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Home My WebLink About13020_Newman Machine_LSA_Report_06_17_2010 REPORT OF LIMITED SITE ASSESSMENT NEWMAN MACHINE PROPERTY 501 JACKSON STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA Project Number: 71107746 Report Date: June 17, 2010 Prepared for: Edwards Companies Columbus, Ohio Prepared by: Charlotte, North Carolina Terracon Consultants, Inc. 2020 Starita Road, Suite E Charlotte, NC 28206 [704] 509 1777 terracon.com June 17, 2010 Mr. Dave Tyndall Edwards Companies 495 South High Street, Suite 150 Columbus, Ohio 43215 Telephone: 614-241-2070 Facsimile: 614-241-2080 Email: dave.tyndall@edwardscdc.com Re: Report of Limited Site Assessment Newman Machine Property 501 Jackson Street Greensboro, Guilford County, North Carolina Project No. 71107746 Dear Mr. Tyndall: Terracon Consultants, Inc. (Terracon) is pleased to submit this Report of Limited Site Assessment (LSA) to Edwards Companies for the above referenced property. The work was performed in general accordance with Terracon’s Proposal 71097E076, dated August 10, 2009. This report has been prepared in accordance with North Carolina Department of Environment and Natural Resources (NCDENR), UST Section Guidelines for Assessment and Corrective Action for UST Releases, dated July 15, 2008, revised December 1, 2008. If you have any questions regarding this report or the assessment activities, please contact us at 704-509-1777. Sincerely, Terracon Consultants, Inc. Stephen C. Brown Christopher L. Corbitt, PG Project Geologist Environmental Services Manager Enclosures Table of Contents A. SITE IDENTIFICATION .......................................................................................................... 1 B. RISK CHARACTERIZATION ................................................................................................. 2 Part I – Groundwater/Surface Water/Vapor Impacts ................................................................. 2 High Risk ............................................................................................................................... 2 Intermediate Risk .................................................................................................................. 2 Part II – Land Use ..................................................................................................................... 3 Property Containing Source Area of Discharge or Release .................................................. 3 Property Surrounding Source Area of Discharge or Release ............................................... 4 C. RECEPTOR INFORMATION ................................................................................................. 4 1. Water Supply Wells .............................................................................................................. 4 2. Public Water Supplies ......................................................................................................... 4 3. Surface Water ..................................................................................................................... 4 4. Wellhead Protection Areas ................................................................................................. 4 5. Deep Aquifers in the Coastal Plain Physiographic Region ................................................. 5 6. Subsurface Structures ........................................................................................................ 5 7. Property Owners and Occupants ........................................................................................ 5 D. SITE GEOLOGY AND HYDROGEOLOGY ............................................................................ 5 E. SAMPLING RESULTS ........................................................................................................... 6 1. Soil Sampling ...................................................................................................................... 6 2. Groundwater Sampling ....................................................................................................... 7 3. Monitoring Well Construction Information ........................................................................... 7 F. CONCLUSIONS AND RECOMMENDATIONS ...................................................................... 7 Table of Contents Cont'd FIGURES Figure 1: Receptor Survey Map Figure 2: Site and Surrounding Properties Map Figure 3: USGS Topographic Map Figure 4: Monitoring Well Location Map TABLES Table 1: Summary of Soil Sampling Analyses Table 2: Summary of Groundwater Analyses APPENDICES Appendix A: Laboratory Analytical Results and Chain-of-Custody Forms Appendix B: Well Construction Records Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 1 REPORT OF LIMITED SITE ASSESSMENT A. Site Identification Date of Report: June 17, 2010 NCDENR Incident No: Not Assigned Facility ID: Not Assigned Site Name: Newman Machine Property Site Location: 501 Jackson Street Greensboro, Guilford County, North Carolina (336) 273-8261 Land Use Category: Industrial UST Owner/Operator: Newman Machine Company 507 Jackson Street Greensboro, North Carolina Current Property Owner: Newman Machine Company 507 Jackson Street Greensboro, North Carolina (336) 273-8261 Owner’s Representative: Mr. James N. Duggins, Jr. Tuggle Duggins & Merchan, P.A. (336) 271-5214 Consultant: Terracon Consultants, Inc. (Contact: Stephen Brown) 2020-E Starita Road Charlotte, North Carolina 28206 (704) 509-1777 Release Information: As part of our initial sampling activities conducted at Newman Machine Company in July 2009, Terracon utilizing a Geoprobe® drill rig advanced soil boring B-3 to a depth of approximately 30 feet below ground surface (bgs) and boring B-4 to refusal at a depth of approximately 15 feet bgs in an area reported by Newman personnel as having contained a gasoline UST and dispenser. A soil sample from each boring was submitted for laboratory analysis by Total Petroleum Hydrocarbons (TPH) for Gasoline Range Organics (GRO) and Diesel Range Organics (DRO). As a result of elevated soil vapor readings measured on a Foxboro Total Vapor Analyzer (TVA), a second soil sample was collected from a deeper interval in boring B-3 and submitted for analysis of volatile and semi-volatile organic compounds by EPA Methods 8260 and 8270, respectively. A water sample was also collected from boring B-3 and submitted for analysis of volatile and semi-volatile organic compounds by EPA Methods 8260 and 8270, respectively. The laboratory results from the soil and groundwater samples obtained from borings B-3 and B-4 indicated the need to conduct a Limited Site Assessment at the location of the former gasoline UST. Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 3 9. Is the discharge or release located in the Coastal Plain region as designated on the map entitled “Geology of North Carolina” published by the NCDENR in 1985? NO 10. Do the levels of groundwater contamination for any contaminant exceed the gross contamination levels established by the NCDENR? NO Part II – Land Use The questions in Part II pertain to the “source area” property. 1. Does the property contain one or more primary or secondary residences (permanent or temporary)? NO 2. Does the property contain a school, daycare center, hospital, playground, park, recreation area, church, nursing home, or other place of public assembly? NO 3. Does the property contain a commercial (e.g., retail, warehouse, office/business space) or industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum bulk storage) enterprise, an inactive commercial or industrial enterprise, or is the land undeveloped? YES, the property is occupied by a former textile machine company. 4. Do children visit the property? YES, but not regularly. 5. Is access to the property reliably restricted consistent with its use (such as fences, security personnel or both)? YES, the property is enclosed by a chain-link fence. 6. Do pavements, buildings, or other structures cap the contaminated soil? YES If yes, what mechanisms are in place or can be utilized to ensure that the contaminated soil will remain capped in the foreseeable future. Our risk management plan will stipulate that the source area will be capped as a result of future development on the site. 7. What is the zoning status of the property? Recently rezoned as Conditional – Planned Unit Development – Infill District (CD-PDI) 8. Is the use of the property likely to change in the next 20 years? YES, the site is planned for development as residential (student housing). The questions below pertain to nearby properties within 1500 feet of the source area of the discharge or release (excluding the property containing the source area of the release). 9. What is the distance from the source area of the release to the nearest primary or secondary residence (permanent or temporary)? The nearest residences are located approximately 300 feet northwest of the source area, across Spring Garden Street. Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 4 10. What is the distance from the source area of the release to the nearest school, daycare center, hospital, playground, park, recreation area, church, nursing home or other place of public assembly? The nearest school is located about 1150 feet south of the source area along West Lee Street. Greensboro College is located about 800 feet to the north. The nearest church is located approximately 700 feet to the northwest. 11. What is the zoning status of properties in the surrounding area? Adjacent properties to the north, south, east and west are zoned as Conditional – Planned Unit Development – Infill District (CD-PDI). An adjacent property to the northwest is zoned as single-family residential (RS-5). Areas farther to the north are zoned as residential (RS-5 and RM-26). 12. Briefly characterize the use and activities of the properties in the surrounding area. Land use for the surrounding area is primarily residential with commercial development to the south along West Lee Street. C. RECEPTOR INFORMATION 1. Water Supply Wells To determine the presence of water supply wells in the vicinity of the project site, Terracon performed a walking/driving reconnaissance in the project area. No well houses were identified from public streets. A number of water meters were identified in the area. According to information obtained during the reconnaissance, there do not appear to be any water supply wells within the 1,500 foot radius of the source area of the release. 2. Public Water Supplies Public water supply is available for the site and surrounding properties. Based on information obtained from the City of Greensboro Water Resources Department website, the Guilford County public water source is the Reedy Fork Creek stream system either from Lake Brandt (situated approximately 7.5 miles northwest of the site) or Lake Townsend (situated approximately 6.5 miles north of the site). 3. Surface Water Based on review of the USGS Topographic Map, an unnamed tributary to North Buffalo Creek is situated approximately 1,100 feet northeast of the site. The unnamed tributary is shown on Figure 1 – Receptor Survey Map. 4. Wellhead Protection Areas According to the NCDENR public water supply website, the source area for the release is not located within 1,500 feet of a wellhead protection area as defined in 42 USC 300h-7(e). (http://www.deh.enr.state.nc.us/pws/wellhead/update/wellhead_protection_program.htm). Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 5 5. Deep Aquifers in the Coastal Plain Physiographic Province Based upon our review of the Geologic Map of North Carolina (1985), the site is located within the Carolina Slate Belt of the Piedmont Physiographic Province. The soils encountered in the Piedmont are the residual products of in-place weathering of the underlying bedrock. The site is underlain by metamorphosed granite. 6. Subsurface Structures Subsurface structures beneath and adjacent to the site include utility lines (storm sewer, sanitary sewer, municipal water and natural gas). Buried utilities are typically at depths between 2 to 6 feet below ground surface. Municipal sanitary sewer service is planned for use at the site. 7. Property Owners and Occupants The site is currently occupied by Newman Machine Company, Inc. Contiguous properties consist of other portions of the Newman Machine property and City of Greensboro parcels. A site and surrounding properties map is included as Figure 2. This information was obtained as part of the receptor survey conducted in November 2009 from a review of data obtained from the City of Greensboro. D. SITE GEOLOGY AND HYDROGEOLOGY The following resources were reviewed to evaluate site-specific geological and hydrogeological characteristics. • Topographic Map, 7.5-minute series, Greensboro, North Carolina Quadrangle dated 1951 and revised in 1994, published by the US Geological Survey (Figure 3) • Geologic Map of North Carolina, dated 1985 • The Geology of the Carolinas, Carolina Geological Society Fiftieth Anniversary Volume, edited by J. Wright Horton, Jr., and Victor A. Zullo, The University of Tennessee Press, dated 1991 • Soil Survey of Guilford County, North Carolina, United States Department of Agriculture and Soil Conservation Service, dated 1977 The site is located within the Piedmont Physiographic Province. The Piedmont generally consists of low, rounded hills and long rolling northeast to southwest trending ridges with incised creeks and river channels. Based on the geologic map, the site is located in the Carolina Slate Belt. According to the geologic map, the site is underlain by metamorphosed granitic rock. In-place chemical and physical weathering of parent rocks typically form residual soils in the Piedmont region. Weathering is facilitated by the presence of fractures, joints, and less resistant minerals in the rock. In areas not altered by erosion, alluvial deposition or the activities of man, the Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 6 typical residual soil profile consists of clay-rich unconsolidated materials at the surface, transitioning to sandy silts and silty sands at depth. Typically, the boundary between soil and rock is not sharply defined. This transitional zone is termed “partially weathered rock” or saprolite. According to soils information obtained from the Guilford County Soil Survey, soils on the site are mapped as Urban land (UL) which indicates the soils have been altered of changed by man-made activities such as grading, cutting or filling. In the Piedmont, groundwater generally occurs in pore spaces within soils and in the structural features present in the underlying rock (i.e. joints, fractures, and faults). Recharge to the water table is primarily by precipitation infiltrating the surficial soils and percolating downward under the influence of gravity to the water table (vadose zone). Typically, the water table is not a level surface, but a subdued reflection of the land surface. The depth to the water table is not consistent and is dependent upon several factors that include the amount of rainfall, permeability of the soil, the extent of fracturing in the underlying rock and the influences of groundwater pumping. Groundwater typically flows in directions parallel to the ground surface and under the influence of gravity, migrates to discharge points such as surface water features, the toes of slopes or natural springs. Please note that fluctuations in the depth of the water table can be expected depending on variations in precipitation, surface water run-off and other factors not evident at the time of our subsurface exploration. Normally, the highest levels of the water table occur in late winter and spring and the lowest levels occur in the late summer and fall. Based on an interpreted groundwater flow direction, groundwater is expected to flow to the northeast at the site. E. SAMPLING ACTIVITIES 1. Soil Sampling Activities Hollow-stem auger boring MW-3 was advanced to an approximate depth of 30 feet bgs within the former gasoline UST basin (suspect source area) on August 25, 2009. The location of the boring is depicted on Figure 4. Soil samples were collected from the boring at approximate 5-foot intervals beginning at a depth of approximately 8 to 10 feet due to backfilled soils placed in the excavation after the UST was removed. A strong petroleum odor was detected in the residual soils (sandy silts) during the drilling activities. Soil samples collected from 8 to 10 feet and 18 to 20 feet bgs were labeled and stored in an ice- packed cooler pending delivery to the laboratory. Chain-of-custody documentation was maintained with the samples. The samples were submitted to Pace Analytical (Pace) in Huntersville, North Carolina for laboratory analysis of volatile organic compounds (VOCs) by EPA Method 8260, semi- volatile organic compounds (SVOCs) by EPA Method 8270 and Massachusetts Department of Environmental Protection (MADEP) extractable petroleum hydrocarbons (EPH) and volatile petroleum hydrocarbons (VPH). The two soil samples submitted for analysis were obtained at 10-ft intervals based on a projected depth to groundwater greater than 25 feet bgs. Although various petroleum constituents were detected in the two soil samples from boring MW-3 Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 7 above their respective