HomeMy WebLinkAbout9209_NorthWakeCDLF_GWMR_DIN28102_20160624North Wake C&D Landfill
Facility Permit No. 92-09
Semi-Annual Sampling Report
(March 2016 Sampling Event)
Wake County
Report
Prepared June 2016
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: 919 325-3500
fax: 919 781-5730
June 24, 2016
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: March 2016 Semi-Annual Groundwater Monitoring Report
North Wake C&D Landfill
Facility Permit No. 92-09
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Wake County, is submitting an electronic copy of the March
2016 semi-annual sampling event report. This letter report presents the results of the most recent
semi-annual sampling event at the North Wake C&D Landfill and constitutes the first sampling event
for 2016. The approved groundwater monitoring network consists of the background well (i.e. MW-1)
and three down gradient compliance wells (i.e. CD-1, -2, and -3). Field activities and results of the
March 2016 sampling event are discussed below.
Field Activities
Groundwater samples from the North Wake C&D Landfill were collected from March 24-25, 2016, by
use of disposable, laboratory decontaminated bailers. Monitoring well locations for the North Wake
C&D Landfill are shown on Figure 1. Well construction details are provided in Table 1.
Groundwater elevations were measured at each well prior to sampling and are presented in Table 2.
These groundwater elevations were used to construct a potentiometric surface map for this sampling
event. The potentiometric contours are shown on Figure 1.
After depth to groundwater was measured, three well volumes of water were removed from each
well prior to sampling to provide fresh formation water within the well water column. Each well
volume was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-
reduction potential using a YSI-556 multi-parameter water quality meter and a HANNA HI 98703
turbidity meter. Monitoring wells with elevated turbidity were allowed to stabilize prior to sample
collection. The water quality parameters at the time of sampling are presented in Table 2.
Ms. Jaclynne Drummond
June 24, 2016
Page 2
Sampling Results
ALS Environmental, Inc. located in Jacksonville, Florida, analyzed the groundwater samples for North
Carolina Appendix I volatile organic compounds (VOCs) and Resource and Conservation Recovery Act
metals (i.e. arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver). In accordance
with Solid Waste Section (SWS) guidelines the analytical results were reported to the laboratory
specific method detection limit (MDL) and are quantifiable at or below SWS Limits (SWSLs). All
monitoring wells for the C&D Landfill had detections of analytes above the MDL but below SWSLs.
These detections were qualified as estimated or “J” flags.
No Appendix I VOCs or metals were detected above the 15A NCAC 02L .0202 (NC 2L) Groundwater
Standards. Equipment and trip blanks were analyzed for quality control. The equipment blank had
estimated detections of 2-butanone and acetone below their respective NC 2L Standards. An
estimated concentration of methylene chloride was detected in the trip blank below the NC 2L
Standard. A complete summary of all detected and estimated concentrations for the March 2016 and
previous sampling events is presented in Table 3. The laboratory analytical data report is provided in
Appendix A. CDM Smith will monitor future analytical results to determine if a trend appears.
The next semi-annual sampling event will be completed in the fall of 2016. If you have any questions
or require further explanation, do not hesitate to call me at (919) 325-3500.
Very truly yours,
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
Table 1
Well Construction Summary
March 2016 Semi-Annual Sampling Event
North Wake C&D Landfill
Facility
Permit
Number
Monitoring
Well Code
Installation
Date Latitude Longitude
Geology of
Screened
Interval
Total
Depth
(feet bgs)
Top of Casing
Elevation
(feet AMSL)
Screened
Interval
(feet bgs)
Filter Pack
Interval
(feet bgs)
Seal
Interval
(feet bgs)
Monitoring
Well Diameter
(inches)
92-09 MW-1 1994 35.90984 78.58489 Regolith 58 333.80 48.0 - 58.0 46.0 - 58.0 44.0 - 46.0 2.0
92-09 CD-1 May 2001 35.90907 78.58318 Regolith 25 296.26 10.0 - 25.0 8.0 - 25.0 8.0 - 10.0 2.0
92-09 CD-2 May 2001 35.91032 78.58207 Regolith 25 282.64 10.0 - 25.0 8.0 - 25.0 8.0 - 10.0 2.0
92-09 CD-3 May 2001 35.91016 78.58340 Regolith 33 301.49 10.0 - 25.0 8.0 - 25.0 8.0 - 10.0 2.0
Notes:
1. bgs - Below Ground Surface
2. AMSL - Above Mean Sea Level
3. Latitude and longitude coordinate system - World Geodetic System 1984
Page 1 of 1 June 2016
Table 2
Water Quality Parameters
North Wake C&D Landfill
pH Conductivity Temperature Turbidity DO ORP TOC
Elevation
Depth to
Groundwater
Groundwater
Elevation
(S.U.)(µS/cm)(degrees Celsius)(NTUs)(mg/L)(mV)(feet AMSL)(feet)(feet AMSL)
MW-1 5.62 82 16.3 49 4.99 52.0 333.80 46.11 287.69
CD-1 6.18 101 16.2 4 5.00 80.8 296.26 13.52 282.74
CD-2 5.72 95 15.2 9 4.50 98.3 282.64 11.16 271.48
CD-3 5.53 82 17.8 22 2.65 68.3 301.49 21.21 280.28
Notes:
1. AMSL - Above Mean Sea Level
2. TOC - Top of Casing
3. µS/cm - Microsiemens per centimeter
4. mg/L - Milligrams per liter
5. ORP - Oxidation-Reduction Potential
6. NTUs - Nephelometric Turbidity Units
7. mV - Millivolts
8. S.U. - Standard Units
9. DO - Dissolved Oxygen
10. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling.
March 2016 Semi-Annual Sampling Event
Monitoring
Well Code
Groundwater Elevations (Measured 3/24/2016)Water Quality Parameters
Page 1 of 1 June 2016
Table 3
Detected Groundwater Constituents - Metals and Volatile Organic Compounds
March 2016 Semi-Annual Sampling Event
North Wake C&D Landfill
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0.01 0.7 0.002 0.01 0.015 0.001 0.02 0.02 6,000 70 5 2,000
0.01 0.1 0.001 0.01 0.01 0.0002 0.01 0.01 100 5 1 1
MW-1 14-Mar-11 0.0421J
MW-1 20-Oct-11 0.0444J 0.00619J
MW-1 11-Apr-12 0.0384J
MW-1 26-Oct-12 0.0431J 0.00387J
MW-1 11-Apr-13 0.040J
MW-1 2-Oct-13 0.050J 0.001J
MW-1 3-Apr-14 0.040J 0.016 8.1J
MW-1 12-Nov-14 0.040J 0.00006J
MW-1 8-Apr-15 0.040J 0.001J 0.00021
MW-1 7-Oct-15 0.060J 0.001J 0.003J 0.00009J
MW-1 24-Mar-16 0.002J 0.040J 0.00013J 8.6J 0.27JB
CD-1 14-Mar-11 0.00312J 0.174 0.00978J 0.00434J
CD-1 20-Oct-11 0.0629J 0.00306J
CD-1 11-Apr-12 0.0731J 0.00372J
CD-1 26-Oct-12 0.227 0.00793J 0.00669J
CD-1 11-Apr-13 0.130 0.007J
CD-1 2-Oct-13 0.220 0.013
CD-1 3-Apr-14 0.130 0.009J
CD-1 12-Nov-14 0.120 0.006J
CD-1 8-Apr-15 0.090J 0.006J
CD-1 7-Oct-15 0.070J 0.004J 6.1J
CD-1 25-Mar-16 0.002J 0.060J 0.003J 0.27JB
CD-2 14-Mar-11 0.0569J 0.00174J 0.00274J 0.97J
CD-2 20-Oct-11 0.0532J 0.00378J 5.9J 1.8J
CD-2 11-Apr-12 0.340 0.0156 0.0142 0.00247J 0.80J
CD-2 26-Oct-12 0.102 0.00481J 0.00389J
CD-2 11-Apr-13 0.120 0.004J
CD-2 2-Oct-13 0.080J 0.005J
CD-2 3-Apr-14 0.060J 0.006J 0.61J
CD-2 12-Nov-14 0.040J 0.003J
CD-2 8-Apr-15 0.060J 0.002J 0.36J
CD-2 7-Oct-15 0.050J 0.0010J 0.003J
CD-2 25-Mar-16 0.002J 0.040J 0.001J
CD-3 14-Mar-11 0.0507J
CD-3 20-Oct-11 0.0453J
CD-3 11-Apr-12 0.0675J 0.00226J
CD-3 26-Oct-12 0.0731J 0.00361J
CD-3 11-Apr-13 0.050J
CD-3 1-Oct-13 0.030J 0.00003J
CD-3 3-Apr-14 0.040J 0.001J
CD-3 12-Nov-14 0.040J 0.00008J
CD-3 8-Apr-15 0.040J 0.0001J
CD-3 7-Oct-15 0.050J 0.00026 0.28JCD-3 24-Mar-16 0.003J 0.050J 0.00060 0.28JB 0.24J
Notes:
