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HomeMy WebLinkAbout4103_GreensboroMSWLF_GWRM_DIN27821_20160926White Street Landfill - Phase I Permit # 41-03 Post-Closure Monitoring September 2016 Greensboro North Carolina S&ME Project No. 1584-98-081C Prepared for: The City of Greensboro Prepared by: S&ME, Inc. 8646 W Market St, Suite 105 Greensboro, NC 27409 January 11, 2017 White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 ii Table of Contents 1.0 Executive Summary...............................................................................................1 2.0 Introduction............................................................................................................1 3.0 Scope Of Work.......................................................................................................2 4.0 Methods Employed...............................................................................................2 4.1 Monitoring Well Sampling..............................................................................................2 4.2 Stream Sampling...............................................................................................................3 5.0 Results......................................................................................................................4 5.1 Groundwater Analytical Results....................................................................................4 5.2 Groundwater Flow Direction..........................................................................................4 5.3 Surface Water....................................................................................................................4 5.4 Quality Assurance............................................................................................................5 6.0 References...............................................................................................................5 7.0 Certification............................................................................................................6 TABLES Table 1:Well Construction and Groundwater Elevation Data Table 2:Summary of Groundwater Sampling Field Parameters Table 3:Summary of Groundwater Analytical Results - Detections Table 4:Summary of Groundwater Standard Exceedances Table 5:Summary of Surface Water Analytical Results - Detections Table 6:Summary of 2B Surface Water Standard - Exceedances FIGURES Figure 1:Groundwater Flow Map Figure 2:Stream Sample Location APPENDICES Appendix I: Groundwater Sampling Field Data Sheets Appendix II: Laboratory Analytical Reports Appendix III: NCDEQ EDDs (CD only) White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 1 1.0 Executive Summary Five monitoring wells and five stream locations at Phase I of the White Street Landfill were sampled between September 26 and September 28, 2016. Five wells (I-1, I-2, I-3, I-4 and MW-13) comprise the groundwater monitoring system for the closed Phase I unit at the White Street Landfill facility. Monitoring well MW-13 serves as a background well for both the Phase I and the Phase II areas. The sampling was conducted according to North Carolina Solid Waste Management Guidelines and samples were analyzed by a North Carolina certified laboratory. Analytical results from the four Phase I monitoring wells indicate that the following NCAC 2L groundwater quality standards were exceeded. ♦Benzene was detected at 4.3 µg/L at well I-1, this concentration exceeds the 15A NCAC 2L groundwater standard (2L Standard) of 1 µg/L. ♦Vinyl Chloride was detected at an estimated concentration of 0.52J µg/L at well I-3, this concentration exceeds the 2L Standard of 0.03 µg/L. With regards to surface water sampling, chloroform, toluene, and acetone were detected. Inorganic constituents (total metals) were detected at each sampled location. Analytical results for surface water samples collected up-stream of the White Street Landfill exhibited concentrations of certain metals. Sample collected down-stream were reported to contain similar metals, with concentrations generally lower than those reported for the up-stream samples. In view of this and prior surface water and groundwater monitoring data, the closed Phase I landfill is not considered to be the source of these constituents. Furthermore, no reported concentrations were greater than the corresponding NCAC 2B surface water standards for Water Supply. It is believed that the cause of the benzene and vinyl chloride 2L Standard exceedances within the hydrogeologic regime at Phase I is from percolation of landfill constituents from the waste management unit into the uppermost groundwater aquifer. Analytical results for the samples obtained from monitoring wells I-1 and I-3 report apparent 2L Standard exceedances. These wells are located less than 100 feet from the limit of waste and between the limits of waste and the compliance boundary. The City of Greensboro believes that Phase I of the White Street Landfill was closed prior to January 1, 1983, and as such, assessment and cleanup of this landfill unit should fall under jurisdiction of the NCDEQ Inactive Hazardous Sites program Pre-Regulatory Landfill Unit, for “orphan landfills.” 