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HomeMy WebLinkAbout9214_HollySpringsCDLF_GWMR_DIN28094_20160623 PREPARED FOR: REPUBLIC SERVICES OF NORTH CAROLINA, LLC 4300 OLD HOLLY SPRINGS ROAD APEX, NORTH CAROLINA 27539 CLOSED HOLLY SPRINGS C&D LANDFILL PERMIT NO. 92-14 FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2016 JULY 2016 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE ENGINEERING PROJECT NO. 00895.1601.12 ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 i EXECUTIVE SUMMARY This report presents the results of the first semiannual water quality monitoring event of 2016 conducted at the closed Holly Springs C&D Landfill on June 23, 2016. Samples were collected by representatives of Joyce Engineering from groundwater monitoring wells. The analytical results from the June 23, 2016, monitoring event have been reported by Analytical Services, Inc. of Norcross, Georgia under NC laboratory certification number 381. During the June 2016 water quality monitoring event, five inorganic constituents (arsenic, barium, chromium, lead and selenium) were reported at quantified concentrations above the Solid Waste Section Report Limit (SWSL) in samples from one or more downgradient monitoring wells. No organic constituents were detected at quantified concentrations above SWSLs in samples from downgradient monitoring wells during the June 2016 event. Arsenic, barium, chromium, and lead were reported above the respective groundwater standards established in 15A NCAC 2L.0202 (NC 2L Standards) in MW-9. Arsenic was detected above the NC 2L Standard in MW-12. The arsenic detected in MW-12 is consistent with historical data and is most likely naturally occurring. The elevated metals concentrations detected in MW-9 appear to be related to higher turbidity at the time of sampling. No other constituents were reported above their respective NC 2L standards during the June 2016 event. Based on the results summarized herein, Republic Services of NC, LLC, will continue monitoring the uppermost aquifer beneath the closed Holly Springs C&D Landfill in accordance with the requirements outlined in Title 15A NCAC 13B.0500. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 ii First Semiannual Water Quality Monitoring Report of 2016 Closed Holly Springs C&D Landfill, Permit No. 94-14 Wake County, North Carolina TABLE OF CONTENTS 1.0  INTRODUCTION ........................................................................................................................... 1  1.1  Site Description and Background ................................................................................................ 1  1.2 Compliance Monitoring History .................................................................................................. 1  1.3 Hydrogeologic Setting ................................................................................................................. 1  2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ........................................ 2  2.1 Visual Inspection Program .......................................................................................................... 2  2.2 Well Network and Groundwater Elevation Measurements ......................................................... 3  2.3 June 2016 Monitoring Event ....................................................................................................... 3  2.4 Laboratory Analysis Program ...................................................................................................... 4  2.5 June 2016 Sampling Results ........................................................................................................ 4  3.0 LABORATORY AND FIELD QA/QC ........................................................................................... 4  4.0 DATA EVALUTION ...................................................................................................................... 5  4.1 Comparisons to Groundwater and Surface Water Standards ....................................................... 5  4.2 Statistical Evaluations.................................................................................................................. 5  5.0 CONCLUSIONS ............................................................................................................................. 6  6.0 REFERENCES ................................................................................................................................ 6  TABLES Table 1 Historical Groundwater Elevations Table 2 Hydraulic Gradients and Linear Groundwater Velocities Table 3 Field Parameters by Location Table 4 Quantified Detections by Monitoring Location Table 5 Exceedances of Standards by Monitoring Location DRAWING Drawing 1 Groundwater Potentiometric Surface Map – June 23, 2016 APPENDICES Appendix A Groundwater and Surface Water Field Data Logs Appendix B June 2016 Laboratory Analytical Report Appendix C Historical Groundwater Constituents in Groundwater Appendix D Historical Surface Water Constituents in Surface Water Appendix E Statistical Analyses Worksheets ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 1 1.0 INTRODUCTION This report summarizes the monitoring results from the June 23, 2016, water quality monitoring event at the closed Holly Springs Construction & Demolition (C&D) Landfill in Wake County, North Carolina in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .0500. The closed Holly Springs C&D Landfill is maintained by Republic Services of North Carolina, LLC (Republic) under Permit No. 92-14 issued by the North Carolina Department of Environment and Natural Resources (DENR). 1.1 Site Description and Background The closed Holly Springs C&D Landfill is located within the town limits of Holly Springs, NC at 4300 Old Holly Springs Apex Road. The landfill is bounded to the north by Ivy Arbor Way, to the east by Old Holly Springs Apex Road, to the south by heavily wooded properties, and to the west by a golf course and wooded areas. The location of the facility is shown on the inlay on Drawing 1. A power line easement runs through the southern portion of the landfill along an east-northeast trending transect. Surrounding land use is primarily rural residential, silvicultural, and commercial. Access to the facility is from Old Holly Springs Apex Road. Topographic elevations at the facility range from approximately 280 to 420 feet above mean sea level. Two small, unnamed perennial streams transect the site in a northwesterly direction toward Little Branch, which is located northwest of the site. The first stream is located in the southwest portion of the site and the second flows from the southeastern corner to the northwest corner of the site. The locations of the streams are shown on Drawing 1. 1.2 Compliance Monitoring History The facility’s current monitoring network is comprised of 12 monitoring wells (MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13), which monitor the uppermost aquifer beneath the facility. Wells MW-1, MW-5, and MW-8 have been decommissioned due to construction activities at the landfill. Two surface water monitoring points are monitored semi-annually: upstream monitoring point SW-1, and downstream monitoring point SW-2. Based on the results of the laboratory analyses, Republic Services of North Carolina, LLC continues to maintain compliance monitoring under Title 15A Subchapter 13B.0500 rules at this facility. 1.3 Hydrogeologic Setting Geologically, the facility is located in the Durham Sub-Basin within the Deep River Triassic Basin in the Piedmont Physiographic Province, east of the Jonesboro Fault zone, where Triassic- aged sediments are situated unconformably upon older igneous and metamorphic rocks of the Carolina Slate Belt (NCGS, 1985). The underlying Triassic sedimentary rocks belong to the Chatham Group, which are composed of conglomerate, arkosic sandstone, siltstone, claystone, and mudstone (Horton and Zullo, 1991). Various dikes and sills are also found in this area. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 2 The groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of unconsolidated sediment, partially weathered rock, and fractured sedimentary rocks. Groundwater depths vary at the site ranging from approximately 6-29 feet below grade. Groundwater elevations obtained during the June 2016 monitoring event, as well as historical groundwater elevations, are summarized in Table 1. Based the on topography shown on Drawing 1, regional groundwater flow in the uppermost aquifer beneath the site is expected to be generally to the northwest toward Little Branch. The hydraulic gradients in the uppermost aquifer underlying the site, as measured along the conceptual flow paths shown on the June 2016 potentiometric surface map (Drawing 1), were calculated to be approximately 0.044 to 0.167 ft/ft (Table 2). The estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne Where Vgw = average linear groundwater velocity (feet per day), K = hydraulic conductivity (feet per day), i = horizontal hydraulic gradient, and ne = effective porosity. Since we have no data on hydraulic conductivity or effective porosity from this facility, we used estimated values based on the average of values for these parameters reported for three other landfills located in Wake County. The average estimated linear groundwater flow velocity under the waste management unit is approximately 0.294 to 1.111 ft/day (Table 2). Flow is generally toward the northwest, although local flow directions vary (Drawing 1). The linear velocity equation and resultant rates are based on the simplifying assumptions of a homogeneous and isotropic aquifer, and may not be accurate when applied to heterogeneous and/or anisotropic conditions. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted as part of the June 2016 monitoring event are discussed in the following sections. 2.1 Visual Inspection Program In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the closed Holly Springs C&D Landfill. This inspection program involves field personnel making the following observations:  Observation of stress induced on the biological community (e.g., dead or dying vegetation);  Indications of leachate impact (e.g., seeps, impacted surface water);  Observations of erosion; and  Negative changes around the waste facility. During the June 2016 monitoring event, no physical indicators were observed in the vicinity of ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 3 the waste management areas. 2.2 Well Network and Groundwater Elevation Measurements The network of groundwater monitoring wells at the closed Holly Springs C&D Landfill consists of 12 wells (MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13). Monitoring well locations are shown on Drawing 1. The network of monitoring wells was constructed to target the preferential flow path for groundwater underlying waste disposal areas. One upstream (SW-1) and one downstream (SW-2) surface water points are also monitored. Monitoring wells MW-1R and MW-10 are the facility’s background wells and are located hydraulically upgradient of the waste disposal area in the southeast portion of the site. The other monitoring wells are located downgradient or sidegradient of the waste disposal area. 2.3 June 2016 Monitoring Event Personnel from Joyce Engineering visited the facility on June 23, 2016, to purge and sample monitoring wells MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13. Surface water point SW-1 was dry and unable to be sampled during the June 23, 2016, monitoring event; however, a sample was collected from SW-2. Depth-to-water measurements were obtained from the network monitoring wells to the nearest 0.01 foot using an electronic water level indicator prior to purging the wells. Monitoring well groundwater elevations for this event are presented in Table 1. A groundwater potentiometric surface map based on June 23, 2016, measurements is shown on Drawing 1. The monitoring wells were purged and sampled using dedicated pumps and micropurge procedures. For all of the monitoring wells, measurements of pH, conductivity, dissolved oxygen, oxidation-reduction potential, temperature, and turbidity were recorded on approximately 1 to 3-minute intervals during the purge, depending on the purge rate. In general, the purge rate for each well was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to water, up to a maximum purge rate of 500 milliliters per minute. Purging was continued until stabilization was indicated by the field parameters. In general, stabilization was deemed to be complete once the range in measured values for each required field parameter was less than 10% over three monitoring intervals. The field parameter data for each well/sample point prior to sampling are presented in Table 3, and field sampling logs are included in Appendix A. Each log includes a description of the sampling location, sampling equipment, sampling method, field observations, and field parameter measurements. Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample container was labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The required groundwater samples were collected directly from the pump discharge tubing in the laboratory- supplied, pre-preserved sample containers after purging was completed based on stabilization of the field parameters. After collection, the samples were placed in a cooler on ice, under chain- of-custody control. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 4 2.4 Laboratory Analysis Program The June 2016 groundwater and surface water samples were submitted to Analytical Services, Inc. of Norcross, Georgia under chain-of-custody control for analysis. The groundwater samples, including the Field Blank, were analyzed for RCRA Metals and North Carolina Appendix I VOCs plus tetrahydrofuran. The Trip Blank was analyzed for North Carolina Appendix I VOCs plus tetrahydrofuran only. Joyce Engineering requested a Level II data report for the final laboratory report. The samples were received by the laboratory on June 24, 2016, in good condition, properly preserved, and within analysis hold times. The laboratory certificates- of-analysis and chains-of-custody for the monitoring event are included in Appendix B. 2.5 June 2016 Sampling Results Constituents detected at quantified concentrations above the Solid Waste Section Reporting Limits (SWSLs) during the June 2016 sampling event are presented in Table 4. Constituents detected above applicable groundwater or surface water standards during the June 2016 sampling event are presented in Table 5. Historical groundwater and surface water analytical data are included in Appendices C and D, respectively. Five RCRA metals (arsenic, barium, chromium, lead and selenium) were detected in samples from downgradient compliance monitoring wells at quantified concentrations above their respective SWSLs. The detections are as follows: arsenic in MW-9 and MW-12; barium in MW-1R, MW-5R, MW-6, MW-7, MW-9, MW-12, and MW-13 and chromium, lead and selenium in MW-9. No organic constituents were detected above their respective SWSLs during the June 2016 monitoring event. Arsenic, barium, chromium, and lead were reported above their respective NC 2L Standards in MW-9. Arsenic was detected above the NC 2L Standard in MW-12. Arsenic detected at 25.6 µg/L in MW-9 exceeds the intrawell statistical background concentration (14.2 µg/L). Barium detected at 972 µg/L im MW-9 exceeds the intrawell statistical background concentration (398 µg/L). No other detections were above the statistical background concentration (see Section 4.2). 3.0 LABORATORY AND FIELD QA/QC A Field Blank was collected by Joyce Engineering personnel as part of the June 2016 monitoring event. In addition to the Field Blank, a laboratory-prepared Trip Blank accompanied the volatile sample containers for the sampling event to and from the laboratory. The Field Blank was analyzed for 8 RCRA metals, NC Appendix I VOCs constituents plus tetrahydrofuran and the Trip Blank for NC Appendix I VOCs only plus tetrahydrofuran. In addition to the Field and Trip Blanks, at least one Method Blank was analyzed by the laboratory for each method used. Upon receipt of the laboratory data package, the data was reviewed by Joyce Engineering personnel for the following: ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 5  General typographical errors;  Correct analyses performed and within method specified hold times;  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples;  Blank-qualified data (B-flags);  Detections above the groundwater and surface water standards; and  Detections that are above historical levels. 