0401_AnsonCountyLF_GWCessReq_DIN27684_20170227

SCS Engineers, P.C. Environmental Consultants 2520 Whitehall Park Drive 704 504-3107
and Contractors Suite 450 FAX [phone] Charlotte, NC 28273-3557 www.scsengineers.com

February 27, 2017 File No. 02209366.04

Mr. Ervin Lane, Hydrogeologist
North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section
217 West Jones Street
Raleigh, North Carolina 27603

Subject: Closed Anson County Landfill - Facility Permit Number 0401-MSWLF-1973 2016 Annual Water Quality Monitoring Report

Dear Mr. Lane:
On behalf of Anson County, SCS Engineers, PC is submitting the attached 2016 Annual Water Quality Monitoring Report (Report) for the closed Anson County Landfill, Facility Permit
Number 0401-MSWLF-1973. The 2016 monitoring event is the fifth and final of the requested
annual groundwater monitoring events for five (5) years. This request is based on a letter dated
May 16, 2011, from Mr. Ervin Lane with NCDENR (currently NCDEQ), Division of Waste Management, Solid Waste Section. In addition to the Report, an Environmental Monitoring Reporting Form and the electronic data deliverable is being submitted.
In summary, during this monitoring event no 40 CFR Part 258 Appendix I organic constituents
were detected within the Landfill’s four groundwater monitoring wells. The four wells consist of
one upgradient and three downgradient of the landfill. During this monitoring event four (4) Appendix I inorganic constituents were detected within the monitoring wells, three of which were below their respective 15A NCAC 02L .0202 Groundwater Quality Standard compliance
limit (or the Groundwater Protection Standard, if a 2L standard has not been established). These
inorganics include Barium in all four monitoring wells, and Cobalt, Nickel, and Zinc in
monitoring well MW-D only. Cobalt was the only inorganic detected above its respective North Carolina Groundwater Protection Standard of 1 µg/L in MW-D. The monitoring event laboratory analytical results for all four monitoring wells are included in the Report as Table 2.
Historical groundwater monitoring laboratory analytical results are included as Table 3.
As stated previously, no Appendix I organics or volatile organic compounds (VOCs) were
detected during this monitoring event. A VOC was last detected during the April 2013 annual monitoring event. The detected VOC was Chlorobenzene in monitoring well MW-C and was at a concentration of 1.4 µg/L, well below its 2L compliance limit of 50 µg/L. Historically, the
levels of Chlorobenzene have been below the compliance limit and have decreased over time.
SCS Engineers, PC proposes that certain Appendix I inorganics or metals are naturally occurring
within the in-situ soils and are not caused by a release from the landfill. An example of this is a
Mr. Ervin Lane, Hydrogeologist
February 27, 2017
Page 2
closed MSW landfill located in Union County, North Carolina where groundwater alternate
source demonstrations(1) were completed and the metals Barium, Beryllium, Chromium, Cobalt,
Copper, Lead, Nickel, Vanadium and Zinc were determined to be naturally occurring in the in-
situ soils at considerable levels. The landfill located in Union County is within the vicinity of
and has similar geologic conditions to the closed Anson County - Lilesville Landfill. In the demonstrations, the reasonable expected concentration for Cobalt in groundwater was 288 µg/L,
Barium was 255.75 µg/L, Nickel was 86.33 µg/L and Zinc was 221.53 µg/L. As such, the
existence of these metals in the in-situ soils at similar levels at the Anson County - Lilesville
Landfill is probable.
Based on the results from the last five years of groundwater monitoring and information and analysis presented in this letter, SCS Engineers, PC on behalf of Anson County requests the
termination of future groundwater monitoring at the Closed Anson County - Lilesville Landfill
as stipulated in the January 18, 1996 landfill closure letter from Mr. James Coffey with the
Department of Environment, Health and Natural Resources - DEHNR (currently NCDEQ) to
Anson County. The referenced closure letter is included in Attachment 4 of the 2016 Annual Water Quality Monitoring Report.
If you have any questions or need additional information please do not hesitate to contact either
of the undersigned at 704-504-3107 ([e-mail]) or Mr. Mike Sessions, Anson
County’s Utilities Director at 704-694-5208.
Sincerely,
Donald Michael Cobb, PG

Albert Glenn, PE
Senior Project Professional Project Manager
SCS ENGINEERS, PC SCS ENGINEERS, PC cc: Mike Sessions – Anson County

Attachments: 2016 Annual Water Quality Monitoring Report, Environmental Monitoring
Reporting Form, and Electronic Data Deliverable.