2.0 Introduction White Street Landfill is a Solid Waste Management Facility (SWMF) located at the north end of White Street in northeastern Greensboro. S&ME, Inc. (S&ME) was contracted by the City of Greensboro to complete this water quality monitoring event. Phase I of the landfill is a closed unit, reportedly covered by Solid Waste Permit #41-03, which also covers Phase II of the Facility.Figure 1 is a map showing the monitor well locations. One up-gradient and four down-gradient monitoring wells located along the perimeter of the closed Phase I disposal area were sampled. Five surface water samples were collected from North Buffalo Creek and one of its tributaries in the vicinity of the White Street facility. Phase I shares the surface water sampling locations with adjacent Phase II. White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 2 The samples collected from Phase I monitoring wells I-1, I-2, I-3, and I-4, were analyzed for Appendix I volatile organic constituents and the eight RCRA metals. Since background monitoring well MW-13 is shared with Phase II, the collected sample was analyzed for Appendix I constituents. This report discusses the field procedures, summarizes the field measurements and analytical results for the post-closure monitoring event completed during September 2016. 3.0 Scope Of Work To complete the scope of work, S&ME completed the following tasks: ♦Sampled four monitoring wells and five surface water locations. ♦Obtained field values for pH, temperature, conductivity, dissolved oxygen (DO), oxidation- reduction potential (ORP), and turbidity at each sampled monitoring well location. ♦Depth to water measurements were collected prior to sampling and during well purging to monitor drawdown. ♦Groundwater samples I-1, I-2, I-3, and I-4, were analyzed for Appendix I organic constituents and 8-RCRA metals by a North Carolina certified laboratory, using State approved methods. ♦Groundwater sample MW-13 was analyzed for Appendix I constituents by a North Carolina certified laboratory, using State approved methods. ♦Surface water samples SW-1, SW-2, SW-3, SW-4 and SW-5 were analyzed for Appendix I constituents by a North Carolina certified laboratory, using State approved methods. ♦Estimated groundwater flow directions for the Phase I area. ♦Prepared and submitted this Post-Closure Monitoring Report to the City of Greensboro and the North Carolina Department of Environmental Quality (NCDEQ). 4.0 Methods Employed 4.1 Monitoring Well Sampling Phase I groundwater monitoring well sampling took place on September 28, 2016, with shared background monitoring well MW-13 sampled on September 27, 2016. The monitoring well locations are shown on Figure 1. A representative from S&ME opened each well and measured the static water level from the top edge of the PVC casing in wells. The total well depth sounding data reported for the sampling events completed during September 1997 and May 1998 were used to determine the volume of water in wells I-1, I-2, I-3, I-4 and MW-13, where dedicated MicroPurge™pumps had been previously installed.Table 1 provides a summary of relevant well construction details. In accordance with the facility's approved Water Quality Monitoring Plan, each well was purged using the dedicated MicroPurge™pumps using compressed air. At each well, the purge rate and the drawdown of the water table were monitored as an indicator of how much stress the purging placed on the aquifer. The purge rates were calculated by recording the time required to fill a graduated cylinder. The purging flow rates varied but were approximately 100 milliliters/minute (ml/min.). During purging, the depth to water was periodically monitored and recorded on the groundwater sampling field data sheets. White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 3 It is our opinion that the observed drawdowns were generally minor during purging; therefore, the stresses placed on the