1. Metal detections are in milligrams per liter (parts per million).
2. Volatile organic compound detections are in micrograms per liter (parts per billion).
4. B - Indicates the analyte was detected in the associated method blank.
- Concentration exceeds the 15A NCAC 02L .0202 (2L) Groundwater Standard
- Indicates the result is below the detection limit
North Carolina 2L Standard
Solid Waste Section Limit
Metals
3. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit.
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Volatile Organic Compounds
Page 1 of 1 June 2016
Figure 1: Potentiometric Surface Map
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Appendix A
Analytical Data
April 05, 2016 Service Request No:J1602198
Aaron Weispfenning
CDM Smith, Inc.
5400 Glenwood Ave
Suite 300
Raleigh, NC 27612
All analyses were performed according to our laboratory’s quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and ALS Environmental is not responsible
for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report. In accordance to the NELAC 2003 Standard, a statement on the estimated uncertainty of
measurement of any quantitative analysis will be supplied upon request.
For your reference, these analyses have been assigned our service request number
Enclosed are the results of the sample(s) submitted to our laboratory
Laboratory Results for:North Wake C&D Landfill
Dear Aaron,
March 26, 2016
J1602198.
Respectfully submitted,
ALS Group USA, Corp. dba ALS Environmental
Mike Kimmel
dba ALS Environmental
ALS Group USA, Corp.
ADDRESS
FAXPHONE
9143 Philips Highway, Suite 200, Jacksonville, FL 32256
+1 904 739 2011+1 904 739 2277 |
Page 1 of 45
CASE NARRATIVE
J1602198
Date Received:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
3/26/16
ALS Environmental
Client: Wake County Solid Waste Management Service Request No.: J1602198
Project: North Wake C&D Landfill Date Received: 3/26/2016
Sample Matrix: Ground Water
CASE NARRATIVE
All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical
results for samples designated for Tier II data deliverables, including results of QC samples analyzed from this delivery group.
When appropriate to the procedure, method blank results have been reported with each analytical test. Analytical procedures
performed by the lab are validated in accordance with NELAC standards. Parameters that are included in the NELAC Fields of
Testing but are not included in the lab’s NELAC accreditation are identified in the discussion of each analytical procedure.
Sample Receipt
Six ground water samples were received for analysis at ALS Environmental on 3/26/2016. The samples were received in good
condition and consistent with the accompanying chain of custody form. Samples are refrigerated at <6°C upon receipt at the lab
except for aqueous samples designated for metals analyses, which are stored at room temperature.
Volatile Organic Analyses:
Method Blank JQ1602476-05 contained a low level of dichloromethane above the Method Detection Limit (MDL), but less than the
Method Reporting Limit (MRL). Affected samples are flagged with a qualifier to indicate the results are estimated values. The
method blank results may indicate the potential for a false positive.
Semi-Volatile Organic Analyses:
No significant data anomalies were noted with this analysis.
Metals Analyses:
No significant data anomalies were noted with this analysis.
9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com
Approved by Date 4/5/2016
Page 2 of 45
State Certifications, Accreditations, and Licenses
Agency Number Expire Date
Department of Defense 66206 9/20/2016
Florida Department of Health E82502 6/30/2016
Georgia Department of Natural Resources 958 6/30/2016
Kentucky Division of Waste Management 63 6/30/2016
Louisiana Department of Environmental Quality 02086 6/30/2016
Maine Department of Health and Human Services 2015002 2/3/2017
North Carolina Department of Environment and Natural Resources 527 12/31/2016
Pennsylvania Department of Environmental Protection 68-04835 8/31/2016
South Carolina Department of Health and Environmental Control 96021001 6/30/2016
Texas Commision on Environmental Quality T104704197-15-7 5/31/2016
Virginia Environmental Accreditation Program 460191 12/14/2016
9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com
Page 3 of 45
+Possible Tedlar bag artifact.
A TIC is a suspected aldol-condensation product
B Analyte found in the associated method blank as well as in the sample.
BC Reported results are not blank corrected.
BH The back section of the tube yielded higher results than the front.
BT Results indicated possible breakthrough; back section >=10% front section.
C Result identification confirmed.
D Compound identified in an analysis at a secondary dilution factor
D Spike was diluted out
DE Reported results are corrected for desorption efficiency.
E Estimated value. Concentration above calibration range
E The percent difference for the serial dilution was greater than 10%, indicating a possible
matrix interference in the sample.
H1 Sample analysis performed past holding time. See case narrative.
H2 Initial analysis within holding time. Reanalysis for the required dilution was past holding
time.
H3 Sample was received and analyzed past holding time.
H4 Sample was extracted past required extraction holding time, but analyzed within analysis
holding time. See case narrative.
I Internal standard not within the specified limits. See case narrative.
J Estimated Value. Concentration found below MRL.
K A deflection in the QC ion may indicate interference with the quantitation of this ion. The
concentration of this analyte should be considered as an estimate.
K Analyte was detected above the method reporting limit prior to normalization.
L1 Laboratory control sample recovery outside the specified limits; results may be biased
high.
L2 Laboratory control sample recovery outside the specified limits; results may be biased low.
L3 Laboratory control sample recovery outside the specified limits.
M Matrix interference; results may be biased high.
M The duplicate injection precision not met.
M1 Matrix interference due to coelution with a non-target compound; results may be biased
high.
N Presumptive evidence of a compound for TICs that have been identified based on a mass
spectral library search.
N The Matrix Spike sample recovery is not within control limits. See case narrative.
P Indicates chlorodiphenyl ether interference present at the retention time of the target
compound.
P Pesticide/Aroclor target analyte > 40% difference for detected concentrations between GC
columns
Q Indicates as estimated value because the P and P + 2 theoretical abundance ratio does not
meet method criteria.
R Duplicate Precision not met.
