4304_CentralCarolinaTire_Phase1and2_April2017_1stSemiAnnual_DIN27783_20170512

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]

May 12, 2017

Ms. Elizabeth S. Werner, Hydrogeologist
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646

RE: Report of Results
Semi-Annual Groundwater and Surface Water Monitoring: April 2017
Central Carolina Tire Monofill Landfill Phase I/II
Cameron, Harnett County, NC
Permit # 43-04

Dear Ms. Werner:

This report presents the results of semi-annual groundwater and surface water quality
monitoring conducted at the landfill site referenced above (Figure 1) on April 19, 2017. The
scope of work performed included sampling and laboratory analysis of groundwater samples
from eight on-site monitoring wells (MW-2 through MW-9) and surface water samples from two
on-site locations (SW-1 and SW-2). The groundwater and surface water samples were
collected in accordance with the NCDEQ, Division of Waste Management (DWM), Solid Waste
Section (SWS), Groundwater Monitoring Guidance Document, and the facility Water Quality
Monitoring Plan. The sampling and data collection methods, as well as the current and
historical results of field and laboratory testing of the water samples, are presented in the
following sections.

1.0 POTENTIOMETRIC PATTERN AND GROUNDWATER FLOW

Groundwater levels were gauged in the site groundwater monitoring wells on April 19, 2017 as
part of the site monitoring. Depths to groundwater were measured using an electronic water
level probe that was thoroughly decontaminated between wells with a non-phosphate soap and
water wash followed in order by multiple rinses with distilled water, an isopropyl alcohol rinse,
and multiple distilled water rinses. Depth to groundwater measurements were made after the
wells were opened for a sufficient period of time to allow water levels to equilibrate with
atmospheric pressure. The locations of the site monitoring wells are depicted in Figure 2.
Groundwater elevation data collected at the monitoring wells on April 19, 2017 are presented in
Table 1. The depth to groundwater across the site, relative to the top of the PVC casing of the
– 2 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
monitoring wells, ranged from 4.37 feet at MW-4 to 22.84 feet at MW-9, which is consistent with
the surface topography.

A water-table elevation contour map that was developed based on the April 19, 2017
groundwater-gauging data for the Type II monitoring wells is presented as Figure 3. The
pattern of the water-table contours indicates that the horizontal component of shallow
groundwater flow at the site is generally to the east-southeast, which is consistent with the
surface topography and drainage features at the site. The average hydraulic gradient of the
water table, based on the data depicted in Figure 3, ranges from approximately 0.032 ft./ft. in
west-southwest portion of the site to approximately 0.018 ft./ft. in the east-northeast portion of
the site.

2.0 RESULTS OF GROUNDWATER AND SURFACE WATER SAMPLING AND ANALYSIS

Groundwater samples were collected from the site monitoring wells and surface water samples
were collected from two on-site locations on April 19, 2017 for laboratory analysis to monitor the
quality of groundwater and surface water at the site. The groundwater and surface water
samples were collected and handled in accordance with the sampling protocols included in the
site Water Quality Monitoring Plan as well as the SWS Groundwater Monitoring Guidance
Document. It is noted that monitoring well MW-9 serves as the upgradient, natural background
well for the facility, and monitoring wells MW-2 through MW-7 serve as the downgradient
monitoring wells. Monitoring well MW-8 is located immediately north of the landfill. Based on its
location relative to the groundwater elevation contours, MW-8 is located hydraulically cross-
gradient to the northern-most area of the landfill and hydraulically up gradient of most of the
landfill area. All reusable sampling equipment was properly decontaminated between sampling
locations with a non-phosphate soap and water wash, followed by multiple rinses with distilled
water. New disposable nitrile or latex gloves were worn during all sampling activities.
Disposable sampling equipment/material was discarded after each use.

Prior to groundwater sampling, all monitoring wells were purged using pre-cleaned Teflon-lined
disposable polyethylene tubing connected to a peristaltic pump under low flow conditions.
During purging, measurements were made in the field of the pH, temperature, specific
conductance and turbidity of the groundwater collected from the monitoring wells, in accordance
with SWS requirements. The results of the field analyses of these parameters are presented in
Table 1. Copies of Groundwater Sampling Forms containing pertinent information recorded in
the field during purging and sampling at each groundwater monitoring well are presented in
Appendix A. The results of the field-measured water-quality parameters indicate that the
values measured in groundwater collected from the site monitoring wells were within the
applicable stabilization criteria (see Groundwater Sampling Forms). Groundwater at the site is
acidic to slightly acidic based on the pH values measured in the field (3.45 to 5.81). Specific
– 3 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
conductance values ranged from 57 (MW-5) to 443 (MW-9) µS/cm. Turbidity values ranged
from 2.6 (MW-7) to 8.7 (MW-5) nephelometric turbidity units (NTUs).

Surface water samples were collected from locations SW-1 and SW-2. The sampling locations
are depicted in Figure 2. SW-1 is located approximately 140-feet south-southeast of the south-
central sedimentation pond and within the drainage feature that parallels the southern limits of
scrap tire disposal within the Phase I/II landfill. SW-2 is located approximately 250-feet south-
southeast of the southeastern sedimentation pond and within the primary drainage feature that
parallels the eastern limits of the Phase I/II landfill. The surface water samples from SW-1 and
SW-2 were collected in accordance with the protocol presented in the SWS Groundwater
Monitoring Guidance Document.

All groundwater and surface water samples were analyzed at a North Carolina-certified
laboratory for Appendix I volatile organic compounds (VOCs) by SW 846 Method 8260 and the
8 RCRA metals by EPA 6000/7000 series methods. Summarized results of laboratory analyses
for groundwater and surface water samples collected from the site on April 19, 2017 are
presented in Table 2. Summarized historical groundwater and surface water quality data for the
site are presented in Table 3. Copies of the original laboratory reports are included in
Appendix B.

The laboratory analytical results for surface water samples SW-1 and SW-2 indicate that no
Appendix I VOCs were reported in either sample. Low levels of various RCRA metals were
reported in both surface water samples. The estimated concentration of silver reported for the
surface water sample collected from sampling location SW-2 (0.073 µg/L) slightly exceeds the
15A NCAC 2B surface water quality standard for fresh water aquatic life (0.06 µg/L). None of
the reported concentrations of the remaining metals in either surface water sample exceed the
corresponding 15A NCAC 2B surface water quality standards.

The laboratory analytical results for the groundwater samples collected from the site monitoring
wells on April 19, 2017 indicate that tetrachloroethene (PCE) was reported at a concentration of
2.5 µg/L in the groundwater sample collected from MW-8, which exceeds the 15A NCAC 2L
.0202 groundwater quality standard of 0.70 µg/L. It is noted that the results of a preliminary site
assessment conducted in November 2010, as well as Phase 2, 3 and 4 site assessments
conducted in April and May 2012, April 2013, and August 2014, respectively, indicate that the
source of PCE in groundwater at MW-8 is unrelated to the Phase I/II landfill and is located in the
vicinity of the maintenance shelter north of MW-8. No other Appendix I VOCs were reported in
any of the groundwater samples.

The results of the metals analyses of the groundwater samples indicate that arsenic was
reported in four of the samples, barium, chromium and lead were reported in all of the samples,
cadmium was reported in one of the samples, mercury was reported in six of the samples,
– 4 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
selenium was reported in five of the groundwater samples, and silver was not reported in any of
the samples. It is noted that barium, chromium, lead and mercury were also reported in the
equipment blank. Further, selenium was reported at a concentration of 53 µg/L in the
groundwater sample collected from monitoring well MW-9, which exceeds the 15A NCAC 2L
.0202 groundwater quality standard of 20 µg/L. The April 2017 monitoring event is the only one
in which selenium was detected at a concentration exceeding the groundwater quality standard
in over 10 years of monitoring, and the result is therefore considered a data outlier. None of the
reported concentrations of the remaining metals in any of the groundwater samples exceed the
corresponding 15A NCAC 2L .0202 groundwater quality standards.

3.0 CONCLUSIONS AND RECOMMENDATIONS

The results of the April 19, 2017 groundwater and surface water quality monitoring conducted at
the Central Carolina Tire Monofill Landfill Phase I/II are generally consistent with the results of
previous monitoring conducted at the site. No Appendix I VOCs were reported in either surface
water sample. Low levels of various RCRA metals were reported in both surface water
samples. The estimated concentration of silver reported for the surface water sample collected
from sampling location SW-2 (0.073 µg/L) slightly exceeds the 15A NCAC 2B surface water
quality standard for fresh water aquatic life (0.06 µg/L). Silver has rarely been detected in
surface water samples collected from sampling location SW-2 in over 10 years of sampling, and
has only been reported twice in the last seven years of monitoring. Therefore, the reported
concentration of silver in excess of the 15A NCAC 2B surface water quality standard for fresh
water aquatic life in sample SW-2 is considered a data outlier. None of the reported
concentrations of the remaining metals in either surface water sample exceed the
corresponding 15A NCAC 2B surface water quality standards.

Tetrachloroethene (PCE) was reported at a concentration of 2.5 µg/L in the groundwater sample
collected from MW-8, which exceeds the 15A NCAC 2L .0202 groundwater quality standard of
0.70 µg/L. The results of a preliminary site assessment conducted in November 2010, as well
as Phase 2, 3 and 4 site assessments conducted in April and May 2012, April 2013, and August
2014, respectively, indicate that the source of PCE in groundwater at MW-8 is unrelated to the
Phase I/II landfill and is located in the vicinity of the maintenance shelter north of MW-8. No
other Appendix I VOCs were reported in any of the groundwater samples. Selenium was
reported at a concentration of 53 µg/L in the groundwater sample collected from monitoring well
MW-9, which exceeds the 15A NCAC 2L .0202 groundwater quality standard of 20 µg/L. The
April 2017 monitoring event is the only one in which selenium was detected at a concentration
exceeding the groundwater quality standard in over 10 years of monitoring, and the result is
therefore considered a data outlier. None of the reported concentrations of the remaining
metals in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202
groundwater quality standards.

– 5 – May 12, 2017
11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
The results of a preliminary site assessment conducted in November 2010, as well as Phase 2,
3 and 4 site assessments conducted in April and May 2012, April 2013, and August 2014,
respectively, indicate that the source of PCE in groundwater at MW-8 is unrelated to the Phase
I/II landfill and is located in the vicinity of the maintenance shelter located north of MW-8. The
results of the preliminary site assessment are reported in the January 2011 Preliminary Site
Assessment Report, the results of the second phase of assessment are reported in the June
2012 Phase 2 Hydrogeologic and Groundwater Quality Assessment Report, the results of the
third phase of assessment are reported in the May 2013 Phase 3 Hydrogeologic and
Groundwater Quality Assessment Report, and the results of the Phase 4 site assessment are
reported in the October 2014 Phase 4 Hydrogeologic and Groundwater Quality Assessment
Report, all of which were previously submitted to the NCDENR Solid Waste Section.

Based on the results of the April 19, 2017 monitoring event, it is recommended that semiannual
detection groundwater monitoring continue without modification. If you have any questions or
require further assistance regarding this report, please call me at 919-995-0363. The next water
quality monitoring event for the Central Carolina Tire Monofill Landfill is scheduled for October
2017.

