HomeMy WebLinkAbout3405_RJReynolds_GWMR_DIN27782_20160906The business of sustainability
R.J. Reynolds Tobacco Company
Groundwater and Surface Water Monitoring
Semi-Annual Summary Report – September 2016
Edwards Road Landfill - Permit # 34-05
Edwards Road
Rural Hall, Forsyth County,
North Carolina
December 2016
ERM NC, Inc.
15720 Brixham Hill Avenue
Suite 120
Charlotte, NC 28277
(704) 541-8345 December 20, 2016
North Carolina Department of Environmental Quality
Division of Waste Management
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Attention: Ms. Jaclynne Drummond
Via Email
Subject: Groundwater and Surface Water Monitoring
Semi-Annual Summary Report – March 2016
Edwards Road Landfill – Permit #34-05
Edwards Road
Rural Hall, Forsyth County, North Carolina
Dear Ms. Drummond:
On behalf of R.J. Reynolds Tobacco Company, ERM NC, Inc. (ERM) is submitting the
summary report for the September 2016 groundwater and surface water monitoring event
associated with the subject property. Please contact Mr. Max Hopkins of R.J. Reynolds
Tobacco Company at 336-741-6932 or me if you have any questions or comments.
Sincerely,
Alan Martin, P.G.
Project Manager
Attachments:
Environmental Monitoring Reporting Form
Groundwater and Surface Water Monitoring Semi-Annual Summary Report
cc: Mr. Max Hopkins - R.J. Reynolds Tobacco Company
Mr. Tom Wilson - ERM
R.J. Reynolds Tobacco Company
Groundwater and Surface Water Monitoring
Semi-Annual Summary Report –
September 2016
Edwards Road Landfill - Permit # 34-05
Edwards Road
Rural Hall, Forsyth County,
North Carolina
December 19, 2016
Project No. 0333036
Alan Martin, P.G. Project Manager
Thomas M. Wilson, P.G.
Principal-in-Charge
ERM NC, Inc.
15720 Brixham Hill Avenue
Suite 120
Charlotte, North Carolina 28277
(704) 541-8345
ERM i 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
TABLE OF CONTENTS
1.0 INTRODUCTION ............................................................................................................. 1
2.0 HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY .................... 1
3.0 SUMMARY OF MONITORING PROGRAM ................................................................ 2
4.0 DESCRIPTION OF WATER QUALITY CONDITIONS ............................................... 3
4.1 SITE HYDROGEOLOGY ..................................................................................... 3
4.2 GROUNDWATER ................................................................................................ 4
4.3 SURFACE WATER ............................................................................................... 5
5.0 PRELIMINARY ANALYSIS ............................................................................................ 5
6.0 REFERENCES ................................................................................................................... 8
LIST OF FIGURES
1 Site Location Plan
2 Site Plan
3 Groundwater Flow Directions
4 Groundwater Sampling Results –September 2016
5 Surface Water Sampling Results – September 2016
6 Sulfate Isocontour Map – Groundwater
7 Hydrogeologic Conceptual Model
8 Sulfate Trends – Groundwater
9 Sulfate Trends – Surface Water
LIST OF TABLES
1 Monitor Well Construction Details
2 Groundwater Elevations
3 Groundwater and Surface Water Sampling Event Summary Data
4 Groundwater Field Parameters
LIST OF APPENDICES
A Historical Groundwater and Surface Water Quality Analytical Data
B Laboratory Data Sheets
C Groundwater Sampling Logs
ERM 1 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
1.0 INTRODUCTION
In accordance with the February 4, 2014 Corrective Action Plan (ERM NC, Inc.) and the
Industrial Solid Waste Landfill Facility Permit No. 34-05-indus-1986 as amended through
August 12, 2011, this report presents the results of the September 2016 groundwater
and surface water sampling event conducted at the closed Edwards Road Landfill
previously operated by R.J. Reynolds Tobacco Company. The closed landfill is located
northeast of the jurisdictional boundaries of Rural Hall, Forsyth County, North
Carolina and the location of the Site along with topographic map coverage of the
vicinity are shown on Figure 1.
Historical monitoring data indicate the occurrence of certain inorganic compounds in
excess of the North Carolina Groundwater Standards (15A NCAC 2L) and Surface
Water Standards (15A NCAC 2B) in portions of the landfill site. Current monitoring
data indicate that no exceedances of applicable Surface Water Standards are present.
A Corrective Action Plan (ERM) to restore groundwater quality beyond the compliance
boundary, to stop unacceptable impacts to the adjacent surface waters, and to reduce
the overall groundwater contamination at the facility was approved by the North
Carolina Department of Environmental Quality (NCDEQ, formerly known as
Department of Environment and Natural Resources) on February 19, 2014. The
selected remedy includes source area contaminant control via the previous installation
of the synthetic liner (cap) over the limits of waste plus drainage improvements
(completed in 2012) to minimize rainfall infiltration, leachate generation and discharge
of constituents to groundwater, to allow intrinsic remediation of the existing affected-
groundwater.
The September 2016 groundwater and surface water sampling event represents the
eighth semi-annual monitoring event conducted at the site since the completion of the
synthetic cap installation and the drainage improvements.
2.0 HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY
Groundwater and surface water quality monitoring has been conducted in the vicinity
of the Edwards Road Landfill since 1989 in accordance with the conditions of Permit
Number 34-05 and subsequent to the closure of the landfill, in accordance with the
approved Post Closure Monitoring Plan. An updated water quality monitoring plan
presented in the February 2014 CAP (ERM) was approved by NCDEQ on February 19,
2014 and is summarized in Section 3.0. Figure 2 depicts the locations of the
groundwater monitor wells and surface water sampling locations and Table 1 presents
a summary of available well construction details. Historical laboratory analytical
results for available groundwater and surface water samples are summarized in
Appendix A.
ERM 2 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
3.0 SUMMARY OF MONITORING PROGRAM
Routine groundwater and surface water monitoring activities were conducted on
September 6 - 9, 2016 and are summarized in the following table:
Sampling and Analyses Plan
Sample
Location I.D.
Analytical Parameters
Metals 1
(EPA 6020B/
7074)
Sulfate
(EPA 300.0 )
Total
Dissolved
Solids
(SM 2540C)
Field
Parameters 2
Groundwater:
W-1
W-2
W-3
W-3B
W-5 -- -- -- --
W-6
W-7
W-8
W-9
PW-1
PZ-1 3 3 3 3 --
PZ-2 --
PZ-3 3 3 3 3 --
PZ-4 3 3 3 3 --
PZ-5 --
Subtotal 14 14 14 9
Surface Water:
SS-01
SS-02
SS-10 -- -- -- --
SS-15 -- -- -- --
SS-20
SS-25
SS-30
SS-40
SS-50 -- --
SS-60
SS-70
SS-80
SS-90
Subtotal 11 10 10 11
TOTAL 25 24 24 20
1 Aluminum, barium, cadmium, chromium (total), iron, lead, manganese and selenium.
2 Field parameters include temperature, pH, conductivity, turbidity, dissolved oxygen, and oxidation-reduction potential (Eh).
3 PZ-1 and PZ-4 were dry during the September 2016 sampling event and PZ-3 was destroyed between March and September 2016.
Depth-to-water measurements and groundwater elevations for available monitor wells
from the September 2016 sampling event are presented in Table 2. Groundwater flow
directions are presented on Figure 3. Groundwater and surface water analytical data
from the September 2016 sampling event are presented in Table 3. Field collection
parameters are provided in Table 4. Historical analytical data for both groundwater
and surface water are presented in Appendix A. Laboratory data sheets for the
September 2016 sampling event are presented in Appendix B. Copies of the sample
ERM 3 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
logs are provided in Appendix C. Groundwater and surface water sample analytical
results from the September 2016 sampling event are presented on Figures 4 and 5,
respectively. Figure 6 depicts the isoconcentration contours of sulfates in groundwater
at the site and Figure 7 presents a hydrogeologic conceptual site model and cross-
section. Sulfate concentrations in groundwater and surface water over time are
presented graphically on Figures 8 and 9, respectively.
4.0 DESCRIPTION OF WATER QUALITY CONDITIONS
4.1 SITE HYDROGEOLOGY
The site geology consists of fractured bedrock (gneiss and schist) overlain by partially
weathered rock and a mantle of residual soils near the surface. The depth to bedrock
beneath the site generally ranges from 10 to 50 feet bgs. The first occurrence of
groundwater beneath the upper portion of the site is within the fractured bedrock. In
the lower portions of the site near the streams, groundwater is encountered within the
partially weathered rock above the top of hard bedrock (transition zone).
Shallow groundwater beneath the Site migrates either along the top of bedrock or
along the permeable zones within the shallow fractured bedrock zone and discharges
into nearby creeks, namely Leak Creek and its tributaries. The regional groundwater
flow regime within the lower portion of the deep bedrock aquifer is north-eastward
toward the nearest regional drainage feature, Town Fork Creek. The depth to
groundwater in the top-of-rock aquifer zone ranges from approximately 0 feet at the
creeks to 13 feet in shallow monitor wells. The depth to water in the bedrock aquifer
ranges from artesian conditions to approximately 110 feet below ground surface in the
measured wells.
Using September 2016 depth to water measurements, site groundwater elevations and
hydraulic gradients for the Site were calculated as summarized below.
Horizontal Hydraulic Gradient - Saprolite/PWR
Well
Designation
September 9, 2016
Reference
Elevation
Depth to
Water Head Elevation
Head
Change
Distance
Change
Hydraulic
Gradient
(ft MSL) (ft) (ft) (ft) (ft) (ft/ft)
W-1 822.68 14.92 807.76 27.76 180 0.1542
Leak Creek1 780 0.00 780.0
W-3 804.43 3.31 801.12 15.62 80 0.1953
Leak Creek1 785.5 0.00 785.5
Average Hydraulic Gradient 0.1748
1 - Leak Creek bed elevation represents groundwater discharge line
Based on the September 2016 hydraulic gradients, the groundwater flow rate (seepage
velocity) in the saprolite/PWR aquifer zone was calculated as summarized below.
ERM 4 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
Groundwater Seepage Velocity Calculation = Ki/ne
where:
K = hydraulic conductivity 0.080 ft/day (estimated)
i = horizontal hydraulic gradient 0.1748 ft/ft (measured)
ne = effective porosity 0.25 (estimated)
Groundwater Seepage Velocity (Saprolite/PWR) =
= (0.08) (0.1748) / (0.25) = 5.59E-02 ft/day
or 20 ft/year
The widely spaced locations of the bedrock monitor wells at the Site does not allow for
calculation of the hydraulic gradient and groundwater flow rate of the bedrock aquifer.
4.2 GROUNDWATER
During the September 2016 groundwater sampling event, nine monitor wells were
sampled utilizing a low flow, low volume sample collection technique. During the
event, two piezometers were sampled using a bailer due to insufficient volume for low
flow sampling procedures. Piezometers PZ-1 and PZ-4 were dry during the sampling
event. Piezometer PZ-3 was destroyed between the March and September 2016
sampling event.
Presently, groundwater within the Site contains concentrations of sulfates, total
dissolved solids, and two metals above the applicable North Carolina groundwater
standards (NC 2L standard). Sulfate, the primary constituent related to the landfill,
was detected in three groundwater samples in excess of the NC 2L standard. Iron and
manganese were detected in 7 of the 11 groundwater samples in excess of the NC 2L
standard. None of the other metals (barium, cadmium, chromium (total), lead and
selenium) were detected in any of the groundwater samples in excess of their
respective NC 2L standard. Dissolved solids were detected in three of the 14
groundwater samples in excess of the NC 2L standard. The elevated concentrations of
iron and manganese in samples from the Site monitor wells appear to be attributable to
their natural occurrence in groundwater as indicated by historical sample results from
onsite background monitor wells (W-6 and former W-4). The elevated concentrations
of iron and manganese in the piezometer samples are attributed to very high observed
turbidity and the inability to sample utilizing low flow procedures, due to insufficient
volume.
As noted in Section 1.0, installation of the synthetic cap and construction of drainage
improvements over the limits of waste were completed in September 2012. The
September 2016 samples were collected approximately 4 years after the cap
installation. Sulfate concentrations from the September 2016 samples from the shallow
monitor wells W-1 and W-2, located near the limits of waste, indicate a continuing
overall trend of decreasing sulfate levels since the installation of the synthetic landfill
cap in 2012. The September 2016 sulfate concentrations from shallow monitor well W-
3, also near the limits of waste, indicate a fluctuating but overall stable trend of sulfate
levels since completion of the landfill cap installation in September 2012. During the
ERM 5 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
same period, sulfate concentrations at bedrock monitor well W-3B, located adjacent to
W-3, continue to decrease. Iron, manganese and total dissolved solids concentrations
in W-1, W-2, and W-3 remained stable or decreased compared to historical sample
results prior to installation of the synthetic cap.
Overall, the September 2016 groundwater quality results and the historical
concentration trends indicate that groundwater quality improvements are evident in
most monitor wells located at the perimeter of the landfill.
4.3 SURFACE WATER
During the September 2016 sampling event, 11 surface water samples were collected.
The September 2016 surface water monitoring results indicate that there are no surface
water quality impacts attributable to the landfill. Concentrations of sulfates and total
dissolved solids in all 11 samples were below the applicable North Carolina surface
water standards (NC 2B standards). Manganese was below the applicable North
Carolina surface water standards (NC 2B standards) in each of the 11 samples. Iron
was below the applicable North Carolina surface water standards (NC 2B standards) in
5 of the 11 samples. Sulfate concentrations from the surface water samples with
historical results display a generally declining to stable trend when compared to the
September 2012 surface water sample results. Laboratory results from the surface
water samples collected indicate concentrations of aluminum in exceedance of the
applicable North Carolina surface water standard (NC 2B standard) at 9 of the 11
sample points, including the upstream (background) samples at points SS-20 and SS-
50.
Overall, September 2016 surface water quality results confirm that the corrective
actions at the site have been effective for the remediation of the surface water quality at
the site. Compared to upstream surface water quality, there have been no exceedances
of surface water quality standards in the streams since 2014.
5.0 PRELIMINARY ANALYSIS
The September 2016 monitoring results demonstrate:
Sulfate, total dissolved solids and two metals in groundwater samples exceed the
NC 2L standards. Concentrations of all detected analytes in groundwater were
within the normal range of historical fluctuations, with the exception of iron and
manganese values detected in the two piezometers. The elevated concentrations of
iron, manganese, barium, and cadmium in the piezometers are not considered
representative because the levels are attributed to very high observed turbidity and
the inability to sample utilizing low flow procedures, due to insufficient volume.
ERM 6 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
Sulfate, manganese, iron, and total dissolved solids concentrations in groundwater
samples from the Site have generally remained stable or have trended downward
compared to results since completion of the landfill cap installation in September
2012.
No elevated concentrations of sulfates, metals or total dissolved solids have been
detected in the off-site groundwater sample. Sulfate levels observed in the off-site
monitoring well W-9 to the southeast and sidegradient of the landfill are comparable
to background levels observed in the upgradient monitoring well W-6.
Concentrations of sulfates and total dissolved solids in the 11 surface water samples
did not exceed the applicable NC 2B standards. Concentrations of iron detected in
surface water samples exceeded the NC 2B standards at 6 of the 11 locations,
including the two upstream, background locations. Concentrations of aluminum
detected in surface water samples exceeded the NC 2B standards at 9 of the 11
locations, including the two upstream, background locations. The presence of
aluminum in the surface water samples is attributed to its natural occurrence in
Piedmont soils and groundwater and is not related to the landfill. Concentrations of
other detected analytes in surface water were within the normal range of historical
fluctuations.
Sulfate, manganese, iron, and total dissolved solids concentrations in surface water
samples from the Site have generally trended downward or remained stable
compared to historical results.
Installation of the synthetic cap and construction of drainage improvements over the
limits of waste were completed in September 2012. The September 2016 samples were
collected approximately 4 years after the cap installation and indicate that
groundwater quality improvements are evident in most of the monitoring wells
located at the landfill perimeter. The September 2016 surface water quality results
indicate that there are no surface water quality impacts attributable to the landfill. The
water quality improvements at the site indicate that the cap installation and the
drainage improvements at the landfill are effective remedial measures.
The schedule for routine monitoring activities is summarized below.