aquifer should have been insignificant. The observed drawdown data suggests that the purging rates should have been low enough such that recharge water should not have been overly agitated, reducing the potential for colloids to be drawn into the well bore. The purge water from each of these wells was monitored for pH, temperature, conductivity, DO, ORP and turbidity. The time interval between measurements approximated one equipment volume, at a minimum. Sample collection commenced when the changes in those readings fluctuated no more than 10 percent and utilizing a turbidity goal of 10 NTU, or less. Despite the use of low flow methods, turbidity values remain higher than ideal during the purging of wells I-2 and I-4; therefore, samples were collected without meeting the turbidity goal, relying upon professional judgement. The field data collected during sampling was recorded on the groundwater sampling field data sheets, included in Appendix I.Table 2 provides a summary of the field data collected during this event. Groundwater samples were collected from dedicated pump discharge Teflon tubing at the top of each well. Immediately upon collection, each sample was placed in laboratory supplied containers and placed in a cooler with ice. The sampler wore nitrile gloves that were changed between wells to reduce the possibility of cross contamination. Upon collection, the groundwater samples were maintained under chain-of custody. Phase I monitoring well samples I-1, I-2, I-3 and I-4 were analyzed for Appendix I volatile organic constituents and the eight RCRA metals. Since background well MW-13 is shared with Phase II, the collected sample was analyzed for Appendix I constituents. Analyses were conducted by Environmental Conservation Laboratories, a North Carolina certified laboratory. 4.2 Stream Sampling Surface water sampling took place on September 26, 2016. Surface water SW-1 was collected from North Buffalo Creek on the west side of the U.S. Highway 29 bridge upstream of the landfill. Surface water SW-2 was collected from a southern tributary of North Buffalo Creek just before it joins the main creek west of the landfill entrance. SW-3 was collected from North Buffalo Creek downstream of the North Buffalo Wastewater Treatment Plant outfall and upstream of the landfill. SW-4 was collected from North Buffalo Creek downstream of the landfill at a USGS gauging station located on North Buffalo Creek about three- quarters of a mile north of the landfill. SW-5 was collected from North Buffalo Creek immediately downstream of the Phase I and II landfill disposal areas. The locations are shown in Figure 2. The surface water samples were collected by immersing laboratory supplied containers in the water to be sampled. After collection, the surface water samples were placed in a cooler with ice and placed under chain-of-custody. Each surface water sample was analyzed for Appendix I inorganic and volatile organic constituents by Environmental Conservation Laboratories; a North Carolina certified laboratory. White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 4 5.0 Results 5.1 Groundwater Analytical Results Table 3 provides a summary of the constituent concentrations reported above the method detection limit (MDL) for the groundwater samples collected. Concentrations reported between the MDL and the Solid Waste Section Limits (SWSL) are considered estimated, thus shown as a “J” flagged concentration.Table 4 provides a summary of the reported concentrations which exceed the 15A NCAC 2L Standards (2L Standard). For some constituents where there is no established 2L Standard, North Carolina has published Interim Maximum Allowable Concentrations (IMACs). The IMAC values are intended to help NCDEQ in assessing conditions and setting health protective groundwater levels at regulated sites. As such the IMAC are only interim and not final groundwater quality standards. The following summarizes the exceedances of the corresponding 2L Standard or IMAC. ♦At well I-1, benzene was detected at 4.3 µg/L, which exceeds the 2L Standard of 1 µg/L. ♦At well I-3, vinyl chloride was detected at an estimated concentration of 0.52 µg/L, which exceeds the 2L Standard of 0.03 µg/L. The complete laboratory analytical reports are included in Appendix II. Analytical results in the NCDEQ EDD format are contained in Appendix III (CD only). 