Cenco GW File Docket-OCR

•
Mr. Peter L. Doorn, Hydrogeologist
February 18, 1994
Page 2
•
b. Turbidity will be measured in the field following completion of purging.
c. Samples which will be analyzed for volatile organic compounds will be collected no
later than 2 hours after completion of the well purging.
d. Samples which will be analyzed for metals will be collected no later than 24 hours
after completion of the well purging. Field filtered and unfiltered samples will be
collected and analyzed.
Based upon your conversation with the undersigned on February 9, 1994, these
recommended changes to the Sampling and Analysis Plan will be implemented commencing
with the February 1994 round of samples.
4. Laboratory analytical data sheets for the ground water monitoring performed in June 1993
and October 1993 are attached.
Please advise if this letter requires additional clarification. Do not hesitate to contact the
undersigned if we can provide additional information or assistance.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
-~LN~
Terry L. Norman
Project Engineer
TLN:dmh
cc: G. Rest
G. Swenson
A. J. Ramsey
G. Simpson
M. Fleischaker, Esquire
O'BRIEN & GERE ENGINEERS
Client Name:
Client ID:
Lab IO: Matrix:
Parameter
Chloromethane
Bromomethane
O'Brien & Gere
MW-6 031220-0001-SA
AQUEOUS
Vinyl Chloride
Chloroethane Methylene chloride
Acetone Carbon disulfide 1,1-Dichloroethene
1,1-Dichloroethane
1,2-Dichloroethene (cis/
trans) Chloroform
1,2-Dichloroethane
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Vinyl Acetate Bromodichloromethane
1,2-Dichloropropane trans-1,3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1,2-Trichloroethane
Benzene
cis-J,3-Dichloropropene
Bromoform
4-Methyl-2-Pentanone
2-Hexanone
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene Chlorobenzene
Ethyl benzene
Styrene
Xylenes (total)
NA -Not Applicable
ND -Not Detected
Reported By: Ann Liang
TCL Volatile Organics
Method 8240
Engineers, Inc.
Sampled: 27 OCT g3
Received: 29 OCT 93
Authorized: 02 NOV 93
Result Units
ND ug/L
ND ug/l
ND ug/L
ND ug/L
ND ug/L
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/l
ND ug/L
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/l
ND ug/L
ND ug/L
Prepared: NA
Analyzed: 10 NOV 93
Reporting
Limit
10
10
10
10
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0 10
5.0
5.0
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
10
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Enseco
A c,,!'tin'I~ Cump.:m~
Approved By: Martha Sullivan
. -,., o n o o o z
' I
Client Name:
Client ID:
Lab ID: Matrix:
Surrogate
O'Brien & Gere
MW-6 031220-0001-SA
AQUEOUS
Toluene-dB
4-Bromofluorobenzene
l,2-Dichloroethane-d4
NA~ Not Applicable
Reported By: Ann Liang
TCL Volatile Organics
Method B240 (cont.) Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Recovery
100
105
110
%
%
%
Prepared: NA
Analyzed: 10 NOV 93
Enseco
A Comm11: c.._..mp1m;
Approved By: Martha Sullivan
""" 003
• Ii I· Enseco
A Lummii: (~1mpdlm
TCL Volatile Organics
Method 8240
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-7
lab ID: 031220-0002-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Prepared: NA
Authorized: 02 NOV 93 Analyzed: 10 NOV 93
Reporting
' Parameter Result Units Limit
Chloromethane ND ug/L 10
Bromomethane ND ug/L 10
Vinyl Chloride 22 ug/L 10
Chloroethane 15 ug/L 10
Methylene chloride ND ug/L 5.0
Acetone 79 ug/L 10
Carbon disulfide ND ug/L 5.0
1,1-Dichloroethene ND ug/L 5.0
1,1-Dichloroethane 3.9 ug/L 5.0 J
1,2-Dichloroethene (cis/
trans) 68 ug/L 5.0
Chloroform ND ug/L 5.0
1,2-Dichloroethane ND ug/L 5.0
2-Butanone ND ug/L 10
1,1,1-Trichloroethane ND ug/L 5.0
Carbon tetrachloride ND ug/L 5.0
Vinyl Acetate ND ug/L 10
Bromodichloromethane ND ug/L 5.0
1,2-Dichloropropane ND ug/L 5.0
trans-1,3-Dichloropropene ND ug/L 5.0
Trichloroethene 1.6 ug/L 5.0 J
Dibromochloromethane NO ug/L 5.0
1,1,2-Trichloroethane NO ug/L 5.0
Benzene 240 ug/L 10 D
cis-1,3-Dichloropropene NO ug/L 5.0
Bromoform ND ug/L 5.0
4-Methyl-2-Pentanone 4.5 ug/L 10 J
2-Hexanone ND ug/L 10
1,1,2,2-Tetrachloroethane ND ug/L 5.0
Tetrachloroethene ND ug/L 5.0
Toluene 22 ug/L 5.0
Chlorobenzene 28 ug/L 5.0
Ethyl benzene 250 ug/L 10 D
Styrene ND ug/L 5.0
D ~ Compound quantitated using a secondary dilution.
J ~ Result is detected below the reporting limit or is an estimated concentration.
NA -Not Applicable
ND -Not Detected
Reported By: Salman Qazi Approved By: Ann Liang
"'1rifQ04
• TCL Volatile Organics
Method 8240
(cont.}
I Enseco
A C0rT11n)!; Comp.mi'
Client Name: O'Brien & Gere Engineers, Inc.
Client ID:
Lab ID:
Matrix:
Parameter
MW-7
031220-0002-SA
AQUEOUS
Xylenes (total}
Surrogate
Toluene-dB
4-Bromofluorobenzene
l,2-Dichloroethane-d4
NA -Not Applicable
Reported By: Salman Qazi
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Result Units
5.2 ug/L
Recovery
100 %
102 %
97 %
Prepared: NA Analyzed: 10 NOV 93
Reporting
Limit
5.0
Approved By: Ann Liang
""'10005
Client Name:
Client IO:
Lab IO:
Matrix:
Parameter
O'Brien & Gere
MW-8
031220-0003-SA
AQUEOUS
Xylenes' (total)
Surrogate
Toluene-dB
4-Bromofluorobenzene l,2-Dichloroethane-d4
NA -Not Applicable
ND -Not Detected
Reported By: Salman Qazi
TCL Volatile Organics
Method 8240
(cont.) Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93 Authorized: 02 NOV 93
Result Units
ND ug/L
Recovery
99 %
101 %
102 %
Prepared: NA
Analyzed: 10 NOV 93
Reporting
Limit
10
Enseco
A Ci>m1n,,r. C1.1111~l'!\
Approved By: Ann Liang
"~~roo7
•
Client Name:
Client ID:
Lab ID:
Matrix:
O'Brien & Gere
MW-16
031220-0008-SA
AQUEOUS
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1,1-Dichloroethene
1,1-Dichloroethane
1,2-Dichloroethene (cis/
trans)
Chloroform
1,2-Dichloroethane
2-Butanone 1,1,1-Trichloroethane Carbon tetrachloride
Vinyl Acetate
Bromodichloromethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Dibromochloromethane
1,1,2-Trichloroethane
Benzene cis-1,3-Dichloropropene
Bromoform
4-Methyl-2-Pentanone
2-Hexanone 1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene Chlorobenzene
Ethyl benzene
Styrene
Xyl en es (total)
NA n Not Applicable
ND ~ Not Detected
Reported By: Ann Liang
TCL Volatile Organics
Method 8240
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Result Units
NO ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
NO ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/l
ND ug/l
ND ug/l
ND ug/L
ND ug/L
ND ug/l
ND ug/L
ND ug/L
I
Prepared: NA
Analyzed: 10 NOV 93
Reporting
Limit
10
10
10
10
5.0
10
5.0
5.0
5.0
5.0
5.0 s.o
10
5.0
5.0
10
5.0
5.0
5.0 5.0
5.0
5.0
5.0
5.0
5.0
10
10
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Enseco
A Comm!: Comp.an1.
Approved By: Martha Sullivan
!'"'" ('16
• I Enseet)
TCL Semivolatile Organics
•\ ~ ,'l'!\11"11'. \ "m~.111,
Method 8270
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-6
Lab ID: 031220-0001-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Prepared: 03 NOV 93
Authorized: 02 NOV 93 Analyzed: 12 NOV 93
Reporting
Parameter Result Units Limit
Phenol · 12 ug/l 10
bis(2-Chloroethyl) ether ND ug/L IO
2-Chloro~henol ND ug/L 10
1,3-0ich orobenzene NO ug/L 10
1,4-Dichlorobenzene ND ug/L 10
1,2-Dichlorobenzene NO ug/L 10
2-Methyl~henol ND ug/L 10
bis(2-Ch oroisopropyl)
ether ND ug/L 10
4-Methylphenol ND ug/l 10
N-Nitroso-di-n-
propylamine ND Ug/l 10
Hexachloroethane ND ug/L 10
Nitrobenzene ND ug/l 10
Isophorone ND ug/L 10
2-Nitrophenol ND ug/L 10
2,4-0imethylphenol NO ug/L 10
bis(2-Chloroethoxy)-
methane ND ug/L 10
2,4-Dichlorophenol ND ug/L 10
1,2,4-Trichlorobenzene NO ug/L 10
Naphthalene ND ug/L 10
4-Chloroaniline ND ug/l 10
Hexachlorobutadiene ND ug/L 10
4-Chloro-3-methylphenol ND ug/L 10
2-Methylnaphthalene ND ug/L 10
Hexachlorocyclo-
pentadiene ND ug/L 10
2,4,6-Trichlorophenol ND ug/L 10
2,4,5-Trichlorophenol ND ug/L 50
2-Chlorona~hthalene ND ug/L 10
2-Nitroani ine ND ug/L 50
Dimethyl phthalate ND ug/L 10
Acenaphthylene ND ug/l IO
3-Nitroani 1 ine ND ug/L 50
Acenaphthene ND ug/L · 10
2,4-Dinitrophenol ND ug/L 50
ND ~ Not Detected
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
r34
Client Name:
Client ID:
Lab ID:
Matrix:
O'Brien & Gere
MW-6
031220-0001-SA
AQUEOUS
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-dS
2-Fl uorophenol
2,4,6-Tribromophenol
Reported By: Leonard Oikun
TCL Semivolatile Organics
Method 8270
(cont.) Engineers, Inc.
Sampled: 27 OCT g3
Received: 29 OCT 93
Authorized: 02 NOV 93
Recovery
64 %
58 % SS %
51 % 50 %
59 %
Prepared: 03 NOV 93
Analyzed: 12 NOV 93
Ensecc)
Approved By: Lori Ann Quinn
-"~0036
~----
• I .•. Ense(()
•\ 1. "''1'ni; ~ ,1mr-.u1>
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere
(cont.)
Engineers, Inc.
Client ID: MW-7
Lab ID: 031220-0002-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Prepared: 03 NOV 93
Authorized: 02 NOV 93 Analyzed: 12 NOV 93
Reporting
Parameter Result Units Limit
Acenaphthene ND ug/L 10
2,4-Dinitrophenol ND ug/L 50
4-Nitrophenol 4.7 ug/L 50 J
Dibenzofuran ND ug/L 10
2,4-Dinitrotoluene ND ug/L 10
2,6-Dinitrotoluene ND ug/L 10
Diethyl phthalate ND ug/L 10
4-Chlorophenyl phenyl
ether ND ug/L 10
Fluorene ND ug/L 10
4-Nitroanil ine ND ug/L 50
4,6-Dinitro-2-50 methyl phenol ND ug/L
N-Nitrosodiphenylamine ND ug/L 10
4-Bromophenyl phenyl 10 ether ND ug/L
Hexachlorobenzene NO ug/L 10
Pentachlorophenol ND ug/L 50
Phenanthrene NO ug/L 10
Anthracene NO ug/L 10
Di-n-butyl phthalate ND ug/L 10
Fluoranthene ND ug/L 10
Pyrene ND ug/L 10
Butyl benzyl phthalate ND ug/L 10
3,3'-Dichlorobenzidine ND ug/L 20
Benzo(a)anthracene ND ug/L 10
bis(2-Ethylhexyl)
phthalate 1.0 ug/L 10 BJ
Chrysene ND ug/L 10
Di-n-octyl phthalate ND ug/L 10
Benzo(b)fluoranthene ND ug/L 10
Benzo(k)fluoranthene ND ug/L 10
Benzo(a)pyrene ND ug/l 10
Indeno(l,2,3-cd)pyrene NO ug/l 10
Dibenz(a,h)anthracene ND ug/L 10
B ~ Compound is also detected in the blank.
J ~ Result is detected below the reporting limit or is an estimated concentration.
ND ~ Not Detected
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
0038
En._o;eco
·\ I. ,"r.'11n\! \ .'Tll!\lll\
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-9
Lab ID: 031220-0004-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Pre)ared: 03 NOV 93
Authorized: 02 NOV 93 Ana yzed: 12 NOV 93
Reporting
Parameter Result Units Limit
Phenol 7.9 ug/L 10 J
bis(2-Chloroethyl) ether NO ug/L 10
2-Chloro)henol NO ug/L 10
1,3-0ich orobenzene ND ug/L 10
1,4-0ichlorobenzene ND ug/L 10
1,2-Dichlorobenzene ND ug/L 10
2-Methyl)henol ND ug/L 10
bis(2-Ch oroisopropyl)
ether ND ug/L 10
4-Methylphenol ND ug/L 10
N-Nitroso-di-n-propylamine ND ug/l 10
Hexachloroethane ND ug/l 10
Nitrobenzene ND ug/L 10
Isophorone ND ug/L 10
2-Nitrophenol ND ug/l 10
2,4-Dimethylphenol ND ug/l 10
bis(2-Chloroethoxy)-
methane NO ug/L 10
2,4-Dichlorophenol ND ug/L 10
1,2,4-Trichlorobenzene ND ug/L 10
Naphthalene ND ug/L 10
4-Chloroaniline ND ug/L 10
Hexachlorobutadiene ND ug/L 10
4-Chloro-3-methylphenol ND ug/L 10
2-Methylnaphthalene ND ug/L 10
Hexachlorocyclo-
pentadiene ND ug/L 10
2,4,6-Trichlorophenol ND ug/L 10
2,4,5-Trichlorophenol ND ug/l 50
2-Chlorona)hthalene ND ug/L 10
2-Nitroani ine ND ug/L 50
Dimethyl phthalate ND ug/L 10
Acenaphthylene ND ug/L 10
3-Nitroaniline ND ug/l 50
Acenaphthene ND ug/L 10
J ~Result is detected below the reporting limit or is an estimated concentration.
ND ~ Not Detected
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
0043
I I Ensel'ci
\ \, • rn•r'..; I "t'r'11',\!>1
TCL Semivolatile Organics
Method 8270
(cont.)
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-9
Lab ID: 031220-0004-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Pre~ared: 03 NOV 93
Authorized: 02 NOV 93 Ana yzed: 12 NOV 93
Parameter Result Units
Reporting
Limit
2,4-Din1trophenol ND ug/L 50
4-Nitrophenol ND ug/L 50
Dibenzofuran ND ug/L 10
2,4-Dinitrotoluene ND ug/L 10
2,6-Dinitrotoluene ND ug/L 10
Diethyl phthalate ND ug/L 10
4-Chlorophenyl phenyl
ether ND ug/L 10
Fluorene ND ug/L 10
4-Nitroan i 1 i ne ND ug/L 50
4,6-Dinitro-2-
methyl phenol ND ug/L 50
N-Nitrosodiphenylamine ND ug/L 10
4-Bromophenyl phenyl
ether ND ug/L 10
Hexachlorobenzene ND ug/L 10
Pentachlorophenol ND ug/L SD
Phenanthrene ND ug/L 10
Anthracene ND ug/L 10
Di-n-butyl phthalate ND ug/L 10
Fluoranthene ND ug/L 10
Pyrene ND ug/l 10
Butyl benzyl ghthalate ND ug/L 10
3,3'-Dichloro enzidine ND ug/L 20
Benzo(a)anthracene ND ug/L 10
bis(2-Ethylhexyl)
phthalate ND ug/l 10
Chrysene ND ug/l 10
Di-n-octyl phthalate ND ug/l 10
Benzo(b)fluoranthene ND ug/L 10
Benzo(k)fluoranthene ND ug/L 10
Benzo(a)pyrene ND ug/L 10
lndeno(!,2,3-cd)pyrene ND ug/L 10
Dibenz(a,h)anthracene ND ug/L 10
Benzo(g,h,i)perylene ND ug/L 10
ND ~ Not Detected
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
"0(0044
·----------·,.......----Enseco
A C.1rrnnii; l'.;omp.i:n\
Client Name:
Client ID:
Lab ID:
Matrix:
O'Brien & Gere
MW-9
031220-0004-SA
AQUEOUS
Surrogate
Nitrobenzene-d5
2-Fluorbbiphenyl
Terphenyl-d14
Phenol-d5 2-Fl uorophenol 2,4,6-Tribromophenol
Reported By: Leonard Dikun
TCL Semivolatile Organics
Method 8270
(cont.) Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Recovery
59 %
54 % 80 % 37 %
35 %
47 %
Prepared: 03 NOV 93
Analyzed: 12 NOV 93
Approved By: Lori Ann Quinn
I' '' ··. 0 0 4 c ., .._) .1 J
Client Name:
Client ID:
Lab ID: Matrix:
Parameter
O'Brien & Gere
MW-10 031220-0005-SA AQUEOUS
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate 4-Chlorophenyl phenyl
ether Fluorene
4-Nitroanil ine
4,6-Dinitro-2-
methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl
ether
Hexachlorobenzene Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(Z-Ethylhexyl)
phthalate
Chrysene Di-n-octyl phthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
Nitrobenzene-dS
ND ~ Not Detected
Reported By: Hina R. Patel
TCL Semivolatile Organics
Method 8270
(cont.)
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93 Authorized: 02 NOV 93
Result Units
ND ug/L
ND ug/L
ND ug/L
ND ug/l
NO ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/l
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/l
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
Recovery
60 %
Prepared: 03 NOV 93
Analyzed: 13 NOV 93
Reporting
Limit
50
10
10
10
10
10 10
50
50
10
10
10 50
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
10
Approved By: Lori Ann Quinn
Enseco
. .\ Conim~ Comp.:in1
0047
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-13
Lab ID: 031220-0006-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93
Authorized: 02 NOV 93
Parameter Result Units
Phenol 280 ug/l
bis(2-Chloroethyl) ether ND ug/L
2-Chloro~henol ND ug/L
1,3-Dich orobenzene ND ug/L
1,4-Dichlorobenzene ND ug/L
1,2-Dichlorobenzene ND ug/L
2-Methyl~henol ND ug/L
bis(2-Ch oroisopropyl)
ether ND ug/L
4-Methylphenol ND ug/L
N-Nitroso-di-n-
propylamine ND ug/L
Hexachloroethane ND ug/L
Nitrobenzene ND ug/L
Isophorone ND ug/l
2-Nitropheno l ND ug/L
2,4-Dimethylphenol ND ug/L
bis(2-Chloroethoxy)-
methane ND ug/l
2,4-Dichlorophenol ND ug/L
1,2,4-Trichlorobenzene ND ug/L
Naphthalene ND ug/L
4-Chloroaniline ND ug/l
Hexachlorobutadiene ND ug/L
4-Chloro-3-methylphenol ND ug/L
2-Methylnaphthalene ND ug/L
Hexachlorocyclo-
pentadiene ND ug/L
2,4,6-Trichlorophenol ND ug/L
2,4,5-Trichlorophenol ND ug/L
2-Chlorona~hthalene ND ug/L
2-Nitroani ine ND ug/l
Dimethyl phthalate ND ug/L
Acenaphthylene ND ug/L
3-Nitroaniline ND ug/L
Acenaphthene ND ug/L
0 ~ Compound quantitated using a secondary dilution.
NO = Not Detected
Enseco
A (._,mm!>': (Otl'lp.!TI\
Pre~ared: 03 NOV 93 Ana yzed: 12 NOV 93
Reporting
Limit
20 D
10
10
10
10
10
10
10
10
10 10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
50
10 50
10
10
50
10
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
---' (' 4 9
.. -------
Enseco
A C.imtn!l (~lrf\r><l!'l\
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere
(cont.) Engineers, Inc.
Client IO: MW-15
Lab IO: 031220-0007-SA Sampled: 27 OCT g3
Matrix: AQUEOUS Received: 29 OCT 93 Pre~ared: 03 NOV 93
Authorized: 02 NOV 93 Ana yzed: 12 NOV 93
Reporting
Parameter Result Units Limit
4-Nitrophenol NO ug/L 50
Di benzofuran ND ug/L 10
2,4-Dinitrotoluene ND ug/L 10
2,6-Dinitrotoluene ND ug/L 10
Diethyl phthalate ND ug/L 10
4-Chlorophenyl phenyl
ether ND ug/L 10
Fluorene ND ug/L 10
4-Nitroanil ine ND ug/L so
4,6-Dinitro-2-
methyl phenol ND ug/L 50
N-Nitrosodiphenylamine ND ug/L 10
4-Bromophenyl phenyl 10 ether ND ug/L
Hexachlorobenzene ND ug/L 10
Pentachlorophenol NO ug/L 50
Phenanthrene ND ug/L 10
Anthracene ND ug/L 10
Di-n-butyl phthalate ND ug/L 10
Fluoranthene ND ug/L 10
Pyrene ND ug/L 10
Butyl benzyl phthalate ND ug/L 10
3,3'-Dichlorobenzidine ND ug/L 20
Benzo(a)anthracene ND ug/L 10
bis(2-Ethylhexyl)
phthalate 1.1 ug/L 10 BJ
Chrysene ND ug/L 10
Di-n-octyl phthalate ND ug/L 10
Benzo(b)fluoranthene ND ug/L 10
Benzo(k)fluoranthene ND ug/L 10
Benzo(a)pyrene ND ug/L 10
Indeno(l,2,3-cd)pyrene ND ug/L 10
Dibenz(a,h)anthracene ND ug/L 10
Benzo(g,h,i)perylene ND ug/l 10
B -Compound is also detected in the blank.
J -Result is detected below the reporting limit or is an estimated concentration.
ND -Not Detected
Reported By: Leonard Dikun Approved By: Lori Ann Quinn
'"'0('53
Client Name:
Client ID:
Lab ID:
Matrix:
Surrogate
O'Brien & Gere
MW-16 031220-0008-SA
AQUEOUS
Nitrobenzene-dS
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-dS
2-Fluorophenol
2,4,6-Tribromophenol
Reported By: Leonard Dikun
TCL Semivolatile Organics
Method 8270
(cont.)
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Recovery
63 %
60 %
87 %
49 %
54 %
69 %
Approved By:
Prepared: 03 NOV 93
Analyzed: 12 NOV 93
Lori Ann Quinn
Enseco
A (L\mtn~ (um~tn
'0057
I I Enseco
A (1\m11'1~ Comp.u11
Client Name:
Client ID:
Lab ID:
Matrix:
Surrogate
O'Brien & Gere
MW-17
031220-000g-sA
AQUEOUS
2-Fluorbbiphenyl
Terphenyl-d14
Phenol-dS
2-Fluorophenol
2,4,6-Tribromophenol
Reported By: Hina R. Patel
TCL Semivolatile Organics
Method 8270
(cont.)
Engineers, Inc.
Sampled: 27 OCT g3
Received: 29 OCT g3
Authorized: 02 NOV g3
Recovery
64 %
25 %
53 %
57 %
65 %
Approved By:
Prepared: 03 NOV g3
Analyzed: 13 NOV g3
Lori Ann Quinn
"~1~0060
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-lB
Lab ID: 031220-0010-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93
Authorized: 02 NOV 93
Parameter Result Units
Phenol 650 ug/L
bis(2-Chloroethyl) ether ND ug/L
2-Chlorophenol ND ug/L
1,3-Dichlorobenzene ND ug/L
1,4-Dichlorobenzene ND ug/L
1,2-Dichlorobenzene ND ug/L
2-Methyllhenol ND ug/L
bis(2-Ch oroisopropyl)
ether ND ug/L
4-Methylphenol ND ug/L
N-Nitroso-di-n-
propylamine ND ug/L
Hexachloroethane ND ug/l
Nitrobenzene ND ug/L
Isophorone ND ug/L
2-Nitropheno 1 ND ug/L
2,4-Dimethylphenol ND ug/L
bis(2-Chloroethoxy)-
methane ND ug/L
2,4-Dichlorophenol ND ug/L
1,2,4-Trichlorobenzene ND ug/L
Naphthalene NO ug/L
4-Chloroaniline ND ug/L
Hexachlorobutadiene ND ug/l
4-Chloro-3-methylphenol ND ug/l
2-Methylnaphthalene ND ug/l
Hexachlorocyclo-
pentadiene ND ug/L
2,4,6-Trichlorophenol ND ug/L
2,4,5-Trichlorophenol ND ug/L
2-Chlorona~hthalene ND ug/L
2-Nitroani ine ND ug/L
Dimethyl phthalate ND ug/L
Acenaphthylene ND ug/L
3-Nitroaniline ND ug/L
Acenaphthene ND ug/L
D ~ Compound quantitated using a secondary dilution.
ND ~ Not Detected
Pre~ared: 03 NOV 93
Ana yzed: 13 NOV 93
Reporting
Limit
50 D
10
10
10
10
10 10
10
10
10
10
10
10
10
10
10 10
10
10
10
10
10
10
10
10
50
10
50
10
10
50
10
Reported By: Hina R. Patel Approved By: Lori Ann Quinn
Enseco
A Comm~ (~•mp.in\
OOG1
Enseco
TCL Semivolatile Organics A (,1mm~ C1.1mp.in1
Method 8270
{cont.)
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-18
Lab ID: 031220-0010-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Pre~ared: 03 NOV 93
Authorized: 02 NOV 93 Ana yzed: 13 NOV 93
Reporting
Parameter Result Units Limit
2,4-Din~trophenol ND ug/L 50
4-Nit ropheno 1 ND ug/l 50
Dibenzofuran ND ug/l 10
2,4-Dinitrotoluene ND ug/L 10
2,6-Dinitrotoluene ND ug/L 10
Diethyl phthalate ND ug/l 10
4-Chlorophenyl phenyl
ether ND ug/l 10
Fluorene ND ug/L 10
4-Nitroaniline ND ug/L 50
4, 6-Di nitro-2-
methyl phenol ND ug/L 50
N-Nitrosodiphenylamine NO ug/L 10
4-Bromophenyl phenyl NO ug/L 10 ether
Hexachlorobenzene ND ug/L 10
Pentachlorophenol ND ug/L 50
Phenanthrene NO ug/L 10
Anthracene ND ug/l 10
Di-n-butyl phthalate ND ug/l 10
Fluoranthene , ND ug/L 10
Pyrene ND ug/L 10
Butyl benzyl ~hthalate NO ug/L 10
3,3'-Dichloro enzidine ND ug/L 20
Benzo(a)anthracene ND ug/l 10
bis{2-Ethylhexyl)
phthalate 2.3 ug/l 10 BJ
Chrysene ND ug/L 10
Di-n-octyl phthalate NO ug/L 10
Benzo{b)fluoranthene ND ug/L 10
Benzo(k)fluoranthene ND ug/L 10
Benzo{a)pyrene ND ug/l 10
lndeno(l,2,3-cd)pyrene ND ug/l 10
Dibenz{a,h)anthracene ND ug/l 10
Benzo(g,h,i)perylene ND ug/L 10
B = Compound is also detected in the blank.
J -Result is detected below the reporting limit or is an estimated concentration.
ND = Not Detected
Reported By: Hina R. Patel Approved By: Lori Ann Quinn
QU62
~~~~----.ii 1~~~ Enseco
A (01'1'11l'l~ l'.:mnJ.'l<!n\
Client Name:
Client ID:
Lab ID:
Matrix:
Surrogate
O'Brien & Gere
MW-18
031220-0010-SA
AQUEOUS
Nitrobenzene-dS
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Reported By: Hina R. Patel
TCL Semivolatile Organics
Method 8270
(cont.)
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT g3
Authorized: 02 NOV 93
Recovery
70 % 63 %
53 %
56 %
64 %
71 %
Approved By:
Prepared: 03 NOV 93
Analyzed: 13 NOV 93
Lori Ann Quinn
COG3
Enseco
A C::ommji: C:oml'<ln\
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: BLANK
Lab ID: 031220-0011-FB Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Pre~ared: 03 NOV 93
Authorized: 02 NOV 93 Ana yzed: 13 NOV 93
Reporting
Parameter Result Units Limit
Phenol ND ug/L 10
bis(2-Chloroethyl) ether ND ug/L 10
2-Chlorophenol ND ug/L 10
1,3-0ichlorobenzene ND ug/L 10
1,4-Dichlorobenzene ND ug/L 10
1,2-Dichlorobenzene ND ug/L IO
2-Methyl ~he no l ND ug/L IO
bis(2-Ch oroisopropyl)
ether ND ug/L 10
4-Methylphenol ND ug/L 10
N-Nitroso-di-n-
propylamine ND ug/L 10
Hexachloroethane ND ug/L IO
Nitrobenzene ND ug/L IO
Isophorone ND ug/L IO
2-Nitrophenol ND ug/L IO
2,4-0imethylphenol ND ug/L 10
bis(2-Chloroethoxy)-
methane ND ug/L 10
2,4-Dichlorophenol ND ug/L JO
1,2,4-Trichlorobenzene ND ug/L 10
Naphthalene 3.7 ug/L IO J
4-Chloroaniline ND ug/L IO
Hexachlorobutadiene ND ug/L 10
4-Chloro-3-methylphenol ND ug/L IO
2-Methylnaphthalene ND ug/L IO
Hexachlorocyclo-
pentadiene NO ug/L IO
2,4,6-Trichlorophenol ND ug/L IO
2,4,5-Trichlorophenol ND ug/L 50
2-Chlorona~hthalene ND ug/l 10
2-Nitroani ine NO ug/L 50
Dimethyl phthalate ND ug/L 10
Acenaphthylene ND ug/L 10
3-Nitroani 1 ine ND ug/L 50
Acenaphthene ND ug/L 10
J ~ Result is detected below the reporting limit or is an estimated concentration.
ND ~ Not Detected
Reported By: Hina R. Patel Approved By: Lori Ann Quinn
·rir1 64
I I Enseco
A Co.Jmmi:. C0mp.m1
TCL Semivolatile Organics
Method 8270
Client Name: O'Brien & Gere
(cont.) Engineers, Inc.
Client 10: BLANK
Lab ID: 031220-0011-FB Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93 Prepared: 03 NOV 93
Authorized: 02 NOV 93 Analyzed: 13 NOV 93
Reporting
Parameter Result Units Limit
2,4-Dinitrophenol ND ug/l 50
4-Nitrophenol ND ug/L 50
Dibenzofuran ND ug/l 10
2,4-Dinitrotoluene ND ug/L 10
2,6-Dinitrotoluene ND ug/L 10
Diethyl phthalate ND ug/L 10
4-Chlorophenyl phenyl
ether ND ug/l 10
Fluorene ND ug/L 10
4-Nitroaniline ND ug/L 50
4,6-Dinitro-2-methyl phenol ND ug/l 50
N-Nitrosodiphenylamine ND ug/L 10
4-Bromophenyl phenyl
ether ND ug/L 10
Hexachlorobenzene ND ug/L 10
Pentachlorophenol ND ug/l 50
Phenanthrene ND ug/l 10
Anthracene ND ug/L 10
Di-n-butyl phthalate ND ug/L 10
Fluoranthene ND ug/L 10
Pyrene ND ug/L 10
Butyl benzyl ghthalate ND ug/L 10
3,3'-Dichloro enzidine ND ug/L 20
Benzo(a)anthracene ND ug/L 10
bis(2-Ethylhexyl)
phthal ate ND ug/L 10
Chrysene ND ug/l 10
Di-n-octyl phthalate ND ug/L 10
Benzo(b)fluoranthene ND ug/l 10
Benzo(k)fluoranthene ND ug/L 10
Benzo(a)pyrene ND ug/L 10
Indeno(l,2,3-cd)pyrene ND ug/L 10
Dibenz(a,h)anthracene ND ug/L 10
Benzo(g,h,i)perylene ND ug/L 10
ND ; Not Detected
Reported By: Hina R. Patel Approved By: Lori Ann Quinn
0 0C0065
_____ ___,. • ....._ ______ -4,~---
Dissolved Metals
Enseco
A COl"!'lll\;: ~(lmp.tn\
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-7
Lab ID: 031220-0014-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical Prepared Analyzed
Parameter Result Units Limit Method Date Date
Aluminum ND mg/L 0.10 200.7 NA 11 NOV 93
Antimony ND mg/L 0.050 200.7 NA 11 NOV 93
Arsenic ND mg/L 0.0050 206.2 NA 08 NOV 93
Barium 0.20 mg/L 0.010 200.7 NA 11 NOV 93
Beryllium ND mg/L 0.0020 200.7 NA 11 NOV 93
Cadmium ND mg/L 0.0050 200.7 NA 11 NOV 93
Calcium 137 mg/L 0.50 200.7 NA 11 NOV 93
Chromium ND mg/L 0.010 200.7 NA 11 NOV 93
Cobalt 0.012 mg/L 0.010 200.7 NA 11 NOV 93
Copper ND mg/L 0.010 200.7 NA 11 NOV 93
Iron 2.2 mg/L 0.10 200.7 NA 11 NOV 93
Lead ND mg/L 0.0050 239.2 NA 09 NOV 93
Magnesium 58.l mg/L 0.50 200.7 NA 11 NOV 93
0.010 200.7 NA 11 NOV 93 Manganese 1.5 mg/L
Mercury ND mg/L 0.00020 245.1 OS NOV 93 05 NOV 93
Ni eke 1 ND mg/L 0.040 200.7 NA
Potassium 13.5 mg/L 5.0 200.7 NA
Selenium ND mg/L 0.0050 270.2 NA
Silver ND mg/L 0.010 200.7 NA
Sodium 132 mg/L 5.0 200.7 NA
Thallium ND mg/L 0.010 279.2 NA
Vanadium ND mg/L 0.010 200.7 NA
Zinc ND mg/L 0.020 200.7 NA
W -Post-digestion spike for furnace AA out of control limits while sample
absorbance less than 50% of spike absorbance.
NA• Not Applicable
ND ~ Not Detected
Reported By: Michael Lifton Approved By: Joasia Przyluska
11 NOV 93 11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
~::ousa
• Enseco
A Comm!':, <;:ompam Dissolved Metals
Client Name; O'Brien & Gere Engineers, Inc.
Client ID: MW-B
Lab ID: 031220-0015-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical Prepared Analyzed
Parameter Result Units Limit Method Date Date
Aluminum ND mg/l 0.10 200.7 NA 11 NOV 93
Antimony ND mg/L 0.050 200.7 NA 11 NOV 93
Arsenic ND mg/L 0.0050 206.2 NA 08 NOV 93
Barium 0.18 mg/L 0.010 200.7 NA 11 NOV 93
Beryllium ND mg/L 0.0020 200.7 NA 11 NOV 93
Cadmium ND mg/L 0.0050 200.7 NA 11 NOV 93
Calcium 72.5 mg/L 0.50 200.7 NA 11 NOV 93
Chromium ND mg/L 0.010 200.7 NA 11 NOV 93
Cobalt 0.012 mg/L 0.010 200.7 NA 11 NOV 93
Copper ND mg/L 0.010 200. 7 . NA 11 NOV 93
Iron ND mg/L 0 .10 200.7 NA 11 NOV 93
Lead ND mg/L 0.0050 239.2 NA 09 NOV 93
Magnesium 44.0 mg/L 0.50 200.7 NA 11 NOV 93
1.8 0.010 200.7 NA 11 NOV 93 Manganese mg/L
Mercury ND mg/L 0.00020 245.l OS NOV 93 05 NOV 93
Nickel NO mg/L 0.040 200.7 NA
Potassium ND mg/L 5.0 200.7 NA
Selenium ND mg/L 0.0050 270.2 NA
Silver ND mg/L 0.010 200.7 NA
Sodium 36.8 mg/L 5.0 200.7 NA
Thallium ND mg/L 0.0050 279.2 NA
Vanadium ND mg/L 0.010 200.7 NA
Zinc ND mg/L 0.020 200.7 NA
W ~ Post-digestion spike for furnace AA out of control limits while sample
absorbance less than 50% of spike absorbance.
NA~ Not Applicable
ND e Not Detected
Reported By; Michael Lifton Approved By: Joasia Przyluska
11 NOV 93
11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
0099
Ensec()
.\ \ •'r'1<f11: I <'fTI!".llh
Dissolved Metals
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: MW-10
Lab ID: 031220-0017-SA Sampled: 27 OCT 93
Matrix: AQUEOUS Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical Prepared Analyzed
Parameter Result Units limit Method Date Date
Aluminum ND mg/L 0.10 200.7 NA 11 NOV 93
Antimony ND mg/L 0.050 200.7 NA 11 NOV 93
Arsenic ND mg/L 0.0050 206.2 NA 08 NOV 93
Barium 0.023 mg/L 0.010 200.7 NA 11 NOV 93
Beryllium ND mg/L 0.0020 200.7 NA 11 NOV 93
Cadmium ND mg/L 0.0050 200.7 NA ll NOV 93
Calcium 23. 9 mg/L 0.50 200.7 NA 11 NOV 93
Chromium ND mg/l 0.010 200.7 NA 11 NOV 93
Caba lt ND mg/l 0.010 200.7 NA 11 NOV 93
Copper ND mg/L 0.010 200.7 NA 11 NOV 93
Iron NO mg/L 0.10 200.7 NA 11 NOV 93
Lead ND mg/l 0.0050 239.2 NA 09 NOV 93
Magnesium 13.8 mg/l 0.50 200.7 NA 11 NOV 93
0.010 200.7 NA 11 NOV 93 Manganese ND mg/L
Mercury ND mg/L 0.00020 245.l 05 NOV 93 05 NOV 93
Nickel ND mg/L 0.040 200.7 NA
Potassium ND mg/L 5.0 200.7 NA
Selenium NO mg/L 0.0050 270.2 NA
Silver ND mg/L 0.010 200.7 NA
Sodium 13.8 mg/L 5.0 200.7 NA
Thallium ND mg/l 0.0050 279.2 NA
Vanadium ND mg/L 0.010 200.7 NA
Zinc ND m9/l 0.020 200.7 NA
W ~ Post-digestion spike for furnace AA out of control absorbance less than 50% of spike absorbance.
limits while sample
NA~ Not Applicable
ND ~ Not Detected
Reported By: Michael Lifton Approved By: Joasia Przyluska
11 NOV 93
11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
08 NOV 93 W
11 NOV 93
11 NOV 93
0101
,..----~~~~~--i·
General Chemistry
Client Name:
Client ID: Lab ID:
Matrix:
Parameter
O'Brien & Gere
MW-6
031220-0001-SA AQUEOUS
Result
Cyanide·, Total NO
pH
Total Dissolved Solids
w -Overaged.
NA -Not Applicable
ND -Not Detected
6.3
610
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Units Reporting
Limit
Analytical
Method
mg/L 0.01 EPA 335.3/9010 units 0.010 EPA 150.1/9040
mg/L 20.0 160 .1
Enseco
ii. (\lnun" C<1"'<p,1n1
Prepared Analyzed Date Date
03 NOV 93 04 NOV 93
NA 01 NOV 93 w
NA 02 NOV 93
Reported By: Katherine Dupont Approved By: Arthur Hannemann
0118
~~~~~~---e.--~~~~~~~1~~~~­
Ge n er al Chemistry
Client Name:
Client ID:
Lab ID:
Matrix:
Parameter
O'Brien & Gere
MW-13
031220-0006-SA
AQUEOUS
Result
Engineers, Inc.
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical
Units Limit Method
Prepared
Date
Enseco
A (.;imm,,:: Col'np.:in'
Analyzed
Date
Cyanide; Total ND mg/L 0.01 EPA 335.3/9010 03 NOV 93 04 NOV 93 pH
Total Dissolved Solids
w -Overaged.
NA -Not Applicable
ND -Not Detected
6.9
710
Reported By: Katherine Dupont
units
mg/L
0.010 EPA 150. I /9040 NA 01 NOV 93 w
20.0 160.l NA 02 NOV 93
Approved By: Arthur Hannemann
r-::,0123
" Enseco
General Chemistry A (0mm~ Comp.:inv
Client Name: O'Brien & Gere
MW-16
031220-0008-SA
AQUEOUS
Engineers, Inc.
Client ID:
Lab ID:
Matrix:
Parameter
Cyanide·, Total
pH
Total Dissolved
Solids
w -Overaged.
