1809_DukeMarshallFGD_March2017_1stSemiAnnual_DIN27937_20170609

Marshall Steam Station
Semiannual Groundwater
Monitoring Report
FGD Residue Landfill, Phase 1, Cell 1
Permit No. 1809
March 2017 Sampling Event
June 27, 2017

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventContents

ii
Contents
Page
Report Verification ......................................................................................................................... i
Contents ........................................................................................................................................ ii
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventSection 1 – BACKGROUND

1
Section 1 – Background
Marshall Steam Station (Marshall) is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy). The Marshall plant has a generating capacity of 2,090 megawatts of electric
power by the combustion of coal. The plant is located in Catawba County, North Carolina, on
Lake Norman and is in the Piedmont physiographic region.
The flue gas desulfurization (FGD) landfill is located northwest of the power plant and west of
the Marshall ash basin as shown on Figure 1. In general, the topography of the landfill site
slopes from the west-northwest to the east-southeast towards the Marshall ash basin. Note that
the asbestos landfill footprint shown in Figure 1 is the permitted extent of the landfill and not its
operational boundaries.
The landfill is permitted to receive FGD residue (gypsum), clarifier sludge, fly ash, bottom ash,
construction and demolition (C&D) waste, asbestos waste, mill rejects (pyrites), waste limestone
material, land clearing and inert debris, boiler slag, ball mill rejects, sand blast material, and coal
waste. Only Cell 1 of the landfill has been constructed to date. Cell 1 is approximately 18 acres
in area. The landfill is constructed with an engineered liner system. Contact stormwater and
leachate are collected in the lined Cell 1 and then piped to the ash basin. The landfill began
receiving waste in 2007. The landfill stopped accepting waste and was considered inactive in
October 2015.
The subsurface conditions at the site consist of residual soils and partially weathered rock which
have been formed by the in-place weathering of the parent rock. These materials are underlain
by bedrock. The site hydrogeological description and information on the monitoring wells can be
found in the Groundwater Sampling and Analysis Plan.1
The monitoring system for the Marshall FGD Landfill, Phase 1, Cell 1 consists the following:
Monitoring Wells: MS-8
MS-9
MS-10
MS-11
MS-12
MS-13
MS-14
MS-15
MS-16

Surface Water Sample: SW-1

Leachate Sample: C1 Leachate

1 Marshall Steam Station Flue Gas Desulfurization (FGD) Residue Landfill Phase 1, Cell 1 Permit No.
1809 Groundwater Sampling and Analysis Plan. Dated August 19, 2011.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventSection 1 – BACKGROUND

2
The locations of the wells, surface water sample location, and the leachate sampling location
are shown on Figure 2. Table 1 presents well construction information for the landfill monitoring
wells. The leachate sampling requirement was added in the revised Permit to Operate for the
Marshall FGD Landfill2 in September 2011. Due to landfill operations, the historical leachate
collection area has not been accessible since the September 2014 sampling event. A new
collection point for leachate sample C1 Leachate was therefore established northwest of the
landfill to allow for sampling at the outlet of the leachate discharge pipe.
Well MS-8 is located north of the landfill and, according to the Groundwater Sampling and
Analysis Plan, is the background monitoring well for the site.
Surface water sample location SW-1 is located within a surface drainage feature located
potentially downgradient of the landfill. The analytical results are compared to Title 15A, North
Carolina Administrative Code (NCAC), Subchapter 2L Standards (2L Standards) for Class GA
groundwater.
2 Attachment 3 – Conditions of Operating Permit, Part I: General Facility Conditions, Monitoring and
Reporting Requirements, #13.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventSection 2 – METHODS

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Field Certification #5193) in accordance with the North Carolina Solid Waste
Management Guidelines. Copies of the field sampling forms are included in Appendix A. The
parameters and constituents reported were selected by Duke Energy and the NCDEQ Division
of Solid Waste and were analyzed by Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248).
The samples were analyzed for the following constituents and/or parameters:
 Barium, beryllium, boron, cobalt, copper, iron, manganese, nickel, silver, and zinc using
Solid Waste (SW)-8463 Method 6010D
 Antimony, arsenic, cadmium, chromium, lead, thallium, selenium, and vanadium using
SW-846 Method 6020B
 Mercury using U.S. Environmental Protection Agency (EPA) Method 7470A
 Total dissolved solids using Standard Method (SM) 2540C
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 9056A
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells MS-8, MS-9, MS-10, MS-11, MS-12, MS-13,
MS-14, MS-15, and MS-16 and leachate sampling location C1 Leachate. Surface water
sample location SW-1 had insufficient water to collect a sample. The samples were
collected on March 29, 2017, and HDR received the data on April 18, 2017. The field
sampling forms are included in Appendix A.
 Reviewed the laboratory analytical results for samples. The EDD provided by Duke
Energy was adapted to conform to the format requirements of the NCDEQ EDD
template. HDR added an italicized J data qualifier (J) to indicate a concentration that is

3 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed August 30, 2016)
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventSection 2 – METHODS

4
equal to or greater than the laboratory’s method reporting limit (MRL) but less than the
Solid Waste Section Limit4 (SWSL). A copy of the original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
4 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
March 2017 Sampling EventSection 3 - RESULTS

5
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours for the site are shown on Figure 3. These contours
were developed using groundwater elevations measured in the wells on the date of sampling.
Calculated groundwater flow velocities are presented in Table 2.
Groundwater flow in the area of the landfill is generally from areas of higher topography located
to the north and west of the landfill, toward the Marshall ash basin, located to the east of the
landfill. To a lesser extent, some component of groundwater flow is expected to be toward
surface water sample location SW-1. Note that SW-1 had insufficient water to sample.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of the groundwater samples collected at the monitoring wells are
summarized in Table 4. The analysis results for these locations are compared to the 2L
Standards. Concentrations with values that attain or exceed the 2L Standards are noted on
Table 4 by bold font. A summary of the analytical results that attain or exceed the 2L Standards
and a preliminary analysis of the cause and significance of the exceedances are presented in
Table 5.
The field and analytical results for the leachate sampling are summarized in Table 6.
Analytical results with values that equal or are greater than the SWSLs are noted on Tables 4
and 6 by gray cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
The laboratory report and chain-of-custody forms are located in Appendix B.
HDR previously prepared and submitted an assessment to NCDEQ on historical exceedances
of 2L Standards at this landfill (Groundwater Assessment Marshall Steam Station FGD Landfill,
Phase 1, Cell 1, July 12, 2012). The report assessed 2L Standard exceedances chromium at
MS-15; iron at MS-8, MS-10, MS-11, MS-16, and SW-1; manganese at MS-16; and pH at MS-8,
MS-10, MS-11, MS-12, MS-13, MS-14, MS-15, MS-16, and SW-1. The assessment report
concluded for the period of analytical results reviewed that the exceedances of the 2L
Standards at the site were naturally occurring and are not related to impacts from the landfill.

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TABLES
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MS
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2
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3
8
 ‐ 44.38

S
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‐15

1
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9
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6
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8
 ‐ 63.08

S
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‐16

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 ‐ 37.46

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k
TO
C
 in
d
i
c
a
t
e
s
 to
p
 of
 ca
s
i
n
g
ft
 in
d
i
c
a
t
e
s
 fe
e
t
in
 in
d
i
c
a
t
e
s
 in
c
h
e
s
 no
m
i
n
a
l
 di
a
m
e
t
e
r
PV
C
 in
d
i
c
a
t
e
s
 po
l
y
v
i
n
y
l
 ch
l
o
r
i
d
e
Ho
r
i
z
o
n
t
a
l
 da
t
u
m
 as
s
u
m
e
d
 to
 be
 NA
D
8
3
El
e
v
a
t
i
o
n
s
 ba
s
e
d
 on
 NA
V
D
 88
 ve
r
t
i
c
a
l
 da
t
u
m
Ta
b
l
e
 2  ‐

Gr
o
u
n
d
w
a
t
e
r
 Fl
o
w
 Ve
l
o
c
i
t
i
e
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
M
a
r
s
h
a
l
l
 St
e
a
m
 St
a
t
i
o
n
FG
D
 Re
s
i
d
u
e
 La
n
d
f
i
l
l
Ph
a
s
e
 1,
 Ce
l
l
 1  ‐

Pe
r
m
i
t
 No
.
 18
0
9
We
l
l
 ID
Up
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Do
w
n
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r
Fl
o
w
Di
s
t
a
n
c
e
(f
t
)
Hy
d
r
a
u
l
i
c
Gr
a
d
i
e
n
t
Hy
d
r
a
u
l
i
c
Co
n
d
u
c
t
i
v
i
t
y
(f
t
/
d
a
y
)
Ef
f
e
c
t
i
v
e
Po
r
o
s
i
t
y
(%)Groundwater Velocity (ft/day)
MS
‐8