(1) Reference: Alternate Source Demonstration Report, Union County Landfill, Wingate North Carolina dated July 2008 and Revised Alternate Source Demonstration for the Union County Landfill dated November 2012.
Water Quality Monitoring Report
2016 Annual Sampling Event
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SCS Engineers, PC (SCS) is submitting this Water Quality Monitoring Report for the closed
Anson County Landfill, a.k.a. Lilesville Landfill, on behalf of the Anson County Utilities
Department. The Landfill’s North Carolina Department of Natural Resources (NCDENR)
facility permit number is 0401-MSWLF-1973. This report provides background information, description of field activities, data, and summary and analysis of the laboratory analytical results
from the groundwater monitoring sampling event conducted on December 19, 2016.
This monitoring event is the fifth (5th) annual monitoring event for a five (5) year period as
requested in a letter dated May 16, 2011 from Mr. Ervin Lane, Compliance Hydrogeologist with NCDENR (currently NCDEQ), Division of Waste Management - Solid Waste Section.
1 BACKGROUND
There are two (2) solid waste landfills, approximately 49.7 and 11.6-acres in size that previously operated along Haileys Ferry Road (SR 1801) in Lilesville, North Carolina. See attached Figure No. 1 for the landfill locations and approximate landfilled waste extents. The 49.7-acre landfill
began operations before 1972 and was closed prior to 1978. The 11.6-acre landfill which is
permitted and subjected to groundwater monitoring was closed with a final cover system in the
fall of 1994 with landfill operations dating back to 1978. The 11.6-acre landfill facility permit number is 0401-MSWLF-1973. Both landfills are unlined.
Based on a letter dated January 18, 1996 from Mr. James Coffey with the Department of
Environment, Health and Natural Resources - DEHNR (currently NCDEQ) to Anson County, the
permitted 11.6-acre landfill was considered officially closed subject to post-closure conditions
including groundwater monitoring for a minimum of five (5) years from the beginning of the post-closure period. This letter is included in Attachment 4 for reference. Since 1994, the landfill has been in a post-closure care period. Based on review of previously prepared
documentation, groundwater monitoring has been conducted at the permitted landfill since 1992.
Currently, the groundwater monitoring program at the landfill consists of four monitoring wells:
one (1) background well and three (3) compliance wells. The background well is designated as MW-A with the compliance wells being designated as MW- B, MW-C, and MW-D.
A Groundwater Monitoring Evaluation Report dated March 18, 2011 was prepared and
submitted to NCDENR by Engineering & Environmental Science Company (E2S) of Raleigh,
North Carolina on behalf of Anson County. This report outlined the historical groundwater
monitoring results at the landfill from 1992 to 2006, evaluating the need to continue with groundwater monitoring and a request to stop further groundwater monitoring at the landfill.
The County received a letter dated May 16, 2011 from Mr. Ervin Lane with NCDENR (currently
NCDEQ), Division of Waste Management stating that the Division had reviewed the
Groundwater Monitoring Evaluation Report including the request to stop the groundwater
monitoring and determined that the County needs to continue groundwater monitoring on an annual basis for the next five (5) years. The letter also stated after five (5) years of additional
monitoring, the monitoring results will be re-evaluated by the NCDENR to determine the need
for continued groundwater monitoring at the landfill. The letter from NCDENR is included in
Attachment 4 for reference.

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2016 Annual Sampling Event
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2 FIELD ACTIVITIES
On December 19, 2016, SCS personnel collected groundwater samples from the four (4) existing monitoring wells at the Anson County Landfill for laboratory analysis of constituents listed in Appendix I of the 40 Code of Federal Regulations (CFR) Part 258. The list of Appendix I
constituents is included for reference in Attachment 2. The wells are designated as MW-A,
MW-B, MW-C, and MW-D. Groundwater was purged and samples were collected from the
monitoring wells using low flow sampling procedures. During the purging process for MW-D three well volumes were not able to be removed from the well due to the well going dry before purging was complete. In addition, this well had minimal well recharge.
SCS’s field sampling logs containing field measurements for pH, conductivity, temperature,
water levels, and dissolved oxygen are included in Attachment 1.
3 GROUNDWATER LEVELS AND FLOW
Water level data for the December 19, 2016 sampling event is summarized in Table 1. Based on
the water level data, a Groundwater Surface Contour Map is presented as Figure 1. The groundwater flow direction is primarily towards the eastern property boundary. The calculated groundwater flow velocity and estimated values for hydraulic conductivity and porosity are
included below in Table 1. Please note that for all the monitoring wells, the estimated values for
hydraulic conductivity and effective porosity in Table 1 are from the Groundwater Monitoring
Evaluation Report prepared by Engineering & Environmental Science Company (E2S) dated March 18, 2011.
TABLE 1
Groundwater Level and Flow Data
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Well
ID Date GS Well TOC K n DTW WL-Elev. I V
Elevation Depth Elevation (ft/yr) (feet) (feet) (ft/ft) (ft/yr)
MW-A 12-19-16 NM 27.82 462.63 517.21 0.25 11.96 450.67 0.020 40.76
MW-B 12-19-16 NM 28.08 451.20 517.21 0.25 14.32 436.88 0.020 40.76
MW-C 12-19-16 NM 22.55 438.19 517.21 0.25 3.53 434.66 0.005 10.94
MW-D 12-19-16 NM 35.53 436.16 517.21 0.25 5.19 430.97 0.005 10.04
Legend:
GS = ground surface TOC = top of casing NM = Not Measured
WL-Elev = water level elevation DTW = depth to water from TOC (measured) V = groundwater flow rate (calculated); V = (K*I)/n
n = effective porosity (estimated based on previous GW monitoring
reports and site conditions)
K = hydraulic conductivity (estimated based on previous GW monitoring
reports and site conditions)
I = hydraulic gradient (calculated); I = WL-elev. difference / horizontal
distance
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2016 Annual Sampling Event
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4 WATER QUALITY
40 CFR Part 258 Appendix I detected constituents with their analytical concentration were compared against the North Carolina Department of Environment and Natural Resources (NCDENR) rule 15A NCAC 02L .0202 Groundwater Quality Standards (2L). When a 15A
NCAC 02L .0202 Groundwater Quality Standard is not available for a detected constituent, the
result is compared against the North Carolina Groundwater Protection Standard (GWP). The
following Table 2 lists the Appendix I detected constituents analytical results from the December 2016 annual water quality monitoring event. In Table 2, constituent analytical results that exceed their associated 2L or GWP compliance limit are shaded. A hard copy of the
laboratory report from Pace Analytical Services, Inc. with a copy of the chain-of-custody form is
included in Attachment 3.
TABLE 2
Summary of Groundwater Quality Data - Appendix I Constituents
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Parameter Sampling
Date
Compliance Limit (µg/L) Analytical Results for Sample Locations
(in µg/L)
SWSL 15A NCAC 02L MW-A MW-B MW-C MW-D
Barium 12-18-2016 100 700 19.5 10.6 39.1 54.0
Cobalt 12-18-2016 10 1 (GWP) ND<5 ND<5 ND<5 5.1
Nickel 12-18-2016 50 100 ND<5 ND<5 ND<5 5.5
Zinc 12-18-2016 10 1000 ND<10 ND<10 ND<10 15.2

Legend:
µg/L = Micrograms per Liter Bold font indicates analyte detection.
Shaded field denotes result that exceeds Compliance Limit. SWSL = Solid Waste Section Limit
GWP = Groundwater Protection Standard (2L Standard not established) NE = Not established
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
4.1 GROUNDWATER ANALYTICAL RESULTS
The description of the Appendix I organic and inorganic constituents detected during the 2016
annual groundwater monitoring event are as follows:
4.1.1 ORGANIC CONSTITUENTS
No Appendix I organic constituents were detected during the monitoring event.

