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Home My WebLink About5603_IAC_GWMR_DIN27947_20161201 Prepared for ABF Environmental 28200 Orchard Lake Road, Suite 101 Farmington Hills, Michigan 48334 Project Number 2679.01 Prepared by Altamont Environmental, Inc. 231 Haywood Street Asheville, NC 28801 828.281.3350 Fall 2016 Water Quality Monitoring Report Old Fort Industrial Solid Waste Landfill McDowell County, North Carolina Permit #56-03 December 28, 2016 Fall 2016 Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page iii P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx Table of Contents 1.0 Introduction .................................................................................................................... 1 2.0 Methods ......................................................................................................................... 2 2.1 Groundwater and Surface Water Sampling ...................................................................2 2.1.1 Groundwater Purging and Sampling Methods ..................................................2 2.1.2 Surface Water Sampling Methods ....................................................................2 2.2 Sample Handling, Documentation, and Analysis...........................................................3 3.0 Findings .......................................................................................................................... 4 3.1 Groundwater Samples ...................................................................................................4 3.1.1 RCRA Metals .....................................................................................................4 3.1.2 Field Parameters ...............................................................................................4 3.2 Surface Water Samples .................................................................................................4 3.2.1 RCRA Metals .....................................................................................................4 3.2.2 Field Parameters ...............................................................................................4 4.0 Summary ........................................................................................................................ 6 4.1 Future Activities .............................................................................................................6 5.0 References ..................................................................................................................... 7 Figures 1. Site Location Map 2. Sample Location Map Tables 1. Summary of Laboratory Analyses Performed on Samples 2. Summary of Analytical Results Appendices A. Sampling Field Logs and Instrument Calibration Data Sheet B. Report of Laboratory Analysis and Chain-of-Custody Documentation C. Environmental Monitoring Reporting Form and Electronic Submittal of Environmental Monitoring Data 5603Dec2016 Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 1 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 1.0 Introduction The International Automotive Components (IAC) Group North America owns and manages the Old Fort Industrial Solid Waste Landfill (Old Fort Landfill, Site) located on State Road 1240 in Old Fort, McDowell County, North Carolina (Figure 1). The landfill is approximately 86 acres in size and is located approximately 5 miles southeast from the IAC plant. Previously, the landfill was owned and operated by Collins & Aikman (C&A) for the disposal of solid waste related to carpet products. In 2007, IAC acquired the landfill and has not utilized it for waste disposal since the acquisition. IAC has subsequently closed the Old Fort Landfill. As a result, a Revised Workplan for Landfill Investigation and Closure (dated November 4, 2010) and a Final Investigation Report (dated June 7, 2011) were prepared by the consulting firm RJN Environmental, Inc. to initiate landfill closure activities. The Final Investigation Report summarizes landfill closure investigation procedures, completed activities, and sampled media analytical results. State regulations applicable to landfills are enforced by the North Carolina Department of Environmental Quality (DEQ, formerly known as the Department of Environment and Natural Resources [DENR]), Division of Waste Management (DWM). The subject landfill is permitted by the DEQ DWM under Permit No. 