9209_NorthWakeSubtitleD_GWMR_DIN28107_20160914

North Wake Subtitle D Landfill
Facility Permit No. 9209-MSWLF-1996
Leachate Sampling Report
(September 2016 Sampling Event)
Wake County
Report
Prepared December 2016

5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]

December 16, 2016

Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778

Subject: September 2016 Semi-Annual Leachate Sampling Results
North Wake Subtitle D Landfill
Facility Permit No. 9209-MSWLF-1996

Dear Ms. Drummond:
CDM Smith Inc., on behalf of Wake County, is submitting an electronic copy of the September 2016
semi-annual leachate sampling results. Leachate samples were collected from the leachate sampling
station at the Wake County Subtitle D Landfill on September 14, 2016. Water quality parameters at
the time samples were collected are presented in Table 1. Shealy Environmental Services, Inc. located
in West Columbia, South Carolina, analyzed the leachate samples for North Carolina Appendix I
volatile organic compounds and metals along with biochemical oxygen demand, chemical oxygen
demand, phosphate, nitrate, and sulfate. Laboratory analytical results are provided in Appendix A. A
copy of this report will be placed in the operating record for this facility.
If you have any questions or require further explanation, do not hesitate to call me at 919-325-3500.
Very truly yours,

Mathew F. Colone, P.G.
CDM Smith Inc.

cc: John Roberson, WCSWM
Elliot Cornell, WCSWM
Table 1
Leachate Water Quality Parameters
September 2016 Semi-Annual Sampling Event
North Wake Subtitle D Landfill - Permit Number 9209-MSWLF-1996
9209-MSWLF-1996 29-Oct-10 7.58 8,461 19.0 101 2.64 12.7
9209-MSWLF-1996 15-Mar-11 7.30 1,361 16.6 55 3.87 -196.7
9209-MSWLF-1996 2-Nov-11 7.13 15,380 19.6 95 1.97 -25.2
9209-MSWLF-1996 11-Apr-12 6.28 12,009 17.4 18 1.64 95.1
9209-MSWLF-1996 26-Oct-12 6.73 7,710 20.5 53 3.73 -128.7
9209-MSWLF-1996 11-Apr-13 6.61 8,884 19.2 31 4.52 -107.9
9209-MSWLF-1996 17-Oct-13 6.41 5,807 21.4 155 3.56 -34.8
9209-MSWLF-1996 3-Apr-14 7.56 14,100 17.0 57 0.51 -256.3
9209-MSWLF-1996 13-Nov-14 7.38 16,790 18.8 185 0.42 -246.7
9209-MSWLF-1996 9-Apr-15 7.38 16,690 19.8 223 1.33 -81.2
9209-MSWLF-1996 15-Oct-15 7.46 1,824 19.6 26 0.84 -153.1
9209-MSWLF-1996 21-Apr-16 8.01 1,630 20.7 95 0.31 -172.3
9209-MSWLF-1996 14-Sep-16 7.64 1,313 21.7 35 0.05 -146.6
Notes:
1. The first sampling event was completed in October 2010 by CDM Smith Inc.
2. µS/cm - Microsiemens per centimeter
3. NTUs - Nephelometric Turbidity Units
4. DO - Dissolved Oxygen
5. mg/L - Milligrams per liter
6. ORP - Oxidation-Reduction Potential
7. S.U. - Standard Units
8. mVs - Millivolts
Leachate
Facility Permit
Number Sampling Date pH
S.U.
Conductivity
(µS/cm)
Temperature
(degrees Celsius)
Turbidity
(NTUs)
DO
(mg/L)
ORP
(mVs)
Page 1 of 1 December 2016

Appendix A
Analytical Data
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
RI15015Lot Number:
North Wake Lined LeachateProject Name:
09/29/2016Date Completed:
Catherine S. Dover
Project Manager

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
CDM Smith
Lot Number: RI15015
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: North Wake Lined Leachate
Project Number:
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
CDM Smith
Lot Number: RI15015

