7906_Duke_DanRiver_Cell2_CCRRemovalVerificationReport_DIN27911_20170609

Belews Creek Steam Station 3195 Pine Hall Road Belews Creek, NC 27009
336-445-0610
336-669-2994

June 9, 2017

North Carolina Department of Environmental Quality Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Elizabeth Werner
Re: Coal Combustion Residual (CCR) Visual Removal Verification
Dan River Landfill Construction - Cell 2
Permit No.: 7906-INDUS-2016
Duke Energy Dan River Steam Station Rockingham County
Eden, North Carolina 27288

Dear Ms. Werner,
Attached you will find the CCR Removal Verification Report for Cell 2 of the Dan River Steam
Station Landfill. This report verifies the removal of CCR material in general accordance with
the Attachment 1, Guidance for Area 1 Dry Stack received from Solid Waste Section of the
Division of Waste Management, NCDEQ on October 11, 2016.
If there are any questions regarding this request, please contact me at [phone] or
[e-mail].

Respectfully submitted,
Melonie Martin Environmental Services
Attachments: Coal Combustion Residual (CCR) Visual Removal Verification, Dan River Landfill
Construction - Secondary Containment Area

cc (via e-mail): Ed Mussler, NCDEQ Shawn McKee, NCDEQ
Eric Kinstler, Duke Energy
Ed Sullivan, Duke Energy

Correspondence:
Amec Foster Wheeler
14424 Albemarle Point Place, Suite 115
Chantilly, Virginia 20151
Tel [phone]
Fax [phone]
Licensures: NC Engineering F-1253, Geology C-247

www.amecfw.com

June 9, 2017

Ms. Melonie Martin
Duke Energy Carolinas, LLC
Dan River Steam Station
3195 Pine Hall Road
Belews Creek, North Carolina 27009
[e-mail]

Subject: Coal Combustion Residual (CCR) Visual Removal Verification
Dan River Landfill Construction – Cell 2
Rockingham County, North Carolina
Amec Foster Wheeler Project No.: 7810-17-0870

Dear Ms. Martin:

Amec Foster Wheeler Environment and Infrastructure, Inc. (Amec Foster Wheeler) is pleased to
submit this documentation verifying Dan River Steam Station (Dan River) Landfill Cell 2 coal
combustion residual (CCR) removal by visual methods. We conclude that visual CCR removal
verification criteria has been satisfied in general accordance with Section 3.0 of the Excavation
Soil Sampling Plan for Area 1 Dry Stack, Rev. 0, dated October 2016 (Attachment 1), and as
approved by the North Carolina Department of Environmental Quality (NCDEQ).

Background

Area 1 Dry Stack, also known as Ash Fill 1, is located at Duke Energy’s Dan River Station in
Eden, North Carolina as shown in Figure 1. Construction of Ash Fill 1 occurred in the 1980s.
Ash Fill 1 is approximately 19.7 acres and contains an estimated CCR volume of 800,000 cubic
yards. Duke Energy is currently removing and transporting CCR material from Ash Fill 1 to an
off-site landfill. The majority of the Ash Fill 1 footprint will be within the proposed Dan River
Landfill grading limits. Figure 1 shows an overview of the site.

Field Execution

Field evaluation consisted of conducting a visual observation of CCR removal and collection of
samples for testing utilizing polarized light microscopy (PLM) and total metals analysis methods.
Amec Foster Wheeler construction quality assurance (CQA) personnel conducted visual
observations and collected samples between December 7 and December 8, 2016 for PLM and
total metals testing and evaluation.

Visual CCR Removal Verification Results

CCR removal was evaluated based on three criteria:

1. Comparison of estimated bottom of CCR grades to post-CCR removal grades;
2. Visual observation; and
3. PLM evaluation.
CCR Visual Removal Verification June 9, 2017
Dan River Landfill Construction – Cell 2 Amec Foster Wheeler Project No. 7810-17-0870
2

The evaluation results are discussed as follows.

Grade Comparison

The estimated bottom of CCR grades and spot elevations of the post-CCR removal grades are
presented in Figure 2 and summarized in the attached Table 1.

The post-CCR removal grades within the area where proposed Dan River Landfill Cell 2
overlaps Ash Fill 1 are generally at or below the estimated bottom of CCR grades, indicating
that CCR removal has been achieved in accordance with the Excavation Soil Sampling Plan as
approved by NCDEQ.

Visual Observation

Visual observation of CCR removal was performed on a 100-foot by 100-foot grid as shown in
Figure 2, the photograph log is included in Attachment 2. CCR material was not observed
during the visual observation, indicating that CCR removal has been achieved in accordance
with the Excavation Soil Sampling Plan as approved by NCDEQ.

PLM Evaluation

Sampling at a depth of 2-feet and visual soil classification were conducted on a one-acre grid as
shown in Figure 3 for PLM evaluation. The PLM evaluation was performed by RJ Lee Group,
results are included in Attachment 3. PLM results indicated a percentage of CCR ranging from
not detected to 1 percent. The maximum allowable CCR percentage is 50 percent as described
in the Excavation Soil Sampling Plan as approved by NCDEQ, indicating that CCR removal has
been achieved in accordance with the Plan. The results of a visual soil classification of near-
surface materials is presented in Table 2 and indicates that CCR removal has been achieved in
accordance with the Plan.

Total Metals Evaluation

Sampling at a depth of 6-inches, 2-feet, and 5-feet was conducted on a one-acre grid as shown
in Figure 3 for total metals evaluation. The total metals results are provided in Attachment 4
and summarized in Table 3.

Conclusions

CCR removal verification criteria has been satisfied in general accordance with Section 3.0 of
the Excavation Soil Sampling Plan for Area 1 Dry Stack, Rev. 0, dated October 2016, and as
approved by the NCDEQ.

CCR Visual Removal Verification June 9, 2017
Dan River Landfill Construction – Cell 2 Amec Foster Wheeler Project No. 7810-17-0870
3

Sincerely,

Amec Foster Wheeler Environment & Infrastructure, Inc.

Cedric H. Ruhl, P.E. Chris Jordan, EIT
Senior Engineer Technical Professional
[e-mail] [e-mail]

Attachments:
Table 1 – CCR Removal Grade Comparison
Table 2 – Field Documentation Summary
Table 3 – Laboratory Test Result Summary
Figure 1 – Site Location Map
Figure 2 – CCR Removal Verification – 100-ft x 100-ft Grid (Visual)
Figure 3 – CCR Removal Verification – One Acre Grid (Sampling)
Attachment 1 – Excavation Soil Sampling Plan for Area 1 Dry Stack
Attachment 2 – Photograph Log
Attachment 3 – Laboratory Test Results – RJ Lee Group
Attachment 4 – Analytical Laboratory Test Results

TABLES

1. CCR Removal Grade Comparison
2. Field Documentation Summary
3. Laboratory Test Result Summary

Point ID
Estimated Bottom of CCR
Elevation
(ft)
Post-CCR Removal
Elevation
(ft)
Elevation Difference1
(ft)
5286 581.97 569.58 -12.39
5287 590.00 578.06 -11.94
5288 583.64 575.77 -7.87
5289 589.31 575.1 -14.21
5290 590.01 582.62 -7.39
5291 590.01 568.62 -21.39
5292 590.05 573.41 -16.64
5293 590.54 582.4 -8.14
5294 587.72 567.33 -20.39
5295 579.62 565.46 -14.16
5296 590.02 583.04 -6.98
5297 584.85 581.59 -3.26
5298 574.00 574.15 0.15
5299 583.98 564.49 -19.49
5300 572.66 564.34 -8.32
5303 589.28 592.24 2.96
5304 590.14 596.65 6.51
21500 597.39 597.92 0.53
21502 586.38 587.05 0.67
21503 605.54 605.49 -0.05
21505 612.45 612.64 0.19
21506 624.63 624.59 -0.04
21508 610.31 610.44 0.13
21509 624.46 624.97 0.51
21510 621.46 622.22 0.76
21511 618.84 618.84 0.00
21512 612.08 611.35 -0.73
21514 589.04 588.44 -0.60
21515 593.44 594.31 0.87
21536 600.74 600.57 -0.17
21537 597.06 598.16 1.10
21538 602.00 603.05 1.05
21539 596.55 600.88 4.33
21540 590.05 591.94 1.89
21541 596.43 595.83 -0.60
21542 590.00 585.63 -4.37
21543 589.34 588.81 -0.53
21693 596.08 596.07 -0.01
1. A positive number indicates that the CCR removal grade is higher than the estimated
bottom of CCR grade
Table 1 - CCR Removal Grade Comparison
Point located outside Ash Fill 1 Limits
Point located within Ash Fill 1 Limits
Legend
Notes:
CCR Removal
Dan River Landfill Cell 2
CCR Removal
Dan River Steam Station Landfill Cell 2
Amec Foster Wheeler Project
Sample 
Location Date Performed Visual Classification Color
E4 1/17/2017 red ‐ tan sandy clay red
E5 1/17/2017 red ‐ tan sandy clay red
F3 1/17/2017 red ‐ tan sandy clay red
F4 1/17/2017 yellow ‐ tan sandy clay yellow
F5 1/17/2017 tan ‐ gray sandy clay tan
G3 1/17/2017 tan sandy clay tan
G4 1/17/2017 red ‐ tan sandy clay red
H2 1/17/2017 red ‐ brown sandy clay red
H3 1/17/2017 red ‐ tan sandy clay red
I2 1/17/2017 ABC stone ‐ tan ‐ red sandy clay tan
I3 1/17/2017 organics ‐ gray ‐ tan sandy clay gray
J0 1/17/2017 organics ‐ red ‐ tan sandy clay red
J1 1/17/2017 ABC stone ‐ organics ‐ red ‐ tan sandy clay red
J2 1/17/2017 red ‐ tan sandy clay ‐ with organics red
J3 1/17/2017 red ‐ tan sandy clay red
K2 1/17/2017 red ‐ tan sandy clay red
K3 1/17/2017 red ‐ tan sandy clay red
Table 2 ‐ Field Documention Summary
CC
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FIGURES

1. Site Location Map
2. CCR Removal Verification – 100 foot x 100 foot Grid (Visual)
3. CCR Removal Verification – One Acre Grid (Sampling)

)*
1PROJECT NO:FIGURE NO:7810-16-0623
0 2,0001,000 Feet
NOTE: THIS FIGURE IS FOR REFERENCE ONLY.
DAN RIVER STEAM STATIONROCKINGHAM COUNTY, NORTH CAROLINA
SITE LOCATION MAPDAN RIVER LANDFILL CONSTRUCTION
F:\AMEC_Projects\2016\7810-16-0623 Dan River\GIS\MXDs\Figure1_SiteLocationMap.mxd, User: maddison.sutton; Checked by: CR; Date: 1/23/2017
)*
¯
Service Layer Credits: Sources: Esri, HERE, DeLorme, USGS, Intermap, increment P Corp., NRCAN, Esri Japan, METI, Esri China (HongKong), Esri (Thailand), MapmyIndia, © OpenStreetMap contributors, and the GIS User CommunityCopyright:© 2013 National Geographic Society, i-cubed
ASH FILL 1
ASH FILL 2
PRIMARY ASH BASIN
SECONDARYASH BASIN
CELL 1
LEGEND
)*DAN RIVER STEAM STATION
APPROXIMATE CCR BOUNDARY
APPROXIMATE DUKE ENERGY PROPERTY BOUNDARY
APPROXIMATE CELL 1 BOUNDARY
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3

ATTACHMENT 1

Excavation Soil Sampling Plan for Area 1 Dry Stack

EXCAVATION SOIL SAMPLING PLAN
FOR AREA 1 DRY STACK
DUKE ENERGY DAN RIVER STEAM STATION

DUKE ENERGY CAROLINAS, LLC.
526 SOUTH CHURCH STREET/EC13K
CHARLOTTE, NORTH CAROLINA 28202

Waste & Groundwater Programs
Revision 0
October 2016

Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page i
TABLE OF CONTENTS
SECTION PAGE
1.0 PURPOSE ................................................................................................................................1
2.0 SOIL SAMPLING METHODOLOGY .............................................................................................1
2.1 Method Summary 1
2.1.1 Equipment 1
2.1.2 Sample Locations 2
2.1.3 Collection of Representative Samples 2
2.1.4 Sample Preservation, Containers, Handling and Storage 3
2.1.5 Decontamination 4
3.0 VISUAL CONFIRMATION OF ASH REMOVAL ..............................................................................4
3.1 Pre-Excavation Documentation 4
3.2 Ash Removal Verification Protocol 4
3.2.1 Field Documentation 5
3.2.2 Fill Evaluation Criteria 5
3.3 Visual Removal Not Applicable 6
4.0 SOIL SAMPLING AND ANALYSIS ...............................................................................................6
4.1 Soil Sampling 6
4.1.1 Scenario 1 6
4.1.2 Scenario 2 7
4.2 Fate and Transport Modeling 7

LIST OF TABLES
Table 1 - Soil Parameters and Analytical Methods

Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 1
1.0 PURPOSE
The purpose of this Excavation Soil Sampling Plan is to provide a standardized method for collecting soil
samples at Duke Energy Dan River Steam Station Area 1 Dry Stack. Soil samples are being collected to
verify removal of CCR material per the NCDEQ Guidance (DIN 26815) provided on October 11, 2016.
This Excavation Soil Sampling Plan is applicable to the collection of representative soil samples. Analysis
of soil samples may be chemical or physical in nature and may be used to determine the following:
• Extent and magnitude of constituent occurrence
• Input concentrations for groundwater fate and transport model
The methodologies discussed in this Excavation Soil Sampling Plan are applicable to the sampling of soil
in the Area 1 Dry Stack at Dan River Steam Station. For the purposes of this plan, soils are those mineral
and organic materials remaining (above bedrock and above the groundwater surface) after all visible ash
has been excavated.
2.0 SOIL SAMPLING METHODOLOGY
2.1 Method Summary
This Excavation Soil Sampling Plan has been adapted from Environmental Protection Agency (EPA)
Standard Operating Procedures (SOPs) #2012 and #2006; and North Carolina Department of
Environmental Quality (DEQ) Attachment 1 Coal Combustion Residuals Surface Impoundment Closure
Guidelines for Protection of Groundwater, September 2016.