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2016 Annual Sampling Event
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4.1.2 INORGANIC CONSTITUENTS
Barium, Cobalt, Nickel, and Zinc were the only Appendix I inorganic constituents detected in one or more of the monitoring wells. Only cobalt was detected above its compliance limit of 1 µg/L. These detections are summarized as follows:
• Barium was detected in all four (4) monitoring wells below its 2L compliance limit
of 700 µg/L. In background monitoring well MW-A the concentration was 19.5
µg/L. In compliance well MW-B the concentration was 10.6 µg/L, MW-C was 39.1
µg/L, and MW-D was 54.0 µg/L.
• Cobalt was only detected in monitoring well MW-D at a concentration of 5.1 µg/L. No 2L compliance limit has been established for cobalt. This concentration is above
the Groundwater Protection Standard of 1.0 µg/L.
• Nickel was only detected in monitoring well MW-D at a concentration of 5.5 µg/L
which is less than its 2L compliance limit of 100 µg/L.
• Zinc was only detected in monitoring well MW-D at a concentration of 15.2 µg/L
which is less than its 2L compliance limit of 1000 µg/L.
5 SUMMARY AND ANALYSIS
A summary of the 2016 annual water quality monitoring event results as well as historical
monitoring results is a follows:
5.1 ORGANICS DETECTION SUMMARY
During the 2016 annual monitoring event, no Appendix I organic constituents were detected in
the monitoring wells. No detection of Appendix I organic constituents occurred during the 2014
and 2015 annual monitoring event as well.
The monitoring wells historical Appendix I organics analytical results are presented in Table 3.
5.2 INORGANICS DETECTION SUMMARY
During the 2016 annual monitoring event, Barium was detected below its respective compliance
limit of 700 µg/L in all four (4) monitoring wells. Barium has historically been detected in all the monitoring wells but below the 2L compliance limit.
Cobalt was detected during this monitoring event in monitoring well MW-D only. No 2L
standard for cobalt has been established. This concentration was above the Groundwater
Protection Standard of 1.0 µg/L. Cobalt has periodically been detected in MW-D, with the last detection occurring in April 2013.
Nickel and Zinc was detected during this monitoring event in monitoring well MW-D only at
levels below their respective compliance limit.
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2016 Annual Sampling Event
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Since 2012 Nickel has been infrequently detected in MW-D only and Zinc has only been
detected in monitoring well MW-D, always below the compliance limit.
The monitoring wells historical Appendix I inorganics analytical results are presented in Table
3.
TABLE 3
Historical Groundwater Monitoring Results
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Sample
Date
Detection
Limit
Compliance Limit
15A NCAC 02L or
Groundwater Protection
Standard
Analytical Results (µg/L)
MW-A MW-B MW-C MW-D
Parameter: Benzene
Apr-99 2 ND<2 ND<2 ND<2 ND<2
Oct-00 1 ND<1 ND<1 2.1 ND<1
Oct-01 2 ND<2 ND<2 2.7 ND<2
Apr-02 1 ND<1 ND<1 1.5 ND<1
Oct-03 1 ND<1 ND<1 1.3 ND<1
May-04 1 ND<1 ND<1 ND<1 ND<1
Oct-04 5 ND<5 ND<5 ND<5 ND<5
May-05 5 ND<5 ND<5 ND<5 ND<5
Oct-06 5 ND<5 ND<5 ND<5 ND<5
Oct-12 1 1 ND<1 ND<1 1.3 ND<1
Apr-13 1 1 ND<1 ND<1 ND<1 ND<1
Nov-14 1 1 ND<1 ND<1 ND<1 ND<1
May-15 1 1 ND<1 ND<1 ND<1 ND<1
Dec-16 1 1 ND<1 ND<1 ND<1 ND<1
Parameter: Chlorobenzene
Apr-99 2 ND<2 ND<2 ND<2 ND<2
Oct-00 1 ND<1 ND<1 14 ND<1
Oct-01 2 ND<2 ND<2 17 ND<2
Apr-02 1 ND<1 ND<1 11 ND<1
Oct-03 1 ND<1 ND<1 6 ND<1
May-04 1 ND<1 ND<1 ND<1 ND<1
Oct-04 5 ND<5 ND<5 ND<5 ND<5
May-05 5 ND<5 ND<5 ND<5 ND<5