Sincerely,
Nautilus Geologic Consulting, PLLC
Brian S. Boutin, P.G.
Consulting Geologist

Cc: Tim McNeil, Central Carolina Holdings, Inc.
Vance Moore, Garrett and Moore, Inc.
Craig Fortner, Garrett & Moore, Inc.
Drawn by: Reviewed by: Drawing #:
Drawing Date: 1
SITE LOCATION MAP
Central Carolina Tire Monofill Landfill
Harnett County, North Carolina
Source: USGS 7.5’ Topographic Quadrangle Series
Murchisontown, NC 2010
Figure No. Project #:
Scale: USGS
1:24,000 05/31/2012
N
11112 Branding Iron Place Wendell, NC 27591
Office: [phone]
Cell: [phone]
Central Carolina Tire
MW-2 20.0 2.0 309.30 5.28 304.02 19.3 4.12 72 6.2
MW-3 20.0 2.0 315.20 9.76 305.44 18.0 4.58 98 6.2
MW-4 20.0 2.0 320.80 4.37 316.43 17.9 4.98 91 6.4
MW-5 20.0 2.0 322.40 4.64 317.76 23.7 5.28 57 8.7
MW-6 25.0 2.0 305.10 6.77 298.33 24.4 5.81 197 8.2
MW-7 20.0 2.0 315.80 6.02 309.78 21.0 3.78 67 2.6
MW-8 20.0 2.0 342.80 6.73 336.07 17.6 3.80 61 6.9
MW-9 30.0 2.0 378.70 22.84 355.86 17.8 3.45 443 3.3
Notes:
MSL = Mean Sea Level
BTOC = Below Top of Casing
Monitoring well construction data taken from October-December 2006 Sampling Event Monitoring Report prepared by Withers & Ravenel.
Well Diameter
(Inches)
Field Parameters
Turbidity
(ntu)
Top of Casing
Elevation
(Feet MSL)
Groundwater
Elevation
(Feet MSL)
Depth to
Groundwater
(Feet BTOC)
Monitoring Well and Groundwater Data
Table 1
April 2017 Sampling Event
Central Carolina Tire Monofill Landfill Phase I/II
Harnett County, North Carolina
Well
Identity
ntu = Nephelometric Turbidity Units
Temp. Co
Well Depth
(Feet BGS)
BGS = Below Ground Surface
GW = Groundwater
April 19, 2017
pH S.C.
umhos/cm
S.C. = Specific Conductance
Permit # 43-04
ORGANIC CONSTITUENTS GWP Std NCAC 2L STD
(ug/L)(ug/L)(ug/L)
Acetone ND ND ND ND ND ND ND ND ND ND NE 6000
Acrylonitrile ND ND ND ND ND ND ND ND ND ND NE NE
Benzene ND ND ND ND ND ND ND ND ND ND NE 1
Bromochloromethane ND ND ND ND ND ND ND ND ND ND 0.6 NE
Bromodichloromethane ND ND ND ND ND ND ND ND ND ND NE 0.6
Bromoform (Tribromoethane)ND ND ND ND ND ND ND ND ND ND NE 4
Bromomethane (Methyl Bromide)ND ND ND ND ND ND ND ND ND ND 10 10
2-Butanone (MEK), (Methyl Ethyl Ketone)ND ND ND ND ND ND ND ND ND ND NE 4000
Carbon Disulfide ND ND ND ND ND ND ND ND ND ND NE 700
Carbon Tetrachloride ND ND ND ND ND ND ND ND ND ND NE 0.3
Chlorobenzene ND ND ND ND ND ND ND ND ND ND NE 50
Chloroethane (Ethyl Chloride)ND ND ND ND ND ND ND ND ND ND NE 3000
Chloroform (Trichloromethane)ND ND ND ND ND ND ND ND ND ND NE 70
1,2-Dibromo-3-Chloropropane (DBCP)ND ND ND ND ND ND ND ND ND ND NE 0.04
Dibromochloromethane (Chlorodibromomethane)ND ND ND ND ND ND ND ND ND ND 0.41 0.4
1,2,-Dibromoethane (Ethylene Dibromide)ND ND ND ND ND ND ND ND ND ND NE 0.02
Dibromomethane (Methylene Bromide)ND ND ND ND ND ND ND ND ND ND 5.5 70
1,2-Dichlorobenzene (O-Dichlorobenzene)ND ND ND ND ND ND ND ND ND ND NE 20
1,3-Dichlorobenzene (M-Dichlorobenzene)ND ND ND ND ND ND ND ND ND ND NE 200
1,4-Dichlorobenzene (P-Dichlorobenzene)ND ND ND ND ND ND ND ND ND ND NE 6
Trans-1,4-Dichloro-2-butene ND ND ND ND ND ND ND ND ND ND NE NE
1,1-Dichloroethane ND ND ND ND ND ND ND ND ND ND NE 6
1,2-Dichloroethane (Ethylene Dichloride)ND ND ND ND ND ND ND ND ND ND NE 0.4
1,1-Dichloroethene (Vinylidene Chloride)ND ND ND ND ND ND ND ND ND ND NE 7
1,2-Dichloroethene (cis and trans isomers)ND ND ND ND ND ND ND ND ND ND 60 60
1,2-Dichloropropane (Propylene Dichloride)ND ND ND ND ND ND ND ND ND ND NE 0.6
1,1-Dichloropropene ND ND ND ND ND ND ND ND ND ND NE NE
1,3-Dichloropropene (cis and trans isomers)ND ND ND ND ND ND ND ND ND ND NE 0.4
Ethylbenzene ND ND ND ND ND ND ND ND ND ND NE 600
Iodomethane (Methyl Iodide)ND ND ND ND ND ND ND ND ND ND NE NE
2-Hexanone (Methyl Butyl Ketone)ND ND ND ND ND ND ND ND ND ND NE 40
Methyl Chloride (Chloromethane)ND ND ND ND ND ND ND ND ND ND NE 3
Methylene Chloride (Dichloromethane)ND ND ND ND ND ND ND ND ND ND NE 5
4-Methyl-2-Pentanone (Methyl Isobutyl Ketone)ND ND ND ND ND ND ND ND ND ND 560 NE
Styrene ND ND ND ND ND ND ND ND ND ND NE 70
1,1,1,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND ND 1 1
1,1,2,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND ND 0.18 0.2
Tetrachloroethene (Tetrachloroethylene), (PCE)ND ND ND ND ND ND ND ND 2.5 ND NE 0.7
Toluene ND ND ND ND ND ND ND ND ND ND NE 600
1,1,1-Trichloroethane (Methylchloroform)ND ND ND ND ND ND ND ND ND ND NE 200
1,1,2-Trichloroethane ND ND ND ND ND ND ND ND ND ND 0.6 0.6
Trichloroethene (Trichloroethylene), (TCE)ND ND ND ND ND ND ND ND ND ND NE 3
Trichlorofluoromethane (CFC-11) ND ND ND ND ND ND ND ND ND ND NE 2000
1,2,3-Trichloropropane ND ND ND ND ND ND ND ND ND ND NE 0.005
Vinyl Acetate ND ND ND ND ND ND ND ND ND ND 88 88
Vinyl Chloride ND ND ND ND ND ND ND ND ND ND NE 0.03
Total Xylenes ND ND ND ND ND ND ND ND ND ND NE 500
INORGANIC CONSTITUENTS GWP Std NCAC 2L STD
(in ug/L)(ug/L)(ug/L)
Arsenic 0.64 J ND ND 0.63 J 0.45 J ND 1.5 ND ND 8.3 NE 10
Barium 24 B 25 B 82 B 28 B 21 B 12 B 46 B 63 B 39 B 400 B NE 700
Cadmium ND 0.12 J ND ND ND ND ND ND ND 0.25 J NE 2
Chromium 0.58 JB 0.34 JB 0.29 JB 0.32 JB 0.33 JB 0.18 JB 0.22 JB 0.17 JB 0.20 JB 0.62 JB NE 10
Lead 0.82 JB 0.34 JB 1.8 JB 0.96 JB 0.96 JB 0.71 JB 0.93 JB 2.2 B 1.1 JB 8.8 B NE 15
Mercury 0.074 JB 0.045 JB 0.053 JB 0.053 JB 0.038 JB 0.043 JB 0.043 JB ND ND 0.21 B NE 1
Selenium ND ND 1.1 J 0.80 J ND ND 0.58 J ND 0.99J 53 NE 20
Silver ND 0.073 J ND ND ND ND ND ND ND ND NE 20
Notes:
Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standard for Class GA groundwater.J = Estimated value above laboratory method detection limit and below SWSL or reporting limit.
NCAC 2L STD = North Carolina Groundwater Standard established in Title 15A of North Carolina Administrative Code Subchapter 2L B = Analyte found in associated field and/or laboratory blank.
GWP Std = Solid Waste Section Groundwater Protection Standard
ND = None detected above laboratory method detection limit.
Table 2
SW-1 SW-2 MW-5 MW-6
Central Carolina Tire Monofill Landfill Phase I/II, Harnett County, NCPermit # 43-04
MW-4
April 2017 Sampling Event
MW-7
NS = Not Sampled, No sample exists for this sampling period
MW-8MW-3
Laboratory Results for Surface Water and Groundwater Samples
MW-9MW-2
April 19, 2017
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-2Arsenic 10 ND ND ND 2.43 JB ND ND ND ND ND ND ND ND 0.80 J ND 0.55 J 0.73 J ND ND ND ND 0.39 J ND ND NDBarium70017015211092.1 JB 162.0 97.5 JB 86.7 JB 115 B 73.4 JB 110.0 69.0 94.0 81.0 95.0 87.0 88.0 74.0 97.0 68.0 90.0 76.0 87.0 75 82 B
Cadmium 2 ND ND ND ND ND ND ND ND 0.29 J 0.18 J 10.00 0.93 J ND ND 0.46 J 0.20 J 0.22 J 0.050 J 0.077 J ND 0.081 J 0.11 J 0.067J ND
Chromium 10 ND ND ND 4.58 JB 3.11 J 2.03 JB 1.77 JB 2.91 JB 2.67 JB ND 1.5 J ND 6.10 ND 2.3 B 0.83 JB ND ND 0.76 J 1.50 2.70 0.87 J ND 0.29 JB
Lead 15 ND ND ND 1.09 J 3.97 J ND ND 4.82 J ND 1.6 J 0.68 J ND 0.45 J ND 0.73 J 1.10 1.60 1.30 1.20 1.20 2.50 1.50 1.1 1.8 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.053 JB
Selenium 20 ND ND ND 3.98 J ND 8.75 J ND ND ND 3.3 J ND ND 2.60 3.30 3.30 2.30 0.45 J 0.66 J ND ND 1.60 1.40 0.68 J 1.1 JSilver20NDNDNDNDND2.36 JB 3.57 JB 1.16 JB 1.25 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.015 J ND ND1,4-Dichlorobenzene 6 ND ND ND ND ND ND ND ND 0.23 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND ND ND ND ND ND 0.160 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Toluene 600 ND ND ND ND ND ND 0.260 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND ND ND 0.390 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-3Arsenic 10 ND ND 3.3 J 3.39 JB ND ND ND ND ND ND 0.92 J ND 2.10 3.20 2.40 2.70 0.98 J 0.39 J 0.95 J 0.88 J 2.00 1.00 0.65 J 0.63 JBarium700ND30.5 34.1 20.0 JB 38.4 J 25.5 JB 28.6 JB 29.5 JB 41.2 JB 31.0 39.0 37.0 44.0 40.0 50.0 39.0 42.0 16.0 33.0 22.0 53.0 26.0 17 28 B
Cadmium 2 1 ND ND ND ND ND ND ND ND ND 2.40 ND ND ND ND ND 0.11 J 0.034 J ND ND 0.079 J 0.077 J 0.20 J ND
Chromium 10 ND ND ND 5.06 JB 1.69 J 2.62 JB 2.62 JB 4.29 JB 2.95 JB ND 1.5 J ND 4.80 ND 2.3 B 0.70 JB ND ND ND 1.40 0.72 J ND 0.66 J 0.32 JB
Lead 15 ND ND ND 1.31 J 3.60 J ND 3.77 J 5.60 J 7.01 J 0.97 J 1.9 J 1.2 J 2.30 1.70 2.70 1.10 1.20 0.20 J 0.39 J 0.40 J 2.00 0.45 J 0.33 J 0.96 JB
Mercury 1 ND ND ND 0.038 J 0.133 J 0.064 J 0.090 J 0.089 J 0.36 0.056 J ND 0.19 J ND 0.21 ND ND ND ND 0.035 J 0.025 J ND ND ND 0.053 JBSelenium20NDNDND5.79 J ND 9.5 J ND ND ND ND 7.60 ND 9.20 11.00 13.00 9.60 3.50 0.93 J 3.60 2.80 9.00 3.80 2.3 0.80 JSilver20NDNDNDNDND2.27 JB 3.74 JB 1.60 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 0.011 J ND NDAcetone6000NDNDNDNDNDNDNDND32.3 J ND ND ND ND 2.7 J ND ND ND ND ND ND ND ND 4.9 J ND
Benzene 1 ND ND ND ND 0.610 J ND ND 0.260 J 0.55 J ND ND ND 0.76 0.51 0.85 ND ND ND ND ND 0.84 ND ND ND
Bromomethane 10 ND ND ND ND ND ND ND ND ND ND ND 1.0 ND ND ND ND ND ND ND ND ND ND ND ND
4-Methyl-2-Pentanone 560 ND ND 0.97 J ND ND ND ND ND 2.8 J 0.56 J 0.89 J ND 0.97 J ND 4.8 J ND ND 1.2 J 5 ND 0.85 J ND ND ND
1,1-Dichloroethane 6 ND ND ND 0.270 J 0.620 J ND ND 0.280 J 0.47 J ND ND ND 0.67 0.47 0.67 ND ND ND ND ND 0.51 ND ND ND1,2-Dichloroethene (isomers)60 ND 1.5 1.7 0.760 J 2.04 J ND 0.230 J 0.660 J 1.21 J 0.53 J 0.84 0.59 2 1.0 2.2 0.7 0.83 ND ND ND 1.40 ND ND NDMethylene Chloride 5 ND ND ND ND ND ND 0.110 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Toluene 600 ND ND ND ND ND ND 0.270 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND 0.140 J ND 0.330 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1.1 ND 0.490 J ND ND ND ND ND ND ND ND ND 0.59 ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-4
Arsenic 10 ND ND 2.9 J 4.16 JB ND ND ND ND ND ND ND ND 1.20 1.10 1.20 1.60 1.30 0.95 J 0.72 J ND 0.42 J 0.33 J ND 0.45 J
Barium 700 ND 23.7 20 20.9 JB 24.3 J 33.2 JB 29.6 JB 29.6 JB 22.2 JB 28.0 28.0 20.0 25.0 20.0 16.0 18.0 23.0 15.0 16.0 20.0 22.0 22.0 19 21 B
Cadmium 2 ND ND ND ND ND ND 0.16 J ND 0.21 J ND 0.48 J ND ND ND 0.26 J 0.058 J 0.57 J 0.034 J 0.18 J ND 0.096 J 0.21 J 0.80 J ND
Chromium 10 ND ND ND 4.09 JB 3.11 J 2.77 JB ND 3.40 JB 2.86 JB ND 1.6 J ND 5.00 ND 2.3 B 0.81 JB ND ND ND 0.54 J 0.78 J 0.54 J ND 0.33 JBLead15NDNDND3.12 J 6.11 J ND ND ND ND ND 0.96 J ND 0.74 J ND 0.81 J 0.79 J 0.85 J 0.26 J 0.56 J 0.29 J 0.48 J 0.47 J 0.70 J 0.96 JBMercury1NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.038 JBSelenium20NDNDND3.73 J ND ND ND ND ND ND 3.4 J ND 2.40 2.90 3.00 2.40 0.78 J 0.39 J ND ND 1.00 ND ND ND
Silver 20 ND ND ND ND ND 2.17 JB 3.90 JB 1.97 JB 1.03 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Acetone 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4.7 J ND
Benzene 1 ND ND ND 0.730 J 0.540 J 0.480 J 0.220 J 0.460 J ND 0.56 J ND 0.87 ND 0.93 0.92 0.91 0.77 0.51 ND 0.69 0.69 ND ND ND
