9606_WayneCountySubtitleD_GWMR_DIN28168_20160302

Wayne County Subtitle D Lined MSWLF
Dudley, North Carolina
March 2016
MESCO Project Number: G15016.0
Semi-Annual Water Quality Monitoring Report
Prepared for
Municipal Engineering Services Company, P.A.
Garner and Boone, North Carolina
P.O. Box 97
Garner, NC 27529
License No. C-0281

Permit Number: 96-06
TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedures Page 2
Field Parameter Data Page 2
Laboratory Results Page 2
Quality Control Samples Page 2
Groundwater Samples Above Standards Page 2
Surface Water Samples Above Standards Page 3
Leachate Samples Page 3
Groundwater and Surface Water Characterization Page 3
Findings Page 3
Closing Page 4
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer Figure 2
TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Detections Above SWSL, GWP, 2L, or 2B (Appendix 1) Table 5
Detections in Leachate Samples above SWSL, GWP or 2L Table 6
Hydrologic Properties at Monitoring Well Locations Table 7
APPENDICIES
Laboratory Analysis Report and Chains of Custody Appendix A
Field Sampling Parameter Data Sheet(s) Appendix B
August 5, 2016
Ms. Jaclynne Drummond
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality
2090 US 70 Highway
Swannanoa, NC 28778
Re: Semi-Annual Water Quality Monitoring Report
Wayne County Subtitle D Lined MSWLF
Permit No. 96-06
MESCO Project No. G15016.0
Event Date(s): March 2-3, 2016
Introduction
On behalf of Wayne County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this
Semi-Annual Water Quality Report for the winter 2016 event performed at the Wayne County Subtitle D Lined
Municipal Solid Waste Landfill (MSWLF). NCDENR Solid Waste Rules 15A NCAC 13B.1632 require that Wayne
County provide this report to the NC SWS on a semi-annual basis. This report documents the quality of the
groundwater, surface waters and leachate during the monitoring event performed on March 2-3, 2016.
During this event total cadmium was detected in most of the groundwater samples with five above 2L Groundwater
Standards including the background well. Preliminary source assigned to the metal detections is erosion of natural
deposits. Benzene was detected above the 2L Standard in sample MW-13 for the second consecutive event. The
preliminary source of benzene is likely anthropogenic. No constituents were detected above established applicable
regulatory compliance Standards in any surface water sample. Contaminants in the untreated leachate samples were
low relative to Standards and published values.
Background
The Wayne County Subtitle D lined MSWLF, permit #96-06 (Phases 1-3), is located at 460-B South Landfill Road,
Dudley, Wayne County, North Carolina. The lined MSWLF is comprised of contiguous Phases 1, 2 & 3 which
are treated as a single unit in this report. Phase 3 was granted a Permit to Operate (PTO) on June 11, 2013 and at the
time of this event waste had been placed upon most of the liner encompassing both the east and west sumps.
The lined landfill is located west and beyond a perennial local discharge feature from a C&D landfill operating upon
an unlined landfill which is monitored separately under Permit #96-01. The site location topographic map is
depicted in the attached Figure 1.
Water quality at this facility has been monitored at least semi-annually including several pre-operation baseline
events with complete historical data available since prior to operation of Phase 1 in 1997. This event was performed
in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the
permit to operate.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water
characterization. Well construction summary table, field observations table, field parameter data table, sampling
and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table,
potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein.

Sampling Procedure
Samples were collected in accordance with the Ground and Surface Water Sampling & Analysis Plan (SAP) [DIN
13717] dated April 25, 2011 and approved by the SWS on May 19, 2011 [DIN 13957]. The site specific SAP
includes water sample collection and analysis from twelve downgradient monitoring wells (MW-2 through MW-
16R), one background well (MW-1), four surface water locations (SW-2, SW-3, SW-4 and SW-5) and a leachate
sample (LE-1). Surface water point SW-1, located downstream of SW-3, monitors the unnamed tributary of
Edward's Branch as part of the separate SAP for the adjacent Active C&D and Closed MSWLF. Results of SW-1
are also presented in this report due to the shared discharge features. Quality control measures, which included
analysis of equipment blank samples (EB), field blank samples (FB), and trip blank samples (TB) were also
reported. Monitoring locations are depicted on the potentiometric map of the uppermost aquifer, Figure 2.
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and
integrity of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table
2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level
elevation. Low-flow pumping methodology or bailing was used to adequately purge the wells to a minimum of
three times the volume of standing water in the well or until dry. Surface water samples were dipped from the
surface at previously designated locations. During well purging and surface water sample collection the required
field parameters were recorded. The samples were then placed into laboratory-prepared, pre-preserved containers
via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC-certified
laboratory under proper chain of custody (C-O-C) protocols and analyzed within the proper hold-times.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
total dissolved solids (TDS) and visual turbidity. A summary of the field parameter data is presented in Table 3 and
the field sampling data sheet is enclosed in Appendix B.
Laboratory Results
Pace Analytical Laboratories (PACE) of Huntersville and Asheville, NC performed the laboratory analysis.
Groundwater, surface water and quality control blank samples were analyzed for the constituents listed in 40 CFR
258 Appendix I including volatile organic compounds (VOCs) by EPA Test Method 8260 and total unfiltered metals
by EPA Test Method series 6000/7000. Leachate samples (LE-1) were analyzed for a leachate specific list that
includes Appendix I parameters, nitrate, phosphorus, chemical oxygen demand (COD), biological oxygen demand
(BOD), sulfate, and pH. A sampling and analysis table summarizing the locations, constituents, and methods is
presented on Table 4.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below
the current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and
surface water samples that attain or were above the current SWSL, SWS adopted Groundwater Protection Standards
(GWP), North Carolina Groundwater Standards (2L), the applicable North Carolina Surface Water Standards (2B)
for a class C waterbody, and Federally established Maximum Contaminant Levels (MCL) also known as “Primary
Drinking Water Standards”. MCL Standards are not applicable for regulatory compliance at this facility rather to
underscore the fact that 2L Standards are more stringent than MCL Standard for 37 constituents. Laboratory results
and C-O-Cs are presented in Appendix A.
Quality Control Samples
Methylene chloride was detected in FB and EB and qualified by the laboratory as C9 “common laboratory
contaminant”. Since neither methylene chloride nor it's biodegradation byproducts were detected in any ground or
surface water samples any potential artifact contamination is non-consequential.
2
Groundwater Samples Above Standards
Total cadmium was detected in samples MW-4 (3.1 µg/L), MW-8 (2.2 µg/L), MW-11 (4.0 µg/L), MW-15 (4.0µg/L)
and background well MW-1 (9.7 µg/L) above the 2L Standard (2.0 µg/L). Total vanadium was also detected in
sample MW-9 (4.4j µg/L) and background well MW-1 (4.4j µg/L) above the GWP (3.5 µg/L) but below the SWSL
thus “j-qualified”. Benzene was detected in sample MW-13 (1.1 µg/L) slightly above the 2L Standard (1.0 µg/L).
Surface Water Samples Above Standards
No constituents were detected above established applicable surface water Standards in any surface water sample.
Total cadmium was detected in sample SW-5 collected upstream of the facility.
Leachate Samples
Leachate sample LE-1 contained quantifiable concentrations of five metals and eight VOCs, however, cadmium
was not detected as presented in Table 6. Contaminant levels in the untreated leachate samples are low compared to
typical published values which is consistent with historical results.
Groundwater and Surface Water Characterization
MESCO prepared a potentiometric map using groundwater elevation data from the uppermost aquifer measured
during this event (Figure 2). Groundwater velocity rates and directions were calculated and are included on Table
7. Consistent with historical observations groundwater flows from the southwest towards Edward's Branch, which
serves as the local discharge feature. Groundwater velocity rates ranged from 2 feet/year (MW-15) to 106 feet/year
(MW-13) averaging approximately 22 feet/year which is also consistent with historical calculations. Streams
located within the facility boundaries were visually observed at moderate seasonal flow, moderate volume and low
turbidity.
Findings
Total cadmium was detected in five of the water samples including background well MW-1 and upstream surface
water point SW-5. Total cadmium is naturally inherent in the ground and surface waters at the facility as evidenced
by detections in upgradient background wells MW-1 (lined), MW-1/MW-1R (closed) and upstream surface water
point SW-5. Total cadmium has never been detected in any of the 65 leachate samples collected at least semi-
annually since the landfill was constructed almost 16 years ago.
Benzene was detected in excess of the 2L Standard and in the same concentration during this and the previous
August 2015 event. MW-13 is located cross-gradient and within the lined Phase 2 relevant compliance boundary.
Landfill gas (LFG) has been detected in the vadose near MW-13. The preliminary source of benzene detected in
MW-13 is likely anthropogenic with a transport mechanism of leachate and or LFG.
3
Figures
Topographic Map with Site Location
01 1 MILE
FIGURE 1
Wayne County Landfill North Carolina (Dudley)
CLOSED MSW FACILITY
SUBTITLE D MSW
LANDFILL FACILITY
460 B South Landfill Rd
Dudley, NC 28333
Lat:35-17-19.1338
Long:-78-04-17.2971
Northing:561283.19
Easting:2277068.62
N
Tables
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
March 2-3, 2016
Latitude Longitude
(inches)(ft)
MW-1 12/5/97 2 22.50 7.50 15 soil 164.51 161.95 153.99 10.52 35.2980417 78.0666750
MW-2 12/5/97 2 20.00 5.00 15 soil 147.27 144.63 138.67 8.60 35.2946417 78.0699806
MW-3 12/4/97 2 20.00 5.00 15 soil 141.13 136.40 134.50 6.63 35.2940694 78.0725889
MW-4 12/3/97 2 25.00 10.00 15 soil 139.80 137.80 126.65 13.15 35.2934694 78.0756444
MW-5 12/3/97 2 23.00 8.00 15 soil 140.15 137.35 126.90 13.25 35.2941972 78.0757333
MW-6 12/3/97 2 25.00 10.00 15 soil 146.58 144.42 132.30 14.28 35.2946000 78.0741306
MW-7 12/4/97 2 20.00 5.00 15 soil 135.89 133.57 130.34 5.55 35.2878278 78.0740694
MW-8 12/18/97 2 20.00 5.00 15 soil 135.25 132.79 128.54 6.71 35.2973056 78.0733889
MW-9 12/4/97 2 23.00 8.00 15 soil 141.31 139.13 131.65 9.66 35.2939444 78.0739453
MW-10 12/4/97 2 23.00 8.00 15 soil 141.43 139.19 130.63 10.80 35.2937472 78.0747222
MW-11 4/15/04 2 15.49 5.49 10 soil 134.76 131.76 131.19 3.57 35.2980861 78.0729639
MW-12 4/15/04 2 16.45 6.45 10 soil 135.19 132.19 132.21 2.98 35.2991889 78.0727111
MW-13 4/15/04 2 15.85 5.85 10 soil 149.89 146.89 143.11 6.78 35.2952722 78.0687417
MW-14 9/21/06 2 21.24 6.24 15 soil 137.51 134.68 131.89 5.62 35.2998500 78.0728806
MW-15 9/26/06 2 16.17 6.17 10 soil 131.74 129.01 129.93 1.81 35.3006028 78.0727778
MW-16R 6/4/13 2 22.00 7.00 15 Soil sand 160.39 157.39 147.51 12.88 35.2962278 78.0673861
P-5 1/11/96 2 19.00 11.00 8 soil 159.42 156.25 146.98 12.44 35.3002167 78.0688833
P3-15S 9/21/06 2 16.53 6.53 10 soil 152.23 149.14 144.00 8.23 35.3005639 78.0700639
Na = not available
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well
Depth
Top of Screen
Depth
Screen
Length
Geology of
Screened
Interval
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 2
Field Observations of Monitoring Locations
March 2-3, 2016
Locked Comments
MW-1 Yes Yes Yes Yes Yes Yes
MW-2 Yes Yes Yes Yes Yes Yes Faint organic odor
MW-3 Yes Yes Yes Yes Yes Yes See comments below
MW-4 Yes Yes Yes Yes Yes Yes
MW-5 Yes Yes Yes Yes Yes Yes ID tag re-installed
MW-6 Yes Yes Yes Yes Yes Yes
MW-7 Yes Yes Yes Yes Yes Yes Not re-painted yet, ID tag is loose
MW-8 Yes Yes Yes Yes Yes ?Pad covered with soil
MW-9 Yes Yes Yes Yes No Yes ID tag missing.
MW-10 Yes Yes Yes Yes Yes Yes
MW-11 Yes Yes Yes Yes Yes ?Pad covered with soil
MW-12 Yes Yes Yes Yes Yes ?Pad covered with soil
MW-13 Yes Yes Yes Yes Yes ?Pad covered with soil
MW-14 Yes Yes Yes Yes Yes Yes Ph 3 well
MW-15 Yes Yes Yes Yes Yes Yes Ph 3 well
MW-16R Yes Yes Yes Yes Yes Yes Ph 3 well. Methane gas venting from PVC
LE-1 Yes -----Leachate lagoon sample. Equal composite from 3 inverts
SW-1 Yes -----Shared Downstream of SW-3
SW-2 Yes -----Shared nearest lined MW-2
SW-3 Yes -----Shared downstream of SW-2
SW-3 No -----Shared Upstream furthest east Dry
SW-4 Yes -----Downstream of Ph 1 on Edward's Branch
SW-5 Yes -----Upstream of facility
Any unusual field conditions, observations, or events:
Phase 3 now in operation with waste covering the footprint except for far west sump.
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Assumed
Effective
Adjoiner west of Edwards Branch across from Ph 2 & 3 has cleared forest since 9/12. Adjoiner may potentially impact wetlands.
County replaced pad and case around MW-3 in August 2013. Riser extended 2.63' so top of casing now 141.13 ft amsl.
