Caroline Courtyard Ground Water Sampling Report-OCR

#=CL#
September 18, 2014
LIMS USE: FR - ALAN GRIFFITH
LIMS OBJECT ID: 92216004
92216004
Project:
Pace Project No.:
RE:
Mr. Alan Griffith
Griffith Enterprises, Inc.
353 Jonestown Rd.
#312
Winston Salem, NC 27104
BARKLEY PROPERTY
Dear Mr. Griffith:
Enclosed are the analytical results for sample(s) received by the laboratory on September 04, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 36
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92216004001 MW-16 22.89 EPA 8260 63 PASI-CGAW
92216004002 MW-19 9.95'EPA 8260 63 PASI-CGAW
92216004003 MW-23 7.79'EPA 8260 63 PASI-CGAW
92216004004 MW-18 7.63'EPA 8260 63 PASI-CMCK
92216004005 MW-22D 7.12'EPA 8260 63 PASI-CGAW
92216004006 MW-25 8.29'EPA 8260 63 PASI-CGAW
92216004007 MW-11 21.09'EPA 8260 63 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 36
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92216004001 MW-16 22.89
Tetrachloroethene 7.8 ug/L 09/09/14 05:111.0EPA 8260
92216004002 MW-19 9.95'
Tetrachloroethene 22.4 ug/L 09/09/14 05:271.0EPA 8260
92216004003 MW-23 7.79'
Tetrachloroethene 9.0 ug/L 09/09/14 05:431.0EPA 8260
92216004004 MW-18 7.63'
cis-1,2-Dichloroethene 1.4 ug/L 09/16/14 07:391.0EPA 8260
Tetrachloroethene 261 ug/L 09/16/14 07:39 E1.0EPA 8260
Trichloroethene 1.1 ug/L 09/16/14 07:391.0EPA 8260
92216004005 MW-22D 7.12'
Tetrachloroethene 130 ug/L 09/10/14 00:082.5EPA 8260
92216004006 MW-25 8.29'
cis-1,2-Dichloroethene 977 ug/L 09/10/14 00:2410.0EPA 8260
Tetrachloroethene 1720 ug/L 09/10/14 00:2410.0EPA 8260
Trichloroethene 407 ug/L 09/10/14 00:2410.0EPA 8260
92216004007 MW-11 21.09'
cis-1,2-Dichloroethene 1.2 ug/L 09/09/14 06:481.0EPA 8260
Tetrachloroethene 2.6 ug/L 09/09/14 06:48 C81.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-16 22.89 Lab ID:92216004001 Collected:09/03/14 09:30 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/09/14 05:11 67-64-125.0 1
Benzene ND ug/L 09/09/14 05:11 71-43-21.0 1
Bromobenzene ND ug/L 09/09/14 05:11 108-86-11.0 1
Bromochloromethane ND ug/L 09/09/14 05:11 74-97-51.0 1
Bromodichloromethane ND ug/L 09/09/14 05:11 75-27-41.0 1
Bromoform ND ug/L 09/09/14 05:11 75-25-21.0 1
Bromomethane ND ug/L 09/09/14 05:11 74-83-92.0 1
2-Butanone (MEK)ND ug/L 09/09/14 05:11 78-93-35.0 1
Carbon tetrachloride ND ug/L 09/09/14 05:11 56-23-51.0 1
Chlorobenzene ND ug/L 09/09/14 05:11 108-90-71.0 1
Chloroethane ND ug/L 09/09/14 05:11 75-00-31.0 1
Chloroform ND ug/L 09/09/14 05:11 67-66-31.0 1
Chloromethane ND ug/L 09/09/14 05:11 74-87-31.0 1
2-Chlorotoluene ND ug/L 09/09/14 05:11 95-49-81.0 1
4-Chlorotoluene ND ug/L 09/09/14 05:11 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 09/09/14 05:11 96-12-82.0 1
Dibromochloromethane ND ug/L 09/09/14 05:11 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 09/09/14 05:11 106-93-41.0 1
Dibromomethane ND ug/L 09/09/14 05:11 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 09/09/14 05:11 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 09/09/14 05:11 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 09/09/14 05:11 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 09/09/14 05:11 75-71-81.0 1
1,1-Dichloroethane ND ug/L 09/09/14 05:11 75-34-31.0 1
1,2-Dichloroethane ND ug/L 09/09/14 05:11 107-06-21.0 1
1,1-Dichloroethene ND ug/L 09/09/14 05:11 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 09/09/14 05:11 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 09/09/14 05:11 156-60-51.0 1
1,2-Dichloropropane ND ug/L 09/09/14 05:11 78-87-51.0 1
1,3-Dichloropropane ND ug/L 09/09/14 05:11 142-28-91.0 1
2,2-Dichloropropane ND ug/L 09/09/14 05:11 594-20-71.0 1
1,1-Dichloropropene ND ug/L 09/09/14 05:11 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 09/09/14 05:11 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 09/09/14 05:11 10061-02-61.0 1
Diisopropyl ether ND ug/L 09/09/14 05:11 108-20-31.0 1
Ethylbenzene ND ug/L 09/09/14 05:11 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 09/09/14 05:11 87-68-31.0 1
2-Hexanone ND ug/L 09/09/14 05:11 591-78-65.0 1
p-Isopropyltoluene ND ug/L 09/09/14 05:11 99-87-61.0 1
Methylene Chloride ND ug/L 09/09/14 05:11 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/09/14 05:11 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 09/09/14 05:11 1634-04-41.0 1
Naphthalene ND ug/L 09/09/14 05:11 91-20-31.0 1
Styrene ND ug/L 09/09/14 05:11 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 09/09/14 05:11 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 09/09/14 05:11 79-34-51.0 1
Tetrachloroethene 7.8 ug/L 09/09/14 05:11 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-16 22.89 Lab ID:92216004001 Collected:09/03/14 09:30 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/09/14 05:11 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 09/09/14 05:11 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 09/09/14 05:11 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 09/09/14 05:11 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 09/09/14 05:11 79-00-51.0 1
Trichloroethene ND ug/L 09/09/14 05:11 79-01-61.0 1
Trichlorofluoromethane ND ug/L 09/09/14 05:11 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 09/09/14 05:11 96-18-41.0 1
Vinyl acetate ND ug/L 09/09/14 05:11 108-05-42.0 1
Vinyl chloride ND ug/L 09/09/14 05:11 75-01-41.0 1
Xylene (Total)ND ug/L 09/09/14 05:11 1330-20-72.0 1
m&p-Xylene ND ug/L 09/09/14 05:11 179601-23-12.0 1
o-Xylene ND ug/L 09/09/14 05:11 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)103 %09/09/14 05:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %09/09/14 05:11 17060-07-070-130 1
Toluene-d8 (S)95 %09/09/14 05:11 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-19 9.95'Lab ID:92216004002 Collected:09/03/14 10:10 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/09/14 05:27 67-64-125.0 1
Benzene ND ug/L 09/09/14 05:27 71-43-21.0 1
Bromobenzene ND ug/L 09/09/14 05:27 108-86-11.0 1
Bromochloromethane ND ug/L 09/09/14 05:27 74-97-51.0 1
Bromodichloromethane ND ug/L 09/09/14 05:27 75-27-41.0 1
Bromoform ND ug/L 09/09/14 05:27 75-25-21.0 1
Bromomethane ND ug/L 09/09/14 05:27 74-83-92.0 1
2-Butanone (MEK)ND ug/L 09/09/14 05:27 78-93-35.0 1
Carbon tetrachloride ND ug/L 09/09/14 05:27 56-23-51.0 1
Chlorobenzene ND ug/L 09/09/14 05:27 108-90-71.0 1
Chloroethane ND ug/L 09/09/14 05:27 75-00-31.0 1
Chloroform ND ug/L 09/09/14 05:27 67-66-31.0 1
Chloromethane ND ug/L 09/09/14 05:27 74-87-31.0 1
2-Chlorotoluene ND ug/L 09/09/14 05:27 95-49-81.0 1
4-Chlorotoluene ND ug/L 09/09/14 05:27 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 09/09/14 05:27 96-12-82.0 1
Dibromochloromethane ND ug/L 09/09/14 05:27 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 09/09/14 05:27 106-93-41.0 1
Dibromomethane ND ug/L 09/09/14 05:27 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 09/09/14 05:27 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 09/09/14 05:27 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 09/09/14 05:27 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 09/09/14 05:27 75-71-81.0 1
