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6301_MooreCDLF_ASDForVOCs_DIN28496_20170228
Golder, Golder Associates and the GA globe design are trademarks of Golder Associates Corporation ALTERNATE SOURCE DEMONSTRATION FOR THE CONSTRUCTION AND DEMOLITION LANDFILL Moore County Landfill Solid Waste Permit No. 63-01 Aberdeen, North Carolina Submitted To: Moore County Public Works 5227 Highway 15-501 Carthage, North Carolina 28327 USA Submitted By: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA Distribution: February 2017 0739615016.400 Alternate Source Demonstration February 2017 i 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx Table of Contents 1.0 INTRODUCTION .............................................................................................................................. 1 2.0 SITE HISTORY AND BACKGROUND ............................................................................................. 2 2.1 MSW and C&D Compliance Monitoring History ........................................................................... 2 2.2 Hydrogeologic Setting .................................................................................................................. 4 3.0 CONSTITUENTS-OF-CONCERN ................................................................................................... 6 3.1 Acetone ........................................................................................................................................ 6 3.2 Benzene ....................................................................................................................................... 6 3.3 Chlorobenzene ............................................................................................................................. 7 3.4 Chloroethane ................................................................................................................................ 7 3.5 1,2-Dichlorobenzene .................................................................................................................... 8 3.6 1,4-Dichlorobenzene .................................................................................................................... 8 3.7 1,1-Dichloroethane ....................................................................................................................... 8 3.8 Cis-1,2-Dichloroethene ................................................................................................................ 9 3.9 Tetrachloroethene ........................................................................................................................ 9 3.10 Trichloroethene .......................................................................................................................... 10 3.11 Vinyl Chloride ............................................................................................................................. 10 3.12 Total Xylenes.............................................................................................................................. 10 4.0 VOC SOURCE EVALUATION SENARIOS ................................................................................... 12 4.1 Scenario 1 – Closed MSW Landfill Leachate ............................................................................. 12 4.2 Scenario 2 – Closed MSW Landfill Gas ..................................................................................... 12 4.3 Scenario 3 – C&D Landfill Leachate or Landfill Gas .................................................................. 12 5.0 ASD INVESTIGATIVE ACTIVITIES ............................................................................................... 13 5.1 Groundwater Sampling .............................................................................................................. 13 5.2 Soil-gas or Headspace Sampling ............................................................................................... 14 5.3 Leachate Sampling .................................................................................................................... 14 6.0 ANALYTICAL RESULTS................................................................................................................ 16 6.1 Groundwater Sampling Results ................................................................................................. 16 6.2 Soil-Gas Sampling Results ........................................................................................................ 16 6.3 Leachate Sampling Results ....................................................................................................... 16 7.0 DATA EVALUATION ...................................................................................................................... 17 7.1 Landfill Gas Source Evaluation .................................................................................................. 17 7.1.1 Methane Concentration Analysis ........................................................................................... 17 7.1.2 Henry’s Law Calculations (Groundwater to Soil-Gas) ........................................................... 18 7.1.3 Henry’s Law Calculations (Soil-gas to Groundwater) ............................................................ 19 7.2 Leachate Source Evaluation ...................................................................................................... 19 7.2.1 Direct Comparison MSW vs C&D Leachate .......................................................................... 20 7.2.2 Piper Plot Analysis ................................................................................................................. 20 February 2017 ii 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 7.2.3 Stiff Diagram Analysis ............................................................................................................ 21 7.2.4 Mixing Analysis ...................................................................................................................... 21 7.3 Groundwater Modeling ............................................................................................................... 22 7.4 Historical Data Review and Evaluation ...................................................................................... 23 8.0 CONCLUSIONS AND RECOMMENDATIONS.............................................................................. 24 9.0 REFERENCES ............................................................................................................................... 26 List of Tables Table 1 Summary of Monitoring Well Construction Information Table 2 Summary of Groundwater Elevations Table 3 Summary of Groundwater Flow Calculations Table 4 Summary of Historical VOC Detections in Groundwater Table 5 Summary of Historical Groundwater Field Parameters Table 6 September 2016 ASD Groundwater Sampling Results Summary Table 7 September 2016 ASD Soil-Gas (or Headspace) Sampling Results Summary Table 8 September 2016 ASD Leachate Sampling Results Summary Table 9 April 2016 Dissolved Methane Results and Headspace Methane Readings Table 10 Henry’s Law Calculations (Groundwater to Soil-Gas) Table 11 Henry’s Law Calculations (Soil-Gas to Groundwater) Table 12 Mixing Calculations (C&D Leachate and Background) Table 13 Mixing Calculations (MSW Leachate and Background) List of Figures Figure 1 Site Location Map Figure 2 Geologic Map Figure 3 Groundwater Surface Contour Map - April 11, 2016 Figure 4 Piper Plot Figure 5 Fixed Scale Stiff Diagrams (Leachate and Groundwater Samples) Figure 6 Variable (or Sliding) Scale Stiff Diagrams (Leachate and Groundwater Samples) Figure 7 Variable (or Sliding) Scale Stiff Diagrams (Mixing Leachate and Groundwater) Figure 8 Groundwater Model Results Summary (Summer) Figure 9 Groundwater Model Results Summary (Winter) List of Appendices Appendix A Boring Logs Appendix B Field Sampling Logs Appendix C Laboratory Certificates-of-Analysis, Laboratory Sample Receipt Summaries, and Chain-of- Custody Forms Appendix D Groundwater Model (Raw Data and Input/ Output Files) February 2017 1 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 1.0 INTRODUCTION Golder Associates NC, Inc. (“Golder”) is submitting this Alternate Source Demonstration (ASD) on behalf of the County in response to a letter received from the North Carolina (NC) Division of Environmental Quality (DEQ), formerly the NC Department of Environment and Natural Resources, on March 14, 2016, with regard to the status of the water quality monitoring program at the Moore County landfill, North Carolina Solid Waste Permit (NCSWP) No. 63-01. In this letter, NC DEQ requested that the County take one of two actions (presented below) in response to volatile organic compounds (VOCs) detected in samples from the active construction and demolition (C&D) landfill monitoring wells: Establish an assessment monitoring program in accordance 15A NCAC 13B .0545 for the C&D landfill; or Demonstrate that a source other than the C&D landfill caused the contamination by submitting an ASD report. In response to this request, the County has elected to submit this ASD to demonstrate that the VOCs detected within the C&D compliance monitoring network pre-date the C&D landfill operation. In addition, the data collected since the initiation of corrective action at the landfill in 2005 have supported that the groundwater impacts observed in the C&D groundwater monitoring network originate from the closed municipal solid waste (MSW) landfill, which is located directly upgradient of the County’s active C&D landfill. February 2017 2 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 2.0 SITE HISTORY AND BACKGROUND The Moore County Landfill (hereafter referred to as the “facility” or the “site”) is situated on approximately 314 acres and contains two solid waste disposal units: the closed MSW landfill (which is located on the eastern side of the facility and has a waste footprint of approximately 60 acres) and the active C&D landfill (which is located on the western side of the facility and has a waste footprint of approximately 18 acres). In accordance with the Water Quality Monitoring Plan (WQMP), dated June 2006, the facility is currently monitored under title 15A NCAC 13B.600 Rules. At the request of the NNC DEQ, the County voluntarily commenced a corrective action program and implemented monitored natural attenuation (MNA) as the remedial strategy at the facility due to VOC groundwater impacts from at the closed MSW landfill in 1996. The Moore County Landfill is located in southwestern Moore County between the towns of Pinehurst and Aberdeen, NC, as shown on Figure 1. The facility is bound to the west by Horse Creek and to the north and south by unnamed tributaries of Horse Creek and a power-line right-of-way that transects the property represents its eastern MSW disposal boundary. Topographic surface elevations at the facility range from approximately 460 feet above mean sea level (AMSL) along the eastern portion of the closed MSW landfill to approximately 350 feet AMSL on the southwestern side of the facility. The site is surrounded predominately by wooded, agricultural, or rural residential properties. The Moore County MSW landfill began operation in 1968 and the facility stopped accepting waste prior to the October 9, 1993, compliance date specified in Title 40 of the Code of Federal Regulation Section 258.1 (40 CFR §258.1). In 1993, a transfer station was constructed adjacent to the Moore County MSW landfill to handle the County’s MSW stream. In September of 1993, Moore County entered into an agreement with Uwharrie Environmental, Inc., which later became Republic Services of North Carolina, LLC, granting the private company operation responsibilities at its transfer station. In addition to the transfer station, after closure of the MSW landfill in 1993 the County opened a C&D landfill under the existing NCSWP No. 63-01. The County temporarily stockpiled C&D waste from approximately 1993 to 1996, until the current landfill C&D landfill was permitted and constructed. The County is currently still managing the C&D waste streams generated within Moore County and currently operates the C&D landfill, which is located immediately west and downgradient of the closed MSW landfill. Final closure of the MSW landfill was approved by NC DEQ in December 1996 and the County expressed their intent to comply with post-closure monitoring in January 1997. 2.1 MSW and C&D Compliance Monitoring History The MSW landfill was originally monitored by five (5) monitoring wells, which were installed in June 1987. The original MSW landfill monitoring network consisted of MW-1, MW-2, MW-3, MW-4, and MW-5. Monitoring wells MW-1, MW-2, MW-3, and MW-4 were used as the downgradient monitoring wells and MW-5 (side gradient of the MSW landfill) was used as the upgradient well. The five (5) original monitoring February 2017 3 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx wells were located with the anticipation of expanding the MSW landfill; however after the promulgation title 15A NCAC 13B.1600 rules, the County made the decision to close the MSW landfill. As discussed, a C&D landfill was constructed under NCSWP No. 63-01 in 1996. The new C&D landfill utilized monitoring wells MW-3 and MW-4 (remnants of the MSW landfill’s monitoring network) as downgradient monitoring wells for the new C&D landfill. In addition to MW-3 and MW-4, monitoring wells MW-6 through MW-9 were installed and incorporated into the C&D compliance network in March 1995 to monitor the area between the MSW and C&D landfills. Due to detections of VOCs in samples from monitoring wells downgradient of the closed MSW landfill and concerns of off-site migration expressed by the NC DEQ in January 1996, the County voluntarily proceeded with groundwater corrective action for the MSW facility. In September 1996, additional groundwater monitoring wells were installed in an effort to delineate the horizontal and vertical extent of groundwater impacts caused by the closed MSW landfill. The additional monitoring wells installed in September 1996 included MW-11S/D, MW-12S/D, MW-13S/D, MW-14, and MW-15. With the exception of MW-15, the new groundwater monitoring wells would also serve as additional monitoring wells for the newly constructed C&D facility. Monitoring wells MW-16S/D were later installed to replace MW-12S/D during an expansion of the C&D facility. A private water supply well at the Blake residence (PW-1), which is located upgradient of the facility, was added to the monitoring network in 1996, along with surface water monitoring points (SW- 1 and SW-2). A summary of monitoring well construction information is presented in Table 1. In a letter dated October 6, 1999, the NC DEQ, in a response to low level VOC detections and exceedances of methane above the lower explosive limit (LEL) along the northern property boundary, requested that the County perform a water quality assessment and explosive gas study in accordance with 15A NCAC 13B .0402(3) to delineate the extent of VOC impacts to groundwater and the possibility of methane gas crossing the property line. A “Methane and Groundwater Quality Assessment Report” was submitted by HDR with an addendum to NC DEQ in December of 2000. In this report, a confining unit was identified at depth, which was reported to limit vertical groundwater contamination. In January 2005, the NC DEQ requested that the County complete an Assessment of Corrective Measures (ACM) and select a remedy in accordance with 15A NCAC 2L .0106. HDR submitted the ACM in July 2005 with MNA as the primary proposed remedy with a contingency plan for active landfill gas (LFG) remediation. The NC DEQ approved the recommendations in the ACM on November 21, 2005; however, they did not require a public hearing, as this was not required for this facility under the applicable regulations (HDR, 2005). A revised WQMP was prepared in July 2006 and approved on October 13, 2006, by the NC DEQ. This revised WQMP includes monitoring of NC Appendix I VOCs and Resource Conservation Recovery Act (RCRA) metals for all groundwater and surface water monitoring points, as well as “performance monitoring” (i.e., MNA) parameters for selected wells. In a letter from the NC DEQ dated April 18, 2008, the County received permission to eliminate hydrogen, carbon dioxide, and volatile fatty acids from the February 2017 4 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx semi-annual monitoring list, and complete groundwater modeling annually. This letter also specified that the County would collect the full suite of “performance monitoring parameters” in April and October 2011, and present a MNA corrective action evaluation report (CAER) after completion of the October 2011 water quality monitoring event (WQME). The CAER was approved in May 2012. The County has currently completed the second five (5) year MNA compliance cycle at the MSW landfill and will submit the next CAER now that the October 2016 event has been completed. . 2.2 Hydrogeologic Setting The facility is located in the inner Coastal Plain physiographic province of NC. The geologic units of this region are relatively young, dating from the Cretaceous Period to the Tertiary Period. The site is underlain by sands, silts, and clays of the Middendorf Formation, which generally consist of intercalated, lenticular, thick-bedded, light-colored sands and clays (mudstones) with local concentrations of clay-clast conglomerates (Figure 2) (NCGS, 1985 and Sohl, Norman, and James, 1991). Borings at the facility describe the subsurface mainly as silty sand, poorly sorted sand, and well sorted sand inter-bedded with discontinuous silt and clay lenses as defined by the Unified Soil Classification System (USCS). The discontinuous silt and clay lenses varied in thickness form one inch to several feet in facility borings. The available boring logs for monitoring wells installed at the facility can be found in Appendix A of this report. A summary of monitoring well construction information is presented in Table 1. The uppermost groundwater beneath the facility is present in a shallow unconfined aquifer comprised of sands mixed with thin clay seams and larger seams of fine sand. The uppermost aquifer at the site is approximately 55 feet thick and underlain by a clay confining layer (HDR, 2005). In general, surface water and groundwater at the facility flows to the west and southwest toward Horse Creek, which is located along the western property boundary. Limited surface water and groundwater flows to the north and south to unnamed tributaries of Horse Creek located along the northern and southern property boundaries (as shown on Figure 2). Based on available data, the unnamed tributaries of Horse Creek appear to be gaining or effluent streams that increase in water volume downstream as a result of infiltrating water from the local aquifer. Groundwater occurs at depths varying from approximately 6 to 34 feet below ground surface across the site. Historical measurements of groundwater elevations are summarized in Table 2. Groundwater elevations from the April 2016 monitoring event were used to prepare a groundwater surface contour map presented as Figure 3. In April 2005 during the ACM study conducted by HDR, seventeen (17) groundwater monitoring wells (MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-11S/D, MW-13S/D, MW-14, MW-15, and MW-16S/D) were used to determine an accurate estimate of hydraulic conductivity for the upper aquifer sediments at the facility. The hydraulic conductivity was evaluated by performing slug tests, which utilizes falling and rising head tests to mathematically calculate the hydraulic conductivity of the uppermost aquifer at the facility. Groundwater flow velocities are calculated for each semi-annual WQME using the calculated February 2017 5 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx hydraulic conductivity of 5.59E-3 centimeters per second (cm/s). An effective porosity of 0.35 was selected for the shallow aquifer at the site based on typical effective porosity values for similar soil types (HDR, 2005). The April 2016 groundwater surface contour map (included as Figure 3) and interpreted flow directions are generally consistent with previously submitted contour map interpretations for this facility. Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne where Vgw = average linear velocity (feet/year), K = hydraulic conductivity (feet/year), i = horizontal hydraulic gradient, and ne = effective porosity. Using several flow pathway calculations, the estimated linear groundwater flow velocity from the April 2016 WQME had a calculated range of 266 to 360 feet per year, with an average value of 301 feet per year, as shown on Table 3. The calculated groundwater flow rates from the April 2016 WQME are consistent with historical calculations of groundwater flow velocities. The linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this equation represents a likely average value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. February 2017 6 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 3.0 CONSTITUENTS-OF-CONCERN A summary of historical groundwater detections for the facility’s compliance network are provided as Table 4. A summary of groundwater field parameters is included as Table 5. Based on the evaluation of recent groundwater monitoring data for the C&D landfill, the following constituents are considered to be constituents-of-concern (COCs) and are addressed in this ASD: acetone benzene chlorobenzene chloroethane 1,2-dichlorobenzene 1,4-dichlorobenzene 1,1-dichloroethane cis-1,2-dichloroethene (DCE) tetrachloroethene (PCE) trichloroethene (TCE) vinyl chloride xylenes 3.1 Acetone Acetone is a common household solvent which is miscible in water. Acetone can be found as the active ingredient in nail polish remover and paint thinner. Acetone is also produced during the normal metabolic process in the human body. In its pure form acetone is a flammable colorless liquid with a pungent or floral odor. Acetone was last detected above the Solid Waste Section Reporting Limit (SWSL) in in the downgradient monitoring well MW-11S during the October 2008 water quality monitoring event. Acetone has been periodically detected in samples from the C&D groundwater monitoring network at estimated concentrations since October 2007. Acetone has been detected at higher concentrations above the SWSL in samples from MW-6, MW-7, MW-8, MW-9, and MW-14 (i.e., wells installed upgradient of the C&D unit to monitor groundwater between the MSW unit and the C&D unit). These data suggest that acetone impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.2 Benzene Benzene is classified as an aromatic hydrocarbon is a commonly used industrial chemical and a common organic component of MSW and C&D landfill leachate and landfill gas. In its pure form, benzene can be described as a colorless liquid with a petroleum-like odor. Under normal conditions benzene is only slightly soluble in water. Benzene is considered a light non-aqueous phase liquid (LNAPL) since it has a specific February 2017 7 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx gravity less than water. Since benzene is less dense than water, benzene contamination can typically be found at the top of the water column. Benzene was detected in downgradient C&D monitoring wells MW-11S, MW-11D, MW-16S at concentrations that exceeded the SWSL and the NC 2L Standard as recently as the April 2016 event. Historically and during the April 2016 water quality monitoring event, benzene was detected in monitoring wells MW-6, MW-7, MW-8, MW-9, and MW-14 (i.e., wells installed upgradient of the C&D unit to monitor groundwater between the MSW unit and the C&D unit) at similar concentrations. Benzene was first detected in monitoring wells located between the MSW and C&D landfills (MW-7, MW-8, and MW-9) during the June 1995 event. Benzene was first detected in the downgradient C&D compliance monitoring wells MW-11D and MW-12D during the March 2000 compliance monitoring event. These data suggest that benzene impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.3 Chlorobenzene Chlorobenzene is classified as an aromatic VOC and is a commonly used as an intermediate in the manufacture of other chemical compounds including herbicides, dyestuffs, and rubber. Historically, chlorobenzene was used in the production of certain pesticides including DDT. Chlorobenzene was also used as the main precursor in the production of phenol. Under the right conditions chlorobenzene is also an aerobic and anaerobic degradation by product of 1,4-dichlorobenzene and an aerobic degradation by product of 1,2-dichlorobenzene. In its pure form chlorobenzene is a flammable colorless liquid with an almond-like odor. Chlorobenzene was detected in samples from the upgradient C&D monitoring well MW-14 at a concentration that exceeded the SWSL as recently as the April 2014 water quality monitoring event. Chlorobenzene has been detected at estimated concentrations below the SWSL in samples from MW-11S, MW-11D, MW-13S, MW-13D, and MW-16S. Historically and during the April 2016 water quality monitoring event, chlorobenzene was detected in the monitoring wells installed between the MSW and the C&D landfill at similar concentrations. These data suggest that chlorobenzene impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.4 Chloroethane Chloroethane has had many industrial uses. Most notably chloroethane was historically used in the production of tetraethyllead (TEL) which was used as an octane rating booster in gasoline from the early 1920s to the mid-1970s. TEL was phased out from use in the mid-1970s due to its damaging effect on catalytic converters and due to the accumulative neurotoxicity of lead. After TEL was phased out of use the demand for chloroethane dropped substantially. In its pure form chloroethane is a flammable colorless liquid with a pungent odor. February 2017 8 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx Chloroethane was last detected in samples from MW-11S at a concentration that exceeded the SWSL during the March 2000 water quality monitoring event. Chloroethane has been detected at estimated concentrations below the SWSL in samples from MW-11S and MW-14. Historically, chloroethane was detected in the monitoring wells installed between the MSW and the C&D landfill at similar concentrations. These data suggest that chloroethane impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.5 1,2-Dichlorobenzene The constituent 1,2-dichlorobenzene was mainly used as an intermediate in the synthesis of agrochemicals and as an insecticide for termites and locust. The volatile 1,2-dichlorobenzene in its pure form is a colorless liquid that is poorly soluble in water. The constituent 1,2-dichlorobenzene has been periodically detected at an estimated concentration below the SWSL in samples from C&D monitoring wells MW-11S, MW-11D, MW-14, and MW-16S. Historically, 1,2-dichlorobenzene was detected in samples from the monitoring wells installed between the MSW and the C&D landfill at similar concentrations. These data suggest that 1,2-dichlorobenzene impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.6 1,4-Dichlorobenzene The constituent 1,4-dichlorobenzene is classified as an aromatic VOC and was commonly used to control moths (e.g., moth balls), molds, mildews, and as a disinfectant. 1,4-Dichlorobenzene is a colorless liquid with a strong odor and under normal conditions has a low solubility in water. The constituent 1,4-Dichlorobenzene was detected in downgradient C&D monitoring wells MW-11S, MW-11D, MW-16S at concentrations that exceeded the SWSL, but below the NC 2L Standard as recently as the April 2016 event. Historically and during the April 2016 water quality monitoring event, 1,4- dichlorobenzene was detected in monitoring wells MW-6, MW-7, MW-8, MW-9, MW-14, and MW-15 (i.e., wells installed upgradient of the C&D unit to monitor groundwater between the MSW unit and the C&D unit) at similar concentrations. 1,4-Dichlorobenzene was first detected in the downgradient C&D monitoring wells MW-11D and MW-12D during the March 2000 compliance monitoring event; however, it was detected in wells upgradient of the C&D landfill (MW-7, MW-8, and MW-9) as early as June 1995. These data suggest that 1,4-dichlorobenzene impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.7 1,1-Dichloroethane The constituent 1,1-dichloroethane is a commonly manufactured chlorinated hydrocarbon which is used as a feedstock in the chemical synthesis of 1,1,1-trichloroethane. It is also commonly used as a degreaser February 2017 9 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx and an insecticide. The constituent 1,1-dichloroethane in its pure form is a colorless oily liquid with a chloroform-like odor. The constituent 1,1-dichloroethane was last detected above the SWSL in samples from the downgradient monitoring well MW-11D during the October 2008 water quality monitoring event. 1,1-Dichloroethane has been detected periodically at estimated concentrations below the SWSL since October 2008 in samples from MW-11S, MW-11D, MW-14, MW-16S, and MW-16D. Historically, 1,1-dichloroethane was detected in samples from the monitoring wells installed between the MSW and the C&D landfill at similar concentrations. These data suggest that 1,1-dichloroethane impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.8 Cis-1,2-Dichloroethene Constituent cis-1,2-dichlorothene is classified as an aliphatic VOC and is commonly produced as a secondary contaminant via the biodegradation of tetrachloroethene. In its pure form cis-1,2-dichloroethene is a flammable colorless liquid with a strong odor. Under normal conditions cis-1,2-dichloroethene has a modest solubility in water. Cis-1,2-dichloroethene was detected in downgradient C&D monitoring well MW-11D at a concentration that exceeded the SWSL, but below the NC 2L Standard as recently as the April 2016 event. Historically and during the April 2016 water quality monitoring event, cis-1,2-dichloroethene was detected in monitoring wells upgradient of the C&D landfill (MW-6, MW-7, MW-8, MW-9, MW-14, and MW-15) at similar concentrations. Cis-1,2-Dichloroethene was first detected in the upgradient (MW-6, MW-14, and MW-15) and downgradient C&D monitoring wells (MW-11S, MW-11D, MW-16S, and MW-16D) during the April 2006 compliance monitoring event. These data suggest that cis-1,2-dichloroethene impacts seen in samples from the downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.9 Tetrachloroethene Tetrachloroethene or perchloroethene (PCE) is classified as an aliphatic VOC and was commonly used in dry cleaning fluids and degreasers. In its pure form PCE is a nonflammable, highly volatile. Under normal conditions PCE is slightly soluble in water. PCE is known as a dense non-aqueous phase liquid (DNAPL) which means it has a specific gravity greater than that of water causing the substance to sink in water. PCE was detected in downgradient C&D monitoring well MW-11D at a concentration that exceeded the SWSL and the NC 2L Standard as recently as the October 2015 event. Historically, PCE has been detected in monitoring wells upgradient of the C&D landfill (MW-6, MW-7, and MW-15) at similar concentrations. PCE was first detected in the downgradient C&D monitoring wells MW-11D and MW-12D during the first compliance monitoring event for the C&D landfill in October 1996. PCE was detected in wells upgradient February 2017 10 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx of the C&D landfill (MW-6 and MW-7) as early as the June 1995 event. These data suggest that PCE impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.10 Trichloroethene Trichloroethene (TCE) is classified as an aliphatic VOC and was commonly used as an industrial solvent. In its pure form TCE is a nonflammable colorless liquid with a sweet odor. Under normal conditions TCE is moderately soluble in water. TCE is also a daughter product of PCE biodegradation. TCE was detected in downgradient C&D monitoring well MW-11D at a concentration that exceeded the SWSL, but below the NC 2L Standard as recently as the October 2015 event. Historically, TCE has been detected in monitoring wells upgradient of the C&D landfill (MW-6, MW-8, MW-14, and MW-15) at similar concentrations. TCE was first detected in the downgradient C&D monitoring well MW-11D during the first compliance monitoring event for the C&D landfill in October 1996. TCE was first detected in a monitoring well upgradient of the C&D landfill (MW-6) during the June 1995 event. These data suggest that TCE impacts seen in downgradient C&D monitoring wells are likely attributable to the MSW landfill. 3.11 Vinyl Chloride Vinyl chloride is classified as an aliphatic VOC and is a daughter product of the biodegradation of PCE. In its pure form vinyl chloride is a highly flammable gas with a sweet odor. Under normal conditions vinyl chloride has a low solubility in water. Vinyl chloride is a common organic contaminant associated with MSW and C&D landfills. Vinyl chloride was detected in downgradient C&D monitoring wells MW-11S, MW-11D, and MW-16S at concentrations that exceeded the SWSL and the NC 2L Standard as recently as the April 2016 event. Historically and during the April 2016 water quality monitoring event, vinyl chloride was detected in monitoring wells upgradient of the C&D landfill (MW-6, MW-7, MW-8, MW-9, MW-14, and MW-15) at similar concentrations. Vinyl chloride was first detected in the downgradient C&D monitoring well MW-12S during the October 1998 compliance monitoring event. Vinyl chloride was first detected in a monitoring wells upgradient of the C&D landfill (MW-6, MW-7, MW-8, MW-9) during the June 1995 event. These data suggest that vinyl chloride impacts seen in downgradient C&D monitoring wells are likely linked to the MSW landfill. 3.12 Total Xylenes Total xylenes refers to the total of three isomers (i.e., o-Xylene, m-Xylene, and p-Xylene). Each of these isomers in its pure forms are flammable colorless liquids. Xylene is considered a BTEX aromatic hydrocarbon. Xylenes are an important petrochemical produced during the manufacturing of coke fuel from coal. Xylenes are primarily used as solvents in the printing, rubber, and leather industries or as a cleaning agent for steel, silicon wafers, or integrated circuits. February 2017 11 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx Total xylenes have been detected periodically in the samples from the C&D groundwater monitoring network since October 2007. Historically, total xylene was also detected in samples from the monitoring wells installed between the MSW and the C&D landfill at similar concentrations. These data suggest that total xylene impacts seen in samples from downgradient C&D monitoring wells are likely attributable to the MSW landfill. February 2017 12 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 4.0 VOC SOURCE EVALUATION SENARIOS Pursuant to 15A NCAC 13B .0544(b)(1)(l), the purpose of this ASD is to determine if a source other than leachate from the C&D landfill’s waste disposal unit is responsible for the concentrations of COC’s that have been reported in recent samples collected from the C&D landfill monitoring network. Based on the review of the available data for the C&D landfill, Golder has identified the three most likely scenarios to account for the COC concentrations in groundwater within the C&D landfill monitoring network. 4.1 Scenario 1 – Closed MSW Landfill Leachate As discussed in detail in Section 2.0 of this report, the C&D landfill is located immediately downgradient of the County’s closed MSW landfill. As noted in the previous section, the available historical data indicate that the closed MSW landfill leachate is a known source of VOC groundwater impacts at the facility. The total VOC plume at the facility has been closely monitored and evaluated since voluntary corrective action began in 2005. To further evaluate the closed MSW landfill leachate as a potential source for low level VOC impacts found in samples from the C&D monitoring well network, additional sampling activities were performed in September 2016. These sampling activities included the collection of a MSW leachate sample and additional groundwater samples for analysis. 4.2 Scenario 2 – Closed MSW Landfill Gas As presented in Section 2.1, LFG migration from the MSW landfill unit has been an issue historically at the facility. Five (5) LFG trench systems and three passive landfill gas extraction wells have been installed to address this issue since 2005. The extent to which the MSW LFG has influenced groundwater at the facility has been difficult to quantify and differentiate from leachate impacts. Groundwater impacts from LFG migrating from the MSW facility is likely due to its close proximity. Therefore, LFG detections in C&D monitoring wells may not necessarily be from the C&D landfill. Further, based on data provided in the ACM, LFG may in part be responsible for the migration of the VOC plume over time. To further evaluate and attempt to differentiate LFG impacts from leachate impacts, additional sampling and analysis was performed in September 2016. The September 2016 additional sampling activities included the collection of an LFG sample from a MSW passive gas extraction well. 4.3 Scenario 3 – C&D Landfill Leachate or Landfill Gas In an attempt to differentiate the groundwater impacts of the closed MSW landfill, additional samples from the C&D facility were collected for analysis in September 2016. These samples include: a C&D leachate sample, additional groundwater, and soil-gas (headspace) samples were collected for analysis. February 2017 13 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 5.0 ASD INVESTIGATIVE ACTIVITIES As discussed above, on September 7 – 8, 2016, Golder personnel collected additional groundwater, headspace (air), and leachate samples from existing monitoring wells and gas vents at the Moore County Landfill. These samples were used to better assess and differentiate the MSW and C&D landfill leachate, and landfill gas as potential groundwater VOC sources. 5.1 Groundwater Sampling The following monitoring wells were purged and sampled using low-flow sampling techniques via the use of a peristaltic or portable bladder pump: MW-5 (the facility upgradient or background well) MW-11S (downgradient C&D compliance well) MW-11D (downgradient C&D compliance well) MW-14 (upgradient C&D compliance well) MW-16S (downgradient C&D compliance well) MW-16D (downgradient C&D compliance well) Measurements of pH, specific conductivity, depth-to-water, dissolved oxygen (DO), oxidation-reduction potential (ORP), temperature, and turbidity were recorded on approximately 3- to 5- minute intervals during the purge (i.e., dependent upon the purge rate). In general, the purge rate was matched to the yield of the monitoring well, as determined by continuously monitoring the depth-to-water and not allowing the purge rate to exceed 500 milliliters per minute. Purging was continued until stabilization was indicated by the field parameters. Prior to sampling, the laboratory-supplied sample containers were labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analysis. The groundwater samples were then collected directly from the pump discharge tubing into the labeled, laboratory supplied, pre- preserved sample containers. After collection, the samples were placed in a cooler on ice, under a chain-of-custody. Copies of the sampling logs are presented in Appendix B. Included on each log is a description of the sampling equipment, sampling location, sampling method, field observations, and water quality measurements. The groundwater samples were sent via courier to Environmental Conservation Laboratories, Inc. (ENCO) in Cary, NC to be analyzed for common cations (including calcium, magnesium, sodium, and potassium) and anions (including carbonate, bicarbonate, chloride, nitrate, nitrite, sulfate, and sulfide). In addition to these parameters, general chemistry parameters including ammonia, pH, alkalinity, and total dissolved solids were also analyzed. The results of these analysis were then analyzed using basic mixing calculations, piper plots, and stiff diagrams to assist in identifying the source of VOC impacts on February 2017 14 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx groundwater at the facility. The laboratory certificates-of-analysis, laboratory receipt condition forms, and sample chains-of-custody are presented in Appendix C and the data is summarized on Table 6. 5.2 Soil-gas or Headspace Sampling Soil-gas or headspace samples were collected from the following locations via the use of summa canisters equipped with a flow regulator: GV-32 (MSW passive landfill gas vent) MW-11S (downgradient C&D compliance well) MW-11D (downgradient C&D compliance well) MW-14 (upgradient C&D compliance well) MW-16S (downgradient C&D compliance well) MW-16D (downgradient C&D compliance well) To collect the soil-gas samples, tubing was inserted into the well to a depth of approximately 2 feet above the groundwater level. With the exception of the deep groundwater wells, the groundwater level in each monitoring well was below the top of the screen when the headspace sample was collected. The summa canister regulator was calibrated by the lab prior to arrival at the site. Sampling was commenced by first connecting the flow regulator (which was turned to the closed position) to the top of the canister. Tubing was lowered in to the well or vent to the desired depth and then attached to the flow regulator with a Swagelok fitting. The canister was then opened (with the flow regulator valve still in the closed position) and the canister pressure was recorded. The flow regulator valve was then opened and the canister was allowed to fill with the gas present in the well headspace. Each regulator was calibrated to take a “30-minute” sample. After the 30-minute sampling period had elapsed the regulator was closed and the canister pressure was recorded. After collection of the samples, the summa canisters were shipped via courier to ENCO in Jacksonville, Florida for analysis of VOCs by EPA method TO-15. The results of these analysis were then analyzed using Henry’s Law calculations to determine if LFG partitioning to groundwater is occurring. The laboratory certificates-of-analysis, laboratory receipt condition forms, and sample chains-of-custody are presented in Appendix C and are summarized on Table 7. 5.3 Leachate Sampling Two leachate grab samples were collected during the September 2016 ASD sampling event. A leachate sample was collected at the MSW landfill from passive gas vent GV-31 (sample L-1). The sample was collected using of a disposal bailer. A leachate sample was collected from the C&D landfill from the eastern side of the C&D landfill where historical seeps were noted (sample L-2). A hand auger was used to create a small hole in the landfill cap February 2017 15 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx until leachate was visible (approximately 2 ft. bgs). The leachate sample was collected by directly filling the sample containers from leachate that collected in the small sump created with the hand auger. Field parameters including pH, conductivity, temperature, and turbidity were obtained from each of these sample locations. After completion of the leachate sampling the small sump dug in the landfill cap was repaired by replacing and compacting the soil. The leachate samples collected were sent to ENCO in Cary, NC to be analyzed for the same geochemical cations, anions, and general chemistry parameters as the groundwater samples. In addition to these parameters, the leachate samples were also analyzed for the NC Appendix I VOC parameter list to be used for direct comparison to previous groundwater VOC concentrations recorded within the C&D groundwater monitoring network. The laboratory certificates-of-analysis, laboratory receipt condition forms, and sample chains-of-custody are presented in Appendix C and are summarized on Table 8. February 2017 16 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 6.0 ANALYTICAL RESULTS The results from the laboratory analysis completed as part of this investigation are discussed in the following sections. As presented in the previous section, the laboratory certificates-of-analysis, laboratory sample receipt forms, and the sample chain-of-custody forms for groundwater, soil-gas (i.e., headspace), and leachate samples analyzed during this investigation are presented in Appendix C. Analytical results for the September 2016 ASD groundwater sampling, soil-gas (i.e., headspace) sampling, and leachate sampling are summarized in Tables 6, 7, and 8, respectively. 6.1 Groundwater Sampling Results Table 6, summarizes the groundwater cation, anion, and additional geochemical data collected and analyzed during the September 2016 ASD sampling event. These results were used in the creation of piper plots, stiff diagrams, and mixing simulations to be used for comparative purposes in an attempt to differentiate leachate and LFG impacts on groundwater, as wells as impacts on groundwater from the closed MSW landfill versus those from the active C&D landfill as alluded to in previous sections of this report. 6.2 Soil-Gas Sampling Results As presented, the soil-gas sampling results from the September 2016 ASD sampling event are summarized in Table 7. Twenty-five (25) VOCs were detected at concentrations that exceeded the laboratory’s method detection limit in the gas sample collected from MSW LFG vent GV-32. Of those, fifteen (15) VOCs were detected at concentrations that exceeded the method quantification limit. Three (3) of the VOCs (toluene, acetone, and 2-butanone) detected in the sample from GV-32 were reported in the sample from MW-14, which is located between the MSW and C&D landfills, above the method detection limit. Fourteen (14) of the VOCs (toluene; cyclohexane; n-hexane; heptane; cis-1,2-dichloroethene; 2,2,4-trimethylpentane; 2-hexanone; acetone; benzene; chloromethane; vinyl chloride; carbon disulfide; 1,1-dichloroethane; and 2-butanone) detected in the sample from GV-32 were reported above the method detection limit in one or more samples from wells downgradient of the C&D landfill. Seven (7) organic constituents (i.e., 1,2,4-trimethylbenzene; ethylbenzene; propene; PCE; TCE; 4-ethyltoluene; and total xylenes) were detected in downgradient C&D monitoring wells that were not detected in GV-32. 