0 3.1 1
Toluene ND ug/L 12/17/16 02:54 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 02:54 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 02:54 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/17/16 02:54 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 02:54 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 02:54 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 02:54 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 02:54 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 02:54 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %12/17/16 02:54 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/17/16 02:54 17060-07-070-130 1
Toluene-d8 (S)100 %12/17/16 02:54 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:47 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP6 Lab ID: 92323615002 Collected: 12/14/16 11:45 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:40 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:40 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)78 %12/22/16 16:40 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)88 %12/22/16 16:40 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:53 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:37 7440-38-212/17/16 01:0010.0 2.5 1
Barium 21.2J ug/L 12/23/16 06:37 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:37 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:53 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:37 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:37 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:37 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 21:53 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:53 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:37 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:37 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:37 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:37 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:37 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:37 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:09 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 03:11 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 03:11 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 03:11 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 03:11 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 03:11 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 03:11 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 03:11 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 03:11 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 03:11 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 03:11 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 03:11 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 03:11 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 03:11 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 03:11 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 03:11 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 03:11 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 03:11 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 03:11 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP6 Lab ID: 92323615002 Collected: 12/14/16 11:45 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 03:11 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 03:11 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 03:11 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 03:11 75-71-85.0 0.21 1
1,1-Dichloroethane 2.6J ug/L 12/17/16 03:11 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 03:11 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 03:11 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.43J ug/L 12/17/16 03:11 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 03:11 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 03:11 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 03:11 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 03:11 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 03:11 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 03:11 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 03:11 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 03:11 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 03:11 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 03:11 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 03:11 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 03:11 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 03:11 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 03:11 109-99-910.0 3.1 1
Toluene ND ug/L 12/17/16 03:11 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 03:11 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 03:11 79-00-51.0 0.29 1
Trichloroethene 0.52J ug/L 12/17/16 03:11 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 03:11 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 03:11 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 03:11 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 03:11 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 03:11 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/17/16 03:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/17/16 03:11 17060-07-070-130 1
Toluene-d8 (S)101 %12/17/16 03:11 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:51 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP7 Lab ID: 92323615003 Collected: 12/14/16 10:05 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:58 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:58 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)105 %12/22/16 16:58 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)94 %12/22/16 16:58 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:56 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:49 7440-38-212/17/16 01:0010.0 2.5 1
Barium 17.5J ug/L 12/23/16 06:49 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:49 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:56 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:49 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:49 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:49 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 06:49 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:56 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:49 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:49 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:49 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:49 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:49 7440-62-212/17/16 01:0025.0 2.5 1
Zinc 6.9J ug/L 12/23/16 06:49 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:11 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 03:45 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 03:45 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 03:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 03:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 03:45 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 03:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 03:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 03:45 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 03:45 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 03:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 03:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 03:45 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 03:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 03:45 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 03:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 03:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 03:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 03:45 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP7 Lab ID: 92323615003 Collected: 12/14/16 10:05 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 03:45 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 03:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 03:45 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 03:45 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/17/16 03:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 03:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 03:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/17/16 03:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 03:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 03:45 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 03:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 03:45 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 03:45 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 03:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 03:45 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 03:45 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 03:45 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 03:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 03:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 03:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 03:45 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 03:45 109-99-910.0 3.1 1
Toluene ND ug/L 12/17/16 03:45 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 03:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 03:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/17/16 03:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 03:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 03:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 03:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 03:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 03:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/17/16 03:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/17/16 03:45 17060-07-070-130 1
Toluene-d8 (S)99 %12/17/16 03:45 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:54 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Lead ug/L ND 10.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Lead ug/L 426500 85 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Lead ug/L 500 99 75-125103 3 25500ND497 514
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386 411
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341294
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893558
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/17/16 02:020.33
1,1,1-Trichloroethane ug/L ND 1.0 12/17/16 02:020.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/17/16 02:020.40
1,1,2-Trichloroethane ug/L ND 1.0 12/17/16 02:020.29
1,1-Dichloroethane ug/L ND 5.0 12/17/16 02:020.32
1,1-Dichloroethene ug/L ND 5.0 12/17/16 02:020.56
1,2,3-Trichloropropane ug/L ND 1.0 12/17/16 02:020.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/17/16 02:022.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/17/16 02:020.27
1,2-Dichlorobenzene ug/L ND 5.0 12/17/16 02:020.30
1,2-Dichloroethane ug/L ND 1.0 12/17/16 02:020.24
1,2-Dichloropropane ug/L ND 1.0 12/17/16 02:020.27
1,4-Dichlorobenzene ug/L ND 1.0 12/17/16 02:020.33
2-Butanone (MEK)ug/L ND 100 12/17/16 02:020.96
2-Hexanone ug/L ND 50.0 12/17/16 02:020.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/17/16 02:020.33
Acetone ug/L ND 100 12/17/16 02:0210.0
Acrylonitrile ug/L ND 200 12/17/16 02:021.9
Benzene ug/L ND 1.0 12/17/16 02:020.25
Bromochloromethane ug/L ND 3.0 12/17/16 02:020.17
Bromodichloromethane ug/L ND 1.0 12/17/16 02:020.18
Bromoform ug/L ND 3.0 12/17/16 02:020.26
Bromomethane ug/L ND 10.0 12/17/16 02:020.29
Carbon disulfide ug/L ND 100 12/17/16 02:021.2
Carbon tetrachloride ug/L ND 1.0 12/17/16 02:020.25
Chlorobenzene ug/L ND 3.0 12/17/16 02:020.23
Chloroethane ug/L ND 10.0 12/17/16 02:020.54
Chloroform ug/L ND 5.0 12/17/16 02:020.14
Chloromethane ug/L ND 1.0 12/17/16 02:020.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/17/16 02:020.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/17/16 02:020.13
Dibromochloromethane ug/L ND 3.0 12/17/16 02:020.21
Dibromomethane ug/L ND 10.0 12/17/16 02:020.21
Dichlorodifluoromethane ug/L ND 5.0 12/17/16 02:020.21
Ethylbenzene ug/L ND 1.0 12/17/16 02:020.30
Iodomethane ug/L ND 10.0 12/17/16 02:020.32
Methylene Chloride ug/L ND 1.0 12/17/16 02:020.97
Styrene ug/L ND 1.0 12/17/16 02:020.26
Tetrachloroethene ug/L ND 1.0 12/17/16 02:020.46
Tetrahydrofuran ug/L ND 10.0 12/17/16 02:023.1
Toluene ug/L ND 1.0 12/17/16 02:020.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893558
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 5.0 12/17/16 02:020.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/17/16 02:020.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/17/16 02:021.0
Trichloroethene ug/L ND 1.0 12/17/16 02:020.47
Trichlorofluoromethane ug/L ND 1.0 12/17/16 02:020.20
Vinyl acetate ug/L ND 50.0 12/17/16 02:020.35
Vinyl chloride ug/L ND 1.0 12/17/16 02:020.62
Xylene (Total)ug/L ND 5.0 12/17/16 02:020.66
1,2-Dichloroethane-d4 (S)%103 70-130 12/17/16 02:02
4-Bromofluorobenzene (S)%94 70-130 12/17/16 02:02
Toluene-d8 (S)%101 70-130 12/17/16 02:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893559LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.450 95 80-125
1,1,1-Trichloroethane ug/L 50.350 101 71-129
1,1,2,2-Tetrachloroethane ug/L 48.950 98 79-124
1,1,2-Trichloroethane ug/L 48.850 98 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.750 115 66-135
1,2,3-Trichloropropane ug/L 46.950 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.250 94 71-133
1,2-Dibromoethane (EDB)ug/L 48.350 97 83-124
1,2-Dichlorobenzene ug/L 48.750 97 80-133
1,2-Dichloroethane ug/L 47.050 94 67-128
1,2-Dichloropropane ug/L 52.550 105 75-132
1,4-Dichlorobenzene ug/L 47.650 95 78-130
2-Butanone (MEK)ug/L 114100 114 61-144
2-Hexanone ug/L 110100 110 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 106100 106 48-146
Acrylonitrile ug/L 298250 119 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 52.250 104 71-125
Bromodichloromethane ug/L 48.650 97 78-124
Bromoform ug/L 45.250 90 71-128
Bromomethane ug/L 46.250 92 40-160
Carbon disulfide ug/L 63.0J50 126 50-160
Carbon tetrachloride ug/L 48.150 96 69-131
Chlorobenzene ug/L 48.450 97 81-122
Chloroethane ug/L 57.650 115 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 61.650 123 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893559LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.550 107 74-124
cis-1,3-Dichloropropene ug/L 50.550 101 72-132
Dibromochloromethane ug/L 48.250 96 78-125
Dibromomethane ug/L 46.050 92 82-120
Dichlorodifluoromethane ug/L 57.450 115 34-157
Ethylbenzene ug/L 48.950 98 79-121
Iodomethane ug/L 105100 105 39-154
Methylene Chloride ug/L 53.750 107 64-133
Styrene ug/L 49.350 99 84-126
Tetrachloroethene ug/L 44.850 90 78-122
Tetrahydrofuran ug/L 611500 122 69-148
Toluene ug/L 49.050 98 80-121
trans-1,2-Dichloroethene ug/L 57.150 114 71-127
trans-1,3-Dichloropropene ug/L 50.250 100 69-141
trans-1,4-Dichloro-2-butene ug/L 43.7J50 87 40-160
Trichloroethene ug/L 48.150 96 78-122
Trichlorofluoromethane ug/L 56.750 113 53-137
Vinyl acetate ug/L 112100 112 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 146150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1893560MATRIX SPIKE SAMPLE:
MSSpike
Result
92323615001
1,1,1,2-Tetrachloroethane ug/L 20.020 100 70-130ND
1,1,1-Trichloroethane ug/L 22.220 111 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.920 104 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 23.620 118 70-130ND
1,1-Dichloroethene ug/L 25.520 127 70-166ND
1,2,3-Trichloropropane ug/L 19.720 98 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.820 99 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.520 103 70-130ND
1,2-Dichlorobenzene ug/L 20.720 103 70-130ND
1,2-Dichloroethane ug/L 21.020 104 70-130ND
1,2-Dichloropropane ug/L 22.620 113 70-130ND
1,4-Dichlorobenzene ug/L 20.120 100 70-130ND
2-Butanone (MEK)ug/L 49.7J40 124 70-130ND
2-Hexanone ug/L 46.4J40 116 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 45.5J40 114 70-130ND
Acetone ug/L 48.1J40 115 70-130ND
Acrylonitrile ug/L 128J100 128 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
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Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1893560MATRIX SPIKE SAMPLE:
MSSpike
Result
92323615001
Benzene ug/L 22.820 114 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 21.420 107 70-130ND
Bromoform ug/L 18.520 92 70-130ND
Bromomethane ug/L 19.520 98 70-130ND
Carbon disulfide ug/L 26.8J M120134 70-130ND
Carbon tetrachloride ug/L 20.920 104 70-130ND
Chlorobenzene ug/L 21.020 105 70-146ND
Chloroethane ug/L 24.320 121 70-130ND
Chloroform ug/L 22.920 115 70-130ND
Chloromethane ug/L 23.820 119 70-130ND
cis-1,2-Dichloroethene ug/L 23.320 116 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 101 70-130ND
Dibromochloromethane ug/L 20.220 101 70-130ND
Dibromomethane ug/L 20.020 100 70-130ND
Dichlorodifluoromethane ug/L 19.220 96 70-130ND
Ethylbenzene ug/L 21.320 107 70-130ND
Iodomethane ug/L 40.940 102 70-130ND
Methylene Chloride ug/L 22.820 114 70-130ND
Styrene ug/L 20.820 104 70-130ND
Tetrachloroethene ug/L 19.220 96 70-130ND
Tetrahydrofuran ug/L 263 M1200131 70-130ND
Toluene ug/L 21.920 109 70-155ND
trans-1,2-Dichloroethene ug/L 24.820 124 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 18.1J20 91 70-130ND
Trichloroethene ug/L 21.120 106 69-151ND
Trichlorofluoromethane ug/L 25.020 125 70-130ND
Vinyl acetate ug/L 39.1J40 98 70-130ND
Vinyl chloride ug/L 20.620 103 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323615002
1893561SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 2.7J 4 302.6J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323615002
1893561SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 0.46J 300.43J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 0.49J 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.49J 300.52J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 2102
4-Bromofluorobenzene (S)%95 094
Toluene-d8 (S)%100 1101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341799
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896365
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 12/22/16 17:160.050
beta-BHC ug/L ND 0.050 12/22/16 17:160.050
Decachlorobiphenyl (S)%104 20-130 12/22/16 17:16
Tetrachloro-m-xylene (S)%88 20-130 12/22/16 17:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.24.25 97 20-150
beta-BHC ug/L 0.25.25 102 20-150
Decachlorobiphenyl (S)%91 20-130
Tetrachloro-m-xylene (S)%94 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896367MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896368
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
alpha-BHC ug/L .5 89 20-15096 7 30.5ND 0.44 0.47
beta-BHC ug/L .5 103 20-150106 2 30.5ND 0.51 0.52
Decachlorobiphenyl (S)%85 20-13088
Tetrachloro-m-xylene (S)%89 20-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323615001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323615001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
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Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342534
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900216
Associated Lab Samples:92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:484.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900217LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 100100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323615002
1900219
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 98 75-12594 5 10100ND99.7 95.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900220MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1900221
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L R110010475-12592 11 10100ND105 94.0
REPORT OF LABORATORY ANALYSIS
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Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323615001 341799 3422261203-SMP5 EPA 3510 EPA 8081
92323615002 341799 3422261203-SMP6 EPA 3510 EPA 8081
92323615003 341799 3422261203-SMP7 EPA 3510 EPA 8081
92323615001 341173 3415711203-SMP5 EPA 3010A EPA 6010
92323615002 341173 3415711203-SMP6 EPA 3010A EPA 6010
92323615003 341173 3415711203-SMP7 EPA 3010A EPA 6010
92323615001 341661 3419801203-SMP5 EPA 7470 EPA 7470
92323615002 341661 3419801203-SMP6 EPA 7470 EPA 7470
92323615003 341661 3419801203-SMP7 EPA 7470 EPA 7470
92323615001 3412941203-SMP5 EPA 8260
92323615002 3412941203-SMP6 EPA 8260
92323615003 3412941203-SMP7 EPA 8260
92323615001 3425331203-SMP5 SM 4500-CN-E
92323615002 3425341203-SMP6 SM 4500-CN-E
92323615003 3425341203-SMP7 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
December 28, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323613
92323613
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Burke Co. Johns R. Blanks
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 45
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 45
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID Matrix Date Collected Date Received
92323613001 1203-Field Blank Water 12/14/16 14:30 12/15/16 10:10
92323613002 1203-Trip Blank Water 12/13/16 07:00 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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Page 3 of 45
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323613001 1203-Field Blank EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CCAH
SM 4500-S2D 1 PASI-AEWS
SM 4500-CN-E 1 PASI-ADMN
92323613002 1203-Trip Blank EPA 8260 67 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 45
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323613001 1203-Field Blank
Chloromethane 0.17J ug/L 12/21/16 20:261.0EPA 8260
Naphthalene 0.26J ug/L 12/21/16 20:2610.0EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 5 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/22/16 16:05 309-00-212/20/16 16:160.050 0.050 1
alpha-BHC ND ug/L 12/22/16 16:05 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:05 319-85-712/20/16 16:160.050 0.050 1
delta-BHC ND ug/L 12/22/16 16:05 319-86-812/20/16 16:160.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/22/16 16:05 58-89-912/20/16 16:160.050 0.050 1
Chlordane (Technical)ND ug/L 12/22/16 16:05 57-74-912/20/16 16:160.50 0.20 1
4,4'-DDD ND ug/L 12/22/16 16:05 72-54-812/20/16 16:160.10 0.050 1
4,4'-DDE ND ug/L 12/22/16 16:05 72-55-912/20/16 16:160.10 0.050 1
4,4'-DDT ND ug/L 12/22/16 16:05 50-29-312/20/16 16:160.10 0.050 1
Dieldrin ND ug/L 12/22/16 16:05 60-57-112/20/16 16:160.075 0.050 1
Endosulfan I ND ug/L 12/22/16 16:05 959-98-812/20/16 16:160.10 0.050 1
Endosulfan II ND ug/L 12/22/16 16:05 33213-65-912/20/16 16:160.10 0.050 1
Endosulfan sulfate ND ug/L 12/22/16 16:05 1031-07-812/20/16 16:160.10 0.050 1
Endrin ND ug/L 12/22/16 16:05 72-20-812/20/16 16:160.10 0.050 1
Endrin aldehyde ND ug/L 12/22/16 16:05 7421-93-412/20/16 16:160.10 0.050 1
Heptachlor ND ug/L 12/22/16 16:05 76-44-812/20/16 16:160.050 0.050 1
Heptachlor epoxide ND ug/L 12/22/16 16:05 1024-57-312/20/16 16:160.075 0.050 1
Methoxychlor ND ug/L 12/22/16 16:05 72-43-512/20/16 16:161.0 0.15 1
Toxaphene ND ug/L 12/22/16 16:05 8001-35-212/20/16 16:161.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)106 %12/22/16 16:05 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)98 %12/22/16 16:05 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 20:30 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 20:30 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 20:30 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 20:30 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 20:30 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 20:30 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 20:30 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)49 %12/20/16 20:30 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/23/16 08:40 94-75-7 H212/22/16 07:300.94 0.22 1
Dinoseb ND ug/L 12/23/16 08:40 88-85-7 H212/22/16 07:300.19 0.057 1
2,4,5-T ND ug/L 12/23/16 08:40 93-76-5 H212/22/16 07:300.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/23/16 08:40 93-72-1 H212/22/16 07:300.19 0.049 1
Surrogates
2,4-DCAA (S)79 %12/23/16 08:40 19719-28-912/22/16 07:3039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:47 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:31 7440-38-212/17/16 01:0010.0 2.5 1
Barium ND ug/L 12/23/16 06:31 7440-39-312/17/16 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 06:31 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:47 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:31 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:31 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:31 7440-50-812/17/16 01:0010.0 2.5 1
Iron ND ug/L 12/23/16 06:31 7439-89-612/17/16 01:00300 25.0 1
Lead ND ug/L 12/23/16 21:47 7439-92-112/17/16 01:0010.0 2.5 1
Manganese ND ug/L 12/23/16 06:31 7439-96-512/17/16 01:0050.0 2.5 1
Nickel ND ug/L 12/23/16 21:47 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:31 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:31 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:31 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:31 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:31 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:31 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:04 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 19:23 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 19:23 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 19:23 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 19:23 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 19:23 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 19:23 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 19:23 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 19:23 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 19:23 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 19:23 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 19:23 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 19:23 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 19:23 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 19:23 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 19:23 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 19:23 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 19:23 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 19:23 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 19:23 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 19:23 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 19:23 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 19:23 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 19:23 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 19:23 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 19:23 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 19:23 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 19:23 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 19:23 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 19:23 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 19:23 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/22/16 19:23 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 19:23 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 19:23 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 19:23 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 19:23 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 19:23 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 19:23 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 19:23 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 19:23 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 19:23 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 19:23 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 19:23 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 19:23 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 19:23 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 19:23 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 19:23 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 19:23 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 19:23 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 19:23 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 19:23 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 19:23 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 19:23 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 19:23 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 19:23 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 19:23 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 19:23 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 19:23 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 19:23 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 19:23 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 19:23 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/22/16 19:23 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 19:23 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 19:23 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 19:23 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 19:23 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 19:2312/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 19:23 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 19:23 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 19:23 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 19:23 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 19:23 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 19:23 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 19:23 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 19:23 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 19:23 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 19:23 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 19:23 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 19:23 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 19:23 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 19:23 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 19:23 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 19:23 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 19:23 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 19:23 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 19:23 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 19:23 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 19:23 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 19:23 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 19:23 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 19:23 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 19:23 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 19:23 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 19:2312/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 19:23 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 19:23 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 19:23 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 19:23 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 19:23 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 19:23 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 19:23 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 19:23 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 19:23 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 19:23 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 19:23 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 19:23 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)58 %12/22/16 19:23 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)68 %12/22/16 19:23 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)71 %12/22/16 19:23 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)16 %12/22/16 19:23 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)26 %12/22/16 19:23 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)70 %12/22/16 19:23 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 20:26 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/21/16 20:26 75-05-855.0 2.2 1
Acrolein ND ug/L 12/21/16 20:26 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/21/16 20:26 107-13-1200 1.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/21/16 20:26 107-05-110.0 1.5 1
Benzene ND ug/L 12/21/16 20:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 20:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 20:26 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 20:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/21/16 20:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 20:26 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/21/16 20:26 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/21/16 20:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 20:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/21/16 20:26 75-00-310.0 0.54 1
Chloroform ND ug/L 12/21/16 20:26 67-66-35.0 0.14 1
Chloromethane 0.17J ug/L 12/21/16 20:26 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/21/16 20:26 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 20:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 20:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 20:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 20:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 20:26 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/21/16 20:26 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/21/16 20:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 20:26 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/21/16 20:26 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/21/16 20:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 20:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 20:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 20:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 20:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/21/16 20:26 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/21/16 20:26 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/21/16 20:26 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/21/16 20:26 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 20:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 20:26 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 20:26 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/21/16 20:26 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/21/16 20:26 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/21/16 20:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/21/16 20:26 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/21/16 20:26 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/21/16 20:26 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/21/16 20:26 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/21/16 20:26 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 20:26 108-10-1100 0.33 1
Naphthalene 0.26J ug/L 12/21/16 20:26 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/21/16 20:26 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Field Blank Lab ID: 92323613001 Collected: 12/14/16 14:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/21/16 20:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 20:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 20:26 79-34-5 L23.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 20:26 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 20:26 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/21/16 20:26 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/21/16 20:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 20:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 20:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 20:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 20:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 20:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 20:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 20:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 20:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 20:26 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 20:26 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/20/16 15:05 18496-25-81000 100 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:46 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Trip Blank Lab ID: 92323613002 Collected: 12/13/16 07:00 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 20:43 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/21/16 20:43 75-05-855.0 2.2 1
Acrolein ND ug/L 12/21/16 20:43 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/21/16 20:43 107-13-1200 1.9 1
Allyl chloride ND ug/L 12/21/16 20:43 107-05-110.0 1.5 1
Benzene ND ug/L 12/21/16 20:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 20:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 20:43 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 20:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/21/16 20:43 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 20:43 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/21/16 20:43 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/21/16 20:43 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 20:43 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/21/16 20:43 75-00-310.0 0.54 1
Chloroform ND ug/L 12/21/16 20:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/21/16 20:43 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/21/16 20:43 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 20:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 20:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 20:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 20:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 20:43 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/21/16 20:43 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/21/16 20:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 20:43 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/21/16 20:43 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/21/16 20:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 20:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 20:43 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 20:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 20:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/21/16 20:43 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/21/16 20:43 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/21/16 20:43 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/21/16 20:43 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 20:43 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 20:43 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 20:43 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/21/16 20:43 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/21/16 20:43 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/21/16 20:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/21/16 20:43 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/21/16 20:43 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/21/16 20:43 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/21/16 20:43 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 12 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample: 1203-Trip Blank Lab ID: 92323613002 Collected: 12/13/16 07:00 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 12/21/16 20:43 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 20:43 108-10-1100 0.33 1
Naphthalene ND ug/L 12/21/16 20:43 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/21/16 20:43 107-12-0150 3.6 1
Styrene ND ug/L 12/21/16 20:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 20:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 20:43 79-34-5 L23.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 20:43 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 20:43 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/21/16 20:43 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/21/16 20:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 20:43 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 20:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 20:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 20:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 20:43 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 20:43 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 20:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)105 %12/21/16 20:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/21/16 20:43 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 20:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Iron ug/L ND 300 12/23/16 05:1125.0
Lead ug/L ND 10.0 12/23/16 05:112.5
Manganese ug/L ND 50.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Iron ug/L 44805000 90 80-120
Lead ug/L 426500 85 80-120
Manganese ug/L 442500 88 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Iron ug/L 5000 80 75-12584 5 255000ND4010 4220
Lead ug/L 500 99 75-125103 3 25500ND497 514
Manganese ug/L 500 79 75-12584 6 25500ND395 419
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386 411
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323613001, 92323613002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323613001, 92323613002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/21/16 16:270.33
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:270.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/21/16 16:270.40
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:270.29
1,1-Dichloroethane ug/L ND 5.0 12/21/16 16:270.32
1,1-Dichloroethene ug/L ND 5.0 12/21/16 16:270.56
1,1-Dichloropropene ug/L ND 5.0 12/21/16 16:270.49
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:270.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/21/16 16:270.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/21/16 16:272.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:270.27
1,2-Dichlorobenzene ug/L ND 5.0 12/21/16 16:270.30
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:270.24
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:270.27
1,3-Dichlorobenzene ug/L ND 5.0 12/21/16 16:270.24
1,3-Dichloropropane ug/L ND 1.0 12/21/16 16:270.28
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.33
2,2-Dichloropropane ug/L ND 15.0 12/21/16 16:270.13
2-Butanone (MEK)ug/L ND 100 12/21/16 16:270.96
2-Hexanone ug/L ND 50.0 12/21/16 16:270.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/21/16 16:270.33
Acetone ug/L ND 100 12/21/16 16:2710.0
Acetonitrile ug/L ND 55.0 12/21/16 16:272.2
Acrolein ug/L ND 53.0 12/21/16 16:271.6
Acrylonitrile ug/L ND 200 12/21/16 16:271.9
Allyl chloride ug/L ND 10.0 12/21/16 16:271.5
Benzene ug/L ND 1.0 12/21/16 16:270.25
Bromochloromethane ug/L ND 3.0 12/21/16 16:270.17
Bromodichloromethane ug/L ND 1.0 12/21/16 16:270.18
Bromoform ug/L ND 3.0 12/21/16 16:270.26
Bromomethane ug/L ND 10.0 12/21/16 16:270.29
Carbon disulfide ug/L ND 100 12/21/16 16:271.2
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:270.25
Chlorobenzene ug/L ND 3.0 12/21/16 16:270.23
Chloroethane ug/L ND 10.0 12/21/16 16:270.54
Chloroform ug/L ND 5.0 12/21/16 16:270.14
Chloromethane ug/L ND 1.0 12/21/16 16:270.11
Chloroprene ug/L ND 20.0 12/21/16 16:270.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/21/16 16:270.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.13
Dibromochloromethane ug/L ND 3.0 12/21/16 16:270.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 17 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323613001, 92323613002
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/21/16 16:270.21
Dichlorodifluoromethane ug/L ND 5.0 12/21/16 16:270.21
Ethyl methacrylate ug/L ND 10.0 12/21/16 16:270.20
Ethylbenzene ug/L ND 1.0 12/21/16 16:270.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/21/16 16:270.71
Iodomethane ug/L ND 10.0 12/21/16 16:270.32
Isobutanol ug/L ND 100 12/21/16 16:2735.0
Methacrylonitrile ug/L ND 100 12/21/16 16:270.93
Methyl methacrylate ug/L ND 30.0 12/21/16 16:272.0
Methylene Chloride ug/L ND 1.0 12/21/16 16:270.97
Naphthalene ug/L ND 10.0 12/21/16 16:270.24
Propionitrile ug/L ND 150 12/21/16 16:273.6
Styrene ug/L ND 1.0 12/21/16 16:270.26
Tetrachloroethene ug/L ND 1.0 12/21/16 16:270.46
Toluene ug/L ND 1.0 12/21/16 16:270.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/21/16 16:270.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/21/16 16:271.0
Trichloroethene ug/L ND 1.0 12/21/16 16:270.47
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:270.20
Vinyl acetate ug/L ND 50.0 12/21/16 16:270.35
Vinyl chloride ug/L ND 1.0 12/21/16 16:270.62
Xylene (Total)ug/L ND 5.0 12/21/16 16:270.66
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L05073 79-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,1-Dichloropropene ug/L 53.650 107 74-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2,4-Trichlorobenzene ug/L 56.250 112 75-134
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 18 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 45.650 91 77-130
1,3-Dichloropropane ug/L 48.150 96 76-131
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2,2-Dichloropropane ug/L 53.050 106 40-160
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acetonitrile ug/L 527500 105 62-150
Acrolein ug/L 223250 89 24-160
Acrylonitrile ug/L 292250 117 40-160
Allyl chloride ug/L 48.450 97 66-137
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.6J50 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
Chloroprene ug/L 57.050 114 75-145
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Dichlorodifluoromethane ug/L 44.650 89 34-157
Ethyl methacrylate ug/L 50.650 101 82-121
Ethylbenzene ug/L 40.650 81 79-121
Hexachloro-1,3-butadiene ug/L 60.650 121 72-131
Iodomethane ug/L 75.3100 75 39-154
Isobutanol ug/L 9791000 98 34-160
Methacrylonitrile ug/L 455500 91 74-134
Methyl methacrylate ug/L 53.350 107 84-124
Methylene Chloride ug/L 54.950 110 64-133
Naphthalene ug/L 57.350 115 73-133
Propionitrile ug/L 485500 97 73-140
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.5J50 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Page 19 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,1-Dichloropropene ug/L 20.020 100 70-130ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2,4-Trichlorobenzene ug/L 19.420 97 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,3-Dichlorobenzene ug/L 19.720 99 70-130ND
1,3-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2,2-Dichloropropane ug/L 22.620 113 70-130ND
2-Butanone (MEK)ug/L 35.8J40 89 70-130ND
2-Hexanone ug/L 39.0J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.0J40 97 70-130ND
Acetone ug/L 40.5J40 98 70-130ND
Acetonitrile ug/L 232200 116 70-130ND
Acrolein ug/L 83.8100 84 70-130ND
Acrylonitrile ug/L 125J100 125 70-130ND
Allyl chloride ug/L 20.920 105 70-130ND
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.5J20 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Page 20 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
Chloroprene ug/L 25.220 126 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Dichlorodifluoromethane ug/L 20.420 102 70-130ND
Ethyl methacrylate ug/L 19.620 98 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Hexachloro-1,3-butadiene ug/L 22.120 111 70-130ND
Iodomethane ug/L 23.2 M14058 70-130ND
Isobutanol ug/L 416400 104 70-130ND
Methacrylonitrile ug/L 183200 92 70-130ND
Methyl methacrylate ug/L 18.3J20 91 70-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
Naphthalene ug/L 20.320 101 70-130ND
Propionitrile ug/L 197200 99 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.4J20 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.6J40 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 1.2J 2 301.2J
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 21 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L 0.45J 300.39J
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.4 0 301.4
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L 0.72J 300.72J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 5.4 10 304.9
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.16J 300.11J
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 3.3J 1 303.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L 1.0J 300.93J
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L 0.37J 300.37J
trans-1,2-Dichloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 22 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.76J 300.58J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 4.9 6 304.6
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341799
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896365
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/22/16 17:160.050
4,4'-DDE ug/L ND 0.10 12/22/16 17:160.050
4,4'-DDT ug/L ND 0.10 12/22/16 17:160.050
Aldrin ug/L ND 0.050 12/22/16 17:160.050
alpha-BHC ug/L ND 0.050 12/22/16 17:160.050
beta-BHC ug/L ND 0.050 12/22/16 17:160.050
Chlordane (Technical)ug/L ND 0.50 12/22/16 17:160.20
delta-BHC ug/L ND 0.050 12/22/16 17:160.050
Dieldrin ug/L ND 0.075 12/22/16 17:160.050
Endosulfan I ug/L ND 0.10 12/22/16 17:160.050
Endosulfan II ug/L ND 0.10 12/22/16 17:160.050
Endosulfan sulfate ug/L ND 0.10 12/22/16 17:160.050
Endrin ug/L ND 0.10 12/22/16 17:160.050
Endrin aldehyde ug/L ND 0.10 12/22/16 17:160.050
gamma-BHC (Lindane)ug/L ND 0.050 12/22/16 17:160.050
Heptachlor ug/L ND 0.050 12/22/16 17:160.050
Heptachlor epoxide ug/L ND 0.075 12/22/16 17:160.050
Methoxychlor ug/L ND 1.0 12/22/16 17:160.15
Toxaphene ug/L ND 1.5 12/22/16 17:160.20
Decachlorobiphenyl (S)%104 20-130 12/22/16 17:16
Tetrachloro-m-xylene (S)%88 20-130 12/22/16 17:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.27.25 108 20-150
4,4'-DDE ug/L 0.25.25 101 20-150
4,4'-DDT ug/L 0.27.25 108 20-150
Aldrin ug/L 0.22.25 89 20-150
alpha-BHC ug/L 0.24.25 97 20-150
beta-BHC ug/L 0.25.25 102 20-150
delta-BHC ug/L 0.27.25 108 20-150
Dieldrin ug/L 0.25.25 102 20-150
Endosulfan I ug/L 0.27.25 109 20-150
Endosulfan II ug/L 0.28.25 115 20-150
Endosulfan sulfate ug/L 0.29.25 116 20-150
Endrin ug/L 0.28.25 114 20-150
Endrin aldehyde ug/L 0.26.25 103 20-150
gamma-BHC (Lindane)ug/L 0.24.25 98 20-150
Heptachlor ug/L 0.23.25 93 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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[phone]
Page 24 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.25.25 103 20-150
Methoxychlor ug/L 0.91J.74 123 20-150
Decachlorobiphenyl (S)%91 20-130
Tetrachloro-m-xylene (S)%94 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896367MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896368
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 109 20-150112 2 30.5ND 0.54 0.55
4,4'-DDE ug/L .5 108 20-150111 3 30.5ND 0.53 0.55
4,4'-DDT ug/L .5 112 20-150115 3 30.5ND 0.55 0.57
Aldrin ug/L .5 91 20-15099 8 30.5ND 0.45 0.49
alpha-BHC ug/L .5 89 20-15096 7 30.5ND 0.44 0.47
beta-BHC ug/L .5 103 20-150106 2 30.5ND 0.51 0.52
delta-BHC ug/L .5 94 20-15098 4 30.5ND 0.46 0.49
Dieldrin ug/L .5 104 20-150108 4 30.5ND 0.51 0.53
Endosulfan I ug/L .5 111 20-150113 2 30.5ND 0.55 0.56
Endosulfan II ug/L .5 114 20-150120 5 30.5ND 0.57 0.60
Endosulfan sulfate ug/L .5 120 20-150125 4 30.5ND 0.60 0.62
Endrin ug/L .5 115 20-150122 6 30.5ND 0.57 0.60
Endrin aldehyde ug/L .5 106 20-150107 2 30.5ND 0.52 0.53
gamma-BHC (Lindane)ug/L .5 92 20-15097 5 30.5ND 0.46 0.48
Heptachlor ug/L .5 85 20-15092 8 30.5ND 0.42 0.46
Heptachlor epoxide ug/L .5 103 20-150106 3 30.5ND 0.51 0.52
Methoxychlor ug/L 1.5 125 20-150128 3 301.5ND 1.9J 1.9J
Decachlorobiphenyl (S)%85 20-13088
Tetrachloro-m-xylene (S)%89 20-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341274
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893343
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/19/16 13:170.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/19/16 13:170.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/19/16 13:170.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/19/16 13:170.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/19/16 13:170.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/19/16 13:170.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/19/16 13:170.50
Decachlorobiphenyl (S)%92 10-132 12/19/16 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893344LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1893345
PCB-1016 (Aroclor 1016)ug/L 4.85 95 50-150904.5 6 30
PCB-1260 (Aroclor 1260)ug/L 5.55 111 50-1501035.1 8 30
Decachlorobiphenyl (S)%82 10-13279
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339874
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1823467
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/23/16 05:410.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/23/16 05:410.049
2,4-D ug/L ND 0.94 12/23/16 05:410.22
Dinoseb ug/L ND 0.19 12/23/16 05:410.057
2,4-DCAA (S)%85 39-139 12/23/16 05:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1823468LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1823948
2,4,5-T ug/L 1.31.2 108 37-1331181.4 9 40
2,4,5-TP (Silvex)ug/L 1.01.2 84 53-134961.2 14 40
2,4-D ug/L 6.16 101 35-1241106.6 8 40
Dinoseb ug/L 0.851.2 70 13-116820.98 15 40
2,4-DCAA (S)%82 39-13990 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341825
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/22/16 10:331.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/22/16 10:331.1
1,3-Dinitrobenzene ug/L ND 20.0 12/22/16 10:331.5
1,4-Naphthoquinone ug/L ND 10.0 12/22/16 10:331.8
1-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.96
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 12/22/16 10:331.6
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/22/16 10:332.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/22/16 10:332.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/22/16 10:331.9
2,4-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.7
2,4-Dimethylphenol ug/L ND 10.0 12/22/16 10:332.2
2,4-Dinitrophenol ug/L ND 50.0 12/22/16 10:336.5
2,4-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.2
2,6-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.8
2,6-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.7
2-Acetylaminofluorene ug/L ND 20.0 12/22/16 10:330.84
2-Chloronaphthalene ug/L ND 10.0 12/22/16 10:332.2
2-Chlorophenol ug/L ND 10.0 12/22/16 10:331.5
2-Methylnaphthalene ug/L ND 10.0 12/22/16 10:330.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/22/16 10:331.7
2-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.98
2-Nitroaniline ug/L ND 50.0 12/22/16 10:332.8
2-Nitrophenol ug/L ND 10.0 12/22/16 10:331.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/22/16 10:331.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/22/16 10:331.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/22/16 10:332.1
3-Methylcholanthrene ug/L ND 10.0 12/22/16 10:330.82
3-Nitroaniline ug/L ND 50.0 12/22/16 10:332.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/22/16 10:331.7
4-Aminobiphenyl ug/L ND 20.0 12/22/16 10:330.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/22/16 10:331.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/22/16 10:334.2
4-Chloroaniline ug/L ND 20.0 12/22/16 10:333.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/22/16 10:332.1
4-Nitroaniline ug/L ND 20.0 12/22/16 10:332.5
4-Nitrophenol ug/L ND 50.0 12/22/16 10:335.8
5-Nitro-o-toluidine ug/L ND 10.0 12/22/16 10:331.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/22/16 10:330.77
Acenaphthene ug/L ND 10.0 12/22/16 10:330.25
Acenaphthylene ug/L ND 10.0 12/22/16 10:330.21
Acetophenone ug/L ND 10.0 12/22/16 10:332.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
Anthracene ug/L ND 10.0 12/22/16 10:330.14
Benzo(a)anthracene ug/L ND 10.0 12/22/16 10:330.33
Benzo(a)pyrene ug/L ND 10.0 12/22/16 10:330.30
Benzo(b)fluoranthene ug/L ND 10.0 12/22/16 10:330.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/22/16 10:330.38
Benzo(k)fluoranthene ug/L ND 10.0 12/22/16 10:330.43
Benzyl alcohol ug/L ND 20.0 12/22/16 10:333.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/22/16 10:331.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/22/16 10:331.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/22/16 10:330.85
Butylbenzylphthalate ug/L ND 10.0 12/22/16 10:330.75
Chlorobenzilate ug/L ND 10.0 12/22/16 10:330.72
Chrysene ug/L ND 10.0 12/22/16 10:330.21
Di-n-butylphthalate ug/L ND 10.0 12/22/16 10:331.1
Di-n-octylphthalate ug/L ND 10.0 12/22/16 10:330.86
Diallate ug/L ND 10.0 12/22/16 10:331.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/22/16 10:330.55
Dibenzofuran ug/L ND 10.0 12/22/16 10:331.8
Diethylphthalate ug/L ND 6000 12/22/16 10:331.3
Dimethoate ug/L ND 20.0 12/22/16 10:330.92
Dimethylphthalate ug/L ND 10.0 12/22/16 10:331.5
Diphenylamine ug/L ND 10.0 12/22/16 10:331.3
Disulfoton ug/L ND 10.0 12/22/16 10:331.4
Ethyl methanesulfonate ug/L ND 20.0 12/22/16 10:331.8
Famphur ug/L ND 20.0 12/22/16 10:331.7
Fluoranthene ug/L ND 10.0 12/22/16 10:330.21
Fluorene ug/L ND 10.0 12/22/16 10:330.21
Hexachlorobenzene ug/L ND 10.0 12/22/16 10:331.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/22/16 10:331.8
Hexachloroethane ug/L ND 10.0 12/22/16 10:331.5
Hexachloropropene ug/L ND 10.0 12/22/16 10:331.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/22/16 10:330.29
Isodrin ug/L ND 20.0 12/22/16 10:332.0
Isophorone ug/L ND 10.0 12/22/16 10:331.8
Isosafrole ug/L ND 10.0 12/22/16 10:331.8
Kepone ug/L ND 20.0 12/22/16 10:333.1
Methapyrilene ug/L ND 100 12/22/16 10:332.7
Methyl methanesulfonate ug/L ND 10.0 12/22/16 10:331.3
Methyl parathion ug/L ND 10.0 12/22/16 10:331.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/22/16 10:332.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/22/16 10:332.1
N-Nitrosodiethylamine ug/L ND 20.0 12/22/16 10:331.8
N-Nitrosodimethylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/22/16 10:331.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Page 29 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/22/16 10:331.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/22/16 10:332.5
Nitrobenzene ug/L ND 10.0 12/22/16 10:331.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/22/16 10:331.8
O-Toluidine ug/L ND 10.0 12/22/16 10:331.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/22/16 10:330.35
p-Phenylenediamine ug/L ND 10.0 12/22/16 10:330.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/22/16 10:331.1
Pentachlorobenzene ug/L ND 10.0 12/22/16 10:332.0
Pentachloronitrobenzene ug/L ND 20.0 12/22/16 10:331.0
Pentachlorophenol ug/L ND 25.0 12/22/16 10:332.3
Phenacetin ug/L ND 20.0 12/22/16 10:330.97
Phenanthrene ug/L ND 10.0 12/22/16 10:330.22
Phenol ug/L ND 10.0 12/22/16 10:331.7
Phorate ug/L ND 10.0 12/22/16 10:331.1
Pronamide ug/L ND 10.0 12/22/16 10:330.97
Pyrene ug/L ND 10.0 12/22/16 10:330.19
Safrole ug/L ND 10.0 12/22/16 10:331.5
Thionazin ug/L ND 20.0 12/22/16 10:331.2
2,4,6-Tribromophenol (S)%70 27-110 12/22/16 10:33
2-Fluorobiphenyl (S)%54 27-110 12/22/16 10:33
2-Fluorophenol (S)%26 12-110 12/22/16 10:33
Nitrobenzene-d5 (S)%50 21-110 12/22/16 10:33
Phenol-d6 (S)%23 10-110 12/22/16 10:33
Terphenyl-d14 (S)%71 31-107 12/22/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 33.650 67 16-129
1,3,5-Trinitrobenzene ug/L 43.250 86 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 37.450 75 31-120
1-Naphthalenamine ug/L 24.050 48 37-126
2,2'-Oxybis(1-chloropropane)ug/L 36.150 72 18-120
2,3,4,6-Tetrachlorophenol ug/L 56.550 113 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 41.050 82 42-120
2,4-Dichlorophenol ug/L 38.450 77 30-120
2,4-Dimethylphenol ug/L 38.750 77 29-111
2,4-Dinitrophenol ug/L 123250 49 19-132
2,4-Dinitrotoluene ug/L 42.350 85 58-128
2,6-Dichlorophenol ug/L 42.550 85 54-128
2,6-Dinitrotoluene ug/L 42.850 86 54-129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Huntersville, NC 28078
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Page 30 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
2-Acetylaminofluorene ug/L 43.750 87 81-160
2-Chloronaphthalene ug/L 41.150 82 43-117
2-Chlorophenol ug/L 36.050 72 37-120
2-Methylnaphthalene ug/L 37.550 75 33-120
2-Methylphenol(o-Cresol)ug/L 25.350 51 31-120
2-Naphthalenamine ug/L 36.650 73 41-136
2-Nitroaniline ug/L 68.5100 69 48-121
2-Nitrophenol ug/L 37.350 75 25-116
3&4-Methylphenol(m&p Cresol)ug/L 38.850 78 23-120
3,3'-Dichlorobenzidine ug/L 86.0250 34 10-154
3,3'-Dimethylbenzidine ug/L 62.6100 63 10-157
3-Methylcholanthrene ug/L 47.750 95 65-130
3-Nitroaniline ug/L 82.5100 83 43-115
4,6-Dinitro-2-methylphenol ug/L 89.5100 89 44-124
4-Aminobiphenyl ug/L 33.650 67 21-125
4-Bromophenylphenyl ether ug/L 37.950 76 34-113
4-Chloro-3-methylphenol ug/L 73.5100 73 31-110
4-Chloroaniline ug/L 67.3100 67 20-120
4-Chlorophenylphenyl ether ug/L 37.750 75 34-116
4-Nitroaniline ug/L 89.4100 89 46-128
4-Nitrophenol ug/L 76.4250 31 11-120
5-Nitro-o-toluidine ug/L 42.150 84 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.250 94 47-124
Acenaphthene ug/L 39.450 79 48-114
Acenaphthylene ug/L 40.750 81 48-112
Acetophenone ug/L 32.650 65 24-120
Anthracene ug/L 41.650 83 57-118
Benzo(a)anthracene ug/L 41.350 83 56-121
Benzo(a)pyrene ug/L 45.750 91 55-127
Benzo(b)fluoranthene ug/L 44.150 88 53-128
Benzo(g,h,i)perylene ug/L 45.950 92 54-125
Benzo(k)fluoranthene ug/L 46.850 94 51-123
Benzyl alcohol ug/L 57.5100 57 27-120
bis(2-Chloroethoxy)methane ug/L 35.650 71 32-120
bis(2-Chloroethyl) ether ug/L 36.450 73 33-111
bis(2-Ethylhexyl)phthalate ug/L 48.250 96 50-145
Butylbenzylphthalate ug/L 47.650 95 54-138
Chlorobenzilate ug/L 45.250 90 65-132
Chrysene ug/L 41.350 83 58-127
Di-n-butylphthalate ug/L 47.250 94 56-125
Di-n-octylphthalate ug/L 49.350 99 50-134
Diallate ug/L 48.250 96 47-123
Dibenz(a,h)anthracene ug/L 47.150 94 53-129
Dibenzofuran ug/L 39.650 79 45-120
Diethylphthalate ug/L 43.4J50 87 53-120
Dimethoate ug/L 50.850 102 57-139
Dimethylphthalate ug/L 41.150 82 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 31 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 42.350 85 42-120
Disulfoton ug/L 50.050 100 49-156
Ethyl methanesulfonate ug/L 38.250 76 43-120
Famphur ug/L 45.6100 46 40-160
Fluoranthene ug/L 45.450 91 57-125
Fluorene ug/L 41.450 83 53-118
Hexachlorobenzene ug/L 39.850 80 49-116
Hexachlorocyclopentadiene ug/L 34.350 69 26-158
Hexachloroethane ug/L 29.350 59 30-114
Hexachloropropene ug/L 33.350 67 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.650 95 55-128
Isodrin ug/L 46.450 93 68-129
Isophorone ug/L 35.550 71 31-118
Isosafrole ug/L 32.650 65 48-107
Kepone ug/L 45.7100 46 10-124
Methapyrilene ug/L 51.7J50 103 40-160
Methyl methanesulfonate ug/L 25.350 51 25-114
Methyl parathion ug/L 51.750 103 58-137
N-Nitroso-di-n-butylamine ug/L 30.850 62 36-115
N-Nitroso-di-n-propylamine ug/L 38.050 76 32-119
N-Nitrosodiethylamine ug/L 38.250 76 47-115
N-Nitrosodimethylamine ug/L 24.850 50 13-120
N-Nitrosodiphenylamine ug/L 42.350 85 43-120
N-Nitrosomethylethylamine ug/L 33.450 67 39-120
N-Nitrosopiperidine ug/L 43.950 88 43-113
N-Nitrosopyrrolidine ug/L 35.650 71 32-110
Nitrobenzene ug/L 33.950 68 33-110
O,O,O-Triethylphosphorothioate ug/L 37.850 76 51-127
O-Toluidine ug/L 33.650 67 27-120
P-Dimethylaminoazobenzene ug/L 19.3100 19 10-120
p-Phenylenediamine ug/L 45.950 92 72-143
Parathion (Ethyl parathion)ug/L 50.750 101 56-140
Pentachlorobenzene ug/L 35.650 71 30-137
Pentachloronitrobenzene ug/L 49.950 100 70-124
Pentachlorophenol ug/L 89.3250 36 10-137
Phenacetin ug/L 46.650 93 60-130
Phenanthrene ug/L 41.150 82 57-117
Phenol ug/L 17.350 35 10-120
Phorate ug/L 51.650 103 55-126
Pronamide ug/L 51.550 103 75-124
Pyrene ug/L 39.350 79 55-122
Safrole ug/L 39.450 79 41-120
Thionazin ug/L 40.050 80 63-137
2,4,6-Tribromophenol (S)%43 27-110
2-Fluorobiphenyl (S)%36 27-110
2-Fluorophenol (S)%20 12-110
Nitrobenzene-d5 (S)%35 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%14 10-110
Terphenyl-d14 (S)%38 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
1,2,4,5-Tetrachlorobenzene ug/L 33.050 66 50-150ND
1,3,5-Trinitrobenzene ug/L 48.950 98 50-150ND
1,3-Dinitrobenzene ug/L 40.450 81 50-150ND
1,4-Naphthoquinone ug/L 33.950 68 50-150ND
1-Naphthalenamine ug/L 23.3 M15047 50-150ND
2,2'-Oxybis(1-chloropropane)ug/L 28.150 56 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 38.450 77 50-150ND
2,4,5-Trichlorophenol ug/L 27.650 55 19-105ND
2,4,6-Trichlorophenol ug/L 25.050 50 13-108ND
2,4-Dichlorophenol ug/L 34.450 69 29-111ND
2,4-Dimethylphenol ug/L 36.750 73 21-103ND
2,4-Dinitrophenol ug/L 28.1J250 11 10-109ND
2,4-Dinitrotoluene ug/L 37.650 75 27-104ND
2,6-Dichlorophenol ug/L 33.350 67 50-150ND
2,6-Dinitrotoluene ug/L 41.750 83 28-101ND
2-Acetylaminofluorene ug/L 40.550 81 50-150ND
2-Chloronaphthalene ug/L 43.950 88 14-102ND
2-Chlorophenol ug/L 31.250 62 16-110ND
2-Methylnaphthalene ug/L 39.850 80 13-110ND
2-Methylphenol(o-Cresol)ug/L 22.650 45 19-110ND
2-Naphthalenamine ug/L 30.350 61 50-150ND
2-Nitroaniline ug/L 59.8100 60 26-103ND
2-Nitrophenol ug/L 33.350 67 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 47.650 95 20-110ND
3,3'-Dichlorobenzidine ug/L 82.5250 33 25-112ND
3,3'-Dimethylbenzidine ug/L 53.4100 53 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 75.3100 75 29-110ND
4,6-Dinitro-2-methylphenol ug/L 51.8100 52 10-117ND
4-Aminobiphenyl ug/L 34.950 70 50-150ND
4-Bromophenylphenyl ether ug/L 40.950 82 20-105ND
4-Chloro-3-methylphenol ug/L 64.1100 64 22-110ND
4-Chloroaniline ug/L 66.4100 66 20-100ND
4-Chlorophenylphenyl ether ug/L 41.850 84 19-102ND
4-Nitroaniline ug/L 99.6100 100 29-110ND
4-Nitrophenol ug/L 36.2J250 14 10-110ND
5-Nitro-o-toluidine ug/L 42.950 86 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 43.750 87 50-150ND
Acenaphthene ug/L 38.350 77 17-100ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
Acenaphthylene ug/L 39.650 79 21-100ND
Acetophenone ug/L 30.850 62 50-150ND
Anthracene ug/L 40.550 81 24-109ND
Benzo(a)anthracene ug/L 39.450 79 22-117ND
Benzo(a)pyrene ug/L 42.050 84 23-104ND
Benzo(b)fluoranthene ug/L 41.050 82 23-103ND
Benzo(g,h,i)perylene ug/L 42.350 85 18-111ND
Benzo(k)fluoranthene ug/L 42.750 85 22-113ND
Benzyl alcohol ug/L 48.7100 49 19-101ND
bis(2-Chloroethoxy)methane ug/L 32.350 65 22-110ND
bis(2-Chloroethyl) ether ug/L 33.950 68 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 42.550 85 23-102ND
Butylbenzylphthalate ug/L 41.950 84 25-110ND
Chlorobenzilate ug/L 42.450 84 50-150ND
Chrysene ug/L 39.850 80 23-115ND
Di-n-butylphthalate ug/L 44.150 88 26-110ND
Di-n-octylphthalate ug/L 43.850 88 22-110ND
Diallate ug/L 46.450 93 50-150ND
Dibenz(a,h)anthracene ug/L 41.250 82 21-112ND
Dibenzofuran ug/L 40.450 81 19-102ND
Diethylphthalate ug/L 39.2J50 78 29-110ND
Dimethoate ug/L 50.950 102 50-150ND
Dimethylphthalate ug/L 42.950 86 27-110ND
Diphenylamine ug/L 49.550 99 50-150ND
Disulfoton ug/L 41.050 82 50-150ND
Ethyl methanesulfonate ug/L 34.450 69 50-150ND
Famphur ug/L 51.1100 51 50-150ND
Fluoranthene ug/L 45.150 90 23-112ND
Fluorene ug/L 46.050 92 22-104ND
Hexachlorobenzene ug/L 42.750 85 21-116ND
Hexachlorocyclopentadiene ug/L 33.950 68 10-110ND
Hexachloroethane ug/L 29.550 59 10-110ND
Hexachloropropene ug/L 37.550 75 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 43.150 86 20-113ND
Isodrin ug/L 45.950 92 50-150ND
Isophorone ug/L 31.950 64 50-150ND
Isosafrole ug/L 31.950 64 50-150ND
Kepone ug/L 60.3100 60 50-150ND
Methapyrilene ug/L 46.8J50 94 50-150ND
Methyl methanesulfonate ug/L 26.950 54 50-150ND
Methyl parathion ug/L 46.350 93 50-150ND
N-Nitroso-di-n-butylamine ug/L 30.250 60 50-150ND
N-Nitroso-di-n-propylamine ug/L 32.750 65 21-105ND
N-Nitrosodiethylamine ug/L 43.250 86 50-150ND
N-Nitrosodimethylamine ug/L 23.050 46 10-110ND
N-Nitrosodiphenylamine ug/L 49.550 99 23-107ND
N-Nitrosomethylethylamine ug/L 31.950 64 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 34 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.050 62 50-150ND
Nitrobenzene ug/L 28.250 56 20-110ND
O,O,O-Triethylphosphorothioate ug/L 39.250 78 50-150ND
O-Toluidine ug/L 28.750 57 50-150ND
P-Dimethylaminoazobenzene ug/L 18.4 M110018 50-150ND
p-Phenylenediamine ug/L 43.850 88 50-150ND
Parathion (Ethyl parathion)ug/L 45.450 91 50-150ND
Pentachlorobenzene ug/L 34.750 69 50-150ND
Pentachloronitrobenzene ug/L 43.150 86 50-150ND
Pentachlorophenol ug/L 32.6250 13 10-118ND
Phenacetin ug/L 45.550 91 50-150ND
Phenanthrene ug/L 41.250 82 24-106ND
Phenol ug/L 14.750 29 12-110ND
Phorate ug/L 46.150 92 50-150ND
Pronamide ug/L 49.050 98 50-150ND
Pyrene ug/L 35.650 71 24-114ND
Safrole ug/L 40.950 82 50-150ND
Thionazin ug/L 42.550 85 50-150ND
2,4,6-Tribromophenol (S)%70 27-110
2-Fluorobiphenyl (S)%75 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%56 21-110
Phenol-d6 (S)%23 10-110
Terphenyl-d14 (S)%68 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,2'-Oxybis(1-chloropropane)ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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[phone]
Page 36 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%68 169
2-Fluorobiphenyl (S)%58 1165
2-Fluorophenol (S)%22 2227
Nitrobenzene-d5 (S)%51 654
Phenol-d6 (S)%15 1818
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 37 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Terphenyl-d14 (S)%70 473
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341532
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894991
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/20/16 15:05100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894992LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 527J500 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323602010
1894994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15001580-12015 10500NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894995MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323608006
1894996
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15004680-12046 0 10500ND231J 231J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323613001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 45
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
BATCH QUALIFIERS
Batch: 340487
A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.[M5]
ANALYTE QUALIFIERS
Extraction or preparation conducted outside EPA method holding time.H2
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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[phone]
Page 41 of 45
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323613001 341799 3422261203-Field Blank EPA 3510 EPA 8081
92323613001 341274 3414911203-Field Blank EPA 3510 EPA 8082
92323613001 339874 3404871203-Field Blank EPA 8151 EPA 8151
92323613001 341173 3415711203-Field Blank EPA 3010A EPA 6010
92323613001 341661 3419801203-Field Blank EPA 7470 EPA 7470
92323613001 341825 3421661203-Field Blank EPA 3510 EPA 8270
92323613001 3420101203-Field Blank EPA 8260
92323613002 3420101203-Trip Blank EPA 8260
92323613001 3415321203-Field Blank SM 4500-S2D
92323613001 3425331203-Field Blank SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
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[phone]
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Page 43 of 45
Page 44 of 45
Page 45 of 45

