4903_IredellCoMSWLF_July2016GWMR_DIN28363_20161121

Iredell County Subtitle D Lined MSWLF, Phases 3 & 4
Statesville, North Carolina
July 2016
Permit Number: 49-03
Semi-Annual Water Quality Monitoring Report
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
MESCO Project Number: G16014.0
P.O. Box 97
Garner, NC 27529
License No. C-0281

TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedure Page 1
Field Parameter Data Page 2
Laboratory Results Page 2
Quality Control Samples Page 2
Groundwater Samples Page 2
Surface Water Samples Page 2
Leachate Samples Page 2
Groundwater and Surface Water Characterization Page 3
Findings Page 3
Closing Page 4
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer Figure 2

TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Detections Above SWSL, GWP, 2L, or 2B (Appendix 1) Table 5
Detections in Leachate Samples above SWSL, GWP or 2L Table 6
Hydrologic Properties at Monitoring Well Locations Table 7
Total Metals Concentrations Evaluation Table Table 8
APPENDICIES
Laboratory Analysis Reports and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
November 29, 2016
Mr. Ervin Lane
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality (DEQ)
217 West Jones Street
Raleigh, NC 27603
Re: Semi-Annual Water Quality Monitoring Report
Iredell County Subtitle D Lined MSWLF, Phases 3 & 4
Permit No. 49-03
MESCO Project No. G16014.0
Event Date(s): July 13, 2016 & Verification October 19, 2016
Dear Mr. Lane,
Introduction
On behalf of Iredell County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this
Semi-Annual Water Quality Report for an event performed at the Iredell County Subtitle D Lined Municipal
Solid Waste Landfill (MSWLF), Phases 3 & 4. The semi-annual event was performed on July 13, 2016 and
verification metal samples were collected from MW-27D and MW-29 on October 19, 2016. NCDEQ Solid Waste
Rules 15A NCAC 13B.1632 requires that Iredell County document the groundwater, surface water and leachate
quality to the SWS on a semi-annual basis.
Laboratory analytical results indicate that vinyl chloride and tetrachloroethene were detected in excess of the NC
groundwater 2L Standard and the Solids Waste Section Limit (SWSL) in sample MW-21S. One or more total metal
was also detected above groundwater Standards in every sample except for MW-21D and MW-27S. The region
monitored by MW-21S has undergone voluntary remediation via landfill gas extraction and the horizontal extent has
been delineated since the last semi-annual report. Contaminants continue to be absent from any surface water
samples. The concentrations of contaminants in the untreated leachate remain low relative to Standards and
published values.
Background
The Iredell County Subtitle D lined MSWLF, permit #49-03, is located at 354 Twin Oaks Road, Statesville, North
Carolina. The site location topographic map is depicted in the attached Figure 1. The lined MSWLF is comprised
of contiguous Phase 3 (inactive) & Phase 4 (active) which are treated as a single unit in this report.

Water quality at this facility has been monitored at least semi-annually since prior to operation in 2002 with all
historical data available and reviewed in support of this report. This event was performed in accordance with the NC
SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS issued
memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water
characterization. Detections compared to Standards tables, a groundwater flow directions/rates table, a field
observations table, a field data results table, potentiometric map, quality assurance/quality control data, and
laboratory analytical data results are also enclosed.
Sampling Procedure
MESCO performed the sampling in general accordance with the SWS approved Ground and Surface Water Sampling
and Analysis Plan contained in the Hydrogeologic Design Study revised on May 8, 2007. Groundwater sample
collection for this event included ten downgradient groundwater monitoring wells (MW-18, MW-19SR, MW-19D,
MW-21S, MW-21D, MW-27S, MW-27D, MW-28, MW-29 and MW-30), one background well (MW-17), and one
leachate sample (FORCEMAIN). The unnamed tributary of Fourth Creek, which serves as the local discharge feature
between both distinct units (Phases 3&4 and Phases 1&2) was monitored at two locations (SW-1 and SW-5). Quality
control measures were implemented during this event, including submittal and subsequent blank quantification,
equipment blank (EB), field blank (FB). Monitoring locations are shown on the potentiometric map (Figure 2).
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and
integrity of all monitoring locations were visually evaluated with no deficiencies observed as documented on Table 2.
The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation.
Low-flow pumping methodology or bailing was utilized to purge the wells to a minimum of three times the volume
of standing water in the well or until dry. Surface water samples were collected from previously designated locations.
The leachate sample was taken directly from the Phase 3 forcemain (FORCEMAIN) which originates from both
Phases 3 & 4. During well purging and surface water sample collection the required field parameters were recorded.
The samples were then placed into laboratory-prepared, pre-preserved containers via a new disposable polyethylene
bailer. Samples were collected, kept on ice, and transported to a NC-certified laboratory under proper chain of
custody (C-O-C) protocols within the specified hold times for each analysis.
Field Parameter Data
Stabilized field parameters were recorded during purging which included static water depth, pH, specific
conductance, temperature and visual turbidity. A summary of the field parameter data is presented in Table 3 and the
field sampling data sheet is enclosed in Appendix B.
Laboratory Results
Pace Analytical Laboratory (PACE) of Huntersville and Asheville, NC performed the laboratory analysis on the
groundwater and surface water samples for the total form of constituents listed in 40 CFR 258 Appendix I.
Verification samples were collected from MW-27D and MW-29 on October 19, 2016 and tested for Appendix I
metals. A raw leachate sample was analyzed for the required leachate specific list, which includes Appendix I,
nitrate, phosphorus, chemical oxygen demand (COD), biological oxygen demand (BOD), and sulfate. A sampling
and analysis table summarizing the locations, targeted constituents, and methods is presented on Table 4. Laboratory
results and C-O-Cs are presented in Appendix A.
2
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below
the current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and
surface water samples that attain or were above the current SWSL, Groundwater Protection Standards (GWP), North
Carolina Groundwater Standards (2L) or the Federal “Drinking Water Standard” Maximum Contaminant Level
(MCL).
Quality Control Samples
The quality control sample EB and FB contained methylene chloride and was flagged by the laboratory as
“C9” which is defined as “common laboratory contaminant”. Since methylene chloride was not detected in any other
sample, the data set appears to be unaffected by false positives or high bias attributed to the identified laboratory
induced artifact contamination.
Groundwater Samples
At least one total metal was detected in excess of their respective groundwater Standard in every groundwater sample
except for MW-21D and MW-27S. Total metals detected above their respective groundwater Standard during the
July event included MW-18 (Cr, Va), MW-19D (Cd, Va), MW-21S (Va), MW-27D (Cd, Va, Sb), MW-28 (Cr, Va),
MW-29 (Pb, Cr, Be, Va), MW-30 (Cr, Va) and background well MW-17 (Cr, Va). The only metal detected above
groundwater Standards during the verification event performed in October 2016 was a “j-qualified” concentration of
total vanadium in MW-29. However, supplemental analysis indicated that dissolved vanadium was not detected in
sample MW-29.
Sample collected from MW-21S contained vinyl chloride at 1.1 uq/L and tetrachloroethene 0.89 ug/L which were
above their respective 2L Standards of 0.03 ug/L and 0.7 ug/L.
Surfacewater Samples
No constituents were detected above the applicable 2B Standard in the surface water samples.
Leachate Samples
The leachate sample (FORCEMAIN) contained quantifiable concentrations of seven total metals and three VOCs as
listed in Table 6. Tetrachlroethene, contaminant detected in MW-21S, has never been detected in any leachate
sample collected from the forcemain.
Groundwater and Surface Water Characterization
MESCO prepared a potentiometric map from groundwater elevation data for the uppermost aquifer recorded during
this event (Figure 2). Groundwater flow rates and directions were calculated and are included on Table 7.
Groundwater flows in a general northeasterly direction towards the unnamed tributary of Fourth Creek, which serves
as the local discharge feature. Groundwater flow rates ranged from approximately 3 feet/year (MW-21S) to 113
feet/year (MW-28) averaging about 50 feet/year. The flow directions and gradients are generally consistent with
historically reported observations. Streams located within the facility boundaries were visually observed to have low
seasonal volume and flow with low turbidity.
Findings
The detections of total metals are not believed to have originated from an anthropogenic source rather a product of
erosion of natural deposits. All concentrations of metals that were found above a Standard were below the highest
levels identified in the facility background wells and above the all time highest observed level in the leachate after
applying a 20:1 dilution mixing factor (Table 8). An Alternative Source Demonstration (ASD) addressing the
inorganic detections is planned to be submitted prior to the February 6, 2017 deadline.
3
Figures
Closed C&D
Lined MSWLF
34 21
C&D
Closed Unlined MSWLF
STATESVILLE
Topographic Map with Site Location
Iredell County Landfill
Figure 102.5 2.5 MILES
STATESVILLE EAST QUADRANGLE
N
354 Twin Oaks Rd
Statesville, NC 28625
Lat:35-46-17.8012
Long:-80-49-22.2973
Northing:740719.35
Easting:1459306.76
UNLINED AREA
MW-1B
MW-7 MW-8
MW-4B
MW-3B
MH #2
MH #3
MH #4
MH #5
MH #6
MH #1
SCALES
FOURTH CREEK TRIBUTARY-UNNAMED
FOURTH CREEK TRIBUTARY-UNNAMED
FOURTH CREEK TRIBUTARY-UNNAMED
MW-6B
MW-6A
P-4
FOURTH CREEK TRIBUTARY-UNNAMED
T
W
I
N
O
A
K
S
R
O
A
D
S.
R
.

2
3
1
9
MW-21S
MW-17
MW-15
MW-14B
MW-11
SW-4
SW-3
SW-2
SW-5
MW-21D
MW-13B
MW-14A
SW-2
P2-10D
P2-10S
P2-19
MW-24S
MW-23
MW-22
MW-24D
P4-7S
MW-28
MW-29
790.44
MW-16
MW-9RR
MW-1C
MW-18
FORCEMAIN
MW-15D
MW-25
SW-6
MW-27D*
P4-7D
TWIN OAKS GOLF COURSE
OWNED BY IREDELL COUNTY
SW-SofConfluence
FIGURE 2
790.44*
SHOP
P2-1S
PZ-1S
801.78
807.16
817.65
817.61
789.74
782.13
795.41
778.62
775.16
773.38
776.18*
778.18
787.02
784.62
87.01
783.17
787.99
798.19
812.59
780.10
842.64
840.67
792.37
798.22
787.27 788.28
811.79
<794.88
<846.93
MW-20
PZ-1S
MW-30
791.07
807.04*
795.40*
790.81*
811.96*
778.62*
790.17
PZ-1D*
P5-1
786.86*
MW-10R
798.54
MW-27S795.40
MW-19D
MW-19SR
SW-1
MW-2
MW-4A
MW-9R
DRY
FOURTH CREEK
MW-13BR
SW-NEofMW-16
MW-12
MW-26S
MW-26D
819.03
824.73*
CD3-11M
LINED MSWLF
PHASE 1
INACTIVE
LINED MSWLF
PHASE 2
INACTIVE
PTO 9/28/98
CHIPPINGS
AND
MULCHING
AREA
C&D
PHASE 1
CLOSED
C&D
PHASE 2
CLOSED
C&D
PHASE 3
CLOSED
FOURTH CREEK TRIBUTARY-UNNAMED
LINED MSWLF PHASE 5
MW-35P-77
P5-4
P5-2S
P5-7
P5-13
P5-6
MW-34
P5-15S
P5-15D
P5-19
P5-20
MW-33S
MW-33D
P5-2D
P5-3
P5-8
P5-9SP5-9D
MW-32
POND
GCCS
GENERATOR
AREA
UNLINED
UNLINED
UNLINED
ACTIVE
GCCS
ACTIVE
GCCS
ACTIVE
GCCS
ACTIVE
GCCS
781.36
LINED MSWLF
PHASE 4
INACTIVE
PTO 7/30/08
ACTIVE PTO 11/18/14
MW-37
MW-36S
852.54
858.61
854.96
845.34
841.92 847.08
849.20
P-83
P-86
P-85
847.37
857.45
MW-36D
853.71*
DRY<792.84
DRY
779.96*
779.95*
MW-1A
842.49*
GMP-3A
GMP-3A
TRIBUTARY-UNNAMED
TW-A SOIL SAMPLE
LINED MSWLF
PHASE 3
INACTIVE
PTO 7/26/02
July 13, 2016
WELL ID
15A NCAC 2L Groundwater Quality Standard 0.03 0.7
MW-17 854.35 36.74 817.61
MW-18 800.72 8.35 792.37
MW-19SR 797.26 9.99 787.27
MW-19D*795.81 8.95 786.86
MW-21S 823.97 34.23 789.74 1.2 0.89 (j)
MW-21D*822.76 31.95 790.81
MW-27S 808.00 12.60 795.40
MW-27D*806.95 11.55 795.40
MW-28 810.17 8.39 801.78
MW-29 809.06 10.84 798.22
MW-30 797.91 7.74 790.17
P-4 839.25 21.60 817.65 NS NS
P4-7S 818.47 11.43 807.04 NS NS
P4-7D*819.00 11.84 807.16 NS NS
* = Wells not used for groundwater contouring
NS = Not Sampled since not required
M ³M´4XDOLILHGFRQFHQWUDWLRQ6:6/FRQVLGHUHGDQHVWLPDWH
Groundwater Levels & VOCs Detected Above 2L Standards
TOP OF
CASING
ELEVATION
(FT AMSL)
DEPTH TO
WATER (FT
BTOC)
GROUNDWATER
POTENTIOMETRIC
ELEVATION
(FT AMSL)
Vinyl
Chloride
(UG/L)
PCE
(UG/L)
MW-21S
Tetrachloroethene - 0.89 (j) ug/l
Vinyl Chloride - 1.1 ug/l
Tables
Iredell County Subtitle D Lined MSWLF, Phases 3 & 4 Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
July 13, 2016
Latitude Longitude
(inches)(ft)
MW-17 5/9/02 2 45.00 30.00 15 Soil 854.35 850.94 817.61 36.74 35.7717 -80.8367
MW-18 6/2/00 2 20.00 5.00 15 Soil 800.72 796.09 792.37 8.35 35.7685 -80.8345
MW-19SR 6/30/06 2 22.02 7.02 15 Sandy Silt 797.26 794.54 787.27 9.99 35.7698 -80.8327
MW-19D 5/9/02 2 59.00 49.00 10 Rock 795.81 793.26 786.86 8.95 35.7685 -80.8345
MW-21S 6/2/00 2 41.00 26.00 15 Silt 823.97 821.03 789.74 34.23 35.7714 -80.8327
MW-21D 6/17/00 2 138.25 128.25 10 Rock 822.76 819.25 790.81 31.95 35.7714 -80.8327
MW-27S 1/3/05 2 20.09 5.09 15 Sandy Silt 808.00 803.90 795.40 12.60 35.7684 -80.8357
MW-27D 1/3/05 2 44.42 39.42 5 Silty Sand 806.95 804.69 795.40 11.55 35.7684 -80.8357
MW-28 12/27/04 2 12.42 7.42 5 Sandy Silt 810.17 807.49 801.78 8.39 35.7691 -80.8380
MW-29 12/27/04 2 17.68 7.68 10 Silty Sand 809.06 806.49 798.22 10.84 35.7687 -80.8372
MW-30 12/14/10 2 17.40 6.40 11 Silt 797.91 794.91 790.17 7.74 35.7689 -80.8333
NOTE:
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen
Length Geology of
Screened
Interval
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
bgs = below ground surface
amsl= above mean sea level
btoc = below top of casing (PVC well casing)
Iredell County Subtitle D MSWLF, Phase 3 & 4 Page 1 of 1
Table 2
Field Observations of Monitoring Locations
July 13, 2016
Locked Comments
MW-17 Yes Yes Yes Yes Yes Yes
MW-18 Yes Yes Yes Yes Yes Yes
MW-19SR Yes Yes Yes Yes Yes Yes
MW-19D Yes Yes Yes Yes Yes Yes
MW-21S Yes Yes Yes Yes Yes Yes
MW-21D Yes Yes Yes Yes Yes Yes
MW-27S Yes Yes Yes Yes Yes Yes Repaired by MESCO in June 2014
MW-27D Yes Yes Yes Yes Yes Yes
MW-28 Yes Yes Yes Yes Yes Yes
MW-29 Yes Yes Yes Yes Yes Yes
MW-30 Yes Yes Yes Yes Yes Yes
SW-1 Yes
SW-2 Yes
SW-5 Yes
P4-7S Yes Yes Yes Yes Yes Yes
P4-7D Yes Yes Yes Yes Yes Yes
P-4 Yes Yes Yes Yes Yes Yes
FORCEMAIN Yes Sample from valve as typical
Any unusual field conditions, observations, or events:
MW-27S repaired by MESCO in June 2014 after being bumped by mower.
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete Surface
Pad Effective
na na na na na
na na na na na
na na na na na
na na na na na
na = not available or applicable
MW-27S top of PVC elevation changed to 808.00 amsl was 807.25 amsl. Elevation determined in field by string level pulled from MW-27D.
