2301_ClevelandCoMSW_LeachateAssmtRpt_DIN28426_20170810

NR
Electronic Data - Email CD loaded:Doc/Event #:
Environmental MonitoringDivision of Waste Management - Solid Waste
and any are AS
available for inspection and examination by any person upon request (NC General Statute 132-6).
lnstructions
n Form
are
Prepare one form for each individually monitored unit.
Please type or print leg¡bly.
Attach a not¡f¡cat¡on table with values that attain or exceed NC 2L groundwater standards or NC 28 surface water standards. The notif¡cat¡on
must include a preliminary analysis of the cause and significance of each value. (e g. naturally occurring, off-s¡te source, pre-existing
condit¡on, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facil¡ty (NCAC 138 .1629 (a)(a)(i)
Send the or¡ginal signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitori Data Submittal lnformation
ent¡ty subm¡tting data (laboratory, consu ltant,
SHIELD ENGINEERING, INC.
Contact for questions about data formatting. lnclude data prepare/s name, telephone number and E-mail address:
Name: J David Wallace, P.E Phone: [phone]'l 49
E-mail: [e-mail]
Facility name
CLEVELAND COUNTY LANDFILL
Facility Address:
I609 AIRPORT ROAD
SHELBY NORTH CAROLINA, 28150
NC Landfill Rule
Facility Permit #.0500 or .1
23-O1
Actual sampling dates (e 9.,October 20-24,2006)
June 20171 600
Environmental Status: (Check all that apply)
I lnitial/Background Monitoring I Detect¡on Monitoring Assessment Monitoring A Corrective Action
of data subm¡tted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells
Leachate mon¡toring data
Surface water monitoring data
Methane gas mon¡tor¡ng data
Corrective action data (specify)
Othe(specify)
TEtr
Leachate Pipe Rupture
attached?
No. No groundwater or surface water standards were exceeded
Yes,anotif¡cationofvaluesexceed¡ngagroundwaterorsurfacewaterstandard¡sattached. ltincludesalistofgroundwaterandsurfacewater
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 28 surface water standard or NC Solid Waste GWpS andprel¡minary analysis of the cause and s¡gnif¡cance of any concentration.
Yes, a not¡f¡cation of values exceeding an explosive methane gas limit is attached lt includes the methane monitoring points, dates, sample
values and explosive methane gas l¡m¡ts.
Gertification
T
To the best of my knowledge, the ¡nlormat¡on reported and statements made on this data submittal and attachments are true and correct.Furthermore, I have attached complete not¡f¡cat¡on of any sampl¡ng values meet¡ng or exceed¡ng groundwater standards or explosive gaslevels, and a preliminary analysis of the cause and sign¡f¡cance of concentrat¡ons exceed¡ng groundwater standards. I am aware that there
are sign¡f¡cant penalt¡es for mak¡ng any false statement, representat¡on, o¡ cert¡ficat¡on including the possibility of a fine and ¡mp¡¡sonment.
J David Wallace, P.E. SENTOR ENG|NEER (704)-971-4149
Title (Area Code) Telephone Number
4301 TAGGART CREEK ROAD, CHARLOTTE, NC 28208
SEAL
20055
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
Facility Representat¡ve Address
F-0856
Affix Geologist Seal
,
Via: E-mail
Iuly 25,2017
Mr. Ervin Lane,
Solid V/aste Section
Division of Waste Management
NCDEQ
1646 Mail Service Center
Raleigh, North Carolina 27 699 -I 646
Subject:Response and Cleanup Report - Leachate Pipe Rupture
Cleveland Counfy Landfïll
Shelby, North Carolina
DSWM Permit No. 23-01
Shield Project No. 1040167
Dear Mr. Lane,
Cleveland County Health Department is currently constructing the Phase III Cell at the Self-
McNeilly Site in Cleveland County, North Carolina. Cleveland County subcontracted this new cell
construction to Earnhardt Grading, Inc. (EGI). On June 12, 2077, a subcontractor of EGI was
working on the installation of and connecting a new fiber optic line from the old landfill Information
Technology (IT) system at the West Site to the new lined (Subtitle D) landfill IT system at the Self
McNeilly Site (for location of these Sites see Figure l).
Background
During the underground boring for the fiber optic line, adjacent to the former East Site lined Landfill,
the borer passed through the double-walled leachate pipe that conveys leachate from the active
landfill cell at the Self McNeilly Site to the leachate tanks located northwest of the East Site. As a
result the leachate pipe was ruptured near the northeast corner of the East Site cell (see Figure 2).
The rupture caused the leachate to leak from the pipe and rise to the ground surface and flow
downgradient toward a nearby drainage swale. The leachate pipe rupture was not observed at the
time of the rupture (probably because the leachate pump was not pumping at that time) and was first
noticed on June 14,2017 by Cleveland County personnel. The leachate pumps were immediately
turned off. The length of time the leachate pipe was discharging leachate is unknown. Also, the
leachate only flows through the leachate pipe whenever the pump, located in the leachate sump back
at the Self-McNeilly Site, is activated as the level rises within the leachate collection sump.
Therefore, the volume of leachate discharged to ground surface is unknown.
4301 Taggañ Creek Road
Charlotte, NC 28208 www.sh¡eldeng¡neering.com Telephone 704.394.691 3
/æ\fè,
Fax [phone]
Response and Cleanup Reporl - Leachate Pipe Rupture
Cleveland County Landfi ll
July 25, 2017
Page 2
Cleveland County personnel started on June 74 excavating the area to uncover the leachate pipe.
Once the leachate pipe was exposed, the pipe was subsequently repaired using one 4 inch x 12 inch
F1 repairclampandone 8 inchx l2 inchFl repairclamp (see Photograph#l inAppendixA). Upon
the completion of the leachate pipe repairs, the pump at the Self-McNeilly Site leachate sump was
restafted. No leaks were visually identified in the area of the pipe rupture, once the leachate pipe
became operational again.
The leachate pipe rupture was reported to Mr. Ervin Lane of the North Carolina Solid Waste Section
(SWS) by Cleveland County personnel on Vy'ednesday afternoon, June 14,2017 . On the moming of
June 1 5,2071 Shield Engineering Inc. (Shield) discussed an action plan by phone with Mr. Lane for
assessing and remediating the area of the leachate rupture. Sample bottles were prepared and
shipped to Shield by the anal¡ical laboratory to arrive at Shield's office in the afternoon of June 15,
2017.
Initial Response Actions
On June 76,2017 , Shield was onsite to document and evaluate the extent of the excavation and to
perform post-excavation confirmatory soil sampling to verify the cleanup of the leachate pipe leak.
Cleveland County Landf,rll personnel excavated soils downgradient from the leachate leak. Due to
the presence of the new leachate pipe currently being installed below Buffalo Creek, located
immediately downgradient from the location of the ruptured currently active leachate pipe, the
excavation was largely preformed with a backhoe approximately 20 feet downgradient from the
ruptured leachate pipe (see Figure 3). Based on low concentrations of volatile organic compounds
(VOCs) typically observed in previous leachate samples it was expected that the application of an
Organic Vapor Analyzer (OVA) would probably be of limited value for field use in detecting the
presence of leachate within the excavation. Therefore, based on observation of the soils within the
excavation Shield personnel determined that the limits of the excavation would be best determined
by the moisture content of the soil using both feel (e.g., soil binding) and visual means.
Potential contaminated areas associated with the leachate pipe rupture, were excavated and placed in
stock piles for future removal. The depth to the ruptured leachate pipe was approximately 3 to 3.5
feet below ground surface (BGS). The depth of the excavated area ranged from 4 to approxim ately 6
feet BGS. By the end of June 16,2077 the lateral extent of the excavation was approximately 45 feet
long in the north-south direction and 12 feet wide in the east-west direction (see Photograph #3 in
Appendix A). The soil moisture declined at the end of this excavation within the shallower horizons,
indicating that the leachate had not migrated any fuilher downgradient toward the drainage swale.
However, excessive soil moisture was encountered in the deeper portion of the excavation, resulting
in seepage cumulating on the floor at the north end of the excavation. Additionally, there was no
surficial evidence that the leachate had migrated as far as the drainage swale. However, because of
the presence of a damp area on the west side of the rip-rap, an additional smaller excavation was
done in this area down gradient from the leachate pipe (see Figure 3). This smaller excavation area
was approximately 7 feet long and 6 feet wide and 4.5 feet BGS (see Figure 3: refer to Photograph #4
in Appendix A). A soil sample (LS-7) was collected from this smaller excavation to conf,rrm that the
wetness in this area was not a result of leachate.
Response and Cleanup Report - Leachale Pipe Rupture
C leve land County LandJil I
July 25, 2017
Page 3
The limits of the excavation were determined by soil wetness, pafticularly in the shallower horizons.
The soil wetness was found to be a good marker for the presence of the spilled leachate. Hence, soil
wetness was used as a basis for determining the extent of the soil penetrated by the spilled leachate.
Upon the completion of the excavation activities on June 16, Shield collected twelve post-excavation
confirmatory soil samples and one background soil sample. Seven soil samples (LS-1 through LS-7)
were collected from the bottom of the excavation area with approximately five-foot spacing between
each bottom sample (see Figure 3). Five wall soil samples (LS-8 through LS-12) were collected
around the perimeter of the excavated area from the walls of the excavation (see Figure 3). The
northeast wall sample was not collected due water percolating in from the northwest and north sides
of the excavated area. Shield personnel observed the water percolating into the excavation at
approximately 3 to 4 feet BGS. No odor was detected from this seeping water, nor was there a sheen
on the water. A sample of the water seeping into the lower end of the excavation was also collected
for analysis (LV/S-1: see Figure 3).
A background soil sample (BKGD-l) was collected approximately 35 feet upgradient from the
ruptured leachate pipe at approximately 0.5 to 1.0 feet BGS (see Photograph #2 in Appendix A).
These twelve conltrmatory soil samples, the background soil sample, and one water sample were
placed in laboratory provided containers, and transported on ice under Chain-of-Custody protocol
through Pace Anal¡ical Services, Inc. (Pace), in Huntersville, NC, for rush processing.
Initial Analytical Results
The submitted soil samples were analyzed for VOCs (EPA Method 826015035A), total phosphorus
(EPA Method 365.1), sulfate (EPA Method 9056 IC Anions) nitrate (IC Anions 48hr) and metals
(EPA Method 6010). The water was analyzed for low level VOCs (EPA Method 8260) and metals
(EPA Methods 60 I 0 and 6020). The laboratory data are summarized in Table 1 . All olthe inorganic
results are shown in Table 1, except for cadmium and silver, which were non-detect in all of the
results (solid and liquid). Only three VOCs were detected in the anal¡ical results and are shown in
Table 1 (i.e., acetone, chlorobenzene, and 1,4-dichlorobenzene). The full laboratory anal¡ical
repofts are included in Appendix B.
The laboratory anal¡ical repoft exhibited acetone concentrations in seven of the soil samples (i.e.,
LS-1,LS-4,LS-8,LS-10,LS-11,LS-l2andBKGD-1:seeTable 1). However,acetoneisacommon
laboratory contaminant, and since the acetone concentration was highest in the background soil
sample (i.e., BKGD-l), Shield did not consider the acetone concentrations to be indicative of the
presence of leachate. The metals identified in the background soil sample (BKGD-l) were
considered to be indicative of metal concentrations in the native soils for the surrounding area. The
background soil sample also had similar detections of metal constituents. The post-excavation soil
samples (LS-1 through LS-12) had detections of metals that exceeded the Inactive Hazardous Site
Branch Preliminary Soils Remediation Goals Table (IHSB-PSRG) for arsenic, cobalt, selenium and
vanadium. However, for each of these same four inorganics, the background concentrations also
exceeded the IHSB-PSRG goals. In each case the background concentrations are either close to or
within the range of concentrations exhibited by the soil samples collected within the excavation
areas. The cobalt concentration for the background sample exceeds the cobalt concentrations for all
Response and Cleanup Report - Leachate Pipe Rupture
C leveland C ounty Landfill
July 25, 2017
Page 4
of the excavation samples. Hence the presence of inorganics within the soil samples could not be
used as a determining factor for the pfesence of leachate in the soil.
Comparing the post-excavation confirmation soil samples with the background soil sample no
elevated levels of metals were identified within the post-excavation soil samples. However Soil
Sample LS-8 (collected on the southwest wall closest to the leachate pipe) exhibited detections of 1,
4,-dichlorobenzene and chlorobenzene (28.7 micrograms per kilogram lf"rglkg] and 5'9 Pglkg,
respectively: see Table 1). The water sample collected on the northwest and north side walls did not
exhibit any detections of VOCs. The leachate water sample did have detections of inorganics;
however these same inorganics have been occasionally detected in monitoring wells at this landf,rll
site in the past.
Even though Soil Sample LS-8 had a concentration of 1,4- dichlorobenzene below the IHSB-PSRG
limit(70 VglkÐ:1,4-dichlorobenzenehasa0.0mg/kglimitunderNorthCarolina's"Contained-In"
Levels for soil (Levels for unrestricted use). The location of Soil Sample LS-8 was on the side of the
excavation closest to the leachate pipe rupture. Therefore, these anal¡ical data for Soil Sample LS-8
posed the question if the VOC concentrations were higher in the soils upgradient from the first
ãxcavation back toward the leachate pipe rupture. Hence the soil remaining between the area of the
first excavation and the leachate pipe rupture had to be excavated. This soil was not previously
excavated in this area due to the known presence of the new leachate pipe (see Figure 3) and concern
of breaking this new pipe.
Follow-un Actions
Shield and Cleveland County personnel returned to the site on June22,2017 and excavated in the
area extending from the ruptured leachate pipe to the previously excavated area (labeled First
Excavation on Figure 3), to remove any possible contaminated soils remaining in this area' The
dimensions for the second excavated area were approximately 23 feet long in the north-south
direction and29 feet wide in the east- west direction and approximately 5.5 feet BGS (see Figure 3:
refer to Photographs #5 and #6 in Appendix A). As before, this excavated soil material was
stockpiled.
After these excavation activities weÍe complete, Shield personnel collected three post-excavation
confirmatory soil samples (LS-13 through LS-15: see Figure 3). These three confirmation soil
samples were submitted to Pace for VOCs (EPA Method 826015035A) (refer to Appendix B)'
Final Ana Results
Reviewing the laboratory report Soil Sample LS-14 had a detection of acetone and 1,4-dichlorobenze
(105 ¡rg/kg and 4.4 þglkg, respectively: see Table 1). However, the reporting limit for 1,4-
dichlorobenze in Soil Sample LS- 14 was equal to the reported detection concentration. This reported
concentration for 1,4-dichlorobenzene of 4.4 Vglkgwas below the IHSB-PSRG limit (70 Fglkg).
After a phone conversation with Mr. Lane of the SWS on June26,2077, Mr. Lane agreed with
Shield that based on the concentrations of 1,4-dichlorobenzene reported to him, that the area has
been remediated.
Response and Cleanup Report - Leachate Pipe Rupture
C I eve I and C ou nty Landfi I I
Homer, GIT
ect Manager
k C. Boland, P.E
pal Engineer
Attachments:
Figures 1 through 3
Table 1
Appendix A - Photograph Log
Appendix B - Laboratory Analytical Data
July 25, 20l7
Page 5
The excavated soils were removed from the location and taken to the landfill to be used for daily
cover at the Self-McNeilly (Subtitle D) landfill. Final results from the excavation show that the
leachate pipe leak has now been remediated and all contaminated soils have been removed.
Conclusions
The remediation actions removed an estimated24} cubic yards of impacted soil. Cleveland County
repurposed the impacted soil and used it for landfill cover on the SelÊMcNeilly (Subtitle D) landfill.
The excavation was completely backfilled with clean soils from the borrow area used for this
landfill. According to the analytical results from the post-excavation soil samples and the water
sample, the leachate spill area has been remediated. Therefore Cleveland County requests a No
Further Action letter from Solid Waste Section in regard to this leachate pipe rupture.
If you have any questions regarding the content of this report, please contact Shield Engineering at
(704)-394-6913.
Thank you,
SHIELD ENGINEERING, INC.
SEAL
20055
'Wallace,w
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by: Ava Homer: June 30,2017
Ch
e
c
k
e
d

by: J.DavidWallace: Julv 17.2017
Clevel and Countv Leachate Resoonse and Clean Un Photo Loo
Photograph#1 - Leachate line repaired using Fl clamps. Fiber
optic line observed on right side of photo.
Photograph#2 - View from southeast looking northwest. pink
paint represents the background soil sample (BKGD-1).
RING, ING.
Photograph #3 - View from northeast looking southwest.
Approximate location of LWS-1.
Photograph#4 - Second excavation north of main excavation.
Water seeped through north side wall. View is from southeast
looking northwest.
,
NEERING, INC
Photograph #5 - June 22,2017 excavation. Two leachate
pipes exposed. View from southwest looking northeast.
Photograph #6 - Excavation activities from June 1G and June
22,2017.
,
NEERING,
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)87s-9092
Analytical
www.pacÊlabscø
June 26,2017
Ayla Homer
Shield
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project: Cleveland County
Pace Project No.: 92344640
DearAyla Homer:
Enclosed are the analytical results for sample(s) received by the laboratory on June 16,2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
lf you have any questions concerning this report, please feel free to contact me
Sincerely,
(ftàú,4*yorr,-/-
Nicole Gasiorowski
nicole. [e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. James Gamertsfelder, Shield Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without lhe written consent of Pace Analyt¡cal Services, LLC.Page 1 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacelabs.con
CERTIFICATIONS
Project:
Pace Project No.:
Cleveland County
92344640
Ormond Beach Certification lDs
B East Tower Circle, Ormond Beach, FL 32174
Alabama Certiflcation #: 41320
Connecticut Certification #: PH-O21 6
Delaware Cert¡fication: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certif¡cation #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciproc¡ty
lllinois Certification #: 200068
lnd¡ana Certification: FL NELAC Reciprocity
Kansas Certifìcation #: E-10383
Louisiana Certifìcation #: FL NELAC Reciprocity
Louisiana Environmenlal Certifìcate #: 05007
Maryland Certifìcation: #346
Michigan Certifìcation #: 9911
Mississippi Certifìcation: FL NELAC Reciprocity
Missouri Certifìcation #: 236
Montana Certifìcation #: Cert 0074
Nebraska Cert¡f¡cation: NE-OS-28-14
Nevada Certification: FL NELAC Reciproc¡ty
New York Certifìcation #: 1 '1608
North Carolina Environmental Certificate #: 667
North Carolina Certifìcation #: 127 1 0
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerlo Rico Certification #i FL01264
South Carol¡na Certification: #96042001
Tennessee Cert¡fication #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin lslands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
\Aloming Certificat¡on: FL NELAC Reciprocity
West Mrginia Certificat¡on #: 9962C
\Msconsin Certification #: 399079670
\Ârloming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification lDs
9800 Kincey Ave. Ste 100, Huntersv¡lle, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #:5342
North Carolina Wastewater Certifìcation #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certifìcation #i E87 627
Kentucky UST Certification #: 84
VirginiaÂ/ELAP Certifìcation #: 46022'l
Asheville Certification lDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: 887 648
Massachusetts Certificat¡on #: M-NC030
N orth Carolina Drinking Water Certifìcalion #: 377 1 2
North Carolina Wastewater Certificalion #: 40
South Carolina Certifìcation #: 99030001
Virgin¡a^/ELAP Certifìcation #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not þe reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seruices, LLC Page 2 of 53
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875-e0e2
Analytical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Cleveland County
92344640
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
92344640001 LS-l
92344640002 LS-2
92344640003 LS-3
92344640004 LS-4
92344640005 LS-s
EPA 601O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365 1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 60I O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
SH1
KPP
DLK
CLW
BRJ
CMD
CMD
SER
KPP
DLK
CLW
BRJ
CMD
CMD
sH1
KPP
DLK
CLW
BRJ
CMD
CMD
SH1
KPP
DLK
CLW
BRJ
CMD
CMD
SH1
KPP
DLK
CLW
BRJ
CMD
CMD
SER
KPP
13
2
52
1
1
1
1
13
2
52
1
,|
1
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13
2
52
1
,|
,|
1
13
2
52
1
1
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13
2
52
1
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1
13
2
PASI-A
PASI-O
PASI.C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASI-O
PASI-C
PASI-C
PASI-A
PASt-O
PASI-O
PASI-A
PASI-O
PASI-C
PASI.C
PASI.A
PASI-O
PASI.O
PASI-A
PASI-O
PASI-C
PASI-C
PASI-A
PASI-O
PASr-O
PASI-A
PASI-O
PASI-C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASt-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
w¡thout the written consent of Pace Analytical Services, LLC
92344640006 LS-6
Page 3 of 53
@
Pace Analytical Services, LLG
9800 KinceyAve. Suite l00
Huntersville, NC 28078
[phone]
Analytical
w.paælabs.æm
SAMPLE ANALYTE COUNT
Project:
Pace Project No.
