13020_Newman Machine_Post_Construction_Report_06_17_2011

N.C. Brownfields Program
Post-Construction Sampling Report

The Province at UNC Greensboro
Greensboro, North Carolina
June 17, 2011
Terracon Project No. 71097746

Prepared for:
ECCC-NC, LLC
Columbus, Ohio

Prepared by:
Terracon Consultants, Inc.
Charlotte, North Carolina

Terracon Consultants, Inc. 2020-E Starita Road Charlotte, North Carolina 28206
P [704] 509 1777 F [704] 509 1888 terracon.com

June 17, 2011

Mr. Mike Cannon, President
ECCC-NC, LLC
Edwards Communities Construction Company
151 South High Street
Charlotte, North Carolina 28204

Re: DRAFT - North Carolina Brownfields Program Post-Construction Sampling Report
The Province at UNC Greensboro
Province Spring Circle
Greensboro, Guilford County, North Carolina
Project No. 71097746

Dear Mr. Cannon:

Terracon Consultants, Inc. (Terracon) appreciates the opportunity to submit this Post
Construction Report for the referenced site in order to assist ECCC-NC, LLC in finalizing
their North Carolina Brownfields Agreement.

We appreciate the opportunity to perform these services for you. Please contact us if you
have questions regarding this information or if we can provide any other services.

Sincerely,
Terracon Consultants, Inc.

Stephen C. Brown Christopher L. Corbitt, PG
Project Geologist Environmental Services Manager

Reliable ■ Responsive ■ Convenient ■ Innovative i
TABLE OF CONTENTS

1.0 INTRODUCTION ......................................................................................................... 1 
1.1 Site Description .................................................................................................. 1 
1.2 Historical Background ........................................................................................ 1 
2.0 REFERENCES ............................................................................................................ 2 
3.0 SOIL MANAGEMENT PRACTICES ........................................................................... 2 
3.1 On-Site Soil Management Areas ....................................................................... 2 
3.2 Off-Site Soil Disposal ......................................................................................... 4 
4.0 POST-CONSTRUCTION SAMPLING ........................................................................ 4 
4.1 Field Activities .................................................................................................... 5 
4.2 Laboratory Analytical Methods ........................................................................... 5 
4.3 Data Evaluation .................................................................................................. 5 

APPENDICES

APPENDIX A Figure 1 – Site Location Map
Figure 2 – Sample Location Plan
APPENDIX B Soil Disposal Documentation
APPENDIX C Laboratory Analytical Reports

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DRAFT POST-CONSTRUCTION SAMPLING REPORT
THE PROVINCE AT UNC GREENSBORO
PROVINCE SPRING CIRCLE
GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA

Project No. 71097746
Report Date: June 17, 2011
1.0 INTRODUCTION
1.1 Site Description
Site Description
Site Name The Province at UNC Greensboro
Site Location/Address Province Spring Circle
Greensboro, Guilford County, North Carolina
Land Area Approximately 11 acres
Site Improvements
The site is developed with twelve residential buildings containing
219 units, a Clubhouse and a maintenance building. Remaining
portions of the site are ashphalt-paved roadways and parking areas
containing 624 parking spaces.

The site location is depicted on Figure 1 of Appendix A which was reproduced from a
portion of the USGS 7.5-minute series topographic map.
1.2 Historical Background
Prior to its current development, most of the site was comprised of Newman Machine
Company, a manufacturer of woodworking equipment for the pulp and paper industry.
Some portions of the site along Houston Street contained a company that bought and sold
used restaurant equipment. The southwestern-most portion of the site along Lilly Avenue
contained a construction company.

Based on a review of available historical information, the site appears to have contained
single-family residences from the late 1800s. Newman Machine manufactured
woodworking equipment on the site from about 1906 to 2010. Newman Machine also
operated Guilford Foundry on the site from approximately 1912 to 1983. Portions of the
site along the south side of Houston Street have included various lumber companies, a
coal supply company and a building supply company prior to the restaurant supply
company. The southwestern-most portion of the site along Lilly Avenue was operated as
various lumber yards and building supply companies from as early as 1922.

Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 2
Terracon assessment activities conducted in 2009 indicated limited areas beneath certain
Newman Machine buildings, and behind a structural retaining wall, contained
contaminants of concern (COCs) due to past industrial use of the site. Based on the
analytical data collected during the various investigations, the fill materials were generally
impacted by various metals and / or polycyclic aromatic hydrocarbons (PAHs).
Groundwater at the site has also been identified as being impacted by petroleum
constituents and chlorinated solvent constituents.
2.0 REFERENCES
Terracon conducted an environmental assessment of the property in 2009. Our report
titled, “Phase I Environmental Site Assessment – The Province at UNC Greensboro”, was
issued on September 24, 2009.

Terracon conducted soil and groundwater sampling activities on the site between July 20,
2009 and September 1, 2009. A report of our findings titled, “Limited Site Investigation –
The Province at UNC Greensboro”, was issued on October 6, 2009.

Risk Management Plan – The Province at UNC Greensboro, Attachment A: Soil
Management Plan, dated June 30, 2010, prepared by Terracon Consultants, Inc.
3.0 SOIL MANAGEMENT PRACTICES
At the request of the client, Terracon provided oversight during certain portions of the site
grading activities to observe changes in on-site soil conditions. Excess “clean” soils were
stockpiled pending off-site removal. Prior to removal from the site, representative
composite soil samples were collected approximately every 200 cubic yards and analyzed
for volatile organic compounds and semi-volatile organic compounds (VOCs and SVOCs),
and RCRA metals in accordance with the Soil Management Plan. Materials determined to
contain COCs by laboratory analysis or visual observations were safely managed by
placing them as fill in one of the seven designated Soil Management Areas (SMAs) on the
site.
3.1 On-Site Soil Management Areas
Soils containing COCs were managed on the site by placing them in designated SMAs.
Once filled, SMAs were capped with an impervious surface, either a building or asphalt
parking/driveway area. No SMAs are present within the railroad easement located in the
southern portion of the site. No SMAs containing VOCs or SVOCs are situated beneath
on-site buildings.

Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 3
SMA #1
SMA #1 is situated along the west side of Fulton Street and includes the parking lot and
the lower level (east side) of Buildings 6 and 7. Green space between Buildings 6 and 7
sidewalks and any other areas not capped with impervious surfaces were excluded as
part of SMA #1. The fill placed with SMA #1 included used foundry sand from a former
structural retaining wall and petroleum-impacted soils from areas within the railroad
easement. The COC concentrations associated with the used foundry sand include:
arsenic ranging from 9 mg/kg to 255 mg/kg, cadmium ranging from 50.1 mg/kg to 115
mg/kg, chromium ranging from 75.7 mg/kg to 262 mg/kg and lead ranging from 3.3 mg/kg
to 5,070 mg/kg. The COC concentrations associated with the petroleum-impacted soils
include various PAHs attributable to use of heavy oils as machinery lubricants and
naphthalene, most likely attributable to a surface spill of diesel fuel or heating oil.

SMA #2
SMA #2 was proposed but never constructed beneath Building 5.

SMA #3
SMA #3 is situated along the west side of Buildings 5 and 6 and includes the parking lot
and driveway areas west of Buildings 5 and 6. SMA #3 also includes sidewalks that abut
the parking lot. Green space such as tree/shrub planters and any other areas not capped
with an impervious surface were excluded as part of SMA #3. SMA #3 is the location of
the former Newman Machine Company machining and milling buildings. The fill placed
within SMA #3 included used foundry sand from the former Newman Machine retaining
wall and petroleum-impacted soils from areas within the railroad easement. The COC
constituents and concentrations were similar to those contained in materials placed in
SMA #1.

SMA #4
SMA #4 is situated along the north side of Buildings 8 and 9 and south of Buildings 1 and
3 near portions of the former Lilly Avenue. SMA #4 includes the parking lot and driveway
areas, but green space such as tree/shrub planters and any other areas not capped with
an impervious surface were excluded as part of SMA #4. This area of the site formerly
contained Newman machine foundry and milling operations. The fill placed with SMA #4
included used foundry sand from the former Newman Machine retaining wall and
petroleum-impacted soils from areas within the railroad easement. The COC constituents
and concentrations were similar to those contained in materials placed in SMA #3.

SMA #5
SMA #5 is situated beneath parking lot and driveway areas in the southwestern-most
portion of the site. Green space such as tree/shrub planters and any other areas not
capped with an impervious surface were excluded as part of SMA #5. The groundwater
beneath SMA #5 is contaminated with concentrations of carbon tetrachloride above its
Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 4
North Carolina 2L water quality standard. The fill placed in SMA #5 included petroleum-
stained crushed concrete floor slab material immediately below the pavement profile.
Laboratory analysis of the stained concrete detected concentrations of various PAHs
related to heavy oils used to lubricate machinery. The fill placed within SMA #5 also
included materials similar to those placed in SMA #3.

SMA #6
SMA #6 is comprised of parking lot and roadway areas along the east side of Buildings 1
and 13 and west of Building 3. Areas not capped with an impervious surface were
excluded as part of SMA #6. The fill placed in SMA #6 is comprised of a 4 to 6 inch lift of
petroleum-stained crushed concrete floor slab material immediately below the pavement
profile. Laboratory analysis of the stained concrete detected concentrations of various
PAHs related to heavy oils used to lubricate machinery.

