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HomeMy WebLinkAbout7602_EnergizerBattery_AnalyticalResults_DIN28303_20160825ANALYTICAL REPORT October 06, 2016 Pyramid Environmental Sample Delivery Group:L855921 Samples Received:08/26/2016 Project Number:2016-224 Description:Energizer Landfill Report To:Brett Higgins 503 Industrial Avenue Greensboro, NC 27406 Entire Report Reviewed By: October 06, 2016 [Preliminary Report] Terrie Fudge Technical Service Representative Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.esclabsciences.com October 07, 2016 Terrie Fudge Technical Service Representative ONE LAB. NATIONWIDE.TABLE OF CONTENTS ¹Cp: Cover Page 1 ²Tc: Table of Contents 2 ³Ss: Sample Summary 3 ⁴Cn: Case Narrative 4 ⁵Sr: Sample Results 5 CELL #1 LEACHATE L855921-01 5 CELL #2 LEACHATE L855921-02 8 ⁶Qc: Quality Control Summary 11 Gravimetric Analysis by Method 2540 C-2011 11 Wet Chemistry by Method 365.4 12 Wet Chemistry by Method 410.4 13 Wet Chemistry by Method 5210 B-2011 14 Wet Chemistry by Method 9040C 16 Wet Chemistry by Method 9056A 17 Mercury by Method 7470A 19 Metals (ICP) by Method 6010C 20 Metals (ICPMS) by Method 6020 22 Volatile Organic Compounds (GC/MS) by Method 8260B 23 ⁷Gl: Glossary of Terms 28 ⁸Al: Accreditations & Locations 29 ⁹Sc: Chain of Custody 30 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 2 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 2 of 31 ONE LAB. NATIONWIDE.SAMPLE SUMMARY Collected by Collected date/time Received date/time CELL #1 LEACHATE L855921-01 GW Hubert McAvinney 08/25/16 12:25 08/26/16 09:00 Method Batch Dilution Preparation Analysis Analyst date/time date/time Gravimetric Analysis by Method 2540 C-2011 WG903430 1 08/31/16 05:31 08/31/16 05:53 JM Mercury by Method 7470A WG902680 100 08/26/16 14:19 08/27/16 07:28 TRB Metals (ICP) by Method 6010C WG902958 1 08/30/16 12:47 08/30/16 19:43 RDS Metals (ICP) by Method 6010C WG902958 1 08/30/16 12:47 08/31/16 09:18 RDS Metals (ICPMS) by Method 6020 WG904394 1 09/01/16 18:05 09/02/16 16:34 ST Metals (ICPMS) by Method 6020 WG904394 5 09/01/16 18:05 09/02/16 19:26 ST Volatile Organic Compounds (GC/MS) by Method 8260B WG902864 1 09/02/16 00:22 09/02/16 00:22 JHH Wet Chemistry by Method 365.4 WG902940 1 08/29/16 16:46 08/30/16 21:05 ADH Wet Chemistry by Method 410.4 WG902731 1 08/26/16 16:14 08/26/16 19:42 MZ Wet Chemistry by Method 5210 B-2011 WG902579 1 08/26/16 12:38 08/31/16 09:37 ARM Wet Chemistry by Method 9040C WG902224 1 08/29/16 12:38 08/29/16 12:38 MHM Wet Chemistry by Method 9056A WG902236 1 08/26/16 12:32 08/26/16 12:32 SAM Collected by Collected date/time Received date/time CELL #2 LEACHATE L855921-02 GW Hubert McAvinney 08/25/16 11:45 08/26/16 09:00 Method Batch Dilution Preparation Analysis Analyst date/time date/time Gravimetric Analysis by Method 2540 C-2011 WG903430 1 08/31/16 05:31 08/31/16 05:53 JM Mercury by Method 7470A WG902680 20 08/26/16 14:19 08/27/16 08:36 TRB Metals (ICP) by Method 6010C WG902958 9 08/30/16 12:47 08/30/16 19:46 RDS Metals (ICP) by Method 6010C WG902958 9 08/30/16 12:47 08/31/16 09:21 RDS Metals (ICPMS) by Method 6020 WG904394 9 09/01/16 18:05 09/02/16 16:37 ST Volatile Organic Compounds (GC/MS) by Method 8260B WG902864 1 09/02/16 00:43 09/02/16 00:43 JHH Wet Chemistry by Method 365.4 WG902940 1 08/29/16 16:46 08/30/16 21:06 ADH Wet Chemistry by Method 410.4 WG902731 1 08/26/16 16:14 08/26/16 19:42 MZ Wet Chemistry by Method 5210 B-2011 WG902579 10 08/26/16 12:42 08/31/16 09:39 ARM Wet Chemistry by Method 9040C WG902224 1 08/29/16 12:38 08/29/16 12:38 MHM Wet Chemistry by Method 9056A WG902236 1 08/26/16 12:46 08/26/16 12:46 SAM 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 3 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 3 of 31 ONE LAB. NATIONWIDE.CASE NARRATIVE All MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. [Preliminary Report] Terrie Fudge Technical Service Representative Sample Handling and Receiving The following samples were prepared and/or analyzed past recommended holding time. Concentrations should be considered minimum values. ESC Sample ID Project Sample ID Method L855921-01 CELL #1 LEACHATE 9040C L855921-02 CELL #2 LEACHATE 9040C The following analysis were performed from an unpreserved, insufficiently or inadequately preserved sample. ESC Sample ID Project Sample ID Method L855921-02 CELL #2 LEACHATE 6010C, 6020, 7470A 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 4 of 31 Terrie Fudge Technical Service Representative ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 4 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01 L855921 CELL #1 LEACHATE Collected date/time: 08/25/16 12:25 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Dissolved Solids 2170 2.82 10.0 1 08/31/2016 05:53 WG903430 Wet Chemistry by Method 365.4 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Phosphorus,Total 0.0509 J 0.0350 0.100 1 08/30/2016 21:05 WG902940 Wet Chemistry by Method 410.4 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time COD 302 3.00 10.0 1 08/26/2016 19:42 WG902731 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/l mg/l date / time BOD U 3.33 1 08/31/2016 09:37 WG902579 Wet Chemistry by Method 9040C Result Qualifier Dilution Analysis Batch Analyte su date / time pH 8.86 1 08/29/2016 12:38 WG902224 Sample Narrative: 9040C L855921-01 WG902224: 8.86 at 12.5c Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Nitrate 1.68 0.0227 0.100 1 08/26/2016 12:32 WG902236 Sulfate 2.30 J 0.0774 5.00 1 08/26/2016 12:32 WG902236 Mercury by Method 7470A Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Mercury 