8
2
6
.
5
8

8
2
5

1
3
4

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
‐9

8
2
5

8
2
0

1
5
4

0
.
0
3

0
.
4
1

0
.
2
5
9

0
.
0
5
MS
‐10

8
3
3
.
7
8

8
3
0

1
1
2

0
.
0
3

0
.
4
1

0
.
2
5
9

0
.
0
5
MS
‐11

8
2
5
.
4
0

8
2
0

3
6
6

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
‐12

8
1
5

8
1
1
.
4
8

2
6
8

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
‐13

8
1
5

8
1
0

4
1
0

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
‐14

8
1
0

8
0
6
.
8
5

4
1
6

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
1
MS
‐15

8
1
0

8
0
8
.
6
3

1
8
5

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
1
MS
‐16

8
1
5

8
1
0

2
0
9

0
.
0
2

0
.
4
1

0
.
2
5
9

0
.
0
4
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
ft
 in
d
i
c
a
t
e
s
 fe
e
t
Li
n
e
a
r
 di
s
t
a
n
c
e
 me
a
s
u
r
e
d
 th
r
o
u
g
h
 mo
n
i
t
o
r
i
n
g
 we
l
l
s
 is
 ge
n
e
r
a
l
l
y
 pe
r
p
e
n
d
i
c
u
l
a
r
 to
 gr
o
u
n
d
w
a
t
e
r
co
n
t
o
u
r
s
At
 mo
n
i
t
o
r
i
n
g
 we
l
l
 lo
c
a
t
i
o
n
s
 wh
e
r
e
 do
w
n
g
r
a
d
i
e
n
t
 co
n
t
o
u
r
s
 ar
e
 no
t
 pr
e
s
e
n
t
,
 th
e
 gr
o
u
n
d
w
a
t
e
r
el
e
v
a
t
i
o
n
 at
 th
e
 mo
n
i
t
o
r
i
n
g
 we
l
l
 is
 us
e
d
 as
 th
e
 do
w
n
g
r
a
d
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 el
e
v
a
t
i
o
n
At
 mo
n
i
t
o
r
i
n
g
 we
l
l
 lo
c
a
t
i
o
n
s
 wh
e
r
e
 up
g
r
a
d
i
e
n
t
 co
n
t
o
u
r
s
 ar
e
 no
t
 pr
e
s
e
n
t
,
 th
e
 gr
o
u
n
d
w
a
t
e
r

el
e
v
a
t
i
o
n
 at
 th
e
 mo
n
i
t
o
r
i
n
g
 we
l
l
 is
 us
e
d
 as
 th
e
 up
g
r
a
d
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 el
e
v
a
t
i
o
n
.
Mo
n
i
t
o
r
i
n
g
 we
l
l
s
 ar
e
 no
t
 li
s
t
e
d
 wh
e
r
e
 in
s
u
f
f
i
c
i
e
n
t
 gr
o
u
n
d
w
a
t
e
r
 co
n
t
o
u
r
 in
f
o
r
m
a
t
i
o
n
 is  available
to
 ca
l
c
u
l
a
t
e
 ve
l
o
c
i
t
y
Hy
d
r
a
u
l
i
c
 gr
a
d
i
e
n
t
s
 an
d
 gr
o
u
n
d
w
a
t
e
r
 ve
l
o
c
i
t
i
e
s
 ar
e
 ap
p
r
o
x
i
m
a
t
e
.
Hy
d
r
a
u
l
i
c
 co
n
d
u
c
t
i
v
i
t
y
 pr
e
s
e
n
t
e
d
 is
 th
e
 ge
o
m
e
t
r
i
c
 me
a
n
 of
 th
e
 co
n
d
u
c
t
i
v
i
t
y
 da
t
a
 fo
r
 the  
on
 Ma
r
c
h
 29
,
 20
1
7
al
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e
 hy
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c
 la
y
e
r
 in
 th
e
 HD
R
 Co
n
d
u
c
t
i
v
i
t
y
 Da
t
a
b
a
s
e
 (u
n
p
u
b
l
i
s
h
e
d

da
t
a
 fr
o
m
 Ca
r
o
l
i
n
a
 si
t
e
s
 wi
t
h
 fo
l
i
a
t
e
d
/
l
a
y
e
r
e
d
 be
d
r
o
c
k
)
Ef
f
e
c
t
i
v
e
 po
r
o
s
i
t
y
 pr
e
s
e
n
t
e
d
 is
 th
e
 me
a
n
 va
l
u
e
 of
 th
e
 al
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e
 hy
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c
la
y
e
r
 es
t
i
m
a
t
e
d
 fr
o
m
 so
i
l
 te
s
t
i
n
g
 us
i
n
g
 Fe
t
t
e
r
/
B
e
a
r
 Di
a
g
r
a
m
s
Hy
d
r
a
u
l
i
c
 gr
a
d
i
e
n
t
s
 an
d
 gr
o
u
n
d
w
a
t
e
r
 ve
l
o
c
i
t
i
e
s
 ca
l
c
u
l
a
t
e
d
 us
i
n
g
 gr
o
u
n
d
w
a
t
e
r
 de
p
t
h
 measured
Ta
b
l
e
 3  ‐

Fi
e
l
d
 Da
t
a
 Pa
r
a
m
e
t
e
r
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
M
a
r
s
h
a
l
l
 St
e
a
m
 St
a
t
i
o
n
FG
D
 Re
s
i
d
u
e
 La
n
d
f
i
l
l
Ph
a
s
e
 1,
 Ce
l
l
 1  ‐

Pe
r
m
i
t
 No
.
 18
0
9
Da
t
e

S
a
m
p
l
e
 ID
We
l
l
De
p
t
h
Be
l
o
w
TO
C
(f
t
)
De
p
t
h
 to
Wa
t
e
r
Be
l
o
w
TO
C
(f
t
)
Gr
o
u
n
d
w
a
t
e
r
El
e
v
a
t
i
o
n
(f
t
)

A
p
p
e
a
r
a
n
c
e

O
d
o
r

P
u
r
g
e
 Me
t
h
o
d
Av
e
r
a
g
e
Pu
m
p
 Ra
t
e
(m
L
/
m
i
n
)
We
l
l
Vo
l
u
m
e
(g
a
l
)
EV
A
C
Vo
l
u
m
e
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
Temperature (°C)Specific Conductance (µԼ /cm)pH (SU)Turbidity (NTU)ORP (mV ‐NHE)DO (mg/L)
3/
2
9
/
2
0
1
7

M
S
‐8

5
1
.
5
8

4
5
.
7
6

8
2
6
.
5
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

0
.
9
5

3
.
2
5

N
O

1
5
.
0
7

4
4

6
.
0

9
.
8

4
1
8

6
.
9
8
3/
2
9
/
2
0
1
7

M
S
‐9

5
3
.
0
0

4
3
.
3
9

8
2
4
.
6
5

N
o
r
m
a
l

N
o
n
e

L
F

2
4
0

1
.
5
7

2
.
2
0

N
/
A

1
5
.
8
8

8
1

6
.
7

4
.
0

3
5
3

7
.
9
5
3/
2
9
/
2
0
1
7

M
S
‐10

2
3
.
3
4

1
7
.
5
1

8
3
3
.
7
8

N
o
r
m
a
l

N
o
n
e

L
F

2
2
0

0
.
9
5

0
.
8
5

N
/
A

1
6
.
0
6

1
9

5
.
1

3
.
4

4
7
7

6
.
2
6
3/
2
9
/
2
0
1
7

M
S
‐11

4
2
.
7
2

3
4
.
3
8

8
2
5
.
4
0

N
o
r
m
a
l

N
o
n
e

L
F

3
7
6

1
.
3
6

3
.
5
0

N
/
A

1
4
.
4
1

4
1

5
.
5

2
.
9

4
4
6

7
.
3
5
3/
2
9
/
2
0
1
7

M
S
‐12

3
1
.
0
9

2
4
.
1
8

8
1
1
.
4
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
1
3

6
.
2
5

N
O

1
4
.
7
9

2
5

5
.
1

9
.
0

5
9
5

7
.
9
2
3/
2
9
/
2
0
1
7

M
S
‐13

4
1
.
5
2

3
1
.
8
7

8
1
0
.
0
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
5
7

7
.
0
0

N
O

1
4
.
4
0

6
0

5
.
4

2
.
9

4
9
5

4
.
1
3
3/
2
9
/
2
0
1
7

M
S
‐14

4
4
.
3
8

3
7
.
2
2

8
0
6
.
8
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
1
7

4
.
2
5

N
O

1
5
.
3
2

5
7

5
.
9

4
.
6

5
2
1

7
.
6
8
3/
2
9
/
2
0
1
7

M
S
‐15

6
3
.
0
8

5
2
.
8
4

8
0
8
.
6
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
6
7

8
.
5
0

N
O

1
6
.
7
0

1
3
9

6
.
5

0
.
5

4
8
4

7
.
5
1
3/
2
9
/
2
0
1
7

M
S
‐16

3
7
.
4
6

2
5
.
7
5

8
1
1
.
2
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
9
1

4
.
7
5

Y
E
S

1
7
.
4
2

1
0
2

6
.
3

3
9
.
6

4
8
7

8
.
7
2
3/
2
9
/
2
0
1
7

S
W
‐1

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
S

N
S

N
S

N
S

N
S

N
S
3/
2
9
/
2
0
1
7

C
1
‐LE
A
C
H
A
T
E

N
/
A

N
/
A

N
/
A

T
u
r
b
i
d

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
6
.
3
7

4
,
5
8
7

6
.
5

5
5
.
1

1
6
9

9
.
2
6
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
Laboratory  Certification  Codes:
NT
U
 in
d
i
c
a
t
e
s
 ne
p
h
e
l
o
m
e
t
r
i
c
 tu
r
b
i
d
i
t
y
 un
i
t
s
mV
‐NH
E
 in
d
i
c
a
t
e
s
 mi
l
l
i
v
o
l
t
s
‐no
r
m
a
l
 hy
d
r
o
g
e
n
 el
e
c
t
r
o
d
e
ft
 in
d
i
c
a
t
e
s
 fe
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A
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p
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1
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Pu
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 Me
t
h
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s
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w
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n
v
e
n
t
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o
n
a
l
 Pu
r
g
e
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‐5  we
l
l
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l
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s
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y
d
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S
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)
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p
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 On
l
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e
r
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g
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m
p
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A
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d
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p
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b
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0
9
Sa
m
p
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m
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S
W
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No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
17
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18
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835.66
5.
5
85
1
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2
9
5.
1