R1 Duplicate precision not within the specified limits; however, the results are below the
MRL and considered estimated.
S Surrogate recovery not within specified limits.
Data Qualifiers
Lab Standard
Page 4 of 45
S The reported value was determined by the Method of Standard Additions (MSA).
T Analyte is a tentatively identified compound, result is estimated.
U Compound was analyzed for, but was not detected (ND).
V1 The continuing calibration verification standard was outside (biased high) the specified
limits for this compound.
V2 The continuing calibration verification standard was outside (biased low) the specified
limits for this compound.
W Result quantified, but the corresponding peak was detected outside the generated retention
time window.
W The post-digestion spike for furnace AA analysis is out of control limits, while sample
absorbance is less than 50% of spike absorbance.
X See case narrative.
Y Recovery outside limits
Y The chromatogram resembles a petroleum product but does not match the calibration
standard.
Z The chromatogram does not resemble a petroleum product.
i The MRL/MDL has been elevated due to a matrix interference.
Data Qualifiers
Lab Standard
Page 5 of 45
ASTM American Society for Testing and Materials
A2LA American Association for Laboratory Accreditation
CARB California Air Resources Board
CAS Number Chemical Abstract Service registry Number
CFC Chlorofluorocarbon
CFU Colony-Forming Unit
DEC Department of Environmental Conservation
DEQ Department of Environmental Quality
DHS Department of Health Services
DOE Department of Ecology
DOH Department of Health
EPA U. S. Environmental Protection Agency
ELAP Environmental Laboratory Accreditation Program
GC Gas Chromatography
GC/MS Gas Chromatography/Mass Spectrometry
LUFT Leaking Underground Fuel Tank
M Modified
MCL Maximum Contaminant Level is the highest permissible concentration of a
substance allowed in drinking water as established by the USEPA.
MDL Method Detection Limit
MPN Most Probable Number
MRL Method Reporting Limit
NA Not Applicable
NC Not Calculated
NCASI National Council of the Paper Industry for Air and Stream Improvement
ND Not Detected
NIOSH National Institute for Occupational Safety and Health
PQL Practical Quantitation Limit
RCRA Resource Conservation and Recovery Act
SIM Selected Ion Monitoring
TPH Total Petroleum Hydrocarbons
tr Trace level is the concentration of an analyte that is less than the PQL but
greater than or equal to the MDL.
Acronyms
ALS Laboratory Group
Page 6 of 45
MW-1J1602198-001 3/24/2016 0800
CD-1J1602198-002 3/24/2016 1310
CD-2J1602198-003 3/25/2016 1315
CD-3J1602198-004 3/25/2016 0835
EQ BlankJ1602198-005 3/24/2016 1330
Trip BlankJ1602198-006 3/25/2016 0000
Client:Wake County Solid Waste Management Service Request:J1602198
Project:North Wake C&D Landfill
SAMPLE CROSS-REFERENCE
SAMPLE #CLIENT SAMPLE ID DATE TIME
Printed 4/5/2016 7:22:54 PM Sample Summary
Page 7 of 45
J1602198-001Lab Code:
Sample Name:MW-1
Volatile Organic Compounds by GC/MS
03/24/16 08:00
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 20:235.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 20:231.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 20:233.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 20:231.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 20:235.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 20:235.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 20:232.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 20:2313 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 20:231.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 20:235.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 20:231.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 20:231.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 20:231.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 20:23100 U2.22-Hexanone 2.2 1 03/29/16 20:2350 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 20:23100 U8.6Acetone 5.6 1 03/29/16 20:23100 J
1.5Acrylonitrile 1.5 1 03/29/16 20:23200 U0.21Benzene 0.21 1 03/29/16 20:231.0 U
0.27Bromochloromethane 0.27 1 03/29/16 20:235.0 U0.22Bromodichloromethane 0.22 1 03/29/16 20:231.0 U
0.42Bromoform 0.42 1 03/29/16 20:233.0 U0.23Bromomethane 0.23 1 03/29/16 20:2310 U
2.4Carbon Disulfide 2.4 1 03/29/16 20:23100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 20:231.0 U
0.16Chlorobenzene 0.16 1 03/29/16 20:233.0 U0.52Chloroethane 0.52 1 03/29/16 20:2310 U
0.35Chloroform 0.35 1 03/29/16 20:235.0 U0.36Chloromethane 0.36 1 03/29/16 20:231.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 20:235.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 20:231.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 20:233.0 U0.36Dibromomethane 0.36 1 03/29/16 20:2310 U
0.21Ethylbenzene 0.21 1 03/29/16 20:231.0 U2.7Iodomethane 2.7 1 03/29/16 20:2310 U
0.31m,p-Xylenes 0.31 1 03/29/16 20:232.0 U0.27Methylene Chloride 0.21 1 03/29/16 20:235.0 BJ
0.14o-Xylene 0.14 1 03/29/16 20:231.0 U0.29Styrene 0.29 1 03/29/16 20:231.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 20:231.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 20:2320 U
0.19Toluene 0.19 1 03/29/16 20:231.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 20:235.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:55 PM 16-0000370084 rev 00Superset Reference:Page 8 of 45
J1602198-001Lab Code:
Sample Name:MW-1
Volatile Organic Compounds by GC/MS
03/24/16 08:00
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 20:231.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 20:23100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 20:231.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 20:2320 U1.9Vinyl Acetate 1.9 1 03/29/16 20:2350 U
0.36Vinyl Chloride 0.36 1 03/29/16 20:231.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 20:2372 - 1211111,2-Dichloroethane-d4 03/29/16 20:2386 - 113954-Bromofluorobenzene
03/29/16 20:2386 - 112102Dibromofluoromethane 03/29/16 20:2388 - 115102Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:55 PM 16-0000370084 rev 00Superset Reference:Page 9 of 45
J1602198-001Lab Code:
Sample Name:MW-1
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
03/24/16 08:00
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 03/29/16 22:41 3/29/160.0200 U
0.007001,2-Dibromoethane (EDB)0.00700 1 03/29/16 22:41 3/29/160.0200 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 22:4170 - 130951,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:00 PM 16-0000370084 rev 00Superset Reference:Page 10 of 45
Client:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:03/24/16 08:00
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:MW-1
Lab Code:J1602198-001
Arsenic, Total 03/29/16 07:51 03/28/161210 J26010C ug/L
Barium, Total 03/29/16 07:51 03/28/1610.3100 J406010C ug/L
Cadmium, Total 03/29/16 07:51 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 07:51 03/28/1610.410 U0.46010C ug/L
Lead, Total 03/29/16 07:51 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:32 03/29/1610.020.20 J0.137470A ug/L
Selenium, Total 03/29/16 07:51 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 07:50 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:03 PM 16-0000370084 rev 00Superset Reference:Page 11 of 45
J1602198-002Lab Code:
Sample Name:CD-1
Volatile Organic Compounds by GC/MS
03/24/16 13:10
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 20:465.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 20:461.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 20:463.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 20:461.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 20:465.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 20:465.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 20:462.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 20:4613 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 20:461.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 20:465.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 20:461.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 20:461.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 20:461.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 20:46100 U2.22-Hexanone 2.2 1 03/29/16 20:4650 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 20:46100 U5.6Acetone 5.6 1 03/29/16 20:46100 U