0.169 V 0.00490 0.0200 100 08/27/2016 07:28 WG902680 Metals (ICP) by Method 6010C Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Barium 0.499 0.00170 0.00500 1 08/30/2016 19:43 WG902958 Beryllium U 0.000700 0.00200 1 08/30/2016 19:43 WG902958 Cadmium 0.0385 0.000700 0.00200 1 08/30/2016 19:43 WG902958 Chromium 0.00284 B J 0.00140 0.0100 1 08/30/2016 19:43 WG902958 Cobalt 0.00375 J 0.00230 0.0100 1 08/30/2016 19:43 WG902958 Copper 3.98 0.00530 0.0100 1 08/30/2016 19:43 WG902958 Nickel 0.0314 0.00490 0.0100 1 08/31/2016 09:18 WG902958 Selenium U 0.00740 0.0100 1 08/30/2016 19:43 WG902958 Silver U 0.00280 0.00500 1 08/30/2016 19:43 WG902958 Vanadium U 0.00240 0.0200 1 08/30/2016 19:43 WG902958 Zinc 5.74 0.00590 0.0500 1 08/30/2016 19:43 WG902958 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 5 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 5 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01 L855921 CELL #1 LEACHATE Collected date/time: 08/25/16 12:25 Metals (ICPMS) by Method 6020 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Antimony 0.000942 J 0.000754 0.00200 1 09/02/2016 16:34 WG904394 Arsenic 0.00102 J 0.000250 0.00200 1 09/02/2016 16:34 WG904394 Lead U 0.000240 0.00200 1 09/02/2016 16:34 WG904394 Thallium 0.00408 J 0.000950 0.0100 5 09/02/2016 19:26 WG904394 Volatile Organic Compounds (GC/MS) by Method 8260B Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Acetone 0.0259 J 0.0100 0.0500 1 09/02/2016 00:22 WG902864 Benzene U 0.000331 0.00100 1 09/02/2016 00:22 WG902864 Bromochloromethane U 0.000520 0.00100 1 09/02/2016 00:22 WG902864 Bromodichloromethane U 0.000380 0.00100 1 09/02/2016 00:22 WG902864 Bromoform U 0.000469 0.00100 1 09/02/2016 00:22 WG902864 Bromomethane U 0.000866 0.00500 1 09/02/2016 00:22 WG902864 Carbon disulfide U 0.000275 0.00100 1 09/02/2016 00:22 WG902864 Carbon tetrachloride U 0.000379 0.00100 1 09/02/2016 00:22 WG902864 Chlorobenzene U 0.000348 0.00100 1 09/02/2016 00:22 WG902864 Chlorodibromomethane U 0.000327 0.00100 1 09/02/2016 00:22 WG902864 Chloroethane U 0.000453 0.00500 1 09/02/2016 00:22 WG902864 Chloroform U 0.000324 0.00500 1 09/02/2016 00:22 WG902864 Chloromethane U 0.000276 0.00250 1 09/02/2016 00:22 WG902864 Cyclohexane U 0.000390 0.00100 1 09/02/2016 00:22 WG902864 1,2-Dibromo-3-Chloropropane U 0.00133 0.00500 1 09/02/2016 00:22 WG902864 Dibromomethane U 0.000346 0.00100 1 09/02/2016 00:22 WG902864 1,2-Dibromoethane U 0.000381 0.00100 1 09/02/2016 00:22 WG902864 1,2-Dichlorobenzene U 0.000349 0.00100 1 09/02/2016 00:22 WG902864 1,3-Dichlorobenzene U 0.000220 0.00100 1 09/02/2016 00:22 WG902864 1,4-Dichlorobenzene U 0.000274 0.00100 1 09/02/2016 00:22 WG902864 Dichlorodifluoromethane U 0.000551 0.00500 1 09/02/2016 00:22 WG902864 1,1-Dichloroethane U 0.000259 0.00100 1 09/02/2016 00:22 WG902864 1,2-Dichloroethane 0.00465 0.000361 0.00100 1 09/02/2016 00:22 WG902864 1,1-Dichloroethene U 0.000398 0.00100 1 09/02/2016 00:22 WG902864 cis-1,2-Dichloroethene U 0.000260 0.00100 1 09/02/2016 00:22 WG902864 trans-1,2-Dichloroethene U 0.000396 0.00100 1 09/02/2016 00:22 WG902864 1,2-Dichloropropane U 0.000306 0.00100 1 09/02/2016 00:22 WG902864 cis-1,3-Dichloropropene U 0.000418 0.00100 1 09/02/2016 00:22 WG902864 trans-1,3-Dichloropropene U 0.000419 0.00100 1 09/02/2016 00:22 WG902864 Ethylbenzene U 0.000384 0.00100 1 09/02/2016 00:22 WG902864 2-Hexanone U 0.00382 0.0100 1 09/02/2016 00:22 WG902864 Iodomethane U 0.00171 0.0100 1 09/02/2016 00:22 WG902864 Isopropylbenzene U 0.000326 0.00100 1 09/02/2016 00:22 WG902864 2-Butanone (MEK)0.123 0.00393 0.0100 1 09/02/2016 00:22 WG902864 Methyl Acetate U 0.00430 0.0200 1 09/02/2016 00:22 WG902864 Methyl Cyclohexane U 0.000380 0.00100 1 09/02/2016 00:22 WG902864 Methylene Chloride U 0.00100 0.00500 1 09/02/2016 00:22 WG902864 4-Methyl-2-pentanone (MIBK)U 0.00214 0.0100 1 09/02/2016 00:22 WG902864 Methyl tert-butyl ether U 0.000367 0.00100 1 09/02/2016 00:22 WG902864 Styrene U 0.000307 0.00100 1 09/02/2016 00:22 WG902864 1,1,1,2-Tetrachloroethane U 0.000385 0.00100 1 09/02/2016 00:22 WG902864 1,1,2,2-Tetrachloroethane U 0.000130 0.00100 1 09/02/2016 00:22 WG902864 Tetrachloroethene U 0.000372 0.00100 1 09/02/2016 00:22 WG902864 Toluene U 0.000780 0.00500 1 09/02/2016 00:22 WG902864 1,2,3-Trichlorobenzene U 0.000230 0.00100 1 09/02/2016 00:22 WG902864 1,2,4-Trichlorobenzene U 0.000355 0.00100 1 09/02/2016 00:22 WG902864 1,1,1-Trichloroethane U 0.000319 0.00100 1 09/02/2016 00:22 WG902864 1,1,2-Trichloroethane U 0.000383 0.00100 1 09/02/2016 00:22 WG902864 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 6 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 6 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01 L855921 CELL #1 LEACHATE Collected date/time: 08/25/16 12:25 Volatile Organic Compounds (GC/MS) by Method 8260B Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Trichloroethene U 0.000398 0.00100 1 09/02/2016 00:22 WG902864 Trichlorofluoromethane U 0.00120 0.00500 1 09/02/2016 00:22 WG902864 1,1,2-Trichlorotrifluoroethane U 0.000303 0.00100 1 09/02/2016 00:22 WG902864 1,2,3-Trichloropropane U 0.000807 0.00250 1 09/02/2016 00:22 WG902864 Vinyl acetate U 0.00163 0.0100 1 09/02/2016 00:22 WG902864 Vinyl chloride U 0.000259 0.00100 1 09/02/2016 00:22 WG902864 Xylenes, Total 0.00215 J 0.00106 0.00300 1 09/02/2016 00:22 WG902864 trans-1,4-Dichloro-2-butene U 0.000866 0.00250 1 09/02/2016 00:22 WG902864 (S) Toluene-d8 106 90.0-115 09/02/2016 00:22 WG902864 (S) Dibromofluoromethane 108 79.0-121 09/02/2016 00:22 WG902864 (S) a,a,a-Trifluorotoluene 102 90.4-116 09/02/2016 00:22 WG902864 (S) 