1,1-Dichloroethane ND ug/L 09/09/14 05:27 75-34-31.0 1
1,2-Dichloroethane ND ug/L 09/09/14 05:27 107-06-21.0 1
1,1-Dichloroethene ND ug/L 09/09/14 05:27 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 09/09/14 05:27 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 09/09/14 05:27 156-60-51.0 1
1,2-Dichloropropane ND ug/L 09/09/14 05:27 78-87-51.0 1
1,3-Dichloropropane ND ug/L 09/09/14 05:27 142-28-91.0 1
2,2-Dichloropropane ND ug/L 09/09/14 05:27 594-20-71.0 1
1,1-Dichloropropene ND ug/L 09/09/14 05:27 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 09/09/14 05:27 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 09/09/14 05:27 10061-02-61.0 1
Diisopropyl ether ND ug/L 09/09/14 05:27 108-20-31.0 1
Ethylbenzene ND ug/L 09/09/14 05:27 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 09/09/14 05:27 87-68-31.0 1
2-Hexanone ND ug/L 09/09/14 05:27 591-78-65.0 1
p-Isopropyltoluene ND ug/L 09/09/14 05:27 99-87-61.0 1
Methylene Chloride ND ug/L 09/09/14 05:27 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/09/14 05:27 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 09/09/14 05:27 1634-04-41.0 1
Naphthalene ND ug/L 09/09/14 05:27 91-20-31.0 1
Styrene ND ug/L 09/09/14 05:27 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 09/09/14 05:27 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 09/09/14 05:27 79-34-51.0 1
Tetrachloroethene 22.4 ug/L 09/09/14 05:27 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-19 9.95'Lab ID:92216004002 Collected:09/03/14 10:10 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/09/14 05:27 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 09/09/14 05:27 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 09/09/14 05:27 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 09/09/14 05:27 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 09/09/14 05:27 79-00-51.0 1
Trichloroethene ND ug/L 09/09/14 05:27 79-01-61.0 1
Trichlorofluoromethane ND ug/L 09/09/14 05:27 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 09/09/14 05:27 96-18-41.0 1
Vinyl acetate ND ug/L 09/09/14 05:27 108-05-42.0 1
Vinyl chloride ND ug/L 09/09/14 05:27 75-01-41.0 1
Xylene (Total)ND ug/L 09/09/14 05:27 1330-20-72.0 1
m&p-Xylene ND ug/L 09/09/14 05:27 179601-23-12.0 1
o-Xylene ND ug/L 09/09/14 05:27 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)101 %09/09/14 05:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %09/09/14 05:27 17060-07-070-130 1
Toluene-d8 (S)97 %09/09/14 05:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-23 7.79'Lab ID:92216004003 Collected:09/03/14 10:50 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/09/14 05:43 67-64-125.0 1
Benzene ND ug/L 09/09/14 05:43 71-43-21.0 1
Bromobenzene ND ug/L 09/09/14 05:43 108-86-11.0 1
Bromochloromethane ND ug/L 09/09/14 05:43 74-97-51.0 1
Bromodichloromethane ND ug/L 09/09/14 05:43 75-27-41.0 1
Bromoform ND ug/L 09/09/14 05:43 75-25-21.0 1
Bromomethane ND ug/L 09/09/14 05:43 74-83-92.0 1
2-Butanone (MEK)ND ug/L 09/09/14 05:43 78-93-35.0 1
Carbon tetrachloride ND ug/L 09/09/14 05:43 56-23-51.0 1
Chlorobenzene ND ug/L 09/09/14 05:43 108-90-71.0 1
Chloroethane ND ug/L 09/09/14 05:43 75-00-31.0 1
Chloroform ND ug/L 09/09/14 05:43 67-66-31.0 1
Chloromethane ND ug/L 09/09/14 05:43 74-87-31.0 1
2-Chlorotoluene ND ug/L 09/09/14 05:43 95-49-81.0 1
4-Chlorotoluene ND ug/L 09/09/14 05:43 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 09/09/14 05:43 96-12-82.0 1
Dibromochloromethane ND ug/L 09/09/14 05:43 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 09/09/14 05:43 106-93-41.0 1
Dibromomethane ND ug/L 09/09/14 05:43 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 09/09/14 05:43 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 09/09/14 05:43 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 09/09/14 05:43 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 09/09/14 05:43 75-71-81.0 1
1,1-Dichloroethane ND ug/L 09/09/14 05:43 75-34-31.0 1
1,2-Dichloroethane ND ug/L 09/09/14 05:43 107-06-21.0 1
1,1-Dichloroethene ND ug/L 09/09/14 05:43 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 09/09/14 05:43 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 09/09/14 05:43 156-60-51.0 1
1,2-Dichloropropane ND ug/L 09/09/14 05:43 78-87-51.0 1
1,3-Dichloropropane ND ug/L 09/09/14 05:43 142-28-91.0 1
2,2-Dichloropropane ND ug/L 09/09/14 05:43 594-20-71.0 1
1,1-Dichloropropene ND ug/L 09/09/14 05:43 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 09/09/14 05:43 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 09/09/14 05:43 10061-02-61.0 1
Diisopropyl ether ND ug/L 09/09/14 05:43 108-20-31.0 1
Ethylbenzene ND ug/L 09/09/14 05:43 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 09/09/14 05:43 87-68-31.0 1
2-Hexanone ND ug/L 09/09/14 05:43 591-78-65.0 1
p-Isopropyltoluene ND ug/L 09/09/14 05:43 99-87-61.0 1
Methylene Chloride ND ug/L 09/09/14 05:43 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/09/14 05:43 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 09/09/14 05:43 1634-04-41.0 1
Naphthalene ND ug/L 09/09/14 05:43 91-20-31.0 1
Styrene ND ug/L 09/09/14 05:43 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 09/09/14 05:43 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 09/09/14 05:43 79-34-51.0 1
Tetrachloroethene 9.0 ug/L 09/09/14 05:43 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-23 7.79'Lab ID:92216004003 Collected:09/03/14 10:50 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/09/14 05:43 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 09/09/14 05:43 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 09/09/14 05:43 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 09/09/14 05:43 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 09/09/14 05:43 79-00-51.0 1
Trichloroethene ND ug/L 09/09/14 05:43 79-01-61.0 1
Trichlorofluoromethane ND ug/L 09/09/14 05:43 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 09/09/14 05:43 96-18-41.0 1
Vinyl acetate ND ug/L 09/09/14 05:43 108-05-42.0 1
Vinyl chloride ND ug/L 09/09/14 05:43 75-01-41.0 1
Xylene (Total)ND ug/L 09/09/14 05:43 1330-20-72.0 1
m&p-Xylene ND ug/L 09/09/14 05:43 179601-23-12.0 1
o-Xylene ND ug/L 09/09/14 05:43 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)102 %09/09/14 05:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %09/09/14 05:43 17060-07-070-130 1
Toluene-d8 (S)96 %09/09/14 05:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-18 7.63'Lab ID:92216004004 Collected:09/03/14 11:30 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/16/14 07:39 67-64-125.0 1
Benzene ND ug/L 09/16/14 07:39 71-43-21.0 1
Bromobenzene ND ug/L 09/16/14 07:39 108-86-11.0 1
Bromochloromethane ND ug/L 09/16/14 07:39 74-97-51.0 1
Bromodichloromethane ND ug/L 09/16/14 07:39 75-27-41.0 1
Bromoform ND ug/L 09/16/14 07:39 75-25-21.0 1
Bromomethane ND ug/L 09/16/14 07:39 74-83-92.0 1
2-Butanone (MEK)ND ug/L 09/16/14 07:39 78-93-35.0 1
Carbon tetrachloride ND ug/L 09/16/14 07:39 56-23-51.0 1
Chlorobenzene ND ug/L 09/16/14 07:39 108-90-71.0 1