Appendix C

Statistical Analyses Worksheets

JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Analyte:Cobalt
Sample No. Sample Date Location Concentration RL
1 Sep-94 MW-9 52 2.6 120
2 Jan-95 MW-9 35 10 4.0 52
3 Feb-95 MW-9 16 10 4.1 37
4 Mar-95 MW-9 28 10 5.4 37
5 Aug-95 MW-9 ND 10 7.3 35
6 Jan-96 MW-9 17 10 7.8 33
7 Feb-96 MW-9 37 10 9.2 29
8 May-96 MW-9 11 10 9.8 28
9 Oct-96 MW-9 16 10 10 28
10 May-97 MW-9 33 6 10 26
11 Nov-97 MW-9 29 5 10 26
12 May-98 MW-9 28 1 11 22.1
13 Nov-98 MW-9 10 1 12 20
14 May-99 MW-9 20 5 14.9 20
15 Oct-99 MW-9 120 10 16 19.1
16 May-00 MW-9 ND 10 16 19
17 Nov-00 MW-9 ND 10 17 17
18 May-01 MW-9 ND 10 19 16
19 Nov-01 MW-9 ND 10 19.1 16
20 Nov-02 MW-9 ND 10 20 14.9
21 May-03 MW-9 19 10 20 12
22 Nov-03 MW-9 26 10 22.1 11
23 May-04 MW-9 ND 10 26 10
24 Nov-04 MW-9 10 10 26 10
25 May-05 MW-9 12 10 28 10
26 May-99 MW-17 26 10 28 9.8
27 Oct-99 MW-17 37 10 29 9.2
28 May-00 MW-17 ND 10 33 7.8
29 Nov-00 MW-17 20 10 35 7.3
30 May-01 MW-17 ND 10 37 5.4
31 Nov-01 MW-17 ND 10 37 4.1
32 Nov-02 MW-17 ND 10 52 4.0
33 May-03 MW-17 ND 10 120 2.6
34 Nov-03 MW-17 10 J 10
35 May-04 MW-17 ND 10
36 Nov-04 MW-17 ND 10
37 May-05 MW-17 ND 10
38 Nov-05 MW-17 ND 10
39 25-May-06 MW-17 ND 10
40 02-Nov-06 MW-17 ND 10
41 31-May-07 MW-17 4.1 J 10
42 29-Nov-07 MW-17 7.3 J 10
43 29-May-08 MW-17 5.4 J 10
44 06-Nov-08 MW-17 9.2 J 10
45 18-Nov-09 MW-17 14.9 10
46 16-Jun-10 MW-17 19.1 10
47 01-Dec-10 MW-17 9.8 J 10.0
48 01-Dec-10 MW-20 22.1 10.0
49 13-Jan-11 MW-20 ND 10.0
50 01-Jun-11 MW-17 7.8 J 10.0
51 01-Jun-11 MW-20 2.6 J 10.0
52 20-Dec-11 MW-20 ND 10.0
53 30-May-12 MW-20 ND 10.0
54 05-Dec-12 MW-20 ND 10.0
55 12-Jun-13 MW-20 ND 10.0
56 28-Oct-13 MW-20 ND 10.0
57 06-May-14 MW-20 ND 10.0
58 23-Oct-14 MW-21 ND 10.0
59 21-May-15 MW-21 ND 10.0
60 08-Dec-15 MW-21 ND 10.0
61 03-May-16 MW-21 4.0 J 10.0
62 13-Dec-16 MW-21 ND 10.0
Number of Data: 62
Number of Truncated Data: 29
Percentage of Truncated Data: 47%
Upper Tolerance Limit: 90.7 µg/L
Notes: All concentrations in micrograms per liter (µg/L).
J = Estimated Data (used in statistical analyses)
ND = Not detected (truncated).
Sorted
Concentration
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Shapiro Wilk Test Statistic (W) for normality of total Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 2.6 120 117.40 0.4156 48.7914
2 4.0 52 48.00 0.2876 13.8048
3 4.1 37 32.90 0.2451 8.0638
4 5.4 37 31.60 0.2137 6.7529
5 7.3 35 27.70 0.1880 5.2076
6 7.8 33 25.20 0.1660 4.1832
7 9.2 29 19.80 0.1463 2.8967
8 9.8 28 18.20 0.1284 2.3369
9 10.0 28 18.00 0.1118 2.0124
10 10.0 26 16.00 0.0961 1.5376
11 10.0 26 16.00 0.0812 1.2992
12 11.0 22 11.10 0.0669 0.7426
13 12.0 20 8.00 0.0530 0.4240
14 14.9 20 5.10 0.0395 0.2015
15 16.0 19 3.10 0.0262 0.08
16 16.0 19 3.00 0.0131 0.04
17 17.0 17 0.00 0.0000 0.00
18 19.0 16 -3.00
19 19.1 16 -3.10
20 20.0 15 -5.10
21 20.0 12 -8.00
22 22.1 11 -11.10
23 26.0 10 -16.00
24 26.0 10 -16.00
25 28.0 10 -18.00
26 28.0 10 -18.20
27 29.0 9 -19.80
28 33.0 8 -25.20
29 35.0 7 -27.70
30 37.0 5 -31.60
31 37.0 4 -32.90
32 52.0 4 -48.00
33 120.0 3 -117.40
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where:B = summation of (X(n-i+1)-X(i))A(n-i+1)= 98.38
SD = standard deviation of the data group = 21.10
n = number of samples = 33
W = 0.679
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.931
and the calculated W = 0.679
Therefore the data is Non-Normal.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Shapiro Wilk Test Statistic (W) for log normality of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 0.96 4.79 3.8320 0.4156 1.5926
2 1.39 3.95 2.5649 0.2876 0.7377
3 1.41 3.61 2.1999 0.2451 0.5392
4 1.69 3.61 1.9245 0.2137 0.4113
5 1.99 3.56 1.5675 0.1880 0.2947
6 2.05 3.50 1.4424 0.1660 0.2394
7 2.22 3.37 1.1481 0.1463 0.1680
8 2.28 3.33 1.0498 0.1284 0.1348
9 2.30 3.33 1.0296 0.1118 0.1151
10 2.30 3.26 0.9555 0.0961 0.0918
11 2.30 3.26 0.9555 0.0812 0.0776
12 2.40 3.10 0.6977 0.0669 0.0467
13 2.48 3.00 0.5108 0.0530 0.0271
14 2.70 3.00 0.2944 0.0395 0.0116
15 2.77 2.95 0.1771 0.0262 0.0046
16 2.77 2.94 0.1719 0.0131 0.0023
17 2.83 2.83 0.0000 0.0000 0.0000
18 2.94 2.77 -0.1719
19 2.95 2.77 -0.1771
20 3.00 2.70 -0.2944
21 3.00 2.48 -0.5108
22 3.10 2.40 -0.6977
23 3.26 2.30 -0.9555
24 3.26 2.30 -0.9555
25 3.33 2.30 -1.0296
26 3.33 2.28 -1.0498
27 3.37 2.22 -1.1481
28 3.50 2.05 -1.4424
29 3.56 1.99 -1.5675
30 3.61 1.69 -1.9245
31 3.61 1.41 -2.1999
32 3.95 1.39 -2.5649
33 4.79 0.96 -3.8320
The test statistic W can be found using:
W = SQR((B/SD x SQRT(n-1))
where:B = summation of (X(n-i+1)-X(i))A(n-i+1) = 4.4944
SD = standard deviation of the data group = 0.8011
n = number of samples = 33
W = 0.9835
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.931
and the calculated W = 0.984
Therefore the data set is Log-Normal.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Probability Plots to determine the distribution of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
LN[X(i)] = Natural Log Value of sample concentrations arranged from
smallest to largest
[i/(n+1)] = Cumulative probability
n = number of samples = 33
X(i)LN[X(i)] i Rank [Rank/(n+1)] Quantiles
2.6 0.96 1 1 0.029 -1.89
4 1.39 2 2 0.059 -1.56
4.1 1.41 3 3 0.088 -1.35
5.4 1.69 4 4 0.118 -1.19
7.3 1.99 5 5 0.147 -1.05
7.8 2.05 6 6 0.176 -0.93
9.2 2.22 7 7 0.206 -0.82
9.8 2.28 8 8 0.235 -0.72
10 2.30 9 9 0.265 -0.63
10 2.30 10 10 0.294 -0.54
10 2.30 11 11 0.324 -0.46
11 2.40 12 12 0.353 -0.38
12 2.48 13 13 0.382 -0.30
14.9 2.70 14 14 0.412 -0.22
16 2.77 15 15 0.441 -0.15
16 2.77 16 16 0.471 -0.07
17 2.83 17 17 0.500 0.00
19 2.94 18 18 0.529 0.07
19.1 2.95 19 19 0.559 0.15
20 3.00 20 20 0.588 0.22
20 3.00 21 21 0.618 0.30
22.1 3.10 22 22 0.647 0.38
26 3.26 23 23 0.676 0.46
26 3.26 24 24 0.706 0.54
28 3.33 25 25 0.735 0.63
28 3.33 26 26 0.765 0.72
29 3.37 27 27 0.794 0.82
33 3.50 28 28 0.824 0.93
35 3.56 29 29 0.853 1.05
37 3.61 30 30 0.882 1.19
37 3.61 31 31 0.912 1.35
52 3.95 32 32 0.941 1.56
120 4.79 33 33 0.971 1.89
Plot analysis indicates that the data more closely follow a normal distribution in the
log-transformed format.
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Probability Plots to determine the distribution of Cobalt
R² = 0.6351
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
050100150Quantile
Concentration (micrograms per liter)
Normal Probability Plot
Cobalt Concentrations
R² = 0.972
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
2.50
3.00
0.00 1.00 2.00 3.00 4.00 5.00 6.00Quantile
Ln [Concentration (micrograms per liter)]
Log Normal Probability Plot
Cobalt Concentrations
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Determination of reported background value as an outlier
Analyte:Cobalt
Background Data
Sample No. Sample Date Location ln(Concentration)
1 Sep-94 MW-9 3.951
2 Jan-95 MW-9 3.555
3 Feb-95 MW-9 2.773
4 Mar-95 MW-9 3.332
5 Aug-95 MW-9 ND
6 Jan-96 MW-9 2.833
7 Feb-96 MW-9 3.611
8 May-96 MW-9 2.398
9 Oct-96 MW-9 2.773
10 May-97 MW-9 3.49711 Nov-97 MW-9 3.367
12 May-98 MW-9 3.332
13 Nov-98 MW-9 2.303
14 May-99 MW-9 2.996
15 Oct-99 MW-9 4.787
16 May-00 MW-9 ND
17 Nov-00 MW-9 ND
18 May-01 MW-9 ND
19 Nov-01 MW-9 ND20 Nov-02 MW-9 ND
21 May-03 MW-9 2.944
22 Nov-03 MW-9 3.258
23 May-04 MW-9 ND
24 Nov-04 MW-9 2.303
25 May-05 MW-9 2.485
26 May-99 MW-17 3.258
27 Oct-99 MW-17 3.611
28 May-00 MW-17 ND
29 Nov-00 MW-17 2.996
30 May-01 MW-17 ND
31 Nov-01 MW-17 ND
32 Nov-02 MW-17 ND
33 May-03 MW-17 ND
34 Nov-03 MW-17 2.303
35 May-04 MW-17 ND
36 Nov-04 MW-17 ND
37 May-05 MW-17 ND
38 Nov-05 MW-17 ND
39 May-06 MW-17 ND
40 Nov-06 MW-17 ND
41 May-07 MW-17 1.411
42 Nov-07 MW-17 1.988
43 May-08 MW-17 1.686
44 Nov-08 MW-17 2.21945 Nov-09 MW-17 2.701
46 Jun-10 MW-17 2.950
47 Dec-10 MW-17 2.282
48 Dec-10 MW-20 3.096
49 Jan-11 MW-20 ND
50 Jun-11 MW-17 2.054
51 Jun-11 MW-20 0.956
52 Dec-11 MW-20 ND
53 May-12 MW-20 ND
54 Dec-12 MW-20 ND
55 Jun-13 MW-20 ND
56 Oct-13 MW-20 ND
57 May-14 MW-20 ND
58 Oct-14 MW-21 ND
59 May-15 MW-21 ND
60 Dec-15 MW-21 ND
61 May-16 MW-21 1.386
62 Dec-16 MW-21 ND
mean = 2.770
STD = 0.801
Note: All concentrations are micrograms per liter (µg/L)
Using the data listed above, form the statisitc Tn:
Tn = (Xn - mean) / STD
where: Xn = largest observed sample value
mean = mean of the background values
STD = standard deviation of the background values
For Xn = 4.787
mean = 2.770
STD = 0.801
Tn = 2.519
From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at
RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is
Number of samples = 33
Tc = 2.736
Since Tc>Tn, the sample result is not considered to be an outlier
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Aitchison's Adjustment for Cobalt
Background Values (positive detects only)
Concentration ln(conc)
Sample No. Sample Date Location (µg/l)
1 Sep-94 MW-9 52 3.951
2 Jan-95 MW-9 35 3.5553Feb-95 MW-9 16 2.773
4 Mar-95 MW-9 28 3.332
5 Aug-95 MW-9 ND -
6 Jan-96 MW-9 17 2.833
7 Feb-96 MW-9 37 3.611
8 May-96 MW-9 11 2.398
9 Oct-96 MW-9 16 2.773
10 May-97 MW-9 33 3.497
11 Nov-97 MW-9 29 3.367
12 May-98 MW-9 28 3.332
13 Nov-98 MW-9 10 2.303
14 May-99 MW-9 20 2.996
15 Oct-99 MW-9 120 4.787
16 May-00 MW-9 ND -
17 Nov-00 MW-9 ND -
18 May-01 MW-9 ND -
19 Nov-01 MW-9 ND -
20 Nov-02 MW-9 ND -
21 May-03 MW-9 19 2.944
22 Nov-03 MW-9 26 3.258
23 May-04 MW-9 ND -
24 Nov-04 MW-9 10 2.303
25 May-05 MW-9 12 2.485
26 May-99 MW-17 26 3.258
27 Oct-99 MW-17 37 3.611
28 May-00 MW-17 ND -
29 Nov-00 MW-17 20 2.996
30 May-01 MW-17 ND -
31 Nov-01 MW-17 ND -
32 Nov-02 MW-17 ND -
33 May-03 MW-17 ND -
34 Nov-03 MW-17 10 2.303
35 May-04 MW-17 ND -
36 Nov-04 MW-17 ND -37 May-05 MW-17 ND -
38 Nov-05 MW-17 ND -
39 May-06 MW-17 ND -
40 Nov-06 MW-17 ND -
41 May-07 MW-17 4.1 1.411
42 Nov-07 MW-17 7.3 1.988
43 May-08 MW-17 5.4 1.686
44 Nov-08 MW-17 9.2 2.219
45 Nov-09 MW-17 14.9 2.701
46 Jun-10 MW-17 19.1 2.950
47 Dec-10 MW-17 9.8 2.282
48 Dec-10 MW-20 22.1 3.096
49 Jan-11 MW-20 ND -
50 Jun-11 MW-17 7.8 2.054
51 Jun-11 MW-20 2.6 0.956
52 Dec-11 MW-20 ND -
53 May-12 MW-20 ND -
54 Dec-12 MW-20 ND -
55 Jun-13 MW-20 ND -
56 Oct-13 MW-20 ND -
57 May-14 MW-20 ND -
58 Oct-14 MW-21 ND -
59 May-15 MW-21 ND -
60 Dec-15 MW-21 ND -
61 May-16 MW-21 4 1.386
62 Dec-16 MW-21 ND -
Mean of detected values = 2.77
Standard Deviation of detected values = 0.80
The adjusted mean can be found using
M(a) = (1-d/n) x M
where:d = number non- detected values = 29
n = total number samples = 62
M = mean detected values = 2.77
M(a) = 1.47
The adjusted standard deviation squared may be found using
STD(a) = [(n-(d+1))/(n-1)] S + d/n((n-d)/(n-1))MM
where:n = total number samples = 62
d = number non-detected values = 29
S = std deviation of detected values squared = 0.64
MM = mean of detected values squared = 7.67
STD(a) = 2.28
and the adjusted standard deviation is then
S(a) = SQRT(STD(a)) = 1.51
Joyce Project:Burke County - Johns River Landfill
Project No: 277.1701.12.03
Date: 13-Dec-16
Parametric Tolerance Interval for Aitchison's adjusted data
Analyte:Cobalt
Background Data
Sample No. Sample Date Location Concentration ln(Concentration)
1 Sep-94 MW-9 52 3.951
2 Jan-95 MW-9 35 3.555
3 Feb-95 MW-9 16 2.773
4 Mar-95 MW-9 28 3.332
5 Aug-95 MW-9 ND -
6 Jan-96 MW-9 17 2.833
7 Feb-96 MW-9 37 3.611
8 May-96 MW-9 11 2.398
9 Oct-96 MW-9 16 2.773
10 May-97 MW-9 33 3.497
11 Nov-97 MW-9 29 3.367
12 May-98 MW-9 28 3.332
13 Nov-98 MW-9 10 2.303
14 May-99 MW-9 20 2.996
15 Oct-99 MW-9 120 4.787
16 May-00 MW-9 ND -
17 Nov-00 MW-9 ND -
18 May-01 MW-9 ND -
19 Nov-01 MW-9 ND -
20 Nov-02 MW-9 ND -
21 May-03 MW-9 19 2.944
22 Nov-03 MW-9 26 3.258
23 May-04 MW-9 ND -
24 Nov-04 MW-9 10 2.303
25 May-05 MW-9 12 2.485
26 May-99 MW-17 26 3.258
27 Oct-99 MW-17 37 3.611
28 May-00 MW-17 ND -
29 Nov-00 MW-17 20 2.996
30 May-01 MW-17 ND -
31 Nov-01 MW-17 ND -
32 Nov-02 MW-17 ND -
33 May-03 MW-17 ND -
34 Nov-03 MW-17 10 2.303
35 May-04 MW-17 ND -
36 Nov-04 MW-17 ND -
37 May-05 MW-17 ND -
38 Nov-05 MW-17 ND -
39 May-06 MW-17 ND -
40 Nov-06 MW-17 ND -
41 May-07 MW-17 4 1.411
42 Nov-07 MW-17 7 1.988
43 May-08 MW-17 5 1.686
44 Nov-08 MW-17 9 2.219
45 Nov-09 MW-17 15 2.701
46 Jun-10 MW-17 19 2.950
47 Dec-10 MW-17 10 2.282
48 Dec-10 MW-20 22 3.096
49 Jan-11 MW-20 ND -
50 Jun-11 MW-17 8 2.054
51 Jun-11 MW-20 3 0.956
52 Dec-11 MW-20 ND -
53 May-12 MW-20 ND -
54 Dec-12 MW-20 ND -
55 Jun-13 MW-20 ND -
56 Oct-13 MW-20 ND -
57 May-14 MW-20 ND -
58 Oct-14 MW-21 ND -
59 May-15 MW-21 ND -
60 Dec-15 MW-21 ND -
61 May-16 MW-21 4 1.386
62 Dec-16 MW-21 ND -
Note: All sample concentrations are micrograms per liter (µg/L)
The background mean and standard deviation were modified using Aitchison's Adjustment.
The adjusted mean and standard deviation are as follows:
The ln(adjusted mean) and ln(standard deviation) are
ln(adjusted mean) = 1.47
ln(adjusted standard deviation) = 1.51
Using the background data, the upper Tolerance Limit can be determined using
Upper Tolerance Limit = (Mean Concentration) + K x (Standard Deviation Samples)
where: K = factor for constructing one sided normal tolerance limit
taken from table 4-2, page 87, Statistical Methods for Groundwater
Monitoring, Gibbons, 1994
n = number of background samples
For: K = 2.010
n = 62
UTL = 90.7 µg/L
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Analyte:Cobalt (Intrawell MW-10)
Sample No. Sample Date Location Concentration RL
1 18-Jan-95 MW-10 35.0 10 26.0 340
2 6-Feb-95 MW-10 43.0 10 29.0 280
3 Mar-95 MW-10 57.0 10 35.0 170
4 Aug-95 MW-10 58.0 10 37.0 140
5 Jan-96 MW-10 37.0 10 40.0 140
6 Feb-96 MW-10 41.0 10 41.0 139
7 May-96 MW-10 26.0 10 43.0 131
8 Oct-96 MW-10 52.0 10 46.6 130
9 May-97 MW-10 120 6 48.0 126
10 Nov-97 MW-10 99.0 5 52.0 120
11 May-98 MW-10 120 1 53.0 120
12 Nov-98 MW-10 140 1 54.0 99.0
13 11-May-99 MW-10 48.0 5 57.0 96
14 18-Oct-99 MW-10 85.0 10 58.0 92.8
15 3-May-00 MW-10 54.0 10 60.0 90.2
16 7-Nov-00 MW-10 40.0 10 66.0 90.0
17 31-May-01 MW-10 53.0 10 67.2 87.2
18 7-Nov-01 MW-10 29.0 10.0 68.0 85.0
19 22-May-02 MW-10 68.0 10 71.9 80.3
20 14-Nov-02 MW-10 90.0 10 71.9 76.4
21 14-May-03 MW-10 280 10 72.7 72.7
22 20-Nov-03 MW-10 340 10 76.4 71.9
23 6-May-04 MW-10 140 10 80.3 71.9
24 10-Nov-04 MW-10 170 10 85.0 68.0
25 5-May-05 MW-10 130 10 87.2 67.2
26 3-Nov-05 MW-10 66.0 10 90.0 66.0
27 25-May-06 MW-10 80.3 10 90.2 60.0
28 2-Nov-06 MW-10 131 10 92.8 58.0
29 30-May-07 MW-10 87.2 10 96 57.0
30 29-Nov-07 MW-10 67.2 10 99.0 54.0
31 29-May-08 MW-10 71.9 10 120 53.0
32 6-Nov-08 MW-10 71.9 10.0 120 52.0
33 3-Jun-09 MW-10 139 10.0 126 48.0
34 27-Aug-09 MW-10 60.0 10.0 130 46.6
35 18-Nov-09 MW-10 126 10.0 131 43.0
36 16-Jun-10 MW-10 96 10.0 139 41.0
37 1-Dec-10 MW-10 72.7 10.0 140 40.0
38 1-Jun-11 MW-10 76.4 10.0 140 37.0
39 20-Dec-11 MW-10 92.8 10.0 170 35.0
40 30-May-12 MW-10 90.2 10.0 280 29.0
41 5-Dec-12 MW-10 46.6 10.0 340 26.0
Number of Data: 41
Number of Truncated Data: 0
Percentage of Truncated Data: 0%
Upper Tolerance Limit: 253 µg/L
Notes: All concentrations in micrograms per liter (µg/L).
Sorted
Concentration
JEI Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Date: December 2016
Shapiro Wilk Test Statistic (W) for normality of total Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 26.0 340 314.00 0.3940 123.7160
2 29.0 280 251.00 0.2719 68.2469
3 35.0 170 135.00 0.2357 31.8195
4 37.0 140 103.00 0.2091 21.5373
5 40.0 140 100.00 0.1876 18.7600
6 41.0 139 98.00 0.1693 16.5914
7 43.0 131 88.00 0.1531 13.4728
8 46.6 130 83.40 0.1384 11.5426
9 48.0 126 78.00 0.1249 9.7422
10 52.0 120 68.00 0.1123 7.6364
11 53.0 120 67.00 0.1004 6.7268
12 54.0 99 45.00 0.0891 4.0095
13 57.0 96 39.10 0.0782 3.0576
14 58.0 93 34.80 0.0677 2.3560
15 60.0 90 30.20 0.0575 1.7365
16 66.0 90 24.00 0.0476 1.1424
17 67.2 87 20.00 0.0379 0.7580
18 68.0 85 17.00 0.0283 0.4811
19 71.9 80 8.40 0.0188 0.1579
20 71.9 76 4.50 0.0094 0.0423
21 72.7 73 0.00 0.0000 0.0000
22 76.4 72 -4.50
23 80.3 72 -8.40
24 85.0 68 -17.00
25 87.2 67 -20.00
26 90.0 66 -24.00
27 90.2 60 -30.20
28 92.8 58 -34.80
29 96.1 57 -39.10
30 99.0 54 -45.00
31 120.0 53 -67.00
32 120.0 52 -68.00
33 126.0 48 -78.00
34 130.0 47 -83.40
35 131.0 43 -88.00
36 139.0 41 -98.00
37 140.0 40 -100.00
38 140.0 37 -103.00
39 170.0 35 -135.00
40 280.0 29 -251.00
41 340.0 26 -314.00
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 343.53
SD = standard deviation of the data group = 61.90
n = number of samples = 41
W = 0.770
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.941
and the calculated W = 0.770
Therefore the data is Non-Normal
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Shapiro Wilk Test Statistic (W) for log normality of Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 3.26 5.83 2.5708 0.3940 1.0129
2 3.37 5.63 2.2675 0.2719 0.6165
3 3.56 5.14 1.5805 0.2357 0.3725
4 3.61 4.94 1.3307 0.2091 0.2783
5 3.69 4.94 1.2528 0.1876 0.2350
6 3.71 4.93 1.2209 0.1693 0.2067
7 3.76 4.88 1.1140 0.1531 0.1706
8 3.84 4.87 1.0259 0.1384 0.1420
9 3.87 4.84 0.9651 0.1249 0.1205
10 3.95 4.79 0.8362 0.1123 0.0939
11 3.97 4.79 0.8172 0.1004 0.0820
12 3.99 4.60 0.6061 0.0891 0.0540
13 4.04 4.57 0.5223 0.0782 0.0408
14 4.06 4.53 0.4700 0.0677 0.0318
15 4.09 4.50 0.4077 0.0575 0.0234
16 4.19 4.50 0.3102 0.0476 0.0148
17 4.21 4.47 0.2605 0.0379 0.0099
18 4.22 4.44 0.2231 0.0283 0.0063
19 4.28 4.39 0.1105 0.0188 0.0021
20 4.28 4.34 0.0607 0.0094 0.0006
21 4.29 4.29 0.0000 0.0000 0.0000
22 4.34 4.28 -0.0607
23 4.39 4.28 -0.1105
24 4.44 4.22 -0.2231
25 4.47 4.21 -0.2605
26 4.50 4.19 -0.3102
27 4.50 4.09 -0.4077
28 4.53 4.06 -0.4700
29 4.57 4.04 -0.5223
30 4.60 3.99 -0.6061
31 4.79 3.97 -0.8172
32 4.79 3.95 -0.8362
33 4.84 3.87 -0.9651
34 4.87 3.84 -1.0259
35 4.88 3.76 -1.1140
36 4.93 3.71 -1.2209
37 4.94 3.69 -1.2528
38 4.94 3.61 -1.3307
39 5.14 3.56 -1.5805
40 5.63 3.37 -2.2675
41 5.83 3.26 -2.5708
The test statistic W can be found using:
W = SQR((B/SD x SQRT(n-1))
where:B = summation of (X(n-i+1)-X(i))A(n-i+1) = 3.5147
SD = standard deviation of the data group = 0.5620
n = number of samples =41
W = 0.9777
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.941
and the calculated W = 0.978
Therefore the data set is Log-Normal.
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Probability Plots to determine the distribution of Cobalt (Intrawell MW-10)
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
LN[X(i)] = Natural Log Value of sample concentrations arranged from
smallest to largest
[i/(n+1)] = Cumulative probability
n = number of samples = 41
X(i) LN[X(i)] i Rank [Rank/(n+1)] Quantiles
26 3.26 1 1 0.024 -1.98
29 3.37 2 2 0.048 -1.67
35 3.56 3 3 0.071 -1.47
37 3.61 4 4 0.095 -1.31
40 3.69 5 5 0.119 -1.18
41 3.71 6 6 0.143 -1.07
43 3.76 7 7 0.167 -0.97
46.6 3.84 8 8 0.190 -0.88
48 3.87 9 9 0.214 -0.79
52 3.95 10 10 0.238 -0.71
53 3.97 11 11 0.262 -0.64
54 3.99 12 12 0.286 -0.57
57 4.04 13 13 0.310 -0.50
58 4.06 14 14 0.333 -0.43
60 4.09 15 15 0.357 -0.37
66 4.19 16 16 0.381 -0.30
67.2 4.21 17 17 0.405 -0.24
68 4.22 18 18 0.429 -0.18
71.9 4.28 19 19 0.452 -0.12
71.9 4.28 20 20 0.476 -0.06
72.7 4.29 21 21 0.500 0.00
76.4 4.34 22 22 0.524 0.06
80.3 4.39 23 23 0.548 0.12
85 4.44 24 24 0.571 0.18
87.2 4.47 25 25 0.595 0.24
90 4.50 26 26 0.619 0.30
90.2 4.50 27 27 0.643 0.37
92.8 4.53 28 28 0.667 0.43
96.1 4.57 29 29 0.690 0.50
99 4.60 30 30 0.714 0.57
120 4.79 31 31 0.738 0.64
120 4.79 32 32 0.762 0.71
126 4.84 33 33 0.786 0.79
130 4.87 34 34 0.810 0.88
131 4.88 35 35 0.833 0.97
139 4.93 36 36 0.857 1.07
140 4.94 37 37 0.881 1.18
140 4.94 38 38 0.905 1.31
170 5.14 39 39 0.929 1.47
280 5.63 40 40 0.952 1.67
340 5.83 41 41 0.976 1.98
Plot analysis indicates that the data more closely follow a normal distribution in the
log-transformed format.
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Probability Plots to determine the distribution of Cobalt (Intrawell MW-10)
R² = 0.7446
-2.50
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
0 100 200 300 400Quantile
Concentration (micrograms per liter)
Normal Probability Plot
Cobalt Concentrations
R² = 0.9766
-2.00
-1.50
-1.00
-0.50
0.00
0.50
1.00
1.50
2.00
2.50
3.00
0.00 2.00 4.00 6.00 8.00Quantile
Ln [Concentration (micrograms per liter)]
Log Normal Probability Plot
Cobalt Concentrations
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Determination of reported background value as an outlier
Analyte:Cobalt (Intrawell MW-10)
Background Data
Sample No. Sample Date Location ln(Concentration)
1 Jan-95 MW-10 3.555
2 Feb-95 MW-10 3.761
3 Mar-95 MW-10 4.043
4 Aug-95 MW-10 4.060
5 Jan-96 MW-10 3.611
6 Feb-96 MW-10 3.714
7 May-96 MW-10 3.258
8 Oct-96 MW-10 3.951
9 May-97 MW-10 4.787
10 Nov-97 MW-10 4.595
11 May-98 MW-10 4.787
12 Nov-98 MW-10 4.942
13 May-99 MW-10 3.871
14 Oct-99 MW-10 4.443
15 May-00 MW-10 3.989
16 Nov-00 MW-10 3.689
17 May-01 MW-10 3.970
18 Nov-01 MW-10 3.367
19 May-02 MW-10 4.220
20 Nov-02 MW-10 4.500
21 May-03 MW-10 5.635
22 Nov-03 MW-10 5.829
23 May-04 MW-10 4.942
24 Nov-04 MW-10 5.136
25 May-05 MW-10 4.868
26 Nov-05 MW-10 4.190
27 May-06 MW-10 4.386
28 Nov-06 MW-10 4.875
29 May-07 MW-10 4.468
30 Nov-07 MW-10 4.208
31 May-08 MW-10 4.275
32 Nov-08 MW-10 4.275
33 Jun-09 MW-10 4.934
34 Aug-09 MW-10 4.094
35 Nov-09 MW-10 4.836
36 Jun-10 MW-10 4.565
37 Dec-10 MW-10 4.286
38 Jun-11 MW-10 4.336
39 Dec-11 MW-10 4.530
40 May-12 MW-10 4.502
41 Dec-12 MW-10 3.842
mean = 4.345
STD = 0.562
Note: All concentrations are micrograms per liter (µg/L)
Using the data listed above, form the statisitc Tn:
Tn = (Xn - mean) / STD
where:Xn = largest observed sample value
mean = mean of the background values
STD = standard deviation of the background values
For Xn = 5.829
mean = 4.345
STD = 0.562
Tn = 2.641
From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at
RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is
Number of samples =41
Tc = 2.877
Since Tc>Tn, the sample result is not considered to be an outlier
JOYCE Project:Burke County - Johns River Landfill
Project No: 277.1701.12
Task No: 03
Date: December 2016
Parametric Tolerance Interval for log normally distributed data
Analyte:Cobalt (Intrawell MW-10)
Background Data: Note use of log(concentration)
Background Data Quantitation
Concentration Limit Natural Log
Sample No. Sample Date Location (µg/L) Notes (µg/L) Concentration
1 18-Jan-95 MW-10 35 10 3.555
2 06-Feb-95 MW-10 43 10 3.761
3 01-Mar-95 MW-10 57 10 4.043
4 01-Aug-95 MW-10 58 10 4.060
5 01-Jan-96 MW-10 37 10 3.611
6 01-Feb-96 MW-10 41 10 3.714
7 01-May-96 MW-10 26 10 3.258
8 01-Oct-96 MW-10 52 10 3.951
9 01-May-97 MW-10 120 6 4.787
10 01-Nov-97 MW-10 99 5 4.595
11 01-May-98 MW-10 120 1 4.787
12 01-Nov-98 MW-10 140 1 4.942
13 11-May-99 MW-10 48 5 3.871
14 18-Oct-99 MW-10 85 10 4.443
15 03-May-00 MW-10 54 10 3.989
16 07-Nov-00 MW-10 40 10 3.689
17 31-May-01 MW-10 53 10 3.970
18 07-Nov-01 MW-10 29 10 3.367
19 22-May-02 MW-10 68 10 4.220
20 14-Nov-02 MW-10 90 10 4.500
21 14-May-03 MW-10 280 10 5.635
22 20-Nov-03 MW-10 340 10 5.829
23 06-May-04 MW-10 140 10 4.942
24 10-Nov-04 MW-10 170 10 5.136
25 05-May-05 MW-10 130 10 4.868
26 03-Nov-05 MW-10 66 10 4.190
27 25-May-06 MW-10 80 10 4.386
28 02-Nov-06 MW-10 131 10 4.875
29 30-May-07 MW-10 87 10 4.468
30 29-Nov-07 MW-10 67 10 4.208
31 29-May-08 MW-10 72 10 4.275
32 06-Nov-08 MW-10 72 10 4.275
33 03-Jun-09 MW-10 139 10 4.934
34 27-Aug-09 MW-10 60 10 4.094
35 18-Nov-09 MW-10 126 10 4.836
36 16-Jun-10 MW-10 96 10 4.565
37 01-Dec-10 MW-10 72.7 10 4.286
38 01-Jun-11 MW-10 76.4 10 4.336
39 20-Dec-11 MW-10 92.8 10 4.530
40 30-May-12 MW-10 90.2 10 4.502
41 05-Dec-12 MW-10 46.6 10 3.842
Note: All sample concentrations are micrograms per liter
Using the background data, the upper Tolerance Limit can be determined using:
Upper Tolerance Limit = antilog((Mean Concentration)+K x (Standard Deviation Samples))
where: Mean Conc = mean concentration background samples
K = factor for constructing one sided normal tolerance limit
taken from table 4-2, page 87, Statistical Methods for Groundwate
Monitoring, Gibbons, 1994
STDS = Standard Deviation Samples
n = number of background samples
For: n = 41
K = 2.118
Mean Conc = 4.345
STDS = 0.562
UTL = 253 µg/L