4-Bromofluorobenzene 95.4 80.1-120 09/02/2016 00:22 WG902864 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 7 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 7 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02 L855921 CELL #2 LEACHATE Collected date/time: 08/25/16 11:45 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Dissolved Solids 19600 2.82 10.0 1 08/31/2016 05:53 WG903430 Wet Chemistry by Method 365.4 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Phosphorus,Total 1.03 0.0350 0.100 1 08/30/2016 21:06 WG902940 Wet Chemistry by Method 410.4 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time COD 761 3.00 10.0 1 08/26/2016 19:42 WG902731 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/l mg/l date / time BOD 103 33.3 10 08/31/2016 09:39 WG902579 Wet Chemistry by Method 9040C Result Qualifier Dilution Analysis Batch Analyte su date / time pH 10.9 1 08/29/2016 12:38 WG902224 Sample Narrative: 9040C L855921-02 WG902224: 10.92 at 13.2c Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Nitrate 1.95 0.0227 0.100 1 08/26/2016 12:46 WG902236 Sulfate 93.8 0.0774 5.00 1 08/26/2016 12:46 WG902236 Mercury by Method 7470A Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Mercury 0.133 0.000980 0.00400 20 08/27/2016 08:36 WG902680 Metals (ICP) by Method 6010C Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Barium U 0.0153 0.0450 9 08/30/2016 19:46 WG902958 Beryllium U 0.00630 0.0180 9 08/30/2016 19:46 WG902958 Cadmium U 0.00630 0.0180 9 08/30/2016 19:46 WG902958 Chromium 0.0240 B J 0.0126 0.0900 9 08/30/2016 19:46 WG902958 Cobalt 0.0401 J 0.0207 0.0900 9 08/30/2016 19:46 WG902958 Copper 2.50 0.0477 0.0900 9 08/30/2016 19:46 WG902958 Nickel 0.175 0.0441 0.0900 9 08/31/2016 09:21 WG902958 Selenium U 0.0666 0.0900 9 08/30/2016 19:46 WG902958 Silver U 0.0252 0.0450 9 08/30/2016 19:46 WG902958 Vanadium 0.525 0.0216 0.180 9 08/30/2016 19:46 WG902958 Zinc 3.57 0.0531 0.450 9 08/30/2016 19:46 WG902958 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 8 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 8 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02 L855921 CELL #2 LEACHATE Collected date/time: 08/25/16 11:45 Metals (ICPMS) by Method 6020 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Antimony U 0.00679 0.0180 9 09/02/2016 16:37 WG904394 Arsenic 0.141 0.00225 0.0180 9 09/02/2016 16:37 WG904394 Lead U 0.00216 0.0180 9 09/02/2016 16:37 WG904394 Thallium U 0.00171 0.0180 9 09/02/2016 16:37 WG904394 Volatile Organic Compounds (GC/MS) by Method 8260B Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Acetone 0.267 0.0100 0.0500 1 09/02/2016 00:43 WG902864 Benzene U 0.000331 0.00100 1 09/02/2016 00:43 WG902864 Bromochloromethane U 0.000520 0.00100 1 09/02/2016 00:43 WG902864 Bromodichloromethane U 0.000380 0.00100 1 09/02/2016 00:43 WG902864 Bromoform U 0.000469 0.00100 1 09/02/2016 00:43 WG902864 Bromomethane U 0.000866 0.00500 1 09/02/2016 00:43 WG902864 Carbon disulfide U 0.000275 0.00100 1 09/02/2016 00:43 WG902864 Carbon tetrachloride U 0.000379 0.00100 1 09/02/2016 00:43 WG902864 Chlorobenzene U 0.000348 0.00100 1 09/02/2016 00:43 WG902864 Chlorodibromomethane U 0.000327 0.00100 1 09/02/2016 00:43 WG902864 Chloroethane U 0.000453 0.00500 1 09/02/2016 00:43 WG902864 Chloroform U 0.000324 0.00500 1 09/02/2016 00:43 WG902864 Chloromethane U 0.000276 0.00250 1 09/02/2016 00:43 WG902864 Cyclohexane U 0.000390 0.00100 1 09/02/2016 00:43 WG902864 1,2-Dibromo-3-Chloropropane U 0.00133 0.00500 1 09/02/2016 00:43 WG902864 Dibromomethane U 0.000346 0.00100 1 09/02/2016 00:43 WG902864 1,2-Dibromoethane U 0.000381 0.00100 1 09/02/2016 00:43 WG902864 1,2-Dichlorobenzene U 0.000349 0.00100 1 09/02/2016 00:43 WG902864 1,3-Dichlorobenzene U 0.000220 0.00100 1 09/02/2016 00:43 WG902864 1,4-Dichlorobenzene U 0.000274 0.00100 1 09/02/2016 00:43 WG902864 Dichlorodifluoromethane U 0.000551 0.00500 1 09/02/2016 00:43 WG902864 1,1-Dichloroethane U 0.000259 0.00100 1 09/02/2016 00:43 WG902864 1,2-Dichloroethane 0.00205 0.000361 0.00100 1 09/02/2016 00:43 WG902864 1,1-Dichloroethene U 0.000398 0.00100 1 09/02/2016 00:43 WG902864 cis-1,2-Dichloroethene U 0.000260 0.00100 1 09/02/2016 00:43 WG902864 trans-1,2-Dichloroethene U 0.000396 0.00100 1 09/02/2016 00:43 WG902864 1,2-Dichloropropane U 0.000306 0.00100 1 09/02/2016 00:43 WG902864 cis-1,3-Dichloropropene U 0.000418 0.00100 1 09/02/2016 00:43 WG902864 trans-1,3-Dichloropropene U 0.000419 0.00100 1 09/02/2016 00:43 WG902864 Ethylbenzene 0.00119 0.000384 0.00100 1 09/02/2016 00:43 WG902864 2-Hexanone U 0.00382 0.0100 1 09/02/2016 00:43 WG902864 Iodomethane U 0.00171 0.0100 1 09/02/2016 00:43 WG902864 Isopropylbenzene U 0.000326 0.00100 1 09/02/2016 00:43 WG902864 2-Butanone (MEK)0.0298 0.00393 0.0100 1 09/02/2016 00:43 WG902864 Methyl Acetate U 0.00430 0.0200 1 09/02/2016 00:43 WG902864 Methyl Cyclohexane U 0.000380 0.00100 1 09/02/2016 00:43 WG902864 Methylene Chloride U 0.00100 0.00500 1 09/02/2016 00:43 WG902864 4-Methyl-2-pentanone (MIBK)0.00256 J 0.00214 0.0100 1 09/02/2016 00:43 WG902864 Methyl tert-butyl ether U 0.000367 0.00100 1 09/02/2016 00:43 WG902864 Styrene U 0.000307 0.00100 1 09/02/2016 00:43 WG902864 1,1,1,2-Tetrachloroethane U 0.000385 0.00100 1 09/02/2016 00:43 WG902864 1,1,2,2-Tetrachloroethane U 0.000130 0.00100 1 09/02/2016 00:43 WG902864 Tetrachloroethene U 0.000372 0.00100 1 09/02/2016 00:43 WG902864 Toluene U 0.000780 0.00500 1 09/02/2016 00:43 WG902864 1,2,3-Trichlorobenzene U 0.000230 0.00100 1 09/02/2016 00:43 WG902864 1,2,4-Trichlorobenzene U 0.000355 0.00100 1 09/02/2016 00:43 WG902864 1,1,1-Trichloroethane U 