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
March 2-3, 2016
Parameter Temp.ORP DO pH TDS Turbidity
Units C mg/L SU visual %/vol
MW-1 10.52 153.99 164.51 16.2 NR NR 5.13 40 20 Slight NR
MW-2 8.60 138.67 147.27 15.3 NR NR 5.63 410 200 Clear NR
MW-3 6.63 134.50 141.13 14.6 NR NR 5.41 20 10 Slight NR
MW-4 13.15 126.65 139.80 15.8 NR NR 5.07 10 0 Clear NR
MW-5 13.25 126.90 140.15 15.7 NR NR 5.03 0 0 Clear NR
MW-6 14.28 132.30 146.58 16.3 NR NR 5.13 0 0 Clear NR
MW-7 5.55 130.34 135.89 15.8 NR NR 6.02 210 100 Slight NR
MW-8 6.71 128.54 135.25 15.5 NR NR 5.93 10 0 Clear NR
MW-9 9.66 131.65 141.31 15.7 NR NR 5.03 0 0 Slight NR
MW-10 10.80 130.63 141.43 16.3 NR NR 5.38 10 0 Slight NR
MW-11 3.57 131.19 134.76 15.5 NR NR 5.17 40 20 Slight NR
MW-12 2.98 132.21 135.19 15.1 NR NR 5.11 10 0 Slight NR
MW-13 6.78 143.11 149.89 14.7 NR NR 5.07 60 30 Clear NR
MW-14 5.62 131.89 137.51 14.2 NR NR 5.63 80 40 Slight NR
MW-15 1.81 129.93 131.74 15.9 NR NR 5.41 70 30 Clear NR
MW-16R 12.88 147.51 160.39 16.2 NR NR 5.35 10 0 Slight Exists
Minimum 1.81 126.65 131.74 14.2 NR NR 5.03 0 0 Clear NR
Average 8.30 134.38 142.68 15.6 NR NR 5.34 61 28 Slight NR
Maximum 14.28 153.99 164.51 16.3 NR NR 6.02 410 200 Slight Exists
SW-1 ---8.1 189 4.9 6.97 80 40 Clear NR
SW-2 ---7.8 193 5.1 6.99 80 40 Clear NR
SW-3 ---7.7 193 5.2 6.94 80 40 Clear NR
SW-4 ---6.8 NR NR 6.99 80 40 Clear NR
SW-5 ---7.1 NR NR 7.01 90 40 Clear NR
Minimum ---6.8 NR NR 6.94 80 40 Clear NR
Average ---7.5 NR NR 6.98 82 40 Clear NR
Maximum ---8.1 NR NR 7.01 90 40 Clear NR
NR = No Reading Attempted and not required
Exist = Visually observed LFG vapors (waves) from MW-16R
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
Methane Gas
in Well
Headspace
ft (btoc)ft (amsl)ft (amsl)mV цs/cm ppb
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 4
Sampling and Analysis Summary
March 2-3, 2016
Field Parameter Leachate
To
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pH Ph
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La
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3
5
3
.
2
MW-1 x x x x x x x
MW-2 x x x x x x x
MW-3 x x x x x x x
MW-4 x x x x x x x
MW-5 x x x x x x x
MW-6 x x x x x x x
MW-7 x x x x x x x
MW-8 x x x x x x x
MW-9 x x x x x x x
MW-10 x x x x x x x
MW-11 x x x x x x x
MW-12 x x x x x x x
MW-13 x x x x x x x
MW-14 x x x x x x x
MW-15 x x x x x x x
MW-16R x x x x x x x
SW-1 x x x x x x x
SW-2 x x x x x x x
SW-3 Not Sampled since dry which is typical
SW-3 x x x x x x x
SW-4 x x x x x x x
SW-5 x x x x x x x
LE-1 x x x x x x x x
EB x x
FB x x
TB x
Appendix I = List from current 40 CFR 258
App. I
V OC
s
Wayne County Subtitle D MSWLF, Phases 1-3 Page 1 of 2
Table 5
Detections in Water Samples above SWSL, GWP, 2L, 2B or MCL (Appendix I)
March 2-3, 2016
Sample ID Result Unit
MW-1 Vanadium, total 3/2/16 4.4J 2.5 25 NE 3.5 NE
MW-1 Cadmium, total 3/2/16 9.7 0.5 1 2 5 N & B
MW-4 Cadmium, total 3/2/16 3.1 0.5 1 2 5 N
MW-6 Zinc, total 3/2/16 14.1 5 10 1000 NE
MW-6 Acetone 3/2/16 142 10 100 6000 NE
MW-8 Cadmium, total 3/2/16 2.2 0.5 1 2 5 N
MW-9 Vanadium, total 3/2/16 4.4J 2.5 25 NE 3.5 NE
MW-10 Zinc, total 3/2/16 19.8 5 10 1000 NE
MW-11 Cadmium, total 3/2/16 4 0.5 1 2 5 N
MW-12 Zinc, total 3/2/16 11.4 5 10 1000 NE
MW-12 Barium, total 3/2/16 104 2.5 100 700 2000
MW-12 Cobalt, total 3/2/16 35 2.5 10 70 NE
MW-13 Zinc, total 3/3/16 18.6 5 10 1000 NE
MW-13 Benzene 3/3/16 1.1 0.25 1 1 5 L &/or LFG
MW-15 Cadmium, total 3/3/16 4 0.5 1 2 5 N
MW-15 Zinc, total 3/3/16 11.3 5 10 1000 NE
Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Wayne County Subtitle D MSWLF, Phases 1-3 Page 2 of 2
Sample ID Result UnitParameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
SW-2(Shared)Vanadium, total 3/3/16 3.7J 2.5 25 NE NE
SW-2(Shared)Zinc, total 3/3/16 15.6 5 10 50 NE
SW-4 Zinc, total 3/3/16 27.9 5 10 50 NE
SW-4 Barium, total 3/3/16 234 2.5 100 200000 2000
SW-5 Cadmium, total 3/3/16 1 0.5 1 5 5
SW-5 Barium, total 3/3/16 229 2.5 100 200000 2000
EB Methylene Chloride 3/3/16 1.7 (C9)0.97 1 4.6 5
FB Methylene Chloride 3/3/16 1.6 (C9)0.97 1 4.6 5
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions
J=The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
N = Natural originating from erosion of natural deposits. Source not anthropogenic.
L = Leachate
LFG = Landfill Gas
(C9) = “Common laboratory contaminant” as flagged by the laboratory
BOLD = Concentration > 2L, 2B, GWP or MCL Standard
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, 2B or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 2B = North Carolina 15 NCAC 2B Surface Water Quality Standard for this Specific Stream Classification
6 GWP = Groundwater Protection Standard
7 MCL = Maximum Contaminant Level aka Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
8 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard.
B = Background as detected upgradient/upstream of facility
Wayne County Subtitle D MSWLF Page 1 of 1
Table 6
Detections in Leachate Sample Above SWSL, 2L, GWP or MCL
March 3, 2016
Result Unit
LE1 3/3/16 1.1 0.24 1 0.4 5 1841
LE1 3/3/16 2 0.33 1 6 75 13.2
LE1 Benzene 3/3/16 4.7 0.25 1 1 5 221
LE1 3/3/16 6.5 0.3 1 550 70 274
LE1 Xylene (Total)3/3/16 16.7 0.66 5 530 10000 141
LE1 Toluene 3/3/16 126 0.26 1 600 1000 1016
LE1 Acetone 3/3/16 621 50 100 6000 NE 2163
LE1 3/3/16 1520 4.8 100 4200 NE 4151
LE1 Vinyl chloride 3/3/16 0.71J 0.62 1 0.03 NE 2 36.1
LE1 Barium, total 3/3/16 212 2.5 100 700 2000 850
LE1 Zinc, total 3/3/16 256 5 10 1000 NE 8320
LE1 Chromium, total 3/3/16 24.3 2.5 10 50 100 175.4
LE1 Vanadium, total 3/3/16 9.6J 2.5 25 NE 3.5 NE 179
LE1 Antimony, total 3/3/16 11.1 3.8 6 NE 1.4 6 4520
LE1 Arsenic, total 3/3/16 20.5 2.5 10 10 10
LE1 BOD, 5 day 3/3/16 606000 2000 NE NE NE NE 3837000
LE1 Phosphorus 3/3/16 1110 25 NE NE NE NE 7820
LE1 COD 3/3/16 1470000 12500 NE NE NE NE 4773000
LE1 Sulfate 3/3/16 44100J 5000 250000 250000 NE 244000
adjusted for actual sample preparation data and moisture content, where applicable.
NE = Not Established
BOLD = Concentration > 2L, GWP, MCL or “Average Leachate”
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 “Average Leachate”
7
1,2-Dichloroethane ug/L
1,4-Dichlorobenzene ug/L
ug/L
Ethylbenzene ug/L
ug/L
ug/L
ug/L
2-Butanone (MEK)ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains only constituents detected at or above SWSL, GWP, 2L, or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit (Current as of Sampling Event)
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard (Current as of Sampling Event)
5 GWP = Groundwater Protection Standard (Current as of Sampling Event)
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
7 Average concentration of leachate from a comparable “Dry Tomb” Landfill published in 1988 by EPA document Summary of Data on MSWLF Leachate Characteristics
J =The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 7
March 2-3, 2016
Flow Rate
(cm/sec)(%)(ft/ft)(ft/yr)
MW-1 3.21E-04 31 0.0209 22 S06E 10.52 153.99
MW-2 1.37E-03 31 0.0108 49 S66W 8.60 138.67
MW-3 9.72E-04 31 0.0053 17 S53W 6.63 134.50
MW-4 2.33E-04 9 0.0106 28 S61W 13.15 126.65
MW-5 1.45E-04 9 0.0118 20 N83W 13.25 126.9
MW-6 8.38E-05 31 0.0083 2 N84W 14.28 132.3
MW-7 6.84E-05 9 0.0113 9 N81W 5.55 130.34
MW-8 1.68E-04 9 0.0136 26 S65W 6.71 128.54
MW-9 6.37E-04 31 0.0034 7 S68W 9.66 131.65
MW-10 4.74E-04 31 0.0166 26 S63W 10.80 130.63
MW-11 1.46E-04 22 0.0113 8 S79W 3.57 131.19
MW-12 1.63E-04 22 0.0058 4 N87W 2.98 132.21
MW-13 2.14E-03 22 0.0106 106 S20W 6.78 143.11
MW-14 2.63E-04 22 0.0036 4 N77W 5.62 131.89
MW-15 1.82E-05 22 0.0194 2 N63W 1.81 129.93
MW-16R 22 0.0053 S42W 12.88 147.51
Minimum 1.82E-05 9 0.0034 2 -1.81 126.65
Average 4.80E-04 22 0.0105 22 -8.30 134.38
Maximum 2.14E-03 31 0.0209 106 -14.28 153.99
NOTE:
Hydraulic Conductivity values from slug tests performed on each monitoring well.
where
Hydrologic Properties at Monitoring Well Locations
Monitoring
Well
Hydraulic
Conductivity
Effective
Porosity
Hydraulic
Gradient Flow
Direction
Depth to
Groundwater
Groundwater
Potentiometric
Elevation
(ft btoc)(ft amsl)
na na
Effective porosity values from Design Hydrogeologic Studies for Wayne County.
Hydrologic gradient calculated from groundwater elevations recorded on March 2-3, 2016.