Soil to Groundwater Maximum Soil Contaminant Concentrations (MSCC), none of the targeted analytes exceed their respective Residential MSCCs. A summary of analytical results from the soil sampling activities is provided in Table 1. A copy of the laboratory analytical report is provided in Appendix B. 2. Groundwater Sampling Activities As part of the requirements for the LSA, a Type-II groundwater monitoring well was installed in boring MW-3 once groundwater was encountered in the boring. Well MW-3 was installed at the site on August 25, 2009 in accordance with NCDENR 15A NCAC 2C well construction regulations. No evidence of free product was encountered in the well. The depth to groundwater in well MW-3 was measured at 27.7 feet bgs after the water table had stabilized. A groundwater sample was collected from well MW-3 on September 1, 2009. The sample was stored in an ice-packed cooler pending delivery to Pace. Chain-of-custody documentation was maintained with the sample. The water sample was submitted for laboratory analysis of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, EPH and VPH by MADEP Methods and lead by EPA Method 200.7. The results of the laboratory analyses for well MW-3 indicated multiple petroleum constituents were detected in the groundwater sample. The following targeted analytes were detected at concentrations above their respective NCDENR NCAC 15A 2L regulatory standards: lead (24.2 ug/L); benzene (83.1 ug/L); 1, 2-dichloroethane (7.2 ug/L); C5 to C8 aliphatic compounds (962 ug/L); C9 to C12 aliphatic compounds (2310 ug/L); C9-C10 aromatic compounds (310 ug/L); and tetrachloroethene (2 ug/L). The remaining constituents were detected at levels below the 2L standards. None of the detected constituents exceed their respective Gross Contamination Levels (GCLs) for groundwater. A summary of analytical results from the groundwater sampling activities is provided in Table 2. A copy of the laboratory analytical report is provided in Appendix B. 3. Monitoring Well Construction Information Monitoring well MW-3 was constructed of 2-inch diameter, schedule 40 PVC riser pipe (15 feet) and a 15 ft section of 2-inch diameter, 0.010-inch machine slotted PVC well screen. Construction details for well MW-3 are depicted in Appendix C. F. CONCLUSIONS AND RECOMMENDATIONS Based on the findings of our LSA activities completed at the project site, Terracon is providing the following conclusions. • No free product was observed in monitoring well MW-3 during the completion of the LSA. • Contiguous properties surrounding the project site consist of other portions of the Newman Machine Company property and City of Greensboro parcels. Beyond the property boundaries of Newman Machine Company, the nearby properties are comprised of mostly residential and commercial development. Newman Machine Property Project Number 71107746 501 Jackson Street June 17, 2010 8 • Laboratory results of the two soil samples from boring MW-3 (obtained at depths of 8 to 10 feet and 18 to 20 feet) detected seven petroleum-related constituents at concentrations above their corresponding Soil to Groundwater MSCCs. • None of the detected analytes in the soils from well MW-3 exceeded Residential MSCCs. • Laboratory results of the groundwater sample from monitoring well MW-3 detected six target constituents at concentrations above their corresponding NCAC 15A 2L groundwater quality standards. Benzene and 1,2-dichloroethane exceed their established 2L regulatory standards by a factor greater than 10. • None of the detected analytes in the groundwater from well MW-3 exceeded their respective Gross Contamination Levels. • The source of contaminants (gasoline UST) has been removed. • The site currently meets the NCDENR criteria for Low Risk. Since remaining impacted soils are inaccessible due to on-site conditions (building and high-voltage transformer pad), Terracon recommends regulatory closure of the release incident associated with the former gasoline UST located at Newman Machine Company because constituents of concern do not exceed residential MSCCs. Furthermore, constituent concentrations detected in the groundwater do not exceed Gross Contamination Levels. As part of the requirements for closure, a Notice of Residual Petroleum (NRP) will be completed and recorded on the property deed, restricting the future use of soil and groundwater on land parcel 7864343002. Figures UT of North RECEPTOR SURVEY MAP NEWMAN MACHINE PROPERTY 501 JACKSON STREET GREENSBORO, NORTH CAROLINA REFERENCE: USGS Topographic Map; Greensboro, North Carolin Buffalo Creek 1,500 ft denotes approximate site boundary. PROJECT NO.: 71097758 DATE: MAY 26, 2010 DRAWN BY: SCB SCALE: 1”=500’FIGURE NO. 1 na Quadrangle; dated 1951 and revised in 1994. City of Greensboro 7864343City of Greensboro 7864330977 7864333636 SITE AND SURROUNDING PROPERTIES MAP NEWMAN MACHINE PROPERTY 501 JACKSON STREET REFERENCE: City of Greensboro Geographic Information Syst GREENSBORO, NORTH CAROLINA 7864344129 3105 7864344038 7864344040 7864334934 786433483678 6 4 3 3 3 6 3 6 denotes approximate site boundary. PROJECT NO.: 71097746 DATE: JUNE 16, 2010 DRAWN BY: SCB SCALE: NOT TO SCALE FIGURE NO. 2 tem (GIS) via the Internet. N TOPOGRAPHIC MAP NEWMAN MACHINE PROPERTY 507 JACKSON STREET GREENSBORO, NORTH CAROLINA REFERENCE: USGS Topographic Map; Greensboro, North Carolin SITE PROJECT NO.: 71097746 DATE: SEPTEMBER 28, 2009 DRAWN BY: SCB SCALE: 1” = 2000’FIGURE NO. 3 na Quadrangle; dated 1951 and revised in 1994. SITE PLAN NEWMAN MACHINE PROPERTY 501 JACKSON STREET REFERENCE: City of Greensboro Geographic Information Syst GREENSBORO, NORTH CAROLINA MW-3 denotes approximate site boundary. PROJECT NO.: 71097746 DATE: JUNE 16, 2010 DRAWN BY: SCB SCALE: NOT TO SCALE FIGURE NO. 4 tem (GIS) via the Internet. Tables TA B L E 1 So i l S a m p l i n g A n a l y t i c a l R e s u l t s S u m m a r y Ne w m a n M a c h i n e F o r m e r G a s o l i n e U S T 50 1 J a c k s o n S t r e e t Gr e e n s b o r o , N o r t h C a r o l i n a Te r r a c o n P r o j e c t N u m b e r : 7 1 0 9 7 7 4 6 MA D E P EP H MA D E P VP H MA D E P VP H MA D E P VP H 82 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 7 0 D Da t e C o l l e c t e d (m m / d d / y y ) Sa m p l e De p t h (f t B G S ) B- 3 8 / 2 7 / 0 9 8 - 1 0 N D 0 . 0 1 5 0 . 0 3 6 0 . 0 1 1 2 . 9 5 7 . 5 6 0 . 8 8 0 . 9 7 4 . 8 3 3 . 8 N D 2 0 . 6 8 . 2 3 4 . 6 2 8 . 7 5 . 8 8 N D B- 3 8 / 2 7 / 0 9 1 8 - 2 0 0 . 0 1 9 0 . 0 3 2 0 . 0 5 1 0 . 0 1 6 1 . 3 5 3 . 3 6 N D N D 4 . 2 9 1 . 5 1 0 . 8 6 1 1 . 9 3 . 4 8 1 2 . 2 8 . 9 6 3 . 2 7 1 . 2 6 33 0 0 7 2 3 3 0 0 3 4 4 . 3 4 . 6 1 . 7 N S 0 . 5 8 1 . 7 7 . 3 7 . 5 7 . 3 5 5 5 0 . 5 8 93 8 6 9 3 9 9 3 8 6 4 6 9 6 2 6 1 , 5 6 0 1 , 5 6 4 N S 3 1 3 6 2 6 3 , 2 0 0 7 8 2 7 8 2 3 , 1 2 9 3 , 1 2 9 3 , 1 2 9 3 1 3 • f t . B G S = f e e t b e l o w g r o u n d s u r f a c e • L a b o r a t o r y r e s u l t s r e p o r t e d i n m i l l i g r a m s p e r k i l o g r a m ( m g / k g ) . • N S i n d i c a t e s n o r e g u l a t o r y s t a n d a r d h a s b e e n e s t a b l i s h e d a t t h i s t i m e . So i l - t o - W a t e r M a x i m u m S o i l C o n t a m i n a n t Co n c e n t r a t i o n ( M S C C ) Re s i d e n t i a l M a x i m u m S o i l C o n t a m i n a n t Co n c e n t r a t i o n ( M S C C ) n - b u t y l b e n z e n e A l i p h a t i c ( C 0 5 - C 0 8 ) p - i s o p r o p y l t o l u e n e i s o p r o p y l b e n z e n e napathalene toluene 1,2,4-trimethylbenzene 1,3,5-trimethylbenzene xylenes (total)m&p - xylenes o - xylenes n - p r o p y l b e n z e n e An a l y t i c a l M e t h o d e t h y l b e n z e n e Sa m p l e ID Co n t a m i n a n t o f C o n c e r n → A r o m a t i c ( C 0 9 - C 1 0 ) A l i p h a t i c ( C 0 9 - C 1 8 ) n a p h t h a l e n e A l i p h a t i c ( C 0 9 - C 1 2 ) TA B L E 2 Gr o u n d w a t e r S a m p l i n g A n a l y t i c a l R e s u l t s S u m m a r y Ne w m a n M a c h i n e F o r m e r G a s o l i n e U S T 50 1 J a c k s o n S t r e e t Gr e e n s b o r o , N or t h C a r o l i n a Te r r a c o n P r o j e c t N u m b e r : 7 1 0 9 7 7 4 6 MA D E P EP H MA D E P VP H MA D E P VP H MA D E P VP H 82 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 6 0 B 8 2 7 0 D 3 0 3 0 We l l / S a m p l e I. D . Da t e Co l l e c t e d (m m / d d / y y ) MW - 3 9 / 1 / 0 9 ND 96 2 2 3 1 0 3 1 0 43 . 3 83 . 1 1. 8 7. 2 1. 2 9 . 4 1 5 6 1 0 13 2 125 2 7 2 1 2 9 ND 24.2 - 40 0 7 0 0 2 0 0 6 0 0 1 7 0 0 . 3 8 7 0 7 0 6 0 0 2 0 6 0 . 7 6 0 0 5 0 0 5 0 0 -15 - NL N L N L 7 0 0 , 0 0 0 5 0 0 0 7 0 , 0 0 0 3 8 0 7 0 , 0 0 0 7 0 , 0 0 0 8 4 , 5 0 0 2 0 0 , 0 0 0 1 5 , 5 0 0 7 0 0 2 5 7 , 5 0 0 8 7 , 5 0 0 8 7 , 5 0 0 -15,000 • L a b o r a t o r y r e s u l t s r e p o r t e d i n m i c r o g r a m s p e r l i t e r ( µ g / l ) . • C o n t a m i n a n t s d e t e c t e d a b o v e t h e N o r t h C a r o l i n a 2 L S t a n d a r d a r e s h o w n i n bo l d . • 2 L S t a n d a r d = 1 5 A N C A C 2 L G r o u n d w a t e r C l a s s i f i c a t i o n s a n d S t a n d a r d s • N o r t h C a r o l i n a G C L = N o r t h C a r o l i n a G r o s s C o n t a m i n a t i o n L e v e l f o r G r u n d w a t e r • N D = N o t D e t e c t e d i n c o n c e n t r a t i o n s a b o v e t h e m e t h o d d e t e c t i o n l i m i t . • N L = I n d i c a t e s c o n s t i t u e n t n o t l i s t e d i n t h e N o r t h C a r o l i n a r e g u l a t o r y s t a n d a r d . An a l y t i c a l M e t h o d (e . g . V O C b y E P A 8 2 6 0 ) A r o m a t i c ( C 0 9 - C 1 0 ) lead o-xylene tetrachloroethen e All Target Analytes m e t h y l t e r t - b u t y l e t h e r naphthalene toluene m&p-xylene e t h y l b e n z e n e c i s 1 , 2 - d i c h l o r o e t h e n e a c e t o n e b e n z e n e c h l o r o f o r m 1 , 2 - d i c h l o r o e t h a n e d i i s o p r o p y l e t h e r No r t h C a r o l i n a G C L ( µ g / l ) Co n t a m i n a n t o f C o n c e r n → A l l T a r g e t A n a l y t e s A l i p h a t i c ( C 0 5 - C 0 8 ) A l i p h a t i c ( C 0 9 - C 1 2 ) 2L S t a n d a r d ( µ g / l ) Appendix A Laboratory Analytical Results and Chain-of-Custody Forms September 09, 2009 LIMS USE: FR - STEPHEN BROWN LIMS OBJECT ID: 9251947 9251947 Project: Pace Project No.: RE: Mr. Stephen Brown Terracon 2020 E Starita Road Charlotte, NC 28206 THE PROVINCE Dear Mr. Brown: Enclosed are the analytical results for sample(s) received by the laboratory on August 27, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com Project Manager Enclosures cc:Mr. Chris Corbitt, Terracon REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Pace Project No.: Project: 9251947 THE PROVINCE Charlotte Certification IDsWest Virginia Certification #: 357Virginia Certification #: 00213 Tennessee Certification #: 04010South Carolina Drinking Water Cert. #: 990060003South Carolina Certification #: 990060001Pennsylvania Certification #: 68-00784Connecticut Certification #: PH-0104 North Carolina Field Services Certification #: 5342North Carolina Drinking Water Certification #: 37706 New Jersey Certification #: NC012Louisiana/LELAP Certification #: 04034Kentucky UST Certification #: 84Florida/NELAP Certification #: E87627North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Project No.: Project: 9251947 THE PROVINCE Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 9251947001 B-4 10-12'ASTM D2974-87 1 PASI-CTNM EPA 8260 71 PASI-CDLK EPA 8270 58 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW 9251947002 B-4 20-22'ASTM D2974-87 1 PASI-CTNM EPA 8260 71 PASI-CDLK EPA 8270 58 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW 9251947003 B-3 8-10'ASTM D2974-87 1 PASI-CTNM EPA 8260 71 PASI-CDLK EPA 8270 58 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW 9251947004 B-3 18-20'ASTM D2974-87 1 PASI-CTNM EPA 8260 71 PASI-CDLK EPA 8270 58 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 10-12'Lab ID:9251947001 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)ND mg/kg 1 09/02/09 11:0908/31/09 18:0012.4 Aliphatic (C19-C36)ND mg/kg 1 09/02/09 11:0908/31/09 18:0012.4 Aromatic (C11-C22)ND mg/kg 1 09/02/09 11:0908/31/09 18:0012.4 Nonatriacontane (S)76 %1 09/02/09 11:09 7194-86-708/31/09 18:0040-140 o-Terphenyl (S)73 %1 09/02/09 11:09 84-15-108/31/09 18:0040-140 2-Fluorobiphenyl (S)80 %1 09/02/09 11:09 321-60-808/31/09 18:0040-140 2-Bromonaphthalene (S)78 %1 09/02/09 11:09 580-13-208/31/09 18:0040-140 VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH Aliphatic (C05-C08)ND mg/kg 1 09/04/09 04:3209/03/09 16:1010.5 Aliphatic (C09-C12)ND mg/kg 1 09/04/09 04:3209/03/09 16:1010.5 Aromatic (C09-C10)ND mg/kg 1 09/04/09 04:3209/03/09 16:1010.5 2,5-Dibromotoluene (PID)(S)106 %1 09/04/09 04:3209/03/09 16:1070-130 2,5-Dibromotoluene (FID)(S)146 %1 09/04/09 04:32 S309/03/09 16:1070-130 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene ND ug/kg 1 08/31/09 18:51 83-32-908/28/09 14:00410 Acenaphthylene ND ug/kg 1 08/31/09 18:51 208-96-808/28/09 14:00410 Anthracene ND ug/kg 1 08/31/09 18:51 120-12-708/28/09 14:00410 Benzo(a)anthracene ND ug/kg 1 08/31/09 18:51 56-55-308/28/09 14:00410 Benzo(a)pyrene ND ug/kg 1 08/31/09 18:51 50-32-808/28/09 14:00410 Benzo(b)fluoranthene ND ug/kg 1 08/31/09 18:51 205-99-208/28/09 14:00410 Benzo(g,h,i)perylene ND ug/kg 1 08/31/09 18:51 191-24-208/28/09 14:00410 Benzo(k)fluoranthene ND ug/kg 1 08/31/09 18:51 207-08-908/28/09 14:00410 Benzoic Acid ND ug/kg 1 08/31/09 18:51 65-85-008/28/09 14:002050 Benzyl alcohol ND ug/kg 1 08/31/09 18:51 100-51-608/28/09 14:00820 4-Bromophenylphenyl ether ND ug/kg 1 08/31/09 18:51 101-55-308/28/09 14:00410 Butylbenzylphthalate ND ug/kg 1 08/31/09 18:51 85-68-708/28/09 14:00410 4-Chloroaniline ND ug/kg 1 08/31/09 18:51 106-47-808/28/09 14:002050 bis(2-Chloroethoxy)methane ND ug/kg 1 08/31/09 18:51 111-91-108/28/09 14:00410 bis(2-Chloroethyl) ether ND ug/kg 1 08/31/09 18:51 111-44-408/28/09 14:00410 bis(2-Chloroisopropyl) ether ND ug/kg 1 08/31/09 18:51 108-60-108/28/09 14:00410 2-Chloronaphthalene ND ug/kg 1 08/31/09 18:51 91-58-708/28/09 14:00410 4-Chlorophenylphenyl ether ND ug/kg 1 08/31/09 18:51 7005-72-308/28/09 14:00410 Chrysene ND ug/kg 1 08/31/09 18:51 218-01-908/28/09 14:00410 Dibenz(a,h)anthracene ND ug/kg 1 08/31/09 18:51 53-70-308/28/09 14:00410 Dibenzofuran ND ug/kg 1 08/31/09 18:51 132-64-908/28/09 14:00410 1,2-Dichlorobenzene ND ug/kg 1 08/31/09 18:51 95-50-108/28/09 14:00410 1,3-Dichlorobenzene ND ug/kg 1 08/31/09 18:51 541-73-108/28/09 14:00410 1,4-Dichlorobenzene ND ug/kg 1 08/31/09 18:51 106-46-708/28/09 14:00410 3,3'-Dichlorobenzidine ND ug/kg 1 08/31/09 18:51 91-94-108/28/09 14:002050 Diethylphthalate ND ug/kg 1 08/31/09 18:51 84-66-208/28/09 14:00410 Dimethylphthalate ND ug/kg 1 08/31/09 18:51 131-11-308/28/09 14:00410 Di-n-butylphthalate ND ug/kg 1 08/31/09 18:51 84-74-208/28/09 14:00410 2,4-Dinitrotoluene ND ug/kg 1 08/31/09 18:51 121-14-208/28/09 14:00410 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 4 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 10-12'Lab ID:9251947001 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 2,6-Dinitrotoluene ND ug/kg 1 08/31/09 18:51 606-20-208/28/09 14:00410 Di-n-octylphthalate ND ug/kg 1 08/31/09 18:51 117-84-008/28/09 14:00410 1,2-Diphenylhydrazine ND ug/kg 1 08/31/09 18:51 122-66-708/28/09 14:00410 bis(2-Ethylhexyl)phthalate ND ug/kg 1 08/31/09 18:51 117-81-708/28/09 14:00410 Fluoranthene ND ug/kg 1 08/31/09 18:51 206-44-008/28/09 14:00410 Fluorene ND ug/kg 1 08/31/09 18:51 86-73-708/28/09 14:00410 Hexachloro-1,3-butadiene ND ug/kg 1 08/31/09 18:51 87-68-308/28/09 14:00410 Hexachlorobenzene ND ug/kg 1 08/31/09 18:51 118-74-108/28/09 14:00410 Hexachlorocyclopentadiene ND ug/kg 1 08/31/09 18:51 77-47-408/28/09 14:00410 Hexachloroethane ND ug/kg 1 08/31/09 18:51 67-72-108/28/09 14:00410 Indeno(1,2,3-cd)pyrene ND ug/kg 1 08/31/09 18:51 193-39-508/28/09 14:00410 Isophorone ND ug/kg 1 08/31/09 18:51 78-59-108/28/09 14:00410 2-Methylnaphthalene ND ug/kg 1 08/31/09 18:51 91-57-608/28/09 14:00410 Naphthalene ND ug/kg 1 08/31/09 18:51 91-20-308/28/09 14:00410 2-Nitroaniline ND ug/kg 1 08/31/09 18:51 88-74-408/28/09 14:002050 3-Nitroaniline ND ug/kg 1 08/31/09 18:51 99-09-208/28/09 14:002050 4-Nitroaniline ND ug/kg 1 08/31/09 18:51 100-01-608/28/09 14:00820 Nitrobenzene ND ug/kg 1 08/31/09 18:51 98-95-308/28/09 14:00410 N-Nitroso-di-n-propylamine ND ug/kg 1 08/31/09 18:51 621-64-708/28/09 14:00410 N-Nitrosodiphenylamine ND ug/kg 1 08/31/09 18:51 86-30-608/28/09 14:00410 Phenanthrene ND ug/kg 1 08/31/09 18:51 85-01-808/28/09 14:00410 Pyrene ND ug/kg 1 08/31/09 18:51 129-00-008/28/09 14:00410 1,2,4-Trichlorobenzene ND ug/kg 1 08/31/09 18:51 120-82-108/28/09 14:00410 Nitrobenzene-d5 (S)52 %1 08/31/09 18:51 4165-60-008/28/09 14:0030-150 2-Fluorobiphenyl (S)58 %1 08/31/09 18:51 321-60-808/28/09 14:0046-120 Terphenyl-d14 (S)53 %1 08/31/09 18:51 1718-51-008/28/09 14:0038-108 Phenol-d6 (S)38 %1 08/31/09 18:51 13127-88-308/28/09 14:0035-120 2-Fluorophenol (S)29 %1 08/31/09 18:51 367-12-408/28/09 14:0024-120 2,4,6-Tribromophenol (S)40 %1 08/31/09 18:51 118-79-6 1g08/28/09 14:0044-136 8260/5035A Volatile Organics Analytical Method: EPA 8260 Acetone ND ug/kg 1 08/28/09 22:09 67-64-1106 Benzene ND ug/kg 1 08/28/09 22:09 71-43-25.3 Bromobenzene ND ug/kg 1 08/28/09 22:09 108-86-15.3 Bromochloromethane ND ug/kg 1 08/28/09 22:09 74-97-55.3 Bromodichloromethane ND ug/kg 1 08/28/09 22:09 75-27-45.3 Bromoform ND ug/kg 1 08/28/09 22:09 75-25-25.3 Bromomethane ND ug/kg 1 08/28/09 22:09 74-83-910.6 2-Butanone (MEK)ND ug/kg 1 08/28/09 22:09 78-93-3106 n-Butylbenzene ND ug/kg 1 08/28/09 22:09 104-51-85.3 sec-Butylbenzene ND ug/kg 1 08/28/09 22:09 135-98-85.3 tert-Butylbenzene ND ug/kg 1 08/28/09 22:09 98-06-65.3 Carbon tetrachloride ND ug/kg 1 08/28/09 22:09 56-23-55.3 Chlorobenzene ND ug/kg 1 08/28/09 22:09 108-90-75.3 Chloroethane ND ug/kg 1 08/28/09 22:09 75-00-310.6 Chloroform ND ug/kg 1 08/28/09 22:09 67-66-35.