0.000319 0.00100 1 09/02/2016 00:43 WG902864 1,1,2-Trichloroethane U 0.000383 0.00100 1 09/02/2016 00:43 WG902864 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 9 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 9 of 31 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02 L855921 CELL #2 LEACHATE Collected date/time: 08/25/16 11:45 Volatile Organic Compounds (GC/MS) by Method 8260B Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Trichloroethene U 0.000398 0.00100 1 09/02/2016 00:43 WG902864 Trichlorofluoromethane U 0.00120 0.00500 1 09/02/2016 00:43 WG902864 1,1,2-Trichlorotrifluoroethane U 0.000303 0.00100 1 09/02/2016 00:43 WG902864 1,2,3-Trichloropropane U 0.000807 0.00250 1 09/02/2016 00:43 WG902864 Vinyl acetate U 0.00163 0.0100 1 09/02/2016 00:43 WG902864 Vinyl chloride U 0.000259 0.00100 1 09/02/2016 00:43 WG902864 Xylenes, Total 0.0103 0.00106 0.00300 1 09/02/2016 00:43 WG902864 trans-1,4-Dichloro-2-butene U 0.000866 0.00250 1 09/02/2016 00:43 WG902864 (S) Toluene-d8 109 90.0-115 09/02/2016 00:43 WG902864 (S) Dibromofluoromethane 109 79.0-121 09/02/2016 00:43 WG902864 (S) a,a,a-Trifluorotoluene 104 90.4-116 09/02/2016 00:43 WG902864 (S) 4-Bromofluorobenzene 98.6 80.1-120 09/02/2016 00:43 WG902864 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 10 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 10 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG903430 Gravimetric Analysis by Method 2540 C-2011 L855921-01,02 Method Blank (MB) (MB) R3160723-1 08/31/16 05:53 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Dissolved Solids U 2.82 10.0 L855873-01 Original Sample (OS) • Duplicate (DUP) (OS) L855873-01 08/31/16 05:53 • (DUP) R3160723-4 08/31/16 05:53 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% Dissolved Solids 122 120 1 1.65 5 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3160723-2 08/31/16 05:53 • (LCSD) R3160723-3 08/31/16 05:53 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Dissolved Solids 8800 8210 8560 93.3 97.3 85.0-115 4.17 5 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 11 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 11 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902940 Wet Chemistry by Method 365.4 L855921-01,02 Method Blank (MB) (MB) R3160389-1 08/30/16 20:56 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Phosphorus,Total U 0.0350 0.100 L855691-01 Original Sample (OS) • Duplicate (DUP) (OS) L855691-01 08/30/16 21:01 • (DUP) R3160389-4 08/30/16 21:02 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% Phosphorus,Total 0.298 0.170 1 55.0 P1 20 L856137-02 Original Sample (OS) • Duplicate (DUP) (OS) L856137-02 08/30/16 21:32 • (DUP) R3160389-7 08/30/16 21:33 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% Phosphorus,Total 4.13 3.88 1 6.00 20 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3160389-2 08/30/16 20:57 • (LCSD) R3160389-3 08/30/16 20:58 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Phosphorus,Total 1.00 0.968 0.945 97.0 95.0 90.0-110 2.00 20 L855923-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L855923-01 08/30/16 21:07 • (MS) R3160389-5 08/30/16 21:11 • (MSD) R3160389-6 08/30/16 21:12 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Phosphorus,Total 2.50 ND 2.24 2.26 88.0 89.0 1 90.0-110 J6 J6 1.00 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 12 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 12 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902731 Wet Chemistry by Method 410.4 L855921-01,02 Method Blank (MB) (MB) R3159645-1 08/26/16 19:37 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l COD U 3.00 10.0 L854012-03 Original Sample (OS) • Duplicate (DUP) (OS) L854012-03 08/26/16 19:40 • (DUP) R3159645-4 08/26/16 19:40 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% COD 138 141 1 2.00 20 L855968-03 Original Sample (OS) • Duplicate (DUP) (OS) L855968-03 08/26/16 19:47 • (DUP) R3159645-7 08/26/16 19:47 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% COD 36.7 36.9 1 0.000 20 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3159645-2 08/26/16 19:38 • (LCSD) R3159645-3 08/26/16 19:38 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% COD 242 248 247 102 102 90.0-110 0.000 20 L855923-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L855923-02 08/26/16 19:42 • (MS) R3159645-5 08/26/16 19:42 • (MSD) R3159645-6 08/26/16 19:43 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% COD 400 88.7 468 477 95.0 97.0 1 80.0-120 2.00 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 13 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 13 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902579 Wet Chemistry by Method 5210 B-2011 L855921-01,02 Method Blank (MB) (MB) R3160505-1 08/31/16 10:45 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l BOD U 1 1.00 L855937-02 Original Sample (OS) • Duplicate (DUP) (OS) L855937-02 08/31/16 09:48 • (DUP) R3160505-5 08/31/16 09:57 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% BOD U 0.000 1 0 30 L855981-01 Original Sample (OS) • Duplicate (DUP) (OS) L855981-01 08/31/16 10:21 • (DUP) R3160505-6 08/31/16 10:22 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% BOD 31.7 76.2 1 200 J3 30 L855981-02 Original Sample (OS) • Duplicate (DUP) (OS) L855981-02 08/31/16 10:26 • (DUP) R3160505-7 08/31/16 10:33 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% BOD 7.40 7.95 1 7 30 Laboratory Control Sample (LCS) (LCS) R3160505-2 08/31/16 09:28 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% BOD 198 177 89.4 84.6-115 Laboratory Control Sample (LCS) (LCS) R3160505-3 08/31/16 