1910_Brickhaven_RiverbendPCBSampleResults_Feb2017_DIN27752_20170309

#=CL#
March 09, 2017
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92329882
92329882
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17020392
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 14, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92329882
J17020392
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92329882
J17020392
Lab ID Sample ID Matrix Date Collected Date Received
92329882001 2017005223 Solid 02/14/17 10:00 02/14/17 15:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92329882
J17020392
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92329882001 2017005223 EPA 8082 8 PASI-CSWB
EPA 6010 7 PASI-ASH1
EPA 7470 1 PASI-AWAB
ASTM D2974-87 1 PASI-CCLW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 18
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92329882
J17020392
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92329882001 2017005223
PCB-1260 (Aroclor 1260)0.079 mg/kg 02/21/17 15:050.046EPA 8082
Arsenic 0.10 mg/L 02/17/17 09:030.050EPA 6010
Barium 1.8 mg/L 02/17/17 09:030.25EPA 6010
Percent Moisture 28.2 %02/15/17 07:050.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92329882
J17020392
Method:
Client:Duke Energy
EPA 8082
Date:March 09, 2017
Description:8082 GCS PCB
General Information:
1 sample was analyzed for EPA 8082. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92329882
J17020392
Method:
Client:Duke Energy
EPA 6010
Date:March 09, 2017
Description:6010 MET ICP, TCLP
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3010A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92329882
J17020392
Method:
Client:Duke Energy
EPA 7470
Date:March 09, 2017
Description:7470 Mercury, TCLP
General Information:
1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329882
J17020392
Sample:2017005223 Lab ID:92329882001 Collected:02/14/17 10:00 Received:02/14/17 15:10 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8082 Preparation Method: EPA 35468082 GCS PCB
PCB-1016 (Aroclor 1016)ND mg/kg 02/21/17 15:05 12674-11-202/20/17 16:000.046 1
PCB-1221 (Aroclor 1221)ND mg/kg 02/21/17 15:05 11104-28-202/20/17 16:000.046 1
PCB-1232 (Aroclor 1232)ND mg/kg 02/21/17 15:05 11141-16-502/20/17 16:000.046 1
PCB-1242 (Aroclor 1242)ND mg/kg 02/21/17 15:05 53469-21-902/20/17 16:000.046 1
PCB-1248 (Aroclor 1248)ND mg/kg 02/21/17 15:05 12672-29-602/20/17 16:000.046 1
PCB-1254 (Aroclor 1254)ND mg/kg 02/21/17 15:05 11097-69-102/20/17 16:000.046 1
PCB-1260 (Aroclor 1260)0.079 mg/kg 02/21/17 15:05 11096-82-502/20/17 16:000.046 1
Surrogates
Decachlorobiphenyl (S)62 %02/21/17 15:05 2051-24-302/20/17 16:0021-132 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 02/15/17 19:00 Initial pH: 7; Final pH: 5
6010 MET ICP, TCLP
Arsenic 0.10 mg/L 02/17/17 09:03 7440-38-202/16/17 19:300.050 1
Barium 1.8 mg/L 02/17/17 09:03 7440-39-302/16/17 19:300.25 1
Cadmium ND mg/L 02/17/17 09:03 7440-43-902/16/17 19:300.0050 1
Chromium ND mg/L 02/17/17 09:03 7440-47-302/16/17 19:300.050 1
Lead ND mg/L 02/17/17 09:03 7439-92-102/16/17 19:300.025 1
Selenium ND mg/L 02/17/17 09:03 7782-49-202/16/17 19:300.10 1
Silver ND mg/L 02/17/17 09:03 7440-22-402/16/17 19:300.025 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 02/15/17 19:00 Initial pH: 7; Final pH: 5
7470 Mercury, TCLP
Mercury ND mg/L 02/17/17 11:49 7439-97-602/16/17 22:220.00020 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 28.2 %02/15/17 07:050.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329882
J17020392
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348658
EPA 7470
EPA 7470
7470 Mercury TCLP
Associated Lab Samples:92329882001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1934567
Associated Lab Samples:92329882001
Matrix:Water
Analyzed
Mercury mg/L ND 0.00020 02/17/17 11:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934568LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/L 0.0024.0025 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934569MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329847001
1934570
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/L .0025 92 75-12593 2 20.0025ND 0.0023 0.0024
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329882
J17020392
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348654
EPA 3010A
EPA 6010
6010 MET TCLP
Associated Lab Samples:92329882001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1934555
Associated Lab Samples:92329882001
Matrix:Water
Analyzed
Arsenic mg/L ND 0.050 02/17/17 08:18
Barium mg/L ND 0.25 02/17/17 08:18
Cadmium mg/L ND 0.0050 02/17/17 08:18
Chromium mg/L ND 0.050 02/17/17 08:18
Lead mg/L ND 0.025 02/17/17 08:18
Selenium mg/L ND 0.10 02/17/17 08:18
Silver mg/L ND 0.025 02/17/17 08:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934556LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/L 2.52.5 99 80-120
Barium mg/L 2.32.5 91 80-120
Cadmium mg/L 2.42.5 96 80-120
Chromium mg/L 2.42.5 94 80-120
Lead mg/L 2.32.5 93 80-120
Selenium mg/L 2.52.5 100 80-120
Silver mg/L 1.21.2 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934557MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35295057001
1934558
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/L 2.5 98 75-12597 1 202.50.014U 2.4 2.4
Barium mg/L 2.5 91 75-12590 1 202.50.13J 2.4 2.4
Cadmium mg/L 2.5 95 75-12594 1 202.50.0025U 2.4 2.4
Chromium mg/L 2.5 92 75-12590 2 202.50.0038J 2.3 2.3
Lead mg/L 2.5 91 75-12590 1 202.50.020U 2.3 2.2
Selenium mg/L 2.5 98 75-12598 0 202.50.019U 2.5 2.5
Silver mg/L 1.2 95 75-12595 0 201.20.0055J 1.2 1.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329882
J17020392
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349017
EPA 3546
EPA 8082
8082 GCS PCB
Associated Lab Samples:92329882001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1936306
Associated Lab Samples:92329882001
Matrix:Solid
Analyzed
PCB-1016 (Aroclor 1016)mg/kg ND 0.033 02/22/17 00:45
PCB-1221 (Aroclor 1221)mg/kg ND 0.033 02/22/17 00:45
PCB-1232 (Aroclor 1232)mg/kg ND 0.033 02/22/17 00:45
PCB-1242 (Aroclor 1242)mg/kg ND 0.033 02/22/17 00:45
PCB-1248 (Aroclor 1248)mg/kg ND 0.033 02/22/17 00:45
PCB-1254 (Aroclor 1254)mg/kg ND 0.033 02/22/17 00:45
PCB-1260 (Aroclor 1260)mg/kg ND 0.033 02/22/17 00:45
Decachlorobiphenyl (S)%111 21-132 02/22/17 00:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936307LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)mg/kg 0.15.17 89 31-120
PCB-1260 (Aroclor 1260)mg/kg 0.17.17 103 32-120
Decachlorobiphenyl (S)%123 21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329882
J17020392
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348190
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92329882001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329847001
1931982SAMPLE DUPLICATE:
Percent Moisture %20.6 3 2519.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329829006
1931983SAMPLE DUPLICATE:
Percent Moisture %16.3 1 2516.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92329882
J17020392
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92329882
J17020392
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92329882001 349017 3491762017005223EPA 3546 EPA 8082
92329882001 348654 3486622017005223EPA 3010A EPA 6010
92329882001 348658 3487512017005223EPA 7470 EPA 7470
92329882001 3481902017005223ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:47 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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