4304_CentralCarolinaTire_Phase3_April2017_1stSemiAnnual_DIN27784_20170512

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]

May 12, 2017

Ms. Elizabeth S. Werner, Hydrogeologist
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646

RE: Report of Results
Semi-Annual Groundwater and Surface Water Monitoring: April 2017
Central Carolina Tire Monofill Landfill Phase III
Cameron, Harnett County, NC
Permit # 43-04

Dear Ms. Werner:

This report presents the results of semi-annual groundwater and surface water quality
monitoring conducted at the landfill site referenced above (Figure 1) in April 2017. The
scope of work performed included sampling and laboratory analysis of groundwater
samples from eight on-site monitoring wells (MW-10 through MW-14 and MW-16
through MW-18) and one surface water sample (SW-1 (EXP)). It is noted that
monitoring well MW-17 was abandoned on August 30, 2011 and replaced with
monitoring well MW-17AR in accordance with the facility Water Quality Monitoring Plan
submitted as part of the Application for Permit Amendment 5-Year Phase (2011-2016)
prepared by Garrett & Moore, Inc. The Water Quality Monitoring Plan was approved by
the NCDEQ, Division of Waste Management (DWM), Solid Waste Section (SWS), in a
letter to Central Carolina Holdings, LLC dated August 10, 2011. The groundwater and
surface water samples were collected in accordance with the NCDEQ, DWM, SWS
Guidelines for Groundwater, Soil, and Surface Water Sampling Document and the
facility Water Quality Monitoring Plan. The sampling and data collection methods, as
well as the current and historical results of field and laboratory testing of the water
samples, are presented in the following sections.

– 2 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
1.0 POTENTIOMETRIC PATTERN AND GROUNDWATER FLOW

Groundwater levels were gauged in the site groundwater monitoring wells on April 18
and 19, 2017as part of the site monitoring. Depths to groundwater were measured
using an electronic water level probe that was thoroughly decontaminated between
wells with a non-phosphate soap and water wash followed in order by multiple rinses
with distilled water, an isopropyl alcohol rinse, and multiple distilled water rinses. Depth
to groundwater measurements were made after the wells were opened for a sufficient
period of time to allow water levels to equilibrate with atmospheric pressure. The
locations of the site monitoring wells are depicted in Figure 2. Groundwater elevation
data collected at the monitoring wells in April 2017 are presented in Table 1. The depth
to groundwater across the site, as measured in the Type II groundwater monitoring
wells in April 2017, ranged from 3.82 feet (MW-12) to 18.16 feet (MW-16) below grade,
which is consistent with the surface topography.

A water-table elevation contour map that was developed based on the April 2017
groundwater-gauging data for the Type II monitoring wells is presented as Figure 3.
The pattern of the water-table contours indicates that the horizontal component of
shallow groundwater flow at the site is generally to the southeast, which is consistent
with the surface topography and drainage features at the site. The hydraulic gradient of
the water table across the site, based on the data depicted in Figure 3, varies from
approximately 0.004 ft/ft in the northern part of the site to 0.011 ft./ft. in the southeastern
part of the site.

2.0 RESULTS OF GROUNDWATER AND SURFACE WATER SAMPLING AND
ANALYSIS

Groundwater samples were collected from the site monitoring wells and a surface water
sample was collected from the on-site location on April 18 and 19, 2017 for laboratory
analysis to monitor the quality of groundwater and surface water at the site. The
groundwater and surface water samples were collected and handled in accordance with
the sampling protocols included in the site Water Quality Monitoring Plan as well as the
SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document. It is
noted that monitoring well MW-10 serves as the upgradient, natural background well for
the facility, and monitoring wells MW-11 through MW-14 and MW-16 through MW-18
serve as the downgradient monitoring wells. All reusable sampling equipment was
– 3 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
properly decontaminated between sampling locations with a non-phosphate soap and
water wash, followed by multiple rinses with distilled water. New disposable nitrile or
latex gloves were worn during all sampling activities. Disposable sampling
equipment/material was discarded after each use.

Prior to groundwater sampling, all monitoring wells were purged using pre-cleaned
Teflon-lined disposable polyethylene tubing connected to a peristaltic pump under low
flow conditions. During purging, measurements were made in the field of the pH,
temperature, specific conductance and turbidity of the groundwater collected from the
monitoring wells, in accordance with SWS requirements. The results of the field
analyses of these parameters are presented in Table 1. Copies of Groundwater
Sampling Forms containing pertinent information recorded in the field during purging
and sampling at each groundwater monitoring well are presented in Appendix A. The
results of the field-measured water-quality parameters indicate that the values
measured in groundwater collected from the site monitoring wells, with the exception of
turbidity at MW-12, were within the applicable stabilization criteria (see Groundwater
Sampling Forms). Groundwater at the site is acidic to moderately acidic based on the
pH values measured in the field (4.14 to 4.83). Specific conductance values ranged
from 16 (MW-12 and MW-13) to 176 (MW-10) µS/cm in groundwater. Turbidity values
ranged from 4.3 (MW-10) to 44 (MW-12) NTUs.

A surface water sample was collected from monitoring location SW-1 (EXP), which is
located approximately 280 feet southeast of the planned limits of scrap tire disposal
along the primary drainage feature that bisects the southeastern portion of the Phase III
landfill footprint. The sampling location is depicted in Figure 2. The surface water
sample was collected in accordance with the protocol presented in the SWS Guidelines
for Groundwater, Soil, and Surface Water Sampling Document.

All groundwater and surface water samples were analyzed at a North Carolina-certified
laboratory for Appendix I volatile organic compounds (VOCs) by SW 846 Method 8260
and the 8 RCRA metals by EPA 6000/7000 series methods. Summarized results of
laboratory analyses for groundwater and surface water samples collected from the site
in April 2017 are presented in Table 2. Summarized historical groundwater and surface
water quality data for the site are presented in Table 3. Copies of the original laboratory
reports are included in Appendix B.

– 4 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
The laboratory analytical results for the surface water sample (SW-1 (EXP)) collected
from the site indicate that no Appendix I VOCs were reported in the sample. Low levels
of barium, chromium, lead and mercury were reported in surface water sample SW-1
(EXP). The reported estimated concentration of mercury (0.038 µg/L) exceeds the 15A
NCAC 2B surface water quality standard for fresh water aquatic life (0.012 µg/L).
However, mercury was also reported in the associated equipment blank at a
concentration that is equivalent to that reported in the surface water sample collected
from SW-1 (EXP). Consequently, the apparent exceedance of the 15A NCAC 2B
surface water quality standard for mercury is not considered valid. The reported
concentrations for the remaining metals were well below the corresponding 15A NCAC
2L groundwater quality standards and the 15A NCAC 2B surface water standards
applicable to the site.

The laboratory analytical results for the groundwater samples collected from the site
monitoring wells in April 2017 indicate that no Appendix I VOCs were reported in any of
the groundwater samples. The results of the metals analyses of the groundwater
samples indicate that arsenic and cadmium were reported in two of the samples,
barium, chromium and lead were reported in all of the samples, mercury and selenium
were reported in five of the samples, and silver was not reported in any of the samples.
None of the reported concentrations of metals detected in any of the groundwater
samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards.

3.0 CONCLUSIONS AND RECOMMENDATIONS

The results of the April 2017 groundwater and surface water quality monitoring
conducted at the Central Carolina Tire Monofill Landfill are generally consistent with the
results of previous monitoring conducted at the site. No Appendix I VOCs were
reported in surface water sample SW-1 (EXP). The reported estimated concentration of
mercury (0.038 µg/L) in surface water sample SW-1 (EXP) exceeds the 15A NCAC 2B
surface water quality standard for fresh water aquatic life (0.012 µg/L). However,
mercury was also reported in the associated equipment blank at a concentration that is
equivalent to that reported in the surface water sample. Consequently, the apparent
exceedance of the 15A NCAC 2B surface water quality standard for mercury is not
considered valid. The reported concentrations for the remaining metals detected in
surface water sample SW-1 (EXP) were well below the corresponding 15A NCAC 2L
groundwater quality standards and the 15A NCAC 2B surface water standards
– 5 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
applicable to the site. No Appendix I VOCs were reported in any of the groundwater
samples collected from the site in April 2017. In addition, none of the reported
concentrations of metals detected in any of the groundwater samples exceed the
corresponding 15A NCAC 2L .0202 groundwater quality standards.

If you have any questions or require further assistance regarding this report, please call
me at 919-995-0363. The next water quality monitoring event for the Central Carolina
Tire Monofill Landfill is scheduled for October 2017.