Cleveland County
92344640
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
92344640007 LS-7
923,f4640008 LS-8
92344640009 LS-g
92344640010 LS-10
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601 O
EPA 6020
EPA 8260
ASTM D2974-87
DLK
CLW
BRJ
CMD
CMD
SHl
KPP
DLK
CLW
BRJ
CMD
CMD
SH1
KPP
DLK
CLW
BRJ
CMD
CMD
SH1
KPP
DLK
CLW
BRJ
CMD
CMD
SER
CRT
DLK
CLW
BRJ
CMD
CMD
SH1
KPP
DLK
CLW
PASI.C
PASt-C
PASI.A
PASI-O
PASI-O
PASI-A
PASI-O
PASI-C
PASt-C
PASI-A
PASI-O
PASI-O
PASI-A
PASI.O
PASI-C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASr-O
PASI-C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASI-O
PASr-C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASI-O
PASI-C
PASI-C
52
1
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13
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52
1
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLC.
9234,/.640011 LS-lt
Page 4 of 53
@
Pace Analyt¡cal Services, LLC
9800 Kincey Ave Su¡te I 00
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project:
Pace Project No.
Cleveland County
92344640
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
9234464001.2 LS-í2
92344640013 BKGD-1
EPA 365.1
EPA 9056
EPA 9056
EPA 601O
EPA 6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
EPA 601O
EPA6020
EPA 8260
ASTM D2974-87
EPA 365.1
EPA 9056
EPA 9056
BRJ
CMD
CMD
sH1
KPP
DLK
CLW
BRJ
CMD
CMD
SER
KPP
DLK
CLW
BRJ
CMD
CMD
PASI_A
PASI-O
PASI-O
PASI-A
PASI-O
PASI-C
PASI-C
PASI-A
PASI-O
PASI-O
PASI-A
PASI-O
PASI-C
PASI-C
PASI-A
PASI-O
PASI-O
1
1
1
13
2
52
1
1
1
'l
13
2
52
1
1
1
1
REPORT OF LABORATORY ANALYSIS
ïhis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Page 5 of 53
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
(7041875-9092
Analytical
www.pacÊlabs con
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
92344640
Sample: LS-1 Lab lD: 92344640001 Collected: 06h6117 12:50 Received: 06/16/1716:05 Matrix: Solid
Resu/ts reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
601O MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Tinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochloromelhane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ibromoch lorometha ne
1,2-Dibromoethane (EDB)
D¡bromomethane
'l ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1-Dichloroethane
'l ,2-Dichloroethane
'1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans- 1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
4.4
272
1.9
ND
124
12.8
23.8
18.0
57.5
ND
ND
112
100
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
23
1.1
023
0.23
't.1
1.'l
1.1
1.1
11
2.3
1.1
't.1
2.3
2.5
1.2
125
125
62
ôz
6.2
6.2
12.5
125
12.5
oz
o.¿
125
6.2
't2.5
6.2
6.2
6.2
62
62
6.2
6.2
6.2
62
6.2
o.z
6Z
2
2
2
2
2
2
2
2
2
2
2
2
2
06117117 10:55
061'l7l'17 1O55
06117117 10:55
06h7117 10:55
06117117 10:55
O6h7h7 10:55
O6117117 10:55
O6117117 10:55
06117117 10:55
06117117 10:55
061171'17 10:55
O6h7h7 10i55
06117117 1O:55
06119117 23100
O6119117 23:00
O6l'19fi7 23:00
06119117 23:00
O6l19h7 23t00
06119117 23:OO
06119117 23:00
06119117 23:00
06119117 23:00
06119117 23:00
O6119117 23:00
O6119117 23:0O
O6119117 23:OO
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-'l
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
I 06-93-4
74-95-3
95-50-1
1 06-46-7
1 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
20
20
06120117 1805 06123117 01:37 7440-36-0
06120117 1B:O5 06123117 01:37 7440-28-0
N2
127
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
06117117 17:17
06117117 17 .17
06117 117 17:17
06117117 17:17
O6117117 17:17
O6l'17117 17:17
O6117117 17:17
06117117 17:17
06117117 17:17
06h7117 17i17
06117117 17:17
06117117 17:17
06117117 17:17
06117 117 17:17
06117117 17:17
06117117 17:17
06117117 17:17
06117117 17:17
06117117 17:17
06117117 17:17
06117117 17:17
O6117117 17:17
O6117117 17:17
06117117 17:17
06t17117 17:17
06117117 17:'17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDaTe: 0612612017 '11:33 AM Page 6 of 53
@
Pace Analytical Seruices, LLC
9800 Kincey Ave Su¡te '100
Huntersville, NC 28078
[phone]
Analytical
www.paeelabs.con
ANALYTICAL RESULTS
Project:
Pace Project No.:
Sample: LS-1 Lab lD: 92344640001 Collected: 06116117 12:50 Received: 06/16i1716:05 Matrix: Solid
Resu/ús repoñed on a "dry weight" basis and are a justed fot percent moisture, sample size and any dilutions.
Parameters Results Units Report L¡m¡t DF Prepared Analyzed CAS No.
Cleveland County
92344640
Qual
8260/50354 Volatile Organics
'l ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,'1,2,2-fet achlo roethane
Tetrachloroethene
Toluene
1 ,1 ,1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
V¡nyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Su/rogafes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
N¡trate as N
Analytical Method: EPA 8260
Analytical Method: ASTM D2974-87
25.8 %
Analytical Method: EPA 365.1
86.1 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
101
99
't07
70-'t30
70-1 30
70-132
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.2
6.2
62
6.2
62.4
12.5
25.0
62.4
6.2
6.2
6.2
6.2
6.2
6.2
ı.2
6.2
6.2
o¿
62.4
't2.5
12.5
12.5
6.2
06117h7'17:17
O6h7l17 17:17
06117117 17i17
06117117 17:17
06117117 17:17
06117117 17:'17
06117117 17:17
06|17117 17:17
061'17117 17:17
06117117 17:17
061171'17 17:17
061171'17'17 17
o6117t',t7',17:17
O6117117'17:17
061171'17 17:17
06117117 17:17
06117117 17:17
061'17117 17:'17
061'17117 17:'17
061'17h7 17:17
06117117 17:17
06117117 17:17
06117117 17:17
78-87-5
1 0061-01-5
1 0061 -02-6
100-41-4
59'l-78-6
74-BB-4
75-09-2
1 0B-1 0-1
100-42-5
630-20-6
79-34-5
't27-',t8-4
1 08-88-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
1 0B-05-4
75-01-4
1330-20-7
179601-23-1
95-47-6
L2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wilhout the wr¡tten consent of Pace Analytical Services, LLC
06117 l'17'17:17 2037-26-5
O6t17 I'17'17:17 460-00-4
06117 117 17:17'17060-07-0
06/19/17 09:36
06121117 06:15 7723-14-0 M1.R1
06121117 13:30 14808-79-8
06121117 13:30 14797-55-8 H3
o/o
Yo
Yo
0.10 1
2.7 1
6.6 1
66.5 I
Date: 0612612O17 1'1 :33 AM Page 7 of 53
@
Pace Analytical Sery¡ces, LLC
9800 K¡ncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacelabs.cþn
ANALYTICAL RESULTS
Project:
Pace Project No :
Cleveland County
92344640
Sample: LS-2 Lab lD: 92344640002 Collected: 06/16/1713:00 Received: 06/16/17'16:05 Matrix: Solid
Resu/ts reporTed on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
60I O MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitr¡le
Benzene
B ro mo ch loro metha ne
Bromod ichloromethane
Bromoform
Bromomelhane
2-Butanone (MEK)
Carbon d¡sulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
'1,2-Dibromoethane (EDB)
Dibromomethane
I ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans- 1,4-Dichloro-2-butene
1 ,1-Dichloroethane
I ,2-Dichloroethane
'1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
5.5
't't4
1.2
ND
106
8.9
20.0
12.0
29.7
3.2
ND
82.4
35.6
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
0.95
0.48
0 095
0.095
048
0.48
0.48
0.48
048
0.95
0.48
0.48
0.95
108
108
5.4
5.4
5-4
54
108
108
108
54
5.4
10.8
5.4
10.8
5.4
54
5.4
54
5.4
5.4
5.4
54
5.4
54
5.4
5.4
1
1
I
1
1
1
1
1
1
1
,|
1
1
O6117117 1O:55
O6117117 10:55
O6l'17117 10:55
06117117 1055
06117117 10:55
06117117 10:55
06117117 10:55
O6h7h7 10:55
06117117 10:55
06117117 10:55
O6l'17117 10:55
06117h7 10i55
06117117 10:55
06118h7 2043
061'18117 2O:43
O6118117 20:43
06118117 2O:43
061181'17 20:43
06118117 2O:43
06118117 2O:43
06118117 20:43
06118117 20:43
O6118117 20:43
O6118117 20:43
O6118117 20:43
06118117 2O:43
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
ND mg/kg
ND mg/kg
2.6 201.3 20
06120117 18:05 06123h7 01:4O 7440-36-0
06120117 18:05 06123117 O1i40 7440-28-0
N2
M1
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117'17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
061'17117 17:36
06117117 17:36
O6117117 17:36
O6117117 17:36
06117117 17:36
06t17t17 17.36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06t17t17 17.36
06117117 17:36
06117117 17:36
67-64-1
't07-'t3-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-'12-B
124-48-1
1 06-93-4
74-95-3
95-50-.1
1 06-46-7
110-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, LLCDale: 0612612017 '11:33 AM Page I of 53
@
Pace Analytical Services, LLC
9800 Kincey Ave Suite '100
Huntersv¡lle, NC 28078
(704)875-eo92
Analytical
ww.paælabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
Sample: LS-2 Lab lD: 92344640002 Collected: 06/16/17 13:00 Received: 06/16/17 16:05 Matrix: Solid
Resu/fs reporled on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
92344640
Qual
8260/50354 Volatile Organics
1 ,2-Dichloropropane
cis-'1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (Ml BK)
Styrene
I ,1 ,1 ,2-Tetrachloroetha ne
1,1,2,2-fet achloroethane
Tetrachloroethene
Toluene
1,1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
'1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Mo¡sture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
Analytical Melhod: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
98 o/o
97 o/"
104 Yo
Analytical Method: ASTM D2974-87
19.3 o/o
Analytical Method: EPA 365.1
32.2 mg/kg
Analytical Method: EPA 9056
64.5 mg/kg
Analytical Method: EPA 9056
ND mg/kg
06117 117'17:36 2037 -26-5
06117117 17:36 460-00-4
06117117 17:36 17060-07-0
06/19/17 09:36
06121117 06:17 7723-14-0
06121117'14:35 14808-79-8
06121117 14:35 14797-55-8 H3
5.4
54
5.4
5.4
53.8
10.8
21 5
53.8
54
5.4
5.4
5.4
5.4
5.4
5.4
5.4
5.4
54
53.8
10.8
10.8
10.8
5.4
1
1
,|
1
I
1
1
1
1
1
1
1
1
1
1
1
1
1
,|
1
1
1
1
1
1
1
06117117 17:36
O6h7l17 17:36
06117117 17:36
06117117 17:36
O6l'17117 17:36
061'l7l'17 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
O6l'17117 17:36
06117117 17:36
061'17117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
06117117 17:36
O6117117 17:36
061171'17 17:36
O6117117 17:36
061'17117 17i36
7B-87-5
1 0061-01-5
1 0061-02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4 L2
1 08-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-1 8-4
108-05-4 M1
75-O1-4
1330-20-7
17960'l-23-1
95-47-6
70-1 30
70-l 30
70-132
0.'t 0 1
24 1
61.5 ',l
6.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except Ìn full,
w¡thout the written consent of Pace Analyt¡cal Serv¡ces, LLCDale 0612612017 11 :33 AM Page 9 of 53
@
Pace Analytical Services, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacalabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Sample: LS-3 Lab lD: 92344640003 Collected: 06l'16117 13:10 Received: 06/16/17 16:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
Cleveland County
92344640
Qual
601O MET ICP
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
Analyt¡cal Method: EPA6010 Preparat¡on Method: EPA3050
51 0
6.6
178
1.5
ND
140
1'.1.2
24.6
20.5
ND
ND
131
59.6
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
'1 I
0.94
0.19
0.19
0.94
094
094
094
094
1.9
0.94
0.94
19
2.5
1.2
122
122
61
6.1
6.'1
6.1
12.2
122
122
61
61
'122
6.1
't22
6.1
6.1
6.1
61
61
61
6.'1
6.1
6.1
6.1
6.1
6.1
2
2
2
2
2
2
2
2
2
2
2
2
2
061'17117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06117117 1O:55
06117117 10:55
06117117 10:55
06117117 10:55
O6117117 10:55
06117117 '1055
O6117117 10:55
061'17117 10:55
06119117 17:36
O6119117 17:36
O6119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119117 17:36
06119h7 17:36
O6119117 17:36
06117117 17:56
O6117117 17:56
O6117117 17:56
O6117117 17:56
06117117 17:56
06117117 17:56
061'17117 17:56
061171'17 17:56
06117117 17:56
06117117 17:56
O6117117 17:56
06117117 17:56
06117117 17:56
06117h7 17:56
061'17117'17:56
06/17117 17:56
06h7117 17:56
06117117 17:56
06117117 17:56
06117117 17:56
06117h7 17:56
06117h7 17:56
06117117 17:56
O6117117 17:56
O6117117 17:56
06117117 17:56
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
B ro moch lo rometha ne
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
I ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,'l -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-D¡chloroethene
Analytical Method: EPA6020 Preparalion Method: EPA3050
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
20
20
06120117 18:05 06123117 01:43 7440-36-0
06120117 18:05 06123117 0'l:43 7440-28-0
N2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
67-64-'l
107-13-'l
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-1 5-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-1 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
1 06-46-7
I 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Servlces, LLCDale: 0612612017 11 :33 AM Page 10 of53
o
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
w.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344640
Sample: LS-3 Lab lD: 92344640003 Collected: 06i16/17 13:10 Received: 06/16/17 16:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and arc adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
8260/50354 Volatile Organics
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Slyrene
1, 1, 1,2-Tetrachloroethane
1,1,2,2-fet achloroeth a ne
Tetrachloroethene
Toluene
1 ,1 ,1 -Trichloroethane
1, 1,2-Tr¡chloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogafes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
N¡trate as N
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
6.1
6.1
6.1
6.1
61.0
't22
244
61 0
6.1
6.1
6.1
6.1
6.1
6.1
6.1
61
6.1
6.1
61.0
12.2
12.2
12.2
61
70-1 30
70-1 30
70-132
78-87-5
1 0061 -01 -5
1 0061 -02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 0B-1 0-1
'to0-42-5
630-20-6
79-34-5
127-18-4
1 08-88-3
71-55-6
79-00-5
79-0'1-6
75-69-4
96-18-4
1 08-05-4
75-01-4
1330-20-7
179601-23-1
95-47-6
L2
061171'17'17:56
06117117 17:56
06117117 17:56
O6117117 '17:56
O6117117 17:56
O6117117 17:56
06117117 17:56
06117117 17:56
061171'17 17:56
06117117 17:56
06117117 17:56
O6117l'17 17:56
06117117 '17:56
06117h7 17:56
06117117 17:56
O6117117 17:56
06117h7 17:56
06117117 17:56
O6117117'17:56
06117117 17:56
O6117117 17:56
06117117 17:56
O6/17117 17:56
'lO2 To96 Yo
105 To
Analytical Method: ASTM D2974-87
21.6 o/o
Analytical Method: EPA 365.1
23.'l mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
'l
'l
'l
06117 117 17:56 2037-26-5
06117117 17:56 460-00-4
06117117 17:56 17060-07-0
06l'19117 09:37
06121 117 06i18 7723-14-0
06121117 14:56 14808-79-8
06121117'14:56 14797-55-8 H3
010 1
2.2 1
63.3 1
6.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLCDate: 0612612O17 11 :33 AM Page '11 of 53
@
Pace Analyt¡cal Serv¡ces, LLC
9800 K¡nceyAve Suite 100
Huntersv¡lle, NC 28078
(704)875-90e2
Analytical
www.pacþlabs com
ANALYTICAL RESULTS
Project:
Pace Project No.
Sample: LS-4 Lab lD: 92344640004 Collected: 06/16/17 13:30 Received: 06/16/17 16:05 Malrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any d¡lutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
60IO MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon telrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dib romoch lorometh ane
1,2-Dibromoethane (EDB)
Dibromomethane
'l ,2-Dichlorobenzene
'l ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,'l -Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
mg/kg
mg/kg
Analyt¡cal Method: EPA 8260
20
20
ND
ND
7.0
'162
1.3
ND
120
21.9
20.5
17.9
45.7
ND
ND
87.2
48.9
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
3.7
1.9
0.37
037
1.9
1.9
'1.9
1.9
1.9
37
1.9
19
3.7
5.2
't.6
116
116
58
5.8
5.8
5.8
11 .6
1'16
11 .6
58
5.8
1'1 .6
5B
11.6
5.8
5.8
5.8
58
5.8
58
5.8
5B
5.8
58
5.8
5.8
06120117 18:05 06123117 01:46 7440-36-0
061201'17 18i05 06123117 O'l:46 7440-28-0
06117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06117117 1O:55
061171'17 10:55
061171'17 1055
06117117 1O:55
O6117117 1O:55
06117117 10:55
O6117117 1O:55
06117117 10:55
06h7h7 10155
061201'17 12:11
061201'17 12:11
06120117 12:11
O612O117 12:1'l
06120117 12i1'l
O6l2Ùl17 12:11
06120117 12:11
O6l2Ol17 12:11
06120117'12:11
061201'17 12:'11
061201'17 12:11
0612O117 12:'11
06120117 12:11
061'l7l'17 18:'16
06117117 18:16
061'17117 18:16
06117117 18:16
06h7h7 18:16
06117117 18:16
O6117117 18:16
06117117 18:16
06117117'18:16
06117117 18:16
061171'17 18:16
061'l7l'17 18:'16
06117117 18:16
06h7117 18:16
06117117 18:16
06117117 18:16
O6h7h7 18116
06117117 18:16
06117117 18.16
O6117117 18:16
06117117 18:16
06117117 1B:16
06117117 18:16
06117117 18:16
06117117 18:16
06117117 18:16
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
N2
271
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1
1
1
I
1
1
'l
1
'l
1
1
1
1
I
1
I
1
I
1
1
1
1
1
I
I
,|
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-15-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-'12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
110-57-6
75-34-3
107-06-2
75-35-4
't 56-59-2
1 56-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM Page 12 of 53
o
Pace Analyt¡cal Seruices, LLC
9800 KínceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacelabs.con
ANALYTICAL RESULTS
Project:
Pace Project No.