Table 3
Summary of Field Parameter Data
Location Water
Depth
Water
Elevation
TOC
Elevation Temperature ORP DO pH Specific
Conductance TDS
Turbidity
of Metal
Sample
Units ft (btoc)ft (amsl)ft (amsl) C mV mg/L SU цs/cm ppt visual
MW-17 36.74 817.61 854.35 17.4 NR NR 7.0 22 NR Clear
MW-18 8.35 792.37 800.72 16.0 NR NR 6.1 72 NR Clear
MW-19SR 9.99 787.27 797.26 18.0 NR NR 6.6 516 NR Clear
MW-19D 8.95 786.86 795.81 16.8 NR NR 7.2 79 NR Clear
MW-21S 34.23 789.74 823.97 17.5 NR NR 5.6 50 NR Clear
MW-21D 31.95 790.81 822.76 19.1 NR NR 10.1 116 NR Clear
MW-27S 12.60 795.40 808.00 17.0 NR NR 5.6 176 NR Clear
MW-27D 11.55 795.40 806.95 15.9 NR NR 6.0 161 NR Clear
MW-28 8.39 801.78 810.17 17.2 NR NR 6.8 107 NR Clear
MW-29 10.84 798.22 809.06 16.7 NR NR 5.6 69 NR Clear
MW-30 7.74 790.17 797.91 15.7 NR NR 6.6 79 NR Clear
Minimum 7.74 786.86 795.81 15.7 NR NR 5.6 22 NR Clear
Average 16.48 795.06 811.54 17.0 NR NR 6.7 132 NR Clear
Maximum 36.74 817.61 854.35 19.1 NR NR 10.1 516 NR Clear
SW-1 ---23.3 NR NR 7.19 133 NR Clear
SW-2 ---24.6 NR NR 6.93 137 NR Clear
SW-5 ---23.5 NR NR 7.21 161 NR Clear
Minimum ---23.3 NR NR 6.93 133 NR Clear
Average ---23.8 NR NR 7.11 144 NR Clear
Maximum ---24.6 NR NR 7.21 161 NR Clear
July 13, 2016
Iredell County Subtitle D MSWLF, Phase 3 4 Page 1 of 1
Iredell County Subtitle D Lined MSWLF, Phases 3 & 4 Page 1 of 1
Table 4
Sampling and Analysis Summary
July 13, 2016
October 19, 2016 (verification event for metals)
App. I Field Parameter
T o t a l M e t a l s
D i s s o l v e d M e t a l s
T e m p e r a t u r e
C o n d u c t i v i t y
T o t a l D i s s o l v e d S o l i d s (T D S )
p H T u r b i d i t y
S u l f a t e
p H P h o s p h o r u s
B O D , 5 d a y
C O D
N i t r a t e
L a b E P A 8 2 6 0 B
L a b E P A 6 0 0 0 /7 0 0 0
L a b E P A 6 0 0 0 /7 0 0 0
F i e l d M e t e r
F i e l d M e t e r
F i e l d M e t e r
F i e l d M e t e r
F i e l d V i s u a l
L a b A S T M D 5 1 6 -9 0
L a b S M 4 5 0 0 -H /B
L a b E P A 3 6 5 .4
L a b S M 5 2 1 0 B
L a b S M 5 2 2 0 D
L a b E P A 3 5 3 .2
MW-17 x x x x x x x
MW-18 x x x x x x x
MW-19SR x x x x x x x
MW-19D x x x x x x x
MW-21S x x x x x x x
MW-21D x x x x x x x
MW-27S x x x x x x x
MW-27D x V x x x x x
MW-28 x x x x x x x
MW-29 x V V x x x x x
MW-30 x x x x x x x
SW-1 x x x x x x x
SW-2 x x x x x x x
SW-5 x x x x x x x
FORCEMAIN x x x x x x x x
EB x x
FB x x
TB x
App I = Appendix I List from current 40 CFR 258
Leachate
V O C s
V = Verification resampled on October 19, 2016
Iredell County Subtitle D MSWLF, Phase 3 4 Page 1 of 2
Table 5
July 13, 2016
October 19, 2016 (Metals verification at MW-27D and MW-29)
Result Unit
MW-17 Zinc, total 7/13/16 27.2 5 10 1000 NE
MW-17 Chromium, total 7/13/16 11.8 2.5 10 10 100 N (is BG)
MW-17 Vanadium, total 7/13/16 14.7J 2.5 25 NE 3.5 NE N (is BG)
MW-18 Chromium, total 7/13/16 10.2 2.5 10 10 100 N (<BL<BG>L)
MW-18 Vanadium, total 7/13/16 10.3J 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-19D Zinc, total 7/13/16 18 5 10 1000 NE
MW-19D Cadmium, total 7/13/16 3 0.5 1 2 5 N (<BG>L)
MW-19D Vanadium, total 7/13/16 3.7J 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-19SR Barium, total 7/13/16 125 2.5 100 700 1300
MW-19SR Vanadium, total 7/13/16 16.7J 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-21D Cadmium, total 7/13/16 1.2 0.5 1 2 5
MW-21S Zinc, total 7/13/16 19.6 5 10 1000 NE
MW-21S Barium, total 7/13/16 161 2.5 100 700 1300
MW-21S Vinyl chloride 7/13/16 1.1 0.62 1 0.03 2 L &/or LFG
MW-21S 7/13/16 0.89J 0.46 1 0.7 5 L &/or LFG
MW-21S Vanadium, total 7/13/16 11.5J 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-21S Cobalt, total 7/13/16 11.6 2.5 10 NE 70 NE N (<BL<BG>L)
MW-27D Zinc, total 7/13/16 22.7 5 10 1000 NE
MW-27D Zinc, total 10/19/16 ND<5 5 10 1000 NE
MW-27D Cadmium, total 7/13/16 3.1 0.5 1 2 5 N (<BL<BG>L)
MW-27D Cadmium, total 10/19/16 ND<0.5 0.5 1 2 5
MW-27D Vanadium, total 7/13/16 10.6J 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-27D Vanadium, total 10/19/16 2.8J 2.5 25 NE 3.5 NE
MW-27D Antimony, total 7/13/16 6 3.8 6 NE 1.4 6 N (>L) & ND verification
MW-27D Antimony, total 10/19/16 ND<3.8 3.8 6 NE 1.4 6
MW-28 Zinc, total 7/13/16 35.4 5 10 1000 NE
MW-28 Barium, total 7/13/16 101 2.5 100 700 1300
MW-28 Chromium, total 7/13/16 13.1 2.5 10 10 100 N (<BL<BG>L)
MW-28 Beryllium, total 7/13/16 1.5 0.5 1 NE 4 4
MW-28 Cobalt, total 7/13/16 17.6 2.5 10 NE 70 NE N
MW-28 Vanadium, total 7/13/16 37.9 2.5 25 NE 3.5 NE N (<BL<BG>L)
Detections in Water Samples above SWSL, GWP, 2L or MCL (Appendix I)
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 Preliminary Cause 7
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Tetrachloroethene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Iredell County Subtitle D MSWLF, Phase 3 4 Page 2 of 2
Result UnitSample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 Preliminary Cause 7
MW-29 Barium, total 7/13/16 162 2.5 100 700 1300
MW-29 Barium,total 10/19/16 38.5 2.5 100 700 1300
MW-29 Barium, Dissolved 10/19/16 18.9 2.5 100 700 1300
MW-29 Lead, total 7/13/16 20 2.5 10 15 15 N (<BG>L)
MW-29 Lead,total 10/19/16 2.5 2.5 10 15 15
MW-29 Lead, dissolved 10/19/16 ND<2.5 2.5 10 15 15
MW-29 Chromium, total 7/13/16 23.5 2.5 10 10 100 N (<BG>L)
MW-29 Chromium,total 10/19/16 6.6 2.5 10 10 100
MW-29 Chromium,total 10/19/16 ND<2.5 2.5 10 10 100
MW-29 Chromium, Dissolved 10/19/16 2.5J 2.5 10 10 100
MW-29 Beryllium, total 7/13/16 4.3 0.5 1 NE 4 4 N (<BG>L)
MW-29 Beryllium,total 10/19/16 1.1 0.5 1 NE 4 4
MW-29 Beryllium, Dissolved 10/19/16 0.41 0.01 1 NE 4 4
MW-29 Vanadium, total 7/13/16 44.1 2.5 25 NE 3.5 NE N (<BL<BG>L)
MW-29 Vanadium,total 10/19/16 7.6J 2.5 25 NE 3.5 NE N (<BL<BG>L) & ND Dissolved
MW-29 Vanadium,dissolved 10/19/16 ND<2.5 2.5 25 NE 3.5 NE
MW-29 Zinc, total 7/13/16 62 5 10 1000 NE
MW-29 Zinc,total 10/19/16 10.8 5 10 1000 NE
MW-29 Zinc, Dissolved 10/19/16 ND<5 5 10 1000 NE
MW-30 Copper, total 7/13/16 16.4 2.5 10 1000 NE
MW-30 Zinc, total 7/13/16 23.1 5 10 1000 NE
MW-30 Chromium, total 7/13/16 21.7 2.5 10 10 100 N (<BL<BG>L)
MW-30 Vanadium, total 7/13/16 38 2.5 25 NE 3.5 NE N (<BL<BG>L)
EB 7/20/16 1.3C9 0.97 1 4.6 5
FB 7/20/16 1C9 0.97 1 4.6 5
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions
j =The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
<BG = Below the highest level ever observed in the background well
LFG = Landfill Gas
BOLD = Concentration > 2L, GWP or MCL Standard
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Methylene Chloride ug/L
Methylene Chloride ug/L
1 Table contains Appendix I constituents detected above SWSL, 2L, GWP or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 GWP = Groundwater Protection Standard
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
7 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L Standard.
<BL = Below it's own BaseLine level established by the highest of the first 4 initial events within the first six months of operation.
>L = Above the highest ever observed in leachate after a 20:1 dilution factor.
L = Leachate
Iredell County Subtitle D MSWLF, Phase 3 & 4 Page 1 of 1
Table 6
July 13, 2016
Sample ID Result Unit
FORCEMAIN 7/13/16 15.5 0.3 1 550 700 274
FORCEMAIN 7/13/16 16.1 0.66 5 530 1000 141
FORCEMAIN 7/13/16 1.2 0.33 1 6 75 13.2
FORCEMAIN Benzene 7/13/16 7.4 0.25 1 1 5 221
FORCEMAIN Nickel, total 7/13/16 106 2.5 50 100 NE 325.5
FORCEMAIN Chromium, total 7/13/16 28.1 2.5 10 10 100 175.4
FORCEMAIN Vanadium, total 7/13/16 18.8J 2.5 25 NE 3.5 NE 17.9
FORCEMAIN Antimony, total 7/13/16 12.1 3.8 6 NE 1.4 6 4520
FORCEMAIN Barium, total 7/13/16 945 2.5 100 700 1300 850
FORCEMAIN Zinc, total 7/13/16 29.9 5 10 1000 NE 8320
FORCEMAIN Copper, total 7/13/16 77.3 2.5 10 1000 NE 168
1 Table contains only constituents detected at or above SWSL, 2L, 2B, GWP or MCL
adjusted for actual sample preparation data and moisture content, where applicable.
NE = Not Established
BOLD =
Detections in Leachate Sample Above SWSL, GWP, 2L or MCL
Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 “Average Leachate” 7
Ethylbenzene ug/L
Xylene (Total)ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit (Current as of Sampling Event)
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard (Current as of Sampling Event)
5 GWP = Groundwater Protection Standard (Current as of Sampling Event)
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
7 Average concentration of leachate from a comparable “Dry Tomb” Landfill published in 1988 by EPA document Summary of Data on MSWLF Leachate Characteristics
J =The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
Concentration > 2L, GWP, MCL or “Average Leachate”
Iredell County Subtitle D MSWLF, Phase 3 & 4 Page 1 of 1
Table 7
July 13, 2016
(cm/sec)(%)(ft/ft)(ft/yr)
MW-17 3.73E-05 21.7 0.023 4 S68E 36.74 817.61 Silt
MW-18 7.43E-04 21.7 0.018 65 S48E 8.35 792.37 Silt
MW-19SR 4.54E-04 21.7 0.022 47 S67E 9.99 787.27 Sandy Silt
MW-19D 2.81E-03 21.7 n/a n/a n/a 8.95 786.86 Fractured Rock
MW-21S 1.67E-05 21.7 0.043 3 S83E 34.23 789.74
MW-21D 9.08E-07 21.7 n/a n/a n/a 31.95 790.81 Fractured Rock
MW-27S 5.62E-04 17.0 0.018 60 S15E 12.60 795.40 Silty Sand
MW-27D 4.67E-04 6.0 n/a n/a n/a 11.55 795.40 Clayey Sand
MW-28 1.52E-03 17.0 0.012 113 S09W 8.39 801.78 Silty Sand
MW-29 7.70E-04 17.0 0.018 85 S06E 10.84 798.22 Silty Sand
MW-30 2.66E-03 21.7 0.002 24 S53E 7.74 790.17 Silt
Minimum 9.08E-07 6.0 0.002 3 -7.74 786.86 -
Average 9.13E-04 19.0 0.020 50 -16.48 795.06 -
Maximum 2.81E-03 21.7 0.043 113 -36.74 817.61 -
NOTE:Values for hydraulic conductivity previously determined via slug test by MESCO.
Wells screened in rock or deeper cluster counterparts not utilized for flow directions/gradients.
Hydraulic Conductivity value for MW-19SR assumed identical to previously adjacent MW-19S.
K = hydraulic conductivity
Hydrologic Properties at Monitoring Well Locations
Monitoring
Well Hydraulic
Conductivity
Effective
Porosity
Hydraulic
Gradient
Average
Linear
Velocity
Rate
Flow
Direction
Depth to
Groundwater
Groundwater
Potentiometric
Elevation
Screened
Interval
Lithology
(ft btoc)(ft amsl)
Saprolite
Hydrologic Gradient calculated from groundwater elevations recorded on July 13, 2016.
Average linear velocity rate (Q) is defined by modified Darcy's equation:
ne = effective porosity
dh = head difference
dl = horizontal distance
Q=−K
ne
⋅dh
dl
Table 8
Total Metal Concentrations Evaluation Table
Iredell Co. Subtitle D Lined MSWLF, Phases 1&2, 3&4 and 5
Total Metal An
t
i
m
o
n
y
Ar
s
e
n
i
c
Ba
r
i
u
m
Be
r
y
l
l
i
u
m
Ca
d
m
i
u
m
Ch
r
o
m
i
u
m
Co
b
a
l
t
Co
p
p
e
r
Le
a
d
Nic
k
e
l
Se
l
e
n
i
u
m
Si
l
v
e
r
Th
a
l
l
i
u
m
Va
n
a
d
i
u
m
Zi
n
c
SWSL 6 10 100 1 1 10 10 10 10 50 10 10 5.5 25 10
2L/GWP STANDARD
SAMPLE ID
Screened
Lithology Data Period
MW-1A (BG Well)Bedrock All Time High ND 6.5 560 12 48 37 44 130 34 21.7 ND ND 1 610 350
MW-1B (BG Well)Regolith All Time High ND 7 690 6 23 140 32 88 92 ND ND ND 1 420 290
MW-1C (BG Well)Regolith All Time High ND ND 702 4.7 1.7 23.8 21.4 88.4 11 14.5 ND ND 0.13 226 288
MW-17 (BG Well)Regolith All Time High 0.238 3.69 285 1.5 1.2 51.8 14.6 37 15 41 ND 0.12 0.122 69 528
MW-37 (BG Well)Regolith All Time High <5 <5 199 <1 12.5 6.2 7.4 13.1 15 <5 <10 <5 <5.4 33.1 38.4
ALL BG WELLS COMBINED All Time High 0.24 7 702 12 48 140 44 130 92 21.7 ND 0.1 1 610 350
MW-2 Regolith Max Baseline <5 <5 1120 17 <2 123 88 39 72 87 <5 <5 <1 381 443
MW-3A Regolith Max Baseline <5 <5 602 12 <2 103 35 <10 44 19 <5 <5 <1 314 595
MW-3B Regolith Max Baseline <5 <5 154 3 <2 46 17 27 13 10 <5 <5 <1 65 112
MW-4A Regolith Max Baseline <5 6 496 4 <2 128 41 140 30 87 <5 <5 <1 253 233
MW-4B Bedrock Max Baseline <5 <5 750 4 <2 118 44 200 27 <10 <5 <5 <1 280 239
MW-5 Regolith Max Baseline <5 <5 1880 10 1 353 160 <10 29 350 <5 <5 <1 860 1140
MW-6A Regolith Max Baseline <5 <5 110 3 <2 29 10 <10 11 <10 <5 <5 <1 64 74
MW-6B Regolith Max Baseline <5 <5 976 6 <2 124 23 66 34 49 <5 <5 <1 155 230
MW-7 Regolith Max Baseline <5 16 1990 6 <2 327 110 340 211 120 <5 <5 <1 660 640
MW-8 Regolith Max Baseline <5 <5 1040 6 <2 163 130 130 21 33 <5 <5 1 240 300
MW-9 Regolith Max Baseline <5 7 2730 16 <2 155 200 450 88 60 <5 <5 <1 1070 1290
MW-10 Regolith Max Baseline <5 <5 1130 3 1 29 20 <10 51 <10 <5 <5 <1 300 260
MW-11 Regolith Max Baseline <5 12 1100 13 2 98 79 170 55 55 <5 <5 <1 810 650
MW-12 Regolith Max Baseline <5 34 12000 120 1.6 1500 430 700 460 800 <5 <5 <1 3900 2800
MW-13A Regolith Max Baseline <5 5 1000 110 <1 270 68 54 39 170 <5 <5 2 530 490
MW-13B/MW-13BR Regolith Max Baseline <5 13 8700 130 1 680 260 24 280 340 <5 <5 9.2 2100 1600
MW-14A Regolith Max Baseline <5 390 4 <1 <1 76 24 13 16 <10 <5 <5 <1 190 180
MW-14B Regolith Max Baseline <5 38 8700 130 2.1 1500 240 <10 400 550 <5 <5 11 2800 1600
MW-15/MW-15D Regolith Max Baseline <5 47 2900 120 2 2100 930 1600 160 820 <5 7 6.2 2800 1750
MW-17 Regolith Max Baseline <5 <5 160.1.1 <1 7.3 <5 26.9.1 24.<5 <2 <2 43 99.
MW-18 Regolith Max Baseline <5 12 2300 25 3.2 1000 300 1200 140 470 <5 <2 <2 1100 900.
MW-19S/MW-19SR Regolith Max Baseline 9.6 110 3600 40 110 780 300 600.150 320 <5 4.4.7 1100 1300
MW-19D Regolith Max Baseline <5 <5 60.<1 <1 5.7 <5 4.9 <5 <5 <5 <2 <2 5.5 27.
MW-20/MW-30 Regolith Max Baseline <5 12 600.10 3 480 160 620.88 210 <5 <2 <2 560 410.
MW-21S Regolith Max Baseline 5.7 7.4 920 8.4 1.6 170 34.96.51 65.<5 <2 <2 200 260.
MW-21D Regolith Max Baseline 8.4 16 60.<1 6.7 4.9 <5 10.<5 9.9 <5 <2 <2 6 66.
MW-27S Regolith Max Baseline <5 <5 <5 <1 <1 <5 <2 11.9 <5 <5 <5 <2 <1 7.1 <10
MW-27D Bedrock Max Baseline <5 <5 <5 <1 <1 <5 <2 27.2 17 <5 <5 <2 <1 33.8 58.4
MW-28 Regolith Max Baseline <5 <5 282 <1 4.8 21.5 <2 53.4 19 <5 <5 <2 0.731 144 172.