Chloroethane 3000 ND 4.2 1.6 3.59 J 1.99 J 2.35 J 0.820 J 2.55 J ND 1.3 J ND 1.2 ND 1.7 1.4 1.9 ND 0.79 ND 1.1 ND ND ND ND1,1-Dichloroethane 6 ND 1.0 ND 0.350 J 0.560 J 0.210 J ND 0.160 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1,2-Dichloroethane 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
1,2-Dichloroethene (isomers)60 ND ND ND 0.210 J 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
4-Methyl-2-Pentanone 560 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.53 J ND ND ND ND ND ND ND
Toluene 600 ND ND ND ND ND ND 0.310 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND 0.110 J ND 0.540 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-5
Arsenic 10 ND ND ND 4.83 JB 1.93 J ND ND ND ND ND ND ND 0.55 J 1.30 1.10 0.47 J 0.46 J ND ND ND ND ND ND ND
Barium 700 ND ND 19.3 58.2 JB 32.3 J 30.8 JB 30.9 JB 33.6 JB 23.8 JB 30.0 28.0 31.0 27.0 32.0 33.0 27.0 31.0 23.0 23.0 22.0 17.0 16.0 17 12 BCadmium2NDNDNDNDNDNDNDNDNDND0.22 J 0.45 J ND ND ND 0.043 J 0.12 J ND ND 0.098 J 0.068 J 0.17 J 0.26 J NDChromium10NDNDND8.54 JB 5.67 J 1.58 JB 1.25 JB 4.10 JB 2.39 JB 0.60 J 1.7 J ND 5.00 ND 2.3 B 0.77 JB ND ND 0.32 J ND 0.81 J ND 0.59 J 0.18 JB
Lead 15 ND ND ND 14.5 6.02 J ND ND ND ND ND ND ND ND ND 0.34 J 0.39 J 0.87 J 0.064 J ND ND 0.64 J 0.26 J 0.083 J 0.71 JB
Mercury 1 ND ND ND 0.058 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.043 JB
Selenium 20 ND ND ND 5.42 J ND ND ND ND ND ND 3.2 J ND 4.40 5.10 6.80 3.20 0.66 J 0.59 J ND 2.70 1.30 0.53 J 0.93 J ND
Silver 20 ND ND ND ND ND 2.32 JB 3.74 JB 1.72 JB ND ND ND ND ND ND 0.081 J ND ND ND ND ND ND 0.037 J 0.079 J ND
Bromoform 4 ND ND ND ND ND ND ND ND 0.16 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDNDND0.210 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDTotal Xylenes 500 ND ND ND ND ND ND 0.280 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-6
Arsenic 10 ND ND 2.8 J 2.25 JB ND ND ND 3.08 J ND ND 0.9 J ND 2.20 2.20 1.70 1.60 0.98 J 0.69 J 1.30 0.88 J 3.30 1.30 2.2 1.5
Barium 700 ND 37.4 29.9 30.5 JB 26.3 J 36.1 JB 34.1 JB 30.1 JB 21.3 JB 13.0 16 J 18.0 14.0 28.0 22.0 31.0 29.0 31.0 39.0 36.0 42.0 43.0 44 46 B
Cadmium 2 ND ND ND ND ND ND ND ND ND ND 0.26 J ND 0.37 J ND ND 0.088 J 0.054 J ND 1.90 0.15 J 0.10 J 0.13 J ND NDChromium10NDNDND5.05 JB 1.31 J 1.88 JB ND ND 2.76 JB 0.60 J 1.2 J ND 4.40 ND 2.7 B 1.2 B ND ND ND 0.31 J 0.97 J ND ND 0.22 JBLead15NDNDND1.62 J 4.43 J 6.14 J 3.70 J 3.50 J ND 0.74 J 2.7 J ND 0.87 J ND 0.44 J 0.58 J 0.44 J 0.26 J 0.33 J 0.90 J 2.20 0.61 J 0.59 J 0.93 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.043 JB
Selenium 20 ND ND ND 4.75 J ND ND ND ND ND 2.8 J 3.9 J ND 5.80 6.60 6.00 4.40 1.10 0.79 J 1.20 2.60 2.10 1.00 0.96 J 0.58 J
Silver 20 ND ND ND ND ND 2.34 JB 3.79 JB 1.47 JB 0.78 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.060 J ND ND
Acetone 6000 ND ND ND ND ND ND ND 5.74 J 3.34 J 6.0 J 3.1 J ND ND ND ND ND ND ND ND ND ND ND 11 NDBenzene1NDND1.4 1.21 1.03 0.780 J 0.880 J 0.990 J 0.81 J 0.56 J ND ND ND 0.26 J ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDNDND0.180 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDTotal Xylenes 500 ND ND ND ND ND ND 0.380 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Table 3
Vinyl Chloride
Permit # 43-04
Harnett County, North Carolina
Historical Summary of Constituent Detections
ND
Central Carolina Tire Monofill Landfill Phase I/II
0.03 ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 ND 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-7
Arsenic 10 ND ND ND 3.88 JB ND ND ND ND ND ND 1.5 J ND 1.20 1.80 1.40 0.54 J 0.40 J 0.39 J 1.00 ND 0.58 J 0.40 J 0.37 J ND
Barium 700 ND 77 73.6 163 JB 64.2 J 70.7 JB 61.8 JB 63.0 JB 70.0 JB 67.0 65.0 67.0 54.0 65.0 59.0 62.0 52.0 64.0 55.0 59.0 52.0 62.0 35 63 B
Cadmium 2 ND ND ND ND ND ND ND ND ND ND 0.17 J ND ND ND ND ND 0.11 J ND ND ND 0.059 J 0.12 J 0.42 J ND
Chromium 10 ND ND ND 5.47 JB ND 1.58 JB 1.46 JB 3.01 JB 3.05 JB ND 2.6 J ND 4.50 ND 2.8 B 1.3 B ND 0.57 J ND 0.86 J 0.55 J 0.57 J 0.71 J 0.17 JB
Lead 15 ND ND 2.1 J 10.60 6.54 J 5.69 J 4.02 JB 5.74 JB 6.97 J 3.2 J 9.20 2.7 J 4.10 2.50 4.50 3.60 4.00 4.90 1.50 3.60 2.60 2.60 2.7 2.2 BMercury1NDNDND0.043 J 0.097 J 0.062 J ND ND 0.117 J 0.023 J ND ND ND ND ND ND ND ND ND ND ND ND ND NDSelenium20NDNDND3.05 J ND 7.96 J ND ND ND ND 3.7 J ND 4.40 5.10 4.70 3.60 0.96 J 0.70J 1.20 ND 1.90 0.47 J 0.48 J ND
Silver 20 ND ND ND ND ND 2.25 JB 3.62 JB 1.69 JB 0.94 J ND ND ND 0.062 J ND ND ND ND ND ND ND ND ND ND ND
Acetone 6000 ND ND ND ND ND ND ND ND ND ND 8.70 ND ND ND ND ND ND ND ND ND ND ND ND ND
Benzene 1 ND ND ND ND 0.790 J 0.210 J 0.250 J 0.330 J 0.61 J ND ND ND 0.65 0.68 0.64 ND 0.61 ND 0.61 ND 0.79 ND ND ND
1,1-Dichloroethane 6 ND ND ND ND 0.150 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1,2-Dichloroethene (isomers)60 ND ND ND ND 0.240 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDMethylene Chloride 5 ND ND ND ND ND ND ND ND 0.23 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDND0.250 JB 0.320 J ND ND ND 4.90 ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND 0.130 J ND 0.520 J ND 0.11 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-8
Arsenic 10 ND ND ND 2.03 JB ND ND ND ND ND ND ND ND 0.35 J ND ND ND ND ND ND ND ND ND ND ND
Barium 700 ND 41.5 42.5 32.1 JB 41.4 J 43.9 JB 46.1 JB 45.0 JB 39.2 JB 38.0 33.0 40.0 41.0 22.0 60.0 61.0 56.0 49.0 41.0 42.0 40.0 42.0 31 39 BCadmium2NDND1.1 ND ND ND ND ND ND ND 0.59 J 0.17 J ND ND ND 0.12 J 0.064 J 0.053 J ND 0.092 J 0.16 J 0.17 J 0.079 J NDChromium10NDNDND5.03 JB 4.54 J 2.33 JB 1.25 JB 3.20 JB 2.95 JB 0.56 J 1.3 J ND 3.70 ND 2.3 B 1.2 B ND 0.47 J 0.82 J 0.52 J 0.88 J 0.72 J ND 0.20 JBLead15NDNDND1.04 J 7.71 J 7.42 J ND 6.30 J ND 1.1 J 0.72 J 1.1 J 0.74 J ND 1.00 0.94 J 1.30 1.80 1.30 0.75 J 1.20 1.00 0.64 J 1.1 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Selenium 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.7 J 0.33 J ND ND ND ND ND ND ND 0.99J
Silver 20 ND ND ND ND ND 2.28 JB 3.90 JB 1.29 JB 0.8 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.013 J 0.021 J ND
Acetone 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4.6 J ND1,2-Dichloroethene (isomers)60 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.99 ND 1.20 ND ND ND NDEthylbenzene29NDNDNDNDNDND0.120 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Tetrachloroethene 0.7 ND ND 1.8 0.310 J 0.550 J 0.730 J 0.960 J 2.40 1.74 B 6.30 1.80 5.40 6.90 3.40 4.40 3.60 4.00 9.20 6.90 8.20 5.80 4.40 2.10 2.50
Toluene 600 ND ND ND ND ND ND 0.450 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND ND ND 0.700 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:MW-9
Arsenic 10 ND ND 2.6 J 2.88 JB 5.04 J ND ND ND ND 15 ND 13 ND ND ND ND ND ND ND ND ND 1 ND 8.3Barium700360242310462 JB 366.0 288 B 50.1 JB 210 B 311 B 680.0 230.0 940 390 800 390 320 540 640 430 510 590 950 89 400 BCadmium2NDNDNDNDNDNDNDND0.21 J 0.23 J 0.52 J 0.31 J ND ND 0.38 J 0.22 J 0.28 J 0.29 J 0.21 J 0.29 J 0.28 J 0.67 J 0.11 J 0.25 J
Chromium 10 ND ND ND 5.71 JB 1.24 J 1.73 JB 1.35 JB 2.82 JB 5.21 JB 1.0 J 2 J ND 8.3 J ND 3.2 B 1.2 B ND ND ND 0.50 J 1 2 ND 0.62 JB
Lead 15 ND ND ND 7.21 J 6.84 J 5.02 J ND ND ND 10.00 3.4 J 10 4 6 5 3 7 8 7.1 J 10 10 18 2.5 8.8 B
Mercury 1 ND ND ND 0.83 0.077 J ND ND ND ND 0.12 J ND 0.77 0.35 0.23 0.075 J 0.18 J 0.051 J ND ND 0.12 J 0.14 J 0.068 J ND 0.21 B
Selenium 20 ND ND 2.2 J 1.35 J ND ND ND ND ND ND ND ND ND 4 2 1 ND 2 2 3 3 6 0.61 J 53
Silver 20 ND ND ND ND ND ND 3.95 JB 1.18 JB ND ND ND ND ND ND 0.34 J ND ND ND ND ND ND 0.032 J 0.027 J NDBromoform4NDNDNDNDNDNDNDND0.28 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDEthylbenzene600NDNDNDNDNDND0.210 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 5 ND ND ND ND ND ND ND ND 0.16 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Toluene 600 ND ND ND ND ND ND 0.810 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Total Xylenes 500 ND ND ND ND ND ND 1.31 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:SW-1
Arsenic 10 ND ND 2.2 J 2.07 JB 2.86 J ND 2.78 J ND ND ND 0.61 J ND 1.90 ND 1.60 0.98 J 0.65 J 0.51 J ND ND 1.50 0.45 J 0.30 J 0.64 JBarium700NDND17.6 18.7 JB 25.5 J 30.4 JB 384 B 36.2 JB 21.1 JB 19.00 32.00 38.00 38.00 24.00 29.00 23.00 24.00 23.00 44.00 30.00 29.00 68.00 41 24 BCadmium2NDNDNDNDNDNDND0.370 J 0.28 J ND 0.3 J ND ND ND ND 0.20 J 0.052 J ND ND ND 0.091 J 0.081 J 0.025 J ND
Chromium 10 ND ND ND 5.76 JB 2.66 J 2.03 JB 2.09 JB 3.70 JB 2.49 JB 0.70 J 1.3 J ND 5.00 ND 2.6 B 1.5 B ND ND ND 0.91 J 3.80 ND 0.56 J 0.58 JB
Lead 15 ND ND ND ND 5.39 J 6.07 J 7.11 J 3.91 JB ND ND ND ND 0.27 J ND 0.35 J 0.23 J 0.41 J 0.34 J 0.24 J 0.29 J 2.20 0.43 J 0.40 J 0.82 JB
Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.074 JB
Selenium 20 ND ND 3.7 J 1.96 J ND ND ND ND ND ND 3.3 J ND 4.40 3.00 3.90 1.90 0.45 J 0.40 J ND ND 1.50 1.40 0.69 J NDSilver20NDNDNDNDND2.46 JB 2.07 JB 1.38 JB 0.87 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDAcetone6000NDNDNDNDND2.51 JB ND ND ND ND 2.8 J ND ND ND ND ND ND ND ND ND ND 5.90 6.60 NDBenzene11.0 ND ND ND ND ND 0.260 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
4-Methyl-2-Pentanone 560 ND ND ND ND ND ND ND ND ND ND ND ND 1.1 J ND ND ND ND ND ND ND 0.88 J ND ND ND
Sampling Date:2L Standard 10/26/05 3/30/06 10/19/06 4/18/07 10/24/07 4/29/08 10/14/08 4/22/09 10/14/09 4/29/10 10/19/10 4/13/11 10/6/11 4/26/12 10/3/12 4/3/13 10/16/13 4/1/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 4/19/17
Well No:SW-2
Arsenic 10 ND ND 2.9 J 1.70 JB 2.92 J ND ND ND ND ND ND ND NA ND ND ND 0.51 J 0.47 J ND ND 0.42 J ND 0.76 J ND
Barium 700 ND ND 21.1 31.1 JB 14.3 J 30.5 JB 55.6 JB 27.5 JB 75.1 JB 48.0 40.0 31.0 NA 25.0 30.0 18.0 26.0 26.0 24.0 28.0 29.0 23.0 41 25 BCadmium2NDNDNDNDNDNDNDND0.3 J ND 1.2 0.63 J NA ND 0.21 J ND 0.44 J ND ND ND 0.036 J 0.080 J 0.18 J 0.12 JChromium10NDNDND6.09 JB 5.66 2.47 JB 2.82 JB 2.82 JB 11.6 B 1.1 J 1.8 J ND NA ND 2.5 B 1.4 B ND ND ND 0.53 J 0.84 J 0.86 J 0.58 J 0.34 JBLead15NDNDND0.350 J ND 3.79 J 6.25 J 4.42 J 21.3 ND 1.0 J 1.0 J NA ND 0.45 J 0.93 J 2.9 0.44 J 0.21 J ND 0.52 J 0.41 J 0.46 J 0.34 JB
Mercury 1 ND ND 0.15 ND ND ND ND ND ND ND ND ND NA ND ND ND ND ND ND ND ND ND ND 0.045 JB
Selenium 20 ND ND ND ND ND ND ND ND ND 4.2 J ND ND NA 1.90 3.00 1.10 0.43 J 0.42 J ND ND 0.92 J 0.68 J 0.97 J ND
Silver 20 ND ND ND ND ND 2.24 JB 3.73 JB 1.58 JB ND ND ND ND NA ND ND ND ND ND ND ND ND ND 0.012 J 0.073 J
Acetone 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.6 ND
Notes:
Results in parts per billion (ppb) B = Analyte found in associated field and/or laboratory blank.
ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007).
NA - Not analyzed for or not available
Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards.
Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel.
J = Estimated value above laboratory method detection limit and below SWSL or reporting limit.
Historical Summary of Constituent Detections
Harnett County, North Carolina
Table 3 (Continued)
Phase I/II Tire Monofill Landfill (Active)