Sample: LS-4 Lab lD: 92344640004 Collected: 06/16/17 13:30 Received: 06/'16/17 16:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
Cleveland County
92344640
Qual
8260/5035A Volatile Organ¡cs
1 ,2-Dichloropropane
c¡s-'1, 3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (M IBK)
Styrene
1,1,1,2-Telr achlo roetha ne
'' ,1,2,2-Telr achloroeth a ne
Tetrachloroethene
Toluene
1 ,1 ,I -Tr¡chloroethane
l, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
V¡nyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC An¡ons 48hr
Nitrate as N
Analytical Method: EPA 8260
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
78-87-5
1 0061-01-5
1 0061 -02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 0B-1 0-1
'to0-42-5
630-20-6
79-34-5
127-18-4 L2
1 08-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-18-4
1 08-05-4
75-0't-4
1330-20-7
179601-23-1
95-47-6
58
5.8
5.8
5.8
58.0
11 .6
23.2
58.0
5.8
5.8
5.8
5.8
5B
5.8
58
5.8
5.8
5.8
58.0
11-6
11.6
11.6
5.8
06117117'18:16
O6117117 18:'16
061171'17 18:16
06117117 18:16
06117117 18:16
06117117 18:16
O6117l'17 18:16
06117117 18:16
06117117 18:16
061'17117'l8:16
061'17117'18:16
061'17117'18:16
06/,17117'18:16
O6/17117 '18:'16
06117117 18:16
O6h7l17 18116
061171'17 1816
O6117l'17 18:16
06117117 18:16
06117117 18:16
061'17117 'l8:16
06117117 18:16
06117117 18:'16
98
96
104
70-130
70-1 30
70-132
To
o/o
o/o
06117 117 18:'16 2037-26-5
06117117 18:16 460-00-4
06117117 18:16 17060-07-0
O6119117 09:37
06121 117 06:19 7723-14-0
06121 117 15:'17 14808-79-8
06121117 15:17 14797-55-8 H3
Analytical Method: ASTM D297 4-87
22.9 o/o
Analyt¡cal Method: EPA 365.1
7O.7 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
0.10 1
1.8 1
63.7 1
64 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the written consent of Pace Analytical Services, LLCDale: 0612612017 I 1 :33 AM Page 13 of53
@
Pace Analytical Services, LLC
9800 Kincey Ave Su¡te 1 00
Huntersville, NC 28078
[phone]
Analytical
www.pacelahs.con
ANALYTICAL RESULTS
Project:
Pace Project No
Sample: LS-S Lab lD: 92344640005 Collected: 06/16/1713:35 Received: 06/16/1716:05 Matrix: Solid
Resu/fs repoñed on a "dry weight" basis and are a justed îor percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
601O MET ICP Analyt¡cal Method: EPA6010 Preparation Method: EPA3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Ant¡mony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromod ichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
I ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
I ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,'l -Dichloroethene
cis- 1,2-Dichloroethene
trans-1,2-Dichloroethene
l0:55
10:55
10:55
10:55
'10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
17:42
17:42
17:42
17:42
17:42
17142
17:42
'17142
'17'.42
17:42
17:42
17:42
17:42
7.',|
117
1.3
ND
77.0
13.4
't6.2
13.6
23.3
ND
ND
60.2
49.5
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mgikg
mg/kg
mg/kg
mg/kg
mg/kg
2.0
1.0
0.20
020
1.0
10
10
1.0
1.0
2.0
1.0
10
2.0
24
1.2
116
'116
5.8
5.8
5B
5B
11 6
116
11 .6
5B
5.8
11 .6
5.8
11 6
58
5.8
58
5.8
58
5.8
5.8
5.8
5.8
5.8
5.8
5.8
06117117
06117t',t7
06t17t't7
06117t17
06t17t17
o6t17t17
o6t17t17
o6t17t17
06117t17
o6t'17t17
06t't7t17
06t17t17
06t17117
2
2
2
2
2
2
2
2
2
2
2
2
2
06t19117
06t19t17
06t19t17
06t19t17
06t19t't7
06t19t't7
o6t19t17
06t19t17
06t't9t17
06119117
06t19117
06t19t17
06t19t17
061'17117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
O6117117 18:36
O6h7l17 18136
O6117l'17 18:36
06117117'18:36
06117117 '18:36
061'17117 18:36
061'17117'18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
O6117117 18:36
O6117117 18:36
06117117 18:36
06117117'18:36
06117117 18.36
06117117 18:36
061'17117 18:36
06117117 18:36
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
Analytical Method: EPA6020 Preparation Method: EPA3050
ND mg/kgND mg/kg
20
20
06120117 18.05 06123117 01:48 7440-36-0
06120117 18:O5 O6123117 0'lt49 7440-28-0
N2
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
67-64-',\
107 -13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-15-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-1 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
11 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consenl of Pace Analytical Services, LLCDale'. 0612612017 11:33 AM Page '14 of 53
@
Pace Analytical Serv¡ces, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344640
Sample: LS-s Lab lD: 92344640005 Collected: 06/16/1713:35 Received: 06/16/1716:05 Matrix: Solid
Resurfs repoñed on a "dry weight" basis and are adjusted lor percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
8260/50354 Volatile Organics
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-Telr achloroethane
Tetrachloroethene
Toluene
'1 ,1 ,1 -Trichloroethane
1,1,2-Trichloroethane
Tr¡chloroethene
Trichlorofl uoromethane
'1,2, 3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-dB (S)
4-Bromofl uorobenzene (S)
'1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
Analytical Method: EPA 8260
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
58
5.8
5.8
5.8
58.2
11.6
233
58.2
5.8
5.8
5.8
5B
58
58
5.8
5.8
5.8
5.8
58.2
11 6
11.6
11 .6
5.8
70-'t 30
70-1 30
70-132
78-87-5
1 0061 -01-5
1 0061-02-6
100-41-4
591-78-6
74-88-4
75-09-2
'108-10-1
100-42-5
630-20-6
79-34-5
127-18-4
'108-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-18-4
1 08-05-4
75-01-4
't330-20-7
179601-23-1
95-47-6
L2
1
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
1
1
1
1
I
'l
06h7117 18:36
061171'17 18:36
o6t17t't7'tB:36
06117117 18:36
06117l'17 18136
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
06117117 18:36
061'17117 18:36
O6h7l17 18:36
06117117 18:36
O6h7h7 18:36
06117117 18:36
06117117 18:36
061171'17 18:36
061'17117 18:36
06117/17 18136
O6117117 18:36
06h7117 18t36
06117117 18:36
99 To92 Yo
116 o/o
Analytical Method: ASTM D2974-87
22.8 %
Analytical Method: EPA 365.1
66.6 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
0.10 1
22 1
64.5 1
6.5 1
06117|17'18i36 2037-26-5 19
061'17117'18:36 460-00-4
06117117 1B:36 17060-07-0
O6119117 09:37
06121117 06:19 7723-14-0
06121117 15:39 14808-79-8
061211'17 15:39 '14797-55-8 H3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytica¡ Services, LLCDale: O612612017 1'l :33 AM Page 15 of 53
o
Pace Analyt¡cal Serv¡ces, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875-s092
Analytical
www.pacÊlabs æn
ANALYTICAL RESULTS
Project:
Pace Project No.
Sample: LS-6 Lab lD: 92344640006 Collected: 06116117 13:45 Rece¡ved: 06116117 16:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
601O MET ICP Analytical Method: EPA60'10 Preparation Method: EPA3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thall¡um
8260/50354 Volat¡le Organics
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
I ,2-Dichlorobenzene
1 ,4-D¡chlorobenzene
trans- 1,4-Dichloro-2-butene
1 ,'1-Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1, 2-Dichloroethene
trans-1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
8.3
141
1.3
ND
128
9.2
z',t.9
15.7
28.9
3.7
ND
99.4
36.5
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mgikg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
12
060
012
o.12
0.60
0.60
060
0.60
0.60
1.2
060
0.60
12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.4
1.7
124
124
6.2
6.2
62
62
12.4
124
12.4
62
6.2
't2-4
6.2
12.4
6.2
6.2
6.2
62
62
6.2
6.2
6.2
6.2
62
62
62
20
20
06120117 18:05 06123117 01:51 7440-36-0
06120117 18:05 06123117 01151 7440-28-0
06117117 10.55
06117117 1O:55
06117117 10:55
06h7h7 10:55
06117117 10:55
O6h7l17 1055
06117117 10:55
06117117 10155
O6l'17117'10:55
06117117 10:55
06117117 10:55
06117117 '10:55
06117117 1O:55
06118117 20:56
06118l'17 20:56
061181'17 20:56
06118117 20:56
06118117 20:56
06118117 2O:56
06118117 2056
06118117 20.56
O6118117 20:56
06118117 20:56
061181'17 20:56
06118117 20:56
06118117 20:56
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92:l
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-'l
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-15-0
56-23-5
'108-90-7
75-00-3
67-66-3
74-87-3
96-12-B
124-48-'l
'106-93-4
74-95-3
95-50-1
106-46-7
1 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
06117117 18:55
06117117 18:55
06117117 18:55
06117h7 1855
O6117117 18:55
O6117117 18:55
06l'17117 18:55
06117117 18:55
06117117 18:55
o6t17t't7 1B'.55
06117117 18:55
O6h7h7 1855
06117117 18:55
O6117117'18:55
06117117 18:55
06117117 18:55
06117117 18:55
06117117 18:55
06117117 18:55
06117117 18:55
O6117117 18:55
O6117117 18:55
O6117117 18:55
06117117 18:55
O6117117 1B:55
06h7117 18:55
N2
,|
I
1
1
1
1
I
1
1
1
1
1
1
1
1
1
1
1
'l
1
I
1
1
1
1
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017'11 :33 AM Page 16 of53
o
Pace Analyt¡cal Services, LLC
9800 K¡nceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
www-paælabs.com
ANALYTICAL RESULTS
Project:
Pace Project No
Cleveland County
92344640
Sample: LS-6 Lab lD: 92344640006 Collected: 06h6117 13:45 Received: 06/16i'1716:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any d¡lutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.Qual
8260/50354 Volat¡le Organics
'l ,2-Dichloropropane
cis- 1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-lelr achloroetha ne
Tetrachloroethene
Toluene
1,1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromelhane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogafes
Toluene-d8 (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Mo¡sture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC An¡ons 48hr
Nitrate as N
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
99
92
106
06117117 18:55
061'17t17 ',18:55
061'17117 18:55
06117117 18:55
06117117 18:55
06|17117 18:55
O6117117 18:55
O6h7l'17 18:55
O6117117 18:55
06117117 18:55
06117117 18:55
061'17117'18:55
O6l'17117 18:55
06h7h7 18:55
06117117 18:55
06117117 18:55
06117117 18:55
O6117117 18:55
061'17117 1855
06117117 18i55
06117117'lB:55
061'17117'18:55
06117117 18:55
78-87-5
1 0061-01-5
1 0061 -02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 0B-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4
1 0B-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-1 B-4
1 0B-05-4
75-0't-4
1330-20-7
17960't-23-'l
95-47-6
L2
6.2
6.2
6.2
6.2
61 .9
12.4
248
61.9
6.2
6.2
6.2
62
6.2
6.2
6.2
6.2
6.2
6.2
61.9
12.4
12.4
12.4
6.2
70-1 30
70-1 30
70-'t32
,|
'l
1
1
1
1
1
1
1
'l
1
1
1
I
1
'l
'l
1
1
1
1
1
1
o/o
To
Yo
06117l'17 1B:55 2037-26-5
06117117 18:55 460-00-4
06117117 18:55 17060-07-0
06119117 09:37
06121117 06:20 7723:14-0
06121117 16:00 14808-79-8
06121117 '16:00 14797-55-8 H3
Analyt¡cal Melhod: ASTM D2974-87
30.6 %
Analytical Method: EPA 365.1
21.4 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
0.10 1
2.0 'l
7',t.9 1
7.2 I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tlen consent of Pace Analyt¡cal Services, LLCDale: 0612612017 '11:33 AM Page 17 of53
@
Pace Analytical Services, LLC
9800 K¡ncey Ave Suite '100
Huntersville, NC 28078
(704)875-90s2
Analytical
www.pacÊlaß.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344640
Sample: LS-7 Lab lD: 92344640007 Collected: O6116117 14:0O Received: 06/16/17 16:05 Matrix: Solid
Resu/fs reporled on a "dry weight" basis and are adjusted for percent moisture, sample size and any ditutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
60IO MET ICP Analyt¡cal Melhod: EPA6010 Preparation Method: EPA3050
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromod ichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
'1,2-D¡bromo-3-chloropropane
Dib rom och lo rometh ane
1,2-D¡bromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
'l ,4-Dichlorobenzene
tra ns-1,4-Dichloro-2-butene
'1 ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-'1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
9.4
98.3
0.80
ND
28.1
7.7
9.8
21.3
7.9
ND
ND
47.9
28.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
4.4
2.2
0.44
0-44
22
22
22
2.2
2.2
4.4
2.2
22
4.4
121
121
6.'1
6.1
61
61
12.1
121
12.1
6.1
6.1
12.1
61
12 1
61
6.1
6.1
6. 1
61
61
61
6.1
6.1
61
6.'l
61
o6t17t17
o6t17t17
o6t17t17
06t17t17
o6t17t17
06t17t17
o6t17t17
06t17t',t7
o6t17t17
o6t17117
06t17t17
06t17t17
o6t't7t'17
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
10:55
29 20
1.5 20
06120117 12:14
O6120117 12:'14
06120/,17 12:14
06120117 12t14
0612O117'12:14
06120117 12:14
O6120117 12:14
O6120117 12:14
O6120117 12:14
06120117 12:14
06120117'12:14
06120117 12:14
06120117 '12:14
06117117 19:15
O6h7h7 19:15
06h7117 19:15
06117117 19:15
06117117 19:15
06117117 19:15
O6h7h7 19:15
O6117117 19:15
O6h7l17 19:15
O6117117 19:'15
06117117 19115
06117117 19:15
06117117 19:15
06117117 19:15
O6h7l17 19:15
O6117117 19:15
06117117 19:15
06117117'19:15
06117117 19:15
06117117 19:15
06117117 19:15
06117117 19:'15
O6117117 19:15
06117117 19:15
06117117 19:15
06117117 19:15
7440-38-2
7440-39-3
7440-4't-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-O2-O
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-1
107 -13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-1 5-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
1 06-46-7
1't 0-57-6
75-34-3
107-06-2
75-35-4
I 56-59-2
'l56-60-5
N2
t
5
5
5
5
5
t
5
5
5
5
5
5
mg/kg
mg/kg
Analytical Method: EPA 8260
06120117 18:05 O6123117 01:54 7440-36-0
06120117 18i05 06123117 01154 744O-28-O
1
1
I
1
I
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
1
1
1
I
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seru¡ces, LLCDale. 0612612017 11 :33 AM Page 18 of53
@
Pace Analytical Services, LLC
9800 Kincey Ave Suite '100
Huntersv¡lle, NC 28078
(704)875-9Os2
Analytical
www.pacÊlabs.con
ANALYTICAL RESULTS
Project:
Pace Project No
Sample: LS-7 Lab lD: 92344640007 Collected: 06116117 14:OO Received: 06/16/1716:05 Matrix: Solid
Resurfs repoñed on a "dry weight" basis and arc adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
Cleveland County
92344640
Qual
8260/50354 Volatile Organics
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-D¡chloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,'1,2-fet achloroethane
1,1,2,2-fet achloroethane
Telrachloroethene
Toluene
1,1, 1 -Trichloroethane
1,1,2-Tr¡chloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogafes
Toluene-dB (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
Analytical Method: EPA 8260
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
6.1
6.1
61
6.1
60.6
'12.1
24.2
60.6
6.1
61
6.1
61
6.1
6.1
6.1
61
6.1
6.1
60.6
12.1
12 1
12 I
6.1
06117t17
06t17t17
06t17t17
06117117
06117117
06t17t17
06t't7t17
06t't7t17
06t17t17
06t17117
06l't7t't7
06t17t't7
06t17t't7
06t17t't7
06117117
06t17t17
06117117
o6t't7t17
06t17t17
06t17t17
06t't7t17
061't7117
06t17t't7
19:15
19:15
19:15
19:'15
19:15
19:15
1 9:'l 5
19:15
19:15
19:15
',l9:15
19:15
19: 15
19:15
19:'15
19:15
19:15
19:15
19:15
19:15
19:15
19:15
19:15
78-87-5
1 0061-01-5
1 0061 -02-6
100-41-4
591 -78-6
74-88-4
75-09-2
1 08-1 0-1
't00-42-5
630-20-6
79-34-5
127-18-4
1 0B-BB-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
1 08-05-4
75-01-4
't330-20-7
179601-23-1
95-47-6
L2
97
83
't24
Analytical Method: ASTM D2974-87
27.4 %
Analytical Method: EPA 365.1
151 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
%
To
Yo
70-1 30
70-1 30
70-132
06117117'19:15 2037-26-5 19
06117117 19:15 460-00-4
06117117 19:15 17060-07-0
06119117 09:37
06121117 07i55 7723-'14-0
06121 l'17 16:22 14808-79-8
06121117'16:22 14797-55-8 H3
23.7 10
0.10 1
68.9 1
6.9 1
REPORT OF LABORATORY ANALYSIS
This report shall nol be reproduced, except ¡n full,
without lhe wr¡tten consent of Pace Analytic€l Services, LLCDale: O612612O17 11 :33 AM Page 19 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
(704)87s-so92
Analytical
www.pa'Êlabs com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Sample: LS-8 Lab lD: 92344640008 Collected: 06h6h7 14:15 Received: 06116117 1605 Matrix: Solid
Resurls repoñed on a "dry weight" basis and are adjusled for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
60IO MET ICP Analytical Method: EPA6010 Preparation Melhod: EPA 3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selen¡um
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bro mo ch loro meth a ne
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
'1,2-Dibromo-3-chloropropane
Dib romoch lo ro meth ane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
I ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1-Dichloroethane
1,2-Dichloroethane
1 ,1 -Dichloroethene
cis- 1,2-Dichloroethene
trans-1,2-Dichloroethene
8.2
1'.16
1.1
ND
77.7
13.9
18.1
18.4
28.3
ND
ND
63.0
6l.6
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
136 ug/kg
ND ugikgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
5.9 ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
28.7 ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
06120117 18:05 06123117 01i57 7440-36-0
06120117 18:05 061231'17 01:57 744O-28-O
3.7
1.8
0.37
o37
1.8
1.8
18
1.8
1.8
3.7
1.8
1.8
3.7
114
114
5.7
5.7
5.7
5.7
11 4
114
11.4
5.7
5.7
11.4
57
11 4
57
5.7
5.7
5.7
57
5.7
57
57
5.7
5.7
5.7
5.7
Ã
5
5
5
5
5
5
t
5
5
5
5
5
06117117 1055
06117117 10:55
06t17t17 10.55
O6117117 10:55
O6h7l17 10i55
O6117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06h71'17'10:55
O6117117'10:55
061171'17 10:55
06120117 12:17
O612O117 12:17
06120117 12:17
061201'17 12:17
0612O117 12:17
06120117'12:17
06120117 12:17
06120117 12:17
0612O117 12:17
06120117 12:17
06120l'17 12:17
06120117 12:'17
o6t20t17 12'.',t7
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-15-0
56-23-5
I 0B-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
'106-93-4
74-95-3
95-50-1
1 06-46-7
I 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
Analytical Method: EPA6020 Preparation Method: EPA3050
29
1.5
20
20
06117117 19:35
06/17117 19:35
06117117 1935
06117117 19:35
061171'17 19:35
061171'17 19:35
O6117117 19:35
06117117 19:35
06117117 19:35
061'17117 19:35
06117117 19:35
061171'17 19:35
06117117 19:35
06117117 19:35
O6l17h7 19:35
06117117 19:35
06117117 19135
06117117 19:35
06117117 19.35
06117117 19:35
06117117 19:35
06117117 19:35
06117117 19:35
061'17117 19:35
06117117 19.35
06117117 19:35
N2
1
1
I
1
1
1
I
,|
1
1
1
1
1
1
1
1
1
1
1
1
1
,|
1
1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seruices, LLCDale'. 0612612017 l1 :33 AM Page 20 of 53
@
Pace Analyt¡cal Serv¡ces, LLC
9800 K¡ncey Ave Suite '100
Huntersville, NC 28078
(7 04)87 5-9092
Analytical
www.pac'elabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Sample: LS-8 Lab lD: 92344640008 Collected: 06116117 14:'15 Received: 06/16/1716:05 Matrix: Solid
Resurfs reported on a "dry we¡ght" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
Cleveland County
92344640
Qual
8260/5035A Volatile Organics
1 ,2-Dichloropropane
cis- 1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
'l ,1 ,1 ,2-fetachloroethane
1,'' ,2,2-lelr achloroethane
Tetrachloroelhene
Toluene
1 ,1 , 'l -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
.1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-dB (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Mo¡sture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
N¡trate as N
