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Home My WebLink About6512_DukeSutton_BaselineSamplingEvents1and2_DIN28098_20170629DENR USE ONLY: Paper Report Electronic Data - Email CD (data loaded: Yes / No ) Doc/Event #: NC DENR Division of Waste Management - Solid Waste Environmental Monitoring Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off-site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Phone: E-mail: Facility name: Facility Address: Facility Permit # NC Landfill Rule: (.0500 or .1600) Actual sampling dates (e.g., October 20-24, 2006) Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Assessment Monitoring Corrective Action Type of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data Other(specify) Surface water monitoring data Notification attached? No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Facility Representative Name (Print) Title (Area Code) Telephone Number Signature Affix NC Licensed/ Professional Geologist Seal Revised 6/2009 Date Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Bill Wylie Project Scientist Perry Waldrep, NC LG 2453 Senior Project Manager GROUNDWATER MONITORING REPORT BASELINE SAMPLING EVENTS #1 & #2 L.V. SUTTON ENERGY COMPLEX SUTTON ONSITE LANDFILL PERMIT NO. 6512-INDUS-2016 801 SUTTON STEAM PLANT ROAD WILMINGTON, NORTH CAROLINA JUNE 2017 PREPARED FOR DUKE ENERGY PROGRESS, LLC L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page i P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx TABLE OF CONTENTS SECTION PAGE 1.0 BACKGROUND............................................................................................................... 1 2.0 METHODS ........................................................................................................................ 3 2.1 Sampling and Analysis Methods ............................................................................... 3 2.2 Statement of Work ....................................................................................................... 3 3.0 RESULTS ........................................................................................................................... 5 3.1 Site Groundwater Flow ............................................................................................... 5 3.2 Analytical Results ........................................................................................................ 5 4.0 REFERENCES ................................................................................................................... 6 LIST OF FIGURES Figure 1 Site Location Map Figure 2 Sutton Onsite Landfill Monitoring Well Locations Figure 3 Sutton Onsite Landfill Water Level Map LIST OF TABLES Table 1 Well Construction Information Table 2 Groundwater Seepage Velocity Table 3 Field Data Parameters Table 4 Groundwater Field and Analytical Results Table 5 Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards LIST OF APPENDICES Appendix A Field Sampling Forms Appendix B Laboratory Report and Chain-of-Custody Forms L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 1 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx 1.0 BACKGROUND Duke Energy Progress, LLC. (DEP) owns and operates the L.V. Sutton Energy Complex (Site), located on approximately 3,300 acres, addressed at 801 Sutton Steam Plant Road in Wilmington, New Hanover County, North Carolina. A Site Location Map is included as Figure 1. The Sutton Plant began operations in 1954 with three coal-fired boilers that primarily used bituminous coal as fuel to produce steam to generate electricity. The Site ceased burning coal in November 2013 and switched to natural gas for electricity generation, thus the facility no longer generates coal ash. Coal combustion residuals (CCRs) were originally stored on-site in the 'former ash disposal area (FADA)', also known as the ‘lay of land area’, then in the 1971 ash basin (old ash basin), and finally the 1984 ash basin (new ash basin). In 2015, ash removal activities for offsite disposal began in the 1971 ash basin and are currently ongoing. Site development and construction activities for Phase 1 of the new on-site double-lined coal combustion residuals (CCR) landfill (Industrial Waste Landfill Permit #6512- INDUS-2016) began in September 2016 and are ongoing (Figure 2). The new CCR landfill will be constructed in three Phases. Duke Energy intends to remove CCR from the 1971 and 1984 Basins and place it within Phase I of the new double-lined CCR landfill when it becomes operational, currently projected for July 2017. The onsite CCR landfill is permitted to accept the following on-site generated waste types: CCR (including fly and bottom ash, pyrites and coal mill rejects, and boiler slag); Wastewater treatment sludge (WWTS); Petroleum contaminated site soils; and Plant decommissioning-related materials. The liner for the new CCR Landfill consists of a double-lined system (from top down) with a two foot thick protective layer, primary geocomposite drainage layer, 60-mil thick primary high density polyethylene (HDPE) textured geomembrane, secondary geocomposite drainage layer, 60-mil thick secondary HDPE textured geomembrane and a geosynthetic clay liner (GCL). L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 2 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx A Water Quality Monitoring Plan (WQMP) for the new landfill was approved in January 2017. Eight groundwater monitoring wells (BMW-01, BMW-02, BMW-03, BMW-04, DMW-01, DMW-02 DMW-03 and DMW-04) were installed along the east and west sides of the new landfill in February 2017. The WQMP included baseline sampling consisting of four sampling events. The sampling includes measurement of groundwater field parameters and water levels as well as collection of groundwater samples. The results of the first two baseline sampling events, performed on March 7, 8, 9 2017 and April 4, 5, 6, 2017, are reported herein. The sampling locations are depicted on Figure 2. A summary of monitoring well construction information is presented in Table 1. L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 3 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx 2.0 METHODS 2.1 Sampling and Analysis Methods The collection of samples and documentation of sampling was performed by SynTerra Corporation (SynTerra) personnel (SynTerra Field Certification #5591) according to the North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are included in Appendix A. The parameters and constituents reported were analyzed by Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248). The laboratory report and chain-of-custody forms are included in Appendix B. The groundwater samples were analyzed for the following constituents as per email from DEQ to Duke Energy dated February 27, 2017: Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc using Solid Waste Method 6010D Arsenic, cadmium, lead, thallium, and selenium using Solid Waste Method 6020B Chloride, fluoride, nitrate (as nitrogen), and sulfate using EPA Method 9056A Mercury using EPA Method 7440A Total dissolved solids using Standard Method (SM) 2540C Biological oxygen demand (BOD), chemical oxygen demand (COD) and total organic carbon (TOC) were inadvertently omitted from the first two baseline sampling events. Four baseline sampling results will be provided for BOD, COD and TOC in the second Baseline Sampling Event Report. 2.2 Statement of Work SynTerra completed the following tasks: Conducted the first two baseline groundwater sampling events at the Sutton landfill monitoring wells, shipped samples to Duke Energy Laboratory, and submitted all field data to Duke Energy. Reviewed the laboratory analytical results for the samples listed above. The Electronic Data Deliverable (EDD) provided by Duke Energy was adapted to conform to the format requirements of the NCDEQ EDD template. Copies of the original EDDs are retained in SynTerra's files. L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 4 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx Developed generalized groundwater surface contour map using map data and groundwater elevation data supplied by Duke Energy. Calculated groundwater flow velocities based on groundwater elevations on wells perpendicular to groundwater flow. Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke Energy. L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 5 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx 3.0 RESULTS 3.1 Site Groundwater Flow Generalized groundwater surface contours and groundwater flow direction arrows for the site are shown on Figure 3. These contours were developed using the groundwater elevations measured on the date of depth to water collection, April 3, 2017. The water levels in three of the wells, BMW-1 and BMW-3, located on the northeast side of the landfill, and DMW-1, located on the northwest side of the landfill, were below the top of the dedicated pumps and therefore could not be measured. Calculated flow velocities are presented in Table 2. Groundwater elevation data collected in April 2017 indicate groundwater at the landfill flows east to southeast. 3.2 Analytical Results A summary of the field data is presented in Table 3. The field and analytical results of groundwater samples collected from the monitoring wells are presented in Table 4. The analytical results for these samples are compared to the groundwater standards established in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations that equal or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the field and analytical results that attain or exceed the 2L Standards including a preliminary analysis of the cause and significance of the exceedances are presented in Table 5. The laboratory analytical reports are included as Appendix B. L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra Page 6 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx 4.0 REFERENCES Geosyntec - Water Quality Monitoring Plan, L.V. Sutton Energy Complex Onsite Coal Combustion Residuals Landfill, November, 2016. L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx FIGURES 148 RIVER STREET, SUITE 220GREENVILLE, SOUTH CAROLINAPHONE 864-421-9999www.synterracorp.com 2000GRAPHIC SCALE1000 IN FEET 10000 RALEIGH WILMINGTON GREENVILLE GREENSBORO CHARLOTTE FAYETTEVILLE SOURCE:USGS TOPOGRAPHIC MAP OBTAINED FROM THE USGS MAP STORE AThttp://store.usgs.gov/b2c_usgs/b2c/start/%%%28xcm=r3standardpitrex_prd%%%29/.do 06/19/2017 3:25 PM P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting And Recordkeeping\SWLF\Figures\DE SUTTON CCR FIG 1 (SITE LOCATION MAP).dwg J. CHASTAIN FIG 1 (SITE LOC MAP) 10/13/2016 LAYOUT:MAP DATE: 2013 CONTOUR INTERVAL:10ft DATE: PROJECT MANAGER:CRAIG EADY DRAWN BY: NEW HANOVER COUNTY CCR SURFACE IMPOUNDMENT PROPERTY BOUNDARY FIGURE 1 SITE LOCATION MAP L.V. SUTTON ENERGY COMPLEX 801 SUTTON STEAM PLANT RD WILMINGTON, NORTH CAROLINA LELAND AND CASTLE HAYNE NC QUADRANGLES L.V. SUTTON ENERGY COMPLEX APPROXIMATE ROUTE OF THE NEW WILLMINGTON BYPASS (I-140) FORMER ASH DISPOSAL AREA NEW CCR LANDFILL &< &< &< &< &< &< &< &< DMW-2 DMW-1 BMW-2 BMW-4 DMW-4 DMW-3 BMW-3 BMW-1 FORMER ASHDISPOSAL AREA 1971 ASHBASIN 1984 ASHBASIN(LINED) 1984 ASHBASIN(LINED) 1983EXTENSION FIGURE 2SUTTON ONSITE LANDFILLMONITORING WELL LOCATIONSL.V. SUTTON ENERGY COMPLEXWILMINGTON, NORTH CAROLINADRAWN BY: A. FEIGLPROJECT MANAGER: P. WALDREPCHECKED BY: B. WYLIE DATE: 06/23/2017 148 RIVER STREET, SUITE 220GREENVILLE, SOUTH CAROLINA 29601PHONE 864-421-9999www.synterracorp.com P:\Duke Energy Progress.1026\00 GIS BASE DATA\Sutton\Map_Docs\CCR_Draft\SUTTON_PROPCCRWELLS_20170619.mxd 250 0 250 500125 IN FEET GRAPHIC SCALE LEGEND &<NEW LANDFILL MONITORING WELLS RAILROAD BOAT ROAD PHASE 1 AREA INTERCELL ALIGNMENT LANDFILL FINAL COVER (10' INTERVAL) ASH LOADING AREA PHASE 1 SURFACE WATER PONDS ASH BASIN COMPLIANCE BOUNDARY HALF-MILE OFFSET FROM COMPLIANCEBOUNDARY DUKE ENERGY PROGRESS SUTTON PLANTSITE BOUNDARY NOTES:2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDANRCS GEOSPATIAL DATA GATEWAY(https://gdg.sc.egov.usda.gov/GDGOrder.aspx). DRAWING HAS BEEN SET WITH A PROJECTION OF NORTHCAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 WATERTREATMENTPLANT CCP TRAILER LOT DRAI N A G E C A N A L & & & & & & & & &< &< &< &< &< &< &< &< DMW-29.28 DMW-1BTP BMW-28.81 BMW-48.87 DMW-48.54 DMW-3BTP BMW-3BTP BMW-1BTP 8 . 6 8.9 9.2 9.0 8. 7 9.1 8. 8 8.6 8.9 9.2 9.0 8.7 9.1 8.8 FORMER ASHDISPOSAL AREA 1971 ASHBASIN 1984 ASHBASIN(LINED) 1984 ASHBASIN(LINED) 1983EXTENSION FIGURE 3SUTTON ONSITE LANDFILLWATER LEVEL MAPUPPER SURFICIAL - APRIL 3, 2017L.V. SUTTON ENERGY COMPLEXWILMINGTON, NORTH CAROLINADRAWN BY: A. FEIGLPROJECT MANAGER: P. WALDREPCHECKED BY: B. WYLIE DATE: 06/23/2017 148 RIVER STREET, SUITE 220GREENVILLE, SOUTH CAROLINA 29601PHONE 864-421-9999www.synterracorp.com P:\Duke Energy Progress.1026\00 GIS BASE DATA\Sutton\Map_Docs\Water Level\UPPER SURFICIAL_20170403.mxd 250 0 250 500125 GRAPHIC SCALE IN FEET &<UPPER SURFICIAL WELL LOCATION WITHWATER LEVEL ELEVATION &WATER LEVEL BELOW TOP OF PUMP WATER LEVEL LINE GROUNDWATER FLOW DIRECTION RAILROAD BOAT ROAD PHASE 1 AREA INTERCELL ALIGNMENT LANDFILL FINAL COVER (10' INTERVAL) ASH LOADING AREA PHASE 1 SURFACE WATER PONDS ASH BASIN COMPLIANCE BOUNDARY HALF-MILE OFFSET FROM COMPLIANCEBOUNDARY DUKE ENERGY PROGRESS SUTTON PLANTSITE BOUNDARY NOTES:2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDANRCS GEOSPATIAL DATA GATEWAY(https://gdg.sc.egov.usda.gov/GDGOrder.aspx). DRAWING HAS BEEN SET WITH A PROJECTION OF NORTHCAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 WATERTREATMENTPLANT CCP TRAILER LOT DRAI N A G E C A N A L LEGEND BTP L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx TABLES TA B L E 1 WE L L C O N S T R U C T I O N I N F O R M A T I O N SU T T O N O N S I T E L A N D F I L L - P E R M I T N O . 