SMA #7
SMA #7 is comprised of parking lot and roadway areas along the south side of Buildings
2, 4, 14, 14A and 14B and north of Building 3 and the Community Center building. Areas
not capped with an impervious surface were excluded as part of SMA #7. The fill placed
in SMA #7 is comprised of a 4 to 6 inch lift of petroleum-stained crushed concrete floor
slab material immediately below the pavement profile. Laboratory analysis of the stained
concrete detected concentrations of various PAHs related to heavy oils used to lubricate
machinery.
3.2 Off-Site Soil Disposal
Based on the absence of sufficient capacity in the SMAs, approximately 67.53 tons of
petroleum-contaminated soils were removed from a driveway area situated in the railroad
easement in the southeastern portion of the site. The soils were transported to EVO
Corporation in Winston Salem, North Carolina for disposal. A copy of the soil disposal
documentation is included in Appendix B.
4.0 POST-CONSTRUCTION SAMPLING
At the request of the North Carolina Brownfields Program, Terracon conducted post-
construction sampling of shallow soils on the site to evaluate the potential presence of
COCs in uncapped portions of the site such as landscaped areas that could represent
potential pathways to human contact or the environment. No industrial activities were
known to have occurred in the northwestern portion of the site and no COCs were
identified during our previous assessments; thus, this area of the site was excluded from
the post-construction sampling activities.
Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 5
4.1 Field Activities
Terracon mobilized to the site on May 11, 2011 to collect shallow soil samples in selected
locations where impacted soils have been staged, near soil management areas, and other
locations that may represent a potential exposure hazard to future occupants of the site.
Utilizing a stainless steel hand auger, Terracon manually advanced 17 soil borings on the
site to depths approximately 2 to 3 feet below grade surface (bgs). A representative soil
sample was collected for laboratory analysis at each boring location. The hand auger was
decontaminated in an Alconox solution and distilled water prior to advancing each boring.
The approximate boring locations are shown on Figure 2 - Sample Location Plan included
in Appendix A. The soil samples were placed in laboratory provided glassware and
placed in an ice-packed cooler for transport to Pace Analytical Services, Inc., in
Huntersville, North Carolina.

In order to further evaluate potential elevated chromium concentrations on the site,
Terracon collected four additional soil samples on May 25, 2011. Four hand auger
borings were advanced approximately 5 feet north (PCS-1A), east (PCS-1B), south (PCS-
1C), and west (OCS-1D) of soil sample location PCS-1. The hand auger was
decontaminated prior to advancing each boring. The soil samples were placed in
laboratory provided glassware and placed in an ice-packed cooler for transport to Pace
Analytical Services, Inc., in Huntersville, North Carolina.
4.2 Laboratory Analytical Methods
Based on the COCs identified during our previous assessment activities, the post-
construction soil samples were submitted for laboratory analysis of PAHs by EPA Method
8270D and lead and chromium by EPA Method 6010. Results of the laboratory analysis
are discussed below.

4.3 Data Evaluation

Table 1: Analytical Results Summary
Sample
No.
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PCS-1 23.0 55.0 0.441 0.395 0.400 0.377 0.470 1.3 1.4 1.16
PCS-1A NA 33.3 NA NA NA NA NA NA NA NA
PCS-1B NA 16.6 NA NA NA NA NA NA NA NA
PCS-1C NA 15.3 NA NA NA NA NA NA NA NA
PCS-1D NA 16.4 NA NA NA NA NA NA NA NA
Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 6
Table 1: Analytical Results Summary (continued)
Sample
No.
To
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Ph
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Py
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PCS-2 5.4 9 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-3 7.8 14.4 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-4 3.0 15.7 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-5 6.4 15.7 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-6 17.6 7.3 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-7 1.2 10 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-8 6.6 8.5 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-9 0.98 1.4 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-10 2.9 7.5 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-11 2.7 1.4 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-12 6.6 11.1 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-13 4.1 10.3 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-14 13.5 12.2 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-15 2.4 7 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-16 12.1 16 BDL BDL BDL BDL BDL BDL BDL BDL
PCS-17 10.5 14.9 BDL BDL BDL BDL BDL BDL BDL BDL
IHSB
SRGs 400 0.29* 0.15 0.015 0.15 1.5 15 460 N/A 340
IHSB
PSRGs 270 3.8* 0.18 0.059 0.60 5.9 18 330 57 220
Results are reported in milligrams/kilogram (mg/kg)
IHSB SRGs – Inactive Hazardous Sites Branch Soil Remediation Goals
IHSB PSRGs – Inactive Hazardous Sites Branch Protection of Groundwater Soil Remediation Goals
* - Regulatory Action Levels for Chromium(VI)

Based on previous assessment activities on the site and visual evidence of past coal
usage on the property, the PAH constituents are most likely the result of coal fragments in
the soil. According to Mr. Colin Day of the North Carolina Department of Environment and
Natural Resources (NCDENR) Inactive Hazardous Sites Branch (IHSB), coal is a naturally
occurring material and the IHSB generally does not consider coal to represent a potential
environmental concern.

Total chromium was detected at 55 milligrams per kilogram (mg/kg) in soil sample PCS-1.
The IHSB Soil Remediation Goals (SRGs) for chromium (III) is 23,000 mg/kg and the
SRG for chromium (VI) is 0.29 mg/kg. Chromium (VI) or hexavalent chromium is a
manmade material that is generally associated with electro-plating operations. No electro-
plating activities were known to have occurred on the site. Laboratory analysis of a
Draft Post Construction Sampling Report
The Province at UNC Greensboro ■ Charlotte, North Carolina
June 17, 2011 ■ Terracon Project No. 71097746

Reliable ■ Responsive ■ Convenient ■ Innovative 7
background soil sample collected in the northern portion of the site during our 2009
assessment activities detected total chromium concentrations as high as 30.4 mg/kg.
Terracon also conducted Toxicity Characteristic Leachate Procedure (TCLP) analyses as
part of our 2009 assessment activities to evaluate the leachability of metals at the site.
Chromium and lead concentrations were not detected above the TCLP detection limits.

Based on the analytical results from the second sampling event on May 25, 2011, total
chromium concentrations were detected at concentrations consistent with established
background levels for the site. In our opinion, the chromium concentrations detected
during the post-construction sampling activities represent naturally occurring chromium.

APPENDIX A

Figure 1 – Site Location Map
Figure 2 – Sample Location Plan
SITE LOCATION MAP
THE PROVINCE AT UNC GREENSBORO
PROVIDENCE SPRING CIRCLE
GREENSBORO, NORTH CAROLINA
REFERENCE: USGS Topographic Map; Guilford, North Carolina Q
SITE
PROJECT NO.: 71097746
DATE: May 21, 2011
DRAWN BY: SCB
SCALE: 1” = 2000’FIGURE NO. 1
Quadrangle; dated 1951 and revised in 1994.
PC
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17
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SAMPLE

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DATE: MAY 21 , 2011PROJECT NO.: 71097746SAMPLE LOCATION PLAN THE PROVINCE AT UNC GREENSBORO PROVINCE SPRING CIRCLE FIGURE NO. 2 1” ≈ 120’,GREENSBORO, NORTH CAROLINA
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APPENDIX B