Sincerely,
Brian S. Boutin, P.G.
Consulting Geologist

Cc: Tim McNeil, Central Carolina Holdings, Inc.
Vance Moore, Garrett and Moore, Inc.
Craig Fortner, Garrett & Moore, Inc.
Drawn by: Reviewed by: Drawing #:
Drawing Date: 1
SITE LOCATION MAP
Central Carolina Tire Monofill Landfill
Harnett County, North Carolina
Source: USGS 7.5’ Topographic Quadrangle Series
Murchisontown, NC 2010
Figure No. Project #:
Scale: USGS
1:24,000 05/31/2012
N
11112 Branding Iron Place Wendell, NC 27591
Office: [phone]
Cell: [phone]
Central Carolina Tire
MW-10 27.0 2.0 356.28 353.74 13.44 342.84 18.4 4.83 176 4.3
MW-11 23.8 2.0 347.80 345.70 10.80 337.00 18.2 4.42 41 7.1
MW-12 21.6 2.0 336.58 334.45 5.95 330.63 18.1 4.32 16 44
MW-13 20.6 2.0 339.47 337.36 10.50 328.97 15.1 4.14 16 9
MW-14 12.6 2.0 344.12 341.86 7.27 336.85 16.2 4.45 26 8.9
MW-16 28.9 2.0 362.53 360.59 20.10 342.43 16.5 4.16 53 8.4
MW-17AR 20.0 2.0 352.99 350.70 11.73 341.26 19.0 4.46 44 9.2
MW-18 14.8 2.0 344.71 342.45 8.70 336.01 19.9 4.32 50 5.3
Notes:MSL = Mean Sea Level
BTOC = Below Top of Casing
GW = Groundwater
S.C. = Specific Conductance
ntu = Nephelometric Turbidity Units
Monitoring well construction data taken from October-December 2006 Sampling Event Monitoring Report prepared by Withers & Ravenel.
Well Depth
(Feet BTOC)pH S.C.
umhos/cm
Permit # 43-04
Monitoring Well and Groundwater Data
Table 1
April 2017 Sampling Event
Central Carolina Tire Monofill Landfill Phase III
Harnett County, North Carolina
Well
Identity Temp. Co
April 18-19, 2017
Well Diameter
(Inches)
Field Parameters
Turbidity
(ntu)
Ground
Surface
Elevation
(Feet MSL)
Groundwater
Elevation
(Feet MSL)
Depth to
Groundwater
(Feet BTOC)
Top of Casing
Elevation (Feet
MSL)
ORGANIC CONSTITUENTS GWP Std NCAC 2L STD
(ug/L)(ug/L)(ug/L)
Acetone ND ND ND ND ND ND ND ND ND NE 6000
Acrylonitrile ND ND ND ND ND ND ND ND ND NE NE
Benzene ND ND ND ND ND ND ND ND ND NE 1
Bromochloromethane ND ND ND ND ND ND ND ND ND 0.6 NE
Bromodichloromethane ND ND ND ND ND ND ND ND ND NE 0.6
Bromoform (Tribromoethane)ND ND ND ND ND ND ND ND ND NE 4
Bromomethane (Methyl Bromide)ND ND ND ND ND ND ND ND ND 10 10
2-Butanone (MEK), (Methyl Ethyl Ketone)ND ND ND ND ND ND ND ND ND NE 4000
Carbon Disulfide ND ND ND ND ND ND ND ND ND NE 700
Carbon Tetrachloride ND ND ND ND ND ND ND ND ND NE 0.3
Chlorobenzene ND ND ND ND ND ND ND ND ND NE 50
Chloroethane (Ethyl Chloride)ND ND ND ND ND ND ND ND ND NE 3000
Chloroform (Trichloromethane)ND ND ND ND ND ND ND ND ND NE 70
1,2-Dibromo-3-Chloropropane (DBCP)ND ND ND ND ND ND ND ND ND NE 0.04
Dibromochloromethane (Chlorodibromomethane)ND ND ND ND ND ND ND ND ND 0.41 0.4
1,2,-Dibromoethane (Ethylene Dibromide)ND ND ND ND ND ND ND ND ND NE 0.02
Dibromomethane (Methylene Bromide)ND ND ND ND ND ND ND ND ND 5.5 70
1,2-Dichlorobenzene (O-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 20
1,3-Dichlorobenzene (M-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 200
1,4-Dichlorobenzene (P-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 6
Trans-1,4-Dichloro-2-butene ND ND ND ND ND ND ND ND ND NE NE
1,1-Dichloroethane ND ND ND ND ND ND ND ND ND NE 6
1,2-Dichloroethane (Ethylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.4
1,1-Dichloroethene (Vinylidene Chloride)ND ND ND ND ND ND ND ND ND NE 7
1,2-Dichloroethene (cis and trans isomers)ND ND ND ND ND ND ND ND ND 60 60
1,2-Dichloropropane (Propylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.6
1,1-Dichloropropene ND ND ND ND ND ND ND ND ND NE NE
1,3-Dichloropropene (cis and trans isomers)ND ND ND ND ND ND ND ND ND NE 0.4
Ethylbenzene ND ND ND ND ND ND ND ND ND NE 600
Iodomethane (Methyl Iodide)ND ND ND ND ND ND ND ND ND NE NE
2-Hexanone (Methyl Butyl Ketone)ND ND ND ND ND ND ND ND ND NE 280
Methyl Chloride (Chloromethane)ND ND ND ND ND ND ND ND ND NE 3
Methylene Chloride (Dichloromethane)ND ND ND ND ND ND ND ND ND NE 5
4-Methyl-2-Pentanone (Methyl Isobutyl Ketone)ND ND ND ND ND ND ND ND ND 560 NE
Styrene ND ND ND ND ND ND ND ND ND NE 70
1,1,1,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 1 1
1,1,2,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 0.18 0.2
Tetrachloroethene (Tetrachloroethylene), (PCE)ND ND ND ND ND ND ND ND ND NE 0.7
Toluene ND ND ND ND ND ND ND ND ND NE 600
1,1,1-Trichloroethane (Methylchloroform)ND ND ND ND ND ND ND ND ND NE 200
1,1,2-Trichloroethane ND ND ND ND ND ND ND ND ND 0.6 0.6
Trichloroethene (Trichloroethylene), (TCE)ND ND ND ND ND ND ND ND ND NE 3
Trichlorofluoromethane (CFC-11) ND ND ND ND ND ND ND ND ND NE 2000
1,2,3-Trichloropropane ND ND ND ND ND ND ND ND ND NE 0.005
Vinyl Acetate ND ND ND ND ND ND ND ND ND 88 88
Vinyl Chloride ND ND ND ND ND ND ND ND ND NE 0.03
Total Xylenes ND ND ND ND ND ND ND ND ND NE 500
INORGANIC CONSTITUENTS GWP Std NCAC 2L STD
(in ug/L)(ug/L)(ug/L)
Arsenic ND 0.55 J ND 1.4 ND ND ND ND ND NE 10
Barium 42 B 43 B 51 B 9.5 B 8.0 B 32 B 62 B 110 B 62 B NE 700
Cadmium ND 0.064 J ND 0.12 J ND ND ND ND ND NE 2
Chromium 0.20 JB 0.44 JB 0.27 JB 1.8 B 0.24 JB 0.21 JB 0.23 JB 0.54 JB 0.17 JB NE 10
Lead 0.63 JB 0.86 JB 1.0 JB 1.1 JB 0.50 JB 0.63 JB 0.97 JB 1.2 JB 1.3 JB NE 15
Mercury 0.038 JB 0.30 B 0.42 JB 0.061 JB ND ND 0.84 B ND 0.087 JB NE 1
Selenium ND 4.2 J 0.46 J ND ND ND 1.7 J 1.3 J 0.50 J NE 20
Silver ND ND ND ND ND ND ND ND ND NE 20
Notes:
Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standard for Class GA groundwater.J = Estimated value above laboratory method detection limit and below SWSL or reporting limit.
NCAC 2L STD = North Carolina Groundwater Standard established in Title 15A of North Carolina Administrative Code Subchapter 2L B = Analyte found in associated field and/or laboratory blank.
GWP Std = Solid Waste Section Groundwater Protection Standard NE = No standard established.
ND = None detected above laboratory method detection limit.
NS = Not Sampled, No sample exists for this sampling period
MW-17ARMW-11 MW-18MW-10 MW-12
Table 2
SW-1 (EXP)MW-13 MW-14
Central Carolina Tire Monofill Landfill Phase III, Harnett County, NC
Laboratory Results for Surface Water and Groundwater Samples
October 3, 2016
October 2016 Sampling Event
MW-16
Permit # 43-04
Page 1 of 2
Sampling Date:2L Standard 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17
Well No:MW-10
Arsenic 10 ND 1.91 J 2.25 J ND ND 1.5 J ND ND 1.40 1.90 1.80 ND 1.10 ND 1.60 0.77 J 0.64 J 0.69 J 0.55 J
Barium 700 39.2 JB 53.8 JB 63.3 JB 27.8 JB 22.0 0.17 J 32.0 25.0 33.0 17.0 40.0 18.0 29.0 39.0 29.0 40.0 36 50 43 B
Cadmium 2 ND ND ND ND ND 0.69 J ND ND ND ND 0.094 J ND 0.049 J ND ND 0.052 J 0.086 J 0.45 J 0.064 JChromium102.47 JB 1.45 JB 3.01 JB 2.86 JB 0.55 J ND ND 8.4 BJ ND 2.7 B ND ND ND ND 0.26 J 0.51 J ND 2.0 0.44 JBLead154.90 J ND ND ND 0.71 J ND ND 0.95 J 0.21 J 0.28 J 0.2 J 0.26 J 0.33 J ND 0.18 J 0.32 J 0.26 J 0.17 J 0.86 JB
Mercury 1 ND ND 0.281 J ND ND ND ND 0.019 J ND ND ND 0.18 J 0.34 0.15 J 1.80 0.23 1.70 ND 0.30 B
Selenium 20 ND ND ND ND ND 10.00 ND ND 7.20 6.50 7.70 2.00 3.80 3.50 8.60 6.00 8.4 5.2 4.2 J
Silver 20 2.37 JB 3.41 JB ND ND ND ND ND 0.45 J ND 0.18 J ND ND 0.056 J ND ND ND ND ND NDAcetone60001.83 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDBromoform4NDNDNDNDNDNDNDNDNDNDNDNDND1.10 ND ND ND ND ND
Trichloroethene 3 ND ND 0.380 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Toluene 600 ND 5.54 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17
Well No:MW-11
Arsenic 10 ND ND 2.43 J ND ND ND ND ND ND ND ND 0.37 J ND ND ND ND 0.48 J ND NDBarium70055.1 JB 44.6 JB 60.5 JB 29.6 JB 65.0 51.0 33.0 25.0 27.0 28.0 28.0 29.0 63.0 23.0 55.0 43.0 54.0 28 51 BCadmium2NDNDNDNDND2.1 ND 0.27 J ND ND 0.061 J 1.4 ND ND ND 0.14 J 0.16 J 0.069 J ND
Chromium 10 6.94 JB 1.35 JB 3.99 JB 3.42 JB ND 1.5 J ND 7.2 B ND 2.8 B 1.1 B ND ND ND ND 0.64 J 0.54 J ND 0.27 JB
Lead 15 10.60 ND 5.01 JB ND ND 0.81 J ND 0.89 J 0.30 J 0.38 J 0.37 J 0.88 J 0.20 J 0.21 J 0.22 J 0.60 J 0.69 J 0.32 J 1.0 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.86 1.20 ND 0.42 JBSelenium20NDNDNDNDNDNDND0.47 J 0.70 J 1.00 0.62 J ND ND ND ND 0.83 J 0.98 J ND 0.46 JSilver202.03 JB 3.91 JB 1.49 JB 1.56 JB ND ND ND 0.33 J ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND 0.830 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17
Well No:MW-12
Arsenic 10 2.32 J ND 3.00 J ND ND ND ND 0.12 J 0.38 J ND ND 2.70 0.83 J 14.00 0.63 J 2.10 4.00 3.6 1.4
