18004_LRMF_Soil Berm Sampling report 20170615

Via Email

June 15, 2017

NC DOT Geotechnical Engineering Unit
1020 Birch Ridge Drive
Raleigh, North Carolina 27610

Attention: Mr. Gordon Box, LG

Re: Brownfields Soil Berm Sampling Report
Brownfields Project 18044-14-060
State Project: P-2918F
WBS Element: 49999.1.STR8
Mecklenburg County, Charlotte, North Carolina
H&H Project No. ROW-510

Dear Gordon:

Please find attached one electronic copy of the Brownfields Soil Berm Sampling Report for NC
DOT Brownfields Parcels 31.1 and 32 located at the Locomotive and Railcar Maintenance
Facility in Charlotte, Mecklenburg County, North Carolina. Please review and return via
DocuSign for final signatures. If you have any questions or need additional information, please
contact us at [phone].

Sincerely,

Hart & Hickman, PC
David Graham, PG Matt Bramblett, PE
Senior Project Geologist Principal

Attachments

Brownfields Soil Berm Sampling
NC DOT Parcel 31.1/32
Charlotte Locomotive and Railcar
Maintenance Facility

Charlotte, Mecklenburg County
North Carolina

Brownfields Project 18044-14-060
H&H Job No. ROW-510
State Project P-2918F
WBS Element #49999.1.STR8
June 15, 2017

Via Email

June 15, 2017

NC DOT Geotechnical Engineering Unit
1020 Birch Ridge Drive
Raleigh, NC 27610

Attention: Mr. Gordon Box, LG

Re: Brownfields Soil Berm Sampling
NC DOT Parcels 31.1/32
Charlotte Locomotive and Railcar Maintenance Facility
Brownfields Project 18044-14-060
State Project: P-2918F; WBS Element: 49999.1.STR8
Charlotte, Mecklenburg County, North Carolina
H&H Project No. ROW-510

Dear Gordon:

1.0 Introduction

On behalf of the North Carolina Department of Transportation (NC DOT), Hart & Hickman, PC
(H&H) is submitting this letter report documenting soil sampling activities conducted at the
referenced Brownfields property (NC DOT Parcels 31.1/32) located at 1320 and 1336 S. Graham
Street near the proposed Charlotte Locomotive and Railcar Maintenance Facility (LRMF) in
Charlotte, Mecklenburg County, North Carolina. A site location map is included as Figure 1, and a
site map is included as Figure 2. Soil sampling activities were conducted on behalf of NC DOT in
accordance with discussions between H&H, NC DOT, and the NC DEQ Brownfields program. A
brief background of this project is provided below.

NC DOT is developing multiple properties for the LRMF project. NC DOT Parcels 31.1 and 32
were developed under a NC DEQ Brownfields Agreement (Brownfields Project #18044-14-060)
as part of the LRMF project. Widespread impacted soil was previously identified on this
Brownfields property. The primary contaminants are total petroleum hydrocarbons (TPH),
Mr. Gordon Box, LG
June 15, 2017
Page 2

S:\AAA-Master Projects\NC DOT Right-of-Way -ROW\ROW-500s\ROW-510 P-2918F Hazardous Soil & Brownfields\BF Berm\Report\P-2918F_BF Soil
Letter_Parcel 31.1-32.doc
polychlorinated biphenyls (PCBs), and metals (including lead above characteristically hazardous
waste thresholds). A portion of the lead impacted soil above hazardous waste thresholds located
in the LRMF soil cut was previously treated on-site to stabilize the lead below hazardous waste
thresholds. This soil was then removed and disposed at a Subtitle D landfill. The LRMF project
also required soil (including low-level non-hazardous impacted soil) to be cut from the northern
portion of the Brownfields property Parcel 32.

As part of the LRMF construction activities, NC DOT’s construction contractor, Zoladz
Construction Company, Inc. (Zoladz) reused the cut soil from the northern portion of the
Brownfields property Parcel 32 in a privacy berm on the Parcel 31.1 portion of the Brownfields
property (see Figure 2). The NC DEQ Brownfields program previously approved reuse of this
cut soil for construction of the berm. However, during construction activities in April 2017,
Zoladz capped the entire berm with 2 ft of fill material (approximately 2,500 cubic yards) that
was cut from an area of the LRMF project that is located approximately 300 ft east of Parcel 32
and outside of the Brownfields property boundary. Because the approved Environmental
Management Plan (EMP) dated May 6, 2016 for the Brownfields property indicates that fill
material must be sampled before it can be imported onto the Brownfields property, NC DEQ
requested that the berm cap be sampled in five locations in an email from Carolyn Minnich dated
April 25, 2017. The berm cap soil sampling activities are described below.

2.0 Soil Sampling Activities

On May 2, 2017, H&H mobilized to the site and installed five soil borings (BERM-1 through
BERM-5) in the berm area. The soil borings were advanced to a depth of one ft below ground
surface (bgs) of the berm using a stainless steel hand auger. The hand auger was decontaminated
between each boring. The soil borings were advanced at five locations to cover a representative
area of the fill soil that was used to cap the berm. The locations of the soil borings are shown on
Figure 2.

Mr. Gordon Box, LG
June 15, 2017
Page 3

S:\AAA-Master Projects\NC DOT Right-of-Way -ROW\ROW-500s\ROW-510 P-2918F Hazardous Soil & Brownfields\BF Berm\Report\P-2918F_BF Soil
Letter_Parcel 31.1-32.doc
Soil samples were collected from 0 to 1 ft bgs from the berm cap and were field screened with a
photoionization detector (PID). Additionally, H&H observed the soil for visual and olfactory
indications of impacts. There were no obvious indications of impacts based on field screening of
the soil samples collected from the berm cap. Visual observations during sampling activities
indicated that the soil consisted of red and brown silty clay with some gravel throughout the
capped portion of the berm. Soil sample depths and PID readings are included on Table 1. Soil
boring logs are included in Appendix A.

H&H submitted a total of five soil samples from five soil borings (BERM-1 through BERM-5)
for laboratory analysis. The soil samples were placed into laboratory supplied sample containers
using nitrile glove-covered hands. The containers were then labeled as to content, analyses
requested, sample date and time, and sampler’s name. The samples were placed in an iced
cooler upon collection and were subsequently submitted to Pace Analytical Services, Inc. under
standard chain-of-custody protocol. Laboratory analytical data sheets and chain-of-custody
documentation are provided in Appendix B.

The samples were submitted for analysis of volatile organic compounds (VOCs) by EPA Method
8260, semi-VOCs (SVOCs) by EPA Method 8270, Hazardous Substance List (HSL) metals
using EPA Methods 6010/7471, hexavalent chromium by EPA Method 7196, and PCBs by EPA
Method 1668. Soil analytical results are summarized in Table 1. The analytical results are
discussed below.

Upon completion of the berm cap soil sampling activities, the berm was seeded and mulched by
Zoladz with a hydroseeding mechanical device to prevent erosion of the berm.

3.0 Soil Sampling Results

Because this is a Brownfields property and in accordance with the EMP, detected concentrations
in the soil samples were compared to NC DEQ IHSB Industrial Health-Based Soil Remediation
Mr. Gordon Box, LG
June 15, 2017
Page 4

S:\AAA-Master Projects\NC DOT Right-of-Way -ROW\ROW-500s\ROW-510 P-2918F Hazardous Soil & Brownfields\BF Berm\Report\P-2918F_BF Soil
Letter_Parcel 31.1-32.doc
Goals (SRGs). Trace levels of PCB congeners were detected in soil samples BERM-2 and
BERM-3. No Industrial SRGs have been established for the detected congeners. The highest
single congener detection was 0.000642 mg/kg. The total PCBs detected in each of these
samples did not exceed the total PCBs Industrial SRG of 0.94 mg/kg. Low level metals were
detected in each of the soil samples (BERM-1 through BERM-5) below the Industrial SRGs.
The detected metals concentrations were within published background metal concentrations in
the region. No other target constituents were detected above laboratory reporting limits in the
soil samples collected from the berm cap.

4.0 Conclusions

H&H has completed soil sampling activities for the berm cap located on the Brownfields
property at the LRMF project site in Charlotte, Mecklenburg County. Low level PCBs were
detected below the IHSB Industrial SRGs in two of the five soil samples collected from the fill
material that was used to cap the berm. The approved EMP for the Brownfields property
indicates that the screening criteria by which soil disposition decisions will be made (i.e. left in
place, capped in place, etc.) are the Industrial Health-Based SRGs. The detected constituents in
the capped area of the berm are below the Industrial SRGs. Therefore, the berm cap will be left
in place.

Should you have any questions or need additional information, please do not hesitate to contact
us at [phone].

Sincerely,
Hart & Hickman, PC

David Graham, PG Matt Bramblett, PE
Senior Project Geologist Principal

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(
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(
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Background Metals in Soil 3IHSB POG 2 (mg/kg)
Sc
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Table 1 (Page 1 of 1)Hart & Hickman, PC
SITE
0 2000 4000
APPROXIMATE
SCALE IN FEET
N
U.S.G.S. QUADRANGLE MAP
QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)
Charlotte East, NC 1991
TITLE
PROJECT
SITE LOCATION MAP
NC DOT BROWNFIELDS PROPERTY #18044-14-060
1320 & 1336 S. GRAHAM STREET
CHARLOTTE, NORTH CAROLINA
DATE:
JOB NO:
REVISION NO:
FIGURE:
6-8-17 0
1ROW-510
7
1
4
7
1
5
7
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6
716
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CONC
.
BERM LOCATION
BERM-3
BERM-1
BERM-2
BERM-4 BERM-5
CONCRETE PAD
CONCRETE PAD
REVISION NO. 0
FIGURE NO. 2
SOIL BERM SAMPLE LOCATIONSLEGEND
SITE PROPERTY BOUNDARY
PARCEL LINE
FORMER SITE BUILDING
OFF-SITE BUILDING
PROPOSED CUT LINE
RAILROAD RIGHT-OF-WAY
FENCELINE
PROPOSED DRAINAGE DITCH
NC DOT PARCEL NUMBER
SOIL SAMPLE LOCATION
JOB NO. ROW-510
DATE: 6-8-17
NC DOT - BROWNFIELDS PROPERTY #18044-14-060
1320 & 1336 S. GRAHAM STREET
CHARLOTTE, MECKLENBURG COUNTY
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
S:\
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Appendix A
Soil Boring Logs
Slightly moist, red brown, silty CLAY with gravel
Bottom of borehole at 1.0 feet.
0.0 3.7
DRAWN BY:GES
BORING COMPLETED:5/2/17
DRILLING CONTRACTOR:H&H Remarks:
DRILL RIG/ METHOD:Hand Auger
SAMPLING METHOD:Hand Auger Soil sample collected from 0-1 ft bgs forlaboratory analysis.
BORING STARTED:5/2/17
LOGGED BY:DV
TOTAL DEPTH: 1 ft.
TOP OF CASING ELEV:
DEPTH TO WATER:
DE
P
T
H
(f
t
)
DE
P
T
H
(f
t
)
LI
T
H
O
L
O
G
Y
MATERIAL DESCRIPTION
RE
C
O
V
E
R
Y

(
%
)
SA
M
P
L
E

T
Y
P
E
NU
M
B
E
R
OV
A

(
p
p
m
)
BORING DIAGRAM
BK
G
.
SA
M
P
.
Sheet 1 of 1
BORING NUMBER BERM-1
PROJECT:NC DOT Project P-2918F - Parcel 31.1/32
JOB NUMBER:ROW-510
LOCATION:Charlotte, NC
BO
R
I
N
G

L
O
G

-

H
A
R
T

H
I
C
K
M
A
N
.
G
D
T

-

6
/
9
/
1
7

0
9
:
1
8

-

S
:
\
B
B
B

M
A
S
T
E
R

G
I
N
T

P
R
O
J
E
C
T
S
\
R
O
W
-
5
1
0
.
G
P
J
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
3334 Hillsborough Street
Raleigh, North Carolina 27607
919-847-4241(p) 919-847-4261(f)
0
1
0
1
Slightly moist, red brown, silty CLAY with gravel
Bottom of borehole at 1.0 feet.
0.0 2.6
DRAWN BY:GES
BORING COMPLETED:5/2/17
DRILLING CONTRACTOR:H&H Remarks:
DRILL RIG/ METHOD:Hand Auger
SAMPLING METHOD:Hand Auger Soil sample collected from 0-1 ft bgs forlaboratory analysis.
BORING STARTED:5/2/17
LOGGED BY:DV
TOTAL DEPTH: 1 ft.
TOP OF CASING ELEV:
DEPTH TO WATER:
DE
P
T
H
(f
t
)
DE
P
T
H
(f
t
)
LI
T
H
O
L
O
G
Y
MATERIAL DESCRIPTION
RE
C
O
V
E
R
Y

(
%
)
SA
M
P
L
E

T
Y
P
E
NU
M
B
E
R
OV
A

(
p
p
m
)
BORING DIAGRAM
BK
G
.
SA
M
P
.
Sheet 1 of 1
BORING NUMBER BERM-2
PROJECT:NC DOT Project P-2918F - Parcel 31.1/32
JOB NUMBER:ROW-510
LOCATION:Charlotte, NC
BO
R
I
N
G

L
O
G

-

H
A
R
T

H
I
C
K
M
A
N
.
G
D
T

-

6
/
9
/
1
7

0
9
:
1
8

-

S
:
\
B
B
B

M
A
S
T
E
R

G
I
N
T

P
R
O
J
E
C
T
S
\
R
O
W
-
5
1
0
.
G
P
J
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
3334 Hillsborough Street
Raleigh, North Carolina 27607
919-847-4241(p) 919-847-4261(f)
0
1
0
1
Slightly moist, red brown, silty CLAY with gravel
Bottom of borehole at 1.0 feet.
0.0 2.1
DRAWN BY:GES
BORING COMPLETED:5/2/17
DRILLING CONTRACTOR:H&H Remarks:
DRILL RIG/ METHOD:Hand Auger
SAMPLING METHOD:Hand Auger Soil sample collected from 0-1 ft bgs forlaboratory analysis.
BORING STARTED:5/2/17
LOGGED BY:DV
TOTAL DEPTH: 1 ft.
TOP OF CASING ELEV:
DEPTH TO WATER:
DE
P
T
H
(f
t
)
DE
P
T
H
(f
t
)
LI
T
H
O
L
O
G
Y
MATERIAL DESCRIPTION
RE
C
O
V
E
R
Y

(
%
)
SA
M
P
L
E

T
Y
P
E
NU
M
B
E
R
OV
A

(
p
p
m
)
BORING DIAGRAM
BK
G
.
SA
M
P
.
Sheet 1 of 1
BORING NUMBER BERM-3
PROJECT:NC DOT Project P-2918F - Parcel 31.1/32
JOB NUMBER:ROW-510
LOCATION:Charlotte, NC
BO
R
I
N
G

L
O
G

-

H
A
R
T

H
I
C
K
M
A
N
.
G
D
T

-

6
/
9
/
1
7

0
9
:
1
8

-

S
:
\
B
B
B

M
A
S
T
E
R

G
I
N
T

P
R
O
J
E
C
T
S
\
R
O
W
-
5
1
0
.
G
P
J
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
3334 Hillsborough Street
Raleigh, North Carolina 27607
919-847-4241(p) 919-847-4261(f)
0
1
0
1
Slightly moist, red brown, silty CLAY with gravel
Bottom of borehole at 1.0 feet.
0.0 0.9
DRAWN BY:GES
BORING COMPLETED:5/2/17
DRILLING CONTRACTOR:H&H Remarks:
DRILL RIG/ METHOD:Hand Auger
SAMPLING METHOD:Hand Auger Soil sample collected from 0-1 ft bgs forlaboratory analysis.
BORING STARTED:5/2/17
LOGGED BY:DV
TOTAL DEPTH: 1 ft.
TOP OF CASING ELEV:
DEPTH TO WATER:
DE
P
T
H
(f
t
)
DE
P
T
H
(f
t
)
LI
T
H
O
L
O
G
Y
MATERIAL DESCRIPTION
RE
C
O
V
E
R
Y

(
%
)
SA
M
P
L
E

T
Y
P
E
NU
M
B
E
R
OV
A

(
p
p
m
)
BORING DIAGRAM
BK
G
.
SA
M
P
.
Sheet 1 of 1
BORING NUMBER BERM-4
PROJECT:NC DOT Project P-2918F - Parcel 31.1/32
JOB NUMBER:ROW-510
LOCATION:Charlotte, NC
BO
R
I
N
G

L
O
G

-

H
A
R
T

H
I
C
K
M
A
N
.
G
D
T

-

6
/
9
/
1
7

0
9
:
1
8

-

S
:
\
B
B
B

M
A
S
T
E
R

G
I
N
T

P
R
O
J
E
C
T
S
\
R
O
W
-
5
1
0
.
G
P
J
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
3334 Hillsborough Street
Raleigh, North Carolina 27607
919-847-4241(p) 919-847-4261(f)
0
1
0
1
Slightly moist, red brown, silty CLAY with gravel
Bottom of borehole at 1.0 feet.
0.0 0
DRAWN BY:GES
BORING COMPLETED:5/2/17
DRILLING CONTRACTOR:H&H Remarks:
DRILL RIG/ METHOD:Hand Auger
SAMPLING METHOD:Hand Auger Soil sample collected from 0-1 ft bgs forlaboratory analysis.
BORING STARTED:5/2/17
LOGGED BY:DV
TOTAL DEPTH: 1 ft.
TOP OF CASING ELEV:
DEPTH TO WATER:
DE
P
T
H
(f
t
)
DE
P
T
H
(f
t
)
LI
T
H
O
L
O
G
Y
MATERIAL DESCRIPTION
RE
C
O
V
E
R
Y

(
%
)
SA
M
P
L
E

T
Y
P
E
NU
M
B
E
R
OV
A

(
p
p
m
)
BORING DIAGRAM
BK
G
.
SA
M
P
.
Sheet 1 of 1
BORING NUMBER BERM-5
PROJECT:NC DOT Project P-2918F - Parcel 31.1/32
JOB NUMBER:ROW-510
LOCATION:Charlotte, NC
BO
R
I
N
G

L
O
G

-

H
A
R
T

H
I
C
K
M
A
N
.
G
D
T

-

6
/
9
/
1
7

0
9
:
1
8

-

S
:
\
B
B
B

M
A
S
T
E
R

G
I
N
T

P
R
O
J
E
C
T
S
\
R
O
W
-
5
1
0
.
G
P
J
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
3334 Hillsborough Street
Raleigh, North Carolina 27607
919-847-4241(p) 919-847-4261(f)
0
1
0
1