Average Linear Velocity rate (Q) is defined by modified Darcy's equation:
K= hydraulic conductivity
ne= effective porosity
dh= head difference
dl= horizontal distance
Q=−K
ne
⋅dh
dl
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
March 15, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92288935
92288935
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE LINED MSWLF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 74
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 74
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Lab ID Sample ID Matrix Date Collected Date Received
92288935001 MW-1 Water 03/02/16 16:00 03/04/16 09:11
92288935002 MW-2 Water 03/02/16 12:50 03/04/16 09:11
92288935003 MW-3 Water 03/02/16 13:05 03/04/16 09:11
92288935004 MW-4 Water 03/02/16 13:25 03/04/16 09:11
92288935005 MW-5 Water 03/02/16 14:30 03/04/16 09:11
92288935006 MW-6 Water 03/02/16 14:55 03/04/16 09:11
92288935007 MW-7 Water 03/02/16 15:10 03/04/16 09:11
92288935008 MW-8 Water 03/02/16 09:05 03/04/16 09:11
92288935009 MW-9 Water 03/02/16 12:00 03/04/16 09:11
92288935010 MW-10 Water 03/02/16 11:35 03/04/16 09:11
92288935011 MW-11 Water 03/02/16 10:40 03/04/16 09:11
92288935012 MW-12 Water 03/02/16 10:15 03/04/16 09:11
92288935013 MW-13 Water 03/03/16 11:05 03/04/16 09:11
92288935014 MW-14 Water 03/03/16 09:55 03/04/16 09:11
92288935015 MW-15 Water 03/03/16 09:25 03/04/16 09:11
92288935016 MW-16R Water 03/03/16 10:00 03/04/16 09:11
92288935017 SW-4 Water 03/03/16 09:10 03/04/16 09:11
92288935018 SW-5 Water 03/03/16 08:45 03/04/16 09:11
92288935019 LE-1 Water 03/03/16 16:20 03/04/16 09:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 3 of 74
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288935001 MW-1 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935002 MW-2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935003 MW-3 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935004 MW-4 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935005 MW-5 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935006 MW-6 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935007 MW-7 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935008 MW-8 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935009 MW-9 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935010 MW-10 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935011 MW-11 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935012 MW-12 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935013 MW-13 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935014 MW-14 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935015 MW-15 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935016 MW-16R EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935017 SW-4 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935018 SW-5 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288935019 LE-1 EPA 6010 15 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 4 of 74
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 8260 50 PASI-CNB
SM 5210B 1 PASI-ABRJ
EPA 9040 1 PASI-ATEP
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
EPA 365.1 1 PASI-ABRJ
SM 5220D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-1 Lab ID:92288935001 Collected:03/02/16 16:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 18:51 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 18:51 7440-38-203/07/16 18:0010.0 2.5 1
Barium 24.6J ug/L 03/08/16 18:51 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 18:51 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 9.7 ug/L 03/08/16 18:51 7440-43-903/07/16 18:001.0 0.50 1
Chromium 3.3J ug/L 03/08/16 18:51 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 18:51 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 18:51 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 18:51 7439-92-103/07/16 18:0010.0 2.5 1
Nickel 7.5J ug/L 03/08/16 18:51 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 18:51 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 18:51 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 18:51 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 4.4J ug/L 03/08/16 18:51 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 9.9J ug/L 03/08/16 18:51 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 22:01 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 22:01 107-13-12001.9 1
Benzene ND ug/L 03/05/16 22:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 22:01 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 22:01 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 22:01 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 22:01 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 22:01 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 22:01 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 22:01 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 22:01 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 22:01 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 22:01 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 22:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 22:01 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 22:01 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 22:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 22:01 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 22:01 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 22:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 22:01 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 22:01 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 22:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 22:01 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 22:01 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 22:01 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 22:01 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 22:01 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 22:01 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 6 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-1 Lab ID:92288935001 Collected:03/02/16 16:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 22:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 22:01 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 22:01 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 22:01 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 22:01 108-10-11000.33 1
Styrene ND ug/L 03/05/16 22:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 22:01 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 22:01 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 22:01 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 22:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 22:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 22:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 22:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 22:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 22:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 22:01 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 22:01 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 22:01 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %03/05/16 22:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/05/16 22:01 17060-07-070-130 1
Toluene-d8 (S)101 %03/05/16 22:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 7 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-2 Lab ID:92288935002 Collected:03/02/16 12:50 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:03 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:03 7440-38-203/07/16 18:0010.0 2.5 1
Barium 7.7J ug/L 03/08/16 19:03 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:03 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.86J ug/L 03/08/16 19:03 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:03 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt 4.0J ug/L 03/08/16 19:03 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:03 7440-50-803/07/16 18:0010.0 2.5 1
Lead 4.2J ug/L 03/08/16 19:03 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:03 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:03 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:03 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:03 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 2.6J ug/L 03/08/16 19:03 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:03 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 22:17 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 22:17 107-13-12001.9 1
Benzene ND ug/L 03/05/16 22:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 22:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 22:17 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 22:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 22:17 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 22:17 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 22:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 22:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 22:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 22:17 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 22:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 22:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 22:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 22:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 22:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 22:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 22:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 22:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 22:17 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 22:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 22:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 22:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 22:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 22:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 22:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 22:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 22:17 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-2 Lab ID:92288935002 Collected:03/02/16 12:50 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 22:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 22:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 22:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 22:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 22:17 108-10-11000.33 1
Styrene ND ug/L 03/05/16 22:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 22:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 22:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 22:17 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 22:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 22:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 22:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 22:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 22:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 22:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 22:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 22:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 22:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/05/16 22:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/05/16 22:17 17060-07-070-130 1
Toluene-d8 (S)99 %03/05/16 22:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 9 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-3 Lab ID:92288935003 Collected:03/02/16 13:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:06 7440-36-003/07/16 18:006.0 3.8 1
Arsenic 7.0J ug/L 03/08/16 19:06 7440-38-203/07/16 18:0010.0 2.5 1
Barium 19.3J ug/L 03/08/16 19:06 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:06 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.54J ug/L 03/08/16 19:06 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:06 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:06 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:06 7440-50-803/07/16 18:0010.0 2.5 1
Lead 2.7J ug/L 03/08/16 19:06 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:06 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:06 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:06 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:06 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:06 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:06 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 22:34 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 22:34 107-13-12001.9 1
Benzene ND ug/L 03/05/16 22:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 22:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 22:34 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 22:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 22:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 22:34 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 22:34 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 22:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 22:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 22:34 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 22:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 22:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 22:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 22:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 22:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 22:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 22:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 22:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 22:34 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 22:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 22:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 22:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 22:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 22:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 22:34 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 22:34 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 22:34 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 10 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-3 Lab ID:92288935003 Collected:03/02/16 13:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 22:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 22:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 22:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 22:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 22:34 108-10-11000.33 1
Styrene ND ug/L 03/05/16 22:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 22:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 22:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 22:34 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 22:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 22:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 22:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 22:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 22:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 22:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 22:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 22:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 22:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %03/05/16 22:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/05/16 22:34 17060-07-070-130 1
Toluene-d8 (S)102 %03/05/16 22:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 11 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-4 Lab ID:92288935004 Collected:03/02/16 13:25 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:09 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:09 7440-38-203/07/16 18:0010.0 2.5 1
Barium 32.2J ug/L 03/08/16 19:09 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:09 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 3.1 ug/L 03/08/16 19:09 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:09 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:09 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:09 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:09 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:09 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:09 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:09 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:09 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:09 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:09 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 22:51 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 22:51 107-13-12001.9 1
Benzene ND ug/L 03/05/16 22:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 22:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 22:51 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 22:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 22:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 22:51 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 22:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 22:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 22:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 22:51 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 22:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 22:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 22:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 22:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 22:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 22:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 22:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 22:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 22:51 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 22:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 22:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 22:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 22:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 22:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 22:51 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 22:51 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 22:51 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-4 Lab ID:92288935004 Collected:03/02/16 13:25 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 22:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 22:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 22:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 22:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 22:51 108-10-11000.33 1
Styrene ND ug/L 03/05/16 22:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 22:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 22:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 22:51 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 22:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 22:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 22:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 22:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 22:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 22:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 22:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 22:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 22:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/05/16 22:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %03/05/16 22:51 17060-07-070-130 1
Toluene-d8 (S)99 %03/05/16 22:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-5 Lab ID:92288935005 Collected:03/02/16 14:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:12 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:12 7440-38-203/07/16 18:0010.0 2.5 1
Barium 5.8J ug/L 03/08/16 19:12 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:12 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 19:12 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:12 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:12 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:12 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:12 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:12 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:12 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:12 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:12 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:12 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:12 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 23:07 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 23:07 107-13-12001.9 1
Benzene ND ug/L 03/05/16 23:07 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 23:07 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 23:07 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 23:07 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 23:07 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 23:07 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 23:07 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 23:07 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 23:07 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 23:07 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 23:07 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 23:07 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 23:07 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 23:07 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 23:07 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 23:07 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 23:07 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 23:07 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 23:07 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 23:07 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 23:07 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 23:07 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 23:07 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 23:07 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 23:07 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 23:07 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 23:07 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-5 Lab ID:92288935005 Collected:03/02/16 14:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 23:07 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 23:07 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 23:07 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 23:07 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 23:07 108-10-11000.33 1