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 5 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 10-12'Lab ID:9251947001 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 Chloromethane ND ug/kg 1 08/28/09 22:09 74-87-310.6 2-Chlorotoluene ND ug/kg 1 08/28/09 22:09 95-49-85.3 4-Chlorotoluene ND ug/kg 1 08/28/09 22:09 106-43-45.3 1,2-Dibromo-3-chloropropane ND ug/kg 1 08/28/09 22:09 96-12-85.3 Dibromochloromethane ND ug/kg 1 08/28/09 22:09 124-48-15.3 1,2-Dibromoethane (EDB)ND ug/kg 1 08/28/09 22:09 106-93-45.3 Dibromomethane ND ug/kg 1 08/28/09 22:09 74-95-35.3 1,2-Dichlorobenzene ND ug/kg 1 08/28/09 22:09 95-50-15.3 1,3-Dichlorobenzene ND ug/kg 1 08/28/09 22:09 541-73-15.3 1,4-Dichlorobenzene ND ug/kg 1 08/28/09 22:09 106-46-75.3 Dichlorodifluoromethane ND ug/kg 1 08/28/09 22:09 75-71-810.6 1,1-Dichloroethane ND ug/kg 1 08/28/09 22:09 75-34-35.3 1,2-Dichloroethane ND ug/kg 1 08/28/09 22:09 107-06-25.3 1,1-Dichloroethene ND ug/kg 1 08/28/09 22:09 75-35-45.3 cis-1,2-Dichloroethene ND ug/kg 1 08/28/09 22:09 156-59-25.3 trans-1,2-Dichloroethene ND ug/kg 1 08/28/09 22:09 156-60-55.3 1,2-Dichloropropane ND ug/kg 1 08/28/09 22:09 78-87-55.3 1,3-Dichloropropane ND ug/kg 1 08/28/09 22:09 142-28-95.3 2,2-Dichloropropane ND ug/kg 1 08/28/09 22:09 594-20-75.3 1,1-Dichloropropene ND ug/kg 1 08/28/09 22:09 563-58-65.3 cis-1,3-Dichloropropene ND ug/kg 1 08/28/09 22:09 10061-01-55.3 trans-1,3-Dichloropropene ND ug/kg 1 08/28/09 22:09 10061-02-65.3 Diisopropyl ether ND ug/kg 1 08/28/09 22:09 108-20-35.3 Ethylbenzene ND ug/kg 1 08/28/09 22:09 100-41-45.3 Hexachloro-1,3-butadiene ND ug/kg 1 08/28/09 22:09 87-68-35.3 2-Hexanone ND ug/kg 1 08/28/09 22:09 591-78-653.2 Isopropylbenzene (Cumene)ND ug/kg 1 08/28/09 22:09 98-82-85.3 p-Isopropyltoluene ND ug/kg 1 08/28/09 22:09 99-87-65.3 Methylene Chloride ND ug/kg 1 08/28/09 22:09 75-09-221.3 4-Methyl-2-pentanone (MIBK)ND ug/kg 1 08/28/09 22:09 108-10-153.2 Methyl-tert-butyl ether ND ug/kg 1 08/28/09 22:09 1634-04-45.3 Naphthalene ND ug/kg 1 08/28/09 22:09 91-20-35.3 n-Propylbenzene ND ug/kg 1 08/28/09 22:09 103-65-15.3 Styrene ND ug/kg 1 08/28/09 22:09 100-42-55.3 1,1,1,2-Tetrachloroethane ND ug/kg 1 08/28/09 22:09 630-20-65.3 1,1,2,2-Tetrachloroethane ND ug/kg 1 08/28/09 22:09 79-34-55.3 Tetrachloroethene ND ug/kg 1 08/28/09 22:09 127-18-45.3 Toluene ND ug/kg 1 08/28/09 22:09 108-88-35.3 1,2,3-Trichlorobenzene ND ug/kg 1 08/28/09 22:09 87-61-65.3 1,2,4-Trichlorobenzene ND ug/kg 1 08/28/09 22:09 120-82-15.3 1,1,1-Trichloroethane ND ug/kg 1 08/28/09 22:09 71-55-65.3 1,1,2-Trichloroethane ND ug/kg 1 08/28/09 22:09 79-00-55.3 Trichloroethene ND ug/kg 1 08/28/09 22:09 79-01-65.3 Trichlorofluoromethane ND ug/kg 1 08/28/09 22:09 75-69-45.3 1,2,3-Trichloropropane ND ug/kg 1 08/28/09 22:09 96-18-45.3 1,2,4-Trimethylbenzene ND ug/kg 1 08/28/09 22:09 95-63-65.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 6 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 10-12'Lab ID:9251947001 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 1,3,5-Trimethylbenzene ND ug/kg 1 08/28/09 22:09 108-67-85.3 Vinyl acetate ND ug/kg 1 08/28/09 22:09 108-05-453.2 Vinyl chloride ND ug/kg 1 08/28/09 22:09 75-01-410.6 Xylene (Total)ND ug/kg 1 08/28/09 22:09 1330-20-710.6 m&p-Xylene ND ug/kg 1 08/28/09 22:09 1330-20-710.6 o-Xylene ND ug/kg 1 08/28/09 22:09 95-47-65.3 Dibromofluoromethane (S)100 %1 08/28/09 22:09 1868-53-779-116 Toluene-d8 (S)100 %1 08/28/09 22:09 2037-26-588-110 4-Bromofluorobenzene (S)99 %1 08/28/09 22:09 460-00-474-115 1,2-Dichloroethane-d4 (S)93 %1 08/28/09 22:09 17060-07-069-121 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.5 %1 08/31/09 08:440.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 7 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 20-22'Lab ID:9251947002 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)ND mg/kg 1 09/02/09 11:4308/31/09 18:0012.9 Aliphatic (C19-C36)ND mg/kg 1 09/02/09 11:4308/31/09 18:0012.9 Aromatic (C11-C22)ND mg/kg 1 09/02/09 11:4308/31/09 18:0012.9 Nonatriacontane (S)69 %1 09/02/09 11:43 7194-86-708/31/09 18:0040-140 o-Terphenyl (S)68 %1 09/02/09 11:43 84-15-108/31/09 18:0040-140 2-Fluorobiphenyl (S)77 %1 09/02/09 11:43 321-60-808/31/09 18:0040-140 2-Bromonaphthalene (S)81 %1 09/02/09 11:43 580-13-208/31/09 18:0040-140 VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH Aliphatic (C05-C08)ND mg/kg 1 09/04/09 04:5809/03/09 16:1010.4 Aliphatic (C09-C12)ND mg/kg 1 09/04/09 04:5809/03/09 16:1010.4 Aromatic (C09-C10)ND mg/kg 1 09/04/09 04:5809/03/09 16:1010.4 2,5-Dibromotoluene (PID)(S)105 %1 09/04/09 04:5809/03/09 16:1070-130 2,5-Dibromotoluene (FID)(S)125 %1 09/04/09 04:5809/03/09 16:1070-130 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene ND ug/kg 1 08/31/09 20:06 83-32-908/28/09 14:00426 Acenaphthylene ND ug/kg 1 08/31/09 20:06 208-96-808/28/09 14:00426 Anthracene ND ug/kg 1 08/31/09 20:06 120-12-708/28/09 14:00426 Benzo(a)anthracene ND ug/kg 1 08/31/09 20:06 56-55-308/28/09 14:00426 Benzo(a)pyrene ND ug/kg 1 08/31/09 20:06 50-32-808/28/09 14:00426 Benzo(b)fluoranthene ND ug/kg 1 08/31/09 20:06 205-99-208/28/09 14:00426 Benzo(g,h,i)perylene ND ug/kg 1 08/31/09 20:06 191-24-208/28/09 14:00426 Benzo(k)fluoranthene ND ug/kg 1 08/31/09 20:06 207-08-908/28/09 14:00426 Benzoic Acid ND ug/kg 1 08/31/09 20:06 65-85-008/28/09 14:002130 Benzyl alcohol ND ug/kg 1 08/31/09 20:06 100-51-608/28/09 14:00852 4-Bromophenylphenyl ether ND ug/kg 1 08/31/09 20:06 101-55-308/28/09 14:00426 Butylbenzylphthalate ND ug/kg 1 08/31/09 20:06 85-68-708/28/09 14:00426 4-Chloroaniline ND ug/kg 1 08/31/09 20:06 106-47-808/28/09 14:002130 bis(2-Chloroethoxy)methane ND ug/kg 1 08/31/09 20:06 111-91-108/28/09 14:00426 bis(2-Chloroethyl) ether ND ug/kg 1 08/31/09 20:06 111-44-408/28/09 14:00426 bis(2-Chloroisopropyl) ether ND ug/kg 1 08/31/09 20:06 108-60-108/28/09 14:00426 2-Chloronaphthalene ND ug/kg 1 08/31/09 20:06 91-58-708/28/09 14:00426 4-Chlorophenylphenyl ether ND ug/kg 1 08/31/09 20:06 7005-72-308/28/09 14:00426 Chrysene ND ug/kg 1 08/31/09 20:06 218-01-908/28/09 14:00426 Dibenz(a,h)anthracene ND ug/kg 1 08/31/09 20:06 53-70-308/28/09 14:00426 Dibenzofuran ND ug/kg 1 08/31/09 20:06 132-64-908/28/09 14:00426 1,2-Dichlorobenzene ND ug/kg 1 08/31/09 20:06 95-50-108/28/09 14:00426 1,3-Dichlorobenzene ND ug/kg 1 08/31/09 20:06 541-73-108/28/09 14:00426 1,4-Dichlorobenzene ND ug/kg 1 08/31/09 20:06 106-46-708/28/09 14:00426 3,3'-Dichlorobenzidine ND ug/kg 1 08/31/09 20:06 91-94-108/28/09 14:002130 Diethylphthalate ND ug/kg 1 08/31/09 20:06 84-66-208/28/09 14:00426 Dimethylphthalate ND ug/kg 1 08/31/09 20:06 131-11-308/28/09 14:00426 Di-n-butylphthalate ND ug/kg 1 08/31/09 20:06 84-74-208/28/09 14:00426 2,4-Dinitrotoluene ND ug/kg 1 08/31/09 20:06 121-14-208/28/09 14:00426 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 8 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 20-22'Lab ID:9251947002 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 2,6-Dinitrotoluene ND ug/kg 1 08/31/09 20:06 606-20-208/28/09 14:00426 Di-n-octylphthalate ND ug/kg 1 08/31/09 20:06 117-84-008/28/09 14:00426 1,2-Diphenylhydrazine ND ug/kg 1 08/31/09 20:06 122-66-708/28/09 14:00426 bis(2-Ethylhexyl)phthalate ND ug/kg 1 08/31/09 20:06 117-81-708/28/09 14:00426 Fluoranthene ND ug/kg 1 08/31/09 20:06 206-44-008/28/09 14:00426 Fluorene ND ug/kg 1 08/31/09 20:06 86-73-708/28/09 14:00426 Hexachloro-1,3-butadiene ND ug/kg 1 08/31/09 20:06 87-68-308/28/09 14:00426 Hexachlorobenzene ND ug/kg 1 08/31/09 20:06 118-74-108/28/09 14:00426 Hexachlorocyclopentadiene ND ug/kg 1 08/31/09 20:06 77-47-408/28/09 14:00426 Hexachloroethane ND ug/kg 1 08/31/09 20:06 67-72-108/28/09 14:00426 Indeno(1,2,3-cd)pyrene ND ug/kg 1 08/31/09 20:06 193-39-508/28/09 14:00426 Isophorone ND ug/kg 1 08/31/09 20:06 78-59-108/28/09 14:00426 2-Methylnaphthalene ND ug/kg 1 08/31/09 20:06 91-57-608/28/09 14:00426 Naphthalene ND ug/kg 1 08/31/09 20:06 91-20-308/28/09 14:00426 2-Nitroaniline ND ug/kg 1 08/31/09 20:06 88-74-408/28/09 14:002130 3-Nitroaniline ND ug/kg 1 08/31/09 20:06 99-09-208/28/09 14:002130 4-Nitroaniline ND ug/kg 1 08/31/09 20:06 100-01-608/28/09 14:00852 Nitrobenzene ND ug/kg 1 08/31/09 20:06 98-95-308/28/09 14:00426 N-Nitroso-di-n-propylamine ND ug/kg 1 08/31/09 20:06 621-64-708/28/09 14:00426 N-Nitrosodiphenylamine ND ug/kg 1 08/31/09 20:06 86-30-608/28/09 14:00426 Phenanthrene ND ug/kg 1 08/31/09 20:06 85-01-808/28/09 14:00426 Pyrene ND ug/kg 1 08/31/09 20:06 129-00-008/28/09 14:00426 1,2,4-Trichlorobenzene ND ug/kg 1 08/31/09 20:06 120-82-108/28/09 14:00426 Nitrobenzene-d5 (S)51 %1 08/31/09 20:06 4165-60-008/28/09 14:0030-150 2-Fluorobiphenyl (S)71 %1 08/31/09 20:06 321-60-808/28/09 14:0046-120 Terphenyl-d14 (S)62 %1 08/31/09 20:06 1718-51-008/28/09 14:0038-108 Phenol-d6 (S)41 %1 08/31/09 20:06 13127-88-308/28/09 14:0035-120 2-Fluorophenol (S)30 %1 08/31/09 20:06 367-12-408/28/09 14:0024-120 2,4,6-Tribromophenol (S)43 %1 08/31/09 20:06 118-79-6 1g08/28/09 14:0044-136 8260/5035A Volatile Organics Analytical Method: EPA 8260 Acetone ND ug/kg 1 08/28/09 22:27 67-64-1102 Benzene ND ug/kg 1 08/28/09 22:27 71-43-25.1 Bromobenzene ND ug/kg 1 08/28/09 22:27 108-86-15.1 Bromochloromethane ND ug/kg 1 08/28/09 22:27 74-97-55.1 Bromodichloromethane ND ug/kg 1 08/28/09 22:27 75-27-45.1 Bromoform ND ug/kg 1 08/28/09 22:27 75-25-25.1 Bromomethane ND ug/kg 1 08/28/09 22:27 74-83-910.2 2-Butanone (MEK)ND ug/kg 1 08/28/09 22:27 78-93-3102 n-Butylbenzene ND ug/kg 1 08/28/09 22:27 104-51-85.1 sec-Butylbenzene ND ug/kg 1 08/28/09 22:27 135-98-85.1 tert-Butylbenzene ND ug/kg 1 08/28/09 22:27 98-06-65.1 Carbon tetrachloride ND ug/kg 1 08/28/09 22:27 56-23-55.1 Chlorobenzene ND ug/kg 1 08/28/09 22:27 108-90-75.1 Chloroethane ND ug/kg 1 08/28/09 22:27 75-00-310.2 Chloroform ND ug/kg 1 08/28/09 22:27 67-66-35.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 9 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 20-22'Lab ID:9251947002 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 Chloromethane ND ug/kg 1 08/28/09 22:27 74-87-310.2 2-Chlorotoluene ND ug/kg 1 08/28/09 22:27 95-49-85.1 4-Chlorotoluene ND ug/kg 1 08/28/09 22:27 106-43-45.1 1,2-Dibromo-3-chloropropane ND ug/kg 1 08/28/09 22:27 96-12-85.1 Dibromochloromethane ND ug/kg 1 08/28/09 22:27 124-48-15.1 1,2-Dibromoethane (EDB)ND ug/kg 1 08/28/09 22:27 106-93-45.1 Dibromomethane ND ug/kg 1 08/28/09 22:27 74-95-35.1 1,2-Dichlorobenzene ND ug/kg 1 08/28/09 22:27 95-50-15.1 1,3-Dichlorobenzene ND ug/kg 1 08/28/09 22:27 541-73-15.1 1,4-Dichlorobenzene ND ug/kg 1 08/28/09 22:27 106-46-75.1 Dichlorodifluoromethane ND ug/kg 1 08/28/09 22:27 75-71-810.2 1,1-Dichloroethane ND ug/kg 1 08/28/09 22:27 75-34-35.1 1,2-Dichloroethane ND ug/kg 1 08/28/09 22:27 107-06-25.1 1,1-Dichloroethene ND ug/kg 1 08/28/09 22:27 75-35-45.1 cis-1,2-Dichloroethene ND ug/kg 1 08/28/09 22:27 156-59-25.1 trans-1,2-Dichloroethene ND ug/kg 1 08/28/09 22:27 156-60-55.1 1,2-Dichloropropane ND ug/kg 1 08/28/09 22:27 78-87-55.1 1,3-Dichloropropane ND ug/kg 1 08/28/09 22:27 142-28-95.1 2,2-Dichloropropane ND ug/kg 1 08/28/09 22:27 594-20-75.1 1,1-Dichloropropene ND ug/kg 1 08/28/09 22:27 563-58-65.1 cis-1,3-Dichloropropene ND ug/kg 1 08/28/09 22:27 10061-01-55.1 trans-1,3-Dichloropropene ND ug/kg 1 08/28/09 22:27 10061-02-65.1 Diisopropyl ether ND ug/kg 1 08/28/09 22:27 108-20-35.1 Ethylbenzene ND ug/kg 1 08/28/09 22:27 100-41-45.1 Hexachloro-1,3-butadiene ND ug/kg 1 08/28/09 22:27 87-68-35.1 2-Hexanone ND ug/kg 1 08/28/09 22:27 591-78-651.2 Isopropylbenzene (Cumene)ND ug/kg 1 08/28/09 22:27 98-82-85.1 p-Isopropyltoluene ND ug/kg 1 08/28/09 22:27 99-87-65.1 Methylene Chloride ND ug/kg 1 08/28/09 22:27 75-09-220.5 4-Methyl-2-pentanone (MIBK)ND ug/kg 1 08/28/09 22:27 108-10-151.2 Methyl-tert-butyl ether ND ug/kg 1 08/28/09 22:27 1634-04-45.1 Naphthalene ND ug/kg 1 08/28/09 22:27 91-20-35.1 n-Propylbenzene ND ug/kg 1 08/28/09 22:27 103-65-15.1 Styrene ND ug/kg 1 08/28/09 22:27 100-42-55.1 1,1,1,2-Tetrachloroethane ND ug/kg 1 08/28/09 22:27 630-20-65.1 1,1,2,2-Tetrachloroethane ND ug/kg 1 08/28/09 22:27 79-34-55.1 Tetrachloroethene ND ug/kg 1 08/28/09 22:27 127-18-45.1 Toluene ND ug/kg 1 08/28/09 22:27 108-88-35.1 1,2,3-Trichlorobenzene ND ug/kg 1 08/28/09 22:27 87-61-65.1 1,2,4-Trichlorobenzene ND ug/kg 1 08/28/09 22:27 120-82-15.1 1,1,1-Trichloroethane ND ug/kg 1 08/28/09 22:27 71-55-65.1 1,1,2-Trichloroethane ND ug/kg 1 08/28/09 22:27 79-00-55.1 Trichloroethene ND ug/kg 1 08/28/09 22:27 79-01-65.1 Trichlorofluoromethane ND ug/kg 1 08/28/09 22:27 75-69-45.1 1,2,3-Trichloropropane ND ug/kg 1 08/28/09 22:27 96-18-45.1 1,2,4-Trimethylbenzene ND ug/kg 1 08/28/09 22:27 95-63-65.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 10 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-4 20-22'Lab ID:9251947002 Collected:08/27/09 10:00 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 1,3,5-Trimethylbenzene ND ug/kg 1 08/28/09 22:27 108-67-85.1 Vinyl acetate ND ug/kg 1 08/28/09 22:27 108-05-451.2 Vinyl chloride ND ug/kg 1 08/28/09 22:27 75-01-410.2 Xylene (Total)ND ug/kg 1 08/28/09 22:27 1330-20-710.2 m&p-Xylene ND ug/kg 1 08/28/09 22:27 1330-20-710.2 o-Xylene ND ug/kg 1 08/28/09 22:27 95-47-65.1 Dibromofluoromethane (S)99 %1 08/28/09 22:27 1868-53-779-116 Toluene-d8 (S)102 %1 08/28/09 22:27 2037-26-588-110 4-Bromofluorobenzene (S)100 %1 08/28/09 22:27 460-00-474-115 1,2-Dichloroethane-d4 (S)90 %1 08/28/09 22:27 17060-07-069-121 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.5 %1 08/31/09 08:450.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 11 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 8-10'Lab ID:9251947003 Collected:08/27/09 14:10 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)ND mg/kg 1 09/02/09 12:1608/31/09 18:0012.4 Aliphatic (C19-C36)ND mg/kg 1 09/02/09 12:1608/31/09 18:0012.4 Aromatic (C11-C22)ND mg/kg 1 09/02/09 12:1608/31/09 18:0012.4 Nonatriacontane (S)57 %1 09/02/09 12:16 7194-86-708/31/09 18:0040-140 o-Terphenyl (S)55 %1 09/02/09 12:16 84-15-108/31/09 18:0040-140 2-Fluorobiphenyl (S)77 %1 09/02/09 12:16 321-60-808/31/09 18:0040-140 2-Bromonaphthalene (S)82 %1 09/02/09 12:16 580-13-208/31/09 18:0040-140 VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH Aliphatic (C05-C08)14.8 mg/kg 1 09/04/09 05:2209/03/09 16:109.2 Aliphatic (C09-C12)36.2 mg/kg 1 09/04/09 05:2209/03/09 16:109.2 Aromatic (C09-C10)11.3 mg/kg 1 09/04/09 05:2209/03/09 16:109.2 2,5-Dibromotoluene (PID)(S)107 %1 09/04/09 05:2209/03/09 16:1070-130 2,5-Dibromotoluene (FID)(S)125 %1 09/04/09 05:2209/03/09 16:1070-130 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene ND ug/kg 1 08/31/09 20:31 83-32-908/28/09 14:00409 Acenaphthylene ND ug/kg 1 08/31/09 20:31 208-96-808/28/09 14:00409 Anthracene ND ug/kg 1 08/31/09 20:31 120-12-708/28/09 14:00409 Benzo(a)anthracene ND ug/kg 1 08/31/09 20:31 56-55-308/28/09 14:00409 Benzo(a)pyrene ND ug/kg 1 08/31/09 20:31 50-32-808/28/09 14:00409 Benzo(b)fluoranthene ND ug/kg 1 08/31/09 20:31 205-99-208/28/09 14:00409 Benzo(g,h,i)perylene ND ug/kg 1 08/31/09 20:31 191-24-208/28/09 14:00409 Benzo(k)fluoranthene ND ug/kg 1 08/31/09 20:31 207-08-908/28/09 14:00409 Benzoic Acid ND ug/kg 1 08/31/09 20:31 65-85-008/28/09 14:002040 Benzyl alcohol ND ug/kg 1 08/31/09 20:31 100-51-608/28/09 14:00817 4-Bromophenylphenyl ether ND ug/kg 1 08/31/09 20:31 101-55-308/28/09 14:00409 Butylbenzylphthalate ND ug/kg 1 08/31/09 20:31 85-68-708/28/09 14:00409 4-Chloroaniline ND ug/kg 1 08/31/09 20:31 106-47-808/28/09 14:002040 bis(2-Chloroethoxy)methane ND ug/kg 1 08/31/09 20:31 111-91-108/28/09 14:00409 bis(2-Chloroethyl) ether ND ug/kg 1 08/31/09 20:31 111-44-408/28/09 14:00409 bis(2-Chloroisopropyl) ether ND ug/kg 1 08/31/09 20:31 108-60-108/28/09 14:00409 2-Chloronaphthalene ND ug/kg 1 08/31/09 20:31 91-58-708/28/09 14:00409 4-Chlorophenylphenyl ether ND ug/kg 1 08/31/09 20:31 7005-72-308/28/09 14:00409 Chrysene ND ug/kg 1 08/31/09 20:31 218-01-908/28/09 14:00409 Dibenz(a,h)anthracene ND ug/kg 1 08/31/09 20:31 53-70-308/28/09 14:00409 Dibenzofuran ND ug/kg 1 08/31/09 20:31 132-64-908/28/09 14:00409 1,2-Dichlorobenzene ND ug/kg 1 08/31/09 20:31 95-50-108/28/09 14:00409 1,3-Dichlorobenzene ND ug/kg 1 08/31/09 20:31 541-73-108/28/09 14:00409 1,4-Dichlorobenzene ND ug/kg 1 08/31/09 20:31 106-46-708/28/09 14:00409 3,3'-Dichlorobenzidine ND ug/kg 1 08/31/09 20:31 91-94-108/28/09 14:002040 Diethylphthalate ND ug/kg 1 08/31/09 20:31 84-66-208/28/09 14:00409 Dimethylphthalate ND ug/kg 1 08/31/09 20:31 131-11-308/28/09 14:00409 Di-n-butylphthalate ND ug/kg 1 08/31/09 20:31 84-74-208/28/09 14:00409 2,4-Dinitrotoluene ND ug/kg 1 08/31/09 20:31 121-14-208/28/09 14:00409 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 12 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 8-10'Lab ID:9251947003 Collected:08/27/09 14:10 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 2,6-Dinitrotoluene ND ug/kg 1 08/31/09 20:31 606-20-208/28/09 14:00409 Di-n-octylphthalate ND ug/kg 1 08/31/09 20:31 117-84-008/28/09 14:00409 1,2-Diphenylhydrazine ND ug/kg 1 08/31/09 20:31 122-66-708/28/09 14:00409 