Project Name: North Wake Lined Leachate
Project Number:
Sample Number Sample ID Matrix Date Sampled Date Received
001 09/14/2016 1300LEACHATEAqueous 09/15/2016
002 09/14/2016TRIP BLANK Aqueous 09/15/2016
(2 samples)
Page: 3 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
LEACHATE
RI15015-001
09/14/2016 1300
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (BOD, 5 day) SM 5210B-2011 1 09/20/2016 1540 AMM1 09/15/2016 1909 10861
1 (COD) SM 5220D-2011 10 09/27/2016 1435 BWS 09/26/2016 1721
1 (Nitrate - N) 300.0 10 09/15/2016 1955 SLU 22133
1 (Phosphorus) 365.1 1 09/26/2016 1105 KWP 09/25/2016 1512 22825
1 (Sulfate) 300.0 25 09/27/2016 2247 SLU 23119
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
BOD, 5 day SM 5210B-20 480 1mg/L0.182.0
COD SM 5220D-20 2300 D 1mg/L57100
Nitrate - N 300.0 0.14 JD 1mg/L0.0500.20
Phosphorus 7723-14-0 365.1 5.5 B 1mg/L0.0410.25
Sulfate 300.0 8.2 BJD 1mg/L5.025
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 4 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
LEACHATE
RI15015-001
09/14/2016 1300
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 10 09/20/2016 0509 JJG 22380
2 5030B 8260B 10 09/20/2016 1701 TML 22412
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
Acetone 67-64-1 8260B 1000 D 1ug/L20100
Acrylonitrile 107-13-1 8260B 50 U 1ug/L8.050
Benzene 71-43-2 8260B 5.0 U 1ug/L4.05.0
Bromochloromethane 74-97-5 8260B 5.0 U 1ug/L4.05.0
Bromodichloromethane 75-27-4 8260B 5.0 U 1ug/L4.05.0
Bromoform 75-25-2 8260B 5.0 U 1ug/L4.05.0
Bromomethane (Methyl bromide)74-83-9 8260B 5.0 U 1ug/L4.05.0
2-Butanone (MEK)78-93-3 8260B 1200 D 1ug/L20100
Carbon disulfide 75-15-0 8260B 5.0 U 1ug/L4.05.0
Carbon tetrachloride 56-23-5 8260B 5.0 U 1ug/L4.05.0
Chlorobenzene 108-90-7 8260B 5.0 U 1ug/L4.05.0
Chloroethane 75-00-3 8260B 5.0 U 1ug/L4.05.0
Chloroform 67-66-3 8260B 5.0 U 1ug/L4.05.0
Chloromethane (Methyl chloride)74-87-3 8260B 5.0 U 1ug/L4.05.0
1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 5.0 U 1ug/L4.05.0
Dibromochloromethane 124-48-1 8260B 5.0 U 1ug/L4.05.0
1,2-Dibromoethane (EDB)106-93-4 8260B 5.0 U 1ug/L4.05.0
Dibromomethane (Methylene bromide)74-95-3 8260B 5.0 U 1ug/L4.05.0
trans-1,4-Dichloro-2-butene 110-57-6 8260B 20 U 2ug/L4.020
1,2-Dichlorobenzene 95-50-1 8260B 5.0 U 1ug/L4.05.0
1,4-Dichlorobenzene 106-46-7 8260B 4.4 JD 1ug/L4.05.0
1,1-Dichloroethane 75-34-3 8260B 5.0 U 1ug/L4.05.0
1,2-Dichloroethane 107-06-2 8260B 5.0 U 1ug/L4.05.0
1,1-Dichloroethene 75-35-4 8260B 5.0 U 1ug/L4.05.0
cis-1,2-Dichloroethene 156-59-2 8260B 5.0 U 1ug/L4.05.0
trans-1,2-Dichloroethene 156-60-5 8260B 5.0 U 1ug/L4.05.0
1,2-Dichloropropane 78-87-5 8260B 5.0 U 1ug/L4.05.0
cis-1,3-Dichloropropene 10061-01-5 8260B 5.0 U 1ug/L4.05.0
trans-1,3-Dichloropropene 10061-02-6 8260B 5.0 U 1ug/L4.05.0
Ethylbenzene 100-41-4 8260B 5.6 D 1ug/L4.05.0
2-Hexanone 591-78-6 8260B 100 U 1ug/L20100
Methyl iodide (Iodomethane)74-88-4 8260B 50 U 1ug/L4.050
4-Methyl-2-pentanone 108-10-1 8260B 44 JD 1ug/L20100
Methylene chloride 75-09-2 8260B 5.0 U 1ug/L4.05.0
Styrene 100-42-5 8260B 5.0 U 1ug/L4.05.0
1,1,1,2-Tetrachloroethane 630-20-6 8260B 5.0 U 1ug/L4.05.0
1,1,2,2-Tetrachloroethane 79-34-5 8260B 5.0 U 1ug/L4.05.0
Tetrachloroethene 127-18-4 8260B 5.0 U 1ug/L4.05.0
Toluene 108-88-3 8260B 14 D 1ug/L4.05.0
1,1,1-Trichloroethane 71-55-6 8260B 5.0 U 1ug/L4.05.0
1,1,2-Trichloroethane 79-00-5 8260B 5.0 U 1ug/L4.05.0
Trichloroethene 79-01-6 8260B 5.0 U 1ug/L4.05.0
Trichlorofluoromethane 75-69-4 8260B 5.0 U 1ug/L4.05.0
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 5 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
LEACHATE
RI15015-001
09/14/2016 1300
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 10 09/20/2016 0509 JJG 22380
2 5030B 8260B 10 09/20/2016 1701 TML 22412
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
1,2,3-Trichloropropane 96-18-4 8260B 5.0 U 1ug/L4.05.0
Vinyl acetate 108-05-4 8260B 50 U 1ug/L1250
Vinyl chloride 75-01-4 8260B 5.0 U 1ug/L4.05.0
Xylenes (total)1330-20-7 8260B 17 D 1ug/L4.010
AcceptanceAcceptanceRun 2Run 1
Surrogate Q % Recovery Limits % Recovery LimitsQ
Bromofluorobenzene 95 70-130 101 70-130
1,2-Dichloroethane-d4 102 70-130 102 70-130
Toluene-d8 99 70-130 105 70-130
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 6 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