Appendix B
Laboratory Analytical Report

#=CL#
May 23, 2017
LIMS USE: FR - CHEMICAL
LIMS OBJECT ID: 92338971
92338971
Project:
Pace Project No.:
RE:
Chemical Testing Engineer
NCDOT
Materials & Tests Unit
1801 Blue Ridge Road
Raleigh, NC 27607
DOT 49999.1.ST8 ROW 510
Dear Chemical Engineer:
Enclosed are the analytical results for sample(s) received by the laboratory on May 02, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
1(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 97
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 97
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92338971001 BERM-1 EPA 6010 13 PASI-ASH1
EPA 7471 1 PASI-AKAL
EPA 8270 75 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CCLW
EPA 7196 1 PASI-ACJH1
92338971002 BERM-2 EPA 6010 13 PASI-ASH1
EPA 7471 1 PASI-AKAL
EPA 8270 75 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CCLW
EPA 7196 1 PASI-ACJH1
92338971003 BERM-3 EPA 6010 13 PASI-ASH1
EPA 7471 1 PASI-AKAL
EPA 8270 75 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CCLW
EPA 7196 1 PASI-ACJH1
92338971004 BERM-4 EPA 6010 13 PASI-ASH1
EPA 7471 1 PASI-AKAL
EPA 8270 75 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CCLW
EPA 7196 1 PASI-ACJH1
92338971005 BERM-5 EPA 6010 13 PASI-ASH1
EPA 7471 1 PASI-AKAL
EPA 8270 75 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CCLW
EPA 7196 1 PASI-ACJH1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-1 Lab ID:92338971001 Collected:05/02/17 09:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/17 23:20 7440-36-005/03/17 14:150.54 1
Arsenic 1.3 mg/kg 05/03/17 23:20 7440-38-205/03/17 14:151.1 1
Beryllium 0.34 mg/kg 05/03/17 23:20 7440-41-705/03/17 14:150.11 1
Cadmium ND mg/kg 05/03/17 23:20 7440-43-905/03/17 14:150.11 1
Chromium 30.2 mg/kg 05/03/17 23:20 7440-47-305/03/17 14:150.54 1
Copper 52.1 mg/kg 05/03/17 23:20 7440-50-805/03/17 14:150.54 1
Lead 6.2 mg/kg 05/03/17 23:20 7439-92-105/03/17 14:150.54 1
Manganese 633 mg/kg 05/03/17 23:20 7439-96-505/03/17 14:150.54 1
Nickel 12.0 mg/kg 05/03/17 23:20 7440-02-005/03/17 14:150.54 1
Selenium 1.8 mg/kg 05/03/17 23:20 7782-49-205/03/17 14:151.1 1
Silver ND mg/kg 05/03/17 23:20 7440-22-405/03/17 14:150.54 1
Thallium ND mg/kg 05/03/17 23:20 7440-28-005/03/17 14:151.1 1
Zinc 59.4 mg/kg 05/03/17 23:20 7440-66-605/03/17 14:151.1 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.025 mg/kg 05/04/17 17:35 7439-97-605/04/17 06:250.0047 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/17 13:22 83-32-905/04/17 22:234251
Acenaphthylene ND ug/kg 05/05/17 13:22 208-96-805/04/17 22:234251
Aniline ND ug/kg 05/05/17 13:22 62-53-305/04/17 22:234251
Anthracene ND ug/kg 05/05/17 13:22 120-12-705/04/17 22:234251
Benzo(a)anthracene ND ug/kg 05/05/17 13:22 56-55-305/04/17 22:234251
Benzo(a)pyrene ND ug/kg 05/05/17 13:22 50-32-805/04/17 22:234251
Benzo(b)fluoranthene ND ug/kg 05/05/17 13:22 205-99-205/04/17 22:234251
Benzo(g,h,i)perylene ND ug/kg 05/05/17 13:22 191-24-205/04/17 22:234251
Benzo(k)fluoranthene ND ug/kg 05/05/17 13:22 207-08-905/04/17 22:234251
Benzoic Acid ND ug/kg 05/05/17 13:22 65-85-005/04/17 22:2321201
Benzyl alcohol ND ug/kg 05/05/17 13:22 100-51-605/04/17 22:238491
4-Bromophenylphenyl ether ND ug/kg 05/05/17 13:22 101-55-305/04/17 22:234251
Butylbenzylphthalate ND ug/kg 05/05/17 13:22 85-68-705/04/17 22:234251
4-Chloro-3-methylphenol ND ug/kg 05/05/17 13:22 59-50-705/04/17 22:238491
4-Chloroaniline ND ug/kg 05/05/17 13:22 106-47-805/04/17 22:2321201
bis(2-Chloroethoxy)methane ND ug/kg 05/05/17 13:22 111-91-105/04/17 22:234251
bis(2-Chloroethyl) ether ND ug/kg 05/05/17 13:22 111-44-405/04/17 22:234251
2-Chloronaphthalene ND ug/kg 05/05/17 13:22 91-58-705/04/17 22:234251
2-Chlorophenol ND ug/kg 05/05/17 13:22 95-57-805/04/17 22:234251
4-Chlorophenylphenyl ether ND ug/kg 05/05/17 13:22 7005-72-305/04/17 22:234251
Chrysene ND ug/kg 05/05/17 13:22 218-01-905/04/17 22:234251
Dibenz(a,h)anthracene ND ug/kg 05/05/17 13:22 53-70-305/04/17 22:234251
Dibenzofuran ND ug/kg 05/05/17 13:22 132-64-905/04/17 22:234251
1,2-Dichlorobenzene ND ug/kg 05/05/17 13:22 95-50-105/04/17 22:234251
1,3-Dichlorobenzene ND ug/kg 05/05/17 13:22 541-73-1 L205/04/17 22:234251
1,4-Dichlorobenzene ND ug/kg 05/05/17 13:22 106-46-705/04/17 22:234251
3,3'-Dichlorobenzidine ND ug/kg 05/05/17 13:22 91-94-105/04/17 22:2321201
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-1 Lab ID:92338971001 Collected:05/02/17 09:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 05/05/17 13:22 120-83-205/04/17 22:234251
Diethylphthalate ND ug/kg 05/05/17 13:22 84-66-205/04/17 22:234251
2,4-Dimethylphenol ND ug/kg 05/05/17 13:22 105-67-905/04/17 22:234251
Dimethylphthalate ND ug/kg 05/05/17 13:22 131-11-305/04/17 22:234251
Di-n-butylphthalate ND ug/kg 05/05/17 13:22 84-74-205/04/17 22:234251
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/17 13:22 534-52-105/04/17 22:238491
2,4-Dinitrophenol ND ug/kg 05/05/17 13:22 51-28-505/04/17 22:2321201
2,4-Dinitrotoluene ND ug/kg 05/05/17 13:22 121-14-205/04/17 22:234251
2,6-Dinitrotoluene ND ug/kg 05/05/17 13:22 606-20-205/04/17 22:234251
Di-n-octylphthalate ND ug/kg 05/05/17 13:22 117-84-005/04/17 22:234251
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/17 13:22 117-81-705/04/17 22:234251
Fluoranthene ND ug/kg 05/05/17 13:22 206-44-005/04/17 22:234251
Fluorene ND ug/kg 05/05/17 13:22 86-73-705/04/17 22:234251
Hexachloro-1,3-butadiene ND ug/kg 05/05/17 13:22 87-68-305/04/17 22:234251
Hexachlorobenzene ND ug/kg 05/05/17 13:22 118-74-105/04/17 22:234251
Hexachlorocyclopentadiene ND ug/kg 05/05/17 13:22 77-47-405/04/17 22:234251
Hexachloroethane ND ug/kg 05/05/17 13:22 67-72-105/04/17 22:234251
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/17 13:22 193-39-505/04/17 22:234251
Isophorone ND ug/kg 05/05/17 13:22 78-59-105/04/17 22:234251
1-Methylnaphthalene ND ug/kg 05/05/17 13:22 90-12-005/04/17 22:234251
2-Methylnaphthalene ND ug/kg 05/05/17 13:22 91-57-605/04/17 22:234251
2-Methylphenol(o-Cresol)ND ug/kg 05/05/17 13:22 95-48-705/04/17 22:234251
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/17 13:22 15831-10-405/04/17 22:234251
Naphthalene ND ug/kg 05/05/17 13:22 91-20-305/04/17 22:234251
2-Nitroaniline ND ug/kg 05/05/17 13:22 88-74-405/04/17 22:2321201
3-Nitroaniline ND ug/kg 05/05/17 13:22 99-09-205/04/17 22:2321201
4-Nitroaniline ND ug/kg 05/05/17 13:22 100-01-605/04/17 22:238491
Nitrobenzene ND ug/kg 05/05/17 13:22 98-95-305/04/17 22:234251
2-Nitrophenol ND ug/kg 05/05/17 13:22 88-75-505/04/17 22:234251
4-Nitrophenol ND ug/kg 05/05/17 13:22 100-02-705/04/17 22:2321201
N-Nitrosodimethylamine ND ug/kg 05/05/17 13:22 62-75-905/04/17 22:234251
N-Nitroso-di-n-propylamine ND ug/kg 05/05/17 13:22 621-64-705/04/17 22:234251
N-Nitrosodiphenylamine ND ug/kg 05/05/17 13:22 86-30-605/04/17 22:234251
2,2'-Oxybis(1-chloropropane)ND ug/kg 05/05/17 13:22 108-60-105/04/17 22:234251
Pentachlorophenol ND ug/kg 05/05/17 13:22 87-86-505/04/17 22:2321201
Phenanthrene ND ug/kg 05/05/17 13:22 85-01-805/04/17 22:234251
Phenol ND ug/kg 05/05/17 13:22 108-95-205/04/17 22:234251
Pyrene ND ug/kg 05/05/17 13:22 129-00-005/04/17 22:234251
Pyridine ND ug/kg 05/05/17 13:22 110-86-105/04/17 22:234251
1,2,4-Trichlorobenzene ND ug/kg 05/05/17 13:22 120-82-105/04/17 22:234251
2,4,5-Trichlorophenol ND ug/kg 05/05/17 13:22 95-95-405/04/17 22:234251
2,4,6-Trichlorophenol ND ug/kg 05/05/17 13:22 88-06-205/04/17 22:234251
Surrogates
Nitrobenzene-d5 (S)34 %05/05/17 13:22 4165-60-005/04/17 22:2323-110 1
2-Fluorobiphenyl (S)32 %05/05/17 13:22 321-60-805/04/17 22:2330-110 1
Terphenyl-d14 (S)32 %05/05/17 13:22 1718-51-005/04/17 22:2328-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-1 Lab ID:92338971001 Collected:05/02/17 09:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
Phenol-d6 (S)31 %05/05/17 13:22 13127-88-305/04/17 22:2322-110 1
2-Fluorophenol (S)32 %05/05/17 13:22 367-12-405/04/17 22:2313-110 1
2,4,6-Tribromophenol (S)27 %05/05/17 13:22 118-79-605/04/17 22:2327-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 05/03/17 17:26 67-64-11271
Benzene ND ug/kg 05/03/17 17:26 71-43-26.4 1
Bromobenzene ND ug/kg 05/03/17 17:26 108-86-16.4 1
Bromochloromethane ND ug/kg 05/03/17 17:26 74-97-56.4 1
Bromodichloromethane ND ug/kg 05/03/17 17:26 75-27-46.4 1
Bromoform ND ug/kg 05/03/17 17:26 75-25-26.4 1
Bromomethane ND ug/kg 05/03/17 17:26 74-83-912.7 1
2-Butanone (MEK)ND ug/kg 05/03/17 17:26 78-93-31271
n-Butylbenzene ND ug/kg 05/03/17 17:26 104-51-86.4 1
sec-Butylbenzene ND ug/kg 05/03/17 17:26 135-98-86.4 1
tert-Butylbenzene ND ug/kg 05/03/17 17:26 98-06-66.4 1
Carbon tetrachloride ND ug/kg 05/03/17 17:26 56-23-56.4 1
Chlorobenzene ND ug/kg 05/03/17 17:26 108-90-76.4 1
Chloroethane ND ug/kg 05/03/17 17:26 75-00-312.7 1
Chloroform ND ug/kg 05/03/17 17:26 67-66-36.4 1
Chloromethane ND ug/kg 05/03/17 17:26 74-87-312.7 1
2-Chlorotoluene ND ug/kg 05/03/17 17:26 95-49-86.4 1
4-Chlorotoluene ND ug/kg 05/03/17 17:26 106-43-46.4 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/03/17 17:26 96-12-86.4 1
Dibromochloromethane ND ug/kg 05/03/17 17:26 124-48-16.4 1
1,2-Dibromoethane (EDB)ND ug/kg 05/03/17 17:26 106-93-46.4 1
Dibromomethane ND ug/kg 05/03/17 17:26 74-95-36.4 1
1,2-Dichlorobenzene ND ug/kg 05/03/17 17:26 95-50-16.4 1
1,3-Dichlorobenzene ND ug/kg 05/03/17 17:26 541-73-16.4 1
1,4-Dichlorobenzene ND ug/kg 05/03/17 17:26 106-46-76.4 1
Dichlorodifluoromethane ND ug/kg 05/03/17 17:26 75-71-812.7 1
1,1-Dichloroethane ND ug/kg 05/03/17 17:26 75-34-36.4 1
1,2-Dichloroethane ND ug/kg 05/03/17 17:26 107-06-26.4 1
1,1-Dichloroethene ND ug/kg 05/03/17 17:26 75-35-46.4 1
cis-1,2-Dichloroethene ND ug/kg 05/03/17 17:26 156-59-26.4 1
trans-1,2-Dichloroethene ND ug/kg 05/03/17 17:26 156-60-56.4 1
1,2-Dichloropropane ND ug/kg 05/03/17 17:26 78-87-56.4 1
1,3-Dichloropropane ND ug/kg 05/03/17 17:26 142-28-96.4 1
2,2-Dichloropropane ND ug/kg 05/03/17 17:26 594-20-76.4 1
1,1-Dichloropropene ND ug/kg 05/03/17 17:26 563-58-66.4 1
cis-1,3-Dichloropropene ND ug/kg 05/03/17 17:26 10061-01-56.4 1
trans-1,3-Dichloropropene ND ug/kg 05/03/17 17:26 10061-02-66.4 1
Diisopropyl ether ND ug/kg 05/03/17 17:26 108-20-36.4 1
Ethylbenzene ND ug/kg 05/03/17 17:26 100-41-46.4 1
Hexachloro-1,3-butadiene ND ug/kg 05/03/17 17:26 87-68-36.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-1 Lab ID:92338971001 Collected:05/02/17 09:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
2-Hexanone ND ug/kg 05/03/17 17:26 591-78-663.6 1
Isopropylbenzene (Cumene)ND ug/kg 05/03/17 17:26 98-82-86.4 1
p-Isopropyltoluene ND ug/kg 05/03/17 17:26 99-87-66.4 1
Methylene Chloride ND ug/kg 05/03/17 17:26 75-09-225.4 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/03/17 17:26 108-10-163.6 1
Methyl-tert-butyl ether ND ug/kg 05/03/17 17:26 1634-04-46.4 1
Naphthalene ND ug/kg 05/03/17 17:26 91-20-36.4 1
n-Propylbenzene ND ug/kg 05/03/17 17:26 103-65-16.4 1
Styrene ND ug/kg 05/03/17 17:26 100-42-56.4 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/03/17 17:26 630-20-66.4 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/03/17 17:26 79-34-56.4 1
Tetrachloroethene ND ug/kg 05/03/17 17:26 127-18-46.4 1
Toluene ND ug/kg 05/03/17 17:26 108-88-36.4 1
1,2,3-Trichlorobenzene ND ug/kg 05/03/17 17:26 87-61-66.4 1
1,2,4-Trichlorobenzene ND ug/kg 05/03/17 17:26 120-82-16.4 1
1,1,1-Trichloroethane ND ug/kg 05/03/17 17:26 71-55-66.4 1
1,1,2-Trichloroethane ND ug/kg 05/03/17 17:26 79-00-56.4 1
Trichloroethene ND ug/kg 05/03/17 17:26 79-01-66.4 1
Trichlorofluoromethane ND ug/kg 05/03/17 17:26 75-69-46.4 1
1,2,3-Trichloropropane ND ug/kg 05/03/17 17:26 96-18-46.4 1
1,2,4-Trimethylbenzene ND ug/kg 05/03/17 17:26 95-63-66.4 1
1,3,5-Trimethylbenzene ND ug/kg 05/03/17 17:26 108-67-86.4 1
Vinyl acetate ND ug/kg 05/03/17 17:26 108-05-463.6 1
Vinyl chloride ND ug/kg 05/03/17 17:26 75-01-412.7 1
Xylene (Total)ND ug/kg 05/03/17 17:26 1330-20-712.7 1
m&p-Xylene ND ug/kg 05/03/17 17:26 179601-23-112.7 1
o-Xylene ND ug/kg 05/03/17 17:26 95-47-66.4 1
Surrogates
Toluene-d8 (S)101 %05/03/17 17:26 2037-26-570-130 1
4-Bromofluorobenzene (S)98 %05/03/17 17:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)112 %05/03/17 17:26 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 22.3 %05/03/17 07:470.10 1
Analytical Method: EPA 7196 Preparation Method: EPA 7196 Modified7196 Chromium, Hexavalent
Chromium, Hexavalent ND mg/kg 05/10/17 02:31 18540-29-905/10/17 00:155.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-2 Lab ID:92338971002 Collected:05/02/17 09:25 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/17 23:23 7440-36-005/03/17 14:150.45 1
Arsenic 1.1 mg/kg 05/03/17 23:23 7440-38-205/03/17 14:150.89 1
Beryllium 0.23 mg/kg 05/03/17 23:23 7440-41-705/03/17 14:150.089 1
Cadmium ND mg/kg 05/03/17 23:23 7440-43-905/03/17 14:150.089 1
Chromium 23.1 mg/kg 05/03/17 23:23 7440-47-305/03/17 14:150.45 1
Copper 23.1 mg/kg 05/03/17 23:23 7440-50-805/03/17 14:150.45 1
Lead 13.2 mg/kg 05/03/17 23:23 7439-92-105/03/17 14:150.45 1
Manganese 331 mg/kg 05/03/17 23:23 7439-96-505/03/17 14:150.45 1
Nickel 6.0 mg/kg 05/03/17 23:23 7440-02-005/03/17 14:150.45 1
Selenium 1.5 mg/kg 05/03/17 23:23 7782-49-205/03/17 14:150.89 1
Silver ND mg/kg 05/03/17 23:23 7440-22-405/03/17 14:150.45 1
Thallium ND mg/kg 05/03/17 23:23 7440-28-005/03/17 14:150.89 1
Zinc 33.1 mg/kg 05/03/17 23:23 7440-66-605/03/17 14:150.89 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.028 mg/kg 05/04/17 17:38 7439-97-605/04/17 06:250.0024 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/17 13:51 83-32-905/04/17 22:234171
Acenaphthylene ND ug/kg 05/05/17 13:51 208-96-805/04/17 22:234171
Aniline ND ug/kg 05/05/17 13:51 62-53-305/04/17 22:234171
Anthracene ND ug/kg 05/05/17 13:51 120-12-705/04/17 22:234171
Benzo(a)anthracene ND ug/kg 05/05/17 13:51 56-55-305/04/17 22:234171
Benzo(a)pyrene ND ug/kg 05/05/17 13:51 50-32-805/04/17 22:234171
Benzo(b)fluoranthene ND ug/kg 05/05/17 13:51 205-99-205/04/17 22:234171
Benzo(g,h,i)perylene ND ug/kg 05/05/17 13:51 191-24-205/04/17 22:234171
Benzo(k)fluoranthene ND ug/kg 05/05/17 13:51 207-08-905/04/17 22:234171
Benzoic Acid ND ug/kg 05/05/17 13:51 65-85-005/04/17 22:2320901
Benzyl alcohol ND ug/kg 05/05/17 13:51 100-51-605/04/17 22:238351
4-Bromophenylphenyl ether ND ug/kg 05/05/17 13:51 101-55-305/04/17 22:234171
Butylbenzylphthalate ND ug/kg 05/05/17 13:51 85-68-705/04/17 22:234171
4-Chloro-3-methylphenol ND ug/kg 05/05/17 13:51 59-50-705/04/17 22:238351
4-Chloroaniline ND ug/kg 05/05/17 13:51 106-47-805/04/17 22:2320901
bis(2-Chloroethoxy)methane ND ug/kg 05/05/17 13:51 111-91-105/04/17 22:234171
bis(2-Chloroethyl) ether ND ug/kg 05/05/17 13:51 111-44-405/04/17 22:234171
2-Chloronaphthalene ND ug/kg 05/05/17 13:51 91-58-705/04/17 22:234171
2-Chlorophenol ND ug/kg 05/05/17 13:51 95-57-805/04/17 22:234171
4-Chlorophenylphenyl ether ND ug/kg 05/05/17 13:51 7005-72-305/04/17 22:234171
Chrysene ND ug/kg 05/05/17 13:51 218-01-905/04/17 22:234171
Dibenz(a,h)anthracene ND ug/kg 05/05/17 13:51 53-70-305/04/17 22:234171
Dibenzofuran ND ug/kg 05/05/17 13:51 132-64-905/04/17 22:234171
1,2-Dichlorobenzene ND ug/kg 05/05/17 13:51 95-50-105/04/17 22:234171
1,3-Dichlorobenzene ND ug/kg 05/05/17 13:51 541-73-1 L205/04/17 22:234171
1,4-Dichlorobenzene ND ug/kg 05/05/17 13:51 106-46-705/04/17 22:234171
3,3'-Dichlorobenzidine ND ug/kg 05/05/17 13:51 91-94-105/04/17 22:2320901
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-2 Lab ID:92338971002 Collected:05/02/17 09:25 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 05/05/17 13:51 120-83-205/04/17 22:234171
Diethylphthalate ND ug/kg 05/05/17 13:51 84-66-205/04/17 22:234171
2,4-Dimethylphenol ND ug/kg 05/05/17 13:51 105-67-905/04/17 22:234171
Dimethylphthalate ND ug/kg 05/05/17 13:51 131-11-305/04/17 22:234171
Di-n-butylphthalate ND ug/kg 05/05/17 13:51 84-74-205/04/17 22:234171
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/17 13:51 534-52-105/04/17 22:238351
2,4-Dinitrophenol ND ug/kg 05/05/17 13:51 51-28-505/04/17 22:2320901
2,4-Dinitrotoluene ND ug/kg 05/05/17 13:51 121-14-205/04/17 22:234171
2,6-Dinitrotoluene ND ug/kg 05/05/17 13:51 606-20-205/04/17 22:234171
Di-n-octylphthalate ND ug/kg 05/05/17 13:51 117-84-005/04/17 22:234171
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/17 13:51 117-81-705/04/17 22:234171
Fluoranthene ND ug/kg 05/05/17 13:51 206-44-005/04/17 22:234171
Fluorene ND ug/kg 05/05/17 13:51 86-73-705/04/17 22:234171
Hexachloro-1,3-butadiene ND ug/kg 05/05/17 13:51 87-68-305/04/17 22:234171
Hexachlorobenzene ND ug/kg 05/05/17 13:51 118-74-105/04/17 22:234171
Hexachlorocyclopentadiene ND ug/kg 05/05/17 13:51 77-47-405/04/17 22:234171
Hexachloroethane ND ug/kg 05/05/17 13:51 67-72-105/04/17 22:234171
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/17 13:51 193-39-505/04/17 22:234171
Isophorone ND ug/kg 05/05/17 13:51 78-59-105/04/17 22:234171
1-Methylnaphthalene ND ug/kg 05/05/17 13:51 90-12-005/04/17 22:234171
2-Methylnaphthalene ND ug/kg 05/05/17 13:51 91-57-605/04/17 22:234171
2-Methylphenol(o-Cresol)ND ug/kg 05/05/17 13:51 95-48-705/04/17 22:234171
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/17 13:51 15831-10-405/04/17 22:234171
Naphthalene ND ug/kg 05/05/17 13:51 91-20-305/04/17 22:234171
2-Nitroaniline ND ug/kg 05/05/17 13:51 88-74-405/04/17 22:2320901
3-Nitroaniline ND ug/kg 05/05/17 13:51 99-09-205/04/17 22:2320901
4-Nitroaniline ND ug/kg 05/05/17 13:51 100-01-605/04/17 22:238351
Nitrobenzene ND ug/kg 05/05/17 13:51 98-95-305/04/17 22:234171
2-Nitrophenol ND ug/kg 05/05/17 13:51 88-75-505/04/17 22:234171
4-Nitrophenol ND ug/kg 05/05/17 13:51 100-02-705/04/17 22:2320901
N-Nitrosodimethylamine ND ug/kg 05/05/17 13:51 62-75-905/04/17 22:234171
N-Nitroso-di-n-propylamine ND ug/kg 05/05/17 13:51 621-64-705/04/17 22:234171
N-Nitrosodiphenylamine ND ug/kg 05/05/17 13:51 86-30-605/04/17 22:234171
2,2'-Oxybis(1-chloropropane)ND ug/kg 05/05/17 13:51 108-60-105/04/17 22:234171
Pentachlorophenol ND ug/kg 05/05/17 13:51 87-86-505/04/17 22:2320901
Phenanthrene ND ug/kg 05/05/17 13:51 85-01-805/04/17 22:234171
Phenol ND ug/kg 05/05/17 13:51 108-95-205/04/17 22:234171
Pyrene ND ug/kg 05/05/17 13:51 129-00-005/04/17 22:234171
Pyridine ND ug/kg 05/05/17 13:51 110-86-105/04/17 22:234171
1,2,4-Trichlorobenzene ND ug/kg 05/05/17 13:51 120-82-105/04/17 22:234171
2,4,5-Trichlorophenol ND ug/kg 05/05/17 13:51 95-95-405/04/17 22:234171
2,4,6-Trichlorophenol ND ug/kg 05/05/17 13:51 88-06-205/04/17 22:234171
Surrogates
Nitrobenzene-d5 (S)49 %05/05/17 13:51 4165-60-005/04/17 22:2323-110 1
2-Fluorobiphenyl (S)47 %05/05/17 13:51 321-60-805/04/17 22:2330-110 1
Terphenyl-d14 (S)64 %05/05/17 13:51 1718-51-005/04/17 22:2328-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-2 Lab ID:92338971002 Collected:05/02/17 09:25 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
Phenol-d6 (S)45 %05/05/17 13:51 13127-88-305/04/17 22:2322-110 1
2-Fluorophenol (S)42 %05/05/17 13:51 367-12-405/04/17 22:2313-110 1
2,4,6-Tribromophenol (S)54 %05/05/17 13:51 118-79-605/04/17 22:2327-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 05/03/17 17:46 67-64-11281
Benzene ND ug/kg 05/03/17 17:46 71-43-26.4 1
Bromobenzene ND ug/kg 05/03/17 17:46 108-86-16.4 1
Bromochloromethane ND ug/kg 05/03/17 17:46 74-97-56.4 1