NA -Not Applicable
ND -Not Detected
Result
ND
7.7
270
Reported By: Katherine Dupont
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical
Units Limit Method
mg/L 0.01 EPA 335.3/9010
units 0.010 EPA 150.1/9040
mg/L 20.0 160.l
Prepared Analyzed
Date Date
03 NOV 93 04 NOV 93
NA 01 NOV 93 w
NA 02 NOV 93
Approved By: Arthur Hannemann
fl 125
,, • ·1-----Enseco
A ~omm~ ( 1'Mp.im General Chemistry
Client Name: O'Brien & Gere
MW-18
031220-0010-SA
AQUEOUS
Engineers, Inc.
Client ID:
Lab ID:
Matrix:
Parameter
Cyanide, Total pH
Total Dissolved
Solids
w -Over aged.
NA -Not Applicable
ND -Not Detected
Result
ND
7.6
290
Reported By: Katherine Dupont
Sampled:
Received:
Authorized:
27 OCT 93
29 OCT 93
02 NOV 93
Reporting Analytical
Method Units Limit
mg/L 0.01 EPA 335.3/9010
units 0.010 EPA 150.1/9040
mg/L 20.0 160.l
Prepared Analyzed
Date Date
03 NOV 93 04 NOV 93
NA 01 NOV 93 w
NA 02 NOV 93
Approved By: Arthur Hannemann
127
,~----
,. • I Enseco
A (~lmlf'll! (cll'l'lp.im General Chemistry
Client Name: O'Brien & Gere Engineers, Inc.
Client ID: BLANK
Lab IO: 031220-0011-FB
Matrix: AQUEOUS
Parameter
Cyanide; Total
pH
Total Dissolved
Solids
w = Overaged.
NA= Not Applicable
ND = Not Detected
Result
ND
5.6
ND
Reported By: Katherine Dupont
Sampled: 27 OCT 93
Received: 29 OCT 93
Authorized: 02 NOV 93
Reporting Analytical Prepared Analyzed
Units Limit Method Date Date
mg/L 0.01 EPA 335.3/9010
units 0.010 EPA 150.1/9040
03 NOV 93 04 NOV 93
NA 01 NOV 93 w
mg/L 20.0 160.l NA 02 NOV 93
Approved By: Arthur Hannemann
0128
---------~
LABORATORIES, INC.
• evolatile Organics
Method 8240
CLIENT CENTRAL TRANSPORT ,_",_I:..:.NC_. ___________ JOB NO. __ 51_7_8_._0_0_6_. 5_1_7 ___ _
OESCRIPTION __ _::Ch=a=-r=-lo=-t=-t=-e=-<-, _:N:.:_C::__ -----------------------------
MATRIX: Water
OATE COLLECTED __ S_e-=-e-'-P"'a,,_g-=-e_::2_ . DATE RECEIVED --=-S-=-e-=-e--=--P-=a-"'g-=-e_::2___ DATE ANAL YZEO _s_e_e_P_a-'g"-e_2 __ _
DESCFllPTIONo
SAMPLE NO.:
Chloromethane
Bromomethane
Vinyl chloride
Cnloroethane
Methylene· chloriae
Acetone
Carbon disulfide
1, 1-Dichloroethene
111 -Dichloroethane
1,2· Dichtoroethene (total)
Chloroform
1,2-Dichloroethane
2-Butanone
1, 1, 1 ·Trichloroethane:
Carbon tetrachloride
Vinyl acetate
Bromodlchloromethane
1.2-Dichloropropane
cis-1 j3-Dichloropropene
Trichloroethene
Dlbromochloromethane
1,1,2-Trichloroethane
Benzene
MW13
S2607
<10.
j
(5.
<10.
<5.
(10.
<S.
(5.
<10.
(5.
Equipment
Blank
$2608
(10.
j
(5,
<10.
<s.
(10,
<5.
(5,
(10.
<5.
OBG La.boratories, lnc., an O'Brien&Gere Limited Company
5000 Bri11ool1eld Parkway I Suite 300. Box 49421 Syracuse. NY 132211 [phone]
QC Trip
Blank
52609
<10.
l
.<5.
<10.
(5.
(10,
(5.
<S.
<10.
<5.
MW7
$2729
(200.
!
(100 •.
<200.
<100.
l
100.
(100.
l
(200.
<100.
<100.
<200.
(100.
180.
MW16
S2730
(10.
j
<5.
<10.
(5,
<10.
(5.
(5.
(10.
<5.
MW17
$2731
<10.
l
(5.
<10.
(5.
6.
<S.
38.
<S.
l
(10.
<S.
<s.
<10.
<s.
Page I of 1
,/? I ) ,A -Authorlzod:~4:f-12Mi'.. C;j.~
Date: July 20, 1993
r·
State of North Carolina Department of Environment.
Health and Natural Resources
Division of Solid Waste Management
James B. Hunt, Jr .• Governor
Jonathan B. Howes. Secretary
Wllllo1m L. Meyer, Director
Mr. Lawrence Wellington
Central Transport, Inc.
600 Melynda Road
January 31, 1994
Charlotte, North Carolina 28208
subject: Ground Water Assessment Program
Dear Mr. Wellington;
(-. 3
DEHNR.
This off ice has evaluated the August 1993 Ground Water Assessment
Report (Report) and the quarterly sampling results, dated January
25, 1994, from the October 1993 sampling event for the Central
Transport, Inc. (CTI), facility in Charlotte, North Carolina.
The Report describes the implementation of assessment activities
to define the vertical extent of contamination at the CTI site in
Charlotte. Upon review of these documents, this office has the
following comments;
1. 'I'he Report contains inconsistencies with regards to the
presence of volatile organic contamination in well MW-18.
In Section 6 of the Report, CTI concludes that MW-18
represents a clean vertical boundary. However, Section 5 of
the Reports states that contamination (6 ppb -toluene) was
found in well MW-18. The October 1993 analytical results
reported that no volatile organic compounds (VOCs) were
detected in MW-18.
Note: When determining presence/absence of voes, the
Hazardous Waste Section uses the practical quantitation
limits (PQLs) of 40 CFR 264, Appendix IX, codified at
1SA NCAC 13A .0009. The PQL for toluene, using method
8240, is 5 ppb.
This office recommends analyzing voes at well MW-18 during
the next two ground water sampling events to confirm the
presence/absence of contamination in the ground water at
this location.
2. The report also states there is poor hydraulic connection
(i.e., a "confining zone") between the zone where MW-7 and
MW-17 are screened and the zone where MW-18 is screened.
~che report further states, that because of this poor
interconnection, the contamination in MW-18 is unrelated to
t;he contamination detected in wells MW-7 and MW-17. This
P.O. Box 27687. Raleigh, North Carolina 27611-7687 Telephone 919·733-4996 FAX [phone]
An Equol Opportunity Amrmotlve Action Employer 50% recycled/ 10% post-consumer paper
Mr. Pete Dorn
January 25, 1994
Page 2
• •
Ground water elevation data collected during the October 1993 sampling event is consistent with
data collected in previous investigations. The direction of ground water flow is to the southwest on
the eastern portion of the site (See Figure 1 attached).
Data collected during previous investigations indicated that MW-18 represented a dean vertical
boundary, and, as depicted on Figure 2, wells MW-6, the former production well, MW-16 and the
intermittent stream define the clean boundary of the plume horizontally. Toluene, which had been
detected in MW-18 in one previous round of sampling, was not detected in the most recent round
of sampling. This confirms that MW-18 is the clean boundary and therefore no additional ground
water assessment investigations are warranted. A new laboratory was utilized for the analytical
services performed during the October 1993 round of samp1ing. Phenol was detected in upgradient
wells MW-6, MW-10, and MW-15, and in wells MW-8, MW-13, MW-16, and MW-18. Phenol had
not been detected in these wells in previous rounds of sampling (in some cases dating back to 1989).
There is no explanation for the positive hits of phenol in the upgradient wells and in some of the
downgradient wells. The next round of quarterly sampling is scheduled for early February. Upon
receipt of those analytical results, O'Brien & Gere Engineers will re-evaluate the validity of the
phenol results.
Certification of Closure of the lagoons was submitted to the State on December 14, 1993. Upon
acceptance of that certification, the post closure period will begin. The ground water monitoring
system will consist of wells MW-9 and MW-15 (upgradient wells) and wells MW-7, MW-8, MW-11,
MW-13, MW-16 and MW-17 (downgradient wells).
Respectfully submitted,
O'BRIEN & GERE ENGINEERS, INC.
/../-/ -73. --;;;;:;, 7-!--G~. Rest, P.E.
Vice President
GBR:TLN:dmh
Attachm<~nts: Table 1
Table 2
Figure 1
Figure 2
cc: G. Simpson -CTI High Point
L. Wellington -CTI Charlotte
M. Fleischaker, Esq.
T. Norman
R. Crowson -OBG Raleigh
U 'BRIEN & GERE ENGINEERS
TABLE 1
WELL SPECIFICATIONS AND GROUND WATER ELEVATIONS
CENTRAL TRANSPORT, INC. -CHARLOTIE TERMINAL
WELL G.ROUNO !!CRO!;N 00
•TOP Of
PVC
CAslNG
WELL WE!.L OEPTH ELEVATION INTf'!lVAL ELEVATION
NO. TYPE (BGL) (MSI.) (BG.l) (M sq
I I I I I
1 l overbDrden I 1s 1 ···• 766.2 I 9"19T · ·· 766:ss
2112193
GROUND
WATER
ELEVATION
(MSL)
e/7/9a
GROUND
WATER
ELEVATION
(MSl.l
10J2719S
G.ROU)llj)
WATER
ELEVATION
(Maj
2 overburden 759:5· :.µ.iµ;...,,:·;_:77;.c······::.:1::::59:..•+------+-----+--------1
6 bedrock 769.6 772'17 761.55 761.05 755.42
7 I badfocl< I 39 I 168.i I .2!1~39 r 768' 71 751.96 752.63 749.82
8 bedrock 769.9 22;32 771.54 755.38 757.26 753.24
7"-!=::07 7~~.38 9 bedrock >42;52 771;as . --·-. . -· 751.03
10 51 785.3• •41251• . ·t767.48 756.96 755.66 752.33
11 27 7S5.5 •• 1 P27 757 .68 748.79 748.26 747.07
-----------------12 bedrock . 9oc rno •75 7 .49 749.91 749.98 748.19
13 bedrock 761. 74 749.02 748.54 747.53
14 bedrock 59 49759 768:91 -------------
15 I bedrock I 65.s j 769.50 I 55.5"65.s I 768.99 744.81 758.89 733.31
1s 1 boo rock I •·· 76 I 759.TI 66~76 I 76LS1 750.84 751.53 748.28
171 bed rock I 66 j 766.39 I 552651 -768. r 751.85 752.38 749.64
717.86 754.24
A I -~~-I · 36.:ll I
18 I b~rock I 1301 768:951 110-130 I 768.81
· 111. o I ----111.54
Bl -"~-1 c ---->36.48
76!url ·. --91 1w.ss
• 768,2 ----· 769. 02
34.98
D 30.66 1sts I 161.18
Sl Jslream p(llnfl "o~-1 i1sili4 I '-~~ I 758'39
S2 sl ream point ----753,50
S3 sl ream point ----7 48. 61!
OBll observation 25 I 753.24 I 5"25 I 752.32 abandoned abandoned abandoned
OB2T 6bserilatlon I 20 I 75386 I · 'TS-'20[ 753.:36 abandoned abandoned abandoned
OB3 I obsefyatlon I 26 I n7£ Eo3 I 6c21J I 7!!0.45 abandoned abandoned abandoned
Page 4 of 5
•
•
ABBREVIATIONS:
NOTES:
BGL is Bel ow Ground Level.
M SL is Mean Sea Level.
BTOC is Bal ow Top of Casing.
• --- - " is Not Available/Not Appl lcabl a.
All maasu raments are in !eat.
Well No. 12 installed 6125190.
Wei I No. 14 installed 1117191.
Well No. 15 instal I ad 1118191 ; ground water el evalions may be influenced by nearby production wel I.
Well Nos. 13 and 16 installed 4113191.
Well No. 17 installed 2/8193.
Well No. 18 Installed 5/24/93
Wells A, B, C, and D not installed by O'Brien & Gere; well types and screened intervals not known.
• Stream points staked 1217190; •top of casing elevation• lor stream points is top of slake elevation.
•Ground water elevation• for stream points is surface water elevation.
Stream point S3 was destroyed during tM installation of wells 13 and 16.
2/28191 elevations -east side wel Is are lowest elevations; west sld e wells are lrom end of day.
•
•
r A.Bt.E '2-GIKllJN'D WATER OUAfJTI DA.l A
CENTRAt TFIANSPOFIT, It-le., CJ-l_ARLOTIE, NORTH CAAOUNA.
GROlJNO WATER ASSESSMENT AEPOOT -Jan!.!a.ry 11194
THIS T ABLf SUMMAFUZES lliE GROUND WAT-ER OOAUT'I' DA.I A FOO THE F-CU.OWlr.!Gi WEli.S:
MW-6, MW-7, MW-a.. MW-'U. M'N-10, MW-13, MW--15, MW-1'3, MW-~7. AN[}MW-1;!;
su.ssr ANCES NOT DETECTED !.'.I AnV SAMF'L.ES HA.VE NOT BEEN ft.ICWDfD !N l~S TABLE.
ABBRE'IJA.TIONS AAE AS fOl..tOWS:
ND Indicate a :su~noe not de1ec1ed :ti~ d~ 11in1.
t.IA lndie&1!MI th.at anafyala wa-s l\01 reql.Hlsted.
NT lndh;:~tea lllle.1 lab did l\Clt Wirt :lor aruil:fK!.
@ lndlcstes di&1 di-n.tiutyl pl"ilhaJate Wll.a de tee lied In ttie field" bkirill-B.1 '6-ppb.
(1} SU. Ortniking Wa.'18r A.ct S~rid""'rd (MCL).
(2:;1 tklrtt1 c..;ro11n1 Wa.1er Cualit"j St&nde.rd. •
•
TABLE "2:-GA.OOND WATER OOAUl'f DATA
CENTflA.l TflA.NSPCfLT. IN'C., CHARLOTTE. t..."OOTI-1 CAi!ia.JNA
GROUND WATER A'SSE:fi'SMENT REf'ORT + .Janlf.al)' 1~
V.'Ell MW-6-[PAGE 1 OF 2"J
CA.lEGCfl'f PA.fUJ.jETER.
MetaJs.
(ppm)
Base/Meutr.Jll
""' Ernac~bl111
""'l
'l/ol&tile
Qr!)Bl"ll~
Compoun.d$
{ppb~
Misc.llMBCIL"'
""m)
Arurrinum
""'"~ Ba~um
BElrylllum
Ciidmlum
Calcium
Ohromium
"""" """"'' I=
'"'' Me~eslum
Mer..ti&neM
Nickel
PotaWum
Sllwr
Sodiom
Vanadium
~~
Cyanide
01-n.-&it)i .Phfl;iril11-kl {p_pti)
Naphthfilerie l'ppb)
Bl111 ~~tti'.f'lhe~l!'i) Ptithatate l'.ppb]
1,3-Dlehlowberwma
.N-~anltlamlmt
f'h&nol {p,pti~
t+olmet!il"lpllenol [ppb-)
1,4-0lchlorobenuina
~nyl ChlC>rtda ,,_,.,
Senunii l'pp21)
1, 1-0lehlol0elh:tfot11e (Wb)
1,:2-DlchlowbermeM {ppb~
f1h]ilbet1Hfllt (ppb)
Me'lh)f•ne Chloride
Tolu&Ml (ppb)
1,2,"1-Trlcf'lloroben-zene-l'ppb)
1, 1,t-Tridlloroe11\rn1'i1
iln'Xyl1n11 [ppb~
Xylen.ea {ppb}
t.2-0lchloroetl1e1'141 ~tote!) [pp'b-)
Ctilorolorm l'pp'b-]
1.1 Dkl"iloroethl!lle
ctilorkla
MiP.N Total ColiPorma
Cci~
"°"'' Auoride
Surbt::_,rmi {MBll.S)
tflb'.site -pH
Suliate
Drln'klng Watet"
S1endel'll:lti
Nona-
0.05 rrgi'I (1}
1.0~[1)
NoM
0.00i5 ~II {1)
Noo•
0.05m;;ii'I (1}
Noo•
1.0 mg.I\ (2)-
0.0J..rrg/I (2jo
0.05.rrgll (l)
Non11-
0.05m:;ii'I (2jo
0.15 .rrg,, (:!lo
Non•
0..05~/l,1)
"'"' -· 5..Gm;;i/'1 ~2)
0..154 mg/I (21-
~· . ~· . ~· ... -o.eoo (1)
"""' """' """' 0.07-5-(1)
0.002{1)
OOM
• O.oo5-[1]
... 0.001 (1)
0,600 (1)
0.700 [1)
0Jl07 {1)
2..000 {1)
0.700 [1)
0."21Xl~tl
10.0 0)
10.0 (1) -• -0.100 (1)
"""' 250 mg/I [2l
1 per 100 .rd. (1j
1• (>)
""' """ [2) :2".0rTl!l'JI (2)
Nona
10,m;i/'I {2)
1.0 rTl!l'll (2)
15.5-B.-5-[2l
250 mgJI [2l
·-[ur.rfllt)
,,,,
O.Ot
"°' NO
"" 3M .. ,
·~2
2.o<
49:9' ....
" ·~ 0.2
"~ ND
19.1
1-43
0~1
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
NT
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
"" "" ..
NA
NA
NA
NA
NA
NA
N•
"'"' (filt.)
0.2
ND
0.01
NO
ND
21.1
NO
NO
0.02
1).13
NO
~s.e
"'" NO
~· 0.02
17.4
0 . .01
NO
ND
NO
NO
NO
NO
NO
"" "" 00
"" lfT
NO
ND
NO
ND
NO
ND
ND
ND
NO
NO
NO
"" ND
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
08/90
(\m"-llli .. ~
D.04
D . .,
ND
ND
"'~ D.DO
O.DO
O.»
au
O.Oll
1•~
1.07
0.00
·~ O.Oll ....
"" 0.14
NT
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
1'A
"" ..
NA
NA ..
NA
NA
NA ..
-(ftl)
O.O!I
NO
0-10
NO
ND ....
NO
NO
"" "" "" ....
"" NO ....
003 .,,
ND
0~1
NI
NA
NA
NA
NA ... ..
"" .. ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA .. .. .. ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1mo
!~ilQ
,.
<0.01
<0.01
0.01
0.02 ..
0:101
MO ._,. ..•
"°' "' u ...
1.l
<0..01
" o ..
0.06
<0.0!
ND
ND
ND
ND
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
NO
NO ,,
>..,160l
10
"" <0.2
<0.(1-1
0.11 , ...
o.a ,.
12'00
(filW
<0..01
<0..01
<0..01
0.()5
<0..01 z
<0..01
<0..G~
<0.01
<(ltO~
<0Jl2
" <-D.oin
"'' <D.05
<0.01
" 0.02
<0.01
"" .. ..
N•
N•
N•
N•
N•
N•
N•
N• .. .. .. .. .. .. ..
"" ..
N•
NA
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
a.'07IS11 3/07191
(IX!!il1} (filt.)
3.0
<0.1)1
0.1
0.-00
<0.1)1 ..
o.co
0.0<
0.17 ..
<0.02'
"' o ...
<0.0:2"
u
<0.01 ,.
<0..01
·~2
<<l(l1
ND
ND
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
NO
NO
"" NO
ND
NO
NO
NO
ND
" <2
>70 ...
<O.:?
<0..01
00
<(1"_02
OA ..
<0.1
<1).(11
<0.1
<0.1 . ., ..
0.00
<0:1)1
0.00
0.(lo7
<0:1)2
" 0.03
<0.1}2
"' 0.1)1
" <0.01
O~\
NA
NA
NA
NA
NA
NA
NA
NA
N•
N•
N• ..
N• .. .. .. .. .. .. ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3l21i'D1 :w211'11
{unfilt) ~All)
~1
<0.01 ,._,
0.00
0.01 ,.
0.01
0,04
oQ-.13
1.•
<oll-..02
" ....
oQ.02 • ·~1
" ....
o ...
<0.1)1
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
NO
NO
NO
ND
ND
ND
NO
" <2 ., ..,
<0.:2
<D.01
OM
'"'2 0.1
"
<-0.1
<.l)_(J.~
<0.1 ....
0.01 ..
<0.01
<0.01
0.01
0.02
<0.02
" 0.02
<0.00
0.71
<0.01
10
<0.01
<(1.01
N•
NA
N•
N•
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
N• ..
N• ..
NA
NA
NA
NA
NA
NA
NA
HA .. ... .. .. .. ..
NA ..
....
{~ilQ
,.
<0..01
<0.()5 •..
<0.01 ..
om
O.o< ....
'U
<-0.02
"' ' 0.02
1.0
001
" 0.11
0.0<
<0.01
NO
ND
NO
NO
NI)
NI)
NI)
"" Nil
ND
NO
NO
NO
NO
NO
ND
NO
NO
NO
NI)
"" NO
ND
" 280 ., ..,
<"2
<0.01
1.1
<0.-02
ao
"
O!>O
ffllO
<0.~
<0.0l
<0.1 . ..
0.01 ..
<0.0'I
<0.01
0'1
0.02
<0.-D:2
" 0.02
<0.1>:2
0.71
<0.D1
10
<6.0t
<0..01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA .. .. .. ..
N•
N•
NA
NA
NA
N•
N•
•
•
TABLE :2. GROONtl WATER OUAUlYDATA
C:ErfTRAL TRANS:l>OAT, ~C: .• C:HA.RLOnE, NORTH CAA.a.JN"A
GROUND WATER ASSESSMENT REPOO.T • January 1:994
WELl MW-8 (PAGE 2 OF 2ji
CA TEGCRV PARM!ETEA .., Drinking Ws!ler
Ma191s.
(ppm]
:Bue,iNalllr.111
Acid
E~trsctabln
~pb)
Vols~re
Q-.g~nic
Compound8
(:ppb)
Mi"SOllllsneout;
~prn·
Ahrrim,un
Areenk
-~ Berytliwn
c.dmJ~
c.rc1~
Ghromiu;m
Cob.alt
Copper
lroo ,...,
Mag.11esi:um
Mer.gane9e
r.fickel
Potu&1;.1m
Sil-.w
SOOiwn.
V.aMi:rium
~~
Cyanide
:m-n<Bufrl Phth.1118'6 [ppl:J.)
Ne.phthnlen• (ppb)
Sin ~2-e'lh:,ihaxyl) Pl'lltld!itti (ppb~
1,l-Olchlorobenuina-
N-NilJOIOdipfimylflfllns
P.Miool [ppti)
2.4-Dlmetlljliplienal (pph)
1.-'-0lcJ'Jlorobenz-sna-
Vln.JC Clilorfd&
-~~ Bei1:5nlil (:ppb)
1.1-illcliloro~·th.)ttirwi {p,pti)
1,2-Dk:hlorobenz.ane [ppb)
Etllylb-snz-sM {pptl~
MsllylMe Ctilorlda
Toluene (ppb)
1 ,2,-4-Trlchlornbenuin.e {ppbl
1,1,t-Trtt:hloiofiltl"-'1•
"11·.-Xylsrie {ppbl
X)"teM! {ppb)
1,2-Dlchloroethana-(»111~ {ppb~
Chlo.reform [ppti)
1,1 Dktikiroetharwi
-ChlOllda
MPN T-c-181 Colikmu
Colo<
Solids.
.fluo.rlda
S!Jrfactult8 (MBAS~
.NlfU.1Et
.Nil!il~
pH
Stil:late
SUlr.d:r.rda.
None
0.0!5 mg/I {1)
1.0 m.:ii'I (1} -· 0.-00:5 mg-II [1)
N~o
O:G5 mtill {1)
None
1.Ci1I'9/l(21i
0.03 mg/I (2)
0.0:5 mg/I [1)
NoM
0.0:5 mgJI (2)
G.15-rrW! (2)
,.. t.kimt
'"" O.o5 m.:ili (1} -· -· s.o .rrgll (2j;
0.154 mg/I (2)
none
OOM
non•
0.800 [1)
non'EI
non•
non.,
0.-075 [1)
0.002111~
"'~
0.1)» [1)
0.007 [1)
0.000 [1)
0.700 [1)
0.007 (1)
2.000 (1)
G.700(1)
0..:200[~)
11).ol) [1)
.. 10.(1. [1) . ~· * 0.100 (1}
~· ,., ..., ""
1 per too mL {1)
15 (:i!li
'°'"'"'"" 2.Gmgfj("2}
No.,.
10 mg/I [:2'j
1.0~11 (2}
6.5-S.S (2jo
:2:50 lf".9i, ~21'
ofl/9:JOUP 6XIOOUP
ll,lllftl1} (file)
<0.~
0.1
o ...
<O.'ln
<0.0~
100
<0.0-1
007
0.04
39
0.03 ..•
·~ .... ...
<0.01
160
0.13.
0.1
<0.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
"" "" ,. ..
211
"' <0.2
<.0.0~
1.1
<0"2
0.5 .,
<0.t
<O.Ot
<0.05
0.04
<0.01 ..
<0.01
O.O:i!
O.O"L ,.
<0.02 ..
4.2
0.0-2
0
<0.01
150
<0:01
<0.0\ .. ..
N• .. ..
HA ..
NA ..
"' ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" "" ..
NA
HA
NA
.,.,
(-unO!ji
"' <0.000
<-0.05
-0.13
<0.01 .,
<0.01
0.04
0.2>
"' 0.15 ..
O.Til
0.0<
'·' <0.01 ,,
0.1
0.03
<0.01
NO
NO
NO
NO
ND
ND
NO
ND
NO
ND
NO
NO
NO
NO
NO
NO
ND
"" NO
NO
NO
NO
NO
" • ..
""' <0.:C
<-0.01 ....
0.14
·-·
.,.,
~~
<0.1
'"''' <0.0:5
0.05
<0.01 ..
<0.01
<0.01
0.03
0.00
''-"
"' <0.01
<0.(12
3.7
0."2 ..
<0.01
0-.01 .. .. .. .. .. •• .. .. ..
N•
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"-'
NA
"-' .. ..
N•
"" N•
NA
"" '"' [QQo [unt.IQ
<0.1
<0.005-
<0.1
<0.05
<0.01 ..
<0.01
<0:05
<0.01
0.07
<0.~
"' <0.05
.::(1.05
<5
<0.01
"' <005
0.40
NA
NO
ND
ND
ND
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
12
" " -<0.1
<0.1
o ...
<0.05
.,
'·' <0.000
0.1
<0.05
<0.0l
" 0.02
<0.05
0.04
·~ <0.ll5 .,
i:J..11
<'llO:S ,,
<.0.01
" <0.05-
o ...
<0.D1
NA
NA
NA
NA
NA
NA
"-'
NA
NA
NA
"-' ..
NA ..
NA ..
"" N•
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
,,.,
[unfil!)
tO
<O.~
0.1
<0.M
<0.01
" 0.00
<0.05-....
" <0.0S ..
0.17
<.0.0:5
<5
<0.01 ..
0.00 ...
<0.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
"" "" "" NA
NA
NA .,.
NA
NA
NA
NA
0.7
NA
-(Alt)
<D.1
<0.005-
'·' <0.00
<G.01 ..
<0.01
<0.M
"'' ,, .. ,, ..
"' 0.00
<0.C6
<5
<0.01 ..
"'°' l).:i!!"'
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" ..
NA
N•
N•
N•
N•
N•
N•
N•
NA
NA
NA
NA
NA
10!0>
[u111filt)
17
<OOC:O
0.18
<O.OO:a:J
'°""' "'·' 0.05 ,.,.
0.14
"~ 0.1)1-9 ,.,,
"" <0.04G ••
().()32 .,
, .. 1
0.!12<
<0.01
ND
ND ....
ND
ND ,.
ND
ND
NO
ND
ND
ND
ND
NO
ND
"" "" "" "" NO
ND
NO
NO
NA
NA
NA
010
NA
NA
NA
NA .._,
NA
""' m~
<0.1
<0.«e
0.090
<0-""'l
<0.00!5 ,.
<0.010
<0.1)10
<0.1)10
<0.10
<0.00::i ... ,
<0.010
''-"" <5
<0.(110 .. ~
<0.-010
<0.1)2ril ~tol M.ETHCO Bl.Am< i'i.T 0.03 PPM. .. .. ..
NA. OETECTED ltf B~K
"" ..
N•
N• ..
N•
N• ..
NA
N•
N•
N•
NA
NA
NA
NA
NA ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
"-' .. ..
•
•
TABLE 2. -GROUND WATER QUALITY DATA
CEtHRAL. lFIANSPCfiT. 1t-iC., CHMLOlTf, NOR.TH CAAOlltfA
GROONO WATEfll ASSESSM.aill PiEPCftl • J&r.ruuy 1994
WEU. M'n'--S (PAGE 1 Of "21i
CA TfGCR'I' PAA,fl,METER • Drlniitlg Wa1er
Me-tels.
.:Wml
flaw/Nalllr.fll
Acid
Extract.11ble:1;
~ .. ,
Vole.til&
Organlc
Oampo•.Hidoi
~)
Ah.uririum
Araenlc
""'"m Beryl II um
~mlum
Calcium
Cllrorrium
Cobol•
°"""'' I~
lood
Magna-$lum
MangmnitlB
MEirc1.uy
"""' Potanfum
s11 .... r
"""'~ "IJ.lf!Mdhrm
~~
Cp;nklei
Ol·M:lllfyl Phtt11111111.•a [ppti)
Hapll'ltla1aMi [ppb]
Bis ~lhyih.exyl) P.hilJla'labii (ppb}
1,.3-0Ech&iroMIWlnit
ru.ll11Jo&Odlphan!P'l111Ritl•
Phanol {pjlb}
:2,-4--Dlrnelhylphenol (;Ppb)
1 ,4-Dlctilo.roben:Hil•
\1111ytChlo.rlda. ,,_,u
8enz1M• (ppb]
1,1--0lclilorowtbylffle (ppb}
1..2-0k:hlorobenztin1 [ppb)
Eth:.rtbeni-anit [ppti}
Mall'lyllil>l'I• Ciiloride
Tdue1141 (ppb}
1,:2.~·TrlcJ'lloroti.nnnoe (ppb}
1 ,1,1· Tirk:llloroetha-n4i
m-X.yleri• l'ppb)
Xy1enes [p_pb)
1,2-0lelllo~ (1otal) (ppb~
Ctiloro:locm (ppb}
1.1 Dlc:lllOlO&"dlar.i&
MiSOE1ll11.neo1111 ctilorid"•
[ppm) MPH Tor.al Colfiorml
Col~
Solld"-il
"""""" SurfacbUlts (MBA.SJ
Nitre.'19
Nitrite
pH
Sul!ate
$1..i!nd.ards
. ·~ .. (1-.(15 mg/I (1}
.. 1.0 mir.11 [1] . """' ,. OJXl6 ~II {1) . """' ... -DJJ51r9{1 (1~
No.,.
1.0mgll(:!i'
0.00 mg/I (:2)
0.1)5 mg/I (1)
NoM
.. rLl.05 mgi\ (2}
,. O..CI005 nl9J'I [1}
,.. -0.1S1r9{1 {2) -· 0.05mg/I [1)
Nooo
Nooo
.. :5..0 mttll (:2)
.. olJ..15'4-~/1{2)
~· ~· ~· l).600 (1)
~· ~· ~· O.OP.5{1)
0:002'.ij1j
non.•
0.005 (1)
0.001 (1]
.. r;J..&00 (1}
.. 0-.700 (1}
.. 0..007 ~1)
:2.000 ~1~
0.700 {1)
0.00:2(1~
10..0 (1j
16..0 ~1) -.. 0.100 (1}
• N<>M
.. 250 mg-II C2l
.. 1pet100 ml...{1)
... 15 ("2jo
... -500 l119J\ (<!lo
2.Gmgfj (2ji -· 10 mgJ\ [2}
1.0mg/1~:2)
e.s~as ~:2)
:250 rr..;i/1 {2)
""' (t.Jnfill) ...
O.o<
~" NO
NO ., ...
0.'2 ....
"" 0.00 ,,.
12.-5-
, .. ,,..
ND .. ,.., ....
NO
ND
NO
ND
NO
NO
NO
ND
ND
ND
"' NO
"" NO
NO
ND
ND
NO
NO
ND
NO
"" "" NO
NA
NA
NA
NA
NA ..
"" .. ..
NA
""" (fill.)
NO
"" 0-.1;(1;
"" "" ..
NO
NO
"'' o ...
NO ....
~·
NO ...
NO
..~
0.1'9'
G.02
NO
NO
NO
NO
ND
NO
NO
NO
NO
NO
NT
NO
"" !fl)
NO
NO
NO
ND
NO
NO
NO
"" NO
NO
NA
NA
NA
NA
NA
NA ..
NA
NA
NA
-[unHl1}
,..,
ND
"" ND
ND .._,
NO
ND
0.01
.C.02
ND
17.e.
0.41
NO
3.4:i!'
0.0<
115.2
ND . ..
NT
ND
NO
ND
NO
NO
ND
ND
"" no
NO
NO
ND
ND
ND
" NO
ND
"" ND
NO
NO
ND
ND
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
....
~Hit.]
0.14
ND
NO
ND
NO ,..,.
NO
ND
0.01
"" "" 43.0.""
2.72*
ND
~.33 ..
·~· 47.&""
ND
0.02
NT
KA
NA
NA .. .. ..
NA
NA
NA
NA
NA
NA ..
NA
NA
"-' ..
NA
NA
NA
NA
NA
KA
NA ..
"" NA
NA
NA
NA
NA
NA
NA
,..,
{INIH[1}
"" <0.01 .... ....
·~' ''° u ... , ,., ...
<0.02 ...
" ,_..
" <0.01 .. ....
M1
<0..01
ND
NO
NO
tro
"" "" ND
ND
ND ..
ND
NO
ND
ND
NO
"" "" ND
NO
ND
ND
NO
NO ..
" .,
""' 0-3
<0.01
<0.02:
<0.0:i!: .. ..
,,,.,
(fil<)
<0.1
<0.01
<0.1
0.00
<{ii.0-1 ..
<Ml
<0.01
<0:01
<0.01
<0.0:i!'
" •••
"'' u
<0.01
" <0..01
<{li.01
NA
NA
NA
NA
NA •• NA ..
"-' .. ..
NA
NA
NA
NA
NA •• NA .. ..
NA
NA
NA
NA
NA ..
NA
NA
"" ..
NA
NA
N•
NA
3l07JSl1 S/07191
[unHll] (flit] ..
<O<>l
L1
o ..
<0.-01
"' 0.00
0.2<
0.151 ,.
<0..02
" • ••
0.1>1
<G..01 ..
-0.17
0.00
<0.01
NO
NO
NO
ND
ND
"" Nil
HO
"" "" NO
NO
ND
ND
ND
NO
ND
"" "" ND
ND
ND
ND ..
<t
"' .,. ••• <0..01
<0Jl2
<0..02 . .•
"
<0.1
<0.-01
<0.1
0."5
<0.01 ..
0.0<
O.o<
0.01
o.o<
<002
41
3.4
<0.02: .,
<0..01 ..
<.0.1)'1
<0.01
"" "" "" ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ... ..
NA
NA
NA
NA
NA
KA
"-'
"" ..
NA
NA
NA
NA
NA
NA
NA
3.i21.'91 3J21JSl1
{W101} (flit..)
"' <0.01
0.12.
0.'9
0.02: ,.,
1.211 ....
1.73-
"' <0.00
"° "
0.7
" <.D.0-1 ..
0.52
O.l!-7
<•101
ND
"" "" "" NO
NO
"" ND
ND
NO
ND
NO
NO
ND
ND
NO
NO
" 00
ND
ND
NO
" 100
<>
10 ...
o.2
<D.01 ,.,
<002
'·' "
<0.1
<0.01
<0.1
'"' <0.01
" <0:01
<0.01
<0..0t
0.1.e.
<-0..02 ,.
o.~;i
<0.02"
0.01
<0..01
" <0.0.1
<0.01
NA •• NA
NA .. ..
"" .. ..
NA
NA
NA
NA ..
NA
NA •• NA .. ..
NA
NA ..
NA
NA •• NA ... .. ..
NA
NA
NA
NA
.,.,
("unlit'!} .. ..
NA ..
NA
NA
NA
NA ..
NA ..
"" ..
NA
NA
NA .. ..
NA
NA
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
" • "" "" 00
NO
ND
ND
ND
ND
ND
"" • NA
NA
NA
NA •• NA ..
"" ..
NA
·~· ~unlit!) . .•
<0.01
<0.05
0.,.
<0.01
" O.Oii!:
om
0.02
" <0.00
"' '-' ......
0.02 ••• <-0.0.1 ..
O.o7
0.00
<0..01
"° ..,
"" "' "" ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
"" "" ND
ND
ND
ND
ND ,.
ct<S • .... ,...
cm
<.0.01
0.00
<0.02 ._, ..
•
•
T A'BLE :2 • GROIJt.ID WATER OOAUTY OAT.A
CENTRAL IAANSPOFIT, !NC., CttMLOTIE, NOFITH CAA.CUNA
-GAQIR.IO WATI:A ASSESSMENT flEPOAT • J&nuary 1994
WELL. M'W-6 .;P,li,GE :2" Cf 2)
CATEGCftY
Metal a
[j:::prr-~
Ba:SoBfl.leoum.1 -E:o.tru:tabfea
(J>ob)
1Jo1fi~I•
C1r9anEc
Colr'pOlll'ldS
(pob)
Misc:ellan&OUlil
"'""~
PARAMETER
Aklrinum
A.reer.~
EWnium
Sei)'llium
Cadmium
Catci!Jm
thl'Clmlum
Cobolt
°"'"' I~
""' MagneEiium
Mlt'lgan.esa-
M11rtul)'
"'""' l'W&ilWlll
.Sil\oer
"""'~ IJ.analfium
""' Cyanlda.
DJ-n-Butyl Ftithdlte {ppb)
tfai;tlltidena [ppb)
Bh (21!1thylt-.e~j Pi'liltlalti'll (ppb}
1 ,3-DEch.lorciboenuinit
N·Ni1rOsod[,phK1~11;rri11•
F1'1tnc4 (ppb~
2,.-4-Dlmethl!iphoan.:il (:Ppb}
1 ,.4-0lchlorobanzffl•
Vll\)'I Oilorkl•
"''"""' S.nZBi'l& (:pj:lb}
1,1-0lcliloroethylffl• (ppti~
1,2--0le'h~nana [pp'b)
E'81~benz.an1t l'ppb}
MB'tljltKI• Ohlor\1:1''8-
lolutil• (ppb}
1 ,2.4·Trk:hlol'ClbanZene (ppb~
1.1,1·Tritllloroethena-
T etr.sehloloetherMi
Tflthloroa@_:;lell!EI
m->:l!iim& l'Jipb)
X.y:tar.ies {ppb-)
1,2-0itllloroethar..a-(»uil) [ppti}
Ctvor<Korm (ppb}
1,1 Olchloroe'!Mn.a
"""""" MPr.IT~I Co1iforma
"""" Solid Iii
AUO<i"'
&Jrfacl.6nts (Ml!i"'-S)
NiD'a!le
Nirrlte
pH
Si-Jlf&1a-
Drfnklng W.aD&r
Stan.:lan:l1
N"'" 0.06 m;/1 {1)
1.l>.rrg/I (t)
Nooo
0.005-mg.i'I (U
NODO
,,. Cl.05 mgJI (1}
"""' 1.0-mg.i\ [2]
1).00. 1?'9 .. ~2)
0.05 lrf:il/l {1)
No~
0.-0:S nlij-/1 [2'J
0.0005 11"9/1 f1)
0. 15 mg.II (:2]
NODO
,,. 0.05-1119Jl (1} . "'"" . "'"" ... -5-.0-mglli (:2]
... 0.15.4 mg/I [2'J
~· ~· ~"'
0.-600 (1)
OOM
"'"' "'"' ,.. Cl.01S (1)
... O..oo:2(1] . ~· .., o..oo5 (1~
.., 0.001 o~
D.600 u~
1).700 f1~
0.oo7 {1~
2.000 {1j
ci.ioo U)
0.00~\~
10.0 {1)
10.0 {1)
,.. .none
... 'il".100 (1}
"'"" 250mgi'& (:2)
1 per 100 ml (1}
15 [2)
50011"91'1 {:<:)
:2.o mall {2J
""" 10 11'9fl ~:?:.
... 1.0 mg-JI (2)
,.. "9.5. e...s (2)
,,. 250 mg/I (:2]
,,.,
(GI.)
<0.1
<0..01
<0.00
011>
<O .. Cl-1
23
0~1
<0.01
<0.01
0.00
<Cl.02
" 0-3>
<0,,,,.