6.3 Leachate Sampling Results As presented in Table 8, six (6) NC Appendix I VOCs (benzene; 1,4-dichlorobenzene; ethylbenzene; toluene; vinyl chloride; and total xylenes) were detected in the MSW landfill leachate sample L-1 (MSW)] at concentrations exceeding the solid waste section limit (SWSL). Two of these constituents (benzene and vinyl chloride) were detected a concentrations that exceed the NC 2L Standard. No NC Appendix I VOCs were detected at concentrations exceeding the SWSL in the C&D leachate sample [L-2 (C&D)]. Leachate cation, anion, and additional geochemical data are summarized in Table 8. February 2017 17 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 7.0 DATA EVALUATION The following sections discuss the data evaluations and interpretations that were completed in consideration of the three scenarios, proposed in Section 4.0, as sources of VOCs that have the potential to impact groundwater quality at the at the C&D landfill. 7.1 Landfill Gas Source Evaluation As presented, to evaluate LFG as a potential source of the VOC concentrations in groundwater samples from the C&D monitoring network, Golder evaluated recent methane concentrations in groundwater obtained from the April 2016 sampling event versus headspace concentrations of methane obtained on August 5, 2016, Golder also evaluated the potential of landfill gas impacts using a numerical soil-gas to groundwater partitioning model utilizing the soil-gas results from the September 2016 ASD sampling. Although more qualitative, Golder also evaluated the potential for LFG to accumulate in the well casing, allowing for direct exposure of groundwater within the well casing to be potentially impacted by headspace gas. It is noted that impacted headspace is not necessarily required for LFG to impact groundwater, as such impacts can happen outside of the well casing and upgradient of the well. These evaluations are discussed in the following sections. 7.1.1 Methane Concentration Analysis Dissolved methane was detected in ten (10) monitoring wells (MW-1, MW-2, MW-4, MW-6, MW-7, MW-9, MW-11S, MW-14, MW-15, and MW-16S) during the April 2016 water quality monitoring event. Methane was detected in the headspace of four (4) of the monitoring wells (i.e., MW-6, MW-7, MW-9, and MW-15) during the April 2016 methane monitoring event. These data are summarized on Table 9. The presence of methane in monitoring well headspaces and the presence of dissolved methane concentrations in groundwater at the facility indicate that methane gas generated from the landfills may have a role in the impacts seen in the groundwater. The limitation is that LFG generated from the MSW landfill cannot be easily differentiated from LFG that may be generated from the C&D landfill. Another potential indicator of LFG impacts on groundwater is pH, which can be helpful in discriminating between LFG and leachate impacts. The pH pf leachate for older landfills tends to range from 7.5 to 9.0 standard units (Kjeldsen, et al., 2002); whereas LFG impacts tend to lower the pH of impacted groundwater due to the dissolution of carbon dioxide, which is a major component of LFG, into the groundwater (Baker, May 1998). In general, the pH of groundwater at the facility is higher around the solid waste units and decrease with increased distance from the solid waste units. Historically, the pH of groundwater in background well MW-5 has ranged from 3.0 to 5.0 standard units while the pH of groundwater in MW-6 through MW-9 (the wells located between the C&D and the MSW landfills) has ranged from approximately 5.0 to 8.0 standard units. These data suggest that groundwater impacts observed at the facility are influenced more by leachate than landfill gas. February 2017 18 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 7.1.2 Henry’s Law Calculations (Groundwater to Soil-Gas) Using the VOC concentrations obtained from the headspace samples collected during the September ASD sampling event, Golder evaluated the COC concentrations observed in groundwater samples collected during the April 2016 water quality monitoring event. Henry’s Law was utilized to calculate the theoretical soil-gas concentrations that would be required to produce the concentration of the COCs in groundwater. These theoretical values were then directly compared to the actual soil-gas concentrations observed during the September 2016 ASD sampling event. The calculations were performed using the dimensionless form of the Henry’s Law Constant (H) for the COCs. The following is an example of the calculation: Analytical Solution: H (dimensionless) = Concentration (gas) Concentration (water) or: Concentration (gas) = Concentration (water) x H (dimensionless) Where: H (dimensionless) = literature reference value obtained for each COC Concentration (gas) = [units = parts per billion (ppb)] Concentration (water) = [units = micrograms per liter (µg/L)] Observed April 2016 benzene concentration in groundwater (at MW-11D): Benzene (water) = 1.3 µg/L Estimated gas concentration necessary to obtain observed groundwater concentrations: COC (gas) = H x COC (water) µg/L Benzene (gas) = 0.228 x 1.3 µg/L Benzene (gas) = 0.2964 µg/L To express in ppb divide by mole conversion factor: Benzene (gas) = 0.2964 ug/L 3.19E-03 Benzene (gas) = 157.24 ppbv Direct comparison: Benzene (gas-calculated) = 92.9 ppbv Benzene (gas-observed) = 2.1 ppbv Table 10 presents the Henry’s Law calculations (as shown above) for each VOC detected in groundwater from the C&D monitoring well network during the April 2016 water quality monitoring event. As presented on Table 10, the numerical simulation suggests that the VOC concentrations in groundwater samples should produce much higher soil-gas VOC concentrations than those that were analyzed from their respective wells. Also, many VOCs detected in the groundwater samples were not detected in the February 2017 19 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx soil-gas samples. The direct comparisons between the theoretical (or calculated) headspace concentrations and the soil-gas concentrations observed during the September 2016 ASD sampling are presented on Table 10. The assumptions used for this model are that steady state equilibrium conditions exist, that the groundwater and soil-gas temperatures are steady and remains at 25°C, that the pressure in the vadose zone is steady and remains at 1 atmosphere (atm) [or 101.325 kilopascals (kPa)], the groundwater volume and surface area is fixed, and that there is no flux in the COC concentrations in the soil-gas or groundwater medium that can be attributed to outside influences (e.g., barometric pressure fluctuations or changes in groundwater flow velocity). 7.1.3 Henry’s Law Calculations (Soil-gas to Groundwater) Using the same model assumptions, a similar analysis to the one presented above was conducted to evaluate the dissolved phase concentrations of COCs that may be partitioned into the groundwater by the gaseous phase COCs observed in the headspace sampling conducted during the September 2016 ASD monitoring. The following equation represents this analytical solution: Analytical Solution: H (dimensionless) = Concentration (gas) ÷ Concentration (water) or: Concentration (water) = H (dimensionless) x Concentration (gas) The results of the soil-gas to groundwater calculations which are based on the equation above are presented in Table 11. The results show that the gaseous phase VOCs detected in the soil-gas samples collected from the C&D monitoring wells and the MSW gas vent are generally not present at concentrations significant enough to partition dissolved phase VOCs at concentrations observed in groundwater results obtained during the April 2016 water quality monitoring event. This finding could be attributable to multiple factors including: no exposed screen in some of the monitoring wells due to a high water table or, as suggested above, the impacts may not be derived by LFG. It should also be noted that methane concentrations can vary greatly spatially and each methane should only be interpreted as one single point in time. The September 2016 results coincide with the groundwater to soil-gas calculations in the section above. The direct comparisons between the theoretical (or calculated) groundwater concentrations and the groundwater concentrations observed during the April 2016 water quality monitoring event are presented on Table 11. 7.2 Leachate Source Evaluation As presented two (2) leachate samples and six (6) groundwater samples were obtained during the September 2016 ASD sampling event to assist in evaluating leachate as a potential source of COC concentrations in groundwater present in the C&D landfill groundwater monitoring network. The September February 2017 20 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 2016 groundwater data and the available historical data for the facility were analyzed, via various methods, to assess or simulate leachate impacts on groundwater within the C&D landfill groundwater monitoring network. The results of these evaluations are discussed in detail in the subsequent sections. 7.2.1 Direct Comparison MSW vs C&D Leachate The first method used to evaluate and differentiate MSW landfill leachate and C&D landfill leachate at the facility was a direct comparison between the MSW leachate sample and the C&D landfill leachate sample collected during the September 2016 ASD sampling event. The direct comparison between the two leachate samples is presented in Table 8. In general, higher concentrations of general chemistry parameters and total dissolved solids were observed in the MSW leachate sample collected from GV-32 [L-1 (MSW)] as compared to the C&D leachate sample [L-2 (C&D)]. As presented on Table 8, six (6) VOCs (i.e., benzene, 1,4-dichlorobenzene, ethylbenzene, toluene, vinyl chloride, and total xylenes) were detected in the MSW leachate sample. No VOCs were detected in the C&D leachate sample collected in September 2016. Based on these data, the MSW leachate is more likely to have impacted the water quality around the C&D landfill, due to the number and concentrations of VOCs detected in the MSW leachate sample. 7.2.2 Piper Plot Analysis After the direct comparison between leachate sample from the MSW and the C&D landfill, a piper plot analysis was prepared to compare the geochemical facies of the leachates and the groundwater present at the facility. The piper plot analysis allows for the direct comparison of the cation and anion data from the leachate (presented on Table 8) and the groundwater samples (presented on Table 6) collected during the September 2016 ASD sampling event. The samples from the MSW leachate, MW-11S, MW-11D, MW-16S, and MW-16D fall within the mixed-bicarbonate geochemical facies. The sample from MW-14 plots within the sodium-bicarbonate geochemical facies. Monitoring well MW-5 plots within the sodium-chloride geochemical facies. The C&D leachate sample is significantly different from the other samples as it plots within the calcium-sulfate geochemical facies. As presented on Figure 4, the piper plot clearly shows some correlation between the cation and anion composition of the MSW leachate sample and the C&D monitoring well samples. As shown, each impacted C&D monitoring well composition plots in close proximity to the MSW leachate sample on the piper plot. The background well MW-5 does not plot near the impacted wells, the MSW leachate, or the C&D leachate. Likewise, the C&D leachate does not plot near any of the monitoring wells or the MSW leachate. The Piper Plot data suggests that MSW leachate shares a similar geochemical signature with the impacted monitoring well samples and that the MSW leachate is a likely source of the groundwater impacts. February 2017 21 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 7.2.3 Stiff Diagram Analysis Fixed scale and variable (or sliding) scale stiff diagrams were prepared and are included as Figures 5 through 6. Initially, fixed and variable scale stiff diagrams were created to examine and compare the shape signatures of each geochemical (i.e., cation and anion) sample collected during the September 2016 ASD monitoring (Figure 5 and 6. The fixed scale stiff diagrams account for total dissolved solids (TDS) and compare each sample based on a fixed scale (i.e., the same scale is used for each diagram). The variable scale stiff diagrams ignore TDS and compare the signature of each sample (i.e., a unique scale is set for each diagram). The fixed and variable scale stiff diagrams on Figures 5 and 6 show that the samples from the impacted wells (MW-11S, MW-11D, MW-14, MW-16S, and MW-16D) generally have a similar shape signature. The shape signatures from the samples from the impacted wells are not similar to the background well (MW-5). The variable scale Stiff diagrams on Figure 6 show there is a similarity between background monitoring well MW-5 and the MSW leachate sample. The major difference between the MSW leachate and the MW-5 samples is the MSW leachate sample has a much higher concentration of TDS than MW-5. The C&D leachate shape signature does not share similarities with groundwater samples or the MSW leachate sample. Based on the shape signatures from Figures 5 and 6, no correlation between the Stiff diagrams of the impacted groundwater sample and leachate samples can be made. 7.2.4 Mixing Analysis In addition to analyzing the existing variations in aquifer geochemistry at the site, Golder modeled potential leachate impacts to groundwater in affected downgradient wells at the facility using an analytical solution; two models were run. The first model was based on simple mixing, where selected proportions of the C&D leachate and background well MW-5 water were mixed (e.g., 10% leachate: 90% MW-5 water) to evaluate the potential evolution of groundwater that was being impacted by increasing concentrations of leachate. The simulated simple mixing model results are summarized in Table 12. Figure 7 displays the simulated mixing model results on Stiff diagrams. These diagrams show the resultant plot shapes of a solution represented by the geochemistry observed in the MW-5 sample progressively mixed with increasing percentages of C&D leachate (1% leachate to 33% leachate). Comparing the results of these shape signatures, the mixed results do morphologically trend toward a shape similar to the C&D leachate; though, the shapes of the C&D leachate plots on Figure 7 do not resemble the shapes for the impacted wells on Figure 6. Thus, these results indicate that typical C&D leachate is unlikely to be the source of the VOCs that have been detected in the groundwater downgradient from the landfill. The second model was based on simple mixing, where selected proportions of the MSW leachate and background well MW-5 water were mixed (e.g., 10% leachate: 90% MW-5 water) to evaluate the potential February 2017 22 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx evolution of groundwater that was being impacted by increasing concentrations of leachate. The simulated simple mixing model results are summarized in Table 13. Figure 7 displays the simulated mixing model results on Stiff diagrams. These diagrams show the resultant plot shapes of a solution represented by the geochemistry observed in the MW-5 sample progressively mixed with increasing percentages of MSW leachate (1% leachate to 33% leachate). Comparing the results of these shape signatures, the mixed results do not morphologically trend toward a shape similar to the MSW leachate, and the shapes of the MSW leachate plots on Figure 7 do not resemble the shapes for the impacted wells on Figure 6. Thus, these results indicate that the MSW leachate is unlikely to be the source of the VOCs that have been detected in the groundwater downgradient from the landfill. Based on these results, it is apparent that the geochemistry of impacted wells cannot be replicated by a simulated leachate release using the facility’s upgradient groundwater chemistry as the sole solution and C&D or MSW leachate chemistry, assuming that there is no precipitation of the ions of interest. 7.3 Groundwater Modeling An analytical groundwater flow model was constructed using AquiferWin32 version 4.0 by Environmental Simulations (2009) to simulate groundwater flow in the uppermost aquifer based on site and regional aquifer conditions. The model was calibrated based on site groundwater levels and hydraulic gradients. The primary assumptions included a median hydraulic conductivity of 12.84 feet per day based on site slug tests, an aquifer storativity of 0.1, an aquifer top of 410 feet above mean sea level (AMSL), and an base of 338 feet AMSL. Recharge is applied at a rate of 0.00208 feet per day representative of summer conditions and 0.00421 feet/day recharge for winter conditions from base flow separation curves for Drowning Creek (USGS 2133500). The recharge was applied from the topographic high, east of the site, and the interpreted downgradient limit of the water table aquifer, to Horse Creek, to the west of the facility. The western extent of the aquifer is interpreted to be along Horse Creek where the aquifer thins. The groundwater flow is interpreted to be controlled by topography and flows radially from the topographic high to the east of the site and flow to the west towards Horse Creek and its tributaries, which are hydraulically connected to the aquifer where groundwater discharges. A constant head elevation of 399 feet AMSL was imposed based on measured groundwater elevations and interpreted groundwater on the eastern side of the closed landfill. The groundwater gradient was developed from line sinks located along all the perennial and intermittent stream sections identified from the Stream Identification Map, April 17, 2013, prepared by Golder. Linear discharge sink head elevations set to interpreted stream bed elevation from site contour maps. The model, presented as Figure 8 and Figure 9, simulated steady state conditions using solutions developed by Strack (1989) for two dimensional flow in an unconfined aquifer. The model was used to simulate steady state conditions during summer and winter. The model groundwater elevations were compared to measured elevations at each observation well. The particle February 2017 23 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx tracking lines have 1 year markers and are shown on Figure 8 and Figure 9. Summary output files from the AquiferWin 32 analytical flow model for each of the scenarios are provided in Appendix D. In general, the groundwater model confirms that groundwater flow presented on Figure 3 is accurate. The particle trace assessment shown on Figure 8 and Figure 9 also confirm that groundwater impacts observed in the C&D groundwater monitoring network could potentially be from the MSW landfill. The flow arrows shown on the figures show a median of approximately 6 to 7 years before groundwater impacts from the MSW could be observed within the C&D monitoring network. The particle trace modelling does not take into account concentrations of the contaminants or the degradation of volatile organics during the transport time period so an estimation of concentrations cannot be made. However, because the MSW landfill has been accepting waste since 1968 this scenario is supported based on the analytical model. 7.4 Historical Data Review and Evaluation A historical data table is presented as Table 4. As presented, the oldest historical data currently available for the landfill facility date back to June 1995 (i.e., before operation of the C&D landfill began). An examination of this data displays several VOC detections in monitoring wells installed between the MSW and C&D landfills (i.e., upgradient of the C&D landfill). The historical data suggest that a release of leachate from the closed MSW landfill occurred prior the construction and operation of the C&D landfill. This fact has been well documented throughout the life of the C&D landfill and was the reason the County voluntarily entered corrective action at the MSW landfill. After the installation of monitoring wells downgradient of the C&D landfill, VOCs were immediately detected in groundwater samples. VOC detections in the C&D landfill date back to the initial sampling event on the C&D monitoring network in October 1996. An examination of this data shows a declining trend in VOC concentrations over time, which was the main reason MNA was chosen as the remedy for the site after completion of the ACM in 2005. The presence of VOCs in samples from MSW monitoring wells pre-dating the C&D landfill, as well as the presence of VOCs in groundwater during the initial monitoring event preformed at the C&D landfill, indicate that groundwater impacts observed at the site are due to a release from the MSW landfill. February 2017 24 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 8.0 CONCLUSIONS AND RECOMMENDATIONS Based on the data and evaluations presented herein, it does not appear that the C&D leachate is the source of VOCs observed in groundwater samples collected from the C&D network. Also, landfill gas does not appear to significantly contribute to groundwater impacts observed at the site based on the data presented herein. As presented in Section 7.3 of this report, VOC impacts at the site have been observed since June 1995 and pre-date the C&D landfill. A summary of the data and evaluations are provided below: Scenario #1 - Closed MSW Landfill Leachate: As presented, this appears to be the most likely scenario due to VOC impacts in groundwater pre-dating the C&D landfill operation facility or shortly after the commencement of operations, and the fact that the C&D wells are directly downgradient of the MSW unit. Supporting evidence for this scenario are summarized below: Higher pH values in impacted wells (as presented in Section 7.1.1) Presence of VOCs in MSW leachate but not in C&D leachate (as presented in Section 7.2.1) Stronger correlation in cation and anion composition between the MSW leachate sample and the C&D monitoring well samples on the piper plot (as presented in Section 7.2.2) Pre-C&D waste historical groundwater data show groundwater VOC impacts downgradient of the MSW landfill (as presented in Section 7.3) The groundwater model (presented in Section 7.2.5) and recent EPA Biochlor modeling (present in the April 2016 Water Quality Monitoring Report) support this scenario There was no strong dissenting evidence to suggest that leachate from the MSW landfill was not contributing to the groundwater impacts noted in recent groundwater samples at the facility. In fact, this theory has been assumed as the source of the groundwater impacts at the facility since the mid-1990s. The only potentially contrary evidence is summarized below: Weak correlation between the variable scale Stiff diagrams from the MSW leachate sample and groundwater samples obtained from the C&D monitoring well network (as presented in Section 7.2.3) Mixing analysis was inconclusive (as presented in Section 7.2.4) Scenario #2 – Closed MSW Landfill Gas: As presented, there was some evidence to suggest that landfill gas from the MSW landfill was contributing to groundwater impacts at the facility. Supporting evidence for this scenario are summarized below: Dissolved methane is present in groundwater samples at the facility (as presented in Section 7.1.1) Historical and continuous evidence of methane gas migration from the MSW landfill (as presented in Section 2.1) Opposing evidence of this theory is summarized below: Higher pH values in impacted wells (as presented in Section 7.1.1); No significant correlation between the headspace (i.e., soil-gas) samples collected and the groundwater impacts observed at the facility when evaluated using Henry’s Law (as presented in Section 7.1.2 and 7.1.3) February 2017 25 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx Scenario #3 – Active C&D Landfill: As presented, this appears to be the least likely scenario. Supporting evidence of the C&D landfill contributing to groundwater impacts is summarized below: The observation of landfill gas in downgradient groundwater monitoring wells at the C&D landfill during recent methane monitoring events. Dissenting evidence of this theory is summarized below: No significant correlations between LFG and groundwater VOC concentrations noted in the Henry’s Law calculations (as present in Section 7.1) No VOCs detected in the leachate sample obtained from the C&D landfill (as presented in Section 7.2.1) No correlation in cation and anion composition between the C&D leachate sample and the C&D monitoring well samples on the piper plot (as presented in Section 7.2.2) No correlation between the mixing simulations and the VOCs concentrations observed in the C&D monitoring well network (as presented in Section 7.2.4) Pre-C&D waste historical groundwater VOC concentrations (as presented in Section 7.3) Conformance to the groundwater model (present in Section 7.2.5) and recent EPA Biochlor modeling (present in the April 2016 Water Quality Monitoring Report) of the MSW landfill groundwater impacts The data collected during the September ASD sampling event summarized in this report, support that the most likely cause of VOC groundwater impacts at the C&D facility is the closed MSW landfill. Presently, there appears to be very little risk presented by the groundwater impacts as the VOC concentrations are relatively low, the plume appears to be contained on site, no receptors have been identified immediately downgradient, and the MSW landfill is already in corrective action. Based on these evaluations, conclusions, and supporting statements, Golder recommends and the County is respectfully requesting, that NC DEQ allow the County to continue with detection monitoring at the C&D landfill and corrective action at the MSW landfill as prescribed in the ACM. February 2017 26 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx 9.0 REFERENCES The following references were used in the preparation of this report and may not be directly reference in the text, tables, and figures. Baes, C.F. (III) and R.D. Sharp. 