56-03. This report is being submitted in general accordance with: (1) our proposal to ABF Environmental dated November 4, 2016 and (2) requirements stipulated in the DEQ Solid Waste Management Rules Title 15A, Subchapter 13B, Section .0500, of the North Carolina Administrative Code (15A NCAC 13B.0500). The water quality monitoring network for the Old Fort Landfill consists of four compliance monitoring wells (MW-1, MW-2, MW-3, and MW-4) and four surface water sampling locations (SW-1, SW-2, SW-3, and SW-4) collected from various tributaries and drainage points on-Site. This Fall 2016 Semiannual Water Quality Report (Report) describes the groundwater and surface water quality sampling event performed on December 1, 2016. Samples associated with the landfill were collected by personnel from Altamont Environmental, Inc. (Altamont), and analyzed by Pace Analytical Services, Inc. (Pace). This water quality monitoring report was prepared by Altamont. Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 2 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 2.0 Methods 2.1 Groundwater and Surface Water Sampling Old Fort Landfill monitoring wells (MW-1, MW-2, MW-3, and MW-4) and surface water sample locations (SW-1, SW-2, SW-3, and SW-4) were sampled by Altamont personnel on December 1, 2016 (Table 1). MW- 1A, located adjacent to MW-1, was not sampled during this event. Approximate sample locations are depicted on Figure 2. Table 1 provides a summary of all groundwater and surface water samples that were collected and the analyses performed on each sample. Field sampling logs are included in Appendix A. 2.1.1 Groundwater Purging and Sampling Methods Monitoring wells MW-1, MW-3, and MW-4 were purged and sampled using low-flow techniques in accordance with the procedures described in “Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures” (Groundwater Issues [Environmental Protection Agency (EPA)], April 1996). During purging, the pH, specific conductivity, dissolved oxygen (DO), oxidation reduction potential (ORP), turbidity, and temperature were measured and recorded approximately every 3 minutes. Well purging continued until these parameters stabilized, as determined by three successive readings in which each parameter was within a range of values, as follows:  pH +/- 0.1 unit  Specific conductivity +/- 3 percent  Temperature +/- 10 percent  DO +/- 10 percent  Turbidity +/- 10 percent  ORP +/- 10 millivolts Once these parameters stabilized, a groundwater sample was collected in laboratory-supplied sample containers by Altamont technicians wearing new pairs of nitrile gloves. Monitoring well MW-2 was purged and sampled using a new, disposable polyethylene bailer. The monitoring well was purged of three successive well volumes prior to sample collection. During purging, the pH, specific conductivity, DO, ORP, turbidity, and temperature were measured and recorded at the start of purging and after each consecutive well volume was purged. After the third consecutive well volume was purged, technicians collected a sample in laboratory-supplied sample containers, while wearing a new pair of nitrile gloves. 2.1.2 Surface Water Sampling Methods Surface water samples SW-1 and SW-2 were collected from locations along an unnamed tributary, downstream of the landfill, as indicated by signage found adjacent to the surface water demarking monitoring locations. Surface water sample SW-3 was collected from a location along the same tributary and indicated by its respective signage. SW-4 was collected from a tributary which is in close proximity to monitoring well MW-4, also indicated by signage, and is located downstream of a stormwater discharge pipe that directs runoff away from the landfill cap. Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 3 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 2.2 Sample Handling, Documentation, and Analysis Water quality parameters and water level measurements are presented in the field logs in Appendix A, Section 3.0 of this report, as well as the Electronic Data Deliverable (EDD) in Appendix C. Following sample collection, groundwater and surface water samples were immediately placed on ice inside a sample cooler. Once all samples were collected, they were transported to Pace, a laboratory certified in North Carolina. Altamont submitted the samples for the following analysis:  Resource Conservation and Recovery Act (RCRA) metals using