1.5Acrylonitrile 1.5 1 03/29/16 20:46200 U0.21Benzene 0.21 1 03/29/16 20:461.0 U
0.27Bromochloromethane 0.27 1 03/29/16 20:465.0 U0.22Bromodichloromethane 0.22 1 03/29/16 20:461.0 U
0.42Bromoform 0.42 1 03/29/16 20:463.0 U0.23Bromomethane 0.23 1 03/29/16 20:4610 U
2.4Carbon Disulfide 2.4 1 03/29/16 20:46100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 20:461.0 U
0.16Chlorobenzene 0.16 1 03/29/16 20:463.0 U0.52Chloroethane 0.52 1 03/29/16 20:4610 U
0.35Chloroform 0.35 1 03/29/16 20:465.0 U0.36Chloromethane 0.36 1 03/29/16 20:461.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 20:465.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 20:461.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 20:463.0 U0.36Dibromomethane 0.36 1 03/29/16 20:4610 U
0.21Ethylbenzene 0.21 1 03/29/16 20:461.0 U2.7Iodomethane 2.7 1 03/29/16 20:4610 U
0.31m,p-Xylenes 0.31 1 03/29/16 20:462.0 U0.27Methylene Chloride 0.21 1 03/29/16 20:465.0 BJ
0.14o-Xylene 0.14 1 03/29/16 20:461.0 U0.29Styrene 0.29 1 03/29/16 20:461.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 20:461.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 20:4620 U
0.19Toluene 0.19 1 03/29/16 20:461.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 20:465.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:55 PM 16-0000370084 rev 00Superset Reference:Page 12 of 45
J1602198-002Lab Code:
Sample Name:CD-1
Volatile Organic Compounds by GC/MS
03/24/16 13:10
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 20:461.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 20:46100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 20:461.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 20:4620 U1.9Vinyl Acetate 1.9 1 03/29/16 20:4650 U
0.36Vinyl Chloride 0.36 1 03/29/16 20:461.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 20:4672 - 1211111,2-Dichloroethane-d4 03/29/16 20:4686 - 113944-Bromofluorobenzene
03/29/16 20:4686 - 112103Dibromofluoromethane 03/29/16 20:4688 - 115100Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:55 PM 16-0000370084 rev 00Superset Reference:Page 13 of 45
J1602198-002Lab Code:
Sample Name:CD-1
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
03/24/16 13:10
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 03/29/16 23:58 3/29/160.0199 U
0.007001,2-Dibromoethane (EDB)0.00700 1 03/29/16 23:58 3/29/160.0199 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 23:5870 - 1301071,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:00 PM 16-0000370084 rev 00Superset Reference:Page 14 of 45
Client:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:03/24/16 13:10
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:CD-1
Lab Code:J1602198-002
Arsenic, Total 03/29/16 07:56 03/28/161210 J26010C ug/L
Barium, Total 03/29/16 07:55 03/28/1610.3100 J606010C ug/L
Cadmium, Total 03/29/16 07:56 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 07:56 03/28/1610.410 J36010C ug/L
Lead, Total 03/29/16 07:56 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:37 03/29/1610.020.20 U0.027470A ug/L
Selenium, Total 03/29/16 07:56 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 07:55 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:03 PM 16-0000370084 rev 00Superset Reference:Page 15 of 45
J1602198-003Lab Code:
Sample Name:CD-2
Volatile Organic Compounds by GC/MS
03/25/16 13:15
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 21:095.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 21:091.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 21:093.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 21:091.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 21:095.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 21:095.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 21:092.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 21:0913 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 21:091.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 21:095.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 21:091.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 21:091.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 21:091.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 21:09100 U2.22-Hexanone 2.2 1 03/29/16 21:0950 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 21:09100 U5.6Acetone 5.6 1 03/29/16 21:09100 U
1.5Acrylonitrile 1.5 1 03/29/16 21:09200 U0.21Benzene 0.21 1 03/29/16 21:091.0 U
0.27Bromochloromethane 0.27 1 03/29/16 21:095.0 U0.22Bromodichloromethane 0.22 1 03/29/16 21:091.0 U
0.42Bromoform 0.42 1 03/29/16 21:093.0 U0.23Bromomethane 0.23 1 03/29/16 21:0910 U
2.4Carbon Disulfide 2.4 1 03/29/16 21:09100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 21:091.0 U
0.16Chlorobenzene 0.16 1 03/29/16 21:093.0 U0.52Chloroethane 0.52 1 03/29/16 21:0910 U
0.35Chloroform 0.35 1 03/29/16 21:095.0 U0.36Chloromethane 0.36 1 03/29/16 21:091.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 21:095.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 21:091.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 21:093.0 U0.36Dibromomethane 0.36 1 03/29/16 21:0910 U
0.21Ethylbenzene 0.21 1 03/29/16 21:091.0 U2.7Iodomethane 2.7 1 03/29/16 21:0910 U
0.31m,p-Xylenes 0.31 1 03/29/16 21:092.0 U0.21Methylene Chloride 0.21 1 03/29/16 21:095.0 U
0.14o-Xylene 0.14 1 03/29/16 21:091.0 U0.29Styrene 0.29 1 03/29/16 21:091.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 21:091.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 21:0920 U
0.19Toluene 0.19 1 03/29/16 21:091.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 21:095.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 16 of 45
J1602198-003Lab Code:
Sample Name:CD-2
Volatile Organic Compounds by GC/MS
03/25/16 13:15
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 21:091.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 21:09100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 21:091.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 21:0920 U1.9Vinyl Acetate 1.9 1 03/29/16 21:0950 U
0.36Vinyl Chloride 0.36 1 03/29/16 21:091.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 21:0972 - 1211111,2-Dichloroethane-d4 03/29/16 21:0986 - 113944-Bromofluorobenzene
03/29/16 21:0986 - 112104Dibromofluoromethane 03/29/16 21:0988 - 115100Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 17 of 45
J1602198-003Lab Code:
Sample Name:CD-2
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
03/25/16 13:15
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 03/30/16 00:24 3/29/160.0199 U
0.007001,2-Dibromoethane (EDB)0.00700 1 03/30/16 00:24 3/29/160.0199 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/30/16 00:2470 - 1301091,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:00 PM 16-0000370084 rev 00Superset Reference:Page 18 of 45
Client:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:03/25/16 13:15
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:CD-2
Lab Code:J1602198-003
Arsenic, Total 03/29/16 08:00 03/28/161210 J26010C ug/L
Barium, Total 03/29/16 08:00 03/28/1610.3100 J406010C ug/L
Cadmium, Total 03/29/16 08:00 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 08:00 03/28/1610.410 J16010C ug/L
Lead, Total 03/29/16 08:00 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:39 03/29/1610.020.20 U0.027470A ug/L
Selenium, Total 03/29/16 08:00 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 08:00 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:03 PM 16-0000370084 rev 00Superset Reference:Page 19 of 45
J1602198-004Lab Code:
Sample Name:CD-3
Volatile Organic Compounds by GC/MS
03/25/16 08:35