ND = Not Detected (below detection limit)
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TABLE 3
Historical Groundwater Monitoring Results
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Sample
Date
Detection
Limit
Compliance Limit
15A NCAC 02L or
Groundwater Protection
Standard
Analytical Results (µg/L)
MW-A MW-B MW-C MW-D
Oct-06 5 ND<5 ND<5 9 ND<5
Oct-12 1 50 ND<1 ND<1 5.2 ND<1
Apr-13 1 50 ND<1 ND<1 1.4 ND<1
Nov-14 1 50 ND<1 ND<1 ND<1 ND<1
May-15 1 50 ND<1 ND<1 ND<1 ND<1
Dec-16 1 50 ND<1 ND<1 ND<1 ND<1
Parameter: Arsenic
Apr-99 5 ND<5 ND<5 ND<5 ND<5
Oct-00 5 ND<5 ND<5 6 ND<5
Oct-01 5 ND<5 27 ND<5 ND<5
Apr-02 5 ND<5 ND<5 8 ND<5
Oct-03 5 ND<5 ND<5 7 ND<5
May-04 5 8 5 5 ND<5
Oct-04 20 ND<20 ND<20 ND<20 ND<20
May-05 20 16 31 81 72
Oct-06 20 ND<20 ND<20 ND<20 ND<20
Oct-12 5 10 ND<5 ND<5 5.4 ND<5
Apr-13 10 10 ND<10 ND<10 ND<10 ND<10
Nov-14 10 10 ND<10 ND<10 ND<10 ND<10
May-15 10 10 ND<10 ND<10 ND<10 ND<10
Dec-16 10 10 ND<10 ND<10 ND<10 ND<10
Parameter: Barium
Apr-99 20 20 14 76 66
Oct-00 20 21 150 211 53
Oct-01 20 21 26 238 66
Apr-02 20 23 18 18 52
Oct-03 20 17 17 205 49
May-04 20 23 24 91 51
Oct-04 40 ND<40 45 150 70
ND = Not Detected (below detection limit)
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TABLE 3
Historical Groundwater Monitoring Results
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Sample
Date
Detection
Limit
Compliance Limit
15A NCAC 02L or
Groundwater Protection
Standard
Analytical Results (µg/L)
MW-A MW-B MW-C MW-D
May-05 40 28 31 81 72
Oct-06 40 ND<40 52 260 65
Oct-12 5 700 18.1 19.6 176 69.4
Apr-13 5 700 21.4 15.5 83.8 74.1
Nov-14 5 700 62.8 18.4 18.6 40.3
May-15 5 700 18.2 14.6 46.0 48.5
Dec-15 5 700 19.5 10.6 39.1 54.0
Parameter: Chromium
Apr-99 5 ND<5 ND<5 ND<5 ND<5
Oct-00 5 ND<5 ND<5 ND<5 ND<5
Oct-01 5 ND<5 ND<5 ND<5 10
Apr-02 5 ND<5 ND<5 ND<5 ND<5
Oct-03 5 ND<5 ND<5 ND<5 6
May-04 5 ND<5 ND<5 ND<5 ND<5
Oct-04 20 ND<20 ND<20 ND<20 ND<20
May-05 20 ND<20 ND<20 ND<20 ND<20
Oct-06 20 ND<20 ND<20 ND<20 ND<20
Oct-12 5 10 ND<5 ND<5 ND<5 176
Apr-13 5 10 ND<5 ND<5 ND<5 350
Nov-14 5 10 ND<5 ND<5 ND<5 ND<5
May-15 5 10 ND<5 ND<5 ND<5 ND<5
Dec-16 5 10 ND<5 ND<5 ND<5 ND<5
Parameter: Lead
Apr-99 3 ND<3 ND<3 ND<3 8
Oct-00 3 ND<3 ND<3 3 34
Oct-01 3 ND<3 5 ND<3 24
Apr-02 2 ND<2 ND<2 4 4
Oct-03 2 ND<2 ND<2 ND<2 3
May-04 2 6 4 ND<2 ND<2
ND = Not Detected (below detection limit)
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TABLE 3
Historical Groundwater Monitoring Results
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Sample
Date
Detection
Limit
Compliance Limit
15A NCAC 02L or
Groundwater Protection
Standard
Analytical Results (µg/L)
MW-A MW-B MW-C MW-D
Oct-04 15 ND<15 ND<15 ND<15 ND<15
May-05 10 ND<10 ND<10 ND<10 ND<10
Oct-06 40 ND<40 ND<40 ND<40 ND<40
Oct-12 5 15 ND<5 ND<5 ND<5 24.8
Apr-13 5 15 ND<5 ND<5 ND<5 28.2
Nov-14 5 15 ND<5 ND<5 ND<5 ND<5
May-15 5 15 ND<5 ND<5 ND<5 ND<5
Dec-16 5 15 ND<5 ND<5 ND<5 ND<5
Parameter: Beryllium
Oct-12 1 4 ND<1 ND<1 ND<1 ND<1
Apr-13 1 4 ND<1 ND<1 ND<1 1.4
Nov-14 1 4 ND<1 ND<1 ND<1 ND<1
May-15 1 4 ND<1 ND<1 ND<1 ND<1
Dec-16 1 4 ND<1 ND<1 ND<1 ND<1
Parameter: Cobalt
Oct-12 5 1 ND<5 ND<5 ND<5 6
Apr-13 5 1 ND<5 19.3 48.4 13.3
Nov-14 5 1 ND<5 ND<5 ND<5 ND<5
May-15 5 1 ND<5 ND<5 ND<5 ND<5
Dec-16 5 1 ND<5 ND<5 ND<5 5.1
Parameter: Copper
Oct-12 5 1000 ND<5 ND<5 ND<5 26.6
Apr-13 5 1000 ND<5 ND<5 ND<5 25
Nov-14 5 1000 ND<5 ND<5 ND<5 ND<5
May-15 5 1000 ND<5 ND<5 ND<5 ND<5
Dec-16 5 1000 ND<5 ND<5 ND<5 ND<5
Parameter: Nickel
Oct-12 5 100 ND<5 ND<5 ND<5 86.6
ND = Not Detected (below detection limit)
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TABLE 3
Historical Groundwater Monitoring Results
Closed Anson County Landfill (Lilesville Landfill) - Facility Permit No. 0401-MSWLF-1973