1983. A proposal for estimation of soil leaching and leaching constants for use in assessment models. Journal of Environmental Quality, V. 12(1):17-28. Baker, J.A. May 1998. Groundwater? An Analysis of Several Landfills Determined the Source of VOCs in Groundwater. The Results May Surprise You. Waste Age. pp. 213-224. Baker, J.A., July 1998. Waste Age. Geochemical Modeling & Groundwater Quality. pp. 77-88. Butler, J.R., and D.T. Secor, Jr., 1991. The Central Piedmont (Chapter 4) in J.W. Horton, Jr. and V.A. Zullo, eds., The Geology of the Carolinas (Carolina Geological Society Fiftieth Anniversary Volume): The University of Tennessee Press, pp. 2, 4, 24, 36, 44-45. Carpenter, M., T. Kramer, and J. Hartley. 1997. Developing a Strategy for Establishing Landfill Gas as a Cause of Groundwater Contamination. CH2M HILL White Paper, Seattle, Washington. 9 p. CWMB (California Waste Management Board). 1998. Landfill Gas Characterization. California Waste Management Board. State of California. Sacramento, California. October. 18 p. Dragun, J. 1988. The Fate of Hazardous Materials in Soil (What Every Geologist Should Know) Part 3. Hazardous Material Control. September/October. pp. 24-43. EPA (Environmental Protection Agency). September 1994. Region III Modifications to National Functional Guidelines for Organic Data Review Multi-Media, Multi-Concentration. United States Environmental Protection Agency, Region II, Central Regional Laboratory, Quality Assurance Branch. OLM-O1.0- OLMO1.9. 107 p. EPA, 1995,. Construction and Demolition Waste Landfills. Office of Solid Waste. Prepared by ICF Inc., Contract No. 68-W3-0008. EPA. May 1996. Soil Screening Guidance: Technical Background Document, Second Edition. Table 38. Office of Emergency and Remedial Response, United States Environmental Protection Agency, Washington, D.C., Publication: 9355.4-17A. EPA. September 1999. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater. EPA/800/R-98/128. February 2017 27 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx EPA. January 2000. Biochlor: Natural Attenuation Decision Support System, User Manual, Version 1.0. EPA/600/R-00/008. Freeze, R.A. and Cherry, J.A. 1979. Groundwater. Englewood Cliffs: Prentice-Hall, Inc. Golder Associates NC, Inc. May 2012. Corrective Action Evaluation Report, Moore County Landfill, Permit No. 63-01, Aberdeen, North Carolina. Golder Associates NC, Inc. August 2016. Water Quality Monitoring Report, First Semi-Annual 2016 Sampling Event, Moore County Landfill, Permit No. 63-01, Aberdeen, North Carolina. Harris, J.M. and J.A. Gaspar. 1989. Management of Leachate from Sanitary Landfills. Environmental Engineering Proceedings of the 1989 Specialty Conference. Environmental Engineering Division of the American Society of Civil Engineers. July. p. 320- 333. HDR Engineering, Inc. of the Carolinas (HDR). June 2005. Assessment of Corrective Measures Report, Moore County Landfill. HDR Engineering, Inc. of the Carolinas (HDR). July 2016. Water Quality Monitoring Plan, Moore County Landfill. Hem, J.D. 1985. Study and Interpretation of Chemical Characteristics of Natural Water, 3rd Ed. United States Geological Survey (USGS), Department of Interior, USGS Water-Supply Paper 2254. Jones-Lee, A. et al, 1993. Groundwater Pollution by Municipal Landfills: Leachate Composition, Detection and Water Quality Significance. Sardinia '93IV International Landfill Symposiums. October 11-15. Kjeldsen, P., M.A. Barlaz, A.P. Rooker, A. Baun, A. Ledin, and T.H. Christensen. 2002. Present and Long- term Composition of MSW Landfill Leachate: A Review. Environmental Science and Technology. 32(4), pp. 297-336. Melendez, B.A., 1996, A Study of Leachate Generated from Construction and Demolition Debris Landfills, 144 pp. National Association of Demolition Contractors. C&D Waste Landfills, Leachate Quality Data, Volume 1, Specific State by State Response. Prepared by Gersham, Brickner & Bratton, Inc., Falls Church, Virginia. February 18, 1994. NCDNRCD (North Carolina Department of Natural Resources and Community Development). 1985. Geologic Map of North Carolina. Scale 1:500,000. February 2017 28 0739615016.400 g:\projects\moore county\groundwater\2016 asd c&d landfill\final\a_report text\moore co asd for c&d landfill.docx NCGS (North Carolina Geologic Survey), 1985. Geologic Map of North Carolina. Olsen, R.L. and A. Davis. 1990a. Predicting the Fate and Transport of Organic Compounds in Groundwater, Part I. Hazardous Material Control. May/June. pp. 39-64. Olsen, R.L. and A. Davis. 1990b. Predicting the Fate and Transport of Organic Compounds in Groundwater, Part II. Hazardous Material Control. July/August. pp. 18-37. Sohl, Norman F. and Owens, James P. 1991. Cretaceous Stratigraphy of the Carolinas Coastal Plan. The Geology of the Carolinas, pp. 191-220. Soltani-Ahamadi, H. 2001. A Review of the Literature Regarding Non-Methane and Volatile Organic Compounds in Municipal Solid Waste Landfill Gas. University of Delaware. Research Paper prepared with support from the Lanny & Kay Hickman Internship, Delaware Solid Waste Authority, and the Solid Waste Association of North America. 39 p. Townsend, T.G. et al., 2000. Continued Research into the Characteristics of Leachate from Construction and Demolition Waste Landfills. Florida Center of Solid and Hazardous Waste Management, Report No. 00-04. State University System of Florida. 62 pp. United States Geological Survey (USGS). 2006. Description, Properties, and Degradation of Selected Volatile Organic Compounds Detected in Groundwater – A Review of Selected Literature. Walsh, P. and P. O'Leary, 2002. Landfilling Demolition and High Volume Industrial Wastes, Waste Age. pp. 68-74. October. Zanetti, M., 2008, Aerobic Biostabilization of Old MSW Landfills: American Journal of Engineering and Applied Sciences, 1 (4): pp. 393-398. Golder, Golder Associates and the GA globe design are trademarks of Golder Associates Corporation Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA Tel: (336) 852-4903 Fax: (336) 852-4904 TABLES February 2017 Page 1 of 1 TABLE 1 Summary of Monitoring Well Construction Information Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Northing Easting MW-1 06/05/87 508605.64 1854636.41 390.70 392.87 20 2 6.97 - 17.07 383.73 - 373.63 Sand Active MW-2 06/06/87 508508.07 1853819.73 373.39 375.50 20 2 7.52 - 17.77 365.87 - 355.62 Sand Active MW-3 06/06/87 508781.79 1852845.34 362.00 363.82 16.5 2 5.75 - 15.88 356.25 - 346.12 Sand and Silty Clay Active MW-4 06/06/87 509793.80 1853641.22 363.40 366.19 15 2 4.28 - 14.09 359.12 - 349.31 Sand and Silty Clay Active MW-5 06/06/87 510970.55 1853091.84 384.06 386.61 20 2 6.96 - 17.21 377.10 - 366.85 Sand and Clayey Sand Active MW-6 03/06/95 510385.96 1853881.79 403.50 405.86 20 2 5.00 - 20.00 398.50 - 383.50 Sand to Silty Sand Active MW-7 03/06/95 509783.24 1853820.43 399.20 402.01 20 2 4.00 - 19.00 395.20 - 380.20 Sand, Silt, Silty Sand, Clay Active MW-8 03/06/95 509384.99 1853844.10 395.20 397.85 20 2 5.00 - 20.00 390.20 - 375.20 Sand, Silt, Silty Sand, Clay Active MW-9 03/06/95 508964.80 1854268.28 403.70 406.06 30 2 15.00 - 30.00 388.70 - 373.70 Silty Sand Active MW-11S 09/16/96 510361.58 1852939.03 380.36 382.34 20 2 5.00 - 20.00 375.36 - 360.36 Sand to Silty Sand Active MW-11D 09/16/96 510342.65 1852938.03 380.03 383.05 40 2 30.00 - 40.00 350.03 - 340.03 Silty Sand Active MW-13S 09/18/96 509580.75 1853131.47 386.35 388.88 20 2 5.00 - 20.00 381.35 -366.35 Sand to Silty Sand Active MW-13D 09/18/96 509568.07 1853130.65 385.65 388.04 40 2 30.00 - 40.00 355.65 - 345.65 Sand to Silty Sand Active MW-14 09/16/96 510056.32 1853641.99 397.88 400.58 20 2 5.00 - 20.00 392.88 - 377.88 Sand to Silty Sand Active MW-15 09/19/96 510597.22 1854401.13 429.31 431.10 35 2 20.00 - 35.00 409.31 - 394.31 Sand to Silty Sand Active MW-16S 04/17/03 509789.42 1852386.76 384.00 386.00 24 2 14.00 - 24.00 370.00 - 360.00 Sand to Silty Sand Active MW-16D 04/17/03 509778.32 1852396.77 384.10 386.10 44 2 34.00 - 44.00 350.00 -340.00 Sand to Silty Sand Active Notes: 1.) ft AMSL = feet above mean sea level 2.) ft BGS = feet below ground surface 3.) NA = not drilled to auger refusal 4.) -- = no data available 5.) Well construction information collected from boring logs and well construction records from HDR Engineering, Inc. of the Carolinas July 2006 Water Quality Monitoring Plan. TOC and Ground Elevations are taken from the July 2005 Assessment of Corrective Measures Repor t and/or well records where available. Total Well Depth (feet) CoordinatesWell Identification Construction Date Ground Surface Elevation (ft AMSL) Measuring Point Elevation (ft AMSL) Well Status Well Diameter (inches) Screened Interval (ft AMSL) Screened Interval (ft bgs) Geology of Screened Interval G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 1 TABLE 2 Summary of Groundwater Elevations Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 TOC Elevation (ft AMSL) 03/05/90 382.00 --368.00 --358.00 --361.00 --377.00 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI03/12/91 381.90 --368.30 --358.30 --349.40 --377.10 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI03/10/92 380.90 --366.60 --357.30 --359.70 --376.10 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 04/13/93 382.86 --369.08 --359.00 --361.39 --378.41 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 10/12/93 379.47 --365.97 --356.66 --358.57 --375.60 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 04/20/94 380.87 --366.96 --357.43 --359.69 --376.53 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI05/20/94 380.79 --367.00 --357.55 --359.86 --376.53 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 10/24/94 380.62 --366.73 --357.53 --359.81 --376.40 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 03/13/95 --------------------389.69 --387.32 --384.68 --383.85 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 04/20/95 381.27 --367.39 --357.77 --359.94 --377.11 --388.66 --385.99 --383.30 --383.13 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI09/22/95 380.95 --366.89 --357.28 --359.35 --376.31 --387.85 --384.75 --382.23 --382.35 --NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 03/28/96 381.79 11.08 367.75 7.75 358.16 5.66 360.25 5.94 377.30 9.31 388.65 17.21 385.85 16.16 383.37 14.48 383.05 23.01 NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI NI 10/29/96 381.90 10.97 368.18 7.32 358.15 5.67 360.45 5.74 377.57 9.04 389.12 16.74 386.50 15.51 384.04 13.81 383.48 22.58 372.47 9.87 373.57 9.48 376.32 12.56 375.59 12.45 384.49 16.09 399.31 32.02 NI NI NI NI 04/08/97 381.79 11.08 367.84 7.66 358.10 5.72 360.16 6.03 377.30 9.31 388.90 16.96 386.22 15.79 383.73 14.12 383.25 22.81 371.74 10.60 372.84 10.21 375.35 13.53 374.60 13.44 383.93 16.65 398.66 32.44 NI NI NI NI10/29/97 381.18 11.69 367.15 8.35 357.67 6.15 359.92 6.27 376.11 10.50 387.84 18.02 384.71 17.30 382.64 15.21 382.27 23.79 370.98 11.36 372.17 10.88 374.68 14.20 373.82 14.22 382.61 17.97 397.71 33.39 NI NI NI NI 04/30/98 382.95 9.92 368.81 6.69 358.69 5.13 360.89 5.30 378.37 8.24 389.90 15.96 388.14 13.87 385.83 12.02 384.40 21.66 372.92 9.42 373.96 9.09 377.17 11.71 376.36 11.68 385.43 15.15 399.99 31.11 NI NI NI NI 10/14/98 381.82 11.05 367.43 8.07 357.73 6.09 360.29 5.90 376.88 9.73 388.23 17.63 385.36 16.65 383.04 14.81 382.63 23.43 371.89 10.45 372.17 10.88 375.21 13.67 374.28 13.76 382.97 17.61 398.23 32.87 NI NI NI NI 04/27/99 381.75 11.12 367.65 7.85 358.16 5.66 359.91 6.28 377.01 9.60 388.55 17.31 385.83 16.18 383.22 14.63 383.09 22.97 371.31 11.03 372.53 10.52 374.87 14.01 374.14 13.90 383.50 17.08 398.33 32.77 NI NI NI NI10/21/99 382.81 10.06 368.29 7.21 358.54 5.28 361.18 5.01 377.46 9.15 388.81 17.05 386.23 15.78 385.10 12.75 383.22 22.84 372.26 10.08 373.44 9.61 376.64 12.24 375.70 12.34 383.97 16.61 398.38 32.72 NI NI NI NI 04/19/00 382.01 10.86 367.89 7.61 358.07 5.75 360.35 5.84 376.10 10.51 388.60 17.26 385.92 16.09 383.62 14.23 383.14 22.92 371.57 10.77 372.71 10.34 375.47 13.41 374.60 13.44 383.53 17.05 408.2*22.90 NI NI NI NI 10/19/00 381.01 11.86 367.00 8.50 357.29 6.53 359.70 6.49 376.28 10.33 387.55 18.31 384.43 17.58 381.65 16.20 382.11 23.95 370.78 11.56 371.93 11.12 373.50 15.38 372.66 15.38 382.31 18.27 397.21 33.89 NI NI NI NI 04/10/01 381.55 11.32 367.51 7.99 358.09 5.73 359.96 6.23 376.72 9.89 387.94 17.92 385.48 16.53 382.73 15.12 382.40 23.66 370.73 11.61 372.00 11.05 374.02 14.86 373.26 14.78 382.76 17.82 396.99 34.11 NI NI NI NI10/11/01 380.37 12.50 366.46 9.04 356.93 6.89 359.34 6.85 375.50 11.11 386.59 19.27 383.40 18.61 380.31 17.54 381.35 24.71 370.13 12.21 371.30 11.75 372.52 16.36 371.87 16.17 381.39 19.19 395.47 35.63 NI NI NI NI 04/18/02 380.75 12.12 366.97 8.53 357.63 6.19 355.57 10.62 367.67 18.94 386.92 18.94 384.23 17.78 381.34 16.51 382.81 23.25 370.43 11.91 371.51 11.54 372.99 15.89 372.33 15.71 381.84 18.74 ----NI NI NI NI 10/08/02 379.89 12.98 365.87 9.63 356.21 7.61 358.88 7.31 374.63 11.98 385.52 20.34 382.71 19.30 379.60 18.25 380.70 25.36 369.51 12.83 370.83 12.22 371.37 17.51 370.83 17.21 380.59 19.99 ----NI NI NI NI 04/09/03 382.98 9.89 368.50 7.00 356.33 7.49 361.18 5.01 377.15 9.46 388.87 16.99 387.01 15.00 384.81 13.04 383.55 22.51 371.50 10.84 372.74 10.31 376.01 12.87 375.19 12.85 383.97 16.61 397.83 33.27 NI NI NI NI10/13/03 381.87 11.00 367.68 7.82 357.67 6.15 359.78 6.41 376.86 9.75 388.65 17.21 386.26 15.75 383.85 14.00 383.37 22.69 371.35 10.99 ----374.90 13.98 ----391.58*9.00 398.33 33.27 366.41 19.59 366.25 19.8504/26/04 381.46 11.41 367.19 8.31 357.31 6.51 359.25 6.94 376.36 10.25 388.15 17.71 385.09 16.92 382.50 15.35 382.75 23.31 370.51 11.83 371.78 11.27 373.57 15.31 371.80 16.24 382.67 17.91 397.85 33.25 365.26 20.74 365.10 21.00 10/25/04 381.21 11.66 367.11 8.39 357.14 6.68 359.21 6.98 376.01 10.60 387.86 18.00 384.81 17.20 382.31 15.54 382.96 23.10 368.45 13.89 ----376.53 12.35 ----382.55 18.03 397.54 33.56 365.44 20.56 ---- 04/04/05 381.68 11.19 367.55 7.95 357.73 6.09 359.84 6.35 376.52 10.09 388.11 17.75 385.53 16.48 383.05 14.80 382.67 23.39 370.55 11.79 371.72 11.33 374.04 14.84 373.31 14.73 382.74 17.84 397.35 33.75 365.48 20.52 365.29 20.8110/04/05 380.49 12.38 366.20 9.30 356.31 7.51 358.59 7.60 375.09 11.52 386.83 19.03 383.70 18.31 380.85 17.00 381.75 24.31 370.23 12.11 ----372.08 16.80 ----381.57 19.01 396.00 35.10 364.44 21.56 ----04/28/06 381.27 11.60 367.11 8.39 357.54 6.28 360.19 6.00 375.96 10.65 387.58 18.28 384.66 17.35 381.90 15.95 382.66 23.40 370.20 12.14 371.43 11.62 373.33 15.55 372.77 15.27 382.04 18.54 396.20 34.90 365.03 20.97 364.87 21.23 10/09/06 380.54 12.33 366.52 8.98 356.78 7.04 359.19 7.00 375.51 11.10 386.91 18.95 383.70 18.31 380.87 16.98 381.75 24.31 370.19 12.15 371.32 11.73 372.55 16.33 371.84 16.20 381.64 18.94 395.87 35.23 365.13 20.87 364.97 21.13 04/23/07 381.93 10.94 367.94 7.56 358.14 5.68 360.19 6.00 379.95 6.66 388.41 17.45 386.01 16.00 383.55 14.30 383.07 22.99 371.24 11.10 372.31 10.74 374.58 14.30 373.87 14.17 383.17 17.41 397.84 33.26 366.87 19.63 366.20 19.90 10/30/07 380.77 12.10 366.68 8.82 356.79 7.03 359.64 6.55 375.55 11.06 386.84 19.02 383.82 18.19 381.29 16.56 381.54 24.52 369.89 12.45 371.12 11.93 372.33 16.55 371.54 16.50 381.38 19.20 395.75 35.35 364.93 21.07 364.69 21.4104/21/08 381.53 11.34 367.70 7.80 357.75 6.07 359.83 6.36 376.31 10.30 388.08 17.78 385.86 16.15 383.06 14.79 382.66 23.40 370.91 11.43 372.04 11.01 374.06 14.82 373.35 14.69 383.04 17.54 396.91 34.19 366.08 19.92 365.97 20.13 10/06/08 381.46 11.41 368.68 6.82 357.57 6.25 359.88 6.31 376.32 10.29 387.94 17.92 385.30 16.71 382.96 14.89 382.75 23.31 371.23 11.11 372.38 10.67 374.40 14.48 373.69 14.35 382.97 17.61 396.79 34.31 366.68 19.32 366.56 19.54 04/13/09 381.67 11.20 367.79 7.71 357.86 5.96 360.14 6.05 376.60 10.01 388.15 17.71 385.50 16.51 382.97 14.88 382.82 23.24 371.23 11.11 372.28 10.77 374.04 14.84 373.35 14.69 382.96 17.62 397.29 33.81 366.68 19.32 366.06 20.04 10/13/09 380.32 12.55 366.25 9.25 356.32 7.50 358.87 7.32 375.14 11.47 386.40 19.46 383.22 18.79 379.90 17.95 381.18 24.88 369.71 12.63 371.09 11.96 371.45 17.43 370.93 17.11 381.16 19.42 393.68 37.42 364.58 21.42 364.45 21.6504/26/10 381.53 11.34 367.65 7.85 357.52 6.30 359.51 6.68 376.47 10.14 388.19 17.67 385.88 16.13 383.09 14.76 382.96 23.10 371.12 11.22 372.32 10.73 374.18 14.70 373.44 14.60 382.96 17.62 397.33 33.77 366.11 19.89 366.06 20.04 10/19/10 381.26 11.61 366.80 8.70 356.98 6.84 359.71 6.48 376.13 10.48 387.46 18.40 384.80 17.21 381.89 15.96 382.28 23.78 370.53 11.81 371.81 11.24 373.16 15.72 372.49 15.55 382.36 18.22 396.50 34.60 366.00 20.00 365.85 20.25 04/18/11 380.78 12.09 366.89 8.61 357.01 6.81 359.20 6.99 375.79 10.82 387.08 18.78 384.20 17.81 381.08 16.77 381.75 24.31 370.24 12.10 371.34 11.71 372.21 16.67 371.60 16.44 381.74 18.84 395.68 35.42 365.00 21.00 364.75 21.35 10/10/11 379.98 12.89 365.92 9.58 355.92 7.90 359.16 7.03 374.62 11.99 385.83 20.03 382.94 19.07 379.42 18.43 380.81 25.25 368.70 13.64 370.51 12.54 370.88 18.00 370.33 17.71 380.77 19.81 393.04 38.06 364.27 21.73 363.85 22.2504/17/12 380.32 12.55 366.81 8.69 357.06 6.76 358.40 7.79 374.76 11.85 386.04 19.82 383.43 18.58 379.09 18.76 381.17 24.89 369.34 13.00 370.90 12.15 371.43 17.45 370.51 17.53 381.07 19.51 393.89 37.21 364.00 22.00 364.13 21.97 10/09/12 379.83 13.04 366.17 9.33 356.66 7.16 360.10 6.09 374.42 12.19 384.89 20.97 382.71 19.30 379.51 18.34 380.48 25.58 372.04 10.30 370.81 12.24 371.43 17.45 370.95 17.09 380.55 20.03 393.16 37.94 364.72 21.28 364.53 21.57 04/15/13 380.34 12.53 366.87 8.63 357.27 6.55 359.73 6.46 374.88 11.73 385.84 20.02 383.71 18.30 380.84 17.01 381.16 24.90 369.52 12.82 371.25 11.80 372.34 16.54 371.74 16.30 381.09 19.49 393.96 37.14 365.15 20.85 364.94 21.16 09/30/13 380.56 12.31 366.88 8.62 356.82 7.00 359.43 6.76 375.04 11.57 386.43 19.43 383.95 18.06 381.38 16.47 381.85 24.21 370.39 11.95 371.60 11.45 373.09 15.79 372.33 15.71 381.70 18.88 393.41 37.69 365.46 20.54 365.18 20.9204/16/14 382.43 10.44 367.90 7.60 357.47 6.35 360.74 5.45 376.24 10.37 387.59 18.27 385.19 16.82 382.57 15.28 382.50 23.56 371.23 11.11 372.30 10.75 374.38 14.50 373.64 14.40 382.52 18.06 394.74 36.36 366.27 19.73 366.15 19.95 10/15/14 380.46 12.41 366.40 9.10 356.44 7.38 359.87 6.32 <366.89 >19.72 386.26 19.60 383.51 18.50 380.55 17.30 381.33 24.73 370.03 12.31 371.34 11.71 372.14 16.74 371.55 16.49 381.27 19.31 <393.30 >37.80 364.78 21.22 373.44 12.66 04/15/15 381.27 11.60 367.40 8.10 357.51 6.31 359.72 6.47 376.26 10.35 387.46 18.40 384.91 17.10 382.17 15.68 382.49 23.57 371.37 10.97 372.07 10.98 373.68 15.20 373.00 15.04 382.47 18.11 396.20 34.90 366.00 20.00 365.81 20.29 10/07/15 382.44 10.43 367.63 7.87 357.63 6.19 360.99 5.20 376.21 10.40 387.50 18.36 385.26 16.75 382.09 15.76 381.68 24.38 370.48 11.86 371.79 11.26 373.38 15.50 372.75 15.29 381.83 18.75 395.36 35.74 365.64 20.36 365.45 20.6504/11/16 381.70 11.17 367.65 7.85 357.63 6.19 359.98 6.21 376.42 10.19 388.34 17.52 385.69 16.32 383.21 14.64 383.02 23.04 371.55 10.79 372.48 10.57 374.47 14.41 373.66 14.38 383.19 17.39 397.84 33.26 366.35 19.65 366.24 19.8611/30/16 381.43 11.44 367.48 8.02 357.30 6.52 359.93 6.26 376.24 10.37 388.05 17.81 384.93 17.08 382.58 15.27 382.68 23.38 370.94 11.40 372.15 10.90 373.75 15.13 372.92 15.12 382.65 17.93 397.75 33.35 365.90 20.10 365.76 20.34 MEAN 381.28 11.56 367.29 8.21 357.44 6.44 359.57 6.45 376.17 10.57 387.67 18.27 384.99 17.09 382.31 15.62 382.42 23.69 370.77 11.57 371.94 11.11 373.77 15.11 372.96 15.08 382.43 17.92 396.60 34.21 365.51 20.51 365.70 20.40 MAXIMUM 382.98 13.04 369.08 9.63 359.00 7.90 361.39 10.62 379.95 18.94 389.90 20.97 388.14 19.30 385.83 18.76 384.40 25.58 372.92 13.89 373.96 12.54 377.17 18.00 376.36 17.71 385.43 20.03 399.99 38.06 366.87 22.00 373.44 22.25MINIMUM379.47 9.89 365.87 6.69 355.92 5.13 349.40 5.01 367.67 6.66 384.89 15.96 382.71 13.87 379.09 12.02 380.48 21.66 368.45 9.42 370.51 9.09 370.88 11.71 370.33 11.68 380.55 9.00 393.04 22.90 364.00 19.32 363.85 12.66 Notes: 1.) ft AMSL = feet above mean sea level 2.) -- = not measured or no data3.) TOC = top of casing 4.) DTW = Depth to Water 5.) NI = not installed 6.) MW = monitoring well7.) * = anamolous data 8.) TOC and water elevation data for dates prior to October 2007 from HDR Engineering, Inc. of the Carolinas Semi-Annual Monitoring Reports and the July 2006 Water Quality Monitoring Plan. 9.) MW-10 TOC elevation inferred from historical depth-to-groundwater and groundwater elevation measurements. 10.) Groundwater elevation and depth-to-water measurements appear to be anamolous for MW-14 during the 10/13/03 event and MW-15 during the 4/19/00 event and are not included in mean, maximum or minimum calculations. MW-13D 388.88 MW-13SMW-1 Date Elevation (ft AMSL)Elevation (ft AMSL)DTW (ft) Elevation (ft AMSL)DTW (ft) 375.50 MW-3MW-2 DTW (ft) Elevation (ft AMSL)DTW (ft) Elevation (ft AMSL)DTW (ft) Elevation (ft AMSL)DTW (ft) Elevation (ft AMSL)DTW (ft) 363.82 Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)Elevation (ft AMSL)DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) DTW (ft) MW-4 366.19 386.61 MW-5 405.86 MW-6 406.06 MW-9 397.85 MW-8 402.01 MW-7 388.04 400.58 MW-14 Monitoring Well 386.10 MW-16D 386.00 MW-16S 431.10 MW-15 383.05 MW-11D 382.34 MW-11S 392.87 G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 1 TABLE 3 Summary of Groundwater Flow Calculations Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Gradient Calculation Segment Flow Direction Gradient Segment Length (feet) Gradient Segment Elevations (feet) Horizontal Gradient (i, feet) Effective Porosity (ne) Hydraulic Conductivity (K, cm/sec) Velocity (Vgw, feet/year) 390 365 390 365 390 360 Notes: 1.) Horizontal velocities based on the modified Darcy equation Vgw = Ki/ne. 2.) Values for K are based on the average of hydraulic conductivities generated from the April 4, 2005 slug testing for the current groundwater monitoring well network as part of HDR Engineering, Inc. of the Carolinas July 2005 Assessment of Corrective Measures Report for the Moore County Landfill. 