'"'" o ...
<0.01 ,.
<0.01
<0.01
N•
N•
NA
NA
NA
NA
NA
NA
llA
"" N•
"" N•
NA
NA
NA
NA
NA
NA
NA
ND
NA
NA
"" N•
N•
NA
NA
NA
NA
NA
NA
NA ..
N•
""
,,.,
{unifilt)
, ..
<0.005
<"-"'
0~1
<-DIJ.1
" 1.2
0.23
u
"'' <0.o>
140 ••• <0.oo:J5
0.45
12
<0.1)1 ..
0.53
0."3
<(1.01
"" "" ND
ND
ND
ND
ND
ND
ND
ND
ND
"" "" "" ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ,.
" """ >10
550 ...
<;Q.01
O.OJ
0.0< ...
""
01>1
(iih)
<0.1
<-0.00:5
<0.05
0.0<
<0..01 ..
<0.01
o"'
"" o.1e
<0.03 ,, ,.
o::l).OC(t5
0.02 ...
<0.01 ..
<0.01
0.01
NA
NA
"" ...
NA
NA
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" NA
"" "" "" NA
NA
NA
NA
NA
NA ..
N•
NA
NA
NA
NA
NA
NA
NA
...
{unfiJI) ..
<0005 ...
<Q.OS.
<6.01 .. .. ,
0.11
0•1
'40
0.1<1
" ·~ 0.005 .. ,.
• <0~
43
0.-42
0.23
<0:01
ND
ND
ND
"" "" NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
"" , ..
190
NO
ND
ND
ND
ND
" <10 ,.
<30
o.•
<0.01
<0.-G5
<0.CIS
' "
... ,,..
[GQo (!JnlUI)
<0.1
<0.00S
0.1
<0.05
<0.01 ,.
<0.01
<0 ..
<0~
<0.05
<0.CIS .. ,_, ·-<0-"> ..
<0.0-1 ..
<0.00
0.32
NA
NA
t<A
"" NA
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA .. ..
"" "" •• NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
NA
" <(1.025
1
<0.00
<0.01
110
u
O.Z>
1.4
>tO
0.13
''° 0.1
O.OOt
0 .. 42
10
<0.01
'1
o ..
0,33
<-0.-1)1
ND
ND
ND
ND
NO
ND
"" ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ,.,
" ND
NO
ND
ND
ND
NA
NA ..
4311
NA
NA
NA
NA ...
NA
IS.i'9:J 10193
~Hit) {un.filt)
<0..01 197
<0.005" <0.Cll50
0.2 1.2:
<0.0S O.oo37
<0.0"I <0.00:50
~1 137
<O.D1 :2".1
<0.C6 0.29
ill01 1..51
.... 300
<o.CJ5 0.-1)1"9
11 21'5-
1.e. 15.4
, ...
(iih)
<0.10
<0.050
(1.18
<0.0oro-
<0 ....
"~ <0.011)
0.012
<0.(110
<0.10
<'-"""' .. ,.
<0.0002 <O.oco21) <Ci .. 00021)
<0.00 0.1 <(l-..D40
<5
<0.01 ..
<0.00
o~ ..
N•
NA
NA
NA
NA
NA
NA
NA
"" ..
NA
N•
N•
NA
NA
NA
NA
NA
NA
NA
NA
t<A ..
NA
"" N•
NA
NA
NA
t<A
NA
NA
NA
NA
NA
""
15.7
<0.010
>M
0.'7
0.03
<0.01
ND
ND
ND
"" "" ...
2.5j
ND
ND
43
ND
ND
"° ND
»I
ND
Nil
"" ...
190
ND
ND
·~ ND
ND ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
" <0..010 ....
<0.o10
<0~ IN METtlOO BLnlK AT 0..(1;3. P.PtA;
t<A ... ..
N•
N•
NA
NA
NA
NA
NA
NA
NA
t<A
NA ..
NA ..
"" N•
N•
NA
NA
NA
NA
NA
NA
NA
N•
NA
""' NA
NA
NA
NA
·~ NA
•
•
TABLE?· GROONO WATER OUMJTY-DATA
CfNl"AAL TflAt.ISP-OflT, INC., tHAAt.OTIE, NCflTH CARCt.JN'A
GACUND WATEfl ASSESSMa.li REPOFIT • Jan11Juy 19!M
WELL PJillY..SJ [PA.GE "2 OF 2)
C.6.TEGC@ ...
Mela ls
"'""'
&&e-/N81J~
Acid
Edrat'8bltt:
-)
Vol11.1il1t
Organic
Compounda
!ppb)
PARAMETER
A.l1Jnin1Jill
Ar.senk
8arium
So-m
CedllRJm
Calc:ium
Cl'llorri1Jm
""""' Copp<•
'"" lood
Ma.gna$lum
Mlltlga.n.e•
"'"" PQtaal>'ium .... ,
Sodl~
VaMtF!um
~~ _,.,
Ol·ll·Butyl fYl"lflala.1a l'ppb)
Neph"IMilana fppb}
Bi~ (2-ethylh.elfYI~ PtilJJa'lat. (ppb)
1 ,.3-Dicl'llor-DbenHlle
N.Jollllro&Odiph.er.iylemlne
Phanol 1'$ipbJ
2,-4·0Wn&th.)"l",il"ianol [pplt)
1 ,4-Dk:hlorobeinz.enti
Vinyl Chforkt•
'°'""' BEir.ztin.e (ppb}
1,1-D!chForoethylHJe (ppb}
1 ,2-Dk:hkir-obe.nz•iw [ppb)
Btl:-"lbermr.e [pp"b]
Mefl:-"leri& Cfllolicki
TOOJKI& [pp'b)
1.2.4-lrk:Mon:it:.nun& l'ppb)
l .1.1+Tlich!oroelt111:n.e
m--X)fe.nit (:ppb)
X.jltann: [ppll)
1.2-0icl'lloroetbene-("lotel) [ppb)
Calbon. Dlwl~e
Oilo)'(lbrm [ppb)
1.1..[lictiloroe-th.ar.a-
MisoellafloiO'!JS Cl'llolkl&
{ppm~ MPN Total tollPorms
Co"'
Solids
fluolid&
Surfaeta:nlB (MB"'-S]
,Ni1n11Ut
iNi'lii!IB
pH
Stilrate
,,. Dr1nldngW119r
... Sta.riden:la.
... "11011&
0.05~(1~
1.0 ll"lg'JI [!]
"°"' 0.005-11'.gJ'j (1 ~
"""' O.OS mg-II (1)
"""' 1.0 !Qtli1 {2)
0.03 mgil (2J
O.o5 mg/I (1)
No"'
0.05 mg:it ("2J.
o.~:5moJ.11't2Jo
NoM
0.05 rr.gJI (1~
"'"' NoM
5.0 mgJI (2)
0.1:54 m;ci/1 {2)
""' "'"' "'"' 0.-600 (1]
"'"' "'"' -D.07'5-(1)
1).00~1)
""'" 1).00:5 (1]
l).oo7 (1]
D.600 (1]
0.700 [1]
0.001 (1]
2.000 (1]
.., "[1'.700 (1]
,,. -G.200(1~
10.-0 (1~
10.0 (1j
nono
... 0.100 {1)
~· 250-mgi'I (2jo
1Jlfi"100 ml[~]
"(21
... 500 rngfl (:2}
ui rngi'I m
N~•
10mgll [2J
1.0 rng1' {21-
... ofU5 • e.5 (2lo
... 250 rngi"i (2j.
'"" [1Jn.filt;I
13
<<l.005
<0.t6
0.1
<0.01
"' <0.01
0.02
0.01 ,.
<M3
"' 0.74
0.0> ..
<0.D1
" 0.00
0.04
<0.1)1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
"" "" "" "" • ,, ..
210
<-G.2'
<0.01
<0.03
O.Oll
·~ .,
.,., ...
1).15
<0.006
<0.00
0.00
<0.01 ,,
<0.01
0.01
0.02
0.00
<O.o> ,.
0~2
<0.<12 . .•
0.02
" <0.01
<.0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" "" "" NA
"" "" "" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
,,.,
[un.filt;I ...
<-0.0CtS
<0.1
<0.(1!5
<0.-01
" <0.01
<.1).05
<0.-01
o ...
<0.05
" o.1e
<0.05
<5
<0.01 ,.
<0.Ct5
0.0<
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
" ,,
""' 0.1
<0.1
0.00
<0.00
'·' "
'"' ~Hl1]
<Q.1
<0.-1))5.
<0.1
<0.0:5
<0.01 .,
<0.01
<0.05
<0.01
<0.05
<0.0:5 ,.
(L11
<(LCJ:5.
<5
<0.01 ,.
<0.00
0.1~
NA
NA
NA
NA
NA
"" NA
"" NA
"" MA
MA
"" ..
"" "" NA .. •• NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ,,,,
NA
NA
'"' (un.filt)
M
,,.,
{HI!]
<0.1
<0!J25 <0.1}2:5.
<0.f <.[1'.1
<0.0:5 <0.0:5
<0.01 <0.01 ,. ,.
<0.01 <0.01
<0.05 <0.0:5
<0.01
0.03
<0.05 ,, ....
<0.05 ..
<0.01 ,.
<0.00 ••• <0..01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
NA
NA
NA
""' NA
"" NA
NA
1A
NA
<0.01
<0.CtS
<0.0:5 ,,
G.2~
<CHl5
<5
<0..01 ,,
<D.O>
<0.01
NA
NA
NA
NA
NA ..
"" "" "" "" "" "" "" "" "" "" NA
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1om
{LR"lftl"I)
<D.11)
1om
CHO
<0.11)
<0.00:SG <(1.0050
<0.010 <0.010
<0.oei:;,:J <0.0020
<0.0050 <0.0-c60
<0.50 22:.9
<0.010 <0.010
<O.D10 <0.010
<0.010 <0.01(1
o.1a <0..10
<0.0C&l <0.0C6G
17..3 17."i
-G.n -0.22
<.I)~ <DAG
<5
<0.01-G
13.i
<0..0tl) .... .,
<0.01
ND
"" "" "" ND
ND
'~ J NO
NO
NO
ND
ND
ND
ND
"° ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
NA
NA
210 ..
NA .. ..
·~ NA
•• <0.011)
HU
<-0..011)
<l).Al20
<0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA ..
NA
NA
NA
NA
NA ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" ""
•
•
TABLE 2"· GRQl.MllO WATER OIJAUT ... DATA
CENT,AAL TA,llJ.ISPOOT, INC., Cftil.FILOnE. NORTH CAROLINA
GROUND WATEP. ASSESSMENT AEPCRT -.Jenl,J(lry 1~
WELL M\'li'-1(1 [PAGE 1 a= 2] •
CATEGCfli't PAAil.METER • Orin.'ldog Water
Me tale
~pm)
6aSotJ'NB<U'lrlll1
Acid
ExtrB.c:tebhH
[ppb)
•J.o'ltilSre
Orgarllc:
CoiT!po1J<1ds
l'J:ipb)
ili.Jurruiwn
Ar&enl:::
Bsr1urn
&rytll111n
C&drnJ~
Colol~
Chromium
Cobalt
""'"'" ·~" lood
M1!l9na:slum
Manger.ew
lllicJ.:.BI
fu1!aslum .... ,
$:xlil.Olll
VarwdWm
~~
"""'"' 01-n.-B>ut',pi PJrtllela'lt-[ppb)
Naphtl"leliNut (;ppb}
Bia l2-elhytha1)(1 F1itila1'te (:ppb)
1,l-Olcl"ilorobenHlnit
ii-~l"IB1111'1111.rnna.
fflenol (ppb}
2",+Dlmatl"lylpMnol l',ppbo)
1,"4-Dlchlo.robenHlnit
Vin)1:-Cl"ilo.r1dtt ,,._,,,
Senuna [ppb)
1,1-Dlch1oroetll)'l'en.e {pj:lbJ
1,2-0lcMocob<en.:z:tine-[ppti~
Eth)ibenzana-(ppb}
Meth.)'fwi• ctitorkk
Toluene (:ppb)
1,2,.ol·Trichlorobenune [p,pti~
1,1. 1-lricl"iloroe-than.e
m-X1ien.e i[ppb}
Xjrl~•H (:Ppb)
1,2-Dk:htor-0ethena. (\Mel) (ppb]
CMorofo.rrn (p,pb)
1,1-Dk:hkir-oEid'llltlei
Mi~llane.;ius Cl"ilodde
fsipmf MPN TOlal c:.olifolms
"""" Scilids
Fluorld&
Sc.ufaetanC$ [MBASI
tilil:m1B
Nii:rltia
'" SLllfa'le
Slendaridti
NOM
0.1)5 mg.il. (1~
1.0mg/'IUl
NOM
O.~~,l1)
N~
0.-0S mgil (1}
NoM
1.0 mg/I {2)
O.D3 mgil (2ji
0.-0!5 mg.II (1}
None
0.05 mg.II (2jo
0.1!5 ITl9JI (2t
N""• 0.-GS rne.i'I (1}
None
N""•
5.-Gm;i/l {2'J
0.1~ mg/I t2)
"""' """' """' O.BOG (1)
"""' non.,
"""' 0.-07'5 (1)
O.OO:iil_1)
"""' 0.(!05 [l)
... -0.007 {I)
.., 0.600 {1)
... 0.700 {1)
... (li.007 {1)
... 2.000 ~1)
.. i:J..700 ~1)
0.:200[1}
111.6 (1)
1-0.fl.(1)
11ona
0.100 ~1)
Nona
"" "'"" (2j 1 .--100 ml (H
,. (2j
500 "'"" (2j 2.0 mgfl (2li
"°"' fO mg!I [2)
1.0 mg.II (2jo
6.!5 -6.5 (:2}
"2"50 rngoJl (:2}
""' [l.Jnfilt)
100
0.0< .... •o
NO
311~
0.17
0.1"2
o.ss
200
0.1!5
34_7
~ ..
o.os
1A
NO
,.~
0.00
(1.1!5
NO •o
•O
NO
NO •o
NO
NO
NO
NO
NT
NO
NO
NO
NO
ND
ND
ND
ND
ND
NO
NO
ND
ND
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
'""' coq
ND
ND
0.0>
ND .._,
•D
ND
ND
o.oa
ND
14~
o."'
ND ..
•D
14A
0.00
0.02
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NY
ND
ND
ND
ND
ND
NO
ND
ND
"" "" ND
ND
ND
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"'"" ~Lrllfilt) ....
ND
o.1e
ND
ND
,.~
0.0<
0.0>
0.05
'·"' 0.02
13~
o.~'1
'"' . ... , ..
15~
NO
0.09
NT
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
ND
NO
NO
"" "" "" "' ND
ND
NO
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0/90
(fill.}
e.15
ND
0.11
ND
NO ....
ND
ND
ND
ND
ND
1:2".31
ND
ND
a10 . ...
1!5.2
ND
'"' NT
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA •• ..
NA ••
"'" (ooliHI ,,
<0.01
<0.1
0.00
0.01 ..
0.02
0.02
O.O•
" O.Ol ,.
0.29
0.0< ,_,
<0.01
" 0.0<
O.Ol
<0.0\
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
"" "" NO
NO
r-1"'-NO
Nili. N"O
NA 00
NA. 11
NA. >:::i600
NA 10
NA 210
NA <0.:2
NA. <0.01
NA. 0.31
NA <0.02
NA 7.0
NA 35
IOM
(filt)
<.0.1
<.U-.01
<0.l
0.0<
<(1..01
22
<(1-.01
<(1..01
<0.01
M2
<(1-.02'
12
<(l.01
<(1.02' ,,.
<(1-.01
" 6.02'
<-0-.01 ..
N• .. .. .. ..
N• ..
N• .. .. ..
"" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3121191 3121mi
[t.mfilt) t~IU
·~ <0.01
<0.1
0.05
0.01
22
<0.01
<0.01
0.02 ....
<0.02:
12
o.1e
<0.02:
a2
<0.01
13
0.02
11.01
<0.01
NO
NO
NO
NO
ND
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
NO
NO
NO
ND
ND
ND
NO
ND
" <2
30
130
<0.2
<0.01
1.16
<0.02 ...
"
<O.i
<0.01
<0.1 , ..
<0.01
"' <0.01
<0.01
<0.01
0.05
'"'" " <0.01
<0.02
<0.!5
<0.01
" <0.01
0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
N•
N•
N•
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA .. ..
'"' (tln~l'I}
34
<0.Cli
<0-"
0.1S
<0..0~ .. ._.. ._ ..
0.19
34 .... ,, ...
OA> ...
<0..(1.1 ••• B.11!io
0.07
<D.A>1
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
"" "" "" "" NO
NO
NO
NO
NO
NO
NO
NO
NO
13
<2 ..
710
<-0.2
<0.01
1.15
<0.02
' "
'"' ~It)
0-.14
<(1..01
<0.05
0-0>
<0.01 •• <0.01
<0.01
0.01
"-"
<0.02
" o~•
<0.02
'·' <0.01 ,.
<0.01
<0.01
NA
NA
NA
NA
NA •• NA
NA
NA •• •• .. .. ..
NA •• •• NA
NA
NA
NA
NA
•A ..
"" "" ..
"" "" "" "" •A
NA
NA
----
•
•
TABLE 2"-GAOlmD WATER QUMJTYDATA
CEtfTRAL TRAt.ISPOOT, INC., CHMlOnE, NOOTH CAROLINA.
GROOND WATER ASSESSMENT R.a'OOT -Jenl.P-al)' 11#9~
'NELL MW-10 .;J>AGE 2 OF 2) •
-CATEGCftY PARAMETER • Drlr.ildng W11.111r
Met11ls
jppm~
&sa-/Neutr.al
hid
EKlr .. C18blee.
jppb)
'Jda~I•
Organic
Comooo""•
jppb)
Alumlru.im
i'tr'8nic .,.,m
Ber:ylllum
c.dmlum
Cd::: I um
Quornlum
CobolO
Cc:ipper
I~
l.&>d
Mag11•&i1.rrn
~no:;;i111ne9&
""'" Po"lefifum
SllYllr
Sodium
'J.ena.dh.im
'"" Cyanide
01-1\<Birtyt f'll!halllle {pptl~
Naphltl"1en& [ppb]
Ble i2-&thylhoe~l'i~ Phthel&ta-[ppb)
1 ,:l-Dlctilorobel'tU!ne
N-tfitro8odlphoenylemlna
F11e.nol [ppb)
:2",4-0lme-"lh)'lph!IC'lol {p_pti~
1 ,4-0h:t1tOA»e1Wmt1
Vin:;I Ctilor\die ,,,_M
8enZ&il&i (ppb}
1 .1-0lc:tiforoeth~• l'siPb)
1 ,:2-0lctilorobemen.t (ppb}
fth}4be~l".ll [ppb)
Meth)"9ne-CtilOlid•
Toh1-ene [ppl>)
1 .2.A-Tflc:Mor-obwwrin.e {ppb]
1 ,1. t-Tlicl!IoroethU11t
m-X..,ien&-f.opb]
X:;le.n•e {p_pti~
1,2-Dkhlotoe-Uven.e {to~1) [ppb)
Carbon OlsulHde
Chforo1orrn [ppb)
1.1..0ietooroed'lane
Misoall&neoua Ciilorlde
(pp.m) UP.ti! TotEil CollfoITT11
"°'°' Solido
Fluoride
SwtaC"lsnts (MBiliS) .... ~ -· pl<
Sut1ue
:S"leridards
•oM
0:05 m;ill U)
1.0 rrgi'J (1}
"""' O.oo:5 mg-II [1]
"'"'' 0.00 m;;il'l it~
No~
1.0~~ (2}
0.00 mg/I i2;1
0.05 mg/I i1)
NoM
0.0!5 m.g/I {2)
o.~s mg/I J2)
NoM
o.~m.g/lf1)
NoM
NOM
!S.-O~/l~2't
0.15'1 mgill (2)
~· ~· ~· 0.-800 {1j
~· ~· -O.OP-3 {1)
0.002(1}
~· ... .0..005 {11
... -0.oo7 {11
... -CHIOO 01
... 0.700 i11
... o.oo7 it~
,.. 2..000 ~H
• o:roo (1}
.. 0..200(1]
• t-0.0 [1]
.. t-D.O (1]
• 11on1
0.100 (1]
NoM
:250 mg,11 {2jl
1 per 100 ml (1}
,. (2)
500 m.g/I {2)
2.0 mg/I {2)
NOM
10m;:i/l~21-
1.0 mg/I {2)
e.!5-e.ii {2ji
:250 mg/I {;211
'"" (!.!nHt"I}
0.0
<0.005
<0.00
0.07
<0.01
"' <0.01
0.01
0.00
7.0
<0.03
" ....
0.02
u
<0.01
13
om
·~2
<0.01
"" ..,
ND
NO ..,
NO
"" NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
NO
12
17 ..,
240
<0.:2
<D.01
rn1
-o.1e
7
"'
,,.,
~Hit) .. ,
<0.005
<O.as
0.0<
<0.tli1
"' <0.-01
<0.01
0.00
0.00
<0.03
" <0.01
0.02: ...
Cl.02' ,.
<0.01
Cl.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
...
~-unftl"I)
'·' <0.005
<0.1
<0.00
<0.01 ,.
<0.01
<0.00
0.02
2.7
<0.00 ,,
M7
<0.00
<5
<0.01
" <0.00 , ..
ND
•D
"" "" NO
"" "" "" NO
"" "" "" NO
NO
"" NO
NO
NO
NO
NO
NO
NO
" NO
NO
" "' 10
""' 0.2
<0.1
1.2
<0"'
1.2
"
-~"
~'
<0.00:5
<0.1
<0.005
<0.01 ..
<0.D1
<0.D:S
0.02
·~ <0.1)5
" 0.00
<0.0:5
<5
<0.0l ,.
<0-.05
0.11
"" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-{1..111filt)
" <0-.02!5
<0.1
<0.-D5
<0.-01 ..
0.01
<0.05
0.01 •.•
<0.05
" 0.00
<0.05
<0
<0.01
" <0.05
0.02'
<0.01
ND
ND
ND
•D
NO
ND
NO
•o
ND
NO
ND
ND
NO
"" NO
HO
NO
NO
NO
NO
NO
NO
NO
NO
NA
NA
NA
"" NA
NA
NA
NA
7.2
NA
~ ..
iHllJ
<0.1
<0.025-
o::-D.1
<Cl.05-
<0..01
"' <0.0\
<0..05-
<0-.01
<0.05-
<0.00
13
<0.00
<0.05
<5
<0..01 ,.
<0.00
<0..01
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
"" "" JtA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
,_
[unfil~ ""'" [ifl)
3.2 0.1
<0.0050 <0.0050
O..Q3.1 O.O:i!3
<0.0020 <0.0020
<0.0050 < O.<:CtSG
22".2 23~
<0.0\0 <0.010
<0.010 <0.010
O.OUio <0.010
:!; <[).10
<0.0050 <0.((151)
13.31 13.a.
"""' <0.<l40
<5
<0..010
" <OAJ.10
<0.020
<O.-G1
NO
ND
NO
NO
ND
" •D
ND
"" "" "" "" "" NO
ND
"" NO
NO
NO
NO
NO
NO
NO
NO .... .. ..
310
"" "" "" "" .., ..,,
<0-.01-0
<0.040
<5
<0.01-0
13.a.
<0.010
<0.0:i:'D
<0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" "" "" NA
"" ....
NA
NA
NA
NA ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
•
•
M\'il-1:3
CATEOCf'l'I'
Me'£119
(ppm]
80'"1E!/fft11..llr.el
"'" E~lr.a~bJes:
{ppbj
IJdatllr;t
Organic
CorniXl'-Jnda
{ppb>
Mi~11!n&OLPO
(ppm)
TABLE 2. GAOOND WATER QUALITY DAT A
CENIBAl TRANSPOfll. ltfC.., CHARLOTTE, NOATH CAROON,i,,
GPIClU.NCI WATER ASSESSMENT AEPCftl -knuary 1'9Q.t
PARAMETEFli
Ah.irriiium
Ar•nlc.
Sari um
Beryllium
Cad ml um
Calcium
Chromium
Co belt
Copper
Iron
Dritild~ W.eler
Sa,ndarcl•
N~•
0.(1.5 IF9f1 ~1)
; .0 rngil (1j
"""' 0.005 m;i!l {1)
No.,.
O.M 1r9i'I (1 j
"""' ~.Omg.~ (21
5,ig1
[un.fillJ
" <0.CJ.1
<0.00
0.1
<0.01 , ..
0.22
0.07
0.13.
211
"" M09nitsiium
0,0.3.lf'9/1{2ji
1),(15 m;:ill (1 j 1??1
M011gari&tl9
N-1
PotiissJ1.1m
:Si Mir
Sodium
'1111111\adlwn
~~
Cyanidit
Dl-l\-81rtyl Phtf11111la'le [ppb)
Naphthakina {ppb}
Bla. [2-t'lh.y!he.Kyt) Ptililla'bte (ppb}
1 ,3-Dlclllorobemlflna
N-Nlb'oilOdlphtin!L'iunln&
F111enol l'ppb)
:2',-41-0lrMth.)fphenol [ppb)
1,4-Dlcllfo~ne
VM)'I Cillorli•
"'""M BaniBfle l'J:lpb}
1, 1-0lcfilorootthylei'lii (Wb}
1 ,2-0lctilorobertzene {pph~
E:th.~ti...nuine {ppb)
Meth}hne Chk>rid•
TolLMIM {p,pb~
1,2,4-Tilclllorobenuine (ppb)
~ ,1,1-Trlcllloroetlla:n11
m-Xylane-[pp'b)
X~tbH· {p,Pb~
1 ,2-Dlchloroa-'llwne-('IO'Lal) tpsib}
Chlorol!orm fppb~
1 , ~ Dkhloroetlume
Chlorlde
MPN Tota.I: Call:ltlrrn$
Color
Solid$
Fluorklao
Surfactiin1a. {MBAS}
Nim.tit
Nllif'lfl
pH
su1r.,,1e
N'"" CHl5n:gil (2)
0.1Smgfj ~
Non•
1),00.~(1~
Nono
Nono
S.Omg.il (21
0.15"4 mg/I {2]
~· ~· ,~.
O.IJOO ~1j
"~' -~· 0.07fi ~1~
"'" ~· O.oo:i (1}
1).007 (1}
.. {U;OO (1}
... 0.700 (1}
... 0..001 (1]
... 2..000 (1]
... (1.700 [1)
... (1.:200
111.0 ~1j
'"' 1D.O {1)
• ~M
... (1-.100 [1] ""M 250 mgll {2)
11*' 100 llll ~1)
"(2)
t 500 mg/I {2)
VJ mg/I (2)
"""' 10 rrgll ~21'
1..0 mgll (2)
... .fl.5 -&.5 f2)
... :::5(1 m;;i11 ~:<:)
..
(1..12
0
<0.01
22
0.13.
<OJJ.1
NO
NO
NO
NO
NO
NO
NO
NO
ND
ND
ND
"" NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ..
'"' "' ,.,
<{li.2
<0.01
0.02
<0.02
'·' "
,,.,
~·)
<0.1
<10
<0.1)5
0.03
<0.01 .,
0.00
0.01
0.04
0.00
O.Ol!
" 0.0>
<0.0:2'
u
o.o>
" <0.01
<0.01
NA .. .. .. ... .. •• ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
,,.,
(Un.flit) ..
<.0.Ql)S
<0.00
0.2!
<0.01
" o ...
0.00
o.1e
IT
<0.03 ..
'-'
0.22 ...
<0.01
·~ 0.21
o ...
<0.01
ND
NO
NO
ND
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
NO
NO
ND
" = ..,
'" <0.2
<0.01
<0.00
0.05 ...
"'
,,.,
( ...
<Cl.1
<0000
<O.-Oi5
0.04
<0.01
118
<O:G1
<O:G1
0."2
0.17
<0.00
"' ,.,
<0.oll-2 • <0.61
" <0.01
<0.1)1
NA
NA
NA
NA
NA
NA
NA •• NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
..,
(l.JnHll] "'"' ffllo
-35 <0.1
<0.005 <0.005
0.3 0.1
<0.o5 <()..OS.
<0,01 <0.01
1'20 1-'0
0.26 <0.01
<0.0S <0..0S.
0.18 <0.01
'52 <O-Cl5
0.(19 <0..0S. .. " 2.2 1.l
D.12 <O.o5
' <5 <:0.0~ <0.0\ " .. 0.18 <0..o5
MO
"° NA NO NA
NO NA
FOO NA
00 NA
NO NA "° NA 00 NA
00 NA
ND NA
.ND N,i,,
NO ""
NO ..
ND ..
NO N'A
ND HA
ND t.IA
ND NA.
ND ;NA
ND t.IA
ND ;NA
ND NA.
ND ..
81 NA
<10 N'.A
10 N'A
310 N'.A
<0.1 tu.
<0.1 N'.A
<0.5 N'.A
<0.5 N'A
7.:3 NA
» NA
.,.,
[un.filt) ..
<0005
OA
<0.05
<0.1)1
'80
0."3
0.07
0.30
" 0.13
BO
••• '·' <0.01
" 0.2S
'-'
<0.01
NO
NO
ND
ND
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
NO
"" NO
NO
rro
"" "" NO
NA
NA
NA
'"' NA
NA
NA
NA
'~ NA
.,.,
ffilO
<0.01
<.0.00:5
<0.1
<0.05
<0.01
100
<0.01
<0.05
<0.01
0.07
<0.05 ,.
1.3
<0.ll5
<5
<0.01 ..
<0.05
0.0:3•
"" ..
N• .. ..
NA .. .. .. .. .. ..
NA •• NA
NA ..
NA ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
....
~·.,.
,~ ..
""'
59.7 <0.10
<-1),0050 <0..oo&l
0.33 0.14
<-Oi.0020 <i0-.0020
<-0..00SO <(1.0050
146 151
0.48 <0..010
0.<165 <0..010
0.2e <0.Cl10
7o!!.3 <0.10
0.034 <(UX150
n.3 42.e
'2:.a. :2'.2
0.:<5 <0-040
e.e. 5.7
<0.Cl10 <0.010
31.9 32.5
0.22 <"0.010
t.5 0.(123 FOOND IM UETHOO BLANK "TCl.0:3 PPM
<0.01 <0.D1
ND t<A
ND N'A.
ND NA
t.ID N'A.
ND N'A "° NA
ND NA
ND .N'A.
ND HA
ND NA.
ND NA
ND NA
ND NA
ND N"
~D N"
tfl) NA
00 NA
NO N•
NO NA
00 NA
r.2D NA.
ND NA.
ND NA.
NA NA
NA NA
NA NA
710 NA.
NA NA.
NA N"
N,i,, NA.
NA. N,i,,
IJ.il N"'-
NA NA
•
•
TABLE :2 • GROtmD WATER a.JAUTY DAT ,i,_
Cf:-ltTRAL TRA.NSPOA.T, ~C .• CHARLOTTE, NORTH CAROLINA.
GROOND WATEFI ASSESSMENl fiEPORT • J&ntiB.fY 1 ~
MW-le
C"'-TEG.Cft'I'
Me-1als
(ppm~
BaH!Neutrel
"'" Extr~ble'i'
{ppO)
'l/ole.tile
Ogenlc
CompoiJrnh
{ppO)
PARAMETER
A.Jurrinum
Ar&anlc-
8.:::rh.:m
Beryllium
Cad ml um
Cak:lurn
Chromium
Cobell
CopPoSr
"'" '"" MaogCleilum
MangEl.ll&iM
t.11™1
Pouis:Slum .... ,
Sodium
v.,,rwu:llwn
~no
Cyeillde
Ol-.n.-Bu1)'1 Phttidltti (:ppb)
Nepbttielene ~)
Bia ~2-e1h)'ltiio;yl} Phthal!ltei l'Jlpb)
1.-3-Dkhloroberlz.,.,"'
N-t.ll'll'G:90dlpti•n)brrinit
Ptnriol {ppb)
:2,-4-Dlmettil!'lphel'IOI (Jipb-)
1,-"l·Dlchloroberlz1ti11a
Vlnl!'I Chlorid•
"°'""'' Serw:in• l'ppb]
1,1-DJch~M {pj)b]
1,2·D.lchl01obenzena-[ppti~
Elfljl'iber'lzKI• (ppb}
Metll:-fen• Chklrida
Tol'tl1H111 (ppb}
1.a4-Trlehlorobenz-ene [ppb}
1.1, 1+ lrlchlo1oetlw1114
m-X:;len• o[ppb~
Xylen" l'ppb]
1.2-0lcli~roittlena-~
Carbon Dlwlfkle
Ctiloro!orm (ppb)
1.1 Dlchloro&'IMMI
Mi$08llaneor.11; Ctilorid"'
{ppm) MPN Tote.I Coll'kcrna-
Colo<
Solids;
fluorklit
S-urf&c'L!lnta {MBAS]
t.liwte
Nltr11e
'" Sulfa1e
,. DJ1nklng Weller
• Stander-de ·----
N~
0.05 !Tl9ll ~1)
1.0 ma-II [1]
Nono
0.00511"9/l {1)
NoM
0.0:5 rrl9J\ (1~
Nono
1.0mgll (:2]
0.03 mgft (~
0.0:5 mgli: (1 ~
Nono
O.CtS mg.I\(~
0.15 mg.it(~
Nono
O.O:Srng.i\(1}
NoM
Nono
15.D mg/I {2)
o.~154 n:gll (:<:)
OOM
"'"' -0.-800 (1)
no no
OOM -0.o7'5-{1]
0.002 -o.oos {~)
O.oo7 (1)
t o..600 {1)
... 0.700 (1)
.. 0..CI0101
.. 2.000 ~1)
.. 0-.100 (1)
0.200
10..0(1]
10.{l-{1]
OOM
0.100 (1}
.,,~
250 mqll [:2J
1 per 100 ml. {1)
" (2J !500 mqll (:2]
2.0 mgll [:2}
Nono
1011"9/'I ~2)
1.-0mgll [2J
15.5 • &.5 {2)
250 lllJ/I {2)
·~· [unfilt.}
••• <0..01
...;;:;..os.
·~ 0.01
" .. ,.
<0..01
M1 ,.
om
11 .. ., ...
·~ <0.01
10
<0..01
G.72
<G.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
•o
ND
ND
ND
ND
ND
ND
ND
ND
"" "" "" "" • "" ..
220
<0.2
<M1
<0..02 ...
1.1 ..
5.I01
ltiU
<0.1
<0.'(111
<0.05
"" <0.01 ..
0 ...
0~1
0.01
0.0>
<0.0:2
11
0.115
<0.0:2
3.4
0.02
" <0.01
<0.01
NA
NA
NA
NA
NA ..
NA
NA
•A
NA
NA
NA
NA
NA
NA
NA
"" ...
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
'"' [unifill]
"' <MOO
<0.05
0.05
<0.01
" <0.01
<0.01
0.03
u
<0.03
11
0.15
<0.02:
<0.01
" <0.01
0.22
<0.01
ND
NO
ND
ND
NO
ND
NO
NO
ND
ND
ND
ND
ND ..
ND
ND
"" "" NO
ND
NO
ND
NO
NO • "" .,
300
<0.2
<0.01
<0.03
<O.O:i!'
'-' ..
"" (fih)
<Cl.1
<0.000
< 0.(IO
"'' <0.'1)1
50
<0.01
<0.61
<0.01
o ...
<0 ..
" ...
<M2
' <-0.0-1
" <0.01
<-0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ..
"" "" NA •• •• NA
NA
NA
NA •• NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
.,.,
(UCll'iI1}
<0-.1
<0.005
<Cl.1
<.Cl.05
<0.01 ..
<0.01
<D.05
<.0.-01
o.~si
< 0."05
10
0.13
< 0:05
<>
<0.{)1
" Cl.4:2 ....
"" "" ND
ND
ND
ND
ND
NO
NO
NO
NO
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
1 ..
ND
"" " <1
10
<0.1
<0.1
0.02
<0.05
7.0
"
...
(lilt.]
O.<
<0.005
<.0.1
<0.00
<0..01
"" <0..01
<0.05-
<0.01
(Jo.13
<0.00
" ~" <0.00 ••
<0.01 ,.
<0.00
·~
"" NA
"" .. .. .. .. .. ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-[un.filt)
<0.1 .,..,,
<0.1
<0.01
<0.01 ..
<0.01
<0.05
<0.01
0.21
<0.0!5 ,_.
<0.05
<0.()15
<5
<0.01
" <0.05
"'' <0.01
ND
ND
ND
ND
ND
ND
ND
ND
"" ND
"" "" "" ND •o
NO
ND
ND
ND
ND
ND
ND
ND
ND
NA
NA
NA
310
NA
"" NA
NA • NA
"'' ~mt.)
<0.1
c(l.005
<D.1
<0..01
<0..01 ..
<0..01
<0.00
<0..01
<0.00
<0.00
" <0<>0
<0.05 ..
<0..01
1S
<0.00
<0..01
"" "" NA ..
NA
"" "" ...
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ..
NA ..
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ..
,,,..
{u.n:filt)
<0.10
<0.000 ·-
10/ll3
{fill)
<.0.10
<0-'50
0.001
<0.00:otl <0.00:i!O
<0.0050 <0.((tSO
5:5.e :Se.
<0..010 <0..0tO
<0..010 <6..010
<OJJ10 <6..010
o.~ <0.10
<0.0050 <0.0050
11.9 1:2".:2
0.14 ··-<5
<0..010
"
0.13 ··-•• <(1..010
14.l!o
<0.010 <0..010
0.(1.:2 <0.0:i!O
<.0.01 <-0..01
ND NA
ND NA
ND N"
ND NA.
ND NA
530 NA
t-!IJ. Ni'I.
NO NA "" .. "" "" Nil NA
,ND .N'A
iNO HA.
;NO HA
ND NA
ND NA
ND NA
ND NA
ND NA
ND NA
ND NA
ND
ND
ND
NA
NA
NA
"' NA
NA
NA
NA
1.1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA ..
•
•
WELL MW.17
CATEGORY
Metals
(ppm)
BeiseJNeutral
Acid
E:dfactabl..;.s
{ppb)
Veile.tile
Qr.ganic
CompOOf'lchl
(pp!>)
Mis-c:ellaneous
(p-,pm)
TABLE 2 · GROUND WATER QUALITY DAT A
CENTAA.l TRANSPORT, INC., CHARLOTTE, NORTH CAROLINA
GROUND WATER ASSESSMENT REPORT · Januery 1994
PARAMETER
Aluminum
Ar:senie
:Barium
Betyllium
cadmium
Carcium
Chrc:mium
Cobalt
Cop.per
'""' Leed
Meignesium
Man-ganese-
Nickel
Potas.sium
SilYer
Sc:dium
V.&na.cflUm
Zinc
Cyanid-e
Oi-n-&rtyl Phthial.ate
Neiphthalene
Bis(-2-e'lhythe:qrl)Phthe.late
1,:]..0ichl orobenzene
N-Nitroscdiphen)'leimine
Ph"™"
2,4--Dimel:h~phenol
1,4--Dichlorotiemene
.,qnym dilcride
A.cetone
Benzene
1, 1--Cictiloroethylene
1,2-Dictl1iXob-emene
Bh)'lbenzene
Meth'f1ene Ghlorlde
Toluene
1,2,4·Trichlor00enze11e
t,1,1--Trictilor~e.ne
m-Xylene
Xylenes
1 ;2--Dichloroethene-(total)
Chlorotorrn
1.1 Dich!oroetMl'Je
Chloride
MPN Total Cdirorms
Cd0<
SOiids
Fluoride
&lrf.flctants (MBAS}
Nitrate
Nitrite
pH
Sulfa!e
Drinking We.teir
Standards
Nooe
0.05 mg/J (1)
1.0 mg/I (i)
None
o.oos "'lln (1)
Nono
O..OS mg/I {1}
Nono
• 1.0 mg/j (2)
o.oo. mg.II (2)
o.os mgfj (1)
Nooe
0.05 mg/1 {2)
0.15 mgn {2}
Nono
0.05 mg/l {1)
Nono
Nono
5..{J mg.JI (2)
0.154 mg.11 (2)
none
nooe
none
• 0.600 (1}
"°"" """" oono
0..075(1)
0.002{1)
nano
0.006 (1)
0.007 (1)
0.600 (1)
0.700 (1)
0.007 (1} ··= (\) ... 0.700 {1)
• 0:200{1)
10.-0-(1)
10.D (1)
nano
0.100 (1}
nooo
250 mg-A (2)
1p-BI100 ml (1)
10 (2)
500 mg.I (>)
2.0 mg,I\ (2)
Nono
10 mgfl (2)
1.0 mg/I (2)
6.5 . 8.5-{2J
:l50 mg/l (2}
>193
(OIQ
<.O.C<l6
0.1
<-G.05
<D.01
75
<0.(11
<0.05
0.0I
0.3>
<.0.05
49
0.86
<D.05
"' <0.(11
" <0.05
0.01
ND
ND
NO
NO
ND
ND
ND
ND
ND
"' ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
31
ND
NO
" <10
10
1100
<(1.1
<(1.1
<D.06
<-0.05
0.0
50
2193
(unFm)
91
<0.00S
0.3
<.0.05
<(1.01
'" D.22-
0.1 ..