ERM 7 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
Activity
Target Completion Date
Conduct Semi-Annual Water Quality Monitoring Event March 2017
Submit Water Quality Monitoring Summary Report to NCDEQ June 2017
Conduct Semi-Annual Water Quality Monitoring Event September 2017
Submit Water Quality Monitoring Summary Report to NCDEQ December 2017
Conduct Semi-Annual Water Quality Monitoring Event March 2018
Submit Water Quality Monitoring Summary Report to NCDEQ June 2018
Conduct Semi-Annual Water Quality Monitoring Event September 2018
Submit Water Quality Monitoring Summary Report to NCDEQ December 2018
ERM 8 2016-09 EDWARDS RD LF RURAL HALL GW REPORT R1.DOCX
6.0 REFERENCES
Date Title Source
1986-05-29 Solid Waste Permit No. 34-05 issued to R.J. Reynolds Tobacco Company NCDENR
1999-10-19 R. J. Reynolds Tobacco Company Ash Landfill Transition Plan Geo-Environmental
Consultants, Inc.
2000-01-25
Work Plan for Upgrading Groundwater Monitoring, Phase II Ash Fill Area Geo-Environmental
Consultants, Inc.
2000-03-13 Upgrade of Groundwater Monitoring Program, Phase II Ash Fill Area Shield Environmental
Associates, Inc.
2001-01-02 Modifications to Transition Plan, Permit #34-05 Shield Environmental
Associates, Inc.
2003-12-23 Post Closure Cover Maintenance Plan, Permit #34-05 Shield Environmental
Associates, Inc.
2009-04-17 Compliance Order with Administrative Penalty, Facility #34-05 NCDENR
2009-07-17 Preliminary Site Assessment Work Plan, Facility #34-05 ERM
2009-10-29 Summary Report – Preliminary Site Assessment, Facility #34-05 ERM
2010-11-15 Letter correspondence to NCDENR DWM regarding Off-Site Well
Locations, Facility #34-05
ERM
2011-03-10 Summary Report – Phase II Site Assessment ERM
2011-06-14 Proposed Closure Modification - Edwards Road Landfill, Permit No. 34-05 ERM
2011-08-12 Regulatory approval Letter Of Closure Modification, Permit No. 34-05 NCDENR
2012-04-30 Summary Report – Ground Water Modelling for Site Assessment ERM
2012-09-21 Construction Quality Assurance for Closure Modification, Permit No. 34-05 ERM
2012-10-09 Letter correspondence to NCDENR regarding Groundwater Modeling &
Water Quality Monitoring, Facility #34-05
ERM
2012-11-07 Groundwater Corrective Action Permit Modification Application ERM
2013-10-01 Groundwater Corrective Action Application and Revised Groundwater Modeling
Scenarios
ERM
2013-10-10 Regulatory approval of Groundwater Corrective Action Application NCDENR
2013-10-11 Regulatory approval of Construction Quality Assurance for Closure
Modification, Permit No. 34-05
NCDENR
2014-02-04 Corrective Action Plan, Permit No. 34-05 ERM
2014-02-19 Regulatory approval of Corrective Action Plan NCDENR
Various Groundwater and Surface Water Monitoring Summary Reports – 2010-present ERM
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T
R
A
T
I
O
N
S
-
M
O
S
T
R
E
C
E
N
T
(µg /L )
PI
E
Z
O
M
E
T
E
R
S SURFACE WATER
`
809
810
811
812
813
814
815
816
817
818
0
500,000
1,000,000
1,500,000
2,000,000
2,500,000
3,000,000
3,500,000
4,000,000
MONITORING WELL W-2
SAPROLITE / PWR AQUIFER Synthetic cap
installed 3Q2012
ft
AMSL ug/L
SULFATE TRENDS - GROUNDWATER
EDWARDS ROAD LANDFILL - PERMIT # 34-05
RURAL HALL, NORTH CAROLINA 8 ERM NC, Inc.
FIGURE
Sulfates
LEGEND
Total Dissolved Solids
NC2L GW STD NC2B SW STD
250,000 ug/L 250,000 ug/L
807
808
809
810
811
812
813
814
815
816
0
500,000
1,000,000
1,500,000
2,000,000
2,500,000
3,000,000
3,500,000
4,000,000
4,500,000
MONITORING WELL W-1
SAPROLITE AQUIFER Synthetic cap
installed 3Q2012
ft
AMSL ug/L
500,000 ug/L 500,000 ug/L
796
797
798
799
800
801
802
803
804
805
0
200,000
400,000
600,000
800,000
1,000,000
1,200,000
1,400,000
1,600,000
MONITORING WELL W-3
SAPROLITE / PWR AQUIFER Synthetic cap
installed 3Q2012
ft
AMSL ug/L
801
802
803
804
805
806
807
808
809
810
0
200,000
400,000
600,000
800,000
1,000,000
1,200,000 MONITORING WELL W-3B
BEDROCK AQUIFER Synthetic cap
installed 3Q2012
ft AMSL ug/L
GW Elevation
>804.53 (artesian)
874
876
878
880
882
884
886
888
0
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000 BACKGROUND MONITORING WELL W-4 & W-6
BEDROCK AQUIFER Synthetic cap
installed 3Q2012
ft AMSL ug/L
W-4: 1995-2003 W-6: 2003-Present
832
833
834
835
836
837
838
839
840
841
0
50,000
100,000
150,000
200,000
250,000 MONITORING WELL W-7
Synthetic cap
installed 3Q2012
BEDROCK AQUIFER, Installed 4Q2010
ft AMSL ug/L
800
802
804
806
808
810
812
0
50,000
100,000
150,000
200,000
250,000
300,000
350,000
MONITORING WELL W-8
PWR AQUIFER, Installed 4Q2010
Synthetic cap
installed 3Q2012
ft
AMSL ug/L
Groundwater Table Elevation (above Mean Sea Level)
796
798
800
802
804
806
0
50,000
100,000
150,000
200,000
250,000
300,000
350,000
MONITORING WELL W-9
BEDROCK AQUIFER, Installed 4Q2010
Synthetic cap
installed 3Q2012
ft
AMSL ug/L
850
852
854
856
858
860
862
864
866
868
870
0
500,000
1,000,000
1,500,000
2,000,000
2,500,000
3,000,000
3,500,000
MONITORING WELL PW-1
BEDROCK AQUIFER
Synthetic cap
installed 3Q2012
ft
AMSL ug/L
`
SULFATE TRENDS - SURFACE WATER
EDWARDS ROAD LANDFILL - PERMIT # 34-05
RURAL HALL, NORTH CAROLINA 9 ERM NC, Inc.
FIGURE
Sulfates
LEGEND
Total Dissolved Solids
NC2L GW STD NC2B SW STD
250,000 ug/L 250,000 ug/L
0
50,000
100,000
150,000
200,000
250,000
300,000
350,000
400,000 SURFACE WATER SS-01
Synthetic cap
installed 3Q2012
ug/L
0
20,000
40,000
60,000
80,000
100,000
120,000
140,000
160,000
180,000 SURFACE WATER SS-25
Synthetic cap installed 3Q2012
ug/L
0
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000 SURFACE WATER SS-60
Synthetic cap
installed 3Q2012
ug/L
0
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000
900,000
1,000,000 SURFACE WATER SS-02
Synthetic cap
installed 3Q2012
ug/L
0
50,000
100,000
150,000
200,000
250,000
300,000
350,000
400,000 SURFACE WATER SS-30
Synthetic cap installed 3Q2012
ug/L
0
50,000
100,000
150,000
200,000
250,000
300,000 SURFACE WATER SS-80
Synthetic cap
installed 3Q2012
ug/L
0
100,000
200,000
300,000
400,000
500,000
600,000 SURFACE WATER SS-90
Synthetic cap
installed 3Q2012
ug/L
0
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000 SURFACE WATER SS-40
Synthetic cap
installed 3Q2012
ug/L
0
50000
100000
150000
200000
250000 SURFACE WATER SS-70
Synthetic cap
installed 3Q2012
ug/L
500,000 ug/L 500,000 ug/L
TABLES
TA
B
L
E
1
MO
N
I
T
O
R
W
E
L
L
C
O
N
S
T
R
U
C
T
I
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D
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I
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S
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W
A
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-
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3
4
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0
5
RU
R
A
L
H
A
L
L
,
N
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T
H
C
A
R
O
L
I
N
A
Page 1 of 1
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2
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Page 1 of 2
Ga
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TABLE 3
GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS - SEPTEMBER 2016
EDWARDS ROAD LANDFILL - PERMIT 34-05
RURAL HALL, NORTH CAROLINA Page 1 of 1
x`Date
A
l
u
m
i
n
u
m
B
a
r
i
u
m
C
a
d
m
i
u
m
C
h
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o
m
i
u
m
(
T
o
t
a
l
)
I
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o
n
L
e
a
d
M
a
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g
a
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S
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f
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D
i
s
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o
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d
S
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i
d
s
NE 700 2 10 300 15 50 20 250,000 500,000
NE 100 1 10 300 10 50 10 250,000 NE
NE 2000 5 100 NE 15 NE 50 NE NE
87 1,000 2 50 1,000 25 200 5 250,000 500,000
GROUND WATER MONITORING WELLS
PW-1 (21'-326' interval) 9/6/16 250 42 0.12 <5 5,300 <1 3,300 2.5 840,000 1,900,000
W-1 9/8/16 <40 22 0.38 <5 1,400 <1 4,800 <1 1,100,000 2,500,000
W-2 9/8/16 1,900 190 <0.1 <5 3,200 <1 31 <1 14,000 230,000
W-3 9/8/16 <40 29 <0.1 <5 300 <1 320 2.7 360,000 840,000
W-3B 9/8/16 <40 45 <0.1 <5 340 <1 380 <1 71,000 380,000
W-3B (Dup-02) 9/8/16 <40 46 <0.1 <5 350 <1 380 1.1 74,000 370,000
W-6 9/6/16 62 37 <0.1 <5 110 <1 <5 <1 9,900 260,000
W-7 9/6/16 260 130 <0.1 <5 1,800 <1 53 <1 9,800 89,000
W-8 9/7/16 1900 280 <0.1 7.9 4,100 <1 60 4.0 64,000 200,000
W-9 9/6/16 74 97 <0.1 <5 39 <1 <5 <1 8,400 260,000
PZ-1 9/7/16 Dry, no sample collected -- -- -- -- -- -- --
PZ-2 9/7/16 1,900 230 1.3 <5 19,000 8.5 4,500 <5 59,000 240,000
PZ-3 9/7/16 Damaged, no sample collected.-- -- -- -- -- --
PZ-4 9/7/16 Dry, no sample collected -- -- -- -- -- -- --
PZ-5 9/7/16 740 58 0.27 <5 6,800 <1 120 <1 28,000 110,000
SURFACE WATER
SS-01 9/7/16 57 72 <0.1 <5 210 <1 5.2 <1 32,000 210,000
SS-01 (Dup-01) 9/7/16 71 67 <0.1 <5 220 <1 6.3 <1 35,000 200,000
SS-02 9/7/16 150 81 <0.1 <5 490 <1 44 <1 86,000 300,000
SS-20 9/7/16 310 59 <0.1 <5 1,100 <1 36 <1 1,600 89,000
SS-25 9/7/16 1,400 77 <0.1 <5 3,200 <1 81 <1 1,700 86,000
SS-30 9/7/16 470 70 <0.1 <5 970 <1 44 <1 48,000 270,000
SS-40 9/7/16 540 94 <0.1 <5 1,300 <1 100 <1 78,000 290,000
SS-50 9/7/16 410 49 <0.1 <5 2,900 <1 180 <1 <1000 99,000
SS-60 9/7/16 780 130 <0.1 <5 2,400 <1 160 <1 250,000 490,000
SS-70 9/7/16 160 52 <0.1 <5 470 <1 18 <1 1,600 81,000
SS-80 9/7/16 140 63 <0.1 <5 430 <1 9.7 <1 13,000 110,000
SS-90 9/7/16 40 73 <0.1 <5 230 <1 17 <1 49,000 200,000
All concentrations in micrograms per liter (ug/L) unless 1 - No freshwater aquatic life standard established. Water Supply criteria presented.
otherwise noted. Bold indicates exceedance of Solid Waste Section Limits (SWSL)
--- Not sampled Gray background indicates exceedance of applicable NC Ground Water or
NE - Not established Surface Water Standard
Piezometer PZ-01 replaced prior to March 2016 sampling event
Sulfate and Dissolved Solids not analyzed for sample SS-50 due to laboratory error
Elevated concentrations of Fe, Mn, Ba, Cd, Cr and Pb in piezometer samples attributed
to high turbidity resulting from inability to low-flow sample due to insufficient water volume.
NC 2L Ground Water Standard
Solid Waste Section Limit
NC 2B Surface Water Standard
Fed. Maximum Contaminant Level
11 1 1
Tables RJRT Ash LF.xlsx/Table 3-Event Data 2016-09
TABLE 4
GROUNDWATER AND SURFACE WATER FIELD PARAMETER RESULTS -
SEPTEMBER 2016
EDWARDS ROAD LANDFILL - PERMIT 34-05
RURAL HALL, NORTH CAROLINA
Page 1 of 1
Sample
Location / ID Date
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)
6.5 - 8.5 NE NE NE NE NE
NE NE NE NE NE NE
6.0 - 9.0 NE NE 50 NE >5.0
GROUND WATER MONITORING WELLS
PW-1 (21'-326' interval) 9/6/16 6.7 17.9 2,080 1.6 -2 0.8
W-1 9/8/16 6.8 22.3 2,905 1.8 -2 0.8
W-2 9/8/16 6.6 17.2 116 >1000 101 1.9
W-3 9/8/16 6.4 20.8 1,048 0.5 88 1.0
W-3B 9/8/16 7.3 21.4 538 0.4 62 0.7
W-6 9/6/16 10.1 17.5 393 2.2 -14 0.4
W-7 9/6/16 7.1 16.8 206 20.5 89 3.1
W-8 9/7/16 6.3 20.1 240 9.6 98 6.5
W-9 9/6/16 11.8 16.6 754 2.0 -106 0.7
PZ-1 9/7/16
PZ-2 9/7/16
PZ-3 9/7/16
PZ-4 9/7/16
PZ-5 9/7/16
SURFACE WATER
SS-01 9/7/16 8.6 21.9 298 3.6 49 8.1
SS-02 9/7/16 8.5 21.8 452 4.6 89 8.4
SS-20 9/7/16 7.6 19.4 80 3.2 59 8.4
SS-25 9/7/16 8.0 19.7 64 2.9 43 8.2
SS-30 9/7/16 8.5 21.6 357 2.8 48 8.5
SS-40 9/7/16 8.2 21.0 427 3.2 121 7.7
SS-50 9/7/16 8.0 22.8 121 3.6 50 6.9
SS-60 9/7/16 7.5 20.1 666 4.7 39 6.5
SS-70 9/7/16 7.5 19.9 93 5.3 26 7.6
SS-80 9/7/16 7.7 21.0 98 2.7 53 8.2
SS-90 9/7/16 8.0 20.8 286 1.8 48 9.0
NE - Not established NM - Not measured
Insufficient volume available for field parameters
Insufficient volume available for field parameters
Insufficient volume available for field parameters
NC 2L Ground Water Standard
Solid Waste Section Limit
NC 2B Surface Water Standard
Insufficient volume available for field parameters
Insufficient volume available for field parameters
Tables RJRT Ash LF.xlsx/Table 4-Field Parameters2016-09
APPENDIX A
HISTORICAL
GROUNDWATER AND
SURFACE WATER QUALITY
ANALYTICAL DATA
AP
P
E
N
D
I
X
A
1
GR
O
U
N
D
W
A
T
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R
A
N
A
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T
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A
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Page 1 of 8
Sa
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/
I
D
D
a
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e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
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-
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0
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71
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3
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6
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3
1
9
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3
1
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------
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2
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6
1
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0
34
6
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.
0
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.
0
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2
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9
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0
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0
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2
6
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3
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3
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0
0
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1
2
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0
0
0
6
.
2
2
0
.
3
4
2
5
------
3/
2
6
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1
9
9
2
2
,
8
5
0
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0
73
6
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.
0
<
2
0
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3
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.
0
1,
8
3
0
0
.
3
2
2
1
.
9
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0
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1,
2
5
0
1
2
3
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0
0
0
4
8
2
,
0
0
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1
4
,
0
0
0
6
.
6
9
.
3
6
8
2
------
9/
3
0
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1
9
9
2
--
<
1
0
12
0
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.
0
<
2
0
<
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<
5
.
0
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0
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2
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2
292,000
7
9
8
,
0
0
0
5,000
5
.
9
1
7
.
8
1
,
1
5
3
------
3/
3
1
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1
9
9
3
3
6
4
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0
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7
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.
0
<
2
0
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3
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0
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2
3
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2
0
13
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2
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0
33
55
0
486,000
1
,
1
6
9
,
0
0
0
33,000
5
.
5
1
6
.
1
1
,
5
8
7
------
9/
1
7
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1
9
9
3
28
,
6
0
0
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0
69
7
3
.