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
APPENDIX A

Groundwater Sampling Forms
Client: NAUTILUS
Project No: CENTRAL
Site Location: CAMERON,
Weather Conds: /i .f v
Date: _+tl\ ht
Time: Start :?45-.;6;-
Finisn i8lf- amipm
LINA TIRE, PERMIT #4304
Gro nd Water Sample Gollection Record
-_s-
wen *Piezometer n
e. Length of WaterColumn t {-3 € 6-b)
f. Calculated Well Volume (see back) A - {
Pumping Rate: 1CO mymin
WATER LEVEL DATA:
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of par
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume removed
Has required turbid been reached
Have parameters
If no or N/A -
SAMPLE COLLEGTION:
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
(from workplan)
No N/Annnf,nn
Comments
rge Volume (@ _ well volumes) _ N/Aurbidity N/A NTUs
10 o/o
Used: Make Model Serial NumberYSI 556 toAtot,LlY
Calibration Documentation Found on Separate Form
Yes.4-ffi'e-
below.
Method: Peristaltic Pump
Signature oate
-qt
(7 nt
t:
/vl u./ -
Date: 4/ n 117
Time: Start 16lr= am/pm
Finish 17oC am/pm
CIiCNt: NAUTILUS
Project No: CENTRAL
Conds: f! Svat.'t
Grou Water Sample Collection Record
WATER LEVEL DATA:
a. Total Well Length
b Water Table Depth
?<^ /)
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of para
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume
Has required turbidity
Have parameters
ll no or N/A - Exp below
SAMPLE COLLECTION:
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
Well -*- Piezometer nre. Length of water column {8 2 3 e-ol
f. Calculated Well Volume (see back) -Z -a
Volume (@ _ well volumes)
-
N/A PumpingRate: /60 mVminN/A NTUsters 10 To
Used: Make Model Serial NumberYSI 556 loTlo(zlY
Calibration Documentation Found on Separate Form
n removed
reached
No N/Anunnnt]
Method: PeristalticPump
Comments
Signature Date qt(1 nz
Grou Water Sample Collection Record
MUv'-
Pumping Rate: / OCr m/min
WATER LEVEL DATA: (meas
a. Total Well Length ,1o .o
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume
Has required turb
Have parameters
lf no or N/A -
SAMPLE COLLECTION:
Comments
from Top of Casing)
c. Casing Material PVC
d. Casino Diamete t 2"
LOW FLOW
(from workplan)
Volume (@ _ well volumes)N/A NTUs----------TA Yo
Calibration Documentation Found on Separate Form
removed
reached
lized
in below
Method: PeristalticPumo
welt k Piezomeier n
e. Length of water column i3 '9 8 6-01
f. Calculated Well Volume (see back) A' 3
Used: Make Model Serial NumberYSI 5so / DI.9CZ1Y.-
Yeqfr)/!+B-
N/Atrnn
Nonnn
Date:
-41i1
/17
Time: Start i5-1? amlpm
Finish -.!!iS- am/pm
Client: NAUTILUS G
Proiect No: CENTEAL C
Site Location: CAMERON,
Weather Conds: f. L'" ru
Volume
Removed ml
RCRA METALS
W b. waterrabte Depth
Signature aate
-qr
l7 nr
ID:/t\Lv -
Grou Water Sample Collection Record
WATER LEVEL DATA: (
4r| -- a. Total Well Length
NEY-'"/" n l\ b Water Table DePth
DL'-
-J , ,{
from Top of Casing)
c. Casing Material PVC
d. Casino Diamete r 2"
LOW FLOW
Calibration Documentation Found on Separate Form
lized
in below
Method: Peristaltic Pump
wett d Piezometer flT-
e. Length of water Column I t.. 7 .7 ta-ol
f. Calculated Well Volume (see back) a " T
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of par
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume
Has required turb
Have parameters
lf no or NIA -
(from workplan)
Volume (@ _ well volumes)
-
N/A Pumping g.1"' i Va ml/min.
N/A NTUS----------TC o/o
Used: Make Model Serial NumberYSI 556 le'l-tct -zt V
Yeq4WW
N/Annn
Nonn
tr
SAMPLE COLLECTION:
Commenis
Dale'.
-41('1
117
Time: Start i YZ<j am/pm
Finish l5{ O am/pm
TIRE, PERMIT #4304
lient: NAUTILUS
Project No: CENTRAL
Site Locaiion: CAMERON
Weaiher Conds' C1.>rtot/ -l A Collector(s) T
Signature
No Lo
Date:
-q
i7 ttz
11*". g1"ri 1-?i€ am/pm
Finish /??8 am/pm
Client: NAUTILUS
Project No: CENTRAL
Weather Conds: C&pu.
Grou Water Sample Collection Record
).Z/4Lv - :>
werrB Piezometer n
e. Length of Water Column lC - 27 O-o)
f. Calculated Well Volume (see back) I -1
-<a,
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
WELL PURGING DATA
a. Purge Method
qi?
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of par
c. Field Testing
d. Field Testing
e. Acceptance criteria
Has required volume
Has required
Have parameters
lf no or N/A -
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
removed
reached
ized
below
Method: Peristaltic Pumo
(from workplan)
Volume (@ _ well volumes) _ N/A Pumping Rate: /d c milmin
N/A NTUs'--------------1i ot
Used: Make Model Serial NumberYSI 556 I od/c,l;Zi V
Calibration Documentation Found on Separate Form
Yes,*
bal4-
N/Annn
Nontrn
SAMPLE COLLECTION:
Comments
Signature oate- q l1 nt
'iu
oate:
-q
l7 tn
Time: Start llor- am/pm
Finish iZ76 am/pm
Clienl NAUTILUS
Project No: CENTRAL
Site Locaiion: CAMERON,
Weather Conds: a cc
RCRA METALS
mw-
Grou Water Sample Collection Record
WATER LEVEL DATA: (
a. Total Well Length 2o . O
b. Water Table Depth V. S
from Top of Casing)
c. Casing Material PVC
d. Casino Diamete t 2"
well d- Piezometer I
e. Lengthofwatercolumn i 6' L S 6-o7
f. Calculated Well Volume (see back) e - 6
WELL PURGING DATA
a. Purge Method LOW FLOW
(from workplan)
Volume (@
-
well volumes) N/A Pumping Rate: Aoc ml/min.
urbidity N/A NTUs3ters 10 To
Make ModelYSt 556
Serial Number/b 'T1E(,Zl
d. Field Testing Eq t Calibrat,on Documentation Found on Separate Form
e. Acceptance criteria p
Has required volume
Has required turbi
Have parameters
lfnoorN/A-E below
SAMPLE COLLECTION:Method: Peristaltic Pump
Comments
YeSE-
w
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of pa
c. Field Testing Equ
removed
reached
No N/ANDnnnn
Signature oate
-+t
I1 rz
/14/ffi
oate: -+tl1 nt
rime: Start l/o#-."vp*
Finish j!!3- am/pm
TIRE, PERMIT #4304
lient: NAUTILUS
Project No: CENTRAL
Site Location: CAMERON
ther Conds: Clocl
TURBIDITY
Grou d Water Sample Collection Record
,t _8
PumpingRate: /d O mUmin,
WATER LEVEL DATA: (
a. Total Well Length 2O . A
b. Water Table Depth 6 "'1
WELL PURGING DATA
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of pa
c. Field Testing E
d. Field Testing Eq
e. Acceptance criteria
Has required volume
Has required
Have parameters
lfnoorN/A-E below
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
(from workplan)
Volume (@ _ well volumes)
N/A NTUS
----to
u
removed
reached
welt E- Piezometer fl
e. Le(gtn of water Column | -3 ' 'r--l 1a-01
f. Calculated Well Volume (see back) "2 ' 2-
Used: Make Model Serial NumberYSI 556 / cJ-(c f,at f
t Calibration Documentation Found on Separate Form
Yeq No l[/A*nn&nnE-nn
SAMPLE COLLECTION:
Comments
Method: Peristaltic Pump
Signature oae
-at
l1 nz
INATIRE. PERMIT#4304 Time: Start i o /<- am/pm
Finish tleo am/Pm
lient: NAUTILUS GE
Project No: CENTRAL
Site Location: CAMERON,
Weather gsnds; c& 4:
ID:fr\LJ -
Water Sample Collection Record
WATER LEVEL DATA:
a. Total Well Length
b. Water Table Depth
3o
from Top of Casing)
c. Casing Material PVC
d. Casing Diamete r 2"
LOW FLOW
werl{.-- Piezometer I
e. Ler{gtn of water column '7. t 6 1a-o1
f. Calculated Well Volume (see back) / ' e*
WELL PURGING DATA
SAMPLE COLLECTION:
Comments
a. Purge Method
b. Acceptance Criteria
- Minimum Required
- Maximum Allowable
- Stabilization of pa
c. Field Testing Equ Used: Make
d. Field Testing E
e. Acceptance criteria
Has required volume removed
Has required been reached
Have parameters
lf no or N/A - below
(from workplan)
Volume (@
-
well volumes)N/A Pumping nate:l OO ml/min.N/A NTUs
-------- 16 o/o
Model Serial Numberyst 556 io-T /a I Lt 7
Calibration Documentation Found on Separate Form
N/Annn
YeS NoffinB- ttfun
Method:Peristaltic Pumo
Signature oa]tr-
-attl
tn
Client: N.
EFM E
(s@l
IPMENT
Project #:
CALIBRATION FORM
aC- -Tr,4{-
INSTRUMENT:alcc /
SERTAL 19.; /oTrE1 a1
INSTRUMENT: V (r ii-6 rca/
SERTAL NejiaTlor>_r
Calibration Recorded
Lot# ' i.'(; )_L Y Exp:
Lot# Ll c^l S*7c- Exp: , [t I
Lot# 7 t"ii tz I
1.413mS Lor# (sl 7ti
iL)'-( il,i
heck /.718 mS
Check 7.0
- t f i )..r -"\ r] ,r"td- ft ) rf rrr-;1 2
Galibration Recorded
1.413mS
k/.718 mS
Check 7.0