4.0 DATA EVALUTION 4.1 Comparisons to Groundwater and Surface Water Standards Four inorganic constituent, arsenic, barium, chromium, and lead were reported at a concentration above their NC 2L Standard during the June 2016 sampling event (Table 5). Arsenic was detected in exceedance of NC 2L in MW-12 and MW-9. The concentration of arsenic in MW-12 is generally consistent with historical data and the historical data indicate arsenic is naturally occurring in both upgradient and downgradient wells. Wake County has been identified as an area of North Carolina with a high probability of naturally occurring arsenic as presented in the October 2003 DENR document “Distribution of Total Arsenic in Groundwater in the North Carolina Piedmont”. No other constituents detected in downgradient monitoring wells were reported above their respective NC 2L standards during the June 2016 event. Arsenic, barium, chromium and lead were detected at quantified concentrations above their respective NC 2L Standards in MW-9. These detections were higher than historical data. The higher concentrations can be attributed to higher turbidity and lower pH as measured at the time of sampling. Due to dry seasonal conditions, only one surface water sample (SW-2) was obtained during the June 2016 monitoring event. There was not enough running water to sample SW-1. There were no quantified detections found in the SW-2 sample. 4.2 Statistical Evaluations The data were evaluated through the use of the Shapiro-Wilk Test, Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-parametric Prediction Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are used, as appropriate based on the background data. The statistical test by which downgradient data are compared to facility background data is based upon the nature of the data and the number of data values that are less than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed tests. For interwell statistical evaluation, the results from downgradient wells are compared to the statistical background based on the historical data from the facility’s upgradient background well. Alternatively, intrawell statistical evaluation may be used to determine the background for a ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 6 specific monitoring well. For intrawell statistical evaluation, the data from most recent six sampling events are excluded and the earlier data are used for the background in the statistical evaluation for comparison with the most recent result for a given constituent. Arsenic, barium, chromium and lead were detected at quantified concentrations above their respective NC 2L in MW-9. Arsenic was also in exceedance of NC 2L in MW-12. These detections were each evaluated using intrawell statistics in accordance with the procedures outlined in 15A NCAC 13B.1632.(g) and (h) to determine if the quantified concentration exceeded the facility background concentration. The statistical worksheets and summary table are presented in Appendix E, and results are summarized below. Constituent NC 2L Statistical Background Sample Location Sample Result SSI Arsenic 10 29.2 MW-12 23.5 NO Arsenic 10 14.2 MW-9 25.6 YES Barium 700 398 MW-9 972 YES Chromium 10 102.8 MW-9 28.8 NO Lead 15 108.5 MW-9 41.3 NO Concentrations are in micrograms per liter (µg/L). SSI = Statistically significant increase over background. 5.0 CONCLUSIONS We recommend redeveloping MW-9 prior to next sampling event to reduce the turbidity and therefore reduce the total metals concentration. Based on the results summarized herein, Republic Services of NC, LLC, will continue monitoring the uppermost aquifer beneath the closed Holly Springs C&D Landfill in accordance with the requirements for Detection Monitoring Program as outlined in Title 15A NCAC 13B.0500. The next compliance monitoring event for this facility is tentatively scheduled for December 2016. 6.0 REFERENCES ESP Associates, P.A., 1997, Construction Quality Assurance (CQA) Submittal Holly Springs Disposal, Inc. C&D Landfill Expansion-Cell 7, Phase A, July 30. ESP Associates, P.A, 2003, Addendum to Permit 92-14 Holly Springs C&D Landfill Proposed Cell 8 Expansion, February. ESP Associates, P.A, 2003. Application for Permit to Operate a Construction & Demolition Debris (C&D) Landfill-Holly Springs C&D Landfill Cell 8, Construction Quality Assurance (CQA) Submittal BFI Waste Systems of North America, Inc., June. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 July 2016 7 Golder Associates NC, Inc., September 2011. Second Semi-Annual 2011 Sampling Event. Prepared for Republic Services of North Carolina, LLC. North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. North Carolina Geologic Survey, 1985, Geologic Map of North Carolina; North Carolina Department of Natural Resources and Community Development, Geological Survey Section; scale 1:500,000. Pippin, Charles G., Michele Butczynski, and Jonathan Clayton, 2003, Distribution of Total Arsenic in Groundwater in the North Carolina Piedmont. Department of Environment and Natural Resources Groundwater Section Resource Evaluation Program; Mooresville Regional Office, October 3. United States Environmental Protection Agency, 2003, Guidance for Developing Ecological Soil Screening Levels. November. TABLES TA B L E 1 Hi s t o r i c a l G r o u n d w a t e r E l e v a t i o n s Cl o s e d H o l l y S p r i n g s C a n d D L a n d f i l l , P e r m i t N o . 9 2 - 1 4 Wa k e C o u n t y , N o r t h C a r o l i n a Lo c a t i o n MW - 1 R M W - 2 M W - 3 M W - 4 M W - 5 R M W - 6 M W - 7 M W - 9 M W - 1 0 M W - 1 1 M W - 1 2 M W - 1 3 TO C E l e v a t i o n : 37 9 . 6 3 3 9 1 . 1 9 3 7 0 . 3 6 3 1 5 . 3 7 3 1 1 . 9 0 3 2 7 . 9 0 2 8 6 . 1 0 3 0 7 . 8 0 3 8 2 . 9 0 2 9 1 . 5 0 2 9 4 . 0 0 3 3 7 . 5 7 22 - J u l - 0 9 35 8 . 8 1 3 6 2 . 5 1 3 5 9 . 1 4 2 9 7 . 7 9 3 0 4 . 6 9 3 1 6 . 8 7 2 7 8 . 8 7 2 9 5 . 7 8 3 6 0 . 2 4 2 7 9 . 7 2 2 8 4 . 5 0 3 2 6 . 6 7 26 - J a n - 1 0 36 1 . 9 5 3 5 9 . 9 0 3 6 4 . 3 4 2 9 8 . 5 7 3 0 6 . 6 5 3 1 7 . 8 8 2 8 1 . 2 9 2 9 8 . 0 7 3 6 1 . 4 5 2 8 0 . 8 1 2 8 5 . 6 5 3 2 7 . 2 8 7- J u l - 1 0 35 6 . 3 2 3 6 3 . 4 1 3 5 8 . 6 1 2 9 8 . 3 0 3 0 4 . 1 9 3 1 6 . 5 7 2 7 8 . 6 3 2 9 6 . 2 3 3 6 1 . 1 2 2 7 8 . 7 6 2 8 4 . 3 2 3 2 5 . 1 5 5- J a n - 1 1 36 2 . 5 5 3 6 0 . 0 0 3 5 8 . 7 1 2 9 7 . 8 5 3 0 4 . 3 1 3 1 7 . 1 9 2 7 9 . 6 9 2 9 5 . 1 2 3 6 0 . 4 5 2 8 0 . 3 6 2 8 4 . 8 4 3 2 6 . 9 2 7- J u l - 1 1 35 6 . 8 9 3 5 8 . 6 9 3 5 8 . 7 3 2 9 7 . 9 6 3 0 5 . 0 1 3 1 7 . 4 5 2 7 9 . 2 3 2 9 6 . 6 1 3 6 0 . 6 6 2 8 0 . 1 5 2 8 4 . 6 3 3 2 6 . 8 5 12 - J a n - 1 2 35 7 . 7 2 3 5 7 . 7 3 3 5 9 . 5 4 2 9 8 . 7 6 3 0 5 . 0 2 3 1 7 . 6 1 2 8 0 . 3 2 2 9 6 . 1 5 3 6 0 . 6 8 2 8 0 . 4 8 2 8 4 . 9 3 3 2 7 . 2 8 12 - J u l - 1 2 35 7 . 7 9 3 5 7 . 5 4 3 5 9 . 1 7 2 9 7 . 6 0 3 0 4 . 2 9 3 1 7 . 0 8 2 7 8 . 8 9 2 9 5 . 7 8 3 6 0 . 3 5 2 7 9 . 3 5 2 8 4 . 4 4 3 2 6 . 3 2 6- F e b - 1 3 36 0 . 1 7 3 5 6 . 0 7 3 5 9 . 5 5 2 9 7 . 0 6 3 0 4 . 8 5 3 1 6 . 5 8 2 7 9 . 8 2 2 9 6 . 9 1 3 5 9 . 6 9 2 7 9 . 9 7 2 8 4 . 6 6 3 2 7 . 0 2 9- J u l - 1 3 35 5 . 7 8 3 5 7 . 3 8 3 5 9 . 4 5 2 9 7 . 5 6 3 0 4 . 2 9 3 1 6 . 9 9 2 8 0 . 2 9 2 9 7 . 8 9 3 6 3 . 0 5 2 7 9 . 2 5 2 8 4 . 7 9 3 2 7 . 5 4 31 - J a n - 1 4 35 7 . 6 2 3 5 6 . 1 0 3 5 9 . 5 2 2 9 6 . 9 7 3 0 4 . 8 1 3 1 6 . 6 0 2 7 9 . 7 9 2 9 6 . 8 9 3 5 9 . 6 4 2 8 0 . 0 0 2 8 4 . 6 0 3 2 6 . 9 8 23 - J u l - 1 4 35 7 . 5 3 3 6 0 . 2 9 3 5 8 . 9 1 2 9 8 . 2 7 3 0 5 . 1 5 3 1 7 . 7 0 2 7 9 . 4 0 2 9 5 . 3 4 3 6 1 . 2 2 2 8 0 . 2 6 2 8 4 . 4 8 3 2 7 . 0 2 27 - J a n - 1 5 36 1 . 3 0 3 5 4 . 7 4 3 6 4 . 4 4 2 9 8 . 4 3 3 0 7 . 2 3 3 1 8 . 9 0 2 8 0 . 7 0 2 9 7 . 2 9 3 6 3 . 9 8 2 8 1 . 5 0 2 8 5 . 5 5 3 2 7 . 7 2 29 - J u l - 1 5 35 8 . 5 8 3 6 2 . 2 9 3 5 8 . 4 6 2 9 8 . 3 9 3 0 5 . 0 0 3 1 7 . 6 6 2 7 9 . 2 6 2 9 7 . 0 1 3 6 1 . 9 0 2 8 0 . 2 3 2 8 4 . 3 4 3 2 6 . 8 7 23 - J u n - 1 6 36 1 . 3 8 3 6 3 . 7 0 3 6 0 . 0 6 2 9 9 . 0 2 3 0 5 . 0 9 3 1 8 . 3 0 2 7 9 . 7 3 2 9 7 . 2 8 3 6 2 . 6 0 2 8 0 . 4 5 2 8 4 . 4 8 3 2 6 . 3 7 ME A N : 35 8 . 6 9 3 5 8 . 9 7 3 5 9 . 8 9 2 9 7 . 9 6 3 0 5 . 0 4 3 1 7 . 3 1 2 7 9 . 7 1 2 9 6 . 5 4 3 6 1 . 1 1 2 8 0 . 0 6 2 8 4 . 7 5 3 2 6 . 8 9 MA X I M U M : 36 2 . 5 5 3 6 3 . 4 1 3 6 4 . 4 4 2 9 8 . 7 6 3 0 7 . 2 3 3 1 8 . 9 0 2 8 1 . 2 9 2 9 8 . 0 7 3 6 3 . 9 8 2 8 1 . 5 0 2 8 5 . 6 5 3 2 7 . 7 2 MI N I M U M : 35 5 . 7 8 3 5 4 . 7 4 3 5 8 . 4 6 2 9 6 . 9 7 3 0 4 . 1 9 3 1 6 . 5 7 2 7 8 . 6 3 2 9 5 . 1 2 3 5 9 . 6 4 2 7 8 . 7 6 2 8 4 . 3 2 3 2 5 . 1 5 No t e s : Al l m e a s u r e m e n t s a r e g i v e n i n f e e t A M S L ( a b o v e m e a n s e a l e v e l ) TO C = T o p o f c a s i n g . Th e T O C e l e v a t i o n f o r M W - 1 2 i s a p p r o x i m a t e . -- = N o d a t a a v a i l a b l e . Al l d a t a p r i o r t o 2 0 1 2 t a k e n f r o m p r e v i o u s r e p o r t s b y G o l d e r A s s o c i a t e s N C , I n c . Re p u b l i c - H o l l y S p r i n g s L a n d f i l l Pe r m i t N o . 9 2 - 1 4 Joyce Engineering Inc. TA B L E 2 Hy d r a u l i c G r a d i e n t s a n d L i n e a r G r o u n d w a t e r V e l o c i t i e s Cl o s e d H o l l y S p r i n g s C a n d D L a n d f i l l , P e r m i t N o . 9 2 - 1 4 Wa k e C o u n t y , N o r t h C a r o l i n a Gr o u n d w a t e r H o r i z o n t a l H y d r a u l i c E f f e c t i v e L i n e a r Se g m e n t C o n t o u r s G r a d i e n t C o n d u c t i v i t y P o r o s i t y V e l o c i t y Le n g t h (B e g i n n i n g / E n d ) iK n e V gw ( l i n e a r f e e t ) (f e e t A M S L ) ( f t / f t ) (f t / d a y ) (ft/day) 36 0 30 0 34 0 30 0 34 0 30 0 36 0 32 0 36 0 31 0 36 0 33 0 AV E R A G E : 0 . 0 7 7 A V E R A G E : 0 . 5 1 5 No t e s : Ho r i z o n t a l v e l o c i t i e s b a s e d o n t h e m o d i f i e d D a r c y e q u a t i o n V gw = K i / n e Va l u e s f o r K a n d n e w e r e o b t a i n e d b y t a k i n g t h e a v e r a g e s o f K a n d n e r e p o r t e d f o r t h r e e o t h e r l a n d f i l l s i n W a k e C o u n t y , N C b as e d o n r e c e n t d o c u m e n t s f o u n d o n t h e D E N R ' s C A R A 3 Po r t a l . Gr a d i e n t s e g m e n t s a r e b a s e d o n t h e J u n e 2 0 1 6 g r o u n d w a t e r c o n t o u r s a s s h o w n o n D r a w i n g 1 . Ju n e 2 0 1 6 0.548 i 6 36 5 W 0. 0 8 2 1. 0 0. 1 5 0.318 i 5 30 0 SW 0. 1 6 7 1. 0 0. 1 5 1.1110.294 i 2 74 5 i 4 83 9 NE 0. 0 4 8 1. 0 0. 1 5 i 3 90 7 NW 0. 0 4 4 1. 0 0. 1 5 Gr a d i e n t Ca l c u l a t i o n Se g m e n t Fl o w Di r e c t i o n i 1 86 6 N 0. 0 6 9 1. 0 0. 1 5 0.462 W 0. 0 5 4 1. 0 0. 1 5 0.358 Re p u b l i c - H o l l y S p r i n g s L a n d f i l l Pe r m i t N o . 9 2 - 1 4 Joyce Engineering Inc. TABLE 3: Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 9214-MW1R Temperature 17.7 °C 6/23/2016 9214-MW1R Dissolved Oxygen 1.93 mg/L 6/23/2016 9214-MW1R Conductivity 315.1 µs/cm 6/23/2016 9214-MW1R pH 5.42 S.U. 6/23/2016 9214-MW1R Oxidation Reduction Potential 48 mV 6/23/2016 9214-MW1R Turbidity 3.49 NTU 6/23/2016 9214-MW1R Static Water Level 18.25 ft 6/23/2016 9214-MW1R Well Depth 54.60 ft 6/23/2016 9214-MW2 Temperature 16.7 °C 6/23/2016 9214-MW2 Dissolved Oxygen 0.59 mg/L 6/23/2016 9214-MW2 Conductivity 222.7 µs/cm 6/23/2016 9214-MW2 pH 5.54 S.U. 6/23/2016 9214-MW2 Oxidation Reduction Potential 56.3 mV 6/23/2016 9214-MW2 Turbidity 4.30 NTU 6/23/2016 9214-MW2 Static Water Level 27.49 ft 6/23/2016 9214-MW2 Well Depth 47.50 ft 6/23/2016 9214-MW3 Temperature 18.4 °C 6/23/2016 9214-MW3 Dissolved Oxygen 2.67 mg/L 6/23/2016 9214-MW3 Conductivity 73.4 µs/cm 6/23/2016 9214-MW3 pH 5.36 S.U. 6/23/2016 9214-MW3 Oxidation Reduction Potential 8.2 mV 6/23/2016 9214-MW3 Turbidity 5.05 NTU 6/23/2016 9214-MW3 Static Water Level 10.30 ft 6/23/2016 9214-MW3 Well Depth 35.39 ft 6/23/2016 9214-MW4 Temperature 15.8 °C 6/23/2016 9214-MW4 Dissolved Oxygen 1.60 mg/L 6/23/2016 9214-MW4 Conductivity 126.8 µs/cm 6/23/2016 9214-MW4 pH 5.2 S.U. 6/23/2016 9214-MW4 Oxidation Reduction Potential 93.1 mV 6/23/2016 9214-MW4 Turbidity 3.00 NTU 6/23/2016 9214-MW4 Static Water Level 16.35 ft 6/23/2016 9214-MW4 Well Depth 34.88 ft 6/23/2016 9214-MW5R Temperature 15.6 °C 6/23/2016 9214-MW5R Dissolved Oxygen 0.40 mg/L 6/23/2016 9214-MW5R Conductivity 679 µs/cm 6/23/2016 9214-MW5R pH 4.75 S.U. 6/23/2016 9214-MW5R Oxidation Reduction Potential 66.0 mV 6/23/2016 9214-MW5R Turbidity 4.79 NTU 6/23/2016 9214-MW5R Static Water Level 6.81 ft 6/23/2016 9214-MW5R Well Depth 24.21 ft 6/23/2016 Republic- Holly Springs Landfill Permit No. 92-14 Page 1 of 3 Joyce Engineering TABLE 3: Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 9214-MW6 Temperature 16.7 °C 6/23/2016 9214-MW6 Dissolved Oxygen 1.07 mg/L 6/23/2016 9214-MW6 Conductivity 313.5 µs/cm 6/23/2016 9214-MW6 pH 4.69 S.U. 6/23/2016 9214-MW6 Oxidation Reduction Potential 60.2 mV 6/23/2016 9214-MW6 Turbidity 1.32 NTU 6/23/2016 9214-MW6 Static Water Level 9.60 ft 6/23/2016 9214-MW6 Well Depth 21.4 ft 6/23/2016 9214-MW7 Temperature 15.7 °C 6/23/2016 9214-MW7 Dissolved Oxygen 0.81 mg/L 6/23/2016 9214-MW7 Conductivity 197.2 µs/cm 6/23/2016 9214-MW7 pH 4.47 S.U. 6/23/2016 9214-MW7 Oxidation Reduction Potential 88.0 mV 6/23/2016 9214-MW7 Turbidity 2.11 NTU 6/23/2016 9214-MW7 Static Water Level 6.37 ft 6/23/2016 9214-MW7 Well Depth 24.2 ft 6/23/2016 9214-MW9 Temperature 15.7 °C 6/23/2016 9214-MW9 Dissolved Oxygen 0.32 mg/L 6/23/2016 9214-MW9 Conductivity 761 µs/cm 6/23/2016 9214-MW9 pH 4.48 S.U. 6/23/2016 9214-MW9 Oxidation Reduction Potential -19.9 mV 6/23/2016 9214-MW9 Turbidity 97.3 NTU 6/23/2016 9214-MW9 Static Water Level 10.52 ft 6/23/2016 9214-MW9 Well Depth 23.80 ft 6/23/2016 9214-MW10 Temperature 17.7 °C 6/23/2016 9214-MW10 Dissolved Oxygen 2.7 mg/L 6/23/2016 9214-MW10 Conductivity 122.9 µs/cm 6/23/2016 9214-MW10 pH 5.54 S.U. 6/23/2016 9214-MW10 Oxidation Reduction Potential 59.7 mV 6/23/2016 9214-MW10 Turbidity 4.47 NTU 6/23/2016 9214-MW10 Static Water Level 20.30 ft 6/23/2016 9214-MW10 Well Depth 47.00 ft 6/23/2016 9214-MW11 Temperature 15.5 °C 6/23/2016 9214-MW11 Dissolved Oxygen 0.49 mg/L 6/23/2016 9214-MW11 Conductivity 649 µs/cm 6/23/2016 9214-MW11 pH 4.55 S.U. 6/23/2016 9214-MW11 Oxidation Reduction Potential 89.1 mV 6/23/2016 9214-MW11 Turbidity 1.75 NTU 6/23/2016 9214-MW11 Static Water Level 11.05 ft 6/23/2016 9214-MW11 Well Depth 25.75 ft 6/23/2016 Republic- Holly Springs Landfill Permit No. 92-14 Page 2 of 3 Joyce Engineering TABLE 3: Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 9214-MW12 Temperature 17.2 °C 6/23/2016 9214-MW12 Dissolved Oxygen 2.47 mg/L 6/23/2016 9214-MW12 Conductivity 752 µs/cm 6/23/2016 9214-MW12 pH 4.77 S.U. 6/23/2016 9214-MW12 Oxidation Reduction Potential 15.7 mV 6/23/2016 9214-MW12 Turbidity 11.91 NTU 6/23/2016 9214-MW12 Static Water Level 9.52 ft 6/23/2016 9214-MW12 Well Depth 25.19 ft 6/23/2016 9214-MW13 Temperature 16.2 °C 6/23/2016 9214-MW13 Dissolved Oxygen 0.6 mg/L 6/23/2016 9214-MW13 Conductivity 391.0 µs/cm 6/23/2016 9214-MW13 pH 5.06 S.U. 6/23/2016 9214-MW13 Oxidation Reduction Potential -72.1 mV 6/23/2016 9214-MW13 Turbidity 5.24 NTU 6/23/2016 9214-MW13 Static Water Level 11.20 ft 6/23/2016 9214-MW13 Well Depth 26.68 ft 6/23/2016 9214-SW-2 Temperature 20.1 °C 6/23/2016 9214-SW-2 Dissolved Oxygen 2.0 mg/L 6/23/2016 9214-SW-2 Conductivity 819.0 µs/cm 6/23/2016 9214-SW-2 pH 5.09 S.U. 6/23/2016 9214-SW-2 Oxidation Reduction Potential 87.6 mV 6/23/2016 9214-SW-2 Turbidity 9.17 NTU 6/23/2016 Notes:ºC= degrees Centigrade mg/L - milligrams per liter µs/cm = microsemens per centimeter S.U.= Standard Units mV = millivolts ntu = Nephelometric Turbidity Units ft = feet Republic- Holly Springs Landfill Permit No. 92-14 Page 3 of 3 Joyce Engineering TA B L E 4 : Q u a n t i f i e d D e t e c t i o n s b y M o n i t o r i n g L o c a t i o n WE L L I D PA R A M E T E R R E S U L T U N I T S S W S L D A T E 92 1 4 - M W 1 R To t a l B a r i u m 37 8 µ g / L 1 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 5 R To t a l B a r i u m 13 1 µ g / L 1 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 6 To t a l B a r i u m 31 7 µ g / L 1 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 7 To t a l B a r i u m 16 4 µ g / L 1 0 1 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l A r s e n i c 25 . 6 µg / L 1 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l B a r i u m 97 2 µg / L 1 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 T o t a l C h r o m i u m 28 . 8 µg / L 1 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l L e a d 41 . 3 µg / L 1 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l S e l e n i u m 16 . 7 µ g / L 1 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 1 2 To t a l A r s e n i c 23 . 5 µg / L 1 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 1 2 To t a l B a r i u m 20 5 µ g / L 1 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 1 3 To t a l B a r i u m 26 6 µ g / L 1 0 0 6 / 2 3 / 2 0 1 6 No t e s : µg / L = M i c o r g r a m s p e r l i t e r . SW S L = N C S o i l d W a s t e S e c t i o n R e p o r t i n g L i m i t . La b o r a t o r y R e p o r t i n g l i m i t u s e d w h e n S W S L h a s n o t b e e n e s t a b l i s h e d . J = E s t i m a t e d c o n c e n t r a t i o n b e l o w t h e S W S L . Re p u b l i c - H o l l y S p r i n g s L a n d f i l l Pe r m i t N o . 