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PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

OXFORD UNIT 1 LANDFILL
PERMIT NO. 3901-CDLF-1997

FIRST SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2016

APRIL 2016

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: [phone] FAX: [phone] JOYCE PROJECT NO. 660.1601.12

FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2016
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
i

1.0 INTRODUCTION ................................................................................................................. 1
1.1 Site Background .................................................................................................................. 1
1.2 Site Conceptual Model ........................................................................................................ 2
1.2.1 Site Geology ............................................................................................................ 2
1.2.2 Site Hydrogeology ................................................................................................... 2
1.3 Aquifer Characteristics & Groundwater Flow Regime ....................................................... 3
1.4 Monitoring History and Regulatory Status ......................................................................... 3
1.4.1 Monitoring History .................................................................................................. 3
1.4.2 Regulatory Status .................................................................................................... 4
2.0 FACILITY MONITORING PROGRAM ........................................................................... 5
2.1 Groundwater Monitoring Program ...................................................................................... 5
2.2 Surface Water Monitoring Program .................................................................................... 7
3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2016 .................................................... 7
3.1 Field Work ........................................................................................................................... 7
3.2 Laboratory Analysis and Quality Control ........................................................................... 7
3.3 Data Analyses ...................................................................................................................... 8
3.3.1 Analytical Results for Groundwater ........................................................................ 8
3.3.1.1 Inorganic Analyses ............................................................................................................................................ 8
3.3.1.2 Organic Analyses .............................................................................................................................................. 9
3.3.1.3 Performance and Sentinel Wells ........................................................................................................................ 9
3.3.2 Analytical Results for Surface Water ...................................................................... 9
3.3.3 Statistical Analyses ............................................................................................... 10
3.3.3.1 Statistical Methods ............................................................................................................................................ 10
3.3.3.2 Results of Statistical Analyses ............................................................................................................................. 10
4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) .................. 10
4.1 MNA Parameters and Biodegradation Screening Matrix ................................................. 10
4.2 Trend Analysis and Plume Stability .................................................................................. 12
5.0 CONCLUSIONS .................................................................................................................. 12
6.0 REFERENCES .................................................................................................................... 12
7.0 ACRONYMS ....................................................................................................................... 14

FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2016
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
ii

TABLES:
Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters
Table 7 Biodegradation Screening Matrix

CHARTS:
Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

FIGURE:
Figure 1 Site Location Map (USGS Topographic Map)

DRAWING:
Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES:
Appendix A Field Sampling Logs
Appendix B Laboratory Reports with Chains of Custody
Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water
Appendix G Historical MNA Parameter Data

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
1

1.0 INTRODUCTION
On behalf of Granville County, Joyce Engineering, (JOYCE) has prepared this Water Quality
Monitoring Report for the Oxford Unit 1 Landfill, Solid Waste Permit Number
3901-CDLF-1997 (facility), in accordance with 15A NCAC 13B.1632 of the North Carolina
Solid Waste Management Rules (NCSWMR).

1.1 Site Background
The Oxford Landfill is located at 6584 Landfill Road, Oxford, Granville County, North Carolina,
near the town of Kinton Fork (Figure 1). The facility is owned and operated by Granville
County under Permit Number 3901-CDLF-1997, issued by the North Carolina Department of
Environment and Natural Resources (DENR) Solid Waste Section (SWS). The Oxford Landfill
consists of two separate waste disposal units. Unit 1 is a former unlined municipal solid waste
(MSW) landfill originally permitted for disposal of domestic, institutional, industrial,
agricultural, and demolition wastes, with an active C&D landfill on top. Unit 2 is a Subtitle-D
MSW landfill. Currently, the facility is disposing of construction and demolition (C&D) wastes
in Unit 1 on top of the closed MSW landfill in accordance with their Transition Plan dated 1994.
The permitted facility consists of approximately 283 acres, of which approximately 29 acres
constitutes the Unit 1 Landfill waste unit.

The groundwater monitoring network at the Unit 1 landfill consists of one upgradient well
(MW-7) and five downgradient wells (MW-2, MW-3R, MW-4R, MW-5R and MW-6R) as
shown on Drawing 1. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced
MW-3, MW-4, MW-5, and MW-6, respectively, in 1999, due to the close proximity to waste of
the original wells. Wells NES-1S&D and NES-2S&D were installed down-gradient of MW-4R
and MW-5R, respectively in May 2004 as part of the Nature and Extent Study (NES). The
Corrective Action Plan (CAP) dated April 23, 2009 designated NES-1S and NES-2S as
performance wells and NES-1D and NES-2D as sentinel wells. MW-7 replaced MW-1A as the
facility background well beginning with the first semiannual monitoring event of 2011. The
monitoring wells are screened within the uppermost aquifer underlying the facility. Well
construction details are summarized in Table 1.

In addition, there are two surface water sampling points, SW-1 and SW-2 associated with Unit 1.
Sampling point SW-1 is a sedimentation pond located near the southeast corner of the waste unit,
and is up-stream of waste. Sampling point SW-2 is a small creek located northeast of the waste
unit and is downstream of the waste unit. The locations of SW-1 and SW-2 are shown on
Drawing 1.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
2

1.2 Site Conceptual Model
1.2.1 Site Geology
The Oxford Unit 1 Landfill is located in the Carolina Slate Belt of the Piedmont Physiographic
Province of North Carolina. The geologic province is characterized by a rolling topography with
a thick mantle of saprolite overlying Late Proterozoic and Paleozoic igneous and metamorphic
bedrock. The Carolina Slate Belt is comprised of 550 to 650 million year old, metamorphosed
sedimentary and volcanic rocks, intruded by granitic rocks.

The Oxford Unit 1 Landfill is underlain by the Flat River Complex, which is a shallow intrusive
complex of granitic composition, which comprises a large portion of the northern Carolina Slate
Belt (Butler, 1991). The landfill is approximately 18 miles east of the Virgilina Synclinorium,
approximately 10 miles west of the Nutbush Creek Fault Zone, and approximately 4 miles
northwest of the Durham Basin (Butler, 1991).

Previous investigations discovered limited exposures in the borrow area of a competent, massive,
gray to greenish gray meta-volcanic rock that is moderately fractured with prominent fractures
with near vertical dips and striking approximately N25o to 30oW (Woodward-Clyde, 1994).
Boring logs indicate that the depth to bedrock at Oxford Unit 1 Landfill ranges from 5 to 30 feet
below ground surface. The overlying saprolite consists of brownish sandy to clayey silt
(Woodward-Clyde, 1994).

1.2.2 Site Hydrogeology
Groundwater in the Piedmont can occur in substantial volumes where soils and regolith are thick,
but groundwater is typically found in minimal volumes in bedrock, primarily restricted to
fractures. The water table under the area of investigation was encountered in the unconfined
aquifer that is mostly in the transition zone that consists of saprolite and highly fractured
bedrock. This unconfined aquifer is pervasive across the site and generally mimics the surface
topography. The saturated portion of the uppermost aquifer beneath the study area is vertically
continuous to bedrock, and no confining layers have been encountered during site investigations.
There is a high degree of connectivity between the saprolite and underlying fractured bedrock
such that they behave as a single continuous aquifer. Depth to water ranged from 5 to 10 feet
below grade in wells MW-4R, MW-6R, NES-2S, and NES-2D; and 10 to 25 feet below grade in
MW-1A, MW-2, MW-3R, MW-5R, MW-7, NES-1S, and NES-1D (Table 2). In general, the
water table is near the saprolite/bedrock interface.

Groundwater in the saprolite feeds the fractures in the bedrock and is discharged into creeks
north of the landfill. Groundwater flow at deeper levels within the fractured bedrock is
controlled by fractures. A groundwater potentiometric surface map, based on static water level
data obtained on February 18, 2016, is presented as Drawing 1. The groundwater map depicts
groundwater flow to the north.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
3

1.3 Aquifer Characteristics & Groundwater Flow Regime
Depth to groundwater is measured in all compliance monitoring wells at the site prior to each
sampling event. The groundwater elevations calculated relative to the surveyed measuring point
(top of casing) for each monitoring well are summarized in Table 2. The groundwater elevation
contours shown in Drawing 1 are based on data from the February 2016 sampling event.
Groundwater flow beneath the Unit 1 Landfill is primarily to the north. Horizontal groundwater
gradients were estimated from the February 2016 groundwater levels and are summarized in
Table 3. Horizontal gradients across the site ranged from 0.0145 to 0.0197 ft/ft. These values
are consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
following modified Darcy equation: V = Ki/n , where V = average linear velocity
(feet/year), K = hydraulic conductivity (feet/day), i = horizontal hydraulic gradient, and n =
effective porosity. The mean of hydraulic conductivities from slug-tests conducted in 1995,
1999 and 2004 (K = 4.36 ft/day) were used in these calculations, along with an estimated
effective porosity of 0.31 based on 85% of the average of laboratory-determined porosities for
site soil. The average estimated linear groundwater flow velocity under the facility was
calculated at 101.2 ft/year (Table 3). The linear velocity equation makes the simplifying
assumptions of a homogeneous and isotropic aquifer.

1.4 Monitoring History and Regulatory Status
1.4.1 Monitoring History
 1995: Oxford Unit 1 entered Assessment Monitoring due to detections of organic
constituents in several monitoring wells.
 1998: Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3,
MW-4, MW-5, and MW-6, respectively.
 2003: Assessment of Corrective Measures (ACM) and Nature and Extent Study (NES)
initiated due to 15A NCAC 2L.0202(NC-2L) Groundwater Standard exceedances of
benzene in MW-4R and vinyl chloride in MW-5R.
 May 2004: Nature and Extent wells NES-1S&D and NES-2S&D installed.
 May 2005: NES, ACM, & Risk Assessment submitted to DENR-SWS.
 August 21, 2006: ACM Public Meeting held in Oxford, NC.
 June 2008: Corrective Action Plan (CAP) submitted to DENR-SWS.
 December 2008: First Baseline sampling event for MNA
 March 2009: Final Revision of CAP submitted to DENR-SWS.
 April 23, 2009: CAP Approved by DENR-SWS.
 June 2010: Final Baseline sampling event for MNA.
 December 23, 2010: Request for Background Well Replacement approved by DENR-
SWS makes MW-7 (formerly P-2) the new site background monitoring well.
 January 27, 2011: Corrective Action Evaluation Report (CAER) reviewed and approved
by DENR-SWS with an updated list of constituents of concern (COCs), along with the

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
4

Alternate Source Demonstration (ASD) for Chromium, Thallium and TDS in MW-1A.
DENR-SWS denied the request to remove selected MNA parameters but allowed a
modified monitoring frequency (beginning June 2011).
 June 9, 2011: The ASD for Iron and Manganese approved by DENR-SWS.
 February 24, 2012: Beta-BHC added to COC list due to confirmed exceedance during
the December 2011 sampling event.
 June 3, 2014: DENR approved the following: Monitoring wells MW-2, MW-3R,
MW-4R, and MW-6R reverted back to detection monitoring (Appendix I) from assessment
monitoring (Appendix II). NES-1S and NES-1D were removed from the groundwater
corrective action monitoring network. Sampling for Monitored Natural Attenuation
parameters in monitoring wells MW-3R and MW-4R was discontinued.
 July 30, 2015: Corrective Action Evaluation Report (CAER) reviewed and approved by
DENR-SWS with an updated list of COCs, removing 1,1-dichloroethane and beta-BHC
from the COC list.

1.4.2 Regulatory Status
The Oxford Unit 1 Landfill has remained in Assessment Monitoring since 1995 due to detections
of organic constituents. There were NC-2L Standard exceedances of benzene in MW-4R in
2003, which have not been detected since, and there have been persistent NC-2L exceedances of
vinyl chloride in MW-5R from 2003 to present. The County received a letter from the SWS
dated August 20, 2003, that requested the County to proceed with assessment activities at Oxford
Unit 1 Landfill. A meeting between JOYCE and the SWS was held on February 11, 2004, to
discuss the SWS’s requirements for a Nature and Extent Study (NES) and an Assessment of
Corrective Measures (ACM). In May 2005, Granville County submitted a NES (JOYCE,
2005a), and an ACM (JOYCE, 2005b) and a Quantitative Risk Assessment (QRA) (JOYCE,
2005c) to the DENR in accordance with 15A NCAC 13B.1634. Granville County held a public
meeting for the ACM on August 21, 2006. A CAP was submitted in June 2008, with revisions in
October 2008 and March 2009 (JOYCE, 2009). The CAP proposed Monitored Natural
Attenuation (MNA) as the primary remedy, supplemented with Control of Decomposition
Gasses as a secondary remedy. The CAP was approved in a letter from DENR-SWS dated April
23, 2009. The gas interception trench proposed in the Control of Decomposition Gasses was
installed July 2009. The last sampling event for the Baseline MNA was completed in December
2010.

A Request for Background Well Replacement was submitted to the SWS October 25, 2010
because the background monitoring well, MW-1A, was dry or affected by low water levels and
excessive sediment as well as possible bore seal damage. The request proposed piezometer P-2
to be upgraded and re-named MW-7 to become the facility background monitoring well. DENR-
SWS approved the request on December 23, 2010. MW-7 became the background monitoring
well for the first semiannual sampling event of 2011.

An Alternate Source Demonstration for Iron and Manganese was submitted to the SWS October
26, 2010, after the requirements for additional constituent monitoring for C&D facilities showed

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
5

elevated concentrations of iron and manganese across multiple site wells in June 2010. The ASD
showed that the concentrations of iron and manganese were a result of natural occurrence in site
soil and not a release from the landfill. The ASD for Iron and Manganese was approved as
described by the SWS on June 9, 2011.

The first CAER was submitted to the SWS on November 29, 2010, and in a letter dated January
27, 2011, the SWS reviewed and approved the CAER. The SWS denied a request to remove
some of the MNA parameters made on behalf of the county, but did approve a reduced alternate
monitoring frequency as follows; carbon dioxide, ferrous iron, volatile fatty acids, total organic
carbon (TOC), sulfide, and dissolved ethane and ethane for every third year on a semiannual
basis. DENR-SWS also approved removing benzene and cis-1,2-dichloroethylene from the
COC list and adding 1,1-dichloroethane. As a result, the current COC list includes vinyl chloride
and 1,1-dichloroethane. The ASD for chromium, thallium, and total dissolved solids in MW-1A
was also approved. The Oxford Unit 1 landfill continues in Assessment Monitoring, with
additional C&D indicator parameters and selected MNA parameters and COC monitored at
designated wells at frequencies presented in the January 27, 2011 SWS review of the CAER and
ASD and summarized in the next section.

Beta-BHC was added to COC list due to confirmed exceedance during the December 2011
sampling event.

In a letter dated May 22, 2014 Joyce Engineering requested the following changes:
 Revert groundwater monitoring wells MW-2, MW-3R, MW-4R, and MW-6R from
assessment monitoring (Appendix II) to detection monitoring (Appendix I).
 Remove groundwater monitoring wells NES-1S and NES-1D from the groundwater
corrective action monitoring network.
 Discontinue sampling for Monitored Natural Attenuation parameters in groundwater
monitoring wells MW-3R and MW-4R.
The SWS granted approval of the changes in a letter dated June 3, 2014.

The second CAER was submitted to the SWS on July 10, 2015, and in a letter dated July 30, 2015,
the SWS reviewed and approved the CAER. The SWS approval included removal of
1,1-dichloroethane and beta-BHC from the COC list due to the lack of recent exceedances. This left
vinyl chloride as the only COC for the facility.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six groundwater monitoring wells comprise the compliance monitoring network at the Oxford
Unit 1 Landfill. The compliance network includes monitoring wells MW-7 (the current facility
background well), MW-2, MW-3R, MW-4R, MW-5R, and MW-6R. In addition, there is one
performance well (NES-2S) that is sampled under the Corrective Action Plan (CAP) for the

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
6

facility. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3, MW-4,
MW-5, and MW-6, respectively, in August 1999, due to the close proximity to waste of the
original wells. The former background well, MW-1, was abandoned in 2001 after being
damaged by a vehicle. MW-1A was replaced as the background monitoring well by MW-7 in
2011, as described in Section 1.4.2, above. MW-1A is still monitored for static water level.
Monitoring wells NES-2S, and NES-2D were installed as part of the NES in May 2004. The
following table summarizes the monitoring network and required analytical parameters for the
first semiannual sampling event of 2016:

Groundwater Monitoring Network
Monitoring
Well
Date
Installed Classification Monitoring
Program TD Lithology of Screened
Interval
1st SA Event
Analyses
2nd SA Event
Analyses
MW-1A unknown Observation Water
Level 28.77 Saprolite NS NS
MW-2 unknown Compliance Detection 29.34 Saprolite/Bedrock App. I, C&D App. I, C&D
MW-3R 8/25/99 Compliance Detection 27.12 Partially Weathered
Rock App. I, C&D App. I, C&D
MW-4R 8/26/99 Compliance Detection 63.22 Bedrock App. I, C&D App. I, C&D
MW-5R 8/25/99 Compliance Assessment 40.25 Bedrock App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
MW-6R 8/25/99 Compliance Detection 42.90 Bedrock App. I, C&D App. I, C&D
MW-7 7/28/08 Background Assessment 34.50 Partially Weathered
Rock
App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
NES-2S 5/11/04 Performance CAMP 21.5 Saprolite COC, MNA COC, MNA
NES-2D 5/11/04 Sentinel CAMP 66.5 Bedrock COC, MNA NS
App. I = NCSWMR Appendix I list of constituents. COC = Constituents of concern.
App. II = NCSWMR Appendix II list of constituents. MNA = Monitoring Natural Attenuation parameters.
App. I + Det. = App. I list plus detected App. II constituents. C&D = C&D indicator parameters.
NS = Not Sampled (After baseline period, sentinel wells are sampled annually).
CAMP = Corrective Action Monitoring Plan.

C&D indicator parameters: mercury, manganese, iron, sulfate, chloride, alkalinity, total
dissolved solids (TDS), temperature, pH, and specific conductance.

Current Appendix II detected constituents: mercury, sulfide, endosulfan I, and beta-
BHC.

Constituents of Concern: 1,1-dichloroethane, vinyl chloride, and beta-BHC.

MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen on a semiannual basis. Dissolved carbon dioxide,
and ferrous iron are sampled for both sampling events every third year.

MNA Laboratory Parameters: Dissolved hydrogen, dissolved methane, nitrate, sulfate,
chloride, alkalinity on a semiannual basis. Sulfide, TOC, ethane, ethene, and volatile
fatty acids are sampled for both sampling events every third year.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
7

2.2 Surface Water Monitoring Program
There are two surface water sampling points, SW-1 and SW-2 associated with the Unit 1 landfill.
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upgradient of the waste. Sampling point SW-2 is located northeast of the waste unit along a
tributary of Little Grassy Creek, down-gradient of the waste. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015
3.1 Field Work
On February 17-18, 2016, JOYCE personnel visited Oxford Unit 1 Landfill to purge and sample
monitoring wells MW-7, MW-2, MW-3R, MW-4R, MW-5R, MW-6R, and NES-2S, collect
samples from surface points SW-1 and SW-2, and obtain a water level for MW-1A.

Monitoring wells were purged and sampled using a 12 volt submersible pump or disposable
bailers. Field measurements of temperature, pH, specific conductivity, and turbidity were
recorded in a field log for all wells and surface water points. For selected wells, additional MNA
field parameters were also measured and recorded. Prior to sampling, laboratory-supplied
containers were prepared with the following information:
 Monitoring well ID (completed by laboratory or field personnel);
 Date and time of sample collection (completed by field personnel);
 Initials of sampling personnel (completed by field personnel);
 Project name and number (completed by the laboratory or field personnel);
 Chemical preservative (completed by the laboratory or field personnel); and
 Requested chemical analysis (completed by the laboratory or field personnel).

Groundwater samples from each monitoring well were collected either immediately after purging
or within 24 hours of the final purge volume and were dispensed directly from the pump flow or
bailers into the provided laboratory containers. Immediately after collection, the samples were
placed in a laboratory provided cooler and chilled on ice. Field sampling logs are provided in
Appendix A.

Surface water point SW-1 and SW-2 were sampled using a decontaminated graduated dipper.
Surface point SW-2 was dry and not sampled. Prepared sampling containers were filled from the
dipper, placed in a cooler, and chilled on ice. Field sampling logs are provided in Appendix A.

3.2 Laboratory Analysis and Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina analyzed the February 2016
groundwater and surface water samples under chain-of-custody control. Groundwater samples
from the compliance wells were analyzed for the parameters summarized in Section 2.1. The
surface water samples were analyzed for NC Appendix I constituents. The samples were

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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8

received by the laboratory February 19, 2016, in good condition, properly preserved, at proper
temperatures, and within analysis hold times.

In addition to samples collected for compliance monitoring at the Oxford Unit 1 Landfill,
JOYCE personnel collected a Field Blank as part of the February 2016 sampling event. The
Field Blank was analyzed for the NC Appendix I plus previously detected Appendix II
constituents, plus iron, manganese and tetrahydrofuran. Also, a Trip Blank that was prepared by
the laboratory accompanied the volatile sampling containers to and from the laboratory. The
Trip Blank was analyzed for the NC Appendix II list of volatile organic compounds and
tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2L (NC-2L) Groundwater Standards or DENR Solid Waste
Section Groundwater Water Protection Standards (GWPS), or 15A NCAC 2B (NC-2B)
Surface Water Standards; and
 Detections above historical levels.

The complete laboratory analytical packages and chains of custody for the February 2016
sampling event are included in Appendix B. Historical data tables are included in Appendices C,
D, E, F, and G.

3.3 Data Analyses
3.3.1 Analytical Results for Groundwater
3.3.1.1 Inorganic Analyses
Inorganic constituents detected at quantified concentrations above the NCDEQ Solid Waste
Section (SWS) report limits (SWSL) in one or monitoring wells during the February 2016 event
include: iron, manganese, alkalinity, chloride, zinc and TDS. A summary of all constituents
with quantified detections for the February 2016 event is presented as Table 4. The laboratory
analytical reports, the laboratory quality assurance/quality control information, and the chains of
custody, are included in the Appendix B. Complete historical analytical results for inorganic
constituents are presented in Appendix C.

Iron, and manganese were the only inorganic constituents detected at quantified concentrations
above their NC 2L or GWPS in one or more monitoring well samples. Iron and manganese were
shown to be naturally occurring in an ASD approved by the NCDEQ-SWS on June 9, 2011. The

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
9

cobalt detection in MW-2 was below the statistical background for cobalt (see Section 3.3.3);
therefore, it is not considered an exceedance of Groundwater Protection Standard (GPS) as
defined in 15A NCAC 13B.1634.g.

3.3.1.2 Organic Analyses
The only organic constituent detected at a quantified concentration above the SWSL during the
February 2016 sampling event was vinyl chloride in MW-5R. Vinyl chloride in MW-5R was
also above the NC 2L Standard, and therefore is in exceedance of the Groundwater Protection
Standard (GPS) as defined in 15A NCAC 13B.1634.g. There were no other quantified detections
or exceedances for organic constituents.

A summary of all constituents with quantified detections for the February 2016 event is
presented as Table 4, and a summary of groundwater and surface water exceedances for the
February 2016 event is presented as Table 5. The laboratory analytical reports, the laboratory
quality assurance/quality control information, and the chains of custody, are included in the
Appendix B. Complete historical analytical results for organic constituents are presented in
Appendix D.

3.3.1.3 Performance and Sentinel Wells
Corrective action performance well (NES-2S) was sampled for the contaminants of concern
(COCs) list approved by the SWS and for MNA parameters. No COCs were detected above the
SWSL, and therefore there were no GPS exceedances in samples from the performance well. A
summary of historical detections of COCs in performance and sentinel wells for the facility is
provided in Appendix E.

3.3.2 Analytical Results for Surface Water
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upgradient of the waste. Sampling point SW-2 is located northeast of the waste unit along
a tributary of Little Grassy Creek, down-gradient of the waste.

Surface water analytical results from the site were compared to the 15A-NCAC-2B (NC 2B)
surface water standards for protection of fresh-water aquatic life or human health, whichever is
lower (more protective) for a given constituent. Zinc was detected in both SW-1 and SW-2 above
the SWSL but did not exceed the NC 2B value. There were no other constituents detected at
quantified concentrations above the SWSL in SW-1 or SW-2 during the February 2016 sampling
event. There were no NC 2B exceedances during the February 2016 sampling event.

The analytical results from the February 2016 surface water sampling event at the Oxford Unit 1
Landfill are presented along with historical data in Appendix F. The laboratory analytical
reports, the laboratory quality assurance/quality control information, and the chain of custody,
are included in Appendix B.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
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3.3.3 Statistical Analyses
3.3.3.1 Statistical Methods
Monitoring well MW-1A was designated as the background well for the facility until the first
semiannual sampling of 2011. Prior to the spring 2001 sampling event, the site had two
background wells, MW-1 and MW-1A. MW-1 was damaged by a vehicle and, with the approval
of DENR, was abandoned in early 2001. MW-1A was affected by low water levels and impact
from high turbidity levels during more recent events, and was therefore approved to be replaced
by MW-7 as the background for the first semiannual sampling event of 2011. Data from MW-1
between September 1994 and October 2000, data from MW-1A from September 1994 to June
2010 and data from MW-7 from June 2011 to present have been used to determine statistical
background concentrations for inorganic constituents detected at the facility in exceedance of
their respective NC-2L or GWPS.

The background data for inorganic constituents are evaluated in accordance with the procedures
outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentrations
exceeded the facility background concentrations using the Shapiro-Wilk Test, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric
Prediction Limits, and Poisson Prediction Limits as appropriate. Background data, tests for
normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are used, as
appropriate based on the background data. The statistical test by which downgradient data are
compared to facility background data is based upon the nature of the data and the number of data
values that are less than the laboratory limit of detection. All statistical tests are evaluated at the
0.05 level of significance, 95% confidence level, and are conducted as one-tailed tests.

3.3.3.2 Results of Statistical Analyses
Iron and manganese were detected in several wells at concentrations above the NC-2L standard
in the February 2016 samples. Iron and manganese were shown to be naturally occurring in an
ASD approved by the DENR-SWS on June 9, 2011.

There were no other quantified detections of any inorganic constituents above the SWSL in any
groundwater samples from the February 2016 event.

4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
4.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the
December 2008 sampling event. The June 2010 sampling event was the fourth and final baseline
sampling event for MNA. MNA sampling was continued in accordance with the modified
sampling frequency approved by DENR-SWS on January 27, 2011.

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11

During the February 2016 sampling event, the MNA parameters were obtained for the following
wells: background well MW-7, downgradient compliance well MW-5R; and performance well
NES-2S. MNA parameters included field parameters temperature, pH, specific conductance,
oxidation reduction potential, turbidity, dissolved oxygen, as well as laboratory parameters
dissolved hydrogen, nitrate, sulfate, chloride, alkalinity, sulfide, and methane. In addition, the
performance well (NES-2S) was sampled and analyzed for the COC vinyl chloride. Field
parameter data for the February 2016 event are summarized in Table 6. Field data logs and
laboratory reports are included in Appendices A and B, respectively. The MNA parameter data
from the February 2016 event, as well as historical MNA data, are presented in Appendix G.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to
determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 19
indicates that there is adequate evidence for anaerobic natural attenuation, and a score of 20 or
more indicates that there is strong evidence that anaerobic natural attenuation is occurring.

The evaluation was performed for data from MW-5R based on the results from the February
2016 sampling event. The Biodegradation Screening Matrix is presented in Table 7 of this
report. One aspect of the scoring process is ambiguous with respect to how it should be applied
to a landfill site such as this facility, and that is the issue of daughter products. Methane, carbon
dioxide (CO2), cis-1,2-dichloroethylene, vinyl chloride, and 1,1-dichlroethane can all be
daughter products produced by the biodegradation of higher-order chlorinated ethanes and
ethenes, and as such, their presence can be strong indicators that biodegradation is occurring, and
are therefore included in the EPA scoring matrix. On the other hand, methane and CO2 are gases
produced by the natural metabolization of biomass by microorganisms in a landfill, and cis-1,2-
dichloroethylene, vinyl chloride, and 1,1-dichloroethane can be primary contaminants leached
from waste in landfills. Some of these compounds are present in the groundwater plume;
however, it is unclear whether or not they are daughter products indicating natural attenuation.
For this reason, the score for MW-5R has been calculated both with and without the points for
daughter products.

The following table summarizes the scoring results from Table 7 for both options for interpreting
the data. The scores ranged from 9 to 17 (limited evidence of natural attenuation to adequate
evidence of natural attenuation). In reality, the best score is probably in the middle of this range.

Points Awarded
including DP’s
Points Awarded
excluding DP’s
17 9
DP’s = Points for possible daughter products.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
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4.2 Trend Analysis and Plume Stability
Chart 1 shows the concentration of vinyl chloride (VC) versus time for MW-5 and MW-5R from
June 1994 through February 2016. Similarly, Chart 2 shows the 1,1-dichloroethane (1,1-DCA)
concentration versus time for the same time period and the same wells. Both charts include best-
fit trend lines through the MW-5R data and both display decreasing trends. These data show that
the plume is generally stable and/or decreasing, and that natural attenuation is adequately
controlling the plume.

5.0 CONCLUSIONS
Iron and manganese were again detected in several wells at concentrations above the NC-2L
standard in the February 2016 samples; however, an ASD showing that iron and manganese are
naturally occurring was approved by DENR-SWS. There were no other quantified detections
above the NC-2L or GWPS of any inorganic constituents in any downgradient wells during the
February 2016 event.

Vinyl chloride was detected in MW-5R in exceedance of its NC-2L Standard during the August
2015 sampling, which is consistent with historical data. There were no other exceedances for
organic constituents. Overall, the organic detections are consistent with historical data from the
site and indicate decreasing trends. MNA data continues to indicate some evidence that natural
attenuation is occurring in the vicinity of MW-5R. There have been downward trends for all
VOCs included the only remaining COC, vinyl chloride, indicating that natural attenuation is
adequately controlling the plume.

The groundwater flow regime is consistent with previous data and the groundwater monitoring
system remains adequate for monitoring the site. The next semiannual sampling event is
tentatively scheduled for August 2016.

6.0 REFERENCES
The references cited herein were used to prepare this document and may or may not be cited in
the text of this report.

Butler, J. Robert, and Secor, Jr., Donald T., 1991, The Central Piedmont, in Horton, J. W., Jr.,
and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press,
p. 59-78.

Cowie, S. (2004). Emission of Non-methane Organic Compounds (NMOCs) and hazardous air
Pollutants (HAPs) from Decomposing Refuse and Individual Waste Components and
Under Different Conditions. Master’s Thesis, North Carolina State University.

Deisper, A. and Stegmann, R. (1994). The Origin and Fate of Volatile Trace Components in
Municipal Solid Waste Landfills. Waste Management & Research. v. 12, p. 129-139.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
13

Joyce Engineering, (JOYCE), 2005a. Nature and Extent Study, Granville County Oxford
Landfill. May 2005.

JOYCE, 2005b. Assessment of Corrective Measures, Granville County Oxford Landfill. May
2005.

JOYCE, 2005c. Quantitative Risk Assessment, Granville County Oxford Landfill. May 2005.

JOYCE, 2009. Corrective Action Plan, Granville County Oxford Landfill. March 2009.

JOYCE, 2010a. Request for Background Well Replacement, Granville County Oxford Landfill,
Permit # 39-01. October 25, 2010.

JOYCE, 2010b. Alternate Source Demonstration for Iron and Manganese, Granville County
Oxford C&D Over MSW Landfill, Permit # 39-01. October 26, 2010.

JOYCE, 2010c. Corrective Action Evaluation Report and Alternate Source
Demonstrations,Granville County Oxford C&D Over MSW Landfill, Permit # 39-01.
November 29, 2010.

JOYCE, 2011. Second Semiannual Water Quality Report of 2010, Oxford Landfill, Granville
County, Permit Number 39-01. May 2011.

North Carolina Department of Environment, Health, and Natural Resources, 1997. North
Carolina Solid Waste Management Rules. 15 NCAC 13B.1600. January 1, 1997.

North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina
Department of Natural Resources and Community Development, scale 1:500000.

NRC, 2000. Natural Attenuation for Groundwater Remediation. National Academy Press,
Washington, D.C. pp. 108-111.

USEPA, 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents
in Groundwater. ORD, EPA/600/R-98/128. September 1998.

USEAP, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities,
Addendum to Interim Final Guidance. July 1992.

Woodward-Clyde Consultants, 1994. Transition Plan, Oxford Landfill Granville County, North
Carolina. April 1994.

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
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7.0 ACRONYMS
ACM Assessment of Corrective Measures (report)
AOC Area of Concern
ASD Alternate Source Demonstration (report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (report)
CAER Corrective Action Evaluation Report (report)
CPVC Chlorinated Poly Vinyl Chloride
CO2 Carbon Dioxide
COC Contaminant of Concern
DCA Dichloroethane
DCE Dichloroethylene
DENR North Carolina Department of Environment and Natural Resources
DH Dissolved Hydrogen
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
Fe2+ Ferrous Iron
GEU Gas Extraction Unit
GWPS Groundwater Protection Standards
HASP Site-specific Health and Safety Plan
HDPE High-density Polyethylene
JE Joyce Engineering
JOYCE Joyce Engineering
LFG Landfill Gas
LEL Lower Explosive Limit
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC-2B North Carolina Surface Water Standards found in 15A NCAC 2B.0101
NC-2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202
NCAC North Carolina Administrative Code
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (report)
O&M Operations and Maintenance
ORP Oxidation-Reduction Potential
OSHA Occupational Health and Safety Association
PCE perchloroethylene (aka – tetrachloroethylene)
PVC Poly Vinyl Chloride
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (report)
RL Reporting Limit (for laboratory data)
SC Specific Conductance

First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 April 2016
15

SSI Statistically Significant Increase (over background concentration)
SWQS Surface Water Quality Standards
SWS DENR Division of Waste Management, Solid Waste Section
SWSL North Carolina Solid Waste Section Reporting Limits (for laboratory data)
TCE Trichloroethylene
TDS Total Dissolved Solids
TOC Total Organic Carbon
TSS Total Suspended Solids
VC Vinyl Chloride
VFA Volatile Fatty Acid
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (report)

TABLES

Table 1 Monitoring Well Construction Data Table 2 Historical Groundwater Elevation Data Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters Table 7 Biodegradation Screening Matrix