Sample
Date
Detection
Limit
Compliance Limit
15A NCAC 02L or
Groundwater Protection
Standard
Analytical Results (µg/L)
MW-A MW-B MW-C MW-D
Apr-13 5 100 ND<5 ND<5 ND<5 160
Nov-14 5 100 ND<5 ND<5 ND<5 ND<5
May-15 5 100 ND<5 ND<5 ND<5 5.2
Dec-16 5 100 ND<5 ND<5 ND<5 5.5
Parameter: Vanadium
Oct-12 5 0.3 ND<5 ND<5 ND<5 18
Apr-13 5 0.3 ND<5 ND<5 ND<5 22.3
Nov-14 5 0.3 ND<5 ND<5 ND<5 ND<5
May-15 5 0.3 ND<5 ND<5 ND<5 ND<5
Dec-16 5 0.3 ND<5 ND<5 ND<5 ND<5
Parameter: Zinc
Oct-12 10 1000 ND<10 ND<10 ND<10 31
Apr-13 10 1000 ND<10 ND<10 ND<10 27.5
Nov-14 10 1000 ND<10 ND<10 ND<10 13.5
May-15 10 1000 ND<10 ND<10 ND<10 16.3
Dec-16 10 1000 ND<10 ND<10 ND<10 15.2
ND = Not Detected (below detection limit)