Barium 700 46.2 JB 23.8 JB 56.2 JB 24.8 JB 5.7 J 11 J 14.0 16.0 15.0 13.0 15.0 17.0 9.0 22.0 8.9 15.0 11.0 9.5 9.5 BCadmium2NDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.18 J 0.088 J 0.042 J 0.12 JChromium1011.6 B 3.25 JB 7.16 JB 4.08 JB 1.6 J 2 J ND 5.60 ND 3.6 B 1.6 B 0.95 J 0.47 J 2.40 1.30 5.70 3.90 2.2 1.8 B
Lead 15 6.31 J 4.80 J 9.68 JB ND 0.81 J 2 J ND 0.62 J 0.64 J 0.96 J 0.41 J 1.70 0.49 J 1.60 0.90 J 2.40 1.70 0.50 J 1.1 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.12 J ND ND 0.061 JB
Selenium 20 7.32 J ND ND ND ND ND ND ND ND ND 0.34 J ND ND ND ND ND 0.72 J ND NDSilver201.93 JB 4.01 JB 1.82 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 0.013 J ND NDAcetone6000NDNDNDNDNDNDNDNDNDNDNDNDND6.60 ND ND ND 4.2 J ND
Chloroform 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND 0.390 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
2-Butanone (MEK)4000 ND ND ND ND ND ND ND ND ND ND ND ND ND 9.80 ND ND ND ND NDToluene6000.510 JB 0.510 JB ND ND ND ND ND ND ND ND ND ND ND 4.5 ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-13Arsenic 10 ND ND ND ND 3.1 J ND ND ND ND 0.60 J ND 0.50 J ND ND ND ND ND ND ND
Barium 700 19.8 JB 14.9 JB 18.5 JB 8.7 JB 7.4 J 4.8 J 6.3 J 7.5 3.9 J 6.0 7.1 11.0 4.5 J 4.2 J 4.9 J 13.0 7.0 4.1 J 8.0 B
Cadmium 2 ND ND ND ND ND ND 0.19 J ND ND ND ND ND ND ND ND 0.10 J 0.089 J 0.10 J ND
Chromium 10 3.07 JB ND 3.60 JB 3.05 JB 2.1 J 1.3 J ND 3.6 B ND 2.6 B 1.1 B ND ND ND ND 1.50 ND ND 0.24 JBLead158.32 J 4.75 J 7.51 JB ND ND ND ND 0.41 J 0.24 J 0.21 J 0.18 J 0.83 J 0.12 J 0.26 J ND 1.1 0.27 J 0.29 J 0.50 JBMercury1NDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.068 J ND ND ND
Selenium 20 ND ND ND ND ND ND ND ND ND ND 0.36 J ND ND ND ND ND ND ND ND
Silver 20 2.88 JB 3.65 JB 1.12 JB 0.78 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Bromoform 4 ND ND ND 0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-14
Arsenic 10 ND ND 2.50 J ND ND 1.9 J ND ND 0.12 J 0.30 J ND ND ND ND ND ND ND 0.31 J ND
Barium 700 180 B 185 B 177 B 159 B 130.0 91.0 110.0 87.0 110.0 100.0 80.0 67.0 38.0 26.0 28.0 42.0 34.0 27 32 B
Cadmium 2 ND ND ND 0.22 J ND 0.34 J ND ND ND ND 0.18 J 0.27 J ND ND ND 0.074 J 0.097 J 0.12 J NDChromium104.86 JB 1.77 JB 3.80 JB 5.02 JB 0.9 J 1.6 J ND 6.9 B ND 2.4 B 1.2 B ND ND ND ND 0.80 J 0.51 J ND 0.21 JBLead158.51 J 5.06 J 3.74 JB 8.24 J 1.7 J 1.7 J 1.4 J 1.80 1.60 1.70 0.82 J 1.10 0.43 J 0.035 J 0.22 J 0.94 J 0.27 J 0.44 J 0.63 JB
Mercury 1 ND ND ND ND ND ND ND 0.019 J ND ND ND ND ND ND ND ND ND ND ND
Selenium 20 ND ND ND ND ND ND ND ND ND ND 0.80 J ND 0.16 J ND ND ND ND ND ND
Silver 20 1.99 JB 3.11 JB 1.29 JB ND ND ND ND ND ND ND 0.12 J ND ND ND ND ND ND ND NDAcetone6000NDNDNDNDNDNDNDNDNDNDNDNDND15.00 ND ND ND ND NDBromoform4NDNDND0.18 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-16
Arsenic 10 ND ND 4.76 JB ND ND ND ND 0.67 J ND 0.41 J ND 0.44 J ND ND ND ND 0.47 J ND ND
Barium 700 69.8 JB 31.1 JB 28.8 JB 16.3 JB 27.0 19 J 24.0 38.0 33.0 31.0 38.0 48.0 41.0 42.0 35.0 37.0 37.0 58 62 B
Cadmium 2 ND ND ND ND ND 0.66 J ND ND ND ND 0.14 J 0.037 J ND ND ND 0.053 J 0.11 J 0.059 J NDChromium103.07 JB 1.87 JB 3.99 JB 2.76 JB 1.0 J 1.5 J ND 8.7 B ND 2.5 B 1.2 B ND ND ND ND 0.83 J 0.63 J ND 0.23 JBLead158.15 J ND 4.74 JB ND 1.1 J ND ND 0.66 J 0.41 J 0.55 J 0.55 J 0.97 J 0.49 J 0.49 J 0.37 J 0.56 J 0.71 J 0.57 J 0.97 JB
Mercury 1 ND 0.114 J ND ND ND ND 0.092 J 0.17 J ND ND ND ND 0.028 J 0.15 J ND 0.46 0.45 ND 0.84 B
Selenium 20 ND ND ND 2.9 J ND ND ND 0.48 J 0.97 J 0.69 J 0.24 J ND ND ND ND ND 0.42 J ND 1.7 J
Silver 20 1.66 JB 4.10 JB 1.85 JB 0.86 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDAcetone60002.42 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDBromoform4NDNDND1.06 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Dibromochloromethane 0.4 ND ND ND 0.25 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
NOTES:
Results in parts per billion (ppb)
ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007).
NA - Not analyzed for or not available
Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards.
Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel.
J = Estimated value above laboratory method detection limit and below SWSL or reporting limit.
B = Analyte found in associated field and/or laboratory blank.
Table 3
Historical Summary of Constituent Detections
Central Carolina Tire Monofill Landfill Phase III
Permit # 43-04
Harnett County, North Carolina
Page 2 of 2
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17Well No:MW-17AR*
Arsenic 10 ND ND 5.63 J ND ND ND ND ND ND ND ND 0.46 J 0.95 J ND ND ND 0.75 J 5.3 NDBarium70071.9 JB 89.5 JB 56.4 JB 68.6 JB 35.0 41.0 41.0 90.0 30.0 120.0 130.0 110.0 25.0 110.0 150.0 110.0 37.0 39 110 BCadmium2NDNDNDNDNDNDNDNDND0.24 J 0.17 J 0.086 J ND 0.093 J ND 0.11 J 0.094 J 0.11 J ND
Chromium 10 2.47 JB ND 3.90 JB 2.58 JB ND 1.6 J ND 4.90 ND 2.6 B 1.2 B ND 2.30 0.32 J 1.10 1.50 2.50 21 0.54 JB
Lead 15 5.88 J ND ND ND ND ND ND 1.00 1.30 1.70 1.40 1.50 1.90 2.00 1.90 2.10 1.40 13 1.2 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDSelenium20NDNDNDNDNDNDNDND0.76 J 0.72 J 0.51 J ND ND ND ND ND 0.52 J 0.50 J 1.3 JSilver202.26 JB 4.19 JB 1.51 JB 0.84 JB ND ND ND ND ND ND 0.041 J ND ND ND ND ND 0.017 J 0.28 J ND
Acetone 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.0 ND
Bromoform 4 ND ND ND 0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND 0.450 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDNDNDND0.58 ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17
Well No:MW-18
Arsenic 10 ND ND 2.22 J ND ND ND ND ND 0.34 J 0.60 J ND 0.37 J 0.51 J ND ND 0.84 J ND 0.70 J ND
Barium 700 43.1 JB 43.8 JB 48.6 JB 48.4 JB 41.0 41.0 46.0 41.0 40.0 41.0 39.0 57.0 31.0 46.0 43.0 55.0 59.0 20 62 BCadmium2NDNDNDNDNDND0.23 J ND ND ND ND 0.050 J 0.039 J ND ND 0.081 J 0.11 J 0.062 J NDChromium102.32 JB 1.25 JB 3.90 JB 3.51 JB ND 1.5 J ND 4.70 ND 2.5 B 1.0 B ND ND ND 0.38 J 0.63 J 0.60 J 3.6 0.17 JB
Lead 15 4.07 J ND 6.38 JB ND 0.96 J 2.3 J ND 0.56 J 0.47 J 0.53 J 0.50 J 0.77 J 0.56 J 0.61 J 0.45 J 0.84 J 0.94 J 2.0 1.3 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND 0.39 0.37 0.029 J 0.26 0.14 J 0.014 J ND ND 0.087 JB
Selenium 20 ND ND ND ND ND ND ND ND 0.67 J 0.75 J 0.92 J ND 0.22 J ND 1.90 4.20 0.79 J ND 0.50 JSilver202.07 JB 3.72 JB 1.69 JB 0.95 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.038 J 0.064 J ND
60 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.75 ND ND ND
Methylene Chloride 5 ND 0.910 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/18/17
Well No:SW-1(Exp)
Arsenic 10 ND ND 1.96 J ND ND ND ND 0.79 J 0.23 J ND ND ND ND ND ND 0.35 J 0.59 J 0.67 J ND
Barium 700 44.4 JB 17.9 JB 21.7 JB 10.5 JB 12.00 9.5 J 13.00 33.00 21.00 21.00 26.00 43.00 34.00 30.00 43.00 33.00 45.00 28 42 BCadmium2NDNDNDNDND0.2 J ND ND 0.31 J ND ND ND ND ND ND 0.049 J 0.10 J 0.049 J NDChromium101.73 JB ND 2.71 JB 2.58 JB ND 1.3 J ND 8.30 ND 4.7 B 1.4 B ND ND ND ND 0.68 J 0.79 J ND 0.20 JB
Lead 15 6.43 J ND 4.49 JB ND 0.76 J ND 0.83 J 7.50 0.95 J 0.44 J ND 1.10 0.27 J 0.35 J ND 0.43 J 1.10 0.39 J 0.63 JB
Mercury 1 ND ND ND ND ND ND ND 0.23 ND ND ND ND ND ND ND ND ND ND 0.038 JB
Selenium 20 ND ND ND ND ND ND ND 0.79 J 1.10 1.00 0.68 J ND 0.22 J ND 1.40 0.86 J 0.36 J 1.2 NDSilver202.53 JB 3.75 JB 1.66 JB 0.98 JB ND ND ND ND 0.22 J ND ND ND ND ND ND ND 0.018 J ND NDStyrene70NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NOTES:
Results in µg/L (parts per billion, ppb)
ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007).* - Monitoring well MW-17 was abandoned on August 30, 2011 to make way for landfill expansion
NA - Not analyzed for or not available and was replaced by monitoring well MW-17AR located outside the expansion footprint.
Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards.
Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel.
J = Estimated value above laboratory method detection limit and below SWSL or reporting limit.
B = Analyte found in associated field and/or laboratory blank.
Table 3 (Continued)
Historical Summary of Constituent Detections
Central Carolina Tire Monofill Landfill Phase III (Planned)
Permit # 43-04
1,2-Dichloroethene
(cis and trans isomers)
Harnett County, North Carolina