91
0.57 ..
'·' 0.09
19
0.01
34
0.5'!
0.33
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
"" NA
"" ......
NA
NA
6193
(unl"iU)
,.
<0.005
0.6
<.0.01
<-0.01
'"' 0.26
0.1:3
2.6
130
0.71
91
2.4
0.14
13
0.01
34
0.63
0 . .119
<.0.01
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
6
ND
ND
ND
ND
ND
ND
ND
ND ..
ND
NO
NA
NA
NA
1100
NA
NA
NA
"" 6.6
NA
6193
(Mt)
<O.D~
<Ci.005
0.2
<.0.00
<0.01
'"" <0.01
<0J)5
<0.01
<0.05
<0.05
64
l.3
<.0.05
<5
<0.01
" <0.05
<0.01
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
"" "" NA
NA
NA
NA
NA
10/93
{oolilt}
10/93
(~t)
88.5 <-0.10
<0.0050 <O.o:&i
0.44 0.16
<0.0020 <0.0020
<.O.C050 <0.0050
1 t5 107
-0.18 <0.o-10
D.09:3 0.-01
1.7 <0.010
90 <-0.10
0.35 <G.0C60
88.2 .fi7.8
2.3
0.093
9.6
<0.010
J>.3
0.39
0.34
<0.01
ND
ND
ND
NO
NO
51
ND
ND
ND
""" ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
37
ND
?Jl J
NA
NA
NA
740
"" "" NA
NA
6.3
NA
\.5
<0.040
<5
<0.1)11)
34.3
<G.010
<G.020
<0.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
"" NA
NA
NA
NA
NA
NA
•
•
TABLE 2-GROUND WATER QUALITY DATA
-CENTRAL TRANSPORT, ™C., CliAA.lOTTE, NORTH CARCUNA
GROUND-WATER ASSESSMENT FIEPCflT -January 1994
l'iELl MW-18
G-ATEGa'l'I' PARAMETER .. o..tnklrrg-W-111er .... . ... ,,,., "'" • Standud1 (llnfilt) ~·) [unHll] ~Hit) ·----
Me!!il! Ahrmlnum . -· .. <0.~ 0.45 <0.10
~pm) ,,..,,~ .. O..o5trgi'j (H <0.00:5 <0.005 <0.00SO <0"""
8srlum • 1.0 mg/I [1] ·~ <0.1 0.-073 '·°" .. _m . ·~ <0.01 <0.00 <0.0020 <0002)
Cadrrlum • 0.005 ~(I ~1) <0.01 <0..01 <0.0050 <0.0000
Calefum • "°"" ,. .. .. ~ "~ Ctirordum • 0.05-lllgl\ (1} o.~:2 <(t.01 0.022 <0.10
""""" • NollB <0.CIS <0.0S <0-010 <0.010
""""' • 1 .0 mg-II {2) 0.115 <G..01 0.012 <0.010
,,~ • o.03 mg11 RI .. <G.05 ' 0.41 , ... • 0.05 mg.~ (1] o.~e <0.00 '·""" <"""""
Magnellfi:.im • NorM " ,. 14.l 1~•
Mang&nE!<M • 0.05 rngJI (:2} u 0.22 ·~ 0.21 • N<k>f • o.~5 mgi1. [:2} 0.00 <O.O• <-0.040 <0.{.\4(1
Pota-ssium • Nonu ,. .. 15.-4 ,.,
Sil..-ff • 0..05rr.gf! (1} <0.01 <0.01 <0.010 <O.Cl10.
SodWm . """' " " 121.4 ,,,
'll~adh.1m . """' 0.13 ..... <0.010 <(1.010
noc ~ '5-..0mgfi[:2} ·~ 0.21 .... ..,,,
C~unld"• • G..15-4 mg/I (2) <0..01 NA <0..0-1 <0.01
Ba.se,'il•u'll\\I Dl>f'l-Butyl Pl"ilhaJ.atti . ~· NO NA NO NA
"'"' Naph.thalen• . ~· NO NA NO NA
E~~bliti BH:[2-a-:tijtlt-.e:icy1)Phttiarai:. • MM• NO NA NO NA
(Wb) ~ ,3-Dlcillorobaruffle • G.'500 (1} NO NA NO NA
H-Nltro80dl,phan~ll'ill• 'Mno NO NA NO NA
""""' • nont-ND NA 000 NA
2)1-0lrnetliylpllenol • nor'.18" ND NA ND NA
1.<1-0lclilo.roberu-me • 0.07S (1] ND NA "" NA
IJoh~llil Yl~-cl"i'klrld'• • 0.002{1) NO NA "" NA
Orge.nle "''""~ '" MOMI ,,. NA Nil NA *"FOOND IN flEUl BL..N.IK AT 11 PPS
Com~ndi Bfilzmu-'" o.-r:os (1J NO NA NO NA
~pb) 1.1-0lctilwoetli~noe ... 0.001 [1) NO NA NO NA
1.?-0lchlcrobenz.an& ... 0.600 (1) NO NA NO NA
Ethylb&nzer11t ... 0.100 (1) NO NA NO NA
M:e~M ctllorlde ... 0.001 [1] NO NA "" NA
Toluene ... 2.-000 (1) • .. NO NA • 1;2,4-T.rtc:hloroberizwiit ... 0.100 (1) NO NA "" NA
1.1,1 +Triohloroetfu111u-... O.:<n0{1) NO N• NO NA
m-X.yhme ... ~0..0 ~1) NO NA NO NA
Xy1er.e:i .,. ~Cl.O ~1) NO N• NO NA
1,.2-0idiloroetliene (tobsil} . """' NO N• "" N•
Ctilororo1111 * 0.100 (1] ND NA "" NA
1.1 Dkl!loroett:.ane .,. non.a ND NA NO NA
Misoellanaouo&; Ctilolfde ... 250 mg/1 ~2) "' NA NA NA
i'sJpm] MPN T-c1el Coi"Forme "' 1 per 100 lllL (1) >1000 NA NA NA
Col~ ... 15 {2) 00 NA NA N•
Solldu. ... 500 ~/1 ~2) "" NA 290 NA
fluoride ... 2.0m:;i/1 ~2) <0.1 NA NA NA
"8'Jrfaete.nts [MBASj • Nooo <0.1 NA NA NA
~llU18 ... 10 mgfj [2J <O.CIS N• NA NA
Nitrite ... ~.OrrQ/l (21' 0.-G7 NA NA NA
'" ... 8.5-+;!!.5(211 1.7 NA 7$ NA
Sulfa1e • 2:50 m;;ilm C21' .. NA NA NA
• • I . ,.
,--·
..,,
.... . -
N.i Oepartmerat or Srwiloamc:nt,
l lcalUi. & Natural l\l:soutce5
Solid Wule M•nap:ll\c.nt l>Msion
SA....LE ANALYSIS REQUES'il' • State Labo,.iory ol PuW< Health
P.O. Bo. 28047, 306 N. Wilmington 5,.,,.,
Raleigl>, North Caroli•• 27611
Site Number /.ltQ o If(, lt(?:<:;'"fO Field Sample N~ber __ __,g'<::..L'f_!f'-'-/ _____ _
Name of SiteJ,wtna / 701."1.)+A?..-.f Site Location. __ _._G,..?h"'..a"""'-"/~:;..:.:#_.r __________ _
Collected By Sr;:Jf;.c;F-::-ID# I 2-Date Collected &/ffa..S T"1111e /3):)
' I
Agency: ~Hazardous Waste _Solid Waste . Supcrfund -.
TCLP Compounds
San11ple Type Inorganic Compounds Results (mg/I)
Environmental Concentrate Comme11!s Arsenic -Barium -__ Ground water (1) _solid (5) c::rF!l -Cadmium
i/ Surface water (2) -Chromium
_Liquid(6) Lead
-Mercury
_Soil (3) _Sludge (1) -Selenium
Silver
_Other (4) i -_Other (8) -
I --Organic Chemistry Inorganic Chemistry -
Parameter Results(mg/l) Parameter Results(mg/I) (a1JOttJ 0l'gllnlc Compounds Results(mg/I)
P&T:GC/MS _L.Alsenic ~-~ bcn=ne
_ Acid:B/N Elct. -<L. Barium -carbon tetrachloride
MTBE ..JL...Cadmium ~0-~ ~?. -chlordane --.,/ Chloride ..L.!;';> ' chlorobc=ne -::Z Chromium (Q-~ ----chloroform
-,/ Copper <:'.b,Q~ -o-cresol
. ~Fluoride Le. 10 m·cresol -7Iron 9~.~--= p·crcsol --7Lcad cresol
---:7' Manganese ~{l· o~ = 1,4-dichloroben=ne
-_L..., Mercury ~=-/J.12-l~ _ 1,2-dichloroethanc
-...L Nitrate 41.0Q _ 1,1-dichlorocthylene ... Selenium < e> ·ai:2.S: _ 2,4-dinitrotoluene
_,.. Silver L..o.g~, _ hcptachlor
Radiochemistry _IL Sulfates L..~
'
hexachlorobcnzcne ' ----~-vZinc <~,Q,(t hexachlorobutadicnc
P•ramet~r Results (PCl/I) /pH -hcxachlorocthanc ,~ I
"' I _ Gross Alpha ;:? Conductivity l'• l~ t::. 'I: '°"' = methyl ethyl ketone
Gross Beta TDS I
' ' nitrobcnzcne -L .-:sa1;....,. ...:. I ! = pentachlorophcnol
.i-"""&il"-"'<: l'-".-rt"• } ..L A!umiMm (4. Ii" _pyridine
~fieF ialemr _, v Anii!Wj c o.D<P.s:: _ tetrachlorocthylcne --(' '2-d:-! :ii ~~ _ trichlorocthylcne
1 l!ai a:netca Results (Cet,flOOml) ,/ ' ~ 4, f _2,4,S-trichlorophenol
, Th... ll; "'"' ~0.{X)J__ ....Li LO•=j' _2,4,6-trichlorophcnol ~~ ~~o..~ v m~ ... --,.·~ s:_ ~· 'I _ vinyl chloride
/''\J .• ·,.t..1 v A,/k;_I L..o.cSi endrin
v v fofo..,3;~.,, 4\ --
' lindane
' Date Received Reported by = methoxychlor
_ toxaphen~
Date Exlradccl Dale Reported 1 _2,4-D
010221 Jllll 10 9 3 __ 2,4,5-TP {:!>ilvex)
Date Analyzed Lab Number ' IJllS 31~1 (l(e,,;..,d 2/91) --
·'
N.t.. Ot'p:trtrnt:.nt of &vimnmentt
Ht:.:i11h, &. Naturnl Re$0urccs
1 " Solid WoN1c Ma"agcmc::nt Division
SIPLE ANALYSIS REQUEST • St•u: l..11tJon1ory of Puh1ic lle•ltli
P.O. Dax 28047. 306 N. Wilmington StR!el
!tJolo:;gh, Nonh C.rollno 27611
Sile Number /,Jr',,r; on It(? <""10 Field Sample Number ___ -'d"--'-9_.j~Z=---------
Name or Site Co1 Im i 7ai .... -;;..,r f Sile Location Of.a,,./.;, II~ -I ·-~__,,.,,,,_,,,.._...:.= /'°'"""-~~---~-----
Col1" cted By ..!{zyl/g~) ID# / L Date Collected &.!f;/'1? Time /07fS-
' '
Agency: _::t_ Ha:z:ar<lous Waste _Solid Waste _Superfund TCLP Cornpounds
Sample Type lnorgank Compounds Results(mg/I)
Environmental Q!neenttate Comments Arsenic -Barium
/Ground water (1) Solid (5) II -Cadmium --Chromium --_Liquid (6) Lead Surface water (2)
-:----Mercury
Soil (3) _Sludge (7) -Selenium -Silver -_Other (4) _Other (8) -
'
'
Organic Chemistry Inorganic Chemistry ! ,...--
Parnmeter Results(mg/I) Pata meter Resulu(~l)lmr "·It) ,Organk Compounds Results(mg/I)
P&T:GC/MS _LAtsenic o.o I ' benzene
-Acid: B /N Ext. ....i.L Barium Q..Q' r-carbon tetrachloride
MTBE ....£.... Cadmium t Q,oq ;:1 chlordane -./Chloride := chlorobenzene -£oa~· -~Chromium i--chloroform
-...!:'.'.:,..Copper 1 __ o-eresol
-...,. Fluoride .L.. o. \0 , m-cresol
-:7 lroo 1--O<f;,s ' p-cresol
-:7Lead
'
1
-c;:reso1 -.-....:::_. Manganese /), ~ :r: I 1,4-dichlorobcnzene -'
-......:.... Mercury <a.coos-1--1,2-dichloroethane ,_
-_£_ Nitrate 4\.Cc : __ 1, 1-dichloroethylene .,, Selenium Q.Qo 8 _ 2,4-dinitrotoluenc
--::::;-Silver .L..o. c.=. _ heptachlor
Radiochemistry _J.L'. Sulfates If'/). (.).£_ -hexachlorobenzene
''""'-··--v Zinc hexachlorohutadiene
Pura meter IResulu (PCl/I) ...,./pH I.] -hexachloroethane
_ Gross Alpha _J,!'.. Conductivity ::i I~ r=:::= si ii!!::, -methyl ethyl ketone
Gross Beta TDS
..,
nitrohenzene -_IL. .... S<d; .... ~ \ ""'\-= pentachlorophenol
T:•'"":i'>"'~ (.<..<.·"'· ) .,r' dlcil!l;~l!J. <;,.o_, t.? _pyridine
<-v AnPMW <o.oos: __ tetrachloroethylenc ·MteF9 Hll9fe' < Q.Co2, trichloroethylene ---~~ , P•mnnder-~••Ulls-(6ol{-100ml) ,/ . ' t'7. i __ 2,4,5-trichlorophenol
,"tho.\l • .,.m < Q.Q6 ~ ,..._._
•,/ ...:.o.o~ __ 2,4,6-trichlorophenol
" ~-ad•1.1"" < O. lJ I v m .... ~.""' ll. 'd::,. __ vinyl chloride . , ;"·,, ... 1"'" <I V A, .'lu I -1...0 _ o.S:. cndrin
'.' 'v f,,i..~,,~ ... .3 --lindane
Dale Received Reported by = methoxychlor
' _ toxaphene
Ihle Ex1rat1cd Date Reported 2,4-D
010222 .JU~~ 10 93 -2,4,5-TP (Silvex)
l)al c Am1lyzcd Lah NumlJer
Ill IS Jl'/I (ll<v;<Od ?/'II) -
ti.',~ n~vanmcnr or r .... vin;H"lmll!nt.
llc::illh, & Nalural Rc$0Utces
&11id Wu;te Mtnagcment Division
s&LE ANALYSIS REQUEST • . Stare Labonrory or r\lhlie Jlc•hh
r.O. Ror 28047, 306 N. Wilmington Slrce1
Ro1e;g11, Notth c..,,r.n1 27611
Site Number Alt~ 0 0 ',I(, It.{ i' Sf 0
Name o( Site Cu.1 Jm / 701 r'i. <; r..,r f ,
field Sample Nuoiber ____ .,,.8._'f,_'?-'--'3.__ _____ _
Site Location'----'Q._"!1.. .. 1 "'¥!"'":......:..:/.,~-""II_-" _________ _
Collcded By ~:rkh!/71/ <", ID# /? Date Collected 6/<?/9.3 Time //.,zo
'
Agency: _L Hazardous Waste __ Solid Waste _Superfund TCLP Compounds
Sample 'fype lno~anir Compounds Results(mg/I)
Envirnnmental f;;gnc:entnte Comments Arsenic --Barium --VGround water (1) _Solid (5) II --Cadmium
Chromium --_ Surface water (2) _Liquid (6) Lead
-Mercury
_Soil (3) _Sludge (7) -Selenium --Silver -_Other (4) Other (8) -----Organic Chemistry Inorganic Chemistry --
Pnrnmetor Rosults(mg/I) Parameter Results(mg/I) (rn/' I) O~nlc Compounds Results(rng/I)
f'&T:GC/MS _;LArsenic (o.o r benzene -Acid,B/N Ext. ....t.L Barium as. k 2. -carbon tetrachloride
MTBE ~Cadmium Q.ooy chlordane ---./Chloride ·:::i c chlorobenzene
~Chromium 6.j/4 -chloroform ---..L Copper 7_,q -o-cresol
...... Fluoride 0-t~ m-cresol ---:7 Iron -p-cresol s-q;?<'f . --:;;-Lead -~. '3._.i-J. ere sol
--' Manganese ;i,;, ~ = 1,4-dichlorobenzene
-_..:_ Mercury <~. -a::e _ l,2-dichloroetha11e
-./ Nitrate .(..\-cc __ 1,1-dichloroethylene
-' Selenium <'. o. ru S:::: _ 2,4-dinitrotoluene
7silver -<-O-o<:!:i _ heptachlor
Radiochemistry _J.L Sulfates '-\9 hcxachlorobenzene --...... ~--~--v Zinc /J, '1 I hexach lorohut adiene --•. /pH P3rumrler Results (PCl/I) ., -Q hexachlorocthane
__ Clros.< Alpha ....!:::'.. Conductivity 1 1~0 ~~ = methyl ethyl kc.tone
Gros.< Beta TDS ' ' nitroben>.ene -...L. .mtSafi,.,,. ~j, 2 8. = pentai:.hlo1 uphenol
T ><<-•ij"-"'~ (.'-"'.'Ii • ) -IL dlw.rii!!:!ll!! __ pyridine
·Miera iel~ y v Antl!J«I# <o.oo.S: __ tetraehloroethylene --~~ !eftt6 __ trichloroethylene
P~ltt Re•11l~€olflQOml) _,.. . __ 2,4,S-trichlorophenol
./.Th .. 11 ........ /I ,,,., •:l ...L~ a_1'd... __ 2,4,6-trichlorophenol
v ~diLti'F\ f) JI./ ..,, m •. ··~··"' B!f..;lj_ __ vinyl chloride
• ,, .-.••........ i .. 1.(... < I ~A,. _•11,/ ~-o"" endrin
'' '"1 f.+..~,; ..... --lindane I~
O:otc Received Reported by = methoxychlor
_ toxaphene
flak Extr:octcd Date Reported 2 4-0 -· -01022] .JU1110 9 3 _ 2,4,5-TP (Silvex)
f):,1 c l\n;ify,cd Lab Number --OtlS :ll')1 (llcvi~cd 2/')1)
I
.
~ . . N.C. llcptr1mc:RI or Environment,
I leollh, & Natural Re~u:rcc5
~olid Waste M•nagernent Division
S.PLE ANALYSIS REQUEST • State l..abOra(ory of r1.1blic llc•hh
P.O. BoJ 28047, 306 N. Wilmington St~c'
Roi.;pi, North C.rol;n• 27611 •
i
Site Number /,JC, n 0 •Vie /11 l' ,5J' 0 F'ield Sample Number ___ ""8_.f.___..-?,...~-------
Nome nr Site Ce.ei Jn., / /0 r.o: rnr f Site Location f?I,,.,,,_,.. /c /I'-" -'--~-~~~~~~.,...........~----___._~~~~-------
Cnllected By ,fr:fP!tp_'S lD# t.. 2-._ Date Collected .-::. "/ f'? Time OB.So
I
Ageney: _l_Hazardous Waste Solid Waste _Superfund TCLP Compounds
Sample Type lnm11anic Compounds Results(mg/I)
Envlronmentld l:!!nsintrate Comments Arsenic --Barium I p, --..LL Ground water (1) Solid (5) Cadmium --Chromium --Surface water (2) Liquid (6) Lead
Mercury
Soil (3) Sludge (7) -Selenium -Silver --Other (4) Other (8) -. ----Organic Chemistry Inorganic Chemistry -
Parnmeter Results(mg/I) Parameter R,.,,ults(111g/l}'m1;9 el Organic Compounds Results(mg/I)
P&T:GC/MS LArsenic ~tf·fr~ ben:>.ene --Acid:B/N Ext. ....LL Barium carbon tetrachloride -MTBE _L_ Cadmium O,oo :f chlordane --/Chloride \I chlorobenzene -~Chromium --tJ... ,. ¥ !:!. chloroform o, !?.. --.,,,!(__ Copper o-cresol --,,,. Fluoride 40_·,o m-cresol ---:;-Iron :z 11.. i,/ Y. p-cresol -/Lead 12, 18 i cresol -----....::::_ Manganese t.· R 8. -1,4-dichlorobenzene
-..L.. Mercury < 0 • 00,0 ,\ __ 1,2-dichloroethanc
-..L Nitrate ...:.. \. cC: __ 1,1-dichloroethylene ., Selenium <o.ooS" __ 2,4-dinitrotoluene
,,,.. Silver .L..o ... c:;S _ heptachlor
Radiochemistry _i..:::: Sulfates "=\ \ hcllachlorobenzcne --
···~·-····-·-v Zinc q.91 hexachlnrnhu1~dienc --Pi.Ira meter Results (PCl/I) __LpH .., • !..e hexachlorocthane
__ Ore'" Alpha ....!=:'.. Conductivity :=i~ D &.=:io:i~ iQI --methyl ethyl ketone
Gro'5 Beta TDS J nitrohcn7.cne -..£. .. S<d;,. .... l ""I ' _ pcnlachlorophenol
J;•"'"i'i-"'" ('-""t' l ./ dlwl!l;~l!l 'J '1-, {. 8 pyridine
·Miera if.1191!' '< V' &f.Mmf') < (). oo.-::-_ tetrachloroethylcne --~~ tt·r·~ trichloroethylenc
"""""""'" --Resull• (Col/lOOml) ..L' __ 2,4,S-trichlnrophenol
.•. IM II..,,.,.,. < tJ, Q <!) ;;!, l,._.,L1 ..:::.o.os 2,4,6-trichlorophenol
... l".~::yftµ~ fJ.. ~ (), v m .... ~ . ..,,. 4':/.,'J. _ vinyl chloride
• , ' 1 < I i/A·"'J,,/ ,,.-..,, ,-.~ endrin I i.1i:!tl1·-. .• <. ,1 ',.t foh,_$,;~,,,. 31..s> --lindane
Oate Rcroived Reported by --__ methoxychlor
_ toxaphene
/J:ilc Exlr:idcJ Dale Reported 2,4.D
010224 .JUN 10 913 --2,4,5-TP (Silvex)
Dale Analytcd Lab Number · --
l>llS 11'11 (l\ovfaod l/91) -
• •
N.C · ll•ponment <lf Eilvlmnment.
• · llcalth, A NelU,.t Rcs<>ur<d
s.~;., Wost• Moneatment l>Molon
~PLE ANALYSIS REQUEST • State bboRtory <lf ""htl< lle1llh
P.O. Dn1 28047, :llJ6 N. Wll111ln1fon Sl1<<t
lbtelall. Nonh Dmlln• 2761 t
Sile Number /JC Doi/(, /l{j Ii t/Q field Sample Number __ _,.Si_~-~=.....3.-.... ______ _
Name or Site C:c n (.,. ,. la&'Sf?DI 'f Site Lot:alion Ci. ,,,,._f,y/I (I
~/'!/£5 Collected By .£niffff<t-$ IOI /,;z..., Date Collected Time Lol/£.. I
Agency: _K_ Haardous Waste _Solid Wa!lle _Supcrfulld TCLP Compounds
Sample Type lnorpnlc Compounds Results(mg/1)
Environmental Cnnmi!!'.111 Cemmenb Arsenic --Barium
VGround waler (1) /f -Cedmium _Solid(S) -Chromium
_ Surface water (2) Uquid (6) -Lead
-Mercury
_Soil (3) _Sludge (7) -Selenium -Silver -_Olher (4) _Other(8). -
-Organic Chemistry Inorganic Chemistry -
hl'llmflff Results(ml/I) l'ltnmdtr Rnulb(mg/l)(•l/lca) Orpnlc Compounds Raults(mg/1)
,/ P&T:GC/MS Arlll'nic ben7.c:ne JZ' Add:B/N Ext. -Barium -carbon tetrachloride
MTBE -Cadmium -chlordane ----Chloride chlorobenzene ---Chromium chloroform --Copper -o-crcsol ----=Fluoride 111-cresol
-Iron --p-cresol -Lead cresol -=Manganese = l,4-dichlorobcn1.ene --_Mercury 1,2-dichloroethanc
--Nitrate = 1,1-dichloroethylene
Selenium _ 2,4-dinitrotoluene -Silver hcptachlor -Radiochemistry Sulratcs he~chlorobenzene --..... ·-··--Zinc huilchlorobutadicne
l'aNlmrter Results (PCl/I) =pH --heicachlorocthane _om .. Alpha Conductivity = methyl ethyl kcotone
Gro~~ Beta TDS nitrobenzene ----penlaehlorophenol TOC --pyridine
Microbiology -tetrachloroethylconco
-trlchlorocthylene
l1urnmeter Resultt (Col/lOOml) --2,4,S-trichlorophenol ---2,4,6-trlchlorophenol --= vinyl chloride --cndrin -lindane
Oatc Recciv~d_fo-ID-9351\ Reporte<! by --__ met!.oxyc!.lor
'!NA. -.. _toxaphenc
O;itc Exlrndcd !f-114551', bl3: Date Reported 2,4-D ,.,. MA 931567 = 2,4,5-TP (Silvcx)
D;ik Amlly,cd lt•/'f.43 fr/1·'1..J Lab Number
llllS )191 (Rcvi>cd 2/91) 1Uq-06.o -
. ;j
I . • N.C 1>< .. u1.,.nt of l'mlmn,..nt,
" lkohh, A Noturol ll<..,..r<tt
S.~id Wnt< Monop.,.111 DM11ion
9™PLE ANALYSIS REQUEST • Slot< bborotory or rubllr ll<•l•h
P.O. &128047. 306 N. WilmlnJI'"' Sir<<!
llal<fsh, North C.rolin• 27611
Site Number /JCDOlflt l(i !i(Q
Name or Site (' '!( "'""' f )~~r./1'"
rield Sample Number 8o6 ( I
( Site Location Ci...a.1-w#t
Cnllccted By .;(1P'/ffa '.3 ID# Id. Dale Collected &/f/<J'<: Tune //~ '
Agency: ..K_ Haurdous Waste _SolidWute Superfund TCLP Co111pounds
Sample 'I)'pe lnllf'l••lc Compounds Rtsulls(mg/I) 1.
Enrlummental Conmi\!'atr eommenb Arsenic -
0 / Oround ,,,.ler {1)
Barium
_· Solid (S) t.'2 --Cadmium --c&romium --_ Surrace ,,,.!er {2) ~Uquld(6) Lead
-Mercury
_Soil (3) _sludge(1) -Selenium -Silver -_Other (4) _Olher{8) ---Organic Chemistry Inorganic Chemistry --
P11rameler Results("'l/ll h.-.metu llelalts(ml/l)(•l/ka) Orpnlc C0111pounds Rnulls(ml/I)
v" P&.T:GC/MS -Arsenic -benune L Acid:B/N Ext. -Barium -carbon tetrachloride
MTBB Cadmium chlordane --Chloride -chlorobenzene ---Chromium chloroform ---_Copper -o-cresol
F1uoride m-cresol -----Iron =p.cresol
Lead cresol ---Manganese = 1,4-dichlorobenune
-Mercury _ 1,2-dichloroethane
--Nitrate _ l,t-dichloroethylene
Selenium _ 2,4-dinitrotoluene --Silver _ heptachlor
Radiochemistry -Sulfates heKachlorobenzene -._,,_ .. ____ Zinc hexachlorobuladiene
Parameter Results (Pel/I) _pH -heKachloroethane
_ Gm~.~ Alpha _ Conductivity = methyl ethyl ketone
Gros.~ Bela TDS nitrobenzene --= pentachlorophenol roe ---pyridine
Microbiology -_ tctrachloroethylene
-_ trichloroelhylene
P11mmelet Rt!ullt (Col/lOOml) _ 2,4,5-lrichlorophenol ---_ 2,4,6-trichlorophenol
--_vinyl chloride
cndrio -lindane
D:1te Received {11 -IQ-Cl3 SA Reported.~ = metho><ychlor
BNA " __ toxaphene
l>:it1· Bxlra1·tcd (g:ll-'l3S8',WG Date Reported _2,4-P
pr Bull-931568 l,4,5-TP (Silvex)
D11tc l\n;1ly1.cd <o-f'f-9.3 "~1'1~'1.S Lab Number
llllS ll?I (llcw•cd 2/91) "/IUI"' gl{) -
PIJRCEABlE COl1PO.JHOS
<Xlt1POUllO
ch lo.-i:metf\ane
b""""""' tf\ane
di ch lorodl fluon:r,..,thane
vinvl chlor"lde
chloroetf\ane
... th:i:lene chloride
trlchlorofluot'OTll!tf\ane
ethen" 1. 1-dlchloro
etf\an" 1. 1-dlchloro-
1.2-trans-dlchlo""'!tllene
chloror.,.,.
ethane. 1.2-dichlorO-
etf\ane 1 1 1-trlchloro-
cari>ont.,trachlorlde
bl"CJTr)dlchlo~thane
nrooane 1 2-dlchloro-
1 . 3-trans-di chlo
trichlol"Oethvlene
chlal"Odlbn:rn:rnethane
benzene
ethane. 1.1 '-trlc:hloro-
1.3-cis-dlchlo ne
2-ch lol"Oethvl vi nvl ether
bl"O!l)fono
• •
STATE l.AllORllTORY OF PU8l!C IEAllH
DIVISION OF HEAlTH SERVICES, 11.C. OEPARll'IENT OF ,IM'Wf AESQJRCES
P.O. BOX 28047 -306 N. lllllllNCTON. sr.:. RAlE!Qi, H.C •. 21611
ciRCANt,c OE111CAi. NU\l.TSlS
I.All "° 0~1~-1. a ...1.::..1,7 Q.Ol. 1 .1.0. 1q.~ 1~1.Y
FIELD I ~N,,?J 'ft'11' ..a.J. fl'{)/• ...
TY~ I ., I I ) . ( I I I l
UNITS run/) Au•ll<O K.n /1 Aon/l<Q Afiil • /k" .<.>0 / l 7u.,/ka ·-__ .. l.I_. ' . ' •• I '
' i
~ L
'
~
I
' . .
"' ••
... __ ...
r''.L ' • •I/
Ii ~ .T
••
.. • •• L I "'~ 'I: .
10 -"
•J
ethane. L I 2 2-tetr-ach1<1ro-5.-·'-'I
ethene tetrach l<1ro-' :::r
toluen" .
ch lorcbenzene I-' -·-
ethvlbenzene ' i , I/ .,
' •• Ii
I
- L • -.1..-,,. -'J ! • • • .. acetOM • 2-butanone .1: u... •• I . '· cari>ondi su 1 rl de 5-..1.. I
2-hexanone 11•; .L I
4-lrethvl-2-""ntanone
st"'"ene
vinvl acetatf' . I
• .,1enu .u..i..n ' I ,/ ' . ·-,/
x~~ro ..... . • ......~ .L_ ~--. -• •• 1 ...... -.... I ~ " -.....l1'c-• .,.,...,,,,.' I --.. 'J_ •• .. ~ LI..-
.
1·-0•'1' '
J -Estimated value. . ~ -Actual valu" Is knowt1 to be less tt>an value given.
.
l -Actual value· ls knowt1 t<1 be greater than value given. I
U -11aterial Ila$ analyzed for but not detected:. The 111.ltOer h the 11lnlnun Oetectlon Limit. HA -Hot analyzed. • ..
II -Tentative Identification. ·
'I.I -On HRDC ,List of Prl~~11ut.ants. ~-~·-~le lab .... ~ ii .c. D1v1n<1n of lie alt ervices
DHS 306.8-0 (4 /8~ .• Laboratory)"----··
,·
( ) I l
... /1 •·•/ko ·.,n/) •••/kn
.
.
MSE/NEUTRAL ANO ACIO
EXTRACTAOLES
aJlolPWID
N-nl trosodimethvlani ne
bisl2...chloroethvllether
7...ch 10"""hell01
ohenol
1-3-dlchlorobenzene
1 4-dlchlorobenzene
1.2-dl ch lorobenzene
blsf2...chlorol llether
hexachloroethane
N-nltroso-dl-n 1 ... 1 ....
nltrobenzene
I """horone
2-nitroohenol
2.4-dimethvl"""nol
b Is (2-ch lal'Dl!thoxvlmethane
2.4-dlchloroohenol
1 2.4-trlchlorobenzene
""'nhthalene
tlexachlorobutadlene
4...chloro-'i...cresol
hexachlorocvrl,.,....ntadiene
., 4 6-trichlornnhenol
2-chloron••hthalene
ace,,..nhthvlene
dimethvl nt.thalate
2 6-dlnltrotoluene
ace•••hthene
2.4-dlnltrnnhenol
2 4-dinltrotoluene
4-nltrnnhenol
fluorene
4...chlaroohenvlohenvlether
diethvl ohthalate
4 6-dlnltro-<>-<:resol
dlohenvlanlne
·azcbenzene
4-b........,henvlnt...nvlether
hexachlorobenzene
""ntachlornnhenol
""'""•nthrene
anthracene
dibutvl ohthalate
fluoranthene
• • STATE LABORATORY OF PU8LlC HEALTH . DlVlSlON OF IEALTH SERVICES, N.C. DEPARTMENT OF HUIWI RES<VtCES P.O. BOX 28041 -306 N • .'fll.lllNGTON, ST., RALUlil, N.C. 27611
•• AUAI UPIS
lA8 NO ..,. ,,_ ~· ., ~7 ,.._,,,_ -<I.r,,,,,. Y -~L\ .-_..-
FIELD I ! '() 1-., ~ "' liOr,.v Ybu .r
TYPI' _:: I r 11 I I l
UNITS ""'1 1 ~ ..... 11 .. ~
,~, • ~ I ~ j • L ~
. . "
10,-
A -
~'l'"O
IA .,,,,
... 0
~
I ' J; 10 c
'l'"O I~
I0/.3!J0
•
•
..,.,/. .,_ .. ,
F/lr lr:t/\ ,
' . 1.1c , . ~ ' / \~ r .... --'I
m'DL
.l -Estimated value. 11,.c/sot L.
K -Actual value Is k.-n to be less than v111ue given.
f l
un/1 un/ka
l -Actual value Is k.-n to be greater than value given.
U -llaterlal was •nalyzed for but not detected. The nlllber Is the "lnlnun Oetectlon Limit. m7>L
Hf\ -Not anal:tzed. - - - -11 -Tentative Identification. '" ~I -Dn NRDC lid of Priority Pollutants. -..
N.C. V.lvM..i.on 06 He.a.Uh SeJLv.lc.u
VHS 3068-0 14/86 LaboJutto~yl
( l
un/1 ""/k<>
BASE/NEUTRAL AND ACID
EXTRACTABLES
CXlllPWlD
N-<>i trosodimethvlani ne
bistZ-ehloroethvl\ether
2-ehlo-henol
t>henol
1 3-dlchlorabenzene
1 4-dlchlorcbenzene
1 2-dlchlorcbenzene
• • STATE l.A90RATORY OF PUBLIC HEALTH • DIVISION OF !£Al.TH SERVICES, N.C. OEPARTIENT OF IUWI RESOORCES P.D. BOX 28047 -306 N. ,Wil.llIHGTON, ST., RALEIGH, N.C, 27611
" Ill •.ar JIHAI " "S
I.AB NO .... .(/< ,,,_,_ ... 1.~ fil ·~ ,,.-,_(j a-~ '~ C.,<j
FIELD I '"() (, 1-. rDI :/ '(jl. ~ ..,,.~, .,,..,
TYPE • •.1 l I I I \ t ' -,
";.,,JJ -... ,, , '---11 ·-= UNtlfii 'Ill ,_,, -. I • -'I •. -u-::::
I
:
' • 7
70'"'
fA ,
blsi2-ehlorol I' ether
he•achloroethane
N-<>itroso-<11-n Janine
nltrcbenzene
l·-oorone
2..nit-henol
2. 4-dimethuJDhenoll
bist2-ehloroethox•~methane
2 4-dlchlo-•-nol
1 . 2 4-trlch lonlbe1,zene
-·-hthalene
he•achlorobutadiene
4-chloro-:i-cresol
hexachlol"l>l':Vcl"""'ntadiene
2 4 6-trichlo~henol
2-ehloron•·hthalene
ace-··hthulene
dimeth"'l nhthalate
2-6-dlnltrotoluene
ace-·-hthene
2 4-dlnlt~henoll
2-4-dlnitrotoluene
4..nlt-henol
fluorene
4-chlo-henvlnhenvlether
diethut nhthalate
4-6-dlnltro-o-cresol
dinhenulanlne
azcbenzene
4-brmr>r>henv]nhenvlether
hexachlol'()l)enzene
-ntachlo-het>ol
...... nanthrene
anthracene
dibutul "hthalalte
fluoranthene
J -Estimated value.
' .... 0
i .. '.ll'~tl
S"O ' -,
,,
, ... 0
)(J, 'S!lO
I tt 1//&oi:> ,,., ,, , .. _
•V
m1>1-
ll&.o/.so11,....
-' J 01"' ,,. -
'
' /
K -Actual value Is known to be less tha.n value given.
'
'
,
-',.., ,,. -
' ~ c,....._.. ' "
( \
•••/1 ·••/kn
l -Actual value ls known to be greater than value given.
U -llaterial was analyzed for but not detected. The nlllber ls the lllninun Detection limit. m1lL
NA -Not analyzed. ' - - - -
11 -tentative Identification. '" ' Y' -On NRDC Lh:t of Priority Pollutanu..
N. C. Viv.i.4ion 06 Hea.Uh SMvicu
VHS 3068-0 14/86 L~bolt.a.to~y)
f \
... /1 ""/ka
'
l'URGEAalE <X)U'QJNOS
CXl'1F'CIUllD
di I Ol"Cmeth.lne
b....._th.ane
dichlol'OdifluoraN!thane
vinvl chloride
chla,,,.,th.lM
.,.thvlene chloride
tridllo~(luoroN)thane
ethene I 1-dlc:hlo~
ethane I 1-dichloro-
1 2-tr•ns-dlc:hloroethene
chlo~fom
eth•ne I 2-dichlo~
ethane 1 1. 1-trlc:tiloro-
cirbontetr•dllorlde
bl'Oftldichloranetllane
"l'OOane 1 2-dlc:hloro-
1 3-trans-dic:hlo
trich loroethvlene
chlol'Odib~thane
benzene
ethane I 1 2-trldlloro-
1 3-cis-dichlo ne
2-chloroethvl vinvl ether
b.....,fo,,.
• •
STATE IMOAATORT OF PIJ8llC HEAUH
DIVlSION OF HEAi.TH SERVICES, 11.C. DEPAIUIEHT OF ,llJIWI AESQJRCES
P.O. 80X 28041 -306 H. WllftlNGTON, ST., RAlEIGll, H.C •. 27611
OACANl.c CHEntCAi. NIAi. TS ts
l.A8 NO a: ., . a: :U"'"l.7 0':1,1' .1.0. I q_" \5t."f
~· .. _.... r:71\l"t ~ --. 9'0111 .. FIElD ' w
TYPE •. J ll I I l I l
UNITS ruo/l ~·all:n r..ji .... , .. ., . •••"I' '"" 1.r.::;/l7ua/ka ·-·-"' u.... •• I j I '
"" -L
; ,
', I •
-"""'
I •
.
C ·.~L • -. • I . , .., :r ,,., ...... ••
_ .. ~:..1. .!') '."{ ,. " 10' ,.,,.,
• .i
ethane 1 1.2.2-tetrachloro-5,.. ... &... I/
ethene. tetrach loro-:::r
tOlll<!ne ••
ch lorcbenzene -' --~-
ethvlbenrene , •F ,., I • ,,
acetone 10-" .l..o....-~
, ___ .. ~ . p I ...
2-lluUnone J; ....... .. ' . j •
cirbondi sulfide .......
2-lle•anone M ·.,.1.
'-<i>ethv1-2~ntanone
stvrene
•inv) acetate .
~le.-es <1.0..1) ' ,, ,;, .t --~ ~ , II
I~"-o•·.I . . ---.I •• . -I• U-
-•Ill!!_"-• ..... -_J 'I I I . . '.L •• .. _,, "
"""D',,. J -Esti.,..ted value.