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Joyce Engineering
TABLE 2: Histroical Groundwater Elevation Data
Background
Well ID:MW-1 MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Well TOC Elev.:121.46 538.18 534.24 518.62 503.82 507.34 489.95 506.81 516.93 516.62 477.20 477.43
Well Total Depth:28.77 34.50 29.34 31.63 63.22 40.25 42.90 36.10 57.75 24.20 69.20
10-Sep-99 101.71 517.91 -507.76 481.40 493.62 467.65 496.53 ----
16-Nov-99 105.76 522.86 -506.32 483.55 494.83 468.75 498.24 ----
10-May-00 109.47 527.66 -507.89 487.20 499.63 470.65 500.59 ----
26-Oct-00 103.54 518.89 -504.12 480.86 495.21 467.39 496.95 ----
18-Apr-01 107.87 526.23 -508.01 486.62 498.50 470.79 500.21 ----
27-Oct-01 -514.65 -501.42 478.79 494.79 466.70 494.92 ----
10-Jun-02 -515.06 -502.91 480.10 495.19 467.06 496.26 ----
19-Nov-02 -518.61 -512.08 489.84 498.82 471.80 498.70 ----
27-Jun-03 -529.42 -508.76 488.69 500.79 471.72 501.38 ----
29-Dec-03 -528.91 -509.06 488.06 499.94 471.10 501.21 ----
29-Jun-04 -520.03 -505.24 481.10 497.84 467.72 499.21 ----
28-Dec-04 -526.73 -509.09 485.27 499.14 469.51 500.76 ----
29-Jun-05 -520.37 -504.64 481.10 497.60 467.63 499.15 ----
29-Dec-05 -519.54 -509.66 482.69 498.33 468.57 499.25 ----
27-Jun-06 -517.93 -507.85 481.85 497.64 468.00 498.63 ----
27-Dec-06 -523.00 -511.07 489.81 499.43 471.76 500.83 493.70 -469.82 -
12-Jul-07 -516.94 -502.49 479.84 497.17 467.18 497.59 ----
18-Dec-07 -510.35 -501.46 477.54 495.40 464.09 493.14 ----
7-Jul-08 -515.96 -501.99 479.52 497.04 466.79 496.71 ----
16-Dec-08 -532.53 -509.80 487.98 498.08 470.11 499.29 489.19 488.63 469.47 472.71
7-Jul-09 -518.28 -505.37 481.57 497.43 467.88 499.36 490.38 490.07 467.73 470.91
14-Dec-09 -533.10 -511.89 491.93 500.61 473.65 501.48 494.70 493.21 470.98 467.14
22-Jun-10 -518.45 -506.72 485.92 499.94 469.67 499.68 493.47 493.07 468.97 471.53
13-Dec-10 -509.41 -507.89 482.82 498.20 467.87 496.65 488.89 -468.03 -
20-Jun-11 -515.17 513.91 504.60 482.72 499.96 467.76 498.63 492.11 491.51 468.03 474.35
5-Dec-11 -513.35 507.92 507.44 484.94 498.29 468.45 497.17 488.15 487.45 468.25 464.93
13-Jun-12 -514.08 513.48 507.48 485.36 499.29 468.04 498.85 487.08 490.33 468.81 467.64
12-Dec-12 -511.34 506.86 503.10 481.55 497.24 466.90 494.83 486.84 486.26 467.26 461.41
29-Apr-13 -515.88 513.26 509.38 485.47 500.82 469.60 501.15 492.31 491.64 470.45 455.26
5-Aug-13 -517.21 514.33 505.98 484.47 500.29 468.65 500.83 494.12 -469.29 -
25-Feb-14 -514.06 511.75 509.82 486.32 501.50 473.05 501.99 491.83 491.54 470.28 461.18
12-Aug-14 -519.34 511.98 507.52 485.44 499.25 468.90 499.30 491.92 491.41 470.29 460.31
11-Mar-15 -524.32 516.39 510.37 487.12 502.94 474.18 504.41 500.98 500.12 470.63 473.63
18-Aug-15 -516.53 512.39 503.47 482.97 500.94 466.45 498.81 492.38 -469.25 449.71
16-Feb-16 -526.03 515.79 510.07 486.93 501.84 475.45 503.66 500.23 -471.15 469.18
Notes:
TOC = top of casing. - = data not available.
Water levels are measured from TOC.MW-7 added to monitoring network in early 2011.
All elevations are in feet above mean sea level (ft-amsl).Prior to December 2012, the TOC elevation for MW-3R was 498.35 ft-amsl.
Downgradient Performance/Sentinel
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Joyce Engineering
TABLE 3: Groundwater Gradients and Calculated Flow Rates
Date of Water Table Measurements:
SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR
FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY
DIRECTION GW ELEVATION i K n e V
(feet-AMSL)(ft/ft) (ft/day)(ft/year)
505
490
505
465
Average 0.0197 Average 101.20
Notes:
Linear flow velocity: V = Ki/n e (modified Darcy equation).
Hydraulic conductivity (K ) is based on the arithmetic mean of values from slug tests conducted at the facility.
Effective porosity (n e ) value is estimated at 85% of the laboratory-determined porosity for soil samples from the facility.
Refer to Drawing 1 for flow line segments.
74.69
February 17, 2016
0.31 101.204.36E+00
FLOW LINE
SEGMENT
SEGMENT
LENGTH
(feet)
i 2 2029 N 0.0197
i 1 1031 N 0.0145 4.36E+00 0.31
Granville Co. - Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
TABLE 4: Quantified Detections of Groundwater Constituents (February 2016)
NC2L/
GWPS*/NC2B**
3901-MW2 Iron 792 µg/L 300 300 2/18/2016
3901-MW2 Manganese 201 µg/L 50 50 2/18/2016
3901-MW2 Chloride 4600 µg/L -250000 2/18/2016
3901-MW2 Total Dissolved Solids 84000 µg/L -500000 2/18/2016
3901-MW3R Manganese 72.7 µg/L 50 50 2/18/2016
3901-MW3R Alkalinity, Total CaCO3 89800 µg/L 1000 2/18/2016
3901-MW3R Chloride 20600 µg/L -250000 2/18/2016
3901-MW3R Total Dissolved Solids 140000 µg/L -500000 2/18/2016
3901-MW4R Manganese 981.0 µg/L 50 50 2/18/2016
3901-MW4R Alkalinity, Total CaCO3 308000 µg/L 1000 2/18/2016
3901-MW4R Chloride 69500 µg/L -250000 2/18/2016
3901-MW4R Total Dissolved Solids 412000 µg/L -500000 2/18/2016
3901-MW5R Manganese 82.4 µg/L 50 50 2/18/2016
3901-MW5R Vinyl Chloride 5.4 µg/L 1 0.03 2/18/2016
3901-MW5R Alkalinity, Total CaCO3 141000 µg/L 1000 2/18/2016
3901-MW5R Chloride 49700 µg/L -250000 2/18/2016
3901-MW5R Total Dissolved Solids 237000 µg/L -500000 2/18/2016
COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater Constituents (February 2016)
NC2L/
GWPS*/NC2B**COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
3901-MW6R Iron 1500 µg/L 300 300 2/18/2016
3901-MW6R Manganese 1620 µg/L 50 50 2/18/2016
3901-MW6R Alkalinity, Total CaCO3 168000 µg/L 1000 2/18/2016
3901-MW6R Chloride 153000 µg/L -250000 2/18/2016
3901-MW6R Total Dissolved Solids 475000 µg/L -500000 2/18/2016
3901-MW7 Zinc 14.8 µg/L 10 1000 2/18/2016
3901-MW7 Alkalinity, Total CaCO3 108000 µg/L 1000 2/18/2016
3901-MW7 Chloride 17200 µg/L -250000 2/18/2016
3901-MW7 Total Dissolved Solids 162000 µg/L -500000 2/18/2016
3901-SW-1 Zinc 13 µg/L 10 50**2/18/2016
3901-SW-2 Zinc 11 µg/L 10 50**2/18/2016
NOTES:All Results in micorgrams per liter (µg/L)
MDL = Method Detection Limit
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
NC2B = NC Surface Water standards for fresh-water aquatic life from 15A-NCAC-2B
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
J = Estimated concentration below the MRL or SWSL
Bold values= Detections above the NC2L, GWPS, or NC2B stardards (see Table 5)
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 5: Exceedances of Groundwater Standards (February 2016)
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS GPS COLLECT DATE
3901-MW2 Iron 792 µg/L 300 300 300 2/18/2016
3901-MW2 Manganese 201 µg/L 50 50 50 2/18/2016
3901-MW3R Manganese 72.7 µg/L 50 50 50 2/18/2016
3901-MW4R Manganese 981.0 µg/L 50 50 50 2/18/2016
3901-MW5R Manganese 82.4 µg/L 50 50 50 2/18/2016
3901-MW5R Vinyl Chloride 5.4 µg/L 1 0.03 0.03 2/18/2016
3901-MW6R Iron 1500 µg/L 300 300 300 2/18/2016
3901-MW6R Manganese 1620 µg/L 50 50 50 2/18/2016
NOTES:All Results in micorgrams per liter (µg/L)
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)
GPS for antimony and cobalt are based on the statistical backgound for the facility.
Bold = GPS Exceedance.
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 6: Field Parameters (February 2016)
WELL ID PARAMETER RESULT UNITS DATE
3901-MW2 Conductivity 88.7 µS/cm 2/18/2016
3901-MW2 pH 6.56 S.U.2/18/2016
3901-MW2 Static Water Level 8.56 ft 2/18/2016
3901-MW2 Temperature 13.9 ºC 2/18/2016
3901-MW2 Turbidity 18.7 NTU 2/18/2016
3901-MW2 Well Depth 29.34 ft 2/18/2016
3901-MW3R Conductivity 220.8 µS/cm 2/18/2016
3901-MW3R pH 6.55 S.U.2/18/2016
3901-MW3R Static Water Level 16.89 ft 2/18/2016
3901-MW3R Temperature 14.2 ºC 2/18/2016
3901-MW3R Turbidity 13.5 NTU 2/18/2016
3901-MW3R Well Depth 31.63 ft 2/18/2016
3901-MW4R Conductivity 547.0 µS/cm 2/18/2016
3901-MW4R pH 6.36 S.U.2/18/2016
3901-MW4R Static Water Level 5.5 ft 2/18/2016
3901-MW4R Temperature 13.4 ºC 2/18/2016
3901-MW4R Turbidity 9.5 NTU 2/18/2016
3901-MW4R Well Depth 63.22 ft 2/18/2016
3901-MW5R Conductivity 311.6 µS/cm 2/18/2016
3901-MW5R Dissolved Oxygen 2.59 mg/l 2/18/2016
3901-MW5R Oxidation Reduction Potential 123.5 mV 2/18/2016
3901-MW5R pH 6.23 S.U.2/18/2016
3901-MW5R Static Water Level 14.50 ft 2/18/2016
3901-MW5R Temperature 12.5 ºC 2/18/2016
3901-MW5R Turbidity 10.75 NTU 2/18/2016
3901-MW5R Well Depth 40.25 ft 2/18/2016
3901-MW6R Conductivity 380.4 µS/cm 2/18/2016
3901-MW6R pH 5.69 S.U.2/18/2016
3901-MW6R Static Water Level 3.15 ft 2/18/2016
3901-MW6R Temperature 8.5 ºC 2/18/2016
3901-MW6R Turbidity 10.4 NTU 2/18/2016
3901-MW6R Well Depth 42.90 ft 2/18/2016
3901-MW7 Conductivity 250.0 µS/cm 2/18/2016
3901-MW7 Dissolved Oxygen 3.51 mg/l 2/18/2016
3901-MW7 Oxidation Reduction Potential 104.2 mV 2/18/2016
3901-MW7 pH 6.89 S.U.2/18/2016
3901-MW7 Static Water Level 18.45 ft 2/18/2016
3901-MW7 Temperature 12.8 ºC 2/18/2016
3901-MW7 Turbidity 8.25 NTU 2/18/2016
3901-MW7 Well Depth 37.32 ft 2/18/2016
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 1 of 2 Joyce Engineering
TABLE 6: Field Parameters (February 2016)
WELL ID PARAMETER RESULT UNITS DATE
3901-NES2S Conductivity 95.7 µS/cm 2/18/2016
3901-NES2S Dissolved Oxygen 2.54 mg/l 2/18/2016
3901-NES2S Oxidation Reduction Potential 105.7 mV 2/18/2016
3901-NES2S pH 6.13 S.U.2/18/2016
3901-NES2S Static Water Level 6.05 ft 2/18/2016
3901-NES2S Temperature 11.3 ºC 2/18/2016
3901-NES2S Turbidity 8.55 NTU 2/18/2016
3901-NES2S Well Depth 24.20 ft 2/18/2016
3901-NES2D Conductivity 293.9 µS/cm 2/18/2016
3901-NES2D Dissolved Oxygen 7.07 mg/l 2/18/2016
3901-NES2D Oxidation Reduction Potential 52.9 mV 2/18/2016
3901-NES2D pH 6.52 S.U.2/18/2016
3901-NES2D Static Water Level 8.25 ft 2/18/2016
3901-NES2D Temperature 14.1 ºC 2/18/2016
3901-NES2D Turbidity 7.75 NTU 2/18/2016
3901-NES2D Well Depth 69.5 ft 2/18/2016
3901-SW1 Conductivity 140 µS/cm 2/17/2016
3901-SW1 pH 6.95 S.U.2/17/2016
3901-SW1 Temperature 15.2 ºC 2/17/2016
3901-SW1 Turbidity 300 NTU 2/17/2016
3901-SW2 Conductivity 71.9 µS/cm 2/17/2016
3901-SW2 pH 7.12 S.U.2/17/2016
3901-SW2 Temperature 10.5 ºC 2/17/2016
3901-SW2 Turbidity 750 NTU 2/17/2016
Notes:ºC= degrees Centigrade µS/cm = microSemens per centimeter
S.U.= Standard Units NTU = Nephelometric Turbidity Units
ft = feet
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 2 of 2 Joyce Engineering
TABLE 7: BIODEGRADATION SCREENING MATRIX (MW-5R)
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 0 0
pathway
Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide > 1 mg/L Reductive pathway possible 3 0 0
Methane < 0.5 mg/L Vinyl chloride oxidizes 0 0 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1 0 0
Potential < -100 mV Reductive pathway likely 2 0 0
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2 0 0
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 2 2
be natural or anthropogenic
Temperature >20o C At T > 20oC biochemical process is accelerated 1 0 0
Carbon Dioxide > 2x background Ultimate oxidative daughter product 1
Alkalinity > 2x background Results from interaction between CO2 and 1 0 0
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0 0 0
Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE)---Material released 0 0 0
Trichloroethene (TCE)---Material released 0 0 0
---Daughter product of PCE 2 0 0
Dichloroethenes (DCE)---Material released 0 0
Daughter product of TCE 2 2
Dichloroethene, cis-1,2,---Material released 0 0
---Daughter product of trichlorethene 2 2
Vinyl Chloride (VC)---Material released 0 0
---Daughter product of DCE 2 2
1,1,1-Trichloroethane (TCA)---Material released 0 0 0
1,1-Dichloroethane (DCA)---Material released 0 0
Daughter product of TCA 2 2
Chloroethane ---Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 0 0
Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2
> 0.1 mg/L 3 0 0
Chloroform ---Material released 0 0 0
---Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC)---Material released 0 0 0
(Methylene Chloride)---Daughter product of chloroform 2 0 0
Based on data collected in August 2014.Total Points Awarded:17 9
mg/L = miligrams per liter
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes
SCORE:Evid. of Nat. Atten.
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate
in Groundwater, September 1988.> 20 strong
Granville County - Oxford Landfill Permit 3901-CDLF-1997 Joyce Engineering

CHARTS
(Reference Section 4.2)

Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

Granville Co., Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
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(
µ
g
/
L
)
CHART 1: Vinyl Chloride vs. Time in MW-5 & MW-5R
MW-5
MW-5R
Linear (MW-5R)
NC 2L Standard for Vinyl Chloride:
Prior to February 2010 = 0.015 µg/L
Feb. 2010 to Present = 0.03 µg/L
Granville Co., Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
0
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(
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g
/
L
)
CHART 2: 1,1-Dichloroethane vs. Time in MW-5 & MW-5R
MW-5
MW-5R
Linear (MW-5R)
NC 2L Standard for 1,1-Dichloroethane:
Prior to February 2010 = 70 µg/L
Feb. 2010 to Present = 6 µg/L

FIGURE

Figure 1 Site Location Map (USGS Topographic Map)

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES

Appendix A Field Sampling Logs Appendix B Laboratory Reports with Chains of Custody Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water Appendix G Historical MNA Parameter Data