5.3 ANALYSIS
During the 2016 annual monitoring event, no 40 CFR Part 258 Appendix I organic constituents
were detected above their respective compliance limits in the monitoring wells. The only
inorganic constituents detected above their respective compliance limit was cobalt. As stated in previous monitoring reports, certain Appendix I inorganics or metals are considered natural occurring within the in-situ soils and are not caused by a release from a landfill. An example of
this is a closed MSW landfill located in Union County, North Carolina where groundwater
alternate source demonstrations(1) for metals were completed and the metals Barium, Beryllium, Chromium, Cobalt, Copper, Lead, Nickel, Vanadium and Zinc were determined to be natural occurring at considerable levels in the in-situ soils. The landfill located in Union County is
within the vicinity of and has similar geologic conditions to the closed Anson County - Lilesville

(1) Reference: Alternate Source Demonstration Report, Union County Landfill, Wingate North Carolina dated July
2008 and Revised Alternate Source Demonstration for the Union County Landfill dated November 2012.
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Landfill. As such, the existence of these metals in the in-situ soils at the Anson County -
Lilesville Landfill is probable. Further investigation of the in-situ soils does not seem warranted
at this time.
No Appendix I organics or volatile organic compounds (VOCs) were detected during the monitoring event. A VOC was last detected in April 2013 during the 2013 annual monitoring
event. The detected VOC was Chlorobenzene in monitoring well MW-C and was at a
concentration below the compliance limit.
The December 2016 groundwater monitoring event is the fifth annual event originally requested by NCDENR (currently NCDEQ) in the May 16, 2011, letter to the County. Based on review of the last five years of groundwater monitoring data, SCS Engineers, PC, recommends that no
further groundwater monitoring is needed for the landfill. Only inorganic constituents have been
detected in groundwater, in most cases below their respective compliance levels. We believe
these detected inorganic constituents are naturally-occurring in the site soils.
Water Quality Monitoring Report
2016 Annual Sampling Event

FIGURE NO. 1
Groundwater Surface Contour Map

OLD LANDFILL AREA
(APPROX. 49.7 ACRES)
CLOSED PRIOR TO 1978
PERMITTED LANDFILL AREA
FACILITY PERMIT NO. 0401-MSWLF-1973
(APPROX. 11.6 ACRES)
OFFICIALLY CLOSED JANUARY 18, 1996
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Water Quality Monitoring Report
2016 Annual Sampling Event

ATTACHMENT 1
Monitoring Well Sampling Logs

ANSON COUNTY LANDFILL - CLOSED LILESVILLE LANDFILL
ANSON COUNTY, NORTH CAROLINA
MONITORING WELL SAMPLE LOG
WELL ID:MW-A WEATHER:Cloudy, Mid 30s
DATE:12/19/2016
PERSONNEL:Michael Cobb; SCS Engineers, PC
Mike Richards; SCS Field Services
Compliance.
Total Well Depth:27.82 ft.
Depth to Water:11.96 ft.
Water Column:15.86 ft.
Well Volume:2.57 gal.
Field Readings 1 2 3 4
Time 1147 1149 1151 1153
Turbidity 4.54 5.04 2.95 2.61
pH 5.03 4.88 4.9 4.85
DO Mg/L 0.62 0.6 0.61 0.55
Temperature 17.5 17.6 17.8 17.9
Sp. Conductivity 36.8 37.6 37.4 36.9 36 gal
5 6 7 8 9 10 11 12
Time 1155 1157 1159 1205 1207 1209 1211 1215
Turbidity 2.26 1.78 2.53 3.84 2.29 1.33 1.14 1.85
pH 4.87 4.8 4.83 4.88 4.9 4.87 4.85 4.84
DO Mg/L 0.51 0.49 0.5 0.52 0.48 0.47 0.51 0.52
Temperature 18 18.1 17.9 18 17.8 17.9 17.9 17.8
Sp. Conductivity 36.8 37 37.1 36.9 37.2 36.7 36.4 36.5
Notes: Purged 15 gallons before taking readings
Sample ID: MW-A
Sample Time:1220
Laboratory:Pace Analytical
Shipping Date:12/20/2016
Total purged from well:
REASON FOR SAMPLING:
ANSON COUNTY LANDFILL - CLOSED LILESVILLE LANDFILL
ANSON COUNTY, NORTH CAROLINA
MONITORING WELL SAMPLE LOG
WELL ID:MW-B WEATHER:Cloudy, Mid 30s
DATE:12/19/2016
PERSONNEL:Michael Cobb; SCS Engineers, PC
Mike Richards; SCS Field Services
Compliance.
Total Well Depth:28.08 ft.
Depth to Water:14.32 ft.
Water Column:13.76 ft.
Well Volume:2.23 gal.
Field Readings 1 2 3 4
Time 1022 1024 1026 1028
Turbidity 1.85 1.33 0.95 1.08
pH 6.15 6.14 6.11 6.12
DO Mg/L 0.66 0.59 0.55 0.58
Temperature 15.9 16 15.8 15.9
Sp. Conductivity 100.1 88.2 73.6 70.2 37 gal
5 6 7 8 9 10 11 12
Time 1033 1035 1037 1040 1042 1044 1046 1048
Turbidity 1.35 0.26 0.61 0.54 0.86 0.71 0.35 0.98
pH 6.1 6.08 6.12 6.13 9.09 6.11 6.08 6.06
DO Mg/L 0.54 0.53 0.55 0.52 0.5 0.51 0.54 0.53
Temperature 15.9 15.9 15.9 15.8 15.8 15.9 15.8 15.9
Sp. Conductivity 65.4 65.9 65.1 63.9 64.1 63.8 63.4 63.7
13 14
Time 1050 1052
Turbidity 0.47 0.97
pH 6.11 6.14
DO Mg/L 0.51 0.5
Temperature 15.8 15.8
Sp. Conductivity 63.4 63.5
Notes: Purged 15 gallons before taking readings
Sample ID: MW-B
Sample Time:1055
Laboratory:Pace Analytical
Shipping Date:12/20/2016
Total purged from well:
REASON FOR SAMPLING:
ANSON COUNTY LANDFILL - CLOSED LILESVILLE LANDFILL
ANSON COUNTY, NORTH CAROLINA
MONITORING WELL SAMPLE LOG
WELL ID:MW-C WEATHER:Cloudy, Mid 30s
DATE:12/19/2016
PERSONNEL:Michael Cobb; SCS Engineers, PC
Mike Richards, SCS Field Services
Compliance.
Total Well Depth:22.55 ft.
Depth to Water:3.53 ft.
Water Column:19.02 ft.
Well Volume:3.08 gal.
Field Readings 1 2 3 4
Time 1410 1412 1414 1417
Turbidity 2.3 2.35 1.9 2.03
pH 6.56 6.5 6.49 6.48
DO Mg/L 0.59 0.61 0.65 0.5
Temperature 17.3 17.1 16.8 16.8
Sp. Conductivity 425.9 299.1 264.3 255.7 28 gal
5
Time 1420
Turbidity 2.07
pH 6.48
DO Mg/L 0.61
Temperature 16.8
Sp. Conductivity 248.6
Notes: Purged 15 gallons before taking readings
Sample ID: MW-C
Sample Time:1430
Laboratory:Pace Analytical
Shipping Date:12/20/2016
Total purged from well:
REASON FOR SAMPLING:
ANSON COUNTY LANDFILL - CLOSED LILESVILLE LANDFILL
ANSON COUNTY, NORTH CAROLINA
MONITORING WELL SAMPLE LOG
WELL ID:MW-D WEATHER:Cloudy, Mid 30s
DATE:12/19/2016
PERSONNEL:Michael Cobb; SCS Engineers, PC
Mike Richards, SCS Field Services
Compliance.
Total Well Depth:35.53 ft.
Depth to Water:5.19 ft.
Water Column:30.34 ft.
Well Volume:5.15 gal.
Field Readings 1 2 3 4
Time
Turbidity
pH
Sp. Conductivity
DO Mg/L
Temp.3.5 gal
Notes:
Well dry before initial purge completed.
Waited for well to recharge and then sampled.
Sample ID: MW-D
Sample Time:1550
Laboratory:Pace Analytical
Shipping Date:12/20/2016
Total purged from well:
REASON FOR SAMPLING:
Water Quality Monitoring Report
2016 Annual Sampling Event