Soil samples are collected directly using stainless steel or plastic trowel, spade, shovel, or scoops.
Following collection, soil is transferred from the sampling device to a stainless steel or plastic bowl to be
homogenized. Once homogenized, the soil is transferred into Duke Energy Laboratory supplied sample
bottles.
Soil samples will be submitted for total metals analysis. Analytical methods for total metals are
described in Table 1. CCR material presence is quantitatively determined by polarized light microscopy
(PLM) by RJ Lee Laboratory (or other approved vendor). PLM analysis passes visible light through a pair
of polarizing filters to create optical effects used in identifying unknown materials. This method is
commonly used in asbestos and coal ash identification.
2.1.1 Equipment
• Stainless steel or plastic trowel, scoop, spade or shovel – used for collecting soil samples
from surface locations.
• Sample containers – To be supplied by Duke Energy Laboratory with appropriate
cooler(s). Estimated that 5-8 ounce samples bottles with Teflon-lined lids will be
required for each sample location and sample depth. For return of cooler to the lab, ice
will be required.
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 2
• Gloves – used for personal protection and to prevent cross-contamination of samples –
nitrile, disposable, powderless.
• Field clothing and Personal Protective Equipment – used as specified in the site Health
and Safety Plan.
• Sampling flags – used for identifying soil sampling locations.
• Field notebook – a bound book used to record progress of sampling effort and record
any problems and field observations during sampling.
• Three-ring binder book – used to store necessary forms and record and track samples
collected at the site.
• Permanent marking pen – used to label sample containers, document field logbooks and
data sheets.
• Stainless steel or plastic spoon – used for homogenizing soil samples within a stainless
steel or plastic bowl.
• Stainless steel or plastic bowl – used for homogenizing soil samples, when applicable.
• Camera – used for photo-documentation of sample locations and samples.
• GPS – device used to obtain elevation, latitude and longitude of sample location.
• Trash bag – used to dispose of gloves and any other non-hazardous waste generated
during sampling.
• Decontamination supplies and equipment.
2.1.2 Sample Locations
General locations for soil sampling are determined by the soil scientist in the field at a rate of
one soil sample for every 1 acre of area excavated. Actual sampling locations on-site may vary
to account for site conditions and to allow collection of representative samples. Collection of
Representative Samples
For the purpose of this plan, surface soil is considered to range from 0 to 6 inches in depth while
deeper samples are considered to two feet below ground surface (unless bedrock, refusal, or
the water table are encountered). A surface soil sample and deeper samples will be collected at
each location for every 1 acre of area excavated. A new pair of nitrile gloves is worn at each
sampling location and each depth. Each sampling location is recorded on the site map prior to
collecting the sample if location is not already noted on the map. The GPS location of each
sampling location (i.e. elevation, latitude and longitude), sample descriptions, and area
photographs are also recorded. All sampling and homogenizing equipment is decontaminated
prior to use irrespective of depth. The following procedure will be used to collect representative
soil samples with a scoop, shovel, or trowel:
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 3
• Locate general sampling locations.
• Determine suitability of sampling location for a representative sample.
• If sampling location appears to reflect conditions that are representative of the
subject grid cell, proceed with sampling procedure. If location is not
representative of the grid cell, notify the project manager so an alternate
location can be identified.
• Using a decontaminated sampling instrument, remove the desired thickness and
volume of soil from the sampling area. Will require enough soil to fill five 8-
ounce sample bottles.
• Transfer the sample into an appropriate sample or homogenization bowl. Non-
dedicated containers should be adequately decontaminated. Stir for
approximately one minute until there appears to be a uniform color and
consistency.
• Transfer homogenized sample to a labeled container(s) of appropriate size and
construction for the analyses requested.
• Secure sample container tightly.
2.1.3 Sample Preservation, Containers, Handling and Storage
Chemical preservation of soils is generally not recommended. Cooling to 4oC on wet ice is
usually the best approach, supplemented by the appropriate holding time for the analyses
requested.
The Duke Energy Laboratory will supply the appropriate sample bottles for the collected soil
samples. The sample volume is a function of the analytical requirements and the Duke Energy
Laboratory will ensure the appropriate number of bottles is supplied.
Table 1 contains a list of parameters to be analyzed with corresponding reporting units and
analytical methods. If a parameter or group of parameters is not included in Table 1, the
laboratory performing the analysis should be contacted to determine the appropriate sample
bottles, volumes, and preservatives.
All non-dedicated sampling/homogenizing devices should be decontaminated and wrapped in
plastic. The sampling device should remain in this wrapping until it is needed. Each
sampling/homogenizing device should be used for only one sample and then decontaminated or
disposed of. Non dedicated sampling/homogenizing devices should be cleaned in the field using
the decontamination procedure described below.
2.1.4 Decontamination
Decontamination procedures can be time consuming; having a sufficient quantity of sampling
tools available is recommended. All non-dedicated sampling/homogenizing equipment must be
decontaminated prior to reuse. Equipment decontamination consists of:
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 4
1. Detergent wash and brush cleaning
2. Tap water rinse
3. Deionized water rinse
4. Air dry
5. Wrap sampling tools with plastic
3.0 VISUAL CONFIRMATION OF ASH REMOVAL
3.1 Pre-Excavation Documentation
Closure by removal is defined herein as removing the primary source (primary source of potential
constituents of interest) to the point that CCR material is not visible to the unaided eye at the ground
surface. This method is intended solely to verify and document CCR material removal and is not
intended to validate environmental quality standards of the subsurface (considered the secondary
source of potential constituents of interest). Pre-excavation documentation would consist of:

• Review topographic mapping, aerial photography, construction drawings, and boring logs to
estimate the pre-CCR placement topography and/or CCR/soil interface

• Preparation of a figure illustrating a grid spacing of 100 feet. Each grid point (node) will be
assigned a unique identifier. Each node of the grid spacing (grid point) will represent a visual
verification location.

3.2 CCR Material Removal Verification Protocol
CCR material excavation will be considered complete based on visual confirmation that all CCR material
has been removed. CCR material removal will be based on sampling of the CCR/soil interface and
analysis by PLM. Soil samples will be examined utilizing methods outlined in American Society for
Testing and Materials (ASTM) D2488, Standard Practice for Description and Identification of Soils (Visual-
Manual Procedure). Vertical and horizontal excavation of CCR material can terminate when the
remaining material can be documented using PLM to contain less than 50% CCR.

Project will excavate CCR material until a visible change in color or texture confirms removal. This
location shall be referred to as the CCR/soil interface. If visual evaluation is inconclusive, then request
additional evaluation to confirm CCR removal.
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 5
3.2.1 Field Documentation
Evaluate the excavated surface elevation relative to the pre-CCR placement topography.
Periodically check bottom elevation to evaluate if fill is present above historic bottom elevation.
Visual confirmation will be performed on a 100 foot grid system. Soil sampling will be
performed on an acre grid system and will be analyzed using PLM.

• Personnel will locate each node by GPS or survey control, determine elevation and
evaluate whether that point is above or below the historic bottom elevation.

• Personnel will then observe the surface area represented by the node to note if visible
CCR is present at the surface. If present, the location should be documented and
excavation will need to continue. If the evaluation indicates the surface soils are
residuum or bedrock, then hand auger to two feet below surface (or refusal) and
perform visual-manual classification of the soils at the surface and depth according to
ASTM method D2488. Submit sample from depth (or shallower if refusal) for PLM
analysis. The conditions shall be documented by taking photographs.

• If the node point elevation is near the historic bottom elevation, soil is confirmed by
visual manual classification (ASTM D2488), and PLM analysis is less than 50% CCR, then
personnel can conclude the CCR material is removed.

3.3 Visual Removal Not Applicable
If possible, excavation of ash should continue even if groundwater is encountered. If Duke Energy
cannot complete visual removal because of site conditions or other restricting factors, documentation
shall be presented to DEQ.

4.0 SOIL SAMPLING AND ANALYSIS
4.1 Soil Sampling
Soil sampling of the remaining soils (less than 50% CCR per PLM analysis) will be necessary to evaluate
the extent any potential for the soil to act as a secondary source of contamination. Soil samples for
laboratory analysis must be collected in a manner that will ensure a relatively uniform distribution of
particles throughout the six inch sample.

The systematic approach and design for soil sampling and analysis is based upon NCDEQ Guidance (DIN
26815) provided on October 11, 2016:

Confirmation sampling will include discrete surface samples collected from the first six inches of
the soil. Sampling will be performed on an acre grid system. This sample collection
methodology shall be sufficient to characterize the horizontal extent of any remaining potential
secondary source impacts for comparison with the DEQ Preliminary Soil Remediation Goals
(PSRG). The samples shall be analyzed by a North Carolina certified laboratory for total
concentrations for the following parameters: antimony, aluminum, arsenic, barium, beryllium,
boron, cadmium, calcium, chloride, chromium (total and hexavalent), cobalt, copper, iron, lead,
magnesium, manganese, mercury, molybdenum, nickel, nitrate as nitrogen, pH, potassium,
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 6
selenium, silver, sodium, strontium, sulfate, thallium, vanadium and zinc. No SPLP testing is
required.

4.2 Fate and Transport Modeling
Site specific fate and transport modeling may be used to evaluate the impact of any contamination
found in excess of the applicable soil screening values.
Excavation Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC. & Duke Energy Progress, LLC. Revision 0

Table
Excavation Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC. Revision 0

TABLE 1
SOIL PARAMETERS AND ANALYTICAL METHODS
TOTALS AND SPLP ANALYSIS
AREA 1 DRY STACK DUKE ENERGY DAN RIVER STEAM STATION

INORGANIC COMPOUNDS UNITS METHOD1
Aluminum mg/kg or µg/l EPA 6010D
Antimony mg/kg or µg/l EPA 6020B
Arsenic mg/kg or µg/l EPA 6020B
Barium mg/kg or µg/l EPA 6010D
Beryllium mg/kg or µg/l EPA 6020B
Boron mg/kg or µg/l EPA 6010D
Cadmium mg/kg or µg/l EPA 6020B
Calcium mg/kg or µg/l EPA 6010D
Chloride mg/kg or µg/l EPA 9056A
Chromium mg/kg or µg/l EPA 6010D
Cobalt mg/kg or µg/l EPA 6020B
Copper mg/kg or µg/l EPA 6010D
Hexavalent Chromium mg/kg or µg/l EPA Method
7199/218.7
Iron mg/kg or µg/l EPA 6010D
Lead mg/kg or µg/l EPA 6020B
Magnesium mg/kg or µg/l EPA 6010D
Manganese mg/kg or µg/l EPA 6010D
Mercury mg/kg or µg/l EPA Method
7470A/7471B
Molybdenum mg/kg or µg/l EPA 6010D
Nickel mg/kg or µg/l EPA 6010D
Nitrate as Nitrogen mg/kg or µg/l EPA 9056A
pH SU EPA 9045D
Potassium mg/kg or µg/l EPA 6010D
Selenium mg/kg or µg/l EPA 6020B
Silver mg/kg or µg/l EPA 6020B
Sodium mg/kg or µg/l EPA 6010D
Strontium mg/kg or µg/l EPA 6010D
Sulfate mg/kg or µg/l EPA 9056A
Thallium (low level) (SPLP Extract only) mg/kg or µg/l EPA 6020B
Vanadium mg/kg or µg/l EPA 6020B
Zinc mg/kg or µg/l EPA 6010D
Notes: 1. Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH
using USEPA Method 9045, as noted above (or similar approved methods). Soil samples will
also be analyzed for leaching potential using SPLP Extraction Method 1312 in conjunction with
USEPA Methods 6010/6020 (or similar approved methods).

ATTACHMENT 2

Photograph Log

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
1
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (3)

Date 01-17-2017
Ash Removal Visual Sample E4

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (4)
Date 01-17-2017
Observations Ash Removal Visual Sample E5

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
2
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (5)
Date 01-17-2017
Observations Ash Removal Visual Sample F3

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (6)
Date 01-17-2017
Observations Ash Removal Visual Sample F4

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
3
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (7)
Date 01-17-2017
Observations Ash Removal Visual Sample F5

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (8)
Date 01-17-2017
Observations Ash Removal Visual Sample G3

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
4
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (9)
Date 01-17-2017
Observations Ash Removal Visual Sample G4

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (10)
Date 01-17-2017
Observations Ash Removal Visual Sample H2

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
5
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (11)
Date 01-17-2017
Observations Ash Removal Visual Sample H3

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (12)
Date 01-17-2017
Observations Ash Removal Visual Sample I2

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
6
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (13)
Date 01-17-2017
Observations Ash Removal Visual Sample I3

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (14)
Date 01-17-2017
Observations Ash Removal Visual Sample J0

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
7
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (15)
Date 01-17-2017
Observations Ash Removal Visual Sample J1

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (16)
Date 01-17-2017
Observations Ash Removal Visual Sample J2

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
8
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170118
Mohon (9)
Date 01-17-2017
Observations Ash Removal Visual Sample J3

Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (18)
Date 01-17-2017
Observations Ash Removal Visual Sample K2

Cell 2 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
April 21, 2017 Amec Foster Wheeler Project No.: 7810-17-0870
9
Point ID
Cell 2 Ash
Removal
Verification
Photo ID
20170117
Mohon (19)
Date 01-17-2017
Observations Ash Removal Visual Sample K3