5
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1
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0
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8
8
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6.
7
85
9
.
7
8
Ac
c
o
r
d
i
n
g
 to
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e
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n
s
t
i
t
u
e
n
t
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o
k
‐up
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b
p
a
g
e
 on
 th
e
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D
E
Q
 Di
v
i
s
i
o
n
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s
t
e
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n
a
g
e
m
e
n
t
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b
p
a
g
e
,
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e
r
e
 is
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S
L
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 St
a
n
d
a
r
d
 fo
r
 ch
o
r
i
d
e
 as
s
o
c
i
a
t
e
d
 wi
t
h
 CA
S
 number  16887 ‐08 ‐6, which  is  the  CAS  reported   
MC
L
 is
 th
e
 Fe
d
e
r
a
l
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x
i
m
u
m
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n
t
a
m
i
n
a
n
t
 Le
v
e
l
 as
 fo
u
n
d
 in
 40
 CF
R
,
 Su
b
p
a
r
t
 G,
 §1
4
1
.
6
2
51
.
5
8
82
4
.
6
5
µԼ /c
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c
r
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m
h
o
s
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r
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n
t
i
m
e
t
e
r
811.48
**
 Co
n
c
e
n
t
r
a
t
i
o
n
 lis
t
e
d
 is
 a  se
c
o
n
d
a
r
y
 ma
x
i
m
u
m
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n
t
a
m
i
n
a
n
t
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v
e
l
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M
C
L
)
;
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C
L
s
 ar
e
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t
a
b
l
i
s
h
e
d
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A
 in
 th
e
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t
i
o
n
a
l
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c
o
n
d
a
r
y
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i
n
k
i
n
g
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t
e
r
 Re
g
u
l
a
t
i
o
n
s
 as
 fo
u
n
d
 in  40  CFR  §143.331.09
82
6
.
5
8
53
.
0
0

4
2
.
7
2
82
5
.
4
83
3
.
7
8
23
.
3
4
Laboratory  Certification  Codes:Duke  Energy  Carolinas  Field  #5193 Duke  Energy  Analytical  Laboratory  #248
MS
‐8M
S
‐9M
S
‐10

M
S
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M
S
‐12
Ma
r
c
h
 29
,
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1
7
Du
k
e
 En
e
r
g
y
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r
o
l
i
n
a
s
,
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C
NE
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d
i
c
a
t
e
s
 no
t
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t
a
b
l
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s
h
e
d
;
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d
i
c
a
t
e
s
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t
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a
l
y
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e
d
;
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a
n
k
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l
l
s
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d
i
c
a
t
e
 th
a
t
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e
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15
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d
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b
o
r
a
t
o
r
y
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r
i
n
g
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a
l
y
s
i
s
by
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e
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b
o
r
a
t
o
r
y
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r
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e
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a
l
y
s
e
s
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m
p
l
e
t
e
d
;
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e
r
e
f
o
r
e
,
 th
e
 SW
S
L
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d
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a
n
d
a
r
d
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s
t
e
d
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e
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e
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l
o
r
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d
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t
h
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S
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m
b
e
r
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3
0
1
 as
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e
c
i
f
i
e
d
 on
 th
e
 Co
n
s
t
i
t
u
e
n
t
 Lo
o
k
‐up  webpage  (last  updated  June  13, 2011)
Gr
a
y
e
d
 va
l
u
e
s
 in
d
i
c
a
t
e
 va
l
u
e
s
 th
a
t
 eq
u
a
l
 or
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e
 gr
e
a
t
e
r
 th
a
n
 th
e
 SW
S
L
Ta
b
l
e
 4  ‐

Gr
o
u
n
d
w
a
t
e
r
 Fi
e
l
d
 an
d
 An
a
l
y
t
i
c
a
l
 Re
s
u
l
t
s
Du
k
e
 En
e
r
g
y
 Ca
r
o
l
i
n
a
s
,
 LL
C
/
M
a
r
s
h
a
l
l
 St
e
a
m
 St
a
t
i
o
n
FG
D
 Re
s
i
d
u
e
 La
n
d
f
i
l
l
Ph
a
s
e
 1,
 Ce
l
l
 1  ‐

Pe
r
m
i
t
 No
.
 18
0
9
Sa
m
p
l
e
 Da
t
e
:
Fi
e
l
d
 Sa
m
p
l
i
n
g
 Pe
r
f
o
r
m
e
d
 By
:
Pa
r
a
m
e
t
e
r

S
W
S
 ID

U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
i
o
n
Co
d
e
MDL

S
W
S
L
15A  NCAC 2L  Standard/IMAC Federal  MCL
Fi
e
l
d
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3
2
0

S
U

5
1
9
3
‐‐NE

6
.
5
‐8.5

6
.
5
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Fi
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l
d
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c
t
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v
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t
y

3
2
3

µ
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m

5
1
9
3
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N
E

N
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p
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3
2
5

°
C

5
1
9
3
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N
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N
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To
p
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3
2
8

f
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N
E
De
p
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h
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t
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3
1
8

f
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r
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f
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l
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4
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1
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5
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4
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J

3
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1
7
Laboratory  Certification  Codes:Duke  Energy  Carolinas  Field  #5193 Duke  Energy  Analytical  Laboratory  #248
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h
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by
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r
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a
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m
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e
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e
f
o
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e
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S
L
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d
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a
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l
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S
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m
b
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3
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d
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e
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t
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t
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e
n
t
 Lo
o
k
‐up  webpage  (last  updated  June  13, 2011)
NE
 in
d
i
c
a
t
e
s
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t
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t
a
b
l
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s
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e
d
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d
i
c
a
t
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s
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t
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a
l
y
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e
d
;
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a
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k
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l
l
s
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d
i
c
a
t
e
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t
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e
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e
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f
o
r
m
a
t
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l
e
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n
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s
p
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t
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SW
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l
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t
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D
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l
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r
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s
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L
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t
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L
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C
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n
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r
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l
 1,
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1
3
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L
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d
e
r
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l
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n
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n
t
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v
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u
n
d
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 40
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R
,
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b
p
a
r
t
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4
1
.
6
2
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n
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r
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t
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s
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r
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t
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t
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r
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t
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Ac
c
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n
s
t
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t
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e
n
t
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b
p
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g
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D
E
Q
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v
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s
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n
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e
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r
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a
n
d
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r
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r
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s
o
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i
a
t
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t
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S
 number  16887 ‐08 ‐6, which  is  the  CAS  reported   
Gr
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i
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c
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d
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A
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A
C
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n
d
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r
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L
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b
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r
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t
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t
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t
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m
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t
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e
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L
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l
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r
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m
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t
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l
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s
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l
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 us
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n
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s
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m
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t
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R
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)
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c
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t
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s
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m
p
l
e
;
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t
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p
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r
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n
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A
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‐‐‐‐‐‐NSNS NS NS NS NS NSNS NS
SU
 in
d
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m
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r
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S
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t
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t
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Ta
b
l
e
 5  ‐

Fi
e
l
d
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d
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a
l
y
t
i
c
a
l
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s
u
l
t
s
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a
t
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u
a
l
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e
e
d
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C
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o
u
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w
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t
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r
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a
l
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a
n
d
a
r
d
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Du
k
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e
r
g
y
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r
o
l
i
n
a
s
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C
/
M
a
r
s
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a
l
l
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e
a
m
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t
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n
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n
d
f
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l
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Ph
a
s
e
 1,
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l
l
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Pe
r
m
i
t
 No
.
 18
0
9
Sa
m
p
l
e
 Da
t
e
:
Pa
r
a
m
e
t
e
r

S
a
m
p
l
e
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R
e
s
u
l
t

U
n
i
t
s
15
A
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A
C
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a
n
d
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r
d
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s
t
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Co
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t
r
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t
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n
s

C
a
u
s
e
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d
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MS
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6
.
0

5
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2
 ‐

6.
3

p
H
 in
 MS
‐8  is
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n
s
i
s
t
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n
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t
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s
t
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l
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a
d
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n
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l
l
.
MS
‐10

5
.
1

4
.
5
 ‐

5.
3

p
H
 in
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‐10
 is
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n
s
i
s
t
e
n
t
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t
h
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s
t
o
r
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c
a
l
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a
d
i
n
g
s
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l
l
.
MS
‐11

5
.
5

5
.
0
 ‐

5.
6

p
H
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‐11
 is
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n
s
i
s
t
e
n
t
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t
h
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s
t
o
r
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c
a
l
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a
d
i
n
g
s
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l
l
.
MS
‐12

5
.
1

4
.
5
 ‐

5.
1

p
H
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‐12
 is
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n
s
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s
t
e
n
t
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t
h
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s
t
o
r
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c
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l
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a
d
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n
g
s
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l
l
.
MS
‐13