5.2 Groundwater Flow Direction The static water levels in the four Phase I monitoring wells were measured on September 28, 2016, while background monitoring well MW-13 was measured on September 27, 2016. The depths to the water for the Phase I compliance wells ranged from 5.07 to 15.49 feet below the top of well casings on these dates. Groundwater and well casing elevation data are presented in Table 1. A groundwater contour map constructed using the data collected during this monitoring event is presented as Figure 1. The groundwater elevation data collected during this monitoring event indicates that the groundwater beneath Phase I generally flows to the north toward Buffalo Creek. 5.3 Surface Water Table 5 provides a summary of the constituent concentrations reported above the MDL for the surface water samples collected. Concentrations reported between the MDL and the SWSL are considered estimated, thus shown as a “J” flagged concentration.Table 6 provides a summary of the reported concentrations which exceed the corresponding 15A NCAC 2B Standard (2B Standard) for Water Supply. The following summarizes the exceedances of the 2B Standards. The complete laboratory analytical report is included in Appendix II. ♦No target constituents were detected above the 2B Standards during the September 2016 sampling event, except for copper. The copper concentrations upstream of the facility were similar to those detected down-stream. Immediate upstream sources include a municipal wastewater treatment plant. Similar constituents were detected up-stream of the facility and down-stream, with constituent concentrations for the up-stream samples generally equal to those reported for down-stream sample locations. Based on the surface water White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 5 analytical data obtained, this closed landfill is not believed to be the source of the apparent copper 2B Standard exceedance. 5.4 Quality Assurance A qualitative review of the data was performed to verify that the detected concentrations in the laboratory report were of known quality. A formal, quantitative data validation was not performed. Laboratory- assigned data qualifiers were evaluated to verify that rejected or unsupportable data were not included in the dataset. Quality control data provided in the laboratory reports were also reviewed. No rejected or otherwise unacceptable quality data were reported from the laboratory. The monitoring wells in Phase I were sampled using dedicated micro-purge pumps. Therefore, no equipment rinse samples were collected for analysis for data quality control. Trip blank samples accompanied the sample bottles from the time they left the laboratory until they returned. The trip blank samples were analyzed for Appendix I volatile organic constituents. No volatile organic constituents were present in the trip blank samples at detectable levels. Laboratory QC samples were analyzed for all constituents included in this sampling event. The results of the trip blank and laboratory QC sample analyses are included in Appendix II. 6.0 References Fetter, C. W., 1988, Applied Hydrogeology, New York; Macmillian Publishing Company, 1988, 592 pp. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Environmental Management, Subchapter 2L, Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, Sections .0100, .0200, and .0300; from the Environmental Management Commission Raleigh, North Carolina. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Environmental Management, Subchapter 2B, Classifications and Water Quality Standards Applicable to the Surface Waters of North Carolina, Section .0200; from the Environmental Management Commission, Raleigh, North Carolina. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Solid Waste Management, subchapter 13B, Solid Waste Management, Section .1600. White Street Landfill – Phase I Post-Closure Monitoring Report Greensboro, North Carolina S&ME Project No. 1584-98-081C January 11, 2017 6 7.0 Certification I hereby certify this 11 th day of January 2017 that this report was prepared by me or under my direct supervision. ______________________________ Edmund Q.B. Henriques, L.G. Senior Geologist / Project Manager Technical support provided by: ______________________________ B. Summers Long Staff Professional TABLE 1 WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA S&ME PROJECT NO. 1584-98-081C Well ID Date Installed Total Depth Well Diameter Depth to Top of Screen Well Screen Interval Geology of Screened Interval Northing Easting Ground Elevation Top of Casing Elevation Depth to Groundwater1 Groundwater Elevation NAD 83 NAD 83 NAVD 88 NAVD 88 Sep-16 Sep-16 (feet)(inches)(feet)(feet bgs)(feet msl.)(feet msl.)