United States (US) EPA Methods 200.7 and 245.1. Proper chain-of-custody documentation procedures were followed during collection and transport of collected samples. The Report of Laboratory Analysis and chain-of-custody documentation are included in Appendix B. Laboratory analyses performed on the samples are summarized in Table 1. Detections of analytes are reported as follows:  Non-Detects—constituents of interests (COIs) that were not detected are reported to the laboratory method detection limit (MDL), which is the minimum concentration of a substance that can be reported by a laboratory with 99 percent confidence that the concentration is greater than zero.  Solid Waste Section Limit (SWSL)—The lowest concentration of an analyte that can be quantitatively determined with suitable precision and accuracy, as established by the DWM SWS. Concentrations below the respective SWSLs are not discussed in the text of this report unless they exceed their constituent-specific water quality standards.  “J”-Flag—If the reported concentration is greater than the MDL, but less than the laboratory method reporting limit (MRL) then the analytical result is an estimate and is flagged with a “J” qualifier. The MRL is the minimum concentration of a target analyte that can be accurately determined by the referenced method. The MRL is referred to as the Practical Quantitation Limit (PQL) in the Pace Report of Laboratory Analysis. If the reported concentration is greater than the MRL but less than the SWSL, the analytical result is qualified as an estimate and reported with an italicized “J” qualifier.  2L standard—Detected concentrations of analytes in groundwater samples were compared to current groundwater quality standards specified in 15A NCAC 2L.0202, which are referred to as 2L standards. Constituents with no established 2L standard were compared to the interim maximum allowable concentrations (IMACs) in accordance with 15A NCAC 02L .0202 [c].  2B standard—Detected concentrations of analytes in surface-water samples were compared to 15A NCAC 2B surface-water quality standards (2B standards). Table 2 presents analytical results for all analytes detected in groundwater and/or surface water samples, and identifies analytes detected above their established SWSLs, 2L standards (including IMACs, if applicable), or 2B standards. In the EDD (Appendix C), the identification of a well (“WELL ID” on the table) consists of the name of the well prefaced by the un-hyphenated permit number for the facility. For example, monitoring well MW-1 is identified in the EDD as 5603-MW1. In the tables and figures of this report, however, the identification of a well consists of the name of the well without the permit number associated with the facility. Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 4 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 3.0 Findings The laboratory analytical results and field parameter data for the groundwater and surface water samples collected at the Old Fort Landfill are provided in the report of laboratory analysis issued by Pace, included as Appendix B. In addition, all the laboratory results are summarized in the EDD format as specified by the Solid Waste Section (SWS) on May 5, 2010. 3.1 Groundwater Samples The following statements summarize detections of RCRA metals and field parameters in groundwater. 3.1.1 RCRA Metals Barium and mercury, were detected in one or more groundwater samples collected from the monitoring wells. Barium was detected above the SWSL (100 micrograms per liter [µg/L]) in monitoring well MW-3 (Table 2). All other detections, including mercury, were reported at concentrations below the SWSL. Metals were not detected at or above their respective 2L standards. 3.1.2 Field Parameters The field pH readings obtained from the groundwater samples collected from the monitoring wells, with the exception of MW-1, were below the acceptable range of 6.5 to 8.5 Standard Units (SU) specified in 15A NCAC 02L .0202[c] (Table 2). The remaining parameters measured in the field have no established groundwater standards and are therefore not discussed in this section. 3.2 Surface Water Samples The following statements summarize detections of RCRA metals and field parameters in surface water. 