9601_WayneCounty_GWMR_DIN28165_20160303

Wayne County Active C&D and Closed MSWLF
Dudley, North Carolina
March 2016
MESCO Project Number: G15016.0
Semi-Annual Water Quality Monitoring Report
with Corrective Action Update
Prepared for
Municipal Engineering Services Company, P.A.
Garner and Boone, North Carolina
P.O. Box 97
Garner, NC 27529
License No. C-0281

Permit Number: 96-01
TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedure Page 2
Field Parameter Data Page 2
Laboratory Results Page 2
Quality Control Samples Page 3
Groundwater Samples Page 3
Surface Water Samples Page 3
Corrective Action Update Page 3
Groundwater and Surface Water Characterization Page 3
Findings Page 3
Closing Page 4
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer w/ VOC Detection Above 2L Standard Figure 2
Time-Series Graphs of Select Constituents Figure 3
TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Detections Above SWSL, 2L, 2B, GWP or MCL Table 5
MNA Parameter Data Summary Table 6
Hydrologic Properties at Monitoring Well Locations Table 7
APPENDICIES
Laboratory Analysis Reports and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
August 5, 2016
Ms. Jaclynne Drummond
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality (NCDEQ)
2090 US 70 Highway
Swannanoa, NC 28778
Re: Semi-Annual Water Quality Monitoring Report with Corrective Action Update
Wayne County Active C&D and Closed MSWLF (Dudley)
Permit No. 96-01
MESCO Project No. G15016.0
Event Date(s): March 3, 2016
Introduction
The Wayne County Landfill (Permit #96-01) is located at 460 S Landfill Road (SR 1129), Dudley, Wayne County,
North Carolina. A topographic map showing the location of the site is included as Figure 1.
The Wayne County unlined closed Municipal Solid Waste Landfill (MSWLF) and active Construction and Demolition
(C&D) Landfill located in Dudley NC, currently operating under Permit #96-01 is required to submit semi-annual
compliance reports as a condition of 15A NCAC 13B.1630. This report documents the quality of the ground and
surface waters during this monitoring event performed on March 3, 2016. Laboratory analytical results indicate that
levels of benzene above the regulatory Standard reappeared in sample MW-2 after being absent the previous two
events. No other contaminants attributed to anthropogenic source were detected in any other ground or surface water
sample during this event. Corrective action via monitored natural attenuation (MNA) is planned to continue.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contains sampling procedures, field and laboratory results, corrective action update,
ground/surface water characterization, and findings. Well construction summary table, field observations table, field
parameter data table, sampling and analysis summary table, detections compared to Standards tables, MNA parameter
summary table, a groundwater flow directions/rates table, potentiometric map, time-series graph, quality
assurance/quality control data, and laboratory analytical data results are enclosed herein.
Background
Prior to operating as a C&D landfill the site operated as a Municipal Solid Waste (MSW) unlined sanitary landfill that
consisted of two units. The first unit (Unit 1) was closed prior to October 1991 with a 24 inch final soil cover. The
second unit (Unit 2) was closed with a low permeability cohesive cap and erosive layer prior to December 31, 1998 in
accordance with the Transition Plan. The C&D landfill is operating on top of the Unit 2 MSW landfill. The separate
active Subtitle D Lined MSWLF (permit #96-06), located adjacent to the C&D landfill across an unnamed tributary of
Edward's Branch, was monitored in conjunction with this site but reported separately.
Water quality at this landfill has been monitored at least semi-annually since 1991. Current data was compared to data
compiled since 1994 in support of this report. Municipal Engineering Services Company, P.A. (MESCO) submitted an
Assessment and Corrective Action (ACM) [DIN8821] report dated August 30, 2007 which was approved by the NC
Solid Waste Section (SWS) on November 1, 2007 [DIN3328]. MESCO then developed a Corrective Action Plan
(CAP) [DIN8821] on October 22, 2009 which was approved by the SWS on October 23, 2009 [DIN8822].
Groundwater remediation using Monitored Natural Attenuation (MNA) was initiated on August 6, 2009 and has
continued on a semi-annual basis.
Following establishment of the two year MNA baseline, MESCO completed a Corrective Action Evaluation Report
(CAER) [DIN 13923] on May 10, 2011. The CAER was reviewed and the proposed modifications of MNA parameters
and frequency were approved by the SWS [DIN 16967]. Background well MW-1 was abandoned and replaced by MW-
1R as pre-authorized by SWS [DIN 19050] on June 4, 2013. MESCO submitted a Request for Appendix II Groundwater
Monitoring Modification dated April 24, 2014 which was approved by the SWS. The Water Quality Sampling and
Analysis Plan (SAP) which provides for a subset of wells to decrease Appendix II monitoring frequency was revised and
submitted on December 15, 2014 as requested by Ms. Christine Ritter of the SWS. Groundwater remediation through
MNA per the CAP is scheduled to continue provided there is no change directed by the SWS.
Sampling Procedure
MESCO performed this sampling event utilizing portable monitoring methodology in accordance with the approved SAP
based on the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April 2008.
The new site-specific SAP entails continued semi-annual water quality monitoring which includes annual corrective
action monitoring and targeting of specific Appendix II constituents at a subset of wells once every three years. Keeping
with the established schedule this event consists of detection monitoring (Appendix I) at all locations and MNA
monitoring at MW-2, MW-8 and background well MW-1R. Water samples were collected from monitoring locations
designated in the SAP with the exception of SW-3 which is chronically dry. Water quality monitoring was performed on
ten wells (MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and MW-11), background well (MW-
1R) and two surface water points (SW-1, SW-2). Quality control measures implemented during this event included
quantification of an equipment blank (EB), field blank (FB) and travel blank (TB). A supplemental surface water sample
(SW-By_MW-2) was collected from the western tributary of Edward's Branch directly downgradient of MW-2. Data
from two surface water locations from the Subtitle D Lined SAP SW-2 (shared) and SW-3 (shared) are presented because
this local discharge feature is shared by both permits. Monitoring locations are depicted on the potentiometric map,
included as Figure 2.
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity
of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table 2. The depth
to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Low-flow
pumping methodology or bailing was utilized to adequately purge the wells a minimum of three times the volume of
standing water in the well or until dry. Surface water samples were dipped from the surface of the creeks at previously
designated locations. Samples were then placed into laboratory-prepared, pre-preserved containers. Samples were kept
on ice and transported to a NC-certified laboratory under proper chain of custody (C-O-C) protocol and analyzed within
the required hold times.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
dissolved oxygen (DO), oxidation reduction potential (ORP), dissolved carbon dioxide (CO2), total dissolved solids
(TDS) and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is
enclosed in Appendix B.
Laboratory Results
Pace Analytical Laboratories (PACE) performed the laboratory analysis. All samples were analyzed for Appendix I
constituents listed in 40 CFR 258 and three wells were tested for MNA performance parameters. A sampling and
analysis table summarizing the locations, targeted constituents and methods is presented as Table 4. Laboratory results
and C-O-Cs are contained in Appendix A.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below the
current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and surface water
samples that attain or were above the current SWSL, SWS adopted Groundwater Protection Standards (GWP), North
Carolina Groundwater Standards (2L), the applicable North Carolina Surface Water Standards (2B) for a Class C
waterbody and Federal Maximum Contaminant Levels (MCL) also known as “Primary Drinking Water Standards”.
2
Quality Control Samples
Methylene chloride was detected in FB and EB and qualified by the laboratory as C9 “common laboratory contaminant”.
Since neither methylene chloride nor it's biodegradation byproducts were detected in any ground or surface water samples
any potential artifact contamination is non-consequential.
Groundwater Samples
Total cadmium was detected in samples MW-10 (4.2 µg/L), MW-11 (7.9 µg/L) and background well MW-1R (7.6 µg/L)
above the 2L Standard (2.0 µg/L). Total vanadium was detected in samples MW-3 (4.3 µg/L), MW-5 (4.7 µg/L), MW-
11 (16.7 µg/L) and background well MW-1R (6.2 µg/L) above the GWP Standard (3.5 µg/L) but below the SWSL (25
µg/L) thus “j-qualified”.
During this event benzene was detected in sample MW-2 at 1.4 µg/L which is above the regulatory compliance 2L
Standard (1.0 µg/L) and below the Drinking Water Standard (5.0 µg/L).
Surface Water Samples
Constituents were not detected in any surface water sample in concentrations above the established 2B Standards.
Supplemental surface water sample SW-By_MW-2 collected at the property line approximately 166 feet hydraulically
downgradient of MW-2 continues to lack contaminants.
Corrective Action Update
Groundwater remediation measures through MNA continues to be implemented at the facility. Semi-annual MNA
monitoring of MW-2, MW-8 and background well MW-1 was initiated on August 6, 2009 and was consistently
performed for the full suite of SWS recommended parameters for six consecutive semi-annual events. The SAP
prescribes MNA monitoring for specific constituents to be performed annually or bi-annually. Keeping with established
SAP select MNA parameters were analyzed during this event as presented on Table 6.
The active Landfill Gas Collection and Control System (GCCS) continues operations. The GCCS extracts LFG for
energy production therefore is closely maintained for optimum efficiency which may have a collateral remediation effect
on groundwater.
Groundwater and Surface Water Characterization
A potentiometric map of the uppermost aquifer created from groundwater elevation data collected during this event is
included as Figure 2. Groundwater flow rates and directions were calculated based on collected data and are included in
Table 6. Groundwater generally generally flows southwesterly towards Edward's Branch ranging from approximately 3
foot/year (MW-5) to 74 feet/year (MW-3) with an average rate of 34 feet/year The calculated flow directions and
gradients are consistent with historical observations. Streams located within the facility boundaries were visually
observed at moderate seasonal flow, moderate volume and low turbidity. A sample was collected from surface water
point SW-2 which is a rarity since the designated upstream headwater site is typically observed to be dry.
Findings
Benzene was detected in MW-2 in levels above 2L Standard after falling below the previous two semi-annual events.
Benzene in MW-2 has been the only VOC detected in excess of regulatory compliance Standards since 2007 (Figure 3).
The horizontal plume extent downgradient of MW-2 appears to have not impacted the adjacent local discharge feature as
evidenced by the lack of detections in surface water samples SW-By_MW-2 and SW-1.
Groundwater quality monitored by MW-8, located hydraulically upgradient of waste, has improved significantly since the
ACM was drafted as evidenced by the lack of contaminant detections in levels exceeding the 2L Standard during the past
8.5 years. The single contaminant of concern detected above 2L in MW-8 since ACM (1,4-dichlorobenzene) has not been
detected at a concentration above its current 2L Standard since August 2007 (Figure 3). Samples collected from MW-9
and MW-10, installed to delineate the impact beyond MW-8, continue to lack detections.
3
Figures
Topographic Map with Site Location
01 1 MILE
FIGURE 1
Wayne County Landfill North Carolina (Dudley)
CLOSED MSW FACILITY
SUBTITLE D MSW
LANDFILL FACILITY
460 B South Landfill Rd
Dudley, NC 28333
Lat:35-17-19.1338
Long:-78-04-17.2971
Northing:561283.19
Easting:2277068.62
N
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Figure 3
Time-Series Graphs of Select Constituents
September 8, 1994 - March 3, 2016
Non-Detects Shown at Method Detection Level.