Soil Disposal Documentation

APPENDIX C

Laboratory Analytical Reports
May 17, 2011
LIMS USE: FR - STEPHEN BROWN
LIMS OBJECT ID: 9294023
9294023
Project:
Pace Project No.:
RE:
Mr. Stephen Brown
Terracon
2020 E Starita Road
Charlotte, NC 28206
THE PROVINCE
Dear Mr. Brown:
Enclosed are the analytical results for sample(s) received by the laboratory on May 12, 2011. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9294023
THE PROVINCE
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078Louisiana/LELAP Certification #: 04034
New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003Virginia Certification #: 00213
Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana DHH Drinking Water # LA 100031West Virginia Certification #: 357
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804Connecticut Certification #: PH-0106Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030New Jersey Certification #: NC011
North Carolina Bioassay Certification #: 9North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 99030002
South Carolina Certification #: 99030001Virginia Certification #: 00072
West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9294023
THE PROVINCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9294023001 PCS-1 EPA 6010 2 PASI-AJDA
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023002 PCS-2 EPA 6010 2 PASI-AJDA
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023003 PCS-3 EPA 6010 2 PASI-AJDA
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023004 PCS-4 EPA 6010 2 PASI-AJDA
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023005 PCS-5 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023006 PCS-6 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023007 PCS-7 EPA 6010 2 PASI-AJMW
EPA 8270 24 PASI-CPPM
ASTM D2974-87 1 PASI-CTNM
9294023008 PCS-8 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023009 PCS-9 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023010 PCS-10 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023011 PCS-11 EPA 6010 2 PASI-AJMW
EPA 8270 24 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023012 PCS-12 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023013 PCS-13 EPA 6010 2 PASI-AJMW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9294023
THE PROVINCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023014 PCS-14 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023015 PCS-15 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023016 PCS-16 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
9294023017 PCS-17 EPA 6010 2 PASI-AJMW
EPA 8270 21 PASI-CBPJ
ASTM D2974-87 1 PASI-CTNM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-1 Lab ID:9294023001 Collected:05/11/11 12:30 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 55.0 mg/kg 1 05/14/11 19:37 7440-47-305/13/11 15:450.56
Lead 23.0 mg/kg 1 05/14/11 19:37 7439-92-105/13/11 15:450.56
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 20:20 83-32-905/13/11 07:20376
Acenaphthylene ND ug/kg 1 05/13/11 20:20 208-96-805/13/11 07:20376
Anthracene ND ug/kg 1 05/13/11 20:20 120-12-705/13/11 07:20376
Benzo(a)anthracene 441 ug/kg 1 05/13/11 20:20 56-55-305/13/11 07:20376
Benzo(a)pyrene 395 ug/kg 1 05/13/11 20:20 50-32-805/13/11 07:20376
Benzo(b)fluoranthene 400 ug/kg 1 05/13/11 20:20 205-99-205/13/11 07:20376
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 20:20 191-24-205/13/11 07:20376
Benzo(k)fluoranthene 377 ug/kg 1 05/13/11 20:20 207-08-905/13/11 07:20376
Chrysene 470 ug/kg 1 05/13/11 20:20 218-01-905/13/11 07:20376
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 20:20 53-70-305/13/11 07:20376
Fluoranthene 1300 ug/kg 1 05/13/11 20:20 206-44-005/13/11 07:20376
Fluorene ND ug/kg 1 05/13/11 20:20 86-73-705/13/11 07:20376
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 20:20 193-39-505/13/11 07:20376
1-Methylnaphthalene ND ug/kg 1 05/13/11 20:20 90-12-005/13/11 07:20376
2-Methylnaphthalene ND ug/kg 1 05/13/11 20:20 91-57-605/13/11 07:20376
Naphthalene ND ug/kg 1 05/13/11 20:20 91-20-305/13/11 07:20376
Phenanthrene 1400 ug/kg 1 05/13/11 20:20 85-01-805/13/11 07:20376
Pyrene 1160 ug/kg 1 05/13/11 20:20 129-00-005/13/11 07:20376
Nitrobenzene-d5 (S)53 %1 05/13/11 20:20 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)62 %1 05/13/11 20:20 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)80 %1 05/13/11 20:20 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 12.2 %1 05/13/11 09:350.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 5 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-2 Lab ID:9294023002 Collected:05/11/11 12:45 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 9.0 mg/kg 1 05/14/11 19:42 7440-47-305/13/11 15:450.52
Lead 5.4 mg/kg 1 05/14/11 19:42 7439-92-105/13/11 15:450.52
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 20:48 83-32-905/13/11 07:20391
Acenaphthylene ND ug/kg 1 05/13/11 20:48 208-96-805/13/11 07:20391
Anthracene ND ug/kg 1 05/13/11 20:48 120-12-705/13/11 07:20391
Benzo(a)anthracene ND ug/kg 1 05/13/11 20:48 56-55-305/13/11 07:20391
Benzo(a)pyrene ND ug/kg 1 05/13/11 20:48 50-32-805/13/11 07:20391
Benzo(b)fluoranthene ND ug/kg 1 05/13/11 20:48 205-99-205/13/11 07:20391
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 20:48 191-24-205/13/11 07:20391
Benzo(k)fluoranthene ND ug/kg 1 05/13/11 20:48 207-08-905/13/11 07:20391
Chrysene ND ug/kg 1 05/13/11 20:48 218-01-905/13/11 07:20391
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 20:48 53-70-305/13/11 07:20391
Fluoranthene ND ug/kg 1 05/13/11 20:48 206-44-005/13/11 07:20391
Fluorene ND ug/kg 1 05/13/11 20:48 86-73-705/13/11 07:20391
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 20:48 193-39-505/13/11 07:20391
1-Methylnaphthalene ND ug/kg 1 05/13/11 20:48 90-12-005/13/11 07:20391
2-Methylnaphthalene ND ug/kg 1 05/13/11 20:48 91-57-605/13/11 07:20391
Naphthalene ND ug/kg 1 05/13/11 20:48 91-20-305/13/11 07:20391
Phenanthrene ND ug/kg 1 05/13/11 20:48 85-01-805/13/11 07:20391
Pyrene ND ug/kg 1 05/13/11 20:48 129-00-005/13/11 07:20391
Nitrobenzene-d5 (S)55 %1 05/13/11 20:48 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)67 %1 05/13/11 20:48 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)89 %1 05/13/11 20:48 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 15.5 %1 05/13/11 09:360.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 6 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-3 Lab ID:9294023003 Collected:05/11/11 12:55 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 14.4 mg/kg 1 05/14/11 19:47 7440-47-305/13/11 15:450.53
Lead 7.8 mg/kg 1 05/14/11 19:47 7439-92-105/13/11 15:450.53
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/14/11 04:10 83-32-905/13/11 07:201990
Acenaphthylene ND ug/kg 1 05/14/11 04:10 208-96-805/13/11 07:201990
Anthracene ND ug/kg 1 05/14/11 04:10 120-12-705/13/11 07:201990
Benzo(a)anthracene ND ug/kg 1 05/14/11 04:10 56-55-305/13/11 07:201990
Benzo(a)pyrene ND ug/kg 1 05/14/11 04:10 50-32-805/13/11 07:201990
Benzo(b)fluoranthene ND ug/kg 1 05/14/11 04:10 205-99-205/13/11 07:201990
Benzo(g,h,i)perylene ND ug/kg 1 05/14/11 04:10 191-24-205/13/11 07:201990
Benzo(k)fluoranthene ND ug/kg 1 05/14/11 04:10 207-08-905/13/11 07:201990
Chrysene ND ug/kg 1 05/14/11 04:10 218-01-905/13/11 07:201990
Dibenz(a,h)anthracene ND ug/kg 1 05/14/11 04:10 53-70-305/13/11 07:201990
Fluoranthene ND ug/kg 1 05/14/11 04:10 206-44-005/13/11 07:201990
Fluorene ND ug/kg 1 05/14/11 04:10 86-73-705/13/11 07:201990
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/14/11 04:10 193-39-505/13/11 07:201990
1-Methylnaphthalene ND ug/kg 1 05/14/11 04:10 90-12-0 P305/13/11 07:201990
2-Methylnaphthalene ND ug/kg 1 05/14/11 04:10 91-57-605/13/11 07:201990
Naphthalene ND ug/kg 1 05/14/11 04:10 91-20-305/13/11 07:201990
Phenanthrene ND ug/kg 1 05/14/11 04:10 85-01-805/13/11 07:201990
Pyrene ND ug/kg 1 05/14/11 04:10 129-00-005/13/11 07:201990
Nitrobenzene-d5 (S)74 %1 05/14/11 04:10 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)85 %1 05/14/11 04:10 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)100 %1 05/14/11 04:10 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 17.3 %1 05/13/11 09:360.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 7 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-4 Lab ID:9294023004 Collected:05/11/11 13:00 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 15.7 mg/kg 1 05/14/11 19:52 7440-47-305/13/11 15:450.52
Lead 3.0 mg/kg 1 05/14/11 19:52 7439-92-105/13/11 15:450.52
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 21:16 83-32-905/13/11 07:20344
Acenaphthylene ND ug/kg 1 05/13/11 21:16 208-96-805/13/11 07:20344
Anthracene ND ug/kg 1 05/13/11 21:16 120-12-705/13/11 07:20344
Benzo(a)anthracene ND ug/kg 1 05/13/11 21:16 56-55-305/13/11 07:20344
Benzo(a)pyrene ND ug/kg 1 05/13/11 21:16 50-32-805/13/11 07:20344
Benzo(b)fluoranthene ND ug/kg 1 05/13/11 21:16 205-99-205/13/11 07:20344
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 21:16 191-24-205/13/11 07:20344
Benzo(k)fluoranthene ND ug/kg 1 05/13/11 21:16 207-08-905/13/11 07:20344
