IDX GW Monitoring Rpt July 1999 (SF)-OCR

*5921HSSF1066*
1111111111111111111111111111
DocumentlD NONCD0001814
Site Name HAMILTON BEACH/PROCTOR SILEX
oocumentType Progress/Monitoring Rpt (PRGMON)
RptSegment 1
DocDate
DocRcvd
Box
Accesslevel
Division
Section
Program
DocCat
10/5/1999
2/20/2007
SF1066
PUBLIC
WASTE MANAGEMENT
SUPERFUND
IHS {IHS)
FACILITY
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CERTIFICATION PAGE
GROUNDWATER MONITORING REPORT
FOR JULY 1999
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater Incident No. 14338
Site Priority Ranking B
I, James Narkunas, a Licensed Geologist in the State of North Carolina, certify that
this I,"eport and its contents have been prepared under my direct control and personal
superv1s10n.
650138.0901 Samp7-99.doc (10/05/99) ii
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TABLE OF CONTENTS
Certification Page ................................................................................................................ ii
List of Figures .................................................................................................................... iv
List of Tables ...................................................................................................................... v
1.0 INTRODUCTION .......... : ................................................................................................ 1-1
2.0 FIELD METHODS .......................................................................................................... 2-1 ,
3.0 RESULTS ........................................................................................................................ 3-1
3 .1 Water Level Measurements ................................................................................. 3-1
3.2 Analytical Re~ults ................................................................................................ 3-1
APPENDIX A WELL CONSTRUCTION REPORTS
APPENDIX B GROUNDWATER SAMPLING ANALYTICAL REPORTS
650138.0901 Samp7-99.doc (10/05/99) 111
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1-1
2-1
3-1
3-2
LIST OF FIGURES
Topographic Map, Hamilton BeachOProctor-Silex, Inc.
Site Map, Washington Facility, Hamilton BeachOProctor-Silex, Inc.
Generalized Groundwater Flow Direction Map for Hydrogeologic Unit A,
Washington Facility
Generalized Groundwater Flow Direction Map for Hydrogeologic Unit B,
Washington Facility
650138.0901 Samp7-99.doc (10/05/99) IV
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LIST OF TABLES
2-1 Monitoring Well Construction Data for Sampled Wells
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-1 Water Level Measurements and Elevations, July 1, 1999
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-2 Historical Water Level Elevations at MW-220
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-3 Historical Water Level Elevations at MW-222
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-4 Historical Water Level Elevations at MW-224
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-5 Historical Water Level Elevations at MW-225
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-6 Historical Water Level Elevations at MW-226
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-7 Historical Water Level Elevations at MW-230
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-8 Historical Water Level Elevations at MW-233
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina . '
3-9 Historical Water Level Elevations at MW-234
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-10 Field Measurements, July 1, 1999
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-11 Qualified Analytical Results, Volatile Organic Compounds by Method 8260B, July 1999
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-12 Historical Analytical Results for MW-220
Hamilton Beach</Proctor/Silex, Inc., Washington, North Carolina
3-13 Historical Analytical Results for MW-222
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
650138.0901 Samp7-99.doc (10/05/99) v
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LIST OF TABLES (Continued)
3-14 Historical Analytical Results for MW-224
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-15 Historical Analytical Results for MW-225
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-16 Historical Analytical Results for MW-226
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-17 Historical Analytical Results for MW-230
Hamilton Beach<> Proctor/Silex, Inc., Washington, North Carolina
3-18 Historical Analytical Results forMW-233
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
3-19 Historic.al Analytical Results for MW-234
Hamilton Beach<>Proctor/Silex, Inc., Washington, North Carolina
650138.0901 Samp7-99.doc (10/05/99) vi
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1.0 INTRODUCTION
The Hamilton Beach<> Proctor-Silex (HB<>PS) facility is located at 234 Springs
Road, north of the City of Washington, in Beaufort County, North Carolina (Figure 1-1). The
facility and surrounding land parcel are owned by the City of Washington and have been leased
by HB<>PS since 1990 and previ0,µsly leased by predecessor companies. The facility is involved
in the final assembly, packaging, and warehousing of small electrical household appliances.
Since 1992, when organic compounds were initially detected in groundwater at
the site, several phases of investigation have been performed, including a comprehensive· site
assessment (CSA). The results of the CSA indicated that a plume of organic compounds is
present in groundwater underlying the site. The specific nature, volume, and time period of any
releases contributing to the plume are unknown. However, the principal constituents of the
plume are no longer used at the facility.
A plan for corrective action at the site has been proposed. Until corrective action
is implemented, groundwater will be sampled and analyzed on a quarterly schedule according to
a monitoring program requested and approved by the Department of Environment and Natural
Resources, Groundwater Section. The purpose of the monitoring program is to sample selected
downgradient monitoring wells to detect potential migration of the plume.
Radian International (Radian) conducted groundwater sampling at the facility in
July 1999. The sampling event included the measurement of water levels, temperature, pH, and
specific conductance; and the collection and analysis of samples from eight monitoring wells.
This report describes the sampling methods and presents the results for the first quarterly
sampling event.
650138.0901 Samp7-99.doc (10/05/99) 1-1
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2.0 FIELD METHODS
Groundwater was sampled on July 1, 1999, in general accordance with the
methods outlined in the Field Sampling and Analysis Plan prepared in April 1997 for this site.
Two of the eight wells (MW-233 and MW-234) sampled were installed in June
1999 and the remaining six wells were installed during the CSA in 1998. The locations of the
eight monitoring wells are shown in Figure 2-1. Details of well cons'truction are provided in
Table 2-1. Well Construction Reports for the newly constructed monitoring wells, MW-233 and
MW-234, are included as Appendix A.
Prior to sampling, the water level in each well was measured using an electric
water-level indicator. The wells were then purged using dedicated inertial foot-valve pumps.
Temperature, pH, and specific conductance were measured and the data were recorded in a field
notebook. Purging continued until temperature, pH, and specific conductance stabilized; a
minimum of three well volumes was extracted; or the well was pumped dry. Each of the wells
was then sampled immediately following well purging using the dedicated inertial foot-valve
pump.
The groundwater samples were sent by overnight courier to Radian Analytical
Services in Austin, Texas, for analysis of volatile organic compounds by EPA Method 8260B.
650138.0901 Samp7-99.doc (10/05/99) 2-1
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3.0 RESULTS
3.1 Water Level Measurements
Table 3-1 presents the depth to groundwater and static water-level elevations
measured in the eight wells samp]ed and three additional wells. Maps showing the generalized
direction of groundwater flow in hydrogeologic units A and B are included as Figures 3-1 and
3-2, respectively. Historical water-level elevations in sampled wells are included in Tables 3-2
to 3-9.
3.2 Analytical Results
Measurements of water temperature, pH, and specific conductance recorded in the
field are summarized in Table 3-10.
A summary of qualified analytical results is presented in Table 3-11. No analytes
were detected above the groundwater standards in ~y sample. Carbon disulfide and toluene
were the only analytes reported at detectable concentrations. Qualified data sheets and
laboratory reports are included in Appendix B.
Historical analytical results for the sampled wells ~re presented in Tables 3-12 to
3-19. A comparison of the latest results with earlier results suggests that the plume remains on-
site, at least 200 feet, or approximately ten years time-of-travel, from the nearest potential
receptors located north of Spring Road (Figure 3-3); In addition, the results indicate that no
vertical migration into the Limestone Aquifer has occurred.
650138.0901 Samp7-99.doc (10/05/99) 3-1
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FIGURES
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TABLES
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Well
V' MW-202
MW-220
v-I-MW-221
MW-222
....... MW-223
MW-224
;::. MW-225
MW-226
.......... MW-230 ..-MW-233
MW-234
Table 3-1
Water Level Measurements and Elevations
July 1, 1999
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Measu.ring Point Water Level
Elevation Elevation
(ft above msl)) Depth to Water (ft) (ft above msl)
34.98 10.18 24.80
31.50 10.00 . 21.50
31.39 9.76 21.63
35.11 l4.50 20.61
35.15 7.70 27.45
33.43 9.04 24.39
33.43' 8.93 24.5Q
28.46 19.92 8.54
33.47 "-11.(57 21.80.
34.55 12.07 22.48
35.03 11.79 23.24
msl = mean sea level
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Table 3-2
Historical Water Level Elevations at MW-220
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 v 25.13
November 16, 1998 20.55
July 1, 1999 21.50
msl = mean sea level
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Table 3-3
Historical Water Level Elevations at MW-222
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Water Level Elevation
Date (ft. above msl)
May 13, 1998 22.34
November 16, 1998 19.99
July 1, 1999 20.61
msl = mean sea level
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Table 3-4
Historical Water Level Elevations at MW-224
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
msl = mean sea level
NM = Not measured
Water Level Elevation
(ft. above msl)
NM
23.64
24.39
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Table 3-5
Historical Water Level Elevations at MW-225
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
msl = mean sea level
NM =Not measured
Water Level Elevation.
(ft. above msl)
NM
24.36
24.50
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Table 3-8
Historical Water Level Elevations at MW-233
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998 ,
November 16, 1998
July 1, 1999
msl = mean sea level
NM =Not measured
Water Level Elevation
(ft. above msl)
NM
NM
22.48
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Table 3-9
Historical Water Level Elevations at MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Date
May 13, 1998
November 16, 1998
July 1, 1999
msl = mean sea level
NM =Not measured
Water Level Elevation
(ft. above msl)
NM
NM
23.24
--~-~---~--~-----~-
Table 3-11
Qualified Analytical Results
Volatile Organic Compounds by Method 8260B
July 1999
Groundwater
Analyte Standard MW-220
Carbon disulfide 700 0.426 J
Toluene 1,000 ND (0.0766)
Target analytes no~ listed were not detected.
All results reported in micrograms per liter.
ND =Not detected at (detection limit).
J = Estimated value.
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Monitorinl! Well Network
MW-222 MW-224 MW-225 MW-226
0.338 J 2.22 ND (0.864) _ ND (0.864)
ND (0.0766) ND (0.0766) ND (0.0766) ND (0.0766)
"MW-230 MW-233 MW-234
ND (0.864) ND (0.864) ND (0.864)
0.286 ND (0.0766) ND (0.0766)
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Table 3-12
Historical Analytical Results for MW-220
Hamilton BeachO Proctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard .
Carbon disulfide . 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS = Not sampled.
May 1998 November 1998
ND (0.0547) ND (0.0547)
ND (0.0715) ND (0.0715)
ND (0.0522) ND (0.0522)
U = Not detected at associated level; blank contamination is present.
July 1999
0.426 J
ND (0.102)
ND (0.0766)
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Table 3-13
Historical Analytical Results for MW-222
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard
Carbon disulfide 700 .
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS "'"Not sampled.
May 1998 November 1998
ND (0.0547) ND (0.0547)
0.0908 J ND (0.0715)
0.156 J ND (0.0522)
U =Not detected at associated level; blank contamination is present.
July 1999
0.388 J
ND (0.102)
ND (0.0766)
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Table 3-15
Historical Analytical Results for MW-225
Hamilton Beach<>Proctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
D = ot detected at (detection limit).
NS = Not sampled.
Mav 1998 November 1998
NS ND (0.0547)
NS ND (0.0715)
NS ND (0.0522)
U = Not detected at associated level; blank contamination is present.
r.rwv-1999
ND (0.864)
ND (0 .102)
ND (0 .864)
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Table 3-16
Historical Analytical Results for MW-226
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS = Not sampled.
May 1998 November 1998
NS ND (0.0547)
NS ND (0.0715)
NS ND (0.0522)
U = Not detected at associated level; blank contamination is present.
CJUly 1999
ND (0 .864)
ND (0.102)
ND (0.0766)
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Table 3-17
Historical Analytical Results for MW-230
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard
Carbon disulfide 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS =Not sampled.
May 1998 November 1998
NS ND (0.0547)
NS ND (0.306) U
NS ND (0.0522)
U =Not detected at associated level; blank contamination is prysent.
July 1999
ND (0.864)
ND (0.102)
0.286
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Table 3-18
Historical Analytical Results for MW-233
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard May 1998 November 1998
Carbon disulfide 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS = Not sampled.
NS
NS
NS
U =Not detected at associated level; blank contamination is present.
NS
NS
NS
JUiy 1999 J
ND (0.864)
ND (0.102)
ND (0.0766)
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Table 3-19
Historical Analytical Results for MW-234
Hamilton BeachOProctor-Silex, Inc.
Washington, North Carolina
Groundwater
Analyte Standard May 1998 November 1998
Carbon disulfide 700
1, 1-Dichloroethene 7
Toluene 1,000
Target analytes not listed were not detected.
All samples reported in micrograms per liter.
J = Estimated value.
ND =Not detected at (detection limit).
NS =Not sampled.
NS
NS
NS
U = Not detected at associated level; blank contamination is present.
NS
NS
NS
aUiY 1999
ND (0.864)
ND (0.102)
ND (0.0766)
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APPENDIX A
WELL .CONSTRUCTION REPORTS ·
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APPENDIXB
GROUNDWATER SAMPLING ANALYTICAL REPORTS
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QUALIFIED DATA
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Introduction
On July 1, 1999, Radian International collected eight groundwater samples (0799HBWW-220, -222, -224-
226, -230, -233, and-234) and an equipment blank (0799HBWWE01) at the Hamilton Beach-Proctor Silex
facility in Washington, NC. The samples were submitted to Radian's Analytical Services (RAS) laboratory
in Austin, Texas for the-determination of volatile organic compounds (VOC) by SW-846 Method 8260B. A
trip blank was included in the shipment of samples to the laboratory for the analysis ofVOC.
Radian reviewed the analytical results, which were reported by the laboratory under work order numbers
9907079 and 9907080. The data e~·aluation was modeled after the National Functional Guidelines for
Organic and Inorganic Data Review (EPA, February 1994). Accuracy was determined from the review of
holding times, spike recoveries, initial and continuing calibration, and blank contamination. Precision was
based on the evaluation of laboratory duplicate results. Sample results, presented in the Results Summary,
have been appropriately qualified based on criteria of the review process. The results of the data evaluation
are summarized below.
Sample Condition upon Receipt and Holding Times
All samples were recej_ved intact and in good condition by RAS laboratory on July 2, 1999. The
temperature of the samples was within laboratory specification limits of 2-6°C upon receipt. Small air
bubbles (2 millimeters in size) were observed in the volatile organic analysis (VOA) vials that were
received by the laboratory for the trip blank. Qualification of the trip blank results is not warranted since
the air bubbles were less than 6 millimeters in size.
Technical hold times were assessed by comparing the sampling dates with that of the analysis date.
Samples were analyzed within EPA-established holding times of seven days for unpreserved samples.
Calibration
Control limits for initial and continuing instrument calibrations are established to ensure that the instrument
is capable of producing accurate quantitative and qualitative data at the beginning and throughout each of
the analyses.
Laboratory specifications were met during the initial and continuing calibrations. Except for a few
analytes, project1 specifications were also met during the calibration of the instrument. During the initial
calibration of May 17 on instrument MSDB, the response factor (0.0322) for acrolein was less than 0.05.
Non-detect sample results for acrolein were qualified as unusable (R) because of poor instrument
sensitivity. The recovery for acetone (71), acetonitrile (78), acrolein (56), and MEK (78) during the July 7
analysis of the continuing calibration standard was less than 80%. The recovery was also less than 80% for
acetone (76), acetonitrile (78), and acrolein (61) during the continuing calibration of July 8. Associated
sample results were qualified as estimated (J/UJ).
Blank Contamina~on
Laboratory blanks are clean liquid and/or solid matrix samples prepared by the analytical laboratory and
analyzed in the same manner as the field samples. Laboratory blanks are us~d to ensure that the field
samples are not contaminated during the sample preparation, sample analysis, or from previous sample
(instrument carry-over). Equipment blanks consist of analyte-free water, which is provided by the
laboratory, poured over or through sampling equipment and collected into the sample bottles. Trip blanks
1 Response factor is greater than or equal to 0.05 and the percent relative standard deviation is less than or equal to 30
for all target analytes during the initial calibration. The recovery of the continuing calibration verification standard is
within 80-120% of the true value during the continuing calibration.
0799 HB-PS DE.doc
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07/21/99
are analyte-free water samples that accompany volatile investigative samples during all stages of shipment,
storage, and analysis. The trip blanks are used to assess the potential for artificial introduction of volatile
compounds into the investigative samples during the transportation and sample handling processes.
voe were not detected in the laboratory blank. Methylene chloride, a common blank contaminant, was
detected at a concentration of 0.182 and 523 parts per billion (ppb) in the trip and equipment blanks,
respectively. Equipment blank 0799HBWWE01 also contained chloromethane and bromochloromethane
at a concentration of 0.450 and 0.509 ppb, respectively. According to the laboratory, the water provided
for the equipment blank had been obtained from the extraction lab and had been apparently contaminated
with voe. Qualification of the data due to blank contamination is not warranted, however, since these
three analytes were not detected in any of the samples.
Surrogate Spikes and Internal Standards
System monitoring compounds (surrogates) are those compounds that are not expected to be detected in the
field samples, but which are chemically similar to the analytes of interest. Surrogate compound percent
recoveries are used to assess extraction efficiencies, possible matrix effects, and overall analytical
accuracy. Internal standards are analytes of interest that are added to each sample prior to analysis to
ensure that Ge/MS sensitivity and responses remain stable.
Surrogate and internal standard results met laboratory specification limits for all samples.
Laboratory Control Samples
Laboratory control samples (LeS) are blank samples fortified (spiked) with known concentrations of
analyte of interest The percent recoveries and/or duplicate results of the Les and their duplicates are used
to assess extraction efficiencies and overall analytical accuracy and precision.
Laboratory specifications were met during the Les VOA. Except for vinyl acetate, projecr specifications
were met during the volatile Les analyses. The recovery ( 50, 51 % ) for vinyl acetate was less than 60%
during the Les and Leso analysis. Non-detect vinyl acetate sample results were qualified as unusable (R)
because of the low recoveries.
Matrix Spikes
Matrix spikes are samples spiked with known concentrations of analytes of interest. MS percent recoveries
and duplicate results are used to assess extraction efficiencies, possible matrix effects, and overall
analytical accuracy and precision.
Accuracy and precision criteria were met during the matrix spike (MS) and MS duplicate analysis of the
batch sample for voe.
2 The recovery of either the LCS or LCSD must be within 60-140%.
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07/21199
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RAW DATA
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I .
I
I
I
I ,,
I
I
-
07/12/99 17:ll:OQ
Report RADIAN INTERNATIONAL
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Prepared _-!:R~a~de!i~a~n~I""n"'t:::e~r""n~a.,,t..;:i:::o,.n~ae!l",....:.L:oL::.C:...
By _ _.:.1~4~0~4~6:......::S~u~m~m~i~t:......::D~r~·~·-=B~l~d~g~·-=B:...