Styrene 0.35J ug/L 03/05/16 23:07 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 23:07 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 23:07 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 23:07 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 23:07 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 23:07 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 23:07 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 23:07 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 23:07 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 23:07 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 23:07 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 23:07 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 23:07 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/05/16 23:07 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/05/16 23:07 17060-07-070-130 1
Toluene-d8 (S)100 %03/05/16 23:07 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-6 Lab ID:92288935006 Collected:03/02/16 14:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:16 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:16 7440-38-203/07/16 18:0010.0 2.5 1
Barium 65.9J ug/L 03/08/16 19:16 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:16 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 19:16 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:16 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:16 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:16 7440-50-803/07/16 18:0010.0 2.5 1
Lead 2.6J ug/L 03/08/16 19:16 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:16 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:16 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:16 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:16 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 2.6J ug/L 03/08/16 19:16 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 14.1 ug/L 03/08/16 19:16 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 142 ug/L 03/05/16 23:24 67-64-1 M110010.0 1
Acrylonitrile ND ug/L 03/05/16 23:24 107-13-12001.9 1
Benzene ND ug/L 03/05/16 23:24 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 23:24 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 23:24 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 23:24 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 23:24 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 23:24 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 23:24 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 23:24 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 23:24 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 23:24 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 23:24 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 23:24 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 23:24 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 23:24 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 23:24 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 23:24 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 23:24 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 23:24 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 23:24 110-57-6 M11001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 23:24 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 23:24 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 23:24 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 23:24 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 23:24 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 23:24 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 23:24 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 23:24 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
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Page 16 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-6 Lab ID:92288935006 Collected:03/02/16 14:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 23:24 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 23:24 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 23:24 74-88-4 M110.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 23:24 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 23:24 108-10-11000.33 1
Styrene ND ug/L 03/05/16 23:24 100-42-5 M11.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 23:24 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 23:24 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 23:24 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 23:24 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 23:24 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 23:24 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 23:24 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 23:24 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 23:24 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 23:24 108-05-4 M150.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 23:24 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 23:24 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/05/16 23:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/05/16 23:24 17060-07-070-130 1
Toluene-d8 (S)99 %03/05/16 23:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 17 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-7 Lab ID:92288935007 Collected:03/02/16 15:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:19 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:19 7440-38-203/07/16 18:0010.0 2.5 1
Barium 27.5J ug/L 03/08/16 19:19 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:19 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.60J ug/L 03/08/16 19:19 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:19 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:19 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:19 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:19 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:19 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:19 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:19 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:19 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:19 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:19 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/05/16 23:40 67-64-110010.0 1
Acrylonitrile ND ug/L 03/05/16 23:40 107-13-12001.9 1
Benzene ND ug/L 03/05/16 23:40 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/05/16 23:40 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/05/16 23:40 75-27-41.0 0.18 1
Bromoform ND ug/L 03/05/16 23:40 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/05/16 23:40 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/05/16 23:40 78-93-31000.96 1
Carbon disulfide ND ug/L 03/05/16 23:40 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/05/16 23:40 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/05/16 23:40 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/05/16 23:40 75-00-310.0 0.54 1
Chloroform ND ug/L 03/05/16 23:40 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/05/16 23:40 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/05/16 23:40 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/05/16 23:40 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/05/16 23:40 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/05/16 23:40 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/05/16 23:40 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/05/16 23:40 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/05/16 23:40 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/05/16 23:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/05/16 23:40 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/05/16 23:40 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/05/16 23:40 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/05/16 23:40 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/05/16 23:40 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/05/16 23:40 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/05/16 23:40 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-7 Lab ID:92288935007 Collected:03/02/16 15:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/05/16 23:40 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/05/16 23:40 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/05/16 23:40 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/05/16 23:40 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/05/16 23:40 108-10-11000.33 1
Styrene ND ug/L 03/05/16 23:40 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/05/16 23:40 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/05/16 23:40 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/05/16 23:40 127-18-41.0 0.46 1
Toluene ND ug/L 03/05/16 23:40 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/05/16 23:40 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/05/16 23:40 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/05/16 23:40 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/05/16 23:40 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/05/16 23:40 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/05/16 23:40 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/05/16 23:40 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/05/16 23:40 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %03/05/16 23:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %03/05/16 23:40 17060-07-070-130 1
Toluene-d8 (S)99 %03/05/16 23:40 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-8 Lab ID:92288935008 Collected:03/02/16 09:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:22 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:22 7440-38-203/07/16 18:0010.0 2.5 1
Barium 11.4J ug/L 03/08/16 19:22 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:22 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 2.2 ug/L 03/08/16 19:22 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:22 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:22 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:22 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:22 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:22 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:22 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:22 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:22 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:22 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 7.2J ug/L 03/08/16 19:22 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 00:13 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 00:13 107-13-12001.9 1
Benzene ND ug/L 03/06/16 00:13 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 00:13 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 00:13 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 00:13 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 00:13 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 00:13 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 00:13 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 00:13 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 00:13 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 00:13 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 00:13 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 00:13 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 00:13 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 00:13 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 00:13 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 00:13 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 00:13 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 00:13 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 00:13 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 00:13 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 00:13 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 00:13 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 00:13 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 00:13 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 00:13 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 00:13 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 00:13 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-8 Lab ID:92288935008 Collected:03/02/16 09:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 00:13 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 00:13 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 00:13 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 00:13 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 00:13 108-10-11000.33 1
Styrene ND ug/L 03/06/16 00:13 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 00:13 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 00:13 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 00:13 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 00:13 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 00:13 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 00:13 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 00:13 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 00:13 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 00:13 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 00:13 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 00:13 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 00:13 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 00:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 00:13 17060-07-070-130 1
Toluene-d8 (S)101 %03/06/16 00:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-9 Lab ID:92288935009 Collected:03/02/16 12:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:25 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:25 7440-38-203/07/16 18:0010.0 2.5 1
Barium 52.9J ug/L 03/08/16 19:25 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:25 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.53J ug/L 03/08/16 19:25 7440-43-903/07/16 18:001.0 0.50 1
Chromium 2.9J ug/L 03/08/16 19:25 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:25 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:25 7440-50-803/07/16 18:0010.0 2.5 1
Lead 2.7J ug/L 03/08/16 19:25 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:25 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:25 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:25 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:25 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 4.4J ug/L 03/08/16 19:25 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:25 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 00:30 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 00:30 107-13-12001.9 1
Benzene ND ug/L 03/06/16 00:30 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 00:30 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 00:30 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 00:30 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 00:30 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 00:30 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 00:30 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 00:30 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 00:30 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 00:30 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 00:30 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 00:30 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 00:30 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 00:30 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 00:30 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 00:30 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 00:30 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 00:30 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 00:30 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 00:30 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 00:30 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 00:30 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 00:30 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 00:30 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 00:30 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 00:30 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 00:30 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 22 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-9 Lab ID:92288935009 Collected:03/02/16 12:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 00:30 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 00:30 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 00:30 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 00:30 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 00:30 108-10-11000.33 1
Styrene ND ug/L 03/06/16 00:30 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 00:30 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 00:30 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 00:30 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 00:30 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 00:30 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 00:30 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 00:30 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 00:30 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 00:30 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 00:30 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 00:30 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 00:30 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 00:30 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 00:30 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 00:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 23 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-10 Lab ID:92288935010 Collected:03/02/16 11:35 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:28 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:28 7440-38-203/07/16 18:0010.0 2.5 1
Barium 17.7J ug/L 03/08/16 19:28 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:28 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 19:28 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:28 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:28 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:28 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:28 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:28 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:28 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:28 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:28 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 2.7J ug/L 03/08/16 19:28 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 19.8 ug/L 03/08/16 19:28 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 00:46 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 00:46 107-13-12001.9 1
Benzene ND ug/L 03/06/16 00:46 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 00:46 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 00:46 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 00:46 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 00:46 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 00:46 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 00:46 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 00:46 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 00:46 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 00:46 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 00:46 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 00:46 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 00:46 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 00:46 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 00:46 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 00:46 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 00:46 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 00:46 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 00:46 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 00:46 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 00:46 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 00:46 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 00:46 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 00:46 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 00:46 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 00:46 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 00:46 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-10 Lab ID:92288935010 Collected:03/02/16 11:35 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 00:46 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 00:46 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 00:46 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 00:46 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 00:46 108-10-11000.33 1
Styrene ND ug/L 03/06/16 00:46 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 00:46 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 00:46 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 00:46 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 00:46 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 00:46 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 00:46 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 00:46 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 00:46 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 00:46 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 00:46 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 00:46 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 00:46 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %03/06/16 00:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 00:46 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 00:46 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-11 Lab ID:92288935011 Collected:03/02/16 10:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:31 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:31 7440-38-203/07/16 18:0010.0 2.5 1
Barium 24.7J ug/L 03/08/16 19:31 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:31 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 4.0 ug/L 03/08/16 19:31 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:31 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:31 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:31 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:31 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:31 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:31 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:31 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:31 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:31 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:31 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 01:03 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 01:03 107-13-12001.9 1