ICP-MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
LEACHATE
RI15015-001
09/14/2016 1300
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020A 5 09/17/2016 0057 BNW 09/16/2016 1034 22163
2 3005A 6020A 5 09/19/2016 1755 BNW 09/16/2016 1034 22163
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
Antimony 7440-36-0 6020A 39 D 2ug/L0.8730
Arsenic 7440-38-2 6020A 350 D 1ug/L1.350
Barium 7440-39-3 6020A 220 JD 2ug/L2.7500
Beryllium 7440-41-7 6020A 5.0 U 2ug/L0.585.0
Cadmium 7440-43-9 6020A 5.0 U 2ug/L0.225.0
Chromium 7440-47-3 6020A 230 D 2ug/L3.250
Cobalt 7440-48-4 6020A 43 JD 2ug/L1.350
Copper 7440-50-8 6020A 4.5 BJD 1ug/L0.7650
Lead 7439-92-1 6020A 2.1 JD 2ug/L0.7450
Nickel 7440-02-0 6020A 200 JD 1ug/L3.1250
Selenium 7782-49-2 6020A 5.0 JD 1ug/L4.850
Silver 7440-22-4 6020A 1.0 JD 2ug/L0.8550
Thallium 7440-28-0 6020A 28 U 2ug/L0.3828
Vanadium 7440-62-2 6020A 140 D 2ug/L5.1130
Zinc 7440-66-6 6020A 61 BD 2ug/L8.050
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 7 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
TRIP BLANK
RI15015-002
09/14/2016
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 09/20/2016 0006 JJG 22380
2 5030B 8260B 1 09/20/2016 1030 TML 22412
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
Acetone 67-64-1 8260B 10 U 1ug/L2.010
Acrylonitrile 107-13-1 8260B 5.0 U 1ug/L0.805.0
Benzene 71-43-2 8260B 0.50 U 1ug/L0.400.50
Bromochloromethane 74-97-5 8260B 0.50 U 1ug/L0.400.50
Bromodichloromethane 75-27-4 8260B 0.50 U 1ug/L0.400.50
Bromoform 75-25-2 8260B 0.50 U 1ug/L0.400.50
Bromomethane (Methyl bromide)74-83-9 8260B 0.50 U 1ug/L0.400.50
2-Butanone (MEK)78-93-3 8260B 10 U 1ug/L2.010
Carbon disulfide 75-15-0 8260B 0.50 U 1ug/L0.400.50
Carbon tetrachloride 56-23-5 8260B 0.50 U 1ug/L0.400.50
Chlorobenzene 108-90-7 8260B 0.50 U 1ug/L0.400.50
Chloroethane 75-00-3 8260B 0.50 U 1ug/L0.400.50
Chloroform 67-66-3 8260B 0.50 U 1ug/L0.400.50
Chloromethane (Methyl chloride)74-87-3 8260B 0.50 U 1ug/L0.400.50
1,2-Dibromo-3-chloropropane (DBCP)96-12-8 8260B 0.50 U 1ug/L0.400.50
Dibromochloromethane 124-48-1 8260B 0.50 U 1ug/L0.400.50
1,2-Dibromoethane (EDB)106-93-4 8260B 0.50 U 1ug/L0.400.50
Dibromomethane (Methylene bromide)74-95-3 8260B 0.50 U 1ug/L0.400.50
trans-1,4-Dichloro-2-butene 110-57-6 8260B 2.0 U 2ug/L0.402.0