MW-29 Regolith Max Baseline <5 <5 <5 1.7 <1 <5 <2 <2 10 <5 <5 <2 <1 18.6 34.6
FORCEMAIN (LEACHATE)-All Time High 38.2 18 1010 4.9 8 160 150 370 86 157 5 0.3 7.37 250 16000
FORCEMAIN Diluted -All Time High D 1.91 0.9 50.5 0.245 0.4 8 7.5 18.5 4.3 7.85 0.25 0.02 0.369 12.5 800
MW-25 Regolith Max Baseline <4 7.8 831 3.3 <1 31.2 26.8 69.4 20 20.7 <10 <5 0.277 150 323
MW-31 Regolith Max Baseline <5 <5 151 1.3 1.9 5.7 14.9 23.5 7.7 9.7 <10 <5 <5.4 35.5 33.4
MW-32 Regolith Max Baseline <5 <5 358 1.2 4.9 10.7 25.6 21 9.4 10.6 <10 <5 <5.4 51.3 58.8
MW-33S Regolith Max Baseline <5 <5 141 1.2 11.3 <5 8.5 13.6 <5 7.3 <10 <5 <5.4 18.4 23.4
MW-33D Bedrock Max Baseline <5 <5 94.5 <1 3.2 10.4 15.2 10.3 <5 <5 <10 <5 <5.4 26 25.3
MW-34 Regolith Max Baseline <5 <5 271 1.6 3.9 8.9 16.6 30 6.3 17.9 <10 <5 <5.4 48.2 42
MW-35 Regolith Max Baseline 5.2 5.2 307 3.3 2.2 <5 8.9 6.9 16 <5 <10 5.2 <5.4 27.2 62.3
MW-36S Regolith Max Baseline <5 <5 164 1.5 <1 5.6 16.3 7.1 6.4 <5 <10 <5 <5.4 28 24.8
MW-36D Bedrock Max Baseline <5 <5 <5 <1 5.2 <5 <5 <5 <5 <5 <10 <5 <5.4 6.5 <10
LAGOON (LEACHATE)-All Time High 18.7 21.8 1300 ND 11 76.4 100 7.7 16 111 9.5 2 27 25.8 4600
LAGOON Diluted -All Time High D 0.9 1.1 65.0 ND 0.6 3.8 5.0 0.4 0.8 5.6 0.5 0.1 1.35 1.3 230.0
Table contains concentrations of Appendix I metals
All Time High = Highest ever recorded at either the upgradient backgound well or untreated leachate sample. Samples consistantly collected on a semi-annual basis. This value will be kept current.
Diluted D = Extrapolated concentration when untreated leachate is mixed with groundwater. A 20:1 dilution ratio (dividing by 20) is the EPA's default dilution attenuation factor (DAF) and the SLSP Method basis
When two wells shown together indicates wells that have been replaced so data used for both wells
RED BOLD =
PHASES 3&4 CONTIGUOUS (PHASE 3 BASELINE 2002) (PHASE 4 BASELINE 2008)
20
(BG Well) = Background Well Located hydraulically upgradient of Waste Unit
GWP = Groundwater Protection Standard (Current as of 10/6/16)
SWSL = Solid Waste Section Reporting Limit
< = Not Detected with Detection Limit Indicated
UNTREATED LEACHATE (EFFECTIVELY A COMPOSITE OF PHASES 1-5) RESULTS FROM 1996 - 2016
70 10001.4 1004 20210
PHASES 1&2 CONTIGUOUS (PHASE 1 BASELINE 1993) (PHASE 2 BASELINE 1998)
10 700
PHASES 5 (PHASE 5 BASELINE 2014)
Max Baseline = Maximum concentration detected during the first four events performed within 6 months of commencement of landfill operations including at least 1 before opening. Considered natural intrawell background levels.
2L = North Carolina 15A NCAC 2L Groundwater Quality Standard (Current as of 10/6/16)
Concentration Exceeded 2L or GWP Standard
0.28 3.5 1000
BACKGROUND WELLS PHASES 1-5
15
Iredell Co. Subtitle D Landfill Page 1 of 1
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
July 29, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92305246
92305246
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
IREDELL LINED 3&4
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on July 14, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 50
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 50
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Lab ID Sample ID Matrix Date Collected Date Received
92305246001 MW-17 Water 07/13/16 15:22 07/14/16 09:05
92305246002 MW-18 Water 07/13/16 16:10 07/14/16 09:05
92305246003 MW-19SR Water 07/13/16 16:22 07/14/16 09:05
92305246004 MW-19D Water 07/13/16 16:29 07/14/16 09:05
92305246005 MW-21S Water 07/13/16 16:47 07/14/16 09:05
92305246006 MW-21D Water 07/13/16 16:42 07/14/16 09:05
92305246007 MW-27S Water 07/13/16 16:05 07/14/16 09:05
92305246008 MW-27D Water 07/13/16 16:00 07/14/16 09:05
92305246009 MW-28 Water 07/13/16 15:42 07/14/16 09:05
92305246010 MW-29 Water 07/13/16 15:51 07/14/16 09:05
92305246011 MW-30 Water 07/13/16 16:15 07/14/16 09:05
92305246012 FORCEMAIN Water 07/13/16 16:35 07/14/16 09:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 50
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92305246001 MW-17 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246002 MW-18 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246003 MW-19SR EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246004 MW-19D EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246005 MW-21S EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246006 MW-21D EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246007 MW-27S EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246008 MW-27D EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246009 MW-28 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246010 MW-29 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246011 MW-30 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92305246012 FORCEMAIN EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
SM 5210B 1 PASI-ACJH1
EPA 9040 1 PASI-AKDF1
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-AWRC
EPA 365.1 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-17 Lab ID:92305246001 Collected:07/13/16 15:22 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 12:59 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 12:59 7440-38-207/18/16 20:2010.0 2.5 1
Barium 81.3J ug/L 07/20/16 12:59 7440-39-307/18/16 20:201002.5 1
Beryllium 0.66J ug/L 07/20/16 12:59 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 12:59 7440-43-907/18/16 20:201.0 0.50 1
Chromium 11.8 ug/L 07/20/16 12:59 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 4.5J ug/L 07/20/16 12:59 7440-48-407/18/16 20:2010.0 2.5 1
Copper 9.1J ug/L 07/20/16 12:59 7440-50-807/18/16 20:2010.0 2.5 1
Lead 3.0J ug/L 07/20/16 12:59 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 8.1J ug/L 07/20/16 12:59 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 12:59 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 12:59 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 12:59 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 14.7J ug/L 07/20/16 12:59 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 27.2 ug/L 07/20/16 12:59 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 17:53 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 17:53 107-13-12001.9 1
Benzene ND ug/L 07/15/16 17:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 17:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 17:53 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 17:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 17:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 17:53 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 17:53 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 17:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 17:53 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 17:53 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 17:53 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 17:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 17:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 17:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 17:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 17:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 17:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 17:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 17:53 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 17:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 17:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 17:53 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 17:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 17:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 17:53 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 17:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 17:53 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
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Page 5 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-17 Lab ID:92305246001 Collected:07/13/16 15:22 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 17:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 17:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 17:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 17:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 17:53 108-10-11000.33 1
Styrene ND ug/L 07/15/16 17:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 17:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 17:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 17:53 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 17:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 17:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 17:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 17:53 79-01-61.0 0.47 1
Trichlorofluoromethane 0.61J ug/L 07/15/16 17:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 17:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 17:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 17:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 17:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %07/15/16 17:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)85 %07/15/16 17:53 17060-07-070-130 1
Toluene-d8 (S)103 %07/15/16 17:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-18 Lab ID:92305246002 Collected:07/13/16 16:10 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:12 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:12 7440-38-207/18/16 20:2010.0 2.5 1
Barium 35.2J ug/L 07/20/16 13:12 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:12 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:12 7440-43-907/18/16 20:201.0 0.50 1
Chromium 10.2 ug/L 07/20/16 13:12 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt ND ug/L 07/20/16 13:12 7440-48-407/18/16 20:2010.0 2.5 1
Copper 7.2J ug/L 07/20/16 13:12 7440-50-807/18/16 20:2010.0 2.5 1
Lead ND ug/L 07/20/16 13:12 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 4.0J ug/L 07/20/16 13:12 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:12 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:12 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:12 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 10.3J ug/L 07/20/16 13:12 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 8.9J ug/L 07/20/16 13:12 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 18:10 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 18:10 107-13-12001.9 1
Benzene ND ug/L 07/15/16 18:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 18:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 18:10 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 18:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 18:10 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 18:10 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 18:10 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 18:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 18:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 18:10 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 18:10 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 18:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 18:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 18:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 18:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 18:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 18:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 18:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 18:10 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 18:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 18:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 18:10 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 18:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 18:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 18:10 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 18:10 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 18:10 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-18 Lab ID:92305246002 Collected:07/13/16 16:10 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 18:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 18:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 18:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 18:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 18:10 108-10-11000.33 1
Styrene ND ug/L 07/15/16 18:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 18:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 18:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 18:10 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 18:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 18:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 18:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 18:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 18:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 18:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 18:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 18:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 18:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %07/15/16 18:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)86 %07/15/16 18:10 17060-07-070-130 1
Toluene-d8 (S)101 %07/15/16 18:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-19SR Lab ID:92305246003 Collected:07/13/16 16:22 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:15 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:15 7440-38-207/18/16 20:2010.0 2.5 1
Barium 125 ug/L 07/20/16 13:15 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:15 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:15 7440-43-907/18/16 20:201.0 0.50 1
Chromium ND ug/L 07/20/16 13:15 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt ND ug/L 07/20/16 13:15 7440-48-407/18/16 20:2010.0 2.5 1
Copper 4.0J ug/L 07/20/16 13:15 7440-50-807/18/16 20:2010.0 2.5 1
Lead ND ug/L 07/20/16 13:15 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 3.3J ug/L 07/20/16 13:15 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:15 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:15 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:15 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 16.7J ug/L 07/20/16 13:15 7440-62-207/18/16 20:2025.0 2.5 1
Zinc ND ug/L 07/20/16 13:15 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 18:27 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 18:27 107-13-12001.9 1
Benzene ND ug/L 07/15/16 18:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 18:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 18:27 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 18:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 18:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 18:27 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 18:27 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 18:27 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 18:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 18:27 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 18:27 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 18:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 18:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 18:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 18:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 18:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 18:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 18:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 18:27 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 18:27 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 18:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 18:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 18:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 18:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 18:27 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 18:27 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 18:27 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-19SR Lab ID:92305246003 Collected:07/13/16 16:22 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 18:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 18:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 18:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 18:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 18:27 108-10-11000.33 1
Styrene ND ug/L 07/15/16 18:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 18:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 18:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 18:27 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 18:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 18:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 18:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 18:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 18:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 18:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 18:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 18:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 18:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %07/15/16 18:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %07/15/16 18:27 17060-07-070-130 1
Toluene-d8 (S)102 %07/15/16 18:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-19D Lab ID:92305246004 Collected:07/13/16 16:29 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:18 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:18 7440-38-207/18/16 20:2010.0 2.5 1
Barium 15.6J ug/L 07/20/16 13:18 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:18 7440-41-707/18/16 20:201.0 0.50 1
Cadmium 3.0 ug/L 07/20/16 13:18 7440-43-907/18/16 20:201.0 0.50 1
Chromium ND ug/L 07/20/16 13:18 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt ND ug/L 07/20/16 13:18 7440-48-407/18/16 20:2010.0 2.5 1
Copper 9.3J ug/L 07/20/16 13:18 7440-50-807/18/16 20:2010.0 2.5 1
Lead ND ug/L 07/20/16 13:18 7439-92-107/18/16 20:2010.0 2.5 1
Nickel ND ug/L 07/20/16 13:18 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:18 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:18 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:18 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 3.7J ug/L 07/20/16 13:18 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 18.0 ug/L 07/20/16 13:18 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 18:44 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 18:44 107-13-12001.9 1
Benzene ND ug/L 07/15/16 18:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 18:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 18:44 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 18:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 18:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 18:44 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 18:44 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 18:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 18:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 18:44 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 18:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 18:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 18:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 18:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 18:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 18:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 18:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 18:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 18:44 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 18:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 18:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 18:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 18:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 18:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 18:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 18:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 18:44 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-19D Lab ID:92305246004 Collected:07/13/16 16:29 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 18:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 18:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 18:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 18:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 18:44 108-10-11000.33 1
Styrene ND ug/L 07/15/16 18:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 18:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 18:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 18:44 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 18:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 18:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 18:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 18:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 18:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 18:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 18:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 18:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 18:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %07/15/16 18:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %07/15/16 18:44 17060-07-070-130 1
Toluene-d8 (S)100 %07/15/16 18:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-21S Lab ID:92305246005 Collected:07/13/16 16:47 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:21 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:21 7440-38-207/18/16 20:2010.0 2.5 1