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
06117117 19:35
06117117 19:35
06117117 19:35
O6117117 19:35
06117117 19:35
06117117 19:35
06117117 19:35
061171'17 19:35
061'l7l'17 19:35
O6117117 19:35
06117117'19:35
o6117l',t7',t9:35
06/17117'19:35
O6117117 19:35
06117117 19:35
06117117 19:35
06117117 19:35
O6h7l17 19:35
O6117117 19:35
06117117 19:35
06117117 19:35
061171'17 19:35
06117117 19:35
78-87-5
1 0061-01-5
't 0061-02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
127-'t8-4 L2
1 08-88-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
1 0B-05-4
75-O1-4
1330-20-7
179601-23-',1
95-47-6
5.7
5.7
57
5.7
56.9
11.4
227
56.9
57
5.7
5.7
5.7
5.7
5.7
5-7
5.7
5.7
5.7
56.9
11 4
11 4
11 4
5.7
Yo
Yo
To
99
94
112
70-1 30
70-1 30
70-132
06l'17 I 17 19:35 2O37 -26-5
06117117 19:35 460-00-4
06117117 19:35 17060-07-0
O6119117 O9:37
06121117 07 55 7723-14-0
06121117 16:43 14808-79-8
061211'17 16:43 14797-55-8 H3
Analytical Method: ASTM D2974-87
23.2 o/o
Analytical Method: EPA 365.1
130 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
1 8.3 10
0.10 1
65.1 I
6.5 'l
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0612612O17 1 1 :33 AM Page 21 of 53
@
Pace Analytical Sewices, LLC
9800 KlnceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacf.labs.com
ANALYTICAL RESULTS
Project:
Pace Project No
Sample: LS-9 Lab lD: 92344640009 Collected: 06116117 14:30 Received: 06/16/17'16:05 Matrix: Solid
Resurfs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any d¡lutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
601O MET ICP Analytical Method: EPA6010 Preparalion Method: EPA3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
B ro moch lo ro metha ne
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-D¡bromo-3-chloropropane
Dibromochloromethane
'1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1 -Dichloroethane
1 ,2-Dichloroethane
'1 ,1-D¡chloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
6.9
135
1.3
ND
1't6
5.8
19.7
17.2
38.4
ND
ND
't1'l
35.0
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
1.4
0.68
0.14
0-14
0.68
0.68
0.68
0.68
0.68
14
0.68
0.68
1.4
124
124
o.z
62
6.2
ôz
124
124
12.4
62
6.2
12.4
6.2
124
oz
6.2
62
6.2
6.2
6.2
6.2
ı.2
o¿
62
6.2
6.2
2
2
2
2
2
2
2
2
2
2
2
2
2
06117117 1O:55
O6h7l17 '10:55
O6117117 1O:55
06117117 10.55
06117117 1O:55
06117117 1O:55
06117117 10:55
06117117 10:55
061'17117 10:55
06117117 10:55
061171'17 1O:55
061171'17 10:55
O6h7l17 10:55
06/19/17 1B:00
06/19/17 18:00
06/19/17 18:00
06/19/17 1B:00
06/19/17 1B:00
06/19/17 18:00
06/19/'17'18:00
06/19/17 18:00
06/19/17 18:00
06/19/17 1B:00
06119117 18:OO
06/19/17 18:00
06119117 18:0O
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-'l
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
I 08-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
1 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
't 56-60-5
mg/kg
mg/kg
Analytical Method: EPA 8260
26 20
'1 .3 20
06120117 18:05 06123117 02:05 7440-36-0
06120117 18:05 06123117 02:O5 7440-28-0
N2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1
I
I
1
1
1
1
I
I
1
1
1
1
1
I
1
1
1
1
I
'l
1
I
1
1
1
O6h7h7 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06h7117 19t55
06117117 19i55
06117l'17 19:55
061'17117 19:55
061'17117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06h7h7 19:55
O6117117 19:55
06t17t17'19'.55
06117117 19:55
06117117 19:55
06117117 19:55
061'17117 19:55
061'l7l'17 19:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDalei 0612612017 11 :33 AM Page 22 of 53
@
Pace Analytical ServÌces, LLC
9800 K¡ncey Ave Suite 1 00
Huntersville, NC 28078
(704)87 5-90s2
Analytical
M.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Sample: LS-g Lab lD: 923¡14640009 Collected: 06116117 14:30 Received: 06/16/1716:05 Matrix: Solid
Resu/fs repo¡7ed on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report L¡mit DF Prepared Analyzed CAS No
Analytical Method: EPA 8260
Cleveland County
92344640
Qual
8260/50354 Volatile Organ¡cs
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (M IBK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-fet achl o roetha ne
Telrachloroethene
Toluene
1 ,1 ,1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trich lo rofl u oro metha ne
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-dB (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
N¡trate as N
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
99
96
't10
70-'t 30
70-1 30
70-132
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
62
6.2
6.2
6.2
62.2
12.4
249
62.2
62
6.2
6.2
6.2
ô.2
o.¿
62
6.2
6.2
6.2
62.2
12.4
12.4
12.4
6.2
06117117 19:55
06117117 19i55
06117117 19:55
06117117 19:55
061'17117 19:55
06|17117 19:55
O6h7l17 19:55
06117117 19"55
06117117 19:55
06117117 19:55
06117117 19:55
061'17117 19:55
06117117 19i55
O6l'l7l'17 19:55
O6117l'17 19:55
06117117 19:55
06117117 19:55
06117117 19:55
06117h7 19:55
061'17h7 19:55
061171'17 19:55
O6117117 19:55
06117117 19:55
78-87-5
1 0061-01-5
I 0061-02-6
100-41-4
591-78-6
74-88-4
75-09-2
't 08-1 0-1
100-42-5
630-20-6
79-34-5
127-',t8-4
1 08-88-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
1 08-05-4
75-O1-4
1330-20-7
179601-23-1
95-47-6
L2
%
To
o/o
06117117 19:55 2037-26-5
06117117 .19:55 460-00-4
06117117 19:55 17060-07-0
O6119117 O9:37
06121 117 06:24 7723-14-0
06121 117 17:47 148O8-79-8
06121117 't7:47 14797-55-8 H3
Analytical Method: ASTM D2974-87
21.3 Yo
Analytical Method: EPA 365.1
16.5 mgikg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
6.6 mg/kg
0.10 1
'1.6 1
63.5 1
6.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, LLCDale: O6/26120'17 11:33 AM Page 23 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacelabs.con
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
92344640
Sample: LS-10 Lab lD: 92344640010 Collected: 06116117 14:35 Received: 06/16/17 '16:05 Matrix: Solid
Resu/fs repo¡led on a "dry weight" bas¡s and are adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
601O MET ICP Analytical Method: EPA6010 Preparalion Method: EPA3050
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ibromoch lo rometh a ne
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
'1 ,1-Dichloroethane
1,2-Dichloroethane
'1 ,I -Dichloroethene
c¡s-1,2-Dichloroethene
trans-1,2-Dichloroethene
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mgikg
mgikg
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
15.0
82.1
1.1
ND
69.5
8.4
15.6
20.6
16.0
3.2
ND
79.5
32.1
12
0.62
0.'t2
0.12
0.62
0.62
o62
0.62
0.62
1.2
0.62
0.62
12
3.1
'1.5
137
137
6.9
6.9
6.9
6.9
137
137
13.7
6.9
6.9
13.7
6.9
137
6.9
6.9
6.9
69
69
69
69
6.9
6.9
6.9
6.9
69
06t17t17
06117117
o6t17t17
o6t17t17
06t17t17
06t't7t17
06117t17
o6t17t17
06117117
o6t17t17
o6t17t17
o6t17t17
06117t17
10:55
10:55
10:55
10:55
'10:55
10:55
10:55
'10:55
10:55
10:55
10:55
10:55
10:55
06118117 21:08
06118117 2'l:08
06118117 21:08
06118117 21:08
06118117 21:08
06118117 21:O8
O6118117 21:08
06118117 21:08
061'18117 2'1108
061't9t't7 21:08
06118117 21:08
06118117 21:08
06118117 21:OB
O6117117 2O:15
06117117 2O:15
06117117 2O:'15
06t17t17 20"15
06117117 20:15
061171'17 20:15
06117117 20:15
06117117 20:15
06117117 20:15
O6117117 20:15
06117117 2O:15
061171'17 2015
06117117 2O:15
06117117 20:15
06117117 20:15
06117117 2O:15
06117117 20:15
06117117 20:15
06t17t17 20'15
06117117 20:15
06117117 20:15
06117117 2O:15
O6117117 20:15
06117117 2O:15
o6t17t17 20"15
06117117 20:15
7440-38-2
7440-39-3
7440-41-7
7440-43-g
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-'l
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-1 2-B
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
110-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
N2
Analytical Method: EPA6020 Preparation Method: EPA3050
20
20
06120117 18'.05 06125117 04:20 7440-36-0
06120117 18:05 06125117 04i20 7440-28-0
187
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analyt¡cal Services, LLCDate: 0612612017'11 :33 AM Page 24 of 53
o
Pace Analytical Seruices, LLC
9800 KlnceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
ww.paælabs.æm
ANALYTICAL RESULTS
Project:
Pace Project No
Cleveland County
92344640
Sample: LS-10 Lab lD: 92344640010 Collected: 06116117 14:35 Received: 06116117 16:05 Matrix: Solid
Resu/fs repoñed on a "dry weight" basis and are adjusted for percent moisture, sample size and any d¡lutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.Qual
8260/50354 Volatile Organics
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Elhylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (M I BK)
Styrene
1, 1, 1,2-Tetrachloroelhane
1 ,1 ,2,2-Tetrachloroetha ne
Tetrachloroethene
Toluene
'1,1,'l -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
'1,2, 3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogaúes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
Analytical Method: EPA 8260
Analytical Method: ASTM D2974-87
25.4 Yo
Analytical Method: EPA 365.1
78.0 mg/kg
Analytical Melhod: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kgND ug/kg
ND ug/kg
ND ug/kg
99
90
107
70-1 30
70-1 30
70-132
6.9
6.9
69
69
68.5
13.7
27.4
68.5
6.9
6.9
69
6.9
6.9
6.9
6.9
6.9
6.9
6.9
68.5
13.7
13-7
13.7
6.9
1
1
1
1
1
1
1
1
1
1
1
I
1
,|
1
1
1
I
1
1
1
1
I
06117117 20"15
06117117 2O:15
06117h7 20i15
06117117 20:15
061171'17 20:15
06117117 2O:15
06117117 2O:15
06117117 20:15
06117117 20:15
06117h7 20:15
O6117117 20:15
06117117 2O:15
06117117 2O:15
06117117 2O:15
06117117 2O:15
06117117 20:15
06117h7 20t15
O6117117 2O:15
06117117 2O:15
06117117 2O:15
06117117 20:15
06h7117 20:15
06117117 20:15
78-87-5
1 0061-01-5
'10061-02-6
100-41-4
591 -78-6
74-BB-4
75-09-2
1 0B-1 0-1
't00-42-5
630-20-6
79-34-5
127-18-4
1 08-88-3
71-55-6
79-00-5
79-0'1-6
75-69-4
96-18-4
1 0B-05-4
75-0',t-4
1330-20-7
179601-23-1
95-47-6
L2
o/o
%
%
061'17 117 20:1 5 2037 -26-5
06117117 20:15 460-00-4
06117 117 20:15 17060-07 -0
06119117 09:37
06121117 O6:24 7723-14-0
06121117 18:09 14808-79-8
06121117 18:09 '14797-55-8 H3
0.10 1
17 1
67.0 1
67 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDate: 0612612017 11 :33 AM Page 25 of 53
Analytical
Pace Analytical Seru¡ces, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]ww.paælabs æm
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
Sample: LS-11 Lab lD: 92344640011 Collected: 06116117 14:45 Received: 06/'t6/1716:05 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
60IO MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acelone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichlorometha ne
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ib romoch lo rom eth a ne
1,2-Dibromoethane (EDB)
Dibromomethane
'1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1-Dichloroethane
1 ,2-Dichloroethane
'1 ,'1 -Dichloroethene
cis-'1,2-Dichloroethene
trans-1,2-Dichloroethene
Analytical Method: EPA6020 Preparation Method: EPA3050
10.6
't16
1.5
ND
't14
12.2
24.4
22.0
35.5
ND
ND
103
40.6
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
1.9
0.94
0.19
0.19
0.94
0.94
094
094
0.94
1.9
0.94
0.94
1.9
2B
14
113
113
57
57
5.7
5.7
1'1 .3
1',t3
11 .3
5.7
57
11.3
57
11 .3
5.7
5-7
5.7
57
5.7
57
5.7
5.7
5.7
5.7
5.7
06t19t17
06t19t17
06t't9t17
06t19t17
06119t17
06t19t17
o6t19t17
o6t19t17
06t19t17
06119117
06119t17
06t19t17
o6t19t17
18:03
18:03
18:03
18:03
18:03
18:03
'18:03
18:03
'18:03
'18:03
18:03
18:03
1B:03
2
2
2
2
2
2
2
2
2
2
2
2
2
06117117 10:55
06117117 10:55
06t17t17 10'.55
06117117 10:55
06l'17117 1055
O6117117 10:55
O6117117 10:55
O6117117 10:55
06117117 10:55
06117117 10:55
06117117 10t55
O6l'17117 10:55
O6117117 1O:55
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
mg/kg
mg/kg
Analytical Method: EPA 8260
20
20
06120117 18:05 06123117 02.11
06120117 18:05 O6123117 02:11
7440-36-0
7440-28-0
N2
122
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1
1
1
,|
I
1
1
1
1
I
1
1
1
I
1
1
1
I
1
1
1
1
1
1
1
I
06117117 20:34
O6h7h7 2034
O6117117 2034
06117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
06117117 2O:34
O6h7h7 20:34
06117117 20:34
O6117117 20:34
O6117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
O6117117 2O:34
06t17t17 20'.34
06117117 2O:34
O6117117 20:34
O6117117 20:34
06117117 20:34
06117h7 20:34
06117117 20:34
o6t17t17 20.34
O6117117 2O:34
O6117117 2O:34
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-1 5-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
'106-93-4
74-95-3
95-50-1
106-46-7
1 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
REPORT OF LABORATORY ANALYSIS
Thìs report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Serv¡ces, LLCDate: 06/26/2017 11 :33 AM Page 26 of 53
Analytical
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersvllle, NC 28078
[phone]www.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344640
Sample: LS-11 Lab lD: 92344640011 Collected: 06116117 14:45 Rece¡ved: 06116117 16:05 Matrix: Solid
Resurfs reporled on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report L¡mit DF Prepared Analyzed CAS No
8260/50354 Volatile Organics Analytical Method: EPA 8260
Qual
1 ,2-Dichloropropane
cis-'1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (M I BK)
Styrene
1 ,1 ,1 ,2-feÍachloroethane
1,1,2,2-fet achl oroetha ne
Tetrachloroethene
Toluene
1,1, 1 -Trichloroethane
1, I,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC An¡ons 48hr
N¡trate as N
100
93
't12
Analytical Method: ASTM D297 4-87
21.4 o/o
Analytical Method: EPA 365.1
83.8 mg/kg
Analyt¡cal Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
57
5.7
5.7
5.7
56.7
11.3
22.7
56.7
5.7
5.7
57
5.7
57
5.7
5.7
5.7
5.7
5.7
56.7
11 3
't1 -3
11 3
5.7
06117117 20:34
06117l'17 20:34
06117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
06117117 2O:34
06117h7 20:34
06117117 20:34
06117117 20:34
06117117 2O:34
06117117 2Oi34
06l'17117 20:34
061'17117 20:34
O6117117 20:34
06117117 20:34
O6117117 20:34
O6117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
06117117 20:34
7B-87-5
1 0061-01 -5
1 0061-02-6
100-41-4
591 -78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4
1 08-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-1 8-4
I 08-05-4
75-O1-4
1330-20-7
179601-23-1
95-47-6
L2
To
Yo
To
70-1 30
70-1 30
70-132
06117 117 2O:34 2O37-26-5
06117 117 2O:34 460-0O-4
06117 117 20:34 17060-07-0
06/19i17 09:38
06121117 06125 7723-'14-0
06121117 18:30 14808-79-8
06121117 18:30 14797-55-8 H3
0.10 1
2.5 1
63.3 1
63 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: O612612O17 '11:33 AM Page 27 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
(7o4r875-9092
Analytical
www.pacelabs con
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
Sample: LS-12 Lab lD: 92344640012 Collected: 06116117 14:50 Rece¡ved: 06/16/17 16:05 Matrix: Solid
Resu/fs reporled on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
601O MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thall¡um
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochlorometha ne
Bromod ichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
'1,2-Dibromo-3-chloropropane
D¡b romoch lorometha ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-'1,2-Dichloroethene
Analytical Method: EPA6020 Preparalion Method: EPA3050
't't.9
99.9
't.5
ND
138
14.9
17.1
19.8
26.4
ND
ND
75.1
51.9
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
4.1
21
0.41
0.41
2.1
2.1
2.1
2.1
2.1
4.1
2.',|
2.1
41
2.9
1.5
139
'139
69
69
6.9
6.9
13.9
139
13.9
69
6.9
13.9
6.9
'13.9
6.9
6.9
69
69
69
69
6.9
69
6.9
6.9
6.9
6.9
06117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
06117117 10:55
061171'17 10:55
06t17t17 10.55
O6117117 10:55
06117h7 10:55
O6117117 10:55
O6117117 10:55
O6h7l17 10:55
06117117 10:55
06120117 12:20
06l2jh7 12:20
O6120117 12:2O
06120117 12:20
06120117 12:2O
06120117 12:20
06120117 12:20
06120117 12:20
06120117 12:20
06120117 12:20
06120117 12:20
O6120117 12:2O
06120117 12:20
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-O2-O
7782-49-2
7440-22-4
7440-62-2
7440-66-6
ND mg/kg
ND mg/kg
Analytical Method: EPA 8260
20
20
06120117 18:05 O6123117 02:14 7440-36-0
06120117 18:05 O6l23h7 02:14 7440-28-0
06117117 20:54
06117117 20:54
06117117 20:54
06117117 20:54
06117117 20:54
06117117 20:54
06117117 2O:54
06117117 20:54
06117117 2O:54
061'17117 2O:54
061'17117 2O:54
061'17117 2O:54
06117117 20:54
06h7117 20i54
06117117 20:54
O6117117 20:54
O6117117 20:54
06117117 2O:54
06117117 20:54
06117117 2O:54
06117117 20:54
06117117 20:54
061'17117 20:54
06117117 20:54
06117117 2054
06117117 20.54
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-1 2-B
124-48-1
I 06-93-4
74-95-3
95-50-'1
1 06-46-7
1'1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
N2
181
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
1
1
1
1
1
1
1
1
1
1
1
'l
'l
'l
I
1
1
1
1
1
1
1
I
I
,|
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: O612612017 11 :33 AM Page 28 of 53
Analytical
Pace Analytical Serv¡ces, LLC
9800 K¡nceyAve Su¡te 100
Huntersv¡lle, NC 28078
(704)87s-90e2www.pa'elabs com
ANALYTICAL RESULTS
Project:
Pace Project No :
Sample: LS-12 Lab lD: 92344640012 Collected: O6h6l17 14i50 Received: 06/16/1716:05 Matrix: Solid
Resurfs reported on a "dry weight" basis and are adjusted for percent moisturc, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
8260/50354 Volatile Organics Analytical Method: EPA 8260
Cleveland County
92344640
Qual
1 ,2-Dichloropropane
cis-1,3-D¡chloropropene
trans-',l,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-1et achloroethane
Tetrachloroethene
Toluene
1 ,1 ,1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroelhene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Su/rogafes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.1 Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
98
89
112
70-1 30
70-1 30
70-132
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.9
6.9
6.9
6.9
69.4
13.9
278
69.4
69
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
69.4
139
13.9
13.9
6.9
0.10 1
061171'17 20:54
06117117 20:54
061171'17 20:54
06h7h7 20:54
06117117 20:54
O6117117 20:54
06117117 2O:54
O6117117 2O:54
06117117 20:54
06117117 20:54
06117117 20:54
061'17l'17 20:54
061171'17 20:54
061171'17 20:54
06117117 20:54
06117117 20:54
06117117 20:54
O6117117 2O:54
06117117 20:54
06117117 2Oi54
061'17117 20:54
O6117117 20:54
06117117 20:54
78-87-5
1 0061 -01 -5
1 0061 -02-6
't00-41-4
591 -78-6
74-88-4
75-09-2
I 0B-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4 L2
1 08-88-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
108-05-4 M1
75-01-4
1330-20-7
179601-23-1
95-47-6
To
%
06117 I'17 20:54 2037 -26-5
06117 117 2O:54 460-00-4
06117 117 20:54 17060-07-0
06i19/17 09:38
06121117 06:28 7723-14-0
06121117 18:51 14808-79-8
06121117 18:51 14797-55-8 H3
Analytical Method: ASTM D2974-87
16.8 Yo
Analytical Method: EPA 365.1
1'14 mg/kg
Analytical Method: EPA 9056
ND mg/kg
Analytical Method: EPA 9056
ND mg/kg
59.6 1
2.4 ',l
60 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tlen consent of Pace Analytical Services, LLCDale: O612612O17 11 :33 AM Page 29 of 53
@
Pace Analytical Services, LLC
9800 Kincey Ave Suite '100
Huntersville, NC 28078
(704)875-90e2
Analytical
www.pacÊlâbs com
ANALYTICAL RESULTS
Project:
Pace Project No.