Appendix D

Historical Detected Inorganic Groundwater Constituents

APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Inorganic Compounds
Antimony 30-May-07 --- 6 --- ND --- --- ND ND 1.09 J ND ND ND ND
GWPS = 1.4 µg/L (10/23/07) 29-Nov-07 --- 6 --- ND --- --- ND ND 1.94 J ND ND ND ND
29-May-08 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.6 6.0 --- ND --- --- ND ND 2.7 J ND 5.9 J ND ND
3-Jun-09 2.6 6.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.6 6.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 2.6 6.0 --- ND --- --- ND ND 2.8 J ND ND ND ND
GWPS = 1 µg/L (8/1/10) 1-Dec-10 2.6 6.0 --- ND ND --- ND 3.5 J 2.9 J ND ND ND ND
1-Jun-11 2.6 6.0 --- ND ND --- ND ND ND ND ND 2.9 J ND
20-Dec-11 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 6.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 6.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 3.8 6.0 --- --- --- ND ND ND 6.3 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 3.8 6.0 --- --- --- --- --- ---6.2 --- --- --- ---
Resample> 4-Feb-16 3.8 6.0 --- --- --- --- --- --- ND --- --- --- ND
3-May-16 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 3.8 6.0 --- --- --- ND ND ND ND ND ND ND ND
Arsenic 30-May-07 --- 10 --- ND --- --- ND 2.2 B ND 3.6 B ND 2.1 B 2.6 J
NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 10 --- 2.5 J --- --- ND ND ND ND 2.1 J ND ND
29-May-08 2.7 10.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 2.7 10.0 --- ND --- --- ND 3.1 B ND 3.2 B 3 B ND 4.1 J
3-Jun-09 2.7 10.0 --- ND --- --- ND ND ND ND ND 3.2 J ND
18-Nov-09 2.7 10.0 --- ND --- --- 3.0 J ND ND ND ND ND ND
NC 2L = 10 µg/L (01/01/10) 16-Jun-10 2.7 10.0 --- ND --- --- ND 4.6 J ND ND 3.0 J ND ND
1-Dec-10 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 2.7 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND 3.7 J ND ND ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND 3.2 J ND ND ND ND 3.5 J ND
Barium 15-Sep-94 --- 100 1320 NI NI NI 194 5580 ND 584 NI NI ND
1-Oct-94 --- 100 --- NI NI NI --- 1030 --- --- NI NI ND
18-Jan-95 --- 100 981 NI NI NI 122 1490 ND 355 NI NI ND
6-Feb-95 --- 100 435 NI NI NI 124 350 ND 311 NI NI ND
1-Mar-95 --- 100 556 NI NI NI 260 732 196 528 NI NI ND
1-Aug-95 --- 100 199 NI --- --- 250 688 ND 408 NI NI ND
1-Jan-96 --- 100 455 NI --- --- 228 734 196 ND NI NI ND
1-Feb-96 --- 100 306 NI --- --- 211 321 288 ND NI NI ND
1-May-96 --- 100 170 NI --- --- ND 453 319 ND NI NI ND
1-Oct-96 --- 100 302 NI --- --- 234 447 102 ND NI NI ND
1-May-97 --- 100 330 NI --- --- 170 360 400 ND NI NI ND
1-Nov-97 --- 100 800 NI --- --- 200 600 800 100 NI NI ND
1-May-98 --- 100 400 NI --- --- 200 400 1200 200 NI NI ND
1-Nov-98 --- 100 140 NI --- --- 270 310 880 ND NI NI ND
11-May-99 --- 5 240 200 --- --- 70 130 200 60 220 16 ND
18-Oct-99 --- 500 1900 ND --- --- ND ND 1400 ND ND ND ND
3-May-00 --- 500 ND ND --- --- ND ND ND ND 730 ND ND
7-Nov-00 --- 500 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 500 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 500 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 500 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 500 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 500 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 500 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 500 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 100 --- 52.0 J --- --- 48.1 J 132 88.4 J 66.9 J 50.9 J 8.0 J 0.20 J
NC 2L = 2,000 µg/L (10/23/07) 29-Nov-07 --- 100 --- 214 --- --- 54.8 J 232 97.0 J 75.3 J 57.9 J 8.6 J 0.50 J
29-May-08 0.20 100 --- 67.9 J --- --- 41.5 J 148 71.0 J 77.0 J 43.7 J 7.9 J ND
6-Nov-08 0.20 100 --- 82.3 J --- --- 45.5 B 118 81.2 J 90.6 J 66.7 J 7.1 B 9.6 J
3-Jun-09 0.20 100 --- 34.2 B --- --- 26.9 B 119 67.6 B 66.9 B 49.5 B 9.8 B 15.9 J
18-Nov-09 0.20 100 --- 78.9 B --- --- 36.3 B 116 88.6 B 81.0 B 46.6 B 7.8 B 20.1 J
NC 2L = 700 µg/L (01/01/10) 16-Jun-10 0.20 100 --- 58.1 J --- --- 50.5 J 296 103 73.4 J 47.0 J 8.6 J 0.77 J
1-Dec-10 0.20 100 --- 60.1 J 376 --- 59.6 J 134 94.1 J 78.7 J 37.5 J 16.3 J ND
1-Jun-11 0.20 100 --- 55.6 J 164 --- 43.3 J 154 74.3 J 74.4 J 44.7 J 12.3 J ND
20-Dec-11 5.0 100 --- --- 119 --- 50.9 J 138 76.6 J 78.3 J 46.7 J 10.5 J ND
30-May-12 5.0 100 --- --- 96.7 J --- 40.6 J 137 77.7 J 74.5 J 67.8 J 9.1 J ND
5-Dec-12 5.0 100 --- --- 63.0 J --- 53.3 J 148 89.8 J 81.4 J 43.6 J 10.5 J ND
12-Jun-13 5.0 100 --- --- 59.6 B --- 28.3 B 167 82.3 J 83.6 J 48.1 B 13.2 B 13.6 J
28-Oct-13 5.0 100 --- --- 47.9 J --- 47.4 J 194 93.8 J 70.7 J 49.4 J 9.6 J ND
6-May-14 5.0 100 --- --- 73.6 J --- 37.3 J 129 89.9 J 73.9 J 45.5 J 8.2 J ND
23-Oct-14 5.0 100 --- --- * 20.3 J 53.4 J 127 74.6 J 76.0 J 46.3 J 13.3 J ND
20-May-15 2.5 100 --- --- --- 17.9 47.5 J 145 75.5 J 76.9 J 44.6 J 8.4 J ND
8-Dec-15 2.5 100 --- --- --- 17.6 J 45.6 J 140 132 82.6 J 50.6 J 8.0 J ND
3-May-16 2.5 100 --- --- --- 26.6 J 43.6 J 156 82.4 J 87.3 J 51.2 J 9.5 J ND
13-Dec-16 2.5 100 --- --- --- 13.4 J 66.0 J 128 83.2 J 80.9 J 48.1 J 10.0 J ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 1 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Beryllium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 1.0 NI --- --- ND 3.0 ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 3.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 1 ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND 4.3 ND ND
18-Oct-99 --- 2 8.0 3.0 J --- --- 2.0 J 2.0 J 13.0 ND ND ND ND
3-May-00 --- 2 ND ND --- --- ND ND ND ND 8.0 ND ND
7-Nov-00 --- 2 ND 2.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 2 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 2 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 2 ND ND --- --- ND ND ND ND ND ND 2.1
14-May-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 2 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 2 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 2 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 2 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 2 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
GWPS = 4 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 1.0 --- ND --- --- 0.18 J ND ND ND ND ND ND
6-Nov-08 0.10 1.0 --- 0.49 B --- --- 0.65 B 0.32 B 0.42 B 0.61 B 0.53 B 0.27 B 0.29 J
3-Jun-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J 0.23 J 2.2 ND
18-Nov-09 0.10 1.0 --- ND --- --- ND ND ND 0.25 J ND ND ND
16-Jun-10 0.10 1.0 --- ND --- --- 0.24 J 0.94 J ND 0.11 J ND ND ND
1-Dec-10 0.10 1.0 --- ND 1.7 --- 0.14 J ND ND ND ND ND ND
1-Jun-11 0.10 1.0 --- ND 0.44 J --- J ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
Cadmium 1-May-97 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND 1.0 ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND 2.0 ND NI NI ND
11-May-99 --- 1 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 1 24.0 6.0 --- --- 6.0 3.0 J 30.0 2.0 J 2.0 J ND ND
3-May-00 --- 1 ND ND --- --- ND 1.0 J 1.0 J ND 5.0 ND ND
7-Nov-00 --- 1 2.0 5.0 --- --- ND ND 1.0 ND 1.0 ND ND
31-May-01 --- 1 ND ND --- --- ND ND 1.0 J ND 1.0 J ND ND
7-Nov-01 --- 1 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 1 ND ND --- --- ND ND ND 2.0 B ND ND 1.3
14-Nov-02 --- 1 ND ND --- --- ND ND 1.2 ND 3.7 ND ND
14-May-03 --- 1 ND ND --- --- 1.1 ND ND ND 2.5 ND ND
20-Nov-03 --- 1 2.0 1.3 --- --- ND ND 1.2 ND ND ND ND
6-May-04 --- 1 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 1 ND ND --- --- 1.5 ND ND ND 2.2 ND ND
5-May-05 --- 1 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 1 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 1 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 1.75 µg/L (10/23/07)29-Nov-07 --- 1 --- ND --- --- ND ND 0.60 J ND ND ND ND
29-May-08 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.50 1.0 --- ND --- --- ND ND ND ND 0.94 J ND ND
3-Jun-09 0.50 1.0 --- ND --- --- ND ND ND ND ND 1.9 ND
18-Nov-09 0.50 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 2 µg/L (01/01/10)16-Jun-10 0.50 1.0 --- ND --- --- ND 6.0 ND ND ND ND ND
Resample> 5-Aug-10 0.50 1.0 --- --- --- --- --- 1.2 --- --- ------ ND
1-Dec-10 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.50 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.0 1.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 1.0 1.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 0.5 1.0 --- --- --- ND ND 0.85 J ND ND ND ND ND
8-Dec-15 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.5 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 2 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Chromium 1-Mar-95 --- 5 ND NI NI NI ND ND 11.0 ND NI NI ND
1-Aug-95 --- 5 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 5 ND NI --- --- ND ND 7.0 ND NI NI ND
1-Feb-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-96 --- 5 ND NI --- --- ND ND 16.0 ND NI NI ND
1-Oct-96 --- 5 ND NI --- --- ND ND 6.0 ND NI NI ND
1-May-97 --- 1 4.0 NI --- --- 2.0 3.0 18.0 3.0 NI NI ND
1-Nov-97 --- 1 6.0 NI --- --- 1.0 1.0 108 2.0 NI NI ND
1-May-98 --- 1 8.0 NI --- --- 4.0 6.0 66.0 6.0 NI NI ND
1-Nov-98 --- 1 3.0 NI --- --- 1.0 3.0 180 3.0 NI NI ND
11-May-99 --- 5 26.0 24.0 --- --- 8.4 6.5 44.0 11.0 46.0 ND ND
18-Oct-99 --- 10 290 58.0 --- --- 44.0 36.0 410 21.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND 12.0 ND 92.0 ND ND
7-Nov-00 --- 10 11.0 30.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND 10.0 ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 12.0 ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 50 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.40 10.0 --- ND --- --- ND 1.9 B 1 B 1.4 B ND ND 0.85 J
6-Nov-08 0.40 10.0 --- 0.59 J --- --- 1 J 0.83 J 2.8 J 3.4 J 2.5 J ND ND
3-Jun-09 0.40 10.0 --- ND --- --- ND 2.1 J ND 1.1 J 0.66 J 2.1 J ND
18-Nov-09 0.40 10.0 --- ND --- --- ND ND 2.2 J 2.2 J ND ND ND
NC 2L = 10 µg/L (01/01/10)16-Jun-10 0.40 10.0 --- 0.43 B --- --- 1.0 B 13.9 4.7 J 1.0 B ND ND 0.74 J
Resample> 5-Aug-10 0.40 10.0 --- --- --- --- --- 0.88 B --- --- ------ 0.51 J
1-Dec-10 0.40 10.0 --- 0.60 B 39.6 --- 1.8 B 1.3 B 5.5 J 1.2 B ND ND 0.51 J
Resample> 13-Jan-11 0.40 10.0 --- --- ND --- --- --- --- --- ------ ND
1-Jun-11 0.40 10.0 --- ND 11.2 --- ND 1.2 B 0.72 B ND ND ND 0.73 J
Resample> 7-Jul-11 0.40 10.0 --- --- 7.8 J --- --- --- --- --- ------ ND
20-Dec-11 5.0 10.0 --- --- 8.2 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 5.3 J --- ND ND ND ND 5.4 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- 6.1 J --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.9 J ND ND ND 4.7 J ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND 13.8 ND ND ND ND
Lab Re-run Analyses> 8-Dec-15 2.5 10.0 --- --- --- --- --- ---14.7 --- ------ ---
Resample> 4-Feb-16 2.5 10.0 --- --- --- --- --- --- ND --- ------ ND
3-May-16 2.5 10.0 --- --- --- 4.2 J ND 3.1 J 4.1 J 4.5 J ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND 3.7 J 4.4 J ND ND ND ND
Cobalt 18-Jan-95 --- 10 35.0 NI NI NI 35.0 14.0 52.0 14.0 NI NI ND
6-Feb-95 --- 10 16.0 NI NI NI 43.0 ND 66.0 ND NI NI ND
Mar-95 --- 10 28.0 NI NI NI 57.0 ND 78.0 20.0 NI NI ND
Aug-95 --- 10 ND NI --- --- 58.0 ND 30.0 32.0 NI NI ND
Jan-96 --- 10 17.0 NI --- --- 37.0 ND 23.0 ND NI NI ND
Feb-96 --- 10 37.0 NI --- --- 41.0 ND 24.0 ND NI NI ND
May-96 --- 10 11.0 NI --- --- 26.0 ND 24.0 ND NI NI ND
Oct-96 --- 10 16.0 NI --- --- 52.0 ND 16.0 ND NI NI ND
May-97 --- 6 33.0 NI --- --- 120 5.0 J 32.0 6.0 NI NI ND
Nov-97 --- 5 29.0 NI --- --- 99.0 11.0 48.0 14.0 NI NI ND
May-98 --- 1 28.0 NI --- --- 120 8.0 76.0 32.0 NI NI ND
Nov-98 --- 1 10.0 NI --- --- 140 6.0 47.0 1.0 NI NI ND
11-May-99 --- 5 20.0 26.0 --- --- 48.0 13.0 34.0 17.0 59.0 ND ND
18-Oct-99 --- 10 120 37.0 --- --- 85.0 20.0 220 16.0 40.0 ND ND
3-May-00 --- 10 ND ND --- --- 54.0 ND 31.0 13.0 89.0 ND ND
7-Nov-00 --- 10 ND 20.0 --- --- 40.0 ND 18.0 ND 32.0 ND ND
31-May-01 --- 10 ND ND --- --- 53.0 ND 30.0 11.0 32.0 ND ND
7-Nov-01 --- 10 ND ND --- --- 29.0 ND 23.0 ND 26.0 ND ND
22-May-02 --- 10 14.0 B 14.0 B --- --- 68.0 16.0 B 51.0 B 17.0 B 39.0 B 12.0 B 11.0
14-Nov-02 --- 10 ND ND --- --- 90.0 ND 41.0 11.0 34.0 ND ND
14-May-03 --- 10 19.0 ND --- --- 280 ND 46.0 53.0 24.0 ND ND
20-Nov-03 --- 10 26.0 10.0 J --- --- 340 18.0 56.0 58.0 30.0 ND ND
6-May-04 --- 10 ND ND --- --- 140 ND 46.0 47.0 29.0 ND ND
10-Nov-04 --- 10 10.0 ND --- --- 170 21.0 50.0 46.0 29.0 ND ND
5-May-05 --- 10 12.0 ND --- --- 130 16.0 46.0 60.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 66.0 15.0 42.0 45.0 25.0 ND ND
25-May-06 --- 10 --- ND --- --- 80.3 21.7 42.7 43.2 24.9 ND ND
2-Nov-06 --- 10 --- ND --- --- 131 30.8 37.0 28.3 26.6 ND ND
30-May-07 --- 10 --- 4.1 J --- --- 87.2 20.7 44.0 36.9 26.6 ND ND
GWPS = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.3 J --- ---67.2 55.5 47.9 J 23.4 30.7 ND ND
29-May-08 0.60 10.0 --- 5.4 J --- ---71.9 54.6 34.8 35.3 ND ND ND
6-Nov-08 0.60 10.0 --- 9.2 J --- ---71.9 60.0 47.9 44.1 24.3 2.2 B 1.6 J
3-Jun-09 0.60 10.0 --- 22.8 B --- ---139 78.6 53.5 49.3 54.7 7.6 B 7.6 J
Resample>27-Aug-09 0.60 10.0 --- --- --- --- 60.0 --- --- --- ------ ---
18-Nov-09 0.60 10.0 --- 14.9 --- ---126 84.5 50.3 44.1 31.8 ND ND
16-Jun-10 0.60 10.0 --- 19.1 --- ---96.1 103 70.9 38.0 48.6 ND ND
Resample> 5-Aug-10 0.60 10.0 --- --- --- --- ---85.5 --- --- ------ ND
GWPS = 1 µg/L (10/1/10)1-Dec-10 0.60 10.0 --- 9.8 J 22.1 ---72.7 151 111 43.1 33.3 ND ND
Resample> 13-Jan-11 0.60 10.0 --- --- ND --- ---84.2 --- --- ------ ND
1-Jun-11 0.60 10.0 --- 7.8 J 2.6 J --- J 76.4 99.3 72.9 41.7 38.6 ND ND
20-Dec-11 5.0 10.0 --- --- ND ---92.8 75.6 62.7 36.5 25.5 ND ND
30-May-12 5.0 10.0 --- --- ND ---90.2 108 78.8 42.3 46.2 ND ND
5-Dec-12 5.0 10.0 --- --- ND ---46.6 27.9 101 45.8 51.4 ND ND
12-Jun-13 5.0 10.0 --- --- ND ---243 150 118 92.2 66.0 ND ND
28-Oct-13 5.0 10.0 --- --- ND ---200 128 124 117 75.7 ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- --- --- ---40.4 ------ ND
6-May-14 5.0 10.0 --- --- ND ---138 33.4 68.9 65.9 26.6 ND ND
22-Oct-14 5.0 10.0 --- --- * ND 126 37.1 82.0 74.9 32.1 ND ND
20-May-15 2.5 10.0 --- --- --- ND 116 34.8 77.8 90.0 34.0 ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 175 61.0 84.8 49.7 32.8 ND ND
3-May-16 2.5 10.0 --- --- --- 4.0 J 132 52.6 69.7 85.0 27.6 ND ND
13-Dec-16 2.5 10.0 --- --- --- ND 93.2 52.4 70.6 58.8 28.1 ND ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 3 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Copper 18-Jan-95 --- 10 16.0 NI NI NI ND ND ND 14.0 NI NI ND
6-Feb-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND 20.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND ND ND 18.0 NI NI ND
1-Jan-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 10 21.0 NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 10 14.0 NI --- --- 13.0 11.0 ND 11.0 NI NI ND
1-Oct-96 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 10 ND NI --- --- 30.0 ND ND ND NI NI ND
1-Nov-97 --- 10 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 10 20.0 NI --- --- ND 10.0 70.0 20.0 NI NI ND
1-Nov-98 --- 10 ND NI --- --- 13.0 ND 28.0 ND NI NI ND
11-May-99 --- 5 28.0 49.0 --- --- 14.0 ND 9.3 28.0 37.0 ND ND
18-Oct-99 --- 200 380 ND --- --- ND ND 240 ND ND ND ND
3-May-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 200 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 200 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 200 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 200 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 200 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 200 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 200 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 200 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 0.7 B --- --- ND ND ND 3.2 B ND ND 1.3 J
NC 2L = 1,000 µg/L (10/23/07) 29-Nov-07 --- 10 --- 8.30 J --- --- ND ND ND 6.10 J ND ND ND
29-May-08 0.30 10.0 --- 0.42 B --- --- 0.99 B 1.5 B 1.0 B 14.9 0.89 B ND 0.37 J
6-Nov-08 0.30 10.0 --- 2.0 B --- --- 1.8 B 0.7 B 2.4 B 16.6 4.2 J 0.46 B 0.65 J
3-Jun-09 0.30 10.0 --- 0.83 J --- --- ND 1 J ND 6.7 J 0.61 J 3.5 J ND
18-Nov-09 0.30 10.0 --- 0.34 J --- --- ND ND 1.2 J 10.7 0.38 J ND ND
16-Jun-10 0.30 10.0 --- 0.37 B --- --- 2.6 B 9.0 J 3.2 B 3.4 B ND ND 0.77 J
1-Dec-10 0.30 10.0 --- 1.3 J 36.1 --- 3.8 J 1.2 J 1.8 J 3.9 J 2.1 J ND ND
1-Jun-11 0.30 10.0 --- 0.54 J 12.9 --- 0.94 J 2.3 J 0.79 J 4.8 J 0.66 J ND ND
20-Dec-11 5.0 10.0 --- --- 9.0 J --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- 7.0 J --- ND ND ND ND 5.6 J ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
12-Jun-13 5.0 10.0 --- --- 34.0 B --- ND ND ND 11.1 B ND ND 9.8 J
28-Oct-13 5.0 10.0 --- --- ND --- ND 6.1 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND ND ND 4.6 J ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 8.1 J 6.4 J 9.7 J ND 5.9 J ND ND
3-May-16 2.5 10.0 --- --- --- 8.7 J ND ND ND 9.6 J ND 8.6 J ND
13-Dec-16 2.5 10.0 --- --- --- 4.1 J ND ND ND ND ND ND ND
Cyanide 1-Nov-98 --- 2 6.0 NI --- --- 2.0 ND 7.0 ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 50 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 50 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 50 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 50 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 50 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 10 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- --- --- ND --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
18-Nov-09 5.0 10.0 --- ND --- --- ND ND ND ND ND --- ND
1-Dec-10 5.0 10.0 --- ND 5.9 J --- ND ND 5.2 J 5.8 J 6.5 J --- ND
Resample> 13-Jan-11 5.0 10.0 --- --- ND --- --- --- 5.0 J ND 5.8 J --- ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND 7.0 J --- ND
28-Oct-13 5.0 10.0 --- --- ND --- 12.4 5.6 J 10.0 ND 6.5 J ND ND
Resample> 10-Dec-13 5.0 10.0 --- --- --- --- 10.8 --- 9.0 J --- ------ ND
6-May-14 0.0 0.0 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 2.5 10.0 --- --- * ND 3.6 J 4.7 J 4.2 J ND 5.2 J --- ND
20-May-15 0.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 4.0 10.0 --- --- --- ND ND ND 5.3 J ND ND --- ND
13-Dec-16 4.0 10.0 --- --- --- ND ND ND ND ND ND --- ND
Iron 1-Jun-11 14.0 300 ---308 11,000 ---20,500 29,200 16,300 886 22,200 413 ND
NC 2L = 300 µg/L (01/01/10) Resample>7-Jul-11 50.0 300 --- ---7,150 --- --- --- --- --- --- --- ND
20-Dec-11 50.0 300 --- ---8,010 ---26,300 36,700 22,900 1,160 22,200 93.5 J ND
30-May-12 50.0 300 --- ---5,940 ---24,500 45,700 21,700 1,300 24,500 ND ND
5-Dec-12 50.0 300 --- ---2,970 ---7,010 8,730 28,200 393 21,700 159 J ND
12-Jun-13 50.0 300 --- ---2,460 ---55,300 55,300 34,800 4,650 26,700 522 81.2 J
28-Oct-13 50.0 300 --- ---883 ---28,700 49,700 29,800 1,730 24,300 ND ND
6-May-14 50.0 300 --- ---4,240 ---47,300 46,800 29,700 1,200 24,600 ND ND
23-Oct-14 50.0 300 --- --- *2,340 33,600 29,200 31,200 528 27,700 171 J ND
20-May-15 25.0 300 --- --- ---350 22,400 22,600 33,800 672 25,800 63.5 J ND
8-Dec-15 25.0 300 --- --- ---1,380 102,000 74,200 50,200 1,460 27,400 43.7 J ND
3-May-16 25.0 300 --- --- ---7,630 39,300 67,900 42,400 3,870 24,000 168 J 27.3 J
13-Dec-16 25.0 300 --- --- ---2,020 17,600 67,800 45,300 969 24,000 217 J ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 4 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Lead 15-Sep-94 --- 5 41.0 NI NI NI 12.0 49.0 7.0 43.0 NI NI ND
1-Oct-94 --- 5 --- NI NI NI --- 9.0 --- --- NI NI ND
18-Jan-95 --- 5 35.0 NI NI NI 9.0 17.0 10.0 30.0 NI NI ND
6-Feb-95 --- 5 15.0 NI NI NI 7.0 ND ND 26.0 NI NI ND
1-Mar-95 --- 5 26.0 NI NI NI 16.0 12.0 9.0 43.0 NI NI ND
1-Aug-95 --- 5 11.0 NI --- --- 25.0 16.0 6.0 48.0 NI NI ND
1-Jan-96 --- 5 22.0 NI --- --- 18.0 12.0 10.0 7.0 NI NI ND
1-Feb-96 --- 5 16.0 NI --- --- 15.0 6.0 9.0 10.0 NI NI ND
1-May-96 --- 5 7.0 NI --- --- 8.0 9.0 15.0 ND NI NI ND
1-Oct-96 --- 5 15.0 NI --- --- 24.0 10.0 7.0 6.0 NI NI ND
1-May-97 --- 5 16.0 NI --- --- 23.0 10.0 22.0 16.0 NI NI ND
1-Nov-97 --- 5 40.0 NI --- --- 27.0 14.0 30.0 24.0 NI NI ND
1-May-98 --- 5 18.0 NI --- --- 9.0 ND 10.0 6.0 NI NI ND
1-Nov-98 --- 5 7.0 NI --- --- 39.0 9.0 47.0 14.0 NI NI ND
11-May-99 --- 10 14.0 18.0 --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 10 160 54.0 --- --- 56.0 27.0 140 23.0 ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND 11.0 J ND ND
7-Nov-00 --- 10 ND 20.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND 19.0 --- --- ND ND ND 20.0 ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 2.5 J --- --- ND ND ND 2.3 J ND ND ND
NC 2L = 15 µg/L (10/23/07)29-Nov-07 --- 10 --- 7.5 J --- --- ND 6.1 J ND 5.1 J ND ND ND
29-May-08 4.0 10.0 --- ND --- --- ND ND ND 6.8 ND ND ND
6-Nov-08 4.0 10.0 --- ND --- --- ND ND ND 8.8 J ND ND ND
3-Jun-09 4.0 10.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 4.0 10.0 --- ND --- --- ND ND ND 5.5 J ND ND ND
16-Jun-10 4.0 10.0 --- ND --- --- 4.4 J 13.9 ND ND ND ND ND
1-Dec-10 4.0 10.0 --- ND 16.8 --- ND ND ND ND ND ND ND
Resample> 13-Jan-11 4.0 10.0 --- ND ND --- --- --- --- --- ------ ND
1-Jun-11 4.0 10.0 --- ND 5.9 J --- ND ND ND ND ND ND ND
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND 5.5 J ND 5.6 J ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND 5.2 J ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND 4.9 J 4.3 J ND ND 2.7 J ND ND
8-Dec-15 2.5 10.0 --- --- --- ND 7.8 J 6.3 J 9.8 J ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND 6.8 J 5.3 J 3.3 J 3.8 J ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND 3.5 J 2.6 J ND ND ND ND
Manganese 1-Jun-11 0.30 50.0 ---385 209 ---5,770 14,500 9,330 1,160 8,460 123 0.36 J
NC 2L = 50 µg/L (01/01/10) Resample>7-Jul-11 5.0 50.0 --- --- 143 --- --- --- --- --- ------ ND
20-Dec-11 5.0 50.0 --- ---136 ---6,670 15,500 D 9,480 1,030 8,540 119 ND
30-May-12 5.0 50.0 --- ---104 ---6,700 14,300 9,370 1,170 8,790 119 ND
5-Dec-12 5.0 50.0 --- ---54.5 ---2,650 8,930 9,150 1,230 9,180 122 ND
12-Jun-13 5.0 50.0 --- --- 49.3 J ---16,800 15,400 11,700 2,060 8,150 130 ND
28-Oct-13 5.0 50.0 --- ---80.0 ---8,420 15,000 9,910 2,500 9,680 124 ND
6-May-14 50.0 500.0 --- ---83.5 ---12,300 18,300 9,950 1,600 9,720 119 ND
23-Oct-14 50.0 500.0 --- --- *73.6 9,400 23,200 11,000 1,740 11,500 115 ND
20-May-15 2.5 50.0 --- --- --- 27.4 9,070 29,800 10,800 2,010 12,400 121 ND
8-Dec-15 12.5 50.0 --- --- --- 50.0 J 15,000 18,100 10,800 1,500 8,440 124 ND
3-May-16 2.5 50.0 --- --- ---142 7,850 17,500 9,140 1,810 6,600 119 ND
13-Dec-16 2.5 50.0 --- --- --- 48.1 J 5,100 17,900 8,850 1,560 10,900 122 ND
Mercury 16-Aug-95 --- 0.2 0.30 B NI --- --- 0.30 B 0.30 B 0.20 B 0.30 B NI NI 0.2
25-Jan-96 --- 0.2 1.6 NI --- --- 0.40 0.70 ND 1.3 NI NI ND
28-Feb-96 --- 0.2 ND NI --- --- 2.4 ND ND 0.20 NI NI ND
1-May-96 --- 0.2 1.4 NI --- --- 1.7 1.5 2.1 2.3 NI NI ND
1-Oct-96 --- 0.5 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- --- --- NI --- --- NS NS NS NS NI NI NS