9 2 - 1 4 Pa g e 1 o f 1 Joyce Engineering TA B L E 5 : E x c e e d a n c e s o f S t a n d a r d s b y M o n i t i o r n g L o c a t i o n WE L L I D PA R A M E T E R RE S U L T U N I T S S W S L NC 2 L / *G W P S GP S D A T E 92 1 4 - M W 9 To t a l A r s e n i c 25 . 6 µ g / L 1 0 1 0 1 4 . 2 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l B a r i u m 97 2 µ g / L 1 0 0 7 0 0 7 0 0 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l C h r o m i u m 28 . 8 µ g / L 1 0 1 0 1 0 2 . 8 6 / 2 3 / 2 0 1 6 92 1 4 - M W 9 To t a l L e a d 41 . 3 µ g / L 1 0 1 5 1 0 8 . 5 6 / 2 3 / 2 0 1 6 92 1 4 - M W 1 2 To t a l A r s e n i c 23 . 5 µ g / L 1 0 1 0 2 9 . 2 6 / 2 3 / 2 0 1 6 No t e s : µ g / L = M i c o r g r a m s p e r l i t e r SW S L = N C S o i l d W a s t e S e c t i o n R e p o r t i n g L i m i t La b o r a t o r y R e p o r t i n g l i m i t u s e d w h e n S W S L h a s n o t b e e n e s t a b l i s h e d NC 2 L = N C G r o u n d w a t e r S t a n d a r d f r o m 1 5 A N C A C 2 L . 0 2 0 2 GW P S = N C S o l i d W a s t e S e c t i o n G r o u n d w a t e r P r o t e c t i o n S t a n d a r d ( f o r c o n s t i t u e n t s w i t h n o N C 2 L ) GP S = G r o u n d w a t e r P r o t e c t i o n S t a n d a r d a s d e f i n e d b y 1 5 A N C A C 1 3 B . 1 6 3 4 ( g ) GP S f o r a r s e n i c , c h r o m i u m , a n d l e a d b a s e d o n s t a t i s t i c a l b a c k g r o u n d . Re p u b l i c - H o l l y S p r i n g s L a n d f i l l Pe r m i t N o . 9 2 - 1 4 Joyce Engineering DRAWING P R O J E C T N O . APPROVED CHECKED DRAWN DESIGNED DATE DATE REVISIONS AND RECORD OF ISSUE BYNO APPCK S C A L E All rights reserved. ” Joyce Engineering, Inc. D R A W I N G N O . L:\Republic NC\Holly Springs\2016 JULY Holly Springs GW Map.dwg Layout=GW map 2211 W. MEADOWVIEW ROAD GREENSBORO, NC 27407 PHONE: (336) 323-0092 NC CORP LIC: C-0782 8 9 5 HOLLY SPRINGS CLOSED C&D LANDFILL WAKE COUNTY, NORTH CAROLINA 2016 1 A S S H O W N GROUNDWATER POTENTIOMETRIC SURFACE MAP JUNE 23, 2016 PERMIT NO. 92-14 GE RH VB VB 07/21/16 V I C I N I T Y M A P 0(FEET)GRAPHIC SCALE20010050 S O U R C E : U . S . G . S . 7 . 5 M I N U T E T O P O F O R A P E X , N C APPENDICES Appendix A Field Data Logs Appendix B Laboratory Analytical Reports PACE ANALYTICAL SERVICES, INC. Environmental Monitoring & Laboratory Analysis 110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 Republic Services of North Carolina, LLC Project: Holly Springs Closed C&D Landfill Conover, NC 28613 1220 Commerce Street, SW Mr. Matt Einsmann We appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, Inc. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed. Laboratory Report Project #:[none] Prepared For: Attention: July 15, 2016 Report Number:AZF0926 Approved: This report may not be reproduced, except in full, without written approval from Pace Analytical Services, Inc. Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Sample ID Laboratory ID Matrix Date Sampled ANALYTICAL REPORT FOR SAMPLES Date Received 9214-MW1R AZF0926-01 06/23/16 09:45 06/24/16 09:45Ground Water 9214-MW2 AZF0926-02 06/23/16 10:40 06/24/16 09:45Ground Water 9214-MW3 AZF0926-03 06/23/16 09:17 06/24/16 09:45Ground Water 9214-MW4 AZF0926-04 06/23/16 11:00 06/24/16 09:45Ground Water 9214-MW5R AZF0926-05 06/23/16 13:18 06/24/16 09:45Ground Water 9214-MW6 AZF0926-06 06/23/16 12:52 06/24/16 09:45Ground Water 9214-MW7 AZF0926-07 06/23/16 11:20 06/24/16 09:45Ground Water 9214-MW9 AZF0926-08 06/23/16 12:18 06/24/16 09:45Ground Water 9214-MW10 AZF0926-09 06/23/16 10:22 06/24/16 09:45Ground Water 9214-MW11 AZF0926-10 06/23/16 11:43 06/24/16 09:45Ground Water 9214-MW12 AZF0926-11 06/23/16 13:44 06/24/16 09:45Ground Water 9214-MW13 AZF0926-12 06/23/16 09:00 06/24/16 09:45Ground Water 9214-SW2 AZF0926-13 06/23/16 11:35 06/24/16 09:45Surface Water 9214-Field Blank AZF0926-14 06/23/16 14:10 06/24/16 09:45Water 9214-Trip Blank AZF0926-15 06/23/16 06:45 06/24/16 09:45Water Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AZF0926-01 AZF092606/23/16 09:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 2.22 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:2307/06/16 10:00 EPA 6020B 378 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:2307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:2307/06/16 10:00 EPA 6020B 0.61 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:2307/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:2307/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:2307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:2307/06/16 10:00 EPA 7470A 0.144 ug/L1Mercury0.200 J 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:2807/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 13:5206/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AZF0926-01 AZF092606/23/16 09:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 13:5206/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AZF0926-01 AZF092606/23/16 09:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 13:5206/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 13:5206/28/16 07:45 EPA 8260B 99 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 13:5206/28/16 07:4580-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 13:5206/28/16 07:4578-120 EPA 8260B 101 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 13:5206/28/16 07:4580-120 EPA 8260B 110 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 13:5206/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AZF0926-02 AZF092606/23/16 10:40 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 5.19 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:2807/06/16 10:00 EPA 6020B 77.3 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:2807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:2807/06/16 10:00 EPA 6020B 1.22 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:2807/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:2807/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:2807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:2807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:3007/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 14:1706/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AZF0926-02 AZF092606/23/16 10:40 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 14:1706/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AZF0926-02 AZF092606/23/16 10:40 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 14:1706/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 14:1706/28/16 07:45 EPA 8260B 98 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 14:1706/28/16 07:4580-120 EPA 8260B 108 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 14:1706/28/16 07:4578-120 EPA 8260B 100 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 14:1706/28/16 07:4580-120 EPA 8260B 107 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 14:1706/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AZF0926-03 AZF092606/23/16 09:17 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 3.39 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:3307/06/16 10:00 EPA 6020B 23.3 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:3307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:3307/06/16 10:00 NDEPA 6020B ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:3307/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:3307/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:3307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:3307/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:3307/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 14:4306/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AZF0926-03 AZF092606/23/16 09:17 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 14:4306/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AZF0926-03 AZF092606/23/16 09:17 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 14:4306/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 14:4306/28/16 07:45 EPA 8260B 96 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 14:4306/28/16 07:4580-120 EPA 8260B 108 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 14:4306/28/16 07:4578-120 EPA 8260B 101 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 14:4306/28/16 07:4580-120 EPA 8260B 107 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 14:4306/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AZF0926-04 AZF092606/23/16 11:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 3.15 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:3807/06/16 10:00 EPA 6020B 74.8 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:3807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:3807/06/16 10:00 NDEPA 6020B ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:3807/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:3807/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:3807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:3807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:3507/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 15:0806/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AZF0926-04 AZF092606/23/16 11:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 15:0806/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AZF0926-04 AZF092606/23/16 11:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 15:0806/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 15:0806/28/16 07:45 EPA 8260B 98 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 15:0806/28/16 07:4580-120 EPA 8260B 108 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 15:0806/28/16 07:4578-120 EPA 8260B 100 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 15:0806/28/16 07:4580-120 EPA 8260B 108 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 15:0806/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AZF0926-05 AZF092606/23/16 13:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 2.75 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:4307/06/16 10:00 EPA 6020B 131 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:4307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:4307/06/16 10:00 EPA 6020B 0.74 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:4307/06/16 10:00 EPA 6020B 0.11 ug/L1Lead10.0 J 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:4307/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:4307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:4307/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:3707/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 15:3406/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AZF0926-05 AZF092606/23/16 13:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 15:3406/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AZF0926-05 AZF092606/23/16 13:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 15:3406/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 15:3406/28/16 07:45 EPA 8260B 98 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 15:3406/28/16 07:4580-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 15:3406/28/16 07:4578-120 EPA 8260B 101 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 15:3406/28/16 07:4580-120 EPA 8260B 110 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 15:3406/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AZF0926-06 AZF092606/23/16 12:52 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 3.16 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 20:5807/06/16 10:00 EPA 6020B 317 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 20:5807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 20:5807/06/16 10:00 EPA 6020B 0.82 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 20:5807/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 20:5807/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 20:5807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 20:5807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:4507/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 15:5906/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AZF0926-06 AZF092606/23/16 12:52 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 15:5906/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AZF0926-06 AZF092606/23/16 12:52 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 15:5906/28/16 07:45 NDEPA 8260B ug/L1Tetrahydrofuran10 6060689EPA 5030B 1.5 109-99-9 06/28/16 15:5906/28/16 07:45 EPA 8260B 99 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 15:5906/28/16 07:4580-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 15:5906/28/16 07:4578-120 EPA 8260B 99 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 15:5906/28/16 07:4580-120 EPA 8260B 106 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 15:5906/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AZF0926-07 AZF092606/23/16 11:20 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 3.07 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:0307/06/16 10:00 EPA 6020B 164 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:0307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:0307/06/16 10:00 NDEPA 6020B ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:0307/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:0307/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:0307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:0307/06/16 10:00 EPA 7470A 0.171 ug/L1Mercury0.200 J 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:4807/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060689EPA 5030B 4.9 67-64-1 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Acrylonitrile200 6060689EPA 5030B 1.8 107-13-1 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Benzene1.0 6060689EPA 5030B 0.2 71-43-2 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Bromochloromethane3.0 6060689EPA 5030B 0.7 74-97-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060689EPA 5030B 0.6 75-27-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Bromoform3.0 6060689EPA 5030B 0.7 75-25-2 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Bromomethane10 6060689EPA 5030B 0.8 74-83-9 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Carbon Disulfide 100 6060689EPA 5030B 0.6 75-15-0 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060689EPA 5030B 0.6 56-23-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Chlorobenzene3.0 6060689EPA 5030B 0.4 108-90-7 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Chloroethane10 6060689EPA 5030B 0.4 75-00-3 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Chloroform5.0 6060689EPA 5030B 0.3 67-66-3 06/28/16 16:2406/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AZF0926-07 AZF092606/23/16 11:20 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060689EPA 5030B 0.4 74-87-3 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060689EPA 5030B 0.7 124-48-1 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060689EPA 5030B 2.0 96-12-8 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060689EPA 5030B 0.7 106-93-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Dibromomethane10 6060689EPA 5030B 0.7 74-95-3 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060689EPA 5030B 0.5 95-50-1 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060689EPA 5030B 0.3 106-46-7 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060689EPA 5030B 1.5 110-57-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060689EPA 5030B 0.4 75-34-3 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060689EPA 5030B 0.3 107-06-2 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060689EPA 5030B 0.5 75-35-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.5 156-59-2 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060689EPA 5030B 0.4 156-60-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060689EPA 5030B 0.5 78-87-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-01-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060689EPA 5030B 0.4 10061-02-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Ethylbenzene1.0 6060689EPA 5030B 0.2 100-41-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Iodomethane10 6060689EPA 5030B 0.6 74-88-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060689EPA 5030B 0.9 591-78-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060689EPA 5030B 0.5 75-09-2 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060689EPA 5030B 1.1 78-93-3 06/28/16 16:2406/28/16 07:45 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AZF0926-07 AZF092606/23/16 11:20 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060689EPA 5030B 1.7 108-10-1 