6 5 1 2 L. V . S U T T O N E N E R G Y C O M P L E X DU K E E N E R G Y P R O G R E S S , L L C , W I L M I N G T O N , N C La t i t u d e L o n g i t u d e BM W - 0 1 0 3 / 0 3 / 2 0 1 7 3 4 . 3 0 1 5 4 6 1 1 - 7 7 . 9 8 5 5 7 4 8 3 3 0 . 6 4 2 8 . 1 3 2 . 5 1 2 2 . 8 6 1 2 . 8 6 1 2 . 8 6 - 2 2 . 8 6 S u f i c i a l U p p e r 2 P V C BM W - 0 2 0 2 / 2 3 / 2 0 1 7 3 4 . 2 9 7 9 0 7 1 2 - 7 7 . 9 8 7 3 3 1 8 9 1 6 . 5 5 1 4 . 0 9 2 . 4 6 1 8 . 8 8 8 . 8 8 8 . 8 8 - 1 8 . 8 8 S u f i c i a l U p p e r 2 P V C BM W - 0 3 0 2 / 2 8 / 2 0 1 7 3 4 . 2 9 9 0 0 4 7 4 - 7 7 . 9 8 4 3 4 3 8 2 2 4 . 8 6 2 2 . 4 9 2 . 3 7 2 3 . 1 0 1 3 . 1 0 1 3 . 1 0 - 2 3 . 1 0 S u f i c i a l U p p e r 2 P V C BM W - 0 4 0 2 / 1 0 / 2 0 1 7 3 4 . 2 9 5 4 9 4 6 7 - 7 7 . 9 8 6 2 7 5 0 1 1 7 . 0 0 1 4 . 7 5 2 . 2 5 1 7 . 8 7 7 . 8 7 7 . 8 7 - 1 7 . 8 7 S u f i c i a l U p p e r 2 P V C DM W - 0 1 0 2 / 2 4 / 2 0 1 7 3 4 . 3 0 1 8 7 6 0 5 - 7 7 . 9 8 8 8 4 2 1 3 2 7 . 0 8 2 4 . 7 6 2 . 3 2 2 0 . 7 6 1 0 . 7 6 1 0 . 7 6 - 2 0 . 7 6 S u f i c i a l U p p e r 2 P V C DM W - 0 2 0 2 / 2 4 / 2 0 1 7 3 4 . 3 0 0 2 6 9 1 9 - 7 7 . 9 8 8 1 9 5 1 1 2 1 . 4 3 1 8 . 9 4 2 . 4 9 1 9 . 8 3 9 . 8 3 9 . 8 3 - 1 9 . 8 3 S u f i c i a l U p p e r 2 P V C DM W - 0 3 0 2 / 2 7 / 2 0 1 7 3 4 . 2 9 4 9 5 8 1 6 - 7 7 . 9 8 2 4 0 7 2 7 2 8 . 1 5 2 5 . 8 2 2 . 3 3 2 0 . 1 3 1 0 . 1 3 1 0 . 1 3 - 2 0 . 1 3 S u f i c i a l U p p e r 2 P V C DM W - 0 4 0 2 / 2 7 / 2 0 1 7 3 4 . 2 9 6 4 5 2 8 0 - 7 7 . 9 8 3 1 2 4 1 7 2 1 . 6 2 1 9 . 3 5 2 . 2 7 2 8 . 6 4 1 8 . 6 4 1 8 . 6 4 - 2 8 . 6 4 S u f i c i a l U p p e r 2 P V C 1. T O C i n d i c a t e s t o p o f c a s i n g . 2. f t . i n d i c a t e s f e e t . 3. i n . i n d i c a t e s i n c h e s n o m i n a l d i a m e t e r . 4. P V C i n d i c a t e s p ol y vi n y l c h l o r i d e . 5. H o r i z o n t a l d a t u m N A D 8 3 . 6. E l e v a t i o n s b a s e d o n N A V D 8 8 . Pr e p a r e d b y : B E R Checked by: PBW No t e s : To t a l W e l l De p t h be l o w T O C (f t . ) Co o r d i n a t e s We l l I D We l l In s t a l l a t i o n Da t e We l l T O C El e v a t i o n (f t . ) Gr o u n d Su r f a c e El e v a t i o n (f t . ) We l l S t i c k - u p He i g h t A b o v e Gr o u n d S u r f a c e (f t . ) Well Diameter (in.)Casing Type De p t h t o T o p of S c r e e n fr o m T O C (f t . ) Sc r e e n e d In t e r v a l be l o w T O C (f t . ) Ge o l o g y o f Sc r e e n e d In t e r v a l P: \ D u k e E n e r g y P r o g r e s s . 1 0 2 6 \ 2 0 8 . S u t t o n C C P C C R G W A s s e s s , W e l l I n s t a l l & M o n i t o r i n g \ 0 7 . R e p o r t i n g a n d R e c o r d k e e p i n g \ S W L F \ R e p o r t \ T a b l e s \ T a b l e 1 W e l l C o n s t r u c t i o n I n f o r m a t i o n . X L S X Page 1 of 1 TA B L E 2 GR O U N D W A T E R S E E P A G E V E L O C I T Y SU T T O N O N S I T E L A N D F I L L L. V . S U T T O N E N E R G Y C O M P L E X DU K E E N E R G Y P R O G R E S S , L L C , W I L M I N G T O N , N C DM W - 2 t o D M W - 4 9 . 2 8 8 . 5 4 2 7 0 0 0 . 0 0 0 2 7 4 6 3 . 5 3 0 . 3 0 . 0 5 8 BM W - 2 t o D M W - 4 8 . 8 1 8 . 5 4 1 9 2 5 0 . 0 0 0 1 4 0 6 3 . 5 3 0 . 3 0 . 0 3 0 BM W - 4 t o D M W - 4 8 . 8 7 8 . 5 4 1 2 5 0 0 . 0 0 0 2 6 4 6 3 . 5 3 0 . 3 0 . 0 5 6 NO T E S : Pr e p a r e d b y : J H G Checked by: MCM Hy d r a u l i c Co n d u c t i v i t y (F t / D a y ) Ef f e c t i v e Po r o s i t y Seepage Velocity (Ft/Day) We l l I D s U p g r a d i e n t Gr o u n d w a t e r El e v a t i o n (F t ) Do w n g r a d i e n t Gr o u n d w a t e r El e v a t i o n ( F t ) Di s t a n c e ( F t ) Hy d r a u l i c Gr a d i e n t (F t / F t ) 1. M o n i t o r i n g w e l l s a r e n o t l i s t e d w h e r e i n s u f f i c i e n t g r o u n d w a t e r c o n t o u r i n f o r m a t i o n i s u n a v a i l a b l e t o c a l c u l a t e v e l o c i t y . 2. H y d r a u l i c g r a d i e n t s , e f f e c t i v e p o r o s t i e s , a n d g r o u n d w a t e r v e l o c i t i e s a r e a p p r o x i m a t e . 3. E f f e c t i v e p o r o s i t y o f 0 . 3 a n d h y d r a u l i c c o n d u c t i v i t y o f 6 3 . 5 3 w e r e o b t a i n e d f r o m L . V . S u t t o n E n e r g y C o m p l e x C A P 2 ( F e b r u a r y 1 , 2 0 1 6 ) T a b l e 6 - 2 - I n p u t P a r a m e t e r s a n d Va l u e s f o r C o n v e c t i v e - D i s p e r s i v e F l o w E q u a t i o n P: \ D u k e E n e r gy P r o g re s s . 1 0 2 6 \ 2 0 8 . S u t t o n C C P C C R G W A s s e s s , W e l l I n s t a l l & M o n i t o r i n g \0 7 . R e p or t i n g a n d R e c o r d k e e p in g \S W L F \ R e p or t \ T a b l e s \ T A B L E 2 - G r o u n d w a t e r S e e p a g e Ve l o c i t y . x l s x Page 1 of 1 TA B L E 3 FI E L D D A T A P A R A M E T E R S SU T T O N O N S I T E L A N D F I L L - P E R M I T N O . 6 5 1 2 L. V . S U T T O N E N E R G Y C O M P L E X DU K E E N E R G Y P R O G R E S S , L L C , W I L M I N G T O N , N C 03 / 0 9 / 2 0 1 7 B M W - 0 1 Cle a r N o t N o t e d L F 40 0 0. 7 2 1 . 0 0 N o 2 1 18 3 4. 9 6 . 3 1 9 9 6 . 7 1 2 . 1 7 18.47 04 / 0 4 / 2 0 1 7 B M W - 0 1 Cle a r N o t N o t e d L F 20 0 N/ A 0 . 2 5 N o 2 4 19 0 4. 9 0 . 7 1 8 0 7 . 1 7 N / A NM 03 / 0 8 / 2 0 1 7 B M W - 0 2 C l e a r w / F i n e s N o t N o t e d L F 38 0 1. 9 4 1 2 . 0 0 N o 1 7 87 6. 0 1 6 . 2 3 9 0 . 2 9 . 5 9 6.96 04 / 0 6 / 2 0 1 7 B M W - 0 2 C l o u d y N o t N o t e d L F 10 0 1. 9 0 3 . 0 0 N o 1 9 90 6. 0 1 2 6 . 0 - 5 4 0 . 2 6 9 . 3 1 7.24 03 / 0 8 / 2 0 1 7 B M W - 0 3 Cle a r N o t N o t e d L F 40 0 1. 0 0 1 . 5 0 N o 1 9 58 6. 0 5 . 3 1 3 4 7 . 8 7 . 8 9 16.97 04 / 0 4 / 2 0 1 7 B M W - 0 3 Cle a r N o t N o t e d L F 15 3 N/ A 3 . 5 0 N o 2 4 42 5. 2 9 . 9 1 2 7 6 . 1 4 N / A NM 03 / 0 8 / 2 0 1 7 B M W - 0 4 Cle a r N o t N o t e d L F 50 0 1. 6 6 1 . 5 0 N o 1 8 17 5 7. 2 2 . 0 7 4 5 . 4 0 9 . 3 4 7.66 04 / 0 5 / 2 0 1 7 B M W - 0 4 Cle a r N o t N o t e d L F 43 6 1. 5 8 1 . 5 0 N o 1 8 18 5 7. 2 1 . 6 6 3 6 . 5 6 8 . 8 5 8.15 03 / 0 9 / 2 0 1 7 D M W - 0 1 C l e a r w / F i n e s N o t N o t e d L F 50 0 0. 7 0 2 . 0 0 N o 2 0 13 3 6. 3 4 . 2 1 5 7 7 . 6 0 1 0 . 6 4 16.44 04 / 0 6 / 2 0 1 7 D M W - 0 1 Cle a r N o t N o t e d L F 45 0 N/ A 1 . 5 0 N o 2 1 81 5. 7 2 . 0 1 4 7 6 . 3 2 N / A NM 03 / 0 9 / 2 0 1 7 D M W - 0 2 Cle a r N o t N o t e d L F 40 0 1. 4 3 1 . 5 0 N o 1 9 72 5. 4 5 . 8 1 6 8 3 . 2 1 0 . 3 9 11.04 04 / 0 6 / 2 0 1 7 D M W - 0 2 Cle a r N o t N o t e d L F 44 4 1. 3 0 4 . 3 0 N o 1 9 55 5. 5 8 . 9 1 4 9 0 . 9 2 9 . 5 9 11.84 03 / 0 7 / 2 0 1 7 D M W - 0 3 Cle a r N o t N o t e d L F 32 0 1. 0 4 1 . 5 0 N o 2 0 36 4. 4 5 . 7 2 1 2 5 . 5 1 4 . 4 1 13.74 04 / 0 5 / 2 0 1 7 D M W - 0 3 Cle a r N o t N o t e d L F 35 0 N/ A 1 . 0 0 N o 2 0 40 4. 5 1 . 7 1 7 0 5 . 1 5 N / A NM 03 / 0 7 / 2 0 1 7 D M W - 0 4 Cle a r N o t N o t e d L F 36 0 1. 5 2 3 . 0 0 N o 2 0 23 8 9. 5 4 . 7 7 5 7 . 6 2 . 3 2 19.30 04 / 0 5 / 2 0 1 7 D M W - 0 4 Cle a r N o t N o t e d L F 45 0 1. 4 8 2 . 5 0 N o 1 9 94 6. 2 1 . 8 1 3 1 7 . 5 9 2 . 0 8 19.54 Prepared by: BER Checked by: PBW No t e s : Groundwater Elevation (ft.)Depth to Water below TOC (ft.) 11 . D e p t h t o w a t e r m e a s u r e m e n t s t a k e n o n M a y 2 , 2 0 1 7 . 12 . N M = N o t M e a s u r e d . Sp e c i f i c Co n d u c t a n c e (µmh o / c m ) pH ( S U ) Tu r b i d i t y (N T U ) 1. P u r g e M e t h o d s ; L F = L o w F l o w , L F ( M ) = L o w F l o w M o d i f i e d , C P = C o n v e n t i o n a l P u r g e ( 3 - 5 we l l v o l u m e s ) , N P = N o P u r g e ( H y d r a S l e e v e ) , E O P = E q u i p m e n t O n l y P u r g e . A v e r a g e p u m p ra t e a p p l i c a b l e t o L F a n d L F ( M ) p u r g i n g o n l y . 2. F i e l d s a m p l i n g p e r f o r m e d b y S y n T e r r a C o r p o r a t i o n p e r s o n n e l . Ap p e a r a n c e O d o r Pu r g e Me t h o d Sa m p l e Da t e Sa m p l e I D OR P (m V ) DO (ug/L) Av e r a g e Pu m p R a t e (m L / m i n ) We l l Vo l u m e (g a l l o n s ) EV A C Vo l u m e (g a l l o n s ) EV A C (y e s / n o ) Te m p (d e g C ) 10 . N / A = N o t A p p l i c a b l e 3. E V A C i n d i c a t e s w h e t e r t h e w a t e r l e v e l i n t h e w e l l w a s d r a w n d o w n t o t h e l e v e l o f t h e pu m p d u r i n g p u r g i n g . 4. µ m h o s / c m = m i c r o m h o s p e r c e n t i m e t e r 5. m L / m i n = m i l l i l i t e r s p e r m i n u t e 6. S U = S t a n d a r d U n i t s 7. N T U = N e p h e l o m e t r i c T u r b i d i t y U n i t s 8. m V = m i l l i v o l t s 9. u g / L = m i c r o g r a m s p e r l i t e r P: \ D u k e E n e r g y P r o g r e s s . 1 0 2 6 \ 2 0 8 . S u t t o n C C P C C R G W A s s e s s , W e l l I n s t a l l & M o n i t o r i n g \ 0 7 . R e p o r t i n g a n d R e c o r d k e e p i n g \ S W L F \ R e p o r t \ T a b l e s \ T a b l e 3 F i e l d D a t a P a r a m e t e r s . x l s x Page 1 of 1 pH Wa t e r Le v e l Te m p S p e c C o n d D O O R P E h T u r b i d i t y A r s e n i c B a r i u m B o r o n C a d m i u m C h l o r i d e C h r o m i u m C o p p e r F l u o r i d e I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l Nitrate (as N)Selenium S i l v e r S u l f a t e T h a l l i u m Total Dissolved SolidsZinc S. U . f t D e g C u m h o s / c m m g / L m V m V N T U s u g / L u g / L u g / L u g / L m g / L u g / L u g / L m g / L u g / L u g / L u g / L u g / L u g / L m g - N / L u g / L u g / L m g / L u g / L m g / L u g / L 6. 5 - 8 . 5 N E N E N E N E N E N E N E 1 0 7 0 0 7 0 0 2 2 5 0 1 0 1 0 0 0 2 3 0 0 1 5 5 0 1 1 0 0 1 0 2 0 2 0 2 5 0 N E 5 0 0 1 0 0 0 Sa m p l e I D Sa m p l e Co l l e c t i o n D a t e BM W - 0 1 0 3 / 0 9 / 2 0 1 7 4. 9 18 . 4 7 2 1 1 8 3 6 . 7 0 1 9 9 4 0 4 6 . 3 < 1 7 2 < 5 0 < 1 7 . 9 < 5 < 5 < 0 . 1 8 9 < 1 2 9 < 0 . 0 5 < 5 4 . 9 < 1 < 5 5 1 < 0 . 2 6 9 < 5 BM W - 0 1 0 4 / 0 4 / 2 0 1 7 4. 9 NM 2 4 1 9 0 7 . 1 7 1 8 0 3 8 5 0 . 6 8 < 1 7 2 < 5 0 < 1 7 . 7 < 5 < 5 < 0 . 1 2 5 < 1 2 5 < 0 . 0 5 < 5 3 . 6 B 2 < 1 < 5 7 9 < 0 . 2 1 2 0 6 BM W - 0 2 0 3 / 0 8 / 2 0 1 7 6. 0 6. 9 6 1 7 8 7 0 . 2 0 3 9 2 4 4 1 6 . 2 1 . 0 3 6 < 5 0 < 1 4 < 5 < 5 < 0 . 1 25 9 0 <1 2 6 < 0 . 0 5 < 5 < 0 . 0 2 3 < 1 < 5 4 . 2 < 0 . 2 6 6 < 5 BM W - 0 2 0 4 / 0 6 / 2 0 1 7 6. 0 7. 2 4 1 9 9 0 0 . 2 6 - 5 4 1 5 1 1 2 6 2 . 2 4 2 2 < 5 0 < 1 4 . 8 17 6< 0 . 1 66 3 0 6. 1 4 2 4 < 0 . 0 5 1 1 < 0 . 0 2 3 < 1 < 5 1 9 < 0 . 2 2 3 0 1 3 BM W - 0 3 0 3 / 0 8 / 2 0 1 7 6. 0 16 . 9 7 1 9 5 8 7 . 8 0 1 3 4 3 3 9 5 . 3 < 1 1 7 < 5 0 < 1 5 . 4 < 5 < 5 < 0 . 1 1 5 < 1 52 <0 . 0 5 < 5 0 . 0 4 < 1 < 5 5 . 9 < 0 . 2 3 3 < 5 BM W - 0 3 D U P 0 3 / 0 8 / 2 0 1 7 6. 0 16 . 9 7 1 9 5 8 7 . 8 0 1 3 4 3 3 9 5 . 3 < 1 1 6 < 5 0 < 1 5 . 5 < 5 < 5 < 0 . 1 < 1 0 < 1 53 <0 . 0 5 < 5 0 . 0 8 < 1 < 5 5 . 9 < 0 . 2 2 6 < 5 BM W - 0 3 0 4 / 0 4 / 2 0 1 7 5. 2 NM 2 4 4 2 6 . 1 4 1 2 7 3 3 2 9 . 9 2 < 1 1 6 < 5 0 < 1 4 . 7 < 5 < 5 0 . 1 4 2 1 8 < 1 65 <0 . 0 5 < 5 0 . 0 8 B 2 < 1 < 5 7 . 7 < 0 . 2 2 8 5 BM W - 0 4 0 3 / 0 8 / 2 0 1 7 7 . 2 7 . 6 6 1 8 1 7 5 5 . 4 0 7 4 2 7 9 2 < 1 < 5 < 5 0 < 1 5 . 7 < 5 < 5 < 0 . 1 1 2 < 1 < 5 < 0 . 0 5 < 5 0 . 4 6 < 1 < 5 6 . 2 < 0 . 2 8 5 < 5 BM W - 0 4 04 / 0 5 / 2 0 1 7 7 . 2 8 . 1 5 1 8 18 5 6. 5 6 63 2 6 8 1 . 5 6 < 1 5 < 5 0 < 1 5 <5 < 5 < 0 . 1 2 6 < 1 <5 < 0 . 0 5 < 5 0 . 3 9 <1 < 5 1 1 M 2 < 0 . 2 1 2 0 < 5 DM W - 0 1 03 / 0 9 / 2 0 1 7 6. 3 16 . 4 4 2 0 13 3 7. 6 0 1 5 7 3 6 2 4 . 2 <1 5 7 < 5 0 < 1 10 < 5 < 5 < 0 . 1 1 5 3 < 1 15 < 0 . 0 5 < 5 4 . 7 <1 < 5 2 . 2 < 0 . 2 1 0 0 < 5 DM W - 0 1 04 / 0 6 / 2 0 1 7 5. 7 NM 2 1 81 6. 3 2 1 4 7 3 5 2 1 . 9 7 < 1 1 2 7 < 5 0 < 1 8 . 3 < 5 < 5 0 . 1 6 2 9 < 1 24 < 0 . 0 5 < 5 3 . 7 <1 < 5 1 . 9 < 0 . 2 8 2 < 5 DM W - 0 2 03 / 0 9 / 2 0 1 7 5. 4 11 . 0 4 1 9 72 3. 2 0 1 6 8 3 7 3 5 . 8 <1 2 0 < 5 0 < 1 4 . 4 < 5 < 5 < 0 . 1 33 7 <1 38 < 0 . 0 5 < 5 3 . 1 <1 < 5 3 . 1 < 0 . 2 9 7 < 5 DM W - 0 2 04 / 0 6 / 2 0 1 7 5. 5 11 . 8 4 1 9 55 0. 9 2 1 4 9 3 5 4 8 . 8 5 < 1 2 2 < 5 0 < 1 4 . 3 < 5 < 5 < 0 . 1 47 1 <1 28 < 0 . 0 5 < 5 2 . 8 <1 < 5 3 . 7 < 0 . 2 5 7 < 5 DM W - 0 2 D U P 04 / 0 6 / 2 0 1 7 5. 5 11 . 8 4 1 9 55 0. 9 2 1 4 9 3 5 4 8 . 8 5 < 1 2 1 < 5 0 < 1 4 . 3 < 5 < 5 < 0 . 1 44 0 <1 28 < 0 . 0 5 < 5 3 <1 < 5 4 . 1 < 0 . 2 5 3 < 5 DM W - 0 3 03 / 0 7 / 2 0 1 7 4. 4 13 . 7 4 2 0 36 5. 5 0 2 1 2 4 1 7 5 . 7 <1 7 < 5 0 < 1 3 . 8 < 5 < 5 0 . 1 2 6 3 < 1 25 < 0 . 0 5 < 5 0 . 0 7 <1 < 5 8 . 7 < 0 . 2 < 2 5 < 5 DM W - 0 3 04 / 0 5 / 2 0 1 7 4. 5 NM 2 0 40 5. 1 5 1 7 0 3 7 5 1 . 6 6 < 1 6 < 5 0 < 1 5 . 4 < 5 < 5 0. 1 2 1 < 1 43 < 0 . 0 5 < 5 0 . 0 5 <1 < 5 1 3 M 2 < 0 . 2 2 6 < 5 DM W - 0 4 03 / 0 7 / 2 0 1 7 9. 5 19 . 3 0 2 0 23 8 7. 6 0 75 2 8 0 4 . 7 2 . 