2L
2L
2L
2L
2L NC Groundwater Standard
MCL
MCL “Drinking Water Standard”
50
Tables
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
March 3, 2016
Latitude Longitude
(inches)(ft)
MW-1R 6/4/13 2 27.32 12.32 15 Soil Sand 169.64 166.64 152.09 17.55 35.292408 -78.064431
MW-2 8/28/90 2 15 10 5 Soil Sand 134.52 132.78 130.34 4.18 35.290714 -78.076225
MW-3 8/27/90 2 18 12 6 Soil Sand 134.81 133.03 133.98 0.83 35.293192 -78.072156
MW-4 8/28/90 2 15 10 5 Soil Sand 150.20 148.17 144.31 5.89 35.293003 -78.066253
MW-5 8/31/94 2 18 3 15 Soil Sand 124.78 120.56 124.78 0.00 35.292597 -78.075936
MW-6 8/31/94 2 18.14 3.14 15 Soil Sand 145.53 143.62 141.02 4.51 35.293439 -78.068656
MW-7 8/31/94 2 19 4 15 Soil Sand 143.59 140.74 139.80 3.79 35.288761 -78.074700
MW-8 8/30/94 2 29 14 15 Soil Sand 161.88 160.88 146.04 15.84 35.290178 -78.068706
MW-9 7/9/09 2 25 10 15 Soil Sand 162.96 159.78 147.14 15.82 35.290025 -78.068242
MW-10 7/9/09 2 25 10 15 Soil Sand 162.90 160.01 149.98 12.92 35.289869 -78.069167
MW-11 7/9/09 2 15 5 10 Soil Sand 127.23 124.50 126.11 1.12 35.291844 -78.076250
NOTE:
Monitoring
Well
Date
Installed
Well Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen Length Geology of
Screened
Interval
Top of
Casing
Elevation
Ground Elevation Groundwater Elevation Depth to Water
(ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Wayne County Active C&D and Closed MSWLF Page 1 of 1
Table 2
Field Observations of Monitoring Locations
March 3, 2016
Locked Comments
MW-1R Yes Yes Yes Yes Yes Yes
MW-2 Yes Yes Yes Yes Yes Yes
MW-3 Yes Yes Yes Yes Yes Yes Flowing artesian, lock rusting
MW-4 Yes Yes Yes Yes Yes Yes
MW-5 Yes Yes Yes Yes Yes Yes Flowing artesian, hinge rusting
MW-6 Yes Yes Yes Yes Yes Yes Hear water cascade into well
MW-7 Yes Yes Yes Yes Yes Yes
MW-8 Yes Yes Yes Yes Yes Yes
MW-9 Yes Yes Yes Yes Yes Yes
MW-10 Yes Yes Yes Yes Yes Yes
MW-11 Yes Yes Yes Yes Yes Yes Flowing artesian, lock rusting
SW-1 Yes -----Shared Downstream of SW-3
SW-2 Yes -----Upstream nearest MW-7. Typically dry
SW-2 Yes -----Shared nearest lined MW-2
SW-3 Yes -----Shared downstream of SW-2
SW-3 No -----Dry-Shared Upstream nearest MW-4
SW-By _MW-2 Yes -----Not required but supplemental sample
Any unusual field conditions, observations, or events:
All wells with the exception of MW-1R and MW-4 have been painted blue by the County since August 2013.
Wells have had sediment removed from concrete pads surrounding wells by County since August 2013.
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Effective
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 3
Field Parameter Data Summary
March 3, 2016
Parameter Temp.ORP DO pH TDS Turbidity
Units C mg/L SU mg/L NTU or Visual
MW-1R 17.55 152.08 169.63 15.8 313 5.9 6.13 0 0 323
MW-2 4.18 130.34 134.52 14.1 -41 0.7 6.83 1280 640 132
MW-3 0.83 133.98 134.81 12.9 233 2.3 5.41 10 0 Slight
MW-4 5.89 144.31 150.20 14.7 241 2.2 5.99 0 0 Clear
MW-5 0.00 124.78 124.78 15.1 219 2.1 5.63 100 40 Slight
MW-6 4.51 141.02 145.53 14.9 143 2.3 5.42 90 40 Clear
MW-7 3.79 139.80 143.59 14.8 327 2.4 5.51 80 40 Clear
MW-8 15.84 146.04 161.88 14.9 341 2.9 5.17 10 0 71
MW-9 15.82 147.14 162.96 15.1 341 3.8 5.19 50 20 Moderate
MW-10 12.92 149.98 162.90 13.8 310 5.2 5.19 60 30 Moderate
MW-11 1.12 126.11 127.23 9.9 119 4.8 5.83 1180 590 Moderate
Minimum 0.00 124.78 124.78 9.9 -41 0.7 5.17 0 0 Clear
Average 7.50 139.60 147.09 14.2 231 3.1 5.66 260 127 Slight
Maximum 17.55 152.08 169.63 15.8 341 5.9 6.83 1280 640 Moderate
SW-1 ---8.1 189 4.9 6.97 80 40 Clear
SW-2(C)---7.9 199 5.1 6.93 80 40 Slight
SW-2 ---7.8 193 5.1 6.99 80 40 Clear
---8.9 191 5.6 6.92 70 30 Clear
SW-3 ---7.7 193 5.2 6.94 80 40 Clear
Minimum ---7.7 189 4.9 6.92 70 30 Clear
Average ---8.1 193 5.2 6.95 78 38 Clear
Maximum ---8.9 199 5.6 6.99 80 40 Slight
NR = No reading attempted
(C)=Indicates SW-2 Closed (upstream near MW-7), Not to be confused with SW-2 which is shared between lined and closed.
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
ft (btoc)ft (amsl)ft (amsl)mV umhos/cm
SW-ByMW-2
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 4
Sampling and Analysis Summary
March 3, 2016
Field Parameter MNA
To
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1
4
MW-1R x x x x x x x x x x x x x x x x x x
MW-2 x x x x x x x x x x x x x x x x x x
MW-3 x x x x x x x x
MW-4 x x x x x x x x
MW-5 x x x x x x x x
MW-6 x x x x x x x x
MW-7 x x x x x x x x
MW-8 x x x x x x x x x x x x x x x x x x x
MW-9 x x x x x x x x
MW-10 x x x x x x x x
MW-11 x x x x x x x x
SW-1 x x x x x x
SW-2 x x x x x x
SW-2 (shared)x x x x x x
x x x x x
SW-3 (shared)x x x x x x
SW-3 Not sampled since dry which is typical for this location
EB x x
FB x x
TB x
App. I App II
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SW-ByMW-2
App I & II = Appendix I & II List from current 40 CFR 258
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 2
Table 5
Detections in Water Samples above SWSL, 2L, 2B, GWP or MCL
March 3, 2016
Sample ID Result Unit
MW-1R Zinc, total 3/3/16 11 5 10 1000 NE
MW-1R Vanadium, total 3/3/16 6.2J 2.5 25 NE 3.5 NE
MW-1R Cadmium, total 3/3/16 7.6 0.5 1 2 5 N & B
MW-2 Benzene 3/3/16 1.4 0.25 1 1 5 L &/or LFG
MW-2 Barium, total 3/3/16 170 2.5 100 700 2000
MW-2 3/3/16 3.2 0.33 1 6 75
MW-2 Cobalt, total 3/3/16 26.6 2.5 10 70 NE
MW-2 3/3/16 13.4 0.23 3 50 100
MW-3 Vanadium, total 3/3/16 4.3J 2.5 25 NE 3.5 NE
MW-3 Zinc, total 3/3/16 10.6 5 10 1000 NE
MW-3 Cadmium, total 3/3/16 1.7 0.5 1 2 5
MW-5 Zinc, total 3/3/16 10.2 5 10 1000 NE
MW-5 Vanadium, total 3/3/16 4.7J 2.5 25 NE 3.5 NE
MW-7 Cadmium, total 3/3/16 1.8 0.5 1 2 5
MW-10 Cadmium, total 3/3/16 4.2 0.5 1 2 5 N
MW-10 Barium, total 3/3/16 407 2.5 100 700 2000
MW-10 Zinc, total 3/3/16 18.6 5 10 1000 NE
MW-11 Barium, total 3/3/16 167 2.5 100 700 2000
MW-11 Cadmium, total 3/3/16 7.9 0.5 1 2 5 N
MW-11 Vanadium, total 3/3/16 16.7J 2.5 25 NE 3.5 NE
SW-2(Closed)Zinc, total 3/3/16 15.3 5 10 50 NE
SW-2(Closed)Cadmium, total 3/3/16 1 0.5 1 2 5
SW-2(Shared)Vanadium, total 3/3/16 3.7J 2.5 25 NE NE
SW-2(Shared)Zinc, total 3/3/16 15.6 5 10 50 NE
Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
ug/L
ug/L
ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
Chlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Wayne County Active C&D and Closed MSWLF (Dudley)Page 2 of 2
Sample ID Result UnitParameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
EB Methylene Chloride 3/3/16 1.7 (C9)0.97 1 4.6 5
FB Methylene Chloride 3/3/16 1.6 (C9)0.97 1 4.6 5
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to EMRF instructions.
J=The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
(C9)= Laboratory flagged as “Common laboratory contaminant”
N = Natural originating from erosion of natural deposits. Source not anthropogenic.
L = Leachate
LFG = Landfill Gas
BOLD = Concentration > 2L, 2B, GWP or MCL Standard
ug/L
ug/L
1 Table contains constituents listed in 40CFR Appendix I detected at or above SWSL, GWP, 2L, 2B or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 2B = North Carolina 15 NCAC 2B Surface Water Quality Standard for this Specific Stream Classification
6 GWP = Groundwater Protection Standard
7 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
8 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard.