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 21:335.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 21:331.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 21:333.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 21:331.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 21:335.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 21:335.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 21:332.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 21:3313 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 21:331.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 21:335.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 21:331.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 21:331.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 21:331.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 21:33100 U2.22-Hexanone 2.2 1 03/29/16 21:3350 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 21:33100 U5.6Acetone 5.6 1 03/29/16 21:33100 U
1.5Acrylonitrile 1.5 1 03/29/16 21:33200 U0.21Benzene 0.21 1 03/29/16 21:331.0 U
0.27Bromochloromethane 0.27 1 03/29/16 21:335.0 U0.22Bromodichloromethane 0.22 1 03/29/16 21:331.0 U
0.42Bromoform 0.42 1 03/29/16 21:333.0 U0.23Bromomethane 0.23 1 03/29/16 21:3310 U
2.4Carbon Disulfide 2.4 1 03/29/16 21:33100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 21:331.0 U
0.16Chlorobenzene 0.16 1 03/29/16 21:333.0 U0.52Chloroethane 0.52 1 03/29/16 21:3310 U
0.35Chloroform 0.35 1 03/29/16 21:335.0 U0.36Chloromethane 0.36 1 03/29/16 21:331.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 21:335.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 21:331.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 21:333.0 U0.36Dibromomethane 0.36 1 03/29/16 21:3310 U
0.21Ethylbenzene 0.21 1 03/29/16 21:331.0 U2.7Iodomethane 2.7 1 03/29/16 21:3310 U
0.31m,p-Xylenes 0.31 1 03/29/16 21:332.0 U0.28Methylene Chloride 0.21 1 03/29/16 21:335.0 BJ
0.14o-Xylene 0.14 1 03/29/16 21:331.0 U0.29Styrene 0.29 1 03/29/16 21:331.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 21:331.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 21:3320 U
0.19Toluene 0.19 1 03/29/16 21:331.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 21:335.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 20 of 45
J1602198-004Lab Code:
Sample Name:CD-3
Volatile Organic Compounds by GC/MS
03/25/16 08:35
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 21:331.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 21:33100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 21:331.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 21:3320 J1.9Vinyl Acetate 1.9 1 03/29/16 21:3350 U
0.36Vinyl Chloride 0.36 1 03/29/16 21:331.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 21:3372 - 1211101,2-Dichloroethane-d4 03/29/16 21:3386 - 113944-Bromofluorobenzene
03/29/16 21:3386 - 112101Dibromofluoromethane 03/29/16 21:3388 - 115101Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 21 of 45
J1602198-004Lab Code:
Sample Name:CD-3
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
03/25/16 08:35
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 03/30/16 00:49 3/29/160.0198 U
0.007001,2-Dibromoethane (EDB)0.00700 1 03/30/16 00:49 3/29/160.0198 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/30/16 00:4970 - 1301031,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:01 PM 16-0000370084 rev 00Superset Reference:Page 22 of 45
Client:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:03/25/16 08:35
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:CD-3
Lab Code:J1602198-004
Arsenic, Total 03/29/16 08:05 03/28/161210 J36010C ug/L
Barium, Total 03/29/16 08:05 03/28/1610.3100 J506010C ug/L
Cadmium, Total 03/29/16 08:05 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 08:05 03/28/1610.410 U0.46010C ug/L
Lead, Total 03/29/16 08:05 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:47 03/29/1610.020.200.607470A ug/L
Selenium, Total 03/29/16 08:05 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 08:05 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:03 PM 16-0000370084 rev 00Superset Reference:Page 23 of 45
J1602198-005Lab Code:
Sample Name:EQ Blank
Volatile Organic Compounds by GC/MS
03/24/16 13:30
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 19:365.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 19:361.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 19:363.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 19:361.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 19:365.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 19:365.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 19:362.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 19:3613 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 19:361.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 19:365.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 19:361.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 19:361.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 19:361.0 U
7.92-Butanone (MEK)3.8 1 03/29/16 19:36100 J2.22-Hexanone 2.2 1 03/29/16 19:3650 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 19:36100 U7.7Acetone 5.6 1 03/29/16 19:36100 J
1.5Acrylonitrile 1.5 1 03/29/16 19:36200 U0.21Benzene 0.21 1 03/29/16 19:361.0 U
0.27Bromochloromethane 0.27 1 03/29/16 19:365.0 U0.22Bromodichloromethane 0.22 1 03/29/16 19:361.0 U
0.42Bromoform 0.42 1 03/29/16 19:363.0 U0.23Bromomethane 0.23 1 03/29/16 19:3610 U
2.4Carbon Disulfide 2.4 1 03/29/16 19:36100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 19:361.0 U
0.16Chlorobenzene 0.16 1 03/29/16 19:363.0 U0.52Chloroethane 0.52 1 03/29/16 19:3610 U
0.35Chloroform 0.35 1 03/29/16 19:365.0 U0.36Chloromethane 0.36 1 03/29/16 19:361.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 19:365.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 19:361.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 19:363.0 U0.36Dibromomethane 0.36 1 03/29/16 19:3610 U
0.21Ethylbenzene 0.21 1 03/29/16 19:361.0 U2.7Iodomethane 2.7 1 03/29/16 19:3610 U
0.31m,p-Xylenes 0.31 1 03/29/16 19:362.0 U0.21Methylene Chloride 0.21 1 03/29/16 19:365.0 U
0.14o-Xylene 0.14 1 03/29/16 19:361.0 U0.29Styrene 0.29 1 03/29/16 19:361.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 19:361.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 19:3620 U
0.19Toluene 0.19 1 03/29/16 19:361.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 19:365.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 24 of 45
J1602198-005Lab Code:
Sample Name:EQ Blank
Volatile Organic Compounds by GC/MS
03/24/16 13:30
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 19:361.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 19:36100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 19:361.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 19:3620 U1.9Vinyl Acetate 1.9 1 03/29/16 19:3650 U
0.36Vinyl Chloride 0.36 1 03/29/16 19:361.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 19:3672 - 1211101,2-Dichloroethane-d4 03/29/16 19:3686 - 113954-Bromofluorobenzene
03/29/16 19:3686 - 112103Dibromofluoromethane 03/29/16 19:3688 - 115101Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:56 PM 16-0000370084 rev 00Superset Reference:Page 25 of 45
J1602198-005Lab Code:
Sample Name:EQ Blank
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
03/24/16 13:30
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 03/30/16 01:15 3/29/160.0197 U
0.007001,2-Dibromoethane (EDB)0.00700 1 03/30/16 01:15 3/29/160.0197 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/30/16 01:1570 - 1301041,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:01 PM 16-0000370084 rev 00Superset Reference:Page 26 of 45
Client:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:03/24/16 13:30
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:EQ Blank
Lab Code:J1602198-005
Arsenic, Total 03/29/16 08:42 03/28/161210 U26010C ug/L
Barium, Total 03/29/16 08:42 03/28/1610.3100 U0.36010C ug/L
Cadmium, Total 03/29/16 08:42 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 08:42 03/28/1610.410 U0.46010C ug/L
Lead, Total 03/29/16 08:42 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:49 03/29/1610.020.20 U0.027470A ug/L