Appendix A

Field Sampling Logs

Appendix B

Laboratory Reports with Chains of Custody

#=CL#
March 04, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92287230
92287230
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD COMPLIANCE UNIT 1
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 19, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 78
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079
Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911
Mississippi Certification: FL NELAC ReciprocityMissouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710
North Dakota Certification #: R-216Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001
Tennessee Certification #: TN02974Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962CWisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 78
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Matrix Date Collected Date Received
92287230001 3901-MW7 Water 02/18/16 09:35 02/19/16 09:30
92287230002 3901-MW5R Water 02/18/16 10:26 02/19/16 09:30
92287230003 3901-FIELD BLANK Water 02/18/16 12:50 02/19/16 09:30
92287230004 3901-MW2 Water 02/18/16 08:47 02/19/16 09:30
92287230005 3901-MW3R Water 02/18/16 11:10 02/19/16 09:30
92287230006 3901-MW4R Water 02/18/16 09:11 02/19/16 09:30
92287230007 3901-MW6R Water 02/18/16 09:00 02/19/16 09:30
92287230008 3901-SW1 Water 02/17/16 16:17 02/19/16 09:30
92287230009 3901-SW2 Water 02/17/16 13:58 02/19/16 09:30
92287230010 3901-TRIP BLANK Water 02/16/16 08:00 02/19/16 09:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92287230001 3901-MW7 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92287230002 3901-MW5R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92287230003 3901-FIELD BLANK EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
SM 4500-S2D 1 PASI-AMJP
EPA 300.0 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 78
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 4500-Cl-E 1 PASI-AWRC
SM 4500-CN-E 1 PASI-AAES2
92287230004 3901-MW2 EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92287230005 3901-MW3R EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92287230006 3901-MW4R EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92287230007 3901-MW6R EPA 6010 17 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CNB
SM 2320B 1 PASI-AMLS
SM 2540C 1 PASI-ASAM
EPA 300.0 1 PASI-AMDW
SM 4500-Cl-E 1 PASI-AWRC
92287230008 3901-SW1 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92287230009 3901-SW2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CNB
92287230010 3901-TRIP BLANK EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92287230001 3901-MW7
Barium 4.4J ug/L 02/24/16 21:50100EPA 6010
Iron 243J ug/L 02/24/16 21:50300EPA 6010
Manganese 5.4J ug/L 02/24/16 21:5050.0EPA 6010
Zinc 14.8 ug/L 02/24/16 21:5010.0EPA 6010
Alkalinity, Total as CaCO3 108000 ug/L 02/25/16 16:595000SM 2320B
Total Dissolved Solids 162000 ug/L 02/22/16 15:5325000SM 2540C
Sulfate 39300J ug/L 02/22/16 19:58500000EPA 300.0
Chloride 17200 ug/L 02/25/16 20:161000SM 4500-Cl-E
92287230002 3901-MW5R
Barium 36.7J ug/L 02/24/16 21:59100EPA 6010
Iron 86.3J ug/L 02/24/16 21:59300EPA 6010
Manganese 82.4 ug/L 02/24/16 21:5950.0EPA 6010
Chlorobenzene 0.79J ug/L 02/23/16 07:203.0EPA 8260
1,2-Dichlorobenzene 1.0J ug/L 02/23/16 07:205.0EPA 8260
1,3-Dichlorobenzene 0.31J ug/L 02/23/16 07:205.0EPA 8260
1,4-Dichlorobenzene 0.92J ug/L 02/23/16 07:201.0EPA 8260
1,1-Dichloroethane 3.4J ug/L 02/23/16 07:205.0EPA 8260
cis-1,2-Dichloroethene 2.5J ug/L 02/23/16 07:205.0EPA 8260
Vinyl chloride 5.4 ug/L 02/23/16 07:201.0EPA 8260
Alkalinity, Total as CaCO3 141000 ug/L 02/25/16 17:125000SM 2320B
Total Dissolved Solids 237000 ug/L 02/22/16 15:5425000SM 2540C
Sulfate 3830J ug/L 02/22/16 20:38250000EPA 300.0
Chloride 49700 ug/L 02/25/16 20:163000SM 4500-Cl-E
92287230004 3901-MW2
Barium 12.1J ug/L 02/24/16 22:15100EPA 6010
Cobalt 7.5J ug/L 02/24/16 22:1510.0EPA 6010
Iron 792 ug/L 02/24/16 22:15300EPA 6010
Manganese 201 ug/L 02/24/16 22:1550.0EPA 6010
Alkalinity, Total as CaCO3 4350J ug/L 02/25/16 18:005000SM 2320B
Total Dissolved Solids 84000 ug/L 02/22/16 15:5525000SM 2540C
Sulfate 11200J ug/L 02/22/16 21:05250000EPA 300.0
Chloride 4600 ug/L 02/25/16 20:181000SM 4500-Cl-E
92287230005 3901-MW3R
Barium 15.7J ug/L 02/24/16 22:18100EPA 6010
Copper 3.6J ug/L 02/24/16 22:1810.0EPA 6010
Iron 270J ug/L 02/24/16 22:18300EPA 6010
Manganese 72.7 ug/L 02/24/16 22:1850.0EPA 6010
Nickel 3.2J ug/L 02/24/16 22:1850.0EPA 6010
Alkalinity, Total as CaCO3 89800 ug/L 02/25/16 18:095000SM 2320B
Total Dissolved Solids 140000 ug/L 02/22/16 15:5525000SM 2540C
Sulfate 7960J ug/L 02/22/16 21:19250000EPA 300.0
Chloride 20600 ug/L 02/25/16 20:192000SM 4500-Cl-E
92287230006 3901-MW4R
Barium 36.4J ug/L 02/24/16 22:21100EPA 6010
Iron 43.0J ug/L 02/24/16 22:21300EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 78
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92287230006 3901-MW4R
Manganese 981 ug/L 02/24/16 22:2150.0EPA 6010
Zinc 6.6J ug/L 02/24/16 22:2110.0EPA 6010
Alkalinity, Total as CaCO3 308000 ug/L 02/25/16 18:415000SM 2320B
Total Dissolved Solids 412000 ug/L 02/22/16 15:5625000SM 2540C
Sulfate 10300J ug/L 02/22/16 21:33250000EPA 300.0
Chloride 69500 ug/L 02/25/16 20:205000SM 4500-Cl-E
92287230007 3901-MW6R
Barium 98.2J ug/L 02/24/16 22:24100EPA 6010
Iron 1500 ug/L 02/24/16 22:24300EPA 6010
Manganese 1620 ug/L 02/24/16 22:2450.0EPA 6010
1,1-Dichloroethane 0.59J ug/L 02/23/16 08:435.0EPA 8260
cis-1,2-Dichloroethene 0.32J ug/L 02/23/16 08:435.0EPA 8260
Alkalinity, Total as CaCO3 168000 ug/L 02/25/16 18:565000SM 2320B
Total Dissolved Solids 475000 ug/L 02/22/16 15:5625000SM 2540C
Sulfate 3310J ug/L 02/22/16 22:13250000EPA 300.0
Chloride 153000 ug/L 02/25/16 20:215000SM 4500-Cl-E
92287230008 3901-SW1
Barium 58.2J ug/L 02/24/16 22:27100EPA 6010
Copper 6.3J ug/L 02/24/16 22:2710.0EPA 6010
Lead 4.0J ug/L 02/24/16 22:2710.0EPA 6010
Nickel 3.3J ug/L 02/24/16 22:2750.0EPA 6010
Vanadium 6.4J ug/L 02/24/16 22:2725.0EPA 6010
Zinc 13.0 ug/L 02/24/16 22:2710.0EPA 6010
92287230009 3901-SW2
Barium 55.0J ug/L 02/24/16 22:30100EPA 6010
Copper 5.7J ug/L 02/24/16 22:3010.0EPA 6010
Lead 2.6J ug/L 02/24/16 22:3010.0EPA 6010
Nickel 3.0J ug/L 02/24/16 22:3050.0EPA 6010
Vanadium 6.1J ug/L 02/24/16 22:3025.0EPA 6010
Zinc 11.0 ug/L 02/24/16 22:3010.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/25/16 23:08 309-00-202/20/16 11:350.050 0.050 1
alpha-BHC ND ug/L 02/25/16 23:08 319-84-602/20/16 11:350.050 0.050 1
beta-BHC ND ug/L 02/25/16 23:08 319-85-702/20/16 11:350.050 0.050 1
delta-BHC ND ug/L 02/25/16 23:08 319-86-802/20/16 11:350.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/25/16 23:08 58-89-902/20/16 11:350.050 0.050 1
Chlordane (Technical)ND ug/L 02/25/16 23:08 57-74-902/20/16 11:350.50 0.20 1
4,4'-DDD ND ug/L 02/25/16 23:08 72-54-802/20/16 11:350.10 0.050 1
4,4'-DDE ND ug/L 02/25/16 23:08 72-55-902/20/16 11:350.10 0.050 1
4,4'-DDT ND ug/L 02/25/16 23:08 50-29-302/20/16 11:350.10 0.050 1
Dieldrin ND ug/L 02/25/16 23:08 60-57-102/20/16 11:350.075 0.050 1
Endosulfan I ND ug/L 02/25/16 23:08 959-98-802/20/16 11:350.10 0.050 1
Endosulfan II ND ug/L 02/25/16 23:08 33213-65-902/20/16 11:350.10 0.050 1
Endosulfan sulfate ND ug/L 02/25/16 23:08 1031-07-802/20/16 11:350.10 0.050 1
Endrin ND ug/L 02/25/16 23:08 72-20-802/20/16 11:350.10 0.050 1
Endrin aldehyde ND ug/L 02/25/16 23:08 7421-93-402/20/16 11:350.10 0.050 1
Heptachlor ND ug/L 02/25/16 23:08 76-44-802/20/16 11:350.050 0.050 1
Heptachlor epoxide ND ug/L 02/25/16 23:08 1024-57-302/20/16 11:350.075 0.050 1
Methoxychlor ND ug/L 02/25/16 23:08 72-43-502/20/16 11:351.0 0.15 1
Toxaphene ND ug/L 02/25/16 23:08 8001-35-202/20/16 11:351.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)73 %02/25/16 23:08 877-09-802/20/16 11:3520-130 1
Decachlorobiphenyl (S)48 %02/25/16 23:08 2051-24-302/20/16 11:3520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/23/16 17:20 12674-11-202/20/16 11:350.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/23/16 17:20 11104-28-202/20/16 11:350.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/23/16 17:20 11141-16-502/20/16 11:350.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/23/16 17:20 53469-21-902/20/16 11:350.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/23/16 17:20 12672-29-602/20/16 11:350.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/23/16 17:20 11097-69-102/20/16 11:350.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/23/16 17:20 11096-82-502/20/16 11:350.50 0.50 1
Surrogates
Decachlorobiphenyl (S)43 %02/23/16 17:20 2051-24-302/20/16 11:3510-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/25/16 07:26 94-75-702/24/16 10:300.97 0.23 1
Dinoseb ND ug/L 02/25/16 07:26 88-85-702/24/16 10:300.19 0.059 1
2,4,5-T ND ug/L 02/25/16 07:26 93-76-502/24/16 10:300.20 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/25/16 07:26 93-72-102/24/16 10:300.20 0.050 1
Surrogates
2,4-DCAA (S)93 %02/25/16 07:26 19719-28-902/24/16 10:3036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 21:50 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 21:50 7440-38-202/22/16 16:3010.0 2.5 1
Barium 4.4J ug/L 02/24/16 21:50 7440-39-302/22/16 16:30100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 02/24/16 21:50 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 21:50 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 21:50 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 21:50 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 21:50 7440-50-802/22/16 16:3010.0 2.5 1
Iron 243J ug/L 02/24/16 21:50 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 21:50 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 5.4J ug/L 02/24/16 21:50 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 21:50 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 21:50 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 21:50 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 21:50 7440-28-002/22/16 16:305.5 5.0 1
Tin ND ug/L 02/24/16 21:50 7440-31-502/22/16 16:30100 2.5 1
Vanadium ND ug/L 02/24/16 21:50 7440-62-202/22/16 16:3025.0 2.5 1
Zinc 14.8 ug/L 02/24/16 21:50 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:41 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/24/16 20:08 83-32-902/24/16 10:1510.0 0.25 1
Acenaphthylene ND ug/L 02/24/16 20:08 208-96-802/24/16 10:1510.0 0.21 1
Acetophenone ND ug/L 02/24/16 20:08 98-86-202/24/16 10:1510.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/24/16 20:08 53-96-302/24/16 10:1520.0 0.84 1
4-Aminobiphenyl ND ug/L 02/24/16 20:08 92-67-102/24/16 10:1520.0 0.92 1
Anthracene ND ug/L 02/24/16 20:08 120-12-702/24/16 10:1510.0 0.14 1
Benzo(a)anthracene ND ug/L 02/24/16 20:08 56-55-302/24/16 10:1510.0 0.33 1
Benzo(a)pyrene ND ug/L 02/24/16 20:08 50-32-802/24/16 10:1510.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/24/16 20:08 205-99-202/24/16 10:1510.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/24/16 20:08 191-24-202/24/16 10:1510.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/24/16 20:08 207-08-902/24/16 10:1510.0 0.43 1
Benzyl alcohol ND ug/L 02/24/16 20:08 100-51-602/24/16 10:1520.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/24/16 20:08 101-55-302/24/16 10:1510.0 1.3 1
Butylbenzylphthalate ND ug/L 02/24/16 20:08 85-68-702/24/16 10:1510.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/24/16 20:08 59-50-702/24/16 10:1520.0 4.2 1
4-Chloroaniline ND ug/L 02/24/16 20:08 106-47-802/24/16 10:1520.0 3.4 1
Chlorobenzilate ND ug/L 02/24/16 20:08 510-15-602/24/16 10:1510.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/24/16 20:08 111-91-102/24/16 10:1510.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/24/16 20:08 111-44-402/24/16 10:1510.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/24/16 20:08 108-60-102/24/16 10:1510.0 1.6 1
2-Chloronaphthalene ND ug/L 02/24/16 20:08 91-58-702/24/16 10:1510.0 2.2 1
2-Chlorophenol ND ug/L 02/24/16 20:08 95-57-802/24/16 10:1510.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/24/16 20:08 7005-72-302/24/16 10:1510.0 2.1 1
Chrysene ND ug/L 02/24/16 20:08 218-01-902/24/16 10:1510.0 0.21 1
Diallate ND ug/L 02/24/16 20:08 2303-16-402/24/16 10:1510.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/24/16 20:08 53-70-302/24/16 10:1510.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 02/24/16 20:08 132-64-902/24/16 10:1510.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/24/16 20:08 91-94-102/24/16 10:1520.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/24/16 20:08 120-83-202/24/16 10:1510.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/24/16 20:08 87-65-002/24/16 10:1510.0 1.8 1
Diethylphthalate ND ug/L 02/24/16 20:08 84-66-202/24/16 10:156000 1.3 1
Dimethoate ND ug/L 02/24/16 20:08 60-51-502/24/16 10:1520.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/24/16 20:08 60-11-702/24/16 10:1510.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/24/16 20:08 57-97-602/24/16 10:1510.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/24/16 20:08 119-93-702/24/16 10:1510.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/24/16 20:08 105-67-902/24/16 10:1510.0 2.2 1
Dimethylphthalate ND ug/L 02/24/16 20:08 131-11-302/24/16 10:1510.0 1.5 1
Di-n-butylphthalate ND ug/L 02/24/16 20:08 84-74-202/24/16 10:1510.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/24/16 20:08 534-52-102/24/16 10:1550.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/24/16 20:08 99-65-002/24/16 10:1520.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/24/16 20:08 51-28-502/24/16 10:1550.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/24/16 20:08 121-14-202/24/16 10:1510.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/24/16 20:08 606-20-202/24/16 10:1510.0 1.7 1
Di-n-octylphthalate ND ug/L 02/24/16 20:08 117-84-002/24/16 10:1510.0 0.86 1
Diphenylamine ND ug/L 02/24/16 20:08 122-39-402/24/16 10:1510.0 1.3 1
Disulfoton ND ug/L 02/24/16 20:08 298-04-402/24/16 10:1510.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/24/16 20:08 117-81-702/24/16 10:1515.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/24/16 20:08 62-50-002/24/16 10:1520.0 1.8 1
Famphur ND ug/L 02/24/16 20:08 52-85-702/24/16 10:1520.0 1.7 1
Fluoranthene ND ug/L 02/24/16 20:08 206-44-002/24/16 10:1510.0 0.21 1
Fluorene ND ug/L 02/24/16 20:08 86-73-702/24/16 10:1510.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/24/16 20:08 87-68-302/24/16 10:1510.0 1.8 1
Hexachlorobenzene ND ug/L 02/24/16 20:08 118-74-102/24/16 10:1510.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/24/16 20:08 77-47-402/24/16 10:1510.0 1.8 1
Hexachloroethane ND ug/L 02/24/16 20:08 67-72-102/24/16 10:1510.0 1.5 1
Hexachloropropene ND ug/L 02/24/16 20:08 1888-71-702/24/16 10:1510.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/24/16 20:08 193-39-502/24/16 10:1510.0 0.29 1
Isodrin ND ug/L 02/24/16 20:08 465-73-602/24/16 10:1520.0 2.0 1
Isophorone ND ug/L 02/24/16 20:08 78-59-102/24/16 10:1510.0 1.8 1
Isosafrole ND ug/L 02/24/16 20:08 120-58-102/24/16 10:1510.0 1.8 1
Kepone ND ug/L 02/24/16 20:08 143-50-0 L202/24/16 10:1520.0 3.1 1
Methapyrilene ND ug/L 02/24/16 20:08 91-80-502/24/16 10:15100 2.7 1
3-Methylcholanthrene ND ug/L 02/24/16 20:08 56-49-502/24/16 10:1510.0 0.82 1
Methyl methanesulfonate ND ug/L 02/24/16 20:08 66-27-302/24/16 10:1510.0 1.3 1
2-Methylnaphthalene ND ug/L 02/24/16 20:08 91-57-602/24/16 10:1510.0 0.28 1
Methyl parathion ND ug/L 02/24/16 20:08 298-00-002/24/16 10:1510.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/24/16 20:08 95-48-702/24/16 10:1510.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/24/16 20:0802/24/16 10:1510.0 1.7 1
1-Naphthalenamine ND ug/L 02/24/16 20:08 134-32-702/24/16 10:1510.0 0.96 1
2-Naphthalenamine ND ug/L 02/24/16 20:08 91-59-802/24/16 10:1510.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/24/16 20:08 130-15-402/24/16 10:1510.0 1.8 1
2-Nitroaniline ND ug/L 02/24/16 20:08 88-74-402/24/16 10:1550.0 2.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3-Nitroaniline ND ug/L 02/24/16 20:08 99-09-202/24/16 10:1550.0 2.4 1
4-Nitroaniline ND ug/L 02/24/16 20:08 100-01-602/24/16 10:1520.0 2.5 1
Nitrobenzene ND ug/L 02/24/16 20:08 98-95-302/24/16 10:1510.0 1.7 1
2-Nitrophenol ND ug/L 02/24/16 20:08 88-75-502/24/16 10:1510.0 1.7 1
4-Nitrophenol ND ug/L 02/24/16 20:08 100-02-702/24/16 10:1550.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/24/16 20:08 99-55-802/24/16 10:1510.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/24/16 20:08 55-18-502/24/16 10:1520.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/24/16 20:08 62-75-902/24/16 10:1510.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/24/16 20:08 924-16-302/24/16 10:1510.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/24/16 20:08 621-64-702/24/16 10:1510.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/24/16 20:08 86-30-602/24/16 10:1510.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/24/16 20:08 10595-95-602/24/16 10:1510.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/24/16 20:08 100-75-402/24/16 10:1520.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/24/16 20:08 930-55-202/24/16 10:1510.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/24/16 20:08 126-68-102/24/16 10:1510.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/24/16 20:08 56-38-202/24/16 10:1510.0 1.1 1
Pentachlorobenzene ND ug/L 02/24/16 20:08 608-93-502/24/16 10:1510.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/24/16 20:08 82-68-802/24/16 10:1520.0 1.0 1
Pentachlorophenol ND ug/L 02/24/16 20:08 87-86-502/24/16 10:1525.0 2.3 1
Phenacetin ND ug/L 02/24/16 20:08 62-44-202/24/16 10:1520.0 0.97 1
Phenanthrene ND ug/L 02/24/16 20:08 85-01-802/24/16 10:1510.0 0.22 1
Phenol ND ug/L 02/24/16 20:08 108-95-202/24/16 10:1510.0 1.7 1
p-Phenylenediamine ND ug/L 02/24/16 20:08 106-50-302/24/16 10:1510.0 0.96 1
Phorate ND ug/L 02/24/16 20:08 298-02-202/24/16 10:1510.0 1.1 1
Pronamide ND ug/L 02/24/16 20:08 23950-58-502/24/16 10:1510.0 0.97 1
Pyrene ND ug/L 02/24/16 20:08 129-00-002/24/16 10:1510.0 0.19 1
Safrole ND ug/L 02/24/16 20:08 94-59-702/24/16 10:1510.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/24/16 20:08 95-94-302/24/16 10:1510.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/24/16 20:08 58-90-202/24/16 10:1510.0 2.3 1
Thionazin ND ug/L 02/24/16 20:08 297-97-202/24/16 10:1520.0 1.2 1
O-Toluidine ND ug/L 02/24/16 20:08 95-53-402/24/16 10:1510.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/24/16 20:08 95-95-402/24/16 10:1510.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/24/16 20:08 88-06-202/24/16 10:1510.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/24/16 20:08 99-35-402/24/16 10:1510.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)56 %02/24/16 20:08 4165-60-002/24/16 10:1521-110 1
2-Fluorobiphenyl (S)65 %02/24/16 20:08 321-60-802/24/16 10:1527-110 1
Terphenyl-d14 (S)90 %02/24/16 20:08 1718-51-002/24/16 10:1531-107 1
Phenol-d6 (S)21 %02/24/16 20:08 13127-88-302/24/16 10:1510-110 1
2-Fluorophenol (S)32 %02/24/16 20:08 367-12-402/24/16 10:1512-110 1
2,4,6-Tribromophenol (S)88 %02/24/16 20:08 118-79-602/24/16 10:1527-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 07:03 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/23/16 07:03 75-05-855.0 2.2 1
Acrolein ND ug/L 02/23/16 07:03 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/23/16 07:03 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/23/16 07:03 107-05-110.0 1.5 1
Benzene ND ug/L 02/23/16 07:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 07:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 07:03 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 07:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 07:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 07:03 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 07:03 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 07:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 07:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 07:03 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 07:03 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 07:03 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/23/16 07:03 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 07:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 07:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 07:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 07:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 07:03 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/23/16 07:03 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/23/16 07:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 07:03 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/23/16 07:03 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/23/16 07:03 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 07:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 07:03 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/23/16 07:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 07:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 07:03 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/23/16 07:03 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/23/16 07:03 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/23/16 07:03 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 07:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 07:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 07:03 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/23/16 07:03 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/23/16 07:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 07:03 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/23/16 07:03 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/23/16 07:03 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/23/16 07:03 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/23/16 07:03 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 07:03 108-10-1100 0.33 1
Naphthalene ND ug/L 02/23/16 07:03 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/23/16 07:03 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92287230001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/23/16 07:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 07:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 07:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 07:03 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 07:03 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 07:03 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/23/16 07:03 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/23/16 07:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 07:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 07:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 07:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 07:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 07:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 07:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 07:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 07:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/23/16 07:03 17060-07-070-130 1
Toluene-d8 (S)100 %02/23/16 07:03 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 108000 ug/L 02/25/16 16:595000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 162000 ug/L 02/22/16 15:5325000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/20/16 12:10 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 39300J ug/L 02/22/16 19:58 14808-79-8500000 2000 2
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 17200 ug/L 02/25/16 20:16 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/24/16 16:48 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/25/16 23:26 309-00-202/20/16 11:350.050 0.050 1
alpha-BHC ND ug/L 02/25/16 23:26 319-84-602/20/16 11:350.050 0.050 1
beta-BHC ND ug/L 02/25/16 23:26 319-85-702/20/16 11:350.050 0.050 1
delta-BHC ND ug/L 02/25/16 23:26 319-86-802/20/16 11:350.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/25/16 23:26 58-89-902/20/16 11:350.050 0.050 1
Chlordane (Technical)ND ug/L 02/25/16 23:26 57-74-902/20/16 11:350.50 0.20 1
4,4'-DDD ND ug/L 02/25/16 23:26 72-54-802/20/16 11:350.10 0.050 1
4,4'-DDE ND ug/L 02/25/16 23:26 72-55-902/20/16 11:350.10 0.050 1
4,4'-DDT ND ug/L 02/25/16 23:26 50-29-302/20/16 11:350.10 0.050 1
Dieldrin ND ug/L 02/25/16 23:26 60-57-102/20/16 11:350.075 0.050 1
Endosulfan I ND ug/L 02/25/16 23:26 959-98-802/20/16 11:350.10 0.050 1
Endosulfan II ND ug/L 02/25/16 23:26 33213-65-902/20/16 11:350.10 0.050 1
Endosulfan sulfate ND ug/L 02/25/16 23:26 1031-07-802/20/16 11:350.10 0.050 1
Endrin ND ug/L 02/25/16 23:26 72-20-802/20/16 11:350.10 0.050 1
Endrin aldehyde ND ug/L 02/25/16 23:26 7421-93-402/20/16 11:350.10 0.050 1
Heptachlor ND ug/L 02/25/16 23:26 76-44-802/20/16 11:350.050 0.050 1
Heptachlor epoxide ND ug/L 02/25/16 23:26 1024-57-302/20/16 11:350.075 0.050 1
Methoxychlor ND ug/L 02/25/16 23:26 72-43-502/20/16 11:351.0 0.15 1
Toxaphene ND ug/L 02/25/16 23:26 8001-35-202/20/16 11:351.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)102 %02/25/16 23:26 877-09-802/20/16 11:3520-130 1
Decachlorobiphenyl (S)80 %02/25/16 23:26 2051-24-302/20/16 11:3520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/23/16 17:40 12674-11-202/20/16 11:350.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/23/16 17:40 11104-28-202/20/16 11:350.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/23/16 17:40 11141-16-502/20/16 11:350.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/23/16 17:40 53469-21-902/20/16 11:350.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/23/16 17:40 12672-29-602/20/16 11:350.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/23/16 17:40 11097-69-102/20/16 11:350.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/23/16 17:40 11096-82-502/20/16 11:350.50 0.50 1
Surrogates
Decachlorobiphenyl (S)51 %02/23/16 17:40 2051-24-302/20/16 11:3510-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/25/16 07:57 94-75-702/24/16 10:300.96 0.23 1
2,4,5-T ND ug/L 02/25/16 07:57 93-76-502/24/16 10:300.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/25/16 07:57 93-72-102/24/16 10:300.19 0.050 1
Dinoseb ND ug/L 02/25/16 07:57 88-85-702/24/16 10:300.19 0.058 1
Surrogates
2,4-DCAA (S)98 %02/25/16 07:57 19719-28-902/24/16 10:3036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 21:59 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 21:59 7440-38-202/22/16 16:3010.0 2.5 1
Barium 36.7J ug/L 02/24/16 21:59 7440-39-302/22/16 16:30100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 02/24/16 21:59 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 21:59 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 21:59 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 21:59 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 21:59 7440-50-802/22/16 16:3010.0 2.5 1
Iron 86.3J ug/L 02/24/16 21:59 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 21:59 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 82.4 ug/L 02/24/16 21:59 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 21:59 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 21:59 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 21:59 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 21:59 7440-28-002/22/16 16:305.5 5.0 1
Tin ND ug/L 02/24/16 21:59 7440-31-502/22/16 16:30100 2.5 1
Vanadium ND ug/L 02/24/16 21:59 7440-62-202/22/16 16:3025.0 2.5 1
Zinc ND ug/L 02/24/16 21:59 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:43 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/26/16 14:39 83-32-902/25/16 13:2710.0 0.25 1
Acenaphthylene ND ug/L 02/26/16 14:39 208-96-802/25/16 13:2710.0 0.21 1
Acetophenone ND ug/L 02/26/16 14:39 98-86-202/25/16 13:2710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/26/16 14:39 53-96-302/25/16 13:2720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/26/16 14:39 92-67-102/25/16 13:2720.0 0.92 1
Anthracene ND ug/L 02/26/16 14:39 120-12-702/25/16 13:2710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/26/16 14:39 56-55-302/25/16 13:2710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/26/16 14:39 50-32-802/25/16 13:2710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/26/16 14:39 205-99-202/25/16 13:2710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/26/16 14:39 191-24-202/25/16 13:2710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/26/16 14:39 207-08-902/25/16 13:2710.0 0.43 1
Benzyl alcohol ND ug/L 02/26/16 14:39 100-51-602/25/16 13:2720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/26/16 14:39 101-55-302/25/16 13:2710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/26/16 14:39 85-68-702/25/16 13:2710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/26/16 14:39 59-50-702/25/16 13:2720.0 4.2 1
4-Chloroaniline ND ug/L 02/26/16 14:39 106-47-802/25/16 13:2720.0 3.4 1
Chlorobenzilate ND ug/L 02/26/16 14:39 510-15-602/25/16 13:2710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/26/16 14:39 111-91-102/25/16 13:2710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/26/16 14:39 111-44-402/25/16 13:2710.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/26/16 14:39 108-60-102/25/16 13:2710.0 1.6 1
2-Chloronaphthalene ND ug/L 02/26/16 14:39 91-58-702/25/16 13:2710.0 2.2 1
2-Chlorophenol ND ug/L 02/26/16 14:39 95-57-802/25/16 13:2710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/26/16 14:39 7005-72-302/25/16 13:2710.0 2.1 1
Chrysene ND ug/L 02/26/16 14:39 218-01-902/25/16 13:2710.0 0.21 1
Diallate ND ug/L 02/26/16 14:39 2303-16-402/25/16 13:2710.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/26/16 14:39 53-70-302/25/16 13:2710.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 02/26/16 14:39 132-64-902/25/16 13:2710.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/26/16 14:39 91-94-102/25/16 13:2720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/26/16 14:39 120-83-202/25/16 13:2710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/26/16 14:39 87-65-0 L202/25/16 13:2710.0 1.8 1
Diethylphthalate ND ug/L 02/26/16 14:39 84-66-202/25/16 13:276000 1.3 1
Dimethoate ND ug/L 02/26/16 14:39 60-51-502/25/16 13:2720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/26/16 14:39 60-11-702/25/16 13:2710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/26/16 14:39 57-97-602/25/16 13:2710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/26/16 14:39 119-93-702/25/16 13:2710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/26/16 14:39 105-67-902/25/16 13:2710.0 2.2 1
Dimethylphthalate ND ug/L 02/26/16 14:39 131-11-302/25/16 13:2710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/26/16 14:39 84-74-202/25/16 13:2710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/26/16 14:39 534-52-102/25/16 13:2750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/26/16 14:39 99-65-002/25/16 13:2720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/26/16 14:39 51-28-502/25/16 13:2750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/26/16 14:39 121-14-202/25/16 13:2710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/26/16 14:39 606-20-202/25/16 13:2710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/26/16 14:39 117-84-002/25/16 13:2710.0 0.86 1
Diphenylamine ND ug/L 02/26/16 14:39 122-39-402/25/16 13:2710.0 1.3 1
Disulfoton ND ug/L 02/26/16 14:39 298-04-402/25/16 13:2710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/26/16 14:39 117-81-702/25/16 13:2715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/26/16 14:39 62-50-002/25/16 13:2720.0 1.8 1
Famphur ND ug/L 02/26/16 14:39 52-85-702/25/16 13:2720.0 1.7 1
Fluoranthene ND ug/L 02/26/16 14:39 206-44-002/25/16 13:2710.0 0.21 1
Fluorene ND ug/L 02/26/16 14:39 86-73-702/25/16 13:2710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/26/16 14:39 87-68-302/25/16 13:2710.0 1.8 1
Hexachlorobenzene ND ug/L 02/26/16 14:39 118-74-102/25/16 13:2710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/26/16 14:39 77-47-402/25/16 13:2710.0 1.8 1
Hexachloroethane ND ug/L 02/26/16 14:39 67-72-102/25/16 13:2710.0 1.5 1
Hexachloropropene ND ug/L 02/26/16 14:39 1888-71-702/25/16 13:2710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/26/16 14:39 193-39-502/25/16 13:2710.0 0.29 1
Isodrin ND ug/L 02/26/16 14:39 465-73-602/25/16 13:2720.0 2.0 1
Isophorone ND ug/L 02/26/16 14:39 78-59-102/25/16 13:2710.0 1.8 1
Isosafrole ND ug/L 02/26/16 14:39 120-58-102/25/16 13:2710.0 1.8 1
Kepone ND ug/L 02/26/16 14:39 143-50-002/25/16 13:2720.0 3.1 1
Methapyrilene ND ug/L 02/26/16 14:39 91-80-502/25/16 13:27100 2.7 1
3-Methylcholanthrene ND ug/L 02/26/16 14:39 56-49-502/25/16 13:2710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/26/16 14:39 66-27-302/25/16 13:2710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/26/16 14:39 91-57-602/25/16 13:2710.0 0.28 1
Methyl parathion ND ug/L 02/26/16 14:39 298-00-002/25/16 13:2710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/26/16 14:39 95-48-702/25/16 13:2710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/26/16 14:39 L302/25/16 13:2710.0 1.7 1
1-Naphthalenamine ND ug/L 02/26/16 14:39 134-32-702/25/16 13:2710.0 0.96 1
2-Naphthalenamine ND ug/L 02/26/16 14:39 91-59-802/25/16 13:2710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/26/16 14:39 130-15-402/25/16 13:2710.0 1.8 1
2-Nitroaniline ND ug/L 02/26/16 14:39 88-74-402/25/16 13:2750.0 2.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3-Nitroaniline ND ug/L 02/26/16 14:39 99-09-202/25/16 13:2750.0 2.4 1
4-Nitroaniline ND ug/L 02/26/16 14:39 100-01-602/25/16 13:2720.0 2.5 1
Nitrobenzene ND ug/L 02/26/16 14:39 98-95-302/25/16 13:2710.0 1.7 1
2-Nitrophenol ND ug/L 02/26/16 14:39 88-75-502/25/16 13:2710.0 1.7 1
4-Nitrophenol ND ug/L 02/26/16 14:39 100-02-702/25/16 13:2750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/26/16 14:39 99-55-802/25/16 13:2710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/26/16 14:39 55-18-502/25/16 13:2720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/26/16 14:39 62-75-902/25/16 13:2710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/26/16 14:39 924-16-302/25/16 13:2710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/26/16 14:39 621-64-702/25/16 13:2710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/26/16 14:39 86-30-602/25/16 13:2710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/26/16 14:39 10595-95-602/25/16 13:2710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/26/16 14:39 100-75-402/25/16 13:2720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/26/16 14:39 930-55-202/25/16 13:2710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/26/16 14:39 126-68-1 L202/25/16 13:2710.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/26/16 14:39 56-38-202/25/16 13:2710.0 1.1 1
Pentachlorobenzene ND ug/L 02/26/16 14:39 608-93-502/25/16 13:2710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/26/16 14:39 82-68-802/25/16 13:2720.0 1.0 1
Pentachlorophenol ND ug/L 02/26/16 14:39 87-86-502/25/16 13:2725.0 2.3 1
Phenacetin ND ug/L 02/26/16 14:39 62-44-202/25/16 13:2720.0 0.97 1
Phenanthrene ND ug/L 02/26/16 14:39 85-01-802/25/16 13:2710.0 0.22 1
Phenol ND ug/L 02/26/16 14:39 108-95-202/25/16 13:2710.0 1.7 1
p-Phenylenediamine ND ug/L 02/26/16 14:39 106-50-302/25/16 13:2710.0 0.96 1
Phorate ND ug/L 02/26/16 14:39 298-02-202/25/16 13:2710.0 1.1 1
Pronamide ND ug/L 02/26/16 14:39 23950-58-502/25/16 13:2710.0 0.97 1
Pyrene ND ug/L 02/26/16 14:39 129-00-002/25/16 13:2710.0 0.19 1
Safrole ND ug/L 02/26/16 14:39 94-59-7 L202/25/16 13:2710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/26/16 14:39 95-94-302/25/16 13:2710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/26/16 14:39 58-90-202/25/16 13:2710.0 2.3 1
Thionazin ND ug/L 02/26/16 14:39 297-97-202/25/16 13:2720.0 1.2 1
O-Toluidine ND ug/L 02/26/16 14:39 95-53-402/25/16 13:2710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/26/16 14:39 95-95-402/25/16 13:2710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/26/16 14:39 88-06-202/25/16 13:2710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/26/16 14:39 99-35-402/25/16 13:2710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)52 %02/26/16 14:39 4165-60-002/25/16 13:2721-110 1
2-Fluorobiphenyl (S)53 %02/26/16 14:39 321-60-802/25/16 13:2727-110 1
Terphenyl-d14 (S)76 %02/26/16 14:39 1718-51-002/25/16 13:2731-107 1
Phenol-d6 (S)16 %02/26/16 14:39 13127-88-302/25/16 13:2710-110 1
2-Fluorophenol (S)24 %02/26/16 14:39 367-12-402/25/16 13:2712-110 1
2,4,6-Tribromophenol (S)61 %02/26/16 14:39 118-79-602/25/16 13:2727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 07:20 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/23/16 07:20 75-05-855.0 2.2 1
Acrolein ND ug/L 02/23/16 07:20 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
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[phone]
Page 17 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/23/16 07:20 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/23/16 07:20 107-05-110.0 1.5 1
Benzene ND ug/L 02/23/16 07:20 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 07:20 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 07:20 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 07:20 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 07:20 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 07:20 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 07:20 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 07:20 56-23-51.0 0.25 1
Chlorobenzene 0.79J ug/L 02/23/16 07:20 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 07:20 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 07:20 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 07:20 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/23/16 07:20 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 07:20 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 07:20 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 07:20 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 07:20 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.0J ug/L 02/23/16 07:20 95-50-15.0 0.30 1
1,3-Dichlorobenzene 0.31J ug/L 02/23/16 07:20 541-73-15.0 0.24 1
1,4-Dichlorobenzene 0.92J ug/L 02/23/16 07:20 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 07:20 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/23/16 07:20 75-71-85.0 0.21 1
1,1-Dichloroethane 3.4J ug/L 02/23/16 07:20 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 07:20 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 07:20 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 2.5J ug/L 02/23/16 07:20 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 07:20 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 07:20 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/23/16 07:20 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/23/16 07:20 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/23/16 07:20 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 07:20 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 07:20 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 07:20 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/23/16 07:20 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/23/16 07:20 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 07:20 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/23/16 07:20 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/23/16 07:20 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/23/16 07:20 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/23/16 07:20 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 07:20 108-10-1100 0.33 1
Naphthalene ND ug/L 02/23/16 07:20 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/23/16 07:20 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92287230002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/23/16 07:20 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 07:20 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 07:20 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 07:20 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 07:20 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 07:20 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/23/16 07:20 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/23/16 07:20 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 07:20 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 07:20 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 07:20 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 07:20 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 07:20 108-05-450.0 0.35 1
Vinyl chloride 5.4 ug/L 02/23/16 07:20 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 07:20 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 07:20 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/23/16 07:20 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 07:20 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 141000 ug/L 02/25/16 17:125000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 237000 ug/L 02/22/16 15:5425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/20/16 12:10 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3830J ug/L 02/22/16 20:38 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 49700 ug/L 02/25/16 20:16 16887-00-63000 1500 3
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/24/16 16:49 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/25/16 23:43 309-00-202/20/16 11:350.050 0.050 1
alpha-BHC ND ug/L 02/25/16 23:43 319-84-602/20/16 11:350.050 0.050 1
beta-BHC ND ug/L 02/25/16 23:43 319-85-702/20/16 11:350.050 0.050 1
delta-BHC ND ug/L 02/25/16 23:43 319-86-802/20/16 11:350.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/25/16 23:43 58-89-902/20/16 11:350.050 0.050 1
Chlordane (Technical)ND ug/L 02/25/16 23:43 57-74-902/20/16 11:350.50 0.20 1
4,4'-DDD ND ug/L 02/25/16 23:43 72-54-802/20/16 11:350.10 0.050 1
4,4'-DDE ND ug/L 02/25/16 23:43 72-55-902/20/16 11:350.10 0.050 1
4,4'-DDT ND ug/L 02/25/16 23:43 50-29-302/20/16 11:350.10 0.050 1
Dieldrin ND ug/L 02/25/16 23:43 60-57-102/20/16 11:350.075 0.050 1
Endosulfan I ND ug/L 02/25/16 23:43 959-98-802/20/16 11:350.10 0.050 1
Endosulfan II ND ug/L 02/25/16 23:43 33213-65-902/20/16 11:350.10 0.050 1
Endosulfan sulfate ND ug/L 02/25/16 23:43 1031-07-802/20/16 11:350.10 0.050 1
Endrin ND ug/L 02/25/16 23:43 72-20-802/20/16 11:350.10 0.050 1
Endrin aldehyde ND ug/L 02/25/16 23:43 7421-93-402/20/16 11:350.10 0.050 1
Heptachlor ND ug/L 02/25/16 23:43 76-44-802/20/16 11:350.050 0.050 1
Heptachlor epoxide ND ug/L 02/25/16 23:43 1024-57-302/20/16 11:350.075 0.050 1
Methoxychlor ND ug/L 02/25/16 23:43 72-43-502/20/16 11:351.0 0.15 1
Toxaphene ND ug/L 02/25/16 23:43 8001-35-202/20/16 11:351.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)83 %02/25/16 23:43 877-09-802/20/16 11:3520-130 1
Decachlorobiphenyl (S)50 %02/25/16 23:43 2051-24-302/20/16 11:3520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/23/16 18:01 12674-11-202/20/16 11:350.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/23/16 18:01 11104-28-202/20/16 11:350.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/23/16 18:01 11141-16-502/20/16 11:350.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/23/16 18:01 53469-21-902/20/16 11:350.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/23/16 18:01 12672-29-602/20/16 11:350.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/23/16 18:01 11097-69-102/20/16 11:350.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/23/16 18:01 11096-82-502/20/16 11:350.50 0.50 1
Surrogates
Decachlorobiphenyl (S)42 %02/23/16 18:01 2051-24-302/20/16 11:3510-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/25/16 08:27 94-75-702/24/16 10:300.97 0.23 1
Dinoseb ND ug/L 02/25/16 08:27 88-85-702/24/16 10:300.19 0.059 1
2,4,5-T ND ug/L 02/25/16 08:27 93-76-502/24/16 10:300.20 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/25/16 08:27 93-72-102/24/16 10:300.20 0.050 1
Surrogates
2,4-DCAA (S)140 %02/25/16 08:27 19719-28-9 S302/24/16 10:3036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:02 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:02 7440-38-202/22/16 16:3010.0 2.5 1
Barium ND ug/L 02/24/16 22:02 7440-39-302/22/16 16:30100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 02/24/16 22:02 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:02 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:02 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:02 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 22:02 7440-50-802/22/16 16:3010.0 2.5 1
Iron ND ug/L 02/24/16 22:02 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 22:02 7439-92-102/22/16 16:3010.0 2.5 1
Manganese ND ug/L 02/24/16 22:02 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 22:02 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:02 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:02 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:02 7440-28-002/22/16 16:305.5 5.0 1
Tin ND ug/L 02/24/16 22:02 7440-31-502/22/16 16:30100 2.5 1
Vanadium ND ug/L 02/24/16 22:02 7440-62-202/22/16 16:3025.0 2.5 1
Zinc ND ug/L 02/24/16 22:02 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:46 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/24/16 21:09 83-32-902/24/16 10:1510.0 0.25 1
Acenaphthylene ND ug/L 02/24/16 21:09 208-96-802/24/16 10:1510.0 0.21 1
Acetophenone ND ug/L 02/24/16 21:09 98-86-202/24/16 10:1510.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/24/16 21:09 53-96-302/24/16 10:1520.0 0.84 1
4-Aminobiphenyl ND ug/L 02/24/16 21:09 92-67-102/24/16 10:1520.0 0.92 1
Anthracene ND ug/L 02/24/16 21:09 120-12-702/24/16 10:1510.0 0.14 1
Benzo(a)anthracene ND ug/L 02/24/16 21:09 56-55-302/24/16 10:1510.0 0.33 1
Benzo(a)pyrene ND ug/L 02/24/16 21:09 50-32-802/24/16 10:1510.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/24/16 21:09 205-99-202/24/16 10:1510.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/24/16 21:09 191-24-202/24/16 10:1510.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/24/16 21:09 207-08-902/24/16 10:1510.0 0.43 1
Benzyl alcohol ND ug/L 02/24/16 21:09 100-51-602/24/16 10:1520.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/24/16 21:09 101-55-302/24/16 10:1510.0 1.3 1
Butylbenzylphthalate ND ug/L 02/24/16 21:09 85-68-702/24/16 10:1510.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/24/16 21:09 59-50-702/24/16 10:1520.0 4.2 1
4-Chloroaniline ND ug/L 02/24/16 21:09 106-47-802/24/16 10:1520.0 3.4 1
Chlorobenzilate ND ug/L 02/24/16 21:09 510-15-602/24/16 10:1510.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/24/16 21:09 111-91-102/24/16 10:1510.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/24/16 21:09 111-44-402/24/16 10:1510.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/24/16 21:09 108-60-102/24/16 10:1510.0 1.6 1
2-Chloronaphthalene ND ug/L 02/24/16 21:09 91-58-702/24/16 10:1510.0 2.2 1
2-Chlorophenol ND ug/L 02/24/16 21:09 95-57-802/24/16 10:1510.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/24/16 21:09 7005-72-302/24/16 10:1510.0 2.1 1
Chrysene ND ug/L 02/24/16 21:09 218-01-902/24/16 10:1510.0 0.21 1
Diallate ND ug/L 02/24/16 21:09 2303-16-402/24/16 10:1510.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/24/16 21:09 53-70-302/24/16 10:1510.0 0.55 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenzofuran ND ug/L 02/24/16 21:09 132-64-902/24/16 10:1510.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/24/16 21:09 91-94-102/24/16 10:1520.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/24/16 21:09 120-83-202/24/16 10:1510.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/24/16 21:09 87-65-002/24/16 10:1510.0 1.8 1
Diethylphthalate ND ug/L 02/24/16 21:09 84-66-202/24/16 10:156000 1.3 1
Dimethoate ND ug/L 02/24/16 21:09 60-51-502/24/16 10:1520.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/24/16 21:09 60-11-702/24/16 10:1510.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/24/16 21:09 57-97-602/24/16 10:1510.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/24/16 21:09 119-93-702/24/16 10:1510.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/24/16 21:09 105-67-902/24/16 10:1510.0 2.2 1
Dimethylphthalate ND ug/L 02/24/16 21:09 131-11-302/24/16 10:1510.0 1.5 1
Di-n-butylphthalate ND ug/L 02/24/16 21:09 84-74-202/24/16 10:1510.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/24/16 21:09 534-52-102/24/16 10:1550.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/24/16 21:09 99-65-002/24/16 10:1520.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/24/16 21:09 51-28-502/24/16 10:1550.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/24/16 21:09 121-14-202/24/16 10:1510.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/24/16 21:09 606-20-202/24/16 10:1510.0 1.7 1
Di-n-octylphthalate ND ug/L 02/24/16 21:09 117-84-002/24/16 10:1510.0 0.86 1
Diphenylamine ND ug/L 02/24/16 21:09 122-39-402/24/16 10:1510.0 1.3 1
Disulfoton ND ug/L 02/24/16 21:09 298-04-402/24/16 10:1510.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/24/16 21:09 117-81-702/24/16 10:1515.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/24/16 21:09 62-50-002/24/16 10:1520.0 1.8 1
Famphur ND ug/L 02/24/16 21:09 52-85-702/24/16 10:1520.0 1.7 1
Fluoranthene ND ug/L 02/24/16 21:09 206-44-002/24/16 10:1510.0 0.21 1
Fluorene ND ug/L 02/24/16 21:09 86-73-702/24/16 10:1510.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/24/16 21:09 87-68-302/24/16 10:1510.0 1.8 1
Hexachlorobenzene ND ug/L 02/24/16 21:09 118-74-102/24/16 10:1510.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/24/16 21:09 77-47-402/24/16 10:1510.0 1.8 1
Hexachloroethane ND ug/L 02/24/16 21:09 67-72-102/24/16 10:1510.0 1.5 1
Hexachloropropene ND ug/L 02/24/16 21:09 1888-71-702/24/16 10:1510.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/24/16 21:09 193-39-502/24/16 10:1510.0 0.29 1
Isodrin ND ug/L 02/24/16 21:09 465-73-602/24/16 10:1520.0 2.0 1
Isophorone ND ug/L 02/24/16 21:09 78-59-102/24/16 10:1510.0 1.8 1
Isosafrole ND ug/L 02/24/16 21:09 120-58-102/24/16 10:1510.0 1.8 1
Kepone ND ug/L 02/24/16 21:09 143-50-0 L202/24/16 10:1520.0 3.1 1
Methapyrilene ND ug/L 02/24/16 21:09 91-80-502/24/16 10:15100 2.7 1
3-Methylcholanthrene ND ug/L 02/24/16 21:09 56-49-502/24/16 10:1510.0 0.82 1
Methyl methanesulfonate ND ug/L 02/24/16 21:09 66-27-302/24/16 10:1510.0 1.3 1
2-Methylnaphthalene ND ug/L 02/24/16 21:09 91-57-602/24/16 10:1510.0 0.28 1
Methyl parathion ND ug/L 02/24/16 21:09 298-00-002/24/16 10:1510.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/24/16 21:09 95-48-702/24/16 10:1510.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/24/16 21:0902/24/16 10:1510.0 1.7 1
1-Naphthalenamine ND ug/L 02/24/16 21:09 134-32-702/24/16 10:1510.0 0.96 1
2-Naphthalenamine ND ug/L 02/24/16 21:09 91-59-802/24/16 10:1510.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/24/16 21:09 130-15-402/24/16 10:1510.0 1.8 1
2-Nitroaniline ND ug/L 02/24/16 21:09 88-74-402/24/16 10:1550.0 2.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 22 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3-Nitroaniline ND ug/L 02/24/16 21:09 99-09-202/24/16 10:1550.0 2.4 1
4-Nitroaniline ND ug/L 02/24/16 21:09 100-01-602/24/16 10:1520.0 2.5 1
Nitrobenzene ND ug/L 02/24/16 21:09 98-95-302/24/16 10:1510.0 1.7 1
2-Nitrophenol ND ug/L 02/24/16 21:09 88-75-502/24/16 10:1510.0 1.7 1
4-Nitrophenol ND ug/L 02/24/16 21:09 100-02-702/24/16 10:1550.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/24/16 21:09 99-55-802/24/16 10:1510.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/24/16 21:09 55-18-502/24/16 10:1520.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/24/16 21:09 62-75-902/24/16 10:1510.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/24/16 21:09 924-16-302/24/16 10:1510.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/24/16 21:09 621-64-702/24/16 10:1510.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/24/16 21:09 86-30-602/24/16 10:1510.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/24/16 21:09 10595-95-602/24/16 10:1510.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/24/16 21:09 100-75-402/24/16 10:1520.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/24/16 21:09 930-55-202/24/16 10:1510.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/24/16 21:09 126-68-102/24/16 10:1510.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/24/16 21:09 56-38-202/24/16 10:1510.0 1.1 1
Pentachlorobenzene ND ug/L 02/24/16 21:09 608-93-502/24/16 10:1510.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/24/16 21:09 82-68-802/24/16 10:1520.0 1.0 1
Pentachlorophenol ND ug/L 02/24/16 21:09 87-86-502/24/16 10:1525.0 2.3 1
Phenacetin ND ug/L 02/24/16 21:09 62-44-202/24/16 10:1520.0 0.97 1
Phenanthrene ND ug/L 02/24/16 21:09 85-01-802/24/16 10:1510.0 0.22 1
Phenol ND ug/L 02/24/16 21:09 108-95-202/24/16 10:1510.0 1.7 1
p-Phenylenediamine ND ug/L 02/24/16 21:09 106-50-302/24/16 10:1510.0 0.96 1
Phorate ND ug/L 02/24/16 21:09 298-02-202/24/16 10:1510.0 1.1 1
Pronamide ND ug/L 02/24/16 21:09 23950-58-502/24/16 10:1510.0 0.97 1
Pyrene ND ug/L 02/24/16 21:09 129-00-002/24/16 10:1510.0 0.19 1
Safrole ND ug/L 02/24/16 21:09 94-59-702/24/16 10:1510.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/24/16 21:09 95-94-302/24/16 10:1510.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/24/16 21:09 58-90-202/24/16 10:1510.0 2.3 1