Barium 161 ug/L 07/20/16 13:21 7440-39-307/18/16 20:201002.5 1
Beryllium 0.69J ug/L 07/20/16 13:21 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:21 7440-43-907/18/16 20:201.0 0.50 1
Chromium 8.9J ug/L 07/20/16 13:21 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 11.6 ug/L 07/20/16 13:21 7440-48-407/18/16 20:2010.0 2.5 1
Copper 5.1J ug/L 07/20/16 13:21 7440-50-807/18/16 20:2010.0 2.5 1
Lead ND ug/L 07/20/16 13:21 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 7.9J ug/L 07/20/16 13:21 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:21 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:21 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:21 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 11.5J ug/L 07/20/16 13:21 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 19.6 ug/L 07/20/16 13:21 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 19:01 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 19:01 107-13-12001.9 1
Benzene ND ug/L 07/15/16 19:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 19:01 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 19:01 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 19:01 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 19:01 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 19:01 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 19:01 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 19:01 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 19:01 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 19:01 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 19:01 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 19:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 19:01 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 19:01 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 19:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 19:01 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 19:01 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 19:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 19:01 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 19:01 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 19:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 19:01 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 19:01 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 19:01 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 19:01 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 19:01 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 19:01 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-21S Lab ID:92305246005 Collected:07/13/16 16:47 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 19:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 19:01 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 19:01 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 19:01 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 19:01 108-10-11000.33 1
Styrene ND ug/L 07/15/16 19:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 19:01 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 19:01 79-34-53.0 0.40 1
Tetrachloroethene 0.89J ug/L 07/15/16 19:01 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 19:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 19:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 19:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 19:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 19:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 19:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 19:01 108-05-450.0 0.35 1
Vinyl chloride 1.1 ug/L 07/15/16 19:01 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 19:01 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %07/15/16 19:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)88 %07/15/16 19:01 17060-07-070-130 1
Toluene-d8 (S)102 %07/15/16 19:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-21D Lab ID:92305246006 Collected:07/13/16 16:42 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:24 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:24 7440-38-207/18/16 20:2010.0 2.5 1
Barium 14.0J ug/L 07/20/16 13:24 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:24 7440-41-707/18/16 20:201.0 0.50 1
Cadmium 1.2 ug/L 07/20/16 13:24 7440-43-907/18/16 20:201.0 0.50 1
Chromium ND ug/L 07/20/16 13:24 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt ND ug/L 07/20/16 13:24 7440-48-407/18/16 20:2010.0 2.5 1
Copper ND ug/L 07/20/16 13:24 7440-50-807/18/16 20:2010.0 2.5 1
Lead ND ug/L 07/20/16 13:24 7439-92-107/18/16 20:2010.0 2.5 1
Nickel ND ug/L 07/20/16 13:24 7440-02-007/18/16 20:2050.0 2.5 1
Selenium 5.0J ug/L 07/20/16 13:24 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:24 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:24 7440-28-007/18/16 20:205.5 5.0 1
Vanadium ND ug/L 07/20/16 13:24 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 5.1J ug/L 07/20/16 13:24 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 19:18 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 19:18 107-13-12001.9 1
Benzene ND ug/L 07/15/16 19:18 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 19:18 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 19:18 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 19:18 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 19:18 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 19:18 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 19:18 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 19:18 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 19:18 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 19:18 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 19:18 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 19:18 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 19:18 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 19:18 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 19:18 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 19:18 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 19:18 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 19:18 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 19:18 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 19:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 19:18 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 19:18 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 19:18 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 19:18 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 19:18 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 19:18 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 19:18 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-21D Lab ID:92305246006 Collected:07/13/16 16:42 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 19:18 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 19:18 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 19:18 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 19:18 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 19:18 108-10-11000.33 1
Styrene ND ug/L 07/15/16 19:18 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 19:18 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 19:18 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 19:18 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 19:18 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 19:18 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 19:18 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 19:18 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 19:18 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 19:18 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 19:18 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 19:18 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 19:18 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %07/15/16 19:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)84 %07/15/16 19:18 17060-07-070-130 1
Toluene-d8 (S)101 %07/15/16 19:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-27S Lab ID:92305246007 Collected:07/13/16 16:05 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:27 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:27 7440-38-207/18/16 20:2010.0 2.5 1
Barium 21.6J ug/L 07/20/16 13:27 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:27 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:27 7440-43-907/18/16 20:201.0 0.50 1
Chromium ND ug/L 07/20/16 13:27 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt ND ug/L 07/20/16 13:27 7440-48-407/18/16 20:2010.0 2.5 1
Copper 3.8J ug/L 07/20/16 13:27 7440-50-807/18/16 20:2010.0 2.5 1
Lead 2.8J ug/L 07/20/16 13:27 7439-92-107/18/16 20:2010.0 2.5 1
Nickel ND ug/L 07/20/16 13:27 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:27 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:27 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:27 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 2.7J ug/L 07/20/16 13:27 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 5.5J ug/L 07/20/16 13:27 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 19:35 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 19:35 107-13-12001.9 1
Benzene ND ug/L 07/15/16 19:35 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 19:35 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 19:35 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 19:35 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 19:35 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 19:35 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 19:35 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 19:35 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 19:35 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 19:35 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 19:35 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 19:35 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 19:35 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 19:35 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 19:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 19:35 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 19:35 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 19:35 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 19:35 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 19:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 19:35 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 19:35 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 19:35 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 19:35 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 19:35 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 19:35 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 19:35 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-27S Lab ID:92305246007 Collected:07/13/16 16:05 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 19:35 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 19:35 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 19:35 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 19:35 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 19:35 108-10-11000.33 1
Styrene ND ug/L 07/15/16 19:35 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 19:35 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 19:35 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 19:35 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 19:35 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 19:35 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 19:35 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 19:35 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 19:35 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 19:35 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 19:35 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 19:35 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 19:35 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)104 %07/15/16 19:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)88 %07/15/16 19:35 17060-07-070-130 1
Toluene-d8 (S)103 %07/15/16 19:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-27D Lab ID:92305246008 Collected:07/13/16 16:00 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 6.0 ug/L 07/20/16 13:30 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:30 7440-38-207/18/16 20:2010.0 2.5 1
Barium 44.1J ug/L 07/20/16 13:30 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:30 7440-41-707/18/16 20:201.0 0.50 1
Cadmium 3.1 ug/L 07/20/16 13:30 7440-43-907/18/16 20:201.0 0.50 1
Chromium 7.7J ug/L 07/20/16 13:30 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 3.4J ug/L 07/20/16 13:30 7440-48-407/18/16 20:2010.0 2.5 1
Copper 6.5J ug/L 07/20/16 13:30 7440-50-807/18/16 20:2010.0 2.5 1
Lead 2.8J ug/L 07/20/16 13:30 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 8.3J ug/L 07/20/16 13:30 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:30 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:30 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:30 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 10.6J ug/L 07/20/16 13:30 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 22.7 ug/L 07/20/16 13:30 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 20:09 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 20:09 107-13-12001.9 1
Benzene ND ug/L 07/15/16 20:09 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 20:09 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 20:09 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 20:09 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 20:09 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 20:09 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 20:09 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 20:09 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 20:09 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 20:09 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 20:09 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 20:09 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 20:09 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 20:09 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 20:09 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 20:09 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 20:09 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 20:09 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 20:09 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 20:09 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 20:09 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 20:09 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 20:09 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 20:09 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 20:09 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 20:09 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 20:09 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-27D Lab ID:92305246008 Collected:07/13/16 16:00 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 20:09 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 20:09 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 20:09 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 20:09 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 20:09 108-10-11000.33 1
Styrene ND ug/L 07/15/16 20:09 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 20:09 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 20:09 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 20:09 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 20:09 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 20:09 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 20:09 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 20:09 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 20:09 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 20:09 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 20:09 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 20:09 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 20:09 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %07/15/16 20:09 460-00-470-130 1
1,2-Dichloroethane-d4 (S)85 %07/15/16 20:09 17060-07-070-130 1
Toluene-d8 (S)100 %07/15/16 20:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-28 Lab ID:92305246009 Collected:07/13/16 15:42 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:33 7440-36-007/18/16 20:206.0 3.8 1
Arsenic 4.8J ug/L 07/20/16 13:33 7440-38-207/18/16 20:2010.0 2.5 1
Barium 101 ug/L 07/20/16 13:33 7440-39-307/18/16 20:201002.5 1
Beryllium 1.5 ug/L 07/20/16 13:33 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:33 7440-43-907/18/16 20:201.0 0.50 1
Chromium 13.1 ug/L 07/20/16 13:33 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 17.6 ug/L 07/20/16 13:33 7440-48-407/18/16 20:2010.0 2.5 1
Copper 3.3J ug/L 07/20/16 13:33 7440-50-807/18/16 20:2010.0 2.5 1
Lead 4.6J ug/L 07/20/16 13:33 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 6.4J ug/L 07/20/16 13:33 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:33 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:33 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:33 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 37.9 ug/L 07/20/16 13:33 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 35.4 ug/L 07/20/16 13:33 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 20:26 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 20:26 107-13-12001.9 1
Benzene ND ug/L 07/15/16 20:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 20:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 20:26 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 20:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 20:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 20:26 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 20:26 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 20:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 20:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 20:26 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 20:26 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 20:26 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 20:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 20:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 20:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 20:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 20:26 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 20:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 20:26 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 20:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 20:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 20:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 20:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 20:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 20:26 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 20:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 20:26 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-28 Lab ID:92305246009 Collected:07/13/16 15:42 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 20:26 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 20:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 20:26 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 20:26 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 20:26 108-10-11000.33 1
Styrene ND ug/L 07/15/16 20:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 20:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 20:26 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 20:26 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 20:26 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 20:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 20:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 20:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 20:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 20:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 20:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 20:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 20:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %07/15/16 20:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)86 %07/15/16 20:26 17060-07-070-130 1
Toluene-d8 (S)102 %07/15/16 20:26 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-29 Lab ID:92305246010 Collected:07/13/16 15:51 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:36 7440-36-007/18/16 20:206.0 3.8 1
Arsenic 5.8J ug/L 07/20/16 13:36 7440-38-207/18/16 20:2010.0 2.5 1
Barium 162 ug/L 07/20/16 13:36 7440-39-307/18/16 20:201002.5 1
Beryllium 4.3 ug/L 07/20/16 13:36 7440-41-707/18/16 20:201.0 0.50 1
Cadmium 0.57J ug/L 07/20/16 13:36 7440-43-907/18/16 20:201.0 0.50 1
Chromium 23.5 ug/L 07/20/16 13:36 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 6.4J ug/L 07/20/16 13:36 7440-48-407/18/16 20:2010.0 2.5 1
Copper 6.2J ug/L 07/20/16 13:36 7440-50-807/18/16 20:2010.0 2.5 1
Lead 20.0 ug/L 07/20/16 13:36 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 9.3J ug/L 07/20/16 13:36 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:36 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:36 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:36 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 44.1 ug/L 07/20/16 13:36 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 62.0 ug/L 07/20/16 13:36 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 20:43 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 20:43 107-13-12001.9 1