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Styrene1.0 6060689EPA 5030B 0.4 100-42-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060689EPA 5030B 0.6 630-20-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060689EPA 5030B 0.5 79-34-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060689EPA 5030B 0.4 127-18-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Toluene1.0 6060689EPA 5030B 0.3 108-88-3 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060689EPA 5030B 0.4 71-55-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060689EPA 5030B 0.8 79-00-5 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Trichloroethene1.0 6060689EPA 5030B 0.4 79-01-6 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060689EPA 5030B 0.5 75-69-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060689EPA 5030B 0.7 96-18-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Vinyl Acetate 50 6060689EPA 5030B 0.8 108-05-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060689EPA 5030B 0.7 75-01-4 06/28/16 16:2406/28/16 07:45 NDEPA 8260B ug/L1Xylenes, total 5.0 6060689EPA 5030B 0.4 1330-20-7 06/28/16 16:2406/28/16 07:45 EPA 8260B 2.9 ug/L1Tetrahydrofuran10 B-01, J 6060689EPA 5030B 1.5 109-99-9 06/28/16 16:2406/28/16 07:45 EPA 8260B 99 %Surr: Dibromofluoromethane 6060689EPA 5030B 1868-53-7 06/28/16 16:2406/28/16 07:4580-120 EPA 8260B 107 %Surr: 1,2-Dichloroethane-d4 6060689EPA 5030B 17060-07-0 06/28/16 16:2406/28/16 07:4578-120 EPA 8260B 100 %Surr: Toluene-d8 6060689EPA 5030B 2037-26-5 06/28/16 16:2406/28/16 07:4580-120 EPA 8260B 107 %Surr: 4-Bromofluorobenzene 6060689EPA 5030B 460-00-4 06/28/16 16:2406/28/16 07:4580-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AZF0926-08 AZF092606/23/16 12:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 25.6 ug/L1Arsenic10.0 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:0807/06/16 10:00 EPA 6020B 972 ug/L5Barium500 6070086EPA 3005A 1.49 7440-39-3 07/13/16 16:2307/06/16 10:00 EPA 6020B 0.16 ug/L1Cadmium1.00 J 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:0807/06/16 10:00 EPA 6020B 28.8 ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:0807/06/16 10:00 EPA 6020B 41.3 ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:0807/06/16 10:00 EPA 6020B 16.7 ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:0807/06/16 10:00 EPA 6020B 0.44 ug/L1Silver10.0 J 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:0807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070223EPA 7470A 0.132 7439-97-6 07/12/16 16:1207/12/16 09:35 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 08:1806/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AZF0926-08 AZF092606/23/16 12:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 08:1806/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AZF0926-08 AZF092606/23/16 12:18 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 08:1806/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 08:1806/29/16 06:30 EPA 8260B 101 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 08:1806/29/16 06:3080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 08:1806/29/16 06:3078-120 EPA 8260B 101 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 08:1806/29/16 06:3080-120 EPA 8260B 108 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 08:1806/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AZF0926-09 AZF092606/23/16 10:22 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 6.71 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:1307/06/16 10:00 EPA 6020B 23.4 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:1307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:1307/06/16 10:00 EPA 6020B 0.93 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:1307/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:1307/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:1307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:1307/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:5207/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 08:4306/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AZF0926-09 AZF092606/23/16 10:22 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 08:4306/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AZF0926-09 AZF092606/23/16 10:22 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 08:4306/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 08:4306/29/16 06:30 EPA 8260B 97 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 08:4306/29/16 06:3080-120 EPA 8260B 107 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 08:4306/29/16 06:3078-120 EPA 8260B 98 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 08:4306/29/16 06:3080-120 EPA 8260B 106 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 08:4306/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AZF0926-10 AZF092606/23/16 11:43 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 2.04 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:1807/06/16 10:00 EPA 6020B 59.0 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:1807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:1807/06/16 10:00 EPA 6020B 1.27 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:1807/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:1807/06/16 10:00 EPA 6020B 1.20 ug/L1Selenium10.0 J 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:1807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:1807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:5507/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 09:0906/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AZF0926-10 AZF092606/23/16 11:43 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 09:0906/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AZF0926-10 AZF092606/23/16 11:43 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 09:0906/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 09:0906/29/16 06:30 EPA 8260B 1.8 ug/L1Tetrahydrofuran10 B-01, J 6060711EPA 5030B 1.5 109-99-9 06/29/16 09:0906/29/16 06:30 EPA 8260B 102 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 09:0906/29/16 06:3080-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 09:0906/29/16 06:3078-120 EPA 8260B 100 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 09:0906/29/16 06:3080-120 EPA 8260B 106 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 09:0906/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AZF0926-11 AZF092606/23/16 13:44 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 23.5 ug/L1Arsenic10.0 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:2307/06/16 10:00 EPA 6020B 205 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:2307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:2307/06/16 10:00 EPA 6020B 1.07 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:2307/06/16 10:00 EPA 6020B 0.46 ug/L1Lead10.0 J 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:2307/06/16 10:00 EPA 6020B 2.33 ug/L1Selenium10.0 J 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:2307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:2307/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:5707/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 09:3406/29/16 06:30 EPA 8260B 0.5 ug/L1Benzene1.0 J 6060711EPA 5030B 0.2 71-43-2 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 09:3406/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AZF0926-11 AZF092606/23/16 13:44 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 09:3406/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AZF0926-11 AZF092606/23/16 13:44 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 09:3406/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 09:3406/29/16 06:30 EPA 8260B 3.1 ug/L1Tetrahydrofuran10 B-01, J 6060711EPA 5030B 1.5 109-99-9 06/29/16 09:3406/29/16 06:30 EPA 8260B 100 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 09:3406/29/16 06:3080-120 EPA 8260B 104 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 09:3406/29/16 06:3078-120 EPA 8260B 99 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 09:3406/29/16 06:3080-120 EPA 8260B 108 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 09:3406/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AZF0926-12 AZF092606/23/16 09:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 8.18 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:2807/06/16 10:00 EPA 6020B 266 ug/L1Barium100 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:2807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:2807/06/16 10:00 NDEPA 6020B ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:2807/06/16 10:00 NDEPA 6020B ug/L1Lead10.0 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:2807/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:2807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:2807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 17:5907/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 09:5906/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AZF0926-12 AZF092606/23/16 09:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 09:5906/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AZF0926-12 AZF092606/23/16 09:00 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 09:5906/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 09:5906/29/16 06:30 EPA 8260B 101 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 09:5906/29/16 06:3080-120 EPA 8260B 107 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 09:5906/29/16 06:3078-120 EPA 8260B 100 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 09:5906/29/16 06:3080-120 EPA 8260B 106 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 09:5906/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AZF0926-13 AZF092606/23/16 11:35 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total EPA 6020B 2.10 ug/L1Arsenic10.0 J 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:3307/06/16 10:00 EPA 6020B 78.4 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:3307/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:3307/06/16 10:00 EPA 6020B 1.05 ug/L1Chromium10.0 J 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:3307/06/16 10:00 EPA 6020B 0.57 ug/L1Lead10.0 J 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:3307/06/16 10:00 EPA 6020B 1.06 ug/L1Selenium10.0 J 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:3307/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:3307/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 18:0207/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 10:2506/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AZF0926-13 AZF092606/23/16 11:35 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 10:2506/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AZF0926-13 AZF092606/23/16 11:35 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 10:2506/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 10:2506/29/16 06:30 EPA 8260B 98 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 10:2506/29/16 06:3080-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 10:2506/29/16 06:3078-120 EPA 8260B 102 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 10:2506/29/16 06:3080-120 EPA 8260B 108 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 10:2506/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AZF0926-14 AZF092606/23/16 14:10 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Metals, Total NDEPA 6020B ug/L1Arsenic10.0 6070086EPA 3005A 0.75 7440-38-2 07/12/16 21:3807/06/16 10:00 EPA 6020B 3.40 ug/L1Barium100 J 6070086EPA 3005A 0.30 7440-39-3 07/12/16 21:3807/06/16 10:00 NDEPA 6020B ug/L1Cadmium1.00 6070086EPA 3005A 0.10 7440-43-9 07/12/16 21:3807/06/16 10:00 NDEPA 6020B ug/L1Chromium10.0 6070086EPA 3005A 0.43 7440-47-3 07/12/16 21:3807/06/16 10:00 EPA 6020B 0.26 ug/L1Lead10.0 J 6070086EPA 3005A 0.08 7439-92-1 07/12/16 21:3807/06/16 10:00 NDEPA 6020B ug/L1Selenium10.0 6070086EPA 3005A 0.85 7782-49-2 07/12/16 21:3807/06/16 10:00 NDEPA 6020B ug/L1Silver10.0 6070086EPA 3005A 0.22 7440-22-4 07/12/16 21:3807/06/16 10:00 NDEPA 7470A ug/L1Mercury0.200 6070116EPA 7470A 0.132 7439-97-6 07/08/16 18:0407/07/16 13:15 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 10:5006/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AZF0926-14 AZF092606/23/16 14:10 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 10:5006/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AZF0926-14 AZF092606/23/16 14:10 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 10:5006/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 10:5006/29/16 06:30 EPA 8260B 99 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 10:5006/29/16 06:3080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 10:5006/29/16 06:3078-120 EPA 8260B 98 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 10:5006/29/16 06:3080-120 EPA 8260B 105 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 10:5006/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AZF0926-15 AZF092606/23/16 06:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 6060711EPA 5030B 4.9 67-64-1 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Acrylonitrile200 6060711EPA 5030B 1.8 107-13-1 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Benzene1.0 6060711EPA 5030B 0.2 71-43-2 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Bromochloromethane3.0 6060711EPA 5030B 0.7 74-97-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Bromodichloromethane1.0 6060711EPA 5030B 0.6 75-27-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Bromoform3.0 6060711EPA 5030B 0.7 75-25-2 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Bromomethane10 6060711EPA 5030B 0.8 74-83-9 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Carbon Disulfide 100 6060711EPA 5030B 0.6 75-15-0 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 6060711EPA 5030B 0.6 56-23-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Chlorobenzene3.0 6060711EPA 5030B 0.4 108-90-7 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Chloroethane10 6060711EPA 5030B 0.4 75-00-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Chloroform5.0 6060711EPA 5030B 0.3 67-66-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Chloromethane1.0 6060711EPA 5030B 0.4 74-87-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Dibromochloromethane3.0 6060711EPA 5030B 0.7 124-48-1 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 6060711EPA 5030B 2.0 96-12-8 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 6060711EPA 5030B 0.7 106-93-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Dibromomethane10 6060711EPA 5030B 0.7 74-95-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 6060711EPA 5030B 0.5 95-50-1 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 6060711EPA 5030B 0.3 106-46-7 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 6060711EPA 5030B 1.5 110-57-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 6060711EPA 5030B 0.4 75-34-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 6060711EPA 5030B 0.3 107-06-2 06/29/16 11:1606/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AZF0926-15 AZF092606/23/16 06:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 6060711EPA 5030B 0.5 75-35-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.5 156-59-2 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 6060711EPA 5030B 0.4 156-60-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 6060711EPA 5030B 0.5 78-87-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-01-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 6060711EPA 5030B 0.4 10061-02-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Ethylbenzene1.0 6060711EPA 5030B 0.2 100-41-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Iodomethane10 6060711EPA 5030B 0.6 74-88-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 6060711EPA 5030B 0.9 591-78-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Methylene Chloride 1.0 6060711EPA 5030B 0.5 75-09-2 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 6060711EPA 5030B 1.1 78-93-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 6060711EPA 5030B 1.7 108-10-1 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Styrene1.0 6060711EPA 5030B 0.4 100-42-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 6060711EPA 5030B 0.6 630-20-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 6060711EPA 5030B 0.5 79-34-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Tetrachloroethene1.0 6060711EPA 5030B 0.4 127-18-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Toluene1.0 6060711EPA 5030B 0.3 108-88-3 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 6060711EPA 5030B 0.4 71-55-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 6060711EPA 5030B 0.8 79-00-5 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Trichloroethene1.0 6060711EPA 5030B 0.4 79-01-6 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 6060711EPA 5030B 0.5 75-69-4 