Bromodichloromethane ND ug/kg 05/03/17 17:46 75-27-46.4 1
Bromoform ND ug/kg 05/03/17 17:46 75-25-26.4 1
Bromomethane ND ug/kg 05/03/17 17:46 74-83-912.8 1
2-Butanone (MEK)ND ug/kg 05/03/17 17:46 78-93-31281
n-Butylbenzene ND ug/kg 05/03/17 17:46 104-51-86.4 1
sec-Butylbenzene ND ug/kg 05/03/17 17:46 135-98-86.4 1
tert-Butylbenzene ND ug/kg 05/03/17 17:46 98-06-66.4 1
Carbon tetrachloride ND ug/kg 05/03/17 17:46 56-23-56.4 1
Chlorobenzene ND ug/kg 05/03/17 17:46 108-90-76.4 1
Chloroethane ND ug/kg 05/03/17 17:46 75-00-312.8 1
Chloroform ND ug/kg 05/03/17 17:46 67-66-36.4 1
Chloromethane ND ug/kg 05/03/17 17:46 74-87-312.8 1
2-Chlorotoluene ND ug/kg 05/03/17 17:46 95-49-86.4 1
4-Chlorotoluene ND ug/kg 05/03/17 17:46 106-43-46.4 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/03/17 17:46 96-12-86.4 1
Dibromochloromethane ND ug/kg 05/03/17 17:46 124-48-16.4 1
1,2-Dibromoethane (EDB)ND ug/kg 05/03/17 17:46 106-93-46.4 1
Dibromomethane ND ug/kg 05/03/17 17:46 74-95-36.4 1
1,2-Dichlorobenzene ND ug/kg 05/03/17 17:46 95-50-16.4 1
1,3-Dichlorobenzene ND ug/kg 05/03/17 17:46 541-73-16.4 1
1,4-Dichlorobenzene ND ug/kg 05/03/17 17:46 106-46-76.4 1
Dichlorodifluoromethane ND ug/kg 05/03/17 17:46 75-71-812.8 1
1,1-Dichloroethane ND ug/kg 05/03/17 17:46 75-34-36.4 1
1,2-Dichloroethane ND ug/kg 05/03/17 17:46 107-06-26.4 1
1,1-Dichloroethene ND ug/kg 05/03/17 17:46 75-35-46.4 1
cis-1,2-Dichloroethene ND ug/kg 05/03/17 17:46 156-59-26.4 1
trans-1,2-Dichloroethene ND ug/kg 05/03/17 17:46 156-60-56.4 1
1,2-Dichloropropane ND ug/kg 05/03/17 17:46 78-87-56.4 1
1,3-Dichloropropane ND ug/kg 05/03/17 17:46 142-28-96.4 1
2,2-Dichloropropane ND ug/kg 05/03/17 17:46 594-20-76.4 1
1,1-Dichloropropene ND ug/kg 05/03/17 17:46 563-58-66.4 1
cis-1,3-Dichloropropene ND ug/kg 05/03/17 17:46 10061-01-56.4 1
trans-1,3-Dichloropropene ND ug/kg 05/03/17 17:46 10061-02-66.4 1
Diisopropyl ether ND ug/kg 05/03/17 17:46 108-20-36.4 1
Ethylbenzene ND ug/kg 05/03/17 17:46 100-41-46.4 1
Hexachloro-1,3-butadiene ND ug/kg 05/03/17 17:46 87-68-36.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-2 Lab ID:92338971002 Collected:05/02/17 09:25 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
2-Hexanone ND ug/kg 05/03/17 17:46 591-78-664.1 1
Isopropylbenzene (Cumene)ND ug/kg 05/03/17 17:46 98-82-86.4 1
p-Isopropyltoluene ND ug/kg 05/03/17 17:46 99-87-66.4 1
Methylene Chloride ND ug/kg 05/03/17 17:46 75-09-225.7 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/03/17 17:46 108-10-164.1 1
Methyl-tert-butyl ether ND ug/kg 05/03/17 17:46 1634-04-46.4 1
Naphthalene ND ug/kg 05/03/17 17:46 91-20-36.4 1
n-Propylbenzene ND ug/kg 05/03/17 17:46 103-65-16.4 1
Styrene ND ug/kg 05/03/17 17:46 100-42-56.4 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/03/17 17:46 630-20-66.4 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/03/17 17:46 79-34-56.4 1
Tetrachloroethene ND ug/kg 05/03/17 17:46 127-18-46.4 1
Toluene ND ug/kg 05/03/17 17:46 108-88-36.4 1
1,2,3-Trichlorobenzene ND ug/kg 05/03/17 17:46 87-61-66.4 1
1,2,4-Trichlorobenzene ND ug/kg 05/03/17 17:46 120-82-16.4 1
1,1,1-Trichloroethane ND ug/kg 05/03/17 17:46 71-55-66.4 1
1,1,2-Trichloroethane ND ug/kg 05/03/17 17:46 79-00-56.4 1
Trichloroethene ND ug/kg 05/03/17 17:46 79-01-66.4 1
Trichlorofluoromethane ND ug/kg 05/03/17 17:46 75-69-46.4 1
1,2,3-Trichloropropane ND ug/kg 05/03/17 17:46 96-18-46.4 1
1,2,4-Trimethylbenzene ND ug/kg 05/03/17 17:46 95-63-66.4 1
1,3,5-Trimethylbenzene ND ug/kg 05/03/17 17:46 108-67-86.4 1
Vinyl acetate ND ug/kg 05/03/17 17:46 108-05-464.1 1
Vinyl chloride ND ug/kg 05/03/17 17:46 75-01-412.8 1
Xylene (Total)ND ug/kg 05/03/17 17:46 1330-20-712.8 1
m&p-Xylene ND ug/kg 05/03/17 17:46 179601-23-112.8 1
o-Xylene ND ug/kg 05/03/17 17:46 95-47-66.4 1
Surrogates
Toluene-d8 (S)100 %05/03/17 17:46 2037-26-570-130 1
4-Bromofluorobenzene (S)96 %05/03/17 17:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)116 %05/03/17 17:46 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 20.9 %05/03/17 07:470.10 1
Analytical Method: EPA 7196 Preparation Method: EPA 7196 Modified7196 Chromium, Hexavalent
Chromium, Hexavalent ND mg/kg 05/10/17 02:31 18540-29-905/10/17 00:156.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-3 Lab ID:92338971003 Collected:05/02/17 09:40 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/17 23:26 7440-36-005/03/17 14:150.60 1
Arsenic 1.8 mg/kg 05/03/17 23:26 7440-38-205/03/17 14:151.2 1
Beryllium 0.36 mg/kg 05/03/17 23:26 7440-41-705/03/17 14:150.12 1
Cadmium ND mg/kg 05/03/17 23:26 7440-43-905/03/17 14:150.12 1
Chromium 40.6 mg/kg 05/03/17 23:26 7440-47-305/03/17 14:150.60 1
Copper 50.6 mg/kg 05/03/17 23:26 7440-50-805/03/17 14:150.60 1
Lead 42.4 mg/kg 05/03/17 23:26 7439-92-105/03/17 14:150.60 1
Manganese 723 mg/kg 05/03/17 23:26 7439-96-505/03/17 14:150.60 1
Nickel 15.0 mg/kg 05/03/17 23:26 7440-02-005/03/17 14:150.60 1
Selenium 1.9 mg/kg 05/03/17 23:26 7782-49-205/03/17 14:151.2 1
Silver ND mg/kg 05/03/17 23:26 7440-22-405/03/17 14:150.60 1
Thallium ND mg/kg 05/03/17 23:26 7440-28-005/03/17 14:151.2 1
Zinc 114 mg/kg 05/03/17 23:26 7440-66-605/03/17 14:151.2 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.036 mg/kg 05/04/17 17:40 7439-97-605/04/17 06:250.0055 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/17 14:20 83-32-905/04/17 22:234241
Acenaphthylene ND ug/kg 05/05/17 14:20 208-96-805/04/17 22:234241
Aniline ND ug/kg 05/05/17 14:20 62-53-305/04/17 22:234241
Anthracene ND ug/kg 05/05/17 14:20 120-12-705/04/17 22:234241
Benzo(a)anthracene ND ug/kg 05/05/17 14:20 56-55-305/04/17 22:234241
Benzo(a)pyrene ND ug/kg 05/05/17 14:20 50-32-805/04/17 22:234241
Benzo(b)fluoranthene ND ug/kg 05/05/17 14:20 205-99-205/04/17 22:234241
Benzo(g,h,i)perylene ND ug/kg 05/05/17 14:20 191-24-205/04/17 22:234241
Benzo(k)fluoranthene ND ug/kg 05/05/17 14:20 207-08-905/04/17 22:234241
Benzoic Acid ND ug/kg 05/05/17 14:20 65-85-005/04/17 22:2321201
Benzyl alcohol ND ug/kg 05/05/17 14:20 100-51-605/04/17 22:238481
4-Bromophenylphenyl ether ND ug/kg 05/05/17 14:20 101-55-305/04/17 22:234241
Butylbenzylphthalate ND ug/kg 05/05/17 14:20 85-68-705/04/17 22:234241
4-Chloro-3-methylphenol ND ug/kg 05/05/17 14:20 59-50-705/04/17 22:238481
4-Chloroaniline ND ug/kg 05/05/17 14:20 106-47-805/04/17 22:2321201
bis(2-Chloroethoxy)methane ND ug/kg 05/05/17 14:20 111-91-105/04/17 22:234241
bis(2-Chloroethyl) ether ND ug/kg 05/05/17 14:20 111-44-405/04/17 22:234241
2-Chloronaphthalene ND ug/kg 05/05/17 14:20 91-58-705/04/17 22:234241
2-Chlorophenol ND ug/kg 05/05/17 14:20 95-57-805/04/17 22:234241
4-Chlorophenylphenyl ether ND ug/kg 05/05/17 14:20 7005-72-305/04/17 22:234241
Chrysene ND ug/kg 05/05/17 14:20 218-01-905/04/17 22:234241
Dibenz(a,h)anthracene ND ug/kg 05/05/17 14:20 53-70-305/04/17 22:234241
Dibenzofuran ND ug/kg 05/05/17 14:20 132-64-905/04/17 22:234241
1,2-Dichlorobenzene ND ug/kg 05/05/17 14:20 95-50-105/04/17 22:234241
1,3-Dichlorobenzene ND ug/kg 05/05/17 14:20 541-73-1 L205/04/17 22:234241
1,4-Dichlorobenzene ND ug/kg 05/05/17 14:20 106-46-705/04/17 22:234241
3,3'-Dichlorobenzidine ND ug/kg 05/05/17 14:20 91-94-105/04/17 22:2321201
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-3 Lab ID:92338971003 Collected:05/02/17 09:40 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 05/05/17 14:20 120-83-205/04/17 22:234241
Diethylphthalate ND ug/kg 05/05/17 14:20 84-66-205/04/17 22:234241
2,4-Dimethylphenol ND ug/kg 05/05/17 14:20 105-67-905/04/17 22:234241
Dimethylphthalate ND ug/kg 05/05/17 14:20 131-11-305/04/17 22:234241
Di-n-butylphthalate ND ug/kg 05/05/17 14:20 84-74-205/04/17 22:234241
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/17 14:20 534-52-105/04/17 22:238481
2,4-Dinitrophenol ND ug/kg 05/05/17 14:20 51-28-505/04/17 22:2321201
2,4-Dinitrotoluene ND ug/kg 05/05/17 14:20 121-14-205/04/17 22:234241
2,6-Dinitrotoluene ND ug/kg 05/05/17 14:20 606-20-205/04/17 22:234241
Di-n-octylphthalate ND ug/kg 05/05/17 14:20 117-84-005/04/17 22:234241
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/17 14:20 117-81-705/04/17 22:234241
Fluoranthene ND ug/kg 05/05/17 14:20 206-44-005/04/17 22:234241
Fluorene ND ug/kg 05/05/17 14:20 86-73-705/04/17 22:234241
Hexachloro-1,3-butadiene ND ug/kg 05/05/17 14:20 87-68-305/04/17 22:234241
Hexachlorobenzene ND ug/kg 05/05/17 14:20 118-74-105/04/17 22:234241
Hexachlorocyclopentadiene ND ug/kg 05/05/17 14:20 77-47-405/04/17 22:234241
Hexachloroethane ND ug/kg 05/05/17 14:20 67-72-105/04/17 22:234241
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/17 14:20 193-39-505/04/17 22:234241
Isophorone ND ug/kg 05/05/17 14:20 78-59-105/04/17 22:234241
1-Methylnaphthalene ND ug/kg 05/05/17 14:20 90-12-005/04/17 22:234241
2-Methylnaphthalene ND ug/kg 05/05/17 14:20 91-57-605/04/17 22:234241
2-Methylphenol(o-Cresol)ND ug/kg 05/05/17 14:20 95-48-705/04/17 22:234241
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/17 14:20 15831-10-405/04/17 22:234241
Naphthalene ND ug/kg 05/05/17 14:20 91-20-305/04/17 22:234241
2-Nitroaniline ND ug/kg 05/05/17 14:20 88-74-405/04/17 22:2321201
3-Nitroaniline ND ug/kg 05/05/17 14:20 99-09-205/04/17 22:2321201
4-Nitroaniline ND ug/kg 05/05/17 14:20 100-01-605/04/17 22:238481
Nitrobenzene ND ug/kg 05/05/17 14:20 98-95-305/04/17 22:234241
2-Nitrophenol ND ug/kg 05/05/17 14:20 88-75-505/04/17 22:234241
4-Nitrophenol ND ug/kg 05/05/17 14:20 100-02-705/04/17 22:2321201
N-Nitrosodimethylamine ND ug/kg 05/05/17 14:20 62-75-905/04/17 22:234241
N-Nitroso-di-n-propylamine ND ug/kg 05/05/17 14:20 621-64-705/04/17 22:234241
N-Nitrosodiphenylamine ND ug/kg 05/05/17 14:20 86-30-605/04/17 22:234241
2,2'-Oxybis(1-chloropropane)ND ug/kg 05/05/17 14:20 108-60-105/04/17 22:234241
Pentachlorophenol ND ug/kg 05/05/17 14:20 87-86-505/04/17 22:2321201
Phenanthrene ND ug/kg 05/05/17 14:20 85-01-805/04/17 22:234241
Phenol ND ug/kg 05/05/17 14:20 108-95-205/04/17 22:234241
Pyrene ND ug/kg 05/05/17 14:20 129-00-005/04/17 22:234241
Pyridine ND ug/kg 05/05/17 14:20 110-86-105/04/17 22:234241
1,2,4-Trichlorobenzene ND ug/kg 05/05/17 14:20 120-82-105/04/17 22:234241
2,4,5-Trichlorophenol ND ug/kg 05/05/17 14:20 95-95-405/04/17 22:234241
2,4,6-Trichlorophenol ND ug/kg 05/05/17 14:20 88-06-205/04/17 22:234241
Surrogates
Nitrobenzene-d5 (S)31 %05/05/17 14:20 4165-60-005/04/17 22:2323-110 1
2-Fluorobiphenyl (S)30 %05/05/17 14:20 321-60-805/04/17 22:2330-110 1
Terphenyl-d14 (S)35 %05/05/17 14:20 1718-51-005/04/17 22:2328-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-3 Lab ID:92338971003 Collected:05/02/17 09:40 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
Phenol-d6 (S)30 %05/05/17 14:20 13127-88-305/04/17 22:2322-110 1
2-Fluorophenol (S)27 %05/05/17 14:20 367-12-405/04/17 22:2313-110 1
2,4,6-Tribromophenol (S)36 %05/05/17 14:20 118-79-605/04/17 22:2327-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 05/03/17 18:06 67-64-11121
Benzene ND ug/kg 05/03/17 18:06 71-43-25.6 1
Bromobenzene ND ug/kg 05/03/17 18:06 108-86-15.6 1
Bromochloromethane ND ug/kg 05/03/17 18:06 74-97-55.6 1
Bromodichloromethane ND ug/kg 05/03/17 18:06 75-27-45.6 1
Bromoform ND ug/kg 05/03/17 18:06 75-25-25.6 1
Bromomethane ND ug/kg 05/03/17 18:06 74-83-911.2 1
2-Butanone (MEK)ND ug/kg 05/03/17 18:06 78-93-31121
n-Butylbenzene ND ug/kg 05/03/17 18:06 104-51-85.6 1
sec-Butylbenzene ND ug/kg 05/03/17 18:06 135-98-85.6 1
tert-Butylbenzene ND ug/kg 05/03/17 18:06 98-06-65.6 1
Carbon tetrachloride ND ug/kg 05/03/17 18:06 56-23-55.6 1
Chlorobenzene ND ug/kg 05/03/17 18:06 108-90-75.6 1
Chloroethane ND ug/kg 05/03/17 18:06 75-00-311.2 1
Chloroform ND ug/kg 05/03/17 18:06 67-66-35.6 1
Chloromethane ND ug/kg 05/03/17 18:06 74-87-311.2 1
2-Chlorotoluene ND ug/kg 05/03/17 18:06 95-49-85.6 1
4-Chlorotoluene ND ug/kg 05/03/17 18:06 106-43-45.6 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/03/17 18:06 96-12-85.6 1
Dibromochloromethane ND ug/kg 05/03/17 18:06 124-48-15.6 1
1,2-Dibromoethane (EDB)ND ug/kg 05/03/17 18:06 106-93-45.6 1
Dibromomethane ND ug/kg 05/03/17 18:06 74-95-35.6 1
1,2-Dichlorobenzene ND ug/kg 05/03/17 18:06 95-50-15.6 1
1,3-Dichlorobenzene ND ug/kg 05/03/17 18:06 541-73-15.6 1
1,4-Dichlorobenzene ND ug/kg 05/03/17 18:06 106-46-75.6 1
Dichlorodifluoromethane ND ug/kg 05/03/17 18:06 75-71-811.2 1
1,1-Dichloroethane ND ug/kg 05/03/17 18:06 75-34-35.6 1
1,2-Dichloroethane ND ug/kg 05/03/17 18:06 107-06-25.6 1
1,1-Dichloroethene ND ug/kg 05/03/17 18:06 75-35-45.6 1
cis-1,2-Dichloroethene ND ug/kg 05/03/17 18:06 156-59-25.6 1
trans-1,2-Dichloroethene ND ug/kg 05/03/17 18:06 156-60-55.6 1
1,2-Dichloropropane ND ug/kg 05/03/17 18:06 78-87-55.6 1
1,3-Dichloropropane ND ug/kg 05/03/17 18:06 142-28-95.6 1
2,2-Dichloropropane ND ug/kg 05/03/17 18:06 594-20-75.6 1
1,1-Dichloropropene ND ug/kg 05/03/17 18:06 563-58-65.6 1
cis-1,3-Dichloropropene ND ug/kg 05/03/17 18:06 10061-01-55.6 1
trans-1,3-Dichloropropene ND ug/kg 05/03/17 18:06 10061-02-65.6 1
Diisopropyl ether ND ug/kg 05/03/17 18:06 108-20-35.6 1
Ethylbenzene ND ug/kg 05/03/17 18:06 100-41-45.6 1
Hexachloro-1,3-butadiene ND ug/kg 05/03/17 18:06 87-68-35.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-3 Lab ID:92338971003 Collected:05/02/17 09:40 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
2-Hexanone ND ug/kg 05/03/17 18:06 591-78-655.8 1
Isopropylbenzene (Cumene)ND ug/kg 05/03/17 18:06 98-82-85.6 1
p-Isopropyltoluene ND ug/kg 05/03/17 18:06 99-87-65.6 1
Methylene Chloride ND ug/kg 05/03/17 18:06 75-09-222.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/03/17 18:06 108-10-155.8 1
Methyl-tert-butyl ether ND ug/kg 05/03/17 18:06 1634-04-45.6 1
Naphthalene ND ug/kg 05/03/17 18:06 91-20-35.6 1
n-Propylbenzene ND ug/kg 05/03/17 18:06 103-65-15.6 1
Styrene ND ug/kg 05/03/17 18:06 100-42-55.6 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/03/17 18:06 630-20-65.6 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/03/17 18:06 79-34-55.6 1
Tetrachloroethene ND ug/kg 05/03/17 18:06 127-18-45.6 1
Toluene ND ug/kg 05/03/17 18:06 108-88-35.6 1
1,2,3-Trichlorobenzene ND ug/kg 05/03/17 18:06 87-61-65.6 1
1,2,4-Trichlorobenzene ND ug/kg 05/03/17 18:06 120-82-15.6 1
1,1,1-Trichloroethane ND ug/kg 05/03/17 18:06 71-55-65.6 1
1,1,2-Trichloroethane ND ug/kg 05/03/17 18:06 79-00-55.6 1
Trichloroethene ND ug/kg 05/03/17 18:06 79-01-65.6 1
Trichlorofluoromethane ND ug/kg 05/03/17 18:06 75-69-45.6 1
1,2,3-Trichloropropane ND ug/kg 05/03/17 18:06 96-18-45.6 1
1,2,4-Trimethylbenzene ND ug/kg 05/03/17 18:06 95-63-65.6 1
1,3,5-Trimethylbenzene ND ug/kg 05/03/17 18:06 108-67-85.6 1
Vinyl acetate ND ug/kg 05/03/17 18:06 108-05-455.8 1
Vinyl chloride ND ug/kg 05/03/17 18:06 75-01-411.2 1
Xylene (Total)ND ug/kg 05/03/17 18:06 1330-20-711.2 1
m&p-Xylene ND ug/kg 05/03/17 18:06 179601-23-111.2 1
o-Xylene ND ug/kg 05/03/17 18:06 95-47-65.6 1
Surrogates
Toluene-d8 (S)100 %05/03/17 18:06 2037-26-570-130 1
4-Bromofluorobenzene (S)98 %05/03/17 18:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)113 %05/03/17 18:06 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 22.2 %05/03/17 07:470.10 1
Analytical Method: EPA 7196 Preparation Method: EPA 7196 Modified7196 Chromium, Hexavalent
Chromium, Hexavalent ND mg/kg 05/10/17 02:31 18540-29-905/10/17 00:155.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-4 Lab ID:92338971004 Collected:05/02/17 09:55 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/17 23:29 7440-36-005/03/17 14:150.50 1
Arsenic 1.2 mg/kg 05/03/17 23:29 7440-38-205/03/17 14:151.0 1
Beryllium 0.40 mg/kg 05/03/17 23:29 7440-41-705/03/17 14:150.10 1
Cadmium ND mg/kg 05/03/17 23:29 7440-43-905/03/17 14:150.10 1
Chromium 7.0 mg/kg 05/03/17 23:29 7440-47-305/03/17 14:150.50 1
Copper 22.7 mg/kg 05/03/17 23:29 7440-50-805/03/17 14:150.50 1
Lead 5.7 mg/kg 05/03/17 23:29 7439-92-105/03/17 14:150.50 1
Manganese 327 mg/kg 05/03/17 23:29 7439-96-505/03/17 14:150.50 1
Nickel 2.5 mg/kg 05/03/17 23:29 7440-02-005/03/17 14:150.50 1
Selenium 1.0 mg/kg 05/03/17 23:29 7782-49-205/03/17 14:151.0 1
Silver ND mg/kg 05/03/17 23:29 7440-22-405/03/17 14:150.50 1
Thallium ND mg/kg 05/03/17 23:29 7440-28-005/03/17 14:151.0 1
Zinc 30.9 mg/kg 05/03/17 23:29 7440-66-605/03/17 14:151.0 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.015 mg/kg 05/04/17 17:42 7439-97-605/04/17 06:250.0043 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/17 14:49 83-32-905/04/17 22:234031
Acenaphthylene ND ug/kg 05/05/17 14:49 208-96-805/04/17 22:234031
Aniline ND ug/kg 05/05/17 14:49 62-53-305/04/17 22:234031
Anthracene ND ug/kg 05/05/17 14:49 120-12-705/04/17 22:234031
Benzo(a)anthracene ND ug/kg 05/05/17 14:49 56-55-305/04/17 22:234031
Benzo(a)pyrene ND ug/kg 05/05/17 14:49 50-32-805/04/17 22:234031
Benzo(b)fluoranthene ND ug/kg 05/05/17 14:49 205-99-205/04/17 22:234031
Benzo(g,h,i)perylene ND ug/kg 05/05/17 14:49 191-24-205/04/17 22:234031
Benzo(k)fluoranthene ND ug/kg 05/05/17 14:49 207-08-905/04/17 22:234031
Benzoic Acid ND ug/kg 05/05/17 14:49 65-85-005/04/17 22:2320201
Benzyl alcohol ND ug/kg 05/05/17 14:49 100-51-605/04/17 22:238071
4-Bromophenylphenyl ether ND ug/kg 05/05/17 14:49 101-55-305/04/17 22:234031
Butylbenzylphthalate ND ug/kg 05/05/17 14:49 85-68-705/04/17 22:234031
4-Chloro-3-methylphenol ND ug/kg 05/05/17 14:49 59-50-705/04/17 22:238071
4-Chloroaniline ND ug/kg 05/05/17 14:49 106-47-805/04/17 22:2320201
bis(2-Chloroethoxy)methane ND ug/kg 05/05/17 14:49 111-91-105/04/17 22:234031
bis(2-Chloroethyl) ether ND ug/kg 05/05/17 14:49 111-44-405/04/17 22:234031
2-Chloronaphthalene ND ug/kg 05/05/17 14:49 91-58-705/04/17 22:234031
2-Chlorophenol ND ug/kg 05/05/17 14:49 95-57-805/04/17 22:234031
4-Chlorophenylphenyl ether ND ug/kg 05/05/17 14:49 7005-72-305/04/17 22:234031
Chrysene ND ug/kg 05/05/17 14:49 218-01-905/04/17 22:234031
Dibenz(a,h)anthracene ND ug/kg 05/05/17 14:49 53-70-305/04/17 22:234031
Dibenzofuran ND ug/kg 05/05/17 14:49 132-64-905/04/17 22:234031
1,2-Dichlorobenzene ND ug/kg 05/05/17 14:49 95-50-105/04/17 22:234031
1,3-Dichlorobenzene ND ug/kg 05/05/17 14:49 541-73-1 L205/04/17 22:234031
1,4-Dichlorobenzene ND ug/kg 05/05/17 14:49 106-46-705/04/17 22:234031
3,3'-Dichlorobenzidine ND ug/kg 05/05/17 14:49 91-94-105/04/17 22:2320201
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-4 Lab ID:92338971004 Collected:05/02/17 09:55 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 05/05/17 14:49 120-83-205/04/17 22:234031
Diethylphthalate ND ug/kg 05/05/17 14:49 84-66-205/04/17 22:234031
2,4-Dimethylphenol ND ug/kg 05/05/17 14:49 105-67-905/04/17 22:234031
Dimethylphthalate ND ug/kg 05/05/17 14:49 131-11-305/04/17 22:234031
Di-n-butylphthalate ND ug/kg 05/05/17 14:49 84-74-205/04/17 22:234031
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/17 14:49 534-52-105/04/17 22:238071
2,4-Dinitrophenol ND ug/kg 05/05/17 14:49 51-28-505/04/17 22:2320201
2,4-Dinitrotoluene ND ug/kg 05/05/17 14:49 121-14-205/04/17 22:234031
2,6-Dinitrotoluene ND ug/kg 05/05/17 14:49 606-20-205/04/17 22:234031
Di-n-octylphthalate ND ug/kg 05/05/17 14:49 117-84-005/04/17 22:234031
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/17 14:49 117-81-705/04/17 22:234031
Fluoranthene ND ug/kg 05/05/17 14:49 206-44-005/04/17 22:234031
Fluorene ND ug/kg 05/05/17 14:49 86-73-705/04/17 22:234031