X • Actual value Is """"" to be less than value given.
.
l -Actual value· ls""""" to be greater than value given.
U -llaterial 11as analyi:ed for but not detected;.. The nu.Oer Is the 11ini11U11 Oetectlon limit. NA -Hot •na lyzed. . ..
1/ -Tentative ldentlrlcatlon. ·
21 -0n 1111oc list .,, Pr15,~11utants. -~1'&le lab no.....-ui W.c. Division of ltealc ervices
Dl!S 306.8-0 (4/86, Laboratory) ------"
'
.·
r l I l
HO/) .. a/kn ··--11 ·--/Ira
'
• • -····-· -----·-~1
SU.TE lAOOAATOOY Of PUSLIC llEAllH
DIVISION Of HEAi.TH SERVICES, N.C. DEPARHIENI Of lfJIWI RESCORCES
P.O. BOX 2e04J -306 N. WlLKINGTON, ST., RALEIGH, N.C. 27611
ORGANIC 0£111CAL ANALYSIS
, BASE/NEUTRAL .MIO AClO l..A8 NO 11.f'. 1<7-'-q3, .. ~-7 0:71 7,,9 ~-:uc-t:.4
EXTAACTUILES FlELO I ( ..,,,,.;. vo1 -!l IM ,, .. <J ~-·, ....
CIJllfOOll() TYPE ,.1..l r7 l ( l ( l
UNITS .. -,o .. -··-1·· I •• -; • .:-11 · .. ,;,
-··rene ·-, '~-v..--. , ' . I A -
benzidlne --.
butul benzul "hthalate Ln. "''0
benzlal"anthraeene
chrvsene -~
3 3-dlchlarcbenzidlne 1 .. ,. .. ~ r,,
bi s'2-ethul he•ul '-htha late ,,, i' ,,,
'
' dl-n-octuJ nhthalate 0/$. 0 I
benzofb fl110ranthene S'O.
benzolk f1110ranthene
benzo•a ·--··rene I
lndenoil 2 3-cd\n;;-rene i
dibenzota hlanthracene .
benzo•.; h P--lene • ' ' \ '
'
aniline ... ,. , , , ~ ,..__ '• • -
benzolc acid I
benzul alcohol I
4-chloroanlline "'"" ' dlbenzofuran ·-~ 2-methvi:-~thalene
2-methvl-'--r.,1
....... thvlnheool . ,.
2-flltroan\Hne .no. " --'
Mltroanll 'lne '
4-n I troan 111 ne ' -
2 4 5-trlchlo~henol ',. ~ 17 ' ,
'
.. , '"'
'
'
'
'
' m'D&-
J -Estimated value. H~O/SOIL
K -Aetual value Is 1c,_.., to be less than value given. l -Aetual value Is k,_.., to be greater than value given.
U -Kater\al was analyzed for but not detected. The nlllt>er Is the 11\ninun Detection limit. NA -!lot analyzed. • ·-. ' ---1/ -Tentative Identification. ZI -On NROC ll<t of Priority Pollutants.
N. C. V.i.v.i..6.fon a 6 Health Suv.i.cu
OHS 3068-0 14/86 Laboltltto~yl
I
{ l { l
•••JI ""/ka """ un/kn
()'J:llt.. ___.
• •
COMPREHENSIVE GROUND WATER MONITORING EVALUATION
CENTRAL TRANSPORT, INC.
POST OFFICE BOX 7007
HIGH POINT, NORTH CAROLINA
E.P.A. I. D. # NCD 046 148 540
JUNE 7 & 9, 1993
NORTH CAROLINA DIVISION OF SOLID WASTE MANAGEMENT
HAZARDOUS WASTE SECTION
P. 0. BOX 27687
401 OBERLIN ROAD
RALEIGH, NORTH CAROLINA 27611-7687
[phone]
• I. Introduction
A. Facility Infonnation:
Central Transport, Inc.
P. o. Box 7007
Charlotte, North Carolina 27264
EPA # NCD 046 148 540
B. Facility Contact:
Lawrence Wellington
•
c. Date of Comprehensive Ground Water Monitoring
Evaluation:
June 7 & 9, 1993
D. Comprehensive Ground Water Monitoring Evaluation
participants:
Central Transport, Inc., Representatives:
Glen Simpson, CTI
Arnold J. Ramsey, O'Brien & Gere
Hazardous Waste Section, Representatives:
Laurie Martin, Hydrogeologist
Gray Stephens, Hydrogeologist
E. Purpose of Evaluation
The purpose of the Comprehensive Ground Water
Monitoring Evaluation (CME) is to ensure compliance
with the ground water monitoring requirements of 40 CFR
265.90-265.94 codified at 15A NCAC 13A .0010, of the
North Carolina Hazardous Waste Management Rules
(Rules). This evaluation includes a review of the
ground water monitoring system; the ground water
sampling and analysis plan; the sample collection
procedures; and the ground water quality records.
II. Facility Description
CTI is located on Melynda Road in Charlotte, Mecklenburg
county, North Carolina. CTI provides bulk hauling services
to a variety of industries. The Charlotte terminal includes
facilities for cleaning the inside of empty tank trucks
following delivery of bulk chemicals. According to CTI,
rinsewaters which are generated from these washing
operations are collected and treated prior to discharge to
the Charlotte Mecklenburn Utility District (CMUD) treatment
plant.
• • Prior to the mid 1980's, two on-site lagoons were used to
treat tank truck rinsewaters (Figure 1). An intermittent
stream runs near lagoon #2. In 1985, two above ground
rinsewater storage tanks and a new pretreatment plant were
constructed. Use of the lagoons was terminated in 1985 when
the new pretreatment system was operational. The sludges
from lagoons #1 and #2 contained phthalates,
trichloroethane, tetrachloroethene, trichlorobenzene,
toluene, styrene, xylene, lead, chromium, cadmium, and
barium (1991 Post-Closure Plan). CTI is currently closing
lagoons #1 and #2.
Prior to January 1992, CTI was periodically using a
production well located east of the lagoons (Figure 1).
Pumping the production well created a hydraulic gradient
away from the lagoons and toward the production well.
Ground water samples from MW8, MW7, and MW17 have indicated
the presence of chlorinated solvents and other hazardous
waste constituents. During pumping conditions, these wells
are downgradient from the lagoons.
III. Ground water Monitoring System [40 CFR 265.91, codified at
15A NCAC 13A, .0010]
A. Hydrogeologic Information:
The Charlotte site is located in the Charlotte Belt,
within the Piedmont physiographic province. The
Charlotte area is underlain by granite and diorite
bedrock, interfingered with a variety of local
sedimentary and metamorphic rocks. The bedrock is
overlain by a layer of unconsolidated clayey to sandy
material. The unconsolidated material acts as a
reservoir which transmits water to the bedrock. The
bedrock ground water is contained in the joints and
fractures in the rock (Figure 2). According to CTI,
flow on the eastern side of the lagoons is generally to
the southwest. Flow on the western side of the lagoons
is generally to the east. static water levels also
suggest vertical ground water flow. CTI's data from
6/27/90 suggests downward flow (well nest MW-11, MW-
12), while data from 5/2/91 suggests upward flow (well
nest MW-13, MW-16).
CTI performed rate of recovery tests (slug tests) on
bedrock wells MW6-MW11 in 1989 and on bedrock well MW14
in 1990. The average hydraulic conductivity value
(MW6-MW11) estimated was 2.44 x lo-s ft/sec or 0.21
ft/day. The estimated hydraulic conductivity value for
MW14 was 9.9 x lo-s ft/sec. Using a hyaraulic gradient
value of 0.018, an aquifer porosity of 0.01, and a
hydraulic conductivity value of 0.21, CTI estimated the
horizontal flow velocity at 0.38 ft/day. CTI estimated
the downward vertical flow velocity at 8.88 ft/day
• •
using the 6/27/90 data.
B. Ground water monitoring system:
According to CTI's April 30, 1993 Ground Water
Assessment Plan and the Section's May 12 letter, CTI
should be sampling MW9, MW15, MW7, MW13, MW16, MW17,
MW18, MW8, MW6, and MWlO for the next phase of the
assessment. CTI is also currently conducting quarterly
monitoring.
During the CME, CTI representatives collected ground
water samples from wells MW9, MW15, MW7, MW13, MW16,
MW17, MW18, MW8, MW6, and MWlO. The Section opted to
collect duplicate samples from wells MW16, MW18, and
MW17.
IV. Ground Water Monitoring Plan and Procedures [40 CFR 265.92,
codified at 15A NCAC l3A, .0010]
A. Evaluation of the Plan:
CTI submitted a sampling and analysis plan dated
December 1992. The section provided corrunents on this
plan in a January 11, 1993 letter. CTI submitted an
addendum to the December 1992 plan in a February 11,
1993 letter.
B. Implementation of the Plan:
During the CME, CTI representatives followed the
procedures set forth in the December 1992 Sampling and
Analysis Plan and in the February 11, 1993 addendum.
v. Ground Water Assessment [40 CFR 265.93 codified at lSA NCAC
13A .0010]
The Hazardous waste Section reviewed CTI's April 30, 1993
assessment plan and provided corrunents in the May 12, 1993
letter to Mr. Gary Honbarrier. As described in the May 12,
1993 letter, CTI should submit an assessment report by
August 6, 1993.
VI. Ground Water Record Keeping and Reporting [40 CFR 265.94,
codified at 15A NCAC 13A .0010]
CTI was found to be in compliance with the record keeping
and reporting requirements of 40 CFR 265.94, codified at 15A
NCAC 13A .0010.
VII. Ground Water guality Analytical Results
A copy of the State's analytical results of duplicate
samples from wells MW-16, MW-17, and MW-18 is forthcoming.
• •
VIII.Conclusions
At the conclusion of the CME, Central Transport, Inc. was
found to be in compliance with 40 CFR 265.93, codified at
15A NCAC 13A .0010, in that they are implementing the ground
water quality assessment plan. CTI should submit an
assessment report by August 6, 1993.
10. !f •ample• are for organic eornpounde and/or metal•
analyai•, doe• the eleaning proeadure ineludJll.he
following •••ntial atep•• ..,,
a. nonpho•p a doterg•n w••h
b, t•p water rinae
e. dilute aeld rinee (HNO, or HCl)
d. di•till•d w•ter rinae
•· aleohol rin•• (additional dletilled water rinae
l• optional)
u. I• SftlPllng equ.ipn1mt thorcu<#ily dry before use?
l2 • l\re equiplll!nt bla..-1(11 takeh t.o ensure that. 11anple
cl"Ollll-allltanimtion hu not. o:curred?
13. tf 'VOlatUe eanples are taken with a poeit.lYe IJ!l!!
t!i l!lplacerent. bladder p.trp, are p11pf..ng rates belOof
too 1111/ml.n?
F, In1it.u or field analyse111
1. Are the follG1i~ labile (chf'mic:ll!llly unstable) para-
net.ers det.erttd.ned in the field1
a. (ft?
b. Tel!1;>Brat.ure?
c. Speclfic COlltllct.ivi t:y?
2. Are field paramatare determined after well evaeuation
and eample removal7
J. If !!lllft'le ls wit.hdra.m Eran the well, 111 parermt.er
rreasured frOlll a split. porUon?
4. Is 1ronitoring equi~nt. callbrllted according to
~ract.urer11' speclfioat.ionB and a:lfUliet.ent. with
SW-846?
5. Is the dat.e, procedure, Md nalnt:.en&tce for equlprent.
calibration dr.xulmnt.ed in the field loJ:xx;k?
IV. Pevlew of Sanple FreservaUat am llandli.ng Procedures
S&ipla cont.ainerw1
1. Are 1111irtples t.raMferred fran t.he 11mpli11g davi~
directly to their C01P'lt.ible containers?
2. l\re smple aJ11Wners for metals (lrYJr91nics) analyses
p:>lyethylene with p:>lYPrcpylene caps?
J. l\re saiple co1tainer11 for or9!1niCB analysis 91ns
bottles with fluorocarbonresin-llned e&ps?
u (Y/N) _j_
(Y/N) j_
(Y/N) .Y.
(Y/N) !J/JJ.
(Y/N) '('
(Y/N) Y
(Y/N) Y::
::J"~T (Y/N) Arn-g t t.W:.
'-" (Y/N) .J_
(Y/N) :::_
(Y/N) .L
(Y/N) u
I
v (Y/N) ...!.....-
\-(Y/N) _J_
g.
• • 4, If glass bottlee are ueed for ll'l!ltals sanples are
the mps fluorocartou:esi11-Uned7
5. Are the s11111?le containers for Pl!tal analysff eleaned
using these sequential steps?
a. ffor1?ho!lphate detergent wash?
b. 111 nltrle ~eid rinse?
e. Tap water rinse?
d. 111 hydrodlloric acid rinse?
e. Tap water rinse?
f, Distilll!d/delcnlted water rinse?
6. Are the 1!181ple contaillf!rs for orgimle analyses cleaned
using these el!lqllentlal st°"s?
a. N~phate detergent/hot. water wash?
b. Tap water rinse?
-c. Oistilll!d/delcnlud water rifl!!le7 1 ~. Acetone rinse?
e. Pesticide-grade helt!l.ne rinse?
7. Are trip blame used for eadJ eanple container type
to wrify eleanllnese7
Sant>le preserlll'ltlon pr-oeedures1
1. Are s;srples for the following analyses cooll!d to 4°C1
!I· 'roC?
2.
b. TCJC7
c. Chloride?
d. Phenols?
e. Sulfate?
f. Ni tr!lt.e?
g. O:.llform ~ct.eria7
h. ey..nl.~7
i. volatiles, eemivolat11ee, pesticides
(40 CFR 264, Appendix IX)
Are eampleu for the following anulyeeu
ecidifiad to pH <2 with HNO,t ... t:otAl metAle
b. diueolved metAlB
c, rAdlum
d. groee Alpha
e. groea beta
field
(Y/N) ..tJ..
(Y/N) fL/#1. (Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N) ]Z
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
U-6
(Y/N) _y_f
{". v" ,,r ,r,, z voc s,
~~~l _!i&
(Y/N) :!£.
(Y/N) ± (Y/N)
(Y/N)
(Y/N) I
(Y/N) I
(Y/N) .J:_
(Y/N) ~ (Y/N)
(Y /N)
(Y/N)
(Y/N)
•
J. Are 11111!ple11 for the following analy1e1 field aeidlfied
to (It c2 with H29J41
a. l'henoil!I?
4. I!! the 11anple for TOC analyses field acidified to
pH C2 with HC17
s. 111 the sanple for TOC analysis pt"e11erved with
1 ml of 1.1 H eodiwn •ulfite?
6. 11 the ssrple for cyanide analy1i11 presened with
NaD!f to pH >127
C. Speeial handling eonelderatlon111
1. Are organie eanplell hanlled wlthwt filtering?
2. Are 11111ple11 for volatile organicu transferred to
the ~cpriate via!e t:o ellnd.nate headspaee over
the 11anple?
3. Are 11anples for 111!1tal analyeil!I epli t into oo
portions?
4. 111 the saiplt!' for di1190lved net.al.JI filtered
thrOJl#l a 0.45 ml.crou filter?
s. 19 the eeeond portion hOI: filtered and analyz.ed
fol' total netal•? '
6. Is one flquipmnt blank prepM"ed each day of
groun<l..-ter sanpllng?
V. Review of Chain-Qf-<llstody Prodecure11
A. S&!ple label11
1. Are 11anple labele used?
2. D::i they provide the follodng infot118Uon1
a. Sar!ple identifieation l"llllt>er?
b. Narie of oollector?
e. Dl'lte and tirre of eollecticn?
d. Plaee of oollect:ion? _
e. Pu--arreter(e) reque11ted and preservativee used?
(Y/N) _
(Y/N) 4"
(Y/N) .!/if
(Y/N) _
(Y/N) _
(Y/N)
(Y/N) _
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N) _r
(Y/N) t (Y/N)
(Y/N)
(Y/N) V
J, Do they r.n legible even if wet? •
e. ~le seals1
l • Are Sllllple s~ls plaoed en t:hoee containers to
ensure the SMf'll!IS are not altered?
'
c. Field l<>:Jlxx:i< ,
l. Is a field logtwxk maintained?
' . '
2. !bes it doC\lltl!nt the folloongr
a. Pl.lftl08e of Rllpling (e.9., detectic:xt or
assessnent_)?
h. tnoatic:xt of -ll(s)?
c. 1'Jtal depth of eadl Ml! 11?
d. Statie·Wl'lter level depth and ITl!lllsurl!lllent
tectinique?
e. Presence of iimdscible layers and
detection Pet:hod?
f. Cbllection rret:hod for intrd.scible layers
and Sll!!ple identification n.lllbers?
9• Well evao.Jation prOl:"!Wres?
h. Sanple witldrll'w'al procedure?
i. Date and t~ of collect.icn?
j. Well sanpling sequence?
k. Types of s~le containers and s~le
identifiC!lticn ~r(s)?
1. Preservati11e(s) used?
m. Pararreten requested?
n. Field analysis data and rmthod(s)?
o. ~le distrHuticn Md transporter?
p. Field ohlervations?
o Unusual \\ell redlarg@ rates?
o 'fquipnent malfuncti<:11(s)?
o R:issible sanple oontainl.nation?
o Saiipling rate?
o. O'lain-of-o.ist.ody record1
l • Is a diain-of-custody record included with
ead1 !ll!lllple?
2. Ooes it dOCUl!li!nt the follo.ring1
a • Sanpl e l'U!ber?
b. Signature of collector?
c. Date ard tine of colled:.ioo?
d. S&lple type? ·
e. Staticn lcaiticn?
f. Nlilber of containers?
· g. Pararetere requested?
h. Signatures of persons involwid in the
dlain-of-p::i!!sesslon?
i. Inclusive datee of pot!!sension?
(Y/N) ~
(Y/N)
(Y/N) -1.
(Y/N) L
(Y/N) <;1_
(Y/N) ~
(Y/N) .1..._
(Y/N) Nt
(Y/N) j,Ji__
(Y/N) ~
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N) I
(Y/N) _J;
(Y/N) _:{_
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N)
• • E. Sarrple analy11is request sheet•
1. D:ie11 a sairple analysis request sheet accatpllny
eadl sanple?
2. tbes the request sheet docultent the follow:l.ng1
a. Narre of person receiving the Ga1Ple?
b. Date of sanple receipt?
c. Laboratory s..iple n.mber (if different than
field l'Ulber)?
d. Analyses to be perlorned?
VI. lleview of Quality Assurance/OJality a:ntrol
A. Ill the validity and reliability of the laboratory
and field generated data ensured by a 01+./0C program?
B. [);)es the Wet: program includer
i. IX>cum:mtation of any deviaUone fran approved
proced.tres?
2. D:>CUITl!lltation of analytical results forr
a. Blarit11?
b. Standards?
c. D..lplicates?
d. Spiked sanples?
e. Detectable 1.iJlli ts for ea.ch panineter
being analyt:ed?
c. Are approlled statistical net:hods used?
D. Are OC sanples used to correct data?
E. Are all data critically ell!lmined to ensure it
has been prcperly calculated and reported?
VII. Surficial Well Inspection and Field Clleervatim
A. Are the wells adequately naintained?
B. Are the rronitoring welle pi:oteeted ard sewre?
c. lb the wells have surveyed easing elevations?
o. /l.re the gx-cund~ter sarrples turbid?
E. Have all physical dlaraeteristie11 of the site been noted
in the inspector's field notes (i.e., surface waters,
tq;iography, surface features)?
(Y/N) y
(Y/N)
(Y/N)
(Y/N)
(Y/N)
(Y/N) :i_
(Y/N) i
(Y/N) J'.._
(Y/N)
(Y/N) -
(Y/N) =
(Y/N) _
(Y/N)
(Y/N)
(Y/N)
(Y/N) ~
(Y/N) ~
(Y/N) ~
(Y/N)
(Y/N)
' . '
. -' . '. . '' .
F. Has a sit~ ·.!ct. beell prepared by the field inspector
With a scale, north arrot, location(s) of tuildings,
location(s) of regulated unite, location of roonitoring
wells, and a rwgh depiction of th .. sit.. drainage pattern?
VIII. O:Jnclusima ·
A. Is the facility currently eperating under the correct
m:initoring p:ogrl'l!ll according to the statistical analyses
(Y/N)
perfo~d by the current cperator? (Y/N)
B. tDee the gromd-ter llD'\itoring system, as designed and
q>erated, allcw for detection or a118ee!lll'l!nt of any po11sible
grcund-ter e6n.tamlnation cau11ed by the faeility? (Y/N)
C. Ooes the Ant>ling and analysie ptocedares permit the
CMler/qierator to detect find, ~re poesible, aesese the
nature and extent of a release of haurdcus constituents
to grwnd W!lter from the ironitored haz!l.rdoue W!lete
nanagenent facility? (Y/N)
' .
• •
STATE LASORA TORY Of PUBLIC H~lTH
OlVlS!ON Of H~LTH SERVICES, N.C. DEPNllMENl Of' .HUMAN RESOURCES
P.O. SOX 280a7 ~ 306 N. HlLMlNGlON, ST., RALElCH, N.C. 27611
ORCAN!C Cl-<EM!CAl ANALYSIS
PUl'IGEABLE CCllPOUNOS LA8 NO qA.1<:1.1~ Q::q.;/.7 q_;:i i;1Aa cia 1s1.9
"'; "='"'"• 3 su11u.i. 5('{){. 5 FIELD I • 6
~D TYPE ( ., ) ( I i { I l ( I l
UNtTS (ua/ 1 hoa/kq ?.4/' ~ ·•/kq .<.q/]7 .. q/lco j,-\fq; l/\Jq/kq
ch l or01ethane 10 .~h u...... I ' I ' I '
bron::::methane
dlchlorodifluorarethane
vinv1 chloride
chloroeth,a,ne 'I/
irethv)ene chloride &;. ,b
trichlorofluorcrnethane '
ethene 1 l--dichloro ' ,..-
ethane 1 1--dich loro---, ,
1 2-trans--dichloroethene ' I I '
chloroform 55
ethane l 2--dichlo,.,;.... I'
~th.ane 1. 1. 1-tr;chloro-
carbontetrachloride \/
b""'1'0dichloroirethane 10 __ j..,
orooa.ne l 2-di ch 1 Oro---r . __ :..J... .
1 3-trans--dichlor-oorooene . -J
trichloroethvlene / _-i ::r
chlorodibrcn.::methane In·-'-I ,
benzene 5',,.,,1., :1 -:s
~thane I 1 2-trichloro-:1 .
1 3--cis--dichlo ne /0 ,..}>
2--<:hloroethvl vinvl ether
bn:m:>form •/
eth.ane l. 1 2 2-tetrachloro-5:n.,h -/
ethene tetra.ch 1 oro-" ~
toluene I'
ch lorobenzene '
ethvlben<ene I ; \I/ ,1; I ' ;
.acetone /OA,J.. ' -c I ---=."' -i: .;j._~-•D I' I p,
2-butanone ,), IA..,.. , ' (.;._. I '
carl>ondi <ul fide 5 ....
2-hexaMne ,,..,· ~i..
4-o'ethvl 2~~ntanone
stvrene
vinvl acetate I
' xvlenes t+d'at'i ' / I / ' ' . --·/
I-:>c.nro.n. I __ ,...__.,,...... ,:;;. ....,_, I , L-~-~ I :I \,(.....
-·.;_,.;_..1,·,~·"--.. "'-i..4-U-...., ") /.;_.
1'MDL-r
J -Estimated value.
K -Actual value is kri<>lm to t>e less th•n value given.
L -Actual value-is kncwn to be greater than value given.
U -Material was analyzed for but not detected. The nurber is the Hininun 6etection limit. llA -Not analyzed.
\/ -ientative identification. · fl -On NROC ~ist of Pribd~Mollutants. B-~·-~le Jab ·_ .-o~
N.C. 01v1s1on of Healch ervices
OHS 3068-0 (4/86 Laboratoi:y)
... ----
( \ ( I
\Jal l ""/k" ·ua/l uo/ko
BASE/NEUTRAL AND ACID
EXTRACT ABLES
COMPOUND
N-nitrosodimethvlamine
bis(2-ehloroethvl)ether
2--eh l orooheno l
ohenol
l .3--<!ichlorobenzene
l 4-dichlorobenzene
l.2-<!ichlorobenzene
• • STATE LA80RATORY OF PUBLIC HEALTH DIVISION OF HEALTH SERVICES, N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047 -306 N. _WILMINGTON, ST., RALEIGH, N.C. 27611
ORGANIC CHEMICAL ANALYSIS
lA8 NO .....,. -if I£.. , 'ef~'-""7 4'.'<'/~y '?', ..:,;. l <-'I
FIELD # vo& .;L. f?ru,, q YO&'! Vo&,)
TYPE ( -~\ I I l I I ) I I )
UNITS uo/l •mil, .. /'uo/ I -.. n/1 L_,._
rn,_i(3D ' -' u I.A---
,f
/Or
i.A.--
bisf2-ehloroi•~roovl)ether
hexachloroethane
N-nitroso-dl.-n-"r""vlamine
nitrobenzene
i=nhorone
2-nit.......,henol
2 4--<limethvlohenol
bis(2-ehloroethoxv\methane
2.4--<!ichlo,..,..,henol
l.2 4-trichlorobenzene
n•nhthalene
hexachlorobutadiene
4--ehloro-m-cresol
hexachlorocvcl"""'ntadiene
2.4 6-trichlO"""henol
2--ehloron•nhthalene
aceMnhthvlene
dimethvl ohthalate
2.6--<linitrotoluene
acen•nhthene
2.4-dinitr....,henol
2 4-<!initrotoluene
4-nitroohenol
fluorene
4-chloroohenvlohenvlether
diethvl ohthalate
4.6-dinitro--0-<:resol
diohenvlamine
azobenzene
4-brrwmnhenvlnhenvlether
hexachlorobenzene
oentachloroohenol
phenanthrene
anthra.cene
dibutvl ohthalate
fl uoranthene
J -Estimated value.
SO//c..So
101~-::i{'j
'i"Oh f..~0
/0/ 230
J,
.<ro "·""" /0.1330
'4
SOl/"."'7
IA r::r'lr.
' ,
m"DL
/i,_O/SOIJ-.
,. ' " JOI::'
UL-
\ /
K -Actual value is known to be less than value given.
/
/,)IC . ,
' 'v<-I /
( )
..n/1 .. n/ka
L -Actual value is known to be greater than value given.
U -Material was analyzed for but not detected. The nl.llber NA -Not analyzed. is the Mini""" Detection Limit. mTJL ~ --
l/ -Tentative identification.
:fl -On NROC List of Priority Pollutant<.
N. C. V.lvio.{.on 06 He.a.Uh SeJLv.{.ce..o
VHS 3068-0 14/86 LabattaA:a~y)
-
( l
"''/l un/ka
-6ASE/NEUTRAL ANO ACID
EXTRACT ABLES
Oll'IPOUN 0
nvrene
benildine
butvl benzvl phthalate
benzlalanthracene
chrvs.ene
3 3-d ich 1 orobenz id i ne
bis(2-ethvlhexvllohthalate
di-n-.-0etvl ohthalate
benzofblfluoranthene
benzo(k)fluoranthene
benzo(alnvrene
i ndeno ( 1 2 3--<:dl m•rene
dibenzo(a.hlanthracene
benzo(o h il~rvlene
aniline
benzoic acid
benzvl alcohol
4-<:hloroaniline
dibenzofuran
2--rrethvloaohthalene
2--rrethvlohenol
4--rrethvl pheoo 1
2-ni troani line
3-ni troanil ine
~itroaniline
2.4.5-trichloroe>henol
• • STATE LA60RATORY Of PU6LIC HEAL TH OlVlSION Of HEALTH SERVICES, N.C. OEPf\RlMENl Of HUMAN RESOURCES P.O. aox 28047 -306 N. WILMINGTON, ST., RALEIGH. N.C. 21611
ORGANIC CHEMICAL ANALYSIS
LAS NO <f ::{ I <7~ {,, qc?, <~7 Ci:;>Jcr-x Cf' '7 / <F,., q
FIELD # vo&..l. vo;;, .... £-C(p<-> R.'J& .-
TYPE ( ..;i_) I I ) (/ ) r I l
UNITS "n/V-11n/l_... J " ,,,.,,1 £.-....n........ "n/l' "
'o/."'"' LA--f .; I JI. IA
so h1.<o
'0/.R=IO
.
so rL."fl
10/ '30
JO/: l20
SOI •£.""
--
\ ' ' ' ' ,
<o , .. IA __. u-1. l A ~
... ,_
10 -=,.,
"" -"o/Jt..<.o
-' ,, ' \I " ,, \
mn1.-
J -Estimated value. H;i.O/ $011-~ -Actual value is known to be less than value given.
( )
uo/ 1 uo/ko
L -Actual value is known to be greater than value given.
U -Material was analyzed for but not detected. The ni.rrl>er NA -NOt analyzed. is the Minirrun Oetection Limit. ('rJ::l>t ..
l/ -Tentative identific~tion. g1 -On NROC List of Priority Pollutant<.
N. C. D-i.v-W-i.i:m 06 He.a.Uh SV!.v-i.C.<!.-6
VHS 3068-0 {4/86 Labol((l):o~y)
-
( )
un/1 .. n/ko
•
Sincerely,
' ' h/l. .J---';;; 0~,~
Laurie Martin,, Hydrogeologist
waste Managemimt Branch
Hazardous Waste Section
cc: Terry Norman
Mike Arnett
Katherine O'Neal
Phil Delp
Marc Fleischaker
John Doyle
central files
•
•
Ms. Laurie Martin, Hydrogeologist
April 30, 1993
Page 2
•
on MW-18 only. Neither pesticides nor PCB's have been detected in any monitoring wells
in nine rounds of samples dating back to 1989. Pesticides and PCB's were not detected in
the lagoon sludges. None of the parameters regulated by the State of North Carolina,
Administrative Code, Title 15, Subchapter 21 have been detected in previous ground water
sampling rounds in any wells. Sample collection and analysis will be in accordance with the
Sampling and Analysis Plan dated December 1992.
Ground water elevations will be collected during sampling from wells MW-6, MW-7, MW-8,
MW-9, MW-10, MW-11, MW-12, MW-13, MW-15, MW-16, MW-17, and MW-18.
A report will be prepared which will include a review of the analytical data, preparation of
boring logs and well construction diagrams, and development of vertical and horizontal
ground water flow maps.
The State has recently informed O'Brien & Gere that they intend to perform a
Comprehensive Ground Water Monitoring Evaluation during the May quarterly sampling
round. Therefore, it is recommended that the well will be installed the week of May 24 with
sampling during the week of May 31 to accommodate the State's schedule.
The April 1, 1993 letter included a statement that lead had been detected in wells MW-17,
MW-8 and MW-13 above the regulatory level of 0.05 ppm. In these cases the exceedence
was in unfiltered ground water samples and in all cases the solids analysis indicated that the
unfiltered samples exceeded the regulatory standard for solids of 500 mg/! in all three cases.
Filtered results were well below the regulatory limit for lead. In previous rounds of analyses
for wells MW-8 and MW-13 (9 rounds and 3 rounds respectively) lead has not been
detected above the regulatory level in either filtered or unfiltered samples. The results of
future sampling rounds will be reviewed to see if lead continues to exceed the regulatory
level.
The April 1, 1993 letter included a statement that manganese had been reported in well
MW-11 at a concentration of 205 ppm. This was a typographical error and should have
been reported at 2.5 ppm. We apologize for this error.
O'BRIEN & GERE ENGINEERS
• •
Ms. Laurie Martin, Hydrogeologist
April 30, 1993
Page 3
•
Please advise if this is acceptable or if additional information or clarification is required.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
~ti~~t-
George B. Rest, P.E. \. ~ ~ J
Vice President
GBR:TLN :rnjh
cc: G. Simpson
M. Fleischaker, Esq.
T. Norman
O'BRIEN & GERE ENGINEERS
Ms. Laurie Martin
February 11, 1993
Page 2
• •
contamination originating from sample transport, shipping and from site conditions. Per
Revision 1, dated 1990 of SW-846 Test Methods for Evaluating Solid Waste, Chapter 4,
page 2, "VOA samples may be contaminated by diffusion of volatile organics through the
septum during shipment and storage. To monitor possible contamination, a trip blank
prepared from distilled deionized water should be carried throughout the sampling, storage
and shipping process." The same caution is not included in the description of sample
collection procedures for semivolatiles which includes pesticides and herbicides. It is quite
unlikely that metals, pesticides, PCB's or semivolatiles would diffuse through the septum.
Step #2 will be modified to state that a new pair of protective/non reactive gloves will be
put on at each new well.
Step #4 will be modified to state that the stainless steel bailer(s) will be field decontaminated
between wells. Dedicated bailers will not be used.
Step #6 will be modified to read, "begin bailing the well from the top of the water column,
making cerlain to keep the sampling equipment (e.g. the polypropylene rope) from the coming
into contact with the ground or other potentially contaminated surfaces.
In Step #8, the sentence which reads, Bail until three times the volume of ground water in the
well has been removed, will be deleted.
In Step #9 a statement will be added that Samples will be collected as soon as technically
feasible and within 24 hours of the purging procedure.
Step # 13 will be modified to state that Sample bottles which are prepared in the field with
preservatives will be field checked for pH so that the metals are properly preserved.
In Step 14 the clarification that samples will be stored at 42 C will be added.
Regarding Step #17, arrangements with the Charlotte Mecklenburg Utility District have not
been finalized by Central Transport, Inc. Upon finalization the agreement will be
appendicized to the Sampling and Analysis Plan.
Section 2.03.02
Step #2 will be modified to state that a new pair of protective/non reactive gloves will be
put on at each new well.
Step #14 will be modified to state that Sample bottles which are prepared in the field with
preservatives will be field checked for pH so that the metals are properly preserved.
O'BRIEN & GERE ENGINEERS
Ms. Laurie Martin
February 11, 1993
Page 3
• •
In Step 15 the clarification that samples will be stored at 4'2-C will be added.
Regarding Step #18, arrangements with the Charlotte Mecklenburg Utility District have not
been finalized by Central Transport, Inc. Upon finalization, the agreement will be
appendicized to the Sampling and Analysis Plan.
Section 2.06
Per your recent discussions with Terry L. Norman of this office, ground water sampling is
being conducted at the Central Transport, Inc. Charlotte site on February 3-11, 1993. The
lagoons are presently being closed and it is expected that backfilling and installation of the
final cover will be completed in 45-60 days. It has been understood that quarterly sampling
will be required only until such time as closure is completed. If the final cover is not
completed in the timeframe outlined above then a second round of quarterly sampling will
be conducted in May 1993. If the final cover is completed in this timeframe that sampling
will be conducted in accordance with the approved post-closure monitoring plan.
The second sentence will be modified to read, The wells to be sampled and the parameters
to be analyzed for assessment will be specified in the most recent ground water assessment plan;
the wells to be sampled and the parameters to be analyzed for post-closure monitoring will be
specified in the approved post-closure plan.
Appendices
Appendix F will be modified as follows:
Parameter
In organics
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Test Method from SW-846
EPA 6010
EPA 6010
EPA 7060
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
O'BRIEN & GERE ENGINEERS
Ms. Laurie Martin
February 11, 1993
Page 4
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Cyanide
•
Ground Water Assessment Plan
Section 2.01
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 6010
EPA 6010
EPA 7740
EPA 6010
EPA 6010
EPA 7841
EPA 6010
EPA 6010
EPA 9012
•
In the second paragraph, sixth line, the sentence beginning "The well assembly will consist
of 10 feet of PVC screen, will be corrected to read with 0.010-inch slot size.
In the paragraph describing well development procedures using compressed air or pumping
methods, a sentence will be added which states, Air from the compre.1;mr will be filtered to
minimize the possibility that oil is introduced into the ground water system.
A sentence will be added which states that, Contaminated media (including soil) generated
during well installation will be managed appropriately. Analytical methods will be used as
appropriate to evaluate the proper divposal options.
Section 2.03
Samples will be analyzed for all constituents included in Appendix F for the first round of
sampling which is being conducted during February 3-11, 1993. Upon receipt of analytical
results and submission of a report to the State, CTI reserves the right to eliminate some of
the parameters from future quarterly sampling rounds, if conducted.
Section 2.04
CTI may elect to perform statistical analyses to assess whether contaminants that may be
detected are statistically significant.
O'BRIEN & GERE ENGINEERS
Ms. Laurie Martin
February 11, 1993
Page 5
• •
This letter will also confirm the discussion pertaining to the sampling of the production well
vs. MW-15. Because the production well has not been in operation and because specific
information about its construction, screen depth, etc is not known, O'Brien & Gere will be
sampling MW-15 to define the eastern boundary of the plume.
Enclosed please find corrected pages for insertion in the Sampling and Analysis Plan and
Ground Water Assessment Plan. Please advise if additional clarification or information is
required.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
/'/ 73, ?W-~Rest,P.E.
Vice President
GBR:TLN:mjh
Enclosures
cc: G. Simpson
M. Fleischaker, Esq.
J. Doyle, Esq.
T. Norman
O'BRIEN & GERE ENGINEERS
• •
WORK PLAN
SAMPLING AND ANALYSIS PLAN
CENTRAL TRANSPORT, INC.
CHARLOTTE, NORTH CAROLINA
DECEMBER 1992
REVISED FEBRUARY 12, 1993
O'Brien & Gere Engineers, Inc.
8201 Corporate Drive, Suite 1000
Landover, Maryland 20785
O'BRIEN & GERE ENGINECHS
• •
Revised February 12, 1993
1. Identify the well and record the location on the Ground Water Sampling Log.
2. Put on a new pair of protective/nonreactive gloves at each well. Wear
protective/nonreactive gloves throughout the water level monitoring procedure.
3. Clean the electric well depth probe by washing it with deionized or distilled water
rinse. Use a probe accurate to 0.01 feet.
4. Measure the depth to water below the measuring point, and the total depth to the
bottom of the well below the measuring point (top of PVC casing). Record this
information in the Ground Water Sampling Log. If the well depth has changed since
the previous sampling event, record this information also.
2.03 Ground Water Sample Collection Procedures
In order to minimize the potential for cross-contamination, wells will be sampled in
order from the least contaminated well to the most contaminated well, based on the most
recent historical analytical data. For each sampling round, (a) one field (i.e., equipment)
blank will be submitted to the laboratory for the entire suite of analytes; and (b) one trip
blank will be submitted to the laboratory for volatile organics analysis.
Where practical, wells will be bailed. Otherwise, a pump will be used to purge the
required volume of ground water.
2-2
U'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
2.03.01 Collection Steps (Bailer)
1. Using the well depth and the depth to water reading, compute the volume of water
in the well, and record this volume on the Ground Water Sampling Log.
2. Put on a new pair of protective/nonreactive gloves at each new well. Wear
protective/nonreactive gloves throughout the ground water sampling procedure.
3. Cut a slit in the center of a plastic sheet, and slip it over the well, creating a clean
surface onto which the sampling equipment can be positioned.
4. Prepare the stainless steel bailer for sampling. Before sampling, the bailer should
have been transported to the site wrapped with material that is nonreactive with the
equipment or the constituents of concern in the ground water. Clean the bailer with
soapy water (using phosphate-free soap and tap water), a tap water rinse, a deionized
or distilled water rinse, an isopropyl alcohol rinse, and a deionized or distilled water
rinse. Allow the equipment to air dry. Stainless steel bailer will be field
decontaminated (as described above) between wells.
5. Attach the polypropylene rope to the bailer.
2-3
O'RRIFN & GF.RE fNGINl_tHS
• •
Revised February 12, 1993
6. Begin bailing the well from the top of the water column, making certain to keep the
sampling equipment (e.g. polypropylene rope) from coming into contact with the
ground or other potentially contaminated surfaces. The purpose of bailing from the
top of the water column is to remove as much of the standing water in the well
casing as possible.
7. After one bailer full of water has been retrieved, record the physical appearance
(color, odor, and presence of floating product) of the ground water on the Ground
Water Sampling Log. Also, measure and record the field parameters (pH,
conductivity, temperature, and turbidity) of the ground water. These field parameters
are to be measured and recorded after each well volume of water is purged, in an
effort to determine whether a representative ground water sample is being obtained
from the well. Stabilization of the parameters indicates a representative sample.
8. Continue bailing throughout the water column. Bailed ground water should be
poured from the bailer into a graduated pail to measure the quantity of purged
water. If a minimum of one well volume has been purged, and the aforementioned
field parameters have stabilized, then proceed with sampling. If the field parameters
have not stabilized, then wait for the well to recharge, and continue purging until the
field parameters have stabilized, or until three well volumes have
2-4
Ci'HHltN & Gi::Ht tNGIN[[R~_;
• •
Revised February 12, 1993
been purged, wh.ichever occurs first. Record this information on the Ground Water
Sampling Log.
