8503_DukeBelewsCreekPineHall_April2017_1stSemiAnnual_DIN28147_20170705

Pine Hall Road Ash Landfill
Permit No. 8503
Semiannual Groundwater
Monitoring Report
April 2017 Sampling Event
Belews Creek Steam Station
July 10, 2017

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2017 Sampling Event
Contents

i
Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 – Results ....................................................................................................................... 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours

Tables
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. 15A NCAC 2L Groundwater Quality Standard Exceedances for Wells within the Review
Boundary
6. 15A NCAC 2L Groundwater Quality Standard Exceedances at or Beyond Review
Boundary

Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2017 Sampling Event
Section 1 – Background

1
Section 1 – Background
The Pine Hall Road Ash Landfill is located at the Duke Energy Carolinas, LLC (Duke Energy)
Belews Creek Steam Station in Stokes County, North Carolina. The landfill is permitted under
the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8503
and was closed in December 2008. The ash landfill was permitted to accept only fly ash from
Belews Creek Steam Station operations. The ash landfill and nearby surrounding area are
portrayed on Figure 1.
The landfill was originally permitted in 1983. The original landfill was unlined and was permitted
with a soil cap 1 foot thick on the side slopes and 2 feet thick on flatter areas. A subsequent
expansion (Phase I Expansion) was permitted in 2003. This phase was also unlined but was
permitted with a synthetic cap system to be applied at closure.
After groundwater exceedances were observed in wells installed near the landfill, the placement
of additional ash in the Phase I Expansion was halted. The closure design was changed to
utilize an engineered cover system for the portion of the landfill indicated on Figure 2. The
engineered cover system consists of a 40-mil linear low-density polyethylene geomembrane, a
geonet composite, 18 inches of compacted soil, and 6 inches of vegetative soil cover. The
engineered cover system was installed over a 37.9-acre area indicated on Figure 2 as
“Approximate Limits of Engineered Cover System.” An adjacent 14.5-acre area, located to the
northeast, had additional soil cover applied and was graded to improve surface drainage. This
area is indicated on Figure 2 as “Limits of Soil Cap.” The construction of the engineered cover
system and additional soil cover on the 14.5-acre area was completed in December 2008.
The ash landfill is located to the north of the surface water divide that runs along Pine Hall Road
and to the east of a surface water divide that runs along Middleton Loop Road. These surface
water divides appear to mimic the shallow groundwater divides in the area near the landfill. Two
surface water features are located in the area near the landfill. One surface water drainage
feature drains along the eastern side of the landfill to the ash basin. The second surface water
drainage feature is located on the western side of the landfill and drains to the ash basin. The
surface water sample locations in these features are groundwater seeps and are believed to be
representative of groundwater. Samples collected from these locations are compared to 15A
North Carolina Administrative Code (NCAC) 2L groundwater quality standards (2L Standards).
Groundwater flow beneath the landfill is from Pine Hall Road, generally northward, toward the
ash basin. The ash basin is operated as a water treatment facility and is permitted by the
National Pollutant Discharge Elimination System (NPDES) program (NPDES Permit
#NC0024406).
The groundwater monitoring system at the landfill consists of the following sample locations as
listed below.

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 1 – Background

2
Monitoring Wells: MW-1 MW-1D
MW-2 MW-3
MW-4 MW-5
MW-6 MW-7
MW2-7 MW2-9
OB-4 OB-5
OB-9

Surface Water Locations: SW-1A SW-2

The locations of the monitoring wells and surface water sample locations are shown on
Figure 2. Monitoring well construction information is presented in Table 1. As defined by the
Groundwater Monitoring, Sampling and Analysis Plan (SAP) for the Pine Hall Road Ash Landfill
(prepared by S&ME, Inc. dated November 8, 2010, and approved by NCDEQ on November 23,
2010), monitoring well MW-3 is considered to represent background groundwater quality
conditions.
The groundwater and surface water sampling was conducted by Duke Energy according to
North Carolina Solid Waste Management Guidelines. The constituents sampled and analyzed
were selected by Duke Energy and the NCDEQ Division of Solid Waste and are listed in the
SAP. The samples were analyzed by a North Carolina certified laboratory.
During previous sampling events, the groundwater samples were also analyzed for Part 40
Code of Federal Regulations (CFR) Part 258, Appendix I constituents, in addition to the
constituents listed in the SAP. Appendix I sampling and analysis was performed as part of the
requirements contained in the Closure Plan Approval letter dated December 7, 2007, Document
ID RC03425.
Sampling of Appendix I volatile organic compounds has been discontinued as per a June 8,
2015, electronic mail correspondence from Elizabeth Werner of the NCDEQ Solid Waste
Section. A copy of this correspondence is retained in Duke Energy’s operating record.
Appendix I inorganics that are not already part of the Belews Creek Pine Hall Road Landfill
Sampling and Analysis Plan are identified in Table 4.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2017 Sampling Event
Section 2 – Methods

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193). Copies of the field
sampling forms are included in Appendix A. The groundwater samples were analyzed by the
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) and provided
to HDR by Duke Energy. The laboratory report and chain-of-custody forms are included in
Appendix B.
The groundwater samples were analyzed for the following constituents and/or parameters:
 Barium, beryllium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using Solid Waste (SW)-8461 Method 6010D
 Antimony, arsenic, cadmium, cobalt, lead, selenium, thallium, and vanadium using
SW-846 Method 6020B
 Mercury using United States Environmental Protection Agency (EPA) SW-846 Method
7470A
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA SW-846 Method 9056A
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy for monitoring wells MW-1,
MW-1D, MW-3, MW-4, MW-5, MW-6, MW-7, MW2-7, MW2-9, OB-4, OB-5, and OB-9
and surface water sampling locations SW-1A and SW-2. A groundwater sample was not
collected from MW-2 due to insufficient water volume in the well. However, a
groundwater level measurement was able to be collected from MW-2. The samples were
collected by Duke Energy personnel on April 11, 2017, and HDR received the data on
March 7, 2017.
 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDD) provided by Duke Energy was adapted to conform to the format requirements of
the NCDEQ EDD template. HDR added an italicized J data qualifier (J) to indicate a
detected concentration that equals or is greater than the laboratory’s method reporting

1 EPA Hazardous Waste Test Methods (SW-846) available online at https://www.epa.gov/hw-sw846
(accessed August 30, 2016)
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 2 – Methods

4
limit (MRL), but is less than the Solid Waste Section Limit2 (SWSL). A copy of the original
EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater contours.
 Prepared this Semiannual Groundwater Monitoring Report and submitted it to Duke
Energy.

2 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
April 2017 Sampling Event
Section 3 – Results

5
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the wells on the date of sampling. Calculated groundwater flow velocities are
presented in Table 2.
Pine Hall Road is located generally along a surface water divide that also appears to be a
groundwater divide. Groundwater flow at the landfill site is from areas of higher topography
along Pine Hall Road, generally northward, toward the ash basin.
3.2 Analytical Results
Field data recorded during this sampling event is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analytical results are compared to the groundwater standards found in Title 15A
NCAC 02L .0202 (g) (2L Standards). Concentrations that attain or exceed the 2L Standards or
Interim Maximum Allowable Concentrations (IMACs) are noted in Table 4 by bold font.
Concentrations that equal or are greater than the SWSLs are noted in Table 4 by gray-shaded
cells.
A summary of the 2L Standard exceedances and a preliminary analysis of the cause and
significance of the exceedances are presented in Table 5 for sampling locations located within
the review boundary and in Table 6 for sampling locations located at or beyond the review
boundary.
Select samples were diluted as is normal laboratory practice to bring samples to the calibrated
range of the analysis. Specifics regarding the samples that were diluted, including the dilution
factor, are reported in the EDD.
HDR previously prepared and submitted an assessment to the NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station Pine Hall
Road Ash Landfill, Permit No. 8503, dated October 1, 2012). The report assessed 2L Standard
exceedances at wells MW-3 and MW-6 and found those exceedances to be attributed to
naturally occurring conditions.
The assessment report reviewed the location of wells and surface water sample locations with
exceedances of 2L Standards (MW-4, MW-7, MW2-7, MW2-9, SW-1A, and SW-2) and found
that the hydrologic boundaries and the groundwater flow at the site was such that the
groundwater at these locations was discharging to the ash basin. The report also concluded that
with the reduced infiltration, due to the engineered cover system installed in 2008, the
groundwater concentration of constituents attributable to fly ash in these wells will likely
continue to decrease over time.

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FIGURE
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BELEWS CREEK STEAM STATION
PINE HALL ROAD ASH LANDFILL
PERMIT NO. 8503
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2
1
.
6
0
 ‐ 36.60

S
a
p
r
o
l
i
t
e

2

P
V
C
OB
‐9

3
/
1
1
/
2
0
0
4

3
6
.
2
8
3
3
4
9
1
‐80
.
0
8
1
0
8
7
2

7
9
9
.
5
9

7
9
7
.
1
1

2
.
4
8

7
6
1
.
6
7

3
7
.
9
2

4
8
.
5
7

3
9
.
1
7

3
9
.
1
7
 ‐ 48.57

P
W
R

2

P
V
C
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
TO
C
 in
d
i
c
a
t
e
s
 to
p
 of
 ca
s
i
n
g
ft
 in
d
i
c
a
t
e
s
 fe
e
t
in
 in
d
i
c
a
t
e
s
 in
c
h
e
s
 no
m
i
n
a
l
 di
a
m
e
t
e
r
PV
C
 in
d
i
c
a
t
e
s
 po
l
y
v
i
n
y
l
 ch
l
o
r
i
d
e
To
p
 of
 ca
s
i
n
g
 an
d
 gr
o
u
n
d
 su
r
f
a
c
e
 el
e
v
a
t
i
o
n
s
 fr
o
m
 Ja
n
u
a
r
y
 20
1
5
 re
‐su
r
v
e
y
 by
 Pr
o
v
i
d
e
n
c
e
 La
n
d
 Gr
o
u
p
Ho
r
i
z
o
n
t
a
l
 da
t
u
m
 as
s
u
m
e
d
 to
 be
 NA
D
8
3
El
e
v
a
t
i
o
n
s
 ba
s
e
d
 on
 NA
V
D
 88
 ve
r
t
i
c
a
l
 da
t
u
m
De
p
t
h
 to
 wa
t
e
r
 ga
u
g
e
d
 on
 Ja
n
u
a
r
y
 11
,
 20
1
7
In
f
o
r
m
a
t
i
o
n
 pr
o
v
i
d
e
d
 by
 Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
 on
 Ma
r
c
h
 7,
 20
1
7
PW
R
 in
d
i
c
a
t
e
s
 pa
r
t
i
a
l
l
y
 we
a
t
h
e
r
e
d
 ro
c
k
To
t
a
l
 we
l
l
 de
p
t
h
s
 fr
o
m
 20
1
5
 we
l
l
 de
p
t
h
 co
n
f
i
r
m
a
t
i
o
n
Ta
b
l
e
 2  ‐

Gr
o
u
n
d
w
a
t
e
r
 Fl
o
w
 Ve
l
o
c
i
t
i
e
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
B
e
l
e
w
s
 Cr
e
e
k
 St
e
a
m
 St
a
t
i
o
n
Pi
n
e
 Ha
l
l
 Ro
a
d
 As
h
 La
n
d
f
i
l
l
 ‐

Pe
r
m
i
t
 No
.
 85
0
3
We
l
l
 ID
Up
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Do
w
n
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r
Fl
o
w
Di
s
t
a
n
c
e
(f
t
)
Hy
d
r
a
u
l
i
c
Gr
a
d
i
e
n
t
Hy
d
r
a
u
l
i
c
Co
n
d
u
c
t
i
v
i
t
y
(f
t
/
d
a
y
)
Effective Porosity (%)Groundwater Velocity (ft/day)
MW
‐4

7
6
0

7
5
5
.
3
9

1
2
0

0
.
0
4

0
.
4
1
1

0
.
2
5
9

0
.
0
6
MW
‐7

8
0
7
.
8
0

8
0
0

2
1
0

0
.
0
4

0
.
4
1
1

0
.
2
5
9

0
.
0
6
OB
‐4

7
6
0

7
5
5
.
3
6

6
1

0
.
0
8

0
.
4
1
1

0
.
2
5
9

0
.
1
2
OB
‐5

7
6
0

7
5
5
.
7
7

1
2
4

0
.
0
3

0
.
4
1
1

0
.
2
5
9

0
.
0
5
OB
‐9

7
7
0

7
6
0

1
6
7

0
.
0
6

0
.
4
1
1

0
.
2
5
9

0
.
1
0
MW
2
‐7

7
7
0

7
6
0

4
9

0
.
2
1

0
.
4
1
1

0
.
2
5
9

0
.
3
3
MW
2
‐9

8
0
0

7
9
0

1
2
2

0
.
0
8

0
.
4
1
1

0
.
2
5
9

0
.
1
3
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
Hy
d
r
a
u
l
i
c
 co
n
d
u
c
t
i
v
i
t
y
 pr
e
s
e
n
t
e
d
 is
 th
e
 ge
o
m
e
t
r
i
c
 me
a
n
 of
 th
e
 co
n
d
u
c
t
i
v
i
t
y
 da
t
a
 for  the  
on
 Ja
n
u
a
r
y
 11
,
 20
1
7
al
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e
 hy
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c
 la
y
e
r
 in
 th
e
 HD
R
 Co
n
d
u
c
t
i
v
i
t
y
 Da
t
a
b
a
s
e
 (unpublished  
da
t
a
 fr
o
m
 Ca
r
o
l
i
n
a
 si
t
e
s
 wi
t
h
 fo
l
i
a
t
e
d
/
l
a
y
e
r
e
d
 be
d
r
o
c
k
)
Ef
f
e
c
t
i
v
e
 po
r
o
s
i
t
y
 pr
e
s
e
n
t
e
d
 is
 th
e
 me
a
n
 va
l
u
e
 of
 th
e
 al
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e
 hy
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c
la
y
e
r
 es
t
i
m
a
t
e
d
 fr
o
m
 so
i
l
 te
s
t
i
n
g
 us
i
n
g
 Fe
t
t
e
r
/
B
e
a
r
 Di
a
g
r
a
m
s
Hy
d
r
a
u
l
i
c
 gr
a
d
i
e
n
t
s
 an
d
 gr
o
u
n
d
w
a
t
e
r
 ve
l
o
c
i
t
i
e
s
 ca
l
c
u
l
a
t
e
d
 us
i
n
g
 gr
o
u
n
d
w
a
t
e
r
 de
p
t
h
 measured
At
 mo
n
i
t
o
r
i
n
g
 we
l
l
 lo
c
a
t
i
o
n
s
 wh
e
r
e
 up
g
r
a
d
i
e
n
t
 co
n
t
o
u
r
s
 ar
e
 no
t
 pr
e
s
e
n
t
,
 th
e
 gr
o
u
n
d
w
a
t
e
r