5
.
4

4
.
9
 ‐

5.
5

p
H
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‐13
 is
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n
s
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s
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n
t
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t
h
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s
t
o
r
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c
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l
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d
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l
.
MS
‐14

5
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9

5
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5
 ‐

6.
2

p
H
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‐14
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n
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n
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t
h
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s
t
o
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c
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l
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d
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l
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MS
‐15

6
.
5

6
.
3
 ‐

9.
8

p
H
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‐15
 is
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n
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n
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t
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s
t
o
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c
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l
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a
d
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n
g
s
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l
l
.
MS
‐16

6
.
3

5
.
8
 ‐

6.
4

p
H
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‐16
 is
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n
s
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s
t
e
n
t
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t
h
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s
t
o
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c
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d
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.
Ch
r
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m
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MS
‐8

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 ‐

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MS
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1
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7
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2
9
4
 ‐

57
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No
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Ir
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n
Table 6 ‐ Leachate Field and Analytical Results
Duke Energy Carolinas, LLC/Marshall Steam Station
FGD Residue Landfill
Phase 1, Cell 1 ‐ Permit No. 1809
Sample Date:
Field Sampling Performed By:
Parameter SWS ID Units
Certification
Code MDL
Field pH 320 SU 5193 ‐‐
Field Specific Conductivity 323 µԼ/cm 5193 ‐‐
Temperature 325 °C 5193 ‐‐
Antimony 13 µg/L 248 5.2 U 5.2
Arsenic 14 µg/L 248 1.4 J 0.78
Barium 15 µg/L 248 21.4 J'0.1
Beryllium 23 µg/L 248 2.22 J 0.2
Boron 428 µg/L 248 45,700 33
Cadmium 34 µg/L 248 1.01 U 1.01
Chloride 455 µg/L 248 367,000 1,100
Chromium 51 µg/L 248 1.37 J 0.61
Cobalt 53 µg/L 248 35.2 0.3
Copper 54 µg/L 248 1U 1
Fluoride 312 µg/L 248 4,960 J 850
Iron 340 µg/L 248 165,000 13
Lead 131 µg/L 248 0.65 U 0.65
Manganese 342 µg/L 248 4,610 0.2
Mercury 132 µg/L 248 0.0334 U 0.0334
Nickel 152 µg/L 248 90.7 0.5
Nitrate (as Nitrogen) 303 µg/L 248 3,120 J'5.4
Selenium 183 µg/L 248 145 0.92
Silver 184 µg/L 248 0.7 U 0.7
Sulfate 315 µg/L 248 2,770,000 9,000
Thallium 194 µg/L 248 0.24 U 0.24
Total Dissolved Solids 311 µg/L 248 3,960,000 334,000
Vanadium 209 µg/L 248 1.87 J 0.53
Zinc 213 µg/L 248 139 2.6
Notes:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
Duke Energy Carolinas, LLC on April 18, 2017
µԼ/cm indicates micromhos per centimeter
SU indicates standard units
°C indicates degrees celsius
MDL is the laboratory method detection limit. 
Qualifiers in non‐italicized text are laboratory data qualifiers or "flags"; "U" is used to identify 
indicate concentrations which equal or are greater than the laboratory's MRL but are less than 
laboratory for the analyses completed; therefore, the SWSL used in the J' qualifier comparison 
are for the chloride with CAS number SW301 as specified on the Constituent Look‐up webpage 
laboratory's method reporting limit (MRL); an italicized J'‐flag is a data qualifier, added by HDR to 
estimated concentrations which equal or are greater than the MDL but are less than the 
SWS ID is the Solid Waste Section Identification Number
Analytical results obtained from Electronic Data Deliverable (EDD) provided by Bryan Moeller of 
information relevant to the respective row
results not detected at concentrations which equal the laboratory's MDL; "J" is used to identify 
NE indicates not established; NA indicates not analyzed; blank cells indicate that there is no 
the SWSL
March 29, 2017
Duke Energy Carolinas, LLC
C1 Leachate
µg/L indicates micrograms per liter
Laboratory Certification Codes:
Duke Energy Carolinas Field #5193
Duke Energy Analytical Laboratory #248
According to the Constituent Look‐up webpage on the NCDEQ Division of Waste Management 
6.5
4,587
16.37
(last updated June 13, 2011)
webpage, there is no SWSL for choride associated with CAS number 16887‐08‐6, 
in a sample that can be quantitatively determined with suitable precision and accuracy
SWSL is the Solid Waste Section Limit. NCDEQ defines the SWSL as the lowest amount of analyte 