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 6
MNA Parameter Data Summary
March 3, 2016
Parameters Method MDL*Units
MW-1R MW-2 MW-8
03/03/16 03/03/16 03/03/16
VFA – Acetic Acid AM23G NS NS NS NS
AM23G NS NS NS NS
AM23G NS NS NS NS
AM23G NS NS NS NS
AM23G NS NS NS NS
VFA – Lactic Acid AM23G NS NS NS NS
AM23G NS NS NS NS
AM23G NS NS NS NS
AM23G NS NS NS NS
Hydrogen AM20GAX NS NS NS NS
Methane AM20GAX NS NS NS NS
AM20GAX NS NS NS NS
Ethane AM20GAX NS NS NS NS
CO2-Dissolved 0 mg/L 30 >100 >100
Alkalinity SM 2320B 1000 <1000 555000 <1000
Sulfate EPA 300.0 1000 1200 j 12100 j 2880 j
Sulfide SM 4500-S2D 100 <100 <100 <100
Chloride SM 4500-Cl-E 500 3270 87100 6880
TOC SM 5310B 500 808 j 22900 1130
COD SM 5220D 12500 <12500 81000 <12500
BOD SM 5210B NS NS NS NS
Iron, ferrous SM 3500-Fe B 0.5 <0.5 4.2 <0.5
Nitrate EPA 353.2 10 43.3 j 72.7 j 805 j
Temperature Field Instrument 0 Degrees C 15.8 14.1 14.9
ORP Field Instrument -900 313 -41 341
DO Field Instrument 0 5.9 0.7 2.9
pH Field Instrument 0.00 SU 6.13 6.83 5.17
Specific Conductance Field Instrument 0 0 1280 10
Turbidity Field Instrument 1.00 NTU 297 132 71
Notes:
VFA = Volatile Fatty Acids
MDL* = Lowest Method Detection Limit for Lab Parameters or Lowest Field Measurement Possible
>100 = CO2 Concentration Exceeds Maximum capability of Method Used
Constituents Below Quantization Limit are shown as <MDL value
NS = Not Sampled as not required during this specific event.
ug/L
VFA – Butyric Acid ug/L
VFA – Hexanoic Acid ug/L
VFA – i-Hexanoic Acid ug/L
VFA – i-Pentanoic Acid ug/L
ug/L
VFA – Pentaonic Acid ug/L
VFA – Propionic Acid ug/L
VFA – Pyruvic Acid ug/L
nM
ug/L
Ethene ug/L
ug/L
Field Hach Kit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mV
ug/L
uMhos
Wayne County Active C&D and Closed MSWLF (Dudley)Page 1 of 1
Table 7
March 3, 2016
Linear Velocity
(cm/sec)(%)(ft/ft)(ft/yr)
MW-1R 20 0.213 N69W 17.55 152.09
MW-2 3.00E-04 20 0.043 66 N68W 4.18 130.34
MW-3 6.40E-03 20 0.0022 74 N38W 0.83 133.98
MW-4 9.90E-04 20 0.007 36 N15W 5.89 144.31
MW-5 3.10E-05 20 0.018 3 N37W 0.00 124.78
MW-6 1.60E-04 20 0.015 12 N23W 4.51 141.02
MW-7 7.30E-05 20 0.008 3 N71W 3.79 139.80
MW-8 3.40E-04 20 0.026 47 N14E 15.84 146.04
Minimum 3.10E-05 20 0.002 3 -0.00 124.78
Average 1.18E-03 20 0.042 34 -6.57 139.05
Maximum 6.40E-03 20 0.213 74 -17.55 152.09
NOTE: Data for conductivities and effective porosity obtained from GAI Consultants' Water Sampling Report (January, 1995).
where
Hydrologic Properties at Monitoring Well Locations
Monitoring
Well
Hydraulic
Conductivity
Effective
Porosity
Hydraulic
Gradient Flow
Direction
Depth to
Groundwater
Groundwater
Potentiometric
Elevation
(ft btoc)(ft amsl)
na na
Hydrologic Gradient from groundwater elevations recorded on March 3, 2016.
Linear Velocity (Q) is defined by modified Darcy's equation:
K = hydraulic conductivity
ne = effective porosity
dh = head difference
dl = horizontal distance
dl
dh
n
KQ
e
-=
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
March 14, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92288938
92288938
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE CLOSED LF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 1 of 51
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 51
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Lab ID Sample ID Matrix Date Collected Date Received
92288938001 MW-1R Water 03/03/16 14:40 03/04/16 09:11
92288938002 MW-2 Water 03/03/16 15:50 03/04/16 09:11
92288938003 MW-8 Water 03/03/16 15:10 03/04/16 09:11
92288938004 MW-3 Water 03/03/16 13:15 03/04/16 09:11
92288938005 MW-4 Water 03/03/16 12:55 03/04/16 09:11
92288938006 MW-5 Water 03/03/16 14:00 03/04/16 09:11
92288938007 MW-6 Water 03/03/16 12:30 03/04/16 09:11
92288938008 MW-7 Water 03/03/16 11:30 03/04/16 09:11
92288938009 MW-9 Water 03/03/16 11:00 03/04/16 09:11
92288938010 MW-10 Water 03/03/16 10:35 03/04/16 09:11
92288938011 MW-11 Water 03/03/16 13:40 03/04/16 09:11
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 51
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288938001 MW-1R EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
SM 2320B 1 PASI-ATEP
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AWRC
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92288938002 MW-2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
SM 2320B 1 PASI-ATEP
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AWRC
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92288938003 MW-8 EPA 6010 15 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 50 PASI-CNB
SM 2320B 1 PASI-ATEP
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AWRC
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92288938004 MW-3 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938005 MW-4 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938006 MW-5 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 4 of 51
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288938007 MW-6 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938008 MW-7 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938009 MW-9 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938010 MW-10 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288938011 MW-11 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 5 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-1R Lab ID:92288938001 Collected:03/03/16 14:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:07 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:07 7440-38-203/07/16 18:0010.0 2.5 1
Barium 11.8J ug/L 03/09/16 00:07 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:07 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 7.6 ug/L 03/09/16 00:07 7440-43-903/07/16 18:001.0 0.50 1
Chromium 4.3J ug/L 03/09/16 00:07 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:07 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:07 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:07 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:07 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:07 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:07 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:07 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 6.2J ug/L 03/09/16 00:07 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 11.0 ug/L 03/09/16 00:07 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 08:47 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 08:47 107-13-12001.9 1
Benzene ND ug/L 03/06/16 08:47 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 08:47 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 08:47 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 08:47 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 08:47 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 08:47 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 08:47 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 08:47 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 08:47 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 08:47 75-00-310.0 0.54 1
Chloroform 0.57J ug/L 03/06/16 08:47 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 08:47 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 08:47 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 08:47 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 08:47 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 08:47 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 08:47 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 08:47 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 08:47 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 08:47 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 08:47 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 08:47 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 08:47 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 08:47 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 08:47 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 08:47 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 08:47 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 6 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-1R Lab ID:92288938001 Collected:03/03/16 14:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 08:47 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 08:47 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 08:47 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 08:47 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 08:47 108-10-11000.33 1
Styrene ND ug/L 03/06/16 08:47 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 08:47 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 08:47 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 08:47 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 08:47 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 08:47 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 08:47 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 08:47 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 08:47 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 08:47 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 08:47 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 08:47 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 08:47 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 08:47 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %03/06/16 08:47 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 08:47 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 03/13/16 16:20500010001
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous ND mg/L 03/08/16 09:58 H1,N20.50 0.50 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 03/08/16 10:50 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1200J ug/L 03/08/16 14:07 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 43.3J ug/L 03/05/16 11:511000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3270 ug/L 03/08/16 17:50 16887-00-610005001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 03/10/16 20:0025000125001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-1R Lab ID:92288938001 Collected:03/03/16 14:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 808J ug/L 03/09/16 13:04 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-2 Lab ID:92288938002 Collected:03/03/16 15:50 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:10 7440-36-003/07/16 18:006.0 3.8 1
Arsenic 5.3J ug/L 03/09/16 00:10 7440-38-203/07/16 18:0010.0 2.5 1
Barium 170 ug/L 03/09/16 00:10 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:10 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/09/16 00:10 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:10 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt 26.6 ug/L 03/09/16 00:10 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:10 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:10 7439-92-103/07/16 18:0010.0 2.5 1
Nickel 6.9J ug/L 03/09/16 00:10 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:10 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:10 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:10 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 3.1J ug/L 03/09/16 00:10 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 5.5J ug/L 03/09/16 00:10 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 09:04 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 09:04 107-13-12001.9 1
Benzene 1.4 ug/L 03/06/16 09:04 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 09:04 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 09:04 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 09:04 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 09:04 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 09:04 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 09:04 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 09:04 56-23-51.0 0.25 1
Chlorobenzene 13.4 ug/L 03/06/16 09:04 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 09:04 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 09:04 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 09:04 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 09:04 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 09:04 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 09:04 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 09:04 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.31J ug/L 03/06/16 09:04 95-50-15.0 0.30 1
1,4-Dichlorobenzene 3.2 ug/L 03/06/16 09:04 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 09:04 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 09:04 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 09:04 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 09:04 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 09:04 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 09:04 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 09:04 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 09:04 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 09:04 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
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[phone]
Page 9 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-2 Lab ID:92288938002 Collected:03/03/16 15:50 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 09:04 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 09:04 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 09:04 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 09:04 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 09:04 108-10-11000.33 1
Styrene ND ug/L 03/06/16 09:04 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 09:04 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 09:04 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 09:04 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 09:04 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 09:04 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 09:04 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 09:04 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 09:04 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 09:04 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 09:04 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 09:04 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 09:04 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 09:04 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 09:04 17060-07-070-130 1
Toluene-d8 (S)98 %03/06/16 09:04 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 555000 ug/L 03/13/16 16:28500010001
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous 4.2 mg/L 03/08/16 09:58 H1,N21.0 1.0 2
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 03/08/16 10:50 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 12100J ug/L 03/08/16 14:21 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 72.7J ug/L 03/05/16 11:571000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 87100 ug/L 03/08/16 17:51 16887-00-6500025005
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 81000 ug/L 03/10/16 20:0025000125001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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Page 10 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-2 Lab ID:92288938002 Collected:03/03/16 15:50 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 22900 ug/L 03/09/16 13:46 7440-44-0200010002
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 11 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-8 Lab ID:92288938003 Collected:03/03/16 15:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:22 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:22 7440-38-203/07/16 18:0010.0 2.5 1
Barium 27.6J ug/L 03/09/16 00:22 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:22 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/09/16 00:22 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:22 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:22 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:22 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:22 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:22 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:22 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:22 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:22 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:22 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/09/16 00:22 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/11/16 13:48 7439-97-603/09/16 16:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 09:21 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 09:21 107-13-12001.9 1