9. Having purged the required amount of ground water, prepare for sampling. Remove
the sampling bottles from their transport containers, and prepare the bottles for
receiving samples. Inspect all labels to insure proper sample identification. Sample
bottles should be kept cool with their caps on until they are ready to receive samples.
Arrange the sampling containers to allow for convenient filling. Begin the Chain of
Custody Record. Samples will be collected as soon as technically feasible and within
24 hours of the purging procedure.
10. In order to collect ground water samples, lower the bailer into the well slowly, in an
effort to minimize degassing of the sample. Record the physical appearance (color,
odor, and presence of floating product) of the ground water on the Ground Water
Sampling Log.
1 l. Fill the sample bottles in the order shown in Appendix D. Appendix D also lists the
analytes and preservatives which match the sample containers.
12. Containers for volatiles sampling require a teflon-covered septum top. The vials
require preservative. Prior to filling with ground water, add preservative to the vials.
2-5
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
The preservative consists of 0.2 ml (per vial) of a mixture of 1 part A.C.S. reagent
grade, concentrated hydrochloric acid (approximately 38%) to 1 part of organic-free
water. (As an alternative, the preservative may be added by the laboratory to the
containers before the containers arrive at the site.) The addition of preservative will
adjust the pH to less than 2. Fill the vial with ground water from one bailer, then
securely cap it. Turn the vial upside down and check for air bubbles. If properly
filled, there should be no air bubbles.
13. Containers labeled "metals" require preservative. Prior to filling with ground water,
add preservative, which consists of A.C.S. reagent grade, concentrated (approximately
69-71 % ) nitric acid. (As an alternative, the preservative may be added by the
laboratory to the containers before the containers arrive at the site.) The addition
of preservative is performed to adjust the pH to less than 2. One set of metals
samples must be filtered through a 0.45 micron filter, before the preservative is
added to the sample. Samples bottles which are-prepared in the field with
preservative will be field checked for pH so that the the metals are properly
preserved.
14. After being filled, sample containers should be stored at 4° C in the cooler for
transport. The samples must not be allowed to freeze.
2-6
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
15. Replace the well cap. Lock the well protection assembly before leaving the well
location.
16. Place the polypropylene rope, gloves, plastic sheeting, and other trash in a suitable
trash receptacle before leaving the well location, for proper disposal after sampling.
17. Contaminated water which is generated during the sampling is to be discharged to
the Charlotte-Mecklenberg Utility District where permitted.
2.03.02 Collection Steps (Pump)
1. Using the well depth and the depth to water reading, compute the volume of water
in the well, and record this volume on the Ground Water Sampling Log.
2. Put on a new pair of protective/nonreactive gloves at each well. Wear
protective/nonreactive gloves throughout the ground water sampling procedure.
3. Prepare the pump for operation. The pump to be used is a WaTerra hand-operated
inertial pump. Connect the dedicated polyethylene tubing to a delrin foot valve.
2-7
D'ARlfN & Gf::Ht tNGINEERS
• •
Revised February 12, 1993
The tubing will be dedicated to a well and therefore not used to purge any other
well. The pump will be used to purge only. Samples will be collected with a bailer.
4. Lower the pump intake within two to three feet below the top of the water column
and pump the ground water into a graduated pail while monitoring the water level.
Periodically lower the pump intake level so that it remains approximately two to
three feet below the top of the water column. However, if a floating product layer
is observed, the pump intake should be kept near the bottom of the well, in order
to minimize disturbance of the floating product layer.
5. After approximately one liter of water has been purged, record the physical
appearance (color, odor, and presence of floating product) of the ground water on
the Ground Water Sampling Log. Also, measure and record the field parameters
(pH, conductivity, temperature, and turbidity) of the ground water. These field
parameters are to be measured and recorded after each well volume of water is
purged, in an effort to determine whether a representative ground water sample is
being obtained from the well. Stabilization of the parameters indicates a
representative sample.
6. Purge until three well volumes have been removed. If a minimum of one well
volume has been purged, and the aforementioned field parameters have stabilized,
2-8
O'BRIEN & GLHL LNGINEERS
... --, • •
Revised February 12, 1993
then proceed with sampling. If the field parameters have not stabilized, then wait
for the well to recharge, and continue purging until the field parameters have
stabilized, of three well volumes have been purged, whichever occurs first. Record
this information on the Ground Water Sampling Log.
7. Cut a slit in the center of a plastic sheet, and slip it over the well, creating a clean
surface onto which the sampling equipment can be positioned.
8. Prepare the stainless steel bailer for sampling. Before sampling, the bailer should
have been transported to the site wrapped with material that is nonreactive with the
equipment or the constituents of concern in the ground water. Clean the bailer with
soapy water (using phosphate-free soap and tap water), a tap water rinse, a deionized
or distilled water rinse, an isopropyl alcohol rinse, and a deionized or distilled water
rinse. Allow the equipment to air dry.
9 Attach the polypropylene rope to the bailer.
10. To collect ground water for the samples, bail the well from the top of the water
column, making certain to keep the polypropylene rope on the plastic sheet.
11. Remove the sampling bottles from their transport containers, and prepare the bottles
2-9
O'Br11EN & GERE ENGINfEHS
• •
Revised February 12, 1993
69-71 % ) nitric acid. (As an alternative, the preservative may be added by the
laboratory to the containers before the containers arrive at the site.) The addition
of preservative is performed to adjust the pH to less than 2. Samples bottles which
are prepared in the field with preservative will be field checked for pH so that the
the metals are properly preserved. One set of metals samples must be filtered
through a 0.45 micron filter, before the preservative is added to the sample.
15. After being filled, sample containers should be stored at 4° C in the cooler for
transport. The samples must not be allowed to freeze.
16. Replace the well cap. Lock the well protection assembly before leaving the well
location.
17. Place the polypropylene rope, gloves, plastic sheeting, and other trash in a suitable
trash receptacle before leaving the well location, for proper disposal after sampling.
18. Contaminated water which is generated during the sampling is to be discharged to
the Charlotte-Mecklenberg Utility District where permitted.
2-11
O'BRIEN & GERE ENGINlLHS
• •
Revised February 12, 1993
2.04 Sample Identification and Shipment
The containers will be labeled with an indelible marker. Information on the
container label will be as follows: place of collection, sample identification number, date
and time of sample collection, parameters requested, type of preservative, and name of
sample collector. An example of a container label is below.
CTI
well: MW7, July 18, 1993, 2 p.m.
analytes: volatile organics
preservative: HCl
J. Smith
The samples will be transported from the site to the laboratory in plastic coolers, via
overnight courier.
2.05 Chain of Custody
A sample chain of custody form is included as Appendix E.
2.06 Analytical Methods
Appendix F contains a list of analytes and methodologies that may be required during
ground water programs conducted at the Central Transport, Inc. site in Charlotte, NC. The
wells to be sampled and the parameters to be analyzed for assessment will be specified in
the most recent ground water assessment plan; the wells to be sampled and the parameters
to be analyzed for post-closure monitoring will be specified in the approved post-closure
plan.
2-12
O'BRIEN & GERE ENGINEFRS
• •
Revised February 12, 1993
SECTION 3 ·SCHEDULE FOR IMPLEMENTATION
40 CFR 265.93( d)(7)(i) requires that sampling be conducted quarterly until final
closure of the facility. The sludge and underlying soils from former lagoons at the site were
removed from October 1990 ~January 1991. The design for the final cover for the area
previously occupied by the lagoons was approved by the State in November 1992.
Installation of the final cover commenced the week of February 8, 1993. Based upon this
schedule it is anticipated that one quarter will elapse following acceptance of this sampling
and analysis plan and installation of the final cover at the facility. One quarterly round of
samples will be collected during February 3-11, 1993. In the event that closure is not
completed as presently anticipated, a second quarterly round of samples will be collected
three months after the first quarterly round (mid-May, 1993). Once closure is complete,
sampling will be conducted in accordance with the Post-Closure Monitoring Plan dated
December 1992 and as otherwise agreed. Analytical data will be submitted to the State of
North Carolina 45-60 days after the samples are collected.
O'ORICN & GERE ENGINEERS
• •
Revised February 12, 1993
APPENDIX F
Analytical Procedures
Following is a list of analytes and methodologies that may be required during ground water
programs conducted at the Central Transport, Inc. site in Charlotte, NC. The required
methodologies will be as specified in the Ground Water Assessment Plan submitted in
December 1992, in the Post-Closure Monitoring Plan submitted in December 1992 or other
work plans that may be developed.
Parameter
In organics
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Cyanide
Test Method from SW-846
EPA 6010
EPA 6010
EPA 7060
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 6010
EPA 6010
EPA 7740
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 9012
F-1
•
WORK PLAN
GROUND WATER ASSESSMENT PLAN
CENTRAL TRANSPORT, INC.
CHARLOTTE, NORTH CAROLINA
DECEMBER 1992
REVISED FEBRUARY 12, 1993
O'Brien & Gere Engineers, Inc.
8201 Corporate Drive, Suite 1000
Landover, Maryland 20785
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
ground water contamination in the vicinity of MW-7 and MW-8. Specifically, there are two
objectives:
1). verify the eastern edge of the plume, and
2). assess whether the contamination near MW-7 extends into the deeper bedrock
aquifer.
Sampling of the production well will be utilized to delineate the eastern edge of the
plume. A newly installed bedrock well (designated MW-17) will be utilized to further define
the vertical extent of contamination in the vicinity of MW-7. Installation of well MW-17 is
more fully described in Section 2.01.
1.03 Description of Ground Water Monitoring System
The ground water monitoring system will consist of wells MW-6, MW-7, MW-8, MW-
9, MW-10, MW-11, MW-13, MW-15, MW-16, and a newly installed bedrock well designated
MW-17. Figure 1 is a site map which shows the locations of the monitoring wells, the
proposed location of MW-17, and other site features, including the former waste
management units (the lagoons.)
The ground water monitoring system is required to include at least one monitoring
well hydraulically upgradient of MW-7 and MW-8; the proposed system includes four
upgradient wells, MW-6, MW-9, MW-10, and MW-15. The ground water monitoring system
is required to include at least three wells in the vicinity of MW-7 and hydraulically
downgradient of the lagoons; the proposed system includes six downgradient wells, MW-7,
1-4
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
MW-8, MW-11, MW-13, MW-16,and the newly installed MW-17 are provided. Two of these
are installed in the "deep bedrock" (MW-16 and MW-17)
Table 1 contains well specifications. The table includes the following data for each
well (except where noted); the screened interval; the elevation of the measuring point (for
water level measurement); and the elevation of the land surface. Data in Table 1 is
accurate to the nearest 0.01 foot, except where noted.
1-5
Cl'AHlf:N & GtHE lNGINEERS
• •
Revised February 12, 1993
SECTION 2 . MONITORING AND COLLECTION PROCEDURES
2.01 Additional Well Installation
In order to assess the potential for vertical ground water contamination in the vicinity
of MW-7, one additional bedrock monitoring well (MW-17) will be installed at the site. The
well will be located adjacent to monitoring well MW-7 so that a well nest is formed. The
additional well will be deeper than MW-7. MW-17 will be completed at a depth which is
a minimum of approximately 25 feet deeper than MW-7 in the first water bearing zone
encountered at or below the minimum depth. A zone will be considered to be water
bearing if it yields a minimum of approximately 1 gallon per minute.
The well installation will be completed using the air rotary drilling method, with a
nominal six-inch diameter bit. The drill cuttings will be inspected in the field for lithology
and moisture content. Once the desired depth has been reached, the monitoring well will
be constructed by lowering an assembly of two-inch inside diameter, flush joint threaded,
PVC well screen and riser casing into the borehole. The well assembly will consist of 10
feet of PVC screen, with 0.010-inch slot size, attached to an appropriate length of riser
casing. A clean sand pack will be installed in the annular space between the well screen
and the borehole. The sand pack will extend two feet above the top of the well screen. A
two-foot thick bentonite seal will then be placed on top of the sand pack. The remaining
annular space between the borehole wall and the well casing will be filled with a cement
2-1
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
grout. The grout will extend to the ground surface, where a locking steel flush mounted
protective casing will complete the well.
A typical well construction diagram is included in Figure 2. The well construction
will be in accordance with the North Carolina Administrative Code, Title 15, Subchapter 2C
-"Well Construction Standards'', Section .0108-Standards of Construction -Wells other than
Water Supply". A well construction permit will be obtained from the State prior to well
installation as required.
Following installation of the well, the well will be developed using compressed air
or pumping methods io order to clear fine-grained sediments from the well screen. Air from
the compressor will be filtered to minimize the possibility that oil is introduced into the
ground water. Water generated from well development will be discharged to the Charlotte-
Mecklenburg Utility District under a Special Use Discharge Permit where permitted.
Equipment used for well installation that comes in contact with potentially
contaminated material will be decontaminated with a high pressure steam clean wash.
Water generated from equipment decontamination will be discharged to the Charlotte-
Mecklenburg Utility District under a Special Use Discharge Permit where permitted.
Potentially contaminated media (including soil) generated during well installation will
be managed appropriately. Analytical methods will be used as appropriate to evaluate the
proper disposal options.
2-2
O'BRIEN & GERE cNGINEERS
• •
Revised February 12, 1993
A field survey will be conducted to determine the location and elevation of the well.
Both the ground surface elevation and top of PVC casing elevation will be obtained for the
well. The survey will be completed using an established on-site bench mark.
2-3
O'BRIFN & GERE ENGINEERS
• •
Revised February 12, 1993
2.02 Sampling Methods
One round of ground water samples will be collected from the following wells: MW-
6, MW-7, MW-8, MW-9, MW-10, MW-11, MW-13, MW-15, MW-16, and a newly installed
bedrock well designated MW-17. Ground water purging or sampling procedures will not be
initiated at MW-17 until a minimum of 24 hours after its development.
Ground water sampling procedures will be according to the Sampling and Analysis
Plan dated December 1992 and revised February 12, 1993.
2.03 Analytical Methods
Ground water samples will be analyzed in accordance with the Sampling and Analysis
Plan dated December 1992 and revised February 12, 1993. Samples will be analyzed for all
constituents included in Appendix F. CTI reserves the right to eliminate some of the
parameters from future quarterly rounds, if conducted.
2.04 Evaluation Procedures
CTI may elect to perform statistical analyses to evaluate whether contaminants that
may be detected are statistically significant. Background arithmetic means, variances and
standard deviations for indicator parameters from upgradient wells will be calculated. Based
on an evaluation of ground water quality data collected at the site since 1989, an
appropriate statistical procedure for comparing upgradient and downgradient wells will be
2-4
O'BHICN & GERE ENGINEERS
• •
Revised February 12, 1993
on an evaluation of ground water quality data collected at the site since 1989, an
appropr.iate statistical procedure for comparing upgradient and downgradient wells will be
selected. The statistical procedure will be selected in accordance with the US
Environmental Protection Agency Guidance entitled " the Statistical Analysis of Ground
Water Monitoring Data at RCRA Facilities", Interim Final Guidance Office of Solid Waste,
dated February 1989. As stated in Section 5 of the referenced guidance document, if more
than 50% of the observations are below the detection limit then the appropriate method is
a test of proportions. If the proportion of detected values is 50% or more, then an analysis
of variance procedure will be used. A statistical analysis will be performed on any
constituent analyzed that has been detected above the detection limits at least once.
O'BRIEN & GERE ENGINEERS
• •
Revised February 12, 1993
SECTION 3 -SCHEDULE FOR IMPLEMENTATION
The investigations outlined in this ground water assessment plan will be implemented
in accordance with the following schedule:
Acceptance of Plans by State
Installation of MW-17
Sampling of wells
Submittal of Report
3-1
Schedule
0 weeks
4 weeks (Feb 8-9, 1993)
5 weeks (Feb 3-11, 1993)
11 weeks (March 8, 1993)
O'BRIEN & GERE ENGINFERS
• •
other potentially contaminated surface.
ln step #8, sentence #3 contradicts sentence #4. Please clarify.
Step #9 should include a statement saying that samples will be
collected as soon as technically feasible and within 24 hours of
the purging procedure.
In step #13, including a field check of the pH would ensure that
the metals were properly preserved.
Step #14 should include •.. "stored" at 4° C.
step #17 should include a reference to documentation of any
disposal arrangements with the Charlotte-Mecklenberg Utility
District. The documentation should be provided in an appendix to
the sampling and analysis plan.
Section 2,03.02
Refer to the applicable comments described above.
Section 2.06
This section should include a statement which specifies the
parameters which will be analyzed during quarterly monitoring and
the schedule for quarterly monitoring. CTI must submit this
information by January 29, 1993.
The second sentence should read, "The wells to be sampled and the
parameters to be analyzed for assessment will be specified in the
most recent ground water assessment plan; the wells to be sampled
and the parameters to be analyzed for post-closure monitoring
will be specified in the approved post-closure plan."
Note.
Appendices
The schedule for post-closure quarterly monitoring
should be included in the post-closure plan.
Appendix F should include SW-846 methodology for the inorganic
parameters.
Note.
Section 2.01
SW-846 methodology is consistent with the
methodology required in the post-closure plan.
GROUND WATER ASSESSMENT PLAN
Air from the compressor should be filtered to ensure that oil is
not introduced into the ground water system.
• •
Contaminated media (including soil) generated during well
installation must be managed appropriately. Analytical methods
should be used to determine the appropriate disposal options.
Section 2.02
This section should include a statement describing which
parameters will be analyzed during the assessment.
Section 2.04
CTI may perform statistical procedures, but they are not a
requirement of the assessment (or the post-closure) program.
CTI should submit the information requested about quarterly
monitoring by January 29, 1993. CTI should respond to the
comments in this letter by February 12, 1993.
If you have any questions, please call me at [phone].
Sincerely,
;/au·-v·r~
Laurie Martin, Hydrogeologist
Waste Management Branch
Hazardous Waste Section
cc: John Lank
Katherine O'Neal
Phil Delp
Marc Fleischaker
John Doyle
~ii!<]7~iLJl!S
• •
GUIDANCE FOR THE DEVELOPMENT OF
A GROUND WATER SAMPLING AND ANALYSIS PLAN
This guidance manual has been developed in an effort to assist
facilities engaged in ground water monitoring programs to develop a
written sample collection protocol. A detailed written protocol
will enable facilities to use consistant sample collection
procedures throughout the life of the monitoring program.
The manual is broken down into several sections including:
1. Description of the Ground Water Monitoring System;
2. Ground Water Sample Collection LogBook;
3. Water Level Monitoring;
4. Ground Water Sample Collection Procedure;
5. Sample Identification and Shipment;
6. Chain of Custody;
7. Analytical Methods; and
8. Sample Collection Schedule.
Each of the above topics should be addressed in the plan in as much
detail as possible.
Revised 5/21/91
1/14/92
7/22/92
1
• • .I.,,,_ Description of the Ground Nater Monitoring System
The ground water sampling and analysis plan (S&A plan) should
include a description of the ground water monitoring system. The
description of the ground water monitoring system should include
the following items.
a. a description of regional, local, and site hydrogeologic
conditions.
b. the well completion reports for each well.
c. a topographic map of the facility (maximum scale: 1" ~ 200')
identifying streams, plant building(s), waste management
unit(s), monitoring wells and other pertinant features.
d. a description of the vertical and horizontal components of
ground water flow including plan view and cross section maps.
e. the elevation of the top and bottom of the screen (to the
nearest 0.01 ft.) for each well.
f. the elevation of the measuring point and land surface (to the
nearest 0.01 ft.) at each well.
g. the identification of the measuring point for each well.
All of this information will enable the facility to document that
the monitoring system is capable of monitoring changes in the
ground water quality due to activities at the facility.
I.I.._ Ground Water Sample Collection Log Book
A logbook should be maintained at the facility documenting each
sampling event. The following field observations should be
documented in the logbook.
a. name(s) of the people present.
b. date of the sampling event.
c. environmental conditions.
d. unusual site conditions (for example: damaged well casing,
well cover was missing, etc.).
e. the following items should be documented for each well:
1. equipment used for water level and well depth measurements;
2. depth to the water level below the measuring point;
3. depth to the bottom of the well below the measuring point;
4. elevation of the water level;
5. well purging time and date;
2
• • 6. equipment used for purging;
7. amount of water removed during purging;
8. sample collection time and date;
9. equipment used for sample collection;
10.field measurements; and
11.types and number of sample containers filled at each well
and any special handling procedures (i.e. preservation
procedures, etc.) •
.I1.!.... Water Level Monitoring
The S&A plan should describe the water level monitoring
procedure including the following items.
a. a statement specifying that static water level measurements
from all wells are obtained prior to beginning the well
purging procedure at any well (static water level measurements
in this case are those measurements taken after the water in
the well has been allowed to reach equilibrium or more than 24
hours has passed since any water has been removed from or
injected into the well, whichever is greater).
Note: if well caps with air/water tight seals are used on the
wells then the caps should be removed and the water
level in the well should be allowed to equilibrate with
the ambient atmospheric pressure prior to obtaining the
water level measurement.
b. a description of the equipment used to obtain the water level
measurements, and how this equipment will be decontaminated
between each well.
c. a statement specifying that well depths are confirmed during
each ground water monitoring event.
d. a statement specifying that all measurements are accurate to
0.01 feet.
e. a statement specifying that the water level and well depth
measurements are documented in the field logbook.
f. a statement specifying that protective/nonreactive gloves will
be worn throughout the water level monitoring procedure.
g. a statement that water level measurements will proceed from
the least to the most contaminated wells based on the most
recent historical analytical data.
IV. Grgµnd Water Sample Collection Procedure
A discussion of the well purging and sampling procedure should be
included in the S&A plan. The description of the procedures
3
should be as spe~fic as possible and includ~~ description of:
the equipment used at each well; the handling procedures for the
contaminated water generated during sample collection; the
equipment cleaning procedures; and the frequency of equipment
cleaning. Any specialized sample collection procedures should
also be specified in the S&A plan.
a, The description of the well purging procedure should specify
the following items.
1. the equipment used in well purging.
2. how the well purging equipment is used. For example:
the pump intake is maintained at the top of the water
column in order to remove all of the standing water in the
well casing.
3. volume of water to be removed in order to determine that a
representative sample has been obtained. For example:
a. three well volumes are removed; or
b. well is purged to dryness; or
c. one well volume is removed and the field parameters
(including pH, specific conductance, and temperature)
stabilize.
Note: field parameters should be obtained before and after
sample collection to ensure that a representative sample
has been collected.
4. field measurements are obtained.
S. protective/nonreactive gloves are worn throughout the well
purging procedure.
Note: It is recommended that each facility use equipment
constructed of stainless steel and/or teflon during all
phases of the ground water sample collection procedure.
If any facility chooses to use equipment constructed of
other material, the facility must demonstrate through
the inclusion of manufacturer's specifications and field
testing that the sampling equipment is constructed of
materials which will not affect the quality of the
sample.
b. A description of the well sampling procedure should include
the following items.
1. the equipment used in sample collection.
2. how the sample collection equipment is used.
3. the field measurements (pH, specific conductance,
temperature, etc.) obtained.
4. the order in which sample containers are filled.
S. the type and number of sample containers used.
6. the sample preservation procedures.
7. the type and number of QA/QC samples (i.e. fiel~ blanks,
trip blanks, equipment blanks, etc.).
8. any special sample collection procedures (for example -
sample bailers are lowered into the well slowly in an
effort to prevent degassing of the sample) .
4
• • 9. a statement specifying that protective/nonreactive gloves
will be worn throughout the sampling procedure.
Note: It is recommended that each facility use equipment
constructed of stainless steel and/or teflon during all
phases of the ground water sample collection procedure.
If any facility chooses to use equipment constructed of
other material, the facility must demonstrate through
the inclusion of manufacturer's specifications and field
testing that the sampling equipment is constructed of
materials which will not affect the quality of the
sample.
c. A list of the equipment used during the ground water sampling
event should be included. Also, the cleaning procedures and
frequency of cleaning of the equipment should be included. It
is recommended that the following cleaning procedures be used.
Stainless Steel Equipment
phosphate-free soap and tap water wash
tap water rinse
deionized or distilled water rinse
isopropyl alcohol rinse
deionized or distilled water rinse
air dry
wrap equipment with material that is nonreactive with the
equipment or the constituents of concern in the ground
water prior to transport into the field
Teflon Equipment
phosphate-free soap and tap water wash
tap water rinse
10% nitric or 10% hydrochloric acid rinse
deionized or distilled water rinse
isopropyl alcohol rinse
deionized or distilled water rinse
air dry
wrap equipment with material that is nonreactive with the
equipment or the constituents of concern in the ground
water prior to transport into the field
d. A list of any specialized sample collection procedures should
be included. For example:
Samples collected for volatile organic analyses should be
collected in a glass bottle with a teflon covered septum top.
The samples should be collected with no headspace ~n order to
prevent volatilization. Samples to be analyzed for organic
compounds are transferred from the sample collection equipment
directly into the sample containers without filtering.
5
• •
y.._ Sample Identification and Shipment
The S&A plan should include a description of the sample
containers, an example of a sample container label, and shipment
procedure. The description should include the following items.
a. how the containers are labeled.
b. the items to be included on a sample label, specifically:
1. place of collection;
2. sample identification number;
3. date and time of sample collection;
4. parameters requested;
5. type of preservative; and
6. name of sample collector.
c. the procedure used to transport the samples from the site to
the laboratory for aJJalyses.
:llI.,_ Chain of Custody
The S&A plan should include a description of the chain of custody
procedure and a sample chain of custody form. The chain of
custody form should inclullle the following items.
a. sample and well identi~ication.
b. signature(s) of the Ea11mple collector, transporter, and
laboratory person z;e:ce:i:ving the sample.
c. inclusive dates of Sall![llle possesion.
d. date and time of sample collection.
e. number of containers ..
f. requested parameters.
g. special requests.
h. laboratory number.
:llI1... Analytical Methods
The S&A plan must specify an EPA approved analytical method found
in EPA publication SW-8·46 for each constituent specified in the
sample collection schedule. •
• • VIII. Schedµle for Sample Reporting
The S&A plan must include a schedule for the collection of ground
water samples. The schedule must specify the following items.
a. the dates (specific months during the year) for sample
collection.
b. the wells to be sampled.
c. the parameters to be analyzed.
d. the dates (specify the number of days after sample collection)
for submission of the analytical data.
GUIDANCE.S&A
?
•• •
v) plans for additional assessment, if necessary, to
define the extent of migration of ground water
contamination.
CTI is also advised that an annual report, as described in 40 CFR
265.94 codified at lSA NCAC 13A .0010, is due by March 1, 1993.
If you have any questions, please call me at [phone].
Sincerely,
,_/ ·~ i7) IU"'-<...t
Laurie Ma tin, Hydrogeologist
Waste Management Branch
Hazardous Waste Section
cc: John Lank
Doug Roberts
Katherine O'Neal
Phil Delp
Marc Fleischaker
John Doyle
central files
•
Ms. Laurie Martin, Hydrogeologist
September 16, 1992
Page 2
Backi:round
•
The results of previous investigations had demonstrated two flow patterns on the eastern
side of lagoons 1 and 2. The non-pumping flow pattern is the natural flow pattern at the
site. Tue second flow pattern resulted when CTI operated a production well at the .site.
With the production well out of service since approximately January, 1992 the ground water
flow has returned to its natural, generally southward trend.
Groundwater Elevations/Geology
Well construction diagrams for observation wells OB-1, OB-2 and OB-3 have been obtained
from Westinghouse/Haztech the remediation contractor and have been used to develop well
construction diagrams found on Figures 3, 4, and 5 and the geologic cross section found on
Figure 6.
To assess the direction of groundwater flow west of the lagoons, ground water elevations
were measured at wells MW-6 through MW-13, MW-16, OB-1, OB-2 and OB-3 on June 3,
1992 and July 14, 1992. The groundwater elevations in the observation wells were lower
than those to the north and east, thus indicated a flow potential to the southwest from the
lagoons, toward the stream. The elevations are summarized on Table 1 and the generalized
flow pattern is depicted on Figures 1 and 2. These data confirmed that wells OB-l, OB-2
and OB-3 will provide representative downgradient samples.
Attachment 8 to the July 11, 1991 hydrogeologic investigation report (see copy attached)
provided a vertical flow cross section. Elevations collected during this supplemental
investigation does not suggest that vertical flow conditions at the site have changed.
Groundwater & Sb'eam Samples
Ground water samples were collected from wells OB-1, OB-2 OB-3 and surface water
samples were collected from the intermittent stream on July 14, 1992 and August 11, 1992.
Samples were collected in accordance with the protocols described in the May 1992 work
plan. The analytical results are summarized on Table 2. The samples were analyzed for
volatiles, base neutral/acid extractables, pesticides/PCBs and metals using the EPA
analytical methods outlined in the May 1992 Work Plan. No volatiles, base neutral/acid
extractables, pesticides/PCBs or herbicides were detected in either of the two sampling
rounds. Chromium and lead were detected in unfiltered ground water samples above the
MCLs however the concentrations detected were similar in magnitude to the results
consistently found in upgradient wells MW6, MW-9 and MW-10.
O'BRIEN & GEHE
• Ms. Laurie Martin, Hydrogeologist
September 16, 1992
Page 3
Conclusions
•
O'Brien & Gere finds no evidence of material release of contaminants to the sou th or west
( downgradient) to the lagoons. This conclusion is based primarily upon the following:
Confirmation of groundwater flow toward the south and west from the
lagoons (See Figures 1 & 2).
No contaminants detected west of the lagoons in two rounds of sampling from
OB-1, OB-2 and OB-3.
No significant contamination detected south of the lagoons in several rounds
of sampling from MWll, 13 or 16.
No contaminants detected in two rounds of stream samples.
The sum of all investigations to date continue to indicate only a limited area of groundwater
contamination, in the vicinity of MW-7 (See Figure 7).
CTI has in correspondence dated September 10, 1992 committed to closing the lagoon area
as a landfill and monitoring downgradient wells MWll, 13 and 16 together with MW-7 for
up to 30 years. The results of this supplemental investigation will be utilized to support CTI
in a future petition for a reduced post-closure monitoring period.
Please advise if the information contained in this letter requires clarification by contacting
the undersigned or Ms. Terry L. Norman of this office.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
-~f 13' f(:T-G~Rest, P.E.
Vice President
GBR:TLN:mjh
cc: T. Norman
G. Swenson
A. J. Ramsey
G. Simpson
J. Doyle, Esq.
M. Fleischaker, Esq.
O'BRIEN & GERE
Page 1 of 4
TABLE 1
WELL SPECIFICATIONS ANO GROUND WATER ELEVATIONS
CENTRAL TRANSPORT, !NC. -CHARLOTTE TERMINAL
1-0/11/89 11/15/89 6/2)/90 11/3/9D 1/4/91 *TOP OF
PVC GROUND GROUND GROUND GROUND GROUND
WELL GROUND SCREENED CASING WATER WATER WATER WATER WATER WELL WELL DEPTH ELEVATION INTERVAL HEVATION ELEVATION ELEVATION ELEVATION £LEVATION ELEVATION
NO. TYPE (BGL) (MSL) (BGL) (MSL) (MSL) (MSL] (MSL) (MSL) (MSL)
overburden 19 766.1 9-19 766.85 751. 94 751.32 750.15 751.05
1 overburden 14 769.8 14-14 771.59 751.11 751.14 751. 14 751.41 753.89 • 6 bedrock 35.5 169.6 15.5-35.5 771.17 751.47 751. 57 154. 75 750.67 755.59
bedrock 39 768.7 29-39 168. 71 750. 71 750.36 151. 39 749. 61 751.16
8 bedrock 31 769.9 11-31 711.54 751. 38 751. 79 153 .16 750 .79 753. 49
9 Dedrock 51 769.4 41-51 771. 83 755.68 755.18 755.11 754.31 756.78
10 bedrock 51 ISS.3 41-51 161.48 755.66 755.31 755.55 155 .08 756.93
11 bedrock 11 755.5 17-11 757. 68 148 .18 147.98 748.91 748.&4 748.85
11 bedrock 100 755.1 90-100 157 .49 --------660.86 748.19 721. 79
13 bedrock 29 759.5 19-19 761. 74
14 l:tedrock 59 169.55 49-59 768.91 ----------------ISO.OJ
15 bedrock 65.5 769. 50 55.5-65.5 168.99 ------------719.14
16 bedrock 16 759.l 66-76 ltil.81
A ----36.31 771.0 771.54 ------------ ----760. 74
B ----34.98 769.1 ----769. 55 --------758.90 • c ----36.48 768.1 ----769.02 --------756.37
0 ----30.66 761.5 ----767.78
Sl stream point 15>.4 ----756.39 --------753.89
$2 stream point 749.2 ----153. 50 --------749.68
$3 st ream point 745.1 ----748.68 ------------145.18
---I
Page 2 of 4
TA8LE 1
WELL SPECIFICATIONS AND GROUND WATER ELEVATIONS
CENTRAL TRANSPORT. INC. -CHARLOTTE TERMINAL
3/7/91 3/18/91 3/17/91 5/1/91 5/3/91 *TOP OF NON-PUMPING PUMPING PVC GROUND GROUND GROUND GROUND GROUND WELL GROUND SCREENED CASING WATER WATER WATER WATER WATER WELL WHL DEPTH REVAT!ON INTERVAL ELEVATION ELEVATION ELEVATION ELEVATION ELEVATION ELEVATION NO. TYPE {BGL) (MSL) (SGL) (MSL) (MSL) (MSL) (MSL) (MSL) {MSL)
over-burden 19 761>.2 9-19 766.85 752.55 747.01 752.01 752. 49 751.39
2 overburden 14 769.8 14-14 77L59 754.15 744.67 754 .19 755.47 755.01
6 bedrock 35.5 769.6 15.5-35.5 771.17 756.20 734.36 755.46 758.47 757 .35
bedrock 39 768.7 19-39 768. 71 751.99 719 .36 751. 26 752.56 751. 79 • 8 Dedrock 31 769.9 11-31 771.54 753.91 741.56 753.61 755.37 754 .54
9 bedrock 51 769.4 41-51 771. 83 757.98 718.19 757 .30 757. 53 757.44
10 bedrock 51 765.3 41-51 767.48 757.93 714.10 757.36 757. 50 757.42
11 bedrock 17 755.5 17-27 757. 68 749.23 728.liO 748.79 748. 73 748.68
11 bedrock 100 755.J 90-100 757 .49 736. 79 654 .69 663. 64 705.11 706.11
13 bedrock 19 759.5 19-19 761. 74 ------------749. 27 749 .OS
14 bedrock 59 769. 55 49-59 768.91 750.91 710. 67 750.63 751.13 750.95
15 bedrock 65.5 769. 50 55.5-65.5 768.99 742.19 729.87 755.85 717.36
16 bedrock 76 759.7 66-76 761. 81 ------------751.39 751. 22
A ----36.31 777.0 ----777. 54 761. 51 761. 67 762.14 761.11
8 ----34.98 769.1 ----769.55 760. 00 ----759 .82 760.09 760. 04
c ----36.48 768.1 ----769.02 757.00 ----756.37 758. 22 757 .57 • 0 ----30.66 767 .5 ----767.78 ------------750. 06 750.01
Sl stream poirit ----753.4 ----756.39 754.16 754.10
S1 st ream poi nt ----749.1 ----753 .50 749 .77 ----749 .68
S3 stream point 745.1 ----748. 68 745. 58 ----748. 68
Page 3 of 4
TABLE J
WELL SPECIFICATIONS ANO GROUND WATER ELEVATIONS
CENTRAL TRANSPORT, !NC. -Cl!ARLOTTE TERMINAL
8/23/91 9/17/91 06/03/92 07 /14/92
*TOP OF NON-PUMPING NON-PUMPING NON-PUMPING NON-PUMPING
PVC GROUND GROUND GROUND GROUND WELL GROUND SCREENtD CASING WATER WATER WATER WATER WELL WELL DEPTH ELEVATION INTERVAL ELEVATION ELEVATION ELEVATION ELEVATION ELEVATION NO. TYPE I BGL) (MSL) (BGL) (MSL) (MSL) {HSL) (MSL) (MSL)
overburderi 19 766.2 9-19 766.85 751.43 747 .81
overburden 24 769.8 14-24 771. 59 755.01 751.87
5 bedrock 35.5 769.6 25. 5-35. 5 772 .1 I 758.12 755.05 159.23 756.98
bedrock 39 768.7 29-39 758.11 752 .05 748. 72 150.77 750.95 • 8 bedrock 32 769.9 22-32 771.54 755.08 751.96 152.96 752.24
9 bedrock 51 769.4 41-52 771.83 754.52 751. 01 155.06 7 51.14
10 bedrock 51 765.3 41-51 751 .48 755.21 755.00 755.65 751.97
11 bedrock 17 755.5 11-17 751.68 747.83 741.13 748.l 745.56
12 bedrock 100 755. l 90-100 751. 49 747.52 749.21 749.56 747.09
13 bedrock 19 759.5 19-29 701. 74 748.84 748 .14 748.61 746.23
14 i>edrock 59 169. 55 49-59 768.91 749.33 749. 04
15 i>edrock 65.5 169. 50 55.5-65.5 768.99 755.84 753. 26
16 l>edrock 76 759.7 66-16 161. 81 751.03 750.97 749.83 747. 65
~ ----36.31 777 .0 117. 54 759. 52 755.89
8 34.98 759.2 ----169.55 755.87 752.64
c ----36.48 158.1 ----lli9. 01 757. 75 754.6
0 ----30.66 157.5 ----167. 78 748.13 747.9 ----• SJ stream point ----753.4 ----156. 39
52 strearn point ----749.1 153.50
S3 stream point 745.2 ----148. 08
081 observation 25 753 .14 5-25 152.31 --------747 .94 749. 01
081 observation 20 753.86 5-20 153.36 ----750.52 750.87
OB3 observation 26 761. 03 6-26 160.45 ----750.01 751. 09
Page 4 of 4
ABBREVIATIONS :
NOTES:
•
•
BGL is 8elow Ground Level.
MSL is Hean Sea Level.
BTOC is Below Top of Casing.
"----" is Nat Available/Not Applicable.
All rneas~rements are in feet.
Well No. 12 installed 6/25/90.
Well No. 14 installed 1/17/91.
Well No. 15 installed 1/18/91; ~round water elevations may De influenced by nearby production well. Well Nos. 13 and 16 installed 4/13/91.
Wells A, a, C, and D not installed Dy O'Brien & Gere; well types and screened intervals not known. * Stream points staked 12/7/90; "top of casing elevation" for stream points is top of stake elevation .
"Ground water elevation" for stream points is surface water elevation.
Stream point S3 was destroyed during the installation of wells 13 and 16.
2/28/Sl elevations -east side wells are lowest elevations; west side wells are from end of day.
5/2/91 -earliest data
5/3/91 -lowest data from second ~umping cycle
•
Laurie Martin, Hydrogeologist
August 14, 1992
Page 2
•
summarizing the results of the July 14, 1992 sampling event was provided to
the State of North Carolina in a submission to Mr. Hamner on August 7,
1992. No volatiles, base neutral/acid extractables or pesticides/PCB's were
detected.
3. O'Brien & Gere is awaiting receipt of well logs/construction diagrams from
CTI's remediation contractor.
4. A report which includes water quality data from the August 11, 1992 sampling
event, a flow net in plan view and cross section, and updated lithologic cross
sections will be submitted to the State no later than September 14, 1992.
Please advise if additional information or clarification is required.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
Jvv2; ~ 74~~/-r4t;Jd,
Terry L. Norman
Project Engineer
TLN:mjh
Attachments
cc: G. Simpson
M. Fleischaker, Esq.
J. Doyle, Esq.
G. Rest
fYBRIEN & GEHE
' •
Laurie Martin, Hydrogeologist
July 8, 1992
Page 2
•
3. O'Brien & Gere has contacted Westinghouse Haztech, the remediation contractor
who installed the wells, and requested well construction diagrams. Available
information on the well construction will be included in the August 14, 1992 report.
4. O'Brien & Gere will collect ground water samples from three observation wells (OB-
1, OB-2 and OB-3) and the intermittent creek downstream of the lagoons near the
culvert. Collecting the sample from the creek is conditional upon there being flow
in the creek.
5. The first round of ground water sampling is tentatively scheduled for the week of
July 13, 1992. Barring some unexpected field or lab complications, this will enable
O'Brien & Gere to submit a report no later than August 14, 1992.
Please advise if you require additional information or clarification.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
.........-----~-~·
\ ~ L JV tfl-'YYIJl..,V\..)