(feet)(feet msl.) I-1 7/14/1989 24 2 14 14 - 24 partially weather rock 1785583.98 859726.77 not measured 713.75 10.88 702.87 I-2 7/14/1989 24 2 14 14 - 24 sandy silt 1785319.23 860640.98 not measured 703.09 5.41 697.68 I-3 7/14/1989 24 2 14 14 - 24 sandy silt 1785334.06 861315.16 not measured 707.43 15.49 691.94 I-4 7/14/1989 15 2 5 5 -15 sandy silt saprolite 1786167.37 861969.09 not measured 694.94 5.07 689.87 MW-13 7/14/1989 34 2 19 19-34 sandy silt saprolite 1783188.52 858763.91 not measured 741.24 20.21 721.03 City of Greensboro provided the top of casing elevations and ground surface elevations Well Construction details obtained from Well Construction Records reported by BPA Environmental & Engineering, Inc. feet bgs. = feet below ground surface feet msl. = feet mean sea level Depth to Groundwater 1 = below top of casing Groundwater Elevation = calculated groundwater elevation T:\Projects\1998\ENV\081C White Street Landfill (2014)\2016 Compliance Monitoring\Fall 2016\Phase 1\Phase1_September_2016_tables.xlsx TABLE 2 SUMMARY OF GROUNDWATER SAMPLING FIELD PARAMETERS PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA S&ME PROJECT NO. 1584-98-081C DATE WELL WELL DEPTH TO WATER ODOR PURGE PUMP WELL EVAC PURGED TEMP pH SPECIFIC ORP DO TURBIDITY ID DEPTH WATER ELEVATION METHOD RATE VOLUME VOLUME DRY?CONDUCTANCE (feet)(feet)(feet)(mL/min)(gallons)(gallons)(yes/no)(deg C)(SU)(μs/cm)(mV-NHE)(mg/L)(NTU) 9/28/2016 I-1 25.00 10.88 702.87 None low flow 100 2.30 1.0 no 20.33 5.64 2.581 22 0.50 2.59 9/28/2016 I-2 21.30 5.41 697.68 None low flow 100 2.59 1.3 no 23.90 5.99 2.076 -32 0.61 38.5 9/28/2016 I-3 24.20 15.49 691.94 None low flow 100 1.42 1.3 no 20.57 6.11 2.324 20.0 0.64 1.2 9/28/2016 I-4 15.00 5.07 689.87 None low flow 100 1.62 1.2 no 21.39 6.57 1.390 -59 0.14 14.0 9/27/2016 MW-13 33.00 20.21 721.03 None low flow 100 2.19 0.8 no 18.06 6.54 0.336 42.2 4.81 21.3 Notes: 1. TEMP = groundwater temperature, measured in degrees Celsius 2. Pump Rate, measured in milliliters/minute 3. Specific Conductance, measured in μs/cm indicates micro Siemens per centimeter. 4. SU indicates Standard Units. 5. NTU indicates Nephelometric Turbidity Units. 6. ORP = Oxidation Reduction Potential, mV-NHE indicates millivolts-Normal Hydrogen Electrode. 7. EVAC = evacuated volume of groundwater 8. DO = dissolved oxygen, measured in milligrams per liter NC SWSL NCAC 2L NCDEQ Federal Well ID I-1 I-2 I-3 I-4 Standards IMAC MCLs Sample ID 4103-I1 4103-I2 4103-I3 4103-I4 Date Collected 09/28/16 09/28/16 09/28/16 09/28/16 Detected Analytes (µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L) 75 1,1-Dichloroethane 0.86 J <0.13 2.9 J <0.13 5 6 ns ns 77 1,1-Dichloroethene <0.21 <0.21 0.80 J <0.21 10 6 ns 7 69 1,2-Dichlorobenzene <0.19 1.5 J 0.83 J <0.19 5 20 ns 600 71 1,4-Dichlorobenzene 4.7 1.6 4.2 2.7 1 6 ns 75 16 Benzene 4.3 <0.15 0.52 J <0.15 1 1 ns 5 39 Chlorobenzene 11 8.7 17 3.9 3 50 ns 100 78 cis-1,2-Dichloroethene 0.77 J <0.15 <0.15 <0.15 5 70 ns 70 211 Vinyl Chloride <0.32 <0.32 0.52 J <0.32 1 0.03 ns 2 14 Arsenic 7.07 J 9.93 J <6.80 <6.80 10 10 ns 10 15 Barium 623 532 135 628 100 700 ns 2,000 34 Cadmium <0.360 <0.360 <0.360 0.427 J 1 2 ns 5 51 Chromium <1.4 2.98 J <1.40 <1.40 1 10 ns 5 131 Lead <3.10 4.94 J <3.10 3.56 J 10 15 ns 15 µg/L =concentrations reported in micrograms per liter (ug/L) < = concentrations is less than the method detection limit shown NC SWSL = North Carolina Solid Waste Section Limit J = Concentration reported greater than the method detection limit but less than the SWSL, thus it is considered estimated NCAC 2L Standards = 15A North Carolina Administrative Code 2L .0200, GW Quality Standards for Class GA groundwater. concentrations in bold exceed the corresponding 2L Standard NCDEQ IMAC = Interim Maximum Allowed Concentration, NCDEQ Federal MCL = Maximum Concentration Levels, USEPA ns = no MCL listed, USEPA na = not analyzed Solid Waste Section ID # Sample Locations 8-RCRA Metals + Appendix II Metals Appendix II Volatile Organic Compounds S&ME PROJECT NO. 1584-98-081C TABLE 3 SUMMARY OF GROUNDWATER ANALYSES RESULTS - DETECTIONS PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA TABLE 4 SUMMARY OF GROUNDWATER STANDARD EXCEEDANCES PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA S&ME PROJECT NO. 1584-98-081C NCAC 2L NCDEQ Federal Well ID I-1 I-3 Standards IMAC MCLs Sample ID 4103-I1 4103-I3 Date Collected 09/28/16 09/28/16 Detected Analytes (µg/L)(µg/L)(µg/L)(µg/L)(µg/L) Appendix I Volatile Organic Compounds 16 Benzene 4.3 1 ns 5 211 Vinyl Chloride 0.52J 0.03 ns 2 µg/L =concentrations reported in micrograms per liter (µg/L) NC SWSL = North Carolina Solid Waste Section Limit NCAC 2L Standards =15A North Carolina Administrative Code 2L .0200, GW Quality Standards for Class GA groundwater. Only concentrations greater than the NCAC 2L Standards are shown NCDEQ IMAC = Interim Maximum Allowed Concentration, NCDEQ Federal MCL = Maximum Concentration Levels, USEPA ns = no MCL listed, USEPA Solid Waste Section ID # Sample Locations NC SWSL NCAC 2B Sample Location SW-1 SW-2 SW-3 SW-4 SW-5 Standards* Sample ID 4103-SW1 4103-SW2 4103-SW3 4103-SW4 4103-SW5 Date Collected 09/26/16 09/26/16 09/26/16 09/26/16 09/26/16 Detected Analytes (µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L) 3 Acetone <10 11 J <10 <10 11 J 100 no standard 44 Chloroform <0.18 <0.18 1.6 J <0.18 <0.19 5 no standard 196 Toluene <0.14 1.1 <0.14 <0.15 <0.16 1 11 13 Antimony <0.220 <0.220 <0.220 <0.220 0.479 J 6 no standard 15 Barium 44.8 J 52.8 J 17.6 J 27.9 J 33.9 J 100 1000 53 Cobalt <1.10 1.30 J <1.10 <1.10 <1.10 10 no standard 54 Copper 4.52 J 2.57 J 6.61 J 6.03 J 8.07 J 10 2.7 152 Nickel <2.20 <2.20 3.54 J 3.34 J 6.44 J 50 25 194 Thallium 0.190 J 0.124 J 0.205 J 0.187 J 0.316 J 5.5 no standard 209 Vanadium 1.95 J <1.40 <1.40 1.64 J 4.58 J 25 no standard 213 Zinc 5.08 J 5.21 J 20.0 16.4 27.7 10 36 J = * = Title 15A NCAC 2B Standards for all Water Supply Classifications µg/L = concentrations reported in micrograms per liter (µg/L) < = concentrations is less than the method detection limit shown NC SWSL = North Carolina Solid Waste Section Limit S&ME PROJECT NO. 1584-98-081C TABLE 5 SUMMARY OF SURFACE WATER ANALYSES RESULTS - DETECTIONS PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA Concentration reported greater than the method detection limit but less than the SWSL, thus it is considered estimated Solid Waste Section ID # Appendix I Metals Appendix I Volatile Organic Compounds Sample Locations SUMMARY OF 2B SURFACE WATER STANDARD EXCEEDANCES PHASE 1 - PERMIT # 41-03 WHITE STREET LANDFILL Sample Locations NC SWSL NCAC 2B Sample Location SW-1 SW-2 SW-3 SW-4 SW-5 Standards* Sample ID 4103-SW1 4103-SW2 4103-SW3 4103-SW4 4103-SW5 Date Collected 09/26/16 09/26/16 09/26/16 09/26/16 09/26/16 Detected Analytes (µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L) 54 Copper 4.52 J 6.61 J 6.03 J 8.07 J 10 2.7 concentrations in bold print are greater than the referenced NCAC 2B Standard µg/L =concentrations reported in micrograms per liter (µg/L) < =concentrations is less than the method detection limit shown * = Title 15A NCAC 2B Standards for all Water Supply Classifications J = Blank cell indicates no 2B Standard exceedance detected. Solid Waste Section ID # Appendix I Volatile Organic Compounds and 8-RCRA Metals TABLE 6 Concentration reported greater than the method detection limit but less than the SWSL, thus it is considered estimated GREENSBORO, NORTH CAROLINA S&ME PROJECT NO. 1584-98-081C II - 8 I- 2 I- 1 I- 3 I- 5 MW-14 II - 6 I - 4 II - 1 II-5 M W - 1 3 II - 1 2 SM W - 4 69 0 . 0 0 70 0 . 0 0 71 0 . 0 0 720 . 0 0 69 2 . 0 0 69 4 . 0 0 69 6 . 0 0 69 8 . 0 0 70 2 . 0 0 704 . 0 0 70 6 . 0 0 70 8 . 0 0 712 . 0 0 714 . 0 0 71 6 . 0 0 71 8 . 0 0 GROUNDWATER FLOW MAP WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA AS SHOWNRDMBSL 1584-98-081CNOVEMBER 20161 PHASE I LE G E N D : SU R F A C E W A T E R S A M P L I N G P O I N T GR O U N D W A T E R E L E V A T I O N ( S E P T E M B E R 2 0 1 6 ) MO N I T O R I N G W E L L L O C A T I O N GR O U N D W A T E R F L O W D I R E C T I O N GR O U N D W A T E R C O N T O U R L I N E (7 0 2 . 8 7 ) (6 9 7 . 6 8 ) (6 8 9 . 8 7 ) (7 0 2 . 8 7 ) (6 9 1 . 9 4 ) (7 2 1 . 0 3 ) PHASE II WHITE STREET LANDFILL GREENSBORO, NORTH CAROLINA AS SHOWNDSB/RDMBSL 1584-98-081NOVEMBER 20162 SURFACE WATER SAMPLING LOCATIONS 0GRAPHIC SCALE 800 400 800 SCALE: 1" = 800' LE G E N D ST R E A M S A M P L E L O C A T I O N Appendices Appendix I – Groundwater Sampling Field Data Sheets Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet 14.12 feet Purge Method Sample Method Start 1115 Stop 1155 Purge Rate ml/min Control Settings On: 3.0 sec.Start 1155 Stop 1205 Off: 27.0 sec. Pressure:psi 2" well: height:14.12 x .163 =2.30156 gallons liters x Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW 1115 9/28/2016 1120 9/28/2016 19.17 5.79 2.473 54 3.58 4.24 11.07 1125 9/28/2016 19.41 5.71 2.506 46 2.06 4.11 11.05 1130 9/28/2016 19.88 5.66 2.553 43 1.27 3.48 11.02 1135 9/28/2016 20.20 5.64 2.573 39 0.89 2.50 11.03 1140 9/28/2016 20.32 5.66 2.577 34 0.69 2.57 11.02 1145 9/28/2016 20.26 5.66 2.571 28 0.60 2.74 11.02 1150 9/28/2016 20.19 5.64 2.576 24 0.55 2.53 11.02 1155 9/28/2016 20.33 5.64 2.581 22 0.50 2.29 11.02 