Chloroethane ND ug/L 09/16/14 07:39 75-00-31.0 1
Chloroform ND ug/L 09/16/14 07:39 67-66-31.0 1
Chloromethane ND ug/L 09/16/14 07:39 74-87-31.0 1
2-Chlorotoluene ND ug/L 09/16/14 07:39 95-49-81.0 1
4-Chlorotoluene ND ug/L 09/16/14 07:39 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 09/16/14 07:39 96-12-82.0 1
Dibromochloromethane ND ug/L 09/16/14 07:39 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 09/16/14 07:39 106-93-41.0 1
Dibromomethane ND ug/L 09/16/14 07:39 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 09/16/14 07:39 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 09/16/14 07:39 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 09/16/14 07:39 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 09/16/14 07:39 75-71-81.0 1
1,1-Dichloroethane ND ug/L 09/16/14 07:39 75-34-31.0 1
1,2-Dichloroethane ND ug/L 09/16/14 07:39 107-06-21.0 1
1,1-Dichloroethene ND ug/L 09/16/14 07:39 75-35-41.0 1
cis-1,2-Dichloroethene 1.4 ug/L 09/16/14 07:39 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 09/16/14 07:39 156-60-51.0 1
1,2-Dichloropropane ND ug/L 09/16/14 07:39 78-87-51.0 1
1,3-Dichloropropane ND ug/L 09/16/14 07:39 142-28-91.0 1
2,2-Dichloropropane ND ug/L 09/16/14 07:39 594-20-71.0 1
1,1-Dichloropropene ND ug/L 09/16/14 07:39 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 09/16/14 07:39 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 09/16/14 07:39 10061-02-61.0 1
Diisopropyl ether ND ug/L 09/16/14 07:39 108-20-31.0 1
Ethylbenzene ND ug/L 09/16/14 07:39 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 09/16/14 07:39 87-68-31.0 1
2-Hexanone ND ug/L 09/16/14 07:39 591-78-65.0 1
p-Isopropyltoluene ND ug/L 09/16/14 07:39 99-87-61.0 1
Methylene Chloride ND ug/L 09/16/14 07:39 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/16/14 07:39 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 09/16/14 07:39 1634-04-41.0 1
Naphthalene ND ug/L 09/16/14 07:39 91-20-31.0 1
Styrene ND ug/L 09/16/14 07:39 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 09/16/14 07:39 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 09/16/14 07:39 79-34-51.0 1
Tetrachloroethene 261 ug/L 09/16/14 07:39 127-18-4 E1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-18 7.63'Lab ID:92216004004 Collected:09/03/14 11:30 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/16/14 07:39 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 09/16/14 07:39 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 09/16/14 07:39 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 09/16/14 07:39 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 09/16/14 07:39 79-00-51.0 1
Trichloroethene 1.1 ug/L 09/16/14 07:39 79-01-61.0 1
Trichlorofluoromethane ND ug/L 09/16/14 07:39 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 09/16/14 07:39 96-18-41.0 1
Vinyl acetate ND ug/L 09/16/14 07:39 108-05-42.0 1
Vinyl chloride ND ug/L 09/16/14 07:39 75-01-41.0 1
Xylene (Total)ND ug/L 09/16/14 07:39 1330-20-72.0 1
m&p-Xylene ND ug/L 09/16/14 07:39 179601-23-12.0 1
o-Xylene ND ug/L 09/16/14 07:39 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)95 %09/16/14 07:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %09/16/14 07:39 17060-07-070-130 1
Toluene-d8 (S)98 %09/16/14 07:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-22D 7.12'Lab ID:92216004005 Collected:09/03/14 12:15 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/10/14 00:08 67-64-162.5 2.5
Benzene ND ug/L 09/10/14 00:08 71-43-22.5 2.5
Bromobenzene ND ug/L 09/10/14 00:08 108-86-12.5 2.5
Bromochloromethane ND ug/L 09/10/14 00:08 74-97-52.5 2.5
Bromodichloromethane ND ug/L 09/10/14 00:08 75-27-42.5 2.5
Bromoform ND ug/L 09/10/14 00:08 75-25-22.5 2.5
Bromomethane ND ug/L 09/10/14 00:08 74-83-95.0 2.5
2-Butanone (MEK)ND ug/L 09/10/14 00:08 78-93-312.5 2.5
Carbon tetrachloride ND ug/L 09/10/14 00:08 56-23-52.5 2.5
Chlorobenzene ND ug/L 09/10/14 00:08 108-90-72.5 2.5
Chloroethane ND ug/L 09/10/14 00:08 75-00-32.5 2.5
Chloroform ND ug/L 09/10/14 00:08 67-66-32.5 2.5
Chloromethane ND ug/L 09/10/14 00:08 74-87-32.5 2.5
2-Chlorotoluene ND ug/L 09/10/14 00:08 95-49-82.5 2.5
4-Chlorotoluene ND ug/L 09/10/14 00:08 106-43-42.5 2.5
1,2-Dibromo-3-chloropropane ND ug/L 09/10/14 00:08 96-12-85.0 2.5
Dibromochloromethane ND ug/L 09/10/14 00:08 124-48-12.5 2.5
1,2-Dibromoethane (EDB)ND ug/L 09/10/14 00:08 106-93-42.5 2.5
Dibromomethane ND ug/L 09/10/14 00:08 74-95-32.5 2.5
1,2-Dichlorobenzene ND ug/L 09/10/14 00:08 95-50-12.5 2.5
1,3-Dichlorobenzene ND ug/L 09/10/14 00:08 541-73-12.5 2.5
1,4-Dichlorobenzene ND ug/L 09/10/14 00:08 106-46-72.5 2.5
Dichlorodifluoromethane ND ug/L 09/10/14 00:08 75-71-82.5 2.5
1,1-Dichloroethane ND ug/L 09/10/14 00:08 75-34-32.5 2.5
1,2-Dichloroethane ND ug/L 09/10/14 00:08 107-06-22.5 2.5
1,1-Dichloroethene ND ug/L 09/10/14 00:08 75-35-42.5 2.5
cis-1,2-Dichloroethene ND ug/L 09/10/14 00:08 156-59-22.5 2.5
trans-1,2-Dichloroethene ND ug/L 09/10/14 00:08 156-60-52.5 2.5
1,2-Dichloropropane ND ug/L 09/10/14 00:08 78-87-52.5 2.5
1,3-Dichloropropane ND ug/L 09/10/14 00:08 142-28-92.5 2.5
2,2-Dichloropropane ND ug/L 09/10/14 00:08 594-20-72.5 2.5
1,1-Dichloropropene ND ug/L 09/10/14 00:08 563-58-62.5 2.5
cis-1,3-Dichloropropene ND ug/L 09/10/14 00:08 10061-01-52.5 2.5
trans-1,3-Dichloropropene ND ug/L 09/10/14 00:08 10061-02-62.5 2.5
Diisopropyl ether ND ug/L 09/10/14 00:08 108-20-32.5 2.5
Ethylbenzene ND ug/L 09/10/14 00:08 100-41-42.5 2.5
Hexachloro-1,3-butadiene ND ug/L 09/10/14 00:08 87-68-32.5 2.5
2-Hexanone ND ug/L 09/10/14 00:08 591-78-612.5 2.5
p-Isopropyltoluene ND ug/L 09/10/14 00:08 99-87-62.5 2.5
Methylene Chloride ND ug/L 09/10/14 00:08 75-09-25.0 2.5
4-Methyl-2-pentanone (MIBK)ND ug/L 09/10/14 00:08 108-10-112.5 2.5
Methyl-tert-butyl ether ND ug/L 09/10/14 00:08 1634-04-42.5 2.5
Naphthalene ND ug/L 09/10/14 00:08 91-20-32.5 2.5
Styrene ND ug/L 09/10/14 00:08 100-42-52.5 2.5
1,1,1,2-Tetrachloroethane ND ug/L 09/10/14 00:08 630-20-62.5 2.5
1,1,2,2-Tetrachloroethane ND ug/L 09/10/14 00:08 79-34-52.5 2.5
Tetrachloroethene 130 ug/L 09/10/14 00:08 127-18-42.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-22D 7.12'Lab ID:92216004005 Collected:09/03/14 12:15 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/10/14 00:08 108-88-32.5 2.5
1,2,3-Trichlorobenzene ND ug/L 09/10/14 00:08 87-61-62.5 2.5
1,2,4-Trichlorobenzene ND ug/L 09/10/14 00:08 120-82-12.5 2.5
1,1,1-Trichloroethane ND ug/L 09/10/14 00:08 71-55-62.5 2.5
1,1,2-Trichloroethane ND ug/L 09/10/14 00:08 79-00-52.5 2.5
Trichloroethene ND ug/L 09/10/14 00:08 79-01-62.5 2.5
Trichlorofluoromethane ND ug/L 09/10/14 00:08 75-69-42.5 2.5
1,2,3-Trichloropropane ND ug/L 09/10/14 00:08 96-18-42.5 2.5
Vinyl acetate ND ug/L 09/10/14 00:08 108-05-45.0 2.5
Vinyl chloride ND ug/L 09/10/14 00:08 75-01-42.5 2.5
Xylene (Total)ND ug/L 09/10/14 00:08 1330-20-75.0 2.5
m&p-Xylene ND ug/L 09/10/14 00:08 179601-23-15.0 2.5
o-Xylene ND ug/L 09/10/14 00:08 95-47-62.5 2.5
Surrogates
4-Bromofluorobenzene (S)98 %09/10/14 00:08 460-00-470-130 2.5