el
e
v
a
t
i
o
n
 at
 th
e
 mo
n
i
t
o
r
i
n
g
 we
l
l
 is
 us
e
d
 as
 th
e
 up
g
r
a
d
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 el
e
v
a
t
i
o
n
.
Mo
n
i
t
o
r
i
n
g
 we
l
l
s
 ar
e
 no
t
 li
s
t
e
d
 wh
e
r
e
 in
s
u
f
f
i
c
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 co
n
t
o
u
r
 in
f
o
r
m
a
t
i
o
n
 is  available
to
 ca
l
c
u
l
a
t
e
 ve
l
o
c
i
t
y
Hy
d
r
a
u
l
i
c
 gr
a
d
i
e
n
t
s
 an
d
 gr
o
u
n
d
w
a
t
e
r
 ve
l
o
c
i
t
i
e
s
 ar
e
 ap
p
r
o
x
i
m
a
t
e
.
ft
 in
d
i
c
a
t
e
s
 fe
e
t
Li
n
e
a
r
 di
s
t
a
n
c
e
 me
a
s
u
r
e
d
 th
r
o
u
g
h
 mo
n
i
t
o
r
i
n
g
 we
l
l
s
 is
 ge
n
e
r
a
l
l
y
 pe
r
p
e
n
d
i
c
u
l
a
r
 to
 groundwater
co
n
t
o
u
r
s
At
 mo
n
i
t
o
r
i
n
g
 we
l
l
 lo
c
a
t
i
o
n
s
 wh
e
r
e
 do
w
n
g
r
a
d
i
e
n
t
 co
n
t
o
u
r
s
 ar
e
 no
t
 pr
e
s
e
n
t
,
 th
e
 groundwater
el
e
v
a
t
i
o
n
 at
 th
e
 mo
n
i
t
o
r
i
n
g
 we
l
l
 is
 us
e
d
 as
 th
e
 do
w
n
g
r
a
d
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 el
e
v
a
t
i
o
n
Ta
b
l
e
 3  ‐

Fi
e
l
d
 Da
t
a
 Pa
r
a
m
e
t
e
r
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
B
e
l
e
w
s
 Cr
e
e
k
 St
e
a
m
 St
a
t
i
o
n
Pi
n
e
 Ha
l
l
 Ro
a
d
 As
h
 La
n
d
f
i
l
l
 ‐

Pe
r
m
i
t
 No
.
 85
0
3
Da
t
e

S
a
m
p
l
e
 ID
We
l
l
De
p
t
h
Be
l
o
w
TO
C
(f
t
)
De
p
t
h
 to
Wa
t
e
r
Be
l
o
w
TO
C
(f
t
)
Gr
o
u
n
d
w
a
t
e
r
El
e
v
a
t
i
o
n
(f
t
)

A
p
p
e
a
r
a
n
c
e

O
d
o
r

P
u
r
g
e
 Me
t
h
o
d
Av
e
r
a
g
e
Pu
m
p
 Ra
t
e
(m
L
/
m
i
n
)
We
l
l
Vo
l
u
m
e
(g
a
l
)
EV
A
C
Vo
l
u
m
e
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
Temperature (°C)Specific Conductance (µԼ /cm)pH (SU)Turbidity (NTU)ORP (mV ‐NHE)DO (mg/L)
4/
1
1
/
2
0
1
7

M
W
‐1

4
7
.
2
0

3
5
.
6
7

8
1
7
.
0
2

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
8
8

5
.
0
0

N
O

1
5
.
2
9

1
9

4
.
9

9
.
3

5
3
5

8
.
3
8
4/
1
1
/
2
0
1
7

M
W
‐1D

9
0
.
5
3

4
3
.
0
1

8
1
1
.
1
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

7
.
7
5

1
6
.
7
5

N
O

1
4
.
4
2

1
2
0

6
.
4

0
.
2

4
5
4

4
.
7
0
4/
1
1
/
2
0
1
7

M
W
‐2

5
0
.
0
0

4
6
.
5
1

8
1
1
.
5
4

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A

0
.
5
7

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S
4/
1
1
/
2
0
1
7

M
W
‐3

4
9
.
5
0

4
2
.
7
2

8
0
0
.
0
9

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A

1
.
1
1

0
.
5
0

N
/
A

1
4
.
3
9

5
8

5
.
6

2
.
0

4
7
7

9
.
4
5
4/
1
1
/
2
0
1
7

M
W
‐4

4
0
.
2
0

1
2
.
1
9

7
5
5
.
3
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

4
.
5
7

9
.
7
5

N
O

1
4
.
8
1

2
9
2

5
.
9

1
3
.
1

4
3
2

2
.
5
8
4/
1
1
/
2
0
1
7

M
W
‐5

6
0
.
2
0

2
5
.
5
9

7
6
1
.
1
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

5
.
6
4

1
1
.
2
5

N
O

1
4
.
6
7

3
6

5
.
6

6
.
3

4
7
7

6
.
9
2
4/
1
1
/
2
0
1
7

M
W
‐6

3
6
.
8
4

3
3
.
7
1

8
0
3
.
2

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A

0
.
5
1

0
.
5
0

N
/
A

1
5
.
6
3

6
4

5
.
4

1
.
6

4
6
9

4
.
4
1
4/
1
1
/
2
0
1
7

M
W
‐7

1
4
.
2
6

7
.
7
7

8
0
7
.
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
0
6

3
.
2
5

N
O

1
3
.
2
6

3
3
1

5
.
4

1
1
.
9

5
1
5

5
.
7
0
4/
1
1
/
2
0
1
7

M
W
2
‐7

3
0
.
6
2

1
4
.
2
8

7
6
3
.
3
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

2
.
6
7

1
3
.
7
5

N
O

1
4
.
4
9

1
9
9
5

5
.
1

3
.
4

5
6
2

0
.
0
0
4/
1
1
/
2
0
1
7

M
W
2
‐9

1
4
.
6
1

5
.
8
3

7
9
1
.
5
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
4
3

2
.
7
5

Y
E
S

1
3
.
5
4

2
6
5

5
.
8

9
.
4

4
9
3

1
.
2
2
4/
1
1
/
2
0
1
7

O
B
‐4

3
0
.
0
3

2
2
.
2
4

7
5
5
.
3
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
7

5
.
0
0

N
O

1
5
.
8
4

2
6
1
0

7
.
1

3
.
3

3
1
7

0
.
0
0
4/
1
1
/
2
0
1
7

O
B
‐5

3
6
.
6

2
5
.
1
6

7
5
5
.
7
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
8
7

6
.
0
0

N
O

1
5
.
5
4

2
6

5
.
2

3
.
3

4
7
1

5
.
8
0
4/
1
1
/
2
0
1
7

O
B
‐9

4
8
.
5
7

3
7
.
9
2

7
6
1
.
6
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
4

5
.
2
5

N
O

1
4
.
9
3

1
7
4
3

5
.
0

2
.
5

5
7
2

0
.
0
0
4/
1
1
/
2
0
1
7

S
W
‐1A

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
3
.
5
6

9
9
5

6
.
2

2
.
7

4
0
2

8
.
7
7
4/
1
1
/
2
0
1
7

S
W
‐2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
4
.
7
8

1
2
8

6
.
3

1
1
.
3

3
3
8

8
.
3
3
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
SU
 in
d
i
c
a
t
e
s
 st
a
n
d
a
r
d
 un
i
t
s
Duke  Energy  Carolinas  Field  #5193
N/
A
 in
d
i
c
a
t
e
s
 no
t
 ap
p
l
i
c
a
b
l
e
;
 NS
 in
d
i
c
a
t
e
s
 th
a
t
 no
 sa
m
p
l
e
 wa
s
 co
l
l
e
c
t
e
d
In
f
o
r
m
a
t
i
o
n
 pr
o
v
i
d
e
d
 by
 Br
y
a
n
 Mo
e
l
l
e
r
 of
 Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
 on
 Ma
r
c
h
 7,
 20
1
7
Pu
r
g
e
 Me
t
h
o
d
s
:
 LF
 = Lo
w
 Fl
o
w
,
 CP
 = Co
n
v
e
n
t
i
o
n
a
l
 Pu
r
g
e
 (3
‐5  we
l
l
 vo
l
u
m
e
s
)
,
 NP
 = No
 Pu
r
g
e
 (H
y
d
r
a
S
l
e
e
v
e
)
,
 EO
P
 = Eq
u
i
p
m
e
n
t
 On
l
y
 Pu
r
g
e
;
 av
e
r
a
g
e
 pu
m
p
 rate  applicable  to  LF  purging  only
EV
A
C
 in
d
i
c
a
t
e
s
 wh
e
t
h
e
r
 th
e
 wa
t
e
r
 le
v
e
l
 in
 th
e
 we
l
l
 wa
s
 dr
a
w
n
 do
w
n
 to
 th
e
 le
v
e
l
 of
 th
e
 pu
m
p
 du
r
i
n
g
 pu
r
g
i
n
g
Laboratory  Certification  Codes:
NT
U
 in
d
i
c
a
t
e
s
 ne
p
h
e
l
o
m
e
t
r
i
c
 tu
r
b
i
d
i
t
y
 un
i
t
s
mV
‐NH
E
 in
d
i
c
a
t
e
s
 mi
l
l
i
v
o
l
t
s
‐no
r
m
a
l
 hy
d
r
o
g
e
n
 el
e
c
t
r
o
d
e
ft
 in
d
i
c
a
t
e
s
 fe
e
t
mL
/
m
i
n
 in
d
i
c
a
t
e
s
 mi
l
l
i
l
i
t
e
r
s
 pe
r
 mi
n
u
t
e
ga
l
 in
d
i
c
a
t
e
s
 US
 ga
l
l
o
n
s
mg
/
L
 in
d
i
c
a
t
e
s
 mi
l
l
i
g
r
a
m
s
 pe
r
 li
t
e
r
°C
 in
d
i
c
a
t
e
s
 de
g
r
e
e
s
 ce
l
s
i
u
s
µԼ /c
m
 in
d
i
c
a
t
e
s
 mi
c
r
o
m
h
o
s
 pe
r
 ce
n
t
i
m
e
t
e
r
TO
C
 in
d
i
c
a
t
e
s
 to
p
 of
 ca
s
i
n
g
Ta
b
l
e
 4  ‐

Fi
e
l
d
 an
d
 An
a
l
y
t
i
c
a
l
 Re
s
u
l
t
s
 fo
r
 Se
m
i
a
n
n
u
a
l
 Co
n
s
t
i
t
u
e
n
t
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
B
e
l
e
w
s
 Cr
e
e
k
 St
e
a
m
 St
a
t
i
o
n
Pi
n
e
 Ha
l
l
 Ro
a
d
 As
h
 La
n
d
f
i
l
l
 ‐

Pe
r
m
i
t
 No
.
 85
0
3
Sa
m
p
l
e
 Da
t
e
:
Fi
e
l
d
 Sa
m
p
l
i
n
g
 Pe
r
f
o
r
m
e
d
 By
:
Pa
r
a
m
e
t
e
r

S
W
S
 ID

U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
i
o
n
Co
d
e
MDL

S
W
S
L
15A  NCAC 2L  Standard/IMAC Federal  MCL
Fi
e
l
d
 pH

3
2
0

S
U

5
1
9
3
‐‐NE

6
.
5
‐8.5

6
.
5
‐8.5*
Fi
e
l
d
 Sp
e
c
i
f
i
c
 Co
n
d
u
c
t
i
v
i
t
y

3
2
3

µ
Լ /c
m

5
1
9
3
‐‐NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
‐‐NE

N
E

N
E
To
p
 of
 Ca
s
i
n
g

3
2
8

f
e
e
t
‐
‐‐NE

N
E

N
E
De
p
t
h
 to
 Wa
t
e
r

3
1
8

f
e
e
t
‐
‐‐NE

N
E

N
E
Wa
t
e
r
 El
e
v
a
t
i
o
n

3
1
9

f
e
e
t
‐
‐‐NE

N
E

N
E
We
l
l
 De
p
t
h

4
1
1

f
e
e
t
‐
‐‐NE

N
E

N
E
An
t
i
m
o
n
y
*

1
3

µ
g
/
L

2
4
8
0.
1
0
6

U

0
.
1
0
6

U

0
.
1
0
6

U

0
.
1
0
6

U

0
.
1
0
6

U
0.106

6

1

6
Ar
s
e
n
i
c

1
4

µ
g
/
L

2
4
8
0.
1
7
1

J

0
.
0
7
8

U

0
.
1
8
4

J

0
.
1
6
8

J

0
.
6
0
1

J
0.078

1
0

1
0

1
0
Ba
r
i
u
m

1
5

µ
g
/
L

2
4
8
20
.
7
J'
0.
9
1
8

J

5
6
.
2
J'
4.
6
2

J

3
3
.
6
J'0.1

1
0
0

7
0
0

2
,
0
0
0
Be
r
y
l
l
i
u
m
*

2
3

µ
g
/
L

2
4
8
0.
2

U

0
.
2

U

0
.
2

U

0
.
2

U

0
.
2

U
0.2

1

4

4
Bo
r
o
n

4
2
8

µ
g
/
L

2
4
8
9.
5
3

J

9
.
5
2

J

5
.
3
8

J
86
4
4.09

J
3.3

N
E

7
0
0

N
E
Ca
d
m
i
u
m

3
4

µ
g
/
L

2
4
8
0.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U
0.101

1

2

5
Ch
l
o
r
i
d
e

4
5
5

µ
g
/
L

2
4
8
2,
1
8
0

7
,
9
6
0

1
1
,
1
0
0

2
,
8
5
0

2
,
0
4
0
22

N
E

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
*
Ch
r
o
m
i
u
m

5
1

µ
g
/
L

2
4
8
0.
5

U

0
.
5

U

4
.
7
5

J
13
.
9
1.58

J
0.5

1
0

1
0

1
0
0
Co
b
a
l
t
*

5
3

µ
g
/
L

2
4
8
1.
0
7
J'
0.
1
1
8

U

0
.
1
5
1

J

0
.
4
5

J

0
.
1
1
8

U
0.118

1
0

1

N
E
Co
p
p
e
r

5
4

µ
g
/
L

2
4
8
1.1
J

1
U

1
U

1
U

1
1
0
1

1
0

1
,
0
0
0

1
,
3
0
0
Fl
u
o
r
i
d
e

3
1
2

µ
g
/
L

2
4
8
17

U

1
2
1
J'
31
.
2

J

4
4
.
3

J

1
7

U
17

2
,
0
0
0

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0

µ
g
/
L

2
4
8
41
5
1.
9
1

J
30
6

9
4
4

3
5
4
1.3

3
0
0

3
0
0

3
0
0
*
*
Le
a
d

1
3
1

µ
g
/
L

2
4
8
1.
2
8
J'
0.
0
6
5

U

0
.
1
9

J

0
.
1
2
5

J

7
.
8
7
J'0.065

1
0

1
5

1
5
Ma
n
g
a
n
e
s
e

3
4
2

µ
g
/
L

2
4
8
31
.
7
J'
1.
7
3

J

6
.
2
5
J'
13
.
9
J'
10 J'0.2

5
0

5
0

5
0
*
*
Me
r
c
u
r
y

1
3
2

µ
g
/
L

2
4
8
0.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U
0.0334

0
.
2

1

2
Ni
c
k
e
l

1
5
2

µ
g
/
L

2
4
8
0.
5
1
5

J

0
.
5

U

2
.
0
9

J

1
.
8
1

J

0
.
5

U
0.5

5
0

1
0
0

N
E
Nit
r
a
t
e
 (a
s
 Ni
t
r
o
g
e
n
)