3.) Values for ne are based on an effective porosity of 35% typical for soils at the site, as referenced in the July 2005 Assessment of Corrective Measures Report. April 2016 i1 1149 0.35 3600.005590.022SW SW W i2 i3 266 277 0.35 0.35 0.00559 0.00559 1551 1793 0.016 0.017 G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Acetone ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 6000 ug/L ug/L 03/21/91 ------------------------------------------ND -- No EPA MCL ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ------------ND ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND --ND ND ------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND 3085 ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND 541 ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----335 390 108 ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND 728 ND 139 ----ND ND ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----185 ND 2628 ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----129 ND ND ND ND ----167 ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----422 110 ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND 192 119 ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----125 113 361 ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND 1400 123 ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND 138 ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --100 ND ND ND 380 60 16 7.7 5.6 ND ND 17 ND ----ND ND 4.8 J 4.3 J ND ND ND ug/L 04/23/08 --100 ND ND ND 420 120 220 10 J ND ND 5.7 J 15 J ND ----ND 37 J ND 5.5 J ND ND NDug/L 10/06/08 --100 ND ND ND 1100 160 56 J 20 B 210 ND ND 280 4.9 B ----5.3 B ND 7.6 B ND 5.1 B ND 5.0 J ug/L 04/13/09 --100 ND ND ND 48 J 240 160 ND 45 J ND ND 88 J ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --100 ND ND ND ND 78 J ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --100 ND ND ND 80 J 25 J 77 J 8.9 J 140 ND ND 6.2 J ND ----ND ND ND 2.3 J ND ND NDug/L 10/19/10 --100 ND ND ND 180 1700 ND ND 170 ND ND 7.0 J ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --100 ND ND ND 29 J 36 J ND 36 J ND ND ND ND ND ----ND ND ND 10 J ND ND ND ug/L 10/10/11 --100 ND ND ND 15 J --ND 5.0 J Dry ND ND ND ND ----82 J ND ND 4.4 J ND ND ND ug/L 04/17/12 --100 ND ND ND 10 J 56 J 12 J 18 J Dry ND ND 10 J ND ----ND ND ND 6.0 J ND ND NDug/L 10/09/12 --100 ND ND ND ND 290 ND 13 J Dry ND ND 16 J ND ----ND ND ND 5.1 J ND ND NDug/L 04/15/13 --100 ND ND ND 150 88 J 73 J 12 J Dry ND ND 6.3 J ND ----26 J ND ND 10 J ND ND ND ug/L 09/30/13 --100 ND ND ND 94 J 24 J 9.8 J 5.5 J Dry ND ND 18 J ND ----11 J ND ND 5.6 J ND ND ND ug/L 04/16/14 --100 ND ND ND 280 36 J 6.3 J 15 J Dry ND ND 37 J ND ----8.4 J ND ND 27 J 5.2 J ND NDug/L 10/15/14 1.2 100 Dry ND ND 16 J 110 6.6 J 12 J Dry ND ND 14 J ND ----ND ND ND 25 J 7.4 J ND NDug/L 04/15/15 1.2 100 ND ND ND 210 110 16 J 7.0 J Dry ND ND 32 J ND ----ND ND ND 10 J 13 J ND ND ug/L 10/07/15 1.2 100 ND ND ND 130 200 6.4 J 2.6 J 98 J ND ND ND ND ----13 J ND ND ND 9.4 J ND ND ug/L 04/11/16 1.2 100 ND ND ND 290 110 ND 55 J 300 ND ND 52 J ND ----ND ND ND 21 J ND ND ND Benzene ug/L 03/05/90 ------------------------------------------ND --NC 2L = 1 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 5 ug/L ug/L 03/10/92 ------------------------------------------ND -- ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND 3.2 8.8 9.8 ------------------------ND --ug/L 09/22/95 ----ND ND ND ND ND 6 6 --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND 59 ND 5 6 ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND 6 9 ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND 6 7 ----ND ND ND ND ND ND ND ----ND --ug/L 10/29/97 ----ND ----5 ND ND 6.5 11 ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND 6.6 ND 6.4 11 ----ND ND ND ND ND ND ND ----ND -- ug/L 10/14/98 ----ND ----ND ND ND ND 8.5 ----ND ND ND ND ND ND ND ----ND -- ug/L 04/27/99 ----ND ----ND ND ND 6.2 10 ----ND ND ND ND ND ND 5.3 ----ND --ug/L 10/21/99 ----ND ----ND ND ND ND 11 ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND 3 3 ND ND 4 11 ND ND ND 4 ND 3 ND ND ND ----ND -- ug/L 04/19/00 ----ND ----ND ND ND ND 7.6 ----ND ND ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----ND ND 5 5.2 9.2 ----ND ND ND ND ND ND ND ----ND --ug/L 04/10/01 ----ND ----ND ND ND 5.1 9.6 ----ND ND ND ND ND ND ND ----ND --ug/L 10/11/01 ----ND ----ND ND ND ND 8 ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND 5 ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/09/03 ----ND ----ND ND ND ND 6.8 ----ND ND ND ND ND ND ND ----ND --ug/L 10/13/03 ----ND ----ND ND ND ND 8.9 ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND 8.4 ----ND ND ----ND ND ND ND ND ND -- ug/L 10/25/04 ----ND ----ND ND ND ND 6.8 ----ND ND ----ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND ND 7.9 ----ND ND ----ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----ND ND ND ND 6.5 ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND 6.6 ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND ND ND 5.5 ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND 4.1 3.5 3.3 ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/30/07 --1 ND ND 1.2 3.0 1.5 2.7 3.2 4.2 ND ND 2.0 0.80 J ----0.33 J ND 2.2 0.69 J ND ND ND ug/L 04/23/08 --1 ND ND 0.92 J ND 2.8 0.84 J 4.0 ND ND ND 2.4 1.1 ----ND 5.1 2.5 0.42 J ND ND ND ug/L 10/06/08 --1 ND ND 0.97 J ND 2.1 2.2 2.5 6.4 ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND 2.6 ND 3.1 3.4 5.9 ND ND 0.88 J 1.2 ----0.53 J 0.53 J 2.3 0.56 J ND ND NDug/L 10/15/09 --1 ND 1.1 1.4 3.4 1.3 2.9 3.5 4.0 ND 0.40 J 2.4 1.2 ----1.2 ND 2.2 0.98 J ND ND ND ug/L 04/26/10 --1 ND ND 1.1 2.2 2.4 3.1 3.6 5.2 ND ND 2.6 1.1 ----0.69 J ND 2.5 ND ND ND ND ug/L 10/19/10 --1 ND ND 1.0 3.1 ND 3.0 3.6 4.6 ND ND 2.6 1.2 ----0.85 J ND 2.3 0.57 J ND ND ND ug/L 04/18/11 --1 ND ND ND ND 0.80 J 3.9 ND 4.1 ND ND 2.4 1.1 ----0.89 J ND ND 0.72 J ND ND NDug/L 10/10/11 --1 ND ND 1.0 3.4 --3.4 3.5 Dry ND ND 2.4 1.2 ----ND ND 2.2 ND ND ND ND ug/L 04/17/12 --1 ND 0.81 J 1.0 3.6 1.2 4.3 3.9 Dry ND ND 2.4 1.3 ----0.79 J ND 2.3 0.66 J ND ND ND ug/L 10/09/12 --1 ND 0.69 J 1.2 2.2 2.2 3.6 4.0 Dry ND ND 2.0 1.1 ----0.79 J ND 2.0 0.49 J ND ND ND ug/L 04/15/13 --1 ND ND 0.74 J 2.4 1.1 3.6 4.2 Dry ND ND 2.5 1.3 ----0.63 J ND 2.1 0.59 J ND ND NDug/L 09/30/13 --1 ND ND 0.50 J 2.2 2.7 2.4 3.4 Dry ND ND ND 1.3 ----0.41 J ND 2.1 0.59 J ND ND ND ug/L 04/16/14 --1 ND ND 0.67 J 2.9 1.8 2.8 3.3 Dry ND ND 1.7 1.3 ----ND 0.41 J 2.0 ND 0.56 J ND ND ug/L 10/15/14 0.15 1 Dry ND 0.81 J 2.8 1.6 3.9 3.4 Dry ND ND 2.4 1.1 ----0.56 J ND 1.9 1.2 0.63 J ND ND ug/L 04/15/15 0.15 1 ND ND 0.81 J 1.5 0.69 J 1.9 2.9 Dry ND ND 2.0 1.2 ----0.50 J ND 1.2 1.0 ND ND NDug/L 10/07/15 0.15 1 ND ND 0.80 J 3.9 1.6 3.1 3.9 6.3 ND ND 2.3 1.6 ----0.70 J ND 2.4 0.47 J 0.47 J ND NDug/L 04/11/16 0.15 1 ND ND 0.54 J 2.0 0.64 J 3.5 3.8 2.8 ND ND 1.8 1.3 ----ND ND 2.2 1.0 0.61 J ND ND Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 2 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Carbon disulfide ug/L 10/30/07 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND NC 2L = 700 ug/L ug/L 04/23/08 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND No EPA MCL ug/L 10/06/08 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/13/09 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/19/10 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/18/11 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/10/11 --100 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --100 ND ND ND ND 1.6 J ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/09/12 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/13 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 09/30/13 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 1.5 100 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/15 1.5 100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/07/15 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/11/16 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND Carbon tetrachloride ug/L 03/05/90 ----------------------------------------ND -- NC 2L = 0.3 ug/L ug/L 03/21/91 ----------------------------------------ND --EPA MCL = 5 ug/L ug/L 03/10/92 ----------------------------------------ND -- ug/L 04/20/95 ----------------------------------------ND -- ug/L 06/27/95 --------ND ND ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND 9 ND ND ND --ND ND ------------------ND --ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/30/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ----ND -- ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND --ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/19/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 0.17 1 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/15 0.17 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 0.17 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.17 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 3 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Chlorobenzene ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 50 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 100 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND ND 6.5 ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND 6 --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND 7.5 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND 5.4 ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND 5.1 ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND 6.1 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND 7.1 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND 3 ND ND ND 6 ND ND ND ND ND ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND 5.5 ND ----ND 32 ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND 12 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----ND ND ND 7.3 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND 13 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND 10.5 ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND 8.6 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND 8.6 ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND 10.8 ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND 10.9 ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND 11.9 ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND 9 ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND 9.1 ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND 7.8 ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND 3.2 ND ND ND 9.1 ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --3 ND ND 4.0 0.93 J 0.98 J 2.4 J 9.2 0.48 J ND ND ND 0.68 J ----0.51 J ND 3.0 0.58 J ND ND ND ug/L 04/23/08 --3 ND ND 2.5 J ND 0.45 J ND 9.9 ND ND ND 1.1 J 0.52 J ----ND ND 2.7 J ND ND ND NDug/L 10/06/08 --3 ND ND 2.6 J ND 0.93 J ND 9.0 ND ND ND 0.85 J 0.47 J ----ND ND 2.1 J ND ND ND ND ug/L 04/13/09 --3 ND ND 3.4 0.71 J ND 1.1 J 11 ND ND ND ND 0.54 J ----ND ND 2.9 J ND ND ND ND ug/L 10/15/09 --3 ND 8.4 3.8 1.2 J 1.0 J 2.9 J 11 0.57 J ND ND 1.0 J 0.56 J ----0.95 J ND 3.2 0.75 J ND ND ND ug/L 04/26/10 --3 ND ND 2.7 J 0.81 J 0.61 J 1.0 J 11 ND ND ND 1.2 J 0.53 J ----0.51 J ND 3.2 ND ND ND NDug/L 10/19/10 --3 ND ND 3.1 0.99 J ND 1.5 J 10 ND ND ND 0.91 J 0.67 J ----0.59 J ND 3.0 0.51 J ND ND ND ug/L 04/18/11 --3 ND ND 2.6 J ND 0.81 J 2.7 J 7.8 ND ND ND 1.2 J ND ----1.0 J ND 3.2 ND ND ND ND ug/L 10/10/11 --3 ND 6.7 3.0 1.6 J --3.6 9.6 Dry ND ND 1.0 J ND ----0.96 J ND 3.9 ND ND ND ND ug/L 04/17/12 --3 ND 6.3 2.8 J 1.4 J 0.86 J 2.3 J 12 Dry ND ND 1.0 J 0.61 J ----0.95 J ND 3.6 0.78 J ND ND NDug/L 10/09/12 --3 ND 5.6 3.1 1.3 J 1.4 J 2.5 J 11 Dry ND ND 1.2 J 0.80 J ----0.91 J ND 3.5 0.59 J ND ND NDug/L 04/15/13 --3 ND ND 1.9 J 1.1 J 0.41 J 1.1 J 10 Dry ND ND 1.2 J 0.60 J ----0.61 J ND 3.1 0.57 J ND ND ND ug/L 09/30/13 --3 ND ND 1.2 J 1.2 J 1.0 J 0.64 J 9.2 Dry ND ND 0.45 J 0.72 J ----0.47 J ND 2.5 J 0.50 J ND ND ND ug/L 04/16/14 --3 ND ND 1.8 J 1.2 J 0.75 J 0.74 J 9.1 Dry ND ND 0.74 J 0.72 J ----ND 0.52 J 3.3 ND ND ND NDug/L 10/15/14 0.17 3 Dry 1.6 J 2.1 J 0.96 J 1.4 J 3.1 10 Dry ND ND 0.86 J 0.59 J ----0.51 J ND 2.6 J 0.62 J ND ND NDug/L 04/15/15 0.17 3 ND ND 2.1 J 0.69 J ND 1.1 J 10 Dry ND ND 0.86 J 0.72 J ----0.53 J 0.44 J 2.7 J 0.76 J ND ND ND ug/L 10/07/15 0.17 3 ND ND 2.3 J 1.2 J 1.8 J 3.6 9.9 0.64 J ND ND 1.2 J 0.76 J ----0.48 J ND 2.6 J 0.51 J ND ND ND ug/L 04/11/16 0.17 3 ND ND 1.2 J 0.74 J ND 2.1 J 10 ND ND ND 0.88 J 0.71 J ----ND ND 2.6 J 0.65 J ND ND ND Chloroethane ug/L 03/05/90 ------------------------------------------ND --NC 2L = 3000 ug/L ug/L 03/21/91 ------------------------------------------ND -- No EPA MCL ug/L 03/10/92 ------------------------------------------ND -- ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------13.3 4.2 6.6 8.5 ------------------------ND --ug/L 09/22/95 ----ND ND ND 12 14 ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND 23 14 ND ND ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND ND ND --------ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----23 ND ND ND ND --------ND ND ND ND ND ----ND --ug/L 10/29/97 ----ND ----17 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----19 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/14/98 ----ND ----16 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/27/99 ----ND ----15 ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/21/99 ----ND ----11 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND 6 ND ND ND 2 ND ND 2 ND ND ND ND ND ND ----ND -- ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/30/07 --10 ND ND ND 1.3 J ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/23/08 --10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/06/08 --10 ND ND ND 4.8 J 0.55 J 0.78 J 1.3 J 2.5 J ND ND 2.0 J ND ----ND ND 1.2 J ND ND ND ND ug/L 04/13/09 --10 ND ND ND ND ND 1.1 J ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/15/09 --10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/19/10 --10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --10 ND ND ND ND ND ND ND ND ND ND 0.80 J ND ----ND ND ND ND ND ND NDug/L 10/10/11 --10 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --10 ND ND ND ND ND 0.54 J ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/09/12 --10 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/13 --10 ND ND ND ND ND 0.79 J ND Dry ND ND ND ND ----ND ND 0.65 J ND ND ND NDug/L 09/30/13 --10 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --10 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 0.23 10 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/15 0.23 10 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/07/15 0.23 10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.23 10 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 4 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells 1,2-Dichlorobenzene ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- NC 2L = 20 ug/L ug/L 04/28/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- EPA MCL = 600 ug/L ug/L 10/09/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/30/07 --5 ND ND 0.75 J ND ND 0.81 J 0.61 J ND ND ND 0.39 J 0.33 J ----ND ND 2.7 J 0.77 J ND ND ND ug/L 04/23/08 --5 ND ND 0.43 J ND ND ND 0.69 J ND ND ND ND ND ----ND ND 2.1 J ND ND ND ND ug/L 10/06/08 --5 ND ND 0.42 J ND ND ND 0.64 J ND ND ND ND ND ----ND ND 1.5 J ND ND ND ND ug/L 04/13/09 --5 ND ND 0.64 J ND ND ND 0.73 J ND ND ND ND ND ----ND ND 2.3 J 0.49 J ND ND NDug/L 10/15/09 --5 ND 0.62 J 0.67 J ND ND 0.81 J 0.69 J ND ND ND ND ND ----ND ND 2.2 J 0.75 J ND ND ND ug/L 04/26/10 --5 ND ND 0.50 J ND ND ND 0.82 J ND ND ND 0.50 J ND ----ND ND 2.0 J ND ND ND ND ug/L 10/19/10 --5 ND ND 0.53 J ND ND ND 0.88 J ND ND ND ND ND ----ND ND 2.1 J 0.57 J ND ND ND ug/L 04/18/11 --5 ND ND 0.43 J ND ND 0.51 J 0.67 J ND ND ND ND ND ----ND ND 2.0 J 0.64 J ND ND NDug/L 10/10/11 --5 ND 0.47 J 0.49 J ND --0.86 J 0.49 J Dry ND ND ND ND ----ND ND 1.9 J 0.62 J ND ND NDug/L 04/17/12 --5 ND 0.49 J 0.64 J ND ND ND 0.66 J Dry ND ND 0.33 J 0.36 J ----ND ND 2.0 J 0.75 J ND ND ND ug/L 10/09/12 --5 ND ND 0.49 J ND ND 0.48 J 0.76 J Dry ND ND ND ND ----ND ND 2.0 J 0.54 J ND ND ND ug/L 04/15/13 --5 ND ND ND ND ND ND 0.65 J Dry ND ND ND ND ----ND ND 1.7 J 0.56 J ND ND NDug/L 09/30/13 --5 ND ND ND ND ND ND 0.72 J Dry ND ND ND ND ----ND ND 1.2 J 0.45 J ND ND NDug/L 04/16/14 --5 ND ND ND ND ND ND 0.68 J Dry ND ND ND ND ----ND ND 1.7 J ND ND ND ND ug/L 10/15/14 0.19 5 Dry ND ND ND ND 0.59 J 0.58 J Dry ND ND ND ND ----ND ND 1.3 J 0.54 J ND ND ND ug/L 04/15/15 0.19 5 ND ND ND ND ND ND 0.51 J Dry ND ND ND ND ----ND ND 1.4 J 0.72 J ND ND ND ug/L 10/07/15 0.19 5 ND ND 0.42 J ND ND 0.65 J ND ND ND ND ND ND ----ND ND 1.1 J 0.50 J ND ND NDug/L 04/11/16 0.19 5 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND 1.0 J 0.59 J ND ND ND 1,4-Dichlorobenzene ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 6 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 75 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND 3.3 2 7.4 ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND 7 6 ----ND ND ND ND ND ND 6 ----ND -- ug/L 10/29/97 ----ND ----ND ND ND 7 6.1 ----ND ND ND ND ND ND 7.8 ----ND -- ug/L 04/30/98 ----ND ----ND ND ND 7.1 ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND 5.2 ND ----ND ND ND ND ND ND 9.7 ----ND -- ug/L 04/27/99 ----ND ----ND ND ND 5.9 5.6 ----ND ND ND ND ND ND 8.7 ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND 21 ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND 3 ND ND ND 4 ND ND ND ND 3 ND 3 ND ND 2 ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND 6.4 ----ND ND ND ND ND ND 7.5 ----ND -- ug/L 10/17/00 ----ND ----ND ND ND 10 6.3 ----ND ND ND ND ND ND 9.5 ----ND -- ug/L 04/10/01 ----ND ----ND ND ND 5.1 5.9 ----ND ND ND ND ND ND 6.7 ----ND -- ug/L 10/11/01 ----ND ----ND ND ND 5.6 8.3 ----ND ND ND ND ND ND ND ----ND --ug/L 04/18/02 ----ND ----ND ND ND 5.9 ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND 5.7 ND ----5.1 ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND 5.3 7.5 ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND 5.8 7.8 ----ND ND ----ND ND ND ND ND ND --ug/L 04/26/04 ----ND ----ND ND ND 5.9 6.9 ----ND ND ----ND ND 5.1 ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND ND 6.1 ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND 6.6 ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND 6.8 ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND 6 ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND 3.5 5.7 ND ND ND ND ----ND ND 5.3 ND ND ND -- ug/L 10/30/07 --1 ND ND 1.9 2.0 0.49 J 4.0 3.0 3.3 ND ND 3.4 2.1 ----0.97 J 0.54 J 5.7 1.1 ND ND ND ug/L 04/23/08 --1 ND ND 1.8 ND ND ND 4.2 ND ND ND 3.6 ND ----ND 3.5 5.5 ND ND ND NDug/L 10/06/08 --1 ND ND ND ND 1.5 ND 3.6 5.8 ND ND 3.3 ND ----0.44 J 0.60 J 4.9 ND ND ND ND ug/L 04/13/09 --1 ND ND 2.3 1.6 ND 0.97 J 4.2 5.9 ND ND 1.2 2.1 ----0.70 J 0.85 J 6.9 1.1 ND ND ND ug/L 10/15/09 --1 ND ND 2.6 3.4 1.6 4.1 3.7 5.3 ND ND 3.2 2.2 ----ND ND 5.5 1.8 ND ND ND ug/L 04/26/10 --1 ND ND 2.0 1.8 1.2 0.67 J 3.9 4.9 ND ND 3.6 ND ----1.1 0.66 J 6.0 ND ND ND NDug/L 10/19/10 --1 ND ND ND ND ND 1.8 3.9 5.3 ND ND 2.8 ND ----ND 0.59 J 4.2 ND ND ND ND ug/L 04/18/11 --1 ND ND 1.5 1.7 0.92 J 3.0 3.0 5.4 ND ND 3.2 1.6 ----1.7 ND 5.0 ND ND ND ND ug/L 10/10/11 --1 ND 0.82 J ND 4.0 --4.1 3.1 Dry ND ND 2.9 ND ----1.5 ND 5.1 1.7 ND ND ND ug/L 04/17/12 --1 ND ND 2.2 4.3 1.1 2.6 4.0 Dry ND ND 3.0 ND ----ND 0.50 J 5.2 1.5 ND ND NDug/L 10/09/12 --1 ND ND ND 3.7 1.8 3.3 4.9 Dry ND ND 3.3 ND ----ND 0.61 J 5.1 ND ND ND ND ug/L 04/15/13 --1 ND ND 1.9 3.2 0.74 J 1.1 3.9 Dry ND ND 3.1 2.0 ----0.89 J 0.52 J 4.7 1.3 ND ND ND ug/L 09/30/13 --1 ND ND ND 3.0 1.4 0.41 J 3.9 Dry ND ND 0.99 J 2.2 ----0.63 J 0.66 J 4.4 ND ND ND ND ug/L 04/16/14 --1 ND ND ND 3.1 0.83 J 0.60 J 3.7 Dry ND ND 2.0 1.9 ----ND ND 4.7 ND ND ND NDug/L 10/15/14 0.19 1 Dry ND ND 2.4 1.6 4.1 3.3 Dry ND ND 2.4 ND ----ND ND 4.0 ND ND ND NDug/L 04/15/15 0.19 1 ND ND ND 1.2 0.58 J 0.72 J 3.4 Dry ND 0.45 J ND 2.1 ----0.41 J ND 4.0 1.3 ND ND ND ug/L 10/07/15 0.19 1 ND ND ND 2.3 1.4 5.4 3.3 7.8 ND ND 3.0 ND ----0.71 J 0.52 J 3.9 0.84 J ND ND ND ug/L 04/11/16 0.19 1 ND ND ND 1.4 ND 2.3 3.1 5.4 ND ND 2.1 2.1 ----ND 0.64 J 4.8 1.2 0.47 J ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 5 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells 1,1,-Dichloroethane ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 6 ug/L ug/L 03/21/91 ------------------------------------------ND -- No EPA MCL ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------7.9 9.3 13.4 9.6 ------------------------ND -- ug/L 09/22/95 ----ND ND 9 18 10 19 12 --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND 11 ND 14 ND 10 ------------------------ND --ug/L 10/29/96 ----ND ----70 7 ND 7 80 ----ND 19 ND ND ND 6 ND ----ND -- ug/L 04/08/97 ----ND ----74 5 ND 6 72 ----16 22 ND 21 6 8 14 ----ND -- ug/L 10/29/97 ----ND ----64 6.2 8.3 7.5 72 ----22 20 ND 18 ND 6.8 12 ----ND -- ug/L 04/30/98 ----ND ----45 8.1 ND 5.3 60 ----ND 21 ND 18 ND 6.7 ND ----ND --ug/L 10/14/98 ----ND ----50 ND ND ND 46 ----9.8 ND 6.1 15 ND 5.2 8.4 ----ND --ug/L 04/27/99 ----ND ----37 ND ND 5.6 39 ----7.8 21 ND 18 ND ND 9.7 ----ND -- ug/L 10/21/99 ----ND ----12 ND ND ND 24 ----5.1 16 ND 13 ND ND ND ----ND -- ug/L 03/14/00 ----ND ND 4 12 ND ND ND 20 ND ND 4 14 ND 10 ND 2 ND ----ND --ug/L 04/19/00 ----ND ----19 ND ND ND 23 ----6.4 17 ND 14 ND ND 5.9 ----ND --ug/L 10/17/00 ----ND ----909 ND ND ND 24 ----9.6 17 ND 12 ND ND ND ----ND -- ug/L 04/10/01 ----ND ----9.2 ND ND ND 23 ----8.4 18 ND 13 ND ND 5.5 ----ND -- ug/L 10/11/01 ----ND ----16 ND 6 ND 22 ----11 16 ND 11 ND ND ND ----ND -- ug/L 04/18/02 ----ND ----5.5 ND ND ND ND ----9.9 13.8 ND 9.3 ND ND ND ----ND --ug/L 10/08/02 ----ND ----5.7 ND ND ND ND ----9 10.9 ND 7.6 ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND 9.5 ----6.8 10.7 ND 7.3 ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND 11.7 ----5.1 --ND --ND ND ND ND 6.9 ND -- ug/L 04/26/04 ----ND ----ND ND ND ND 10.7 ----5.4 10.6 ND --ND ND ND ND 6.9 ND --ug/L 10/25/04 ----ND ----ND ND ND ND 8.5 ----ND --ND --ND ND ND ND ND ND -- ug/L 04/04/05 ----ND ----ND ND ND ND 11.5 ----ND 8.4 ND --ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND 10.7 ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND 10.1 ND ND ND 7.6 ------ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND 17.7 ND ND ND 7.9 ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND 5.9 ND ND ND 7.5 --ND ND ND ND ND ND -- ug/L 10/30/07 --5 ND ND 1.1 J 1.4 J 0.38 J 4.3 J 0.51 J 3.6 J ND 0.69 J 5.2 7.8 ----3.4 J 3.5 J 1.0 J 1.5 J 1.4 J ND ND ug/L 04/23/08 --5 ND ND 0.84 J ND 0.76 J ND 0.87 J 1.0 J ND ND 2.8 J 5.8 ----ND 5.1 1.2 J 1.0 J ND ND NDug/L 10/06/08 --5 ND ND 0.61 J ND ND ND 0.83 J 7.4 ND ND 2.8 J 7.0 ----ND 0.42 J 1.2 J 0.76 J 1.3 J ND ND ug/L 04/13/09 --5 ND ND 0.77 J 0.67 J ND 0.65 J 0.74 J 4.7 J ND ND 0.50 J 4.9 J ----ND ND 0.79 J 0.74 J 0.74 J ND ND ug/L 10/15/09 --5 ND ND 0.76 J 1.1 J ND 1.2 J 0.45 J 2.4 J ND 0.78 J 1.8 J 4.4 J ----ND ND 0.71 J 1.0 J 0.67 J ND ND ug/L 04/26/10 --5 ND ND 0.56 J 0.51 J ND 0.86 J 0.49 J 2.8 J ND ND 1.6 J 4.7 J ----ND