11112 BRANDING IRON PLACE, WENDELL, NC 27591
919-366-3663 Office ● 919-995-0363 Cell ● [e-mail]
APPENDIX B

Laboratory Reports
And
Chain-of-Custody Records

This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Case Narrative
05/09/2017
Nautilus Geologic Consulting, PLLC
Brian S. Boutin
11112 Branding Iron Place
Wendell, NC 27591
Project: Central Carolina Tire
Project No.: 43-04
Lab Submittal Date: 04/21/2017
Prism Work Order: 7040416
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
President/Project Manager
Reviewed ByRobbi A. Jones Robbi A. Jones
President/Project Manager
Data Qualifiers Key Reference:
A Analysis performed outside recommended holding time due to instrument failures.
Aa Reporting limit raised to 2 ug/L on the samples in this analytical batch, therefore, the Lead that was found in the
Method Blank is <1/2 the reporting limit.
CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken.
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
LH High LCS recovery. Analyte not detected in the sample(s). No further action taken.
M Matrix spike outside of the control limits.
Method Detection LimitMDL
Below Reporting LimitBRL
Relative Percent DifferenceRPD
*Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 1 of 61
Sample Receipt Summary
05/09/2017
Prism Work Order: 7040416
Client Sample ID MatrixLab Sample ID Date Sampled Date Received
7040416-01 04/18/174304-TB01 04/21/17Water
7040416-02 04/18/174304-EB01 04/21/17Water
7040416-03 04/18/174304-MW10 04/21/17Water
7040416-04 04/18/174304-MW11 04/21/17Water
7040416-05 04/18/174304-MW12 04/21/17Water
7040416-06 04/19/174304-MW13 04/21/17Water
7040416-07 04/19/174304-MW14 04/21/17Water
7040416-08 04/19/174304-MW16 04/21/17Water
7040416-09 04/18/174304-MW17R 04/21/17Water
7040416-10 04/18/174304-MW18 04/21/17Water
7040416-11 04/19/174304-SW1 04/21/17Water
7040416-12 04/19/174304-SW2 04/21/17Water
7040416-13 04/18/174304-SW1 (Exp)04/21/17Water
7040416-14 04/19/174304-MW2 04/21/17Water
7040416-15 04/19/174304-MW3 04/21/17Water
7040416-16 04/19/174304-MW4 04/21/17Water
7040416-17 04/19/174304-MW5 04/21/17Water
7040416-18 04/19/174304-MW6 04/21/17Water
7040416-19 04/19/174304-MW7 04/21/17Water
7040416-20 04/19/174304-MW8 04/21/17Water
7040416-21 04/19/174304-MW9 04/21/17Water
Samples were received in good condition at 4.2 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 2 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.030 J ug/L7040416-02 4304-EB01 Mercury 7470A
1.3 J ug/L7040416-02 4304-EB01 Barium 6020B
0.12 J ug/L7040416-02 4304-EB01 Chromium 6020B
0.81 J ug/L7040416-02 4304-EB01 Lead 6020B
0.30 ug/L7040416-03 4304-MW10 Mercury 7470A
0.55 J ug/L7040416-03 4304-MW10 Arsenic 6020B
43 ug/L7040416-03 4304-MW10 Barium 6020B
0.064 J ug/L7040416-03 4304-MW10 Cadmium 6020B
0.44 J ug/L7040416-03 4304-MW10 Chromium 6020B
0.86 J ug/L7040416-03 4304-MW10 Lead 6020B
4.2 J ug/L7040416-03 4304-MW10 Selenium 6020B
0.42 ug/L7040416-04 4304-MW11 Mercury 7470A
51 ug/L7040416-04 4304-MW11 Barium 6020B
0.27 J ug/L7040416-04 4304-MW11 Chromium 6020B
1.0 J ug/L7040416-04 4304-MW11 Lead 6020B
0.46 J ug/L7040416-04 4304-MW11 Selenium 6020B
0.061 J ug/L7040416-05 4304-MW12 Mercury 7470A
1.4 ug/L7040416-05 4304-MW12 Arsenic 6020B
9.5 ug/L7040416-05 4304-MW12 Barium 6020B
0.12 J ug/L7040416-05 4304-MW12 Cadmium 6020B
1.8 ug/L7040416-05 4304-MW12 Chromium 6020B
1.1 J ug/L7040416-05 4304-MW12 Lead 6020B
8.0 ug/L7040416-06 4304-MW13 Barium 6020B
0.24 J ug/L7040416-06 4304-MW13 Chromium 6020B
0.50 J ug/L7040416-06 4304-MW13 Lead 6020B
32 ug/L7040416-07 4304-MW14 Barium 6020B
0.21 J ug/L7040416-07 4304-MW14 Chromium 6020B
0.63 J ug/L7040416-07 4304-MW14 Lead 6020B
0.84 ug/L7040416-08 4304-MW16 Mercury 7470A
62 ug/L7040416-08 4304-MW16 Barium 6020B
0.23 J ug/L7040416-08 4304-MW16 Chromium 6020B
0.97 J ug/L7040416-08 4304-MW16 Lead 6020B
1.7 J ug/L7040416-08 4304-MW16 Selenium 6020B
110 ug/L7040416-09 4304-MW17R Barium 6020B
0.54 J ug/L7040416-09 4304-MW17R Chromium 6020B
1.2 J ug/L7040416-09 4304-MW17R Lead 6020B
1.3 J ug/L7040416-09 4304-MW17R Selenium 6020B
0.087 J ug/L7040416-10 4304-MW18 Mercury 7470A
62 ug/L7040416-10 4304-MW18 Barium 6020B
0.17 J ug/L7040416-10 4304-MW18 Chromium 6020B
1.3 J ug/L7040416-10 4304-MW18 Lead 6020B
0.50 J ug/L7040416-10 4304-MW18 Selenium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 3 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.074 J ug/L7040416-11 4304-SW1 Mercury 7470A
0.64 J ug/L7040416-11 4304-SW1 Arsenic 6020B
24 ug/L7040416-11 4304-SW1 Barium 6020B
0.58 J ug/L7040416-11 4304-SW1 Chromium 6020B
0.82 J ug/L7040416-11 4304-SW1 Lead 6020B
0.045 J ug/L7040416-12 4304-SW2 Mercury 7470A
25 ug/L7040416-12 4304-SW2 Barium 6020B
0.12 J ug/L7040416-12 4304-SW2 Cadmium 6020B
0.34 J ug/L7040416-12 4304-SW2 Chromium 6020B
0.34 J ug/L7040416-12 4304-SW2 Lead 6020B
0.073 CCV, J ug/L7040416-12 4304-SW2 Silver 6020B
0.038 J ug/L7040416-13 4304-SW1 (Exp)Mercury 7470A
42 ug/L7040416-13 4304-SW1 (Exp)Barium 6020B
0.20 J ug/L7040416-13 4304-SW1 (Exp)Chromium 6020B
0.63 J ug/L7040416-13 4304-SW1 (Exp)Lead 6020B
0.053 J ug/L7040416-14 4304-MW2 Mercury 7470A
82 ug/L7040416-14 4304-MW2 Barium 6020B
0.29 J ug/L7040416-14 4304-MW2 Chromium 6020B
1.8 J ug/L7040416-14 4304-MW2 Lead 6020B
1.1 J ug/L7040416-14 4304-MW2 Selenium 6020B
0.053 J ug/L7040416-15 4304-MW3 Mercury 7470A
0.63 J ug/L7040416-15 4304-MW3 Arsenic 6020B
28 ug/L7040416-15 4304-MW3 Barium 6020B
0.32 J ug/L7040416-15 4304-MW3 Chromium 6020B
0.96 J ug/L7040416-15 4304-MW3 Lead 6020B
0.80 J ug/L7040416-15 4304-MW3 Selenium 6020B
0.038 J ug/L7040416-16 4304-MW4 Mercury 7470A
0.45 J ug/L7040416-16 4304-MW4 Arsenic 6020B
21 ug/L7040416-16 4304-MW4 Barium 6020B
0.33 J ug/L7040416-16 4304-MW4 Chromium 6020B
0.96 J ug/L7040416-16 4304-MW4 Lead 6020B
0.043 J ug/L7040416-17 4304-MW5 Mercury 7470A
12 ug/L7040416-17 4304-MW5 Barium 6020B
0.18 J ug/L7040416-17 4304-MW5 Chromium 6020B
0.71 J ug/L7040416-17 4304-MW5 Lead 6020B
0.043 J ug/L7040416-18 4304-MW6 Mercury 7470A
1.5 ug/L7040416-18 4304-MW6 Arsenic 6020B
46 ug/L7040416-18 4304-MW6 Barium 6020B
0.22 J ug/L7040416-18 4304-MW6 Chromium 6020B
0.93 J ug/L7040416-18 4304-MW6 Lead 6020B
0.58 J ug/L7040416-18 4304-MW6 Selenium 6020B
63 ug/L7040416-19 4304-MW7 Barium 6020B
0.17 J ug/L7040416-19 4304-MW7 Chromium 6020B
2.2 ug/L7040416-19 4304-MW7 Lead 6020B
39 ug/L7040416-20 4304-MW8 Barium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 4 of 61
Client ID ResultParameterMethod UnitsPrism ID
Prism Work Order: 7040416
05/09/2017
Summary of Detections
0.20 J ug/L7040416-20 4304-MW8 Chromium 6020B
1.1 J ug/L7040416-20 4304-MW8 Lead 6020B
0.99 J ug/L7040416-20 4304-MW8 Selenium 6020B
2.5 ug/L7040416-20 4304-MW8 Tetrachloroethylene 8260B
0.21 ug/L7040416-21 4304-MW9 Mercury 7470A
8.3 ug/L7040416-21 4304-MW9 Arsenic 6020B
400 ug/L7040416-21 4304-MW9 Barium 6020B
0.25 J ug/L7040416-21 4304-MW9 Cadmium 6020B
0.62 J ug/L7040416-21 4304-MW9 Chromium 6020B
8.8 ug/L7040416-21 4304-MW9 Lead 6020B
53 ug/L7040416-21 4304-MW9 Selenium 6020B
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 5 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-01
Prism Work Order: 7040416
Time Collected: 04/18/17 00:00
Time Submitted: 04/21/17 16:40
4304-TB01
43-04
SWSL
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 4:13 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 4:13 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.079Chloromethane1<0.079
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 4:13 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 6 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-01
Prism Work Order: 7040416
Time Collected: 04/18/17 00:00
Time Submitted: 04/21/17 16:40
4304-TB01
43-04
SWSL
8260B P7D050011.0 4/29/17 4:13 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 4:13 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 4:13 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 4:13 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 4:13 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 4:13 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124108 %4-Bromofluorobenzene
75-129102 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 7 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-02
Prism Work Order: 7040416
Time Collected: 04/18/17 13:30
Time Submitted: 04/21/17 16:40
4304-EB01
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 9:27 JABJug/L 0.030Mercury0.20.030
6020B P7E000411.0 5/3/17 19:43 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 19:43 BGMJug/L 0.12Barium1001.3
6020B P7E000411.0 5/3/17 19:43 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 19:43 BGMJug/L 0.081Chromium100.12
6020B P7E000412.0 5/3/17 19:43 BGMJug/L 0.061Lead100.81
6020B P7E000415.0 5/3/17 19:43 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 19:43 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7D050012.0 4/29/17 4:39 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.31Acetone100<0.31
8260B P7D05001204/29/17 4:39 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.048Benzene1<0.048
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.040Bromoform3<0.040
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.18Bromomethane10<0.18
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.22Chloroethane10<0.22
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.076Chloroform5<0.076
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 8 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-02
Prism Work Order: 7040416
Time Collected: 04/18/17 13:30
Time Submitted: 04/21/17 16:40
4304-EB01
43-04
SWSL
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.065Dibromomethane10<0.065
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7D050015.0 4/29/17 4:39 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7D050011.0 4/29/17 4:39 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.044o-Xylene NE<0.044
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.047Styrene1<0.047
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7D05001104/29/17 4:39 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.044Toluene1<0.044
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7D05001104/29/17 4:39 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7D050012.0 4/29/17 4:39 KDMCC
V
ug/L 0.060Vinyl acetate 50<0.060
8260B P7D050010.50 4/29/17 4:39 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7D050011.5 4/29/17 4:39 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124107 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12396 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 9 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-11
Prism Work Order: 7040416
Time Collected: 04/19/17 13:45
Time Submitted: 04/21/17 16:40
4304-SW1
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:09 JABJug/L 0.030Mercury0.20.074
6020B P7E000411.0 5/3/17 20:51 BGMJug/L 0.45Arsenic100.64
6020B P7E000415.0 5/3/17 20:51 BGMug/L 0.12Barium10024
6020B P7E000411.0 5/3/17 20:51 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 20:51 BGMJug/L 0.081Chromium100.58
6020B P7E000412.0 5/3/17 20:51 BGMJug/L 0.061Lead100.82
6020B P7E000415.0 5/3/17 20:51 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 20:51 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E003911.0 5/2/17 21:03 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E003912.0 5/2/17 21:03 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.31Acetone100<0.31
8260B P7E00391205/2/17 21:03 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.048Benzene1<0.048
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E003911.0 5/2/17 21:03 KDMug/L 0.040Bromoform3<0.040
8260B P7E003911.0 5/2/17 21:03 KDMug/L 0.18Bromomethane10<0.18
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.22Chloroethane10<0.22
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.076Chloroform5<0.076
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 26 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-11
Prism Work Order: 7040416
Time Collected: 04/19/17 13:45
Time Submitted: 04/21/17 16:40
4304-SW1
43-04
SWSL
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E003911.0 5/2/17 21:03 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E003915.0 5/2/17 21:03 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E003911.0 5/2/17 21:03 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.047Styrene1<0.047
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00391105/2/17 21:03 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.044Toluene1<0.044