Final Readings 1155 9/28/2016 20.33 5.64 2.581 22 0.50 2.59 11.02 * C units mS/cm mV mg/L NTU Sample Collection Time Was well purged dry Field Analyses Volume of water in well Volume of water removed 4.0 100 Depth to well bottom from measuring point:25.00 Height of water column: Bladder Pump Measuring point:Top of Casing Well Purging & Sample Collection Bladder Pump Purge Time Gary Simcox Depth to water from measuring point:10.88 1205 Sunny 80 *F Water Level & Well Data Wednesday, September 28, 2016 Wednesday, September 28, 2016 Blank White Street Landfill 1584-98-081 4103-I1 Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet 15.89 feet Purge Method Sample Method Start 1225 Stop 1315 Purge Rate ml/min Control Settings On: 3.0 sec.Start 1315 Stop 1325 Off: 27.0 sec. Pressure:psi 2" well: height:15.89 x .163 =2.59007 gallons liters x Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW 1225 9/28/2016 1230 9/28/2016 22.68 5.85 2.230 -12 1.09 8.59 6.39 1235 9/28/2016 22.88 5.97 2.147 -26 0.96 13.50 6.62 1240 9/28/2016 22.84 5.97 2.072 -41 0.86 23.30 6.82 1245 9/28/2016 23.46 6.00 2.079 -38 0.77 45.50 6.91 1250 9/28/2016 24.43 5.98 2.114 -31 0.73 48.90 6.89 1255 9/28/2016 24.71 6.00 2.121 -28 0.58 46.50 6.86 1300 9/28/2016 24.64 6.00 2.120 -35 0.56 41.40 6.90 1305 9/28/2016 24.44 6.00 2.107 -36 0.52 38.70 6.97 1310 9/28/2016 24.23 6.00 2.096 -32 0.59 37.80 7.01 1315 9/28/2016 23.90 5.99 2.076 -32 0.61 38.50 6.98 Final Readings 1315 9/28/2016 23.90 5.99 2.076 -32 0.61 38.50 6.98 * C units mS/cm mV mg/L NTU Wednesday, September 28, 2016 Friday, September 02, 2016 White Street Landfill 1584-98-081 4103-I2 Bladder Pump Purge Time GROUNDWATER SAMPLING FIELD DATA Water Level & Well Data Depth to water from measuring point:5.41 1325 Height of water column: Measuring point:Top of Casing Well Purging & Sample Collection Cloudy 80 *FGary Simcox Depth to well bottom from measuring point:21.30 Field Analyses Volume of water in well Volume of water removed 4.0 Bladder Pump 100 Sample Collection Time Was well purged dry Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet feet Purge Method Sample Method Start 1355 Stop 1445 Purge Rate ml/min Control Settings On: 3.0 sec.Start 1455 Stop 1505 Off: 27.0 sec. Pressure: 21 psi 2" well: height:8.71 x .163 =1.41973 gallons liters x Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW 1355 9/28/2016 1400 9/28/2016 20.20 6.24 2.096 32 3.34 17.40 15.69 1405 9/28/2016 20.24 6.14 2.180 15 2.13 12.70 15.73 1410 9/28/2016 20.32 0.14 2.210 16 1.86 6.37 15.79 1415 9/28/2016 20.51 6.12 2.270 18 1.34 5.55 15.77 1420 9/28/2016 20.75 6.12 2.321 16 0.88 2.37 15.69 1425 9/28/2016 20.79 6.11 2.329 16 0.83 1.69 15.77 1430 9/28/2016 20.89 6.11 2.338 18 0.77 1.63 15.71 1435 9/28/2016 20.91 6.10 2.342 20 0.61 1.54 15.79 1440 9/28/2016 20.69 6.10 2.337 22 0.62 1.32 15.75 1445 9/28/2016 20.57 6.11 2.324 20 0.64 1.20 15.72 Final Readings 1445 9/28/2016 20.57 6.11 2.324 20 0.64 1.20 15.72 * C units mS/cm mV mg/L NTU Field Analyses Volume of water in well Volume of water removed 4.0 Bladder Pump 100 Sample Collection Time Was well purged dry Measuring point:Top of Casing Well Purging & Sample Collection Bladder Pump Purge Time Depth to well bottom from measuring point:24.20 Height of water column:8.71 Gary Simcox Depth to water from measuring point:15.49 Cloudy 80 *F Water Level & Well Data Wednesday, September 28, 2016 Wednesday, September 28, 2016 GROUNDWATER SAMPLING FIELD DATA White Street Landfill 1584-98-081 4103-I3 1505 Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet feet Purge Method Sample Method Start 1520 Stop 1605 Purge Rate ml/min Control Settings On: 2.0 sec.Start 1605 Stop 1615 Off: 28.0 sec. Pressure: 15 psi 2" well: height:9.93 x .163 =1.61859 gallons liters x Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW 1520 9/28/2016 1525 9/28/2016 20.42 6.52 1.601 -50 0.95 54.60 6.39 1530 9/28/2016 21.12 6.55 1.483 -58 0.37 23.30 6.61 1535 9/28/2016 21.40 6.57 1.442 -60 0.24 18.90 6.81 1540 9/28/2016 21.30 6.58 1.442 -59 0.19 16.40 6.87 1545 9/28/2016 21.18 6.57 1.402 -60 0.16 16.00 6.91 1550 9/28/2016 21.30 6.61 1.398 -61 0.18 14.10 7.01 1555 9/28/2016 21.38 6.57 1.396 -58 0.14 13.00 7.04 1600 9/28/2016 21.37 6.57 1.392 -60 0.15 13.30 7.08 1605 9/28/2016 21.39 6.57 1.390 -59 0.14 14.00 7.11 Final Readings 1605 9/28/2016 21.39 6.57 1.390 -59 0.14 14.00 7.11 * C units mS/cm mV mg/L NTU Water Level & Well Data White Street Landfill 1584-98-081 4103-I4 Wednesday, September 28, 2016 1615 Cloudy Wednesday, September 28, 2016 Was well purged dry Field Analyses 70 *FGary Simcox Measuring point:Top of