ND 0.64 J ND 0.85 J ND NDug/L 10/19/10 --5 ND ND 0.59 J 0.75 J ND 0.74 J 0.59 J 2.7 J ND ND 1.2 J 5.0 ----ND ND 0.68 J 0.53 J 0.79 J ND ND ug/L 04/18/11 --5 ND ND 0.47 J 0.51 J ND 1.0 J 0.50 J 2.0 J ND ND 1.4 J 4.2 J ----ND ND 0.69 J 0.83 J 0.67 J ND ND ug/L 10/10/11 --5 ND ND 0.53 J 0.91 J --1.0 J 0.45 J Dry ND 0.42 J 1.4 J 3.8 J ----ND ND 0.78 J 0.85 J 0.65 J ND ND ug/L 04/17/12 --5 ND ND 0.51 J 0.87 J ND 1.0 J 0.40 J Dry ND ND 1.2 J 4.1 J ----ND ND 0.66 J 0.71 J 0.46 J ND NDug/L 10/09/12 --5 ND ND 0.64 J 0.46 J ND 0.75 J 0.55 J Dry ND ND 1.0 J 4.2 J ----ND ND 0.58 J 0.59 J 0.46 J ND NDug/L 04/15/13 --5 ND ND ND 0.53 J ND 0.85 J 0.45 J Dry ND ND 1.1 J 5.6 ----ND ND 0.49 J 0.64 J 0.60 J ND ND ug/L 09/30/13 --5 ND ND ND 0.49 J 0.42 J ND ND Dry ND ND ND 2.9 J ----ND ND ND ND 0.73 J ND ND ug/L 04/16/14 --5 ND ND ND 0.53 J ND 0.45 J 0.42 J Dry ND ND 0.47 J 3.8 J ----ND ND ND ND 1.6 J ND NDug/L 10/15/14 0.13 5 Dry ND ND 0.50 J ND 0.87 J ND Dry ND ND 0.59 J 4.2 J ----ND ND ND ND 0.80 J ND NDug/L 04/15/15 0.13 5 ND ND ND ND ND ND ND Dry ND ND 0.49 J 3.0 J ----ND ND ND 0.44 J ND ND ND ug/L 10/07/15 0.13 5 ND ND ND 0.58 J ND 0.62 J ND 1.1 J ND ND 0.53 J 3.9 J ----ND ND 0.73 J ND 0.45 J ND ND ug/L 04/11/16 0.13 5 ND ND ND ND ND 0.61 J ND 0.90 J ND ND 0.42 J 1.7 J ----ND ND 0.66 J ND 0.62 J ND ND 1,2-Dichloroethane ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDNC 2L = 0.4 ug/L ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND EPA MCL = 5 ug/L ug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND 0.45 J ----ND ND ND ND ND ND ND ug/L 10/19/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND 0.48 J ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 0.40 J ----ND ND ND ND ND ND ND ug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/16/14 --1 ND ND 1.4 ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 0.21 1 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/15 0.21 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 0.21 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.21 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDcis-1,2-Dichloroethene ug/L 04/28/06 ----ND ND 6.4 19.6 ND ND ND 18.4 ND ND 13.9 31 ------ND 16.3 13.1 8.4 ND -- NC 2L = 70 ug/L ug/L 10/09/06 ----ND ND 5.1 14.3 9.5 ND 9.3 19.4 ND ND 12 26.3 ----ND ND 17.3 11.3 8.6 ND -- EPA MCL = 70 ug/L ug/L 04/24/07 ----ND ND ND 15.3 ND ND ND 7.3 ND ND 8.3 27.4 ----ND 5 19.3 8.7 12.1 ND --ug/L 10/30/07 --5 ND ND 5.1 14 6.4 3.0 J 1.6 J 17 0.35 J 4.4 J 9.8 25 ----3.8 J 3.0 J 20 12 5.3 ND NDug/L 04/23/08 --5 ND ND 3.0 J 3.8 J 3.1 J ND 2.2 J 3.2 J ND ND 9.8 19 ----3.6 J 11 20 7.0 ND ND ND ug/L 10/06/08 --5 ND ND 2.8 J 5.1 5.8 ND 2.5 J 12 ND ND 8.7 22 ----1.6 J 3.2 J 14 5.2 4.3 J ND ND ug/L 04/13/09 --5 ND ND 3.7 J 6.1 ND ND 2.9 J 12 ND ND 2.3 J 19 ----2.8 J 3.6 J 14 6.4 2.4 J ND ND ug/L 10/15/09 --5 ND 1.9 J 4.6 J 15 5.1 5.0 1.8 J 16 0.41 J 6.2 8.1 22 ----4.3 J 2.0 J 17 12 3.0 J ND NDug/L 04/26/10 --5 ND ND 2.8 J 7.5 3.2 J ND 2.3 J 7.2 0.43 J 0.60 J 8.0 18 ----3.0 J 2.6 J 13 5.2 2.9 J ND ND ug/L 10/19/10 --5 ND ND 3.0 J 8.4 ND ND 2.8 J 10 ND ND 5.7 23 ----3.4 J 2.6 J 13 6.8 4.4 J ND ND ug/L 04/18/11 --5 ND ND 2.8 J 6.8 3.4 J ND 1.9 J 11 ND ND 6.3 18 ----2.8 J 2.1 J 12 8.2 2.0 J ND ND ug/L 10/10/11 --5 ND 1.5 J 2.6 J 13 --2.8 J 1.6 J Dry ND 3.0 J 6.7 19 ----3.4 J 2.0 J 12 9.1 3.4 J ND NDug/L 04/17/12 --5 ND 1.4 J 2.2 J 16 2.8 J ND 1.6 J Dry 0.39 J 1.8 J 6.4 19 ----3.3 J 1.9 J 11 8.0 0.88 J ND ND ug/L 10/09/12 --5 ND 1.5 J 2.5 J 9.1 3.2 J ND 2.0 J Dry ND ND 6.6 18 ----2.2 J 1.6 J 7.0 5.5 2.5 J ND ND ug/L 04/15/13 --5 ND ND 1.7 J 11 1.2 J ND 1.7 J Dry ND ND 6.9 23 ----1.8 J 1.9 J 7.3 6.6 2.0 J ND ND ug/L 09/30/13 --5 ND ND 1.2 J 5.6 2.7 J ND 1.7 J Dry ND ND 1.8 J 14 ----1.2 J 1.9 J 4.0 J 4.3 J 3.2 J ND NDug/L 04/16/14 --5 ND ND 1.6 J 6.8 1.6 J ND 2.1 J Dry ND ND 2.4 J 16 ----0.66 J 1.9 J 6.7 2.1 J 6.8 ND ND ug/L 10/15/14 0.15 5 Dry 0.70 J 1.9 J 4.3 J 2.5 J ND 1.2 J Dry ND 0.43 J 2.9 J 17 ----1.3 J 1.4 J 5.3 5.5 4.9 J ND ND ug/L 04/15/15 0.15 5 ND ND 2.0 J 1.6 J 0.47 J ND 0.89 J Dry ND 3.1 J 2.2 J 14 ----0.76 J 0.72 J 3.4 J 6.4 3.7 J ND ND ug/L 10/07/15 0.15 5 ND ND 1.7 J 2.6 J 2.7 J ND 0.69 J 1.5 J ND ND 2.5 J 15 ----1.3 J 1.5 J 4.3 J 2.5 J 2.9 J ND NDug/L 04/11/16 0.15 5 ND ND 0.88 J 2.0 J 0.49 J 0.50 J 0.85 J 0.42 J ND 1.0 J 1.1 J 8.6 ----0.82 J 1.4 J 3.1 J 3.9 J 3.9 J ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 6 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Ethylbenzene ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 600 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 700 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND ND 9.4 ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/19/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/15/14 0.13 1 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/15 0.13 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 0.13 1 ND ND ND 0.66 J ND ND ND ND ND ND ND ND ----ND ND 0.62 J ND ND ND ND ug/L 04/11/16 0.13 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND Chloromethane ug/L 03/05/90 ------------------------------------------ND --NC 2L = 3 ug/L ug/L 03/21/91 ------------------------------------------ND -- No EPA MCL ug/L 03/10/92 ------------------------------------------ND -- ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND ND ND ------------------------ND --ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND ND ------------------------ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ------------------------ND --ug/L 10/29/97 ----ND ----ND ND 26 ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND 40 ----ND -- ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND 32 ----ND -- ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ----ND -- ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/19/10 --1 ND ND ND ND ND ND ND ND 0.67 J ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 0.13 1 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/15 0.13 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/07/15 0.13 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.13 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 7 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Methylene chloride ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 5 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 5 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND 40 ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND 15 ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND 12 ND 12 ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND 13 ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND ND ND ----ND 15 ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND 3 ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND 0.60 B ----ND ND ND ND ND ND 0.67 Jug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/19/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND 0.42 J ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND 0.40 J ----ND ND ND ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 0.52 J ----ND ND ND ND ND ND NDug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 0.50 J ----ND ND ND ND ND ND NDug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND 0.92 J ----ND ND ND ND ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/15/14 0.23 1 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/15 0.23 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 0.23 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/11/16 0.23 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND 2-Butanone ug/L 10/30/07 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDNC 2L = 4000 ug/L ug/L 04/23/08 --100 ND ND ND ND 4.8 J 2.8 J ND ND ND ND ND ND ----ND ND ND ND ND ND ND No EPA MCL ug/L 10/06/08 --100 ND ND ND 17 J 14 J ND ND ND ND ND 33 J ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/09 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/26/10 --100 ND ND ND ND ND ND 6.8 J ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/19/10 --100 ND ND ND 3.8 J ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/10/11 --100 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/17/12 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/09/12 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/13 --100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 09/30/13 --100 ND ND ND 2.6 J ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/16/14 --100 ND ND ND 2.4 J 1.3 J ND 13 J Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 1.3 100 Dry ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/15/15 1.3 100 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 1.3 100 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 1.3 100 ND ND ND 28 J 7.0 J ND 4.2 J ND ND ND ND ND ----ND ND ND ND ND ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 8 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Tetrachloroethene ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 0.7 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 5 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------8.4 3.2 ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND 12 ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND 6 ----ND 8 ND 7 ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND 8 ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----9.2 ND ND ND 9.1 ----ND 15 ND 15 ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND 8.2 ----ND 17 ND 13 ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND ND 5 ----ND 12.7 ND 8.7 ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND 10 ND 7.9 ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND 7.6 ----ND 8.6 ND 6.5 ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND 3 ND ND ND 8 ND 6 ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND 10 ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND 9 ND 6.5 ND ND ND ----ND -- ug/L 04/10/01 ----ND ----8.1 ND ND ND ND ----ND 6.5 ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND 8.4 ND 6.3 ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND 7.3 ND 5.9 ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND 6 ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND 5.3 ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ------ND ND ND ND 6.3 ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND 5.2 ----ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ------ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND 4 J ----ND ND ND ND 3 ND -- ug/L 10/30/07 --1 ND ND ND ND ND ND ND 0.38 J ND 0.35 J ND 3.1 J ----ND 0.43 J 0.52 J 0.71 J 0.49 J ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND 2.8 ----ND ND 0.40 J 0.54 J ND ND NDug/L 10/06/08 --1 ND ND ND ND ND ND ND 0.49 J ND ND ND 2.0 ----ND ND ND 0.49 J ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND 0.49 J ND ND ND 2.9 ----ND 0.48 J 0.44 J 0.47 J 0.84 J ND ND ug/L 10/15/09 --1 ND ND ND ND ND ND ND 0.50 J ND ND ND 2.7 ----ND 0.44 J ND 0.53 J ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND 0.47 J ND ND ND 2.9 ----ND 0.52 J ND ND 0.46 J ND NDug/L 10/19/10 --1 ND ND ND ND ND ND ND 0.52 J ND ND ND 2.7 ----ND ND ND ND 0.41 J ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND 1.8 ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND 1.8 ----ND ND ND ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 2.0 ----ND ND ND ND ND ND NDug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 2.5 ----ND ND ND ND ND ND NDug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND 2.2 ----ND ND ND ND ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND 1.5 ----ND ND ND ND ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND 2.2 ----ND ND ND ND 0.57 J ND NDug/L 10/15/14 0.17 1 Dry ND ND ND ND ND ND Dry ND ND ND 1.8 ----ND ND ND ND ND ND NDug/L 04/15/15 0.17 1 ND ND ND ND ND ND ND Dry ND ND ND 1.7 ----ND ND ND ND ND ND ND ug/L 10/07/15 0.17 1 ND ND ND ND ND ND ND ND ND ND ND 1.4 ----ND ND ND ND ND ND ND ug/L 04/11/16 0.17 1 ND ND ND ND ND ND ND ND ND ND ND 0.67 J ----ND ND ND ND ND ND ND Toluene ug/L 03/05/90 ------------------------------------------ND --NC 2L = 600 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 1000 ug/L ug/L 03/10/92 ------------------------------------------ND -- ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND ND ND ------------------------ND --ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/29/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND 15 ----ND ND ND ND ND ND ND ----ND -- ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND 2 ND ND ND ND ND ND ND ----ND -- ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/30/07 --1 ND ND ND ND ND ND ND ND ND ND 0.52 J ND ----ND ND 0.31 J ND ND ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND 0.44 J ND ND ND ND ND ug/L 10/06/08 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND ND ND ND 0.56 J ND ----ND ND 0.53 J ND ND ND NDug/L 10/15/09 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND 0.47 J ND ND ND ND ug/L 10/19/10 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND 0.47 J ND ND ND ND ug/L 10/09/12 --1 ND ND ND ND 0.44 J ND ND Dry ND ND ND ND ----ND ND 0.43 J ND ND ND ND ug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND 0.46 J ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/15/14 0.14 1 Dry ND ND ND ND 0.59 J ND Dry ND ND ND ND ----ND ND ND 0.40 J ND ND ND ug/L 04/15/15 0.14 1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/07/15 0.14 1 ND ND ND ND ND 0.56 J ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.14 1 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 9 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Trichloroethene ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 3 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 5 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------3.6 ND ND ND ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND 6.4 ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND 5 ----ND 7 ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND 9 ND 6 ND ND ND ----ND -- ug/L 10/29/97 ----ND ----ND ND ND ND 5.9 ----ND 8.9 ND 6.3 ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND 5.4 ----ND 9.8 ND 6.4 ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND 8.4 ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND 7.2 ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND 6.2 ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND 3 ND ND ND 8 ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND 7.6 ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND 5.1 ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----5.2 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND 5.6 ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ------ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --1 ND ND 0.30 J ND ND 0.31 J ND 0.46 J ND 0.40 J 0.36 J 1.9 J ----0.31 J ND 1.5 J 0.85 J 0.48 J ND ND ug/L 04/23/08 --1 ND ND ND ND ND ND ND ND ND ND ND 2.2 ----ND 0.50 J 1.0 0.53 J ND ND NDug/L 10/06/08 --1 ND ND ND ND ND ND ND 0.46 J ND ND ND 1.5 ----ND ND 0.76 J 0.41 J ND ND ND ug/L 04/13/09 --1 ND ND ND ND ND ND ND 0.74 J ND ND ND 1.7 ----ND ND 1.0 0.51 J ND ND ND ug/L 10/15/09 --1 ND 0.64 J ND ND ND 0.44 J ND 0.50 J ND 0.51 J ND 1.6 ----ND ND 0.97 J 0.79 J ND ND ND ug/L 04/26/10 --1 ND ND ND ND ND ND ND 0.50 J ND ND ND 1.7 ----ND ND 0.85 J 0.42 J ND ND NDug/L 10/19/10 --1 ND ND ND ND ND ND ND 0.42 J ND ND ND 1.6 ----ND ND 0.59 J ND ND ND ND ug/L 04/18/11 --1 ND ND ND ND ND ND ND ND ND ND ND 1.3 ----ND ND ND ND ND ND ND ug/L 10/10/11 --1 ND ND ND ND --ND ND Dry ND ND ND 1.2 ----ND ND 0.77 J ND ND ND ND ug/L 04/17/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 1.6 ----ND ND 0.50 J 0.61 J ND ND NDug/L 10/09/12 --1 ND ND ND ND ND ND ND Dry ND ND ND 1.9 ----ND ND 0.54 J 0.56 J ND ND NDug/L 04/15/13 --1 ND ND ND ND ND ND ND Dry ND ND ND 1.9 ----ND ND ND 0.58 J ND ND ND ug/L 09/30/13 --1 ND ND ND ND ND ND ND Dry ND ND ND 1.1 ----ND ND ND ND ND ND ND ug/L 04/16/14 --1 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND 0.41 J ND 0.55 J ND NDug/L 10/15/14 0.15 1 Dry ND ND ND ND ND ND Dry ND ND ND 1.3 ----ND ND ND 0.40 J ND ND NDug/L 04/15/15 0.15 1 ND ND ND ND ND ND ND Dry ND ND ND 1.5 ----ND ND 0.50 J ND ND ND ND ug/L 10/07/15 0.15 1 ND ND ND ND ND ND ND 0.53 J ND ND ND 1.1 ----ND ND ND ND 0.51 J ND ND ug/L 04/11/16 0.15 1 ND ND ND ND ND ND ND ND ND ND ND 0.70 J ----ND ND ND ND ND ND ND Vinyl chloride ug/L 03/05/90 ------------------------------------------ND --NC 2L = 0.03 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 2 ug/L ug/L 03/10/92 ------------------------------------------ND -- ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------5.3 9.4 40.3 15.9 ------------------------ND --ug/L 09/22/95 ----ND ND ND ND ND 45 20 --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND 13 ND ND 12 ND ------------------------ND -- ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/29/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND 10 ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND 13 ND ND ND 35 ----ND -- ug/L 04/27/99 ----ND ----18 ND ND ND ND ----ND ND ND ND ND ND 58 ----ND --ug/L 10/21/99 ----ND ----21 ND ND ND 17 ----ND ND ND ND ND ND 28 ----ND -- ug/L 03/14/00 ----ND ND 8 15 5 4 ND 9 ND ND 7 8 ND 8 3 ND 16 ----ND -- ug/L 04/19/00 ----ND ----25 21 ND ND 11 ----19 16 ND ND ND ND ND ----ND -- ug/L 10/17/00 ----ND ----14 ND 28 13 ND ----18 ND 14 ND ND ND 40 ----ND --ug/L 04/10/01 ----ND ----25 16 ND 11 16 ----21 13 13 14 ND ND 35 ----ND --ug/L 10/11/01 ----ND ----15 12 28 ND ND ----26 ND 14 ND ND ND 12 ----ND -- ug/L 04/18/02 ----ND ----13 10.8 17.7 ND ND ----25.9 ND ND ND ND ND ND ----ND -- ug/L 10/08/02 ----ND ----ND ND ND ND ND ----22 ND ND ND ND ND ND ----ND --ug/L 04/09/03 ----ND ----ND ND ND ND ND ----26.1 ND ND ND ND ND 18.5 ----ND --ug/L 10/13/03 ----ND ----ND ND ND 11.4 ND ----15.8 ND ----ND ND 12.5 ND ND ND -- ug/L 04/26/04 ----ND ----ND ND 19.4 ND ND ----19.4 ND ----ND ND 15.9 ND ND ND -- ug/L 10/25/04 ----ND ----ND ND 13.3 ND ND ----13.3 ------ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/04/05 ----ND ----11.7 ND 12.8 ND ND ----11.9 ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND 14.2 ND ND ND ND ND ND 25 ND ----ND ND 12.8 ND ND ND -- ug/L 10/09/06 ----ND ND ND ND ND 12.4 ND ND ND ND 18.9 ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND --ND ND ND 10.2 ND ----ND ND 7.6 ND ND ND --ug/L 10/30/07 --1 ND ND 2.7 3.6 ND 4.2 1.2 ND ND 0.30 J 6.3 2.6 ----ND ND 2.8 ND 0.43 J ND ND ug/L 04/23/08 --1 ND ND 1.4 ND 3.0 ND 1.8 ND ND ND 9.1 1.8 ----ND ND 5.1 0.90 J ND ND ND ug/L 10/06/08 --1 ND ND 1.2 3.4 J 2.1 ND 1.9 3.9 ND ND 11 3.3 ----ND 0.59 J 5.8 0.78 J ND ND ND ug/L 04/13/09 --1 ND ND 1.6 1.3 ND 0.67 J 1.7 3.0 ND ND 3.1 2.2 ----0.59 J ND 5.4 0.95 J ND ND NDug/L 10/15/09 --1 ND 0.92 J 2.1 4.0 ND 5.3 1.1 ND ND 0.62 J 7.5 2.7 ----ND ND 3.5 1.4 ND ND ND ug/L 04/26/10 --1 ND ND 1.9 2.0 2.4 0.81 J 1.6 2.4 ND ND 7.2 ND ----0.84 J ND 5.4 0.61 J ND ND ND ug/L 10/19/10 --1 ND ND 1.3 ND ND 0.53 J ND 2.1 ND ND ND 3.3 ----ND ND ND ND ND ND ND ug/L 04/18/11 --1 ND ND 0.91 J 0.78 J 0.90 J 1.0 0.71 J 2.2 ND ND 5.7 2.8 ----ND ND 2.8 0.81 J ND ND NDug/L 10/10/11 --1 ND ND 0.86 J 2.8 --3.7 1.2 Dry ND ND 5.0 2.2 ----ND ND 3.1 0.73 J ND ND ND ug/L 04/17/12 --1 ND 0.39 J 0.79 J 2.0 1.5 ND 1.1 Dry ND ND 5.0 2.3 ----0.85 J ND 3.7 0.79 J ND ND ND ug/L 10/09/12 --1 ND ND 1.3 2.0 2.0 ND 1.4 Dry ND ND 4.0 2.0 ----0.66 J ND 2.6 0.70 J ND ND ND ug/L 04/15/13 --1 ND ND 0.61 J 2.6 1.5 ND 1.1 Dry ND ND 6.2 2.4 ----0.67 J ND 3.5 0.75 J ND ND NDug/L 09/30/13 --1 ND ND ND 3.1 1.4 ND 0.85 J Dry ND ND 1.6 2.2 ----0.41 J ND 2.3 ND ND ND ND ug/L 04/16/14 --1 ND ND ND 1.7 1.8 ND 1.3 Dry ND ND 3.1 2.5 ----ND 0.43 J 3.1 ND 0.59 J ND ND ug/L 10/15/14 0.32 1 Dry ND 0.62 J 2.2 1.5 0.57 J 0.55 J Dry ND ND 4.8 2.6 ----0.77 J ND 2.3 0.94 J 0.42 J ND ND ug/L 04/15/15 0.32 1 ND ND 0.72 J 0.78 J ND ND ND Dry ND ND ND 2.3 ----ND ND 1.8 1.2 ND ND NDug/L 10/07/15 0.32 1 ND ND 0.61 J 2.7 1.5 ND 0.51 J 1.2 ND ND 3.4 3.7 ----ND ND 3.4 ND ND ND NDug/L 04/11/16 0.32 1 ND ND ND 0.72 J 0.71 J 0.48 J 0.42 J ND ND ND 2.8 2.5 ----ND ND 3.3 1.2 0.61 J ND ND G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 10 of 10 Project No. 0739615016 MW-5 MW-1 MW-2 MW-6 MW-7 MW-8 MW-9 MW-15 MW-3 MW-4 MW-11S MW-11D MW-12S MW-12D MW-13S MW-13D MW-14 MW-16S MW-16D PW-1 Aberdeen, North Carolina TABLE 4 Summary of Historical VOC Detections in Groundwater Moore County Landfill, Permit No. 63-01 Blanks Site Background SWS Reporting Limit Detected Monitoring Constituent/Parameter Reporting Units Sample Date Method Detection Limit C&D Monitoring WellsMSW Monitoring Wells Xylenes (Total)ug/L 03/05/90 ------------------------------------------ND -- NC 2L = 500 ug/L ug/L 03/21/91 ------------------------------------------ND -- EPA MCL = 10000 ug/L ug/L 03/10/92 ------------------------------------------ND --ug/L 04/20/95 ------------------------------------------ND -- ug/L 06/27/95 ----------ND ND 4.7 4.3 ------------------------ND -- ug/L 09/22/95 ----ND ND ND ND ND ND ND --ND ND ------------------ND -- ug/L 03/28/96 ----ND ND ND ND ND ND ND ------------------------ND --ug/L 10/29/96 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/08/97 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/29/97 ----ND ----10.2 ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/30/98 ----ND ----ND ND ND ND 18 ----ND ND ND ND ND ND ND ----ND --ug/L 10/14/98 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 04/27/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/21/99 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 03/14/00 ----ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ----ND --ug/L 04/19/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/17/00 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/10/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/11/01 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/18/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND --ug/L 10/08/02 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 04/09/03 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ----ND -- ug/L 10/13/03 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 04/26/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND --ug/L 10/25/04 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND --ND -- ug/L 04/04/05 ----ND ----ND ND ND ND ND ----ND ND ----ND ND ND ND ND ND -- ug/L 10/04/05 ----ND ----ND ND ND ND ND ----ND ND ND ND ND ND ND ND ND ND -- ug/L 04/28/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND --ug/L 10/09/06 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 04/24/07 ----ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND -- ug/L 10/30/07 --5 ND ND ND 0.34 J ND 4.4 J 0.44 J ND ND ND 4.3 J 3.8 J ----3.7 J ND 0.52 J ND ND ND ND ug/L 04/23/08 --5 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/06/08 --5 ND ND ND ND ND ND ND 5.4 ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/13/09 --5 ND ND ND ND ND ND 0.41 J 0.98 J ND ND ND ND ----ND ND 0.47 J ND ND ND ND ug/L 10/15/09 --5 ND ND ND ND ND 0.46 J 0.45 J ND ND ND 0.54 J ND ----ND ND 0.51 J ND ND ND ND ug/L 04/26/10 --5 ND ND ND ND ND ND ND 1.3 J ND ND ND ND ----ND ND 0.52 J ND ND ND NDug/L 10/19/10 --5 ND ND ND ND ND 0.47 J 0.41 J ND ND ND 0.47 J ND ----ND ND 0.48 J ND ND ND ND ug/L 04/18/11 --5 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/10/11 --5 ND ND ND ND --ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/17/12 --5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND 0.56 J ND ND ND NDug/L 10/09/12 --5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND 0.45 J ND ND ND NDug/L 04/15/13 --5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 