A
Appendix A
Field Sampling Forms

STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 222.0 ŷŷŹ 227 226.5 ŷŷŹ 227
SS 74.4 ŷŷŹ 75 74.6 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)6.99 ŷŷŹ 7.02 7.04 ŷŷŹ 7.02
B (4.00)3.99 ŷŷŹ 4.00 4.02 ŷŷŹ 4.00
B (10.00)10.03 ŷŷŹ 10.06 10.05 ŷŷŹ 10.04
20.31 20.55
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
437 ŷŷŹ 441 441 ŷŷŹ 440
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.11 20.41
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.89 ŷŷŹ 8.92 8.92 ŷŷŹ 8.93
After Cal 8.91 99.83 8.93 99.98
LCS 8.93 100.06 8.94 100.09
LCSD 8.94 0.11 8.95 0.11
SS 50.9 ŷŷŹ 51.2 51.5 ŷŷŹ 51.2
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
FIELD SAMPLING CALIBRATION FORM
DATE (s): March 29, 2017 SURFACE UNIT READER:
MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING PROGRAM
OTHER EQUIPMENT:TURBIDIMETER NO.3 - 3260-GW WEATHER CONDITIONS:Clear, calm, 45 to 70 deg F
LDC
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0800
ANALYZER MODEL#: HL4 400439
3210.6 VALIDATED BY:
Calibration Date / Time 29-Mar-17 450 30-Mar-17 550
HYDROLAB PROCEDURE #:
CALIBRATION BP (mmHg)741.92 CALIBRATION BP (mmHg)744.39
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
109.20 107.10
ORP Temp. ORP Temp.
DO
(mg/L)
19.68 19.81
741.92
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
744.39
CALIBRATION PASS CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.41 (mmHg)Ending BP 742.17
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R
SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R
de
ORP
TUR
(ntu
STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 222.3 ŷŷŹ 227 226.1 ŷŷŹ 227
SS 74.8 ŷŷŹ 75 73.1 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)6.93 ŷŷŹ 7.02 7.01 ŷŷŹ 7.02
B (4.00)4.01 ŷŷŹ 4.00 3.99 ŷŷŹ 4.00
B (10.00)10.05 ŷŷŹ 10.06 10.03 ŷŷŹ 10.04
20.28 20.53
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
439 ŷŷŹ 441 440.0 ŷŷŹ 440
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.10 20.35
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.92 ŷŷŹ 8.94 8.97 ŷŷŹ 8.94
After Cal 8.94 100.05 8.96 100.23
LCS 8.99 100.61 8.99 100.57
LCSD 8.97 -0.22 9.02 0.33
SS 54.1 ŷŷŹ 54.3 53.6 ŷŷŹ 54.3
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Beginning BP
DATE (s): March 29, 2017 SURFACE UNIT READER: PSP
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0662
ANALYZER MODEL#: HL4 400440
HYDROLAB PROCEDURE #:3210.6 VALIDATED BY:
Parameter
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, calm, 45 to 70 deg F
CALIBRATION BP (mmHg)741.92 CALIBRATION BP (mmHg)744.39
Calibration Date / Time 29-Mar-17 430 30-Mar-17 535
Calibration Results Calibration Results
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
Buffer Temp.
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED
742.41
SS = Standard solution
TURB
(ntu)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
(mmHg)
ORP CALIBRATION ACCEPTED
Field Barometric Pressure
CALIBRATION ACCEPTED
Buffer Temp.
104.10
After Cal % SAT After Cal % SAT
CALIBRATION PASS
Replaced DO electrolyte See Notes
Buffer Temp.
See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK
See Notes
ORP Temp. ORP Temp.
104.60
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Cleaned Electrodes
INSTRUMENT MAINTENANCE DATE / TIME
DO
(mg/L)
19.62 19.77
741.92 744.39
CALIBRATION PASS
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Replaced ref Electrode KCL
LCSD = Lab Control Standard DuplicateW = Winkler
Replaced Ref. Electrode Tip
pH Subsystem
Cleaned Electrodes
Conductance Subsystem
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK See Notes Tested - OK
(mmHg)
B = Buffer ŷŷŹ $GMXVWHG7R
N/A = Not Applicable
LCS = Lab Control Standard
Ending BP 742.17
ŷŷŹ 1RW$GMXVWHG7R
BP = Barometric Pressure
NOTES:
AW = Average Winkler
MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING PROGRAM
FIELD SAMPLING CALIBRATION FORM
WEATHER CONDITIONS:
de
ORP
TUR
(ntu
N/A
41.58 51.58
35 (psi)15 (sec) (sec)
(gal)
0.95 (gal)
@
QC By:
WELL VOL:
N/AN/A
DATE: TIME: WATER LEVEL:
Evacuated:If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge. Sampled:
SAMPLING PROCEDURE NO. 3175.4
MS-8
NO
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Fire ants around well pad.
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
ACCESS TO WELLS
WELL CAPS
FLUSH MOUNT WELLS
< 2.0Sample preservation verified to pH
(units)
N/A
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
NO 15.26 43 6.02 16.1 435 6.24
0.75 NO 15.07 44 6.03 9.8
CHLORINE(mg/l)SAMPLE COLLECTED BY DATE TIME
3.25
(recalculates on
current water level)(mV -NHE)(mg/L)
0.75 47.76
1.00 47.27 NO 15.46 47 6.12 2.2 460
418 6.98
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
6.89
0.75 NO 15.16 44 6.03 10.2 419 6.42
0.70
0.62
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
PURGE METHOD
Conventional
WELL TYPE WELL INFORMATION
MONITORING WELL
5.82
WATER ELEVATION (ft msl) 826.58 WELL VOLUME
ODOR STRENGTH None
WELL/SAMPLING INFORMATION
(gal)
NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 51.58 GS ELEV (ft msl) 869.35 PUMP INTAKE DEPTH (ft TOC) 50.60
26055 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
ELEV REF
RECHARGE DISCHARGE 5
SITE NAME
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME
SAMPLING DATE(s)29-Mar-2017 WELL/LOCATION NAME
DUKE ENERGY
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 872.34 MIDDLE OF WETTED SCREEN (ft toc)48.67
SCREEN LENGTH (ft) 10
WELL USE
FOSSIL LANDFILL NPDES
PUMP CONTROLLER SETTINGS
PRESSURE
0.95
DETECTED ODOR None
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 45.76 WATER COLUMN (ft)
STICK UP WELL
OXYGEN
LDC 3/29/2017 0805
TOTAL PURGE
VOLUME
Fire Ants
Casing in good condition
Well Impacted By Silting:
Lock in good conditionWELL LOCK CONDITION
Good Condition
LDC, PSP
SITE ID 18-09PERMIT #MARSHALL STEAM STATION
FIELD CREWFGD LANDFILL GROUNDWATER MONITORING PROGRAM
SAMPLING NOTES
Access cleared around wellACCESS AROUND WELL
Well cap in good conditon
Well tag in good condition
Access cleared into well
Well found lockedWELL SECURITY
29 M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
43.00 53.00
22 (psi)10 (sec) (sec)
(gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.20 (gal)LDC 3/29/2017 0910
DRAW-DOWN 0.82 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 0.25 (gal)
7.95 N/A
7.79 N/A
9:05 44.21 240 15.88 81 6.69 4.0 353
7.66 N/A
9:00 44.21 240 15.87 83 6.70 1.8 354
7.52 N/A
8:55 44.21 240 15.82 85 6.71 1.9 351
7.27 N/A
8:50 44.21 240 15.59 89 6.75 1.9 342
6.94 N/A
8:45 44.21 240 15.82 90 6.78 1.7 326
7.09 N/A
8:40 44.21 240 15.80 94 6.86 2.4 304
(mV-NHE)(mg/L)
8:35 44.21 240 15.80 83 6.76 1.4 393
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 824.65 WELL VOLUME 1.57
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 43.39 WATER COLUMN (ft) 9.61
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 26055 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 53.00 GS ELEV (ft msl) 865.36 PUMP INTAKE DEPTH (ft TOC) 52.00
MS-9
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 868.04 MIDDLE OF WETTED SCREEN (ft toc)48.20
SAMPLING DATE(s)29-Mar-201729
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
13.34 23.34
10 (psi)5 (sec) (sec)
(gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.85 (gal)LDC 3/29/2017 1000
DRAW-DOWN 0.18 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 0.25 (gal)
6.26 N/A
6.46 N/A
9:55 17.69 220 16.06 19 5.09 3.4 477
6.90 N/A
9:50 17.69 220 16.06 19 5.10 2.5 470
(mV-NHE)(mg/L)
9:45 17.69 220 15.90 19 5.10 0.7 458
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 833.78 WELL VOLUME 0.95
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 17.51 WATER COLUMN (ft) 5.83
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 26055 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 23.34 GS ELEV (ft msl) 848.29 PUMP INTAKE DEPTH (ft TOC) 22.30
MS-10
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 851.29 MIDDLE OF WETTED SCREEN (ft toc)20.43
SAMPLING DATE(s)29-Mar-201729
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
32.72 42.72
20 (psi)10 (sec) (sec)
(gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.50 (gal)PSP 3/29/2017 0755
DRAW-DOWN 0.97 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 2.00 (gal)
7.35 N/A
7.37 N/A
7:50 35.35 376 14.41 41 5.48 2.9 446
7.40 N/A
7:45 35.35 376 14.41 40 5.49 3.4 444
7.45 N/A
7:40 35.35 376 14.40 40 5.49 3.5 439
(mV-NHE)(mg/L)
7:35 35.35 376 14.39 40 5.47 4.4 431
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 825.40 WELL VOLUME 1.36
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 34.38 WATER COLUMN (ft) 8.34
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28652 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 42.72 GS ELEV (ft msl) 856.87 PUMP INTAKE DEPTH (ft TOC) 41.70
MS-11
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 859.78 MIDDLE OF WETTED SCREEN (ft toc)38.55
SAMPLING DATE(s)29-Mar-201729
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
21.09 31.09
15 (psi)10 (sec) (sec)
(gal)
1.13 (gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
0855 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)SAMPLE COLLECTED BY DATE TIME
6.25 PSP 3/29/2017
N/A N/A N/A
Sampled:N/A N/A N/A N/A
7.92
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
7.97
1.25 NO 14.79 25 5.05 9.0 595
8.00
1.25 NO 14.78 25 5.06 10.7 592
8.02
1.25 NO 14.78 24 5.06 18.8 586
8.05
1.25 NO 14.77 24 5.07 23.2 579
(mV -NHE)(mg/L)
1.25 NO 14.77 25 5.07 38.3 568
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(gal)
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 811.48 WELL VOLUME 1.13
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 24.18 WATER COLUMN (ft) 6.91
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28652 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 31.09 GS ELEV (ft msl) 832.70 PUMP INTAKE DEPTH (ft TOC) 30.10
MS-12
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 835.66 MIDDLE OF WETTED SCREEN (ft toc)27.64
SAMPLING DATE(s)29-Mar-201729M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
31.52 41.52
23 (psi)10 (sec) (sec)
(gal)
1.57 (gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
0950 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE(mg/l)SAMPLE COLLECTED BY DATE TIME
7.00 PSP 3/29/2017
N/A N/A N/A
Sampled:N/A N/A N/A N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
4.13
4.09
1.75 NO 14.40 60 5.38 2.9 495
4.07
1.75 NO 14.39 60 5.38 2.5 469
4.62
1.75 NO 14.39 59 5.36 2.9 511
(mV -NHE)(mg/L)
1.75 NO 14.38 55 5.33 4.7 459
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(gal)
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 810.03 WELL VOLUME 1.57