3.2.1 RCRA Metals Barium and mercury were detected in the four collected surface water samples. Barium was detected in all four surface water samples at concentrations above the SWSL, but well below its 2B standard. Mercury was detected at concentrations above the 2B surface water standard, established at 0.012 µg/L, in all four surface water samples. Concentrations of mercury ranged from 0.071 J micrograms per liter (µg/L) to 0.078 J µg/L. Mercury detections were J-flagged by the laboratory, indicating that the concentration was estimated. A full summary of detections can be found in Table 2. 3.2.2 Field Parameters The field pH readings measured in surface water samples SW-3 and SW-4 were outside the established 2B standard range of 6.0 to 9.0 SU at the time of sample collection. SW-3 and SW-4 had pH readings of 5.96 SU and 5.62 SU, respectively (Table 2). Dissolved oxygen (DO) readings measured in surface water sample SW-3 was below the 2B standard established as greater than or equal to 5.0 milligrams per liter (mg/L) for Class C surface waters (Table 2). The turbidity readings measured in all four surface water samples did not exceed the 2B standard established at 25 nephelometric turbidity units (NTUs). Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 5 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx The remaining parameters measured in the field have no established groundwater standards and are therefore not discussed in this section. Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 6 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 4.0 Summary Altamont collected groundwater and surface water samples on December 1, 2016 at the Old Fort Landfill. Tables 1 and 2, field logs in Appendix A, the Pace Report of Laboratory Analysis in Appendix B, and the EDD in Appendix C provide detailed presentation of analytical results and field data representing the groundwater and surface water quality at the Old Fort Landfill. Analytical results are summarized as follows:  Groundwater o pH—below the established 2L standard range of 6.5-8.5 SU in samples collected from monitoring wells MW-2, MW-3, and MW-4. o Metals—barium was detected in the four samples at concentrations below the 2L standard. Mercury was detected in samples collected from monitoring wells MW-3 and MW-4 at concentrations below the SWSL and 2L standard.  Surface water o pH—below the 2B standard range in samples from surface water locations SW-3 and SW-4. o DO—below the 2B standard range in samples from surface water location SW-3. o Metals—barium was detected above the SWSL, but well below the respective 2B standard, in the four surface water samples. Mercury was detected above the 2B standard in the four surface water samples, though the concentrations were estimated. 4.1 Future Activities Altamont will continue to collect groundwater and surface water samples on an annual basis at the Old Fort Landfill and continue to report the analytical results for groundwater and surface water monitoring on an annual basis. The next water quality sampling event is scheduled to occur in October 2017. Fall 2016 Semiannual Water Quality Monitoring Report December 28, 2016 Old Fort Industrial Solid Waste Landfill, Permit #56-03 Page 7 P:\ABF Environmental\Report\2016\Fall\5603Dec2016 Water Quality Report Final.docx 5.0 References Altamont Environmental, Inc. July 28, 2013. Fall 2013 Water Quality Monitoring Report. DENR DWM SWS. October 27, 2006. New Guidelines for Electronic Submittal of Environmental Monitoring Data. DENR DWM SWS. February 23, 2007. Addendum to October 27, 2006, NC SWS Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data. RJN Environmental, Inc. November 4, 2010. Revised Workplan for Landfill Investigation and Closure. RJN Environmental, Inc. June 7, 2011. Final Investigation Report. FIGURES 1  ¦                  !U!U!U !U !U #* #* #* #*          1520 14 4 0 1460 15 4 0 1480 1420 1560 1380 1360 1580 1560 15 2 0 1580 1560 1 4 8 0 1560 1 5 6 0 1580 1540 1 5 8 0 1 4 6 0 154 0 1560 156 0 1 5 6 0 152 0 1540 1 5 8 0 158 0  NC OneMap, NC Center for Geographic Information and Analysis, NC 911 Board          2   ¦  #* !U            0 150 30075Feet                            TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Old Fort Landfill, McDowell County, North Carolina GROUNDWATER SAMPLES FACILITY PERMIT EPA 200.7 EPA 245.1 56-03 MW-1 12/01/2016 X X 56-03 MW-2 12/01/2016 X X 56-03 MW-3 12/01/2016 X X 56-03 MW-4 12/01/2016 X X SURFACE WATER SAMPLES FACILITY PERMIT EPA 200.7 EPA 245.1 56-03 SW-1 12/01/2016 X X 56-03 SW-2 12/01/2016 X X 56-03 SW-3 