Benzene ND ug/L 03/06/16 09:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 09:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 09:21 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 09:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 09:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 09:21 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 09:21 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 09:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 09:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 09:21 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 09:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 09:21 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 09:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 09:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 09:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 09:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 09:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 09:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 09:21 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 09:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 09:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 09:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 09:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 09:21 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 12 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-8 Lab ID:92288938003 Collected:03/03/16 15:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 03/06/16 09:21 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 09:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 09:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 03/06/16 09:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 09:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 09:21 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 09:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 09:21 108-10-11000.33 1
Styrene ND ug/L 03/06/16 09:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 09:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 09:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 09:21 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 09:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 09:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 09:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 09:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 09:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 09:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 09:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 09:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 09:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 09:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 09:21 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 09:21 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 03/13/16 16:40500010001
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous ND mg/L 03/08/16 09:58 H1,N20.50 0.50 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 03/08/16 10:50 18496-25-810001001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 2880J ug/L 03/08/16 14:35 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 805J ug/L 03/05/16 11:561000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 6880 ug/L 03/08/16 17:55 16887-00-6200010002
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-8 Lab ID:92288938003 Collected:03/03/16 15:10 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 03/10/16 20:0025000125001
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1130 ug/L 03/09/16 13:58 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-3 Lab ID:92288938004 Collected:03/03/16 13:15 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:25 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:25 7440-38-203/07/16 18:0010.0 2.5 1
Barium 16.6J ug/L 03/09/16 00:25 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:25 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 1.7 ug/L 03/09/16 00:25 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:25 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:25 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:25 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:25 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:25 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:25 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:25 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:25 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 4.3J ug/L 03/09/16 00:25 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 10.6 ug/L 03/09/16 00:25 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 09:37 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 09:37 107-13-12001.9 1
Benzene ND ug/L 03/06/16 09:37 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 09:37 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 09:37 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 09:37 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 09:37 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 09:37 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 09:37 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 09:37 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 09:37 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 09:37 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 09:37 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 09:37 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 09:37 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 09:37 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 09:37 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 09:37 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 09:37 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 09:37 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 09:37 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 09:37 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 09:37 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 09:37 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 09:37 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 09:37 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 09:37 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 09:37 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 09:37 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-3 Lab ID:92288938004 Collected:03/03/16 13:15 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 09:37 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 09:37 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 09:37 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 09:37 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 09:37 108-10-11000.33 1
Styrene ND ug/L 03/06/16 09:37 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 09:37 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 09:37 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 09:37 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 09:37 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 09:37 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 09:37 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 09:37 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 09:37 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 09:37 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 09:37 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 09:37 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 09:37 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 09:37 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %03/06/16 09:37 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 09:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-4 Lab ID:92288938005 Collected:03/03/16 12:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:28 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:28 7440-38-203/07/16 18:0010.0 2.5 1
Barium 92.5J ug/L 03/09/16 00:28 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:28 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/09/16 00:28 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:28 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:28 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:28 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:28 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:28 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:28 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:28 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:28 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:28 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/09/16 00:28 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 09:54 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 09:54 107-13-12001.9 1
Benzene ND ug/L 03/06/16 09:54 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 09:54 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 09:54 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 09:54 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 09:54 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 09:54 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 09:54 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 09:54 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 09:54 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 09:54 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 09:54 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 09:54 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 09:54 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 09:54 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 09:54 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 09:54 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 09:54 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 09:54 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 09:54 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 09:54 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 09:54 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 09:54 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 09:54 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 09:54 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 09:54 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 09:54 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 09:54 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 17 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-4 Lab ID:92288938005 Collected:03/03/16 12:55 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 09:54 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 09:54 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 09:54 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 09:54 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 09:54 108-10-11000.33 1
Styrene ND ug/L 03/06/16 09:54 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 09:54 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 09:54 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 09:54 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 09:54 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 09:54 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 09:54 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 09:54 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 09:54 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 09:54 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 09:54 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 09:54 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 09:54 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 09:54 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %03/06/16 09:54 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 09:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-5 Lab ID:92288938006 Collected:03/03/16 14:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:31 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:31 7440-38-203/07/16 18:0010.0 2.5 1
Barium 31.7J ug/L 03/09/16 00:31 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:31 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/09/16 00:31 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:31 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:31 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:31 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:31 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:31 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:31 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:31 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:31 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 4.7J ug/L 03/09/16 00:31 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 10.2 ug/L 03/09/16 00:31 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 10:10 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 10:10 107-13-12001.9 1
Benzene ND ug/L 03/06/16 10:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 10:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 10:10 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 10:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 10:10 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 10:10 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 10:10 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 10:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 10:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 10:10 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 10:10 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 10:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 10:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 10:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 10:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 10:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 10:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 10:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 10:10 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 10:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 10:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 10:10 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 10:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 10:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 10:10 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 10:10 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 10:10 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-5 Lab ID:92288938006 Collected:03/03/16 14:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 10:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 10:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 10:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 10:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 10:10 108-10-11000.33 1
Styrene ND ug/L 03/06/16 10:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 10:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 10:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 10:10 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 10:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 10:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 10:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 10:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 10:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 10:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 10:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 10:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 10:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 10:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 10:10 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 10:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-6 Lab ID:92288938007 Collected:03/03/16 12:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:34 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:34 7440-38-203/07/16 18:0010.0 2.5 1
Barium 29.8J ug/L 03/09/16 00:34 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:34 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.85J ug/L 03/09/16 00:34 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:34 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:34 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:34 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:34 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:34 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:34 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:34 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:34 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:34 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 8.7J ug/L 03/09/16 00:34 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 10:27 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 10:27 107-13-12001.9 1