Terry L. Norman
Project Engineer
TLN:mjh
cc: G. Simpson
J. Doyle, Esq.
M. Fleischaker, Esq.
G. Rest, P.E.
O'BRIEN & GERE
• •
5. Assuming the "OB" wells provide representative data, CTI
should submit to the Section, within thirty days after
receipt of the first set of water quality data and no later
than August 14, 1992:
a. water quality data;
b. flow net in plan view and cross seciton;
c. updated lithologic cross sections using the data from
the "OB" wells; and
d. plans for additional assessment including, but not
limited to, the collection of water quality data to
define the vertical extent of contamination.
If you have any questions, please call me at [phone].
Sincerely,
" / YVJ. --'-,;( Cuu-,,,u. I'~
Laurie Martin, Hydrogeologist
Waste Management Branch
Hazardous Waste Section
cc: John Lank
Doug Roberts
Katherine O'Neal
Jesse Wells
D. Keith Masters .
central files ~
Mr. Robert Glaser
May 29, 1992
Page 2
•
It is intended that this supplemental investigation will:
•
1. Obtain additional ground water elevation data points that will permit a more refined
definition of the flow patterns on the site.
2. As appropriate, assess the possibility of a release of contamination from the lagoons
in a direction west of the lagoons via ground water sampling.
If elevations collected in the monitoring wells suggest that wells OB-1 and OB-3 are
downgradient, and samples collected in these wells and in the stream are "clean" then it will
be concluded that there has been no release from the lagoons in the southerly or westerly
directions.
It is intended that implementation of the activities will begin 3 weeks after your concurrence
with the approach outlined in this plan.
Please advise if the information contained in this letter or the accompanying plan requires
additional clarification.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
G~~M
George B Rest, P.E. (~'(\-fl Y))
Vice President
GBR:TLN:mjh
cc: G. Simpson -CTI
L. Wellington -CTI
T. Norman
O'BRIEN & GCRE
•
Mr. Robert Glaser, P.G., Hydrogeologist
March 31, 1992
Page 2
•
3) There are other technical issues which we feel deserve further discussion, and
therefore request a meeting with the Department representatives at your
earliest convenience. The purpose of the meeting will be to review the entire
Lagoon Closure Program including the March 9, 1992 and March 25, 1992
letters from the Section. We will contact you and Dr. Hamner within 5 days
to suggest several dates.
Please also note that we received your March 9, 1992 letter on March 23, 1992, and request
a revision to the suggested schedule for the submittal of a groundwater assessment plan by
April 3, 1992. We suggest that a revised submittal date, if a groundwater assessment plan
is still deemed appropriate, can be resolved at the time of the meeting. Thank you for your
consideration in this matter. If you have any questions, please do not hesitate to contact
me, or Terry Norman.
Very truly yours,
O'BRIEN & GERE ENGINEERS, INC.
.4 25. /f:--C Georg~ Rest, P.E.
Vice President
GBR:mjh
cc; G. Honbarrier
J. Doyle, Esquire
M. Fleischaker, Esquire
G. Simpson
J. Carter
W. Hamner, Ph.D.
T. Norman
S. Mogilnicki
O'BRIEN & GERE
• •
the two different flow conditions which occur east of the
lagoons, depending on whether the production well is pumping or
not pumping. Figures 1 (4/18/91), 2 (7/11/91), and 3 (1/17/92)
were submitted to illustrate the flow potential during non-
pumping conditions. Figures 4 (4/18/91) and 5 (7/11/91) were
submitted to illustrate the flow potential during pumping
conditions. These figures illustrate that the flow potential
east of the lagoons is dramatically altered from its natural
condition when the production well is in use.
Figures 4 and 5 illustrate that under pumping conditions, wells
MW-7 and MW-8 are downgradient from the lagoons. ln the May 14,
1991 correspondence to the Section, CTI's consultant reported
that at CTI, volatiles and semi-volatiles were detected in MW-7
and MW-8. Reviewing CTI's ground water quality data (submitted
by CTI's consultant with the January 17, 1992 letter), the
Section notes that the following constituents were detected in
ground water samples from wells MW-8 and MW-7:
MW-8
benzene (32 ppb), 1,1-Dichloroethylene (5 ppb), 1,1,l-
Trichloroethane (16 ppb), and 1,1 Dichloroethane (13
ppb)
MW-7
1,4-Dichlorobenzene (17 ppb), vinyl chloride (88 ppb),
benzene (42 ppb), 1,1-Dichloroethylene (700 ppb),
ethylbenzene (110 ppb), Toluene (11 ppb),1,1,1-
Trichloroethane (11 ppb), xylenes (81 ppb), and 1,2-
Dichloroethene (64 ppb).
CTI has identified ground water contamination downgradient of the
lagoons, and consequently, a ground water assessment plan must be
submitted and implemented. The plan must be in conformance with
40 CFR 265.93(d)(3), codified at lSA NCAC 13A .0010 and must be
implemented in conformance with 40 CFR 265.93(d)(4), codified at
lSA NCAC 13A .0010.
The assessment plan should contain the following elements:
ll the number, location, and depth of wells;
2) sampling and analytical methods for those hazardous wastes
or hazardous waste constituents in the facility;
Note Ill: CTI has consistently referred to the "July
1990 Work Plan for the Supplemental Phase 1
Hydrogeologic Investigation" when referring
to sampling procedures. The Section has a
document entitled "Work Plan -Supplemental
Phase l Hydrogeologic Investigation" in
Appendix E of the Closure/Post Closure Plan
(July 1990 amended January 1991). The
section assumes that CTI is referencing
• •
Appendix E. If this is not true, please send
the Section the July 1990 Work Plan as soon
as possible.
Note 12: On December 31, 1990, the Section sent CTI
conunents on the sampling and analysis plan
included in the "Work Plan -Supplemental Phase 1
Hydrogeologic Investigation" dated June 1990.
These conunents have been attached to this letter.
CTI should incorporate these conunents into a new
sampling and analysis plan. The sampling and
analysis plan should be submitted to the Section
along with the ground water assessment plan.
3) evaluation procedures, including any use of previously
gathered ground water quality data; and
4) a schedule of implementation.
The ground water assessment plan as well as the sampling and
analysis plan must be submitted by April 3, 1992.
Upon completion of the activities described in the ground water
assessment plan due April 3, CTI must submit a ground water
assessment report. The assessment report must be submitted to
the section and contain, at a minimum, the following items.
ll a topographic map of the site.
2) potentiometric maps in both plan view and cross-section
illustrating ground water flow (these maps must be developed
from water level data collected at the site on the same
day).
3) plume maps in plan view and cross-section illustrating the
extent and concentration of the ground water contamination.
Note: The potentiometric and plume maps must include
data that was collected from the same ground water
monitoring event. ~~
4) well construction records, diagrams, and boring logs.
5) description of the ground water assessment activities.
If the extent and rate of migration of ground water contamination
has not been defined by the time the assessment report is due,
then a plan describing additional assessment activities must also
be submitted with the report.
CTI is also advised that an annual report, as described in 40 CFR
265.94 codified at 15A NCAC 13A .0010, is due by March 1, 1992.
• •
If there are any questions, please call me at [phone].
Sincerely,
~~~ Robert Glaser, Hydrogeologist
Waste Management Branch
Hazardous waste Section
cc: John Lank
Doug Roberts
Terry Norman
Katherine O'Neal
Jesse Wells
D. Keith Masters
Judy Bullock
Glenn Simpson
Laurie Martin
Larry Wellington
central files
Table 1
CENTRAL IR~SPORT, INC. -CKARLOTTE TERM!r!AL
GRCIJND WATER QUALITY ANALYSES
MW-1
CATEGORY PARAMETER * Drinking Mater • 11/89 M/90 M/90 12/90 12/90 3{21/91 3/21/91 6/91 6{91
• Stardards • Cfi ltl <until t) (fil t) (unfi lt) (f Ht) (uni Ht) (fil tJ (unfit t) (fil t) ------------------------------------* ---------------• ---------------------------------------------------------
Metals AL wi ll\.01 * None • ND 6.86 0.14 4.6 <0.1 38 0.25 11 <0.1
(ppm) Arsenic • 0.05 mgfl (1) • ND ND ND <0.01D <0.01 <0.01 <0.01 <0.01 <0.01
earilli'I • 1-0 mgfl (1) • 0.17 ND 0.25 <O .1 <0.1 0.41 <0-1 0.18 <0.05
Berylllw * None • ND ND ND 0.03 0.01 0.09 0.01 0.03 0.01
Cadt!iun • 0. 005 mgfl (1) • HD ND ND 0.02 0.01 <0.01 <0.01 <0.01 <0.01
Calcii..m * None • 42.5 0.32 37.5 35 35 38 29 37 32
Chromi Lill • 0 .05 mg/[ (1) • ND 0.01 ND <0.01 <0.01 0.13 <0.01 0.03 0.01
Cobalt * Nooe • 0.03 0.01 0.01 <0.01 <0.01 0.08 <0.01 0.03 <0.01
Copper • 1.0 lll!lll (2) • NO 0.02 0.02 0.01 <0.01 0.18 0.01 0.05 0.01
Iron • 0.03 lll!ll l (2) • 15 .8 35.9 23.3 21 22 99 13 59 17
Lead • 0.05 lll!lll (1) • 0.03 o.oi. 0.03 <0.02 <0.02 0.18 <0.02 0.05 <0.02 • Mag:MS i lll1 * None • 25.1 20.9 19. 5 17 17 27 16 21 17
Manganese • 0.05 lll!lf( (2) • 0.55 0.40 0.31 0.38 0.39 2.4 0.25 1.3 0.22
Mercury • 0.0005 lll!lfl (1) • ND ND ND ND <0.0005 <0.0005 <0.0005 <0.0005 <0.0005
Nickel • 0.15 mgfl (2) • NO 0.02 ND 0.06 0.04 0.07 <0.02 0.02 <0.02
Potassitm * )ilone • 8.1 6.4 6.64 5.6 4.4 3.3 5.6 4.3 6
Silver • 0.05 mg/[ (1) • ND 0.05 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
SodiLlll * None • 237 216 200 260 250 220 21,0 190 200
'Vanadilln • None • 0.1 ND ND 0.02 0.01 0.41 <0.01 0.17 <0.01
Zinc • 5.0 lll!l/l (2) • 0.03 0.01, 0.03 0.07 <0.01 0.1 0.01 0.04 0.01
Cyanide • 0.154 lll!l/l (2) • ND NT NT <0.01 rlA <0.01 NA <0.01 NA
B-a.se/Neut ra l Di-n-Butyl Phthalate * none • ND ND NA ND NA ND NA ND NA
Acid Na1:1itha I ene * none • ND ND NA ND NA ND NA NO NA
Extractables 8is(2-ethy(hexyl)Phthalate * none • ND ND NA ND NA ND NA ND NA
(ppb) 1~3-Dichloroben,ene • 0.600 (1) • NO ND NA ND NA ND NA ND NA
N-Nitrosodiphenylarnine * none • ND ND NA ND NA ND HA NO NA
Phenol * none • ND ND NA ND NA NO NA ND rlA
2, 4-0 i me<Ayl phenol • none • ND NO rlA NO HA ND rlA NO rlA
1,4-0ichlorobenzene • 0.075 (1) • ND NO rlA ND NA ND rlA NO NA
Vol at i Le vinyl ch tori de • 0.002( 1) • NO ND NA ND NA ND rlA ND NA
Organic Acetone * none • NI ND NA ND NA NO NA ND NA
COlll>Ounds Benzene • o.oos ( 1) • ND Ill) NA NO rlA ND NA ND NA
(ppb) 1J1-Dichlor-0ethylene • 0.007 ( 1) • ND ND NA NO NA ND NA ND NA
1J2-0ichtorobenzene • 0.600 ( 1) • ND ND NA NO NA ND NA ND NA
Ethyl benzene • 0.700 (1) • ND ND NA ND NA ND NA NO NA
Methylene Chloride • 0.007 (1) • ND NO NA ND NA ND NA ND NA • Toluene • 2.000 (1) • ND ND NA ND NA ND NA NO NA
1,2,4-Trichlorobenzene • 0.700 (1) • ND HO NA ND NA ND NA HD NA
1,1,1 -Trichloroethane • 0.200(1) • ND NO NA ND NA NO NA ND NA
rn-Xylene • 10.0 (1) • ND ND rlA ND NA ND NA ND rlA
Xylenes • 10.0 (1) • Ill) ND NA ND NA ND rlA Ill) NA
1,2-Dichloroetherle (total) • none • NO ND NA ND NA lfD NA NO NA
Chlorofom • 0.100 (1) • ND NO NA ND rlA NO NA ND NA
1,1 Dichloroethane it none • ND ND NA NO rlA ND NA ND NA
Miscellaneous Chloride • 250 mgfl (2) • NA NA NA 62 NA 62 NA 57 NA
(ppm) HPH Total Cotifor111S • 1 per 100 ml. (1) • NA NA NA >=1600 NA <2 NA 170 NA
Color • 15 (2) • NA NA NA 50 NA >70 NA 20 NA
Sot ids • 500 11l9/l (2) • NA NA NA 690 NA 690 NA 790 NA
Ftuo-ride • 2.0 11l9/l (2) • rlA NA NA 0.2 NA <0.2 NA <0.2 NA
Surfactants CMBAS) • None • rlA HA NA <0.01 NA <0.01 NA <0.01 NA
Ni tr-ate • 10 11l9/l (2) * NA rlA rlA 0.12 NA <0.02 NA 0.05 rlA
Nitrite • 1.0 lll!lfl (2) • NA NA rlA <0.02 NA <0.02 rlA o.oi. NA
pH • 6.5 -B.5 (2) • NA NA NA 6.8 rlA 6.3 NA 6.7 NA
Sulfate • 250 mgfl (2) • NA NA NA 32 NA 15 rlA 46 NA
Tabte 1
CENTRAL TRANSPORT, INC. -CHARLOTTE TERHINAL
GROJNO WATER QUALITY ANALYSES
1111-2
CATEGORY PARAAETER *Drinking Water • 11/89 M/90 M/90 12/90 12/90 3/21/91 3/21/91 6/91 6/91 * S ta.ndards • (fil t) <unfi ltJ (fil t) (<Rlfi It) (filt) (unfilt) (lilt) (Lnfilt) (fil t)
-~----------------------------------* ---------------• --------------------------···-·· -----------------· ------
Metals Ali..minuri * None • 0.2 76.2 0.13 3.8 <0.1 50 0.11 20 0.2
(ppll) Arsenic • 0.05 mg/l (1) • ND NO NO <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
BariLm * 1.0 lfll/L (1 l • 0. 1 0.62 0.19 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05
BerylliUTI * None • ND ND ND 0.05 0.03 0.12 0.04 0.07 0.03
CerlrliUTJ • 0.005 mg/l (1) • ND NO NO <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Calcitll'I * None • 26.4 37.8 22.2 28 24 35 20 17 12
Ch rc:mi lll1 • 0.05 mg/ L (1) • NO 0.90 ND 0.02 <0.01 0.43 <0.01 0.2 0.03
Cobalt * None • 0.05 0.18 0.04 0.04 <0.01 0.16 <0.01 0.13 0.04
Copper • 1.0 mg/I (2) • 0.02 o. 71 0.02 0.05 <0.01 0.47 0.01 0.22 0.01
Iron * 0.03 mg/ I (2) • O.M 115 0.83 3.4 0.3 50 0.01 19 0.25
Lead * 0.05 mg/ I (1) • 0.03 0.07 ND <0.02 <0.02 <0.02 <0.02 0.02 <0.02
MagnesiLITI * N'one • 22.3 85.1 16.3 22 17 71 15 31 9.9 • Manganese • 0. 05 lfll/l (2) • 0.86 3.01 0.95 1 . 1 0.78 2.7 0.52 2 0.63
.Mercur-y • 0.0005 lfll/l (1) • ND NO NO <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005
Nickel • 0.15 mg/l (2) • ND 0.27 0.02 0.03 <0.02 0.19 0.03 0.07 <0.02
Potassim *:Nooe • 2.8 7.29 2.06 1.7 <0.5 4 <0.5 <0.5 0.66
Silver • 0.05 lfll/l (1) • ND ND 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
SodiUTI * None • 54 57.8 52.8 60 59 52 62 51 54
VanadiUTI * None • 0.00 ND ND 0.01 <0.01 0.12 <0.01 0.04 0.02
Zinc * 5.0 lfll/ L (2) • 0.04 0.29 0.04 0.07 0.01 0.22 0.04 o. 1 0.02
Cyanide • 0.154 lfll/l (2) • NO NT NT <0.01 NA <0.01 NA <0.01 NA
Base/Neut rat Di-o-Butyl Phthalate Cppb) * none • ND ND NA ND NA ND NA NO NA
Acid Naphthalene (ppb) * none • ND ND HA ND NA ND NA ND NA
Extractables Bis (2-ethylhexyl) Phthalete* none • ND ND HA NO NA NO HA ND NA
(ppb) 113-Dichlorobenieoe • 0.600 ( 1) • NO NO HA ND NA NO NA NO NA
~-Nitrosodi(:fienylamine * none • NO NO NA ND NA ND NA ND NA
Pheno L ( ppb) • none • NO NO NA ND NA ND NA ND NA
2,4-Dimethylphenol (ppb) • none • NO ND NA ND NA ND NA ND NA
1,4-Dichlorobentene • 0.075 (1) • ND ND NA ND NA ND NA NO NA
Volatile Vinyt Chloride • 0.002(1) • NO ND NA NO NA ND NA NO NA
Organic Acetone • none • NT ND NA ND NA ND NA HD NA
C~unds Benzene (ppb) * 0.005 (1) • ND ND NA NO NA NO NA HD NA
(ppb) 1,1-Dichloroethylene (ppb) • 0.007 (1) • NO NO NA ND NA NO NA NO NA
1,2-Dichtorobenzene Cppb> • 0.600 (1) • NO NO NA ND NA ND NA NO NA
Ethylbenzene (ppb) • 0.700 (1) • ND NO NA ND NA NO NA ND NA
Methylene Chloride • 0.007 (1) • ND NO NA ND NA NO NA ND NA • Toluene (ppb) • 2.000 ( 1) • ND ND MA NO NA NO NA NO NA
1,2,4~Trichlorobenzene Cppb)* 0.700 (1) • ND ND NA NO NA ND NA NO NA
11 1,1-Trichloroethane * 0~200(1) • ND ND NA NO NA ND NA ND NA
m-Xylene (ppb) • 10.0 (1) • ND NO NA ND NA ND NA ND NA
Xylenes (ppbJ • 10.0 (1) • ND NO NA ND NA ND NA ND NA
11 2-Dichloroethene (total) (• none • ND NO NA ND NA NO NA ND NA
Ch lorofonn (ppb) * 0.100 (1) • ND NO NA ND NA NO NA ND NA
11 1 Dichloroethane * none • NO NO NA NO NA ND NA ND NA
Miscellaneous Chloride • 250 mg/l (2) • NA NA NA 88 NA 88 NA 89 NA
(ppll) MPH Total Coliforrns • 1 per 100 ml (1) • NA NA NA >=1600 NA <2 NA 2 NA
Color • 15 (2) • NA NA NA 30 NA 50 NA 20 NA
Sol ids * 500 lfll/ L (2) • NA NA NA 290 NA 290 NA 270 NA
fluoride * 2.0 mg/ I (2) • NA NA NA <0.2 NA <0.2 NA <0.2 NA
Surfactants {MBAS) • NOf\E • NA NA NA <0.01 NA <0.01 NA <0.01 NA
Nitrate • 10 mg/l (2) • NA NA NA 0.03 NA 0.02 NA 0.07 NA
Nitrite • 1.0 mg/( (2) • NA NA NA <0.02 NA <0.02 NA <0.02 NA
pH • 6.5 -8.5 (2) • NA NA NA 6.3 NA 6 NA 5.7 NA
sulfate • 250 lfll/l (2) • NA NA NA 35 NA 21 NA 51 NA
_...,;
Table 1
CENTRAL TRANSPORT, INC. -CHARLOTTE TERMINAL
GROUND WATER QUALITY ANALYSES
MW-6
CATEGORY PARAMETER * Ori nki ng Water • 10/89 11/89 06/9() 6/90 12/90 12/90 3/07/91 3/07/91 3/21/91 3/21/91 6/91 6/91 * Stardards * (unfflt) (fil t.) (unfil t) (fi!t.) (unfilt)(filt.) (...,filt)(filt.) (unfilt) (fil t) (tnfil t) (fil t) ------------------------------------* ---------------* ---------------------------------------------- -------
------------------------
Metals All.El:i!lUTI * N'one * 200 0.2 38.6 0.06 7.5 <0.01 3.9 <0.1 2.7 <0.1 28 <0.1
(1'{:<11) Arsenic • D.05 mg/I C1J * 0.01 NO 0.04 MO <0.01 <0.01 <0.01 <D.Dt <0.D1 <D.01 <0.01 <0.01
Baril.Ill • 1.0 mg/! ( 1) * 2.09 D.D7 0.40 0.10 <0.01 <0.01 o. 1 <D.1 <0.1 <0.1 <0.05 <0.1
Beryl l ilRI * Nooe • MD NO NO NO 0.07 0.05 0.05 <D.1 0.(16 D.05 0.1 0.D5
C.actnii..m • D.005 mg/l ( 1) • NO MO MO NO 0.02 <0.01 <0.01 D. D1 D. D1 D.D1 <0.01 0.Dl
Calciun *Mone • 35.6 21 . 1 27.2 8.55 28 23 29 24 28 24 35 24
Cliromiun * 0.05 mg/l ( 1) • 0.41 ND 0.08 NO 0.01 <0.01 0.05 0.(16 D. D1 <D.D1 0.07 <D.D1
Cobalt *None • 0.32 ND 0.06 NO 0.06 <0.01 0.04 <0.01 D.04 <O.D1 0.04 <D.D1
Copper • 1.0 mg/l (2) • 2.04 0.02 0.3D NO 0.16 <D.D1 0.17 0.03 D.13 O.D1 0.25 D. D1
Iron • 0.03 mg/l (2) • 49.9 0 .13 39.4 NO 6.6 <D.D1 2.9 0.07 1.6 0.02 27 D.D2
l .. d • 0.05 mg/l (1) • 0.26 ND D.08 ND 0.03 <D.D2 <D.D2 <0.02 <0.02 <0.02 <0.02 <D.02 • Magnes i LITI * None • 82 15.6 19.8 5.39 2D 15 2D 15 18 15 26 15
Manganese • a.as mg/l <2l • 6.5 0.03 1. D7 NO 1.3 <0.01 D.84 0.03 0.69 0.02 1 0.02
N}ckel • 0.15 mg/[ (2) • 0.2 NO D.06 NO 0.04 0.03 <D.02 <0.02 0.02 <0.02 D.D2 <0.02
Mercury • 0.DDD5 mg/l (1) • ND NO ND ND <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <O.DDD5 <0.0005
Potassiun * None • 32.5 2.4 4.3 1.26 1.7 <0.05 1.3 1.3 4 o. 71 t.6 0.71
Silver • D.D5 mg/I (1) • ND D.D2 0.09 0.03 <0.D1 <D.01 <0.01 0.D1 0.01 <0.01 0.01 <0.01
SodiLIJI * N'one • 19.7 17.4 20.1 8.37 16 15 18 19 18 19 19 19
Vanadi1.111 * None • 1.43 D.D7 NO ND 0.04 0.02 <0.01 <D.D1 0.03 <0.01 0.11 <0.01
Z~f'IC • 5 .o mg/l (2) • 0.31 ND 0.14 0.01 0.06 <0.01 0.02 D. D1 D.04 <0.01 0.04 <0.D1
cyanide • 0.154 mg/l (2) • NO ND NT NT <0.01 NA <0.01 NA <D.01 NA <0.01 NA
ease/.N eut ra l Oi-n-Butyl Phthalate (ppb) * none • ND ND NO NA NO NA ND NA NO NA ND NA
Acid Naphtha l er.e ( ppb) * none • ND NO NO NA NO NA NO NA NO NA MO NA
Ext ractab l es Bis (2-ethylhexyl) Phthalate* none • NO MD NO NA NO NA NO NA ND NA MO NA
(pj:l:l) 1,3-Dichlorobenzene • 0.600 ( 1) • ND ND ND NA NO NA NO NA ND NA NO NA
N-Nitrosodiphenylarnine • oone • NO ND ND NA Ill) NA ND NA NO NA NO NA
Phenol ( ppb) * none • ND NO ND NA ND NA ND NA ND NA NO NA
2,4-Dimethylphenol (pj:l:l) * none • ND NO NO NA ND NA ND NA MO NA ND NA
1,4-Dichlorobenzene • 0.D75 <1) • ND NO NO NA NO NA ND NA ND NA Ill) MA
Vol a ti te Vinyl Chloride • 0.DD2(1) • ND NO ND NA NO NA ND NA ND NA ND NA
Organic Acetone * none • NT NT ND NA ND NA ND NA NO NA ND NA
COIJ"!'Ol"lds Bentene (ppb) • D.DD5 (1) • ND NO MD NA ND MA ND HA NO NA ND NA
(ppb) 1,1-Dichloroethylene (pj:l:l) • D.DD7 (1) • ND ND MD NA NO MA ND NA NO NA MD MA
1,2·DichloNlbenzene (ppb) • D.600 ( 1) • ND ND NO NA NO NA ND NA ND NA ND NA
Ethylbenzene (pj:l:l) • D.700 (1) • NO MD NO NA ND MA MD NA NO NA ND NA Methylene Chloride • D.007 (1) • NO MO NO NA NO NA ND NA NO NA MD NA • Toluene (pj:l:l) • 2.000 ( 1> • NO NO NO HA NO NA ND MA ND NA MD NA
1,2,4-Trichlorobenzene (ppb)* 0.700 (1} • NO ND ND NA NO NA ND NA ND NA ND NA
1,1,1-Trichtoroethane * 0.200(1) • ND ND ND NA NO NA NO NA MD NA ND NA
m-Xylene (pj:l:l) • 10.0 (1) • NO NO NO NA NO NA NO NA ND NA ND NA
Xylenes (pj:l:l) • 10.0 (1) • NO ND ND MA NO NA ND NA ND NA NO NA 1,2-Dichloroethene (total) C* none • NO ND ND NA Ill) NA ND NA MD MA ND NA
Cli loroform (ppb) • 0.10D (1) • NO NO NO NA NO NA ND NA NO NA ND NA
1,1 Dichloroethane . ..,,,. • ND NO ND NA ND NA ND MA NO NA ND NA
Miscellaneous C~loride • 250 mg/[ (2) • NA NA NA NA 16 NA 16 NA 14 NA 17 NA
(Pl") ~FN Total Cotiforms * 1 per 10D ml (1) • NA NA NA MA >~1600 NA <2 NA <2 NA 28D NA
Color-• 15 (2) • NA NA NA NA 10 NA >70 NA 20 MA 2D NA
Sol ids • SOD mg/l <2) • NA NA MA NA 550 MA 240 NA 260 NA 53D NA
Fluoride * 2.D mg/ I C2J • NA NA NA NA -<0.2 NA <0.2 NA <0.2 NA <0.2 MA surfactants CHBAS) ir llorte • NA NA NA AA -<O .01 •A <0.01 •A <0.01 NA <0.01 NA
Nitrate * lD mg/I (2) • NA NA NA NA 0.77 MA 0.6 NA 0.52 NA 1 . 1 NA
Nitrite * 1.0 mg/l (2) • NA MA NA NA <0.02 NA <0.02 NA <D.D2 NA <0.02 HA
pll • 6.5 • 8.5 (2) • NA NA NA NA 6.6 NA 6.4 NA 6.1 NA 6.5 NA
Sulfate • 250 mg/l (2) • NA NA NA NA 70 NA 69 NA 39 NA 87 NA
Table 1
CENTRAL TRANSPORT, INC. -CHARLOTTE TERMINAL GROllND VATER QUALITY ANALYSES 1111-7
CATEGCRY PARAMETER '* Drinking Water • 10/89 11/89 06/90 6/90 12/9(1 12/9(1 3/07/91 3/07/91 3/21/91 3/21/91 6/91 6/91 * Standards • (unfit t) (lilt.) (until t) (lilt.) (..,filt)(fi(t.) (ll'lfi!t)(filt.) (unfilt) (lilt) (unfilt) (fi!t) ------------------------------------· ---------------• ------------------ -----------------------------------------------------------
Metals All,.lllinwi '* ~one • 340 ND 90.4 0.15 1;8 <0.01 6.9 <0.1 21 <0.1 <0.1 <0.1
(ppll) Arsenic • 0.05 mg/l (1) • 0 .1 ND 0.13 ND <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Bari Lill • 1.0 mg/l (1) • 1.14 0.28 0.87 0.30 <0.1 <0.1 <0.1 <0.1 0.12 <0.1 0.82 <0.05
Beryl l iUTI • ~one • ND ND ND ND 0.02 0.02 0.05 0.03 0.1 0.03 0.17 0.05
Cac:lni llll • o. 005 mg/l (1) • ND ND ND ND 0.02 <0.01 <0.01 <0.01 0.01 0.01 <0.01 <0.01
Calciun '* .None • 117 54 85.9 67.5 59 52 57 54 68 54 140 59
Chr001i1.111 • 0.05 mg/l {1) • 0.58 ND 0.21 ND 0.08 <0.01 0.05 0.04 0.04 <0.01 0.13 <0.01
Cobalt * .None • 0.33 0.05 0.11 0.02 0.08 <0.01 0,03 0.01 0.13 0.01 0.34 0.03
Copper • 1. 0 mg/[ (2) • 5.11 0.02 1.02 ND 0.38 <0.01 0.02 0.01 0.02 <0.01 0.75 0.02
Iron • 0. 03 mg/l (2) • 743 16.7 104 13.4 60 10.32 19 10 63 11 38 0.09
Lead • 0.05 mg/! (1) * 1.45 0.05 0.32 ND o. 17 <0.02 0.02 <0.02 0.08 <0.02 0.05 <0.02
.MagnesillTI * Alone • 185 39.7 68.7 43.0 45 36 43 41 57 42 120 37
:Manganese • o. 05 mg/[ (2) * 5.7 3 .15 4.49 3.38 5.0 4.4 5 4.7 5.7 4.4 9.5 1.7 • iMerCUf'y • 0.0005 mg/l (1) * ND ND ND ND <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005
Nickel • 0.15 mg/l (2) • 0.29 ND 0. 11 0.03 0.07 0.01 0.03 <0.02 0.04 0.02 0.27 0.02
Potassitm * None • 71 16.8 15.0 7.54 7.1 3.0 4.8 3.5 5.7 2.8 6.8 3.4
Si l\l'er • 0.05 mgjl (1) • ND ND 0.15 0.01 <0.01 <0.01 <O.Ol 0.01 <0.01 0.02 <0.01 0.02
Sodi Liii * None • 298 253 212 195 19(1 190 190 190 170 180 76 73
\l'anadiL.D • None • 1.97 0.16 NO ND 0.2 <0.01 0.03 <0.01 0.2 <0.01 0.2 <0.01
Zinc • 5.0 mg/l (2) • 1.05 0.02 0.34 0.02 0.19 <0.01 0.09 0.01 0.17 0. 01 0.25 0.01 Cyanide • 0.154 mg/l (2) • 0.01 0.01 HT NT <0.01 NA <0.01 HA <0.01 HA <0.01 NA
8.ase/~ eut r-a l Di-n-Butyl Phthalate (ppb) • none • 28@ 45 1 NA ND NA NI) HA ND HA ND HA
Acid Naphtha l er.e ( ppb) • none • 8 12 2 HA ND NA ND HA ND NA ND HA
Extract.ab Les Bis (2-ethylhexyl) Phthalate• none • ND 240 ND HA ND NA ND NA HD NA HD HA
(ppb) 113-Dichlorobenzene • 0.600 (1) • ND ND 3 NA 3 HA ND NA ND NA ND HA
~-Hitrosodiphenylamine • none • ND ND ND NA ND NA ND NA ND NA HD HA
Phenol (ppb) • none • ND 9 ND NA ND NA ND NA ND NA HD HA
2,4-Dhnethylphenol (ppb) • none • ND 2 9 NA 4 HA ND NA 5 NA ND NA
1,4-Dichlorobentene • 0.075 ( 1> • NI) ND ND NA ND HA ND NA 7 NA 20 HA
Volatile Vinyl Chloride • 0.002( 1) • ND ND HD HA ND HA NA NA 110 NA 220 HA
Organic Acetone * none • NT NT HD NA ND HA ND NA ND NA ND NA
Coopounds Benzene (ppb) • 0.005 ( 1) • 570 460 190 NA NO HA 110 NA 42 NA 170 NA
(ppb) 11 1-Dichloroethylene Cppb) • 0.007 ( 1) • 790 ND HD NA ND NA HD NA ND NA ND NA
1,2-Dichlorobentene {ppb) • 0.600 ( 1) • 3 ND ND NA ND NA ND HA ND NA ND HA
Ethylbenzene (ppb) • 0.70D (1) • 640 570 ND NA NO NA 30 NA 37 NA 37 HA
Methylene Chloride • O.OD7 ( 1) • HD ND MD NA ND NA HD NA HD NA ND HA Toluene (ppb) • 2.000 ( 1) • 360 400 ND HA ND NA HD NA HD NA NO HA • 1,2J4-Trichlorobenzene (ppb)* 0.700 (1) • 5 ND MD HA ND NA ND HA ND NA ND HA
1,1,1-Tichloroethane • 0.200( 1) • HD ND MD HA ND NA ND NA 11 NA ND HA m-Xylene (ppb) • 10.0 (1) • 510 ND MD NA ND NA ND NA ND HA HD NA Xylenes (ppb) • 10.0 (1) • ND 1570 1500 NA ND NA 59 NA 81 HA 29 NA
1,2 Dichloroethene • None • HD 60 31 HA ND NA ND NA 64 NA ND NA
Chloroform (ppb) • 0.100 (1) • ND 260 HD NA ND NA ND NA ND HA ND NA
1,1 Dichlorethane "* None • HD ND NO NA HD NA NA NA ND NA HD NA
Miscellaneous Chloride • 250 mg/l (2) • HA NA NA NA 140 NA 140 NA 110 HA 220 HA
(ppll) MP~ Total Coliforms • 1 per 100 ml (1) • NA NA NA NA >=1600 NA <2 NA <2 HA 2 HA
Color • 15 (2) • NA NA HA NA 20 HA >70 NA 30 NA 30 HA
Sol ids • 500 mg/l (2) • NA NA NA NA no NA 740 HA 760 NA 110D NA
F tuoride • 2.0 mg/l (2) • NA NA NA NA 0.3 NA 0.3 HA <0.2 NA 0.3 HA
Surfactants {MBAS) * lfone • HA NA NA HA <0.01 HA <0.01 HA <0.01 NA <0.01 HA
-N'i trat-e • 10 mg/l (2) • NA NA NA NA <0.02 HA 0.07 NA 0.03 NA 0.04 HA
.N"i trite • 1. 0 mg/[ (2) • NA NA NA HA <0.02 NA 0.05 NA <0.02 NA <0.02 NA pH * 6.5 -S.5 (2) • NA NA NA NA 6.8 NA 6.6 NA 6.4 NA 6.6 NA
Sul fate • 250 mg/l (2) • NA NA NA NA 110 NA 24 NA 35 HA 51 NA
Table 1 CENTRAL TRANSPORT, INC. · CHARLOTTE TERHINAL
GROIJND WATER QUALITY ANALYSES
MW·8
CATEGORY PARAMETER ,.. D-r inking Water • 10/89 11/89 06/90 6/9fJ 12!9fJ 12/90 3/07/91 3/07/91 3/21 /91 3/21 /91 6/91 6/91
:1t Standards * (Ulfi Lt) (Ii! t.) (mfi Lt) Cfi It.) (o.nfil t)(f il t. J (unfit t)(fil t. J (mfil t) ( fi lt.) Cool il tJ (fil t) ------------------------------------* ---------------• -------------------------------------------------------------------------- -------
Metals A LUTii IUll-•None • 320 ND 1.83 0.14 220 <0.1 22 <0.1 180 <O .1 9.8 <0.1
(-) Arsenic • 0.05 mg/l (1) • 0.04 ND NO ND <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
El.arilRI • 1.0 mg/l (1) • 2. 11 0.16 0.10 ND OS6 <0.1 1. 7 <0.1 0.12 <0.1 <0.05 <0.05
Eleryl l iUTI *None • NO ND ND ND 0.22 0.05 0.09 0.05 0.39 0.01 0.08 0.05
CachiUTI • 0.005 mg/l (1) * ND ND NO ND 0.01 <0.01 <0.01 <0.01 0.02 <0.01 <0.01 <0.01
Calc\UTI • None * 91 43 24.7 70.1* 150 69 1?0 62 16() 17 31 23
ChromiUTI • 0.05 mg/! (1) * 2.65 rID NO ND 1.8 <0.01 0.06 0.04 1.28 <0.01 0.02 0.01
Cobalt * None * 0.62 rill ND ND 0.41 <0.01 0.24 0.04 0.49 <0.01 0.03 <0.01
Copper • 1.0 mg/l (2) • 2.48 0.02 0.01 0.01 1.7 <0.01 0.61 0.01 1.73 <0.01 0.02 <0.01
Iron • 0.03 mg/l (2) • 820 0.118 4.02 NO 260 <0.01 19 0.04 170 0.18 20 0.09
Lead • 0.05 mg/l (1) • 0.06 ND ND ND <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 • .Magnesilll1 * None • 375 46.8 17.8 43.8* 26() 43 93 41 230 10 25 17
Manganese • 0.05 mg/l (2) • 12.5 2.2 0.41 2.72* 10 2.2 9.6 3.4 12 0.49 1. 1 0.35