Casing Well Purging & Sample Collection Depth to water from measuring point:5.07 Depth to well bottom from measuring point:15.00 Height of water column:9.93 Bladder Pump Purge Time Volume of water in well Volume of water removed 5.0 Bladder Pump 100 Sample Collection Time Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet 0.00 feet Purge Method Sample Method Start Stop Purge Rate ml/min Control Settings On:sec.Start Stop Off:sec. Pressure:psi 2" well: height:0 x .163 =0 gallons liters Yes No *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW Final Readings 1210 9/26/2016 21.60 7.22 293.000 * C units mS/cm Measuring point: Monday, September 26, 2016 Monday, September 26, 2016 Height of water column: Sample Collection Time Depth to well bottom from measuring point: Well Purging & Sample Collection Purge Time Field Analyses Volume of water in well Volume of water removed Was well purged dry Blank Water Level & Well Data Depth to water from measuring point: 1210 1584-98-081 White Street Landfill 4112-SW1 Gary Simcox Sunny 75 *F Summit Avenue Bridge Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet 0.00 feet Purge Method Sample Method Start Stop Purge Rate ml/min Control Settings On:sec.Start Stop Off:sec. Pressure:psi 2" well: height:0 x .163 =0 gallons liters x Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW Final Readings 1130 9/26/2016 20.60 6.75 214.000 * C units mS/cm Depth to well bottom from measuring point: Monday, September 26, 2016 Monday, September 26, 2016 White Street Landfill 1584-98-081 4112-SW2 White Street and Nealtown Road Height of water column: Measuring point: Well Purging & Sample Collection Purge Time GROUNDWATER SAMPLING FIELD DATA Water Level & Well Data Depth to water from measuring point: 1505 Cloudy 75 *FGary Simcox Sample Collection Time Was well purged dry Field Analyses Volume of water in well Volume of water removed Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:No:Weather: Sampled By:Air Temp: feet feet feet Purge Method Sample Method Start Stop Purge Rate ml/min Control Settings On:sec.Start Stop Off:sec. Pressure:psi 2" well: height:0 x .163 =0 gallons liters Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW Final Readings 1345 9/26/2016 23.80 7.21 439.000 * C units mS/cm Was well purged dry Field Analyses Volume of water in well Volume of water removed GROUNDWATER SAMPLING FIELD DATA Water Level & Well Data Depth to water from measuring point: 1345 75 *F White Street Landfill Monday, September 26, 2016 Monday, September 26, 2016 1584-98-081 4112-SW3 Gary Simcox Cloudy Waste Water Treatment Plant Depth to well bottom from measuring point: Purge Time Measuring point: Sample Collection Time Well Purging & Sample Collection Height of water column:0.00 Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet feet Purge Method Sample Method Start Stop Purge Rate ml/min Control Settings On:sec.Start Stop Off:sec. Pressure:psi 2" well: height:0 x .163 =0 gallons liters Yes No *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW Final Readings 1245 9/26/2016 22.50 7.30 412.000 * C units mS/cm GROUNDWATER SAMPLING FIELD DATA Water Level & Well Data 1245 Cloudy 75 *F White Street Landfill Monday, September 26, 2016 1584-98-081 4112-SW4 Gary Simcox Rankin Mill Road Bridge Sample Collection Time Was well purged dry Purge Time Volume of water in well Field Analyses Monday, September 26, 2016 Measuring point: Depth to water from measuring point: Depth to well bottom from measuring point: Height of water column:0.00 Volume of water removed Well Purging & Sample Collection Location:Purge Date: Project No.:Purge Time: Source Well:Sample Date: Sample Time: Locked?:Yes:x No:Weather: Sampled By:Air Temp: feet feet feet Purge Method Sample Method Start Stop Purge Rate gpm Control Settings On:sec.Start Stop Off:sec. Pressure:psi 2" well: height:0 x .163 =0 gallons x liters Yes No x *Stabilization Parameters Time Date Temp pH Conductivity *ORP *D.O.*Turbidity DTW Final Readings 1100 9/26/2016 22.60 7.34 427.000 * C units mS/cm Was well purged dry Field Analyses Volume of water in well Volume of water removed 0.0 GROUNDWATER SAMPLING FIELD DATA Water Level & Well Data Depth to water from measuring point: 1100 75 *F White Street Landfill Monday, September 26, 2016 Tuesday, September 06, 2016 1584-98-081 4112-SW5 Gary Simcox Cloudy Below monitor well II-3 Depth to well bottom from measuring point: Purge Time Measuring point: Sample Collection Time Well Purging & Sample Collection Height of water column:0.00 Appendix II – Laboratory Analytical Reports Appendix III – NCDEQ EDDs (CD Only)