1,2-Dichlorobenzene 95-50-1 8260B 0.50 U 1ug/L0.400.50
1,4-Dichlorobenzene 106-46-7 8260B 0.50 U 1ug/L0.400.50
1,1-Dichloroethane 75-34-3 8260B 0.50 U 1ug/L0.400.50
1,2-Dichloroethane 107-06-2 8260B 0.50 U 1ug/L0.400.50
1,1-Dichloroethene 75-35-4 8260B 0.50 U 1ug/L0.400.50
cis-1,2-Dichloroethene 156-59-2 8260B 0.50 U 1ug/L0.400.50
trans-1,2-Dichloroethene 156-60-5 8260B 0.50 U 1ug/L0.400.50
1,2-Dichloropropane 78-87-5 8260B 0.50 U 1ug/L0.400.50
cis-1,3-Dichloropropene 10061-01-5 8260B 0.50 U 1ug/L0.400.50
trans-1,3-Dichloropropene 10061-02-6 8260B 0.50 U 1ug/L0.400.50
Ethylbenzene 100-41-4 8260B 0.50 U 1ug/L0.400.50
2-Hexanone 591-78-6 8260B 10 U 1ug/L2.010
Methyl iodide (Iodomethane)74-88-4 8260B 5.0 U 1ug/L0.405.0
4-Methyl-2-pentanone 108-10-1 8260B 10 U 1ug/L2.010
Methylene chloride 75-09-2 8260B 0.50 U 1ug/L0.400.50
Styrene 100-42-5 8260B 0.50 U 1ug/L0.400.50
1,1,1,2-Tetrachloroethane 630-20-6 8260B 0.50 U 1ug/L0.400.50
1,1,2,2-Tetrachloroethane 79-34-5 8260B 0.50 U 1ug/L0.400.50
Tetrachloroethene 127-18-4 8260B 0.50 U 1ug/L0.400.50
Toluene 108-88-3 8260B 0.50 U 1ug/L0.400.50
1,1,1-Trichloroethane 71-55-6 8260B 0.50 U 1ug/L0.400.50
1,1,2-Trichloroethane 79-00-5 8260B 0.50 U 1ug/L0.400.50
Trichloroethene 79-01-6 8260B 0.50 U 1ug/L0.400.50
Trichlorofluoromethane 75-69-4 8260B 0.50 U 1ug/L0.400.50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 8 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
CDM Smith
TRIP BLANK
RI15015-002
09/14/2016
09/15/2016
Aqueous
Project Name: North Wake Lined Leachate
Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 09/20/2016 0006 JJG 22380
2 5030B 8260B 1 09/20/2016 1030 TML 22412
AnalyticalCAS
Parameter Number Method Result Q PQL Units RunMDL
1,2,3-Trichloropropane 96-18-4 8260B 0.50 U 1ug/L0.400.50
Vinyl acetate 108-05-4 8260B 5.0 U 1ug/L1.25.0
Vinyl chloride 75-01-4 8260B 0.50 U 1ug/L0.400.50
Xylenes (total)1330-20-7 8260B 1.0 U 1ug/L0.401.0
AcceptanceAcceptanceRun 2Run 1
Surrogate Q % Recovery Limits % Recovery LimitsQ
Bromofluorobenzene 97 70-130 97 70-130
1,2-Dichloroethane-d4 103 70-130 103 70-130
Toluene-d8 99 70-130 105 70-130
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
D = Dilution > 1
Page: 9 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