1-Nov-97 --- 0.2 ND NI --- --- 0.80 ND ND ND NI NI ND
1-May-98 --- 0.2 ND NI --- --- 0.80 ND ND 0.40 NI NI ND
1-Nov-98 --- 0.2 ND NI --- --- 1.3 ND ND 0.49 NI NI ND
11-May-99 --- 0.2 --- ND --- --- --- --- --- --- ND ND ---
18-Oct-99 --- 0.5 ND ND --- --- --- ND ND 0.55 ND ND ND
3-May-00 --- 0.5 --- --- --- --- --- --- --- --- ------ ---
7-Nov-00 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 0.5 ND --- --- --- 0.70 ND ND 0.90 ND --- ND
7-Nov-01 --- 0.5 ND --- --- --- ND ND ND 1.0 ND --- ND
22-May-02 --- 0.5 ND --- --- --- 0.62 ND ND ND ND --- ND
14-Nov-02 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
14-May-03 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 0.5 ND --- --- --- 0.80 ND ND 0.73 ND --- ND
6-May-04 --- 0.5 ND --- --- --- 0.71 ND ND 0.52 ND --- ND
10-Nov-04 --- 0.5 ND --- --- --- ND ND ND 0.74 ND --- ND
5-May-05 --- 0.5 ND --- --- --- ND ND ND ND ND --- ND
3-Nov-05 --- 0.5 --- ND --- --- 1.0 ND ND ND ND --- ND
25-May-06 --- 2 --- --- --- --- ND ND ND ND ND --- ND
2-Nov-06 --- 0.5 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 0.2 --- --- --- --- 0.12 J ND ND 0.13 J ND --- ---
NC 2L = 1.05 µg/L (10/23/07)29-Nov-07 --- 0.2 --- ND --- --- 0.88 ND ND 0.50 ND ND ND
29-May-08 0.090 0.20 --- --- --- --- 0.12 B ND 0.13 B 0.66 0.12 B --- 0.1 J
6-Nov-08 0.090 0.20 --- ND --- --- ND ND ND 0.41 ND ND ND
3-Jun-09 0.070 0.20 --- ND --- --- ND ND ND 0.14 J ND --- ND
18-Nov-09 0.070 0.20 --- ND --- --- ND ND ND 0.43 ND ND ND
NC 2L = 1 µg/L (01/01/10)16-Jun-10 0.070 0.20 --- ND --- --- 0.17 J ND ND 0.077 J ------ ND
1-Dec-10 0.070 0.20 --- 0.089 J ND --- 0.62 ND ND 0.21 ND ND ND
1-Jun-11 0.10 0.20 --- ND ND --- 0.19 J ND ND 0.19 J ND --- ND
20-Dec-11 0.10 0.20 --- --- ND --- 0.14 J ND ND 0.15 J ND ND ND
30-May-12 0.10 0.10 --- --- ND --- 0.13 J ND ND 0.10 J ND ND ND
5-Dec-12 0.10 0.20 --- --- ND --- 0.11 J ND ND 0.27 ND --- ND
12-Jun-13 0.10 0.20 --- --- ND --- ND ND ND 0.56 ND ND ND
28-Oct-13 0.10 0.20 --- --- ND --- 0.15 J ND ND 0.11 J ND ND ND
6-May-14 0.10 0.20 --- --- ND --- 0.15 J ND ND ND ND ND ND
23-Oct-14 0.10 0.20 --- --- * ND ND ND ND 0.38 ND ND ND
20-May-15 0.10 0.20 --- --- --- ND 0.13 J ND ND 0.45 ND ND ND
8-Dec-15 0.10 0.20 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.10 0.20 --- --- --- ND 0.33 ND ND 0.40 ND ND ND
13-Dec-16 0.10 0.20 --- --- --- ND 0.25 ND ND 0.15 J ND ND ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 5 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Nickel 15-Sep-94 --- 50 ND NI NI NI ND ND 100 ND NI NI ND
1-Oct-94 --- 50 --- NI NI NI --- ND --- --- NI NI ND
18-Jan-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
6-Feb-95 --- 50 ND NI NI NI ND ND 71.0 ND NI NI ND
1-Mar-95 --- 50 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND 80.0 ND NI NI ND
1-May-98 --- 50 ND NI --- --- ND ND 90.0 ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- ND ND 74.0 ND NI NI ND
11-May-99 --- 5 21.0 33.0 --- --- 16.0 11.0 63.0 14.0 53.0 ND ND
18-Oct-99 --- 50 180 67.0 --- --- 55.0 ND 570 ND ND ND ND
3-May-00 --- 50 ND ND --- --- ND ND ND ND 71.0 ND ND
7-Nov-00 --- 50 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 50 --- 2.2 J --- --- 2.1 J 2.2 J 3.7 J 4.1 J ND ND ND
NC 2L = 100 µg/L (10/23/07)29-Nov-07 --- 50 --- 3.9 J --- --- ND 7.3 J 8.0 J 2.2 J ND ND ND
29-May-08 1.7 50.0 --- 3.6 J --- --- 3.1 J 5.6 J 3.0 J 4.3 J 2.5 J ND ND
6-Nov-08 1.7 50.0 --- 2.2 J --- --- 2.9 J 5.6 J 6.8 J 5.1 J 5.6 J ND ND
3-Jun-09 1.7 50.0 --- 3.1 B --- --- 2.6 B 8.5 B ND 4.1 B 2.8 B 2.2 B 1.7 J
18-Nov-09 1.7 50.0 --- 2.4 J --- --- 3.2 J 5.9 J 4.9 J 4.9 J 1.8 J ND ND
16-Jun-10 1.7 50.0 --- 1.7 J --- --- 4.5 J 13.1 J 8.2 J 3.4 J 1.7 J ND ND
1-Dec-10 1.7 50.0 --- ND 19.0 J --- 3.1 J 4.1 J 7.8 J 3.7 J ND ND ND
1-Jun-11 1.7 50.0 --- ND 4.7 B --- 2.2 B 3.5 B 2.2 B 3.0 B ND ND 2.3 J
20-Dec-11 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 50.0 --- --- ND --- ND ND ND ND 5.2 J ND ND
5-Dec-12 5.0 50.0 --- --- ND --- ND ND 6.7 J ND ND ND ND
12-Jun-13 5.0 50.0 --- --- ND --- ND ND 5.2 J 5.4 J ND ND ND
28-Oct-13 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 50.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 50.0 --- --- * ND 6.0 J ND ND ND ND ND ND
20-May-15 2.5 50.0 --- --- --- ND 5.3 J 4.6 J 3.1 J 4.4 J ND ND ND
8-Dec-15 2.5 50.0 --- --- --- ND 5.5 J 3.4 J 17.7 J 4.2 J ND ND ND
3-May-16 2.5 50.0 --- --- --- ND 4.5 J 5.0 J 21.6 J 5.6 J ND ND ND
13-Dec-16 2.5 50.0 --- --- --- ND 3.9 J 3.8 J 29.7 J 3.8 J ND ND ND
Selenium 29-May-08 3.8 10.0 --- ND --- --- ND 6.1 J ND ND 5.8 J ND ND
6-Nov-08 3.8 10.0 --- ND --- --- 13.2 6.4 J 6.7 J ND 5.8 J ND ND
3-Jun-09 3.8 10.0 --- ND --- --- ND 5.4 J ND ND ND ND ND
18-Nov-09 3.8 10.0 --- ND --- --- ND 4.3 J 4.7 J 4.4 J 5.0 J ND ND
NC 2L = 20 µg/L (01/01/10)16-Jun-10 3.8 10.0 --- ND --- --- 3.8 J ND 6.9 J ND ND ND ND
1-Dec-10 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 3.8 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 10.0 10.0 --- --- ND --- 11.7 11.3 ND ND ND ND ND
5-Dec-12 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 10.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 5.0 10.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 6 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Silver 6-Feb-95 --- 10 ND NI NI NI 11.0 ND 11.0 ND NI NI ND
1-Mar-95 --- 10 ND NI NI NI ND ND ND ND NI NI ND
1-Aug-95 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Jan-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Feb-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Oct-96 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-97 --- 5 ND NI --- --- 6.0 ND ND ND NI NI ND
1-Nov-97 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND ND NI NI ND
11-May-99 --- 2 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 15.0 B 15.0 B --- --- 14.0 B 15.0 B 14.0 B 12.0 B 16.0 B 16.0 B 15.0
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 10 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 17.5 µg/L (10/23/07)29-Nov-07 --- 10 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.10 10.0 --- 0.14 J --- --- 0.59 J 1.1 J 0.45 J ND 0.57 J ND ND
6-Nov-08 0.10 10.0 --- 0.25 B --- --- 1.1 B 2.1 J 1.3 J 0.26 B 1.1 B 0.22 B 0.23 J
3-Jun-09 0.10 10.0 --- 0.68 B --- --- 1.0 B 1.4 B 0.73 B 0.13 B 0.76 B 1.0 B 0.31 J
18-Nov-09 0.10 10.0 --- 0.28 B --- --- 0.72 B 1.0 B 0.61 B 0.19 B 0.57 B 0.19 B 0.23 J
NC 2L = 20 µg/L (01/01/10)16-Jun-10 0.10 10.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.10 10.0 --- ND ND --- ND 0.24 J ND ND ND ND ND
1-Jun-11 0.10 10.0 --- 0.39 B 0.16 B --- 0.22 B 0.60 B 0.32 B 0.29 B 0.22 B 0.23 B 0.17 J
20-Dec-11 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.0 10.0 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.0 10.0 --- --- * ND ND ND ND ND ND ND ND
20-May-15 2.5 10.0 --- --- --- ND ND 3.6 J ND ND ND ND ND
8-Dec-15 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 2.5 10.0 --- --- --- ND ND ND ND ND ND ND ND
Sulfide 1-Aug-95 --- 100 900 NI --- --- ND 600 ND 100 NI NI ND
1-Jan-96 --- 100 ND NI --- --- ND 300 ND ND NI NI ND
1-Feb-96 --- 100 ND NI --- --- ND 100 ND ND NI NI ND
1-May-96 --- 100 200 NI --- --- ND 900 700 300 NI NI ND
1-Oct-96 --- 100 2800 NI --- --- ND 200 3000 7500 NI NI ND
1-May-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-Nov-97 --- 50 ND NI --- --- ND ND ND ND NI NI ND
1-May-98 --- 50 50 NI --- --- ND ND ND ND NI NI ND
1-Nov-98 --- 50 ND NI --- --- 130 ND 80.0 110 NI NI ND
11-May-99 --- 50 ND ND --- --- ND ND ND ND --- ND ND
18-Oct-99 --- 1000 ND ND --- --- --- ND ND ND ND ND ND
7-Nov-00 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
31-May-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
7-Nov-01 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
14-Nov-02 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
20-Nov-03 --- 1000 ND --- --- --- ND ND ND ND ND --- ND
10-Nov-04 --- 1000 ND --- --- --- ND ND ND ND ND ---6
3-Nov-05 --- --- --- ND --- --- ND ND 1800 ND ND --- ND
2-Nov-06 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
NC 2L = NE (10/23/07)29-Nov-07 --- 1000 --- ND --- --- ND ND ND ND ND --- ND
6-Nov-08 100 1000 --- ND --- --- ND ND ND ND ND --- ND
3-Jun-09 100 1000 --- ND --- --- --- ND ND --- ND --- ND
18-Nov-09 100 1000 --- ND --- --- ND ND ND ND ND --- ND
16-Jun-10 100 1000 --- ND --- --- --- ND ND --- ND --- ND
1-Dec-10 100 1000 --- ND ND --- ND ND ND ND ND --- ND
5-Dec-12 100 1000 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 100 1000 --- --- ND --- ND ND ND ND ND --- ND
28-Oct-13 100 1000 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 100 1000 --- --- * ND --- --- --- --- ------ ND
8-Dec-15 100 1000 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 100 1000 --- --- --- ND --- --- --- --- ------ ND
13-Dec-16 100 1000 --- --- --- ND ND ND ND ND ND --- ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 7 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Thallium 1-Nov-97 --- 1 2.0 B NI --- --- 2.0 B 2.0 B 3.0 B 1.0 B NI NI 2.0
1-May-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
1-Nov-98 --- 1 ND NI --- --- ND ND ND 1.0 NI NI ND
11-May-99 --- 2 2.0 3.0 --- --- 4.0 3.0 4.0 ND 3 2.0 ND
18-Oct-99 --- 10 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 10 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 10 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 10 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 10 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 10 16.0 ND --- --- 41.0 23.0 25.0 14.0 26.0 ND ND
3-Nov-05 --- 10 --- ND --- --- 19.0 17.0 15.0 ND 13.0 ND ND
25-May-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 10 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.5 --- ND --- --- 0.169 J 0.29 J 0.221 J 0.131 J 0.078 J ND ND
GWPS = 0.28 µg/L (10/23/07)29-Nov-07 --- 5.5 --- 0.042 J --- --- 0.118 J 0.321 J 0.199 J 0.150 J 0.065 J ND ND
29-May-08 3.0 5.5 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 3.0 5.5 --- ND --- ---8.9 ND ND ND ND ND ND
3-Jun-09 3.0 5.5 --- ND --- --- ND ND ND ND ND 14.8 ND
18-Nov-09 3.0 5.5 --- ND --- --- ND ND ND ND ND ND 4.2 J
16-Jun-10 3.0 5.5 --- ND --- --- 5.3 J 7.7 4.1 J ND 4.0 J ND ND
Resample> 5-Aug-10 3.0 5.5 --- --- --- --- ---20.4 --- --- ------ 3.2 J
GWPS = 0.2 µg/L (10/1/1)1-Dec-10 3.0 5.5 --- 3.3 B ND --- 3.3 B 9.1 B 5.1 B ND 7.8 B ND 3.1 J
1-Jun-11 3.0 5.5 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.4 5.5 --- --- ND --- ND ND ND ND ND ND 6.8
12-Jun-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 5.4 5.5 --- --- ND --- ND ND ND ND ND ND ND
23-Oct-14 5.4 5.5 --- --- * ND ND ND ND ND ND ND ND
20-May-15 5.0 5.5 --- --- --- ND ND 6.4 ND ND ND ND ND
8-Dec-15 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 5.0 5.5 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 5.0 5.5 --- --- --- ND 5.3 J 5.1 J ND ND ND ND ND
Tin 6-Nov-08 1.8 100 --- ND --- --- 2.3 J 3.8 J 2.1 J ND 2.9 J --- ND
GWPS = 0.28 µg/L (10/23/07)3-Jun-09 --- --- --- --- --- --- --- --- --- --- ------ ---
18-Nov-09 1.8 100 --- ND --- --- ND ND ND ND ND ND ND
GWPS =2,100 µg/L (01/01/10)16-Jun-10 1.8 100 --- ND --- --- ND ND ND ND ------ ND
GWPS =2,000 µg/L (10/1/10)1-Dec-10 1.8 100 --- ND ND --- ND ND ND ND ND --- ND
1-Jun-11 1.8 100 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 5.0 100 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 5.0 100 --- --- ND --- ND 5.1 J ND ND ND --- ND
6-May-14 5.0 100 --- --- ND --- ND ND ND ND ND --- ND
23-Oct-14 5.0 100 --- --- * ND ND ND ND ND ND --- ND
20-May-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 2.5 100 --- --- --- ND ND ND ND ND ND --- ND
Vanadium 1-May-97 --- 5 12.0 NI --- --- 5.0 ND 66.0 9.0 NI NI ND
1-Nov-97 --- 40 ND NI --- --- ND ND 180 ND NI NI ND
1-May-98 --- 5 14.0 NI --- --- 6.0 7.0 159 22.0 NI NI ND
1-Nov-98 --- 5 15.0 NI --- --- 12.0 8.0 110 14.0 NI NI ND
11-May-99 --- 5 55.0 58.0 --- --- 25.0 16.0 72.0 31.0 71.0 100 ND
18-Oct-99 --- 40 630 150 --- --- 150 79.0 690 62.0 ND ND ND
3-May-00 --- 40 ND ND --- --- ND ND ND ND 140 ND ND
7-Nov-00 --- 40 ND 66.0 --- --- ND ND ND ND ND ND ND
31-May-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 40 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 40 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 40 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 40 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 40 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 40 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 40 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 25 --- ND --- --- ND ND ND ND ND ND 1.3 J
GWPS = 3.5 µg/L (10/23/07)29-Nov-07 --- 25 --- 7.3 J --- --- ND ND ND ND ND ND ND
29-May-08 0.2 25.0 --- 0.43 J --- --- ND 2.4 J 1.3 J 3.7 J ND ND ND
6-Nov-08 0.2 25.0 --- 3.0 B --- --- 2.2 B 0.53 B 5.5 B 11.1 J 6.2 B 1.4 B 2.1 J
3-Jun-09 0.2 25.0 --- 0.94 B --- --- 0.47 B 0.91 B 0.66 B 5.2 J 1.8 B 2.7 B 1.0 J
18-Nov-09 0.20 25.0 --- 0.82 B --- --- 0.43 B 0.66 B 4.1 J 5.4 J 1.3 B 0.29 B 0.56 J
16-Jun-10 0.20 25.0 --- 1.1 B --- --- 4.5 B 28.5 8.3 J 2.0 B 1.3 B 0.66 B 0.98 J
Resample> 5-Aug-10 0.20 25.0 --- --- --- --- --- 1.5 B --- --- ------ 0.62 J
GWPS = 0.3 µg/L (10/1/10)1-Dec-10 0.20 25.0 --- 0.48 J 55.2 --- 3.2 J 0.63 J 5.7 J 0.33 J 2.9 J 2.4 J ND
Resample> 13-Jan-11 0.20 25.0 --- --- 0.55 B --- --- --- --- --- ------ 0.33 J
1-Jun-11 0.20 25.0 --- 0.69 J 17.2 J --- 0.34 J 1.5 J 0.32 J 0.37 J ND 5.5 J ND
20-Dec-11 5.0 25.0 --- --- 10.7 J --- ND ND ND ND ND ND ND
30-May-12 5.0 25.0 --- --- 9.2 J --- ND ND ND ND 7.9 J ND ND
5-Dec-12 5.0 25.0 --- --- ND --- ND ND 6.1 J ND ND ND ND
12-Jun-13 5.0 25.0 --- --- ND --- ND ND ND 5.6 J ND ND ND
28-Oct-13 5.0 25.0 --- --- ND --- ND 8.3 J ND ND ND ND ND
6-May-14 5.0 25.0 --- --- 6.7 J --- ND ND ND ND ND ND ND
22-Oct-14 5.0 25.0 --- --- * 9.6 J ND ND ND ND ND ND ND
20-May-15 2.5 25.0 --- --- --- ND 9.1 J 20.1 J 10.7 J 2.6 J 11.3 J ND ND
8-Dec-15 2.5 25.0 --- --- --- 6.6 J 20.4 J 23.5 J 36.9 3.0 J 11.5 J ND ND
Lab Re-run analyses> 8-Dec-15 2.5 25.0 --- --- --- --- --- --- 19.8 J --- ------ ---
3-May-16 2.5 25.0 --- --- ---29.7 ND ND ND 5.7 J ND ND ND
13-Dec-16 2.5 25.0 --- --- --- 6.8 J ND ND ND ND ND ND ND
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 8 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Zinc 15-Sep-94 --- 10 36.0 NI NI NI ND 27.0 ND ND NI NI ND
1-Oct-94 --- 10 --- NI NI NI --- 52.0 --- --- NI NI ND
18-Jan-95 --- 10 21.0 NI NI NI ND 27.0 21.0 ND NI NI ND
6-Feb-95 --- 10 21.0 NI NI NI ND 18.0 37.0 14.0 NI NI ND
1-Mar-95 --- 10 27.0 NI NI NI 14.0 24.0 29.0 29.0 NI NI ND
1-Aug-95 --- 10 ND NI --- --- ND 29.0 23.0 27.0 NI NI ND
1-Jan-96 --- 10 28.0 NI --- --- 22.0 37.0 49.0 21.0 NI NI ND
1-Feb-96 --- 10 48.0 NI --- --- 27.0 24.0 31.0 26.0 NI NI ND
1-May-96 --- 10 46.0 NI --- --- 46.0 48.0 56.0 55.0 NI NI ND
1-Oct-96 --- 10 23.0 NI --- --- 16.0 30.0 20.0 16.0 NI NI ND
1-May-97 --- 10 50.0 NI --- --- 50.0 50.0 80.0 50.0 NI NI ND
1-Nov-97 --- 10 60.0 NI --- --- 20.0 30.0 80.0 ND NI NI ND
1-May-98 --- 10 40.0 NI --- --- 30.0 40.0 110 30.0 NI NI ND
1-Nov-98 --- 10 29.0 NI --- --- 24.0 23.0 150 ND NI NI ND
11-May-99 --- 20 64.0 43.0 --- --- 150 28.0 68.0 61.0 69.0 210 ND
18-Oct-99 --- 50 570 89.0 --- --- 160 140 700 75.0 J ND 99.0 ND
3-May-00 --- 50 ND ND --- --- ND ND ND 62.0 J 160 63.0 J ND
7-Nov-00 --- 50 130 150 --- --- ND 110 60.0 70.0 ND ND ND
31-May-01 --- 50 ND ND --- --- ND ND 79.0 ND ND ND ND
7-Nov-01 --- 50 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 50 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 50 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 50 ND 100 --- --- 50.0 ND ND ND ND ND ND
6-May-04 --- 50 ND ND --- --- 78.0 ND ND ND ND ND ND
10-Nov-04 --- 50 ND ND --- --- ND ND ND ND ND ND ND
5-May-05 --- 50 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 50 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 50 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10 --- 5.9 B --- --- 7.6 B 11.4 19.3 14.0 46.5 1.3 1.6 J
NC 2L = 1,050 µg/L (10/23/07) 29-Nov-07 --- 10 --- 20.4 --- --- 10.9 B 62.0 30.2 16.4 44.5 35.6 3.1 J
29-May-08 0.40 10.0 --- 2.9 B --- --- 20.4 44.3 27.9 25.7 35.2 25.0 3.0 J
6-Nov-08 0.40 10.0 --- 12.1 B --- --- 10.2 B 16.6 18.6 27.1 76.7 30.9 2.7 J
3-Jun-09 0.40 10.0 --- 3.9 B --- --- 4.6 B 40.5 B 7.0 B 20.0 B 19.2 B 6.6 B 82.0
18-Nov-09 0.40 10.0 --- 4.2 B --- --- 7.2 B 21.4 18.6 22.1 13.6 B 2.5 B 3.1 J
NC 2L = 1,000 µg/L (01/01/10)16-Jun-10 0.40 10.0 --- ND --- --- 6.0 J 56.2 20.5 10.1 24.0 ND ND
1-Dec-10 0.40 10.0 --- 6.5 J 76.5 --- 14.1 33.4 25.6 16.2 119 5.4 J 0.62 J
1-Jun-11 0.40 10.0 --- 8.3 B 31.6 B --- 14.3 B 40.8 B 27.2 B 20.1 B 24.9 B 44.7 B 13.7
20-Dec-11 10.0 10.0 --- --- 19.6 --- 13.3 40.8 20.2 17.6 30.5 15.8 ND
30-May-12 10.0 10.0 --- --- 11.5 --- ND 39.2 16.6 13.3 48.8 ND ND
5-Dec-12 10.0 10.0 --- --- ND --- 12.1 17.8 24.4 17.8 ND 11.2 ND
12-Jun-13 10.0 10.0 --- --- 31.4 --- ND 38.9 B ND 23.7 B ND 32.2 B 76.5
28-Oct-13 10.0 10.0 --- --- 15.9 --- ND 68.9 14.3 22.0 18.2 ND ND
6-May-14 10.0 10.0 --- --- 13.7 --- ND 23.4 12.2 17.2 11.7 ND ND
23-Oct-14 10.0 10.0 --- --- * ND ND 17.8 11.2 18.5 32.2 13.9 ND
20-May-15 5.0 10.0 --- --- --- 26.4 9.6 J 24.2 15.6 19.8 20.4 ND ND
8-Dec-15 5.0 10.0 --- --- --- ND 9.0 J 20.0 65.1 19.0 47.3 8.2 J ND
3-May-16 5.0 10.0 --- --- --- 10.5 B 7.5 B 35.3 B 8.4 B 23.2 B 20.7 B 9.3 B 7.4 J
13-Dec-16 5.0 10.0 --- --- --- ND 12.8 17.6 9.7 J 15.7 51 6.8 J ND
Alkalinity, Total as CaCO3 1-Jun-11 5,000 5,000 --- 45,100 --- --- --- 177,000 70,700 --- 109,000 --- ND
NC 2L = NE (01/01/10)20-Dec-11 5,000 5,000 --- --- 8,580 --- 53,600 189,000 70,800 ND 77,200 47,200 ND
30-May-12 1,000 1,000 --- --- 8,140 --- 64,700 200,000 76,700 8,360 104,000 44,400 ND
5-Dec-12 1,000 5,000 --- --- 7,690 --- 22,600 178,000 76,600 ND 106,000 46,500 ND
12-Jun-13 1,000 5,000 --- --- 7,950 --- 138,000 202,000 111,000 7,020 99,700 51,700 ND
28-Oct-13 1,000 5,000 --- --- 8,140 --- 69,900 197,000 91,300 9,520 116,000 45,000 ND
6-May-14 1,000 5,000 --- --- 8,060 --- 85,900 208,000 90,600 5,520 119,000 45,700 ND
23-Oct-14 1,000 5,000 --- --- * 1,360 J 88,100 215,000 96,100 7,500 122,000 52,000 ---
20-May-15 1,000 5,000 --- --- --- ND 67,300 153,000 67,500 8,780 92,100 41,600 ---
8-Dec-15 1,000 NE --- --- --- 1,030 J 98,400 202,000 88,800 9,130 95,900 46,200 ---
3-May-16 1,000 NE --- --- --- 1,250 J 57,400 146,000 56,800 9,300 79,200 49,600 ND
13-Dec-16 1,000 5,000 --- --- --- 1,190 J 35,700 97,700 54,100 9,380 72,100 49,400 ---
Chloride 1-Jun-11 5,000 5,000 --- ND --- --- --- 17,000 6,330 --- 7,870 --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 6,320 20,200 6,400 ND 6,530 ND ND
30-May-12 1,000 1,000 --- --- 1,480 --- 6,190 20,000 ND 2,100 5,840 ND ND
5-Dec-12 1,000 1,000 --- --- 2,130 --- 5,970 19,500 7,290 2,060 7,430 1,130 ND
12-Jun-13 1,000 1,000 --- --- 1,380 --- 13,300 19,500 7,500 2,260 5,100 ND ND
28-Oct-13 1,000 1,000 --- --- 1,120 --- 11,400 18,100 7,750 2,210 8,490 ND ND
6-May-14 1,000 1,000 --- --- ND --- 17,300 18,200 8,140 1,890 8,920 ND ND
23-Oct-14 500 1,000 --- --- * ND 19,200 20,800 9,050 1,570 8,120 642 J ND
20-May-15 500 1,000 --- --- --- --- 14,000 25,300 9,680 1,720 10,400 572 J ---
8-Dec-15 500 NE --- --- --- 859 J 26,500 30,800 9,400 1,910 4,190 945 J ---
3-May-16 500 NE --- --- --- 558 J 13,500 33,200 11,300 3,170 7,810 1,120 ---
13-Dec-16 500 1,000 --- --- --- 1,470 9,040 35,000 7,650 1,810 9,280 965 J ---
Sulfate 1-Jun-11 5,000 5,000 --- ND --- --- --- ND ND --- ND --- ND
NC 2L = 250,000 µg/L (01/01/10) 20-Dec-11 5,000 5,000 --- --- ND --- 5,150 ND ND ND ND 8,630 ND
30-May-12 2,000 250,000 --- --- ND --- 5,380 J ND ND ND ND 8,860 J ND
5-Dec-12 2,000 250,000 --- --- ND --- 2,880 J 2,920 J 4,400 J ND 2,320 J 8,910 J ND
12-Jun-13 2,000 250,000 --- --- ND --- 11,200 J 3,080 J 2,910 J 6,940 J ND 9,310 J ND
28-Oct-13 2,000 250,000 --- --- ND --- 4,420 J ND 2,940 J ND ND 8,150 J ND
6-May-14 2,000 250,000 --- --- ND --- 10,500 J 2,300 J 3,720 J ND 2,070 J 8,780 J ND
23-Oct-14 1,000 250,000 --- --- * ND 7,270 J 2,280 J 3,740 J 1,240 J 1,940 J 9,710 J ND
20-May-15 1,000 250,000 --- --- --- ND 5,620 J 2,310 J 3,440 J ND 2,150 J 8,780 J ---
8-Dec-15 1,000 250,000 --- --- --- ND 10,200 J 1,530 J 2,020 J ND ND 9,260 J ---
3-May-16 2,000 250,000 --- --- --- ND 5,300 J 5,490 J 3,440 J ND ND 8,720 J ---
13-Dec-16 1,000 250,000 --- --- --- 1,340 J 3,220 J 3,500 J 4,050 J 1,340 J 1,930 J 9,850 J ---
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 9 of 10 Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED INORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Total Dissolved Solids, Dissolved 1-Jun-11 25,000 25,000 --- 62,000 --- --- --- 200,000 93,000 --- 127,000 --- ND
NC 2L = 500,000 µg/L (01/01/10) 20-Dec-11 25,000 25,000 --- --- ND --- 59,000 196,000 82,000 ND 103,000 78,000 ND
30-May-12 25,000 25,000 --- --- 37,000 --- 85,000 12,500 J 109,000 ND 136,000 90,000 ND
5-Dec-12 25,000 25,000 --- --- 35,000 --- 50,000 219,000 109,000 28,000 134,000 97,000 ND
12-Jun-13 25,000 25,000 --- --- 34,000 --- 177,000 225,000 136,000 ND 111,000 107,000 ND
28-Oct-13 25,000 25,000 --- --- 49,000 --- 109,000 227,000 134,000 ND 138,000 112,000 ND
6-May-14 25,000 25,000 --- --- 34,000 --- 136,000 234,000 115,000 32,000 126,000 102,000 ND
23-Oct-14 25,000 25,000 --- --- * ND 126,000 238,000 119,000 ND 129,000 98,000 ND
20-May-15 25,000 25,000 --- --- --- ND 112,000 252,000 122,000 30,000 135,000 88,000 ---
8-Dec-15 25,000 NE --- --- --- ND 182,000 280,000 117,000 ND 106,000 93,000 ---
3-May-16 25,000 NE --- --- --- ND 110,000 245,000 129,000 ND 89,000 89,000 ---
13-Dec-16 25,000 25,000 --- --- --- ND 73,000 241,000 133,000 ND 131,000 90,000 ---
Notes:
(Abbreviations and Referrences)
All concentrations in micrograms per liter (µg/L) = parts per billion.
--- = Not sampled for this parameter or not reported.
AB = Monitoring well abandoned.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NE = No NC 2L or GWPS established.
NI = Not Installed; monitoring was not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A).
See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
The dates on the table above reflect the last samples were collected during the semiannual monitoring event. Individual collection dates are preserved in the Lab Reports (Appendix B).
Pace Analytical Re-ran the analysis for Antimony, Chromium, and Vanadium in MW-12 on January 19, 2016 from the samples collected in December 2016, and the results are included in the table.
A Verification Sampling Event was performed for beta-BHC in MW-11 and Antimony and Chromium in MW-12 on February 4, 2016, for the December 2015 event and results are included.
Burke County - Johns River C and D over MSW Landfill
Permit 12-03 Page 10 of 10 Joyce Engineering