ATTACHMENT 2
Constituents for Detection Monitoring 40 CFR 258, Appendix I

Constituents for Detection Monitoring
(40 CFR 258, Appendix I)
Common name CAS RN
Antimony (Total)
Arsenic (Total)
Barium (Total)
Beryllium (Total)
Cadmium (Total)
Chromium (Total)
Cobalt (Total)
Copper (Total)
Lead (Total)
Nickel (Total)
Selenium (Total)
Silver (Total)
Thallium (Total)
Vanadium (Total)
Zinc (Total)
Acetone 67-64-1
Acrylonitrile 107-13-1
Benzene 71-43-2
Bromochloromethane 74-97-5
Bromodichloromethane 75-27-4
Bromoform; Tribromomethane 75-25-2
Carbon disulfide 75-15-0
Carbon tetrachloride 56-23-5
Chlorobenzene 108-90-7
Chloroethane; Ethyl chloride 75-00-3
Chloroform; Trichloromethane 67-66-3
Dibromochloromethane; Chlorodibromomethane 124-48-1
1,2-Dibromo-3-chlorpropane; DBCP 96-12-8
1,2-Dibromoethane; Ethylene dibromide; EDB 106-93-4
o-Dichlorobenzene; 1,2-Dichlorobenzene 95-50-1
p-Dichlorobenzene; 1,4-Dichlorobenzene 106-46-7
trans-1,4-Dichloro-2-butene 110-57-6
1,1-Dichloroethane; Ethylidene chloride 75-34-3
1,2-Dichloroethane; Ethlyene dichloride 107-06-2
1,1-Dichloroethylene; 1-1-Dichloroethene; Vinylidene
chloride
75-35-4
cis-1,2-Dichloroethylene; cis-1,2-Dichloroethene 156-59-2
trans-1,2-Dichloroethylene; trans-1,2-Dichloroethene 156-60-5
1,2-Dichlorpropane; Propylene dichloride 78-87-5
cis-1,3-Dichlorpropene 10061-01-5
trans-1,3-Dichlorpropene 10061-02-6
Ethylbenzene 100-41-4
2-hexanone; Methyl butyl ketone 591-78-6
Methyl bromide; Bromomethane 74-83-9
Methyl chloride; Chloromethane 74-87-3
Methylene bromide Dibromomethane 74-95-3
Methylene chloride; Dichloromethane 75-09-2
Methyl ethyl ketone; MEK; 2-Butanone 78-93-3
Methyl iodide; Iodomethane 74-88-4
4-Methyl-2-pentanone; Methyl isobutyl isobutyl
ketone
108-10-1
Styrene 100-42-5
1,1,1,2-Tetrachloroethane 630-20-6
1,1,2,2-Tetrachloroethane 79-34-5
Tetrachloroethylene; Tetracholorethene;
Perchloroethylene
127-18-4
Toluene 108-88-3
1,1,1-Trochlorethane; Methylchloroform 71-55-6
1,1,2-Trichloroethane 79-00-5
Trichloroethylene; Trichlorethene 79-01-6
Trichlorofluoromethane; CFC-11 75-69-4
1,2,3-Trichloropropane 96-18-4
Vinyl acetate 108-05-4
Vinyl chloride 75-01-4
Xylenes 1330-20-7
NC Department of Environment and Natural Resources
Waste Management - Constituent List
Sections and Programs » Solid Waste Section » Environmental Monitoring » List
Solid Waste Environmental Monitoring Reporting Limits and Standards
All units are in (ug/L) unless noted.
NE = Not Established
CAS numbers that begin with "SW" are not real CAS numbers, instead this represents the Solid Waste Section's ID
number.
CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
630-20-6 1,1,1,2-Tetrachloroethane Ethane, 1,1,1,2-tetrachloro- NE 1 5 190 I
71-55-6 1,1,1-Trichloroethane; Ethane, 1,1,1-trichloro- 200 -- 1 200 I
79-34-5 1,1,2,2-Tetrachloroethane Ethane, 1,1,2,2-tetrachloro- 0.2 0.18 3 191 I
79-00-5 1,1,2-Trichloroethane Ethane, 1,1,2-trichloro- NE 0.6 1 202 I
76-13-1 1,1,2-Trichlorotrifluoroethane CFC-113 200000 NE NE 398
92-52-4 1,1-biphenyl 1,1-biphenyl 400 -- 10 421
75-34-3 1,1-Dichloroethane; Ethyldidene Ethane, 1,1-dichloro- 6 -- 5 75 I
75-35-4 1,1-Dichloroethylene; 1,1- Ethene, 1,1-dichloro- 7 -- 5 77 I
563-58-6 1,1-Dichloropropene 1-Propene, 1,1-dichloro- NE NE 5 85
96-18-4 1,2,3-Trichloropropane Propane, 1,2,3-trichloro- 0.005 -- 1 206 I
95-94-3 1,2,4,5-Tetrachlorobenzene Benzene, 1,2,4,5-tetrachloro- NE 2 10 189
120-82-1 1,2,4-Trichlorobenzene Benzene, 1,2,4-trichloro- 70 70 10 199
95-63-6 1,2,4-Trimethylbenzene Pseudocumene 400 NE NE 372
226-36-8 1,2,5,6-Dibenzacridine NE NE NE 385
96-12-8 1,2-Dibromo-3-chloropropane; DBCP Propane, 1,2-dibromo-3-chloro- 0.04 -- 13 67 I
106-93-4 1,2-Dibromoethane; Ethylene dibromide; Ethane, 1,2-dibromo- 0.02 -- 1 68 I
107-06-2 1,2-Dichloroethane; Ethylene Ethane, 1,2-dichloro- 0.4 -- 1 76 I
540-59-0 1,2-Dichloroethylene mixed isomers Mixed Isomers NE 60 NE 481
78-87-5 1,2-Dichloropropane Propane, 1,2-dichloro- 0.6 -- 1 82 I
122-66-7 1,2-Diphenylhydrazine NE NE NE 394
108-67-8 1,3,5-Trimethylbenzene) Mesitylene 400 NE NE 373
142-28-9 1,3-Dichloropropane; Trimethylene Propane, 1,3-dichloro- NE NE 1 83
106-37-6 1,4-Dibromobenzene p-Dibromobenzene, p-Bromobenzene 70 471
123-91-1 1,4-dioxane 1,4-dioxane 3 -- 10 422
130-15-4 1,4-Naphthoquinone 1,4-Naphthalenedione NE NE 10 149
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
87-61-6 1-2-3-Trichlorobenzene NE NE NE 371
90-12-0 1-Methylnaphthalene α-methylnaphthalene NE 1 NE 503
134-32-7 1-Naphthylamine 1-Naphthalenamine NE NE 10 150
120-36-5 2-(2-4-dichlorophenoxy)propionic NE NE NE 352
594-20-7 2,2-Dichloropropane; Isopropylidene Propane, 2,2-dichloro- NE NE 15 84
58-90-2 2,3,4,6-Tetrachlorophenol Phenol, 2,3,4,6-tetrachloro- 200 -- 10 193
93-76-5 2,4,5-T; 2,4,5-Trichlorophenoxyacetic Acetic acid, (2,4,5-trichlorophenoxy)- NE NE 2 188
93-72-1 2,4,5-TP Acid Silvex 50 NE NE 452
95-95-4 2,4,5-Trichlorophenol Phenol, 2,4,5-trichloro- NE 63 10 204
88-06-2 2,4,6-Trichlorophenol Phenol, 2,4,6-trichloro- NE 4 10 205