Benzene ND ug/L 03/06/16 10:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 10:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 10:27 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 10:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 10:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 10:27 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 10:27 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 10:27 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 10:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 10:27 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 10:27 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 10:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 10:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 10:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 10:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 10:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 10:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 10:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 10:27 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 10:27 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 10:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 10:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 10:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 10:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 10:27 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 10:27 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 10:27 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-6 Lab ID:92288938007 Collected:03/03/16 12:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 10:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 10:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 10:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 10:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 10:27 108-10-11000.33 1
Styrene ND ug/L 03/06/16 10:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 10:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 10:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 10:27 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 10:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 10:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 10:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 10:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 10:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 10:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 10:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 10:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 10:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 10:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 10:27 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 10:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-7 Lab ID:92288938008 Collected:03/03/16 11:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:37 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:37 7440-38-203/07/16 18:0010.0 2.5 1
Barium 28.2J ug/L 03/09/16 00:37 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:37 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 1.8 ug/L 03/09/16 00:37 7440-43-903/07/16 18:001.0 0.50 1
Chromium 2.8J ug/L 03/09/16 00:37 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:37 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:37 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:37 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:37 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:37 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:37 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:37 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:37 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/09/16 00:37 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 10:44 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 10:44 107-13-12001.9 1
Benzene ND ug/L 03/06/16 10:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 10:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 10:44 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 10:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 10:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 10:44 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 10:44 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 10:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 10:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 10:44 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 10:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 10:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 10:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 10:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 10:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 10:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 10:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 10:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 10:44 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 10:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 10:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 10:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 10:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 10:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 10:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 10:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 10:44 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-7 Lab ID:92288938008 Collected:03/03/16 11:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 10:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 10:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 10:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 10:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 10:44 108-10-11000.33 1
Styrene ND ug/L 03/06/16 10:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 10:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 10:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 10:44 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 10:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 10:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 10:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 10:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 10:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 10:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 10:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 10:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 10:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 10:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 10:44 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 10:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-9 Lab ID:92288938009 Collected:03/03/16 11:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:40 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:40 7440-38-203/07/16 18:0010.0 2.5 1
Barium 36.0J ug/L 03/09/16 00:40 7440-39-3 B03/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:40 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 0.98J ug/L 03/09/16 00:40 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:40 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:40 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:40 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:40 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/09/16 00:40 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:40 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:40 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:40 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:40 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/09/16 00:40 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 11:00 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 11:00 107-13-12001.9 1
Benzene ND ug/L 03/06/16 11:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 11:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 11:00 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 11:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 11:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 11:00 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 11:00 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 11:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 11:00 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 11:00 75-00-310.0 0.54 1
Chloroform 1.0J ug/L 03/06/16 11:00 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 11:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 11:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 11:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 11:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 11:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 11:00 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 11:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 11:00 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 11:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 11:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 11:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 11:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 11:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 11:00 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 11:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 11:00 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-9 Lab ID:92288938009 Collected:03/03/16 11:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 11:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 11:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 11:00 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 11:00 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 11:00 108-10-11000.33 1
Styrene ND ug/L 03/06/16 11:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 11:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 11:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 11:00 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 11:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 11:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 11:00 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 11:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 11:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 11:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 11:00 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 11:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 11:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %03/06/16 11:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %03/06/16 11:00 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 11:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-10 Lab ID:92288938010 Collected:03/03/16 10:35 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:43 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/09/16 00:43 7440-38-203/07/16 18:0010.0 2.5 1
Barium 407 ug/L 03/09/16 00:43 7440-39-303/07/16 18:001002.5 1
Beryllium 0.51J ug/L 03/09/16 00:43 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 4.2 ug/L 03/09/16 00:43 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:43 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt 3.1J ug/L 03/09/16 00:43 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:43 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/09/16 00:43 7439-92-103/07/16 18:0010.0 2.5 1
Nickel 4.1J ug/L 03/09/16 00:43 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:43 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:43 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:43 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/09/16 00:43 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 18.6 ug/L 03/09/16 00:43 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 11:17 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 11:17 107-13-12001.9 1
Benzene ND ug/L 03/06/16 11:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 11:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 11:17 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 11:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 11:17 74-83-9 M110.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 11:17 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 11:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 11:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 11:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 11:17 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 11:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 11:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 11:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 11:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 11:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 11:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 11:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 11:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 11:17 110-57-6 M11001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 11:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 11:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 11:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 11:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 11:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 11:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 11:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 11:17 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-10 Lab ID:92288938010 Collected:03/03/16 10:35 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 11:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 11:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 11:17 74-88-4 M110.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 11:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 11:17 108-10-11000.33 1
Styrene ND ug/L 03/06/16 11:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 11:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 11:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 11:17 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 11:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 11:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 11:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 11:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 11:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 11:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 11:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 11:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 11:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 11:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 11:17 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 11:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-11 Lab ID:92288938011 Collected:03/03/16 13:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/09/16 00:46 7440-36-003/07/16 18:006.0 3.8 1
Arsenic 4.6J ug/L 03/09/16 00:46 7440-38-203/07/16 18:0010.0 2.5 1
Barium 167 ug/L 03/09/16 00:46 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/09/16 00:46 7440-41-703/07/16 18:001.0 0.50 1
Cadmium 7.9 ug/L 03/09/16 00:46 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/09/16 00:46 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/09/16 00:46 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/09/16 00:46 7440-50-803/07/16 18:0010.0 2.5 1
Lead 3.2J ug/L 03/09/16 00:46 7439-92-103/07/16 18:0010.0 2.5 1
Nickel 7.7J ug/L 03/09/16 00:46 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/09/16 00:46 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/09/16 00:46 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/09/16 00:46 7440-28-003/07/16 18:005.5 5.0 1
Vanadium 16.7J ug/L 03/09/16 00:46 7440-62-203/07/16 18:0025.0 2.5 1
Zinc 8.2J ug/L 03/09/16 00:46 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 11:34 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 11:34 107-13-12001.9 1
Benzene ND ug/L 03/06/16 11:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 11:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 11:34 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 11:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 11:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 11:34 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 11:34 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 11:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 11:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 11:34 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 11:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 11:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 11:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 11:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 11:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 11:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 11:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 11:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 11:34 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 11:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 11:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 11:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.21J ug/L 03/06/16 11:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 11:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 11:34 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 11:34 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 11:34 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Sample:MW-11 Lab ID:92288938011 Collected:03/03/16 13:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 11:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 11:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 11:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 11:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 11:34 108-10-11000.33 1