Sample: BKGD-I Lab lD: 92344640013 Collected: 06/16/1715:00 Received: 06/'16/1716:05 Matrix: Solid
Resu/fs reporled on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
601O MET ICP Analytical Method: EPA6010 Preparation Method: EPA 3050
Cleveland County
92344640
Qual
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochlorometha ne
Bro mod ich loro metha ne
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ibromoch lo rometh a ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
I ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroelhene
Analytical Method: EPA6020 Preparation Method: EPA3050
10.2
75.8
0.92
ND
65.2
32.O
20.5
14.7
23.5
2.4
ND
66.6
39.7
2030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mgikg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
2.2 201.1 20
U- ¡/b
0.38
0.076
0.076
0.38
0.38
0.38
0.38
0.38
0.76
0.38
0.38
076
124
124
62
62
6.2
6.2
12.4
124
12.4
62
62
12.4
6.2
12.4
6.2
o.z
o.z
62
62
62
6.2
6.2
62
6.2
o¿
62
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-"t5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-12-B
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
1 I 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
I
1
'l
1
1
1
1
1
1
1
1
1
1
O6117117 1055
06117117 10:55
06117117 1O:55
O6h7l17 10:55
O6h7h7 10:55
O6h7h7 10:55
06l'17117 10:55
06117117 10:55
06117117 10.55
06117l'17 10i55
06117117 10:55
06117117 10:55
06117117 1O:55
O6l'18117 21:27
O6118117 21:27
06118117 21:27
06118117 21:27
06118117 21:27
06118117 21:27
06118117 21:27
06t18t17 21'.27
061'18117 21:27
061'18117 21:27
O6118117 21:27
06118l'17 21:27
O6118117 21:27
06117117 21:14
06117117 21:14
06117117 21'.14
06117117 21:14
061'17117 21:14
061'17117 21:14
061171'17 21:14
O6117117 21:14
06117117 2'l:'14
O6117117 21:14
06117117 21:14
06117117 21:14
061'17117 21:14
06117117 21:14
06117117 21:14
06117117 21:'14
06117117 21:14
o6t17t17 21.14
06117117 21:14
06117117 21:14
06117117 21:14
061171'17 21:14
06117h7 21:14
06117117 21.14
O6117117 21:14
O6117117 21:14
mg/kg
mg/kg
Analytical Method: EPA 8260
ND
ND
06120117 1805 06123117 02:16 7440-36-0
06120117 18:O5 06123117 02t16 7440-28-0
N2
E1
1
1
1
1
I
1
1
1
1
I
,|
1
1
1
1
1
1
I
1
1
1
1
1
1
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except jn full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDale. 0612612017 1'1:33 AM Page 30 of 53
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
(704)875-e092
Analytrcal
w.pacelabs mm
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County
92344640
Sample: BKGD-1 Lab lD: 92344640013 Collected: 06/16/17 15:00 Received: 06116117 16:05 Matrix: Solid
Resurfs reported on a "dry weight" basis and are adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
8260/50354 Volatile Organ¡cs Analytical Method: EPA 8260
Qual
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-D¡chloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (Ml BK)
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-fet achloroethane
Tetrachloroethene
Toluene
1 ,1 ,1 -Trichloroelhane
'1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogafes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
365.'l Phosphorus, Total
Phosphorus
9056 lC Anions
Sulfate
9056 lC Anions 48hr
Nitrate as N
101
93
'123
Analytical Method: ASTM D2974-87
15.3 To
Analytical Method: EPA 365.1
72.1 mg/kg
Analytical Method: EPA 9056
446 mg/kg
Analytical Method: EPA 9056
ND mg/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
6.2
6.2
6.2
6.2
61.9
12.4
24.7
61.9
6.2
6.2
6.2
6-2
6.2
6.2
6.2
62
6.2
6.2
61.9
12.4
't2.4
12.4
6.2
70-1 30
70-l 30
70-132
7B-87-5
10061-01-5
1 0061 -02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4
1 08-88-3
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
1 08-05-4
75-01-4
1330-20-7
179601-23-'l
95-47-6
L2
1
I
1
1
1
1
I
1
,|
'l
'l
1
1
1
1
1
I
1
1
'l
1
I
1
O6117l'17 21:14
06117117 21:'14
06l'17117 21:'14
O6117117 21:14
O6117117 21:14
06117117 21:14
06117117 21:14
06117117 2'l:14
06117117 2'l:14
06117117 2'l:14
O6l'17117 2'l:'14
06117h7 21:'14
06117117 21:14
06117117 21:14
O6117117 21:14
O6117117 21:14
06117117 21:14
061171'17 21:14
06117117 2'l:'14
06h7117 21:14
061'17117 21:'14
06l'17117 21:14
06117117 21:14
Yo
o/o
%
06117 117 21t14 2037 -26-5
06117 117 21:14 460-00-4
06117 117 21:1417060-07 -0
06119117 O9:42
06121 117 06:28 7723-14-0
06121117 19:13'14808-73-8
06121117 19:13 14797-55-8 H3
0.10 1
58.4 1
2.2 1
5.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDale: 0612612017 11 :33 AM Page 31 of 53
o
Pace Analytical Senrices, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.paælabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
QC Batch: 365272 Analysis Method: EPA6010
QC Batch Method: EPA3050 Analysis Description: 6010 MET
Assoc¡ated Lab Samples: 92344640001, 92344640002,92344640003, 92344640004,92344640005, 92344640006, 92344640007,
92344640008, 92344640009, 92344640010, 92344640011 , 92344640012, 92344640013
METHOD BLANK: 2025374 Matrix: Solid
Associated Lab Samples: 92344640001 , 92344640002,92344640003, 92344640004,92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 92344640010, 92344640011 , 92344640012, 92344640013Blank Reporting
Parameter Units Result Lim¡t Analyzed Qualifìers
Arsen¡c
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mgikg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.0
0.50
0.10
010
0.50
050
0.50
0.50
0.50
1.0
0.50
0.50
1.0
06118117 2O:12
061'lBl'17 20:12
06118117 20:12
0611Bl'17 20:12
O6118l'17 2O:12
06118117 20:12
O6h8l17 20:12
06118117 20:12
06118117 20:12
06118117 20:12
06118117 2012
O6118117 2O:12
06118117 2O:12
LABORATORY CONTROL SAMPLE:
Parameter
2025375
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
46.2
49.5
48.4
483
48.5
48.0
49.0
47.1
47.4
48.6
24.8
47.6
48.0
92
99
97
97
97
96
98
94
95
97
99
95
96
50
50
50
50
50
50
50
50
50
50
25
50
50
80-120
80-1 20
80-120
B0-120
80-120
80-120
80-120
80-1 20
80-1 20
80-120
80-1 20
B0-'t20
B0-1 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2025376
Parameter
3531 821 4001
Units Result
MS
Spike
Conc.
MSD
Spike
Conc
2025377
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
L¡mits RPD Qual
Arsen¡c
Barium
mg/kg
mg/kg
0.61J
96 42
42 45.3 36.8 39.2
45.3 48.3 49.2
86 85 75-125
87 75-125
6
92
Results presented on th¡s page are in the unlts ¡nd¡cated by the "Unlts" column except where an alternate un¡t ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM
2
Page 32 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve. Su¡te 100
Huntersvìlle, NC 28078
[phone]
Analytical
w.pacelabs com
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2025376
Parameter
3531 8214001
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
2025377
Result
MSD
Result
MS
% Rec
MSD
o/o Rec
MS % Rec
Limits RPD Qual
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
0.048J
0.039u
2.7
0.20u
14
9.2
0.54
0.39U
0.20u
5.0
72
42
42
42
42
42
42
42
42
2'l
42
42
45.3
45.3
45.3
45.3
45.3
45.3
45.3
45.3
22.6
45.3
45.3
40.5
39.9
43.0
38.0
44.0
50.9
38.2
38.5
2't 1
44.3
50.4
42.3
42.O
44.9
39.6
45.6
55.1
39.5
40.4
222
46.2
51.4
96
95
96
91
102
99
90
91
100
94
103
93
93
93
87
98
101
86
B8
98
91
97
75-125
75-125
75-',!25
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
4
5
4
4
4
B
3
5
5
4
2
Results presented on th¡s page are ¡n the uníts indicated by the "Units" column except where an altemate un¡t ís presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLC.Dale: 0612612017 1 1 :33 AM Page 33 of 53
6
Pace Analytical Services, LLC
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
[phone]
Analyttcal
www.pacÊlabs con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
QC Batch: 376200 Analysis Method: EPA6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004, 92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 92344640010, 92344640011 , 92344640012, 92344640013
METHOD BLANK: 2036958 Matrix: Solid
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004, 92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 9234464001 0, 9234464001',t , 92344640012, 9234464001 3Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony
Thallium
mg/kg
mg/kg
ND
ND
1.9
0.97
06123117 01:15 N2
06123117 01:15
LABORATORY CONTROL SAMPLE:
Parameter
2036959
Un¡ts
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
Thallium
mg/kg
mg/kg
30.9
30.9
33.6
31.6
109
102
80-120 N2
80-'t20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2036960
Parameter
3531 902901 0
Un¡ts Result
MS
Splke
Conc.
MSD
Spike
Conc.
2036961
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
Antimony
Thallium
36 34.7
34.7
't07
103
105
102
mg/kg
mg/kg
1.3U
0.64U
38.7
37.2
36.6
35.7
75-125
75-125
5N2
436
Results prcsented on this page are in the units ¡ndicated by the "Unlts" column except where an alternate un¡t is presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Seruices, LLCDale: O612612017 11 :33 AM Page 34 of 53
6
Pace Analytical Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacielabs com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland Counly
92344640
QC Batch: 365296 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV 5035A Volatile Organics
Associated Lab Samples: 92344640001, 92344640002, 92344640003, 92344640004, 92344640005, 92344640006, 92344640007
92344640008, 92344640009, 9234464001 0
METHOD BLANK: 2025500 Matrix: Solid
Assoc¡ated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004,92344640005, 92344640006, 92344640007
92344640008, 92344640009, 9234464001 0
Blank ReportingParameter Units Result Lim¡t Analyzed Qualifìers
1 ,1 ,1 ,2-Tetrachloroethane
1, 1, 1 -Trichloroethane
1,1,2,2-Telr achloroethane
'1, 1,2-Trichloroethane
1 ,I -Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
I ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (M IBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichlorometha ne
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
D ib ro moch loro melha ne
Dibromomelhane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.9
5.9
5.9
5.9
59
5.9
5.9
5.9
5.9
5.9
59
59
5.9
118
59.0
590
118
118
5.9
5.9
5.9
5.9
11 8
11.8
5.9
5.9
11 .B
5.9
11 .8
59
59
5.9
5.9
59
11 .B
11 8
23.6
59
5.9
5.9
O6h7l17 12:00
06l'17117 12:00
O6117117'12:00
06117117 12:OO
06117117 12:OO
06117117 12:OO
06117h7 12:00
06117117 12:00
O6117117'12:00
061'17117 12:O0
06117117 12:OO
06117117 12:OO
06117117 12:00
06117h7 12:00
06117117 12:O0
06117117 12:O0
06117117 12:O0
O6117117 12:OO
06117117 12:0O
06117117 12:00
06117117 12:00
06117117 12:00
O6117117 12:00
O6l'l7l'17 12:00
06117117 12:00
O6117117 12:00
06117117 12:O0
O6117117 12:00
06117117 12:00
o6t17t17 12.00
06117117 12:O0
06117117 12:O0
06117117 12:O0
o6t17t17 12'.00
O6117117 12:0O
06117117 12:00
O6117117 12:00
061'17117'12:00
06117117 12:00
O6h7l'17 12:00
Results presented on this page are in the units ind¡cated by the "Un¡ts" column except where an alternate unit ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in [ull,
without the written consent of Pace Analytical Services, LLCDale: O612612017 11 :33 AM Page 35 of 53
o
Pace Analytical Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacelabs.crm
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
METHOD BLANK: 2025500 Matrix: Solid
Associated Lab Samples: 92344640001, 92344640002,92344640003, 92344640004,92344640005,92344640006, 92344640007
92344640008, 92344640009, 9234464001 0
Blank Report¡ngParameter Units Result Limit Analyzed Qualifìers
Toluene
trans- 1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
'1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
To
%
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
110
99
100
5.9
5.9
5.9
5.9
5.9
5.9
59.0
11.8
1l.8
70-132
70-1 30
70-130
06117117 12:O0
06117117 12:00
061171'17 12:00
06/17117 12:00
06117117 12:00
061171'17 12:00
O6117117 12:0O
06117117 12:OO
06117117 12:OO
061'17117 12:00
061'17117 12:O0
061171'17 12:00
LABORATORY CONTROL SAMPLE:
Parameter
2025501
Units
Spike
Conc.
LCS
Result
LCS
7o Rec
% Rec
L¡m¡ts Qualifìers
1,1,1,2-Tetachloroethane
l, 1, 1 -Trichloroethane
1,1,2,2-fel¡ achloroethane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,I -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-D¡chloroethane
I ,2-Dichloropropane
'1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (Ml BK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
B romod ich loro m eth a ne
Bromoform
Bromomethane
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
58.7
58.7
58.7
58.7
58.7
58.7
58.7
587
587
587
58.7
58.7
58.7
117
't17
117
117
293
587
58.7
58-7
58.7
58.7
58.7
587
58.7
58.7
58.5
55.8
60.2
58.7
57.2
58.4
59.0
58.1
58.6
5B,B
57.6
5B.B
58.6
128
131
136
11 5J
309
57.3
56.4
60.2
56.7
58.7
57.6
56.5
580
59.5
100
95
103
100
98
100
101
99
100
100
98
100
100
109
112
116
98
105
98
96
103
97
100
9B
96
oo
101
74-137
67-140
72-141
78-1 38
69-1 34
67-1 38
69-144
65-1 40
77-135
77-141
65-1 37
72-136
76-1 38
58-147
62-145
64-149
53-1 53
56-1 53
73-1 35
73-134
71-135
66-141
53-1 60
63-140
60-145
78-1 30
64-149
Results presented on th¡s page are in the units ¡ndicated by the "Unlts" column except where an alternate un¡t ls presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYS¡S
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: O612612017 11:33 AM Page 36 of 53
Analytical
Pace Analytical Services, LLC
9800 K¡ncey Ave Suite '100
Huntersville, NC 28078
(704)87s-9092www.pacÊlabs æm
QUALITY CONTROL DATA
Project:
Pace Project No
Cleveland County
92344640
LABORATORY CONTROL SAMPLE
Parameter
2025501
Units
Spike
Conc.
LCS
Result
LCS
o/o Rec
% Rec
Limits Qualifiers
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromelhane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-'1,3-Dichloropropene
trans- 1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
o/o
Yo
%
58.7
58.7
58.7
58.7
58.7
58.7
58.7
117
117
58.7
58.7
58.7
58.7
587
58.7
58.7
58.7
58.7
58.7
't17
58.7
176
58.8
66.9
574
60.2
60.6
54.3
58.8
110
116
52.0
58.1
55.3
344
57.8
58.2
60.1
6'1.1
568
58.6
't22
57.8
174
100
1',!4
9B
103
103
92
100
93
98
89
99
94
59
9B
99
'l02
104
97
100
104
9B
99
101
101
101
70-134
52-150
70-1 33
6B-1 34
71-138
74-130
75-133
69-144
75-1 36
45-154
76-141
79-137
71-138 L2
74-131
67-1 35
65-146
70-1 30
67-1 35
59-144
40-r 60
56-141
76-137
70-'t32
70-1 30
70-1 30
MATRIX SPIKE SAMPLE:
Parameter
2025817
Un¡ts
92344640002
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifiers
MS
1 ,1 ,1 ,2-Tetrachloroethane
1 ,1 , I -Trichloroethane
'1,'1,2,2-Tetachloroethane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1,2, 3-Trichloropropane
1,2-Dibromo-3-chloropropane
'1,2-Dibromoethane (EDB)
'1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22-9
22.9
459
45.9
45.9
24.',|
25.1
26.0
20.2
249
27.8
255
22.3
22.4
21.8
23.8
23.9
227
52.5J
52 1J
49J
105
110
113
88
'108
121
111
97
98
95
104
104
99
't|5
't14
107
70-1 30
70-130
70-1 30
70-1 30
70-1 30
49-'180
70-1 30
70-1 30
70-1 30
70-1 30
70-'130
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Results presented on th¡s page are ¡n the units ind¡cated by the "Units" column except where an alternate un¡t is presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in tull,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM Page 37 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875-e092
Analytical
www.pacÊlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No
Cleveland Counly
92344640
MATRIX SPIKE SAMPLE:
Parameter
2025817
Units
92344640002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Acetone
Acrylonitrile
Benzene
Bromochloromethane
B romod ¡ch lorometh a ne
Bromoform
Bromomethane
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Elhylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans- 1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
45.9
115
22.9
22.9
229
22.9
22.9
22.9
22.9
22-9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
22.9
45.9
45.9
229
22.9
229
22.9
22.9
22.9
22.9
22.9
22-9
22.9
45.9
22.9
120
131
238
23.4
23.1
21.6
27.4
24.5
25.9
23.8
25.2
24.2
28',!
24.7
23.5
24.1
22.6
25.1
40-7
48.5
24.4
238
22.7
199
23.5
26.2
21.5
20-5
23.6
27.8
23J
25.7
't 88
't15
104
102
101
94
1'19
107
113
104
110
'106
'122
108
102
10s
99
110
89
106
107
104
99
87
103
114
94
90
103
121
50
112
'103
96
9B
70-130 M1
70-1 30
50-166
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
43-169
70-1 30
70-'t 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-130
70-1 30
70-1 30
70-1 30
70-130
70-130
70-130
52-1 63
70-1 30
70-1 30
70- 1 30
49-',t67
70-'t 30
70-130 M1
70-1 30
70-132
70-130
70-130
SAMPLE DUPLICATE: 2025816
Parameter Units
92344307010
Result
Dup
Result RPD Qualifiers
1, 1, 1,2-Tetrachloroethane
1 ,1 ,1 -Trichloroelhane
1,1,2,2-fet achloroethane
1, 1,2-Trichloroethane
1 ,1-Dichloroethane
1 ,1 -Dichloroethene
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Results presented on th¡s page are ¡n the units ¡nd¡cated by the "Units" column except where an alternate unit ¡s presented to lhe right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM Page 38 of 53
o
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pa6Êlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
SAMPLE DUPLICATE: 2025816
Parameter
92344307010
Result
Dup
Units Result RPD Qualifiers
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
'l ,2-Dichlorobenzene
1 ,2-D¡chloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-'1,2-Dichloroethene
trans-'1, 3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
94
oo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
36.6J
ND
2.8J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.9J
ND
2.2J
ND
ND
6.5
ND
ND
ND
ND
ND
ND
ND
ND
0
90
105
SO
't1
2
Results presented on th¡s page are in the units ind¡cated by the "Un¡ts" column except where an alternate un¡t is presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDale: 0612612017 11:33 AM Page 39 of 53
@
Pace Analyt¡câl Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacìÊlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
QC Batch: 365297 Analysis Method:
QC Batch Method: EPA 8260 Analysis Description
Associated Lab Samples: 92344640011, 92344640012, 923446400'13
EPA 8260
8260 MSV 5035AVolatile Organics
METHOD BLANK: 2025502 Matrix: Solicl
Associated Lab Samples: 92344640011, 92344640012, 92344640013
Blank Reporting
Parameter Un¡ts Result Limit Analyzed Qualif ers
1 ,1 ,1 ,2-fetachloroethane
1, 1, 1 -Trichloroethane
'' ,1,2,2-Telr achl o roethane
1, 1,2-Trichloroethane
1 ,1-Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-D¡chloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitr¡le
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
5.6
113
56.4
56.4
1',!3
113
5.6
5.6
5.6
5.6
't1.3
11.3
5.6
5.6
11.3
5.6
11.3
5.6
5.6
5.6
56
5.6
11 3
11.3
22.6
5.6
5.6
5.6
5.6
06117117 11:40
061171'17 11:40
061'17117 11:40
06117117 11 40
06117117 11:40
06117117 11:40
06117117 11:40
061171'17 11:40
061171'17 11:40
06117l'17 1'l:40
06t17t',t7 1',t:40
o6117l',t7 1',t:40
061171'17 11:40
O6117117 11:40
061'17117 11 40
O6117117 '11:40
O6117117 11:4O
O6117117 11:4O
06117117 '11:40
06117117 11:40
O6117l'17 11:40
061171'17 11:40
06117117 1'l:40
061171'17 11:40
O6117l'17 11:40
O6117117 11:40
O6l'17117 1'l:40
06117117 11:40
O6117117 11:40
06117h7 11:40
06117117 '11:40
06117117 '11:40
06117117 11:4O
06117117 11:4O
O6h7l17 11140
O6117l'17 11:40
06117l'17 1'l:40
o6117t',t7 1',t:40
061'17117 1'l:40
O6l'17117 1'l:40
06117117 1'l:40
Results presented on th¡s page are ¡n the un¡ts ¡ndicated by the "Units" column except where an alternate unlt ls presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Servìces, LLC.Dale: 0612612017 11 :33 AM Page 40 of 53
@
Pace Analytical Seruices, LLC
9800 K¡ncey Ave Suite 1 00
Huntersville, NC 28078
[phone]
Analytical
www.pãcÊlabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
METHOD BLANK: 2025502 Matrix: Solid
Associated Lab Samples: 92344640011|, 9234464001 2, 9234464001|3
Blank
ResultParamelerUnits
Reporting
Limit Analyzed Qualifìers
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
trans- 1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
'1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
ND
ND
ND
ND
ND
ND
ND
ND
104
100
98
5.6
5.6
56
5.6
5.6
56.4
11.3
11 .3
70-132
70-1 30
70-1 30
06117117 11:40
O6117117 11:4O
O6l'17117 '11:40
06117117 11:40
061'17h7 11:40
06117117 1'l:40
06117117 11:40
06t17t17 11'40
06t17t17 11'.40
O6117117 11:40
06117117 11:40
LABORATORY CONTROL SAMPLE:
Parameter
2025503
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
I ,1 , '1 ,2-Tetrachloroethane
1, I, 1 -Trichloroethane
1,1,2,2-Telr achloroethane
1, 1,2-Trichloroethane
I ,1-Dichloroethane
I ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (M IBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Brom od ichlorometh a ne
Bromoform
Bromomethane
Carbon disulf¡de
Carbon telrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
63.9
63.9
63.9
63.9
63.9
63.9
639
639
63.9
63.9
63.9
63.9
63.9
128
128
128
128
320
63.9
63.9
63.9
639
639
639
63.9
63.9
639
63.9
63.9
65.9
61.6
71.7
659
643
654
66.4
70.5
66.9
67.1
63.7
65.8
67.2
146
155
157
135
356
63.6
63-2
66.3
657
639
63.4
63.4
663
649
63.0
74.6
103
96
112
103
101
102
104
110
105
105
100
103
105
114
121
123
'106
111
99
99
104
103
100
oo
99
104
101
98
117
74-137
67-140
72-141
78-1 38
69-1 34
67-1 38
69-144
65-140
77-135
77-141
65-'137
72-136
76-1 38
5B-147
62-145
64-149
53-1 53
56- t 53
73-1 35
73-134
71-135
66-1 41
53-1 60
63-140
60-145
78-1 30
64-149
70-134
52-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit ¡s presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall nol be reproduced, except ¡n full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM Page 41 of 53
@
Pace Analytical Sery¡ces, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
wwwpacelafu com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
LABORATORY CONTROL SAMPLE:
Parameter
2025503
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Oualifiers
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
D ib romo ch loro melh a ne
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-D¡chloropropene
trans-'1,4-D¡chloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chlorìde
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
o/o
63.9
63.9
639
63.9
639
128
128
639
63.9
639
639
63.9
63.9
63.9
63.9
63.9
639
128
639
192
636
67.4
69.6
620
662
126
130
58.4
66 1
oJ.b
39.0
64.7
64.5
68.3
766
62.1
65.1
169
63.3
196
100
105
109
97
104
9B
102
91
103
99
61
101
101
107
120
97
102
132
oo
102
101
101
10'1
70-1 33
68-1 34
7 1-138
74-130
75-1 33
69-144
75-1 36
45-',!54
76-141
79-137
71-138 t2
74-131
67-1 35
65-146
70-1 30
67-1 35
59-144
40-1 60
56-141
76-137
70-132
70-1 30
70-1 30
MATRIX SPIKE SAMPLE:
Parameter
2025815
Units
923446400',t2
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifìers
MS
1 ,1 ,1 ,2-fetachloroethane
1, 1, 1 -Trichloroethane
'1,1,2,2-Telr achlo roeth a n e
1,1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
'1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
I ,2-Dichlorobenzene
1 ,2-Dichloroethane
1,2-Dichloropropane
I ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
26.2
262
262
26.2
26.2
26.2
26.2
262
26.2
26.2
26.2
26.2
262
524
524
524
52.4
't 3'1
247
26.6
26.6
25.3
27.5
28.9
26 1
27.7
259
21.5
25.9
26.'l
23.2
70.2J
58.5J
58 5J
z5t
135
94
102
101
97
105
't10
'100
106
99
82
99
't 00
8B
108
112
112
107
103
70- 1 30
70-'130
70-'130
70-1 30
70-1 30
49-1 80
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70- 1 30
70-1 30
70-1 30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
181
ND
Results presented on th¡s page are in the un¡ts ¡nd¡cated by the "Unlls" column except where an alternate un¡t ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0612612017 11 :33 AM Page 42 of 53
@
Pace Analytical Services, LLC
9800 KÌnceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacþlabs com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
MATRIX SPIKE SAMPLE:
Parameter
2025815
Units
92344640012
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifìers
MS
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomelhane
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans- 1,2-Dichloroethene
trans-1,3-D¡chloropropene
trans-1,4-Dichloro-2-butene
Tr¡chloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
'1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
%
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
262
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
52.4
52.4
26.2
262
26.2
26.2
26.2
26.2
26.2
26.2
26.2
26.2
52.4
26.2
50-166
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
43-169
70-1 30
70-'t 30
70-1 30
70-1 30
70-130
70-130
70-'t30
70-130
70-1 30
70-'130
70-1 30
70-130
70-130
70-1 30
52-163
70-1 30
70-1 30
70-1 30
49-167
70-1 30
70-130 M1
70-1 30
70-132
70-1 30
70-1 30
27.9
22.',|
25.7
22.3
27.6
28.2
28.5
23.4
27.5
262
32.2
27.3
26.2
25.9
26.4
26.5
42.4
50.2
33.4
24.6
20.2
22.1
27.0
28.1
24.O
24.4
26.1
29.3
16.6J
27.8
107
84
9B
85
105
108
109
B9
105
100
123
104
100
99
101
101
81
96
128
94
77
84
103
't07
9'l
93
100
'112
32
106
102
96
103
SAMPLE DUPLICATE: 2025814
Parameter
92344640011
Result
Dup
Units Result RPD Qualifìers
1 ,1 ,1 ,2-Tetrachloroethane
1 , 1 ,1-Trichloroethane
1,1,2,2-felrachloroethane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Results presented on thls page are in the un¡ts ¡ndicated by the "Un¡ts" column except where an altemate unit ¡s presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except Ìn full,
without the wr¡tten consent of Pace Analytical Serv¡ces, LLC.Date: O612612O17 11:33 AM Page 43 of 53
Analytical'
Pace Analyt¡cal Seruices, LLC
9800 K¡nceyAve Su¡te 100
Huntersville, NC 28078
[phone]www.pa'iâlabs cffi
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
SAMPLE DUPLICATE: 2025814
Parameter
92344640011
Result
Dup
Un¡ts Result RPD Qualifiers
1,2-Dibromoethane (EDB)
I ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
D¡bromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
o/o
%
%
ND
ND
ND
ND
ND
ND
ND
ND
122
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1't2
93
100
ND
ND
ND
ND
ND
ND
ND
ND
138
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.5J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
110
100
'102
13
13
4I
Results presented on this page are in the un¡ts ¡ndicated by the "Units" column except where an altemate un¡t ¡s presented to the rlght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLC.Dale: 0612612017 1 1 :33 AM Page 44 of 53
Analytical
Pace Analytical Seryices, LLC
9800 K¡ncey Ave Suite 1 00
Huntersville, NC 28078
[phone]www.pac,elabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
QC Batch: 365253 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry WeighUPercent Moisture
Associated Lab Samples: 92344640001,92344640002,92344640003, 92344640004,92344640005, 92344640006, 92344640007,
92344640008, 92344640009, 92344640010,92344640011 , 92344640012, 923446400',t3
SAMPLE DUPLICATE: 2025310
Parameter
9234464000't
Result
Dup
Units Result RPD Qualifìers
Percent Moisture o/o 25.8 24.3 6
SAMPLE DUPLICATE: 2025311
Parameter Un¡ts
9234461 8009
Result Result
27.7
RPD Qualifìers
To 39.1 34 R1
Results presented on this page are ln the unlts ¡ndlcated by the "l,Jn¡ts" column except where an alternate unit ¡s presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLC.