QC Summary
Page: 10 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:RQ22133-001
22133
Analytical Method:300.0
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Nitrate - N 0.020 09/15/2016 1331U0.020 0.0050 mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 11 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:RQ22133-002
22133
Analytical Method:300.0
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Nitrate - N 0.81 09/15/2016 13551010.80 90-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 12 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:Prep Method:
Prep Date:
Sample ID:RQ22825-001
22825 365.1
09/25/2016 1512Analytical Method:365.1
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Phosphorus 0.0057 09/26/2016 1105J0.010 0.0016 mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 13 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:Prep Method:
Prep Date:
Sample ID:RQ22825-002
22825 365.1
09/25/2016 1512Analytical Method:365.1
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Phosphorus 0.24 09/26/2016 1105980.25 90-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 14 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - MB
Batch:
Sample ID:RQ23119-001
23119
Analytical Method:300.0
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Sulfate 0.43 09/27/2016 2122J1.0 0.20 mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 15 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Inorganic non-metals - LCS
Batch:
Sample ID:RQ23119-002
23119
Analytical Method:300.0
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Sulfate 22 09/27/2016 21341102090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 16 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - MB
Batch:Prep Method:
Sample ID:RQ22380-001
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Acetone 10 09/19/2016 2322U102.0 ug/L1
Acrylonitrile 5.0 09/19/2016 2322U5.0 0.80 ug/L1
Benzene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Bromochloromethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Bromodichloromethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Bromoform 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Bromomethane (Methyl bromide)0.50 09/19/2016 2322U0.50 0.40 ug/L1
2-Butanone (MEK)10 09/19/2016 2322U102.0 ug/L1
Carbon disulfide 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Carbon tetrachloride 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Chlorobenzene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Chloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Chloroform 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Chloromethane (Methyl chloride)0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2-Dibromo-3-chloropropane (DBCP)0.50 09/19/2016 2322U0.50 0.40 ug/L1
Dibromochloromethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2-Dibromoethane (EDB)0.50 09/19/2016 2322U0.50 0.40 ug/L1
Dibromomethane (Methylene bromide)0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,4-Dichlorobenzene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2-Dichlorobenzene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2-Dichloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1-Dichloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
trans-1,2-Dichloroethene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
cis-1,2-Dichloroethene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1-Dichloroethene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2-Dichloropropane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
trans-1,3-Dichloropropene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
cis-1,3-Dichloropropene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Ethylbenzene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
2-Hexanone 10 09/19/2016 2322U102.0 ug/L1
Methyl iodide (Iodomethane)5.0 09/19/2016 2322U5.0 0.40 ug/L1
4-Methyl-2-pentanone 10 09/19/2016 2322U102.0 ug/L1