bis(2-Ethylhexyl)phthalate ND ug/kg 1 08/31/09 20:31 117-81-708/28/09 14:00409 Fluoranthene ND ug/kg 1 08/31/09 20:31 206-44-008/28/09 14:00409 Fluorene ND ug/kg 1 08/31/09 20:31 86-73-708/28/09 14:00409 Hexachloro-1,3-butadiene ND ug/kg 1 08/31/09 20:31 87-68-308/28/09 14:00409 Hexachlorobenzene ND ug/kg 1 08/31/09 20:31 118-74-108/28/09 14:00409 Hexachlorocyclopentadiene ND ug/kg 1 08/31/09 20:31 77-47-408/28/09 14:00409 Hexachloroethane ND ug/kg 1 08/31/09 20:31 67-72-108/28/09 14:00409 Indeno(1,2,3-cd)pyrene ND ug/kg 1 08/31/09 20:31 193-39-508/28/09 14:00409 Isophorone ND ug/kg 1 08/31/09 20:31 78-59-108/28/09 14:00409 2-Methylnaphthalene ND ug/kg 1 08/31/09 20:31 91-57-608/28/09 14:00409 Naphthalene ND ug/kg 1 08/31/09 20:31 91-20-308/28/09 14:00409 2-Nitroaniline ND ug/kg 1 08/31/09 20:31 88-74-408/28/09 14:002040 3-Nitroaniline ND ug/kg 1 08/31/09 20:31 99-09-208/28/09 14:002040 4-Nitroaniline ND ug/kg 1 08/31/09 20:31 100-01-608/28/09 14:00817 Nitrobenzene ND ug/kg 1 08/31/09 20:31 98-95-308/28/09 14:00409 N-Nitroso-di-n-propylamine ND ug/kg 1 08/31/09 20:31 621-64-708/28/09 14:00409 N-Nitrosodiphenylamine ND ug/kg 1 08/31/09 20:31 86-30-608/28/09 14:00409 Phenanthrene ND ug/kg 1 08/31/09 20:31 85-01-808/28/09 14:00409 Pyrene ND ug/kg 1 08/31/09 20:31 129-00-008/28/09 14:00409 1,2,4-Trichlorobenzene ND ug/kg 1 08/31/09 20:31 120-82-108/28/09 14:00409 Nitrobenzene-d5 (S)55 %1 08/31/09 20:31 4165-60-008/28/09 14:0030-150 2-Fluorobiphenyl (S)54 %1 08/31/09 20:31 321-60-808/28/09 14:0046-120 Terphenyl-d14 (S)63 %1 08/31/09 20:31 1718-51-008/28/09 14:0038-108 Phenol-d6 (S)39 %1 08/31/09 20:31 13127-88-308/28/09 14:0035-120 2-Fluorophenol (S)29 %1 08/31/09 20:31 367-12-408/28/09 14:0024-120 2,4,6-Tribromophenol (S)33 %1 08/31/09 20:31 118-79-6 1g08/28/09 14:0044-136 8260/5035A Volatile Organics Analytical Method: EPA 8260 Acetone ND ug/kg 100 08/29/09 00:54 67-64-19740 Benzene ND ug/kg 100 08/29/09 00:54 71-43-2487 Bromobenzene ND ug/kg 100 08/29/09 00:54 108-86-1487 Bromochloromethane ND ug/kg 100 08/29/09 00:54 74-97-5487 Bromodichloromethane ND ug/kg 100 08/29/09 00:54 75-27-4487 Bromoform ND ug/kg 100 08/29/09 00:54 75-25-2487 Bromomethane ND ug/kg 100 08/29/09 00:54 74-83-9974 2-Butanone (MEK)ND ug/kg 100 08/29/09 00:54 78-93-39740 n-Butylbenzene 2950 ug/kg 100 08/29/09 00:54 104-51-8487 sec-Butylbenzene ND ug/kg 100 08/29/09 00:54 135-98-8487 tert-Butylbenzene ND ug/kg 100 08/29/09 00:54 98-06-6487 Carbon tetrachloride ND ug/kg 100 08/29/09 00:54 56-23-5487 Chlorobenzene ND ug/kg 100 08/29/09 00:54 108-90-7487 Chloroethane ND ug/kg 100 08/29/09 00:54 75-00-3974 Chloroform ND ug/kg 100 08/29/09 00:54 67-66-3487 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 13 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 8-10'Lab ID:9251947003 Collected:08/27/09 14:10 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 Chloromethane ND ug/kg 100 08/29/09 00:54 74-87-3974 2-Chlorotoluene ND ug/kg 100 08/29/09 00:54 95-49-8487 4-Chlorotoluene ND ug/kg 100 08/29/09 00:54 106-43-4487 1,2-Dibromo-3-chloropropane ND ug/kg 100 08/29/09 00:54 96-12-8487 Dibromochloromethane ND ug/kg 100 08/29/09 00:54 124-48-1487 1,2-Dibromoethane (EDB)ND ug/kg 100 08/29/09 00:54 106-93-4487 Dibromomethane ND ug/kg 100 08/29/09 00:54 74-95-3487 1,2-Dichlorobenzene ND ug/kg 100 08/29/09 00:54 95-50-1487 1,3-Dichlorobenzene ND ug/kg 100 08/29/09 00:54 541-73-1487 1,4-Dichlorobenzene ND ug/kg 100 08/29/09 00:54 106-46-7487 Dichlorodifluoromethane ND ug/kg 100 08/29/09 00:54 75-71-8974 1,1-Dichloroethane ND ug/kg 100 08/29/09 00:54 75-34-3487 1,2-Dichloroethane ND ug/kg 100 08/29/09 00:54 107-06-2487 1,1-Dichloroethene ND ug/kg 100 08/29/09 00:54 75-35-4487 cis-1,2-Dichloroethene ND ug/kg 100 08/29/09 00:54 156-59-2487 trans-1,2-Dichloroethene ND ug/kg 100 08/29/09 00:54 156-60-5487 1,2-Dichloropropane ND ug/kg 100 08/29/09 00:54 78-87-5487 1,3-Dichloropropane ND ug/kg 100 08/29/09 00:54 142-28-9487 2,2-Dichloropropane ND ug/kg 100 08/29/09 00:54 594-20-7487 1,1-Dichloropropene ND ug/kg 100 08/29/09 00:54 563-58-6487 cis-1,3-Dichloropropene ND ug/kg 100 08/29/09 00:54 10061-01-5487 trans-1,3-Dichloropropene ND ug/kg 100 08/29/09 00:54 10061-02-6487 Diisopropyl ether ND ug/kg 100 08/29/09 00:54 108-20-3487 Ethylbenzene 7560 ug/kg 100 08/29/09 00:54 100-41-4487 Hexachloro-1,3-butadiene ND ug/kg 100 08/29/09 00:54 87-68-3487 2-Hexanone ND ug/kg 100 08/29/09 00:54 591-78-64870 Isopropylbenzene (Cumene)882 ug/kg 100 08/29/09 00:54 98-82-8487 p-Isopropyltoluene 974 ug/kg 100 08/29/09 00:54 99-87-6487 Methylene Chloride ND ug/kg 100 08/29/09 00:54 75-09-21950 4-Methyl-2-pentanone (MIBK)ND ug/kg 100 08/29/09 00:54 108-10-14870 Methyl-tert-butyl ether ND ug/kg 100 08/29/09 00:54 1634-04-4487 Naphthalene 4830 ug/kg 100 08/29/09 00:54 91-20-3487 n-Propylbenzene 3800 ug/kg 100 08/29/09 00:54 103-65-1487 Styrene ND ug/kg 100 08/29/09 00:54 100-42-5487 1,1,1,2-Tetrachloroethane ND ug/kg 100 08/29/09 00:54 630-20-6487 1,1,2,2-Tetrachloroethane ND ug/kg 100 08/29/09 00:54 79-34-5487 Tetrachloroethene ND ug/kg 100 08/29/09 00:54 127-18-4487 Toluene ND ug/kg 100 08/29/09 00:54 108-88-3487 1,2,3-Trichlorobenzene ND ug/kg 100 08/29/09 00:54 87-61-6487 1,2,4-Trichlorobenzene ND ug/kg 100 08/29/09 00:54 120-82-1487 1,1,1-Trichloroethane ND ug/kg 100 08/29/09 00:54 71-55-6487 1,1,2-Trichloroethane ND ug/kg 100 08/29/09 00:54 79-00-5487 Trichloroethene ND ug/kg 100 08/29/09 00:54 79-01-6487 Trichlorofluoromethane ND ug/kg 100 08/29/09 00:54 75-69-4487 1,2,3-Trichloropropane ND ug/kg 100 08/29/09 00:54 96-18-4487 1,2,4-Trimethylbenzene 20600 ug/kg 500 08/31/09 11:20 95-63-62430 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 14 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 8-10'Lab ID:9251947003 Collected:08/27/09 14:10 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 1,3,5-Trimethylbenzene 8220 ug/kg 100 08/29/09 00:54 108-67-8487 Vinyl acetate ND ug/kg 100 08/29/09 00:54 108-05-44870 Vinyl chloride ND ug/kg 100 08/29/09 00:54 75-01-4974 Xylene (Total)34600 ug/kg 100 08/29/09 00:54 1330-20-7974 m&p-Xylene 28700 ug/kg 100 08/29/09 00:54 1330-20-7974 o-Xylene 5880 ug/kg 100 08/29/09 00:54 95-47-6487 Dibromofluoromethane (S)98 %100 08/29/09 00:54 1868-53-779-116 Toluene-d8 (S)100 %100 08/29/09 00:54 2037-26-588-110 4-Bromofluorobenzene (S)100 %100 08/29/09 00:54 460-00-474-115 1,2-Dichloroethane-d4 (S)95 %100 08/29/09 00:54 17060-07-069-121 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.3 %1 08/31/09 08:450.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 15 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 18-20'Lab ID:9251947004 Collected:08/27/09 14:40 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)18.9 mg/kg 1 09/02/09 12:4908/31/09 18:0013.4 Aliphatic (C19-C36)ND mg/kg 1 09/02/09 12:4908/31/09 18:0013.4 Aromatic (C11-C22)ND mg/kg 1 09/02/09 12:4908/31/09 18:0013.4 Nonatriacontane (S)62 %1 09/02/09 12:49 7194-86-708/31/09 18:0040-140 o-Terphenyl (S)65 %1 09/02/09 12:49 84-15-108/31/09 18:0040-140 2-Fluorobiphenyl (S)82 %1 09/02/09 12:49 321-60-808/31/09 18:0040-140 2-Bromonaphthalene (S)81 %1 09/02/09 12:49 580-13-208/31/09 18:0040-140 VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH Aliphatic (C05-C08)31.7 mg/kg 1 09/04/09 05:4609/03/09 16:1010.6 Aliphatic (C09-C12)51.2 mg/kg 1 09/04/09 05:4609/03/09 16:1010.6 Aromatic (C09-C10)15.7 mg/kg 1 09/04/09 05:4609/03/09 16:1010.6 2,5-Dibromotoluene (PID)(S)109 %1 09/04/09 05:4609/03/09 16:1070-130 2,5-Dibromotoluene (FID)(S)115 %1 09/04/09 05:4609/03/09 16:1070-130 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene ND ug/kg 1 08/31/09 20:56 83-32-908/28/09 14:00444 Acenaphthylene ND ug/kg 1 08/31/09 20:56 208-96-808/28/09 14:00444 Anthracene ND ug/kg 1 08/31/09 20:56 120-12-708/28/09 14:00444 Benzo(a)anthracene ND ug/kg 1 08/31/09 20:56 56-55-308/28/09 14:00444 Benzo(a)pyrene ND ug/kg 1 08/31/09 20:56 50-32-808/28/09 14:00444 Benzo(b)fluoranthene ND ug/kg 1 08/31/09 20:56 205-99-208/28/09 14:00444 Benzo(g,h,i)perylene ND ug/kg 1 08/31/09 20:56 191-24-208/28/09 14:00444 Benzo(k)fluoranthene ND ug/kg 1 08/31/09 20:56 207-08-908/28/09 14:00444 Benzoic Acid ND ug/kg 1 08/31/09 20:56 65-85-008/28/09 14:002220 Benzyl alcohol ND ug/kg 1 08/31/09 20:56 100-51-608/28/09 14:00887 4-Bromophenylphenyl ether ND ug/kg 1 08/31/09 20:56 101-55-308/28/09 14:00444 Butylbenzylphthalate ND ug/kg 1 08/31/09 20:56 85-68-708/28/09 14:00444 4-Chloroaniline ND ug/kg 1 08/31/09 20:56 106-47-808/28/09 14:002220 bis(2-Chloroethoxy)methane ND ug/kg 1 08/31/09 20:56 111-91-108/28/09 14:00444 bis(2-Chloroethyl) ether ND ug/kg 1 08/31/09 20:56 111-44-408/28/09 14:00444 bis(2-Chloroisopropyl) ether ND ug/kg 1 08/31/09 20:56 108-60-108/28/09 14:00444 2-Chloronaphthalene ND ug/kg 1 08/31/09 20:56 91-58-708/28/09 14:00444 4-Chlorophenylphenyl ether ND ug/kg 1 08/31/09 20:56 7005-72-308/28/09 14:00444 Chrysene ND ug/kg 1 08/31/09 20:56 218-01-908/28/09 14:00444 Dibenz(a,h)anthracene ND ug/kg 1 08/31/09 20:56 53-70-308/28/09 14:00444 Dibenzofuran ND ug/kg 1 08/31/09 20:56 132-64-908/28/09 14:00444 1,2-Dichlorobenzene ND ug/kg 1 08/31/09 20:56 95-50-108/28/09 14:00444 1,3-Dichlorobenzene ND ug/kg 1 08/31/09 20:56 541-73-108/28/09 14:00444 1,4-Dichlorobenzene ND ug/kg 1 08/31/09 20:56 106-46-708/28/09 14:00444 3,3'-Dichlorobenzidine ND ug/kg 1 08/31/09 20:56 91-94-108/28/09 14:002220 Diethylphthalate ND ug/kg 1 08/31/09 20:56 84-66-208/28/09 14:00444 Dimethylphthalate ND ug/kg 1 08/31/09 20:56 131-11-308/28/09 14:00444 Di-n-butylphthalate ND ug/kg 1 08/31/09 20:56 84-74-208/28/09 14:00444 2,4-Dinitrotoluene ND ug/kg 1 08/31/09 20:56 121-14-208/28/09 14:00444 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 16 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 18-20'Lab ID:9251947004 Collected:08/27/09 14:40 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 2,6-Dinitrotoluene ND ug/kg 1 08/31/09 20:56 606-20-208/28/09 14:00444 Di-n-octylphthalate ND ug/kg 1 08/31/09 20:56 117-84-008/28/09 14:00444 1,2-Diphenylhydrazine ND ug/kg 1 08/31/09 20:56 122-66-708/28/09 14:00444 bis(2-Ethylhexyl)phthalate ND ug/kg 1 08/31/09 20:56 117-81-708/28/09 14:00444 Fluoranthene ND ug/kg 1 08/31/09 20:56 206-44-008/28/09 14:00444 Fluorene ND ug/kg 1 08/31/09 20:56 86-73-708/28/09 14:00444 Hexachloro-1,3-butadiene ND ug/kg 1 08/31/09 20:56 87-68-308/28/09 14:00444 Hexachlorobenzene ND ug/kg 1 08/31/09 20:56 118-74-108/28/09 14:00444 Hexachlorocyclopentadiene ND ug/kg 1 08/31/09 20:56 77-47-408/28/09 14:00444 Hexachloroethane ND ug/kg 1 08/31/09 20:56 67-72-108/28/09 14:00444 Indeno(1,2,3-cd)pyrene ND ug/kg 1 08/31/09 20:56 193-39-508/28/09 14:00444 Isophorone ND ug/kg 1 08/31/09 20:56 78-59-108/28/09 14:00444 2-Methylnaphthalene ND ug/kg 1 08/31/09 20:56 91-57-608/28/09 14:00444 Naphthalene 1260 ug/kg 1 08/31/09 20:56 91-20-308/28/09 14:00444 2-Nitroaniline ND ug/kg 1 08/31/09 20:56 88-74-408/28/09 14:002220 3-Nitroaniline ND ug/kg 1 08/31/09 20:56 99-09-208/28/09 14:002220 4-Nitroaniline ND ug/kg 1 08/31/09 20:56 100-01-608/28/09 14:00887 Nitrobenzene ND ug/kg 1 08/31/09 20:56 98-95-308/28/09 14:00444 N-Nitroso-di-n-propylamine ND ug/kg 1 08/31/09 20:56 621-64-708/28/09 14:00444 N-Nitrosodiphenylamine ND ug/kg 1 08/31/09 20:56 86-30-608/28/09 14:00444 Phenanthrene ND ug/kg 1 08/31/09 20:56 85-01-808/28/09 14:00444 Pyrene ND ug/kg 1 08/31/09 20:56 129-00-008/28/09 14:00444 1,2,4-Trichlorobenzene ND ug/kg 1 08/31/09 20:56 120-82-108/28/09 14:00444 Nitrobenzene-d5 (S)56 %1 08/31/09 20:56 4165-60-008/28/09 14:0030-150 2-Fluorobiphenyl (S)71 %1 08/31/09 20:56 321-60-808/28/09 14:0046-120 Terphenyl-d14 (S)69 %1 08/31/09 20:56 1718-51-008/28/09 14:0038-108 Phenol-d6 (S)39 %1 08/31/09 20:56 13127-88-308/28/09 14:0035-120 2-Fluorophenol (S)37 %1 08/31/09 20:56 367-12-408/28/09 14:0024-120 2,4,6-Tribromophenol (S)42 %1 08/31/09 20:56 118-79-6 1g08/28/09 14:0044-136 8260/5035A Volatile Organics Analytical Method: EPA 8260 Acetone ND ug/kg 100 08/29/09 01:12 67-64-110600 Benzene ND ug/kg 100 08/29/09 01:12 71-43-2532 Bromobenzene ND ug/kg 100 08/29/09 01:12 108-86-1532 Bromochloromethane ND ug/kg 100 08/29/09 01:12 74-97-5532 Bromodichloromethane ND ug/kg 100 08/29/09 01:12 75-27-4532 Bromoform ND ug/kg 100 08/29/09 01:12 75-25-2532 Bromomethane ND ug/kg 100 08/29/09 01:12 74-83-91060 2-Butanone (MEK)ND ug/kg 100 08/29/09 01:12 78-93-310600 n-Butylbenzene 1350 ug/kg 100 08/29/09 01:12 104-51-8532 sec-Butylbenzene ND ug/kg 100 08/29/09 01:12 135-98-8532 tert-Butylbenzene ND ug/kg 100 08/29/09 01:12 98-06-6532 Carbon tetrachloride ND ug/kg 100 08/29/09 01:12 56-23-5532 Chlorobenzene ND ug/kg 100 08/29/09 01:12 108-90-7532 Chloroethane ND ug/kg 100 08/29/09 01:12 75-00-31060 Chloroform ND ug/kg 100 08/29/09 01:12 67-66-3532 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 17 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 18-20'Lab ID:9251947004 Collected:08/27/09 14:40 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 Chloromethane ND ug/kg 100 08/29/09 01:12 74-87-31060 2-Chlorotoluene ND ug/kg 100 08/29/09 01:12 95-49-8532 4-Chlorotoluene ND ug/kg 100 08/29/09 01:12 106-43-4532 1,2-Dibromo-3-chloropropane ND ug/kg 100 08/29/09 01:12 96-12-8532 Dibromochloromethane ND ug/kg 100 08/29/09 01:12 124-48-1532 1,2-Dibromoethane (EDB)ND ug/kg 100 08/29/09 01:12 106-93-4532 Dibromomethane ND ug/kg 100 08/29/09 01:12 74-95-3532 1,2-Dichlorobenzene ND ug/kg 100 08/29/09 01:12 95-50-1532 1,3-Dichlorobenzene ND ug/kg 100 08/29/09 01:12 541-73-1532 1,4-Dichlorobenzene ND ug/kg 100 08/29/09 01:12 106-46-7532 Dichlorodifluoromethane ND ug/kg 100 08/29/09 01:12 75-71-81060 1,1-Dichloroethane ND ug/kg 100 08/29/09 01:12 75-34-3532 1,2-Dichloroethane ND ug/kg 100 08/29/09 01:12 107-06-2532 1,1-Dichloroethene ND ug/kg 100 08/29/09 01:12 75-35-4532 cis-1,2-Dichloroethene ND ug/kg 100 08/29/09 01:12 156-59-2532 trans-1,2-Dichloroethene ND ug/kg 100 08/29/09 01:12 156-60-5532 1,2-Dichloropropane ND ug/kg 100 08/29/09 01:12 78-87-5532 1,3-Dichloropropane ND ug/kg 100 08/29/09 01:12 142-28-9532 2,2-Dichloropropane ND ug/kg 100 08/29/09 01:12 594-20-7532 1,1-Dichloropropene ND ug/kg 100 08/29/09 01:12 563-58-6532 cis-1,3-Dichloropropene ND ug/kg 100 08/29/09 01:12 10061-01-5532 trans-1,3-Dichloropropene ND ug/kg 100 08/29/09 01:12 10061-02-6532 Diisopropyl ether ND ug/kg 100 08/29/09 01:12 108-20-3532 Ethylbenzene 3360 ug/kg 100 08/29/09 01:12 100-41-4532 Hexachloro-1,3-butadiene ND ug/kg 100 08/29/09 01:12 87-68-3532 2-Hexanone ND ug/kg 100 08/29/09 01:12 591-78-65320 Isopropylbenzene (Cumene)ND ug/kg 100 08/29/09 01:12 98-82-8532 p-Isopropyltoluene ND ug/kg 100 08/29/09 01:12 99-87-6532 Methylene Chloride ND ug/kg 100 08/29/09 01:12 75-09-22130 4-Methyl-2-pentanone (MIBK)ND ug/kg 100 08/29/09 01:12 108-10-15320 Methyl-tert-butyl ether ND ug/kg 100 08/29/09 01:12 1634-04-4532 Naphthalene 4290 ug/kg 100 08/29/09 01:12 91-20-3532 n-Propylbenzene 1510 ug/kg 100 08/29/09 01:12 103-65-1532 Styrene ND ug/kg 100 08/29/09 01:12 100-42-5532 1,1,1,2-Tetrachloroethane ND ug/kg 100 08/29/09 01:12 630-20-6532 1,1,2,2-Tetrachloroethane ND ug/kg 100 08/29/09 01:12 79-34-5532 Tetrachloroethene ND ug/kg 100 08/29/09 01:12 127-18-4532 Toluene 858 ug/kg 100 08/29/09 01:12 108-88-3532 1,2,3-Trichlorobenzene ND ug/kg 100 08/29/09 01:12 87-61-6532 1,2,4-Trichlorobenzene ND ug/kg 100 08/29/09 01:12 120-82-1532 1,1,1-Trichloroethane ND ug/kg 100 08/29/09 01:12 71-55-6532 1,1,2-Trichloroethane ND ug/kg 100 08/29/09 01:12 79-00-5532 Trichloroethene ND ug/kg 100 08/29/09 01:12 79-01-6532 Trichlorofluoromethane ND ug/kg 100 08/29/09 01:12 75-69-4532 1,2,3-Trichloropropane ND ug/kg 100 08/29/09 01:12 96-18-4532 1,2,4-Trimethylbenzene 11900 ug/kg 100 08/29/09 01:12 95-63-6532 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 18 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9251947 THE PROVINCE Sample:B-3 18-20'Lab ID:9251947004 Collected:08/27/09 14:40 Received:08/27/09 17:35 Matrix:Solid Results reported on a "dry-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260/5035A Volatile Organics Analytical Method: EPA 8260 1,3,5-Trimethylbenzene 3480 ug/kg 100 08/29/09 01:12 108-67-8532 Vinyl acetate ND ug/kg 100 08/29/09 01:12 108-05-45320 Vinyl chloride ND ug/kg 100 08/29/09 01:12 75-01-41060 Xylene (Total)12200 ug/kg 100 08/29/09 01:12 1330-20-71060 m&p-Xylene 8960 ug/kg 100 08/29/09 01:12 1330-20-71060 o-Xylene 3270 ug/kg 100 08/29/09 01:12 95-47-6532 Dibromofluoromethane (S)96 %100 08/29/09 01:12 1868-53-779-116 Toluene-d8 (S)101 %100 08/29/09 01:12 2037-26-588-110 4-Bromofluorobenzene (S)101 %100 08/29/09 01:12 460-00-474-115 1,2-Dichloroethane-d4 (S)88 %100 08/29/09 01:12 17060-07-069-121 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.6 %1 08/31/09 08:450.