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
APPENDIX A

Groundwater Sampling Forms
l/Piezo lD fl1t- -(
nd Water Sample Gollection Record
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
WELL PURGING DATA
a. Purge Method
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
well W Piezometer nr-e. Length of Water Column f .z-3 @-o)
f. Calculated Well Volume (see back) O - t
b. Acceptance Criteria
- Minimum Required
(from workplan)
Volume (@ _ well volumes) _ N/A Pumping Raie: /d O ml/minurbidity N/A NTUS
1Q o/o
Used: Make Model Serial Number
- Maximum Allowable
- Stabillzation of para
c. Field Testing
d. Field Testing Eq
e. Accepiance criteria
Has required
Has required turbi
Have parameters
lf no or N/A -
been removed
been reached
No N/Annnnnn
SAMPLE COLLECTION:
Comments
lient: NAUTILUS
No: CENTRAL
Location: CAMERON,
Conds: C/4 etr;'
Date: 4l t7 n7
Time: Start egt " .^tp^
Finish /Ce C) am/pm
INA TIRE, PERMIT #4304
Volume
Removed ml
YSt 556 tb_flc(LrY
t Calibration Documentation Found on Separate Form
Yes.&&*below.
Method: Peristaltic Pump
Signature oate
-q
l? nt
Client: NAUTILUS
Project No: CENTRAL
Site Location: CAMERON,
ther Conds: tu liV 4
oate:
-qt[?
nz
rime. Start c8 /7 rr/p-
Sinis6 clcT am/pm
RCRA METALS
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
WELL PURGING DATA
Has required
Has required
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete t 2"
LOW FLOW
/r:
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum
- Stabilization of par
Turbidity N/A NTUsneters 10 Yo
c. Field Testing Eq t Used: Make
nd Water Sample Gollection Record
tluu'-/ 3
werrd=Piezometer n
e. Length of Water Cotumn I L'. a C @-o)
f. Calculated Well Volume (see back) 1 6
Serial NumbercT{e(>t
(from workplan)
Volume (@ _ well volumes)Pumping Rale: / 6 O mllmin
d. Field Testing Equ Calibration Documentation Found on Separate Form
e. Acceptance criteria Yes.frfr^rt-
SAMPLE COLLECTION:Method: PeristalticPump
Have parameters
lf no or N/A -
been removed
been reached
lized
in below.
N/Atrn
T-t
Nonnn
Comments
Signature oate
-u
il tr
Client: NAUTILUS
Project No: CENTRAL
oate:
-q
lal nz
Time: Start 6?.tt am/pm
Finish c8 /Cr smyprn
INA TIRE. PERMIT #4304
TURBIDITY
MLt' -/ 6
nd Water Sample Collection Record
WATER LEVEL DATA: (
a. Total Well Length
b. Water Table Depth
WELL PURGING DATA
a. Purge Method
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
Well #- Piezometer flre. Lengih of Water Column {- t €' O-Ol
f. Calculated Well Votume (see back) | 3
b. Acceptance Criteria
- Minimum Required
- Maximum
- Stabilization of
c. Field Testing E
d. Field Testing
e. Accepiance criteria
Has required volu
Has required
been removed
been reached
(from workplan)
Volume (@ _ well volumes)Pumping Rate: /f,e muminN/A NTUs
-----7d
o/o
Used: Make Model Serial NumberySI 556 /a:-/e( 2J ?
Calibration Documentation Found on Separate Form
Yes&&H-
Method: Peristaltic Pump
N/Annn
NonntrHave parameters
lf no or N/A -below
SAMPLE COLLECTION:
Comments
Signature
Date:
-4
i8 ht
Time: Start I 7 -f-t am/pmrOl +Frnrsh rtr\ am/pm
Client: NAUTILUS GE
Project No: CEIITBAL
Site Location: CAMI
Weather Conds'. (7o"r.
Grou Water Sample Collection Record
ID:
f11 L4-/-
Well .Piezometer n
e. ler{gtn of Water Column /S-- f '5-- 1a-n;
f. Calculated Well Volume (see back) a/.f
WATER LEVEL DATA:
a. Total Well Length '? i
b. Water Table Depth
-t?
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of
c. Field Testing Eq
d. Field Testing
e. Acceptance criteria
Has required volume removed
Has required turbidi been reached
Have parameters
lf no or N/A -below
from Top of Casing)
c. Casing Material PVC
d Casino Diamete t 2"
LOW FLOW
(from workplan)
rqe Volume (@ well volumes)
-
N/A Pumping Rar;: I 6 C mllmin.
urbidity N/A NTUs3ters 10 Yo
Jsed: Make Model Serial Numberyst 556 iaT{a t}t y
Calibration Documentation Found on Separate Form
N/Annn
Yes Nodnu#T LJwrl
SAMPLE COLLECTION:
Comments
Method: PeristalticPump
Signature Date 4l lY h7
Client: NAUTILUS
Project No: CENTRAL
Site Location: CAME
Date'.
-4
/Y ttt
Time: Start l(f€ am/pm
Finish (1 ?O am/pm
INA TIRE, PERMIT #4304
nd Water Sample Collection Record
from Top of Casing)Well !
.t-U.O c. Casing Material PVC
4llLt - l'7
Piezometer I
e. Length of Water Column I . L1 6-01
f. Calculated Well Volume (see back) / . Y
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
WELL PURGING DATA
Has required turbidi
Have parameters
lf no or N/A -
SAMPLE COLLECTION:
Comments
d. Casing Diamete r 2"
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum
- Stabilization of
c. Field'l'esting Eq
d. Field Testing
e. Acceptance criteria sslfail
Has required
LOW FLOW
(from workplan)
Volume (@ _ well volumes) _ N/A Pumping Rate: / fC ml/minTurbidity N/A NTUs
1A o/o
Make Model Serial Number
been removed
been reached
No N/ADNunnn
YSI 556 /cT/e t.?t /
Calibration Documentation Found on Separate Form
vgg-b-4.A_
below.
Method: Peristaltic Pump
Signature oae - at ll rz
TIRE. PERMIT #4344
Date'.
-4
tX tfi
Time: Start lf-?O amlpm
Finish l€>A.a ambm
Client: NAUTILUS
Project No: CENTRAL
Site Location: CAMER
Conds: dzc,t)g ?
4304- /v\W (A
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth tjv
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
urbidity N/A NTUsrters 10 Yo
Used: Make Model
well il Piezometer n
e. Lengthofwatercolumn ,g. ob 6-b)
f. Calculated Well Volume (see back) '2 " I
Water Sample Collection Record
i./\W.IO
Serial Number
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of par
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume removed
Has required been reached
Have parameters
lfnoorN/A-E in below
(from workplan)
Volume (@ _ well volumes)Pumping Rate 1OO milmin
YSI 556 icr{/D/dt-/
Calibration Documentation Found on Separate Form
Yes-a_EF
Method: PeristalticPumo
No N/AntrnnNI
SAMPLE COLLECTION:
Comments
Signature Date 4t/ tr /17
: NAUTILUS
No: CENTRAL
Weather Conds: <{d ul
Date:
-il
i8 n7
Time: Start lgJO am/pm
Finish -llf am/pm
NA TIRE, PERMIT #4
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
s-
8.7
Water Sample Collection Record
from Top of Casing)weil #-
t^) -
Piezometer E
e. Length of Water Column (: . -\ c/6. S-cr 1a_ny
f. Calculated Well Volume (see back) ( " I
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minlmum Required
- Maximum Allowable
- Stabilization of par
c. Field Testing Equi
d. Field Testing
e" Acceptance criteria
Has required volume
Has required
Have parameters
lf no or N/A -
(from workplan)
Volume (@ _well volumes) _ N/A Pumping P"1"' l2C 6Yry1;n.N/A NTUS
----fiYo
Used: Make Model Serial NumberYSI 556 (bTt o I el /
Yesg4g-
Calibration Documentation Found on Separate Form
removed
reached
Method: Peristaltic Pump
N/Antrn
Nonntr
SAMPLE COLLECTION:
Comments
{,
Signature Date 4 18 nt
lient: NAUTILUS GE
No: CENTRAL
Site Location: CAMERON
oate:
-q
lf' ttz
Time: Startl@-am/pm
Finish iq.ao amipm
NATIRE, PERMIT#4304
/1W - (\
Gro d Water Sample Collection Record
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
from Top of Casing)
to.8
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable urbidity N/A NTUs
-.ters 10 o/"
Used: Make Model Serial NumberYSt 556 /e.T/b/ 2
a
d. Field Testing Calibration Documentation Found on Separate Form
e. Acceptance criteria
Has required volume removed
reachedHas required
Have parameters
lf no or N/A -
SAMPLE COLLECTION:Method: Peristaltic Pump
Comments
.-5,c. Casing Material PVC
d. Casing Diamete t 2"
LOW FLOW
well ffi-' Piezometer nlrn4(.-
e. Length of Water Column /.< .' ( L @-b)
f. Calculated Well Volume (see back) J ' /
J (from workplan)
Volume (@ well volumes) Pumping pgls / a O milmin.
- Stabilization of
c. Field Testing
Yes.E,t
N/Antrrl
Nonnu
n below.
Signature Date _4 /f n7
Client: N.
EFM E
(s@l
IPMENT
Project #:
CALIBRATION FORM
aC- -Tr,4{-
INSTRUMENT:alcc /
SERTAL 19.; /oTrE1 a1
INSTRUMENT: V (r ii-6 rca/
SERTAL NejiaTlor>_r
Calibration Recorded
Lot# ' i.'(; )_L Y Exp:
Lot# Ll c^l S*7c- Exp: , [t I
Lot# 7 t"ii tz I
1.413mS Lor# (sl 7ti
iL)'-( il,i
heck /.718 mS
Check 7.0
- t f i )..r -"\ r] ,r"td- ft ) rf rrr-;1 2
Galibration Recorded
1.413mS
k/.718 mS
Check 7.0