Thionazin ND ug/L 02/24/16 21:09 297-97-202/24/16 10:1520.0 1.2 1
O-Toluidine ND ug/L 02/24/16 21:09 95-53-402/24/16 10:1510.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/24/16 21:09 95-95-402/24/16 10:1510.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/24/16 21:09 88-06-202/24/16 10:1510.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/24/16 21:09 99-35-402/24/16 10:1510.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)42 %02/24/16 21:09 4165-60-002/24/16 10:1521-110 1
2-Fluorobiphenyl (S)49 %02/24/16 21:09 321-60-802/24/16 10:1527-110 1
Terphenyl-d14 (S)80 %02/24/16 21:09 1718-51-002/24/16 10:1531-107 1
Phenol-d6 (S)16 %02/24/16 21:09 13127-88-302/24/16 10:1510-110 1
2-Fluorophenol (S)26 %02/24/16 21:09 367-12-402/24/16 10:1512-110 1
2,4,6-Tribromophenol (S)65 %02/24/16 21:09 118-79-602/24/16 10:1527-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 07:36 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/23/16 07:36 75-05-855.0 2.2 1
Acrolein ND ug/L 02/23/16 07:36 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/23/16 07:36 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/23/16 07:36 107-05-110.0 1.5 1
Benzene ND ug/L 02/23/16 07:36 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 07:36 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 07:36 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 07:36 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 07:36 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 07:36 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 07:36 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 07:36 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 07:36 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 07:36 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 07:36 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 07:36 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/23/16 07:36 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 07:36 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 07:36 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 07:36 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 07:36 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 07:36 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/23/16 07:36 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/23/16 07:36 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 07:36 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/23/16 07:36 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/23/16 07:36 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 07:36 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 07:36 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/23/16 07:36 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 07:36 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 07:36 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/23/16 07:36 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/23/16 07:36 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/23/16 07:36 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 07:36 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 07:36 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 07:36 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/23/16 07:36 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/23/16 07:36 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 07:36 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/23/16 07:36 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/23/16 07:36 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/23/16 07:36 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/23/16 07:36 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 07:36 108-10-1100 0.33 1
Naphthalene ND ug/L 02/23/16 07:36 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/23/16 07:36 107-12-0150 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-FIELD BLANK Lab ID: 92287230003 Collected: 02/18/16 12:50 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/23/16 07:36 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 07:36 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 07:36 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 07:36 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 07:36 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 07:36 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/23/16 07:36 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/23/16 07:36 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 07:36 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 07:36 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 07:36 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 07:36 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 07:36 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 07:36 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 07:36 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %02/23/16 07:36 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/23/16 07:36 17060-07-070-130 1
Toluene-d8 (S)100 %02/23/16 07:36 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 02/25/16 17:525000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 02/22/16 15:5425000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/20/16 12:10 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 02/22/16 20:52 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride ND ug/L 02/25/16 20:17 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/24/16 16:50 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW2 Lab ID: 92287230004 Collected: 02/18/16 08:47 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:15 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:15 7440-38-202/22/16 16:3010.0 2.5 1
Barium 12.1J ug/L 02/24/16 22:15 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:15 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:15 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:15 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt 7.5J ug/L 02/24/16 22:15 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 22:15 7440-50-802/22/16 16:3010.0 2.5 1
Iron 792 ug/L 02/24/16 22:15 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 22:15 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 201 ug/L 02/24/16 22:15 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 22:15 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:15 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:15 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:15 7440-28-002/22/16 16:305.5 5.0 1
Vanadium ND ug/L 02/24/16 22:15 7440-62-202/22/16 16:3025.0 2.5 1
Zinc ND ug/L 02/24/16 22:15 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:48 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 07:53 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 07:53 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 07:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 07:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 07:53 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 07:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 07:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 07:53 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 07:53 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 07:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 07:53 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 07:53 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 07:53 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 07:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 07:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 07:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 07:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 07:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 07:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 07:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 07:53 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 07:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 07:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 07:53 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW2 Lab ID: 92287230004 Collected: 02/18/16 08:47 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/23/16 07:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 07:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 07:53 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 07:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 07:53 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 07:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 07:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 07:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 07:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 07:53 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 07:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 07:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 07:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 07:53 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 07:53 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 07:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 07:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 07:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 07:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 07:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 07:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 07:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 07:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 07:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 07:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/23/16 07:53 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 07:53 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 4350J ug/L 02/25/16 18:005000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 84000 ug/L 02/22/16 15:5525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 11200J ug/L 02/22/16 21:05 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4600 ug/L 02/25/16 20:18 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW3R Lab ID: 92287230005 Collected: 02/18/16 11:10 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:18 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:18 7440-38-202/22/16 16:3010.0 2.5 1
Barium 15.7J ug/L 02/24/16 22:18 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:18 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:18 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:18 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:18 7440-48-402/22/16 16:3010.0 2.5 1
Copper 3.6J ug/L 02/24/16 22:18 7440-50-802/22/16 16:3010.0 2.5 1
Iron 270J ug/L 02/24/16 22:18 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 22:18 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 72.7 ug/L 02/24/16 22:18 7439-96-502/22/16 16:3050.0 2.5 1
Nickel 3.2J ug/L 02/24/16 22:18 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:18 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:18 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:18 7440-28-002/22/16 16:305.5 5.0 1
Vanadium ND ug/L 02/24/16 22:18 7440-62-202/22/16 16:3025.0 2.5 1
Zinc ND ug/L 02/24/16 22:18 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:50 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 08:10 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 08:10 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 08:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 08:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 08:10 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 08:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 08:10 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 08:10 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 08:10 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 08:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 08:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 08:10 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 08:10 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 08:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 08:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 08:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 08:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 08:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 08:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 08:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 08:10 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 08:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 08:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 08:10 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW3R Lab ID: 92287230005 Collected: 02/18/16 11:10 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/23/16 08:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 08:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 08:10 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 08:10 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 08:10 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 08:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 08:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 08:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 08:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 08:10 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 08:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 08:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 08:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 08:10 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 08:10 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 08:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 08:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 08:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 08:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 08:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 08:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 08:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 08:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 08:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %02/23/16 08:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/23/16 08:10 17060-07-070-130 1
Toluene-d8 (S)102 %02/23/16 08:10 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 89800 ug/L 02/25/16 18:095000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 140000 ug/L 02/22/16 15:5525000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 7960J ug/L 02/22/16 21:19 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 20600 ug/L 02/25/16 20:19 16887-00-62000 1000 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW4R Lab ID: 92287230006 Collected: 02/18/16 09:11 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:21 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:21 7440-38-202/22/16 16:3010.0 2.5 1
Barium 36.4J ug/L 02/24/16 22:21 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:21 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:21 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:21 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:21 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 22:21 7440-50-802/22/16 16:3010.0 2.5 1
Iron 43.0J ug/L 02/24/16 22:21 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 22:21 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 981 ug/L 02/24/16 22:21 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 22:21 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:21 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:21 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:21 7440-28-002/22/16 16:305.5 5.0 1
Vanadium ND ug/L 02/24/16 22:21 7440-62-202/22/16 16:3025.0 2.5 1
Zinc 6.6J ug/L 02/24/16 22:21 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 14:57 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 08:26 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 08:26 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 08:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 08:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 08:26 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 08:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 08:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 08:26 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 08:26 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 08:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 08:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 08:26 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 08:26 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 08:26 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 08:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 08:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 08:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 08:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 08:26 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 08:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 08:26 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 08:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 08:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 08:26 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW4R Lab ID: 92287230006 Collected: 02/18/16 09:11 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/23/16 08:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 08:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 08:26 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 08:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 08:26 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 08:26 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 08:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 08:26 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 08:26 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 08:26 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 08:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 08:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 08:26 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 08:26 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 08:26 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 08:26 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 08:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 08:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 08:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 08:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 08:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 08:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 08:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 08:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %02/23/16 08:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/23/16 08:26 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 08:26 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 308000 ug/L 02/25/16 18:415000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 412000 ug/L 02/22/16 15:5625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 10300J ug/L 02/22/16 21:33 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 69500 ug/L 02/25/16 20:20 16887-00-65000 2500 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW6R Lab ID: 92287230007 Collected: 02/18/16 09:00 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:24 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:24 7440-38-202/22/16 16:3010.0 2.5 1
Barium 98.2J ug/L 02/24/16 22:24 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:24 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:24 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:24 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:24 7440-48-402/22/16 16:3010.0 2.5 1
Copper ND ug/L 02/24/16 22:24 7440-50-802/22/16 16:3010.0 2.5 1
Iron 1500 ug/L 02/24/16 22:24 7439-89-602/22/16 16:30300 25.0 1
Lead ND ug/L 02/24/16 22:24 7439-92-102/22/16 16:3010.0 2.5 1
Manganese 1620 ug/L 02/24/16 22:24 7439-96-502/22/16 16:3050.0 2.5 1
Nickel ND ug/L 02/24/16 22:24 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:24 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:24 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:24 7440-28-002/22/16 16:305.5 5.0 1
Vanadium ND ug/L 02/24/16 22:24 7440-62-202/22/16 16:3025.0 2.5 1
Zinc ND ug/L 02/24/16 22:24 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/03/16 15:00 7439-97-603/02/16 17:150.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 08:43 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 08:43 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 08:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 08:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 08:43 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 08:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 08:43 74-83-9 M110.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 08:43 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 08:43 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 08:43 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 08:43 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 08:43 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 08:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 08:43 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 08:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 08:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 08:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 08:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 08:43 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 08:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 08:43 110-57-6100 1.0 1
1,1-Dichloroethane 0.59J ug/L 02/23/16 08:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 08:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 08:43 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 32 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW6R Lab ID: 92287230007 Collected: 02/18/16 09:00 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene 0.32J ug/L 02/23/16 08:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 08:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 08:43 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 08:43 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 08:43 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 08:43 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 08:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 08:43 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 08:43 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 08:43 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 08:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 08:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 08:43 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 08:43 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/23/16 08:43 109-99-910.0 3.1 1
Toluene ND ug/L 02/23/16 08:43 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 08:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 08:43 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 08:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 08:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 08:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 08:43 108-05-4 M150.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 08:43 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 08:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 08:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/23/16 08:43 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 08:43 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 168000 ug/L 02/25/16 18:565000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 475000 ug/L 02/22/16 15:5625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3310J ug/L 02/22/16 22:13 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 153000 ug/L 02/25/16 20:21 16887-00-65000 2500 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 33 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW1 Lab ID: 92287230008 Collected: 02/17/16 16:17 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:27 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:27 7440-38-202/22/16 16:3010.0 2.5 1
Barium 58.2J ug/L 02/24/16 22:27 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:27 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:27 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:27 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:27 7440-48-402/22/16 16:3010.0 2.5 1
Copper 6.3J ug/L 02/24/16 22:27 7440-50-802/22/16 16:3010.0 2.5 1
Lead 4.0J ug/L 02/24/16 22:27 7439-92-102/22/16 16:3010.0 2.5 1
Nickel 3.3J ug/L 02/24/16 22:27 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:27 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:27 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:27 7440-28-002/22/16 16:305.5 5.0 1
Vanadium 6.4J ug/L 02/24/16 22:27 7440-62-202/22/16 16:3025.0 2.5 1
Zinc 13.0 ug/L 02/24/16 22:27 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 08:59 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 08:59 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 08:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 08:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 08:59 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 08:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 08:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 08:59 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 08:59 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 08:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 08:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 08:59 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 08:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 08:59 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 08:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 08:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 08:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 08:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 08:59 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 08:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 08:59 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 08:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 08:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 08:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/23/16 08:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 08:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 08:59 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 08:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 08:59 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW1 Lab ID: 92287230008 Collected: 02/17/16 16:17 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/23/16 08:59 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 08:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 08:59 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 08:59 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 08:59 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 08:59 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 08:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 08:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 08:59 127-18-41.0 0.46 1
Toluene ND ug/L 02/23/16 08:59 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 08:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 08:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 08:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 08:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 08:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 08:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 08:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 08:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %02/23/16 08:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/23/16 08:59 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 08:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW2 Lab ID: 92287230009 Collected: 02/17/16 13:58 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/24/16 22:30 7440-36-002/22/16 16:306.0 3.8 1
Arsenic ND ug/L 02/24/16 22:30 7440-38-202/22/16 16:3010.0 2.5 1
Barium 55.0J ug/L 02/24/16 22:30 7440-39-302/22/16 16:30100 2.5 1
Beryllium ND ug/L 02/24/16 22:30 7440-41-702/22/16 16:301.0 0.50 1
Cadmium ND ug/L 02/24/16 22:30 7440-43-902/22/16 16:301.0 0.50 1
Chromium ND ug/L 02/24/16 22:30 7440-47-302/22/16 16:3010.0 2.5 1
Cobalt ND ug/L 02/24/16 22:30 7440-48-402/22/16 16:3010.0 2.5 1
Copper 5.7J ug/L 02/24/16 22:30 7440-50-802/22/16 16:3010.0 2.5 1
Lead 2.6J ug/L 02/24/16 22:30 7439-92-102/22/16 16:3010.0 2.5 1
Nickel 3.0J ug/L 02/24/16 22:30 7440-02-002/22/16 16:3050.0 2.5 1
Selenium ND ug/L 02/24/16 22:30 7782-49-202/22/16 16:3010.0 5.0 1
Silver ND ug/L 02/24/16 22:30 7440-22-402/22/16 16:3010.0 2.5 1
Thallium ND ug/L 02/24/16 22:30 7440-28-002/22/16 16:305.5 5.0 1
Vanadium 6.1J ug/L 02/24/16 22:30 7440-62-202/22/16 16:3025.0 2.5 1
Zinc 11.0 ug/L 02/24/16 22:30 7440-66-602/22/16 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 09:33 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 09:33 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 09:33 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 09:33 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 09:33 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 09:33 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 09:33 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 09:33 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 09:33 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 09:33 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 09:33 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 09:33 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 09:33 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 09:33 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 09:33 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 09:33 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 09:33 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 09:33 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 09:33 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 09:33 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 09:33 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 09:33 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 09:33 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 09:33 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/23/16 09:33 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 09:33 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 09:33 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 09:33 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 09:33 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW2 Lab ID: 92287230009 Collected: 02/17/16 13:58 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/23/16 09:33 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 09:33 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 09:33 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 09:33 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 09:33 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 09:33 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 09:33 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 09:33 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 09:33 127-18-41.0 0.46 1
Toluene ND ug/L 02/23/16 09:33 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 09:33 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 09:33 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 09:33 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 09:33 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 09:33 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 09:33 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 09:33 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/23/16 09:33 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 09:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %02/23/16 09:33 17060-07-070-130 1
Toluene-d8 (S)102 %02/23/16 09:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-TRIP BLANK Lab ID: 92287230010 Collected: 02/16/16 08:00 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/23/16 09:49 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/23/16 09:49 107-13-1200 1.9 1
Benzene ND ug/L 02/23/16 09:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/23/16 09:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/23/16 09:49 75-27-41.0 0.18 1
Bromoform ND ug/L 02/23/16 09:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/23/16 09:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/23/16 09:49 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/23/16 09:49 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/23/16 09:49 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/23/16 09:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/23/16 09:49 75-00-310.0 0.54 1
Chloroform ND ug/L 02/23/16 09:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/23/16 09:49 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/23/16 09:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/23/16 09:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/23/16 09:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/23/16 09:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/23/16 09:49 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/23/16 09:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/23/16 09:49 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/23/16 09:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/23/16 09:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/23/16 09:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/23/16 09:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/23/16 09:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/23/16 09:49 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/23/16 09:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/23/16 09:49 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/23/16 09:49 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/23/16 09:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/23/16 09:49 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/23/16 09:49 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/23/16 09:49 108-10-1100 0.33 1
Styrene ND ug/L 02/23/16 09:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/23/16 09:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/23/16 09:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/23/16 09:49 127-18-41.0 0.46 1
Toluene ND ug/L 02/23/16 09:49 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/23/16 09:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/23/16 09:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/23/16 09:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/23/16 09:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/23/16 09:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/23/16 09:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/23/16 09:49 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 38 of 78
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Sample: 3901-TRIP BLANK Lab ID: 92287230010 Collected: 02/16/16 08:00 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 02/23/16 09:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %02/23/16 09:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/23/16 09:49 17060-07-070-130 1
Toluene-d8 (S)101 %02/23/16 09:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 39 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/9017
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1676109
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 03/03/16 14:290.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1676110LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.72.5 107 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1676111MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287435001
1676112
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125101 0 252.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 40 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20758
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007,
92287230008, 92287230009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670856
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007,
92287230008, 92287230009
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/24/16 21:443.8
Arsenic ug/L ND 10.0 02/24/16 21:442.5
Barium ug/L ND 100 02/24/16 21:442.5
Beryllium ug/L ND 1.0 02/24/16 21:440.50
Cadmium ug/L ND 1.0 02/24/16 21:440.50
Chromium ug/L ND 10.0 02/24/16 21:442.5
Cobalt ug/L ND 10.0 02/24/16 21:442.5
Copper ug/L ND 10.0 02/24/16 21:442.5
Iron ug/L ND 300 02/24/16 21:4425.0
Lead ug/L ND 10.0 02/24/16 21:442.5
Manganese ug/L ND 50.0 02/24/16 21:442.5
Nickel ug/L ND 50.0 02/24/16 21:442.5
Selenium ug/L ND 10.0 02/24/16 21:445.0
Silver ug/L ND 10.0 02/24/16 21:442.5
Thallium ug/L ND 5.5 02/24/16 21:445.0
Tin ug/L ND 100 02/24/16 21:442.5
Vanadium ug/L ND 25.0 02/24/16 21:442.5
Zinc ug/L ND 10.0 02/24/16 21:445.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670857LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 422500 84 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 514500 103 80-120
Beryllium ug/L 511500 102 80-120
Cadmium ug/L 503500 101 80-120
Chromium ug/L 535500 107 80-120
Cobalt ug/L 478500 96 80-120
Copper ug/L 500500 100 80-120
Iron ug/L 53705000 107 80-120
Lead ug/L 470500 94 80-120
Manganese ug/L 500500 100 80-120
Nickel ug/L 506500 101 80-120
Selenium ug/L 472500 94 80-120
Silver ug/L 220250 88 80-120
Thallium ug/L 480500 96 80-120
Tin ug/L 421500 84 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Huntersville, NC 28078
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Page 41 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670857LABORATORY CONTROL SAMPLE:
LCSSpike
Vanadium ug/L 507500 101 80-120
Zinc ug/L 493500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670858MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230001
1670859
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 84 75-12584 0 25500ND420 422
Arsenic ug/L 500 93 75-12594 1 25500ND466 469
Barium ug/L 500 101 75-125102 1 255004.4J 508 514
Beryllium ug/L 500 101 75-125102 1 25500ND504 509
Cadmium ug/L 500 100 75-125101 1 25500ND498 504
Chromium ug/L 500 105 75-125104 1 25500ND526 523
Cobalt ug/L 500 92 75-12592 0 25500ND458 458
Copper ug/L 500 99 75-12599 1 25500ND494 497
Iron ug/L 5000 105 75-125106 1 255000243J5500 5540
Lead ug/L 500 90 75-12592 1 25500ND452 458
Manganese ug/L 500 98 75-12598 0 255005.4J 493 493
Nickel ug/L 500 97 75-12597 0 25500ND486 484
Selenium ug/L 500 93 75-12593 1 25500ND464 469
Silver ug/L 250 87 75-12589 2 25250ND218 223
Thallium ug/L 500 93 75-12595 3 25500ND463 476
Tin ug/L 500 82 75-12583 1 25500ND411 416
Vanadium ug/L 500 100 75-125100 0 25500ND503 504
Zinc ug/L 500 94 75-12595 0 2550014.8 487 488
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 42 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35666
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007,
92287230008, 92287230009, 92287230010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670824
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007,
92287230008, 92287230009, 92287230010
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/23/16 01:310.33
1,1,1-Trichloroethane ug/L ND 1.0 02/23/16 01:310.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/23/16 01:310.40
1,1,2-Trichloroethane ug/L ND 1.0 02/23/16 01:310.29
1,1-Dichloroethane ug/L ND 5.0 02/23/16 01:310.32
1,1-Dichloroethene ug/L ND 5.0 02/23/16 01:310.56
1,1-Dichloropropene ug/L ND 5.0 02/23/16 01:310.49
1,2,3-Trichloropropane ug/L ND 1.0 02/23/16 01:310.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/23/16 01:310.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/23/16 01:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/23/16 01:310.27
1,2-Dichlorobenzene ug/L ND 5.0 02/23/16 01:310.30
1,2-Dichloroethane ug/L ND 1.0 02/23/16 01:310.24
1,2-Dichloropropane ug/L ND 1.0 02/23/16 01:310.27
1,3-Dichlorobenzene ug/L ND 5.0 02/23/16 01:310.24
1,3-Dichloropropane ug/L ND 1.0 02/23/16 01:310.28
1,4-Dichlorobenzene ug/L ND 1.0 02/23/16 01:310.33
2,2-Dichloropropane ug/L ND 15.0 02/23/16 01:310.13
2-Butanone (MEK)ug/L ND 100 02/23/16 01:310.96
2-Hexanone ug/L ND 50.0 02/23/16 01:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/23/16 01:310.33
Acetone ug/L ND 100 02/23/16 01:3110.0
Acetonitrile ug/L ND 55.0 02/23/16 01:312.2
Acrolein ug/L ND 53.0 02/23/16 01:311.6
Acrylonitrile ug/L ND 200 02/23/16 01:311.9
Allyl chloride ug/L ND 10.0 02/23/16 01:311.5
Benzene ug/L ND 1.0 02/23/16 01:310.25
Bromochloromethane ug/L ND 3.0 02/23/16 01:310.17
Bromodichloromethane ug/L ND 1.0 02/23/16 01:310.18
Bromoform ug/L ND 3.0 02/23/16 01:310.26
Bromomethane ug/L ND 10.0 02/23/16 01:310.29
Carbon disulfide ug/L ND 100 02/23/16 01:311.2
Carbon tetrachloride ug/L ND 1.0 02/23/16 01:310.25
Chlorobenzene ug/L ND 3.0 02/23/16 01:310.23
Chloroethane ug/L ND 10.0 02/23/16 01:310.54
Chloroform ug/L ND 5.0 02/23/16 01:310.14
Chloromethane ug/L ND 1.0 02/23/16 01:310.11
Chloroprene ug/L ND 20.0 02/23/16 01:310.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/23/16 01:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/23/16 01:310.13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 43 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670824
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007,
92287230008, 92287230009, 92287230010
Matrix: Water
AnalyzedMDL
Dibromochloromethane ug/L ND 3.0 02/23/16 01:310.21
Dibromomethane ug/L ND 10.0 02/23/16 01:310.21
Dichlorodifluoromethane ug/L ND 5.0 02/23/16 01:310.21
Ethyl methacrylate ug/L ND 10.0 02/23/16 01:310.20
Ethylbenzene ug/L ND 1.0 02/23/16 01:310.30
Iodomethane ug/L ND 10.0 02/23/16 01:310.32
Isobutanol ug/L ND 100 02/23/16 01:3135.0
Methacrylonitrile ug/L ND 100 02/23/16 01:310.93
Methyl methacrylate ug/L ND 30.0 02/23/16 01:312.0
Methylene Chloride ug/L ND 1.0 02/23/16 01:310.97
Naphthalene ug/L ND 10.0 02/23/16 01:310.24
Propionitrile ug/L ND 150 02/23/16 01:313.6
Styrene ug/L ND 1.0 02/23/16 01:310.26
Tetrachloroethene ug/L ND 1.0 02/23/16 01:310.46
Tetrahydrofuran ug/L ND 10.0 02/23/16 01:313.1
Toluene ug/L ND 1.0 02/23/16 01:310.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/23/16 01:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/23/16 01:310.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/23/16 01:311.0
Trichloroethene ug/L ND 1.0 02/23/16 01:310.47
Trichlorofluoromethane ug/L ND 1.0 02/23/16 01:310.20
Vinyl acetate ug/L ND 50.0 02/23/16 01:310.35
Vinyl chloride ug/L ND 1.0 02/23/16 01:310.62
Xylene (Total)ug/L ND 5.0 02/23/16 01:310.66
1,2-Dichloroethane-d4 (S)%92 70-130 02/23/16 01:31
4-Bromofluorobenzene (S)%101 70-130 02/23/16 01:31
Toluene-d8 (S)%100 70-130 02/23/16 01:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670825LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.950 94 80-125
1,1,1-Trichloroethane ug/L 44.850 90 71-129
1,1,2,2-Tetrachloroethane ug/L 45.250 90 79-124
1,1,2-Trichloroethane ug/L 45.650 91 85-125
1,1-Dichloroethane ug/L 42.150 84 73-126
1,1-Dichloroethene ug/L 46.150 92 66-135
1,1-Dichloropropene ug/L 44.750 89 74-135
1,2,3-Trichloropropane ug/L 45.750 91 75-130
1,2,4-Trichlorobenzene ug/L 47.650 95 75-134
1,2-Dibromo-3-chloropropane ug/L 44.950 90 71-133
1,2-Dibromoethane (EDB)ug/L 47.350 95 83-124
1,2-Dichlorobenzene ug/L 45.450 91 80-133
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 44 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670825LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloroethane ug/L 41.450 83 67-128
1,2-Dichloropropane ug/L 43.550 87 75-132
1,3-Dichlorobenzene ug/L 45.950 92 77-130
1,3-Dichloropropane ug/L 44.850 90 76-131
1,4-Dichlorobenzene ug/L 45.850 92 78-130
2,2-Dichloropropane ug/L 41.050 82 40-160
2-Butanone (MEK)ug/L 81.5J100 82 61-144
2-Hexanone ug/L 88.4100 88 68-143
4-Methyl-2-pentanone (MIBK)ug/L 88.2J100 88 72-135
Acetone ug/L 80.4J100 80 48-146
Acetonitrile ug/L 428500 86 62-150
Acrolein ug/L 276250 110 24-160
Acrylonitrile ug/L 226250 90 40-160
Allyl chloride ug/L 36.950 74 66-137
Benzene ug/L 43.750 87 80-125
Bromochloromethane ug/L 46.550 93 71-125
Bromodichloromethane ug/L 46.350 93 78-124
Bromoform ug/L 49.350 99 71-128
Bromomethane ug/L 36.850 74 40-160
Carbon disulfide ug/L 47.9J50 96 50-160
Carbon tetrachloride ug/L 45.050 90 69-131
Chlorobenzene ug/L 45.150 90 81-122
Chloroethane ug/L 37.450 75 39-148
Chloroform ug/L 42.850 86 73-127
Chloromethane ug/L 35.150 70 44-146
Chloroprene ug/L 46.950 94 75-145
cis-1,2-Dichloroethene ug/L 43.250 86 74-124
cis-1,3-Dichloropropene ug/L 47.150 94 72-132
Dibromochloromethane ug/L 48.650 97 78-125
Dibromomethane ug/L 47.750 95 82-120
Dichlorodifluoromethane ug/L 40.750 81 34-157
Ethyl methacrylate ug/L 42.750 85 82-121
Ethylbenzene ug/L 43.050 86 79-121
Iodomethane ug/L 80.7100 81 39-154
Isobutanol ug/L 9201000 92 34-160
Methacrylonitrile ug/L 424500 85 74-134
Methyl methacrylate ug/L 46.550 93 84-124
Methylene Chloride ug/L 45.250 90 64-133
Naphthalene ug/L 46.850 94 73-133
Propionitrile ug/L 437500 87 73-140
Styrene ug/L 45.350 91 84-126
Tetrachloroethene ug/L 43.850 88 78-122
Tetrahydrofuran ug/L 417500 83 69-148
Toluene ug/L 44.450 89 80-121
trans-1,2-Dichloroethene ug/L 43.650 87 71-127
trans-1,3-Dichloropropene ug/L 46.850 94 69-141
trans-1,4-Dichloro-2-butene ug/L 42.3J50 85 40-160
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670825LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 45.250 90 78-122
Trichlorofluoromethane ug/L 43.250 86 53-137
Vinyl acetate ug/L 87.9100 88 40-160
Vinyl chloride ug/L 42.950 86 58-137
Xylene (Total)ug/L 129150 86 81-126
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1670826MATRIX SPIKE SAMPLE:
MSSpike
Result
92287230007
1,1,1,2-Tetrachloroethane ug/L 19.320 97 70-130ND
1,1,1-Trichloroethane ug/L 20.220 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.620 93 70-130ND
1,1,2-Trichloroethane ug/L 19.320 96 70-130ND
1,1-Dichloroethane ug/L 19.920 96 70-1300.59J
1,1-Dichloroethene ug/L 20.820 104 70-166ND
1,1-Dichloropropene ug/L 19.820 99 70-130ND
1,2,3-Trichloropropane ug/L 19.720 99 70-130ND
1,2,4-Trichlorobenzene ug/L 20.420 102 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.920 90 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.320 97 70-130ND
1,2-Dichlorobenzene ug/L 18.620 93 70-130ND
1,2-Dichloroethane ug/L 17.820 89 70-130ND
1,2-Dichloropropane ug/L 19.720 98 70-130ND
1,3-Dichlorobenzene ug/L 19.020 95 70-130ND
1,3-Dichloropropane ug/L 18.820 94 70-130ND
1,4-Dichlorobenzene ug/L 18.820 94 70-130ND
2,2-Dichloropropane ug/L 15.620 78 70-130ND
2-Butanone (MEK)ug/L 34.5J40 86 70-130ND
2-Hexanone ug/L 37.2J40 93 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 37.3J40 93 70-130ND
Acetone ug/L 35.7J40 89 70-130ND
Acetonitrile ug/L 180200 90 70-130ND
Acrolein ug/L 98.4100 98 70-130ND
Acrylonitrile ug/L 93.8J100 94 70-130ND
Allyl chloride ug/L 16.520 82 70-130ND
Benzene ug/L 19.820 99 70-148ND
Bromochloromethane ug/L 20.120 101 70-130ND
Bromodichloromethane ug/L 20.020 100 70-130ND
Bromoform ug/L 19.420 97 70-130ND
Bromomethane ug/L 13.9 M12069 70-130ND
Carbon disulfide ug/L 21.4J20 107 70-130ND
Carbon tetrachloride ug/L 21.220 106 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1670826MATRIX SPIKE SAMPLE:
MSSpike
Result
92287230007
Chlorobenzene ug/L 19.120 96 70-146ND
Chloroethane ug/L 19.820 99 70-130ND
Chloroform ug/L 19.320 97 70-130ND
Chloromethane ug/L 17.220 86 70-130ND
Chloroprene ug/L 21.620 108 70-130ND
cis-1,2-Dichloroethene ug/L 19.720 97 70-1300.32J
cis-1,3-Dichloropropene ug/L 19.320 97 70-130ND
Dibromochloromethane ug/L 19.220 96 70-130ND
Dibromomethane ug/L 21.520 108 70-130ND
Dichlorodifluoromethane ug/L 19.920 99 70-130ND
Ethyl methacrylate ug/L 18.020 90 70-130ND
Ethylbenzene ug/L 18.420 92 70-130ND
Iodomethane ug/L 31.540 79 70-130ND
Isobutanol ug/L 361400 90 70-130ND
Methacrylonitrile ug/L 178200 89 70-130ND
Methyl methacrylate ug/L 19.1J20 96 70-130ND
Methylene Chloride ug/L 17.720 88 70-130ND
Naphthalene ug/L 19.120 96 70-130ND
Propionitrile ug/L 184200 92 70-130ND
Styrene ug/L 18.420 92 70-130ND
Tetrachloroethene ug/L 19.520 98 70-130ND
Tetrahydrofuran ug/L 175200 87 70-130ND
Toluene ug/L 19.620 98 70-155ND
trans-1,2-Dichloroethene ug/L 20.120 101 70-130ND
trans-1,3-Dichloropropene ug/L 18.820 94 70-130ND
trans-1,4-Dichloro-2-butene ug/L 14.5J20 73 70-130ND
Trichloroethene ug/L 20.420 102 69-151ND
Trichlorofluoromethane ug/L 20.820 104 70-130ND
Vinyl acetate ug/L 25.9J M14065 70-130ND
Vinyl chloride ug/L 20.920 105 70-130ND
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287230008
1670827SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 47 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287230008
1670827SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 48 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287230008
1670827SAMPLE DUPLICATE:
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%93 193
4-Bromofluorobenzene (S)%101 1102
Toluene-d8 (S)%101 0101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 49 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40919
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92287230001, 92287230002, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670371
Associated Lab Samples:92287230001, 92287230002, 92287230003
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 02/25/16 14:000.050
4,4'-DDE ug/L ND 0.10 02/25/16 14:000.050
4,4'-DDT ug/L ND 0.10 02/25/16 14:000.050
Aldrin ug/L ND 0.050 02/25/16 14:000.050
alpha-BHC ug/L ND 0.050 02/25/16 14:000.050
beta-BHC ug/L ND 0.050 02/25/16 14:000.050
Chlordane (Technical)ug/L ND 0.50 02/25/16 14:000.20
delta-BHC ug/L ND 0.050 02/25/16 14:000.050
Dieldrin ug/L ND 0.075 02/25/16 14:000.050
Endosulfan I ug/L ND 0.10 02/25/16 14:000.050
Endosulfan II ug/L ND 0.10 02/25/16 14:000.050
Endosulfan sulfate ug/L ND 0.10 02/25/16 14:000.050
Endrin ug/L ND 0.10 02/25/16 14:000.050
Endrin aldehyde ug/L ND 0.10 02/25/16 14:000.050
gamma-BHC (Lindane)ug/L ND 0.050 02/25/16 14:000.050
Heptachlor ug/L ND 0.050 02/25/16 14:000.050
Heptachlor epoxide ug/L ND 0.075 02/25/16 14:000.050
Methoxychlor ug/L ND 1.0 02/25/16 14:000.15
Toxaphene ug/L ND 1.5 02/25/16 14:000.20
Decachlorobiphenyl (S)%79 20-130 02/25/16 14:00
Tetrachloro-m-xylene (S)%87 20-130 02/25/16 14:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670372LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1670373
4,4'-DDD ug/L 0.22.25 90 20-150870.22 4 30
4,4'-DDE ug/L 0.21.25 83 20-150850.21 2 30
4,4'-DDT ug/L 0.24.25 95 20-150910.23 4 30
Aldrin ug/L 0.17.25 70 20-150680.17 3 30
alpha-BHC ug/L 0.21.25 84 20-150890.22 6 30
beta-BHC ug/L 0.23.25 92 20-1501000.25 8 30
delta-BHC ug/L 0.23.25 94 20-150990.25 6 30
Dieldrin ug/L 0.21.25 84 20-150860.21 2 30
Endosulfan I ug/L 0.22.25 89 20-150920.23 3 30
Endosulfan II ug/L 0.24.25 99 20-1501040.26 5 30
Endosulfan sulfate ug/L 0.25.25 102 20-1501070.26 4 30
Endrin ug/L 0.23.25 92 20-150930.23 1 30
Endrin aldehyde ug/L 0.23.25 92 20-150970.24 6 30
gamma-BHC (Lindane)ug/L 0.21.25 86 20-150900.22 5 30
Heptachlor ug/L 0.18.25 74 20-150680.17 8 30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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[phone]
Page 50 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670372LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1670373
Heptachlor epoxide ug/L 0.21.25 85 20-150870.21 2 30
Methoxychlor ug/L 0.82J.74 110 20-1501050.78J 5 30
Decachlorobiphenyl (S)%64 20-13063
Tetrachloro-m-xylene (S)%83 20-13086
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40920
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92287230001, 92287230002, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670374
Associated Lab Samples:92287230001, 92287230002, 92287230003
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 02/23/16 19:240.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 02/23/16 19:240.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 02/23/16 19:240.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 02/23/16 19:240.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 02/23/16 19:240.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 02/23/16 19:240.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 02/23/16 19:240.50
Decachlorobiphenyl (S)%68 10-132 02/23/16 19:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670375LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1670376
PCB-1016 (Aroclor 1016)ug/L 3.25 65 50-150834.1 24 30
PCB-1260 (Aroclor 1260)ug/L 3.95 79 50-150894.4 12 30
Decachlorobiphenyl (S)%54 10-13256