09/30/13 --5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 04/16/14 --5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 10/15/14 0.45 5 Dry ND ND ND ND 0.60 J ND Dry ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/15/15 0.45 5 ND ND ND ND ND ND ND Dry ND ND ND ND ----ND ND ND ND ND ND ND ug/L 10/07/15 0.45 5 ND ND ND ND ND 0.93 J ND ND ND ND ND ND ----ND ND ND ND ND ND NDug/L 04/11/16 0.45 5 ND ND ND ND ND ND ND ND ND ND ND ND ----ND ND ND ND ND ND ND Notes: 1.) ug/L = Micrograms per liter2.) ND = Not detected at the stated reporting limit3.) NM = Not measured 4.) J = Estimated concentration reported below Solid Waste Section Limit 5.) -- = No data available 6.) Blanks = Field, trip, and method blanks7.) Reanalysis = Reanalysis result in parenthesis next to the original result (e.g., reanalysis was performed for selenium in April 2012) 8.) Bold = Concentration above the current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard 9.) Shaded and Bold = Concentration above the current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCL10.) EPA MCL = US Environmental Protection Agency Maximum Contaminant Level11.) SWS GSP = Solid Waste Section Groundwater Protection Standard 12.) SWS Reporting Limit = NCPQL or lab-specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 13.) * = EPA MCL is an action level 14.) # = EPA MCL is a secondary standard15.) Historical data prior to 10/30/07 provided by HDR Engineering of the Carolinas, Inc. 16.) Samples collected using low-flow purge and sample techniques. G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 2 Project No. 0739615016.400 Parameter Reporting Units Sample Date MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8*MW-9 MW-11S MW-11D*MW-13S*MW-13D*MW-14 MW-15 MW-16S MW-16D*PW-1*Blanks pH (field)S.U.04/28/06 5.00 6.10 5.00 5.10 4.90 5.90 5.90 6.10 6.40 6.30 4.70 --5.40 5.90 5.50 4.70 4.70 5.00 -- S.U.10/09/06 5.10 6.10 4.90 5.20 4.70 5.80 5.90 6.10 6.50 6.40 4.70 6.10 5.30 6.00 5.60 4.60 4.90 4.50 -- S.U.04/24/07 5.30 6.00 4.80 4.60 5.00 5.60 6.00 6.00 6.30 6.20 5.10 6.10 5.10 5.80 5.60 4.60 4.70 5.60 -- S.U.11/01/07 4.59 6.08 4.65 5.04 4.53 5.82 5.89 5.99 6.43 6.40 4.73 5.87 4.92 5.96 5.53 5.28 4.63 5.03 -- S.U.04/23/08 5.55 7.20 5.89 6.07 5.63 7.19 7.62 7.62 7.50 7.78 5.85 8.16 6.55 8.00 7.46 6.59 4.98 5.46 -- S.U.10/08/08 4.52 5.83 3.66 4.82 4.00 5.65 6.00 5.75 6.36 6.16 4.53 7.22 5.13 5.96 5.27 5.56 4.69 4.27 -- S.U.04/13/09 4.76 6.08 4.65 5.05 4.52 5.70 5.70 5.55 6.38 6.23 5.31 5.62 5.10 5.92 5.42 6.02 4.13 3.71 -- S.U.10/17/09 5.69 6.17 4.61 5.46 4.46 6.06 5.78 6.16 6.49 6.39 4.90 5.99 5.11 6.06 5.66 6.28 5.08 7.28 -- S.U.04/26/10 4.53 5.74 4.28 4.42 4.20 5.62 6.02 5.31 6.23 6.05 5.10 5.41 4.54 5.68 5.48 5.65 4.99 4.33 -- S.U.10/19/10 4.66 6.03 4.41 5.01 4.32 5.83 5.93 5.92 6.39 6.35 4.99 6.03 5.05 6.01 5.56 5.88 5.38 4.71 -- S.U.04/18/11 4.39 5.59 4.17 4.72 4.11 5.36 5.68 5.55 6.04 6.13 4.63 5.62 5.00 5.62 5.41 5.87 5.18 5.13 -- S.U.10/10/11 6.12 7.41 6.59 6.79 4.96 6.23 --6.24 6.38 7.15 6.08 6.21 5.25 6.24 Dry 7.91 7.13 5.78 -- S.U.04/17/12 5.33 5.56 3.88 3.91 3.46 5.76 5.80 5.57 6.38 5.86 4.69 5.38 4.68 5.74 Dry 5.92 4.62 5.76 -- S.U.10/09/12 5.58 6.19 4.85 5.22 4.98 6.14 5.57 6.06 6.49 6.07 4.74 5.70 4.67 6.04 Dry 5.73 5.32 5.17 -- S.U.04/15/13 5.19 6.26 4.02 4.71 4.28 5.95 6.12 6.04 6.57 6.67 5.28 5.77 4.70 6.04 Dry 6.07 5.52 5.31 -- S.U.09/30/13 4.83 6.22 4.74 5.31 4.72 6.14 6.23 6.02 6.48 6.14 5.33 6.24 5.67 6.16 Dry 6.13 5.73 4.97 -- S.U.04/16/14 5.28 6.46 5.14 6.16 5.00 6.41 6.64 6.29 6.77 6.70 6.19 6.72 6.07 6.47 Dry 6.61 6.50 6.23 -- S.U.10/15/14 5.63 6.59 5.30 6.12 Dry 6.55 6.62 6.73 7.07 7.06 5.85 6.65 5.73 6.58 Dry 7.13 6.66 5.60 -- S.U.04/15/15 4.61 6.09 4.40 5.93 3.01 6.33 6.44 6.36 6.97 5.86 5.56 6.74 5.93 6.48 Dry 6.57 6.33 5.54 -- S.U.10/07/15 4.38 5.29 3.51 4.70 3.59 6.07 4.11 5.32 6.32 5.60 4.44 5.52 4.12 4.52 4.37 4.80 5.94 6.46 -- S.U.04/11/16 4.81 5.78 3.82 4.94 3.75 5.66 5.70 5.27 6.41 6.42 4.87 5.07 4.87 6.29 5.61 6.32 5.58 4.74 -- Specific Conductance (field)uS/cm 04/28/06 88 697 31 27 21 398 267 728 1788 1144 56 --60 370 241 194 77 28 -- (lab prior to Oct. 07)uS/cm 10/09/06 103 635 34 120 20 398 328 622 1577 1206 48 348 45 447 332 147 74 31 -- uS/cm 04/24/07 105 621 43 98 19 323 479 594 1362 957 74 273 47 430 271 172 61 27 -- uS/cm 11/01/07 103 779 41 132 27 445 472 723 2170 1790 66 338 47 499 300 556 91 26 -- uS/cm 04/23/08 90 705 32 82 20 179 499 403 2163 1532 90 330 48 502 264 476 120 26 -- uS/cm 10/08/08 80 554 30 90 17 316 505 328 1773 1330 105 999 215 457 245 529 684 17 -- uS/cm 04/13/09 92 791 38 123 13 373 369 530 2214 1323 178 258 76 563 315 1160 148 28 -- uS/cm 10/17/09 239 879 44 216 22 623 437 854 2270 1981 81 436 45 584 403 1115 184 21 -- uS/cm 04/26/10 76 717 40 148 15 379 653 551 2184 1645 139 331 56 624 286 425 177 21 -- uS/cm 10/19/10 78 729 46 129 20 523 502 682 2199 1953 97 387 74 679 384 670 207 22 -- uS/cm 04/18/11 89 802 49 142 21 478 452 869 2395 1802 98 410 81 710 392 1406 235 21 -- uS/cm 10/10/11 281 855 53 265 24 699 --1041 2342 1452 64 418 47 671 Dry 898 302 24 -- uS/cm 04/17/12 202 807 39 118 21 619 383 698 2328 791 69 357 49 620 Dry 869 123 24 -- uS/cm 10/09/12 152 821 37 25 20 642 406 698 2092 926 58 341 56 572 Dry 627 212 20 -- uS/cm 04/15/13 71 694 34 75 18 645 405 697 2176 963 52 313 60 532 Dry 930 206 20 -- uS/cm 09/30/13 77 491 43 102 21 725 761 550 2303 1014 144 391 106 673 Dry 1227 359 22 -- uS/cm 04/16/14 95 534 54 99 58 769 697 671 2292 1103 227 422 158 690 Dry 797 684 60 -- uS/cm 10/15/14 120 580 88 148 Dry 920 640 1150 2360 1186 105 420 91 710 Dry 2260 810 45 -- uS/cm 04/15/15 87 576 40 398 23 523 300 455 1835 728 191 263 107 494 Dry 2030 846 17 -- uS/cm 10/07/15 69 588 47 118 23 907 495 1085 2381 1638 180 361 82 739 373.00 670 633 28 -- uS/cm 04/11/16 53 467 53 351 19 818 521 564 1803 1804 243 261 133 625 280 1326 759 36 -- Temperature (field)Celsius 04/28/06 16.00 15.00 14.00 16.00 16.00 17.00 17.00 13.00 18.00 18.00 18.00 --14.00 17.00 19.00 16.00 16.00 15.00 -- (lab prior to Oct. 07)Celsius 10/09/06 20.00 19.00 19.00 20.00 20.00 19.00 20.00 20.00 20.00 21.00 20.00 21.00 19.00 19.00 18.00 21.00 21.00 18.00 -- Celsius 04/24/07 18.00 17.00 17.00 19.00 17.00 17.00 18.00 16.00 20.00 19.00 17.00 16.00 16.00 16.00 18.00 19.00 17.00 19.00 -- Celsius 11/01/07 18.31 19.20 19.70 19.54 19.48 19.18 23.88 20.66 20.17 19.57 19.27 22.63 20.36 18.73 18.67 21.79 20.70 18.79 -- Celsius 04/23/08 14.84 15.59 14.80 16.55 14.83 16.52 16.28 16.61 17.82 16.83 17.56 16.92 17.97 16.55 17.33 18.28 19.26 18.49 -- Celsius 10/08/08 15.72 18.90 18.81 19.48 18.79 19.77 19.84 19.20 19.23 20.29 20.25 21.33 20.11 19.63 19.27 21.52 23.46 16.55 -- Celsius 04/13/09 14.94 14.91 14.86 15.24 14.55 15.82 16.55 14.09 18.62 16.47 16.64 14.52 15.95 16.11 17.43 17.99 17.69 16.35 -- Celsius 10/17/09 17.45 18.56 18.18 18.80 17.80 18.77 17.82 19.38 18.79 17.57 18.76 20.43 19.24 18.22 17.98 20.40 22.62 16.38 -- Celsius 04/26/10 14.40 15.51 14.85 15.66 16.23 17.05 18.24 16.05 18.45 16.52 18.63 16.30 17.85 16.85 17.25 18.44 20.91 16.89 -- Celsius 10/19/10 20.26 19.20 18.21 18.22 18.68 20.55 19.28 21.16 20.74 18.97 18.13 19.53 17.94 20.51 18.97 21.33 19.78 16.72 -- Celsius 04/18/11 17.39 15.45 15.45 16.10 15.48 16.95 19.00 15.23 21.49 17.19 18.09 15.69 17.59 17.16 19.89 19.67 22.01 17.15 -- Celsius 10/10/11 19.55 19.66 20.27 20.55 18.69 19.13 --19.40 19.20 19.52 18.65 19.40 17.70 18.65 Dry 23.36 23.08 19.07 -- Celsius 04/17/12 17.55 16.39 16.11 16.25 16.60 18.01 16.55 16.42 19.29 18.15 18.06 17.34 19.68 17.29 Dry 20.47 21.08 19.85 -- Celsius 10/09/12 18.77 18.76 18.85 20.14 18.13 20.17 20.54 19.57 19.14 20.62 18.68 19.67 18.48 19.04 Dry 22.11 22.26 16.24 -- Celsius 04/15/13 15.28 14.26 14.04 14.23 14.23 16.92 17.86 16.11 19.24 18.08 18.63 15.72 16.97 16.64 Dry 19.06 19.35 17.65 -- Celsius 09/30/13 20.70 19.30 19.50 20.40 19.00 19.90 20.70 20.80 20.10 20.60 19.60 19.20 17.90 20.10 Dry 22.20 22.10 17.80 -- Celsius 04/16/14 13.20 13.70 13.60 14.00 12.90 15.20 16.80 13.80 17.10 15.80 17.30 14.60 16.40 14.80 Dry 14.80 17.10 15.50 -- Celsius 10/15/14 18.80 18.50 19.10 20.00 Dry 18.40 19.80 19.50 19.40 18.80 18.20 17.20 17.80 18.10 Dry 20.80 20.00 18.30 -- Celsius 04/15/15 13.71 13.38 13.45 13.52 13.69 14.21 14.37 12.66 16.53 14.29 16.40 13.65 15.35 13.47 Dry 15.42 16.12 15.45 -- Celsius 10/07/15 20.40 19.01 19.57 21.15 19.20 19.99 21.67 20.61 20.46 19.76 19.78 20.46 18.60 20.04 17.64 22.92 23.64 18.76 -- Celsius 04/11/16 14.06 14.90 15.70 13.71 15.60 16.20 16.30 13.72 16.65 14.90 16.88 14.93 16.25 14.61 17.80 15.73 20.15 14.90 -- TABLE 5 Summary of Historical Groundwater Field Parameters Moore County Landfill, Permit No. 63-01 Aberdeen, North Carolina G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 2 of 2 Project No. 0739615016.400 Parameter Reporting Units Sample Date MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8*MW-9 MW-11S MW-11D*MW-13S*MW-13D*MW-14 MW-15 MW-16S MW-16D*PW-1*Blanks TABLE 5 Summary of Historical Groundwater Field Parameters Moore County Landfill, Permit No. 63-01 Aberdeen, North Carolina Turbidity (field)NTU 04/28/06 70 7.8 12 5.1 7.4 55 86 NM 240 290 NM NM NM 20 35 7.2 NM NM -- (lab prior to Oct. 07)NTU 10/09/06 65 55 34 120 13 210 500 NM 330 850 NM NM NM 500 75 --NM NM -- NTU 04/24/07 2.2 11 2.4 6 3.1 45 700 NM 350 700 NM NM NM 300 400 1.5 NM NM -- NTU 11/01/07 39.4 96.3 99.1 330 116 116 105 151 155 >1000 204 243 415 95.1 111 137 116 156 -- NTU 04/23/08 2.71 8.15 4.35 12.2 21.7 9.36 29.2 7.07 67.9 369 2.34 20.2 45.1 3.91 15.8 12.4 3.33 2.11 -- NTU 10/08/08 3.94 1.03 1.11 5.77 2.46 7.37 47.9 4.75 90.4 286 5.68 46.6 6.21 8.06 30.4 20.1 2.11 4.12 -- NTU 04/13/09 3.98 17.6 15.8 6.49 2.26 --69.4 15.6 16.7 38.2 9.91 9.42 13.7 12.6 81.5 28.8 2.33 5.20 -- NTU 10/17/09 13.3 4.02 3.52 52.8 3.17 4.18 207 7.79 30.8 85.4 2.32 25.0 2.89 5.96 36.8 24.0 3.20 12.7 -- NTU 04/26/10 6.23 4.92 4.20 6.69 5.07 13.0 37.4 10.9 61.0 648 5.83 18.2 5.54 2.67 32.9 17.7 7.09 11.6 -- NTU 10/19/10 10.3 36.1 2.44 52.9 17.8 12.8 71.3 <100 23.0 87.6 0.43 39.2 6.73 <100 8.36 8.94 2.54 1.61 -- NTU 04/18/11 32.1 13.0 78.9 35.4 30.2 8.57 83.7 12.8 19.0 145 100 20.0 26.1 12.1 12.1 35.8 22.1 9.13 -- NTU 10/10/11 35.8 6.70 5.13 15.8 35.9 15.2 --18.7 11.5 52.8 57.7 10.6 26.4 66 Dry 15.6 76.7 5.13 -- NTU 04/17/12 76.6 74.0 7.35 64.0 31.6 25.8 97.6 22.5 91.5 84.9 51.2 21.5 26.8 80.4 Dry 95.4 18.1 11.80 -- NTU 10/09/12 32.7 2.57 2.25 64.7 20.1 14.7 82.0 41.7 17.8 47.3 5.77 2.04 18.8 9.06 Dry 19.3 24.7 1.28 -- NTU 04/15/13 46.5 9.02 7.47 71.5 15.8 129 55.4 57.9 33.9 200 14.6 15.60 44.3 12.7 Dry 26.1 30.9 14.4 -- NTU 09/30/13 33.1 9.06 7.12 52.5 12.1 36.7 30.5 24.7 61.0 44.6 26.4 8.75 13.7 16.3 Dry 12.1 51.3 32.1 -- NTU 04/16/14 51.2 8.42 19.1 58.8 24.2 46.5 47.5 16.9 19.0 82.6 30.1 13.8 17.4 18.5 Dry 24.1 52.5 11.1 -- NTU 10/15/14 53 2.06 3.81 62.7 Dry 18.6 46.6 7.03 66.2 93.6 24.7 17.2 13.6 10 Dry 51 39.9 1.6 -- NTU 04/15/15 21.0 4.76 1.21 18.8 35.7 22.3 31.1 36.9 11.8 48.5 26.1 13.2 24.9 18.4 Dry 29.0 142 5.32 -- NTU 10/07/15 25.4 0.99 0.78 39.5 4.85 19.3 32.6 1.81 8.6 724 10.1 30.1 45.5 9.19 25.20 11.0 3.83 6.16 -- NTU 04/11/16 10.4 2.23 0.77 18.1 3.67 16.5 10.7 1.34 22.60 148 4.38 3.7 11.8 15.8 94.1 5.9 39.2 5.81 -- Oxidation Reduction Pot.mV 04/28/06 258 79 254 239 286 2 9 NM -43 -46 NM NM NM 31 128 265 NM NM -- (field)mV 10/09/06 2.4 32 220 194 232 4 -2 NM -4 -68 NM NM NM 7 -7 252 NM NM -- (lab prior to Oct. 07)mV 04/24/07 168 32 220 198 190 -8 -38 NM -60 -77 NM NM NM 9 22 224 NM NM -- mV 11/01/07 332 -48 331 180 252 -84 -119 NM -123 -171 NM NM NM -87 -72 18 NM NM -- mV 04/23/08 21.4 -4.7 67.1 45.7 60.9 -112.5 -113.5 -90.9 -81.7 -101.6 65.2 -89.5 50.4 -58.2 -133.5 31.1 134.8 NM -- mV 10/08/08 228 66.1 309.3 217.6 223.0 -106.6 -65.1 -32.1 -94.4 -72.1 164 -119 89 -45.3 -60.7 66.1 179 NM -- mV 04/13/09 283.5 -8.3 292.0 214.4 285.2 -73.6 -28.5 -17.9 -90.9 -87.8 92.5 -22.8 119.4 -25.1 -27.0 -16.3 332.2 363.2 -- mV 10/17/09 36.9 -18.1 255.8 117.6 296.9 -54.6 -24.6 -59.9 -94.3 -92.5 192.7 -62.6 134.8 -48.3 -16.4 -48.4 182.0 NM -- mV 04/26/10 172.8 28.0 173.3 200.1 221.0 -98.0 -42.7 -15.6 -85.9 -86.7 83.5 -52.3 118.0 -48.5 -77.9 54.4 145.7 NM -- mV 10/19/10 148.0 82.9 198.7 208.2 282.2 -81.7 -22.4 -48.9 -94.8 -83.7 104.9 -51.8 155.3 -44.0 -109.6 71.1 132.6 NM -- mV 04/18/11 223.4 45.2 220.0 214.4 267.0 -16.8 -44.7 12.8 -79.4 -62.8 208.7 11.8 121.3 -30.9 -5.1 -2.2 151.4 207.0 -- mV 10/10/11 23.3 15.7 142.6 97.3 80.9 -86.3 ---75.4 -102.4 -47.6 138.6 -70.1 87.4 -85.1 Dry -25.9 61.8 109.7 -- mV 04/17/12 67.2 138.4 180.8 163.0 244.8 -61.1 1.90 -24.4 -111.8 -27.9 141.7 -5.4 126.4 -53.9 Dry 16.3 187.8 NM -- mV 10/09/12 70.0 19.4 101.4 89.8 106.2 -79.3 -32.1 -53.2 -98.0 -58.9 85.8 -32.2 111.0 -76.4 Dry 13.1 60.8 NM -- mV 04/15/13 193.0 86.5 214.9 133.0 198.6 -38.7 -60.7 -72.5 -113.4 -86.8 170.1 -33.9 106.8 -74.4 Dry -4.7 116.7 NM -- mV 09/30/13 308.5 128.0 332.6 213.2 286.1 -45.7 -43.9 -16.4 -64.6 -41.6 138.6 -33.2 104.8 -34.6 Dry -3.3 81.0 NM -- mV 04/16/14 282.2 142.5 338.4 232.2 338.3 -59.3 -55.0 -39.8 -42.2 -95.8 40.4 -62.2 88.3 -60.0 Dry 4.9 31.3 NM -- mV 10/15/14 245.9 58.8 394.5 187.1 Dry -56.1 -21.9 -60.7 -103 -77.9 209.1 -56.2 177.5 -38.6 Dry -81.9 25 336.9 -- mV 04/15/15 90.4 -20.8 65.1 -22.1 339.9 -55.9 -19.8 -36.6 -97.2 -9.1 61.4 -52.6 6.8 -63.3 Dry -53.7 16.5 119.2 -- mV 10/07/15 18.1 -61.9 20.2 -40.5 115.6 -73.1 -96.2 -100 -135.7 -182.9 3.8 -20.9 27.1 -61.1 ---77.2 -116.5 -45.5 -- mV 04/11/16 189.7 105 354.2 64 373.4 -41.8 24.7 -14.6 -70.4 -70.3 50.4 -29.2 40.7 -55.3 ---29.09 8 177.9 -- Dissolved Oxygen (field)mg/L 04/28/06 7.02 0.59 4.19 7.79 7.98 0.63 0.44 NM 0.47 1.02 NM NM NM 0.32 0.37 0.49 NM NM -- (lab prior to Oct. 07)mg/L 10/09/06 1.32 0.38 2.23 0.50 6.59 0.36 0.55 NM 0.87 0.41 NM NM NM 0.35 1.49 0.25 NM NM -- mg/L 04/24/07 6.37 5.25 4.26 4.26 10.02 0.90 1.19 NM 0.75 0.99 NM NM NM 0.91 1.41 0.84 NM NM -- mg/L 11/01/07 7.26 0.64 4.93 2.17 8.02 0.75 0.33 NM 0.47 0.40 NM NM NM 1.08 0.41 0.59 NM NM -- mg/L 04/23/08 5.66 1.53 6.74 4.50 9.65 1.78 1.66 2.24 2.20 1.55 1.69 2.29 2.49 1.48 1.60 1.58 2.43 NM -- mg/L 10/08/08 5.41 0.81 3.84 1.67 7.12 0.49 0.86 0.85 6.29 0.72 2.28 0.67 0.54 0.98 1.46 2.15 0.79 NM -- mg/L 04/13/09 5.55 1.40 5.52 2.65 8.29 0.67 1.38 1.31 0.78 1.12 1.49 0.68 2.06 1.30 1.66 1.45 2.00 NM -- mg/L 10/17/09 1.84 1.23 4.89 1.80 9.10 0.74 0.55 2.05 1.05 0.85 0.88 0.89 1.37 1.04 3.97 1.15 0.95 NM -- mg/L 04/26/10 4.23 0.91 5.52 1.06 7.96 0.54 1.98 1.08 0.70 0.28 1.23 0.43 0.99 1.05 0.96 1.28 1.21 NM -- mg/L 10/19/10 4.77 0.27 4.52 2.07 7.77 0.31 1.50 0.50 0.31 0.60 0.54 0.25 1.96 0.60 0.36 0.47 1.13 NM -- mg/L 04/18/11 4.94 0.59 5.15 1.90 8.02 0.65 2.38 0.77 0.59 0.25 0.46 0.89 0.97 0.55 0.72 0.62 0.89 8.89 -- mg/L 10/10/11 1.09 0.64 4.53 0.86 6.78 0.87 --1.09 0.93 0.79 0.60 0.63 0.53 0.62 Dry 0.65 1.07 6.60 -- mg/L 04/17/12 1.58 0.68 5.64 1.44 9.09 0.29 7.01 1.07 0.88 1.31 1.00 0.24 1.78 0.91 Dry 1.01 2.73 NM -- mg/L 10/09/12 0.56 0.49 2.98 4.86 6.36 0.43 6.38 0.44 0.57 0.23 0.23 0.48 0.39 0.23 Dry 0.24 0.32 NM -- mg/L 04/15/13 5.34 0.73 6.64 2.97 8.50 1.13 40.5 0.54 0.41 1.04 0.86 0.83 0.89 0.81 Dry 0.82 1.21 NM -- mg/L 09/30/13 1.95 0.40 2.48 0.70 7.46 2.29 0.70 0.37 0.34 0.68 0.32 0.42 0.47 0.42 Dry 0.27 0.61 NM -- mg/L 04/16/14 6.04 0.39 5.89 7.87 8.20 1.05 1.55 0.48 0.36 0.49 0.33 0.77 0.49 0.53 Dry 1.79 1.79 NM -- mg/L 10/15/14 0.95 0.58 1.93 1.07 Dry 0.67 1.27 0.41 0.88 0.85 0.57 0.90 0.71 0.68 Dry 0.60 0.65 6.14 -- mg/L 04/15/15 3.19 0.59 4.00 0.53 7.24 0.96 1.72 0.75 0.69 0.61 0.89 0.84 0.86 0.86 Dry 0.59 0.68 9.88 -- mg/L 10/07/15 3.61 1.65 2.76 1.90 5.45 0.59 0.35 0.72 5.13 0.40 0.93 1.24 2.00 0.38 --0.49 0.81 8.02 -- mg/L 04/11/16 3.42 0.87 3.93 1.17 7.77 0.92 1.21 0.82 0.54 1.01 1.85 0.87 1.16 0.53 --0.58 1.30 8.24 -- Notes: 1.) mg/L = milligrams per liter 2.) ND = not detected at or above the laboratory reporting limit 3.) NM = not measured 4.) uS/cm = microseimens per centimeter 5.) NTU = Nephelometric Turbidity Units 6.) S.U. = Standard Units 7.) Samples collected using low-flow purge and sample techniques (when possible). 8.) * = Parameters shown are from purging. Monitoring well was bailed and bottles were filled. No water was left for parameters at the time of sampling. G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx Feburary 2017 Page 1 of 1 TABLE 6 September 2016 ASD Groundwater Samping Results Summary Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Detected Monitoring Constituent/Parameter EPA METHOD UNITS MDL SWSL pH SM 4500H+B-2000 pH 1 6-9 4.7 6.6 6.4 6.2 6.9 6.7 ND Bicarbonate (as CaCO3)SM 4500CO2 D-1997 mg/L 14 NE ND 520 64 120 770 330 ND Sodium Total EPA 6010D ug/L 400 NE 1520 83900 14800 35600 111000 77000 ND Calcium Total EPA 6010D ug/L 39 NE 363 159000 9430 10500 139000 67200 ND Magnesium Total EPA 6010D ug/L 29 NE 382 33800 4540 6440 27600 18200 ND Potassium Total EPA 6010D ug/L 150 NE 372 J 35200 3040 5190 66000 25100 ND Boron Total EPA 6010D ug/L 5.7 NE 13.2 J 2970 126 59.8 6050 3500 6.03 Sulfide SM 4500S2 D-2000 ug/L 0 1 ND ND ND 0.02 J 0.10 J 0.012 J ND Chloride EPA 300.0 ug/L 0.002 NE 2.3 J 46 11 34 48 0.025 ND Nitrate as N EPA 353.2 ug/L 0.025 10 0.58 J 0.082 J 0.13 J 0.10 J 0.10 J 0.092 J ND Nitrite as N EPA 353.2 ug/L 0.017 1 ND ND ND ND ND ND ND Total Dissolved Solids SM 2540C-1997 ug/L 50 NE ND 810 ND 270 870 490 ND Sulfate as SO4 EPA 300.0 ug/L 2.9 250 ND 66 J 11 J 13 J 79 J 100 J ND Total Alkalinity as CaCO3 EPA 310.2 ug/L 14 NE ND 520 64 120 770 330 ND Carbonate (as CaCO3)SM 4500CO2 D-1997 ug/L 0.014 NE ND ND ND ND ND ND ND Ammonia as N EPA 350.1 ug/L 0.45 NE ND 44 3.2 8.7 52 17 ND Notes: 1.) ug/L = Micrograms per liter 2.) J = Estimated concentration reported below Solid Waste Section Limit 3.) NE = Not existing 4.) MDL = Method Detection Limit 5.) SWSL = Solid Waste Section Limit 6.) Samples from MW-16D were diluted at 10x for sulfate. Samples from MW-11S, MW-16S, MW-16D were diluted at 10x for alkalinity. Samples from MW-11S, MW-11D, MW-14, MW-16S, MW-16D were diluted at 10x for ammonia. 7.) Samples presented were collected on September 7, 2016. BlankMW-5 MW-14MW-11S MW-11D MW-16S MW-16D G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 1 TABLE 7 September 2016 ASD Soil-Gas (or Headspace) Sampling Results Summary Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Ethylbenzene TO-15 ppbv 1.2 14 ND ND ND ND ND 0.40 J 4-Methyl-2-pentanone TO-15 ppbv 1.8 14 21 ND ND ND ND ND Toluene TO-15 ppbv 1.1 14 190 1.5 J 1.6 J 1.5 J 2.4 J 2.2 J n-Hexane TO-15 ppbv 1.7 14 96 440 ND ND ND ND Cyclohexane TO-15 ppbv 1.5 14 51 110 ND ND ND 0.77 J Propene TO-15 ppbv 1.8 14 ND ND 4.3 J ND 11 J 5.6 J Tetrachloroethene TO-15 ppbv 1.0 14 ND ND 28 ND 4.5 J 0.53 J Xylenes (Total)TO-15 ppbv 2.4 14 ND ND ND ND ND 1.9 J Heptane TO-15 ppbv 1.5 14 81 8.1 J ND ND 2.0 J 1.0 J cis-1,2-Dichloroethene TO-15 ppbv 1.2 14 50 ND 13 J ND 1.6 J ND trans-1,2-Dichloroethene TO-15 ppbv 1.1 14 2.2 J ND ND ND ND ND Methyl-tert-butyl ether TO-15 ppbv 0.97 14 10 J ND ND ND ND ND 2,2,4-Trimethylpentane TO-15 ppbv 1.4 14 49 26 ND ND ND ND 2-Hexanone TO-15 ppbv 2.1 14 4.8 J ND ND ND ND 2.6 J 4-Ethyltoluene TO-15 ppbv 1.5 14 ND ND ND ND ND 0.49 J 2-Propanol TO-15 ppbv 31 130 250 ND ND ND ND ND Acetone TO-15 ppbv 83 130 500 260 350 130 1700 83 Chloroform TO-15 ppbv 1.0 14 2.5 J 1.2 1.2 ND ND ND Benzene TO-15 ppbv 1.2 14 38 ND 2.1 J ND ND 0.81 J 1,1,1-Trichloroethane TO-15 ppbv 0.86 14 1.8 J ND ND ND ND ND Chloromethane TO-15 ppbv 1.6 14 3.6 J 15 ND ND ND ND Chloroethane TO-15 ppbv 1.5 14 20 ND ND ND ND ND Vinyl chloride TO-15 ppbv 1.6 14 210 ND 2.0 J ND ND ND Methylene chloride TO-15 ppbv 1.6 14 15 ND ND ND ND ND Carbon disulfide TO-15 ppbv 1.2 14 3.3 J ND 19 ND 1.7 J 0.44 J 1,1-Dichloroethane TO-15 ppbv 1.1 14 9.1 J ND 2.4 J ND ND ND Trichlorofluoromethane TO-15 ppbv 0.92 14 6.4 J ND ND ND ND ND Dichlorodifluoromethane TO-15 ppbv 1.3 14 31 ND ND ND ND ND Freon 114 TO-15 ppbv 1.8 14 3.7 J ND ND ND ND ND 2-Butanone TO-15 ppbv 35 130 360 ND ND 6.1 J ND 21 Trichloroethene TO-15 ppbv 1.2 14 ND ND 5.7 J ND 3.1 J ND 1,2,4-Trimethylbenzene TO-15 ppbv 1.6 14 ND ND ND ND ND 0.54 J Total Light Petroleum Hydrocarbons TO-15 ppbv 1300 1300 3300 27000 15000 15000 22000 15000 Notes: 1.) ug/L = Micrograms per liter 2.) J = Estimated concentration reported below Method Quanitation Limit 3.) D = Sample diluted prior to analysis 4.) MDL = Method Detection Limit 5.) MQL = Method Quantitation Limit 5.) SWSL = Solid Waste Section Limit 6.) Dilutions: GV-32 @ 1.35x; MW-11S @ 1.54x; MW-11D @ 1.58x; MW-14 @ 1.37x; MW-16S @ 1.57x; and MW-16D @ 1.58x 7.) Samples were taken on September 7, 2016. Result Result Result Result Result Result GV-32 MW-11S MW-11D MW-14 MW-16S MW-16DMQLDetected Monitoring Constituent/Parameter Method Units MDL G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 1 TABLE 8 September 2016 ASD Leachate Sampling Results Summary Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina 0739615016.400 Detected Monitoring Constituent/Parameter EPA METHOD UNITS MDL SWSL L-1(MSW)L-2 (C&D) Sodium Total 6010D ug/L 400 NE 592000 10300 Calcium Total 6010D ug/L 39.0 NE 227000 118000 Magnesium Total 6010D ug/L 29.0 NE 230000 11200 Potassium Total 6010D ug/L 150 NE 225000 14500 Boron Total 6010D ug/L 5.70 NE 2750 1460 Benzene 8260B ug/L 0.15 1 2.9 ND 1,4-Dichlorobenzene 8260B ug/L 0.19 1 2.2 ND Ethylbenzene 8260B ug/L 0.13 1 12 ND Toluene 8260B ug/L 0.14 1 3.2 ND Vinyl chloride 8260B ug/L 0.32 1 1.0 ND Xylenes (Total)8260B ug/L 0.45 5 13 ND Bicarbonate (as CaCO3)SM 4500CO2 D-1997 mg/L 14 NE 2300 190 Chloride 300.0 mg/L 22 NE 580 2.6 J Nitrite as N 353.2 mg/L 0.017 1000 0.018 J ND Total Dissolved Solids SM 2540C-1997 mg/L 100 NE 3600 480 Sulfate as SO4 300.0 mg/L 29 250000 730 J 160 J Total Alkalinity as CaCO3 310.2 mg/L 700 NE 2300 190 Ammonia as N 350.1 mg/L 20 NE 340 0.38 pH SM 4500H+B-2000 S.U.1.0 7.2 7.4 Notes: 1.) ug/L = Micrograms per liter 2.) mg/L = milligrams per liter 3.) J = Estimated concentration reported below Solid Waste Section Limit 4.) MDL = Method Detection Limit 5.) SWSL = Solid Waste Section Limit 6.) NE = Not existing 7.) S.U. = Standard units 8.) Dilutions: Chloride @ 10x; Sulfate @ 10x; Alkalinity @ 50x; Ammonia @ 450x 9.) L-1 was sampled on September 8, 2016. L-2 was sampled on September 7, 2016. G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 Page 1 of 1 Project No. 0739615016.400 Parameter Reporting Units Sample Date Method Detection Limit Dissolved Methane mg/L 04/11/16 0.0004 0.000608 J 0.0640 ND 0.535000 ND 3.8 3.59 NM 3.79 1.3 NM NM NM 2.10 2.30 0.585 NM ND Headspace Methane %04/11/16 0.1 NS 0.0 0.0 0.0 0.0 14.8 15.2 NS 0.4 0.0 NS NS NS 0.0 10.6 0.0 NS NA April 2016 Dissolved Methane Results and Headspace Methane Readings Moore County Landfill, Permit No. 63-01 Aberdeen, North Carolina TABLE 9 MW-13D*MW-14 MW-15 MW-16S MW-16D*BlanksMW-7 MW-8*MW-9 MW-11S MW-11D*MW-13S*MW-6MW-1 MW-2 MW-3 MW-4 MW-5 G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 1 of 1 TABLE 10 Henry's Law Calculations (Groundwater to Soil-Gas) Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D 1,1-Dichloroethane ND 0.42 1.7 0.66 ND 0.62 98.96 25 101.325 2.47E+02 --103.834 420.280 163.167 --153.278 2.30E-01 --23.88 96.66 37.53 --35.25 9.1 ND 2.4 ND ND ND 1,2-Dichlorobenzene ND ND ND 1.0 0.59 ND 147.01 25 101.325 1.66E+02 ------166.419 98.187 --7.79E-02 ------12.96 7.65 --ND ND ND ND ND ND1,4-Dichlorobenzene 2.2 2.1 2.1 4.8 1.2 0.47 147.00 25 101.325 1.66E+02 366.146 349.503 349.503 798.864 199.716 78.222 9.96E-02 36.47 34.81 34.81 79.57 19.89 7.79 ND ND ND ND ND ND Acetone ND 52 ND ND 21.0 ND 58.08 25 101.325 4.21E+02 --21904.122 ----8845.895 --1.59E-03 --34.83 ----14.06 --500 260 350.0 130.0 1700.0 83.0 Benzene 2.9 1.8 1.3 2.2 1.0 0.61 78.12 25 101.325 3.13E+02 908.207 563.715 407.127 688.985 313.175 191.037 2.28E-01 207.07 128.53 92.83 157.09 71.40 43.56 38 ND 2.1 ND ND 0.81ChlorobenzeneND0.88 0.71 2.6 0.65 ND 112.56 25 101.325 2.17E+02 --191.270 154.320 565.117 141.279 --1.52E+01 --2907.31 2345.67 8589.78 2147.44 --ND ND ND ND ND ND cis-1,2-Dichloroethene ND 1.1 8.6 3.1 3.9 3.9 96.94 25 101.325 2.52E+02 --277.612 2170.424 782.362 984.262 984.262 1.67E-01 --46.36 362.46 130.65 164.37 164.37 50 ND 13.0 ND 1.6 NDEthylbenzene12NDNDNDNDND106.17 25 101.325 2.30E+02 2765.265 ----------3.23E-01 893.18 ----------ND ND ND ND ND 0.4TetrachloroethaneNDND0.67 ND ND ND 165.83 25 101.325 1.48E+02 ----98.846 ------7.54E-01 ----74.53 ------ND ND 28.0 ND 4.5 0.53 Toluene 3.2 ND ND ND ND ND 92.13 25 101.325 2.66E+02 849.763 ----------2.72E-01 231.14 ----------190 1.5 1.6 1.5 2.4 2.2TrichloroetheneNDND0.70 ND ND ND 131.39 25 101.325 1.86E+02 ----130.342 ------4.22E-01 ----55.00 ------ND ND 5.7 ND 3.1 NDVinyl Chloride 1.0 2.8 2.5 3.3 1.2 0.61 62.50 25 101.325 3.91E+02 391.444 1096.042 978.609 1291.764 469.732 238.781 1.11E+00 434.50 1216.61 1086.26 1433.86 521.40 265.05 210 ND 2.0 ND ND ND Xylenes 13 ND ND ND ND ND 106.17 25 101.325 2.30E+02 2995.647 ----------2.76E-01 826.80 ----------ND ND ND ND ND 1.9 Notes: 1) ug/L = micrograms per liter 2) Calculated groundwater concentrations based on headspace gas sample analyses from the April 2016 sampling event. 