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
APPENDIX B

Laboratory Reports
And
Chain-of-Custody Records

This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Case Narrative
05/09/2017
Nautilus Geologic Consulting, PLLC
Brian S. Boutin
11112 Branding Iron Place
Wendell, NC 27591
Project: Central Carolina Tire
Project No.: 43-04
Lab Submittal Date: 04/21/2017
Prism Work Order: 7040416
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
President/Project Manager
Reviewed ByRobbi A. Jones Robbi A. Jones
President/Project Manager
Data Qualifiers Key Reference:
A Analysis performed outside recommended holding time due to instrument failures.
Aa Reporting limit raised to 2 ug/L on the samples in this analytical batch, therefore, the Lead that was found in the
Method Blank is <1/2 the reporting limit.
CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken.
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
LH High LCS recovery. Analyte not detected in the sample(s). No further action taken.
M Matrix spike outside of the control limits.
Method Detection LimitMDL
Below Reporting LimitBRL
Relative Percent DifferenceRPD
*Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 1 of 61
Sample Receipt Summary
05/09/2017
Prism Work Order: 7040416
Client Sample ID MatrixLab Sample ID Date Sampled Date Received
7040416-01 04/18/174304-TB01 04/21/17Water
7040416-02 04/18/174304-EB01 04/21/17Water
7040416-03 04/18/174304-MW10 04/21/17Water
7040416-04 04/18/174304-MW11 04/21/17Water
7040416-05 04/18/174304-MW12 04/21/17Water
7040416-06 04/19/174304-MW13 04/21/17Water
7040416-07 04/19/174304-MW14 04/21/17Water
7040416-08 04/19/174304-MW16 04/21/17Water
7040416-09 04/18/174304-MW17R 04/21/17Water
7040416-10 04/18/174304-MW18 04/21/17Water
7040416-11 04/19/174304-SW1 04/21/17Water
7040416-12 04/19/174304-SW2 04/21/17Water
7040416-13 04/18/174304-SW1 (Exp)04/21/17Water
7040416-14 04/19/174304-MW2 04/21/17Water
7040416-15 04/19/174304-MW3 04/21/17Water
7040416-16 04/19/174304-MW4 04/21/17Water
7040416-17 04/19/174304-MW5 04/21/17Water
7040416-18 04/19/174304-MW6 04/21/17Water
7040416-19 04/19/174304-MW7 04/21/17Water
7040416-20 04/19/174304-MW8 04/21/17Water
7040416-21 04/19/174304-MW9 04/21/17Water
Samples were received in good condition at 4.2 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 2 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.030 J ug/L7040416-02 4304-EB01 Mercury 7470A
1.3 J ug/L7040416-02 4304-EB01 Barium 6020B
0.12 J ug/L7040416-02 4304-EB01 Chromium 6020B
0.81 J ug/L7040416-02 4304-EB01 Lead 6020B
0.30 ug/L7040416-03 4304-MW10 Mercury 7470A
0.55 J ug/L7040416-03 4304-MW10 Arsenic 6020B
43 ug/L7040416-03 4304-MW10 Barium 6020B
0.064 J ug/L7040416-03 4304-MW10 Cadmium 6020B
0.44 J ug/L7040416-03 4304-MW10 Chromium 6020B
0.86 J ug/L7040416-03 4304-MW10 Lead 6020B
4.2 J ug/L7040416-03 4304-MW10 Selenium 6020B
0.42 ug/L7040416-04 4304-MW11 Mercury 7470A
51 ug/L7040416-04 4304-MW11 Barium 6020B
0.27 J ug/L7040416-04 4304-MW11 Chromium 6020B
1.0 J ug/L7040416-04 4304-MW11 Lead 6020B
0.46 J ug/L7040416-04 4304-MW11 Selenium 6020B
0.061 J ug/L7040416-05 4304-MW12 Mercury 7470A
1.4 ug/L7040416-05 4304-MW12 Arsenic 6020B
9.5 ug/L7040416-05 4304-MW12 Barium 6020B
0.12 J ug/L7040416-05 4304-MW12 Cadmium 6020B
1.8 ug/L7040416-05 4304-MW12 Chromium 6020B
1.1 J ug/L7040416-05 4304-MW12 Lead 6020B
8.0 ug/L7040416-06 4304-MW13 Barium 6020B
0.24 J ug/L7040416-06 4304-MW13 Chromium 6020B
0.50 J ug/L7040416-06 4304-MW13 Lead 6020B
32 ug/L7040416-07 4304-MW14 Barium 6020B
0.21 J ug/L7040416-07 4304-MW14 Chromium 6020B
0.63 J ug/L7040416-07 4304-MW14 Lead 6020B
0.84 ug/L7040416-08 4304-MW16 Mercury 7470A
62 ug/L7040416-08 4304-MW16 Barium 6020B
0.23 J ug/L7040416-08 4304-MW16 Chromium 6020B
0.97 J ug/L7040416-08 4304-MW16 Lead 6020B
1.7 J ug/L7040416-08 4304-MW16 Selenium 6020B
110 ug/L7040416-09 4304-MW17R Barium 6020B
0.54 J ug/L7040416-09 4304-MW17R Chromium 6020B
1.2 J ug/L7040416-09 4304-MW17R Lead 6020B
1.3 J ug/L7040416-09 4304-MW17R Selenium 6020B
0.087 J ug/L7040416-10 4304-MW18 Mercury 7470A
62 ug/L7040416-10 4304-MW18 Barium 6020B
0.17 J ug/L7040416-10 4304-MW18 Chromium 6020B
1.3 J ug/L7040416-10 4304-MW18 Lead 6020B
0.50 J ug/L7040416-10 4304-MW18 Selenium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 3 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.074 J ug/L7040416-11 4304-SW1 Mercury 7470A
0.64 J ug/L7040416-11 4304-SW1 Arsenic 6020B
24 ug/L7040416-11 4304-SW1 Barium 6020B
0.58 J ug/L7040416-11 4304-SW1 Chromium 6020B
0.82 J ug/L7040416-11 4304-SW1 Lead 6020B
0.045 J ug/L7040416-12 4304-SW2 Mercury 7470A
25 ug/L7040416-12 4304-SW2 Barium 6020B
0.12 J ug/L7040416-12 4304-SW2 Cadmium 6020B
0.34 J ug/L7040416-12 4304-SW2 Chromium 6020B
0.34 J ug/L7040416-12 4304-SW2 Lead 6020B
0.073 CCV, J ug/L7040416-12 4304-SW2 Silver 6020B
0.038 J ug/L7040416-13 4304-SW1 (Exp)Mercury 7470A
42 ug/L7040416-13 4304-SW1 (Exp)Barium 6020B
0.20 J ug/L7040416-13 4304-SW1 (Exp)Chromium 6020B
0.63 J ug/L7040416-13 4304-SW1 (Exp)Lead 6020B
0.053 J ug/L7040416-14 4304-MW2 Mercury 7470A
82 ug/L7040416-14 4304-MW2 Barium 6020B
0.29 J ug/L7040416-14 4304-MW2 Chromium 6020B
1.8 J ug/L7040416-14 4304-MW2 Lead 6020B
1.1 J ug/L7040416-14 4304-MW2 Selenium 6020B
0.053 J ug/L7040416-15 4304-MW3 Mercury 7470A
0.63 J ug/L7040416-15 4304-MW3 Arsenic 6020B
28 ug/L7040416-15 4304-MW3 Barium 6020B
0.32 J ug/L7040416-15 4304-MW3 Chromium 6020B
0.96 J ug/L7040416-15 4304-MW3 Lead 6020B
0.80 J ug/L7040416-15 4304-MW3 Selenium 6020B
0.038 J ug/L7040416-16 4304-MW4 Mercury 7470A
0.45 J ug/L7040416-16 4304-MW4 Arsenic 6020B
21 ug/L7040416-16 4304-MW4 Barium 6020B
0.33 J ug/L7040416-16 4304-MW4 Chromium 6020B
0.96 J ug/L7040416-16 4304-MW4 Lead 6020B
0.043 J ug/L7040416-17 4304-MW5 Mercury 7470A
12 ug/L7040416-17 4304-MW5 Barium 6020B
0.18 J ug/L7040416-17 4304-MW5 Chromium 6020B
0.71 J ug/L7040416-17 4304-MW5 Lead 6020B
0.043 J ug/L7040416-18 4304-MW6 Mercury 7470A
1.5 ug/L7040416-18 4304-MW6 Arsenic 6020B
46 ug/L7040416-18 4304-MW6 Barium 6020B
0.22 J ug/L7040416-18 4304-MW6 Chromium 6020B
0.93 J ug/L7040416-18 4304-MW6 Lead 6020B
0.58 J ug/L7040416-18 4304-MW6 Selenium 6020B
63 ug/L7040416-19 4304-MW7 Barium 6020B
0.17 J ug/L7040416-19 4304-MW7 Chromium 6020B
2.2 ug/L7040416-19 4304-MW7 Lead 6020B
39 ug/L7040416-20 4304-MW8 Barium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 4 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.20 J ug/L7040416-20 4304-MW8 Chromium 6020B
1.1 J ug/L7040416-20 4304-MW8 Lead 6020B
0.99 J ug/L7040416-20 4304-MW8 Selenium 6020B
2.5 ug/L7040416-20 4304-MW8 Tetrachloroethylene 8260B
0.21 ug/L7040416-21 4304-MW9 Mercury 7470A
8.3 ug/L7040416-21 4304-MW9 Arsenic 6020B
400 ug/L7040416-21 4304-MW9 Barium 6020B
0.25 J ug/L7040416-21 4304-MW9 Cadmium 6020B
0.62 J ug/L7040416-21 4304-MW9 Chromium 6020B
8.8 ug/L7040416-21 4304-MW9 Lead 6020B
53 ug/L7040416-21 4304-MW9 Selenium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 5 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-01
Prism Work Order: 7040416
Time Collected: 04/18/17 00:00
Time Submitted: 04/21/17 16:40
4304-TB01
43-04
SWSL
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 4:13 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 4:13 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.079Chloromethane1<0.079
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 6 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-01
Prism Work Order: 7040416
Time Collected: 04/18/17 00:00
Time Submitted: 04/21/17 16:40
4304-TB01
43-04
SWSL
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 4:13 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 4:13 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 4:13 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 4:13 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124108 %4-Bromofluorobenzene
75-129102 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 7 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-02
Prism Work Order: 7040416
Time Collected: 04/18/17 13:30
Time Submitted: 04/21/17 16:40
4304-EB01
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:27 JABJug/L 0.030Mercury0.20.030
6020B P7E000411.0 5/3/17 19:43 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 19:43 BGMJug/L 0.12Barium1001.3
6020B P7E000411.0 5/3/17 19:43 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 19:43 BGMJug/L 0.081Chromium100.12
6020B P7E000412.0 5/3/17 19:43 BGMJug/L 0.061Lead100.81
6020B P7E000415.0 5/3/17 19:43 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 19:43 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 4:39 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 4:39 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 8 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-02
Prism Work Order: 7040416
Time Collected: 04/18/17 13:30
Time Submitted: 04/21/17 16:40
4304-EB01
43-04
SWSL
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 4:39 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 4:39 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 4:39 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 4:39 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124107 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12396 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 9 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-03