Hexachloro-1,3-butadiene ND ug/kg 05/05/17 14:49 87-68-305/04/17 22:234031
Hexachlorobenzene ND ug/kg 05/05/17 14:49 118-74-105/04/17 22:234031
Hexachlorocyclopentadiene ND ug/kg 05/05/17 14:49 77-47-405/04/17 22:234031
Hexachloroethane ND ug/kg 05/05/17 14:49 67-72-105/04/17 22:234031
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/17 14:49 193-39-505/04/17 22:234031
Isophorone ND ug/kg 05/05/17 14:49 78-59-105/04/17 22:234031
1-Methylnaphthalene ND ug/kg 05/05/17 14:49 90-12-005/04/17 22:234031
2-Methylnaphthalene ND ug/kg 05/05/17 14:49 91-57-605/04/17 22:234031
2-Methylphenol(o-Cresol)ND ug/kg 05/05/17 14:49 95-48-705/04/17 22:234031
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/17 14:49 15831-10-405/04/17 22:234031
Naphthalene ND ug/kg 05/05/17 14:49 91-20-305/04/17 22:234031
2-Nitroaniline ND ug/kg 05/05/17 14:49 88-74-405/04/17 22:2320201
3-Nitroaniline ND ug/kg 05/05/17 14:49 99-09-205/04/17 22:2320201
4-Nitroaniline ND ug/kg 05/05/17 14:49 100-01-605/04/17 22:238071
Nitrobenzene ND ug/kg 05/05/17 14:49 98-95-305/04/17 22:234031
2-Nitrophenol ND ug/kg 05/05/17 14:49 88-75-505/04/17 22:234031
4-Nitrophenol ND ug/kg 05/05/17 14:49 100-02-705/04/17 22:2320201
N-Nitrosodimethylamine ND ug/kg 05/05/17 14:49 62-75-905/04/17 22:234031
N-Nitroso-di-n-propylamine ND ug/kg 05/05/17 14:49 621-64-705/04/17 22:234031
N-Nitrosodiphenylamine ND ug/kg 05/05/17 14:49 86-30-605/04/17 22:234031
2,2'-Oxybis(1-chloropropane)ND ug/kg 05/05/17 14:49 108-60-105/04/17 22:234031
Pentachlorophenol ND ug/kg 05/05/17 14:49 87-86-505/04/17 22:2320201
Phenanthrene ND ug/kg 05/05/17 14:49 85-01-805/04/17 22:234031
Phenol ND ug/kg 05/05/17 14:49 108-95-205/04/17 22:234031
Pyrene ND ug/kg 05/05/17 14:49 129-00-005/04/17 22:234031
Pyridine ND ug/kg 05/05/17 14:49 110-86-105/04/17 22:234031
1,2,4-Trichlorobenzene ND ug/kg 05/05/17 14:49 120-82-105/04/17 22:234031
2,4,5-Trichlorophenol ND ug/kg 05/05/17 14:49 95-95-405/04/17 22:234031
2,4,6-Trichlorophenol ND ug/kg 05/05/17 14:49 88-06-205/04/17 22:234031
Surrogates
Nitrobenzene-d5 (S)37 %05/05/17 14:49 4165-60-005/04/17 22:2323-110 1
2-Fluorobiphenyl (S)39 %05/05/17 14:49 321-60-805/04/17 22:2330-110 1
Terphenyl-d14 (S)55 %05/05/17 14:49 1718-51-005/04/17 22:2328-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-4 Lab ID:92338971004 Collected:05/02/17 09:55 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
Phenol-d6 (S)35 %05/05/17 14:49 13127-88-305/04/17 22:2322-110 1
2-Fluorophenol (S)29 %05/05/17 14:49 367-12-405/04/17 22:2313-110 1
2,4,6-Tribromophenol (S)43 %05/05/17 14:49 118-79-605/04/17 22:2327-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 05/03/17 18:26 67-64-11471
Benzene ND ug/kg 05/03/17 18:26 71-43-27.3 1
Bromobenzene ND ug/kg 05/03/17 18:26 108-86-17.3 1
Bromochloromethane ND ug/kg 05/03/17 18:26 74-97-57.3 1
Bromodichloromethane ND ug/kg 05/03/17 18:26 75-27-47.3 1
Bromoform ND ug/kg 05/03/17 18:26 75-25-27.3 1
Bromomethane ND ug/kg 05/03/17 18:26 74-83-914.7 1
2-Butanone (MEK)ND ug/kg 05/03/17 18:26 78-93-31471
n-Butylbenzene ND ug/kg 05/03/17 18:26 104-51-87.3 1
sec-Butylbenzene ND ug/kg 05/03/17 18:26 135-98-87.3 1
tert-Butylbenzene ND ug/kg 05/03/17 18:26 98-06-67.3 1
Carbon tetrachloride ND ug/kg 05/03/17 18:26 56-23-57.3 1
Chlorobenzene ND ug/kg 05/03/17 18:26 108-90-77.3 1
Chloroethane ND ug/kg 05/03/17 18:26 75-00-314.7 1
Chloroform ND ug/kg 05/03/17 18:26 67-66-37.3 1
Chloromethane ND ug/kg 05/03/17 18:26 74-87-314.7 1
2-Chlorotoluene ND ug/kg 05/03/17 18:26 95-49-87.3 1
4-Chlorotoluene ND ug/kg 05/03/17 18:26 106-43-47.3 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/03/17 18:26 96-12-87.3 1
Dibromochloromethane ND ug/kg 05/03/17 18:26 124-48-17.3 1
1,2-Dibromoethane (EDB)ND ug/kg 05/03/17 18:26 106-93-47.3 1
Dibromomethane ND ug/kg 05/03/17 18:26 74-95-37.3 1
1,2-Dichlorobenzene ND ug/kg 05/03/17 18:26 95-50-17.3 1
1,3-Dichlorobenzene ND ug/kg 05/03/17 18:26 541-73-17.3 1
1,4-Dichlorobenzene ND ug/kg 05/03/17 18:26 106-46-77.3 1
Dichlorodifluoromethane ND ug/kg 05/03/17 18:26 75-71-814.7 1
1,1-Dichloroethane ND ug/kg 05/03/17 18:26 75-34-37.3 1
1,2-Dichloroethane ND ug/kg 05/03/17 18:26 107-06-27.3 1
1,1-Dichloroethene ND ug/kg 05/03/17 18:26 75-35-47.3 1
cis-1,2-Dichloroethene ND ug/kg 05/03/17 18:26 156-59-27.3 1
trans-1,2-Dichloroethene ND ug/kg 05/03/17 18:26 156-60-57.3 1
1,2-Dichloropropane ND ug/kg 05/03/17 18:26 78-87-57.3 1
1,3-Dichloropropane ND ug/kg 05/03/17 18:26 142-28-97.3 1
2,2-Dichloropropane ND ug/kg 05/03/17 18:26 594-20-77.3 1
1,1-Dichloropropene ND ug/kg 05/03/17 18:26 563-58-67.3 1
cis-1,3-Dichloropropene ND ug/kg 05/03/17 18:26 10061-01-57.3 1
trans-1,3-Dichloropropene ND ug/kg 05/03/17 18:26 10061-02-67.3 1
Diisopropyl ether ND ug/kg 05/03/17 18:26 108-20-37.3 1
Ethylbenzene ND ug/kg 05/03/17 18:26 100-41-47.3 1
Hexachloro-1,3-butadiene ND ug/kg 05/03/17 18:26 87-68-37.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-4 Lab ID:92338971004 Collected:05/02/17 09:55 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
2-Hexanone ND ug/kg 05/03/17 18:26 591-78-673.5 1
Isopropylbenzene (Cumene)ND ug/kg 05/03/17 18:26 98-82-87.3 1
p-Isopropyltoluene ND ug/kg 05/03/17 18:26 99-87-67.3 1
Methylene Chloride ND ug/kg 05/03/17 18:26 75-09-229.4 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/03/17 18:26 108-10-173.5 1
Methyl-tert-butyl ether ND ug/kg 05/03/17 18:26 1634-04-47.3 1
Naphthalene ND ug/kg 05/03/17 18:26 91-20-37.3 1
n-Propylbenzene ND ug/kg 05/03/17 18:26 103-65-17.3 1
Styrene ND ug/kg 05/03/17 18:26 100-42-57.3 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/03/17 18:26 630-20-67.3 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/03/17 18:26 79-34-57.3 1
Tetrachloroethene ND ug/kg 05/03/17 18:26 127-18-47.3 1
Toluene ND ug/kg 05/03/17 18:26 108-88-37.3 1
1,2,3-Trichlorobenzene ND ug/kg 05/03/17 18:26 87-61-67.3 1
1,2,4-Trichlorobenzene ND ug/kg 05/03/17 18:26 120-82-17.3 1
1,1,1-Trichloroethane ND ug/kg 05/03/17 18:26 71-55-67.3 1
1,1,2-Trichloroethane ND ug/kg 05/03/17 18:26 79-00-57.3 1
Trichloroethene ND ug/kg 05/03/17 18:26 79-01-67.3 1
Trichlorofluoromethane ND ug/kg 05/03/17 18:26 75-69-47.3 1
1,2,3-Trichloropropane ND ug/kg 05/03/17 18:26 96-18-47.3 1
1,2,4-Trimethylbenzene ND ug/kg 05/03/17 18:26 95-63-67.3 1
1,3,5-Trimethylbenzene ND ug/kg 05/03/17 18:26 108-67-87.3 1
Vinyl acetate ND ug/kg 05/03/17 18:26 108-05-473.5 1
Vinyl chloride ND ug/kg 05/03/17 18:26 75-01-414.7 1
Xylene (Total)ND ug/kg 05/03/17 18:26 1330-20-714.7 1
m&p-Xylene ND ug/kg 05/03/17 18:26 179601-23-114.7 1
o-Xylene ND ug/kg 05/03/17 18:26 95-47-67.3 1
Surrogates
Toluene-d8 (S)101 %05/03/17 18:26 2037-26-570-130 1
4-Bromofluorobenzene (S)93 %05/03/17 18:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)115 %05/03/17 18:26 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 18.2 %05/03/17 07:480.10 1
Analytical Method: EPA 7196 Preparation Method: EPA 7196 Modified7196 Chromium, Hexavalent
Chromium, Hexavalent ND mg/kg 05/10/17 02:31 18540-29-905/10/17 00:154.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-5 Lab ID:92338971005 Collected:05/02/17 10:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Antimony ND mg/kg 05/03/17 23:32 7440-36-005/03/17 14:150.53 1
Arsenic 1.1 mg/kg 05/03/17 23:32 7440-38-205/03/17 14:151.1 1
Beryllium 0.36 mg/kg 05/03/17 23:32 7440-41-705/03/17 14:150.11 1
Cadmium ND mg/kg 05/03/17 23:32 7440-43-905/03/17 14:150.11 1
Chromium 17.9 mg/kg 05/03/17 23:32 7440-47-305/03/17 14:150.53 1
Copper 32.1 mg/kg 05/03/17 23:32 7440-50-805/03/17 14:150.53 1
Lead 8.8 mg/kg 05/03/17 23:32 7439-92-105/03/17 14:150.53 1
Manganese 370 mg/kg 05/03/17 23:32 7439-96-505/03/17 14:150.53 1
Nickel 5.7 mg/kg 05/03/17 23:32 7440-02-005/03/17 14:150.53 1
Selenium 1.5 mg/kg 05/03/17 23:32 7782-49-205/03/17 14:151.1 1
Silver ND mg/kg 05/03/17 23:32 7440-22-405/03/17 14:150.53 1
Thallium ND mg/kg 05/03/17 23:32 7440-28-005/03/17 14:151.1 1
Zinc 36.0 mg/kg 05/03/17 23:32 7440-66-605/03/17 14:151.1 1
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.027 mg/kg 05/04/17 17:45 7439-97-605/04/17 06:250.0042 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 05/05/17 15:18 83-32-905/04/17 22:234251
Acenaphthylene ND ug/kg 05/05/17 15:18 208-96-805/04/17 22:234251
Aniline ND ug/kg 05/05/17 15:18 62-53-305/04/17 22:234251
Anthracene ND ug/kg 05/05/17 15:18 120-12-705/04/17 22:234251
Benzo(a)anthracene ND ug/kg 05/05/17 15:18 56-55-305/04/17 22:234251
Benzo(a)pyrene ND ug/kg 05/05/17 15:18 50-32-805/04/17 22:234251
Benzo(b)fluoranthene ND ug/kg 05/05/17 15:18 205-99-205/04/17 22:234251
Benzo(g,h,i)perylene ND ug/kg 05/05/17 15:18 191-24-205/04/17 22:234251
Benzo(k)fluoranthene ND ug/kg 05/05/17 15:18 207-08-905/04/17 22:234251
Benzoic Acid ND ug/kg 05/05/17 15:18 65-85-005/04/17 22:2321301
Benzyl alcohol ND ug/kg 05/05/17 15:18 100-51-605/04/17 22:238511
4-Bromophenylphenyl ether ND ug/kg 05/05/17 15:18 101-55-305/04/17 22:234251
Butylbenzylphthalate ND ug/kg 05/05/17 15:18 85-68-705/04/17 22:234251
4-Chloro-3-methylphenol ND ug/kg 05/05/17 15:18 59-50-705/04/17 22:238511
4-Chloroaniline ND ug/kg 05/05/17 15:18 106-47-805/04/17 22:2321301
bis(2-Chloroethoxy)methane ND ug/kg 05/05/17 15:18 111-91-105/04/17 22:234251
bis(2-Chloroethyl) ether ND ug/kg 05/05/17 15:18 111-44-405/04/17 22:234251
2-Chloronaphthalene ND ug/kg 05/05/17 15:18 91-58-705/04/17 22:234251
2-Chlorophenol ND ug/kg 05/05/17 15:18 95-57-805/04/17 22:234251
4-Chlorophenylphenyl ether ND ug/kg 05/05/17 15:18 7005-72-305/04/17 22:234251
Chrysene ND ug/kg 05/05/17 15:18 218-01-905/04/17 22:234251
Dibenz(a,h)anthracene ND ug/kg 05/05/17 15:18 53-70-305/04/17 22:234251
Dibenzofuran ND ug/kg 05/05/17 15:18 132-64-905/04/17 22:234251
1,2-Dichlorobenzene ND ug/kg 05/05/17 15:18 95-50-105/04/17 22:234251
1,3-Dichlorobenzene ND ug/kg 05/05/17 15:18 541-73-1 L205/04/17 22:234251
1,4-Dichlorobenzene ND ug/kg 05/05/17 15:18 106-46-705/04/17 22:234251
3,3'-Dichlorobenzidine ND ug/kg 05/05/17 15:18 91-94-105/04/17 22:2321301
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
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Page 20 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-5 Lab ID:92338971005 Collected:05/02/17 10:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 05/05/17 15:18 120-83-205/04/17 22:234251
Diethylphthalate ND ug/kg 05/05/17 15:18 84-66-205/04/17 22:234251
2,4-Dimethylphenol ND ug/kg 05/05/17 15:18 105-67-905/04/17 22:234251
Dimethylphthalate ND ug/kg 05/05/17 15:18 131-11-305/04/17 22:234251
Di-n-butylphthalate ND ug/kg 05/05/17 15:18 84-74-205/04/17 22:234251
4,6-Dinitro-2-methylphenol ND ug/kg 05/05/17 15:18 534-52-105/04/17 22:238511
2,4-Dinitrophenol ND ug/kg 05/05/17 15:18 51-28-505/04/17 22:2321301
2,4-Dinitrotoluene ND ug/kg 05/05/17 15:18 121-14-205/04/17 22:234251
2,6-Dinitrotoluene ND ug/kg 05/05/17 15:18 606-20-205/04/17 22:234251
Di-n-octylphthalate ND ug/kg 05/05/17 15:18 117-84-005/04/17 22:234251
bis(2-Ethylhexyl)phthalate ND ug/kg 05/05/17 15:18 117-81-705/04/17 22:234251
Fluoranthene ND ug/kg 05/05/17 15:18 206-44-005/04/17 22:234251
Fluorene ND ug/kg 05/05/17 15:18 86-73-705/04/17 22:234251
Hexachloro-1,3-butadiene ND ug/kg 05/05/17 15:18 87-68-305/04/17 22:234251
Hexachlorobenzene ND ug/kg 05/05/17 15:18 118-74-105/04/17 22:234251
Hexachlorocyclopentadiene ND ug/kg 05/05/17 15:18 77-47-405/04/17 22:234251
Hexachloroethane ND ug/kg 05/05/17 15:18 67-72-105/04/17 22:234251
Indeno(1,2,3-cd)pyrene ND ug/kg 05/05/17 15:18 193-39-505/04/17 22:234251
Isophorone ND ug/kg 05/05/17 15:18 78-59-105/04/17 22:234251
1-Methylnaphthalene ND ug/kg 05/05/17 15:18 90-12-005/04/17 22:234251
2-Methylnaphthalene ND ug/kg 05/05/17 15:18 91-57-605/04/17 22:234251
2-Methylphenol(o-Cresol)ND ug/kg 05/05/17 15:18 95-48-705/04/17 22:234251
3&4-Methylphenol(m&p Cresol)ND ug/kg 05/05/17 15:18 15831-10-405/04/17 22:234251
Naphthalene ND ug/kg 05/05/17 15:18 91-20-305/04/17 22:234251
2-Nitroaniline ND ug/kg 05/05/17 15:18 88-74-405/04/17 22:2321301
3-Nitroaniline ND ug/kg 05/05/17 15:18 99-09-205/04/17 22:2321301
4-Nitroaniline ND ug/kg 05/05/17 15:18 100-01-605/04/17 22:238511
Nitrobenzene ND ug/kg 05/05/17 15:18 98-95-305/04/17 22:234251
2-Nitrophenol ND ug/kg 05/05/17 15:18 88-75-505/04/17 22:234251
4-Nitrophenol ND ug/kg 05/05/17 15:18 100-02-705/04/17 22:2321301
N-Nitrosodimethylamine ND ug/kg 05/05/17 15:18 62-75-905/04/17 22:234251
N-Nitroso-di-n-propylamine ND ug/kg 05/05/17 15:18 621-64-705/04/17 22:234251
N-Nitrosodiphenylamine ND ug/kg 05/05/17 15:18 86-30-605/04/17 22:234251
2,2'-Oxybis(1-chloropropane)ND ug/kg 05/05/17 15:18 108-60-105/04/17 22:234251
Pentachlorophenol ND ug/kg 05/05/17 15:18 87-86-505/04/17 22:2321301
Phenanthrene ND ug/kg 05/05/17 15:18 85-01-805/04/17 22:234251
Phenol ND ug/kg 05/05/17 15:18 108-95-205/04/17 22:234251
Pyrene ND ug/kg 05/05/17 15:18 129-00-005/04/17 22:234251
Pyridine ND ug/kg 05/05/17 15:18 110-86-105/04/17 22:234251
1,2,4-Trichlorobenzene ND ug/kg 05/05/17 15:18 120-82-105/04/17 22:234251
2,4,5-Trichlorophenol ND ug/kg 05/05/17 15:18 95-95-405/04/17 22:234251
2,4,6-Trichlorophenol ND ug/kg 05/05/17 15:18 88-06-205/04/17 22:234251
Surrogates
Nitrobenzene-d5 (S)43 %05/05/17 15:18 4165-60-005/04/17 22:2323-110 1
2-Fluorobiphenyl (S)44 %05/05/17 15:18 321-60-805/04/17 22:2330-110 1
Terphenyl-d14 (S)62 %05/05/17 15:18 1718-51-005/04/17 22:2328-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-5 Lab ID:92338971005 Collected:05/02/17 10:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
Phenol-d6 (S)42 %05/05/17 15:18 13127-88-305/04/17 22:2322-110 1
2-Fluorophenol (S)39 %05/05/17 15:18 367-12-405/04/17 22:2313-110 1
2,4,6-Tribromophenol (S)52 %05/05/17 15:18 118-79-605/04/17 22:2327-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 05/03/17 18:45 67-64-11441
Benzene ND ug/kg 05/03/17 18:45 71-43-27.2 1
Bromobenzene ND ug/kg 05/03/17 18:45 108-86-17.2 1
Bromochloromethane ND ug/kg 05/03/17 18:45 74-97-57.2 1
Bromodichloromethane ND ug/kg 05/03/17 18:45 75-27-47.2 1
Bromoform ND ug/kg 05/03/17 18:45 75-25-27.2 1
Bromomethane ND ug/kg 05/03/17 18:45 74-83-914.4 1
2-Butanone (MEK)ND ug/kg 05/03/17 18:45 78-93-31441
n-Butylbenzene ND ug/kg 05/03/17 18:45 104-51-87.2 1
sec-Butylbenzene ND ug/kg 05/03/17 18:45 135-98-87.2 1
tert-Butylbenzene ND ug/kg 05/03/17 18:45 98-06-67.2 1
Carbon tetrachloride ND ug/kg 05/03/17 18:45 56-23-57.2 1
Chlorobenzene ND ug/kg 05/03/17 18:45 108-90-77.2 1
Chloroethane ND ug/kg 05/03/17 18:45 75-00-314.4 1
Chloroform ND ug/kg 05/03/17 18:45 67-66-37.2 1
Chloromethane ND ug/kg 05/03/17 18:45 74-87-314.4 1
2-Chlorotoluene ND ug/kg 05/03/17 18:45 95-49-87.2 1
4-Chlorotoluene ND ug/kg 05/03/17 18:45 106-43-47.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 05/03/17 18:45 96-12-87.2 1
Dibromochloromethane ND ug/kg 05/03/17 18:45 124-48-17.2 1
1,2-Dibromoethane (EDB)ND ug/kg 05/03/17 18:45 106-93-47.2 1
Dibromomethane ND ug/kg 05/03/17 18:45 74-95-37.2 1
1,2-Dichlorobenzene ND ug/kg 05/03/17 18:45 95-50-17.2 1
1,3-Dichlorobenzene ND ug/kg 05/03/17 18:45 541-73-17.2 1
1,4-Dichlorobenzene ND ug/kg 05/03/17 18:45 106-46-77.2 1
Dichlorodifluoromethane ND ug/kg 05/03/17 18:45 75-71-814.4 1
1,1-Dichloroethane ND ug/kg 05/03/17 18:45 75-34-37.2 1
1,2-Dichloroethane ND ug/kg 05/03/17 18:45 107-06-27.2 1
1,1-Dichloroethene ND ug/kg 05/03/17 18:45 75-35-47.2 1
cis-1,2-Dichloroethene ND ug/kg 05/03/17 18:45 156-59-27.2 1
trans-1,2-Dichloroethene ND ug/kg 05/03/17 18:45 156-60-57.2 1
1,2-Dichloropropane ND ug/kg 05/03/17 18:45 78-87-57.2 1
1,3-Dichloropropane ND ug/kg 05/03/17 18:45 142-28-97.2 1
2,2-Dichloropropane ND ug/kg 05/03/17 18:45 594-20-77.2 1
1,1-Dichloropropene ND ug/kg 05/03/17 18:45 563-58-67.2 1
cis-1,3-Dichloropropene ND ug/kg 05/03/17 18:45 10061-01-57.2 1
trans-1,3-Dichloropropene ND ug/kg 05/03/17 18:45 10061-02-67.2 1
Diisopropyl ether ND ug/kg 05/03/17 18:45 108-20-37.2 1
Ethylbenzene ND ug/kg 05/03/17 18:45 100-41-47.2 1
Hexachloro-1,3-butadiene ND ug/kg 05/03/17 18:45 87-68-37.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 97
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Sample:BERM-5 Lab ID:92338971005 Collected:05/02/17 10:10 Received:05/02/17 11:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
2-Hexanone ND ug/kg 05/03/17 18:45 591-78-671.8 1
Isopropylbenzene (Cumene)ND ug/kg 05/03/17 18:45 98-82-87.2 1
p-Isopropyltoluene ND ug/kg 05/03/17 18:45 99-87-67.2 1
Methylene Chloride ND ug/kg 05/03/17 18:45 75-09-228.7 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 05/03/17 18:45 108-10-171.8 1
Methyl-tert-butyl ether ND ug/kg 05/03/17 18:45 1634-04-47.2 1
Naphthalene ND ug/kg 05/03/17 18:45 91-20-37.2 1
n-Propylbenzene ND ug/kg 05/03/17 18:45 103-65-17.2 1
Styrene ND ug/kg 05/03/17 18:45 100-42-57.2 1
1,1,1,2-Tetrachloroethane ND ug/kg 05/03/17 18:45 630-20-67.2 1
1,1,2,2-Tetrachloroethane ND ug/kg 05/03/17 18:45 79-34-57.2 1
Tetrachloroethene ND ug/kg 05/03/17 18:45 127-18-47.2 1
Toluene ND ug/kg 05/03/17 18:45 108-88-37.2 1
1,2,3-Trichlorobenzene ND ug/kg 05/03/17 18:45 87-61-67.2 1
1,2,4-Trichlorobenzene ND ug/kg 05/03/17 18:45 120-82-17.2 1
1,1,1-Trichloroethane ND ug/kg 05/03/17 18:45 71-55-67.2 1
1,1,2-Trichloroethane ND ug/kg 05/03/17 18:45 79-00-57.2 1
Trichloroethene ND ug/kg 05/03/17 18:45 79-01-67.2 1
Trichlorofluoromethane ND ug/kg 05/03/17 18:45 75-69-47.2 1
1,2,3-Trichloropropane ND ug/kg 05/03/17 18:45 96-18-47.2 1
1,2,4-Trimethylbenzene ND ug/kg 05/03/17 18:45 95-63-67.2 1
1,3,5-Trimethylbenzene ND ug/kg 05/03/17 18:45 108-67-87.2 1
Vinyl acetate ND ug/kg 05/03/17 18:45 108-05-471.8 1
Vinyl chloride ND ug/kg 05/03/17 18:45 75-01-414.4 1
Xylene (Total)ND ug/kg 05/03/17 18:45 1330-20-714.4 1
m&p-Xylene ND ug/kg 05/03/17 18:45 179601-23-114.4 1
o-Xylene ND ug/kg 05/03/17 18:45 95-47-67.2 1
Surrogates
Toluene-d8 (S)101 %05/03/17 18:45 2037-26-570-130 1
4-Bromofluorobenzene (S)98 %05/03/17 18:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)117 %05/03/17 18:45 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 22.4 %05/03/17 07:480.10 1
Analytical Method: EPA 7196 Preparation Method: EPA 7196 Modified7196 Chromium, Hexavalent
Chromium, Hexavalent ND mg/kg 05/10/17 02:31 18540-29-905/10/17 00:154.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
358912
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1990469
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
Mercury mg/kg ND 0.0060 05/04/17 16:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1990470LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.078.083 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1990471MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92338908007
1990472
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury mg/kg M1.067 68 75-12577 10.0710.032 0.078 0.086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
358955
EPA 3050
EPA 6010
6010 MET
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1990655
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
Antimony mg/kg ND 0.50 05/03/17 22:40
Arsenic mg/kg ND 1.0 05/03/17 22:40
Beryllium mg/kg ND 0.10 05/03/17 22:40
Cadmium mg/kg ND 0.10 05/03/17 22:40
Chromium mg/kg ND 0.50 05/03/17 22:40
Copper mg/kg ND 0.50 05/03/17 22:40