4.) Henry's law constant obtained from: www.nj.gov/dep/stp/guidance/rs/chemproperties.pdf 5) Henry's Law Constant = dimensionless value6) ppbv = parts per billion by volume 7) -- = not calculated 8) Bold = calculated concentrations greater than 2L Groundwater Standard9) ND = not detected 10) Shaded cells = identified as constituents of concern for the facility as discussed in text 11) ppb (v/v) = parts per billion on a volume by volume basis12) NC 2L Standard = the North Carolina groundwater standards 13) SWSL = Solid Waste Section Limit14) Molecular weights calculated using values from Microseeps conversion table. = Henry's Law constants coverted to dimensionless speciation from listed values obtained from "Compilation of Henry's Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry" by Rolf Sander Version 3 (April 8, 1999). 3) Values obtained from Table 2 - Summary of Non-Methane organic Compounds in Various Landfills in "A Review of the Literature Regarding Non-Methane and Volatile Organic Compounds In Municipal Solid Waste Landfill Gas" by Hamideh Soltani-Ahmadi and from the 1996, EPA, Soil Screening User Guidance, EPA/540/r-96/018. PARAMETER Groundwater Sample Concentrations (ug/L)Molecular Weight (g/mol) Temperature (°C) Pressure (1 atm = 101.325 kPA) ug/L to ppbv conversion Gas Concentrations (ug/L-gas) Henry's Law Constant (Dimensionle ss) Calculated Soil Gas Concentrations (ppbv)Actual Soil Gas Concentrations (ppbv) G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 1 of 1 TABLE 11 Henry's Law Calculations (Soil-Gas to Groundwater)Moore County Landfill, NCSWP # 63-01Aberdeen, North Carolina Project No. 0739615016.400 GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D GV-32 MW-11S MW-11D MW-14 MW-16S MW-16D 1,1,1-Trichloroethane 1.8 ND ND ND ND ND 133.40 25 101.325 5.45E-03 0.010 ----------7.05E-01 0.01 ----------ND ND ND ND ND ND 200 11,1-Dichloroethane 9.1 ND 2.4 ND ND ND 98.96 25 101.325 4.04E-03 0.037 --0.010 ------2.30E-01 0.16 --0.04 ------ND 0.42 1.7 0.66 ND 0.62 6 51,2-Dichlorobenzene ND ND ND ND ND ND 147.01 25 101.325 6.01E-03 ------------7.79E-02 ------------ND ND ND 1.0 0.59 ND 20 51,4-Dichlorobenzene ND ND ND ND ND ND 147.00 25 101.325 6.01E-03 ------------9.96E-02 ------------ND 2.1 2.1 4.8 1.2 0.47 6 12-Butanone 360 ND ND 6.1 ND 21 72.11 25 101.325 2.95E-03 1.061 ----0.018 --0.062 2.30E-03 461.34 ----7.82 --26.91 ND ND ND ND ND ND 4000 1004-Methyl-2-pentanone 21 ND ND ND ND ND 100.16 25 101.325 4.09E-03 0.086 ----------2.20E+00 0.04 ----------ND ND ND ND ND ND 560*100 Acetone 500 260 350 130 1700 83 58.08 25 101.325 2.37E-03 1.187 0.617 0.831 0.309 4.036 0.197 1.59E-03 746.54 388.20 522.57 194.10 2538.22 123.92 ND 52 ND ND ND ND 6000 100 Benzene 38 ND 2.1 ND ND 0.81 78.11 25 101.325 3.19E-03 0.121 --0.007 ----0.003 2.28E-01 0.53 --0.03 ----0.01 2.9 1.8 1.3 2.2 1.0 0.61 1 1 Carbon Disulfide 3.3 ND 19 ND 1.7 0.44 76.14 25 101.325 3.11E-03 0.010 --0.059 --0.005 0.001 1.24E+00 0.01 --0.05 --0.00 0.00 ND ND ND ND ND ND 700 100ChlorobenzeneNDNDNDNDNDND112.56 25 101.325 4.60E-03 ------------1.52E+01 ------------ND 0.88 0.71 2.6 ND ND 50 3Chloroethane20NDNDNDNDND64.51 25 101.325 2.64E-03 0.053 ----------3.61E-01 0.15 ----------ND ND ND ND ND ND 3000 10 Chloroform 2.5 ND ND ND ND ND 119.38 25 101.325 4.88E-03 0.012 ----------1.50E-01 0.08 ----------ND ND ND ND ND ND 70 5 Chloromethane 3.6 15 ND ND ND ND 50.49 25 101.325 2.06E-03 0.007 0.031 --------3.61E-01 0.02 0.09 --------ND ND ND ND ND ND 3 1cis-1,2-Dichloroethene 50 ND 13 ND 1.6 ND 96.95 25 101.325 3.96E-03 0.198 --0.052 --0.006 --1.67E-01 1.19 --0.31 --0.04 --ND 1.1 8.6 3.1 3.9 3.9 70 5EthylbenzeneNDNDNDNDND0.40 106.17 25 101.325 4.34E-03 ----------0.002 3.23E-01 ----------0.01 12 ND ND ND ND ND 600 1 Methylene Chloride 15 ND ND ND ND ND 84.93 25 101.325 3.47E-03 0.052 ----------8.89E-02 0.59 ----------ND ND ND ND ND ND 5 1 Tetrachloroethane ND ND 28 ND 4.5 0.53 165.82 25 101.325 6.78E-03 ----0.190 --0.031 0.004 7.54E-01 ----0.25 --0.04 0.00 ND ND 0.67 ND ND ND 0.7 1Toluene1901.5 1.6 1.5 2.4 2.2 92.14 25 101.325 3.77E-03 0.716 0.006 0.006 0.006 0.009 0.008 2.72E-01 2.63 0.02 0.02 0.02 0.03 0.03 3.2 ND ND ND ND ND 600 1trans-1,2-Dichloroethene 2.2 ND ND ND ND ND 96.94 25 101.325 3.96E-03 0.009 ----------3.85E-01 0.02 ----------ND ND ND ND ND ND 100 5 Trichloroethene ND ND 5.7 ND 3.1 ND 131.40 25 101.325 5.37E-03 ----0.031 --0.017 --4.22E-01 ----0.07 --0.04 --ND ND 0.70 ND ND ND 3 1 Trichlorofluoromethane 6.4 ND ND ND ND ND 137.37 25 101.325 5.61E-03 0.036 ----------3.98E+00 0.01 ----------ND ND ND ND ND ND 2000 1Vinyl Chloride 210 ND 2.0 ND ND ND 62.50 25 101.325 2.55E-03 0.536 --0.005 ------1.11E+00 0.48 --0.00 ------1.0 2.8 2.5 3.3 1.2 0.61 0.03 1XylenesNDNDNDNDND1.9 106.16 25 101.325 4.34E-03 ----------0.008 2.76E-01 ----------0.03 13 ND ND ND ND ND 500 5 Notes: 1) ug/L = micrograms per liter 2) Calculated groundwater concentrations based on headspace gas sample analyses from the April 2016 sampling event. 4) Henry's Law Constant = dimensionless value5) ppbv = parts per billion by volume 6) -- = not calculated 7) Bold = calculated concentrations greater than 2L Groundwater Standard8) ND = not detected9) Shaded cells = identified as constituents of concern for the facility as discussed in text 10) ppb (v/v) = parts per billion on a volume by volume basis 11) NC 2L Standard = the North Carolina groundwater standards12) SWSL = Solid Waste Section Limit= Henry's Law constants coverted to dimensionless speciation from listed values obtained from "Compilation of Henry's Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry" by Rolf Sander Version 3 (April 8, 1999). SWSL (ug/L) 3) Values obtained from Table 2 - Summary of Non-Methane organic Compounds in Various Landfills in "A Review of the Literature Regarding Non-Methane and Volatile Organic Compounds In Municipal Solid Waste Landfill Gas" by Hamideh Soltani-Ahmadi and from the 1996, EPA, Soil Screening User Guidance, EPA/540/r-96/018. ppbv to ug/L conversion Gas Concentrations (ug/L-gas)Henry's Law Constant (Dimensionless) Calculated Water Concentrations (ug/L)Actual Water Concentrations (ug/L)NC 2L Standard(ug/L) PARAMETER Observed Headspace Samples (ppbv)Molecular Weight (g/mol) Temperature (°C) Pressure (1 atm = 101.325 kPA) G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 1 of 1 TABLE 12 Mixing Calculations (C and D Leachate and Background) Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Solution 1:L-2 (C&D Landfill Condensate/Leachate) Solution 2:MW-5 (Upgradient Monitoring Well) Percentage of solution 1 in target solution 1%-70% Solution 1 100%70%58%45%33%20%10%9%8%7%6%5%4%3%2%1%0% Solution 2 0%30%42%55%67%80%90%91%92%93%94%95%96%97%98%99%100% Na+1 (mg/L)10.3 8 7 5 4 3 2 2 2 2 2 2 2 2 2 2 1.52 35.6 83.9 14.8 111 77 K+1 (mg/L)14.5 10 9 7 5 3 2 2 2 1 1 1 1 1 1 1 0.372 5.19 35.2 3.04 66 25.1 Ca+2 (mg/L)118 83 69 53 39 24 12 11 10 9 7 6 5 4 3 2 0.363 10.5 159 9.43 139 67.2 Mg+2 (mg/L)11.2 8 7 5 4 3 1 1 1 1 1 1 1 1 1 0 0.382 6.44 33.8 4.54 27.6 18.2 Cl-1 (mg/L)2.6 3 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2.3 34 46 11 48 25 CO2-3 (mg/L)0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 HCO3-1 (mg/L)190 133 110 86 63 38 19 17 15 13 11 10 8 6 4 2 0 120 520 64 770 330 SO4-2 (mg/L)160 112 93 72 53 32 16 14 13 11 10 8 6 5 3 2 0 13 66 11 79 100 Notes: 1) mg/L = milligrams per Liter 2) % = percent Mixture Proportions Direct Comparison MW-14 MW-11S MW-11D MW-16S MW-16D G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx February 2017 1 of 1 TABLE 13 Mixing Calculations (MSW Leachate and Background) Moore County Landfill, NCSWP # 63-01 Aberdeen, North Carolina Project No. 0739615016.400 Solution 1:L-1 (MSW Landfill Condensate/Leachate) Solution 2:MW-5 (Upgradient Monitoring Well) Percentage of solution 1 in target solution 1%-70% Solution 1 100%70%58%45%33%20%10%9%8%7%6%5%4%3%2%1%0% Solution 2 0%30%42%55%67%80%90%91%92%93%94%95%96%97%98%99%100% Na+1 (mg/L)592 415 344 267 196 120 61 55 49 43 37 31 25 19 13 7 1.52 35.6 83.9 14.8 111 77 K+1 (mg/L)225 158 131 101 74 45 23 21 18 16 14 12 9 7 5 3 0.372 5.19 35.2 3.04 66 25.1 Ca+2 (mg/L)227 159 132 102 75 46 23 21 18 16 14 12 9 7 5 3 0.363 10.5 159 9.43 139 67.2 Mg+2 (mg/L)230 161 134 104 76 46 23 21 19 16 14 12 10 7 5 3 0.382 6.44 33.8 4.54 27.6 18.2 Cl-1 (mg/L)580 407 336 262 193 118 60 54 49 43 37 31 25 20 14 8 2.3 34 46 11 48 25 CO2-3 (mg/L)0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 HCO3-1 (mg/L)2300 1610 1334 1035 759 460 230 207 184 161 138 115 92 69 46 23 0 120 520 64 770 330 SO4-2 (mg/L)730 511 423 329 241 146 73 66 58 51 44 37 29 22 15 7 0 13 66 11 79 100 Notes: 1) mg/L = milligrams per Liter 2) % = percent Mixture Proportions Direct Comparison MW-14 MW-11S MW-11D MW-16S MW-16D G:\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\B_Tables\Tables.xlsx FIGURES Golder Associates NC, Inc. Copyright:© 2013 National Geographic Society, i-cubed FIGURE ALTERNATE SOURCE DEMONSTRATIONC&D LANDFILL, SW PERMIT NO. 63-01 1 SITE LOCATION MAP Map: G:\PROJECTS\Moore County\Groundwater\CAER\Figures\Figure 1 - Site Location Map.mxd | Modified: 2/28/2017 12:57:51 PM | Plotted: 2/28/2017 12:58:01 PM by bdraperPROJECT No.0739615011.500 ³ Property Line LEGEND TITLE PROJECT/REPORT 2,000 0 2,0001,000 FEET1:24,000SCALE REFERENCES Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet USGS Map provided by USA Topo Map GIS Application. Golder Associates NC, Inc. Km Tp Tp Km Copyright:© 2013 National Geographic Society, i-cubed FIGURE ALTERNATE SOURCE DEMONSTRATIONC&D LANDFILL, SW PERMIT NO. 63-01 2 GEOLOGIC MAP Map: G:\PROJECTS\Moore County\Groundwater\CAER\Figures\Figure 2. - Geologic Map.mxd | Modified: 2/28/2017 12:59:44 PM | Plotted: 2/28/2017 12:59:52 PM by bdraperPROJECT No.0739615011.500 ³ Property LineGeological Formation Km Middendorf Formation - Cretaceous in age; Composedof sand, sandstone, and mudstone, gray to pale graywith an orange cast, mottled; clay balls and iron-cemented concretions common, beds laterallydiscontinuous, cross-bedding common. Tp Pinehurst Formation - Tertiary in age; Composed ofsand, medium- to coarse-grained, cross bedding andrhythmic bands of clayey sand common, unconsolidated. LEGEND TITLE PROJECT/REPORT 2,000 0 2,0001,000 FEET1:24,000SCALE REFERENCES Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet Geologic Map obtained form the NCGS geol.shp file.Geologic Descriptions provided by the USGS Mineral Resources On-line Spatial Datawebpage. CATCH BASIN CATCH BASIN 3953953653603703803753853903903853753803703653553604003 5 5 400i3 i2 i1 GP-10 CLOSED MSW LANDFILL ACTIVE C&D LANDFILL TO GP-9 SW-2 SW-4 GP-15 GP-16 GP-14 GP-13 SW-3 SW-1 GP-11 GP-17 GP-10 MW-7 385.69 MW-4359.98 366.35MW-16S 366.24MW-16D GP-12 357.63MW-3 367.65MW-2 381.70MW-1 383.02 MW-9 383.21 MW-8 MW-13S374.47MW-13D 373.66 383.19 MW-14 388.54 MW-6 MW-11D372.48 MW-11S371.55 MW-5 376.42 MW-15 397.84 PW-1 CONSULTANT DESIGN PREPARED REVIEW APPROVED YYYY-MM-DD TITLE PROJECT No.Rev. PROJECTCLIENT Path: \\greensboro\CAD\_2007\0739615 - Moore\PRODUCTION\_B - 2016 GW Report\ | File Name: 0739615015B001.dwgIF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI D01 in0739615015 PHASE 100 DRAWING 30 2016-07-07 BSD TJM BSD RPK MOORE COUNTY LANDFILL PERMIT NO. 63-01 ABERDEEN, NORTH CAROLINA MOORE COUNTY GROUNDWATER SURFACE CONTOUR MAP APRIL 11, 2016 PERENNIAL STREAM INTERMITTENT STREAM EPHEMERAL STREAM POND AND WETLAND LIMITS EXISTING 10 FT GROUND SURFACE CONTOUR EXISTING 2 FT GROUND SURFACE CONTOUR PROPERTY LINE APPROXIMATE LIMITS OF WASTE EXISTING ROAD POTENTIOMETRIC GROUNDWATER CONTOURS (5 FT. INTERVAL) GROUNDWATER FLOW SEGMENTS MONITORING WELL AND IDENTIFICATION METHANE PROBE AND IDENTIFICATION SURFACE WATER MONITORING POINT AND IDENTIFICATION LANDFILL GAS TRENCH VENTS AND IDENTIFICATION PASSIVE LANDFILL GAS VENTS PRIVATE WELL LOCATION AND IDENTIFICATION WETLAND AREA LEGEND NOTES 1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2.GROUNDWATER SURFACE CONTOUR INTERVAL = 5 FEET 3.GROUNDWATER ELEVATIONS MEASURED ON APRIL 11, 2016. 4.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5.GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO THE RELATIONSHIP BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS. 6.PROPERTY BOUNDARY SURVEY BY JAMES L. WRIGHT DATED NOVEMBER 1984. ITS LOCATION IS RELATIVE TO TOPOGRAPHY APPROXIMATE BY HDR ENGINEERING, INC. 7.EXISTING TOPOGRAPHY WITHIN ACTIVE AND PROPOSED LANDFILL PROVIDED BY MATTHEWS LAND SURVEYING & MAPPING, PLLC DATED APRIL 17, 2015. 8.MONITORING WELLS MW-1 THROUGH MW-5 SURVEYED JUNE 1987 BY S&ME, INC. MONITORING WELLS MW-6 THROUGH MW-16 SURVEYED APRIL 1995, SEPTEMBER 1996, AND APRIL 2003 BY HDR ENGINEERING INC./ ED BUCKNER RLS APRIL 17, 2015. 9.THE LOCATIONS OF LANDFILL GAS TRENCH VENTS ARE APPROXIMATE. 10.GROUNDWATER WELLS MW-11D, MW-13D, AND MW-16D ARE NOT SCREENED IN THE SHALLOW AQUIFER AND ELEVATION DATA WERE NOT USED IN THE CONSTRUCTION OF GROUNDWATER CONTOURS. 11.A STREAM DETERMINATION WAS CONDUCTED ON APRIL 17, 2013 BY A GOLDER ASSOCIATES NC, INC. REPRESENTATIVE. THE STREAM DETERMINATION WAS CONDUCTED USING NCDWQ'S "METHODOLOGY FOR IDENTIFICATION OF INTERMITTENT AND PERENNIAL STREAMS AND THEIR ORIGINGS, VERSION 4.11". 381.70 MW-1 GP-10 SW-1 PW-1 385 SITE LOCATION MAP NOT TO SCALE SITE LOCATION 0 FEET 200 400 SCALE Reviewed By: DYR Prepared By: BSD Project #: 0739615016 DATE: 01/12/17 Figure No. 4 Title: PIPER PLOT Cation vs. Anion 01 in0739615016 PHASE 400 FIGURE 50 2016-11-11 BSD BSD DYR RPK ALTERNATE SOURCE DEMONSTRATION C&D LANDFILL, SW PERMIT NO. 63-01 MOORE COUNTY LANDFILL ABERDEEN, NORTH CAROLINA FIXED SCALE STIFF DIAGRAMS (LEACHATE AND GROUNDWATER) TITLE PROJECT NO.REV. PROJECTCLIENT CONSULTANT PREPARED DESIGNED REVIEWED APPROVED YYYY-MM-DD IF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI BPath: \\greensboro\DATA\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\WIP\F_Figures\ | File Name: Stiff Diagrams.dwg | Last Edited By: bdraper Date: 2017-02-28 Time:11:58:46 AM | Printed By: bdraper Date: 2017-02-28 Time:11:59:08 AMGOLDER ASSOCIATES NC, INC. PE C-2862 PG C-399 01 in0739615016 PHASE 400 FIGURE 60 2016-11-11 BSD BSD DYR RPK ALTERNATE SOURCE DEMONSTRATION C&D LANDFILL, SW PERMIT NO. 63-01 MOORE COUNTY LANDFILL ABERDEEN, NORTH CAROLINA VARIABLE (OR SLIDING SCALE) STIFF DIAGRAMS (LEACHATE AND GROUNDWATER SAMPLES) TITLE PROJECT NO.REV. PROJECTCLIENT CONSULTANT PREPARED DESIGNED REVIEWED APPROVED YYYY-MM-DD IF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI BPath: \\greensboro\DATA\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\WIP\F_Figures\ | File Name: Stiff Diagrams.dwg | Last Edited By: bdraper Date: 2017-02-28 Time:11:58:46 AM | Printed By: bdraper Date: 2017-02-28 Time:11:59:44 AMGOLDER ASSOCIATES NC, INC. PE C-2862 PG C-399 01 in0739615016 PHASE 400 FIGURE 70 2016-11-11 BSD BSD DYR RPK ALTERNATE SOURCE DEMONSTRATION C&D LANDFILL, SW PERMIT NO. 63-01 MOORE COUNTY LANDFILL ABERDEEN, NORTH CAROLINA VARIABLE (OR SLIDING SCALE) STIFF DIAGRAM (MIXING LEACHATE AND GROUNDWATER) TITLE PROJECT NO.REV. PROJECTCLIENT CONSULTANT PREPARED DESIGNED REVIEWED APPROVED YYYY-MM-DD IF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI BPath: \\greensboro\DATA\PROJECTS\Moore County\Groundwater\2016 ASD C&D Landfill\DRAFT\WIP\F_Figures\ | File Name: Stiff Diagrams.dwg | Last Edited By: bdraper Date: 2017-02-28 Time:11:58:46 AM | Printed By: bdraper Date: 2017-02-28 Time:12:00:26 PMGOLDER ASSOCIATES NC, INC. PE C-2862 PG C-399 365 390 370 375 380 385 360 39 5355 350 400 345 365 350 360 3 5 5 4 00CLIENTMOORE COUTNY LANDFILLABERDEEN, NORTH CAROLINA LEGEND 1 Yr Particle Trace Markers Particle Trace Flow Lines Groundwater Contours NOTES REFERENCE 1.) THIS DRAWING PRESENTS THE RESULTS OF THEGROUNDWATER FLOW MODEL CONSTRUCTED USINGAQUIFERWIN32 VERSION 4.0 BY ENVIRONMENTAL SIMULATION(2009). 2.) THE MODEL WAS CALIBRATED USING HISTORICAL SITEGROUNDWATER ELEVATIONS. 3.) AVAILABLE SITE SLUG TESTS WERE USED TO ESTIMATECONDUCTIVITY. 4.) STORATIVITY WAS ESTIMATED BY EXAMINATION OF THEBORING LOGS. 5.) A RECHARGE RATE WAS APPLIED BASED ON BASE FLOWSEPERATION CURVES FROM NEARBY DROWNING CREEK. 6.) THE GROUNDWATER MODEL INPUTS AND OUTPUTS AREPRESENTED IN APPENDIX D. 1.) SERVICE LAYER CREDITS: SOURCE: ESRI, DIGITALGLOBE,GEOEYE, EARTHSTAR GEOGRAPHICS, CNES/AIRBUS DS,USDA, USGS, AEX, GETMAPPING, AEROGRID, IGN, IGP,SWISSTOPO, AND THE GIS USER COMMUNITY 2.) COORDINATE SYSTEM: NAD 1983 STATEPLANE NORTHCAROLINA FIPS 3200 FEETPROJECTION: LAMBERT CONFORMAL CONICDATUM: NORTH AMERICAN 1983 PROJECTALTERNATE SOURCE DEMONSTRATIONC&D LANDFILL, SW PERMIT NO. 63-01 TITLEGROUNDWATER MODEL RESULTS SUMMARY (SUMMER) 0739615016 400 0 8 2017-02-08 BSD PN DYR RPK 1 in0Path: W:\Projects\Moore County\MXD\Groundwater_Model_Results_(Summer).mxd KEY MAP IF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET HAS BEEN MODIFIED FROM: ANSI BCONSULTANT PROJECT No.PHASE Rev.FIGURE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED ³ GOLDER ASSOCIATES NC, INC. 370 365 375 380 385 390 360 39 5 3 5 5 350 400 3 4 5 370360 375 360 355 365 3654 0 0 CLIENTMOORE COUTNY LANDFILLABERDEEN, NORTH CAROLINA LEGEND 1 Yr Particle Trace Markers Particle Trace Flow Lines Groundwater Contours NOTES REFERENCE 1.) THIS DRAWING PRESENTS THE RESULTS OF THEGROUNDWATER FLOW MODEL CONSTRUCTED USINGAQUIFERWIN32 VERSION 4.0 BY ENVIRONMENTAL SIMULATION(2009). 2.) THE MODEL WAS CALIBRATED USING HISTORICAL SITEGROUNDWATER ELEVATIONS. 3.) AVAILABLE SITE SLUG TESTS WERE USED TO ESTIMATECONDUCTIVITY. 4.) STORATIVITY WAS ESTIMATED BY EXAMINATION OF THEBORING LOGS. 5.) A RECHARGE RATE WAS APPLIED BASED ON BASE FLOWSEPERATION CURVES FROM NEARBY DROWNING CREEK. 6.) THE GROUNDWATER MODEL INPUTS AND OUTPUTS AREPRESENTED IN APPENDIX D. 1.) SERVICE LAYER CREDITS: SOURCE: ESRI, DIGITALGLOBE,GEOEYE, EARTHSTAR GEOGRAPHICS, CNES/AIRBUS DS,USDA, USGS, AEX, GETMAPPING, AEROGRID, IGN, IGP,SWISSTOPO, AND THE GIS USER COMMUNITY 2.) COORDINATE SYSTEM: NAD 1983 STATEPLANE NORTHCAROLINA FIPS 3200 FEETPROJECTION: LAMBERT CONFORMAL CONICDATUM: NORTH AMERICAN 1983 PROJECTALTERNATE SOURCE DEMONSTRATIONC&D LANDFILL, SW PERMIT NO. 63-01 TITLEGROUNDWATER MODEL RESULTS SUMMARY (WINTER) 0739615016 400 0 9 2017-02-08 BSD PN DYR RPK 1 in0Path: W:\Projects\Moore County\MXD\Groundwater_Model_Results_(Winter).mxd KEY MAP IF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET HAS BEEN MODIFIED FROM: ANSI BCONSULTANT PROJECT No.PHASE Rev.FIGURE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED ³ GOLDER ASSOCIATES NC, INC. APPENDIX A BORING LOGS APPENDIX B FIELD SAMPLING LOGS APPENDIX C LABORATORY CERTIFICATES-OF-ANALYSIS, LABORATORY SAMPLE RECEIPT SUMMARIES AND CHAIN-OF-CUSTODY FORMS Soil Gas Sampling GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Moore County ASD Project Reference Number: 0739615016 Sampling Event Date: September 7, 2016 Review Date: January 4, 2017 Initials: TM Report #: BZ03918 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi- Concentration, September 1994; Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility/C & D List X TO15 (SUMMA) NC Appendix I + Detects NC Appendix II 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical Method Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). TM MS/MSD/LCS data results are provided for each analytical method. The matric spike and matrix spike duplicate had recoveries that were outside acceptance limits for propene, but by virtue of a laboratory control sample being in control, the laboratory has demonstrated to be in control of its internal process. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. GV-32 ALLX5.4 MW-11S ALLX6.16 (n-Hexane X12.3) MW-11D ALLX6.32 (Acetone X 12.6, total light petroleum hydrocarbons X12.6) MW-14 ALLX5.48 MW-16S ALLX6.28 MW-16D ALLX1.59 TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (i.e., GA Reporting Limits). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. N/A No inorganic or organic constituents were reported above their respective GA MCLs in wells or field/equipment/trip blanks, or above Surface Water Standards in surface points. N/A No quantifiable inorganic or organic constituents were detected in a well or surface water point at concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). N/A Other report issues/Communications with laboratory/etc.: Water Sampling GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Moore County ASD Project Reference Number: 0739615016 Sampling Event Date: September 7, 2016 Review Date: January 4, 2017 Initials: TM Report #: BZ03918 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi- Concentration, September 1994; Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility/C & D List X TO15 (SUMMA) NC Appendix I + Detects NC Appendix II 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical Method Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free. TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). TM MS/MSD/LCS data results are provided for each analytical method. The matric spike and matrix spike duplicate had recoveries that were outside acceptance limits for propene, but by virtue of a laboratory control sample being in control, the laboratory has demonstrated to be in control of its internal process. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 TM Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. JD It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. GV-32 ALLX5.4 MW-11S ALLX6.16 (n-Hexane X12.3) MW-11D ALLX6.32 (Acetone X 12.6, total light petroleum hydrocarbons X12.6) MW-14 ALLX5.48 MW-16S ALLX6.28 MW-16D ALLX1.59 TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (i.e., GA Reporting Limits). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. N/A No inorganic or organic constituents were reported above their respective GA MCLs in wells or field/equipment/trip blanks, or above Surface Water Standards in surface points. TM No quantifiable inorganic or organic constituents were detected in a well or surface water point at concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). N/A Other report issues/Communications with laboratory/etc.: APPENDIX D GROUNDWATER MODEL (RAW DATA AND INPUT/OUTPUT FILES)