3
0
3

µ
g
/
L

2
4
8
17
9
J'
1,
9
1
0
J'
5.
4

U

1
,
1
8
0
J'
619 J'5.4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3

µ
g
/
L

2
4
8
0.
0
9
2

U

0
.
0
9
2

U

0
.
0
9
2

U
21
.
1
0.122

J
0.092

1
0

2
0

5
0
Si
l
v
e
r

1
8
4

µ
g
/
L

2
4
8
1.
2
8

J

0
.
7

U

1
.
4
5

J

1
.
4
5

J

1
.
3
7

J
0.7

1
0

2
0

1
0
0
*
*
Su
l
f
a
t
e

3
1
5

µ
g
/
L

2
4
8
1,
1
9
0
J'
96
1
J'
27
6
J'
96
,
3
0
0
J'
105 J'18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
*
Th
a
l
l
i
u
m
*

1
9
4

µ
g
/
L

2
4
8
0.
1
3
3

U

0
.
1
3
3

U

0
.
1
3
3

U

0
.
1
3
3

U

0
.
1
3
3

U
0.133

5
.
5

0
.
2

2
To
t
a
l
 Di
s
s
o
l
v
e
d
 So
l
i
d
s

3
1
1

µ
g
/
L

2
4
8
38
,
0
0
0

8
4
,
0
0
0

4
1
,
0
0
0

2
1
4
,
0
0
0

3
7
,
0
0
0
16,700

N
E

5
0
0
,
0
0
0

5
0
0
,
0
0
0
*
*
Va
n
a
d
i
u
m
*

2
0
9

µ
g
/
L

2
4
8
0.
5
3
1
J
0.
4
5
4
J
1.
0
3
J'
4.
2
9
J'
0.947 J 0.053

2
5

0
.
3

N
E
Zi
n
c

2
1
3

µ
g
/
L

2
4
8
6.
7
4
J'
2.
6

U

4
.
3
8

J

5
.
0
1
J'
61.4 2.6

1
0

1
,
0
0
0

5
,
0
0
0
*
*
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
17
.
18
.
19
.
In
s
u
f
f
i
c
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 in
 MW
‐2  pr
e
v
e
n
t
e
d
 sa
m
p
l
i
n
g
"J
"
 is
 us
e
d
 to
 id
e
n
t
i
f
y
 es
t
i
m
a
t
e
d
 co
n
c
e
n
t
r
a
t
i
o
n
s
 wh
i
c
h
 eq
u
a
l
 or
 ar
e
 gr
e
a
t
e
r
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a
n
 th
e
 MD
L
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t
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e
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s
s
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a
n
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e
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b
o
r
a
t
o
r
y
'
s
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t
h
o
d
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p
o
r
t
i
n
g
 li
m
i
t
 (M
R
L
)
,
an
d
 an
 it
a
l
i
c
i
z
e
d
 J'‐fl
a
g
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t
a
 qu
a
l
i
f
i
e
r
,
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d
e
d
 by
 HD
R
 to
 in
d
i
c
a
t
e
 co
n
c
e
n
t
r
a
t
i
o
n
s
 wh
i
c
h
 eq
u
a
l
 or
 ar
e
 gr
e
a
t
e
r
 th
a
n
 th
e
 la
b
o
r
a
t
o
r
y
'
s
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L
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t
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e
 le
s
s
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a
n
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e
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S
L
An
a
l
y
t
i
c
a
l
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s
u
l
t
s
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t
a
i
n
e
d
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o
m
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e
c
t
r
o
n
i
c
 Da
t
a
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l
i
v
e
r
a
b
l
e
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D
D
)
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o
v
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d
e
d
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 Br
y
a
n
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e
l
l
e
r
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k
e
 En
e
r
g
y
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r
o
l
i
n
a
s
,
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C
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r
c
h
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1
7
36
49
.
5
0
80
0
.
0
9
42
.
7
2
46
.
5
1
81
1
.
5
4
50
.
0
0
90
.
5
3
81
1
.
1
4
43
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0
1
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9
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14
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2
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y
e
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l
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e
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a
t
e
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l
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e
s
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t
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u
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l
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e
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e
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t
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r
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n
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S
L
85
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Se
m
i
a
n
n
u
a
l
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n
s
t
i
t
u
e
n
t
s
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f
e
r
s
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n
s
t
i
t
u
e
n
t
s
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q
u
i
r
e
d
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a
l
y
z
e
d
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 th
e
 Gr
o
u
n
d
w
a
t
e
r
 Mo
n
i
t
o
r
i
n
g
,
 Sa
m
p
l
i
n
g
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d
 An
a
l
y
s
i
s
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a
n
 fo
r
 th
e
 Pi
n
e
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l
l
 Ro
a
d
 As
h
 La
n
d
f
i
l
l
 da
t
e
d
 No
v
e
m
b
e
r
 1, 2008
MC
L
 is
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e
 Fe
d
e
r
a
l
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x
i
m
u
m
 Co
n
t
a
m
i
n
a
n
t
 Le
v
e
l
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 fo
u
n
d
 in
 40
 CF
R
,
 Su
b
p
a
r
t
 G,
 §1
4
1
.
6
2
Ma
x
i
m
u
m
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l
o
w
a
b
l
e
 Co
n
c
e
n
t
r
a
t
i
o
n
s
 (I
M
A
C
s
)
**
 Co
n
c
e
n
t
r
a
t
i
o
n
 li
s
t
e
d
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 a  se
c
o
n
d
a
r
y
 ma
x
i
m
u
m
 co
n
t
a
m
i
n
a
n
t
 le
v
e
l
 (S
M
C
L
)
;
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C
L
s
 ar
e
 es
t
a
b
l
i
s
h
e
d
 by
 EP
A
 in
 th
e
 Na
t
i
o
n
a
l
 Se
c
o
n
d
a
r
y
 Dr
i
n
k
i
n
g
 Wa
t
e
r
 Re
g
u
l
a
t
i
o
n
s
 as
 fo
u
n
d
 in
 40
 CF
R
 §143.3
by
 th
e
 la
b
o
r
a
t
o
r
y
 fo
r
 th
e
 an
a
l
y
s
e
s
 co
m
p
l
e
t
e
d
;
 th
e
r
e
f
o
r
e
,
 th
e
 SW
S
L
 an
d
 2L
 St
a
n
d
a
r
d
 lis
t
e
d
 ar
e
 fo
r
 th
e
 ch
l
o
r
i
d
e
 wi
t
h
 CA
S
 nu
m
b
e
r
 SW
3
0
1
 as
 sp
e
c
i
f
i
e
d
 on
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
‐up
 we
b
p
a
g
e
 (last  updated  June  13, 2011)
SW
S
L
 is
 th
e
 So
l
i
d
 Wa
s
t
e
 Se
c
t
i
o
n
 Li
m
i
t
.
 NC
D
E
Q
 de
f
i
n
e
s
 th
e
 SW
S
L
 as
 th
e
 lo
w
e
s
t
 am
o
u
n
t
 of
 an
a
l
y
t
e
 in
 a  sa
m
p
l
e
 th
a
t
 ca
n
 be
 qu
a
n
t
i
t
a
t
i
v
e
l
y
 de
t
e
r
m
i
n
e
d
 wi
t
h
 su
i
t
a
b
l
e
 pr
e
c
i
s
i
o
n
 an
d
 ac
c
u
r
a
c
y
Qu
a
l
i
f
i
e
r
s
 in
 no
n
‐it
a
l
i
c
i
z
e
d
 te
x
t
 ar
e
 la
b
o
r
a
t
o
r
y
 da
t
a
 qu
a
l
i
f
i
e
r
s
 or
 "f
l
a
g
s
"
,
 "U
"
 is
 us
e
d
 to
 id
e
n
t
i
f
y
 re
s
u
l
t
s
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t
 de
t
e
c
t
e
d
 at
 co
n
c
e
n
t
r
a
t
i
o
n
s
 wh
i
c
h
 eq
u
a
l
 th
e
 la
b
o
r
a
t
o
r
y
'
s
 MD
L
,
SW
S
 ID
 is
 th
e
 So
l
i
d
 Wa
s
t
e
 Se
c
t
i
o
n
 Id
e
n
t
i
f
i
c
a
t
i
o
n
 Nu
m
b
e
r
Ac
c
o
r
d
i
n
g
 to
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
‐up
 we
b
p
a
g
e
 on
 th
e
 NC
D
E
Q
 Di
v
i
s
i
o
n
 of
 Wa
s
t
e
 Ma
n
a
g
e
m
e
n
t
 we
b
p
a
g
e
,
 th
e
r
e
 is
 no
 SW
S
L
 or
 2L
 St
a
n
d
a
r
d
 fo
r
 ch
o
r
i
d
e
 as
s
o
c
i
a
t
e
d
 wi
t
h
 CA
S
 nu
m
b
e
r
 16
8
8
7
‐08 ‐6, which  is  the  CAS  reported   
µg
/
L
 in
d
i
c
a
t
e
s
 mic
r
o
g
r
a
m
s
 pe
r
 li
t
e
r
NE
 in
d
i
c
a
t
e
s
 no
t
 es
t
a
b
l
i
s
h
e
d
;
 NA
 in
d
i
c
a
t
e
s
 no
t
 an
a
l
y
z
e
d
;
 bl
a
n
k
 ce
l
l
s
 in
d
i
c
a
t
e
 th
a
t
 th
e
r
e
 is
 no
 in
f
o
r
m
a
t
i
o
n
 re
l
e
v
a
n
t
 to
 th
e
 re
s
p
e
c
t
i
v
e
 ro
w
15
A
 NC
A
C
 2L
 St
a
n
d
a
r
d
 re
f
e
r
s
 to
 Cl
a
s
s
 GA
 St
a
n
d
a
r
d
s
 as
 fo
u
n
d
 in
 15
A
 NC
A
C
 02
L
 .0
2
0
2
 Gr
o
u
n
d
w
a
t
e
r
 Qu
a
l
i
t
y
 St
a
n
d
a
r
d
s
,
 la
s
t
 am
e
n
d
e
d
 on
 Ap
r
i
l
 1,
 20
1
3
* 40
 CF
R
 Pa
r
t
 25
8
 Ap
p
e
n
d
i
x
 I  in
o
r
g
a
n
i
c
s
 ar
e
 re
p
o
r
t
e
d
.

Th
e
y
 ar
e
 no
t
 in
c
l
u
d
e
d
 in
 th
e
 Pi
n
e
 Ha
l
l
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a
d
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n
d
f
i
l
l
 sa
m
p
l
i
n
g
 an
d
 an
a
l
y
s
i
s
 pl
a
n
;
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n
s
t
i
t
u
e
n
t
s
 ar
e
 co
m
p
a
r
e
d
 to
 No
r
t
h
 Ca
r
o
l
i
n
a
 In
t
e
r
i
m

°C
 in
d
i
c
a
t
e
s
 de
g
r
e
e
s
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l
s
i
u
s
Bo
l
d
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l
u
e
s
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d
i
c
a
t
e
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l
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e
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t
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i
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A
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n
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r
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o
r
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r
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t
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t
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e
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m
p
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e
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t
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l
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e
d
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e
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b
o
r
a
t
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r
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r
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n
g
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a
l
y
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i
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d
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c
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t
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s
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r
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n
t
i
m
e
t
e
r
76
7
.
5
8
Laboratory  Certification  Codes:Duke  Energy  Carolinas  Field  #5193 Duke  Energy  Analytical  Laboratory  #248
MW
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No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
17
.
18
.
An
a
l
y
t
i
c
a
l
 re
s
u
l
t
s
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t
a
i
n
e
d
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o
m
 El
e
c
t
r
o
n
i
c
 Da
t
a
 De
l
i
v
e
r
a
b
l
e
 (E
D
D
)
 pr
o
v
i
d
e
d
 by
 Br
y
a
n
 Mo
e
l
l
e
r
 of
 Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
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C
 on
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r
c
h
 7,
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1
7
36.6
14
.
6
1