Lead mg/kg ND 0.50 05/03/17 22:40
Manganese mg/kg ND 0.50 05/03/17 22:40
Nickel mg/kg ND 0.50 05/03/17 22:40
Selenium mg/kg ND 1.0 05/03/17 22:40
Silver mg/kg ND 0.50 05/03/17 22:40
Thallium mg/kg ND 1.0 05/03/17 22:40
Zinc mg/kg ND 1.0 05/03/17 22:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1990656LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 48.750 97 80-120
Arsenic mg/kg 48.450 97 80-120
Beryllium mg/kg 48.650 97 80-120
Cadmium mg/kg 49.350 99 80-120
Chromium mg/kg 48.750 97 80-120
Copper mg/kg 50.750 101 80-120
Lead mg/kg 48.850 98 80-120
Manganese mg/kg 49.050 98 80-120
Nickel mg/kg 48.350 97 80-120
Selenium mg/kg 50.350 101 80-120
Silver mg/kg 24.325 97 80-120
Thallium mg/kg 49.050 98 80-120
Zinc mg/kg 50.450 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1990657MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92338908007
1990658
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony mg/kg M152.8 56 75-12553 1845.80.34J 29.7 24.8
Arsenic mg/kg M152.8 73 75-12570 1745.80.52J 38.8 32.6
Beryllium mg/kg 52.8 93 75-12590 1745.80.32 49.2 41.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1990657MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92338908007
1990658
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Cadmium mg/kg 52.8 91 75-12590 1545.8ND 47.9 41.4
Chromium mg/kg 52.8 91 75-12577 1845.831.3 79.5 66.3
Copper mg/kg 52.8 107 75-125103 1545.810.9 67.3 58.2
Lead mg/kg 52.8 85 75-12586 1145.811.0 55.9 50.2
Manganese mg/kg 52.8 97 75-125108 145.8155 206 204
Nickel mg/kg 52.8 87 75-12586 1545.80.97 46.9 40.4
Selenium mg/kg M152.8 66 75-12562 1945.82.3 37.1 30.8
Silver mg/kg 26.4 93 75-12591 1522.90.31J 24.7 21.2
Thallium mg/kg 52.8 81 75-12580 1645.8ND 42.8 36.6
Zinc mg/kg 52.8 96 75-12593 1545.87.8 58.6 50.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
358980
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1990887
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.8 05/03/17 14:09
1,1,1-Trichloroethane ug/kg ND 5.8 05/03/17 14:09
1,1,2,2-Tetrachloroethane ug/kg ND 5.8 05/03/17 14:09
1,1,2-Trichloroethane ug/kg ND 5.8 05/03/17 14:09
1,1-Dichloroethane ug/kg ND 5.8 05/03/17 14:09
1,1-Dichloroethene ug/kg ND 5.8 05/03/17 14:09
1,1-Dichloropropene ug/kg ND 5.8 05/03/17 14:09
1,2,3-Trichlorobenzene ug/kg ND 5.8 05/03/17 14:09
1,2,3-Trichloropropane ug/kg ND 5.8 05/03/17 14:09
1,2,4-Trichlorobenzene ug/kg ND 5.8 05/03/17 14:09
1,2,4-Trimethylbenzene ug/kg ND 5.8 05/03/17 14:09
1,2-Dibromo-3-chloropropane ug/kg ND 5.8 05/03/17 14:09
1,2-Dibromoethane (EDB)ug/kg ND 5.8 05/03/17 14:09
1,2-Dichlorobenzene ug/kg ND 5.8 05/03/17 14:09
1,2-Dichloroethane ug/kg ND 5.8 05/03/17 14:09
1,2-Dichloropropane ug/kg ND 5.8 05/03/17 14:09
1,3,5-Trimethylbenzene ug/kg ND 5.8 05/03/17 14:09
1,3-Dichlorobenzene ug/kg ND 5.8 05/03/17 14:09
1,3-Dichloropropane ug/kg ND 5.8 05/03/17 14:09
1,4-Dichlorobenzene ug/kg ND 5.8 05/03/17 14:09
2,2-Dichloropropane ug/kg ND 5.8 05/03/17 14:09
2-Butanone (MEK)ug/kg ND 115 05/03/17 14:09
2-Chlorotoluene ug/kg ND 5.8 05/03/17 14:09
2-Hexanone ug/kg ND 57.6 05/03/17 14:09
4-Chlorotoluene ug/kg ND 5.8 05/03/17 14:09
4-Methyl-2-pentanone (MIBK)ug/kg ND 57.6 05/03/17 14:09
Acetone ug/kg ND 115 05/03/17 14:09
Benzene ug/kg ND 5.8 05/03/17 14:09
Bromobenzene ug/kg ND 5.8 05/03/17 14:09
Bromochloromethane ug/kg ND 5.8 05/03/17 14:09
Bromodichloromethane ug/kg ND 5.8 05/03/17 14:09
Bromoform ug/kg ND 5.8 05/03/17 14:09
Bromomethane ug/kg ND 11.5 05/03/17 14:09
Carbon tetrachloride ug/kg ND 5.8 05/03/17 14:09
Chlorobenzene ug/kg ND 5.8 05/03/17 14:09
Chloroethane ug/kg ND 11.5 05/03/17 14:09
Chloroform ug/kg ND 5.8 05/03/17 14:09
Chloromethane ug/kg ND 11.5 05/03/17 14:09
cis-1,2-Dichloroethene ug/kg ND 5.8 05/03/17 14:09
cis-1,3-Dichloropropene ug/kg ND 5.8 05/03/17 14:09
Dibromochloromethane ug/kg ND 5.8 05/03/17 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1990887
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 5.8 05/03/17 14:09
Dichlorodifluoromethane ug/kg ND 11.5 05/03/17 14:09
Diisopropyl ether ug/kg ND 5.8 05/03/17 14:09
Ethylbenzene ug/kg ND 5.8 05/03/17 14:09
Hexachloro-1,3-butadiene ug/kg ND 5.8 05/03/17 14:09
Isopropylbenzene (Cumene)ug/kg ND 5.8 05/03/17 14:09
m&p-Xylene ug/kg ND 11.5 05/03/17 14:09
Methyl-tert-butyl ether ug/kg ND 5.8 05/03/17 14:09
Methylene Chloride ug/kg ND 23.0 05/03/17 14:09
n-Butylbenzene ug/kg ND 5.8 05/03/17 14:09
n-Propylbenzene ug/kg ND 5.8 05/03/17 14:09
Naphthalene ug/kg ND 5.8 05/03/17 14:09
o-Xylene ug/kg ND 5.8 05/03/17 14:09
p-Isopropyltoluene ug/kg ND 5.8 05/03/17 14:09
sec-Butylbenzene ug/kg ND 5.8 05/03/17 14:09
Styrene ug/kg ND 5.8 05/03/17 14:09
tert-Butylbenzene ug/kg ND 5.8 05/03/17 14:09
Tetrachloroethene ug/kg ND 5.8 05/03/17 14:09
Toluene ug/kg ND 5.8 05/03/17 14:09
trans-1,2-Dichloroethene ug/kg ND 5.8 05/03/17 14:09
trans-1,3-Dichloropropene ug/kg ND 5.8 05/03/17 14:09
Trichloroethene ug/kg ND 5.8 05/03/17 14:09
Trichlorofluoromethane ug/kg ND 5.8 05/03/17 14:09
Vinyl acetate ug/kg ND 57.6 05/03/17 14:09
Vinyl chloride ug/kg ND 11.5 05/03/17 14:09
Xylene (Total)ug/kg ND 11.5 05/03/17 14:09
1,2-Dichloroethane-d4 (S)%112 70-132 05/03/17 14:09
4-Bromofluorobenzene (S)%97 70-130 05/03/17 14:09
Toluene-d8 (S)%100 70-130 05/03/17 14:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1990888LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 52.653.1 99 74-137
1,1,1-Trichloroethane ug/kg 55.153.1 104 67-140
1,1,2,2-Tetrachloroethane ug/kg 54.253.1 102 72-141
1,1,2-Trichloroethane ug/kg 54.253.1 102 78-138
1,1-Dichloroethane ug/kg 54.753.1 103 69-134
1,1-Dichloroethene ug/kg 55.853.1 105 67-138
1,1-Dichloropropene ug/kg 58.353.1 110 69-139
1,2,3-Trichlorobenzene ug/kg 57.753.1 109 70-146
1,2,3-Trichloropropane ug/kg 55.453.1 104 69-144
1,2,4-Trichlorobenzene ug/kg 59.453.1 112 68-148
1,2,4-Trimethylbenzene ug/kg 56.553.1 106 74-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1990888LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/kg 56.353.1 106 65-140
1,2-Dibromoethane (EDB)ug/kg 56.953.1 107 77-135
1,2-Dichlorobenzene ug/kg 57.753.1 109 77-141
1,2-Dichloroethane ug/kg 55.753.1 105 65-137
1,2-Dichloropropane ug/kg 56.353.1 106 72-136
1,3,5-Trimethylbenzene ug/kg 56.853.1 107 76-133
1,3-Dichlorobenzene ug/kg 57.253.1 108 74-138
1,3-Dichloropropane ug/kg 56.753.1 107 71-139
1,4-Dichlorobenzene ug/kg 58.153.1 110 76-138
2,2-Dichloropropane ug/kg 54.553.1 103 68-137
2-Butanone (MEK)ug/kg 116106 110 58-147
2-Chlorotoluene ug/kg 57.253.1 108 73-139
2-Hexanone ug/kg 103106 97 62-145
4-Chlorotoluene ug/kg 57.453.1 108 76-141
4-Methyl-2-pentanone (MIBK)ug/kg 114106 108 64-149
Acetone ug/kg 126106 119 53-153
Benzene ug/kg 54.953.1 103 73-135
Bromobenzene ug/kg 57.653.1 109 75-133
Bromochloromethane ug/kg 56.453.1 106 73-134
Bromodichloromethane ug/kg 56.753.1 107 71-135
Bromoform ug/kg 52.253.1 98 66-141
Bromomethane ug/kg 44.253.1 83 53-160
Carbon tetrachloride ug/kg 53.053.1 100 60-145
Chlorobenzene ug/kg 56.453.1 106 78-130
Chloroethane ug/kg 53.553.1 101 64-149
Chloroform ug/kg 55.653.1 105 70-134
Chloromethane ug/kg 54.153.1 102 52-150
cis-1,2-Dichloroethene ug/kg 58.253.1 110 70-133
cis-1,3-Dichloropropene ug/kg 59.453.1 112 68-134
Dibromochloromethane ug/kg 55.953.1 105 71-138
Dibromomethane ug/kg 56.953.1 107 74-130
Dichlorodifluoromethane ug/kg 43.453.1 82 40-160
Diisopropyl ether ug/kg 55.853.1 105 69-141
Ethylbenzene ug/kg 55.053.1 104 75-133
Hexachloro-1,3-butadiene ug/kg 55.753.1 105 68-143
Isopropylbenzene (Cumene)ug/kg 54.953.1 103 76-143
m&p-Xylene ug/kg 109106 102 75-136
Methyl-tert-butyl ether ug/kg 57.153.1 108 68-144
Methylene Chloride ug/kg 54.853.1 103 45-154
n-Butylbenzene ug/kg 58.453.1 110 72-137
n-Propylbenzene ug/kg 55.353.1 104 76-136
Naphthalene ug/kg 60.253.1 113 68-151
o-Xylene ug/kg 55.753.1 105 76-141
p-Isopropyltoluene ug/kg 57.453.1 108 76-140
sec-Butylbenzene ug/kg 55.553.1 104 79-139
Styrene ug/kg 56.953.1 107 79-137
tert-Butylbenzene ug/kg 50.153.1 94 74-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1990888LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 46.453.1 87 71-138
Toluene ug/kg 56.353.1 106 74-131
trans-1,2-Dichloroethene ug/kg 56.753.1 107 67-135
trans-1,3-Dichloropropene ug/kg 59.353.1 112 65-146
Trichloroethene ug/kg 54.453.1 102 67-135
Trichlorofluoromethane ug/kg 58.353.1 110 59-144
Vinyl acetate ug/kg 117106 111 40-160
Vinyl chloride ug/kg 51.053.1 96 56-141
Xylene (Total)ug/kg 164159 103 76-137
1,2-Dichloroethane-d4 (S)%104 70-132
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1991724MATRIX SPIKE SAMPLE:
MSSpike
Result
92338869001
1,1,1,2-Tetrachloroethane ug/kg 13.819.8 70 70-130ND
1,1,1-Trichloroethane ug/kg 16.819.8 85 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 13.4 M119.8 67 70-130ND
1,1,2-Trichloroethane ug/kg 13.919.8 70 70-130ND
1,1-Dichloroethane ug/kg 17.119.8 86 70-130ND
1,1-Dichloroethene ug/kg 17.919.8 90 49-180ND
1,1-Dichloropropene ug/kg 18.419.8 93 70-130ND
1,2,3-Trichlorobenzene ug/kg 8.4 M119.8 42 70-130ND
1,2,3-Trichloropropane ug/kg 13.2 M119.8 66 70-130ND
1,2,4-Trichlorobenzene ug/kg 8.2 M119.8 41 70-130ND
1,2,4-Trimethylbenzene ug/kg 14.319.8 72 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 12.3 M119.8 62 70-130ND
1,2-Dibromoethane (EDB)ug/kg 14.419.8 73 70-130ND
1,2-Dichlorobenzene ug/kg 11.7 M119.8 59 70-130ND
1,2-Dichloroethane ug/kg 13.919.8 70 70-130ND
1,2-Dichloropropane ug/kg 15.519.8 78 70-130ND
1,3,5-Trimethylbenzene ug/kg 14.919.8 75 70-130ND
1,3-Dichlorobenzene ug/kg 12.0 M119.8 61 70-130ND
1,3-Dichloropropane ug/kg 14.819.8 75 70-130ND
1,4-Dichlorobenzene ug/kg 12.1 M119.8 61 70-130ND
2,2-Dichloropropane ug/kg 16.719.8 84 70-130ND
2-Butanone (MEK)ug/kg 26.2J M139.7 66 70-130ND
2-Chlorotoluene ug/kg 14.419.8 72 70-130ND
2-Hexanone ug/kg 21.8J M139.7 55 70-130ND
4-Chlorotoluene ug/kg 13.1 M119.8 66 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 25.2J M139.7 64 70-130ND
Acetone ug/kg 45.8J39.7 115 70-130ND
Benzene ug/kg 15.919.8 80 50-166ND
Bromobenzene ug/kg 13.8 M119.8 69 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1991724MATRIX SPIKE SAMPLE:
MSSpike
Result
92338869001
Bromochloromethane ug/kg 15.219.8 77 70-130ND
Bromodichloromethane ug/kg 14.719.8 74 70-130ND
Bromoform ug/kg 12.0 M119.8 60 70-130ND
Bromomethane ug/kg 14.919.8 75 70-130ND
Carbon tetrachloride ug/kg 16.519.8 83 70-130ND
Chlorobenzene ug/kg 14.919.8 75 43-169ND
Chloroethane ug/kg 17.019.8 86 70-130ND
Chloroform ug/kg 15.419.8 78 70-130ND
Chloromethane ug/kg 14.019.8 71 70-130ND
cis-1,2-Dichloroethene ug/kg 17.119.8 86 70-130ND
cis-1,3-Dichloropropene ug/kg 14.119.8 71 70-130ND
Dibromochloromethane ug/kg 13.5 M119.8 68 70-130ND
Dibromomethane ug/kg 14.319.8 72 70-130ND
Dichlorodifluoromethane ug/kg 11.0 M119.8 55 70-130ND
Diisopropyl ether ug/kg 15.319.8 77 70-130ND
Ethylbenzene ug/kg 15.519.8 78 70-130ND
Hexachloro-1,3-butadiene ug/kg 11.1 M119.8 56 70-130ND
Isopropylbenzene (Cumene)ug/kg 15.519.8 78 70-130ND
m&p-Xylene ug/kg 29.939.7 75 70-130ND
Methyl-tert-butyl ether ug/kg 15.519.8 78 70-130ND
Methylene Chloride ug/kg 14.3J19.8 72 70-130ND
n-Butylbenzene ug/kg 13.6 M119.8 69 70-130ND
n-Propylbenzene ug/kg 14.919.8 75 70-130ND
Naphthalene ug/kg 11.6 M119.8 59 70-130ND
o-Xylene ug/kg 14.619.8 74 70-130ND
p-Isopropyltoluene ug/kg 13.4 M119.8 68 70-130ND
sec-Butylbenzene ug/kg 15.019.8 75 70-130ND
Styrene ug/kg 13.5 M119.8 68 70-130ND
tert-Butylbenzene ug/kg 13.919.8 70 70-130ND
Tetrachloroethene ug/kg 15.019.8 76 70-130ND
Toluene ug/kg 16.019.8 81 52-163ND
trans-1,2-Dichloroethene ug/kg 17.619.8 89 70-130ND
trans-1,3-Dichloropropene ug/kg 13.7 M119.8 69 70-130ND
Trichloroethene ug/kg 16.019.8 81 49-167ND
Trichlorofluoromethane ug/kg 17.819.8 90 70-130ND
Vinyl acetate ug/kg ND M139.7 13 70-130ND
Vinyl chloride ug/kg 16.519.8 83 70-130ND
1,2-Dichloroethane-d4 (S)%105 70-132
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92338971001
1991723SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92338971001
1991723SAMPLE DUPLICATE:
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg NDND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg NDND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg NDND
m&p-Xylene ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92338971001
1991723SAMPLE DUPLICATE:
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg NDND
o-Xylene ug/kg NDND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg NDND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg NDND
1,2-Dichloroethane-d4 (S)%106 7112
4-Bromofluorobenzene (S)%101 1698
Toluene-d8 (S)%102 14101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
359093
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1991642
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 05/04/17 11:51
1,2-Dichlorobenzene ug/kg ND 330 05/04/17 11:51
1,3-Dichlorobenzene ug/kg ND 330 05/04/17 11:51
1,4-Dichlorobenzene ug/kg ND 330 05/04/17 11:51
1-Methylnaphthalene ug/kg ND 330 05/04/17 11:51
2,2'-Oxybis(1-chloropropane)ug/kg ND 330 05/04/17 11:51
2,4,5-Trichlorophenol ug/kg ND 330 05/04/17 11:51
2,4,6-Trichlorophenol ug/kg ND 330 05/04/17 11:51
2,4-Dichlorophenol ug/kg ND 330 05/04/17 11:51
2,4-Dimethylphenol ug/kg ND 330 05/04/17 11:51
2,4-Dinitrophenol ug/kg ND 1650 05/04/17 11:51
2,4-Dinitrotoluene ug/kg ND 330 05/04/17 11:51
2,6-Dinitrotoluene ug/kg ND 330 05/04/17 11:51
2-Chloronaphthalene ug/kg ND 330 05/04/17 11:51
2-Chlorophenol ug/kg ND 330 05/04/17 11:51
2-Methylnaphthalene ug/kg ND 330 05/04/17 11:51
2-Methylphenol(o-Cresol)ug/kg ND 330 05/04/17 11:51
2-Nitroaniline ug/kg ND 1650 05/04/17 11:51
2-Nitrophenol ug/kg ND 330 05/04/17 11:51
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 05/04/17 11:51
3,3'-Dichlorobenzidine ug/kg ND 1650 05/04/17 11:51
3-Nitroaniline ug/kg ND 1650 05/04/17 11:51
4,6-Dinitro-2-methylphenol ug/kg ND 660 05/04/17 11:51
4-Bromophenylphenyl ether ug/kg ND 330 05/04/17 11:51
4-Chloro-3-methylphenol ug/kg ND 660 05/04/17 11:51
4-Chloroaniline ug/kg ND 1650 05/04/17 11:51
4-Chlorophenylphenyl ether ug/kg ND 330 05/04/17 11:51
4-Nitroaniline ug/kg ND 660 05/04/17 11:51
4-Nitrophenol ug/kg ND 1650 05/04/17 11:51
Acenaphthene ug/kg ND 330 05/04/17 11:51
Acenaphthylene ug/kg ND 330 05/04/17 11:51
Aniline ug/kg ND 330 05/04/17 11:51
Anthracene ug/kg ND 330 05/04/17 11:51
Benzo(a)anthracene ug/kg ND 330 05/04/17 11:51
Benzo(a)pyrene ug/kg ND 330 05/04/17 11:51
Benzo(b)fluoranthene ug/kg ND 330 05/04/17 11:51
Benzo(g,h,i)perylene ug/kg ND 330 05/04/17 11:51
Benzo(k)fluoranthene ug/kg ND 330 05/04/17 11:51
Benzoic Acid ug/kg ND 1650 05/04/17 11:51
Benzyl alcohol ug/kg ND 660 05/04/17 11:51
bis(2-Chloroethoxy)methane ug/kg ND 330 05/04/17 11:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 34 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1991642
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
bis(2-Chloroethyl) ether ug/kg ND 330 05/04/17 11:51
bis(2-Ethylhexyl)phthalate ug/kg ND 330 05/04/17 11:51
Butylbenzylphthalate ug/kg ND 330 05/04/17 11:51
Chrysene ug/kg ND 330 05/04/17 11:51
Di-n-butylphthalate ug/kg ND 330 05/04/17 11:51
Di-n-octylphthalate ug/kg ND 330 05/04/17 11:51
Dibenz(a,h)anthracene ug/kg ND 330 05/04/17 11:51
Dibenzofuran ug/kg ND 330 05/04/17 11:51
Diethylphthalate ug/kg ND 330 05/04/17 11:51
Dimethylphthalate ug/kg ND 330 05/04/17 11:51
Fluoranthene ug/kg ND 330 05/04/17 11:51
Fluorene ug/kg ND 330 05/04/17 11:51
Hexachloro-1,3-butadiene ug/kg ND 330 05/04/17 11:51
Hexachlorobenzene ug/kg ND 330 05/04/17 11:51
Hexachlorocyclopentadiene ug/kg ND 330 05/04/17 11:51
Hexachloroethane ug/kg ND 330 05/04/17 11:51
Indeno(1,2,3-cd)pyrene ug/kg ND 330 05/04/17 11:51
Isophorone ug/kg ND 330 05/04/17 11:51
N-Nitroso-di-n-propylamine ug/kg ND 330 05/04/17 11:51
N-Nitrosodimethylamine ug/kg ND 330 05/04/17 11:51
N-Nitrosodiphenylamine ug/kg ND 330 05/04/17 11:51
Naphthalene ug/kg ND 330 05/04/17 11:51
Nitrobenzene ug/kg ND 330 05/04/17 11:51
Pentachlorophenol ug/kg ND 1650 05/04/17 11:51
Phenanthrene ug/kg ND 330 05/04/17 11:51
Phenol ug/kg ND 330 05/04/17 11:51
Pyrene ug/kg ND 330 05/04/17 11:51
Pyridine ug/kg ND 330 05/04/17 11:51
2,4,6-Tribromophenol (S)%75 27-110 05/04/17 11:51
2-Fluorobiphenyl (S)%73 30-110 05/04/17 11:51
2-Fluorophenol (S)%66 13-110 05/04/17 11:51
Nitrobenzene-d5 (S)%68 23-110 05/04/17 11:51
Phenol-d6 (S)%67 22-110 05/04/17 11:51
Terphenyl-d14 (S)%94 28-110 05/04/17 11:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1991643LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1991644
1,2,4-Trichlorobenzene ug/kg 914 R116705536-120751250 31 30
1,2-Dichlorobenzene ug/kg 874 R116705241-120721200 31 30
1,3-Dichlorobenzene ug/kg 882 L216705366-120711190 30 30
1,4-Dichlorobenzene ug/kg 8731670 52 42-120701170 29 30
1-Methylnaphthalene ug/kg 10301670 62 40-120751250 19 30
2,2'-Oxybis(1-chloropropane)ug/kg 8271670 50 17-120671110 29 30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
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[phone]
Page 35 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1991643LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1991644
2,4,5-Trichlorophenol ug/kg 10801670 65 37-120721210 11 30
2,4,6-Trichlorophenol ug/kg 11401670 68 40-120791320 15 30
2,4-Dichlorophenol ug/kg 10201670 61 33-120801340 27 30
2,4-Dimethylphenol ug/kg 10401670 63 36-120841390 29 30
2,4-Dinitrophenol ug/kg 60308330 72 22-121715920 2 30
2,4-Dinitrotoluene ug/kg 15501670 93 60-120931560 0 30
2,6-Dinitrotoluene ug/kg 15201670 91 54-120951580 4 30
2-Chloronaphthalene ug/kg 9931670 60 41-120761260 24 30
2-Chlorophenol ug/kg 920 R116705539-120761270 32 30
2-Methylnaphthalene ug/kg 10401670 62 26-120751260 19 30
2-Methylphenol(o-Cresol)ug/kg 9051670 54 41-120691150 24 30
2-Nitroaniline ug/kg 24703330 74 45-120792630 6 30
2-Nitrophenol ug/kg 9721670 58 35-120761260 26 30
3&4-Methylphenol(m&p Cresol)ug/kg 9181670 55 35-120691150 22 30
3,3'-Dichlorobenzidine ug/kg 22903330 69 16-125702340 2 30
3-Nitroaniline ug/kg 25903330 78 45-120812710 4 30
4,6-Dinitro-2-methylphenol ug/kg 26503330 79 46-120792630 1 30
4-Bromophenylphenyl ether ug/kg 12301670 74 36-120811340 9 30
4-Chloro-3-methylphenol ug/kg 26203330 79 37-120822730 4 30
4-Chloroaniline ug/kg 21303330 64 35-120752500 16 30
4-Chlorophenylphenyl ether ug/kg 11601670 70 30-120761270 9 30
4-Nitroaniline ug/kg 27903330 84 48-120832780 0 30
4-Nitrophenol ug/kg 62608330 75 43-120726040 3 30
Acenaphthene ug/kg 11001670 66 46-120761270 14 30
Acenaphthylene ug/kg 10601670 64 46-120741240 15 30
Aniline ug/kg 7301670 44 33-12058959 27 30
Anthracene ug/kg 12701670 76 63-120801330 4 30
Benzo(a)anthracene ug/kg 12401670 74 61-120791310 6 30
Benzo(a)pyrene ug/kg 12201670 73 59-120791310 8 30
Benzo(b)fluoranthene ug/kg 11801670 71 55-120761260 7 30
Benzo(g,h,i)perylene ug/kg 12901670 78 57-120811360 5 30
Benzo(k)fluoranthene ug/kg 11801670 71 56-120771280 8 30
Benzoic Acid ug/kg 48208330 58 13-120584820 0 30
Benzyl alcohol ug/kg 19203330 58 34-120732440 24 30
bis(2-Chloroethoxy)methane ug/kg 9321670 56 21-120721200 26 30
bis(2-Chloroethyl) ether ug/kg 9131670 55 25-120701170 25 30
bis(2-Ethylhexyl)phthalate ug/kg 14201670 85 56-123881460 3 30
Butylbenzylphthalate ug/kg 13801670 83 57-120851420 3 30