Benzene ND ug/L 03/06/16 01:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 01:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 01:03 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 01:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 01:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 01:03 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 01:03 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 01:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 01:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 01:03 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 01:03 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 01:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 01:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 01:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 01:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 01:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 01:03 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 01:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 01:03 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 01:03 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 01:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 01:03 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 01:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 01:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 01:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 01:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 01:03 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-11 Lab ID:92288935011 Collected:03/02/16 10:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 01:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 01:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 01:03 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 01:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 01:03 108-10-11000.33 1
Styrene ND ug/L 03/06/16 01:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 01:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 01:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 01:03 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 01:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 01:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 01:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 01:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 01:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 01:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 01:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 01:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 01:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 01:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 01:03 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 01:03 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-12 Lab ID:92288935012 Collected:03/02/16 10:15 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:43 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:43 7440-38-203/07/16 18:0010.0 2.5 1
Barium 104 ug/L 03/08/16 19:43 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:43 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.59J ug/L 03/08/16 19:43 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:43 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt 35.0 ug/L 03/08/16 19:43 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:43 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:43 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:43 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:43 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:43 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:43 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:43 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 11.4 ug/L 03/08/16 19:43 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 01:20 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 01:20 107-13-12001.9 1
Benzene ND ug/L 03/06/16 01:20 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 01:20 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 01:20 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 01:20 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 01:20 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 01:20 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 01:20 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 01:20 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 01:20 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 01:20 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 01:20 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 01:20 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 01:20 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 01:20 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 01:20 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 01:20 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 01:20 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 01:20 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 01:20 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 01:20 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 01:20 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 01:20 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 01:20 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 01:20 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 01:20 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 01:20 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 01:20 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 28 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-12 Lab ID:92288935012 Collected:03/02/16 10:15 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 01:20 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 01:20 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 01:20 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 01:20 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 01:20 108-10-11000.33 1
Styrene ND ug/L 03/06/16 01:20 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 01:20 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 01:20 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 01:20 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 01:20 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 01:20 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 01:20 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 01:20 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 01:20 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 01:20 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 01:20 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 01:20 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 01:20 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 01:20 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %03/06/16 01:20 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 01:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 29 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-13 Lab ID:92288935013 Collected:03/03/16 11:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:46 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:46 7440-38-203/07/16 18:0010.0 2.5 1
Barium 29.6J ug/L 03/08/16 19:46 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:46 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.52J ug/L 03/08/16 19:46 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:46 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:46 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:46 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:46 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:46 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:46 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:46 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:46 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:46 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 18.6 ug/L 03/08/16 19:46 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 01:36 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 01:36 107-13-12001.9 1
Benzene 1.1 ug/L 03/06/16 01:36 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 01:36 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 01:36 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 01:36 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 01:36 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 01:36 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 01:36 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 01:36 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 01:36 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 01:36 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 01:36 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 01:36 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 01:36 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 01:36 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 01:36 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 01:36 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 01:36 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 01:36 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 01:36 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 01:36 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 01:36 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 01:36 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 01:36 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 01:36 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 01:36 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 01:36 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 01:36 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-13 Lab ID:92288935013 Collected:03/03/16 11:05 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 01:36 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 01:36 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 01:36 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 01:36 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 01:36 108-10-11000.33 1
Styrene ND ug/L 03/06/16 01:36 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 01:36 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 01:36 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 01:36 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 01:36 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 01:36 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 01:36 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 01:36 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 01:36 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 01:36 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 01:36 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 01:36 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 01:36 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %03/06/16 01:36 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %03/06/16 01:36 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 01:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-14 Lab ID:92288935014 Collected:03/03/16 09:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 19:52 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 19:52 7440-38-203/07/16 18:0010.0 2.5 1
Barium 43.5J ug/L 03/08/16 19:52 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 19:52 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 19:52 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 19:52 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 19:52 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 19:52 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 19:52 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 19:52 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 19:52 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 19:52 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 19:52 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 19:52 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 19:52 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 01:53 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 01:53 107-13-12001.9 1
Benzene ND ug/L 03/06/16 01:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 01:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 01:53 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 01:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 01:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 01:53 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 01:53 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 01:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 01:53 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 01:53 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 01:53 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 01:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 01:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 01:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 01:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 01:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 01:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 01:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 01:53 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 01:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 01:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 01:53 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 01:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 01:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 01:53 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 01:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 01:53 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-14 Lab ID:92288935014 Collected:03/03/16 09:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 01:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 01:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 01:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 01:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 01:53 108-10-11000.33 1
Styrene ND ug/L 03/06/16 01:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 01:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 01:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 01:53 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 01:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 01:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 01:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 01:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 01:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 01:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 01:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 01:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 01:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %03/06/16 01:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 01:53 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 01:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-15 Lab ID:92288935015 Collected:03/03/16 09:25 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 23:42 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 23:42 7440-38-203/07/16 18:0010.0 2.5 1
Barium 4.3J ug/L 03/08/16 23:42 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 23:42 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 4.0 ug/L 03/08/16 23:42 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 23:42 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 23:42 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 23:42 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 23:42 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 23:42 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 23:42 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 23:42 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 23:42 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 23:42 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 11.3 ug/L 03/08/16 23:42 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 02:09 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 02:09 107-13-12001.9 1
Benzene ND ug/L 03/06/16 02:09 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 02:09 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 02:09 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 02:09 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 02:09 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 02:09 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 02:09 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 02:09 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 02:09 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 02:09 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 02:09 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 02:09 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 02:09 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 02:09 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 02:09 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 02:09 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 02:09 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 02:09 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 02:09 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 02:09 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 02:09 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 02:09 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 02:09 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 02:09 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 02:09 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 02:09 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 02:09 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 34 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-15 Lab ID:92288935015 Collected:03/03/16 09:25 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 02:09 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 02:09 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 02:09 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 02:09 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 02:09 108-10-11000.33 1
Styrene ND ug/L 03/06/16 02:09 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 02:09 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 02:09 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 02:09 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 02:09 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 02:09 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 02:09 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 02:09 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 02:09 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 02:09 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 02:09 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 02:09 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 02:09 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 02:09 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %03/06/16 02:09 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 02:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-16R Lab ID:92288935016 Collected:03/03/16 10:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 23:51 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 23:51 7440-38-203/07/16 18:0010.0 2.5 1
Barium 25.0J ug/L 03/08/16 23:51 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 23:51 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 23:51 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 23:51 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 23:51 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 23:51 7440-50-803/07/16 18:0010.0 2.5 1
Lead 3.7J ug/L 03/08/16 23:51 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 23:51 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 23:51 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 23:51 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 23:51 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 23:51 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 6.2J ug/L 03/08/16 23:51 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 15.0J ug/L 03/06/16 02:26 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 02:26 107-13-12001.9 1
Benzene ND ug/L 03/06/16 02:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 02:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 02:26 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 02:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 02:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 02:26 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 02:26 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 02:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 02:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 02:26 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 02:26 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 02:26 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 02:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 02:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 02:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 02:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 02:26 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 02:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 02:26 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 02:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 02:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 02:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 02:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 02:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 02:26 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 02:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 02:26 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:MW-16R Lab ID:92288935016 Collected:03/03/16 10:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 02:26 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 02:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 02:26 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 02:26 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 02:26 108-10-11000.33 1