DUp
Percent Moisture
Dale: 0612612017 11 :33 AM Page 45 of 53
@
Pace Analytical Seruices, LLC
9800 K¡ncey Ave Suite '100
Huntersvìlle, NC 28078
[phone]
Analytical
www.pacelabs com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
QC Batch: 365714 Analys¡s Method: EPA 365 1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Tolal
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004, 92344640005,92344640006, 92344640007
92344640008,92344640009,92344640010,92344640011,92344640012,92344640013
METHOD BLANK: 2027548 Matr¡x: Sol¡d
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004, 92344640005,92344640006, 92344640007
92344640008, 92344640009, 92344640010,92344640011 , 923446400't2,9234464001 3
Blank ReportingParameter Units Result Limit Analyzed Qualifìers
Phosphorus mg/kg 2.0 06121117 07:54ND
LABORATORY CONTROL SAMPLE:
Parameter
2027549
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
Phosphorus mg/kg 50 46.1 92 90-1 1 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027550
Parameter
9234464000',!Units Result
MS
Sp¡ke
Conc.
MSD
Spike
Conc.
2027551
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
Phosphorus mg/kg 86.1 67.4 66.1 110 96.7 36 16 90-110 13 M1.R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027552
Parameter
923446400't1
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
2027553
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limils RPD Qual
Phosphorus mg/kg 83.8 52-2 6'1.2 136 148 100 105 90-110 I
Results presented on this page are in the un¡ts ¡ndicated by the "Un¡ts" column except where an alternate unit is presented to lhe r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017 11:33 AM Page 46 of 53
@
Pace Analytical Services, LLC
9800 KinceyAve Suite'100
HuntersvÌlle, NC 28078
[phone]
Analytieal
www.paælabs.cw
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344640
QC Batch: 376095 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 lC Antons
Associated Lab Samples: 92344640001,92344640002,92344640003, 92344640004,92344640005, 92344640006, 92344640007,
92344640008, 92344640009, 92344640010, 92344640011 , 92344640012, 92344640013
METHOD BLANK: 2036381 Matrix: Solid
Associated Lab Samples: 92344640001 , 92344640002,92344640003, 92344640004, 92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 92344640010,92344640011 , 923446400',12, 92344640013
Blank Reporting
Parameter Units Result Limit Analyzed Qualif ers
Sulfate mg/kg 49.4 06121117 21:00ND
LABORATORY CONTROL SAMPLE:
Parameter
2036382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Sulfate mg/kg 491 464 95 80-1 20
MATRIX SPIKE SAMPLE:
Parameter
2036384
Units
92344640001
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifiers
MS
Sulfate mg/kg ND 668 595 85 80-120
SAMPLE DUPLICATE: 2036383
Parameter Units
92344640001
Result Result RPD Qualifiers
mg/kg ND
Results presented on th¡s page are in the units ¡nd¡cated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analyt¡cal Services, LLC
Dup
Sulfate ND
Dale: 06126120'17 11 :33 AM Page 47 o'f 53
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Analytrcal
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QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344640
QC Batch: 376094 Analysis Method: EPA9056
QC Batch Method: EPA 9056 Analysis Description: 9056 lC Anions
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004, 92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 92344640010, 92344640011 , 92344640012, 92344640013
METHOD BLANK: 2036377 Matrix: Solid
Associated Lab Samples: 92344640001 , 92344640002, 92344640003, 92344640004,92344640005, 92344640006, 92344640007 ,
92344640008, 92344640009, 92344640010, 9234464001',t , 92344640012, 92344640013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifìers
Nitrate as N mg/kg ND 4.9 061211'17 21:OO
LABORATORY CONTROL SAMPLE:
Parameter
2036378
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Nitrate as N mg/kg 49.5 46.9 95 80-120
MATRIX SPIKE SAMPLE
Parameter
2036380
Units
92344640001
Result
MS
% Rec
% Rec
Lim¡ts Qualifiers
Spike
Conc.Result
MS
Nitrate as N mg/kg ND 66.2 61.7 93 B0-120 H3
SAMPLE DUPLICATE: 2036379
Parameter Units
92344640001
Result
Dup
Result RPD
Nitrate as N
Qualifìers
mg/kg ND ND H3
Results presented on this page are ¡n the units ind¡cated by the "Unlts" column except whefe an alternate unit is presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Serv¡ces, LLCDate: 0612612017 1'l :33 AM Page 48 of 53
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Pace Analytical Seruices, LLC
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Huntersv¡lle, NC 28078
[phone]
Analytrcal
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QUALIFIERS
Project:
Pace Project No.:
Cleveland County
92344640
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to d¡lut¡on of the sample aliquol
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentrat¡on above the adjusted method detection lim¡t and below the adjusted reporting limit.
MDL - Adjusted Method Deteclion Limit.
PQL - Practical Quantitation Limit
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentrat¡on.
Consistent w¡th EPA guidelines, unrounded data are d¡splayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Malrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent D¡fference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - lndicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SWB46 Chapter 4 for the analysis of Acrolein and Acrylon¡trile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separaled from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC lnstitute.
LABORATORIES
PASI-A
PASI-C
PASI-O
Pace Analytical Services - Asheville
Pace Analytical Serv¡ces - Charlotte
Pace Analytical Services - Ormond Beach
The internal standard response is below criteria. No hits associated with this ¡nternal standard. Results unaffected by
h¡gh b¡as.
Analyte concentration exceeded the calibration range The reporled result is estimated.
Sample was received or analysis requested beyond the recognized method holding time.
Analyte recovery in the laboratory conlrol sample (LCS) was below QC lim¡ts. Results for this analyte in associated
samples may be biased low
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
The lab does not hold NELAC/TNl accreditation for this parameter
RPD value was outside control limits.
Surrogate recovery outside laboratory control l¡m¡ts.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLC
t1l Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference
ANALYTE QUALIFIERS
BATCH QUALIFIERS
Balch:376228
1g
E
H3
L2
M1
N2
R1
SO
DaTe: 0612612017 11:33 AM Page 49 of 53
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[phone]
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QUAL]TY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No
Cleveland County
92344640
Lab lD Sample lD QC Batch Method QC Batch Analytical Method
Analyt¡cal
Batch
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
9234464001 0
9234464001',!
92344640012
92344640013
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
923446400't0
923446400'.t1
923446400't2
92344640013
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
923446400',t0
923446400',t1
92344640012
92344640013
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
LS-1
LS-2
LS-3
LS.4
LS-5
LS-6
LS-7
LS-8
LS-9
LS-10
LS-I1
LS.12
BKGD.I
LS-1
LS-2
LS-3
LS-4
LS-5
LS-6
LS-7
LS-8
LS-9
LS-10
LS-11
LS-I2
BKGD.I
365272
365272
365272
365272
365272
365272
365272
365272
365272
365272
365272
365272
365272
EPA 601 O
EPA 601O
EPA 601 O
EPA 601 O
EPA 601 O
EPA 601O
EPA 60,10
EPA 601O
EPA 601O
EPA 601O
EPA 601O
EPA 601O
EPA 601 O
EPA 6020
EPA 6020
EPA 6020
EPA 6020
EPA 6O2O
EPA 6O2O
EPA 6020
EPA 6020
EPA 6020
EPA 6020
EPA 6020
EPA 6020
EPA 6020
36531 7
36531 7
3653'17
36531 7
3653'17
36531 7
36531 7
3653'17
36531 7
36531 7
36531 7
36531 7
3653 1 7
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3O5O
EPA 3050
EPA 305O
EPA 305O
EPA 3O5O
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
ASTM D2974-87
ASTM D2974.87
ASTM D2974-87
ASTM D2974.87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
376200
376200
376200
376200
376200
376200
376200
376200
376200
376200
376200
376200
376200
365296
365296
365296
365296
365296
365296
365296
365296
365296
365296
376228
376228
376228
376228
376228
376228
376228
376228
376228
376228
376228
376228
376228
LS-I
LS-2
LS-3
LS-4
LS-5
LS-6
LS-7
LS-8
LS-9
LS-10
LS-11
LS-12
BKGD-1
LS-l
LS-2
LS-3
LS-4
LS-s
LS-6
LS-7
LS-8
365297
365297
365297
365253
365253
365253
365253
365253
365253
365253
365253
REPORT OF LABORATORY ANALYSIS
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w¡thout the written consent of Pace Analytical Seruices, LLCDate.0612612017 1'1 :33 AM Page 50 of 53
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Pace Analytical Services, LLC
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[phone]
Analytical
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QUAL¡TY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Cleveland CounÇ
92344640
Lab lD Sample lD QC Batch Method QC Batch Analytical Method
Analytical
Batch
92344640009
9234464001 0
92344640011
92344640012
92344640013
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
92344640010
92344640011
92344640012
92344640013
92344640001
92344640002
923¡f4640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
92344640010
9234464001'l
92344640012
92344640013
92344640001
92344640002
92344640003
92344640004
92344640005
92344640006
92344640007
92344640008
92344640009
9234464001 0
92344640011
92344640012
92344640013
LS-9
LS.1O
LS-11
LS-12
BKGD-I
LS-l
LS-2
LS-3
LS.4
LS-5
LS-6
LS.7
LS-8
LS-9
LS.1O
LS.II
LS-12
BKGD.I
LS-1
LS-2
LS-3
LS-4
LS-s
LS-6
LS-7
LS-8
LS-9
LS-10
LS.Il
LS-I2
BKGD.I
LS-I
LS-2
LS.3
LS-4
LS-5
LS-6
LS-7
LS.8
LS-9
LS-10
LS-fi
LS-I2
BKGD-I
ASTM
ASTM
ASTM
ASTM
ASTM
D2974-87
D2974-87
D2974-87
D2974-87
D2974-87
365253
365253
365253
365253
365253
365714
365714
365714
365714
365714
365714
365714
365714
365714
365714
365714
365714
365714
376094
376094
376094
376094
376094
376094
376094
376094
376094
376094
376094
376094
376094
EPA 365 1
EPA 365 1
EPA 365.1
EPA 365.1
EPA 365.1
EPA 365.'1
EPA 365.1
EPA 365.1
EPA 365.1
EPA 365.1
EPA 365.1
EPA365 1
EPA 365 1
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
EPA 9056
376095
376095
376095
376095
376095
376095
376095
376095
376095
376095
376095
376095
376095
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analyt¡cal Services, LLC.Dale: O612612O17 11 :33 AM Page 5'l of 53
:Ë¡þ '4**r^CHAIN-OF-CUSTODY / Analytical Request Document
The Cha¡n-of-Custody ¡s a LEGAL DOCUMENT All relevanl fields must be compleled accuralely
Sccllon CSêctlon À Sêcdon B
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Pace Analytical Services, LLC
9800 K¡nceyAve Suite'100
Huntersville, NC 28078
(704)875-90s2
Analyttcal
wwvpacelabs.con
June 26,2017
Ayla Homer
Shield
4301 Taggaft Creek Road
Charlotte, NC 28208
RE: Project: Cleveland County
Pace Project No.: 92344890
DearAyla Homer:
Enclosed are the analytical results for sample(s) received by the laboratory on June 20,2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless othen¡yise noted in the body of the report.
lf you have any questions concerning this report, please feel free to contact me
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. James Gamertsfelder, Shield Engineer¡ng
REPORT OF LABORATORY ANALYSIS
This report shall nol be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Serv¡ces, LLC.Page 1 of 15
o
Pace Analytical Seruices, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pac€,labs.com
CERTIFICATIONS
Project:
Pace Project No.
Cleveland County
92344890
Charlotte Certification lDs
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carol¡na Field Services Certification #:5342
North Carolina Wastewaler Certification #: 12
South Carolina Certifìcation #: 99006001
FloridaiNELAP Certification #: 887627
Kentucky UST Certification #: 84
VirginiaA/ELAP Cert¡fìcat¡on #: 460221
Asheville Gertification lDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetls Certif¡cation #: M-NC030
North Carolina Drinking Water Cert¡fication #: 377 1 2
Norlh Carolina Wastewater Certifìcation #: 40
South Carolina Certification #: 99030001
VìrginiaA/ELAP Certifìcation #: 460222
REPORT OF LABORATORY ANALYS]S
This report shall not be reproduced, except ¡n full,
without the wr¡ften consent of Pace Analytical Serv¡ces, LLC Page 2 of 15
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Huntersv¡lle, NC 28078
[phone]
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.
Cleveland Counly
92344890
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
92344890001 LWS-'I EPA 601 O
EPA 6020B
EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLC.