Styrene ND ug/L 03/06/16 11:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 11:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 11:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 11:34 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 11:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 11:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 11:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 11:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 11:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 11:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 11:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 11:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 11:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 11:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 11:34 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 11:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/9047
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1681738
Associated Lab Samples:92288938003
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 03/11/16 13:080.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1681739LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.22.5 88 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1681740MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288825001
1681741
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 78 75-12577 1 252.50.52 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20892
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92288938001, 92288938002, 92288938003, 92288938004, 92288938005, 92288938006, 92288938007,
92288938008, 92288938009, 92288938010, 92288938011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680484
Associated Lab Samples:92288938001, 92288938002, 92288938003, 92288938004, 92288938005, 92288938006, 92288938007,
92288938008, 92288938009, 92288938010, 92288938011
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 03/08/16 23:273.8
Arsenic ug/L ND 10.0 03/08/16 23:272.5
Barium ug/L 4.2J 100 03/08/16 23:272.5
Beryllium ug/L ND 1.0 03/08/16 23:270.50
Cadmium ug/L ND 1.0 03/08/16 23:270.50
Chromium ug/L ND 10.0 03/08/16 23:272.5
Cobalt ug/L ND 10.0 03/08/16 23:272.5
Copper ug/L ND 10.0 03/08/16 23:272.5
Lead ug/L ND 10.0 03/08/16 23:272.5
Nickel ug/L ND 50.0 03/08/16 23:272.5
Selenium ug/L ND 10.0 03/08/16 23:275.0
Silver ug/L ND 10.0 03/08/16 23:272.5
Thallium ug/L ND 5.5 03/08/16 23:275.0
Vanadium ug/L ND 25.0 03/08/16 23:272.5
Zinc ug/L ND 10.0 03/08/16 23:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680485LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 456500 91 80-120
Arsenic ug/L 542500 108 80-120
Barium ug/L 568500 114 80-120
Beryllium ug/L 530500 106 80-120
Cadmium ug/L 527500 105 80-120
Chromium ug/L 537500 107 80-120
Cobalt ug/L 544500 109 80-120
Copper ug/L 572500 114 80-120
Lead ug/L 543500 109 80-120
Nickel ug/L 532500 106 80-120
Selenium ug/L 530500 106 80-120
Silver ug/L 225250 90 80-120
Thallium ug/L 520500 104 80-120
Vanadium ug/L 507500 101 80-120
Zinc ug/L 545500 109 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680486MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288935015
1680487
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 90 75-12587 3 25500ND451437
Arsenic ug/L 500 107 75-125104 3 25500ND534518
Barium ug/L 500 113 75-125110 3 255004.3J 571 556
Beryllium ug/L 500 106 75-125103 3 25500ND530516
Cadmium ug/L 500 104 75-125101 3 255004.0 526 511
Chromium ug/L 500 107 75-125105 2 25500ND536524
Cobalt ug/L 500 107 75-125104 3 25500ND536519
Copper ug/L 500 115 75-125112 3 25500ND575559
Lead ug/L 500 107 75-125104 3 25500ND535519
Nickel ug/L 500 105 75-125102 3 25500ND525509
Selenium ug/L 500 104 75-125101 3 25500ND518505
Silver ug/L 250 90 75-12588 2 25250ND224220
Thallium ug/L 500 102 75-125100 2 25500ND510500
Vanadium ug/L 500 101 75-12599 2 25500ND507496
Zinc ug/L 500 107 75-125104 3 2550011.3 548 530
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35831
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288938001, 92288938002, 92288938003, 92288938004, 92288938005, 92288938006, 92288938007,
92288938008, 92288938009, 92288938010, 92288938011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679876
Associated Lab Samples:92288938001, 92288938002, 92288938003, 92288938004, 92288938005, 92288938006, 92288938007,
92288938008, 92288938009, 92288938010, 92288938011
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/06/16 05:120.33
1,1,1-Trichloroethane ug/L ND 1.0 03/06/16 05:120.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/06/16 05:120.40
1,1,2-Trichloroethane ug/L ND 1.0 03/06/16 05:120.29
1,1-Dichloroethane ug/L ND 5.0 03/06/16 05:120.32
1,1-Dichloroethene ug/L ND 5.0 03/06/16 05:120.56
1,2,3-Trichloropropane ug/L ND 1.0 03/06/16 05:120.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/06/16 05:122.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/06/16 05:120.27
1,2-Dichlorobenzene ug/L ND 5.0 03/06/16 05:120.30
1,2-Dichloroethane ug/L ND 1.0 03/06/16 05:120.24
1,2-Dichloropropane ug/L ND 1.0 03/06/16 05:120.27
1,4-Dichlorobenzene ug/L ND 1.0 03/06/16 05:120.33
2-Butanone (MEK)ug/L ND 100 03/06/16 05:120.96
2-Hexanone ug/L ND 50.0 03/06/16 05:120.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/06/16 05:120.33
Acetone ug/L ND 100 03/06/16 05:1210.0
Acrylonitrile ug/L ND 200 03/06/16 05:121.9
Benzene ug/L ND 1.0 03/06/16 05:120.25
Bromochloromethane ug/L ND 3.0 03/06/16 05:120.17
Bromodichloromethane ug/L ND 1.0 03/06/16 05:120.18
Bromoform ug/L ND 3.0 03/06/16 05:120.26
Bromomethane ug/L ND 10.0 03/06/16 05:120.29
Carbon disulfide ug/L ND 100 03/06/16 05:121.2
Carbon tetrachloride ug/L ND 1.0 03/06/16 05:120.25
Chlorobenzene ug/L ND 3.0 03/06/16 05:120.23
Chloroethane ug/L ND 10.0 03/06/16 05:120.54
Chloroform ug/L ND 5.0 03/06/16 05:120.14
Chloromethane ug/L ND 1.0 03/06/16 05:120.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/06/16 05:120.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/06/16 05:120.13
Dibromochloromethane ug/L ND 3.0 03/06/16 05:120.21
Dibromomethane ug/L ND 10.0 03/06/16 05:120.21
Ethylbenzene ug/L ND 1.0 03/06/16 05:120.30
Iodomethane ug/L ND 10.0 03/06/16 05:120.32
Methylene Chloride ug/L ND 1.0 03/06/16 05:120.97
Styrene ug/L ND 1.0 03/06/16 05:120.26
Tetrachloroethene ug/L ND 1.0 03/06/16 05:120.46
Toluene ug/L ND 1.0 03/06/16 05:120.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/06/16 05:120.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679876
Associated Lab Samples:92288938001, 92288938002, 92288938003, 92288938004, 92288938005, 92288938006, 92288938007,
92288938008, 92288938009, 92288938010, 92288938011
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 03/06/16 05:120.26
trans-1,4-Dichloro-2-butene ug/L ND 100 03/06/16 05:121.0
Trichloroethene ug/L ND 1.0 03/06/16 05:120.47
Trichlorofluoromethane ug/L ND 1.0 03/06/16 05:120.20
Vinyl acetate ug/L ND 50.0 03/06/16 05:120.35
Vinyl chloride ug/L ND 1.0 03/06/16 05:120.62
Xylene (Total)ug/L ND 5.0 03/06/16 05:120.66
1,2-Dichloroethane-d4 (S)%100 70-130 03/06/16 05:12
4-Bromofluorobenzene (S)%95 70-130 03/06/16 05:12
Toluene-d8 (S)%100 70-130 03/06/16 05:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679877LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125
1,1,1-Trichloroethane ug/L 47.950 96 71-129
1,1,2,2-Tetrachloroethane ug/L 47.850 96 79-124
1,1,2-Trichloroethane ug/L 48.550 97 85-125
1,1-Dichloroethane ug/L 48.950 98 73-126
1,1-Dichloroethene ug/L 51.250 102 66-135
1,2,3-Trichloropropane ug/L 51.350 103 75-130
1,2-Dibromo-3-chloropropane ug/L 49.350 99 71-133
1,2-Dibromoethane (EDB)ug/L 51.450 103 83-124
1,2-Dichlorobenzene ug/L 47.250 94 80-133
1,2-Dichloroethane ug/L 48.150 96 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
1,4-Dichlorobenzene ug/L 50.450 101 78-130
2-Butanone (MEK)ug/L 95.1J100 95 61-144
2-Hexanone ug/L 97.8100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 105100 105 72-135
Acetone ug/L 93.2J100 93 48-146
Acrylonitrile ug/L 256250 102 40-160
Benzene ug/L 48.650 97 80-125
Bromochloromethane ug/L 51.350 103 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 46.450 93 71-128
Bromomethane ug/L 42.250 84 40-160
Carbon disulfide ug/L 49.3J50 99 50-160
Carbon tetrachloride ug/L 47.450 95 69-131
Chlorobenzene ug/L 49.650 99 81-122
Chloroethane ug/L 48.850 98 39-148
Chloroform ug/L 48.750 97 73-127
Chloromethane ug/L 38.350 77 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679877LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 49.950 100 74-124
cis-1,3-Dichloropropene ug/L 47.350 95 72-132
Dibromochloromethane ug/L 49.150 98 78-125
Dibromomethane ug/L 50.550 101 82-120
Ethylbenzene ug/L 48.650 97 79-121
Iodomethane ug/L 51.4100 51 39-154
Methylene Chloride ug/L 46.050 92 64-133
Styrene ug/L 49.550 99 84-126
Tetrachloroethene ug/L 47.750 95 78-122
Toluene ug/L 47.450 95 80-121
trans-1,2-Dichloroethene ug/L 49.350 99 71-127
trans-1,3-Dichloropropene ug/L 46.750 93 69-141
trans-1,4-Dichloro-2-butene ug/L 34.1J50 68 40-160
Trichloroethene ug/L 47.450 95 78-122
Trichlorofluoromethane ug/L 49.050 98 53-137
Vinyl acetate ug/L 97.8100 98 40-160
Vinyl chloride ug/L 49.250 98 58-137
Xylene (Total)ug/L 140150 93 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679878MATRIX SPIKE SAMPLE:
MSSpike
Result
92288938010
1,1,1,2-Tetrachloroethane ug/L 20.820 104 70-130ND
1,1,1-Trichloroethane ug/L 21.920 110 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.220 96 70-130ND
1,1,2-Trichloroethane ug/L 20.820 104 70-130ND
1,1-Dichloroethane ug/L 21.920 110 70-130ND
1,1-Dichloroethene ug/L 23.520 118 70-166ND
1,2,3-Trichloropropane ug/L 21.920 110 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.020 100 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 20.520 102 70-130ND
1,2-Dichloropropane ug/L 21.420 107 70-130ND
1,4-Dichlorobenzene ug/L 20.820 104 70-130ND
2-Butanone (MEK)ug/L 39.1J40 98 70-130ND
2-Hexanone ug/L 39.0J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 43.4J40 108 70-130ND
Acetone ug/L 44.1J40 99 70-130ND
Acrylonitrile ug/L 99.8J100 100 70-130ND
Benzene ug/L 22.020 110 70-148ND
Bromochloromethane ug/L 21.920 110 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679878MATRIX SPIKE SAMPLE:
MSSpike
Result
92288938010
Bromodichloromethane ug/L 21.120 105 70-130ND
Bromoform ug/L 18.320 92 70-130ND
Bromomethane ug/L 12.2 M1206170-130ND
Carbon disulfide ug/L 23.0J20 115 70-130ND
Carbon tetrachloride ug/L 21.320 107 70-130ND
Chlorobenzene ug/L 20.820 104 70-146ND
Chloroethane ug/L 23.920 120 70-130ND
Chloroform ug/L 21.520 107 70-130ND
Chloromethane ug/L 17.120 85 70-130ND
cis-1,2-Dichloroethene ug/L 21.820 109 70-130ND
cis-1,3-Dichloropropene ug/L 19.420 97 70-130ND
Dibromochloromethane ug/L 20.720 104 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 21.220 106 70-130ND
Iodomethane ug/L 18.0 M1404570-130ND
Methylene Chloride ug/L 20.520 102 70-130ND
Styrene ug/L 20.120 100 70-130ND
Tetrachloroethene ug/L 20.320 101 70-130ND
Toluene ug/L 21.320 107 70-155ND
trans-1,2-Dichloroethene ug/L 22.720 114 70-130ND
trans-1,3-Dichloropropene ug/L 18.620 93 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.5J M1205870-130ND
Trichloroethene ug/L 21.220 106 69-151ND
Trichlorofluoromethane ug/L 23.120 116 70-130ND
Vinyl acetate ug/L 29.6J40 74 70-130ND
Vinyl chloride ug/L 23.520 117 70-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288938011
1679879SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288938011
1679879SAMPLE DUPLICATE:
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 0.25J 300.21J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%95 196
Toluene-d8 (S)%100 199
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
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Page 38 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43539
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1684610
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 03/13/16 14:121000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1684611LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4940050000 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1684612MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289440001
1684613
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 94 80-12094 0 2550000ND4680046900
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1684614MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288938003
1684615
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12096 1 2550000ND4800048400
REPORT OF LABORATORY ANALYSIS
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Page 39 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43444
SM 3500-Fe B
SM 3500-Fe B
Iron, Ferrous
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680689
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Iron, Ferrous mg/L ND 0.50 N203/08/16 09:580.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680690LABORATORY CONTROL SAMPLE:
LCSSpike
Iron, Ferrous mg/L 1.5 N21.5 102 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288938001
1680691SAMPLE DUPLICATE:
Iron, Ferrous mg/L ND H1,N210ND
REPORT OF LABORATORY ANALYSIS
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Page 40 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43433
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680264
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 03/08/16 10:50100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680265LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 518J500 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680266MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288787002
1680267
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 105 90-110105 0 10500ND526J526J
REPORT OF LABORATORY ANALYSIS
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Page 41 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26695
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680643
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 03/08/16 10:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680644LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 18800J20000 94 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680645MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288834001
1680646
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M6200002890-11031 0 10200002590 mg/L 2600000
J
2600000
J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
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Page 42 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26679
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679828
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 20.0 03/05/16 11:4810.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679829LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 24402500 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1679830MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288938001
1679831
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 95 90-11096 0 10250043.3J 2430 2430
REPORT OF LABORATORY ANALYSIS
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Page 43 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26686
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680236
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 03/08/16 17:36500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680237LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2050020000 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680238MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288834005
1680239
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M6250000012190-110123 1 1025000004300 mg/L 7320000 7370000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680240MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288938003
1680241
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 50000 110 90-110110 0 105000068806190061900
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 44 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26727
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1682498
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 03/10/16 20:0012500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1682499LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 744000750000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1682500MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289401001
1682501
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 110 90-110110 0 3750000ND833000833000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1682502MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92289104001
1682503
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M17500007890-11078 0 3750000877 mg/L 1460000 1460000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
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Page 45 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26700
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples:92288938001, 92288938002, 92288938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680874
Associated Lab Samples:92288938001, 92288938002, 92288938003
Matrix:Water
AnalyzedMDL
Total Organic Carbon ug/L ND 1000 03/09/16 12:38500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680875LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2430025000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680876MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288938001