12/01/2016 X X 56-03 SW-4 12/01/2016 X X Notes: Metals Analysis include the following RCRA metals: arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver, per December 18, 1997 Water Quality Monitoring Plan and permit requirements. WELL ID COLLECT DATE METALS SAMPLE ID COLLECT DATE METALS P:\ABF Environmental\Analytical & Data\2016\Fall\5603Nov2016 T1, T2 Page 1of 1 Table 2 Summary of Analytical Results Old Fort Landfill, McDowell County, North Carolina Metals (RCRA)Field Parameters Laboratory Certification 40 5445 (pH only) Laboratory Methods 200.7, 245.1 Parameter Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver pH Dissolved Oxygen Turbidity CAS Number 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7439-97-6 7782-49-2 7440-22-4 SW320 7782-44-7 SW330 SWS ID 14 15 34 51 131 132 183 184 320 356 330 Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L SU mg/L NTU Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-1 12/1/2016 5.0 U 3.9 J 0.50 U 0.50 U 2.5 U 0.070 U 5.0 U 2.5 U 7.06 2.86 7.65 MW-2 12/1/2016 5.0 U 56.1 J 0.50 U 0.50 U 2.5 U 0.070 U 5.0 U 2.5 U 6.25 3.24 37.6 MW-3 12/1/2016 5.0 U 112 0.50 U 0.50 U 2.5 U 0.070 J 5.0 U 2.5 U 5.64 3.35 5.80 MW-4 12/1/2016 5.0 U 66.5 J 0.50 U 0.50 U 2.5 U 0.075 J 5.0 U 2.5 U 4.95 2.06 28.4 Surface Water Samples SW-1 12/1/2016 5.0 U 134 0.50 U 0.50 U 2.5 U 0.073 J 5.0 U 2.5 U 6.64 6.11 5.92 SW-2 12/1/2016 5.0 U 136 0.50 U 0.50 U 2.5 U 0.078 J 5.0 U 2.5 U 6.36 5.74 4.64 SW-3 12/1/2016 5.0 U 165 0.50 U 0.50 U 2.5 U 0.076 J 5.0 U 2.5 U 5.96 4.56 4.64 SW-4 12/1/2016 5.0 U 296 0.50 U 0.50 U 2.5 U 0.071 J 5.0 U 2.5 U 5.62 6.81 2.90 MDL 5.0 5.0 0.50 0.50 2.5 0.070 5.0 2.5 NA NA NA MRL 10.0 10.0 1.0 5.0 5.0 0.20 10.0 5.0 NA NA NA SWSL 10 100 1 10 10 0.2 10 10 NE NE NE 2L 700 700 2 10 15 1 20 20 6.5-8.5 NE NE IMAC NE NE NE NE NE NE NE NE NE NE NE 2B 10 200,000 0.15 35 0.54 0.012 5 0.06 6.0-9.0 > 5.0 mg/L 25 Notes: Parameters Only detected constituents are listed on this table. Please refer to Pace Report of Laboratory Analysis (Appendix B) for further details. Lab Method The EPA approved analytical method used to analyze the constituents. CAS Number A unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters. SWS ID Solid Waste Section parameter Identification Number. Units RCRA Resource Conservation and Recovery Act MDL MRL SWSL U A laboratory data qualifier used for parameters not detected at concentrations above MDL. J A laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL. J Assigned by Altamont to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL. 2L IMAC Interim maximum allowable concentration. IMAC concentrations are listed in Appendix #1 of the 2L. 2B NE Not Established NA Not Applicable 112 Indicates a result in exceedance of the SWSL. 6.25 A shaded cell indicates the result is in exceedance of the 2L standard, IMAC, GWP Standard, or 2B standard. Surface water standard per "North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards," (last amended March, 2016) or standard obtained from National Criteria per EPA table (current as of May 15, 2013). The method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. Groundwater standards from "North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards," DEQ (Amended April 1, 2013). The method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method. The MRL is also represented as the PQL in the Pace Laboratory Report of Analysis. Micrograms per liter (µg/L) for analytical results, Standard Units (SU) for pH, nephelometric turbidity units (NTU) for turbidity, and milligrams per liter (mg/L) for dissolved oxygen. P:\ABF Environmental\Analytical & Data\2016\Fall\5603Nov2016 T1, T2 Page 1 of 1 APPENDICES APPENDIX A Sampling Field Logs and Instrument Calibration Data Sheet APPENDIX B Report of Laboratory Analysis and Chain-of-Custody Documentation #=CL# December 08, 2016 LIMS USE: FR - BRIAN GANT LIMS OBJECT ID: 92321569 92321569 Project: Pace Project No.: RE: Brian Gant Altamont Environmental 231 Haywood Street Asheville, NC 28804 IAC Old Fort Landfill Sampling Dear Brian Gant: Enclosed are the analytical results for sample(s) received by the laboratory on December 01, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 1 of 22 #=CP# CERTIFICATIONS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 22 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Lab ID Sample ID Matrix Date Collected Date Received 92321569001 MW-1 Water 12/01/16 13:49 