5 3 9 < 5 0 < 1 11 < 5 < 5 < 0 . 1 4 9 < 1 5 <0 . 0 5 < 5 7 . 2 <1 < 5 2 4 < 0 . 2 1 7 0 < 5 DM W - 0 4 04 / 0 5 / 2 0 1 7 6. 2 19 . 5 4 1 9 94 7. 5 9 1 3 1 3 3 6 1 . 7 9 < 1 3 7 < 5 0 < 1 5 . 4 < 5 < 5 < 0 . 1 3 6 < 1 61 <0 . 0 5 < 5 2 . 5 <1 < 5 1 2 M 2 < 0 . 2 7 1 6 Prepared by: BER Checked By: PBW No t e s : - B o l d h i g h l i g h t e d c o n c e n t r a t i o n i n d i c a t e s e x c e e d a n c e o f t h e 1 5 A N C A C 0 2 L . 0 2 0 2 S t a n d a r d o r t h e I M A C . ( E f f e c t i v e d a t e f o r 1 5 A N CA C 0 2 L . 0 2 0 2 S t a n d a r d a n d I M A C i s A p r i l 1 , 2 0 1 3 ) De g C - D e g r e e s C e l s i u s N T U - N e p h e l o m e t r i c t u r b i d i t y u n i t m g / L - M i l l i g r a m s p e r l i t e r N E - N o t e s t a b l i s h e d OR P - O x i d a t i o n - R e d u c t i o n P o t e n t i a l OR P - O x i d a t i o n - R e d u c t i o n P o t e n t i a l ug / L - M i c r o g r a m s p e r l i t e r NM - N o t m e a s u r e d DO - D i s s o l v e d o x y g e n S. U . - S t a n d a r d U n i t mV - M i l l i v o l t s Eh - R e d o x P o t e n t i a l Sp e c C o n d - S p e c i f i c C o n d u c t a n c e mg - N / L - M i l l i g r a m s n i t r o g e n p e r l i t e r ft - F e e t Te m p - T e m p e r a t u r e um h o s / c m - M i c r o m h o s p e r c e n t i m e t e r B2 - T a r g e t a n a l y t e w a s d e t e c t e d i n b l a n k ( s ) a t a c o n c e n t r a t i o n g r e a t e r t h a n 1 / 2 t h e r e p o r t i n g l i m i t b u t l e s s t h a n t h e r e p o r t i n g l i m i t . A n a l y t e c o n c e n t r a t i o n i n s a m p l e i s v a l i d a n d m a y b e u s e d f o r c o m p l i a n c e p u r p o s e s . B3 - T a r g e t a n a l y t e w a s d e t e c t e d i n C o n t i n u i n g C a l i b r a t i o n B l a n k ( s ) a t a c o n c e n t r a t i o n g r e a t e r t h a n 1 / 2 t h e r e p o r t i n g l i m i t b u t le s s t h a n t h e r e p o r t i n g l i m i t . A n a l y t e c o n c e n t r a t i o n i n s a m p l e i s v a l i d a n d m a y b e u s e d f o r c o m p l i a n c e p u r p o s e s . M2 - M a t r i x s p i k e r e c o v e r y w a s L o w : t h e a s s o c i a t e d L a b o r a t o r y C o n t r o l S p i k e ( L C S ) w a s a c c e p t a b l e . TA B L E 4 GR O U N D W A T E R F I E L D A N D A N A L Y T I C A L R E S U L T S L. V . S U T T O N E N E R G Y C O M P L E X DU K E E N E R G Y P R O G R E S S , L L C , W I L M I N G T O N , N C Fie l d P a r a m e t e r s NC 2 L S t a n d a r d Re p o r t i n g U n i t s An a l y t i c a l P a r a m e t e r An a l y t i c a l R e s u l t s P: \ D u k e E n e r g y P r o g r e s s . 1 0 2 6 \ 2 0 8 . S u t t o n C C P C C R G W A s s e s s , W e l l I n s t all & M o n i t o r i n g \ 0 7 . R e p o r t i n g a n d R e c o r d k e e p i n g \ S W L F \ R e p o r t \T a b l e s \ T a b l e 4 G W F i e l d a n d A n a l y t i c a l R e s u l t s . x l s x Page 1 of 1 Parameter Sample ID Result (April 2017)Units 15A NCAC 2L Standard Historical Concentrations (March 2017)Cause and Significance BMW-01 4.9 4.9 Statistical evaluation of baseline data will be used to determine cause and significance. BMW-02 6.0 6.0 Statistical evaluation of baseline data will be used to determine cause and significance. BMW-03 5.2 6.0 Statistical evaluation of baseline data will be used to determine cause and significance. DMW-01 5.7 6.3 Statistical evaluation of baseline data will be used to determine cause and significance. DMW-02 5.5 5.4 Statistical evaluation of baseline data will be used to determine cause and significance. DMW-03 4.5 4.4 Statistical evaluation of baseline data will be used to determine cause and significance. DMW-04 6.2 9.5 Statistical evaluation of baseline data will be used to determine cause and significance. Chromium BMW-02 17 µg/L 10 <5 Statistical evaluation of baseline data will be used to determine cause and significance. Iron BMW-02 6630 µg/L 300 2590 Statistical evaluation of baseline data will be used to determine cause and significance. BMW-03 65 52 Statistical evaluation of baseline data will be used to determine cause and significance. DMW-04 61 5 Statistical evaluation of baseline data will be used to determine cause and significance. Prepared by: PBW Checked by: JHG Notes: 1. 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013. 2. µg/L indicates micrograms per liter. 3. SU indicates Standard Units. 4. Historical concentrations are based on initial baseline sampling event in March 2017. 5. Field sampling performed by SynTerra Corporation, Sample Dates: March 7,8,9 and April 4, 5, 6, 2017 TABLE 5 FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED 15A NCAC 2L GROUNDWATER QUALITY STANDARDS ONSITE SUTTON LANDFILL - PERMIT NO. 6512-INDUS-2016L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC SU 6.5-8.5Field pH Manganese µg/L 50 P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\Tables\Table 5 Field and Analystical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality StandardsTable 5 Field and An L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx APPENDIX A FIELD SAMPLING FORMS L.V. Sutton Groundwater Monitoring Report – Baseline Sampling Events #1 & #2 June 2017 Duke Energy Progress, LLC SynTerra P:\Duke Energy Progress.1026\208.Sutton CCP CCR GW Assess, Well Install & Monitoring\07.Reporting and Recordkeeping\SWLF\Report\FINAL Sutton Baseline Report.docx APPENDIX B LABORATORY REPORT AND CHAIN-OF-CUSTODY FORMS 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17030090 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:3/23/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017007141 Sutton 08-Mar-17 12:58 PM Plant Personell BMW-2 2017007996 Sutton 08-Mar-17 3:49 PM Plant Personell BMW-3 2017007997 Sutton 08-Mar-17 2:39 PM Plant Personell BMW-4 2017007998 Sutton 08-Mar-17 3:49 PM Plant Personell BMW-3 DUP 2017007999 Sutton 08-Mar-17 4:05 PM Plant Personell EQB 5 Total Samples Page 2 of 16 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:3/23/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 2017007141 Collection Date:08-Mar-17 12:58 PM Site:BMW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.0 mg/L EPA 9056A 03/09/2017 14:13 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/09/2017 14:13 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 03/09/2017 14:13 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 03/09/2017 14:13 BGN90340.023 1 Sulfate 4.2 mg/L EPA 9056A 03/09/2017 14:13 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:33 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.006 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:15 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Iron (Fe)2.59 mg/L SW 6010D 03/14/2017 10:15 MHH71310.01 1 Manganese (Mn)0.026 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:15 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Arsenic (As)1.03 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 18:11 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 18:11 CWSPEN30.2 1 Vanadium (V) Low Level 2.47 ug/L SW 6020B 03/14/2017 18:11 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 66 mg/L SM2540C 03/14/2017 15:00 MGIGANT251 Page 4 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 2017007996 Collection Date:08-Mar-17 3:49 PM Site:BMW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.4 mg/L EPA 9056A 03/09/2017 14:28 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/09/2017 14:28 BGN90340.1 1 Nitrate 0.19 mg/L EPA 9056A 03/09/2017 14:28 BGN90340.1 1 Nitrate as N 0.04 mg-N/L EPA 9056A 03/09/2017 14:28 BGN90340.023 1 Sulfate 5.9 mg/L EPA 9056A 03/09/2017 14:28 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:35 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.017 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:32 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Iron (Fe)0.015 mg/L SW 6010D 03/14/2017 10:32 MHH71310.01 1 Manganese (Mn)0.052 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:32 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Cobalt (Co)1.58 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 17:42 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 17:42 CWSPEN30.2 1 Vanadium (V) Low Level 0.888 ug/L SW 6020B 03/14/2017 17:42 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 33 mg/L SM2540C 03/14/2017 15:00 MGIGANT251 Page 5 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 2017007997 Collection Date:08-Mar-17 2:39 PM Site:BMW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.7 mg/L EPA 9056A 03/09/2017 14:43 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/09/2017 14:43 BGN90340.1 1 Nitrate 2.1 mg/L EPA 9056A 03/09/2017 14:43 BGN90340.1 1 Nitrate as N 0.46 mg-N/L EPA 9056A 03/09/2017 14:43 BGN90340.023 1 Sulfate 6.2 mg/L EPA 9056A 03/09/2017 14:43 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:38 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:36 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Iron (Fe)0.012 mg/L SW 6010D 03/14/2017 10:36 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:36 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 18:40 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 18:40 CWSPEN30.2 1 Vanadium (V) Low Level 0.579 ug/L SW 6020B 03/14/2017 18:40 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 85 mg/L SM2540C 03/14/2017 15:00 MGIGANT251 Page 6 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 2017007998 Collection Date:08-Mar-17 3:49 PM Site:BMW-3 DUP Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.5 mg/L EPA 9056A 03/09/2017 14:59 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/09/2017 14:59 BGN90340.1 1 Nitrate 0.34 mg/L EPA 9056A 03/09/2017 14:59 BGN90340.1 1 Nitrate as N 0.08 mg-N/L EPA 9056A 03/09/2017 14:59 BGN90340.023 1 Sulfate 5.9 mg/L EPA 9056A 03/09/2017 14:59 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:40 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.016 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:40 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 03/14/2017 10:40 MHH71310.01 1 Manganese (Mn)0.053 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:40 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Cobalt (Co)1.46 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 18:47 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 18:47 CWSPEN30.2 1 Vanadium (V) Low Level 0.812 ug/L SW 6020B 03/14/2017 18:47 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 26 mg/L SM2540C 03/14/2017 15:00 MGIGANT251 Page 7 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 2017007999 Collection Date:08-Mar-17 4:05 PM Site:EQB Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 9056A 03/09/2017 11:42 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/09/2017 11:42 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 03/09/2017 11:42 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 03/09/2017 11:42 BGN90340.023 1 Sulfate < 0.1 mg/L EPA 9056A 03/09/2017 11:42 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:43 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:44 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 03/14/2017 10:44 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:44 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 18:55 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 18:55 CWSPEN30.2 1 Vanadium (V) Low Level 0.403 ug/L SW 6020B 03/14/2017 18:55 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 03/14/2017 15:00 MGIGANT251 Page 8 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030218 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.038 mg/L -10.038 0.1 < 1/2 RDL Fluoride 0.0183 mg/L -10.0183 0.1 < 1/2 RDL Nitrate 0.0166 mg/L -10.0166 0.1 < 1/2 RDL Sulfate -0.0333 mg/L -1-0.0333 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 9.2 50 98.7mg/L -120801092 Fluoride 4.89 50 97.4mg/L -120801048.9 Nitrate 5.09 50 101mg/L -120801050.9 Sulfate 5.24 50 101mg/L -120801052.4 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 9.22 50 99.1 0.421mg/L -120801092.2 Fluoride 4.89 50 97.4 0.0164mg/L -120801048.9 Nitrate 5.08 50 101 0.085mg/L -120801050.8 Sulfate 5.24 50 101 0.00197mg/L -120801052.4 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 5.17 5 103mg/L -1109015.17 Fluoride 5.15 5 103mg/L -1109015.15 Nitrate 5.16 5 103mg/L -1109015.16 Sulfate 5.18 5 104mg/L -1109015.18 Page 9 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030514 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) -0.008 ug/L -1-0.008 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.88 2 94.1ug/L -1158511.88 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.87 2 93.5ug/L -1158511.87 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006886 Mercury (Hg) 0.845 1 84.4ug/L -1257510.845 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006886 Mercury (Hg) 0.849 1 84.8 0.473ug/L -1257510.849 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006889 Mercury (Hg) 0.911 1 90.5ug/L -1257510.911 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006889 Mercury (Hg) 0.928 1 92.2 1.86ug/L -1257510.928 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006899 Mercury (Hg) 0.89 1 89.6ug/L -1257510.89 