1,2-Dichloroethane-d4 (S)101 %09/10/14 00:08 17060-07-070-130 2.5
Toluene-d8 (S)99 %09/10/14 00:08 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-25 8.29'Lab ID:92216004006 Collected:09/03/14 13:00 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/10/14 00:24 67-64-125010
Benzene ND ug/L 09/10/14 00:24 71-43-210.0 10
Bromobenzene ND ug/L 09/10/14 00:24 108-86-110.0 10
Bromochloromethane ND ug/L 09/10/14 00:24 74-97-510.0 10
Bromodichloromethane ND ug/L 09/10/14 00:24 75-27-410.0 10
Bromoform ND ug/L 09/10/14 00:24 75-25-210.0 10
Bromomethane ND ug/L 09/10/14 00:24 74-83-920.0 10
2-Butanone (MEK)ND ug/L 09/10/14 00:24 78-93-350.0 10
Carbon tetrachloride ND ug/L 09/10/14 00:24 56-23-510.0 10
Chlorobenzene ND ug/L 09/10/14 00:24 108-90-710.0 10
Chloroethane ND ug/L 09/10/14 00:24 75-00-310.0 10
Chloroform ND ug/L 09/10/14 00:24 67-66-310.0 10
Chloromethane ND ug/L 09/10/14 00:24 74-87-310.0 10
2-Chlorotoluene ND ug/L 09/10/14 00:24 95-49-810.0 10
4-Chlorotoluene ND ug/L 09/10/14 00:24 106-43-410.0 10
1,2-Dibromo-3-chloropropane ND ug/L 09/10/14 00:24 96-12-820.0 10
Dibromochloromethane ND ug/L 09/10/14 00:24 124-48-110.0 10
1,2-Dibromoethane (EDB)ND ug/L 09/10/14 00:24 106-93-410.0 10
Dibromomethane ND ug/L 09/10/14 00:24 74-95-310.0 10
1,2-Dichlorobenzene ND ug/L 09/10/14 00:24 95-50-110.0 10
1,3-Dichlorobenzene ND ug/L 09/10/14 00:24 541-73-110.0 10
1,4-Dichlorobenzene ND ug/L 09/10/14 00:24 106-46-710.0 10
Dichlorodifluoromethane ND ug/L 09/10/14 00:24 75-71-810.0 10
1,1-Dichloroethane ND ug/L 09/10/14 00:24 75-34-310.0 10
1,2-Dichloroethane ND ug/L 09/10/14 00:24 107-06-210.0 10
1,1-Dichloroethene ND ug/L 09/10/14 00:24 75-35-410.0 10
cis-1,2-Dichloroethene 977 ug/L 09/10/14 00:24 156-59-210.0 10
trans-1,2-Dichloroethene ND ug/L 09/10/14 00:24 156-60-510.0 10
1,2-Dichloropropane ND ug/L 09/10/14 00:24 78-87-510.0 10
1,3-Dichloropropane ND ug/L 09/10/14 00:24 142-28-910.0 10
2,2-Dichloropropane ND ug/L 09/10/14 00:24 594-20-710.0 10
1,1-Dichloropropene ND ug/L 09/10/14 00:24 563-58-610.0 10
cis-1,3-Dichloropropene ND ug/L 09/10/14 00:24 10061-01-510.0 10
trans-1,3-Dichloropropene ND ug/L 09/10/14 00:24 10061-02-610.0 10
Diisopropyl ether ND ug/L 09/10/14 00:24 108-20-310.0 10
Ethylbenzene ND ug/L 09/10/14 00:24 100-41-410.0 10
Hexachloro-1,3-butadiene ND ug/L 09/10/14 00:24 87-68-310.0 10
2-Hexanone ND ug/L 09/10/14 00:24 591-78-650.0 10
p-Isopropyltoluene ND ug/L 09/10/14 00:24 99-87-610.0 10
Methylene Chloride ND ug/L 09/10/14 00:24 75-09-220.0 10
4-Methyl-2-pentanone (MIBK)ND ug/L 09/10/14 00:24 108-10-150.0 10
Methyl-tert-butyl ether ND ug/L 09/10/14 00:24 1634-04-410.0 10
Naphthalene ND ug/L 09/10/14 00:24 91-20-310.0 10
Styrene ND ug/L 09/10/14 00:24 100-42-510.0 10
1,1,1,2-Tetrachloroethane ND ug/L 09/10/14 00:24 630-20-610.0 10
1,1,2,2-Tetrachloroethane ND ug/L 09/10/14 00:24 79-34-510.0 10
Tetrachloroethene 1720 ug/L 09/10/14 00:24 127-18-410.0 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-25 8.29'Lab ID:92216004006 Collected:09/03/14 13:00 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/10/14 00:24 108-88-310.0 10
1,2,3-Trichlorobenzene ND ug/L 09/10/14 00:24 87-61-610.0 10
1,2,4-Trichlorobenzene ND ug/L 09/10/14 00:24 120-82-110.0 10
1,1,1-Trichloroethane ND ug/L 09/10/14 00:24 71-55-610.0 10
1,1,2-Trichloroethane ND ug/L 09/10/14 00:24 79-00-510.0 10
Trichloroethene 407 ug/L 09/10/14 00:24 79-01-610.0 10
Trichlorofluoromethane ND ug/L 09/10/14 00:24 75-69-410.0 10
1,2,3-Trichloropropane ND ug/L 09/10/14 00:24 96-18-410.0 10
Vinyl acetate ND ug/L 09/10/14 00:24 108-05-420.0 10
Vinyl chloride ND ug/L 09/10/14 00:24 75-01-410.0 10
Xylene (Total)ND ug/L 09/10/14 00:24 1330-20-720.0 10
m&p-Xylene ND ug/L 09/10/14 00:24 179601-23-120.0 10
o-Xylene ND ug/L 09/10/14 00:24 95-47-610.0 10
Surrogates
4-Bromofluorobenzene (S)101 %09/10/14 00:24 460-00-470-130 10
1,2-Dichloroethane-d4 (S)101 %09/10/14 00:24 17060-07-070-130 10
Toluene-d8 (S)98 %09/10/14 00:24 2037-26-570-130 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-11 21.09'Lab ID:92216004007 Collected:09/03/14 14:00 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Acetone ND ug/L 09/09/14 06:48 67-64-125.0 1
Benzene ND ug/L 09/09/14 06:48 71-43-21.0 1
Bromobenzene ND ug/L 09/09/14 06:48 108-86-11.0 1
Bromochloromethane ND ug/L 09/09/14 06:48 74-97-51.0 1
Bromodichloromethane ND ug/L 09/09/14 06:48 75-27-41.0 1
Bromoform ND ug/L 09/09/14 06:48 75-25-21.0 1
Bromomethane ND ug/L 09/09/14 06:48 74-83-92.0 1
2-Butanone (MEK)ND ug/L 09/09/14 06:48 78-93-35.0 1
Carbon tetrachloride ND ug/L 09/09/14 06:48 56-23-51.0 1
Chlorobenzene ND ug/L 09/09/14 06:48 108-90-71.0 1
Chloroethane ND ug/L 09/09/14 06:48 75-00-31.0 1
Chloroform ND ug/L 09/09/14 06:48 67-66-31.0 1
Chloromethane ND ug/L 09/09/14 06:48 74-87-31.0 1
2-Chlorotoluene ND ug/L 09/09/14 06:48 95-49-81.0 1
4-Chlorotoluene ND ug/L 09/09/14 06:48 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 09/09/14 06:48 96-12-82.0 1
Dibromochloromethane ND ug/L 09/09/14 06:48 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 09/09/14 06:48 106-93-41.0 1
Dibromomethane ND ug/L 09/09/14 06:48 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 09/09/14 06:48 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 09/09/14 06:48 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 09/09/14 06:48 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 09/09/14 06:48 75-71-81.0 1
1,1-Dichloroethane ND ug/L 09/09/14 06:48 75-34-31.0 1
1,2-Dichloroethane ND ug/L 09/09/14 06:48 107-06-21.0 1
1,1-Dichloroethene ND ug/L 09/09/14 06:48 75-35-41.0 1
cis-1,2-Dichloroethene 1.2 ug/L 09/09/14 06:48 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 09/09/14 06:48 156-60-51.0 1
1,2-Dichloropropane ND ug/L 09/09/14 06:48 78-87-51.0 1
1,3-Dichloropropane ND ug/L 09/09/14 06:48 142-28-91.0 1
2,2-Dichloropropane ND ug/L 09/09/14 06:48 594-20-71.0 1
1,1-Dichloropropene ND ug/L 09/09/14 06:48 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 09/09/14 06:48 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 09/09/14 06:48 10061-02-61.0 1
Diisopropyl ether ND ug/L 09/09/14 06:48 108-20-31.0 1
Ethylbenzene ND ug/L 09/09/14 06:48 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 09/09/14 06:48 87-68-31.0 1
2-Hexanone ND ug/L 09/09/14 06:48 591-78-65.0 1
p-Isopropyltoluene ND ug/L 09/09/14 06:48 99-87-61.0 1
Methylene Chloride ND ug/L 09/09/14 06:48 75-09-22.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 09/09/14 06:48 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 09/09/14 06:48 1634-04-41.0 1
Naphthalene ND ug/L 09/09/14 06:48 91-20-31.0 1
Styrene ND ug/L 09/09/14 06:48 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 09/09/14 06:48 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 09/09/14 06:48 79-34-51.0 1
Tetrachloroethene 2.6 ug/L 09/09/14 06:48 127-18-4 C81.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 17 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Sample:MW-11 21.09'Lab ID:92216004007 Collected:09/03/14 14:00 Received:09/04/14 12:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level