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 52 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/26719
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92287230001, 92287230002, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1487386
Associated Lab Samples:92287230001, 92287230002, 92287230003
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 02/25/16 05:250.042
2,4,5-TP (Silvex)ug/L ND 0.19 02/25/16 05:250.049
2,4-D ug/L ND 0.94 02/25/16 05:250.22
Dinoseb ug/L ND 0.19 02/25/16 05:250.057
2,4-DCAA (S)%100 36-130 02/25/16 05:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1487387LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 1.31.2 106 40-130
2,4,5-TP (Silvex)ug/L 1.21.2 100 58-130
2,4-D ug/L 6.16 101 42-134
Dinoseb ug/L 0.911.2 76 10-157
2,4-DCAA (S)%94 36-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1488050MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230002
1488051
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 2.7 103 40-13094 9 402.7ND 2.7 2.5
2,4,5-TP (Silvex)ug/L 2.7 104 58-13094 10 402.7ND 2.8 2.5
2,4-D ug/L 13.3 98 42-13489 9 4013.3ND 13.1 11.9
Dinoseb ug/L 2.7 81 10-15770 15 402.7ND 2.2 1.9
2,4-DCAA (S)%96 36-13085 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 53 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40984
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92287230001, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672159
Associated Lab Samples:92287230001, 92287230003
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 02/24/16 15:311.7
1,3,5-Trinitrobenzene ug/L ND 10.0 02/24/16 15:311.1
1,3-Dinitrobenzene ug/L ND 20.0 02/24/16 15:311.5
1,4-Naphthoquinone ug/L ND 10.0 02/24/16 15:311.8
1-Naphthalenamine ug/L ND 10.0 02/24/16 15:310.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 02/24/16 15:312.3
2,4,5-Trichlorophenol ug/L ND 10.0 02/24/16 15:312.2
2,4,6-Trichlorophenol ug/L ND 10.0 02/24/16 15:311.9
2,4-Dichlorophenol ug/L ND 10.0 02/24/16 15:311.7
2,4-Dimethylphenol ug/L ND 10.0 02/24/16 15:312.2
2,4-Dinitrophenol ug/L ND 50.0 02/24/16 15:316.5
2,4-Dinitrotoluene ug/L ND 10.0 02/24/16 15:311.2
2,6-Dichlorophenol ug/L ND 10.0 02/24/16 15:311.8
2,6-Dinitrotoluene ug/L ND 10.0 02/24/16 15:311.7
2-Acetylaminofluorene ug/L ND 20.0 02/24/16 15:310.84
2-Chloronaphthalene ug/L ND 10.0 02/24/16 15:312.2
2-Chlorophenol ug/L ND 10.0 02/24/16 15:311.5
2-Methylnaphthalene ug/L ND 10.0 02/24/16 15:310.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/24/16 15:311.7
2-Naphthalenamine ug/L ND 10.0 02/24/16 15:310.98
2-Nitroaniline ug/L ND 50.0 02/24/16 15:312.8
2-Nitrophenol ug/L ND 10.0 02/24/16 15:311.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/24/16 15:311.7
3,3'-Dichlorobenzidine ug/L ND 20.0 02/24/16 15:311.4
3,3'-Dimethylbenzidine ug/L ND 10.0 02/24/16 15:312.1
3-Methylcholanthrene ug/L ND 10.0 02/24/16 15:310.82
3-Nitroaniline ug/L ND 50.0 02/24/16 15:312.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 02/24/16 15:311.7
4-Aminobiphenyl ug/L ND 20.0 02/24/16 15:310.92
4-Bromophenylphenyl ether ug/L ND 10.0 02/24/16 15:311.3
4-Chloro-3-methylphenol ug/L ND 20.0 02/24/16 15:314.2
4-Chloroaniline ug/L ND 20.0 02/24/16 15:313.4
4-Chlorophenylphenyl ether ug/L ND 10.0 02/24/16 15:312.1
4-Nitroaniline ug/L ND 20.0 02/24/16 15:312.5
4-Nitrophenol ug/L ND 50.0 02/24/16 15:315.8
5-Nitro-o-toluidine ug/L ND 10.0 02/24/16 15:311.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 02/24/16 15:310.77
Acenaphthene ug/L ND 10.0 02/24/16 15:310.25
Acenaphthylene ug/L ND 10.0 02/24/16 15:310.21
Acetophenone ug/L ND 10.0 02/24/16 15:312.0
Anthracene ug/L ND 10.0 02/24/16 15:310.14
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 54 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672159
Associated Lab Samples:92287230001, 92287230003
Matrix: Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 02/24/16 15:310.33
Benzo(a)pyrene ug/L ND 10.0 02/24/16 15:310.30
Benzo(b)fluoranthene ug/L ND 10.0 02/24/16 15:310.28
Benzo(g,h,i)perylene ug/L ND 10.0 02/24/16 15:310.38
Benzo(k)fluoranthene ug/L ND 10.0 02/24/16 15:310.43
Benzyl alcohol ug/L ND 20.0 02/24/16 15:313.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/24/16 15:311.7
bis(2-Chloroethyl) ether ug/L ND 10.0 02/24/16 15:311.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 02/24/16 15:311.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 02/24/16 15:310.85
Butylbenzylphthalate ug/L ND 10.0 02/24/16 15:310.75
Chlorobenzilate ug/L ND 10.0 02/24/16 15:310.72
Chrysene ug/L ND 10.0 02/24/16 15:310.21
Di-n-butylphthalate ug/L ND 10.0 02/24/16 15:311.1
Di-n-octylphthalate ug/L ND 10.0 02/24/16 15:310.86
Diallate ug/L ND 10.0 02/24/16 15:311.3
Dibenz(a,h)anthracene ug/L ND 10.0 02/24/16 15:310.55
Dibenzofuran ug/L ND 10.0 02/24/16 15:311.8
Diethylphthalate ug/L ND 6000 02/24/16 15:311.3
Dimethoate ug/L ND 20.0 02/24/16 15:310.92
Dimethylphthalate ug/L ND 10.0 02/24/16 15:311.5
Diphenylamine ug/L ND 10.0 02/24/16 15:311.3
Disulfoton ug/L ND 10.0 02/24/16 15:311.4
Ethyl methanesulfonate ug/L ND 20.0 02/24/16 15:311.8
Famphur ug/L ND 20.0 02/24/16 15:311.7
Fluoranthene ug/L ND 10.0 02/24/16 15:310.21
Fluorene ug/L ND 10.0 02/24/16 15:310.21
Hexachloro-1,3-butadiene ug/L ND 10.0 02/24/16 15:311.8
Hexachlorobenzene ug/L ND 10.0 02/24/16 15:311.1
Hexachlorocyclopentadiene ug/L ND 10.0 02/24/16 15:311.8
Hexachloroethane ug/L ND 10.0 02/24/16 15:311.5
Hexachloropropene ug/L ND 10.0 02/24/16 15:311.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/24/16 15:310.29
Isodrin ug/L ND 20.0 02/24/16 15:312.0
Isophorone ug/L ND 10.0 02/24/16 15:311.8
Isosafrole ug/L ND 10.0 02/24/16 15:311.8
Kepone ug/L ND 20.0 02/24/16 15:313.1
Methapyrilene ug/L ND 100 02/24/16 15:312.7
Methyl methanesulfonate ug/L ND 10.0 02/24/16 15:311.3
Methyl parathion ug/L ND 10.0 02/24/16 15:311.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 02/24/16 15:312.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/24/16 15:312.1
N-Nitrosodiethylamine ug/L ND 20.0 02/24/16 15:311.8
N-Nitrosodimethylamine ug/L ND 10.0 02/24/16 15:311.3
N-Nitrosodiphenylamine ug/L ND 10.0 02/24/16 15:311.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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[phone]
Page 55 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672159
Associated Lab Samples:92287230001, 92287230003
Matrix: Water
AnalyzedMDL
N-Nitrosomethylethylamine ug/L ND 10.0 02/24/16 15:311.8
N-Nitrosopiperidine ug/L ND 20.0 02/24/16 15:311.9
N-Nitrosopyrrolidine ug/L ND 10.0 02/24/16 15:312.5
Nitrobenzene ug/L ND 10.0 02/24/16 15:311.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 02/24/16 15:311.8
O-Toluidine ug/L ND 10.0 02/24/16 15:311.6
P-Dimethylaminoazobenzene ug/L ND 10.0 02/24/16 15:310.35
p-Phenylenediamine ug/L ND 10.0 02/24/16 15:310.96
Parathion (Ethyl parathion)ug/L ND 10.0 02/24/16 15:311.1
Pentachlorobenzene ug/L ND 10.0 02/24/16 15:312.0
Pentachloronitrobenzene ug/L ND 20.0 02/24/16 15:311.0
Pentachlorophenol ug/L ND 25.0 02/24/16 15:312.3
Phenacetin ug/L ND 20.0 02/24/16 15:310.97
Phenanthrene ug/L ND 10.0 02/24/16 15:310.22
Phenol ug/L ND 10.0 02/24/16 15:311.7
Phorate ug/L ND 10.0 02/24/16 15:311.1
Pronamide ug/L ND 10.0 02/24/16 15:310.97
Pyrene ug/L ND 10.0 02/24/16 15:310.19
Safrole ug/L ND 10.0 02/24/16 15:311.5
Thionazin ug/L ND 20.0 02/24/16 15:311.2
2,4,6-Tribromophenol (S)%73 27-110 02/24/16 15:31
2-Fluorobiphenyl (S)%74 27-110 02/24/16 15:31
2-Fluorophenol (S)%38 12-110 02/24/16 15:31
Nitrobenzene-d5 (S)%62 21-110 02/24/16 15:31
Phenol-d6 (S)%26 10-110 02/24/16 15:31
Terphenyl-d14 (S)%97 31-107 02/24/16 15:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672160LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 35.250 70 16-129
1,3,5-Trinitrobenzene ug/L 34.450 69 55-125
1,3-Dinitrobenzene ug/L 41.850 84 30-122
1,4-Naphthoquinone ug/L 33.150 66 31-120
1-Naphthalenamine ug/L 32.650 65 37-126
2,3,4,6-Tetrachlorophenol ug/L 79.450 159 54-276
2,4,5-Trichlorophenol ug/L 36.950 74 43-113
2,4,6-Trichlorophenol ug/L 40.250 80 42-120
2,4-Dichlorophenol ug/L 36.550 73 30-120
2,4-Dimethylphenol ug/L 33.850 68 29-111
2,4-Dinitrophenol ug/L 125250 50 19-132
2,4-Dinitrotoluene ug/L 43.150 86 58-128
2,6-Dichlorophenol ug/L 35.850 72 54-128
2,6-Dinitrotoluene ug/L 45.150 90 54-129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672160LABORATORY CONTROL SAMPLE:
LCSSpike
2-Acetylaminofluorene ug/L 42.350 85 81-160
2-Chloronaphthalene ug/L 40.950 82 43-117
2-Chlorophenol ug/L 34.450 69 37-120
2-Methylnaphthalene ug/L 30.750 61 33-120
2-Methylphenol(o-Cresol)ug/L 27.650 55 31-120
2-Naphthalenamine ug/L 40.250 80 41-136
2-Nitroaniline ug/L 51.5100 51 48-121
2-Nitrophenol ug/L 35.650 71 25-116
3&4-Methylphenol(m&p Cresol)ug/L 22.550 45 23-120
3,3'-Dichlorobenzidine ug/L 88.5250 35 10-154
3,3'-Dimethylbenzidine ug/L 68.4100 68 10-157
3-Methylcholanthrene ug/L 45.950 92 65-130
3-Nitroaniline ug/L 75.4100 75 43-115
4,6-Dinitro-2-methylphenol ug/L 72.8100 73 44-124
4-Aminobiphenyl ug/L 32.550 65 21-125
4-Bromophenylphenyl ether ug/L 43.050 86 34-113
4-Chloro-3-methylphenol ug/L 71.6100 72 31-110
4-Chloroaniline ug/L 65.2100 65 20-120
4-Chlorophenylphenyl ether ug/L 41.550 83 34-116
4-Nitroaniline ug/L 74.0100 74 46-128
4-Nitrophenol ug/L 74.7250 30 11-120
5-Nitro-o-toluidine ug/L 43.150 86 78-160
7,12-Dimethylbenz(a)anthracene ug/L 44.950 90 47-124
Acenaphthene ug/L 33.950 68 48-114
Acenaphthylene ug/L 35.450 71 48-112
Acetophenone ug/L 32.750 65 24-120
Anthracene ug/L 36.750 73 57-118
Benzo(a)anthracene ug/L 42.050 84 56-121
Benzo(a)pyrene ug/L 40.250 80 55-127
Benzo(b)fluoranthene ug/L 40.850 82 53-128
Benzo(g,h,i)perylene ug/L 39.450 79 54-125
Benzo(k)fluoranthene ug/L 38.250 76 51-123
Benzyl alcohol ug/L 56.3100 56 27-120
bis(2-Chloroethoxy)methane ug/L 28.650 57 32-120
bis(2-Chloroethyl) ether ug/L 30.250 60 33-111
bis(2-Chloroisopropyl) ether ug/L 17.350 35 15-120
bis(2-Ethylhexyl)phthalate ug/L 44.250 88 50-145
Butylbenzylphthalate ug/L 46.550 93 54-138
Chlorobenzilate ug/L 45.750 91 65-132
Chrysene ug/L 41.250 82 58-127
Di-n-butylphthalate ug/L 42.350 85 56-125
Di-n-octylphthalate ug/L 40.250 80 50-134
Diallate ug/L 31.050 62 47-123
Dibenz(a,h)anthracene ug/L 36.550 73 53-129
Dibenzofuran ug/L 39.150 78 45-120
Diethylphthalate ug/L 40.4J50 81 53-120
Dimethoate ug/L 28.850 58 57-139
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672160LABORATORY CONTROL SAMPLE:
LCSSpike
Dimethylphthalate ug/L 40.150 80 55-116
Diphenylamine ug/L 35.750 71 42-120
Disulfoton ug/L 30.450 61 49-156
Ethyl methanesulfonate ug/L 28.950 58 43-120
Famphur ug/L 53.0100 53 40-160
Fluoranthene ug/L 38.650 77 57-125
Fluorene ug/L 39.450 79 53-118
Hexachloro-1,3-butadiene ug/L 29.250 58 23-120
Hexachlorobenzene ug/L 44.050 88 49-116
Hexachlorocyclopentadiene ug/L 24.950 50 26-158
Hexachloroethane ug/L 27.650 55 30-114
Hexachloropropene ug/L 23.250 46 13-137
Indeno(1,2,3-cd)pyrene ug/L 44.150 88 55-128
Isodrin ug/L 41.050 82 68-129
Isophorone ug/L 27.550 55 31-118
Isosafrole ug/L 41.350 83 48-107
Kepone ug/L ND L01000 10-124
Methapyrilene ug/L 33.3J50 67 40-160
Methyl methanesulfonate ug/L 24.150 48 25-114
Methyl parathion ug/L 36.950 74 58-137
N-Nitroso-di-n-butylamine ug/L 26.150 52 36-115
N-Nitroso-di-n-propylamine ug/L 27.650 55 32-119
N-Nitrosodiethylamine ug/L 34.450 69 47-115
N-Nitrosodimethylamine ug/L 17.650 35 13-120
N-Nitrosodiphenylamine ug/L 35.750 71 43-120
N-Nitrosomethylethylamine ug/L 30.450 61 39-120
N-Nitrosopiperidine ug/L 36.850 74 43-113
N-Nitrosopyrrolidine ug/L 33.350 67 32-110
Nitrobenzene ug/L 26.750 53 33-110
O,O,O-Triethylphosphorothioate ug/L 38.850 78 51-127
O-Toluidine ug/L 32.750 65 27-120
P-Dimethylaminoazobenzene ug/L 21.9100 22 10-120
p-Phenylenediamine ug/L 37.850 76 72-143
Parathion (Ethyl parathion)ug/L 36.050 72 56-140
Pentachlorobenzene ug/L 41.850 84 30-137
Pentachloronitrobenzene ug/L 48.550 97 70-124
Pentachlorophenol ug/L 64.5250 26 10-137
Phenacetin ug/L 35.650 71 60-130
Phenanthrene ug/L 36.650 73 57-117
Phenol ug/L 15.750 31 10-120
Phorate ug/L 31.450 63 55-126
Pronamide ug/L 42.650 85 75-124
Pyrene ug/L 38.750 77 55-122
Safrole ug/L 34.450 69 41-120
Thionazin ug/L 39.250 78 63-137
2,4,6-Tribromophenol (S)%96 27-110
2-Fluorobiphenyl (S)%69 27-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672160LABORATORY CONTROL SAMPLE:
LCSSpike
2-Fluorophenol (S)%37 12-110
Nitrobenzene-d5 (S)%57 21-110
Phenol-d6 (S)%26 10-110
Terphenyl-d14 (S)%89 31-107
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672161MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287435001
1672162
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4,5-Tetrachlorobenzene ug/L 100 78 50-15083 5 30100ND78.4 82.5
1,3,5-Trinitrobenzene ug/L 100 69 50-15073 6 30100ND69.3 73.3
1,3-Dinitrobenzene ug/L 100 88 50-15089 2 30100ND87.6 89.1
1,4-Naphthoquinone ug/L 100 72 50-15077 7 30100ND71.8 76.8
1-Naphthalenamine ug/L 100 67 50-15067 0 30100ND67.4 67.4
2,3,4,6-Tetrachlorophenol ug/L M110017850-150181 1 30100ND178 181
2,4,5-Trichlorophenol ug/L 100 83 19-10584 1 30100ND83.1 83.8
2,4,6-Trichlorophenol ug/L 100 89 13-10893 4 30100ND89.1 92.9
2,4-Dichlorophenol ug/L 100 84 29-11185 2 30100ND83.6 85.2
2,4-Dimethylphenol ug/L 100 78 21-10380 2 30100ND77.8 79.5
2,4-Dinitrophenol ug/L 500 76 10-10975 1 30500ND379 375
2,4-Dinitrotoluene ug/L 100 90 27-10490 1 30100ND89.7 90.2
2,6-Dichlorophenol ug/L 100 80 50-15083 3 30100ND80.4 82.6
2,6-Dinitrotoluene ug/L 100 94 28-10195 1 30100ND93.8 94.8
2-Acetylaminofluorene ug/L 100 89 50-15096 8 30100ND88.9 96.2
2-Chloronaphthalene ug/L 100 86 14-10295 11 30100ND85.5 95.4
2-Chlorophenol ug/L 100 80 16-11083 3 30100ND80.3 83.1
2-Methylnaphthalene ug/L 100 69 13-11071 4 30100ND68.6 71.4
2-Methylphenol(o-Cresol) ug/L 100 69 19-11072 4 30100ND69.3 71.8
2-Naphthalenamine ug/L 100 65 50-15068 5 30100ND64.6 67.7
2-Nitroaniline ug/L 200 56 26-10357 1 30200ND112 113
2-Nitrophenol ug/L 100 81 20-11084 3 30100ND81.2 83.6
3&4-Methylphenol(m&pCresol)ug/L 100 60 20-11061 2 30100ND60.5 61.5
3,3'-Dichlorobenzidine ug/L 500 36 25-11237 3 30500ND181 186
3,3'-Dimethylbenzidine ug/L 200 51 50-15053 4 30200ND103 107
3-Methylcholanthrene ug/L 100 97 50-15098 1 30100ND96.9 97.7
3-Nitroaniline ug/L 200 82 29-11080 2 30200ND164 160
4,6-Dinitro-2-methylphenol ug/L 200 84 10-11783 0 30200ND168 167
4-Aminobiphenyl ug/L 100 65 50-15066 2 30100ND64.8 66.3
4-Bromophenylphenyl ether ug/L 100 89 20-10590 1 30100ND88.7 89.8
4-Chloro-3-methylphenol ug/L 200 81 22-11082 2 30200ND161 165
4-Chloroaniline ug/L 200 74 20-10075 2 30200ND147 151
4-Chlorophenylphenyl ether ug/L 100 88 19-10291 4 30100ND87.6 91.1
4-Nitroaniline ug/L 200 79 29-11079 0 30200ND159 159
4-Nitrophenol ug/L 500 49 10-11048 2 30500ND243 238
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672161MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287435001
1672162
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
5-Nitro-o-toluidine ug/L 100 91 50-15090 1 30100ND91.2 90.5
7,12-
Dimethylbenz(a)anthracene ug/L 100 94 50-15093 1 30100ND93.7 92.5
Acenaphthene ug/L 100 74 17-10076 3 30100ND74.0 76.5
Acenaphthylene ug/L 100 77 21-10079 3 30100ND77.1 79.1
Acetophenone ug/L 100 73 50-15075 3 30100ND73.1 75.3
Anthracene ug/L 100 77 24-10976 1 30100ND77.0 76.1
Benzo(a)anthracene ug/L 100 88 22-11788 0 30100ND87.8 87.6
Benzo(a)pyrene ug/L 100 85 23-10485 1 30100ND84.9 85.5
Benzo(b)fluoranthene ug/L 100 85 23-10386 1 30100ND84.6 85.5
Benzo(g,h,i)perylene ug/L 100 85 18-11182 4 30100ND85.3 81.9
Benzo(k)fluoranthene ug/L 100 78 22-11381 4 30100ND77.6 80.7
Benzyl alcohol ug/L 200 71 19-10173 3 30200ND142 146
bis(2-Chloroethoxy)methane ug/L 100 65 22-11066 1 30100ND64.6 65.6
bis(2-Chloroethyl) ether ug/L 100 67 16-11069 4 30100ND66.7 69.4
bis(2-Chloroisopropyl) ether ug/L 100 38 14-11039 2 30100ND38.1 38.9
bis(2-Ethylhexyl)phthalate ug/L 100 92 23-10291 2 30100ND92.2 90.8
Butylbenzylphthalate ug/L 100 97 25-11095 2 30100ND96.6 94.7
Chlorobenzilate ug/L 100 93 50-15091 2 30100ND92.8 91.0
Chrysene ug/L 100 86 23-11586 1 30100ND86.3 85.7
Di-n-butylphthalate ug/L 100 87 26-11088 1 30100ND86.7 87.8
Di-n-octylphthalate ug/L 100 85 22-11086 2 30100ND84.8 86.2
Diallate ug/L 100 62 50-15064 3 30100ND62.3 64.4
Dibenz(a,h)anthracene ug/L 100 84 21-11282 3 30100ND84.4 81.6
Dibenzofuran ug/L 100 87 19-10288 1 30100ND87.1 87.9
Diethylphthalate ug/L 100 86 29-11086 1 30100ND86.2J 85.7J
Dimethoate ug/L 100 62 50-15064 3 30100ND61.8 64.0
Dimethylphthalate ug/L 100 84 27-11084 0 30100ND84.2 84.4
Diphenylamine ug/L 100 74 50-15074 1 30100ND74.3 73.5
Disulfoton ug/L 100 61 50-15062 1 30100ND61.4 62.1
Ethyl methanesulfonate ug/L 100 66 50-15069 4 30100ND65.6 68.6
Famphur ug/L 200 66 50-15063 5 30200ND131 126
Fluoranthene ug/L 100 79 23-11280 2 30100ND78.7 80.5
Fluorene ug/L 100 84 22-10484 1 30100ND83.6 84.3
Hexachloro-1,3-butadiene ug/L 100 67 10-11068 2 30100ND66.7 68.0
Hexachlorobenzene ug/L 100 89 21-11691 2 30100ND89.3 91.4
Hexachlorocyclopentadiene ug/L 100 61 10-11066 9 30100ND60.6 66.2
Hexachloroethane ug/L 100 63 10-11064 2 30100ND62.9 63.9
Hexachloropropene ug/L 100 59 50-15062 6 30100ND58.8 62.4
Indeno(1,2,3-cd)pyrene ug/L 100 94 20-11393 1 30100ND93.8 93.0
Isodrin ug/L 100 82 50-15086 4 30100ND82.4 86.1
Isophorone ug/L 100 62 50-15063 2 30100ND61.6 62.7
Isosafrole ug/L 100 91 50-15093 3 30100ND90.7 93.4
Kepone ug/L M0200050-1500 30200NDND ND
Methapyrilene ug/L 100 57 50-15062 30100ND57.4J 62.2J
Methyl methanesulfonate ug/L 100 61 50-15061 1 30100ND60.7 61.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672161MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287435001
1672162
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl parathion ug/L 100 77 50-15079 2 30100ND77.2 78.7
N-Nitroso-di-n-butylamine ug/L 100 57 50-15060 5 30100ND56.8 59.7
N-Nitroso-di-n-propylamine ug/L 100 65 21-10567 3 30100ND64.8 66.5
N-Nitrosodiethylamine ug/L 100 78 50-15079 2 30100ND77.5 79.0
N-Nitrosodimethylamine ug/L 100 50 10-11051 2 30100ND49.6 50.5
N-Nitrosodiphenylamine ug/L 100 74 23-10774 1 30100ND74.3 73.5
N-Nitrosomethylethylamine ug/L 100 71 50-15075 5 30100ND71.0 74.6
N-Nitrosopiperidine ug/L 100 82 50-15085 4 30100ND81.7 84.7
N-Nitrosopyrrolidine ug/L 100 83 50-15085 3 30100ND83.0 85.2
Nitrobenzene ug/L 100 57 20-11058 2 30100ND57.3 58.3
O,O,O-
Triethylphosphorothioate ug/L 100 85 50-15089 5 30100ND85.0 89.1
O-Toluidine ug/L 100 73 50-15077 5 30100ND73.3 77.0
P-Dimethylaminoazobenzene ug/L M12002250-15021 4 30200ND44.1 42.6
p-Phenylenediamine ug/L 100 84 50-15086 2 30100ND83.9 85.6
Parathion (Ethyl parathion) ug/L 100 73 50-15077 5 30100ND73.5 77.0
Pentachlorobenzene ug/L 100 90 50-15094 5 30100ND89.7 93.9
Pentachloronitrobenzene ug/L 100 102 50-150102 1 30100ND102 102
Pentachlorophenol ug/L 500 31 10-11832 2 30500ND156 160
Phenacetin ug/L 100 75 50-15077 3 30100ND75.1 77.3
Phenanthrene ug/L 100 75 24-10675 0 30100ND75.2 74.9
Phenol ug/L 100 47 12-11050 5 30100ND47.4 49.6
Phorate ug/L 100 63 50-15064 1 30100ND62.8 63.6
Pronamide ug/L 100 88 50-15088 0 30100ND88.1 87.9
Pyrene ug/L 100 79 24-11476 4 30100ND78.9 75.6
Safrole ug/L 100 77 50-15079 2 30100ND77.5 79.2
Thionazin ug/L 100 80 50-15082 2 30100ND79.9 81.5
2,4,6-Tribromophenol (S)%101 27-110104
2-Fluorobiphenyl (S)%75 27-11078
2-Fluorophenol (S)%50 12-11053
Nitrobenzene-d5 (S)%62 21-11064
Phenol-d6 (S)%40 10-11042
Terphenyl-d14 (S)%75 31-10775
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/41013
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92287230002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673497
Associated Lab Samples:92287230002
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 02/26/16 14:111.7
1,3,5-Trinitrobenzene ug/L ND 10.0 02/26/16 14:111.1
1,3-Dinitrobenzene ug/L ND 20.0 02/26/16 14:111.5
1,4-Naphthoquinone ug/L ND 10.0 02/26/16 14:111.8
1-Naphthalenamine ug/L ND 10.0 02/26/16 14:110.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 02/26/16 14:112.3
2,4,5-Trichlorophenol ug/L ND 10.0 02/26/16 14:112.2
2,4,6-Trichlorophenol ug/L ND 10.0 02/26/16 14:111.9
2,4-Dichlorophenol ug/L ND 10.0 02/26/16 14:111.7
2,4-Dimethylphenol ug/L ND 10.0 02/26/16 14:112.2
2,4-Dinitrophenol ug/L ND 50.0 02/26/16 14:116.5
2,4-Dinitrotoluene ug/L ND 10.0 02/26/16 14:111.2
2,6-Dichlorophenol ug/L ND 10.0 02/26/16 14:111.8
2,6-Dinitrotoluene ug/L ND 10.0 02/26/16 14:111.7
2-Acetylaminofluorene ug/L ND 20.0 02/26/16 14:110.84
2-Chloronaphthalene ug/L ND 10.0 02/26/16 14:112.2
2-Chlorophenol ug/L ND 10.0 02/26/16 14:111.5
2-Methylnaphthalene ug/L ND 10.0 02/26/16 14:110.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/26/16 14:111.7
2-Naphthalenamine ug/L ND 10.0 02/26/16 14:110.98
2-Nitroaniline ug/L ND 50.0 02/26/16 14:112.8
2-Nitrophenol ug/L ND 10.0 02/26/16 14:111.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/26/16 14:111.7
3,3'-Dichlorobenzidine ug/L ND 20.0 02/26/16 14:111.4
3,3'-Dimethylbenzidine ug/L ND 10.0 02/26/16 14:112.1
3-Methylcholanthrene ug/L ND 10.0 02/26/16 14:110.82
3-Nitroaniline ug/L ND 50.0 02/26/16 14:112.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 02/26/16 14:111.7
4-Aminobiphenyl ug/L ND 20.0 02/26/16 14:110.92
4-Bromophenylphenyl ether ug/L ND 10.0 02/26/16 14:111.3
4-Chloro-3-methylphenol ug/L ND 20.0 02/26/16 14:114.2
4-Chloroaniline ug/L ND 20.0 02/26/16 14:113.4
4-Chlorophenylphenyl ether ug/L ND 10.0 02/26/16 14:112.1
4-Nitroaniline ug/L ND 20.0 02/26/16 14:112.5
4-Nitrophenol ug/L ND 50.0 02/26/16 14:115.8
5-Nitro-o-toluidine ug/L ND 10.0 02/26/16 14:111.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 02/26/16 14:110.77
Acenaphthene ug/L ND 10.0 02/26/16 14:110.25
Acenaphthylene ug/L ND 10.0 02/26/16 14:110.21
Acetophenone ug/L ND 10.0 02/26/16 14:112.0
Anthracene ug/L ND 10.0 02/26/16 14:110.14
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Huntersville, NC 28078
[phone]
Page 62 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673497
Associated Lab Samples:92287230002
Matrix: Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 02/26/16 14:110.33
Benzo(a)pyrene ug/L ND 10.0 02/26/16 14:110.30
Benzo(b)fluoranthene ug/L ND 10.0 02/26/16 14:110.28
Benzo(g,h,i)perylene ug/L ND 10.0 02/26/16 14:110.38
Benzo(k)fluoranthene ug/L ND 10.0 02/26/16 14:110.43
Benzyl alcohol ug/L ND 20.0 02/26/16 14:113.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/26/16 14:111.7
bis(2-Chloroethyl) ether ug/L ND 10.0 02/26/16 14:111.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 02/26/16 14:111.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 02/26/16 14:110.85
Butylbenzylphthalate ug/L ND 10.0 02/26/16 14:110.75
Chlorobenzilate ug/L ND 10.0 02/26/16 14:110.72
Chrysene ug/L ND 10.0 02/26/16 14:110.21
Di-n-butylphthalate ug/L ND 10.0 02/26/16 14:111.1
Di-n-octylphthalate ug/L ND 10.0 02/26/16 14:110.86
Diallate ug/L ND 10.0 02/26/16 14:111.3
Dibenz(a,h)anthracene ug/L ND 10.0 02/26/16 14:110.55
Dibenzofuran ug/L ND 10.0 02/26/16 14:111.8
Diethylphthalate ug/L ND 6000 02/26/16 14:111.3
Dimethoate ug/L ND 20.0 02/26/16 14:110.92
Dimethylphthalate ug/L ND 10.0 02/26/16 14:111.5
Diphenylamine ug/L ND 10.0 02/26/16 14:111.3
Disulfoton ug/L ND 10.0 02/26/16 14:111.4
Ethyl methanesulfonate ug/L ND 20.0 02/26/16 14:111.8
Famphur ug/L ND 20.0 02/26/16 14:111.7
Fluoranthene ug/L ND 10.0 02/26/16 14:110.21
Fluorene ug/L ND 10.0 02/26/16 14:110.21
Hexachloro-1,3-butadiene ug/L ND 10.0 02/26/16 14:111.8
Hexachlorobenzene ug/L ND 10.0 02/26/16 14:111.1
Hexachlorocyclopentadiene ug/L ND 10.0 02/26/16 14:111.8
Hexachloroethane ug/L ND 10.0 02/26/16 14:111.5
Hexachloropropene ug/L ND 10.0 02/26/16 14:111.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/26/16 14:110.29
Isodrin ug/L ND 20.0 02/26/16 14:112.0
Isophorone ug/L ND 10.0 02/26/16 14:111.8
Isosafrole ug/L ND 10.0 02/26/16 14:111.8
Kepone ug/L ND 20.0 02/26/16 14:113.1
Methapyrilene ug/L ND 100 02/26/16 14:112.7
Methyl methanesulfonate ug/L ND 10.0 02/26/16 14:111.3
Methyl parathion ug/L ND 10.0 02/26/16 14:111.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 02/26/16 14:112.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/26/16 14:112.1
N-Nitrosodiethylamine ug/L ND 20.0 02/26/16 14:111.8
N-Nitrosodimethylamine ug/L ND 10.0 02/26/16 14:111.3
N-Nitrosodiphenylamine ug/L ND 10.0 02/26/16 14:111.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 63 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673497
Associated Lab Samples:92287230002
Matrix: Water
AnalyzedMDL
N-Nitrosomethylethylamine ug/L ND 10.0 02/26/16 14:111.8
N-Nitrosopiperidine ug/L ND 20.0 02/26/16 14:111.9
N-Nitrosopyrrolidine ug/L ND 10.0 02/26/16 14:112.5
Nitrobenzene ug/L ND 10.0 02/26/16 14:111.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 02/26/16 14:111.8
O-Toluidine ug/L ND 10.0 02/26/16 14:111.6
P-Dimethylaminoazobenzene ug/L ND 10.0 02/26/16 14:110.35
p-Phenylenediamine ug/L ND 10.0 02/26/16 14:110.96
Parathion (Ethyl parathion)ug/L ND 10.0 02/26/16 14:111.1
Pentachlorobenzene ug/L ND 10.0 02/26/16 14:112.0
Pentachloronitrobenzene ug/L ND 20.0 02/26/16 14:111.0
Pentachlorophenol ug/L ND 25.0 02/26/16 14:112.3
Phenacetin ug/L ND 20.0 02/26/16 14:110.97
Phenanthrene ug/L ND 10.0 02/26/16 14:110.22
Phenol ug/L ND 10.0 02/26/16 14:111.7
Phorate ug/L ND 10.0 02/26/16 14:111.1
Pronamide ug/L ND 10.0 02/26/16 14:110.97
Pyrene ug/L ND 10.0 02/26/16 14:110.19
Safrole ug/L ND 10.0 02/26/16 14:111.5
Thionazin ug/L ND 20.0 02/26/16 14:111.2
2,4,6-Tribromophenol (S)%28 27-110 02/26/16 14:11
2-Fluorobiphenyl (S)%68 27-110 02/26/16 14:11
2-Fluorophenol (S)%17 12-110 02/26/16 14:11
Nitrobenzene-d5 (S)%67 21-110 02/26/16 14:11
Phenol-d6 (S)%19 10-110 02/26/16 14:11
Terphenyl-d14 (S)%91 31-107 02/26/16 14:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673498LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1673499
1,2,4,5-Tetrachlorobenzene ug/L 20.5 R1504116-1296833.8 49 30
1,3,5-Trinitrobenzene ug/L 53.450 107 55-12511858.9 10 30
1,3-Dinitrobenzene ug/L 42.150 84 30-1228643.0 2 30
1,4-Naphthoquinone ug/L 30.750 61 31-1207035.1 13 30
1-Naphthalenamine ug/L 31.150 62 37-1265929.7 5 30
2,3,4,6-Tetrachlorophenol ug/L 86.950 174 54-27618190.3 4 30
2,4,5-Trichlorophenol ug/L 35.550 71 43-1138140.7 14 30
2,4,6-Trichlorophenol ug/L 35.450 71 42-1208944.4 23 30
2,4-Dichlorophenol ug/L 21.1 R1504230-1206733.7 46 30
2,4-Dimethylphenol ug/L 21.0 R1504229-1116833.8 47 30
2,4-Dinitrophenol ug/L 204 R12508119-132115288 34 30
2,4-Dinitrotoluene ug/L 43.850 88 58-1288843.8 0 30
2,6-Dichlorophenol ug/L 20.0 L0,R1504054-1286130.3 41 30
2,6-Dinitrotoluene ug/L 41.450 83 54-1298643.2 4 30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 64 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673498LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1673499
2-Acetylaminofluorene ug/L 44.750 89 81-1608743.6 3 30
2-Chloronaphthalene ug/L 29.9 R1506043-1178844.1 38 30
2-Chlorophenol ug/L 19.7 R1503937-1206632.8 50 30
2-Methylnaphthalene ug/L 20.0 R1504033-1206230.9 43 30
2-Methylphenol(o-Cresol)ug/L 18.5 R1503731-1206130.4 49 30
2-Naphthalenamine ug/L 37.850 76 41-1367236.0 5 30
2-Nitroaniline ug/L 79.2100 79 48-1218483.9 6 30
2-Nitrophenol ug/L 19.9 R1504025-1166833.8 52 30
3&4-Methylphenol(m&p Cresol)ug/L 40.9 L0,R1508223-12012562.5 42 30
3,3'-Dichlorobenzidine ug/L 102250 41 10-1543998.4 4 30
3,3'-Dimethylbenzidine ug/L 74.6100 75 10-1576767.3 10 30
3-Methylcholanthrene ug/L 44.850 90 65-1308844.0 2 30
3-Nitroaniline ug/L 81.5100 82 43-1157979.3 3 30
4,6-Dinitro-2-methylphenol ug/L 74.8100 75 44-1247777.3 3 30
4-Aminobiphenyl ug/L 37.350 75 21-1257035.2 6 30
4-Bromophenylphenyl ether ug/L 35.150 70 34-1137236.1 3 30
4-Chloro-3-methylphenol ug/L 63.7100 64 31-1107373.1 14 30
4-Chloroaniline ug/L 43.6 R11004420-1206261.7 34 30
4-Chlorophenylphenyl ether ug/L 35.350 71 34-1168039.9 12 30
4-Nitroaniline ug/L 86.5100 86 46-1288585.4 1 30
4-Nitrophenol ug/L 96.2250 38 11-12041103 7 30
5-Nitro-o-toluidine ug/L 50.050 100 78-16010050.1 0 30
7,12-Dimethylbenz(a)anthracene ug/L 46.850 94 47-1249346.3 1 30
Acenaphthene ug/L 27.950 56 48-1147235.8 25 30
Acenaphthylene ug/L 29.050 58 48-1127437.1 24 30
Acetophenone ug/L 24.5 R1504924-1207637.9 43 30
Anthracene ug/L 35.850 72 57-1187135.6 0 30
Benzo(a)anthracene ug/L 44.050 88 56-1218542.7 3 30
Benzo(a)pyrene ug/L 43.650 87 55-1278643.0 1 30
Benzo(b)fluoranthene ug/L 49.750 99 53-12810049.9 0 30
Benzo(g,h,i)perylene ug/L 39.650 79 54-1257939.6 0 30
Benzo(k)fluoranthene ug/L 39.950 80 51-1237939.4 1 30
Benzyl alcohol ug/L 36.5 R11003727-1205959.2 47 30
bis(2-Chloroethoxy)methane ug/L 19.4 R1503932-1206432.0 49 30
bis(2-Chloroethyl) ether ug/L 21.3 R1504333-1116834.1 46 30
bis(2-Chloroisopropyl) ether ug/L 18.6 R1503715-1206130.6 49 30
bis(2-Ethylhexyl)phthalate ug/L 48.650 97 50-1459346.7 4 30
Butylbenzylphthalate ug/L 53.950 108 54-13810552.3 3 30
Chlorobenzilate ug/L 42.550 85 65-1328542.3 1 30
Chrysene ug/L 40.750 81 58-1278040.1 1 30
Di-n-butylphthalate ug/L 43.050 86 56-1258442.2 2 30
Di-n-octylphthalate ug/L 42.950 86 50-1348341.5 3 30
Diallate ug/L 37.750 75 47-1237638.1 1 30
Dibenz(a,h)anthracene ug/L 42.350 85 53-1298542.5 0 30
Dibenzofuran ug/L 32.550 65 45-1207638.2 16 30
Diethylphthalate ug/L 42.0J50 84 53-1208442.1J 0 30
Dimethoate ug/L 38.850 78 57-1397839.2 1 30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Huntersville, NC 28078
[phone]
Page 65 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673498LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1673499
Dimethylphthalate ug/L 39.950 80 55-1168241.2 3 30
Diphenylamine ug/L 35.850 72 42-1207236.0 1 30
Disulfoton ug/L 39.650 79 49-1567738.6 2 30
Ethyl methanesulfonate ug/L 22.8 R1504643-1207336.6 47 30
Famphur ug/L 59.4100 59 40-1606564.9 9 30
Fluoranthene ug/L 38.450 77 57-1257638.0 1 30
Fluorene ug/L 36.750 73 53-1188140.3 9 30
Hexachloro-1,3-butadiene ug/L 17.1 R1503423-1205929.3 52 30
Hexachlorobenzene ug/L 35.650 71 49-1167236.0 1 30
Hexachlorocyclopentadiene ug/L 18.2 R1503626-1587034.9 63 30
Hexachloroethane ug/L 21.9 R1504430-1147035.0 46 30
Hexachloropropene ug/L 14.0 R1502813-1374623.1 49 30
Indeno(1,2,3-cd)pyrene ug/L 44.950 90 55-1288944.7 0 30
Isodrin ug/L 43.250 86 68-1298542.7 1 30
Isophorone ug/L 20.3 R1504131-1186532.4 46 30
Isosafrole ug/L 29.5 R1505948-1078442.1 35 30
Kepone ug/L 113100 113 10-124118118 5 30
Methapyrilene ug/L 46.0J50 92 40-1608944.7J 30
Methyl methanesulfonate ug/L 17.5 R1503525-1145527.6 45 30
Methyl parathion ug/L 41.350 83 58-1378240.8 1 30
N-Nitroso-di-n-butylamine ug/L 20.450 41 36-1155125.7 23 30
N-Nitroso-di-n-propylamine ug/L 25.0 R1505032-1197939.3 44 30
N-Nitrosodiethylamine ug/L 24.1 R1504847-1157637.9 45 30
N-Nitrosodimethylamine ug/L 12.8 R1502613-1204120.3 45 30
N-Nitrosodiphenylamine ug/L 35.850 72 43-1207236.0 1 30
N-Nitrosomethylethylamine ug/L 21.9 R1504439-1207135.7 48 30
N-Nitrosopiperidine ug/L 21.7 R1504343-1136432.1 39 30
N-Nitrosopyrrolidine ug/L 27.2 R1505432-1107638.2 34 30
Nitrobenzene ug/L 19.6 R1503933-1106331.3 46 30
O,O,O-Triethylphosphorothioate ug/L 17.4 L0,R1503551-1275627.9 47 30
O-Toluidine ug/L 23.3 R1504727-1206934.5 39 30
P-Dimethylaminoazobenzene ug/L 19.4100 19 10-1201918.9 2 30
p-Phenylenediamine ug/L 39.950 80 72-1437437.1 7 30
Parathion (Ethyl parathion)ug/L 39.650 79 56-1407738.7 2 30
Pentachlorobenzene ug/L 29.650 59 30-1377236.1 20 30
Pentachloronitrobenzene ug/L 49.150 98 70-1249748.6 1 30
Pentachlorophenol ug/L 81.9250 33 10-1373485.0 4 30
Phenacetin ug/L 41.650 83 60-1308441.8 1 30
Phenanthrene ug/L 35.950 72 57-1177135.6 1 30
Phenol ug/L 10.4 R1502110-1203417.1 49 30
Phorate ug/L 44.050 88 55-1268441.8 5 30
Pronamide ug/L 48.150 96 75-1249647.8 1 30
Pyrene ug/L 39.750 79 55-1227738.6 3 30
Safrole ug/L 18.2 L0,R1503641-1205527.6 41 30
Thionazin ug/L 43.650 87 63-1378643.1 1 30
2,4,6-Tribromophenol (S)%87 27-11085
2-Fluorobiphenyl (S)%47 27-11071
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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[phone]
Page 66 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673498LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1673499
2-Fluorophenol (S)%23 12-11038
Nitrobenzene-d5 (S)%41 21-11065
Phenol-d6 (S)%16 10-11027
Terphenyl-d14 (S)%85 31-10780
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Huntersville, NC 28078
[phone]
Page 67 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43210
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672086
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/25/16 14:361000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672087LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 5000050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672088MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287453001
1672089
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 94 80-120103 9 2550000ND48600 53300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672090MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230002
1672091
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 103 80-120110 2 2550000141000192000 196000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
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Page 68 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43175
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670521
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 02/22/16 15:4825000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670522LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 244000250000 98 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287225001
1670523SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287230005
1670524SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 138000 1 5140000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 02:59 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43167
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92287230001, 92287230002, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670316
Associated Lab Samples:92287230001, 92287230002, 92287230003
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/20/16 12:10100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670317LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 520J500 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670318MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287091001
1670319
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 97 90-11097 0 10500ND486J 486J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670320MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287257002
1670321
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 94 90-11094 0 10500ND470J 470J
REPORT OF LABORATORY ANALYSIS
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Page 70 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26506
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670412
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 02/22/16 15:531000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670413LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670414MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
30174071001
1670415
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 0 1034200J 34200J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670416MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230001
1670417
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 104 90-110105 0 102000039300J60100J 60300J
REPORT OF LABORATORY ANALYSIS
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Page 71 of 78
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26557
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673098
Associated Lab Samples:92287230001, 92287230002, 92287230003, 92287230004, 92287230005, 92287230006, 92287230007
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/25/16 20:07500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673099LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2010020000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673100MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287020003
1673101
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011190-110112 0 101000012.6 mg/L 23800 23900
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673102MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287285001
1673103
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M1500004190-11042 0 1050000105 mg/L 126000 126000
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26537
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92287230001, 92287230002, 92287230003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672186
Associated Lab Samples:92287230001, 92287230002, 92287230003
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 02/24/16 16:264.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672187LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 104100 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672188MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287213005
1672189
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1,R11003175-12527 11 101000.011
mg/L 42.1 37.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672190MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287087001
1672191
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 86 75-12584 1 10100ND89.5 88.3
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associatedsamples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.
Results unaffected by high bias.S3
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92287230001 OEXT/40919 GCSV/241683901-MW7 EPA 3510 EPA 8081
92287230002 OEXT/40919 GCSV/241683901-MW5R EPA 3510 EPA 8081
92287230003 OEXT/40919 GCSV/241683901-FIELD BLANK EPA 3510 EPA 8081
92287230001 OEXT/40920 GCSV/241693901-MW7 EPA 3510 EPA 8082
92287230002 OEXT/40920 GCSV/241693901-MW5R EPA 3510 EPA 8082
92287230003 OEXT/40920 GCSV/241693901-FIELD BLANK EPA 3510 EPA 8082
92287230001 OEXT/26719 GCSV/173853901-MW7 EPA 8151 EPA 8151
92287230002 OEXT/26719 GCSV/173853901-MW5R EPA 8151 EPA 8151
92287230003 OEXT/26719 GCSV/173853901-FIELD BLANK EPA 8151 EPA 8151
92287230001 MPRP/20758 ICP/187113901-MW7 EPA 3010A EPA 6010
92287230002 MPRP/20758 ICP/187113901-MW5R EPA 3010A EPA 6010
92287230003 MPRP/20758 ICP/187113901-FIELD BLANK EPA 3010A EPA 6010
92287230004 MPRP/20758 ICP/187113901-MW2 EPA 3010A EPA 6010
92287230005 MPRP/20758 ICP/187113901-MW3R EPA 3010A EPA 6010
92287230006 MPRP/20758 ICP/187113901-MW4R EPA 3010A EPA 6010
92287230007 MPRP/20758 ICP/187113901-MW6R EPA 3010A EPA 6010
92287230008 MPRP/20758 ICP/187113901-SW1 EPA 3010A EPA 6010
92287230009 MPRP/20758 ICP/187113901-SW2 EPA 3010A EPA 6010
92287230001 MERP/9017 MERC/86653901-MW7 EPA 7470 EPA 7470
92287230002 MERP/9017 MERC/86653901-MW5R EPA 7470 EPA 7470
92287230003 MERP/9017 MERC/86653901-FIELD BLANK EPA 7470 EPA 7470
92287230004 MERP/9017 MERC/86653901-MW2 EPA 7470 EPA 7470
92287230005 MERP/9017 MERC/86653901-MW3R EPA 7470 EPA 7470
92287230006 MERP/9017 MERC/86653901-MW4R EPA 7470 EPA 7470
92287230007 MERP/9017 MERC/86653901-MW6R EPA 7470 EPA 7470
92287230001 OEXT/40984 MSSV/119153901-MW7 EPA 3510 EPA 8270
92287230002 OEXT/41013 MSSV/119223901-MW5R EPA 3510 EPA 8270
92287230003 OEXT/40984 MSSV/119153901-FIELD BLANK EPA 3510 EPA 8270
92287230001 MSV/356663901-MW7 EPA 8260
92287230002 MSV/356663901-MW5R EPA 8260
92287230003 MSV/356663901-FIELD BLANK EPA 8260
92287230004 MSV/356663901-MW2 EPA 8260
92287230005 MSV/356663901-MW3R EPA 8260
92287230006 MSV/356663901-MW4R EPA 8260
92287230007 MSV/356663901-MW6R EPA 8260
92287230008 MSV/356663901-SW1 EPA 8260
92287230009 MSV/356663901-SW2 EPA 8260
92287230010 MSV/356663901-TRIP BLANK EPA 8260
92287230001 WET/432103901-MW7 SM 2320B
92287230002 WET/432103901-MW5R SM 2320B
92287230003 WET/432103901-FIELD BLANK SM 2320B
92287230004 WET/432103901-MW2 SM 2320B
92287230005 WET/432103901-MW3R SM 2320B
92287230006 WET/432103901-MW4R SM 2320B
REPORT OF LABORATORY ANALYSIS
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Page 75 of 78
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92287230
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92287230007 WET/432103901-MW6R SM 2320B
92287230001 WET/431753901-MW7 SM 2540C
92287230002 WET/431753901-MW5R SM 2540C
92287230003 WET/431753901-FIELD BLANK SM 2540C
92287230004 WET/431753901-MW2 SM 2540C
92287230005 WET/431753901-MW3R SM 2540C
92287230006 WET/431753901-MW4R SM 2540C
92287230007 WET/431753901-MW6R SM 2540C
92287230001 WET/431673901-MW7 SM 4500-S2D
92287230002 WET/431673901-MW5R SM 4500-S2D
92287230003 WET/431673901-FIELD BLANK SM 4500-S2D
92287230001 WETA/265063901-MW7 EPA 300.0
92287230002 WETA/265063901-MW5R EPA 300.0
92287230003 WETA/265063901-FIELD BLANK EPA 300.0
92287230004 WETA/265063901-MW2 EPA 300.0
92287230005 WETA/265063901-MW3R EPA 300.0
92287230006 WETA/265063901-MW4R EPA 300.0
92287230007 WETA/265063901-MW6R EPA 300.0
92287230001 WETA/265573901-MW7 SM 4500-Cl-E
92287230002 WETA/265573901-MW5R SM 4500-Cl-E
92287230003 WETA/265573901-FIELD BLANK SM 4500-Cl-E
92287230004 WETA/265573901-MW2 SM 4500-Cl-E
92287230005 WETA/265573901-MW3R SM 4500-Cl-E
92287230006 WETA/265573901-MW4R SM 4500-Cl-E
92287230007 WETA/265573901-MW6R SM 4500-Cl-E
92287230001 WETA/265373901-MW7 SM 4500-CN-E
92287230002 WETA/265373901-MW5R SM 4500-CN-E
92287230003 WETA/265373901-FIELD BLANK SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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Page 77 of 78
Page 78 of 78
#=CL#
February 29, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92287219
92287219
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Oxford Unit 1 MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 19, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064
Alabama Certification #40770Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #Pace
Connecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959
Georgia EPD #: PaceIdaho Certification #: MN00064
Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01
Iowa Certification #: 368Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001Maine Certification #: 2013011
Maryland Certification #: 322Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: Pace
Montana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: Pace
New Jersey Certification #: MN-002New York Certification #: 11647
North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036
Ohio EPA #: 4150Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563Puerto Rico Certification
Saipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192
Tennessee Certification #: 02818Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486
West Virginia Certification #: 382West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Lab ID Sample ID Matrix Date Collected Date Received
92287219001 3901-MW7 Water 02/18/16 09:35 02/19/16 09:30
92287219002 3901-MW5R Water 02/18/16 10:26 02/19/16 09:30
92287219003 3901-NES2S Water 02/18/16 11:34 02/19/16 09:30
92287219004 3901-NES2D Water 02/18/16 11:44 02/19/16 09:30
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92287219001 3901-MW7 RSK 175 1 PASI-MDR1
EPA 353.2 1 PASI-ADMN
92287219002 3901-MW5R RSK 175 1 PASI-MDR1
EPA 353.2 1 PASI-ADMN
92287219003 3901-NES2S RSK 175 1 PASI-MDR1
EPA 8260 4 PASI-CNB
SM 2320B 1 PASI-AMLS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
92287219004 3901-NES2D RSK 175 1 PASI-MDR1
EPA 8260 4 PASI-CNB
SM 2320B 1 PASI-AMLS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92287219001 3901-MW7
Methane 1.8J ug/L 02/22/16 21:2810.0RSK 175
Nitrogen, Nitrate 179J ug/L 02/20/16 08:2910000EPA 353.2
92287219002 3901-MW5R
Methane 21.8 ug/L 02/22/16 21:3610.0RSK 175
Nitrogen, Nitrate 37.3J ug/L 02/20/16 08:3010000EPA 353.2
92287219003 3901-NES2S
Methane 512 ug/L 02/22/16 21:4410.0RSK 175
Alkalinity, Total as CaCO3 49600 ug/L 02/25/16 16:355000SM 2320B
Sulfate 4840J ug/L 02/22/16 19:30250000EPA 300.0
Chloride 6280 ug/L 02/25/16 20:141000SM 4500-Cl-E
92287219004 3901-NES2D
Methane 1.9J ug/L 02/22/16 21:5310.0RSK 175
Alkalinity, Total as CaCO3 150000 ug/L 02/25/16 16:475000SM 2320B
Sulfate 54700J ug/L 02/22/16 19:441250000EPA 300.0
Nitrogen, Nitrate 122J ug/L 02/20/16 08:4710000EPA 353.2
Chloride 5650 ug/L 02/25/16 20:151000SM 4500-Cl-E
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Sample: 3901-MW7 Lab ID: 92287219001 Collected: 02/18/16 09:35 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1.8J ug/L 02/22/16 21:28 74-82-810.0 0.63 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 179J ug/L 02/20/16 08:2910000 10.0 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Sample: 3901-MW5R Lab ID: 92287219002 Collected: 02/18/16 10:26 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 21.8 ug/L 02/22/16 21:36 74-82-810.0 0.63 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 37.3J ug/L 02/20/16 08:3010000 10.0 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Sample: 3901-NES2S Lab ID: 92287219003 Collected: 02/18/16 11:34 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 512 ug/L 02/22/16 21:44 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 02/23/16 06:30 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)99 %02/23/16 06:30 460-00-470-130 1
1,2-Dichloroethane-d4 (S)90 %02/23/16 06:30 17060-07-070-130 1
Toluene-d8 (S)100 %02/23/16 06:30 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 49600 ug/L 02/25/16 16:355000 1000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 4840J ug/L 02/22/16 19:30 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 02/20/16 08:4110000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 6280 ug/L 02/25/16 20:14 16887-00-61000 500 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Sample: 3901-NES2D Lab ID: 92287219004 Collected: 02/18/16 11:44 Received: 02/19/16 09:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1.9J ug/L 02/22/16 21:53 74-82-810.0 0.63 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 02/23/16 06:46 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)100 %02/23/16 06:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/23/16 06:46 17060-07-070-130 1
Toluene-d8 (S)100 %02/23/16 06:46 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 150000 ug/L 02/25/16 16:475000 1000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 54700J ug/L 02/22/16 19:44 14808-79-81250000 5000 5
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 122J ug/L 02/20/16 08:4710000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 5650 ug/L 02/25/16 20:15 16887-00-61000 500 1
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25282
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples: 92287219001, 92287219002, 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2196493
Associated Lab Samples:92287219001, 92287219002, 92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Methane ug/L 1.6J 10.0 02/22/16 19:250.63
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2196494LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2196495
Methane ug/L 57.460.7 95 85-1159456.8 1 20
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2196856MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286712006
2196857
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methane ug/L 60.7 71 30-15069 3 2060.7ND 45.1 43.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286712004
2196858SAMPLE DUPLICATE:
Methane ug/L 1.7J 20ND
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35665
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670820
Associated Lab Samples:92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 02/23/16 01:480.62
1,2-Dichloroethane-d4 (S)%90 70-130 02/23/16 01:48
4-Bromofluorobenzene (S)%99 70-130 02/23/16 01:48
Toluene-d8 (S)%101 70-130 02/23/16 01:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670821LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 47.050 94 58-137
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1670822MATRIX SPIKE SAMPLE:
MSSpike
Result
92287200001
Vinyl chloride ug/L 20.320 102 70-130ND
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287200002
1670823SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%92 191
4-Bromofluorobenzene (S)%103 3100
Toluene-d8 (S)%102 2100
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43210
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1672086
Associated Lab Samples:92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/25/16 14:361000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1672087LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 5000050000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672088MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287453001
1672089
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 94 80-120103 9 2550000ND48600 53300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1672090MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230002
1672091
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 103 80-120110 2 2550000141000192000 196000
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Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26506
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670412
Associated Lab Samples:92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 02/22/16 15:531000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670413LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670414MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
30174071001
1670415
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 0 1034200J 34200J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670416MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287230001
1670417
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 104 90-110105 0 102000039300J60100J 60300J
REPORT OF LABORATORY ANALYSIS
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Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26497
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92287219001, 92287219002, 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1670299
Associated Lab Samples:92287219001, 92287219002, 92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 02/20/16 08:2610.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1670300LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2440J2500 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670301MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287195001
1670302
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L M125008890-11089 0 1025002.3 mg/L 4480J 4500J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1670303MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287219003
1670304
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 92 90-11092 0 102500ND2300J 2300J
REPORT OF LABORATORY ANALYSIS
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Page 14 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26557
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92287219003, 92287219004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673098
Associated Lab Samples:92287219003, 92287219004
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/25/16 20:07500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673099LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2010020000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673100MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287020003
1673101
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011190-110112 0 101000012.6 mg/L 23800 23900
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673102MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287285001
1673103
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M1500004190-11042 0 1050000105 mg/L 126000 126000
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92287219
Oxford Unit 1 MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92287219001 AIR/252823901-MW7 RSK 175
92287219002 AIR/252823901-MW5R RSK 175
92287219003 AIR/252823901-NES2S RSK 175
92287219004 AIR/252823901-NES2D RSK 175
92287219003 MSV/356653901-NES2S EPA 8260
92287219004 MSV/356653901-NES2D EPA 8260
92287219003 WET/432103901-NES2S SM 2320B
92287219004 WET/432103901-NES2D SM 2320B
92287219003 WETA/265063901-NES2S EPA 300.0
92287219004 WETA/265063901-NES2D EPA 300.0
92287219001 WETA/264973901-MW7 EPA 353.2
92287219002 WETA/264973901-MW5R EPA 353.2
92287219003 WETA/264973901-NES2S EPA 353.2
92287219004 WETA/264973901-NES2D EPA 353.2
92287219003 WETA/265573901-NES2S SM 4500-Cl-E
92287219004 WETA/265573901-NES2D SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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Page 18 of 19
Page 19 of 19
#=CL#
February 29, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92287160
92287160
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD DISSOLVED HYDROGEN
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 19, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
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#=CL#
February 29, 2016
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92287160
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92287160
OXFORD DISSOLVED HYDROGEN
Lab ID Sample ID Matrix Date Collected Date Received
92287160001 3901-MW7 Water 02/18/16 09:35 02/19/16 09:30
92287160002 3901-MW5R Water 02/18/16 10:26 02/19/16 09:30
92287160003 3901-NES2S Water 02/18/16 11:34 02/19/16 09:30
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Appendix C