8
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0
44
5
9
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7
0
0
1
3
3
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4
9
0
<0
.
2
0
5.
1
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0
19
5
92
5
565,000
1
,
6
4
3
,
0
0
0
6,000
5
.
9
1
8
.
0
2
,
3
1
0
------
we
l
l
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e
p
l
a
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e
d
1
1
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9
3
3
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3
0
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1
9
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4
5,
3
2
0
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0
54
5
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.
0
<
2
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20
1
8
,
8
0
0
8
50
5
<0
.
2
0
6
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0
10
7
39
0
633,000 1,680,000 --5.6
1
5
.
2
1
,
2
5
0
------
9/
3
0
/
1
9
9
4
1
,
8
1
0
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0
<
2
5
0
<
2
.
0
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0
22
9
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6
0
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.
0
4,
4
7
0
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.
2
0
13
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0
19
45
0
758,000
2
,
4
2
0
,
0
0
0
123,000
6
.
0
1
8
.
1
3
,
0
1
0
------
3/
3
1
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1
9
9
5
24
,
0
0
0
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0
1,
2
5
0
<2
.
0
<
2
0
26
5
3
,
9
0
0
1
1
1
,
5
8
0
<0
.
2
0
12
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0
11
5
85
0
797,000
2
,
1
4
0
,
0
0
0
--5.9
1
5
.
8
2
,
8
2
0
------
9/
2
9
/
1
9
9
5
7,
6
5
0
<1
0
36
7
4
<2
0
24
1
8
,
8
0
0
10
4,
0
2
0
<0
.
2
0
12
<1
0
--
1,
0
0
0
464,000
2
,
7
8
0
,
0
0
0
4,040
4
.
5
1
6
.
2
3
,
7
2
0
------
3/
2
0
/
1
9
9
6
14
9
,
0
0
0
<1
0
96
0
5
0
2
0
0
2
2
0
--
63
1
1
,
4
0
0
<0
.
2
0
<
1
0
<
1
0
69
5
--
2,320,000
2
,
6
7
0
,
0
0
0
8,750
6
.
5
1
5
.
0
3
,
0
6
0
------
9/
2
7
/
1
9
9
6
7,
1
1
0
<1
0
<
2
5
0
<
2
.
0
<
2
0
<
2
0
22
,
6
0
0
7
2,
3
0
0
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.
2
0
<
1
0
<
1
0
51
1,
5
2
0
1,320,000
2
,
9
7
0
,
0
0
0
3,810
6
.
1
1
9
.
0
3
,
3
5
0
------
3/
2
9
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1
9
9
7
2
,
9
9
0
<1
0
<
2
5
0
<
2
.
0
<
2
0
<
2
0
--
16
2
,
3
4
0
<0
.
2
0
<
1
0
<
1
0
72
1,
2
0
0
1,360,000
2
,
8
6
0
,
0
0
0
6,870
6
.
0
1
4
.
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Page 2 of 8
Sa
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D
D
a
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Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
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1
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.
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1
,
4
6
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6
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0
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30
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0
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0
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7,220 ----
3
,
6
9
0
------
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2
7
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0
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8
6
8
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0
0
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13,800 ----
3
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7
0
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5
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8
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22,000 ----
1
,
1
1
0
------
10
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6
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13
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0
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8,990 ----
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0
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45
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2
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8
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0
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9,010 ----
1
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8
8
0
------
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9,710 ----
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Page 3 of 8
Sa
m
p
l
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Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
0
1
0
7
0
0
2
1
0
1
,
0
0
0
3
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5
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0
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N
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6
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5
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8
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5
N
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N
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N
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N
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N
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1
0
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3
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5
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2
1
0
1
0
1
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0
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0
0
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2
5
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0
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N
E
N
E
N
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N
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N
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N
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N
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87
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N
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29
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37,000 <25.0 7,600 5.8
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4
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3
NA
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9
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3
NA
<
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N
A
N
A
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A
39,000
1
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0
0
0
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0
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8
2
8
.
2
1
2
6
3
.
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3
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5
1
1
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0
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A
14
8
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5
.
0
N
A
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1
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N
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N
A
N
A
43,900 134,000 NA 7.6
1
6
.
3
2
5
6
8
.
7
2 0
6
.
9
4
9/
1
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2
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1
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6,
8
0
0
NA
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5
NA
8,
8
0
0
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0
93
NA
<
2
0
N
A
N
A
N
A
18,000
1
9
0
,
0
0
0
NA 5.3
2
2
.
4
1
5
5
3
0
.
0
2
7
2
1
.
3
8
3/
8
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2
0
1
6
8
6
0
NA
28
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1
<
5
N
A
1,
3
0
0
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29
NA
<
1
N
A
N
A
N
A
41,000
1
3
0
,
0
0
0
NA 5.7
2
1
.
2
1
9
3
2
9
.
7
1
3
6
5
.
5
9
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8
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1
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9
0
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NA
19
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5
N
A
3,
2
0
0
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31
NA
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N
A
N
A
N
A
14,000
2
3
0
,
0
0
0
NA 6.6
1
7
.
2
1
1
6
>1000 101
1
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6
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5
1
6
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2
2
3
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10
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9
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Page 4 of 8
Sa
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I
D
D
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Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
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Page 5 of 8
Sa
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I
D
D
a
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e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
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Page 6 of 8
Sa
m
p
l
e
Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
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Page 7 of 8
Sa
m
p
l
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Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
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NC
2
L
G
r
o
u
n
d
W
a
t
e
r
S
t
a
n
d
a
r
d
So
l
i
d
W
a
s
t
e
S
e
c
t
i
o
n
L
i
m
i
t
NC
2
B
S
u
r
f
a
c
e
W
a
t
e
r
S
t
a
n
d
a
r
d
2
2
2
2 2
1
9/
1
0
/
2
0
1
3
1
,
0
1
0
<0
.
0
1
52
.
4
<1
.
0
<
5
.
0
<
5
.
0
5,
6
8
0
<5
.
0
2,
9
9
0
<2
.
0
<
0
.
0
1
<
5
.
0
18
.
8
<0
.
0
2
1,150,000
2
,
2
4
0
,
0
0
0
20,500 6.2
1
7
.
7
2
,
1
9
1
5
.
2
4
4
0
.
4
0
4/
7
/
2
0
1
4
6
2
8
NA
48
.
9
<1
.
0
<
5
.
0
N
A
4,
7
8
0
<5
.
0
3,
1
3
0
NA
<
1
0
N
A
N
A
N
A
914,000
1
,
9
8
0
,
0
0
0
16,600 6.2
1
5
.
3
2
,
6
8
9
3
.
2
4
1
0
.
8
3
9/
5
/
2
0
1
4
1
,
3
7
0
NA
32
.
3
<1
.
0
8.
4
NA
6,
1
6
0
<5
.
0
3,
0
8
0
NA
49
.
9
NA
N
A
N
A
1,010,000
2
,
2
6
0
,
0
0
0
NA 6.1
1
6
.
7
2
,
5
5
2
5
.
7
-
1
6
3
.
9
3
4/
2
/
2
0
1
5
1
9
5
NA
45
<1
.
0
<
5
.
0
N
A
43
5
<5
.
0
59
5
NA
62
.
3
NA
N
A
N
A
1,010,000 187,000 NA 6.0
2
1
.
6
2
4
1
6
.
6
3
3
2
4
.
5
9
9/
9
/
2
0
1
5
4
1
0
NA
54
0
.
8
8
.
3
NA
5,
0
0
0
<1
0
3,
4
0
0
NA
<
2
0
N
A
N
A
N
A
990,000
2
,
1
0
0
,
0
0
0
NA 6.3
2
6
.
1
2
,
2
2
0
0
.
0
1
0
.
4
9
3/
8
/
2
0
1
6
4
2
0
NA
51
<0
.
1
8.
8
NA
5,
0
0
0
<1
3,
5
0
0
NA
<
1
N
A
N
A
N
A
940,000
2
,
1
0
0
,
0
0
0
NA 6.4
1
4
.
3
2
,
5
2
4
3
.
1
3
9
0
.
4
0
9/
6
/
2
0
1
6
2
5
0
NA
42
0
.
1
2
<5
.
0
N
A
5,
3
0
0
<1
3,
3
0
0
NA
2.
5
NA
N
A
N
A
840,000
1
,
9
0
0
,
0
0
0
NA 6.7
1
7
.
9
2
,
0
8
0
1
.
6
-
2
0
.
8
0
1/
4
/
2
0
1
1
--
-
-
81
<0
.
1
<
5
.
0
-
-
1,
6
0
0
<1
0
78
--<1
0
-
-
-
-
-
-
98,000
1
8
0
,
0
0
0
--
4/
2
0
/
2
0
1
1
4
0
<1
.
0
63
<0
.
1
<5
.
0
1.
9
2,
7
0
0
1.
6
11
0
<0
.
1
0
<
1
.
0
<
1.
0
<1
0
11
0
3
0
,
0
0
0
1
0
0
,
0
0
0
4
,
2
0
0
9/
2
5
/
2
0
1
2
<5
0
<
2
.
7
99
.
7
<50
<
2
.
0
<
2
.
0
13
8
<0
.
0
0
4
0
11
9
<0.10
<
5
.
0
<
2
.
5
<
5
.
0
1,
9
0
0
319,000
8
0
6
,
0
0
0
--
4/
1
7
/
2
0
1
3
1
8
2
<0
.
0
1
64
.
3
<1
.
0
<
5
.
0
<
5
.
0
20
0
<5
.
0
55
.
6
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
24
0
9
5
,
5
0
0
2
1
7
,
0
0
0
5,000
9/
1
0
/
2
0
1
3
<0
.
1
<
0
.
0
1
82
.
7
<1
.
0
<
5
.
0
<
5
.
0
72
.
1
<5
.
0
17
.
8
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
1,
5
8
0
1
7
9
,
0
0
0
4
8
5
,
0
0
0
6,530
4/
6
/
2
0
1
4
<0
.
1
0
0
N
A
56
.
7
<1
.
0
<
5
.
0
N
A
14
8
<5
.
0
28
.
3
NA
<
1
0
N
A
N
A
N
A
98,900 1,430,000 5,000
9/
3
/
2
0
1
4
52
,
8
0
0
NA
77
8
<1
.
0
28
0
NA
69
,
2
0
0
2
7
3
,
1
3
0
NA
<
1
0
N
A
N
A
N
A
162,000 503,000 NA
4/
1
/
2
0
1
5
<0
.
1
0
0
N
A
60
.
1
<1
.
0
<
5
.
0
N
A
87
<5
.
0
11
.
4
NA
<
1
0
N
A
N
A
N
A
91,900
2
9
0
,
0
0
0
NA 8.13
1
6
.
4
8
5
0
9
2
.
1
9
1
7
.
4
0
7
.
5
1
9/
8
/
2
0
1
5
--
------------------
3/
7
/
2
0
1
6
72
,
0
0
0
NA
1,
1
0
0
<0
.
5
22
0
NA
11
0
,
0
0
0
5
8
2
,
8
0
0
NA
<
5
N
A
N
A
N
A
110,000
2
6
0
,
0
0
0
NA
9/
7
/
2
0
1
6
D
r
y
,
n
o
s
a
m
p
l
e
c
o
l
l
e
c
t
e
d
--
--
--
--
--
--
--
--
--
--
--
------------------
1/
4
/
2
0
1
1
--
--
12
0
<0
.
1
<
5
.
0
--
77
0
<1
0
41
0
--<1 0-
--
--
-180,000
3
6
0
,
0
0
0
--
4/
2
0
/
2
0
1
1
4,
2
0
0
<1
.
0
9.
9
<0
.
1
6.
9
2.
7
7,
4
0
0
3.
4
41
0
0.
1
4
<1
.
0
<
1
.
0
<
1
0
10
0
82,000 250,000
6
,
7
0
0
9/
2
5
/
2
0
1
2
<5
0
<
2
.
7
11
3
<50
<
2
.
0
<
2
.
0
10
6
<0
.
0
0
4
0
38
.
9
<0.10
<
5
.
0
<
2
.
5
<
5
.
0
2,
0
0
0
306,000
7
6
7
,
0
0
0
--
4/
1
7
/
2
0
1
3
2
2
2
<0
.
0
1
63
.
7
<1
.
0
<
5
.
0
<
5
.
0
24
7
<5
.
0
28
.
4
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
18
0
9
8
,
2
0
0
1
9
7
,
0
0
0
4,600
9/
1
0
/
2
0
1
3
<0
.
1
<
0
.
0
1
83
.
9
<1
.
0
<
5
.
0
<
5
.
0
83
.
8
<5
.
0
13
.
8
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
1,
6
9
0
1
6
9
,
0
0
0
4
5
5
,
0
0
0
6,250
4/
6
/
2
0
1
4
1
1
4
NA
54
<1
.
0
<
5
.
0
N
A
18
0
<5
.
0
12
NA
<
1
0
N
A
N
A
N
A
93,800
2
5
5
,
0
0
0
4,000
4/
1
/
2
0
1
5
<0
.
1
0
0
N
A
58
.
4
<1
.
0
<
5
.
0
N
A
15
9
<5
.
0
9.
7
NA
<
1
0
N
A
N
A
N
A
82,200
2
6
7
,
0
0
0
NA 8.15
1
5
.
9
3
4
6
6
3
.
1
7
1
8
.
7
0
8
.
0
5
9/
8
/
2
0
1
5
41
,
0
0
0
NA
56
0
9
.
5
6
6
NA
85
,
0
0
0
3
0
9
,
6
0
0
NA
<
2
0
N
A
N
A
N
A
97,000
3
4
0
,
0
0
0
NA
3/
7
/
2
0
1
6
49
,
0
0
0
NA
81
0
3
.
4
6
9
NA
11
0
,
0
0
0
3
4
1
6
,
0
0
0
NA
<
5
N
A
N
A
N
A
38,000
1
4
0
,
0
0
0
NA
9/
7
/
2
0
1
6
1
,
9
0
0
NA
23
0
1
.
3
<5
.
0
N
A
19
,
0
0
0
8.
5
4,
5
0
0
NA
<
5
N
A
N
A
N
A
59,000
2
4
0
,
0
0
0
NA
1/
5
/
2
0
1
1
--
--
14
0
<0
.
1
9.
4
--
14
,
0
0
0
<1
0
1,
7
0
0
--<1 0-
--
--
-24,000
1
4
0
,
0
0
0
--
4/
2
1
/
2
0
1
1
<0
.
0
4
<1
.
0
55
<0
.
1
<
5
.
0
<
1
.
0
6,
7
0
0
<1
.
0
56
0
<0
.
1
0
<1.
0
<
1
.
0
<
1
0
49
2
5
,
0
0
0
1
0
0
,
0
0
0
3
,
0
0
0
9/
2
5
/
2
0
1
2
<Co
u
l
d
n
o
t
b
e
l
o
c
a
t
e
d
,
n
o
s
a
m
p
l
e
c
o
l
l
e
c
t
e
d
--
--
--
--
--
--
--
--
--
--
------------------
4/
1
7
/
2
0
1
3
9
1
4
<0
.
0
1
55
.
7
<1
.
0
<
5
.
0
<
5
.
0
1,
0
9
0
<5
.
0
10
.
2
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
<
0
.
0
2
30,500
8
7
,
0
0
0
3
,
2
0
0
9/
9
/
2
0
1
3
<0
.
1
<
0
.
0
1
68
.
6
<1
.
0
<
5
.
0
<
5
.
0
17
9
<5
.
0
7.
2
<2
.
0
<
0
.
0
1
<
5
.
0
<
0
.
0
1
67
.
5
4
5
,
2
0
0
1
5
8
,
0
0
0
1
3
,
3
0
0
4/
6
/
2
0
1
4
2
0
5
NA
51
.
2
<1
.
0
<
5
.
0
N
A
26
5
<5
.
0
<
5
.
0
N
A
<
1
0
N
A
N
A
N
A
25,200
1
1
9
,
0
0
0
2
,
5
0
0
9/
4
/
2
0
1
4
<0
.
1
0
0
N
A
80
<1
.
0
<
5
.
0
N
A
23
3
<5
.
0
62
.
5
NA
<
1
0
N
A
N
A
N
A
37,300
1
7
7
,
0
0
0
NA Not measured - insufficient sample volume due to limited recharge
4/
1
/
2
0
1
5
1
4
3
NA
57
.
9
<1
.
0
<
5
.
0
N
A
33
5
<5
.
0
5.
4
NA
<
1
0
N
A
N
A
N
A
30,400
1
0
5
,
0
0
0
NA 10.39
1
0
.
7
8
1
7
8
4
.
5
8
1
2
.
0
0
9
.