ATTACHMENT 3

Laboratory Test Results – RJ Lee Group

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ATTACHMENT 4

Analytical Laboratory Test Results

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16120243
Project Name:DANRIVER -
Lab Contact: Peggy Kendall
Date:1/11/2017
Customer Address:900 S. Edgewood Rd
Customer Name(s):Jason Jomp; Melonie Martin; Chad Groover
Mail Code: Dan River Steam Station
Eden, NC 27288
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Peggy Kendall
Page 1 of 115
ggy
P KKKKK dll
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016039216 DANRIVER 07-Dec-16 9:43 AM Jason Jamp DRSC Cell # 2 - B2-A
2016039217 DANRIVER 07-Dec-16 10:17 AM Jason Jamp DRSC Cell # 2 - B2-B
2016039218 DANRIVER 07-Dec-16 10:29 AM Jason Jamp DRSC Cell # 2 - B2-C
2016039219 DANRIVER 07-Dec-16 12:38 PM Jason Jamp DRSC Cell # 2 - C2-A
2016039220 DANRIVER 07-Dec-16 12:56 PM Jason Jamp DRSC Cell # 2 - C2-B
2016039221 DANRIVER 07-Dec-16 1:11 PM Jason Jamp DRSC Cell # 2 - C2-C
2016039222 DANRIVER 07-Dec-16 2:59 PM Jason Jamp DRSC Cell # 2 - D2-A
2016039223 DANRIVER 07-Dec-16 3:15 PM Jason Jamp DRSC Cell # 2 - D2-B
2016039224 DANRIVER 07-Dec-16 3:22 PM Jason Jamp DRSC Cell # 2 - D2-C
2016039225 DANRIVER 08-Dec-16 8:30 AM Jason Jamp DRSC Cell # 2 - C3-A
2016039226 DANRIVER 08-Dec-16 8:51 AM Jason Jamp DRSC Cell # 2 - C3-B
2016039227 DANRIVER 08-Dec-16 9:02 AM Jason Jamp DRSC Cell # 2 - C3-C
2016039228 DANRIVER 08-Dec-16 10:20 AM Jason Jamp DRSC Cell # 2 - C1-A
2016039229 DANRIVER 08-Dec-16 10:31 AM Jason Jamp DRSC Cell # 2 - C1-B
2016039230 DANRIVER 08-Dec-16 10:49 AM Jason Jamp DRSC Cell # 2 - C1-C
2016039231 DANRIVER 08-Dec-16 11:38 AM Jason Jamp DRSC Cell # 2 - D1-A
2016039232 DANRIVER 08-Dec-16 11:48 AM Jason Jamp DRSC Cell # 2 - D1-B
2016039233 DANRIVER 08-Dec-16 1:08 PM Jason Jamp DRSC Cell # 2 - E1-A
2016039234 DANRIVER 08-Dec-16 1:36 PM Jason Jamp DRSC Cell # 2 - E1-B
2016039235 DANRIVER 08-Dec-16 1:51 PM Jason Jamp DRSC Cell # 2 - E1-C
2016039236 DANRIVER 08-Dec-16 2:47 PM Jason Jamp DRSC Cell # 2 - E2-A
2016039237 DANRIVER 08-Dec-16 3:03 PM Jason Jamp DRSC Cell # 2 - E2-B
2016039238 DANRIVER 08-Dec-16 3:25 PM Jason Jamp DRSC Cell # 2 - E2-C
23 Total Samples
Page 2 of 115
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Peggy Kendall Date:1/11/2017
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039216
Collection Date:07-Dec-16 9:43 AM
Site:DRSC Cell # 2 - B2-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 4 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039217
Collection Date:07-Dec-16 10:17 AM
Site:DRSC Cell # 2 - B2-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 5 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039218
Collection Date:07-Dec-16 10:29 AM
Site:DRSC Cell # 2 - B2-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 6 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039219
Collection Date:07-Dec-16 12:38 PM
Site:DRSC Cell # 2 - C2-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 7 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039220
Collection Date:07-Dec-16 12:56 PM
Site:DRSC Cell # 2 - C2-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 8 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039221
Collection Date:07-Dec-16 1:11 PM
Site:DRSC Cell # 2 - C2-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 9 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039222
Collection Date:07-Dec-16 2:59 PM
Site:DRSC Cell # 2 - D2-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 10 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039223
Collection Date:07-Dec-16 3:15 PM
Site:DRSC Cell # 2 - D2-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 11 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039224
Collection Date:07-Dec-16 3:22 PM
Site:DRSC Cell # 2 - D2-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 12 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039225
Collection Date:08-Dec-16 8:30 AM
Site:DRSC Cell # 2 - C3-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 13 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039226
Collection Date:08-Dec-16 8:51 AM
Site:DRSC Cell # 2 - C3-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 14 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039227
Collection Date:08-Dec-16 9:02 AM
Site:DRSC Cell # 2 - C3-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 15 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039228
Collection Date:08-Dec-16 10:20 AM
Site:DRSC Cell # 2 - C1-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 16 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039229
Collection Date:08-Dec-16 10:31 AM
Site:DRSC Cell # 2 - C1-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 17 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039230
Collection Date:08-Dec-16 10:49 AM
Site:DRSC Cell # 2 - C1-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 18 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039231
Collection Date:08-Dec-16 11:38 AM
Site:DRSC Cell # 2 - D1-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 19 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039232
Collection Date:08-Dec-16 11:48 AM
Site:DRSC Cell # 2 - D1-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 20 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039233
Collection Date:08-Dec-16 1:08 PM
Site:DRSC Cell # 2 - E1-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 21 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039234
Collection Date:08-Dec-16 1:36 PM
Site:DRSC Cell # 2 - E1-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 22 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039235
Collection Date:08-Dec-16 1:51 PM
Site:DRSC Cell # 2 - E1-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 23 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039236
Collection Date:08-Dec-16 2:47 PM
Site:DRSC Cell # 2 - E2-A
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 24 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039237
Collection Date:08-Dec-16 3:03 PM
Site:DRSC Cell # 2 - E2-B
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
Page 25 of 115
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120243
2016039238
Collection Date:08-Dec-16 3:25 PM
Site:DRSC Cell # 2 - E2-C
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 26 of 115
#=CL#
January 10, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92322972
92322972
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16120243
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 12, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 77
Page 27 of 115
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92322972
J16120243
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 77
Page 28 of 115
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID Matrix Date Collected Date Received
92322972001 2016039216 Solid 12/07/16 09:43 12/12/16 13:50
92322972002 2016039218 Solid 12/07/16 10:29 12/12/16 13:50
92322972003 2016039219 Solid 12/07/16 12:38 12/12/16 13:50
92322972004 2016039221 Solid 12/07/16 13:11 12/12/16 13:50
92322972005 2016039222 Solid 12/07/16 14:59 12/12/16 13:50
92322972006 2016039224 Solid 12/07/16 15:22 12/12/16 13:50
92322972007 2016039225 Solid 12/08/16 08:30 12/12/16 13:50
92322972008 2016039227 Solid 12/08/16 09:02 12/12/16 13:50
92322972009 2016039228 Solid 12/08/16 10:20 12/12/16 13:50
92322972010 2016039230 Solid 12/08/16 10:49 12/12/16 13:50
92322972011 2016039231 Solid 12/08/16 11:38 12/12/16 13:50
92322972012 2016039232 Solid 12/08/16 11:48 12/12/16 13:50
92322972013 2016039233 Solid 12/08/16 13:08 12/12/16 13:50
92322972014 2016039235 Solid 12/08/16 13:51 12/12/16 13:50
92322972015 2016039236 Solid 12/08/16 14:47 12/12/16 13:50
92322972016 2016039238 Solid 12/08/16 15:25 12/12/16 13:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 77
Page 29 of 115
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92322972001 2016039216 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972002 2016039218 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972003 2016039219 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972004 2016039221 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972005 2016039222 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 77
Page 30 of 115
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972006 2016039224 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972007 2016039225 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972008 2016039227 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972009 2016039228 EPA 6010 17 PASI-OBDS
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972010 2016039230 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 77
Page 31 of 115
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972011 2016039231 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972012 2016039232 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972013 2016039233 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972014 2016039235 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 77
Page 32 of 115
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 9056 1 PASI-OCMB
92322972015 2016039236 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92322972016 2016039238 EPA 6010 17 PASI-OBDS, JTJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-OMLO
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 77
Page 33 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972001 2016039216
Aluminum 14700 mg/kg 12/29/16 18:23 M1,R16.6EPA 6010
Barium 103 mg/kg 12/29/16 18:23 M10.66EPA 6010
Beryllium 0.64 mg/kg 12/29/16 18:23 R10.066EPA 6010
Boron 12.4 mg/kg 12/29/16 18:23 M13.3EPA 6010
Calcium 1410 mg/kg 12/29/16 18:23 M1,R132.9EPA 6010
Chromium 13.8 mg/kg 12/29/16 18:230.33EPA 6010
Copper 17.1 mg/kg 12/29/16 18:23 M10.33EPA 6010
Iron 19600 mg/kg 12/30/16 21:27 M626.3EPA 6010
Magnesium 2530 mg/kg 12/29/16 18:23 M1,R132.9EPA 6010
Manganese 582 mg/kg 12/29/16 18:23 M10.33EPA 6010
Nickel 12.0 mg/kg 12/29/16 18:23 M10.33EPA 6010
Potassium 1190 mg/kg 12/29/16 18:23 M165.8EPA 6010
Strontium 21.0 mg/kg 12/29/16 18:23 M1,R10.66EPA 6010
Zinc 36.6 mg/kg 12/29/16 18:231.3EPA 6010
Arsenic 1.4 mg/kg 12/19/16 17:291.1EPA 6020
Cobalt 8.6 mg/kg 12/19/16 17:291.1EPA 6020
Lead 12.7 mg/kg 12/19/16 17:291.1EPA 6020
Selenium 1.5 mg/kg 12/19/16 17:291.1EPA 6020
Vanadium 24.4 mg/kg 12/19/16 17:291.1EPA 6020
Mercury 0.021 mg/kg 01/09/17 18:06 H1,H20.0092EPA 7471
Percent Moisture 15.0 %01/05/17 12:000.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972002 2016039218
Aluminum 21300 mg/kg 12/29/16 18:3131.4EPA 6010
Barium 83.5 mg/kg 12/29/16 05:400.63EPA 6010
Beryllium 0.47 mg/kg 12/29/16 05:400.063EPA 6010
Calcium 300 mg/kg 12/29/16 05:4031.4EPA 6010
Chromium 12.5 mg/kg 12/29/16 05:400.31EPA 6010
Copper 20.6 mg/kg 12/29/16 05:400.31EPA 6010
Iron 25800 mg/kg 12/30/16 21:3125.1EPA 6010
Magnesium 1870 mg/kg 12/29/16 05:4031.4EPA 6010
Manganese 801 mg/kg 12/29/16 18:311.6EPA 6010
Nickel 9.8 mg/kg 12/29/16 05:400.31EPA 6010
Potassium 1620 mg/kg 12/29/16 18:31314EPA 6010
Strontium 7.8 mg/kg 12/29/16 05:400.63EPA 6010
Zinc 38.8 mg/kg 12/29/16 18:316.3EPA 6010
Cobalt 12.7 mg/kg 12/19/16 17:471.2EPA 6020
Lead 22.6 mg/kg 12/19/16 17:471.2EPA 6020
Vanadium 23.4 mg/kg 12/19/16 17:471.2EPA 6020
Mercury 0.014 mg/kg 01/09/17 18:09 H1,H20.0076EPA 7471
Percent Moisture 10.6 %01/05/17 12:000.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972003 2016039219
Aluminum 17900 mg/kg 12/29/16 18:3534.7EPA 6010
Barium 110 mg/kg 12/29/16 18:353.5EPA 6010
Beryllium 0.92 mg/kg 12/29/16 18:350.35EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 77
Page 34 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972003 2016039219
Boron 20.2 mg/kg 12/29/16 18:3517.3EPA 6010
Calcium 823 mg/kg 12/29/16 18:35173EPA 6010
Chromium 18.9 mg/kg 12/29/16 18:351.7EPA 6010
Copper 21.4 mg/kg 12/29/16 18:351.7EPA 6010
Iron 24400 mg/kg 12/30/16 21:3527.7EPA 6010
Magnesium 2100 mg/kg 12/29/16 18:35173EPA 6010
Manganese 439 mg/kg 12/29/16 18:351.7EPA 6010
Nickel 12.6 mg/kg 12/29/16 18:351.7EPA 6010
Potassium 1500 mg/kg 12/29/16 18:35347EPA 6010
Strontium 22.8 mg/kg 12/29/16 18:353.5EPA 6010
Zinc 44.7 mg/kg 12/29/16 18:356.9EPA 6010
Arsenic 1.7 mg/kg 12/19/16 17:511.3EPA 6020
Cobalt 12.6 mg/kg 12/19/16 17:511.3EPA 6020
Lead 15.0 mg/kg 12/19/16 17:511.3EPA 6020
Vanadium 26.1 mg/kg 12/19/16 17:511.3EPA 6020
Mercury 0.018 mg/kg 01/09/17 18:11 H1,H20.010EPA 7471
Percent Moisture 10.3 %01/05/17 12:000.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972004 2016039221
Aluminum 31200 mg/kg 12/29/16 18:3936.5EPA 6010
Barium 70.6 mg/kg 12/29/16 18:393.6EPA 6010
Beryllium 0.74 mg/kg 12/29/16 18:390.36EPA 6010
Boron 45.4 mg/kg 12/29/16 18:3918.2EPA 6010
Chromium 40.0 mg/kg 12/29/16 18:391.8EPA 6010
Copper 51.1 mg/kg 12/29/16 18:391.8EPA 6010
Iron 61900 mg/kg 12/30/16 21:3929.2EPA 6010
Magnesium 652 mg/kg 12/29/16 18:39182EPA 6010
Manganese 65.5 mg/kg 12/29/16 18:391.8EPA 6010
Nickel 9.2 mg/kg 12/29/16 18:391.8EPA 6010
Potassium 1020 mg/kg 12/29/16 18:39365EPA 6010
Strontium 16.3 mg/kg 12/29/16 18:393.6EPA 6010
Zinc 40.1 mg/kg 12/29/16 18:397.3EPA 6010
Arsenic 33.2 mg/kg 12/19/16 17:541.4EPA 6020
Cobalt 2.3 mg/kg 12/19/16 17:541.4EPA 6020
Lead 36.3 mg/kg 12/19/16 17:541.4EPA 6020
Selenium 2.5 mg/kg 12/19/16 17:541.4EPA 6020
Vanadium 50.1 mg/kg 12/19/16 17:541.4EPA 6020
Mercury 0.027 mg/kg 01/09/17 18:13 H1,H20.0084EPA 7471
Percent Moisture 19.7 %01/05/17 12:000.10ASTM D2974-87
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10EPA 9045
Chromium, Hexavalent 1.1 mg/kg 01/06/17 19:020.77EPA 7199
92322972005 2016039222
Aluminum 26000 mg/kg 12/29/16 19:5236.0EPA 6010
Barium 81.2 mg/kg 12/29/16 19:523.6EPA 6010
Beryllium 1.1 mg/kg 12/29/16 19:520.36EPA 6010
Boron 35.9 mg/kg 12/29/16 19:5218.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 77
Page 35 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972005 2016039222
Chromium 21.6 mg/kg 12/29/16 19:521.8EPA 6010
Copper 34.8 mg/kg 12/29/16 19:521.8EPA 6010
Iron 40600 mg/kg 12/29/16 19:5214.4EPA 6010
Magnesium 1370 mg/kg 12/29/16 19:52180EPA 6010
Manganese 177 mg/kg 12/29/16 19:521.8EPA 6010
Nickel 10.5 mg/kg 12/29/16 19:521.8EPA 6010
Potassium 1800 mg/kg 12/29/16 19:52360EPA 6010
Zinc 50.2 mg/kg 12/29/16 19:527.2EPA 6010
Arsenic 4.3 mg/kg 12/19/16 17:581.3EPA 6020
Cobalt 9.4 mg/kg 12/19/16 17:581.3EPA 6020
Lead 17.5 mg/kg 12/19/16 17:581.3EPA 6020
Vanadium 40.4 mg/kg 12/19/16 17:581.3EPA 6020
Mercury 0.013 mg/kg 01/05/17 13:29 H10.011EPA 7471
Percent Moisture 20.0 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.1 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972006 2016039224
Aluminum 31000 mg/kg 12/30/16 21:4662.3EPA 6010
Barium 246 mg/kg 12/30/16 21:466.2EPA 6010
Beryllium 3.4 mg/kg 12/30/16 21:460.62EPA 6010
Boron 36.9 mg/kg 12/30/16 21:4631.2EPA 6010
Chromium 25.7 mg/kg 12/30/16 21:463.1EPA 6010
Copper 27.1 mg/kg 12/30/16 21:463.1EPA 6010