Chrysene ug/kg 12001670 72 64-120771280 7 30
Di-n-butylphthalate ug/kg 13801670 83 58-120841400 1 30
Di-n-octylphthalate ug/kg 13601670 82 47-121821360 0 30
Dibenz(a,h)anthracene ug/kg 13901670 84 56-120821360 2 30
Dibenzofuran ug/kg 11301670 68 43-120751250 10 30
Diethylphthalate ug/kg 13001670 78 55-120791310 1 30
Dimethylphthalate ug/kg 12701670 76 54-120781300 2 30
Fluoranthene ug/kg 13201670 79 61-120791320 0 30
Fluorene ug/kg 12001670 72 51-120781290 8 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1991643LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1991644
Hexachloro-1,3-butadiene ug/kg 871 R116705222-120761270 37 30
Hexachlorobenzene ug/kg 12301670 74 53-120801340 8 30
Hexachlorocyclopentadiene ug/kg 843 R116705118-150751250 39 30
Hexachloroethane ug/kg 8731670 52 39-120701170 29 30
Indeno(1,2,3-cd)pyrene ug/kg 13201670 79 58-120831390 5 30
Isophorone ug/kg 12901670 77 38-120871450 12 30
N-Nitroso-di-n-propylamine ug/kg 10301670 62 30-120731210 16 30
N-Nitrosodimethylamine ug/kg 874 R116705232-120751250 36 30
N-Nitrosodiphenylamine ug/kg 12201670 73 50-120801330 9 30
Naphthalene ug/kg 9141670 55 38-120731220 29 30
Nitrobenzene ug/kg 1010 R116706137-120821370 31 30
Pentachlorophenol ug/kg 24803330 74 10-120752490 0 30
Phenanthrene ug/kg 12301670 74 62-120771280 4 30
Phenol ug/kg 10101670 60 37-120801330 28 30
Pyrene ug/kg 11901670 72 63-120771280 7 30
Pyridine ug/kg 639 R116703815-12056929 37 30
2,4,6-Tribromophenol (S)%79 27-11084
2-Fluorobiphenyl (S)%57 30-11073
2-Fluorophenol (S)%52 13-11073
Nitrobenzene-d5 (S)%54 23-11073
Phenol-d6 (S)%55 22-11074
Terphenyl-d14 (S)%77 28-11083
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
358829
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Dup
Result QualifiersRPDResult
92338908001
1989945SAMPLE DUPLICATE:
Percent Moisture %24.5 224.1
Parameter Units
Dup
Result QualifiersRPDResult
92338869004
1989946SAMPLE DUPLICATE:
Percent Moisture %17.2 117.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 97
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
359825
EPA 7196 Modified
EPA 7196
7196 Chromium, Hexavalent
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1995497
Associated Lab Samples:92338971001, 92338971002, 92338971003, 92338971004, 92338971005
Matrix:Solid
Analyzed
Chromium, Hexavalent mg/kg ND 5.0 05/10/17 02:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1995498LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/kg 26.025 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1995499MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92338971001
1995500
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chromium, Hexavalent mg/kg 26.8 99 75-125104 526.8ND 26.5 27.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
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Huntersville, NC 28078
[phone]
Page 39 of 97
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/23/2017 02:20 PM
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[phone]
Page 40 of 97
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92338971
DOT 49999.1.ST8 ROW 510
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92338971001 358955 359033BERM-1 EPA 3050 EPA 6010
92338971002 358955 359033BERM-2 EPA 3050 EPA 6010
92338971003 358955 359033BERM-3 EPA 3050 EPA 6010
92338971004 358955 359033BERM-4 EPA 3050 EPA 6010
92338971005 358955 359033BERM-5 EPA 3050 EPA 6010
92338971001 358912 359103BERM-1 EPA 7471 EPA 7471
92338971002 358912 359103BERM-2 EPA 7471 EPA 7471
92338971003 358912 359103BERM-3 EPA 7471 EPA 7471
92338971004 358912 359103BERM-4 EPA 7471 EPA 7471
92338971005 358912 359103BERM-5 EPA 7471 EPA 7471
92338971001 359093 359186BERM-1 EPA 3546 EPA 8270
92338971002 359093 359186BERM-2 EPA 3546 EPA 8270
92338971003 359093 359186BERM-3 EPA 3546 EPA 8270
92338971004 359093 359186BERM-4 EPA 3546 EPA 8270
92338971005 359093 359186BERM-5 EPA 3546 EPA 8270
92338971001 358980BERM-1 EPA 8260
92338971002 358980BERM-2 EPA 8260
92338971003 358980BERM-3 EPA 8260
92338971004 358980BERM-4 EPA 8260
92338971005 358980BERM-5 EPA 8260
92338971001 358829BERM-1 ASTM D2974-87
92338971002 358829BERM-2 ASTM D2974-87
92338971003 358829BERM-3 ASTM D2974-87
92338971004 358829BERM-4 ASTM D2974-87
92338971005 358829BERM-5 ASTM D2974-87
92338971001 359825 359827BERM-1 EPA 7196 Modified EPA 7196
92338971002 359825 359827BERM-2 EPA 7196 Modified EPA 7196
92338971003 359825 359827BERM-3 EPA 7196 Modified EPA 7196
92338971004 359825 359827BERM-4 EPA 7196 Modified EPA 7196
92338971005 359825 359827BERM-5 EPA 7196 Modified EPA 7196
REPORT OF LABORATORY ANALYSIS
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Page 41 of 97
Page 42 of 97
Page 43 of 97
Page 44 of 97
This report should not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
The results relate only to the samples included in this report.
Report of Laboratory Analysis
www.pacelabs.com
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Kevin Godwin
PACE Charlotte
9800 Kincey Ave.
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS
FOR PCBs
This report has been reviewed by:
Invoicing & Reporting Options:
Report Information:
Report Prepared Date:
May 16, 2017
Pace Project #: 10387444
Sample Receipt Date: 05/04/2017
Client Project #: 92338971
Client Sub PO #: N/A
The report provided has been invoiced as a Level 2
PCB Report. If an upgrade of this report package is
requested, an additional charge may be applied.
Please review the attached invoice for accuracy and
forward any questions to Nathan Boberg, your Pace
Project Manager.
State Cert #: 27700
Report Prepared for:
Page 1 of 53Report No.....10387444_1668A
May 16, 2017
Sarah Platzer, Project Manager
612-607-6451
[phone] (fax)
[e-mail]
Page 45 of 97
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
This report presents the results from the analyses performed on five samples submitted
by a representative of Pace Analytical - NC. The samples were analyzed for the
presence or absence of polychlorinated biphenyl (PCB) congeners using USEPA
Method 1668A. Reporting limits were set to approximately 50-150 parts per trillion and
were adjusted for the amount of dry sample extracted.
The isotopically-labeled PCB internal standards in the sample extracts were recovered
at 46-109%. All of the recoveries obtained for this project were within the target ranges
specified in the method. Since the quantification of the native PCB congeners was
based on internal standard and isotope dilution methodology, the data were
automatically corrected for variation in recovery and accurate values were obtained.
A laboratory method blank was prepared and analyzed with the sample batch as part of
our routine quality control procedures. The results show the blank to be free of PCB
congeners at the reporting limits. This indicates that the sample preparation
procedures did not significantly contribute to the PCB content determined for the
sample material.
Laboratory spike samples were also prepared with the sample batch using reference
material that had been fortified with native standards. The results show that the spiked
native compounds were recovered at 92-108% with relative percent differences of
0.0-10.3%. These values were within method limits. Matrix spikes were not extracted
with either sample batch.
DISCUSSION
Page 2 of 53Report No.....10387444_1668A
Page 46 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Report No.....10387444
Minnesota Laboratory Certifications
Authority Certificate #Authority Certificate #
A2LA 2926.01 Mississippi MN00064
Alabama 40770 Montana 92
Alaska MN00064 Nebraska NE-OS-18-06
Arizona AZ0014 Nevada MN_00064_200
Arkansas 88-0680 New Jersey (NE MN002
California 01155CA New York (NEL 11647
Colorado MN00064 North Carolina 27700
Connecticut PH-0256 North Dakota R-036
EPA Region 8 8TMS-Q Ohio 4150
Florida (NELAP E87605 Oklahoma D9922
Georgia (DNR)959 Oregon (ELAP)MN200001-005
Guam 959 Oregon (OREL MN300001-001
Hawaii SLD Pennsylvania 68-00563
Idaho MN00064 Puerto Rico MN00064
Illinois 200012 Saipan MP0003
Indiana C-MN-01 South Carolina 74003001
Indiana C-MN-01 Tennessee TN02818
Iowa 368 Texas T104704192-08
Kansas E-10167 Utah (NELAP)MN00064
Kentucky 90062 Virginia 00251
Louisiana 03086 Washington C755
Maine 2007029 West Virginia #9952C
Maryland 322 West Virginia D 382
Michigan 9909 Wisconsin 999407970
Minnesota 027-053-137 Wyoming 8TMS-Q
Page 3 of 53Report No.....10387444_1668A
Page 47 of 97
Appendix A
Sample Management
Pace Analytical Services, Inc.Page 4 of 53Report No.....10387444_1668A
Page 48 of 97
Page 5 of 53Report No.....10387444_1668A
Page 49 of 97
05/05/17
Page 6 of 53Report No.....10387444_1668A
Page 50 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Report No.....10387444
Reporting Flags
A =
B =
C =
D =
E =
I =
J =
Nn =
P =
R =
S =
U =
V =
X =
Y =
* =
Reporting Limit based on signal to noise
Less than 10x higher than method blank level
Result obtained from confirmation analysis
Result obtained from analysis of diluted sample
Exceeds calibration range
Interference present
Estimated value
Value obtained from additional analysis
PCDE Interference
Recovery outside target range
Peak saturated
Analyte not detected
Result verified by confirmation analysis
%D Exceeds limits
Calculated using average of daily RFs
See Discussion
Page 7 of 53Report No.....10387444_1668A
Page 51 of 97
Appendix B
Sample Analysis Summary
Pace Analytical Services, Inc.Page 8 of 53Report No.....10387444_1668A
Page 52 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client - PACE Charlotte
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID BLANK-55516
P170514A_01
P170514A02
5.05 g
22.36.50 g
BAL
P170514A_08
92338971001
BERM-1
MatrixDilution
Collected
Received
Extracted
Analyzed 05/14/2017 07:35
05/09/2017 16:45
05/04/2017 09:30
05/02/2017 09:10
5Solid
Method 1668A Polychlorobiphenyl Sample Analysis Results
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 3.44 2.08.288 1.29 6413C-4-MoCB 3 3.09 2.010.900 1.32 6613C-2,2'-DiCB 4 1.58 2.011.163 1.29 6413C-4,4'-DiCB 15 1.57 2.017.967 1.45 7313C-2,2',6-TrCB 19 1.05 2.014.792 1.25 6213C-3,4,4'-TrCB 37 1.13 2.025.568 1.50 7513C-2,2',6,6'-TeCB 54 0.79 2.018.240 1.31 6513C-3,4,4',5-TeCB 81 0.78 2.032.632 1.14 5713C-3,3',4,4'-TeCB 77 0.84 2.033.270 1.13 5713C-2,2',4,6,6'-PeCB 104 1.57 2.024.209 1.30 6513C-2,3,3',4,4'-PeCB 105 1.66 2.036.763 1.31 6513C-2,3,4,4',5-PeCB 114 1.61 2.036.109 1.31 6513C-2,3',4,4',5-PeCB 118 1.62 2.035.572 1.40 7013C-2,3',4,4',5'-PeCB 123 1.57 2.035.220 1.39 6913C-3,3',4,4',5-PeCB 126 1.56 2.039.932 1.39 6913C-2,2',4,4',6,6'-HxCB 155 1.24 2.030.167 1.39 7013C-HxCB (156/157)156/157 1.25 4.042.972 2.85 7113C-2,3',4,4',5,5'-HxCB 167 1.27 2.041.798 1.46 7313C-3,3',4,4',5,5'-HxCB 169 1.24 2.046.292 0.973 4913C-2,2',3,4',5,6,6'-HpCB 188 1.07 2.036.042 1.56 7813C-2,3,3',4,4',5,5'-HpCB 189 1.11 2.048.771 1.87 9313C-2,2',3,3',5,5',6,6'-OcCB 202 0.87 2.041.479 1.84 9213C-2,3,3',4,4',5,5',6-OcCB 205 0.94 2.051.336 0.995 5013C-2,2',3,3',4,4',5,5',6-NoCB 206 0.87 2.053.211 1.26 6313C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.83 2.048.232 1.38 6913C--DeCB 209 0.71 2.055.151 1.17 58
Cleanup Standards13C-2,4,4'-TrCB 28 1.07 2.021.258 1.61 8113C-2,3,3',5,5'-PeCB 111 1.52 2.033.270 1.19 5913C-2,2',3,3',5,5',6-HpCB 178 1.06 2.039.160 1.63 81
Recovery Standards13C-2,5-DiCB 9 1.65 2.013.546 NA NA13C-2,2',5,5'-TeCB 52 0.80 2.023.220 NA NA13C-2,2',4,5,5'-PeCB 101 1.57 2.030.419 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.30 2.038.724 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.92 2.050.862 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a dry weight basis
Page 9 of 53Report No.....10387444_1668A
Page 53 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Lab Sample ID 92338971001
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.0
3 ---ND------50.04---ND------50.05---ND------50.0
6 ---ND------50.07---ND------50.08---ND------50.0
9 ---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------66.016---ND------50.0
17 ---ND------50.01818/30 ---ND------10019---ND------50.0
20 20/28 ---ND------2582121/33 ---ND------27022---ND------190
23 ---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------100
31 ---ND------26032---ND------50.03321/33 ---ND------270
34 ---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------300
42 ---ND------1004343/73 ---ND------1004444/47/65 ---ND------300
45 45/51 ---ND------20046---ND------1004744/47/65 ---ND------300
48 ---ND------100
Page 10 of 53Report No.....10387444_1668A
Page 54 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Lab Sample ID 92338971001
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
49 49/69 ---ND------2005050/53 ---ND------200
51 45/51 ---ND------20052---ND------3085350/53 ---ND------200
54 ---ND------10055---ND------10056---ND------100
57 ---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------100
65 44/47/65 ---ND------30066---ND------16867---ND------100
68 ---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------400
71 40/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------100
79 ---ND------10080---ND------10081---ND------100
82 ---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------100
90 90/101/113 ---ND------3009188/91 ---ND------20092---ND------100
93 93/98/100/102 ---ND------40094---ND------10095---ND------190
96 ---ND------100
Page 11 of 53Report No.....10387444_1668A
Page 55 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Lab Sample ID 92338971001
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
97 86/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------400
99 ---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------300
102 93/98/100/102 ---ND------400103---ND------100104---ND------100
105 ---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------100
113 90/101/113 ---ND------300114---ND------100115110/115 ---ND------200
116 85/116/117 ---ND------30011785/116/117 ---ND------300118---ND------128
119 86/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100
127 ---ND------100128128/166 ---ND------200129129/138/163 ---ND------300
130 ---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200136---ND------100137---ND------100
138 129/138/163 ---ND------300139139/140 ---ND------200140139/140 ---ND------200
141 ---ND------100142---ND------100143134/143 ---ND------200
144 ---ND------100
Page 12 of 53Report No.....10387444_1668A
Page 56 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Lab Sample ID 92338971001
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
145 ---ND------100146---ND------100
147 147/149 ---ND------200148---ND------100149147/149 ---ND------200
150 ---ND------100151135/151 ---ND------200152---ND------100
153 153/168 ---ND------200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100
161 ---ND------100162---ND------100163129/138/163 ---ND------300
164 ---ND------100165---ND------100166128/166 ---ND------200
167 ---ND------100168153/168 ---ND------200169---ND------100170---ND------100171171/173 ---ND------200172---ND------100173171/173 ---ND------200174---ND------100
175 ---ND------100176---ND------100177---ND------100
178 ---ND------100179---ND------100180180/193 ---ND------200181---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200
186 ---ND------100187---ND------100188---ND------100
189 ---ND------100190---ND------100191---ND------100
192 ---ND------100
Page 13 of 53Report No.....10387444_1668A
Page 57 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Lab Sample ID 92338971001
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
193 180/193 ---ND------200194---ND------150
195 ---ND------150196---ND------150197197/200 ---ND------300
198 198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300
201 ---ND------150202---ND------150203---ND------150204---ND------150205---ND------150206---ND------150207---ND------150208---ND------150
209 ---ND------150
Page 14 of 53Report No.....10387444_1668A
Page 58 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-1
P170514A_08
Sample Analysis Results
Lab Sample ID 92338971001
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls ND
Total Heptachloro Biphenyls ND
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls ND
Decachloro Biphenyls ND
Total PCBs ND
Results reported on a dry weight basis
ND = Not Detected
Page 15 of 53Report No.....10387444_1668A
Page 59 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client - PACE Charlotte
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID BLANK-55516
P170514A_01
P170514A02
5.30 g
20.96.70 g
BAL
P170514A_09
92338971002
BERM-2
MatrixDilution
Collected
Received
Extracted
Analyzed 05/14/2017 08:34
05/09/2017 16:45
05/04/2017 09:30
05/02/2017 09:25
5Solid
Method 1668A Polychlorobiphenyl Sample Analysis Results
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 2.84 2.08.252 0.925 4613C-4-MoCB 3 2.72 2.010.851 1.06 5313C-2,2'-DiCB 4 1.59 2.011.115 0.993 5013C-4,4'-DiCB 15 1.55 2.017.906 1.25 6213C-2,2',6-TrCB 19 0.98 2.014.731 1.05 5313C-3,4,4'-TrCB 37 1.07 2.025.528 1.52 7613C-2,2',6,6'-TeCB 54 0.82 2.018.184 1.13 5713C-3,4,4',5-TeCB 81 0.80 2.032.575 1.68 8413C-3,3',4,4'-TeCB 77 0.81 2.033.161 1.50 7513C-2,2',4,6,6'-PeCB 104 1.50 2.024.153 1.12 5613C-2,3,3',4,4'-PeCB 105 1.57 2.036.721 1.64 8213C-2,3,4,4',5-PeCB 114 1.63 2.036.050 1.56 7813C-2,3',4,4',5-PeCB 118 1.58 2.035.514 1.59 7913C-2,3',4,4',5'-PeCB 123 1.54 2.035.178 1.62 8113C-3,3',4,4',5-PeCB 126 1.54 2.039.890 1.75 8713C-2,2',4,4',6,6'-HxCB 155 1.24 2.030.110 1.31 6513C-HxCB (156/157)156/157 1.32 4.042.930 3.40 8513C-2,3',4,4',5,5'-HxCB 167 1.24 2.041.756 1.70 8513C-3,3',4,4',5,5'-HxCB 169 1.30 2.046.216 1.74 8713C-2,2',3,4',5,6,6'-HpCB 188 1.03 2.035.983 1.39 6913C-2,3,3',4,4',5,5'-HpCB 189 1.09 2.048.736 1.72 8613C-2,2',3,3',5,5',6,6'-OcCB 202 0.89 2.041.438 1.49 7413C-2,3,3',4,4',5,5',6-OcCB 205 0.89 2.051.322 1.59 7913C-2,2',3,3',4,4',5,5',6-NoCB 206 0.79 2.053.175 1.35 6713C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.80 2.048.197 1.42 7113C--DeCB 209 0.69 2.055.136 1.37 69
Cleanup Standards13C-2,4,4'-TrCB 28 1.09 2.021.219 1.35 6713C-2,3,3',5,5'-PeCB 111 1.56 2.033.161 1.28 6413C-2,2',3,3',5,5',6-HpCB 178 1.11 2.039.118 1.42 71
Recovery Standards13C-2,5-DiCB 9 1.52 2.013.437 NA NA13C-2,2',5,5'-TeCB 52 0.81 2.023.180 NA NA13C-2,2',4,5,5'-PeCB 101 1.55 2.030.378 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.24 2.038.666 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.93 2.050.826 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a dry weight basis
Page 16 of 53Report No.....10387444_1668A
Page 60 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Lab Sample ID 92338971002
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.0
3 ---ND------50.04---ND------50.05---ND------50.0
6 ---ND------50.07---ND------50.08---ND------50.0
9 ---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------66.016---ND------50.0
17 ---ND------50.01818/30 ---ND------10019---ND------50.0
20 20/28 ---ND------2582121/33 ---ND------27022---ND------190
23 ---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------100
31 ---ND------26032---ND------50.03321/33 ---ND------270
34 ---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------300
42 ---ND------1004343/73 ---ND------1004444/47/65 ---ND------300