1680877
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 98 90-11098 0 1025000808J2540025400
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
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Page 46 of 51
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Analysis conducted outside the EPA method holding time.H1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/14/2016 03:10 PM
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[phone]
Page 47 of 51
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288938001 MPRP/20892 ICP/18814MW-1R EPA 3010A EPA 6010
92288938002 MPRP/20892 ICP/18814MW-2 EPA 3010A EPA 6010
92288938003 MPRP/20892 ICP/18814MW-8 EPA 3010A EPA 6010
92288938004 MPRP/20892 ICP/18814MW-3 EPA 3010A EPA 6010
92288938005 MPRP/20892 ICP/18814MW-4 EPA 3010A EPA 6010
92288938006 MPRP/20892 ICP/18814MW-5 EPA 3010A EPA 6010
92288938007 MPRP/20892 ICP/18814MW-6 EPA 3010A EPA 6010
92288938008 MPRP/20892 ICP/18814MW-7 EPA 3010A EPA 6010
92288938009 MPRP/20892 ICP/18814MW-9 EPA 3010A EPA 6010
92288938010 MPRP/20892 ICP/18814MW-10 EPA 3010A EPA 6010
92288938011 MPRP/20892 ICP/18814MW-11 EPA 3010A EPA 6010
92288938003 MERP/9047 MERC/8693MW-8 EPA 7470 EPA 7470
92288938001 MSV/35831MW-1R EPA 8260
92288938002 MSV/35831MW-2 EPA 8260
92288938003 MSV/35831MW-8 EPA 8260
92288938004 MSV/35831MW-3 EPA 8260
92288938005 MSV/35831MW-4 EPA 8260
92288938006 MSV/35831MW-5 EPA 8260
92288938007 MSV/35831MW-6 EPA 8260
92288938008 MSV/35831MW-7 EPA 8260
92288938009 MSV/35831MW-9 EPA 8260
92288938010 MSV/35831MW-10 EPA 8260
92288938011 MSV/35831MW-11 EPA 8260
92288938001 WET/43539MW-1R SM 2320B
92288938002 WET/43539MW-2 SM 2320B
92288938003 WET/43539MW-8 SM 2320B
92288938001 WET/43444MW-1R SM 3500-Fe B
92288938002 WET/43444MW-2 SM 3500-Fe B
92288938003 WET/43444MW-8 SM 3500-Fe B
92288938001 WET/43433MW-1R SM 4500-S2D
92288938002 WET/43433MW-2 SM 4500-S2D
92288938003 WET/43433MW-8 SM 4500-S2D
92288938001 WETA/26695MW-1R EPA 300.0
92288938002 WETA/26695MW-2 EPA 300.0
92288938003 WETA/26695MW-8 EPA 300.0
92288938001 WETA/26679MW-1R EPA 353.2
92288938002 WETA/26679MW-2 EPA 353.2
92288938003 WETA/26679MW-8 EPA 353.2
92288938001 WETA/26686MW-1R SM 4500-Cl-E
92288938002 WETA/26686MW-2 SM 4500-Cl-E
92288938003 WETA/26686MW-8 SM 4500-Cl-E
92288938001 WETA/26727MW-1R SM 5220D
92288938002 WETA/26727MW-2 SM 5220D
92288938003 WETA/26727MW-8 SM 5220D
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 48 of 51
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288938
WAYNE CLOSED LF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288938001 WETA/26700MW-1R SM 5310B
92288938002 WETA/26700MW-2 SM 5310B
92288938003 WETA/26700MW-8 SM 5310B
REPORT OF LABORATORY ANALYSIS
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Page 49 of 51
Page 50 of 51
Page 51 of 51
#=CL#
March 10, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92288913
92288913
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE CLOSED MSWLF SW-ByMW-2
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
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Page 1 of 13
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Page 2 of 13
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Lab ID Sample ID Matrix Date Collected Date Received
92288913001 SW-ByMW-2 Water 03/03/16 04:00 03/04/16 09:11
REPORT OF LABORATORY ANALYSIS
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Page 3 of 13
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288913001 SW-ByMW-2 EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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Page 4 of 13
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Sample:SW-ByMW-2 Lab ID:92288913001 Collected:03/03/16 04:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 16:17 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 16:17 107-13-12001.9 1
Benzene ND ug/L 03/06/16 16:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 16:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 16:17 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 16:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 16:17 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 16:17 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 16:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 16:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 16:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 16:17 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 16:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 16:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 16:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 16:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 16:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 16:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 16:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 16:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 16:17 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 16:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 16:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 16:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 16:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 16:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 16:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 16:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 16:17 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 03/06/16 16:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 16:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 16:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 16:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 16:17 108-10-11000.33 1
Styrene ND ug/L 03/06/16 16:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 16:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 16:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 16:17 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 16:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 16:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 16:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 16:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 16:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 16:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 16:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 16:17 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Sample:SW-ByMW-2 Lab ID:92288913001 Collected:03/03/16 04:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 03/06/16 16:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %03/06/16 16:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %03/06/16 16:17 17060-07-070-130 1
Toluene-d8 (S)99 %03/06/16 16:17 2037-26-570-130 1
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Page 6 of 13
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35845
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288913001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679920
Associated Lab Samples:92288913001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/06/16 16:000.33
1,1,1-Trichloroethane ug/L ND 1.0 03/06/16 16:000.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/06/16 16:000.40
1,1,2-Trichloroethane ug/L ND 1.0 03/06/16 16:000.29
1,1-Dichloroethane ug/L ND 5.0 03/06/16 16:000.32
1,1-Dichloroethene ug/L ND 5.0 03/06/16 16:000.56
1,2,3-Trichloropropane ug/L ND 1.0 03/06/16 16:000.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/06/16 16:002.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/06/16 16:000.27
1,2-Dichlorobenzene ug/L ND 5.0 03/06/16 16:000.30
1,2-Dichloroethane ug/L ND 1.0 03/06/16 16:000.24
1,2-Dichloropropane ug/L ND 1.0 03/06/16 16:000.27
1,4-Dichlorobenzene ug/L ND 1.0 03/06/16 16:000.33
2-Butanone (MEK)ug/L ND 100 03/06/16 16:000.96
2-Hexanone ug/L ND 50.0 03/06/16 16:000.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/06/16 16:000.33
Acetone ug/L ND 100 03/06/16 16:0010.0
Acrylonitrile ug/L ND 200 03/06/16 16:001.9
Benzene ug/L ND 1.0 03/06/16 16:000.25
Bromochloromethane ug/L ND 3.0 03/06/16 16:000.17
Bromodichloromethane ug/L ND 1.0 03/06/16 16:000.18
Bromoform ug/L ND 3.0 03/06/16 16:000.26
Bromomethane ug/L ND 10.0 03/06/16 16:000.29
Carbon disulfide ug/L ND 100 03/06/16 16:001.2
Carbon tetrachloride ug/L ND 1.0 03/06/16 16:000.25
Chlorobenzene ug/L ND 3.0 03/06/16 16:000.23
Chloroethane ug/L ND 10.0 03/06/16 16:000.54
Chloroform ug/L ND 5.0 03/06/16 16:000.14
Chloromethane ug/L ND 1.0 03/06/16 16:000.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/06/16 16:000.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/06/16 16:000.13
Dibromochloromethane ug/L ND 3.0 03/06/16 16:000.21
Dibromomethane ug/L ND 10.0 03/06/16 16:000.21
Ethylbenzene ug/L ND 1.0 03/06/16 16:000.30
Iodomethane ug/L ND 10.0 03/06/16 16:000.32
Methylene Chloride ug/L ND 1.0 03/06/16 16:000.97
Styrene ug/L ND 1.0 03/06/16 16:000.26
Tetrachloroethene ug/L ND 1.0 03/06/16 16:000.46
Toluene ug/L ND 1.0 03/06/16 16:000.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/06/16 16:000.49
trans-1,3-Dichloropropene ug/L ND 1.0 03/06/16 16:000.26
REPORT OF LABORATORY ANALYSIS
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Page 7 of 13
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679920
Associated Lab Samples:92288913001
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 03/06/16 16:001.0
Trichloroethene ug/L ND 1.0 03/06/16 16:000.47
Trichlorofluoromethane ug/L ND 1.0 03/06/16 16:000.20
Vinyl acetate ug/L ND 50.0 03/06/16 16:000.35
Vinyl chloride ug/L ND 1.0 03/06/16 16:000.62
Xylene (Total)ug/L ND 5.0 03/06/16 16:000.66
1,2-Dichloroethane-d4 (S)%99 70-130 03/06/16 16:00
4-Bromofluorobenzene (S)%96 70-130 03/06/16 16:00
Toluene-d8 (S)%99 70-130 03/06/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679921LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.950 96 80-125
1,1,1-Trichloroethane ug/L 47.850 96 71-129
1,1,2,2-Tetrachloroethane ug/L 44.850 90 79-124
1,1,2-Trichloroethane ug/L 46.550 93 85-125
1,1-Dichloroethane ug/L 48.550 97 73-126
1,1-Dichloroethene ug/L 51.450 103 66-135
1,2,3-Trichloropropane ug/L 50.250 100 75-130
1,2-Dibromo-3-chloropropane ug/L 44.150 88 71-133
1,2-Dibromoethane (EDB)ug/L 49.950 100 83-124
1,2-Dichlorobenzene ug/L 46.250 92 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 47.150 94 75-132
1,4-Dichlorobenzene ug/L 49.150 98 78-130
2-Butanone (MEK)ug/L 85.0J100 85 61-144
2-Hexanone ug/L 87.0100 87 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.3J100 97 72-135
Acetone ug/L 83.0J100 83 48-146
Acrylonitrile ug/L 231250 92 40-160
Benzene ug/L 47.950 96 80-125
Bromochloromethane ug/L 49.150 98 71-125
Bromodichloromethane ug/L 46.850 94 78-124
Bromoform ug/L 45.750 91 71-128
Bromomethane ug/L 35.650 71 40-160
Carbon disulfide ug/L 49.6J50 99 50-160
Carbon tetrachloride ug/L 45.650 91 69-131
Chlorobenzene ug/L 48.550 97 81-122
Chloroethane ug/L 50.050 100 39-148
Chloroform ug/L 47.750 95 73-127
Chloromethane ug/L 35.750 71 44-146
cis-1,2-Dichloroethene ug/L 48.950 98 74-124
cis-1,3-Dichloropropene ug/L 48.050 96 72-132
REPORT OF LABORATORY ANALYSIS
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Page 8 of 13
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679921LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 47.850 96 78-125
Dibromomethane ug/L 47.950 96 82-120
Ethylbenzene ug/L 47.450 95 79-121
Iodomethane ug/L 54.9100 55 39-154
Methylene Chloride ug/L 44.650 89 64-133
Styrene ug/L 47.250 94 84-126
Tetrachloroethene ug/L 47.950 96 78-122
Toluene ug/L 46.950 94 80-121
trans-1,2-Dichloroethene ug/L 49.950 100 71-127
trans-1,3-Dichloropropene ug/L 46.450 93 69-141
trans-1,4-Dichloro-2-butene ug/L 30.9J50 62 40-160
Trichloroethene ug/L 47.050 94 78-122
Trichlorofluoromethane ug/L 50.150 100 53-137
Vinyl acetate ug/L 93.9100 94 40-160
Vinyl chloride ug/L 49.050 98 58-137
Xylene (Total)ug/L 136150 91 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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Page 9 of 13
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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Page 10 of 13
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288913
WAYNE CLOSED MSWLF SW-ByMW-2
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288913001 MSV/35845SW-ByMW-2 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 11 of 13
Page 12 of 13
Page 13 of 13
#=CL#
March 10, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92288930
92288930
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on March 04, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92288930001 EB Water 03/03/16 05:30 03/04/16 09:11
92288930002 FB Water 03/03/16 05:40 03/04/16 09:11
92288930003 TB Water 03/03/16 00:00 03/04/16 09:11
REPORT OF LABORATORY ANALYSIS
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Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92288930001 EB EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288930002 FB EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92288930003 TB EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92288930001 Collected:03/03/16 05:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 18:42 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 18:42 7440-38-203/07/16 18:0010.0 2.5 1
Barium ND ug/L 03/08/16 18:42 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 18:42 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 18:42 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 18:42 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 18:42 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 18:42 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 18:42 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 18:42 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 18:42 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 18:42 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 18:42 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 18:42 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 18:42 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 06:35 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 06:35 107-13-12001.9 1
Benzene ND ug/L 03/06/16 06:35 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 06:35 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 06:35 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 06:35 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 06:35 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 06:35 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 06:35 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 06:35 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 06:35 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 06:35 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 06:35 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 06:35 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 06:35 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 06:35 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 06:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 06:35 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 06:35 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 06:35 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 06:35 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 06:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 06:35 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 06:35 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 06:35 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 06:35 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 06:35 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 06:35 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 06:35 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:EB Lab ID:92288930001 Collected:03/03/16 05:30 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 06:35 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 06:35 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 06:35 74-88-410.0 0.32 1
Methylene Chloride 1.7 ug/L 03/06/16 06:35 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 06:35 108-10-11000.33 1
Styrene ND ug/L 03/06/16 06:35 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 06:35 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 06:35 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 06:35 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 06:35 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 06:35 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 06:35 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 06:35 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 06:35 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 06:35 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 06:35 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 06:35 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 06:35 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %03/06/16 06:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %03/06/16 06:35 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 06:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92288930002 Collected:03/03/16 05:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 03/08/16 18:45 7440-36-003/07/16 18:006.0 3.8 1