Iron 44200 mg/kg 12/30/16 21:4624.9EPA 6010
Magnesium 4430 mg/kg 12/30/16 21:46312EPA 6010
Manganese 1280 mg/kg 12/30/16 21:463.1EPA 6010
Nickel 37.1 mg/kg 12/30/16 21:463.1EPA 6010
Potassium 2640 mg/kg 01/03/17 11:361250EPA 6010
Zinc 145 mg/kg 12/30/16 21:4612.5EPA 6010
Arsenic 3.7 mg/kg 12/19/16 18:011.2EPA 6020
Cobalt 43.5 mg/kg 12/19/16 18:011.2EPA 6020
Lead 11.7 mg/kg 12/19/16 18:011.2EPA 6020
Selenium 8.7 mg/kg 12/28/16 11:552.9EPA 6020
Vanadium 36.7 mg/kg 12/19/16 18:011.2EPA 6020
Percent Moisture 14.8 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.7 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972007 2016039225
Aluminum 42600 mg/kg 12/30/16 21:5073.9EPA 6010
Barium 251 mg/kg 12/30/16 21:507.4EPA 6010
Beryllium 4.5 mg/kg 12/30/16 21:500.74EPA 6010
Boron 37.7 mg/kg 12/30/16 21:5037.0EPA 6010
Chromium 34.6 mg/kg 12/30/16 21:503.7EPA 6010
Copper 60.8 mg/kg 12/30/16 21:503.7EPA 6010
Iron 47100 mg/kg 12/30/16 21:5029.6EPA 6010
Magnesium 8130 mg/kg 12/30/16 21:50370EPA 6010
Manganese 1170 mg/kg 12/30/16 21:503.7EPA 6010
Nickel 27.4 mg/kg 12/29/16 20:070.37EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 77
Page 36 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972007 2016039225
Potassium 2980 mg/kg 01/03/17 11:411480EPA 6010
Strontium 57.3 mg/kg 12/30/16 21:507.4EPA 6010
Zinc 109 mg/kg 12/29/16 20:071.5EPA 6010
Arsenic 5.2 mg/kg 12/19/16 18:051.1EPA 6020
Cobalt 46.2 mg/kg 12/19/16 18:051.1EPA 6020
Lead 30.7 mg/kg 12/19/16 18:051.1EPA 6020
Selenium 6.1 mg/kg 12/28/16 11:592.8EPA 6020
Vanadium 31.9 mg/kg 12/19/16 18:051.1EPA 6020
Mercury 0.0099 mg/kg 01/05/17 13:45 H10.0099EPA 7471
Percent Moisture 21.0 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.4 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972008 2016039227
Aluminum 28900 mg/kg 12/29/16 20:1236.4EPA 6010
Barium 182 mg/kg 12/29/16 20:123.6EPA 6010
Beryllium 1.8 mg/kg 12/29/16 20:120.36EPA 6010
Boron 26.8 mg/kg 12/29/16 20:1218.2EPA 6010
Calcium 645 mg/kg 12/29/16 20:12182EPA 6010
Chromium 23.7 mg/kg 12/29/16 20:121.8EPA 6010
Copper 24.2 mg/kg 12/29/16 20:121.8EPA 6010
Iron 31000 mg/kg 12/29/16 20:1214.6EPA 6010
Magnesium 6890 mg/kg 12/29/16 20:12182EPA 6010
Manganese 403 mg/kg 12/29/16 20:121.8EPA 6010
Nickel 27.7 mg/kg 12/29/16 20:121.8EPA 6010
Potassium 1880 mg/kg 12/29/16 20:12364EPA 6010
Strontium 32.1 mg/kg 12/29/16 20:123.6EPA 6010
Zinc 86.0 mg/kg 12/29/16 20:127.3EPA 6010
Arsenic 3.6 mg/kg 12/19/16 18:091.4EPA 6020
Cobalt 16.5 mg/kg 12/19/16 18:091.4EPA 6020
Lead 12.9 mg/kg 12/19/16 18:091.4EPA 6020
Selenium 4.5 mg/kg 12/28/16 12:023.6EPA 6020
Vanadium 32.5 mg/kg 12/19/16 18:091.4EPA 6020
Percent Moisture 16.1 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.8 Std. Units 12/20/16 09:45 H60.10EPA 9045
Chromium, Hexavalent 2.0 mg/kg 01/06/17 19:540.74EPA 7199
92322972009 2016039228
Aluminum 14400 mg/kg 12/29/16 20:1533.2EPA 6010
Barium 60.5 mg/kg 12/29/16 20:153.3EPA 6010
Beryllium 0.49 mg/kg 12/29/16 20:150.33EPA 6010
Boron 22.7 mg/kg 12/29/16 20:1516.6EPA 6010
Chromium 23.5 mg/kg 12/29/16 20:151.7EPA 6010
Copper 10.7 mg/kg 12/29/16 20:151.7EPA 6010
Iron 26500 mg/kg 12/29/16 20:1513.3EPA 6010
Magnesium 629 mg/kg 12/29/16 20:15166EPA 6010
Manganese 382 mg/kg 12/29/16 20:151.7EPA 6010
Nickel 4.9 mg/kg 12/29/16 20:151.7EPA 6010
Potassium 692 mg/kg 12/29/16 20:15332EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 77
Page 37 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972009 2016039228
Zinc 21.9 mg/kg 12/29/16 20:156.6EPA 6010
Arsenic 2.8 mg/kg 12/19/16 18:121.1EPA 6020
Cobalt 6.2 mg/kg 12/19/16 18:121.1EPA 6020
Lead 14.2 mg/kg 12/19/16 18:121.1EPA 6020
Vanadium 30.9 mg/kg 12/19/16 18:121.1EPA 6020
Mercury 0.026 mg/kg 12/22/16 15:220.0089EPA 7471
Percent Moisture 9.5 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972010 2016039230
Aluminum 29300 mg/kg 12/30/16 05:487.3EPA 6010
Barium 89.2 mg/kg 12/30/16 05:480.73EPA 6010
Beryllium 1.0 mg/kg 12/30/16 05:480.073EPA 6010
Boron 4.3 mg/kg 12/30/16 05:483.6EPA 6010
Chromium 16.4 mg/kg 12/30/16 05:480.36EPA 6010
Copper 29.4 mg/kg 12/30/16 05:480.36EPA 6010
Iron 47000 mg/kg 12/30/16 21:5429.0EPA 6010
Magnesium 1190 mg/kg 12/30/16 05:4836.3EPA 6010
Manganese 171 mg/kg 12/30/16 05:480.36EPA 6010
Nickel 6.8 mg/kg 12/30/16 05:480.36EPA 6010
Potassium 1770 mg/kg 12/30/16 05:4872.6EPA 6010
Sodium 86.3 mg/kg 12/30/16 05:4872.6EPA 6010
Strontium 3.8 mg/kg 12/30/16 05:480.73EPA 6010
Zinc 34.0 mg/kg 12/29/16 20:191.5EPA 6010
Arsenic 1.9 mg/kg 12/19/16 18:161.2EPA 6020
Cobalt 2.2 mg/kg 12/19/16 18:161.2EPA 6020
Lead 32.3 mg/kg 12/19/16 18:161.2EPA 6020
Selenium 1.3 mg/kg 12/19/16 18:161.2EPA 6020
Vanadium 40.8 mg/kg 12/19/16 18:161.2EPA 6020
Mercury 0.050 mg/kg 12/22/16 15:240.010EPA 7471
Percent Moisture 18.6 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972011 2016039231
Aluminum 20700 mg/kg 12/30/16 05:526.8EPA 6010
Barium 83.5 mg/kg 12/30/16 05:520.68EPA 6010
Beryllium 0.85 mg/kg 12/30/16 05:520.068EPA 6010
Boron 3.6 mg/kg 12/30/16 05:523.4EPA 6010
Calcium 213 mg/kg 12/30/16 05:5234.0EPA 6010
Chromium 22.3 mg/kg 12/30/16 05:520.34EPA 6010
Copper 27.1 mg/kg 12/30/16 05:520.34EPA 6010
Iron 36400 mg/kg 12/30/16 22:0627.2EPA 6010
Magnesium 1100 mg/kg 12/30/16 05:5234.0EPA 6010
Manganese 190 mg/kg 12/30/16 05:520.34EPA 6010
Molybdenum 0.79 mg/kg 12/30/16 05:520.68EPA 6010
Nickel 8.1 mg/kg 12/30/16 05:520.34EPA 6010
Potassium 1310 mg/kg 12/30/16 05:5268.0EPA 6010
Strontium 6.0 mg/kg 12/30/16 05:520.68EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 77
Page 38 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972011 2016039231
Zinc 39.4 mg/kg 12/29/16 20:231.4EPA 6010
Arsenic 9.4 mg/kg 12/19/16 18:191.2EPA 6020
Cobalt 9.5 mg/kg 12/19/16 18:191.2EPA 6020
Lead 16.6 mg/kg 12/19/16 18:191.2EPA 6020
Vanadium 41.7 mg/kg 12/19/16 18:191.2EPA 6020
Mercury 0.037 mg/kg 12/22/16 15:260.0079EPA 7471
Percent Moisture 9.5 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972012 2016039232
Aluminum 28200 mg/kg 12/30/16 05:576.6EPA 6010
Barium 82.8 mg/kg 12/30/16 05:570.66EPA 6010
Beryllium 1.7 mg/kg 12/30/16 22:100.66EPA 6010
Boron 46.5 mg/kg 12/30/16 22:1033.2EPA 6010
Calcium 51.6 mg/kg 12/30/16 05:5733.2EPA 6010
Chromium 32.6 mg/kg 12/30/16 22:103.3EPA 6010
Copper 63.0 mg/kg 12/30/16 22:103.3EPA 6010
Iron 53200 mg/kg 12/30/16 22:1026.6EPA 6010
Magnesium 1660 mg/kg 12/30/16 05:5733.2EPA 6010
Manganese 121 mg/kg 12/30/16 22:103.3EPA 6010
Molybdenum 0.71 mg/kg 12/30/16 05:570.66EPA 6010
Nickel 12.6 mg/kg 12/30/16 05:570.33EPA 6010
Potassium 1760 mg/kg 12/30/16 05:5766.4EPA 6010
Sodium 90.5 mg/kg 12/30/16 05:5766.4EPA 6010
Strontium 3.9 mg/kg 12/30/16 05:570.66EPA 6010
Zinc 70.2 mg/kg 12/29/16 20:271.3EPA 6010
Arsenic 4.5 mg/kg 12/19/16 18:371.1EPA 6020
Cobalt 6.6 mg/kg 12/19/16 18:371.1EPA 6020
Lead 17.4 mg/kg 12/19/16 18:371.1EPA 6020
Selenium 2.9 mg/kg 12/28/16 12:062.8EPA 6020
Vanadium 49.1 mg/kg 12/19/16 18:371.1EPA 6020
Mercury 0.040 mg/kg 01/05/17 13:49 H10.0095EPA 7471
Percent Moisture 13.8 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.4 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972013 2016039233
Aluminum 22900 mg/kg 12/30/16 06:015.5EPA 6010
Barium 101 mg/kg 12/30/16 06:010.55EPA 6010
Beryllium 0.54 mg/kg 12/30/16 06:010.055EPA 6010
Boron 3.3 mg/kg 12/30/16 06:012.7EPA 6010
Calcium 324 mg/kg 12/30/16 06:0127.5EPA 6010
Chromium 18.0 mg/kg 12/30/16 06:010.27EPA 6010
Copper 25.4 mg/kg 12/30/16 06:010.27EPA 6010
Iron 34000 mg/kg 12/30/16 22:1422.0EPA 6010
Magnesium 1910 mg/kg 12/30/16 06:0127.5EPA 6010
Manganese 160 mg/kg 12/30/16 06:010.27EPA 6010
Nickel 11.4 mg/kg 12/30/16 06:010.27EPA 6010
Potassium 1980 mg/kg 12/30/16 06:0154.9EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 77
Page 39 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972013 2016039233
Sodium 94.7 mg/kg 12/30/16 06:0154.9EPA 6010
Strontium 8.1 mg/kg 12/30/16 06:010.55EPA 6010
Zinc 43.4 mg/kg 12/29/16 20:311.1EPA 6010
Arsenic 2.6 mg/kg 12/19/16 18:411.5EPA 6020
Cobalt 6.6 mg/kg 12/19/16 18:411.5EPA 6020
Lead 18.7 mg/kg 12/19/16 18:411.5EPA 6020
Vanadium 47.4 mg/kg 12/19/16 18:411.5EPA 6020
Mercury 0.031 mg/kg 01/05/17 13:51 H10.011EPA 7471
Percent Moisture 15.7 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 4.9 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972014 2016039235
Aluminum 24100 mg/kg 12/30/16 06:067.0EPA 6010
Barium 70.6 mg/kg 12/30/16 06:060.70EPA 6010
Beryllium 0.92 mg/kg 12/30/16 06:060.070EPA 6010
Boron 4.5 mg/kg 12/30/16 06:063.5EPA 6010
Chromium 24.7 mg/kg 12/30/16 06:060.35EPA 6010
Copper 22.9 mg/kg 12/30/16 06:060.35EPA 6010
Iron 52800 mg/kg 12/30/16 22:1828.0EPA 6010
Magnesium 1730 mg/kg 12/30/16 06:0634.9EPA 6010
Manganese 51.0 mg/kg 12/30/16 06:060.35EPA 6010
Nickel 10.4 mg/kg 12/30/16 06:060.35EPA 6010
Potassium 1720 mg/kg 12/30/16 06:0669.9EPA 6010
Sodium 118 mg/kg 12/30/16 06:0669.9EPA 6010
Strontium 5.9 mg/kg 12/30/16 06:060.70EPA 6010
Zinc 50.7 mg/kg 12/29/16 20:351.4EPA 6010
Cobalt 3.6 mg/kg 12/19/16 18:441.3EPA 6020
Lead 16.1 mg/kg 12/19/16 18:441.3EPA 6020
Vanadium 41.5 mg/kg 12/19/16 18:441.3EPA 6020
Mercury 0.022 mg/kg 01/09/17 18:19 H1,H20.012EPA 7471
Percent Moisture 15.8 %01/05/17 12:010.10ASTM D2974-87
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972015 2016039236
Aluminum 23500 mg/kg 12/30/16 06:106.3EPA 6010
Barium 99.7 mg/kg 12/30/16 06:100.63EPA 6010
Beryllium 1.5 mg/kg 12/30/16 22:220.63EPA 6010
Calcium 125 mg/kg 12/30/16 06:1031.3EPA 6010
Chromium 23.2 mg/kg 12/30/16 22:223.1EPA 6010
Copper 34.3 mg/kg 12/30/16 22:223.1EPA 6010
Iron 34600 mg/kg 12/30/16 22:2225.0EPA 6010
Magnesium 1770 mg/kg 12/30/16 06:1031.3EPA 6010
Manganese 572 mg/kg 12/30/16 22:223.1EPA 6010
Nickel 14.9 mg/kg 12/30/16 06:100.31EPA 6010
Potassium 1760 mg/kg 12/30/16 06:1062.6EPA 6010
Sodium 101 mg/kg 12/30/16 06:1062.6EPA 6010
Strontium 4.4 mg/kg 12/30/16 06:100.63EPA 6010
Zinc 54.3 mg/kg 12/29/16 20:391.3EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 77
Page 40 of 115
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92322972
J16120243
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92322972015 2016039236
Arsenic 1.9 mg/kg 12/19/16 18:481.3EPA 6020
Cobalt 22.3 mg/kg 12/19/16 18:481.3EPA 6020
Lead 20.3 mg/kg 12/19/16 18:481.3EPA 6020
Selenium 4.1 mg/kg 12/28/16 12:173.2EPA 6020
Vanadium 37.7 mg/kg 12/19/16 18:481.3EPA 6020
Percent Moisture 16.2 %01/05/17 12:020.10ASTM D2974-87
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10EPA 9045
92322972016 2016039238
Aluminum 14500 mg/kg 12/30/16 06:156.2EPA 6010
Barium 87.8 mg/kg 12/30/16 06:150.62EPA 6010
Beryllium 0.76 mg/kg 12/30/16 06:150.062EPA 6010
Boron 3.5 mg/kg 12/30/16 06:153.1EPA 6010
Calcium 422 mg/kg 12/30/16 06:1531.0EPA 6010
Chromium 17.8 mg/kg 12/30/16 06:150.31EPA 6010
Copper 23.6 mg/kg 12/30/16 06:150.31EPA 6010
Iron 29800 mg/kg 12/30/16 22:2624.8EPA 6010
Magnesium 756 mg/kg 12/30/16 06:1531.0EPA 6010
Manganese 184 mg/kg 12/30/16 06:150.31EPA 6010
Molybdenum 0.71 mg/kg 12/30/16 06:150.62EPA 6010
Nickel 7.7 mg/kg 12/30/16 06:150.31EPA 6010
Potassium 932 mg/kg 12/30/16 06:1562.0EPA 6010
Strontium 23.2 mg/kg 12/30/16 06:150.62EPA 6010
Zinc 35.8 mg/kg 12/29/16 20:511.2EPA 6010
Arsenic 5.3 mg/kg 12/19/16 18:510.98EPA 6020
Cobalt 8.3 mg/kg 12/19/16 18:510.98EPA 6020
Lead 13.7 mg/kg 12/19/16 18:510.98EPA 6020
Vanadium 28.4 mg/kg 12/19/16 18:510.98EPA 6020
Mercury 0.028 mg/kg 01/09/17 18:24 H1,H20.011EPA 7471
Percent Moisture 14.4 %01/05/17 12:020.10ASTM D2974-87
pH at 25 Degrees C 4.5 Std. Units 12/20/16 09:45 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 77
Page 41 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 6010
Date:January 10, 2017
Description:6010 MET ICP
General Information:
16 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 340581
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92322972001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1827665)
• Aluminum
• Barium
• Boron
• Calcium
• Copper
• Magnesium
• Manganese
• Molybdenum
• Nickel
• Silver
• Strontium
• MSD (Lab ID: 1827666)
• Aluminum
• Boron
• Copper
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 77
Page 42 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 6010
Date:January 10, 2017
Description:6010 MET ICP
QC Batch: 340581
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92322972001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Magnesium
• Manganese
• Molybdenum
• Potassium
• Silver
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1827665)
• Iron
• MSD (Lab ID: 1827666)
• Iron
R1: RPD value was outside control limits.
• MSD (Lab ID: 1827666)
• Aluminum
• Beryllium
• Calcium
• Magnesium
• Sodium
• Strontium
Additional Comments:
Analyte Comments:
QC Batch: 340581
1g: Analyte was detected in theCCB. All associated samples had concentrations of at least ten times greater than the blank or were
below the reporting limit.
• BLANK (Lab ID: 1827663)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 77
Page 43 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 6020
Date:January 10, 2017
Description:6020 MET ICPMS
General Information:
16 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 338970
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35281740008
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1818048)
• Lead
• MSD (Lab ID: 1818049)
• Arsenic
• Cadmium
• Lead
R1: RPD value was outside control limits.
• MSD (Lab ID: 1818049)
• Antimony
• Arsenic
• Cadmium
• Cobalt
• Lead
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 77
Page 44 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 6020
Date:January 10, 2017
Description:6020 MET ICPMS
QC Batch: 338970
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35281740008
R1: RPD value was outside control limits.
• Selenium
• Thallium
• Vanadium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 77
Page 45 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 7471
Date:January 10, 2017
Description:7471 Mercury
General Information:
16 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H1: Analysis conducted outside the EPA method holding time.
• 2016039216 (Lab ID: 92322972001)
• 2016039218 (Lab ID: 92322972002)
• 2016039219 (Lab ID: 92322972003)
• 2016039221 (Lab ID: 92322972004)
• 2016039222 (Lab ID: 92322972005)
• 2016039224 (Lab ID: 92322972006)
• 2016039225 (Lab ID: 92322972007)
• 2016039227 (Lab ID: 92322972008)
• 2016039232 (Lab ID: 92322972012)
• 2016039233 (Lab ID: 92322972013)
• 2016039235 (Lab ID: 92322972014)
• 2016039236 (Lab ID: 92322972015)
• 2016039238 (Lab ID: 92322972016)
H2: Extraction or preparation conducted outside EPA method holding time.
• 2016039216 (Lab ID: 92322972001)
• 2016039218 (Lab ID: 92322972002)
• 2016039219 (Lab ID: 92322972003)
• 2016039221 (Lab ID: 92322972004)
• 2016039235 (Lab ID: 92322972014)
• 2016039236 (Lab ID: 92322972015)
• 2016039238 (Lab ID: 92322972016)
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 77
Page 46 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 7471
Date:January 10, 2017
Description:7471 Mercury