Selenium, Total 03/29/16 08:42 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 08:41 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:04 PM 16-0000370084 rev 00Superset Reference:Page 27 of 45
J1602198-006Lab Code:
Sample Name:Trip Blank
Volatile Organic Compounds by GC/MS
03/25/16 00:00
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 18:495.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 18:491.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 18:493.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 18:491.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 18:495.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 18:495.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 18:492.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 18:4913 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 18:491.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 18:495.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 18:491.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 18:491.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 18:491.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 18:49100 U2.22-Hexanone 2.2 1 03/29/16 18:4950 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 18:49100 U5.6Acetone 5.6 1 03/29/16 18:49100 U
1.5Acrylonitrile 1.5 1 03/29/16 18:49200 U0.21Benzene 0.21 1 03/29/16 18:491.0 U
0.27Bromochloromethane 0.27 1 03/29/16 18:495.0 U0.22Bromodichloromethane 0.22 1 03/29/16 18:491.0 U
0.42Bromoform 0.42 1 03/29/16 18:493.0 U0.23Bromomethane 0.23 1 03/29/16 18:4910 U
2.4Carbon Disulfide 2.4 1 03/29/16 18:49100 U0.34Carbon Tetrachloride 0.34 1 03/29/16 18:491.0 U
0.16Chlorobenzene 0.16 1 03/29/16 18:493.0 U0.52Chloroethane 0.52 1 03/29/16 18:4910 U
0.35Chloroform 0.35 1 03/29/16 18:495.0 U0.36Chloromethane 0.36 1 03/29/16 18:491.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 18:495.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 18:491.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 18:493.0 U0.36Dibromomethane 0.36 1 03/29/16 18:4910 U
0.21Ethylbenzene 0.21 1 03/29/16 18:491.0 U2.7Iodomethane 2.7 1 03/29/16 18:4910 U
0.31m,p-Xylenes 0.31 1 03/29/16 18:492.0 U0.53Methylene Chloride 0.21 1 03/29/16 18:495.0 BJ
0.14o-Xylene 0.14 1 03/29/16 18:491.0 U0.29Styrene 0.29 1 03/29/16 18:491.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 18:491.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 18:4920 U
0.19Toluene 0.19 1 03/29/16 18:491.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 18:495.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:57 PM 16-0000370084 rev 00Superset Reference:Page 28 of 45
J1602198-006Lab Code:
Sample Name:Trip Blank
Volatile Organic Compounds by GC/MS
03/25/16 00:00
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
03/26/16 09:20
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 18:491.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 18:49100 U0.36Trichloroethene (TCE)0.36 1 03/29/16 18:491.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 18:4920 U1.9Vinyl Acetate 1.9 1 03/29/16 18:4950 U
0.36Vinyl Chloride 0.36 1 03/29/16 18:491.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 18:4972 - 1211101,2-Dichloroethane-d4 03/29/16 18:4986 - 113954-Bromofluorobenzene
03/29/16 18:4986 - 112101Dibromofluoromethane 03/29/16 18:4988 - 115102Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:57 PM 16-0000370084 rev 00Superset Reference:Page 29 of 45
JQ1602476-05Lab Code:
Sample Name:Method Blank
Volatile Organic Compounds by GC/MS
NA
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
NA
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.191,1,1,2-Tetrachloroethane 0.19 1 03/29/16 18:031.0 U
0.171,1,1-Trichloroethane (TCA)0.17 1 03/29/16 18:031.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 03/29/16 18:031.0 U
0.401,1,2-Trichloroethane 0.40 1 03/29/16 18:031.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 03/29/16 18:031.0 U
0.161,1-Dichloroethene (1,1-DCE)0.16 1 03/29/16 18:031.0 U0.421,2,3-Trichloropropane 0.42 1 03/29/16 18:032.0 U
2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 03/29/16 18:035.0 U0.461,2-Dibromoethane (EDB)0.46 1 03/29/16 18:031.0 U
0.481,2-Dichlorobenzene 0.48 1 03/29/16 18:031.0 U0.221,2-Dichloroethane 0.22 1 03/29/16 18:031.0 U
0.191,2-Dichloropropane 0.19 1 03/29/16 18:031.0 U0.161,4-Dichlorobenzene 0.16 1 03/29/16 18:031.0 U
3.82-Butanone (MEK)3.8 1 03/29/16 18:0310 U2.22-Hexanone 2.2 1 03/29/16 18:0325 U
1.14-Methyl-2-pentanone (MIBK)1.1 1 03/29/16 18:0325 U5.6Acetone 5.6 1 03/29/16 18:0350 U
1.5Acrylonitrile 1.5 1 03/29/16 18:0310 U0.21Benzene 0.21 1 03/29/16 18:031.0 U
0.27Bromochloromethane 0.27 1 03/29/16 18:035.0 U0.22Bromodichloromethane 0.22 1 03/29/16 18:031.0 U
0.42Bromoform 0.42 1 03/29/16 18:032.0 U0.23Bromomethane 0.23 1 03/29/16 18:035.0 U
2.4Carbon Disulfide 2.4 1 03/29/16 18:0310 U0.34Carbon Tetrachloride 0.34 1 03/29/16 18:031.0 U
0.16Chlorobenzene 0.16 1 03/29/16 18:031.0 U0.52Chloroethane 0.52 1 03/29/16 18:035.0 U
0.35Chloroform 0.35 1 03/29/16 18:031.0 U0.36Chloromethane 0.36 1 03/29/16 18:031.0 U
0.36cis-1,2-Dichloroethene 0.36 1 03/29/16 18:031.0 U0.20cis-1,3-Dichloropropene 0.20 1 03/29/16 18:031.0 U
0.21Dibromochloromethane 0.21 1 03/29/16 18:031.0 U0.36Dibromomethane 0.36 1 03/29/16 18:035.0 U
0.21Ethylbenzene 0.21 1 03/29/16 18:031.0 U2.7Iodomethane 2.7 1 03/29/16 18:035.0 U
0.31m,p-Xylenes 0.31 1 03/29/16 18:032.0 U0.49Methylene Chloride 0.21 1 03/29/16 18:035.0 J
0.14o-Xylene 0.14 1 03/29/16 18:031.0 U0.29Styrene 0.29 1 03/29/16 18:031.0 U
0.22Tetrachloroethene (PCE)0.22 1 03/29/16 18:031.0 U5.3Tetrahydrofuran 5.3 1 03/29/16 18:0320 U
0.19Toluene 0.19 1 03/29/16 18:031.0 U0.19trans-1,2-Dichloroethene 0.19 1 03/29/16 18:031.0 U
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:58 PM 16-0000370084 rev 00Superset Reference:Page 30 of 45
JQ1602476-05Lab Code:
Sample Name:Method Blank
Volatile Organic Compounds by GC/MS
NA
NA
ug/L
Basis:
Units:
8260BAnalysis Method:
NA
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate AnalyzedDil.MDLPQLResult
0.23trans-1,3-Dichloropropene 0.23 1 03/29/16 18:031.0 U
2.2trans-1,4-Dichloro-2-butene 2.2 1 03/29/16 18:0320 U0.36Trichloroethene (TCE)0.36 1 03/29/16 18:031.0 U
0.24Trichlorofluoromethane 0.24 1 03/29/16 18:0320 U1.9Vinyl Acetate 1.9 1 03/29/16 18:0310 U
0.36Vinyl Chloride 0.36 1 03/29/16 18:031.0 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 18:0372 - 1211081,2-Dichloroethane-d4 03/29/16 18:0386 - 113934-Bromofluorobenzene
03/29/16 18:0386 - 112102Dibromofluoromethane 03/29/16 18:0388 - 115100Toluene-d8
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:22:58 PM 16-0000370084 rev 00Superset Reference:Page 31 of 45
JQ1602471-01Lab Code:
Sample Name:Method Blank
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
NA
NA
ug/L
Basis:
Units:
8011Analysis Method:
MethodPrep Method:
NA
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult
0.01051,2-Dibromo-3-chloropropane (DBCP)0.0105 1 03/29/16 21:49 3/29/160.0300 U
0.01051,2-Dibromoethane (EDB)0.0105 1 03/29/16 21:49 3/29/160.0300 U
Surrogate Name Q% Rec Control Limits Date Analyzed
03/29/16 21:4970 - 130961,1,1,2-Tetrachloroethane
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:01 PM 16-0000370084 rev 00Superset Reference:Page 32 of 45
Client:
NA
J1602198
Date Received:
Date Collected:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:NA
Inorganic Parameters
Basis:NA
Analysis
MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits
Sample Name:Method Blank
Lab Code:J1602198-MB
Arsenic, Total 03/29/16 06:56 03/28/161210 U26010C ug/L
Barium, Total 03/29/16 06:56 03/28/1610.3100 U0.36010C ug/L
Cadmium, Total 03/29/16 06:56 03/28/1610.25.0 U0.26010C ug/L
Chromium, Total 03/29/16 06:56 03/28/1610.410 U0.46010C ug/L
Lead, Total 03/29/16 06:56 03/28/161210 U26010C ug/L
Mercury, Total 03/29/16 14:23 03/29/1610.020.20 U0.027470A ug/L
Selenium, Total 03/29/16 06:56 03/28/161310 U36010C ug/L
Silver, Total 03/29/16 06:56 03/28/1610.610 U0.66010C ug/L
Analytical Report
ALS Group USA, Corp.