3
0
.
0
3
36
.
8
4
SW
S
L
 is
 th
e
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l
i
d
 Wa
s
t
e
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c
t
i
o
n
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m
i
t
.
 NC
D
E
Q
 de
f
i
n
e
s
 th
e
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S
L
 as
 th
e
 lo
w
e
s
t
 am
o
u
n
t
 of
 an
a
l
y
t
e
 in
 a  sa
m
p
l
e
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a
t
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n
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a
n
t
i
t
a
t
i
v
e
l
y
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t
e
r
m
i
n
e
d
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t
h
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i
t
a
b
l
e
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e
c
i
s
i
o
n
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d
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c
u
r
a
c
y
Ac
c
o
r
d
i
n
g
 to
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
‐up
 we
b
p
a
g
e
 on
 th
e
 NC
D
E
Q
 Di
v
i
s
i
o
n
 of
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s
t
e
 Ma
n
a
g
e
m
e
n
t
 we
b
p
a
g
e
,
 th
e
r
e
 is
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S
L
 or
 2L
 St
a
n
d
a
r
d
 fo
r
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o
r
i
d
e
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s
o
c
i
a
t
e
d
 wi
t
h
 CA
S
 nu
m
b
e
r
 16
8
8
7
‐08 ‐6, which  is  the  CAS  reported   
by
 th
e
 la
b
o
r
a
t
o
r
y
 fo
r
 th
e
 an
a
l
y
s
e
s
 co
m
p
l
e
t
e
d
;
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e
r
e
f
o
r
e
,
 th
e
 SW
S
L
 an
d
 2L
 St
a
n
d
a
r
d
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s
t
e
d
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e
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r
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e
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l
o
r
i
d
e
 wi
t
h
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S
 nu
m
b
e
r
 SW
3
0
1
 as
 sp
e
c
i
f
i
e
d
 on
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
‐up
 we
b
p
a
g
e
 (last  updated  June  13, 2011)
NE
 in
d
i
c
a
t
e
s
 no
t
 es
t
a
b
l
i
s
h
e
d
;
 NA
 in
d
i
c
a
t
e
s
 no
t
 an
a
l
y
z
e
d
;
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a
n
k
 ce
l
l
s
 in
d
i
c
a
t
e
 th
a
t
 th
e
r
e
 is
 no
 in
f
o
r
m
a
t
i
o
n
 re
l
e
v
a
n
t
 to
 th
e
 re
s
p
e
c
t
i
v
e
 ro
w
Gr
a
y
e
d
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l
u
e
s
 in
d
i
c
a
t
e
 va
l
u
e
s
 th
a
t
 eq
u
a
l
 or
 ar
e
 gr
e
a
t
e
r
 th
a
n
 th
e
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S
L
Bo
l
d
 va
l
u
e
s
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d
i
c
a
t
e
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l
u
e
s
 th
a
t
 at
t
a
i
n
 or
 ex
c
e
e
d
 th
e
 15
A
 NC
A
C
 2L
 St
a
n
d
a
r
d
MD
L
 is
 th
e
 la
b
o
r
a
t
o
r
y
 me
t
h
o
d
 de
t
e
c
t
i
o
n
 li
m
i
t
.
 Th
e
 MD
L
 va
l
u
e
s
 pr
e
s
e
n
t
e
d
 ar
e
 fo
r
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m
p
l
e
s
 no
t
 di
l
u
t
e
d
 by
 th
e
 la
b
o
r
a
t
o
r
y
 du
r
i
n
g
 an
a
l
y
s
i
s
SW
S
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 is
 th
e
 So
l
i
d
 Wa
s
t
e
 Se
c
t
i
o
n
 Id
e
n
t
i
f
i
c
a
t
i
o
n
 Nu
m
b
e
r
Qu
a
l
i
f
i
e
r
s
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 no
n
‐it
a
l
i
c
i
z
e
d
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x
t
 ar
e
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b
o
r
a
t
o
r
y
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t
a
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a
l
i
f
i
e
r
s
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 "f
l
a
g
s
"
,
 "U
"
 is
 us
e
d
 to
 id
e
n
t
i
f
y
 re
s
u
l
t
s
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t
 de
t
e
c
t
e
d
 at
 co
n
c
e
n
t
r
a
t
i
o
n
s
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i
c
h
 eq
u
a
l
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e
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b
o
r
a
t
o
r
y
'
s
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L
,
SU
 in
d
i
c
a
t
e
s
 st
a
n
d
a
r
d
 un
i
t
s
30
.
6
2
5.2
"J
"
 is
 us
e
d
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e
n
t
i
f
y
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t
i
m
a
t
e
d
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n
c
e
n
t
r
a
t
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o
n
s
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i
c
h
 eq
u
a
l
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e
 gr
e
a
t
e
r
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a
n
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e
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L
 bu
t
 ar
e
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s
s
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a
n
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e
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b
o
r
a
t
o
r
y
'
s
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t
h
o
d
 re
p
o
r
t
i
n
g
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m
i
t
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R
L
)
,
an
d
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 it
a
l
i
c
i
z
e
d
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a
g
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t
a
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l
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f
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e
d
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R
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d
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c
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t
e
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n
c
e
n
t
r
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t
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n
s
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c
h
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u
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l
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e
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e
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t
e
r
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a
n
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e
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b
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r
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t
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r
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s
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L
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t
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e
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s
s
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n
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e
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S
L
15
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C
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n
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r
d
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s
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s
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n
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r
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u
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C
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o
u
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t
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r
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y
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n
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r
d
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s
t
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e
n
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e
d
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r
i
l
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1
3
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R
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r
t
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p
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n
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s
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e
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r
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.

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e
y
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t
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M
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s
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Laboratory  Certification  Codes:Duke  Energy  Carolinas  Field  #5193 Duke  Energy  Analytical  Laboratory  #248
MW
‐6M
W
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2
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No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
17
.
18
.
‐‐
OB
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37
.
9
2
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‐
‐
‐‐‐‐

‐
‐
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48
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5
7
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t
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t
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t
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e
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s
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 Se
c
t
i
o
n
 Li
m
i
t
.
 NC
D
E
Q
 de
f
i
n
e
s
 th
e
 SW
S
L
 as
 th
e
 lo
w
e
s
t
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o
u
n
t
 of
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a
l
y
t
e
 in
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m
p
l
e
 th
a
t
 ca
n
 be
 qu
a
n
t
i
t
a
t
i
v
e
l
y
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t
e
r
m
i
n
e
d
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h
 su
i
t
a
b
l
e
 precision  and  accuracy
‐‐

‐
‐
14
.
7
8
**
 Co
n
c
e
n
t
r
a
t
i
o
n
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s
t
e
d
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c
o
n
d
a
r
y
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x
i
m
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m
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n
t
a
m
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n
a
n
t
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v
e
l
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M
C
L
)
;
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C
L
s
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t
a
b
l
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s
h
e
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A
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e
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t
i
o
n
a
l
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c
o
n
d
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r
y
 Dr
i
n
k
i
n
g
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t
e
r
 Re
g
u
l
a
t
i
o
n
s
 as  found  in  40  CFR  §143.3
* 40
 CF
R
 Pa
r
t
 25
8
 Ap
p
e
n
d
i
x
 I  in
o
r
g
a
n
i
c
s
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e
 re
p
o
r
t
e
d
.

Th
e
y
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e
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t
 in
c
l
u
d
e
d
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 th
e
 Pin
e
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l
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a
d
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n
d
f
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l
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m
p
l
i
n
g
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d
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a
l
y
s
i
s
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a
n
;
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n
s
t
i
t
u
e
n
t
s
 ar
e
 co
m
p
a
r
e
d
 to  North  Carolina  Interim  Laboratory  Certification  Codes:
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
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C
Duke  Energy  Carolinas  Field  #5193 Duke  Energy  Analytical  Laboratory  #248
Ja
n
u
a
r
y
 11
,
 20
1
7
SW
‐2

F
i
e
l
d
 Bl
a
n
k
14
.
9
3

1
3
.
5
6
79
9
.
5
9
‐‐
12
8
‐‐
6.
3
Ac
c
o
r
d
i
n
g
 to
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
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 we
b
p
a
g
e
 on
 th
e
 NC
D
E
Q
 Di
v
i
s
i
o
n
 of
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s
t
e
 Ma
n
a
g
e
m
e
n
t
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b
p
a
g
e
,
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e
r
e
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S
L
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 St
a
n
d
a
r
d
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r
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o
r
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d
e
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s
o
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t
e
d
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NS
SW
‐1A
76
1
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6
7
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d
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a
l
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t
a
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R
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d
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t
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e
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r
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n
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by
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a
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,
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S
L
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d
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e
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l
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h
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S
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m
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e
r
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3
0
1
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 on
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µg
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d
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c
a
t
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s
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l
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s
t
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n
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t
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t
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a
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o
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m
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e
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l
l
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a
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up
d
a
t
e
d
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n
e
 13
,
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1
1
)
15
A
 NC
A
C
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a
n
d
a
r
d
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f
e
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s
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s
s
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a
n
d
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s
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A
C
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L
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2
0
2
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o
u
n
d
w
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r
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a
l
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y
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a
n
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t
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e
n
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r
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l
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1
3
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L
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e
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d
e
r
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l
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x
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m
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i
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a
n
t
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v
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l
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u
n
d
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 CF
R
,
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b
p
a
r
t
 G,
 §1
4
1
.
6
2
Ta
b
l
e
 5  ‐

Se
m
i
a
n
n
u
a
l
 Co
n
s
t
i
t
u
e
n
t
s
 15
A
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A
C
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o
u
n
d
w
a
t
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r
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a
l
i
t
y
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c
e
e
d
a
n
c
e
s

fo
r
 We
l
l
s
 Wi
t
h
i
n
 Re
v
i
e
w
 Bo
u
n
d
a
r
y
Du
k
e
 En
e
r
g
y
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r
o
l
i
n
a
s
,
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C
/
B
e
l
e
w
s
 Cr
e
e
k
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a
m
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a
t
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n
Pi
n
e
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l
l
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a
d
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h
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n
d
f
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l
l
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Pe
r
m
i
t
 No
.
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0
3
Sa
m
p
l
e
 Da
t
e
:
Pa
r
a
m
e
t
e
r

S
a
m
p
l
e
 ID

R
e
s
u
l
t

U
n
i
t
s
15
A
 NC
A
C
2L
 St
a
n
d
a
r
d
Hi
s
t
o
r
i
c
a
l
Co
n
c
e
n
t
r
a
t
i
o
n
s

C
a
u
s
e
 an
d
 Si
g
n
i
f
i
c
a
n
c
e
MW
‐1D
6.
4
6.3
 ‐

6.
9

p
H
 in
 MW
‐1D
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 his
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
2
‐7
5.
1
4.9
 ‐

5.
5

p
H
 in
 MW
2
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐4
5.
9
5.4
 ‐

6.
7

p
H
 in
 MW
‐4  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
OB
‐5
5.
2
5.0
 ‐

5.
7

p
H
 in
 OB
‐5  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
OB
‐9
5.
0
4.9
 ‐

5.
7

p
H
 in
 OB
‐9  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
An
t
i
m
o
n
y
*

O
B
‐4
26
.
2
µg
/
L

1

7
.
1
 ‐

99

A
n
t
i
m
o
n
y
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐4  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 his
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
Ar
s
e
n
i
c

O
B
‐4
30
.
7
µg
/
L

1
0

2
7
 ‐

92

A
r
s
e
n
i
c
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐4  is
 co
n
s
i
s
t
e
n
t
 wit
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
2
‐7
22
,
7
0
0
10
,
0
0
0
 ‐

22
,
9
0
0

B
o
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
2
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐4
86
4
16
6
 ‐

71
8

B
o
r
o
n
 in
 MW
‐4  is
 th
e
 hig
h
e
s
t
 co
n
c
e
n
t
r
a
t
i
o
n
 re
p
o
r
t
e
d
 at
 th
e
 we
l
l
 ov
e
r
 th
e
 pe
r
i
o
d
 of  monitoring
OB
‐4
14
,
8
0
0
15
,
4
0
0
 ‐

49
,
4
8
2

B
o
r
o
n
 in
 OB
‐4  is
 th
e
 lo
w
e
s
t
 co
n
c
e
n
t
r
a
t
i
o
n
 re
p
o
r
t
e
d
 at
 th
e
 we
l
l
 ov
e
r
 th
e
 pe
r
i
o
d
 of
 monitoring
OB
‐9
26
,
7
0
0
19
,
7
0
0
 ‐

33
,
4
0
0

B
o
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐9  is
 co
n
s
i
s
t
e
n
t
 wit
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
Ca
d
m
i
u
m

O
B
‐9
2.
4
µg
/
L

2

2
.
3
 ‐

5.
7

C
a
d
m
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐9  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
Ch
r
o
m
i
u
m

M
W
‐4
13
.
9
µg
/
L

1
0

5
.
8
 ‐

29

C
h
r
o
m
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐4  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 tu
r
b
i
d
i
t
y
 reported  at  13.1  NTU
Ir
o
n

M
W
‐4
94
4
µg
/
L

3
0
0

2
6
 ‐

8,
5
1
6

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐4  is
 co
n
s
i
s
t
e
n
t
 wit
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 tu
r
b
i
d
i
t
y
 reported  at  13.1  NTU
MW
2
‐7
43
5
71
 ‐

51
5

M
a
n
g
a
n
e
s
e
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
2
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
OB
‐4
81
.
7
45
 ‐

5,
7
7
9

M
a
n
g
a
n
e
s
e
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐4  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
OB
‐9
1,
8
4
0
1,
0
1
0
 ‐

3,
7
7
6

M
a
n
g
a
n
e
s
e
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 OB
‐9  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
Ni
t
r
a
t
e
 as
 N

M
W
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0
0
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4
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N
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MW
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4

S
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1
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S
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l
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r
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r
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d
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OB
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13
1
11
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35
0

S
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l
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r
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5
4
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26
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7
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S
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l
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t
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n
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n
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S
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t
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5
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T
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2
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T
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l
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Th
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B
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3
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µg
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L

0
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2

7
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0
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26

T
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5
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h
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t
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2
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t
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20
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No
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:
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10
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In
s
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4
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3
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6

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2
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5
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5
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7
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2

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2
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5
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6

5
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0
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6.
1

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 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 MW
‐3  is
 th
e
 si
t
e
 ba
c
k
g
r
o
u
n
d
 water  quality  monitoring  well
MW
‐5

5
.
6

5
.
0
 ‐

6.
4

p
H
 in
 MW
‐5  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐6

5
.
4

4
.
9
 ‐

5.
7

p
H
 in
 MW
‐6  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐7

5
.
4

5
.
1
 ‐

6.
2

p
H
 in
 MW
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
SW
‐1A

6
.
2

5
.
5
 ‐

6.
6

p
H
 at
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
SW
‐2

6
.
3

5
.
9
 ‐

6.
7

p
H
 at
 SW
‐2  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐7

2
,
0
0
0

1
2
 ‐

6,
7
4
0

B
o
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐7  is
 co
n
s
i
s
t
e
n
t
 wit
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
SW
‐1A

8
,
5
2
0

8
8
5
 ‐

21
,
6
0
0

B
o
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
SW
‐2

9
5
7

9
5
1
 ‐

19
,
1
6
1

B
o
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐2  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐1

4
1
5

1
2
 ‐

6,
9
6
0

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐1  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
2
‐9

1
,
6
3
0

1
,
1
2
0
 ‐

11
,
9
6
0

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
2
‐9  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐3