Styrene ND ug/L 03/06/16 02:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 02:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 02:26 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 02:26 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 02:26 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 02:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 02:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 02:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 02:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 02:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 02:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 02:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 02:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %03/06/16 02:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 02:26 17060-07-070-130 1
Toluene-d8 (S)98 %03/06/16 02:26 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:SW-4 Lab ID:92288935017 Collected:03/03/16 09:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 23:57 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 23:57 7440-38-203/07/16 18:0010.0 2.5 1
Barium 234 ug/L 03/08/16 23:57 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 23:57 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 23:57 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 23:57 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 23:57 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 23:57 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 23:57 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 23:57 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 23:57 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 23:57 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 23:57 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 23:57 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 27.9 ug/L 03/08/16 23:57 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 05:28 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 05:28 107-13-12001.9 1
Benzene ND ug/L 03/06/16 05:28 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 05:28 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 05:28 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 05:28 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 05:28 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 05:28 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 05:28 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 05:28 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 05:28 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 05:28 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 05:28 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 05:28 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 05:28 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 05:28 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 05:28 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 05:28 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 05:28 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 05:28 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 05:28 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 05:28 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 05:28 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 05:28 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 05:28 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 05:28 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 05:28 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 05:28 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 05:28 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:SW-4 Lab ID:92288935017 Collected:03/03/16 09:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 05:28 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 05:28 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 05:28 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 05:28 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 05:28 108-10-11000.33 1
Styrene ND ug/L 03/06/16 05:28 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 05:28 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 05:28 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 05:28 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 05:28 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 05:28 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 05:28 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 05:28 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 05:28 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 05:28 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 05:28 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 05:28 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 05:28 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 05:28 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 05:28 17060-07-070-130 1
Toluene-d8 (S)98 %03/06/16 05:28 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:SW-5 Lab ID:92288935018 Collected:03/03/16 08:45 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:00 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:00 7440-38-203/07/16 18:0010.0 2.5 1
Barium 229 ug/L 03/09/16 00:00 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:00 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 1.0 ug/L 03/09/16 00:00 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:00 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:00 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:00 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:00 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:00 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:00 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:00 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:00 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:00 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 9.1J ug/L 03/09/16 00:00 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 05:45 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 05:45 107-13-12001.9 1
Benzene ND ug/L 03/06/16 05:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 05:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 05:45 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 05:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 05:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 05:45 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 05:45 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 05:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 05:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 05:45 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 05:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 05:45 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 05:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 05:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 05:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 05:45 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 05:45 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 05:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 05:45 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 05:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 05:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 05:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 05:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 05:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 05:45 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 05:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 05:45 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 40 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:SW-5 Lab ID:92288935018 Collected:03/03/16 08:45 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 05:45 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 05:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 05:45 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 05:45 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 05:45 108-10-11000.33 1
Styrene ND ug/L 03/06/16 05:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 05:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 05:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 05:45 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 05:45 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 05:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 05:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 05:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 05:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 05:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 05:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 05:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 05:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 05:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 05:45 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 05:45 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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9800 Kincey Ave. Suite 100
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Page 41 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:LE-1 Lab ID:92288935019 Collected:03/03/16 16:20 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 11.1 ug/L 03/09/16 00:03 7440-36-003/07/16 18:006.0 3.8 1
Arsenic 20.5 ug/L 03/09/16 00:03 7440-38-203/07/16 18:0010.0 2.5 1
Barium 212 ug/L 03/09/16 00:03 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:03 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/09/16 00:03 7440-43-903/07/16 18:001.0 0.50 1
Chromium 24.3 ug/L 03/09/16 00:03 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt 3.7J ug/L 03/09/16 00:03 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:03 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:03 7439-92-103/07/16 18:0010.0 2.5 1
Nickel 35.8J ug/L 03/09/16 00:03 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:03 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:03 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:03 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 9.6J ug/L 03/09/16 00:03 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 256 ug/L 03/09/16 00:03 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 621 ug/L 03/06/16 15:10 67-64-150050.0 5
Acrylonitrile ND ug/L 03/06/16 06:01 107-13-12001.9 1
Benzene 4.7 ug/L 03/06/16 06:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 06:01 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 06:01 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 06:01 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 06:01 74-83-910.0 0.29 1
2-Butanone (MEK)1520 ug/L 03/06/16 15:10 78-93-35004.8 5
Carbon disulfide 2.2J ug/L 03/06/16 06:01 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 06:01 56-23-51.0 0.25 1
Chlorobenzene 0.70J ug/L 03/06/16 06:01 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 06:01 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 06:01 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 06:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 06:01 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 06:01 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 06:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 06:01 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 06:01 95-50-15.0 0.30 1
1,4-Dichlorobenzene 2.0 ug/L 03/06/16 06:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 06:01 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 06:01 75-34-35.0 0.32 1
1,2-Dichloroethane 1.1 ug/L 03/06/16 06:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 06:01 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.43J ug/L 03/06/16 06:01 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 06:01 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 06:01 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 06:01 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 06:01 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 42 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Sample:LE-1 Lab ID:92288935019 Collected:03/03/16 16:20 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene 6.5 ug/L 03/06/16 06:01 100-41-41.0 0.30 1
2-Hexanone 16.7J ug/L 03/06/16 06:01 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 06:01 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 06:01 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)14.9J ug/L 03/06/16 06:01 108-10-11000.33 1
Styrene 0.26J ug/L 03/06/16 06:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 06:01 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 06:01 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 06:01 127-18-41.0 0.46 1
Toluene 126 ug/L 03/06/16 06:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 06:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 06:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 06:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 06:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 06:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 06:01 108-05-450.0 0.35 1
Vinyl chloride 0.71J ug/L 03/06/16 06:01 75-01-41.0 0.62 1
Xylene (Total)16.7 ug/L 03/06/16 06:01 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 06:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 06:01 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 06:01 2037-26-570-130 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 606000 ug/L 03/09/16 23:5403/05/16 03:30200020001
Analytical Method: EPA 90409040 pH
pH 7.0 Std. Units 03/11/16 14:05 H60.10 0.10 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 44100J ug/L 03/08/16 13:54 14808-79-8125000050005
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 208J ug/L 03/05/16 12:021000010.0 1
Analytical Method: EPA 365.1365.1 Phosphorus, Total
Phosphorus 1110 ug/L 03/11/16 22:05 7723-14-050.0 25.0 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 1470000 ug/L 03/14/16 20:2025000125001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 43 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20891
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92288935001, 92288935002, 92288935003, 92288935004, 92288935005, 92288935006, 92288935007,
92288935008, 92288935009, 92288935010, 92288935011, 92288935012, 92288935013, 92288935014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680479
Associated Lab Samples:92288935001, 92288935002, 92288935003, 92288935004, 92288935005, 92288935006, 92288935007,
92288935008, 92288935009, 92288935010, 92288935011, 92288935012, 92288935013, 92288935014
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 03/08/16 18:273.8
Arsenic ug/L ND 10.0 03/08/16 18:272.5
Barium ug/L ND 100 03/08/16 18:272.5
Beryllium ug/L ND 1.0 03/08/16 18:270.50
Cadmium ug/L ND 1.0 03/08/16 18:270.50
Chromium ug/L ND 10.0 03/08/16 18:272.5
Cobalt ug/L ND 10.0 03/08/16 18:272.5
Copper ug/L ND 10.0 03/08/16 18:272.5
Lead ug/L ND 10.0 03/08/16 18:272.5
Nickel ug/L ND 50.0 03/08/16 18:272.5
Selenium ug/L ND 10.0 03/08/16 18:275.0
Silver ug/L ND 10.0 03/08/16 18:272.5
Thallium ug/L ND 5.5 03/08/16 18:275.0
Vanadium ug/L ND 25.0 03/08/16 18:272.5
Zinc ug/L ND 10.0 03/08/16 18:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680480LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 468500 94 80-120
Arsenic ug/L 548500 110 80-120
Barium ug/L 552500 110 80-120
Beryllium ug/L 547500 109 80-120
Cadmium ug/L 553500 111 80-120
Chromium ug/L 548500 110 80-120
Cobalt ug/L 554500 111 80-120
Copper ug/L 564500 113 80-120
Lead ug/L 548500 110 80-120
Nickel ug/L 554500 111 80-120
Selenium ug/L 546500 109 80-120
Silver ug/L 228250 91 80-120
Thallium ug/L 537500 107 80-120
Vanadium ug/L 550500 110 80-120
Zinc ug/L 545500 109 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680481MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288741001
1680482
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 85 75-12588 4 25500ND426441
Arsenic ug/L 500 100 75-125103 3 25500ND500515
Barium ug/L 500 103 75-125106 2 255009.6 526 538
Beryllium ug/L 500 103 75-125105 2 25500ND514526
Cadmium ug/L 500 101 75-125105 4 25500ND506524
Chromium ug/L 500 101 75-125105 4 25500ND506528
Cobalt ug/L 500 101 75-125105 4 25500ND505526
Copper ug/L 500 103 75-125108 5 25500ND515540
Lead ug/L 500 100 75-125103 4 25500ND498517
Nickel ug/L 500 101 75-125105 4 25500ND505524
Selenium ug/L 500 100 75-125104 4 25500ND501521
Silver ug/L 250 84 75-12588 4 25250ND211219
Thallium ug/L 500 98 75-125102 3 25500ND492508
Vanadium ug/L 500 101 75-125106 4 25500ND505528
Zinc ug/L 500 99 75-125103 4 25500ND501520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20892
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92288935015, 92288935016, 92288935017, 92288935018, 92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680484
Associated Lab Samples:92288935015, 92288935016, 92288935017, 92288935018, 92288935019
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 03/08/16 23:273.8
Arsenic ug/L ND 10.0 03/08/16 23:272.5
Barium ug/L 4.2J 100 03/08/16 23:272.5
Beryllium ug/L ND 1.0 03/08/16 23:270.50
Cadmium ug/L ND 1.0 03/08/16 23:270.50
Chromium ug/L ND 10.0 03/08/16 23:272.5
Cobalt ug/L ND 10.0 03/08/16 23:272.5
Copper ug/L ND 10.0 03/08/16 23:272.5
Lead ug/L ND 10.0 03/08/16 23:272.5
Nickel ug/L ND 50.0 03/08/16 23:272.5
Selenium ug/L ND 10.0 03/08/16 23:275.0
Silver ug/L ND 10.0 03/08/16 23:272.5
Thallium ug/L ND 5.5 03/08/16 23:275.0
Vanadium ug/L ND 25.0 03/08/16 23:272.5
Zinc ug/L ND 10.0 03/08/16 23:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680485LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 456500 91 80-120
Arsenic ug/L 542500 108 80-120
Barium ug/L 568500 114 80-120
Beryllium ug/L 530500 106 80-120
Cadmium ug/L 527500 105 80-120
Chromium ug/L 537500 107 80-120
Cobalt ug/L 544500 109 80-120
Copper ug/L 572500 114 80-120
Lead ug/L 543500 109 80-120
Nickel ug/L 532500 106 80-120
Selenium ug/L 530500 106 80-120
Silver ug/L 225250 90 80-120
Thallium ug/L 520500 104 80-120
Vanadium ug/L 507500 101 80-120
Zinc ug/L 545500 109 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680486MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288935015
1680487
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 90 75-12587 3 25500ND451437
Arsenic ug/L 500 107 75-125104 3 25500ND534518
Barium ug/L 500 113 75-125110 3 255004.3J 571 556
Beryllium ug/L 500 106 75-125103 3 25500ND530516
Cadmium ug/L 500 104 75-125101 3 255004.0 526 511
Chromium ug/L 500 107 75-125105 2 25500ND536524
Cobalt ug/L 500 107 75-125104 3 25500ND536519
Copper ug/L 500 115 75-125112 3 25500ND575559
Lead ug/L 500 107 75-125104 3 25500ND535519
Nickel ug/L 500 105 75-125102 3 25500ND525509
Selenium ug/L 500 104 75-125101 3 25500ND518505
Silver ug/L 250 90 75-12588 2 25250ND224220
Thallium ug/L 500 102 75-125100 2 25500ND510500
Vanadium ug/L 500 101 75-12599 2 25500ND507496
Zinc ug/L 500 107 75-125104 3 2550011.3 548 530
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35828
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288935001, 92288935002, 92288935003, 92288935004, 92288935005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679864
Associated Lab Samples:92288935001, 92288935002, 92288935003, 92288935004, 92288935005
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/05/16 18:090.33
1,1,1-Trichloroethane ug/L ND 1.0 03/05/16 18:090.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/05/16 18:090.40
1,1,2-Trichloroethane ug/L ND 1.0 03/05/16 18:090.29
1,1-Dichloroethane ug/L ND 5.0 03/05/16 18:090.32
1,1-Dichloroethene ug/L ND 5.0 03/05/16 18:090.56
1,2,3-Trichloropropane ug/L ND 1.0 03/05/16 18:090.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/05/16 18:092.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/05/16 18:090.27
1,2-Dichlorobenzene ug/L ND 5.0 03/05/16 18:090.30
1,2-Dichloroethane ug/L ND 1.0 03/05/16 18:090.24
1,2-Dichloropropane ug/L ND 1.0 03/05/16 18:090.27
1,4-Dichlorobenzene ug/L ND 1.0 03/05/16 18:090.33
2-Butanone (MEK)ug/L ND 100 03/05/16 18:090.96
2-Hexanone ug/L ND 50.0 03/05/16 18:090.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/05/16 18:090.33
Acetone ug/L ND 100 03/05/16 18:0910.0
Acrylonitrile ug/L ND 200 03/05/16 18:091.9
Benzene ug/L ND 1.0 03/05/16 18:090.25
Bromochloromethane ug/L ND 3.0 03/05/16 18:090.17
Bromodichloromethane ug/L ND 1.0 03/05/16 18:090.18
Bromoform ug/L ND 3.0 03/05/16 18:090.26
Bromomethane ug/L ND 10.0 03/05/16 18:090.29
Carbon disulfide ug/L ND 100 03/05/16 18:091.2
Carbon tetrachloride ug/L ND 1.0 03/05/16 18:090.25
Chlorobenzene ug/L ND 3.0 03/05/16 18:090.23
Chloroethane ug/L ND 10.0 03/05/16 18:090.54
Chloroform ug/L ND 5.0 03/05/16 18:090.14
Chloromethane ug/L ND 1.0 03/05/16 18:090.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/05/16 18:090.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/05/16 18:090.13
Dibromochloromethane ug/L ND 3.0 03/05/16 18:090.21
Dibromomethane ug/L ND 10.0 03/05/16 18:090.21
Ethylbenzene ug/L ND 1.0 03/05/16 18:090.30
Iodomethane ug/L ND 10.0 03/05/16 18:090.32
Methylene Chloride ug/L ND 1.0 03/05/16 18:090.97
Styrene ug/L ND 1.0 03/05/16 18:090.26
Tetrachloroethene ug/L ND 1.0 03/05/16 18:090.46
Toluene ug/L ND 1.0 03/05/16 18:090.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/05/16 18:090.49
trans-1,3-Dichloropropene ug/L ND 1.0 03/05/16 18:090.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679864
Associated Lab Samples:92288935001, 92288935002, 92288935003, 92288935004, 92288935005
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 03/05/16 18:091.0
Trichloroethene ug/L ND 1.0 03/05/16 18:090.47
Trichlorofluoromethane ug/L ND 1.0 03/05/16 18:090.20
Vinyl acetate ug/L ND 50.0 03/05/16 18:090.35
Vinyl chloride ug/L ND 1.0 03/05/16 18:090.62
Xylene (Total)ug/L ND 5.0 03/05/16 18:090.66
1,2-Dichloroethane-d4 (S)%99 70-130 03/05/16 18:09
4-Bromofluorobenzene (S)%97 70-130 03/05/16 18:09
Toluene-d8 (S)%100 70-130 03/05/16 18:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679865LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.150 98 80-125
1,1,1-Trichloroethane ug/L 49.050 98 71-129
1,1,2,2-Tetrachloroethane ug/L 44.950 90 79-124
1,1,2-Trichloroethane ug/L 48.650 97 85-125
1,1-Dichloroethane ug/L 48.750 97 73-126
1,1-Dichloroethene ug/L 51.750 103 66-135
1,2,3-Trichloropropane ug/L 48.550 97 75-130
1,2-Dibromo-3-chloropropane ug/L 44.950 90 71-133
1,2-Dibromoethane (EDB)ug/L 49.350 99 83-124
1,2-Dichlorobenzene ug/L 47.250 94 80-133
1,2-Dichloroethane ug/L 46.550 93 67-128
1,2-Dichloropropane ug/L 48.750 97 75-132
1,4-Dichlorobenzene ug/L 51.150 102 78-130
2-Butanone (MEK)ug/L 95.6J100 96 61-144
2-Hexanone ug/L 93.3100 93 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 91.4J100 91 48-146
Acrylonitrile ug/L 240250 96 40-160
Benzene ug/L 49.550 99 80-125