Methylene chloride 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Styrene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1,2,2-Tetrachloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1,1,2-Tetrachloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Tetrachloroethene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Toluene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1,2-Trichloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,1,1-Trichloroethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Trichloroethene 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Trichlorofluoromethane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
1,2,3-Trichloropropane 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Vinyl acetate 5.0 09/19/2016 2322U5.0 1.2 ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 17 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - MB
Batch:Prep Method:
Sample ID:RQ22380-001
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Vinyl chloride 0.50 09/19/2016 2322U0.50 0.40 ug/L1
Xylenes (total)1.0 09/19/2016 2322U1.0 0.40 ug/L1
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 95 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 97 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 18 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - LCS
Batch:Prep Method:
Sample ID:RQ22380-002
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Acetone 91 09/19/2016 22229110060-1401
Acrylonitrile 87 09/19/2016 22228710060-1401
Benzene 47 09/19/2016 2222935070-1301
Bromochloromethane 46 09/19/2016 2222915070-1301
Bromodichloromethane 49 09/19/2016 2222985070-1301
Bromoform 39 09/19/2016 2222795070-1301
Bromomethane (Methyl bromide)46 09/19/2016 2222935060-1401
2-Butanone (MEK)85 09/19/2016 22228510060-1401
Carbon disulfide 47 09/19/2016 2222945060-1401
Carbon tetrachloride 49 09/19/2016 2222995070-1301
Chlorobenzene 47 09/19/2016 2222945070-1301
Chloroethane 46 09/19/2016 2222935060-1401
Chloroform 44 09/19/2016 2222895070-1301
Chloromethane (Methyl chloride)54 09/19/2016 22221085050-1301
1,2-Dibromo-3-chloropropane (DBCP)42 09/19/2016 2222835070-1301
Dibromochloromethane 45 09/19/2016 2222895070-1301
1,2-Dibromoethane (EDB)45 09/19/2016 2222905070-1301
Dibromomethane (Methylene bromide)48 09/19/2016 2222955070-1301
1,4-Dichlorobenzene 45 09/19/2016 2222905070-1301
1,2-Dichlorobenzene 47 09/19/2016 2222945070-1301
1,2-Dichloroethane 48 09/19/2016 2222965070-1301
1,1-Dichloroethane 47 09/19/2016 2222935070-1301
trans-1,2-Dichloroethene 48 09/19/2016 2222965070-1301
cis-1,2-Dichloroethene 46 09/19/2016 2222915070-1301
1,1-Dichloroethene 48 09/19/2016 2222965070-1301
1,2-Dichloropropane 49 09/19/2016 2222985070-1301
trans-1,3-Dichloropropene 45 09/19/2016 2222895070-1301
cis-1,3-Dichloropropene 48 09/19/2016 2222965070-1301
Ethylbenzene 49 09/19/2016 2222975070-1301
2-Hexanone 99 09/19/2016 22229910060-1401
Methyl iodide (Iodomethane)43 09/19/2016 2222865070-1301
4-Methyl-2-pentanone 100 09/19/2016 222210310060-1401
Methylene chloride 42 09/19/2016 2222845070-1301
Styrene 49 09/19/2016 2222985070-1301
1,1,2,2-Tetrachloroethane 47 09/19/2016 2222945070-1301
1,1,1,2-Tetrachloroethane 47 09/19/2016 2222955070-1301
Tetrachloroethene 49 09/19/2016 2222985070-1301
Toluene 46 09/19/2016 2222925070-1301
1,1,2-Trichloroethane 46 09/19/2016 2222935070-1301
1,1,1-Trichloroethane 46 09/19/2016 2222925070-1301
Trichloroethene 49 09/19/2016 2222985070-1301
Trichlorofluoromethane 54 09/19/2016 22221085060-1401
1,2,3-Trichloropropane 48 09/19/2016 2222955070-1301
Vinyl acetate 48 09/19/2016 2222965060-1401
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 19 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - LCS
Batch:Prep Method:
Sample ID:RQ22380-002
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Vinyl chloride 48 09/19/2016 2222965060-1401
Xylenes (total)97 09/19/2016 22229710070-1301
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 98 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 100 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 20 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - MS
Batch:Prep Method:
Sample ID:RI15015-001MS
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(ug/L)(ug/L)(ug/L)
Acetone 2800 09/20/2016 0556N179100060-140100010
Acrylonitrile 930 09/20/2016 055693100060-1400.0 10