9
1
9/
8
/
2
0
1
5
1
1
0
NA
82
<5
<
1
0
N
A
18
0
<1
0
17
NA
<
2
0
N
A
N
A
N
A
56,000
2
1
0
,
0
0
0
NA
3/
7
/
2
0
1
6
16
,
0
0
0
NA
20
0
1
.
9
2
0
NA
56
,
0
0
0
10
40
0
NA
<
1
N
A
N
A
N
A
18,000
4
9
,
0
0
0
NA
9/
7
/
2
0
1
6
No
t
s
a
m
p
l
e
d
d
u
e
t
o
b
e
i
n
g
w
a
s
h
e
d
o
u
t
.
W
e
l
l
c
a
s
i
n
g
f
o
u
n
d
d
o
w
n
s
t
r
e
a
m
o
f
o
r
i
g
i
n
a
l
l
o
c
a
t
i
o
n
--
--
--
--
--
--
--
------------------Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge
No
t
s
a
m
p
l
e
d
d
u
e
t
o
b
l
o
c
k
a
g
e
i
n
c
a
s
i
n
g
.
A
d
j
a
c
e
n
t
s
u
r
f
a
c
e
w
a
t
e
r
s
a
m
p
l
e
c
o
l
l
e
c
t
e
d
,
S
S
-
3
5
.
P
Z
w
a
s
r
e
p
l
a
c
e
d
b
e
f
o
r
e
A
p
r
i
l
2
0
1
6
s
a
m
p
l
i
n
g
e
v
e
n
t
.
Not measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited recharge
Re
p
l
a
c
e
d
P
Z
-
1
3/
2
0
1
6
PZ
-
3
PZ
-
1
PZ
-
2
Not measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge
Ta
b
l
e
s
R
J
R
T
A
s
h
L
F
.
x
l
s
x
/
T
a
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Page 8 of 8
Sa
m
p
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e
Lo
c
a
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i
o
n
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I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-Nitrite
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
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8
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6
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N
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39
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N
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24,200
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4
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N
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41,200
1
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3
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1
/
2
0
1
5
1
3
3
NA
54
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6
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0
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5
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N
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24
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7
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N
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45,000
1
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7
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9
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6
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NA
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9
NA
N
A
N
A
306,000
7
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1
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2
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4
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N
A
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9
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0
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3
NA
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1
0
N
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N
A
N
A
153,000
3
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1
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5
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1
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1
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--
--
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------------------
3/
7
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2
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41
,
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63,000
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2
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6
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8
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N
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28,000
1
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0
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NA
All
c
o
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c
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r
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c
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L
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t
s
(
S
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)
Anal ysis for arsenic, copper, mercury, silver, zinc, nitrates & T OC
NE
-
N
o
t
e
s
t
a
b
l
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d
1 -
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Gr
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iscontinued in 2014 per Corrective Action Plan (ERM, 2/2014).
--
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2 -
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Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited recharge
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.
Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge
PZ
-
5
PZ
-
4
Not measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited rechargeNot measured - insufficient sample volume due to limited recharge
Ta
b
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Page 1 of 7
Sa
m
p
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e
Lo
c
a
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i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
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Sa
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Lo
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n
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I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
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0
9
,
0
0
0
3
,
1
9
0
7
.
6
2
0
.
0
6
1
3
------
03
/
2
9
/
9
7
20
9
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0
<
2
5
0
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2
.
0
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2
0
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2
0
64
4
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.
0
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6
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2
0
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1
0
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1
0
10
4
5
0
7
2
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8
0
0
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5
5
,
0
0
0
2
,
4
7
0
7
.
8
1
6
.
0
2
2
4
------
09
/
1
7
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9
7
16
5
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0
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2
5
0
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.
0
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8
6
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5
.
0
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6
0
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0
0
0
562,000 2,430
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.
8
1
8
.
0
8
2
6
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7
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9
8
22
0
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5
0
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0
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2
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4
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0
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3
,
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6
0
7
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8
1
7
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5
7
2
4
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8
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6
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8
5
0
7
.
4
1
9
.
0
3
6
8
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03
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9
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0
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0
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94
7
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0
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5
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6
0
7
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4
1
7
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0
3
4
0
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9
9
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2
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21
16
0
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5
,
7
0
0
1
7
3
,
0
0
0
8
,
1
0
0
7
.
6
1
7
.
0
6
2
3
------
09
/
1
5
/
0
0
28
3
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0
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2
5
0
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2
.
0
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2
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0
22
5
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.
0
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2
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0
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4
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0
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0
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3
9
,
0
0
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6
,
5
8
0
7
.
4
2
0
.
0
6
4
0
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03
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6
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0
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5
0
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.
0
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0
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4
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.
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0
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0
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1
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1,
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8
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175,000
5
0
0
,
0
0
0
3
,
7
5
0
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03
/
2
3
/
0
1
10
8
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0
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2
5
0
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.
0
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0
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26
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7
13
5
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.
2
0
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0
34
10
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2
4
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3
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0
8
0
6
.
6
1
6
.
0
1
7
0
------
10
/
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16
6
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2
5
0
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2
.
0
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2
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74
6
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0
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421,000
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,
2
5
0
,
0
0
0
27,000
7
.
2
1
9
.
0
6
8
0
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03
/
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8
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12
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5
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2
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0
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0
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32
0
1
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7
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0
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4
0
5
,
0
0
0
2
,
9
7
0
7
.
4
1
1
.
0
5
1
0
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10
/
0
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2
22
0
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0
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2
5
0
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2
.
0
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2
0
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0
49
4
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.
0
54
9
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.
2
0
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1
0
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0
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2
0
1,
1
1
0
266,000
5
1
7
,
0
0
0
4,280
5
.
8
1
8
.
0
1
3
0
------
03
/
2
5
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0
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5
7
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8
0
6
26
4
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0
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9
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3
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3
4
,
0
0
0
1
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9
1
0
6
.
0
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8
.
0
1
,
2
6
0
------
du
p
l
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c
a
t
e
03
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2
5
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0
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7
5
0
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0
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0
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5
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2
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24
19
4
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4
,
6
0
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3
5
,
0
0
0
2
,
0
0
0
6
.
0
1
8
.
0
1
,
2
6
0
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10
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0
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0
3
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2
5
0
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0
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.
0
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6
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.
2
0
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1
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0
61
0
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5
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0
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9
5
,
0
0
0
2
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5
0
0
6
.
5
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4
.
0
5
5
6
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4
10
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40
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60
8
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2
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0
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9
4
,
0
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2
6
0
--
1
2
.
7
6
2
3
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6
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4
21
6
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5
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9
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5
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0
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3,060 ----
8
0
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7
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4
1
9
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10
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3
439,000 303,000
4
,
4
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0
----
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300,000
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9
0
8
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Page 3 of 7
Sa
m
p
l
e
Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
0
1
0
7
0
0
2
1
0
1
,
0
0
0
3
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5
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N
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6
.
5
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8
.
5
N
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N
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N
E
N
E
N
E
NE
1
0
1
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1
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0
3
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0
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.
2
1
0
1
0
1
0
1
0
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0
0
0
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5
0
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0
0
0
N
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N
E
N
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N
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N
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N
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N
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N
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87
5
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0
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5
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0
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0
0
0
N
E
6
.
0
-
9
.
0
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N
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5
0
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5
.
0
NC
2
L
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2
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2
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1
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14
.
2
40
7
342,000
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0
8
,
0
0
0
3,430
-
-
-
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1
,
0
7
0
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8
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0
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.
4
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1
0
19
.
2
49
9
2
0
1
,
0
0
0
518,000 3,390
-
-
-
-
8
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1
-
-
-
-
-
-
08
/
2
6
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0
9
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71
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0
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5
.
0
-
-
11
0
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.
0
22
0
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0
-
-
-
-
-
-
310,000 --
-
-
7.8
2
1
.
6
2
,
1
2
0
6
.
4
1
0
1
6
.
4
10
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0
9
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0
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0
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5
.
0
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3
0
32
0
210,000 510,000 10,300
7
.
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1
3
.
3
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0
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.
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1
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5
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5
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0
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0
390,000 6,300 7.6
1
0
.
6
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10
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5
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660,000 4,700 7.6
1
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.
2
9
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0
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8
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0
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360,000 3,000 7.6
1
8
.
6
6
0
2
4
.
2
2
4
1
9
.
7
10
/
1
8
/
1
1
<1
0
0
<
5
.
0
74
.
9
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.
0
<
5
.
0
<
5
.
0
18
1
<5
.
0
26
6
<0
.
2
0
<
1
0
<
5
.
0
<
1
0
47
0
2
0
2
,
0
0
0
582,000 7,300 7.4
1
7
.
6
5
3
6
4
.
6
2
4
8
9
.
7
03
/
1
6
/
1
2
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0
0
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.
0
71
.
8
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.
0
<
5
.
0
<
5
.
0
17
1
<5
.
0
65
.
8
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.
2
0
<
10
<5
.
0
<
1
0
1,
6
0
0
1
5
2
,
0
0
0
614,000 6,300 7.6
1
5
.
4
7
8
1
3
.
4
1
5
1
1
.
5
09
/
2
5
/
1
2
<5
0
<
2
.
7
97
.
6
<50
<
2
.
0
<
2
.
0
23
6
<4
.
0
30
1
<0.10
<
5
.
0
<
2
.
5
<
5
.
0
1,
6
0
0
400,000
8
5
8
,
0
0
0
--8.5
1
6
.
2
1
,
4
2
0
9
.
7
1
8
1
9
.
1
04
/
1
7
/
1
3
19
4
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0
71
.
4
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.
0
<
5
.
0
<
5
.
0
24
2
<5
.
0
11
0
<0
.
2
0
<
1
0
<
5
.
0
<
1
0
21
0
7
9
,
1
0
0
2
0
7
,
0
0
0
5,000 8.1
2
0
.
8
3
8
2
4
.
7
7
9
.
6
8
.
0
09
/
1
0
/
1
3
<1
0
0
<
1
0
83
<1
.
0
<
5
.
0
<
5
.
0
13
5
<5
.
0
10
2
<0
.
2
0
<
1
0
<
5
.
0
<
1
0
1,
1
6
0
1
6
7
,
0
0
0
4
9
3
,
0
0
0
6,290 8.0
1
9
.
8
6
5
7
8
.
2
9
9
.
8
7
.
1
04
/
0
6
/
1
4
13
3
NA
56
.
4
<1
.
0
<
5
.
0
N
A
19
4
<5
.
0
21
.
2
NA
<
1
0
N
A
N
A
N
A
87,000
2
7
7
,
0
0
0
5,000 8.9
1
4
.
0
4
4
5
7
.
5
1
3
8
1
2
.
1
09
/
0
3
/
1
4
<1
0
0
N
A
83
.
7
<1
.
0
<
5
.
0
N
A
68
.
6
<5
.
0
11
.
1
NA
<
1
0
N
A
N
A
N
A
158,000 526,000 NA 8.1
2
3
.
4
7
3
3
2
.
5
6
1
.
3
5
.
1
04
/
0
1
/
1
5
<1
0
0
N
A
59
<1
.
0
<
5
.
0
N
A
96
.
1
<5
.
0
16
.
7
NA
<
1
0
N
A
N
A
N
A
92,200
2
9
7
,
0
0
0
NA 8.1
1
5
.
0
5
0
8
1
.
8
9
.
6
8
.
1
09
/
0
8
/
1
5
26
0
NA
10
0
<5
1.
1
NA
45
0
<1
0
70
NA
<
2
0
N
A
N
A
N
A
160,000
4
6
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
15
0
NA
65
<0
.
1
<
5
N
A
26
0
<1
36
NA
1.
7
NA
NA
N
A
61,000
1
8
0
,
0
0
0
NA 8.4
8
.5 368
N
M
2
2
7
1
1
.
3
09
/
0
7
/
1
6
15
0
NA
81
<0
.
1
<
5
N
A
49
0
<1
44
NA
<
1
.
0
N
A
N
A
N
A
86,000
3
0
0
,
0
0
0
NA 8.5
2
1
.
8
4
5
2
4
.
6
8
9
8
.
4
SS
-
1
0
08
/
1
1
/
0
9
--
--
65
<1
.
0
<
5
.
0
--
12
,
0
0
0
<5
.
0
40
0
--<2 0-
--
--
-11,000 ----7.1
2
0
.
6
1
,
8
9
0
4
2
.
9
-
4
0
3
.
4
SS
-
1
5
08
/
1
1
/
0
9
--
--
52
<1
.
0
<
5
.
0
--
90
0
<5
.
0
35
--<2 0-
--
--
-7,500 ----7.8
2
0
.
7
1
,
8
4
0
5
2
.
5
1
1
4
9
.
7
08
/
1
1
/
0
9
--
--
58
<1
.
0
<
5
.
0
--
80
0
<5
.
0
46
--<2 0-
--
--
-8,200 ----8.4
2
3
.
9
1
,
1
1
2
2
7
.
3
5
8
7
.
6
04
/
2
1
/
1
1
19
0
<1
0
54
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.
1
<
5
.
0
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1
.
0
55
0
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.
0
17
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.
1
0
<
1
.
0
<
1
.
0
<
1
0
10
0
4
,
8
0
0
9
6
,
0
0
0
1
,
9
0
0
7
.
7
1
4
.
6
8
7
1
4
.
2
1
2
8
9
.
4
09
/
2
4
/
1
2
37
8
<2
.
7
51
.
4
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<
2
.
0
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2
.
0
1,
5
8
0
<4
.
0
51
.
1
<0
.
1
0
<
5
.
0
<
2
.
5
<
5
.
0
<
0
.
0
2
3,600
8
9
,
0
0
0
--7.3
1
5
.
6
1
4
6
1
0
.
3
1
5
9
8
.
6
04
/
1
7
/
1
3
78
8
<1
0
56
<1
.
0
<
5
.
0
<
5
.
0
1,
0
5
0
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.
0
19
.
8
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.
2
0
<
1
0
<
5
.
0
<
1
0
<
0
.
0
2
5,600
5
5
,
0
0
0
2,800 7.5
1
9
.
8
2
8
3
7
.
2
1
5
8
8
.
7
09
/
0
9
/
1
3
45
6
<1
0
60
.
3
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.
0
<
5
.
0
<
5
.
0
1,
1
7
0
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.
0
48
.
4
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.
2
0
<
1
0
<
5
.
0
<
1
0
27
4
3
,
6
1
0
7
8
,
0
0
0
2,280 7.4 21.7
9
7
9
.7 24.2
8
.
4
04
/
0
6
/
1
4
12
6
NA
54
.
2
<1
.
0
<
5
.
0
N
A
26
9
<5
.
0
6
NA
<
1
0
N
A
N
A
N
A
5,200
6
8
,
0
0
0
1,900 8.1
9
.
6
2
1
2
1
4
.
4
1
3
5
1
0
.
3
09
/
0
3
/
1
4
81
8
NA
73
.
7
<1
.
0
<
5
.
0
N
A
2,
4
5
0
<5
.
0
71
.
4
NA
<
1
0
N
A
N
A
N
A
3,600
9
7
,
0
0
0
NA 7.4
2
0
.
6
1
0
0
2
0
.
9
-
1
2
.
5
5
.
3
04
/
0
1
/
1
5
2,
3
2
0
NA
10
5
<1
.
0
<
5
.
0
N
A
4,
8
4
0
<5
.
0
99
.
1
NA
<
1
0
N
A
N
A
N
A
5,000
6
6
,
0
0
0
NA 7.7
1
4
.
9
1
0
3
7
.
3
7
.
2
7
.
6
09
/
0
9
/
1
5
4,
7
0
0
NA
13
0
<5
5.
8
NA
7,
6
0
0
<1
0
17
0
NA
<
2
0
N
A
N
A
N
A
3,500
9
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
47
0
NA
53
<0
.
1
<
5
N
A
45
0
<1
8.
9
NA
<
1
N
A
N
A
N
A
4,300
6
5
,
0
0
0
NA 7.9
1
2
.
1
7
4
N
M
1
1
4
8
.
7
09
/
0
7
/
1
6
31
0
NA
59
<0
.
1
<
5
N
A
1,
1
0
0
<1
36
NA
<
1
N
A
N
A
N
A
1,600
8
9
,
0
0
0
NA 7.6
1
9
.
4
8
0
3
.
2
5
9
8
.
4
08
/
1
1
/
0
9
--
--
60
<1
.
0
<
5
.
0
--
59
0
<5
.
0
53
--<2 0-
--
--
-28,000 ----8.4
2
2
.
1
1
,
8
3
0
3
2
.
1
7
5
7
.
6
04
/
2
1
/
1
1
15
0
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0
50
<0
.
1
<
5
.
0
<
1
.
0
47
<1
.
0
8.