45 45/51 ---ND------20046---ND------1004744/47/65 ---ND------300
48 ---ND------100
Page 17 of 53Report No.....10387444_1668A
Page 61 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Lab Sample ID 92338971002
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
49 49/69 ---ND------2005050/53 ---ND------200
51 45/51 ---ND------20052---ND------3085350/53 ---ND------200
54 ---ND------10055---ND------10056---ND------100
57 ---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------100
65 44/47/65 ---ND------30066---ND------16867---ND------100
68 ---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------400
71 40/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------100
79 ---ND------10080---ND------10081---ND------100
82 ---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------100
90 90/101/113 ---ND------3009188/91 ---ND------20092---ND------100
93 93/98/100/102 ---ND------40094---ND------10095---ND------190
96 ---ND------100
Page 18 of 53Report No.....10387444_1668A
Page 62 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Lab Sample ID 92338971002
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
97 86/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------400
99 ---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------300
102 93/98/100/102 ---ND------400103---ND------100104---ND------100
105 ---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------100
113 90/101/113 ---ND------300114---ND------100115110/115 ---ND------200
116 85/116/117 ---ND------30011785/116/117 ---ND------300118---ND------128
119 86/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100
127 ---ND------100128128/166 ---ND------200129129/138/163 ---ND------300
130 ---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200136---ND------100137---ND------100
138 129/138/163 ---ND------300139139/140 ---ND------200140139/140 ---ND------200
141 ---ND------100142---ND------100143134/143 ---ND------200
144 ---ND------100
Page 19 of 53Report No.....10387444_1668A
Page 63 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Lab Sample ID 92338971002
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
145 ---ND------100146---ND------100
147 147/149 ---ND------200148---ND------100149147/149 ---ND------200
150 ---ND------100151135/151 ---ND------200152---ND------100
153 153/168 ---ND------200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100
161 ---ND------100162---ND------100163129/138/163 ---ND------300
164 ---ND------100165---ND------100166128/166 ---ND------200
167 ---ND------100168153/168 ---ND------200169---ND------100170---ND------100171171/173 ---ND------200172---ND------100173171/173 ---ND------200174---ND------100
175 ---ND------100176---ND------100177---ND------100
178 ---ND------100179---ND------100180180/193 1.04 21544.321 ---200181---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200
186 ---ND------1001871.08 12140.057 ---100188---ND------100
189 ---ND------100190---ND------100191---ND------100
192 ---ND------100
Page 20 of 53Report No.....10387444_1668A
Page 64 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Lab Sample ID 92338971002
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
193 180/193 1.04 (215)44.321 ---200194---ND------150
195 ---ND------150196---ND------150197197/200 ---ND------300
198 198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300
201 ---ND------150202---ND------150203---ND------150204---ND------150205---ND------150206---ND------150207---ND------150208---ND------150
209 ---ND------150
Page 21 of 53Report No.....10387444_1668A
Page 65 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-2
P170514A_09
Sample Analysis Results
Lab Sample ID 92338971002
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls ND
Total Heptachloro Biphenyls 336
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls ND
Decachloro Biphenyls ND
Total PCBs 336
Results reported on a dry weight basis
ND = Not Detected
Page 22 of 53Report No.....10387444_1668A
Page 66 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client - PACE Charlotte
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID BLANK-55516
P170514A_01
P170514A02
5.13 g
22.26.60 g
BAL
P170514A_10
92338971003
BERM-3
MatrixDilution
Collected
Received
Extracted
Analyzed 05/14/2017 09:33
05/09/2017 16:45
05/04/2017 09:30
05/02/2017 09:40
5Solid
Method 1668A Polychlorobiphenyl Sample Analysis Results
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 3.29 2.08.276 1.30 6513C-4-MoCB 3 3.16 2.010.887 1.39 7013C-2,2'-DiCB 4 1.49 2.011.163 1.35 6713C-4,4'-DiCB 15 1.55 2.017.978 1.50 7513C-2,2',6-TrCB 19 1.07 2.014.791 1.35 6813C-3,4,4'-TrCB 37 1.14 2.025.544 1.75 8713C-2,2',6,6'-TeCB 54 0.81 2.018.251 1.44 7213C-3,4,4',5-TeCB 81 0.83 2.032.591 1.66 8313C-3,3',4,4'-TeCB 77 0.83 2.033.212 1.63 8213C-2,2',4,6,6'-PeCB 104 1.59 2.024.170 1.35 6813C-2,3,3',4,4'-PeCB 105 1.59 2.036.721 1.82 9113C-2,3,4,4',5-PeCB 114 1.63 2.036.067 1.64 8213C-2,3',4,4',5-PeCB 118 1.56 2.035.531 1.68 8413C-2,3',4,4',5'-PeCB 123 1.55 2.035.195 1.80 9013C-3,3',4,4',5-PeCB 126 1.55 2.039.907 1.78 8913C-2,2',4,4',6,6'-HxCB 155 1.29 2.030.127 1.28 6413C-HxCB (156/157)156/157 1.28 4.042.930 3.37 8413C-2,3',4,4',5,5'-HxCB 167 1.32 2.041.773 1.67 8413C-3,3',4,4',5,5'-HxCB 169 1.27 2.046.250 1.88 9413C-2,2',3,4',5,6,6'-HpCB 188 1.05 2.036.000 1.29 6413C-2,3,3',4,4',5,5'-HpCB 189 1.07 2.048.736 1.74 8713C-2,2',3,3',5,5',6,6'-OcCB 202 0.91 2.041.471 1.48 7413C-2,3,3',4,4',5,5',6-OcCB 205 0.86 2.051.322 1.56 7813C-2,2',3,3',4,4',5,5',6-NoCB 206 0.79 2.053.197 1.40 7013C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.83 2.048.197 1.35 6813C--DeCB 209 0.71 2.055.137 1.35 68
Cleanup Standards13C-2,4,4'-TrCB 28 1.02 2.021.236 1.57 7813C-2,3,3',5,5'-PeCB 111 1.55 2.033.212 1.46 7313C-2,2',3,3',5,5',6-HpCB 178 1.04 2.039.119 1.35 68
Recovery Standards13C-2,5-DiCB 9 1.58 2.013.605 NA NA13C-2,2',5,5'-TeCB 52 0.79 2.023.197 NA NA13C-2,2',4,5,5'-PeCB 101 1.58 2.030.395 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.26 2.038.700 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.89 2.050.848 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a dry weight basis
Page 23 of 53Report No.....10387444_1668A
Page 67 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Lab Sample ID 92338971003
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.0
3 ---ND------50.04---ND------50.05---ND------50.0
6 ---ND------50.07---ND------50.08---ND------50.0
9 ---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------66.016---ND------50.0
17 ---ND------50.01818/30 ---ND------10019---ND------50.0
20 20/28 ---ND------2582121/33 ---ND------27022---ND------190
23 ---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------100
31 ---ND------26032---ND------50.03321/33 ---ND------270
34 ---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------300
42 ---ND------1004343/73 ---ND------1004444/47/65 ---ND------300
45 45/51 ---ND------20046---ND------1004744/47/65 ---ND------300
48 ---ND------100
Page 24 of 53Report No.....10387444_1668A
Page 68 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Lab Sample ID 92338971003
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
49 49/69 ---ND------2005050/53 ---ND------200
51 45/51 ---ND------20052---ND------3085350/53 ---ND------200
54 ---ND------10055---ND------10056---ND------100
57 ---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------100
65 44/47/65 ---ND------30066---ND------16867---ND------100
68 ---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------400
71 40/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------100
79 ---ND------10080---ND------10081---ND------100
82 ---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------100
90 90/101/113 ---ND------3009188/91 ---ND------20092---ND------100
93 93/98/100/102 ---ND------40094---ND------10095---ND------190
96 ---ND------100
Page 25 of 53Report No.....10387444_1668A
Page 69 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Lab Sample ID 92338971003
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
97 86/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------400
99 ---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------300
102 93/98/100/102 ---ND------400103---ND------100104---ND------100
105 ---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------100
113 90/101/113 ---ND------300114---ND------100115110/115 ---ND------200
116 85/116/117 ---ND------30011785/116/117 ---ND------300118---ND------128
119 86/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100
127 ---ND------100128128/166 ---ND------200129129/138/163 1.25 64238.716 ---300
130 ---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200136---ND------100137---ND------100
138 129/138/163 1.25 (642)38.716 ---300139139/140 ---ND------200140139/140 ---ND------200
141 ---ND------100142---ND------100143134/143 ---ND------200
144 ---ND------100
Page 26 of 53Report No.....10387444_1668A
Page 70 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Lab Sample ID 92338971003
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
145 ---ND------100146---ND------100
147 147/149 1.24 28434.340 ---200148---ND------100149147/149 1.24 (284)34.340 ---200
150 ---ND------100151135/151 ---ND------200152---ND------100
153 153/168 1.19 37337.442 ---200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100
161 ---ND------100162---ND------100163129/138/163 1.25 (642)38.716 ---300
164 ---ND------100165---ND------100166128/166 ---ND------200
167 ---ND------100168153/168 1.19 (373)37.442 ---200169---ND------1001701.01 24245.612 ---100171171/173 ---ND------200172---ND------100173171/173 ---ND------2001741.07 25140.951 ---100
175 ---ND------100176---ND------1001770.94 15241.404 ---100
178 ---ND------100179---ND------100180180/193 1.02 56644.338 ---200181---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200
186 ---ND------1001871.06 32740.074 ---100188---ND------100
189 ---ND------100190---ND------100191---ND------100
192 ---ND------100
Page 27 of 53Report No.....10387444_1668A
Page 71 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Lab Sample ID 92338971003
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
193 180/193 1.02 (566)44.338 ---200194---ND------150
195 ---ND------150196---ND------150197197/200 ---ND------300
198 198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300
201 ---ND------150202---ND------150203---ND------150204---ND------150205---ND------1502060.79 22253.219 ---150207---ND------150208---ND------150
209 0.69 21355.180 ---150
Page 28 of 53Report No.....10387444_1668A
Page 72 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-3
P170514A_10
Sample Analysis Results
Lab Sample ID 92338971003
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls 1300
Total Heptachloro Biphenyls 1540
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls 222
Decachloro Biphenyls 213
Total PCBs 3270
Results reported on a dry weight basis
ND = Not Detected
Page 29 of 53Report No.....10387444_1668A
Page 73 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client - PACE Charlotte
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID BLANK-55516
P170514A_01
P170514A02
5.24 g
18.26.40 g
BAL
P170514A_11
92338971004
BERM-4
MatrixDilution
Collected
Received
Extracted
Analyzed 05/14/2017 10:32
05/09/2017 16:45
05/04/2017 09:30
05/02/2017 09:55
5Solid
Method 1668A Polychlorobiphenyl Sample Analysis Results
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 2.66 2.08.264 1.38 6913C-4-MoCB 3 2.69 2.010.863 1.42 7113C-2,2'-DiCB 4 1.47 2.011.127 1.31 6613C-4,4'-DiCB 15 1.57 2.017.906 1.46 7313C-2,2',6-TrCB 19 1.09 2.014.731 1.33 6613C-3,4,4'-TrCB 37 1.09 2.025.511 1.56 7813C-2,2',6,6'-TeCB 54 0.80 2.018.201 1.30 6513C-3,4,4',5-TeCB 81 0.82 2.032.558 1.55 7813C-3,3',4,4'-TeCB 77 0.79 2.033.161 1.55 7713C-2,2',4,6,6'-PeCB 104 1.59 2.024.153 1.38 6913C-2,3,3',4,4'-PeCB 105 1.55 2.036.704 1.72 8613C-2,3,4,4',5-PeCB 114 1.54 2.036.050 1.61 8113C-2,3',4,4',5-PeCB 118 1.64 2.035.514 1.63 8213C-2,3',4,4',5'-PeCB 123 1.53 2.035.179 1.65 8313C-3,3',4,4',5-PeCB 126 1.64 2.039.890 1.79 9013C-2,2',4,4',6,6'-HxCB 155 1.29 2.030.110 1.34 6713C-HxCB (156/157)156/157 1.29 4.042.930 3.38 8413C-2,3',4,4',5,5'-HxCB 167 1.28 2.041.739 1.73 8613C-3,3',4,4',5,5'-HxCB 169 1.27 2.046.233 2.04 10213C-2,2',3,4',5,6,6'-HpCB 188 1.07 2.035.983 1.30 6513C-2,3,3',4,4',5,5'-HpCB 189 1.10 2.048.736 1.81 9113C-2,2',3,3',5,5',6,6'-OcCB 202 0.90 2.041.438 1.40 7013C-2,3,3',4,4',5,5',6-OcCB 205 0.92 2.051.300 1.61 8113C-2,2',3,3',4,4',5,5',6-NoCB 206 0.80 2.053.175 1.39 6913C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.78 2.048.197 1.37 6813C--DeCB 209 0.71 2.055.115 1.46 73
Cleanup Standards13C-2,4,4'-TrCB 28 1.02 2.021.219 1.56 7813C-2,3,3',5,5'-PeCB 111 1.57 2.033.161 1.46 7313C-2,2',3,3',5,5',6-HpCB 178 1.03 2.039.119 1.47 73
Recovery Standards13C-2,5-DiCB 9 1.55 2.013.485 NA NA13C-2,2',5,5'-TeCB 52 0.79 2.023.163 NA NA13C-2,2',4,5,5'-PeCB 101 1.64 2.030.378 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.26 2.038.683 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.90 2.050.826 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a dry weight basis
Page 30 of 53Report No.....10387444_1668A
Page 74 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Lab Sample ID 92338971004
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.0
3 ---ND------50.04---ND------50.05---ND------50.0
6 ---ND------50.07---ND------50.08---ND------50.0
9 ---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------66.016---ND------50.0
17 ---ND------50.01818/30 ---ND------10019---ND------50.0
20 20/28 ---ND------2582121/33 ---ND------27022---ND------190
23 ---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------100
31 ---ND------26032---ND------50.03321/33 ---ND------270
34 ---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------300
42 ---ND------1004343/73 ---ND------1004444/47/65 ---ND------300
45 45/51 ---ND------20046---ND------1004744/47/65 ---ND------300
48 ---ND------100
Page 31 of 53Report No.....10387444_1668A
Page 75 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Lab Sample ID 92338971004
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
49 49/69 ---ND------2005050/53 ---ND------200
51 45/51 ---ND------20052---ND------3085350/53 ---ND------200
54 ---ND------10055---ND------10056---ND------100
57 ---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------100
65 44/47/65 ---ND------30066---ND------16867---ND------100
68 ---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------400
71 40/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------100
79 ---ND------10080---ND------10081---ND------100
82 ---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------100
90 90/101/113 ---ND------3009188/91 ---ND------20092---ND------100
93 93/98/100/102 ---ND------40094---ND------10095---ND------190
96 ---ND------100
Page 32 of 53Report No.....10387444_1668A
Page 76 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Lab Sample ID 92338971004
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
97 86/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------400
99 ---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------300
102 93/98/100/102 ---ND------400103---ND------100104---ND------100
105 ---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------100
113 90/101/113 ---ND------300114---ND------100115110/115 ---ND------200
116 85/116/117 ---ND------30011785/116/117 ---ND------300118---ND------128
119 86/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100
127 ---ND------100128128/166 ---ND------200129129/138/163 ---ND------300
130 ---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200136---ND------100137---ND------100
138 129/138/163 ---ND------300139139/140 ---ND------200140139/140 ---ND------200
141 ---ND------100142---ND------100143134/143 ---ND------200
144 ---ND------100
Page 33 of 53Report No.....10387444_1668A
Page 77 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Lab Sample ID 92338971004
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
145 ---ND------100146---ND------100
147 147/149 ---ND------200148---ND------100149147/149 ---ND------200
150 ---ND------100151135/151 ---ND------200152---ND------100
153 153/168 ---ND------200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100
161 ---ND------100162---ND------100163129/138/163 ---ND------300
164 ---ND------100165---ND------100166128/166 ---ND------200
167 ---ND------100168153/168 ---ND------200169---ND------100170---ND------100171171/173 ---ND------200172---ND------100173171/173 ---ND------200174---ND------100
175 ---ND------100176---ND------100177---ND------100
178 ---ND------100179---ND------100180180/193 ---ND------200181---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200
186 ---ND------100187---ND------100188---ND------100
189 ---ND------100190---ND------100191---ND------100
192 ---ND------100
Page 34 of 53Report No.....10387444_1668A
Page 78 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Lab Sample ID 92338971004
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
193 180/193 ---ND------200194---ND------150
195 ---ND------150196---ND------150197197/200 ---ND------300
198 198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300
201 ---ND------150202---ND------150203---ND------150204---ND------150205---ND------150206---ND------150207---ND------150208---ND------150
209 ---ND------150
Page 35 of 53Report No.....10387444_1668A
Page 79 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-4
P170514A_11
Sample Analysis Results
Lab Sample ID 92338971004
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls ND
Total Heptachloro Biphenyls ND
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls ND
Decachloro Biphenyls ND
Total PCBs ND
Results reported on a dry weight basis
ND = Not Detected
Page 36 of 53Report No.....10387444_1668A
Page 80 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client - PACE Charlotte
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID BLANK-55516
P170514A_01
P170514A02
5.04 g
22.46.50 g
BAL
P170514A_12
92338971005
BERM-5
MatrixDilution
Collected
Received
Extracted
Analyzed 05/14/2017 11:31
05/09/2017 16:45
05/04/2017 09:30
05/02/2017 10:10
5Solid
Method 1668A Polychlorobiphenyl Sample Analysis Results
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 3.33 2.08.264 1.16 5813C-4-MoCB 3 2.69 2.010.863 1.33 6613C-2,2'-DiCB 4 1.51 2.011.127 1.24 6213C-4,4'-DiCB 15 1.64 2.017.918 1.52 7613C-2,2',6-TrCB 19 1.11 2.014.731 1.34 6713C-3,4,4'-TrCB 37 1.06 2.025.528 1.74 8713C-2,2',6,6'-TeCB 54 0.82 2.018.201 1.45 7313C-3,4,4',5-TeCB 81 0.80 2.032.592 1.66 8313C-3,3',4,4'-TeCB 77 0.81 2.033.179 1.67 8313C-2,2',4,6,6'-PeCB 104 1.62 2.024.170 1.42 7113C-2,3,3',4,4'-PeCB 105 1.71 2.036.721 1.84 9213C-2,3,4,4',5-PeCB 114 1.55 2.036.068 1.69 8513C-2,3',4,4',5-PeCB 118 1.54 2.035.514 1.70 8513C-2,3',4,4',5'-PeCB 123 1.60 2.035.179 1.75 8813C-3,3',4,4',5-PeCB 126 1.62 2.039.907 1.92 9613C-2,2',4,4',6,6'-HxCB 155 1.27 2.030.127 1.38 6913C-HxCB (156/157)156/157 1.23 4.042.947 3.76 9413C-2,3',4,4',5,5'-HxCB 167 1.23 2.041.757 1.82 9113C-3,3',4,4',5,5'-HxCB 169 1.27 2.046.233 2.18 10913C-2,2',3,4',5,6,6'-HpCB 188 1.03 2.036.000 1.29 6413C-2,3,3',4,4',5,5'-HpCB 189 1.09 2.048.758 1.96 9813C-2,2',3,3',5,5',6,6'-OcCB 202 0.93 2.041.455 1.41 7113C-2,3,3',4,4',5,5',6-OcCB 205 0.89 2.051.322 1.75 8713C-2,2',3,3',4,4',5,5',6-NoCB 206 0.82 2.053.197 1.48 7413C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.79 2.048.198 1.41 7013C--DeCB 209 0.75 2.055.137 1.46 73