Benzene ND ug/L 07/15/16 20:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 20:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 20:43 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 20:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 20:43 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 20:43 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 20:43 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 20:43 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 20:43 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 20:43 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 20:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 20:43 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 20:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 20:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 20:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 20:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 20:43 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 20:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 20:43 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 20:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 20:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 20:43 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 20:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 20:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 20:43 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 20:43 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 20:43 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-29 Lab ID:92305246010 Collected:07/13/16 15:51 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 20:43 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 20:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 20:43 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 20:43 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 20:43 108-10-11000.33 1
Styrene ND ug/L 07/15/16 20:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 20:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 20:43 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 20:43 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 20:43 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 20:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 20:43 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 20:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 20:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 20:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 20:43 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 20:43 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 20:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %07/15/16 20:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)87 %07/15/16 20:43 17060-07-070-130 1
Toluene-d8 (S)102 %07/15/16 20:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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Page 24 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-30 Lab ID:92305246011 Collected:07/13/16 16:15 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/20/16 13:40 7440-36-007/18/16 20:206.0 3.8 1
Arsenic ND ug/L 07/20/16 13:40 7440-38-207/18/16 20:2010.0 2.5 1
Barium 56.0J ug/L 07/20/16 13:40 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:40 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:40 7440-43-907/18/16 20:201.0 0.50 1
Chromium 21.7 ug/L 07/20/16 13:40 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 8.2J ug/L 07/20/16 13:40 7440-48-407/18/16 20:2010.0 2.5 1
Copper 16.4 ug/L 07/20/16 13:40 7440-50-807/18/16 20:2010.0 2.5 1
Lead 3.3J ug/L 07/20/16 13:40 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 12.3J ug/L 07/20/16 13:40 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:40 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:40 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:40 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 38.0 ug/L 07/20/16 13:40 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 23.1 ug/L 07/20/16 13:40 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 21:00 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 21:00 107-13-12001.9 1
Benzene ND ug/L 07/15/16 21:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 21:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 21:00 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 21:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 21:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/15/16 21:00 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 21:00 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 21:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/15/16 21:00 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 21:00 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 21:00 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 21:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 21:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 21:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 21:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 21:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 21:00 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/15/16 21:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 21:00 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 21:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 21:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 21:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 21:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 21:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 21:00 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 21:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 21:00 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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Page 25 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:MW-30 Lab ID:92305246011 Collected:07/13/16 16:15 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/15/16 21:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 21:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 21:00 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 21:00 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 21:00 108-10-11000.33 1
Styrene ND ug/L 07/15/16 21:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 21:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 21:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 21:00 127-18-41.0 0.46 1
Toluene ND ug/L 07/15/16 21:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 21:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 21:00 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 21:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 21:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 21:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 21:00 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 21:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/15/16 21:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %07/15/16 21:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)83 %07/15/16 21:00 17060-07-070-130 1
Toluene-d8 (S)102 %07/15/16 21:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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9800 Kincey Ave. Suite 100
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Page 26 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:FORCEMAIN Lab ID:92305246012 Collected:07/13/16 16:35 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 12.1 ug/L 07/20/16 13:52 7440-36-007/18/16 20:206.0 3.8 1
Arsenic 9.9J ug/L 07/20/16 13:52 7440-38-207/18/16 20:2010.0 2.5 1
Barium 945 ug/L 07/20/16 13:52 7440-39-307/18/16 20:201002.5 1
Beryllium ND ug/L 07/20/16 13:52 7440-41-707/18/16 20:201.0 0.50 1
Cadmium ND ug/L 07/20/16 13:52 7440-43-907/18/16 20:201.0 0.50 1
Chromium 28.1 ug/L 07/20/16 13:52 7440-47-307/18/16 20:2010.0 2.5 1
Cobalt 9.8J ug/L 07/20/16 13:52 7440-48-407/18/16 20:2010.0 2.5 1
Copper 77.3 ug/L 07/20/16 13:52 7440-50-807/18/16 20:2010.0 2.5 1
Lead 3.2J ug/L 07/20/16 13:52 7439-92-107/18/16 20:2010.0 2.5 1
Nickel 106 ug/L 07/20/16 13:52 7440-02-007/18/16 20:2050.0 2.5 1
Selenium ND ug/L 07/20/16 13:52 7782-49-207/18/16 20:2010.0 5.0 1
Silver ND ug/L 07/20/16 13:52 7440-22-407/18/16 20:2010.0 2.5 1
Thallium ND ug/L 07/20/16 13:52 7440-28-007/18/16 20:205.5 5.0 1
Vanadium 18.8J ug/L 07/20/16 13:52 7440-62-207/18/16 20:2025.0 2.5 1
Zinc 29.9 ug/L 07/20/16 13:52 7440-66-607/18/16 20:2010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/15/16 21:17 67-64-110010.0 1
Acrylonitrile ND ug/L 07/15/16 21:17 107-13-12001.9 1
Benzene 7.4 ug/L 07/15/16 21:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/15/16 21:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/15/16 21:17 75-27-41.0 0.18 1
Bromoform ND ug/L 07/15/16 21:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/15/16 21:17 74-83-910.0 0.29 1
2-Butanone (MEK)24.4J ug/L 07/15/16 21:17 78-93-31000.96 1
Carbon disulfide ND ug/L 07/15/16 21:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/15/16 21:17 56-23-51.0 0.25 1
Chlorobenzene 0.67J ug/L 07/15/16 21:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/15/16 21:17 75-00-310.0 0.54 1
Chloroform ND ug/L 07/15/16 21:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/15/16 21:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/15/16 21:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/15/16 21:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/15/16 21:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/15/16 21:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/15/16 21:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.2 ug/L 07/15/16 21:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/15/16 21:17 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/15/16 21:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/15/16 21:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/15/16 21:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/15/16 21:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/15/16 21:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/15/16 21:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/15/16 21:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/15/16 21:17 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Sample:FORCEMAIN Lab ID:92305246012 Collected:07/13/16 16:35 Received:07/14/16 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene 15.5 ug/L 07/15/16 21:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/15/16 21:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/15/16 21:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/15/16 21:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/15/16 21:17 108-10-11000.33 1
Styrene ND ug/L 07/15/16 21:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/15/16 21:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/15/16 21:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/15/16 21:17 127-18-41.0 0.46 1
Toluene 0.81J ug/L 07/15/16 21:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/15/16 21:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/15/16 21:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/15/16 21:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/15/16 21:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/15/16 21:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/15/16 21:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/15/16 21:17 75-01-41.0 0.62 1
Xylene (Total)16.1 ug/L 07/15/16 21:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %07/15/16 21:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)84 %07/15/16 21:17 17060-07-070-130 1
Toluene-d8 (S)104 %07/15/16 21:17 2037-26-570-130 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 42200 ug/L 07/19/16 23:1007/15/16 02:00200020001
Analytical Method: EPA 90409040 pH
pH 7.6 Std. Units 07/26/16 09:56 H60.10 0.10 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 9510J ug/L 07/27/16 00:23 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 314J ug/L 07/15/16 14:261000010.0 1
Analytical Method: EPA 365.1365.1 Phosphorus, Total
Phosphorus 743 ug/L 07/28/16 15:45 7723-14-050.0 25.0 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 743000 ug/L 07/27/16 11:0025000125001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321452
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92305246001, 92305246002, 92305246003, 92305246004, 92305246005, 92305246006, 92305246007,
92305246008, 92305246009, 92305246010, 92305246011, 92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781562
Associated Lab Samples:92305246001, 92305246002, 92305246003, 92305246004, 92305246005, 92305246006, 92305246007,
92305246008, 92305246009, 92305246010, 92305246011, 92305246012
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/20/16 12:373.8
Arsenic ug/L ND 10.0 07/20/16 12:372.5
Barium ug/L ND 100 07/20/16 12:372.5
Beryllium ug/L ND 1.0 07/20/16 12:370.50
Cadmium ug/L ND 1.0 07/20/16 12:370.50
Chromium ug/L ND 10.0 07/20/16 12:372.5
Cobalt ug/L ND 10.0 07/20/16 12:372.5
Copper ug/L ND 10.0 07/20/16 12:372.5
Lead ug/L ND 10.0 07/20/16 12:372.5
Nickel ug/L ND 50.0 07/20/16 12:372.5
Selenium ug/L ND 10.0 07/20/16 12:375.0
Silver ug/L ND 10.0 07/20/16 12:372.5
Thallium ug/L ND 5.5 07/20/16 12:375.0
Vanadium ug/L ND 25.0 07/20/16 12:372.5
Zinc ug/L ND 10.0 07/20/16 12:375.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781563LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 500500 100 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 490500 98 80-120
Beryllium ug/L 494500 99 80-120
Cadmium ug/L 495500 99 80-120
Chromium ug/L 485500 97 80-120
Cobalt ug/L 493500 99 80-120
Copper ug/L 499500 100 80-120
Lead ug/L 491500 98 80-120
Nickel ug/L 491500 98 80-120
Selenium ug/L 489500 98 80-120
Silver ug/L 247250 99 80-120
Thallium ug/L 492500 98 80-120
Vanadium ug/L 489500 98 80-120
Zinc ug/L 484500 97 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781564MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305243001
1781565
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-125100 1 25500ND498502
Arsenic ug/L 500 100 75-12599 0 25500ND498497
Barium ug/L 500 97 75-12596 1 25500257743738
Beryllium ug/L 500 99 75-12599 0 25500ND497496
Cadmium ug/L 500 98 75-12599 1 25500ND492494
Chromium ug/L 500 96 75-12597 1 25500ND481487
Cobalt ug/L 500 94 75-12595 1 25500ND470474
Copper ug/L 500 98 75-12599 1 25500ND492496
Lead ug/L 500 92 75-12593 0 25500ND461463
Nickel ug/L 500 93 75-12594 1 25500ND468474
Selenium ug/L 500 96 75-12597 1 25500ND482488
Silver ug/L 250 97 75-12598 1 25250ND244246
Thallium ug/L 500 89 75-12589 0 25500ND447448
Vanadium ug/L 500 98 75-125100 1 25500ND492499
Zinc ug/L 500 94 75-12596 2 25500ND476484
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321369
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92305246001, 92305246002, 92305246003, 92305246004, 92305246005, 92305246006, 92305246007,
92305246008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781001
Associated Lab Samples:92305246001, 92305246002, 92305246003, 92305246004, 92305246005, 92305246006, 92305246007,
92305246008
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/15/16 13:220.33
1,1,1-Trichloroethane ug/L ND 1.0 07/15/16 13:220.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/15/16 13:220.40
1,1,2-Trichloroethane ug/L ND 1.0 07/15/16 13:220.29
1,1-Dichloroethane ug/L ND 5.0 07/15/16 13:220.32
1,1-Dichloroethene ug/L ND 5.0 07/15/16 13:220.56
1,2,3-Trichloropropane ug/L ND 1.0 07/15/16 13:220.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/15/16 13:222.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/15/16 13:220.27
1,2-Dichlorobenzene ug/L ND 5.0 07/15/16 13:220.30
1,2-Dichloroethane ug/L ND 1.0 07/15/16 13:220.24
1,2-Dichloropropane ug/L ND 1.0 07/15/16 13:220.27
1,4-Dichlorobenzene ug/L ND 1.0 07/15/16 13:220.33
2-Butanone (MEK)ug/L ND 100 07/15/16 13:220.96
2-Hexanone ug/L ND 50.0 07/15/16 13:220.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/15/16 13:220.33
Acetone ug/L ND 100 07/15/16 13:2210.0
Acrylonitrile ug/L ND 200 07/15/16 13:221.9
Benzene ug/L ND 1.0 07/15/16 13:220.25
Bromochloromethane ug/L ND 3.0 07/15/16 13:220.17
Bromodichloromethane ug/L ND 1.0 07/15/16 13:220.18
Bromoform ug/L ND 3.0 07/15/16 13:220.26
Bromomethane ug/L ND 10.0 07/15/16 13:220.29
Carbon disulfide ug/L ND 100 07/15/16 13:221.2
Carbon tetrachloride ug/L ND 1.0 07/15/16 13:220.25
Chlorobenzene ug/L ND 3.0 07/15/16 13:220.23
Chloroethane ug/L ND 10.0 07/15/16 13:220.54
Chloroform ug/L ND 5.0 07/15/16 13:220.14
Chloromethane ug/L ND 1.0 07/15/16 13:220.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/15/16 13:220.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/15/16 13:220.13
Dibromochloromethane ug/L ND 3.0 07/15/16 13:220.21
Dibromomethane ug/L ND 10.0 07/15/16 13:220.21
Ethylbenzene ug/L ND 1.0 07/15/16 13:220.30
Iodomethane ug/L ND 10.0 07/15/16 13:220.32
Methylene Chloride ug/L ND 1.0 07/15/16 13:220.97
Styrene ug/L ND 1.0 07/15/16 13:220.26
Tetrachloroethene ug/L ND 1.0 07/15/16 13:220.46
Toluene ug/L ND 1.0 07/15/16 13:220.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/15/16 13:220.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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[phone]
Page 31 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781001
Associated Lab Samples:92305246001, 92305246002, 92305246003, 92305246004, 92305246005, 92305246006, 92305246007,
92305246008
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 07/15/16 13:220.26
trans-1,4-Dichloro-2-butene ug/L ND 100 07/15/16 13:221.0
Trichloroethene ug/L ND 1.0 07/15/16 13:220.47
Trichlorofluoromethane ug/L ND 1.0 07/15/16 13:220.20
Vinyl acetate ug/L ND 50.0 07/15/16 13:220.35
Vinyl chloride ug/L ND 1.0 07/15/16 13:220.62
Xylene (Total)ug/L ND 5.0 07/15/16 13:220.66
1,2-Dichloroethane-d4 (S)%84 70-130 07/15/16 13:22
4-Bromofluorobenzene (S)%102 70-130 07/15/16 13:22
Toluene-d8 (S)%100 70-130 07/15/16 13:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781002LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.050 106 80-125
1,1,1-Trichloroethane ug/L 46.450 93 71-129
1,1,2,2-Tetrachloroethane ug/L 48.050 96 79-124
1,1,2-Trichloroethane ug/L 51.450 103 85-125
1,1-Dichloroethane ug/L 47.750 95 73-126
1,1-Dichloroethene ug/L 47.450 95 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 43.950 88 71-133
1,2-Dibromoethane (EDB)ug/L 54.450 109 83-124
1,2-Dichlorobenzene ug/L 52.650 105 80-133
1,2-Dichloroethane ug/L 41.950 84 67-128
1,2-Dichloropropane ug/L 48.350 97 75-132
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 86.9J100 87 61-144
2-Hexanone ug/L 84.5100 84 68-143
4-Methyl-2-pentanone (MIBK)ug/L 91.4J100 91 72-135
Acetone ug/L 75.6J100 76 48-146
Acrylonitrile ug/L 229250 92 40-160
Benzene ug/L 51.250 102 80-125
Bromochloromethane ug/L 50.850 102 71-125
Bromodichloromethane ug/L 48.850 98 78-124
Bromoform ug/L 45.550 91 71-128
Bromomethane ug/L 40.750 81 40-160
Carbon disulfide ug/L 48.0J50 96 50-160
Carbon tetrachloride ug/L 48.250 96 69-131
Chlorobenzene ug/L 51.650 103 81-122
Chloroethane ug/L 50.850 102 39-148
Chloroform ug/L 46.850 94 73-127
Chloromethane ug/L 48.750 97 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781002LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 47.950 96 74-124
cis-1,3-Dichloropropene ug/L 50.950 102 72-132
Dibromochloromethane ug/L 51.450 103 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 49.350 99 79-121
Iodomethane ug/L 93.4100 93 39-154
Methylene Chloride ug/L 48.450 97 64-133
Styrene ug/L 53.150 106 84-126
Tetrachloroethene ug/L 51.650 103 78-122
Toluene ug/L 50.450 101 80-121
trans-1,2-Dichloroethene ug/L 48.850 98 71-127
trans-1,3-Dichloropropene ug/L 48.150 96 69-141
trans-1,4-Dichloro-2-butene ug/L 70.2J50 140 40-160
Trichloroethene ug/L 52.350 105 78-122
Trichlorofluoromethane ug/L 48.650 97 53-137
Vinyl acetate ug/L 90.0100 90 40-160
Vinyl chloride ug/L 49.150 98 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1781004MATRIX SPIKE SAMPLE:
MSSpike
Result
92305246008
1,1,1,2-Tetrachloroethane ug/L 21.320 107 70-130ND
1,1,1-Trichloroethane ug/L 20.820 104 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.720 103 70-130ND
1,1,2-Trichloroethane ug/L 22.620 113 70-130ND
1,1-Dichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethene ug/L 21.820 109 70-166ND
1,2,3-Trichloropropane ug/L 19.920 99 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.820 94 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.420 112 70-130ND
1,2-Dichlorobenzene ug/L 22.820 114 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 21.420 107 70-130ND
1,4-Dichlorobenzene ug/L 21.420 107 70-130ND
2-Butanone (MEK)ug/L 43.8J40 110 70-130ND
2-Hexanone ug/L 39.4J40 98 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.3J40 106 70-130ND
Acetone ug/L 39.3J40 91 70-130ND
Acrylonitrile ug/L 102J100 102 70-130ND
Benzene ug/L 23.020 115 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1781004MATRIX SPIKE SAMPLE:
MSSpike
Result
92305246008
Bromodichloromethane ug/L 20.920 105 70-130ND
Bromoform ug/L 18.620 93 70-130ND
Bromomethane ug/L 15.720 79 70-130ND
Carbon disulfide ug/L 23.7J20 119 70-130ND
Carbon tetrachloride ug/L 21.120 105 70-130ND
Chlorobenzene ug/L 22.520 113 70-146ND
Chloroethane ug/L 22.620 113 70-130ND
Chloroform ug/L 20.320 101 70-130ND
Chloromethane ug/L 20.620 103 70-130ND
cis-1,2-Dichloroethene ug/L 21.320 106 70-130ND