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006899 Mercury (Hg) 0.892 1 89.8 0.223ug/L -1257510.892 Page 10 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030299 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) 0.0005 mg/L -10.0005 0.005 < 1/2 RDL Boron (B) 0.000057 mg/L -10.000057 0.05 < 1/2 RDL Chromium (Cr) -0.00029 mg/L -1-0.00029 0.005 < 1/2 RDL Copper (Cu) -0.000444 mg/L -1-0.000444 0.005 < 1/2 RDL Iron (Fe) -0.00003 mg/L -1-0.00003 0.01 < 1/2 RDL Manganese (Mn) -0.000335 mg/L -1-0.000335 0.005 < 1/2 RDL Nickel (Ni) -0.00033 mg/L -1-0.00033 0.005 < 1/2 RDL Silver (Ag) -0.000015 mg/L -1-0.000015 0.005 < 1/2 RDL Zinc (Zn) -0.000308 mg/L -1-0.000308 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.08 5 102mg/L -1208015.08 Boron (B) 5.02 5 100mg/L -1208015.02 Chromium (Cr) 5.07 5 101mg/L -1208015.07 Copper (Cu) 5.03 5 101mg/L -1208015.03 Iron (Fe) 5.11 5 102mg/L -1208015.11 Manganese (Mn) 5.1 5 102mg/L -1208015.1 Nickel (Ni) 5.13 5 103mg/L -1208015.13 Silver (Ag) 0.488 0.5 97.6mg/L -1208010.488 Zinc (Zn) 5.14 5 103mg/L -1208015.14 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Barium (Ba) 5.01 5 100mg/L -1257515.01 Boron (B) 4.98 5 98.7mg/L -1257514.98 Chromium (Cr) 5.02 5 100mg/L -1257515.02 Copper (Cu) 4.94 5 98.8mg/L -1257514.94 Iron (Fe) 7.54 5 99mg/L -1257517.54 Manganese (Mn) 5.07 5 101mg/L -1257515.07 Nickel (Ni) 5.08 5 102mg/L -1257515.08 Silver (Ag) 0.482 0.5 96.3mg/L -1257510.482 Zinc (Zn) 5.1 5 102mg/L -1257515.1 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Barium (Ba) 4.97 5 99.3 0.822mg/L -1257514.97 Boron (B) 4.91 5 97.4 1.33mg/L -1257514.91 Chromium (Cr) 4.96 5 99.2 1.16mg/L -1257514.96 Copper (Cu) 4.89 5 97.9 0.875mg/L -1257514.89 Page 11 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030299 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Iron (Fe) 7.4 5 96.3 2.75mg/L -1257517.4 Manganese (Mn) 5.02 5 99.9 1.02mg/L -1257515.02 Nickel (Ni) 5.03 5 101 0.95mg/L -1257515.03 Silver (Ag) 0.477 0.5 95.3 1.05mg/L -1257510.477 Zinc (Zn) 5.04 5 101 1.15mg/L -1257515.04 Page 12 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030306 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) -0.051 ug/L -1-0.051 1 < 1/2 RDL Arsenic (As) 0.011 ug/L -10.011 1 < 1/2 RDL Beryllium (Be) 0.006 ug/L -10.006 1 < 1/2 RDL Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL Cobalt (Co) 0 ug/L -10 1 < 1/2 RDL Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL Selenium (Se) -0.007 ug/L -1-0.007 1 < 1/2 RDL Thallium (Tl) Low Level -0.014 ug/L -1-0.014 0.2 < 1/2 RDL Vanadium (V) Low Level 0.033 ug/L -10.033 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 50.3 50 101ug/L -12080150.3 Arsenic (As) 50.6 50 101ug/L -12080150.6 Beryllium (Be) 50.4 50 101ug/L -12080150.4 Cadmium (Cd) 50.4 50 101ug/L -12080150.4 Cobalt (Co) 48.9 50 97.7ug/L -12080148.9 Lead (Pb) 50.3 50 101ug/L -12080150.3 Selenium (Se) 47.8 50 95.6ug/L -12080147.8 Thallium (Tl) Low Level 47.6 50 95.1ug/L -12080147.6 Vanadium (V) Low Level 50 50 99.9ug/L -12080150 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Antimony (Sb) 50.5 50 101ug/L -12575150.5 Arsenic (As) 51.1 50 101ug/L -12575151.1 Beryllium (Be) 51.9 50 104ug/L -12575151.9 Cadmium (Cd) 50.2 50 100ug/L -12575150.2 Cobalt (Co) 50.1 50 97.1ug/L -12575150.1 Lead (Pb) 50.4 50 101ug/L -12575150.4 Selenium (Se) 48.3 50 96.5ug/L -12575148.3 Thallium (Tl) Low Level 48.1 50 96.1ug/L -12575148.1 Vanadium (V) Low Level 50.9 50 100ug/L -12575150.9 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Antimony (Sb) 50.5 50 101 0.115ug/L -12575150.5 Arsenic (As) 50.8 50 101 0.524ug/L -12575150.8 Beryllium (Be) 53.1 50 106 2.12ug/L -12575153.1 Cadmium (Cd) 49.8 50 99.4 0.887ug/L -12575149.8 Page 13 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030306 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Cobalt (Co) 49.9 50 96.7 0.39ug/L -12575149.9 Lead (Pb) 50.2 50 100 0.32ug/L -12575150.2 Selenium (Se) 47.8 50 95.6 0.951ug/L -12575147.8 Thallium (Tl) Low Level 48.9 50 97.7 1.69ug/L -12575148.9 Vanadium (V) Low Level 51.3 50 101 0.781ug/L -12575151.3 Page 14 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030090 Q17030328 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17020482 -- 2017005667 TDS 4820 0.414mg/L -14820 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17020482 -- 2017005668 TDS 5140 0.781mg/L -15140 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J17030048 -- 2017006912 TDS 172 1.73mg/L -1172 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 94 100 94mg/L -11090194 Page 15 of 16 P a g e 1 6 o f 1 6 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17030216 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:3/23/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017007749 Sutton 07-Mar-17 2:08 PM ILLEGIBLE DMW-3 2017007750 Sutton 07-Mar-17 11:34 AM ILLEGIBLE DMW-4 2017007751 Sutton 07-Mar-17 6:00 PM ILLEGIBLE FIELD BLANK 3 Total Samples Page 2 of 16 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:3/23/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 2017007749 Collection Date:07-Mar-17 2:08 PM Site:DMW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 3.8 mg/L EPA 9056A 03/08/2017 14:06 BGN90340.1 1 Fluoride 0.12 mg/L EPA 9056A 03/08/2017 14:06 BGN90340.1 1 Nitrate 0.33 mg/L EPA 9056A 03/08/2017 14:06B3 BGN90340.1 1 Nitrate as N 0.07 mg-N/L EPA 9056A 03/08/2017 14:06 BGN90340.023 1 Sulfate 8.7 mg/L EPA 9056A 03/08/2017 14:06 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/08/2017 15:15 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.007 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/13/2017 09:40 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Iron (Fe)0.063 mg/L SW 6010D 03/13/2017 09:40 MHH71310.01 1 Manganese (Mn)0.025 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/13/2017 09:40 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/10/2017 15:12 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/10/2017 15:12 CWSPEN30.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 03/10/2017 15:12 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 03/11/2017 15:00 MGIGANT251 Page 4 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 2017007750 Collection Date:07-Mar-17 11:34 AM Site:DMW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 11 mg/L EPA 9056A 03/08/2017 14:39 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 03/08/2017 14:39 BGN90340.1 1 Nitrate 32 mg/L EPA 9056A 03/08/2017 14:39B3 BGN90340.5 5 Nitrate as N 7.2 mg-N/L EPA 9056A 03/08/2017 14:39 BGN90340.023 1 Sulfate 24 mg/L EPA 9056A 03/08/2017 14:39 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:45 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.009 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/13/2017 09:52 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Iron (Fe)0.049 mg/L SW 6010D 03/13/2017 09:52 MHH71310.01 1 Manganese (Mn)0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/13/2017 09:52 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Arsenic (As)2.53 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/10/2017 14:43 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/10/2017 14:43 CWSPEN30.2 1 Vanadium (V) Low Level 4.50 ug/L SW 6020B 03/10/2017 14:43 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 170 mg/L SM2540C 03/11/2017 15:00 MGIGANT251 Page 5 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 2017007751 Collection Date:07-Mar-17 6:00 PM Site:FIELD BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 9056A 03/08/2017 10:19 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/08/2017 10:19 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 03/08/2017 10:19B3 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 03/08/2017 10:19 BGN90340.023 1 Sulfate < 0.1 mg/L EPA 9056A 03/08/2017 10:19 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/21/2017 14:48 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/13/2017 09:56 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 03/13/2017 09:56 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/13/2017 09:56 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/10/2017 15:41 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/10/2017 15:41 CWSPEN30.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 03/10/2017 15:41 CWSPEN30.3 1 Qualifiers: B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than ½ the reporting limit, but less than the reporting limit. Page 6 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030172 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0335 mg/L -10.0335 0.1 < 1/2 RDL Fluoride 0.0162 mg/L -10.0162 0.1 < 1/2 RDL Nitrate 0.0387 mg/L -10.0387 0.1 < 1/2 RDL Sulfate -0.0293 mg/L -1-0.0293 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 5.96 25 99mg/L -12080529.8 Fluoride 4.74 25 94.3mg/L -12080523.7 Nitrate 6.11 25 98.2mg/L -12080530.5 Sulfate 7.34 25 96.5mg/L -12080536.7 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 5.96 25 99.1 0.0727mg/L -12080529.8 Fluoride 4.74 25 94.4 0.0551mg/L -12080523.7 Nitrate 6.13 25 98.7 0.518mg/L -12080530.7 Sulfate 7.34 25 96.5 0.0104mg/L -12080536.7 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Chloride 7.29 25 102mg/L -12080536.4 Fluoride 4.83 25 95.7mg/L -12080524.2 Nitrate 7.22 25 101mg/L -12080536.1 Sulfate 5.29 25 102mg/L -12080526.4 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Chloride 7.31 25 102 0.495mg/L -12080536.6 Fluoride 4.85 25 96 0.294mg/L -12080524.2 Nitrate 7.23 25 101 0.199mg/L -12080536.1 Sulfate 5.3 25 102 0.214mg/L -12080526.5 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.94 5 98.8mg/L -1109014.94 Fluoride 5.03 5 101mg/L -1109015.03 Nitrate 4.98 5 99.6mg/L -1109014.98 Sulfate 4.99 5 99.7mg/L -1109014.99 Page 7 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030215 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.024 ug/L -10.024 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Mercury (Hg) 0.013 ug/L -10.013 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.07 1 105ug/L -1257511.07 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Mercury (Hg) 1.06 1 104 0.954ug/L -1257511.06 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.99 2 99.5ug/L -1158511.99 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.9 2 95.1ug/L -1158511.9 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17020548 -- 2017006027 Mercury (Hg) 0.952 1 92.3ug/L -1257510.952 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17020548 -- 2017006027 Mercury (Hg) 0.953 1 92.4 0.108ug/L -1257510.953 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17020578 -- 2017006125 Mercury (Hg) 0.982 1 97.1ug/L -1257510.982 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17020578 -- 2017006125 Mercury (Hg) 0.966 1 95.5 1.66ug/L -1257510.966 Page 8 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030215 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17020664 -- 2017006381 Mercury (Hg) 0.916 1 90.7ug/L -1257510.916 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17020664 -- 2017006381 Mercury (Hg) 0.902 1 89.3 1.56ug/L -1257510.902 Page 9 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030514 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) -0.008 ug/L -1-0.008 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.88 2 94.1ug/L -1158511.88 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.87 2 93.5ug/L -1158511.87 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006886 Mercury (Hg) 0.845 1 84.4ug/L -1257510.845 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006886 Mercury (Hg) 0.849 1 84.8 0.473ug/L -1257510.849 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006889 Mercury (Hg) 0.911 1 90.5ug/L -1257510.911 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006889 Mercury (Hg) 0.928 1 92.2 1.86ug/L -1257510.928 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006899 Mercury (Hg) 0.89 1 89.6ug/L -1257510.89 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17030046 -- 2017006899 Mercury (Hg) 0.892 1 89.8 0.223ug/L -1257510.892 Page 10 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030220 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) 0.0003 mg/L -10.0003 0.005 < 1/2 RDL Boron (B) 0.0055 mg/L -10.0055 0.05 < 1/2 RDL Chromium (Cr) 0.000282 mg/L -10.000282 0.005 < 1/2 RDL Copper (Cu) 0.000728 mg/L -10.000728 0.005 < 1/2 RDL Iron (Fe) 0.00119 mg/L -10.00119 0.01 < 1/2 RDL Manganese (Mn) 0.000527 mg/L -10.000527 0.005 < 1/2 RDL Nickel (Ni) 0.00024 mg/L -10.00024 0.005 < 1/2 RDL Silver (Ag) 0.000608 mg/L -10.000608 0.005 < 1/2 RDL Zinc (Zn) 0.00122 mg/L -10.00122 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 4.95 5 99mg/L -1208014.95 Boron (B) 4.87 5 97.4mg/L -1208014.87 Chromium (Cr) 4.9 5 98.1mg/L -1208014.9 Copper (Cu) 4.88 5 97.6mg/L -1208014.88 Iron (Fe) 4.95 5 98.9mg/L -1208014.95 Manganese (Mn) 4.92 5 98.5mg/L -1208014.92 Nickel (Ni) 4.96 5 99.1mg/L -1208014.96 Silver (Ag) 0.477 0.5 95.5mg/L -1208010.477 Zinc (Zn) 4.94 5 98.8mg/L -1208014.94 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007749 Barium (Ba) 5 5 99.9mg/L -1257515 Boron (B) 4.89 5 97.5mg/L -1257514.89 Chromium (Cr) 4.93 5 98.6mg/L -1257514.93 Copper (Cu) 4.9 5 98mg/L -1257514.9 Iron (Fe) 