Appendix E

Historical Detected Organic Groundwater Constituents

APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Organic CompoundsAcetone 30-May-07 --- 100.0 --- 2.7 B --- --- ND ND ND ND ND ND 2.1 J
NC 2L = 700 µg/L (10/23/07)29-Nov-07 --- 100.0 --- 8.1 B --- --- 3 B ND 2.8 B 8.1 B 13 B 2.6 B 5.1 J29-May-08 20.0 100.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 20.0 100.0 --- 26.8 J --- --- ND ND ND ND ND ND ND3-Jun-09 2.2 100.0 --- 48.3 J --- --- 6.5 J ND ND ND 18.5 J ND ND
18-Nov-09 2.2 100.0 --- ND ND --- ND ND ND ND ND ND NDNC 2L = 6,000 µg/L (01/01/10)16-Jun-10 2.2 100.0 --- 5.3 B --- --- ND 3.1 B ND ND ND ND 7.2 J
1-Dec-10 2.2 100.0 --- ND ND --- 8.4 B ND ND ND 56.6 J ND 3.7 J1-Jun-11 2.2 100.0 --- 3.5 B ND --- 3.4 B 8.1 B 7.7 B ND 80 J ND 3.9 J
20-Dec-11 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 2.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 10.0 100.0 --- --- ND --- 33 J ND ND ND 20.5 J ND ND
28-Oct-13 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 10.0 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 10.0 100.0 --- --- * ND ND ND 10.4 J ND ND ND ND
21-May-15 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 10.0 100.0 --- --- --- ND ND ND ND ND 16.5 J ND ND
3-May-16 10.0 100.0 --- --- --- ND ND ND ND 41.5 J ND ND ND
13-Dec-16 10.0 100.0 --- --- --- ND ND ND ND ND ND ND ND
Acrolein 8-Dec-15 1.6 53.0 --- --- --- 1.6 B ND ND ND ND ND ---2.8 J
# NC 2L = 6,000 µg/L (01/01/10) 13-Dec-16 1.6 53.0 --- --- --- ND ND ND ND ND ND ---ND
Benzene 1-Oct-96 --- 5.0 --- NI --- --- ND 6 ND ND NI NI ---1-May-97 --- 5.0 ND NI --- --- ND 6.8 2.7 J ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND 9 ND ND NI NI ---1-May-98 --- 5.0 ND NI --- --- ND 10 9.4 ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 11.6 ND ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND 13 ND ND 5.3 ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 12 ND ND 5.4 ND ND3-May-00 --- 5.0 ND ND --- --- ND 10 ND ND 6.3 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND 9.2 ND ND ND ND ND31-May-01 --- 5.0 ND ND --- --- ND 7.7 ND ND 5.8 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 8.1 5.2 ND 6.7 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 8.2 8.1 ND 8.0 ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND 5.1 7.7 ND 9.4 ND ND
14-May-03 --- 5.0 ND ND --- --- ND 8 5.4 7 13 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 7.3 5.7 7.5 9.2 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 7.3 7.2 9.3 9.6 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 7.5 6 8.5 10 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 8 9 11 9 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 58 6ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 6.1 8.5 5.3 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 5.3 5.3 11 7.6 ND ND
30-May-07 --- 1.0 --- 0.22 J --- --- 0.87 J 7.3 7.4 13 6.6 ND ND
NC 2L = 1 µg/L (10/23/07) 29-Nov-07 --- 1.0 --- 0.6 J --- --- 0.79 J 3.6 2.8 12 3.3 ND ND
29-May-08 0.25 1.0 --- 0.49 J --- --- 0.88 J 4.6 4.6 13.5 4.1 ND ND
6-Nov-08 0.25 1.0 --- 0.53 J --- --- 0.81 J 4.3 4.4 12 3.1 ND ND
3-Jun-09 0.25 1.0 --- 0.67 J --- ---1.2 4.5 5.4 15.3 4.1 ND ND18-Nov-09 0.25 1.0 --- 1.3 --- --- 0.81 J 4 5.6 14.9 3.3 ND ND
16-Jun-10 0.25 1.0 --- 0.59 J --- --- 0.81 J 5.9 5 14.3 2.4 ND ND1-Dec-10 0.25 1.0 --- ND ND --- 0.96 J 5 3 11.5 4 ND ND
1-Jun-11 0.25 1.0 --- 0.99 J ND --- 1 5.4 3.9 16.1 1.2 ND ND20-Dec-11 0.25 1.0 --- --- ND --- 1 J 4.2 3.1 12.9 D 2 ND ND
30-May-12 0.25 1.0 --- --- ND --- ND 4.4 2.8 14.7 2 ND ND5-Dec-12 0.25 1.0 --- --- ND --- 0.83 J 4.1 2.8 14.9 1.6 ND ND
12-Jun-13 0.25 1.0 --- --- ND ---1.5 3.5 4.2 15.9 2.9 ND ND28-Oct-13 0.25 1.0 --- --- ND --- 1 4.1 4.1 15.6 2 ND ND
6-May-14 0.25 1.0 --- --- ND ---1.6 3.9 3.8 17.2 2.1 ND ND
22-Oct-14 0.25 1.0 --- --- * ND 1.8 2.8 3.0 14.9 1.8 ND ND
21-May-15 0.25 1.0 --- --- ND ND 1.3 2.8 2.8 12.3 1.2 ND ND
8-Dec-15 0.25 1.0 --- --- * ND 1.6 2.2 2.3 13.8 1.7 ND ND
3-May-16 0.25 1.0 --- --- --- ND 1.8 2.8 2.9 14.1 1.5 ND ND
13-Dec-16 0.25 1.0 --- --- --- ND 1.7 2.3 2.8 14.5 1.4 ND ND
Bromodichloromethane 30-May-07 --- 1.0 --- ND --- --- 0.54 J ND 0.63 J ND ND ND ND
NC 2L = 0.56 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.18 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.18 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.18 1.0 --- ND ND --- ND ND ND ND ND ND ND20-Dec-11 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND5-Dec-12 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.18 1.0 --- --- ND --- ND ND ND ND ND ND 18.6028-Oct-13 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.18 1.0 --- --- ND --- ND ND ND ND ND ND ND22-Oct-14 0.18 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.18 1.0 --- --- --- ND ND ND ND ND ND ND ND
Bromomethane 12-Jun-13 0.29 10.0 --- --- ND --- 1.4 J ND ND ND ND ND ND
NC 2L = NE (10/23/07) 28-Oct-13 0.29 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.29 10.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.29 10.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.29 10.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 1 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
2-Butanone (MEK)20-Dec-11 0.96 100.0 --- --- ND --- ND ND ND 5.6
J
D ND ND ND
NC 2L = 4000 µg/L (10/23/07)30-May-12 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND5-Dec-12 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.96 100.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.96 100.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.96 100.0 --- --- --- ND ND ND ND ND ND ND ND
Carbon Disulfide 1-Nov-97 --- 1.0 8 NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 6.2 NI --- --- ND ND 8.9 ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND 6.7 9 ND 100 ND
18-Oct-99 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND3-May-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND31-May-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND14-May-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND6-May-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND27-May-05 --- 100.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 700 µg/L (10/23/07)29-Nov-07 --- 100.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 1.2 100.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 1.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 1.2 100.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND28-Oct-13 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 1.2 100.0 --- --- ND --- ND ND ND ND ND ND ND22-Oct-14 1.2 100.0 --- --- * ND ND ND ND ND ND ND 1.4 J
21-May-15 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND13-Dec-16 1.2 100.0 --- --- --- ND ND ND ND ND ND ND ND
Chlorobenzene 30-May-07 --- 3.0 --- ND --- --- ND 0.63 J 1.1 J 0.3 J 0.61 J ND ND
NC 2L = 50 µg/L (10/23/07) 29-Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.23 3.0 --- ND --- --- ND 0.48 J 0.7 J 0.32 J 0.59 J ND ND
6-Nov-08 0.23 3.0 --- ND --- --- ND 0.53 J 0.8 J 0.3 J 0.59 J ND ND
3-Jun-09 0.23 3.0 --- ND --- --- 0.26 J 0.47 J 0.73 J 0.39 J 0.76 J ND ND
18-Nov-09 0.23 3.0 --- ND --- --- ND 0.51 J 1.0 J 0.39 J 0.71 J ND ND
16-Jun-10 0.23 3.0 --- ND --- --- ND 0.9 J 1.2 J 0.41 J 0.79 J ND ND
1-Dec-10 0.23 3.0 --- ND ND --- ND 0.74 J 0.63 J ND 0.72 J ND ND
1-Jun-11 0.23 3.0 --- ND ND --- ND 0.8 J 1.0 J 0.5 J 0.4 J ND ND
20-Dec-11 0.23 3.0 --- --- ND --- ND 0.7 J 0.7 J ND 0.7 J ND ND
30-May-12 0.23 3.0 --- --- ND --- 0.24 J 0.73 J 0.7 J 0.47 J 0.7 J ND ND
5-Dec-12 0.23 3.0 --- --- ND --- ND 0.7 J 0.6 J 0.54 J 0.7 J ND ND
12-Jun-13 0.23 3.0 --- --- ND --- 0.88 J 0.57 J 0.86 J 0.57 J 0.65 J ND ND
28-Oct-13 0.23 3.0 --- --- ND --- 0.35 J 0.93 J 0.94 J 0.6 J 0.91 J ND ND
6-May-14 0.23 3.0 --- --- ND --- 0.7 J 0.93 J 0.9 J 0.79 J 0.91 J ND ND22-Oct-14 0.23 3.0 --- --- * ND 0.84 J 0.77 J 0.79 J 0.80 J 0.78 J ND ND
21-May-15 0.23 3.0 --- --- --- ND 0.67 J 0.84 J 0.74 J 0.72 J 0.58 J ND ND8-Dec-15 0.23 3.0 --- --- --- ND 1.5 J 0.61 J 0.73 J 0.86 J 0.82 J ND ND
3-May-16 0.23 3.0 --- --- --- ND 1.0 J 0.58 J 0.94 J 0.81 J 0.63 J ND ND13-Dec-16 0.23 3.0 --- --- --- ND 0.85 J 0.48 J 0.63 J 0.96 J 0.69 J ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 2 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Chloroethane 1-Sep-94 --- 10.0 ND NI NI NI ND 29 ND ND NI NI ---1-Jan-95 --- 10.0 --- NI NI NI ND 16 ND ND NI NI ---
1-Feb-95 --- 10.0 --- NI NI NI ND 32 ND ND NI NI ---1-Mar-95 --- 10.0 ND NI NI NI ND 34 11 ND NI NI ---
1-Aug-95 --- 10.0 ND NI --- --- ND 47 ND ND NI NI ---1-Jan-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 10.0 --- NI --- --- ND 28 ND ND NI NI ---1-May-96 --- 10.0 --- NI --- --- ND 34 11 ND NI NI ---
1-Oct-96 --- 10.0 --- NI --- --- ND 23 11.00 ND NI NI ---1-May-97 --- 5.0 3.8 J NI --- --- 15 33 11 ND NI NI ---
1-Nov-97 --- 1.0 3 NI --- --- 10 ND 7 ND NI NI ---
1-May-98 --- 10.0 ND NI --- --- ND 30 28 10 NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- --- ND 10.0 ND ND 17 ND ND
18-Oct-99 --- 10.0 ND ND --- --- ND 12 ND ND 21 ND ND
3-May-00 --- 10.0 ND ND --- --- ND ND 6.1 6.7 19 ND ND
7-Nov-00 --- 10.0 ND ND --- --- ND ND ND ND 13 ND ND
31-May-01 --- 10.0 ND ND --- --- ND ND ND ND 12 ND ND
7-Nov-01 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 10.0 12 ND --- --- ND ND ND ND 12 ND ND
14-Nov-02 --- 10.0 10 ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
6-May-04 --- 10.0 ND ND --- --- ND ND ND ND ND ND ND10-Nov-04 --- 10.0 ND ND --- --- ND ND 10 ND ND ND ND
27-May-05 --- 10.0 ND ND --- --- ND ND 10.0 ND ND ND ND3-Nov-05 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 10.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 10.0 --- ND --- --- ND ND 9.8 J 8.9 J ND ND NDNC 2L = 2,800 µg/L (10/23/07)29-Nov-07 --- 10.0 --- 1.4 J --- --- ND ND 4.3 J 5.7 JD 4.3 J ND ND
29-May-08 0.54 10.0 --- 1.2 J --- --- 1.1 J ND 1.5 J 6.0 J 2.6 J ND ND6-Nov-08 0.54 10.0 --- 2 J --- --- ND 0.9 J 3.5 J 5.6 J 4.3 J ND ND
3-Jun-09 0.54 10.0 --- 1.1 J --- --- ND ND ND 4.0 J 4.4 J ND ND
18-Nov-09 0.54 10.0 --- 3.1 J --- --- 0.8 J 0.6 J 5.5 J 5.1 J 3.5 J ND ND
NC 2L = 3,000 µg/L (01/01/10)16-Jun-10 0.54 10.0 --- 1.7 J --- --- 0.72 J 0.88 J 3.1 J 4.5 J 2.2 J ND ND
1-Dec-10 0.54 10.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.54 10.0 --- 1.5 J ND --- 0.71 J ND 2.7 J 3.8 J ND ND ND
20-Dec-11 0.54 10.0 --- --- ND --- 0.64 J ND 2.1 J ND 2.9 J ND ND
30-May-12 0.54 10.0 --- --- ND --- ND ND 1.5 J 2.4 J ND ND ND
5-Dec-12 0.54 10.0 --- --- ND --- ND ND 1.8 J 2.7 J 1.9 J ND ND
12-Jun-13 0.54 10.0 --- --- ND --- ND ND 0.63 J 0.84 J 1.5 J ND ND
28-Oct-13 0.54 10.0 --- --- ND --- ND ND 1.9 J 2.3 J ND ND ND
6-May-14 0.54 10.0 --- --- ND --- ND ND 1.6 J 1.7 J 1.3 J ND ND
22-Oct-14 0.54 10.0 --- --- * ND 0.75 J ND ND 2.1 J 1.6 J ND ND
21-May-15 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND3-May-16 0.54 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.54 10.0 --- --- --- ND ND ND 3.0 J 1.2 J 1.7 J ND ND
Chloromethane 18-Nov-09 0.11 1.0 --- ND --- --- ND ND ND 0.45 J ND ND NDNC 2L = 3 µg/L (01/01/10)16-Jun-10 0.11 1.0 --- ND --- --- 0.14 J ND ND 0.48 J ND ND ND
1-Dec-10 0.11 1.0 --- ND ND --- ND ND ND ND ND ND ND1-Jun-11 0.11 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND30-May-12 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND12-Jun-13 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND6-May-14 0.11 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.11 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.11 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.11 1.0 --- --- --- ND ND ND ND ND 0.16 B ND 0.17 J
Chloroform 30-May-07 --- 5.0 --- ND --- --- 0.92 B 1.2 B 0.99 B 1.4 B 1 B ND 0.98 J
NC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
6-Nov-08 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
18-Nov-09 0.14 5.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0.14 5.0 --- ND --- --- ND ND ND 0.2 B ND ND 0.29 J
1-Dec-10 0.14 5.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.14 5.0 --- ND ND --- ND ND ND 0.36 B ND ND 0.63 J
20-Dec-11 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND30-May-12 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.14 5.0 --- --- ND --- ND ND ND 0.14 J ND ND ND12-Jun-13 0.14 5.0 --- --- ND --- ND ND ND ND ND ND 46
28-Oct-13 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND6-May-14 0.14 5.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.14 5.0 --- --- * ND ND ND ND ND ND ND ND21-May-15 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND3-May-16 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.14 5.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 3 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Dibromochloromethane 30-May-07 --- 1.0 --- ND --- --- 1.7 ND ND ND 1.7 ND NDGWPS = 0.41 µg/L (10/23/07)Nov-07 --- 3.0 --- ND --- --- ND ND ND ND ND ND ND
May-08 0.21 3.0 --- ND --- --- ND ND ND ND ND ND NDNov-08 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
Jun-09 0.21 3.0 --- ND --- --- ND ND ND ND ND ND NDNov-09 0.21 3.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 0.4 µg/L (01/01/10)Jun-10 0.21 3.0 --- ND --- --- ND ND ND ND ND ND NDDec-10 0.21 3.0 --- ND ND --- ND ND ND ND ND ND ND
Jun-11 0.21 3.0 --- ND ND --- ND ND ND ND ND ND NDDec-11 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
May-12 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.21 3.0 --- --- ND --- ND ND ND ND ND ND 9.2
28-Oct-13 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.21 3.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.21 3.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.21 3.0 --- --- --- ND ND ND ND ND ND ND ND
1,2-Dichlorobenzene 3-Jun-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND
NC 2L = 24 µg/L (10/23/07)18-Nov-09 0.3 5.0 --- ND --- --- ND ND ND 0.4 J ND ND ND
NC 2L = 20 µg/L (01/01/10)16-Jun-10 0.3 5.0 --- ND --- --- ND 0.39 J ND 0.4 J ND ND ND1-Dec-10 0.3 5.0 --- ND ND --- ND 0.49 J ND 0.5 J ND ND ND
1-Jun-11 0.3 5.0 --- ND ND --- ND 0.5 J ND 0.5 J ND ND ND20-Dec-11 0.3 5.0 --- --- ND --- ND 0.4 J ND ND ND ND ND
30-May-12 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND5-Dec-12 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND
12-Jun-13 0.3 5.0 --- --- ND --- ND 0.4 J ND 0.6 J ND ND ND28-Oct-13 0.3 5.0 --- --- ND --- ND 0.39 J ND 0.54 J ND ND ND
6-May-14 0.3 5.0 --- --- ND --- ND 0.46 J ND 0.55 J ND ND ND22-Oct-14 0.3 5.0 --- --- * ND ND 0.45 J ND ND ND ND ND
21-May-15 0.3 5.0 --- --- --- ND ND 0.45 J ND 0.58 J ND ND ND
8-Dec-15 0.3 5.0 --- --- --- ND ND 0.39 J ND 0.45 J ND ND ND
3-May-16 0.3 5.0 --- --- --- ND ND 0.42 J ND 0.54 J ND ND ND
13-Dec-16 0.3 5.0 --- --- --- ND ND 0.32 J ND 0.67 J ND ND ND
1,4-Dichlorobenzene 1-Sep-94 --- 5.0 ND NI NI NI ND 6.5 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI ---8 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 9.8 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12.0 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 14.0 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 20 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 19.0 ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 18 ND ND NI NI ---1-Oct-96 --- 5.0 --- NI --- --- ND 16.0 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND 14.0 ND ND NI NI ---1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---24-Nov-98 --- 2.0 ND NI --- --- ND 4 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND 7.2 ND ND 6.5 ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND 12 ND ND 5.7 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 14 ND ND 5.2 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 17 ND ND 6.7 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 20.0 ND ND 6.0 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 21 ND ND 6.0 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 16.5 ND ND 5.4 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 16 ND ND 7.2 ND ND
30-May-07 --- 1.0 --- ND --- --- ND 23.0 5.2 4.4 7.2 ND ND
NC 2L = 1.4 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND 11 2.3 4.5 5.2 ND ND
29-May-08 0.33 1.0 --- ND --- --- ND 13.5 3.1 5.2 6.0 ND ND
6-Nov-08 0.33 1.0 --- ND --- --- ND 9.7 Q 3.7 4.3 5.5 ND ND
3-Jun-09 0.33 1.0 --- ND --- --- ND 14.3 4.2 7.3 8.0 ND ND
18-Nov-09 0.33 1.0 --- ND --- --- ND 12.2 4.5 6.4 6.8 ND 0.55 JNC 2L = 6 µg/L (01/01/10)16-Jun-10 0.33 1.0 --- ND --- --- ND 19.8 4.7 6.8 5.7 ND ND
1-Dec-10 0.33 1.0 --- ND ND --- 0.43 J 18.5 3.5 7.5 7.5 ND ND1-Jun-11 0.33 1.0 --- ND ND --- ND 19.2 4.5 8.4 3.4 ND ND
20-Dec-11 0.33 1.0 --- --- ND --- 0.37 J 13.9 4 7.8 D 6.5 ND ND30-May-12 0.33 1.0 --- --- ND --- ND 16.4 4.2 9.9 7.0 ND ND
5-Dec-12 0.33 1.0 --- --- ND --- ND 15 4.4 9.7 6.0 ND ND12-Jun-13 0.33 1.0 --- --- ND --- 0.48 J 12.4 4.9 9.7 7.5 ND ND
28-Oct-13 0.33 1.0 --- --- 0.63 J --- 0.45 J 16.7 5 10.1 8.3 ND ND6-May-14 0.33 1.0 --- --- ND --- 0.63 J 18 5.2 12.3 8.9 ND ND
22-Oct-14 0.33 1.0 --- --- * ND 0.73 J 16.1 4.8 11.9 7.5 ND ND21-May-15 0.33 1.0 --- --- --- ND 0.7 J 17.1 5.0 12.0 7.1 ND ND
8-Dec-15 0.33 1.0 --- --- --- ND 0.98 J 12.6 4.8 13.2 9.1 ND ND
3-May-16 0.33 1.0 --- --- --- ND 0.93 J 14.2 6.0 15.0 6.6 ND ND
13-Dec-16 0.33 1.0 --- --- --- ND 0.89 J 10.5 4.7 13.9 7.2 ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 4 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Dichlorodifluoromethane 1-Aug-95 --- 5.0 ND NI --- --- ND 26 ND 22 NI NI ---#1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Feb-96 --- 10.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 10.0 --- NI --- --- ND 35 25 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-May-97 --- 5.0 6.4 NI --- --- ND 16 20.0 42.0 NI NI ---
1-Nov-97 --- 5.0 14 NI --- --- ND ND 31.0 90.0 NI NI ---24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 10.0 ND ND --- --- ND ND 19.0 27.0 ND ND ND18-Oct-99 --- 5.0 ND ND --- --- --- 14.0 50.0 130.0 25 ND ND
3-May-00 --- 5.0 --- --- --- --- --- ND 16.00 36.0 8.9 --- ND
7-Nov-00 --- 5.0 ND --- --- --- ND ND 9.40 30.0 7.9 --- ND
31-May-01 --- 5.0 ND --- --- --- ND ND 13 25 6.2 --- ND
7-Nov-01 --- 5.0 ND --- --- --- ND 5.5 ND 34 12 --- ND
22-May-02 --- 5.0 ND --- --- --- ND 5 15 24 11 --- ND
14-Nov-02 --- 5.0 ND --- --- --- ND ND ND 20 ND --- ND
14-May-03 --- 5.0 ND --- --- --- ND ND 8.7 12 ND --- ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 6.3 10 ND ND ND
6-May-04 --- 5.0 ND --- --- --- ND ND ND 9.2 ND --- ND
10-Nov-04 --- 5.0 ND --- --- --- ND ND 7.6 10 ND ND ND
27-May-05 --- 5.0 ND --- --- --- ND ND 14 22 ND --- ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 9 12 ND ND ND
25-May-06 --- 5.0 --- --- --- --- ND ND ND 5.4 ND --- ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.2 6.6 ND ND ND30-May-07 --- 5.0 --- --- --- --- ND ND 7.1 7.6 ND --- ---
NC 2L = 1,400 µg/L (10/23/07)29-Nov-07 --- 5.0 --- ND --- --- ND ND 1.1 J 1.8 JD ND ND ND29-May-08 0.21 1.0 --- --- --- --- ND 0.35 J 2.9 3.6 ND --- ND
6-Nov-08 0.21 5.0 --- 0.62 J --- --- ND 0.33 J 1.9 J 2.2 J 0.69 J ND ND3-Jun-09 0.21 5.0 --- 0.45 J --- --- 0.96 J ND 2.5 J 1.9 J 0.72 J ND ND
18-Nov-09 0.21 5.0 --- ND --- --- ND ND 1.2 J 1.9 J 0.47 J ND NDNC 2L = 1,000 µg/L (01/01/10)16-Jun-10 0.21 5.0 --- ND --- --- ND ND 0.81 J 1.4 J ND ND ND
1-Dec-10 0.21 5.0 --- 0.26 J ND --- ND ND 0.69 J 1.1 J 0.55 J ND ND1-Jun-11 0.21 5.0 --- 0.42 J ND --- ND ND ND 1.2 J ND ND ND
20-Dec-11 0.21 5.0 --- --- ND --- ND ND ND 0.76
J
D ND ND ND
30-May-12 0.21 5.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.21 5.0 --- --- ND --- ND ND ND ND ND --- ND
12-Jun-13 0.21 5.0 --- --- ND --- 0.34 J ND ND ND ND ND ND
28-Oct-13 0.21 5.0 --- --- ND --- ND ND ND 1.1 J ND ND ND
6-May-14 0.21 5.0 --- --- ND --- ND ND ND ND ND --- ND
22-Oct-14 0.21 5.0 --- --- * ND ND ND ND ND ND --- ND
21-May-15 0.21 5.0 --- --- --- ND ND ND ND ND ND --- ND
8-Dec-15 0.21 5.0 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 0.21 5.0 --- --- --- ND ND ND ND 0.54 J 0.26 J --- ND
13-Dec-16 0.21 5.0 --- --- --- ND ND ND ND 0.57 J ND --- ND
1,1-Dichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 50 7.5 ND NI NI ---1-Jan-95 --- 5.0 ---NI NI NI ND 35 33 ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 66 34 ND NI NI ---1-Mar-95 --- 5.0 ND NI NI NI ND 72 34 ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 96 ND ND NI NI ---1-Jan-96 --- 5.0 --- NI --- --- 13 120 54 ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- 11 ND ND ND NI NI ---1-May-96 --- 5.0 --- NI --- --- 12 110 68 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- 17 140 86 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- 39 170 100 4 J NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- 22 200 69.0 8 NI NI ---
1-May-98 --- 5.0 5.5 NI --- --- 22.0 250.0 250.0 45.0 NI NI ---
24-Nov-98 --- 2.0 3.8 NI --- --- 14 150.0 57 19.9 NI NI ---
10-May-99 --- 5.0 7.7 ND --- --- 9.7 180.0 64.0 30.0 120 ND ND
18-Oct-99 --- 5.0 11.0 J ND --- --- 9.3 J 200 59 30.0 120 ND ND
3-May-00 --- 5.0 9.3 J ND --- --- 6.2 J 120.0 61.0 38.0 120 ND ND
7-Nov-00 --- 5.0 9.5 ND --- --- 5.0 110.0 60.0 44.0 92 ND ND
31-May-01 --- 5.0 7.9 6 --- --- ND 80.0 75.0 45.0 79 ND ND
7-Nov-01 --- 5.0 14.0 5.3 --- --- ND 84.0 100.0 42.0 95 ND ND
22-May-02 --- 5.0 19.0 ND --- --- ND 75.0 110.0 57 100 ND ND
14-Nov-02 --- 5.0 21.0 ND --- --- ND 41.0 90.0 50.0 82 ND ND
14-May-03 --- 5.0 27.0 ND --- --- ND 48.0 60.0 69.0 82 ND ND20-Nov-03 --- 5.0 25.0 ND --- --- ND 34.0 48.0 62.0 59 ND ND
6-May-04 --- 5.0 33.0 ND --- --- ND 33 58.0 72.0 58 ND ND10-Nov-04 --- 5.0 38.0 ND --- --- ND 22.0 37.0 50.0 42 ND ND
27-May-05 --- 5.0 68.0 ND --- --- ND 25 48 66 44.0 ND ND3-Nov-05 --- 5.0 --- ND --- --- ND 18.0 34 54.0 38 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 10.9 27 37.6 25.3 ND ND2-Nov-06 --- 5.0 --- ND --- --- ND 12 34 47 33 ND ND
30-May-07 --- 5.0 --- 5.3 --- --- 3.3 J 16 48 59 41 ND NDNC 2L = 70 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 6.1 --- --- 2.2 J 7.7 39 44 34 ND ND
29-May-08 0.32 5.0 --- 1.7 J --- --- 1.7 J 8.7 38.8 ND 29.7 ND ND
6-Nov-08 0.32 5.0 --- 5.7 --- --- 1.9 J 8.1 34.6 52.3 26.2 ND ND
3-Jun-09 0.32 5.0 --- 6.3 --- --- 1.3 J 8.2 47.8 53.1 32 ND ND
18-Nov-09 0.32 5.0 --- 10.8 --- --- 1.2 J 6.7 41.9 52.0 29.4 ND ND
NC 2L = 6 µg/L (01/01/10)16-Jun-10 0.32 5.0 --- 3.9 J --- --- 1.2 J 5.7 35.7 43.1 32.1 ND ND
1-Dec-10 0.32 5.0 ---6.8 ND --- 1.7 J 5.4 41.3 37.9 16.9 ND ND
1-Jun-11 0.32 5.0 ---9.3 ND --- 2 J 6.8 45.5 53.3 19.1 ND ND
20-Dec-11 0.32 5.0 --- --- ND --- 1.9 J 5.1 39.7 39.7 D 26.2 ND ND
30-May-12 0.32 5.0 --- --- ND --- 1.5 J 5.9 38.2 45.8 24.1 ND ND
5-Dec-12 0.32 5.0 --- --- ND --- 1.7 J 4.6 J 39.3 39.3 26.5 ND ND
12-Jun-13 0.32 5.0 --- --- ND --- 0.73 J 5.3 37.1 41.6 21.4 ND ND
28-Oct-13 0.32 5.0 --- --- ND --- 1 J 4.9 J 43.2 41.8 26.2 ND ND
6-May-14 0.32 5.0 --- --- ND --- 1 J 4 J 43.4 39.5 21.5 ND ND
22-Oct-14 0.32 5.0 --- --- * ND 1.3 J 3.6 J 34.4 33.2 25.3 ND ND
21-May-15 0.32 5.0 --- --- --- ND 0.75 J 2.8 J 26.7 23.1 17.3 ND ND
8-Dec-15 0.32 5.0 --- --- --- ND 0.95 J 3.2 J 31.7 33.7 10.3 ND ND
3-May-16 0.32 5.0 --- --- --- ND 1.3 J 3.4 J 23.4 28.4 14.8 ND ND
13-Dec-16 0.32 5.0 --- --- --- ND 1.4 J 3.0 J 27.4 26.4 22.1 ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 5 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
1,2-Dichloroethane 3-Nov-05 --- 5.0 --- ND --- --- ND 13 ND ND ND ND ND25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND30-May-07 --- 1.0 --- ND --- --- ND 2.4 ND 1.6 ND ND ND
NC 2L = 0.38 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND29-May-08 0.12 1.0 --- ND --- --- ND 1.2 0.64 J 1.5 1.1 ND ND
6-Nov-08 0.12 1.0 --- ND --- --- ND 0.65 B 0.27 B 1.8 B 0.46 B ND 1 J3-Jun-09 0.12 1.0 --- ND --- --- ND 0.78 J 0.8 J 1.9 0.98 J ND ND
18-Nov-09 0.12 1.0 --- ND --- --- ND 0.98 J 1.0 1.8 0.97 J ND NDNC 2L = 0.4 µg/L (01/01/10)16-Jun-10 0.12 1.0 --- ND --- --- ND 1.2 1.1 1.8 1.0 ND ND
1-Dec-10 0.12 1.0 --- ND ND --- ND 0.94 J 0.58 J 1.5 0.18 J ND ND
1-Jun-11 0.12 1.0 --- ND ND --- ND ND 1.1 2.1 1.0 ND ND
20-Dec-11 0.12 1.0 --- --- ND --- ND 0.8 J 0.92 J 1.8 J 1.0 ND ND
30-May-12 0.12 1.0 --- --- ND --- ND 0.75 J 0.97 J 2 1 ND ND
5-Dec-12 0.12 1.0 ------ND --- ND 0.7 J 0.8 J 1.7 1.3 ND ND
12-Jun-13 0.12 1.0 --- --- ND --- ND 0.6 J 1.3 1.7 1.0 ND ND
28-Oct-13 0.12 1.0 --- --- ND --- ND 0.9 J 1.4 1.7 1.4 ND ND
6-May-14 0.12 1.0 --- --- ND --- ND 0.8 J 1.2 1.6 1.2 ND ND
22-Oct-14 0.12 1.0 --- --- * ND ND 0.51 J 0.85 J 1.5 1.2 ND ND
21-May-15 0.12 1.0 --- --- --- ND ND ND 0.71 J ND ND ND ND
8-Dec-15 0.24 1.0 --- --- --- ND ND 0.65 J ND 1.3 1.3 ND ND
3-May-16 0.24 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.24 1.0 --- --- --- ND ND 0.48 J 1.1 1.3 1.2 ND ND
1,1-Dichloroethene 1-May-97 --- 5.0 ND NI --- ---ND 3 J ND 4 J NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND31-May-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 5.0 --- ND --- --- ND ND 0.93 J 1.8 J 0.42 J ND ND
NC 2L = 7 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- ND ND 0.8 J 1.2 JD 0.59 J ND ND
29-May-08 0.6 1.0 --- ND --- --- ND ND 0.75 J 1.3 ND ND ND
6-Nov-08 0.6 5.0 --- ND --- --- ND ND 0.64 J 1.1 J ND ND ND
3-Jun-09 0.6 5.0 --- ND --- --- ND ND 0.95 J 1.1 J ND ND ND18-Nov-09 0.6 5.0 --- ND --- --- ND ND 0.78 J 1.1 J ND ND ND
16-Jun-10 0.6 5.0 --- ND --- --- 0.98 J ND 0.68 J 1.2 J ND ND ND1-Dec-10 0.6 5.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.6 5.0 --- ND ND --- ND ND 0.68 J 0.82 J ND ND ND20-Dec-11 0.6 5.0 --- --- ND --- ND ND 0.59 J ND ND ND ND
30-May-12 0.6 5.0 --- --- ND --- ND ND 0.62 J 0.58 J ND ND ND5-Dec-12 0.6 5.0 --- --- ND --- ND ND 0.66 J 0.58 J ND ND ND
NC 2L = 350 µg/L (04/01/2013)12-Jun-13 0.6 5.0 --- --- ND --- ND ND ND ND ND ND ND28-Oct-13 0.6 5.0 --- --- ND --- ND ND 0.6 J ND ND ND ND
6-May-14 0.6 5.0 --- --- ND --- ND ND 0.59 J ND ND ND ND22-Oct-14 0.6 5.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.6 5.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 6 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
cis-1,2-Dichloroethene 1-Feb-96 --- 5.0 --- NI --- --- 11 89 35 ND NI NI ---1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-May-97 --- 5.0 ND NI --- --- ND 2.1 J ND ND NI NI ---
1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND 2.8 ND ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND ND ND ND 7 ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 6.3 ND ND 14 ND ND3-May-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND 13 ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND ND ND 14 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 5.9 6.5 ND 18 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 8 11 ND 24 ND ND
14-Nov-02 --- 5.0 ND ND --- --- 5 7 13.0 ND 28 ND ND
14-May-03 --- 5.0 ND ND --- --- 7 11 8 5 36 ND ND
20-Nov-03 --- 5.0 ND ND --- --- 5 14 13 6 27 ND ND
6-May-04 --- 5.0 ND ND --- --- ND 16 17 7.2 32 ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND 14 13 5.8 29 ND ND
27-May-05 --- 5.0 ND ND --- --- ND 16 23 8 23 ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND 5 6 ND 9 ND ND
25-May-06 --- 5.0 --- ND --- --- ND 8.2 9.3 5.2 7.7 ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND 16 12.0 12 17 ND ND
30-May-07 --- 5.0 --- ND --- --- 4.9 J 20 21.0 17 15 ND NDNC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 5.0 --- ND --- --- 2.9 J 8.6 7.2 13 9.1 ND ND
29-May-08 0.19 5.0 --- ND --- --- 2.8 J 13.4 10.9 18.4 10.4 ND ND6-Nov-08 0.19 5.0 --- 0.5 J --- --- 2.8 J 12.7 10 20.4 7.6 ND ND
3-Jun-09 0.19 5.0 --- 0.71 J --- --- 2.5 J 13.1 11.9 25.3 10.4 ND ND18-Nov-09 0.19 5.0 --- 2.8 B --- --- 2.5 B 12.2 B 20 25.9 10.8 B ND 2.6 J
16-Jun-10 0.19 5.0 --- 1.7 J --- --- 2.3 J 14.8 15.6 22.2 9.7 ND ND1-Dec-10 0.19 5.0 --- 0.66 J ND --- 3.1 J 11.3 9.2 19.7 7.1 ND ND
1-Jun-11 0.19 5.0 --- 0.89 J ND --- 3.7 J 14.5 13.8 28.8 5.7 ND ND20-Dec-11 0.19 5.0 --- --- ND --- 3.7 J 9.5 9.7 21.4 D 6.5 ND ND
30-May-12 0.19 5.0 --- --- ND --- 3.1 J 11.8 11.2 26.5 6.8 ND ND
5-Dec-12 0.19 5.0 --- --- ND --- 3.3 J 9.1 9.4 25.4 6.6 ND ND
12-Jun-13 0.19 5.0 --- --- ND --- 2.5 J 9 12.8 26.2 6.2 ND ND
28-Oct-13 0.19 5.0 --- --- ND --- 3 J 11.2 14 29.1 7.7 ND ND
6-May-14 0.19 5.0 --- --- ND --- 3.4 J 9.5 13 27.1 7.7 ND ND
22-Oct-14 0.19 5.0 --- --- * ND 4.3 J 8.0 10.1 25 7.1 ND ND
21-May-15 0.19 5.0 --- --- --- ND 2.8 J 6.7 7.6 17.0 4.2 J ND ND
8-Dec-15 0.19 5.0 --- --- --- ND 3.9 J 6.9 9.9 25.8 4.4 J ND ND
3-May-16 0.19 5.0 --- --- --- ND 4.3 J 5.9 9.6 23.9 4.6 J ND ND
13-Dec-16 0.19 5.0 --- --- --- ND 5.1 5.7 9.8 25.7 6.1 ND ND
trans-1,2-Dichloroethene 5-Dec-13 0.49 5.0 --- --- ND --- ND ND 0.67 J 0.59 J ND ND ND
NC 2L = 100 µg/L (10/23/07)12-Jun-13 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.49 5.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.49 5.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND3-May-16 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.49 5.0 --- --- --- ND ND ND ND ND ND ND ND
1,2-Dichloropropane 30-May-07 --- 1.0 --- ND --- --- ND ND ND 2.2 2.5 ND NDNC 2L = 0.51 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND 0.7 J ND ND
29-May-08 0.27 1.0 --- ND --- --- ND ND 0.4 J 0.72 J 0.85 J ND ND6-Nov-08 0.27 1.0 --- ND --- --- ND 0.32 J 0.5 J 0.68 J 0.67 J ND ND
3-Jun-09 0.27 1.0 --- ND --- --- ND ND ND 0.88 J 0.9 J ND ND18-Nov-09 0.27 1.0 --- ND --- --- ND ND 0.5 J 0.7 J 0.84 J ND ND
NC 2L = 0.6 µg/L (01/01/10)16-Jun-10 0.27 1.0 --- ND --- --- ND ND 0.5 J 0.7 J 0.67 J ND ND
1-Dec-10 0.27 1.0 --- ND ND --- ND 0.33 J 0.29 J 0.55 J 0.72 J ND ND
1-Jun-11 0.27 1.0 --- ND ND --- ND ND ND 0.88 J ND ND ND
20-Dec-11 0.27 1.0 --- --- ND --- ND ND 0.35 J 0.57 JD 0.48 J ND ND
30-May-12 0.27 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.27 1.0 --- --- ND --- ND ND 0.37 J 0.65 J 0.59 J ND ND
12-Jun-13 0.27 1.0 --- --- ND --- ND ND 0.35 J 0.6 J 0.59 J ND ND
28-Oct-13 0.27 1.0 --- --- ND --- ND ND ND ND 0.47 J ND ND
6-May-14 0.27 1.0 --- --- ND --- ND ND 0.33 J 0.54 J 0.58 J ND ND
22-Oct-14 0.27 1.0 --- --- * ND ND ND ND ND 0.49 J ND ND
21-May-15 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.27 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 7 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Ethylbenzene 1-May-98 --- 5.0 ND NI --- --- ND ND 6.4 ND NI NI ---24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND 6.4 ND ND ND ND7-Nov-01 --- 5.0 ND ND --- --- ND ND 5 ND ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND14-Nov-02 --- 5.0 ND ND --- --- ND ND 14 ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND 11 8.8 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 15 8.3 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 21 7.6 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND 11.0 ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND 23 8 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 14 9 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND 17 5.8 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND 8.4 ND ND ND ND
30-May-07 --- 1.0 --- ND --- --- ND ND 18 4.1 ND ND ND
NC 2L = 550 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND 0.54 J 2 ND ND ND
29-May-08 0.3 1.0 --- ND --- --- ND ND 2.6 2.6 ND ND ND
6-Nov-08 0.3 1.0 --- ND --- --- ND ND 2 3.5 ND ND ND
3-Jun-09 0.3 1.0 --- ND --- --- ND ND 6 8 ND ND ND
18-Nov-09 0.3 1.0 --- ND --- --- ND ND 3.3 4.1 ND ND NDNC 2L = 600 µg/L (01/01/10)16-Jun-10 0.3 1.0 --- ND --- --- ND ND 6.5 5 ND ND ND
1-Dec-10 0.3 1.0 --- ND ND --- ND ND 2.9 3 ND ND ND1-Jun-11 0.3 1.0 --- ND ND --- ND ND 1.3 3 ND ND ND
20-Dec-11 0.3 1.0 --- --- ND --- ND ND 0.59 J 1.2 JD ND ND ND30-May-12 0.3 1.0 --- --- ND --- ND 0.38 J 0.77 J 7 ND ND ND
5-Dec-12 0.3 1.0 --- --- ND --- ND 0.32 J 1.1 2.1 ND ND ND12-Jun-13 0.3 1.0 --- --- ND --- ND 0.4 J 2.3 5.1 ND ND ND
28-Oct-13 0.3 1.0 --- --- ND --- ND 0.35 J 1 5.9 ND ND ND6-May-14 0.3 1.0 --- --- ND --- ND ND ND 1.6 ND ND ND
22-Oct-14 0.3 1.0 --- --- * ND ND ND 0.32 J 1.5 ND ND ND
21-May-15 0.3 1.0 --- --- --- ND ND ND 0.86 J 1.3 ND ND ND
8-Dec-15 0.3 1.0 --- --- --- ND ND ND 1.2 2.7 ND ND ND
3-May-16 0.3 1.0 --- --- --- ND ND ND 1.4 4.6 ND ND ND
13-Dec-16 0.3 1.0 --- --- --- ND ND ND ND 3.0 ND ND ND
Methylene Chloride 1-Sep-94 --- 5.0 ND NI NI NI ND 360 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI ---430 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 290 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 560 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 610 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 810 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 380 ND ND NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-May-96 --- 5.0 --- NI --- --- ND 330 5.3 ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ---68 19 ND NI NI ---1-May-97 --- 5.0 ND NI --- --- 2.4 J 280 11 ND NI NI ---