12/01/16 15:15 92321569002 MW-2 Water 12/01/16 12:25 12/01/16 15:15 92321569003 MW-3 Water 12/01/16 11:21 12/01/16 15:15 92321569004 MW-4 Water 12/01/16 10:26 12/01/16 15:15 92321569005 SW-1 Water 12/01/16 12:45 12/01/16 15:15 92321569006 SW-2 Water 12/01/16 12:35 12/01/16 15:15 92321569007 SW-3 Water 12/01/16 11:00 12/01/16 15:15 92321569008 SW-4 Water 12/01/16 10:07 12/01/16 15:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 3 of 22 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92321569001 MW-1 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569002 MW-2 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569003 MW-3 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569004 MW-4 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569005 SW-1 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569006 SW-2 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569007 SW-3 EPA 200.7 7 PASI-AJMW EPA 245.1 1 PASI-ASER 92321569008 SW-4 EPA 200.7 7 PASI-ASH1 EPA 245.1 1 PASI-ASER REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 4 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:MW-1 Lab ID:92321569001 Collected:12/01/16 13:49 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 21:55 7440-38-212/02/16 22:4010.0 5.0 1 Barium 3.9J ug/L 12/03/16 21:55 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 21:55 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 21:55 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 21:55 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 21:55 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 21:55 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury ND ug/L 12/07/16 02:49 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 5 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:MW-2 Lab ID:92321569002 Collected:12/01/16 12:25 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 21:58 7440-38-212/02/16 22:4010.0 5.0 1 Barium 56.1 ug/L 12/03/16 21:58 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 21:58 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 21:58 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 21:58 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 21:58 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 21:58 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury ND ug/L 12/07/16 02:52 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 6 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:MW-3 Lab ID:92321569003 Collected:12/01/16 11:21 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 22:02 7440-38-212/02/16 22:4010.0 5.0 1 Barium 112 ug/L 12/03/16 22:02 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 22:02 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 22:02 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 22:02 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 22:02 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 22:02 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.070J ug/L 12/07/16 02:54 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 7 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:MW-4 Lab ID:92321569004 Collected:12/01/16 10:26 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 22:05 7440-38-212/02/16 22:4010.0 5.0 1 Barium 66.5 ug/L 12/03/16 22:05 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 22:05 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 22:05 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 22:05 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 22:05 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 22:05 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.075J ug/L 12/07/16 02:57 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 8 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:SW-1 Lab ID:92321569005 Collected:12/01/16 12:45 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 22:08 7440-38-212/02/16 22:4010.0 5.0 1 Barium 134 ug/L 12/03/16 22:08 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 22:08 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 22:08 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 22:08 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 22:08 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 22:08 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.073J ug/L 12/07/16 03:08 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 9 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:SW-2 Lab