P. 0. Box 201088
Austin, TX 78720-1088
CSC JALINDSEY
Project Sample
Description
0799HBWW220
0799HBWW222
0799HBWW224
0799HBWW225
0799HBWW226
0799HBWW230
0799HBWW233
0799HBWWE01
ID/
----.. -
WOR~ ORDBR SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON NC
Work ID WATER SUPPLY
Case II "N"'A..._ _______ _
SDG II ~N~A _______ _
RAS # 90222AJAL
Lab Sample ID Test Code(s)
on. 826SWACM
OlB SPAREBOO
OlC SPAREBOO
02A 826SWACM
02B SPAREBOO
02C SPAREBOO
03A 826SWACM
03B SPAREBOO
03C SPAREBOO
04A 826SWACM
04B SPAREBOO
04C SPAREBOO
05A 826SWACM
05B SPAREBOO
05C SPAREBOO
06A 826SWACM
06B SPAREBOO
06C SPAREBOO
07A 826SWACM
07B SPAREBOO
07C SPAREBOO
08A 826SWACM
OBB SPARE~OO
.. -- -
Work Order # 9907079
Page _1_
RCN 650138.0901
New York ELAP ID#: 10915
•
Method Desciption
Volatile Organics by GC/MS
Spare Sample
Spare Sample
V~latile Organics by GC/MS
Spare Sample
Spare Sample
Volatile Organics by GC/MS
Spare Sample
Spare Sample
Volatile Organics by GC/MS
Spare Sample
Spare Sample
Volatile Organics by GC/MS
Spare Sample
Spare Sample
Volatile Organics by GC/MS
Spare Sample
Spare sample
Volatile Organics by GC/MS
Spare Sample
Spare Sample
Volatile Organics by GC/MS
Spare Sample
- - ------
------
07/12/99 17:11:00
Report RADIAN INTERNATIONAL
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Prepared --"R~a~d,,,,i:.::a:.:.n,_,Io.:.n:..::t:.::e:..:r:.:.n,,a:..::t:..::i:.::o"-n"'a:..::l"''-"L"'L"'C'­
By --=1:.:4..:::0:.:4..:::6--==:S..:::uc:;;m:::;m:.::i..:::t--"D:.::r..:.._,_, _:;B:.::l..:::d:.;;q..,-_:;B'-
P. 0. Box 201088
Austin, TX 78720-1088
CSC JALINDSEY
Project Sample
Description
0799HBWWE01
TRIP BLANK
ID/
--- ------ --
II 0 R :I: 0 R D B R S UM MAR Y (Cont'd)
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON,NC
Wo~k ID WATER SUPPLY
Case # .:;N;.:.A,__ _______ _
SDG II .N .. A...._ _______ _
RAS II 90222AJAL
Lab Sample ID Test Code(s)
oac SPAREBOO
09A 826SWACM
09B SPAREBOO
Work Order # 9907079
Page L._
RCN 650138.0901
New York ELAP ID II: 10915
~
Method Desciption
Spare Sample
Volatile Organics by GC/MS
Spare Sample
---
07/12/99 17:11:00
---
llORI: ORDBR COMMBJITS
The standard Method 8260A surrogate tolerances are laboratory derived from
historical data. Project specific tolerances may differ.
... -- ---------
Work Order # 9907079
Page _3_
-- --
-- ----
07/12/99 l7:ll:OO
State
Arkansas
California
Kansas
Louisiana
North Carolina
New Jersey
New York
Oklahoma
South Carolina
Utah
Wisconsin
--- ----
ST.II.TB C B R T I F I C A T I 0 II S
Agency
Department of Pollution Control and Ecology
California Environmental Laboratory Accreditation Program
Kansas Department of Health and Environment
Louisiana Department of Health and Hospitals
Department of Environment, Health and Natural Resources
New Jersey Department of Environmental Protection
New York State Department of Health
Oklahoma Water Resources Board
Dep~rtment of Health and Environmental Control
Utah Department of Health
Wisconsin Department of Natural Resources
- - --
Work Order U 9907079
Page _4_
Certification ID
2257
E-10165
LA 97-29
302
82005
10915 • 8720
82003001
RADC
99885260
--
-
07/12/99 17:11:00 ANALYTICAL PROTOCOL SUMMARY
FLAG DBPillITIONS
Flag Definition
< DL
NA
NC
ND
NR
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPD and/or \ Recovery not calculated. See Narrative for explanation.
Not detected. No instrument response for analyte or result less than zero.
Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit.
NS Analyte not spiked.
-
A Presence of hydrocarbon mix eluting in the Lube Oil range. The pattern does not match that of Lube Oil.
B Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero).
C Confirming data obtained using second GC column or GCMS.
D Presence of hydrocarbon mix eluting in the Diesel range. The pattern does not match that of Diesel.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
G Presence of hydrocarbon mix eluting in the Jet Fuel range. The pattern does not match that of Jet Fuel.
H Presence of analyte previously confirmed by historical data.
I Analyte identification suspect. See Narrative for explanation.
J Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
See Narrative for explanation. M
p
Result modified from previous Report.
Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
S Analyte concentration obtained using Method of Standard Additions (MSA) .
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
z See Narrative for explanation.
- -------- --
Work Order # 9907079
Page _s_
-----
-- --
07/12/99 17:11:0Q
Client HAMILTON BEACH
Facility WASHINGTON,NC
Client Code HAM BEACH NC
-
Method Volatile Organics SWB260B
Project Sample ID/Description
0799HBWW220 . 0799HBWW222
0799HBWW224
0799HBWW225
0799HBWW226
0799HBWW230
0799HBWW233
0799HBWWE01
0799HBWWE01
TRIP BLANK
---- ---
ANALYTICAL PROTOCOL SUMMARY
Extraction/Digestion
Lab Sample ID Test Code(s) Batch II
9907079-0lA 826SWACM NA
9907079-02A 826SWACM NA
9901079-03A 826SWACM NA
9907079-04A 826SWACM NA
9907079-0SA 826SWACM NA
9907079-0GA 826SWACM NA
9907079-078 826SWACM NA
9907079-0BA 826SWACM NA
9907079-0BB 826SWACM NA
9907079-09A 826SWACM NA
- ---
Work Order II 9907079
Page _6 _
Analysis Batch II
MSMSDB90707132401
MSMSDB90707132401
MSMSDB90707132401
MSMSDB?0707132401
MSMSDB90707132401
MSMSDB90707132401
MSMSDB90707132401
MSMSDB90707132401
MSMSDB90707132401
MSMSDB90707132401
--
-
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
F'ile ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-9hloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
-- --
RBSULTS SUMMARY
0799HBWW220 0799HBWW222
9907079-0lA 9907079-02A
80707919 80707920
07/01/99 13:45 07/01/99 12:40
00:00:00 00:00:00
07/07/99 21:06:00 07/07/99 21:33:00
1 1
Water Water
ug/L ug/L
received received
Cone. DL Cone. DL
ND 1.43 ND 1.43
ND 4.21 ND 4.21
ND 0.876 ND 0.876
ND 0.152 ND 0.152
ND 0.0759 ND 0.0759
ND 0.0372 ND 0.0372
ND 0.0766 ND 0.0766
ND 0.0867 ND 0.0867
ND 0.0884 ND 0.0884
ND 0.0908 ND 0.0908
ND 0.110 ND 0.110
ND 0.769 ND 0.769
ND 0.108 ND 0.108
ND 0. 0975 ND 0.0975
ND 0.110 ND 0.110
0.426 J 0.864 0.338 J 0.864
!ID 0.0962 ND 0.0962
ND 0.0802 ND 0.0802
ND 0.0718 ND 0.0718
ND 0.110 ND 0.110
- -----
0799HBWW224
9907079-03A
80707921
07/01/99 11:10
00:00:00
0"'//07/99 22:01:00
1
Water
ug/L
received
Cone. DL
ND 1.43
ND 4.21
ND 0.876
ND 0.152
ND 0.0759
ND 0.0372
ND 0.0766
ND 0.0867
ND 0.0884
ND 0.0908
ND O.llO
ND 0.769
ND 0.108
ND 0.0975
ND 0.110
2.22 0.864
ND 0.0962
ND 0.0802
ND 0.0718
ND 0.110
---
Work Order # 9907079
Page _7_
0799HBWW225
9907079-04A
80707922
07/01/99 11:15
00:00:00
07/07/99 22:28:00
1
Water
ug/L
' received
Cone. DL
ND 1.43
ND 4.21
ND 0.876
ND 0.152
ND 0.0759
ND 0.0372
ND 0.0766
ND 0.0867
ND 0.0884
ND 0.0908
ND 0.110
ND 0.769
ND 0.108
ND 0.0975
ND 0.110
ND .o. 864
ND 0.0962
ND 0.0802
ND 0. 0718
ND 0.110
- ----
-- - --
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4 -Chlorotol,_uene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
---- -----
R B S U L T S S UM MA R Y (Cont'd)
0799H8WW220
9907079-0lA
80707919
07/01/99 13:45
00:00:00
07/07/99 21:06:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
.ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
0.0424
0.107
0.114
0.125
Q.0845
0.0586
0.907
0.0530
0.104
0.0434
0.845
0.0664
0.0549
0 .104
0.0978
0.0736
0.0349
0.102
0.0595
0.138
0799H8WW222
9907079-02A
80707920
07/01/99 12:40
00:00:00
07/07/99 21:33:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Nb
ND
ND
ND
ND
ND
ND
ND
DL
0.0424
0.107
0.114
0.125
0.0845
0.0586
0.907
0.0530
0.104
0.0434
0.845
0.0664
0.0549
0.104
0.0978
0.0736
0.0349
0.102
0.0595
0.138
0799H8WW224
9907079-03A
80707921
07/01/99 11:10
00:00:00
07/07/99 22:01:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
·ND
DL
0.0424
0.107
0.114
0.125
0.0845
0.0586
0.907
0.0530
0.104
0.0434
0.845
0.0664
0.0549
0 .104
0.0978
0.0736
0.0349
0.102
0.0595
0.138
- --
Work Order # 9907079
Page _8_
0799H8WW225
9907079-04A
80707922
07/01/99 11:15
00:00:00
07/07/99 2f :28:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
0. 0424
0.107
0.114
0.125
0.0845
·0.0586
0.907
0.0530
0 .104
0.0434
0.845
0.0664
0.0549
0 .104
0.0978
Cl". 0736
0.0349
0.102
0.0595
0.138
--
-
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1, 3-D,ichloropropene
Ethyl rnethacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Iodornethane
Isopropylbenzene
p-Isopropyltoluene
Methyl rnethacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MI8K)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
----
R B S 0 L T S S 0 MM A R Y (Cont'd)
0799H8WW220
9907079-0lA
80707919
07/01/99 13:45
00:00:00
07/07/99 21:06:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0677
0.0544
0.101
0.0823
0.0584
0.0757
0.0587
0.102
0.251
0.180
0.0656
0.0750
0.116
0.156
0.0334
0.123
0.0776
0.148
1.18
0.0929
- --
0799H8WW222
9907079-02A
80707920
07/01/99 12:40
00:00:00
07/07/99 21:33:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
--
DL
0. 0677
0.0544
0.101
0.0823
0.0584
0.0757
0.0587
0.102
0.251
0.180
0.0656
0.0750
0.116
0.156
0.0334
0.123
0.0776
0.148
1.18
0.0929
-
0799H8WW224
9907079-03A
80707921
07/01/99 11:10
00:00:00
07/07/99 22:01:00
1
Water
ug/L
received
Cone.
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-
DL
0.0677
0.0544
0.101
0.0823
0.0584
0.0757
0.0587
0.102
0.251
0.180
0.0656
0.0750
0.116
0.156
0.0334
0.123
0.0776
0.148
1.18
0.0929
-
Work Order # 9907079
Page _9_
0799H8WW225
9907079-04A
80707922
07/01/99 11:15
00:00:00
07/07/99 42:28:00
1
-
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-
DL
0.0677
0.0544
0.101
0.0823
0.0584
0.0757
0.0587
0.102
0.251
0.180
0.0656
0.0750
0.116
0.156
0.0334
0.123
0.0776
0.148
1.18
0.0929
---
-- - -- ---- - ---------
07/12/99 17:11:00 RBSULTS
0
SUMMARY (Cont'd) Work Order # 9907079
Page lQ_
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID: 0799HBWW220 0799H8WW222 0799HBWW224 0799H8WW225
Lab ID: 9907079-0lA 9907079-02A 9907079-03A 9907079-04A
File ID: 80707919 80707920 80707921 80707922
Date Collected: 07/01/99 13 :45 07/01/99 12:40 07/01/99 11 :10 07/01/99 11:15
Date Prepared: 00:00:00 00:00:00 00:00:00 00:00:00
Date Analyzed: 07/07/99 21:06:00 07/07/99 21:33:00 07/07/99 22:01:00 07/07/99 2,2:28:00
Dilution Factor: 1 1 1 1
Matrix: Water Water Water Water
Units: ug/L ug/L ug/L ug/L
Report as: received received received ' received
Column:
Analyte Cone. DL Cone. DL Cone. DL Cone. DL
Styrene ND 0.0650 ND 0.0650 ND 0.0650 ND 0.0650
1,1,1,2-Tetrachloroethane ND 0.0920 ND 0.0920 ND 0.0920 ND 0. 0920
1,1,2,2-Tetrachloroethane ND 0.117 ND 0.117 ND 0.117 ND 0.117
Tetrachloroethene ND 0.114 ND 0.114 ND 0.114 ND 0.114
Tetrahydrofuran ND 1.26 ND 1.26 ND 1.26 ND 1.26
Toluene ND 0.0766 ND 0.0766 ND 0.0766 ND 0.0766
1,2,3-Trichlorobenzene ND 0.211 ND 0.211 ND 0.211 ND 0.211
1,2,4-Trichlorobenzene ND 0.158 ND 0.158 ND 0.158 ND 0.158
1,1,1-Trichloroethane ND 0.0731 ND 0.0731 ND 0.0731 ND 0.0731
1,1,2-Trichloroethane ND 0.0392 ND 0.0392 ND 0.0392 ND 0.0392
Trichloroethene ND 0.0929 ND 0. 0929 ND 0.0929 ND 0.0929
Trichlorof luoromethane ND 0.0886 ND 0.0886 ND 0.0886 ND 0.0886
1,2,3-Trichloropropane ND 0.0856 ND 0.0856 ND 0.0856 ND 0.0856
1,1,2-Trichlorotrifluoroethane ND 0.112 ND 0.112 ND 0.112 ND 0.112
1,2,4-Trimethylbenzene ND 0.0798 ND 0.0798 ND 0.0798 ND 0.0798
1,3,5-Trimethylbenzene ND 0.0910 ND 0. 0910 ND 0.0910 ND 0.0910
Vinyl acetate ND 0.323 ND 0.323 ND 0.323 ND 0.323
Vinyl chloride ND 0.0889 ND 0.0889 ND 0.0889 ND 0.0889
m&p-Xylene ND 0.164 ND 0.164 ND 0.164 ND 0.164
a-Xylene ND 0.0807 ND 0.0807 ND 0.0807 ND 0.0807
-- ---
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
--
0799HBWW226
9907079-05A
80707923
07/01/99 10:30
00:00:00
07/07/99 22:55:00
l
Water
ug/L
received
Cone.
ND
ND
ND
ND
No
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
1.43
4.21
0.876
0.152
0.0759
0.0372
0.0766
0.0867
0.0884
O.P908
0.110
0.769
0.108
0.0975
0.110
0.864
0.0962
0.0802
0.0718
0. llO
-- - ----
R B S U L T S S UM MA R Y (Cont'd)
0799HBWW230
9907079-06A
80707924
07/01/99 13:30
00:00:00
07/07/99 23:23:00
l
Water
ug/L
received
Cone.
ND
ND
ND
ND.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
l.43
4.21
0.876
0.152
0.0759
o. 0372
0.0766
0.0867
0.0884
0.0908
0.110
o·. 769
0.108
0.0975
0.110
0.864
0.0962
0.0802
0.0718
0.110
0799HBWW233
9907079--078
80707925
07/01/99 12:25
00:00:00
07/07/99 23:50:00
l
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
1.43
4.21
0.876
0.152
0.0759
0.0372
0.0766
0.0867
0.0884
0.0908
O.llO
0.769
0.108
0.0975
0.110
0.864
0.0962
0,0802
0.0718
0. llO
- --
Work Order tt 9907079
Page lL
0799HBWWE01
9907079-08A
80707926
07/01/99 10:45
00:00:00
07/08/99 00:18:00
1
Water
ug/L
received
Cone.
ND
ND
ND
ND
ND
ND
ND
0.509
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DL
l.43
4.21
0.876
0.152
0.0759
0.0372
0.0766
0.0867
0.0884
0.0908
0.110
0.769
0.108
0. 0975
6.110
0.864
0. 0962
0.0802
0.0718
O. llO
--
-
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
----
R B S U LT S S U MM A R Y (Cont'd)
0799H8WW226 0799H8WW230 0799HBWW233
9907079-05A 9907079-06A 9907079-078
80707923 80707924 80707925
07/01/99 10:30 07/01/99 13:30 07/01/99 12:25
00:00:00 00:00:00 00:00:00
07/07/99 22:55:00 07/07/99 23:23:00 07/07/99 23:50:00
1 1 1
Water Water-Water
ug/L ug/L ug/L
received received received
Cone. DL Cone. DL Cone. DL
ND 0.0424 ND 0.0424 ND 0.0424
ND 0.107 ND 0.107 ND 0.107
ND 0.114 ND 0.114 ND 0.114
ND 0.125 ND 0.125 ND 0.125
ND 0.0845 ND 0.0845 ND 0.0845
ND 0.0586 ND 0. 0586 .. ND 0.0586
ND 0.907 ND 0.907 ND 0.907
ND 0.0530 ND 0.0530 ND 0.0530
ND 0.104 ND 0.104 ND 0.104
ND 0.0434 ND 0. 0434 ND 0. 0434
ND 0.845 ND 0.845 ND 0.845
ND 0.0664 ND 0.0664 ND 0.0664
ND 0.0549 ND 0. 0549 ND 0.0549
ND 0.104 ND 0.104 ND 0.104
ND 0.0978 ND 0.0978 ND 0.0978
ND 0.0736 ND 0.0736 ND 0.0736,
ND 0.0349 ND 0.0349 ND 0.0349
ND 0.102 ND 0.102 ND 0.102
ND 0.0595 ND 0.0595 ND 0.0595
ND 0.138 ND 0.138 .ND 0.138
--- ------
Work Order # 9907079
Page 1:]_
0799H8WWE01
9907079-08A
80707926
07/01/99 10:45
00:00:00
07/08/99 (!0:18:00
1
Water
ug/L
' received
Cone. DL
0 .450 0.0424
ND 0.107
ND 0.114
ND 0,.125
ND 0.0845
ND 0.0586
ND 0.907
ND 0.0530
ND 0 .104
ND 0. 0434
ND o. 845
ND 0.0664
ND 0. 054°9
ND 0.104
ND 0.0978
ND 0.0736
ND 0. 0349
ND 0.102
ND 0.0595
ND 0.138
-- ---
-- ---
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
l,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
.l,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-D~chloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MI8K)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene·
--- ---·---
R B S U L T S S UM MAR Y (Coot•d)
0799H8WW226 0799H8WW230 0799H8WW233
9907079-05A 9907079-06A 9907079-078
80707923 80707924 80707925
07/01/99 10:30 07/01/99 13 :30 07/01/99 12:25
00:00:00 00:00:00 00:00:00
07/07/99 22:55:00 07/07/99 23:23:00 07/07/99 23:50:00
l 1 l
Water Water Water
ug/L ug/L ug/L
received received received
Cone. DL Cone. DL Cone. DL
ND 0. 0677 ND 0.0677 ND 0.0677
ND 0.0544 ND 0.0544 ND 0.0544
ND 0.101 ND 0.101 ND 0.101
ND 0.0823 ND 0.0823 ND 0.0823
ND 0.0584 ND 0.0584 ND 0.0584
ND O.Q757 ND 0.0757 ND 0.0757
ND 0.0587 ND 0.0587 ND 0.0587
ND 0.102 ND 0.102 ND 0.102
ND 0.251 ND 0.251 ND 0.251
ND 0.180 ND 0.180 ND 0.180
ND 0.0656 ND 0.0656 ND 0.0656
ND 0.0750 ND 0.0750 ND 0.0750
ND 0.116 ND 0.116 ND 0 .116
ND 0.156 ND 0.156 ND 0.156
ND 0.0334 ND 0.0334 ND 0.0334
ND 0.123 ND 0.123 ND 0.123
ND 0.0776 ND 0. 0776 ND 0.0776
ND 0.148 ND 0 .148 ND 0.148
ND 1.18 ND 1.18 ND 1.18
ND 0. 0929 ND 0.0929 ND 0. 0929
---
Work Order tt 9907079
Page ll_
0799H8WWE01
9907079-08A
8070?.926
07/01/99 10 :45
00:00:00
07/08/99 00:18:00
l
Water
ug/L
• received
Cone. DL
ND 0.0677
ND 0.0544
ND 0.101
ND 0.0823
ND 0.0584
ND 0.0757
ND 0.0587
ND 0.102
ND 0.251
ND 0.180
ND 0.0656
ND 0.0750
ND 0.116
ND 0.156
ND 0.0334
ND 0.123
396 ER 0.0776
ND 0.148
ND 1.18
ND 0.0929
--
-
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrof uran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
· Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
--- -
R B S UL T S S UM MAR Y (Cont'd)
0799H8WW226 0799H8WW230 0799H8WW233
9907079-05A 9907079-06A 9907079-078
80707923 80707924 80707925
07/01/99 10:30 07/01/99 13:30 07/01/99 12:25
00:00:00 00:00:00 00:00:00
07/07/99 22:55:00 07/07/99 23:23:00 07/07/99 23:50:00
l l 1
Water Water Water
ug/L ug/L ug/L
received received received
Cone. DL Cone. DL Cone. DL
ND 0.0650 ND 0.0650 ND 0,0650
ND 0. 0920 ND 0.0920 ND 0.0920
ND 0.117 ND 0.117 ND 0.117
ND 0.114 ND 0.114 ND 0.114
ND l.26 ND l. 26 ND l.26
ND 0.0766 0.286 0.0766 ND 0.0766
ND 0.211 ND 0.211 ND 0.211
ND 0.158 ND 0.158 ND 0.158
ND 0.0731 ND 0. 0731 ND 0. 0731
ND 0.0392 ND 0.0392 ND 0.0392
ND 0.0929 ND 0.0929 ND 0. 0929
ND 0,0886 ND 0.0886 ND 0.0886
ND 0.0856 ND 0.0856 ND 0.0856
ND 0.112 ND 0.112 ND 0.112
ND 0.0798 ND 0. 0798 ND 0.0798
ND 0.0910 ND 0.0910 ND 0. 0910
ND 0.323 ND 0.323 ND 0.323
ND 0.0889 ND 0.0889 ND 0.0889
ND 0.164 ND 0.164 ND 0.164
ND 0.0807 ND 0.0807 ND 0.0807
---------
Work Order # 9907079
Page .!§_
0799H8WWE01
9907079-08A
80707926
07/01/99 10:45
00:00:00
07/08/99 00:18:00
1
Water
ug/L . received
Cone. DL
ND 0.0650
ND 0. 0920
ND 0.117
ND 0 .114
ND 1.26
ND 0.0766
ND 0.211
ND 0.158
ND 0. 0731
ND 0.0392
ND 0.0929
ND 0.0886
ND 0.0856
ND 0.112
ND 0.0798
ND 0. 0910
ND 0.323
ND 0.0889
ND 0.164
ND 0.0807
-----
--- --
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix: .