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 19 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/8117 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:9251947001, 9251947002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329246 Associated Lab Samples:9251947001, 9251947002 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane ug/kg ND 5.0 08/28/09 15:44 1,1,1-Trichloroethane ug/kg ND 5.0 08/28/09 15:44 1,1,2,2-Tetrachloroethane ug/kg ND 5.0 08/28/09 15:44 1,1,2-Trichloroethane ug/kg ND 5.0 08/28/09 15:44 1,1-Dichloroethane ug/kg ND 5.0 08/28/09 15:44 1,1-Dichloroethene ug/kg ND 5.0 08/28/09 15:44 1,1-Dichloropropene ug/kg ND 5.0 08/28/09 15:44 1,2,3-Trichlorobenzene ug/kg ND 5.0 08/28/09 15:44 1,2,3-Trichloropropane ug/kg ND 5.0 08/28/09 15:44 1,2,4-Trichlorobenzene ug/kg ND 5.0 08/28/09 15:44 1,2,4-Trimethylbenzene ug/kg ND 5.0 08/28/09 15:44 1,2-Dibromo-3-chloropropane ug/kg ND 5.0 08/28/09 15:44 1,2-Dibromoethane (EDB)ug/kg ND 5.0 08/28/09 15:44 1,2-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:44 1,2-Dichloroethane ug/kg ND 5.0 08/28/09 15:44 1,2-Dichloropropane ug/kg ND 5.0 08/28/09 15:44 1,3,5-Trimethylbenzene ug/kg ND 5.0 08/28/09 15:44 1,3-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:44 1,3-Dichloropropane ug/kg ND 5.0 08/28/09 15:44 1,4-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:44 2,2-Dichloropropane ug/kg ND 5.0 08/28/09 15:44 2-Butanone (MEK)ug/kg ND 100 08/28/09 15:44 2-Chlorotoluene ug/kg ND 5.0 08/28/09 15:44 2-Hexanone ug/kg ND 50.0 08/28/09 15:44 4-Chlorotoluene ug/kg ND 5.0 08/28/09 15:44 4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 08/28/09 15:44 Acetone ug/kg ND 100 08/28/09 15:44 Benzene ug/kg ND 5.0 08/28/09 15:44 Bromobenzene ug/kg ND 5.0 08/28/09 15:44 Bromochloromethane ug/kg ND 5.0 08/28/09 15:44 Bromodichloromethane ug/kg ND 5.0 08/28/09 15:44 Bromoform ug/kg ND 5.0 08/28/09 15:44 Bromomethane ug/kg ND 10.0 08/28/09 15:44 Carbon tetrachloride ug/kg ND 5.0 08/28/09 15:44 Chlorobenzene ug/kg ND 5.0 08/28/09 15:44 Chloroethane ug/kg ND 10.0 08/28/09 15:44 Chloroform ug/kg ND 5.0 08/28/09 15:44 Chloromethane ug/kg ND 10.0 08/28/09 15:44 cis-1,2-Dichloroethene ug/kg ND 5.0 08/28/09 15:44 cis-1,3-Dichloropropene ug/kg ND 5.0 08/28/09 15:44 Dibromochloromethane ug/kg ND 5.0 08/28/09 15:44 Dibromomethane ug/kg ND 5.0 08/28/09 15:44 Dichlorodifluoromethane ug/kg ND 10.0 08/28/09 15:44 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 20 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329246 Associated Lab Samples:9251947001, 9251947002 Matrix:Solid Analyzed Diisopropyl ether ug/kg ND 5.0 08/28/09 15:44 Ethylbenzene ug/kg ND 5.0 08/28/09 15:44 Hexachloro-1,3-butadiene ug/kg ND 5.0 08/28/09 15:44 Isopropylbenzene (Cumene)ug/kg ND 5.0 08/28/09 15:44 m&p-Xylene ug/kg ND 10.0 08/28/09 15:44 Methyl-tert-butyl ether ug/kg ND 5.0 08/28/09 15:44 Methylene Chloride ug/kg ND 20.0 08/28/09 15:44 n-Butylbenzene ug/kg ND 5.0 08/28/09 15:44 n-Propylbenzene ug/kg ND 5.0 08/28/09 15:44 Naphthalene ug/kg ND 5.0 08/28/09 15:44 o-Xylene ug/kg ND 5.0 08/28/09 15:44 p-Isopropyltoluene ug/kg ND 5.0 08/28/09 15:44 sec-Butylbenzene ug/kg ND 5.0 08/28/09 15:44 Styrene ug/kg ND 5.0 08/28/09 15:44 tert-Butylbenzene ug/kg ND 5.0 08/28/09 15:44 Tetrachloroethene ug/kg ND 5.0 08/28/09 15:44 Toluene ug/kg ND 5.0 08/28/09 15:44 trans-1,2-Dichloroethene ug/kg ND 5.0 08/28/09 15:44 trans-1,3-Dichloropropene ug/kg ND 5.0 08/28/09 15:44 Trichloroethene ug/kg ND 5.0 08/28/09 15:44 Trichlorofluoromethane ug/kg ND 5.0 08/28/09 15:44 Vinyl acetate ug/kg ND 50.0 08/28/09 15:44 Vinyl chloride ug/kg ND 10.0 08/28/09 15:44 Xylene (Total)ug/kg ND 10.0 08/28/09 15:44 1,2-Dichloroethane-d4 (S)%94 69-121 08/28/09 15:44 4-Bromofluorobenzene (S)%101 74-115 08/28/09 15:44 Dibromofluoromethane (S)%102 79-116 08/28/09 15:44 Toluene-d8 (S)%104 88-110 08/28/09 15:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329247LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/kg 58.850 118 75-137 1,1,1-Trichloroethane ug/kg 53.450 107 70-140 1,1,2,2-Tetrachloroethane ug/kg 58.050 116 74-133 1,1,2-Trichloroethane ug/kg 55.750 111 79-129 1,1-Dichloroethane ug/kg 54.250 108 72-139 1,1-Dichloroethene ug/kg 55.950 112 69-154 1,1-Dichloropropene ug/kg 59.050 118 74-138 1,2,3-Trichlorobenzene ug/kg 62.850 126 71-150 1,2,3-Trichloropropane ug/kg 56.050 112 74-135 1,2,4-Trichlorobenzene ug/kg 69.050 138 68-150 1,2,4-Trimethylbenzene ug/kg 63.650 127 70-130 1,2-Dibromo-3-chloropropane ug/kg 46.950 94 65-146 1,2-Dibromoethane (EDB)ug/kg 58.450 117 77-136 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 21 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329247LABORATORY CONTROL SAMPLE: LCSSpike 1,2-Dichlorobenzene ug/kg 59.950 120 75-141 1,2-Dichloroethane ug/kg 52.350 105 74-134 1,2-Dichloropropane ug/kg 59.050 118 77-138 1,3,5-Trimethylbenzene ug/kg 60.950 122 65-128 1,3-Dichlorobenzene ug/kg 62.050 124 76-133 1,3-Dichloropropane ug/kg 58.750 117 79-132 1,4-Dichlorobenzene ug/kg 60.850 122 75-137 2,2-Dichloropropane ug/kg 58.950 118 73-137 2-Butanone (MEK)ug/kg 101100 101 61-138 2-Chlorotoluene ug/kg 56.250 112 73-138 2-Hexanone ug/kg 107100 107 58-159 4-Chlorotoluene ug/kg 62.850 126 75-136 4-Methyl-2-pentanone (MIBK)ug/kg 102100 102 74-139 Acetone ug/kg 95.7J100 96 58-150 Benzene ug/kg 55.250 110 71-140 Bromobenzene ug/kg 57.650 115 72-144 Bromochloromethane ug/kg 55.850 112 78-133 Bromodichloromethane ug/kg 52.450 105 78-133 Bromoform ug/kg 53.250 106 74-132 Bromomethane ug/kg 73.750 147 63-184 Carbon tetrachloride ug/kg 55.850 112 73-143 Chlorobenzene ug/kg 59.350 119 77-137 Chloroethane ug/kg 40.250 80 68-146 Chloroform ug/kg 55.350 111 75-137 Chloromethane ug/kg 47.950 96 54-143 cis-1,2-Dichloroethene ug/kg 56.750 113 71-143 cis-1,3-Dichloropropene ug/kg 60.950 122 76-133 Dibromochloromethane ug/kg 54.650 109 77-131 Dibromomethane ug/kg 56.750 113 63-184 Dichlorodifluoromethane ug/kg 40.550 81 36-173 Diisopropyl ether ug/kg 53.450 107 68-144 Ethylbenzene ug/kg 61.150 122 69-141 Hexachloro-1,3-butadiene ug/kg 58.450 117 70-152 Isopropylbenzene (Cumene)ug/kg 64.550 129 77-143 m&p-Xylene ug/kg 126100 126 72-138 Methyl-tert-butyl ether ug/kg 55.050 110 2-138 Methylene Chloride ug/kg 49.450 99 69-136 n-Butylbenzene ug/kg 65.3 L05013165-128 n-Propylbenzene ug/kg 62.150 124 72-139 Naphthalene ug/kg 62.950 126 61-138 o-Xylene ug/kg 61.950 124 74-137 p-Isopropyltoluene ug/kg 63.450 127 66-128 sec-Butylbenzene ug/kg 62.450 125 72-140 Styrene ug/kg 56.950 114 76-137 tert-Butylbenzene ug/kg 59.550 119 68-141 Tetrachloroethene ug/kg 62.250 124 72-136 Toluene ug/kg 57.350 115 69-139 trans-1,2-Dichloroethene ug/kg 53.950 108 72-144 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 22 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329247LABORATORY CONTROL SAMPLE: LCSSpike trans-1,3-Dichloropropene ug/kg 60.050 120 73-135 Trichloroethene ug/kg 57.850 116 75-136 Trichlorofluoromethane ug/kg 48.350 97 69-144 Vinyl acetate ug/kg 203 L310020350-150 Vinyl chloride ug/kg 50.050 100 61-145 Xylene (Total)ug/kg 188150 126 73-138 1,2-Dichloroethane-d4 (S)%90 69-121 4-Bromofluorobenzene (S)%102 74-115 Dibromofluoromethane (S)%98 79-116 Toluene-d8 (S)%101 88-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 329800MATRIX SPIKE SAMPLE: MSSpike Result 9251902001 1,1-Dichloroethene ug/kg 77.351 152 33-158ND Benzene ug/kg 57.451 113 46-143ND Chlorobenzene ug/kg 58.051 114 29-159ND Toluene ug/kg 58.151 114 38-145ND Trichloroethene ug/kg 59.651 117 70-130ND 1,2-Dichloroethane-d4 (S)%112 69-121 4-Bromofluorobenzene (S)%96 74-115 Dibromofluoromethane (S)%S012379-116 Toluene-d8 (S)%101 88-110 Parameter Units Dup Result QualifiersRPDResult 9251845002 329799SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/kg NDND 1,1,1-Trichloroethane ug/kg NDND 1,1,2,2-Tetrachloroethane ug/kg NDND 1,1,2-Trichloroethane ug/kg NDND 1,1-Dichloroethane ug/kg NDND 1,1-Dichloroethene ug/kg NDND 1,1-Dichloropropene ug/kg NDND 1,2,3-Trichlorobenzene ug/kg NDND 1,2,3-Trichloropropane ug/kg NDND 1,2,4-Trichlorobenzene ug/kg NDND 1,2,4-Trimethylbenzene ug/kg NDND 1,2-Dibromo-3-chloropropane ug/kg NDND 1,2-Dibromoethane (EDB)ug/kg NDND 1,2-Dichlorobenzene ug/kg NDND 1,2-Dichloroethane ug/kg NDND 1,2-Dichloropropane ug/kg NDND 1,3,5-Trimethylbenzene ug/kg NDND 1,3-Dichlorobenzene ug/kg NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 23 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units Dup Result QualifiersRPDResult 9251845002 329799SAMPLE DUPLICATE: 1,3-Dichloropropane ug/kg NDND 1,4-Dichlorobenzene ug/kg NDND 2,2-Dichloropropane ug/kg NDND 2-Butanone (MEK)ug/kg NDND 2-Chlorotoluene ug/kg NDND 2-Hexanone ug/kg NDND 4-Chlorotoluene ug/kg NDND 4-Methyl-2-pentanone (MIBK)ug/kg NDND Acetone ug/kg NDND Benzene ug/kg NDND Bromobenzene ug/kg NDND Bromochloromethane ug/kg NDND Bromodichloromethane ug/kg NDND Bromoform ug/kg NDND Bromomethane ug/kg NDND Carbon tetrachloride ug/kg NDND Chlorobenzene ug/kg NDND Chloroethane ug/kg NDND Chloroform ug/kg NDND Chloromethane ug/kg NDND cis-1,2-Dichloroethene ug/kg NDND cis-1,3-Dichloropropene ug/kg NDND Dibromochloromethane ug/kg NDND Dibromomethane ug/kg NDND Dichlorodifluoromethane ug/kg NDND Diisopropyl ether ug/kg NDND Ethylbenzene ug/kg NDND Hexachloro-1,3-butadiene ug/kg NDND Isopropylbenzene (Cumene)ug/kg NDND m&p-Xylene ug/kg NDND Methyl-tert-butyl ether ug/kg NDND Methylene Chloride ug/kg NDND n-Butylbenzene ug/kg NDND n-Propylbenzene ug/kg NDND Naphthalene ug/kg NDND o-Xylene ug/kg NDND p-Isopropyltoluene ug/kg NDND sec-Butylbenzene ug/kg NDND Styrene ug/kg NDND tert-Butylbenzene ug/kg NDND Tetrachloroethene ug/kg NDND Toluene ug/kg NDND trans-1,2-Dichloroethene ug/kg NDND trans-1,3-Dichloropropene ug/kg NDND Trichloroethene ug/kg NDND Trichlorofluoromethane ug/kg NDND Vinyl acetate ug/kg NDND Vinyl chloride ug/kg NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 24 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units Dup Result QualifiersRPDResult 9251845002 329799SAMPLE DUPLICATE: Xylene (Total)ug/kg NDND 1,2-Dichloroethane-d4 (S)%87 1594 4-Bromofluorobenzene (S)%100 10102 Dibromofluoromethane (S)%97 998 Toluene-d8 (S)%102 7101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 25 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/2678 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Parameter Units Dup Result QualifiersRPDResult 9251902001 329682SAMPLE DUPLICATE: Percent Moisture %13.6 213.4 Parameter Units Dup Result QualifiersRPDResult 9251851005 329690SAMPLE DUPLICATE: Percent Moisture %24.7 225.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 26 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/8119 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:9251947003, 9251947004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329277 Associated Lab Samples:9251947003, 9251947004 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane ug/kg ND 5.0 08/28/09 15:25 1,1,1-Trichloroethane ug/kg ND 5.0 08/28/09 15:25 1,1,2,2-Tetrachloroethane ug/kg ND 5.0 08/28/09 15:25 1,1,2-Trichloroethane ug/kg ND 5.0 08/28/09 15:25 1,1-Dichloroethane ug/kg ND 5.0 08/28/09 15:25 1,1-Dichloroethene ug/kg ND 5.0 08/28/09 15:25 1,1-Dichloropropene ug/kg ND 5.0 08/28/09 15:25 1,2,3-Trichlorobenzene ug/kg ND 5.0 08/28/09 15:25 1,2,3-Trichloropropane ug/kg ND 5.0 08/28/09 15:25 1,2,4-Trichlorobenzene ug/kg ND 5.0 08/28/09 15:25 1,2,4-Trimethylbenzene ug/kg ND 5.0 08/28/09 15:25 1,2-Dibromo-3-chloropropane ug/kg ND 5.0 08/28/09 15:25 1,2-Dibromoethane (EDB)ug/kg ND 5.0 08/28/09 15:25 1,2-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:25 1,2-Dichloroethane ug/kg ND 5.0 08/28/09 15:25 1,2-Dichloropropane ug/kg ND 5.0 08/28/09 15:25 1,3,5-Trimethylbenzene ug/kg ND 5.0 08/28/09 15:25 1,3-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:25 1,3-Dichloropropane ug/kg ND 5.0 08/28/09 15:25 1,4-Dichlorobenzene ug/kg ND 5.0 08/28/09 15:25 2,2-Dichloropropane ug/kg ND 5.0 08/28/09 15:25 2-Butanone (MEK)ug/kg ND 100 08/28/09 15:25 2-Chlorotoluene ug/kg ND 5.0 08/28/09 15:25 2-Hexanone ug/kg ND 50.0 08/28/09 15:25 4-Chlorotoluene ug/kg ND 5.0 08/28/09 15:25 4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 08/28/09 15:25 Acetone ug/kg ND 100 08/28/09 15:25 Benzene ug/kg ND 5.0 08/28/09 15:25 Bromobenzene ug/kg ND 5.0 08/28/09 15:25 Bromochloromethane ug/kg ND 5.0 08/28/09 15:25 Bromodichloromethane ug/kg ND 5.0 08/28/09 15:25 Bromoform ug/kg ND 5.0 08/28/09 15:25 Bromomethane ug/kg ND 10.0 08/28/09 15:25 Carbon tetrachloride ug/kg ND 5.0 08/28/09 15:25 Chlorobenzene ug/kg ND 5.0 08/28/09 15:25 Chloroethane ug/kg ND 10.0 08/28/09 15:25 Chloroform ug/kg ND 5.0 08/28/09 15:25 Chloromethane ug/kg ND 10.0 08/28/09 15:25 cis-1,2-Dichloroethene ug/kg ND 5.0 08/28/09 15:25 cis-1,3-Dichloropropene ug/kg ND 5.0 08/28/09 15:25 Dibromochloromethane ug/kg ND 5.0 08/28/09 15:25 Dibromomethane ug/kg ND 5.0 08/28/09 15:25 Dichlorodifluoromethane ug/kg ND 10.0 08/28/09 15:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 27 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329277 Associated Lab Samples:9251947003, 9251947004 Matrix:Solid Analyzed Diisopropyl ether ug/kg ND 5.0 08/28/09 15:25 Ethylbenzene ug/kg ND 5.0 08/28/09 15:25 Hexachloro-1,3-butadiene ug/kg ND 5.0 08/28/09 15:25 Isopropylbenzene (Cumene)ug/kg ND 5.0 08/28/09 15:25 m&p-Xylene ug/kg ND 10.0 08/28/09 15:25 Methyl-tert-butyl ether ug/kg ND 5.0 08/28/09 15:25 Methylene Chloride ug/kg ND 20.0 08/28/09 15:25 n-Butylbenzene ug/kg ND 5.0 08/28/09 15:25 n-Propylbenzene ug/kg ND 5.0 08/28/09 15:25 Naphthalene ug/kg ND 5.0 08/28/09 15:25 o-Xylene ug/kg ND 5.0 08/28/09 15:25 p-Isopropyltoluene ug/kg ND 5.0 08/28/09 15:25 sec-Butylbenzene ug/kg ND 5.0 08/28/09 15:25 Styrene ug/kg ND 5.0 08/28/09 15:25 tert-Butylbenzene ug/kg ND 5.0 08/28/09 15:25 Tetrachloroethene ug/kg ND 5.0 08/28/09 15:25 Toluene ug/kg ND 5.0 08/28/09 15:25 trans-1,2-Dichloroethene ug/kg ND 5.0 08/28/09 15:25 trans-1,3-Dichloropropene ug/kg ND 5.0 08/28/09 15:25 Trichloroethene ug/kg ND 5.0 08/28/09 15:25 Trichlorofluoromethane ug/kg ND 5.0 08/28/09 15:25 Vinyl acetate ug/kg ND 50.0 08/28/09 15:25 Vinyl chloride ug/kg ND 10.0 08/28/09 15:25 Xylene (Total)ug/kg ND 10.0 08/28/09 15:25 1,2-Dichloroethane-d4 (S)%90 69-121 08/28/09 15:25 4-Bromofluorobenzene (S)%100 74-115 08/28/09 15:25 Dibromofluoromethane (S)%98 79-116 08/28/09 15:25 Toluene-d8 (S)%100 88-110 08/28/09 15:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329278LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/kg 57.550 115 75-137 1,1,1-Trichloroethane ug/kg 53.350 107 70-140 1,1,2,2-Tetrachloroethane ug/kg 54.650 109 74-133 1,1,2-Trichloroethane ug/kg 54.850 110 79-129 1,1-Dichloroethane ug/kg 54.950 110 72-139 1,1-Dichloroethene ug/kg 56.450 113 69-154 1,1-Dichloropropene ug/kg 59.550 119 74-138 1,2,3-Trichlorobenzene ug/kg 62.850 126 71-150 1,2,3-Trichloropropane ug/kg 54.350 109 74-135 1,2,4-Trichlorobenzene ug/kg 69.450 139 68-150 1,2,4-Trimethylbenzene ug/kg 64.750 129 70-130 1,2-Dibromo-3-chloropropane ug/kg 46.150 92 65-146 1,2-Dibromoethane (EDB)ug/kg 57.450 115 77-136 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 28 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329278LABORATORY CONTROL SAMPLE: LCSSpike 1,2-Dichlorobenzene ug/kg 60.350 121 75-141 1,2-Dichloroethane ug/kg 52.050 104 74-134 1,2-Dichloropropane ug/kg 56.850 114 77-138 1,3,5-Trimethylbenzene ug/kg 62.450 125 65-128 1,3-Dichlorobenzene ug/kg 62.450 125 76-133 1,3-Dichloropropane ug/kg 55.850 112 79-132 1,4-Dichlorobenzene ug/kg 61.950 124 75-137 2,2-Dichloropropane ug/kg 59.650 119 73-137 2-Butanone (MEK)ug/kg 94.5J100 94 61-138 2-Chlorotoluene ug/kg 57.650 115 73-138 2-Hexanone ug/kg 103100 103 58-159 4-Chlorotoluene ug/kg 63.050 126 75-136 4-Methyl-2-pentanone (MIBK)ug/kg 100100 100 74-139 Acetone ug/kg 88.3J100 88 58-150 Benzene ug/kg 55.450 111 71-140 Bromobenzene ug/kg 57.750 115 72-144 Bromochloromethane ug/kg 55.950 112 78-133 Bromodichloromethane ug/kg 52.050 104 78-133 Bromoform ug/kg 50.350 101 74-132 Bromomethane ug/kg 71.950 144 63-184 Carbon tetrachloride ug/kg 55.250 110 73-143 Chlorobenzene ug/kg 58.150 116 77-137 Chloroethane ug/kg 39.850 80 68-146 Chloroform ug/kg 55.050 110 75-137 Chloromethane ug/kg 47.550 95 54-143 cis-1,2-Dichloroethene ug/kg 55.950 112 71-143 cis-1,3-Dichloropropene ug/kg 60.450 121 76-133 Dibromochloromethane ug/kg 53.650 107 77-131 Dibromomethane ug/kg 54.750 109 63-184 Dichlorodifluoromethane ug/kg 40.650 81 36-173 Diisopropyl ether ug/kg 53.250 106 68-144 Ethylbenzene ug/kg 60.750 121 69-141 Hexachloro-1,3-butadiene ug/kg 59.650 119 70-152 Isopropylbenzene (Cumene)ug/kg 63.450 127 77-143 m&p-Xylene ug/kg 125100 125 72-138 Methyl-tert-butyl ether ug/kg 53.750 107 2-138 Methylene Chloride ug/kg 49.450 99 69-136 n-Butylbenzene ug/kg 66.1 L05013265-128 n-Propylbenzene ug/kg 63.450 127 72-139 Naphthalene ug/kg 62.150 124 61-138 o-Xylene ug/kg 61.850 124 74-137 p-Isopropyltoluene ug/kg 63.950 128 66-128 sec-Butylbenzene ug/kg 63.650 127 72-140 Styrene ug/kg 55.650 111 76-137 tert-Butylbenzene ug/kg 60.350 121 68-141 Tetrachloroethene ug/kg 61.750 123 72-136 Toluene ug/kg 56.450 113 69-139 trans-1,2-Dichloroethene ug/kg 53.450 107 72-144 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 29 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329278LABORATORY CONTROL SAMPLE: LCSSpike trans-1,3-Dichloropropene ug/kg 59.450 119 73-135 Trichloroethene ug/kg 57.750 115 75-136 Trichlorofluoromethane ug/kg 48.050 96 69-144 Vinyl acetate ug/kg 187 L310018750-150 Vinyl chloride ug/kg 50.450 101 61-145 Xylene (Total)ug/kg 186150 124 73-138 1,2-Dichloroethane-d4 (S)%89 69-121 4-Bromofluorobenzene (S)%101 74-115 Dibromofluoromethane (S)%95 79-116 Toluene-d8 (S)%101 88-110 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 30 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: GCV/3448 MADEP VPH MADEP VPH VPH NC Soil Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:331562 Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Matrix:Solid Analyzed Aliphatic (C05-C08)mg/kg ND 10.0 09/04/09 01:43 Aliphatic (C09-C12)mg/kg ND 10.0 09/04/09 01:43 Aromatic (C09-C10)mg/kg ND 10.0 09/04/09 01:43 2,5-Dibromotoluene (FID)(S)%98 70-130 09/04/09 01:43 