06/29/16 11:1606/29/16 06:30 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AZF0926-15 AZF092606/23/16 06:45 Project:Holly Springs Closed C&D Landfill 06/24/16 09:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 6060711EPA 5030B 0.7 96-18-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Vinyl Acetate 50 6060711EPA 5030B 0.8 108-05-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Vinyl Chloride 1.0 6060711EPA 5030B 0.7 75-01-4 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Xylenes, total 5.0 6060711EPA 5030B 0.4 1330-20-7 06/29/16 11:1606/29/16 06:30 NDEPA 8260B ug/L1Tetrahydrofuran10 6060711EPA 5030B 1.5 109-99-9 06/29/16 11:1606/29/16 06:30 EPA 8260B 100 %Surr: Dibromofluoromethane 6060711EPA 5030B 1868-53-7 06/29/16 11:1606/29/16 06:3080-120 EPA 8260B 107 %Surr: 1,2-Dichloroethane-d4 6060711EPA 5030B 17060-07-0 06/29/16 11:1606/29/16 06:3078-120 EPA 8260B 101 %Surr: Toluene-d8 6060711EPA 5030B 2037-26-5 06/29/16 11:1606/29/16 06:3080-120 EPA 8260B 109 %Surr: 4-Bromofluorobenzene 6060711EPA 5030B 460-00-4 06/29/16 11:1606/29/16 06:3080-120 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 6070086 - EPA 3005A Blank (6070086-BLK1)Prepared: 07/06/16 Analyzed: 07/12/16 Arsenic ug/LND10.0 Barium ug/LND100 Cadmium ug/LND1.00 Chromium ug/LND10.0 Lead ug/LND10.0 Selenium ug/LND10.0 Silver ug/LND10.0 LCS (6070086-BS1)Prepared: 07/06/16 Analyzed: 07/12/16 Arsenic ug/L10510.0 100.00 80-120105 Barium ug/L101100 100.00 80-120101 Cadmium ug/L1021.00 100.00 80-120102 Chromium ug/L10110.0 100.00 80-120101 Lead ug/L10110.0 100.00 80-120101 Selenium ug/L10210.0 100.00 80-120102 Silver ug/L10910.0 100.00 80-120109 Matrix Spike (6070086-MS1)Prepared: 07/06/16 Analyzed: 07/12/16 Source: AZF0926-07 Arsenic ug/L10110.0 100.00 3.07 75-12598 Barium ug/L291100 100.00 164 QM-0275-125127 Cadmium ug/L96.0 1.00 100.00 ND 75-12596 Chromium ug/L96.1 10.0 100.00 ND 75-12596 Lead ug/L97.5 10.0 100.00 ND 75-12598 Selenium ug/L93.0 10.0 100.00 ND 75-12593 Silver ug/L10410.0 100.00 ND 75-125104 Matrix Spike Dup (6070086-MSD1)Prepared: 07/06/16 Analyzed: 07/12/16 Source: AZF0926-07 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 6070086 - EPA 3005A Matrix Spike Dup (6070086-MSD1)Prepared: 07/06/16 Analyzed: 07/12/16 Source: AZF0926-07 Arsenic ug/L10810.0 100.00 3.07 2075-125105 7 Barium ug/L299100 100.00 164 20 QM-0275-125134 3 Cadmium ug/L1001.00 100.00 ND 2075-125100 4 Chromium ug/L97.6 10.0 100.00 ND 2075-12598 2 Lead ug/L10110.0 100.00 ND 2075-125101 4 Selenium ug/L10110.0 100.00 ND 2075-125101 8 Silver ug/L10510.0 100.00 ND 2075-125105 0.5 Post Spike (6070086-PS1)Prepared: 07/06/16 Analyzed: 07/12/16 Source: AZF0926-07 Arsenic ug/L109 100.00 3.07 80-120106 Barium ug/L282 100.00 164 80-120117 Cadmium ug/L97.0 100.00 0.03 80-12097 Chromium ug/L96.4 100.00 0.27 80-12096 Lead ug/L97.0 100.00 0.03 80-12097 Selenium ug/L98.1 100.00 0.17 80-12098 Silver ug/L102 100.00 0.07 80-120102 Batch 6070116 - EPA 7470A Blank (6070116-BLK1)Prepared: 07/07/16 Analyzed: 07/08/16 Mercury ug/LND0.200 LCS (6070116-BS1)Prepared: 07/07/16 Analyzed: 07/08/16 Mercury ug/L2.42 0.200 2.5000 80-12097 Matrix Spike (6070116-MS1)Prepared: 07/07/16 Analyzed: 07/08/16 Source: AZF0926-07 Mercury ug/L1.68 0.200 2.5000 0.171 QM-0575-12560 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 6070116 - EPA 7470A Matrix Spike Dup (6070116-MSD1)Prepared: 07/07/16 Analyzed: 07/08/16 Source: AZF0926-07 Mercury ug/L1.50 0.200 2.5000 0.171 20 QM-0575-12553 12 Post Spike (6070116-PS1)Prepared: 07/07/16 Analyzed: 07/08/16 Source: AZF0926-07 Mercury ug/L1.04 1.6667 0.114 QM-0580-12055 Batch 6070223 - EPA 7470A Blank (6070223-BLK1)Prepared & Analyzed: 07/12/16 Mercury ug/LND0.200 LCS (6070223-BS1)Prepared & Analyzed: 07/12/16 Mercury ug/L2.61 0.200 2.5000 80-120104 Duplicate (6070223-DUP1)Prepared & Analyzed: 07/12/16 Source: AZF0926-08RE1 Mercury ug/L0.169 0.200 ND 20 J Matrix Spike (6070223-MS1)Prepared & Analyzed: 07/12/16 Source: AZG0163-05 Mercury ug/L2.60 0.200 2.5000 ND 75-125104 Matrix Spike Dup (6070223-MSD1)Prepared & Analyzed: 07/12/16 Source: AZG0163-05 Mercury ug/L2.67 0.200 2.5000 ND 2075-125107 3 Post Spike (6070223-PS1)Prepared & Analyzed: 07/12/16 Source: AZG0163-05 Mercury ug/L1.65 1.6667 -0.017 80-120100 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060689 - EPA 5030B Blank (6060689-BLK1)Prepared & Analyzed: 06/28/16 Acetone ug/LND100 Acrylonitrile ug/LND200 Benzene ug/LND1.0 Bromochloromethane ug/LND3.0 Bromodichloromethane ug/LND1.0 Bromoform ug/LND3.0 Bromomethane ug/LND10 Carbon Disulfide ug/LND100 Carbon Tetrachloride ug/LND1.0 Chlorobenzene ug/LND3.0 Chloroethane ug/LND10 Chloroform ug/LND5.0 Chloromethane ug/LND1.0 Dibromochloromethane ug/LND3.0 1,2-Dibromo-3-chloropropane ug/LND13 1,2-Dibromoethane ug/LND1.0 Dibromomethane ug/LND10 1,2-Dichlorobenzene ug/LND5.0 1,4-Dichlorobenzene ug/LND1.0 trans-1,4-Dichloro-2-butene ug/LND100 1,1-Dichloroethane ug/LND5.0 1,2-Dichloroethane ug/LND1.0 1,1-Dichloroethene ug/LND5.0 cis-1,2-Dichloroethene ug/LND5.0 trans-1,2-Dichloroethene ug/LND5.0 1,2-Dichloropropane ug/LND1.0 cis-1,3-Dichloropropene ug/LND1.0 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060689 - EPA 5030B Blank (6060689-BLK1)Prepared & Analyzed: 06/28/16 trans-1,3-Dichloropropene ug/LND1.0 Ethylbenzene ug/LND1.0 Iodomethane ug/LND10 Methyl Butyl Ketone (2-Hexanone)ug/LND50 Methylene Chloride ug/LND1.0 Methyl Ethyl Ketone (2-Butanone)ug/LND100 4-Methyl-2-pentanone (MIBK)ug/LND100 Styrene ug/LND1.0 1,1,1,2-Tetrachloroethane ug/LND5.0 1,1,2,2-Tetrachloroethane ug/LND3.0 Tetrachloroethene ug/LND1.0 Toluene ug/LND1.0 1,1,1-Trichloroethane ug/LND1.0 1,1,2-Trichloroethane ug/LND1.0 Trichloroethene ug/LND1.0 Trichlorofluoromethane ug/LND1.0 1,2,3-Trichloropropane ug/LND1.0 Vinyl Acetate ug/LND50 Vinyl Chloride ug/LND1.0 Xylenes, total ug/LND5.0 Tetrahydrofuran ug/L1.6 10 J ug/L 50.000 80-120Surr: Dibromofluoromethane 10050 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10251 ug/L 50.000 80-120Surr: Toluene-d8 9949 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10954 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060689 - EPA 5030B LCS (6060689-BS1)Prepared & Analyzed: 06/28/16 Benzene ug/L48 50.000 67-13497 Chlorobenzene ug/L44 50.000 69-12288 1,1-Dichloroethene ug/L54 50.000 58-142107 Toluene ug/L47 50.000 68-12794 Trichloroethene ug/L46 50.000 72-13293 ug/L 50.000 80-120Surr: Dibromofluoromethane 10050 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10452 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10753 Matrix Spike (6060689-MS1)Prepared & Analyzed: 06/28/16 Source: AZF0926-07 Benzene ug/L54 50.000 ND 67-134107 Chlorobenzene ug/L48 50.000 ND 69-12295 1,1-Dichloroethene ug/L58 50.000 ND 58-142115 Toluene ug/L53 50.000 ND 68-127105 Trichloroethene ug/L51 50.000 ND 72-132102 ug/L 50.000 80-120Surr: Dibromofluoromethane 10754 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10854 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10653 Matrix Spike Dup (6060689-MSD1)Prepared & Analyzed: 06/28/16 Source: AZF0926-07 Benzene ug/L54 50.000 ND 967-134108 0.8 Chlorobenzene ug/L48 50.000 ND 1369-12297 2 1,1-Dichloroethene ug/L58 50.000 ND 958-142117 1 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060689 - EPA 5030B Matrix Spike Dup (6060689-MSD1)Prepared & Analyzed: 06/28/16 Source: AZF0926-07 Toluene ug/L53 50.000 ND 968-127106 1 Trichloroethene ug/L51 50.000 ND 1172-132102 0.04 ug/L 50.000 80-120Surr: Dibromofluoromethane 10753 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10553 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10552 Batch 6060711 - EPA 5030B Blank (6060711-BLK1)Prepared & Analyzed: 06/29/16 Acetone ug/LND100 Acrylonitrile ug/LND200Benzeneug/LND1.0 Bromochloromethane ug/LND3.0 Bromodichloromethane ug/LND1.0 Bromoform ug/LND3.0 Bromomethane ug/LND10 Carbon Disulfide ug/LND100 Carbon Tetrachloride ug/LND1.0 Chlorobenzene ug/LND3.0Chloroethane ug/LND10 Chloroform ug/LND5.0 Chloromethane ug/LND1.0 Dibromochloromethane ug/LND3.0 1,2-Dibromo-3-chloropropane ug/LND13 1,2-Dibromoethane ug/LND1.0 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060711 - EPA 5030B Blank (6060711-BLK1)Prepared & Analyzed: 06/29/16 Dibromomethane ug/LND10 1,2-Dichlorobenzene ug/LND5.0 1,4-Dichlorobenzene ug/LND1.0 trans-1,4-Dichloro-2-butene ug/LND100 1,1-Dichloroethane ug/LND5.0 1,2-Dichloroethane ug/LND1.0 1,1-Dichloroethene ug/LND5.0 cis-1,2-Dichloroethene ug/LND5.0 trans-1,2-Dichloroethene ug/LND5.0 1,2-Dichloropropane ug/LND1.0 cis-1,3-Dichloropropene ug/LND1.0 trans-1,3-Dichloropropene ug/LND1.0 Ethylbenzene ug/LND1.0 Iodomethane ug/LND10 Methyl Butyl Ketone (2-Hexanone)ug/LND50 Methylene Chloride ug/LND1.0 Methyl Ethyl Ketone (2-Butanone)ug/LND100 4-Methyl-2-pentanone (MIBK)ug/LND100 Styrene ug/LND1.0 1,1,1,2-Tetrachloroethane ug/LND5.0 1,1,2,2-Tetrachloroethane ug/LND3.0 Tetrachloroethene ug/LND1.0 Toluene ug/LND1.0 1,1,1-Trichloroethane ug/LND1.0 1,1,2-Trichloroethane ug/LND1.0 Trichloroethene ug/LND1.0 Trichlorofluoromethane ug/LND1.0 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060711 - EPA 5030B Blank (6060711-BLK1)Prepared & Analyzed: 06/29/16 1,2,3-Trichloropropane ug/LND1.0 Vinyl Acetate ug/LND50 Vinyl Chloride ug/LND1.0 Xylenes, total ug/LND5.0 Tetrahydrofuran ug/L1.6 10 J ug/L 50.000 80-120Surr: Dibromofluoromethane 9950 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10552 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10754 LCS (6060711-BS1)Prepared & Analyzed: 06/29/16 Benzene ug/L52 50.000 67-134105 Chlorobenzene ug/L48 50.000 69-12296 1,1-Dichloroethene ug/L59 50.000 58-142118 Toluene ug/L51 50.000 68-127102 Trichloroethene ug/L50 50.000 72-132101 ug/L 50.000 80-120Surr: Dibromofluoromethane 10150 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10452 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10854 Matrix Spike (6060711-MS1)Prepared & Analyzed: 06/29/16 Source: AZF0926-10 Benzene ug/L53 50.000 ND 67-134106 Chlorobenzene ug/L47 50.000 ND 69-12294 1,1-Dichloroethene ug/L57 50.000 ND 58-142115 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 6060711 - EPA 5030B Matrix Spike (6060711-MS1)Prepared & Analyzed: 06/29/16 Source: AZF0926-10 Toluene ug/L52 50.000 ND 68-127105 Trichloroethene ug/L50 50.000 ND 72-132100 ug/L 50.000 80-120Surr: Dibromofluoromethane 10753 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10753 ug/L 50.000 80-120Surr: Toluene-d8 10251 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10552 Matrix Spike Dup (6060711-MSD1)Prepared & Analyzed: 06/29/16 Source: AZF0926-10 Benzene ug/L54 50.000 ND 967-134108 2 Chlorobenzene ug/L48 50.000 ND 1369-12296 1 1,1-Dichloroethene ug/L59 50.000 ND 958-142118 3 Toluene ug/L51 50.000 ND 968-127103 2 Trichloroethene ug/L51 50.000 ND 1172-132102 2 ug/L 50.000 80-120Surr: Dibromofluoromethane 10854 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10653 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10452 Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Laboratory Certifications Code Description Number Expires 02069Louisiana 06/30/2016LA 381North Carolina 12/31/2016NC E87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/2016 06/30/2017NELAC 98011001South Carolina 07/30/2016SC T104704397-08-TXTexas 03/31/2017TX 1340Virginia 12/14/2016VA Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092 (770) 734-4200 FAX (770) 734-4201 PACE ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann July 15, 2016 Legend Defination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLND SWSL/RL MDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection Limit Qualifiers - Dilution FactorDF QM-05 The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries. QM-02 The spike recovery is outside acceptance limits due to insignificant spike amount as compared to sample concentration. J Estimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag). B-01 Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values. Note: Unless otherwise noted, all results are reported on an as received basis. LOG-IN CHECKLIST Republic Services of North Carolina, LLC Holly Springs Closed C&D LandfillProject: Client: Printed: 7/15/2016 4:55:24PM Environmental Monitoring & Laboratory Analysis (770) 734-4200 FAX (770) 734-4201 110 Technology Parkway, Peachtree Corners, GA 30092 PACE ANALYTICAL SERVICES, INC. Date Received:06/24/16 09:45 Logged In By:Charles Hawks Work Order:AZF0926 OBSERVATIONS Attn: Mr. Matt Einsmann #Samples: 15 #Containers: 67 2.0 2.0 YES Minimum Temp(C):Maximum Temp(C): CHECKLIST ITEMS COC included with Samples Sample Container(s) Intact Chain of Custody Complete Sample Container(s) Match COC Custody seal Intact Temperature in Compliance Sufficient Sample Volume for Analysis Zero Headspace Maintained for VOA Analyses Samples labeled preserved (If Applicable) Samples received within Allowable Hold Times Samples Received on Ice Preservation Confirmed YES YES YES YES YES YES YES YES YES YES YES Custody Seal(s) Used:Yes Comments: Page 1 of 1 Appendix C Historical Groundwater Constituents APPENDIX C Historical Groundwater Constituents/Analytes Analyte Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Inorganic Compounds Total Arsenic 07/22/09 2.8 10.0 3.84 J 7.37 J 6.86 J 5.85 J 6.60 J 6.26 J 7.04 J 4.87 J 4.26 J 7.19 J 21.4 9.63 J ND NC 2L = 10 µg/L 01/26/10 3.9 10.0 9.21 J 6.79 J 5.08 J 4.20 J 4.78 J ND ND 5.83 J ND ND 13.5 8.24 J ND 07/07/10 2.8 10.0 5.02 J 6.27 J ND 4.34 J 6.90 J ND 3.15 J ND ND ND 13.0 10.20 ND 01/05/11 2.8 10.0 ND 4.15 J 3.99 J ND ND ND ND ND ND ND 11.6 3.84 J ND 07/07/11 2.8 10.0 ND 5.06 J ND ND 5.31 J ND 3.15 J ND ND ND 14.0 8.09 J ND 01/12/12 2.8 10.0 1.82 J 2.81 J 2.81 J 4.32 J 2.89 J ND ND 1.52 J 14.20 ND 10.8 2.11 J ND 07/12/12 2.8 10.0 ND 1.40 J 3.57 J 1.33 J 1.85 J ND ND ND ND ND 14.6 6.86 J ND 02/06/13 2.8 10.0 ND 2.58 J 3.56 J 3.70 J 3.66 J ND ND 1.45 J ND 1.29 J 8.0 J 3.80 J ND 07/09/13 2.8 10.0 1.62 J 4.44 J 3.70 J 2.68 J 4.10 J ND 1.74 J ND ND ND 25.0 8.44 J ND 01/31/14 2.8 10.0 ND 5.77 J 2.72 J 2.31 J 3.47 J ND ND 0.89 J 5.72 J ND 21.3 1.47 J ND 07/23/14 1.13 10.0 1.14 J 4.39 J 2.40 J 3.42 J 1.67 J 1.19 J ND ND ND ND 22.1 20.2 ND 01/27/15 1.13 10.0 1.61 J 5.13 J 3.09 J 3.30 J 2.76 J ND 1.21 J 1.83 J 2.59 J ND 21.6 10.8 ND 07/29/15 0.75 10.0 ND 5.49 J 4.36 J 3.53 J 3.02 J ND 2.10 B 3.48 B 11.6 1.71 B 19.8 6.17 J 0.93 J 06/23/16 0.75 10.0 2.22 J 6.71 J 5.19 J 3.39 J 3.15 J 2.75 J 3.16 J 3.07 J 25.6 2.04 J 23.5 8.18 J ND Total Barium 07/22/09 4.2 100.0 258 48.1 J 72.6 J 30.6 J 54.4 J 162 266 122 112 84.3 J 209 386 ND NC 2L = 700 µg/L 01/26/10 0.25 100.00 327 49.9 J 77.8 J 36.2 J 45.3 J 144 275 105 138 45.2 J 220 540 0.66 J 07/07/10 1.0 100.0 219 24.8 J 61.0 J 27.5 J 43.4 J 131 209 126 113 44.3 J 149 385 ND 01/05/11 1.0 100.0 229 32.5 J 81.5 J 27.2 J 45.8 J 134 222 80.0 J 125 45.3 J 200 312 ND 07/07/11 1.0 100.0 266 27.5 J 80.4 J 31.7 J 53.6 J 130 272 141 196 56.8 J 217 354 ND 01/12/12 --- 100 260 42.6 J 82.0 J 46.2 J 48.4 J 130 261 97.6 J 387 40.8 J 243 300 0.09 J 07/12/12 --- 100 238 34.9 J 71.3 J 27.7 J 48.9 J 110 246 142 76.0 J 48.7 J 220 316 1.47 J 02/06/13 --- 100 250 43.6 J 67.6 J 26.8 J 48.2 J 113 248 70.6 J 106 59.3 J 118 263 1.05 J 07/09/13 --- 100 252 23.4 J 69.4 J 26.2 J 54.1 J 123 307 130 80.6 J 47.7 J 228 237 0.46 J 01/31/14 --- 100 258 22.0 J 74.4 J 29.5 J 54.2 J 109 245 116 129 35.3 J 163 259 ND 07/23/14 0.10 100 251 20.9 J 77.8 J 121 62.2 J 147 282 150 61.0 J 48.2 J 173 324 0.33 J 01/27/15 0.10 100 318 24.0 J 71.4 J 50.1 J 61.5 J 110 262 112 83.4 J 56.7 J 186 629 0.17 J 07/29/15 0.30 100 299 23.6 J 72.4 J 23.8 J 68.9 J 134 278 93.4 J 708 51.8 J 167 295 0.84 J 06/23/16 0.30 100 378 23.4 J 77.3 J 23.3 J 74.8 J 131 317 164 972 59.0 J 205 266 3.40 J Total Cadmium 07/22/09 0.1 1 0.31 J 0.14 J ND 0.16 J 0.194 J 0.37 J ND 0.232 J 0.49 J 0.17 J 0.39 J 0.17 J ND NC 2L = 2 µg/L 01/26/10 0.1 1 0.36 B 0.19 B ND 0.24 B 0.211 B 0.20 B 0.23 B 0.335 B 0.25 B 0.39 B ND 0.13 B 0.14 J 07/07/10 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.4 1 0.07 J ND ND ND ND ND ND ND 0.12 J ND ND ND ND 07/12/12 --- 1.00 0.11 J ND ND ND ND 0.06 J ND ND ND ND ND 0.10 J ND 02/06/13 --- 1.00 0.16 J ND ND ND ND ND ND ND 0.06 J 0.06 J 0.20 J 0.06 J ND 07/09/13 --- 1.00 ND ND ND ND ND ND ND ND 0.20 J ND 0.15 J ND ND 01/31/14 --- 1.00 ND ND ND ND ND ND ND ND 0.06 J ND 0.27 J ND ND 07/23/14 --- 1.00 ND ND ND 0.06 J ND ND ND ND 0.14 J 0.05 J 0.12 J ND ND 01/27/15 0.05 1.00 ND ND ND ND ND ND ND ND 0.08 J 0.07 J 0.09 J ND ND 07/29/15 0.10 1.00 ND ND ND ND ND ND ND ND 0.20 J ND ND ND ND 06/23/16 0.10 1.00 ND ND ND ND ND ND ND ND 0.16 J ND ND ND ND Total Chromium 07/22/09 0.7 10 ND 2.74 J 4.45 J 3.53 J ND 1.03 J 1.47 J 1.25 J 3.60 J 5.39 J 1.89 J ND ND NC 2L = 10 µg/L 01/26/10 1.7 10 2.91 J 2.03 J 6.80 J 4.05 J ND ND ND 2.38 J 5.17 J 4.39 J ND 1.72 J ND 07/07/10 1.0 10 1.50 J 1.59 J 3.16 J 2.46 J 1.93 J 1.70 J 1.10 J 1.06 