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 31.87 WATER COLUMN (ft) 9.65
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28652 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 41.52 GS ELEV (ft msl) 839.19 PUMP INTAKE DEPTH (ft TOC) 40.50
MS-13
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 841.90 MIDDLE OF WETTED SCREEN (ft toc)36.70
SAMPLING DATE(s)29-Mar-201729M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
34.38 44.38
25 (psi)10 (sec) (sec)
(gal)
1.17 (gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Sediment was covering well pad, unable to adequately inspect well pad.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Debris covering well pad Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
1250 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE(mg/l)SAMPLE COLLECTED BY DATE TIME
4.25 PSP 3/29/2017
N/A N/A N/A
Sampled:N/A N/A N/A N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
7.68
7.43
1.25 NO 15.32 57 5.89 4.6 521
7.12
1.25 NO 15.20 57 5.89 5.4 520
(mV -NHE)(mg/L)
1.75 NO 15.18 58 5.93 8.4 515
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(gal)
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 806.85 WELL VOLUME 1.17
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 37.22 WATER COLUMN (ft) 7.16
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28652 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 44.38 GS ELEV (ft msl) 841.27 PUMP INTAKE DEPTH (ft TOC) 43.40
MS-14
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 844.07 MIDDLE OF WETTED SCREEN (ft toc)40.80
SAMPLING DATE(s)29-Mar-201729M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
53.08 63.08
30 (psi)12 (sec) (sec)
(gal)
1.67 (gal)
@
QC By:
SAMPLING NOTES
WELL SECURITY Well found unlocked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Well was found unlocked.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
1210 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE(mg/l)SAMPLE COLLECTED BY DATE TIME
8.50 LDC 3/29/2017
N/A N/A
Sampled:
7.51
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:
7.55 1.30
1.50 NO 16.70 139 6.49 0.5 484
7.55
1.75 55.08 NO 16.65 141 6.52 0.6 466
7.58
1.75 NO 16.48 142 6.57 1.0 455
7.58
1.75 NO 16.47 144 6.72 1.1 433
(mV -NHE)(mg/L)
1.75 NO 16.31 172 6.75 1.2 415
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(gal)
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 808.63 WELL VOLUME 1.67
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 52.84 WATER COLUMN (ft) 10.24
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
LEVEL METER SERIAL# 26055 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 63.08 GS ELEV (ft msl) 858.42 PUMP INTAKE DEPTH (ft TOC) 62.10
MS-15
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 861.47 MIDDLE OF WETTED SCREEN (ft toc)58.08
SAMPLING DATE(s)29-Mar-201729M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
27.46 37.46
18 (psi)10 (sec) (sec)
(gal)
1.91 (gal)
@
QC By:
SAMPLING NOTES
After 1st well volume, water level drops below top of pump and well considered evacuated.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag damaged / illegible
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon Tag was illegible, could not read information on tag.
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
Sample preservation verified to pH
(units)< 2.0
1110 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE(mg/l)SAMPLE COLLECTED BY DATE TIME
4.75 PSP 3/29/2017
N/A BELOW PUMP N/A
Sampled:N/A N/A N/A
8.72
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
8.04
0.50 YES 17.42 102 6.30 39.6 487
6.82
0.50 NO 17.25 106 6.28 63.9 474
6.58 0.48
0.50 NO 16.88 106 6.17 60.7 467
6.46 1.25
1.25 34.51 NO 16.41 107 6.14 68.5 465
(mV -NHE)(mg/L)
2.00 29.79 NO 16.39 109 6.12 19.5 440
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(gal)
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 811.23 WELL VOLUME 1.91
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 25.75 WATER COLUMN (ft) 11.71
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
SEE NOTE BELOW PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28652 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 37.46 GS ELEV (ft msl) 834.25 PUMP INTAKE DEPTH (ft TOC) 36.50
MS-16
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 836.98 MIDDLE OF WETTED SCREEN (ft toc)32.46
SAMPLING DATE(s)29-Mar-201729M
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SAMPLING NOTES
Location was effectively dry, minimal water present from rain events the past few days, not enough water/deep enough to collect samples, the standing water present would not have been a
representative sample, no samples collected.
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
TIME
PSP 3/29/2017 N/A
Sample preservation verified to pH
(units)N/A
N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR
ODOR STRENGTH LOCATION DRY - SEE NOTE BELOWAPPEARANCE
SAMPLING INFORMATION
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
WELL/LOCATION NAME
SAMPLING METHOD: LOCATION ENVIRONMENT: WOODED LOCATION DRY
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: WAS WATER PRESENT: NO WAS THERE A NOTICABLE FLOW: NO
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
SW-1SAMPLING DATE(s)29-Mar-201729
T SP DISSTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SAMPLING NOTES
Sample untreated leachate from leachate piping at SE corner of landfill
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
TIME
PSP 3/29/2017 1015 N/A
Sample preservation verified to pH
(units)< 2.0
55.1 169 9.26 N/A
FLOW
CONDITIONS:
Flow from leachate drainage pipe. Purged about
3.00 gallons before taking reading of field
parameters @ ~ 1700 ml/min
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 16.37 4587 6.53
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Turbid
SAMPLING INFORMATION
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
WELL/LOCATION NAME
SAMPLING METHOD: PERISTALTIC PUMP LOCATION ENVIRONMENT: FIELD
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
C1-LEACHATESAMPLING DATE(s)29-Mar-201729
T SP DISSTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
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B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J17030078
Project Name:MARSHALL - GW FGD LANDFILL
Lab Contact: Anne Pridgeon
Date:4/17/2017
Customer Address:8320 NC Hwy 150 East
Customer Name(s):Chuck Campbell, Ed Sullivan, Tim Hunsucker
Mail Code: Marshall Steam Station
Terrell, NC 28682
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Page 1 of 26
Reason: I have reviewed
this document.
Date: 2017.04.17 11:57:48
-04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2017007056 MARSHALL 29-Mar-17 8:05 AM LDC MS-8
2017007058 MARSHALL 29-Mar-17 9:10 AM LDC MS-9
2017007059 MARSHALL 29-Mar-17 10:00 AM LDC MS-10
2017007060 MARSHALL 29-Mar-17 7:55 AM PSP MS-11
2017007061 MARSHALL 29-Mar-17 8:55 AM PSP MS-12
2017007062 MARSHALL 29-Mar-17 9:50 AM PSP MS-13
2017007063 MARSHALL 29-Mar-17 12:50 PM PSP MS-14
2017007064 MARSHALL 29-Mar-17 12:10 PM LDC MS-15
2017007065 MARSHALL 29-Mar-17 11:10 AM PSP MS-16
2017007067 MARSHALL 29-Mar-17 10:15 AM PSP C-1 LEACHATE
2017007068 MARSHALL 29-Mar-17 1:00 PM LDC FIELD BLANK
11 Total Samples
Page 2 of 26
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/17/2017
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007056
Collection Date:29-Mar-17 8:05 AM
Site:MS-8
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 03/30/2017 13:55 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 03/29/2017 16:13 BGN90340.1 1
Fluoride 0.14 mg/L EPA 9056A 03/29/2017 16:13 BGN90340.1 1
Nitrate 0.50 mg/L EPA 9056A 03/29/2017 16:13 BGN90340.1 1
Nitrate as N 0.11 mg-N/L EPA 9056A 03/29/2017 16:13 BGN90340.023 1
Sulfate 0.17 mg/L EPA 9056A 03/29/2017 16:13 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:02 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:19 MHH71310.05 1
Calcium (Ca)2.94 mg/L SW 6010D 04/11/2017 10:19 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Iron (Fe)0.558 mg/L SW 6010D 04/11/2017 10:19 MHH71310.01 1
Magnesium (Mg)1.42 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Manganese (Mn)0.006 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Potassium (K)1.07 mg/L SW 6010D 04/11/2017 10:19 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
Sodium (Na)4.13 mg/L SW 6010D 04/11/2017 10:19 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 10:19 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Chromium (Cr)5.11 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
Vanadium (V)5.15 ug/L SW 6020B 04/03/2017 18:45 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 45 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 4 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007058
Collection Date:29-Mar-17 9:10 AM
Site:MS-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)34 mg/L
(CaCO3)
SM 2320B201
INORGANIC IONS BY IC
Chloride 1.1 mg/L EPA 9056A 03/29/2017 17:05 BGN90340.1 1
Fluoride 0.14 mg/L EPA 9056A 03/29/2017 17:05 BGN90340.1 1
Nitrate 0.70 mg/L EPA 9056A 03/29/2017 17:05 BGN90340.1 1
Nitrate as N 0.16 mg-N/L EPA 9056A 03/29/2017 17:05 BGN90340.023 1
Sulfate 0.38 mg/L EPA 9056A 03/29/2017 17:05 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:09 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:31 MHH71310.05 1
Calcium (Ca)10.8 mg/L SW 6010D 04/11/2017 10:31 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Iron (Fe)0.132 mg/L SW 6010D 04/11/2017 10:31 MHH71310.01 1
Magnesium (Mg)0.906 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Manganese (Mn)0.009 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Potassium (K)1.23 mg/L SW 6010D 04/11/2017 10:31 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
Sodium (Na)3.76 mg/L SW 6010D 04/11/2017 10:31 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 10:31 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Chromium (Cr)2.86 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
Vanadium (V)2.93 ug/L SW 6020B 04/03/2017 18:14 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 68 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 5 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007059
Collection Date:29-Mar-17 10:00 AM
Site:MS-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/30/2017 14:14 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 03/29/2017 17:22 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/29/2017 17:22 BGN90340.1 1
Nitrate 2.9 mg/L EPA 9056A 03/29/2017 17:22 BGN90340.1 1
Nitrate as N 0.65 mg-N/L EPA 9056A 03/29/2017 17:22 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/29/2017 17:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:11 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.119 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 11:06 MHH71310.05 1