Arsenic ND ug/L 03/08/16 18:45 7440-38-203/07/16 18:0010.0 2.5 1
Barium ND ug/L 03/08/16 18:45 7440-39-303/07/16 18:001002.5 1
Beryllium ND ug/L 03/08/16 18:45 7440-41-703/07/16 18:001.0 0.50 1
Cadmium ND ug/L 03/08/16 18:45 7440-43-903/07/16 18:001.0 0.50 1
Chromium ND ug/L 03/08/16 18:45 7440-47-303/07/16 18:0010.0 2.5 1
Cobalt ND ug/L 03/08/16 18:45 7440-48-403/07/16 18:0010.0 2.5 1
Copper ND ug/L 03/08/16 18:45 7440-50-803/07/16 18:0010.0 2.5 1
Lead ND ug/L 03/08/16 18:45 7439-92-103/07/16 18:0010.0 2.5 1
Nickel ND ug/L 03/08/16 18:45 7440-02-003/07/16 18:0050.0 2.5 1
Selenium ND ug/L 03/08/16 18:45 7782-49-203/07/16 18:0010.0 5.0 1
Silver ND ug/L 03/08/16 18:45 7440-22-403/07/16 18:0010.0 2.5 1
Thallium ND ug/L 03/08/16 18:45 7440-28-003/07/16 18:005.5 5.0 1
Vanadium ND ug/L 03/08/16 18:45 7440-62-203/07/16 18:0025.0 2.5 1
Zinc ND ug/L 03/08/16 18:45 7440-66-603/07/16 18:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 06:51 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 06:51 107-13-12001.9 1
Benzene ND ug/L 03/06/16 06:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 06:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 06:51 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 06:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 06:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 06:51 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 06:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 06:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 06:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 06:51 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 06:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 06:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 06:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 06:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 06:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 06:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 06:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 06:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 06:51 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 06:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 06:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 06:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 06:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 06:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 06:51 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 06:51 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 06:51 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:FB Lab ID:92288930002 Collected:03/03/16 05:40 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 03/06/16 06:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 06:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 06:51 74-88-410.0 0.32 1
Methylene Chloride 1.6 ug/L 03/06/16 06:51 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 06:51 108-10-11000.33 1
Styrene ND ug/L 03/06/16 06:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 06:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 06:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 06:51 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 06:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 06:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 06:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 06:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 06:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 06:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 06:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 06:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 03/06/16 06:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %03/06/16 06:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %03/06/16 06:51 17060-07-070-130 1
Toluene-d8 (S)98 %03/06/16 06:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92288930003 Collected:03/03/16 00:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 03/06/16 07:08 67-64-110010.0 1
Acrylonitrile ND ug/L 03/06/16 07:08 107-13-12001.9 1
Benzene ND ug/L 03/06/16 07:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 03/06/16 07:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 03/06/16 07:08 75-27-41.0 0.18 1
Bromoform ND ug/L 03/06/16 07:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 03/06/16 07:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 03/06/16 07:08 78-93-31000.96 1
Carbon disulfide ND ug/L 03/06/16 07:08 75-15-01001.2 1
Carbon tetrachloride ND ug/L 03/06/16 07:08 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 03/06/16 07:08 108-90-73.0 0.23 1
Chloroethane ND ug/L 03/06/16 07:08 75-00-310.0 0.54 1
Chloroform ND ug/L 03/06/16 07:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 03/06/16 07:08 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 03/06/16 07:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 03/06/16 07:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 03/06/16 07:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 03/06/16 07:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 03/06/16 07:08 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 03/06/16 07:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 03/06/16 07:08 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 03/06/16 07:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 03/06/16 07:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 03/06/16 07:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 03/06/16 07:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 03/06/16 07:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 03/06/16 07:08 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 03/06/16 07:08 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 03/06/16 07:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 03/06/16 07:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 03/06/16 07:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 03/06/16 07:08 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 03/06/16 07:08 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 03/06/16 07:08 108-10-11000.33 1
Styrene ND ug/L 03/06/16 07:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 03/06/16 07:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 03/06/16 07:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 03/06/16 07:08 127-18-41.0 0.46 1
Toluene ND ug/L 03/06/16 07:08 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 03/06/16 07:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 03/06/16 07:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 03/06/16 07:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 03/06/16 07:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 03/06/16 07:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 03/06/16 07:08 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 03/06/16 07:08 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Sample:TB Lab ID:92288930003 Collected:03/03/16 00:00 Received:03/04/16 09:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 03/06/16 07:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %03/06/16 07:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %03/06/16 07:08 17060-07-070-130 1
Toluene-d8 (S)100 %03/06/16 07:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20891
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92288930001, 92288930002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1680479
Associated Lab Samples:92288930001, 92288930002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 03/08/16 18:273.8
Arsenic ug/L ND 10.0 03/08/16 18:272.5
Barium ug/L ND 100 03/08/16 18:272.5
Beryllium ug/L ND 1.0 03/08/16 18:270.50
Cadmium ug/L ND 1.0 03/08/16 18:270.50
Chromium ug/L ND 10.0 03/08/16 18:272.5
Cobalt ug/L ND 10.0 03/08/16 18:272.5
Copper ug/L ND 10.0 03/08/16 18:272.5
Lead ug/L ND 10.0 03/08/16 18:272.5
Nickel ug/L ND 50.0 03/08/16 18:272.5
Selenium ug/L ND 10.0 03/08/16 18:275.0
Silver ug/L ND 10.0 03/08/16 18:272.5
Thallium ug/L ND 5.5 03/08/16 18:275.0
Vanadium ug/L ND 25.0 03/08/16 18:272.5
Zinc ug/L ND 10.0 03/08/16 18:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1680480LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 468500 94 80-120
Arsenic ug/L 548500 110 80-120
Barium ug/L 552500 110 80-120
Beryllium ug/L 547500 109 80-120
Cadmium ug/L 553500 111 80-120
Chromium ug/L 548500 110 80-120
Cobalt ug/L 554500 111 80-120
Copper ug/L 564500 113 80-120
Lead ug/L 548500 110 80-120
Nickel ug/L 554500 111 80-120
Selenium ug/L 546500 109 80-120
Silver ug/L 228250 91 80-120
Thallium ug/L 537500 107 80-120
Vanadium ug/L 550500 110 80-120
Zinc ug/L 545500 109 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1680481MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92288741001
1680482
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 85 75-12588 4 25500ND426441
Arsenic ug/L 500 100 75-125103 3 25500ND500515
Barium ug/L 500 103 75-125106 2 255009.6 526 538
Beryllium ug/L 500 103 75-125105 2 25500ND514526
Cadmium ug/L 500 101 75-125105 4 25500ND506524
Chromium ug/L 500 101 75-125105 4 25500ND506528
Cobalt ug/L 500 101 75-125105 4 25500ND505526
Copper ug/L 500 103 75-125108 5 25500ND515540
Lead ug/L 500 100 75-125103 4 25500ND498517
Nickel ug/L 500 101 75-125105 4 25500ND505524
Selenium ug/L 500 100 75-125104 4 25500ND501521
Silver ug/L 250 84 75-12588 4 25250ND211219
Thallium ug/L 500 98 75-125102 3 25500ND492508
Vanadium ug/L 500 101 75-125106 4 25500ND505528
Zinc ug/L 500 99 75-125103 4 25500ND501520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35830
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92288930001, 92288930002, 92288930003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288930001, 92288930002, 92288930003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 03/06/16 04:550.33
1,1,1-Trichloroethane ug/L ND 1.0 03/06/16 04:550.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 03/06/16 04:550.40
1,1,2-Trichloroethane ug/L ND 1.0 03/06/16 04:550.29
1,1-Dichloroethane ug/L ND 5.0 03/06/16 04:550.32
1,1-Dichloroethene ug/L ND 5.0 03/06/16 04:550.56
1,2,3-Trichloropropane ug/L ND 1.0 03/06/16 04:550.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 03/06/16 04:552.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 03/06/16 04:550.27
1,2-Dichlorobenzene ug/L ND 5.0 03/06/16 04:550.30
1,2-Dichloroethane ug/L ND 1.0 03/06/16 04:550.24
1,2-Dichloropropane ug/L ND 1.0 03/06/16 04:550.27
1,4-Dichlorobenzene ug/L ND 1.0 03/06/16 04:550.33
2-Butanone (MEK)ug/L ND 100 03/06/16 04:550.96
2-Hexanone ug/L ND 50.0 03/06/16 04:550.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 03/06/16 04:550.33
Acetone ug/L ND 100 03/06/16 04:5510.0
Acrylonitrile ug/L ND 200 03/06/16 04:551.9
Benzene ug/L ND 1.0 03/06/16 04:550.25
Bromochloromethane ug/L ND 3.0 03/06/16 04:550.17
Bromodichloromethane ug/L ND 1.0 03/06/16 04:550.18
Bromoform ug/L ND 3.0 03/06/16 04:550.26
Bromomethane ug/L ND 10.0 03/06/16 04:550.29
Carbon disulfide ug/L ND 100 03/06/16 04:551.2
Carbon tetrachloride ug/L ND 1.0 03/06/16 04:550.25
Chlorobenzene ug/L ND 3.0 03/06/16 04:550.23
Chloroethane ug/L ND 10.0 03/06/16 04:550.54
Chloroform ug/L ND 5.0 03/06/16 04:550.14
Chloromethane ug/L ND 1.0 03/06/16 04:550.11
cis-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.19
cis-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.13
Dibromochloromethane ug/L ND 3.0 03/06/16 04:550.21
Dibromomethane ug/L ND 10.0 03/06/16 04:550.21
Ethylbenzene ug/L ND 1.0 03/06/16 04:550.30
Iodomethane ug/L ND 10.0 03/06/16 04:550.32
Methylene Chloride ug/L ND 1.0 03/06/16 04:550.97
Styrene ug/L ND 1.0 03/06/16 04:550.26
Tetrachloroethene ug/L ND 1.0 03/06/16 04:550.46
Toluene ug/L ND 1.0 03/06/16 04:550.26
trans-1,2-Dichloroethene ug/L ND 5.0 03/06/16 04:550.49
trans-1,3-Dichloropropene ug/L ND 1.0 03/06/16 04:550.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1679872
Associated Lab Samples:92288930001, 92288930002, 92288930003
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 03/06/16 04:551.0
Trichloroethene ug/L ND 1.0 03/06/16 04:550.47
Trichlorofluoromethane ug/L ND 1.0 03/06/16 04:550.20
Vinyl acetate ug/L ND 50.0 03/06/16 04:550.35
Vinyl chloride ug/L ND 1.0 03/06/16 04:550.62
Xylene (Total)ug/L ND 5.0 03/06/16 04:550.66
1,2-Dichloroethane-d4 (S)%100 70-130 03/06/16 04:55
4-Bromofluorobenzene (S)%97 70-130 03/06/16 04:55
Toluene-d8 (S)%99 70-130 03/06/16 04:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.850 102 80-125
1,1,1-Trichloroethane ug/L 48.750 97 71-129
1,1,2,2-Tetrachloroethane ug/L 49.050 98 79-124
1,1,2-Trichloroethane ug/L 48.550 97 85-125
1,1-Dichloroethane ug/L 49.350 99 73-126
1,1-Dichloroethene ug/L 52.350 105 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 49.250 98 71-133
1,2-Dibromoethane (EDB)ug/L 52.850 106 83-124
1,2-Dichlorobenzene ug/L 48.650 97 80-133
1,2-Dichloroethane ug/L 47.950 96 67-128
1,2-Dichloropropane ug/L 49.750 99 75-132
1,4-Dichlorobenzene ug/L 52.250 104 78-130
2-Butanone (MEK)ug/L 95.7J100 96 61-144
2-Hexanone ug/L 98.0100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 106100 106 72-135
Acetone ug/L 94.5J100 94 48-146
Acrylonitrile ug/L 260250 104 40-160
Benzene ug/L 50.150 100 80-125
Bromochloromethane ug/L 52.950 106 71-125
Bromodichloromethane ug/L 50.950 102 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 40.050 80 40-160
Carbon disulfide ug/L 50.3J50 101 50-160
Carbon tetrachloride ug/L 49.050 98 69-131
Chlorobenzene ug/L 51.250 102 81-122
Chloroethane ug/L 51.150 102 39-148
Chloroform ug/L 48.550 97 73-127
Chloromethane ug/L 38.050 76 44-146
cis-1,2-Dichloroethene ug/L 50.250 100 74-124
cis-1,3-Dichloropropene ug/L 50.350 101 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
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[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1679873LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 50.450 101 78-125
Dibromomethane ug/L 51.650 103 82-120
Ethylbenzene ug/L 50.250 100 79-121
Iodomethane ug/L 50.5100 51 39-154
Methylene Chloride ug/L 46.750 93 64-133
Styrene ug/L 50.250 100 84-126
Tetrachloroethene ug/L 48.850 98 78-122
Toluene ug/L 49.550 99 80-121
trans-1,2-Dichloroethene ug/L 50.550 101 71-127
trans-1,3-Dichloropropene ug/L 47.650 95 69-141
trans-1,4-Dichloro-2-butene ug/L 35.5J50 71 40-160
Trichloroethene ug/L 50.150 100 78-122
Trichlorofluoromethane ug/L 50.750 101 53-137
Vinyl acetate ug/L 97.0100 97 40-160
Vinyl chloride ug/L 50.150 100 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
1,1,1,2-Tetrachloroethane ug/L 20.520 103 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.520 97 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 22.220 111 70-130ND
1,1-Dichloroethene ug/L 24.020 120 70-166ND
1,2,3-Trichloropropane ug/L 21.020 105 70-130ND
1,2-Dibromo-3-chloropropane ug/L 18.820 94 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.920 104 70-130ND
1,2-Dichlorobenzene ug/L 19.620 98 70-130ND
1,2-Dichloroethane ug/L 20.920 105 70-130ND
1,2-Dichloropropane ug/L 21.020 105 70-130ND
1,4-Dichlorobenzene ug/L 21.320 107 70-130ND
2-Butanone (MEK)ug/L 39.7J40 99 70-130ND
2-Hexanone ug/L 38.7J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.1J40 105 70-130ND
Acetone ug/L 40.9J40 102 70-130ND
Acrylonitrile ug/L 105J100 105 70-130ND
Benzene ug/L 22.020 110 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 20.620 103 70-130ND
Bromoform ug/L 18.220 91 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1679874MATRIX SPIKE SAMPLE:
MSSpike
Result
92288937001
Bromomethane ug/L 9.6J M1204870-130ND
Carbon disulfide ug/L 23.8J20 119 70-130ND
Carbon tetrachloride ug/L 22.320 111 70-130ND
Chlorobenzene ug/L 21.220 106 70-146ND
Chloroethane ug/L 23.720 118 70-130ND
Chloroform ug/L 21.120 105 70-130ND
Chloromethane ug/L 16.820 84 70-130ND
cis-1,2-Dichloroethene ug/L 22.520 113 70-130ND
cis-1,3-Dichloropropene ug/L 19.820 99 70-130ND
Dibromochloromethane ug/L 20.120 100 70-130ND
Dibromomethane ug/L 21.620 108 70-130ND
Ethylbenzene ug/L 20.820 104 70-130ND
Iodomethane ug/L 14.1 M1403570-130ND
Methylene Chloride ug/L 20.820 104 70-130ND
Styrene ug/L 20.320 101 70-130ND
Tetrachloroethene ug/L 21.520 107 70-130ND
Toluene ug/L 21.120 106 70-155ND
trans-1,2-Dichloroethene ug/L 22.920 115 70-130ND
trans-1,3-Dichloropropene ug/L 19.120 96 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.2J M1205670-130ND
Trichloroethene ug/L 21.520 107 69-151ND
Trichlorofluoromethane ug/L 23.320 116 70-130ND
Vinyl acetate ug/L 28.3J40 71 70-130ND
Vinyl chloride ug/L 23.720 118 70-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92288937002
1679875SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%98 099
4-Bromofluorobenzene (S)%94 498
Toluene-d8 (S)%100 298
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92288930
WAYNE MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92288930001 MPRP/20891 ICP/18813EBEPA 3010A EPA 6010
92288930002 MPRP/20891 ICP/18813FBEPA 3010A EPA 6010
92288930001 MSV/35830EBEPA 8260
92288930002 MSV/35830FBEPA 8260
92288930003 MSV/35830TBEPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/10/2016 09:47 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 21
Page 20 of 21
Page 21 of 21
Appendix B
Field Sampling Parameter Data Sheet(s)