Chrysene ND ug/kg 1 05/13/11 21:16 218-01-905/13/11 07:20344
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 21:16 53-70-305/13/11 07:20344
Fluoranthene ND ug/kg 1 05/13/11 21:16 206-44-005/13/11 07:20344
Fluorene ND ug/kg 1 05/13/11 21:16 86-73-705/13/11 07:20344
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 21:16 193-39-505/13/11 07:20344
1-Methylnaphthalene ND ug/kg 1 05/13/11 21:16 90-12-005/13/11 07:20344
2-Methylnaphthalene ND ug/kg 1 05/13/11 21:16 91-57-605/13/11 07:20344
Naphthalene ND ug/kg 1 05/13/11 21:16 91-20-305/13/11 07:20344
Phenanthrene ND ug/kg 1 05/13/11 21:16 85-01-805/13/11 07:20344
Pyrene ND ug/kg 1 05/13/11 21:16 129-00-005/13/11 07:20344
Nitrobenzene-d5 (S)55 %1 05/13/11 21:16 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)65 %1 05/13/11 21:16 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)84 %1 05/13/11 21:16 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 3.9 %1 05/13/11 09:360.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 8 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-5 Lab ID:9294023005 Collected:05/11/11 13:05 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 15.7 mg/kg 1 05/17/11 12:45 7440-47-305/16/11 14:450.65
Lead 6.4 mg/kg 1 05/17/11 12:45 7439-92-105/16/11 14:450.65
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 21:43 83-32-905/13/11 07:20431
Acenaphthylene ND ug/kg 1 05/13/11 21:43 208-96-805/13/11 07:20431
Anthracene ND ug/kg 1 05/13/11 21:43 120-12-705/13/11 07:20431
Benzo(a)anthracene ND ug/kg 1 05/13/11 21:43 56-55-305/13/11 07:20431
Benzo(a)pyrene ND ug/kg 1 05/13/11 21:43 50-32-805/13/11 07:20431
Benzo(b)fluoranthene ND ug/kg 1 05/13/11 21:43 205-99-205/13/11 07:20431
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 21:43 191-24-205/13/11 07:20431
Benzo(k)fluoranthene ND ug/kg 1 05/13/11 21:43 207-08-905/13/11 07:20431
Chrysene ND ug/kg 1 05/13/11 21:43 218-01-905/13/11 07:20431
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 21:43 53-70-305/13/11 07:20431
Fluoranthene ND ug/kg 1 05/13/11 21:43 206-44-005/13/11 07:20431
Fluorene ND ug/kg 1 05/13/11 21:43 86-73-705/13/11 07:20431
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 21:43 193-39-505/13/11 07:20431
1-Methylnaphthalene ND ug/kg 1 05/13/11 21:43 90-12-005/13/11 07:20431
2-Methylnaphthalene ND ug/kg 1 05/13/11 21:43 91-57-605/13/11 07:20431
Naphthalene ND ug/kg 1 05/13/11 21:43 91-20-305/13/11 07:20431
Phenanthrene ND ug/kg 1 05/13/11 21:43 85-01-805/13/11 07:20431
Pyrene ND ug/kg 1 05/13/11 21:43 129-00-005/13/11 07:20431
Nitrobenzene-d5 (S)58 %1 05/13/11 21:43 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)60 %1 05/13/11 21:43 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)78 %1 05/13/11 21:43 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 23.4 %1 05/13/11 09:360.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 9 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-6 Lab ID:9294023006 Collected:05/11/11 13:15 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 7.3 mg/kg 1 05/17/11 12:57 7440-47-305/16/11 14:450.64
Lead 17.6 mg/kg 1 05/17/11 12:57 7439-92-105/16/11 14:450.64
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 22:11 83-32-905/13/11 07:20438
Acenaphthylene ND ug/kg 1 05/13/11 22:11 208-96-805/13/11 07:20438
Anthracene ND ug/kg 1 05/13/11 22:11 120-12-705/13/11 07:20438
Benzo(a)anthracene ND ug/kg 1 05/13/11 22:11 56-55-305/13/11 07:20438
Benzo(a)pyrene ND ug/kg 1 05/13/11 22:11 50-32-805/13/11 07:20438
Benzo(b)fluoranthene ND ug/kg 1 05/13/11 22:11 205-99-205/13/11 07:20438
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 22:11 191-24-205/13/11 07:20438
Benzo(k)fluoranthene ND ug/kg 1 05/13/11 22:11 207-08-905/13/11 07:20438
Chrysene ND ug/kg 1 05/13/11 22:11 218-01-905/13/11 07:20438
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 22:11 53-70-305/13/11 07:20438
Fluoranthene ND ug/kg 1 05/13/11 22:11 206-44-005/13/11 07:20438
Fluorene ND ug/kg 1 05/13/11 22:11 86-73-705/13/11 07:20438
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 22:11 193-39-505/13/11 07:20438
1-Methylnaphthalene ND ug/kg 1 05/13/11 22:11 90-12-005/13/11 07:20438
2-Methylnaphthalene ND ug/kg 1 05/13/11 22:11 91-57-605/13/11 07:20438
Naphthalene ND ug/kg 1 05/13/11 22:11 91-20-305/13/11 07:20438
Phenanthrene ND ug/kg 1 05/13/11 22:11 85-01-805/13/11 07:20438
Pyrene ND ug/kg 1 05/13/11 22:11 129-00-005/13/11 07:20438
Nitrobenzene-d5 (S)46 %1 05/13/11 22:11 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)49 %1 05/13/11 22:11 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)75 %1 05/13/11 22:11 1718-51-005/13/11 07:2028-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 24.7 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 10 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-7 Lab ID:9294023007 Collected:05/11/11 13:25 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 10.0 mg/kg 1 05/17/11 13:07 7440-47-305/16/11 14:450.54
Lead 1.2 mg/kg 1 05/17/11 13:07 7439-92-105/16/11 14:450.54
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/13/11 22:39 83-32-905/13/11 07:20368
Acenaphthylene ND ug/kg 1 05/13/11 22:39 208-96-805/13/11 07:20368
Anthracene ND ug/kg 1 05/13/11 22:39 120-12-705/13/11 07:20368
Benzo(a)anthracene ND ug/kg 1 05/13/11 22:39 56-55-305/13/11 07:20368
Benzo(a)pyrene ND ug/kg 1 05/13/11 22:39 50-32-805/13/11 07:20368
Benzo(b)fluoranthene ND ug/kg 1 05/13/11 22:39 205-99-205/13/11 07:20368
Benzo(g,h,i)perylene ND ug/kg 1 05/13/11 22:39 191-24-205/13/11 07:20368
Benzo(k)fluoranthene ND ug/kg 1 05/13/11 22:39 207-08-905/13/11 07:20368
Chrysene ND ug/kg 1 05/13/11 22:39 218-01-905/13/11 07:20368
Dibenz(a,h)anthracene ND ug/kg 1 05/13/11 22:39 53-70-305/13/11 07:20368
Fluoranthene ND ug/kg 1 05/13/11 22:39 206-44-005/13/11 07:20368
Fluorene ND ug/kg 1 05/13/11 22:39 86-73-705/13/11 07:20368
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/13/11 22:39 193-39-505/13/11 07:20368
1-Methylnaphthalene ND ug/kg 1 05/13/11 22:39 90-12-005/13/11 07:20368
2-Methylnaphthalene ND ug/kg 1 05/13/11 22:39 91-57-605/13/11 07:20368
Naphthalene ND ug/kg 1 05/13/11 22:39 91-20-305/13/11 07:20368
Phenanthrene ND ug/kg 1 05/13/11 22:39 85-01-805/13/11 07:20368
Pyrene ND ug/kg 1 05/13/11 22:39 129-00-005/13/11 07:20368
Nitrobenzene-d5 (S)62 %1 05/13/11 22:39 4165-60-005/13/11 07:2023-110
2-Fluorobiphenyl (S)66 %1 05/13/11 22:39 321-60-805/13/11 07:2030-110
Terphenyl-d14 (S)84 %1 05/13/11 22:39 1718-51-005/13/11 07:2028-110
Phenol-d6 (S)55 %1 05/13/11 22:39 13127-88-305/13/11 07:2022-110
2-Fluorophenol (S)59 %1 05/13/11 22:39 367-12-405/13/11 07:2013-110
2,4,6-Tribromophenol (S)64 %1 05/13/11 22:39 118-79-605/13/11 07:2027-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 10.2 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 11 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-8 Lab ID:9294023008 Collected:05/11/11 13:30 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 8.5 mg/kg 1 05/17/11 13:22 7440-47-305/16/11 14:450.51
Lead 6.6 mg/kg 1 05/17/11 13:22 7439-92-105/16/11 14:450.51
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 10 05/17/11 13:54 83-32-905/14/11 10:3218500
Acenaphthylene ND ug/kg 10 05/17/11 13:54 208-96-805/14/11 10:3218500
Anthracene ND ug/kg 10 05/17/11 13:54 120-12-705/14/11 10:3218500
Benzo(a)anthracene ND ug/kg 10 05/17/11 13:54 56-55-305/14/11 10:3218500
Benzo(a)pyrene ND ug/kg 10 05/17/11 13:54 50-32-805/14/11 10:3218500
Benzo(b)fluoranthene ND ug/kg 10 05/17/11 13:54 205-99-205/14/11 10:3218500
Benzo(g,h,i)perylene ND ug/kg 10 05/17/11 13:54 191-24-205/14/11 10:3218500
Benzo(k)fluoranthene ND ug/kg 10 05/17/11 13:54 207-08-905/14/11 10:3218500
Chrysene ND ug/kg 10 05/17/11 13:54 218-01-905/14/11 10:3218500
Dibenz(a,h)anthracene ND ug/kg 10 05/17/11 13:54 53-70-305/14/11 10:3218500
Fluoranthene ND ug/kg 10 05/17/11 13:54 206-44-005/14/11 10:3218500
Fluorene ND ug/kg 10 05/17/11 13:54 86-73-705/14/11 10:3218500
Indeno(1,2,3-cd)pyrene ND ug/kg 10 05/17/11 13:54 193-39-505/14/11 10:3218500
1-Methylnaphthalene ND ug/kg 10 05/17/11 13:54 90-12-0 D3,P305/14/11 10:3218500
2-Methylnaphthalene ND ug/kg 10 05/17/11 13:54 91-57-605/14/11 10:3218500
Naphthalene ND ug/kg 10 05/17/11 13:54 91-20-305/14/11 10:3218500
Phenanthrene ND ug/kg 10 05/17/11 13:54 85-01-805/14/11 10:3218500
Pyrene ND ug/kg 10 05/17/11 13:54 129-00-005/14/11 10:3218500
Nitrobenzene-d5 (S)0 %10 05/17/11 13:54 4165-60-0 S405/14/11 10:3223-110
2-Fluorobiphenyl (S)0 %10 05/17/11 13:54 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)0 %10 05/17/11 13:54 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 10.8 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 12 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-9 Lab ID:9294023009 Collected:05/11/11 13:35 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 1.4 mg/kg 1 05/17/11 13:27 7440-47-305/16/11 14:450.57
Lead 0.98 mg/kg 1 05/17/11 13:27 7439-92-105/16/11 14:450.57
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/16/11 23:30 83-32-905/14/11 10:32401
Acenaphthylene ND ug/kg 1 05/16/11 23:30 208-96-805/14/11 10:32401