Calcium (Ca)0.233 mg/L SW 6010D 04/11/2017 11:06 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Iron (Fe)0.225 mg/L SW 6010D 04/11/2017 11:06 MHH71310.01 1
Magnesium (Mg)0.392 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Manganese (Mn)0.024 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Potassium (K)0.919 mg/L SW 6010D 04/11/2017 11:06 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
Sodium (Na)1.83 mg/L SW 6010D 04/11/2017 11:06 MHH71310.05 1
Zinc (Zn)0.006 mg/L SW 6010D 04/11/2017 11:06 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
Vanadium (V)1.02 ug/L SW 6020B 04/03/2017 18:53 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 6 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007060
Collection Date:29-Mar-17 7:55 AM
Site:MS-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)13 mg/L
(CaCO3)
SM 2320B 03/30/2017 14:20 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.1 mg/L EPA 9056A 03/29/2017 17:40 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/29/2017 17:40 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/29/2017 17:40 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/29/2017 17:40 BGN90340.023 1
Sulfate 0.24 mg/L EPA 9056A 03/29/2017 17:40 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:14 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.069 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 11:10 MHH71310.05 1
Calcium (Ca)2.45 mg/L SW 6010D 04/11/2017 11:10 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Iron (Fe)0.114 mg/L SW 6010D 04/11/2017 11:10 MHH71310.01 1
Magnesium (Mg)1.23 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Manganese (Mn)0.006 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Potassium (K)1.98 mg/L SW 6010D 04/11/2017 11:10 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
Sodium (Na)2.70 mg/L SW 6010D 04/11/2017 11:10 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 11:10 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Chromium (Cr)2.45 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
Vanadium (V)< 1 ug/L SW 6020B 04/03/2017 19:01 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 36 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 7 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007061
Collection Date:29-Mar-17 8:55 AM
Site:MS-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/30/2017 14:27 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.0 mg/L EPA 9056A 03/29/2017 17:57 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/29/2017 17:57 BGN90340.1 1
Nitrate 0.54 mg/L EPA 9056A 03/29/2017 17:57 BGN90340.1 1
Nitrate as N 0.12 mg-N/L EPA 9056A 03/29/2017 17:57 BGN90340.023 1
Sulfate 0.22 mg/L EPA 9056A 03/29/2017 17:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.078 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:43 MHH71310.05 1
Calcium (Ca)0.183 mg/L SW 6010D 04/11/2017 10:43 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Iron (Fe)0.305 mg/L SW 6010D 04/11/2017 10:43 MHH71310.01 1
Magnesium (Mg)0.526 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Manganese (Mn)0.028 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Potassium (K)2.06 mg/L SW 6010D 04/11/2017 10:43 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
Sodium (Na)1.93 mg/L SW 6010D 04/11/2017 10:43 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 10:43 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
Vanadium (V)1.07 ug/L SW 6020B 04/03/2017 19:09 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 8 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007062
Collection Date:29-Mar-17 9:50 AM
Site:MS-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B 03/30/2017 14:33 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 9056A 03/29/2017 18:15 BGN90340.2 2
Fluoride 0.12 mg/L EPA 9056A 03/29/2017 18:15 BGN90340.1 1
Nitrate 6.0 mg/L EPA 9056A 03/29/2017 18:15 BGN90340.1 1
Nitrate as N 1.4 mg-N/L EPA 9056A 03/29/2017 18:15 BGN90340.023 1
Sulfate 0.22 mg/L EPA 9056A 03/29/2017 18:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/08/2017 13:19 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.088 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:47 MHH71310.05 1
Calcium (Ca)5.09 mg/L SW 6010D 04/11/2017 10:47 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Iron (Fe)0.072 mg/L SW 6010D 04/11/2017 10:47 MHH71310.01 1
Magnesium (Mg)1.14 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Manganese (Mn)0.008 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Potassium (K)2.22 mg/L SW 6010D 04/11/2017 10:47 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
Sodium (Na)3.29 mg/L SW 6010D 04/11/2017 10:47 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 10:47 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
Vanadium (V)< 1 ug/L SW 6020B 04/03/2017 19:17 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 9 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007063
Collection Date:29-Mar-17 12:50 PM
Site:MS-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)24 mg/L
(CaCO3)
SM 2320B 03/30/2017 07:34 CJELLIO201
INORGANIC IONS BY IC
Chloride 0.97 mg/L EPA 9056A 03/29/2017 18:32 BGN90340.1 1
Fluoride 0.13 mg/L EPA 9056A 03/29/2017 18:32 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/29/2017 18:32 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/29/2017 18:32 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/29/2017 18:32 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/11/2017 13:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.046 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 11:14 MHH71310.05 1
Calcium (Ca)4.28 mg/L SW 6010D 04/11/2017 11:14 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Iron (Fe)0.101 mg/L SW 6010D 04/11/2017 11:14 MHH71310.01 1
Magnesium (Mg)0.890 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Potassium (K)1.59 mg/L SW 6010D 04/11/2017 11:14 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
Sodium (Na)6.13 mg/L SW 6010D 04/11/2017 11:14 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 11:14 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
Vanadium (V)2.44 ug/L SW 6020B 04/03/2017 19:25 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 59 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 10 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007064
Collection Date:29-Mar-17 12:10 PM
Site:MS-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)63 mg/L
(CaCO3)
SM 2320B 03/30/2017 07:38 CJELLIO201
INORGANIC IONS BY IC
Chloride 3.0 mg/L EPA 9056A 03/29/2017 18:50 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 03/29/2017 18:50 BGN90340.1 1
Nitrate 1.0 mg/L EPA 9056A 03/29/2017 18:50 BGN90340.1 1
Nitrate as N 0.23 mg-N/L EPA 9056A 03/29/2017 18:50 BGN90340.023 1
Sulfate 0.97 mg/L EPA 9056A 03/29/2017 18:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/11/2017 13:33 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.112 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:55 MHH71310.05 1
Calcium (Ca)17.2 mg/L SW 6010D 04/11/2017 10:55 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Iron (Fe)0.011 mg/L SW 6010D 04/11/2017 10:55 MHH71310.01 1
Magnesium (Mg)4.87 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Potassium (K)2.49 mg/L SW 6010D 04/11/2017 10:55 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
Sodium (Na)4.39 mg/L SW 6010D 04/11/2017 10:55 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 10:55 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Chromium (Cr)20.2 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
Vanadium (V)4.25 ug/L SW 6020B 04/03/2017 19:32 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 88 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 11 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007065
Collection Date:29-Mar-17 11:10 AM
Site:MS-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)46 mg/L
(CaCO3)
SM 2320B 03/30/2017 07:40 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.5 mg/L EPA 9056A 03/29/2017 19:07 BGN90340.1 1
Fluoride 0.22 mg/L EPA 9056A 03/29/2017 19:07 BGN90340.1 1
Nitrate 1.8 mg/L EPA 9056A 03/29/2017 19:07 BGN90340.1 1
Nitrate as N 0.40 mg-N/L EPA 9056A 03/29/2017 19:07 BGN90340.023 1
Sulfate 0.34 mg/L EPA 9056A 03/29/2017 19:07 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/11/2017 13:36 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.104 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 10:59 MHH71310.05 1
Calcium (Ca)8.52 mg/L SW 6010D 04/11/2017 10:59 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Iron (Fe)1.74 mg/L SW 6010D 04/11/2017 10:59 MHH71310.01 1
Magnesium (Mg)3.93 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Manganese (Mn)0.023 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Potassium (K)2.37 mg/L SW 6010D 04/11/2017 10:59 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
Sodium (Na)7.23 mg/L SW 6010D 04/11/2017 10:59 MHH71310.05 1
Zinc (Zn)0.006 mg/L SW 6010D 04/11/2017 10:59 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Chromium (Cr)4.20 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
Vanadium (V)7.82 ug/L SW 6020B 04/03/2017 20:04 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 89 mg/L SM2540C 03/30/2017 15:00 MGIGANT251
Page 12 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007067
Collection Date:29-Mar-17 10:15 AM
Site:C-1 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 03/30/2017 14:40 CJELLIO51
INORGANIC IONS BY IC
Chloride 370 mg/L EPA 9056A 03/29/2017 20:51 BGN9034550
Fluoride < 5 mg/L EPA 9056A 03/29/2017 20:51 BGN9034550
Nitrate 14 mg/L EPA 9056A 03/29/2017 20:51 BGN9034550
Nitrate as N 3.1 mg-N/L EPA 9056A 03/29/2017 20:51 BGN90340.023 1
Sulfate 2800 mg/L EPA 9056A 03/29/2017 20:51 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/11/2017 13:38 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.021 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Boron (B)45.7 mg/L SW 6010D 04/11/2017 11:30 MHH71310.5 10
Calcium (Ca)610 mg/L SW 6010D 04/11/2017 11:30 MHH71310.1 10
Cobalt (Co)0.035 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Iron (Fe)165 mg/L SW 6010D 04/11/2017 11:30 MHH71310.1 10
Magnesium (Mg)199 mg/L SW 6010D 04/11/2017 11:30 MHH71310.05 10
Manganese (Mn)4.61 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Nickel (Ni)0.091 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Potassium (K)91.0 mg/L SW 6010D 04/11/2017 11:30 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
Sodium (Na)153 mg/L SW 6010D 04/11/2017 11:30 MHH71310.5 10