2,5-Dibromotoluene (PID)(S)%91 70-130 09/04/09 01:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 331563LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 331564 Aliphatic (C05-C08)mg/kg 16.215 108 70-13011316.9 4 25 Aliphatic (C09-C12)mg/kg 12.415 83 30-1309414.1 13 25 Aromatic (C09-C10)mg/kg ND5 103 70-130110ND 25 2,5-Dibromotoluene (FID)(S)%126 70-130116 2,5-Dibromotoluene (PID)(S)%111 70-130115 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 31 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: OEXT/7837 EPA 3546 EPA 8270 8270 Solid MSSV Microwave Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329183 Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Matrix:Solid Analyzed 1,2,4-Trichlorobenzene ug/kg ND 330 08/31/09 18:01 1,2-Dichlorobenzene ug/kg ND 330 08/31/09 18:01 1,2-Diphenylhydrazine ug/kg ND 330 08/31/09 18:01 1,3-Dichlorobenzene ug/kg ND 330 08/31/09 18:01 1,4-Dichlorobenzene ug/kg ND 330 08/31/09 18:01 2,4-Dinitrotoluene ug/kg ND 330 08/31/09 18:01 2,6-Dinitrotoluene ug/kg ND 330 08/31/09 18:01 2-Chloronaphthalene ug/kg ND 330 08/31/09 18:01 2-Methylnaphthalene ug/kg ND 330 08/31/09 18:01 2-Nitroaniline ug/kg ND 1650 08/31/09 18:01 3,3'-Dichlorobenzidine ug/kg ND 1650 08/31/09 18:01 3-Nitroaniline ug/kg ND 1650 08/31/09 18:01 4-Bromophenylphenyl ether ug/kg ND 330 08/31/09 18:01 4-Chloroaniline ug/kg ND 1650 08/31/09 18:01 4-Chlorophenylphenyl ether ug/kg ND 330 08/31/09 18:01 4-Nitroaniline ug/kg ND 660 08/31/09 18:01 Acenaphthene ug/kg ND 330 08/31/09 18:01 Acenaphthylene ug/kg ND 330 08/31/09 18:01 Anthracene ug/kg ND 330 08/31/09 18:01 Benzo(a)anthracene ug/kg ND 330 08/31/09 18:01 Benzo(a)pyrene ug/kg ND 330 08/31/09 18:01 Benzo(b)fluoranthene ug/kg ND 330 08/31/09 18:01 Benzo(g,h,i)perylene ug/kg ND 330 08/31/09 18:01 Benzo(k)fluoranthene ug/kg ND 330 08/31/09 18:01 Benzoic Acid ug/kg ND 1650 08/31/09 18:01 Benzyl alcohol ug/kg ND 660 08/31/09 18:01 bis(2-Chloroethoxy)methane ug/kg ND 330 08/31/09 18:01 bis(2-Chloroethyl) ether ug/kg ND 330 08/31/09 18:01 bis(2-Chloroisopropyl) ether ug/kg ND 330 08/31/09 18:01 bis(2-Ethylhexyl)phthalate ug/kg ND 330 08/31/09 18:01 Butylbenzylphthalate ug/kg ND 330 08/31/09 18:01 Chrysene ug/kg ND 330 08/31/09 18:01 Di-n-butylphthalate ug/kg ND 330 08/31/09 18:01 Di-n-octylphthalate ug/kg ND 330 08/31/09 18:01 Dibenz(a,h)anthracene ug/kg ND 330 08/31/09 18:01 Dibenzofuran ug/kg ND 330 08/31/09 18:01 Diethylphthalate ug/kg ND 330 08/31/09 18:01 Dimethylphthalate ug/kg ND 330 08/31/09 18:01 Fluoranthene ug/kg ND 330 08/31/09 18:01 Fluorene ug/kg ND 330 08/31/09 18:01 Hexachloro-1,3-butadiene ug/kg ND 330 08/31/09 18:01 Hexachlorobenzene ug/kg ND 330 08/31/09 18:01 Hexachlorocyclopentadiene ug/kg ND 330 08/31/09 18:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 32 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:329183 Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Matrix:Solid Analyzed Hexachloroethane ug/kg ND 330 08/31/09 18:01 Indeno(1,2,3-cd)pyrene ug/kg ND 330 08/31/09 18:01 Isophorone ug/kg ND 330 08/31/09 18:01 N-Nitroso-di-n-propylamine ug/kg ND 330 08/31/09 18:01 N-Nitrosodiphenylamine ug/kg ND 330 08/31/09 18:01 Naphthalene ug/kg ND 330 08/31/09 18:01 Nitrobenzene ug/kg ND 330 08/31/09 18:01 Phenanthrene ug/kg ND 330 08/31/09 18:01 Pyrene ug/kg ND 330 08/31/09 18:01 2,4,6-Tribromophenol (S)%50 44-136 08/31/09 18:01 2-Fluorobiphenyl (S)%53 46-120 08/31/09 18:01 2-Fluorophenol (S)%34 24-120 08/31/09 18:01 Nitrobenzene-d5 (S)%56 30-150 08/31/09 18:01 Phenol-d6 (S)%38 35-120 08/31/09 18:01 Terphenyl-d14 (S)%61 38-108 08/31/09 18:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329184LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/kg 9251670 55 50-150 1,2-Dichlorobenzene ug/kg 8771670 53 50-150 1,2-Diphenylhydrazine ug/kg 9951670 60 43-130 1,3-Dichlorobenzene ug/kg 8721670 52 50-150 1,4-Dichlorobenzene ug/kg 9561670 57 50-150 2,4-Dinitrotoluene ug/kg 10101670 60 50-150 2,6-Dinitrotoluene ug/kg 9781670 59 50-150 2-Chloronaphthalene ug/kg 9871670 59 50-150 2-Methylnaphthalene ug/kg 8351670 50 50-150 2-Nitroaniline ug/kg 956J1670 57 50-150 3,3'-Dichlorobenzidine ug/kg 899J1670 54 50-150 3-Nitroaniline ug/kg 911J1670 55 50-150 4-Bromophenylphenyl ether ug/kg 10701670 64 50-150 4-Chloroaniline ug/kg 1150J1670 69 50-150 4-Chlorophenylphenyl ether ug/kg 11201670 67 50-150 4-Nitroaniline ug/kg 9481670 57 50-150 Acenaphthene ug/kg 11001670 66 50-150 Acenaphthylene ug/kg 10901670 66 50-150 Anthracene ug/kg 11801670 71 50-150 Benzo(a)anthracene ug/kg 9641670 58 50-150 Benzo(a)pyrene ug/kg 10301670 62 50-150 Benzo(b)fluoranthene ug/kg 17201670 103 50-150 Benzo(g,h,i)perylene ug/kg 11801670 71 24-117 Benzo(k)fluoranthene ug/kg 17601670 106 50-150 Benzoic Acid ug/kg 407J1670 24 15-104 Benzyl alcohol ug/kg 10001670 60 50-150 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 33 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 329184LABORATORY CONTROL SAMPLE: LCSSpike bis(2-Chloroethoxy)methane ug/kg 9361670 56 50-150 bis(2-Chloroethyl) ether ug/kg 8641670 52 50-150 bis(2-Chloroisopropyl) ether ug/kg 10101670 60 50-150 bis(2-Ethylhexyl)phthalate ug/kg 12301670 74 50-150 Butylbenzylphthalate ug/kg 12701670 76 50-150 Chrysene ug/kg 10601670 64 50-150 Di-n-butylphthalate ug/kg 11301670 68 50-150 Di-n-octylphthalate ug/kg 12101670 72 50-150 Dibenz(a,h)anthracene ug/kg 12101670 73 17-128 Dibenzofuran ug/kg 10601670 63 50-150 Diethylphthalate ug/kg 11101670 66 50-150 Dimethylphthalate ug/kg 10801670 65 50-150 Fluoranthene ug/kg 9471670 57 50-150 Fluorene ug/kg 12001670 72 50-150 Hexachloro-1,3-butadiene ug/kg 9141670 55 50-150 Hexachlorobenzene ug/kg 9171670 55 50-150 Hexachlorocyclopentadiene ug/kg 8811670 53 15-114 Hexachloroethane ug/kg 9121670 55 50-150 Indeno(1,2,3-cd)pyrene ug/kg 12601670 75 19-128 Isophorone ug/kg 8871670 53 50-150 N-Nitroso-di-n-propylamine ug/kg 8631670 52 50-150 N-Nitrosodiphenylamine ug/kg 12301670 74 50-150 Naphthalene ug/kg 10101670 60 50-150 Nitrobenzene ug/kg 10201670 61 50-150 Phenanthrene ug/kg 11501670 69 50-150 Pyrene ug/kg 10501670 63 50-150 2,4,6-Tribromophenol (S)%54 44-136 2-Fluorobiphenyl (S)%59 46-120 2-Fluorophenol (S)%36 24-120 Nitrobenzene-d5 (S)%61 30-150 Phenol-d6 (S)%44 35-120 Terphenyl-d14 (S)%57 38-108 Parameter Units MS Result % Rec Limits Qual% RecConc. 329185MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 9251947001 329186 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/kg M020804350-15055 262080ND8841150 1,4-Dichlorobenzene ug/kg 2080 51 50-15052 02080ND10601070 2,4-Dinitrotoluene ug/kg 2080 55 50-15060 82080ND11401240 Acenaphthene ug/kg 2080 52 50-15051 22080ND10701050 N-Nitroso-di-n-propylamine ug/kg 2080 53 50-15053 12080ND11001100 Pyrene ug/kg 2080 50 50-15056 112080ND10401160 2,4,6-Tribromophenol (S)%1g4244-13636 2-Fluorobiphenyl (S)%56 46-12053 2-Fluorophenol (S)%33 24-12029 Nitrobenzene-d5 (S)%60 30-15054 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 34 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE Parameter Units MS Result % Rec Limits Qual% RecConc. 329185MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 9251947001 329186 MSD Result MSD % Rec RPD MSDMS Spike Conc. Phenol-d6 (S)%36 35-12044 Terphenyl-d14 (S)%71 38-10850 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 35 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9251947 THE PROVINCE QC Batch: QC Batch Method: Analysis Method: Analysis Description: OEXT/7856 MADEP EPH MADEP EPH MADEP EPH NC Soil Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:330073 Associated Lab Samples:9251947001, 9251947002, 9251947003, 9251947004 Matrix:Solid Analyzed Aliphatic (C09-C18)mg/kg ND 10.0 09/01/09 15:43 Aliphatic (C19-C36)mg/kg ND 10.0 09/01/09 15:43 Aromatic (C11-C22)mg/kg ND 10.0 09/01/09 15:43 2-Bromonaphthalene (S)%69 40-140 09/01/09 15:43 2-Fluorobiphenyl (S)%79 40-140 09/01/09 15:43 Nonatriacontane (S)%65 40-140 09/01/09 15:43 o-Terphenyl (S)%71 40-140 09/01/09 15:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 330074LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 330075 Aliphatic (C09-C18)mg/kg ND10 46 40-14068ND 50 Aliphatic (C19-C36)mg/kg ND13.3 60 40-1407510.0 50 Aromatic (C11-C22)mg/kg 22.228.3 78 40-1408824.9 11 50 2-Bromonaphthalene (S)%86 40-14093 2-Fluorobiphenyl (S)%90 40-14090 Nonatriacontane (S)%48 40-14070 o-Terphenyl (S)%74 40-14079 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 36 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Pace Project No.: Project: 9251947 THE PROVINCE DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. LABORATORIES Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Acid surrogate recovery outside of control limits. The data was accepted based on valid recovery of the 2 remaining acid surrogates.1g Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.L3 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0 Surrogate recovery outside laboratory control limits.S0 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.S3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 37 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 9251947 THE PROVINCE Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 9251947001 OEXT/7837 MSSV/3034B-4 10-12'EPA 3546 EPA 8270 9251947002 OEXT/7837 MSSV/3034B-4 20-22'EPA 3546 EPA 8270 9251947003 OEXT/7837 MSSV/3034B-3 8-10'EPA 3546 EPA 8270 9251947004 OEXT/7837 MSSV/3034B-3 18-20'EPA 3546 EPA 8270 9251947001 MSV/8117B-4 10-12'EPA 8260 9251947002 MSV/8117B-4 20-22'EPA 8260 9251947003 MSV/8119B-3 8-10'EPA 8260 9251947004 MSV/8119B-3 18-20'EPA 8260 9251947001 PMST/2678B-4 10-12'ASTM D2974-87 9251947002 PMST/2678B-4 20-22'ASTM D2974-87 9251947003 PMST/2678B-3 8-10'ASTM D2974-87 9251947004 PMST/2678B-3 18-20'ASTM D2974-87 9251947001 OEXT/7856 GCSV/6150B-4 10-12'MADEP EPH MADEP EPH 9251947002 OEXT/7856 GCSV/6150B-4 20-22'MADEP EPH MADEP EPH 9251947003 OEXT/7856 GCSV/6150B-3 8-10'MADEP EPH MADEP EPH 9251947004 OEXT/7856 GCSV/6150B-3 18-20'MADEP EPH MADEP EPH 9251947001 GCV/3448 GCV/3452B-4 10-12'MADEP VPH MADEP VPH 9251947002 GCV/3448 GCV/3452B-4 20-22'MADEP VPH MADEP VPH 9251947003 GCV/3448 GCV/3452B-3 8-10'MADEP VPH MADEP VPH 9251947004 GCV/3448 GCV/3452B-3 18-20'MADEP VPH MADEP VPH REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/09/2009 03:00 PM Page 38 of 38 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 September 14, 2009 LIMS USE: FR - STEPHEN BROWN LIMS OBJECT ID: 9252195 9252195 Project: Pace Project No.: RE: Mr. Stephen Brown Terracon 2020 E Starita Road Charlotte, NC 28206 THE PROVINCE 71097746 Dear Mr. Brown: Enclosed are the analytical results for sample(s) received by the laboratory on September 02, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Brandon Helton for Kevin Herring kevin.herring@pacelabs.com Project Manager Enclosures cc:Mr. Chris Corbitt, Terracon REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Charlotte Certification IDsConnecticut Certification #: PH-0104Florida/NELAP Certification #: E87627 West Virginia Certification #: 357Virginia Certification #: 00213Tennessee Certification #: 04010South Carolina Drinking Water Cert. #: 990060003South Carolina Certification #: 990060001 Pennsylvania Certification #: 68-00784North Carolina Wastewater Certification #: 12 North Carolina Field Services Certification #: 5342North Carolina Drinking Water Certification #: 37706New Jersey Certification #: NC012Louisiana/LELAP Certification #: 04034Kentucky UST Certification #: 84 Asheville Certification IDs Connecticut Certification #: PH-0106 Virginia Certification #: 00072Tennessee Certification #: 2980South Carolina Certification #: 99030001 South Carolina Bioassay Certification #: 99030002Pennsylvania Certification #: 68-03578 West Virginia Certification #: 356 North Carolina Drinking Water Certification #: 37712 North Carolina Bioassay Certification #: 9New Jersey Certification #: NC011Massachusetts Certification #: M-NC030 Louisiana/LELAP Certification #: 03095Florida/NELAP Certification #: E87648 North Carolina Wastewater Certification #: 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 9252195001 MW-3 EPA 200.7 1 PASI-ASHB EPA 8260 63 PASI-CAW EPA 8270 75 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW 9252195002 MW-4 EPA 200.7 1 PASI-ASHB EPA 8260 63 PASI-CAW EPA 8270 75 PASI-CBET MADEP EPH 7 PASI-CJAC MADEP VPH 5 PASI-CDHW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-3 Lab ID:9252195001 Collected:09/01/09 15:20 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)ND ug/L 1 09/11/09 11:0309/09/09 14:59119 Aliphatic (C19-C36)ND ug/L 1 09/11/09 11:0309/09/09 14:59119 Aromatic (C11-C22)ND ug/L 1 09/11/09 11:0309/09/09 14:59119 Nonatriacontane (S)97 %1 09/11/09 11:03 7194-86-709/09/09 14:5940-140 o-Terphenyl (S)90 %1 09/11/09 11:03 84-15-109/09/09 14:5940-140 2-Fluorobiphenyl (S)93 %1 09/11/09 11:03 321-60-809/09/09 14:5940-140 2-Bromonaphthalene (S)96 %1 09/11/09 11:03 580-13-209/09/09 14:5940-140 VPH NC Water Analytical Method: MADEP VPH Aliphatic (C05-C08)962 ug/L 1 09/10/09 00:49100 Aliphatic (C09-C12)2310 ug/L 1 09/10/09 00:49100 Aromatic (C09-C10)310 ug/L 1 09/10/09 00:49100 2,5-Dibromotoluene (PID)(S)95 %1 09/10/09 00:4970-130 2,5-Dibromotoluene (FID)(S)102 %1 09/10/09 00:4970-130 200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C Lead 24.2 ug/L 1 09/04/09 17:59 7439-92-109/03/09 10:405.0 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 Acenaphthene ND ug/L 1 09/10/09 23:16 83-32-909/08/09 09:3011.1 Acenaphthylene ND ug/L 1 09/10/09 23:16 208-96-809/08/09 09:3011.1 Aniline ND ug/L 1 09/10/09 23:16 62-53-309/08/09 09:3011.1 Anthracene ND ug/L 1 09/10/09 23:16 120-12-709/08/09 09:3011.1 Benzo(a)anthracene ND ug/L 1 09/10/09 23:16 56-55-309/08/09 09:3011.1 Benzo(a)pyrene ND ug/L 1 09/10/09 23:16 50-32-809/08/09 09:3011.1 Benzo(b)fluoranthene ND ug/L 1 09/10/09 23:16 205-99-209/08/09 09:3011.1 Benzo(g,h,i)perylene ND ug/L 1 09/10/09 23:16 191-24-209/08/09 09:3011.1 Benzo(k)fluoranthene ND ug/L 1 09/10/09 23:16 207-08-909/08/09 09:3011.1 Benzoic Acid ND ug/L 1 09/10/09 23:16 65-85-009/08/09 09:3055.6 Benzyl alcohol ND ug/L 1 09/10/09 23:16 100-51-609/08/09 09:3022.2 4-Bromophenylphenyl ether ND ug/L 1 09/10/09 23:16 101-55-309/08/09 09:3011.1 Butylbenzylphthalate ND ug/L 1 09/10/09 23:16 85-68-709/08/09 09:3011.1 4-Chloro-3-methylphenol ND ug/L 1 09/10/09 23:16 59-50-709/08/09 09:3022.2 4-Chloroaniline ND ug/L 1 09/10/09 23:16 106-47-809/08/09 09:3055.6 bis(2-Chloroethoxy)methane ND ug/L 1 09/10/09 23:16 111-91-109/08/09 09:3011.1 bis(2-Chloroethyl) ether ND ug/L 1 09/10/09 23:16 111-44-409/08/09 09:3011.1 bis(2-Chloroisopropyl) ether ND ug/L 1 09/10/09 23:16 108-60-109/08/09 09:3011.1 2-Chloronaphthalene ND ug/L 1 09/10/09 23:16 91-58-709/08/09 09:3011.1 2-Chlorophenol ND ug/L 1 09/10/09 23:16 95-57-809/08/09 09:3011.1 4-Chlorophenylphenyl ether ND ug/L 1 09/10/09 23:16 7005-72-309/08/09 09:3011.1 Chrysene ND ug/L 1 09/10/09 23:16 218-01-909/08/09 09:3011.1 Dibenz(a,h)anthracene ND ug/L 1 09/10/09 23:16 53-70-309/08/09 09:3011.1 Dibenzofuran ND ug/L 1 09/10/09 23:16 132-64-909/08/09 09:3011.1 1,2-Dichlorobenzene ND ug/L 1 09/10/09 23:16 95-50-109/08/09 09:3011.1 1,3-Dichlorobenzene ND ug/L 1 09/10/09 23:16 541-73-109/08/09 09:3011.1 1,4-Dichlorobenzene ND ug/L 1 09/10/09 23:16 106-46-709/08/09 09:3011.