Units:
Report as:
Column:
Analyte
Surrogate(s)
l,4-8rornofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
--
0799H8WW226
9907079-05A
80707923
07/01/99 10:30
00:00:00
07/07/99 22:55:00
1
Water
ug/L
received
Cone. DL
Recovery
\
101
100
97
-------
RB SULT S SUMMARY (Cont'd)
0799H8WW230 0799H8WW233
9907079-06A 9907079-078
80707924 80707925
07/01/99 13:30 07/01/99 12:25
00:00:00 00:00:00
07/07/99°23:23:00 07/07/99 23:50:00
1 1
Water Water
ug/L ug/L
received received
Cone. DL Cone. DL
Recovery Recovery
\ \
99 101
104 103
96 97
- --
Work Order # 9907079
Page !.§__
0799H8WWE01
9907079-08A
80707926
07/01/99 10:45
00:00:00
07/08/99 00~:18:00
1
Water
ug/L
' received
Cone. DL
Recovery
\
101
104
97
--
-
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
----
It B SULT S SUMMA It Y (Cont'd)
0799HBWWE01 TRIP BLANK
9907079-08B 9907079-09A
B0707930 B0707918
07/01/99 10 :45 07/01/99
00:00:00 00:00:00
07/08/99 13:46:00 07/07/99 20:39:00
10 1
Water Water
ug/L ug/L
received received
Cone. DL Cone. DL Cone.
ND 14.3 ND 1.43
ND 42.1 ND 4.21
ND 8.76 ND 0.876
ND 1.52 ND 0.152
ND 0.759 ND 0.0759
ND 0.372 ND 0. 0372
ND 0.766 ND 0.0766
ND 0.867 ND 0.0867
ND 0.884 ND 0.0884
ND 0.908 ND 0.0908
ND 1.10 ND 0.110
ND 7.69 ND 0.769
ND 1.08 ND 0.108
ND 0.975 ND 0.0975
ND 1.10 ND 0.110
ND 8.64 ND 0.864
ND 0.962 ND 0.0962
ND 0.802 ND 0.0802
ND 0. 718 ND 0.0718
ND 1.10 ND 0.110
---- ---
DL
--
Work Order tt 9907079
Page u_
'
Cone. DL
---- -
- ----
07/12/99 17:11:00
Method Volatile Organics SW82608
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
l,2-Dibromoethane
Dibromomethane
trans-l,4-Dichloro-2-butene
l,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
l,l-Dichloroethane
l,2-Dichloroethane
1,1-Dichloroethene
cis-l,2-Dichloroethene
trans-l,2-Dichloroethene
--
0799HBWWE01
9907079-088
80707930
07/0l/99 10:45
00:00:00
07/08/99 13:46:00
10
Water
ug/L
received
Cone. DL
ND 0.424
ND l.07
ND 1.14
ND 1.25
ND 0. 845
ND 0.586
ND 9.07
ND 0.530
ND l.04
ND 0.434
ND 8.45
ND 0.664
ND 0.549
ND l.04
ND 0.978
ND 0.736
ND 0.349
ND 1. 02
ND 0.595
ND 1.38
------- - -- --
RESULTS S UM MA RY (Cont'd) Work Order # 9907079
· Page .l!L
TRIP BLANK
9907079-09A
80707918
07/0l/99
00:00:00
07/07/99 20:39:00
l
Water
ug/L
received '
Cone. DL Cone. DL Cone. DL
ND 0.0424
ND 0.107
ND 0.114
ND 0.125
ND 0. 0845
ND 0.0586
ND 0.907
ND 0.0530
ND 0.104
ND 0. 0434
ND 0.845
ND 0.0664
ND 0.0549
ND 0.104
ND 0.0978
ND 0.0736
ND 0.0349
ND 0.102
ND 0.0595
ND 0.138
-
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared·:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
l,l-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
----
R B S ULT S S UM MA lt Y (Cont'd)
0799HBWWEOl TRIP BLANK
9907079-088 9907079-09A
80707930 80707918
07/01/99 10:45 07/01/99
00:00:00 00:00:00
07/08/99 13:46:00 07/07/99 20:39:00
10 l
Wat; er Water
ug/L ug/L
received received
Cone. Df,i Cone. DL Cone.
ND 0.677 ND 0.0677
ND 0.544 ND 0.0544
ND l. 01 ND 0.101
ND 0.823 ND 0.0823
ND 0.584 ND 0.0584
ND 0.757 ND 0.0757
ND 0.587 ND 0.0587
ND 1.02 ND 0.102
ND 2.51 ND 0.251
ND l.80 ND 0.180
ND 0.656 ND 0.0656
ND 0.750 ND 0.0750
ND 1.16 ND 0.116
ND 1.56 ND 0.156
ND 0.334 ND 0.0334
ND 1.23 ND 0.123
523 0.776 0.182 0.0776
ND l.48 ND 0.148
ND 11.8 ND 1.18
ND 0.929 ND 0.0929
-------
DL
--
Work Order # 9907079
Page 12_
Cone. DL
--- --
- ----
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Dat:e Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
- - - -- --
RESULTS SUMMARY (Cont'd)
0799HBWWE01 TRIP BLANK
9907079-088 9907079-09A
80707930 80707918
07/01/99 10:45 07/01/99
00:00:00 00:00:00
07/08/99 13:46:00 07/07/99 20:39:00
10 1
Water Water
ug/L ug/L
received received
Cone. DL Cone. DL Cone.
ND 0.650 ND 0.0650
ND 0.920 ND 0. 0920
ND 1.17 ND 0.111
ND 1.14 ND 0.114
ND 12.6 ND 1.26
ND 0.766 ND 0.0766
ND 2.11 ND 0.211
ND 1.58 ND 0.158
ND 0.731 ND 0.0731
ND 0 .392 ND 0.0392
ND 0.929 ND 0.0929
ND 0.886 ND 0.0886
ND 0.856 ND 0.0856
ND 1.12 ND 0.112
ND 0.798 ND 0.0798
ND 0.910 ND 0.0910
ND 3.23 ND 0.323
ND 0.889 ND 0.0889
ND 1.64 ND 0.164
ND 0.807 ND 0.0807
- -
DL
- - -
Work Order # 9907079
Page ,;ut_
Cone. DL
--
-
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix: .
Units:
Report as:
Column:
Analyte
Surrogate{s)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-de
- - --
0799HBWWE01
9907079-088
80707930
07/01/99 10:45
00:00:00
07/08/99 13:46:00
10
Water
ug/L
received
Cone. DL
Recovery
'
98
100
96
--
R B S U L TS S UM MA R Y (Cont'd)
TRIP BLANK
9907079-09A
80707918
07/01/99
00:00:00
07/07/99 20:39:00
1
Water
ug/L
received
Cone. DL Cone.
Recovery Recovery
\ \
102
99
98
------
DL
-
Work Order tt 9907079
Page £L
•
Cone. DL
Recovery
\
-----
- -----
07/12/99 17:11:00
Project Sample ID ~0~7~9~9~H~B~WW"""2~3~0'--~~~~~~­
Lab Sample ID 9907079-06A
File 11 B0707924
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Acetone ,
Acetonitrile
Acrolein
Acrylonitrile
Benzene ,
1-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
CAS II
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
107-04-0
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
5_6-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
-- --------- --
RBSOLTS Work Order II 9907079
Extraction Batch II Page ~
Analysis Batch II MSMSDB90707132401
Date Collected 01Lo1L99 13:30 Instrument ~ Reporting Subset Matrix !i
Date Received 01t_o2t_99 Column Spikes S~bset ~-Report As received
Date Prepared 00:00:00 Analyst !':lliR Specs Subset ~-\ Moisture
Date Analyzed 07 t.01 l99 23:23:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
.. Measured Concentration Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 1.43 0
ND. 4.21 0
ND 0.876 0
ND 0.152 0
ND 0. 0759 0
ND 0.0372 0
ND 0.0766 0
ND 0.0867 0
ND 0.0884 0
ND 0.0908 0
ND 0.110 0
ND 0.769 0
ND 0.108 0
ND 0.0975 0
ND 0.110 0
ND 0.864 0
ND 0.0962 0
ND 0.0802 0
ND 0.0718 0
ND 0 .110 0
ND 0. 0424 0
ND 0.107 0
ND 0.114 0
ND 0.125 0
ND 0.0845 0
------
07/12/99 17:11:00
Project Sample ID ~0~7~9~9~H=B~W~W=2~3=0~~~~~~~­
Lab Sample ID 9907079-06A
File U 80707924
Method Volatile Organics SW8260B
Test Code 826SWACM
-
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t.-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethyl~enzene
CAS II
74-88-4
98-82-8
99-87-6
80-62-6
1634-04-4
108-10-1
75-09-2
91-20-3
107-12-0
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
109-99-9
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
76-13-1
95-63-6
--- ---- -- - ---
R B S U L T S (Cont'd) Work Order U 9907079
Extraction Batch U Page §.Q_
Analysis Batch # MSMSDB90707132401
Date Collected o7L01L99 13:30 Instrument !:!2Q!L Reporting Subset ~-Matrix !i
Date Received 01Lo2L99 Column Spikes Subset ~-Report As received
Date Prepared 00:00:00 Analyst ~ Specs Subset % Moisture
Date Analyzed o7L07L99 23:23:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1 ~
Measured Concentration Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.0656 0
ND 0.0750 0
ND 0 .116 0
ND 0.156 0
ND 0.0334 0
ND 0.123 0
ND 0.0776 0
ND· 0.148 0
ND 1.18 0
ND 0.0929 0
ND 0.0650 0
ND 0.0920 0
ND 0.117 0
ND 0.114 0
ND 1.26 0
0.286 0.0766 0
ND 0 .211 0
ND 0.158 0
ND 0.0731 0
ND 0.0392 0
ND 0. 0929 0
ND 0.0886 0
ND 0.0856 0
ND 0.112 0
ND 0.0798 0
-
07/12/99 17:11:00 R B S U L T S (Clont'd) Work Order # 9907079
Extraction Batch # Page &l_
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~0'--------­
Lab Sample ID 9907079-0GA
File # B0707924
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
l,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylent;
Surrogate(s)
1,4-Bromofluorobenzene
CAS #
108-67-8
108-05-4
75-01-4
NO_CAS
95-47-6
CAS #
460-00-4
Date
Date
Date
Date
l,2-Dichloroethane-d4 17060-07-0
Toluene-dB 2037-26-5
- - -- -
Analysis Batch # MSMSDB9070713240l
Collected 01Lo1L99 13:30 Instrument ~
Received 01Lo2L99 Column
Prepared 00:00:00 Analyst !!lfili
Analyzed 01Lo1L99 23:23:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Concentration
ug/L
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
16.7 16.5
16.7 17.3
16.7 16.0
-- - --
Reporting Subset __ Matrix !i
Sp~kes Subset __ Report As received
Specs Subset __ % Moisture
.
Detection Limit Reporting Limit
ug/L ug/L
0.0910 0
0.323 0
0.0889 0
0.164 0
0.0807 0
Specification Limits
Recovery Low High
\ % \
99 77 117
104 61 143
96 87 113
- -- - ---
-- - --- - - - - -·-
07/12/99 17:11:00 RBS ULT S
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~3'--~~~~~~­
Lab Sample ID 9907079-07B
File jj B0707925
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene.
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
CAS jj
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
107-04-0
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
Extraction Batch jj
Analysis Batch jj MSMSDB90707132401
Date Collected 07£'.01£'.99 12:25 Instrument !:1fil2L
Date Received 07£'.02£'.99 Column
Date Prepared 00:00:00 Analyst ~
Date Analyzed 07£'.07£'.99 23:50:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Concentration
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
ND
ND
ND
ND
ND
ND
ND
ND
- -- - -
Work Order jj 9907079
Page§£_
Reporting Subset ~-Matrix !i
Spikes Subset ~-Report As received
Specs Subset ~-% Moisture
• ...
~· Detection Limit Reporting Limit
ug/L ug/L
1.43 0
4.21 0
0.876 0
0.152 0
0.0759 0
0.0372 0
0.0766 0
0.0867 0
0.0884 0
0.0908 0
0.110 0
0.769 0
0.108 0
0.0975 0
0.110 0
0.864 0
0.0962 0
0.0802 0
0.0718 0
0.110 0
0.0424 0
0.107 0
O.lH 0
0.125 0
0.0845 0
--
--· ----------
07/12/99 17:11:00 RH S 0 LT S (Cont'd)
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~3'--------­
Lab Sample ID 9907079-078
File # 80707925
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Iodomethane
lsopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
CAS #
74-88-4
98-82-8
99-87-6
80-62-6
-
Methyl t,-butyl ether 1634-04-4
4-Methyl-2-pentanone(MIBKJ 108-10-1
Methylene chloride 75-09-2
Naphthalene 91-20-3
Propanenitrile 107-12-0
n-Propylbenzene 103-65-1
Styrene 100-42-5
l,l,l,2-Tetrachloroethane 630-20-6
l,l,2,2-Tetrachloroethane 79-34-5
Tetrachloroethene 127-18-4
Tetrahydrof uran 109-99-9
Toluene 108-88-3
1,2,3-Trichlorobenzene 87-61-6
1,2,4-Trichlorobenzene 120-82-1
l,l,l-Trichloroethane 71-55-6
l,l,2-Trichloroethane 79-00-5
Trichloroethene 79-01-6
Trichlorof luoromethane 75-69-4
1,2,3-Trichloropropane 96-18-4
l,l,2-Trichlorotrifluoroethane 76-13-1
1,2,4-Trimethylbenzene 95-63-6
Extraction Batch #
Analysis Batch # MSMSDB90707132401
Date Collected 07/_0l/_99 12:25 Instrument ~
Date Received 07/_02/_99 Column
Date Prepared 00:00:00 Analyst ~
Date Analyzed 07{.07/_99 23:50:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Concentration
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
----
Work Order # 9907079
Page §.i_
Reporting Subset __ Matrix .!:!
-
Spikes Subset __ Report As received
Specs Subset __ \ Moisture
'
Detection Limit Reporting Limit
ug/L ;ig/L
0.0656 0
0.0750 0
0.116 0
0.156 0
0.0334 0
0.123 0
0.0776 0
0.148 0
1.18 0
0.0929 0
0.0650 0
0.0920 0
0.117 0
0.114 0
1.26 0
0.0766 0
0.211 0
0.158 0
0. 0731 0
0.0392 0
0.0929 0
0.0886 0
0.0856 0
0.112 0
0.0798 0
--
-
07/12/99 17:11:00 R K S 0 LT S (Cont'd) Work Order # 9907079
Extraction Batch # Page §2_
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~3~~~~~~~­
Lab Sample ID 9907079-07B
Date
Date
Pile # 80707925
Method Volatile Organics SW8260B
Test Code 826SWACM
-
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylen~
Surrogate(s)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Date
Date
CAS #
108-67-8
108-05-4
75-01-4
NO_cAs
95-47-6
CAS #
460-00-4
17060-07-0
2037-26-5
Analysis Batch # MSMSDB90707132401
Collected 07[01[99 12:25 Instrument ~
Received 07[02[99 Column
Prepared 00:00:00 Analyst !':!fili
Analyzed 07[07[99 23:50:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Concentration
ug/L
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
16.7 16.9
16.7 17.3
16.7 16.2
----·----·---
Reporting Subset ~-Matrix li
Spikes Subset ~-Report As received
Specs Subset \" Moisture
'.
Detection Limit Reporting Limit
ug/L ug/L
0.0910 0
0.323 0
0.0889 0
0 .164 0
0.0807 0
Specification Limits
Recovery Low High
\" t \"
101 77 117
103 61 143
97 87 113
---- ---
------
07/12/99 17:11:00
Project Sample ID ~0~7~9~9~H~B~W~W~E~O~l:.,._ ______ _
Lab Sample ID 9907079-08A
File tt B0707926
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3 ·-Ch loropropene
2-Chlorotoluene
CAS tt
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
107-04-0
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
- -- -----.. ----
RESULTS Work Order tt 9907079
Extraction Batch tt Page §..§.__
Analysis Batch tt MSMSDB90707132401
Date Collected 07l0ll99 10:45 Instrument ~ Reporting Subset __ Matrix !:!