Toluene ND ug/L 09/09/14 06:48 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 09/09/14 06:48 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 09/09/14 06:48 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 09/09/14 06:48 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 09/09/14 06:48 79-00-51.0 1
Trichloroethene ND ug/L 09/09/14 06:48 79-01-61.0 1
Trichlorofluoromethane ND ug/L 09/09/14 06:48 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 09/09/14 06:48 96-18-41.0 1
Vinyl acetate ND ug/L 09/09/14 06:48 108-05-42.0 1
Vinyl chloride ND ug/L 09/09/14 06:48 75-01-41.0 1
Xylene (Total)ND ug/L 09/09/14 06:48 1330-20-72.0 1
m&p-Xylene ND ug/L 09/09/14 06:48 179601-23-12.0 1
o-Xylene ND ug/L 09/09/14 06:48 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)102 %09/09/14 06:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %09/09/14 06:48 17060-07-070-130 1
Toluene-d8 (S)97 %09/09/14 06:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 18 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/28257
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92216004001, 92216004002, 92216004003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1280696
Associated Lab Samples:92216004001, 92216004002, 92216004003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 09/08/14 22:56
1,1,1-Trichloroethane ug/L ND 1.0 09/08/14 22:56
1,1,2,2-Tetrachloroethane ug/L ND 1.0 09/08/14 22:56
1,1,2-Trichloroethane ug/L ND 1.0 09/08/14 22:56
1,1-Dichloroethane ug/L ND 1.0 09/08/14 22:56
1,1-Dichloroethene ug/L ND 1.0 09/08/14 22:56
1,1-Dichloropropene ug/L ND 1.0 09/08/14 22:56
1,2,3-Trichlorobenzene ug/L ND 1.0 09/08/14 22:56
1,2,3-Trichloropropane ug/L ND 1.0 09/08/14 22:56
1,2,4-Trichlorobenzene ug/L ND 1.0 09/08/14 22:56
1,2-Dibromo-3-chloropropane ug/L ND 2.0 09/08/14 22:56
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/08/14 22:56
1,2-Dichlorobenzene ug/L ND 1.0 09/08/14 22:56
1,2-Dichloroethane ug/L ND 1.0 09/08/14 22:56
1,2-Dichloropropane ug/L ND 1.0 09/08/14 22:56
1,3-Dichlorobenzene ug/L ND 1.0 09/08/14 22:56
1,3-Dichloropropane ug/L ND 1.0 09/08/14 22:56
1,4-Dichlorobenzene ug/L ND 1.0 09/08/14 22:56
2,2-Dichloropropane ug/L ND 1.0 09/08/14 22:56
2-Butanone (MEK)ug/L ND 5.0 09/08/14 22:56
2-Chlorotoluene ug/L ND 1.0 09/08/14 22:56
2-Hexanone ug/L ND 5.0 09/08/14 22:56
4-Chlorotoluene ug/L ND 1.0 09/08/14 22:56
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 09/08/14 22:56
Acetone ug/L ND 25.0 09/08/14 22:56
Benzene ug/L ND 1.0 09/08/14 22:56
Bromobenzene ug/L ND 1.0 09/08/14 22:56
Bromochloromethane ug/L ND 1.0 09/08/14 22:56
Bromodichloromethane ug/L ND 1.0 09/08/14 22:56
Bromoform ug/L ND 1.0 09/08/14 22:56
Bromomethane ug/L ND 2.0 09/08/14 22:56
Carbon tetrachloride ug/L ND 1.0 09/08/14 22:56
Chlorobenzene ug/L ND 1.0 09/08/14 22:56
Chloroethane ug/L ND 1.0 09/08/14 22:56
Chloroform ug/L ND 1.0 09/08/14 22:56
Chloromethane ug/L ND 1.0 09/08/14 22:56
cis-1,2-Dichloroethene ug/L ND 1.0 09/08/14 22:56
cis-1,3-Dichloropropene ug/L ND 1.0 09/08/14 22:56
Dibromochloromethane ug/L ND 1.0 09/08/14 22:56
Dibromomethane ug/L ND 1.0 09/08/14 22:56
Dichlorodifluoromethane ug/L ND 1.0 09/08/14 22:56
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 19 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1280696
Associated Lab Samples:92216004001, 92216004002, 92216004003
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 09/08/14 22:56
Ethylbenzene ug/L ND 1.0 09/08/14 22:56
Hexachloro-1,3-butadiene ug/L ND 1.0 09/08/14 22:56
m&p-Xylene ug/L ND 2.0 09/08/14 22:56
Methyl-tert-butyl ether ug/L ND 1.0 09/08/14 22:56
Methylene Chloride ug/L ND 2.0 09/08/14 22:56
Naphthalene ug/L ND 1.0 09/08/14 22:56
o-Xylene ug/L ND 1.0 09/08/14 22:56
p-Isopropyltoluene ug/L ND 1.0 09/08/14 22:56
Styrene ug/L ND 1.0 09/08/14 22:56
Tetrachloroethene ug/L ND 1.0 09/08/14 22:56
Toluene ug/L ND 1.0 09/08/14 22:56
trans-1,2-Dichloroethene ug/L ND 1.0 09/08/14 22:56
trans-1,3-Dichloropropene ug/L ND 1.0 09/08/14 22:56
Trichloroethene ug/L ND 1.0 09/08/14 22:56
Trichlorofluoromethane ug/L ND 1.0 09/08/14 22:56
Vinyl acetate ug/L ND 2.0 09/08/14 22:56
Vinyl chloride ug/L ND 1.0 09/08/14 22:56
Xylene (Total)ug/L ND 2.0 09/08/14 22:56
1,2-Dichloroethane-d4 (S)%94 70-130 09/08/14 22:56
4-Bromofluorobenzene (S)%104 70-130 09/08/14 22:56
Toluene-d8 (S)%96 70-130 09/08/14 22:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1280697LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 55.350 111 70-130
1,1,1-Trichloroethane ug/L 51.650 103 70-130
1,1,2,2-Tetrachloroethane ug/L 46.350 93 70-130
1,1,2-Trichloroethane ug/L 51.150 102 70-130
1,1-Dichloroethane ug/L 48.650 97 70-130
1,1-Dichloroethene ug/L 44.850 90 70-132
1,1-Dichloropropene ug/L 51.150 102 70-130
1,2,3-Trichlorobenzene ug/L 52.650 105 70-135
1,2,3-Trichloropropane ug/L 46.550 93 70-130
1,2,4-Trichlorobenzene ug/L 53.250 106 70-134
1,2-Dibromo-3-chloropropane ug/L 42.950 86 70-130
1,2-Dibromoethane (EDB)ug/L 52.450 105 70-130
1,2-Dichlorobenzene ug/L 51.650 103 70-130
1,2-Dichloroethane ug/L 45.950 92 70-130
1,2-Dichloropropane ug/L 48.850 98 70-130
1,3-Dichlorobenzene ug/L 50.950 102 70-130
1,3-Dichloropropane ug/L 47.950 96 70-130
1,4-Dichlorobenzene ug/L 49.950 100 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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[phone]
Page 20 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1280697LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 50.650 101 58-145
2-Butanone (MEK)ug/L 79.1100 79 70-145
2-Chlorotoluene ug/L 49.050 98 70-130
2-Hexanone ug/L 87.1100 87 70-144
4-Chlorotoluene ug/L 48.150 96 70-130
4-Methyl-2-pentanone (MIBK)ug/L 87.5100 87 70-140
Acetone ug/L 78.6100 79 50-175
Benzene ug/L 48.650 97 70-130
Bromobenzene ug/L 48.150 96 70-130
Bromochloromethane ug/L 52.250 104 70-130
Bromodichloromethane ug/L 58.150 116 70-130
Bromoform ug/L 50.850 102 70-130
Bromomethane ug/L 43.950 88 54-130
Carbon tetrachloride ug/L 54.950 110 70-132
Chlorobenzene ug/L 49.150 98 70-130
Chloroethane ug/L 44.850 90 64-134
Chloroform ug/L 53.250 106 70-130
Chloromethane ug/L 43.950 88 64-130
cis-1,2-Dichloroethene ug/L 50.550 101 70-131
cis-1,3-Dichloropropene ug/L 47.450 95 70-130
Dibromochloromethane ug/L 55.550 111 70-130
Dibromomethane ug/L 55.150 110 70-131
Dichlorodifluoromethane ug/L 60.050 120 56-130
Diisopropyl ether ug/L 46.950 94 70-130
Ethylbenzene ug/L 49.150 98 70-130
Hexachloro-1,3-butadiene ug/L 52.350 105 70-130
m&p-Xylene ug/L 99.6100 100 70-130
Methyl-tert-butyl ether ug/L 49.550 99 70-130
Methylene Chloride ug/L 44.150 88 63-130
Naphthalene ug/L 51.950 104 70-138
o-Xylene ug/L 50.050 100 70-130
p-Isopropyltoluene ug/L 52.850 106 70-130
Styrene ug/L 53.350 107 70-130
Tetrachloroethene ug/L 54.450 109 70-130
Toluene ug/L 49.350 99 70-130
trans-1,2-Dichloroethene ug/L 48.450 97 70-130
trans-1,3-Dichloropropene ug/L 46.550 93 70-132
Trichloroethene ug/L 54.750 109 70-130
Trichlorofluoromethane ug/L 48.350 97 62-133
Vinyl acetate ug/L 89.8100 90 66-157