J 3.85 J 2.94 J ND 2.68 J ND 01/05/11 1.0 10 ND 2.10 J 7.40 J 6.03 J ND 2.59 J 1.95 J 1.11 J 7.43 J 7.10 J ND ND ND 07/07/11 1.0 10 ND 2.41 J 4.75 J 2.01 J 1.06 J 1.80 J 1.28 J ND 22.50 3.54 J 1.82 J 1.62 J ND 01/12/12 1.0 10 ND 1.65 B 11.0 22.8 ND ND 0.84 B 1.38 B 17.90 3.19 B 1.07 B 1.47 B 0.82 J 07/12/12 --- 10.0 ND ND 1.23 J 3.01 J ND ND ND ND 3.00 J 1.02 J ND ND ND 02/06/13 --- 10.0 ND 0.86 B ND 3.40 B ND 1.18 B 15.70 ND 5.10 B ND 4.50 B 1.80 B 1.42 J 07/09/13 --- 10.0 2.56 B ND 0.60 B ND ND 2.16 B 7.47 B 1.39 B 4.15 B 3.11 B 3.24 B 2.39 B 3.51 J 01/31/14 --- 10.0 3.56 B 1.31 B 2.47 B 1.63 B ND 3.93 B 7.32 B 2.99 B 8.64 B 5.11 B 2.31 B 3.96 B 2.79 J 07/23/14 --- 10.0 1.99 J 1.43 J 2.86 J 7.72 J ND 1.75 J 2.81 J 1.58 J 3.57 J 2.65 J ND ND ND 01/27/15 0.73 10.0 1.53 J 3.08 J 1.74 J 1.52 J ND ND 1.05 J ND 2.69 J 4.37 J ND 3.37 J ND 07/29/15 0.43 10.0 2.44 J ND ND ND ND 0.76 J ND ND 17.0 1.56 J ND ND ND 06/23/16 0.43 10.0 0.61 J 0.93 J 1.22 J ND ND 0.74 J 0.82 J ND 28.8 1.27 J 1.07 J ND ND Total Lead 07/22/09 1.6 10 1.72 J ND ND ND ND ND ND ND 2.31 J 3.82 J 2.44 J ND ND NC 2L = 15 µg/L 01/26/10 1.1 10 3.05 J ND ND ND ND ND ND ND 4.9 J ND ND 2.24 J ND 07/07/10 1.9 10 ND ND ND ND ND ND ND ND 2.66 J ND ND ND ND 01/05/11 1.9 10 ND 2.40 J ND ND ND ND ND ND ND ND ND ND ND 07/07/11 1.9 10 ND ND ND ND ND ND ND ND 11.30 ND ND ND ND 01/12/12 1.9 10 ND ND 0.21 J 2.43 ND ND ND ND 19.60 0.59 J ND ND ND 07/12/12 --- 10.0 0.12 J ND ND 0.31 J ND ND ND ND 0.98 J 0.11 J ND 0.23 J ND 02/06/13 --- 10.0 0.26 J ND 0.11 J 0.68 J 0.09 J ND 0.68 J ND 5.48 J 0.22 J 1.63 J 0.13 J ND 07/09/13 --- 10.0 1.36 J ND 0.06 B 0.23 B 0.08 B ND 0.24 B ND 1.42 J ND 1.64 J 0.28 B 0.08 J 01/31/14 --- 10.0 0.08 J ND ND 0.85 J ND ND 0.24 J ND 10.4 0.08 J 0.32 J 0.13 J ND 07/23/14 --- 10.0 0.05 J ND 0.17 J 5.31 J ND ND ND ND 1.68 J 0.09 J 0.22 J 0.53 J ND 01/27/15 0.05 10.0 0.33 J ND ND 1.44 J ND ND ND ND 2.15 J 1.35 J 0.05 J 1.88 J ND 07/29/15 0.08 10.0 ND ND ND 0.11 J 0.32 J ND ND ND 32.8 0.15 J 0.20 J ND ND 06/23/16 0.08 10.0 ND ND ND ND ND 0.11 B ND ND 41.3 ND 0.46 B ND 0.26 J Total Mercury 07/22/09 0.1 0.2 ND ND ND ND ND ND ND 0.206 ND ND ND ND ND NC 2L = 1 µg/L 01/26/10 0.1 0.2 ND ND ND ND ND ND ND 0.115 J ND ND 0.070 J ND ND 07/07/10 0.2 0.2 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.2 0.2 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.2 0.2 ND ND ND ND ND ND ND 0.194 J ND ND ND ND ND 01/12/12 0.2 0.2 ND ND ND ND ND ND ND 0.201 ND ND ND ND ND 07/12/12 --- 0.2 ND ND ND ND ND ND ND 0.197 J ND ND ND ND ND 02/06/13 --- 0.2 ND ND ND ND ND ND ND 0.066 J ND ND ND ND ND 07/09/13 --- 0.2 {0.088} B ND ND ND ND 0.067 J 0.074 J 0.259 ND ND 0.069 J 0.08 J ND {0.084} J 01/31/14 --- 0.2 ND ND 0.073 B ND ND ND 0.068 B 0.286 B ND ND 0.072 B ND 0.114 J 07/23/14 --- 0.2 0.069 J ND ND ND ND 0.126 J 0.065 J 0.193 J ND ND ND ND ND 01/27/15 0.064 0.2 ND ND 0.163 J ND ND ND ND 0.275 ND ND ND ND ND 07/29/15 0.070 0.2 ND ND ND ND ND ND ND 0.218 0.122 J ND ND ND ND 06/23/16 0.132 0.2 0.144 J ND ND ND ND ND ND 0.171 J ND ND ND ND ND Holly Springs Closed C and D Landfill Permit No. 92-14 Page 1 of 4 Joyce Engineering APPENDIX C Historical Groundwater Constituents/Analytes Analyte Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Total Selenium 07/22/09 3.4 10 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 20 µg/L 01/26/10 0.8 10 ND ND ND ND ND 1.50 J 0.97 J 1.01 J 4.32 J 3.22 J 2.02 J 1.10 J ND 07/07/10 2.7 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 2.7 10 ND ND ND ND ND ND ND ND ND ND 3.55 B ND 3.01 J 07/07/11 2.7 10 ND ND 6.34 (0.985) B ND ND ND ND ND 2.79 (6.37) B ND ND ND 3.21 J 01/12/12 2.7 10 ND ND ND 2.20 J ND ND ND ND 29.20 2.17 J 1.60 J ND ND 07/12/12 --- 10.0 ND ND ND ND ND ND ND 1.03 J 2.18 J 0.91 J 2.05 J 0.73 J ND 02/06/13 --- 10.0 ND ND ND ND ND 0.56 J ND ND 2.56 J 1.50 J ND ND ND 07/09/13 --- 10.0 ND ND ND ND ND ND ND 0.85 J 3.31 J 1.21 J 1.13 J ND ND 01/31/14 --- 10.0 ND ND ND ND ND ND ND 0.91 J 3.04 J 1.42 J 1.17 J ND ND 07/23/14 --- 10.0 ND ND ND ND ND 1.03 J 1.33 J 1.99 J 2.80 J 1.73 J 4.99 J 1.11 J ND 01/27/15 1.01 10.0 ND ND ND ND ND ND ND ND 3.62 J 1.66 J 2.41 J ND ND 07/29/15 0.85 10.0 ND ND ND ND ND 1.20 J ND 0.93 J 3.05 J 1.25 J 4.12 J 1.07 J ND 06/23/16 0.85 10.0 ND ND ND ND ND ND ND ND 16.7 1.20 J 2.33 J ND ND Total Silver 07/22/09 1.0 10 ND ND ND ND 1.28 J ND ND ND 1.04 J ND ND ND ND NC 2L = 20 µg/L 01/26/10 0.5 10 0.68 B 0.56 B 1.17 B ND 0.549 B 0.92 B 0.52 B 0.529 B 0.60 B 1.57 B 0.84 B 0.83 B 0.73 J 07/07/10 1.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 1.9 10 ND ND ND ND ND ND ND ND ND ND 2.68 J ND ND 07/07/11 1.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 1.9 10 ND ND 0.22 ND ND ND ND 0.58 J 0.20 J ND ND ND ND 07/12/12 --- 10.0 0.14 J ND 0.23 J ND ND ND ND ND ND ND 0.16 J 0.24 J ND 02/06/13 --- 10.0 ND ND ND ND ND ND ND ND ND ND 0.28 J ND ND 07/09/13 --- 10.0 0.85 J ND ND ND ND ND ND ND ND ND 0.51 J ND ND 01/31/14 --- 10.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 10.0 ND ND ND ND ND ND ND ND ND ND ND 0.86 J ND 01/27/15 0.17 10.0 0.21 J 0.24 J 0.26 J 0.18 J ND ND ND ND ND 0.23 J ND 3.11 J ND 07/29/15 0.22 10.0 ND ND ND ND ND ND ND ND 0.28 J ND ND ND ND 06/23/16 0.22 10.0 ND ND ND ND ND ND ND ND 0.44 J ND ND ND ND Organic Compounds Acetone 07/22/09 1.5 100 ND ND ND ND ND ND ND ND ND ND 2.0 J ND ND NC 2L = 6000 µg/L 01/26/10 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 1.2 100 ND ND ND ND ND ND ND ND ND ND 10.0 J ND ND 01/12/12 1.2 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND 2.4 J 01/31/14 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 100 ND ND ND 6.3 J ND ND ND ND ND ND 8.6 J ND ND 01/27/15 5.7 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/29/15 3.1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 06/23/16 4.9 100 ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene 07/22/09 0.2 1 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 1 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.2 1 ND ND ND ND ND ND ND ND ND ND 0.5 J ND ND 01/05/11 0.2 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.7 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND 0.4 J ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND 0.6 J ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND 0.2 J ND ND 07/29/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND 0.5 J ND ND 06/23/16 0.2 1.0 ND ND ND ND ND ND ND ND ND ND 0.5 J ND ND Chloroform 07/22/09 0.2 5 ND ND 0.6 J ND ND ND ND ND ND ND ND ND ND NC 2L = 70 µg/L 01/26/10 0.1 5 ND ND 0.7 J ND ND ND ND ND ND ND ND ND ND 07/07/10 0.2 5 ND ND 0.4 J ND ND ND ND ND ND ND ND ND ND 01/05/11 0.2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.7 5 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 --- 5.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 5.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 5.0 ND ND 0.5 J ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 5.0 ND ND 0.4 B ND ND ND ND ND ND ND ND ND 0.50 J 01/31/14 --- 5.0 ND ND 0.3 J ND ND ND ND 0.3 J ND ND ND ND ND 07/23/14 --- 5.0 ND ND 0.3 J ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 5.0 ND ND ND ND ND ND ND 0.2 J ND ND ND ND ND 07/29/15 0.2 5.0 ND ND ND ND ND ND ND 0.2 J ND ND ND ND ND 06/23/16 0.3 5.0 ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane 07/22/09 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 3 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.3 1 ND ND ND ND ND ND ND ND 0.45 J ND 0.43 J ND ND 01/05/11 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/29/15 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 06/23/16 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND Methyl Ethyl Ketone (2-Butanone) 07/23/14 --- 100 2.0 J ND 0.9 J ND ND ND ND ND ND ND ND ND ND NC 2L = 4,000 µg/L 01/27/15 0.8 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/29/15 0.9 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 06/23/16 1.1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND Holly Springs Closed C and D Landfill Permit No. 92-14 Page 2 of 4 Joyce Engineering APPENDIX C Historical Groundwater Constituents/Analytes Analyte Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Toluene 07/22/09 0.3 1 0.84 J ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 600 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.9 1 ND ND ND ND ND ND ND ND ND ND 1.80 ND ND 07/14/11 0.9 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND 0.20 J ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/29/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 06/23/16 0.3 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene 07/29/15 0.3 1.0 ND 0.50 J 0.30 J ND ND 0.40 J 0.30 J ND ND ND ND ND ND 06/23/16 0.4 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 0.7 µg/L Tetrahydrofuran 01/05/11 0.8 10 ND ND ND ND ND ND ND ND ND ND ND ND ND (No Standard)07/07/11 0.8 10 ND ND ND ND 1.7 ND ND 3.4 ND 2.80 1.20 ND ND 01/12/12 0.8 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 3.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/29/15 0.7 10 ND ND ND ND ND 2.3 J ND 4.0 J ND 3.5 J 3.2 J ND ND 06/23/16 1.5 10 ND ND ND ND ND ND ND 2.9 J ND 1.8 J 3.1 J ND ND Field Parameters pH 07/22/09 -- -- 7.20 6.70 6.19 5.94 5.47 6.03 5.97 5.35 5.20 5.46 5.04 5.61 -- S.U.01/26/10 -- -- 6.80 6.46 6.04 6.18 5.38 5.76 5.90 5.14 5.07 5.39 5.38 5.50 -- 07/07/10 -- -- 6.64 6.24 6.52 6.13 5.72 6.00 6.04 5.29 5.35 5.68 5.40 5.89 -- 01/05/11 -- -- 6.79 6.12 6.18 5.99 5.54 5.92 5.88 5.6 5.39 5.69 5.45 5.84 -- 07/07/11 -- -- 6.66 5.93 6.25 5.95 5.31 5.78 5.60 5.16 5.10 5.38 5.23 5.67 -- 01/12/12 -- -- 7.06 6.41 6.39 6.14 5.78 7.73 7.81 6.24 5.40 6.35 5.66 5.99 -- 07/12/12 -- -- 7.16 6.74 6.56 6.30 5.78 6.19 6.10 5.49 5.33 5.73 5.58 5.99 -- 02/06/13 -- -- 6.80 6.49 6.25 6.13 5.64 6.19 6.09 5.95 5.33 5.70 5.38 5.86 -- 07/09/13 -- -- 7.05 6.59 6.60 5.61 5.08 6.19 5.99 5.29 5.3 5.50 5.95 5.48 -- 01/31/14 -- -- 7.06 6.96 6.87 6.29 6.71 6.45 6.75 6.02 6.13 6.10 6.29 7.19 -- 07/23/14 --- --- 6.72 6.37 6.14 6.5 5.90 6.05 5.32 5.16 5.25 5.77 5.42 5.72 --- 01/27/15 FIELD FIELD 5.84 5.45 6.05 6.03 5.39 6.06 5.80 5.65 5.23 5.95 5.75 5.53 --- 07/29/15 FIELD FIELD 6.45 6.30 6.57 6.14 5.60 6.30 6.15 5.53 5.49 5.82 5.68 6.07 --- 06/23/16 FIELD FIELD 5.42 5.54 5.54 5.36 5.20 4.75 4.69 4.47 4.48 4.55 4.77 5.06 --- Conductivity 07/22/09 -- -- 295 188 283 93.0 104 676 322 168 640 907 526 477 -- µS/cm 01/26/10 -- -- 296 186 283 99.0 100 673 376 151 791 934 503 444 -- 07/07/10 -- -- 276 154 266 95.0 106 717 315 197 729 852 590 432 -- 01/05/11 -- -- 272 143 294 111.0 114 757 337 162 889 966 629 471 -- 07/07/11 -- -- 264 137 249 93.0 103 676 319 191 793 774 605 460 -- 01/12/12 -- -- 218 166 254 87.0 95 558 271 137 709 709 621 424 -- 07/12/12 -- -- 248 142.2 225.9 86.5 97.6 621 294 192.7 685 687 597 445.6 -- 02/06/13 -- -- 257 157.8 215.2 79.4 100.6 517 278.9 114.7 692 683 201 406.3 -- 07/09/13 -- -- 238 6.59 195.1 69.7 87.8 538 249.3 45.1 572 554 587 372 -- 01/31/14 -- -- 220 14.0 220.7 77.9 100.6 589 282.6 158.4 631 752 429 368.2 -- 07/23/14 --- --- 262 118.0 236.0 92.3 115.7 648 309.1 198 629 776 673 472.3 --- 01/27/15 FIELD FIELD 2361 114.3 199.8 65.2 109.6 573 283.2 146.7 676 596 532 363.3 --- 07/29/15 FIELD FIELD 265 124 211 68.0 113 630 286 141 636 649 641 433 --- 06/23/16 FIELD FIELD 315.1 122.9 222.7 73.4 126.8 679 313.5 197.2 761 649 752 391 --- Temperature 07/22/09 -- -- 22.31 17.98 19.84 20.64 18.96 17.43 18.57 18.84 18.23 17.03 19.23 28.29 -- °C 01/26/10 -- -- 16.22 15.72 12.89 10.09 15.73 13.39 13.26 12.3 13.23 14.52 14.32 12.67 -- 07/07/10 -- -- 20.97 23.07 19.09 22.46 18.97 18.5 19.44 19.23 17.75 19.28 17.33 18.5 -- 01/05/11 -- -- 15.19 13.16 13.22 16.14 15.76 12.97 15.94 13.68 13.98 14.46 14.09 14.64 -- 07/07/11 -- -- 19 21.21 21.2 22.05 19.5 17.96 19.23 21.14 20.17 18.59 17.07 18.41 -- 01/12/12 -- -- 13.33 14.55 16.48 17.55 17 14.24 15.27 14.76 15.56 15.88 14.97 14.78 -- 07/12/12 -- -- 18.8 19.60 19.4 20.70 18.2 18.1 18.40 18.8 17.80 18.40 16.2 20.9 -- 02/06/13 -- -- 13.9 17.40 17.2 16.90 16.5 14.8 16.20 14.9 14.90 15.60 14.5 14.6 -- 07/09/13 -- -- 22.5 17.10 17.3 17.20 16.2 15.7 16.20 15.3 15.30 15.30 16 17 -- 01/31/14 -- -- 12.7 16.70 15.6 14.50 15.7 14.5 15.00 14.1 14.40 14.70 14.1 14 -- 07/23/14 --- --- 19.6 19.10 19.1 ---16.9 16.3 17.70 16.4 16.40 18.30 15.9 17.7 --- 01/27/15 FIELD FIELD 12.7 16.9 15.4 15.1 15.9 13.8 15.1 13.5 13.7 13.8 13.9 13.7 --- 07/29/15 FIELD FIELD 19.2 19.53 19.75 17.98 17.36 17.97 18.40 17.50 16.30 17.69 16.68 19.79 --- 06/23/16 FIELD FIELD 17.7 17.7 16.7 18.4 15.8 15.6 16.7 15.7 15.7 15.5 17.2 16.2 --- Turbidity 07/22/09 -- -- 7.51 10.80 5.82 11.20 2.52 4.17 8.48 12 51.60 96.30 42.40 22.40 -- NTU 01/26/10 -- -- 135.0 1.95 1.6 5.51 1.19 0.7 2.89 1 64.60 1.82 43.90 78.60 -- 07/07/10 -- -- 7.7 0.61 5.2 3.98 1.97 0.7 1.43 1.72 62.20 1.1 2.30 66.70 -- 01/05/11 -- -- 0.3 0.97 1.6 2.70 1.7 0.4 0.44 0.41 66.70 0.92 5.89 17.50 -- 07/07/11 -- -- 0.4 5.69 3.9 3.31 2.26 1.3 0.84 1.88 91.5 5.0 2.39 52.40 -- 01/12/12 -- -- 8.8 0.73 1.2 8.43 6.81 6.2 6.23 11.11 30.10 19.30 4.45 9.55 -- 07/12/12 -- -- 3.1 1.99 2.6 9.10 3.77 3.3 4.62 2.73 16.7 3.41 4.76 5.67 -- 02/06/13 -- -- 16.5 12.60 4.7 16.70 2.5 --13.40 4.27 16.00 6.02 44.90 ---- 07/09/13 -- -- 5.4 5.03 7.6 7.81 5.8 7.1 9.37 8.72 15.3 5.29 48.20 6.15 -- 01/31/14 -- -- 4.1 5.81 4.9 4.02 3.99 4.2 5.89 5.32 8.4 5.11 4.40 4.02 -- 07/23/14 --- --- 4.6 3.25 3.8 25.0 4.34 3.5 3.44 5.5 6.3 6.51 5.02 27.10 --- 01/27/15 FIELD FIELD 3.95 3.64 1.83 34.3 1.06 1.14 1.1 0.95 17.4 21.8 5.93 729 --- 07/29/15 FIELD FIELD 7.9 4.8 4.6 4.6 4.5 8 4.6 3.5 153 6.1 7.4 38.4 --- 06/23/16 FIELD FIELD 3.49 4.47 4.30 5.05 3.00 4.79 1.32 2.11 97.3 1.75 11.91 5.24 --- Holly Springs Closed C and D Landfill Permit No. 92-14 Page 3 of 4 Joyce Engineering APPENDIX C Historical Groundwater Constituents/Analytes Analyte Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Oxidation Reduction Potential 07/22/09 -- -- 75.4 92.10 44.1 56.70 108.1 95.4 104.10 128 127.4 118.30 67.30 -20.30 -- mV 01/26/10 -- -- -- 121.10 132.9 175.50 190.3 156.8 115.10 220.1 192.6 174.10 122.20 101.00 -- 07/07/10 -- -- -71.7 -39.30 -3.1 -20.70 53.8 6.2 -31.40 65.9 -46.5 -47.20 -101.10 -116.00 -- 01/05/11 -- -- 46.1 94.10 114.2 109.80 153.5 190.6 173.60 149.5 262.5 139.50 81.70 124.30 -- 07/07/11 -- -- -0.7 104.70 17.0 104.50 77 69.7 79.60 67.2 104.0 18.00 -26.20 77.90 -- 01/12/12 -- -- -39 249.20 83 150.60 61.3 174 -237.80 24.8 201.1 26.70 -18.20 -4.10 -- 07/12/12 -- -- 77.8 67.60 25.7 71.50 125.2 138.4 123.70 137.1 110.2 145.90 4.10 -28.60 -- 02/06/13 -- -- 139.1 131.30 89.3 98.00 179.6 63.2 278.90 182 137.4 211.30 80.20 55.10 -- 07/09/13 -- -- 88.20 159.50 53.10 106.60 174.1 121.90 5.40 169.4 103.10 144.20 100.00 67.90 -- 01/31/14 -- -- 10.80 60.20 65.10 97.60 92.3 51.30 71.00 124.2 100.60 60.20 95.00 48.90 -- 07/23/14 --- --- 765.0 49.1 75.8 29.7 84.2 -567.0 29.2 94.2 98.2 57.5 792.0 80.0 --- 01/27/15 FIELD FIELD 1239.0 125.0 100.4 120.8 142.1 127.1 115.4 140.1 142.3 137.3 105.6 102.4 --- 07/29/15 FIELD FIELD 77.5 77.9 21.7 87.6 124.5 -80.6 20.1 146.6 79.5 61.9 -2.0 43.7 --- 06/23/16 FIELD FIELD 48.0 59.7 56.3 8.2 93.1 66.0 60.2 88.0 -19.9 89.1 15.7 -72.1 --- Dissolved Oxygen 07/22/09 -- -- 3.50 4.16 3.31 3.80 1.58 0.53 1.53 0.67 0.42 0.40 0.67 0.78 -- mg/L 01/26/10 -- -- --7.70 4.64 8.96 4.01 3.43 5.18 6.51 1.76 7.60 1.27 1.89 -- 07/07/10 -- -- 3.70 6.40 4.30 3.60 2.59 2.17 1.03 0.5 0.28 0.57 0.83 0.46 -- 01/05/11 -- -- 1.32 4.36 2.16 4.04 2.72 3.92 2.19 4.66 2.46 4.63 0.73 1.26 -- 07/07/11 -- -- 2.63 5.88 3.12 3.88 3.83 1.18 0.90 0.9 0.71 0.89 0.99 0.63 -- 01/12/12 -- -- 0.69 3.03 2.04 5.50 2.19 2.51 1.00 4.07 2.87 6.18 3.01 0.70 -- 07/12/12 -- -- 3.68 5.72 0.96 3.38 2.37 0.21 0.52 0.3 0.73 0.33 0.27 0.26 -- 02/06/13 -- -- 1.67 2.50 1.48 5.29 4.11 2.99 2.97 5.41 0.86 2.96 0.28 0.88 -- 07/09/13 -- -- 5.25 6.89 0.80 0.49 2.66 0.51 0.22 1.29 0.57 0.86 1.58 1.07 -- 01/31/14 -- -- 2.94 3.98 0.43 5.79 2.2 2.88 1.24 2.8 1.04 7.65 2.38 1.61 -- 07/23/14 --- --- 4.51 5.60 1.42 5.25 2.1 0.98 0.84 1.06 1.77 3.40 1.23 1.12 --- 01/27/15 FIELD FIELD 2.07 5.84 4.95 7.14 2.38 3.36 1.87 3.95 2.49 8.11 1.38 2.69 --- 07/29/15 FIELD FIELD 0.42 6.13 0.60 5.99 1.12 0.86 0.35 0.95 0.41 1.89 0.81 0.67 --- 06/23/16 FIELD FIELD 1.93 2.70 0.59 2.67 1.6 0.40 1.07 0.81 0.32 0.49 2.47 0.60 --- Notes: DL = Method Detection Limit. SWSL = NC-DENR Solid Waste Section Limit. NC 2L = Groundwater Standard established in 15 A NCAC 2L.0202 GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L. ND = Not detected above the DL. J = Estimated concentration below the RL. B = Blank qualified data. dry = Insufficient water to sample. --- = No data. mg/L = milligrams per liter µg/L = micrograms per liter S.U. = Standard Units. NTU = Nephelometric Turbidity Units. µS/cm= microsiemens per centimeter. mV = Millivolts.Bold = Concentrations above the NC 2L or Groundwater Protection standards (GWPS) have