Date Received 01Lo2L99 Column Spikes Subset __ Report As received
Date· Prepared 00:00:00 Analyst MER Specs Subset __ % Moisture
Date Analyzed 01Lo8l99 00:18:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1 . --
Measured Concentration Detection Limit Reporting Limit •• J
ug/L ug/L ug/L
ND 1.43 0
ND 4.21 0
ND 0.876 0
ND 0.152 0
ND 0.0759 0
ND 0. 0372 0
ND 0.0766 0
0.509 0.0867 0
ND 0.0884 0
ND 0.0908 0
ND 0.110 0
ND 0.769 0
ND 0.108 0
ND 0.0975 0
ND 0.110 0
ND 0.864 0
ND 0.0962 0
ND 0.0802 0
ND 0. 0718 0
ND 0.110 0
0 .450 0. 0424 0
ND 0.107 0
ND 0.114 0
ND 0.125 0
ND 0.0845 0
-
07/12/99 17:11:00 KB SOLT S (Cont'd)
Extraction Batch H
Project Sample ID ~0~7~9~9~H~B~W~W~E~O~l'--~~~~~~­
Lab Sample ID 9907079-0SA
Date
Date
File H 80707926
Method Volatile Organics SW82608
Test Code 826SWACM
Analyte
4-Chlorotoluene
l,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromo"!ethane
trans-l,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
l,l-Dichloroethane
1,2-Dichloroethane
l,l-Dichloroethene
cis-l,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
l,l-Dichloropropene
cis-1,3-Dichloropropene
trans-l,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Date
Date
CAS H
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
110-57-6
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
97-63-2
100-41-4
87-68-3
591-78-6
Analysis Batch H MSMSDB9070713240l
Collected 07£'.01£'.99 10 :45 Instrument ~
Received 07l02l99 Column
Prepared 00:00:00 Analyst !:!fili
Analyzed 01l08l99 00:18:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mLl
Dilution Factor l
Measured Concentration
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ---·
Work Order H 9907079
Page §2._
Reporting Subset ~-Matrix ~
Spikes Subset ~-Report As received
Specs Subset ~-\ Moisture
Detection Limit Reporting Limit
ug/L ug/L
0.0586 0
0.907 0
0.0530 0
0.104 0
0.0434 0
0.845 0
0.0664 0
0.0549 0
0.104 0
0.0978 0
0 .0736 0
0.0349 0
0.102 0
0.0595 0
0.138 0
0. 0677 0
0.0544 0
0.101 0
0.0823 0
0.0584 0
0.0757 0
0.0587 0
0 .1,02 0
0.251 0
0.180 0 --
-- --- -
07/12/99 17:11:00
Project Sample ID ~0~7~9~9~H~B~WW:.:..:.=E~O~l'--~~~~~~­
Lab Sample ID 9907079-08A
File ft B0707926
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t.-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroet~ane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane.
1,2,4-Trimethylbenzene
CAS #
74-88-4
98-82-8
99-87-6
80-62-6
1634-04-4
108-10-1
75-09-2
91-20-3
107-12-0
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
109-99-9
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
76-13-1
95-63-6
- --- ------ - -
R B S U L T S (Cont'd) Work Order # 9907079
Extraction Batch # Page .§.§._
Analysis Batch # MSMSDB90707132401
Date Collected 01Lo1L99 10:45 Instrument !::!fil2L Reporting Subset Matrix .!'.!
Date Received 01Lo2L99 Column Spikes Subset ~-Report As received
Date Prepared 00:00:00 Analyst !1fS Specs Subset ~·-\ Moisture
Date Analyzed 01(_08L99 00:18:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
.. Measured Concentration Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.0656 0
ND 0.0750 0
ND 0.116 0
ND 0.156 0
ND 0.0334 0
ND 0.123 0
396 ER 0.0776 0
ND 0 .148 0
ND 1.18 0
ND 0.0929 0
'i! ND 0.0650 0
ND 0.0920 0
ND 0.117 0
ND 0.114 0
ND 1.26 0
ND 0.0766 0
ND 0.211 0
ND 0.158 0
NJ? 0.0731 0
ND 0.0392 0
ND 0.0929 0
ND 0.0886 0
ND 0.0856 0
ND 0. J:l2 0
ND 0.0798 0
-
07/12/99 17:11:00 R B S U L T S (Cont'd) Work Order tt 9907079
Extraction Batch # Page .2..2_
Project Sample ID ~0~7~9~9~H~B~W~W~E~O~l'--~~~~~~­
Lab Sample ID 9907079-08A
Date
Date
File # B0707926
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
Date
Date
CAS tt
106-67-8
108-05-4
75-01-4
NO_CAS
95-47-6
CAS #
460-00-4
17060-07-0
2037-26-5
Analysis Batch tt MSMSDB90707132401
Collected 071'.0ll'.99 10:45 Instrument !!1§.lliL
Received 071'.021'.99 Column
Prepared 00:00:00 Analyst MER
Analyzed 07L08L99 00:18:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Concentration
ug/L
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
16.7 16.9
16.7 17.3
16.7 16.2
-----\--- ---
Reporting Subset ~-Matrix Ji
Spikes Subset ~-Report As received
Specs Subset ~-\ Moisture
Detection Limit Reporting Limit
ug/L ug/L
0.0910 0
0.323 0
0.0889 0
0.164 0
0.0807 0
Specification Limits
Recovery Low High
\ \ \
101 77 117
104 61 143
97 87 113
- -- ----
---· -- -------
07/12/99 17:11:00 RBS ULT S
Project Sample ID ~0~7~9~9~H~B~W~W~E"'-"'O:l~~~~~~~~
Lab Sample ID 9907079-088
File # B0707930
Method Volatile Organics SW8260B
Test Code 826SWACM
-
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide.
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene'
CAS #
67-64-1
75-05-8
107-02-8
107-13-1
71-43-2
107-04-0
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
75-15-0
56-23-5
126-99-8
108-90-7
75-00-3
67-66-3
544-10-5
74-87-3
107-05-1
95-49-8
Extraction Batch #
Analysis Batch # MSMSDB90707132401
Date Collected 07 /'.0l/'.99 10:45 Instrument !§illL
Date Received 07 /'.02/'.99 Column
Date Prepared 00:00:00 Analyst !1!IB
Date Analyzed 07 /'.08/'.99 13:46:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 10
Measured Concentration
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
. ND
ND
ND
ND
ND
ND
- - --·
Work Order # 9907079
Page 1JJ_
Reporting Subset ~-Matrix !:!
-
Spikes Subset ~-Report As received
Specs Subset \ Moisture
• --.
Detection Limit Reporting Limit ,. ___
ug/L ug/L
14. 3 0
42.1 0
8.76 0
1. 52 0
0.759 0
0.372 0
0.766 0
0.867 0
0.884 0
0.908 0
l. lb 0
7.69 0
1. 08 0
0.975 0
1.10 0
8.64 0
0.962 0
0.802 0
0. 718 0
1.10 0
0 .424 0
1. 07 0
1.14 0
1.25 -0
0.845 0
--
--- ---
07/12/99 17:11:00
Project Sample ID ~0~7~9-9~H~B~W~W~E_o_1.._ ______ ~
Lab Sample ID 9907079-08B
File II B0707930
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
. Propanenitrile
n-Propylbenzene
Styrene
1, 1,.1, 2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
.1, 2, 3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
CAS 11
74-88-4
98-82-8
99-87-6
80-62-6
1634-04-4
108-10-1
75-09-2
91-20-3
107-12-0
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
109-99-9
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
76-13-1
95-63-6
.. - ----------.. -
R B S U L T S (Cont'd) Work Order # 9907079
Extraction Batch # · Page 11._
Analysis Batch # MSMSDB90707132401
Date Collected 01Lo1L99 10 :45 Insti:::ument ~ Reporting Subset __ Matrix .!'.!.
Date Received 01Lo2{99 Column Spikes Subset __ Report As received
Date Prepared 00:00:00 Analyst !1§E Specs Subset __ \ Moisture
Date Analyzed 01t.00L99 13:46:00 Reviewer APS
Aliquot Mass/Volume I
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 10 •
Measured Concentration Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.656 0
ND 0.750 0
ND 1.16 0
ND 1.5"6 0
ND 0.334 0
ND 1.23 0
523 0. 776 0
ND 1.48 0
ND 11.8 0
ND 0.929 0
ND 0.650 0
ND 0.920 0
ND 1.17 0
ND 1.14 0
ND 12.6 0
ND 0.766 0
ND 2.11 0
ND 1. 58 0
ND 0.731 0
ND 0.392 0
ND 0.929 0
ND 0.886 0
ND 0.856 0
ND 1. i2 0
ND 0.798 0
-
07/12/99 17:11:00 R B S U L T S (Cont'd) Work Order # 9907079
Extraction Batch # Page 1.l._
Project Sample ID ~0~7~9~9~H~B~W~W~E~O~l'--~~~~~~­
Lab Sample ID 9907079-08B
Date
Date
File # B0707930
Method Volatile Organics SW8260B
Test Code 826SWACM
l
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylen~
Surrogate(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
Date
Date
CAS #
108-67-8
108-05-4
75-01-4
NO_CAS
95-47-6
CAS #
460-00-4
17060-07-0
2037-26-5
Analysis Batch # MSMSDB90707132401
Collected 07£'.01£'.99 10 :45 Instrument tlli.Q!L_
Received 07(02£'.99 Column
Prepared 00:00:00 Analyst !1fil1
Analyzed 07(08(99 13:46:00 Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 10
.· Measured Concentration
ug/L
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
167 163
167 166
167 160
--- - ---- ---
Reporting Subset Matrix !'.l.
Spikes Subset ~-Report As received
Specs Subset ~·-\ Moisture
Detection Limit Reporting Limit
ug/L ug/L
0.910 0
3.23 0
0.889 0
1. 64 0
0.807 0
Specification Limits
Recovery Low High
\ \ \
98 77 117
100 61 143
96 87 113
--- --.. -
----- --------- --
07/12/99 17:11:00 L JI, B 0 R A T 0 R Y B L A Ii )[ I Ii P 0 R M A T I 0 Ii
Extraction Batch # ~---------­
Analysis Batch # MSMSDB90707132401
Lab Sample ID ~B~L~K~9~9~5~6~3~-----­
file # B0707905
Date Prepared 00:00:00 Instrument !1§Q!L__
Column-----
Analyst !::lliB.
Reporting Subset
Spikes Subset
Specs Subset
Date Analyzed 07/07/99 14:45:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzfi!ne
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
Reviewer A-=P~S ___ _
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Cone. Detection Limit
ug/L ug/L
ND 1.43
ND 4.21
ND 0.876
ND 0.152
ND 0.0759
ND 0.0372
ND 0.0766
ND 0.0867
ND 0.0884
ND 0.0908
ND 0.110
ND 0.769
ND 0.108
ND 0.0975
ND 0.110
ND 0.864
ND 0.0962
ND 0.0802
ND 0.0718
ND 0.110
ND 0.0424
ND 0.107
ND 0.114
ND 0.125
ND 0.0845
Work Order # 9907079
Page 1.i_
Matrix !:!
.
Reporting Limit
ug/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
--
-
07/12/99 17:ll:Oq LABORATORY B L A Ii I I Ii F 0 R MAT I 0 Ii (cont'd)
Lab Sample ID =B:..:L"'K:..:9"'9""5""6""3"------
File # B0707905
Method Volatile Organics SW8260B
Test Code 826SWACM
-
Analyte
4-Chlorotoluene
Date Prepared
Date Analyzed
l,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-l,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
1;1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
l',3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
~rans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone -----
Extraction Batch U
Analysis Batch # MSMSDB90707132401
00:00:00 Instrument ~ Reporting Subset
07{.07{.99 14:45:00 Column Spikes Subset
Analyst !:lliE Specs Subset
Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Cone. Detection Limit
ug/L ug/L
ND 0.0586
ND 0.907
ND 0.0530
ND 0.104
ND 0. 0434
ND 0.845
ND 0.0664
ND 0.0549
ND 0 .104
ND 0.0978
ND 0.0736
ND 0.0349
ND 0.102
ND 0.0595
ND 0.138
ND 0.0677
ND 0.0544
ND 0.101
ND 0.0823
ND 0.0584
ND 0.0757
ND 0.0587
ND 0.102
ND 0.251
ND 0.180 - ------
Work Order U 9907079
Page 1.2_
Matrix !:!
•
Reporting Limit
ug/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 --- --
- ---- --- - -------
07/12/99 17:11:00 LABORATORY BLAJiI I Ji F 0 RM AT I 0 Ji (coot'd)
Extraction Batch#-----------
Analysis Batch # MSMSDB90707132401
Lab Sample ID ~B:..L::,:K,_,9:,.,9:,.,5"'6:..:3:_ ___ _ Date Prepared 00:00:00 Instrument ~
Column
Reporting Subset
Spi~es Subset
Specs Subset
Fi.le II 80707905 Date Analyzed 07/07/99 14:45:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
-----
Analyst ~
Reviewer ~A~P~S ___ _
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Cone. Detection Limit
ug/L ug/L
ND 0.0656
ND 0.0750
ND 0.116
ND 0.156
ND 0.0334
ND 0.123
ND 0.0776
ND 0.148
ND 1.18
ND 0. 0929
ND 0.0650
ND 0.0920
ND 0.117
ND 0.114
ND 1.26
ND 0.0766
ND 0.211
ND 0.158
ND 0. 0731
ND 0.0392
ND 0. 0929
ND 0.0886
ND 0.0856
ND 0.112
ND 0.0798
Work Order # 9907079
Page 1..2._
Matrix !:!
' Reporting Limit
ug/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o·
0
-·--
-
07/12/99 17:11:00
Lab Sample ID ;B~L•K•9~9~5~6~3~~~~~
File # B0707905
Method Volatile' organics SW8260B
Test Code 826SWACM
Analyte
Date
Date
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
---- -
L A B 0 R A T 0 R Y B L A II J( I II P 0 R H A T I 0 II (cont'd)
Prepared
Analyzed
Extraction Batch # ~~~~~~~~~~
Analysis Batch # MSMSDB90707132401
00:00:00 Instrument !§Q!L
07/..07/..99 14:45:00 Column
Analyst !::lfili
Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Cone.
ug/L
.ND
ND
ND
ND
ND
Spiked
Cone. Measured Cone.
ug/L ug/L
16.7 16.9
16.7 16.7
16.7 15.9
Reporting Subset
Spikes Subset
Specs Subset
Detection Limit
ug/L
0. 0910
0.323
0.0889
0.164
0.0807
Recovery
\
101
100
95
Work Order # 9907079
Page 1]_
Matrix Ji
•
Reporting Limit
ug/L
0
0
0
0
0
Specification Limits
Low High
\ \
77 117
61 143
87 113
-- ------- --·--
- ---- -- -·-- ------ ---
07/12/99 17:11:00 LABORATORY CONTROL SAMP LB Work Order # 9907079
Extraction Batch H Page 1.!L
Analysis Batch # MSMSDB90707132401
Method Volatile Organics SW8260B Date Prepared 00:00:00 Instrument !1fil2l!._ Reporting Subset Matrix !i
Test Code 826SWAOO Date Analyzed 01Lo1L99 14:18:00 Column Spikes Subset Report As received
Analyst !:lliB Specs Subset % Moisti..re
Reviewer APS Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Control Std. H Vol. Added Surrogate Sol'n H Vol. Added LCS LCS Duplicate Recovery
LCSl ~ 1!.L__ 1 12-DCA-d4 _1 __ 1!.L__ Lab Sample ID Lab Sample ID Spec.
LCS2 ~ 1!.L__ Toluene-dB _1 __ 1!.L__ LCS992548 'LCSD99254 9 Limits RPD
1 4-BFB _1 __ 1!.L__ File ID B0707903 File ID B0707904 ------
Spiked Measured Spiked Measured Spec.
Analyte Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
.· ug/L ug/L % ug/L ug/L 'I; \ \ ·"~· 'I;
Acetone 20.0 19.6 98 20.0 18.3 92 0.1 240 6.3 71
Benzene 20.0 19.3 96 20.0 20.6 103 71 133 7.0 17
Bromobenzene 20.0 21.8 109 20.0 22.3 112 67 127 2.7 12
Bromochloromethane 20.0 21.8 109 20.0 22.3 112 61 145 2.7 21
Bromodichloromethane 20.0 20.4 102 20.0 21.4 107 57 135 4.8 19
Bromof orm 20.0 23.7 119 20.0 24.9 125 23 151 4.9 17
Bromomethane 20.0 17.5 87 20.0 17.6 88 34 128 1.1 25
2-Butanone(MEK) 20.0 18.9 95 20.0 20.6 103 0.1 214 8.1 39
n-Butylbenzene 20.0 20.1 100 20.0 21. 0 105 . 28 184 4.9 30
sec-Butylbenzene 20.0 19.8 99 20.0 20.6 103 45 160 4.0 31
tert-Butylbenzene 20.0 20.1 100 20.0 20.9 104 65 148 3.9 27
Carbon disulfide 20.0 21. 7 108 20.0 21. 8 109 29 223 0.92 23
Carbon tetrachloride 20.0 19.7 98 20.0 20.8 104 46 150 5.9 23
Chlorobenzene 20.0 21. 9 109 20.0 22.6 113 77 129 3.6 14
Chloroethane 20.0 20.1 101 20.0 20.5 103 39 133 2.0 27
Chloroform 20.0 21.2 106 20.0 21. 5 107 64 146 0.94 16
20.0 17.7 88 20.0 18.7 94 18 140 6.6 26 Chloromethane
2-Chlorotoluene 20.0 20.6 103 20.0 21. 0 105 70 136 1. 9 24
4-Chlorotoluene 20.0 21.1 106 20.0 21.4 107 74 132 0. 94 23
1,2-Dibromo-3-chloropropane 20.0 21.2 106 20.0 21. 0 105 39 171 0.95 25
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWAOO
Control Std. # Vol. Added
LCSl Ll_ !&!..__
LCS2 Ll_ !&!..__
------
Analyte
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
1,1-Dichloroethane
1:2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
- ---
LAB 0 R A T 0 R Y C 0 II T R 0 L S AM P L ll: Cont'd Work Order tt 9907079
Extraction Batch # Page 1..2_
Analysis Batch # MSMSDB90707132401
Date Prepared 00:00:00
Date Analyzed 07/07/99 14:18:00
Surrogate Sol'n # Vol. Added
1 1 2-DCA-d4 _1 __ !&!..__
Toluene-dB _1 __ !&!..__
l 4-BFB _1 __ !&!..__
Instrument ~
Column-----
Analyst !:!fill.
Reviewer ~A~P=S ___ _
LCS
Lab Sample ID
LCS992548
File ID B0707903
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 22.9
20.0 22.7
20.0 21. 7
20.0 21. l
20.0 20.6
20.0 20.9
20.0 18.2
20.0 18.8
20.0 19.4
20.0 22.4
20.0 20.3
20.0 21.2
20.0 19.3
20.0 22.2
20.0 16.7
20.0 21.4
20.0 19.8
20.0 22.0
20.0 21. 9
20.0 18.7
Reporting S~bset
Spikes Subset
Specs Subset
LCS Duplicate
Lab Sample ID
LCSD992549
File ID B0707904
Spiked Measured
Rec. Cone. Cone.
\ ug/L ug/L
115 20.0 24.l
114 20.0 23.7
108 20.0 22.6
105 20.0 21.4
103 20.0 21.3
104 20.0 21.2
91 20.0 18.8
94 20.0 19.l
97 20.0 20.l
112 20.0 22.9
102 20.0 20.4
106 20.0 21.3
97 20.0 20.0
111 20.0 23.6
84 20.0 .. 17 .0
107 20.0 22.6
99 20.0 20.3
110 20.0 22.8
109 20.0 22.8
93 20.0 19.0
Matrix !i
Report As received
\ Moisture
Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Recovery
Spec.
Limits RPD
Spec.
Rec. Low High Result Limit
\ \ \ \ \
120 45 137 4.3 15.
118 19 187 3.4 19
113 52 138 4.5 21
107 67 135 l. 9 14
106 68 134 2.9 14
106 70 132 1. 9 13
94 0.1 166 3.2 26
96 66 138 2.1 19
101 48 152 4.0 23
115 47 175 2.6 25
102 66 144 0 18
106 62 146 0 22
100 61 133 3.0 17
118 70 128 6.1 16
85 40 168 1.2 30
113 71 155 5.4 31
102 36 142 3.0 16
114 34 138 3.6 21
114 75 131 4.5 14
95 46 150 2.1 34
-- -- --- -·-- - ---
--- -- ---- --- ---- ---
07/12/99 17:11:00 LABORATORY C 0 Ill T R 0 L SAMPLB Cont'd Work Order II 9907079
Extraction Batch II Page !!Q_
Analysis Batch II MSMSDB90707132401
Method Volatile Organics SW8260B Date Prepared 00:00:00 Instrument MSDB Reporting Subset Matrix l'!