1-Nov-97 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---1-May-98 --- 5.0 ND NI --- --- ND 420 450 61 NI NI ---
24-Nov-98 --- 10.0 ND NI --- --- ND 92.5 B ND ND NI NI ---10-May-99 --- 5.0 ND ND --- --- ND 120.00 ND 37 ND ND ND
18-Oct-99 --- 10.0 ND ND --- --- ND 78.00 B ND 34 B ND ND 213-May-00 --- 10.0 ND ND --- --- ND 98 ND 68 ND ND ND
7-Nov-00 --- 10.0 ND ND --- --- ND ND ND 56 ND ND ND31-May-01 --- 10.0 ND ND --- --- ND 18 ND 96 ND ND ND
7-Nov-01 --- 10.0 ND ND --- --- ND ND ND 88 ND ND ND
22-May-02 --- 10.0 ND ND --- --- ND ND 11 130 ND ND ND
14-Nov-02 --- 10.0 ND ND --- --- ND ND 20 130 ND ND ND
14-May-03 --- 10.0 ND ND --- --- ND 18 ND 320 ND ND ND
20-Nov-03 --- 10.0 ND ND --- --- ND ND ND 570 ND ND ND
6-May-04 --- 10.0 12 ND --- --- ND ND 10 420 ND ND ND
10-Nov-04 --- 10.0 12 ND --- --- ND ND ND 360 ND ND ND
27-May-05 --- 10.0 40 ND --- --- ND ND ND 480 ND ND ND
3-Nov-05 --- 10.0 --- ND --- --- ND ND ND 510 ND ND ND
25-May-06 --- 10.0 --- ND --- --- ND ND ND 375 ND ND ND
2-Nov-06 --- 10.0 --- ND --- --- ND ND ND 210 ND ND ND
30-May-07 --- 1.0 --- 2.3 B --- --- ND ND ND 310 ND ND 3.2
NC 2L = 4.6 µg/L (10/23/07)29-Nov-07 --- 1.0 ---4.8 --- --- 0.89 J ND ND 220 ND ND ND
29-May-08 0.97 2.0 --- 2.2 B --- --- ND ND ND 285 ND ND 1.5 J
6-Nov-08 0.97 2.0 --- 2.6 B --- --- 1.1 B ND ND 831 ND ND 3.2 J
3-Jun-09 0.97 2.0 --- ND --- --- ND ND ND 278 ND ND 19.118-Nov-09 0.97 2.0 ---11.1 --- --- ND ND ND 241 ND ND ND
NC 2L = 5 µg/L (01/01/10)16-Jun-10 0.97 2.0 --- ND --- --- ND ND ND 234 ND ND ND1-Dec-10 0.97 1.0 --- 2.2 ND --- ND ND ND 174 ND ND ND
1-Jun-11 0.97 1.0 --- 2.3 ND --- ND ND ND 232 ND ND ND20-Dec-11 0.97 1.0 --- --- ND --- ND ND ND 196 D ND ND 1.9
30-May-12 0.97 1.0 --- --- ND --- ND ND ND 185 ND ND ND5-Dec-12 0.97 1.0 --- --- ND --- ND ND ND 174 ND ND ND
12-Jun-13 0.97 1.0 --- --- ND --- ND ND ND 77.9 ND ND ND28-Oct-13 0.97 1.0 --- --- ND --- ND ND ND 128 ND ND ND
6-May-14 0.97 1.0 --- --- ND --- ND ND ND 154 ND ND 2.222-Oct-14 0.97 1.0 --- --- * ND ND ND ND 130 ND ND ND
21-May-15 0.97 1.0 --- --- --- ND ND ND ND 82.8 ND ND 1.7
8-Dec-15 0.97 1.0 --- --- --- ND ND ND ND 113 ND ND 2.0
3-May-16 0.97 1.0 --- --- --- ND ND ND ND 30.5 ND ND ND
13-Dec-16 0.97 1.0 --- --- --- ND ND ND ND 41.8 ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 8 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Iodomethane 29-May-08 0 10.0 --- 0.35 J --- --- ND ND ND ND ND ND NDNC 2L = NE (10/23/07) 6-Nov-08 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
3-Jun-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND18-Nov-09 0 10.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0 10.0 --- ND --- --- ND ND ND ND ND ND ND1-Dec-10 0 10.0 --- ND ND --- 5 J ND ND ND ND ND ND
1-Jun-11 0.32 10.0 --- ND ND --- ND ND ND ND ND ND ND20-Dec-11 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND5-Dec-12 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.32 10.0 --- --- ND --- 8.6 J ND ND ND ND ND ND
28-Oct-13 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.32 10.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.32 10.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.32 10.0 --- --- --- ND ND ND ND ND ND ND ND
Styrene 3-Jun-09 0.26 1.0 --- ND --- --- ND 2 ND ND ND ND ND
NC 2L = 100 µg/L (10/23/07) 18-Nov-09 0.26 1.0 --- ND --- --- ND ND ND ND ND ND ND
NC 2L = 70 µg/L (01/01/10) 16-Jun-10 0.26 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.26 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.26 1.0 --- ND ND --- ND ND ND ND ND ND ND20-Dec-11 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND5-Dec-12 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND28-Oct-13 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.26 1.0 --- --- ND --- ND ND ND ND ND ND ND22-Oct-14 0.26 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.26 1.0 --- --- --- ND ND ND ND ND ND ND ND
Tetrachloroethene 1-May-97 --- 5.0 5.6 NI --- --- ND 6.3 3.6 J ND NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 6.7 NI --- --- ND 7.8 3.2 ND NI NI ---
10-May-99 --- 5.0 8.5 ND --- --- ND 9.3 ND ND ND ND ND
18-Oct-99 --- 5.0 5.3 ND --- --- ND 7.3 ND ND ND ND ND
3-May-00 --- 5.0 7 ND --- --- ND 6.4 ND ND ND ND ND
7-Nov-00 --- 5.0 6.6 ND --- --- ND 5.3 ND ND ND ND ND
31-May-01 --- 5.0 9.6 ND --- --- ND 7.1 ND ND ND ND ND
7-Nov-01 --- 5.0 9.5 ND --- --- ND 5.6 5 ND ND ND ND
22-May-02 --- 5.0 10 ND --- --- ND 5.7 5.5 ND ND ND ND
14-Nov-02 --- 5.0 8 ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 10 ND --- --- ND 5.5 ND ND ND ND ND20-Nov-03 --- 5.0 8.8 ND --- --- ND 6.6 ND ND ND ND ND
6-May-04 --- 5.0 8.9 ND --- --- ND ND ND ND ND ND ND10-Nov-04 --- 5.0 12 ND --- --- ND ND ND 5.1 ND ND ND
27-May-05 --- 5.0 10 ND --- --- ND ND ND ND ND ND ND3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 12 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 5.8 ND ND ND
30-May-07 --- 1.0 ---1.6 --- --- ND 0.44 J 1.6 5.9 ND ND NDNC 2L = 0.7 µg/L (10/23/07) 29-Nov-07 --- 1.0 ---1.7 --- --- ND ND 1.1 4.9 ND ND ND
29-May-08 0.46 1.0 ---2.2 --- --- ND ND 1.1 6.6 ND ND ND6-Nov-08 0.46 1.0 ---2.7 --- --- ND ND 1.3 6.2 ND ND ND
3-Jun-09 0.46 1.0 ---2.1 --- --- ND ND 0.7 J 7.5 ND ND ND
18-Nov-09 0.46 1.0 ---2.6 --- --- ND ND 0.49 J 6.3 ND ND ND
16-Jun-10 0.46 1.0 ---1.2 --- --- ND ND 0.46 J 6.7 ND ND ND
1-Dec-10 0.46 1.0 ---3 ND --- ND ND ND 5.8 ND ND ND
1-Jun-11 0.46 1.0 ---3.6 ND --- ND ND ND 7.7 ND ND ND
20-Dec-11 0.46 1.0 --- --- ND --- ND 0.59 B 0.7 B 5.7 D ND ND 1 J
30-May-12 0.46 1.0 --- --- ND --- ND ND ND 7.7 ND ND ND
5-Dec-12 0.46 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND
12-Jun-13 0.46 1.0 --- --- ND --- ND ND ND 6.4 ND ND ND
28-Oct-13 0.46 1.0 --- --- ND --- ND ND ND 5.7 ND ND ND
6-May-14 0.46 1.0 --- --- ND --- ND ND ND 7.3 ND ND ND
22-Oct-14 0.46 1.0 --- --- * ND ND ND ND 7.0 ND ND ND
21-May-15 0.46 1.0 --- --- --- ND ND ND ND 6.4 ND ND ND
8-Dec-15 0.46 1.0 --- --- --- ND ND ND ND 5.6 ND ND ND3-May-16 0.46 1.0 --- --- --- ND ND ND ND 7.6 ND ND ND
13-Dec-16 0.46 1.0 --- --- --- ND ND ND ND 5.9 ND ND ND
Tetrahydrofuran 1-Dec-10 3.1 10.0 --- ND ND --- ND ND ND 10.1 ND ND NDNC 2L = NE (01/01/10)1-Jun-11 3.1 10.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 3.1 10.0 --- --- ND --- ND ND ND 9.3 JD ND ND ND30-May-12 3.1 10.0 --- --- ND --- ND ND ND 8.9 J ND ND ND
5-Dec-12 3.1 10.0 --- --- ND --- ND ND ND 6.9 J ND ND ND12-Jun-13 3.1 10.0 --- --- ND --- ND ND ND 6.3 J ND ND ND
28-Oct-13 3.1 10.0 --- --- ND --- ND ND ND 8.6 J ND ND ND6-May-14 3.1 10.0 --- --- ND --- ND ND ND 10.2 ND ND ND
22-Oct-14 3.1 10.0 --- --- * ND ND ND ND 7.4 J ND ND ND
21-May-15 3.1 NE --- --- --- ND ND ND ND 6.3 J ND ND ND
8-Dec-15 3.1 NE --- --- --- ND ND ND ND 9.7 J ND ND ND
3-May-16 3.1 NE --- --- --- ND ND ND ND 7.9 J ND ND ND
13-Dec-16 3.1 NE --- --- --- ND ND ND ND 9.2 J ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 9 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Toluene 1-Jan-95 --- 5.0 --- NI NI NI ND ND 19 ND NI NI ---1-Feb-95 --- 5.0 --- NI NI NI ND ND ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND ND ND ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-Feb-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND ND ND ND NI NI ---1-Oct-96 --- 5.0 --- NI --- --- ND ND 5 ND NI NI ---
1-May-97 --- 5.0 ND NI --- --- ND ND 2 J 3.4 J NI NI ---1-Nov-97 --- 1.0 ND NI --- --- ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND ND ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- --- ND ND ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND ND 22 15.00 ND ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND ND 11 7.20 ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND 11 17.00 ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND 21 ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND 8.4 86 ND ND ND
20-Nov-03 --- 5.0 ND ND --- --- ND ND 14 77 ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND 22 54 ND ND ND
10-Nov-04 --- 5.0 ND ND --- --- ND ND ND 35 ND ND ND27-May-05 --- 5.0 ND ND --- --- ND ND ND 100 ND ND ND
3-Nov-05 --- 5.0 --- ND --- --- ND ND 20 80 ND ND ND25-May-06 --- 5.0 --- ND --- --- ND ND 30.4 35.6 ND ND ND
2-Nov-06 --- 5.0 --- ND --- --- ND ND ND 22 ND ND ND30-May-07 --- 1.0 --- ND --- --- 0.22 B 0.3 B 27.0 30 0.58 B ND 0.44 J
NC 2L = 1,000 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND 1.5 12.0 ND ND ND29-May-08 0.26 1.0 --- ND --- --- ND ND 3.1 12.8 5.9 ND ND
6-Nov-08 0.26 1.0 --- ND --- --- ND ND 0.7 J 23.5 0.76 J ND ND3-Jun-09 0.26 1.0 --- ND --- --- ND ND 0.4 J 52.6 0.85 J ND ND
18-Nov-09 0.26 1.0 --- ND --- --- ND ND ND 27.2 0.55 J ND ND
NC 2L = 600 µg/L (01/01/10)16-Jun-10 0.26 1.0 --- ND --- --- ND ND 2.5 34.8 0.38 J ND ND
1-Dec-10 0.26 1.0 --- ND ND --- ND ND 4.1 17.5 ND ND ND
1-Jun-11 0.26 1.0 --- ND ND --- ND ND ND 24.7 1.1 ND ND
20-Dec-11 0.26 1.0 --- --- ND --- ND ND ND 4.9 D 0.53 J ND ND
30-May-12 0.26 1.0 --- --- ND --- ND ND ND 46.8 0.67 J ND ND
5-Dec-12 0.26 1.0 --- --- ND --- ND ND 0.33 J 10.7 0.45 J ND ND
12-Jun-13 0.26 1.0 --- --- ND --- ND ND ND 27.6 0.7 J ND ND
28-Oct-13 0.26 1.0 --- --- ND --- ND ND ND 14.6 0.5 J ND ND
6-May-14 0.26 1.0 --- --- ND --- ND ND ND 3.9 0.48 J ND ND
22-Oct-14 0.26 1.0 --- --- * ND ND ND ND 4.3 0.28 J ND ND
21-May-15 0.26 1.0 --- --- --- ND ND ND ND 4.1 ND ND ND
8-Dec-15 0.26 1.0 --- --- --- ND ND ND ND 6.0 0.31 J ND ND
3-May-16 0.26 1.0 --- --- --- ND ND ND ND 38.2 0.53 J ND ND13-Dec-16 0.26 1.0 --- --- --- ND ND ND ND 6.8 0.28 J ND ND
1,1,1-Trichloroethane 1-Sep-94 --- 5.0 ND NI NI NI ND 26 ND ND NI NI ---
1-Oct-94 --- 5.0 --- NI NI NI --- ND --- --- NI NI ---1-Jan-95 --- 5.0 --- NI NI NI ND 23 ND ND NI NI ---
1-Feb-95 --- 5.0 --- NI NI NI ND 27 ND ND NI NI ---1-Mar-95 --- 5.0 ND NI NI NI ND 28 6.5 ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- --- ND 42 ND 5 NI NI ---1-Jan-96 --- 5.0 --- NI --- --- ND 44 6 9 NI NI ---
1-Feb-96 --- 5.0 --- NI --- --- ND 31 6.7 ND NI NI ---1-May-96 --- 5.0 --- NI --- --- ND 30 6.7 9.2 NI NI ---
1-Oct-96 --- 5.0 --- NI --- --- ND 22 5 9 NI NI ---
1-May-97 --- 5.0 16 NI --- --- 2.4 J 19 5.3 17 NI NI ---
1-Nov-97 --- 1.0 14 NI --- --- ND ND ND 14 NI NI ---
1-May-98 --- 5.0 15 NI --- --- ND 9.3 9.3 22.0 NI NI ---
24-Nov-98 --- 2.0 10.1 NI --- --- ND 4.9 3 9.3 NI NI ---
10-May-99 --- 5.0 15 ND --- --- ND ND ND 8.7 ND ND ND
18-Oct-99 --- 5.0 11 ND --- --- ND ND ND 9.2 ND ND ND
3-May-00 --- 5.0 12 ND --- --- ND ND ND 8.5 ND ND ND
7-Nov-00 --- 5.0 10 ND --- --- ND ND ND 7.3 ND ND ND
31-May-01 --- 5.0 9.8 ND --- --- ND ND ND 6.0 ND ND ND
7-Nov-01 --- 5.0 14 ND --- --- ND ND ND 7.9 ND ND ND
22-May-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
14-May-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND20-Nov-03 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
6-May-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND10-Nov-04 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND
27-May-05 --- 5.0 ND ND --- --- ND ND ND ND ND ND ND3-Nov-05 --- 5.0 --- ND --- --- ND ND ND 5.0 ND ND ND
25-May-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND2-Nov-06 --- 5.0 --- ND --- --- ND ND ND ND ND ND ND
30-May-07 --- 1.0 --- ND --- --- ND ND ND 3 ND ND NDNC 2L = 200 µg/L (10/23/07)29-Nov-07 --- 1.0 --- ND --- --- ND ND ND ND ND ND ND
29-May-08 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND6-Nov-08 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND
3-Jun-09 0.48 1.0 --- ND --- --- ND ND ND 1 J ND ND ND18-Nov-09 0.48 1.0 --- ND --- --- ND ND ND ND ND ND ND
16-Jun-10 0.48 1.0 --- ND --- --- ND ND ND ND ND ND ND
1-Dec-10 0.48 1.0 --- ND ND --- ND ND ND ND ND ND ND
1-Jun-11 0.48 1.0 --- ND ND --- ND ND ND ND ND ND ND
20-Dec-11 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
30-May-12 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
5-Dec-12 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
12-Jun-13 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
28-Oct-13 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
6-May-14 0.48 1.0 --- --- ND --- ND ND ND ND ND ND ND
22-Oct-14 0.48 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
8-Dec-15 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
13-Dec-16 0.48 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 10 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Trichloroethene 1-Sep-94 --- 5.0 ND NI NI NI ND 9 ND ND NI NI ---1-Oct-94 --- 5.0 --- NI NI NI ---11 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 6 ND ND NI NI ---1-Feb-95 --- 5.0 --- NI NI NI ND 10 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---1-Aug-95 --- 5.0 ND NI --- --- ND 13 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- --- ND 13 ND ND NI NI ---1-Feb-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---1-Oct-96 --- 5.0 --- NI --- --- ND 14 ND ND NI NI ---
1-May-97 --- 5.0 2 J NI --- --- ND 13 5 J ND NI NI ---
1-Nov-97 --- 1.0 2 NI --- --- ND 16 J ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- --- ND 14 13 ND NI NI ---
24-Nov-98 --- 2.0 4 NI --- --- ND 16 4 ND NI NI ---
10-May-99 --- 5.0 6 ND --- --- ND 19 5 ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- --- ND 15 ND ND 5 ND ND
3-May-00 --- 5.0 5.4 ND --- --- ND 14 6 ND 6 ND ND
7-Nov-00 --- 5.0 ND ND --- --- ND 12 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- --- ND 12 7 6 5 ND ND
7-Nov-01 --- 5.0 ND ND --- --- ND 12 8 7 5 ND ND
22-May-02 --- 5.0 ND ND --- --- ND 10 9 8 ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND 5.5 7.6 6.5 ND ND ND14-May-03 --- 5.0 ND ND --- ---ND 11 7 12 6.8 ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND 9.5 6.6 12 ND ND ND6-May-04 --- 5.0 ND ND --- ---ND 9.1 5.8 12 ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND 8.6 ND 11 ND ND ND27-May-05 --- 5.0 5 ND --- ---ND 11 ND 12 ND ND ND
3-Nov-05 --- 5.0 --- ND --- ---ND 9 ND 14 ND ND ND25-May-06 --- 5.0 --- ND --- ---ND 8.6 ND 10 ND ND ND
2-Nov-06 --- 5.0 --- ND --- ---ND 7 ND 12 ND ND ND
30-May-07 --- 1.0 --- 2 --- ---1.9 8.5 4.6 12 2.8 ND ND
NC 2L = 2.8 µg/L (10/23/07)29-Nov-07 --- 1.0 --- 1 --- ---0.45 J 3.5 2.5 9.7 1.6 ND ND
29-May-08 0.47 1.0 --- ND --- ---ND 3.5 2.9 11.9 1.4 ND ND
6-Nov-08 0.47 1.0 --- 1.3 --- ---0.53 J 3.7 3.3 11.6 1.3 ND ND
3-Jun-09 0.47 1.0 --- 1.8 --- ---ND 3.6 4.3 12.1 1.4 ND ND
18-Nov-09 0.47 1.0 --- 1.9 --- ---0.58 J 3.3 3.3 11.2 1.2 ND ND
NC 2L = 3 µg/L (01/01/10)16-Jun-10 0.47 1.0 --- 0.6 J --- ---ND 5.1 3.3 11.2 1.4 ND ND
1-Dec-10 0.47 1.0 --- 1.9 ND ---0.76 J 3.7 3.3 9.3 ND ND ND
1-Jun-11 0.47 1.0 --- 2 ND ---0.51 J 2.8 3.2 11.4 ND ND ND
20-Dec-11 0.47 1.0 --- ---ND ---0.6 J 2.5 3.5 10 D 1.1 ND ND
30-May-12 0.47 1.0 --- ---ND ---ND 2.5 2.6 11.1 0.55 J ND ND
5-Dec-12 0.47 1.0 --- ---ND ---0.53 J 2.3 3.3 11.2 0.67 J ND ND
12-Jun-13 0.47 1.0 --- ---ND ---0.66 J 2.1 1.8 11.5 0.76 J ND ND28-Oct-13 0.47 1.0 --- ---ND ---ND 3.1 2.5 10.7 0.76 J ND ND
6-May-14 0.47 1.0 --- ---ND ---ND 2 2.6 11.9 0.6 J ND ND22-Oct-14 0.47 1.0 --- --- * ND 0.61 J 1.3 2.2 11.4 0.86 J ND ND
21-May-15 0.47 1.0 --- --- --- ND ND 0.9 J 2.3 10.1 ND ND ND8-Dec-15 0.47 1.0 --- --- --- ND ND 0.71 J 1.4 9.7 ND ND ND
3-May-16 0.47 1.0 --- --- --- ND 0.53 J 0.63 J 1.8 10.1 ND ND ND13-Dec-16 0.47 1.0 --- --- --- ND 0.52 J 0.56 J 2.1 9.9 0.64 J ND ND
Trichlorofluoromethane 1-Oct-94 --- 5.0 --- NI NI NI --- 60 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 37 ND ND NI NI ---1-Feb-95 --- 5.0 --- NI NI NI ND 40 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 48 ND ND NI NI ---
1-Aug-95 --- 5.0 ND NI --- ---ND 51 ND 9 NI NI ---
1-Jan-96 --- 5.0 --- NI --- ---ND 20 5 11 NI NI ---
1-Feb-96 --- 5.0 --- NI --- ---ND 11 6.2 7.9 NI NI ---
1-May-96 --- 5.0 --- NI --- ---ND 8.8 ND 9.1 NI NI ---
1-Oct-96 --- 5.0 --- NI --- ---ND ND ND 9 NI NI ---
1-May-97 --- 5.0 4.2 J NI --- ---ND 2.1 J 3.4 J 11 NI NI ---
1-Nov-97 --- 1.0 4 NI --- ---ND ND ND 11 NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND ND ND 5 NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND ND ND 7.6 NI NI ---
10-May-99 --- 10.0 ND ND --- ---ND ND ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND ND ND 12 ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND ND ND 9.4 ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND ND ND 10 ND ND ND31-May-01 --- 5.0 ND ND --- ---ND ND ND 6.5 ND ND ND
7-Nov-01 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND22-May-02 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND ND ND 6.5 ND ND ND14-May-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND6-May-04 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND27-May-05 --- 5.0 ND ND --- ---ND ND ND ND ND ND ND
3-Nov-05 ---5.0 --- ND --- ---ND ND ND ND ND ND ND25-May-06 --- 5.0 --- ND --- ---ND ND ND ND ND ND ND
2-Nov-06 --- 5.0 --- ND --- ---ND ND ND ND ND ND ND
30-May-07 --- 1.0 --- ND --- ---ND ND ND 4.2 ND ND ND
NC 2L = 2,100 µg/L (10/23/07)29-Nov-07 --- 1.0 --- 0.74 J --- ---ND ND ND ND ND ND ND
29-May-08 0.2 1.0 --- 0.42 J --- ---ND ND ND ND ND ND ND
6-Nov-08 0.2 1.0 --- 0.71 J --- ---ND ND 0.24 J 1.1 ND ND ND
3-Jun-09 0.2 1.0 --- 0.38 J --- ---ND ND ND ND ND ND ND
18-Nov-09 0.2 1.0 --- 1.9 --- ---ND ND 1.6 2.1 ND ND ND
NC 2L = 2,000 µg/L (01/01/10) 16-Jun-10 0.2 1.0 --- ND --- ---ND ND ND ND ND ND ND
1-Dec-10 0.2 1.0 --- 0.34 J ND ---ND ND ND 0.58 J ND ND ND
1-Jun-11 0.2 1.0 --- 0.5 J ND ---ND ND ND 0.79 J ND ND ND
20-Dec-11 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
30-May-12 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
5-Dec-12 0.2 1.0 --- ---ND ---ND ND ND 0.65 J ND ND ND
12-Jun-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND28-Oct-13 0.2 1.0 --- ---ND ---ND ND ND ND ND ND ND
6-May-14 0.2 1.0 --- ---ND ---ND ND ND 0.3 J ND ND ND22-Oct-14 0.2 1.0 --- --- * ND ND ND ND ND ND ND ND
21-May-15 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND8-Dec-15 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
3-May-16 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND13-Dec-16 0.2 1.0 --- --- --- ND ND ND ND ND ND ND ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 11 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Vinyl Chloride 30-May-07 0.62 1.0 --- ND --- ---ND 0.46 J 1.6 ND 3.1 ND NDNC 2L = 0.015 µg/L (10/23/07)29-Nov-07 0.62 1.0 --- 0.42 J --- ---ND ND 1.4 ND 1.9 ND ND
29-May-08 0.62 1.0 --- ND --- ---ND ND 1.2 ND 2.2 ND ND6-Nov-08 0.62 1.0 --- 0.63 J --- ---ND 0.68 J 1.1 ND 1.8 ND ND
3-Jun-09 0.62 1.0 --- ND --- ---ND ND 0.95 J ND 2 ND ND
18-Nov-09 0.62 1.0 --- 0.69 J --- ---ND 0.66 J 1.6 ND 2.5 ND ND
NC 2L = 0.03 µg/L (01/01/10)16-Jun-10 0.62 1.0 --- ND --- ---ND ND 1.1 ND 2.1 ND ND
1-Dec-10 0.62 1.0 --- ND ND ---ND 0.65 J 0.93 J ND 3.5 ND ND
1-Jun-11 0.62 1.0 --- ND ND ---ND 0.87 J 1.1 ND 1.8 ND ND
20-Dec-11 0.62 1.0 --- ---ND ---ND 0.63 J ND ND 1.4 ND ND
30-May-12 0.62 1.0 --- ---ND ---ND ND ND ND 1.6 ND ND
5-Dec-12 0.62 1.0 --- ---ND ---ND ND ND ND ND ND ND
12-Jun-13 0.62 1.0 --- ---ND ---ND ND 0.96 J ND 2.1 ND ND
28-Oct-13 0.62 1.0 --- ---ND ---ND ND 0.74 J ND 1.3 ND ND
6-May-14 0.62 1.0 --- ---ND ---ND ND 0.77 J ND 1.8 ND ND
22-Oct-14 0.62 1.0 --- --- * ND ND ND ND ND 1.3 ND ND
21-May-15 0.62 1.0 --- --- --- ND ND ND ND ND 1.1 ND ND
8-Dec-15 0.62 1.0 --- --- --- ND ND 0.72 J ND ND 1.4 ND ND3-May-16 0.62 1.0 --- --- --- ND ND ND 0.74 J ND 1.2 ND ND
13-Dec-16 0.62 1.0 --- --- --- ND ND ND ND ND 0.9 J ND ND
Xylene (Total)1-Sep-94 --- 5.0 ND NI NI NI ND 12 ND ND NI NI ---1-Oct-94 --- 5.0 --- NI NI NI --- 22 --- --- NI NI ---
1-Jan-95 --- 5.0 --- NI NI NI ND 7.6 ND ND NI NI ---1-Feb-95 --- 5.0 --- NI NI NI ND 20 ND ND NI NI ---
1-Mar-95 --- 5.0 ND NI NI NI ND 24 ND ND NI NI ---1-Aug-95 --- 5.0 ND NI NI NI ND 5 ND ND NI NI ---
1-Jan-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---1-Feb-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---
1-May-96 --- 5.0 --- NI --- ---ND ND ND ND NI NI ---
1-Oct-96 --- 5.0 --- NI --- ---ND 6 ND ND NI NI ---
1-May-97 --- 5.0 ND NI --- ---ND 9.2 4.3 J ND NI NI ---
1-Nov-97 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 5.0 ND NI --- ---ND 5.6 ND ND NI NI ---
24-Nov-98 --- 2.0 ND NI --- ---ND 14.8 ND ND NI NI ---
10-May-99 --- 5.0 ND ND --- ---ND 13 ND ND ND ND ND
18-Oct-99 --- 5.0 ND ND --- ---ND 14 ND ND ND ND ND
3-May-00 --- 5.0 ND ND --- ---ND 17.5 ND ND ND ND ND
7-Nov-00 --- 5.0 ND ND --- ---ND 11 ND ND ND ND ND
31-May-01 --- 5.0 ND ND --- ---ND 10 9 10 ND ND ND
7-Nov-01 --- 5.0 ND ND --- ---ND 7.9 5.3 7.6 ND ND ND
22-May-02 --- 5.0 ND ND --- ---ND 5.3 8.5 14 ND ND ND
14-Nov-02 --- 5.0 ND ND --- ---ND ND 21.3 12 ND ND ND14-May-03 --- 5.0 ND ND --- ---ND 5.4 6.6 48 ND ND ND
20-Nov-03 --- 5.0 ND ND --- ---ND ND 7.4 50 ND ND ND6-May-04 --- 5.0 ND ND --- ---ND ND 18.9 58 ND ND ND
10-Nov-04 --- 5.0 ND ND --- ---ND ND ND 54 ND ND ND27-May-05 --- 5.0 11 ND --- ---ND ND 7 58 ND ND ND
3-Nov-05 --- 5.0 --- ND --- ---ND ND 26 119 ND ND ND25-May-06 --- 5.0 --- ND --- ---ND ND 17.4 38.7 ND ND ND
2-Nov-06 --- 10.0 --- ND --- ---ND ND ND 31 ND ND ND30-May-07 --- 4.0 --- 1.1 J --- ---ND 2 J 24 34 1.2 J ND ND
NC 2L = 530 µg/L (10/23/07)29-Nov-07 --- 5.0 --- 2.7 J --- ---ND ND 3.9 J 24 ND ND ND
29-May-08 0.89 10.0 --- 1.7 J --- ---ND 0.92 J 6.2 J 29.6 ND ND ND
6-Nov-08 0.66 2.0 --- 2.3 --- ---ND 0.78 J 2.8 28.7 ND ND ND
3-Jun-09 0.66 2.0 --- 1.6 J ------ND ND 4.7 46.5 ND ND ND
18-Nov-09 0.66 2.0 --- 5.7 --- ---ND ND 3.1 40.3 ND ND ND
NC 2L = 500 µg/L (01/01/10)16-Jun-10 0.66 2.0 --- 1.8 J --- ---ND 1 J 5.2 40.3 ND ND ND
1-Dec-10 0.66 2.0 --- 2.3 ND ---ND ND 5.6 42.9 ND ND ND
1-Jun-11 0.66 2.0 --- 3.6 ND ---ND ND 0.88 J 44.1 ND ND ND
20-Dec-11 0.66 2.0 --- ---ND ---ND ND 0.94 J 26.8 D ND ND ND
30-May-12 0.66 2.0 --- ---ND ---ND ND 0.7 J 53.5 ND ND ND
5-Dec-12 0.66 5.0 --- ---ND ---ND ND 2.4 J 43.6 ND ND ND
12-Jun-13 0.66 5.0 --- ---ND ---ND ND ND 48.3 ND ND ND
28-Oct-13 0.66 5.0 --- ---ND ---ND ND ND 49.3 ND ND ND
6-May-14 0.66 5.0 --- ---ND ---ND ND ND 40.7 ND ND ND
22-Oct-14 0.66 5.0 --- --- * ND ND ND ND 46.6 ND ND ND
21-May-15 0.66 5.0 --- --- --- ND ND ND ND 43.6 ND ND ND8-Dec-15 0.66 5.0 --- --- --- ND ND ND ND 45.4 ND ND ND
3-May-16 0.66 5.0 --- --- --- ND ND ND ND 72.4 ND ND ND13-Dec-16 0.66 5.0 --- --- --- ND ND ND ND 63.8 ND ND ND
Diethyl phthalate 29-Nov-07 --- 10.0 --- ND --- ---1.7 J 2.3 J 2 J ND 1.3 J --- ND
# 6-Nov-08 2.5 10.0 --- ND --- ---ND ND ND ND ND ND NDNC 2L = 5,000 µg/L (10/23/07) 18-Nov-09 4 10.0 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 2.7 10.0 --- ND ND ---ND ND ND ND ND --- ND20-Dec-11 0.58 10.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.58 6000 --- ---ND ---ND ND ND ND ND --- ND28-Oct-13 0.58 6000 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.91 6000 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 1.3 6000 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16
Naphthalene 29-Nov-07 --- 10.0 --- ND --- ---ND ND ND 1.3 JD ND --- ND
# 6-Nov-08 0.24 10.0 --- ND --- ---ND ND ND ND ND --- 0.67 J
NC 2L = 21 µg/L (10/23/07) 18-Nov-09 0.24 10.0 --- ND --- ---ND ND ND 0.77 JD ND --- ND
1-Dec-10 4 10.0 --- ND ND ---ND ND ND 0.96 J ND --- ND
20-Dec-11 0.34 10.0 --- ---ND ---ND ND ND 0.84 JD ND --- ND
5-Dec-12 0.34 10.0 --- ---ND ---ND ND ND 1.5 B ND --- 0.46 J
28-Oct-13 0.24 10.0 --- ---ND ---ND ND ND 1.6 J ND --- ND
22-Oct-14 0.24 10.0 --- --- * ND ND ND ND 1.9 J ND --- ND
8-Dec-15 0.24 10.0 --- --- --- ND ND ND ND 2.2 J ND --- ND
13-Dec-16 0.24 10.0 --- --- --- ND ND ND ND 2.6 J ND --- 0.26 J
Burke County Johns River C D over MSWLF
Permit 12-03 Page 12 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Pentachlorophenol 29-Nov-07 --- 25.0 --- ND --- ---ND ND ND 0.42 JD ND --- ND#6-Nov-08 1.7 25.0 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.29 µg/L (10/23/07)18-Nov-09 5 50.0 --- ND --- ---ND ND ND ND ND --- ND1-Dec-10 18 25.0 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 4.6 25.0 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 1.2 25.0 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 2.3 25.0 --- --- --- ND ND ND ND ND ND --- ND
alpha-BHC 1-Oct-96 --- 0.050 --- NI --- ---ND 0.07 ND ND NI NI ---
#1-May-97 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
1-Nov-97 --- 0.100 ND NI --- ---ND ND ND ND NI NI ---
1-May-98 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
24-Nov-98 --- 0.050 ND NI --- ---ND ND ND ND NI NI ---
10-May-99 --- 0.050 ND ND --- ---0.061 ND ND ND ND ND ND
18-Oct-99 --- 0.050 ND ND --- ------ ND ND ND ND ND ND3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND
7-Nov-00 --- 0.050 ND ------ ---ND ND ND ND ND --- ND7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- NDGWPS = 0.006 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND18-Nov-09 0.00031 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0003 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND 0.19 ND --- ND
Resample >10-Dec-13 0.05 0.050 --- ------ ------ --- ---0.085 --- --- ND
6-May-14 0.05 0.050 --- ---ND ---ND ND ND 0.07 ND --- ---
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
21-May-15 0.05 0.050 --- --- --- ND ND ND ND 0.12 ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
3-May-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND 0.063 ND --- ND
beta-BHC 1-Dec-10 0.0005 0.050 --- ND ND ---ND ND 0.019 J ND ND --- ND
# Resample >13-Jan-11 0.0005 0.050 --- ------ ------ --- ND --- ------ ND
GWPS = 0.019 µg/L (10/23/07)20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND8-Dec-15 0.05 0.050 --- --- --- ND ND 0.16 ND ND ND --- ND
Resample >4-Feb-16 0.05 0.050 --- --- --- --- ---0.33 --- --- ------ ND3-May-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND 0.120 ND ND ND --- ND
Delta-BHC 18-Oct-99 --- 0.050 ND ND --- ------ 0.06 J ND ND ND ND ND#3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND
7-Nov-00 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.019 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.00041 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0004 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Gamma-BHC 18-Oct-99 --- 0.050 ND ND --- ------ 0.08 J ND ND ND ND ND
(Lindane)3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND#7-Nov-00 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
7-Nov-01 ---0.050 ND ------ ---ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.2 µg/L (10/23/07)29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.00021 0.010 --- 0.032 --- ---ND ND ND ND ND --- ND
Resample >19-Jan-10 0.00021 0.010 --- ND --- ------ --- --- --- --- --- ND
1-Dec-10 0.0002 0.050 --- ND ND ---ND ND 0.034 J ND ND --- ND
Resample >13-Jan-11 0.0002 0.050 --- ------ ------ --- 0.048 J --- --- --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 13 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
Heptachlor 18-Oct-99 --- 0.050 ND ND --- ------ 0.11 J ND ND ND ND ND#3-May-00 --- 0.050 ND ------ ---ND ND --- --- ------ ND
7-Nov-01 --- 0.050 ND ------ ---ND ND ND ND ND --- ND14-Nov-02 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 0.050 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 0.0078 µg/L (10/23/07) 29-Nov-07 --- 0.050 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 0.05 0.050 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.0015 0.010 --- ND --- ---ND ND ND ND ND --- ND
1-Dec-10 0.0015 0.050 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.050 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.050 --- --- * ND ND ND ND ND ND --- ND
8-Dec-15 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.050 --- --- --- ND ND ND ND ND ND --- ND
N-Nitroso-di-n-butylamine 22-Oct-14 1.3 10.0 --- --- --- --- 4.0 J ND ND 11.2 ND --- ND# Resample >22-Dec-14 1.3 10.0 --- --- --- --- --- --- --- ND ------ ---
NC 2L = NE (01/01/10)8-Dec-15 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND13-Dec-16 2.2 10.0 --- --- --- ND ND ND ND ND ND --- ND
PCB-1232 18-Oct-99 --- 2.0 4.7 ND --- ------ ND ND ND ND ND ND
#3-May-00 --- 2.0 ND ------ ---ND ND --- --- ------ ND7-Nov-00 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
7-Nov-00 --- 2.0 ND ------ ---ND ND ND ND ND --- ND31-May-01 --- 2.0 ND ------ ------ --- --- --- ------ ND
7-Nov-01 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 1.0 ND ------ ---ND ND ND ND ND --- ND
6-May-05 --- 1.0 --- ------ ------ --- --- --- ------ ---
3-Nov-05 --- 1.0 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 1.0 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.5 µg/L (10/23/07)29-Nov-07 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
6-Nov-08 1 NE --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.12 0.5 --- ND --- ---ND ND ND ND ND --- ND
GWPS = 0.09 µg/L (10/01/10)1-Dec-10 0.5 0.5 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.5 0.5 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.5 0.5 --- ---*NDND ND ND ND ND --- ND
8-Dec-15 0.5 0.5 --- --- --- ND ND ND ND ND ND --- ND
2,4-D 1-Aug-95 --- 0.3 ND NI --- ---ND 0.478 ND ND NI NI ---
# 1-Jan-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---1-Feb-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---
1-May-96 --- 2.0 --- NI --- ---ND ND ND ND NI NI ---1-Oct-96 --- 0.5 --- NI --- ---ND ND ND ND NI NI ---
1-Nov-97 --- 0.4 ND NI --- ---ND ND ND ND NI NI ---24-Nov-98 --- 2.0 ND NI --- ---ND ND ND ND NI NI ---
18-Oct-99 --- 2.0 ND ND --- ------ ND ND ND ND ND ND
7-Nov-01 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
14-Nov-02 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
20-Nov-03 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
10-Nov-04 --- 2.0 ND ------ ---ND ND ND ND ND --- ND
3-Nov-05 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
2-Nov-06 --- 2.0 --- ND --- ---ND ND ND ND ND --- ND
NC 2L = 70 µg/L (10/23/07) 29-Nov-07 --- 2.0 --- ND --- ---ND 1.4 J ND ND ND --- ND
6-Nov-08 1 2.0 --- ND --- ---ND ND ND ND ND --- ND
18-Nov-09 0.22 2.0 --- ND --- ---ND ND ND ND ND --- ND
Resample >19-Jan-10 0.23 1.0 --- ND --- ------ --- --- ND --- --- ND
1-Dec-10 0.22 2.0 --- ND ND ---ND ND ND ND ND --- ND
20-Dec-11 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND28-Oct-13 0.22 2.0 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.23 0.96 --- --- * ND ND ND ND ND ND --- ---8-Dec-15 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.22 2.00 --- --- --- ND ND ND ND ND ND --- ND
2,4,5-TP (Silvex) 13-Dec-16 0.049 2.00 --- --- --- ND ND 0.14 J ND ND ND --- NDNC 2L = 50 µg/L (01/01/10)
4,4'-DDD 1-Dec-10 0.0019 0.10 --- ND ND ---ND 0.019 J ND ND ND --- ND
# Resample >13-Jan-11 0.0019 0.10 --- ------ ------ ND --- --- --- --- ND
NC 2L = 0.1 µg/L (01/01/10) 20-Dec-11 0.05 0.05 --- ---ND ---ND ND ND ND ND --- ND
5-Dec-12 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
Burke County Johns River C D over MSWLF
Permit 12-03 Page 14 of 15 Joyce Engineering
APPENDIX E:
HISTORICAL DETECTED ORGANIC GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL RL MW-9 MW-17 MW-20 MW-21 MW-10 MW-11 MW-12 MW-13 MW-16S MW-16D Blanks
4,4'-DDE 1-Dec-10 0.0009 0.10 --- ND ND ---ND ND ND 0.019 J ND --- ND# Resample >13-Jan-11 0.0009 0.10 --- ------ ------ --- --- 0.027 J ------ ND
NC 2L = NE (01/01/10)20-Dec-11 0.05 0.05 --- ---ND ---ND ND ND ND ND --- ND5-Dec-12 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
28-Oct-13 0.05 0.10 --- ---ND ---ND ND ND ND ND --- ND
22-Oct-14 0.05 0.10 --- --- * ND ND ND ND ND ND --- ---
8-Dec-15 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
13-Dec-16 0.05 0.10 --- --- --- ND ND ND ND ND ND --- ND
Notes:
(Abbreviations and Referrences)All concentrations in micrograms per liter (µg/L) = parts per billion.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.
--- = Not sampled for this parameter or Not reported
AB = Monitoring well abandoned.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
DL = Laboratory Detection Limit.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
When the NC 2L Groundwater Standard has not been established, the GWPS will be used.
J = Estimated value - concentration is less than the RL but greater than the DL.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NE = No NC 2L or GWPS established.
NI = Not Installed. Monitoring well not yet installed.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).Values above the NC2L Standard or GWPS are bold.
Notes: (Event Narratives)
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004. There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well for the C&D Expansion (Phase 1A). See the Water Quality Monitrong Report for the C&D Expansion Area for current results for MW-20.
Sample Collection Date Column displays the last day of the Respective Semiannaul Monitoring Event that samples were collected. Each individual sampling point date is preserved in the Lab Reports (Appendix A).
Burke County Johns River C D over MSWLF
Permit 12-03 Page 15 of 15 Joyce Engineering