10:24 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% BOD 198 172 86.7 84.6-115 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 14 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 14 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902579 Wet Chemistry by Method 5210 B-2011 L855921-01,02 Laboratory Control Sample (LCS) (LCS) R3160505-4 08/31/16 10:43 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% BOD 198 162 81.8 84.6-115 J- 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 15 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 15 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902224 Wet Chemistry by Method 9040C L855921-01,02 L855631-03 Original Sample (OS) • Duplicate (DUP) (OS) L855631-03 08/29/16 12:38 • (DUP) WG902224-3 08/29/16 12:38 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte su su %% pH 8.11 8.18 1 0.859 1 L855937-03 Original Sample (OS) • Duplicate (DUP) (OS) L855937-03 08/29/16 12:38 • (DUP) WG902224-4 08/29/16 12:38 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte su su %% pH 6.95 6.89 1 0.867 1 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) WG902224-1 08/29/16 12:38 • (LCSD) WG902224-2 08/29/16 12:38 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte su su su %%%%% pH 6.11 6.14 6.14 100 100 98.4-102 0.000 1 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 16 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 16 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902236 Wet Chemistry by Method 9056A L855921-01,02 Method Blank (MB) (MB) R3159681-1 08/25/16 21:10 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Nitrate U 0.0227 0.100 Sulfate U 0.0774 5.00 L855673-05 Original Sample (OS) • Duplicate (DUP) (OS) L855673-05 08/26/16 00:24 • (DUP) R3159681-5 08/26/16 00:39 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% Sulfate 143 142 10 1 15 L855673-05 Original Sample (OS) • Duplicate (DUP) (OS) L855673-05 08/26/16 02:08 • (DUP) R3159681-6 08/26/16 02:53 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/l mg/l %% Nitrate 9.66 9.65 1 0 15 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3159681-2 08/25/16 21:25 • (LCSD) R3159681-3 08/25/16 21:40 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Nitrate 8.00 8.09 8.13 101 102 80-120 1 15 Sulfate 40.0 40.2 40.3 100 101 80-120 0 15 L855667-05 Original Sample (OS) • Matrix Spike (MS) (OS) L855667-05 08/25/16 22:24 • (MS) R3159681-4 08/25/16 22:39 Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier Analyte mg/l mg/l mg/l %% Nitrate 5.00 2.11 7.01 98 1 80-120 Sulfate 50.0 25.6 74.7 98 1 80-120 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 17 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 17 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902236 Wet Chemistry by Method 9056A L855921-01,02 L855927-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L855927-01 08/26/16 14:31 • (MS) R3159681-7 08/26/16 15:16 • (MSD) R3159681-8 08/26/16 15:31 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Nitrate 5.00 0.600 5.00 5.05 88 89 1 80-120 1 15 Sulfate 50.0 2.92 54.2 54.1 103 102 1 80-120 0 15 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 18 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 18 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902680 Mercury by Method 7470A L855921-01,02 Method Blank (MB) (MB) R3159674-1 08/27/16 06:42 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Mercury U 0.000049 0.000200 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3159674-2 08/27/16 06:45 • (LCSD) R3159674-3 08/27/16 06:48 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Mercury 0.00300 0.00304 0.00320 101 107 80-120 5 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 19 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 19 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902958 Metals (ICP) by Method 6010C L855921-01,02 Method Blank (MB) (MB) R3160404-1 08/30/16 19:08 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Barium U 0.0017 0.00500 Beryllium U 0.0007 0.00200 Cadmium U 0.0007 0.00200 Chromium 0.00242 J 0.0014 0.0100 Cobalt U 0.0023 0.0100 Copper U 0.0053 0.0100 Selenium U 0.0074 0.0100 Silver U 0.0028 0.00500 Vanadium U 0.0024 0.0200 Zinc U 0.0059 0.0500 Method Blank (MB) (MB) R3160468-1 08/31/16 09:00 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Nickel U 0.0049 0.0100 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3160404-2 08/30/16 19:11 • (LCSD) R3160404-3 08/30/16 19:13 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Barium 1.00 1.01 1.02 101 102 80-120 1 20 Beryllium 1.00 1.01 1.01 101 101 80-120 0 20 Cadmium 1.00 0.990 0.999 99 100 80-120 1 20 Chromium 1.00 0.984 0.987 98 99 80-120 0 20 Cobalt 1.00 1.01 1.02 101 102 80-120 1 20 Copper 1.00 0.999 1.00 100 100 80-120 0 20 Selenium 1.00 0.999 1.01 100 101 80-120 1 20 Silver 1.00 0.977 0.978 98 98 80-120 0 20 Vanadium 1.00 0.989 0.994 99 99 80-120 0 20 Zinc 1.00 0.985 0.990 98 99 80-120 1 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 20 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 20 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902958 Metals (ICP) by Method 6010C L855921-01,02 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3160468-2 08/31/16 09:02 • (LCSD) R3160468-3 08/31/16 09:05 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Nickel 1.00 1.02 1.01 102 101 80-120 0 20 L856255-12 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L856255-12 08/30/16 19:16 • (MS) R3160404-5 08/30/16 19:21 • (MSD) R3160404-6 08/30/16 19:24 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Barium 