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00391105/2/17 21:03 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E003912.0 5/2/17 21:03 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E003910.50 5/2/17 21:03 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E003911.5 5/2/17 21:03 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124102 %4-Bromofluorobenzene
75-129100 %Dibromofluoromethane
77-123101 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 27 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-12
Prism Work Order: 7040416
Time Collected: 04/19/17 17:10
Time Submitted: 04/21/17 16:40
4304-SW2
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:20 JABJug/L 0.030Mercury0.20.045
6020B P7E000411.0 5/3/17 21:10 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:10 BGMug/L 0.12Barium10025
6020B P7E000411.0 5/3/17 21:10 BGMJug/L 0.053Cadmium10.12
6020B P7E000411.0 5/3/17 21:10 BGMJug/L 0.081Chromium100.34
6020B P7E000412.0 5/3/17 21:10 BGMJug/L 0.061Lead100.34
6020B P7E000415.0 5/3/17 21:10 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 21:10 BGMCC
V, J
ug/L 0.067Silver100.073
Volatile Organic Compounds by GC/MS
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E005611.0 5/3/17 14:45 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E005612.0 5/3/17 14:45 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.31Acetone100<0.31
8260B P7E00561205/3/17 14:45 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.048Benzene1<0.048
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E005611.0 5/3/17 14:45 KDMug/L 0.040Bromoform3<0.040
8260B P7E005611.0 5/3/17 14:45 KDMug/L 0.18Bromomethane10<0.18
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.22Chloroethane10<0.22
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.076Chloroform5<0.076
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 28 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-12
Prism Work Order: 7040416
Time Collected: 04/19/17 17:10
Time Submitted: 04/21/17 16:40
4304-SW2
43-04
SWSL
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E005611.0 5/3/17 14:45 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E005615.0 5/3/17 14:45 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E005611.0 5/3/17 14:45 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.047Styrene1<0.047
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00561105/3/17 14:45 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.044Toluene1<0.044
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00561105/3/17 14:45 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E005612.0 5/3/17 14:45 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E005610.50 5/3/17 14:45 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E005611.5 5/3/17 14:45 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12498 %4-Bromofluorobenzene
75-129100 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 29 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-14
Prism Work Order: 7040416
Time Collected: 04/19/17 14:51
Time Submitted: 04/21/17 16:40
4304-MW2
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:28 JABJug/L 0.030Mercury0.20.053
6020B P7E000411.0 5/3/17 21:22 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:22 BGMug/L 0.12Barium10082
6020B P7E000411.0 5/3/17 21:22 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:22 BGMJug/L 0.081Chromium100.29
6020B P7E000412.0 5/3/17 21:22 BGMJug/L 0.061Lead101.8
6020B P7E000415.0 5/3/17 21:22 BGMJug/L 0.45Selenium101.1
6020B P7E000415.0 5/3/17 21:22 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E005611.0 5/3/17 15:11 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E005612.0 5/3/17 15:11 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.31Acetone100<0.31
8260B P7E00561205/3/17 15:11 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.048Benzene1<0.048
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E005611.0 5/3/17 15:11 KDMug/L 0.040Bromoform3<0.040
8260B P7E005611.0 5/3/17 15:11 KDMug/L 0.18Bromomethane10<0.18
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.22Chloroethane10<0.22
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.076Chloroform5<0.076
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 32 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-14
Prism Work Order: 7040416
Time Collected: 04/19/17 14:51
Time Submitted: 04/21/17 16:40
4304-MW2
43-04
SWSL
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E005611.0 5/3/17 15:11 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E005615.0 5/3/17 15:11 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E005611.0 5/3/17 15:11 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.047Styrene1<0.047
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00561105/3/17 15:11 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.044Toluene1<0.044
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00561105/3/17 15:11 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E005612.0 5/3/17 15:11 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E005610.50 5/3/17 15:11 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E005611.5 5/3/17 15:11 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12499 %4-Bromofluorobenzene
75-129100 %Dibromofluoromethane
77-12398 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 33 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-15
Prism Work Order: 7040416
Time Collected: 04/19/17 13:22
Time Submitted: 04/21/17 16:40
4304-MW3
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:32 JABJug/L 0.030Mercury0.20.053
6020B P7E000411.0 5/3/17 21:28 BGMJug/L 0.45Arsenic100.63
6020B P7E000415.0 5/3/17 21:28 BGMug/L 0.12Barium10028
6020B P7E000411.0 5/3/17 21:28 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:28 BGMJug/L 0.081Chromium100.32
6020B P7E000412.0 5/3/17 21:28 BGMJug/L 0.061Lead100.96
6020B P7E000415.0 5/3/17 21:28 BGMJug/L 0.45Selenium100.80
6020B P7E000415.0 5/3/17 21:28 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E005611.0 5/3/17 15:37 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E005612.0 5/3/17 15:37 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.31Acetone100<0.31
8260B P7E00561205/3/17 15:37 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.048Benzene1<0.048
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E005611.0 5/3/17 15:37 KDMug/L 0.040Bromoform3<0.040
8260B P7E005611.0 5/3/17 15:37 KDMug/L 0.18Bromomethane10<0.18
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.22Chloroethane10<0.22
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.076Chloroform5<0.076
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.079Chloromethane1<0.079
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 34 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-15
Prism Work Order: 7040416
Time Collected: 04/19/17 13:22
Time Submitted: 04/21/17 16:40
4304-MW3
43-04
SWSL
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E005611.0 5/3/17 15:37 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E005615.0 5/3/17 15:37 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E005611.0 5/3/17 15:37 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.047Styrene1<0.047
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00561105/3/17 15:37 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.044Toluene1<0.044
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00561105/3/17 15:37 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E005612.0 5/3/17 15:37 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E005610.50 5/3/17 15:37 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E005611.5 5/3/17 15:37 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12499 %4-Bromofluorobenzene
75-12999 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 35 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-16
Prism Work Order: 7040416
Time Collected: 04/19/17 12:34
Time Submitted: 04/21/17 16:40
4304-MW4
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:35 JABJug/L 0.030Mercury0.20.038
6020B P7E000411.0 5/3/17 21:35 BGMJug/L 0.45Arsenic100.45
6020B P7E000415.0 5/3/17 21:35 BGMug/L 0.12Barium10021
6020B P7E000411.0 5/3/17 21:35 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:35 BGMJug/L 0.081Chromium100.33
6020B P7E000412.0 5/3/17 21:35 BGMJug/L 0.061Lead100.96
6020B P7E000415.0 5/3/17 21:35 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 21:35 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E005611.0 5/3/17 16:02 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E005612.0 5/3/17 16:02 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.31Acetone100<0.31
8260B P7E00561205/3/17 16:02 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.048Benzene1<0.048
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E005611.0 5/3/17 16:02 KDMug/L 0.040Bromoform3<0.040
8260B P7E005611.0 5/3/17 16:02 KDMug/L 0.18Bromomethane10<0.18
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.22Chloroethane10<0.22
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.076Chloroform5<0.076
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 36 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-16
Prism Work Order: 7040416
Time Collected: 04/19/17 12:34
Time Submitted: 04/21/17 16:40
4304-MW4
43-04
SWSL
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E005611.0 5/3/17 16:02 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E005615.0 5/3/17 16:02 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E005611.0 5/3/17 16:02 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.047Styrene1<0.047
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00561105/3/17 16:02 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.044Toluene1<0.044
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00561105/3/17 16:02 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E005612.0 5/3/17 16:02 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E005610.50 5/3/17 16:02 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E005611.5 5/3/17 16:02 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12496 %4-Bromofluorobenzene
75-12999 %Dibromofluoromethane
77-12398 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 37 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-17
Prism Work Order: 7040416
Time Collected: 04/19/17 17:57
Time Submitted: 04/21/17 16:40
4304-MW5
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:39 JABJug/L 0.030Mercury0.20.043
6020B P7E000411.0 5/3/17 21:41 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:41 BGMug/L 0.12Barium10012
6020B P7E000411.0 5/3/17 21:41 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:41 BGMJug/L 0.081Chromium100.18
6020B P7E000412.0 5/3/17 21:41 BGMJug/L 0.061Lead100.71
6020B P7E000415.0 5/3/17 21:41 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 21:41 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS A
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E008911.0 5/6/17 19:08 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E008912.0 5/6/17 19:08 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.31Acetone100<0.31
8260B P7E00891205/6/17 19:08 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.048Benzene1<0.048
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E008911.0 5/6/17 19:08 KDMug/L 0.040Bromoform3<0.040
8260B P7E008911.0 5/6/17 19:08 KDMug/L 0.18Bromomethane10<0.18
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.22Chloroethane10<0.22
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.076Chloroform5<0.076
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 38 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-17
Prism Work Order: 7040416
Time Collected: 04/19/17 17:57
Time Submitted: 04/21/17 16:40
4304-MW5
43-04
SWSL
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E008911.0 5/6/17 19:08 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E008915.0 5/6/17 19:08 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E008911.0 5/6/17 19:08 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.047Styrene1<0.047
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00891105/6/17 19:08 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.044Toluene1<0.044