Appendix F

Historical Detected Constituents in Performance & Sentinel Wells

APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Sample EPA
Analyte Collection Date Method DL RL MW-18 MW-19 MW-36 MW-38 Blanks
Organic Compounds
Benzene 18-Feb-13 0.25 1.0 ------8.0 3.8 ND
NC 2L = 6 µg/L (01/01/10)18-Jul-13 0.25 1.0 ------------ND
28-Oct-13 0.25 1.0 ND ND ------ND
6-May-14 0.25 1.0 ND ND 8.7 6.5 ND
22-Oct-14 EPA 8260 0.25 1.0 ND ND 8.3 5.9 ND
21-May-15 EPA 8260 0.25 1.0 ND ND 5.8 4.9 ND
18-Jul-13 0.33 1.0 ------------ND
28-Oct-13 0.33 1.0 ND ND ------ND
6-May-14 0.33 1.0 ND ND 10.0 13.5 ND
22-Oct-14 EPA 8260 0.33 1.0 ND ND 15.2 12.9 ND
NC 2L = 1 µg/L (02/1/15)21-May-15 EPA 8260 0.33 1.0 ND ND 18.7 12.3 ND
8-Dec-15 0.33 1.0 ------5.8 4.4 ND
3-May-16 0.33 1.0 ND ND 6.7 5.4 ND
14-Dec-16 0.33 1.0 ------5.5 3.0 ND
1,1-Dichloroethane 3-Jun-09 0.3 5.0 3.9 J 2.8 J ------ND
18-Nov-09 0.3 5.0 6.7 3.7 J ------ND
16-Jun-10 0.3 5.0 4.4 J 2.3 J ------ND
1-Dec-10 0.3 5.0 ------------ND
1-Jun-11 0.3 5.0 2.8 J 2.6 J ------ND
20-Dec-11 0.3 5.0 ------------ND
30-May-12 0.3 5.0 1.6 J 2.7 J ------ND
5-Dec-12 0.3 5.0 ------------ND
18-Feb-13 0.32 5.0 ------7.9 9.1 ND
12-Jun-13 0.3 5.0 ------------ND
18-Jul-13 0.32 5.0 ------------ND
28-Oct-13 0.3 5.0 0.93 J 3.0 J ------ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.32 5.0 1.2 J 2.9 J 11.6 8.1 ND
22-Oct-14 EPA 8260 0.32 5.0 ------9.0 6.9 ND
21-May-15 EPA 8260 0.32 5.0 ND 1.7 J 4.8 J 5.5 ND
8-Dec-15 0.32 5.0 ------5.9 7.2 ND
3-May-16 0.32 5.0 0.4 J 2.5 J 5.9 6.5 ND
14-Dec-16 0.32 5.0 ------4.4 J 6.0 ND
1,2-Dichloroethane 3-Jun-09 0.1 1.0 0.33 J ND ------ND
18-Nov-09 0.1 1.0 0.56 J ND ------ND
16-Jun-10 0.1 1.0 0.37 J ND ------ND
1-Dec-10 0.1 1.0 ------------ND
1-Jun-11 0.1 1.0 0.34 J ND ------ND
20-Dec-11 0.1 1.0 ------------ND
30-May-12 0.1 1.0 ND ND ------ND
5-Dec-12 0.1 1.0 ------------ND
18-Feb-13 0.12 1.0 ------1.0 0.59 J ND
12-Jun-13 0.1 1.0 ------------ND
18-Jul-13 0.12 1.0 ------------ND
28-Oct-13 0.1 1.0 ND ND ------ND
NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.12 1.0 ND ND 0.78 J ND ND
22-Oct-14 EPA 8260 0.12 1.0 ------0.92 J 0.63 J ND
21-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND
8-Dec-15 0.12 1.0 ------0.66 J 0.70 J ND
3-May-16 0.12 1.0 ND ND 0.92 J 0.74 J ND
14-Dec-16 0.12 1.0 ------ND ND ND
Methylene Chloride 18-Feb-13 0.97 1.0 ------17.9 ND ND
18-Jul-13 0.97 1.0 ------------ND
28-Oct-13 0.97 1.0 ND ND ------ND
NC 2L = 5 µg/L (01/01/10)6-May-14 0.97 1.0 ------24.1 1.7 2.20
22-Oct-14 EPA 8260 0.97 1.0 ------15.7 ND ND
21-May-15 EPA 8260 0.97 1.0 ND ND 9.5 B ND 1.7
8-Dec-15 0.97 1.0 ------11.2 B ND 2.0
3-May-16 0.97 1.0 ND ND 3.1 ND ND
14-Dec-16 0.97 1.0 ------ND ND ND
Sentinel Performance
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Page 1 of 2
Joyce Engineering
APPENDIX F:
CONSTITUENTS OF CONCERN DETECTIONS
IN PERFORMANCE AND SENTINEL WELLS
Sample EPA
Analyte Collection Date Method DL RL MW-18 MW-19 MW-36 MW-38 Blanks
Sentinel Performance
Tetrachloroethene 18-Feb-13 0.46 1.0 --- ---5.5 ND ND
18-Jul-13 0.46 1.0 --- --- --- --- ND
28-Oct-13 0.46 1.0 ND ND --- --- ND
NC 2L = 0.7 µg/L (10/23/07) 6-May-14 0.46 1.0 --- ---7.9 ND ND
22-Oct-14 EPA 8260 0.46 1.0 --- ---7.3 ND ND
21-May-15 EPA 8260 0.46 1.0 ND ND 6.0 ND ND
8-Dec-15 0.46 1.0 ------5.0 ND ND
3-May-16 0.46 1.0 ND ND 4.5 ND ND
14-Dec-16 0.46 1.0 ------ND ND ND
Trichloroethene 18-Feb-13 0.47 1.0 ------3.6 2.7 ND
18-Jul-13 0.47 1.0 ------------ND
28-Oct-13 0.47 1.0 ND ND ------ND
NC 2L = 3 µg/L (01/01/10)6-May-14 0.47 1.0 ------6.0 2.1 ND
22-Oct-14 EPA 8260 0.47 1.0 ------5.1 1.8 ND
21-May-15 EPA 8260 0.47 1.0 ND ND 3.5 0.9 J ND
8-Dec-15 0.47 1.0 ------2.9 2.1 ND
3-May-16 0.47 1.0 ND ND 3.1 1.7 ND
14-Dec-16 0.47 1.0 ------ND 1.8 ND
Vinyl chloride 18-Feb-13 0.62 1.0 ------1.2 ND ND
18-Jul-13 0.62 1.0 ------------ND
28-Oct-13 0.62 1.0 ND ND ------ND
NC 2L = 0.03 µg/L (01/01/10)6-May-14 0.62 1.0 ------1.1 ND ND
22-Oct-14 EPA 8260 0.62 1.0 ------0.9 J ND ND
21-May-15 EPA 8260 0.62 1.0 ND ND ND ND ND
8-Dec-15 0.62 1.0 ------0.80 J ND ND
3-May-16 0.62 1.0 ND ND 0.80 J 1.8 ND
Resample > 9-Jun-16 0.62 1.0 ---------ND ND
14-Dec-16 0.62 1.0 ---------ND ND
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
DL = Laboratory Detection Limit.
RL = SWSL = Solid Waste Section Reporting Limit.
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L.
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or not monitored.
Italics = Constituent of Concern (COC).
Resample > indicates results of a verification sample event.
For MW-36 and MW-38, only COC's are reported in this Appendix. Additional constituents required for the Phase 1A area are included in the Semiannual Groundwater Monitoring
Report for Phase 1A.
Burke Co. - Johns River C+D-over-MSWLF
Permit No. 12-03
Page 2 of 2
Joyce Engineering

Appendix G

Historical Detected Surface Water Constituents

APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
NC 2B = 5.6 µg/L (03/01/16) 4-May-16 3.8 6.0 ND ND ND ND
14-Dec-16 3.8 6.0 ND ND ND ND
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J --- ND
18-Nov-09 2.7 10.0 ND ND --- ND
NC 2B = 10 µg/L (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND
1-Dec-10 2.7 10.0 ND ND --- ND
1-Jun-11 2.7 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 10 µg/L (03/01/16) 4-May-16 2.5 10.0 3.0 J ND 3.3 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J ---ND
6-Nov-08 0.20 100 82.5 J 40.2 B ---9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/L (05/01/07)15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J ---ND
1-Jun-11 0.20 100 51.6 J 19.9 J ---ND
20-Dec-11 5.0 100 63.7 J 13.9 J ---ND
30-May-12 5.0 100 16.9 J 22.0 J ---ND
5-Dec-12 5.0 100 69.9 J 24.8 J ---ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J ---ND
6-May-14 5.0 100 37.0 J 17.8 J ---ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
NC 2B = 1,000 µg/L (03/01/16)4-May-16 2.5 100 41.4 J 37.3 J 51.0 J ND
14-Dec-16 2.5 100 44.7 J 21.2 J 17.5 J ND
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND ---ND
20-Nov-03 --- 2 ND ND ---ND
6-May-04 --- 2 ND ND ---ND
10-Nov-04 --- 2 ND ND ---ND
5-May-05 --- 2 ND ND ---ND
3-Nov-05 --- 2 ND ND ---ND
25-May-06 --- 2 ND ND ---ND
2-Nov-06 --- 2 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.10 1.0 ND ND ---ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J ---ND
18-Nov-09 0.10 1.0 ND ND ---ND
NC 2B = 6.5 µg/L (05/01/07)15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND ---ND
1-Jun-11 0.10 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 6.5 µg/L Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 ---ND
22-May-02 --- 1 ND 1.7 B ---1.3
14-Nov-02 --- 1 ND ND ---ND
14-May-03 --- 1 ND ND ---ND
20-Nov-03 --- 1 ND ND ---ND
6-May-04 --- 1 ND ND ---ND
10-Nov-04 --- 1 ND ND ---ND
5-May-05 --- 1 ND ND ---ND
3-Nov-05 --- 1 ND ND ---ND
25-May-06 --- 1 ND ND ---ND
2-Nov-06 --- 1 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND ---ND
6-Nov-08 0.50 1.0 ND ND ---ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND ---ND
NC 2B = 2 µg/L (05/01/07)15-Jun-10 0.50 1.0 ND ND ---ND
1-Dec-10 0.50 1.0 ND ND ---ND
1-Jun-11 0.50 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 0.15 µg/L Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
Chromium, total 6-Nov-08 0.40 10.0 ND 0.47 J ---ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J ---ND
18-Nov-09 0.40 10.0 ND ND ---ND
NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 11 µg/L Chronic (03/01/16)*4-May-16 2.5 10.0 4.7 J 4.6 J 8.8 J ND
14-Oct-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND 10.0 ---ND
20-Nov-03 --- 10 14.0 ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 10.0 ND ---ND
5-May-05 --- 10 10.0 ND ---ND
3-Nov-05 --- 10 16.0 ND ---ND
25-May-06 --- 10 12 ND ---ND
2-Nov-06 --- 10 13.6 ND ---ND
30-May-07 --- 10 12.3 8.8 J ---ND
29-Nov-07 --- 10 19.0 2.1 J ---ND
29-May-08 0.60 10.0 13.7 ND ---ND
6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B ---7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J ---ND
NC 2B = NE (05/01/07)15-Jun-10 0.60 10.0 6.4 J 22.3 ---ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J ---ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 29.0 7.7 J ---ND
12-Jun-13 5.0 10.0 ND 9.1 J ---ND
28-Oct-13 5.0 10.0 11.5 12.4 ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 3 µg/L (03/01/16)4-May-16 2.5 10.0 4.0 J 5.6 J 3.3 J ND
14-Dec-16 2.5 10.0 5.9 J ND ND ND
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J ---ND
18-Nov-09 0.30 10.0 ND ND ---ND
NC 2B = 7 µg/L (05/01/07)15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J ---ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 5.2 B ND ---9.8 J
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 2.7 µg/L Chronic (3/1/16)*4-May-16 2.5 10.0 4.6 J 5.5 J 11 ND
resample 17-May-16 2.5 10.0 --- --- ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND ---ND
18-Nov-09 4.0 10.0 ND ND ---ND
NC 2B = 25 µg/L (05/01/07)15-Jun-10 4.0 10.0 ND ND ---ND
1-Dec-10 4.0 10.0 ND 4.6 J ---ND
1-Jun-11 4.0 10.0 ND ND ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 14 µg/L Acute, 0.54 µg/L Chronic * 4-May-16 2.5 10.0 ND 4.9 J 7.2 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
Nickel 3-Jun-09 1.7 50.0 5.5 B ND ---1.7 J
18-Nov-09 1.7 50.0 ND ND ---ND
NC 2B = 25 µg/L (05/01/07)15-Jun-10 1.7 50.0 ND ND ---ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J ---ND
1-Jun-11 1.7 50.0 ND ND ---2.3 J
20-Dec-11 5.0 50.0 ND ND ---ND
30-May-12 5.0 50.0 ND ND ---ND
5-Dec-12 5.0 50.0 ND ND ---ND
12-Jun-13 5.0 50.0 ND ND ---ND
28-Oct-13 5.0 50.0 ND ND ---ND
6-May-14 5.0 50.0 ND ND ---ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
NC 2B = 16 µg/L Chronic (03/01/16)*4-May-16 2.5 50.0 3.8 J 3.9 J 6.7 J ND
14-Dec-16 2.5 50.0 ND ND ND ND
Selenium 6-Nov-08 3.8 10 ND 10.9 ---ND
3-Jun-09 3.8 10.0 ND ND ---ND
18-Nov-09 3.8 10.0 ND ND ---ND
NC 2B = 5 µg/L (05/01/07)15-Jun-10 3.8 10.0 ND ND ---ND
1-Dec-10 3.8 10.0 ND ND ---ND
1-Jun-11 3.8 10.0 ND ND ---ND
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND ---ND
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 5 µg/L (03/01/16)4-May-16 5.0 10.0 ND ND ND ND
14-Dec-16 5.0 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND ND ---ND
20-Nov-03 --- 10 ND ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 ND ND ---ND
5-May-05 --- 10 ND ND ---ND
3-Nov-05 --- 10 ND ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 10 ND ND ---ND
29-Nov-07 --- 10 ND ND ---ND
29-May-08 0.10 10.0 0.29 J 0.13 J ---ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J
3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/L (05/01/07)15-Jun-10 0.10 10.0 ND ND ---ND
1-Dec-10 0.10 10.0 ND ND ---ND
1-Jun-11 0.10 10.0 ND 0.22 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 0.06 µg/L Chronic (03/01/16)*4-May-16 2.5 10.0 ND ND ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
Thallium 5-May-05 --- 10 22.0 11.0 ---ND
3-Nov-05 --- 10 20.0 ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 5.5 0.053 J ND ---ND
29-Nov-07 --- 5.5 0.055 J ND ---ND
29-May-08 3.0 5.5 ND ND ---ND
6-Nov-08 3.0 5.5 ND ND ---ND
3-Jun-09 3.0 5.5 ND ND ---ND
18-Nov-09 3.0 5.5 ND ND ---4.2 J
NC 2B = NE (05/01/07)15-Jun-10 3.0 5.5 3.2 J ND ---ND
1-Dec-10 3.0 5.5 ND ND ---4.0 J
1-Jun-11 3.0 5.5 ND ND ---ND
20-Dec-11 5.4 5.5 ND ND ---ND
30-May-12 5.4 5.5 ND ND ---ND
5-Dec-12 5.4 5.5 ND ND ---ND
12-Jun-13 5.4 5.5 ND ND ---ND
28-Oct-13 5.4 5.5 ND ND ---ND
6-May-14 5.4 5.5 ND ND ---ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
NC 2B = 0.24 (03/01/16)4-May-16 5.0 5.5 ND ND ND ND
14-Dec-16 5.0 5.5 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B ---2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J ---1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J
NC 2B = NE (05/01/07)15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J ---ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J ---ND
20-Dec-11 5.0 25.0 ND ND ---ND
30-May-12 5.0 25.0 ND ND ---ND
5-Dec-12 5.0 25.0 ND ND ---ND
12-Jun-13 5.0 25.0 7.6 J ND ---ND
28-Oct-13 5.0 25.0 ND ND ---ND
6-May-14 5.0 25.0 ND ND ---ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
4-May-16 2.5 25.0 10.9 J 11.4 J 23.9 J ND
14-Dec-16 2.5 25.0 ND ND ND ND
Zinc 30-May-07 --- 10 1.8 B ND ---1.6 J
29-Nov-07 --- 10 9.6 B ND ---3.1 J
29-May-08 0.40 10.0 6.0 B ND ---3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B ---2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B ---3.1 J
NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 ND ND ---ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND --- 76.5
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 36 µg/L Acute, Chronic (03/01/16)* 4-May-16 5.0 10.0 8.7 J 7.7 J 15.2 ND
14-Dec-16 5.0 10.0 ND ND 6.9 J ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
NC 2B = 1,100 mg/L (03/01/16) 4-May-16 10.0 100 ND ND ND ND
14-Dec-16 10.0 100 ND ND ND ---
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND
NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND
1-Jun-11 0.11 1.0 ND ND --- ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
NC 2B = NE (03/01/16) 4-May-16 0.11 1.0 ND ND ND ND
14-Dec-16 0.11 1.0 ND ND ND ---
Trichloroethene 14-Dec-16 0.47 1.0 ND 0.52 J ND ---
NC 2B = 30 µg/L (03/01/16)
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND
NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND
30-May-12 0.32 5.0 ND ND --- ND
5-Dec-12 0.32 5.0 ND 1.6 J --- ND
12-Jun-13 0.32 5.0 ND ND --- ND
28-Oct-13 0.32 5.0 ND 0.96 J --- ND
6-May-14 0.32 5.0 ND ND --- ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
NC 2B = 0.38 µg/L (03/01/16) 4-May-16 0.32 5.0 ND ND ND ND
14-Dec-16 0.32 5.0 ND 2.6 J ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 9
Joyce Engineering
APPENDIX G:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
NC 2B = NE (05/15/13)21-May-15 0.2 5.0 ND ND ND ND
9-Dec-15 0.2 5.0 ND ND ND ND
NC 2B = 60 µg/L (03/01/16)4-May-16 0.2 5.0 ND ND ND ND
14-Dec-16 0.2 5.0 ND 0.43 J ND ---
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
based on dissolved metal and in-stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
*NC 2B Groundwater Standards and Protective Values updated March 2016 to include acute and chronic exposure levels for designated metals
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 9 of 9
Joyce Engineering