1.00 U 1.02 1.03 102 103 1 75-125 1 20 Beryllium 1.00 U 1.01 1.02 101 102 1 75-125 1 20 Cadmium 1.00 U 0.996 1.00 100 100 1 75-125 1 20 Chromium 1.00 0.00276 0.988 0.998 99 100 1 75-125 1 20 Cobalt 1.00 U 1.01 1.02 101 102 1 75-125 1 20 Copper 1.00 U 1.00 1.02 100 102 1 75-125 2 20 Selenium 1.00 U 1.00 1.01 100 101 1 75-125 1 20 Silver 1.00 U 0.983 0.992 98 99 1 75-125 1 20 Vanadium 1.00 U 0.992 1.00 99 100 1 75-125 1 20 Zinc 1.00 U 0.989 0.997 99 100 1 75-125 1 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 21 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 21 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG904394 Metals (ICPMS) by Method 6020 L855921-01,02 Method Blank (MB) (MB) R3161262-4 09/02/16 16:11 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Antimony U 0.000754 0.00200 Arsenic U 0.00025 0.00200 Lead 0.00093 J 0.00024 0.00200 Thallium U 0.00019 0.00200 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3161262-5 09/02/16 16:14 • (LCSD) R3161262-6 09/02/16 16:18 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Antimony 0.0579 0.0577 0.0565 100 97 80-120 2 20 Arsenic 0.0500 0.0521 0.0494 104 99 80-120 5 20 Lead 0.0500 0.0525 0.0516 105 103 80-120 2 20 Thallium 0.0500 0.0524 0.0508 105 102 80-120 3 20 L856839-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L856839-02 09/02/16 16:21 • (MS) R3161262-8 09/02/16 16:27 • (MSD) R3161262-9 09/02/16 16:30 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Antimony 0.0579 U 0.0566 0.0582 98 101 1 75-125 3 20 Arsenic 0.0500 0.0685 0.120 0.123 103 109 1 75-125 2 20 Lead 0.0500 U 0.0513 0.0523 103 105 1 75-125 2 20 Thallium 0.0500 U 0.0505 0.0522 101 104 1 75-125 3 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 22 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 22 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902864 Volatile Organic Compounds (GC/MS) by Method 8260B L855921-01,02 Method Blank (MB) (MB) R3161330-3 09/01/16 18:33 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Acetone U 0.0100 0.0500 Benzene U 0.000331 0.00100 Bromodichloromethane U 0.000380 0.00100 Bromochloromethane U 0.000520 0.00100 Bromoform U 0.000469 0.00100 Bromomethane U 0.000866 0.00500 Carbon disulfide U 0.000275 0.00100 Carbon tetrachloride U 0.000379 0.00100 Chlorobenzene U 0.000348 0.00100 Chlorodibromomethane U 0.000327 0.00100 Chloroethane U 0.000453 0.00500 Chloroform U 0.000324 0.00500 Chloromethane U 0.000276 0.00250 Cyclohexane U 0.000390 0.00100 1,2-Dibromo-3-Chloropropane U 0.00133 0.00500 1,2-Dibromoethane U 0.000381 0.00100 Dibromomethane U 0.000346 0.00100 1,2-Dichlorobenzene U 0.000349 0.00100 1,3-Dichlorobenzene U 0.000220 0.00100 1,4-Dichlorobenzene U 0.000274 0.00100 trans-1,4-Dichloro-2-butene U 0.000866 0.00250 Dichlorodifluoromethane U 0.000551 0.00500 1,1-Dichloroethane U 0.000259 0.00100 1,2-Dichloroethane U 0.000361 0.00100 1,1-Dichloroethene U 0.000398 0.00100 cis-1,2-Dichloroethene U 0.000260 0.00100 trans-1,2-Dichloroethene U 0.000396 0.00100 1,2-Dichloropropane U 0.000306 0.00100 cis-1,3-Dichloropropene U 0.000418 0.00100 trans-1,3-Dichloropropene U 0.000419 0.00100 Ethylbenzene U 0.000384 0.00100 2-Hexanone U 0.00382 0.0100 Iodomethane U 0.00171 0.0100 Isopropylbenzene U 0.000326 0.00100 2-Butanone (MEK)U 0.00393 0.0100 Methyl Acetate U 0.00430 0.0200 Methylene Chloride U 0.00100 0.00500 Methyl Cyclohexane U 0.000380 0.00100 Methyl tert-butyl ether U 0.000367 0.00100 4-Methyl-2-pentanone (MIBK)U 0.00214 0.0100 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 23 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 23 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902864 Volatile Organic Compounds (GC/MS) by Method 8260B L855921-01,02 Method Blank (MB) (MB) R3161330-3 09/01/16 18:33 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l 1,1,2,2-Tetrachloroethane U 0.000130 0.00100 Tetrachloroethene U 0.000372 0.00100 Styrene U 0.000307 0.00100 1,1,1,2-Tetrachloroethane U 0.000385 0.00100 Toluene U 0.000780 0.00500 1,2,4-Trichlorobenzene U 0.000355 0.00100 1,1,1-Trichloroethane U 0.000319 0.00100 1,1,2-Trichloroethane U 0.000383 0.00100 1,1,2-Trichlorotrifluoroethane U 0.000303 0.00100 1,2,3-Trichlorobenzene U 0.000230 0.00100 Trichloroethene U 0.000398 0.00100 Trichlorofluoromethane U 0.00120 0.00500 1,2,3-Trichloropropane U 0.000807 0.00250 Vinyl chloride U 0.000259 0.00100 Vinyl acetate U 0.00163 0.0100 Xylenes, Total U 0.00106 0.00300 (S) Toluene-d8 106 90.0-115 (S) Dibromofluoromethane 109 79.0-121 (S) a,a,a-Trifluorotoluene 107 90.4-116 (S) 4-Bromofluorobenzene 101 80.1-120 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3161330-1 09/01/16 17:31 • (LCSD) R3161330-2 09/01/16 17:51 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% Acetone 0.125 0.126 0.107 101 85.5 28.7-175 16.5 20.9 Benzene 0.0250 0.0245 0.0242 97.9 97.0 73.0-122 0.920 20 Bromodichloromethane 0.0250 0.0248 0.0245 99.1 97.8 75.5-121 1.25 20 Bromochloromethane 0.0250 0.0260 0.0254 104 102 78.9-123 2.29 20 Bromoform 0.0250 0.0261 0.0253 105 101 71.5-131 3.06 20 Bromomethane 0.0250 0.0187 0.0174 75.0 69.5 22.4-187 7.57 20 Carbon disulfide 0.0250 0.0232 0.0222 92.7 88.7 53.0-134 4.44 20 Carbon tetrachloride 0.0250 0.0261 0.0252 104 101 70.9-129 3.50 20 Chlorobenzene 0.0250 0.0247 0.0250 98.8 100 79.7-122 1.22 20 Chlorodibromomethane 0.0250 0.0258 0.0258 103 103 78.2-124 0.320 20 Chloroethane 0.0250 0.0251 0.0237 100 94.9 41.2-153 5.57 20 Chloroform 0.0250 0.0250 0.0248 100 99.1 73.2-125 0.850 20 Chloromethane 0.0250 0.0260 0.0252 104 101 55.8-134 2.95 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 24 