2
<0
.
1
0
<
1
.
0
<
1
.
0
<
1
0
40
5
,
0
0
0
1
0
0
,
0
0
0
1
,
9
0
0
7
.
6
1
4
.
8
8
9
1
5
.
5
1
2
8
9
.
7
09
/
2
4
/
1
2
50
8
<2
.
7
52
.
2
<50
<
2
.
0
<
2
.
0
1,
5
8
0
<4
.
0
10
3
<0.10
<
5 .0
<
2
.
5
<
5
.
0
20
3
9
,
8
0
0
1
5
6
,
0
0
0
--7.2
1
5
.
9
2
5
7
1
3
.
6
1
4
5
8
.
4
04
/
1
7
/
1
3
82
0
<1
0
54
.
9
<1
.
0
<
5
.
0
<
5
.
0
1,
1
7
0
<5
.
0
32
.
6
<0
.
2
0
<
1
0
<
5
.
0
<
1
0
<
0
.
0
2
5,800
6
2
,
0
0
0
2,900 7.5
1
9
.
6
3
3
6
6
.
8
1
6
3
8
.
9
09
/
0
9
/
1
3
34
5
<1
0
54
.
3
<1
.
0
<
5
.
0
<
5
.
0
80
9
<5
.
0
23
.
8
<0
.
2
0
<
1
0
<
5
.
0
<
1
0
60
.
9
3
,
6
5
0
8
2
,
0
0
0
2,590 7.4
2
0
.
3
1
3
4
5
.
9
2
3
.
7
8
.
3
04
/
0
6
/
1
4
31
0
NA
51
.
1
<1
.
0
<
5
.
0
N
A
55
5
<5
.
0
13
.
8
NA
<
1
0
N
A
N
A
N
A
5,500
7
5
,
0
0
0
2,000 7.1
9
.
6
8
3
1
1
.
9
8
6
.
6
1
0
.
4
09
/
0
3
/
1
4
2,
0
0
0
NA
83
.
3
<1
.
0
<
5
.
0
N
A
3,
8
8
0
<5
.
0
79
.
3
NA
<
1
0
N
A
N
A
N
A
3,400
1
0
0
,
0
0
0
NA 7.4
2
1
.
4
9
2
3
2
.
1
-
1
1
.
9
5
.
6
04
/
0
1
/
1
5
29
2
NA
53
.
4
<1
.
0
<
5
.
0
N
A
64
9
<5
.
0
10
.
6
NA
<
1
0
N
A
N
A
N
A
5,200
7
4
,
0
0
0
NA 7.1
1
5
.
0
8
9
9
.
5
1
6
.
3
5
.
9
09
/
0
9
/
1
5
66
0
NA
63
<5
<
1
0
N
A
1,
5
0
0
<1
0
58
NA
<
2
0
N
A
N
A
N
A
3,700
8
5
,
0
0
0
NA --------
03
/
0
8
/
1
6
1,
7
0
0
NA
92
<0
.
1
<
5
N
A
2,
5
0
0
1.
8
90
NA
<
1
N
A
N
A
N
A
4,700
8
3
,
0
0
0
NA 8.3
1
2
.
8
7
3
N
M
6
3
.
0
1
1
.
8
09
/
0
7
/
1
6
1,
4
0
0
NA
77
<0
.
1
<
5
N
A
3,
2
0
0
<1
81
NA
<
1
N
A
N
A
N
A
1,700
8
6
,
0
0
0
NA 8.0 19.7
6
4
2
.9 43.0
8
.
2
Not measured Not measured Not measured
SS
-
2
5
SS
-
2
0
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Page 4 of 7
Sa
m
p
l
e
Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
0
1
0
7
0
0
2
1
0
1
,
0
0
0
3
0
0
1
5
5
0
1
2
0
2
0
1
,
0
0
0
1
0
,
0
0
0
2
5
0
,
0
0
0
5
0
0
,
0
0
0
N
E
6
.
5
-
8
.
5
N
E
N
E
N
E
N
E
N
E
NE
1
0
1
0
0
1
1
0
1
0
3
0
0
1
0
5
0
0
.
2
1
0
1
0
1
0
1
0
,
0
0
0
2
5
0
,
0
0
0
N
E
N
E
N
E
N
E
N
E
N
E
N
E
N
E
87
5
0
1
,
0
0
0
2
5
0
7
1
,
0
0
0
2
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.
0
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NC
2
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1
5
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4
5
6
7
1
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9
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4
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0
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0
3
1
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4
4
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18,200 7.8
2
1
.
1
2
6
8
8
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7
6
2
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2
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6
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7
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9
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1
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A
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6
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A
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9
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5
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A
N
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A
33,200
1
7
0
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0
0
0
4,000 8.0
9
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5
2
7
0
5
.
5
1
5
9
1
6
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2
09
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3
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4
14
5
NA
84
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3
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0
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5
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0
N
A
27
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0
16
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4
NA
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0
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A
N
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N
A
43,600
2
5
3
,
0
0
0
NA 8.4
2
1
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4
3
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8
1
1
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0
1
6
.
6
7
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0
04
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1
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5
17
3
NA
67
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1
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0
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5
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0
N
A
29
1
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0
11
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2
NA
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0
N
A
N
A
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A
43,200
1
9
1
,
0
0
0
NA 7.9
1
6
.
5
3
4
8
6
.
3
6
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2
7
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7
09
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9
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1
5
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0
0
NA
86
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0
N
A
11
0
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0
5.
8
NA
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N
A
N
A
N
A
98,000
2
8
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
87
0
NA
67
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1
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5
N
A
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0
0
0
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32
NA
<
1
N
A
N
A
N
A
31,000
1
5
0
,
0
0
0
NA 8.5
9
.
3
2
7
5
N
M
1
6
4
1
2
.
0
09
/
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7
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1
6
47
0
NA
70
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1
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5
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A
97
0
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44
NA
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1
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A
N
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A
48,000
2
7
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0
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2
1
.
6
3
5
7
2
.
8
4
8
8
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5
SS
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5
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N
A
10
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1
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N
A
72
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0
28
NA
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2
0
N
A
N
A
N
A
170,000
4
7
0
,
0
0
0
NA --------
08
/
2
6
/
0
9
--
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91
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0
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5
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80
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22
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2
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1
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6
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5
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20
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4
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4
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6,230 7.9 19.8
6
1
0
5
.
7
8
7
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8
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04
/
0
6
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4
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0
N
A
53
.
2
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.
0
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5
.
0
N
A
18
5
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.
0
11
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5
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1
0
N
A
N
A
N
A
81,600
2
5
6
,
0
0
0
16,200 9.2
1
4
.
0
3
9
7
8
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3
1
3
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1
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4
09
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3
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4
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N
A
86
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5
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0
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5
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0
N
A
58
.
1
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5
NA
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1
0
N
A
N
A
N
A
152,000
4
7
3
,
0
0
0
NA 8.1
2
3
.
7
6
8
9
2
.
5
6
9
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4
4
.
9
04
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1
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5
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0
N
A
58
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5
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0
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5
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A
15
4
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0
10
.
8
NA
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1
0
N
A
N
A
N
A
84,200
2
6
4
,
0
0
0
NA 8.0
1
8
.
3
4
6
9
4
.
2
1
3
.
5
8
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3
09
/
0
8
/
1
5
21
0
NA
11
0
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1
0
N
A
37
0
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0
48
NA
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2
0
N
A
N
A
N
A
160,000
4
4
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
22
0
NA
62
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.
1
<
5
N
A
31
0
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12
NA
<
1
N
A
N
A
N
A
57,000
1
8
0
,
0
0
0
NA 8.4
8
.
9
3
3
3
N
M
2
3
8
1
3
.
4
09
/
0
7
/
1
6
54
0
NA
94
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.
1
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5
N
A
1,
3
0
0
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10
0
NA
<
1
N
A
N
A
N
A
78,000
2
9
0
,
0
0
0
NA 8.2
2
1
.
0
4
2
7
3
.
2
1
2
1
7
.
7
08
/
1
1
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0
9
--
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29
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0
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5
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0
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9
0
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2
5
.
4
1
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1
8
0
3
2
.
0
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5
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5
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13
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7
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8
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1
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5
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14
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1
6
1
9
.
6
1
6 8.8
04
/
1
7
/
1
3
Dr
y
,
n
o
s
a
m
p
l
e
c
o
l
l
e
c
t
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d
--
--
--
--
--
--
--
--
--
--
--
------------------
09
/
0
9
/
1
3
Dr
y
,
n
o
s
a
m
p
l
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c
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l
l
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c
t
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d
--
--
--
--
--
--
--
--
--
--
--
------------------
04
/
0
6
/
1
4
Dr
y
,
n
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s
a
m
p
l
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c
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d
--
--
--
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--
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------------------
09
/
0
3
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1
4
Dr
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,
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s
a
m
p
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--
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--
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--
--
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04
/
0
1
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1
5
88
6
NA
49
.
4
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.
0
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5
.
0
N
A
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6
2
0
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0
17
0
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1
0
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A
2,900
6
3
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0
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1
3
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5
9
0
1
8
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8
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3
1
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7
09
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9
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1
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6
2
5
0
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85
0
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0
0
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1
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6
,
0
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NA
<
4
0
N
A
N
A
N
A
640
7
5
,
0
0
0
NA --------
03
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0
8
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1
6
93
0
NA
46
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1
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5
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A
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7
0
0
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46
NA
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1
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A
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N
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1
2
.
5
7
2
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M
1
1
2
9
.
8
09
/
0
7
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1
6
41
0
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49
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.
1
<
5
N
A
2,
9
0
0
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18
0
NA
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1
N
A
N
A
N
A
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1
0
0
0
99,000 ---8.0
2
2
.
8
1
2
1
3
.
6
5
0
6
.
9
08
/
2
6
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9
--
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0
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5
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0
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28
0
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0
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0
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--
--
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2
0
.
3
4
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0
4
0
6
5
.
9
1
0
6
.
7
04
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2
1
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1
1
68
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0
61
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1
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5
.
0
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24
0
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0
11
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1
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0
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0
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0
1
3
0
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0
0
0
2
7
0
,
0
0
0
2
,
7
0
0
7
.
2
1
5
.
9
4
4
6
1
4
.
3
1
7
7
8
.
9
09
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5
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2
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0
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.
7
75
.
9
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2
.
0
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.
0
31
2
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.
0
85
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.
1
0
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5
.
0
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.
5
<
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.
0
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0
.
0
2
58,100
1
9
1
,
0
0
0
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1
2
.
5
3
3
7
1
1
.
7
1
7
9
8
.
8
04
/
1
7
/
1
3
53
4
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0
63
.
4
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.
0
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5
.
0
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.
0
66
7
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.
0
43
.
8
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5
.
0
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2
164,000
2
7
4
,
0
0
0
4,200 7.8
2
0
.
2
3
8
0
8
.
6
7
0
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6
1
0
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8
09
/
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3
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0
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0
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5
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6
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0
75
.
5
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2
0
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5
.
0
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1
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0
275,000
6
6
3
,
0
0
0
6,150 7.5
2
1
.
0
4
2
3
8
.
4
8
7
.
6
8
.
2
04
/
0
6
/
1
4
15
4
NA
64
.
9
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.
0
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5
.
0
N
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17
5
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.
0
5.
7
NA
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1
0
N
A
N
A
N
A
119,000
2
3
4
,
0
0
0
3,300 7.6
1
3
.
6
4
2
1
5
.
9
1
8
6
1
2
.
8
09
/
0
4
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4
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A
12
7
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0
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5
.
0
N
A
70
9
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.
0
53
7
NA
16
.
8
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A
290,000
7
1
7
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2
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8
8
4
5
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3
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SS
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Page 5 of 7
Sa
m
p
l
e
Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
0
1
0
7
0
0
2
1
0
1
,
0
0
0
3
0
0
1
5
5
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1
2
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0
0
0
N
E
6
.
5
-
8
.
5
N
E
N
E
N
E
N
E
N
E
NE
1
0
1
0
0
1
1
0
1
0
3
0
0
1
0
5
0
0
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2
1
0
1
0
1
0
1
0
,
0
0
0
2
5
0
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0
0
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N
E
N
E
N
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N
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N
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N
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N
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87
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1
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5
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0
0
0
N
E
6
.
0
-
9
.
0
N
E
N
E
5
0
N
E
>
5
.
0
NC
2
L
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2
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a
r
d
2
2
2
2
2
1
04
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0
1
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5
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3
2
0
NA
93
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0
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5
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0
N
A
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1
4
0
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0
69
.
5
NA
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1
0
N
A
N
A
N
A
159,000
3
5
9
,
0
0
0
NA 7.1
9
.
7
5
3
8
1
8
.
8
1
.
5
6
6
.
6
09
/
0
8
/
1
5
19
0
NA
57
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1
0
N
A
41
0
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0
33
NA
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2
0
N
A
N
A
N
A
13,000
1
1
0
,
0
0
0
NA --
-
-
-
-
-
-
03
/
0
8
/
1
6
51
0
NA
68
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.
1
<
5
N
A
41
0
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8.
6
NA
3
NA
N
A
N
A
120,000
2
7
0
,
0
0
0
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9
.
3
3
7
5
N
M
2
5
2
1
0
.
6
09
/
0
7
/
1
6
78
0
NA
13
0
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1
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5
N
A
2,
4
0
0
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16
0
NA
<
1
N
A
N
A
N
A
250,000
4
9
0
,
0
0
0
NA 7.5
2
0
.
1
6
6
6
4
.
7
3
9
6
.
5
SS
-
6
5
09
/
0
8
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1
5
78
0
NA
80
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1.
3
NA
1,
3
0
0
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0
96
NA
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A
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A
44,000
1
5
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0
0
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-
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6
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9
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0
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6.9
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8
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9
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1
9
7
.
6
8
5
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3
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1
04
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6
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4
37
4
NA
47
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7
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5
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0
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A
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3
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A
21,000
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6
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0
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0
2,300 7.5
1
3
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3
1
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5
8
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3
1
6
5
9
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9
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4
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A
79
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5
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0
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A
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5
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0
71
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1
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A
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A
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A
35,000
1
4
6
,
0
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0
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2
1
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0
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1
7
3
.
7
2
2
.
3
7
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3
04
/
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5
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7
NA
55
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1
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0
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5
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0
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A
28
2
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0
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4
NA
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1
0
N
A
N
A
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A
27,300
9
3
,
0
0
0
NA 7.4
1
1
.
1
1
5
9
1
.
6
5
.
0
1
8
.
2
09
/
0
8
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5
95
NA
71
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1
0
N
A
26
0
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0
27
NA
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2
0
N
A
N
A
N
A
33,000
1
6
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
64
0
NA
47
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1
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5
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0
N
A
54
0
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5.
7
NA
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1
N
A
N
A
N
A
18,000
9
0
,
0
0
0
NA 8.2
1
0
.
0
1
1
3
N
M
2
4
4
1
1
.
4
09
/
0
7
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1
6
16
0
NA
52
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1
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5
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0
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47
0
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18
NA
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1
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A
N
A
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A
1,600
8
1
,
0
0
0
NA 7.5
1
9
.
9
9
3
5
.
3
2
6
7
.
6
SS
-
7
5
09
/
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5
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A
78
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1
0
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A
23
0
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0
26
NA
9.
9
NA
NA
N
A
41,000
1
7
0
,
0
0
0
NA --------
08
/
2
6
/
0
9
--
--
12
0
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.
0
<
5
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25
0
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--
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2
0
.
6
5
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1
9
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5
.
8
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.
3
04
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5
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5
1
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5
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74,600
2
7
0
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9
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8
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2
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1
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3
9
7
.
6
7
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5
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2
1
.
6
4
1
7
6
.
9
8
7
.
9
7
.
9
04
/
0
6
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4
18
0
NA
53
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7
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0
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5
.
0
N
A
32
8
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0
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5
.
0
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A
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1
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N
A
N
A
N
A
17,500
8
4
,
0
0
0
2,400 7.4
1
3
.
9
1
0
6
8
.
7
1
3
6
1
1
.
8
09
/
0
4
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1
4
14
9
NA
81
.
1
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0
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5
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0
N
A
43
6
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0
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.
8
NA
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1
0
N
A
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A
30,100
1
5
5
,
0
0
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NA 8.1
2
1
.
2
2
4
5
1
1
.
3
1
7
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5
7
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0
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5
24
6
NA
58
.
1
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38
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1
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25,500
8
9
,
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NA 7.9
1
2
.
8
1
6
2
4
.
4
4
.
3
7
9
.
6
09
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5
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84
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1
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0
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N A<
2
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N
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AN
A
41,000
1
7
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,
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NA --------
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0
8
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1
6
64
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54
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1
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4
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24,000
1
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0
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8
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4
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2
3
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1
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7
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<
1
0
<
5
.