Bromochloromethane ug/L 49.550 99 71-125
Bromodichloromethane ug/L 49.050 98 78-124
Bromoform ug/L 45.850 92 71-128
Bromomethane ug/L 32.750 65 40-160
Carbon disulfide ug/L 50.9J50 102 50-160
Carbon tetrachloride ug/L 48.150 96 69-131
Chlorobenzene ug/L 48.950 98 81-122
Chloroethane ug/L 49.350 99 39-148
Chloroform ug/L 48.350 97 73-127
Chloromethane ug/L 39.850 80 44-146
cis-1,2-Dichloroethene ug/L 49.150 98 74-124
cis-1,3-Dichloropropene ug/L 49.450 99 72-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679865LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 48.050 96 78-125
Dibromomethane ug/L 48.450 97 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 56.2100 56 39-154
Methylene Chloride ug/L 45.650 91 64-133
Styrene ug/L 49.150 98 84-126
Tetrachloroethene ug/L 49.250 98 78-122
Toluene ug/L 48.050 96 80-121
trans-1,2-Dichloroethene ug/L 50.550 101 71-127
trans-1,3-Dichloropropene ug/L 48.650 97 69-141
trans-1,4-Dichloro-2-butene ug/L 36.8J50 74 40-160
Trichloroethene ug/L 48.450 97 78-122
Trichlorofluoromethane ug/L 50.050 100 53-137
Vinyl acetate ug/L 95.4100 95 40-160
Vinyl chloride ug/L 49.050 98 58-137
Xylene (Total)ug/L 138150 92 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679867MATRIX SPIKE SAMPLE:
MSSpike
Result
92288658004
1,1,1,2-Tetrachloroethane ug/L 22.420 112 70-130ND
1,1,1-Trichloroethane ug/L 23.420 117 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.020 105 70-130ND
1,1,2-Trichloroethane ug/L 21.520 107 70-130ND
1,1-Dichloroethane ug/L 23.920 119 70-130ND
1,1-Dichloroethene ug/L 25.820 129 70-166ND
1,2,3-Trichloropropane ug/L 21.920 109 70-130ND
1,2-Dibromo-3-chloropropane ug/L 21.120 105 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.820 114 70-130ND
1,2-Dichlorobenzene ug/L 21.120 106 70-130ND
1,2-Dichloroethane ug/L 22.220 110 70-130ND
1,2-Dichloropropane ug/L 23.020 115 70-130ND
1,4-Dichlorobenzene ug/L 21.620 108 70-130ND
2-Butanone (MEK)ug/L 44.0J40 110 70-130ND
2-Hexanone ug/L 43.5J40 109 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 46.8J40 117 70-130ND
Acetone ug/L 41.9J40 105 70-130ND
Acrylonitrile ug/L 114J100 114 70-130ND
Benzene ug/L 23.320 116 70-148ND
Bromochloromethane ug/L 23.720 118 70-130ND
Bromodichloromethane ug/L 22.720 114 70-130ND
Bromoform ug/L 20.520 103 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679867MATRIX SPIKE SAMPLE:
MSSpike
Result
92288658004
Bromomethane ug/L 15.720 79 70-130ND
Carbon disulfide ug/L 24.8J20 124 70-130ND
Carbon tetrachloride ug/L 23.620 118 70-130ND
Chlorobenzene ug/L 22.520 113 70-146ND
Chloroethane ug/L 24.220 121 70-130ND
Chloroform ug/L 22.820 114 70-130ND
Chloromethane ug/L 18.920 95 70-130ND
cis-1,2-Dichloroethene ug/L 24.020 120 70-130ND
cis-1,3-Dichloropropene ug/L 22.420 112 70-130ND
Dibromochloromethane ug/L 21.520 107 70-130ND
Dibromomethane ug/L 22.520 113 70-130ND
Ethylbenzene ug/L 22.520 112 70-130ND
Iodomethane ug/L 14.4 M1403670-130ND
Methylene Chloride ug/L 22.120 110 70-130ND
Styrene ug/L 22.020 110 70-130ND
Tetrachloroethene ug/L 22.220 111 70-130ND
Toluene ug/L 22.520 113 70-155ND
trans-1,2-Dichloroethene ug/L 24.420 122 70-130ND
trans-1,3-Dichloropropene ug/L 21.420 107 70-130ND
trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND
Trichloroethene ug/L 22.520 113 69-151ND
Trichlorofluoromethane ug/L 24.820 124 70-130ND
Vinyl acetate ug/L 34.5J40 86 70-130ND
Vinyl chloride ug/L 24.920 125 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288658002
1679866SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288658002
1679866SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 0101
4-Bromofluorobenzene (S)%94 196
Toluene-d8 (S)%98 2100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35829
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288935006, 92288935007, 92288935008, 92288935009, 92288935010, 92288935011, 92288935012,
92288935013, 92288935014, 92288935015, 92288935016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679868
Associated Lab Samples:92288935006, 92288935007, 92288935008, 92288935009, 92288935010, 92288935011, 92288935012,
92288935013, 92288935014, 92288935015, 92288935016
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/05/16 18:260.33
1,1,1-Trichloroethane ug/L ND 1.0 03/05/16 18:260.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/05/16 18:260.40
1,1,2-Trichloroethane ug/L ND 1.0 03/05/16 18:260.29
1,1-Dichloroethane ug/L ND 5.0 03/05/16 18:260.32
1,1-Dichloroethene ug/L ND 5.0 03/05/16 18:260.56
1,2,3-Trichloropropane ug/L ND 1.0 03/05/16 18:260.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/05/16 18:262.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/05/16 18:260.27
1,2-Dichlorobenzene ug/L ND 5.0 03/05/16 18:260.30
1,2-Dichloroethane ug/L ND 1.0 03/05/16 18:260.24
1,2-Dichloropropane ug/L ND 1.0 03/05/16 18:260.27
1,4-Dichlorobenzene ug/L ND 1.0 03/05/16 18:260.33
2-Butanone (MEK)ug/L ND 100 03/05/16 18:260.96
2-Hexanone ug/L ND 50.0 03/05/16 18:260.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/05/16 18:260.33
Acetone ug/L ND 100 03/05/16 18:2610.0
Acrylonitrile ug/L ND 200 03/05/16 18:261.9
Benzene ug/L ND 1.0 03/05/16 18:260.25
Bromochloromethane ug/L ND 3.0 03/05/16 18:260.17
Bromodichloromethane ug/L ND 1.0 03/05/16 18:260.18
Bromoform ug/L ND 3.0 03/05/16 18:260.26
Bromomethane ug/L ND 10.0 03/05/16 18:260.29
Carbon disulfide ug/L ND 100 03/05/16 18:261.2
Carbon tetrachloride ug/L ND 1.0 03/05/16 18:260.25
Chlorobenzene ug/L ND 3.0 03/05/16 18:260.23
Chloroethane ug/L ND 10.0 03/05/16 18:260.54
Chloroform ug/L ND 5.0 03/05/16 18:260.14
Chloromethane ug/L ND 1.0 03/05/16 18:260.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/05/16 18:260.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/05/16 18:260.13
Dibromochloromethane ug/L ND 3.0 03/05/16 18:260.21
Dibromomethane ug/L ND 10.0 03/05/16 18:260.21
Ethylbenzene ug/L ND 1.0 03/05/16 18:260.30
Iodomethane ug/L ND 10.0 03/05/16 18:260.32
Methylene Chloride ug/L ND 1.0 03/05/16 18:260.97
Styrene ug/L ND 1.0 03/05/16 18:260.26
Tetrachloroethene ug/L ND 1.0 03/05/16 18:260.46
Toluene ug/L ND 1.0 03/05/16 18:260.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/05/16 18:260.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679868
Associated Lab Samples:92288935006, 92288935007, 92288935008, 92288935009, 92288935010, 92288935011, 92288935012,
92288935013, 92288935014, 92288935015, 92288935016
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 03/05/16 18:260.26
trans-1,4-Dichloro-2-butene ug/L ND 100 03/05/16 18:261.0
Trichloroethene ug/L ND 1.0 03/05/16 18:260.47
Trichlorofluoromethane ug/L ND 1.0 03/05/16 18:260.20
Vinyl acetate ug/L ND 50.0 03/05/16 18:260.35
Vinyl chloride ug/L ND 1.0 03/05/16 18:260.62
Xylene (Total)ug/L ND 5.0 03/05/16 18:260.66
1,2-Dichloroethane-d4 (S)%99 70-130 03/05/16 18:26
4-Bromofluorobenzene (S)%94 70-130 03/05/16 18:26
Toluene-d8 (S)%99 70-130 03/05/16 18:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679869LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.650 99 80-125
1,1,1-Trichloroethane ug/L 47.450 95 71-129
1,1,2,2-Tetrachloroethane ug/L 46.250 92 79-124
1,1,2-Trichloroethane ug/L 48.850 98 85-125
1,1-Dichloroethane ug/L 47.750 95 73-126
1,1-Dichloroethene ug/L 50.550 101 66-135
1,2,3-Trichloropropane ug/L 51.450 103 75-130
1,2-Dibromo-3-chloropropane ug/L 46.650 93 71-133
1,2-Dibromoethane (EDB)ug/L 50.550 101 83-124
1,2-Dichlorobenzene ug/L 47.750 95 80-133
1,2-Dichloroethane ug/L 46.350 93 67-128
1,2-Dichloropropane ug/L 48.150 96 75-132
1,4-Dichlorobenzene ug/L 50.150 100 78-130
2-Butanone (MEK)ug/L 94.1J100 94 61-144
2-Hexanone ug/L 94.3100 94 68-143
4-Methyl-2-pentanone (MIBK)ug/L 99.9J100 100 72-135
Acetone ug/L 92.8J100 93 48-146
Acrylonitrile ug/L 243250 97 40-160
Benzene ug/L 48.650 97 80-125
Bromochloromethane ug/L 50.050 100 71-125
Bromodichloromethane ug/L 48.350 97 78-124
Bromoform ug/L 46.150 92 71-128
Bromomethane ug/L 37.750 75 40-160
Carbon disulfide ug/L 49.2J50 98 50-160
Carbon tetrachloride ug/L 47.950 96 69-131
Chlorobenzene ug/L 49.150 98 81-122
Chloroethane ug/L 46.950 94 39-148
Chloroform ug/L 46.750 93 73-127
Chloromethane ug/L 39.650 79 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679869LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 48.850 98 74-124
cis-1,3-Dichloropropene ug/L 50.150 100 72-132
Dibromochloromethane ug/L 49.050 98 78-125
Dibromomethane ug/L 48.550 97 82-120
Ethylbenzene ug/L 48.150 96 79-121
Iodomethane ug/L 52.9100 53 39-154
Methylene Chloride ug/L 44.050 88 64-133
Styrene ug/L 49.350 99 84-126
Tetrachloroethene ug/L 49.550 99 78-122
Toluene ug/L 47.850 96 80-121
trans-1,2-Dichloroethene ug/L 48.650 97 71-127
trans-1,3-Dichloropropene ug/L 47.850 96 69-141
trans-1,4-Dichloro-2-butene ug/L 37.2J50 74 40-160
Trichloroethene ug/L 48.150 96 78-122
Trichlorofluoromethane ug/L 48.550 97 53-137
Vinyl acetate ug/L 95.3100 95 40-160
Vinyl chloride ug/L 48.650 97 58-137
Xylene (Total)ug/L 140150 93 81-126
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679870MATRIX SPIKE SAMPLE:
MSSpike
Result
92288935006
1,1,1,2-Tetrachloroethane ug/L 22.020 110 70-130ND
1,1,1-Trichloroethane ug/L 22.920 114 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,2-Trichloroethane ug/L 21.420 107 70-130ND
1,1-Dichloroethane ug/L 22.820 114 70-130ND
1,1-Dichloroethene ug/L 24.520 122 70-166ND
1,2,3-Trichloropropane ug/L 21.320 106 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.120 101 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.920 109 70-130ND
1,2-Dichlorobenzene ug/L 20.420 102 70-130ND
1,2-Dichloroethane ug/L 21.220 105 70-130ND
1,2-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 22.220 111 70-130ND
2-Butanone (MEK)ug/L 39.7J40 99 70-130ND
2-Hexanone ug/L 39.8J40 100 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 43.9J40 110 70-130ND
Acetone ug/L 168 M1406570-130142
Acrylonitrile ug/L 107J100 107 70-130ND
Benzene ug/L 23.120 115 70-148ND
Bromochloromethane ug/L 22.820 114 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679870MATRIX SPIKE SAMPLE:
MSSpike
Result
92288935006
Bromodichloromethane ug/L 21.820 109 70-130ND
Bromoform ug/L 19.120 96 70-130ND
Bromomethane ug/L 14.620 73 70-130ND
Carbon disulfide ug/L 24.1J20 120 70-130ND
Carbon tetrachloride ug/L 22.520 112 70-130ND
Chlorobenzene ug/L 22.220 111 70-146ND
Chloroethane ug/L 22.020 110 70-130ND
Chloroform ug/L 22.520 112 70-130ND
Chloromethane ug/L 17.620 88 70-130ND
cis-1,2-Dichloroethene ug/L 23.320 117 70-130ND
cis-1,3-Dichloropropene ug/L 20.920 105 70-130ND
Dibromochloromethane ug/L 21.220 106 70-130ND
Dibromomethane ug/L 22.020 110 70-130ND
Ethylbenzene ug/L 21.820 109 70-130ND
Iodomethane ug/L 18.9 M1404770-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
Styrene ug/L ND M120170-130ND
Tetrachloroethene ug/L 22.220 111 70-130ND
Toluene ug/L 22.120 110 70-155ND
trans-1,2-Dichloroethene ug/L 23.520 117 70-130ND
trans-1,3-Dichloropropene ug/L 20.620 103 70-130ND
trans-1,4-Dichloro-2-butene ug/L 12.8J M1206470-130ND
Trichloroethene ug/L 21.920 110 69-151ND
Trichlorofluoromethane ug/L 24.720 123 70-130ND
Vinyl acetate ug/L 4.8J M1401270-130ND
Vinyl chloride ug/L 24.220 121 70-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288935007
1679871SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288935007
1679871SAMPLE DUPLICATE:
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 2101
4-Bromofluorobenzene (S)%94 093
Toluene-d8 (S)%100 199
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35830
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288935017, 92288935018, 92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288935017, 92288935018, 92288935019
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/06/16 04:550.33
1,1,1-Trichloroethane ug/L ND 1.0 03/06/16 04:550.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/06/16 04:550.40
1,1,2-Trichloroethane ug/L ND 1.0 03/06/16 04:550.29
1,1-Dichloroethane ug/L ND 5.0 03/06/16 04:550.32
1,1-Dichloroethene ug/L ND 5.0 03/06/16 04:550.56
1,2,3-Trichloropropane ug/L ND 1.0 03/06/16 04:550.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/06/16 04:552.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/06/16 04:550.27
1,2-Dichlorobenzene ug/L ND 5.0 03/06/16 04:550.30
1,2-Dichloroethane ug/L ND 1.0 03/06/16 04:550.24
1,2-Dichloropropane ug/L ND 1.0 03/06/16 04:550.27
1,4-Dichlorobenzene ug/L ND 1.0 03/06/16 04:550.33
2-Butanone (MEK)ug/L ND 100 03/06/16 04:550.96
2-Hexanone ug/L ND 50.0 03/06/16 04:550.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/06/16 04:550.33
Acetone ug/L ND 100 03/06/16 04:5510.0
Acrylonitrile ug/L ND 200 03/06/16 04:551.9
Benzene ug/L ND 1.0 03/06/16 04:550.25
Bromochloromethane ug/L ND 3.0 03/06/16 04:550.17
Bromodichloromethane ug/L ND 1.0 03/06/16 04:550.18
Bromoform ug/L ND 3.0 03/06/16 04:550.26
Bromomethane ug/L ND 10.0 03/06/16 04:550.29
Carbon disulfide ug/L ND 100 03/06/16 04:551.2
Carbon tetrachloride ug/L ND 1.0 03/06/16 04:550.25
Chlorobenzene ug/L ND 3.0 03/06/16 04:550.23
Chloroethane ug/L ND 10.0 03/06/16 04:550.54
Chloroform ug/L ND 5.0 03/06/16 04:550.14
Chloromethane ug/L ND 1.0 03/06/16 04:550.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.13
Dibromochloromethane ug/L ND 3.0 03/06/16 04:550.21
Dibromomethane ug/L ND 10.0 03/06/16 04:550.21
Ethylbenzene ug/L ND 1.0 03/06/16 04:550.30
Iodomethane ug/L ND 10.0 03/06/16 04:550.32
Methylene Chloride ug/L ND 1.0 03/06/16 04:550.97
Styrene ug/L ND 1.0 03/06/16 04:550.26
Tetrachloroethene ug/L ND 1.0 03/06/16 04:550.46
Toluene ug/L ND 1.0 03/06/16 04:550.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.49
trans-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288935017, 92288935018, 92288935019
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 03/06/16 04:551.0
Trichloroethene ug/L ND 1.0 03/06/16 04:550.47
Trichlorofluoromethane ug/L ND 1.0 03/06/16 04:550.20
Vinyl acetate ug/L ND 50.0 03/06/16 04:550.35
Vinyl chloride ug/L ND 1.0 03/06/16 04:550.62
Xylene (Total)ug/L ND 5.0 03/06/16 04:550.66
1,2-Dichloroethane-d4 (S)%100 70-130 03/06/16 04:55
4-Bromofluorobenzene (S)%97 70-130 03/06/16 04:55
Toluene-d8 (S)%99 70-130 03/06/16 04:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.850 102 80-125
1,1,1-Trichloroethane ug/L 48.750 97 71-129
1,1,2,2-Tetrachloroethane ug/L 49.050 98 79-124
1,1,2-Trichloroethane ug/L 48.550 97 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 52.350 105 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 49.250 98 71-133
1,2-Dibromoethane (EDB)ug/L 52.850 106 83-124
1,2-Dichlorobenzene ug/L 48.650 97 80-133
1,2-Dichloroethane ug/L 47.950 96 67-128
1,2-Dichloropropane ug/L 49.750 99 75-132
1,4-Dichlorobenzene ug/L 52.250 104 78-130
2-Butanone (MEK)ug/L 95.7J100 96 61-144
2-Hexanone ug/L 98.0100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 106100 106 72-135
Acetone ug/L 94.5J100 94 48-146
Acrylonitrile ug/L 260250 104 40-160
Benzene ug/L 50.150 100 80-125
Bromochloromethane ug/L 52.950 106 71-125
Bromodichloromethane ug/L 50.950 102 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.3J50 101 50-160
Carbon tetrachloride ug/L 49.050 98 69-131
Chlorobenzene ug/L 51.250 102 81-122
Chloroethane ug/L 51.150 102 39-148
Chloroform ug/L 48.550 97 73-127
Chloromethane ug/L 38.050 76 44-146
cis-1,2-Dichloroethene ug/L 50.250 100 74-124
cis-1,3-Dichloropropene ug/L 50.350 101 72-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 50.450 101 78-125
Dibromomethane ug/L 51.650 103 82-120
Ethylbenzene ug/L 50.250 100 79-121
Iodomethane ug/L 50.5100 51 39-154
Methylene Chloride ug/L 46.750 93 64-133
Styrene ug/L 50.250 100 84-126
Tetrachloroethene ug/L 48.850 98 78-122
Toluene ug/L 49.550 99 80-121
trans-1,2-Dichloroethene ug/L 50.550 101 71-127
trans-1,3-Dichloropropene ug/L 47.650 95 69-141
trans-1,4-Dichloro-2-butene ug/L 35.5J50 71 40-160
Trichloroethene ug/L 50.150 100 78-122
Trichlorofluoromethane ug/L 50.750 101 53-137
Vinyl acetate ug/L 97.0100 97 40-160
Vinyl chloride ug/L 50.150 100 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
1,1,1,2-Tetrachloroethane ug/L 20.520 103 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.520 97 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 22.220 111 70-130ND
1,1-Dichloroethene ug/L 24.020 120 70-166ND
1,2,3-Trichloropropane ug/L 21.020 105 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.820 94 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.920 104 70-130ND
1,2-Dichlorobenzene ug/L 19.620 98 70-130ND
1,2-Dichloroethane ug/L 20.920 105 70-130ND
1,2-Dichloropropane ug/L 21.020 105 70-130ND
1,4-Dichlorobenzene ug/L 21.320 107 70-130ND
2-Butanone (MEK)ug/L 39.7J40 99 70-130ND
2-Hexanone ug/L 38.7J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.1J40 105 70-130ND
Acetone ug/L 40.9J40 102 70-130ND
Acrylonitrile ug/L 105J100 105 70-130ND
Benzene ug/L 22.020 110 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 20.620 103 70-130ND
Bromoform ug/L 18.220 91 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
Bromomethane ug/L 9.6J M1204870-130ND
Carbon disulfide ug/L 23.8J20 119 70-130ND
Carbon tetrachloride ug/L 22.320 111 70-130ND
Chlorobenzene ug/L 21.220 106 70-146ND
Chloroethane ug/L 23.720 118 70-130ND
Chloroform ug/L 21.120 105 70-130ND
Chloromethane ug/L 16.820 84 70-130ND
cis-1,2-Dichloroethene ug/L 22.520 113 70-130ND
cis-1,3-Dichloropropene ug/L 19.820 99 70-130ND
Dibromochloromethane ug/L 20.120 100 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 20.820 104 70-130ND
Iodomethane ug/L 14.1 M1403570-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 20.320 101 70-130ND
Tetrachloroethene ug/L 21.520 107 70-130ND
Toluene ug/L 21.120 106 70-155ND
trans-1,2-Dichloroethene ug/L 22.920 115 70-130ND
trans-1,3-Dichloropropene ug/L 19.120 96 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.2J M1205670-130ND
Trichloroethene ug/L 21.520 107 69-151ND
Trichlorofluoromethane ug/L 23.320 116 70-130ND
Vinyl acetate ug/L 28.3J40 71 70-130ND
Vinyl chloride ug/L 23.720 118 70-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 099
4-Bromofluorobenzene (S)%94 498
Toluene-d8 (S)%100 298
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43417
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples:92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679779
Associated Lab Samples:92288935019
Matrix:Water
AnalyzedMDL
BOD, 5 day ug/L ND 2000 03/09/16 23:542000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679780LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 168000198000 85 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288829001
1679781SAMPLE DUPLICATE:
BOD, 5 day ug/L 24200 D6161028.4 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43478
EPA 9040
EPA 9040
9040 pH
Associated Lab Samples:92288935019
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288389001
1682318SAMPLE DUPLICATE:
pH Std. Units 6.9 H6096.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288968001
1682319SAMPLE DUPLICATE:
pH Std. Units 4.6 H6094.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26695
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680643
Associated Lab Samples:92288935019
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 03/08/16 10:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680644LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 18800J20000 94 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680645MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288834001
1680646
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M6200002890-11031 0 10200002590 mg/L 2600000
J
2600000
J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26679
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679828
Associated Lab Samples:92288935019
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 20.0 03/05/16 11:4810.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679829LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 24402500 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1679830MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288938001
1679831
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 95 90-11096 0 10250043.3J 2430 2430
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26719
EPA 365.1
EPA 365.1
365.1 Phosphorus, Total
Associated Lab Samples:92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1681816
Associated Lab Samples:92288935019
Matrix:Water
AnalyzedMDL
Phosphorus ug/L ND 50.0 03/11/16 22:0325.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1681817LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus ug/L 25202500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1681818MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288935019
1681819
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 109 90-110105 2 102500111038203740
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1681820MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289194010
1681821
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 102 90-110102 0 1025000.81 mg/L 3360 3350
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 67 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26788
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92288935019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1685541
Associated Lab Samples:92288935019
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 03/14/16 20:2012500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1685542LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 763000750000 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1685543MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289228002
1685544
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M66000000011890-110118 0 36000000011100
mg/L
8210000
0
8210000
0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1685545MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289394003
1685546
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 102 90-110102 0 3750000ND766000766000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analysis initiated outside of the 15 minute EPA required holding time.H6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 69 of 74
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288935001 MPRP/20891 ICP/18813MW-1 EPA 3010A EPA 6010
92288935002 MPRP/20891 ICP/18813MW-2 EPA 3010A EPA 6010
92288935003 MPRP/20891 ICP/18813MW-3 EPA 3010A EPA 6010
92288935004 MPRP/20891 ICP/18813MW-4 EPA 3010A EPA 6010
92288935005 MPRP/20891 ICP/18813MW-5 EPA 3010A EPA 6010
92288935006 MPRP/20891 ICP/18813MW-6 EPA 3010A EPA 6010
92288935007 MPRP/20891 ICP/18813MW-7 EPA 3010A EPA 6010
92288935008 MPRP/20891 ICP/18813MW-8 EPA 3010A EPA 6010
92288935009 MPRP/20891 ICP/18813MW-9 EPA 3010A EPA 6010
92288935010 MPRP/20891 ICP/18813MW-10 EPA 3010A EPA 6010