dba ALS Environmental
Printed 4/5/2016 7:23:04 PM 16-0000370084 rev 00Superset Reference:Page 33 of 45
Sample Matrix:Ground Water
SURROGATE RECOVERY SUMMARY
Analysis Method:8260B
Sample Name Lab Code
1,2-Dichloroethane-d4 4-Bromofluorobenzene Dibromofluoromethane
72 - 121 86 - 113 86 - 112
Volatile Organic Compounds by GC/MS
MW-1 J1602198-001 102 95 111
CD-1 J1602198-002 103 94 111
CD-2 J1602198-003 104 94 111
CD-3 J1602198-004 101 94 110
EQ Blank J1602198-005 103 95 110
Trip Blank J1602198-006 101 95 110
Lab Control Sample JQ1602476-03 104 93 103
Duplicate Lab Control Sample JQ1602476-04 102 93 100
Method Blank JQ1602476-05 102 93 108
ALS Group USA, Corp.
QA/QC Report
Client:
Project:North Wake C&D Landfill
Wake County Solid Waste Management Service Request:J1602198
dba ALS Environmental
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:22:58 PM
Page 34 of 45
Sample Matrix:Ground Water
SURROGATE RECOVERY SUMMARY
Analysis Method:8260B
Sample Name Lab Code
Toluene-d8
88 - 115
Volatile Organic Compounds by GC/MS
MW-1 J1602198-001 102
CD-1 J1602198-002 100
CD-2 J1602198-003 100
CD-3 J1602198-004 101
EQ Blank J1602198-005 101
Trip Blank J1602198-006 102
Lab Control Sample JQ1602476-03 100
Duplicate Lab Control Sample JQ1602476-04 101
Method Blank JQ1602476-05 100
ALS Group USA, Corp.
QA/QC Report
Client:
Project:North Wake C&D Landfill
Wake County Solid Waste Management Service Request:J1602198
dba ALS Environmental
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:22:58 PM
Page 35 of 45
Duplicate Lab Control Sample
JQ1602476-04
Lab Control Sample
JQ1602476-03
Analyte Name
J1602198
Date Analyzed:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Duplicate Lab Control Sample Summary
Volatile Organic Compounds by GC/MS
Analysis Method:8260B
NA
ug/L
Basis:
Units:
Analysis Lot:489572
03/29/16
Spike
AmountResult % Rec % RecResult
Spike
Amount
% Rec
Limits RPD
RPD
Limit
dba ALS Environmental
ALS Group USA, Corp.
QA/QC Report
52.4 50.01,1,1,2-Tetrachloroethane 303 77-118102 50.050.8 105
54.5 50.01,1,1-Trichloroethane (TCA)301 70-122108 50.053.9 109
51.6 50.01,1,2,2-Tetrachloroethane 302 66-135101 50.050.4 103
48.4 50.01,1,2-Trichloroethane 30<1 75-12296 50.048.3 97
51.8 50.01,1-Dichloroethane (1,1-DCA)302 79-117101 50.050.7 104
47.5 50.01,1-Dichloroethene (1,1-DCE)30<1 72-12895 50.047.3 95
54.8 50.01,2,3-Trichloropropane 301 70-123108 50.054.1 110
47.6 50.01,2-Dibromo-3-chloropropane (DBCP)302 60-12294 50.046.9 95
50.4 50.01,2-Dibromoethane (EDB)301 76-118100 50.049.8 101
52.9 50.01,2-Dichlorobenzene 303 81-115103 50.051.5 106
50.5 50.01,2-Dichloroethane 30<1 70-117101 50.050.6 101
49.1 50.01,2-Dichloropropane 301 79-11797 50.048.5 98
53.8 50.01,4-Dichlorobenzene 303 82-115105 50.052.3 108
59.4 50.02-Butanone (MEK)30<1 62-138120 50.060.0 119
57.0 50.02-Hexanone 30<1 74-127114 50.057.0 114
55.2 50.04-Methyl-2-pentanone (MIBK)301 77-120109 50.054.5 110
56.4 50.0Acetone 30<1 42-161114 50.056.9 113
55.3 50.0Acrylonitrile 302 63-132113 50.056.4 111
49.3 50.0Benzene 30<1 80-11798 50.049.0 99
52.1 50.0Bromochloromethane 30<1 78-118104 50.051.9 104
48.2 50.0Bromodichloromethane 30<1 75-11896 50.047.8 96
47.9 50.0Bromoform 301 63-12195 50.047.4 96
40.0 50.0Bromomethane 303 31-15378 50.038.8 80
48.7 50.0Carbon Disulfide 304 72-12894 50.046.8 97
52.6 50.0Carbon Tetrachloride 303 67-124102 50.051.1 105
52.5 50.0Chlorobenzene 303 83-118102 50.050.8 105
44.6 50.0Chloroethane 301 68-13288 50.044.1 89
51.7 50.0Chloroform 30<1 77-116103 50.051.5 103
53.3 50.0Chloromethane 304 60-128103 50.051.4 107
52.1 50.0cis-1,2-Dichloroethene 301 78-117103 50.051.5 104
47.3 50.0cis-1,3-Dichloropropene 304 80-11991 50.045.6 95
50.1 50.0Dibromochloromethane 303 74-12197 50.048.7 100
50.3 50.0Dibromomethane 303 76-11798 50.048.8 101
51.7 50.0Ethylbenzene 303 82-119100 50.050.0 103
36.3 50.0Iodomethane 303 51-13770 50.035.2 73
112 100m,p-Xylenes 302 79-122110 100110 112
44.2 50.0Methylene Chloride 30<1 75-12388 50.044.0 88
51.1 50.0o-Xylene 302 80-119100 50.050.0 102
51.4 50.0Styrene 303 80-121100 50.050.1 103
53.5 50.0Tetrachloroethene (PCE)305 75-126101 50.050.7 107
116 100Tetrahydrofuran 30<1 40-152114 100114 116
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:22:58 PM Page 36 of 45
Duplicate Lab Control Sample
JQ1602476-04
Lab Control Sample
JQ1602476-03
Analyte Name
J1602198
Date Analyzed:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Duplicate Lab Control Sample Summary
Volatile Organic Compounds by GC/MS
Analysis Method:8260B
NA
ug/L
Basis:
Units:
Analysis Lot:489572
03/29/16
Spike
AmountResult % Rec % RecResult
Spike
Amount
% Rec
Limits RPD
RPD
Limit
dba ALS Environmental
ALS Group USA, Corp.