0
<
1
0
35
3
8
,
9
0
0
1
2
7
,
0
0
0
3,700 7.9
1
9
.
7
2
0
3
6
.
9
6
6
7
.
6
09
/
1
0
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1
3
14
8
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0
86
.
6
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0
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5
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0
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5
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0
26
5
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0
32
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4
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5
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64
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2
2
.
2
4
2
9
7
.
9
9
1
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6
7
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3
04
/
0
6
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1
4
15
4
NA
48
.
5
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.
0
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5
.
0
N
A
27
4
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0
9.
4
NA
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0
N
A
N
A
N
A
45,300
1
5
1
,
0
0
0
3,300 8.9
1
5
.
1
2
5
5
5
.
6
1
2
1
1
5
.
4
09
/
0
3
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1
4
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0
NA
90
.
8
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.
0
<
5
.
0
N
A
77
.
5
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.
0
16
NA
<10
N
A
N
A
N
A
94,500
3
5
7
,
0
0
0
NA 7.5
2
3
.
5
5
1
8
5
.
6
6
5
.
3
6
.
4
04
/
0
1
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1
5
12
5
NA
58
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.
0
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5
.
0
N
A
18
9
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.
0
9
NA
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1
0
N
A
N
A
N
A
51,400
1
6
6
,
0
0
0
NA 8.8
1
1
.
4
3
1
8
6
.
0
5
.
9
5
9
.
9
09
/
0
8
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1
5
29
0
NA
10
0
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1.
0
NA
53
0
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0
80
NA
<
2
0
N
A
N
A
N
A
110,000
3
4
0
,
0
0
0
NA --------
03
/
0
8
/
1
6
39
0
NA
58
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.
1
<
5
N
A
47
0
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11
NA
<
1
N
A
N
A
N
A
33,000
1
1
0
,
0
0
0
NA 8.4
8
.
5
2
1
0
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M
2
3
9
1
3
.
1
09
/
0
7
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1
6
40
NA
73
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.
1
<
5
N
A
23
0
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17
NA
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1
N
A
N
A
N
A
49,000
2
0
0
,
0
0
0
NA 8.0
2
0
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8
2
8
8
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1
.
8
4
8
9
.
0
SS
-
9
0
Not measured
SS
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8
0
SS
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7
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Not measured Not measured Not measured Not measuredNot measured
3 3
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Page 6 of 7
Sa
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p
l
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Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
5
0
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7
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6
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6
.
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1,560,000 2,930,000 7,920
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5,210
6
.
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1
9
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0
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0
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Page 7 of 7
Sa
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I
D
D
a
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e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen
Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)Turbidity (NTUs) Oxidation-Reduction Potential (mV)Dissolved Oxygen(mg/L)
3,
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Page 1 of 1
Sa
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Lo
c
a
t
i
o
n
/
I
D
D
a
t
e
Aluminum
Arsenic
Barium
Cadmium
Chromium
(Total)
Copper
Iron
Lead
Manganese
Mercury
Selenium
Silver
Zinc
Nitrate-nitrogen Sulfate Dissolved SolidsTotal Organic Carbon pH Temperature (degrees Celsius) Conductivity (µmhos/cm)
NC
2
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3
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APPENDIX B
ANALYTICAL LABORATORY
DATA SHEETS –
GROUNDWATER AND
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SH
E
A
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NC Field Parameters No: 5639
NE
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:
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10
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10
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a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
1
4
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
3
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
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n
o
f
c
o
m
p
o
u
n
d
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c
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d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
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c
a
b
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e
,
a
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s
a
m
p
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a
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a
l
y
s
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r
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p
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a
d
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t
b
a
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s
s
f
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g
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d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 10 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
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e
W
e
s
t
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b
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a
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S
C
2
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7
2
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8
0
3
)
7
9
1
-
9
7
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0
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a
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3
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1
1
1
w
w
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:
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Cli
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b
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y
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t
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9
0
0
3
-
0
0
2
09
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0
8
/
2
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1
6
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8
4
5
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0
9
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0
1
6
Aq
u
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Ru
n
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p
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d
A
n
a
l
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l
M
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t
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A
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l
y
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i
s
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t
e
A
n
a
l
y
s
t
P
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p
D
a
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h
1
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0
0
5
A
6
0
2
0
A
1
0
9
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1
3
/
2
0
1
6
1
7
1
0
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
2
3
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5
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6
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1
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9
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1
3
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2
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1
6
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8
B
N
W
0
9
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2
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0
1
6
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7
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4
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1
7
8
0
An
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y
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i
c
a
l
CA
S
Pa
r
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Me
t
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Re
s
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l
t
Q
P
Q
L
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Al
u
m
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n
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m
7
4
2
9
-
9
0
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5
6
0
2
0
A
1
9
0
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
1
9
0
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
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4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
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n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
3
2
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
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L
1.0
Ma
n
g
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n
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7
4
3
9
-
9
6
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5
6
0
2
0
A
3
1
1
ug
/
L
5.0
Se
l
e
n
i
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m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
2
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
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e
a
n
a
l
y
s
i
s
a
r
e
r
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p
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r
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e
d
o
n
a
d
r
y
w
e
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g
h
t
b
a
s
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s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
1
1
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
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n
t
D
r
i
v
e
W
e
s
t
C
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l
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m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
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a
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(
8
0
3
)
7
9
1
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9
1
1
1
w
w
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.
s
h
e
a
l
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a
b
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c
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Sh
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e
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t
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s
,
I
n
c
.
In
o
r
g
a
n
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c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
W3
RI09003-003
09
/
0
8
/
2
0
1
6
1
1
1
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
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o
d
D
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l
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t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
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p
D
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h
1
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l
f
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t
e
)
3
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0
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0
5
0
9
/
1
0
/
2
0
1
6
0
8
4
2
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
3
/
2
0
1
6
1
6
1
0
D
M
A
2
1
8
7
3
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
3
6
0
1
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
8
4
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
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c
a
b
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e
,
a
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s
a
m
p
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l
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s
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r
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r
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p
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r
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d
o
n
a
d
r
y
w
e
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g
h
t
b
a
s
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s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 12 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
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a
x
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8
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3
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7
9
1
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1
1
1
w
w
w
.
s
h
e
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a
b
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c
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s
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c
.
IC
P
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S
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s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
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a
m
p
l
e
d
:
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M
N
C
,
I
n
c
.
W3
RI0
9
0
0
3
-
0
0
3
09
/
0
8
/
2
0
1
6
1
1
1
0
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
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a
t
e
A
n
a
l
y
s
t
P
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p
D
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t
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B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
1
7
1
5
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
3
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
5
/
2
0
1
6
0
9
2
8
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Alu
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
N
D
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
2
9
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
3
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
3
2
0
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
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2
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2
.
7
3
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L
1.0
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P
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n
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D
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=
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c
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l
q
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d
b
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d
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c
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t
w
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G
C
c
o
l
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m
n
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d
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%
ND
=
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:
Matrix:
Da
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R
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c
e
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v
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d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
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S
a
m
p
l
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d
:
ER
M
N
C
,
I
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c
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W3
B
RI09003-004
09
/
0
8
/
2
0
1
6
1
2
1
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09
/
0
9
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2
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A
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1
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6
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2
1
7
0
1
1
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M
2
5
4
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1
1
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9
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1
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A
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l
CA
S
Pa
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m
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b
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Me
t
h
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d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
7
1
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
3
8
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
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d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
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n
o
f
c
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m
p
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d
t
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c
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l
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b
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a
t
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n
r
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g
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P =
T
h
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R
P
D
b
e
t
w
e
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t
w
o
G
C
c
o
l
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m
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x
c
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d
s
4
0
%
ND
=
N
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d
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N = Recovery is out of criteria
_
H = Out of holding time Page: 14 of 77
10
6
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7
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6
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4
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1
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7
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4
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7
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A
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5.0
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9
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8
9
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6
6
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3
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20
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3
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l
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7
7
8
2
-
4
9
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2
6
0
2
0
A
N
D
2
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L
1.0
J =
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s
t
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m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
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c
a
l
q
u
a
n
t
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t
a
t
i
o
n
l
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m
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B
=
D
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c
t
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d
i
n
t
h
e
m
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t
h
o
d
b
l
a
n
k
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=
Q
u
a
n
t
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t
a
t
i
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n
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f
c
o
m
p
o
u
n
d
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c
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d
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d
t
h
e
c
a
l
i
b
r
a
t
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o
n
r
a
n
g
e
P =
T
h
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R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
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d
a
t
o
r
a
b
o
v
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t
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Q
L
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a
p
p
l
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c
a
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a
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s
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n
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s
f
l
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d
w
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h
a
"
W
"
N =
R
e
c
o
v
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r
y
i
s
o
u
t
o
f
c
r
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t
e
r
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a
_
H =
O
u
t
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f
h
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d
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n
g
t
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m
e
Pa
g
e
:
1
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7
7
10
6
V
a
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a
,
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2
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2
(
8
0
3
)
7
9
1
-
9
7
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8
0
3
)
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1
1
1
w
w
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a
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c
n
o
n
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s
De
s
c
r
i
p
t
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o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
W6
RI09003-005
09
/
0
6
/
2
0
1
6
1
7
0
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09
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0
9
/
2
0
1
6
Aqueous
Ru
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M
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A
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A
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A
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1
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2
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2
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1
1
(
T
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M
2
5
4
0
C
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1
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9
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1
6
1
6
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6
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1
7
8
9
An
a
l
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t
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c
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l
CA
S
Pa
r
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m
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t
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r
Nu
m
b
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r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
9
.
9
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
6
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
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c
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l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
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t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
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n
o
f
c
o
m
p
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u
n
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c
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d
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d
t
h
e
c
a
l
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b
r
a
t
i
o
n
r
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n
g
e
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T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
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a
b
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v
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t
h
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a
p
p
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c
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s
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N = Recovery is out of criteria
_
H = Out of holding time Page: 16 of 77
10
6
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N = Recovery is out of criteria
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H = Out of holding time Page: 18 of 77
10
6
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9
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9
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d
7
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3
9
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7
7
8
2
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4
9
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2
6
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2
0
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N
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J =
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s
t
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m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
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=
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r
a
c
t
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c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
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t
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=
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e
t
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c
t
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d
i
n
t
h
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m
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t
h
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d
b
l
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k
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a
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t
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t
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t
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n
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f
c
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p
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n
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d
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c
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l
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b
r
a
t
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n
r
a
n
g
e
P =
T
h
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R
P
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b
e
t
w
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n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
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d
s
4
0
%
ND
=
N
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t
d
e
t
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c
t
e
d
a
t
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a
b
o
v
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t
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a
p
p
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c
a
b
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n
l
e
s
s
f
l
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e
d
w
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t
h
a
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W
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N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
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m
e
Pa
g
e
:
1
9
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f
7
7
10
6
V
a
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t
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g
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P
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t
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s
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2
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7
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8
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:
Matrix:
Da
t
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R
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c
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v
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d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
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S
a
m
p
l
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d
:
ER
M
N
C
,
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c
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W8
RI09003-007
09
/
0
7
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2
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1
6
1
7
2
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A
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A
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3
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0
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2
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1
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1
1
0
6
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
3
/
2
0
1
6
1
6
1
0
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M
A
2
1
8
7
3
An
a
l
y
t
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c
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l
CA
S
Pa
r
a
m
e
t
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r
Nu
m
b
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Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
6
4
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
0
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
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t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
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a
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c
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m
p
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d
t
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e
c
a
l
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b
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n
r
a
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g
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P =
T
h
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R
P
D
b
e
t
w
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e
n
t
w
o
G
C
c
o
l
u
m
n
s
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x
c
e
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d
s
4
0
%
ND
=
N
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d
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d
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b
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a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 20 of 77
10
6
V
a
n
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D
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9
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6
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7
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9
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L
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6
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2
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6
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9
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6
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0
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s
t
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m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
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c
t
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c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
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m
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B
=
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c
t
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d
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n
t
h
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m
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t
h
o
d
b
l
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n
k
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=
Q
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a
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t
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t
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t
i
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n
o
f
c
o
m
p
o
u
n
d
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x
c
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d
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d
t
h
e
c
a
l
i
b
r
a
t
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o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
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c
t
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d
a
t
o
r
a
b
o
v
e
t
h
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Q
L
Wh
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a
p
p
l
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c
a
b
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a
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l
s
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a
m
p
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d
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n
l
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s
s
f
l
a
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g
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d
w
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t
h
a
"
W
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N =
R
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c
o
v
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y
i
s
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t
o
f
c
r
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t
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r
i
a
_
H =
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u
t
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f
h
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d
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Pa
g
e
:
2
1
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7
7
10
6
V
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3
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7
9
1
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7
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8
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1
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n
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s
De
s
c
r
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p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
W9
RI09003-008
09
/
0
6
/
2
0
1
6
1
1
3
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09
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0
9
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2
0
1
6
Aqueous
Ru
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M
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A
n
a
l
y
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A
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a
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1
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2
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1
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1
8
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L
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2
1
7
0
1
1
(
T
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M
2
5
4
0
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1
1
0
9
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2
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1
6
1
6
5
6
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2
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7
8
9
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a
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CA
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Me
t
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d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
8
.
4
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
6
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
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s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
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=
P
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c
t
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q
u
a
n
t
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t
a
t
i
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n
l
i
m
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t
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e
t
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c
t
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d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
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=
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u
a
n
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t
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c
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m
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n
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d
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c
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l
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b
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n
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h
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P
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b
e
t
w
e
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t
w
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C
c
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l
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m
n
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c
e
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d
s
4
0
%
ND
=
N
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d
a
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p
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w
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a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 22 of 77
10
6
V
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b
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0
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B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
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1
7
8
0
An
a
l
y
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c
a
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Pa
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40
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7
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9
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6
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9
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6
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1
ug
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L
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1
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m
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m
7
4
4
0
-
4
7
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3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
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6
6
0
2
0
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3
9
1
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L
20
Le
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d
7
4
3
9
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9
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1
6
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0
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N
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7
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2
0
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l
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7
7
8
2
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4
9
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2
6
0
2
0
A
N
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1
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L
1.0
J =
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s
t
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m
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d
r
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s
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t
<
P
Q
L
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n
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>
M
D
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PQ
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=
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r
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c
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l
q
u
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n
t
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t
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c
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d
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d
b
l
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p
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d
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c
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b
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T
h
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P
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b
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w
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n
t
w
o
G
C
c
o
l
u
m
n
s
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x
c
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d
s
4
0
%
ND
=
N
o
t
d
e
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a
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a
b
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Wh
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w
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N =
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c
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v
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7
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r
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p
t
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n
:
Matrix:
Da
t
e
R
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c
e
i
v
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d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
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S
a
m
p
l
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d
:
ER
M
N
C
,
I
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c
.
PW
1
RI09003-009
09
/
0
6
/
2
0
1
6
1
4
2
0
09
/
0
9
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2
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1
6
Aqueous
Ru
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A
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A
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p
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9
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2
4
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L
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2
1
7
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1
1
(
T
D
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)
S
M
2
5
4
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2
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1
1
1
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9
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1
6
1
6
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6
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M
A
2
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7
8
9
An
a
l
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c
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CA
S
Pa
r
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m
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Me
t
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Result
Q
P
Q
L
U
n
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t
s
R
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n
Su
l
f
a
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e
30
0
.
0
8
4
0
1
mg/L 25
TD
S
S
M
2
5
4
0
C
-
2
0
1
9
0
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
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c
a
l
q
u
a
n
t
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t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
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c
t
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d
i
n
t
h
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m
e
t
h
o
d
b
l
a
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k
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=
Q
u
a
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d
t
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c
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l
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b
r
a
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n
r
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g
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P =
T
h
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R
P
D
b
e
t
w
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n
t
w
o
G
C
c
o
l
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m
n
s
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x
c
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d
s
4
0
%
ND
=
N
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t
d
e
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c
t
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d
a
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b
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p
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N = Recovery is out of criteria
_
H = Out of holding time Page: 24 of 77
10
6
V
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P
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PW
1
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9
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09
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3
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6
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0
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3
B
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9
/
1
2
/
2
0
1
6
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6
0
7
0
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B
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0
9
/
1
2
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2
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1
6
1
7
3
4
2
1
7
8
0
3
3
0
0
5
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6
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A
5
0
9
/
1
5
/
2
0
1
6
0
7
1
4
B
N
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0
9
/
1
2
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2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
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t
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c
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l
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S
Pa
r
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m
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m
b
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Me
t
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d
Re
s
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l
t
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Q
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n
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t
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Al
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m
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n
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m
7
4
2
9
-
9
0
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5
6
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2
0
A
2
5
0
1
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/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
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3
6
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0
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4
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1
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/
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d
m
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1
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L
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1
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Ch
r
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7
4
4
0
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7
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6
0
2
0
A
N
D
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L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
5
3
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
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n
g
a
n
e
s
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7
4
3
9
-
9
6
-
5
6
0
2
0
A
3
3
0
0
3
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/
L
25
Se
l
e
n
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m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
2
.