Prism Work Order: 7040416
Time Collected: 04/18/17 16:03
Time Submitted: 04/21/17 16:40
4304-MW10
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:38 JABug/L 0.030Mercury0.20.30
6020B P7E000411.0 5/3/17 20:01 BGMJug/L 0.45Arsenic100.55
6020B P7E000415.0 5/3/17 20:01 BGMug/L 0.12Barium10043
6020B P7E000411.0 5/3/17 20:01 BGMJug/L 0.053Cadmium10.064
6020B P7E000411.0 5/3/17 20:01 BGMJug/L 0.081Chromium100.44
6020B P7E000412.0 5/3/17 20:01 BGMJug/L 0.061Lead100.86
6020B P7E000415.0 5/3/17 20:01 BGMJug/L 0.45Selenium104.2
6020B P7E000415.0 5/3/17 20:01 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 10:43 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 10:43 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 10:43 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 10:43 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 10:43 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.079Chloromethane1<0.079
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 10 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-03
Prism Work Order: 7040416
Time Collected: 04/18/17 16:03
Time Submitted: 04/21/17 16:40
4304-MW10
43-04
SWSL
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 10:43 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 10:43 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7D050011.0 4/29/17 10:43 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 10:43 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 10:43 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 10:43 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 10:43 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 10:43 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124104 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12396 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 11 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-04
Prism Work Order: 7040416
Time Collected: 04/18/17 14:12
Time Submitted: 04/21/17 16:40
4304-MW11
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:42 JABug/L 0.030Mercury0.20.42
6020B P7E000411.0 5/3/17 20:07 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:07 BGMug/L 0.12Barium10051
6020B P7E000411.0 5/3/17 20:07 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:07 BGMJug/L 0.081Chromium100.27
6020B P7E000412.0 5/3/17 20:07 BGMJug/L 0.061Lead101.0
6020B P7E000415.0 5/3/17 20:07 BGMJug/L 0.45Selenium100.46
6020B P7E000415.0 5/3/17 20:07 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 11:09 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 11:09 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 11:09 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 11:09 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 11:09 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 12 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-04
Prism Work Order: 7040416
Time Collected: 04/18/17 14:12
Time Submitted: 04/21/17 16:40
4304-MW11
43-04
SWSL
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 11:09 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 11:09 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7D050011.0 4/29/17 11:09 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 11:09 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 11:09 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 11:09 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 11:09 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 11:09 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124105 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12397 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 13 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-05
Prism Work Order: 7040416
Time Collected: 04/18/17 18:52
Time Submitted: 04/21/17 16:40
4304-MW12
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:46 JABJug/L 0.030Mercury0.20.061
6020B P7E000411.0 5/3/17 20:14 BGMug/L 0.45Arsenic101.4
6020B P7E000415.0 5/3/17 20:14 BGMug/L 0.12Barium1009.5
6020B P7E000411.0 5/3/17 20:14 BGMJug/L 0.053Cadmium10.12
6020B P7E000411.0 5/3/17 20:14 BGMug/L 0.081Chromium101.8
6020B P7E000412.0 5/3/17 20:14 BGMJug/L 0.061Lead101.1
6020B P7E000415.0 5/3/17 20:14 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 20:14 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 18:28 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 18:28 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 18:28 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 18:28 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 18:28 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.079Chloromethane1<0.079
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 14 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-05
Prism Work Order: 7040416
Time Collected: 04/18/17 18:52
Time Submitted: 04/21/17 16:40
4304-MW12
43-04
SWSL
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 18:28 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 18:28 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 18:28 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 18:28 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 18:28 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 18:28 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 18:28 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 18:28 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124100 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-123100 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 15 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-06
Prism Work Order: 7040416
Time Collected: 04/19/17 08:50
Time Submitted: 04/21/17 16:40
4304-MW13
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:50 JABug/L 0.030Mercury0.2<0.030
6020B P7E000411.0 5/3/17 20:20 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:20 BGMug/L 0.12Barium1008.0
6020B P7E000411.0 5/3/17 20:20 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:20 BGMJug/L 0.081Chromium100.24
6020B P7E000412.0 5/3/17 20:20 BGMJug/L 0.061Lead100.50
6020B P7E000415.0 5/3/17 20:20 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 20:20 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 18:54 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 18:54 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 18:54 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 18:54 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 18:54 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 16 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-06
Prism Work Order: 7040416
Time Collected: 04/19/17 08:50
Time Submitted: 04/21/17 16:40
4304-MW13
43-04
SWSL
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 18:54 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 18:54 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 18:54 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 18:54 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 18:54 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 18:54 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 18:54 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 18:54 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124101 %4-Bromofluorobenzene
75-12999 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 17 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-07
Prism Work Order: 7040416
Time Collected: 04/19/17 09:47
Time Submitted: 04/21/17 16:40
4304-MW14
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:54 JABug/L 0.030Mercury0.2<0.030
6020B P7E000411.0 5/3/17 20:26 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:26 BGMug/L 0.12Barium10032
6020B P7E000411.0 5/3/17 20:26 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:26 BGMJug/L 0.081Chromium100.21
6020B P7E000412.0 5/3/17 20:26 BGMJug/L 0.061Lead100.63
6020B P7E000415.0 5/3/17 20:26 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 20:26 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 19:20 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 19:20 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 19:20 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 19:20 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 19:20 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 18 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-07
Prism Work Order: 7040416
Time Collected: 04/19/17 09:47
Time Submitted: 04/21/17 16:40
4304-MW14
43-04
SWSL
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 19:20 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 19:20 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 19:20 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 19:20 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 19:20 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 19:20 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 19:20 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 19:20 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124100 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 19 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-08