been bolded.Blanks = field, trip and/or method blanks. All data prior to 2012 taken from previous reports by Golder Associates NC, Inc. Holly Springs Closed C and D Landfill Permit No. 92-14 Page 4 of 4 Joyce Engineering Appendix D Historical Surface Water Constituents APPENDIX D Historical Surface Water Constituents/Analytes Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Inorganic Compounds Total Arsenic 07/22/09 --- --- dry dry --- NC 2B = 50 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND 07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 ND ND ND 07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry ND ND 07/09/13 --- 10.0 ND 2.39 J ND 01/31/14 --- 10.0 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 1.13 10.0 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.75 10.0 --- 2.10 J ND Total Barium 07/22/09 --- --- dry dry --- No NC 2B Standard 01/26/10 10 100 45.2 J 52.3 J 0.66 J 07/07/10 10 100 dry dry ND 01/05/11 10 100 dry 39.1 J ND 07/07/11 10 100 dry 43.8 J ND 01/12/12 --- 100 74.2 J 48.1 J 0.90 J 07/12/12 --- 100 dry 35.1 J 1.47 J 02/06/13 --- 100 dry 59.8 J 1.05 J 07/09/13 --- 100 51.2 J 79.4 J 0.46 J 01/31/14 --- 100 dry 65.2 J ND 07/23/14 --- --- dry dry --- 01/27/15 0.10 100 37.1 J 75.9 J 0.17 J 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.30 100 --- 78.4 J 3.40 J Total Cadmium 07/22/09 --- --- dry dry --- NC 2B = 2 µg/L 01/26/10 1 1.00 0.14 B ND 0.14 J 07/07/10 1 1.00 dry dry ND 01/05/11 1 1.00 dry ND ND 07/07/11 1 1.00 dry ND ND 01/12/12 --- 1.00 ND ND ND 07/12/12 --- 1.00 dry ND ND 02/06/13 --- 1.00 dry ND ND 07/09/13 --- 1.00 ND 0.07 J ND 01/31/14 --- 1.00 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 0.05 1.00 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.10 1.00 --- ND ND Total Chromium 07/22/09 --- --- dry dry --- NC 2B = 50 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND 07/07/11 10 10.0 dry 1.85 J ND 01/12/12 --- 10.0 2.45 B 2.56 B 0.82 J 07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry 1.46 B 1.42 J 07/09/13 --- 10.0 3.12 B 3.03 B 3.51 J 01/31/14 --- 10.0 dry 0.97 B 2.79 J 07/23/14 --- --- dry dry --- 01/27/15 0.73 10.0 ND 3.31 J ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.43 10.0 --- 1.05 J ND Holly Springs Closed C and D Landfill Permit No. 92-14 1 of 4 Joyce Engineering APPENDIX D Historical Surface Water Constituents/Analytes Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Total Lead 07/22/09 --- --- dry dry --- NC 2B = 25 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND 07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 1.52 J 0.35 J ND 07/12/12 --- 10.0 dry 0.17 J ND 02/06/13 --- 10.0 dry ND ND 07/09/13 --- 10.0 1.26 J 4.50 J 0.08 J 01/31/14 --- 10.0 dry 0.08 J ND 07/23/14 --- --- dry dry --- 01/27/15 0.05 10.0 0.59 J 0.31 J ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.08 10.0 ---0.57 J 0.26 J Total Mercury 07/22/09 --- --- dry dry --- NC 2B = 0.012 µg/L 01/26/10 0.2 0.200 0.06 J ND ND 07/07/10 0.2 0.200 dry dry ND 01/05/11 0.2 0.200 dry ND ND 07/07/11 0.2 0.200 dry ND ND 01/12/12 --- 0.200 ND ND ND 07/12/12 --- 0.200 dry ND ND 02/06/13 --- 0.200 dry ND ND 07/09/13 --- 0.200 0.08 J ND ND 01/31/14 --- 0.200 dry ND 0.114 J 07/23/14 --- --- dry dry --- 01/27/15 0.064 0.200 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.132 0.200 ---ND ND Total Selenium 07/22/09 --- --- dry dry --- NC 2B = 5 µg/L 01/26/10 1 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND 3.01 J 07/07/11 10 10.0 dry ND 3.21 J 01/12/12 --- 10.0 ND 0.81 J ND 07/12/12 --- 10.0 dry 0.72 J ND 02/06/13 --- 10.0 dry 1.59 J ND 07/09/13 --- 10.0 ND 1.65 J ND 01/31/14 --- 10.0 dry 1.19 J ND 07/23/14 --- --- dry dry --- 01/27/15 1.01 10.0 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.85 10.0 ---1.06 J ND Total Silver 07/22/09 --- --- dry dry --- NC 2B = 0.06 µg/L 01/26/10 10 10.0 ND ND 0.73 J 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND 07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 ND ND ND 07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry ND ND 07/09/13 --- 10.0 ND ND ND 01/31/14 --- 10.0 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 0.17 10.0 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 0.22 10.0 ---ND ND Holly Springs Closed C and D Landfill Permit No. 92-14 2 of 4 Joyce Engineering APPENDIX D Historical Surface Water Constituents/Analytes Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Organic Compounds Acetone 01/26/10 5 100 ND ND ND No NC 2B Standard 07/07/10 5 100 dry dry ND 01/05/11 5 100 dry ND ND 07/07/11 5 100 dry 4.4 J ND 01/12/12 --- 100 ND ND ND 07/12/12 --- 100 dry ND ND 02/06/13 --- 100 dry ND ND 07/09/13 --- 100 1.80 B 3.50 B 2.40 J 01/31/14 --- 100 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 5.7 100.0 ND ND ND 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 4.9 100 --- ND ND Field Parameters pH 07/22/09 --- --- dry dry --- S.U. 01/26/10 --- --- 6.65 5.71 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 6.43 --- 07/07/11 --- --- dry 6.87 --- 01/12/12 --- --- 5.83 6.92 --- 07/12/12 --- --- dry 7.25 --- 02/06/13 --- --- dry 6.63 --- 07/09/13 --- --- 6.33 6.29 --- 01/31/14 --- --- dry 6.76 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 6.07 6.30 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 5.09 --- Conductivity 07/22/09 --- --- dry dry --- µS/cm 01/26/10 --- --- 49.00 191.0 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 190.0 --- 07/07/11 --- --- dry 430.0 --- 01/12/12 --- --- 115.00 527.0 --- 07/12/12 --- --- dry 383.5 --- 02/06/13 --- --- dry 652.9 --- 07/09/13 --- --- 99.90 771.0 --- 01/31/14 --- --- dry 506.0 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 260.9 397.2 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 819.0 --- Temperature 07/22/09 --- --- dry dry --- °C 01/26/10 --- --- 6.71 9.16 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 5.85 --- 07/07/11 --- --- dry 21.94 --- 01/12/12 --- --- 10.2 11.02 --- 07/12/12 --- --- dry 23.00 --- 02/06/13 --- --- dry 10.60 --- 07/09/13 --- --- 24.20 23.90 --- 01/31/14 --- --- dry 4.50 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 7.0 6.5 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 20.1 --- Holly Springs Closed C and D Landfill Permit No. 92-14 3 of 4 Joyce Engineering APPENDIX D Historical Surface Water Constituents/Analytes Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Turbidity 07/22/09 --- --- dry dry --- NTU 01/26/10 --- --- 7.79 1.70 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 5.33 --- 07/07/11 --- --- dry 22.30 --- 01/12/12 --- --- 25.50 13.87 --- 07/12/12 --- --- dry 45.00 --- 02/06/13 --- --- dry 4.60 --- 07/09/13 --- --- 21.20 6.29 --- 01/31/14 --- --- dry 3.30 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 15.10 3.76 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 9.17 --- Oxidation Reduction Potential 07/22/09 --- --- dry dry --- mV 01/26/10 --- --- 212.90 20.0 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 117.8 --- 07/07/11 --- --- dry 19.2 --- 01/12/12 --- --- 16.30 100.8 --- 07/12/12 --- --- dry 95.0 --- 02/06/13 --- --- dry 37.0 --- 07/09/13 --- --- -0.90 80.4 --- 01/31/14 --- --- dry 86.0 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 114.7 32.0 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 87.6 --- Dissolved Oxygen 07/22/09 --- --- dry dry --- mg/L 01/26/10 --- --- 11.50 11.49 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 10.22 --- 07/07/11 --- --- dry 6.05 --- 01/12/12 --- --- 7.94 7.87 --- 07/12/12 --- --- dry 2.15 --- 02/06/13 --- --- dry 9.12 --- 07/09/13 --- --- 5.0 6.50 --- 01/31/14 --- --- dry 13.98 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 12.90 12.67 --- 07/29/15 FIELD FIELD DRY DRY --- 06/23/16 FIELD FIELD DRY 1.95 --- Notes: DL = Method Detection Limit. SWSL = NC-DENR Solid Waste Section Limit. NC 2B = Surface Water Standard established in 15A NCAC 2B (NC Freshwater Aquatic Life - Little Branch - Class C Waters) ND = Not detected above the DL. J = Estimated concentration below the SWSL.B = Blank qualified data. dry = Insufficient water flow for sampling. --- = No data. mg/L = milligrams per liter µg/L = micrograms per liter S.U. = Standard Units.NTU = Nephelometric Turbidity Units. µS/cm= microsiemens per centimeter.mV = Millivolts. Bold = Concentrations above the NC 2B Standards. Blanks = field, trip and/or method blanks. All data prior to 2012 taken from previous reports by Golder Associates NC, Inc. Holly Springs Closed C and D Landfill Permit No. 92-14 4 of 4 Joyce Engineering Appendix E Statistical Analyses Worksheets & Summary Table AP P E N D I X E : St a t i s t i c a l B a c k g r o u n d A n a l y s e s Ar s e n i c 1 0 0 % N D , L o g Up p e r T o l e r a n c e L i m i t - I n t r a w e l l 29 . 2 M W - 1 2 2 3 . 5 N O Ar s e n i c 1 0 7 1 % N D N o n - P a r a m e t r i c P r e d i c t i o n I n t e r v a l - I n t r a w e l l 1 4 . 2 MW - 9 2 5 . 6 Y E S Ba r i u m 7 0 0 0 % N D , L o g Up p e r T o l e r a n c e L i m i t - I n t e r w e l l 39 8 MW - 9 9 7 2 Y E S Ch r o m i u m 1 0 0 % N D , L o g Up p e r T o l e r a n c e L i m i t - I n t r a w e l l 10 2 . 8 M W - 9 2 8 . 8 N O Le a d 1 5 1 4 % N D , L o g U p p e r T o l e r a n c e L i m i t - I n t r a w e l l 10 8 . 5 M W - 9 4 1 . 3 N O No t e s : Co n c e n t r a t i o n s a r e i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . NC 2 L = N o r t h C a r o l i n a 2 L G r o u n d w a t e r S t a n d a r d . GW P S = S o l i d W a s t e S e c t i o n G r o u n d w a t e r P r o t e c t S t a n d a r d . SS I = S t a t i s t i c a l l y s i g n i f i c a n t i n c r e a s e o v e r b a c k g r o u n d . %N D = P e r c e n t a g e o f d a t a t h a t w a s n o n - d e t e c t ( t r u n c a t e d ) . Co n s t i t u e n t Da t a D i s t r i b u t i o n St a t i s t i c a l M e t h o d u s e d t o E s t a b l i s h Ba c k g r o u n d Ca l c u l a t e d Ba c k g r o u n d Co n c e n t r a t i o n Sa m p l e Lo c a t i o n SSI NC 2 L Sample Result (µg/L) Re p u b l i c S e r v i c e s - H o l l y S p r i n g s L a n d f i l l Pe r m i t N o . 9 2 - 1 4 Joyce Engineering JOYCE Project: Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Analyte: Arsenic (MW-12 Intrawell) Quantitation Concentration Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 7/22/2009 MW-12 21.40 10 8.00 21.40 2 1/26/2010 MW-12 13.50 10 10.80 14.60 3 7/7/2010 MW-12 13.00 10 11.60 14.00 4 1/5/2011 MW-12 11.60 10 13.00 13.50 5 7/7/2011 MW-12 14.00 10 13.50 13.00 6 1/12/2012 MW-12 10.80 10 14.00 11.60 7 7/12/2012 MW-12 14.60 10 14.60 10.80 8 2/6/2013 MW-13 8.00 10 21.40 8.00 Number of Data: 8 Number of Truncated Data: 0 Percentage of Truncated Data: 0% Upper Tolerance Limit: 29.2 µg/l Notes: All concentrations in micrograms per liter (µg/l). B = Blank qualified data - not used in statistical calculations. ND = Not detected (truncated). Sorted Concentration (µg/l) JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for normality of total Arsenic (MW-12 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 8.00 21.40 13.4 0.6052 8.11 2 10.80 14.60 3.8 0.3164 1.20 3 11.60 14.00 2.4 0.1743 0.42 4 13.00 13.50 0.5 0.0561 0.03 5 13.50 13.00 -0.5 6 14.00 11.60 -2.4 7 14.60 10.80 -3.8 8 21.40 8.00 -13.4 The test statistic W can be found using: W = SQR[B/(SD x SQRT(n-1))] where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 9.76 SD = standard deviation of the data group = 3.88 n = number of samples = 8 W = 0.906 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.874 and the calculated W = 0.906 Therefore the data set is Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for normality of total Arsenic (MW-12 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 2.08 3.06 0.98394938 0.6233 0.61 2 2.38 2.68 0.301475395 0.3031 0.09 3 2.45 2.64 0.188052232 0.1401 0.03 4 2.56 2.60 0.037740328 0.1401 0.01 5 2.60 2.56 -0.03774033 6 2.64 2.45 -0.18805223 7 2.68 2.38 -0.30147539 8 3.06 2.08 -0.98394938 The test statistic W can be found using: W = SQR[B/(SD x SQRT(n-1))] where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 0.74 SD = standard deviation of the data group = 0.28 n = number of samples = 8 W = 0.983 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.803 and the calculated W = 0.983 Therefore the data set is Log-Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Arsenic (MW-12 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest LN[X(i)] = Natural Log Value of sample concentrations arranged from smallest to largest [i/(n+1)] = Cumulative probability n = number of samples = 8 X(i) LN[X(i)] i Rank [Rank/(n+1)]Quantiles 8 2.08 1 1 0.111 -1.22 10.8 2.38 2 2 0.222 -0.76 11.6 2.45 3 3 0.333 -0.43 13 2.56 4 4 0.444 -0.14 13.5 2.60 5 5 0.556 0.14 14 2.64 6 6 0.667 0.43 14.6 2.68 7 7 0.778 0.76 21.4 3.06 8 8 0.889 1.22 Plot analysis indicates that the data more closely follow a normal distribution in the log-transformed format. JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Arsenic (MW-12 Intrawell) R² = 0.8654 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 0 5 10 15 20 25 Qu a n t i l e Concentration (micrograms per liter) Normal Probability Plot Lead Concentrations R² = 0.9162 -2.00 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Qu a n t i l e Ln [Concentration (micrograms per liter)] Log Normal Probability Plot Lead Concentrations JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Determination of reported background value as an outlier Analyte:Arsenic (MW-12 Intrawell) Background Data Quantitation ln(Concentration) Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 07/22/09 MW-12 3.063 10 2 01/26/10 MW-12 2.603 10 3 07/07/10 MW-12 2.565 10 4 01/05/11 MW-12 2.451 10 5 07/07/11 MW-12 2.639 10 6 01/12/12 MW-12 2.380 10 7 07/12/12 MW-12 2.681 10 8 02/06/13 MW-13 2.079 10 mean = 2.558 STD = 0.281 Note: All concentrations are micrograms per liter Using the data listed above, form the statisitc Tn: Tn = (Xn - mean) / STD where: Xn = largest observed sample value mean = mean of the background values STD = standard deviation of the background values For Xn = 3.063 mean = 2.558 STD = 0.281 Tn = 1.802 From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is Number of samples = 8 Tc = 2.032 Since Tc>Tn, the sample result is not considered to be an outlier JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Parametric Tolerance Interval for normally distributed data Analyte:Arsenic (MW-12 Intrawell) Background Data Nat Log Quantitation Concentration Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 07/22/09 MW-12 3.06 10 2 01/26/10 MW-12 2.60 10 3 07/07/10 MW-12 2.56 10 4 01/05/11 MW-12 2.45 10 5 07/07/11 MW-12 2.64 10 6 01/12/12 MW-12 2.38 10 7 07/12/12 MW-12 2.68 10 8 02/06/13 MW-13 2.08 10 Note: All sample concentrations are micrograms per liter Using the background data, the upper Tolerance Limit can be determined using: Upper Tolerance Limit = (Mean Concentration) + K x (Standard Deviation Samples) where: Mean Conc = mean concentration background samples K = factor for constructing one sided normal tolerance limit taken from table 4-2, page 87, Statistical Methods for Groundwater Monitoring, Gibbons, 1994 n = number of background samples STDS = Standard Deviation Samples For:n = 8 K = 3.399 Mean Conc = 2.63 STDS = 0.22 UTL = 29.2 µg/l JOYCE Project: Republic Holly Springs Project No: 895.1501.12 Date: 29-Jul-15 Analyte: Arsenic (MW-9 Intrawell) Quantitation Concentration Limit Sample No. Sample Date Location (µg/L) (µg/L) 1 7/22/2009 MW-9 4.26 J 10 4.26 14.2 2 1/26/2010 MW-9 ND 10 14.20 4.26 3 7/7/2010 MW-9 ND 10 4 1/5/2011 MW-9 ND 10 5 7/7/2011 MW-9 ND 10 6 1/12/2012 MW-9 14.20 10 7 7/12/2012 MW-9 ND 10 Number of Data: 7 Number of Truncated Data: 5 Percentage of Truncated Data: 71% Non-Parametric Prediction Interval: 14.20 µg/L Notes: All concentrations in micrograms per liter (µg/L). B = Blank qualified data - not used in statistical calculations. J = Estimated concentration between laboratory detection limit and quatitation limit. ND = Not detected (truncated). Sorted Concentration (µg/L) JOYCE Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Analyte:Barium Quantitation Concentration Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 7/22/2009 MW-1R 258 100 219 378 2 1/26/2010 MW-1R 327 100 229 327 3 7/7/2010 MW-1R 219 100 238 318 4 1/5/2011 MW-1R 229 100 250 299 5 7/7/2011 MW-1R 266 100 251 266 6 1/12/2012 MW-1R 260 100 252 260 7 7/12/2012 MW-1R 238 100 258 258 8 2/6/2013 MW-1R 250 100 258 258 9 7/9/2013 MW-1R 252 100 260 252 10 1/31/2014 MW-1R 258 100 266 251 11 7/23/2014 MW-1R 251 100 299 250 12 1/27/2015 MW-1R 318 100 318 238 13 7/29/2015 MW-1R 299 100 327 229 14 6/23/2016 MW-1R 378 100 378 219 Number of Data: 14 Number of Truncated Data: 0 Percentage of Truncated Data: 0% Upper Tolerance Limit: 398 µg/l Notes: All concentrations in micrograms per liter (µg/l). B = Blank qualified