ID:92321569006 Collected:12/01/16 12:35 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 22:11 7440-38-212/02/16 22:4010.0 5.0 1 Barium 136 ug/L 12/03/16 22:11 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 22:11 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 22:11 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 22:11 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 22:11 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 22:11 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.078J ug/L 12/07/16 03:10 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 10 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:SW-3 Lab ID:92321569007 Collected:12/01/16 11:00 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/03/16 22:14 7440-38-212/02/16 22:4010.0 5.0 1 Barium 165 ug/L 12/03/16 22:14 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/03/16 22:14 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/03/16 22:14 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/03/16 22:14 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/03/16 22:14 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/03/16 22:14 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.076J ug/L 12/07/16 03:13 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 11 of 22 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Sample:SW-4 Lab ID:92321569008 Collected:12/01/16 10:07 Received:12/01/16 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Arsenic ND ug/L 12/06/16 01:51 7440-38-212/02/16 22:4010.0 5.0 1 Barium 296 ug/L 12/06/16 01:51 7440-39-312/02/16 22:405.0 2.5 1 Cadmium ND ug/L 12/06/16 01:51 7440-43-912/02/16 22:401.0 0.50 1 Chromium ND ug/L 12/06/16 01:51 7440-47-312/02/16 22:405.0 2.5 1 Lead ND ug/L 12/06/16 17:19 7439-92-112/02/16 22:405.0 2.5 1 Selenium ND ug/L 12/06/16 01:51 7782-49-212/02/16 22:4010.0 5.0 1 Silver ND ug/L 12/06/16 01:51 7440-22-412/02/16 22:405.0 2.5 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury 0.071J ug/L 12/07/16 03:16 7439-97-612/02/16 11:150.20 0.070 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 12 of 22 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 339045 EPA 245.1 EPA 245.1 245.1 Mercury Associated Lab Samples:92321569001, 92321569002, 92321569003, 92321569004, 92321569005, 92321569006, 92321569007, 92321569008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1880183 Associated Lab Samples:92321569001, 92321569002, 92321569003, 92321569004, 92321569005, 92321569006, 92321569007, 92321569008 Matrix:Water AnalyzedMDL Mercury ug/L ND 0.20 12/07/16 02:330.070 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1880184LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 2.72.5 110 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880185MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321226011 1880186 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 2.5 106 70-130104 2 202.5ND 2.7 2.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880187MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321141001 1880188 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L M12.5 65 70-13059 9 202.5ND 1.7 1.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 13 of 22 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 339076 EPA 200.7 EPA 200.7 200.7 MET Associated Lab Samples:92321569001, 92321569002, 92321569003, 92321569004, 92321569005, 92321569006, 92321569007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1880242 Associated Lab Samples:92321569001, 92321569002, 92321569003, 92321569004, 92321569005, 92321569006, 92321569007 Matrix:Water AnalyzedMDL Arsenic ug/L ND 10.0 12/03/16 20:385.0 Barium ug/L ND 5.0 12/03/16 20:382.5 Cadmium ug/L ND 1.0 12/03/16 20:380.50 Chromium ug/L ND 5.0 12/03/16 20:382.5 Lead ug/L ND 5.0 12/03/16 20:382.5 Selenium ug/L ND 10.0 12/03/16 20:385.0 Silver ug/L ND 5.0 12/03/16 20:382.5 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1880243LABORATORY CONTROL SAMPLE: LCSSpike Arsenic ug/L 482500 96 85-115 Barium ug/L 499500 100 85-115 Cadmium ug/L 492500 98 85-115 Chromium ug/L 496500 99 85-115 Lead ug/L 494500 99 85-115 Selenium ug/L 501500 100 85-115 Silver ug/L 252250 101 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880244MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92320967001 1880245 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 97 70-13097 1 20500ND490487 Barium ug/L 500 102 70-130101 1 2050078.8 587 582 