Mercury • 0.0005 mg/l (1) • NO NO llO NO 0.003 <0.0005 <0.0005 <0.0005 0.004 <0.0005 0.0028 <0.0005
li!ickel • 0.15 mg/l {2) • 1.08 NO NO NO 0.84 0.02 0.09 <0.02 0.7 <0.02 0.02 <0.02
Potassi Lm *None • 37.4 4.5 3.42 4.33* 15 1.3 7 4.3 12 0.97 5.6 0.98
Si Lver-• 0.05 mg/l (1) • ND ND 0.08 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
SodiUTI *None • 59 48.5 16.2 47.6* 44 52 59 58 58 17 12 14
V.anadilUI • None • 1.93 0.19 ND ND 0.68 <0.01 0.17 <0.01 0.52 <0.01 0.07 <0.01
Zinc • 5. 0 l!ll!l (2) • 0.84 0.02 0.05 0.02 0.67 <0.01 0.09 <0.01 0.57 <0.01 0.06 <0.01
Cyanide • 0.154 l!lll l (2) • ND ND NT NT <0.01 NA <0.01 NA <0.01 NA <0.01 NA
Base/Neutral Di·n·Butyl Phthalate (ppb) • none • ND llO ND NA ND NA ND NA ND NA ND NA
Acid Naphthalene (ppb) • none • ND llO ND NA ND NA ND NA NO NA ND NA
E;ii;:tract ables Bis {2-ethylhexyl) Phthalate* none • ND ND ND NA ND NA NO NA ND NA ND NA
(ppb) 1,3-0ichtorobenzene • 0.600 ( 1) * ND ND ND NA ND NA NO NA ND NA ND NA
N-~itrosodiphenylamine * none • NO ND ND NA ND NA ND NA ND NA ND NA
Phenol (ppbJ * none • NO ND ND NA ND NA ND NA ND NA NO NA
2,4-Dimethylphenol (ppb) * none • ND ND ND NA ND NA ND NA ND NA ND NA
1,4-Dichlorobenzene • 0.075 (1) • ND ND NO NA NO NA ND NA ND NA ND NA
Vol.a ti le Vinyl Chloride * 0.002(1) • ND ND ND NA ND NA NO NA ND NA ND NA
Organic Acetone •none • NT NT ND NA 43 NA NO NA ND NA NO NA
Coopounds Benzene (ppb) • 0.005 (1) • ND ND ND NA ND NA NO NA NO NA ND NA
(ppb) 1,1-Dichloroethylene (ppb) • 0.007 (1) • NO ND ND NA ND NA ND NA ND NA ND NA
1,2·Dichlorobenzene (ppb) • 0.6()0 (1) • NO ND ND NA ND NA ND NA ND NA ND NA
Ethylbenzene (ppb) • 0.700 (1) * NO ND ND NA NO NA ND NA ND NA ND NA • ~ethylene Chloride • 0.007 ( 1) • NO ND 13 NA ND NA ND NA ND NA ND NA
Toluene (ppb) • 2.000 ( 1) * ND ND NO NA llO NA ND NA ND NA NO NA
1,2,4-Trichlorobenzene (ppb)* 0.700 (1) * ND llO ND NA llO NA ND NA ND NA NO NA
1,1,1-Trichtoroethane * 0.002(1} * ND NI) ND NA NO NA ND NA 16 NA ND NA
rn·Xylene (ppb) • 10.0 (1) • ND ND ND NA ND NA ND NA ND NA NI) NA
Xylenes (ppb) • 10.0 (1) * NI) ND ND NA ND NA ND NA NO NA NO NA
1,2-0ichtoroethene (total) (* none • NO ND ND NA ND NA NO NA NO NA ND NA
Chloroform (ppb) • 0.100 (1) • NO ND ND NA ND NA llO NA ND NA ND NA
1,1 Dichloroethane * None • ND NO NO NA NO NA ND NA 13 NA ND NA
Miscellaneous Chloride • 250 mg/l (2) • NA NA NA NA 93 NA 90 NA 100 NA QNS NA
(Jlllll) MPN Total Coliforms • 1 per 100 ml (1) • NA NA NA NA 13 NA <1 NA <2 NA 8 NA
Color-* 15 (2) • NA NA NA NA 20 NA 70 NA 70 NA QNS NA
Solids • 500 mg/l (2) • NA NA NA NA 530 NA 510 NA 540 NA QNS NA
F Luoride • 2 .0 "Ill I (2) • NA NA NA NA 0.3 NA 0.2 NA 0.2 NA QNS NA
Surfactants (MBAS) *None * NA NA NA NA <0.01 NA <0.01 NA <0.01 NA <0.01 NA
Wi trate • 10 ms!l <2J * rtA NA NA NA <0.02 NA <0.02 NA 0.118 NA 0.05 NA
Hitrlte • 1.0 l!ll/l (2) * NA NA NA NA <0.02 NA <0.02 NA <0.02 NA <0.02 NA
pl! • 6.5 . 8.5 (2) • NA NA NA NA 6.4 NA 5.9 NA 6.1 NA 6.7 NA
Sulfate • 250 mg/l (2) • NA NA NA NA 64 NA 48 NA 53 NA 59 NA
T.able 1
CENTRAL TRANSPORT, INC. -CHARLOTTE TERMlNAL GROUND WATER QUALITY ANALYSES
~~-9
CATEGORY PA~ETER * Drinking Water • 10/89 11/89 06/90 6/9() 12/9() 12/9() 3/21/91 3/21/91 6/91 6/91 * Standards * Cunfi l t) (fi lt.) {unf1 l t) (fi(t.) (unfilt)(filt.) (lA'lfilt)(filt.) (unfi\t) (fi!t.) -----------------·------------------* ---------~-----• ---···-------------. ·~----------------· ·-·------------------------~
Metals Al U11 i nLITI * 'fone • 39 ND 1.63 0.11 3.2 <0.1 4.9 <0.1 2.5 <0.1
(Pll!l) Arsenic • 0.05 lll!l/l ( 1) • NO ND NO NO <0.01 <0.01 <O .01 <0.01 <0.01 <0.01
Bariun • 1.0 lll!l/l (1) • 0.28 0.01 0.10 0.10 <0.1 1 <0.1 <0.1 <0.05 <0.05
Beryl Li Lm * None • ND ND ND NO 0.06 0.05 0.07 0.05 0.05 0.04
CadriiU'll • 0. 005 11l9/l ( 1) • ND NO ND NO 0.04 <0.01 0.01 0.01 <0.01 <0.0\
C.a lciUll * )ilone • 33.9 22.2 26.0 24.1 26 25 28 22 28 22
Chr001iUTI • 0.05 11l9/l (1) • 0.06 NO ND NO 0.02 <0.01 <0.01 0.01 0.02 0.01
Coba!t * None • 0.04 NO 0.01 NO 0.02 <0.01 0.02 <0.01 0.01 <0.01
Copper • 1.0 lll!l/L (2) • 0.08 NO NO ND 0.03 <0.01 <0.01 0.01 0.05 <0.01
Iron • 0.03 lll!l/l (2) • 195 0.09 3.63 0.69 6.2 <0.01 12 0.51 1.4 0.03
Lead • 0.05 lll!l/l (1) • NO NO NO ND <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
.Magnes i llrl * None • 51.1 19.6 18.0 17 .2 19 18 22 16 15 12 • iManganese • 0.05 lll!l/l (2) • 2.78 0.32 0.41 0.34 0.44 0.31 0.88 0.28 0.36 <0.01
Mercury • 0.0005 mg/! (1) • NO NO NO NO <0.0005 <0.0005 <0.0005 <0.0005 <O. 0005 <O. 0005
.Nickel • 0.15 mg/l (2) • 0.04 NO NO NO 0.05 0.02 <0.02 <0.02 <0.02 <0.02
PotassiLlll .. N'one • 11. 9 3.3 4.33 3.09 3.<I 1.8 3.5 3.7 <0.5 -<0.5
Si Lver * 0. OS lll!l/l C 1) • NO ND 0.07 0.02 <0.01 <0.01 0.01 0.01 <0.01 <0.01
Sodillll * None • 15.6 21.2 16. 7 16.9 14 16 14 13 12 13
V.anadim *,None • 0.19 0.07 ND NO 0.02 <0.01 0.04 <0.01 0.02 <0.01
Zinc • 5.0 mg/l (2) • 0.12 0.02 0.02 o.~ 0.05 0.01 0.01; 0.01 0.02 <0.01
cyanide * 0.151; mg/L (2) • NO NO NT NT <0.01 NA <0.01 NA <0.01 NA
Base/Neutral Di·n-Butyl Phthalate (ppb) * none • NO NO ND NA NO NA NO NA NO NA
Acid Naphthalene (ppb) • r.one • NO NO NO NA NO NA NO NA NO NA
Ext r .ac ta bl es Bis (2-ethylhexyl) Phthalate* ncne • NO NO NO NA NO NA NO NA NO NA
(ppb) 1,3-0ichlorobenzene-• 0.600 (1) • NO NO NO NA NO NA NO NA NO NA
N-Nitrosodiphenylarnine * none • NO NO NO NA NO NA NO NA NO NA
Phenol ( ppb) * none • ND NO NO NA NO NA NO NA NO NA
2,4-Dimethylphenol (ppb) !Ill' none • ND NO NO NA ND NA ND NA ND NA
1,4-Dichlorobenzene • 0.075 ( 1) • NO ND NO NA ND NA NO NA ND NA
Volatile Vinyl Chloride • 0.002(1) • ND ND NO NA NO NA ND NA ND NA
Organic Acetone "* none • NT NT NO NA NO NA ND NA ND NA
C~unds Benzene (ppb) * 0.005 (1) * NO ND ND NA ND NA ND NA ND NA
(ppb) 1,1-Dichloroethylene Cppb) * 0.007 (1) • NO ND ND NA ND NA ND NA ND NA
1,2-Dich L-oro.benzene (l=J:b) • 0.600 (1) • NO NO ND NA NO NA ND NA NO NA Ethylbenzene (ppb) • 0.700 (1) * NO ND ND NA ND NA ND NA NO NA
Methylene Chloride • 0.007 (1) • NO ND ND NA NO NA NO NA NO NA • Toluene (ppb) • 2.000 (1) • NO NO ND NA NO NA NO NA NO NA
1,2,4·Trichlorobenzene (ppb)* 0.700 (1) • NO HO ND NA NO NA NO NA NO NA
1,1,1·Trichloroethane * 0~200(1) • MO NO ND NA NO NA NO NA NO NA m-Xylene (ppb) • 10.0 (1) • NO NO NO NA NO NA NO NA NO NA
Xyl en es ( ppb) • 10.0 (1) • NO NO NO NA NO NA NO NA NO NA
1,2-0ichloroethene (total) {* none • NO NO NO NA NO NA NO NA NO NA
Chloroform (ppb) • 0.100 (1) • NO NO NO NA NO NA NO NA NO NA
1,1-Dichloroethane • none * ND ND NO NA NO NA NO NA NO NA
Miscellaneous Chloride * 250 mg/l (2) * NA NA NA NA 8 NA 7 NA 7 NA
(ppm) KP~ Total Cotiforms • 1 per 100 n. (1) • NA NA NA NA >=1600 NA <2 NA <2 NA
Color * 15 (2) • NA NA NA NA 20 NA 10 NA 20 NA
Sol ids • 500 mg/L (2) • NA NA NA NA 190 NA 180 NA 230 NA
Fluoride • 2.0 mg/l (2) • NA NA NA NA 0.2 NA <0.2 NA <0.2 NA
Surfactants (KB-AS) • Nooe • NA NA NA NA <0.01 NA <0.01 NA <0.01 NA
Nitrate • 10 111!!/l (2) • NA NA NA NA <0.02 NA 0.07 NA 0.06 NA
Nitrite • 1.0 111!!/l (2) • NA NA NA NA 0.03 NA <0.02 NA 0.02 NA
pll • 6.5 -8.5 (2) • NA NA NA NA 7.0 NA 6.6 NA 7.1 NA
Sulfate • 250 lll!l/l (2) • NA NA NA NA 81 NA 12 NA 26 NA
Table t
CENTRAL TRANSPORT, !NC. -CKARLOTTE TERMINAL GR!XJMO WATER QUALITY ANALYSES
• MW-10
CATEGORY PARAMETER * Drinking Water • 10/89 11/89 06/90 6/90 12!90 12/90 3/21/91 3/21/91 6/91 6/91 * Stardards • (ll'lfilt) (fil t.) (unti lt) ( fi l t.) (until t)(fil t.) (oofi l t)(fi l t.) (unf il t) Cf; l t.) ------------------------------------* ---------------• ------------------------------------------------------------ -------Metals AtUflinun • Mone • 100 MO 8.48 0.15 15 <0.1 1 .5 <0~1 34 0.14
(ppll) Arsenic • 0.05 rog/l (1) • 0.04 MO ND ND <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Bariun • 1.0 rog/l (1) • 0.48 0.02 0.16 0.11 <0.1 <0.1 <O. 1 <0.1 <0.05 <0.05
Beryl l iun • None • MO ND NO 0.09 0.04 0.05 0.04 0.13 0.03 CadriiUll • 0.005 rog/l (1) • NO NO NO NO 0.01 <0.01 0.01 <0.01 <0.01 <0.01
Calciun * None • 36.5 22.7 25.0 22.6 25 22 22 23 69 49
Chromim • 0.05 rog/l (1) • 0.17 NO 0.04 ND 0.02 <0.01 <0.01 <0.01 0.05 <0.01
Cobalt • None • 0.12 NO 0.02 NO 0.02 <0.01 <0.01 <0.01 0.04 <0.01
Copper • 1.0 rog/l (2) • 0.55 NO 0.05 NO 0.04 <0.01 0.02 <0.01 0.19 0.01 Jroo • 0.03 rog/l (2) • 200 0.03 7.24 NO 12 0.02 0.84 0.05 34 0.06
Le.ad • 0.05 rog/l (1) • 0.15 NO 0.02 NO 0.03 <0.02 <0.02 <0.02 0.04 <0.02 • Magnesfun • None • 34.7 14.9 13.5 12.3 14 12 12 12 27 14
Manganese • 0.05 rog/l (2) • 2.29 0.03 0. 19 NO o.w <0.01 0.16 <ll.01 4.6 0.59 Mercury • 0.0005 rog/! (1) • NO NO ND ND <0.0005 <0.0005 <0.0005 <0.0005 <O. 0005 <O. 0005
Wicket • 0.15 rog/l (2) • 0.05 NO 0.02 NO a.or. <0.02 <0.02 <0.02 0.03 <0.02 Potassitm * None-• 7.6 2.8 3.24 2.79 1.7 <0.5 2.2 <0.5 3.6 2.8
Sit ver • 0.05 rog/l (1) • NO NO 0.04 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Sodiun * None-• 14.5 14.6 15.5 15.2 14 15 13 15 9.9 14
VanadiL.lll * None • 0.66 0.06 NO ND 0.04 0.02 0.02 <0.01 o. 15 <0.01 Zinc • 5.0 lll!lfl (2) • 0.15 0.02 0.09 0.02 0.07 <0.01 0.01 0.01 0.07 <0.01
Cyanide • 0.154 lll!lfl (2) • NO ND NT NT <0.01 NA <0.01 NA <0.01 NA Base/ti! eut ra l Oi-n-Butyl Phthalate (ppb) * none • NO ND NO NA ND NA NO NA ND NA
Acid Naphthalene (ppb) * none • NO ND NO NA ND NA NO NA ND NA
Ext ractab l es Bis C2-ethylhexyl) Phthalate* none • NO ND NO NA ND NA NO NA ND NA
(ppb) 1,3-Dichlorobeniene • 0.600 (1) • NO ND NO NA ND NA NO NA NO NA N-Nitrosodiphenylam!ne .. none • NO ND NO NA ND NA NO NA NO NA Phenol (ppb) .. none • ND ND NO NA ND NA NO NA NO NA 2,4·0imethylphenol (ppb) * none • ND ND NO NA ND NA NO NA NO NA
1,4-0ichlorobeniene • 0.075 (1) • ND ND NO NA ND NA NO NA NO NA
Volatile Vinyl Chloride • 0.002(1) • ND ND NO NA ND NA NO NA NO NA
Organic Acetone • none • NT NT NO NA ND NA NO NA NO NA Coopounds Benzene (ppb) • 0.005 (1) • ND NO NO NA ND NA NO NA NO NA
(ppb) 1,1·0ichloroethylene (ppb) • 0.007 (1) • ND ND NO NA ND NA NO NA NO NA 1,2-0ichlorobenzene (ppb) • 0.600 (1) • ND ND NO NA ND NA NO NA NO NA Ethylbenzene (ppb) • 0.700 (1) • ND ND NO NA ND NA NO NA NO NA
Methylene Chloride • 0.007 (1) • ND ND NO NA ND NA NO NA NO NA • Toluene (ppb) • 2.000 (1) • ND ND NO NA ND NA NO NA NO NA 1,2,4-Trichlorobenzene (ppb)• 0.700 (1) • ND NO NO NA ND NA NO NA NO NA
1,1,1-Trichloroethane • 0.200(1) • ND NO NO NA ND NA NO NA NO NA rn-Xylene (ppb) *10.0(1) • ND NO HO NA ND NA NO NA HO HA Xylenes (ppb) • 10.0 (\) • ND ND NO NA ND NA NO NA NO NA 1,2·0ichloroethene (total) (!Ir none • ND NO NO HA ND NA NO NA NO MA Chlorofonn (ppb) • 0.100 (1) • ND NO NO NA ND NA NO NA HO MA
1,1-0ichloroethane "'" N'one • ND ND NO NA ND NA "° NA NO NA
Miscellaneous Chloride • 250 rog/ l (2) • NA NA NA NA 11 NA 12 NA 13 NA
(P!'fTI) NPN Total Collforms • t per 100 ml (1) • NA NA MA NA >=16()0 NA <2 HA <2 MA
Color • 15 (2) • NA NA NA NA 10 MA 30 NA 20 NA
Sol ids • 500 lllilfl (2) • NA NA NA MA 270 NA 180 MA 710 NA
Fluoride • 2.0 IJlil/l (2) • NA NA NA NA <0.2 NA <0.2 NA <0.2 NA Surfactants CMBAS} * N-one • NA NA NA NA <0.01 NA <0.01 NA <0.01 NA
Nitrate • 10 rog/l (2) • NA NA NA MA 0.81 NA 1.18 MA 1.15 NA
N'itrite • 1. 0 rog/l (2) • NA NA NA NA <0.02 NA <0.02 NA <0.02 NA
pH • 6.5 -8.5 (2) • NA NA NA NA 7.0 NA 6.5 NA 7 NA
Sul fate * 250 mg/ I (2) • NA NA NA NA 35 NA 12 NA 13 NA
Tabte 1
CENTRAL TRANSPORT, INC. · CHARLOTTE TERMINAL
GROlND WATER QUALITY ANALYSES
MW·11
CATEGORY PARAMETER * Drinking ~ater • 10/89 11/89 06/'IG 6/90 12/90 12/90 3/21/91 3/21/91 6/91 6/91 * St andaf'ds * Cunfi Lt) (fil t.) <oofi l tJ Cfil t .) (unfi l t)(f il t.) (mfi l t)(fit t.) (..,IH t) (fil t. J ------------------------------------* ---------------• --------------------------------------------~----------~-------·~·~
Hetals Al uni nun ,., NOl"le • 4. t ND 10.4 0.14 89 <0.01 12 <0.1 130 <0.1
(~) Arsenic • 0.05 mg/l (1) • ND ND ND ND <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Barlun • 1.0 mg/l (1) • 0.19 0.15 0.37 0 .15 0.65 <0.1 0.2 <0.1 <0.05 <0.05
Beryl l i un * ~one • ND ND ND ND 0.24 0.02 0.07 0.03 0.29 0.03
CaciniLITI-• 0 .005 mg/ l (1) • NO NO ND ND 0.01 <0.01 0.01 0.01 0.01 <0.01
CalCiLITI * None * 70 78 157 89.1 72 35 74 44 140 72
Chir001iw-* 0.05 mg/I (1) • ND ND 0.16 0.08 0.2 <0.01 0.04 <0.01 0.78 <0.01
Cobalt * None • NO ND 0.02 ND 0.17 <0.01 0.05 <0.01 0.22 <0.01
copper • 1.0 mg/l (2) • 0.02 0.02 0.06 ND 0.53 <0.01 0. 11 0.01 0.47 0.01
Iron • 0.03 mg/l (2) • 2.23 ND 8.52 ND 98 <0.01 16 0.12 160 0.11
Lead • 0.05 rng/l ( 1) • ND 0.03 0.04 ND 0. 1 <0.02 <0.02 <0.02 0.03 <0.02 • M.agnesiUTI * .None • 44.1 38. l 9.81 0.78 58 11 25 13 140 25
Manganese • 0.05 ng/l (2) • 1.79 1.84 0.88 ND 16 0.4 7.3 0.33 6.2 0.86
Mercury • 0.0005 ng/l (1) • ND NO ND ND <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005
Wicket * 0.15 ng/l (2) * ND ND 0.03 NO 0.19 <0.02 0.03 <0.02 0.48 <0.02
Potassiun * None • 10.2 7.5 1>1. 7 56.2 14 3.1 8.4 5.6 8.7 4.5
Silver * 0 .OS mg/l C1J • ND ND 0.04 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Sodi1.J11 * None * 24.4 22.7 33.6 31.4 5.2 12 12 14 4.6 16
Vanadiun * None • 0.46 0.16 NO ND 0.38 0.01 0.1 <0.01 0.51 <D.01
Zinc • 5.0 mg/l (2) • NO 0.02 0.07 ND 0.28 <0.01 0.05 0.01 9.5 0.07
Cyanide • 0.154 mg/l (2) • ND ND NT NT <0.01 NA <0.01 NA <0.01 NA
Elase/Neutr.al Di-n·Butyl Phthalate (ppb) * .none • ND ND ND NA ND NA ND NA ND NA
Acid Na):fithalene (pj)b) * rione • ND ND NO NA ND NA ND NA ND !IA
Ext ractabl es Bis (2-ethylhexyl) Phthalate* none • ND ND NO NA ND NA ND NA ND NA
(ppb) 1,3-Dichlorobentene • 0.600 (1) • ND ND NO NA ND NA ND NA ND NA
W-Witrosodipllenyl.amine • none • ND ND ND NA ND NA ND NA ND NA
Phenol ( ppb) • none * ND ND NO NA ND NA ND NA NO NA
2,4·Dimethyl):fienol (ppbJ • none • ND ND ND NA ND NA ND NA MD NA
1,4-0ichlorobentene • 0.075 (1) • NO ND ND NA ND NA NO NA ND MA
Volatile Vinyl Chloride • 0.002( 1) • ND ND ND NA ND NA ND NA ND NA
Organic Acetone • none • NT NT 11 NA NO NA ND NA ND MA
c~unds Benzene (ppb) • 0.005 ( 1) • NO ND NO MA ND NA ND NA NO MA
(ppb) 1,1-Dichloroethylene (ppb) • 0.007 ( 1) • ND ND ND NA MD NA NO NA NO NA
1,2-Dichlorobenzene (ppbl • 0.600 ( 1) • ND ND ND NA ND NA NO NA NO NA
Ethylbenzene Cppb) • 0.700 (1) • ND ND ND NA ND NA ND NA ND NA
Methylene Chloride • 0.007 (1) • ND NO NO NA ND NA NO NA ND NA • Toluene (ppbJ • 2.000 (1) • NO NO NO NA ND NA NO NA ND NA
1,2,4-Trichtorobenzene (ppb)* 0.700 (1) • ND ND NO NA ND NA NO NA ND NA
1,i,1 Trichloroethane • 0.200 • ND ND NO NA ND NA ND NA ND NA
m·Xylene (ppb) • 10.0 (1) * ND ND NO NA ND NA ND NA ND NA
Xylenes (ppb) • 10.0 (1) • NO ND ND NA ND NA ND NA ND NA
1,2-0ichloroethene (total) (* none • NO NO ND NA ND NA ND NA ND NA
Chloroform (ppb) • 0.100 (1) • NO NO ND NA ND NA NO MA ND MA
1,1 Di~hloroethane • J • ND ND ND NA ND NA ND NA ND NA
Mlsceltaneous Chloride • 250 rng/l (2) • NA NA NA NA 11 NA 13 NA 13 NA
(~) MP~ Total Coliforms • l per 100 ~ (1) • NA NA NA NA >=1600 NA 17 NA 900 NA
Cot-or • 15 (2) • NA NA NA NA 20 NA 60 NA 40 NA
Sol ids • 500 ng/l (2) • NA NA NA NA 220 NA 290 NA 330 NA
Fluoride • 2. 0 ng/l (2) • NA NA NA NA <0.2 NA -<0~2 NA <0.2 /IA
SU~factants (MBAS) *Nooe • NA NA NA NA <0.01 NA <0.01 NA <0.01 llA
Nitrate • 10 ng/l (2) * NA NA NA NA 0.11 NA 0.04 NA 0.07 NA
t.li trite • 1.0 mg/l (2) • NA NA NA NA 0.03 NA <0.02 NA 0.02 NA
pH • 6.5 . 8.5 (2) • NA NA NA NA 7.4 NA 6.8 NA 7.3 NA
Sulfate * 250 mg/ I (2) • NA NA NA NA 86 NA 15 NA 49 NA
Table 1
CENTRAL TRANSPORT, INC. · CHARLOTTE TERMINAL
GROUND WATER QUALITY ANALYSES
CATEGORY
Meta ls
(ppm)
•
Base/iN-eutral
Acid
Extractables
(ppb)
Volatile
Or-ganic
C'"'IJOUl"ls
(ppb)
•
PARAMETER * nrinking Water * 5/91 * Standards *<unfilt.) -----------------------------* ---------------*
AlLITlini..m * N"one * Arsenic * 0.-QS mg/l (1) *
Barii..m * 1.0 mg/l (1) *
Beryllil.111 *None *
CadmiLlll * 0.005 mg/l (1) *
C:alcii..m * None * Chromillll • 0.05 mg/l (1) •
C:obal t * None *
Copper • 1.0 mg/ I (2) *
Iron * 0.03 mg/l (2) *
28 <0.01 <0.05
0 .1
<0.01
140
0.22 0.07
0.13
28
Lead * 0.05 mg/l (1) *????
MagnesiUll * ~-one *
Manganese * 0.05 mg/L (2) *
Mercury * 0.0005 mg/l (1) *
Nickel * 0.15 mg/I (2) •
PotassiL.m *None *
Silver * 0.05 mg/l (1) •
SOOil.lll *None *
Van ad i Lill * None *
line * 5.0 rng/l (2) *
Cyanide • 0.154 IJlll/\ (2) •
Di-n-Butyl Phthalate {ppb) * none *
Naphthalene (ppb) • r.one •
Sis <2-ethythexyl) Phthalate* none *
1,3-Dichlorobenzene * 0.600 C1/ *
~-Nitrosodipllenytamine * none *
Phenol Cppb> * none *
2,4-Dimethylphenol (ppb) * none *
1,4-Dichlorobenzene * 0.075 {1) *
Vinyl Chloride • 0.002 •
Acetone * none *
Sen<ene (ppb) • 0.005 (\) •
1,1-Dichloroethylene (ppb) • 0.007 (1) •
1,2-Dichloroben<ene (ppb) • 0.600 (1) * Ethylben<ene (ppb) • 0.700 (\) • Methylene Chloride • 0.007 (1) •
Toluene (ppb) • 2.000 (1) •
1,2,4-Trichlorobenzene CJ:Pb)* 0.700 {1) *
1,1,1-Trichloroethane * 0.200 * m-Xylene (ppb) • 10.0 (1) *
Xylenes (ppb) * 10.0 (1) *
1,2-Dichloroethene (total) C* none *
Chlorolonn (ppb) • 0.100 (1) •
1,1 Dichloroethane *None *
60
3 <0.0005
0.12
5 <0.01
22
0.13
4
Miscellaneous Chloride * 250 1119/L (2) *
<0.01 ND
ND ND
HD
ND
ND
HD
HD
HD
ND
ND
NO ND
ND
ND
ND
ND
HD HD
HD
ND HD
ND
65
170
70
490
(ppm) MPN lotal Colilonns • 1per100 ml (1) •
Color • 15 (2) •
Solids * 500 mg/ I (2) * Fluoride • 2.0 mg/I (2) •
SUrfactants (MBAS) • Hone * :Nitrate ii' 10 mg/l (2) *
~itrite ii' 1.0 mall (2) *
pH * 6.5 • 8.5 (2) *
Sul fate • 250 IJlll/l (2) •
<0.2
<0.01 0.02 <0.02
7.7
67
MW·13
5/91 6/91
(lilt.) (unfllt.)
<0.1
<10 <0.05
0.03
<0.01
93 0.05
0.01
0.04
0.05
0.02
33
0.92 <0.0005
<0.02
4.3
0.02
19 <0.01
<0.01
NA
NA
NA
NA
HA HA HA
HA
NA
NA
NA
NA NA
NA
NA
NA
HA
NA
HA
HA
HA
HA HA
HA
HA
NA
NA
NA
NA
HA
NA
HA
NA HA
8.4 <0.01
<0.05
0.06 <0.01
59
0.01
<0.01
0.05
12
0.09
13
0.35
<0.0005 <0.02
4.4 <0.01
13
<0.01
0.68 <0.01 ND ND
ND
llD
HD ND
NO
ND
ND
ND
ND ND ND ND
ND
ND
ND ND ND
NO
NO ND ND
31
33
20
460
-<Cl.2
<0.01
0.06
0.04
7.5
44
6/91
(fil t.)
<0.1 <0.01 <0.05
0.03
<0.01
54 <0.01
<0.01
0.02
0.1
0.02
11
0.15 <0.0005
<0.02
1.3
<0.01
13 <0.01
0.04
HA
HA
NA
NA
HA HA
HA
NA
NA
NA NA
NA NA NA
NA
NA
NA NA
NA
HA
HA
HA
HA
HA
NA
NA
NA
HA
NA
HA
HA NA
NA
HA
Table 1
CENTRAL TRANSPORT, INC. -C~ARLOTTE TERMINAL
GRCIJtlO WATER QUALITY ~AlYSES
MIM4
CATEGORY PARAMETER * Orinklng Water • 3/07191 3/07/91 3/21/91 3/21/91
• Standards *(un1i lt.) (tilt.) (unf il t.) (fil t. J ------------------------------------* ---------------• ------- ---------------------
Metals A lUTii lllll1 * None • 2.6 <O.t 4.6 <0.1
(-) Arsenic • 0.05 mg/l ( 1) • <0.01 <0.01 <0.01 <0.01
Elariun • 1.0 mg/l (1) • <0.1 <0.1 <O~ 1 <0.1
eerylliUTI * ~one-• 0.04 0.05 0.07 0.05
CadliiUll • 0.005 mg/l (1) • 0.01 <0.01 <0.01 <0.01
CalcillTI * N!one • 16 13 16 12
ChromiLITI • 0.05 mg/l ( 1) • 0.05 0.04 <0.01 0.02
C<lbal t * N'one • 0.03 <0.01 0.03 <0.01
Copper • 1.0 mg/[ (2) • 0.04 0.02 0.05 0.02
Iron • 0.03 mg/l (2) • 2 .1 0.05 4.2 0.56
Lead • 0.05 rng/l ( 1) • <0.02 <0.02 <0.02 <0.02 • M-agnesiL.111 * None • 7.8 5 8.4 4.8 M..aoganese • 0. 05 mg/[ (2) • 0.36 0.02 0.51 0.02
Mercury • 0.0005 mg/l (1) • <0.0005 <0.0005 <0.0005 0.0006
tilickel • o. 15 mg/l (2) • <0.02 <0.02 <0.02 0.02
PotassiLD * :None • 1.5 0.97 2.8 3.4
Silver • 0.05 mg/ l (1) • <0.01 0.01 <0.01 0.01
Sodiun * None • 11 12 11 11 V.anadillll * tilooe • <0.01 <0.01 0.02 <0.01
Zinc • 5 .0 mg/I (2) • 0.02 <0.01 O.Oli 0.01
Cyanide • 0.154 mg/ l (2) • <0.01 NA <0.01 NA
8-ase/N'eutf'al Oi·n-Butyl Phthalate (ppb) • none • tlO NA ND NA
Acid Naphthalene CppbJ • none • tlO NA ND NA
Extractables Bis (2-ethylhexyl) Phthalate* none • ND NA ND NA
(ppb) 1,3-Dichlorobenzene • 0.600 (1) • ND NA NO NA N-Nitrosodiphenyl.amine • none • ND NA NO NA Phenol (ppb) • none • ND NA NO NA 2,4-Dimethylphenol (ppb) * none • ND NA NO NA
1,4-Dichlorobenzene • 0.075 ( 1) • ND NA NO NA
Volatile Vinyl Chloride • 0.002 • ND NA NO NA
Organic Acetone * none • ND NA ND NA
C~unds Benzene (ppb) • 0.005 ( 1) • ND NA ND NA
(ppb) 1,1-Dichloroethy\ene (ppb) • 0.007 ( 1) • ND NA ND NA 1,2-Dichlorobenzene (ppb) • 0.600 ( 1) • ND NA ND NA Ethylbenzene (ppb) • 0.700 (1) • ND NA ND NA
~ethylene Chloride • 0.007 (1) • NO NA ND NA • Toluene (ppb) • 2.000 (1) • NO NA ND NA
1,2,li·Trichlorobenzene (ppb)* 0.700 (1) • NO NA ND NA
1,1,1-Tiichloroethane • 0.200 * NO NA NO NA m·Xylene (ppb) • 10.0 (l) • NO NA ND NA Xylenes (ppb) • 10.0 (l) • NO NA ND NA
1,2-Dicbloroethene (total) * none • NO NA NO NA Chloroform (ppb) • 0.100 (1) • NO NA ND NA
1,1 Oichloroethane *None • ND NA ND NA
Miscellaneous Chloride • 250 mg/l (2) • 9 NA 8 NA
(PF") MPN Total ColifQrlllS * t per 100 nj_ (1) • <2 WA <2 NA
Color • 15 (2) • 70 NA >70 NA Sol ids • 500 mg/ l (2) • 120 NA 140 NA
Fluoride • 2.0 mg/[ (2) • <0.2 NA <0.2 NA
Surfactants {HBAS) * ~one • <0.01 NA <0.01 NA
Nii trate • 10 mg/I (2) • 0.53 NA 0.49 NA
N'itrite • 1.0 mg/[ (2) • <0.02 NA <0.02 NA
pfl • 6.5 -8.5 (2) • 6.4 NA 6 NA
Sul fate • 250 mg/ l (2) • 50 NA 19 NA
Table 1
CENTRAL TRANSPORT, INC. -CHARLOTTE TERMINAL
GRCIJND HATER QUALITY ANALYSES
Kll-16
CATEGORY PARAMETER *Drinking Water • 5/91 5/91 6/91 6/91 * Standards *(mfilt.) (lilt.) (oofilt.J Cfi It.) ------------------------------------* ---------------• ----------------------------
Metals AtUTiinun * :None • 3.9 <0.1 8.2 -<O. 1
(Pl") Arsenic • 0.05 mg/l (1) • <0.01 <0.01 <0.01 <0.01
BariUTI • 1.0 mg/[ (1) • <0.05 <0.05 <0.05 <0.05
Beryltiun * t.lone • 0.04 0.03 0.05 0.03
CachiUTI • 0 .005 mg/l (1) • 0.01 <0.01 <0.01 <0.01
catciUTI * None • 57 56 58 55
chromiUTI • 0.05 mg/[ (1) • 0.09 0.05 0.02 <0.01
Cobalt * None • <0.01 0.01 <0.01 <0.01
Copper • 1.0 mg/ l (2) • 0.07 0.01 0.06 0.01
Iron • 0.03 mg/l (2) • 16 0.02 12 0.09
Lead • 0.05 mg/l (1) • 0.03 <0.02 <0.02 <0.02 • MagnesiUTI * None • 11 11 13 11
li!anganese • 0.05 mg/l (2) • 0.47 0.16 0.34 0.015
Mercury • 0.0005 mg/l (1) • <0.0005 <0.0005 <0.0005 <0.0005
N'ickel • 0.15 mg/I (2) • 0.02 <0.02 0.02 <0.02
Potassillll * None-• 6.5 3.4 6.4 2.8
Si tver • 0.05 mg/\ (1) • <0.01 0.02 <0.01 <0.01
Sodiun * Mione • 16 14 12 13
Va.nadil.lll * N'one • <0.01 <0.01 0.02 <O.Ot
Zinc • 5 .0 mg/l (2) • 0.72 <0.01 0.67 0.04
Cyanide • 0.154 mg/l (2) • <0.01 NA <0.01 NA
Base/Neutra L Di-n-Sutyl Phthalate (ppb) *none • HD NA ND NA
Acid Naplitholene (ppb) • none • ND NA ND NA
Extract.ables Bis (2-ethylhexyl) Phtholote* none • ND NA ND NA
(ppb) 1,3-Dicliloroben•ene • 0.600 (1) • NO NA ND NA
N-NitrosodiP,enylamine • none • HO NA ND NA
Phenol (ppb) • none • HO NA NO HA
2,4-0imethylplienot (ppb) • none • HO HA HO NA
,,4-Dichlorobenzene • 0.075 (1) • NO NA HO NA
'u'olati le Vinyl Ch loricle • 0.002 • ND NA NO NA
Organic Acetone • none • NO NA NO NA
C~unds Benzene (ppb) • 0 .005 (1) • NO NA NO NA (ppb) 1,1-0ichloroethylene (ppbl • 0.007 (1) • NO HA HO NA
1,2-0ich!orobenzenE (ppbl • 0.600 (1) • NO NA NO NA
Ethylben•ene (ppb) • 0.700 (1) • NO NA NO NA
Methylene Chloride • 0.007 ( 1) • NO NA NO NA • faluene (ppb) • 2.000 ( 1) • NO NA NO NA
1,2,4-Trichlorobenzene (ppb}* 0.700 (,) • ND NA NO NA
1,1,1-Trichloroethane * 0.200 • ND NA NO NA
m-)(ylene (ppb) • 10.0 (1) • ND NA NO NA
Xyl en es ( ppb) • 10.0 (1) • NO NA NO NA
1,2-Dichloroethene (total) * none • NO NA Ill) NA chloroform ( ppb) • 0.100 (1) • NO NA Ill) NA
1,1 Oichloroethone *N:one • NO NA Ill) NA
Miscellaneous Chloride • 250 mg/l (2) • 9 NA 9 NA
(pj:111) MPN Total Coliforms • 1 per 100 ml (1) • 500 NA <2 NA
Co tor • 15 (2) • 60 NA 20 NA
Solids • 500 mg/l (2) • 220 NA 270 NA Flooride • 2. 0 mg/[ (2) • <0.2 NA <ll.2 NA
Su~f actants CMBAS) *.Nooe • <0.01 NA <0.0\ NA
tH trate • 10 mg/l (2) • <0.02 HA 0.03 NA
;Ni tr-i te • 1 .o mg/l (2) • 0.08 HA 0.03 HA
pH • 6.5 -8.5 (2) • 7.7 NA 7.6 HA
Sul f.ate • 250 mg/ l (2) • 29 NA 46 NA
Table ! CENTRAL TRANSPORT, !NC. -CHARLOTTE TERHlHAL GRCUNO WATER QUALITY AHALYSES
• Production We l l
CATEGORY PARAMETER * Drinking Water • 3/07/91 3/07/91 3/21/91 3/21/91
• Standards "'"<un1i lt.) (fil t.) (unfil t.) (fil t.) ------------------------------------* ---------------• --------------------- -------
Metals Alunin1.111 * N'one * <0.1 <O.t <0.1 <0.1
(-) Arsenic * 0. 05 mg/l (1) * <0.01 <0.01 <0.01 <0.01
Bariun • 1.0 mg/l (1) * <0.1 <O. 1 <O .1 <0.1
Beryl l iun * None * 0.03 0.03 0.04 0.04
Caclrli LITI * 0.005 mg/ I ( 1) • <0.01 <0.01 <0.01 <0.01
CalciLJTI *:Nooe • 56 54 70 71
Chrc:mi LITI * 0.05 mg/I (1) • 0.04 0.04 <0.01 <0.01
Cobol t * None • <0. 01 <0.01 <0.01 <0.01
Copper • 1 .0 mg/I (2) • 0.01 0.02 0.01 0.02
Iron • 0 .03 mg/! (2) • 0.41 0.04 0.14 0.7
L.,d • 0.05 mg/l ( 1) • <0.02 <0.02 <0.02 <0.02 • M a_gne.s i UTI * None • 11 11 14 14
Manganese • 0.05 mg/l (2) • 0.67 0.64 0.8 0.8
Mercury • 0.0005 mg/l (1) • <0.0005 <0.0005 <0.0005
Nickel • 0.15 mg/l (2) • <0.02 <0.02 <0.02 0.02
Potassiun * None • 5.2 3.5 5.2 3.7
Silver • 0.05 mg/l (1) • <0.01 <0.01 <0.01 <0.01
Sodiun * N'one * 11 10 13 13
VanadiL.111 * N'one * <0.01 <0.01 <0.01 <0.01
Zinc • 5.0 mg/l (2) • 0.06 0.06 0.07 0.09
Cyanide * 0. 154 mg/ I (2) • <0.01 NA <0.01 NA
Base/Neutral Di-n·Butyl Phtholote (ppb) • none • NO NA MD NA
Acid Naphthal""e (ppb) • none • NO NA ND NA
Extractables Bis (2-ethylhexyl) Phthalate* none • NO NA ND NA
(ppb) 1,3-oiohlorobenz.,,e • 0.6()0 (1) • ND NA MD NA
N-~itrosodiphenylamine • none • ND NA ND NA
Phenol (ppb) • none • ND NA ND NA
2,4-Dimethylphenot (ppb) * none • ND NA ND NA
114-Dichlorobenzene • 0.075 ( 1) • ND NA ND NA
Volatile Vinyl Chloride • 0.002(1) • ND HA NO NA
Organic Acetone * none • ND NA NO NA
Coopounds Benzene (ppb) • 0.005 (1) • ND HA ND MA
(ppb) 1,1·Dichloroethylene (ppb) • 0.007 (1) • ND NA NO NA
1,2-Dichlorobenzene (ppb) • 0.600 (1) * ND NA ND HA
Ethylbenzene (ppb) • 0. 700 (1) * ND NA ND HA
Methylene Chloride * 0.007 (1) • ND NA ND NA • Toluene (ppb) • 2.000 (1) • ND NA MD NA
1,2,4-Trichlorobenzene (ppb)* 0.700 (1) • ND NA MD NA
1,1,1-Trichloroethane * 0.200(1) • NO NA MD NA
m-Xylene (ppb) • 10.0 (1) • NO NA MD MA
Xylenes (ppb) • 10.0 (1) • NO NA ND MA
1,2-0ichloroethene {total} (* liOfie • ND NA ND MA
Chloroform (ppb) • 0.100 (1) • ND NA NO NA
1,1 Oichloroethane • None • ND NA NO NA
Miscellaneous Chtoride • 250 1Jl9/l (2) • 15 NA 17 NA
(-) KPH Total Coliforms • 1 per 100 nj_ (1) • <2 NA <2 NA
Color • 15 (2) • 10 HA <10 NA
Sol ids • 500 "'9/l (2) • 26() HA 310 NA
Fluoride • 2.0 mg/l (2) * <0.2 NA <0.2 NA
surfactants (MBAS) * rfone * <0.01 NA <0.01 MA
Nitrate • 10 mg/l (2) • 0.18 NA 0.27 HA
~itrite • 1. 0 mg/l (2) • <0.02 NA <0.02 HA
~ * 6.5 -8.5 (2) • 6.8 NA 7.3 HA
Sulfate • 250 mg/ l (2) • 22 MA 30 NA
~