92288935011 MPRP/20891 ICP/18813MW-11 EPA 3010A EPA 6010
92288935012 MPRP/20891 ICP/18813MW-12 EPA 3010A EPA 6010
92288935013 MPRP/20891 ICP/18813MW-13 EPA 3010A EPA 6010
92288935014 MPRP/20891 ICP/18813MW-14 EPA 3010A EPA 6010
92288935015 MPRP/20892 ICP/18814MW-15 EPA 3010A EPA 6010
92288935016 MPRP/20892 ICP/18814MW-16R EPA 3010A EPA 6010
92288935017 MPRP/20892 ICP/18814SW-4 EPA 3010A EPA 6010
92288935018 MPRP/20892 ICP/18814SW-5 EPA 3010A EPA 6010
92288935019 MPRP/20892 ICP/18814LE-1 EPA 3010A EPA 6010
92288935001 MSV/35828MW-1 EPA 8260
92288935002 MSV/35828MW-2 EPA 8260
92288935003 MSV/35828MW-3 EPA 8260
92288935004 MSV/35828MW-4 EPA 8260
92288935005 MSV/35828MW-5 EPA 8260
92288935006 MSV/35829MW-6 EPA 8260
92288935007 MSV/35829MW-7 EPA 8260
92288935008 MSV/35829MW-8 EPA 8260
92288935009 MSV/35829MW-9 EPA 8260
92288935010 MSV/35829MW-10 EPA 8260
92288935011 MSV/35829MW-11 EPA 8260
92288935012 MSV/35829MW-12 EPA 8260
92288935013 MSV/35829MW-13 EPA 8260
92288935014 MSV/35829MW-14 EPA 8260
92288935015 MSV/35829MW-15 EPA 8260
92288935016 MSV/35829MW-16R EPA 8260
92288935017 MSV/35830SW-4 EPA 8260
92288935018 MSV/35830SW-5 EPA 8260
92288935019 MSV/35830LE-1 EPA 8260
92288935019 WET/43417 WET/43418LE-1 SM 5210B SM 5210B
92288935019 WET/43478LE-1 EPA 9040
92288935019 WETA/26695LE-1 EPA 300.0
92288935019 WETA/26679LE-1 EPA 353.2
92288935019 WETA/26719LE-1 EPA 365.1
92288935019 WETA/26788LE-1 SM 5220D
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 70 of 74
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288935
WAYNE LINED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/15/2016 09:22 AM
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Page 71 of 74
Page 72 of 74
Page 73 of 74
Page 74 of 74
#=CL#
March 10, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92288930
92288930
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92288930001 EB Water 03/03/16 05:30 03/04/16 09:11
92288930002 FB Water 03/03/16 05:40 03/04/16 09:11
92288930003 TB Water 03/03/16 00:00 03/04/16 09:11
REPORT OF LABORATORY ANALYSIS
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Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288930001 EB EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288930002 FB EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288930003 TB EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92288930001 Collected:03/03/16 05:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 18:42 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 18:42 7440-38-203/07/16 18:0010.0 2.5 1
Barium ND ug/L 03/08/16 18:42 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 18:42 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 18:42 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 18:42 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 18:42 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 18:42 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 18:42 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 18:42 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 18:42 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 18:42 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 18:42 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 18:42 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 18:42 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 06:35 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 06:35 107-13-12001.9 1
Benzene ND ug/L 03/06/16 06:35 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 06:35 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 06:35 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 06:35 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 06:35 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 06:35 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 06:35 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 06:35 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 06:35 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 06:35 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 06:35 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 06:35 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 06:35 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 06:35 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 06:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 06:35 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 06:35 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 06:35 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 06:35 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 06:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 06:35 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 06:35 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 06:35 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 06:35 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 06:35 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 06:35 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 06:35 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92288930001 Collected:03/03/16 05:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 06:35 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 06:35 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 06:35 74-88-410.0 0.32 1
Methylene Chloride 1.7 ug/L 03/06/16 06:35 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 06:35 108-10-11000.33 1
Styrene ND ug/L 03/06/16 06:35 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 06:35 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 06:35 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 06:35 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 06:35 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 06:35 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 06:35 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 06:35 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 06:35 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 06:35 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 06:35 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 06:35 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 06:35 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 06:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %03/06/16 06:35 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 06:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92288930002 Collected:03/03/16 05:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 18:45 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 18:45 7440-38-203/07/16 18:0010.0 2.5 1
Barium ND ug/L 03/08/16 18:45 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 18:45 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 18:45 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 18:45 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 18:45 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 18:45 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 18:45 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 18:45 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 18:45 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 18:45 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 18:45 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 18:45 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 18:45 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 06:51 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 06:51 107-13-12001.9 1
Benzene ND ug/L 03/06/16 06:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 06:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 06:51 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 06:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 06:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 06:51 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 06:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 06:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 06:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 06:51 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 06:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 06:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 06:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 06:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 06:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 06:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 06:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 06:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 06:51 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 06:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 06:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 06:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 06:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 06:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 06:51 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 06:51 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 06:51 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92288930002 Collected:03/03/16 05:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 06:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 06:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 06:51 74-88-410.0 0.32 1
Methylene Chloride 1.6 ug/L 03/06/16 06:51 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 06:51 108-10-11000.33 1
Styrene ND ug/L 03/06/16 06:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 06:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 06:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 06:51 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 06:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 06:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 06:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 06:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 06:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 06:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 06:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 06:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 06:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 06:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 06:51 17060-07-070-130 1
Toluene-d8 (S)98 %03/06/16 06:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92288930003 Collected:03/03/16 00:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 07:08 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 07:08 107-13-12001.9 1
Benzene ND ug/L 03/06/16 07:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 07:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 07:08 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 07:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 07:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 07:08 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 07:08 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 07:08 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 07:08 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 07:08 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 07:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 07:08 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 07:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 07:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 07:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 07:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 07:08 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 07:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 07:08 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 07:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 07:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 07:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 07:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 07:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 07:08 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 07:08 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 07:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 03/06/16 07:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 07:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 07:08 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 07:08 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 07:08 108-10-11000.33 1
Styrene ND ug/L 03/06/16 07:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 07:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 07:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 07:08 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 07:08 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 07:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 07:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 07:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 07:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 07:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 07:08 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 07:08 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92288930003 Collected:03/03/16 00:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 03/06/16 07:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %03/06/16 07:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %03/06/16 07:08 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 07:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Huntersville, NC 28078
[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20891
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92288930001, 92288930002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680479
Associated Lab Samples:92288930001, 92288930002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 03/08/16 18:273.8
Arsenic ug/L ND 10.0 03/08/16 18:272.5
Barium ug/L ND 100 03/08/16 18:272.5
Beryllium ug/L ND 1.0 03/08/16 18:270.50
Cadmium ug/L ND 1.0 03/08/16 18:270.50
Chromium ug/L ND 10.0 03/08/16 18:272.5
Cobalt ug/L ND 10.0 03/08/16 18:272.5
Copper ug/L ND 10.0 03/08/16 18:272.5
Lead ug/L ND 10.0 03/08/16 18:272.5
Nickel ug/L ND 50.0 03/08/16 18:272.5
Selenium ug/L ND 10.0 03/08/16 18:275.0
Silver ug/L ND 10.0 03/08/16 18:272.5
Thallium ug/L ND 5.5 03/08/16 18:275.0
Vanadium ug/L ND 25.0 03/08/16 18:272.5
Zinc ug/L ND 10.0 03/08/16 18:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680480LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 468500 94 80-120
Arsenic ug/L 548500 110 80-120
Barium ug/L 552500 110 80-120
Beryllium ug/L 547500 109 80-120
Cadmium ug/L 553500 111 80-120
Chromium ug/L 548500 110 80-120
Cobalt ug/L 554500 111 80-120
Copper ug/L 564500 113 80-120
Lead ug/L 548500 110 80-120
Nickel ug/L 554500 111 80-120
Selenium ug/L 546500 109 80-120
Silver ug/L 228250 91 80-120
Thallium ug/L 537500 107 80-120
Vanadium ug/L 550500 110 80-120
Zinc ug/L 545500 109 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680481MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288741001
1680482
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 85 75-12588 4 25500ND426441
Arsenic ug/L 500 100 75-125103 3 25500ND500515
Barium ug/L 500 103 75-125106 2 255009.6 526 538
Beryllium ug/L 500 103 75-125105 2 25500ND514526
Cadmium ug/L 500 101 75-125105 4 25500ND506524
Chromium ug/L 500 101 75-125105 4 25500ND506528
Cobalt ug/L 500 101 75-125105 4 25500ND505526
Copper ug/L 500 103 75-125108 5 25500ND515540
Lead ug/L 500 100 75-125103 4 25500ND498517
Nickel ug/L 500 101 75-125105 4 25500ND505524
Selenium ug/L 500 100 75-125104 4 25500ND501521
Silver ug/L 250 84 75-12588 4 25250ND211219
Thallium ug/L 500 98 75-125102 3 25500ND492508
Vanadium ug/L 500 101 75-125106 4 25500ND505528
Zinc ug/L 500 99 75-125103 4 25500ND501520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35830
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288930001, 92288930002, 92288930003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288930001, 92288930002, 92288930003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/06/16 04:550.33
1,1,1-Trichloroethane ug/L ND 1.0 03/06/16 04:550.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/06/16 04:550.40
1,1,2-Trichloroethane ug/L ND 1.0 03/06/16 04:550.29
1,1-Dichloroethane ug/L ND 5.0 03/06/16 04:550.32
1,1-Dichloroethene ug/L ND 5.0 03/06/16 04:550.56
1,2,3-Trichloropropane ug/L ND 1.0 03/06/16 04:550.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/06/16 04:552.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/06/16 04:550.27
1,2-Dichlorobenzene ug/L ND 5.0 03/06/16 04:550.30
1,2-Dichloroethane ug/L ND 1.0 03/06/16 04:550.24
1,2-Dichloropropane ug/L ND 1.0 03/06/16 04:550.27
1,4-Dichlorobenzene ug/L ND 1.0 03/06/16 04:550.33
2-Butanone (MEK)ug/L ND 100 03/06/16 04:550.96
2-Hexanone ug/L ND 50.0 03/06/16 04:550.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/06/16 04:550.33
Acetone ug/L ND 100 03/06/16 04:5510.0
Acrylonitrile ug/L ND 200 03/06/16 04:551.9
Benzene ug/L ND 1.0 03/06/16 04:550.25
Bromochloromethane ug/L ND 3.0 03/06/16 04:550.17
Bromodichloromethane ug/L ND 1.0 03/06/16 04:550.18
Bromoform ug/L ND 3.0 03/06/16 04:550.26
Bromomethane ug/L ND 10.0 03/06/16 04:550.29
Carbon disulfide ug/L ND 100 03/06/16 04:551.2
Carbon tetrachloride ug/L ND 1.0 03/06/16 04:550.25
Chlorobenzene ug/L ND 3.0 03/06/16 04:550.23
Chloroethane ug/L ND 10.0 03/06/16 04:550.54
Chloroform ug/L ND 5.0 03/06/16 04:550.14
Chloromethane ug/L ND 1.0 03/06/16 04:550.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.13
Dibromochloromethane ug/L ND 3.0 03/06/16 04:550.21
Dibromomethane ug/L ND 10.0 03/06/16 04:550.21
Ethylbenzene ug/L ND 1.0 03/06/16 04:550.30
Iodomethane ug/L ND 10.0 03/06/16 04:550.32
Methylene Chloride ug/L ND 1.0 03/06/16 04:550.97
Styrene ug/L ND 1.0 03/06/16 04:550.26
Tetrachloroethene ug/L ND 1.0 03/06/16 04:550.46
Toluene ug/L ND 1.0 03/06/16 04:550.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.49
trans-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288930001, 92288930002, 92288930003
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 03/06/16 04:551.0
Trichloroethene ug/L ND 1.0 03/06/16 04:550.47
Trichlorofluoromethane ug/L ND 1.0 03/06/16 04:550.20
Vinyl acetate ug/L ND 50.0 03/06/16 04:550.35
Vinyl chloride ug/L ND 1.0 03/06/16 04:550.62
Xylene (Total)ug/L ND 5.0 03/06/16 04:550.66
1,2-Dichloroethane-d4 (S)%100 70-130 03/06/16 04:55
4-Bromofluorobenzene (S)%97 70-130 03/06/16 04:55
Toluene-d8 (S)%99 70-130 03/06/16 04:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.850 102 80-125
1,1,1-Trichloroethane ug/L 48.750 97 71-129
1,1,2,2-Tetrachloroethane ug/L 49.050 98 79-124
1,1,2-Trichloroethane ug/L 48.550 97 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 52.350 105 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 49.250 98 71-133
1,2-Dibromoethane (EDB)ug/L 52.850 106 83-124
1,2-Dichlorobenzene ug/L 48.650 97 80-133
1,2-Dichloroethane ug/L 47.950 96 67-128
1,2-Dichloropropane ug/L 49.750 99 75-132
1,4-Dichlorobenzene ug/L 52.250 104 78-130
2-Butanone (MEK)ug/L 95.7J100 96 61-144
2-Hexanone ug/L 98.0100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 106100 106 72-135
Acetone ug/L 94.5J100 94 48-146
Acrylonitrile ug/L 260250 104 40-160
Benzene ug/L 50.150 100 80-125
Bromochloromethane ug/L 52.950 106 71-125
Bromodichloromethane ug/L 50.950 102 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.3J50 101 50-160
Carbon tetrachloride ug/L 49.050 98 69-131
Chlorobenzene ug/L 51.250 102 81-122
Chloroethane ug/L 51.150 102 39-148
Chloroform ug/L 48.550 97 73-127
Chloromethane ug/L 38.050 76 44-146
cis-1,2-Dichloroethene ug/L 50.250 100 74-124
cis-1,3-Dichloropropene ug/L 50.350 101 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 50.450 101 78-125
Dibromomethane ug/L 51.650 103 82-120
Ethylbenzene ug/L 50.250 100 79-121
Iodomethane ug/L 50.5100 51 39-154
Methylene Chloride ug/L 46.750 93 64-133
Styrene ug/L 50.250 100 84-126
Tetrachloroethene ug/L 48.850 98 78-122
Toluene ug/L 49.550 99 80-121
trans-1,2-Dichloroethene ug/L 50.550 101 71-127
trans-1,3-Dichloropropene ug/L 47.650 95 69-141
trans-1,4-Dichloro-2-butene ug/L 35.5J50 71 40-160
Trichloroethene ug/L 50.150 100 78-122
Trichlorofluoromethane ug/L 50.750 101 53-137
Vinyl acetate ug/L 97.0100 97 40-160
Vinyl chloride ug/L 50.150 100 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
1,1,1,2-Tetrachloroethane ug/L 20.520 103 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.520 97 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 22.220 111 70-130ND
1,1-Dichloroethene ug/L 24.020 120 70-166ND
1,2,3-Trichloropropane ug/L 21.020 105 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.820 94 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.920 104 70-130ND
1,2-Dichlorobenzene ug/L 19.620 98 70-130ND
1,2-Dichloroethane ug/L 20.920 105 70-130ND
1,2-Dichloropropane ug/L 21.020 105 70-130ND
1,4-Dichlorobenzene ug/L 21.320 107 70-130ND
2-Butanone (MEK)ug/L 39.7J40 99 70-130ND
2-Hexanone ug/L 38.7J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.1J40 105 70-130ND
Acetone ug/L 40.9J40 102 70-130ND
Acrylonitrile ug/L 105J100 105 70-130ND
Benzene ug/L 22.020 110 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 20.620 103 70-130ND
Bromoform ug/L 18.220 91 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
Bromomethane ug/L 9.6J M1204870-130ND
Carbon disulfide ug/L 23.8J20 119 70-130ND
Carbon tetrachloride ug/L 22.320 111 70-130ND
Chlorobenzene ug/L 21.220 106 70-146ND
Chloroethane ug/L 23.720 118 70-130ND
Chloroform ug/L 21.120 105 70-130ND
Chloromethane ug/L 16.820 84 70-130ND
cis-1,2-Dichloroethene ug/L 22.520 113 70-130ND
cis-1,3-Dichloropropene ug/L 19.820 99 70-130ND
Dibromochloromethane ug/L 20.120 100 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 20.820 104 70-130ND
Iodomethane ug/L 14.1 M1403570-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 20.320 101 70-130ND
Tetrachloroethene ug/L 21.520 107 70-130ND
Toluene ug/L 21.120 106 70-155ND
trans-1,2-Dichloroethene ug/L 22.920 115 70-130ND
trans-1,3-Dichloropropene ug/L 19.120 96 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.2J M1205670-130ND
Trichloroethene ug/L 21.520 107 69-151ND
Trichlorofluoromethane ug/L 23.320 116 70-130ND
Vinyl acetate ug/L 28.3J40 71 70-130ND
Vinyl chloride ug/L 23.720 118 70-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 099
4-Bromofluorobenzene (S)%94 498
Toluene-d8 (S)%100 298
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288930001 MPRP/20891 ICP/18813EBEPA 3010A EPA 6010
92288930002 MPRP/20891 ICP/18813FBEPA 3010A EPA 6010
92288930001 MSV/35830EBEPA 8260
92288930002 MSV/35830FBEPA 8260
92288930003 MSV/35830TBEPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 21
Page 20 of 21
Page 21 of 21
Appendix B
Field Sampling Parameter Data Sheet(s)