Cleanup Standards13C-2,4,4'-TrCB 28 1.03 2.021.219 1.73 8613C-2,3,3',5,5'-PeCB 111 1.59 2.033.195 1.47 7313C-2,2',3,3',5,5',6-HpCB 178 1.06 2.039.119 1.52 76
Recovery Standards13C-2,5-DiCB 9 1.64 2.013.449 NA NA13C-2,2',5,5'-TeCB 52 0.82 2.023.180 NA NA13C-2,2',4,5,5'-PeCB 101 1.61 2.030.395 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.27 2.038.683 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.90 2.050.827 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a dry weight basis
Page 37 of 53Report No.....10387444_1668A
Page 81 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Lab Sample ID 92338971005
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.0
3 ---ND------50.04---ND------50.05---ND------50.0
6 ---ND------50.07---ND------50.08---ND------50.0
9 ---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------66.016---ND------50.0
17 ---ND------50.01818/30 ---ND------10019---ND------50.0
20 20/28 ---ND------2582121/33 ---ND------27022---ND------190
23 ---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------100
31 ---ND------26032---ND------50.03321/33 ---ND------270
34 ---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------300
42 ---ND------1004343/73 ---ND------1004444/47/65 ---ND------300
45 45/51 ---ND------20046---ND------1004744/47/65 ---ND------300
48 ---ND------100
Page 38 of 53Report No.....10387444_1668A
Page 82 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Lab Sample ID 92338971005
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
49 49/69 ---ND------2005050/53 ---ND------200
51 45/51 ---ND------20052---ND------3085350/53 ---ND------200
54 ---ND------10055---ND------10056---ND------100
57 ---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------100
65 44/47/65 ---ND------30066---ND------16867---ND------100
68 ---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------400
71 40/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------100
79 ---ND------10080---ND------10081---ND------100
82 ---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------100
90 90/101/113 ---ND------3009188/91 ---ND------20092---ND------100
93 93/98/100/102 ---ND------40094---ND------10095---ND------190
96 ---ND------100
Page 39 of 53Report No.....10387444_1668A
Page 83 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Lab Sample ID 92338971005
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
97 86/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------400
99 ---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------300
102 93/98/100/102 ---ND------400103---ND------100104---ND------100
105 ---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------100
113 90/101/113 ---ND------300114---ND------100115110/115 ---ND------200
116 85/116/117 ---ND------30011785/116/117 ---ND------300118---ND------128
119 86/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100
127 ---ND------100128128/166 ---ND------200129129/138/163 ---ND------300
130 ---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200136---ND------100137---ND------100
138 129/138/163 ---ND------300139139/140 ---ND------200140139/140 ---ND------200
141 ---ND------100142---ND------100143134/143 ---ND------200
144 ---ND------100
Page 40 of 53Report No.....10387444_1668A
Page 84 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Lab Sample ID 92338971005
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
145 ---ND------100146---ND------100
147 147/149 ---ND------200148---ND------100149147/149 ---ND------200
150 ---ND------100151135/151 ---ND------200152---ND------100
153 153/168 ---ND------200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100
161 ---ND------100162---ND------100163129/138/163 ---ND------300
164 ---ND------100165---ND------100166128/166 ---ND------200
167 ---ND------100168153/168 ---ND------200169---ND------100170---ND------100171171/173 ---ND------200172---ND------100173171/173 ---ND------200174---ND------100
175 ---ND------100176---ND------100177---ND------100
178 ---ND------100179---ND------100180180/193 ---ND------200181---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200
186 ---ND------100187---ND------100188---ND------100
189 ---ND------100190---ND------100191---ND------100
192 ---ND------100
Page 41 of 53Report No.....10387444_1668A
Page 85 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
Results reported on a dry weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = Nanograms
Sample Analysis Results
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Lab Sample ID 92338971005
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
193 180/193 ---ND------200194---ND------150
195 ---ND------150196---ND------150197197/200 ---ND------300
198 198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300
201 ---ND------150202---ND------150203---ND------150204---ND------150205---ND------150206---ND------150207---ND------150208---ND------150
209 ---ND------150
Page 42 of 53Report No.....10387444_1668A
Page 86 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
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Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
BERM-5
P170514A_12
Sample Analysis Results
Lab Sample ID 92338971005
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls ND
Total Heptachloro Biphenyls ND
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls ND
Decachloro Biphenyls ND
Total PCBs ND
Results reported on a dry weight basis
ND = Not Detected
Page 43 of 53Report No.....10387444_1668A
Page 87 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Lab Sample ID
Injected By
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
BLANK-55516
P170513A_06
BAL10.2 g
P170513A02
P170513A_01
MatrixExtracted
Analyzed
Solid05/09/2017 16:45
05/13/2017 15:53
Blank Analysis Results
Dilution 5
PCB Isomer RT % Recoveryng's Foundng's AddedIUPACRatio
Labeled Analytes13C-2-MoCB 1 3.07 2.08.252 1.40 7013C-4-MoCB 3 3.50 2.010.875 1.35 6713C-2,2'-DiCB 4 1.63 2.011.151 1.27 6413C-4,4'-DiCB 15 1.54 2.017.990 1.47 7313C-2,2',6-TrCB 19 1.05 2.014.767 1.33 6613C-3,4,4'-TrCB 37 1.08 2.025.511 1.74 8713C-2,2',6,6'-TeCB 54 0.78 2.018.251 1.58 7913C-3,4,4',5-TeCB 81 0.81 2.032.560 1.63 8113C-3,3',4,4'-TeCB 77 0.78 2.033.247 1.71 8613C-2,2',4,6,6'-PeCB 104 1.55 2.024.153 1.48 7413C-2,3,3',4,4'-PeCB 105 1.53 2.036.706 1.91 9613C-2,3,4,4',5-PeCB 114 1.61 2.036.052 1.75 8813C-2,3',4,4',5-PeCB 118 1.57 2.035.516 1.72 8613C-2,3',4,4',5'-PeCB 123 1.57 2.035.164 1.85 9313C-3,3',4,4',5-PeCB 126 1.58 2.039.875 1.89 9513C-2,2',4,4',6,6'-HxCB 155 1.27 2.030.111 1.27 6413C-HxCB (156/157)156/157 1.21 4.042.915 3.45 8613C-2,3',4,4',5,5'-HxCB 167 1.24 2.041.725 1.66 8313C-3,3',4,4',5,5'-HxCB 169 1.25 2.046.218 1.95 9813C-2,2',3,4',5,6,6'-HpCB 188 1.08 2.035.985 1.19 6013C-2,3,3',4,4',5,5'-HpCB 189 1.02 2.048.717 1.75 8713C-2,2',3,3',5,5',6,6'-OcCB 202 0.90 2.041.440 1.39 6913C-2,3,3',4,4',5,5',6-OcCB 205 0.83 2.051.304 1.67 8313C-2,2',3,3',4,4',5,5',6-NoCB 206 0.85 2.053.179 1.39 7013C-2,2',3,3',4,5,5',6,6'-NoCB 208 0.77 2.048.178 1.31 6613C--DeCB 209 0.70 2.055.097 1.46 73
Cleanup Standards13C-2,4,4'-TrCB 28 1.05 2.021.219 1.68 8413C-2,3,3',5,5'-PeCB 111 1.56 2.033.230 1.61 8013C-2,2',3,3',5,5',6-HpCB 178 1.08 2.039.104 1.37 69
Recovery Standards13C-2,5-DiCB 9 1.57 2.013.557 NA NA13C-2,2',5,5'-TeCB 52 0.82 2.023.164 NA NA13C-2,2',4,5,5'-PeCB 101 1.59 2.030.380 NA NA13C-2,2',3,4,4',5'-HxCB 138 1.22 2.038.651 NA NA13C-2,2',3,3',4,4',5,5'-OcCB 194 0.87 2.050.808 NA NA
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
Nn = Value obtained from additional analyses
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
ng's = NanogramsResults reported on a total weight basis
Page 44 of 53Report No.....10387444_1668A
Page 88 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
ng/L = Nanograms per liter
Results reported on a total weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
Method 1668A Polychlorobiphenyl
Lab Sample ID
Filename
BLANK-55516
P170513A_06
Blank Analysis Results
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
1 ---ND------50.02---ND------50.03---ND------50.04---ND------50.05---ND------50.06---ND------50.07---ND------50.08---ND------50.09---ND------50.010---ND------50.011---ND------4901212/13 ---ND------1001312/13 ---ND------10014---ND------50.015---ND------50.016---ND------50.017---ND------50.01818/30 ---ND------10019---ND------50.02020/28 ---ND------2582121/33 ---ND------27022---ND------19023---ND------50.024---ND------50.025---ND------50.02626/29 ---ND------10027---ND------50.02820/28 ---ND------2582926/29 ---ND------1003018/30 ---ND------10031---ND------26032---ND------50.03321/33 ---ND------27034---ND------50.035---ND------50.036---ND------50.037---ND------10638---ND------50.039---ND------50.04040/41/71 ---ND------3004140/41/71 ---ND------30042---ND------1004343/73 ---ND------1004444/47/65 ---ND------3004545/51 ---ND------200
Page 45 of 53Report No.....10387444_1668A
Page 89 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
ng/L = Nanograms per liter
Results reported on a total weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
Method 1668A Polychlorobiphenyl
Lab Sample ID
Filename
BLANK-55516
P170513A_06
Blank Analysis Results
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
46 ---ND------1004744/47/65 ---ND------30048---ND------1004949/69 ---ND------2005050/53 ---ND------2005145/51 ---ND------20052---ND------3085350/53 ---ND------20054---ND------10055---ND------10056---ND------10057---ND------10058---ND------1005959/62/75 ---ND------30060---ND------1006161/70/74/76 ---ND------4006259/62/75 ---ND------30063---ND------10064---ND------1006544/47/65 ---ND------30066---ND------16867---ND------10068---ND------1006949/69 ---ND------2007061/70/74/76 ---ND------4007140/41/71 ---ND------30072---ND------1007343/73 ---ND------1007461/70/74/76 ---ND------4007559/62/75 ---ND------3007661/70/74/76 ---ND------40077---ND------10078---ND------10079---ND------10080---ND------10081---ND------10082---ND------10083---ND------10084---ND------1008585/116/117 ---ND------3008686/87/97/108/119/125 ---ND------6008786/87/97/108/119/125 ---ND------6008888/91 ---ND------20089---ND------1009090/101/113 ---ND------300
Page 46 of 53Report No.....10387444_1668A
Page 90 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
ng/L = Nanograms per liter
Results reported on a total weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
Method 1668A Polychlorobiphenyl
Lab Sample ID
Filename
BLANK-55516
P170513A_06
Blank Analysis Results
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
91 88/91 ---ND------20092---ND------1009393/98/100/102 ---ND------40094---ND------10095---ND------19096---ND------1009786/87/97/108/119/125 ---ND------6009893/98/100/102 ---ND------40099---ND------10010093/98/100/102 ---ND------40010190/101/113 ---ND------30010293/98/100/102 ---ND------400103---ND------100104---ND------100105---ND------100106---ND------100107107/124 ---ND------20010886/87/97/108/119/125 ---ND------600109---ND------100110110/115 ---ND------200111---ND------100112---ND------10011390/101/113 ---ND------300114---ND------100115110/115 ---ND------20011685/116/117 ---ND------30011785/116/117 ---ND------300118---ND------12811986/87/97/108/119/125 ---ND------600120---ND------100121---ND------100122---ND------100123---ND------100124107/124 ---ND------20012586/87/97/108/119/125 ---ND------600126---ND------100127---ND------100128128/166 ---ND------200129129/138/163 ---ND------300130---ND------100131---ND------100132---ND------100133---ND------100134134/143 ---ND------200135135/151 ---ND------200
Page 47 of 53Report No.....10387444_1668A
Page 91 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
ng/L = Nanograms per liter
Results reported on a total weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
Method 1668A Polychlorobiphenyl
Lab Sample ID
Filename
BLANK-55516
P170513A_06
Blank Analysis Results
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
136 ---ND------100137---ND------100138129/138/163 ---ND------300139139/140 ---ND------200140139/140 ---ND------200141---ND------100142---ND------100143134/143 ---ND------200144---ND------100145---ND------100146---ND------100147147/149 ---ND------200148---ND------100149147/149 ---ND------200150---ND------100151135/151 ---ND------200152---ND------100153153/168 ---ND------200154---ND------100155---ND------100156156/157 ---ND------200157156/157 ---ND------200158---ND------100159---ND------100160---ND------100161---ND------100162---ND------100163129/138/163 ---ND------300164---ND------100165---ND------100166128/166 ---ND------200167---ND------100168153/168 ---ND------200169---ND------100170---ND------100171171/173 ---ND------200172---ND------100173171/173 ---ND------200174---ND------100175---ND------100176---ND------100177---ND------100178---ND------100179---ND------100180180/193 ---ND------200
Page 48 of 53Report No.....10387444_1668A
Page 92 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Conc = Concentration
EML =Method Specified Reporting Limit (1668A)
EMPC = Estimated Maximum Possible Concentration
A = Limit of Detection based on signal to noise
B = Less than 10 times higher than method blank level
R = Recovery outside of Method 1668A control limits
ng/L = Nanograms per liter
Results reported on a total weight basis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
X = Outside QC Limits
RT = Retention Time
I = Interference
Method 1668A Polychlorobiphenyl
Lab Sample ID
Filename
BLANK-55516
P170513A_06
Blank Analysis Results
Co-elutions RT ng/Kg
EMLEMPCConcentration
ng/KgIUPACRatio ng/Kg
181 ---ND------100182---ND------100183183/185 ---ND------200184---ND------100185183/185 ---ND------200186---ND------100187---ND------100188---ND------100189---ND------100190---ND------100191---ND------100192---ND------100193180/193 ---ND------200194---ND------150195---ND------150196---ND------150197197/200 ---ND------300198198/199 ---ND------300199198/199 ---ND------300200197/200 ---ND------300201---ND------150202---ND------150203---ND------150204---ND------150205---ND------150206---ND------150207---ND------150208---ND------150209---ND------150
Page 49 of 53Report No.....10387444_1668A
Page 93 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyl
Client Sample ID
Filename
CBLKES
P170513A_06
Blank Analysis Results
Lab Sample ID BLANK-55516
Congener Group
Concentration
ng/Kg
Total Monochloro Biphenyls ND
Total Dichloro Biphenyls ND
Total Trichloro Biphenyls ND
Total Tetrachloro Biphenyls ND
Total Pentachloro Biphenyls ND
Total Hexachloro Biphenyls ND
Total Heptachloro Biphenyls ND
Total Octachloro Biphenyls ND
Total Nonachloro Biphenyls ND
Decachloro Biphenyls ND
Total PCBs ND
Results reported on a total weight basis
ND = Not Detected
Page 50 of 53Report No.....10387444_1668A
Page 94 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyls
Lab Sample ID
Injected By
FilenameTotal Amount Extracted
ICAL ID
CCal Filename(s)
LCS-55517
P170513A_03
BAL
10.1 g
P170513A02
P170513A_01
MatrixDilution
Extracted
Analyzed
Solid
05/09/2017 16:45
05/13/2017 12:57
5
Method Blank ID BLANK-55516
Laboratory Control Spike Analysis Results
PCB Spiked Found Spiked Found %
RecoveryIsomer(ng)(ng)
%
Recovery(ng)(ng)
Native Analytes Labeled Analytes
1 1.0 1.01 2.0 1.48 74101
3 1.0 0.999 2.0 1.47 73100
4 1.0 0.971 2.0 1.48 7497151.0 0.917 2.0 1.53 7792
19 1.0 0.948 2.0 1.45 7295
37 1.0 0.963 2.0 1.85 9296
54 1.0 1.03 2.0 1.66 83103
81 1.0 0.960 2.0 1.87 9396771.0 0.982 2.0 1.91 9598
104 1.0 1.03 2.0 1.54 77103
105 1.0 1.02 2.0 2.08 104102
114 1.0 1.02 2.0 1.88 94102
118 1.0 1.00 2.0 1.92 961001231.0 1.04 2.0 2.07 104104
126 1.0 0.993 2.0 2.08 10499
155 1.0 0.997 2.0 1.34 67100
156/157 2.0 2.02 4.0 3.63 91101
167 1.0 0.991 2.0 1.76 88991691.0 1.02 2.0 2.14 107102
188 1.0 1.03 2.0 1.27 63103
189 1.0 1.03 2.0 1.85 92103
202 1.0 0.987 2.0 1.45 7399
205 1.0 0.972 2.0 1.68 84972061.0 1.04 2.0 1.41 71104
208 1.0 1.03 2.0 1.39 70103
209 1.0 0.930 2.0 1.50 7593
R = Recovery outside of method 1668A control limits
Nn = Result obtained from alternate analysis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
ng = Nanograms
I = Interference
Page 51 of 53Report No.....10387444_1668A
Page 95 of 97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Method 1668A Polychlorobiphenyls
Lab Sample ID
Injected By
FilenameTotal Amount Extracted
ICAL ID
CCal Filename(s)
LCSD-55518
P170513A_04
BAL
10.4 g
P170513A02
P170513A_01
MatrixDilution
Extracted
Analyzed
Solid
05/09/2017 16:45
05/13/2017 13:56
5
Method Blank ID BLANK-55516
Laboratory Control Spike Analysis Results
PCB Spiked Found Spiked Found %
RecoveryIsomer(ng)(ng)
%
Recovery(ng)(ng)
Native Analytes Labeled Analytes
1 1.0 0.996 2.0 1.67 84100
3 1.0 0.958 2.0 1.59 8096
4 1.0 0.998 2.0 1.57 78100151.0 1.02 2.0 1.70 85102
19 1.0 0.968 2.0 1.54 7797
37 1.0 0.959 2.0 1.85 9296
54 1.0 0.992 2.0 1.74 8799
81 1.0 0.989 2.0 1.88 9499771.0 0.988 2.0 1.88 9499
104 1.0 1.03 2.0 1.56 78103
105 1.0 1.08 2.0 1.93 97108
114 1.0 1.07 2.0 1.83 91107
118 1.0 1.07 2.0 1.84 921071231.0 1.04 2.0 1.97 99104
126 1.0 1.06 2.0 2.02 101106
155 1.0 1.03 2.0 1.38 69103
156/157 2.0 2.00 4.0 3.78 95100
167 1.0 0.999 2.0 1.82 911001691.0 0.978 2.0 2.21 11098
188 1.0 1.06 2.0 1.31 65106
189 1.0 1.04 2.0 1.94 97104
202 1.0 0.972 2.0 1.50 7597
205 1.0 1.00 2.0 1.78 891002061.0 1.01 2.0 1.57 79101
208 1.0 1.03 2.0 1.51 76103
209 1.0 0.932 2.0 1.63 8193
R = Recovery outside of method 1668A control limits
Nn = Result obtained from alternate analysis
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
* = See Discussion
ng = Nanograms
I = Interference
Page 52 of 53Report No.....10387444_1668A
Page 96 of 97
REPORT OF LABORATORY ANALYSIS
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1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Client
Spike 1 ID
Spike 1 Filename P170513A_03
LCS-55517
PACE Charlotte
Spike Recovery Relative Percent Difference (RPD) Results
Spike 2 ID
Spike 2 Filename P170513A_04
LCSD-55518
Method 1668A
Spike 1 Spike 2
Compound %REC %REC %RPDIUPAC
2-MoCB 101 100 1.014-MoCB 100 96 4.132,2'-DiCB 97 100 3.044,4'-DiCB 92 102 10.3152,2',6-TrCB 95 97 2.1193,4,4'-TrCB 96 96 0.0372,2',6,6'-TeCB 103 99 4.0543,3',4,4'-TeCB 98 99 1.0773,4,4',5-TeCB 96 99 3.1812,2',4,6,6'-PeCB 103 103 0.01042,3,3',4,4'-PeCB 102 108 5.71052,3,4,4',5-PeCB 102 107 4.81142,3',4,4',5-PeCB 100 107 6.81182,3',4,4',5'-PeCB 104 104 0.01233,3',4,4',5-PeCB 99 106 6.81262,2',4,4',6,6'-HxCB 100 103 3.0155(156/157)101 100 1.0156/1572,3',4,4',5,5'-HxCB 99 100 1.01673,3',4,4',5,5'-HxCB 102 98 4.01692,2',3,4',5,6,6'-HpCB 103 106 2.91882,3,3',4,4',5,5'-HpCB 103 104 1.01892,2',3,3',5,5',6,6'-OcCB 99 97 2.02022,3,3',4,4',5,5',6-OcCB 97 100 3.02052,2',3,3',4,4',5,5',6-NoCB 104 101 2.92062,2',3,3',4,5,5',6,6'-NoCB 103 103 0.0208Decachlorobiphenyl93930.0209
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
Page 53 of 53Report No.....10387444_1668A
Page 97 of 97