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 77
Page 47 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 9045
Date:January 10, 2017
Description:9045 pH Soil
General Information:
16 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H6: Analysis initiated outside of the 15 minute EPA required holding time.
• 2016039216 (Lab ID: 92322972001)
• 2016039218 (Lab ID: 92322972002)
• 2016039219 (Lab ID: 92322972003)
• 2016039221 (Lab ID: 92322972004)
• 2016039222 (Lab ID: 92322972005)
• 2016039224 (Lab ID: 92322972006)
• 2016039225 (Lab ID: 92322972007)
• 2016039227 (Lab ID: 92322972008)
• 2016039228 (Lab ID: 92322972009)
• 2016039230 (Lab ID: 92322972010)
• 2016039231 (Lab ID: 92322972011)
• 2016039232 (Lab ID: 92322972012)
• 2016039233 (Lab ID: 92322972013)
• 2016039235 (Lab ID: 92322972014)
• 2016039236 (Lab ID: 92322972015)
• 2016039238 (Lab ID: 92322972016)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 77
Page 48 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 7199
Date:January 10, 2017
Description:7199 Hexavalent Chromium Soil
General Information:
16 samples were analyzed for EPA 7199. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3060 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 342360
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92320478001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1836321)
• Chromium, Hexavalent
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 77
Page 49 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 9056
Date:January 10, 2017
Description:9056 IC Anions
General Information:
16 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 77
Page 50 of 115
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92322972
J16120243
Method:
Client:Duke Energy
EPA 9056
Date:January 10, 2017
Description:9056 IC Anions 48hr
General Information:
16 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• 2016039216 (Lab ID: 92322972001)
• 2016039218 (Lab ID: 92322972002)
• 2016039219 (Lab ID: 92322972003)
• 2016039221 (Lab ID: 92322972004)
• 2016039222 (Lab ID: 92322972005)
• 2016039224 (Lab ID: 92322972006)
• 2016039225 (Lab ID: 92322972007)
• 2016039227 (Lab ID: 92322972008)
• 2016039228 (Lab ID: 92322972009)
• 2016039230 (Lab ID: 92322972010)
• 2016039231 (Lab ID: 92322972011)
• 2016039232 (Lab ID: 92322972012)
• 2016039233 (Lab ID: 92322972013)
• 2016039235 (Lab ID: 92322972014)
• 2016039236 (Lab ID: 92322972015)
• 2016039238 (Lab ID: 92322972016)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 77
Page 51 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039216 Lab ID: 92322972001 Collected: 12/07/16 09:43 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 14700 mg/kg 12/29/16 18:23 7429-90-5 M1,R112/23/16 11:556.6 1
Barium 103 mg/kg 12/29/16 18:23 7440-39-3 M112/23/16 11:550.66 1
Beryllium 0.64 mg/kg 12/29/16 18:23 7440-41-7 R112/23/16 11:550.066 1
Boron 12.4 mg/kg 12/29/16 18:23 7440-42-8 M112/23/16 11:553.3 1
Calcium 1410 mg/kg 12/29/16 18:23 7440-70-2 M1,R112/23/16 11:5532.9 1
Chromium 13.8 mg/kg 12/29/16 18:23 7440-47-312/23/16 11:550.33 1
Copper 17.1 mg/kg 12/29/16 18:23 7440-50-8 M112/23/16 11:550.33 1
Iron 19600 mg/kg 12/30/16 21:27 7439-89-6 M612/23/16 11:5526.3 10
Magnesium 2530 mg/kg 12/29/16 18:23 7439-95-4 M1,R112/23/16 11:5532.9 1
Manganese 582 mg/kg 12/29/16 18:23 7439-96-5 M112/23/16 11:550.33 1
Molybdenum ND mg/kg 12/29/16 18:23 7439-98-7 M112/23/16 11:550.66 1
Nickel 12.0 mg/kg 12/29/16 18:23 7440-02-0 M112/23/16 11:550.33 1
Potassium 1190 mg/kg 12/29/16 18:23 7440-09-7 M112/23/16 11:5565.8 1
Silver ND mg/kg 12/29/16 18:27 7440-22-4 M112/23/16 11:551.6 5
Sodium ND mg/kg 12/30/16 21:27 7440-23-5 R112/23/16 11:55658 10
Strontium 21.0 mg/kg 12/29/16 18:23 7440-24-6 M1,R112/23/16 11:550.66 1
Zinc 36.6 mg/kg 12/29/16 18:23 7440-66-612/23/16 11:551.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 17:29 7440-36-0 N212/16/16 08:122.2 20
Arsenic 1.4 mg/kg 12/19/16 17:29 7440-38-212/16/16 08:121.1 20
Cadmium ND mg/kg 12/19/16 17:29 7440-43-912/16/16 08:120.13 20
Cobalt 8.6 mg/kg 12/19/16 17:29 7440-48-412/16/16 08:121.1 20
Lead 12.7 mg/kg 12/19/16 17:29 7439-92-112/16/16 08:121.1 20
Selenium 1.5 mg/kg 12/19/16 17:29 7782-49-212/16/16 08:121.1 20
Thallium ND mg/kg 12/19/16 17:29 7440-28-012/16/16 08:121.1 20
Vanadium 24.4 mg/kg 12/19/16 17:29 7440-62-212/16/16 08:121.1 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.021 mg/kg 01/09/17 18:06 7439-97-6 H1,H201/05/17 14:060.0092 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.0 %01/05/17 12:000.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 18:23 18540-29-901/05/17 14:450.75 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/17/16 22:18 16887-00-657.3 1
Sulfate ND mg/kg 12/17/16 22:18 14808-79-857.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 77
Page 52 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039216 Lab ID: 92322972001 Collected: 12/07/16 09:43 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/17/16 22:18 14797-55-8 H35.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 77
Page 53 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039218 Lab ID: 92322972002 Collected: 12/07/16 10:29 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 21300 mg/kg 12/29/16 18:31 7429-90-512/23/16 11:5531.4 5
Barium 83.5 mg/kg 12/29/16 05:40 7440-39-312/23/16 11:550.63 1
Beryllium 0.47 mg/kg 12/29/16 05:40 7440-41-712/23/16 11:550.063 1
Boron ND mg/kg 12/29/16 05:40 7440-42-812/23/16 11:553.1 1
Calcium 300 mg/kg 12/29/16 05:40 7440-70-212/23/16 11:5531.4 1
Chromium 12.5 mg/kg 12/29/16 05:40 7440-47-312/23/16 11:550.31 1
Copper 20.6 mg/kg 12/29/16 05:40 7440-50-812/23/16 11:550.31 1
Iron 25800 mg/kg 12/30/16 21:31 7439-89-612/23/16 11:5525.1 10
Magnesium 1870 mg/kg 12/29/16 05:40 7439-95-412/23/16 11:5531.4 1
Manganese 801 mg/kg 12/29/16 18:31 7439-96-512/23/16 11:551.6 5
Molybdenum ND mg/kg 12/29/16 05:40 7439-98-712/23/16 11:550.63 1
Nickel 9.8 mg/kg 12/29/16 05:40 7440-02-012/23/16 11:550.31 1
Potassium 1620 mg/kg 12/29/16 18:31 7440-09-712/23/16 11:55314 5
Silver ND mg/kg 12/29/16 18:31 7440-22-412/23/16 11:551.6 5
Sodium ND mg/kg 12/30/16 21:31 7440-23-512/23/16 11:55628 10
Strontium 7.8 mg/kg 12/29/16 05:40 7440-24-612/23/16 11:550.63 1
Zinc 38.8 mg/kg 12/29/16 18:31 7440-66-612/23/16 11:556.3 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 17:47 7440-36-0 N212/16/16 08:122.4 20
Arsenic ND mg/kg 12/19/16 17:47 7440-38-212/16/16 08:121.2 20
Cadmium ND mg/kg 12/19/16 17:47 7440-43-912/16/16 08:120.14 20
Cobalt 12.7 mg/kg 12/19/16 17:47 7440-48-412/16/16 08:121.2 20
Lead 22.6 mg/kg 12/19/16 17:47 7439-92-112/16/16 08:121.2 20
Selenium ND mg/kg 12/19/16 17:47 7782-49-212/16/16 08:121.2 20
Thallium ND mg/kg 12/19/16 17:47 7440-28-012/16/16 08:121.2 20
Vanadium 23.4 mg/kg 12/19/16 17:47 7440-62-212/16/16 08:121.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.014 mg/kg 01/09/17 18:09 7439-97-6 H1,H201/05/17 14:060.0076 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 10.6 % 01/05/17 12:000.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 18:36 18540-29-901/05/17 14:450.69 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/17/16 23:24 16887-00-656.0 1
Sulfate ND mg/kg 12/17/16 23:24 14808-79-856.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 77
Page 54 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039218 Lab ID: 92322972002 Collected: 12/07/16 10:29 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/17/16 23:24 14797-55-8 H35.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 77
Page 55 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039219 Lab ID: 92322972003 Collected: 12/07/16 12:38 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 17900 mg/kg 12/29/16 18:35 7429-90-512/23/16 11:5534.7 5
Barium 110 mg/kg 12/29/16 18:35 7440-39-312/23/16 11:553.5 5
Beryllium 0.92 mg/kg 12/29/16 18:35 7440-41-712/23/16 11:550.35 5
Boron 20.2 mg/kg 12/29/16 18:35 7440-42-812/23/16 11:5517.3 5
Calcium 823 mg/kg 12/29/16 18:35 7440-70-212/23/16 11:55173 5
Chromium 18.9 mg/kg 12/29/16 18:35 7440-47-312/23/16 11:551.7 5
Copper 21.4 mg/kg 12/29/16 18:35 7440-50-812/23/16 11:551.7 5
Iron 24400 mg/kg 12/30/16 21:35 7439-89-612/23/16 11:5527.7 10
Magnesium 2100 mg/kg 12/29/16 18:35 7439-95-412/23/16 11:55173 5
Manganese 439 mg/kg 12/29/16 18:35 7439-96-512/23/16 11:551.7 5
Molybdenum ND mg/kg 12/29/16 18:35 7439-98-712/23/16 11:553.5 5
Nickel 12.6 mg/kg 12/29/16 18:35 7440-02-012/23/16 11:551.7 5
Potassium 1500 mg/kg 12/29/16 18:35 7440-09-712/23/16 11:55347 5
Silver ND mg/kg 12/29/16 18:35 7440-22-412/23/16 11:551.7 5
Sodium ND mg/kg 12/30/16 21:35 7440-23-512/23/16 11:55693 10
Strontium 22.8 mg/kg 12/29/16 18:35 7440-24-612/23/16 11:553.5 5
Zinc 44.7 mg/kg 12/29/16 18:35 7440-66-612/23/16 11:556.9 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 17:51 7440-36-0 N212/16/16 08:122.6 20
Arsenic 1.7 mg/kg 12/19/16 17:51 7440-38-212/16/16 08:121.3 20
Cadmium ND mg/kg 12/19/16 17:51 7440-43-912/16/16 08:120.16 20
Cobalt 12.6 mg/kg 12/19/16 17:51 7440-48-412/16/16 08:121.3 20
Lead 15.0 mg/kg 12/19/16 17:51 7439-92-112/16/16 08:121.3 20
Selenium ND mg/kg 12/19/16 17:51 7782-49-212/16/16 08:121.3 20
Thallium ND mg/kg 12/19/16 17:51 7440-28-012/16/16 08:121.3 20
Vanadium 26.1 mg/kg 12/19/16 17:51 7440-62-212/16/16 08:121.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.018 mg/kg 01/09/17 18:11 7439-97-6 H1,H201/05/17 14:060.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 10.3 %01/05/17 12:000.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 18:49 18540-29-901/05/17 14:450.71 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/17/16 23:46 16887-00-655.3 1
Sulfate ND mg/kg 12/17/16 23:46 14808-79-855.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 77
Page 56 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039219 Lab ID: 92322972003 Collected: 12/07/16 12:38 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/17/16 23:46 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 77
Page 57 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039221 Lab ID: 92322972004 Collected: 12/07/16 13:11 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 31200 mg/kg 12/29/16 18:39 7429-90-512/23/16 11:5536.5 5
Barium 70.6 mg/kg 12/29/16 18:39 7440-39-312/23/16 11:553.6 5
Beryllium 0.74 mg/kg 12/29/16 18:39 7440-41-712/23/16 11:550.36 5
Boron 45.4 mg/kg 12/29/16 18:39 7440-42-812/23/16 11:5518.2 5
Calcium ND mg/kg 12/29/16 18:39 7440-70-212/23/16 11:55182 5
Chromium 40.0 mg/kg 12/29/16 18:39 7440-47-312/23/16 11:551.8 5
Copper 51.1 mg/kg 12/29/16 18:39 7440-50-812/23/16 11:551.8 5
Iron 61900 mg/kg 12/30/16 21:39 7439-89-612/23/16 11:5529.2 10
Magnesium 652 mg/kg 12/29/16 18:39 7439-95-412/23/16 11:55182 5
Manganese 65.5 mg/kg 12/29/16 18:39 7439-96-512/23/16 11:551.8 5
Molybdenum ND mg/kg 12/29/16 18:39 7439-98-712/23/16 11:553.6 5
Nickel 9.2 mg/kg 12/29/16 18:39 7440-02-012/23/16 11:551.8 5
Potassium 1020 mg/kg 12/29/16 18:39 7440-09-712/23/16 11:55365 5
Silver ND mg/kg 01/04/17 05:35 7440-22-412/23/16 11:5518.2 50
Sodium ND mg/kg 12/30/16 21:39 7440-23-512/23/16 11:55730 10
Strontium 16.3 mg/kg 12/29/16 18:39 7440-24-612/23/16 11:553.6 5
Zinc 40.1 mg/kg 12/29/16 18:39 7440-66-612/23/16 11:557.3 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 17:54 7440-36-0 N212/16/16 08:122.7 20
Arsenic 33.2 mg/kg 12/19/16 17:54 7440-38-212/16/16 08:121.4 20
Cadmium ND mg/kg 12/19/16 17:54 7440-43-912/16/16 08:120.16 20
Cobalt 2.3 mg/kg 12/19/16 17:54 7440-48-412/16/16 08:121.4 20
Lead 36.3 mg/kg 12/19/16 17:54 7439-92-112/16/16 08:121.4 20
Selenium 2.5 mg/kg 12/19/16 17:54 7782-49-212/16/16 08:121.4 20
Thallium ND mg/kg 12/19/16 17:54 7440-28-012/16/16 08:121.4 20
Vanadium 50.1 mg/kg 12/19/16 17:54 7440-62-212/16/16 08:121.4 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.027 mg/kg 01/09/17 18:13 7439-97-6 H1,H201/05/17 14:060.0084 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.7 %01/05/17 12:000.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent 1.1 mg/kg 01/06/17 19:02 18540-29-901/05/17 14:450.77 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 00:08 16887-00-661.4 1
Sulfate ND mg/kg 12/18/16 00:08 14808-79-861.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 77
Page 58 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039221 Lab ID: 92322972004 Collected: 12/07/16 13:11 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 00:08 14797-55-8 H36.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 77
Page 59 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039222 Lab ID: 92322972005 Collected: 12/07/16 14:59 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 26000 mg/kg 12/29/16 19:52 7429-90-512/23/16 11:5536.0 5
Barium 81.2 mg/kg 12/29/16 19:52 7440-39-312/23/16 11:553.6 5
Beryllium 1.1 mg/kg 12/29/16 19:52 7440-41-712/23/16 11:550.36 5
Boron 35.9 mg/kg 12/29/16 19:52 7440-42-812/23/16 11:5518.0 5
Calcium ND mg/kg 12/29/16 19:52 7440-70-212/23/16 11:55180 5
Chromium 21.6 mg/kg 12/29/16 19:52 7440-47-312/23/16 11:551.8 5
Copper 34.8 mg/kg 12/29/16 19:52 7440-50-812/23/16 11:551.8 5
Iron 40600 mg/kg 12/29/16 19:52 7439-89-612/23/16 11:5514.4 5
Magnesium 1370 mg/kg 12/29/16 19:52 7439-95-412/23/16 11:55180 5
Manganese 177 mg/kg 12/29/16 19:52 7439-96-512/23/16 11:551.8 5
Molybdenum ND mg/kg 12/29/16 19:52 7439-98-712/23/16 11:553.6 5
Nickel 10.5 mg/kg 12/29/16 19:52 7440-02-012/23/16 11:551.8 5
Potassium 1800 mg/kg 12/29/16 19:52 7440-09-712/23/16 11:55360 5
Silver ND mg/kg 01/03/17 11:32 7440-22-412/23/16 11:557.2 20
Sodium ND mg/kg 12/29/16 19:52 7440-23-512/23/16 11:55360 5
Strontium ND mg/kg 12/29/16 19:52 7440-24-612/23/16 11:553.6 5
Zinc 50.2 mg/kg 12/29/16 19:52 7440-66-612/23/16 11:557.2 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 17:58 7440-36-0 N212/16/16 08:122.7 20
Arsenic 4.3 mg/kg 12/19/16 17:58 7440-38-212/16/16 08:121.3 20
Cadmium ND mg/kg 12/21/16 15:32 7440-43-912/16/16 08:120.40 50
Cobalt 9.4 mg/kg 12/19/16 17:58 7440-48-412/16/16 08:121.3 20
Lead 17.5 mg/kg 12/19/16 17:58 7439-92-112/16/16 08:121.3 20
Selenium ND mg/kg 12/21/16 15:32 7782-49-212/16/16 08:123.3 50
Thallium ND mg/kg 12/19/16 17:58 7440-28-012/16/16 08:121.3 20
Vanadium 40.4 mg/kg 12/19/16 17:58 7440-62-212/16/16 08:121.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.013 mg/kg 01/05/17 13:29 7439-97-6 H101/03/17 14:120.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 20.0 % 01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.1 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 19:15 18540-29-901/05/17 14:450.77 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 01:14 16887-00-661.5 1
Sulfate ND mg/kg 12/18/16 01:14 14808-79-861.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 77
Page 60 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039222 Lab ID: 92322972005 Collected: 12/07/16 14:59 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 01:14 14797-55-8 H36.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 77