Vinyl chloride ug/L 50.450 101 50-150
Xylene (Total)ug/L 150150 100 70-130
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 21 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1281102MATRIX SPIKE SAMPLE:
MSSpike
Result
92216004002
1,1,1,2-Tetrachloroethane ug/L 21.220 106 70-130ND
1,1,1-Trichloroethane ug/L 21.920 109 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.320 106 70-130ND
1,1,2-Trichloroethane ug/L 20.720 104 70-130ND
1,1-Dichloroethane ug/L 21.520 108 70-130ND
1,1-Dichloroethene ug/L 20.220 101 70-166ND
1,1-Dichloropropene ug/L 21.520 107 70-130ND
1,2,3-Trichlorobenzene ug/L 23.920 119 70-130ND
1,2,3-Trichloropropane ug/L 20.820 104 70-130ND
1,2,4-Trichlorobenzene ug/L 22.720 113 70-130ND
1,2-Dibromo-3-chloropropane ug/L 22.520 112 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.020 110 70-130ND
1,2-Dichlorobenzene ug/L 21.220 106 70-130ND
1,2-Dichloroethane ug/L 19.320 96 70-130ND
1,2-Dichloropropane ug/L 21.120 105 70-130ND
1,3-Dichlorobenzene ug/L 21.220 106 70-130ND
1,3-Dichloropropane ug/L 21.220 106 70-130ND
1,4-Dichlorobenzene ug/L 21.220 106 70-130ND
2,2-Dichloropropane ug/L 21.320 106 70-130ND
2-Butanone (MEK)ug/L 37.540 94 70-130ND
2-Chlorotoluene ug/L 21.620 108 70-130ND
2-Hexanone ug/L 46.940 117 70-130ND
4-Chlorotoluene ug/L 22.120 111 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 44.540 111 70-130ND
Acetone ug/L 34.740 79 70-130ND
Benzene ug/L 21.220 106 70-148ND
Bromobenzene ug/L 21.720 108 70-130ND
Bromochloromethane ug/L 21.320 106 70-130ND
Bromodichloromethane ug/L 20.220 101 70-130ND
Bromoform ug/L 19.920 99 70-130ND
Bromomethane ug/L 16.620 83 70-130ND
Carbon tetrachloride ug/L 22.520 112 70-130ND
Chlorobenzene ug/L 21.420 107 70-146ND
Chloroethane ug/L 17.220 86 70-130ND
Chloroform ug/L 20.220 101 70-130ND
Chloromethane ug/L 13.4 M0206770-130ND
cis-1,2-Dichloroethene ug/L 21.720 108 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 20.120 101 70-130ND
Dibromomethane ug/L 20.120 101 70-130ND
Dichlorodifluoromethane ug/L 10.0 M0205070-130ND
Diisopropyl ether ug/L 21.320 107 70-130ND
Ethylbenzene ug/L 21.620 108 70-130ND
Hexachloro-1,3-butadiene ug/L 24.320 122 70-130ND
m&p-Xylene ug/L 43.940 110 70-130ND
Methyl-tert-butyl ether ug/L 20.920 105 70-130ND
Methylene Chloride ug/L 18.420 92 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 22 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1281102MATRIX SPIKE SAMPLE:
MSSpike
Result
92216004002
Naphthalene ug/L 25.120 125 70-130ND
o-Xylene ug/L 21.720 108 70-130ND
p-Isopropyltoluene ug/L 23.020 115 70-130ND
Styrene ug/L 22.720 114 70-130ND
Tetrachloroethene ug/L 44.320 110 70-13022.4
Toluene ug/L 21.120 105 70-155ND
trans-1,2-Dichloroethene ug/L 20.720 104 70-130ND
trans-1,3-Dichloropropene ug/L 20.020 100 70-130ND
Trichloroethene ug/L 21.620 106 69-151ND
Trichlorofluoromethane ug/L 20.220 101 70-130ND
Vinyl acetate ug/L 34.640 86 70-130ND
Vinyl chloride ug/L 16.220 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92216004001
1281101SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L NDND
1,1,1-Trichloroethane ug/L NDND
1,1,2,2-Tetrachloroethane ug/L NDND
1,1,2-Trichloroethane ug/L NDND
1,1-Dichloroethane ug/L NDND
1,1-Dichloroethene ug/L NDND
1,1-Dichloropropene ug/L NDND
1,2,3-Trichlorobenzene ug/L NDND
1,2,3-Trichloropropane ug/L NDND
1,2,4-Trichlorobenzene ug/L NDND
1,2-Dibromo-3-chloropropane ug/L NDND
1,2-Dibromoethane (EDB)ug/L NDND
1,2-Dichlorobenzene ug/L NDND
1,2-Dichloroethane ug/L NDND
1,2-Dichloropropane ug/L NDND
1,3-Dichlorobenzene ug/L NDND
1,3-Dichloropropane ug/L NDND
1,4-Dichlorobenzene ug/L NDND
2,2-Dichloropropane ug/L NDND
2-Butanone (MEK)ug/L NDND
2-Chlorotoluene ug/L NDND
2-Hexanone ug/L NDND
4-Chlorotoluene ug/L NDND
4-Methyl-2-pentanone (MIBK)ug/L NDND
Acetone ug/L NDND
Benzene ug/L NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 23 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92216004001
1281101SAMPLE DUPLICATE:
Bromobenzene ug/L NDND
Bromochloromethane ug/L NDND
Bromodichloromethane ug/L NDND
Bromoform ug/L NDND
Bromomethane ug/L NDND
Carbon tetrachloride ug/L NDND
Chlorobenzene ug/L NDND
Chloroethane ug/L NDND
Chloroform ug/L NDND
Chloromethane ug/L NDND
cis-1,2-Dichloroethene ug/L NDND
cis-1,3-Dichloropropene ug/L NDND
Dibromochloromethane ug/L NDND
Dibromomethane ug/L NDND
Dichlorodifluoromethane ug/L NDND
Diisopropyl ether ug/L NDND
Ethylbenzene ug/L NDND
Hexachloro-1,3-butadiene ug/L NDND
m&p-Xylene ug/L NDND
Methyl-tert-butyl ether ug/L NDND
Methylene Chloride ug/L NDND
Naphthalene ug/L NDND
o-Xylene ug/L NDND
p-Isopropyltoluene ug/L NDND
Styrene ug/L NDND
Tetrachloroethene ug/L 7.6 37.8
Toluene ug/L NDND
trans-1,2-Dichloroethene ug/L NDND
trans-1,3-Dichloropropene ug/L NDND
Trichloroethene ug/L NDND
Trichlorofluoromethane ug/L NDND
Vinyl acetate ug/L NDND
Vinyl chloride ug/L NDND
Xylene (Total)ug/L NDND
1,2-Dichloroethane-d4 (S)%100 298
4-Bromofluorobenzene (S)%101 2103
Toluene-d8 (S)%98 395
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
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Page 24 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/28319
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92216004004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1285290
Associated Lab Samples:92216004004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 09/16/14 03:29
1,1,1-Trichloroethane ug/L ND 1.0 09/16/14 03:29
1,1,2,2-Tetrachloroethane ug/L ND 1.0 09/16/14 03:29
1,1,2-Trichloroethane ug/L ND 1.0 09/16/14 03:29
1,1-Dichloroethane ug/L ND 1.0 09/16/14 03:29
1,1-Dichloroethene ug/L ND 1.0 09/16/14 03:29
1,1-Dichloropropene ug/L ND 1.0 09/16/14 03:29
1,2,3-Trichlorobenzene ug/L ND 1.0 09/16/14 03:29
1,2,3-Trichloropropane ug/L ND 1.0 09/16/14 03:29
1,2,4-Trichlorobenzene ug/L ND 1.0 09/16/14 03:29
1,2-Dibromo-3-chloropropane ug/L ND 2.0 09/16/14 03:29
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/16/14 03:29
1,2-Dichlorobenzene ug/L ND 1.0 09/16/14 03:29
1,2-Dichloroethane ug/L ND 1.0 09/16/14 03:29
1,2-Dichloropropane ug/L ND 1.0 09/16/14 03:29
1,3-Dichlorobenzene ug/L ND 1.0 09/16/14 03:29
1,3-Dichloropropane ug/L ND 1.0 09/16/14 03:29
1,4-Dichlorobenzene ug/L ND 1.0 09/16/14 03:29
2,2-Dichloropropane ug/L ND 1.0 09/16/14 03:29
2-Butanone (MEK)ug/L ND 5.0 09/16/14 03:29
2-Chlorotoluene ug/L ND 1.0 09/16/14 03:29
2-Hexanone ug/L ND 5.0 09/16/14 03:29
4-Chlorotoluene ug/L ND 1.0 09/16/14 03:29
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 09/16/14 03:29
Acetone ug/L ND 25.0 09/16/14 03:29
Benzene ug/L ND 1.0 09/16/14 03:29
Bromobenzene ug/L ND 1.0 09/16/14 03:29
Bromochloromethane ug/L ND 1.0 09/16/14 03:29
Bromodichloromethane ug/L ND 1.0 09/16/14 03:29
Bromoform ug/L ND 1.0 09/16/14 03:29
Bromomethane ug/L ND 2.0 09/16/14 03:29
Carbon tetrachloride ug/L ND 1.0 09/16/14 03:29
Chlorobenzene ug/L ND 1.0 09/16/14 03:29
Chloroethane ug/L ND 1.0 09/16/14 03:29
Chloroform ug/L ND 1.0 09/16/14 03:29
Chloromethane ug/L ND 1.0 09/16/14 03:29
cis-1,2-Dichloroethene ug/L ND 1.0 09/16/14 03:29
cis-1,3-Dichloropropene ug/L ND 1.0 09/16/14 03:29