Prism Work Order: 7040416
Time Collected: 04/19/17 08:00
Time Submitted: 04/21/17 16:40
4304-MW16
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:58 JABug/L 0.030Mercury0.20.84
6020B P7E000411.0 5/3/17 20:32 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:32 BGMug/L 0.12Barium10062
6020B P7E000411.0 5/3/17 20:32 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:32 BGMJug/L 0.081Chromium100.23
6020B P7E000412.0 5/3/17 20:32 BGMJug/L 0.061Lead100.97
6020B P7E000415.0 5/3/17 20:32 BGMJug/L 0.45Selenium101.7
6020B P7E000415.0 5/3/17 20:32 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 19:46 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 19:46 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 19:46 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 19:46 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 19:46 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 20 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-08
Prism Work Order: 7040416
Time Collected: 04/19/17 08:00
Time Submitted: 04/21/17 16:40
4304-MW16
43-04
SWSL
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 19:46 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 19:46 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 19:46 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 19:46 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 19:46 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 19:46 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 19:46 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 19:46 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12497 %4-Bromofluorobenzene
75-12996 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 21 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-09
Prism Work Order: 7040416
Time Collected: 04/18/17 17:27
Time Submitted: 04/21/17 16:40
4304-MW17R
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:01 JABug/L 0.030Mercury0.2<0.030
6020B P7E000411.0 5/3/17 20:39 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:39 BGMug/L 0.12Barium100110
6020B P7E000411.0 5/3/17 20:39 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:39 BGMJug/L 0.081Chromium100.54
6020B P7E000412.0 5/3/17 20:39 BGMJug/L 0.061Lead101.2
6020B P7E000415.0 5/3/17 20:39 BGMJug/L 0.45Selenium101.3
6020B P7E000415.0 5/3/17 20:39 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 20:11 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 20:11 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 20:11 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 20:11 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 20:11 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 22 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-09
Prism Work Order: 7040416
Time Collected: 04/18/17 17:27
Time Submitted: 04/21/17 16:40
4304-MW17R
43-04
SWSL
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 20:11 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 20:11 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 20:11 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 20:11 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 20:11 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 20:11 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 20:11 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 20:11 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124102 %4-Bromofluorobenzene
75-129103 %Dibromofluoromethane
77-123102 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 23 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-10
Prism Work Order: 7040416
Time Collected: 04/18/17 15:07
Time Submitted: 04/21/17 16:40
4304-MW18
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:05 JABJug/L 0.030Mercury0.20.087
6020B P7E000411.0 5/3/17 20:45 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 20:45 BGMug/L 0.12Barium10062
6020B P7E000411.0 5/3/17 20:45 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:45 BGMJug/L 0.081Chromium100.17
6020B P7E000412.0 5/3/17 20:45 BGMJug/L 0.061Lead101.3
6020B P7E000415.0 5/3/17 20:45 BGMJug/L 0.45Selenium100.50
6020B P7E000415.0 5/3/17 20:45 BGMug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 20:37 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 20:37 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 20:37 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 20:37 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 20:37 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.079Chloromethane1<0.079
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 24 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-10
Prism Work Order: 7040416
Time Collected: 04/18/17 15:07
Time Submitted: 04/21/17 16:40
4304-MW18
43-04
SWSL
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 20:37 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 20:37 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 20:37 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 20:37 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 20:37 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 20:37 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 20:37 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 20:37 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12498 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-123101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 25 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-13
Prism Work Order: 7040416
Time Collected: 04/18/17 18:10
Time Submitted: 04/21/17 16:40
4304-SW1 (Exp)
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:24 JABJug/L 0.030Mercury0.20.038
6020B P7E000411.0 5/3/17 21:16 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:16 BGMug/L 0.12Barium10042
6020B P7E000411.0 5/3/17 21:16 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:16 BGMJug/L 0.081Chromium100.20
6020B P7E000412.0 5/3/17 21:16 BGMJug/L 0.061Lead100.63
6020B P7E000415.0 5/3/17 21:16 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 21:16 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 21:29 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 21:29 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 21:29 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 21:29 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 21:29 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 30 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-13
Prism Work Order: 7040416
Time Collected: 04/18/17 18:10
Time Submitted: 04/21/17 16:40
4304-SW1 (Exp)
43-04
SWSL
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 21:29 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 21:29 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 21:29 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 21:29 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 21:29 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 21:29 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 21:29 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 21:29 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12499 %4-Bromofluorobenzene
75-12999 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 31 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0500 - 5030B
Blank (P7D0500-BLK1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 48 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0500 - 5030B
Blank (P7D0500-BLK1)Prepared: 04/28/17 Analyzed: 04/29/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10954.6
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10452.1
ug/L 50.00 77-123Surrogate: Toluene-d8 9949.7
LCS (P7D0500-BS1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1-Dichloroethylene ug/L21.6 0.50 20.00 70-154108
Benzene ug/L22.6 0.50 20.00 77-128113
Chlorobenzene ug/L22.2 0.50 20.00 78-119111
Tetrahydrofuran ug/L24.1 10 20.00 70-130121
Toluene ug/L22.4 0.50 20.00 76-131112
Trichloroethylene ug/L21.9 0.50 20.00 77-133109
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10853.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10050.0
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
LCS Dup (P7D0500-BSD1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1-Dichloroethylene ug/L20.4 0.50 20.00 2070-154102 6
Benzene ug/L21.2 0.50 20.00 2077-128106 6
Chlorobenzene ug/L20.6 0.50 20.00 2078-119103 8
Tetrahydrofuran ug/L25.8 10 20.00 2070-130129 7
Toluene ug/L21.1 0.50 20.00 2076-131105 6
Trichloroethylene ug/L20.4 0.50 20.00 2077-133102 7
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10552.5
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 9447.2
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 49 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0039 - 5030B
Blank (P7E0039-BLK1)Prepared & Analyzed: 05/02/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 50 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0039 - 5030B
Blank (P7E0039-BLK1)Prepared & Analyzed: 05/02/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10552.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.6