Page 61 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039224 Lab ID: 92322972006 Collected: 12/07/16 15:22 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 31000 mg/kg 12/30/16 21:46 7429-90-512/23/16 11:5562.3 10
Barium 246 mg/kg 12/30/16 21:46 7440-39-312/23/16 11:556.2 10
Beryllium 3.4 mg/kg 12/30/16 21:46 7440-41-712/23/16 11:550.62 10
Boron 36.9 mg/kg 12/30/16 21:46 7440-42-812/23/16 11:5531.2 10
Calcium ND mg/kg 12/30/16 21:46 7440-70-212/23/16 11:55312 10
Chromium 25.7 mg/kg 12/30/16 21:46 7440-47-312/23/16 11:553.1 10
Copper 27.1 mg/kg 12/30/16 21:46 7440-50-812/23/16 11:553.1 10
Iron 44200 mg/kg 12/30/16 21:46 7439-89-612/23/16 11:5524.9 10
Magnesium 4430 mg/kg 12/30/16 21:46 7439-95-412/23/16 11:55312 10
Manganese 1280 mg/kg 12/30/16 21:46 7439-96-512/23/16 11:553.1 10
Molybdenum ND mg/kg 12/30/16 21:46 7439-98-712/23/16 11:556.2 10
Nickel 37.1 mg/kg 12/30/16 21:46 7440-02-012/23/16 11:553.1 10
Potassium 2640 mg/kg 01/03/17 11:36 7440-09-712/23/16 11:551250 20
Silver ND mg/kg 01/04/17 05:40 7440-22-412/23/16 11:5515.6 50
Sodium ND mg/kg 12/30/16 21:46 7440-23-512/23/16 11:55623 10
Strontium ND mg/kg 12/30/16 21:46 7440-24-612/23/16 11:556.2 10
Zinc 145 mg/kg 12/30/16 21:46 7440-66-612/23/16 11:5512.5 10
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:01 7440-36-0 N212/16/16 08:122.3 20
Arsenic 3.7 mg/kg 12/19/16 18:01 7440-38-212/16/16 08:121.2 20
Cadmium ND mg/kg 12/21/16 15:40 7440-43-912/16/16 08:120.35 50
Cobalt 43.5 mg/kg 12/19/16 18:01 7440-48-412/16/16 08:121.2 20
Lead 11.7 mg/kg 12/19/16 18:01 7439-92-112/16/16 08:121.2 20
Selenium 8.7 mg/kg 12/28/16 11:55 7782-49-212/16/16 08:122.9 50
Thallium ND mg/kg 12/19/16 18:01 7440-28-012/16/16 08:121.2 20
Vanadium 36.7 mg/kg 12/19/16 18:01 7440-62-212/16/16 08:121.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 01/05/17 13:40 7439-97-6 H101/03/17 14:120.0088 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 14.8 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.7 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 19:28 18540-29-901/05/17 14:450.72 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 01:36 16887-00-659.3 1
Sulfate ND mg/kg 12/18/16 01:36 14808-79-859.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 77
Page 62 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039224 Lab ID: 92322972006 Collected: 12/07/16 15:22 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 01:36 14797-55-8 H35.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 77
Page 63 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039225 Lab ID: 92322972007 Collected: 12/08/16 08:30 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 42600 mg/kg 12/30/16 21:50 7429-90-512/23/16 11:5573.9 10
Barium 251 mg/kg 12/30/16 21:50 7440-39-312/23/16 11:557.4 10
Beryllium 4.5 mg/kg 12/30/16 21:50 7440-41-712/23/16 11:550.74 10
Boron 37.7 mg/kg 12/30/16 21:50 7440-42-812/23/16 11:5537.0 10
Calcium ND mg/kg 12/30/16 21:50 7440-70-212/23/16 11:55370 10
Chromium 34.6 mg/kg 12/30/16 21:50 7440-47-312/23/16 11:553.7 10
Copper 60.8 mg/kg 12/30/16 21:50 7440-50-812/23/16 11:553.7 10
Iron 47100 mg/kg 12/30/16 21:50 7439-89-612/23/16 11:5529.6 10
Magnesium 8130 mg/kg 12/30/16 21:50 7439-95-412/23/16 11:55370 10
Manganese 1170 mg/kg 12/30/16 21:50 7439-96-512/23/16 11:553.7 10
Molybdenum ND mg/kg 12/29/16 20:07 7439-98-712/23/16 11:550.74 1
Nickel 27.4 mg/kg 12/29/16 20:07 7440-02-012/23/16 11:550.37 1
Potassium 2980 mg/kg 01/03/17 11:41 7440-09-712/23/16 11:551480 20
Silver ND mg/kg 01/04/17 05:45 7440-22-412/23/16 11:5518.5 50
Sodium ND mg/kg 12/30/16 21:50 7440-23-512/23/16 11:55739 10
Strontium 57.3 mg/kg 12/30/16 21:50 7440-24-612/23/16 11:557.4 10
Zinc 109 mg/kg 12/29/16 20:07 7440-66-612/23/16 11:551.5 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:05 7440-36-0 N212/16/16 08:122.3 20
Arsenic 5.2 mg/kg 12/19/16 18:05 7440-38-212/16/16 08:121.1 20
Cadmium ND mg/kg 12/21/16 15:43 7440-43-912/16/16 08:120.34 50
Cobalt 46.2 mg/kg 12/19/16 18:05 7440-48-412/16/16 08:121.1 20
Lead 30.7 mg/kg 12/19/16 18:05 7439-92-112/16/16 08:121.1 20
Selenium 6.1 mg/kg 12/28/16 11:59 7782-49-212/16/16 08:122.8 50
Thallium ND mg/kg 12/19/16 18:05 7440-28-012/16/16 08:121.1 20
Vanadium 31.9 mg/kg 12/19/16 18:05 7440-62-212/16/16 08:121.1 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.0099 mg/kg 01/05/17 13:45 7439-97-6 H101/03/17 14:120.0099 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 21.0 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.4 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 19:41 18540-29-901/05/17 14:450.82 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 01:58 16887-00-663.4 1
Sulfate ND mg/kg 12/18/16 01:58 14808-79-863.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 77
Page 64 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039225 Lab ID: 92322972007 Collected: 12/08/16 08:30 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 01:58 14797-55-8 H36.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 77
Page 65 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039227 Lab ID: 92322972008 Collected: 12/08/16 09:02 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 28900 mg/kg 12/29/16 20:12 7429-90-512/23/16 11:5536.4 5
Barium 182 mg/kg 12/29/16 20:12 7440-39-312/23/16 11:553.6 5
Beryllium 1.8 mg/kg 12/29/16 20:12 7440-41-712/23/16 11:550.36 5
Boron 26.8 mg/kg 12/29/16 20:12 7440-42-812/23/16 11:5518.2 5
Calcium 645 mg/kg 12/29/16 20:12 7440-70-212/23/16 11:55182 5
Chromium 23.7 mg/kg 12/29/16 20:12 7440-47-312/23/16 11:551.8 5
Copper 24.2 mg/kg 12/29/16 20:12 7440-50-812/23/16 11:551.8 5
Iron 31000 mg/kg 12/29/16 20:12 7439-89-612/23/16 11:5514.6 5
Magnesium 6890 mg/kg 12/29/16 20:12 7439-95-412/23/16 11:55182 5
Manganese 403 mg/kg 12/29/16 20:12 7439-96-512/23/16 11:551.8 5
Molybdenum ND mg/kg 12/29/16 20:12 7439-98-712/23/16 11:553.6 5
Nickel 27.7 mg/kg 12/29/16 20:12 7440-02-012/23/16 11:551.8 5
Potassium 1880 mg/kg 12/29/16 20:12 7440-09-712/23/16 11:55364 5
Silver ND mg/kg 12/29/16 20:12 7440-22-412/23/16 11:551.8 5
Sodium ND mg/kg 12/29/16 20:12 7440-23-512/23/16 11:55364 5
Strontium 32.1 mg/kg 12/29/16 20:12 7440-24-612/23/16 11:553.6 5
Zinc 86.0 mg/kg 12/29/16 20:12 7440-66-612/23/16 11:557.3 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:09 7440-36-0 N212/16/16 08:122.9 20
Arsenic 3.6 mg/kg 12/19/16 18:09 7440-38-212/16/16 08:121.4 20
Cadmium ND mg/kg 12/21/16 15:47 7440-43-912/16/16 08:120.43 50
Cobalt 16.5 mg/kg 12/19/16 18:09 7440-48-412/16/16 08:121.4 20
Lead 12.9 mg/kg 12/19/16 18:09 7439-92-112/16/16 08:121.4 20
Selenium 4.5 mg/kg 12/28/16 12:02 7782-49-212/16/16 08:123.6 50
Thallium ND mg/kg 12/19/16 18:09 7440-28-012/16/16 08:121.4 20
Vanadium 32.5 mg/kg 12/19/16 18:09 7440-62-212/16/16 08:121.4 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 01/05/17 13:47 7439-97-6 H101/03/17 14:120.0093 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.1 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.8 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent 2.0 mg/kg 01/06/17 19:54 18540-29-901/05/17 14:450.74 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 02:20 16887-00-658.4 1
Sulfate ND mg/kg 12/18/16 02:20 14808-79-858.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 77
Page 66 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039227 Lab ID: 92322972008 Collected: 12/08/16 09:02 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 02:20 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 77
Page 67 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039228 Lab ID: 92322972009 Collected: 12/08/16 10:20 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 14400 mg/kg 12/29/16 20:15 7429-90-512/23/16 11:5533.2 5
Barium 60.5 mg/kg 12/29/16 20:15 7440-39-312/23/16 11:553.3 5
Beryllium 0.49 mg/kg 12/29/16 20:15 7440-41-712/23/16 11:550.33 5
Boron 22.7 mg/kg 12/29/16 20:15 7440-42-812/23/16 11:5516.6 5
Calcium ND mg/kg 12/29/16 20:15 7440-70-212/23/16 11:55166 5
Chromium 23.5 mg/kg 12/29/16 20:15 7440-47-312/23/16 11:551.7 5
Copper 10.7 mg/kg 12/29/16 20:15 7440-50-812/23/16 11:551.7 5
Iron 26500 mg/kg 12/29/16 20:15 7439-89-612/23/16 11:5513.3 5
Magnesium 629 mg/kg 12/29/16 20:15 7439-95-412/23/16 11:55166 5
Manganese 382 mg/kg 12/29/16 20:15 7439-96-512/23/16 11:551.7 5
Molybdenum ND mg/kg 12/29/16 20:15 7439-98-712/23/16 11:553.3 5
Nickel 4.9 mg/kg 12/29/16 20:15 7440-02-012/23/16 11:551.7 5
Potassium 692 mg/kg 12/29/16 20:15 7440-09-712/23/16 11:55332 5
Silver ND mg/kg 12/29/16 20:15 7440-22-412/23/16 11:551.7 5
Sodium ND mg/kg 12/29/16 20:15 7440-23-512/23/16 11:55332 5
Strontium ND mg/kg 12/29/16 20:15 7440-24-612/23/16 11:553.3 5
Zinc 21.9 mg/kg 12/29/16 20:15 7440-66-612/23/16 11:556.6 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:12 7440-36-0 N212/16/16 08:122.2 20
Arsenic 2.8 mg/kg 12/19/16 18:12 7440-38-212/16/16 08:121.1 20
Cadmium ND mg/kg 12/19/16 18:12 7440-43-912/16/16 08:120.13 20
Cobalt 6.2 mg/kg 12/19/16 18:12 7440-48-412/16/16 08:121.1 20
Lead 14.2 mg/kg 12/19/16 18:12 7439-92-112/16/16 08:121.1 20
Selenium ND mg/kg 12/19/16 18:12 7782-49-212/16/16 08:121.1 20
Thallium ND mg/kg 12/19/16 18:12 7440-28-012/16/16 08:121.1 20
Vanadium 30.9 mg/kg 12/19/16 18:12 7440-62-212/16/16 08:121.1 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.026 mg/kg 12/22/16 15:22 7439-97-612/21/16 14:130.0089 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 9.5 % 01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 20:07 18540-29-901/05/17 14:450.71 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 02:42 16887-00-654.1 1
Sulfate ND mg/kg 12/18/16 02:42 14808-79-854.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 77
Page 68 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039228 Lab ID: 92322972009 Collected: 12/08/16 10:20 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 02:42 14797-55-8 H35.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 77
Page 69 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039230 Lab ID: 92322972010 Collected: 12/08/16 10:49 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 29300 mg/kg 12/30/16 05:48 7429-90-512/23/16 11:557.3 1
Barium 89.2 mg/kg 12/30/16 05:48 7440-39-312/23/16 11:550.73 1
Beryllium 1.0 mg/kg 12/30/16 05:48 7440-41-712/23/16 11:550.073 1
Boron 4.3 mg/kg 12/30/16 05:48 7440-42-812/23/16 11:553.6 1
Calcium ND mg/kg 12/30/16 05:48 7440-70-212/23/16 11:5536.3 1
Chromium 16.4 mg/kg 12/30/16 05:48 7440-47-312/23/16 11:550.36 1
Copper 29.4 mg/kg 12/30/16 05:48 7440-50-812/23/16 11:550.36 1
Iron 47000 mg/kg 12/30/16 21:54 7439-89-612/23/16 11:5529.0 10
Magnesium 1190 mg/kg 12/30/16 05:48 7439-95-412/23/16 11:5536.3 1
Manganese 171 mg/kg 12/30/16 05:48 7439-96-512/23/16 11:550.36 1
Molybdenum ND mg/kg 12/30/16 05:48 7439-98-712/23/16 11:550.73 1
Nickel 6.8 mg/kg 12/30/16 05:48 7440-02-012/23/16 11:550.36 1
Potassium 1770 mg/kg 12/30/16 05:48 7440-09-712/23/16 11:5572.6 1
Silver ND mg/kg 01/04/17 05:49 7440-22-412/23/16 11:5518.1 50
Sodium 86.3 mg/kg 12/30/16 05:48 7440-23-512/23/16 11:5572.6 1
Strontium 3.8 mg/kg 12/30/16 05:48 7440-24-612/23/16 11:550.73 1
Zinc 34.0 mg/kg 12/29/16 20:19 7440-66-612/23/16 11:551.5 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:16 7440-36-0 N212/16/16 08:122.4 20
Arsenic 1.9 mg/kg 12/19/16 18:16 7440-38-212/16/16 08:121.2 20
Cadmium ND mg/kg 12/19/16 18:16 7440-43-912/16/16 08:120.14 20
Cobalt 2.2 mg/kg 12/19/16 18:16 7440-48-412/16/16 08:121.2 20
Lead 32.3 mg/kg 12/19/16 18:16 7439-92-112/16/16 08:121.2 20
Selenium 1.3 mg/kg 12/19/16 18:16 7782-49-212/16/16 08:121.2 20
Thallium ND mg/kg 12/19/16 18:16 7440-28-012/16/16 08:121.2 20
Vanadium 40.8 mg/kg 12/19/16 18:16 7440-62-212/16/16 08:121.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.050 mg/kg 12/22/16 15:24 7439-97-612/21/16 14:130.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 18.6 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 20:20 18540-29-901/05/17 14:450.80 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 03:04 16887-00-661.8 1
Sulfate ND mg/kg 12/18/16 03:04 14808-79-861.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 77
Page 70 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039230 Lab ID: 92322972010 Collected: 12/08/16 10:49 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 03:04 14797-55-8 H36.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 77
Page 71 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039231 Lab ID: 92322972011 Collected: 12/08/16 11:38 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 20700 mg/kg 12/30/16 05:52 7429-90-512/23/16 11:556.8 1
Barium 83.5 mg/kg 12/30/16 05:52 7440-39-312/23/16 11:550.68 1
Beryllium 0.85 mg/kg 12/30/16 05:52 7440-41-712/23/16 11:550.068 1
Boron 3.6 mg/kg 12/30/16 05:52 7440-42-812/23/16 11:553.4 1
Calcium 213 mg/kg 12/30/16 05:52 7440-70-212/23/16 11:5534.0 1
Chromium 22.3 mg/kg 12/30/16 05:52 7440-47-312/23/16 11:550.34 1
Copper 27.1 mg/kg 12/30/16 05:52 7440-50-812/23/16 11:550.34 1
Iron 36400 mg/kg 12/30/16 22:06 7439-89-612/23/16 11:5527.2 10
Magnesium 1100 mg/kg 12/30/16 05:52 7439-95-412/23/16 11:5534.0 1
Manganese 190 mg/kg 12/30/16 05:52 7439-96-512/23/16 11:550.34 1
Molybdenum 0.79 mg/kg 12/30/16 05:52 7439-98-712/23/16 11:550.68 1
Nickel 8.1 mg/kg 12/30/16 05:52 7440-02-012/23/16 11:550.34 1
Potassium 1310 mg/kg 12/30/16 05:52 7440-09-712/23/16 11:5568.0 1
Silver ND mg/kg 01/03/17 11:50 7440-22-412/23/16 11:556.8 20
Sodium ND mg/kg 12/30/16 05:52 7440-23-512/23/16 11:5568.0 1
Strontium 6.0 mg/kg 12/30/16 05:52 7440-24-612/23/16 11:550.68 1
Zinc 39.4 mg/kg 12/29/16 20:23 7440-66-612/23/16 11:551.4 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:19 7440-36-0 N212/16/16 08:122.5 20
Arsenic 9.4 mg/kg 12/19/16 18:19 7440-38-212/16/16 08:121.2 20
Cadmium ND mg/kg 12/19/16 18:19 7440-43-912/16/16 08:120.15 20
Cobalt 9.5 mg/kg 12/19/16 18:19 7440-48-412/16/16 08:121.2 20
Lead 16.6 mg/kg 12/19/16 18:19 7439-92-112/16/16 08:121.2 20
Selenium ND mg/kg 12/19/16 18:19 7782-49-212/16/16 08:121.2 20
Thallium ND mg/kg 12/19/16 18:19 7440-28-012/16/16 08:121.2 20
Vanadium 41.7 mg/kg 12/19/16 18:19 7440-62-212/16/16 08:121.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.037 mg/kg 12/22/16 15:26 7439-97-612/21/16 14:130.0079 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 9.5 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 20:59 18540-29-901/05/17 14:450.71 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 03:26 16887-00-654.8 1
Sulfate ND mg/kg 12/18/16 03:26 14808-79-854.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 77
Page 72 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039231 Lab ID: 92322972011 Collected: 12/08/16 11:38 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 03:26 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 77
Page 73 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039232 Lab ID: 92322972012 Collected: 12/08/16 11:48 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 28200 mg/kg 12/30/16 05:57 7429-90-512/23/16 11:556.6 1