QA/QC Report
50.9 50.0Toluene 304 52-15298 50.048.8 102
53.1 50.0trans-1,2-Dichloroethene 302 75-121104 50.051.9 106
47.2 50.0trans-1,3-Dichloropropene 301 76-11893 50.046.6 94
45.9 50.0trans-1,4-Dichloro-2-butene 302 10-19890 50.044.8 92
54.3 50.0Trichloroethene (TCE)30<1 78-122108 50.054.0 109
54.7 50.0Trichlorofluoromethane 30<1 58-134108 50.054.3 109
49.9 50.0Vinyl Acetate 301 36-169101 50.050.4 100
48.4 50.0Vinyl Chloride 301 69-13896 50.048.0 97
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:22:58 PM Page 37 of 45
Sample Matrix:Ground Water
SURROGATE RECOVERY SUMMARY
Analysis Method:8011
Extraction Method:Method
Sample Name Lab Code
1,1,1,2-Tetrachloroethane
70 - 130
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
MW-1 J1602198-001 95
CD-1 J1602198-002 107
CD-2 J1602198-003 109
CD-3 J1602198-004 103
EQ Blank J1602198-005 104
Method Blank JQ1602471-01 96
Lab Control Sample JQ1602471-02 107
MW-1 JQ1602471-03 100
MW-1 JQ1602471-04 105
ALS Group USA, Corp.
QA/QC Report
Client:
Project:North Wake C&D Landfill
Wake County Solid Waste Management Service Request:J1602198
dba ALS Environmental
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:23:02 PM
Page 38 of 45
QA/QC Report
ug/L
J1602198-001 Basis:Lab Code:
Units:Sample Name:MW-1
1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography
Duplicate Matrix Spike Summary
NA
Client:
Project:
Sample Matrix:
Wake County Solid Waste Management
North Wake C&D Landfill
Ground Water
Service Request:
Date Analyzed:
Date Received:
J1602198
03/29/16
03/26/16
Date Collected:03/24/16
Method
8011
Prep Method:
Analysis Method:
Analyte Name
RPD
LimitRPDResult
Sample
Result
Spike
Amount % Rec
Matrix Spike
JQ1602471-03 JQ1602471-04
Duplicate Matrix Spike
% Rec
Spike
AmountResult
% Rec
Limits
ALS Group USA, Corp.
dba ALS Environmental
03/29/16Date Extracted:
1,2-Dibromo-3-chloropropane (DBCP)0.00700 U 0.265 0.245 108 0.239 0.249 96 65-135 10 20
1,2-Dibromoethane (EDB)0.00700 U 0.269 0.245 110 0.252 0.249 101 65-135 7 20
Results flagged with an asterisk (*) indicate values outside control criteria.
Results flagged with a pound (#) indicate the control criteria is not applicable.
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
Printed 4/5/2016 7:23:01 PM 16-0000370084 rev 00Superset Reference:Page 39 of 45
QA/QC Report
ug/L
J1602198-004 Basis:Lab Code:
Units:Sample Name:CD-3
Inorganic Parameters
Duplicate Matrix Spike Summary
NA
Client:
Project:
Sample Matrix:
Wake County Solid Waste Management
North Wake C&D Landfill
Ground Water
Service Request:
Date Analyzed:
Date Received:
J1602198
03/29/16
03/26/16
Date Collected:03/25/16
EPA 3005A
6010C
Prep Method:
Analysis Method:
Analyte Name
RPD
LimitRPDResult
Sample
Result
Spike
Amount % Rec
Matrix Spike
J1602198-004MS J1602198-004DMS
Duplicate Matrix Spike
% Rec
Spike
AmountResult
% Rec
Limits
ALS Group USA, Corp.
dba ALS Environmental
03/28/16Date Extracted:
Arsenic, Total 3 J 517 500 103 505 500 100 75-125 2 20
Barium, Total 50 J 590 500 106 570 500 104 75-125 2 20
Cadmium, Total 0.2 U 254 250 102 249 250 100 75-125 2 20
Chromium, Total 0.4 U 527 500 105 517 500 103 75-125 2 20
Lead, Total 2 U 498 500 100 490 500 98 75-125 2 20
Selenium, Total 3 U 508 500 102 496 500 99 75-125 2 20
Silver, Total 0.6 U 528 500 106 519 500 104 75-125 2 20
Results flagged with an asterisk (*) indicate values outside control criteria.
Results flagged with a pound (#) indicate the control criteria is not applicable.
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
Printed 4/5/2016 7:23:03 PM 16-0000370084 rev 00Superset Reference:Page 40 of 45
QA/QC Report
ug/L
J1602198-003 Basis:Lab Code:
Units:Sample Name:CD-2
Inorganic Parameters
Duplicate Matrix Spike Summary
NA
Client:
Project:
Sample Matrix:
Wake County Solid Waste Management
North Wake C&D Landfill
Ground Water
Service Request:
Date Analyzed:
Date Received:
J1602198
03/29/16
03/26/16
Date Collected:03/25/16
Method
7470A
Prep Method:
Analysis Method:
Analyte Name
RPD
LimitRPDResult
Sample
Result
Spike
Amount % Rec
Matrix Spike
J1602198-003MS J1602198-003DMS
Duplicate Matrix Spike
% Rec
Spike
AmountResult
% Rec
Limits
ALS Group USA, Corp.
dba ALS Environmental
03/29/16Date Extracted:
Mercury, Total 0.02 U 1.2 1.25 98 1.3 1.25 102 75-125 3 20
Results flagged with an asterisk (*) indicate values outside control criteria.
Results flagged with a pound (#) indicate the control criteria is not applicable.
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
Printed 4/5/2016 7:23:04 PM 16-0000370084 rev 00Superset Reference:Page 41 of 45
Analyte Name
J1602198
Date Analyzed:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Lab Control Sample Summary
Inorganic Parameters
NA
ug/L
Basis:
Units:
Lab Control Sample
J1602198-LCS
03/29/16
Spike AmountResult % Rec % Rec LimitsAnalytical Method
dba ALS Environmental
ALS Group USA, Corp.
QA/QC Report
Arsenic, Total 80-120102 500509 6010C
Barium, Total 80-120105 500523 6010C
Cadmium, Total 80-120101 250253 6010C
Chromium, Total 80-120104 500520 6010C
Lead, Total 80-120101 500505 6010C
Selenium, Total 80-120102 500512 6010C
Silver, Total 80-120105 500523 6010C
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:23:04 PM Page 42 of 45
Analyte Name
J1602198
Date Analyzed:
Service Request:
Ground Water
North Wake C&D Landfill
Wake County Solid Waste Management
Sample Matrix:
Project:
Client:
Lab Control Sample Summary
Inorganic Parameters
NA
ug/L
Basis:
Units:
Lab Control Sample
J1602198-LCS
03/29/16
Spike AmountResult % Rec % Rec LimitsAnalytical Method
dba ALS Environmental
ALS Group USA, Corp.
QA/QC Report
Mercury, Total 80-120102 1.251.28 7470A
16-0000370084 rev 00Superset Reference:Printed 4/5/2016 7:23:04 PM Page 43 of 45
Page 44 of 45
Page 45 of 45
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