3
0
6

2
1
 ‐

8,
5
4
0

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐3  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 MW
‐3  is  the  site  background  water  quality  monitoring  well
MW
‐5

3
5
4

3
0
 ‐

3,
8
5
0

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐5  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐7

3
2
4

2
6
5
 ‐

38
,
0
0
0

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 tu
r
b
i
d
i
t
y
 reported  at  11.9  NTU
SW
‐2

3
3
8

6
3
 ‐

5,
4
9
1

I
r
o
n
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐2  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 tu
r
b
i
d
i
t
y
 reported  at  11.3
MW
2
‐9

1
6
2

3
3
1
 ‐

13
,
0
7
0

M
a
n
g
a
n
e
s
e
 in
 MW
2
‐9  is
 th
e
 lo
w
e
s
t
 co
n
c
e
n
t
r
a
t
i
o
n
 re
p
o
r
t
e
d
 at
 th
e
 we
l
l
 ov
e
r
 th
e
 period  of  monitoring
SW
‐1A

2
6
0

4
5
 ‐

1,
6
6
0

M
a
n
g
a
n
e
s
e
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 well
MW
‐7

2
1
.
4

6
.
7
 ‐

67

S
e
l
e
n
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 turbidity  reported  at  11.9  NTU
SW
‐1A

5
3
.
2

3
9
 ‐

15
9

S
e
l
e
n
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
Su
l
f
a
t
e

S
W
‐1A

5
2
3
,
0
0
0

µ
g
/
L

2
5
0
,
0
0
0

3
1
,
6
0
0
 ‐

1,
0
2
0
,
0
0
0

S
u
l
f
a
t
e
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
To
t
a
l
 Di
s
s
o
l
v
e
d

So
l
i
d
s
SW
‐1A

7
8
1
,
0
0
0

µ
g
/
L

5
0
0
,
0
0
0

1
8
2
,
0
0
0
 ‐

1,
8
1
0
,
0
0
0

T
o
t
a
l
 Di
s
s
o
l
v
e
d
 So
l
i
d
s
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐1A
 is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at  well
MW
‐1

0
.
5
3
1
 J<
1
 ‐

<5

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐1  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 his
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
2
‐9

1
.
8

<
1
 ‐

<5

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
2
‐9  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐3

1
.
0
3

<
1
 ‐

10

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐3  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 MW ‐3  is  the  site  background  water  quality  monitoring  well
MW
‐5

0
.
9
4
7
 J<
1
 ‐

<5

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐5  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 his
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐6

0
.
5
1
5
 J<
1
 ‐

<5

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐6  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 his
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
MW
‐7

0
.
8
1
6
 J<
1
 ‐

25

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 in
 MW
‐7  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 turbidity  reported  at  11.9  NTU
SW
‐2

0
.
5
0
1
 J<
1
 ‐

<1
0

V
a
n
a
d
i
u
m
 co
n
c
e
n
t
r
a
t
i
o
n
 at
 SW
‐2  is
 co
n
s
i
s
t
e
n
t
 wi
t
h
 hi
s
t
o
r
i
c
a
l
 re
a
d
i
n
g
s
 at
 we
l
l
;
 turbidity  reported  at  11.3
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
Bo
r
o
n

µ
g
/
L

7
0
0
Ja
n
u
a
r
y
 11
,
 20
1
7
pH

S
U

6
.
5
 ‐

8.
5
* 40
 CF
R
 Pa
r
t
 25
8
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p
e
n
d
i
x
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o
r
g
a
n
i
c
s
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e
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p
o
r
t
e
d
;
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e
y
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e
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t
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c
l
u
d
e
d
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 th
e
 Pi
n
e
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l
l
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a
d
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n
d
f
i
l
l
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m
p
l
i
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g
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d
 an
a
l
y
s
i
s
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a
n
;
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n
s
t
i
t
u
e
n
t
s
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e
 co
m
p
a
r
e
d
 to
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r
t
h
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In
t
e
r
i
m
 Ma
x
i
m
u
m
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l
o
w
a
b
l
e
 Co
n
c
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a
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M
A
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)
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s
t
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r
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l
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n
c
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t
r
a
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n
s
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s
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t
a
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 Du
k
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r
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t
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/
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c
r
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r
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i
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a
n
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a
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i
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s
NT
U
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d
i
c
a
t
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p
h
e
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m
e
t
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r
b
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i
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n
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i
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b
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t
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p
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m
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e
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e
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e
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t
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t
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s
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b
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s
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t
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p
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m
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m
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a
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Appendix A
Field Sampling Forms

STUDY:
ANALYZER SERIAL #:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 223.4 ▬▬►227 226.5 ▬/▬►227
SS 74.8 ▬/▬►75 74.2 ▬/▬►75
SS 2214.9 ▬/▬►2200 2234.4 ▬/▬►2200
SS
B (7.00)7.03 ▬▬►7.02 7.02 ▬/▬►7.02
B (4.00)4.00 ▬▬►4.00 4.00 ▬/▬►4.00
B (10.00)10.04 ▬/▬►10.06 10.04 ▬/▬►10.04
20.41 20.50
pH Check B (7.00)▬▬►7.13
Time:0.00
438 ▬▬►440 439 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.45 20.34
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.99 ▬▬►8.99 8.96 ▬/▬►8.96
After Cal 8.99 99.95 8.97 100.11
LCS 8.98 99.83 8.97 100.11
LCSD 8.97 -0.11 8.98 0.11
SS 51.0 ▬/▬►51.2 51.1 ▬/▬►51.2
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ▬▬► = Adjusted To
SS = Standard solution LCSD = Lab Control Standard Duplicate ▬/▬►= Not Adjusted To
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 747.90 (mmHg)Ending BP 748.65
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
109.90 110.80
ORP Temp.ORP Temp.
DO
(mg/L)
19.73 19.87
748.35
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
747.60
CALIBRATION PASS
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION BP (mmHg)748.35 CALIBRATION BP (mmHg)747.60
Parameter Calibration Results Calibration Results
3210.6 VALIDATED BY:
Calibration Date / Time 11-Apr-17 420 12-Apr-17 645
HYDROLAB PROCEDURE #:
FIELD SAMPLING CALIBRATION FORM
DATE (s):April 11, 2017 SURFACE UNIT READER:
BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM
OTHER EQUIPMENT:TURBIDIMETER NO.3 - 3260-GW WEATHER CONDITIONS:Clear, breezy, 55 to 75 deg F
LDC
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0964
ANALYZER MODEL#:HL4 400439
STUDY:
ANALYZER SERIAL #:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 230.5 ▬▬►227 217.8 ▬/▬►227
SS 72.9 ▬/▬►75 72.4 ▬/▬►75
SS 2155.3 ▬/▬►2200 2161.5 ▬/▬►2200
SS
B (7.00)7.01 ▬▬►7.02 7.00 ▬/▬►7.02
B (4.00)3.97 ▬▬►4.00 3.99 ▬/▬►4.00
B (10.00)10.02 ▬/▬►10.06 10.00 ▬/▬►10.06
20.35 20.47
pH Check B (7.00)▬▬►7.13
Time:0.00
439 ▬▬►440 440.0 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.45 20.40
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.01 ▬▬►9.01 8.99 ▬/▬►8.97
After Cal 9.02 100.16 9.00 100.36
LCS 9.02 100.16 9.02 100.58
LCSD 9.04 0.22 9.01 -0.11
SS 53.0 ▬/▬►54.3 54.3 ▬/▬►54.3
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM
FIELD SAMPLING CALIBRATION FORM
WEATHER CONDITIONS:
BP = Barometric Pressure
NOTES:
AW = Average Winkler
(mmHg)
B = Buffer ▬▬► = Adjusted To
N/A = Not Applicable
LCS = Lab Control Standard
Ending BP 748.65
▬/▬►= Not Adjusted To
Tested - OK See Notes Tested - OK
pH Subsystem
Cleaned Electrodes
Conductance Subsystem
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Replaced ref Electrode KCL
LCSD = Lab Control Standard DuplicateW = Winkler
Replaced Ref. Electrode Tip
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Cleaned Electrodes
INSTRUMENT MAINTENANCE DATE / TIME
DO
(mg/L)
19.67 19.83
748.35 747.60
CALIBRATION PASS
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK
See Notes
ORP Temp.ORP Temp.
104.50
TURB
(ntu)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
(mmHg)
ORP CALIBRATION ACCEPTED
Field Barometric Pressure
CALIBRATION ACCEPTED
Buffer Temp.
103.70
After Cal % SAT After Cal % SAT
CALIBRATION PASS
Replaced DO electrolyte See Notes
Calibration Results Calibration Results
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
Buffer Temp.
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED
CALIBRATION ACCEPTED
747.90
SS = Standard solution
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, breezy, 55 to 75 deg F
CALIBRATION BP (mmHg)748.35 CALIBRATION BP (mmHg)747.60
Calibration Date / Time 11-Apr-17 400 12-Apr-17 630
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED
Beginning BP
DATE (s):April 11, 2017 SURFACE UNIT READER:PSP
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0722
ANALYZER MODEL#:HL4 400440
HYDROLAB PROCEDURE #:3210.6 VALIDATED BY:
Parameter
N/A
37.20 47.20
25 (psi)12 (sec)(sec)
(gal)
1.88 (gal)
@
QC By:
LDC, PSP
SITE ID 85-03PERMIT #BELEWS CREEK STEAM STATION
FIELD CREWPINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM
SAMPLING NOTES
Access cleared around wellACCESS AROUND WELL
Well cap in good conditon
Well tag in good condition
Access cleared into well
Well found lockedWELL SECURITY
Lock in good conditionWELL LOCK CONDITION
Good Condition
Good Condition
Casing in good condition
Well Impacted By Silting:
OXYGEN
LDC 4/11/2017 1320
TOTAL PURGE
VOLUME
WELL USE
FOSSIL LANDFILL NPDES
PUMP CONTROLLER SETTINGS
PRESSURE
1.88
DETECTED ODOR None
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.67 WATER COLUMN (ft)
STICK UP WELL
RECHARGE DISCHARGE 8
SITE NAME
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
DUKE ENERGY
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)852.69 MIDDLE OF WETTED SCREEN (ft toc)42.20
SCREEN LENGTH (ft)10 NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)47.20 GS ELEV (ft msl)850.55 PUMP INTAKE DEPTH (ft TOC)46.20
28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
ELEV REF
PURGE METHOD
Conventional
WELL TYPE WELL INFORMATION
MONITORING WELL
11.53
WATER ELEVATION (ft msl)817.02 WELL VOLUME
ODOR STRENGTH None
WELL/SAMPLING INFORMATION
(gal)
1.47
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.(recalculates on
current water level)(mV -NHE)(mg/L)
1.50
2.00 38.21 NO 14.60 19 4.82 49.1 497
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.14
1.50 NO 15.29 19 4.85 9.3 535 8.38
NO 14.76 19 4.83 21.0 525 8.31
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.00 N/A
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
NO
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
ACCESS TO WELLS
WELL CAPS
FLUSH MOUNT WELLS
< 2.0Sample preservation verified to pH
(units)
SAMPLING PROCEDURE NO.3175.4
MW-1
WELL VOL:DATE:TIME:WATER LEVEL:
Evacuated:If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge. Sampled:
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
85.53 90.53
60 (psi)9 (sec)(sec)
(gal)
7.75 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)90.53 GS ELEV (ft msl)850.99 PUMP INTAKE DEPTH (ft TOC)89.50
MW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)854.15 MIDDLE OF WETTED SCREEN (ft toc)88.03
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)5 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGSSee note below PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)811.14 WELL VOLUME 7.75
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)43.01 WATER COLUMN (ft)47.52
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
7.75 63.94 NO 14.30 118 6.32 0.4 441
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
4.77
4.50 NO 14.42 120 6.37 0.2 454
4.79 4.34
4.50 NO 14.32 114 6.28 0.2 453
4.70
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
1035 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
16.75 LDC 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
After initial well is removed, recalculate well volume for subsequent readings. WL drawdown appears to stabilize around 64 ft.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
40.00 50.00
30 (psi)5 (sec)(sec)
(gal)
1075 (ml)
495 (ml)
1570 (ml)=0.41 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC)50.00 GS ELEV (ft msl)855.44 PUMP INTAKE DEPTH (ft TOC)49.50
MW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)858.05 MIDDLE OF WETTED SCREEN (ft toc)48.26
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGSSee note below PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None No sample - Insufficient vol / rechargeAPPEARANCE
WATER ELEVATION (ft msl)811.54 WELL VOLUME 0.57
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)46.51 WATER COLUMN (ft)3.49
OXYGEN
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
46.51
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume SAMPLE COLLECTED BY DATE TIME
Sampled:
Total Purge Volume LDC 4/11/2017 N/A
Sample preservation verified to pH
(units)N/A
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Ants inside air connector on well cap.
WELL CASING Ants Inside Casing / Tubing
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
4/24/12 - Replaced pump and tubing in well and set intake to 49.5 ft (six inches from well bottom).
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
39.50 49.50
25 (psi)14 (sec)(sec)
(gal)
1053 (ml)
495 (ml)
1548 (ml)=0.41 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC)49.50 GS ELEV (ft msl)840.57 PUMP INTAKE DEPTH (ft TOC)48.50
MW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)842.81 MIDDLE OF WETTED SCREEN (ft toc)46.11
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)800.09 WELL VOLUME 1.11
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.72 WATER COLUMN (ft)6.78
OXYGEN
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
477 9.45 N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
42.72 540 45.32 14.39 58 5.56 2.0
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME
Sampled:
Total Purge Volume LDC 4/11/2017 1055 N/A
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
30.20 40.20
22 (psi)10 (sec)(sec)
(gal)
4.57 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)40.20 GS ELEV (ft msl)766.10 PUMP INTAKE DEPTH (ft TOC)39.20
MW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)767.58 MIDDLE OF WETTED SCREEN (ft toc)35.20
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)755.39 WELL VOLUME 4.57
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.19 WATER COLUMN (ft)28.01
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
4.75 25.14 NO 14.72 301 5.99 16.2 437
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
2.97
2.50 NO 14.81 292 5.94 13.1 432
3.74 2.46
2.50 NO 14.77 299 5.95 13.2 431
2.58
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
0845 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.75 LDC 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
50.20 60.20
30 (psi)9 (sec)(sec)
(gal)
5.64 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)785.39 PUMP INTAKE DEPTH (ft TOC)59.20
MW-5
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)786.77 MIDDLE OF WETTED SCREEN (ft toc)55.20
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)761.18 WELL VOLUME 5.64
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.59 WATER COLUMN (ft)34.61
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
5.75 44.43 NO 14.88 36 5.68 25.1 477
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
7.19
2.75 NO 14.67 36 5.62 6.3 477
7.17 2.57
2.75 NO 14.74 36 5.67 13.5 474
6.92
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
1425 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
11.25 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Gap between lid and casing
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Gap between lid and protective well casing. Well was found unlocked with
rock ontop of protective casing. WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found unlocked
WELL LOCK CONDITION Lock in good condition
WELL TAG
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
26.84 36.84
25 (psi)7 (sec)(sec)
(gal)
778 (ml)
495 (ml)
1273 (ml)=0.34 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC)36.84 GS ELEV (ft msl)834.40 PUMP INTAKE DEPTH (ft TOC)35.84
MW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)836.91 MIDDLE OF WETTED SCREEN (ft toc)35.28
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 3
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)803.20 WELL VOLUME 0.51
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.71 WATER COLUMN (ft)3.13
OXYGEN
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
469 4.41 N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
33.71 204 34.31 15.63 64 5.38 1.6
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME
Sampled:
Total Purge Volume LDC 4/11/2017 1140 N/A
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
4.26 14.26
20 (psi)10 (sec)(sec)
(gal)
1.06 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)14.26 GS ELEV (ft msl)812.52 PUMP INTAKE DEPTH (ft TOC)13.26
MW-7
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)815.57 MIDDLE OF WETTED SCREEN (ft toc)11.02
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)807.80 WELL VOLUME 1.06
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)7.77 WATER COLUMN (ft)6.49
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.25 9.16 NO 13.24 327 5.36 13.8 508
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
6.45
1.00 NO 13.26 331 5.41 11.9 515
7.62 0.83
1.00 NO 13.20 332 5.38 9.2 514
5.70
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
0745 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.25 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Well pad partly covered with grass.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Grass Growing Over Well Pad Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
20.62 30.62
25 (psi)5 (sec)(sec)
(gal)
2.67 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)30.62 GS ELEV (ft msl)775.45 PUMP INTAKE DEPTH (ft TOC)29.62
MW2-7
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)777.64 MIDDLE OF WETTED SCREEN (ft toc)25.62
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)763.36 WELL VOLUME 2.67
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)14.28 WATER COLUMN (ft)16.34
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
2.75 NO 14.43 1313 5.02 3.7 554
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
0.00
2.75 NO 14.51 1873 5.08 4.7 559
0.00
2.75 NO 14.47 1736 5.07 6.3 550
0.00
2.75 NO 14.49 1995 5.09 3.4 562
0.00
2.75 NO 14.51 1934 5.09 3.7 561
Sampled:
0.00
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
1025 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
13.75 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Well pad covered by dirt and grass
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Debris covering well pad Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
4.61 14.61
10 (psi)5 (sec)(sec)
(gal)
1.43 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)14.61 GS ELEV (ft msl)794.75 PUMP INTAKE DEPTH (ft TOC)13.61
MW2-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)797.38 MIDDLE OF WETTED SCREEN (ft toc)10.22
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)791.55 WELL VOLUME 1.43
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)5.83 WATER COLUMN (ft)8.78
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.50 7.28 NO 13.13 265 5.87 10.4 497
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
1.22 0.77
2.11 1.20
1.25 9.87 YES 13.54 265 5.84 9.4 493
0900 BELOW PUMP N/A
Sampled:4/11/2017 1240 11.13 0.57
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:4/11/2017
1245 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.75 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Grass growing over well pad.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Grass Growing Over Well Pad Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
15.03 30.03
15 (psi)10 (sec)(sec)
(gal)
1.27 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)30.03 GS ELEV (ft msl)774.72 PUMP INTAKE DEPTH (ft TOC)29.10
OB-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)777.60 MIDDLE OF WETTED SCREEN (ft toc)26.14
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)15 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)755.36 WELL VOLUME 1.27
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.24 WATER COLUMN (ft)7.79
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.50 NO 15.82 2618 7.05 3.6 324
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
0.00
1.50 NO 15.84 2610 7.11 3.3 317
0.00
2.00 NO 15.80 2635 7.09 3.8 319
0.00
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
1125 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.00 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Grass growing over well pad, ants were inside air line.
WELL CASING Ants Inside Casing / Tubing
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Grass Growing Over Well Pad Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
21.60 36.60
18 (psi)8 (sec)(sec)
(gal)
1.87 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)36.60 GS ELEV (ft msl)778.13 PUMP INTAKE DEPTH (ft TOC)35.50
OB-5
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)780.93 MIDDLE OF WETTED SCREEN (ft toc)30.88
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)15 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
LEVEL METER SERIAL#28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)755.77 WELL VOLUME 1.87
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.16 WATER COLUMN (ft)11.44
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
2.00 NO 15.51 25 5.20 3.4 487
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
5.35
2.00 NO 15.54 26 5.20 3.3 471
5.07
2.00 NO 15.53 26 5.20 3.0 468
5.80
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
0745 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
6.00 LDC 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
39.17 48.57
25 (psi)10 (sec)(sec)
(gal)
1.74 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC)48.57 GS ELEV (ft msl)797.11 PUMP INTAKE DEPTH (ft TOC)46.00
OB-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2.00 TOC ELEV (ft msl)799.59 MIDDLE OF WETTED SCREEN (ft toc)43.87
SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft)9 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl)761.67 WELL VOLUME 1.74
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)37.92 WATER COLUMN (ft)10.65
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.75 NO 14.97 1748 5.01 3.3 558
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water level)
0.00
1.75 NO 14.93 1743 5.04 2.5 572
0.00
1.75 NO 14.97 1758 5.03 2.7 567
0.00
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:TIME:WATER LEVEL:WELL VOL:
Evacuated:
1230 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 4/11/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Well tag getting hard to read.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag damaged / illegible
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR SURFACE WATER SAMPLING
SW-1ASAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
SAMPLING METHOD:PERISTALTIC PUMP LOCATION ENVIRONMENT:WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE:STREAM WAS WATER PRESENT:YES WAS THERE A NOTICABLE FLOW:YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
INTAKE COND.OXYGEN
TIME
PSP 4/11/2017 0940 N/A
Sample preservation verified to pH
(units)< 2.0
2.7 402 8.77 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
0.10 13.56 995 6.18
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR SURFACE WATER SAMPLING
SW-2SAMPLING DATE(s)11-Apr-2017 WELL/LOCATION NAME
SAMPLING METHOD:GRAB LOCATION ENVIRONMENT:WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE:STREAM WAS WATER PRESENT:YES WAS THERE A NOTICABLE FLOW:YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
INTAKE COND.OXYGEN
TIME
PSP 4/11/2017 1150 N/A
Sample preservation verified to pH
(units)< 2.0
11.3 338 8.33 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 14.78 128 6.28
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
MW-1 MW-1D MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW2-7 MW2-9 OB-4 OB-5 OB-9 SW-1A SW-2
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
NO NO NO NO NO NO NO NO NO NO NO NO NO N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES N/A N/A
YES
YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES SEE NOTE SEE NOTE SEE NOTE SEE NOTE YES YES
YES YES YES YES YES YES YES YES YES YES
SEE NOTE
SEE NOTE SEE NOTE
YES YES YES YES YES YES YES YES YES YES YES YES YES
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES
YES
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Fallen tree blocking access
WELL DEPTH
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE:SAMPLE DATE April 11, 2017
SITE CONTACT
FIELD CREW LDC, PSPPROJECT:
Keeley McCormick, Kimberly Witt, Will Harrison, Melonie Martin
BELEWS CREEK STEAM STATION
PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
FLUSH MOUNT WELLS
WELL PROTECTIVE CASINGS
CONCRETE PADS
WELL SECURITY
Well found locked
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
MW-2 and OB-4 had ants inside air line. MW-5 well was found unlocked with a rock sitting on top and has gap between lid and protective casing (easy access for wasps to build). MW-7, MW2-7, MW2-9 and OB-4 have grass covering the well pad (not able to inspect for cracks in
pad). OB-9 well tag has become difficult to read.
NOTE:
Damaged casing / repair required
Pad in good condition
Minor cracks
Well tag damaged / illegible
Lacks required information - Static WL / date
Undermined / washing out
Fire ants around concrete pad
Lacks required information - Driller Reg #
Lacks required information - Completion date
Lacks required information - Total well depth
Vault in good condition
Casing in good condition
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required info - Casing depth / diam.
Lacks required information - Screen interval
Lacks required information - Non potable tag
Lacks required information - Depth to screen
Water inside vault
Vault bolt holes broken or stripped
Bolts strippedVault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Replaced damaged well cap
Major cracks / broken / repair required
Ants inside protective casing
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
WEATHER Clear, breezy, 55 to 75 deg F4/11/2017
Well impacted by silting
PAGE 1 OF 1
DATE WELL NO
WELL
DEPTH (ft - TOC)
DEPTH TO
WATER (ft - TOC)
WATER
ELEV. (ft)
APPEARANCE ODOR PURGE METHOD