Barium 82.8 mg/kg 12/30/16 05:57 7440-39-312/23/16 11:550.66 1
Beryllium 1.7 mg/kg 12/30/16 22:10 7440-41-712/23/16 11:550.66 10
Boron 46.5 mg/kg 12/30/16 22:10 7440-42-812/23/16 11:5533.2 10
Calcium 51.6 mg/kg 12/30/16 05:57 7440-70-212/23/16 11:5533.2 1
Chromium 32.6 mg/kg 12/30/16 22:10 7440-47-312/23/16 11:553.3 10
Copper 63.0 mg/kg 12/30/16 22:10 7440-50-812/23/16 11:553.3 10
Iron 53200 mg/kg 12/30/16 22:10 7439-89-612/23/16 11:5526.6 10
Magnesium 1660 mg/kg 12/30/16 05:57 7439-95-412/23/16 11:5533.2 1
Manganese 121 mg/kg 12/30/16 22:10 7439-96-512/23/16 11:553.3 10
Molybdenum 0.71 mg/kg 12/30/16 05:57 7439-98-712/23/16 11:550.66 1
Nickel 12.6 mg/kg 12/30/16 05:57 7440-02-012/23/16 11:550.33 1
Potassium 1760 mg/kg 12/30/16 05:57 7440-09-712/23/16 11:5566.4 1
Silver ND mg/kg 01/04/17 05:54 7440-22-412/23/16 11:5516.6 50
Sodium 90.5 mg/kg 12/30/16 05:57 7440-23-512/23/16 11:5566.4 1
Strontium 3.9 mg/kg 12/30/16 05:57 7440-24-612/23/16 11:550.66 1
Zinc 70.2 mg/kg 12/29/16 20:27 7440-66-612/23/16 11:551.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:37 7440-36-0 N212/16/16 08:122.2 20
Arsenic 4.5 mg/kg 12/19/16 18:37 7440-38-212/16/16 08:121.1 20
Cadmium ND mg/kg 12/21/16 15:50 7440-43-912/16/16 08:120.33 50
Cobalt 6.6 mg/kg 12/19/16 18:37 7440-48-412/16/16 08:121.1 20
Lead 17.4 mg/kg 12/19/16 18:37 7439-92-112/16/16 08:121.1 20
Selenium 2.9 mg/kg 12/28/16 12:06 7782-49-212/16/16 08:122.8 50
Thallium ND mg/kg 12/19/16 18:37 7440-28-012/16/16 08:121.1 20
Vanadium 49.1 mg/kg 12/19/16 18:37 7440-62-212/16/16 08:121.1 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.040 mg/kg 01/05/17 13:49 7439-97-6 H101/03/17 14:120.0095 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.8 % 01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.4 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 21:12 18540-29-901/05/17 14:450.74 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 03:48 16887-00-658.1 1
Sulfate ND mg/kg 12/18/16 03:48 14808-79-858.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 77
Page 74 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039232 Lab ID: 92322972012 Collected: 12/08/16 11:48 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 03:48 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 77
Page 75 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039233 Lab ID: 92322972013 Collected: 12/08/16 13:08 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 22900 mg/kg 12/30/16 06:01 7429-90-512/23/16 11:555.5 1
Barium 101 mg/kg 12/30/16 06:01 7440-39-312/23/16 11:550.55 1
Beryllium 0.54 mg/kg 12/30/16 06:01 7440-41-712/23/16 11:550.055 1
Boron 3.3 mg/kg 12/30/16 06:01 7440-42-812/23/16 11:552.7 1
Calcium 324 mg/kg 12/30/16 06:01 7440-70-212/23/16 11:5527.5 1
Chromium 18.0 mg/kg 12/30/16 06:01 7440-47-312/23/16 11:550.27 1
Copper 25.4 mg/kg 12/30/16 06:01 7440-50-812/23/16 11:550.27 1
Iron 34000 mg/kg 12/30/16 22:14 7439-89-612/23/16 11:5522.0 10
Magnesium 1910 mg/kg 12/30/16 06:01 7439-95-412/23/16 11:5527.5 1
Manganese 160 mg/kg 12/30/16 06:01 7439-96-512/23/16 11:550.27 1
Molybdenum ND mg/kg 12/30/16 06:01 7439-98-712/23/16 11:550.55 1
Nickel 11.4 mg/kg 12/30/16 06:01 7440-02-012/23/16 11:550.27 1
Potassium 1980 mg/kg 12/30/16 06:01 7440-09-712/23/16 11:5554.9 1
Silver ND mg/kg 01/03/17 11:59 7440-22-412/23/16 11:555.5 20
Sodium 94.7 mg/kg 12/30/16 06:01 7440-23-512/23/16 11:5554.9 1
Strontium 8.1 mg/kg 12/30/16 06:01 7440-24-612/23/16 11:550.55 1
Zinc 43.4 mg/kg 12/29/16 20:31 7440-66-612/23/16 11:551.1 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:41 7440-36-0 N212/16/16 08:122.9 20
Arsenic 2.6 mg/kg 12/19/16 18:41 7440-38-212/16/16 08:121.5 20
Cadmium ND mg/kg 12/19/16 18:41 7440-43-912/16/16 08:120.18 20
Cobalt 6.6 mg/kg 12/19/16 18:41 7440-48-412/16/16 08:121.5 20
Lead 18.7 mg/kg 12/19/16 18:41 7439-92-112/16/16 08:121.5 20
Selenium ND mg/kg 12/19/16 18:41 7782-49-212/16/16 08:121.5 20
Thallium ND mg/kg 12/19/16 18:41 7440-28-012/16/16 08:121.5 20
Vanadium 47.4 mg/kg 12/19/16 18:41 7440-62-212/16/16 08:121.5 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.031 mg/kg 01/05/17 13:51 7439-97-6 H101/03/17 14:120.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.7 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.9 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 21:25 18540-29-901/05/17 14:450.73 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 04:10 16887-00-659.1 1
Sulfate ND mg/kg 12/18/16 04:10 14808-79-859.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 77
Page 76 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039233 Lab ID: 92322972013 Collected: 12/08/16 13:08 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 04:10 14797-55-8 H35.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 77
Page 77 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039235 Lab ID: 92322972014 Collected: 12/08/16 13:51 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 24100 mg/kg 12/30/16 06:06 7429-90-512/23/16 11:557.0 1
Barium 70.6 mg/kg 12/30/16 06:06 7440-39-312/23/16 11:550.70 1
Beryllium 0.92 mg/kg 12/30/16 06:06 7440-41-712/23/16 11:550.070 1
Boron 4.5 mg/kg 12/30/16 06:06 7440-42-812/23/16 11:553.5 1
Calcium ND mg/kg 12/30/16 06:06 7440-70-212/23/16 11:5534.9 1
Chromium 24.7 mg/kg 12/30/16 06:06 7440-47-312/23/16 11:550.35 1
Copper 22.9 mg/kg 12/30/16 06:06 7440-50-812/23/16 11:550.35 1
Iron 52800 mg/kg 12/30/16 22:18 7439-89-612/23/16 11:5528.0 10
Magnesium 1730 mg/kg 12/30/16 06:06 7439-95-412/23/16 11:5534.9 1
Manganese 51.0 mg/kg 12/30/16 06:06 7439-96-512/23/16 11:550.35 1
Molybdenum ND mg/kg 12/30/16 06:06 7439-98-712/23/16 11:550.70 1
Nickel 10.4 mg/kg 12/30/16 06:06 7440-02-012/23/16 11:550.35 1
Potassium 1720 mg/kg 12/30/16 06:06 7440-09-712/23/16 11:5569.9 1
Silver ND mg/kg 01/04/17 05:59 7440-22-412/23/16 11:5517.5 50
Sodium 118 mg/kg 12/30/16 06:06 7440-23-512/23/16 11:5569.9 1
Strontium 5.9 mg/kg 12/30/16 06:06 7440-24-612/23/16 11:550.70 1
Zinc 50.7 mg/kg 12/29/16 20:35 7440-66-612/23/16 11:551.4 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:44 7440-36-0 N212/16/16 08:122.5 20
Arsenic ND mg/kg 12/19/16 18:44 7440-38-212/16/16 08:121.3 20
Cadmium ND mg/kg 12/19/16 18:44 7440-43-912/16/16 08:120.15 20
Cobalt 3.6 mg/kg 12/19/16 18:44 7440-48-412/16/16 08:121.3 20
Lead 16.1 mg/kg 12/19/16 18:44 7439-92-112/16/16 08:121.3 20
Selenium ND mg/kg 12/19/16 18:44 7782-49-212/16/16 08:121.3 20
Thallium ND mg/kg 12/19/16 18:44 7440-28-012/16/16 08:121.3 20
Vanadium 41.5 mg/kg 12/19/16 18:44 7440-62-212/16/16 08:121.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.022 mg/kg 01/09/17 18:19 7439-97-6 H1,H201/05/17 14:060.012 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.8 %01/05/17 12:010.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.0 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 21:38 18540-29-901/05/17 14:450.77 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 04:32 16887-00-658.0 1
Sulfate ND mg/kg 12/18/16 04:32 14808-79-858.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 77
Page 78 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039235 Lab ID: 92322972014 Collected: 12/08/16 13:51 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 04:32 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 77
Page 79 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039236 Lab ID: 92322972015 Collected: 12/08/16 14:47 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 23500 mg/kg 12/30/16 06:10 7429-90-512/23/16 11:556.3 1
Barium 99.7 mg/kg 12/30/16 06:10 7440-39-312/23/16 11:550.63 1
Beryllium 1.5 mg/kg 12/30/16 22:22 7440-41-712/23/16 11:550.63 10
Boron ND mg/kg 12/30/16 22:22 7440-42-812/23/16 11:5531.3 10
Calcium 125 mg/kg 12/30/16 06:10 7440-70-212/23/16 11:5531.3 1
Chromium 23.2 mg/kg 12/30/16 22:22 7440-47-312/23/16 11:553.1 10
Copper 34.3 mg/kg 12/30/16 22:22 7440-50-812/23/16 11:553.1 10
Iron 34600 mg/kg 12/30/16 22:22 7439-89-612/23/16 11:5525.0 10
Magnesium 1770 mg/kg 12/30/16 06:10 7439-95-412/23/16 11:5531.3 1
Manganese 572 mg/kg 12/30/16 22:22 7439-96-512/23/16 11:553.1 10
Molybdenum ND mg/kg 12/30/16 06:10 7439-98-712/23/16 11:550.63 1
Nickel 14.9 mg/kg 12/30/16 06:10 7440-02-012/23/16 11:550.31 1
Potassium 1760 mg/kg 12/30/16 06:10 7440-09-712/23/16 11:5562.6 1
Silver ND mg/kg 01/03/17 12:08 7440-22-412/23/16 11:556.3 20
Sodium 101 mg/kg 12/30/16 06:10 7440-23-512/23/16 11:5562.6 1
Strontium 4.4 mg/kg 12/30/16 06:10 7440-24-612/23/16 11:550.63 1
Zinc 54.3 mg/kg 12/29/16 20:39 7440-66-612/23/16 11:551.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:48 7440-36-0 N212/16/16 08:122.6 20
Arsenic 1.9 mg/kg 12/19/16 18:48 7440-38-212/16/16 08:121.3 20
Cadmium ND mg/kg 12/21/16 15:54 7440-43-912/16/16 08:120.39 50
Cobalt 22.3 mg/kg 12/19/16 18:48 7440-48-412/16/16 08:121.3 20
Lead 20.3 mg/kg 12/19/16 18:48 7439-92-112/16/16 08:121.3 20
Selenium 4.1 mg/kg 12/28/16 12:17 7782-49-212/16/16 08:123.2 50
Thallium ND mg/kg 12/19/16 18:48 7440-28-012/16/16 08:121.3 20
Vanadium 37.7 mg/kg 12/19/16 18:48 7440-62-212/16/16 08:121.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 01/09/17 18:21 7439-97-6 H1,H201/05/17 14:060.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.2 %01/05/17 12:020.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.8 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 21:51 18540-29-901/05/17 14:450.76 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 05:38 16887-00-660.0 1
Sulfate ND mg/kg 12/18/16 05:38 14808-79-860.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 77
Page 80 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039236 Lab ID: 92322972015 Collected: 12/08/16 14:47 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 05:38 14797-55-8 H36.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 77
Page 81 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039238 Lab ID: 92322972016 Collected: 12/08/16 15:25 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 14500 mg/kg 12/30/16 06:15 7429-90-512/23/16 11:556.2 1
Barium 87.8 mg/kg 12/30/16 06:15 7440-39-312/23/16 11:550.62 1
Beryllium 0.76 mg/kg 12/30/16 06:15 7440-41-712/23/16 11:550.062 1
Boron 3.5 mg/kg 12/30/16 06:15 7440-42-812/23/16 11:553.1 1
Calcium 422 mg/kg 12/30/16 06:15 7440-70-212/23/16 11:5531.0 1
Chromium 17.8 mg/kg 12/30/16 06:15 7440-47-312/23/16 11:550.31 1
Copper 23.6 mg/kg 12/30/16 06:15 7440-50-812/23/16 11:550.31 1
Iron 29800 mg/kg 12/30/16 22:26 7439-89-612/23/16 11:5524.8 10
Magnesium 756 mg/kg 12/30/16 06:15 7439-95-412/23/16 11:5531.0 1
Manganese 184 mg/kg 12/30/16 06:15 7439-96-512/23/16 11:550.31 1
Molybdenum 0.71 mg/kg 12/30/16 06:15 7439-98-712/23/16 11:550.62 1
Nickel 7.7 mg/kg 12/30/16 06:15 7440-02-012/23/16 11:550.31 1
Potassium 932 mg/kg 12/30/16 06:15 7440-09-712/23/16 11:5562.0 1
Silver ND mg/kg 01/03/17 12:22 7440-22-412/23/16 11:556.2 20
Sodium ND mg/kg 12/30/16 06:15 7440-23-512/23/16 11:5562.0 1
Strontium 23.2 mg/kg 12/30/16 06:15 7440-24-612/23/16 11:550.62 1
Zinc 35.8 mg/kg 12/29/16 20:51 7440-66-612/23/16 11:551.2 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 12/19/16 18:51 7440-36-0 N212/16/16 08:122.0 20
Arsenic 5.3 mg/kg 12/19/16 18:51 7440-38-212/16/16 08:120.98 20
Cadmium ND mg/kg 12/19/16 18:51 7440-43-912/16/16 08:120.12 20
Cobalt 8.3 mg/kg 12/19/16 18:51 7440-48-412/16/16 08:120.98 20
Lead 13.7 mg/kg 12/19/16 18:51 7439-92-112/16/16 08:120.98 20
Selenium ND mg/kg 12/19/16 18:51 7782-49-212/16/16 08:120.98 20
Thallium ND mg/kg 12/19/16 18:51 7440-28-012/16/16 08:120.98 20
Vanadium 28.4 mg/kg 12/19/16 18:51 7440-62-212/16/16 08:120.98 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.028 mg/kg 01/09/17 18:24 7439-97-6 H1,H201/05/17 14:060.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 14.4 %01/05/17 12:020.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.5 Std. Units 12/20/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 01/06/17 22:04 18540-29-901/05/17 14:450.74 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 12/18/16 06:00 16887-00-658.2 1
Sulfate ND mg/kg 12/18/16 06:00 14808-79-858.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 77
Page 82 of 115
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92322972
J16120243
Sample: 2016039238 Lab ID: 92322972016 Collected: 12/08/16 15:25 Received: 12/12/16 13:50 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 12/18/16 06:00 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 77
Page 83 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340032
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples: 92322972009, 92322972010, 92322972011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1824222
Associated Lab Samples:92322972009, 92322972010, 92322972011
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.0069 12/22/16 14:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1824223LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.093.098 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1824224MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35283296001
1824225
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg 2.81 94 80-12095 15 203.30.23J 2.9 3.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 77
Page 84 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341974
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples: 92322972005, 92322972006, 92322972007, 92322972008, 92322972012, 92322972013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1834608
Associated Lab Samples:92322972005, 92322972006, 92322972007, 92322972008, 92322972012, 92322972013
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.0074 01/05/17 13:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1834609LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.084.092 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1834610MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322972005
1834611
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg H1.095 87 80-120101 15 20.09880.013 0.097 0.11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 77
Page 85 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342500
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972014, 92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1837320
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972014, 92322972015, 92322972016
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.0074 01/09/17 17:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1837321LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.078.088 89 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1837322MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35285150006
1837323
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg .0901 85 80-12089 3 20.08910.011 0.088 0.090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 77
Page 86 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340581
EPA 3050
EPA 6010
6010 MET Solid
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1827663