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 24 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902864 Volatile Organic Compounds (GC/MS) by Method 8260B L855921-01,02 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3161330-1 09/01/16 17:31 • (LCSD) R3161330-2 09/01/16 17:51 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% 1,2-Dibromo-3-Chloropropane 0.0250 0.0281 0.0249 112 99.5 64.8-131 12.3 20 1,2-Dibromoethane 0.0250 0.0258 0.0255 103 102 79.8-122 1.12 20 1,2-Dichlorobenzene 0.0250 0.0246 0.0248 98.2 99.2 84.7-118 1.04 20 Dibromomethane 0.0250 0.0265 0.0254 106 101 79.5-118 4.26 20 1,3-Dichlorobenzene 0.0250 0.0247 0.0249 98.8 99.4 77.6-127 0.650 20 1,4-Dichlorobenzene 0.0250 0.0229 0.0233 91.6 93.3 82.2-114 1.78 20 Dichlorodifluoromethane 0.0250 0.0276 0.0264 110 106 56.0-134 4.21 20 trans-1,4-Dichloro-2-butene 0.0250 0.0250 0.0233 100 93.1 58.3-129 7.21 20 1,1-Dichloroethane 0.0250 0.0255 0.0249 102 99.7 71.7-127 2.18 20 1,2-Dichloroethane 0.0250 0.0254 0.0250 101 100 65.3-126 1.36 20 1,1-Dichloroethene 0.0250 0.0247 0.0240 98.8 95.8 59.9-137 3.02 20 cis-1,2-Dichloroethene 0.0250 0.0255 0.0248 102 99.1 77.3-122 2.93 20 trans-1,2-Dichloroethene 0.0250 0.0229 0.0242 91.6 96.9 72.6-125 5.58 20 1,2-Dichloropropane 0.0250 0.0255 0.0249 102 99.5 77.4-125 2.38 20 cis-1,3-Dichloropropene 0.0250 0.0253 0.0251 101 100 77.7-124 0.730 20 trans-1,3-Dichloropropene 0.0250 0.0250 0.0245 99.9 98.1 73.5-127 1.78 20 Ethylbenzene 0.0250 0.0247 0.0247 98.7 98.8 80.9-121 0.0600 20 2-Hexanone 0.125 0.127 0.114 101 91.5 59.4-151 10.4 20 Iodomethane 0.125 0.128 0.123 102 98.7 64.6-137 3.47 20 Isopropylbenzene 0.0250 0.0249 0.0248 99.5 99.1 81.6-124 0.430 20 2-Butanone (MEK)0.125 0.125 0.110 100 87.7 46.4-155 13.3 20 Methylene Chloride 0.0250 0.0256 0.0249 102 99.8 69.5-120 2.41 20 4-Methyl-2-pentanone (MIBK)0.125 0.135 0.121 108 96.9 63.3-138 10.6 20 Methyl tert-butyl ether 0.0250 0.0232 0.0236 92.9 94.5 70.1-125 1.66 20 Styrene 0.0250 0.0256 0.0255 102 102 79.9-124 0.280 20 1,1,1,2-Tetrachloroethane 0.0250 0.0259 0.0265 104 106 78.5-125 2.38 20 1,1,2,2-Tetrachloroethane 0.0250 0.0250 0.0237 99.9 95.0 79.3-123 5.05 20 Tetrachloroethene 0.0250 0.0254 0.0245 102 97.9 73.5-130 3.81 20 Toluene 0.0250 0.0240 0.0236 95.8 94.4 77.9-116 1.52 20 1,1,2-Trichlorotrifluoroethane 0.0250 0.0253 0.0236 101 94.6 62.0-141 6.73 20 1,2,3-Trichlorobenzene 0.0250 0.0246 0.0246 98.2 98.4 75.7-134 0.170 20 1,2,4-Trichlorobenzene 0.0250 0.0238 0.0234 95.4 93.7 76.1-136 1.73 20 1,1,1-Trichloroethane 0.0250 0.0245 0.0237 97.8 94.7 71.1-129 3.29 20 1,1,2-Trichloroethane 0.0250 0.0242 0.0239 96.8 95.6 81.6-120 1.25 20 Trichloroethene 0.0250 0.0264 0.0250 105 100 79.5-121 5.24 20 Trichlorofluoromethane 0.0250 0.0273 0.0256 109 102 49.1-157 6.49 20 1,2,3-Trichloropropane 0.0250 0.0264 0.0248 105 99.2 74.9-124 6.09 20 Vinyl acetate 0.125 0.124 0.118 98.8 94.2 41.7-159 4.77 20 Vinyl chloride 0.0250 0.0272 0.0261 109 105 61.5-134 3.90 20 Xylenes, Total 0.0750 0.0740 0.0738 98.7 98.3 79.2-122 0.350 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 25 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 25 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902864 Volatile Organic Compounds (GC/MS) by Method 8260B L855921-01,02 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3161330-1 09/01/16 17:31 • (LCSD) R3161330-2 09/01/16 17:51 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l %%%%% (S) Toluene-d8 106 107 90.0-115 (S) Dibromofluoromethane 107 106 79.0-121 (S) a,a,a-Trifluorotoluene 106 106 90.4-116 (S) 4-Bromofluorobenzene 104 104 80.1-120 L855839-12 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L855839-12 09/01/16 22:59 • (MS) R3161330-4 09/01/16 21:11 • (MSD) R3161330-5 09/01/16 22:18 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Acetone 0.125 U 0.0756 0.0623 60.5 49.9 1 25.0-156 19.2 21.5 Benzene 0.0250 U 0.0220 0.0208 88.0 83.2 1 58.6-133 5.64 20 Bromodichloromethane 0.0250 U 0.0238 0.0229 95.0 91.6 1 69.2-127 3.61 20 Bromochloromethane 0.0250 U 0.0233 0.0216 93.2 86.4 1 74.4-128 7.66 20 Bromoform 0.0250 U 0.0259 0.0249 104 99.4 1 66.3-140 4.16 20 Bromomethane 0.0250 U 0.0144 0.0129 57.5 51.5 1 16.6-183 11.0 20.5 Carbon disulfide 0.0250 U 0.0144 0.0130 57.5 51.9 1 34.9-138 10.2 20 Carbon tetrachloride 0.0250 U 0.0233 0.0207 93.3 82.7 1 60.6-139 12.1 20 Chlorobenzene 0.0250 U 0.0237 0.0234 94.7 93.8 1 70.1-130 0.930 20 Chlorodibromomethane 0.0250 U 0.0253 0.0248 101 99.1 1 71.6-132 2.17 20 Chloroethane 0.0250 U 0.0195 0.0176 78.2 70.4 1 33.3-155 10.5 20 Chloroform 0.0250 U 0.0237 0.0216 94.7 86.6 1 66.1-133 8.93 20 Chloromethane 0.0250 U 0.0178 0.0154 71.1 61.7 1 40.7-139 14.2 20 1,2-Dibromo-3-Chloropropane 0.0250 U 0.0272 0.0243 109 97.1 1 63.9-142 11.5 20.2 1,2-Dibromoethane 0.0250 U 0.0248 0.0241 99.1 96.4 1 73.8-131 2.70 20 1,2-Dichlorobenzene 0.0250 U 0.0250 0.0239 100 95.5 1 77.4-127 4.77 20 Dibromomethane 0.0250 U 0.0250 0.0235 99.9 93.9 1 72.8-127 6.13 20 1,3-Dichlorobenzene 0.0250 U 0.0245 0.0231 98.0 92.4 1 67.9-136 5.81 20 1,4-Dichlorobenzene 0.0250 U 0.0238 0.0228 95.1 91.3 1 74.4-123 4.03 20 Dichlorodifluoromethane 0.0250 U 0.0193 0.0167 77.1 66.6 1 42.2-146 14.6 20 trans-1,4-Dichloro-2-butene 0.0250 0.0255 0.0239 102 95.8 1 57.6-136 6.22 20 1,1-Dichloroethane 0.0250 U 0.0232 0.0215 92.7 86.1 1 64.0-134 7.34 20 1,2-Dichloroethane 0.0250 U 0.0244 0.0225 97.5 90.1 1 60.7-132 7.81 20 1,1-Dichloroethene 0.0250 U 0.0210 0.0186 84.0 74.2 1 48.8-144 12.3 20 cis-1,2-Dichloroethene 0.0250 0.000556 0.0229 0.0216 89.5 84.3 1 60.6-136 5.80 20 trans-1,2-Dichloroethene 0.0250 U 0.0209 0.0170 83.5 67.9 1 