SH1
CDF
GAW
't3
2
52
PASI-A
PASI-A
PASI-C
Page 3 of 15
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9800 KinceyAve Suite 100
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[phone]
Analytical
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ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344890
Sample: LWS-I
Parameters
Lab lD: 92344890001
Results Units
Collected: 06120117 10100
Report Limit DF
Received: 06120117 12:35 Matrix: Water
Prepared Analyzed CAS No.Qual
60IO MET ICP
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Antimony
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
B ro m och lo ro metha ne
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachlor¡de
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ibrom och lo rometh a ne
1,2-Dibromoethane (EDB)
D¡bromomethane
1 ,2-Dichlorobenzene
'l ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
I ,1-Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
Analytical Method: EPA6010 Preparation Method: EPA3010A
ND
342
ND
ND
'143
28.4
33.7
25.',|
46.2
ND
ND
108
135
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
50.0
25.0
5.0
5.0
250
25.0
250
250
25-O
50.0
25.0
250
500
1g
1g
1g
1g
1g
1g
1g
1g
1g
1g
1g
1g
1g
I
'l
I
1
1
1
1
I
1
1
,|
1
I
06121117 1900
06121117 19100
06121117 19:00
06121117 19:00
O6121117 19:O0
O6121117 19:00
061211'17 19:00
06121117 19:00
06121117 19:00
06121117 19i00
06121117 19:00
06121117 19:00
06121117 19:00
06122117 11:19
06122117 11 '19
06122117'11:19
06122117 11:19
O6122117 11:19
06122117 11:19
O6122117 1'l:19
06122117 11:19
06122117 11:19
06122117 11:'19
06122117'11:19
06122117 11:19
O6122117 11:19
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-47-3
7440-48-4
7440-50-8
7439-92-1
7440-02-0
7782-49-2
7440-22-4
7440-62-2
7440-66-6
Analytical Method: EPA60208 Preparation Method: EPA3010A
ND ug/L
0.51 ug/L
Analytical Method: EPA 8260
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ugiLND ug/L
ND ug/L
ND ug/L
2.5
050
25.0
10 0
1.0
1.0
1.0
1.0
20
50
20
'1.0
10
1.0
1.0
10
2.0
10
10
10
1.0
'1.0
'1 0
10
10
10
1.0
1.0
1.0
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
7B-93-3
75-1 5-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
I 06-93-4
74-95-3
95-50-1
106-46-7
'11 0-57-6
75-34-3
't07-06-2
75-35-4
'156-59-2
I 56-60-5
78-87-5
5
E
06121117 04:30 06124117 13:08 7440-36-0
06121117 04:30 06124117 13:08 744O-28-O
D3
D3
M1
M1
1
I
I
1
1
1
1
1
1
1
1
1
I
1
1
I
1
1
1
I
1
'l
1
1
1
1
I
06121117 03:45
O6l21h7 03t45
06121117 03:45
O6121117 O3:45
06121117 O3:45
06121117 O3i45
061211'17 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 0345
0612'1117 03:45
06121117 03:45
06121117 03:45
O6121117 O3:45
06121117 O3:45
O6121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
06121117 03:45
O6121117 03:45
O6l21h7 03:45
REPORT OF LABORATORY ANALYS]S
Th¡s report shâll not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017 09:1 3 AM Page 4 of 15
6
Pace Analyt¡cal Services, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analyttcal
www.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County
92344890
Sample: LWS-I
Parameters
Lab lD: 92344890001
Results Units
Collected: 061201'17 10:00
Report Limit DF
Received: 06120l'17 12:35 Matrix: Water
Prepared Analyzed CAS No.Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans-1,3-D¡chloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (Ml BK)
Styrene
1,1,1,2-felr achl oroelha ne
1,1,2,2-feÍ achloroethane
Tetrachloroethene
Toluene
1, 1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-dB (S)
Analyt¡cal Method
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
EPA 8260
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
06121117 O3:45
06121h7 03i45
06121117 03:45
06121117 03:45
0612'1117 03:45
06121117 O3:45
06121117 03:45
O612'1117 O3:45
06121117 03:45
06121117 03:45
06121117 O3:45
06121117 03:45
06121l'17 03:45
06121117 03:45
O6l21h7 03:45
06121117 03:45
06121117 03:45
06121117 03:45
O6121117 O3:45
0612'1117 03:45
06121117 O3:45
061211'17 03:45
1 0061 -01 -5
1 0061-02-6
100-41-4
591-78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
127-18-4
1 08-88-3
71 -55-6
79-00-5
79-01 -6
75-69-4
96-1 B-4
1 08-05-4
75-0't-4
1330-20-7
179601-23-1
95-47-6
1.0 11.0 1
1.0 'l
5.0 1
50 'l
10 1
50 1
1.0 1
1.0 1
1.0 1
1.0 1
1.0 110 1
1.0 I
1.0 1't.0 'l
1.0 'l
2-O 1
1.0 11.0 1
2.0 110 I
103
93
99
Yo
To
To
70-1 30
70-1 30
70-1 30
061211'17 03:45 460-00-4
06121117 03:45 17060-07-0
06121 I'17 O3:45 2O37 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seru¡ces, LLC.Dale: 0612612017 09:13 AM Page 5 of 15
@
Pace Analyt¡cal Services, LLC
9800 K¡ncey Ave Suite '100
Huntersville, NC 28078
(704)875-90e2
Analytical
www.pactlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344890
QC Batch: 365721
QC Batch Method: EPA30l0A
AssociatedLabSamples: 92344890001
Analysis Method:
Analys¡s Description
EPA 601 O
601O MET
METHOD BLANK: 2027584
AssociatedLabSamples: 92344s90001
Parameter
Matrix: Water
Units
Blank
Result
Reporting
Limit Analyzed Qualifiers
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
't 0.0
50
1.0
1.0
5.0
5.0
5.0
50
50
100
5.0
5.0
10.0
06122117 '11:13
06122117 11:13
O6l22h7 11i13
06122117 11:13
O6122117 11:13
06122117 11:13
06122117 11:'13
06122|17 11:13
06122117 11:'13
06122117 11:13
O6122117 1'l:13
06122117 11:13
06122117 11:13
LABORATORY CONTROL SAMPLE:
Parameter
2027585
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
L¡mits Qualifiers
Arsenic
Barium
Beryllium
Cadm¡um
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanad¡um
Zinc
B0-1 20
80-120
80-1 20
80-1 20
B0-120
B0-1 20
80-1 20
80-1 20
80-'t20
80-120
80-'t20
80-120
B0-120
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
486
506
493
501
499
505
5'16
495
489
517
260
492
505
500
500
500
500
500
500
500
500
500
500
250
500
500
97
101
99
100
100
101
103
99
98
103
104
98
101
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027586
Parameter
92344831001
Units Result
MS
Spike
Conc.
MSD
Spike
Conc
2027587
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
Arsen¡c
Barium
Beryllium
ugiL
ug/L
ug/L
23.2
318
ND
521
aaa
497
528
841
505
500
500
s00
500
500
500
99
101
99
101
104
101
75-125
75-125
75-125
1
2
2
Results presented on th¡s page are ¡n the un¡ts ¡nd¡cated by the "un¡ts" column except where an alternate un¡t ¡s presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDale: 0612612D'17 09:'l 3 AM Page 6 of 15
@
Pace Analytical Services, LLC
9800 KinceyAve Su¡te 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacÊlabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344890
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027586
Parameter
92344831001Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
2027587
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selen¡um
Silver
Vanad¡um
Zinc
500
500
500
500
500
500
500
250
500
500
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
5.4
2.8J
ND
ND
4.0J
ND
100
99
99
105
97
96
101
105
100
99
101
99
100
106
97
96
102
106
101
100
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-'t25
75-125
75-'t25
507
500
500
529
492
484
508
265
508
499
501
497
496
524
488
481
504
262
503
496
500
500
500
500
500
500
500
250
500
500
Results presented on th¡s page are in the units ¡nd¡cated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLC-Date: 0612612O17 09:13 AM Page 7 of 15
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacÊlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344890
QC Batch: 365737
QC Batch Method: EPA3010A
AssociatedLabSamples: 92344890001
Analysis Method:
Analysis Description
EPA 602OB
6020 MET
METHOD BLANK: 2027634
AssociatedLabSamples: 92344890001
Parameler
Matrix: Water
Units
Blank
Result
Reporting
Limit Analyzed Qualifìers
Antimony
Thallium
ND
ND
ug/L
ug/L
0.50
0.10
06124h7'13:04
06124117'13:04
LABORATORY CONTROL SAMPLE
Parameter
2027635
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Ant¡mony
Thallium
96
95
ug/L
ug/L
100
100
96.1
95.1
80-1 20
B0-1 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027636
Parameter
92344890001
Un¡ts Result
MS
Spike
Conc.
MSD
Spike
Conc.
2027637
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
Antimony
Thallium
ug/L
ug/L
ND
0.51
81 0
96 1
80.9
92.6
81
96
100
100
100
100
80 75-125
92 75-125
0
4
Results presented on th¡s paqe are ¡n the un¡ts ¡nd¡cated by the "Un¡ts" column except where an alternate unit is presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
Th¡s report shall nol be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Serv¡ces, LLCDaae: 0612612017 09:13 AM Page I of 15
@
Pace Analytical Seruices, LLC
9800 Kincey Ave Suite 1 00
Huntersv¡lle, NC 28078
[phone]
Analytical
w.pacÊlabs con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344890
QC Batch: 365738
QC Batch Method: EPA8260
AssociatedLabSamples: 92344890001
Analysis Method:
Analysis Description
EPA 8260
8260 MSV Low Level Landfìll
METHOD BLANK: 2027638
AssociatedLabSamples: 92344890001
Parameter
Matr¡x: Water
Units
Blank
Result
Reporting
Limit Analyzed Qualifiers
1 ,1 ,1 ,2-Tetrachloroethane
1 ,1 ,1 -Trichloroethane
1,1,2,2-Tetrachloroethane
1, 1,2-Trichloroethane
1, l-Dichloroethane
I ,1 -D¡chloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
',l,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (M IBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroelhene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Elhylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.0
1.0
1.0
't.0
1.0
1.0
'1.0
2.0
1.0
1.0
1.0
10
10
50
5.0
5.0
25.0
10.0
1.0
1.0
1.0
'1.0
20
2.O
10
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
20
10
't 0
1.0
10
1.0
06121117 O2:53
0612'lh7 02:53
O6121l'17 O2:53
06121117 02:53
O6121117 02:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 O2:53
06121117 02:53
06121117 O2:53
061211'17 O2:53
0612'1117 O2:53
06121117 02:53
0612'1117 02:53
O6121117 O2:53
06121h7 02:53
O6121117 O2:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 O2:53
06121117 O2:53
06121117 02:53
06121117 02:53
0612'll'17 O2:53
061211'17 02:53
O6121l'17 O2:53
06121117 02:53
O6121l'17 02:53
06121117 02:53
06121117 02:53
06121h7 02:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 02:53
06121117 O2:53
06121117 O2i53
Results presented on this page are in the un¡ts ¡nd¡cated by the "Un¡ts" column except where an alternate unlt ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale. 0612612O17 09:1 3 AM Page 9 of 15
o
Pace Analytical Seruices, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.paælabs com
QUALITY CONTROL DATA
Project:
Pace Project No
Cleveland County
92344890
METHOD BLANK: 2027638
AssociatedLabSamples: 92344890001
Parameter
Matrix: Water
Units
Blank
Result
Reporting
Limit Analyzed Qualifìers
trans- 1,2-Dichloroethene
trans-'1, 3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
To
Yo
o/o
ND
ND
ND
ND
ND
ND
ND
ND
90
94
99
10
1.0
1.0
'1 0
1.0
20
1.0
1.0
70-1 30
70-1 30
70-'130
O6121117 02:53
06121117 02:53
O612'1117 02:53
0612'lh7 02:53
06121117 02:53
0612'1117 02:53
06121117 02:53
06121117 O2:53
06121117 02:53
06121117 O2:53
0612'1117 O2:53
LABORATORY CONTROL SAMPLE:
Parameter
2027639
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
L¡m¡ts Qualifìers
I ,1 ,1 ,2-Tetrachloroethane
1, 1, 1 -Trichloroethane
1,1,2,2-1el¡ achloroethane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
I ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomelhane
Carbon d¡sulf¡de
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
50
50
50
50
50
50
50
50
50
50
50
50
50
'100
100
100
100
250
50
50
50
50
50
50
50
50
50
50
50
48.'l
45.5
48.4
48.1
45.6
47.1
476
470
493
47.g
42.9
48.3
48.4
862
90.0
87.0
96.3
222
49.1
46.7
485
45.8
61 2
45.3
46.8
488
50.7
47.2
67 1
96
91
97
96
91
94
95
94
99
96
B6
97
97
86
90
87
96
B9
98
93
97
92
122
9'1
94
98
101
94
134
B0-125
71-129
79-124
85-1 25
73-126
66-l 35
75-1 30
71-133
83-124
B0-1 33
67-',t28
75-'t32
78-1 30
61-'t44
68-143
72-'t35
48-',!46
40-160
80-125
71-125
78-124
71-128
40-1 60
50-1 60
69-1 31
81-122
39-1 48
73-127
44-146
Results presented on this page are ¡n the units ¡ndlcated by the "Un¡ts" column except where an alternate un¡t ls presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shal¡ not be reproduced, except in full,
without the written consent of Pace Analytical Seru¡ces, LLC.Date: 0612612O17 09:1 3 AM Page 10 of 15
@
Pace Analytical Seruices, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.paælahs.con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County
92344890
LABORATORY CONTROL SAMPLE:
Parameter
2027639
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
cis-'1,2-Dichloroethene
cis-1,3-Dichloropropene
D ib romoch lo ro metha ne
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
lrans-'t,2-D¡chloroethene
trans-1,3-Dichloropropene
trans- 1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
Yo
50
50
50
50
50
100
100
50
50
50
50
50
50
50
50
50
50
100
50
'150
460
49.4
499
46.2
48.9
109
967
38.8
50.3
51.0
47.0
48.9
45.6
49.5
51.2
47.9
47.2
948
536
'147
74-124
72-132
7B-125
82-120
79-121
39-1 54
B1-'t24
64-1 33
79-131
84-',t26
78-122
80-121
7',t-127
69-141
40-160
78-122
53-1 37
40-1 60
5B-137
81-126
70-1 30
70-1 30
70-130
92
99
100
92
9B
109
97
78
101
102
94
98
91
99
't02
96
94
95
107
98
94
103
97
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027640
Parameter
92344890001Un¡ts Result
MS
Spike
Conc.
MSD
Spike
Conc.
2027641
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
'1,'1,1,2-Telr achloroeth ane
1 ,1 ,1 -Trichloroethane
1,1,2,2-1et achloroethane
1, 1,2-Trichloroethane
1 ,l -Dichloroethane
1 ,1 -Dichloroethene
1,2, 3-Trichloropropane
'1,2-Dibromo-3-chloropropa ne
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
'1 ,2-Dichloroethane
'1 ,2-D¡chloropropane
1 ,4-D¡chlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
20
20
20
20
20
20
20
20
20
20
20
20
20
40
40
40
40
22.8
22.'l
22.4
21 4
240
235
234
17.9
23.5
23.5
21.2
229
23.5
35.0
37.3
367
43.8
20.3
23.9
18.1
23.7
239
25.1
18 6
20.5
20.5
24.5
20.9
23 1
236
375
34.7
402
43.1
114
11'l
112
't07
120
118
1',t7
89
117
1',t7
106
115
't1B
88
93
92
109
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
20
20
20
20
20
20
20
20
20
20
20
20
20
40
40
40
40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
102
119
91
118
119
125
93
102
103
122
105
115
118
94
87
100
108
70-l 30
70-1 30
70-l 30
70-1 30
70-1 30
70-1 66
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-'t30
70-1 30
70-1 30
70-1 30
70-130
11
I
21
't0
0
6
23
14
14
4
1
1
1
7
7
I
I
Results presented on th¡s page are in the un¡ts ind¡cated by the "Un¡ts" column except where an altemate un¡t ¡s presented to the rlght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Serv¡ces, LLCDale: 0612612017 09:1 3 AM Page I1 of15
@
Pace Analytical Senrices, LLC
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Huntersv¡lle, NC 28078
[phone]
Analytical
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QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County
92344890
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2027640
Parameter
92344890001
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
202764'l
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon telrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
c¡s-1,3-D¡chloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-'1,2-Dichloroethene
trans-1,3-D¡chloropropene
trans-1,4-Dichloro-2-butene
Trichloroelhene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
100
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
40
20
20
20
20
20
20
20
20
20
20
40
20
100
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
40
20
20
20
20
20
20
20
20
20
20
40
20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
o/o
%
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
257
22.4
22.3
't8.7
27.2
26.6
23.O
246
23 1
23.5
21 4
23.8
21 4
19.8
22.O
24-9
40.0
49.5
20.4
247
25.0
24.1
22.9
24.O
19.0
15.4
22.9
23-7
33.1
232
103
24.O
22.3
20.5
158
279
26.7
23.3
22.9
2'1.3
234
22.2
24-2
2',t.6
16.8
20.6
230
473
45.8
21.O
2't.2
19.9
19.4
22-6
24.6
21 .3
14.6
242
225
32.8
23.5
103
128
112
111
93
136
133
115
123
116
117
't07
119
107
99
110
124
100
124
102
124
't25
't20
115
120
95
77
't14
119
83
1'16
94
108
96
103
120
112
103
79
140
133
116
115
107
1't7
111
't21
108
84
103
115
118
1',t4
105
106
99
97
't13
'123
't07
73
12'l
112
82
1',t7
92
85
93
70-1 30
70-',!48
70-1 30
70-130
70-130
70-1 30
70-130
70-130
70-146
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-'t 30
70-1 30
70-130
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-'t55
70-1 30
70-130
70-1 30
69-151
70-l 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
0
6
0
8
17
2M1
0M1
1
7
I
0
3
2
1
16
6
8
17
B
3
15
23
21
2
3
't1
5
6
5
1
1
Results presented on th¡s page are ln the unlts lnd¡cated by the "l,Jn¡ts" column except where an alternate unlt is presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Seruices, LLCDale: 061261201 7 09:1 3 AM Page 12 of 15
@
Pace Analytical Serv¡ces, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
(704)875-90e2
Analytical
www.pacÊlabs com
QUALIFIERS
Project:
Pace Project No
Cleveland County
92344890
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentrat¡on above the adjusted method detection l¡mit and below the adjusted reporting limit.
MDL - Adjusted Melhod Detection Limit.
PQL - Practical Quant¡tation Lim¡t.
RL - Reporting Limit.
S - Surrogale
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA gu¡delines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Dupl¡cate)
MS(D) - Matr¡x Sp¡ke (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - lndicates the compound was analyzed for, but not detecled
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyle is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC lnst¡tute.
LABORATORIES
PASI-A Pace Analytical Serv¡ces - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
1g Sample prepared at dilution due to insufficent sample volume.
D3 Sample was diluted due to the presence of high levels of non-target analytes or other matrix ¡nterference.
M1 Malrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytiæl Seruices, LLCDale: O612612017 09: 1 3 AM Page 13 of 15
@
Pace Analytical Services, LLC
9800 K¡nceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analyttcal
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Cleveland County
92344890
Lab lD Sample lD QC Batch Method QG Batch Analytical Method
Analytical
Batch
92344890001
923,14890001
923¡14890001
LWS-1
LWS-,I
LWS-I
EPA 301OA
EPA 301OA
EPA 8260
365721
365737
365738
EPA 601O
EPA 6020B
365989
366282
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Services, LLCDate: 0612612017 09:13 AM Page 14 of 15
tjl
PaceAnalytÌcal
M.p¡.r¡¡ùr.con
CHAIN-OF-CUSTODY / Analytical Request Document
The Chain'ofcuslody is ã LÉGAL DOCUMENT Àll relcvanl nclds musl ba æmpleled accu€lely.
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F.ALL-O-020rev 07, t
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
(704)875-e092
Analytical
www.pac:êlabs.clñ
June 26,2017
Ayla Homer
Shield
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project: Cleveland County Leachate
Pace Project No.: 92345286
DearAyla Homer:
Enclosed are the analytical results for sample(s) received by the laboratory on June 22,2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless othen¡¡ise noted in the body of the report.
lf you have any questions concerning this report, please feel free to contact me.
Sincerely,
4ltcc(t j,J*ua.*-'/*
Nicole Gasiorowski
nicole. [e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. James Gamertsfelder, Shield Engineering
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Serv¡ces, LLC Page 1 of 18
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9800 Kincey Ave Su¡te 1 00
Huntersville, NC 28078
(704)875-s0e2
Analytical
www.pacalabs.com
CERT¡FICATIONS
Project:
Pace Project No.
Cleveland County Leachate
92345286
Charlotte Certification lDs
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #:5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: Ê87 627
Kentucky UST Certification #: 84
VirginiatuELAP Certificat¡on #'. 460221
REPORT OF LABORATORY ANALYSIS
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Analytical
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Cleveland County Leachate
92345286
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
9234528600't LS-13
92345286002 LS-'t4
92345286003 LS-r5
EPA 8260
ASTM D2974.87
EPA 8260
ASTM D2974.87
EPA 8260
ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Serv¡ces, LLC
DLK
CLW
DLK
CLW
DLK
CLW
52
'l
52
1
52
1
PASI-C
PASI-C
PASI-C
PASI-C
PASt-C
PASt-C
Page 3 of l8
o
Pace Analyt¡cal Seru¡ces, LLC
9800 KinceyAve Suite 100
Huntersv¡lle. NC 28078
[phone]
Analytical
ww.pacÊlabs con
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County Leachate
92345286
Sample: LS-13 Lab lD: 92345286001 Collected: 06122117 09:50 Received: 06122117 12:33 Matrix: Solid
Resurfs reported on a "dry weight" basis and are adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochlorometha ne
Bromod ichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ib rom och loro metha ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
I ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 ,1 -Dichloroethane
I ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroelhene
I ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1, 1,',l,2-Tetrachloroethane
1, 1,2,2-felr achlo roeth a n e
Tetrachloroethene
Toluene
1 ,1 , 1-Trichloroethane
',l, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uorometha ne
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Analytical Method: EPA 8260
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
114
114
57
5.7
5.7
5.7
11 .4
114
11.4
5.7
5.7
11 4
5.7
11.4
5.7
5.7
5-7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
56.9
11.4
22.8
56.9
57
5.7
5.7
5.7
5.7
5.7
5.7
57
57
5-7
56.9
11.4
06123117 13:02
06123117 13:02
06123117 13:02
06123117 1302
06123117 13:02
O6123117'13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123117'13i02
O6l23h7 13t02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
O6l23h7 13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
06123h7'13t02
06123117 13i02
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
O6l23h713i02
06123117'l3ig2
06123117 13:02
06123117 13:02
06123117 13:02
06123117 13:02
O6123117 13:02
O6123117'13:02
06t23t't7 13.02
06123117 13:02
06123117 13:02
06123117 13:02
O6123117'13:02
06123117'13:02
06123117 13:02
06123117 13:02
06123117 13:02
67-64-1
107-13-'l
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
106-46-7
110-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
1 0061-01-5
1 0061 -02-6
100-41-4
591 -78-6
74-88-4
75-09-2
108-'1 0-1
100-42-5
630-20-6
79-34-5
127-18-4
I 08-88-3
71-55-6
79-00-5
79-01 -6
75-69-4
96-1 8-4
1 08-05-4
75-01-4
L1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Seruices, LLCDale: 0612612017 08:39 PM Page 4 of 18
@
Pace Analytical Sedices, LLC
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
[phone]
Analytical
ww.pacÊlabs com
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County Leachate
Sample: LS-13 Lab lD: 92345286001 Collected: 06122117 O9:5O Received: 06122117 12:33 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Un¡ts Report Limit DF Prepared Analyzed CAS No.