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Matrix: Solid
Analyzed
Aluminum mg/kg ND 5.7 12/29/16 17:43
Barium mg/kg ND 0.57 12/29/16 17:43
Beryllium mg/kg ND 0.057 12/29/16 17:43
Boron mg/kg ND 2.9 12/29/16 17:43
Calcium mg/kg ND 28.6 12/29/16 17:43
Chromium mg/kg ND 0.29 12/29/16 17:43
Copper mg/kg ND 0.29 12/29/16 17:43
Iron mg/kg ND 2.3 1g12/29/16 17:43
Magnesium mg/kg ND 28.6 12/29/16 17:43
Manganese mg/kg ND 0.29 12/29/16 17:43
Molybdenum mg/kg ND 0.57 12/29/16 17:43
Nickel mg/kg ND 0.29 12/29/16 17:43
Potassium mg/kg ND 57.3 12/29/16 17:43
Silver mg/kg ND 0.29 12/29/16 17:43
Sodium mg/kg ND 57.3 CU12/29/16 17:43
Strontium mg/kg ND 0.57 12/29/16 17:43
Zinc mg/kg ND 1.1 12/29/16 17:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1827664LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/kg 121118 103 80-120
Barium mg/kg 12.211.8 104 80-120
Beryllium mg/kg 1.11.2 97 80-120
Boron mg/kg 109118 93 80-120
Calcium mg/kg 602590 102 80-120
Chromium mg/kg 12.711.8 107 80-120
Copper mg/kg 12.111.8 102 80-120
Iron mg/kg 127118 107 80-120
Magnesium mg/kg 614590 104 80-120
Manganese mg/kg 12.611.8 107 80-120
Molybdenum mg/kg 12.411.8 105 80-120
Nickel mg/kg 12.711.8 107 80-120
Potassium mg/kg 605590 102 80-120
Silver mg/kg 1.21.2 99 80-120
Sodium mg/kg 601590 102 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 77
Page 87 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1827664LABORATORY CONTROL SAMPLE:
LCSSpike
Strontium mg/kg 12.211.8 104 80-120
Zinc mg/kg 58.759 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1827665MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322972001
1827666
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/kg M1,R1171147075-1253930 21 201641470017200 21200
Barium mg/kg M117.1 56 75-12597 6 2016.4103 112 119
Beryllium mg/kg R11.65 107 75-12579 23 201.650.64 2.5 1.9
Boron mg/kg M11716175-12561 3 2016412.4 116 112
Calcium mg/kg M1,R1852975-12594 38 2082014101480 2180
Chromium mg/kg 17.1 92 75-12587 5 2016.413.8 29.4 28.1
Copper mg/kg M117.1 52 75-12565 7 2016.417.1 26.0 27.8
Iron mg/kg M6171234075-1251180 9 201641960023600 21500
Magnesium mg/kg M1,R1852-37 75-12569 33 2082025302210 3090
Manganese mg/kg M117.1 -1510 75-125-1530 2 2016.4582 325 330
Molybdenum mg/kg M117.1 71 75-12571 4 2016.4ND 12.2 11.8
Nickel mg/kg M117.1 70 75-12586 9 2016.412.0 23.9 26.1
Potassium mg/kg M18528375-125135 19 2082011901900 2300
Silver mg/kg M11.65 12 75-12523 201.65ND .2J 0.38
Sodium mg/kg R18529375-125125 25 20820ND804 1040
Strontium mg/kg M1,R117.1 53 75-125103 23 2016.421.0 30.1 38.0
Zinc mg/kg 85.2 77 75-12590 8 208236.6 102 110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 77
Page 88 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
338970
EPA 3050
EPA 6020
6020 MET SOLID
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1818046
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Matrix: Solid
Analyzed
Antimony mg/kg ND 1.7 N212/19/16 17:08
Arsenic mg/kg ND 0.85 12/19/16 17:08
Cadmium mg/kg ND 0.10 12/19/16 17:08
Cobalt mg/kg ND 0.85 12/19/16 17:08
Lead mg/kg ND 0.85 12/19/16 17:08
Selenium mg/kg ND 0.85 12/19/16 17:08
Thallium mg/kg ND 0.85 12/19/16 17:08
Vanadium mg/kg ND 0.85 12/19/16 17:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1818047LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 28.0 N230.5 92 80-120
Arsenic mg/kg 27.430.5 90 80-120
Cadmium mg/kg 2.93.1 97 80-120
Cobalt mg/kg 31.030.5 102 80-120
Lead mg/kg 31.630.5 104 80-120
Selenium mg/kg 25.830.5 84 80-120
Thallium mg/kg 31.330.5 103 80-120
Vanadium mg/kg 31.230.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1818048MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35281740008
1818049
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg N2,R198.9 84 75-12582 25 2076.210.3 93.6 72.6
Arsenic mg/kg M6,R198.9 94 75-12562 39 2076.246.3 140 93.7
Cadmium mg/kg M6,R19.84 82 75-125445207.6213.3 21.5 13.6
Cobalt mg/kg R198.9 101 75-12590 29 2076.221.5 121 90.2
Lead mg/kg M6,R198.9 -546 75-125-2010 52 2076.22930 2390 1400
Selenium mg/kg R198.9 84 75-12587 22 2076.22.0U 84.2 67.8
Thallium mg/kg R198.9 103 75-125102 28 2076.22.0U 102 77.6
Vanadium mg/kg R198.9 96 75-12593 24 2076.215.6 110 86.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 77
Page 89 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342512
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35284533001
1837375SAMPLE DUPLICATE:
Percent Moisture %6.8 1 106.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35285907003
1837377SAMPLE DUPLICATE:
Percent Moisture %4.5 D641106.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35286060001
1837378SAMPLE DUPLICATE:
Percent Moisture %8.3 2 108.5
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35286060010
1837379SAMPLE DUPLICATE:
Percent Moisture %7.6 D618106.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35286130019
1837380SAMPLE DUPLICATE:
Percent Moisture %0.87 D638100.59
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35286473002
1837381SAMPLE DUPLICATE:
Percent Moisture %97.3 0 1097.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322972002
1837382SAMPLE DUPLICATE:
Percent Moisture %11.7 10 1010.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 77
Page 90 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322972011
1837383SAMPLE DUPLICATE:
Percent Moisture %9.5 1 109.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 77
Page 91 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342360
EPA 3060
EPA 7199
7199 Hexavelent Chromium Soil
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1836318
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Matrix: Solid
Analyzed
Chromium, Hexavalent mg/kg ND 0.65 01/06/17 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1836319LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/kg 39.839.7 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1836321MATRIX SPIKE SAMPLE:
MSSpike
Result
92320478001
Chromium, Hexavalent mg/kg 9.4 M144.1 21 75-125ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92320478001
1836320SAMPLE DUPLICATE:
Chromium, Hexavalent mg/kg ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 77
Page 92 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339228
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1820062
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Matrix: Solid
Analyzed
Chloride mg/kg ND 49.8 12/17/16 20:06
Sulfate mg/kg ND 49.8 12/17/16 20:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1820063LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/kg 468496 94 80-120
Sulfate mg/kg 459496 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1820066MATRIX SPIKE SAMPLE:
MSSpike
Result
92322972001
Chloride mg/kg 563591 92 80-120ND
Sulfate mg/kg 560591 90 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322972001
1820064SAMPLE DUPLICATE:
Chloride mg/kg ND 20ND
Sulfate mg/kg ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 77
Page 93 of 115
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92322972
J16120243
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339226
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1820053
Associated Lab Samples: 92322972001, 92322972002, 92322972003, 92322972004, 92322972005, 92322972006, 92322972007,
92322972008, 92322972009, 92322972010, 92322972011, 92322972012, 92322972013, 92322972014,
92322972015, 92322972016
Matrix: Solid
Analyzed
Nitrate as N mg/kg ND 5.0 12/17/16 20:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1820054LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrate as N mg/kg 45.449.6 91 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1820056MATRIX SPIKE SAMPLE:
MSSpike
Result
92322972001
Nitrate as N mg/kg 56.3 H359.1 95 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322972001
1820055SAMPLE DUPLICATE:
Nitrate as N mg/kg ND H320ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 77
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92322972
J16120243
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte was detected in theCCB. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.1g
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples.CU
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analysis conducted outside the EPA method holding time.H1
Extraction or preparation conducted outside EPA method holding time.H2
Sample was received or analysis requested beyond the recognized method holding time.H3
Analysis initiated outside of the 15 minute EPA required holding time.H6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold NELAC/TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 77
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92322972001 340581 3407132016039216EPA 3050 EPA 6010
92322972002 340581 3407132016039218EPA 3050 EPA 6010
92322972003 340581 3407132016039219EPA 3050 EPA 6010
92322972004 340581 3407132016039221EPA 3050 EPA 6010
92322972005 340581 3407132016039222EPA 3050 EPA 6010
92322972006 340581 3407132016039224EPA 3050 EPA 6010
92322972007 340581 3407132016039225EPA 3050 EPA 6010
92322972008 340581 3407132016039227EPA 3050 EPA 6010
92322972009 340581 3407132016039228EPA 3050 EPA 6010
92322972010 340581 3407132016039230EPA 3050 EPA 6010
92322972011 340581 3407132016039231EPA 3050 EPA 6010
92322972012 340581 3407132016039232EPA 3050 EPA 6010
92322972013 340581 3407132016039233EPA 3050 EPA 6010
92322972014 340581 3407132016039235EPA 3050 EPA 6010
92322972015 340581 3407132016039236EPA 3050 EPA 6010
92322972016 340581 3407132016039238EPA 3050 EPA 6010
92322972001 338970 3391682016039216EPA 3050 EPA 6020
92322972002 338970 3391682016039218EPA 3050 EPA 6020
92322972003 338970 3391682016039219EPA 3050 EPA 6020
92322972004 338970 3391682016039221EPA 3050 EPA 6020
92322972005 338970 3391682016039222EPA 3050 EPA 6020
92322972006 338970 3391682016039224EPA 3050 EPA 6020
92322972007 338970 3391682016039225EPA 3050 EPA 6020
92322972008 338970 3391682016039227EPA 3050 EPA 6020
92322972009 338970 3391682016039228EPA 3050 EPA 6020
92322972010 338970 3391682016039230EPA 3050 EPA 6020
92322972011 338970 3391682016039231EPA 3050 EPA 6020
92322972012 338970 3391682016039232EPA 3050 EPA 6020
92322972013 338970 3391682016039233EPA 3050 EPA 6020
92322972014 338970 3391682016039235EPA 3050 EPA 6020
92322972015 338970 3391682016039236EPA 3050 EPA 6020
92322972016 338970 3391682016039238EPA 3050 EPA 6020
92322972001 342500 3426432016039216EPA 7471 EPA 7471
92322972002 342500 3426432016039218EPA 7471 EPA 7471
92322972003 342500 3426432016039219EPA 7471 EPA 7471
92322972004 342500 3426432016039221EPA 7471 EPA 7471
92322972005 341974 3421562016039222EPA 7471 EPA 7471
92322972006 341974 3421562016039224EPA 7471 EPA 7471
92322972007 341974 3421562016039225EPA 7471 EPA 7471
92322972008 341974 3421562016039227EPA 7471 EPA 7471
92322972009 340032 3401232016039228EPA 7471 EPA 7471
92322972010 340032 3401232016039230EPA 7471 EPA 7471
92322972011 340032 3401232016039231EPA 7471 EPA 7471
92322972012 341974 3421562016039232EPA 7471 EPA 7471
92322972013 341974 3421562016039233EPA 7471 EPA 7471
92322972014 342500 3426432016039235EPA 7471 EPA 7471
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 77
Page 96 of 115
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92322972015 342500 3426432016039236EPA 7471 EPA 7471
92322972016 342500 3426432016039238EPA 7471 EPA 7471
92322972001 3425122016039216ASTM D2974-87
92322972002 3425122016039218ASTM D2974-87
92322972003 3425122016039219ASTM D2974-87
92322972004 3425122016039221ASTM D2974-87
92322972005 3425122016039222ASTM D2974-87
92322972006 3425122016039224ASTM D2974-87
92322972007 3425122016039225ASTM D2974-87
92322972008 3425122016039227ASTM D2974-87
92322972009 3425122016039228ASTM D2974-87
92322972010 3425122016039230ASTM D2974-87
92322972011 3425122016039231ASTM D2974-87
92322972012 3425122016039232ASTM D2974-87
92322972013 3425122016039233ASTM D2974-87
92322972014 3425122016039235ASTM D2974-87
92322972015 3425122016039236ASTM D2974-87
92322972016 3425122016039238ASTM D2974-87
92322972001 3395192016039216EPA 9045
92322972002 3395192016039218EPA 9045
92322972003 3395192016039219EPA 9045
92322972004 3395192016039221EPA 9045
92322972005 3395192016039222EPA 9045
92322972006 3395192016039224EPA 9045
92322972007 3395192016039225EPA 9045
92322972008 3395192016039227EPA 9045
92322972009 3395192016039228EPA 9045
92322972010 3395192016039230EPA 9045
92322972011 3395192016039231EPA 9045
92322972012 3395192016039232EPA 9045
92322972013 3395192016039233EPA 9045
92322972014 3395192016039235EPA 9045
92322972015 3395192016039236EPA 9045
92322972016 3395192016039238EPA 9045
92322972001 342360 3429412016039216EPA 3060 EPA 7199
92322972002 342360 3429412016039218EPA 3060 EPA 7199
92322972003 342360 3429412016039219EPA 3060 EPA 7199
92322972004 342360 3429412016039221EPA 3060 EPA 7199
92322972005 342360 3429412016039222EPA 3060 EPA 7199
92322972006 342360 3429412016039224EPA 3060 EPA 7199
92322972007 342360 3429412016039225EPA 3060 EPA 7199
92322972008 342360 3429412016039227EPA 3060 EPA 7199
92322972009 342360 3429412016039228EPA 3060 EPA 7199
92322972010 342360 3429412016039230EPA 3060 EPA 7199
92322972011 342360 3429412016039231EPA 3060 EPA 7199
92322972012 342360 3429412016039232EPA 3060 EPA 7199
92322972013 342360 3429412016039233EPA 3060 EPA 7199
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 77
Page 97 of 115
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92322972
J16120243
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92322972014 342360 3429412016039235EPA 3060 EPA 7199
92322972015 342360 3429412016039236EPA 3060 EPA 7199
92322972016 342360 3429412016039238EPA 3060 EPA 7199
92322972001 3392282016039216EPA 9056
92322972002 3392282016039218EPA 9056
92322972003 3392282016039219EPA 9056
92322972004 3392282016039221EPA 9056
92322972005 3392282016039222EPA 9056
92322972006 3392282016039224EPA 9056
92322972007 3392282016039225EPA 9056
92322972008 3392282016039227EPA 9056
92322972009 3392282016039228EPA 9056
92322972010 3392282016039230EPA 9056
92322972011 3392282016039231EPA 9056
92322972012 3392282016039232EPA 9056
92322972013 3392282016039233EPA 9056
92322972014 3392282016039235EPA 9056
92322972015 3392282016039236EPA 9056
92322972016 3392282016039238EPA 9056
92322972001 3392262016039216EPA 9056
92322972002 3392262016039218EPA 9056
92322972003 3392262016039219EPA 9056
92322972004 3392262016039221EPA 9056
92322972005 3392262016039222EPA 9056
92322972006 3392262016039224EPA 9056
92322972007 3392262016039225EPA 9056
92322972008 3392262016039227EPA 9056
92322972009 3392262016039228EPA 9056
92322972010 3392262016039230EPA 9056
92322972011 3392262016039231EPA 9056
92322972012 3392262016039232EPA 9056
92322972013 3392262016039233EPA 9056
92322972014 3392262016039235EPA 9056
92322972015 3392262016039236EPA 9056
92322972016 3392262016039238EPA 9056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/10/2017 01:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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