PUMP RATE (ml/min)
WELL
VOL. (gal)
EVAC
VOL. (gal)
EVAC
(YES/NO)
TEMP. (deg. C)
SPECIFIC
CONDUCTANCE (umho/cm)
pH (units)TURBIDITY (NTU's)ORP (mV-NHE)DO (mg/L)
4/11/2017 MW-1 47.20 35.67 817.02 Normal None C N/A 1.88 5.00 NO 15.29 19 4.85 9.3 535 8.38
4/11/2017 MW-1D 90.53 43.01 811.14 Normal None C N/A 7.75 16.75 NO 14.42 120 6.37 0.2 454 4.70
4/11/2017 MW-2 50.00 46.51 811.54 1/0/1900 None EOP N/A 0.57 0.00 N/A 0.00 0 0.00 0.0 0 0.00
4/11/2017 MW-3 49.50 42.72 800.09 Normal None EOP N/A 1.11 0.50 N/A 14.39 58 5.56 2.0 477 9.45
4/11/2017 MW-4 40.20 12.19 755.39 Normal None C N/A 4.57 9.75 NO 14.81 292 5.94 13.1 432 2.58
4/11/2017 MW-5 60.20 25.59 761.18 Normal None C N/A 5.64 11.25 NO 14.67 36 5.62 6.3 477 6.92
4/11/2017 MW-6 36.84 33.71 803.20 Normal None EOP N/A 0.51 0.50 N/A 15.63 64 5.38 1.6 469 4.41
4/11/2017 MW-7 14.26 7.77 807.80 Normal None C N/A 1.06 3.25 NO 13.26 331 5.41 11.9 515 5.70
4/11/2017 MW2-7 30.62 14.28 763.36 Normal None C N/A 2.67 13.75 NO 14.49 1995 5.09 3.4 562 0.00
4/11/2017 MW2-9 14.61 5.83 791.55 Normal None C N/A 1.43 2.75 YES 13.54 265 5.84 9.4 493 1.22
4/11/2017 OB-4 30.03 22.24 755.36 Normal None C N/A 1.27 5.00 NO 15.84 2610 7.11 3.3 317 0.00
4/11/2017 OB-5 36.60 25.16 755.77 Normal None C N/A 1.87 6.00 NO 15.54 26 5.20 3.3 471 5.80
4/11/2017 OB-9 48.57 37.92 761.67 Normal None C N/A 1.74 5.25 NO 14.93 1743 5.04 2.5 572 0.00
4/11/2017 SW-1A N/A Normal None SWS N/A N/A N/A 13.56 995 6.18 2.7 402 8.77
4/11/2017 SW-2 N/A Normal None SWS N/A N/A N/A 14.78 128 6.28 11.3 338 8.33
BELEWS CREEK STEAM STATION
PINE HALL LANDFILL GROUNDWATER MONITORING PROGRAM
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-03
Purge Methods
LF = Low Flow NP = No PurgeEOP = Equip. Only Purge LO = Level Only LF(M) = Low Flow (Mod.)* = Applicable to LF & LF(M) Purging OnlyC = Connventional