cis-1,3-Dichloropropene ug/L 19.920 99 70-130ND
Dibromochloromethane ug/L 19.920 100 70-130ND
Dibromomethane ug/L 23.320 116 70-130ND
Ethylbenzene ug/L 21.820 109 70-130ND
Iodomethane ug/L 36.740 92 70-130ND
Methylene Chloride ug/L 20.720 103 70-130ND
Styrene ug/L 22.320 112 70-130ND
Tetrachloroethene ug/L 21.820 109 70-130ND
Toluene ug/L 22.920 115 70-155ND
trans-1,2-Dichloroethene ug/L 21.720 108 70-130ND
trans-1,3-Dichloropropene ug/L 19.320 97 70-130ND
trans-1,4-Dichloro-2-butene ug/L 15.9J20 79 70-130ND
Trichloroethene ug/L 23.120 116 69-151ND
Trichlorofluoromethane ug/L 20.420 102 70-130ND
Vinyl acetate ug/L 32.7J40 82 70-130ND
Vinyl chloride ug/L 21.020 105 70-130ND
1,2-Dichloroethane-d4 (S)%85 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305246007
1781003SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305246007
1781003SAMPLE DUPLICATE:
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%88 088
4-Bromofluorobenzene (S)%103 1104
Toluene-d8 (S)%101 2103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321373
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92305246009, 92305246010, 92305246011, 92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781019
Associated Lab Samples:92305246009, 92305246010, 92305246011, 92305246012
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/15/16 13:390.33
1,1,1-Trichloroethane ug/L ND 1.0 07/15/16 13:390.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/15/16 13:390.40
1,1,2-Trichloroethane ug/L ND 1.0 07/15/16 13:390.29
1,1-Dichloroethane ug/L ND 5.0 07/15/16 13:390.32
1,1-Dichloroethene ug/L ND 5.0 07/15/16 13:390.56
1,2,3-Trichloropropane ug/L ND 1.0 07/15/16 13:390.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/15/16 13:392.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/15/16 13:390.27
1,2-Dichlorobenzene ug/L ND 5.0 07/15/16 13:390.30
1,2-Dichloroethane ug/L ND 1.0 07/15/16 13:390.24
1,2-Dichloropropane ug/L ND 1.0 07/15/16 13:390.27
1,4-Dichlorobenzene ug/L ND 1.0 07/15/16 13:390.33
2-Butanone (MEK)ug/L ND 100 07/15/16 13:390.96
2-Hexanone ug/L ND 50.0 07/15/16 13:390.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/15/16 13:390.33
Acetone ug/L ND 100 07/15/16 13:3910.0
Acrylonitrile ug/L ND 200 07/15/16 13:391.9
Benzene ug/L ND 1.0 07/15/16 13:390.25
Bromochloromethane ug/L ND 3.0 07/15/16 13:390.17
Bromodichloromethane ug/L ND 1.0 07/15/16 13:390.18
Bromoform ug/L ND 3.0 07/15/16 13:390.26
Bromomethane ug/L ND 10.0 07/15/16 13:390.29
Carbon disulfide ug/L ND 100 07/15/16 13:391.2
Carbon tetrachloride ug/L ND 1.0 07/15/16 13:390.25
Chlorobenzene ug/L ND 3.0 07/15/16 13:390.23
Chloroethane ug/L ND 10.0 07/15/16 13:390.54
Chloroform ug/L ND 5.0 07/15/16 13:390.14
Chloromethane ug/L ND 1.0 07/15/16 13:390.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/15/16 13:390.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/15/16 13:390.13
Dibromochloromethane ug/L ND 3.0 07/15/16 13:390.21
Dibromomethane ug/L ND 10.0 07/15/16 13:390.21
Ethylbenzene ug/L ND 1.0 07/15/16 13:390.30
Iodomethane ug/L ND 10.0 07/15/16 13:390.32
Methylene Chloride ug/L ND 1.0 07/15/16 13:390.97
Styrene ug/L ND 1.0 07/15/16 13:390.26
Tetrachloroethene ug/L ND 1.0 07/15/16 13:390.46
Toluene ug/L ND 1.0 07/15/16 13:390.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/15/16 13:390.49
trans-1,3-Dichloropropene ug/L ND 1.0 07/15/16 13:390.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781019
Associated Lab Samples:92305246009, 92305246010, 92305246011, 92305246012
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 07/15/16 13:391.0
Trichloroethene ug/L ND 1.0 07/15/16 13:390.47
Trichlorofluoromethane ug/L ND 1.0 07/15/16 13:390.20
Vinyl acetate ug/L ND 50.0 07/15/16 13:390.35
Vinyl chloride ug/L ND 1.0 07/15/16 13:390.62
Xylene (Total)ug/L ND 5.0 07/15/16 13:390.66
1,2-Dichloroethane-d4 (S)%84 70-130 07/15/16 13:39
4-Bromofluorobenzene (S)%106 70-130 07/15/16 13:39
Toluene-d8 (S)%101 70-130 07/15/16 13:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781020LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.950 104 80-125
1,1,1-Trichloroethane ug/L 45.950 92 71-129
1,1,2,2-Tetrachloroethane ug/L 47.450 95 79-124
1,1,2-Trichloroethane ug/L 51.150 102 85-125
1,1-Dichloroethane ug/L 47.150 94 73-126
1,1-Dichloroethene ug/L 46.150 92 66-135
1,2,3-Trichloropropane ug/L 46.350 93 75-130
1,2-Dibromo-3-chloropropane ug/L 42.550 85 71-133
1,2-Dibromoethane (EDB)ug/L 53.950 108 83-124
1,2-Dichlorobenzene ug/L 52.650 105 80-133
1,2-Dichloroethane ug/L 41.050 82 67-128
1,2-Dichloropropane ug/L 46.750 93 75-132
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 90.3J100 90 61-144
2-Hexanone ug/L 85.4100 85 68-143
4-Methyl-2-pentanone (MIBK)ug/L 91.2J100 91 72-135
Acetone ug/L 77.8J100 78 48-146
Acrylonitrile ug/L 234250 94 40-160
Benzene ug/L 50.050 100 80-125
Bromochloromethane ug/L 51.050 102 71-125
Bromodichloromethane ug/L 48.450 97 78-124
Bromoform ug/L 45.150 90 71-128
Bromomethane ug/L 41.850 84 40-160
Carbon disulfide ug/L 47.3J50 95 50-160
Carbon tetrachloride ug/L 46.550 93 69-131
Chlorobenzene ug/L 51.050 102 81-122
Chloroethane ug/L 47.950 96 39-148
Chloroform ug/L 45.650 91 73-127
Chloromethane ug/L 46.250 92 44-146
cis-1,2-Dichloroethene ug/L 47.350 95 74-124
cis-1,3-Dichloropropene ug/L 49.250 98 72-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781020LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 51.150 102 78-125
Dibromomethane ug/L 51.650 103 82-120
Ethylbenzene ug/L 47.850 96 79-121
Iodomethane ug/L 91.7100 92 39-154
Methylene Chloride ug/L 48.450 97 64-133
Styrene ug/L 51.650 103 84-126
Tetrachloroethene ug/L 49.250 98 78-122
Toluene ug/L 48.550 97 80-121
trans-1,2-Dichloroethene ug/L 47.550 95 71-127
trans-1,3-Dichloropropene ug/L 47.350 95 69-141
trans-1,4-Dichloro-2-butene ug/L 74.8J50 150 40-160
Trichloroethene ug/L 51.250 102 78-122
Trichlorofluoromethane ug/L 47.450 95 53-137
Vinyl acetate ug/L 90.7100 91 40-160
Vinyl chloride ug/L 48.450 97 58-137
Xylene (Total)ug/L 139150 93 81-126
1,2-Dichloroethane-d4 (S)%87 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1781022MATRIX SPIKE SAMPLE:
MSSpike
Result
92305251005
1,1,1,2-Tetrachloroethane ug/L 20.920 105 70-130ND
1,1,1-Trichloroethane ug/L 21.520 107 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.120 101 70-130ND
1,1,2-Trichloroethane ug/L 22.120 110 70-130ND
1,1-Dichloroethane ug/L 22.220 111 70-130ND
1,1-Dichloroethene ug/L 21.620 108 70-166ND
1,2,3-Trichloropropane ug/L 19.120 95 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.720 88 70-130
1,2-Dibromoethane (EDB)ug/L 21.620 108 70-130
1,2-Dichlorobenzene ug/L 22.820 114 70-130ND
1,2-Dichloroethane ug/L 18.520 91 70-130ND
1,2-Dichloropropane ug/L 21.720 109 70-130ND
1,4-Dichlorobenzene ug/L 23.220 109 70-1301.5
2-Butanone (MEK)ug/L 42.4J40 106 70-130ND
2-Hexanone ug/L 38.1J40 95 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.7J40 104 70-130ND
Acetone ug/L 40.6J40 97 70-130ND
Acrylonitrile ug/L 102J100 102 70-130ND
Benzene ug/L 26.020 117 70-1482.5
Bromochloromethane ug/L 23.220 116 70-130ND
Bromodichloromethane ug/L 20.720 104 70-130ND
Bromoform ug/L 18.220 91 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1781022MATRIX SPIKE SAMPLE:
MSSpike
Result
92305251005
Bromomethane ug/L 14.820 74 70-130ND
Carbon disulfide ug/L 24.1J20 120 70-130ND
Carbon tetrachloride ug/L 21.020 105 70-130ND
Chlorobenzene ug/L 23.620 113 70-1460.96J
Chloroethane ug/L 24.520 123 70-130ND
Chloroform ug/L 21.220 106 70-130ND
Chloromethane ug/L 21.020 105 70-130ND
cis-1,2-Dichloroethene ug/L 21.720 109 70-130ND
cis-1,3-Dichloropropene ug/L 20.120 101 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 22.620 113 70-130ND
Ethylbenzene ug/L 22.020 110 70-130ND
Iodomethane ug/L 32.540 81 70-130ND
Methylene Chloride ug/L 21.320 107 70-130ND
Styrene ug/L 23.120 116 70-130ND
Tetrachloroethene ug/L 21.720 108 70-130ND
Toluene ug/L 23.220 116 70-155ND
trans-1,2-Dichloroethene ug/L 21.220 106 70-130ND
trans-1,3-Dichloropropene ug/L 18.620 93 70-130ND
trans-1,4-Dichloro-2-butene ug/L 15.4J20 77 70-130ND
Trichloroethene ug/L 23.920 120 69-151ND
Trichlorofluoromethane ug/L 23.120 116 70-130ND
Vinyl acetate ug/L 31.6J40 79 70-130ND
Vinyl chloride ug/L 23.320 106 70-1302.1
1,2-Dichloroethane-d4 (S)%85 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305251004
1781021SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30
1,2-Dibromoethane (EDB)ug/L ND 30
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305251004
1781021SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L 0.37J 300.48J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%84 084
4-Bromofluorobenzene (S)%101 1103
Toluene-d8 (S)%102 2101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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Page 40 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321267
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples:92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1780589
Associated Lab Samples:92305246012
Matrix:Water
AnalyzedMDL
BOD, 5 day ug/L ND 2000 07/19/16 23:102000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1780590LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 209000198000 106 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305171001
1780591SAMPLE DUPLICATE:
BOD, 5 day ug/L ND 10ND
REPORT OF LABORATORY ANALYSIS
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Page 41 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322534
EPA 9040
EPA 9040
9040 pH
Associated Lab Samples:92305246012
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305001001
1786968SAMPLE DUPLICATE:
pH Std. Units 7.9 H6198.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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[phone]
Page 42 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322656
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1787703
Associated Lab Samples:92305246012
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 07/26/16 21:301000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1787704LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1787705MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305501001
1787706
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M6200008590-11078 3 102000040.1 mg/L 57200J 55600J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1787707MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305953006
1787708
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 0 102000010.2 mg/L 30700J 30900J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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[phone]
Page 43 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321374
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781032
Associated Lab Samples:92305246012
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 20.0 07/15/16 14:2310.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781033LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 24502500 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781034MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305246012
1781035
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 108 90-110106 2 102500314J30102960
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 44 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322458
EPA 365.1
EPA 365.1
365.1 Phosphorus, Total
Associated Lab Samples:92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1786745
Associated Lab Samples:92305246012
Matrix:Water
AnalyzedMDL
Phosphorus ug/L ND 50.0 07/28/16 15:2725.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1786746LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus ug/L 25702500 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1786747MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304845003
1786748
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L M625006890-11086 2 10250026.5 mg/L 28200 28600
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1786749MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305198001
1786750
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 100 90-110100 0 102500ND25402530
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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Huntersville, NC 28078
[phone]
Page 45 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322464
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92305246012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1786770
Associated Lab Samples:92305246012
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 07/27/16 11:0012500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1786771LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 778000750000 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1786772MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305350001
1786773
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M675000013190-110131 0 375000010800
mg/L
1180000
0
1180000
0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1786774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305188001
1786775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M675000018590-110185 0 37500007490 mg/L 8880000 8880000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 46 of 50
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analysis initiated outside of the 15 minute EPA required holding time.H6
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 47 of 50
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92305246
IREDELL LINED 3&4
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92305246001 321452 321630MW-17 EPA 3010A EPA 6010
92305246002 321452 321630MW-18 EPA 3010A EPA 6010
92305246003 321452 321630MW-19SR EPA 3010A EPA 6010
92305246004 321452 321630MW-19D EPA 3010A EPA 6010
92305246005 321452 321630MW-21S EPA 3010A EPA 6010
92305246006 321452 321630MW-21D EPA 3010A EPA 6010
92305246007 321452 321630MW-27S EPA 3010A EPA 6010
92305246008 321452 321630MW-27D EPA 3010A EPA 6010
92305246009 321452 321630MW-28 EPA 3010A EPA 6010
92305246010 321452 321630MW-29 EPA 3010A EPA 6010
92305246011 321452 321630MW-30 EPA 3010A EPA 6010
92305246012 321452 321630FORCEMAINEPA 3010A EPA 6010
92305246001 321369MW-17 EPA 8260
92305246002 321369MW-18 EPA 8260
92305246003 321369MW-19SR EPA 8260
92305246004 321369MW-19D EPA 8260
92305246005 321369MW-21S EPA 8260
92305246006 321369MW-21D EPA 8260
92305246007 321369MW-27S EPA 8260
92305246008 321369MW-27D EPA 8260
92305246009 321373MW-28 EPA 8260
92305246010 321373MW-29 EPA 8260
92305246011 321373MW-30 EPA 8260
92305246012 321373FORCEMAINEPA 8260
92305246012 321267 321277FORCEMAINSM 5210B SM 5210B
92305246012 322534FORCEMAINEPA 9040
92305246012 322656FORCEMAINEPA 300.0
92305246012 321374FORCEMAINEPA 353.2
92305246012 322458FORCEMAINEPA 365.1
92305246012 322464FORCEMAINSM 5220D
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/29/2016 08:54 AM
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9800 Kincey Ave. Suite 100
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Page 48 of 50
Page 49 of 50
Page 50 of 50
#=CL#
October 28, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92317000
92317000
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
IREDELL LINED 3&4
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 21, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 12
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
Page 2 of 12
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Lab ID Sample ID Matrix Date Collected Date Received
92317000001 MW-27D Water 10/19/16 11:40 10/21/16 09:20
92317000002 MW-29 Water 10/19/16 12:10 10/21/16 09:20
REPORT OF LABORATORY ANALYSIS
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Page 3 of 12
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92317000001 MW-27D EPA 6010 15 PASI-ASER
92317000002 MW-29 EPA 6010 15 PASI-ASER
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 12
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Sample:MW-27D Lab ID:92317000001 Collected:10/19/16 11:40 Received:10/21/16 09:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/27/16 20:32 7440-36-010/25/16 18:556.0 3.8 1
Arsenic ND ug/L 10/27/16 20:32 7440-38-210/25/16 18:5510.0 2.5 1
Barium 18.5J ug/L 10/27/16 20:32 7440-39-310/25/16 18:551002.5 1
Beryllium ND ug/L 10/27/16 20:32 7440-41-710/25/16 18:551.0 0.50 1
Cadmium ND ug/L 10/27/16 20:32 7440-43-910/25/16 18:551.0 0.50 1
Chromium 3.6J ug/L 10/27/16 20:32 7440-47-310/25/16 18:5510.0 2.5 1
Cobalt ND ug/L 10/27/16 20:32 7440-48-410/25/16 18:5510.0 2.5 1
Copper ND ug/L 10/27/16 20:32 7440-50-810/25/16 18:5510.0 2.5 1
Lead ND ug/L 10/27/16 20:32 7439-92-110/25/16 18:5510.0 2.5 1
Nickel ND ug/L 10/27/16 20:32 7440-02-010/25/16 18:5550.0 2.5 1
Selenium ND ug/L 10/27/16 20:32 7782-49-210/25/16 18:5510.0 5.0 1
Silver ND ug/L 10/27/16 20:32 7440-22-410/25/16 18:5510.0 2.5 1
Thallium ND ug/L 10/27/16 20:32 7440-28-010/25/16 18:555.5 5.0 1
Vanadium 2.8J ug/L 10/27/16 20:32 7440-62-210/25/16 18:5525.0 2.5 1
Zinc ND ug/L 10/27/16 20:32 7440-66-610/25/16 18:5510.0 5.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:23 PM
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Page 5 of 12
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Sample:MW-29 Lab ID:92317000002 Collected:10/19/16 12:10 Received:10/21/16 09:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/27/16 20:35 7440-36-010/25/16 18:556.0 3.8 1
Arsenic ND ug/L 10/27/16 20:35 7440-38-210/25/16 18:5510.0 2.5 1
Barium 38.5J ug/L 10/27/16 20:35 7440-39-310/25/16 18:551002.5 1
Beryllium 1.1 ug/L 10/27/16 20:35 7440-41-710/25/16 18:551.0 0.50 1
Cadmium 0.76J ug/L 10/27/16 20:35 7440-43-910/25/16 18:551.0 0.50 1
Chromium 6.6J ug/L 10/27/16 20:35 7440-47-310/25/16 18:5510.0 2.5 1
Cobalt ND ug/L 10/27/16 20:35 7440-48-410/25/16 18:5510.0 2.5 1
Copper ND ug/L 10/27/16 20:35 7440-50-810/25/16 18:5510.0 2.5 1
Lead 2.5J ug/L 10/27/16 20:35 7439-92-110/25/16 18:5510.0 2.5 1
Nickel ND ug/L 10/27/16 20:35 7440-02-010/25/16 18:5550.0 2.5 1
Selenium ND ug/L 10/27/16 20:35 7782-49-210/25/16 18:5510.0 5.0 1
Silver ND ug/L 10/27/16 20:35 7440-22-410/25/16 18:5510.0 2.5 1
Thallium ND ug/L 10/27/16 20:35 7440-28-010/25/16 18:555.5 5.0 1
Vanadium 7.6J ug/L 10/27/16 20:35 7440-62-210/25/16 18:5525.0 2.5 1
Zinc 10.8 ug/L 10/27/16 20:35 7440-66-610/25/16 18:5510.0 5.0 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
334367
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92317000001, 92317000002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1853514
Associated Lab Samples:92317000001, 92317000002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/27/16 19:513.8
Arsenic ug/L ND 10.0 10/27/16 19:512.5
Barium ug/L ND 100 10/27/16 19:512.5
Beryllium ug/L ND 1.0 10/27/16 19:510.50
Cadmium ug/L ND 1.0 10/27/16 19:510.50
Chromium ug/L ND 10.0 10/27/16 19:512.5
Cobalt ug/L ND 10.0 10/27/16 19:512.5
Copper ug/L ND 10.0 10/27/16 19:512.5
Lead ug/L ND 10.0 10/27/16 19:512.5
Nickel ug/L ND 50.0 10/27/16 19:512.5
Selenium ug/L ND 10.0 10/27/16 19:515.0
Silver ug/L ND 10.0 10/27/16 19:512.5
Thallium ug/L ND 5.5 10/27/16 19:515.0
Vanadium ug/L ND 25.0 10/27/16 19:512.5
Zinc ug/L ND 10.0 10/27/16 19:515.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1853515LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 504500 101 80-120
Arsenic ug/L 490500 98 80-120
Barium ug/L 497500 99 80-120
Beryllium ug/L 503500 101 80-120
Cadmium ug/L 501500 100 80-120
Chromium ug/L 495500 99 80-120
Cobalt ug/L 507500 101 80-120
Copper ug/L 514500 103 80-120
Lead ug/L 498500 100 80-120
Nickel ug/L 493500 99 80-120
Selenium ug/L 510500 102 80-120
Silver ug/L 253250 101 80-120
Thallium ug/L 514500 103 80-120
Vanadium ug/L 496500 99 80-120
Zinc ug/L 509500 102 80-120
REPORT OF LABORATORY ANALYSIS
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Page 7 of 12
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1853516MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92316975007
1853517
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12599 2 25500ND481493
Arsenic ug/L 500 96 75-12598 2 25500ND481492
Barium ug/L 500 100 75-125101 1 2550082.1J 582 588
Beryllium ug/L 500 98 75-12599 1 25500ND492495
Cadmium ug/L 500 98 75-125100 2 255000.80J 490 500
Chromium ug/L 500 96 75-12597 1 25500ND483488
Cobalt ug/L 500 97 75-12599 2 2550017.6 502 512
Copper ug/L 500 102 75-125105 2 255003.2J 515 526
Lead ug/L 500 95 75-12597 2 25500ND476484
Nickel ug/L 500 95 75-12597 2 25500ND477486
Selenium ug/L 500 98 75-12599 2 25500ND489496
Silver ug/L 250 99 75-125101 1 25250ND248252
Thallium ug/L 500 96 75-12598 2 25500ND484495
Vanadium ug/L 500 97 75-12599 1 25500ND488494
Zinc ug/L 500 97 75-12599 2 255008.5J 495 505
REPORT OF LABORATORY ANALYSIS
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Page 8 of 12
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
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Page 9 of 12
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317000
IREDELL LINED 3&4
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317000001 334367 334530MW-27D EPA 3010A EPA 6010
92317000002 334367 334530MW-29 EPA 3010A EPA 6010
REPORT OF LABORATORY ANALYSIS
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Page 10 of 12
Page 11 of 12
Page 12 of 12
#=CL#
July 25, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92305833
92305833
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
IREDELL SW-1_5
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on July 20, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 19
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 19