Zinc (Zn)0.139 mg/L SW 6010D 04/11/2017 11:30 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Arsenic (As)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Cadmium (Cd)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Chromium (Cr)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Lead (Pb)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Selenium (Se)145 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Thallium (Tl)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
Vanadium (V)< 10 ug/L SW 6020B 04/04/2017 21:41 CWSPEN31010
TOTAL DISSOLVED SOLIDS
TDS 4000 mg/L SM2540C 03/30/2017 15:00 MGIGANT5001
Page 13 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
2017007068
Collection Date:29-Mar-17 1:00 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 03/30/2017 07:48 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 03/29/2017 20:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 03/29/2017 20:34 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 03/29/2017 20:34 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 03/29/2017 20:34 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 03/29/2017 20:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 04/11/2017 13:41 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 04/11/2017 11:18 MHH71310.05 1
Calcium (Ca)< 0.01 mg/L SW 6010D 04/11/2017 11:18 MHH71310.01 1
Cobalt (Co)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 04/11/2017 11:18 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 04/11/2017 11:18 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 04/11/2017 11:18 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 04/11/2017 11:18 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Thallium (Tl)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Vanadium (V)< 1 ug/L SW 6020B 04/03/2017 20:20 CWSPEN311
Page 14 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030738 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030078 -- 2017007058
Alkalinity (mg/L CaCO3) 35 1.53mg/L (CaCO3)-135
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 96.1 103 93.3mg/L (CaCO3)-12080196.1
Alkalinity (mg/L CaCO3) 96.1 103 93.3mg/L
(CaCO3)
-196.1
Page 15 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030772 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030078 -- 2017007056
Alkalinity (mg/L CaCO3) 17.9 1.24mg/L (CaCO3)-117.9
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 18.7 20.6 90.6mg/L (CaCO3)-12080118.7
Page 16 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030714 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0251 mg/L -10.0251 0.1 < 1/2 RDL
Fluoride 0.026 mg/L -10.026 0.1 < 1/2 RDL
Nitrate 0.0176 mg/L -10.0176 0.1 < 1/2 RDL
Sulfate -0.0141 mg/L -1-0.0141 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.17 5 98.8mg/L -1208016.17
Fluoride 4.98 5 96.8mg/L -1208014.98
Nitrate 5.46 5 99.3mg/L -1208015.46
Sulfate 5.11 5 98.7mg/L -1208015.11
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.16 5 98.6 0.203mg/L -1208016.16
Fluoride 4.95 5 96.2 0.665mg/L -1208014.95
Nitrate 5.48 5 99.6 0.388mg/L -1208015.48
Sulfate 5.1 5 98.7 0.073mg/L -1208015.1
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5 5 100mg/L -1208015
Fluoride 5.16 5 103mg/L -1208015.16
Nitrate 5.03 5 101mg/L -1208015.03
Sulfate 5.04 5 101mg/L -1208015.04
Page 17 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17040158 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.99 2 99.3ug/L -1158511.99
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.85 2 92.6ug/L -1158511.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030469 -- 2017009210
Mercury (Hg) 0.953 1 95.6ug/L -1257510.953
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030469 -- 2017009210
Mercury (Hg) 0.955 1 95.8 0.209ug/L -1257510.955
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030500 -- 2017009355
Mercury (Hg) 0.625 1 53.8ug/L -1257510.625
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030500 -- 2017009355
Mercury (Hg) 0.647 1 56 4.01ug/L -1257510.647
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17030537 -- 2017009506
Mercury (Hg) 0.953 1 94.2ug/L -1257510.953
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17030537 -- 2017009506
Mercury (Hg) 0.938 1 92.7 1.61ug/L -1257510.938
Page 18 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17040158 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007056
Mercury (Hg) 0.918 1 91.8ug/L -1257510.918
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007056
Mercury (Hg) 0.937 1 93.7 2.05ug/L -1257510.937
Page 19 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17040229 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.001 ug/L -1-0.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) -0.003 ug/L -1-0.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.3ug/L -1158511.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.3ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007063
Mercury (Hg) 0.958 1 95.8ug/L -1257510.958
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007063
Mercury (Hg) 0.973 1 97.3 1.55ug/L -1257510.973
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17030579 -- 2017009702
Mercury (Hg) 0.953 1 95.1ug/L -1257510.953
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17030579 -- 2017009702
Mercury (Hg) 0.938 1 93.6 1.59ug/L -1257510.938
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J17030611 -- 2017009991
Mercury (Hg) 0.941 1 93.9ug/L -1257510.941
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J17030611 -- 2017009991
Mercury (Hg) 0.938 1 93.6 0.32ug/L -1257510.938
Page 20 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030782 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000379 mg/L -10.000379 0.005 < 1/2 RDL
Beryllium (Be) 0.000806 mg/L -10.000806 0.005 < 1/2 RDL
Boron (B) 0.000177 mg/L -10.000177 0.05 < 1/2 RDL
Calcium (Ca) 0.00402 mg/L -10.00402 0.01 < 1/2 RDL
Cobalt (Co) 0.00067 mg/L -10.00067 0.005 < 1/2 RDL
Copper (Cu) 0.000767 mg/L -10.000767 0.005 < 1/2 RDL
Iron (Fe) 0.00153 mg/L -10.00153 0.01 < 1/2 RDL
Magnesium (Mg) -0.000764 mg/L -1-0.000764 0.005 < 1/2 RDL
Manganese (Mn) 0.000663 mg/L -10.000663 0.005 < 1/2 RDL
Nickel (Ni) 0.000492 mg/L -10.000492 0.005 < 1/2 RDL
Potassium (K) -0.0147 mg/L -1-0.0147 0.1 < 1/2 RDL
Silver (Ag) 0.000218 mg/L -10.000218 0.005 < 1/2 RDL
Sodium (Na) 0.00539 mg/L -10.00539 0.05 < 1/2 RDL
Zinc (Zn) 0.00113 mg/L -10.00113 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.01 5 100mg/L -1208015.01
Beryllium (Be) 4.96 5 99.1mg/L -1208014.96
Boron (B) 4.98 5 99.6mg/L -1208014.98
Calcium (Ca) 5.04 5 101mg/L -1208015.04
Cobalt (Co) 4.99 5 99.8mg/L -1208014.99
Copper (Cu) 4.95 5 99mg/L -1208014.95
Iron (Fe) 5.03 5 101mg/L -1208015.03
Magnesium (Mg) 4.92 5 98.3mg/L -1208014.92
Manganese (Mn) 5.01 5 100mg/L -1208015.01
Nickel (Ni) 5.01 5 100mg/L -1208015.01
Potassium (K) 4.9 5 98mg/L -1208014.9
Silver (Ag) 0.508 0.5 102mg/L -1208010.508
Sodium (Na) 4.89 5 97.7mg/L -1208014.89
Zinc (Zn) 5 5 100mg/L -1208015
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007056
Barium (Ba) 5 5 99.3mg/L -1257515
Beryllium (Be) 4.91 5 98.1mg/L -1257514.91
Boron (B) 4.88 5 97.5mg/L -1257514.88
Calcium (Ca) 7.74 5 95.9mg/L -1257517.74
Cobalt (Co) 4.92 5 98.5mg/L -1257514.92
Copper (Cu) 4.9 5 97.9mg/L -1257514.9
Page 21 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030782 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007056
Iron (Fe) 5.54 5 99.6mg/L -1257515.54
Magnesium (Mg) 6.16 5 94.7mg/L -1257516.16
Manganese (Mn) 4.95 5 98.9mg/L -1257514.95
Nickel (Ni) 4.95 5 98.9mg/L -1257514.95
Potassium (K) 5.9 5 96.6mg/L -1257515.9
Silver (Ag) 0.493 0.5 98.6mg/L -1257510.493
Sodium (Na) 8.83 5 94mg/L -1257518.83
Zinc (Zn) 4.92 5 98.4mg/L -1257514.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007056
Barium (Ba) 4.8 5 95.2 4.26mg/L -1257514.8
Beryllium (Be) 4.68 5 93.5 4.8mg/L -1257514.68
Boron (B) 4.7 5 93.9 3.74mg/L -1257514.7
Calcium (Ca) 7.56 5 92.5 3.67mg/L -1257517.56
Cobalt (Co) 4.65 5 93.1 5.64mg/L -1257514.65
Copper (Cu) 4.7 5 93.9 4.19mg/L -1257514.7
Iron (Fe) 5.34 5 95.7 3.95mg/L -1257515.34
Magnesium (Mg) 5.98 5 91.1 3.9mg/L -1257515.98
Manganese (Mn) 4.75 5 94.9 4.17mg/L -1257514.75
Nickel (Ni) 4.74 5 94.8 4.28mg/L -1257514.74
Potassium (K) 5.72 5 93 3.76mg/L -1257515.72
Silver (Ag) 0.472 0.5 94.4 4.32mg/L -1257510.472
Sodium (Na) 8.66 5 90.6 3.62mg/L -1257518.66
Zinc (Zn) 4.72 5 94.4 4.19mg/L -1257514.72
Page 22 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030791 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.033 ug/L -1-0.033 1 < 1/2 RDL
Arsenic (As) 0.028 ug/L -10.028 1 < 1/2 RDL
Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL
Chromium (Cr) 0.018 ug/L -10.018 1 < 1/2 RDL
Lead (Pb) 0.003 ug/L -10.003 1 < 1/2 RDL
Selenium (Se) 0.018 ug/L -10.018 1 < 1/2 RDL
Thallium (Tl) -0.028 ug/L -1-0.028 1 < 1/2 RDL
Vanadium (V) 0.232 ug/L -10.232 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.4 50 101ug/L -12080150.4
Arsenic (As) 48.9 50 97.7ug/L -12080148.9
Cadmium (Cd) 50.3 50 101ug/L -12080150.3
Chromium (Cr) 50.3 50 101ug/L -12080150.3
Lead (Pb) 50 50 99.9ug/L -12080150
Selenium (Se) 46.7 50 93.5ug/L -12080146.7
Thallium (Tl) 50 50 100ug/L -12080150
Vanadium (V) 49.7 50 99.4ug/L -12080149.7
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007058
Antimony (Sb) 48.9 50 97.7ug/L -12575148.9
Arsenic (As) 46.9 50 93.5ug/L -12575146.9
Cadmium (Cd) 48.9 50 97.7ug/L -12575148.9
Chromium (Cr) 51.3 50 96.9ug/L -12575151.3
Lead (Pb) 48.5 50 96.4ug/L -12575148.5
Selenium (Se) 45.4 50 90.7ug/L -12575145.4
Thallium (Tl) 50.3 50 101ug/L -12575150.3
Vanadium (V) 51.8 50 97.8ug/L -12575151.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007058
Antimony (Sb) 46.6 50 93.1 4.8ug/L -12575146.6
Arsenic (As) 44.4 50 88.4 5.55ug/L -12575144.4
Cadmium (Cd) 46.8 50 93.6 4.31ug/L -12575146.8
Chromium (Cr) 49.5 50 93.2 3.8ug/L -12575149.5
Lead (Pb) 46.2 50 91.9 4.81ug/L -12575146.2
Selenium (Se) 43 50 85.9 5.44ug/L -12575143
Thallium (Tl) 47.9 50 95.8 4.8ug/L -12575147.9
Page 23 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030791 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17030078 -- 2017007058
Vanadium (V) 49.6 50 93.4 4.53ug/L -12575149.6
Page 24 of 26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17030078
Q17030737 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17030078 -- 2017007056
TDS 40 11.8mg/L -140
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17030078 -- 2017007058
TDS 68 0mg/L -168
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030078 -- 2017007059
TDS 16 11.8mg/L -116
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 98 100 98mg/L -11090198
Page 25 of 26
Page 26 of 26