Anthracene ND ug/kg 1 05/16/11 23:30 120-12-705/14/11 10:32401
Benzo(a)anthracene ND ug/kg 1 05/16/11 23:30 56-55-305/14/11 10:32401
Benzo(a)pyrene ND ug/kg 1 05/16/11 23:30 50-32-805/14/11 10:32401
Benzo(b)fluoranthene ND ug/kg 1 05/16/11 23:30 205-99-205/14/11 10:32401
Benzo(g,h,i)perylene ND ug/kg 1 05/16/11 23:30 191-24-205/14/11 10:32401
Benzo(k)fluoranthene ND ug/kg 1 05/16/11 23:30 207-08-905/14/11 10:32401
Chrysene ND ug/kg 1 05/16/11 23:30 218-01-905/14/11 10:32401
Dibenz(a,h)anthracene ND ug/kg 1 05/16/11 23:30 53-70-305/14/11 10:32401
Fluoranthene ND ug/kg 1 05/16/11 23:30 206-44-005/14/11 10:32401
Fluorene ND ug/kg 1 05/16/11 23:30 86-73-705/14/11 10:32401
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/16/11 23:30 193-39-505/14/11 10:32401
1-Methylnaphthalene ND ug/kg 1 05/16/11 23:30 90-12-005/14/11 10:32401
2-Methylnaphthalene ND ug/kg 1 05/16/11 23:30 91-57-605/14/11 10:32401
Naphthalene ND ug/kg 1 05/16/11 23:30 91-20-305/14/11 10:32401
Phenanthrene ND ug/kg 1 05/16/11 23:30 85-01-805/14/11 10:32401
Pyrene ND ug/kg 1 05/16/11 23:30 129-00-005/14/11 10:32401
Nitrobenzene-d5 (S)50 %1 05/16/11 23:30 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)53 %1 05/16/11 23:30 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)61 %1 05/16/11 23:30 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 17.7 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 13 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-10 Lab ID:9294023010 Collected:05/11/11 13:45 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 7.5 mg/kg 1 05/17/11 13:31 7440-47-305/16/11 14:450.54
Lead 2.9 mg/kg 1 05/17/11 13:31 7439-92-105/16/11 14:450.54
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/16/11 23:58 83-32-905/14/11 10:32395
Acenaphthylene ND ug/kg 1 05/16/11 23:58 208-96-805/14/11 10:32395
Anthracene ND ug/kg 1 05/16/11 23:58 120-12-705/14/11 10:32395
Benzo(a)anthracene ND ug/kg 1 05/16/11 23:58 56-55-305/14/11 10:32395
Benzo(a)pyrene ND ug/kg 1 05/16/11 23:58 50-32-805/14/11 10:32395
Benzo(b)fluoranthene ND ug/kg 1 05/16/11 23:58 205-99-205/14/11 10:32395
Benzo(g,h,i)perylene ND ug/kg 1 05/16/11 23:58 191-24-205/14/11 10:32395
Benzo(k)fluoranthene ND ug/kg 1 05/16/11 23:58 207-08-905/14/11 10:32395
Chrysene ND ug/kg 1 05/16/11 23:58 218-01-905/14/11 10:32395
Dibenz(a,h)anthracene ND ug/kg 1 05/16/11 23:58 53-70-305/14/11 10:32395
Fluoranthene ND ug/kg 1 05/16/11 23:58 206-44-005/14/11 10:32395
Fluorene ND ug/kg 1 05/16/11 23:58 86-73-705/14/11 10:32395
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/16/11 23:58 193-39-505/14/11 10:32395
1-Methylnaphthalene ND ug/kg 1 05/16/11 23:58 90-12-005/14/11 10:32395
2-Methylnaphthalene ND ug/kg 1 05/16/11 23:58 91-57-605/14/11 10:32395
Naphthalene ND ug/kg 1 05/16/11 23:58 91-20-305/14/11 10:32395
Phenanthrene ND ug/kg 1 05/16/11 23:58 85-01-805/14/11 10:32395
Pyrene ND ug/kg 1 05/16/11 23:58 129-00-005/14/11 10:32395
Nitrobenzene-d5 (S)49 %1 05/16/11 23:58 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)63 %1 05/16/11 23:58 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)61 %1 05/16/11 23:58 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.4 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 14 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-11 Lab ID:9294023011 Collected:05/11/11 13:50 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 1.4 mg/kg 1 05/17/11 13:36 7440-47-305/16/11 14:450.44
Lead 2.7 mg/kg 1 05/17/11 13:36 7439-92-105/16/11 14:450.44
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 00:25 83-32-905/14/11 10:32385
Acenaphthylene ND ug/kg 1 05/17/11 00:25 208-96-805/14/11 10:32385
Anthracene ND ug/kg 1 05/17/11 00:25 120-12-705/14/11 10:32385
Benzo(a)anthracene ND ug/kg 1 05/17/11 00:25 56-55-305/14/11 10:32385
Benzo(a)pyrene ND ug/kg 1 05/17/11 00:25 50-32-805/14/11 10:32385
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 00:25 205-99-205/14/11 10:32385
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 00:25 191-24-205/14/11 10:32385
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 00:25 207-08-905/14/11 10:32385
Chrysene ND ug/kg 1 05/17/11 00:25 218-01-905/14/11 10:32385
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 00:25 53-70-305/14/11 10:32385
Fluoranthene ND ug/kg 1 05/17/11 00:25 206-44-005/14/11 10:32385
Fluorene ND ug/kg 1 05/17/11 00:25 86-73-705/14/11 10:32385
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 00:25 193-39-505/14/11 10:32385
1-Methylnaphthalene ND ug/kg 1 05/17/11 00:25 90-12-005/14/11 10:32385
2-Methylnaphthalene ND ug/kg 1 05/17/11 00:25 91-57-605/14/11 10:32385
Naphthalene ND ug/kg 1 05/17/11 00:25 91-20-305/14/11 10:32385
Phenanthrene ND ug/kg 1 05/17/11 00:25 85-01-805/14/11 10:32385
Pyrene ND ug/kg 1 05/17/11 00:25 129-00-005/14/11 10:32385
Nitrobenzene-d5 (S)46 %1 05/17/11 00:25 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)53 %1 05/17/11 00:25 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)65 %1 05/17/11 00:25 1718-51-005/14/11 10:3228-110
Phenol-d6 (S)41 %1 05/17/11 00:25 13127-88-305/14/11 10:3222-110
2-Fluorophenol (S)46 %1 05/17/11 00:25 367-12-405/14/11 10:3213-110
2,4,6-Tribromophenol (S)49 %1 05/17/11 00:25 118-79-605/14/11 10:3227-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.3 %1 05/13/11 09:380.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 15 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-12 Lab ID:9294023012 Collected:05/11/11 14:15 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 11.1 mg/kg 1 05/17/11 13:41 7440-47-305/16/11 14:450.48
Lead 6.6 mg/kg 1 05/17/11 13:41 7439-92-105/16/11 14:450.48
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 12:59 83-32-905/14/11 10:32381
Acenaphthylene ND ug/kg 1 05/17/11 12:59 208-96-805/14/11 10:32381
Anthracene ND ug/kg 1 05/17/11 12:59 120-12-705/14/11 10:32381
Benzo(a)anthracene ND ug/kg 1 05/17/11 12:59 56-55-305/14/11 10:32381
Benzo(a)pyrene ND ug/kg 1 05/17/11 12:59 50-32-805/14/11 10:32381
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 12:59 205-99-205/14/11 10:32381
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 12:59 191-24-205/14/11 10:32381
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 12:59 207-08-905/14/11 10:32381
Chrysene ND ug/kg 1 05/17/11 12:59 218-01-905/14/11 10:32381
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 12:59 53-70-305/14/11 10:32381
Fluoranthene ND ug/kg 1 05/17/11 12:59 206-44-005/14/11 10:32381
Fluorene ND ug/kg 1 05/17/11 12:59 86-73-705/14/11 10:32381
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 12:59 193-39-505/14/11 10:32381
1-Methylnaphthalene ND ug/kg 1 05/17/11 12:59 90-12-005/14/11 10:32381
2-Methylnaphthalene ND ug/kg 1 05/17/11 12:59 91-57-605/14/11 10:32381
Naphthalene ND ug/kg 1 05/17/11 12:59 91-20-305/14/11 10:32381
Phenanthrene ND ug/kg 1 05/17/11 12:59 85-01-805/14/11 10:32381
Pyrene ND ug/kg 1 05/17/11 12:59 129-00-005/14/11 10:32381
Nitrobenzene-d5 (S)54 %1 05/17/11 12:59 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)65 %1 05/17/11 12:59 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)73 %1 05/17/11 12:59 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.3 %1 05/13/11 09:370.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 16 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-13 Lab ID:9294023013 Collected:05/11/11 14:20 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 10.3 mg/kg 1 05/17/11 13:47 7440-47-305/16/11 14:450.55
Lead 4.1 mg/kg 1 05/17/11 13:47 7439-92-105/16/11 14:450.55
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 01:49 83-32-905/14/11 10:32383
Acenaphthylene ND ug/kg 1 05/17/11 01:49 208-96-805/14/11 10:32383
Anthracene ND ug/kg 1 05/17/11 01:49 120-12-705/14/11 10:32383
Benzo(a)anthracene ND ug/kg 1 05/17/11 01:49 56-55-305/14/11 10:32383
Benzo(a)pyrene ND ug/kg 1 05/17/11 01:49 50-32-805/14/11 10:32383
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 01:49 205-99-205/14/11 10:32383
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 01:49 191-24-205/14/11 10:32383
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 01:49 207-08-905/14/11 10:32383
Chrysene ND ug/kg 1 05/17/11 01:49 218-01-905/14/11 10:32383
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 01:49 53-70-305/14/11 10:32383
Fluoranthene ND ug/kg 1 05/17/11 01:49 206-44-005/14/11 10:32383
Fluorene ND ug/kg 1 05/17/11 01:49 86-73-705/14/11 10:32383
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 01:49 193-39-505/14/11 10:32383
1-Methylnaphthalene ND ug/kg 1 05/17/11 01:49 90-12-005/14/11 10:32383
2-Methylnaphthalene ND ug/kg 1 05/17/11 01:49 91-57-605/14/11 10:32383
Naphthalene ND ug/kg 1 05/17/11 01:49 91-20-305/14/11 10:32383
Phenanthrene ND ug/kg 1 05/17/11 01:49 85-01-805/14/11 10:32383
Pyrene ND ug/kg 1 05/17/11 01:49 129-00-005/14/11 10:32383
Nitrobenzene-d5 (S)46 %1 05/17/11 01:49 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)61 %1 05/17/11 01:49 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)67 %1 05/17/11 01:49 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.9 %1 05/13/11 14:330.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 17 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-14 Lab ID:9294023014 Collected:05/11/11 14:30 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 12.2 mg/kg 1 05/17/11 13:53 7440-47-305/16/11 14:450.52