ug/L 50.00 77-123Surrogate: Toluene-d8 10150.7
LCS (P7E0039-BS1)Prepared & Analyzed: 05/02/17
1,1-Dichloroethylene ug/L18.8 0.50 20.00 70-15494
Benzene ug/L21.0 0.50 20.00 77-128105
Chlorobenzene ug/L21.4 0.50 20.00 78-119107
Tetrahydrofuran ug/L19.7 10 20.00 70-13099
Toluene ug/L21.1 0.50 20.00 76-131106
Trichloroethylene ug/L20.1 0.50 20.00 77-133101
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10251.1
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
LCS Dup (P7E0039-BSD1)Prepared & Analyzed: 05/02/17
1,1-Dichloroethylene ug/L17.9 0.50 20.00 2070-15489 5
Benzene ug/L20.1 0.50 20.00 2077-128100 4
Chlorobenzene ug/L20.3 0.50 20.00 2078-119102 5
Tetrahydrofuran ug/L19.8 10 20.00 2070-13099 0.2
Toluene ug/L20.2 0.50 20.00 2076-131101 4
Trichloroethylene ug/L19.3 0.50 20.00 2077-13397 4
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10351.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 51 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0056 - 5030B
Blank (P7E0056-BLK1)Prepared & Analyzed: 05/03/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 52 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0056 - 5030B
Blank (P7E0056-BLK1)Prepared & Analyzed: 05/03/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10250.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10150.5
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
LCS (P7E0056-BS1)Prepared & Analyzed: 05/03/17
1,1-Dichloroethylene ug/L17.5 0.50 20.00 70-15488
Benzene ug/L20.6 0.50 20.00 77-128103
Chlorobenzene ug/L21.0 0.50 20.00 78-119105
Tetrahydrofuran ug/L19.8 10 20.00 70-13099
Toluene ug/L20.9 0.50 20.00 76-131105
Trichloroethylene ug/L20.4 0.50 20.00 77-133102
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9848.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.9
ug/L 50.00 77-123Surrogate: Toluene-d8 9949.5
LCS Dup (P7E0056-BSD1)Prepared & Analyzed: 05/03/17
1,1-Dichloroethylene ug/L16.8 0.50 20.00 2070-15484 4
Benzene ug/L19.6 0.50 20.00 2077-12898 5
Chlorobenzene ug/L19.9 0.50 20.00 2078-11999 5
Tetrahydrofuran ug/L19.2 10 20.00 2070-13096 3
Toluene ug/L20.0 0.50 20.00 2076-131100 5
Trichloroethylene ug/L19.3 0.50 20.00 2077-13397 5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10050.2
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.6
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.0
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 53 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0089 - 5030B
Blank (P7E0089-BLK1)Prepared & Analyzed: 05/06/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 54 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0089 - 5030B
Blank (P7E0089-BLK1)Prepared & Analyzed: 05/06/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9647.9
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10050.1
ug/L 50.00 77-123Surrogate: Toluene-d8 9849.0
LCS (P7E0089-BS1)Prepared & Analyzed: 05/06/17
1,1-Dichloroethylene ug/L22.1 0.50 20.00 70-154110
Benzene ug/L20.7 0.50 20.00 77-128104
Chlorobenzene ug/L20.6 0.50 20.00 78-119103
Tetrahydrofuran ug/L18.4 10 20.00 70-13092
Toluene ug/L20.4 0.50 20.00 76-131102
Trichloroethylene ug/L21.4 0.50 20.00 77-133107
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9748.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10150.5
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
LCS Dup (P7E0089-BSD1)Prepared & Analyzed: 05/06/17
1,1-Dichloroethylene ug/L21.0 0.50 20.00 2070-154105 5
Benzene ug/L19.8 0.50 20.00 2077-12899 5
Chlorobenzene ug/L20.0 0.50 20.00 2078-119100 3
Tetrahydrofuran ug/L17.2 10 20.00 2070-13086 7
Toluene ug/L19.5 0.50 20.00 2076-13197 5
Trichloroethylene ug/L20.0 0.50 20.00 2077-133100 7
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9648.2
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.7
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 55 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals - Quality Control
Batch P7E0004 - 3005A
Blank (P7E0004-BLK1)Prepared: 05/01/17 Analyzed: 05/03/17
Arsenic ug/LBRL1.0
Barium ug/L0.622 5.0 J
Cadmium ug/LBRL1.0
Chromium ug/LBRL1.0
Lead ug/L0.660 1.0 Aa, J
Selenium ug/LBRL5.0
Silver ug/L0.0670 5.0 CCV, J
LCS (P7E0004-BS1)Prepared: 05/01/17 Analyzed: 05/03/17
Arsenic ug/L1091.0 100.0 80-120109
Barium ug/L1025.0 100.0 80-120102
Cadmium ug/L1091.0 100.0 80-120109
Chromium ug/L99.4 1.0 100.0 80-12099
Lead ug/L1111.0 100.0 80-120111
Selenium ug/L1055.0 100.0 80-120105
Silver ug/L1225.0 100.0 CCV, LH80-120122
Matrix Spike (P7E0004-MS1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L1121.0 100.0 BRL 75-125112
Barium ug/L1055.0 100.0 1.27 75-125104
Cadmium ug/L1111.0 100.0 BRL 75-125111
Chromium ug/L1031.0 100.0 0.118 75-125102
Lead ug/L1151.0 100.0 0.812 75-125114
Selenium ug/L1055.0 100.0 BRL 75-125105
Silver ug/L1265.0 100.0 BRL CCV, M75-125126
Matrix Spike Dup (P7E0004-MSD1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L1061.0 100.0 BRL 2075-125106 5
Barium ug/L1005.0 100.0 1.27 2075-12599 5
Cadmium ug/L1071.0 100.0 BRL 2075-125107 4
Chromium ug/L97.6 1.0 100.0 0.118 2075-12598 5
Lead ug/L1101.0 100.0 0.812 2075-125109 4
Selenium ug/L1015.0 100.0 BRL 2075-125101 4
Silver ug/L1215.0 100.0 BRL 20 CCV75-125121 4
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 56 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals - Quality Control
Batch P7E0004 - 3005A
Post Spike (P7E0004-PS1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L100 100.0 0.122 80-120100
Barium ug/L99.3 100.0 1.27 80-12098
Cadmium ug/L102 100.0 0.00100 80-120102
Chromium ug/L93.1 100.0 0.118 80-12093
Lead ug/L106 100.0 0.812 80-120105
Selenium ug/L94.3 100.0 0.176 80-12094
Silver ug/L109 100.0 0.0410 CCV80-120109
Batch P7E0008 - 7470A
Blank (P7E0008-BLK1)Prepared: 05/01/17 Analyzed: 05/02/17
Mercury ug/LBRL0.20
LCS (P7E0008-BS1)Prepared: 05/01/17 Analyzed: 05/02/17
Mercury ug/L9.51 0.20 9.375 80-120101
Matrix Spike (P7E0008-MS1)Prepared: 05/01/17 Analyzed: 05/02/17 Source: 7040416-02
Mercury ug/L9.27 0.20 9.375 BRL 80-12099
Matrix Spike Dup (P7E0008-MSD1)Prepared: 05/01/17 Analyzed: 05/02/17 Source: 7040416-02
Mercury ug/L8.97 0.20 9.375 BRL 2080-12096 3
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 57 of 61
Sample Extraction Data
Prep Method: 3005A
Lab Number Batch Date/TimeInitialFinal
P7E00047040416-02 05/01/17 8:155050mLmL
P7E00047040416-03 05/01/17 8:155050mLmL
P7E00047040416-04 05/01/17 8:155050mLmL
P7E00047040416-05 05/01/17 8:155050mLmL
P7E00047040416-06 05/01/17 8:155050mLmL
P7E00047040416-07 05/01/17 8:155050mLmL
P7E00047040416-08 05/01/17 8:155050mLmL
P7E00047040416-09 05/01/17 8:155050mLmL
P7E00047040416-10 05/01/17 8:155050mLmL
P7E00047040416-11 05/01/17 8:155050mLmL
P7E00047040416-12 05/01/17 8:155050mLmL
P7E00047040416-13 05/01/17 8:155050mLmL
P7E00047040416-14 05/01/17 8:155050mLmL
P7E00047040416-15 05/01/17 8:155050mLmL
P7E00047040416-16 05/01/17 8:155050mLmL
P7E00047040416-17 05/01/17 8:155050mLmL
P7E00047040416-18 05/01/17 8:155050mLmL
P7E00047040416-19 05/01/17 8:155050mLmL
P7E00047040416-20 05/01/17 8:155050mLmL
P7E00047040416-21 05/01/17 8:155050mLmL
Prep Method: 7470A
Lab Number Batch Date/TimeInitialFinal
P7E00087040416-02 05/01/17 9:452030mLmL
P7E00087040416-03 05/01/17 9:452030mLmL
P7E00087040416-04 05/01/17 9:452030mLmL
P7E00087040416-05 05/01/17 9:452030mLmL
P7E00087040416-06 05/01/17 9:452030mLmL
P7E00087040416-07 05/01/17 9:452030mLmL
P7E00087040416-08 05/01/17 9:452030mLmL
P7E00087040416-09 05/01/17 9:452030mLmL
P7E00087040416-10 05/01/17 9:452030mLmL
P7E00087040416-11 05/01/17 9:452030mLmL
P7E00087040416-12 05/01/17 9:452030mLmL
P7E00087040416-13 05/01/17 9:452030mLmL
P7E00087040416-14 05/01/17 9:452030mLmL
P7E00087040416-15 05/01/17 9:452030mLmL
P7E00087040416-16 05/01/17 9:452030mLmL
P7E00087040416-17 05/01/17 9:452030mLmL
P7E00087040416-18 05/01/17 9:452030mLmL
P7E00087040416-19 05/01/17 9:452030mLmL
P7E00087040416-20 05/01/17 9:452030mLmL
P7E00087040416-21 05/01/17 9:452030mLmL
Prep Method: 5030B
Lab Number Batch Date/TimeInitialFinal
P7D05007040416-01 04/28/17 14:121010mLmL
P7D05007040416-02 04/28/17 14:121010mLmL
P7D05007040416-03 04/28/17 14:121010mLmL
P7D05007040416-04 04/28/17 14:121010mLmL
P7E00397040416-05 05/02/17 10:091010mLmL
P7E00397040416-06 05/02/17 10:091010mLmL
P7E00397040416-07 05/02/17 10:091010mLmL
P7E00397040416-08 05/02/17 10:091010mLmL
P7E00397040416-09 05/02/17 10:091010mLmL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 58 of 61
Sample Extraction Data
Prep Method: 5030B
Lab Number Batch Date/TimeInitialFinal
P7E00397040416-10 05/02/17 10:091010mLmL
P7E00397040416-11 05/02/17 10:091010mLmL
P7E00567040416-12 05/03/17 10:351010mLmL
P7E00397040416-13 05/02/17 10:091010mLmL
P7E00567040416-14 05/03/17 10:351010mLmL
P7E00567040416-15 05/03/17 10:351010mLmL
P7E00567040416-16 05/03/17 10:351010mLmL
P7E00897040416-17 05/06/17 15:451010mLmL
P7E00897040416-18 05/06/17 15:451010mLmL
P7E00897040416-19 05/06/17 15:451010mLmL
P7E00897040416-20 05/06/17 15:451010mLmL
P7E00897040416-21 05/06/17 15:451010mLmL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 59 of 61
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