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 4 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-3 Lab ID:9252195001 Collected:09/01/09 15:20 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 3,3'-Dichlorobenzidine ND ug/L 1 09/10/09 23:16 91-94-109/08/09 09:3055.6 2,4-Dichlorophenol ND ug/L 1 09/10/09 23:16 120-83-209/08/09 09:3011.1 Diethylphthalate ND ug/L 1 09/10/09 23:16 84-66-209/08/09 09:3011.1 2,4-Dimethylphenol ND ug/L 1 09/10/09 23:16 105-67-909/08/09 09:3011.1 Dimethylphthalate ND ug/L 1 09/10/09 23:16 131-11-309/08/09 09:3011.1 Di-n-butylphthalate ND ug/L 1 09/10/09 23:16 84-74-209/08/09 09:3011.1 4,6-Dinitro-2-methylphenol ND ug/L 1 09/10/09 23:16 534-52-109/08/09 09:3022.2 2,4-Dinitrophenol ND ug/L 1 09/10/09 23:16 51-28-509/08/09 09:3055.6 2,4-Dinitrotoluene ND ug/L 1 09/10/09 23:16 121-14-209/08/09 09:3011.1 2,6-Dinitrotoluene ND ug/L 1 09/10/09 23:16 606-20-209/08/09 09:3011.1 Di-n-octylphthalate ND ug/L 1 09/10/09 23:16 117-84-009/08/09 09:3011.1 1,2-Diphenylhydrazine ND ug/L 1 09/10/09 23:16 122-66-709/08/09 09:3011.1 bis(2-Ethylhexyl)phthalate ND ug/L 1 09/10/09 23:16 117-81-709/08/09 09:3011.1 Fluoranthene ND ug/L 1 09/10/09 23:16 206-44-009/08/09 09:3011.1 Fluorene ND ug/L 1 09/10/09 23:16 86-73-709/08/09 09:3011.1 Hexachloro-1,3-butadiene ND ug/L 1 09/10/09 23:16 87-68-309/08/09 09:3011.1 Hexachlorobenzene ND ug/L 1 09/10/09 23:16 118-74-109/08/09 09:3011.1 Hexachlorocyclopentadiene ND ug/L 1 09/10/09 23:16 77-47-409/08/09 09:3011.1 Hexachloroethane ND ug/L 1 09/10/09 23:16 67-72-109/08/09 09:3011.1 Indeno(1,2,3-cd)pyrene ND ug/L 1 09/10/09 23:16 193-39-509/08/09 09:3011.1 Isophorone ND ug/L 1 09/10/09 23:16 78-59-109/08/09 09:3011.1 1-Methylnaphthalene ND ug/L 1 09/10/09 23:16 90-12-009/08/09 09:3011.1 2-Methylnaphthalene ND ug/L 1 09/10/09 23:16 91-57-609/08/09 09:3011.1 2-Methylphenol(o-Cresol)ND ug/L 1 09/10/09 23:16 95-48-709/08/09 09:3011.1 3&4-Methylphenol(m&p Cresol)ND ug/L 1 09/10/09 23:1609/08/09 09:3011.1 Naphthalene ND ug/L 1 09/10/09 23:16 91-20-309/08/09 09:3011.1 2-Nitroaniline ND ug/L 1 09/10/09 23:16 88-74-409/08/09 09:3055.6 3-Nitroaniline ND ug/L 1 09/10/09 23:16 99-09-209/08/09 09:3055.6 4-Nitroaniline ND ug/L 1 09/10/09 23:16 100-01-609/08/09 09:3055.6 Nitrobenzene ND ug/L 1 09/10/09 23:16 98-95-309/08/09 09:3011.1 2-Nitrophenol ND ug/L 1 09/10/09 23:16 88-75-509/08/09 09:3011.1 4-Nitrophenol ND ug/L 1 09/10/09 23:16 100-02-709/08/09 09:3055.6 N-Nitrosodimethylamine ND ug/L 1 09/10/09 23:16 62-75-909/08/09 09:3011.1 N-Nitroso-di-n-propylamine ND ug/L 1 09/10/09 23:16 621-64-709/08/09 09:3011.1 N-Nitrosodiphenylamine ND ug/L 1 09/10/09 23:16 86-30-609/08/09 09:3011.1 Pentachlorophenol ND ug/L 1 09/10/09 23:16 87-86-509/08/09 09:3055.6 Phenanthrene ND ug/L 1 09/10/09 23:16 85-01-809/08/09 09:3011.1 Phenol ND ug/L 1 09/10/09 23:16 108-95-209/08/09 09:3011.1 Pyrene ND ug/L 1 09/10/09 23:16 129-00-009/08/09 09:3011.1 1,2,4-Trichlorobenzene ND ug/L 1 09/10/09 23:16 120-82-109/08/09 09:3011.1 2,4,5-Trichlorophenol ND ug/L 1 09/10/09 23:16 95-95-409/08/09 09:3011.1 2,4,6-Trichlorophenol ND ug/L 1 09/10/09 23:16 88-06-209/08/09 09:3011.1 Nitrobenzene-d5 (S)60 %1 09/10/09 23:16 4165-60-009/08/09 09:3030-150 2-Fluorobiphenyl (S)61 %1 09/10/09 23:16 321-60-809/08/09 09:3030-150 Terphenyl-d14 (S)64 %1 09/10/09 23:16 1718-51-009/08/09 09:3030-150 Phenol-d6 (S)26 %1 09/10/09 23:16 13127-88-309/08/09 09:3025-150 2-Fluorophenol (S)36 %1 09/10/09 23:16 367-12-409/08/09 09:3025-150 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 5 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-3 Lab ID:9252195001 Collected:09/01/09 15:20 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 2,4,6-Tribromophenol (S)66 %1 09/10/09 23:16 118-79-609/08/09 09:3025-150 8260 MSV Low Level Analytical Method: EPA 8260 Acetone 43.3 ug/L 1 09/09/09 08:56 67-64-125.0 Benzene 83.1 ug/L 1 09/09/09 08:56 71-43-21.0 Bromobenzene ND ug/L 1 09/09/09 08:56 108-86-11.0 Bromochloromethane ND ug/L 1 09/09/09 08:56 74-97-51.0 Bromodichloromethane ND ug/L 1 09/09/09 08:56 75-27-41.0 Bromoform ND ug/L 1 09/09/09 08:56 75-25-21.0 Bromomethane ND ug/L 1 09/09/09 08:56 74-83-95.0 2-Butanone (MEK)ND ug/L 1 09/09/09 08:56 78-93-35.0 Carbon tetrachloride ND ug/L 1 09/09/09 08:56 56-23-51.0 Chlorobenzene ND ug/L 1 09/09/09 08:56 108-90-71.0 Chloroethane ND ug/L 1 09/09/09 08:56 75-00-31.0 Chloroform 1.8 ug/L 1 09/09/09 08:56 67-66-31.0 Chloromethane ND ug/L 1 09/09/09 08:56 74-87-31.0 2-Chlorotoluene ND ug/L 1 09/09/09 08:56 95-49-81.0 4-Chlorotoluene ND ug/L 1 09/09/09 08:56 106-43-41.0 1,2-Dibromo-3-chloropropane ND ug/L 1 09/09/09 08:56 96-12-83.0 Dibromochloromethane ND ug/L 1 09/09/09 08:56 124-48-11.0 1,2-Dibromoethane (EDB)ND ug/L 1 09/09/09 08:56 106-93-41.0 Dibromomethane ND ug/L 1 09/09/09 08:56 74-95-31.0 1,2-Dichlorobenzene ND ug/L 1 09/09/09 08:56 95-50-11.0 1,3-Dichlorobenzene ND ug/L 1 09/09/09 08:56 541-73-11.0 1,4-Dichlorobenzene ND ug/L 1 09/09/09 08:56 106-46-71.0 Dichlorodifluoromethane ND ug/L 1 09/09/09 08:56 75-71-81.0 1,1-Dichloroethane ND ug/L 1 09/09/09 08:56 75-34-31.0 1,2-Dichloroethane 7.2 ug/L 1 09/09/09 08:56 107-06-21.0 1,1-Dichloroethene ND ug/L 1 09/09/09 08:56 75-35-41.0 cis-1,2-Dichloroethene 1.2 ug/L 1 09/09/09 08:56 156-59-21.0 trans-1,2-Dichloroethene ND ug/L 1 09/09/09 08:56 156-60-51.0 1,2-Dichloropropane ND ug/L 1 09/09/09 08:56 78-87-51.0 1,3-Dichloropropane ND ug/L 1 09/09/09 08:56 142-28-91.0 2,2-Dichloropropane ND ug/L 1 09/09/09 08:56 594-20-71.0 1,1-Dichloropropene ND ug/L 1 09/09/09 08:56 563-58-61.0 cis-1,3-Dichloropropene ND ug/L 1 09/09/09 08:56 10061-01-51.0 trans-1,3-Dichloropropene ND ug/L 1 09/09/09 08:56 10061-02-61.0 Diisopropyl ether 9.4 ug/L 1 09/09/09 08:56 108-20-31.0 Ethylbenzene 156 ug/L 1 09/09/09 08:56 100-41-41.0 Hexachloro-1,3-butadiene ND ug/L 1 09/09/09 08:56 87-68-31.0 2-Hexanone ND ug/L 1 09/09/09 08:56 591-78-65.0 p-Isopropyltoluene ND ug/L 1 09/09/09 08:56 99-87-61.0 Methylene Chloride ND ug/L 1 09/09/09 08:56 75-09-22.0 4-Methyl-2-pentanone (MIBK)ND ug/L 1 09/09/09 08:56 108-10-15.0 Methyl-tert-butyl ether 10 ug/L 1 09/09/09 08:56 1634-04-41.0 Naphthalene 13.0 ug/L 1 09/09/09 08:56 91-20-31.0 Styrene ND ug/L 1 09/09/09 08:56 100-42-51.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 6 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-3 Lab ID:9252195001 Collected:09/01/09 15:20 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260 MSV Low Level Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane ND ug/L 1 09/09/09 08:56 630-20-61.0 1,1,2,2-Tetrachloroethane ND ug/L 1 09/09/09 08:56 79-34-51.0 Tetrachloroethene 2.0 ug/L 1 09/09/09 08:56 127-18-41.0 Toluene 125 ug/L 1 09/09/09 08:56 108-88-31.0 1,2,3-Trichlorobenzene ND ug/L 1 09/09/09 08:56 87-61-61.0 1,2,4-Trichlorobenzene ND ug/L 1 09/09/09 08:56 120-82-11.0 1,1,1-Trichloroethane ND ug/L 1 09/09/09 08:56 71-55-61.0 1,1,2-Trichloroethane ND ug/L 1 09/09/09 08:56 79-00-51.0 Trichloroethene ND ug/L 1 09/09/09 08:56 79-01-61.0 Trichlorofluoromethane ND ug/L 1 09/09/09 08:56 75-69-41.0 1,2,3-Trichloropropane ND ug/L 1 09/09/09 08:56 96-18-41.0 Vinyl acetate ND ug/L 1 09/09/09 08:56 108-05-42.0 Vinyl chloride ND ug/L 1 09/09/09 08:56 75-01-41.0 m&p-Xylene 272 ug/L 1 09/09/09 08:56 1330-20-72.0 o-Xylene 129 ug/L 1 09/09/09 08:56 95-47-61.0 4-Bromofluorobenzene (S)105 %1 09/09/09 08:56 460-00-487-109 Dibromofluoromethane (S)102 %1 09/09/09 08:56 1868-53-785-115 1,2-Dichloroethane-d4 (S)110 %1 09/09/09 08:56 17060-07-079-120 Toluene-d8 (S)97 %1 09/09/09 08:56 2037-26-570-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 7 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-4 Lab ID:9252195002 Collected:09/01/09 14:10 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18)ND ug/L 1 09/11/09 11:3609/09/09 14:59118 Aliphatic (C19-C36)ND ug/L 1 09/11/09 11:3609/09/09 14:59118 Aromatic (C11-C22)ND ug/L 1 09/11/09 11:3609/09/09 14:59118 Nonatriacontane (S)93 %1 09/11/09 11:36 7194-86-709/09/09 14:5940-140 o-Terphenyl (S)105 %1 09/11/09 11:36 84-15-109/09/09 14:5940-140 2-Fluorobiphenyl (S)108 %1 09/11/09 11:36 321-60-809/09/09 14:5940-140 2-Bromonaphthalene (S)113 %1 09/11/09 11:36 580-13-209/09/09 14:5940-140 VPH NC Water Analytical Method: MADEP VPH Aliphatic (C05-C08)ND ug/L 1 09/10/09 01:13100 Aliphatic (C09-C12)ND ug/L 1 09/10/09 01:13100 Aromatic (C09-C10)ND ug/L 1 09/10/09 01:13100 2,5-Dibromotoluene (PID)(S)95 %1 09/10/09 01:1370-130 2,5-Dibromotoluene (FID)(S)102 %1 09/10/09 01:1370-130 200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C Lead 5.5 ug/L 1 09/04/09 18:11 7439-92-109/03/09 10:405.0 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 Acenaphthene ND ug/L 1 09/10/09 23:38 83-32-909/08/09 09:3010.6 Acenaphthylene ND ug/L 1 09/10/09 23:38 208-96-809/08/09 09:3010.6 Aniline ND ug/L 1 09/10/09 23:38 62-53-309/08/09 09:3010.6 Anthracene ND ug/L 1 09/10/09 23:38 120-12-709/08/09 09:3010.6 Benzo(a)anthracene ND ug/L 1 09/10/09 23:38 56-55-309/08/09 09:3010.6 Benzo(a)pyrene ND ug/L 1 09/10/09 23:38 50-32-809/08/09 09:3010.6 Benzo(b)fluoranthene ND ug/L 1 09/10/09 23:38 205-99-209/08/09 09:3010.6 Benzo(g,h,i)perylene ND ug/L 1 09/10/09 23:38 191-24-209/08/09 09:3010.6 Benzo(k)fluoranthene ND ug/L 1 09/10/09 23:38 207-08-909/08/09 09:3010.6 Benzoic Acid ND ug/L 1 09/10/09 23:38 65-85-009/08/09 09:3053.2 Benzyl alcohol ND ug/L 1 09/10/09 23:38 100-51-609/08/09 09:3021.3 4-Bromophenylphenyl ether ND ug/L 1 09/10/09 23:38 101-55-309/08/09 09:3010.6 Butylbenzylphthalate ND ug/L 1 09/10/09 23:38 85-68-709/08/09 09:3010.6 4-Chloro-3-methylphenol ND ug/L 1 09/10/09 23:38 59-50-709/08/09 09:3021.3 4-Chloroaniline ND ug/L 1 09/10/09 23:38 106-47-809/08/09 09:3053.2 bis(2-Chloroethoxy)methane ND ug/L 1 09/10/09 23:38 111-91-109/08/09 09:3010.6 bis(2-Chloroethyl) ether ND ug/L 1 09/10/09 23:38 111-44-409/08/09 09:3010.6 bis(2-Chloroisopropyl) ether ND ug/L 1 09/10/09 23:38 108-60-109/08/09 09:3010.6 2-Chloronaphthalene ND ug/L 1 09/10/09 23:38 91-58-709/08/09 09:3010.6 2-Chlorophenol ND ug/L 1 09/10/09 23:38 95-57-809/08/09 09:3010.6 4-Chlorophenylphenyl ether ND ug/L 1 09/10/09 23:38 7005-72-309/08/09 09:3010.6 Chrysene ND ug/L 1 09/10/09 23:38 218-01-909/08/09 09:3010.6 Dibenz(a,h)anthracene ND ug/L 1 09/10/09 23:38 53-70-309/08/09 09:3010.6 Dibenzofuran ND ug/L 1 09/10/09 23:38 132-64-909/08/09 09:3010.6 1,2-Dichlorobenzene ND ug/L 1 09/10/09 23:38 95-50-109/08/09 09:3010.6 1,3-Dichlorobenzene ND ug/L 1 09/10/09 23:38 541-73-109/08/09 09:3010.6 1,4-Dichlorobenzene ND ug/L 1 09/10/09 23:38 106-46-709/08/09 09:3010.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 8 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-4 Lab ID:9252195002 Collected:09/01/09 14:10 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 3,3'-Dichlorobenzidine ND ug/L 1 09/10/09 23:38 91-94-109/08/09 09:3053.2 2,4-Dichlorophenol ND ug/L 1 09/10/09 23:38 120-83-209/08/09 09:3010.6 Diethylphthalate ND ug/L 1 09/10/09 23:38 84-66-209/08/09 09:3010.6 2,4-Dimethylphenol ND ug/L 1 09/10/09 23:38 105-67-909/08/09 09:3010.6 Dimethylphthalate ND ug/L 1 09/10/09 23:38 131-11-309/08/09 09:3010.6 Di-n-butylphthalate ND ug/L 1 09/10/09 23:38 84-74-209/08/09 09:3010.6 4,6-Dinitro-2-methylphenol ND ug/L 1 09/10/09 23:38 534-52-109/08/09 09:3021.3 2,4-Dinitrophenol ND ug/L 1 09/10/09 23:38 51-28-509/08/09 09:3053.2 2,4-Dinitrotoluene ND ug/L 1 09/10/09 23:38 121-14-209/08/09 09:3010.6 2,6-Dinitrotoluene ND ug/L 1 09/10/09 23:38 606-20-209/08/09 09:3010.6 Di-n-octylphthalate ND ug/L 1 09/10/09 23:38 117-84-009/08/09 09:3010.6 1,2-Diphenylhydrazine ND ug/L 1 09/10/09 23:38 122-66-709/08/09 09:3010.6 bis(2-Ethylhexyl)phthalate ND ug/L 1 09/10/09 23:38 117-81-709/08/09 09:3010.6 Fluoranthene ND ug/L 1 09/10/09 23:38 206-44-009/08/09 09:3010.6 Fluorene ND ug/L 1 09/10/09 23:38 86-73-709/08/09 09:3010.6 Hexachloro-1,3-butadiene ND ug/L 1 09/10/09 23:38 87-68-309/08/09 09:3010.6 Hexachlorobenzene ND ug/L 1 09/10/09 23:38 118-74-109/08/09 09:3010.6 Hexachlorocyclopentadiene ND ug/L 1 09/10/09 23:38 77-47-409/08/09 09:3010.6 Hexachloroethane ND ug/L 1 09/10/09 23:38 67-72-109/08/09 09:3010.6 Indeno(1,2,3-cd)pyrene ND ug/L 1 09/10/09 23:38 193-39-509/08/09 09:3010.6 Isophorone ND ug/L 1 09/10/09 23:38 78-59-109/08/09 09:3010.6 1-Methylnaphthalene ND ug/L 1 09/10/09 23:38 90-12-009/08/09 09:3010.6 2-Methylnaphthalene ND ug/L 1 09/10/09 23:38 91-57-609/08/09 09:3010.6 2-Methylphenol(o-Cresol)ND ug/L 1 09/10/09 23:38 95-48-709/08/09 09:3010.6 3&4-Methylphenol(m&p Cresol)ND ug/L 1 09/10/09 23:3809/08/09 09:3010.6 Naphthalene ND ug/L 1 09/10/09 23:38 91-20-309/08/09 09:3010.6 2-Nitroaniline ND ug/L 1 09/10/09 23:38 88-74-409/08/09 09:3053.2 3-Nitroaniline ND ug/L 1 09/10/09 23:38 99-09-209/08/09 09:3053.2 4-Nitroaniline ND ug/L 1 09/10/09 23:38 100-01-609/08/09 09:3053.2 Nitrobenzene ND ug/L 1 09/10/09 23:38 98-95-309/08/09 09:3010.6 2-Nitrophenol ND ug/L 1 09/10/09 23:38 88-75-509/08/09 09:3010.6 4-Nitrophenol ND ug/L 1 09/10/09 23:38 100-02-709/08/09 09:3053.2 N-Nitrosodimethylamine ND ug/L 1 09/10/09 23:38 62-75-909/08/09 09:3010.6 N-Nitroso-di-n-propylamine ND ug/L 1 09/10/09 23:38 621-64-709/08/09 09:3010.6 N-Nitrosodiphenylamine ND ug/L 1 09/10/09 23:38 86-30-609/08/09 09:3010.6 Pentachlorophenol ND ug/L 1 09/10/09 23:38 87-86-509/08/09 09:3053.2 Phenanthrene ND ug/L 1 09/10/09 23:38 85-01-809/08/09 09:3010.6 Phenol ND ug/L 1 09/10/09 23:38 108-95-209/08/09 09:3010.6 Pyrene ND ug/L 1 09/10/09 23:38 129-00-009/08/09 09:3010.6 1,2,4-Trichlorobenzene ND ug/L 1 09/10/09 23:38 120-82-109/08/09 09:3010.6 2,4,5-Trichlorophenol ND ug/L 1 09/10/09 23:38 95-95-409/08/09 09:3010.6 2,4,6-Trichlorophenol ND ug/L 1 09/10/09 23:38 88-06-209/08/09 09:3010.6 Nitrobenzene-d5 (S)50 %1 09/10/09 23:38 4165-60-009/08/09 09:3030-150 2-Fluorobiphenyl (S)61 %1 09/10/09 23:38 321-60-809/08/09 09:3030-150 Terphenyl-d14 (S)80 %1 09/10/09 23:38 1718-51-009/08/09 09:3030-150 Phenol-d6 (S)31 %1 09/10/09 23:38 13127-88-309/08/09 09:3025-150 2-Fluorophenol (S)29 %1 09/10/09 23:38 367-12-409/08/09 09:3025-150 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 9 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-4 Lab ID:9252195002 Collected:09/01/09 14:10 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8270 MSSV Semivolatile Organic Analytical Method: EPA 8270 Preparation Method: EPA 3510 2,4,6-Tribromophenol (S)64 %1 09/10/09 23:38 118-79-609/08/09 09:3025-150 8260 MSV Low Level Analytical Method: EPA 8260 Acetone ND ug/L 1 09/09/09 09:20 67-64-125.0 Benzene ND ug/L 1 09/09/09 09:20 71-43-21.0 Bromobenzene ND ug/L 1 09/09/09 09:20 108-86-11.0 Bromochloromethane ND ug/L 1 09/09/09 09:20 74-97-51.0 Bromodichloromethane ND ug/L 1 09/09/09 09:20 75-27-41.0 Bromoform ND ug/L 1 09/09/09 09:20 75-25-21.0 Bromomethane ND ug/L 1 09/09/09 09:20 74-83-95.0 2-Butanone (MEK)ND ug/L 1 09/09/09 09:20 78-93-35.0 Carbon tetrachloride 1.2 ug/L 1 09/09/09 09:20 56-23-51.0 Chlorobenzene ND ug/L 1 09/09/09 09:20 108-90-71.0 Chloroethane ND ug/L 1 09/09/09 09:20 75-00-31.0 Chloroform ND ug/L 1 09/09/09 09:20 67-66-31.0 Chloromethane ND ug/L 1 09/09/09 09:20 74-87-31.0 2-Chlorotoluene ND ug/L 1 09/09/09 09:20 95-49-81.0 4-Chlorotoluene ND ug/L 1 09/09/09 09:20 106-43-41.0 1,2-Dibromo-3-chloropropane ND ug/L 1 09/09/09 09:20 96-12-83.0 Dibromochloromethane ND ug/L 1 09/09/09 09:20 124-48-11.0 1,2-Dibromoethane (EDB)ND ug/L 1 09/09/09 09:20 106-93-41.0 Dibromomethane ND ug/L 1 09/09/09 09:20 74-95-31.0 1,2-Dichlorobenzene ND ug/L 1 09/09/09 09:20 95-50-11.0 1,3-Dichlorobenzene ND ug/L 1 09/09/09 09:20 541-73-11.0 1,4-Dichlorobenzene ND ug/L 1 09/09/09 09:20 106-46-71.0 Dichlorodifluoromethane ND ug/L 1 09/09/09 09:20 75-71-81.0 1,1-Dichloroethane ND ug/L 1 09/09/09 09:20 75-34-31.0 1,2-Dichloroethane ND ug/L 1 09/09/09 09:20 107-06-21.0 1,1-Dichloroethene ND ug/L 1 09/09/09 09:20 75-35-41.0 cis-1,2-Dichloroethene ND ug/L 1 09/09/09 09:20 156-59-21.0 trans-1,2-Dichloroethene ND ug/L 1 09/09/09 09:20 156-60-51.0 1,2-Dichloropropane ND ug/L 1 09/09/09 09:20 78-87-51.0 1,3-Dichloropropane ND ug/L 1 09/09/09 09:20 142-28-91.0 2,2-Dichloropropane ND ug/L 1 09/09/09 09:20 594-20-71.0 1,1-Dichloropropene ND ug/L 1 09/09/09 09:20 563-58-61.0 cis-1,3-Dichloropropene ND ug/L 1 09/09/09 09:20 10061-01-51.0 trans-1,3-Dichloropropene ND ug/L 1 09/09/09 09:20 10061-02-61.0 Diisopropyl ether ND ug/L 1 09/09/09 09:20 108-20-31.0 Ethylbenzene ND ug/L 1 09/09/09 09:20 100-41-41.0 Hexachloro-1,3-butadiene ND ug/L 1 09/09/09 09:20 87-68-31.0 2-Hexanone ND ug/L 1 09/09/09 09:20 591-78-65.0 p-Isopropyltoluene ND ug/L 1 09/09/09 09:20 99-87-61.0 Methylene Chloride ND ug/L 1 09/09/09 09:20 75-09-22.0 4-Methyl-2-pentanone (MIBK)ND ug/L 1 09/09/09 09:20 108-10-15.0 Methyl-tert-butyl ether 1.6 ug/L 1 09/09/09 09:20 1634-04-41.0 Naphthalene ND ug/L 1 09/09/09 09:20 91-20-31.0 Styrene ND ug/L 1 09/09/09 09:20 100-42-51.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 10 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Sample:MW-4 Lab ID:9252195002 Collected:09/01/09 14:10 Received:09/02/09 08:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit 8260 MSV Low Level Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane ND ug/L 1 09/09/09 09:20 630-20-61.0 1,1,2,2-Tetrachloroethane ND ug/L 1 09/09/09 09:20 79-34-51.0 Tetrachloroethene ND ug/L 1 09/09/09 09:20 127-18-41.0 Toluene ND ug/L 1 09/09/09 09:20 108-88-31.0 1,2,3-Trichlorobenzene ND ug/L 1 09/09/09 09:20 87-61-61.0 1,2,4-Trichlorobenzene ND ug/L 1 09/09/09 09:20 120-82-11.0 1,1,1-Trichloroethane ND ug/L 1 09/09/09 09:20 71-55-61.0 1,1,2-Trichloroethane ND ug/L 1 09/09/09 09:20 79-00-51.0 Trichloroethene ND ug/L 1 09/09/09 09:20 79-01-61.0 Trichlorofluoromethane ND ug/L 1 09/09/09 09:20 75-69-41.0 1,2,3-Trichloropropane ND ug/L 1 09/09/09 09:20 96-18-41.0 Vinyl acetate ND ug/L 1 09/09/09 09:20 108-05-42.0 Vinyl chloride ND ug/L 1 09/09/09 09:20 75-01-41.0 m&p-Xylene ND ug/L 1 09/09/09 09:20 1330-20-72.0 o-Xylene ND ug/L 1 09/09/09 09:20 95-47-61.0 4-Bromofluorobenzene (S)101 %1 09/09/09 09:20 460-00-487-109 Dibromofluoromethane (S)99 %1 09/09/09 09:20 1868-53-785-115 1,2-Dichloroethane-d4 (S)108 %1 09/09/09 09:20 17060-07-079-120 Toluene-d8 (S)97 %1 09/09/09 09:20 2037-26-570-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 11 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 QC Batch: QC Batch Method: Analysis Method: Analysis Description: GCV/3459 MADEP VPH MADEP VPH VPH NC Water Associated Lab Samples:9252195001, 9252195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:333938 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed Aliphatic (C05-C08)ug/L ND 100 09/09/09 19:14 Aliphatic (C09-C12)ug/L ND 100 09/09/09 19:14 Aromatic (C09-C10)ug/L ND 100 09/09/09 19:14 2,5-Dibromotoluene (FID)(S)%100 70-130 09/09/09 19:14 2,5-Dibromotoluene (PID)(S)%102 70-130 09/09/09 19:14 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 333939LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 333940 Aliphatic (C05-C08)ug/L 312300 104 70-130102305 2 25 Aliphatic (C09-C12)ug/L 272300 91 30-13095286 5 25 Aromatic (C09-C10)ug/L 102100 102 70-130104104 2 25 2,5-Dibromotoluene (FID)(S)%119 70-130122 2,5-Dibromotoluene (PID)(S)%119 70-130124 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 12 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/8192 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:9252195001, 9252195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:332161 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 09/09/09 00:31 1,1,1-Trichloroethane ug/L ND 1.0 09/09/09 00:31 1,1,2,2-Tetrachloroethane ug/L ND 1.0 09/09/09 00:31 1,1,2-Trichloroethane ug/L ND 1.0 09/09/09 00:31 1,1-Dichloroethane ug/L ND 1.0 