5.05 5 99.8mg/L -1257515.05 Manganese (Mn) 4.99 5 99.3mg/L -1257514.99 Nickel (Ni) 4.97 5 99.4mg/L -1257514.97 Silver (Ag) 0.476 0.5 95.1mg/L -1257510.476 Zinc (Zn) 4.94 5 98.8mg/L -1257514.94 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007749 Barium (Ba) 4.98 5 99.5 0.441mg/L -1257514.98 Boron (B) 4.88 5 97.4 0.144mg/L -1257514.88 Chromium (Cr) 4.91 5 98.3 0.325mg/L -1257514.91 Copper (Cu) 4.89 5 97.7 0.327mg/L -1257514.89 Page 11 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030220 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007749 Iron (Fe) 5.03 5 99.3 0.522mg/L -1257515.03 Manganese (Mn) 4.96 5 98.7 0.586mg/L -1257514.96 Nickel (Ni) 4.95 5 98.9 0.545mg/L -1257514.95 Silver (Ag) 0.478 0.5 95.5 0.387mg/L -1257510.478 Zinc (Zn) 4.91 5 98.2 0.589mg/L -1257514.91 Page 12 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030231 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) -0.03 ug/L -1-0.03 1 < 1/2 RDL Arsenic (As) 0.008 ug/L -10.008 1 < 1/2 RDL Beryllium (Be) -0.03 ug/L -1-0.03 1 < 1/2 RDL Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL Cobalt (Co) -0.002 ug/L -1-0.002 1 < 1/2 RDL Lead (Pb) -0.009 ug/L -1-0.009 1 < 1/2 RDL Selenium (Se) 0.017 ug/L -10.017 1 < 1/2 RDL Thallium (Tl) Low Level -0.051 ug/L -1-0.051 0.2 < 1/2 RDL Vanadium (V) Low Level 0.009 ug/L -10.009 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 50.1 50 100ug/L -12080150.1 Arsenic (As) 50.7 50 101ug/L -12080150.7 Beryllium (Be) 53.3 50 107ug/L -12080153.3 Cadmium (Cd) 50.3 50 101ug/L -12080150.3 Cobalt (Co) 49.7 50 99.5ug/L -12080149.7 Lead (Pb) 50.1 50 100ug/L -12080150.1 Selenium (Se) 48.8 50 97.6ug/L -12080148.8 Thallium (Tl) Low Level 47.4 50 94.9ug/L -12080147.4 Vanadium (V) Low Level 50.3 50 101ug/L -12080150.3 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007750 Antimony (Sb) 50.4 50 100ug/L -12575150.4 Arsenic (As) 53.3 50 102ug/L -12575153.3 Beryllium (Be) 52.8 50 105ug/L -12575152.8 Cadmium (Cd) 50.3 50 101ug/L -12575150.3 Cobalt (Co) 49.2 50 98ug/L -12575149.2 Lead (Pb) 50 50 100ug/L -12575150 Selenium (Se) 48.7 50 96.3ug/L -12575148.7 Thallium (Tl) Low Level 48.3 50 96.6ug/L -12575148.3 Vanadium (V) Low Level 54.8 50 101ug/L -12575154.8 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007750 Antimony (Sb) 50.7 50 101 0.617ug/L -12575150.7 Arsenic (As) 53.2 50 101 0.13ug/L -12575153.2 Beryllium (Be) 51.2 50 102 2.99ug/L -12575151.2 Cadmium (Cd) 50.4 50 101 0.117ug/L -12575150.4 Page 13 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030231 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030216 -- 2017007750 Cobalt (Co) 49.4 50 98.4 0.399ug/L -12575149.4 Lead (Pb) 50.2 50 100 0.244ug/L -12575150.2 Selenium (Se) 49.2 50 97.3 1.04ug/L -12575149.2 Thallium (Tl) Low Level 48.3 50 96.6 0.0228ug/L -12575148.3 Vanadium (V) Low Level 55.1 50 101 0.547ug/L -12575155.1 Page 14 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030216 Q17030281 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17020369 -- 2017005137 TDS 230 0.866mg/L -1230 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17020369 -- 2017005138 TDS 61 3.33mg/L -161 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 95 100 95mg/L -11090195 Page 15 of 16 Page 16 of 16 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17030289 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:3/27/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017008140 Sutton 09-Mar-17 2:48 PM Plant Personell DMW-2 2017008141 Sutton 09-Mar-17 9:51 AM Plant Personell BMW-1 2017008142 Sutton 09-Mar-17 12:21 PM Plant Personell DMW-1 3 Total Samples Page 2 of 14 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:3/27/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 2017008140 Collection Date:09-Mar-17 2:48 PM Site:DMW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.4 mg/L EPA 9056A 03/10/2017 15:04 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/10/2017 15:04 BGN90340.1 1 Nitrate 14 mg/L EPA 9056A 03/10/2017 15:04 BGN90340.5 5 Nitrate as N 3.1 mg-N/L EPA 9056A 03/10/2017 15:04 BGN90340.023 1 Sulfate 3.1 mg/L EPA 9056A 03/10/2017 15:04 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/24/2017 13:30 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.020 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:48 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Iron (Fe)0.337 mg/L SW 6010D 03/14/2017 10:48 MHH71310.01 1 Manganese (Mn)0.038 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:48 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 19:02 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 19:02 CWSPEN30.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 03/14/2017 19:02 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 97 mg/L SM2540C 03/15/2017 15:00 MGIGANT251 Page 4 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 2017008141 Collection Date:09-Mar-17 9:51 AM Site:BMW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 7.9 mg/L EPA 9056A 03/10/2017 14:33 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 03/10/2017 14:33 BGN90340.1 1 Nitrate 22 mg/L EPA 9056A 03/10/2017 14:33 BGN9034110 Nitrate as N 4.9 mg-N/L EPA 9056A 03/10/2017 14:33 BGN90340.023 1 Sulfate 51 mg/L EPA 9056A 03/10/2017 14:33 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/24/2017 13:33 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.072 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:52 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Iron (Fe)0.089 mg/L SW 6010D 03/14/2017 10:52 MHH71310.01 1 Manganese (Mn)0.029 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:52 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 19:09 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 19:09 CWSPEN30.2 1 Vanadium (V) Low Level 0.304 ug/L SW 6020B 03/14/2017 19:09 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 69 mg/L SM2540C 03/15/2017 15:00 MGIGANT251 Page 5 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 2017008142 Collection Date:09-Mar-17 12:21 PM Site:DMW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 10 mg/L EPA 9056A 03/10/2017 14:49 BGN9034110 Fluoride < 0.1 mg/L EPA 9056A 03/10/2017 14:49 BGN90340.1 1 Nitrate 21 mg/L EPA 9056A 03/10/2017 14:49 BGN9034110 Nitrate as N 4.7 mg-N/L EPA 9056A 03/10/2017 14:49 BGN90340.023 1 Sulfate 2.2 mg/L EPA 9056A 03/10/2017 14:49 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 03/24/2017 13:35 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.057 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 03/14/2017 10:56 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Iron (Fe)0.153 mg/L SW 6010D 03/14/2017 10:56 MHH71310.01 1 Manganese (Mn)0.015 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 03/14/2017 10:56 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 03/14/2017 19:16 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 03/14/2017 19:16 CWSPEN30.2 1 Vanadium (V) Low Level 1.53 ug/L SW 6020B 03/14/2017 19:16 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 100 mg/L SM2540C 03/15/2017 15:00 MGIGANT251 Page 6 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030266 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0344 mg/L -10.0344 0.1 < 1/2 RDL Fluoride 0.0191 mg/L -10.0191 0.1 < 1/2 RDL Nitrate 0.0215 mg/L -10.0215 0.1 < 1/2 RDL Sulfate -0.0286 mg/L -1-0.0286 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 5.57 50 102mg/L -120801055.7 Fluoride 4.91 50 97.9mg/L -120801049.1 Nitrate 6.49 50 101mg/L -120801064.9 Sulfate 5.4 50 100mg/L -120801054 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 5.59 50 103 0.374mg/L -120801055.9 Fluoride 4.92 50 98 0.0592mg/L -120801049.2 Nitrate 6.52 50 101 0.633mg/L -120801065.2 Sulfate 5.41 50 100 0.176mg/L -120801054 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 5.11 5 102mg/L -1208015.11 Fluoride 5.16 5 103mg/L -1208015.16 Nitrate 5.12 5 102mg/L -1208015.12 Sulfate 5.15 5 103mg/L -1208015.15 Page 7 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030622 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.003 ug/L -1-0.003 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) -0.008 ug/L -1-0.008 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.92 2 96ug/L -1158511.92 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.84 2 92ug/L -1158511.84 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030217 -- 2017007757 Mercury (Hg) 0.952 1 95.7ug/L -1257510.952 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030217 -- 2017007757 Mercury (Hg) 0.953 1 95.8 0.104ug/L -1257510.953 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030267 -- 2017008002 Mercury (Hg) 0.941 1 94.2ug/L -1257510.941 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030267 -- 2017008002 Mercury (Hg) 0.939 1 94 0.213ug/L -1257510.939 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17030290 -- 2017008143 Mercury (Hg) 0.901 1 90.5ug/L -1257510.901 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17030290 -- 2017008143 Mercury (Hg) 0.915 1 91.9 1.54ug/L -1257510.915 Page 8 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030299 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) 0.0005 mg/L -10.0005 0.005 < 1/2 RDL Boron (B) 0.000057 mg/L -10.000057 0.05 < 1/2 RDL Chromium (Cr) -0.00029 mg/L -1-0.00029 0.005 < 1/2 RDL Copper (Cu) -0.000444 mg/L -1-0.000444 0.005 < 1/2 RDL Iron (Fe) -0.00003 mg/L -1-0.00003 0.01 < 1/2 RDL Manganese (Mn) -0.000335 mg/L -1-0.000335 0.005 < 1/2 RDL Nickel (Ni) -0.00033 mg/L -1-0.00033 0.005 < 1/2 RDL Silver (Ag) -0.000015 mg/L -1-0.000015 0.005 < 1/2 RDL Zinc (Zn) -0.000308 mg/L -1-0.000308 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.08 5 102mg/L -1208015.08 Boron (B) 5.02 5 100mg/L -1208015.02 Chromium (Cr) 5.07 5 101mg/L -1208015.07 Copper (Cu) 5.03 5 101mg/L -1208015.03 Iron (Fe) 5.11 5 102mg/L -1208015.11 Manganese (Mn) 5.1 5 102mg/L -1208015.1 Nickel (Ni) 5.13 5 103mg/L -1208015.13 Silver (Ag) 0.488 0.5 97.6mg/L -1208010.488 Zinc (Zn) 5.14 5 103mg/L -1208015.14 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Barium (Ba) 5.01 5 100mg/L -1257515.01 Boron (B) 4.98 5 98.7mg/L -1257514.98 Chromium (Cr) 5.02 5 100mg/L -1257515.02 Copper (Cu) 4.94 5 98.8mg/L -1257514.94 Iron (Fe) 7.54 5 99mg/L -1257517.54 Manganese (Mn) 5.07 5 101mg/L -1257515.07 Nickel (Ni) 5.08 5 102mg/L -1257515.08 Silver (Ag) 0.482 0.5 96.3mg/L -1257510.482 Zinc (Zn) 5.1 5 102mg/L -1257515.1 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Barium (Ba) 4.97 5 99.3 0.822mg/L -1257514.97 Boron (B) 4.91 5 97.4 1.33mg/L -1257514.91 Chromium (Cr) 4.96 5 99.2 1.16mg/L -1257514.96 Copper (Cu) 4.89 5 97.9 0.875mg/L -1257514.89 Page 9 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030299 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007141 Iron (Fe) 7.4 5 96.3 2.75mg/L -1257517.4 Manganese (Mn) 5.02 5 99.9 1.02mg/L -1257515.02 Nickel (Ni) 5.03 5 101 0.95mg/L -1257515.03 Silver (Ag) 0.477 0.5 95.3 1.05mg/L -1257510.477 Zinc (Zn) 5.04 5 101 1.15mg/L -1257515.04 Page 10 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030306 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) -0.051 ug/L -1-0.051 1 < 1/2 RDL Arsenic (As) 0.011 ug/L -10.011 1 < 1/2 RDL Beryllium (Be) 0.006 ug/L -10.006 1 < 1/2 RDL Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL Cobalt (Co) 0 ug/L -10 1 < 1/2 RDL Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL Selenium (Se) -0.007 ug/L -1-0.007 1 < 1/2 RDL Thallium (Tl) Low Level -0.014 ug/L -1-0.014 0.2 < 1/2 RDL Vanadium (V) Low Level 0.033 ug/L -10.033 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 50.3 50 101ug/L -12080150.3 Arsenic (As) 50.6 50 101ug/L -12080150.6 Beryllium (Be) 50.4 50 101ug/L -12080150.4 Cadmium (Cd) 50.4 50 101ug/L -12080150.4 Cobalt (Co) 48.9 50 97.7ug/L -12080148.9 Lead (Pb) 50.3 50 101ug/L -12080150.3 Selenium (Se) 47.8 50 95.6ug/L -12080147.8 Thallium (Tl) Low Level 47.6 50 95.1ug/L -12080147.6 Vanadium (V) Low Level 50 50 99.9ug/L -12080150 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Antimony (Sb) 50.5 50 101ug/L -12575150.5 Arsenic (As) 51.1 50 101ug/L -12575151.1 Beryllium (Be) 51.9 50 104ug/L -12575151.9 Cadmium (Cd) 50.2 50 100ug/L -12575150.2 Cobalt (Co) 50.1 50 97.1ug/L -12575150.1 Lead (Pb) 50.4 50 101ug/L -12575150.4 Selenium (Se) 48.3 50 96.5ug/L -12575148.3 Thallium (Tl) Low Level 48.1 50 96.1ug/L -12575148.1 Vanadium (V) Low Level 50.9 50 100ug/L -12575150.9 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Antimony (Sb) 50.5 50 101 0.115ug/L -12575150.5 Arsenic (As) 50.8 50 101 0.524ug/L -12575150.8 Beryllium (Be) 53.1 50 106 2.12ug/L -12575153.1 Cadmium (Cd) 49.8 50 99.4 0.887ug/L -12575149.8 Page 11 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030306 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030090 -- 2017007996 Cobalt (Co) 49.9 50 96.7 0.39ug/L -12575149.9 Lead (Pb) 50.2 50 100 0.32ug/L -12575150.2 Selenium (Se) 47.8 50 95.6 0.951ug/L -12575147.8 Thallium (Tl) Low Level 48.9 50 97.7 1.69ug/L -12575148.9 Vanadium (V) Low Level 51.3 50 101 0.781ug/L -12575151.3 Page 12 of 14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17030289 Q17030355 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17020369 -- 2017005134 TDS 103 2.87mg/L -1103 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17020369 -- 2017005135 TDS 290 1.04mg/L -1290 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J17020369 -- 2017005136 TDS 381 0.263mg/L -1381 Final QualifierDilMeasuredUnits:Parameter Duplicate # 4 RPD Parent Sample: J17020369 -- 2017005139 TDS 338 0.59mg/L -1338 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 98 100 98mg/L -11090198 Page 13 of 14 Page 14 of 14 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17040090 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:4/20/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017011211 Sutton 04-Apr-17 11:28 AM Plant Personell BMW-1 2017011213 Sutton 04-Apr-17 3:28 PM Plant Personell BMW-3 2 Total Samples Page 2 of 16 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Peggy Kendall Date:4/20/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 2017011211 Collection Date:04-Apr-17 11:28 AM Site:BMW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 7.7 mg/L EPA 9056A 04/05/2017 12:18 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/05/2017 12:18 BGN90340.1 1 Nitrate 16 mg/L EPA 9056A 04/05/2017 12:18B2 BGN9034110 Nitrate as N 3.6 mg-N/L EPA 9056A 04/05/2017 12:18B2 BGN90340.023 1 Sulfate 79 mg/L EPA 9056A 04/05/2017 12:18 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:26 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.072 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/07/2017 09:25 MHALL30.