61.0-132 J3 20.6 20 1,2-Dichloropropane 0.0250 U 0.0237 0.0237 94.8 94.8 1 69.7-130 0.0100 20 cis-1,3-Dichloropropene 0.0250 U 0.0244 0.0245 97.6 97.9 1 71.1-129 0.330 20 trans-1,3-Dichloropropene 0.0250 U 0.0249 0.0251 99.5 100 1 66.3-136 0.740 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 26 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 26 of 31 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG902864 Volatile Organic Compounds (GC/MS) by Method 8260B L855921-01,02 L855839-12 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L855839-12 09/01/16 22:59 • (MS) R3161330-4 09/01/16 21:11 • (MSD) R3161330-5 09/01/16 22:18 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Ethylbenzene 0.0250 U 0.0229 0.0228 91.6 91.0 1 62.7-136 0.630 20 2-Hexanone 0.125 U 0.114 0.104 91.2 83.5 1 59.4-154 8.78 20.1 Iodomethane 0.125 0.105 0.0946 84.0 75.7 1 55.2-140 10.4 20 Isopropylbenzene 0.0250 U 0.0234 0.0228 93.4 91.2 1 67.4-136 2.48 20 2-Butanone (MEK)0.125 U 0.102 0.0887 81.3 70.9 1 45.0-156 13.6 20.8 Methylene Chloride 0.0250 U 0.0213 0.0189 85.3 75.7 1 61.5-125 11.9 20 4-Methyl-2-pentanone (MIBK)0.125 U 0.135 0.124 108 98.8 1 60.7-150 8.66 20 Methyl tert-butyl ether 0.0250 U 0.0224 0.0203 89.7 81.1 1 61.4-136 10.1 20 Styrene 0.0250 U 0.0243 0.0241 97.0 96.5 1 68.2-133 0.550 20 1,1,1,2-Tetrachloroethane 0.0250 U 0.0246 0.0242 98.5 96.7 1 70.5-132 1.85 20 1,1,2,2-Tetrachloroethane 0.0250 U 0.0255 0.0233 102 93.3 1 64.9-145 8.79 20 Tetrachloroethene 0.0250 0.00289 0.0249 0.0245 88.1 86.4 1 57.4-141 1.70 20 Toluene 0.0250 U 0.0219 0.0220 87.4 87.9 1 67.8-124 0.490 20 1,1,2-Trichlorotrifluoroethane 0.0250 U 0.0233 0.0204 93.2 81.6 1 53.7-150 13.2 20 1,2,3-Trichlorobenzene 0.0250 U 0.0255 0.0241 102 96.3 1 65.7-143 5.96 20 1,2,4-Trichlorobenzene 0.0250 U 0.0249 0.0241 99.6 96.4 1 67.0-146 3.32 20 1,1,1-Trichloroethane 0.0250 U 0.0225 0.0210 90.1 83.8 1 58.7-134 7.18 20 1,1,2-Trichloroethane 0.0250 U 0.0241 0.0239 96.3 95.5 1 74.1-130 0.850 20 Trichloroethene 0.0250 U 0.0233 0.0219 93.2 87.6 1 48.9-148 6.16 20 Trichlorofluoromethane 0.0250 U 0.0224 0.0202 89.6 80.7 1 39.9-165 10.4 20 1,2,3-Trichloropropane 0.0250 U 0.0268 0.0253 107 101 1 71.5-134 5.93 20 Vinyl acetate 0.125 0.131 0.122 105 97.6 1 42.8-181 7.33 20 Vinyl chloride 0.0250 U 0.0198 0.0178 79.3 71.0 1 44.3-143 10.9 20 Xylenes, Total 0.0750 U 0.0686 0.0676 91.5 90.2 1 65.6-133 1.43 20 (S) Toluene-d8 108 108 90.0-115 (S) Dibromofluoromethane 108 99.8 79.0-121 (S) a,a,a-Trifluorotoluene 104 105 90.4-116 (S) 4-Bromofluorobenzene 101 101 80.1-120 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 27 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 27 of 31 ONE LAB. NATIONWIDE.GLOSSARY OF TERMS Abbreviations and Definitions SDG Sample Delivery Group. MDL Method Detection Limit. RDL Reported Detection Limit. U Not detected at the Reporting Limit (or MDL where applicable). RPD Relative Percent Difference. Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. (S)Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. Rec.Recovery. Qualifier Description B The same analyte is found in the associated blank. J The identification of the analyte is acceptable; the reported value is an estimate. J3 The associated batch QC was outside the established quality control range for precision. J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low. J-The associated batch QC was outside the lower control limits; associated data has a potential negative bias. P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit. V The sample concentration is too high to evaluate accurate spike recoveries. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 28 of 31 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 28 of 31 ONE LAB. NATIONWIDE.ACCREDITATIONS & LOCATIONS 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/06/16 17:27 29 of 31 Our Locations Alabama 40660 Alaska UST-080 Arizona AZ0612 Arkansas 88-0469 California 01157CA Colorado TN00003 Conneticut PH-0197 Florida E87487 Georgia NELAP Georgia 1 923 Idaho TN00003 Illinois 200008 Indiana C-TN-01 Iowa 364 Kansas E-10277 Kentucky 1 90010 Kentucky 2 16 Louisiana AI30792 Maine TN0002 Maryland 324 Massachusetts M-TN003 Michigan 9958 Minnesota 047-999-395 Mississippi TN00003 Missouri 340 Montana CERT0086 Nebraska NE-OS-15-05 Nevada TN-03-2002-34 New Hampshire 2975 New Jersey–NELAP TN002 New Mexico TN00003 New York 11742 North Carolina Env375 North Carolina 1 DW21704 North Carolina 2 41 North Dakota R-140 Ohio–VAP CL0069 Oklahoma 9915 Oregon TN200002 Pennsylvania 68-02979 Rhode Island 221 South Carolina 84004 South Dakota n/a Tennessee 1 4 2006 Texas T 104704245-07-TX Texas 5 LAB0152 Utah 6157585858 Vermont VT2006 Virginia 109 Washington C1915 West Virginia 233 Wisconsin 9980939910 Wyoming A2LA A2LA – ISO 17025 1461.01 Canada 1461.01 EPA–Crypto TN00003 AIHA 100789 DOD 1461.01 USDA S-67674 State Accreditations Third Party & Federal Accreditations ESC Lab Sciences is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our “one location” design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. ESC Lab Sciences has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. ESC Lab Sciences performs all testing at our central laboratory. 1. Drinking Water 2. Underground Storage Tanks 3. Aquatic Toxicity 4. Chemical/Microbiological 5. Mold n/a Accreditation not applicable 1461.02A2LA – ISO 170255 * Not all certifications held by the laboratory are applicable to the results reported in the attached report. ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Pyramid Environmental 2016-224 L855921 10/07/16 10:10 29 of 31