Test Code 826SWAOO Date Analyzed 07[07[99 14:18:00 Column Spikes Subset Report As received
Analyst !:!fili Specs Subset % Moisture
Reviewer APS Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Control Std. II Vol. Added Surrogate Sol'n II Vol. Added LCS LCS Duplicate Recovery
LCSl h.Q_ J!b.._ 1 12-DCA-d4 _1 __ J!b.._ Lab Sample ID Lab Sample ID Spec.
LCS2 h.Q_ J!b.._ Toluene-dB _1 __ J!b.._ LCS992548 LCSD992549 Limits RPO
------- 1 4-BFB _1 __ J!b.._ File ID 80707903 File ID B0707904
Spiked Measured Spiked Measured ' Spec.
Analyte Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L \ ug/L ug/L % % % \, t
2-Hexanone 20.0 20.9 104 20.0 21.4 107 22 164 2.8 34
Isopropylbenzene 20.0 21. 9 109 20.0 23.2 ll6 54 152 6.2 26
p-Isopropyltoluene 20.0 i9.8 99 20.0 20.5 103 41 165 4.0 28
4-Methyl-2-pentanone(MIBK) 20.0 19.5 98 20.0 21.2 106 27 149 7.8 36
Methylene chloride 20.0 20.4 102 20.0 20.2 101 36 166 0.98 23
Naphthalene 20.0 20.8 104 20.0 21.2 106 32 172 1. 9 22
n-Propylbenzene 20.0 20.7 103 20.0 21.4 107 61 143 3. 8 28
s.tyrene 20.0 22.0 110 20.0 22.8 114 68 136 . 3.6 14
1,1,1,2-Tetrachloroethane 20.0 22.9 114 20.0 23.9 120 63 141 5.1 20
1,1,2,2-Tetrachloroethane 20.0 22.5 113 20.0 23.8 119 47 143 5.2 20
Tetrachloroethene 20.0 23.6 118 20.0 24.9 124 69 137 5.0 16
Toluene 20.0 22.3 111 20.0 22:6 113 70 132 1.8 17
1,2,3-Trichlorobenzene 20.0 21. 7 108 20.0 22.1 110 66 140 1.8 20
1,2,4-Trichlorobenzene 20.0 22.3 112 20.0 23.0 115 66 144 2.6 22
1,1,1-Trichloroethane 20.0 17.6 88 20.0 18 .. o 90 49 155 2.2 24
1,1,2-Trichloroethane 20.0 21.8 109 20.0 22.6 ll3 67 135 3.6 17
Trichloroethene 20.0 21.5 107• 20.0 22.3 111 71 129 3.7 17
Trichlorofluoromethane 20.0 21. 7 108 20.0 22.3 112 39 147 3.6 29
1,2,3-Trichloropropane 20.0 22.1 110 20.0 23.4 ll7 64 140 6.2 18
1,2,4-Trimethylbenzene 20.0 20.6 103 20.0 21.0 105 54 156 1. 9 25
07/12/99 17:11:00
Method Volatile Organics SW8260B
Test Code 826SWAOO
Control Std. # Vol. Added
LCSl ~ J:ili__
LCS2 ~ J:ili__
------
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
- - --
Date Prepared
Date Analyzed
Surrogate Sol'n
11 2-DCA-d4
Toluene-dB
1 4-BFB
--
#
LABORATORY COllTROL SAMPLB Cont'd Work Order # 9907079
Extraction Batch # Page ~
Analysis Batch # MSMSDB90707132401
00:00:00
07/07/99 14:18:00
Vol. Added
_1 __ J:ili__
_1 __ J:ili__
_1 __ J:ili__
Instrument ~
Column-----
Analyst ~
Reviewer ~A~P=S ___ _
LCS
Lab Sample ID
LCS992548
File ID B0707903
Spiked Measured
Reporting Subset
Spikes Subset
Specs Subset
LCS Duplicate
' Lab Sample ID
LCSD992549
File ID B0707904
Spiked Measured
Matrix !'!
Report As received
\ Moisture
Aliquot Mass or Vol
Extract Mass or Vol
Recovery
Spec.
Limits
.
Cone. Cone. Rec. Cone. Cone. Rec. Low High
ug/L ug/L \ ug/L ug/L \ \ \
20.0 20.7 103 20.0 20.9 104 62 144
20.0 10.2 51 20.0 10.0 50 0.1 164
20.0 20.3 102 20.0 20.8 104 24 138
40.0 44.4 111 40.0 46.6 116 76 134
20.0 21.8 109 20.0 22.5 113 77 131
16.7 17.3 103 16.7 17.5 105 77 117
16.7 16.7 100 16.7 16.5 99 61 143
16.'7 16.2 9'1 16.'1 16.1 96 87 113
-- -- --- -- -
----=1~5:...:.._,,_0 (mL)
----=1::..5:...:.·~o (mL)
RPO
Spec.
Result Limit
\ \
0.97 25
2.0 31
1. 9 27
4.4 15
3.6 15
---
--- -
07/12/99 17:11:00
Project Sample ID
Method Volatile Organics SW8260B
Test Code 826SWAMS
Spike Sol 'n # Vol. Added
CCV ~ J.!h._
------
------
Surrogate Sol'n Vol. Added
112-DCA-d4 _1 __ J.!h._
Toluene-dB _1 __ J.!h._
1 4-BFB _l __ J.!h._
Analyte
Benzene -
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
Surrogate(s}
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
-
Spike
Sol'n
Cone.
ug/L
200000
20·0000
200000
200000
200000
250000
250000
250000
-- ----·------ -
MATRIX SPlltB(S) Work Order # 9907079
Extraction Batch # Page ~
Analysis Batch # MSMSDB90707132401
Date Collected 06l29l99 15:50 Instrument ~ Reporting Subset
Spikes Subset
Specs Subset
Date Received 06l30l99 Colutnn
Date Prepared 00:00:00 Analyst ~
Date Analyzed 07l07l99 18:50:00 Reviewer APS
Sample Spiked Sample Spiked Sample Dup
Lab Sample ID Lab Sample ID Lab Sample ID
9906929-07A 9906929-0BA MS . 9906929-09A MSD
File # 80707912 File # B0707913 File # B0707914
Aliquot Mass/Vol Aliquot Mass/Vol Aliquot Mass/Vol
15.0 {mL} 15.0 {mL} 15.0 {mL}
Extract Mass/Vol Extract Mass/Vol Extract Mass/Vol
15.0 (mL} 15.0 (mL} 15.0 (mL}
Dil Fact. l Oil Fact. 1 Dil Fact. 1
Measured Spiked Measured Spiked Measured
Cone. Cone. Cone. Rec. Cone. Cone. Rec.
ug/L ug/L ug/L \ ug/L ug/L \
ND 20.0 19.4 97 20.0 19.8 99
ND 20.0 21.5 108 20.0 21. 9 109
ND 20.0 21.1 105 20.0 20.4 102
ND 20.0 22.0 110 20.0 22.7 113
ND 20.0 20.6 103 20.0 20.7 103
16.8 16.7 17.3 103 16.7 17.4 104
17.1 16.7 16.6 99 16.7 16.4 98
15.9 16.7 15.9 95 16.7 16.2 97
Matrix !i
Report A~ received
% Moisture
Recovery
• Specifi---cation
Limits RPO
specifi-
cation
Low High Result Limit
% \ % \
71 133 2.0 17
77 129 0.92 14
47 175 2.9 25
70 132 2.7 17
71 129 0 17
77 117
61 143
87 113
-
-
07/12/99 17:11:00 COlllTilllUilllG(OR DAILY) C A L I B R A T I 0 Ill Work Order # 9907079
Page~
-
V B R I F I C A T I 0 Ill
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Lab Sample ID VSTDCAL
File # B0707902
Date Analyzed 07/07/99 13:24:00 Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Instrument ~
Analyst !:1§.g
Reviewer ~A~P~S.__~~~ Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
-----
Measured
Concentration
ug/L
14.3
77.5
56.2
18.4
18.8
19.0
20.5
20.2
19.1
22.1
17.8
15.7
19.9
19.9
19.1
21.5
18.5
20.5
20.6
19 .. 4
19.6
20.8
18.6
17.3
20.0
--
Recovery
Specification
Limits
Reference
Concentration Recovery Low High
ug/L \ \ \
20.0 71
100 78
100 56
20.0 92
20.0 94
20.0 95
20.0 102
20.0 101
20.0 96
20.0 110
20.0 89
20.0 78
20.0 100
20.0 99
20.0 96
20.0 107
20.0 92
20.0 102
20.0 103
20.0 97
20.0 98 80 120
20.0 104
20.0 93
20.0 87
20.0 100
----------
------- ----- -- - --
07/12/99 17:11:00 COHTillOIJIG(OR DAILY) C A L I B R A T I 0 Iii Work Order II 9907079
Page .§.!___ V B R I P I C A T I 0 Iii (Cont'd)
Analysis Batch II MSMSDB90707132401
Initial Calibration II MSDB990517000000
Lab Sample ID VSTDCAL Date Analyzed 07/07/99 13:24:00 Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
File 11 8070790'2
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
t,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Measured
Concentration
ug/L
20.4
19.2
21.4
20 .4
19.8
19.2
19.7
20.l
19.8
23.0
18.5
18.5
21.9
19.6
19.8
19.2
20.8
16.5
20.1
19 .. 3
20.2
20.6
20.9
19.3
18.9
Reference
Concentration Recovery
ug/L \
20.0 102
20.0 96
20.0 107
20.0 102
20.0 99
20.0 96
20.0 99
20.0 100
20.0 99
20.0 115
20.0 93
20.0 93
20.0 109
20.0 98
20.0 99
20.0 96
20.0 104
20.0 82
20.0 100
20.0 96
20.0 101
20.0 103
20.0 105
20.0 97 .
20.0 ,94
Instrument ~
Analyst !:!fili
Reviewer ~A~P~S---~~~
Recovery
Specification
Limits
Low High
\ \
80 120
80 120
so· 120
--
-
07/12/99 17:11:00 COllTillUillG(OR DAILY) CALIBRATIOll Work Order # 9907079
Page J!L
-
V K R I P I CAT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Lab Sample ID VSTDCAL
File # 80707902
Date Analyzed 07/07/99 13:24:00 Reporting Subset __
Spikes Subset __
Specs Subset __
Instrument !!l2Q!L_
Analyst !:lliE
Method Volatile Organics SWB260B
Test Code 826SWAOO
.
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenii;rile
n-Propylbenzene
Styrene
l,1,l,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Tr~chloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
-- ---
Measured
Concentration
ug/L
20.6
21.4
19.4
18.9
19.8
18.l
19.l
19.4
93.3
20.2
20.9
20.6
20.8
22.2
18.0
21.2
20.2
20.9
16.9
21.~
19.6
22.2
20.6
21. 0
19.7
--
Reviewer ._A .. P_s.._ __ _
Recovery
Specification
Limits
Reference
Concentration Recovery Low High
ug/L \ \ \
20.0 103
20.0 107
20.0 97
20.0 95
20.0 99
. 20.0 91
20.0 95
20.0 97
100 93
20.0 101
20.0 105
20.0 103
20.0 104
20.0 111
20.0 90
20.0 106 80 120
20.0 101
20.0 104
20.0 85
20.0 107
20.0 98
20.0 111
20.0 103
20.0 105
20.0 98
--------- -
- ------ -- ----- - --
07/12/99 17:11:00 C 0 H T I H U I II G OR DAILY) CALIBRATION Work Order # 9907079
Page .§..§._
Lab Sample ID VSTDCAL
File # 80707902
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
1,3,S-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
Toluent-dB
V B R I F I CAT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/07/99 13:24:00
Measured Reference
Concentration Concentration
ug/L ug/L
20.0 20.0
20.1 20.0
20.1 20.0
42.7 40.0
21.3 20.0
17.0 16.7
16.7 16.7
16.4 16.7
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
%
100
101
101
107
106
102
100
98
Instrument !:§.Q!L__
Analyst !:!!IB
Reviewer A:.!!..P~S~~~-
Recovery
Specification
Limits
Low High
% %
80 120
77 117
61 143
87 113
--
.. .,..·
-
07/12/99 17:11:00 C 0 II T I II U I II G ( 0 R. D A I L Y ) CALIBR.ATI0.11 Work Order U 9907079
Page i7_
--
V B R. I F I C A T I 0 II
Analysis Batch U MSMSDB90707132401
Initial Calibration U MSDB990517000000
Lab Sample ID VSTDCAL
File # 80707929
Date Analyzed 07/08/99 13:18:00 Reporting Subset __
Spikes Subset __
Specs Subset Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
B~omochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone (MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
----
Measured Reference
Concentration Concentration Recovery
ug/L ug/L %
15.2 20.0 76
78.4 100 78
60.6 100 61
18.7 20.0 93
20.l 20.0 101
19.5 20.0 98
21.2 20.0 106
20.9 20.0 104
20.2 20.0 101
22.2 20.0 111
18.l 20.0 91
18.5 20.0 93
21.5 20.0 107
21·. 0 20.0 105
20.4 20.0 102
22.4 20.0 112
20.l 20.0 101
21.0 20.0 105
21.5 20.0 108
20 ._3 20.0 102
20.2 20.0 101
21.9 20.0 110
18.3 20.0 92
17.8 20.0 89
20.9 20.0 104
-·-----
Instrument ~
Analyst !:!§E
Reviewer "A::.P"'S'-----
Recovery
Specification
Limits
Low High
\ \
80 120
------
- --- - - ---------- -
07/12/99 17:11:00 COllTillUillG(OR DAILY) CALIBRATIOll Work Order # 9907079
Page filL
Lab Sample ID VSTDCAL
File # 80707929
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
"1, 2 -Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
V B R I P I CAT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/08/99 13:18:00
Measured Reference
Concentration Concentration
ug/L ug/L
21.1 20.0
19.3 20.0
22.2 20.0
20.9 20.0
20.7 20.0
19.5 20.0
20.6 20.0
20.6 20.0
20.5 20.0
21.7 20.0
18.9 20.0
19.3 20.0
22.8 20.0
20.5 20,0
20.5 20.0
20.0 20.0
21.1 20.0
17.1 20.0
21.5 20.0
19 .. 8 20.0
20.6 20.0
20.9 20.0
22.2 20.0
20.8 20.0
18.8 20.0
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
.
Recovery
\
105
96
111
104
103
98
103
103
103
109
94
96
114
102
102
100
105
86
108
99
103
105
111
104
94
Instrument MSDB
Analyst MER
Reviewer ~A~P~S'--~~-
Recovery
Specification
Limits
Low High
\ %
80 120
80 120
80 120
--
-
07/12/99 17:11:00 COllTillOillG(OR DAILY) CALIBRATIOll Work Order # 9907079
Page !lJL V 11 R I F I C AT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Lab Sample ID VSTDCAL
File # 80707929
Date Analyzed 07/08/99 13:18:00 Reporting Subset __
Spikes Subset __
Specs Subset
Instrument !:l§!lli__
Analyst ~
Reviewer "A"'P""'S'-----Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorof luoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
-----
Measured
Concentration
ug/L
22.0
22.5
20 .. 7
19.2
16.6
17.7
19.8
18.9
90.3
21.0
21.5
22.0
20.6
23".5
20.5
21.9
21. 0
21.0
17.7
21.§
21. 3
23.4
21. 5
22.l
20.7
--
Recovery . Specification
Limits
Reference
Concentration Recovery Low High
ug/L \ \ \
20.0 110
20.0 112
20.0 103
20.0 96
20.0 83
20.0 88
20.0 99
20.0 94
100 90
20.0 105
20.0 108
20.0 110
20.0 103
20.0 117
20.0 102
20.0 109 80 120
20.0 105
20.0 105
20.0 89
20.0 108
20.0 107
20.0 117
20.0 107
20.0 lll
20.0 103
----------
- -- --- -------- ---
07/12/99 17:ll:OQ C 0 B T I B 0 I II G ( 0 11. D A I L Y ) CALIBRATION Work Order # 9907079
Page .2.Q__
Lab Sample ID VSTDCAL
File # B0707929
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
V B II. I F I CAT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration# MSDB990517000000
Date Analyzed 07/08/99 13:18:00
Measured Reference
Concentration Concentration
ug/L ug/L
20.8 20.0
18.9 20.0
20.8 20.0
44.8 40.0
22.1 20.0
17.1 16.7
16.1 16.7
16.3 16.7
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
\
104
94
104
112
l:LO
102
96
98
Instrument !:lfil2lL_
Analyst !:!fili
Reviewer ~A~P~S'--~~-
Recovery
Specification
Limits
Low High
\ \
80 120
77 117
61 143
87 113
--
07/12/99 17:11:00
Method Volatile Organics SW8260B
Lab Sample ID
File ID
--
Project Sample
ID/Description
--
Specification# ~~~~
Analyte
---
ARALYTICAL PROTOCOL SUMMARY
COMMBHTS/HARRATIVB
Flag Comment/Narrative
-- --- -
Corrective Action
- -
work Order # 9907079
Page 2_L
- ---
-
07/12/99 17:10:07
Report RADIAN INTERNATIONAL
To 3200 E. CHAPEL HILL RD.
P.O. BOX 13000
Attention JIM NARKUNAS
Prepared _.....!:R:::a~d~i:::a~n~Ic!.n~t:.::e:=rc!.n:::a~t:..::i:.::o~n:::a~l""'-!:L~L:::C:...
By _ __:1~4~0~4~6--==S~u~m~m~i~t--=D~r~·~'--=B~l~d~q~.--=B'­
P. 0. Box 201088
Austin, TX 78720-1088
CSC JALINDSEY
Project Sample
Description
0799HBWW234
ID/
------
MOR~ ORDBR SUMMARY
Client Code HAM BEACH NC
Client HAMILTON BEACH
Facility WASHINGTON,NC
Work ID WATER SUPPLY
Case II .,N~A"---------
SDG II :.:N:..:A _______ _
RAS II 90222AJAL
Lab Sample ID Test Code(s)
OlA 826SWACM
OlB SPAREBOO
OlC SPAREBOO
--- -
Work Order II 9907080
Page _1_
RCN 650138.0901
New York ELAP ID II: 10915
-.-
Method Desciption
Volatile Organics by GC/MS
Spare Sample
Spare Sample
- - ------
- --
07/12/99 17:10:07
-- - --- ---
NORI: ORDER COMMBlllTS
The standard Method 8260A surrogate tolerances are laboratory derived from
historical data. Project specific tolerances may differ.
- -- - --
Work Order tt 9907080
Page _2_
-
07/12/99 17:10:07
State
Arkansas
California
Kansas
Louisiana
North Carolina
New Jersey
New York
Oklahoma
South Carolina
Utah
Wisconsin
-- --- -
STATB CBRTIPICATIOBS
Agency
Department of Pollution Control and Ecology
California Environmental Laboratory Accreditation Program
Kansas Department of Health and Environment
Louisiana Department of Health and Hospitals
Department of Environment, Health and Natural Resources
New Jersey Department of Environmental Protection
New York State Department of Health
Oklahoma Water Resources Board
Department of Health and Environmental Control
Utah Department of Health
Wisconsin Department of Natural Resources
- - -- -- -
Work Order # 9907080
Page _3_
Certification ID
2257
E-10165
LA 97-29
302
82005
10915
8720
82003001
RADC
99885260
- - -- --
- ----- --- ---- -
07/12/99 17:10:07 ANALYTICAL PR.OTOCOL SUMMAR.Y
FLAG DBPINITIOBS
Flag Definition
< DL
NA
NC
Result less than stated Detection Limit and greater than or equal to zero.