Historical Detected Inorganic Constituents in Compliance Wells

APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Inorganic Compounds
Antimony 14-Sep-94 ---30 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---30 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---30.0 6 ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---30.0 32 ND ---ND ---ND ---ND ---68 ---ND ---
26-Oct-00 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
2-Jul-07 ---6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 1.4 µg/L (10/23/07)19-Dec-07 ---6.0 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---6.0 ---ND#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 1 µg/L (08/01/10)14-Dec-10 2.6 6.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
Arsenic 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND 7.0 ---14.0 14.0 ---ND ---ND ---5.0 ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND 5.0 ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---12.0 8.0 ---ND ---ND ---6.0 ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---11.0 ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---4.4 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---4.9 J ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------2.9 J ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---182#---3.7 J ---ND ---ND ---ND ---ND ND
16-Dec-08 2.7 11.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 2.7 10.0 ---9.7 J ---ND ---ND ---4.9 J ---ND ---2.9 J ND
15-Dec-09 2.7 10.0 ---ND ---3.2 J ---ND ---ND ---ND ---ND ND
NC 2L = 10 µg/L (2/5/10)23-Jun-10 2.7 10.0 ---5.9 J ---2.7 J ---ND ---5.2 J ---ND ---4.4 J ND
14-Dec-10 2.7 10.0 ---------ND ---ND ---4.4 J ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 5.5 J ---2.9 J ---3.8 J ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Barium 14-Sep-94 ---500 680 680 ---260 580 ---30,300 ---ND ---1,740 ------
2-Dec-94 ---500 ND ND ---ND ND ---540 ---ND ---ND ------
8-Feb-95 ---500 ND ND ---ND ND ---621 ---ND ---ND ------
2-Mar-95 ---500 ND ND ---ND 541 ---2,710 ---ND ---ND ------
17-Nov-95 ---500 ND ND ---ND ND ---2,440 ---ND ---ND ------
23-May-96 ---500 ND ND ---ND ND ---0 ---ND ---ND ------
14-Nov-96 ---500 2,500 510 ---600 480 ---1,700 ---39 ---21 ------
18-Jun-97 ---500 960 1,200 ---280 720 ---3,400 ---93 ---700 ------
2-Dec-97 ---500 1,100 410 ---150 510 ---4,300 ---68 ---260 ------
27-May-98 ---500 2,100 310 ---95 660 ---2,800 ---69 ---350 ------
16-Nov-98 ---500 5,000 3,200 ---4,800 7,600 ---10,000 ---100 ---5,900 ------
10-Sep-99 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---15.4 ---30.8 ---24.8 ---78.5 ---33.4 ---77.4 0.20 J
NC 2L = 2,000 µg/L (10/23/07)12-Jul-07 ---100 ---19.4 J ---13.8 J ---24.5 J ---82.5 J ---27.3 J ---76.2 J ND
19-Dec-07 ---100 ---------14.7 B ---20.1 B ---28.7 B ---27.2 B ---64.9 10.5
8-Jul-08 ---100 ---5360#---21.7 J ---19.6 J ---54.1 J ---35.3 J ---78.2 J 0.29 J
16-Dec-08 0.20 100 ---19.4 B ---11.2 B ---16.5 B ---27.0 B ---38.8 B ---66.7 J 10.7 J
8-Jul-09 0.20 100 ---213 ---11.9 B ---26.6 B ---74.6 B ---34.2 B ---78.4 B 17.6 J
15-Dec-09 0.20 100 ---12.6 B ---16.4 B ---18.8 B ---38.2 B ---39.8 B ---89.3 J 17.1 J
NC 2L = 700 µg/L (2/5/10)23-Jun-10 0.20 100 ---61.2 B ---12.0 B ---17.7 B ---107 B ---36.7 B ---74.2 B 27.3 J
14-Dec-10 0.20 100 ---------11.7 B ---26.8 B ---37.6 B ---46.1 B ---79.0 J 12.1 J
21-Jun-11 5.0 100 ------6.8 J 14.6 J ---18.6 J ---37.2 J ---41.7 J ---78.7 J ND
6-Dec-11 5.0 100 ------16.2 J 13.2 J ---27.8 J ---38.4 J ---43.3 J ---83.7 J ND
13-Jun-12 5.0 100 ------9.2 J 16.5 J ---20.4 J ---52.2 J ---39.0 J ---82.2 J ND
11-Dec-12 5.0 100 ------5.2 J 12.6 J ---17.2 J ---32.1 J ---47.3 J ---81.9 J ND
29-Apr-13 5.0 100 ------ND 14.7 J ---19.6 J ---37.6 J ---42.2 J ---81.8 J ND
6-Aug-13 5.0 100 ------ND 19.7 J ---18.7 J ---39.8 J ---43.1 J ---84.7 J ND
25-Feb-14 5.0 100 ------5.6 J 15.3 J ---52.7 J ---38.0 J ---48.0 J ---77.0 J ND
13-Aug-14 5.0 100 ------ND 19.0 J ---28.4 J ---37.7 J ---49.6 J ---92.6 J ND
12-Mar-15 2.5 100 ------12.4 J 13.3 J ---28.0 J ---38.6 J ---38.9 J ---93.1 J ND
19-Aug-15 2.5 100 ------4.9 J 17.5 J ---25.3 J ---36.2 J ---42.2 J ---90.5 J ND
18-Feb-16 2.5 100 ------4.4 J 12.1 J ---15.7 J ---36.4 J ---36.7 J ---98.2 J ND
Beryllium 14-Sep-94 ---2 ND ND ---ND ND ---200 ---ND ---ND ------
2-Dec-94 ---2 2.0 ND ---ND 4.0 ---2.0 ---ND ---ND ------
8-Feb-95 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---2 ND ND ---ND 6.0 ---7.0 ---ND ---ND ------
17-Nov-95 ---2 ND ND ---ND 2.0 ---7.0 ---ND ---ND ------
23-May-96 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---2 1.0 2.0 ---ND 2.0 ---2.0 ---ND ---ND ------
18-Jun-97 ---2 5.0 14.0 ---3.0 7.0 ---13.0 ---ND ---3.0 ------
2-Dec-97 ---2 1.0 2.0 ---ND 2.0 ---5.0 ---ND ---1.0 ------
27-May-98 ---2 7.0 4.0 ---2.0 8.0 ---10.0 ---ND ---3.0 ------
16-Nov-98 ---2 9.0 5.0 ---2.0 5.0 ---4.0 ---ND ---4.0 ------
10-Sep-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---2 ---ND ---ND ---ND ---ND ---ND ---4.0 ---
10-Jun-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---65.2 ---0.14 J ---0.10 J ---ND ---ND ---ND ND
16-Dec-08 0.10 1.0 ---0.21 J ---ND ---ND ---ND ---0.18 J ---ND ND
8-Jul-09 0.10 1.0 ---4.9 ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.10 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.10 1.0 ---1.3 ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/01/10)14-Dec-10 0.10 1.0 ---------ND ---{ND}---{ND}---{ND}---ND ND {0.15} J
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Cadmium 14-Sep-94 ---1 ND ND ---ND 2.0 ---4.0 ---ND ---1.0 ------
2-Dec-94 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
8-Feb-95 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---1 ND ND ---ND 1.0 ---1.0 ---ND ---ND ------
17-Nov-95 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
23-May-96 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
14-Nov-96 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
18-Jun-97 ---1 ND ND ---ND 2.0 ---1.0 ---ND ---3.0 ------
2-Dec-97 ---1 ND ND ---ND ND ---2.0 ---ND ---ND ------
27-May-98 ---1 ND ND ---ND 1.0 ---ND ---ND ---1.0 ------
16-Nov-98 ---1 2.0 ND ---ND 2.0 ---1.0 ---ND ---4.0 ------
10-Sep-99 ---1 ND ND ---ND ---1.0 ---ND ---ND ---ND ---
16-Nov-99 ---1 2.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1 ND ND ---ND ---ND ---ND ---ND ---1.0 ---
26-Oct-00 ---1 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---1 ---ND ---2.0 ---2.0 ---ND ---ND ---2.0 ---
10-Jun-02 ---1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---
13-Jun-02 ---1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---
19-Nov-02 ---1 ---4.0 ---3.0 ---2.0 ---ND ---1.0 ---ND ---
27-Jun-03 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---1 ---ND ---ND ---1.0 ---ND ---ND ---ND ND
29-Dec-04 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1 ---0.90 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---213#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.50 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Chromium 14-Sep-94 ---10 74.0 74.0 ---91.0 340 ---457 ---ND ---177 ------
2-Dec-94 ---10 93.0 ND ---88.0 106 ---18.0 ---ND ---24.0 ------
8-Feb-95 ---10 ND 48.0 ---56.0 87.0 ---15.0 ---ND ---19.0 ------
2-Mar-95 ---10 ND 41.0 ---66.0 313 ---79.0 ---ND ---10 ------
17-Nov-95 ---10 130.0 11.0 ---53.0 92.0 ---79.0 ---ND ---ND ------
23-May-96 ---10 71.0 ND ---34.0 51.0 ---11.0 ---ND ---ND ------
14-Nov-96 ---10 3.0 6.0 ---8.0 11.0 ---4.0 ---ND ---8.0 ------
18-Jun-97 ---10 470 340 ---100 270 ---100 ---10.0 ---83.0 ------
2-Dec-97 ---10 17.0 8.0 ---14.0 ND ---18.0 ---5.0 ---26.0 ------
27-May-98 ---10 470 150 ---31.0 190 ---69.0 ---6.0 ---40.0 ------
16-Nov-98 ---10 1000 220 ---130 190 ---44.0 ---4.0 ---260 ------
10-Sep-99 ---10 23.0 ND ---ND ---40.0 ---ND ---ND ---23.0 ---
16-Nov-99 ---10 28.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 16.0 ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---13.0 ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---16.0 ---56.0 ---10 ---ND ---ND ---
10-Jun-02 ---10 ---ND ---ND ---13.0 ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---17.0 ---ND ---ND ---ND ---
19-Nov-02 ---10 ---12.0 ---12.0 ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---13.0 ---ND ---ND ---37.0 ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---67.0 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---2.8 J ---8.9 J ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---3.3 J ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------2.4 J ---2.5 J ---ND ---2.4 J ---ND ND
8-Jul-08 ---10.0 ---488#---8.0 J ---2.8 J ---ND ---1.8 J ---ND ND
6-Dec-08 0.40 10.0 ---1.5 J ---2.0 J ---3.2 J ---ND ---1.9 J ---ND ND
8-Jul-09 0.40 10.0 ---22.1 ---3.3 J ---7.2 J ---ND ---0.86 J ---ND ND
15-Dec-09 0.40 10.0 ---0.60 J ---4.6 J ---3.6 J ---ND ---0.64 J ---ND ND
NC 2L = 10 µg/L (2/5/10)23-Jun-10 0.40 10.0 ---12.0 ---4.1 J ---2.6 B ---0.90 B ---1.3 B ---1.1 B 0.71 J
Resample >12-Aug-10 0.40 10.0 ---87.8#J ------------------------------ND
14-Dec-10 0.40 10.0 ---------2.8 J ---9.1 J ---1.0 J ---1.2 J ---0.43 J ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---11.6 ---ND ---ND ---ND ND
Resample >25-Jan-12 5.0 10.0 ---------------6.1 J ------------------ND
13-Jun-12 5.0 10.0 ------ND 5.1 J ---7.5 J ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---19.6 ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND 6.1 J ---6.6 J ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 3.3 J ---10.6 ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 5.9 J ---7.5 J ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Cobalt 14-Sep-94 ---10 160 160 ---ND 250 ---2810 ---ND ---ND ------
2-Dec-94 ---10 47.0 ND ---53.0 133 ---31.0 ---ND ---ND ------
8-Feb-95 ---10 ND 45.0 ---ND 158 ---42.0 ---ND ---23.0 ------
2-Mar-95 ---10 ND 35.0 ---22.0 258 ---89.0 ---ND ---24.0 ------
17-Nov-95 ---10 58.0 13.0 ---31.0 86.0 ---76.0 ---ND ---15.0 ------
23-May-96 ---10 29.0 ND ---19.0 88.0 ---34.0 ---ND ---16.0 ------
14-Nov-96 ---10 12.0 93.0 ---55.0 120 ---90.0 ---2.0 ---16.0 ------
18-Jun-97 ---10 200 430 ---52.0 520 ---550 ---4.0 ---28.0 ------
2-Dec-97 ---10 7.0 34.0 ---16.0 99.0 ---240 ---6.0 ---14.0 ------
27-May-98 ---10 150 73.0 ---13.0 180 ---350 ---4.0 ---18.0 ------
16-Nov-98 ---10 380 120 ---54.0 100 ---440 ---12.0 ---45.0 ------
10-Sep-99 ---10 11.0 ND ---ND ---32.0 ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 10.0 ND ---15.0 ---11.0 ---ND ---ND ---ND ---
18-Apr-01 ---10 ---17.0 ---ND ---21.0 ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---28.0 ---ND ---ND ---ND ---
10-Jun-02 ---10 ---ND ---11.0 ---15.0 ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---11.0 ---15.0 ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---12.0 ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---12.0 ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---11.0 ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---21.3 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---2.1 J ---16.4 ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---11.2 ---ND ---ND ---ND ---ND ND
GWPS = 70 µg/L (10/23/07)19-Dec-07 ---10 ---------17.0 ---4.6 B ---1.1 B ---1.4 B ---ND 1.6 J
8-Jul-08 ---10.0 ---436#---15.0 B ---4.2 B ---3.1 B ---5.0 B ---6.1 B 6.2 J
16-Dec-08 0.60 10.0 ---2.5 B ---11.0 ---3.2 B ---1.4 B ---3.1 B ---2.5 B 2.4 J
8-Jul-09 0.60 10.0 ---8.1 J ---10.6 ---ND ---ND ---ND ---ND ND
15-Dec-09 0.60 10.0 ---ND ---8.8 J ---ND ---ND ---ND ---ND ND
23-Jun-10 0.60 10.0 ---3.9 J ---11.8 ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 0.60 10.0 ------------------------------------ND
GWPS = 1 µg/L (10/01/10)14-Dec-10 0.60 10.0 ---------10.9 ---3.7 B ---ND ---3.1 B ---0.71 B 1.6 J
21-Jun-11 5.0 10.0 ------ND 11.6 ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------5.0 J 9.3 J ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND 10.7 ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND 10.1 ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND 13.0 ---ND ---ND ---ND ---5.1 J ND
6-Aug-13 5.0 10.0 ------ND 20.5 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND 13.9 ---11.4 ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND 9.5 J ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 8.0 J ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 11.8 ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND 7.5 J ---ND ---ND ---ND ---ND ND
Copper 14-Sep-94 ---200 260 260 ---130 340 ---4780 ---ND ---ND ------
2-Dec-94 ---200 ND ND ---ND 237 ---ND ---ND ---ND ------
8-Feb-95 ---200 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---200 ND ND ---ND 270 ---545 ---ND ---ND ------
17-Nov-95 ---200 ND ND ---ND ND ---456 ---ND ---ND ------
23-May-96 ---200 ND ND ---ND ND ---ND ---200 ---ND ------
14-Nov-96 ---200 10.0 31.0 ---54.0 17.0 ---60.0 ---12.0 ---15.0 ------
18-Jun-97 ---200 96.0 340 ---97.0 310 ---660 ---170 ---45.0 ------
2-Dec-97 ---200 10.0 13.0 ---24.0 26 ---210 ---130 ---17.0 ------
27-May-98 ---200 84.0 100 ---26.0 300 ---400 ---91.0 ---28.0 ------
16-Nov-98 ---200 280 320 ---150 290 ---400 ---320 ---80.0 ------
10-Sep-99 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---1.7 B ---3.5 J ---1.7 B ---2.5 B ---0.90 B ---ND 0.60 J
12-Jul-07 ---10 ---ND ---ND ---2.0 J ---ND ---ND ---ND ND
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---10 ---------4.6 B ---3.8 B ---0.56 B ---1.9 B ---0.58 B 10.5 B
8-Jul-08 ---10.0 ---828#---9.3 J ---1.6 J ---ND ---ND ---0.75 J ND
16-Dec-08 0.30 10.0 ---2.0 J ---2.1 J ---2.3 J ---ND ---6.9 J ---ND ND
8-Jul-09 0.30 10.0 ---32.7 ---1.6 J ---3.3 J ---ND ---ND ---ND ND
15-Dec-09 0.30 10.0 ---0.79 J ---2.9 J ---2.7 J ---ND ---2.1 J ---ND ND
23-Jun-10 0.30 10.0 ---23.2 ---2.0 J ---1.1 J ---ND ---0.86 J ---ND ND
Resample >12-Aug-10 0.30 10.0 ------------------------------------ND
14-Dec-10 0.30 10.0 ---------1.8 B ---8.1 J ---0.39 B ---5.9 J ---ND 0.49 J
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------15.5 ND ---10.0 ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---5.6 J ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 6.6 J ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---14.7 ---ND ---6.4 J ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---7.6 J ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 5.0 J ---6.8 J ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---3.6 J ---ND ---ND ---ND ND
Iron 23-Jun-10 14.0 300 ---11800 ---4150 ---1040 ---102 J ---413 ---776 ND
NC 2L = 300 µg/L (2/5/10) Resample >12-Aug-10 140 3000 ---123,000 ------------------------------ND
14-Dec-10 14 300 ---------3210 ---3880 ---141 J ---877 ---1100 ND
21-Jun-11 50.0 300 ------2190 6030 ---667 ---114 J ---981 ---1020 ND
6-Dec-11 50.0 300 ------8610 2680 ---5420 ---86.1 J ---287 J ---1040 ND
13-Jun-12 50.0 300 ------1770 5610 ---3280 ---63.4 J ---698 ---1680 ND
11-Dec-12 50.0 300 ------1680 4020 ---1260 ---ND ---545 ---981 ND
29-Apr-13 50.0 300 ------414 3500 ---1130 ---112 J ---635 ---1750 ND
6-Aug-13 50.0 300 ------397 8970 ---307 ---ND ---378 ---2130 ND
25-Feb-14 50.0 300 ------1040 7060 ---9750 ---102 J ---2030 ---1710 ND
13-Aug-14 50.0 300 ------209 J 5380 ---3030 ---107 J ---904 ---2140 ND
12-Mar-15 25.0 300 ------269 J 3680 ---6040 ---40.8 J ---262 J ---2650 ND
19-Aug-15 25.0 300 ------156 J 7250 ---3780 ---34.9 J ---58.0 J ---1460 ND
18-Feb-16 25.0 300 ------243 J 792 ---270 J ---43.0 J ---86.3 J ---1500 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Lead 14-Sep-94 ---10 31.0 31.0 ---230 23.0 ---355 ---ND ---190 ------
2-Dec-94 ---10 17.0 ND ---26.0 30.0 ---11.0 ---ND ---31.0 ------
8-Feb-95 ---10 ND 13.0 ---23.0 10.0 ---19.0 ---ND ---15.0 ------
2-Mar-95 ---10 ND 11.0 ---14.0 27.0 ---47.0 ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND 13.0 ---51.0 ---ND ---ND ------
23-May-96 ---10 ND ND ---10.0 ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 33.0 69.0 ---21.0 40.0 ---78.0 ---8 ---70.0 ------
2-Dec-97 ---10 8.0 8.0 ---20.0 14.0 ---21.0 ---11 ---24.0 ------
27-May-98 ---10 27.0 18.0 ---23.0 31.0 ---32.0 ---ND ---32.0 ------
16-Nov-98 ---10 43.0 36.0 ---33.0 34.0 ---32.0 ---ND ---110 ------
10-Sep-99 ---10 ND 18.0 ---ND ---14.0 ---ND ---ND ---ND ---
16-Nov-99 ---10 11.0 ND ---ND ---ND ---ND ---11.0 ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---28.0 ---15.0 ---ND ---18.0 ---29.0 ---
10-Jun-02 ---10 ---ND ---13.0 ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---13.0 ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---10.0 ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---2.0 J ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 15 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---78#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 4.0 10.0 ---22.5 ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 4.0 10.0 ---6.7 J ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 4.0 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 2.9 J ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Mercury 17-Nov-95 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.5 ND ND ---ND 1.0 ---ND ---ND ---ND ------
10-Sep-99 ---0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---------------------------------------------
10-Jun-02 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---------------------------------------------
27-Jun-03 ---1.5 ---ND ---ND ---ND ---ND ---0.78 ---ND ---
30-Dec-03 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---0.2 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---0.2 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.05 µg/L (10/23/07)19-Dec-07 ---0.2 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---0.20 ---0.34#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.090 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1 µg/L (2/5/10)23-Jun-10 0.070 0.20 ---ND ---ND ---ND ---0.094 J ---ND ---ND ND
14-Dec-10 0.070 0.20 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
Manganese 23-Jun-10 0.30 50.0 ---88.3 ---217 ---44.0 B ---513 ---127 ---1470 9.0 J
NC 2L = 50 µg/L (2/5/10) Resample>12-Aug-10 3.00 500 ---972 ------------------------------0.35 J
14-Dec-10 0.30 50.0 ---------208 ---139 ---730 ---194 ---1260 1.1 J
21-Jun-11 5.0 50.0 ------38.2 J 245 ---36.9 J ---833 ---130 ---1400 ND
6-Dec-11 5.0 50.0 ------198 216 ---170 ---808 ---187 ---1350 ND
13-Jun-12 5.0 50.0 ------41.7 J 226 ---95.8 ---760 ---125 ---1360 ND
11-Dec-12 5.0 50.0 ------33.8 J 230 ---28.9 J ---770 ---279 ---1340 ND
29-Apr-13 5.0 50.0 ------14.2 J 193 ---47.3 J ---724 ---139 ---1220 ND
6-Aug-13 5.0 50.0 ------10.3 J 273 ---38.5 J ---749 ---135 ---1220 ND
25-Feb-14 5.0 50.0 ------29.8 J 222 ---340 ---897 ---154 ---862 ND
13-Aug-14 5.0 50.0 ------5.8 J 209 ---108 ---1230 ---125 ---1450 ND
12-Mar-15 2.5 50.0 ------6.0 J 210 ---200 ---676 ---104 ---1370 ND
19-Aug-15 2.5 50.0 ------4.3 J 288 ---199 ---802 ---103 ---1490 ND
18-Feb-16 2.5 50.0 ------5.4 J 201 ---72.7 ---981 ---82.4 ---1620 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Nickel 14-Sep-94 ---50 180 18.0 ---ND 250 ---680 ---ND ---ND ------
2-Dec-94 ---50 118 ND ---119 164 ---ND ---ND ---ND ------
8-Feb-95 ---50 ND ND ---ND 84.0 ---ND ---ND ---ND ------
2-Mar-95 ---50 ND ND ---ND 204 ---75.0 ---ND ---ND ------
17-Nov-95 ---50 71.0 ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---50 69.0 ND ---ND 51 ---ND ---ND ---ND ------
14-Nov-96 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---50 330 280 ---65.0 200 ---ND ---ND ---ND ------
2-Dec-97 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---50 310 88.0 ---ND 170 ---61 ---ND ---ND ------
16-Nov-98 ---50 840 270 ---ND ND ---ND ---ND ---150 ------
10-Sep-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---50 ---ND ---ND ---59 ---ND ---ND ---ND ---
10-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---50 ---4.7 J ---7.0 J ---7.2 J ---2.4 J ---ND ---ND ND
12-Jul-07 ---50 ---4.6 J ---3.2 J ---2.5 J ---ND ---ND ---ND ND
NC 2L = 100 µg/L (10/23/07)19-Dec-07 ---50 ---------3.2 J ---5.0 ---ND ---2.3 J ---ND ND
8-Jul-08 ---50.0 ---122 J ---5.3 J ---2.3 J ---ND ---1.7 J ---ND ND
16-Dec-08 1.7 50.0 ---ND ---2.3 B ---2.5 B ---ND ---2.7 B ---ND 2.4 J
8-Jul-09 1.7 50.0 ---38.6 J ---3.2 J ---6.0 J ---ND ---1.8 J ---ND ND
15-Dec-09 1.7 50.0 ---ND ---3.6 B ---4.4 B ---2.1 B ---2.6 B ---2.0 B 3.0 J
23-Jun-10 1.7 50.0 ---10 J ---2.3 J ---ND ---ND ---ND ---ND ND
14-Dec-10 1.7 50.0 ---------1.8 B ---2.6 B ---ND ---ND ---ND 2.7 J
21-Jun-11 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 50.0 ------ND ND ---6.4 J ---ND ---ND ---ND ND
13-Jun-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 50.0 ------ND ND ---11.3 J ---ND ---ND ---ND ND
13-Aug-14 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 50.0 ------ND ND ---11.7 J ---ND ---ND ---ND ND
19-Aug-15 2.5 50.0 ------ND 3.7 J ---8.9 J ---ND ---ND ---ND ND
18-Feb-16 2.5 50.0 ------ND ND ---3.2 J ---ND ---ND ---ND ND
Selenium 14-Sep-94 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---20 ND 24.0 ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---ND#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 3.8 10.0 ---4.2 B ---ND ---ND ---ND ---ND ---ND 4.9 J
8-Jul-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 3.8 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Silver 14-Sep-94 ---10 ND ND ---ND ND ---50.0 ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---4.0 ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 17.5 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---0.26 J ---ND ---ND ND
8-Jul-08 ---10.0 ---14.6#J ---0.27 J ---0.41 J ---0.83 J ---0.39 J ---0.56 J ND
16-Dec-08 0.10 10.0 ---ND ---ND ---0.25 J ---0.53 J ---0.40 J ---0.46 J ND
8-Jul-09 0.10 10.0 ---0.16 J ---ND ---ND ---0.17 J ---ND ---ND ND
15-Dec-09 0.10 10.0 ---ND ---ND ---0.32 J ---0.64 J ---0.53 J ---0.53 J ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ---ND ---ND ---ND ---0.13 J ---0.13 J ---ND ND
14-Dec-10 0.10 10.0 ---------ND ---{0.24}B ---{0.58}B ---{0.34}B ---0.17 B {0.25 J}
0.19 J
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Thallium 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---5.0 ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.01 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 0.28 µg/L (10/23/07)19-Dec-07 ---5.5 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---5.5 ---31.7#---4.5 J ---ND ---ND ---ND ---ND ND
16-Dec-08 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.0 5.5 ---ND ---ND ---ND ---ND ---3.8 J ---ND ND
23-Jun-10 3.0 5.5 ---6.6 ---ND ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 30.0 55.0 ---ND#------------------------------ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 ---------ND ---ND ---8.1 ---ND ---ND ND
21-Jun-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
Tin 8-Jul-08 ---100 ---232#J ---1.9 J ---3.0 J ---3.0 J ---3.6 J ---3.6 J ND
16-Dec-08 1.8 100 ------------------------------------ND
8-Jul-09 1.8 100 ---7.4 J ---ND ---ND ---1.8 J ---ND ---ND ND
15-Dec-09 ---------------------------------------------
GWPS = 2100 µg/L (2/5/10)23-Jun-10 1.8 100 ---2.9 J ---ND ---ND ---1.9 J ---2.5 J ---3.3 J ND
GWPS = 2000 µg/L (10/01/10)14-Dec-10 ---------------------------------------------
21-Jun-11 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 100 ---------------------------------------
13-Jun-12 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 ---------------------------------------------
29-Apr-13 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 2.5 100 ------ND ------------------ND ------ND
18-Feb-16 2.5 100 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Vanadium 14-Sep-94 ---40 580 580 ---390 540 ---12800 ---ND ---340 ------
2-Dec-94 ---40 107 ND ---233 316 ---201 ---ND ---ND ------
8-Feb-95 ---40 ND 81.0 ---132 162 ---190 ---ND ---ND ------
2-Mar-95 ---40 ND 62.0 ---173 468 ---1260 ---ND ---ND ------
17-Nov-95 ---40 100 ND ---84.0 120 ---984 ---ND ---ND ------
23-May-96 ---40 92.0 ND ---103 139 ---196 ---ND ---ND ------
14-Nov-96 ---40 16.0 10.0 ---140 280 ---320 ---10.0 ---22.0 ------
18-Jun-97 ---40 470 1600 ---310 600 ---1700 ---57.0 ---82.0 ------
2-Dec-97 ---40 32.0 15.0 ---52.0 120 ---970 ---22.0 ---27.0 ------
27-May-98 ---40 330 120 ---71.0 460 ---1000 ---34.0 ---41.0 ------
16-Nov-98 ---40 900 280 ---340 470 ---730 ---49.0 ---97.0 ------
10-Sep-99 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---40 ---ND ---67.0 ---53.0 ---ND ---63.0 ---ND ---
10-Jun-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---40 ---ND ---ND ---ND ---ND ---94.0 ---ND ---
30-Dec-03 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---40 ---ND ---ND ---71.1 ---ND ---ND ---ND ND
28-Dec-06 ---25 ---2.2 J ---28.4 ---ND ---ND ---1.8 J ---ND ND
12-Jul-07 ---25 ---3.7 J ---3.4 J ---2.2 J ---ND ---ND ---ND ND
GWPS = 3.5 µg/L (10/23/07)19-Dec-07 ---25 ---------7.6 ---3.2 J ---1.1 B ---0.82 B ---0.93 B 0.51 J
Resample >14-Feb-08 ---25 ---------7.2 ------------------------0.24 J
Filtered >14-Feb-08 ---25 ---------3.2 J ------------------------ND
8-Jul-08 ---25.0 ---772#---21.9 J ---2.2 J ---0.94 B ---0.78 B ---2.3 J 0.20 J
16-Dec-08 0.20 25.0 ---3.4 J ---4.9 J ---3.4 J ---0.84 B ---6.1 J ---0.47 B 0.76 J
8-Jul-09 0.20 25.0 ---39.6 ---10.6 J ---8.3 J ---1.7 B ---1.9 B ---1.4 B 1.3 J
15-Dec-09 0.20 25.0 ---1.2 B ---12.1 J ---3.8 J ---1.3 B ---2.3 B ---ND 0.53 J
23-Jun-10 0.20 25.0 ---18.7 J ---10.7 J ---2.0 J ---0.51 J ---1.2 J ---0.54 J ND
Resample >12-Aug-10 0.20 25.0 ------------------------------------0.33 J
GWPS = 0.3 µg/L (10/01/10)14-Dec-10 0.20 25.0 ---------7.3 J ---{8.0}J ---{1.2}B ---{4.0}J ---ND {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 ------5.9 J 14.6 J ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 25.0 ------19.8 J 5.3 J ---10 J ---ND ---ND ---ND ND
13-Jun-12 5.0 25.0 ------5.2 J 13.0 J ---6.5 J ---ND ---ND ---ND ND
11-Dec-12 5.0 25.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 25.0 ------ND 8.4 J ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 25.0 ------ND 27.6 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 25.0 ------ND 18.6 J ---19.0 J ---ND ---7.0 J ---ND ND
13-Aug-14 5.0 25.0 ------ND 15.0 J ---7.2 J ---ND ---ND ---ND ND
12-Mar-15 2.5 25.0 ------ND 9.5 J ---14.8 J ---ND ---3.3 J ---ND ND
19-Aug-15 2.5 25.0 ------ND 19.2 J ---8.3 J ---ND ---ND ---ND ND
18-Feb-16 2.5 25.0 ------ND ND ---ND ---ND ---ND ---ND ND
Zinc 14-Sep-94 ---50 680 680 ---400 910 ---17,400 ---ND ---640 ------
2-Dec-94 ---50 299 ND ---380 553 ---279 ---ND ---98.0 ------
8-Feb-95 ---50 ND 185 ---236 255 ---320 ---156 ---108 ------
2-Mar-95 ---50 ND 114 ---102 601 ---1,530 ---191 ---ND ------
17-Nov-95 ---50 309 67.0 ---154 199 ---1,300 ---59.0 ---ND ------
23-May-96 ---50 237 94.0 ---116 237 ---314 ---149 ---ND ------
14-Nov-96 ---50 240 180 ---140 120 ---140 ---15.0 ---48.0 ------
18-Jun-97 ---50 930 800 ---250 650 ---1,800 ---160 ---190 ------
2-Dec-97 ---50 140 150 ---110 120 ---510 ---150 ---130 ------
27-May-98 ---50 1,000 280 ---90.0 560 ---1,300 ---100 ---110 ------
16-Nov-98 ---50 4,300 2,500 ---3,600 5,600 ---7,000 ---230 ---3,900 ------
10-Sep-99 ---50 153 ND ---ND ---96.0 ---ND ---ND ---ND ---
16-Nov-99 ---50 140 119 ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---64.0 ---ND ---ND ---ND ---
27-Oct-01 ---50 ---23.0 ---55.0 ---136.0 ---ND ---32.0 ---ND ---
10-Jun-02 ---50 ---ND ---ND ---72.0 ---ND ---ND ---370 ---
13-Jun-02 ---50 ---ND ---ND ---72.0 ---ND ---ND ---370 ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---52.0 ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---126 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---7.7 J ---14.0 ---7.8 J ---ND ---ND ---1.5 J ND
12-Jul-07 ---10 ---48.1 ---3.6 J ---6.5 J ---ND ---ND ---ND ND
NC 2L = 1,050 µg/L (10/23/07)19-Dec-07 ---10 ---------0.4 B ---ND ---4.5 B ---ND ---ND 87.9
8-Jul-08 ---10.0 ---4,540#---12.6 ---ND ---ND ---ND ---ND 1.2 J
16-Dec-08 0.40 10.0 ---9.6 J ---0.45 J ---3.8 J ---ND ---12.3 ---ND ND
8-Jul-09 0.40 10.0 ---169 ---0.67 J ---7.0 J ---ND ---ND ---ND 1.6 J
15-Dec-09 0.40 10.0 ---6.6 B ---5.5 B ---6.9 B ---ND ---1.9 B ---ND 7.7 J
NC 2L = 1,000 µg/L (2/5/10)23-Jun-10 0.40 10.0 ---55.2 ---2.2 J ---1.0 J ---ND ---ND ---ND ND
14-Dec-10 0.40 10.0 ---------16.3 B ---12.6 B ---ND ---ND ---2.6 B 6.7 J
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 10.0 10.0 ------21.8 B ND ---21.0 B ---ND ---ND ---ND 12.4
13-Jun-12 10.0 10.0 ------ND ND ---14.0 ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 10.0 ------ND ND ---31.9 ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND ---24.1 ---ND ---ND ---ND ND
12-Mar-15 5.0 10.0 ------9.2 B 11.5 B ---24.3 B ---6.8 B ---7.5 B ---7.1 B 6.1 J
19-Aug-15 5.0 10.0 ------ND 7.2 B ---16.3 B ---ND ---ND ---ND 11.5
18-Feb-16 5.0 10.0 ------14.8 ND ---ND ---6.6 J ---ND ---ND ND
Alkalinity, Total as CaCO3 23-Jun-10 5,000 5,000 ---7,290 ---20,400 ---82,100 ---253,000 ---135,000 ------ND
NC 2L = NE µg/L (2/5/10)14-Dec-10 5,000 5,000 ---------17,600 ---99,800 ---291,000 ---169,000 ---178,000 ND
21-Jun-11 5,000 5,000 ------100,000 20,800 ---77,000 ---269,000 ---194,000 ---156,000 ND
6-Dec-11 5,000 5,000 ------98,700 10,500 ---81,900 ---274,000 ---164,000 ---151,000 ND
13-Jun-12 1,000 1,000 ------101,000 13,700 ---87,500 ---271,000 ---152,000 ---149,000 ND
11-Dec-12 1,000 5,000 ------100,000 16,500 ---98,300 ---284,000 ---147,000 ---152,000 ND
29-Apr-13 1,000 5,000 ------99,300 13,800 ---97,300 ---293,000 ---156,000 ---122,000 ND
6-Aug-13 1,000 5,000 ------102,000 14,300 ---99,100 ---148,000 ---86,800 ---159,000 ND
25-Feb-14 1,000 5,000 ------107,000 15,800 ---123,000 ---298,000 ---178,000 ---153,000 ND
13-Aug-14 1000 5000 ------103000 14300 ---93800 ---301000 ---187000 ---164000 ND
12-Mar-15 1000 5000 ------99700 14700 ---88300 ---306000 ---151000 ---164000 ND
19-Aug-15 1000 5000 ------102000 19600 ---88200 ---294000 ---180000 ---164000 ND
18-Feb-16 1000 5000 ------108000 4350 J ---89800 ---308000 ---141000 ---168000 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Chloride 23-Jun-10 5,000 5,000 ---7,950 ---ND ---37,400 ---40,000 ---39,700 ---97,900 ND
NC 2L = 250000 µg/L (2/5/10)14-Dec-10 5,000 5,000 ---------5,100 ---38,400 ---44,500 ---39,600 ---108,000 ND
21-Jun-11 5,000 5,000 ------8,600 ND ---35,800 ---45,300 ---41,400 ---106,000 ND
6-Dec-11 5,000 5,000 ------9,340 ND ---28,600 ---49,200 ---39,200 ---110,000 ND
13-Jun-12 1,000 1,000 ------9,410 4,540 ---29,400 ---49,300 ---46,400 ---109,000 ND
11-Dec-12 1,000 1,000 ------8,570 5,220 ---30,800 ---50,600 ---46,600 ---107,000 ND
29-Apr-13 1,000 1,000 ------9,550 4,120 ---30,000 ---49,800 ---22,300 ---122,000 ND
6-Aug-13 1,000 1,000 ------7,590 5,180 ---25,700 ---50,100 ---48,700 ---107,000 ND
25-Feb-14 1,000 1,000 ------9,140 5,510 ---33,200 ---60,300 ---57,400 ---120,000 ND
13-Aug-14 500 1,000 ------8,030 4,070 ---21,300 ---97,600 ---43,400 ---106,000 ND
12-Mar-15 500 1,000 ------8,840 4,350 ---20,700 ---51,700 ---42,600 ---121,000 ND
19-Aug-15 500 1,000 ------9,440 5,160 ---23,200 ---51,500 ---48,500 ---111,000 ND
18-Feb-16 500 1,000 ------17,200 4,600 ---20,600 ---69,500 ---49,700 ---153,000 ND
Total Cyanide 8-Jul-08 ---10.0 ---------ND ---ND ---6.2 J ---ND ---ND ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
8-Jul-09 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------ND ---------------------------------
23-Jun-10 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 5.0 10 ---------5.8 J ---6.2 J ---5.2 J ---------------
11-Dec-12 ---------------------------------------------
29-Apr-13 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
Sulfide 17-Nov-95 ---1,000 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---1,000 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---1,000 ND ND ---1,000 ND ---ND ---1,200 ---1400 ------
27-May-98 ---1,000 ND ND ---1,000 ND ---ND ---ND ---ND ------
16-Nov-98 ---1,000 12,000 1,200 ---13,000 2,200 ---ND ---13,000 ---ND ------
10-Sep-99 ---1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1,000 ---------17,000 ---5,000 ---47,000 ---33,000 ---36,000 ---
26-Oct-00 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---1,000 ---------------------------------ND ---
30-Dec-03 ---1,000 ---------------------------------------
30-Jun-04 ---1,000 ---ND ---ND ---7 ---ND ---ND ---ND ---
29-Dec-04 ---1,000 ---------------------------------------
29-Jun-05 ---1,000 ---ND ---ND ---ND ---ND ---ND ---1,200 ND
29-Dec-05 ---1,000 ---1,200 B ---ND ---ND ---1,700 B ---ND ---ND 1,200
28-Jun-06 ---1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1,000 ---700 J ---ND ---500 J ---ND ---ND ---ND ND
12-Jul-07 ---1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---1,000 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1,000 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 100 1,000 ---259 J ---ND ---150 J ---ND ---141 J ---ND ND
8-Jul-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 100 1,000 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 100 1,000 ------ND ND ---ND ---ND ---117 J ---ND ND
29-Apr-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 100 1,000 ------ND ND ---141 J ---189 J ---ND ---ND ND
13-Aug-14 50 1,000 ------ND ------------------ND ------ND
12-Mar-15 100 1,000 ------ND ------------------ND ------ND
19-Aug-15 100 1,000 ------ND ------------------ND ------ND
18-Feb-16 100 1,000 ------ND ------------------ND ------ND
Sulfate 23-Jun-10 ---5,000 ---5,160 ---14,800 ---7,180 ---9,140 ---ND ------ND
NC 2L = 250000 µg/L (2/5/10)14-Dec-10 ---5,000 ---------14,500 ---9,210 ---9,700 ---ND ---ND ND
21-Jun-11 ---5,000 ------24,400 11,400 ---7,490 ---7,740 ---ND ---ND ND
6-Dec-11 5,000 5,000 ------39,800 13,800 ---8,000 ---7,730 ---ND ---ND ND
13-Jun-12 2,000 250,000 ------25,400 J 13,700 J ---8,140 J ---8,400 J ---2,790 J ---3,040 J ND
11-Dec-12 2,000 250,000 ------28,000 J 14,800 J ---9,120 J ---10,100 J ---4,420 J ---2,900 J ND
29-Apr-13 2,000 250,000 ------26,100 J 12,300 J ---9,150 J ---17,100 J ---2,730 J ---3,200 J ND
6-Aug-13 2,000 250,000 ------25,300 J 7,370 J ---7,830 J ---11,700 J ---2,760 J ---3,320 J ND
25-Feb-14 2,000 250,000 ------28,900 J 11,200 J ---8,130 J ---9,550 J ---2,590 J ---4,620 J ND
13-Aug-14 1,000 250,000 ------31,900 J 9,370 J ---7,910 J ---11,600 J ---2,450 J ---2,780 J ND
12-Mar-15 1,000 250,000 ------32,600 J 12,100 J ---8,040 J ---8,340 J ---3,400 J ---3,330 J ND
19-Aug-15 10,000 250,000 ------42,900 J 10,200 J ---8,110 J ---10,400 J ---2,890 J ---3,210 J ND
18-Feb-16 2,000 500,000 ------39,300 J 11,200 J ---7,960 J ---10,300 J ---3,830 J ---3,310 J ND
Total Dissolved Solids, Dissolved 23-Jun-10 250,000 250,000 ---710,000 ---96,200 ---184,000 ---364,000 ---237,000 ---360,000 ND
NC 2L = 500,000 µg/L (2/5/10)14-Dec-10 25,000 25,000 ---------100,000 ---218,000 ---372,000 ---260,000 ---347,000 ND
21-Jun-11 5,000 5,000 ------170,000 89,000 ---194,000 ---374,000 ---238,000 ---378,000 ND
6-Dec-11 25,000 25,000 ------174,000 92,000 ---168,000 ---378,000 ---242,000 ---408,000 ND
13-Jun-12 25,000 25,000 ------189,000 98,000 ---184,000 ---390,000 ---253,000 ---402,000 ND
11-Dec-12 25,000 25,000 ------199,000 141,000 ---199,000 ---427,000 ---274,000 ---419,000 ND
29-Apr-13 25,000 25,000 ------170,000 114,000 ---183,000 ---416,000 ---276,000 ---466,000 ND
6-Aug-13 25,000 25,000 ------179,000 142,000 ---175,000 ---421,000 ---291,000 ---423,000 ND
25-Feb-14 25,000 25,000 ------173,000 109,000 ---206,000 ---405,000 ---281,000 ---421,000 ND
13-Aug-14 25000 25000 ------172000 184000 ---187000 ---446000 ---319000 ---504000 ND
12-Mar-15 25000 25000 ------229000 113000 ---184000 ---430000 ---256000 ---470000 ND
19-Aug-15 25000 25000 ------217000 149000 ---172000 ---431000 ---303000 ---487000 ND
18-Feb-16 25000 25000 ------162000 84000 ---140000 ---412000 ---237000 ---475000 ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
# = Data for MW-1A during the July 2008 event was not used in background calculations because samples were composed of too much sediment due to basically dry conditions, leading to skewed values of inorganic constituents.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 9
Joyce Engineering