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00891105/6/17 19:08 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E008912.0 5/6/17 19:08 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E008910.50 5/6/17 19:08 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E008911.5 5/6/17 19:08 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124101 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12398 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 39 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-18
Prism Work Order: 7040416
Time Collected: 04/19/17 16:44
Time Submitted: 04/21/17 16:40
4304-MW6
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:43 JABJug/L 0.030Mercury0.20.043
6020B P7E000411.0 5/3/17 21:47 BGMug/L 0.45Arsenic101.5
6020B P7E000415.0 5/3/17 21:47 BGMug/L 0.12Barium10046
6020B P7E000411.0 5/3/17 21:47 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:47 BGMJug/L 0.081Chromium100.22
6020B P7E000412.0 5/3/17 21:47 BGMJug/L 0.061Lead100.93
6020B P7E000415.0 5/3/17 21:47 BGMJug/L 0.45Selenium100.58
6020B P7E000415.0 5/3/17 21:47 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS A
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E008911.0 5/6/17 19:34 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E008912.0 5/6/17 19:34 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.31Acetone100<0.31
8260B P7E00891205/6/17 19:34 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.048Benzene1<0.048
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E008911.0 5/6/17 19:34 KDMug/L 0.040Bromoform3<0.040
8260B P7E008911.0 5/6/17 19:34 KDMug/L 0.18Bromomethane10<0.18
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.22Chloroethane10<0.22
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.076Chloroform5<0.076
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.079Chloromethane1<0.079
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 40 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-18
Prism Work Order: 7040416
Time Collected: 04/19/17 16:44
Time Submitted: 04/21/17 16:40
4304-MW6
43-04
SWSL
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E008911.0 5/6/17 19:34 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E008915.0 5/6/17 19:34 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E008911.0 5/6/17 19:34 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.047Styrene1<0.047
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00891105/6/17 19:34 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.044Toluene1<0.044
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00891105/6/17 19:34 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E008912.0 5/6/17 19:34 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E008910.50 5/6/17 19:34 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E008911.5 5/6/17 19:34 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12498 %4-Bromofluorobenzene
75-129102 %Dibromofluoromethane
77-12397 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 41 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-19
Prism Work Order: 7040416
Time Collected: 04/19/17 15:53
Time Submitted: 04/21/17 16:40
4304-MW7
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:47 JABug/L 0.030Mercury0.2<0.030
6020B P7E000411.0 5/3/17 21:53 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:53 BGMug/L 0.12Barium10063
6020B P7E000411.0 5/3/17 21:53 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:53 BGMJug/L 0.081Chromium100.17
6020B P7E000412.0 5/3/17 21:53 BGMug/L 0.061Lead102.2
6020B P7E000415.0 5/3/17 21:53 BGMug/L 0.45Selenium10<0.45
6020B P7E000415.0 5/3/17 21:53 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS A
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E008911.0 5/6/17 19:59 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E008912.0 5/6/17 19:59 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.31Acetone100<0.31
8260B P7E00891205/6/17 19:59 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.048Benzene1<0.048
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E008911.0 5/6/17 19:59 KDMug/L 0.040Bromoform3<0.040
8260B P7E008911.0 5/6/17 19:59 KDMug/L 0.18Bromomethane10<0.18
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.22Chloroethane10<0.22
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.076Chloroform5<0.076
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 42 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-19
Prism Work Order: 7040416
Time Collected: 04/19/17 15:53
Time Submitted: 04/21/17 16:40
4304-MW7
43-04
SWSL
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E008911.0 5/6/17 19:59 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E008915.0 5/6/17 19:59 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E008911.0 5/6/17 19:59 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.047Styrene1<0.047
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00891105/6/17 19:59 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.044Toluene1<0.044
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00891105/6/17 19:59 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E008912.0 5/6/17 19:59 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E008910.50 5/6/17 19:59 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E008911.5 5/6/17 19:59 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124101 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12398 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 43 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-20
Prism Work Order: 7040416
Time Collected: 04/19/17 11:40
Time Submitted: 04/21/17 16:40
4304-MW8
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:51 JABug/L 0.030Mercury0.2<0.030
6020B P7E000411.0 5/3/17 21:59 BGMug/L 0.45Arsenic10<0.45
6020B P7E000415.0 5/3/17 21:59 BGMug/L 0.12Barium10039
6020B P7E000411.0 5/3/17 21:59 BGMug/L 0.053Cadmium1<0.053
6020B P7E000411.0 5/3/17 21:59 BGMJug/L 0.081Chromium100.20
6020B P7E000412.0 5/3/17 21:59 BGMJug/L 0.061Lead101.1
6020B P7E000415.0 5/3/17 21:59 BGMJug/L 0.45Selenium100.99
6020B P7E000415.0 5/3/17 21:59 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS A
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E008911.0 5/6/17 20:25 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E008912.0 5/6/17 20:25 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.31Acetone100<0.31
8260B P7E00891205/6/17 20:25 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.048Benzene1<0.048
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E008911.0 5/6/17 20:25 KDMug/L 0.040Bromoform3<0.040
8260B P7E008911.0 5/6/17 20:25 KDMug/L 0.18Bromomethane10<0.18
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.22Chloroethane10<0.22
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.076Chloroform5<0.076
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.079Chloromethane1<0.079
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 44 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-20
Prism Work Order: 7040416
Time Collected: 04/19/17 11:40
Time Submitted: 04/21/17 16:40
4304-MW8
43-04
SWSL
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E008911.0 5/6/17 20:25 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E008915.0 5/6/17 20:25 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E008911.0 5/6/17 20:25 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.047Styrene1<0.047
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.098Tetrachloroethylene12.5
8260B P7E00891105/6/17 20:25 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.044Toluene1<0.044
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00891105/6/17 20:25 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E008912.0 5/6/17 20:25 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E008910.50 5/6/17 20:25 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E008911.5 5/6/17 20:25 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-124100 %4-Bromofluorobenzene
75-129100 %Dibromofluoromethane
77-12397 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 45 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-21
Prism Work Order: 7040416
Time Collected: 04/19/17 10:47
Time Submitted: 04/21/17 16:40
4304-MW9
43-04
SWSL
Total Metals
7470A P7E000810.20 5/2/17 10:54 JABug/L 0.030Mercury0.20.21
6020B P7E000411.0 5/3/17 22:06 BGMug/L 0.45Arsenic108.3
6020B P7E000415.0 5/3/17 22:06 BGMug/L 0.12Barium100400
6020B P7E000411.0 5/3/17 22:06 BGMJug/L 0.053Cadmium10.25
6020B P7E000411.0 5/3/17 22:06 BGMJug/L 0.081Chromium100.62
6020B P7E000412.0 5/3/17 22:06 BGMug/L 0.061Lead108.8
6020B P7E000415.0 5/3/17 22:06 BGMug/L 0.45Selenium1053
6020B P7E000415.0 5/3/17 22:06 BGMCC
V
ug/L 0.067Silver10<0.067
Volatile Organic Compounds by GC/MS A
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.111,1,1,2-Tetrachloroethane 5<0.11
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0611,1,1-Trichloroethane 1<0.061
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0361,1,2,2-Tetrachloroethane 3<0.036
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0661,1,2-Trichloroethane 1<0.066
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0831,1-Dichloroethane 5<0.083
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0831,1-Dichloroethylene 5<0.083
8260B P7E008911.0 5/6/17 20:50 KDMug/L 0.141,2,3-Trichloropropane 1<0.14
8260B P7E008912.0 5/6/17 20:50 KDMug/L 0.171,2-Dibromo-3-chloropropane 13<0.17
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0511,2-Dibromoethane 1<0.051
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0761,2-Dichlorobenzene 5<0.076
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0661,2-Dichloroethane 1<0.066
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.111,2-Dichloropropane 1<0.11
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.0501,4-Dichlorobenzene 1<0.050
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.31Acetone100<0.31
8260B P7E00891205/6/17 20:50 KDMug/L 0.20Acrylonitrile200<0.20
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.048Benzene1<0.048
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.14Bromochloromethane3<0.14
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.062Bromodichloromethane1<0.062
8260B P7E008911.0 5/6/17 20:50 KDMug/L 0.040Bromoform3<0.040
8260B P7E008911.0 5/6/17 20:50 KDMug/L 0.18Bromomethane10<0.18
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.075Carbon disulfide 100<0.075
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.11Carbon Tetrachloride 1<0.11
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.062Chlorobenzene3<0.062
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.22Chloroethane10<0.22
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.076Chloroform5<0.076
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.079Chloromethane1<0.079
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.056cis-1,2-Dichloroethylene 5<0.056
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 46 of 61
Laboratory Report
05/09/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
FactorUnitsMDL Analyst
11112 Branding Iron Place Project No.:
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040416-21
Prism Work Order: 7040416
Time Collected: 04/19/17 10:47
Time Submitted: 04/21/17 16:40
4304-MW9
43-04
SWSL
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.079cis-1,3-Dichloropropylene 1<0.079
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.081Dibromochloromethane3<0.081
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.065Dibromomethane10<0.065
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.061Ethylbenzene1<0.061
8260B P7E008911.0 5/6/17 20:50 KDMug/L 0.12m,p-Xylenes NE<0.12
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.065Methyl Butyl Ketone (2-Hexanone)50<0.065
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.24Methyl Ethyl Ketone (2-Butanone)100<0.24
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.33Methyl Iodide 10<0.33
8260B P7E008915.0 5/6/17 20:50 KDMug/L 0.078Methyl Isobutyl Ketone 100<0.078
8260B P7E008911.0 5/6/17 20:50 KDMug/L 0.083Methylene Chloride 1<0.083
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.044o-Xylene NE<0.044
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.047Styrene1<0.047
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.098Tetrachloroethylene1<0.098
8260B P7E00891105/6/17 20:50 KDMug/L 0.16TetrahydrofuranNE<0.16
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.044Toluene1<0.044
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.094trans-1,2-Dichloroethylene 5<0.094
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.070trans-1,3-Dichloropropylene 1<0.070
8260B P7E00891105/6/17 20:50 KDMug/L 0.12trans-1,4-Dichloro-2-butene 100<0.12