Analyte concentration not available for this analysis.
RPO and/or % Recovery not calculated. See Narrative for explanation.
ND Not detected. No instrument response for analyte or result less than zero.
NR Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting 0Limit.
NS Analyte not spiked.
A Presence of hydrocarbon mix eluting in the Lube Oil range. The pattern does not match that of Lube Oil.
B Analyte detected in method blank at concentration greater than the Reporting Limit (and greater than zero) .
C Confirming data obtained using second GC column or GCMS.
D Presence of hydrocarbon mix eluting in the Diesel range. The pattern does not match that of Diesel.
E Analyte concentration exceeded calibration range.
F Interference or coelution suspected. See Narrative for explanation.
G Presence of hydrocarbon mix eluting in the Jet Fuel range. The pattern does not match that of Jet Fuel.
H Presence of analyte previously confirmed by historical data.
I Analyte identification suspect. See Narrat_ive for explanation.
J R,esult is less than stated Detection Limit but greater than or equal to specified Reporting Limit.
K Peak did not meet method identification criteria. Analyte not detected on other GC column.
M Result modified from previous Report. See Narrative for explanation.
p Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3.
Q QC result does not meet tolerance in Protocol Specification.
R Result reported elsewhere.
s Analyte concentration obtained using Method of Standard Additions (MSA) .
T Second column confirmational analysis not performed.
X See Narrative for explanation.
Y See Narrative for explanation.
z See Narrative for explanation.
- --
Work Order # 9907080
Page i._
--
-
07/12/99 17:10:07
Client HAMILTON BEACH
Facility WASHINGTON NC
Client Code HAM BEACH NC
Method Volatile Organics SW8260B
Project Sample ID/Description
0799HBWW234
- - --
AllALYTICAL PROTOCOL SUMMARY
Extraction/Digestion
Lab Sample ID Test Code (s) Batch #
9907080-0lA 826SWACM NA
- -- -- -- --
Work Order # 9907080
Page _s_
Analysis Batch n
MSMSDB90707132401
-- - --
- ----
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
1-Bromo-2-cnloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone (MEKl
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disu°lf ide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
- -- -
RBSULTS
0799HBWW234
9907080-0lA
B0707927
07/01/99 12:20
00:00:00
07/08/99 00:45:00
l
Water
ug/L
received
Cone. DL Cone.
ND 1.43
ND 4.21
ND 0.876
ND 0.152
ND 0.0759
ND 0.0372
ND 0.0766
ND 0.0867
ND 0.0884
ND 0.0908
ND o.ilo
ND 0.769
ND 0.108
ND 0.0975
ND 0.110
ND 0.864
ND 0.0962
ND 0.0802
ND 0,0718
ND 0.110
---- -
SUMMARY
DL Cone. DL
.
- --
Work Order # 9907080
Page .L_
.
Cone. DL
--
-
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix: .
Units:
Report as:
Column:
Analyte
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
4-Chlorotol~ene .
l,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1, 4 -Dichloro-2·-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
--- -
R. B S U L T S
0799HBWW234
9907080-0lA
80707927
07/01/99 12:20
00:00:00
07/08/99 00:45:00
l
Water
ug/L
received
Cone. DL Cone.
ND 0.0424
ND 0.107
ND 0.114
ND 0.125
ND 0. 0845
ND 0.0586
ND 0.907
ND 0.0530
ND 0.104
ND 0.0434
ND 0.845
ND 0.0664
ND 0.0549
ND 0.104
ND 0. 0978
ND 0. 0736
ND 0. 034 9
ND 0.102
ND 0.0595
ND 0.138
----
S UM MA R. Y (Cont'd)
DL Cone. DL
--- --
Work Order tt 9907080
Page _7_
•
Cone. DL
-----
----
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
1,2-Dichloropropane
l,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
-
0799HBWW234
9907080-0lA
80707927
07/01/99 12:20
00:00:00
07/08/99 00:45:00
l
Water
ug/L
received
Cone. DL
ND 0.0677
ND 0.0544
ND O.lOl
ND 0.0823
ND 0.0584
ND 0.0757
ND 0.0587
ND 0.102
ND 0.251
ND o·.100
ND 0.0656
ND 0.0750
ND 0.116
ND. 0.156
ND 0.0334
ND 0.123
ND· 0.0776
ND 0.148
ND 1.18
ND 0.0929
-----·
RESULTS S 0 MM AR Y (Cont'd)
Cone. DL Cone. DL
-
Work Order # 9907080
Page _a_
•
-
Cone. DL
"'
--
·-
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWACM
Project Sample ID:
Lab ID:
File ID:
Date Collected:
Date Prepared:
Date Analyzed:
Dilution Factor:
Matrix:
Units:
Report as:
Column:
Analyte
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
l,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorof luoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
--
RESULTS
0799HBWW234
9907080-0lA
80707927
07/01/99 12:20
00:00:00
07/08/99 00:45:00
l
Water
ug/L
received
Cone. DL Cone.
ND 0.0650
ND 0.0920
ND 0.117
ND 0.114
ND 1.26
ND 0.0766
ND 0.211
ND 0.158
ND 0.0731
ND 0.0392
ND 0.0929
ND 0'.0886
ND 0.0856
ND 0.112
ND 0.0798
ND 0.0910
ND 0.323
ND 0.0889
ND 0.164
ND 0.0807
---
S UM MAR Y (Cont'd)
DL Cone. DL
---· - -
Work Order U 9907080
Page _9_
Cone. DL
--- -
-
07/12/99 17:10:07 I II I T I A L CALIBJlATIOll
Sol'n tt #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Response
Factor
Reference
Cone.
Analytes ug/L
Dichlorodif luoromethane 1.023
1
Chloromethane 2.030
SPCC 0.5
Vinyl chloride 1. 706
CCC 0.5
Bromomethane 1.125
0.5
Chloroethane 0.846
0.5
Trichlorofluoromethane 1.121
0.5
Acrolein 0.030
25
Acetonitrile 0.046
25
Acetone 0.27S
s
Iodomethane 1. 696
1
Response
Factor
Reference
Cone.
ug/L
1.338
5
1. 874
5
1. 666
5
0.873
5
0.880
s
1.172
s
0.030
so
0.047
so
0.222
10
1. 801
s
----· ·--
Initial Calibration tt MSDB990517000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
1.360 1.298 1. 339
20 50 100
1.687 1. 382 1.346
20 50 100
1.677 1. 570 1.586
20 50 100
0.754 0.604 0.573
20 50 100
0.856 0.814 0.791
20 so 100
1.181 1.130 1.123
20 50 100
0.032 0.037 0.032
100 250 soo
0.047 0. 043 0.04S
100 2SO 500
0.212 0.209 0.188
20 50 100
1.765 1.554 1.486
20 50 100
Response
Reference
' Cone.
-.. - -
... -
Response
Reference
Cone.
-
.
Work Order tt 9907080
Page .!.L
Instrument ~
Analyst !:lli£
Reviewer ~A~P~S'-----
Correlation -
RF \ RSD Coefficient
1.27 11. l
1.66 18.0
1.64 3.63
0.786 28.6
0.837 4.19
1.15 2.51
0.0322 8.89
0.04S6 3.67
0.221 14.7
1.66 8.18
--- -
-· ---·, - ----·-
07/12/99 17:10:07 INITIAL CA L I B RAT I 0 H Cont'd
Sol'n # #MS-VOA-STD-19 p. 11
Method Volatile Organics SW82608
Test Code 826SWXOO
Analytes
-
1,1-Dichloroethene
CCC
Carbon disulfide
1,1,2-Trichlorotrifluoroethane
Acrylonitrile
3-Chloropropene
Methylene chloride
trans-1,2-Dichloroethene
Propanenitrile
1,1-Dichloroethane
SPCC
Methyl t-butyl ether
Response Response
Factor Factor
Reference Reference
Cone. Cone.
ug/L ug/L
0.946 0.934
0.5 5
3.563 3.773
1 5
0.700 0.745
l 5
0.198 0.202
5 10
1.991 2.031
0.5 5
1.179 1.116
1 5
0.968 0.932
0.5 5
0.072 0.064
5 25
1.998 1. 891
0.5 5
1.528 1.585
0.5 5
Initial Calibration # MSD89905r7000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.922 0.841 0.808
20 so 100
3.682 3 .400 3.290
20 50 100
0.747 0.675 0.665
20 50 100
0.212 0.213 0.210
20 50 100
2. 042 1.905 1.798
20 50 100
1.085 1.022 0.963
20 50 100
0.925 0.857 0.851
20 50 100
0.073 0.074 0.071
100 250 500
1. 876 1. 774 1. 727
20 50 100
1.848 1. 895 1.876
20 50 100
--
Response Re.sponse
Reference Reference
' Cone. Cone.
--·--
.
Work Order # 9907080
Page g_
Instrument ~
Analyst JEC
Reviewer ~A~P~S~~--
Correlation -
RF \ RSD Coefficient
0.890 6.93
3.54 s.60 -
0.706 5.43
0.207 3.20
1.95 5.23
1. 07 7.79
0.907 5.60
0.0708 5.60
1. 85 5.73
1. 75 10.0
-
-·
07/12/99 17:10:07
Sol'n # #MS-VOA-STD-19 p. 11
Method Volatile Organics SW82608
Test Code 826SWXOO
Analytes
Vinyl acetate
2-Chloro-1,3-butadiene
2-Butanone(MEK)
Tetrahydrof uran
cis-1,2-Dichloroethene
2,2-Dichloropropane
Bromochloromethane
Chloroform
CCC
l,l,l-Trichloroethane
1,2-Dichloroethane
Response
Factor
Reference
Cone.
ug/L
l.295
1
0.824
1
0.354
2
0.13S
2
1.033
0.5
0.902
1
0.601
o.s
1.610
0.5
1.119
o.s
1.133
o.s ... - ---
I Ii I T I A L CAL I B R AT I 0 B Cont'd
Response
Factor
Reference
Cone.
ug/L
1.204
s
0.883
s
0.310
s
0.166
5
1.113
s
0.899
s
O.S76
5
1.622
5
l.082
5
1.067
s
-
Initial Calibration # MSDB990Sl7000000
Calibration Date OS/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
1.304 l.2S8 l.396
20 so 100
0.879 0.823 0.807
20 so 100
0.330 0.306 0.3S2
20 so 100
0.171 0.188 0.199
20 50 100
1.117 1.061 1.038
20 50 100
0.898 0.833 0.816
20 50 100
0.613 O.S93 O.S90
20 50 100
1.631 1.574 1.552
20 so 100
1.071 1.027 l.008
20 so 100
1. 079 1. 073 1.060
20 so 100
·--·-
Response Response
Reference Reference
Cone. Cone.
--
Work Order # 9907080
Page .u._
Instrument !:lfil2!L_
Analyst ~
Reviewer ~A~P~s'--· ~~-
Correlation -
RF !; RSD Coefficient
1.29 S.46
0.843 4.17
0.330 6.83
0 .172 14.2
1. 07 3.76
0.870 4.79
O.S9S 2.30
1.60 2.10
1. 06 4.18
1.08 2.69
----
--•• ---· ----
07/12/99 17:10:07 I Ii I T I A L CA L I B R AT I 0 Ii Cont'd
Sol'n u #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Response
Factor
Reference
Cone.
Analytes ug/L
1,1-Dichloropropene 0.356
0.5
Benzene 1. 350
0.5
Carbon tetrachloride 0.258
0.5
2-Hexanone 0.294
5
4-Methyl-2-pentanone(MIBK) 0.173
2
1,2-Dichloropropane 0.355
CCC 0.5
Trichloroethene 0 .294
0.5
Dibromomethane 0.124
0.5
Bromodichloromethane 0.302
0.5
Methyl methacrylate 0.103
l
Response
Factor
Reference
Cone.
ug/L
0.379
5
1.271
5
0.255
5
0.308
10
0.18
5
0.348
5
0.280
5
0.132
5
0.322
s
0.112
5
Initial Calibration # MSDB990517000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.382 0.358 0. 354
20 50 100
1.258 1.159 1. 090
20 50 100
0.253 0.235 0.228
20 50 100
0.32 0.329 0.322
20 50 100
0.197 0.203 0.203
20 50 100
0.357 0.342 0.328
20 50 100
0.279 0.268 0.257
20 50 100
0 .138 0.139 0.137
20 50 100
0.328 0.323 0.319
20 50 100
0.125 0.128 0.129
20 so 100
---
Response Response
Reference Reference
' Cone. Cone.
•
---
Work Order tt 9907080
Page li._
Instrument ~
Analyst ~
Reviewer ~A,..P-=S'-----
Correlation -
RF \ RSD Coefficient
0.366 3.70
1.23 8. 3.0"-
0. 246 5.45
0.315 4.38
0.191 7.25
0.346 3.38
0.276 5. 04
0.134 4.63
0.319 3.12
0.119 9.56
-
-
07/12/99 17:10:07 I Ii I T I A L CAL I B R AT I 0 Ii Cont'd
Sol'n # #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
2-Chloroethyl vinyl ether
trans-1,3-Dichloropropene
cis-1,3-Dichloropropene
Toluene
CCC
1,1,2-Trichloroethane
Ethyl rnethacrylate
1,3-Dichloropropane
Dibrornochloromethane
1,2-Dibrornoethane
Tetrachloroethene
Response Response
Factor Factor
Reference Reference
Cone. Cone.
ug/L ug/L
0.091 0.117
o.s s
0.77 0.739
o.s s
0.394 0.432
0.5 5
1.862 1.8
0.5 5
0.412 0.463
o.s s
0.S97 0.577
0.5 5
o. 776 0.791
0.5 5
0.523 0.532
o.s s
0.443 0.411
o.s 5
0.514 0.517
0.5 5
- -- - --
Initial Calibration # MSDB990Sl7000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.13 0.131 0.132
20 50 100
0.76 0.759 0.738
20 so 100
0.452 0.442 0.439
20 so 100
l.67S 1.577 1.499
20 so 100
0.4S8 0.456 0.4S
20 so 100
0. 641 0.641 0.634
20 so 100
0. 791 0.784 0.767
20 so 100
0.544 0.532 0.53
2g so 100
0.428 0.431 0.429
20 50 100
0. 504 0.475 0.471
20 50 100
Response
Reference
' Cone.
-·--· -
Response
Reference
Cone.
•
--
Work Order # 9907080
Page .!.§__
Instrument ~
Analyst !l§£
Reviewer :.A:.;P..-S.._ __ _
Correlation -
RF \ RSD Coefficient
0.120 14 .s
0.753 1. 87
0.432 5.17
1.68 8.96
0.448 4.59
0.618 4.74
0.782 1. 32
0.532 1.42
0.428 2.67
0.496 4.39
----
- --.. -
07/12/99 17:10:07
Sol'n # #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
Chlorobenzene
SPCC
1,1,1,2-Tetrachloroethane
1-Chlorohexane
Ethylbenzene
m&p-Xylene
Bromof orm
SPCC
Styrene
o-Xylene
trans-1,4-Dichloro-2-butene
1,1,2,2-Tetrachloroethane
SPCC
Response
Factor
Reference
Cone.
Ug/L
1. 792
o.s
0.497
o.s
0.92
o.s
0.943
o.s
1.168
1
0.243
1
1. 779
o.s
1.209
o.s
0.118
2
0.429
o.s
--.. ---·
I H I T I A L CA L I B RA T I 0 H Cont'd
Response
Factor
Reference
Cone.
ug/L
1.823
s
O.S39
s
0.904
s
0.977
s
1.167
10
0.278
s
1.86
s
1.llS
5
0.13S
5
0.46
5
Initial Calibration # MSDB990S17000000
Calibration Date OS/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
1.764 1.684 1.63S
20 so 100
O.S3S O.SlS O.Sl
20 so 100
0.877 0.84 0.844
20 so 100
o. 929 0.878 0.8SS
20 so 100
1.123 1. 038 0.974
40 100 200
0.29S 0.297 0.298
20 so 100
1.827 1.786 l.7S8
20 so 100
1.lOS 1.0S4 1.021
20 50 100
0.144 0.148 0.153
20 so 100
0.492 0.484 0.483
20 so 100
Response
Reference
Cone.
--
Response
Reference
Cone.
'
-.. -
Work Order # 9907080
Page .!.§__
Instrument .!:!fil2!L_
Analyst !!§£
Reviewer ~A~P~S ___ _
Correlation -
RF % RSD Coefficient
.1. 74 4.48
O.S19 3. ~.~-.
0.877 4.0S
o. 916 S.40
1.09 7.81 -
0.282 8.29
1.80 2.27
1.10 6.SO
o .140 9.86
0.470 s .46
-
-
07/12/99 17:10:07
Sol'n tt #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
1,2,3-Trichloropropane
Isopropylbenzene
Bromobenzene
2-Chlorotoluene
n-Propylbenzene
4-Chlorotoluene
1,3,S-Trimethylbenzene
1,2,4-Trimethylbenzene
tert-Butylbenzene
1,3-Dichlorobenzene
Response
Factor
Reference
C9nc.
ug/L
0.299
0.5
2.665
1
0.873
0.5
0.881
0.5
0.92
1
0.847
1
2.687
1
2.827
1
2. 726
1
1. 618
o.s
-·---
I Ill I T I A L CALIBRATIOJI Cont'd
Response
Factor
Reference
Cone.
ug/L
0.329
5
2.674
5
0.846
5
0.903
5
0.931
5
0.857
5
2.778
s
2.762
s
2.577
5
1. 544
5
Initial Calibration # MSDB990517000000
Calibration Date 05/17/99 00:00:00
Response Response Respons·e
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.351 0.355 0.351
20 50 100
2.616 2.43 2.335
20 so 100
0.825 0.778 0.784
20 so 100
0.865 0.792 0.799
20 50 100
0.906 0.835 0.84
20 50 100
0.841 0.79 0.795
20 so· 100
2.667 2.451 2.424
20 so 100
2.657 2.446 2.364
20 so 100
2.452 2.225 2.144
20 so 100
1. 553 1.452 l.4Sl
20 50 100
Response
Reference
Cone.
------
R~sponse
Reference
Cone.
.
-
Work Order tt 9907080
Page .!1._
Inst,rument !:!2QJL_
Analyst !!§£
Reviewer ~A~P~S ___ _
Correlation -
RF \-RSD Coefficient
0.337 7.00
2.54 6.01
0.821 4.93
0.848 5.88
0.886 5.14
0.826 3.77
2.60 S.98
2 .61 7.6S
2 .42 9.96
1.52 4.71
-- --
---·--
07/12/99 17:10:07
Sol'n " #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
sec-Butylbenzene
1,4-Dichlorobenzene
p-Isopropyltoluene
l,2-Dichlorobenzene
n-Butylbenzene
1,2-Dibromo-3-chloropropane
l,2,4-Trichlorobenzene
Naphthalene
1,2,3-Trichlorobenzene
Hexachlorobutadiene
Response
Factor
Reference
Cone.
ug/L
3.494
1
1. 599
0.5
2.762
1
l.327
0.5
2.484
l
0.06
5
0.496
l
0. 725
0.5
0.267
0.5
0.319
1
---.. -·--
IHITIAL CA L I B RA T I 0 Ii Cont'd
Response
Factor
Reference
Cone.
ug/L
3.585
5
1.538
5
2.726
5
1.336
5
2.628
5
0.077
10
0.592
5
0.861
5
0.395
5
0.346
5
Initial Calibration # MSDB990517000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor. Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
3.355 3.018 2.926
20 50 100
1. 526 1.428 1.406
20 50 100
2.643 2.446 2.431
20 50 100
1.354 1.282 l .294
20 50 100
2.595 2.454 2.468
20 50 100
0.079 0.079 0.082
20 50 100
0.7 0.696 0.697
20 50 100
l.096 1.113 l .113.
20 50 100
0.489 0.475 0.433
20 50 100
0.342 0 .311 0.31
20 50 100
Response
Reference
Cone.