5
2
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
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P
Q
L
Wh
e
r
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a
p
p
l
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c
a
b
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,
a
l
l
s
o
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a
m
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a
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d
o
n
a
d
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w
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h
t
b
a
s
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s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
2
5
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
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v
e
W
e
s
t
C
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m
b
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a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
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a
x
(
8
0
3
)
7
9
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9
1
1
1
w
w
w
.
s
h
e
a
l
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l
a
b
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c
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e
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r
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v
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c
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s
,
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n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
5
0
RI09003-010
09
/
0
7
/
2
0
1
6
0
9
1
5
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
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o
d
D
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l
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t
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o
n
A
n
a
l
y
s
i
s
D
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t
e
A
n
a
l
y
s
t
P
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e
p
D
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t
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B
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h
1
(
S
u
l
f
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t
e
)
3
0
0
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0
1
0
9
/
1
0
/
2
0
1
6
1
3
0
6
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
N
D
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
9
9
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 26 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
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9
1
1
1
w
w
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e
a
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a
b
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c
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n
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s
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I
n
c
.
IC
P
-
M
S
De
s
c
r
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p
t
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n
:
Ma
t
r
i
x
:
Da
t
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R
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c
e
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v
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d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
5
0
RI0
9
0
0
3
-
0
1
0
09
/
0
7
/
2
0
1
6
0
9
1
5
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
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p
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a
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e
B
a
t
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h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
0
3
8
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
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r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
4
1
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
4
9
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
2
9
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
1
8
0
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
2
7
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
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m
Sh
e
a
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y
E
n
v
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r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
2
5
RI09003-011
09
/
0
7
/
2
0
1
6
0
9
5
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
3
3
0
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
1
.
7
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
8
6
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 28 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
2
5
RI0
9
0
0
3
-
0
1
1
09
/
0
7
/
2
0
1
6
0
9
5
0
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
0
4
3
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
1
4
0
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
7
7
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
3
2
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
8
1
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
2
9
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
2
0
RI09003-012
09
/
0
7
/
2
0
1
6
1
0
0
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
4
4
2
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
1
.
6
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
8
9
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 30 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
2
0
RI0
9
0
0
3
-
0
1
2
09
/
0
7
/
2
0
1
6
1
0
0
0
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
0
4
8
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
3
1
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
5
9
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
1
1
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
3
6
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
3
1
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
6
0
RI09003-013
09
/
0
7
/
2
0
1
6
1
1
5
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
2
(
S
u
l
f
a
t
e
)
3
0
0
.
0
5
0
9
/
1
7
/
2
0
1
6
1
5
2
9
S
L
U
2
2
3
7
3
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
2
5
0
2
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
4
9
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 32 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
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Matrix:
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Cli
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Laboratory ID:
Da
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N = Recovery is out of criteria
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10
6
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7
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s
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d
r
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t
<
P
Q
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>
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D
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PQ
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=
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b
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c
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b
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P
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t
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C
c
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ND
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N
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d
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p
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c
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3
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c
o
m
Sh
e
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l
y
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n
v
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m
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n
t
a
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v
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s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
7
0
RI09003-015
09
/
0
7
/
2
0
1
6
1
2
1
5
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
5
5
4
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
1
.
6
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
8
1
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
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e
a
p
p
l
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c
a
b
l
e
,
a
l
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s
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s
a
m
p
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a
n
a
l
y
s
i
s
a
r
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r
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p
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r
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d
o
n
a
d
r
y
w
e
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g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
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g
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d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 36 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
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e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
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0
F
a
x
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8
0
3
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7
9
1
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9
1
1
1
w
w
w
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I
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c
.
IC
P
-
M
S
De
s
c
r
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p
t
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:
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t
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x
:
Da
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R
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c
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Cli
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n
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:
La
b
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a
t
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y
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:
Da
t
e
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a
m
p
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:
ER
M
N
C
,
I
n
c
.
SS
7
0
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9
0
0
3
-
0
1
5
09
/
0
7
/
2
0
1
6
1
2
1
5
09
/
0
9
/
2
0
1
6
Aq
u
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u
s
Ru
n
P
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p
M
e
t
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d
A
n
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c
a
l
M
e
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D
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A
n
a
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D
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t
e
A
n
a
l
y
s
t
P
r
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p
D
a
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B
a
t
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h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
1
1
2
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
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S
Pa
r
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m
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t
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Nu
m
b
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Me
t
h
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Re
s
u
l
t
Q
P
Q
L
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n
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t
s
R
u
n
Al
u
m
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n
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m
7
4
2
9
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9
0
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5
6
0
2
0
A
1
6
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
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3
6
0
2
0
A
5
2
1
ug
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L
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Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
4
7
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
1
8
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
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g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
3
7
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
8
0
RI09003-016
09
/
0
7
/
2
0
1
6
1
2
4
5
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
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l
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t
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o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
7
0
7
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
1
3
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
1
1
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
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c
a
b
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,
a
l
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l
s
a
m
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a
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l
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s
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r
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p
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d
o
n
a
d
r
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w
e
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g
h
t
b
a
s
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s
u
n
l
e
s
s
f
l
a
g
g
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d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 38 of 77
10
6
V
a
n
t
a
g
e
P
o
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n
t
D
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v
e
W
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t
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m
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7
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)
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9
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.
IC
P
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De
s
c
r
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p
t
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n
:
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t
r
i
x
:
Da
t
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c
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v
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d
:
Cli
e
n
t
:
La
b
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r
a
t
o
r
y
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D
:
Da
t
e
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a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
8
0
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9
0
0
3
-
0
1
6
09
/
0
7
/
2
0
1
6
1
2
4
5
09
/
0
9
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2
0
1
6
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u
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P
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A
n
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l
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t
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n
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A
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a
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t
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h
1
3
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0
5
A
6
0
2
0
A
1
0
9
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1
3
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2
0
1
6
2
1
1
7
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
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c
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CA
S
Pa
r
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t
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r
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m
b
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Me
t
h
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d
Re
s
u
l
t
Q
P
Q
L
U
n
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t
s
R
u
n
Al
u
m
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n
u
m
7
4
2
9
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9
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6
0
2
0
A
1
4
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
6
3
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
4
3
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
9
.
7
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
3
9
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
9
0
RI09003-017
09
/
0
7
/
2
0
1
6
1
3
0
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
7
3
1
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
4
9
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
0
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 40 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
9
0
RI0
9
0
0
3
-
0
1
7
09
/
0
7
/
2
0
1
6
1
3
0
0
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
1
2
2
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
4
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
7
3
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
2
3
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
1
7
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
4
1
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
4
0
RI09003-018
09
/
0
7
/
2
0
1
6
1
3
1
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
7
5
5
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
7
8
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
9
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
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k
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Q
u
a
n
t
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t
a
t
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f
c
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m
p
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d
t
h
e
c
a
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b
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n
r
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g
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T
h
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R
P
D
b
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w
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t
w
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G
C
c
o
l
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m
n
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x
c
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d
s
4
0
%
ND
=
N
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t
d
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N = Recovery is out of criteria
_
H = Out of holding time Page: 42 of 77
10
6
V
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7
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J =
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d
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<
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Q
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b
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d
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b
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T
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P
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b
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t
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G
C
c
o
l
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m
n
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4
0
%
ND
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:
Matrix:
Da
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R
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Cli
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Laboratory ID:
Da
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ER
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09
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Q
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T
h
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b
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t
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c
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l
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c
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N = Recovery is out of criteria
_
H = Out of holding time Page: 44 of 77
10
6
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5
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Me
t
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t
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6
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1
5
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1
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40
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4
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1
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d
m
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7
4
4
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3
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6
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1
0
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r
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m
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7
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4
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7
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3
6
0
2
0
A
N
D
1
ug
/
L
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Ir
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n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
4
9
0
1
ug
/
L
20
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a
d
7
4
3
9
-
9
2
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1
6
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2
0
A
N
D
1
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L
1.0
Ma
n
g
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n
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s
e
7
4
3
9
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9
6
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5
6
0
2
0
A
4
4
1
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/
L
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Se
l
e
n
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m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
4
5
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
0
1
RI09003-020
09
/
0
7
/
2
0
1
6
1
5
2
0
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
1
0
9
/
1
0
/
2
0
1
6
1
8
4
3
S
L
U
2
1
7
0
1
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
3
2
1
mg/L 1.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
1
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 46 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
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Sh
e
a
l
y
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n
v
i
r
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n
m
e
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t
a
l
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e
r
v
i
c
e
s
,
I
n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
0
1
RI0
9
0
0
3
-
0
2
0
09
/
0
7
/
2
0
1
6
1
5
2
0
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
2
1
3
7
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
0
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
5
7
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
7
2
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
2
1
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
5
.
2
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
4
7
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
3
0
RI09003-021
09
/
0
7
/
2
0
1
6
1
5
3
5
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
5
0
9
/
1
7
/
2
0
1
6
1
5
4
1
S
L
U
2
2
3
7
3
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
4
8
1
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
7
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 48 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
SS
3
0
RI0
9
0
0
3
-
0
2
1
09
/
0
7
/
2
0
1
6
1
5
3
5
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
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c
a
l
M
e
t
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d
D
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t
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n
A
n
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i
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a
t
e
A
n
a
l
y
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t
P
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a
t
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h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
1
5
2
2
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
1
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
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r
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m
b
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Me
t
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s
u
l
t
Q
P
Q
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n
i
t
s
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n
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u
m
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n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
4
7
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
7
0
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
9
7
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
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1.0
Ma
n
g
a
n
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e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
4
4
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
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P
Q
L
Wh
e
r
e
a
p
p
l
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c
a
b
l
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,
a
l
l
s
o
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a
m
p
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a
n
a
l
y
s
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s
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r
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p
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d
o
n
a
d
r
y
w
e
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g
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t
b
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n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
4
9
o
f
7
7
10
6
V
a
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D
r
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C
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l
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m
b
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a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
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9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
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m
Sh
e
a
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n
v
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r
o
n
m
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t
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r
v
i
c
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s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
DU
P
0
1
RI09003-022
09
/
0
7
/
2
0
1
6
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
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o
d
D
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l
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t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
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e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
5
0
9
/
1
7
/
2
0
1
6
1
5
5
3
S
L
U
2
2
3
7
3
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
2
/
2
0
1
6
1
6
5
6
D
M
A
2
1
7
8
9
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
3
5
1
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
0
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
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c
a
b
l
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,
a
l
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s
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l
s
a
m
p
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e
a
n
a
l
y
s
i
s
a
r
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r
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p
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d
o
n
a
d
r
y
w
e
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g
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t
b
a
s
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u
n
l
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s
s
f
l
a
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g
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d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 50 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
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v
e
W
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t
C
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l
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m
b
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a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
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a
x
(
8
0
3
)
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9
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1
1
1
w
w
w
.
s
h
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a
b
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c
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t
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s
,
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n
c
.
IC
P
-
M
S
De
s
c
r
i
p
t
i
o
n
:
Ma
t
r
i
x
:
Da
t
e
R
e
c
e
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v
e
d
:
Cli
e
n
t
:
La
b
o
r
a
t
o
r
y
I
D
:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
DU
P
0
1
RI0
9
0
0
3
-
0
2
2
09
/
0
7
/
2
0
1
6
09
/
0
9
/
2
0
1
6
Aq
u
e
o
u
s
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
3
0
0
5
A
6
0
2
0
A
1
0
9
/
1
3
/
2
0
1
6
1
5
2
6
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
1
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
7
1
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
6
7
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
-
4
3
-
9
6
0
2
0
A
N
D
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
2
2
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
N
D
1
ug
/
L
1.0
Ma
n
g
a
n
e
s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
6
.
3
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
e
d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
5
1
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
DU
P
0
2
RI09003-023
09
/
0
8
/
2
0
1
6
09
/
0
9
/
2
0
1
6
Aqueous
Ru
n
P
r
e
p
M
e
t
h
o
d
A
n
a
l
y
t
i
c
a
l
M
e
t
h
o
d
D
i
l
u
t
i
o
n
A
n
a
l
y
s
i
s
D
a
t
e
A
n
a
l
y
s
t
P
r
e
p
D
a
t
e
B
a
t
c
h
1
(
S
u
l
f
a
t
e
)
3
0
0
.
0
5
0
9
/
1
7
/
2
0
1
6
1
6
0
5
S
L
U
2
2
3
7
3
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
/
1
3
/
2
0
1
6
1
6
1
0
D
M
A
2
1
8
7
3
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
e
r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
7
4
1
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
3
7
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
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n
o
f
c
o
m
p
o
u
n
d
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x
c
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d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
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r
a
b
o
v
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t
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Wh
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a
p
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a
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t
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s
f
l
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g
g
e
d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 52 of 77
10
6
V
a
n
t
a
g
e
P
o
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t
D
r
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e
W
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2
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8
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3
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7
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:
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Cli
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La
b
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Da
t
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:
ER
M
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I
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DU
P
0
2
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9
0
0
3
-
0
2
3
09
/
0
8
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2
0
1
6
09
/
0
9
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2
0
1
6
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u
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Ru
n
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3
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6
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1
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0
9
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2
0
1
6
1
7
3
4
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1
7
8
1
An
a
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c
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l
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S
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l
t
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Q
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m
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m
7
4
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9
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0
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5
6
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0
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N
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1
ug
/
L
40
Ba
r
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m
7
4
4
0
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9
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3
6
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4
6
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d
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7
4
4
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3
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6
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0
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N
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1
ug
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L
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1
0
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r
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m
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7
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4
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7
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3
6
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0
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D
1
ug
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L
5.0
Ir
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n
7
4
3
9
-
8
9
-
6
6
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2
0
A
3
5
0
1
ug
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L
20
Le
a
d
7
4
3
9
-
9
2
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1
6
0
2
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N
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1
ug
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L
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n
g
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7
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6
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6
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0
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3
8
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L
5.0
Se
l
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n
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7
7
8
2
-
4
9
-
2
6
0
2
0
A
1
.
1
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
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t
B
=
D
e
t
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c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
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c
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d
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d
t
h
e
c
a
l
i
b
r
a
t
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o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
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n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
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d
s
4
0
%
ND
=
N
o
t
d
e
t
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c
t
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d
a
t
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a
b
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v
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Wh
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a
p
p
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n
l
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s
s
f
l
a
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g
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d
w
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t
h
a
"
W
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N =
R
e
c
o
v
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r
y
i
s
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u
t
o
f
c
r
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t
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r
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a
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H =
O
u
t
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f
h
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l
d
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Pa
g
e
:
5
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7
7
10
6
V
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n
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2
9
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8
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3
)
7
9
1
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7
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In
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a
n
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c
n
o
n
-
m
e
t
a
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s
De
s
c
r
i
p
t
i
o
n
:
Matrix:
Da
t
e
R
e
c
e
i
v
e
d
:
Cli
e
n
t
:
Laboratory ID:
Da
t
e
S
a
m
p
l
e
d
:
ER
M
N
C
,
I
n
c
.
PZ
2
RI09003-024
09
/
0
7
/
2
0
1
6
1
3
2
0
09
/
0
9
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2
0
1
6
Aqueous
Ru
n
P
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p
M
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t
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d
A
n
a
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t
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c
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M
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A
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A
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a
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y
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t
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p
D
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e
)
3
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0
5
0
9
/
1
7
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2
0
1
6
1
6
1
7
S
L
U
2
2
3
7
3
1
(
T
D
S
)
S
M
2
5
4
0
C
-
2
0
1
1
1
0
9
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1
2
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2
0
1
6
1
6
5
6
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M
A
2
1
7
8
9
An
a
l
y
t
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c
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l
CA
S
Pa
r
a
m
e
t
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r
Nu
m
b
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r
Me
t
h
o
d
Result
Q
P
Q
L
U
n
i
t
s
R
u
n
Su
l
f
a
t
e
30
0
.