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Lab ID Sample ID Matrix Date Collected Date Received
92305833001 SW-1 Water 07/19/16 13:50 07/20/16 12:53
92305833002 SW-5 Water 07/19/16 14:35 07/20/16 12:53
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92305833001 SW-1 EPA 6010 15 PASI-AJMW
EPA 8260 50 PASI-CNB
92305833002 SW-5 EPA 6010 15 PASI-AJMW
EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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Page 4 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Sample:SW-1 Lab ID:92305833001 Collected:07/19/16 13:50 Received:07/20/16 12:53 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/24/16 00:06 7440-36-007/22/16 17:556.0 3.8 1
Arsenic ND ug/L 07/24/16 00:06 7440-38-207/22/16 17:5510.0 2.5 1
Barium 28.2J ug/L 07/24/16 00:06 7440-39-307/22/16 17:551002.5 1
Beryllium ND ug/L 07/24/16 00:06 7440-41-707/22/16 17:551.0 0.50 1
Cadmium ND ug/L 07/24/16 00:06 7440-43-907/22/16 17:551.0 0.50 1
Chromium ND ug/L 07/24/16 00:06 7440-47-307/22/16 17:5510.0 2.5 1
Cobalt ND ug/L 07/24/16 00:06 7440-48-407/22/16 17:5510.0 2.5 1
Copper ND ug/L 07/24/16 00:06 7440-50-807/22/16 17:5510.0 2.5 1
Lead ND ug/L 07/24/16 00:06 7439-92-107/22/16 17:5510.0 2.5 1
Nickel ND ug/L 07/24/16 00:06 7440-02-007/22/16 17:5550.0 2.5 1
Selenium ND ug/L 07/24/16 00:06 7782-49-207/22/16 17:5510.0 5.0 1
Silver ND ug/L 07/24/16 00:06 7440-22-407/22/16 17:5510.0 2.5 1
Thallium ND ug/L 07/24/16 00:06 7440-28-007/22/16 17:555.5 5.0 1
Vanadium ND ug/L 07/24/16 00:06 7440-62-207/22/16 17:5525.0 2.5 1
Zinc ND ug/L 07/24/16 00:06 7440-66-607/22/16 17:5510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/21/16 23:47 67-64-110010.0 1
Acrylonitrile ND ug/L 07/21/16 23:47 107-13-12001.9 1
Benzene ND ug/L 07/21/16 23:47 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/21/16 23:47 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/21/16 23:47 75-27-41.0 0.18 1
Bromoform ND ug/L 07/21/16 23:47 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/21/16 23:47 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/21/16 23:47 78-93-31000.96 1
Carbon disulfide ND ug/L 07/21/16 23:47 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/21/16 23:47 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/21/16 23:47 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/21/16 23:47 75-00-310.0 0.54 1
Chloroform ND ug/L 07/21/16 23:47 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/21/16 23:47 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/21/16 23:47 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/21/16 23:47 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/21/16 23:47 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/21/16 23:47 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/21/16 23:47 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/21/16 23:47 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/21/16 23:47 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/21/16 23:47 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/21/16 23:47 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/21/16 23:47 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/21/16 23:47 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/21/16 23:47 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/21/16 23:47 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/21/16 23:47 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/21/16 23:47 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Sample:SW-1 Lab ID:92305833001 Collected:07/19/16 13:50 Received:07/20/16 12:53 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/21/16 23:47 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/21/16 23:47 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/21/16 23:47 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/21/16 23:47 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/21/16 23:47 108-10-11000.33 1
Styrene ND ug/L 07/21/16 23:47 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/21/16 23:47 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/21/16 23:47 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/21/16 23:47 127-18-41.0 0.46 1
Toluene ND ug/L 07/21/16 23:47 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/21/16 23:47 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/21/16 23:47 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/21/16 23:47 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/21/16 23:47 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/21/16 23:47 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/21/16 23:47 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/21/16 23:47 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/21/16 23:47 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %07/21/16 23:47 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %07/21/16 23:47 17060-07-070-130 1
Toluene-d8 (S)101 %07/21/16 23:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Sample:SW-5 Lab ID:92305833002 Collected:07/19/16 14:35 Received:07/20/16 12:53 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/24/16 00:09 7440-36-007/22/16 17:556.0 3.8 1
Arsenic ND ug/L 07/24/16 00:09 7440-38-207/22/16 17:5510.0 2.5 1
Barium 27.6J ug/L 07/24/16 00:09 7440-39-307/22/16 17:551002.5 1
Beryllium ND ug/L 07/24/16 00:09 7440-41-707/22/16 17:551.0 0.50 1
Cadmium ND ug/L 07/24/16 00:09 7440-43-907/22/16 17:551.0 0.50 1
Chromium ND ug/L 07/24/16 00:09 7440-47-307/22/16 17:5510.0 2.5 1
Cobalt ND ug/L 07/24/16 00:09 7440-48-407/22/16 17:5510.0 2.5 1
Copper ND ug/L 07/24/16 00:09 7440-50-807/22/16 17:5510.0 2.5 1
Lead ND ug/L 07/24/16 00:09 7439-92-107/22/16 17:5510.0 2.5 1
Nickel ND ug/L 07/24/16 00:09 7440-02-007/22/16 17:5550.0 2.5 1
Selenium ND ug/L 07/24/16 00:09 7782-49-207/22/16 17:5510.0 5.0 1
Silver ND ug/L 07/24/16 00:09 7440-22-407/22/16 17:5510.0 2.5 1
Thallium ND ug/L 07/24/16 00:09 7440-28-007/22/16 17:555.5 5.0 1
Vanadium ND ug/L 07/24/16 00:09 7440-62-207/22/16 17:5525.0 2.5 1
Zinc ND ug/L 07/24/16 00:09 7440-66-607/22/16 17:5510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/22/16 00:05 67-64-110010.0 1
Acrylonitrile ND ug/L 07/22/16 00:05 107-13-12001.9 1
Benzene ND ug/L 07/22/16 00:05 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/22/16 00:05 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/22/16 00:05 75-27-41.0 0.18 1
Bromoform ND ug/L 07/22/16 00:05 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/22/16 00:05 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/22/16 00:05 78-93-31000.96 1
Carbon disulfide ND ug/L 07/22/16 00:05 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/22/16 00:05 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/22/16 00:05 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/22/16 00:05 75-00-310.0 0.54 1
Chloroform ND ug/L 07/22/16 00:05 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/22/16 00:05 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/22/16 00:05 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/22/16 00:05 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/22/16 00:05 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/22/16 00:05 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/22/16 00:05 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/22/16 00:05 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/22/16 00:05 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/22/16 00:05 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/22/16 00:05 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/22/16 00:05 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/22/16 00:05 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/22/16 00:05 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/22/16 00:05 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/22/16 00:05 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/22/16 00:05 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Sample:SW-5 Lab ID:92305833002 Collected:07/19/16 14:35 Received:07/20/16 12:53 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/22/16 00:05 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/22/16 00:05 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/22/16 00:05 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 07/22/16 00:05 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/22/16 00:05 108-10-11000.33 1
Styrene ND ug/L 07/22/16 00:05 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/22/16 00:05 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/22/16 00:05 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/22/16 00:05 127-18-41.0 0.46 1
Toluene ND ug/L 07/22/16 00:05 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/22/16 00:05 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/22/16 00:05 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/22/16 00:05 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/22/16 00:05 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/22/16 00:05 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/22/16 00:05 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/22/16 00:05 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/22/16 00:05 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %07/22/16 00:05 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %07/22/16 00:05 17060-07-070-130 1
Toluene-d8 (S)101 %07/22/16 00:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322123
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92305833001, 92305833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1785302
Associated Lab Samples:92305833001, 92305833002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/23/16 23:393.8
Arsenic ug/L ND 10.0 07/23/16 23:392.5
Barium ug/L ND 100 07/23/16 23:392.5
Beryllium ug/L ND 1.0 07/23/16 23:390.50
Cadmium ug/L ND 1.0 07/23/16 23:390.50
Chromium ug/L ND 10.0 07/23/16 23:392.5
Cobalt ug/L ND 10.0 07/23/16 23:392.5
Copper ug/L ND 10.0 07/23/16 23:392.5
Lead ug/L ND 10.0 07/23/16 23:392.5
Nickel ug/L ND 50.0 07/23/16 23:392.5
Selenium ug/L ND 10.0 07/23/16 23:395.0
Silver ug/L ND 10.0 07/23/16 23:392.5
Thallium ug/L ND 5.5 07/23/16 23:395.0
Vanadium ug/L ND 25.0 07/23/16 23:392.5
Zinc ug/L ND 10.0 07/23/16 23:395.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1785303LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 499500 100 80-120
Arsenic ug/L 488500 98 80-120
Barium ug/L 527500 105 80-120
Beryllium ug/L 534500 107 80-120
Cadmium ug/L 509500 102 80-120
Chromium ug/L 519500 104 80-120
Cobalt ug/L 502500 100 80-120
Copper ug/L 514500 103 80-120
Lead ug/L 499500 100 80-120
Nickel ug/L 509500 102 80-120
Selenium ug/L 496500 99 80-120
Silver ug/L 250250 100 80-120
Thallium ug/L 514500 103 80-120
Vanadium ug/L 512500 102 80-120
Zinc ug/L 495500 99 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1785304MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92305796001
1785305
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 101 75-12599 1 25500ND504497
Arsenic ug/L 500 99 75-12597 1 25500ND495487
Barium ug/L 500 106 75-125106 0 25500112642643
Beryllium ug/L 500 109 75-125108 0 25500ND544542
Cadmium ug/L 500 102 75-125101 1 25500ND511507
Chromium ug/L 500 104 75-125104 0 25500ND521520
Cobalt ug/L 500 99 75-12598 1 25500ND496490
Copper ug/L 500 104 75-125104 1 25500ND522519
Lead ug/L 500 98 75-12598 0 25500ND490489
Nickel ug/L 500 100 75-125100 1 25500ND503500
Selenium ug/L 500 99 75-12599 0 25500ND495496
Silver ug/L 250 100 75-125100 0 25250ND251250
Thallium ug/L 500 102 75-125102 0 25500ND508510
Vanadium ug/L 500 104 75-125103 0 25500ND520519
Zinc ug/L 500 95 75-12595 0 2550054210201020
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322075
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92305833001, 92305833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1784841
Associated Lab Samples:92305833001, 92305833002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/21/16 22:560.33
1,1,1-Trichloroethane ug/L ND 1.0 07/21/16 22:560.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/21/16 22:560.40
1,1,2-Trichloroethane ug/L ND 1.0 07/21/16 22:560.29
1,1-Dichloroethane ug/L ND 5.0 07/21/16 22:560.32
1,1-Dichloroethene ug/L ND 5.0 07/21/16 22:560.56
1,2,3-Trichloropropane ug/L ND 1.0 07/21/16 22:560.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/21/16 22:562.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/21/16 22:560.27
1,2-Dichlorobenzene ug/L ND 5.0 07/21/16 22:560.30
1,2-Dichloroethane ug/L ND 1.0 07/21/16 22:560.24
1,2-Dichloropropane ug/L ND 1.0 07/21/16 22:560.27
1,4-Dichlorobenzene ug/L ND 1.0 07/21/16 22:560.33
2-Butanone (MEK)ug/L ND 100 07/21/16 22:560.96
2-Hexanone ug/L ND 50.0 07/21/16 22:560.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/21/16 22:560.33
Acetone ug/L ND 100 07/21/16 22:5610.0
Acrylonitrile ug/L ND 200 07/21/16 22:561.9
Benzene ug/L ND 1.0 07/21/16 22:560.25
Bromochloromethane ug/L ND 3.0 07/21/16 22:560.17
Bromodichloromethane ug/L ND 1.0 07/21/16 22:560.18
Bromoform ug/L ND 3.0 07/21/16 22:560.26
Bromomethane ug/L ND 10.0 07/21/16 22:560.29
Carbon disulfide ug/L ND 100 07/21/16 22:561.2
Carbon tetrachloride ug/L ND 1.0 07/21/16 22:560.25
Chlorobenzene ug/L ND 3.0 07/21/16 22:560.23
Chloroethane ug/L ND 10.0 07/21/16 22:560.54
Chloroform ug/L ND 5.0 07/21/16 22:560.14
Chloromethane ug/L ND 1.0 07/21/16 22:560.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/21/16 22:560.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/21/16 22:560.13
Dibromochloromethane ug/L ND 3.0 07/21/16 22:560.21
Dibromomethane ug/L ND 10.0 07/21/16 22:560.21
Ethylbenzene ug/L ND 1.0 07/21/16 22:560.30
Iodomethane ug/L ND 10.0 07/21/16 22:560.32
Methylene Chloride ug/L ND 1.0 07/21/16 22:560.97
Styrene ug/L ND 1.0 07/21/16 22:560.26
Tetrachloroethene ug/L ND 1.0 07/21/16 22:560.46
Toluene ug/L ND 1.0 07/21/16 22:560.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/21/16 22:560.49
trans-1,3-Dichloropropene ug/L ND 1.0 07/21/16 22:560.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1784841
Associated Lab Samples:92305833001, 92305833002
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 07/21/16 22:561.0
Trichloroethene ug/L ND 1.0 07/21/16 22:560.47
Trichlorofluoromethane ug/L ND 1.0 07/21/16 22:560.20
Vinyl acetate ug/L ND 50.0 07/21/16 22:560.35
Vinyl chloride ug/L ND 1.0 07/21/16 22:560.62
Xylene (Total)ug/L ND 5.0 07/21/16 22:560.66
1,2-Dichloroethane-d4 (S)%100 70-130 07/21/16 22:56
4-Bromofluorobenzene (S)%94 70-130 07/21/16 22:56
Toluene-d8 (S)%102 70-130 07/21/16 22:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1784842LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.850 96 80-125
1,1,1-Trichloroethane ug/L 52.350 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.050 100 79-124
1,1,2-Trichloroethane ug/L 50.050 100 85-125
1,1-Dichloroethane ug/L 53.750 107 73-126
1,1-Dichloroethene ug/L 58.450 117 66-135
1,2,3-Trichloropropane ug/L 48.850 98 75-130
1,2-Dibromo-3-chloropropane ug/L 54.950 110 71-133
1,2-Dibromoethane (EDB)ug/L 52.650 105 83-124
1,2-Dichlorobenzene ug/L 51.650 103 80-133
1,2-Dichloroethane ug/L 48.450 97 67-128
1,2-Dichloropropane ug/L 50.750 101 75-132
1,4-Dichlorobenzene ug/L 52.050 104 78-130
2-Butanone (MEK)ug/L 112100 112 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 110100 110 72-135
Acetone ug/L 106100 106 48-146
Acrylonitrile ug/L 293250 117 40-160
Benzene ug/L 52.450 105 80-125
Bromochloromethane ug/L 53.150 106 71-125
Bromodichloromethane ug/L 50.950 102 78-124
Bromoform ug/L 48.150 96 71-128
Bromomethane ug/L 33.150 66 40-160
Carbon disulfide ug/L 55.3J50 111 50-160
Carbon tetrachloride ug/L 51.450 103 69-131
Chlorobenzene ug/L 51.050 102 81-122
Chloroethane ug/L 49.350 99 39-148
Chloroform ug/L 51.950 104 73-127
Chloromethane ug/L 46.850 94 44-146
cis-1,2-Dichloroethene ug/L 55.650 111 74-124
cis-1,3-Dichloropropene ug/L 52.350 105 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1784842LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 50.150 100 78-125
Dibromomethane ug/L 48.850 98 82-120
Ethylbenzene ug/L 49.950 100 79-121
Iodomethane ug/L 71.8100 72 39-154
Methylene Chloride ug/L 56.450 113 64-133
Styrene ug/L 52.050 104 84-126
Tetrachloroethene ug/L 45.750 91 78-122
Toluene ug/L 50.550 101 80-121
trans-1,2-Dichloroethene ug/L 56.950 114 71-127
trans-1,3-Dichloropropene ug/L 51.450 103 69-141
trans-1,4-Dichloro-2-butene ug/L 44.2J50 88 40-160
Trichloroethene ug/L 48.650 97 78-122
Trichlorofluoromethane ug/L 45.650 91 53-137
Vinyl acetate ug/L 107100 107 40-160
Vinyl chloride ug/L 52.050 104 58-137
Xylene (Total)ug/L 147150 98 81-126
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1784843MATRIX SPIKE SAMPLE:
MSSpike
Result
92305830001
1,1,1,2-Tetrachloroethane ug/L 20.520 102 70-130ND
1,1,1-Trichloroethane ug/L 23.420 117 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.020 100 70-130ND
1,1,2-Trichloroethane ug/L 20.520 103 70-130ND
1,1-Dichloroethane ug/L 23.620 118 70-130ND
1,1-Dichloroethene ug/L 25.420 127 70-166ND
1,2,3-Trichloropropane ug/L 19.720 99 70-130ND
1,2-Dibromo-3-chloropropane ug/L 22.120 111 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.020 110 70-130ND
1,2-Dichloroethane ug/L 20.820 103 70-130ND
1,2-Dichloropropane ug/L 22.120 110 70-130ND
1,4-Dichlorobenzene ug/L 21.320 106 70-130ND
2-Butanone (MEK)ug/L 45.9J40 115 70-130ND
2-Hexanone ug/L 42.9J40 107 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 44.9J40 112 70-130ND
Acetone ug/L 46.0J40 111 70-130ND
Acrylonitrile ug/L 115J100 115 70-130ND
Benzene ug/L 22.820 114 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 21.420 107 70-130ND
Bromoform ug/L 18.520 92 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1784843MATRIX SPIKE SAMPLE:
MSSpike
Result
92305830001
Bromomethane ug/L 13.6 M1206870-130ND
Carbon disulfide ug/L 25.4J20 127 70-130ND
Carbon tetrachloride ug/L 23.020 115 70-130ND
Chlorobenzene ug/L 22.020 110 70-146ND
Chloroethane ug/L 22.020 110 70-130ND
Chloroform ug/L 22.820 114 70-130ND
Chloromethane ug/L 21.720 109 70-130ND
cis-1,2-Dichloroethene ug/L 23.820 119 70-130ND
cis-1,3-Dichloropropene ug/L 20.720 104 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 20.620 103 70-130ND
Ethylbenzene ug/L 22.020 110 70-130ND
Iodomethane ug/L 28.740 72 70-130ND
Methylene Chloride ug/L 22.220 111 70-130ND
Styrene ug/L 21.820 109 70-130ND
Tetrachloroethene ug/L 20.020 100 70-130ND
Toluene ug/L 22.020 110 70-155ND
trans-1,2-Dichloroethene ug/L 24.420 122 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.6J20 88 70-130ND
Trichloroethene ug/L 20.820 104 69-151ND
Trichlorofluoromethane ug/L 21.320 107 70-130ND
Vinyl acetate ug/L 35.2J40 88 70-130ND
Vinyl chloride ug/L 22.020 110 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305838001
1784844SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92305838001
1784844SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%104 1103
4-Bromofluorobenzene (S)%93 194
Toluene-d8 (S)%101 0101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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Page 16 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92305833
IREDELL SW-1_5
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92305833001 322123 322331SW-1 EPA 3010A EPA 6010
92305833002 322123 322331SW-5 EPA 3010A EPA 6010
92305833001 322075SW-1 EPA 8260
92305833002 322075SW-5 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/25/2016 02:18 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 17 of 19
Page 18 of 19
Page 19 of 19
#=CL#
October 28, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92317001
92317001
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Iredell Lined 3 & 4
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 21, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 11
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 11
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Lab ID Sample ID Matrix Date Collected Date Received
92317001001 MW-29 Water 10/19/16 12:10 10/21/16 09:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 11
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92317001001 MW-29 EPA 6010 15 PASI-ASER
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 11
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Sample:MW-29 Lab ID:92317001001 Collected:10/19/16 12:10 Received:10/21/16 09:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP, Lab Filtered
Antimony, Dissolved ND ug/L 10/27/16 18:40 7440-36-010/25/16 23:425.0 3.8 1
Arsenic, Dissolved ND ug/L 10/27/16 18:40 7440-38-210/25/16 23:4210.0 5.0 1
Barium, Dissolved 18.9 ug/L 10/27/16 18:40 7440-39-310/25/16 23:425.0 2.5 1
Beryllium, Dissolved 0.41J ug/L 10/27/16 18:40 7440-41-710/25/16 23:421.0 0.050 1
Cadmium, Dissolved ND ug/L 10/27/16 18:40 7440-43-910/25/16 23:421.0 0.50 1
Chromium, Dissolved 2.5J ug/L 10/27/16 18:40 7440-47-310/25/16 23:425.0 2.5 1
Cobalt, Dissolved ND ug/L 10/27/16 18:40 7440-48-410/25/16 23:425.0 2.5 1
Copper, Dissolved ND ug/L 10/27/16 18:40 7440-50-810/25/16 23:425.0 2.5 1
Lead, Dissolved ND ug/L 10/27/16 18:40 7439-92-110/25/16 23:425.0 2.5 1
Nickel, Dissolved ND ug/L 10/27/16 18:40 7440-02-010/25/16 23:425.0 2.5 1
Selenium, Dissolved ND ug/L 10/27/16 18:40 7782-49-210/25/16 23:4210.0 5.0 1
Silver, Dissolved ND ug/L 10/27/16 18:40 7440-22-410/25/16 23:425.0 2.5 1
Thallium, Dissolved ND ug/L 10/27/16 18:40 7440-28-010/25/16 23:4210.0 5.0 1
Vanadium, Dissolved ND ug/L 10/27/16 18:40 7440-62-210/25/16 23:425.0 2.5 1
Zinc, Dissolved ND ug/L 10/27/16 18:40 7440-66-610/25/16 23:4210.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:19 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 11