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.078Trichloroethylene1<0.078
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.062Trichlorofluoromethane1<0.062
8260B P7E008912.0 5/6/17 20:50 KDMug/L 0.060Vinyl acetate 50<0.060
8260B P7E008910.50 5/6/17 20:50 KDMug/L 0.097Vinyl chloride 1<0.097
8260B P7E008911.5 5/6/17 20:50 KDMug/L 0.15Xylenes, total 5<0.15
Surrogate Recovery Control Limits
80-12499 %4-Bromofluorobenzene
75-129101 %Dibromofluoromethane
77-12399 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 47 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0500 - 5030B
Blank (P7D0500-BLK1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 48 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0500 - 5030B
Blank (P7D0500-BLK1)Prepared: 04/28/17 Analyzed: 04/29/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10954.6
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10452.1
ug/L 50.00 77-123Surrogate: Toluene-d8 9949.7
LCS (P7D0500-BS1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1-Dichloroethylene ug/L21.6 0.50 20.00 70-154108
Benzene ug/L22.6 0.50 20.00 77-128113
Chlorobenzene ug/L22.2 0.50 20.00 78-119111
Tetrahydrofuran ug/L24.1 10 20.00 70-130121
Toluene ug/L22.4 0.50 20.00 76-131112
Trichloroethylene ug/L21.9 0.50 20.00 77-133109
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10853.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10050.0
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
LCS Dup (P7D0500-BSD1)Prepared: 04/28/17 Analyzed: 04/29/17
1,1-Dichloroethylene ug/L20.4 0.50 20.00 2070-154102 6
Benzene ug/L21.2 0.50 20.00 2077-128106 6
Chlorobenzene ug/L20.6 0.50 20.00 2078-119103 8
Tetrahydrofuran ug/L25.8 10 20.00 2070-130129 7
Toluene ug/L21.1 0.50 20.00 2076-131105 6
Trichloroethylene ug/L20.4 0.50 20.00 2077-133102 7
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10552.5
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 9447.2
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 49 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0039 - 5030B
Blank (P7E0039-BLK1)Prepared & Analyzed: 05/02/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 50 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0039 - 5030B
Blank (P7E0039-BLK1)Prepared & Analyzed: 05/02/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10552.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.6
ug/L 50.00 77-123Surrogate: Toluene-d8 10150.7
LCS (P7E0039-BS1)Prepared & Analyzed: 05/02/17
1,1-Dichloroethylene ug/L18.8 0.50 20.00 70-15494
Benzene ug/L21.0 0.50 20.00 77-128105
Chlorobenzene ug/L21.4 0.50 20.00 78-119107
Tetrahydrofuran ug/L19.7 10 20.00 70-13099
Toluene ug/L21.1 0.50 20.00 76-131106
Trichloroethylene ug/L20.1 0.50 20.00 77-133101
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10251.1
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
LCS Dup (P7E0039-BSD1)Prepared & Analyzed: 05/02/17
1,1-Dichloroethylene ug/L17.9 0.50 20.00 2070-15489 5
Benzene ug/L20.1 0.50 20.00 2077-128100 4
Chlorobenzene ug/L20.3 0.50 20.00 2078-119102 5
Tetrahydrofuran ug/L19.8 10 20.00 2070-13099 0.2
Toluene ug/L20.2 0.50 20.00 2076-131101 4
Trichloroethylene ug/L19.3 0.50 20.00 2077-13397 4
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10351.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.8
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 51 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0056 - 5030B
Blank (P7E0056-BLK1)Prepared & Analyzed: 05/03/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 52 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0056 - 5030B
Blank (P7E0056-BLK1)Prepared & Analyzed: 05/03/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10250.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10150.5
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.2
LCS (P7E0056-BS1)Prepared & Analyzed: 05/03/17
1,1-Dichloroethylene ug/L17.5 0.50 20.00 70-15488
Benzene ug/L20.6 0.50 20.00 77-128103
Chlorobenzene ug/L21.0 0.50 20.00 78-119105
Tetrahydrofuran ug/L19.8 10 20.00 70-13099
Toluene ug/L20.9 0.50 20.00 76-131105
Trichloroethylene ug/L20.4 0.50 20.00 77-133102
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9848.8
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.9
ug/L 50.00 77-123Surrogate: Toluene-d8 9949.5
LCS Dup (P7E0056-BSD1)Prepared & Analyzed: 05/03/17
1,1-Dichloroethylene ug/L16.8 0.50 20.00 2070-15484 4
Benzene ug/L19.6 0.50 20.00 2077-12898 5
Chlorobenzene ug/L19.9 0.50 20.00 2078-11999 5
Tetrahydrofuran ug/L19.2 10 20.00 2070-13096 3
Toluene ug/L20.0 0.50 20.00 2076-131100 5
Trichloroethylene ug/L19.3 0.50 20.00 2077-13397 5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10050.2
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.6
ug/L 50.00 77-123Surrogate: Toluene-d8 10050.0
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 53 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0089 - 5030B
Blank (P7E0089-BLK1)Prepared & Analyzed: 05/06/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,2,3-Trichloropropane ug/LBRL1.0
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Ethylbenzene ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Iodide ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
o-Xylene ug/LBRL0.50
Styrene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Tetrahydrofuran ug/LBRL10
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
trans-1,4-Dichloro-2-butene ug/LBRL10
Trichloroethylene ug/LBRL0.50
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 54 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7E0089 - 5030B
Blank (P7E0089-BLK1)Prepared & Analyzed: 05/06/17
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
Xylenes, total ug/LBRL1.5
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9647.9
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10050.1
ug/L 50.00 77-123Surrogate: Toluene-d8 9849.0
LCS (P7E0089-BS1)Prepared & Analyzed: 05/06/17
1,1-Dichloroethylene ug/L22.1 0.50 20.00 70-154110
Benzene ug/L20.7 0.50 20.00 77-128104
Chlorobenzene ug/L20.6 0.50 20.00 78-119103
Tetrahydrofuran ug/L18.4 10 20.00 70-13092
Toluene ug/L20.4 0.50 20.00 76-131102
Trichloroethylene ug/L21.4 0.50 20.00 77-133107
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9748.3
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10150.5
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
LCS Dup (P7E0089-BSD1)Prepared & Analyzed: 05/06/17
1,1-Dichloroethylene ug/L21.0 0.50 20.00 2070-154105 5
Benzene ug/L19.8 0.50 20.00 2077-12899 5
Chlorobenzene ug/L20.0 0.50 20.00 2078-119100 3
Tetrahydrofuran ug/L17.2 10 20.00 2070-13086 7
Toluene ug/L19.5 0.50 20.00 2076-13197 5
Trichloroethylene ug/L20.0 0.50 20.00 2077-133100 7
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9648.2
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.7
ug/L 50.00 77-123Surrogate: Toluene-d8 9848.8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 55 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals - Quality Control
Batch P7E0004 - 3005A
Blank (P7E0004-BLK1)Prepared: 05/01/17 Analyzed: 05/03/17
Arsenic ug/LBRL1.0
Barium ug/L0.622 5.0 J
Cadmium ug/LBRL1.0
Chromium ug/LBRL1.0
Lead ug/L0.660 1.0 Aa, J
Selenium ug/LBRL5.0
Silver ug/L0.0670 5.0 CCV, J
LCS (P7E0004-BS1)Prepared: 05/01/17 Analyzed: 05/03/17
Arsenic ug/L1091.0 100.0 80-120109
Barium ug/L1025.0 100.0 80-120102
Cadmium ug/L1091.0 100.0 80-120109
Chromium ug/L99.4 1.0 100.0 80-12099
Lead ug/L1111.0 100.0 80-120111
Selenium ug/L1055.0 100.0 80-120105
Silver ug/L1225.0 100.0 CCV, LH80-120122
Matrix Spike (P7E0004-MS1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L1121.0 100.0 BRL 75-125112
Barium ug/L1055.0 100.0 1.27 75-125104
Cadmium ug/L1111.0 100.0 BRL 75-125111
Chromium ug/L1031.0 100.0 0.118 75-125102
Lead ug/L1151.0 100.0 0.812 75-125114
Selenium ug/L1055.0 100.0 BRL 75-125105
Silver ug/L1265.0 100.0 BRL CCV, M75-125126
Matrix Spike Dup (P7E0004-MSD1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L1061.0 100.0 BRL 2075-125106 5
Barium ug/L1005.0 100.0 1.27 2075-12599 5
Cadmium ug/L1071.0 100.0 BRL 2075-125107 4
Chromium ug/L97.6 1.0 100.0 0.118 2075-12598 5
Lead ug/L1101.0 100.0 0.812 2075-125109 4
Selenium ug/L1015.0 100.0 BRL 2075-125101 4
Silver ug/L1215.0 100.0 BRL 20 CCV75-125121 4
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 56 of 61
5/9/17
Level II QC Report
11112 Branding Iron Place Project No: 43-04
Project: Central Carolina TireNautilus Geologic Consulting, PLLC
Wendell, NC 27591
Attn: Brian S. Boutin
Prism Work Order: 7040416
Time Submitted: 4/21/2017 4:40:00PM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals - Quality Control
Batch P7E0004 - 3005A
Post Spike (P7E0004-PS1)Prepared: 05/01/17 Analyzed: 05/03/17 Source: 7040416-02
Arsenic ug/L100 100.0 0.122 80-120100
Barium ug/L99.3 100.0 1.27 80-12098
Cadmium ug/L102 100.0 0.00100 80-120102
Chromium ug/L93.1 100.0 0.118 80-12093
Lead ug/L106 100.0 0.812 80-120105
Selenium ug/L94.3 100.0 0.176 80-12094
Silver ug/L109 100.0 0.0410 CCV80-120109
Batch P7E0008 - 7470A
Blank (P7E0008-BLK1)Prepared: 05/01/17 Analyzed: 05/02/17
Mercury ug/LBRL0.20
LCS (P7E0008-BS1)Prepared: 05/01/17 Analyzed: 05/02/17
Mercury ug/L9.51 0.20 9.375 80-120101
Matrix Spike (P7E0008-MS1)Prepared: 05/01/17 Analyzed: 05/02/17 Source: 7040416-02
Mercury ug/L9.27 0.20 9.375 BRL 80-12099
Matrix Spike Dup (P7E0008-MSD1)Prepared: 05/01/17 Analyzed: 05/02/17 Source: 7040416-02
Mercury ug/L8.97 0.20 9.375 BRL 2080-12096 3
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 57 of 61
Sample Extraction Data
Prep Method: 3005A
Lab Number Batch Date/TimeInitialFinal
P7E00047040416-02 05/01/17 8:155050mLmL
P7E00047040416-03 05/01/17 8:155050mLmL
P7E00047040416-04 05/01/17 8:155050mLmL
P7E00047040416-05 05/01/17 8:155050mLmL
P7E00047040416-06 05/01/17 8:155050mLmL
P7E00047040416-07 05/01/17 8:155050mLmL
P7E00047040416-08 05/01/17 8:155050mLmL
P7E00047040416-09 05/01/17 8:155050mLmL
P7E00047040416-10 05/01/17 8:155050mLmL
P7E00047040416-11 05/01/17 8:155050mLmL
P7E00047040416-12 05/01/17 8:155050mLmL
P7E00047040416-13 05/01/17 8:155050mLmL
P7E00047040416-14 05/01/17 8:155050mLmL
P7E00047040416-15 05/01/17 8:155050mLmL
P7E00047040416-16 05/01/17 8:155050mLmL
P7E00047040416-17 05/01/17 8:155050mLmL
P7E00047040416-18 05/01/17 8:155050mLmL
P7E00047040416-19 05/01/17 8:155050mLmL
P7E00047040416-20 05/01/17 8:155050mLmL
P7E00047040416-21 05/01/17 8:155050mLmL
Prep Method: 7470A
Lab Number Batch Date/TimeInitialFinal
P7E00087040416-02 05/01/17 9:452030mLmL
P7E00087040416-03 05/01/17 9:452030mLmL
P7E00087040416-04 05/01/17 9:452030mLmL
P7E00087040416-05 05/01/17 9:452030mLmL
P7E00087040416-06 05/01/17 9:452030mLmL
P7E00087040416-07 05/01/17 9:452030mLmL
P7E00087040416-08 05/01/17 9:452030mLmL
P7E00087040416-09 05/01/17 9:452030mLmL
P7E00087040416-10 05/01/17 9:452030mLmL
P7E00087040416-11 05/01/17 9:452030mLmL
P7E00087040416-12 05/01/17 9:452030mLmL
P7E00087040416-13 05/01/17 9:452030mLmL
P7E00087040416-14 05/01/17 9:452030mLmL
P7E00087040416-15 05/01/17 9:452030mLmL
P7E00087040416-16 05/01/17 9:452030mLmL
P7E00087040416-17 05/01/17 9:452030mLmL
P7E00087040416-18 05/01/17 9:452030mLmL
P7E00087040416-19 05/01/17 9:452030mLmL
P7E00087040416-20 05/01/17 9:452030mLmL
P7E00087040416-21 05/01/17 9:452030mLmL
Prep Method: 5030B
Lab Number Batch Date/TimeInitialFinal
P7D05007040416-01 04/28/17 14:121010mLmL
P7D05007040416-02 04/28/17 14:121010mLmL
P7D05007040416-03 04/28/17 14:121010mLmL
P7D05007040416-04 04/28/17 14:121010mLmL
P7E00397040416-05 05/02/17 10:091010mLmL
P7E00397040416-06 05/02/17 10:091010mLmL
P7E00397040416-07 05/02/17 10:091010mLmL
P7E00397040416-08 05/02/17 10:091010mLmL
P7E00397040416-09 05/02/17 10:091010mLmL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 58 of 61
Sample Extraction Data
Prep Method: 5030B
Lab Number Batch Date/TimeInitialFinal
P7E00397040416-10 05/02/17 10:091010mLmL
P7E00397040416-11 05/02/17 10:091010mLmL
P7E00567040416-12 05/03/17 10:351010mLmL
P7E00397040416-13 05/02/17 10:091010mLmL
P7E00567040416-14 05/03/17 10:351010mLmL
P7E00567040416-15 05/03/17 10:351010mLmL
P7E00567040416-16 05/03/17 10:351010mLmL
P7E00897040416-17 05/06/17 15:451010mLmL
P7E00897040416-18 05/06/17 15:451010mLmL
P7E00897040416-19 05/06/17 15:451010mLmL
P7E00897040416-20 05/06/17 15:451010mLmL
P7E00897040416-21 05/06/17 15:451010mLmL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 59 of 61
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