Lead 13.5 mg/kg 1 05/17/11 13:53 7439-92-105/16/11 14:450.52
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 13:26 83-32-905/14/11 10:32385
Acenaphthylene ND ug/kg 1 05/17/11 13:26 208-96-805/14/11 10:32385
Anthracene ND ug/kg 1 05/17/11 13:26 120-12-705/14/11 10:32385
Benzo(a)anthracene ND ug/kg 1 05/17/11 13:26 56-55-305/14/11 10:32385
Benzo(a)pyrene ND ug/kg 1 05/17/11 13:26 50-32-805/14/11 10:32385
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 13:26 205-99-205/14/11 10:32385
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 13:26 191-24-205/14/11 10:32385
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 13:26 207-08-905/14/11 10:32385
Chrysene ND ug/kg 1 05/17/11 13:26 218-01-905/14/11 10:32385
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 13:26 53-70-305/14/11 10:32385
Fluoranthene ND ug/kg 1 05/17/11 13:26 206-44-005/14/11 10:32385
Fluorene ND ug/kg 1 05/17/11 13:26 86-73-705/14/11 10:32385
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 13:26 193-39-505/14/11 10:32385
1-Methylnaphthalene ND ug/kg 1 05/17/11 13:26 90-12-005/14/11 10:32385
2-Methylnaphthalene ND ug/kg 1 05/17/11 13:26 91-57-605/14/11 10:32385
Naphthalene ND ug/kg 1 05/17/11 13:26 91-20-305/14/11 10:32385
Phenanthrene ND ug/kg 1 05/17/11 13:26 85-01-805/14/11 10:32385
Pyrene ND ug/kg 1 05/17/11 13:26 129-00-005/14/11 10:32385
Nitrobenzene-d5 (S)49 %1 05/17/11 13:26 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)62 %1 05/17/11 13:26 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)63 %1 05/17/11 13:26 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.2 %1 05/13/11 14:350.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 18 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-15 Lab ID:9294023015 Collected:05/11/11 14:40 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 7.0 mg/kg 1 05/17/11 13:56 7440-47-305/16/11 14:450.53
Lead 2.4 mg/kg 1 05/17/11 13:56 7439-92-105/16/11 14:450.53
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 11:08 83-32-905/14/11 10:32359
Acenaphthylene ND ug/kg 1 05/17/11 11:08 208-96-805/14/11 10:32359
Anthracene ND ug/kg 1 05/17/11 11:08 120-12-705/14/11 10:32359
Benzo(a)anthracene ND ug/kg 1 05/17/11 11:08 56-55-305/14/11 10:32359
Benzo(a)pyrene ND ug/kg 1 05/17/11 11:08 50-32-805/14/11 10:32359
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 11:08 205-99-205/14/11 10:32359
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 11:08 191-24-205/14/11 10:32359
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 11:08 207-08-905/14/11 10:32359
Chrysene ND ug/kg 1 05/17/11 11:08 218-01-905/14/11 10:32359
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 11:08 53-70-305/14/11 10:32359
Fluoranthene ND ug/kg 1 05/17/11 11:08 206-44-005/14/11 10:32359
Fluorene ND ug/kg 1 05/17/11 11:08 86-73-705/14/11 10:32359
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 11:08 193-39-505/14/11 10:32359
1-Methylnaphthalene ND ug/kg 1 05/17/11 11:08 90-12-005/14/11 10:32359
2-Methylnaphthalene ND ug/kg 1 05/17/11 11:08 91-57-605/14/11 10:32359
Naphthalene ND ug/kg 1 05/17/11 11:08 91-20-305/14/11 10:32359
Phenanthrene ND ug/kg 1 05/17/11 11:08 85-01-805/14/11 10:32359
Pyrene ND ug/kg 1 05/17/11 11:08 129-00-005/14/11 10:32359
Nitrobenzene-d5 (S)43 %1 05/17/11 11:08 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)52 %1 05/17/11 11:08 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)68 %1 05/17/11 11:08 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 8.2 %1 05/13/11 14:350.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 19 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-16 Lab ID:9294023016 Collected:05/11/11 14:45 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 16.0 mg/kg 1 05/17/11 14:00 7440-47-305/16/11 14:450.47
Lead 12.1 mg/kg 1 05/17/11 14:00 7439-92-105/16/11 14:450.47
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 12:04 83-32-905/14/11 10:32387
Acenaphthylene ND ug/kg 1 05/17/11 12:04 208-96-805/14/11 10:32387
Anthracene ND ug/kg 1 05/17/11 12:04 120-12-705/14/11 10:32387
Benzo(a)anthracene ND ug/kg 1 05/17/11 12:04 56-55-305/14/11 10:32387
Benzo(a)pyrene ND ug/kg 1 05/17/11 12:04 50-32-805/14/11 10:32387
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 12:04 205-99-205/14/11 10:32387
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 12:04 191-24-205/14/11 10:32387
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 12:04 207-08-905/14/11 10:32387
Chrysene ND ug/kg 1 05/17/11 12:04 218-01-905/14/11 10:32387
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 12:04 53-70-305/14/11 10:32387
Fluoranthene ND ug/kg 1 05/17/11 12:04 206-44-005/14/11 10:32387
Fluorene ND ug/kg 1 05/17/11 12:04 86-73-705/14/11 10:32387
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 12:04 193-39-505/14/11 10:32387
1-Methylnaphthalene ND ug/kg 1 05/17/11 12:04 90-12-005/14/11 10:32387
2-Methylnaphthalene ND ug/kg 1 05/17/11 12:04 91-57-605/14/11 10:32387
Naphthalene ND ug/kg 1 05/17/11 12:04 91-20-305/14/11 10:32387
Phenanthrene ND ug/kg 1 05/17/11 12:04 85-01-805/14/11 10:32387
Pyrene ND ug/kg 1 05/17/11 12:04 129-00-005/14/11 10:32387
Nitrobenzene-d5 (S)58 %1 05/17/11 12:04 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)66 %1 05/17/11 12:04 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)80 %1 05/17/11 12:04 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.8 %1 05/13/11 14:350.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 20 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294023
THE PROVINCE
Sample:PCS-17 Lab ID:9294023017 Collected:05/11/11 14:55 Received:05/12/11 08:20 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 14.9 mg/kg 1 05/17/11 14:05 7440-47-305/16/11 14:450.49
Lead 10.5 mg/kg 1 05/17/11 14:05 7439-92-105/16/11 14:450.49
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 05/17/11 12:31 83-32-905/14/11 10:32417
Acenaphthylene ND ug/kg 1 05/17/11 12:31 208-96-805/14/11 10:32417
Anthracene ND ug/kg 1 05/17/11 12:31 120-12-705/14/11 10:32417
Benzo(a)anthracene ND ug/kg 1 05/17/11 12:31 56-55-305/14/11 10:32417
Benzo(a)pyrene ND ug/kg 1 05/17/11 12:31 50-32-805/14/11 10:32417
Benzo(b)fluoranthene ND ug/kg 1 05/17/11 12:31 205-99-205/14/11 10:32417
Benzo(g,h,i)perylene ND ug/kg 1 05/17/11 12:31 191-24-205/14/11 10:32417
Benzo(k)fluoranthene ND ug/kg 1 05/17/11 12:31 207-08-905/14/11 10:32417
Chrysene ND ug/kg 1 05/17/11 12:31 218-01-905/14/11 10:32417
Dibenz(a,h)anthracene ND ug/kg 1 05/17/11 12:31 53-70-305/14/11 10:32417
Fluoranthene ND ug/kg 1 05/17/11 12:31 206-44-005/14/11 10:32417
Fluorene ND ug/kg 1 05/17/11 12:31 86-73-705/14/11 10:32417
Indeno(1,2,3-cd)pyrene ND ug/kg 1 05/17/11 12:31 193-39-505/14/11 10:32417
1-Methylnaphthalene ND ug/kg 1 05/17/11 12:31 90-12-005/14/11 10:32417
2-Methylnaphthalene ND ug/kg 1 05/17/11 12:31 91-57-605/14/11 10:32417
Naphthalene ND ug/kg 1 05/17/11 12:31 91-20-305/14/11 10:32417
Phenanthrene ND ug/kg 1 05/17/11 12:31 85-01-805/14/11 10:32417
Pyrene ND ug/kg 1 05/17/11 12:31 129-00-005/14/11 10:32417
Nitrobenzene-d5 (S)58 %1 05/17/11 12:31 4165-60-005/14/11 10:3223-110
2-Fluorobiphenyl (S)62 %1 05/17/11 12:31 321-60-805/14/11 10:3230-110
Terphenyl-d14 (S)78 %1 05/17/11 12:31 1718-51-005/14/11 10:3228-110
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 20.9 %1 05/13/11 14:350.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 21 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/8363
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:9294023001, 9294023002, 9294023003, 9294023004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:606037
Associated Lab Samples:9294023001, 9294023002, 9294023003, 9294023004
Matrix:Solid
Analyzed
Chromium mg/kg ND 0.50 05/14/11 18:08
Lead mg/kg ND 0.50 05/14/11 18:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
606038LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium mg/kg 48.550 97 80-120
Lead mg/kg 49.350 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
606214MATRIX SPIKE SAMPLE:
MSSpike
Result
9293846001
Chromium mg/kg 49.343.9 95 75-1257.6
Lead mg/kg 44.243.9 87 75-1256.0
Parameter Units
Dup
Result QualifiersRPDResult
9293846002
606215SAMPLE DUPLICATE:
Chromium mg/kg 29.4 428.1
Lead mg/kg 12.7 1014.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 22 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/8365
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:9294023005, 9294023006, 9294023007, 9294023008, 9294023009, 9294023010, 9294023011, 9294023012,
9294023013, 9294023014, 9294023015, 9294023016, 9294023017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:606047
Associated Lab Samples:9294023005, 9294023006, 9294023007, 9294023008, 9294023009, 9294023010, 9294023011, 9294023012,
9294023013, 9294023014, 9294023015, 9294023016, 9294023017
Matrix:Solid
Analyzed
Chromium mg/kg ND 0.50 05/17/11 12:38