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
334370
EPA 3010
EPA 6010
6010 MET Filtered Diss.
Associated Lab Samples:92317001001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1853522
Associated Lab Samples:92317001001
Matrix:Water
AnalyzedMDL
Antimony, Dissolved ug/L ND 5.0 10/27/16 18:123.8
Arsenic, Dissolved ug/L ND 10.0 10/27/16 18:125.0
Barium, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Beryllium, Dissolved ug/L ND 1.0 10/27/16 18:120.050
Cadmium, Dissolved ug/L ND 1.0 10/27/16 18:120.50
Chromium, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Cobalt, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Copper, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Lead, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Nickel, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Selenium, Dissolved ug/L ND 10.0 10/27/16 18:125.0
Silver, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Thallium, Dissolved ug/L ND 10.0 10/27/16 18:125.0
Vanadium, Dissolved ug/L ND 5.0 10/27/16 18:122.5
Zinc, Dissolved ug/L ND 10.0 10/27/16 18:122.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1853523LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony, Dissolved ug/L 471500 94 80-120
Arsenic, Dissolved ug/L 466500 93 80-120
Barium, Dissolved ug/L 484500 97 80-120
Beryllium, Dissolved ug/L 480500 96 80-120
Cadmium, Dissolved ug/L 479500 96 80-120
Chromium, Dissolved ug/L 474500 95 80-120
Cobalt, Dissolved ug/L 479500 96 80-120
Copper, Dissolved ug/L 492500 98 80-120
Lead, Dissolved ug/L 472500 94 80-120
Nickel, Dissolved ug/L 471500 94 80-120
Selenium, Dissolved ug/L 480500 96 80-120
Silver, Dissolved ug/L 242250 97 80-120
Thallium, Dissolved ug/L 504500 101 80-120
Vanadium, Dissolved ug/L 474500 95 80-120
Zinc, Dissolved ug/L 484500 97 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 11
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1853524MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92316712009
1853525
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony, Dissolved ug/L 500 89 75-12589 1 20500ND448445
Arsenic, Dissolved ug/L 500 89 75-12588 0 20500ND443441
Barium, Dissolved ug/L 500 91 75-12590 1 2050062.2 518 514
Beryllium, Dissolved ug/L 500 92 75-12591 1 20500ND458455
Cadmium, Dissolved ug/L 500 91 75-12590 0 20500ND453451
Chromium, Dissolved ug/L 500 91 75-12590 1 20500ND456452
Cobalt, Dissolved ug/L 500 91 75-12591 1 205007.3 464 461
Copper, Dissolved ug/L 500 93 75-12592 0 20500ND466464
Lead, Dissolved ug/L 500 89 75-12589 0 20500ND448446
Nickel, Dissolved ug/L 500 89 75-12589 0 205004.5J 451 449
Selenium, Dissolved ug/L 500 91 75-12591 0 20500ND455456
Silver, Dissolved ug/L 250 91 75-12591 0 20250ND228228
Thallium, Dissolved ug/L 500 91 75-12592 0 20500ND457458
Vanadium, Dissolved ug/L 500 90 75-12590 1 20500ND452449
Zinc, Dissolved ug/L 500 93 75-12592 0 20500123587584
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:19 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 7 of 11
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 11
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317001
Iredell Lined 3 & 4
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317001001 334370 334528MW-29 EPA 3010 EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/28/2016 02:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 11
Page 10 of 11
Page 11 of 11
#=CL#
August 23, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92309767
92309767
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
IREDELL BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92306187012 EB Water 07/20/16 15:00 07/22/16 09:57
92306187013 FB Water 07/20/16 15:05 07/22/16 09:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92306187012 EB EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
92306187013 FB EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Sample:EB Lab ID:92306187012 Collected:07/20/16 15:00 Received:07/22/16 09:57 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/29/16 01:21 7440-36-007/26/16 18:306.0 3.8 1
Arsenic ND ug/L 07/29/16 01:21 7440-38-207/26/16 18:3010.0 2.5 1
Barium 3.4J ug/L 07/29/16 01:21 7440-39-307/26/16 18:301002.5 1
Beryllium ND ug/L 07/29/16 01:21 7440-41-707/26/16 18:301.0 0.50 1
Cadmium ND ug/L 07/29/16 01:21 7440-43-907/26/16 18:301.0 0.50 1
Chromium ND ug/L 07/29/16 01:21 7440-47-307/26/16 18:3010.0 2.5 1
Cobalt ND ug/L 07/29/16 01:21 7440-48-407/26/16 18:3010.0 2.5 1
Copper ND ug/L 07/29/16 01:21 7440-50-807/26/16 18:3010.0 2.5 1
Lead ND ug/L 07/29/16 01:21 7439-92-107/26/16 18:3010.0 2.5 1
Nickel ND ug/L 07/29/16 01:21 7440-02-007/26/16 18:3050.0 2.5 1
Selenium ND ug/L 07/29/16 01:21 7782-49-207/26/16 18:3010.0 5.0 1
Silver ND ug/L 07/29/16 01:21 7440-22-407/26/16 18:3010.0 2.5 1
Thallium ND ug/L 07/29/16 01:21 7440-28-007/26/16 18:305.5 5.0 1
Vanadium ND ug/L 07/29/16 01:21 7440-62-207/26/16 18:3025.0 2.5 1
Zinc ND ug/L 07/29/16 01:21 7440-66-607/26/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/25/16 17:23 67-64-110010.0 1
Acrylonitrile ND ug/L 07/25/16 17:23 107-13-12001.9 1
Benzene ND ug/L 07/25/16 17:23 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/25/16 17:23 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/25/16 17:23 75-27-41.0 0.18 1
Bromoform ND ug/L 07/25/16 17:23 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/25/16 17:23 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/25/16 17:23 78-93-31000.96 1
Carbon disulfide ND ug/L 07/25/16 17:23 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/25/16 17:23 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/25/16 17:23 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/25/16 17:23 75-00-310.0 0.54 1
Chloroform ND ug/L 07/25/16 17:23 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/25/16 17:23 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/25/16 17:23 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/25/16 17:23 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/25/16 17:23 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/25/16 17:23 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/25/16 17:23 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/25/16 17:23 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/25/16 17:23 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/25/16 17:23 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/25/16 17:23 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/25/16 17:23 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/25/16 17:23 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/25/16 17:23 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/25/16 17:23 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/25/16 17:23 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/25/16 17:23 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Sample:EB Lab ID:92306187012 Collected:07/20/16 15:00 Received:07/22/16 09:57 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/25/16 17:23 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/25/16 17:23 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/25/16 17:23 74-88-410.0 0.32 1
Methylene Chloride 1.3 ug/L 07/25/16 17:23 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/25/16 17:23 108-10-11000.33 1
Styrene ND ug/L 07/25/16 17:23 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/25/16 17:23 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/25/16 17:23 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/25/16 17:23 127-18-41.0 0.46 1
Toluene ND ug/L 07/25/16 17:23 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/25/16 17:23 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/25/16 17:23 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/25/16 17:23 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/25/16 17:23 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/25/16 17:23 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/25/16 17:23 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/25/16 17:23 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/25/16 17:23 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %07/25/16 17:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %07/25/16 17:23 17060-07-070-130 1
Toluene-d8 (S)102 %07/25/16 17:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Sample:FB Lab ID:92306187013 Collected:07/20/16 15:05 Received:07/22/16 09:57 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 07/29/16 01:24 7440-36-007/26/16 18:306.0 3.8 1
Arsenic ND ug/L 07/29/16 01:24 7440-38-207/26/16 18:3010.0 2.5 1
Barium 3.3J ug/L 07/29/16 01:24 7440-39-307/26/16 18:301002.5 1
Beryllium ND ug/L 07/29/16 01:24 7440-41-707/26/16 18:301.0 0.50 1
Cadmium ND ug/L 07/29/16 01:24 7440-43-907/26/16 18:301.0 0.50 1
Chromium ND ug/L 07/29/16 01:24 7440-47-307/26/16 18:3010.0 2.5 1
Cobalt ND ug/L 07/29/16 01:24 7440-48-407/26/16 18:3010.0 2.5 1
Copper ND ug/L 07/29/16 01:24 7440-50-807/26/16 18:3010.0 2.5 1
Lead ND ug/L 07/29/16 01:24 7439-92-107/26/16 18:3010.0 2.5 1
Nickel ND ug/L 07/29/16 01:24 7440-02-007/26/16 18:3050.0 2.5 1
Selenium ND ug/L 07/29/16 01:24 7782-49-207/26/16 18:3010.0 5.0 1
Silver ND ug/L 07/29/16 01:24 7440-22-407/26/16 18:3010.0 2.5 1
Thallium ND ug/L 07/29/16 01:24 7440-28-007/26/16 18:305.5 5.0 1
Vanadium ND ug/L 07/29/16 01:24 7440-62-207/26/16 18:3025.0 2.5 1
Zinc ND ug/L 07/29/16 01:24 7440-66-607/26/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 07/25/16 17:40 67-64-110010.0 1
Acrylonitrile ND ug/L 07/25/16 17:40 107-13-12001.9 1
Benzene ND ug/L 07/25/16 17:40 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 07/25/16 17:40 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 07/25/16 17:40 75-27-41.0 0.18 1
Bromoform ND ug/L 07/25/16 17:40 75-25-23.0 0.26 1
Bromomethane ND ug/L 07/25/16 17:40 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 07/25/16 17:40 78-93-31000.96 1
Carbon disulfide ND ug/L 07/25/16 17:40 75-15-01001.2 1
Carbon tetrachloride ND ug/L 07/25/16 17:40 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 07/25/16 17:40 108-90-73.0 0.23 1
Chloroethane ND ug/L 07/25/16 17:40 75-00-310.0 0.54 1
Chloroform ND ug/L 07/25/16 17:40 67-66-35.0 0.14 1
Chloromethane ND ug/L 07/25/16 17:40 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 07/25/16 17:40 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 07/25/16 17:40 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 07/25/16 17:40 106-93-41.0 0.27 1
Dibromomethane ND ug/L 07/25/16 17:40 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 07/25/16 17:40 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 07/25/16 17:40 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 07/25/16 17:40 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 07/25/16 17:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 07/25/16 17:40 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 07/25/16 17:40 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 07/25/16 17:40 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 07/25/16 17:40 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 07/25/16 17:40 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 07/25/16 17:40 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 07/25/16 17:40 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
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Page 7 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Sample:FB Lab ID:92306187013 Collected:07/20/16 15:05 Received:07/22/16 09:57 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 07/25/16 17:40 100-41-41.0 0.30 1
2-Hexanone ND ug/L 07/25/16 17:40 591-78-650.0 0.46 1
Iodomethane ND ug/L 07/25/16 17:40 74-88-410.0 0.32 1
Methylene Chloride 1.0 ug/L 07/25/16 17:40 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 07/25/16 17:40 108-10-11000.33 1
Styrene ND ug/L 07/25/16 17:40 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 07/25/16 17:40 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 07/25/16 17:40 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 07/25/16 17:40 127-18-41.0 0.46 1
Toluene ND ug/L 07/25/16 17:40 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 07/25/16 17:40 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 07/25/16 17:40 79-00-51.0 0.29 1
Trichloroethene ND ug/L 07/25/16 17:40 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 07/25/16 17:40 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 07/25/16 17:40 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 07/25/16 17:40 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 07/25/16 17:40 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 07/25/16 17:40 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %07/25/16 17:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %07/25/16 17:40 17060-07-070-130 1
Toluene-d8 (S)102 %07/25/16 17:40 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
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Page 8 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322501
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92306187012, 92306187013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1786911
Associated Lab Samples:92306187012, 92306187013
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 07/29/16 00:133.8
Arsenic ug/L ND 10.0 07/29/16 00:132.5
Barium ug/L ND 100 07/29/16 00:132.5
Beryllium ug/L ND 1.0 07/29/16 00:130.50
Cadmium ug/L ND 1.0 07/29/16 00:130.50
Chromium ug/L ND 10.0 07/29/16 00:132.5
Cobalt ug/L ND 10.0 07/29/16 00:132.5
Copper ug/L ND 10.0 07/29/16 00:132.5
Lead ug/L ND 10.0 07/29/16 14:502.5
Nickel ug/L ND 50.0 07/29/16 00:132.5
Selenium ug/L ND 10.0 07/29/16 00:135.0
Silver ug/L ND 10.0 07/29/16 00:132.5
Thallium ug/L ND 5.5 07/29/16 00:135.0
Vanadium ug/L ND 25.0 07/29/16 00:132.5
Zinc ug/L ND 10.0 07/29/16 00:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1786912LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 476500 95 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 536500 107 80-120
Beryllium ug/L 497500 99 80-120
Cadmium ug/L 499500 100 80-120
Chromium ug/L 515500 103 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 507500 101 80-120
Lead ug/L 501500 100 80-120
Nickel ug/L 498500 100 80-120
Selenium ug/L 479500 96 80-120
Silver ug/L 249250 100 80-120
Thallium ug/L 499500 100 80-120
Vanadium ug/L 503500 101 80-120
Zinc ug/L 491500 98 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1786913MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92306179001
1786914
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 86 75-12589 4 25500ND429447
Arsenic ug/L 500 89 75-12593 5 25500ND445466
Barium ug/L 500 105 75-125106 1 25500120643652
Beryllium ug/L 500 97 75-12599 3 255000.67J 484 496
Cadmium ug/L 500 95 75-12599 3 2550012.5 489 505
Chromium ug/L 500 99 75-125104 5 2550013.1 508 532
Cobalt ug/L 500 93 75-12596 3 255004.7J 470 484
Copper ug/L 500 99 75-125101 2 255008.7J 502 515
Lead ug/L 500 95 75-12599 4 255005.1J 480 499
Nickel ug/L 500 96 75-12599 4 255005.8J 483 502
Selenium ug/L 500 90 75-12593 4 25500ND450466
Silver ug/L 250 95 75-12598 3 25250ND238246
Thallium ug/L 500 96 75-12599 3 25500ND480495
Vanadium ug/L 500 97 75-125100 3 2550018.3J 501 517
Zinc ug/L 500 93 75-12596 3 2550027.6 492 506
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322427
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92306187012, 92306187013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1786595
Associated Lab Samples:92306187012, 92306187013
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/25/16 11:590.33
1,1,1-Trichloroethane ug/L ND 1.0 07/25/16 11:590.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 07/25/16 11:590.40
1,1,2-Trichloroethane ug/L ND 1.0 07/25/16 11:590.29
1,1-Dichloroethane ug/L ND 5.0 07/25/16 11:590.32
1,1-Dichloroethene ug/L ND 5.0 07/25/16 11:590.56
1,2,3-Trichloropropane ug/L ND 1.0 07/25/16 11:590.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 07/25/16 11:592.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 07/25/16 11:590.27
1,2-Dichlorobenzene ug/L ND 5.0 07/25/16 11:590.30
1,2-Dichloroethane ug/L ND 1.0 07/25/16 11:590.24
1,2-Dichloropropane ug/L ND 1.0 07/25/16 11:590.27
1,4-Dichlorobenzene ug/L ND 1.0 07/25/16 11:590.33
2-Butanone (MEK)ug/L ND 100 07/25/16 11:590.96
2-Hexanone ug/L ND 50.0 07/25/16 11:590.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 07/25/16 11:590.33
Acetone ug/L ND 100 07/25/16 11:5910.0
Acrylonitrile ug/L ND 200 07/25/16 11:591.9
Benzene ug/L ND 1.0 07/25/16 11:590.25
Bromochloromethane ug/L ND 3.0 07/25/16 11:590.17
Bromodichloromethane ug/L ND 1.0 07/25/16 11:590.18
Bromoform ug/L ND 3.0 07/25/16 11:590.26
Bromomethane ug/L ND 10.0 07/25/16 11:590.29
Carbon disulfide ug/L ND 100 07/25/16 11:591.2
Carbon tetrachloride ug/L ND 1.0 07/25/16 11:590.25
Chlorobenzene ug/L ND 3.0 07/25/16 11:590.23
Chloroethane ug/L ND 10.0 07/25/16 11:590.54
Chloroform ug/L ND 5.0 07/25/16 11:590.14
Chloromethane ug/L ND 1.0 07/25/16 11:590.11
cis-1,2-Dichloroethene ug/L ND 5.0 07/25/16 11:590.19
cis-1,3-Dichloropropene ug/L ND 1.0 07/25/16 11:590.13
Dibromochloromethane ug/L ND 3.0 07/25/16 11:590.21
Dibromomethane ug/L ND 10.0 07/25/16 11:590.21
Ethylbenzene ug/L ND 1.0 07/25/16 11:590.30
Iodomethane ug/L ND 10.0 07/25/16 11:590.32
Methylene Chloride ug/L ND 1.0 07/25/16 11:590.97
Styrene ug/L ND 1.0 07/25/16 11:590.26
Tetrachloroethene ug/L ND 1.0 07/25/16 11:590.46
Toluene ug/L ND 1.0 07/25/16 11:590.26
trans-1,2-Dichloroethene ug/L ND 5.0 07/25/16 11:590.49
trans-1,3-Dichloropropene ug/L ND 1.0 07/25/16 11:590.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1786595
Associated Lab Samples:92306187012, 92306187013
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 07/25/16 11:591.0
Trichloroethene ug/L ND 1.0 07/25/16 11:590.47
Trichlorofluoromethane ug/L ND 1.0 07/25/16 11:590.20
Vinyl acetate ug/L ND 50.0 07/25/16 11:590.35
Vinyl chloride ug/L ND 1.0 07/25/16 11:590.62
Xylene (Total)ug/L ND 5.0 07/25/16 11:590.66
1,2-Dichloroethane-d4 (S)%92 70-130 07/25/16 11:59
4-Bromofluorobenzene (S)%100 70-130 07/25/16 11:59
Toluene-d8 (S)%103 70-130 07/25/16 11:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1786596LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.650 95 80-125
1,1,1-Trichloroethane ug/L 43.250 86 71-129
1,1,2,2-Tetrachloroethane ug/L 45.250 90 79-124
1,1,2-Trichloroethane ug/L 46.350 93 85-125
1,1-Dichloroethane ug/L 42.350 85 73-126
1,1-Dichloroethene ug/L 41.250 82 66-135
1,2,3-Trichloropropane ug/L 43.750 87 75-130
1,2-Dibromo-3-chloropropane ug/L 47.350 95 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 47.950 96 80-133
1,2-Dichloroethane ug/L 40.350 81 67-128
1,2-Dichloropropane ug/L 44.050 88 75-132
1,4-Dichlorobenzene ug/L 48.750 97 78-130
2-Butanone (MEK)ug/L 102100 102 61-144
2-Hexanone ug/L 106100 106 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 96.6J100 97 48-146
Acrylonitrile ug/L 220250 88 40-160
Benzene ug/L 45.250 90 80-125
Bromochloromethane ug/L 43.850 88 71-125
Bromodichloromethane ug/L 42.950 86 78-124
Bromoform ug/L 43.550 87 71-128
Bromomethane ug/L 33.950 68 40-160
Carbon disulfide ug/L 51.0J50 102 50-160
Carbon tetrachloride ug/L 44.250 88 69-131
Chlorobenzene ug/L 48.250 96 81-122
Chloroethane ug/L 35.650 71 39-148
Chloroform ug/L 42.050 84 73-127
Chloromethane ug/L 42.250 84 44-146
cis-1,2-Dichloroethene ug/L 43.150 86 74-124
cis-1,3-Dichloropropene ug/L 47.450 95 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
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[phone]
Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1786596LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 48.850 98 78-125
Dibromomethane ug/L 46.650 93 82-120
Ethylbenzene ug/L 45.250 90 79-121
Iodomethane ug/L 96.3100 96 39-154
Methylene Chloride ug/L 43.250 86 64-133
Styrene ug/L 48.350 97 84-126
Tetrachloroethene ug/L 45.050 90 78-122
Toluene ug/L 44.450 89 80-121
trans-1,2-Dichloroethene ug/L 43.850 88 71-127
trans-1,3-Dichloropropene ug/L 47.250 94 69-141
trans-1,4-Dichloro-2-butene ug/L 61.0J50 122 40-160
Trichloroethene ug/L 44.750 89 78-122
Trichlorofluoromethane ug/L 37.450 75 53-137
Vinyl acetate ug/L 85.2100 85 40-160
Vinyl chloride ug/L 42.450 85 58-137
Xylene (Total)ug/L 134150 89 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1786598MATRIX SPIKE SAMPLE:
MSSpike
Result
92306187011
1,1,1,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,1-Trichloroethane ug/L 21.320 106 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.120 100 70-130ND
1,1,2-Trichloroethane ug/L 21.420 107 70-130ND
1,1-Dichloroethane ug/L 20.920 104 70-130ND
1,1-Dichloroethene ug/L 21.220 106 70-166ND
1,2,3-Trichloropropane ug/L 20.220 101 70-130ND
1,2-Dibromo-3-chloropropane ug/L 22.220 111 70-130ND
1,2-Dibromoethane (EDB)ug/L 23.620 118 70-130ND
1,2-Dichlorobenzene ug/L 22.520 113 70-130ND
1,2-Dichloroethane ug/L 19.920 99 70-130ND
1,2-Dichloropropane ug/L 21.320 107 70-130ND
1,4-Dichlorobenzene ug/L 22.420 112 70-130ND
2-Butanone (MEK)ug/L 43.0J40 107 70-130ND
2-Hexanone ug/L 43.0J40 107 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.6J40 104 70-130ND
Acetone ug/L 38.5J40 96 70-130ND
Acrylonitrile ug/L 101J100 101 70-130ND
Benzene ug/L 22.220 111 70-148ND
Bromochloromethane ug/L 22.920 115 70-130ND
Bromodichloromethane ug/L 20.620 103 70-130ND
Bromoform ug/L 19.920 99 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
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Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1786598MATRIX SPIKE SAMPLE:
MSSpike
Result
92306187011
Bromomethane ug/L 18.020 90 70-130ND
Carbon disulfide ug/L 16.5J20 82 70-130ND
Carbon tetrachloride ug/L 21.820 109 70-130ND
Chlorobenzene ug/L 23.120 115 70-146ND
Chloroethane ug/L 20.320 101 70-130ND
Chloroform ug/L 20.920 105 70-130ND
Chloromethane ug/L 20.920 105 70-130ND
cis-1,2-Dichloroethene ug/L 21.920 110 70-130ND
cis-1,3-Dichloropropene ug/L 20.820 104 70-130ND
Dibromochloromethane ug/L 21.720 108 70-130ND
Dibromomethane ug/L 21.820 109 70-130ND
Ethylbenzene ug/L 21.820 109 70-130ND
Iodomethane ug/L 41.640 104 70-130ND
Methylene Chloride ug/L 21.120 105 70-130ND
Styrene ug/L 22.920 115 70-130ND
Tetrachloroethene ug/L 22.120 110 70-130ND
Toluene ug/L 21.720 109 70-155ND
trans-1,2-Dichloroethene ug/L 20.820 104 70-130ND
trans-1,3-Dichloropropene ug/L 19.820 99 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.0J20 95 70-130ND
Trichloroethene ug/L 22.520 113 69-151ND
Trichlorofluoromethane ug/L 21.320 107 70-130ND
Vinyl acetate ug/L 29.5J40 74 70-130ND
Vinyl chloride ug/L 21.720 109 70-130ND
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92306187010
1786597SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92306187010
1786597SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 300.28J
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%94 292
4-Bromofluorobenzene (S)%100 1101
Toluene-d8 (S)%103 2100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92309767
IREDELL BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92309767
IREDELL BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92306187012 322501 322671EBEPA 3010A EPA 6010
92306187013 322501 322671FBEPA 3010A EPA 6010
92306187012 322427EBEPA 8260
92306187013 322427FBEPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:36 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
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Page 20 of 20
Appendix B
Field Sampling Parameter Data Sheet(s)