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Iron (Fe)0.025 mg/L SW 6010D 04/07/2017 09:25 MHALL30.01 1 Manganese (Mn)0.025 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 Zinc (Zn)0.006 mg/L SW 6010D 04/07/2017 09:25 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Cobalt (Co)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 04/07/2017 14:05 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/07/2017 14:05 CWSPEN30.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 04/07/2017 14:05 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 120 mg/L SM2540C 04/06/2017 15:00 MGIGANT251 Page 4 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 2017011213 Collection Date:04-Apr-17 3:28 PM Site:BMW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.7 mg/L EPA 9056A 04/05/2017 11:44 BGN90340.1 1 Fluoride 0.14 mg/L EPA 9056A 04/05/2017 11:44 BGN90340.1 1 Nitrate 0.35 mg/L EPA 9056A 04/05/2017 11:44B2 BGN90340.1 1 Nitrate as N 0.08 mg-N/L EPA 9056A 04/05/2017 11:44B2 BGN90340.023 1 Sulfate 7.7 mg/L EPA 9056A 04/05/2017 11:44 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:29 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.016 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/07/2017 09:37 MHALL30.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Iron (Fe)0.218 mg/L SW 6010D 04/07/2017 09:37 MHALL30.01 1 Manganese (Mn)0.065 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 Zinc (Zn)0.005 mg/L SW 6010D 04/07/2017 09:37 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Arsenic (As)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Beryllium (Be)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Cobalt (Co)1.43 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 04/07/2017 13:34 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/07/2017 13:34 CWSPEN30.2 1 Vanadium (V) Low Level 0.737 ug/L SW 6020B 04/07/2017 13:34 CWSPEN30.3 1 TOTAL DISSOLVED SOLIDS TDS 28 mg/L SM2540C 04/06/2017 15:00 MGIGANT251 Nitrate/Nitrate as N B3: Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Qualifiers: B2 Target analyte was detected in Method Blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. Page 5 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040066 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0186 mg/L -10.0186 0.1 < 1/2 RDL Fluoride -0.0049 mg/L -1-0.0049 0.1 < 1/2 RDL Nitrate 0.0621 mg/L -10.0621 0.1 > 1/2 RDL Sulfate -0.0439 mg/L -1-0.0439 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 6.19 5 99.3mg/L -1208016.19 Fluoride 5.66 5 113mg/L -1208015.66 Nitrate 6.53 5 106mg/L -1208016.53 Sulfate 5.3 5 95mg/L -1208015.3 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 6.21 5 99.5 0.251mg/L -1208016.21 Fluoride 5.68 5 113 0.446mg/L -1208015.68 Nitrate 6.47 5 105 1.17mg/L -1208016.47 Sulfate 5.26 5 94.4 0.699mg/L -1208015.26 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Chloride 10.1 100 105mg/L -1208020203 Fluoride 100mg/L -120801Not Tested Nitrate 5.23 100 103mg/L -1208020105 Sulfate 6.07 100 105mg/L -1208020121 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Chloride 10.1 100 105 0.21mg/L -1208020202 Fluoride 100mg/L -120801Not Tested Nitrate 5.23 100 103 0mg/L -1208020105 Sulfate 6.08 100 105 0.0931mg/L -1208020122 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 5.38 5 108mg/L -1109015.38 Fluoride 5.17 5 103mg/L -1109015.17 Nitrate 5.36 5 107mg/L -1109015.36 Sulfate 5.32 5 106mg/L -1109015.32 Page 6 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040158 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.99 2 99.3ug/L -1158511.99 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.85 2 92.6ug/L -1158511.85 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030469 -- 2017009210 Mercury (Hg) 0.953 1 95.6ug/L -1257510.953 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030469 -- 2017009210 Mercury (Hg) 0.955 1 95.8 0.209ug/L -1257510.955 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030500 -- 2017009355 Mercury (Hg) 0.625 1 53.8ug/L -1257510.625 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030500 -- 2017009355 Mercury (Hg) 0.647 1 56 4.01ug/L -1257510.647 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17030537 -- 2017009506 Mercury (Hg) 0.953 1 94.2ug/L -1257510.953 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17030537 -- 2017009506 Mercury (Hg) 0.938 1 92.7 1.61ug/L -1257510.938 Page 7 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040158 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 4 % Recovery LCL UCLSpike Parent Sample: J17030078 -- 2017007056 Mercury (Hg) 0.918 1 91.8ug/L -1257510.918 Final QualifierDilMeasuredUnits:Parameter MSD # 4 RPD% Recovery LCL UCLSpike Parent Sample: J17030078 -- 2017007056 Mercury (Hg) 0.937 1 93.7 2.05ug/L -1257510.937 Page 8 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040103 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.000239 mg/L -1-0.000239 0.005 < 1/2 RDL Boron (B) -0.000669 mg/L -1-0.000669 0.05 < 1/2 RDL Chromium (Cr) -0.000346 mg/L -1-0.000346 0.005 < 1/2 RDL Copper (Cu) 0.000131 mg/L -10.000131 0.005 < 1/2 RDL Iron (Fe) 0.000334 mg/L -10.000334 0.01 < 1/2 RDL Manganese (Mn) -0.000114 mg/L -1-0.000114 0.005 < 1/2 RDL Nickel (Ni) -0.000138 mg/L -1-0.000138 0.005 < 1/2 RDL Silver (Ag) -0.000008 mg/L -1-0.000008 0.005 < 1/2 RDL Zinc (Zn) 0.00002 mg/L -10.00002 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Barium (Ba) -0.000144 mg/L -1-0.000144 0.005 < 1/2 RDL Boron (B) -0.00198 mg/L -1-0.00198 0.05 < 1/2 RDL Chromium (Cr) -0.00002 mg/L -1-0.00002 0.005 < 1/2 RDL Copper (Cu) 0.000137 mg/L -10.000137 0.005 < 1/2 RDL Iron (Fe) 0.000406 mg/L -10.000406 0.01 < 1/2 RDL Manganese (Mn) -0.00006 mg/L -1-0.00006 0.005 < 1/2 RDL Nickel (Ni) 0.000013 mg/L -10.000013 0.005 < 1/2 RDL Silver (Ag) -0.000021 mg/L -1-0.000021 0.005 < 1/2 RDL Zinc (Zn) 0.000218 mg/L -10.000218 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.06 5 101mg/L -1208015.06 Boron (B) 4.95 5 98.9mg/L -1208014.95 Chromium (Cr) 4.99 5 99.9mg/L -1208014.99 Copper (Cu) 5.01 5 100mg/L -1208015.01 Iron (Fe) 5.03 5 101mg/L -1208015.03 Manganese (Mn) 5.04 5 101mg/L -1208015.04 Nickel (Ni) 5.07 5 101mg/L -1208015.07 Silver (Ag) 0.507 0.5 101mg/L -1208010.507 Zinc (Zn) 5.03 5 101mg/L -1208015.03 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Barium (Ba) 4.99 5 99.8mg/L -1208014.99 Boron (B) 4.86 5 97.2mg/L -1208014.86 Chromium (Cr) 4.9 5 98mg/L -1208014.9 Copper (Cu) 4.97 5 99.4mg/L -1208014.97 Page 9 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040103 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Iron (Fe) 4.96 5 99.2mg/L -1208014.96 Manganese (Mn) 5 5 100mg/L -1208015 Nickel (Ni) 5.04 5 101mg/L -1208015.04 Silver (Ag) 0.49 0.5 98.1mg/L -1208010.49 Zinc (Zn) 5 5 99.9mg/L -1208015 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040090 -- 2017011211 Barium (Ba) 5.18 5 102mg/L -1257515.18 Boron (B) 5.05 5 100mg/L -1257515.05 Chromium (Cr) 5.01 5 100mg/L -1257515.01 Copper (Cu) 5.05 5 101mg/L -1257515.05 Iron (Fe) 5.08 5 101mg/L -1257515.08 Manganese (Mn) 5.1 5 101mg/L -1257515.1 Nickel (Ni) 5.07 5 101mg/L -1257515.07 Silver (Ag) 0.505 0.5 101mg/L -1257510.505 Zinc (Zn) 5.03 5 101mg/L -1257515.03 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040090 -- 2017011211 Barium (Ba) 4.98 5 98.1 3.98mg/L -1257514.98 Boron (B) 4.81 5 95.4 5.01mg/L -1257514.81 Chromium (Cr) 4.81 5 96.2 4.13mg/L -1257514.81 Copper (Cu) 4.83 5 96.6 4.41mg/L -1257514.83 Iron (Fe) 4.87 5 96.9 4.2mg/L -1257514.87 Manganese (Mn) 4.9 5 97.5 4mg/L -1257514.9 Nickel (Ni) 4.85 5 97 4.37mg/L -1257514.85 Silver (Ag) 0.486 0.5 97.1 3.84mg/L -1257510.486 Zinc (Zn) 4.83 5 96.5 4.08mg/L -1257514.83 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17040097 -- 2017011245 Barium (Ba) 5.14 5 102mg/L -1257515.14 Boron (B) 4.96 5 99mg/L -1257514.96 Chromium (Cr) 5.01 5 100mg/L -1257515.01 Copper (Cu) 5.08 5 101mg/L -1257515.08 Iron (Fe) 7.86 5 98.6mg/L -1257517.86 Manganese (Mn) 5.17 5 102mg/L -1257515.17 Nickel (Ni) 5.09 5 102mg/L -1257515.09 Silver (Ag) 0.501 0.5 100mg/L -1257510.501 Page 10 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040103 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17040097 -- 2017011245 Zinc (Zn) 5.04 5 101mg/L -1257515.04 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17040097 -- 2017011245 Barium (Ba) 4.65 5 92.4 10.1mg/L -1257514.65 Boron (B) 4.59 5 91.7 7.63mg/L -1257514.59 Chromium (Cr) 4.52 5 90.5 10.2mg/L -1257514.52 Copper (Cu) 4.58 5 91.6 10.2mg/L -1257514.58 Iron (Fe) 7.39 5 89.1 10.1mg/L -1257517.39 Manganese (Mn) 4.68 5 92.1 10mg/L -1257514.68 Nickel (Ni) 4.6 5 91.9 10.1mg/L -1257514.6 Silver (Ag) 0.463 0.5 92.5 8.03mg/L -1257510.463 Zinc (Zn) 4.56 5 91.1 9.99mg/L -1257514.56 Page 11 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040109 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) -0.032 ug/L -1-0.032 1 < 1/2 RDL Arsenic (As) 0.041 ug/L -10.041 1 < 1/2 RDL Beryllium (Be) 0.115 ug/L -10.115 1 < 1/2 RDL Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL Cobalt (Co) 0.004 ug/L -10.004 1 < 1/2 RDL Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL Selenium (Se) 0.008 ug/L -10.008 1 < 1/2 RDL Thallium (Tl) Low Level -0.028 ug/L -1-0.028 0.2 < 1/2 RDL Vanadium (V) Low Level 0.054 ug/L -10.054 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Antimony (Sb) -0.026 ug/L -1-0.026 1 < 1/2 RDL Arsenic (As) 0.029 ug/L -10.029 1 < 1/2 RDL Beryllium (Be) 0.029 ug/L -10.029 1 < 1/2 RDL Cadmium (Cd) 0.009 ug/L -10.009 1 < 1/2 RDL Cobalt (Co) 0.013 ug/L -10.013 1 < 1/2 RDL Lead (Pb) 0.01 ug/L -10.01 1 < 1/2 RDL Selenium (Se) 0.002 ug/L -10.002 1 < 1/2 RDL Thallium (Tl) Low Level -0.029 ug/L -1-0.029 0.2 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 49.8 50 99.7ug/L -12080149.8 Arsenic (As) 48.3 50 96.7ug/L -12080148.3 Beryllium (Be) 50.9 50 102ug/L -12080150.9 Cadmium (Cd) 49.5 50 99ug/L -12080149.5 Cobalt (Co) 48.3 50 96.6ug/L -12080148.3 Lead (Pb) 48.9 50 97.8ug/L -12080148.9 Selenium (Se) 48 50 96ug/L -12080148 Thallium (Tl) Low Level 49.8 50 99.7ug/L -12080149.8 Vanadium (V) Low Level 49.7 50 99.4ug/L -12080149.7 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Antimony (Sb) 51.7 50 103ug/L -12080151.7 Arsenic (As) 51.1 50 102ug/L -12080151.1 Beryllium (Be) 54.5 50 109ug/L -12080154.5 Cadmium (Cd) 51.4 50 103ug/L -12080151.4 Cobalt (Co) 51 50 102ug/L -12080151 Page 12 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040109 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Lead (Pb) 50.3 50 101ug/L -12080150.3 Selenium (Se) 47.5 50 95.1ug/L -12080147.5 Thallium (Tl) Low Level 50.1 50 100ug/L -12080150.1 Vanadium (V) Low Level 50ug/L -120801Not Tested Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040090 -- 2017011213 Antimony (Sb) 49 50 98ug/L -12575149 Arsenic (As) 47.9 50 95.3ug/L -12575147.9 Beryllium (Be) 51.6 50 103ug/L -12575151.6 Cadmium (Cd) 49.1 50 98ug/L -12575149.1 Cobalt (Co) 49.2 50 95.5ug/L -12575149.2 Lead (Pb) 49.2 50 98ug/L -12575149.2 Selenium (Se) 47.5 50 95ug/L -12575147.5 Thallium (Tl) Low Level 50.4 50 101ug/L -12575150.4 Vanadium (V) Low Level 50.5 50 99.6ug/L -12575150.5 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040090 -- 2017011213 Antimony (Sb) 47.7 50 95.3 2.72ug/L -12575147.7 Arsenic (As) 46.2 50 91.9 3.61ug/L -12575146.2 Beryllium (Be) 49.2 50 98.1 4.8ug/L -12575149.2 Cadmium (Cd) 47.2 50 94.4 3.8ug/L -12575147.2 Cobalt (Co) 47.8 50 92.7 3.02ug/L -12575147.8 Lead (Pb) 47.6 50 94.8 3.28ug/L -12575147.6 Selenium (Se) 45.8 50 91.5 3.71ug/L -12575145.8 Thallium (Tl) Low Level 49.2 50 98.4 2.45ug/L -12575149.2 Vanadium (V) Low Level 48.5 50 95.6 4.12ug/L -12575148.5 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17040097 -- 2017011246 Antimony (Sb) 50.2 50 100ug/L -12575150.2 Arsenic (As) 48.6 50 97.1ug/L -12575148.6 Beryllium (Be) 53.9 50 108ug/L -12575153.9 Cadmium (Cd) 49 50 97.9ug/L -12575149 Cobalt (Co) 47.6 50 95.2ug/L -12575147.6 Lead (Pb) 48.6 50 97.2ug/L -12575148.6 Selenium (Se) 47.1 50 94.1ug/L -12575147.1 Thallium (Tl) Low Level 49.4 50 98.8ug/L -12575149.4 Vanadium (V) Low Level 50ug/L -125751Not Tested Page 13 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040109 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17040097 -- 2017011246 Antimony (Sb) 47.1 50 94.1 6.3ug/L -12575147.1 Arsenic (As) 45.6 50 91.1 6.37ug/L -12575145.6 Beryllium (Be) 50.1 50 100 7.25ug/L -12575150.1 Cadmium (Cd) 45.4 50 90.8 7.56ug/L -12575145.4 Cobalt (Co) 44.7 50 89.4 6.34ug/L -12575144.7 Lead (Pb) 45.5 50 91 6.6ug/L -12575145.5 Selenium (Se) 44.3 50 88.5 6.17ug/L -12575144.3 Thallium (Tl) Low Level 46.6 50 93.2 5.8ug/L -12575146.6 Vanadium (V) Low Level 50ug/L -125751Not Tested Page 14 of 16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040090 Q17040100 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17030093 -- 2017007155 TDS 199 0.504mg/L -1199 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17030149 -- 2017007395 TDS 234 1.27mg/L -1234 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J17030335 -- 2017008415 TDS 358 0.834mg/L -1358 Final QualifierDilMeasuredUnits:Parameter Duplicate # 4 RPD Parent Sample: J17030335 -- 2017008416 TDS 138 2.86mg/L -1138 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 104 100 104mg/L -110901104 Page 15 of 16 P a g e 1 6 o f 1 6 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17040152 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:4/21/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: The nitrate, fluoride, and chloride analysis for BMW4 was run 4-6 at 17:25. The sulfate analysis for BMW4 was run 4/7 at 23:57. The LIMS system only allows one date/time to be entered for the test code. So, the last date/time run is entered. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017011537 Sutton 05-Apr-17 2:00 PM Ashley Booth BMW-4 2017011545 Sutton 05-Apr-17 2:30 PM Ashley Booth DMW-3 2017011546 Sutton 05-Apr-17 5:12 PM Ashley Booth DMW-4 3 Total Samples Page 2 of 15 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Peggy Kendall Date:4/21/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 2017011537 Collection Date:05-Apr-17 2:00 PM Site:BMW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.0 mg/L EPA 9056A 04/07/2017 23:57 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/07/2017 23:57 BGN90340.1 1 Nitrate 1.8 mg/L EPA 9056A 04/07/2017 23:57 BGN90340.1 1 Nitrate as N 0.39 mg-N/L EPA 9056A 04/07/2017 23:57 BGN90340.023 1 Sulfate 11 mg/L EPA 9056A 04/07/2017 23:57N1 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/18/2017 12:41 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:06 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Iron (Fe)0.026 mg/L SW 6010D 04/11/2017 12:06 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:06 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 17:39 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 17:39 PARMSTR0.2 1 Vanadium (V) Low Level 0.659 ug/L SW 6020B 04/11/2017 17:39 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 120 mg/L SM2540C 04/11/2017 15:00 MGIGANT251 Page 4 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 2017011545 Collection Date:05-Apr-17 2:30 PM Site:DMW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.4 mg/L EPA 9056A 04/06/2017 20:01 BGN90340.1 1 Fluoride 0.10 mg/L EPA 9056A 04/06/2017 20:01 BGN90340.1 1 Nitrate 0.19 mg/L EPA 9056A 04/06/2017 20:01 BGN90340.1 1 Nitrate as N 0.05 mg-N/L EPA 9056A 04/06/2017 20:01 BGN90340.023 1 Sulfate 13 mg/L EPA 9056A 04/06/2017 20:01N1 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/18/2017 13:17 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.006 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:18 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Iron (Fe)0.021 mg/L SW 6010D 04/11/2017 12:18 MHH71310.01 1 Manganese (Mn)0.043 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:18 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 17:10 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 17:10 PARMSTR0.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 04/11/2017 17:10 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 26 mg/L SM2540C 04/11/2017 15:00 MGIGANT251 Page 5 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 2017011546 Collection Date:05-Apr-17 5:12 PM Site:DMW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.4 mg/L EPA 9056A 04/06/2017 20:19 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/06/2017 20:19 BGN90340.1 1 Nitrate 11 mg/L EPA 9056A 04/06/2017 20:19 BGN90340.5 5 Nitrate as N 2.5 mg-N/L EPA 9056A 04/06/2017 20:19 BGN90340.023 1 Sulfate 12 mg/L EPA 9056A 04/06/2017 20:19N1 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/18/2017 13:25 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.037 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:22 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Iron (Fe)0.036 mg/L SW 6010D 04/11/2017 12:22 MHH71310.01 1 Manganese (Mn)0.061 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 Zinc (Zn)0.006 mg/L SW 6010D 04/11/2017 12:22 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 17:47 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 17:47 PARMSTR0.2 1 Vanadium (V) Low Level 0.471 ug/L SW 6020B 04/11/2017 17:47 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 71 mg/L SM2540C 04/11/2017 15:00 MGIGANT251 N1: The IS#2 sulfate recovery (78.6%) fell below the QC limit (80-120%). The associated Laboratory Control Spike (LCS) was acceptable. Qualifiers: N1 See additional information listed below. Page 6 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040111 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0252 mg/L -10.0252 0.1 < 1/2 RDL Fluoride 0 mg/L -10 0.1 < 1/2 RDL Nitrate 0.0416 mg/L -10.0416 0.1 < 1/2 RDL Sulfate -0.0364 mg/L -1-0.0364 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 7.33 25 104mg/L -12080536.6 Fluoride 4.89 25 97.3mg/L -12080524.5 Nitrate 6.32 25 108mg/L -12080531.6 Sulfate 8.62 25 101mg/L -12080543.1 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 7.32 25 104 0.0772mg/L -12080536.6 Fluoride 4.91 25 97.6 0.351mg/L -12080524.5 Nitrate 6.29 25 107 0.557mg/L -12080531.5 Sulfate 8.63 25 102 0.223mg/L -12080543.1 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Chloride 6 50 109mg/L -120801060 Fluoride 5.4 50 108mg/L -120801054 Nitrate 5.43 50 107mg/L -120801054.3 Sulfate 5.97 50 78.6mg/L -120801059.7 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Chloride 6.05 50 110 0.982mg/L -120801060.5 Fluoride 5.53 50 110 2.41mg/L -120801055.3 Nitrate 5.5 50 109 1.24mg/L -120801055 Sulfate 6.05 50 80.1 1.86mg/L -120801060.5 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 5.09 5 102mg/L -1208015.09 Fluoride 5.16 5 103mg/L -1208015.16 Nitrate 5.02 5 102mg/L -1208015.12 Sulfate 5.03 5 101mg/L -1208015.03 Page 7 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040410 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.011 ug/L -10.011 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Mercury (Hg) 0.013 ug/L -10.013 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 2.11 2 105ug/L -1158512.11 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.98 2 99ug/L -1158511.98 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17030697 -- 2017010461 Mercury (Hg) 1.05 1 104ug/L -1257511.05 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17030697 -- 2017010461 Mercury (Hg) 1.04 1 103 0.867ug/L -1257511.04 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030746 -- 2017010660 Mercury (Hg) 1.01 1 99.8ug/L -1257511.01 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030746 -- 2017010660 Mercury (Hg) 1.03 1 102 1.79ug/L -1257511.03 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Mercury (Hg) 1.01 1 99.4ug/L -1257511.01 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Mercury (Hg) 1 1 98.2 1.21ug/L -1257511 Page 8 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040410 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 4 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Mercury (Hg) 0.995 1 98ug/L -1257510.995 Final QualifierDilMeasuredUnits:Parameter MSD # 4 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Mercury (Hg) 0.988 1 97.3 0.717ug/L -1257510.988 Page 9 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.000288 mg/L -1-0.000288 0.005 < 1/2 RDL Boron (B) 0.000657 mg/L -10.000657 0.05 < 1/2 RDL Chromium (Cr) -0.000192 mg/L -1-0.000192 0.005 < 1/2 RDL Copper (Cu) 0.000159 mg/L -10.000159 0.005 < 1/2 RDL Iron (Fe) 0.00156 mg/L -10.00156 0.01 < 1/2 RDL Manganese (Mn) 0.00002 mg/L -10.00002 0.005 < 1/2 RDL Nickel (Ni) 0.000013 mg/L -10.000013 0.005 < 1/2 RDL Silver (Ag) -0.00013 mg/L -1-0.00013 0.005 < 1/2 RDL Zinc (Zn) 0.000062 mg/L -10.000062 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.08 5 102mg/L -1208015.08 Boron (B) 5 5 99.9mg/L -1208015 Chromium (Cr) 5.03 5 101mg/L -1208015.03 Copper (Cu) 4.98 5 99.6mg/L -1208014.98 Iron (Fe) 4.97 5 99.4mg/L -1208014.97 Manganese (Mn) 5.01 5 100mg/L -1208015.01 Nickel (Ni) 5.01 5 100mg/L -1208015.01 Silver (Ag) 0.504 0.5 101mg/L -1208010.504 Zinc (Zn) 4.97 5 99.3mg/L -1208014.97 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Barium (Ba) 5.08 5 102mg/L -1257515.08 Boron (B) 5.02 5 100mg/L -1257515.02 Chromium (Cr) 4.97 5 99.5mg/L -1257514.97 Copper (Cu) 4.92 5 98.5mg/L -1257514.92 Iron (Fe) 4.94 5 98.3mg/L -1257514.94 Manganese (Mn) 4.95 5 99.1mg/L -1257514.95 Nickel (Ni) 4.91 5 98.1mg/L -1257514.91 Silver (Ag) 0.501 0.5 100mg/L -1257510.501 Zinc (Zn) 4.87 5 97.4mg/L -1257514.87 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Barium (Ba) 4.9 5 97.8 3.71mg/L -1257514.9 Boron (B) 4.77 5 95.1 5.16mg/L -1257514.77 Chromium (Cr) 4.8 5 96.1 3.46mg/L -1257514.8 Copper (Cu) 4.76 5 95.1 3.47mg/L -1257514.76 Page 10 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Iron (Fe) 4.79 5 95.3 3.12mg/L -1257514.79 Manganese (Mn) 4.79 5 95.7 3.41mg/L -1257514.79 Nickel (Ni) 4.74 5 94.7 3.51mg/L -1257514.74 Silver (Ag) 0.475 0.5 95 5.18mg/L -1257510.475 Zinc (Zn) 4.71 5 94.2 3.32mg/L -1257514.71 Page 11 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040180 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) 0.063 ug/L -10.063 1 < 1/2 RDL Arsenic (As) 0.023 ug/L -10.023 1 < 1/2 RDL Beryllium (Be) -0.023 ug/L -1-0.023 1 < 1/2 RDL Cadmium (Cd) 0.007 ug/L -10.007 1 < 1/2 RDL Cobalt (Co) -0.001 ug/L -1-0.001 1 < 1/2 RDL Lead (Pb) 0.002 ug/L -10.002 1 < 1/2 RDL Selenium (Se) 0.002 ug/L -10.002 1 < 1/2 RDL Thallium (Tl) Low Level 0.004 ug/L -10.004 0.2 < 1/2 RDL Vanadium (V) Low Level 0.077 ug/L -10.077 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 49.2 50 98.4ug/L -12080149.2 Arsenic (As) 48.5 50 97ug/L -12080148.5 Beryllium (Be) 50.8 50 102ug/L -12080150.8 Cadmium (Cd) 49.3 50 98.7ug/L -12080149.3 Cobalt (Co) 47.8 50 95.6ug/L -12080147.8 Lead (Pb) 48.5 50 97.1ug/L -12080148.5 Selenium (Se) 46.9 50 93.8ug/L -12080146.9 Thallium (Tl) Low Level 49.9 50 99.7ug/L -12080149.9 Vanadium (V) Low Level 48 50 96.1ug/L -12080148 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Antimony (Sb) 49.5 50 98.8ug/L -12575149.5 Arsenic (As) 47.8 50 95.4ug/L -12575147.8 Beryllium (Be) 51 50 102ug/L -12575151 Cadmium (Cd) 49.3 50 98.5ug/L -12575149.3 Cobalt (Co) 47.8 50 94.6ug/L -12575147.8 Lead (Pb) 48.3 50 96.5ug/L -12575148.3 Selenium (Se) 46.3 50 92.5ug/L -12575146.3 Thallium (Tl) Low Level 50.1 50 100ug/L -12575150.1 Vanadium (V) Low Level 48.2 50 95.8ug/L -12575148.2 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Antimony (Sb) 47.6 50 95 3.94ug/L -12575147.6 Arsenic (As) 46.2 50 92.2 3.42ug/L -12575146.2 Beryllium (Be) 49.9 50 99.7 2.13ug/L -12575149.9 Cadmium (Cd) 47.3 50 94.6 4.01ug/L -12575147.3 Page 12 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040180 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Cobalt (Co) 46.2 50 91.4 3.49ug/L -12575146.2 Lead (Pb) 46.9 50 93.6 2.98ug/L -12575146.9 Selenium (Se) 45.5 50 91 1.7ug/L -12575145.5 Thallium (Tl) Low Level 48.3 50 96.6 3.63ug/L -12575148.3 Vanadium (V) Low Level 46.7 50 92.8 3.23ug/L -12575146.7 Page 13 of 15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040152 Q17040227 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17030331 -- 2017008372 TDS 201 1mg/L -1201 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17030331 -- 2017008373 TDS 447 0mg/L -1447 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J17030331 -- 2017008374 TDS 421 0.715mg/L -1421 Final QualifierDilMeasuredUnits:Parameter Duplicate # 4 RPD Parent Sample: J17030331 -- 2017008375 TDS 610 0.327mg/L -1610 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 96 100 96mg/L -11090196 Page 14 of 15 Page 15 of 15 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17040200 Project Name:SUTTON - PRE-OPERATIONS SAMPLING Lab Contact:Peggy Kendall Date:4/20/2017 Customer Address: Customer Name(s):John Toepfer, Perry Waldrep Phone: 980-875-5848 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017011719 Sutton 06-Apr-17 10:57 AM Plant Personell BMW-2 2017011729 Sutton 