Appendix D

Historical Detected Organic Constituents in Compliance Wells

APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Organic Compounds
Acetone 15-Dec-09 2.2 100 ---ND ---ND ---ND ---ND ---ND ---ND 2.8 J
23-Jun-10 2.2 100 ---ND ---ND ---ND ---ND ---ND ---ND 7.7 J
NC 2L = 700 µg/L (10/23/07)14-Dec-10 2.2 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 2.2 100 ------ND 3.8 B ---2.8 B ---ND ---ND ---ND 3.9 J
NC 2B = NE µg/L (05/01/07)6-Dec-11 2.2 100 ------ND ND ---ND ---ND ---ND ---ND 8.8 J
NC 2L = 6,000 µg/L (2/5/10)13-Jun-12 2.2 100 ------ND ND ---ND ---ND ---ND ---ND 4.7 J
12-Dec-12 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 100 ------ND ND ---ND ---ND ---ND ---ND 14.6 J
6-Aug-13 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 100 ------ND ND ---ND ---ND ---ND ---ND 19.3 J
13-Aug-14 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
Benzene 14-Sep-94 ---5 ND ND ---ND 12.0 ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND 14.0 ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND 15.0 ---ND ---ND ---ND ------
2-Mar-95 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND 16.0 ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND 15.0 ---ND ---ND ---ND ------
14-Nov-96 ---5 ND ND ---ND 9.0 ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
27-May-98 ---5 ND ND ---ND 12.0 ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND 12.4 ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---7.0 ---ND ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---12.0 ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND 1.3 ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---0.40 J ---ND ND
NC 2L = 1 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---0.53 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.59 J ---ND ND
16-Dec-08 0.25 1.0 ---ND ---ND ---ND ---ND ---0.40 J ---ND ND
8-Jul-09 0.25 1.0 ---ND ---ND ---ND ---ND ---0.54 J ---ND ND
15-Dec-09 0.25 1.0 ---ND ---ND ---ND ---ND ---0.37 J ---ND ND
23-Jun-10 0.25 1.0 ---ND ---ND ---ND ---ND ---0.42 J ---ND ND
14-Dec-10 0.25 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.25 1.0 ------ND ND ---ND ---ND ---0.39 J ---ND ND
6-Dec-11 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
13-Jun-12 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.25 1.0 ------ND ND ---ND ---ND ---0.41 J ---ND ND
29-Apr-13 0.25 1.0 ------ND ND ---ND ---ND ---0.33 J ---ND ND
6-Aug-13 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
25-Feb-14 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
13-Aug-14 0.25 1.0 ------ND ND ---ND ---ND ---0.41 J ---ND ND
12-Mar-15 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.25 1.0 ------ND ND ---ND ---ND ---0.35 J ---ND ND
18-Feb-16 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Carbon Disulfide 18-Jun-97 ---100 ND ND ---ND ND ---ND ---ND ---16.0 ------
2-Dec-97 ---100 ND ND ---ND 12.0 ---ND ---ND ---23.0 ------
27-May-98 ---100 ND ND ---ND ND ---ND ---ND ---46.0 ------
16-Nov-98 ---100 ND ND ---ND 3.3 ---ND ---ND ---33.5 ------
10-Sep-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---100 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 1.2 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Chlorobenzene 16-Nov-98 ---5 ND ND ---ND ND ---2.7 ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND ---ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---3 ---ND ---ND ---ND ---ND ---0.34 J ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---3 ---------ND ---0.64 J ---ND ---0.44 J ---ND ND
8-Jul-08 ---3.0 ---------ND ---ND ---ND ---0.97 J ---ND ND
16-Dec-08 0.23 3.0 ---ND ---ND ---ND ---ND ---0.42 J ---ND ND
8-Jul-09 0.23 3.0 ---ND ---ND ---0.25 J ---ND ---0.57 J ---ND ND
15-Dec-09 0.23 3.0 ---ND ---ND ---0.25 J ---ND ---0.49 J ---ND ND
23-Jun-10 0.23 3.0 ---ND ---ND ---0.26 J ---ND ---0.53 J ---ND ND
14-Dec-10 0.23 3.0 ---------ND ---ND ---ND ---0.93 B ---ND 0.43 J
21-Jun-11 0.23 3.0 ------ND ND ---0.27 J ---ND ---0.65 J ---ND ND
6-Dec-11 0.23 3.0 ------ND ND ---ND ---ND ---0.63 J ---ND ND
13-Jun-12 0.23 3.0 ------ND ND ---ND ---ND ---0.55 J ---ND ND
12-Dec-12 0.23 3.0 ------ND ND ---ND ---ND ---1.0 J ---ND ND
29-Apr-13 0.23 3.0 ------ND ND ---ND ---ND ---0.70 J ---ND ND
6-Aug-13 0.23 3.0 ------ND ND ---ND ---ND ---0.83 J ---ND ND
25-Feb-14 0.23 3.0 ------ND ND ---ND ---ND ---0.78 J ---ND ND
13-Aug-14 0.23 3.0 ------ND ND ---ND ---ND ---0.87 J ---ND ND
12-Mar-15 0.23 3.0 ------ND ND ---ND ---ND ---0.64 J ---ND ND
19-Aug-15 0.23 3.0 ------ND ND ---ND ---ND ---0.89 J ---ND ND
18-Feb-16 0.23 3.0 ------ND ND ---ND ---ND ---0.79 J ---ND ND
Chloroethane 14-Sep-94 ---10 ND ND ---ND 30.0 ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND 26.0 ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND 33.0 ---ND ---ND ---35.0 ------
2-Mar-95 ---10 ND ND ---ND 26.0 ---ND ---ND ---24.0 ------
17-Nov-95 ---10 ND ND ---ND 25.0 ---ND ---ND ---27.0 ------
23-May-96 ---10 ND ND ---ND 26.0 ---ND ---ND ---56.0 ------
14-Nov-96 ---10 ND ND ---ND 16.0 ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND 21.0 ---ND ---ND ---63.0 ------
2-Dec-97 ---10 ND ND ---ND 22.0 ---2.0 ---ND ---64.0 ------
27-May-98 ---10 ND ND ---ND 16.0 ---ND ---ND ---78.0 ------
16-Nov-98 ---10 ND ND ---ND 15.8 ---ND ---ND ---36.2 ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 2,800 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 3,000 µg/L (2/5/10)23-Jun-10 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.54 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Chloromethane 23-Jun-10 0.11 1.0 ---0.14 J ---ND ---0.12 J ---ND ---ND ---0.16 J ND
NC 2L = 3 µg/L (2/5/10)14-Dec-10 0.11 1.0 ---------ND ---ND ---ND ---ND ---ND ND
NC 2B = NE µg/L (05/01/07)21-Jun-11 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,2-Dichlorobenzene 12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---0.6 J ---ND ND
NC 2B = NE µg/L (05/01/07)19-Dec-07 ---5 ---------ND ---0.32 J ---ND ---0.99 J ---ND ND
NC 2L = 24 µg/L (10/23/07)8-Jul-08 ---5.0 ---------ND ---ND ---ND ---1.3 J ---ND ND
16-Dec-08 0.30 5.0 ---ND ---ND ---ND ---ND ---0.73 J ---ND ND
8-Jul-09 0.30 5.0 ---ND ---ND ---ND ---ND ---1.1 J ---ND ND
15-Dec-09 0.30 5.0 ---ND ---ND ---ND ---ND ---0.99 J ---ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.30 5.0 ---ND ---ND ---ND ---ND ---1.0 J ---ND ND
14-Dec-10 0.30 5.0 ---------ND ---ND ---ND ---0.78 J ---ND ND
21-Jun-11 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
6-Dec-11 0.30 5.0 ------ND ND ---ND ---ND ---0.74 J ---ND ND
13-Jun-12 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
12-Dec-12 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
29-Apr-13 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
6-Aug-13 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
25-Feb-14 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
13-Aug-14 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
12-Mar-15 0.30 5.0 ------ND ND ---ND ---ND ---0.89 J ---ND ND
19-Aug-15 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
18-Feb-16 0.30 5.0 ------ND ND ---ND ---ND ---1.0 J ---ND ND
1,3-Dichlorobenzene 8-Jul-08 ---5.0 ---------ND ---ND ---ND ---0.29 J ---ND ND
NC 2L = 170 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 5.0 ---ND ---ND ---ND ---ND ---0.38 J ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 200 µg/L (2/5/10)23-Jun-10 0.24 5.0 ---------ND ---------ND ---0.35 J ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.24 5.0 ------ND ND ---------ND ---0.32 J ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.24 5.0 ------ND ND ---ND ---ND ---0.29 J ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.24 5.0 ------ND ND ---ND ---ND ---0.36 J ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.24 5.0 ------ND ND ---ND ---ND ---0.29 J ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.24 5.0 ------ND ------------------ND ------ND
18-Feb-16 0.24 5.0 ------ND ------------------0.31 J ------ND
1,4-Dichlorobenzene 14-Sep-94 ---5 ND ND ---ND 5.0 ---ND ---ND ---ND ---NA
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
8-Feb-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND 2.0 ---2.0 ---ND ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND 2.1 ---3.2 ---ND ---2.2 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10.5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND 3.7 ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---0.32 J ---ND ---ND ---ND ND
Resample >21-Aug-07 ---1 ---------------0.30 J ---------------------
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---0.52 J ---ND ---0.71 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.96 J ---ND ND
16-Dec-08 0.33 1.0 ---ND ---ND ---ND ---ND ---0.64 J ---ND ND
8-Jul-09 0.33 1.0 ---ND ---ND ---ND ---ND ---0.84 J ---ND ND
15-Dec-09 0.33 1.0 ---ND ---ND ---ND ---ND ---0.76 J ---ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.33 1.0 ---ND ---ND ---ND ---ND ---0.79 J ---ND ND
14-Dec-10 0.33 1.0 ---------ND ---ND ---ND ---0.96 B ---ND 0.35 J
21-Jun-11 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
6-Dec-11 0.33 1.0 ------ND ND ---ND ---ND ---0.81 J ---ND ND
13-Jun-12 0.33 1.0 ------ND ND ---ND ---ND ---0.77 J ---ND ND
12-Dec-12 0.33 1.0 ------ND ND ---ND ---ND ---0.83 J ---ND ND
29-Apr-13 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
6-Aug-13 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
25-Feb-14 0.33 1.0 ------ND ND ---ND ---ND ---0.82 J ---ND ND
13-Aug-14 0.33 1.0 ------ND ND ---ND ---ND ---0.97 J ---ND ND
12-Mar-15 0.33 1.0 ------ND ND ---ND ---ND ---0.86 J ---ND ND
19-Aug-15 0.33 1.0 ------ND ND ---ND ---ND ---1.00 ---ND ND
18-Feb-16 0.33 1.0 ------ND ND ---ND ---ND ---0.92 J ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Trans-1,4-Dichloro-2-Butene 27-May-98 ---100 ND ND ---ND ND ---ND ---ND ---6.9 ------
16-Nov-98 ---100 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---100 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 1.0 100 ---------ND ---ND ---ND ---ND ---ND ND
14-Dec-10 1.0 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
Dichlorodifluoromethane 17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---5 ND ND ---ND ND ---6.1 ---ND ---6.0 ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---------------------------------------
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---------------------------------------
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ------------------------ND ---ND ------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1,400 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------ND ---------------------------
8-Jul-09 0.21 5.0 ---ND ---ND ---ND ---ND ---0.37 J ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 1000 µg/L (2/5/10)23-Jun-10 0.21 5.0 ---------ND ---ND ---ND ---0.29 J ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.21 5.0 ------ND ND ---ND ---ND ---0.36 J ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.21 5.0 ------ND ------------------ND ------ND
18-Feb-16 0.21 5.0 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,1-Dichloroethane 14-Sep-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND ND ---ND ---7.0 ---ND ------
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---5.0 ---7.0 ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---ND ---9.7 ------
2-Dec-97 ---5 ND ND ---ND ND ---2.0 ---10.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---6.0 ---12.0 ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---9.0 ---5.2 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---6.0 ---ND ---
16-Dec-99 ---5 ---------------------------5.0 ---------
10-May-00 ---5 ND ND ---ND ---ND ---ND ---6.0 ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---7.0 ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---7.2 ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---6.3 ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---6.5 ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---6.9 ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---6.6 ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ND ND 1.7 5.3 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---0.33 J ---ND ---5.4 ---ND ND
Resample >21-Aug-07 ---5 ---------------0.40 J ---------------------
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ---------ND ---ND ---ND ---6.2 ---ND ND
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---5.1 ---ND ND
16-Dec-08 0.32 5.0 ---ND ---ND ---ND ---ND ---3.4 J ---ND ND
8-Jul-09 0.32 5.0 ---ND ---ND ---ND ---ND ---9.3 ---ND ND
15-Dec-09 0.32 5.0 ---ND ---ND ---ND ---ND ---6.4 ---ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.32 5.0 ---ND ---ND ---ND ---ND ---6.5 ---ND ND
14-Dec-10 0.32 5.0 ---------ND ---ND ---ND ---3.9 J ---ND ND
21-Jun-11 0.32 5.0 ------ND ND ---ND ---ND ---6.7 ---ND ND
6-Dec-11 0.32 5.0 ------ND ND ---ND ---ND ---3.0 J ---ND ND
13-Jun-12 0.32 5.0 ------ND ND ---ND ---ND ---3.7 J ---ND ND
12-Dec-12 0.32 5.0 ------ND ND ---ND ---ND ---2.5 J ---ND ND
29-Apr-13 0.32 5.0 ------ND ND ---ND ---ND ---5.8 ---ND ND
6-Aug-13 0.32 5.0 ------ND ND ---ND ---ND ---5.0 ---ND ND
25-Feb-14 0.32 5.0 ------ND ND ---ND ---ND ---4.5 J ---0.35 J ND
13-Aug-14 0.32 5.0 ------ND ND ---ND ---ND ---3.4 J ---0.39 J ND
12-Mar-15 0.32 5.0 ------ND ND ---ND ---ND ---4.2 J ---ND ND
19-Aug-15 0.32 5.0 ------ND ND ---ND ---ND ---3.7 J ---0.54 J ND
18-Feb-16 0.32 5.0 ------ND ND ---ND ---ND ---3.4 J ---0.59 J ND
1,2-Dichloroethane 6-Aug-13 0.12 1.0 ------ND ND ---0.62 J ---ND ---ND ---ND ND
NC 2L = 0.4 µg/L (2/5/10)25-Feb-14 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.24 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.24 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
cis-1,2-Dichloroethene 14-Sep-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND ND ---ND ---23.0 ---ND ------
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---14.0 ---ND ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---19.0 ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---12.0 ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---23.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---12.0 ---5.8 ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---24.8 ---3.7 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---7.0 ---ND ---
16-Dec-99 ---5 ---------------------------7.0 ---------
10-May-00 ---5 ND ND ---ND ---ND ---ND ---8.0 ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---9.0 ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---13.0 ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---12.0 ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---10.0 ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---9.3 ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---9.4 ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ND ND ---8.8 ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ---ND 5.3 6.0 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---6.2 ---ND ND
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ---------ND ---ND ---ND ---7.2 ---ND ND
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---9.8 ---ND ND
16-Dec-08 1.9 5.0 ---ND ---ND ---ND ---0.91 B ---4.2 J ---ND 0.31 J
8-Jul-09 0.19 5.0 ---ND ---ND ---ND ---ND ---7.7 ---ND ND
15-Dec-09 0.19 5.0 ---ND ---ND ---ND ---ND ---7.4 ---ND ND
23-Jun-10 0.19 5.0 ---ND ---ND ---ND ---ND ---7.1 ---ND ND
14-Dec-10 0.19 5.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.19 5.0 ------ND ND ---ND ---ND ---6.4 ---ND ND
6-Dec-11 0.19 5.0 ------ND ND ---ND ---ND ---3.0 J ---ND ND
13-Jun-12 0.19 5.0 ------ND ND ---ND ---ND ---4.3 J ---ND ND
12-Dec-12 0.19 5.0 ------ND ND ---ND ---ND ---3.3 J ---ND ND
29-Apr-13 0.19 5.0 ------ND ND ---ND ---ND ---4.8 J ---ND ND
6-Aug-13 0.19 5.0 ------ND ND ---ND ---ND ---3.6 J ---ND ND
25-Feb-14 0.19 5.0 ------ND ND ---ND ---ND ---3.7 J ---ND ND
13-Aug-14 0.19 5.0 ------ND ND ---ND ---ND ---2.8 J ---ND ND
12-Mar-15 0.19 5.0 ------ND ND ---ND ---ND ---2.6 J ---ND ND
19-Aug-15 0.19 5.0 ------ND ND ---ND ---ND ---3.1 J ---0.35 J ND
18-Feb-16 0.19 5.0 ------ND ND ---ND ---ND ---2.5 J ---0.32 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
2-Hexanone 27-May-98 ---50 ND ND ---ND ND ---ND ---ND ---61.0 ------
16-Nov-98 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---50 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 280 µg/L (10/23/07)19-Dec-07 ---50 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---50.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.46 50.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.46 50.0 ------ND ND ---0.55 J ---ND ---ND ---ND ND
25-Feb-14 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
Methylene Chloride 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ---NA
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---6.0 ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---17.0 ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---8.2 ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---12.0 ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---15.0 ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 4.6 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---2.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND 9.6
15-Dec-09 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 5 µg/L (2/5/10)23-Jun-10 0.97 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.97 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND 1.9 J
13-Aug-14 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND 1.1
18-Feb-16 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Naphthalene 8-Jul-08 ---10.0 ---------ND ---ND ---ND ---ND ---2.9 J ND
NC 2L = 21 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.24 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.24 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.24 10.0 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Toluene 18-Jun-97 ---5 ND ND ---ND 13 ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---7 ---ND ---ND ---ND ---ND ---
19-Oct-99 ---5 ---------ND ---------------------------
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND 0.34 J
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 600 µg/L (2/5/10)23-Jun-10 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.26 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Trichloroethene 2-Dec-97 ---5 ND ND ---ND ND ---ND ---2.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---2.7 ---2.9 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---0.68 J ---ND ND
NC 2L = 2.8 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---0.64 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.51 J ---ND ND
16-Dec-08 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.47 1.0 ---ND ---ND ---ND ---ND ---0.53 J ---ND ND
15-Dec-09 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 3 µg/L (2/5/10)23-Jun-10 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.47 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Vinyl chloride 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---26.0 ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---13.0 ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---17.0 ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND 2.0 ---ND ---33.0 ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---13.0 ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---25.8 ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---12.0 ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
10-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---26.9 ---ND ND
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---10.0 ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---11.0 ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---12.0 ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---14.0 ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---15.0 ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---12.5 ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ND ND 8.1 8.9 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---8.3 ---ND ND
NC 2L = 0.015 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---8.4 ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---10.6 ---ND ND
16-Dec-08 0.62 1.0 ---ND ---ND ---ND ---ND ---5.0 ---ND ND
8-Jul-09 0.62 1.0 ---ND ---ND ---ND ---ND ---13.3 ---ND ND
15-Dec-09 0.62 1.0 ---ND ---ND ---ND ---ND ---9.9 ---ND ND
NC 2L = 0.03 µg/L (2/5/10)23-Jun-10 0.62 1.0 ---ND ---ND ---ND ---ND ---11.2 ---ND ND
14-Dec-10 0.62 1.0 ---------ND ---ND ---ND ---8.4 ---ND ND
21-Jun-11 0.62 1.0 ------ND ND ---ND ---ND ---10.5 ---ND ND
6-Dec-11 0.62 1.0 ------ND ND ---ND ---ND ---4.1 ---ND ND
13-Jun-12 0.62 1.0 ------ND ND ---ND ---ND ---6.6 ---ND ND
12-Dec-12 0.62 1.0 ------ND ND ---ND ---ND ---3.3 ---ND ND
29-Apr-13 0.62 1.0 ------ND ND ---ND ---ND ---7.6 ---ND ND
6-Aug-13 0.62 1.0 ------ND ND ---ND ---ND ---9.1 ---ND ND
25-Feb-14 0.62 1.0 ------ND ND ---ND ---ND ---6.8 ---ND ND
13-Aug-14 0.62 1.0 ------ND ND ---ND ---ND ---5.4 ---ND ND
12-Mar-15 0.62 1.0 ------ND ND ---ND ---ND ---5.1 ---ND ND
19-Aug-15 0.62 1.0 ------ND ND ---ND ---ND ---5.0 ---ND ND18-Feb-16 0.62 1.0 ------ND ND ---ND ---ND ---5.4 ---ND ND
Bis(2-ethylhexyl)phthalate 21-Jun-11 0.79 15.0 ------ND 2.5 J ---ND ---4.5 J ---ND ---ND ND
NC 2L = 3 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.79 15.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.79 15.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.79 15.0 ------ND ND ---40.4 ---5.0 J ---ND ---ND ND
Resample >15-Apr-14 0.79 15.0 ---------------ND ------------------ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.49 15.0 ------ND ------------------ND ------ND
18-Feb-16 0.85 15.0 ------ND ------------------ND ------ND
Diethylphthalate 17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---24.0 ---ND ---ND ------
23-Mar-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---10 ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---------------------------------------
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 5,000 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---20.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 2.7 11.1 ---ND ---------ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 6,000 µg/L (2/5/10)23-Jun-10 3.9 14.3 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.58 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.58 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.58 6000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.58 6000 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.91 6000 ------ND ------------------ND ------ND
18-Feb-16 1.30 6000 ------ND ------------------ND ------ND
Benzo(g,h,i)perylene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
NC 2L = 200 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.45 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.38 10.0 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dibenz(a,h)anthracene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
NC 2L = 0.005 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.49 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.55 10.0 ------ND ------------------ND ------ND
Indeno(1,2,3-cd)pyrene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
NC 2L = 0.05 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.29 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.29 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.29 10.0 ------ND ------ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.53 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.29 10.0 ------ND ------------------ND ------ND
Phorate 17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ---------ND ---1.0 ---ND ---0.8 ---ND ---
26-Oct-00 ---1.5 ---------ND ---5.2 ---ND ---ND ---ND ---
18-Apr-01 ---10 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---------------------------------------
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---------------------------------------
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---40.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 6.6 22.2 ---ND ---------ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 1 µg/L (2/5/10)23-Jun-10 7.7 28.6 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.83 10.0 ------ND ------------------ND ------ND
18-Feb-16 1.10 10.0 ------ND ------------------ND ------ND
Aldrin 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.073 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---------------------------------------
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---------------------------------------
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Alpha-BHC 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---0.20 ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND 0.073 ---0.16 ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---0.095 ---0.053 ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.23 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---------------------------------------
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---------------------------------------
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ---
GWPS = 0.006 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
23-Jun-10 0.00032 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00030 0.050 ------ND ND ---0.054 ---ND ---ND ---ND ND
Resample >28-Jul-11 0.00030 0.050 ---------------ND ------------------ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
Beta-BHC 27-Jun-03 ---1.05 ---ND ---ND ---0.068 ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 0.019 µg/L (10/23/07)19-Dec-07 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.010 0.100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.00050 0.050 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.00050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.050 0.050 ------ND ND ---ND ---ND ---0.059 ---ND ND
Resample >25-Jan-12 0.050 0.050 ------ND ------------------0.082 ------ND
13-Jun-12 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.050 0.050 ------ND ND ---ND ---ND ---0.078 ---ND ND
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---0.056 ---ND ND
13-Aug-14 0.050 0.050 ------ND ------------------ND ------ND
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
19-Aug-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
4,4'-DDT 23-Jun-10 0.0037 0.010 ---ND ---ND ---ND ---ND ---0.016 J ---ND ND
NC 2L = 0.1 µg/L (2/5/10)14-Dec-10 ---------------------------------ND ---------
NC 2B = 0.001 µg/L (05/01/07)21-Jun-11 0.0036 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------ND ---------
13-Jun-12 0.05 0.10 ------ND ND ---ND ---ND ---0.090 J ---ND ND
12-Dec-12 ---------------------------------ND ---------
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.10 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 10 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dieldrin 17-Nov-95 ---0.1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.1 ND ND ---ND ND ---0.10 ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.1 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---0.1 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.1 ---------------------------------------
30-Jun-04 ---0.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.1 ---------------------------------------
28-Jun-06 ---0.1 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = 0.002 µg/L (05/01/07)12-Jul-07 ---0.075 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 0.0022 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.075 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.075 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 0.002 µg/L (2/5/10)23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------ND ---------
29-Apr-13 0.050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.075 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.075 ------ND ------------------ND ------ND
Endosulfan I 21-Jun-11 0.00070 0.10 ------ND ND ---0.52 ---ND ---ND ---ND ND
NC 2L = 40 µg/L (2/5/10) Resample >28-Jul-11 0.00070 0.10 ---------------ND ------------------ND
6-Dec-11 ---------------------ND ------------------ND
13-Jun-12 0.050 0.10 ------ND ND ---0.33 ---ND ---ND ---ND ND
12-Dec-12 0.050 0.10 ------ND ND ---1.33 ---ND ---ND ---ND ND
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.050 0.10 ------ND ------------------ND ------ND
12-Mar-15 0.050 0.10 ------ND ------------------ND ------ND
19-Aug-15 0.050 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.10 ------ND ------------------ND ------ND
Endosulfan Sulfate 13-Jun-12 0.050 0.10 ------ND ND ---0.090 J ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.05 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.05 0.10 ------ND ------------------ND ------ND
Heptachlor 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.068 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ------------------------------------ND
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.05 ------------------------------------ND
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ------------------------------------ND
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2B = 0.004 µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 ---0.05 ------------------------------------ND
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 0.008 µg/L (2/5/10)23-Jun-10 0.0016 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.0015 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 11 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Methoxychlor 17-Nov-95 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---1 ND ND ---ND ND ---0.51 ---ND ---ND ------
10-Sep-99 ---1 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---1 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---1 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---------------------------------------------
30-Jun-04 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---1 ---------------------------------------
28-Jun-06 ---1 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = 0.03 µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 35 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 40 µg/L (2/5/10)23-Jun-10 0.0074 1.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.0070 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.15 0.15 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.15 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.15 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.15 1.0 ------ND ------------------ND ------ND
18-Feb-16 0.15 1.0 ------ND ------------------ND ------ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 12 of 12
Joyce Engineering

Appendix E

Historical Detected COCs in Performance and Sentinel Wells

APPENDIX E:
Historical Detected COCs in Performance and Sentinel Wells
Sample
Analyte Collection Date RL NES-1S NES-1D NES-2S NES-2D Blanks
ORGANICS
Vinyl Chloride 18-May-04 10 ND ND ND ND ND
30-Jun-04 10 ND ND ND ND ND
28-Dec-06 6 ND NS ND NS ND
NC 2L = 0.015 µg/L (10/23/07)16-Dec-08 1 ND ND ND ND ND
8-Jul-09 1 ND ND ND ND ND
15-Dec-09 2 ND ND ND ND ND
NC 2L = 0.03 µg/L (01/01/10)23-Jun-10 1.0 ND ND ND ND ND
14-Dec-10 1.0 ND NS ND NS ND
21-Jun-11 1.0 ND ND ND ND ND
5-Dec-11 1.0 ND ND ND ND ND
13-Jun-12 1.0 ND ND ND ND ND
10-Dec-12 1.0 ND ND ND ND ND
30-Apr-13 1.0 ND ND ND ND ND
7-Aug-13 1.0 ND NS ND NS ND
25-Feb-14 1.0 ND ND ND ND ND
13-Aug-14 1.0 NS NS ND NS ND
12-Mar-15 1.0 NS NS ND NS ND
19-Aug-15 1.0 NS NS ND NS ND
18-Feb-16 1.0 NS NS ND NS ND
1,1-Dichloroethane *18-May-04 5 ND ND ND ND ND
30-Jun-04 5 ND ND ND ND ND
28-Dec-06 5 ND NS ND NS ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 5 NS NS NS NS NS
8-Jul-09 5 NS NS NS NS NS
15-Dec-09 5 NS NS NS NS NS
NC 2L = 6 µg/L (01/01/10)23-Jun-10 5.0 NS NS ND*ND*ND
14-Dec-10 5.0 0.32 J NS ND NS ND
21-Jun-11 5.0 ND 0.33 J ND ND ND
5-Dec-11 5.0 ND ND ND ND ND
13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND 0.38 J ND ND ND
30-Apr-13 5.0 ND 0.38 J ND ND ND
7-Aug-13 5.0 ND NS ND NS ND
25-Feb-14 5.0 ND 0.33 J ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
18-Feb-16 5.0 NS NS ND NS ND
beta-BHC *13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND ND ND ND ND
GWPS = 0.019 µg/L (10/23/07)30-Apr-13 5.0 ND ND ND ND ND
7-Aug-13 5.0 ND ND ND ND ND
25-Feb-14 5.0 ND ND ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
Notes:
COC = Constituents of Concern.µg/L = micrograms per liter = parts per billion.
RL = Reporting Limit. J = Estimated concentraion below the RL.
B = Blank-qualified detection.
* 1,1-DCA was added to the COC list and Benzene and cis-1,2-dichloroethylene ND = Not detected above the laboratory detection limit.
were dropped following DENR SWS approval dataed January 27, 2011.NS = Not sampled for this parameter during this event.
1,1-DCA and beta-BHC were dropped from the COC list following DENR-SWS
approval dated July 30, 2015.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Joyce Engineering

Appendix F

Historical Detected Constituents in Surface Water

APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
INORGANICS
Antimony 23-Jun-10 2.6 6.0 2.8 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 2.6 6.0 ND Dry ND
21-Jun-11 5.0 6.0 ND Dry ND
6-Dec-11 5.0 6.0 ND ND ND
13-Jun-12 5.0 6.0 ND ND ND
11-Dec-12 5.0 6.0 ND Dry ND
29-Apr-13 5.0 6.0 ND ND ND
6-Aug-13 5.0 6.0 ND ND ND
25-Feb-14 5.0 6.0 ND ND ND
13-Aug-14 5.0 6.0 ND ND ND
11-Mar-15 3.8 6.0 ND ND ND
19-Aug-15 3.8 6.0 ND Dry ND
18-Feb-16 3.8 6.0 ND ND ND
Arsenic 19-Dec-07 NR 10 5.3 Dry ND
NC 2B = 50 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 2.7 11.0 ND ND ND
8-Jul-09 2.7 10.0 ND Dry ND
15-Dec-09 2.7 10.0 ND 2.7 J ND
23-Jun-10 2.7 10.0 9.2 J ND ND
14-Dec-10 2.7 10.0 3.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 6.5 J ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 4.9 J 2.7 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 1 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Barium 14-Sep-94 NR 500 160 ND NS
2-Dec-94 NR 500 ND ND NS
8-Feb-95 NR 500 ND ND NS
2-Mar-95 NR 500 ND ND NS
17-Nov-95 NR 500 ND ND NS
23-May-96 NR 500 ND ND NS
14-Nov-96 NR 500 69 29 NS
18-Jun-97 NR 500 64 25 NS
2-Dec-97 NR 500 61 41 NS
27-May-98 NR 500 130 50 NS
16-Nov-98 NR 500 93 100 NS
10-Sep-99 NR 500 ND ND NS
16-Nov-99 NR 500 ND ND NS
10-May-00 NR 500 ND ND NS
26-Oct-00 NR 500 ND ND NS
18-Apr-01 NR 500 ND ND NS
19-Nov-02 NR 500 NS ND NS
27-Jun-03 NR 500 ND ND NS
30-Dec-03 NR 500 ND ND ND
30-Jun-04 NR 500 ND ND ND
29-Dec-04 NR 500 ND ND ND
29-Jun-05 NR 500 ND ND ND
29-Dec-05 NR 500 ND ND ND
28-Jun-06 NR 500 ND ND ND
NC 2B = NE (05/01/07)28-Dec-06 NR 100 40.0 47.2 0.20 J
12-Jul-07 NR 100 66.2 J Dry ND
19-Dec-07 NR 100 112 Dry 10.5
8-Jul-08 NR 100 89.0 J Dry 0.29 J
16-Dec-08 0.20 100 42.1 B 54.8 J 10.7 J
8-Jul-09 0.20 100 101 Dry 17.6 J
15-Dec-09 0.20 100 36.3 B 48.4 B 17.1 J
23-Jun-10 0.20 100 115 B 39.1 B 27.3 J
14-Dec-10 0.20 100 97.4 J Dry 12.1 J
21-Jun-11 5.0 100 66.3 J Dry ND
6-Dec-11 5.0 100 59.7 J 55.3 J ND
13-Jun-12 5.0 100 161 85.4 J ND
11-Dec-12 5.0 100 71.1 J Dry ND
29-Apr-13 5.0 100 43.5 J 43.5 J ND
6-Aug-13 5.0 100 80.3 J 23.8 J ND
25-Feb-14 5.0 100 63.9 J 61.8 J ND
13-Aug-14 5.0 100 47.4 J 43.9 J ND
11-Mar-15 2.5 100 28.5 J 42.0 J ND
19-Aug-15 2.5 100 37.0 J Dry ND
18-Feb-16 2.5 100 58.2 J 55.0 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 2 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Beryllium 16-Nov-98 NR 2 1.0 1.0 NS
NC 2B = 6.5 µg/L (05/01/07)10-Sep-99 NR 2 ND ND NS
16-Nov-99 NR 2 ND ND NS
10-May-00 NR 2 ND ND NS
26-Oct-00 NR 2 ND ND NS
18-Apr-01 NR 2 ND ND NS
19-Nov-02 NR 2 ND ND NS
27-Jun-03 NR 2 ND ND NS
30-Dec-03 NR 2 ND ND ND
30-Jun-04 NR 2 ND ND ND
29-Dec-04 NR 2 ND ND ND
29-Jun-05 NR 2 ND ND ND
29-Dec-05 NR 2 ND ND ND
28-Jun-06 NR 2 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 6.5 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
19-Dec-07 NR 1 0.93 J Dry ND
8-Jul-08 NR 1.0 0.47 J Dry ND
16-Dec-08 0.10 1.0 0.21 J 0.27 J ND
8-Jul-09 0.10 1.0 0.29 J Dry ND
15-Dec-09 0.10 1.0 0.27 J 0.22 J ND
23-Jun-10 0.10 1.0 1.2 ND ND
14-Dec-10 0.10 1.0 0.78 J Dry ND {0.15} J
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 1.5 ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND Dry ND
18-Feb-16 0.5 1.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cadmium 19-Nov-02 NR 1 ND 1.0 NS
27-Jun-03 NR 1 ND ND NS
30-Dec-03 NR 1 ND ND ND
30-Jun-04 NR 1 ND ND ND
29-Dec-04 NR 1 ND ND ND
29-Jun-05 NR 1 ND ND ND
29-Dec-05 NR 1 ND ND ND
28-Jun-06 NR 1 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 2 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 NR 1 ND Dry ND
8-Jul-08 NR 1.0 ND Dry ND
16-Dec-08 0.50 1.0 ND ND ND
8-Jul-09 0.50 1.0 ND Dry ND
15-Dec-09 0.50 1.0 ND ND ND
23-Jun-10 0.50 1.0 ND ND ND
14-Dec-10 0.50 1.0 ND Dry ND
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 ND ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND ND ND
18-Feb-16 0.5 1.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 4 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Chromium 18-Jun-97 NR 10 12.0 ND NS
2-Dec-97 NR 10 8.0 ND NS
27-May-98 NR 10 15.0 ND NS
16-Nov-98 NR 10 30.0 31.0 NS
10-Sep-99 NR 10 24.0 ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 12.6 ND ND
28-Dec-06 NR 10 4.8 J 6.1 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 27.9 Dry ND
8-Jul-08 NR 10.0 19.3 Dry ND
6-Dec-08 0.40 10.0 6.4 J 8.4 J ND
8-Jul-09 0.40 10.0 12.9 Dry ND
15-Dec-09 0.40 10.0 6.0 J 5.0 J ND
23-Jun-10 0.40 10.0 41.8 4.8 J 0.71 J
Resample >12-Aug-10 0.40 10.0 44.4 NS ND
14-Dec-10 0.40 10.0 32.4 Dry ND
21-Jun-11 5.0 10.0 12.1 Dry ND
6-Dec-11 5.0 10.0 11.8 7.5 J ND
13-Jun-12 5.0 10.0 46.1 20.7 ND
11-Dec-12 5.0 10.0 19.1 Dry ND
29-Apr-13 5.0 10.0 5.8 J 5.8 J ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 13.5 13.2 ND
13-Aug-14 5.0 10.0 10.8 10 J ND
11-Mar-15 2.5 10.0 4.0 J 3.1 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 5 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cobalt 14-Nov-96 NR 10 3.0 ND NS
18-Jun-97 NR 10 3.0 ND NS
2-Dec-97 NR 10 ND ND NS
27-May-98 NR 10 8.0 5.0 NS
16-Nov-98 NR 10 4.9 5.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 2.8 J ND
NC 2B = NE (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 34.3 Dry 1.6 J
8-Jul-08 NR 10.0 10.0 B Dry 6.2 J
16-Dec-08 0.60 10.0 4.8 B 5.1 B 2.4 J
8-Jul-09 0.60 10.0 7.2 J Dry ND
15-Dec-09 0.60 10.0 1.6 J 1.3 J ND
23-Jun-10 0.60 10.0 23.0 2.7 J ND
Resample >12-Aug-10 0.60 10.0 30.5 NS ND
14-Dec-10 0.60 10.0 27.0 Dry 1.6 J
21-Jun-11 5.0 10.0 5.4 J Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 12.5 6.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 10.2 10.8 ND
6-Aug-13 5.0 10.0 9.0 J ND ND
25-Feb-14 5.0 10.0 10.1 10.6 ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 6 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Copper 18-Jun-97 NR 200 11.0 ND NS
2-Dec-97 NR 200 11.0 ND NS
27-May-98 NR 200 21.0 ND NS
16-Nov-98 NR 200 14.0 16.0 NS
10-Sep-99 NR 200 ND ND NS
16-Nov-99 NR 200 ND ND NS
10-May-00 NR 200 ND ND NS
26-Oct-00 NR 200 ND ND NS
18-Apr-01 NR 200 ND ND NS
19-Nov-02 NR 200 NS ND NS
27-Jun-03 NR 200 ND ND NS
30-Dec-03 NR 200 ND ND ND
30-Jun-04 NR 200 ND ND ND
29-Dec-04 NR 200 ND ND ND
29-Jun-05 NR 200 ND ND ND
29-Dec-05 NR 200 ND ND ND
28-Jun-06 NR 200 ND ND ND
28-Dec-06 NR 10 3.0 B 3.9 0.60 J
NC 2B = 7 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 23.7 B Dry 10.5 B
8-Jul-08 NR 10.0 14.7 Dry ND
16-Dec-08 0.30 10.0 6.4 J 8.0 J ND
8-Jul-09 0.30 10.0 7.0 J Dry ND
15-Dec-09 0.30 10.0 5.2 J 4.4 J ND
23-Jun-10 0.30 10.0 23.9 2.7 J ND
Resample >12-Aug-10 0.30 10.0 25.9 ND ND
14-Dec-10 0.30 10.0 21.1 Dry 0.49 J
21-Jun-11 5.0 10.0 7.7 J Dry ND
6-Dec-11 5.0 10.0 12.5 7.7 J ND
13-Jun-12 5.0 10.0 34.5 14.8 ND
11-Dec-12 5.0 10.0 16.4 Dry ND
29-Apr-13 5.0 10.0 7.7 J 7.4 J ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 11.2 10.3 ND
13-Aug-14 5.0 10.0 9.6 J 7.7 J ND
11-Mar-15 2.5 10.0 3.1 J 2.6 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 6.3 J 5.7 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 7 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Lead 2-Dec-97 NR 10 ND 6.0 NS
27-May-98 NR 10 8.0 ND NS
16-Nov-98 NR 10 7.3 8.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 4.8 J ND
NC 2B = 25 µg/L (05/01/07)12-Jul-07 NR 10 3.2 J Dry ND
19-Dec-07 NR 10 ND Dry ND
8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 4.0 10.0 ND ND ND
8-Jul-09 4.0 10.0 ND Dry ND
15-Dec-09 4.0 10.0 ND ND ND
23-Jun-10 4.0 10.0 9.2 J ND ND
14-Dec-10 4.0 10.0 5.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 14.3 5.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 4.0 J 2.6 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 8 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Nickel 28-Dec-06 NR 50 4.6 J 6.2 J ND
NC 2B = 88 µg/L (05/01/07)12-Jul-07 NR 50 4.0 J Dry ND
19-Dec-07 NR 50 21.9 Dry ND
8-Jul-08 NR 50.0 12.1 J Dry ND
16-Dec-08 1.7 50.0 5.2 B 6.8 B 2.4 J
8-Jul-09 1.7 50.0 10.0 J Dry ND
15-Dec-09 1.7 50.0 4.8 B 4.7 B 3.0 J
23-Jun-10 1.7 50.0 21.5 J ND ND
14-Dec-10 1.7 50.0 14.4 J Dry 2.7 J
21-Jun-11 5.0 50.0 5.8 J Dry ND
6-Dec-11 5.0 50.0 7.2 J ND ND
13-Jun-12 5.0 50.0 17.1 J 7.5 J ND
11-Dec-12 5.0 50.0 7.6 J Dry ND
29-Apr-13 5.0 50.0 ND ND ND
6-Aug-13 5.0 50.0 ND ND ND
25-Feb-14 5.0 50.0 7.3 J 6.6 J ND
13-Aug-14 5.0 50.0 7.5 J 5.4 J ND
11-Mar-15 2.5 50.0 3.0 J 2.8 J ND
19-Aug-15 2.5 50.0 ND Dry ND
18-Feb-16 2.5 50.0 3.3 J 3.0 J ND
Selenium 19-Dec-07 NR 10 15.6 Dry ND
NC 2B = 5 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 3.8 10.0 3.9 B ND 4.9 J
8-Jul-09 3.8 10.0 ND Dry ND
15-Dec-09 3.8 10.0 ND ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ND ND ND
14-Dec-10 3.8 10.0 5.9 J Dry ND
21-Jun-11 10.0 10.0 ND Dry ND
6-Dec-11 10.0 10.0 ND ND ND
13-Jun-12 10.0 10.0 ND ND ND
11-Dec-12 10.0 10.0 ND Dry ND
29-Apr-13 10.0 10.0 ND ND ND
6-Aug-13 10.0 10.0 ND ND ND
25-Feb-14 10.0 10.0 ND ND ND
13-Aug-14 10.0 10.0 ND ND ND
11-Mar-15 5.0 10.0 ND ND ND
19-Aug-15 5.0 10.0 ND Dry ND
18-Feb-16 5.0 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 9 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Silver 8-Jul-08 NR 10.0 0.22 J Dry ND
NC 2B = 0.06 µg/L (05/01/07)16-Dec-08 0.10 10.0 ND 0.11 J ND
8-Jul-09 0.10 10.0 ND Dry ND
15-Dec-09 0.10 10.0 ND 0.19 J ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ND ND ND
14-Dec-10 0.10 10.0 0.21 B Dry {0.25 J} 0.19 J
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 ND ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
Thallium 19-Dec-07 NR 5.5 5.1 J Dry ND
NC 2B = NE (05/01/07)8-Jul-08 NR 5.5 5.2 J Dry ND
16-Dec-08 3.0 5.5 ND ND ND
8-Jul-09 3.0 5.5 ND Dry ND
15-Dec-09 3.0 5.5 ND ND ND
23-Jun-10 3.0 5.5 ND ND ND
Resample >12-Aug-10 30.0 55.0 NS NS ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 6.5 Dry ND
21-Jun-11 5.4 5.5 8.2 Dry ND
6-Dec-11 5.4 5.5 ND ND ND
13-Jun-12 5.4 5.5 ND ND ND
11-Dec-12 5.4 5.5 ND Dry ND
29-Apr-13 5.4 5.5 ND ND ND
6-Aug-13 5.4 5.5 ND ND ND
25-Feb-14 5.4 5.5 ND ND ND
13-Aug-14 5.4 5.5 ND ND ND
11-Mar-15 5.0 5.5 ND ND ND
19-Aug-15 5.0 5.5 ND Dry ND
18-Feb-16 5.0 5.5 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 10 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Vanadium 14-Nov-96 NR 40 11.0 5.0 NS
18-Jun-97 NR 40 20.0 ND NS
2-Dec-97 NR 40 16.0 ND NS
27-May-98 NR 40 44.0 ND NS
16-Nov-98 NR 40 44.0 47.0 NS
10-Sep-99 NR 40 ND ND NS
16-Nov-99 NR 40 ND ND NS
10-May-00 NR 40 ND ND NS
26-Oct-00 NR 40 ND ND NS
18-Apr-01 NR 40 ND ND NS
19-Nov-02 NR 40 ND ND NS
27-Jun-03 NR 40 ND ND NS
30-Dec-03 NR 40 ND ND ND
30-Jun-04 NR 40 ND ND ND
29-Dec-04 NR 40 ND ND ND
29-Jun-05 NR 40 ND ND ND
29-Dec-05 NR 40 ND ND ND
28-Jun-06 NR 40 ND ND ND
28-Dec-06 NR 25 8.6 J 10.7 ND
NC 2B = NE (05/01/07)12-Jul-07 NR 25 5.3 J ND ND
19-Dec-07 NR 25 41.2 ND 0.51 J
Resample >14-Feb-08 NR 25 12.4 Dry 0.24 J
Filtered >14-Feb-08 NR 25 1.6 J Dry ND
8-Jul-08 NR 25.0 38.2 Dry 0.20 J
16-Dec-08 0.20 25.0 11.5 J 14.1 J 0.76 J
8-Jul-09 0.20 25.0 24.3 J Dry 1.3 J
15-Dec-09 0.20 25.0 10 J 7.0 J 0.53 J
23-Jun-10 0.20 25.0 63.4 8.3 J ND
Resample >12-Aug-10 0.20 25.0 67.9 NS 0.33 J
14-Dec-10 0.20 25.0 52.3 Dry {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 25.3 Dry ND
6-Dec-11 5.0 25.0 19.7 J 13.0 J ND
13-Jun-12 5.0 25.0 130 61.5 ND
11-Dec-12 5.0 25.0 50.7 Dry ND
29-Apr-13 5.0 25.0 16.9 J 18.4 J ND
6-Aug-13 5.0 25.0 15.4 J ND ND
25-Feb-14 5.0 25.0 29.2 29.4 ND
13-Aug-14 5.0 25.0 18.0 J 18.2 J ND
11-Mar-15 2.5 25.0 7.8 J 8.3 J ND
19-Aug-15 2.5 25.0 2.8 J Dry ND
18-Feb-16 2.5 25.0 6.4 J 6.1 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 11 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Zinc 14-Sep-94 NR 50 ND ND NS
2-Dec-94 NR 50 61.0 ND NS
8-Feb-95 NR 50 ND ND NS
2-Mar-95 NR 50 64.0 ND NS
17-Nov-95 NR 50 ND ND NS
23-May-96 NR 50 ND ND NS
14-Nov-96 NR 50 ND ND NS
18-Jun-97 NR 50 26.0 ND NS
2-Dec-97 NR 50 32.0 40.0 NS
27-May-98 NR 50 57.0 28.0 NS
16-Nov-98 NR 50 28.0 31.0 NS
10-Sep-99 NR 50 ND ND NS
16-Nov-99 NR 50 ND ND NS
10-May-00 NR 50 ND ND NS
26-Oct-00 NR 50 ND ND NS
18-Apr-01 NR 50 ND ND NS
19-Nov-02 NR 50 NS ND NS
27-Jun-03 NR 50 ND ND NS
30-Dec-03 NR 50 ND ND ND
30-Jun-04 NR 50 ND ND ND
29-Dec-04 NR 50 ND ND ND
29-Jun-05 NR 50 ND ND ND
29-Dec-05 NR 50 ND ND ND
28-Jun-06 NR 50 ND ND ND
28-Dec-06 NR 10 7.4 J 8.5 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 10.2 Dry ND
19-Dec-07 NR 10 24.1 B Dry 87.9
8-Jul-08 NR 10.0 17.2 Dry 1.2 J
16-Dec-08 0.40 10.0 8.9 J 11.9 ND
8-Jul-09 0.40 10.0 9.4 J Dry 1.6 J
15-Dec-09 0.40 10.0 8.3 B 8.5 B 7.7 J
23-Jun-10 0.40 10.0 29.3 4.0 J ND
14-Dec-10 0.40 10.0 25.1 B Dry 6.7 J
21-Jun-11 10.0 10.0 10.9 Dry ND
6-Dec-11 10.0 10.0 15.0 B 10.3 B 12.4
13-Jun-12 10.0 10.0 46.3 19.8 ND
11-Dec-12 10.0 10.0 25.4 Dry ND
29-Apr-13 10.0 10.0 13.8 12.5 ND
6-Aug-13 10.0 10.0 11.3 ND ND
25-Feb-14 10.0 10.0 15.0 14.8 ND
13-Aug-14 10.0 10.0 14.3 ND ND
11-Mar-15 5.0 10.0 62.3 11.6 B 6.1 J
19-Aug-15 5.0 10.0 ND Dry 11.5
18-Feb-16 5.0 10.0 13.0 11.0 ND
Organic Compounds
Acetone 15-Dec-09 2.2 100 3.9 B 3.2 B 2.8 J
NC 2B = NE (05/01/07)23-Jun-10 2.2 100 5.4 B 2.2 B 7.7 J
14-Dec-10 2.2 100 ND Dry ND
21-Jun-11 2.2 100 3.4 B Dry 3.9 J
6-Dec-11 2.2 100 ND ND 8.8 J
13-Jun-12 2.2 100 2.2 B ND 4.7 J
12-Dec-12 10.0 100 ND Dry ND
29-Apr-13 10.0 100 ND ND 14.6 J
6-Aug-13 10.0 100 ND ND ND
25-Feb-14 10.0 100 ND ND ND
13-Aug-14 10.0 100 ND ND 19.3 J
11-Mar-15 10.0 100 ND ND ND
19-Aug-15 10.0 100 ND Dry ND
18-Feb-16 10.0 100 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 12 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
2-Hexanone 23-Jun-10 0.46 50.0 1.5 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 0.46 50.0 ND Dry ND
21-Jun-11 0.46 50.0 ND Dry ND
6-Dec-11 0.46 50.0 ND ND ND
13-Jun-12 0.46 50.0 ND ND ND
12-Dec-12 0.46 50.0 0.47 J Dry ND
29-Apr-13 0.46 50.0 ND ND ND
6-Aug-13 0.46 50.0 ND ND ND
25-Feb-14 0.46 50.0 ND ND ND
13-Aug-14 0.46 50.0 ND ND ND
11-Mar-15 0.46 50.0 ND ND ND
19-Aug-15 0.46 50.0 ND Dry ND
18-Feb-16 0.46 50.0 ND ND ND
Methylene Chloride 29-Apr-13 0.97 1.0 0.98 J ND ND
NC 2B = NE (05/01/07)6-Aug-13 0.97 1.0 ND ND ND
25-Feb-14 0.97 1.0 ND ND ND
13-Aug-14 0.97 1.0 ND ND ND
11-Mar-15 0.97 1.0 ND ND ND
19-Aug-15 0.97 1.0 ND Dry ND
18-Feb-16 0.97 1.0 ND ND ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry (12/14/10 SW-2 sample attempted, but stream was frozen solid).
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.
NE = Not established.
Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
Please see the report for information regarding NC 2B exceedences of surface water samples.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 13 of 13
Joyce Engineering