data - not used in statistical calculations. J = Estimated concentration between laboratory detection limit and quatitation limit. ND = Not detected (truncated). Sorted Concentration (µg/l) JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for normality of total Barium Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 219.00 378.00 159 0.5251 83.49 2 229.00 327.00 98 0.3318 32.52 3 238.00 318.00 80 0.246 19.68 4 250.00 299.00 49 0.1802 8.83 5 251.00 266.00 15 0.124 1.86 6 252.00 260.00 8 0.0727 0.58 7 258.00 258.00 0 0.024 0.00 8 258.00 258.00 0 0.00 9 260.00 252.00 -8 0.00 10 266.00 251.00 -15 0.00 11 299.00 250.00 -49 0.00 12 318.00 238.00 -80 0.00 13 327.00 229.00 -98 0.00 14 378.00 219.00 -159 0.00 The test statistic W can be found using: W = SQR[B/(SD x SQRT(n-1))] where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 146.96 SD = standard deviation of the data group = 43.69 n = number of samples = 14 W = 0.870 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.874 and the calculated W = 0.870 Therefore the data is Non-Normal JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for log normality of Barium Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 5.39 5.93 0.5458 0.5251 0.2866 2 5.43 5.79 0.3562 0.3318 0.1182 3 5.47 5.76 0.2898 0.2460 0.0713 4 5.52 5.70 0.1790 0.1802 0.0323 5 5.53 5.58 0.0580 0.1240 0.0072 6 5.53 5.56 0.0313 0.0727 0.0023 7 5.55 5.55 0.0000 0.0240 0.0000 8 5.55 5.55 0.0000 0.0000 9 5.56 5.53 -0.0313 0.0000 10 5.58 5.53 -0.0580 0.0000 11 5.70 5.52 -0.1790 0.0000 12 5.76 5.47 -0.2898 0.0000 13 5.79 5.43 -0.3562 0.0000 14 5.93 5.39 -0.5458 0.0000 The test statistic W can be found using: W = SQR((B/SD x SQRT(n-1)) where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 0.5178 SD = standard deviation of the data group = 0.1507 n = number of samples = 14 W = 0.9077 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.874 and the calculated W = 0.908 Therefore the data set is Log-Normal JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Barium Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest LN[X(i)] = Natural Log Value of sample concentrations arranged from smallest to largest [i/(n+1)] = Cumulative probability n = number of samples = 14 X(i) LN[X(i)] i Rank [Rank/(n+1)]Quantiles 219 5.39 1 1 0.067 -1.50 229 5.43 2 2 0.133 -1.11 238 5.47 3 3 0.200 -0.84 250 5.52 4 4 0.267 -0.62 251 5.53 5 5 0.333 -0.43 252 5.53 6 6 0.400 -0.25 258 5.55 7 7 0.467 -0.08 258 5.55 8 8 0.533 0.08 260 5.56 9 9 0.600 0.25 266 5.58 10 10 0.667 0.43 299 5.70 11 11 0.733 0.62 318 5.76 12 12 0.800 0.84 327 5.79 13 13 0.867 1.11 378 5.93 14 14 0.933 1.50 Plot analysis indicates that the data more closely follow a normal distribution in the log-transformed format. JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Barium R² = 0.8575 -2.00 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 0 100 200 300 400 Qu a n t i l e Concentration (micrograms per liter) Normal Probability Plot Lead Concentrations R² = 0.899 -2.00 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 2.50 5.20 5.40 5.60 5.80 6.00 Qu a n t i l e Ln [Concentration (micrograms per liter)] Log Normal Probability Plot Lead Concentrations JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Determination of reported background value as an outlier Analyte:Barium Background Data Quantitation ln(Concentration) Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 07/22/09 MW-1R 5.553 100 2 01/26/10 MW-1R 5.790 100 3 07/07/10 MW-1R 5.389 100 4 01/05/11 MW-1R 5.434 100 5 07/07/11 MW-1R 5.583 100 6 01/12/12 MW-1R 5.561 100 7 07/12/12 MW-1R 5.472 100 8 02/06/13 MW-1R 5.521 100 9 07/09/13 MW-1R 5.529 100 10 01/31/14 MW-1R 5.553 100 11 07/23/14 MW-1R 5.525 100 12 01/27/15 MW-1R 5.762 100 13 07/29/15 MW-1R 5.700 100 14 06/23/16 MW-1R 5.935 100 mean = 5.593 STD = 0.151 Note: All concentrations are micrograms per liter Using the data listed above, form the statisitc Tn: Tn = (Xn - mean) / STD where: Xn = largest observed sample value mean = mean of the background values STD = standard deviation of the background values For Xn = 5.935 mean = 5.593 STD = 0.151 Tn = 2.265 From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is Number of samples = 14 Tc = 2.371 Since Tc>Tn, the sample result is not considered to be an outlier JEI Project:Republic - Holly Springs Landfill Project No: 895.1601.12 Date: June 2016 Parametric Tolerance Interval for log normally distributed data Analyte:Barium Background Data: Note use of log(concentration) Background Data Quantitation Concentration Limit Natural Log Sample No. Sample Date Location (µg/l) (µg/l) Concentration 1 07/22/09 MW-1R 258 100 5.553 2 01/26/10 MW-1R 327 100 5.790 3 07/07/10 MW-1R 219 100 5.389 4 01/05/11 MW-1R 229 100 5.434 5 07/07/11 MW-1R 266 100 5.583 6 01/12/12 MW-1R 260 100 5.561 7 07/12/12 MW-1R 238 100 5.472 8 02/06/13 MW-1R 250 100 5.521 9 07/09/13 MW-1R 252 100 5.529 10 01/31/14 MW-1R 258 100 5.553 11 07/23/14 MW-1R 251 100 5.525 12 01/27/15 MW-1R 318 100 5.762 13 07/29/15 MW-1R 299 100 5.700 14 06/23/16 MW-1R 378 100 5.935 Note: All sample concentrations are micrograms per liter Using the background data, the upper Tolerance Limit can be determined using: Upper Tolerance Limit = antilog((Mean Concentration)+K x (Standard Deviation Samples)) where: Mean Conc = mean concentration background samples K = factor for constructing one sided normal tolerance limit taken from table 4-2, page 87, Statistical Methods for Groundwater Monitoring, Gibbons, 1994 STDS = Standard Deviation Samples n = number of background samples For: n = 14 K = 2.614 Mean Conc = 5.593 STDS = 0.151 UTL = 398 µg/l JOYCE Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Analyte:Chromium (MW-9 Intrawell) Quantitation Concentration Limit Sample No. Sample Date Location (µg/l) (µg/l) 1 7/22/2009 MW-9 3.60 10 3.00 22.50 2 1/26/2010 MW-9 5.17 10 3.60 17.90 3 7/7/2010 MW-9 3.85 10 3.85 7.43 4 1/5/2011 MW-9 7.43 10 5.17 5.17 5 7/7/2011 MW-9 22.50 10 7.43 3.85 6 1/12/2012 MW-9 17.90 10 17.90 3.60 7 7/12/2012 MW-9 3.00 10 22.50 3.00 Number of Data: 5 Number of Truncated Data: 0 Percentage of Truncated Data: 0% Upper Tolerance Limit: 102.8 µg/l Notes: All concentrations in micrograms per liter (µg/l). B = Blank qualified data - not used in statistical calculations. ND = Not detected (truncated). Sorted Concentration (µg/l) JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for normality of total Chromium (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 3.00 22.50 19.5 0.6233 12.15 2 3.60 17.90 14.3 0.3031 4.33 3 3.85 7.43 3.58 0.1401 0.50 4 5.17 5.17 0 0.0000 0.00 5 7.43 3.85 -3.58 6 17.90 3.60 -14.3 7 22.50 3.00 -19.5 The test statistic W can be found using: W = SQR[B/(SD x SQRT(n-1))] where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 16.99 SD = standard deviation of the data group = 7.86 n = number of samples = 7 W = 0.780 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.803 and the calculated W = 0.780 Therefore the data is Non-Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for log normality of Chromium (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 1.10 3.11 2.0149 0.6233 1.2559 2 1.28 2.88 1.6039 0.3031 0.4861 3 1.35 2.01 0.6575 0.1401 0.0921 4 1.64 1.64 0.0000 0.0000 0.0000 5 2.01 1.35 -0.6575 6 2.88 1.28 -1.6039 7 3.11 1.10 -2.0149 The test statistic W can be found using: W = SQR((B/SD x SQRT(n-1)) where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 1.8341 SD = standard deviation of the data group = 0.8009 n = number of samples = 7 W = 0.8740 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.803 and the calculated W = 0.874 Therefore the data set is Log-Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Chromium (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest LN[X(i)] = Natural Log Value of sample concentrations arranged from smallest to largest [i/(n+1)] = Cumulative probability n = number of samples = 7 X(i) LN[X(i)] i Rank [Rank/(n+1)]Quantiles 3 1.10 1 1 0.125 -1.15 3.6 1.28 2 2 0.250 -0.67 3.85 1.35 3 3 0.375 -0.32 5.17 1.64 4 4 0.500 0.00 7.43 2.01 5 5 0.625 0.32 17.9 2.88 6 6 0.750 0.67 22.5 3.11 7 7 0.875 1.15 Plot analysis indicates that the data more closely follow a normal distribution in the log-transformed format. JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Chromium (MW-9 Intrawell) R² = 0.7927 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 0 5 10 15 20 25 Qu a n t i l e Concentration (micrograms per liter) Normal Probability Plot Lead Concentrations R² = 0.9002 -2.00 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Qu a n t i l e Ln [Concentration (micrograms per liter)] Log Normal Probability Plot Lead Concentrations JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Determination of reported background value as an outlier Analyte:Chromium (MW-9 Intrawell) Background Data Quantitation ln(Concentration) Limit Sample No. Sample Date Location (ug/l) (ug/l) 1 07/22/09 MW-9 1.281 10 2 01/26/10 MW-9 1.643 10 3 07/07/10 MW-9 1.348 10 4 01/05/11 MW-9 2.006 10 5 07/07/11 MW-9 3.114 10 6 01/12/12 MW-9 2.885 10 7 07/12/12 MW-9 1.099 10 mean = 1.878 STD = 0.748 Note: All concentrations are micrograms per liter Using the data listed above, form the statisitc Tn: Tn = (Xn - mean) / STD where: Xn = largest observed sample value mean = mean of the background values STD = standard deviation of the background values For Xn = 3.114 mean = 1.878 STD = 0.748 Tn = 1.652 From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is Number of samples = 7 Tc = 1.938 Since Tc>Tn, the sample result is not considered to be an outlier JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Parametric Tolerance Interval for log normally distributed data Analyte:Chromium (MW-9 Intrawell) Background Data: Note use of log(concentration) Background Data Quantitation Concentration Limit Natural Log Sample No. Sample Date Location (µg/l) (µg/l) Concentration 1 07/22/09 MW-9 3.600 10.000 1.281 2 01/26/10 MW-9 5.170 10.000 1.643 3 07/07/10 MW-9 3.850 10.000 1.348 4 01/05/11 MW-9 7.430 10.000 2.006 5 07/07/11 MW-9 22.500 10.000 3.114 6 01/12/12 MW-9 17.900 10.000 2.885 7 07/12/12 MW-9 3.000 10.000 1.099 Note: All sample concentrations are micrograms per liter Using the background data, the upper Tolerance Limit can be determined using: Upper Tolerance Limit = antilog((Mean Concentration)+K x (Standard Deviation Samples)) where: Mean Conc = mean concentration background samples K = factor for constructing one sided normal tolerance limit taken from table 4-2, page 87, Statistical Methods for Groundwater Monitoring, Gibbons, 1994 STDS = Standard Deviation Samples n = number of background samples For: n = 7 K = 3.399 Mean Conc = 1.911 STDS = 0.801 UTL = 102.82 µg/l JOYCE Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Analyte:Lead (MW-9 Intrawell) Quantitation Concentration Limit (QL) Sample No. Sample Date Location (µg/l) (µg/l) 1 7/22/2009 MW-9 2.31 10 0.98 19.60 2 1/26/2010 MW-9 4.85 10 2.31 11.30 3 7/7/2010 MW-9 2.66 10 2.66 5.48 4 1/5/2011 MW-9 5.00 10 4.85 5.00 5 7/7/2011 MW-9 11.30 10 5.00 4.85 6 1/12/2012 MW-9 19.60 10 5.48 2.66 7 7/12/2012 MW-9 0.98 10 11.30 2.31 8 2/6/2013 MW-9 5.48 10 19.60 0.98 Number of Data 8 Number of Truncated Data 1 Percentage of Truncated Data 13% Upper Tolerance Limit: 108.5 µg/l Notes: All concentrations in micrograms per liter (µg/l). B = Blank qualified data - not used in statistical calculations. J = Estimated concentration between laboratory detection limit and quatitation limit. ND = Not detected (truncated). ND have been replaced with 1/2 QL and are shaded Sorted Concentration (µg/l) JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for normality of total Lead (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 0.98 19.60 18.62 0.6052 11.27 2 2.31 11.30 8.99 0.3164 2.84 3 2.66 5.48 2.82 0.1743 0.49 4 4.85 5.00 0.15 0.0561 0.01 5 5.00 4.85 -0.15 6 5.48 2.66 -2.82 7 11.30 2.31 -8.99 8 19.60 0.98 -18.62 The test statistic W can be found using: W = SQR[B/(SD x SQRT(n-1))] where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 14.61 SD = standard deviation of the data group = 6.13 n = number of samples = 8 W = 0.811 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.749 and the calculated W = 0.811 Therefore the data set is Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Shapiro Wilk Test Statistic (W) for log normality of Lead (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest X(n-i+1) = sample values arranged from largest to smallest A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water Data at RCRA Facilities B(i) = summation of (X(n-i+1)-X(i))A(n-i+1) i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i) 1 -0.02 2.98 2.9957 0.6052 1.8130 2 0.84 2.42 1.5876 0.3164 0.5023 3 0.98 1.70 0.7228 0.1743 0.1260 4 1.58 1.61 0.0305 0.0561 0.0017 5 1.61 1.58 -0.0305 6 1.70 0.98 -0.7228 7 2.42 0.84 -1.5876 8 2.98 -0.02 -2.9957 The test statistic W can be found using: W = SQR((B/SD x SQRT(n-1)) where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 2.4430 SD = standard deviation of the data group = 0.9345 n = number of samples = 8 W = 0.9764 Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft) July, 1992, to determine if the data is normally distributed. From Table A-2 with (n) samples and a 95% confidence level, the critical value is W(crit) = 0.749 and the calculated W = 0.976 Therefore the data set is Log-Normal JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Lead (MW-9 Intrawell) Complete the following table where i = ordered value of sample, arranged from smallest to largest X(i) = sample values arranged from smallest to largest LN[X(i)] = Natural Log Value of sample concentrations arranged from smallest to largest [i/(n+1)] = Cumulative probability n = number of samples = 8 X(i) LN[X(i)] i Rank [Rank/(n+1)]Quantiles 0.98 -0.02 1 1 0.111 -1.22 2.31 0.84 2 2 0.222 -0.76 2.66 0.98 3 3 0.333 -0.43 4.85 1.58 4 4 0.444 -0.14 5 1.61 5 5 0.556 0.14 5.48 1.70 6 6 0.667 0.43 11.3 2.42 7 7 0.778 0.76 19.6 2.98 8 8 0.889 1.22 Plot analysis indicates that the data more closely follow a normal distribution in the log-transformed format. JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Probability Plots to determine the distribution of Lead (MW-9 Intrawell) R² = 0.7918 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 2.00 0 5 10 15 20 25 Qu a n t i l e Concentration (micrograms per liter) Normal Probability Plot Lead Concentrations R² = 0.9651 -2.00 -1.50 -1.00 -0.50 0.00 0.50 1.00 1.50 -0.50 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Qu a n t i l e Ln [Concentration (micrograms per liter)] Log Normal Probability Plot Lead Concentrations JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Determination of reported background value as an outlier Analyte:Lead (MW-9 Intrawell) Background Data Quantitation ln(Concentration) Limit Sample No. Sample Date Location (ug/l) (ug/l) 1 07/22/09 MW-9 0.837 10 2 01/26/10 MW-9 1.579 10 3 07/07/10 MW-9 0.978 10 4 01/05/11 MW-9 1.609 10 5 07/07/11 MW-9 2.425 10 6 01/12/12 MW-9 2.976 10 7 07/12/12 MW-9 -0.020 10 8 02/06/13 MW-9 1.701 10 mean = 1.511 STD = 0.934 Note: All concentrations are micrograms per liter Using the data listed above, form the statisitc Tn: Tn = (Xn - mean) / STD where: Xn = largest observed sample value mean = mean of the background values STD = standard deviation of the background values For Xn = 2.425 mean = 1.511 STD = 0.934 Tn = 0.978 From Table 8 included in the Staistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Interim Final Guidance, the critical value for the given sample group is Number of samples = 8 Tc = 2.032 Since Tc>Tn, the sample result is not considered to be an outlier JEI Project:Republic Holly Springs Project No: 895.1601.12 Date: June 2016 Parametric Tolerance Interval for log normally distributed data Analyte:Lead (MW-9 Intrawell) Background Data: Note use of log(concentration) Background Data Quantitation Concentration Limit Natural Log Sample No. Sample Date Location (µg/l) (µg/l) Concentration 1 07/22/09 MW-9 2.310 10.000 0.837 2 01/26/10 MW-9 4.850 10.000 1.579 3 07/07/10 MW-9 2.660 10.000 0.978 4 01/05/11 MW-9 5.000 10.000 1.609 5 07/07/11 MW-9 11.300 10.000 2.425 6 01/12/12 MW-9 19.600 10.000 2.976 7 07/12/12 MW-9 0.980 10.000 -0.020 8 02/06/13 MW-9 5.480 10.000 1.701 Note: All sample concentrations are micrograms per liter Using the background data, the upper Tolerance Limit can be determined using: Upper Tolerance Limit = antilog((Mean Concentration)+K x (Standard Deviation Samples)) where: Mean Conc = mean concentration background samples K = factor for constructing one sided normal tolerance limit taken from table 4-2, page 87, Statistical Methods for Groundwater Monitoring, Gibbons, 1994 STDS = Standard Deviation Samples n = number of background samples For: n = 8 K = 3.399 Mean Conc = 1.511 STDS = 0.934 UTL = 108.52 µg/l