09/09/09 00:31 1,1-Dichloroethene ug/L ND 1.0 09/09/09 00:31 1,1-Dichloropropene ug/L ND 1.0 09/09/09 00:31 1,2,3-Trichlorobenzene ug/L ND 1.0 09/09/09 00:31 1,2,3-Trichloropropane ug/L ND 1.0 09/09/09 00:31 1,2,4-Trichlorobenzene ug/L ND 1.0 09/09/09 00:31 1,2-Dibromo-3-chloropropane ug/L ND 3.0 09/09/09 00:31 1,2-Dibromoethane (EDB)ug/L ND 1.0 09/09/09 00:31 1,2-Dichlorobenzene ug/L ND 1.0 09/09/09 00:31 1,2-Dichloroethane ug/L ND 1.0 09/09/09 00:31 1,2-Dichloropropane ug/L ND 1.0 09/09/09 00:31 1,3-Dichlorobenzene ug/L ND 1.0 09/09/09 00:31 1,3-Dichloropropane ug/L ND 1.0 09/09/09 00:31 1,4-Dichlorobenzene ug/L ND 1.0 09/09/09 00:31 2,2-Dichloropropane ug/L ND 1.0 09/09/09 00:31 2-Butanone (MEK)ug/L ND 5.0 09/09/09 00:31 2-Chlorotoluene ug/L ND 1.0 09/09/09 00:31 2-Hexanone ug/L ND 5.0 09/09/09 00:31 4-Chlorotoluene ug/L ND 1.0 09/09/09 00:31 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 09/09/09 00:31 Acetone ug/L ND 25.0 09/09/09 00:31 Benzene ug/L ND 1.0 09/09/09 00:31 Bromobenzene ug/L ND 1.0 09/09/09 00:31 Bromochloromethane ug/L ND 1.0 09/09/09 00:31 Bromodichloromethane ug/L ND 1.0 09/09/09 00:31 Bromoform ug/L ND 1.0 09/09/09 00:31 Bromomethane ug/L ND 5.0 09/09/09 00:31 Carbon tetrachloride ug/L ND 1.0 09/09/09 00:31 Chlorobenzene ug/L ND 1.0 09/09/09 00:31 Chloroethane ug/L ND 1.0 09/09/09 00:31 Chloroform ug/L ND 1.0 09/09/09 00:31 Chloromethane ug/L ND 1.0 09/09/09 00:31 cis-1,2-Dichloroethene ug/L ND 1.0 09/09/09 00:31 cis-1,3-Dichloropropene ug/L ND 1.0 09/09/09 00:31 Dibromochloromethane ug/L ND 1.0 09/09/09 00:31 Dibromomethane ug/L ND 1.0 09/09/09 00:31 Dichlorodifluoromethane ug/L ND 1.0 09/09/09 00:31 Diisopropyl ether ug/L ND 1.0 09/09/09 00:31 Ethylbenzene ug/L ND 1.0 09/09/09 00:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 13 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:332161 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed Hexachloro-1,3-butadiene ug/L ND 1.0 09/09/09 00:31 m&p-Xylene ug/L ND 2.0 09/09/09 00:31 Methyl-tert-butyl ether ug/L ND 1.0 09/09/09 00:31 Methylene Chloride ug/L ND 2.0 09/09/09 00:31 Naphthalene ug/L ND 1.0 09/09/09 00:31 o-Xylene ug/L ND 1.0 09/09/09 00:31 p-Isopropyltoluene ug/L ND 1.0 09/09/09 00:31 Styrene ug/L ND 1.0 09/09/09 00:31 Tetrachloroethene ug/L ND 1.0 09/09/09 00:31 Toluene ug/L ND 1.0 09/09/09 00:31 trans-1,2-Dichloroethene ug/L ND 1.0 09/09/09 00:31 trans-1,3-Dichloropropene ug/L ND 1.0 09/09/09 00:31 Trichloroethene ug/L ND 1.0 09/09/09 00:31 Trichlorofluoromethane ug/L ND 1.0 09/09/09 00:31 Vinyl acetate ug/L ND 2.0 09/09/09 00:31 Vinyl chloride ug/L ND 1.0 09/09/09 00:31 1,2-Dichloroethane-d4 (S)%103 79-120 09/09/09 00:31 4-Bromofluorobenzene (S)%100 87-109 09/09/09 00:31 Dibromofluoromethane (S)%95 85-115 09/09/09 00:31 Toluene-d8 (S)%97 70-120 09/09/09 00:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 332162LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.950 114 83-125 1,1,1-Trichloroethane ug/L 49.850 100 80-129 1,1,2,2-Tetrachloroethane ug/L 49.150 98 73-127 1,1,2-Trichloroethane ug/L 51.450 103 77-123 1,1-Dichloroethane ug/L 48.350 97 76-129 1,1-Dichloroethene ug/L 49.750 99 78-146 1,1-Dichloropropene ug/L 48.650 97 79-134 1,2,3-Trichlorobenzene ug/L 48.950 98 70-150 1,2,3-Trichloropropane ug/L 52.650 105 72-125 1,2,4-Trichlorobenzene ug/L 49.550 99 68-127 1,2-Dibromo-3-chloropropane ug/L 46.650 93 65-128 1,2-Dibromoethane (EDB)ug/L 54.050 108 81-125 1,2-Dichlorobenzene ug/L 50.350 101 82-126 1,2-Dichloroethane ug/L 53.150 106 72-126 1,2-Dichloropropane ug/L 47.750 95 80-127 1,3-Dichlorobenzene ug/L 50.050 100 82-124 1,3-Dichloropropane ug/L 50.150 100 79-124 1,4-Dichlorobenzene ug/L 49.450 99 79-125 2,2-Dichloropropane ug/L 51.950 104 58-140 2-Butanone (MEK)ug/L 89.6100 90 50-134 2-Chlorotoluene ug/L 48.250 96 81-126 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 14 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 332162LABORATORY CONTROL SAMPLE: LCSSpike 2-Hexanone ug/L 89.7100 90 58-138 4-Chlorotoluene ug/L 49.750 99 82-126 4-Methyl-2-pentanone (MIBK)ug/L 98.8100 99 70-131 Acetone ug/L 89.7100 90 50-146 Benzene ug/L 45.150 90 78-128 Bromobenzene ug/L 48.050 96 81-127 Bromochloromethane ug/L 49.150 98 73-124 Bromodichloromethane ug/L 51.150 102 81-125 Bromoform ug/L 48.050 96 71-125 Bromomethane ug/L 64.250 128 50-150 Carbon tetrachloride ug/L 53.450 107 81-137 Chlorobenzene ug/L 49.250 98 82-126 Chloroethane ug/L 45.350 91 69-140 Chloroform ug/L 49.350 99 77-129 Chloromethane ug/L 42.650 85 54-139 cis-1,2-Dichloroethene ug/L 50.050 100 76-133 cis-1,3-Dichloropropene ug/L 53.350 107 76-127 Dibromochloromethane ug/L 48.050 96 77-125 Dibromomethane ug/L 54.850 110 77-125 Dichlorodifluoromethane ug/L 41.650 83 50-150 Diisopropyl ether ug/L 46.350 93 74-131 Ethylbenzene ug/L 49.850 100 80-127 Hexachloro-1,3-butadiene ug/L 50.750 101 78-145 m&p-Xylene ug/L 99.4100 99 82-127 Methyl-tert-butyl ether ug/L 47.150 94 71-130 Methylene Chloride ug/L 45.450 91 67-133 Naphthalene ug/L 54.850 110 52-136 o-Xylene ug/L 54.050 108 83-124 p-Isopropyltoluene ug/L 53.350 107 73-122 Styrene ug/L 48.750 97 80-130 Tetrachloroethene ug/L 50.650 101 78-128 Toluene ug/L 47.350 95 76-126 trans-1,2-Dichloroethene ug/L 46.450 93 78-134 trans-1,3-Dichloropropene ug/L 56.250 112 75-125 Trichloroethene ug/L 52.050 104 79-127 Trichlorofluoromethane ug/L 48.850 98 76-148 Vinyl acetate ug/L 99.2100 99 50-150 Vinyl chloride ug/L 49.150 98 67-143 1,2-Dichloroethane-d4 (S)%103 79-120 4-Bromofluorobenzene (S)%106 87-109 Dibromofluoromethane (S)%101 85-115 Toluene-d8 (S)%98 70-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 15 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units MS Result % Rec Limits Qual% RecConc. 332163MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 9251976006 332164 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1-Dichloroethene ug/L 50 119 60-150116 350ND59.7 57.9 Benzene ug/L 50 98 74-13699 1503.2 52.2 52.6 Chlorobenzene ug/L 50 106 79-135105 1500.80J 54.0 53.3 Toluene ug/L 50 102 73-131101 150ND50.9 50.5 Trichloroethene ug/L 50 114 73-131113 150ND57.0 56.3 1,2-Dichloroethane-d4 (S)%107 79-120109 4-Bromofluorobenzene (S)%103 87-109101 Dibromofluoromethane (S)%98 85-115101 Toluene-d8 (S)%95 70-12096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 16 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/5021 SM 3030C EPA 200.7 200.7 MET 3030C Associated Lab Samples:9252195001, 9252195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:331421 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed Lead ug/L ND 5.0 09/04/09 17:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 331422LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 521500 104 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 331423MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 9252195001 331424 MSD Result MSD % Rec RPD MSDMS Spike Conc. Lead ug/L 500 91 70-13092 150024.2 477 483 Parameter Units Dup Result QualifiersRPDResult 9252195002 331425SAMPLE DUPLICATE: Lead ug/L 4.5J5.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 17 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 QC Batch: QC Batch Method: Analysis Method: Analysis Description: OEXT/7933 MADEP EPH MADEP EPH MADEP EPH NC Water Associated Lab Samples:9252195001, 9252195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:333307 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed Aliphatic (C09-C18)ug/L ND 100 09/10/09 10:24 Aliphatic (C19-C36)ug/L ND 100 09/10/09 10:24 Aromatic (C11-C22)ug/L ND 100 09/10/09 10:24 2-Bromonaphthalene (S)%92 40-140 09/10/09 10:24 2-Fluorobiphenyl (S)%95 40-140 09/10/09 10:24 Nonatriacontane (S)%82 40-140 09/10/09 10:24 o-Terphenyl (S)%83 40-140 09/10/09 10:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 333308LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 333309 Aliphatic (C09-C18)ug/L 127 R13004240-14080240 62 50 Aliphatic (C19-C36)ug/L 334400 83 40-140115460 32 50 Aromatic (C11-C22)ug/L 791850 93 40-14091772 2 50 2-Bromonaphthalene (S)%112 40-14096 2-Fluorobiphenyl (S)%108 40-14091 Nonatriacontane (S)%78 40-140121 o-Terphenyl (S)%95 40-14082 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 18 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 QC Batch: QC Batch Method: Analysis Method: Analysis Description: OEXT/7921 EPA 3510 EPA 8270 8270 Water MSSV Associated Lab Samples:9252195001, 9252195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:332837 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 09/10/09 18:53 1,2-Dichlorobenzene ug/L ND 10.0 09/10/09 18:53 1,2-Diphenylhydrazine ug/L ND 10.0 09/10/09 18:53 1,3-Dichlorobenzene ug/L ND 10.0 09/10/09 18:53 1,4-Dichlorobenzene ug/L ND 10.0 09/10/09 18:53 1-Methylnaphthalene ug/L ND 10.0 09/10/09 18:53 2,4,5-Trichlorophenol ug/L ND 10.0 09/10/09 18:53 2,4,6-Trichlorophenol ug/L ND 10.0 09/10/09 18:53 2,4-Dichlorophenol ug/L ND 10.0 09/10/09 18:53 2,4-Dimethylphenol ug/L ND 10.0 09/10/09 18:53 2,4-Dinitrophenol ug/L ND 50.0 09/10/09 18:53 2,4-Dinitrotoluene ug/L ND 10.0 09/10/09 18:53 2,6-Dinitrotoluene ug/L ND 10.0 09/10/09 18:53 2-Chloronaphthalene ug/L ND 10.0 09/10/09 18:53 2-Chlorophenol ug/L ND 10.0 09/10/09 18:53 2-Methylnaphthalene ug/L ND 10.0 09/10/09 18:53 2-Methylphenol(o-Cresol)ug/L ND 10.0 09/10/09 18:53 2-Nitroaniline ug/L ND 50.0 09/10/09 18:53 2-Nitrophenol ug/L ND 10.0 09/10/09 18:53 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 09/10/09 18:53 3,3'-Dichlorobenzidine ug/L ND 50.0 09/10/09 18:53 3-Nitroaniline ug/L ND 50.0 09/10/09 18:53 4,6-Dinitro-2-methylphenol ug/L ND 20.0 09/10/09 18:53 4-Bromophenylphenyl ether ug/L ND 10.0 09/10/09 18:53 4-Chloro-3-methylphenol ug/L ND 20.0 09/10/09 18:53 4-Chloroaniline ug/L ND 50.0 09/10/09 18:53 4-Chlorophenylphenyl ether ug/L ND 10.0 09/10/09 18:53 4-Nitroaniline ug/L ND 50.0 09/10/09 18:53 4-Nitrophenol ug/L ND 50.0 09/10/09 18:53 Acenaphthene ug/L ND 10.0 09/10/09 18:53 Acenaphthylene ug/L ND 10.0 09/10/09 18:53 Aniline ug/L ND 10.0 09/10/09 18:53 Anthracene ug/L ND 10.0 09/10/09 18:53 Benzo(a)anthracene ug/L ND 10.0 09/10/09 18:53 Benzo(a)pyrene ug/L ND 10.0 09/10/09 18:53 Benzo(b)fluoranthene ug/L ND 10.0 09/10/09 18:53 Benzo(g,h,i)perylene ug/L ND 10.0 09/10/09 18:53 Benzo(k)fluoranthene ug/L ND 10.0 09/10/09 18:53 Benzoic Acid ug/L ND 50.0 09/10/09 18:53 Benzyl alcohol ug/L ND 20.0 09/10/09 18:53 bis(2-Chloroethoxy)methane ug/L ND 10.0 09/10/09 18:53 bis(2-Chloroethyl) ether ug/L ND 10.0 09/10/09 18:53 bis(2-Chloroisopropyl) ether ug/L ND 10.0 09/10/09 18:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 19 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:332837 Associated Lab Samples:9252195001, 9252195002 Matrix:Water Analyzed bis(2-Ethylhexyl)phthalate ug/L ND 10.0 09/10/09 18:53 Butylbenzylphthalate ug/L ND 10.0 09/10/09 18:53 Chrysene ug/L ND 10.0 09/10/09 18:53 Di-n-butylphthalate ug/L ND 10.0 09/10/09 18:53 Di-n-octylphthalate ug/L ND 10.0 09/10/09 18:53 Dibenz(a,h)anthracene ug/L ND 10.0 09/10/09 18:53 Dibenzofuran ug/L ND 10.0 09/10/09 18:53 Diethylphthalate ug/L ND 10.0 09/10/09 18:53 Dimethylphthalate ug/L ND 10.0 09/10/09 18:53 Fluoranthene ug/L ND 10.0 09/10/09 18:53 Fluorene ug/L ND 10.0 09/10/09 18:53 Hexachloro-1,3-butadiene ug/L ND 10.0 09/10/09 18:53 Hexachlorobenzene ug/L ND 10.0 09/10/09 18:53 Hexachlorocyclopentadiene ug/L ND 10.0 09/10/09 18:53 Hexachloroethane ug/L ND 10.0 09/10/09 18:53 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 09/10/09 18:53 Isophorone ug/L ND 10.0 09/10/09 18:53 N-Nitroso-di-n-propylamine ug/L ND 10.0 09/10/09 18:53 N-Nitrosodimethylamine ug/L ND 10.0 09/10/09 18:53 N-Nitrosodiphenylamine ug/L ND 10.0 09/10/09 18:53 Naphthalene ug/L ND 10.0 09/10/09 18:53 Nitrobenzene ug/L ND 10.0 09/10/09 18:53 Pentachlorophenol ug/L ND 50.0 09/10/09 18:53 Phenanthrene ug/L ND 10.0 09/10/09 18:53 Phenol ug/L ND 10.0 09/10/09 18:53 Pyrene ug/L ND 10.0 09/10/09 18:53 2,4,6-Tribromophenol (S)%68 25-150 09/10/09 18:53 2-Fluorobiphenyl (S)%68 30-150 09/10/09 18:53 2-Fluorophenol (S)%34 25-150 09/10/09 18:53 Nitrobenzene-d5 (S)%65 30-150 09/10/09 18:53 Phenol-d6 (S)%26 25-150 09/10/09 18:53 Terphenyl-d14 (S)%74 30-150 09/10/09 18:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 332838LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 22.250 44 19-120 1,2-Dichlorobenzene ug/L 24.650 49 19-120 1,2-Diphenylhydrazine ug/L 38.550 77 50-150 1,3-Dichlorobenzene ug/L 23.750 47 15-120 1,4-Dichlorobenzene ug/L 24.350 49 15-120 1-Methylnaphthalene ug/L 25.550 51 21-120 2,4,5-Trichlorophenol ug/L 31.450 63 23-113 2,4,6-Trichlorophenol ug/L 37.150 74 21-113 2,4-Dichlorophenol ug/L 27.450 55 12-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 20 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 332838LABORATORY CONTROL SAMPLE: LCSSpike 2,4-Dimethylphenol ug/L 27.550 55 24-120 2,4-Dinitrophenol ug/L 25.3J50 51 10-127 2,4-Dinitrotoluene ug/L 37.150 74 36-115 2,6-Dinitrotoluene ug/L 38.250 76 37-114 2-Chloronaphthalene ug/L 32.850 66 36-101 2-Chlorophenol ug/L 27.350 55 24-120 2-Methylnaphthalene ug/L 23.350 47 19-120 2-Methylphenol(o-Cresol)ug/L 25.350 51 25-120 2-Nitroaniline ug/L 38.2J50 76 30-109 2-Nitrophenol ug/L 27.750 55 24-120 3&4-Methylphenol(m&p Cresol)ug/L 22.450 45 24-120 3,3'-Dichlorobenzidine ug/L 39.2J50 78 14-120 3-Nitroaniline ug/L 38.3J50 77 23-133 4,6-Dinitro-2-methylphenol ug/L 27.150 54 10-128 4-Bromophenylphenyl ether ug/L 41.150 82 35-113 4-Chloro-3-methylphenol ug/L 30.150 60 32-107 4-Chloroaniline ug/L 18J50 36 12-150 4-Chlorophenylphenyl ether ug/L 38.250 76 36-110 4-Nitroaniline ug/L 47.6J50 95 12-150 4-Nitrophenol ug/L 34.6J50 69 10-120 Acenaphthene ug/L 34.450 69 27-102 Acenaphthylene ug/L 37.050 74 25-105 Aniline ug/L 17.150 34 10-150 Anthracene ug/L 37.250 74 30-113 Benzo(a)anthracene ug/L 34.850 70 27-113 Benzo(a)pyrene ug/L 34.750 69 27-119 Benzo(b)fluoranthene ug/L 28.250 56 22-114 Benzo(g,h,i)perylene ug/L 42.850 86 10-129 Benzo(k)fluoranthene ug/L 34.750 69 24-111 Benzoic Acid ug/L ND L0501424-120 Benzyl alcohol ug/L 32.650 65 24-120 bis(2-Chloroethoxy)methane ug/L 34.950 70 32-120 bis(2-Chloroethyl) ether ug/L 38.950 78 29-120 bis(2-Chloroisopropyl) ether ug/L 35.250 70 22-120 bis(2-Ethylhexyl)phthalate ug/L 38.450 77 29-125 Butylbenzylphthalate ug/L 38.950 78 33-120 Chrysene ug/L 34.550 69 23-112 Di-n-butylphthalate ug/L 40.050 80 38-116 Di-n-octylphthalate ug/L 42.750 85 32-122 Dibenz(a,h)anthracene ug/L 42.550 85 10-129 Dibenzofuran ug/L 34.750 69 37-107 Diethylphthalate ug/L 40.850 82 40-111 Dimethylphthalate ug/L 39.050 78 39-108 Fluoranthene ug/L 36.550 73 27-112 Fluorene ug/L 35.250 70 29-107 Hexachloro-1,3-butadiene ug/L 21.450 43 10-113 Hexachlorobenzene ug/L 36.250 72 29-119 Hexachlorocyclopentadiene ug/L 14.650 29 10-113 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 21 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 332838LABORATORY CONTROL SAMPLE: LCSSpike Hexachloroethane ug/L 22.950 46 10-120 Indeno(1,2,3-cd)pyrene ug/L 41.350 83 14-123 Isophorone ug/L 30.150 60 23-150 N-Nitroso-di-n-propylamine ug/L 42.950 86 31-104 N-Nitrosodimethylamine ug/L 21.450 43 10-120 N-Nitrosodiphenylamine ug/L 33.950 68 27-139 Naphthalene ug/L 24.950 50 17-120 Nitrobenzene ug/L 31.850 64 27-120 Pentachlorophenol ug/L 19.6J50 39 10-135 Phenanthrene ug/L 36.250 72 28-111 Phenol ug/L 11.150 22 10-120 Pyrene ug/L 33.050 66 27-113 2,4,6-Tribromophenol (S)%76 25-150 2-Fluorobiphenyl (S)%65 30-150 2-Fluorophenol (S)%30 25-150 Nitrobenzene-d5 (S)%54 30-150 Phenol-d6 (S)%25 25-150 Terphenyl-d14 (S)%66 30-150 Parameter Units MS Result % Rec Limits Qual% RecConc. 332839MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 9252348001 332840 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/L 100 50 13-12048 3100ND49.9 48.4 1,4-Dichlorobenzene ug/L 100 50 19-12056 11100ND50.5 56.5 2,4-Dinitrotoluene ug/L 100 71 41-10958 20100ND71.3 58.3 2-Chlorophenol ug/L 100 59 33-12056 4100ND58.6 56.3 4-Chloro-3-methylphenol ug/L 100 66 30-10854 20100ND65.9 53.7 4-Nitrophenol ug/L 100 60 10-12051100ND59.9J 51.4J Acenaphthene ug/L 100 72 27-10160 18100ND72.1 60.1 N-Nitroso-di-n-propylamine ug/L 100 87 34-12080 8100ND86.6 79.8 Pentachlorophenol ug/L 100 32 10-13823100ND31.9J 23.4J Phenol ug/L 100 39 10-12034 12100ND38.9 34.4 Pyrene ug/L 100 66 31-11056 16100ND66.2 56.3 2,4,6-Tribromophenol (S)%79 25-15055 2-Fluorobiphenyl (S)%70 30-15059 2-Fluorophenol (S)%36 25-15037 Nitrobenzene-d5 (S)%58 30-15052 Phenol-d6 (S)%39 25-15035 Terphenyl-d14 (S)%75 30-15056 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 22 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Pace Project No.: Project: 9252195 THE PROVINCE 71097746 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 23 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 9252195 THE PROVINCE 71097746 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 9252195001 MPRP/5021 ICP/4655MW-3 SM 3030C EPA 200.7 9252195002 MPRP/5021 ICP/4655MW-4 SM 3030C EPA 200.7 9252195001 MSV/8192MW-3 EPA 8260 9252195002 MSV/8192MW-4 EPA 8260 9252195001 OEXT/7921 MSSV/3065MW-3 EPA 3510 EPA 8270 9252195002 OEXT/7921 MSSV/3065MW-4 EPA 3510 EPA 8270 9252195001 OEXT/7933 GCSV/6198MW-3 MADEP EPH MADEP EPH 9252195002 OEXT/7933 GCSV/6198MW-4 MADEP EPH MADEP EPH 9252195001 GCV/3459MW-3 MADEP VPH 9252195002 GCV/3459MW-4 MADEP VPH REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 09/14/2009 09:12 AM Page 24 of 24 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Appendix B Well Construction Records