06-Apr-17 12:43 PM Plant Personell DMW-2 2017011730 Sutton 06-Apr-17 12:43 PM Plant Personell DMW-2 Duplicate 2017011731 Sutton 06-Apr-17 12:00 PM Plant Personell FIELD BLANK 2017011732 Sutton 06-Apr-17 1:05 PM Plant Personell DMW-1 5 Total Samples Page 2 of 17 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/20/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 2017011719 Collection Date:06-Apr-17 10:57 AM Site:BMW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.8 mg/L EPA 9056A 04/07/2017 12:31 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 04/07/2017 12:31 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 04/07/2017 12:31 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2017 12:31 BGN90340.023 1 Sulfate 19 mg/L EPA 9056A 04/07/2017 12:31 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 12:45 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:26 MHH71310.05 1 Chromium (Cr)0.017 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Copper (Cu)0.006 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Iron (Fe)6.63 mg/L SW 6010D 04/11/2017 12:26 MHH71310.01 1 Manganese (Mn)0.024 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Nickel (Ni)0.011 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 Zinc (Zn)0.013 mg/L SW 6010D 04/11/2017 12:26 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Arsenic (As)2.24 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Cobalt (Co)1.50 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Lead (Pb)6.14 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 17:54 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 17:54 PARMSTR0.2 1 Vanadium (V) Low Level 15.3 ug/L SW 6020B 04/11/2017 17:54 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 230 mg/L SM2540C 04/12/2017 15:00 MGIGANT251 Page 4 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 2017011729 Collection Date:06-Apr-17 12:43 PM Site:DMW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.3 mg/L EPA 9056A 04/07/2017 12:48 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/07/2017 12:48 BGN90340.1 1 Nitrate 12 mg/L EPA 9056A 04/07/2017 12:48 BGN90340.5 5 Nitrate as N 2.8 mg-N/L EPA 9056A 04/07/2017 12:48 BGN90340.023 1 Sulfate 3.7 mg/L EPA 9056A 04/07/2017 12:48 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 12:47 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:30 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Iron (Fe)0.471 mg/L SW 6010D 04/11/2017 12:30 MHH71310.01 1 Manganese (Mn)0.028 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:30 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 18:01 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 18:01 PARMSTR0.2 1 Vanadium (V) Low Level 0.425 ug/L SW 6020B 04/11/2017 18:01 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 57 mg/L SM2540C 04/12/2017 15:00 MGIGANT251 Page 5 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 2017011730 Collection Date:06-Apr-17 12:43 PM Site:DMW-2 Duplicate Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.3 mg/L EPA 9056A 04/07/2017 13:05 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/07/2017 13:05 BGN90340.1 1 Nitrate 13 mg/L EPA 9056A 04/07/2017 13:05 BGN90340.5 5 Nitrate as N 3.0 mg-N/L EPA 9056A 04/07/2017 13:05 BGN90340.023 1 Sulfate 4.1 mg/L EPA 9056A 04/07/2017 13:05 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 12:50 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.021 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:34 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Iron (Fe)0.440 mg/L SW 6010D 04/11/2017 12:34 MHH71310.01 1 Manganese (Mn)0.028 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:34 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 18:30 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 18:30 PARMSTR0.2 1 Vanadium (V) Low Level 0.416 ug/L SW 6020B 04/11/2017 18:30 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 53 mg/L SM2540C 04/12/2017 15:00 MGIGANT251 Page 6 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 2017011731 Collection Date:06-Apr-17 12:00 PM Site:FIELD BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 9056A 04/07/2017 11:58 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 04/07/2017 11:58 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 04/07/2017 11:58 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 04/07/2017 11:58 BGN90340.023 1 Sulfate < 0.1 mg/L EPA 9056A 04/07/2017 11:58 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 12:52 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:38 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 04/11/2017 12:38 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:38 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 18:37 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 18:37 PARMSTR0.2 1 Vanadium (V) Low Level < 0.3 ug/L SW 6020B 04/11/2017 18:37 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 04/12/2017 15:00 MGIGANT251 Page 7 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 2017011732 Collection Date:06-Apr-17 1:05 PM Site:DMW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 8.3 mg/L EPA 9056A 04/07/2017 13:22 BGN90340.1 1 Fluoride 0.16 mg/L EPA 9056A 04/07/2017 13:22 BGN90340.1 1 Nitrate 17 mg/L EPA 9056A 04/07/2017 13:22 BGN90340.5 5 Nitrate as N 3.7 mg-N/L EPA 9056A 04/07/2017 13:22 BGN90340.023 1 Sulfate 1.9 mg/L EPA 9056A 04/07/2017 13:22 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 04/19/2017 12:26 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.127 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 12:42 MHH71310.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Iron (Fe)0.029 mg/L SW 6010D 04/11/2017 12:42 MHH71310.01 1 Manganese (Mn)0.024 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 12:42 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Arsenic (As)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Beryllium (Be)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Cobalt (Co)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 04/11/2017 18:44 PARMSTR11 Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 04/11/2017 18:44 PARMSTR0.2 1 Vanadium (V) Low Level 0.756 ug/L SW 6020B 04/11/2017 18:44 PARMSTR0.3 1 TOTAL DISSOLVED SOLIDS TDS 82 mg/L SM2540C 04/12/2017 15:00 MGIGANT251 Page 8 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040129 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0353 mg/L -10.0353 0.1 < 1/2 RDL Fluoride 0.0292 mg/L -10.0292 0.1 < 1/2 RDL Nitrate 0.0206 mg/L -10.0206 0.1 < 1/2 RDL Sulfate -0.0138 mg/L -1-0.0138 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 6.24 125 99.8mg/L -1208025156 Fluoride 4.97 125 99.3mg/L -1208025124 Nitrate 4.87 125 96.5mg/L -1208025122 Sulfate 9.57 125 81.2mg/L -1208025239 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 6.26 125 100 0.31mg/L -1208025156 Fluoride 4.97 125 99.4 0.0338mg/L -1208025124 Nitrate 4.92 125 97.6 1.09mg/L -1208025123 Sulfate 9.56 125 80.9 0.375mg/L -1208025239 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.96 5 99.2mg/L -1109014.96 Fluoride 5.13 5 103mg/L -1109015.13 Nitrate 4.91 5 98.2mg/L -1109014.91 Sulfate 5 5 100mg/L -1109015 Page 9 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040463 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) 0 ug/L -10 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) 0.013 ug/L -10.013 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 2.06 2 103ug/L -1158512.06 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.93 2 96.5ug/L -1158511.93 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040200 -- 2017011732 Mercury (Hg) 1.07 1 106ug/L -1257511.07 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040200 -- 2017011732 Mercury (Hg) 1.07 1 107 0.376ug/L -1257511.07 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17030324 -- 2017008323 Mercury (Hg) 0.126 1 13.7ug/L -1257510.126 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17030324 -- 2017008323 Mercury (Hg) 0.121 1 13.2 3.72ug/L -1257510.121 Final QualifierDilMeasuredUnits:Parameter MS # 3 % Recovery LCL UCLSpike Parent Sample: J17030324 -- 2017008326 Mercury (Hg) 0.175 1 17.2ug/L -1257510.175 Final QualifierDilMeasuredUnits:Parameter MSD # 3 RPD% Recovery LCL UCLSpike Parent Sample: J17030324 -- 2017008326 Mercury (Hg) 0.174 1 17.1 0.583ug/L -1257510.174 Page 10 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040463 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 4 % Recovery LCL UCLSpike Parent Sample: J17040007 -- 2017010902 Mercury (Hg) 0.987 1 97.9ug/L -1257510.987 Final QualifierDilMeasuredUnits:Parameter MSD # 4 RPD% Recovery LCL UCLSpike Parent Sample: J17040007 -- 2017010902 Mercury (Hg) 0.986 1 97.8 0.102ug/L -1257510.986 Page 11 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.000288 mg/L -1-0.000288 0.005 < 1/2 RDL Boron (B) 0.000657 mg/L -10.000657 0.05 < 1/2 RDL Chromium (Cr) -0.000192 mg/L -1-0.000192 0.005 < 1/2 RDL Copper (Cu) 0.000159 mg/L -10.000159 0.005 < 1/2 RDL Iron (Fe) 0.00156 mg/L -10.00156 0.01 < 1/2 RDL Manganese (Mn) 0.00002 mg/L -10.00002 0.005 < 1/2 RDL Nickel (Ni) 0.000013 mg/L -10.000013 0.005 < 1/2 RDL Silver (Ag) -0.00013 mg/L -1-0.00013 0.005 < 1/2 RDL Zinc (Zn) 0.000062 mg/L -10.000062 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.08 5 102mg/L -1208015.08 Boron (B) 5 5 99.9mg/L -1208015 Chromium (Cr) 5.03 5 101mg/L -1208015.03 Copper (Cu) 4.98 5 99.6mg/L -1208014.98 Iron (Fe) 4.97 5 99.4mg/L -1208014.97 Manganese (Mn) 5.01 5 100mg/L -1208015.01 Nickel (Ni) 5.01 5 100mg/L -1208015.01 Silver (Ag) 0.504 0.5 101mg/L -1208010.504 Zinc (Zn) 4.97 5 99.3mg/L -1208014.97 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Barium (Ba) 5.08 5 102mg/L -1257515.08 Boron (B) 5.02 5 100mg/L -1257515.02 Chromium (Cr) 4.97 5 99.5mg/L -1257514.97 Copper (Cu) 4.92 5 98.5mg/L -1257514.92 Iron (Fe) 4.94 5 98.3mg/L -1257514.94 Manganese (Mn) 4.95 5 99.1mg/L -1257514.95 Nickel (Ni) 4.91 5 98.1mg/L -1257514.91 Silver (Ag) 0.501 0.5 100mg/L -1257510.501 Zinc (Zn) 4.87 5 97.4mg/L -1257514.87 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Barium (Ba) 4.9 5 97.8 3.71mg/L -1257514.9 Boron (B) 4.77 5 95.1 5.16mg/L -1257514.77 Chromium (Cr) 4.8 5 96.1 3.46mg/L -1257514.8 Copper (Cu) 4.76 5 95.1 3.47mg/L -1257514.76 Page 12 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011537 Iron (Fe) 4.79 5 95.3 3.12mg/L -1257514.79 Manganese (Mn) 4.79 5 95.7 3.41mg/L -1257514.79 Nickel (Ni) 4.74 5 94.7 3.51mg/L -1257514.74 Silver (Ag) 0.475 0.5 95 5.18mg/L -1257510.475 Zinc (Zn) 4.71 5 94.2 3.32mg/L -1257514.71 Page 13 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040180 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Antimony (Sb) 0.063 ug/L -10.063 1 < 1/2 RDL Arsenic (As) 0.023 ug/L -10.023 1 < 1/2 RDL Beryllium (Be) -0.023 ug/L -1-0.023 1 < 1/2 RDL Cadmium (Cd) 0.007 ug/L -10.007 1 < 1/2 RDL Cobalt (Co) -0.001 ug/L -1-0.001 1 < 1/2 RDL Lead (Pb) 0.002 ug/L -10.002 1 < 1/2 RDL Selenium (Se) 0.002 ug/L -10.002 1 < 1/2 RDL Thallium (Tl) Low Level 0.004 ug/L -10.004 0.2 < 1/2 RDL Vanadium (V) Low Level 0.077 ug/L -10.077 0.3 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Antimony (Sb) 49.2 50 98.4ug/L -12080149.2 Arsenic (As) 48.5 50 97ug/L -12080148.5 Beryllium (Be) 50.8 50 102ug/L -12080150.8 Cadmium (Cd) 49.3 50 98.7ug/L -12080149.3 Cobalt (Co) 47.8 50 95.6ug/L -12080147.8 Lead (Pb) 48.5 50 97.1ug/L -12080148.5 Selenium (Se) 46.9 50 93.8ug/L -12080146.9 Thallium (Tl) Low Level 49.9 50 99.7ug/L -12080149.9 Vanadium (V) Low Level 48 50 96.1ug/L -12080148 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Antimony (Sb) 49.5 50 98.8ug/L -12575149.5 Arsenic (As) 47.8 50 95.4ug/L -12575147.8 Beryllium (Be) 51 50 102ug/L -12575151 Cadmium (Cd) 49.3 50 98.5ug/L -12575149.3 Cobalt (Co) 47.8 50 94.6ug/L -12575147.8 Lead (Pb) 48.3 50 96.5ug/L -12575148.3 Selenium (Se) 46.3 50 92.5ug/L -12575146.3 Thallium (Tl) Low Level 50.1 50 100ug/L -12575150.1 Vanadium (V) Low Level 48.2 50 95.8ug/L -12575148.2 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Antimony (Sb) 47.6 50 95 3.94ug/L -12575147.6 Arsenic (As) 46.2 50 92.2 3.42ug/L -12575146.2 Beryllium (Be) 49.9 50 99.7 2.13ug/L -12575149.9 Cadmium (Cd) 47.3 50 94.6 4.01ug/L -12575147.3 Page 14 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040180 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17040152 -- 2017011545 Cobalt (Co) 46.2 50 91.4 3.49ug/L -12575146.2 Lead (Pb) 46.9 50 93.6 2.98ug/L -12575146.9 Selenium (Se) 45.5 50 91 1.7ug/L -12575145.5 Thallium (Tl) Low Level 48.3 50 96.6 3.63ug/L -12575148.3 Vanadium (V) Low Level 46.7 50 92.8 3.23ug/L -12575146.7 Page 15 of 17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17040200 Q17040251 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J17030485 -- 2017009303 TDS 272 1.11mg/L -1272 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J17030485 -- 2017009304 TDS 1060 0.283mg/L -11060 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J17030485 -- 2017009305 TDS 525 0.19mg/L -1525 Final QualifierDilMeasuredUnits:Parameter Duplicate # 4 RPD Parent Sample: J17030485 -- 2017009306 TDS 460 0.217mg/L -1460 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 98 100 98mg/L -11090198 Page 16 of 17 Page 17 of 17