Analytical Method: EPA 8260
92345286
Qual
8260/50354 Volatile Organics
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
ug/kg
ug/kg
ug/kg
Analytical Method: ASTM D2974-87
21.8 %
ND
ND
ND
't| -4
1't.4
57
103
't02
89
70-1 30
70-1 30
70-132
06123117 13:02 133O-2O-7
06123117 13:02 179601 -23-1
06123117 13:02 95-47-6
06123117'13:02 2O37-26-5
06123117 13:02 460-00-4
06123117 13:02 17060-07-0
06123117 O8:22
To
To
o/o
010 1
REPORT OF LABORATORY ANALYSIS
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w¡thout the wr¡tten consent of Pace Analytical Services, LLCDale: 0612612017 08:39 PM Page 5 of 18
o
Pace Analytical Services, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs æm
ANALYTICAL RESULTS
Project:
Pace Project No.
Cleveland County Leachate
92345286
Sample: LS-14 Lab lD: 92345286002 Collected: 06122117 09:35 Received: 06122117 12i33 Matrix: Solid
Resu/fs reported on a "dry weight" basis and are adjusted for percent mo¡sture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
8260/50354 Volatile Organics
Acetone
Acrylonitrile
Benzene
Bromochlorometha ne
Bromodichlorometha ne
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dib rom och lo romethan e
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
I ,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
'l ,1 -Dichloroethane
1 ,2-Dichloroethane
I ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (M IBK)
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-feIr achlo roeth a ne
Tetrachloroethene
Toluene
1 ,'1 , '1 -Trichloroethane
'1,'1,2-Trichloroethane
Trichloroelhene
Trichlorofl uorometha ne
1,2,3-Trichloropropane
Vlnyl acetate
Vinyl chloride
Analytical Method: EPA 8260
105
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
BB.7
BB.7
4.4
4.4
4.4
4.4
8.9
887
8.9
4.4
4.4
8.9
4.4
8.9
4.4
4-4
4.4
44
4.4
4.4
4.4
44
44
4.4
4.4
4.4
4-4
4.4
4.4
4.4
44.3
8.9
17.7
44.3
44
44
4.4
4.4
44
4.4
4.4
4.4
4.4
4.4
443
8.9
06123117 13:22
06123117 13:22
O6123117 13:22
06123117 13:22
061231'17 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06t23t17 13.22
O6123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
0612311713:22
O6123117 13:22
06123117 13:22
06123117 13:22
06t23t17 13.22
06123117 13:22
06123117 13:22
O6123117 13:22
06123117 13:22
O6123117 13:22
06123117 13:22
06123117 13:22
06123h713:22
O6123117 13:22
06123117 13:22
061231'17 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06t23t17 13.22
06t23117 13.22
06123117 13:22
06123117 13:22
06123117 13:22
06123117 13:22
06t23t17 13'.22
06123117 13.22
06123117 13:22
67-64-1
107-13-1
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-1 5-0
56-23-5
I 0B-90-7
75-00-3
67-66-3
74-87-3
96-12-B
124-48-1
I 06-93-4
74-95-3
95-50-1
1 06-46-7
110-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
I 0061 -01 -5
1 0061 -02-6
100-41-4
59 t-78-6
74-88-4
75-09-2
I 0B-10-"1
100-42-5
630-20-6
79-34-5
127-18-4
I 08-88-3
7't-55-6
79-00-5
79-01 -6
75-69-4
96-1 8-4
1 08-05-4
75-O1-4
L1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seru¡ces, LLCDale: 0612612017 08:39 PM Page 6 of 18
o
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
ww.pacelahs.con
ANALYTICAL RESULTS
Project:
Pace Project No
Cleveland County Leachate
92345286
Sample: LS-14 Lab lD: 92345286002 Collected: 061221'17 09:35 Received: 06122117 12:33 Matrix: Solid
Resu/fs repoñed on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.Qual
8260/50354 Volatile Organics
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogaúes
Toluene-d8 (S)
4-Bromofl uorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Analytical Method: EPA 8260
ug/kg
ug/kg
ug/kg
101 Yo100 %
93 To
Analyt¡cal Method: ASTM D2974-87
24.3 %
89
89
44
ND
ND
ND
061231 17 13:22 1330-20-7
061231'17'13:22 17960'l-23-1
061231'17 13:22 95-47-6
06123117 13:22 2037 -26-5
06123117 13:22 460-00-4
06123117 13:22 17060-07-0
061231'17 08:22
70-'130
70-1 30
70-132
0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLC.Dale: 0612612017 08:39 PM Page 7 of 18
Analytical
Pace Analyt¡cal Services, LLC
9800 KinceyAve Su¡te 100
Huntersv¡lle, NC 28078
[phone]www.pacÊlabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
Cleveland County Leachate
92345286
Sample: LS-15 Lab lD: 92345286003 Collected: O6122117 1O:15 Received: 06122117 12:33 Matrix: Solid
Resurfs reporied on a "dry weight" basis and are adjusted lor percent moisture, sample size and any d¡lutions.
Parameters Results Units Report Lim¡t DF Prepared Analyzed CAS No Qual
8260/50354 Volatile Organics Analytical Method: EPA 8260
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromod¡chlorometha ne
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfìde
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
D ibrom och loro meth a ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,4-Dichlorobenzene
trans- 1,4-Dichloro-2-butene
1 ,1-Dichloroethane
1 ,2-Dichloroethane
I ,'l -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-"1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (Ml BK)
Styrene
1 ,1 ,1 ,2-Tetrachloroetha ne
1,1,2,2-felr achl oroeth a ne
Telrachloroethene
Toluene
1,1, 1 -Trichloroethane
'1,1,2-Trichloroethane
Trichloroelhene
Trichlorofl uoromethane
1,2,3-Trichloropropane
V¡nyl acetate
Vinyl chloride
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
104
104
52
52
5.2
5.2
10.4
104
10.4
52
5.2
'to 4
5.2
10.4
5.2
5.2
52
5.2
52
5.2
5.2
5.2
5-2
5.2
5.2
5.2
5.2
5.2
5.2
5.2
52.1
10.4
208
52.1
5.2
5.2
5.2
5.2
5.2
5.2
5.2
5.2
52
5.2
52.1
10.4
06123117 13143
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123/17 13:43
o6t23t't7 't3'.43
06123117 13:43
06123117 13:43
06123117 13:43
06123h7 13:43
06123117 13:43
06123117 13:43
06123117 13:43
O6123117'13:43
O6123117 13:43
O6123117 13:43
06123117 13:43
06123h7 13:43
06123117 13:43
06123117 13:43
O6123117 13:43
06123117 13:43
06123117'13:43
061231'1713:43
O6123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
O6123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
o6t23t17 13'.43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
06123117 13:43
67-64-1
't07-13-'l
71-43-2
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
75-15-0
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
96-12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
1 06-46-7
1 1 0-57-6
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
7B-87-5
1 0061 -01 -5
't 0061-02-6
100-41-4
591 -78-6
74-88-4
75-09-2
1 08-1 0-1
100-42-5
630-20-6
79-34-5
't27-18-4
1 0B-88-3
7't-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
1 0B-05-4
75-O1-4
L1
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seruices, LLCDate: 0612612017 08:39 PM Page 8 of 18
o
Pace Analytical Services, LLC
9800 K¡nceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pac:þlabs.con
ANALYTIGAL RESULTS
Project:
Pace Project No
Cleveland County Leachate
92345286
Sample: LS-15 Lab lD: 92345286003 Collected: 06122117 10:'15 Received: 06122117 12:33 Matrix: Solid
Resurfs reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
Analytical Method: EPA 8260
Qual
8260/50354 Volatile Organics
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogafes
Toluene-dB (S)
4-Bromofl uorobenzene (S)
1,2-D¡chloroethane-d4 (S)
Percent Moisture
Percent Moisture
Analytical Method: ASTM D2974-87
21.4 o/o
ND
ND
ND
ug/kg
ug/kg
ug/kg
10-4
10.4
5.2
06123117 13:43 1330-2O-7
06123117 13i43 17960'l-23-1
06123117 13:43 95-47-6
06123117 13:43 2037-26-5
06123Í17 13:43 460-00-4
06123117'13:43 17060-07-0
06123117 08:22
102
101
85
Yo
o/o
Yo
70-1 30
70-1 30
70-132
0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the writlen consent of Pace Analyt¡cal Seruices, LLC.Dale: 0612612017 08:39 PM Page I of 18
o
Pace Analyt¡cal Seruices, LLC
9800 Kincey Ave Su¡te .100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs com
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County Leachate
92345286
QC Batch: 366258 Analysis Method:
QC Batch Method: EPA 8260 Analysis Description
Associated Lab Samples: 92345286001, 92345286002, 92345286003
EPA 8260
8260 MSV 5035A Volatile Organics
METHOD BLANK: 2030269 Matr¡x:
Associated Lab samples: 92345286001, 92345286002, 92345286003
Blank
Parameter Units Result
Sol¡d
Reporting
Limit Analyzed Qualifiers
1,1,1,2-Telr achloroeth ane
1, 1, 1 -Trichloroethane
'' ,'' ,2,2-lelr achlo roetha ne
'1, 1,2-Trichloroethane
1 , 1-Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromod ich lorometh a ne
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis- 1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.7
5.7
5.7
5.7
57
5.7
5.7
5.7
5.7
5.7
57
57
5.7
114
56.9
56.9
'114
114
5.7
5.7
5.7
5-7
11.4
11.4
5.7
5.7
11.4
5.7
't1.4
57
5.7
5.7
5.7
5.7
11 .4
11.4
22.8
5.7
57
5.7
5.7
06123117 1O:59
06123117 1O:59
06123117 1O:59
06123117 1O:59
06123117 10:59
06123117 1O:59
O6123l'17 10:59
06123l'17 1O:59
O6123117 1O:59
06123117 1O:59
06123117 10:59
06123117'10:59
O6123117 10:59
06123117 10:59
061231'17 10:59
06123117 1O:59
06123117 1O:59
06123117'10:59
06123117 1O:59
O6123l'17 10:59
061231'17 10:59
O6123117 10:59
0612311710:59
06123117'10:59
06123117'lO:59
O6123117 1O:59
06123117 10:59
061231'17 10:59
06123/17 10:59
06123117 10:59
06123117'lO:59
06123117 10:59
O6123117 10:59
O6123l'17 10:59
06123117 10:59
O6123117 10:59
06123117 1O:59
06123117'lO:59
06123117 1O:59
06t23t17 10'59
O6123117 10:59
Results presented on th¡s page are ¡n the unlts lndlcated by the "Un¡ts" column except where an altemate unit is presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 06126120'17 08:39 PM Page 10 of 1B
@
Pace Analyt¡cal Seryices, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacelabs.ctn
QUALITY CONTROL DATA
Project:
Pace Project No
Cleveland County Leachate
92345286
METHOD BLANK: 2030269 Matrix: Solid
Associated Lab Samples: 92345286001, 92345286002, 92345286003
Blank ReportingParameter Units Result Limit Analyzed Qualifiers
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
ND
ND
ND
ND
ND
ND
ND
ND
90
102
103
5.7
5.7
5.7
5.7
5.7
56.9
11.4
11.4
70-132
70-1 30
70-1 30
06123117 1O:59
06123117'lO:59
06123117 10:59
06123117 10:59
O6123117 10:59
06123117 10:59
O6123117 10:59
O6123117 10:59
06123117 1O:59
06123117 10:59
06123117 1O:59
LABORATORY CONTROL SAMPLE:
Parameler
2030270
Units
Spike
Conc.
LCS
Result
LCS
7o Rec
% Rec
Limits Qualifìers
'1, 1, 1,2-Tetrachloroethane
1, 1, 1 -Trichloroethane
1,1,2,2-Telr achloroethane
1,'1,2-Trichloroethane
I ,1 -D¡chloroethane
1 ,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
I ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (M I BK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
57.1
57 -1
57.1
57.'l
57.'l
57 1
57.1
57.1
57.1
57.1
57.'l
57.1
57.1
114
114
114
't14
285
57.1
57.1
57.1
57 1
57.1
57.1
57.1
57.1
57.1
57 -1
57.'l
56.7
49.6
53.9
53.9
50.7
52.7
56.4
59.1
60.5
57.4
50.0
54.3
55.8
111 J
123
115
115
270
52.2
53.6
552
54.5
52.7
47.8
51.5
55.4
500
5't.8
493
99
87
94
94
89
92
99
104
106
'101
88
95
98
97
107
101
101
95
91
94
97
95
92
84
90
97
88
91
86
74-137
67-140
72-141
7B-1 38
69-1 34
67-1 38
69-144
65-140
77-135
77-'t41
65-1 37
72-136
76-1 38
58-147
62-145
64-149
53-1 53
56-'153
73-1 35
73-134
71-135
66-141
53-1 60
63-140
60-'145
78-1 30
64-149
70-',134
52-'t50
Results presented on th¡s page are ¡n the units ind¡cated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
Thìs report sha¡l not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seruices, LLCDale: 0612612017 08:39 PM Page 11 of 18
@
Pace Analytical Seruices, LLC
9800 Kincey Ave Suite I 00
Huntersville, NC 28078
[phone]
Analytical
wwvpacÊlabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.
Cleveland County Leachate
92345286
LABORATORY CONTROL SAMPLE:
Parameter
2030270
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chlor¡de
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
lrans-1,3-Dichloropropene
trans-1,4-Dichloro-2-bulene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
%
%
57.'l
57.1
57.1
57.1
57.1
114
114
57.1
57.'l
57 1
57.1
57.1
57.1
57.'l
57.',|
57.'l
57.1
114
57.1
171
52.3
57.0
569
54.2
536
102
106
48.2
53.0
54.0
49.0
51 9
506
56.8
76.7
54.8
52.8
71.2
48.0
159
92
100
100
95
94
90
93
84
93
95
B6
91
B9
99
134
96
93
62
84
93
100
99
97
70-133
68-1 34
71-138
74-130
75-l 33
69-144
75-1 36
45-154
76-',I41
79-137
7't-138
74-131
67-1 35
65-1 46
70-130 L1
67-'t 35
59-',!44
40-1 60
56-141
76-137
70-132
70-1 30
70-1 30
MATRIX SPIKE SAMPLE:
Parameter
203't151
Units
923445960',t4
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifiers
MS
1, 1, 1,2-Tetrachloroethane
1 ,1 ,1 -Trichloroelhane
1,1,2,2-fet achloroeth ane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (Ml BK)
Acetone
Acrylonitrile
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.9
17.9
17.9
17.9
17.9
'17.9
17.9
17.9
17.9
179
17.9
17.9
17.9
35.7
35.7
357
atl
16.6
18.2
17.7
16.8
166
16.3
99
17.2
17.6
't5.7
16.4
16.7
.16 I
37.8J
34.8J
34.2J
29.7J
85.8J
93
102
99
94
93
9'1
55
96
98
88
92
94
90
106
97
96
83
70-130
70-130
70-1 30
70-1 30
70-1 30
49-1 B0
70-130 M't
70-1 30
70-1 30
70-130
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
70-1 30
Results presented on th¡s page are ¡n the un¡ts indicated by the "Units" column except where an alternate un¡t ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analyt¡cal Services, LLCDale: 0612612017 08:39 PM Page 12 of 18
@
Pace Analyt¡cal Serv¡ces, LLC
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
(704)87s-9092
Analytical
www.pacÊlabs com
QUALITY CONTROL DATA
Project:
Pace Project No :
Cleveland County Leachate
92345286
MATRIX SPIKE SAMPLE:
Parameter
2031151
Unils
92344596014
Result
Spike
Conc.Result
MS
% Rec
% Rec
Limits Qualifiers
MS
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
17.9
17.9
17.9
17.9
17.9
50-166
70-1 30
70-130
70-130
70-1 30
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ugikg
ugikg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Yo
Yo
%
17 -0
18.4
17.1
13.6
16.2
13.9
18.2
16.3
13.4
18.2
12.9
't6.7
18.1
164
15.8
15.7
25.2
30.2
1 3.1J
't4-4
't2.6
14.4
16.5
tb.b
170
203
16.6
15.6
13J
't3.4
70-1 30
43-169
70-1 30
70-1 30
70-1 30
70-1 30
70-'t30
70-130
70-130
70-130
70-1 30
70-1 30
70-130
70-1 30
70-1 30
52-163
70-'t30
70-130
49-167
70-1 30
70-130 M1
70-1 30
70-132
70-1 30
70-1 30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.9
'17.9
17.9
17.9
17.9
179
17.9
17.9
17.9
17.9
ND
ND
ND
ND
ND
ND
ND
ND
35.7
17.9
17.9
17.9
17.9
'17.9
't7.9
't7.9
95
103
96
76
90
101
91
75
102
72
93
01
92
88
BB
84
/J
8,1
70
80
92
93
95
ND
ND
ND
ND
'17.9
17.9
357
17.9
93
87
Jb
75
'114
103
104
SAMPLE DUPLICATE: 2031'150
Parameter
923445960'13
Result
Dup
Units Result RPD Qualifiers
1 ,1 ,1 ,2-felrachloroethane
I , 1 ,1-Trichloroethane
1,1,2,2-Telrachloroethane
1, 1,2-Tr¡chloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
'l,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Results presented on this page are in the un¡ts ¡nd¡cated by the "Un¡ts" column except where an alternate un¡t is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDatet 0612612017 08:39 PM Page l3 of 18
6
Pace Analytical Serv¡ces, LLC
9800 K¡ncey Ave Suite '100
Hunlersville, NC 28078
(704)875-s092
Analytical
www.pacÊlabs.cffi
QUALITY CONTROL DATA
Project:
Pace Project No.:
Cleveland County Leachate
92345286
SAMPLE DUPLICATE: 2031150
Parameter
9234459601 3
Result
Dup
Units Result RPD Qualifiers
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1 ,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (M IBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromod ichlorometh a ne
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-',l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
m&p-Xylene
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans- 1,2-Dichloroethene
trans-'1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Trichloroethene
Trichlorofl uoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
u9/kg
ug/kg
ug/kg
%
o/o
To
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
106
100
'105
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
87
9B
102
'15
2
2
Results presented on thls page are ¡n the un¡ts ¡nd¡cated by the "Units" column except where an alternate un¡t is presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDate: 0612612017 08:39 PM Page 14 of 18
Analytrcal
Pace Analyt¡cal Services, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
(7041875-9092www.pacÊlabs con
QUALITY CONTROL DATA
Project:
Pace Projecl No
Cleveland County Leachate
92345286
QC Batch: 366113 Analysis Method:
QC Batch Method: ASTM D2974-87 Analysis Description:
Associaled Lab Samples: 92345286001, 92345286002, 92345286003
ASTM D2974-87
Dry WeighVPercent Moisture
SAMPLE DUPLICATE: 2029575
Parameter
3531 7371 001
Result
Dup
Units Result RPD Qualifiers
Percent Moisture Yo 27.3 25.7 6
SAMPLE DUPLICATE: 2029576
Parameter
92345287003
Result
Dup
Units Result RPD Qualifìers
Percent Moisture o/o 16.9 16.8
Results presented on thls page are ¡n the un¡ts lndlcated by the "Unlts" column except where an alternate unit is presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLCDale: 0612612017 08:39 PM Page 15 of 18
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacêlabs.æn
QUALIFIERS
Project:
Pace Project No.:
Cleveland County Leachate
92345286
DEFINITIONS
DF - D¡lution Factor, if reported, represents the factor applied to the reporled data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concenlration above the adjusted method detection l¡mit and below the adjusted reporting limit
MDL - Adjusted Method Detect¡on Limit.
PQL - Pract¡cal Quantitation Limit.
RL - Reporting Limit
S - Surrogate
1,2-Diphenylhydraz¡ne decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a comb¡ned concentralion.
Consistentwith EPAguidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - lnd¡cates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical ¡s TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC lnstitute.
LABORATORIES
PASI-C Pace Analytical Serv¡ces - Charlotte
ANALYTE QUALIFIERS
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, LLC.Dale: 0612612017 08:39 PM Page 16 of 'tB
@
Pace Analyt¡cal Seruices, LLC
9800 KinceyAve Suite 100
Huntersvìlle, NC 28078
[phone]
Analytical
www.pãt$labs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No
Cleveland County Leachate
92345286
Lab lD Sample lD QC Batch Method QC Batch Analytical Method
Analytical
Batch
92345286001
92345286002
92345286003
92345286001
92345286002
92345286003
LS-13
LS-14
LS-í5
LS-13
LS-,I4
LS-15
EPA 8260
EPA B260
EPA 8260
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
366258
366258
366258
36611 3
36611 3
36611 3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
w¡thout the wr¡tten consent of Pace Analytical Serv¡ces, LLCDale: O612612017 08:39 PM Page 17 of 18
t:l
PaceAnalvticalm.¡¡cá¡¡s.con
CHAIN-OF-CUSTODY / Analytical Request Document
The Châin.ol-Cuslody is a LEGAL OOCUIVIENT All relovant lìèlds must be coñpleted âccuraloly
Sectlon A
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