Cadmium ug/L 500 99 70-13099 0 205001.3 495 496 Chromium ug/L 500 100 70-130100 0 205006.3 504 504 Lead ug/L 500 98 70-13097 0 20500108597595 Selenium ug/L 500 101 70-130101 0 20500ND505506 Silver ug/L 250 101 70-130102 1 20250ND254255 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880246MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321515001 1880247 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 101 70-130100 2 20500ND509500 Barium ug/L 500 103 70-130101 1 20500140653647 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 14 of 22 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1880246MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321515001 1880247 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cadmium ug/L 500 102 70-130101 1 20500ND512505 Chromium ug/L 500 101 70-130100 1 20500ND507500 Lead ug/L 500 99 70-13098 1 20500ND493489 Selenium ug/L 500 104 70-130102 1 20500ND518512 Silver ug/L 250 102 70-130102 0 20250ND256255 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 15 of 22 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 339077 EPA 200.7 EPA 200.7 200.7 MET Associated Lab Samples:92321569008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1880248 Associated Lab Samples:92321569008 Matrix:Water AnalyzedMDL Arsenic ug/L ND 10.0 12/06/16 01:455.0 Barium ug/L ND 5.0 12/06/16 01:452.5 Cadmium ug/L ND 1.0 12/06/16 01:450.50 Chromium ug/L ND 5.0 12/06/16 01:452.5 Lead ug/L ND 5.0 12/06/16 17:122.5 Selenium ug/L ND 10.0 12/06/16 01:455.0 Silver ug/L ND 5.0 12/06/16 01:452.5 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1880249LABORATORY CONTROL SAMPLE: LCSSpike Arsenic ug/L 460500 92 85-115 Barium ug/L 501500 100 85-115 Cadmium ug/L 480500 96 85-115 Chromium ug/L 493500 99 85-115 Lead ug/L 507500 101 85-115 Selenium ug/L 482500 96 85-115 Silver ug/L 243250 97 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880250MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321569008 1880251 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 93 70-13093 0 20500ND463464 Barium ug/L 500 100 70-130100 0 20500296796798 Cadmium ug/L 500 97 70-13097 0 20500ND483484 Chromium ug/L 500 98 70-13098 0 20500ND489490 Lead ug/L 500 101 70-130101 0 20500ND507505 Selenium ug/L 500 96 70-13096 0 20500ND480482 Silver ug/L 250 97 70-13098 0 20250ND243244 Parameter Units MS Result % Rec Limits Qual% RecConc. 1880252MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321092003 1880253 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 91 70-13090 1 20500ND458453 Barium ug/L 500 101 70-130100 1 2050014.8 521 514 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 16 of 22 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1880252MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92321092003 1880253 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Cadmium ug/L 500 96 70-13095 1 20500ND480474 Chromium ug/L 500 98 70-13097 1 20500ND490486 Lead ug/L 500 93 70-13092 1 20500ND468464 Selenium ug/L 500 96 70-13095 1 20500ND480474 Silver ug/L 250 97 70-13096 1 20250ND243241 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 17 of 22 #=QL# QUALIFIERS Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 18 of 22 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92321569 IAC Old Fort Landfill Sampling Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92321569001 339076 339242MW-1 EPA 200.7 EPA 200.7 92321569002 339076 339242MW-2 EPA 200.7 EPA 200.7 92321569003 339076 339242MW-3 EPA 200.7 EPA 200.7 92321569004 339076 339242MW-4 EPA 200.7 EPA 200.7 92321569005 339076 339242SW-1 EPA 200.7 EPA 200.7 92321569006 339076 339242SW-2 EPA 200.7 EPA 200.7 92321569007 339076 339242SW-3 EPA 200.7 EPA 200.7 92321569008 339077 339243SW-4 EPA 200.7 EPA 200.7 92321569001 339045 339228MW-1 EPA 245.1 EPA 245.1 92321569002 339045 339228MW-2 EPA 245.1 EPA 245.1 92321569003 339045 339228MW-3 EPA 245.1 EPA 245.1 92321569004 339045 339228MW-4 EPA 245.1 EPA 245.1 92321569005 339045 339228SW-1 EPA 245.1 EPA 245.1 92321569006 339045 339228SW-2 EPA 245.1 EPA 245.1 92321569007 339045 339228SW-3 EPA 245.1 EPA 245.1 92321569008 339045 339228SW-4 EPA 245.1 EPA 245.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/08/2016 01:55 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 19 of 22 Page 20 of 22 Page 21 of 22 Page 22 of 22 APPENDIX C Environmental Monitoring Reporting Form and Electronic Submittal of Environmental Monitoring Data 5603Dec2016