Benzene 530 09/20/2016 055610550070-1300.0 10
Bromochloromethane 510 09/20/2016 055610150070-1300.0 10
Bromodichloromethane 570 09/20/2016 055611350070-1300.0 10
Bromoform 520 09/20/2016 055610350070-1300.0 10
Bromomethane (Methyl bromide)500 09/20/2016 055610050060-1400.0 10
2-Butanone (MEK)2100 09/20/2016 055695100060-140120010
Carbon disulfide 560 09/20/2016 055611250060-1400.0 10
Carbon tetrachloride 580 09/20/2016 055611650070-1300.0 10
Chlorobenzene 520 09/20/2016 055610550070-1300.0 10
Chloroethane 530 09/20/2016 055610750060-1400.0 10
Chloroform 500 09/20/2016 055610050070-1300.0 10
Chloromethane (Methyl chloride)570 09/20/2016 055611450020-1580.0 10
1,2-Dibromo-3-chloropropane (DBCP)490 09/20/2016 05569750070-1300.0 10
Dibromochloromethane 530 09/20/2016 055610750070-1300.0 10
1,2-Dibromoethane (EDB)500 09/20/2016 05569950070-1300.0 10
Dibromomethane (Methylene bromide)530 09/20/2016 055610750070-1300.0 10
1,2-Dichlorobenzene 510 09/20/2016 055610150070-1300.0 10
1,4-Dichlorobenzene 500 09/20/2016 05569950070-1304.4 10
1,1-Dichloroethane 530 09/20/2016 055610650070-1300.0 10
1,2-Dichloroethane 550 09/20/2016 055611050070-1300.0 10
1,1-Dichloroethene 560 09/20/2016 055611150070-1300.0 10
cis-1,2-Dichloroethene 520 09/20/2016 055610450070-1300.0 10
trans-1,2-Dichloroethene 550 09/20/2016 055610950070-1300.0 10
1,2-Dichloropropane 560 09/20/2016 055611150070-1300.0 10
cis-1,3-Dichloropropene 540 09/20/2016 055610850070-1300.0 10
trans-1,3-Dichloropropene 520 09/20/2016 055610450070-1300.0 10
Ethylbenzene 560 09/20/2016 055611050070-1305.6 10
2-Hexanone 1100 09/20/2016 0556109100060-1400.0 10
Methyl iodide (Iodomethane)500 09/20/2016 05569950070-1300.0 10
4-Methyl-2-pentanone 1200 09/20/2016 0556114100060-1404410
Methylene chloride 490 09/20/2016 05569850070-1300.0 10
Styrene 560 09/20/2016 055611150070-1300.0 10
1,1,1,2-Tetrachloroethane 520 09/20/2016 055610550070-1300.0 10
1,1,2,2-Tetrachloroethane 480 09/20/2016 05569550070-1300.0 10
Tetrachloroethene 550 09/20/2016 055611150070-1300.0 10
Toluene 530 09/20/2016 055610450070-1301410
1,1,1-Trichloroethane 540 09/20/2016 055610850070-1300.0 10
1,1,2-Trichloroethane 510 09/20/2016 055610150070-1300.0 10
Trichloroethene 590 09/20/2016 055611750070-1300.0 10
Trichlorofluoromethane 650 09/20/2016 055612950060-1400.0 10
1,2,3-Trichloropropane 560 09/20/2016 055611350070-1300.0 10
Vinyl acetate 68 09/20/2016 0556N1450029-1970.0 10
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 21 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - MS
Batch:Prep Method:
Sample ID:RI15015-001MS
22380 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(ug/L)(ug/L)(ug/L)
Vinyl chloride 540 09/20/2016 055610950060-1400.0 10
Xylenes (total)1100 09/20/2016 0556111100070-1301710
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 98 70-130
Toluene-d8 99 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 22 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - MB
Batch:Prep Method:
Sample ID:RQ22412-001
22412 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
trans-1,4-Dichloro-2-butene 2.0 09/20/2016 1000U2.0 0.40 ug/L1
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 99 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 104 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 23 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - LCS
Batch:Prep Method:
Sample ID:RQ22412-002
22412 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
trans-1,4-Dichloro-2-butene 53 09/20/2016 09061055034-1421
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 95 70-130
Toluene-d8 104 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 24 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Volatile Organic Compounds by GC/MS - LCSD
Batch:Prep Method:
Sample ID:RQ22412-003
22412 5030B
Analytical Method:8260B
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
trans-1,4-Dichloro-2-butene 49 09/20/2016 1833995034-1426.7 201
Surrogate Q % Rec
Acceptance
Limit
Bromofluorobenzene 103 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 106 70-130
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 25 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