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17040007
Project Name:BELEWS - GW PINE HALL LF
Lab Contact: Anne Pridgeon
Date:4/25/2017
Customer Address:3195 Pine Hall Rd
Customer Name(s):C Campbell, T. Hunsucker, E Sullivan, B Moeller
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Sample location MW-2 not collected due to insufficient volume.
Metals via ICP: The method blank associated with samples in this dataset recovered above the reporting limit for calcium and potassium. Since concentrations are neither 10X the method blank content nor non detect, contamination is possible.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 30
Reason: I have reviewed
this document.
Date: 2017.04.25 15:42:52
-04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2017010896 BELEWS 11-Apr-17 1:20 PM LDC MW-1
2017010897 BELEWS 11-Apr-17 10:35 AM LDC MW-1D
2017010899 BELEWS 11-Apr-17 10:55 AM LDC MW-3
2017010900 BELEWS 11-Apr-17 8:45 AM LDC MW-4
2017010901 BELEWS 11-Apr-17 2:25 PM PSP MW-5
2017010902 BELEWS 11-Apr-17 11:40 AM LDC MW-6
2017010903 BELEWS 11-Apr-17 7:45 AM PSP MW-7
2017010904 BELEWS 11-Apr-17 10:25 AM PSP MW2-7
2017010905 BELEWS 11-Apr-17 12:45 PM PSP MW2-9
2017010906 BELEWS 11-Apr-17 11:25 AM PSP OB-4
2017010907 BELEWS 11-Apr-17 7:45 AM LDC OB-5
2017010908 BELEWS 11-Apr-17 12:30 PM PSP OB-9
2017010909 BELEWS 11-Apr-17 9:40 AM PSP SW-1A
2017010910 BELEWS 11-Apr-17 11:50 AM PSP SW-2
2017010911 BELEWS 11-Apr-17 2:35 PM PSP FIELD BLANK
15 Total Samples
Duke Energy Analytical Lab
Page 2 of 30
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/25/2017
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010896
Collection Date:11-Apr-17 1:20 PM
Site:MW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:01 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 9056A 04/13/2017 08:24 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 04/13/2017 08:24 BGN90340.1 1
Nitrate 0.79 mg/L EPA 9056A 04/13/2017 08:24 BGN90340.1 1
Nitrate as N 0.18 mg-N/L EPA 9056A 04/13/2017 08:24 BGN90340.023 1
Sulfate 1.2 mg/L EPA 9056A 04/13/2017 08:24 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 13:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.021 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 18:13 SLS25600.05 1
Calcium (Ca)0.078 mg/L SW 6010D 04/20/2017 18:13B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Iron (Fe)0.415 mg/L SW 6010D 04/20/2017 18:13 SLS25600.01 1
Magnesium (Mg)0.283 mg/L SW 6010D 04/20/2017 18:13B3 SLS25600.005 1
Manganese (Mn)0.032 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Potassium (K)0.428 mg/L SW 6010D 04/20/2017 18:13B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:13 SLS25600.005 1
Sodium (Na)1.93 mg/L SW 6010D 04/20/2017 18:13B3 SLS25600.05 1
Zinc (Zn)0.007 mg/L SW 6010D 04/20/2017 18:13B3 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Cobalt (Co)1.07 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Lead (Pb)1.28 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 19:16 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 19:16 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 38 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 4 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010897
Collection Date:11-Apr-17 10:35 AM
Site:MW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)33 mg/L
(CaCO3)
SM 2320B 04/13/2017 10:57 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.0 mg/L EPA 9056A 04/12/2017 09:49 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 04/12/2017 09:49 BGN90340.1 1
Nitrate 8.5 mg/L EPA 9056A 04/12/2017 09:49 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 9056A 04/12/2017 09:49 BGN90340.023 1
Sulfate 0.96 mg/L EPA 9056A 04/12/2017 09:49 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:00 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 18:33 SLS25600.05 1
Calcium (Ca)6.21 mg/L SW 6010D 04/20/2017 18:33B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/20/2017 18:33 SLS25600.01 1
Magnesium (Mg)5.26 mg/L SW 6010D 04/20/2017 18:33B3 SLS25600.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Potassium (K)1.82 mg/L SW 6010D 04/20/2017 18:33B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
Sodium (Na)9.19 mg/L SW 6010D 04/20/2017 18:33 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 18:33 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/19/2017 12:19 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/19/2017 12:19 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 84 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 5 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010899
Collection Date:11-Apr-17 10:55 AM
Site:MW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)6.9 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:12 CJELLIO51
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 9056A 04/13/2017 09:15 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 04/13/2017 09:15 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/13/2017 09:15 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/13/2017 09:15 BGN90340.023 1
Sulfate 0.28 mg/L EPA 9056A 04/13/2017 09:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:03 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.056 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 18:37 SLS25600.05 1
Calcium (Ca)3.83 mg/L SW 6010D 04/20/2017 18:37B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Iron (Fe)0.306 mg/L SW 6010D 04/20/2017 18:37 SLS25600.01 1
Magnesium (Mg)1.21 mg/L SW 6010D 04/20/2017 18:37B3 SLS25600.005 1
Manganese (Mn)0.006 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Potassium (K)2.44 mg/L SW 6010D 04/20/2017 18:37B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
Sodium (Na)3.10 mg/L SW 6010D 04/20/2017 18:37 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 18:37 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 19:23 CWSPEN30.2 1
Vanadium (V)1.03 ug/L SW 6020B 04/18/2017 19:23 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 41 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 6 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010900
Collection Date:11-Apr-17 8:45 AM
Site:MW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)28 mg/L
(CaCO3)
SM 2320B 04/13/2017 11:02 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 9056A 04/12/2017 12:21 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 12:21 BGN90340.1 1
Nitrate 5.2 mg/L EPA 9056A 04/12/2017 12:21 BGN90340.1 1
Nitrate as N 1.2 mg-N/L EPA 9056A 04/12/2017 12:21 BGN90340.023 1
Sulfate 96 mg/L EPA 9056A 04/12/2017 12:21 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:05 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Boron (B)0.864 mg/L SW 6010D 04/20/2017 18:41 SLS25600.05 1
Calcium (Ca)25.1 mg/L SW 6010D 04/20/2017 18:41B SLS25600.01 1
Chromium (Cr)0.014 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Iron (Fe)0.944 mg/L SW 6010D 04/20/2017 18:41 SLS25600.01 1
Magnesium (Mg)14.7 mg/L SW 6010D 04/20/2017 18:41B3 SLS25600.005 1
Manganese (Mn)0.014 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Potassium (K)1.28 mg/L SW 6010D 04/20/2017 18:41B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
Sodium (Na)8.97 mg/L SW 6010D 04/20/2017 18:41 SLS25600.05 1
Zinc (Zn)0.005 mg/L SW 6010D 04/20/2017 18:41 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Selenium (Se)21.1 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 19:31 CWSPEN30.2 1
Vanadium (V)4.29 ug/L SW 6020B 04/18/2017 19:31 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 7 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010901
Collection Date:11-Apr-17 2:25 PM
Site:MW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:20 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 9056A 04/12/2017 10:40 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 10:40 BGN90340.1 1
Nitrate 2.7 mg/L EPA 9056A 04/12/2017 10:40 BGN90340.1 1
Nitrate as N 0.62 mg-N/L EPA 9056A 04/12/2017 10:40 BGN90340.023 1
Sulfate 0.10 mg/L EPA 9056A 04/12/2017 10:40 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:08 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 18:45 SLS25600.05 1
Calcium (Ca)1.62 mg/L SW 6010D 04/20/2017 18:45B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Copper (Cu)0.110 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Iron (Fe)0.354 mg/L SW 6010D 04/20/2017 18:45 SLS25600.01 1
Magnesium (Mg)0.604 mg/L SW 6010D 04/20/2017 18:45B3 SLS25600.005 1
Manganese (Mn)0.010 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Potassium (K)2.49 mg/L SW 6010D 04/20/2017 18:45B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
Sodium (Na)3.84 mg/L SW 6010D 04/20/2017 18:45 SLS25600.05 1
Zinc (Zn)0.061 mg/L SW 6010D 04/20/2017 18:45 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Lead (Pb)7.87 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:02 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:02 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 8 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010902
Collection Date:11-Apr-17 11:40 AM
Site:MW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)12 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:27 CJELLIO51
INORGANIC IONS BY IC
Chloride 8.1 mg/L EPA 9056A 04/12/2017 10:57 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 10:57 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/12/2017 10:57 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/12/2017 10:57 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/12/2017 10:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:17 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.068 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 18:49 SLS25600.05 1
Calcium (Ca)2.29 mg/L SW 6010D 04/20/2017 18:49B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Iron (Fe)0.050 mg/L SW 6010D 04/20/2017 18:49 SLS25600.01 1
Magnesium (Mg)0.860 mg/L SW 6010D 04/20/2017 18:49B3 SLS25600.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Potassium (K)1.07 mg/L SW 6010D 04/20/2017 18:49B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
Sodium (Na)8.15 mg/L SW 6010D 04/20/2017 18:49 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 18:49 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:10 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:10 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 53 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 9 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010903
Collection Date:11-Apr-17 7:45 AM
Site:MW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:34 CJELLIO51
INORGANIC IONS BY IC
Chloride 8.0 mg/L EPA 9056A 04/12/2017 12:38 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 04/12/2017 12:38 BGN90340.5 5
Nitrate 12 mg/L EPA 9056A 04/12/2017 12:38 BGN90340.5 5
Nitrate as N 2.7 mg-N/L EPA 9056A 04/12/2017 12:38 BGN90340.023 1
Sulfate 140 mg/L EPA 9056A 04/12/2017 12:38 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:25 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Boron (B)2.00 mg/L SW 6010D 04/20/2017 18:53 SLS25600.05 1
Calcium (Ca)28.5 mg/L SW 6010D 04/20/2017 18:53B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Iron (Fe)0.324 mg/L SW 6010D 04/20/2017 18:53 SLS25600.01 1
Magnesium (Mg)13.2 mg/L SW 6010D 04/20/2017 18:53B3 SLS25600.005 1
Manganese (Mn)0.011 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Potassium (K)2.12 mg/L SW 6010D 04/20/2017 18:53B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
Sodium (Na)14.4 mg/L SW 6010D 04/20/2017 18:53 SLS25600.05 1
Zinc (Zn)0.006 mg/L SW 6010D 04/20/2017 18:53 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Selenium (Se)21.4 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:18 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:18 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 10 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010904
Collection Date:11-Apr-17 10:25 AM
Site:MW2-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:42 CJELLIO51
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 9056A 04/12/2017 12:55 BGN9034220
Fluoride < 2 mg/L EPA 9056A 04/12/2017 12:55 BGN9034220
Nitrate 170 mg/L EPA 9056A 04/12/2017 12:55 BGN9034220
Nitrate as N 39 mg-N/L EPA 9056A 04/12/2017 12:55 BGN90340.023 1
Sulfate 1300 mg/L EPA 9056A 04/12/2017 12:55 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.08 ug/L EPA 7470A 04/19/2017 14:27 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Boron (B)22.7 mg/L SW 6010D 04/20/2017 18:57 SLS25600.5 10
Calcium (Ca)254 mg/L SW 6010D 04/20/2017 18:57B SLS25600.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Iron (Fe)0.036 mg/L SW 6010D 04/20/2017 18:57 SLS25600.01 1
Magnesium (Mg)123 mg/L SW 6010D 04/20/2017 18:57B3 SLS25600.05 10
Manganese (Mn)0.435 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Nickel (Ni)0.013 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Potassium (K)3.81 mg/L SW 6010D 04/20/2017 18:57B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
Sodium (Na)73.4 mg/L SW 6010D 04/20/2017 18:57 SLS25600.05 1
Zinc (Zn)0.018 mg/L SW 6010D 04/20/2017 18:57 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Selenium (Se)202 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:25 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:25 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1800 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 11 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010905
Collection Date:11-Apr-17 12:45 PM
Site:MW2-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)66 mg/L
(CaCO3)
SM 2320B 04/13/2017 11:19 CJELLIO201
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 9056A 04/12/2017 13:12 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 13:12 BGN90340.1 1
Nitrate 5.3 mg/L EPA 9056A 04/12/2017 13:12 BGN90340.1 1
Nitrate as N 1.2 mg-N/L EPA 9056A 04/12/2017 13:12 BGN90340.023 1
Sulfate 64 mg/L EPA 9056A 04/12/2017 13:12 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:30 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.059 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Boron (B)0.325 mg/L SW 6010D 04/20/2017 19:01 SLS25600.05 1
Calcium (Ca)26.1 mg/L SW 6010D 04/20/2017 19:01B SLS25600.01 1
Chromium (Cr)0.009 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Iron (Fe)1.63 mg/L SW 6010D 04/20/2017 19:01 SLS25600.01 1
Magnesium (Mg)10.7 mg/L SW 6010D 04/20/2017 19:01B3 SLS25600.005 1
Manganese (Mn)0.162 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Nickel (Ni)0.007 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Potassium (K)4.92 mg/L SW 6010D 04/20/2017 19:01B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
Sodium (Na)19.0 mg/L SW 6010D 04/20/2017 19:01 SLS25600.05 1
Zinc (Zn)0.005 mg/L SW 6010D 04/20/2017 19:01 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:33 CWSPEN30.2 1
Vanadium (V)1.80 ug/L SW 6020B 04/18/2017 20:33 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 12 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010906
Collection Date:11-Apr-17 11:25 AM
Site:OB-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)290 mg/L
(CaCO3)
SM 2320B 04/13/2017 11:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.7 mg/L EPA 9056A 04/12/2017 13:28 BGN9034220
Fluoride < 2 mg/L EPA 9056A 04/12/2017 13:28 BGN9034220
Nitrate 8.6 mg/L EPA 9056A 04/12/2017 13:28 BGN9034220
Nitrate as N 1.9 mg-N/L EPA 9056A 04/12/2017 13:28 BGN90340.023 1
Sulfate 1500 mg/L EPA 9056A 04/12/2017 13:28 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:32 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Boron (B)14.8 mg/L SW 6010D 04/20/2017 19:05 SLS25600.05 1
Calcium (Ca)644 mg/L SW 6010D 04/20/2017 19:05B SLS25600.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Iron (Fe)0.028 mg/L SW 6010D 04/20/2017 19:05 SLS25600.01 1
Magnesium (Mg)42.6 mg/L SW 6010D 04/20/2017 19:05B3 SLS25600.005 1
Manganese (Mn)0.082 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Potassium (K)39.7 mg/L SW 6010D 04/20/2017 19:05B SLS2560110
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
Sodium (Na)8.96 mg/L SW 6010D 04/20/2017 19:05 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 19:05 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)26.2 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Arsenic (As)30.7 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Cobalt (Co)1.07 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Selenium (Se)131 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