Dibromochloromethane ug/L ND 1.0 09/16/14 03:29
Dibromomethane ug/L ND 1.0 09/16/14 03:29
Dichlorodifluoromethane ug/L ND 1.0 09/16/14 03:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1285290
Associated Lab Samples:92216004004
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 09/16/14 03:29
Ethylbenzene ug/L ND 1.0 09/16/14 03:29
Hexachloro-1,3-butadiene ug/L ND 1.0 09/16/14 03:29
m&p-Xylene ug/L ND 2.0 09/16/14 03:29
Methyl-tert-butyl ether ug/L ND 1.0 09/16/14 03:29
Methylene Chloride ug/L ND 2.0 09/16/14 03:29
Naphthalene ug/L ND 1.0 09/16/14 03:29
o-Xylene ug/L ND 1.0 09/16/14 03:29
p-Isopropyltoluene ug/L ND 1.0 09/16/14 03:29
Styrene ug/L ND 1.0 09/16/14 03:29
Tetrachloroethene ug/L ND 1.0 09/16/14 03:29
Toluene ug/L ND 1.0 09/16/14 03:29
trans-1,2-Dichloroethene ug/L ND 1.0 09/16/14 03:29
trans-1,3-Dichloropropene ug/L ND 1.0 09/16/14 03:29
Trichloroethene ug/L ND 1.0 09/16/14 03:29
Trichlorofluoromethane ug/L ND 1.0 09/16/14 03:29
Vinyl acetate ug/L ND 2.0 09/16/14 03:29
Vinyl chloride ug/L ND 1.0 09/16/14 03:29
Xylene (Total)ug/L ND 2.0 09/16/14 03:29
1,2-Dichloroethane-d4 (S)%94 70-130 09/16/14 03:29
4-Bromofluorobenzene (S)%96 70-130 09/16/14 03:29
Toluene-d8 (S)%100 70-130 09/16/14 03:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1285291LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.450 105 70-130
1,1,1-Trichloroethane ug/L 49.150 98 70-130
1,1,2,2-Tetrachloroethane ug/L 55.550 111 70-130
1,1,2-Trichloroethane ug/L 54.450 109 70-130
1,1-Dichloroethane ug/L 50.850 102 70-130
1,1-Dichloroethene ug/L 58.750 117 70-132
1,1-Dichloropropene ug/L 56.350 113 70-130
1,2,3-Trichlorobenzene ug/L 54.650 109 70-135
1,2,3-Trichloropropane ug/L 54.450 109 70-130
1,2,4-Trichlorobenzene ug/L 52.450 105 70-134
1,2-Dibromo-3-chloropropane ug/L 52.250 104 70-130
1,2-Dibromoethane (EDB)ug/L 53.750 107 70-130
1,2-Dichlorobenzene ug/L 53.450 107 70-130
1,2-Dichloroethane ug/L 48.950 98 70-130
1,2-Dichloropropane ug/L 55.250 110 70-130
1,3-Dichlorobenzene ug/L 53.250 106 70-130
1,3-Dichloropropane ug/L 55.650 111 70-130
1,4-Dichlorobenzene ug/L 52.950 106 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1285291LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 41.050 82 58-145
2-Butanone (MEK)ug/L 114100 114 70-145
2-Chlorotoluene ug/L 52.250 104 70-130
2-Hexanone ug/L 123100 123 70-144
4-Chlorotoluene ug/L 52.450 105 70-130
4-Methyl-2-pentanone (MIBK)ug/L 115100 115 70-140
Acetone ug/L 106100 106 50-175
Benzene ug/L 54.350 109 70-130
Bromobenzene ug/L 52.750 105 70-130
Bromochloromethane ug/L 56.150 112 70-130
Bromodichloromethane ug/L 56.950 114 70-130
Bromoform ug/L 60.250 120 70-130
Bromomethane ug/L 48.050 96 54-130
Carbon tetrachloride ug/L 51.150 102 70-132
Chlorobenzene ug/L 53.750 107 70-130
Chloroethane ug/L 50.850 102 64-134
Chloroform ug/L 58.450 117 70-130
Chloromethane ug/L 55.450 111 64-130
cis-1,2-Dichloroethene ug/L 59.250 118 70-131
cis-1,3-Dichloropropene ug/L 52.350 105 70-130
Dibromochloromethane ug/L 62.250 124 70-130
Dibromomethane ug/L 53.750 107 70-131
Dichlorodifluoromethane ug/L 42.950 86 56-130
Diisopropyl ether ug/L 56.050 112 70-130
Ethylbenzene ug/L 53.150 106 70-130
Hexachloro-1,3-butadiene ug/L 47.050 94 70-130
m&p-Xylene ug/L 105100 105 70-130
Methyl-tert-butyl ether ug/L 53.250 106 70-130
Methylene Chloride ug/L 58.950 118 63-130
Naphthalene ug/L 58.950 118 70-138
o-Xylene ug/L 52.050 104 70-130
p-Isopropyltoluene ug/L 52.350 105 70-130
Styrene ug/L 55.550 111 70-130
Tetrachloroethene ug/L 51.150 102 70-130
Toluene ug/L 53.550 107 70-130
trans-1,2-Dichloroethene ug/L 59.150 118 70-130
trans-1,3-Dichloropropene ug/L 53.150 106 70-132
Trichloroethene ug/L 51.850 104 70-130
Trichlorofluoromethane ug/L 50.450 101 62-133
Vinyl acetate ug/L 147100 147 66-157
Vinyl chloride ug/L 57.250 114 50-150
Xylene (Total)ug/L 157150 105 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1285292MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92216510003
1285293
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 113 70-130110 320ND22.6 22.0
1,1,1-Trichloroethane ug/L 20 109 70-130111 120ND21.9 22.2
1,1,2,2-Tetrachloroethane ug/L 20 116 70-130115 120ND23.3 23.1
1,1,2-Trichloroethane ug/L 20 120 70-130118 220ND23.9 23.5
1,1-Dichloroethane ug/L 20 116 70-130115 120ND23.1 22.9
1,1-Dichloroethene ug/L 20 135 70-166134 120ND27.0 26.8
1,1-Dichloropropene ug/L 20 130 70-130130 020ND25.9 26.0
1,2,3-Trichlorobenzene ug/L 20 120 70-130130 820ND24.1 26.0
1,2,3-Trichloropropane ug/L 20 111 70-130114 220ND22.2 22.7
1,2,4-Trichlorobenzene ug/L 20 122 70-130125 320ND24.3 25.1
1,2-Dibromo-3-chloropropane ug/L 20 111 70-130109 120ND22.2 21.9
1,2-Dibromoethane (EDB)ug/L 20 115 70-130112 320ND23.0 22.3
1,2-Dichlorobenzene ug/L 20 121 70-130128 620ND24.2 25.7
1,2-Dichloroethane ug/L 20 111 70-130108 320ND22.1 21.6
1,2-Dichloropropane ug/L 20 124 70-130122 120ND24.8 24.5
1,3-Dichlorobenzene ug/L 20 120 70-130129 720ND24.0 25.7
1,3-Dichloropropane ug/L 20 118 70-130121 220ND23.7 24.1
1,4-Dichlorobenzene ug/L 20 120 70-130125 520ND23.9 25.0
2,2-Dichloropropane ug/L 20 107 70-130108 120ND21.3 21.5
2-Butanone (MEK)ug/L 40 98 70-130101 340ND39.4 40.5
2-Chlorotoluene ug/L 20 118 70-130125 620ND23.7 25.0
2-Hexanone ug/L 40 107 70-130113 540ND42.9 45.1
4-Chlorotoluene ug/L 20 120 70-130127 620ND23.9 25.4
4-Methyl-2-pentanone (MIBK)ug/L 40 117 70-130120 240ND46.9 47.9
Acetone ug/L 40 105 70-130100 440ND43.9 42.0
Benzene ug/L 20 124 70-148122 220ND24.8 24.4
Bromobenzene ug/L 20 118 70-130122 320ND23.5 24.4
Bromochloromethane ug/L 20 122 70-130121 120ND24.4 24.2
Bromodichloromethane ug/L 20 125 70-130125 020ND25.0 24.9
Bromoform ug/L 20 114 70-130118 420ND22.8 23.6
Bromomethane ug/L M12013170-130137 520ND26.2 27.4
Carbon tetrachloride ug/L 20 116 70-130120 320ND23.1 23.9
Chlorobenzene ug/L 20 118 70-146117 020ND23.6 23.5
Chloroethane ug/L M12013070-130134 320ND26.1 26.8
Chloroform ug/L M12012870-130133 320ND25.6 26.5
Chloromethane ug/L M12013670-130136 020ND27.3 27.3
cis-1,2-Dichloroethene ug/L M12013370-130131 120ND26.5 26.3
cis-1,3-Dichloropropene ug/L 20 115 70-130113 120ND23.0 22.7
Dibromochloromethane ug/L M12012970-130131 120ND25.8 26.1
Dibromomethane ug/L 20 116 70-130115 120ND23.2 23.0
Dichlorodifluoromethane ug/L 20 116 70-130117 120ND23.2 23.4
Diisopropyl ether ug/L 20 123 70-130121 220ND24.6 24.1
Ethylbenzene ug/L 20 119 70-130121 220ND23.9 24.2
Hexachloro-1,3-butadiene ug/L 20 127 70-130115 1020ND25.4 23.1
m&p-Xylene ug/L 40 119 70-130120 140ND47.6 48.1
Methyl-tert-butyl ether ug/L 20 107 70-130105 120ND21.3 21.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1285292MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92216510003
1285293
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 127 70-130124 220ND25.3 24.8
Naphthalene ug/L 20 116 70-130128 1020ND23.2 25.5
o-Xylene ug/L 20 114 70-130118 320ND22.9 23.7
p-Isopropyltoluene ug/L 20 124 70-130129 420ND24.8 25.8
Styrene ug/L 20 119 70-130123 320ND23.9 24.5
Tetrachloroethene ug/L 20 117 70-130124 520ND23.5 24.7