ICP-MS - MB
Batch:Prep Method:
Prep Date:
Sample ID:RQ22163-001
22163 3005A
09/16/2016 1034Analytical Method:6020A
Matrix:Aqueous
Parameter Result Q PQL MDL Units Analysis DateDil
Antimony 6.0 09/19/2016 1806U6.0 0.17 ug/L1
Arsenic 10 09/16/2016 2327U100.26 ug/L1
Barium 100 09/19/2016 1806U1000.53 ug/L1
Beryllium 1.0 09/19/2016 1806U1.0 0.12 ug/L1
Cadmium 1.0 09/16/2016 2327U1.0 0.044 ug/L1
Chromium 10 09/19/2016 1806U100.63 ug/L1
Cobalt 10 09/19/2016 1806U100.26 ug/L1
Copper 0.21 09/16/2016 2327J100.15 ug/L1
Lead 10 09/19/2016 1806U100.15 ug/L1
Nickel 50 09/16/2016 2327U500.63 ug/L1
Selenium 10 09/16/2016 2327U100.95 ug/L1
Silver 10 09/19/2016 1806U100.17 ug/L1
Thallium 5.5 09/19/2016 1806U5.5 0.075 ug/L1
Vanadium 25 09/19/2016 1806U251.0 ug/L1
Zinc 2.2 09/19/2016 1806J101.6 ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 26 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

ICP-MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:RQ22163-002
22163 3005A
09/16/2016 1034Analytical Method:6020A
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Antimony 100 09/19/2016 181210010080-1201
Arsenic 110 09/16/2016 233311010080-1201
Barium 100 09/19/2016 181210310080-1201
Beryllium 120 09/19/2016 1812N12210080-1201
Cadmium 110 09/16/2016 233311210080-1201
Chromium 97 09/19/2016 18129710080-1201
Cobalt 98 09/19/2016 18129810080-1201
Copper 110 09/16/2016 233311410080-1201
Lead 100 09/19/2016 181210210080-1201
Nickel 110 09/16/2016 233311310080-1201
Selenium 110 09/16/2016 233310610080-1201
Silver 110 09/19/2016 181210610080-1201
Thallium 100 09/19/2016 181210310080-1201
Vanadium 96 09/19/2016 18129610080-1201
Zinc 100 09/19/2016 181210410080-1201
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
U = Not detected at or above the detection limit
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
Page: 27 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

Chain of Custody
and
Miscellaneous Documents
Page: 28 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

Page: 29 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

SHEALY ENVIRONMENTAL SERVICES, INC.

Page: 30 of 29
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.

cdmsmith.com