Thallium (Tl) Low Level 8.39 ug/L SW 6020B 04/18/2017 20:41 CWSPEN30.2 1
Vanadium (V)203 ug/L SW 6020B 04/18/2017 20:41 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 2600 mg/L SM2540C 04/12/2017 15:00 MGIGANT5001
Duke Energy Analytical Lab
Page 13 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010907
Collection Date:11-Apr-17 7:45 AM
Site:OB-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 9056A 04/12/2017 14:35 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 14:35 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/12/2017 14:35 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/12/2017 14:35 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/12/2017 14:35 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:35 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.101 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 19:18 SLS25600.05 1
Calcium (Ca)0.882 mg/L SW 6010D 04/20/2017 19:18B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Iron (Fe)0.199 mg/L SW 6010D 04/20/2017 19:18 SLS25600.01 1
Magnesium (Mg)0.474 mg/L SW 6010D 04/20/2017 19:18B3 SLS25600.005 1
Manganese (Mn)0.021 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Potassium (K)2.58 mg/L SW 6010D 04/20/2017 19:18B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
Sodium (Na)1.50 mg/L SW 6010D 04/20/2017 19:18 SLS25600.05 1
Zinc (Zn)0.006 mg/L SW 6010D 04/20/2017 19:18 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:49 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:49 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 14 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010908
Collection Date:11-Apr-17 12:30 PM
Site:OB-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.3 mg/L
(CaCO3)
SM 2320B 04/19/2017 13:56 CJELLIO51
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 9056A 04/12/2017 16:50 BGN9034220
Fluoride < 2 mg/L EPA 9056A 04/12/2017 16:50 BGN9034220
Nitrate 22 mg/L EPA 9056A 04/12/2017 16:50 BGN9034220
Nitrate as N 5.0 mg-N/L EPA 9056A 04/12/2017 16:50 BGN90340.023 1
Sulfate 1200 mg/L EPA 9056A 04/12/2017 16:50 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.09 ug/L EPA 7470A 04/19/2017 14:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.013 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Boron (B)26.7 mg/L SW 6010D 04/20/2017 19:22 SLS25600.5 10
Calcium (Ca)201 mg/L SW 6010D 04/20/2017 19:22B SLS25600.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/20/2017 19:22 SLS25600.01 1
Magnesium (Mg)88.1 mg/L SW 6010D 04/20/2017 19:22B3 SLS25600.005 1
Manganese (Mn)1.84 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Nickel (Ni)0.010 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Potassium (K)7.52 mg/L SW 6010D 04/20/2017 19:22B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
Sodium (Na)98.3 mg/L SW 6010D 04/20/2017 19:22 SLS25600.5 10
Zinc (Zn)0.042 mg/L SW 6010D 04/20/2017 19:22 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Cadmium (Cd)2.40 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Selenium (Se)300 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 20:56 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 20:56 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 15 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010909
Collection Date:11-Apr-17 9:40 AM
Site:SW-1A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)34 mg/L
(CaCO3)
SM 2320B 04/13/2017 11:34 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.6 mg/L EPA 9056A 04/12/2017 17:07 BGN9034110
Fluoride < 1 mg/L EPA 9056A 04/12/2017 17:07 BGN9034110
Nitrate 44 mg/L EPA 9056A 04/12/2017 17:07 BGN9034110
Nitrate as N 9.8 mg-N/L EPA 9056A 04/12/2017 17:07 BGN90340.023 1
Sulfate 520 mg/L EPA 9056A 04/12/2017 17:07 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Boron (B)8.52 mg/L SW 6010D 04/20/2017 19:26 SLS25600.05 1
Calcium (Ca)123 mg/L SW 6010D 04/20/2017 19:26B SLS25600.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Iron (Fe)0.056 mg/L SW 6010D 04/20/2017 19:26 SLS25600.01 1
Magnesium (Mg)50.1 mg/L SW 6010D 04/20/2017 19:26B3 SLS25600.005 1
Manganese (Mn)0.260 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Potassium (K)4.03 mg/L SW 6010D 04/20/2017 19:26B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
Sodium (Na)33.4 mg/L SW 6010D 04/20/2017 19:26 SLS25600.05 1
Zinc (Zn)0.006 mg/L SW 6010D 04/20/2017 19:26 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Cobalt (Co)1.06 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Selenium (Se)53.2 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 21:04 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 21:04 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 780 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 16 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010910
Collection Date:11-Apr-17 11:50 AM
Site:SW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 04/19/2017 14:03 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.2 mg/L EPA 9056A 04/12/2017 17:23 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 17:23 BGN90340.1 1
Nitrate 1.8 mg/L EPA 9056A 04/12/2017 17:23 BGN90340.1 1
Nitrate as N 0.41 mg-N/L EPA 9056A 04/12/2017 17:23 BGN90340.023 1
Sulfate 38 mg/L EPA 9056A 04/12/2017 17:23 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:42 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Boron (B)0.957 mg/L SW 6010D 04/20/2017 19:30 SLS25600.05 1
Calcium (Ca)6.45 mg/L SW 6010D 04/20/2017 19:30B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Iron (Fe)0.338 mg/L SW 6010D 04/20/2017 19:30 SLS25600.01 1
Magnesium (Mg)4.53 mg/L SW 6010D 04/20/2017 19:30B3 SLS25600.005 1
Manganese (Mn)0.026 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Potassium (K)1.82 mg/L SW 6010D 04/20/2017 19:30B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
Sodium (Na)10.6 mg/L SW 6010D 04/20/2017 19:30 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 19:30 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Selenium (Se)6.04 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 21:12 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 21:12 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 04/12/2017 15:00 MGIGANT251
Duke Energy Analytical Lab
Page 17 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
2017010911
Collection Date:11-Apr-17 2:35 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 04/13/2017 11:40 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 04/12/2017 15:42 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 04/12/2017 15:42 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 04/12/2017 15:42 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 04/12/2017 15:42 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 04/12/2017 15:42 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 14:45 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/20/2017 19:34 SLS25600.05 1
Calcium (Ca)< 0.01 mg/L SW 6010D 04/20/2017 19:34B SLS25600.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/20/2017 19:34 SLS25600.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 04/20/2017 19:34B3 SLS25600.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Potassium (K)< 0.1 mg/L SW 6010D 04/20/2017 19:34B SLS25600.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 04/20/2017 19:34 SLS25600.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/20/2017 19:34 SLS25600.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/18/2017 21:43 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 04/18/2017 21:43 CWSPEN311
Duke Energy Analytical Lab
Page 18 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Qualifiers:
B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to contamination.
B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than ½ the
reporting limit, but less than the reporting limit.
Duke Energy Analytical Lab
Page 19 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040307 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17040007 -- 2017010911
Alkalinity (mg/L CaCO3) 0.324 8mg/L (CaCO3)-10.324
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 41.3 50.1 82.5mg/L (CaCO3)-12080141.3
Alkalinity (mg/L CaCO3) 41.3 50.1 82.5mg/L
(CaCO3)
-141.3
Duke Energy Analytical Lab
Page 20 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040464 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17040007 -- 2017010896
Alkalinity (mg/L CaCO3) 0.371 2.89mg/L (CaCO3)-10.371
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 21.3 25.05 85.1mg/L (CaCO3)-12080121.3
Duke Energy Analytical Lab
Page 21 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040241 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0239 mg/L -10.0239 0.1 < 1/2 RDL
Fluoride 0.0115 mg/L -10.0115 0.1 < 1/2 RDL
Nitrate 0.0045 mg/L -10.0045 0.1 < 1/2 RDL
Sulfate -0.0488 mg/L -1-0.0488 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.62 25 104mg/L -12080528.1
Fluoride 5.28 25 105mg/L -12080526.4
Nitrate 5.35 25 102mg/L -12080526.8
Sulfate 5.3 25 104mg/L -12080526.5
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.62 25 104 0.12mg/L -12080528.1
Fluoride 5.24 25 104 0.772mg/L -12080526.2
Nitrate 5.36 25 102 0.0781mg/L -12080526.8
Sulfate 5.3 25 104 0.0325mg/L -12080526.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.1 5 102mg/L -1208015.1
Fluoride 5.15 5 103mg/L -1208015.15
Nitrate 5.12 5 102mg/L -1208015.12
Sulfate 5.08 5 102mg/L -1208015.08
Duke Energy Analytical Lab
Page 22 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040463 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0 ug/L -10 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.013 ug/L -10.013 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.5ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040200 -- 2017011732
Mercury (Hg) 1.07 1 106ug/L -1257511.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040200 -- 2017011732
Mercury (Hg) 1.07 1 107 0.376ug/L -1257511.07
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030324 -- 2017008323
Mercury (Hg) 0.126 1 13.7ug/L -1257510.126
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030324 -- 2017008323
Mercury (Hg) 0.121 1 13.2 3.72ug/L -1257510.121
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17030324 -- 2017008326
Mercury (Hg) 0.175 1 17.2ug/L -1257510.175
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17030324 -- 2017008326
Mercury (Hg) 0.174 1 17.1 0.583ug/L -1257510.174
Duke Energy Analytical Lab
Page 23 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040463 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010902
Mercury (Hg) 0.987 1 97.9ug/L -1257510.987
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010902
Mercury (Hg) 0.986 1 97.8 0.102ug/L -1257510.986
Duke Energy Analytical Lab
Page 24 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040397 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000897 mg/L -1-0.000897 0.005 < 1/2 RDL
Beryllium (Be) -0.000721 mg/L -1-0.000721 0.005 < 1/2 RDL
Boron (B) 0.00851 mg/L -10.00851 0.05 < 1/2 RDL
Calcium (Ca) 0.0157 mg/L -10.0157 0.01 > RDL
Chromium (Cr) -0.000592 mg/L -1-0.000592 0.005 < 1/2 RDL
Copper (Cu) -0.000353 mg/L -1-0.000353 0.005 < 1/2 RDL
Iron (Fe) -0.000364 mg/L -1-0.000364 0.01 < 1/2 RDL
Magnesium (Mg) 0.00246 mg/L -10.00246 0.005 < 1/2 RDL
Manganese (Mn) -0.00042 mg/L -1-0.00042 0.005 < 1/2 RDL
Nickel (Ni) -0.000767 mg/L -1-0.000767 0.005 < 1/2 RDL
Potassium (K) 0.179 mg/L -10.179 0.1 > RDL
Silver (Ag) 0.000527 mg/L -10.000527 0.005 < 1/2 RDL
Sodium (Na) 0.0234 mg/L -10.0234 0.05 < 1/2 RDL
Zinc (Zn) 0.00134 mg/L -10.00134 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.15 5 103mg/L -1208015.15
Beryllium (Be) 5.09 5 102mg/L -1208015.09
Boron (B) 5.17 5 103mg/L -1208015.17
Calcium (Ca) 5.15 5 103mg/L -1208015.15
Chromium (Cr) 5.01 5 100mg/L -1208015.01
Copper (Cu) 5.06 5 101mg/L -1208015.06
Iron (Fe) 5.14 5 103mg/L -1208015.14
Magnesium (Mg) 5.09 5 102mg/L -1208015.09
Manganese (Mn) 5.04 5 101mg/L -1208015.04
Nickel (Ni) 5.01 5 100mg/L -1208015.01
Potassium (K) 5.08 5 102mg/L -1208015.08
Silver (Ag) 0.495 0.5 99mg/L -1208010.495
Sodium (Na) 5.18 5 104mg/L -1208015.18
Zinc (Zn) 4.95 5 99mg/L -1208014.95
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010896
Barium (Ba) 4.83 5 96.1mg/L -1257514.83
Beryllium (Be) 4.76 5 95.1mg/L -1257514.76
Boron (B) 4.82 5 96.3mg/L -1257514.82
Calcium (Ca) 4.9 5 96.5mg/L -1257514.9
Chromium (Cr) 4.7 5 94mg/L -1257514.7
Copper (Cu) 4.73 5 94.6mg/L -1257514.73
Duke Energy Analytical Lab
Page 25 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040397 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010896
Iron (Fe) 5.24 5 96.5mg/L -1257515.24
Magnesium (Mg) 5.06 5 95.6mg/L -1257515.06
Manganese (Mn) 4.74 5 94.1mg/L -1257514.74
Nickel (Ni) 4.67 5 93.3mg/L -1257514.67
Potassium (K) 5.09 5 93.2mg/L -1257515.09
Silver (Ag) 0.462 0.5 92.1mg/L -1257510.462
Sodium (Na) 6.7 5 95.5mg/L -1257516.7
Zinc (Zn) 4.63 5 92.4mg/L -1257514.63
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010896
Barium (Ba) 4.99 5 99.3 3.3mg/L -1257514.99
Beryllium (Be) 4.95 5 99 3.96mg/L -1257514.95
Boron (B) 5.01 5 99.9 3.75mg/L -1257515.01
Calcium (Ca) 5.1 5 101 4.08mg/L -1257515.1
Chromium (Cr) 4.9 5 98 4.17mg/L -1257514.9
Copper (Cu) 4.93 5 98.6 4.16mg/L -1257514.93
Iron (Fe) 5.41 5 99.8 3.36mg/L -1257515.41
Magnesium (Mg) 5.26 5 99.5 4.02mg/L -1257515.26
Manganese (Mn) 4.91 5 97.5 3.59mg/L -1257514.91
Nickel (Ni) 4.87 5 97.5 4.32mg/L -1257514.87
Potassium (K) 5.27 5 96.9 3.85mg/L -1257515.27
Silver (Ag) 0.481 0.5 96 4.18mg/L -1257510.481
Sodium (Na) 6.92 5 99.8 4.4mg/L -1257516.92
Zinc (Zn) 4.83 5 96.4 4.19mg/L -1257514.83
Duke Energy Analytical Lab
Page 26 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040406 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.056 ug/L -1-0.056 1 < 1/2 RDL
Arsenic (As) 0.059 ug/L -10.059 1 < 1/2 RDL
Cadmium (Cd) 0 ug/L -10 1 < 1/2 RDL
Cobalt (Co) 0.001 ug/L -10.001 1 < 1/2 RDL
Lead (Pb) 0.004 ug/L -10.004 1 < 1/2 RDL
Selenium (Se) 0.063 ug/L -10.063 1 < 1/2 RDL
Thallium (Tl) Low Level -0.001 ug/L -1-0.001 0.2 < 1/2 RDL
Vanadium (V) 0.285 ug/L -10.285 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.7 50 99.5ug/L -12080149.7
Arsenic (As) 48.6 50 97.2ug/L -12080148.6
Cadmium (Cd) 49.8 50 99.6ug/L -12080149.8
Cobalt (Co) 47.9 50 95.8ug/L -12080147.9
Lead (Pb) 49.3 50 98.6ug/L -12080149.3
Selenium (Se) 50.4 50 101ug/L -12080150.4
Thallium (Tl) Low Level 50.5 50 101ug/L -12080150.5
Vanadium (V) 47.6 50 95.3ug/L -12080147.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010897
Antimony (Sb) 48.9 50 97.9ug/L -12575148.9
Arsenic (As) 47.4 50 94.7ug/L -12575147.4
Cadmium (Cd) 48.5 50 97ug/L -12575148.5
Cobalt (Co) 46.2 50 92.3ug/L -12575146.2
Lead (Pb) 48 50 96ug/L -12575148
Selenium (Se) 48.3 50 96.6ug/L -12575148.3
Thallium (Tl) Low Level 49.2 50 98.5ug/L -12575149.2
Vanadium (V) 46.9 50 92.9ug/L -12575146.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010897
Antimony (Sb) 50.2 50 100 2.55ug/L -12575150.2
Arsenic (As) 48.7 50 97.3 2.73ug/L -12575148.7
Cadmium (Cd) 50 50 100 3.15ug/L -12575150
Cobalt (Co) 47.4 50 94.8 2.7ug/L -12575147.4
Lead (Pb) 49.4 50 98.7 2.77ug/L -12575149.4
Selenium (Se) 50 50 100 3.52ug/L -12575150
Thallium (Tl) Low Level 50.3 50 101 2.11ug/L -12575150.3
Duke Energy Analytical Lab
Page 27 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040406 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17040007 -- 2017010897
Vanadium (V) 48.8 50 96.7 4.07ug/L -12575148.8
Duke Energy Analytical Lab
Page 28 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17040007
Q17040336 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030155 -- 2017007427
TDS 247 1.21mg/L -1247
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17040007 -- 2017010896
TDS 37 2.67mg/L -137
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17040007 -- 2017010897
TDS 85 1.18mg/L -185
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J17040007 -- 2017010899
TDS 45 9.3mg/L -145
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 97 100 97mg/L -11090197
Duke Energy Analytical Lab
Page 29 of 30
Duke Energy Analytical Lab Page 30 of 30