Appendix H

Historical MNA Parameters

APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Temperature (FP)11/3/2006 oC 14.90 NS NS 15.25 16.97 16.52 NI NI
6/3/2009 oC 15.90 NS NS 19.10 19.40 14.50 16.20 16.30
11/17/2009 oC 12.0 NS NS 13.9 15.9 13.7 13.8 12.0
6/16/2010 oC 16.06 NS NS 17.65 17.8 17.69 18.83 16.3
12/1/2010 oC 13.43 NU NS 11.17 12.27 14.1 14.4 14.6
6/1/2011 oC 17.21 NU NS 18.39 17.59 21.68 15.04 16.57
12/20/2011 oC NS 14.30 NS 14.52 14.30 14.69 NS NS
5/30/2012 oC NS 18.18 NS 21.70 20.80 16.90 16.99 17.26
12/5/2012 oC NS 15.40 NS 15.00 15.50 16.90 NS NS
6/12/2013 oC NS 18.10 NS 18.70 18.20 16.30 NS NS
10/28/2013 oC NS 17.70 NS 18.40 18.20 17.50 17.40 17.10
5/6/2014 oC NS 16.90 NS 22.40 21.00 18.00 14.90 14.50
10/23/2014 oC NS * 17.20 13.00 11.50 9.80 NS NS
5/21/2015 oC NS 17.80 19.80 18.70 22.20 18.60 18.10 25.50
12/8/2015 oC NS 16.20 15.20 15.40 16.10 16.90 NS NS
5/3/2016 oC NS 17.5 17.9 17.0 18.4 17.2 13.7 15.8
12/13/2016 oC NS 14.1 14.4 14.9 14.9 14.8 NS NS
pH (FP)11/3/2006 S.U. 5.34 NS NS 5.32 5.40 5.68 NI NI
6/3/2009 S.U. 5.79 NS NS 5.74 5.62 5.96 6.20 6.28
11/17/2009 S.U. 6.03 NS NS 5.92 5.49 6.08 5.84 6.24
6/16/2010 S.U. 6.23 NS NS 6.37 6.28 5.64 6.28 6.05
12/1/2010 S.U. 5.40 NU NS 6.10 6.10 6.05 6.52 6.36
6/1/2011 S.U. 5.83 NU NS 6.01 5.96 5.87 6.25 6.24
12/20/2011 S.U. NS 6.12 NS 5.98 5.90 6.01 NS NS
5/30/2012 S.U. NS 6.61 NS 5.74 5.57 5.61 5.84 5.76
12/5/2012 S.U. NS 5.41 NS 6.12 5.93 5.75 NS NS
6/12/2013 S.U. NS 5.92 NS 6.00 5.32 5.57 NS NS
10/28/2013 S.U. NS 6.89 NS 5.85 5.88 5.76 6.12 6.22
5/6/2014 S.U. NS 5.37 NS 5.46 5.69 5.74 5.41 5.74
10/23/2014 S.U. NS * 5.52 5.80 5.64 5.41 NS NS
5/21/2015 S.U. NS 6.18 5.29 6.03 6.25 5.88 6.09 6.19
12/8/2015 S.U. NS 6.09 5.13 6.06 5.81 5.66 NS NS
5/3/2016 S.U. NS 19.70 4.83 5.54 5.34 5.06 5.30 5.29
12/13/2016 S.U. NS 6.45 5.17 6.05 6.22 5.77 NS NS
Specific Conductance (FP)11/3/2006 µS/cm 59 NS NS 133 95 207 NI NI
6/3/2009 µS/cm 139.5 NS NS 258 146.2 286 220 329
11/17/2009 µS/cm 182.7 NS NS 279 146.9 245 218 330
6/16/2010 µS/cm 124 NS NS 310 214 213 216 309
12/1/2010 µS/cm 143 NU NS 235 133 160 292 310
6/1/2011 µS/cm 69 NU NS 384 175 293 241 392
12/20/2011 µS/cm NS 26 NS 314 152 229 NS NS
5/30/2012 µS/cm NS 26.0 NS 392.0 177.0 229.0 227.0 256.0
12/5/2012 µS/cm NS 19.5 NS 370.1 148.8 197.4 NS NS
6/12/2013 µS/cm NS 29.8 NS 345.2 201.7 201.7 NS NS
10/28/2013 µS/cm NS 24.5 NS 430.0 189.5 229.9 215.6 295.2
5/6/2014 µS/cm NS 30.1 NS 460.7 208.5 230.4 179.0 276.9
10/23/2014 µS/cm NS * 68.1 311.0 170.2 103.8 NS NS
5/21/2015 µS/cm NS 19.8 27.2 435.4 221.5 231.2 262.0 412.2
12/8/2015 µS/cm NS 24.1 15.5 400.6 203.4 208.5 NS NS
5/3/2016 µS/cm NS 19.7 16.0 473.5 247.0 221.0 292.0 256.9
12/13/2016 µS/cm NS 66.0 180.4 458 198 215 NS NS
Background Downgradient Sentinel
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 1 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
ORP (FP)11/3/2006 mV 93.8 NS NS 143.9 90.5 43.2 NI NI
6/3/2009 mV 195.0 NS NS 150.0 130.0 138.0 132.0 113.0
11/17/2009 mV 167.0 NS NS 133.0 162.0 132.0 158.0 128.0
6/16/2010 mV 13.8 NS NS -12.5 -58.6 -73.4 -36.8 -63.5
12/1/2010 mV 31.6 NU NS -49.1 -74.7 -105.9 NS NS
6/1/2011 mV 73.2 NU NS 28.6 -7.2 40.1 10.3 -2.6
12/20/2011 mV NS 56.8 NS 18.7 30.3 3.9 NS NS
5/30/2012 mV NS 7.1 NS -14.8 38.9 21.7 26.70 20.10
12/5/2012 mV NS 227.2 NS -6.9 46.0 23.4 NS NS
6/12/2013 mV NS 104.7 NS -38.0 29.6 86.4 NS NS
10/28/2013 mV NS 21.7 NS -10.5 53.2 47.3 -7.20 5.40
5/6/2014 mV NS 116.5 NS 21.0 29.7 228.0 94.20 33.90
10/23/2014 mV NS * 104.6 -2.3 -3.8 36.6 NS NS
5/21/2015 mV NS 61.80 136.8 21.9 66.0 46.9 66.00 12.50
12/8/2015 mV NS 148.80 269.9 -21.4 -6.2 25.7 NS NS
5/3/2016 mV NS 81.70 80.4 14.1 29.3 57.3 29.9 45.7
12/13/2016 mV NS 217.40 180.4 29.0 18.1 70.9 NS NS
Turbidity (FP)11/3/2006 ntu 10.4 NS NS 7.97 64.0 16.3 NI NI
6/3/2009 ntu 154 NS NS 20.6 7.54 39.1 390 125
11/17/2009 ntu 318 NS NS 19.65 7.89 23.0 <100 22.2
6/16/2010 ntu 44.8 NS NS 165 95.9 43.2 14.9 9.29
12/1/2010 ntu 20.2 NU NS 31 46.4 43.1 >1000 463
6/1/2011 ntu 7.58 NU NS 19.06 13.14 5.74 33.4 59.6
12/20/2011 ntu NS 80.4 NS 46.30 36.70 24.80 NS NS
5/30/2012 ntu NS 14.0 NS 19.80 33.50 15.90 20.60 27.30
12/5/2012 ntu NS 631 NS 19.50 23.50 7.14 NS NS
6/12/2013 ntu NS 21.3 NS 10.82 15.80 8.11 NS NS
10/28/2013 ntu NS 7.39 NS 8.30 6.41 4.31 4.62 14.30
5/6/2014 ntu NS 37.1 NS 12.95 6.05 4.29 37.00 9.20
10/23/2014 ntu NS * 8.15 21.7 10.04 7.55 NS NS
5/21/2015 ntu NS 27.10 8.15 12.6 17.50 7.72 9.10 11.13
12/8/2015 ntu NS 55.60 25.5 16.7 35.40 30.50 NS NS
5/3/2016 ntu NS 29.20 17.55 19.75 16.88 18.30 21.30 28.10
12/13/2016 ntu NS 17.55 12.63 9.48 10.20 9.70 NS NS
Dissolved Oxygen (FP)11/3/2006 mg/l 4.01 NS NS 0.95 1.21 1.10 NI NI
6/3/2009 mg/l 1.21 NS NS 0.84 0.57 0.99 1.38 0.60
11/17/2009 mg/l NS NS NS 2.35 4.12 3.50 2.23 3.20
6/16/2010 mg/l 4.61 NS NS 2.49 2.86 2.10 3.59 4.16
12/1/2010 mg/l 7.94 NU NS 1.29 1.29 5.15 NS NS
6/1/2011 mg/l 4.76 NU NS 2.46 1.77 1.64 3.80 3.27
12/20/2011 mg/l NS 8.18 NS 1.87 2.17 2.17 NS NS
5/30/2012 mg/l NS 6.24 NS 3.67 6.33 1.98 8.47 8.11
12/5/2012 mg/l NS 7.29 NS 2.09 3.57 0.99 NS NS
6/12/2013 mg/l NS 8.68 NS 1.53 1.25 1.75 NS NS
10/28/2013 mg/l NS 7.14 NS 3.42 2.47 2.82 3.62 3.21
5/6/2014 mg/l NS 7.83 NS 1.89 1.47 1.33 2.25 1.86
10/23/2014 mg/l NS * 5.74 2.78 1.36 2.75 NS NS
5/21/2015 mg/l NS 0.10 5.66 1.01 1.79 0.01 1.01 0.10
12/8/2015 mg/l NS 7.53 7.59 4.62 2.47 1.49 NS NS
5/3/2016 mg/l NS 9.55 7.26 1.60 2.23 3.35 4.19 2.20
12/13/2016 mg/l NS 7.69 5.41 5.11 3.23 2.07 NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 2 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Carbon Dioxide (FP)11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 170 NS NS 295 255 325 185 315.00
11/17/2009 mg/l 220 NS NS 355 335 385 NS 280
6/16/2010 mg/l 220 NS NS 510 395 430 185 280
12/1/2010 mg/l 25 NU NS 440 285 230 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS 25.0 NS 80 95 90 NS NS
10/28/2013 mg/l NS 25.0 NS 335 240 130 160 130
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS 30 95 85 155 220 150
12/13/2016 mg/l NS NS NS NS NS NS NS NS
Iron II (ferrous iron) (FP)11/3/2006 mg/l NS NS NS 0.5 6.4 7.5 NI NI
6/3/2009 mg/l 0.0 NS NS 5.9 9.5 9.4 7.2 9.4
11/17/2009 mg/l 0.0 NS NS 5.0 6.8 4.0 4.0 6.0
6/16/2010 mg/l 6.5 NS NS 8.0 6.5 4.0 5.0 8.8
12/1/2010 mg/l 0.0 NU NS 6.2 4.6 10.0 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS 0.0 NS 6.1 4.5 5.6 NS NS
5/30/2012 mg/l NS 0.0 NS 5.6 3.8 5.2 3.20 3.30
12/5/2012 mg/l NS 0.0 NS 5.2 4.0 6.3 NS NS
6/12/2013 mg/l NS 0.0 NS 6.0 4.2 3.0 NS NS
10/28/2013 mg/l NS 0.0 NS 5.5 9.0 4.8 6.5 6.0
5/6/2014 mg/l NS 0.0 NS 7.3 4.3 5.8 5.0 5.8
10/23/2014 mg/l NS * 0.0 4.5 7.0 3.75 NS NS
5/21/2015 mg/l NS NS 0.0 5.8 7.0 7.0 4.7 5.8
12/8/2015 mg/l NS NS 0.0 3.5 2.0 3.2 NS NS
5/3/2016 mg/l NS NS 0.8 4.5 5.0 3.5 3.4 4.0
12/13/2016 mg/l NS NS 0.5 5.2 3.0 2.2 NS NS
Nitrate 11/3/2006 mg/l NS NS NS <0.5 <0.5 <0.5 NI NI
6/3/2009 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 0.26
11/17/2009 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
6/16/2010 mg/l <0.1 NS NS <0.1 <0.1 <0.1 <0.1 <0.1
12/1/2010 mg/l <0.1 NU NS <0.1 <0.1 <0.1 NS NS
6/1/2011 mg/l <0.1 NU NS <0.1 <0.1 <0.1 <0.1 <0.1
12/20/2011 mg/l NS <0.1 NS <0.1 <0.1 <0.1 NS NS
5/30/2012 mg/l NS .207 J NS <0.1 <0.1 <0.1 <0.1 <0.1
12/5/2012 mg/l NS .294 J NS <0.1 <0.1 <0.1 NS NS
6/12/2013 mg/l NS .384 J NS <0.1 <0.1 <0.1 NS NS
10/28/2013 mg/l NS .333 J NS <0.1 <0.1 <0.1 <0.1 <0.1
5/6/2014 mg/l NS .282 J NS <0.1 <0.1 <0.1 <0.1 <0.1
10/23/2014 mg/l NS * <0.1 <0.1 <0.1 <0.1 NS NS
5/21/2015 mg/l NS <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
12/8/2016 mg/l NS NS .256 J <0.1 <0.1 <0.1 NS NS
5/3/2016 mg/l NS NS 0.120 J ND ND ND <0.1 <0.1
12/13/2016 mg/l NS NS 0.210 J ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 3 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Alkalinity 11/3/2006 mg/l NS NS NS 47 36 106 NI NI
6/3/2009 mg/l 163 NS NS 112 62.5 76.6 80.8 128
11/17/2009 mg/l 70.8 NS NS 121 50.0 83.3 81.2 115
6/16/2010 mg/l 61.2 NS NS 154 59.1 111 74.7 185
12/1/2010 mg/l 35.2 NU NS 156 86.9 64.4 NS NS
6/1/2011 mg/l 45.1 NU NS 177 70.7 109 84.6 132
12/20/2011 mg/l NS 8.58 NS 189 70.8 77.2 NS NS
5/30/2012 mg/l NS 8.14 NS 200 76.7 104 107.0 150.0
12/5/2012 mg/l NS 7.69 NS 178 76.6 106 NS NS
6/12/2013 mg/l NS 7.95 NS 202 111 99.7 NS NS
10/28/2013 mg/l NS 8.14 NS 197 91.3 116 NS NS
5/6/2014 mg/l NS 8.06 NS 208 90.6 119 68.90 113.0
10/23/2014 mg/l NS * 1.36 J 215 96.1 122 NS NS
5/21/2015 mg/l NS 6.54 ND 153.000 67.500 92.100 51.300 154.000
12/8/2015 mg/l NS 8.280 1.030 J 202.000 88.800 95.900 NS NS
5/3/2016 mg/l NS NS 1.370 J 122.000 49.000 76.800 62.500 100.000
12/13/2016 mg/l NS 6.190 1.190 J 106.000 45.600 77.600 NS NS
Chloride 11/3/2006 mg/l NS NS NS 9.30 1.69 2.49 NI NI
6/3/2009 mg/l <5.0 NS NS 16.1 <5.0 6.7 5.9 <5.0
11/17/2009 mg/l <5.0 NS NS 16.8 <5.0 <5.0 6.8 <5.0
6/16/2010 mg/l <5.0 NS NS 5.45 6.29 8.55 8.23 <5.0
12/1/2010 mg/l <5.0 NU NS 15.1 6.84 <5.0 NS NS
6/1/2011 mg/l <5.0 NU NS 17.0 6.33 7.87 9.45 <5.0
12/20/2011 mg/l NS <5.0 NS 20.2 6.40 6.53 NS NS
5/30/2012 mg/l NS 1.48 NS 20.0 6.32 5.84 133.0 2.79
12/5/2012 mg/l NS 2.13 NS 19.5 7.29 7.43 NS NS
6/12/2013 mg/l NS 1.38 NS 19.5 7.50 5.1 NS NS
10/28/2013 mg/l NS 1.12 NS 18.1 7.75 8.49 NS NS
5/6/2014 mg/l NS ND NS 18.2 8.14 8.92 13.50 2.41
10/23/2014 mg/l NS * ND 20.8 9.05 8.12 NS NS
5/21/2015 mg/l NS 1.550 ND 25.300 9.680 10.400 12.400 2.500
12/8/2015 mg/l NS 1.840 0.859 J 30.800 9.400 4.190 NS NS
5/3/2016 mg/l NS NS 6.07 33.700 14.000 7.980 13.600 7.150
12/13/2016 mg/l NS 1.460 1.330 30.300 10.700 8.240 NS NS
Sulfate 11/3/2006 mg/l NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/l <5.1 NS NS <5.0 <5.0 <5.0 5.8 ND
11/17/2009 mg/l <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
6/16/2010 mg/l <5.0 NS NS <5.0 <5.0 <5.0 <5.0 <5.0
12/1/2010 mg/l <2.5 NU NS <12.5 <12.5 <12.5 NS NS
6/1/2011 mg/l <5.0 NU NS <5.0 <5.0 <5.0 <5.0 <5.0
12/20/2011 mg/l NS <5.0 NS <5.0 <5.0 <5.0 NS NS
5/30/2012 mg/l NS <5.0 NS <5.0 <5.0 <5.0 <5.0 <5.0
12/5/2012 mg/l NS ND NS ND 4.4 J ND NS NS
6/12/2013 mg/l NS ND NS 3.08 J 2.91 J ND NS NS
10/28/2013 mg/l NS ND NS ND 2.94 J ND NS NS
5/6/2014 mg/l NS ND NS 2.30 J 3.72 J 2.07 J ND 2.49 J
10/23/2014 mg/l NS * ND 2.28 J 3.74 J 1.94 J NS NS
5/21/2015 mg/l NS ND ND 2.310 J 3.440 J 2.750 J 1.700 J 1.980 J
12/8/2015 mg/l NS ND ND 1.530 J 2.020 J 9.260 J NS NS
5/3/2016 mg/l NS 1.270 J 1.090 J 5.490 J 3.440 J 8.720 J 2.900 J 3.020 J
12/13/2016 mg/l NS 1.530 J ND 3.500 J 4.020 J 10.700 J NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 4 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Sulfide 11/3/2006 mg/l NS NS NS 3.72 <2 <2 NI NI
6/3/2009 mg/l <0.10 NS NS <0.10 <0.10 <0.10 <0.10 ND
11/17/2009 mg/l <0.10 NS NS <0.10 <0.10 <0.10 NS NS
6/16/2010 mg/l <0.10 NS NS <0.10 <0.10 <0.10 <0.10 <0.10
12/1/2010 mg/l <0.10 NU NS <0.10 <0.10 <0.10 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS ND NS ND ND ND NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS ND ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * ND ND ND ND NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS ND ND ND ND NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
Methane 11/3/2006 mg/l NS NS NS 2.23 2.50 2.92 NI NI
6/3/2009 mg/l 0.340 NS NS 0.111 8.61 8.26 0.494 0.814
11/17/2009 mg/l 2.580 NS NS 4.310 0.147 10.300 1.200 0.271
Resample 1/19/2010 mg/l NS NS NS NS 2.120 NS NS NS
6/16/2010 mg/l 0.750 NS NS 4.600 6.000 6.200 1.000 1.100
12/1/2010 mg/l 1.35 NU NS 3.04 6.0 6.65 NS NS
6/1/2011 mg/l 2.1 NU NS 0.157 0.0128 <0.010 0.899 2.64
12/20/2011 mg/l NS <0.005 NS 1.460 6.300 5.650 NS NS
5/30/2012 mg/l NS 0.0061 NS 0.883 6.130 3.760 0.46 0.718
12/5/2012 mg/l NS ND NS 2.070 2.050 4.910 NS NS
6/12/2013 mg/l NS 0.0063 NS 0.964 8.900 11.400 NS NS
10/28/2013 mg/l NS ND NS .0033 J 2.610 0.173 0.0581 0.0085
5/6/2014 mg/l NS ND NS 2.040 6.190 4.360 0.3850 1.5900
10/23/2014 mg/l NS * 5.93 2.21 ND 5.61 NS NS
5/21/2015 mg/l NS 0.0018 J 0.0012 J 2.270 6.700 4.940 0.136 3.060
12/8/2015 mg/l NS NS 0.0020 J 0.959 0.796 7.510 NS NS
5/3/2016 mg/l NS NS 0.0014 J 1.880 5.350 5.160 0.457 0.514
12/13/2016 mg/l NS NS NS 3.050 8.940 17.300 NS NS
Ethane 11/3/2006 mg/l NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/l NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/l <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/l <0.0022 NU NS <0.0022 <0.0022 <0.0022 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS .0016 J ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2016 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 5 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Ethylene (Ethene)11/3/2006 mg/l NS NS NS <0.002 <0.002 <0.002 NI NI
6/3/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
11/17/2009 mg/l <0.005 NS NS <0.005 <0.005 <0.005 <0.005 <0.005
Resample 1/19/2010 mg/l NS NS NS NS <0.005 NS NS NS
6/16/2010 mg/l <0.013 NS NS <0.013 <0.011 <0.011 <0.013 <0.013
12/1/2010 mg/l <0.0018 NU NS <0.0018 <0.0018 <0.0018 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS .0017 J ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
Dissolved Hydrogen 11/3/2006 nM NS NS NS NS NS NS NI NI
6/3/2009 nM 0.480 J NS NS 0.720 <0.600 0.350 J 0.580 J 0.790
11/17/2009 nM 0.780 NS NS 0.850 0.690 1.000 1.200 0.630
6/16/2010 nM 4.800 NS NS 3.400 2.800 2.200 2.800 3.300
12/1/2010 nM 1.500 NU NS 0.850 0.740 0.950 NS NS
6/1/2011 nM 2.300 NU NS 2.400 1.900 2.200 2.100 2.000
12/20/2011 nM NS 21 NS 19 6.3 7.0 NS NS
5/30/2012 nM NS 0.74 NS 2.0 1.1 0.84 0.79 0.76
12/5/2012 nM NS 1.7 NS 0.5 J 0.35 J 0.57 J NS NS
6/12/2013 nM NS 1.1 NS 1.1 0.83 1.60 NS NS
10/28/2013 nM NS 0.61 NS 0.61 0.55 J 0.52 J 0.56 J 0.68
5/6/2014 nM NS 0.61 NS 0.82 1.1 J 1.1 J 0.61 3.50
10/23/2014 nM NS * 0.75 0.86 0.85 1.2 NS NS
5/21/2015 nM NS NS 1.7 1.3 1.1 1.6 1.6 1.2
12/8/2016 nM NS NS 2.0 1.6 2.3 1.9 NS NS
5/3/2016 nM NS NS 0.97 0.86 0.82 0.77 0.80 0.80
12/13/2016 nM NS NS 1.9 2.0 1.5 1.3 NS NS
Volatile Fatty Acids 11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 10.9 NS NS 0.5 J ND ND ND ND
11/17/2009 mg/l 0.9 J NS NS ND 0.6 J ND 0.9 J ND
6/16/2010 mg/l ND NS NS 32.0 ND 1.3 0.8 J 5.2
12/1/2010 mg/l ND NU NS ND ND 6.4 J NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS NS NS NS NS NS NS NS
5/30/2012 mg/l NS NS NS NS NS NS NS NS
12/5/2012 mg/l NS NS NS NS NS NS NS NS
6/12/2013 mg/l NS ND NS ND ND ND NS NS
10/28/2013 mg/l NS ND NS ND ND ND ND ND
5/6/2014 mg/l NS NS NS NS NS NS NS NS
10/23/2014 mg/l NS * NS NS NS NS NS NS
5/21/2015 mg/l NS NS NS NS NS NS NS NS
12/8/2015 mg/l NS NS NS NS NS NS NS NS
5/3/2016 mg/l NS NS ND ND ND ND ND ND
12/13/2016 mg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 6 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
TOC 11/3/2006 mg/l NS NS NS NS NS NS NI NI
6/3/2009 mg/l 9.4 NS NS 11.1 10.1 17.8 8.6 14.2
11/17/2009 mg/l 2.1 NS NS 13.1 12.6 14.6 3.9 11.4
6/16/2010 mg/l 24.9 NS NS 12.9 8.66 11.1 6.4 16.8
12/1/2010 mg/l 17.6 NU NS 29.3 23.4 43.8 NS NS
6/1/2011 mg/l NS NU NS NS NS NS NS NS
12/20/2011 mg/l NS 6.53 NS 13.6 12.2 16.1 NS NS
5/30/2012 mg/l NS 6.49 NS 12.5 12.1 14.5 6.55 10.90
12/5/2012 mg/l NS ND NS 13.1 13.1 16.0 NS NS
6/12/2013 mg/l NS ND NS 13.3 12.9 18.3 NS NS
10/28/2013 mg/l NS ND NS 15.3 12.9 15.2 7.5 14.7
5/6/2014 mg/l NS ND NS 17.6 12.0 19.9 9.54 11.3
10/23/2014 mg/l NS * 27.0 35.7 66.4 33.2 NS NS
5/21/2015 mg/l NS ND ND 4.410 4.580 3.880 2.530 8.580
12/8/2016 mg/l NS ND ND 5.320 -- 6.070 NS NS
5/3/2016 mg/l NS NS 0.528 J 4.330 2.380 6.080 2.010 3.520
12/13/2016 mg/l NS NS 0.70 J 4.0 3.7 3.6 NS NS
Tetrachloroethene (PCE) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l 2.1 NS NS ND 0.70 J ND ND ND
11/17/2009 µg/l 2.6 NS NS ND 0.49 J ND ND ND
6/16/2010 µg/l 1.2 NS NS ND 0.46 J ND ND ND
12/1/2010 µg/l 3.0 NU NS ND ND ND NS NS
6/1/2011 µg/l 3.6 NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS 0.59 J 0.70 J ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND ND ND
5/6/2014 µg/l NS ND NS ND ND ND ND ND
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND ND ND
12/8/2016 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
Trichloroethene (TCE) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l 1.8 NS NS 3.6 4.3 1.4 ND ND
11/17/2009 µg/l 1.9 NS NS 3.3 3.3 1.2 ND ND
6/16/2010 µg/l 0.61 J NS NS 5.1 3.3 1.4 ND ND
12/1/2010 µg/l 1.9 NU NS 3.7 3.3 ND NS NS
6/1/2011 µg/l 2.0 NU NS 2.8 3.2 ND ND ND
12/20/2011 µg/l NS ND NS 2.5 3.5 1.1 NS NS
5/30/2012 µg/l NS ND NS 2.5 2.6 0.55 J ND ND
12/5/2012 µg/l NS ND NS 2.3 3.3 0.67 J NS NS
6/12/2013 µg/l NS ND NS 2.1 1.8 0.76 J NS NS
10/28/2013 µg/l NS ND NS 3.1 2.5 0.76 J ND ND
5/6/2014 µg/l NS ND NS 2.0 2.6 0.60 J ND ND
10/23/2014 µg/l NS * ND 1.3 2.2 0.86 J NS NS
5/21/2015 µg/l NS ND ND 0.9 J 2.3 ND ND ND
12/8/2016 µg/l NS ND ND 0.71 J 1.4 ND NS NS
5/3/2016 µg/l NS NS ND 0.63 J 1.8 ND ND ND
12/13/2016 µg/l NS NS ND 0.56 J 2.1 0.64 J NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 7 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
1,2-Dichloroethene (DCE) 11/3/2006 µg/l ND NS NS 16 12 17 NI NI
(Total including all isomers) 6/3/2009 µg/l 0.71 J NS NS 13.3 12.1 10.6 3.9 J ND
11/17/2009 µg/l 2.8 J NS NS 12.5 20.3 11.1 NS NS
6/16/2010 µg/l 1.7 J NS NS 14.9 15.6 9.9 4.5 J ND
12/1/2010 µg/l 0.66 J NU NS 11.5 9.3 7.4 NS NS
6/1/2011 µg/l 0.66 J NU NS 14.6 13.9 5.7 4.6 J ND
12/20/2011 µg/l NS ND NS 9.7 9.8 6.6 NS NS
5/30/2012 µg/l NS ND NS 11.8 11.2 6.8 ND ND
12/5/2012 µg/l NS ND NS 9.1 10.07 6.6 NS NS
6/12/2013 µg/l NS ND NS 9.0 12.8 6.2 NS NS
10/28/2013 µg/l NS ND NS 11.2 14.0 7.7 NS NS
5/6/2014 µg/l NS ND NS 9.5 13.0 7.7 NS NS
10/23/2014 µg/l NS * ND 8.0 10.1 7.1 NS NS
5/21/2015 µg/l NS ND ND 6.7 7.6 4.2 NS NS
12/8/2015 µg/l NS ND ND 0.65 J ND 1.3 NS NS
5/3/2016 µg/l NS NS ND 5.9 9.6 4.6 1.5 J ND
12/13/2016 µg/l NS NS ND 5.7 9.8 6.1 NS NS
Vinyl Chloride (VC) 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND 0.95 J 2.0 ND ND
11/17/2009 µg/l 0.69 J NS NS 0.66 J 1.6 2.5 ND ND
6/16/2010 µg/l ND NS NS ND 1.1 2.1 ND ND
12/1/2010 µg/l ND NU NS 0.65 J 0.93 J 3.5 NS NS
6/1/2011 µg/l ND NU NS 0.87 J 1.1 1.8 ND ND
12/20/2011 µg/l NS ND NS 0.63 J ND 1.4 NS NS
5/30/2012 µg/l NS ND NS ND ND 1.6 ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND 0.96 J 2.10 NS NS
10/28/2013 µg/l NS ND NS ND 0.74 J 1.3 ND ND
5/6/2014 µg/l NS ND NS ND 0.77 J 1.8 ND ND
10/23/2014 µg/l NS * ND ND ND 1.3 NS NS
5/21/2015 µg/l NS ND ND ND ND 1.1 ND ND
12/8/2015 µg/l NS 0.72 J ND ND ND 1.4 NS NS
5/3/2016 µg/l NS NS ND ND 0.74 J 1.2 ND ND
12/13/2016 µg/l NS NS ND ND ND 0.9 J NS NS
1,1,1-Trichloroethane 11/3/2006 µg/l ND NS NS ND ND ND NI NI
(TCA) 6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l ND NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l ND NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND NS NS
5/6/2014 µg/l NS ND NS ND ND ND NS NS
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
Burke Co.- Johns River C and D-over-MSWLF
Permit No. 12-03 Page 8 of 10
Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
1,1-Dichloroethane 11/3/2006 µg/l ND NS NS 12 34 33 NI NI
(DCA)6/3/2009 µg/l 6.3 NS NS 8.2 47.8 32.0 3.9 J 2.8 J
11/17/2009 µg/l 10.8 NS NS 6.7 41.9 29.4 6.7 3.7 J
6/16/2010 µg/l 3.9 J NS NS 5.7 35.7 32.1 4.4 J 2.3 J
12/1/2010 µg/l 6.8 NU NS 5.4 41.3 16.9 NS NS
6/1/2011 µg/l 9.3 NU NS 6.8 45.5 19.1 2.8 J 2.6 J
12/20/2011 µg/l NS ND NS 5.1 39.7 26.2 NS NS
5/30/2012 µg/l NS ND NS 5.9 38.2 24.1 1.6 J 2.7 J
12/5/2012 µg/l NS ND NS 4.6 J 39.3 26.5 NS NS
6/12/2013 µg/l NS ND NS 5.3 37.1 21.4 NS NS
10/28/2013 µg/l NS ND NS 4.6 J 43.2 26.2 0.93 J 3.0 J
5/6/2014 µg/l NS ND NS 4.0 J 43.4 21.5 1.2 J 2.9 J
10/23/2014 µg/l NS * ND 3.6 J 34.4 25.3 NS NS
5/21/2015 µg/l NS ND ND 2.8 J 26.7 17.3 ND 1.7 J
12/8/2015 µg/l NS ND ND 3.2 J 31.7 10.3 NS NS
5/3/2016 µg/l NS NS ND ND ND ND 0.44 J 2.5 J
12/13/2016 µg/l NS NS ND 3.0 J 27.4 22.1 NS NS
Chloroethane 11/3/2006 µg/l ND NS NS ND ND ND NI NI
(CA)6/3/2009 µg/l 1.1 J NS NS ND ND 4.4 J 4.3 J ND
11/17/2009 µg/l 3.1 J NS NS 0.63 J 5.5 J 3.5 J 2.9 J 0.90 J
6/16/2010 µg/l 1.7 J NS NS 0.88 J 3.1 J 2.2 J 2.6 J 0.80 J
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l 1.5 J NU NS ND 2.7 J ND 3.6 J 0.85 J
12/20/2011 µg/l NS ND NS ND 2.1 J 2.9 J NS NS
5/30/2012 µg/l NS ND NS ND 1.5 J ND ND ND
12/5/2012 µg/l NS ND NS ND 1.8 J 1.9 J NS NS
6/12/2013 µg/l NS ND NS ND 0.63 J 1.5 J NS NS
10/28/2013 µg/l NS ND NS ND 1.9 J ND NS NS
5/6/2014 µg/l NS ND NS ND 1.6 J 1.3 J NS NS
10/23/2014 µg/l NS * ND ND ND 1.6 J NS NS
5/21/2015 µg/l NS ND ND ND ND 1.6 J NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND 3.0 J 1.7 J NS NS
Chloroform 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l ND NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l ND NU NS ND ND ND NS NS
6/1/2011 µg/l ND NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND NS NS
5/6/2014 µg/l NS ND NS ND ND ND NS NS
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND NS NS
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
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Joyce Engineering
APPENDIX H:
HISTORICAL MONITORED NATURAL ATTENUATION PARAMETERS
Analyte/Parameter Date Units MW-17 MW-20 MW-21 MW-11 MW-12 MW-16S MW-18 MW-19
Methylene Chloride 11/3/2006 µg/l ND NS NS ND ND ND NI NI
6/3/2009 µg/l ND NS NS ND ND ND ND ND
11/17/2009 µg/l 11.1 NS NS ND ND ND ND ND
6/16/2010 µg/l ND NS NS ND ND ND ND ND
12/1/2010 µg/l 2.2 NU NS ND ND ND NS NS
6/1/2011 µg/l 2.3 NU NS ND ND ND ND ND
12/20/2011 µg/l NS ND NS ND ND ND NS NS
5/30/2012 µg/l NS ND NS ND ND ND ND ND
12/5/2012 µg/l NS ND NS ND ND ND NS NS
6/12/2013 µg/l NS ND NS ND ND ND NS NS
10/28/2013 µg/l NS ND NS ND ND ND ND ND
5/6/2014 µg/l NS ND NS ND ND ND ND ND
10/23/2014 µg/l NS * ND ND ND ND NS NS
5/21/2015 µg/l NS ND ND ND ND ND ND ND
12/8/2015 µg/l NS ND ND ND ND ND NS NS
5/3/2016 µg/l NS NS ND ND ND ND ND ND
12/13/2016 µg/l NS NS ND ND ND ND NS NS
Notes:
(FP) = Field Parameter
ND = Not Detected
NS = Not Sampled
mV = millivolts
S.U. = standard units
oC = degrees Celcius
mS/cm = microsiemens per centimeter
mg/l = milligrams per liter (parts per million)
µg/l = micrograms per liter (parts per billion)
NU = Not Used as background data until approved
* MW-21 replaced MW-20 as the background well starting with the Fall 2014 sampling event; however MW-20 continues to be sampled as a compliance well
for the C&D Expansion (Phase 1A).
May 20, 2015: Shaded dissolved oxygen results are suspect. The DO Sensor began reading very low, re-calibration attempts did not appear to correct the issue.
A short in the DO probe was diagnosed after the field event.
-- MW-12 TOC sample for 12/08/15 was broken in transit to the laboratory and could not be analyzed.
Burke Co.- Johns River C and D-over-MSWLF
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Joyce Engineering