Toluene ug/L 20 119 70-155119 020ND23.8 23.9
trans-1,2-Dichloroethene ug/L M12013670-130132 320ND27.1 26.4
trans-1,3-Dichloropropene ug/L 20 112 70-130113 020ND22.4 22.5
Trichloroethene ug/L 20 115 69-151117 120ND23.1 23.3
Trichlorofluoromethane ug/L 20 121 70-130121 020ND24.3 24.2
Vinyl acetate ug/L M14015770-130155 140ND62.6 62.1
Vinyl chloride ug/L M12013970-130138 120ND27.8 27.6
1,2-Dichloroethane-d4 (S)%95 70-13097
4-Bromofluorobenzene (S)%96 70-13097
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/28372
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92216004005, 92216004006, 92216004007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1287920
Associated Lab Samples:92216004005, 92216004006, 92216004007
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 09/18/14 12:46
1,1,1-Trichloroethane ug/L ND 1.0 09/18/14 12:46
1,1,2,2-Tetrachloroethane ug/L ND 1.0 09/18/14 12:46
1,1,2-Trichloroethane ug/L ND 1.0 09/18/14 12:46
1,1-Dichloroethane ug/L ND 1.0 09/18/14 12:46
1,1-Dichloroethene ug/L ND 1.0 09/18/14 12:46
1,1-Dichloropropene ug/L ND 1.0 09/18/14 12:46
1,2,3-Trichlorobenzene ug/L ND 1.0 09/18/14 12:46
1,2,3-Trichloropropane ug/L ND 1.0 09/18/14 12:46
1,2,4-Trichlorobenzene ug/L ND 1.0 09/18/14 12:46
1,2-Dibromo-3-chloropropane ug/L ND 2.0 09/18/14 12:46
1,2-Dibromoethane (EDB)ug/L ND 1.0 09/18/14 12:46
1,2-Dichlorobenzene ug/L ND 1.0 09/18/14 12:46
1,2-Dichloroethane ug/L ND 1.0 09/18/14 12:46
1,2-Dichloropropane ug/L ND 1.0 09/18/14 12:46
1,3-Dichlorobenzene ug/L ND 1.0 09/18/14 12:46
1,3-Dichloropropane ug/L ND 1.0 09/18/14 12:46
1,4-Dichlorobenzene ug/L ND 1.0 09/18/14 12:46
2,2-Dichloropropane ug/L ND 1.0 09/18/14 12:46
2-Butanone (MEK)ug/L ND 5.0 09/18/14 12:46
2-Chlorotoluene ug/L ND 1.0 09/18/14 12:46
2-Hexanone ug/L ND 5.0 09/18/14 12:46
4-Chlorotoluene ug/L ND 1.0 09/18/14 12:46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 09/18/14 12:46
Acetone ug/L ND 25.0 09/18/14 12:46
Benzene ug/L ND 1.0 09/18/14 12:46
Bromobenzene ug/L ND 1.0 09/18/14 12:46
Bromochloromethane ug/L ND 1.0 09/18/14 12:46
Bromodichloromethane ug/L ND 1.0 09/18/14 12:46
Bromoform ug/L ND 1.0 09/18/14 12:46
Bromomethane ug/L ND 2.0 09/18/14 12:46
Carbon tetrachloride ug/L ND 1.0 09/18/14 12:46
Chlorobenzene ug/L ND 1.0 09/18/14 12:46
Chloroethane ug/L ND 1.0 09/18/14 12:46
Chloroform ug/L ND 1.0 09/18/14 12:46
Chloromethane ug/L ND 1.0 09/18/14 12:46
cis-1,2-Dichloroethene ug/L ND 1.0 09/18/14 12:46
cis-1,3-Dichloropropene ug/L ND 1.0 09/18/14 12:46
Dibromochloromethane ug/L ND 1.0 09/18/14 12:46
Dibromomethane ug/L ND 1.0 09/18/14 12:46
Dichlorodifluoromethane ug/L ND 1.0 09/18/14 12:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1287920
Associated Lab Samples:92216004005, 92216004006, 92216004007
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 09/18/14 12:46
Ethylbenzene ug/L ND 1.0 09/18/14 12:46
Hexachloro-1,3-butadiene ug/L ND 1.0 09/18/14 12:46
m&p-Xylene ug/L ND 2.0 09/18/14 12:46
Methyl-tert-butyl ether ug/L ND 1.0 09/18/14 12:46
Methylene Chloride ug/L ND 2.0 09/18/14 12:46
Naphthalene ug/L ND 1.0 09/18/14 12:46
o-Xylene ug/L ND 1.0 09/18/14 12:46
p-Isopropyltoluene ug/L ND 1.0 09/18/14 12:46
Styrene ug/L ND 1.0 09/18/14 12:46
Tetrachloroethene ug/L ND 1.0 09/18/14 12:46
Toluene ug/L ND 1.0 09/18/14 12:46
trans-1,2-Dichloroethene ug/L ND 1.0 09/18/14 12:46
trans-1,3-Dichloropropene ug/L ND 1.0 09/18/14 12:46
Trichloroethene ug/L ND 1.0 09/18/14 12:46
Trichlorofluoromethane ug/L ND 1.0 09/18/14 12:46
Vinyl acetate ug/L ND 2.0 09/18/14 12:46
Vinyl chloride ug/L ND 1.0 09/18/14 12:46
Xylene (Total)ug/L ND 2.0 09/18/14 12:46
1,2-Dichloroethane-d4 (S)%97 70-130 09/18/14 12:46
4-Bromofluorobenzene (S)%99 70-130 09/18/14 12:46
Toluene-d8 (S)%99 70-130 09/18/14 12:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1287921LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.050 102 70-130
1,1,1-Trichloroethane ug/L 48.650 97 70-130
1,1,2,2-Tetrachloroethane ug/L 50.350 101 70-130
1,1,2-Trichloroethane ug/L 49.750 99 70-130
1,1-Dichloroethane ug/L 47.350 95 70-130
1,1-Dichloroethene ug/L 52.150 104 70-132
1,1-Dichloropropene ug/L 50.950 102 70-130
1,2,3-Trichlorobenzene ug/L 51.550 103 70-135
1,2,3-Trichloropropane ug/L 49.650 99 70-130
1,2,4-Trichlorobenzene ug/L 50.850 102 70-134
1,2-Dibromo-3-chloropropane ug/L 49.050 98 70-130
1,2-Dibromoethane (EDB)ug/L 51.850 104 70-130
1,2-Dichlorobenzene ug/L 50.250 100 70-130
1,2-Dichloroethane ug/L 47.950 96 70-130
1,2-Dichloropropane ug/L 51.550 103 70-130
1,3-Dichlorobenzene ug/L 49.050 98 70-130
1,3-Dichloropropane ug/L 50.350 101 70-130
1,4-Dichlorobenzene ug/L 49.950 100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1287921LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 53.050 106 58-145
2-Butanone (MEK)ug/L 106100 106 70-145
2-Chlorotoluene ug/L 49.250 98 70-130
2-Hexanone ug/L 102100 102 70-144
4-Chlorotoluene ug/L 50.750 101 70-130
4-Methyl-2-pentanone (MIBK)ug/L 110100 110 70-140
Acetone ug/L 65.4100 65 50-175
Benzene ug/L 50.750 101 70-130
Bromobenzene ug/L 51.250 102 70-130
Bromochloromethane ug/L 50.850 102 70-130
Bromodichloromethane ug/L 51.450 103 70-130
Bromoform ug/L 53.350 107 70-130
Bromomethane ug/L 63.050 126 54-130
Carbon tetrachloride ug/L 50.650 101 70-132
Chlorobenzene ug/L 50.550 101 70-130
Chloroethane ug/L 50.350 101 64-134
Chloroform ug/L 52.450 105 70-130
Chloromethane ug/L 53.850 108 64-130
cis-1,2-Dichloroethene ug/L 53.350 107 70-131
cis-1,3-Dichloropropene ug/L 53.450 107 70-130
Dibromochloromethane ug/L 53.750 107 70-130
Dibromomethane ug/L 51.250 102 70-131
Dichlorodifluoromethane ug/L 52.150 104 56-130
Diisopropyl ether ug/L 52.550 105 70-130
Ethylbenzene ug/L 49.750 99 70-130
Hexachloro-1,3-butadiene ug/L 47.050 94 70-130
m&p-Xylene ug/L 101100 101 70-130
Methyl-tert-butyl ether ug/L 39.250 78 70-130
Methylene Chloride ug/L 32.150 64 63-130
Naphthalene ug/L 52.650 105 70-138
o-Xylene ug/L 51.250 102 70-130
p-Isopropyltoluene ug/L 50.750 101 70-130
Styrene ug/L 51.850 104 70-130
Tetrachloroethene ug/L 49.850 100 70-130
Toluene ug/L 51.050 102 70-130
trans-1,2-Dichloroethene ug/L 36.750 73 70-130
trans-1,3-Dichloropropene ug/L 54.750 109 70-132
Trichloroethene ug/L 47.850 96 70-130
Trichlorofluoromethane ug/L 48.450 97 62-133
Vinyl acetate ug/L 121100 121 66-157
Vinyl chloride ug/L 55.050 110 50-150
Xylene (Total)ug/L 153150 102 70-130
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Result may be biased high due to carryover from previously analyzed sample.C8
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92216004
BARKLEY PROPERTY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92216004001 MSV/28257MW-16 22.89 EPA 8260
92216004002 MSV/28257MW-19 9.95'EPA 8260
92216004003 MSV/28257MW-23 7.79'EPA 8260
92216004004 MSV/28319MW-18 7.63'EPA 8260
92216004005 MSV/28372MW-22D 7.12'EPA 8260
92216004006 MSV/28372MW-25 8.29'EPA 8260
92216004007 MSV/28372MW-11 21.09'EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/18/2014 04:47 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 36