0
5
9
1
mg/L 5.0
TD
S
S
M
2
5
4
0
C
-
2
0
2
4
0
1
mg/L 10
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
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=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
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x
c
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d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
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d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
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d
a
t
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r
a
b
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v
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t
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Q
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Wh
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a
p
p
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c
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b
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b
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f
l
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g
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d
w
i
t
h
a
"
W
"
N = Recovery is out of criteria
_
H = Out of holding time Page: 54 of 77
10
6
V
a
n
t
a
g
e
P
o
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t
D
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2
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8
0
3
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9
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7
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1
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c
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IC
P
-
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S
De
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c
r
i
p
t
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n
:
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t
r
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x
:
Da
t
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c
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v
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d
:
Cli
e
n
t
:
La
b
o
r
a
t
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r
y
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:
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t
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p
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:
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M
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C
,
I
n
c
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PZ
2
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9
0
0
3
-
0
2
4
09
/
0
7
/
2
0
1
6
1
3
2
0
09
/
0
9
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2
0
1
6
Aq
u
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Ru
n
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p
M
e
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d
A
n
a
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c
a
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M
e
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A
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P
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h
1
3
0
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5
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6
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2
0
A
1
0
9
/
1
3
/
2
0
1
6
1
5
3
6
B
N
W
0
9
/
1
2
/
2
0
1
6
1
7
3
4
2
1
7
8
1
An
a
l
y
t
i
c
a
l
CA
S
Pa
r
a
m
e
t
e
r
Nu
m
b
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r
Me
t
h
o
d
Re
s
u
l
t
Q
P
Q
L
U
n
i
t
s
R
u
n
Al
u
m
i
n
u
m
7
4
2
9
-
9
0
-
5
6
0
2
0
A
1
9
0
0
1
ug
/
L
40
Ba
r
i
u
m
7
4
4
0
-
3
9
-
3
6
0
2
0
A
2
3
0
1
ug
/
L
5.0
Ca
d
m
i
u
m
7
4
4
0
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4
3
-
9
6
0
2
0
A
1
.
3
1
ug
/
L
0.
1
0
Ch
r
o
m
i
u
m
7
4
4
0
-
4
7
-
3
6
0
2
0
A
N
D
1
ug
/
L
5.0
Ir
o
n
7
4
3
9
-
8
9
-
6
6
0
2
0
A
1
9
0
0
0
1
ug
/
L
20
Le
a
d
7
4
3
9
-
9
2
-
1
6
0
2
0
A
8
.
5
1
ug
/
L
1.0
Ma
n
g
a
n
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s
e
7
4
3
9
-
9
6
-
5
6
0
2
0
A
4
5
0
0
1
ug
/
L
5.0
Se
l
e
n
i
u
m
7
7
8
2
-
4
9
-
2
6
0
2
0
A
N
D
1
ug
/
L
1.0
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
B
=
D
e
t
e
c
t
e
d
i
n
t
h
e
m
e
t
h
o
d
b
l
a
n
k
E
=
Q
u
a
n
t
i
t
a
t
i
o
n
o
f
c
o
m
p
o
u
n
d
e
x
c
e
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d
e
d
t
h
e
c
a
l
i
b
r
a
t
i
o
n
r
a
n
g
e
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
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r
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p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
H =
O
u
t
o
f
h
o
l
d
i
n
g
t
i
m
e
Pa
g
e
:
5
5
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
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v
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W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
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a
x
(
8
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1
1
1
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w
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a
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b
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c
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n
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e
r
v
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c
e
s
,
I
n
c
.
QC
S
u
m
m
a
r
y
Page: 56 of 77
10
6
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P
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c
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In
o
r
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a
n
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c
n
o
n
-
m
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a
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-
M
B
Ba
t
c
h
:
Sa
m
p
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I
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RQ
2
1
7
0
1
-
0
0
1
21
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An
a
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y
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a
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M
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0
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0
Ma
t
r
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:
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R
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l
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P
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An
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D
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Dil
Su
l
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D
09
/
1
0
/
2
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1
6
0
7
0
6
1.
0
m
g
/
L
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
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d
a
t
o
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a
b
o
v
e
t
h
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P
Q
L
Wh
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a
p
p
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c
a
b
l
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,
a
l
l
s
o
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a
m
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n
a
l
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s
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r
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r
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d
o
n
a
d
r
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w
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i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
R
P
D
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
Pa
g
e
:
5
7
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
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a
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8
0
3
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7
9
1
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9
1
1
1
w
w
w
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,
I
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c
.
In
o
r
g
a
n
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c
n
o
n
-
m
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t
a
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-
L
C
S
Ba
t
c
h
:
Sa
m
p
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e
I
D
:
RQ
2
1
7
0
1
-
0
0
2
21
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An
a
l
y
t
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c
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l
M
e
t
h
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d
:
30
0
.
0
Matrix:Aqueous
Pa
r
a
m
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t
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r
Re
s
u
l
t
Q% Rec
Sp
i
k
e
Am
o
u
n
t
Analysis Date% Rec Limit
Di
l
(m
g
/
L
)
(
m
g
/
L
)
Su
l
f
a
t
e
1
8
0
9
/
1
0
/
2
0
1
6
0
7
3
0
91
20
9
0
-
1
1
0
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N = Recovery is out of criteria
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ = RPD is out of criteria
_
Page: 58 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
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7
9
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1
1
w
w
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b
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c
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n
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In
o
r
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a
n
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n
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t
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M
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Ba
t
c
h
:
Sa
m
p
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D
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9
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3
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0
0
5
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S
21
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1
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a
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t
r
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D
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%
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Lim
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Sa
m
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Am
o
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t
Dil
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g
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L
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(
m
g
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L
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(
m
g
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Su
l
f
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2
9
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9
/
1
0
/
2
0
1
6
0
9
5
4
97
20
9
0
-
1
1
0
9.9
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
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d
b
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f
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r
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r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
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r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
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e
a
n
a
l
y
s
i
s
a
r
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r
e
p
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r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
R
P
D
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
Pa
g
e
:
5
9
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
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a
l
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a
b
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c
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n
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In
o
r
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a
n
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c
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o
n
-
m
e
t
a
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M
S
D
Ba
t
c
h
:
Sa
m
p
l
e
I
D
:
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9
0
0
3
-
0
0
5
M
D
21
7
0
1
An
a
l
y
t
i
c
a
l
M
e
t
h
o
d
:
30
0
.
0
Matrix:Aqueous
Pa
r
a
m
e
t
e
r
Re
s
u
l
t
Q% Rec
Sp
i
k
e
Am
o
u
n
t
Analysis Date % RPD% Rec Limit% RPD Limit
Sa
m
p
l
e
Am
o
u
n
t
Dil
(m
g
/
L
)
(
m
g
/
L
)
(
m
g
/
L
)
Su
l
f
a
t
e
2
9
0
9
/
1
0
/
2
0
1
6
1
0
1
8
97
20
9
0
-
1
1
0
0.16
2
0
9.
9
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
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P =
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c
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0
%
+ = RPD is out of criteria
_
Page: 60 of 77
10
6
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c
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%
+ = RPD is out of criteria
_
Page: 62 of 77
10
6
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n
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C
c
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e
x
c
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d
s
4
0
%
+ = RPD is out of criteria
_
Page: 64 of 77
10
6
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n
t
Dil
(m
g
/
L
)
(
m
g
/
L
)
TD
S
3
0
0
0
9
/
1
2
/
2
0
1
6
1
6
5
6
14
2
0
26
0
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
R
P
D
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
Pa
g
e
:
6
5
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
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c
o
m
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n
v
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r
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n
m
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n
t
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l
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e
r
v
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s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
-
D
u
p
l
i
c
a
t
e
Ba
t
c
h
:
Sa
m
p
l
e
I
D
:
RI0
9
0
0
3
-
0
2
2
D
U
21
7
8
9
An
a
l
y
t
i
c
a
l
M
e
t
h
o
d
:
SM
2
5
4
0
C
-
2
0
1
1
Matrix:Aqueous
Pa
r
a
m
e
t
e
r
Re
s
u
l
t
Q
Analysis Date % RPD% RPD Limit
Sa
m
p
l
e
Am
o
u
n
t
Di
l
(m
g
/
L
)
(
m
g
/
L
)
TD
S
2
3
0
0
9
/
1
2
/
2
0
1
6
1
6
5
6
13
2
0
20
0
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N = Recovery is out of criteria
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ = RPD is out of criteria
_
Page: 66 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
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F
a
x
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8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
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s
h
e
a
l
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b
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c
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n
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r
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n
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t
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r
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n
c
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o
r
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a
n
i
c
n
o
n
-
m
e
t
a
l
s
-
M
B
Ba
t
c
h
:
Sa
m
p
l
e
I
D
:
RQ
2
1
8
7
3
-
0
0
1
21
8
7
3
An
a
l
y
t
i
c
a
l
M
e
t
h
o
d
:
SM
2
5
4
0
C
-
2
0
1
1
Ma
t
r
i
x
:
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u
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o
u
s
Pa
r
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m
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r
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u
l
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P
Q
L
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n
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s
An
a
l
y
s
i
s
D
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t
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Dil
TD
S
N
D
09
/
1
3
/
2
0
1
6
1
6
1
0
10
m
g
/
L
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
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d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
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d
r
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u
n
d
-
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f
f
e
r
r
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r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
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r
t
e
d
o
n
a
d
r
y
w
e
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g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
R
P
D
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
_
Pa
g
e
:
6
7
o
f
7
7
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
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Sh
e
a
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y
E
n
v
i
r
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m
e
n
t
a
l
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e
r
v
i
c
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s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
-
L
C
S
Ba
t
c
h
:
Sa
m
p
l
e
I
D
:
RQ
2
1
8
7
3
-
0
0
2
21
8
7
3
An
a
l
y
t
i
c
a
l
M
e
t
h
o
d
:
SM
2
5
4
0
C
-
2
0
1
1
Matrix:Aqueous
Pa
r
a
m
e
t
e
r
Re
s
u
l
t
Q% Rec
Sp
i
k
e
Am
o
u
n
t
Analysis Date% Rec Limit
Di
l
(m
g
/
L
)
(
m
g
/
L
)
TD
S
1
5
0
0
0
9
/
1
3
/
2
0
1
6
1
6
1
0
97
15
0
0
9
0
-
1
1
0
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
e
d
b
e
f
o
r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N = Recovery is out of criteria
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ = RPD is out of criteria
_
Page: 68 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
i
v
e
W
e
s
t
C
o
l
u
m
b
i
a
,
S
C
2
9
1
7
2
(
8
0
3
)
7
9
1
-
9
7
0
0
F
a
x
(
8
0
3
)
7
9
1
-
9
1
1
1
w
w
w
.
s
h
e
a
l
y
l
a
b
.
c
o
m
Sh
e
a
l
y
E
n
v
i
r
o
n
m
e
n
t
a
l
S
e
r
v
i
c
e
s
,
I
n
c
.
In
o
r
g
a
n
i
c
n
o
n
-
m
e
t
a
l
s
-
D
u
p
l
i
c
a
t
e
Ba
t
c
h
:
Sa
m
p
l
e
I
D
:
RI0
9
0
0
3
-
0
0
1
D
U
21
8
7
3
An
a
l
y
t
i
c
a
l
M
e
t
h
o
d
:
SM
2
5
4
0
C
-
2
0
1
1
Ma
t
r
i
x
:
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u
e
o
u
s
Pa
r
a
m
e
t
e
r
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s
u
l
t
Q
An
a
l
y
s
i
s
D
a
t
e
%
R
P
D
%
R
P
D
Lim
i
t
Sa
m
p
l
e
Am
o
u
n
t
Dil
(m
g
/
L
)
(
m
g
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L
)
TD
S
2
8
0
0
0
9
/
1
3
/
2
0
1
6
1
6
1
0
12
2
0
25
0
0
1
No
t
e
:
C
a
l
c
u
l
a
t
i
o
n
s
a
r
e
p
e
r
f
o
r
m
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d
b
e
f
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r
e
r
o
u
n
d
i
n
g
t
o
a
v
o
i
d
r
o
u
n
d
-
o
f
f
e
r
r
o
r
s
i
n
c
a
l
c
u
l
a
t
e
d
r
e
s
u
l
t
s
PQ
L
=
P
r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
o
t
d
e
t
e
c
t
e
d
a
t
o
r
a
b
o
v
e
t
h
e
P
Q
L
Wh
e
r
e
a
p
p
l
i
c
a
b
l
e
,
a
l
l
s
o
i
l
s
a
m
p
l
e
a
n
a
l
y
s
i
s
a
r
e
r
e
p
o
r
t
e
d
o
n
a
d
r
y
w
e
i
g
h
t
b
a
s
i
s
u
n
l
e
s
s
f
l
a
g
g
e
d
w
i
t
h
a
"
W
"
J =
E
s
t
i
m
a
t
e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
i
t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
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Page: 70 of 77
10
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_
Page: 72 of 77
10
6
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+ =
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P
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7
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S
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8
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3005A 09/12/2016 1734
An
a
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c
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M
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t
h
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d
:
60
2
0
A
Matrix:Aqueous
Pa
r
a
m
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Re
s
u
l
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Q% Rec
Sp
i
k
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Am
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t
Analysis Date% Rec Limit
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m
p
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Am
o
u
n
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u
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m
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1
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6
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1
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1
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r
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d
m
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a
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n
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r
a
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t
i
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l
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a
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t
i
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p
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f
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d
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s
t
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m
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d
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P
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L
a
n
d
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M
D
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N = Recovery is out of criteria
P =
T
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e
R
P
D
b
e
t
w
e
e
n
t
w
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G
C
c
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l
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n
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e
x
c
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d
s
4
0
%
+ = RPD is out of criteria
_
Page: 74 of 77
10
6
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a
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n
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l
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1
No
t
e
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a
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c
u
l
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t
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n
s
a
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r
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v
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f
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r
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c
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c
u
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a
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d
r
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s
u
l
t
s
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L
=
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r
a
c
t
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c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
ND
=
N
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t
d
e
t
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c
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d
a
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a
b
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v
e
t
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L
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a
p
p
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a
b
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,
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l
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s
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a
m
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n
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s
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d
w
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J =
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s
t
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m
a
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d
r
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s
u
l
t
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P
Q
L
a
n
d
>
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D
L
N =
R
e
c
o
v
e
r
y
i
s
o
u
t
o
f
c
r
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t
e
r
i
a
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ =
R
P
D
i
s
o
u
t
o
f
c
r
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t
e
r
i
a
_
Pa
g
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:
7
5
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f
7
7
10
6
V
a
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P
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9
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m
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1
7
8
1
-
0
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21
7
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1
3005A 09/12/2016 1734
An
a
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y
t
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c
a
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M
e
t
h
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d
:
60
2
0
A
Matrix:Aqueous
Pa
r
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m
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t
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r
R
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s
u
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t
Q
P
Q
L
U
n
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t
s
Analysis Date
Di
l
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m
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n
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m
N
D
09/13/2016
1
4
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8
40
u
g
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L
1
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r
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09/13/2016
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d
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m
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09/13/2016
1
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m
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09/13/2016
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n
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09/13/2016
1
4
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20
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d
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09/13/2016
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09/13/2016
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l
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m
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1
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1
No
t
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:
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a
l
c
u
l
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t
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s
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r
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r
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d
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t
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d
r
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n
d
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f
f
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r
r
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c
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l
c
u
l
a
t
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d
r
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s
u
l
t
s
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L
=
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r
a
c
t
i
c
a
l
q
u
a
n
t
i
t
a
t
i
o
n
l
i
m
i
t
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=
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o
t
d
e
t
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c
t
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d
a
t
o
r
a
b
o
v
e
t
h
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a
p
p
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c
a
b
l
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,
a
l
l
s
o
i
l
s
a
m
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n
a
l
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s
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s
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f
l
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d
w
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s
t
i
m
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e
d
r
e
s
u
l
t
<
P
Q
L
a
n
d
>
M
D
L
N = Recovery is out of criteria
P =
T
h
e
R
P
D
b
e
t
w
e
e
n
t
w
o
G
C
c
o
l
u
m
n
s
e
x
c
e
e
d
s
4
0
%
+ = RPD is out of criteria
_
Page: 76 of 77
10
6
V
a
n
t
a
g
e
P
o
i
n
t
D
r
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W
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m
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.
APPENDIX C
GROUNDWATER SAMPLING
LOGS
ERM consulting services worldwide www.erm.com
ERM has over 150 offices
across the following
countries worldwide
ERM’s Charlotte, North Carolina Office
ERM NC, Inc.
15720 Brixham Hill Avenue, Suite 120
Charlotte, North Carolina 28277
T: 704-541-8345
F: 704-624-7928
www.erm.com
Argentina New Zealand
Australia Panama
Belgium Peru
Brazil Poland
Canada Portugal
China Puerto Rico
Colombia Romania
France Russia
Germany Singapore
Hong Kong South Africa
India South Korea
Indonesia Spain
Ireland Sweden
Italy Taiwan
Japan Thailand
Kazakhstan The Netherlands
Kenya United Arab Emirates
Malaysia United Kingdom
Mexico United States
Mozambique Vietnam