Lead mg/kg ND 0.50 05/17/11 12:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
606048LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium mg/kg 50.350 101 80-120
Lead mg/kg 50.150 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
606049MATRIX SPIKE SAMPLE:
MSSpike
Result
9294023005
Chromium mg/kg 70.964 86 75-12515.7
Lead mg/kg 53.4 M0647375-1256.4
Parameter Units
Dup
Result QualifiersRPDResult
9294023006
606050SAMPLE DUPLICATE:
Chromium mg/kg 5.4 R1307.3
Lead mg/kg 4.4 R112017.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 23 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/13575
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9294023001, 9294023002, 9294023003, 9294023004, 9294023005, 9294023006, 9294023007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:605823
Associated Lab Samples:9294023001, 9294023002, 9294023003, 9294023004, 9294023005, 9294023006, 9294023007
Matrix:Solid
Analyzed
1-Methylnaphthalene ug/kg ND 330 05/13/11 17:31
2-Methylnaphthalene ug/kg ND 330 05/13/11 17:31
Acenaphthene ug/kg ND 330 05/13/11 17:31
Acenaphthylene ug/kg ND 330 05/13/11 17:31
Anthracene ug/kg ND 330 05/13/11 17:31
Benzo(a)anthracene ug/kg ND 330 05/13/11 17:31
Benzo(a)pyrene ug/kg ND 330 05/13/11 17:31
Benzo(b)fluoranthene ug/kg ND 330 05/13/11 17:31
Benzo(g,h,i)perylene ug/kg ND 330 05/13/11 17:31
Benzo(k)fluoranthene ug/kg ND 330 05/13/11 17:31
Chrysene ug/kg ND 330 05/13/11 17:31
Dibenz(a,h)anthracene ug/kg ND 330 05/13/11 17:31
Fluoranthene ug/kg ND 330 05/13/11 17:31
Fluorene ug/kg ND 330 05/13/11 17:31
Indeno(1,2,3-cd)pyrene ug/kg ND 330 05/13/11 17:31
Naphthalene ug/kg ND 330 05/13/11 17:31
Phenanthrene ug/kg ND 330 05/13/11 17:31
Pyrene ug/kg ND 330 05/13/11 17:31
2,4,6-Tribromophenol (S)%75 27-110 05/13/11 17:31
2-Fluorobiphenyl (S)%76 30-110 05/13/11 17:31
2-Fluorophenol (S)%65 13-110 05/13/11 17:31
Nitrobenzene-d5 (S)%70 23-110 05/13/11 17:31
Phenol-d6 (S)%60 22-110 05/13/11 17:31
Terphenyl-d14 (S)%97 28-110 05/13/11 17:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
605824LABORATORY CONTROL SAMPLE:
LCSSpike
1-Methylnaphthalene ug/kg 11301670 68 45-105
2-Methylnaphthalene ug/kg 10701670 64 39-112
Acenaphthene ug/kg 13401670 81 38-117
Acenaphthylene ug/kg 12801670 77 46-107
Anthracene ug/kg 13501670 81 50-110
Benzo(a)anthracene ug/kg 12901670 78 47-116
Benzo(a)pyrene ug/kg 11801670 71 47-106
Benzo(b)fluoranthene ug/kg 12301670 74 47-109
Benzo(g,h,i)perylene ug/kg 11601670 70 39-115
Benzo(k)fluoranthene ug/kg 13401670 80 45-117
Chrysene ug/kg 13201670 79 49-110
Dibenz(a,h)anthracene ug/kg 11601670 70 43-116
Fluoranthene ug/kg 11901670 71 50-114
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 24 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
605824LABORATORY CONTROL SAMPLE:
LCSSpike
Fluorene ug/kg 13401670 80 46-114
Indeno(1,2,3-cd)pyrene ug/kg 11601670 69 42-115
Naphthalene ug/kg 11401670 68 41-110
Phenanthrene ug/kg 13101670 78 50-110
Pyrene ug/kg 15201670 91 45-114
2,4,6-Tribromophenol (S)%80 27-110
2-Fluorobiphenyl (S)%75 30-110
2-Fluorophenol (S)%66 13-110
Nitrobenzene-d5 (S)%69 23-110
Phenol-d6 (S)%60 22-110
Terphenyl-d14 (S)%92 28-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
605825MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9294023007
605826
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1-Methylnaphthalene ug/kg 1860 68 24-11678 141860ND12601450
2-Methylnaphthalene ug/kg 1860 64 10-13574 141860ND12001380
Acenaphthene ug/kg 1860 78 26-11486 101860ND14501600
Acenaphthylene ug/kg 1860 75 32-10883 91860ND13901530
Anthracene ug/kg 1860 77 32-11185 101860ND14301580
Benzo(a)anthracene ug/kg 1860 68 25-11782 191860ND12601510
Benzo(a)pyrene ug/kg 1860 61 25-10672 161860ND11401330
Benzo(b)fluoranthene ug/kg 1860 64 24-11075 151860ND11901380
Benzo(g,h,i)perylene ug/kg 1860 67 19-11277 131860ND12501420
Benzo(k)fluoranthene ug/kg 1860 69 24-11480 141860ND12801480
Chrysene ug/kg 1860 68 30-11081 171860ND12701500
Dibenz(a,h)anthracene ug/kg 1860 64 23-11176 171860ND11901410
Fluoranthene ug/kg 1860 65 33-10978 181860ND12001440
Fluorene ug/kg 1860 75 32-11384 111860ND14001560
Indeno(1,2,3-cd)pyrene ug/kg 1860 64 10-12275 161860ND11901390
Naphthalene ug/kg 1860 68 25-11077 121860ND12701430
Phenanthrene ug/kg 1860 74 30-11482 101860ND13801530
Pyrene ug/kg 1860 85 25-11690 61860ND15801670
2,4,6-Tribromophenol (S)%78 27-11088
2-Fluorobiphenyl (S)%74 30-11081
2-Fluorophenol (S)%64 13-11073
Nitrobenzene-d5 (S)%67 23-11076
Phenol-d6 (S)%60 22-11070
Terphenyl-d14 (S)%79 28-11085
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 25 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/13593
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9294023008, 9294023009, 9294023010, 9294023011, 9294023012, 9294023013, 9294023014, 9294023015,
9294023016, 9294023017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:606558
Associated Lab Samples:9294023008, 9294023009, 9294023010, 9294023011, 9294023012, 9294023013, 9294023014, 9294023015,
9294023016, 9294023017
Matrix:Solid
Analyzed
1-Methylnaphthalene ug/kg ND 330 05/16/11 22:35
2-Methylnaphthalene ug/kg ND 330 05/16/11 22:35
Acenaphthene ug/kg ND 330 05/16/11 22:35
Acenaphthylene ug/kg ND 330 05/16/11 22:35
Anthracene ug/kg ND 330 05/16/11 22:35
Benzo(a)anthracene ug/kg ND 330 05/16/11 22:35
Benzo(a)pyrene ug/kg ND 330 05/16/11 22:35
Benzo(b)fluoranthene ug/kg ND 330 05/16/11 22:35
Benzo(g,h,i)perylene ug/kg ND 330 05/16/11 22:35
Benzo(k)fluoranthene ug/kg ND 330 05/16/11 22:35
Chrysene ug/kg ND 330 05/16/11 22:35
Dibenz(a,h)anthracene ug/kg ND 330 05/16/11 22:35
Fluoranthene ug/kg ND 330 05/16/11 22:35
Fluorene ug/kg ND 330 05/16/11 22:35
Indeno(1,2,3-cd)pyrene ug/kg ND 330 05/16/11 22:35
Naphthalene ug/kg ND 330 05/16/11 22:35
Phenanthrene ug/kg ND 330 05/16/11 22:35
Pyrene ug/kg ND 330 05/16/11 22:35
2,4,6-Tribromophenol (S)%55 27-110 05/16/11 22:35
2-Fluorobiphenyl (S)%68 30-110 05/16/11 22:35
2-Fluorophenol (S)%62 13-110 05/16/11 22:35
Nitrobenzene-d5 (S)%63 23-110 05/16/11 22:35
Phenol-d6 (S)%55 22-110 05/16/11 22:35
Terphenyl-d14 (S)%79 28-110 05/16/11 22:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
606559LABORATORY CONTROL SAMPLE:
LCSSpike
1-Methylnaphthalene ug/kg 9981670 60 45-105
2-Methylnaphthalene ug/kg 9351670 56 39-112
Acenaphthene ug/kg 11401670 68 38-117
Acenaphthylene ug/kg 10701670 64 46-107
Anthracene ug/kg 11501670 69 50-110
Benzo(a)anthracene ug/kg 10901670 65 47-116
Benzo(a)pyrene ug/kg 10101670 60 47-106
Benzo(b)fluoranthene ug/kg 10401670 63 47-109
Benzo(g,h,i)perylene ug/kg 10601670 64 39-115
Benzo(k)fluoranthene ug/kg 11201670 67 45-117
Chrysene ug/kg 11001670 66 49-110
Dibenz(a,h)anthracene ug/kg 10301670 62 43-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 26 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
606559LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoranthene ug/kg 11001670 66 50-114
Fluorene ug/kg 12401670 74 46-114
Indeno(1,2,3-cd)pyrene ug/kg 10301670 62 42-115
Naphthalene ug/kg 10301670 62 41-110
Phenanthrene ug/kg 11201670 67 50-110
Pyrene ug/kg 12001670 72 45-114
2,4,6-Tribromophenol (S)%65 27-110
2-Fluorobiphenyl (S)%61 30-110
2-Fluorophenol (S)%61 13-110
Nitrobenzene-d5 (S)%63 23-110
Phenol-d6 (S)%55 22-110
Terphenyl-d14 (S)%74 28-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
606560MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9294023011
606561
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1-Methylnaphthalene ug/kg 1950 59 24-11659 11950ND11501140
2-Methylnaphthalene ug/kg 1950 56 10-13555 21950ND10801060
Acenaphthene ug/kg 1950 67 26-11467 11950ND13001310
Acenaphthylene ug/kg 1950 63 32-10863 01950ND12301230
Anthracene ug/kg 1950 65 32-11166 11950ND12601280
Benzo(a)anthracene ug/kg 1950 56 25-11761 81950ND11001190
Benzo(a)pyrene ug/kg 1950 50 25-10655 91950ND9721070
Benzo(b)fluoranthene ug/kg 1950 50 24-11055 101950ND9721070
Benzo(g,h,i)perylene ug/kg 1950 52 19-11259 141950ND10101150
Benzo(k)fluoranthene ug/kg 1950 55 24-11461 111950ND10701200
Chrysene ug/kg 1950 58 30-11062 71950ND11201200
Dibenz(a,h)anthracene ug/kg 1950 51 23-11155 81950ND9861070
Fluoranthene ug/kg 1950 57 33-10963 101950ND11101220
Fluorene ug/kg 1950 66 32-11369 41950ND12801340
Indeno(1,2,3-cd)pyrene ug/kg 1950 50 10-12257 121950ND9811100
Naphthalene ug/kg 1950 57 25-11056 21950ND11201100
Phenanthrene ug/kg 1950 63 30-11464 21950ND12301250
Pyrene ug/kg 1950 69 25-11668 11950ND13401320
2,4,6-Tribromophenol (S)%62 27-11060
2-Fluorobiphenyl (S)%58 30-11058
2-Fluorophenol (S)%57 13-11051
Nitrobenzene-d5 (S)%58 23-11054
Phenol-d6 (S)%52 22-11048
Terphenyl-d14 (S)%62 28-11064
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 27 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3922
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9294023001, 9294023002, 9294023003, 9294023004, 9294023005, 9294023006, 9294023007, 9294023008,
9294023009, 9294023010, 9294023011, 9294023012
Parameter Units
Dup
Result QualifiersRPDResult
9294023011
605353SAMPLE DUPLICATE:
Percent Moisture %13.8 314.3
Parameter Units
Dup
Result QualifiersRPDResult
9293071001
605365SAMPLE DUPLICATE:
Percent Moisture %36.3 337.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 28 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294023
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3923
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9294023013, 9294023014, 9294023015, 9294023016, 9294023017
Parameter Units
Dup
Result QualifiersRPDResult
9294020001
605473SAMPLE DUPLICATE:
Percent Moisture %12.5 112.6
Parameter Units
Dup
Result QualifiersRPDResult
9294023013
605517SAMPLE DUPLICATE:
Percent Moisture %13.2 513.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 29 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
9294023
THE PROVINCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Sample extract could not be concentrated to the routine final volume, resulting in elevated reporting limits.P3
RPD value was outside control limits.R1
Surrogate recovery not evaluated against control limits due to sample dilution.S4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 30 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9294023
THE PROVINCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9294023001 MPRP/8363 ICP/7725PCS-1 EPA 3050 EPA 6010
9294023002 MPRP/8363 ICP/7725PCS-2 EPA 3050 EPA 6010
9294023003 MPRP/8363 ICP/7725PCS-3 EPA 3050 EPA 6010
9294023004 MPRP/8363 ICP/7725PCS-4 EPA 3050 EPA 6010
9294023005 MPRP/8365 ICP/7743PCS-5 EPA 3050 EPA 6010
9294023006 MPRP/8365 ICP/7743PCS-6 EPA 3050 EPA 6010
9294023007 MPRP/8365 ICP/7743PCS-7 EPA 3050 EPA 6010
9294023008 MPRP/8365 ICP/7743PCS-8 EPA 3050 EPA 6010
9294023009 MPRP/8365 ICP/7743PCS-9 EPA 3050 EPA 6010
9294023010 MPRP/8365 ICP/7743PCS-10 EPA 3050 EPA 6010
9294023011 MPRP/8365 ICP/7743PCS-11 EPA 3050 EPA 6010
9294023012 MPRP/8365 ICP/7743PCS-12 EPA 3050 EPA 6010
9294023013 MPRP/8365 ICP/7743PCS-13 EPA 3050 EPA 6010
9294023014 MPRP/8365 ICP/7743PCS-14 EPA 3050 EPA 6010
9294023015 MPRP/8365 ICP/7743PCS-15 EPA 3050 EPA 6010
9294023016 MPRP/8365 ICP/7743PCS-16 EPA 3050 EPA 6010
9294023017 MPRP/8365 ICP/7743PCS-17 EPA 3050 EPA 6010
9294023001 OEXT/13575 MSSV/4922PCS-1 EPA 3546 EPA 8270
9294023002 OEXT/13575 MSSV/4922PCS-2 EPA 3546 EPA 8270
9294023003 OEXT/13575 MSSV/4922PCS-3 EPA 3546 EPA 8270
9294023004 OEXT/13575 MSSV/4922PCS-4 EPA 3546 EPA 8270
9294023005 OEXT/13575 MSSV/4922PCS-5 EPA 3546 EPA 8270
9294023006 OEXT/13575 MSSV/4922PCS-6 EPA 3546 EPA 8270
9294023007 OEXT/13575 MSSV/4922PCS-7 EPA 3546 EPA 8270
9294023008 OEXT/13593 MSSV/4935PCS-8 EPA 3546 EPA 8270
9294023009 OEXT/13593 MSSV/4935PCS-9 EPA 3546 EPA 8270
9294023010 OEXT/13593 MSSV/4935PCS-10 EPA 3546 EPA 8270
9294023011 OEXT/13593 MSSV/4935PCS-11 EPA 3546 EPA 8270
9294023012 OEXT/13593 MSSV/4935PCS-12 EPA 3546 EPA 8270
9294023013 OEXT/13593 MSSV/4935PCS-13 EPA 3546 EPA 8270
9294023014 OEXT/13593 MSSV/4935PCS-14 EPA 3546 EPA 8270
9294023015 OEXT/13593 MSSV/4935PCS-15 EPA 3546 EPA 8270
9294023016 OEXT/13593 MSSV/4935PCS-16 EPA 3546 EPA 8270
9294023017 OEXT/13593 MSSV/4935PCS-17 EPA 3546 EPA 8270
9294023001 PMST/3922PCS-1 ASTM D2974-87
9294023002 PMST/3922PCS-2 ASTM D2974-87
9294023003 PMST/3922PCS-3 ASTM D2974-87
9294023004 PMST/3922PCS-4 ASTM D2974-87
9294023005 PMST/3922PCS-5 ASTM D2974-87
9294023006 PMST/3922PCS-6 ASTM D2974-87
9294023007 PMST/3922PCS-7 ASTM D2974-87
9294023008 PMST/3922PCS-8 ASTM D2974-87
9294023009 PMST/3922PCS-9 ASTM D2974-87
9294023010 PMST/3922PCS-10 ASTM D2974-87
9294023011 PMST/3922PCS-11 ASTM D2974-87
9294023012 PMST/3922PCS-12 ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 31 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9294023
THE PROVINCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9294023013 PMST/3923PCS-13 ASTM D2974-87
9294023014 PMST/3923PCS-14 ASTM D2974-87
9294023015 PMST/3923PCS-15 ASTM D2974-87
9294023016 PMST/3923PCS-16 ASTM D2974-87
9294023017 PMST/3923PCS-17 ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/17/2011 03:57 PM Page 32 of 32
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
May 31, 2011
LIMS USE: FR - STEPHEN BROWN
LIMS OBJECT ID: 9294953
9294953
Project:
Pace Project No.:
RE:
Mr. Stephen Brown
Terracon
2020 E Starita Road
Charlotte, NC 28206
THE PROVINCE
Dear Mr. Brown:
Enclosed are the analytical results for sample(s) received by the laboratory on May 25, 2011. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9294953
THE PROVINCE
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078Louisiana/LELAP Certification #: 04034
New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003Virginia Certification #: 00213
Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana DHH Drinking Water # LA 100031West Virginia Certification #: 357
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804Connecticut Certification #: PH-0106Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030New Jersey Certification #: NC011
North Carolina Bioassay Certification #: 9North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 99030002
South Carolina Certification #: 99030001Virginia Certification #: 00072
West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9294953
THE PROVINCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9294953001 PCS-1A EPA 6010 1 PASI-AJMW
ASTM D2974-87 1 PASI-CTNM
9294953002 PCS-1B EPA 6010 1 PASI-AJMW
ASTM D2974-87 1 PASI-CTNM
9294953003 PCS-1C EPA 6010 1 PASI-AJMW
ASTM D2974-87 1 PASI-CTNM
9294953004 PCS-1D EPA 6010 1 PASI-AJMW
ASTM D2974-87 1 PASI-CTNM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294953
THE PROVINCE
Sample:PCS-1A Lab ID:9294953001 Collected:05/25/11 14:50 Received:05/25/11 16:50 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 33.3 mg/kg 1 05/26/11 18:39 7440-47-305/26/11 11:000.55
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.4 %1 05/26/11 08:300.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 4 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294953
THE PROVINCE
Sample:PCS-1B Lab ID:9294953002 Collected:05/25/11 15:00 Received:05/25/11 16:50 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 16.6 mg/kg 1 05/26/11 18:45 7440-47-305/26/11 11:000.52
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.7 %1 05/26/11 08:300.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 5 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294953
THE PROVINCE
Sample:PCS-1C Lab ID:9294953003 Collected:05/25/11 15:05 Received:05/25/11 16:50 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 15.3 mg/kg 1 05/26/11 18:51 7440-47-305/26/11 11:000.47
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.0 %1 05/26/11 08:300.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 6 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9294953
THE PROVINCE
Sample:PCS-1D Lab ID:9294953004 Collected:05/25/11 15:15 Received:05/25/11 16:50 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Chromium 16.4 mg/kg 1 05/26/11 18:56 7440-47-305/26/11 11:000.54
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 11.2 %1 05/26/11 08:310.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 7 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294953
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/8446
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:9294953001, 9294953002, 9294953003, 9294953004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:611652
Associated Lab Samples:9294953001, 9294953002, 9294953003, 9294953004
Matrix:Solid
Analyzed
Chromium mg/kg ND 0.50 05/26/11 17:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
611653LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium mg/kg 48.050 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
611668MATRIX SPIKE SAMPLE:
MSSpike
Result
9294811001
Chromium mg/kg 50.753.2 88 75-1254.0
Parameter Units
Dup
Result QualifiersRPDResult
9294811002
611669SAMPLE DUPLICATE:
Chromium mg/kg 1.4 R1231.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 8 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9294953
THE PROVINCE
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3947
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9294953001, 9294953002, 9294953003, 9294953004
Parameter Units
Dup
Result QualifiersRPDResult
9294629001
611520SAMPLE DUPLICATE:
Percent Moisture %13.9 314.3
Parameter Units
Dup
Result QualifiersRPDResult
9294833004
611521SAMPLE DUPLICATE:
Percent Moisture %5.0 105.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 9 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
9294953
THE PROVINCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 10 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9294953
THE PROVINCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9294953001 MPRP/8446 ICP/7803PCS-1A EPA 3050 EPA 6010
9294953002 MPRP/8446 ICP/7803PCS-1B EPA 3050 EPA 6010
9294953003 MPRP/8446 ICP/7803PCS-1C EPA 3050 EPA 6010
9294953004 MPRP/8446 ICP/7803PCS-1D EPA 3050 EPA 6010
9294953001 PMST/3947PCS-1A ASTM D2974-87
9294953002 PMST/3947PCS-1B ASTM D2974-87
9294953003 PMST/3947PCS-1C ASTM D2974-87
9294953004 PMST/3947PCS-1D ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/31/2011 01:32 PM Page 11 of 11
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]