Appendix G

Historical MNA Parameter Data

APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Temperature 30-Dec-03 oC 15.40 NI NA NS 12.51 13.58 NA NS NS NS NS
18-May-04 oC 14.05 NI NA NS 18.17 14.53 NA 15.04 17.15 12.86 16.41
30-Jun-04 oC 13.88 NI NA NS 14.33 14.18 NA 14.37 17.98 15.67 15.66
29-Dec-04 oC 14.30 NI NA NS 14.80 14.40 NA NS NS NS NS
28-Dec-06 ºC 11.60 NI 15.10 NS 14.60 13.40 14.50 14.30 NS 11.20 NS
11-Jul-07 ºC 15.90 NI 15.70 NS 17.30 15.90 19.00 NS NS NS NS
19-Dec-08 ºC 14.50 NM 13.50 12.30 12.80 15.70 12.40 13.90 14.30 12.50 13.20
8-Jul-09 ºC 14.80 NM 15.20 16.00 16.10 17.00 16.90 15.40 14.80 16.00 17.50
14-Dec-09 ºC 9.20 NM 12.50 12.80 12.70 12.50 11.30 13.70 14.60 13.20 13.40
23-Jun-10 ºC 18.50 NM 16.69 18.93 18.43 15.76 19.05 18.10 20.28 19.65 20.22
14-Dec-10 ºC Dry NM 11.80 11.31 10.63 12.20 13.20 12.12 NS 10.80 NS
21-Jun-11 ºC WL 15.26 15.90 15.85 17.20 15.66 18.20 15.56 18.40 18.33 16.53
6-Dec-11 ºC WL 16.75 16.70 15.99 16.18 14.97 15.70 15.10 15.01 15.37 14.77
13-Jun-12 ºC WL 18.18 15.60 16.60 15.88 14.90 17.50 15.50 15.60 19.20 17.07
11-Dec-12 ºC WL 16.70 15.00 16.60 16.10 14.90 15.10 15.80 15.20 16.30 15.10
29-Apr-13 ºC WL 16.40 15.90 17.20 16.70 14.90 17.00 15.20 15.20 14.60 16.20
6-Aug-13 ºC WL 18.2 15.9 18.1 18.3 16.1 16.7 15.4 NS 19.4 NS
25-Feb-14 ºC WL 14.9 14.1 15.7 13.4 14.6 13.0 12.6 12.5 12.5 12.5
13-Aug-14 ºC WL 22.4 19.7 19.8 17.3 16.1 15.9 NS NS 21.0 NS
12-Mar-15 ºC WL 13.9 11.6 17.0 11.6 12.5 15.2 NS NS 15.9 20.7
19-Aug-15 ºC WL 17.26 17.80 18.69 16.36 15.75 19.2 NS NS 19.04 NS
18-Feb-16 ºC WL 12.80 13.90 14.20 13.40 12.50 8.5 NS NS 11.3 14.1
pH 30-Dec-03 SU 7.31 NI NA NS 6.90 7.24 NA NS NS NS NS
[Field Test]18-May-04 SU 6.31 NI NA NS 7.27 6.39 NA 7.29 7.46 7.43 7.73
30-Jun-04 SU 8.03 NI NA NS 7.74 7.11 NA 6.70 6.79 6.93 7.64
29-Dec-04 SU 6.31 NI NA NS 7.47 6.67 NA NS NS NS NS
28-Dec-06 SU 7.50 NI 6.51 NS 7.38 6.46 8.02 6.06 NS 6.52 NS
11-Jul-07 SU 6.73 NI 6.58 NS 7.65 6.72 7.42 NS NS NS NS
19-Dec-08 SU 6.26 NM 5.92 7.81 7.10 6.63 7.03 7.61 5.81 8.12 7.35
8-Jul-09 SU 6.75 NM 7.90 6.13 8.43 7.86 7.46 8.12 8.43 5.93 8.64
14-Dec-09 SU 6.82 NM 6.76 6.20 7.65 6.70 7.23 6.38 7.50 7.43 6.86
23-Jun-10 SU 5.28 NM 5.45 5.90 6.98 6.11 6.69 5.52 7.35 5.71 6.92
14-Dec-10 SU Dry NM 7.09 5.92 7.61 6.12 7.20 5.67 NS 6.36 NS
21-Jun-11 SU WL 6.20 5.98 6.13 7.07 6.58 7.15 6.07 7.14 6.04 7.12
6-Dec-11 SU WL 6.79 6.10 6.61 7.54 6.73 6.92 6.28 7.05 6.46 7.17
13-Jun-12 SU WL 7.49 6.15 6.43 6.95 6.43 6.88 6.46 7.02 7.15 7.31
11-Dec-12 SU WL 6.48 6.15 7.47 7.38 6.25 6.92 5.79 6.99 5.99 7.60
29-Apr-13 SU WL 6.11 5.68 5.96 7.15 6.23 6.91 5.85 6.54 6.69 7.01
6-Aug-13 SU WL 6.29 7.56 5.96 7.00 6.48 6.96 7.23 NS 5.82 NS
25-Feb-14 SU WL 6.73 5.77 5.98 6.61 6.81 6.41 5.89 6.60 6.70 7.61
13-Aug-14 SU WL 6.16 6.86 6.16 7.11 6.69 6.79 NS NS 5.89 NS
12-Mar-15 SU WL 6.53 6.77 6.61 6.26 6.33 6.77 NS NS 6.50 7.49
19-Aug-15 SU WL 6.27 6.67 5.88 7.21 6.46 6.79 NS NS 5.88 NS
18-Feb-16 SU WL 6.89 6.56 6.55 6.36 6.23 5.69 NS NS 6.13 6.52
Oxidation-Reduction Potential 30-Dec-03 mV 257.2 NI NS NS 212.7 187.3 NS NS NS NS NS
(ORP) (Redox Potential)18-May-04 mV 352.8 NI NS NS 158.6 173.2 NS 150.5 105.7 129.1 55.1
[Field Test]30-Jun-04 mV 275.0 NI NS NS 154.1 174.7 NS 182.8 223.0 179.4 199.7
28-Dec-06 mV 70.2 NI NS NS 72.6 75.8 NS 84.7 NS 69.3 NS
11-Jul-07 mV 281.0 NI NS NS 269.0 296.0 NS NS NS NS NS
19-Dec-08 mV 186.0 NM NS 210.0 181.0 149.0 NS 218.0 240.0 44.0 207.0
8-Jul-09 mV 104.0 NM NS 219.0 115.0 124.0 NS 144.0 146.0 160.0 159.0
14-Dec-09 mV 195.0 NM NS 138.0 175.0 92.0 NS 96.0 126.0 147.0 119.0
23-Jun-10 mV 139.6 NM NS 32.0 -15.0 52.8 NS 33.8 22.8 61.7 1.3
14-Dec-10 mV Dry NM NS 50.0 48.0 40.2 NS 42.5 NS 46.2 NS
21-Jun-11 mV WL 89.90 NS 52.8 38.1 50.8 NS 19.9 9.6 44.8 46.4
6-Dec-11 mV WL 119.6 NS 68.8 38.9 38.4 NS 28.1 25.0 75.1 87.0
13-Jun-12 mV WL -32.2 NS -14.3 136.0 67.5 NS -4.1 105.6 -18.1 21.8
11-Dec-12 mV WL 114.9 NS 158.8 105.5 98.9 NS 123.7 164.8 157.8 121.9
29-Apr-13 mV WL 78.4 NS 146.9 65.5 117.7 NS 61.3 90.0 142.3 74.3
6-Aug-13 mV WL 89.0 NS 110.6 62.3 83.7 NS 112.7 NS 101.0 NS
25-Feb-14 mV WL 102.3 NS 140.0 -44.2 137.8 NS 60.6 88.0 74.3 102.1
13-Aug-14 mV WL 76.0 NS NS NS 49.2 NS NS NS 90.4 NS
12-Mar-15 mV WL 71.8 NS NS NS 68.1 NS NS NS 72.2 49.6
19-Aug-15 mV WL 61.9 NS NS NS 22.5 NS NS NS 57.9 NS
18-Feb-16 mV WL 104.2 NS NS NS 123.5 NS NS NS 105.7 52.9
Conductivity 28-Dec-06 µS/cm 65.3 NI 104.8 NS 588.0 355.0 642.0 173.4 NS 172.2 NS
[Field Test]11-Jul-07 µS/cm 62.5 NI 122.4 NS 631.0 373.0 604.0 NS NS NS NS
19-Dec-08 µS/cm 61.0 NM 100.4 291.0 562.0 384.0 530.0 155.0 1137.0 165.0 376.0
8-Jul-09 µS/cm 17.7 NM 111.8 377.0 625.0 421.0 578.0 321.0 792.0 159.0 369.0
14-Dec-09 µS/cm 60.2 NM 83.6 304.0 564.0 373.0 540.0 374.0 527.0 109.7 382.0
23-Jun-10 µS/cm 38.0 NM 68.0 269.0 540.0 347.0 528.0 282.0 466.0 111.0 427.0
14-Dec-10 µS/cm Dry NM 114.3 229.0 355.0 294.0 589.0 236.0 NS 104.0 NS
21-Jun-11 µS/cm WL 230.0 123.5 279.0 568.0 368.0 633.0 297.0 640.0 103.0 401.0
6-Dec-11 µS/cm WL 237.0 104.3 251.0 548.0 360.0 607.0 348.0 518.0 129.0 331.0
13-Jun-12 µS/cm WL 259.0 82.7 246.0 553.0 416.0 586.0 405.0 641.0 122.0 392.0
11-Dec-12 µS/cm WL 222.2 101.6 246.5 548.0 432.0 624.0 204.6 575.0 165.6 354.5
29-Apr-13 µS/cm WL 215.7 75.7 242.3 562.0 328.9 537.0 389.1 609.0 98.8 356.7
6-Aug-13 µS/cm WL 286.8 81.9 292.7 636.0 414.8 590 272.4 NS 151.2 NS
25-Feb-14 µS/cm WL 231.3 61.5 289.2 470.2 399.2 502 341.1 450.8 95.3 288.3
13-Aug-14 µS/cm WL 307.3 95.4 283.0 634.0 452.4 591 NS NS 135.2 NS
12-Mar-15 µS/cm WL 123.4 36.9 222.8 482.9 323.5 553 NS NS 114.2 447.9
19-Aug-15 µS/cm WL 28.4 13.4 215.0 565.0 386.0 556 NS NS 112.0 NS
18-Feb-16 µS/cm WL 250.0 88.7 220.8 547.0 311.6 380 NS NS 95.7 293.9
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ferrous Iron (Fe2+)30-Dec-03 0.1 mg/L ND NI NS NS ND ND NS NS NS NS NS
[Field Test]18-May-04 0.1 mg/L ND NI NS NS ND 0.5 NS ND ND ND ND
30-Jun-04 0.1 mg/L ND NI NS NS ND ND NS ND ND ND NS
28-Dec-06 0.1 mg/L 0.0 NI NS NS 0.0 0.0 NS 0.0 NS 0.0 NS
11-Jul-07 0.1 mg/L 0.2 NI NS NS 0.1 0.0 NS NS NS NS NS
19-Dec-08 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 0.0 0.0 0.0 0.0
8-Jul-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 1.8 0.0 0.0 0.0
14-Dec-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 2.0 0.0 0.0 0.0
23-Jun-10 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 4.1 0.0 0.0 0.0
14-Dec-10 0.1 mg/L Dry NM NS 0.0 0.0 0.0 NS 1.1 NS 0.0 NS
21-Jun-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 0.1 mg/L WL 0.0 NS NS NS NS NS NS NS NS NS
11-Dec-12 NR NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 3.5 0.0 0.0 0.0
6-Aug-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 1.0 NS 0.75 NS
25-Feb-14 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 2.0 0.0 1.0 0.0
13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 0.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.5 0.0
19-Aug-15 1.1 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 1.1 mg/L WL 0.00 NS NS NS 0.0 NS NS NS 1.0 0.0
Dissolved Carbon Dioxide 11-Jul-07 mg/L 60 NI NS NS 50 100 NS NS NS NS NS
[Field Test]19-Dec-08 mg/L 30 NM NS 60 25 102 NS 40 35 35 30
8-Jul-09 mg/L 28 NM NS 120 50 170 NS 175 40 116 40
14-Dec-09 mg/L 40 NM NS 130 50 50 NS 235 30 70 60
23-Jun-10 mg/L 40 NM NS 160 65 140 NS 300 60 90 30
14-Dec-10 mg/L Dry NM NS 135 60 136 NS 435 NS 50 NS
21-Jun-11 NS WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL 60 NS NS NS NS NS NS NS NS NS
11-Dec-12 NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/L WL 65 NS 55 35 70 NS 85 65 15 55
6-Aug-13 mg/L WL 50 NS 120 55 115 NS 155 NS 45 NS
25-Feb-14 mg/L WL 55 NS 95 60 85 NS 95 50 30 55
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 mg/L WL 45 NS NS NS 50 NS NS NS 35 20
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 mg/L WL 55 NS NS NS 45 NS NS NS 105 85
Dissolved Oxygen (DO)30-Dec-03 0.01 mg/L 9.49 NI NS NS 24.19 15.31 NS NS NS NS NS
[Field Test]18-May-04 0.01 mg/L 7.15 NI NS NS 11.77 1.15 NS 3.48 19.25 2.24 10.70
30-Jun-04 0.01 mg/L -NI NS NS --NS 12.71 9.20 3.59 4.37
28-Dec-06 0.01 mg/L 10.30 NI NS NS 3.18 7.99 NS 1.62 NS 5.11 NS
11-Jul-07 0.01 mg/L 8.20 NI NS NS 3.70 3.60 NS NS NS NS NS
19-Dec-08 0.01 mg/L 2.86 NM NS 4.38 3.56 1.55 NS 1.22 NS NS 8.10
8-Jul-09 0.01 mg/L 2.78 NM NS 1.98 0.88 0.48 NS 0.54 4.51 0.91 7.76
14-Dec-09 0.01 mg/L 1.34 NM NS 4.50 3.46 2.96 NS 0.57 NS 1.89 NS
23-Jun-10 0.01 mg/L 4.09 NM NS 3.35 3.49 2.89 NS 4.76 7.98 1.56 6.06
14-Dec-10 0.01 mg/L Dry NM NS 8.18 4.55 2.97 NS 1.60 NS 5.85 NS
21-Jun-11 0.01 mg/L WL 7.57 NS 3.94 2.68 3.49 NS 1.55 9.12 2.63 6.20
6-Dec-11 0.01 mg/L WL 3.82 NS 6.24 3.13 2.01 NS 1.50 8.50 1.79 8.08
13-Jun-12 0.01 mg/L WL 13.78 NS 16.46 12.22 11.31 NS 12.57 12.69 13.09 16.32
11-Dec-12 0.01 mg/L WL 3.51 NS 3.38 3.17 6.21 NS 0.86 8.72 1.53 7.93
29-Apr-13 0.01 mg/L WL 3.51 NS 1.27 2.75 1.87 NS 0.98 9.04 2.01 6.68
6-Aug-13 0.01 mg/L WL 2.56 NS 1.26 2.08 1.33 NS 2.43 NS 1.38 NS
25-Feb-14 0.01 mg/L WL 3.90 NS 2.11 1.42 1.42 NS 1.69 8.33 1.88 7.12
13-Aug-14 0.01 mg/L WL 3.96 NS NS NS 4.14 NS NS NS 2.22 NS
12-Mar-15 0.01 mg/L WL 3.62 NS NS NS 1.24 NS NS NS 0.74 6.17
19-Aug-15 0.01 mg/L WL 5.29 NS NS NS 2.46 NS NS NS 2.74 NS
18-Feb-16 0.01 mg/L WL 3.51 NS NS NS 2.59 NS NS NS 2.54 7.07
Dissolved Hydrogen 19-Dec-08 0.600 nM 0.920 NM NS 1.300 2.500 1.300 NS 1.100 NS 1.1 NS
8-Jul-09 1.600 nM NS(dry)NM NS 1.100 2.100 1.400 NS 1.900 4.200 4.900 NS(dry)
14-Dec-09 0.600 nM 1.000 NM NS 1.100 3.000 1.000 NS 0.880 2.500 0.750 NS(dry)
23-Jun-10 0.600 nM 4.400 NM NS 4.500 5.600 3.700 NS 4.000 9.100 4.000 NS(dry)
14-Dec-10 0.600 nM Dry NM NS 0.800 1.500 1.000 NS 1.000 NS 0.620 NS(dry)
21-Jun-11 0.600 nM WL 1.30 NS 1.400 2.900 1.400 NS 1.100 3.800 1.100 NS(dry)
6-Dec-11 0.60 nM WL 2.4 NS 3.6 5.4 5.6 NS 5.3 5.2 3.4 NS(dry)
13-Jun-12 0.60 nM WL 0.81 NS 2.7 4.7 3.8 NS 2.8 3.5 0.83 NS(dry)
11-Dec-12 0.60 nM WL 0.53 J NS 0.46 J 3.0 0.6 NS 0.056 J 0.53 J 0.22 J NS
29-Apr-13 0.60 nM WL 0.38 J NS 0.41 J 1.9 NS NS 0.37 J 1.3 0.39 J 0.42 J
6-Aug-13 0.60 nM WL 0.84 NS 0.98 0.83 0.79 NS 1.0 NS 0.84 NS
25-Feb-14 0.60 nM WL 0.65 NS 0.92 0.77 0.86 NS 1.1 0.81 0.70 0.81
13-Aug-14 0.60 nM WL 1.3 NS NS NS 1.2 NS NS NS 1.1 NS
12-Mar-15 0.60 nM WL 1.5 NS NS NS -NS NS NS 1.2 1.5
30-Apr-15 0.60 nM WL NS NS NS NS 1.5 NS NS NS NS NS
19-Aug-15 0.60 nM WL 1.6 NS NS NS 2.0 NS NS NS 1.7 NS
18-Feb-16 0.60 nM WL 2.9 NS NS NS 10.0 NS NS NS 2.2 NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Chloride 30-Dec-03 1 mg/L 3 NI NS NS 17 24 NS NS NS NS NS
18-May-04 1 mg/L 3.2 NI NS NS 26 26 NS 6.3 16 6.2 9.1
30-Jun-04 1 mg/L 2.5 NI NS NS 28 26 NS 8.1 15 7.8 4.3
28-Dec-06 5 mg/L 1.8 NI NS NS 22 18 NS 4.7 NS 6.6 NS
11-Jul-07 5 mg/L 0.66 (2.6)NI NS NS 17 (34)15 (29)NS NS NS NS NS
19-Dec-08 5 mg/L 5.7 NM NS 37.0 39.4 36.4 NS 16.0 10.8 12.6 6.2
8-Jul-09 5 mg/L 6.8 NM NS 46.8 39.1 38.6 NS 23.1 11.3 7.7 28.4
14-Dec-09 5.0 mg/L ND NM NS 36.4 38.8 37.6 NS 33.0 11.5 5.5 6.2
23-Jun-10 5.0 mg/L 7.95 NM ND 37.4 40.0 39.7 97.9 17.6 13.4 5.97 6.5
14-Dec-10 5.0 mg/L Dry NM 5.1 38.4 44.5 39.6 108.0 29.1 NS 16.40 NS
NC-2L 250,000 ug/L 21-Jun-11 5.0 mg/L WL 8.6 ND 35.8 45.3 41.4 106.0 23.3 13.5 6.60 6.07
6-Dec-11 5.0 nM WL 9.34 ND 28.6 49.2 39.2 110.0 47.8 22.5 13.9 6.2
13-Jun-12 5.0 mg/L WL 9.41 4.54 29.4 49.3 46.4 109.0 44.4 26.7 7.77 6.36
11-Dec-12 1.0 mg/L WL 8.57 5.22 30.8 50.6 46.6 107.0 40.1 25.7 15.6 6.26
29-Apr-13 1.0 mg/L WL 9.55 4.12 30.0 49.8 22.3 122.0 44.9 31.1 5.84 6.08
6-Aug-13 1.0 mg/L WL 7.59 5.18 25.7 50.1 48.7 107.0 24.8 NS 7.05 NS
25-Feb-14 1.0 mg/L WL 9.22 5.51 33.2 60.3 57.4 120.0 26.9 29.2 5.39 6.53
13-Aug-14 1.0 mg/L WL 8.03 4.07 21.3 97.6 43.4 106.0 NS NS 5.61 NS
12-Mar-15 1.0 mg/L WL 8.84 43.5 20.7 51.7 42.6 121.0 NS NS 5.81 5.58
19-Aug-15 1.0 mg/L WL 9.44 5.16 23.2 51.5 48.5 111.0 NS NS 6.35 NS
18-Feb-16 1.0 mg/L WL 17.20 4.60 20.6 69.5 49.7 153.0 NS NS 6.28 5.65
Nitrate 30-Dec-03 0.10 mg/L 0.23 NI NS NS ND ND NS NS NS NS NS
18-May-04 0.10 mg/L 0.21 NI NS NS ND ND NS ND 1.10 0.14 ND
30-Jun-04 0.10 mg/L 0.15 NI NS NS ND ND NS ND 0.95 0.20 ND
28-Dec-06 100.0 mg/L 0.15 NI NS NS 0.51 0.33 NS 0.36 NS 0.43 NS
11-Jul-07 100.0 mg/L 0.14 NI NS NS 0.111 0.031 NS NS NS NS NS
19-Dec-08 100.0 mg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 200.0 mg/L ND NM NS ND ND ND NS ND ND ND 0.30
14-Dec-09 0.10 mg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 0.10 mg/L ND NM NS ND ND ND NS ND ND 183 107
14-Dec-10 0.10 mg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 0.10 mg/L WL ND NS ND ND ND NS ND ND 0.146 ND
6-Dec-11 0.10 mg/L WL ND NS ND ND ND NS ND ND ND ND
13-Jun-12 0.10 mg/L WL 0.181 NS 0.0743 ND ND NS ND 0.0798 0.162 0.251
11-Dec-12 10.00 mg/L WL 0.115 J NS 0.0655 J ND 0.0326 J NS 0.0557 J 0.022 ND 0.192 J
29-Apr-13 0.02 mg/L WL 0.0938 NS 0.0280 ND ND NS ND 0.0298 0.0851 0.141
6-Aug-13 10.00 mg/L WL 0.0999 J NS ND ND ND NS ND NS ND NS
25-Feb-14 10.00 mg/L WL NS NS ND ND ND ND ND ND ND 0.417 J
13-Aug-14 10.00 mg/L WL 0.144 J NS NS NS ND NS NS NS ND NS
12-Mar-15 10.00 mg/L WL 0.134 J NS NS NS 0.0224 J NS NS NS ND 0.229 J
19-Aug-15 10.00 mg/L WL 0.186 J NS NS NS ND NS NS NS ND NS
18-Feb-16 10.00 mg/L WL 0.179 J NS NS NS 0.0373 J NS NS NS ND 0.122 J
Nitrite 28-Dec-06 mg/L <0.100 NI NS NS <0.100 <0.100 NS <0.100 NS <0.100 NS
11-Jul-07 mg/L <0.1 NI NS NS <0.1 <0.1 NS NS NS NS NS
14-Dec-10 mg/L Dry NM NS NS NS NS NS NS NS NS NS
21-Jun-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Sulfate 30-Dec-03 2.0 mg/L 4.0 NI NS NS 17 2.7 NS NS NS NS NS
18-May-04 2.0 mg/L 3.3 NI NS NS 40 2.8 NS 21 120 5.6 13
30-Jun-04 2.0 mg/L ND NI NS NS 29 ND NS 5.5 180 4.7 12
28-Dec-06 5 mg/L 0.03 NI NS NS 10 4.6 NS 5.2 NS 12 NS
11-Jul-07 5 mg/L 1.6 NI NS NS 13 2.2 NS NS NS NS NS
19-Dec-08 5 mg/L 11.2 NM NS 9.6 9 ND NS 5.3 191 16.1 18.3
8-Jul-09 5 mg/L 1140 NM NS 8.4 9.3 ND NS 5.2 161 8.4 39.2
14-Dec-09 5 mg/L ND NM NS 6.9 7.3 ND NS ND 79.5 6.5 49.7
23-Jun-10 5 mg/L 5.16 NM 14.8 7.18 9.14 ND ND ND ND 25.1 ND
14-Dec-10 5 mg/L Dry NM 14.5 9.21 9.7 ND ND 5.38 NS 10.80 NS
21-Jun-11 5 mg/L WL 24.4 11.4 7.49 7.74 ND ND ND 91.9 ND ND
NC-2L 250,000 ug/L 6-Dec-11 5 mg/L WL ND NS ND ND ND NS ND 31.4 11.80 52.9
13-Jun-12 5 mg/L WL 25.4 13.7 8.14 8.4 2.79 3.04 4.70 24.5 5.38 83.1
11-Dec-12 2 mg/L WL 28.0 J 14.8 J 9.12 J 10.1 J 4.42 J 2.90 J 3.16 J 36.0 7.91 J 78.8
29-Apr-13 250 mg/L WL 26.1 J 12.3 J 9.15 J 17.1 J 2.73 J 3.20 J 5.23 J 57.0 J 4.61 J 73.8 J
6-Aug-13 250 mg/L WL 25.3 J 7.37 J 7.83 J 11.7 J 2.76 J 3.32 J 4.29 J NS 5.07 J NS
25-Feb-14 250 mg/L WL 28.9 J 11.2 J 8.13 J 9.55 J 2.59 J 4.62 J 3.59 J 10.4 J 33.8 J 4.56 J
13-Aug-14 250 mg/L WL 31.9 J 9.37 J 7.91 J 11.6 J 2.45 J 2.78 J NS NS 4.46 J NS
12-Mar-15 250 mg/L WL 32.6 J 12.1 J 8.04 J 8.34 J 3.34 J 3.33 J NS NS 4.81 J 83.4 J
19-Aug-15 250 mg/L WL 42.9 J 102 J 8.11 J 10.4 J 2.89 J 3.21 J NS NS 4.93 J NS
18-Feb-16 250 mg/L WL 39.9 J 112 J 7.96 J 10.3 J 3.83 J 3.31 NS NS 4.84 J 54.7 J
Sulfide 30-Dec-03 1.0 mg/L ND NI NS NS 5.0 ND NS NS NS NS NS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
19-Dec-08 1000 µg/L 259 J NM ND 150 J ND 141 J ND ND ND ND ND
8-Jul-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
23-Jun-10 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-10 1000 µg/L Dry NM ND ND ND ND ND ND NS ND NS
21-Jun-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
NC SWSL 1000 ug/L 6-Dec-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
13-Jun-12 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 1000 µg/L WL ND ND ND ND 117 J NS NS NS NS NS
29-Apr-13 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Aug-13 1000 µg/L WL ND ND ND ND ND ND ND NS ND NS
25-Feb-14 1000 µg/L WL ND ND ND ND ND ND ND ND ND ND
13-Aug-14 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
19-Aug-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
18-Feb-16 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Hydrogen Sulfide 30-Dec-03 1.0 mg/L ND NI NS NS 21 ND NS NS NS NS NS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
14-Dec-10 NR mg/L Dry NM NS NS NS NS NS NS NS NS NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1.0 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Organic Carbon (TOC)11-Jul-07 1 mg/L 0.48 NI NS NS 3.2 1.9 NS NS NS NS NS
19-Dec-08 1 mg/L 6.3 NM NS 48 24.7 21.1 NS 21.2 22.8 11.4 19.1
8-Jul-09 1 mg/L 28.1 NM NS 6.6 5.9 6.2 NS 3.4 5.7 4.2 4.4
14-Dec-09 1 mg/L 3.0 NM NS 32.4 48.2 ND NS 11.5 5.0 2.9 3.8
23-Jun-10 1 mg/L 3.7 NM NS 3.16 5.8 6.07 NS 2.91 5.96 2.82 3.61
14-Dec-10 1 mg/L Dry NM NS 23.7 7.52 7.77 NS 23 NS 5.01 NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1 mg/L WL 3.71 NS NS NS NS NS NS NS NS NS
11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 1 mg/L WL 4.68 NS 7.42 8.93 9.63 NS 12.4 NS 4.08 NS
25-Feb-14 1 mg/L WL NS NS 8.62 20.4 19.9 NS 33.7 26.2 9.50 8.03
13-Aug-14 1 mg/L WL 4.55 NS NS NS 8.34 NS NS NS 4.33 NS
12-Mar-15 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
Alkalinity 30-Dec-03 10 mg/L 14 NI NS NS 90 130 NS NS NS NS NS
(total as CaCO3)18-May-04 10 mg/L ND NI NS NS 210 140 NS 56 260 63 81
30-Jun-04 10 mg/L 11 NI NS NS 240 160 NS 120 280 46 130
28-Dec-06 5 mg/L 10 NI NS NS 255 133 NS 57 NS 42 NS
11-Jul-07 5 mg/L 20 NI NS NS 220 150 NS NS NS NS NS
19-Dec-08 5 mg/L 18.9 NM NS 88.2 296 163 NS 76.7 202 44.2 222
8-Jul-09 6 mg/L 16.5 NM NS 110 301 176 NS 137 278 44.0 155
14-Dec-09 5 mg/L 6.7 NM NS 82.1 253 135 NS 134 210 29.6 137
23-Jun-10 5 mg/L 7.29 NM 20.4 99.8 291 169 178.0 134 262 39.7 170
14-Dec-10 5 mg/L Dry NM 17.6 99.6 292 168 156 168 NS 39.4 NS
21-Jun-11 5 mg/L WL 100 20.8 77 269 194 156 128 288.0 42.2 153.0
6-Dec-11 5 mg/L WL 98.7 10.5 81.9 274 164 151 146 297 35.7 144
13-Jun-12 5 mg/L WL 101 13.7 87.5 271 152 149 152 309 46.2 147
11-Dec-12 5 mg/L WL 100 16.5 98.3 284 147 152 130 339 44.6 148
29-Apr-13 5 mg/L WL 99.3 13.8 97.3 293 156 153 180 339 46.2 143
6-Aug-13 5 mg/L WL 102 14.3 99.1 148 86.8 159 123 NS 43.3 NS
25-Feb-14 5 mg/L WL 98 15.8 123 298 178 153 145 303 164 3.87
13-Aug-14 5 mg/L WL 103 14.3 93.8 301 187 164 NS NS 49.8 NS
12-Mar-15 5 mg/L WL 99.7 14.7 88.3 306 151 164 NS NS 39.5 139
19-Aug-15 5 mg/L WL 102 19.6 88.2 294 180 164 NS NS 46.9 NS
19-Aug-15 5 mg/L WL 108 4.35 J 89.8 308 141 168 NS NS 49.6 150
Ethane 30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-08 20.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10.0 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 6.2 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ethylene (Ethene)30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-08 20.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 11.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10.0 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 6.2 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
Methane 30-Dec-03 0.001 mg/L ND NI NS NS 1.8 0.1 NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS 1.50 0.12 NS 0.09 0.46 0.004 ND
30-Jun-04 0.001 mg/L ND NI NS NS 0.66 0.06 NS 0.26 ND ND ND
28-Dec-06 10.0 mg/L 0.01 NI NS NS 0.173 0.044 NS 0.021 NS 0.001 NS
11-Jul-07 10.0 mg/L 0.001 NI NS NS 0.189 0.008 NS NS NS NS NS
19-Dec-08 10.0 mg/L ND NM NS 0.0054 J 0.162 0.102 NS 0.0164 ND ND ND
8-Jul-09 10.0 mg/L ND NM NS 0.0202 0.088 0.128 NS 0.226 ND ND ND
14-Dec-09 10.0 mg/L ND NM NS 0.0083 J 0.0205 0.0648 NS 1.130 ND ND ND
23-Jun-10 0.010 mg/L 0.0018 B NM NS 0.0117 B 0.064 0.101 NS 0.415 0.002 B 0.0012 B 0.0013 B
14-Dec-10 0.010 mg/L Dry NM NS 0.0025 J 0.155 0.102 NS 0.510 NS ND NS
21-Jun-11 0.010 mg/L WL 0.0016 J NS 0.099 J 0.103 0.108 NS 0.770 0.0017 J 0.0014 J 0.0017 J
6-Dec-11 0.010 mg/L WL ND NS 0.009 J 0.032 0.086 NS 0.376 ND ND ND
13-Jun-12 0.010 mg/L WL 0.0011 J NS 0.0062 J 0.0524 0.0698 NS 0.157 0.0017 J 0.0015 J 0.0013 J
11-Dec-12 0.01 mg/L WL ND NS 0.0036 0.0825 0.0506 NS 0.183 ND ND ND
29-Apr-13 0.01 mg/L WL ND NS 0.0180 0.0737 0.0923 NS 1.290 ND ND ND
6-Aug-13 0.0066 mg/L WL ND NS 0.0229 0.0590 0.113 NS 0.284 NS 0.060 NS
25-Feb-14 0.0066 mg/L WL ND NS 0.0170 0.0703 0.0263 NS 0.498 ND ND ND
13-Aug-14 0.0066 mg/L WL ND NS NS NS 0.108 NS NS NS 0.339 NS
12-Mar-15 0.0066 mg/L WL ND NS NS NS 0.0188 NS NS NS 0.330 0.0119
19-Aug-15 0.0066 mg/L WL 0.89 J NS NS NS 0.0398 NS NS NS 0.340 NS
19-Aug-15 0.0066 mg/L WL 0.0018 J NS NS NS 0.0218 NS NS NS 0.512 0.0019 J
Pyruvic Acid 28-Dec-06 100 µg/L ND NI NS ND ND ND NS ND ND ND NS
19-Dec-08 100 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 10000 µg/L ND NM NS ND ND ND NS ND ND ND 2800 J
14-Dec-10 10000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 10000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 10000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 10000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Lactic Acid 28-Dec-06 1000 µg/L ND NI NS ND ND NS NS ND ND ND NS
19-Dec-08 1000 µg/L ND NM NS ND ND 4300 NS ND ND ND ND
8-Jul-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 25000 µg/L ND NM NS ND ND ND NS ND ND 1900 J ND
14-Dec-10 25000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 25000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 25000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 25000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 25000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Acetic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND NS ND NS
19-Dec-08 1000 µg/L ND NM NS 1200 ND ND NS ND 1000 ND 1600
8-Jul-09 1000 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 1000 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Propionic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND NS NS NS ND ND NS
19-Dec-08 1000 µg/L ND NM NS 9900 ND 64200 NS 1300 ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS 800 J ND ND NS ND 3800 ND ND
14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Butyric Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND ND ND NS
19-Dec-08 1000 µg/L ND NM NS 1500 ND ND NS ND ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND 600 J ND NS 1000 J ND ND ND
14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Volatile Fatty Acids 19-Dec-08 µg/L ND NM NS 12600 ND 68500 NS 1300 1000 ND ND
(sum of above 5 parameters)8-Jul-09 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 µg/L ND NM NS 800 J 600 J ND NS 1000 J 3800 1900 J 2800 J
14-Dec-10 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 µg/L WL NS NS NS NS NS NS NS NS NS NS
BTEX 28-Dec-06 µg/L ND NI ND ND ND NS ND ND ND ND NS
(sum of benzene, toluene,19-Dec-08 µg/L ND NM ND ND ND 0.40 J ND ND ND ND ND
ethylbenzene, & xylenes)8-Jul-09 µg/L ND NM ND ND ND 0.54 J ND 0.60 J ND ND ND
14-Dec-09 µg/L ND NM ND ND ND 0.37 J ND NS J NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 0.42 J ND ND ND ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 0.53 J NS ND NS
21-Jun-11 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 0.41 J ND NS NS NS NS
29-Apr-13 µg/L WL ND ND ND ND 0.33 J ND NS NS NS NS
6-Aug-13 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 0.40 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 0.41 J ND NS NS ND NS
12-Mar-15 µg/L WL ND ND ND ND ND ND NS NS ND ND
19-Aug-15 µg/L WL ND ND ND ND 0.35 J ND NS NS ND ND
18-Feb-16 µg/L WL ND ND ND ND ND ND NS NS ND ND
DCE 28-Dec-06 µg/L ND NI ND NS ND 6 ND 0.84 J NS ND NS
(sum of dichloroethylenes )11-Jul-07 µg/L ND NI ND NS ND 6.2 ND NS NS NS NS
19-Dec-08 µg/L ND NM ND ND ND ND ND ND ND ND ND
8-Jul-09 µg/L ND NM ND ND ND 7.7 ND 4.1 J 0.30 J ND ND
14-Dec-09 µg/L ND NM ND ND ND 7.4 ND NS NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 13.6 ND 5.6 0.55 J ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 5.9 NS ND NS
21-Jun-11 µg/L WL ND ND ND ND 6.4 ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 3.0 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND 4.3 J ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 3.3 J ND NS NS NS NS
29-Apr-13 µg/L WL ND ND ND ND 4.8 J ND NS NS NS NS
6-Aug-13 µg/L WL ND ND ND ND 3.6 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 3.7 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 2.8 J 0.39 J NS NS ND NS
12-Mar-15 µg/L WL ND ND ND ND 2.6 J ND NS NS ND ND
19-Aug-15 µg/L WL ND ND ND ND 3.1 J 0.89 J NS NS NS NS
18-Feb-16 µg/L WL ND ND ND ND 2.5 J 0.32 J NS NS NS NS
Notes: ND = Not detected above the laboratory detection limit.mV = millivolts.NA= Data not avaliable
NS = Not sampled for this parameter during this event.mS/cm = milliseimens/centimeter.
mg/L = milligrams per liter = parts per million.SU = standard units.
µg/L = micrograms per liter = parts per billion.ºC = degrees centigrade
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 8 Joyce Engineering