--
Response
Reference
Cone.
•
-
.. ---
Work Order # 9S07080
Page l!L
Instrument ~
Analyst ~
Reviewer ~A~P~S'-----
Correlation -
RF \ RSD Coefficient
3.28 8.88
1. 50 5 .. 31-· '
2.60 5.96
1. 32 2.27
2.53 3 .16-
0.0754 11. 7
0.636 14.3
0.982 18.2
0.412 21.6
0.326 5.29
-
07/12/99 17:10:07
Sol'n tt #MS-VOA-STD-19 p. 11
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
l-Bromo-2-ehloroethane
Response
Factor
Reference
Cone.
ug/L
0.317
o.s
-----I
I II I T I A L CALIBRATIOll Cont'd
Response
Factor
Reference
Cone.
ug/L
0.339
s
-
Initial Calibration # MSDB990517000000
Calibration Date 05/17/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.358 0.36 0.355
20 so 100
Response
Reference
Cone.
--- ---
Response
Reference
Cone.
- -
Work Order tt 9907080
Page l2..._
Instrument MSDB
Analyst !I§£
Reviewer ~A~P~S'"----
Correlation -
RF \" RSD Coefficient
o. 346 5.23
- --
--- ----· ----... -
07/12/99 17:10:07 I II I T I A L CA L I.B R. AT I 0 II
Sol'n " #MS-VOA-STD-19 p. 19
Method Volatile Organics SW8260B
Test Code 826SWXOO
Analytes
4-Methyl-2-pentanol(MIBC)
,
-
Response
Factor
Reference
Cone.
ug/L
0.003
25
Response
Factor
Reference
Cone.
ug/L
0.003
50
. ·
Initial Calibration # MSDB990520000000
Calibration Date 05/20/99 00:00:00
Response Response Response
Factor Factor Factor
Reference Reference Reference
Cone. Cone. Cone.
ug/L ug/L ug/L
0.004 0.005 0.005
100 250 500
Response
Reference
' Cone.
..
Response
Reference
Cone.
- --· -
Work Order # 9907080
Page ~
Inst~ument t:!2.Q!L_
Analyst ~
Reviewer -J~H~C..__ __ _
Correlation -
RF \ RSD Coefficient
0.00400 25.0
•
-~
-
-
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWAOO
Initial Calibration# MSDB990517000000
Calibration Date _o~5·/~1~7./_9_9~~~~-
Sequence/Analysis Time
1 07/07/99 12:30:00
2 07/07/99 13:24:00
3 07 /07./99 13:24:00
4 07/07/99 13:51:00
5 07/07/99 14:18:00
6 07/07/99 14:45:00
7 07/07/99 15:12:00
8 07/07/99 15:39:00
9 07/07/99 16:07:00
10 07/07/99 16:34:00
11 07/07/99 17:01:00
12 07/07/99 17:28:00
13 0~/07/99 17:55:00
14 07/07/99 18:22:00
15 07/07/99 18:50:00
16 07/07/99 19:17:00
17 07/07/99 19:44:00
18 07/07/99 20:11:00
19 07/07/99 20:39:00
20 07/07/99 21:06:00
21 07/07/99 21:33:00
22 07/07/99 22:01:00
23 07/07/99 22:28:00
24 07/07/99 22:55:00
25 07/07/99 23:23:00
26 07/07/99 23:50:00
27 07/08/99 00:18:00
28 07/08/99 00:45:00
29 07/08/99 12:50:00
30 07/08/99 13:18:00
----
A Ill A L Y S I S B A T C B S U M M A R y
Analysis Batch # MSMSDB90707132401
Analysis Start Date/Time 07/07/99 13:24:00
Analysis Stop Date/Time 07/08/99 13:46:00
Work Order # 9907080
Page £1_
Instrument M2£!L__
Analyst M!IB
Reviewer ~A~P~S~~~~~~~~-
Project Sample ID Lab Sample ID Sample Type Analysis File #
SB Blank, System B0707901
BFB GC/MS tune files B0707902
VS TD CAL Continuing Calibration Verification B0707902
LCS992548 Lab Control Sample B0707903
LCSD992549 Lab Control Sample Duplicate B0707904
BLK99563 Blank, Method B0707905
9906929-0lA Sample B0707906
9906929-02A Sample B0707907
9906929-03A Sample B0707908
9906929-04A Sample B0707909
9906929-05A Sample B0707910
9906929-06A Sample B0707911
9906929-07A Sample B0707912
9906929-08A Matrix Spike B0707913
9906929-09A Matrix Spike Duplicate B0707914
9907061-0lA Sample B0707915
9907061-02A Sample B0707916
9907061-03A Sample B0707917
9907079-09A Sample B0707918
9907079-0lA Sample B0707919
9907079-02A Sample B0707920
9907079-03A Sample B0707921
9907079-04A Sample B0707922
9907079-05A Sample B0707923
9907079-06A Sample B0707924
' 9907079-07B Sample B0707925
9907079-08A Sample B0707926
0799HBWW234 9907080-0lA Sample B0707927
SB Blank, System B0707928
BFB GC/MS tune files B0707929
-------... ---- -
--- -
07/12/99 17:10:0\
Method Volatile Organics SW82608
Test Code 826SWAOO
Initial Calibration# MSD8990517000000
Calibration Date ~0~5~/~1~7~/~9~9'-----~
Sequence/Analysis Time
31 07/08/99 13:18:00
32 07/08/99 13:46:00 -
-- -- --- ----
AM A L Y S I S B AT C H S 0 M MAR Y (cont'd)
Analysis Batch # MSMSDB90707132401
Analysis Start Date/Time 07/07/99 13:24:00
Analysis Stop Date/Time 07/08/99 13:46:00
Project Sample ID Lab Sample ID Sample Type
VSTDCAL Continuing
9907079-088 Sample
Calibration
Work Order # 9907080
Page 3..£_
Instrument MSD8
Analyst MJIB
Reviewer :.A:.:P_,.S'----------
Analysis File #
Verification 80707929
80707930
- -
------·----- -- ---
07/12/99 17:10:07 R B S 0 L T S (Cont'd) Work Order # 9907080
Extraction Batch # Page ~
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~4"--~~~~~~­
Lab Sample ID 9907080-0lA
Date
Date
File # 80707927
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
l,l-Dichloroethane
1,2-Dichloroethane
l,l-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
l,l-Dichloropropene
cis-1,3-Dichloropropene
trans-l,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Date
Date
CAS #
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
110-57-6
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
97-63-2
100-41-4
87-68-3
591-7-8-6
Analysis Batch # MSMSDB90707132401
Collected 07 £'.01£'.99 12:20 Instrument !:filQL Reporting Subset ~-Matrix !:!
Received 07 £'.02£'.99 Column Spikes Subset ~-Report As received
Prepared 00:00:00 Analyst !:!fili Specs Subset ~-% Moisture
Analyzed 07 £'.08£'.99 00:45:00 Reviewer APS
Aliquot Mass/Volume '
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1 •
Measured Concentration Detection Limit Reporting Limit
ug/L ug/L ug/L
ND 0.0586 0
ND 0.907 0
ND 0.0530 0
ND 0.104 0
ND 0.0434 0
ND 0.845 0
ND 0.0664 0
ND 0.0549 0
ND 0.104 0
ND 0.0978 0
ND 0.0736 0
ND 0.0349 o
ND 0.102 o
ND 0.0595 o
ND 0.138 o
ND 0.0677 o
ND 0.0544 o
ND 0.101 o
ND 0.0823 0
ND 0.0584 0
ND 0.0757 0
ND 0.0587 0
ND 0.102 o
ND 0.251 0
ND 0.180 0
--
- ------ --------- -
07/12/99 17:10:07 R BS 0 LT S (Cont'd) Work Order II 9907080
Extraction Batch II Page 6f_
Project Sample ID ~0~7~9~9~H~B~W~W~2~3~4'--~~~~~~­
Lab Sample ID 9907080-0lA
File II B0707927
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-XylenE;
Surrogate(s)
l,4-Bromofluorobenzene
CAS II
108-67-8
108-05-4
75-01-4
NO_CAS
95-47-6
CAS #
460-00-4
Date
Date
Date
Date
l,2-Dichloroethane-d4 17060-07-0
Toluene-dB 2037-26-5
Analysis Batch II MSMSDB90707132401
Collected 07{.0l{.99 12:20 Instrument ~
Received 07{.02{.99 Column
Prepared 00:00:00 Analyst !:!fili
Analyzed 07{.0B{.99 00:45:00 Reviewer APS
Aliquot Mass/Volume .
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Concentration
ug/L
ND
ND
ND
ND
ND
Spiked
Cone. Measured Concentration
ug/L ug/L
16.7 16.8
16.7 16.8
16.7 16.l
Reporting Subset ~-Matrix !'.!
Spikes Subset ~-Report As received
Specs Subset ~-t Moisture
'
Detection Limit Reporting Limit
ug/L ug/L
0.0910 .0
0.323 0
0.0889 0
0.164 0
0.0807 0
Specification Limits
Recovery Low High
\ \ \
100 77 117
100 61 143
96 87 113
--
-
07/12/99 17:10:07
Lab Sample ID !:B'-"L"'K'-'9:..:9:..:5:.,,6:..:3,__ ___ _ Date
File # B0707905 Date
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Br-0mo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-l,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene --- --
LABORATORY BLAlil'. IliFORMATIOli
Extraction Batch #
Analysis Batch # MSMSDB90707l3240l
Prepared 00:00:00 Instrument ~ Reporting Subset
Analyzed o7Lo7L99 14:45:00 Column Spikes Subset
Analyst Mfili Specs Subset
Reviewer APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Cone. Detection Limit .· ug/L ug/L
ND l.43
ND 4,21
ND 0.876
ND 0.152
ND 0.0759
ND 0.0372
ND 0.0766
ND 0.0867
ND 0.0884
ND 0.0908
ND 0.110
ND 0.769
ND 0.108
ND 0.0975
ND 0.110
ND 0.864
ND 0.0962
ND 0.0802
ND 0.0718
ND 0.110
ND 0.0424
ND 0.107
ND 0.114
ND 0.125
ND 0.0845 - -·------
Work Order # 9907080
Page l1_
Matrix .!'.!
•
Reporting Limit
ug/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 ---- -
------- -------- -
07/12/99 17:10:07 LABORATORY B L A N It I NF 0 RM AT I 0 N (cont'd)
Extraction Batch #
Analysis Batch # MSMSDB90707l3240l
Lab Sample ID -B~L~K~9-9_5_6_3~~~~~
File # B0707905
Date Prepared 00:00:00 Instrument MSDB
Column
Reporting Subset
Spikes Subset
Specs Subset
Date Analyzed 07/07/99 14:45:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
4-Chlorotoluene
l,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-l,4-Dichloro-2-butene
l,2-Dichlorobenzene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
Dichlorodifluoromethane
l,l-Dichloroethane
l,2-Dichloroethane
l,l-Dichloroethene
cis-l,2-Dichloroe~hene
trans-l,2-Dichloroethene
l,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
Analyst MER
Reviewer ~A~P~S~~~-
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor l
Measured Cone. Detection Limit
ug/L ug/L
ND 0.0586
ND 0.907
ND 0.0530
ND 0.104
ND 0.0434
ND 0.845
ND 0.0664
ND 0 .. 0549
ND 0.104
ND 0.0978
ND 0.0736
ND 0.0349
ND 0.102
ND 0.0595
ND 0.138
ND 0.0677
ND 0.0544
ND 0.101
ND 0.0823
ND 0.0584
ND 0.0757
ND 0.0587
ND 0.102
Nb 0.251
ND 0.180
Work Order # 9907080
Page~
Matrix !'.!
•
Reporting Limit
ug/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
- --
-
07/12/99 17:10:07 LABORATORY BLAJllI I Ill F 0 RM AT I 0 H (cont'd) Work Order # 9907080
Page~
Lab Sample ID =B=L~K~9=9=5=6=3~~~~~
File # 80707905
Date Prepared
Date Analyzed
Method Volatile Organics SW8260B
Test Code 826SWACM
-
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1·, 2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorof luoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene - ----
Extraction Batch #
Analysis Batch # MSMSDB90707132401
00:00:00 Instrument Mfil2!L_
07{.07{.99 14:45:00 Column
Analyst !:l§B
Reviewer APS
Aliquot Mass/Volume
~ 15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Cone.
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ----
Reporting Subset Matrix !'.!
Spikes Subset
Specs Subset
'
Detection Limit Reporting Limit
ug/L ug/L
0.0656 o
0.0750 0
0.116 ·o
0.156 o
0.0334 0
0.123 0
0.0776 o
0.148 o
1.18 0
0.0929 0
0.0650 o
0.0920 0
0.117 0
0.114 o
1.26 o
0.0766 0
0.211 0
0.158 0
0.0731 o
0.0392 0
ci.0929 0
0.0886 0
0.0856 0
0.112 0
0.0798 0 --- -----
- -----
07/12/99 17:10:07
- - ---- --
LABORATORY BLAlll: I II F 0 RM AT I 0 11 (cont'd)
Extraction Batch II
Analysis Batch II MSMSDB90707132401
--
Work Order II 9907080
Page lQ_
Lab Sample ID :B;.:L::.K,.9"'9;..:5:.;:6;..:3:_. ___ _ Date Prepared 00:00:00 Instrument ~
Column-----
Analyst !:!fill,
Reporting Subset
Spi)<es Subset
Specs Subset
Matrix !:!
File 11 B0707905 Date Analyzed 07/07/99 14:45:00
Method Volatile Organics SW8260B
Test Code 826SWACM
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
Surrog<>te(s)
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
Spiked
Cone.
ug/L
16.7
16.7
16.7
Reviewer ~A:.::P..:.S:_. __ _
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor 1
Measured Cone. Detection Limit
ug/L ug/L
ND 0.0910
ND 0.323
ND 0.0889
ND 0.164
ND 0.0807
Measured Cone. Recovery
ug/L \
16.9 101
16.7 100
15.9 95
•
Reporting Limit
ug/L
0
0
0
0
0
Specification Limits
Low High
\ \
77 117
61 143
87 113
- --
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWAOO
Control Std. # Vol. Added
LCSl §..JL_ 1ili_
LCS2 §..JL_ 1ili_
------
Analyte
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone(MEK)
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
-- --
LABORATORY CONTROL SAMPLE Work orqer # 9907080
Extraction Batch # Page 1!_
Analysis Batch # MSMSDB90707132401
Date Prepared 00:00:00
Date Analyzed 07/07/99 14:18:00
Surrogate Sol'n # Vol. Added
112-DCA-d4 _1 __ 1!1._
Toluene-dB _1 __ 1!1._
1 4-BFB _1 __ 1!1._
Instrument !':!fil2!!__
Column -----
Analyst !:!§B
Reviewer ~A~P~S'------
LCS
Lab Sample ID
LCS992548
File ID 80707903
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 19.6
20.0 19.3
20.0 21. 8
20.0 21.8
20.0 20.4
20.0 23.7
20.0 17.5
20.0 18.9
20.0 20.1
20.0 19.8
20.0 20.l
20.0 21. 7
20.0 19.7
20.0 21.9
20.0 20.l
20.0 21.2
20.0 17. 7
20.0 20.6
20.0 21. l
20.0 21.2
Reporting Subset
Spikes Subset
Specs Subset
LCS Duplicate
Lab Sample ID
LCSD992549
File ID 80707904
Spiked Measured
Rec. Cone. Cone.
\ ug/L ug/L
98 20.0 18.3
96 20.0 20.6
109 20.0 22.3
109 20.0 22.3
102 20.0 21.4
119 20.0 24.9
87 20.0 17.6
95 20.0 20.6
100 20.0 21. 0
99 20.0 20.6
100 20.0 20.9
108 20.0 21.8
98 20.0 20.8
109 20.0 22.6
101 20.0 20.5
106 20.0 21.5
88 20.0 18.7
103 20.0 21. 0
106 20.0 21.4
106 20.0 21. 0
Matrix !i
Report As received
% Moisture
Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Recovery
Spec.
Limits RPD
' Spec.
Rec. Low High Result Limit
\ \ \ \ \
92 0.1 240 6.3 71'
103 71 133 7.0 17
112 67 127 2.7 12
112 61 145 2.7 21
107 57 135 4.8 19
125 23 151 4.9 17
88 34 128 1.1 25
103 0.1 214 8 .1 39
105 28 184 4.9 30
103 45 160 4.0 31
104 65 148 3.9 27
109 29 223 0.92 23
104 46 150 5.9 23
113 77 129 3. 6 14
103 39 133 2.0 27
107 64 146 o.!34 16
94 18 140 6. 6 26
105 70 136 l. 9 24
107 74 132 0.94 23
105 39 171 0.95 25
- -- ------ - - ----
----
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWAOO
Control Std. # Vol. Added
LCSl .LlL !:!!!._
LCS2 .LlL !:!!!._
------
Analyte
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene -
Dichlorodifluoromethane
1~1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
-- --- - -·-- --- -
L AB 0 RAT 0 R Y C 0 Ji T R 0 L S AM P L B Cont'd
Extraction Batch #
Analysis Batch # MSMSDB90707132401
Date Prepared 00:00:00
Date Analyzed 07 /07 /99 14: 18.: 00
Surrogate Sol'n # Vol. Added
1 12-DCA-d4 _1 __ !:!!!._
Toluene-dB _1 __ !:!!!._
1 14-BFB _1 __ !:!!!._
.·
Instrument ~
Column-----
Analyst Mfill.
Reviewer ~A~P~S ___ _
LCS
Lab Sample ID
LCS992548
File ID 80707903
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 22.9
20.0 22.7
20.0 21. 7
20.0 21.1
20.0 20.6
20.0 20.9
20.0 18.2
20.0 18.8
20.0 19.4
20.0 22.4
20.0 20.3
20.0 21.2
20.0 19.3
20.0 22.2
20.0 16.7
20.0 21.4
20.0 19.8
20.0 22.0
20.0 21. 9
20.0 18.7
Reporting Subset
Spikes Subset
Specs Subset
LCS Duplicate
Lab Sample ID
LCSD992549
File ID 80707904
Spiked Measured
Rec. Cone. Cone.
% ug/L ug/L
115 20.0 24 .1·
114 20.0 23.7
108 20.0 22.6
105 20.0 21.4
103 20.0 21.3
104 20.0 21.2
91 20.0 18.8
94 20.0 19.1
97 20.0 20.1
112 20.0 22.9
102 20.0 20.4
106 20.0 21. 3
97 20.0 20.0
111 20.0 23.6
84 20.0 17.0
107 20.0 22.6
99 20.0 20.3
110 20.0 22.8
109 20.0 22.8
93 20.0 19.0
Work Order # 9907080
Page 1L
Matrix !:!.
Report As received
% Moisture
Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Recovery
Spec.
Limits RPD
• Spec.
Rec. Low High Result Limit
% \ \ % \
120 45 137 4.3 15
118 19 187 3.4 19
113 52 138 4.5 21
107 67 135 1. 9 14
106 68 134 2.9 14
106 70 132 1. 9 13
94 0.1 166 3.2 26
96 66 138 2.1 19
101 48 152 4.0 23
115 47 175 2.6 25
102 66 144 0 18
106 62 146 0 22
100 61 133 3.0 17
118 70 128 6.1 16
85 40 168 1.2 30
113 71 155 5.4 31
102 36 142 3.0 16
114 34 138 3. 6 21
114 75 131 4.5 14
95 46 150 2.1 34
--
07/12/99 17:10:07
Method Volatile Organics SW8260B
Test Code 826SWAOO
Control Std. II Vol. Added
LCSl §...:..Q_ 1!!:....__
LCS2 §...:..Q_ 1!!:....__
------
Analyte
2-Hexanone
Isopropylbenzene
p-Isopropyltoluene
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
n-Propylbenzene
Styrene
l;l,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorof luoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
- - -
LA B 0 R AT 0 R•Y C 0 H T R 0 L S AM P L B Cont'd Work Order U 9907080
Extraction Batch II Page 11...
Analysis Batch II MSMSDB90707132401
Date Prepared 00:00:00
Date Analyzed 07/07/99 14:18:00
Surrogate Sol•n II Vol. Added
1 1 2-DCA-d4 _1 __ 1!!:....__
Toluene-de _1 __ 1!!:....__
1 14-BFB _1__ 1!!:....__
Instrument ~
Column-----
Analyst !:!§!!
Reviewer ~A~P~S'-----
LCS
Lab Sample ID
LCS992548
File ID B0707903
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 20.9
20.0 21. 9
20.0 19.8
20.0 19.5
20.0 20.4
20.0 20.8
20.0 20.7
20.0 22.0
20.0 22.9
20.0 22.5
20.0 23.6
20.0 22.3
20.0 21. 7
20.0 22.3
20.0 17.6
20.0 21.8
20.0 21.5
20.0 21. 7
20.0 22.l
20.0 20.6
Reporting Subset
Spikes Subset
Specs Subset
LCS Duplicate
Lab Sample ID
LCSD992549
File ID B0707904
Spiked Measured
Rec. Cone. Cone.
% ug/L ug/L
104 20.0 21.4
109 20.0 23.2
99 20.0 20.5
98 20.0 21.2
102 20.0 20.2
104 20.0 21.2
103 20.0 21.4
110 20.0 22.8
114 20.0 23.9
113 20.0 23.8
118 20.0 24. 9
111 20.0 22.6
108 20.0 22.l
112 20.0 23.0
88 20.0 18.0
109 20.0 22.6
107 20.0 22.3
108 20.0 22.3
110 20.0 23.4
103 20.0 21. 0
Matrix ~
Report As received
% Moisture
Aliquot Mass or Vol
Extract Mass or Vol
Recovery
Spec.
Limits
'
Rec. Low High
\ % \
107 22 164
116 54 152
103 41 165
106 27 149
101 36 166
106 32 172
107 61 143
114 68 136
120 63 141
119 47 143
124 69 137
113 70 132
110 66 140
115 66 144
90 49 155
113 67 135
111 71 129
112 39 147
117 64 140
105 54 156
----- - --- - - -
15.0 (mL)
15.0 (mL)
RPO
Spec.
Result Limit
't %
2.8 34·
6.2 26
4.0 28
7.8 36
0.98 23
l. 9 22
3.8 28
3.6 14
5.1 20
5.2 20
5.0 16
1.8 17
1.8 20
2.6 22
2.2 24
3.6 17
3.7 17
3.6 29
6.2 18
1. 9 25
---
--- ----- ------ -----
07/12/99 17:10:07 LABORATORY COllTROL SAMPLE Cont'd Work Order # 9907080
Extraction Batch # Page l.1_
Analysis Batch fl MSMSDB90707132401
Method Volatile Organics SW8260B o_ate Prepared 00:00:00 Instrument !:lfil2!L Reporting Subset Matrix !:!
Test Code 826SWAOO Date Analyzed 07(.07/..99 14:1B:OO Column Spikes Subset Report As received
Analyst t!fili Specs Subset % Moisture
Reviewer APS Aliquot Mass or Vol 15.0 (mL)
Extract Mass or Vol 15.0 (mL)
Control Std. fl Vol. Added Surrogate Sol•n # Vol. Added LCS LCS Duplicate Recovery
LCSl 5.0 uL l,2-DCA-d4 _1 __ 1!1,__ Lab Sample ID Lab Sample ID Spec. ---.---
LCS2 Ll_~ Toluene-dB _1 __ 1!1__ LCS99254B LCSD992549 Limits RPD
-1 4-BFB _1 __ 1!1__ File ID 80707903 File ID 80707904 ------
Spiked Measured Spiked Measured Spec.
Analyte Cone. Cone. Rec. Cone. Cone. Rec. Low High Result Limit
ug/L ug/L \ ug/L ug/L \ \ \ \ \
1,3,5-Trimethylbenzene 20.0 20.7 103 20.0 20.9 104 62 144 0.97 25
Vinyl acetate 20.0 10.2 51 20.0 10.0 so 0.1 164 2.0 31
Vinyl chloride 20.0 20.3 102 20.0 20.B 104 24 13B 1. 9 27
m&p-Xylene 40.0 44.4 111 40.0 46.6 116 76 134 4.4 15
a-Xylene 20.0 21.8 109 20.0 22.5 113 77 131 3.6 15
Surrogate(s)
1,4-Bromofluorobenzene 16.7 17.3 103 16.7 17.5 105 77 117
l,2-Dichloroethane-d4 16.7 16.7 100 16.7 16."5 99 61 143
Toluene-dB 16.7 16.2 97 16.7 16.1 96 B7 113
07/12/99 17:10:07
Project Sample ID
Method Volatile Organics SWB260B
Test Code B26SWAMS
Spike Sol'n # Vol. Added
CCV 2..:...Q_ !:ili_
------
------
Surrogate Sol'n Vol. Added
112-DCA-d4 _1 __ Jlli.._
Toluene-dB _1 __ Jlli.._
1 4-BFB _1 __ ~
Analyte
Benzene
Chlorobenzene
1,1-Dichloroethene
Toiuene
Trichloroethene
Spike
Sol'n
Cone.
ug/L
200000
200000
200000
200000
200000
..__
Surrogate(s)
1,4-Bromofluorobenzene 250000
l,2-Dichloroethane-d4 250000
Toluene-dB 250000
-- ---
MATRIX SPll:B(S) Work Order # 99070BO
Extraction Batch # Page 1.2._
Analysis Batch # MSMSDB90707132401
Date Collected 06[29[99 15:50 Instrument !W2!L_ Reporting Subset
Spikes Subset
Specs Subset
Matrix !:!
Date Received 06[30[99 Column
Date Prepared 00:00:00 Analyst !!1fili
Date Analyzed 07[07[99 1B:50:00 Reviewer APS
Sample Spiked Sample
Lab Sample ID Lab Sample ID
9906929-07A 9906929-0BA MS
File # B0707912 File # B0707913
Aliquot Mass/Vol Aliquot Mass/Vol
15.0 (mL} 15.0 (mL}
Extract Mass/Vol Extract Mass/Vol
15.0 (mL} 15.0 (mL}
Dil Fact. 1 Dil Fact. l
Measured Spiked Measured
Cone. Cone. Cone. Rec.
ug/L ug/L ug/L \
ND 20.0 19.4 97
ND 20.0 21.5 lOB
ND 20.0 21. l 105
ND 20.0 22.0 110
ND 20.0 20.6 103
16.8 16.7 17.3 103
17.1 16.7 16.6 99
15.9 16.7 15.9 95
-- ----
Spiked Sample Dup
Lab Sample ID
9906929-09A MSD
File # B0707914
Aliquot Mass/Vol
15.0 (mL}
Extract Mass/Vol
15.0 (mL)
Dil Fact. 1
Spiked Measured
Cone. Cone.
ug/L ug/L
20.0 19.B
20.0 21.9
20.0 20.4
20.0 22.7
20.0 20.7
16.7 17 .4
16.7 16.4
16.7 16.2
- --
Rec.
\
99
109
102
113
103
104
98
97
Report As received
\ Moisture
Recovery
;specifi-
cation
Limits RPD
Specifi-
cation
Low High Result Limit
\ \ \ \
71 133 2.0 17
77 129 0.92 14
47 175 2.9 25
70 132 2.7 17
71 129 0 17
77 117
61 143
B7 113
- ----
- ----- - - -- ---- - - -
07/12/99 17:10:07 CONTINUING OR DAILY) CALIBRATION Work Order # 9907080
Page li_
Lab Sample ID VSTDCAL
File tt B0707902
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Acetone ·
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromof orm
Bromomethane
2-Butanone(MEKl
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chloro-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
VERIFICATION
Analysis Batch tt MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/07/99 13:24:00
Measured Reference
Concentration Concentration
ug/L ug/L
14.3 20.0
77.5 100
56.2 100
18.4 20.0
18.8 20.0
19.0 20.0
20.5 20.0
20.2 20.0
19.1 20.0
22.1 20.0
17.8 20.0
15.7 20.0
19.9 20.0
19.9 20.0
19.l 20.0
21. 5 20.0
18.5 20.0
20.5 20.0
20.6 20.0
19.4 20.0
19.6 20.0
20.8 20.0
18.6 20.0
17.3 20.0
20.0 20.0
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
%
7l
78
56
92
94
95
102
101
96
110
89
78
100
99
96
107
92
102
103
97
98
104
93
87
100
Instrument ~
Analyst t!fR
Reviewer ~A~P~S~~~-
Recovery
Specification
Limits
Low High
% %
80 120
--
-
07/12/99 17:10:07 C 0 Ii T I Ii U I Ii G OR DAILY) CALIBRATION Work Order # 9907080
Page lL
-
Lab Sample ID VSTDCAL
File # 80707902
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
4-Chlorotoluene
l,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
l,~-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodif luoromethane
l,l-Dichloroethane
l,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
l,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethyl benzene
Hexachlorobutadiene
2-Hexanone
----
V ll: R I P I CAT I 0 Ii (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/07/99 13:24:00
Measured Reference
Concentration Concentration
ug/L ug/L
20.4 20.0
19.2 20.0
21.4 20.0
20.4 20.0
19.8 20.0
19.2 20.0
19.7 20.0
20.l 20.0
19.8 20.0
23.0 20.0
18.5 20.0
18.5 20.0
21.9 20.0
19.6 20.0
19.8 20.0
19.2 20.0
20.8 20.0
16.5 20.0
20.1 20.0
19.3 20.0
20.2 20.0
20.6 20.0
20.9 20.0
19.3 20.0
18.9 20.0
Reporting Subset ~­
Spikes Subset ~­
Specs Subset
Recovery
%
102
96
107
102
99
96
99
100
99
115
93
93
109
98
99
96
104
82
100
96
101
103
105
97
94
Instrument !::llill!L_
Analyst MER
Reviewer ~A~P~S'--~~-
Recovery
Specification
Limits
Low High
% %
80 120
80 120
80 120
- ------------
-- --- --------- - --
07/12/99 17:10:07 CONTINUING OR DAILY) CALIBRATION Work Order II 9907080
Page lL V B R I F I CA T I 0 N (Cont'd)
Analysis Batch II MSMSDB90707132401
Initial Calibration II MSDB990517000000
Lab Sample ID VSTDCAL
File II 80707902
Date Analyzed 07/07/99 13:24:00 Repor~ing Subset ~­
Spikes Subset ~­
Specs Subset ~-Method Volatile Organics SW8260B
Test Code 826SWAOO
Anal:yte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBKl
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
l,l,l-Trichloroethane
·1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
l,2,4-Trimethylbenzene
Measured Reference
Concentration Concentration Recovery
ug/L ug/L \
20.6 20.0 103
21.4 20.0 107
19.4 20.0 97
18.9 20.0 95
19.8 20.0 99
18.1 :20.0 91
19.1 20.0 95
19.4 20.0 97
93.3 100 93
20.2 20.0 101
20.9 20.0 105
20.6 20.0 103
20.8 20.0 104
22.2 20.Q 111
18.0 20:0 9Q
21.2 20.0 106
20.2 20.0 101
20.9 20.0 104
16.9 20.0 85
21. 3 20.0 107
19.6 20.0 98
22.2 20.0 111
20.6 20.0 103
21. 0 20.0 105
19.7 20.0 98
Recovery
Instrument t:1fil2!!.__
Analyst !:!!IB
Reviewer ~A~P~S'--~~-
Specification
Limits
Low High
\ \
80 120
--
-
07/12/99 17:10:0~ CONTINUIHG(OR DAILY) CALIBRATION Work Order U 9907080
Page l.2_
-
Lab Sample ID VSTDCAL
File # 80707902
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogate(s)
1,4-Bromofluorobenzene
1,2-Dichloroethane-d4
'l'oluene-d8
-- --
V B R I F I C A T I 0 II (Coot 'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/07/99 13:24:00
Measured Reference
Concentration Concentration
ug/L ug/L
20.0 20.0
20.1 20.0
20.1 20.0
42.7 40.0
21.3 20.0
17.0 16.7
16.7 16.7
16.4 16.7
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
\
100
101
101
107
106
102
100
98
Instrument !:lliQ§.__
Analyst MER
Reviewer ~A~P=S~~~-
Recovery
Specification
Limits
Low High
\ \
80 120
77 117
61 143
87 113
--------- -- --
- -- -- - - ----- - --- -
07/12/99 17:10:07 COHTIHUIHG(OR DAILY) CALIBRATION Work Order # 9907080
Page iQ_
Lab Sample ID VSTDCAL
File 11 80707929
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
l-Bromo-2-chloroethane
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEKl
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
2-Chlor9-1,3-butadiene
Chlorobenzene
Chloroethane
Chloroform
1-Chlorohexane
Chloromethane
3-Chloropropene
2-Chlorotoluene
VBRIFICATIOJI
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Date Analyzed 07/08/99 13:18:00
Measured Reference
Concentration Concentration
ug/L ug/L
15.2 20.0
78.4 100
60.6 100
18.7 20.0
20.1 20.0
19.5 '20.0
2i.2 20.0
20.9 20.0
20.2 20.0
22.2 20.0
18.1 20.0
18.5 20.0
21.5 20.0
21.0 20.0
20.4 20.0
22.4 20.0
20.1 20.0
21. 0 20.0
21.5 20.0
20.3 20.0
20.2 20.0
21.9 20.0
18.3 20.0
17.8 .20. 0
20.9 20.0
Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Recovery
\
76
78
61
93
101
98
106
104
101
111
91
93
107
105
102
112
101
105
108
102
101
110
92
89
104
Instrument !:l§!2!L_
Analyst tl!IB
Reviewer ~A~P~S~~~-
Recovery
Specification
Limits
Low High
\ \
80 120
--
-
07/12/99 17:10:07 C 0 II T I II 0 I JI G ( 0 R D A I L Y ) C A L I B R A T I 0 JI
V B R I P I CAT I 0 JI (Cont'd)
-
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Work Order # 9907080
Page .il._
Lab Sample ID VSTDCAL
File # 80707929
Date Analyzed 07/08/99 13:18:00 Reporting Subset __
Spikes Subset __
Specs Subset __
Instrument !:l2.Q!L_
Analyst MER
Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane
Dibromomethane
trans-1,4-Dichloro-2-butene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl methacrylate
Ethylbenzene
Hexachlorobutadiene
2-Hexanone
-- ---
Measured
Concentration
ug/L
21.1
19.3
22.2
20.9
20.7
19.S
20.6
20.6
20.S
21. 7
18.9
19.3
22.8
20.5
20.5
20.0
21.1
17.1
21.5
19.8
20.6
20.9
22.2
20.8
18.8
--
Reviewer ~A~P~S ___ _
J;!.ecovery
' Specification
Limits
Reference
Concentration Recovery Low High
ug/L \ \ \
20.0 105
20.0 96
20.0 111
20.0 104
20.0 103
20.0 98
20.0 103
20.0 103
20.0 103
20.0 109
20.0 94
20.0 96
20.0 114 80 120
20.0 102
20.0 102
20.0 100 80 120
20.0 105
20.0 86
20.0 108
20.0 99
20.0 103
20.0 105
20.0 111 80 120
20.0 104
20.0 94
----------
- ---- --------- ---
07/12/99 17:10:07 COHTIHUIHG(OR DAILY) CALIBRATION Work Order # 9907080
Page il_ V B R I F I CAT I 0 H (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Lab Sample ID VSTDCAL
File H 80707929
Date Analyzed 07/08/99 13:18:00 Reporting Subset ~­
Spikes Subset ~­
Specs Subset Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
Iodomethane
Isopropylbenzene
p-Isopropyltoluene
Methyl methacrylate
Methyl t-butyl ether
4-Methyl-2-pentanone(MIBK)
Methylene chloride
Naphthalene
Propanenitrile
n-Propylbenzene
Styrene
l,1,1,2-Tetrachloroethane
l,l,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,2,3-Trichlorobenzene
l,2,4-Trichlorobenzene
1,1,l-Trichloroethane
l,l,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
l,2,3-Trichloropropane
1,1,2-Trichlorotrifluoroethane
1,2,4-Trimethylbenzene
'
Measured Reference
Concentration Concentration Recovery
ug/L ug/L \
22.0 20.0 110
22.5 20.0 112
20.7 20.0 103
19.2 20.0 96
16.6 20.0 83
17.7 20.0 88
19.8 20.0 99
18.9 20.0 94
90.3 100 90
21. 0 20.0 105
21.5 20.0 108
22.0 20.0 110
20.6 ~0.0 103
23.5 20.0 117
20.5 20.0 102
21. 9 20.0 109
21.0 20.0 105
21.0 20.0 105
17.7 20.0 89
21.6 20.0 108
21.3 20.0 107
23.4 20.0 117
21.5 20.0 107
22.1 20.0 111
20.7 20.0 103
Instrument ~
A,nalyst !:!JIB
Reviewer ~A~P~S'--~~-
Recovery
Specification
Limits
Low High
\ \
80 120
-· -
-
07/12/99 17:10:07 C 0 II T I II U I II G ( 0 ll D A I L Y ) C A L I B ll A T I 0 II Work Order # 9907080
Page iL_
-
V B ll I P I CAT I 0 II (Cont'd)
Analysis Batch # MSMSDB90707132401
Initial Calibration # MSDB990517000000
Lab Sample ID VSTDCAL
File # 80707929
Date Analyzed 07/08/99 13:18:00 Reporting Subset ~­
Spikes Subset ~­
Specs Subset ~-
Instrument ~
Analyst !:!!IB
Reviewer ~A~P~S'--~~-Method Volatile Organics SW8260B
Test Code 826SWAOO
Analyte
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m&.p-Xylene
o-Xylene
Surrogate(s}
1,4-Bromofluorobenzene
l,2-Dichloroethane-d4
Toluene-dB
- - - --
Measured
Concentration
ug/L
20.8
18.9
20.8
44.8
22.1
17.1
16.1
16.3
--
Recovery
I Specification
Limits
Reference
Concentration Recovery Low High
ug/L \ \ \
20.0 104
20.0 94
20.0 104 80 120
40.0 112
20.0 110
16.7 102 77 117
16.7 96 61 143
16.7 98 87 113
--- --- -- --
- - - -
07/12/99 17:10:07
Method Volatile Organics SW8260B
Lab Sample ID
File ID
Project S.ample
ID/Description
- - -
Specificationll
Analyte
- -- ---
ANALYTICAL PROTOCOL SUMMARY
COMMBHTS/RARRATIVB
Flag Comment/Narrative
•
- -
Corrective Action
-·--
Work Order II 9907080
Page ii_
-
4.0 CONDffiON OF BOTILES/CONTAINERS
Samples received match COC: · · ~S ON~
See additional discrepancies/comments section: DYES ~O
5.0 ADDmONAL DISCREPAI"iCIES
Appears on COC
A _ .
11
. Page.2 of2
VERIFIED BY: __ ~__.,._-'--_,.,.· ______ -__
Bottles received intact: ~S ONO
S~ples received from USDA rc;stricted area: DYES ~
Appears on Label
Sample ID Date/rime Analysis p Sample ID Datetrime Analysis Conunents
•·
6.0 SHIPPING DOCUMENTATION
Freight bill is available and attached to COC: ~S ONO Carrier: _·_·· ... ·5_.'=eJ,=--__..~"'--------------
Freight bill numbers: '?\ ~~ ;;l;}3't1f/&Q
7.0 OTHER COMI\-IENTS:
Vok:;~N~ol
Client Chain-of-Custody is signed, dated with time of receipt, and addendwn number is noted in the Comments section.
Chain of Custody Addendum Verified By:~ LQ.a. ocff.g~ Date: { ( "2--h S
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