94-75-7 2,4-D; 2,4-Dichlorophenoxyacetic Acetic acid, (2,4-dichlorophenoxy)- 70 -- 2 59
120-83-2 2,4-Dichlorophenol Phenol, 2,4-dichloro- NE 0.98 10 80
105-67-9 2,4-Dimethylphenol; m-Xylenol Phenol, 2,4-dimethyl- 100 -- 10 95
51-28-5 2,4-Dinitrophenol Phenol, 2,4-dinitro- NE NE 50 99
121-14-2 2,4-Dinitrotoluene Benzene, 1-methyl-2,4-dinitro- NE 0.1 10 100
87-65-0 2,6-Dichlorophenol Phenol, 2,6-dichloro- NE NE 10 81
606-20-2 2,6-Dinitrotoluene Benzene, 2-methyl-1,3-dinitro- NE NE 10 101
94-82-6 2-4 DB NE NE NE 350
53-96-3 2-Acetylaminofluorene; 2-AAF Acetamide, N-9H-fluoren-2-yl- NE NE 20 6
110-75-8 2-Chloroethylvinyl ether NE NE NE 358
91-58-7 2-Chloronaphthalene Naphthalene, 2-chloro- NE NE 10 47
95-57-8 2-Chlorophenol Phenol, 2-chloro- 0.4 -- 10 48
591-78-6 2-Hexanone; Methyl butyl ketone 2-Hexanone NE 40 50 124 I
91-57-6 2-Methylnaphthalene Naphthalene, 2-methyl- 30 -- 10 145
91-59-8 2-Naphthylamine 2-Naphthalenamine NE NE 10 151
109-06-8 2-Picoline NE NE NE 390
91-94-1 3,3'-Dichlorobenzidine [1,1'-Biphenyl]-4,4'-diamine,3,3'- NE NE 20 72
119-93-7 3,3'-Dimethylbenzidine [1,1'-Biphenyl]-4,4'-diamine,3,3'- NE NE 10 94
56-49-5 3-Methylcholanthrene Benz[j]aceanthrylene,1,2-dihydro-3- NE NE 10 138
72-54-8 4,4'-DDD Benzene 1,1'-(2,2- 0.1 -- 0.1 60
72-55-9 4,4'-DDE Benzene, 1,1'- NE NE 0.1 61
50-29-3 4,4'-DDT Benzene, 1,1'-(2,2,2- 0.1 -- 0.1 62
534-52-1 4,6-Dinitro-o-cresol; 4,6-Dinitro-2- Phenol, 2-methyl-4,6-dinitro- NE NE 50 98
92-67-1 4-Aminobiphenyl [1,1'-Biphenyl]-4-amine NE NE 20 11
460-00-4 4-Bromofluorobenzene NE NE NE 463
101-55-3 4-Bromophenyl phenyl ether Benzene, 1-bromo-4-phenoxy- NE NE 10 31
* GWP = Groundwater Protection
** SWSL = Solid Waste
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
7005-72-3 4-Chlorophenyl phenyl ether Benzene, 1-chloro-4-phenoxy- NE NE 10 49
108-10-1 4-Methyl-2-pentanone; Methyl isobutyl 2-Pentanone, 4-methyl- NE 560 100 147 I
56-57-5 4-nitroquinoline-1-oxide NE NE NE 388
99-55-8 5-Nitro-o-toluidine Benzenamine, 2-methyl-5-nitro- NE NE 10 157
57-97-6 7,12-Dimethylbenz[a]anthracene Benz[a]anthracene, 7,12-dimethyl- NE NE 10 93
83-32-9 Acenaphthene Acenaphthylene, 1,2-dihydro- 80 -- 10 1
208-96-8 Acenaphthylene Acenaphthylene 200 -- 10 2
SW416 Acetic Acid Acetic Acid NE NE NE 416
34256-82-1 Acetochlor 100 490
187022-11-3 Acetochlor ESA 1000 491
184992-44-4 Acetochlor OXA 1000 492
67-64-1 Acetone 2-Propanone 6000 -- 100 3 I
75-05-8 Acetonitrile; Methyl cyanide Acetonitrile NE 42 55 4
98-86-2 Acetophenone Ethanone, 1-phenyl- NE 700 10 5
50594-66-6 Acifluorofen Acifluorofen 453
107-02-8 Acrolein 2-Propenal NE 4 53 7
79-06-1 Acrylamide Acrylamide 0.008 -- NE 429
107-13-1 Acrylonitrile 2-Propenenitrile NE NE 200 8 I
15972-60-8 Alachlor 0.4 469
309-00-2 Aldrin 1,4:5,8- NE 0.002 0.05 9
SW337 Alkalinity NE NE NE 337
107-05-1 Allyl chloride 1-Propene, 3-chloro- NE NE 10 10
319-84-6 alpha-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- NE 0.006 0.05 24
319-84-6 alpha-Hexachlorocyclohexane α-Benzenehexachloride NE 0.006 NE 501
-- Aluminum Aluminum NE 3500 NE 454
7429-90-5 Aluminum NE 3500 NE 438
7664-41-7 Ammonia Ammonia NE 1500 NE 435
62-53-3 Aniline NE NE NE 381
120-12-7 Anthracene Anthracene 2000 -- 10 12
7440-36-0 Antimony Antimony NE 1 6 13 I
140-57-8 Aramite NE NE NE 382
12674-11-2 Aroclor 1016 congener of PCB; see (1336-36-3) NE NE NE 401
11104-28-2 Aroclor 1221 congener of PCB; see (1336-36-3) NE NE NE 402
11141-16-5 Aroclor 1232 congener of PCB; see (1336-36-3) NE NE NE 403
53469-21-9 Aroclor 1242 congener of PCB; see (1336-36-3) NE NE NE 404
12672-29-6 Aroclor 1248 congener of PCB; see (1336-36-3) NE NE NE 405
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
11097-69-1 Aroclor 1254 congener of PCB; see (1336-36-3) NE NE NE 406
11096-82-5 Aroclor 1260 congener of PCB; see (1336-36-3) NE NE NE 407
7440-38-2 Arsenic Arsenic 10 -- 10 14 I
7440-39-3 Barium Barium 700 -- 100 15 I
25057-89-0 Bentazon NE NE NE 462
100-52-7 Benzaldehyde Phenylmethanal, NE 700 NE 496
71-43-2 Benzene Benzene 1 -- 1 16 I
122-09-8 Benzeneethanamine, alpha,alpha- NE NE NE 386
92-87-5 Benzidine NE NE NE 383
56-55-3 Benzo[a]anthracene; Benz[a]anthracene 0.05 -- 10 17
50-32-8 Benzo[a]pyrene Benzo[a]pyrene 0.005 -- 10 21
205-99-2 Benzo[b]fluoranthene Benz[e]acephenanthrylene 0.05 -- 10 18
191-24-2 Benzo[ghi]perylene Benzo[ghi]perylene 200 -- 10 20
207-08-9 Benzo[k]fluoranthene Benzo[k]fluoranthene 0.5 -- 10 19
65-85-0 Benzoic Acid 30000 28000 NE 395
100-51-6 Benzyl alcohol Benzenemethanol NE 700 20 22
7440-41-7 Beryllium Beryllium NE 4 1 23 I
319-85-7 beta-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- NE 0.019 0.05 25
319-85-7 beta-Hexachlorocyclohexane β-Benzenehexachloride NE 0.02 NE 502
SW347 Bicarbonate (as CaCO3) NE NE NE 347
SW316 Biological Oxygen Demand BOD NE NE NE 316
101-84-8 biphenyl ether biphenyl ether NE NE 10 423
108-60-1 Bis(2-chloro-1-methylethyl) ether; 2,2'- Propane, 2,2'-oxybis[1-chloro- NE NE 10 46
111-91-1 Bis(2-chloroethoxy)methane Ethane, 1,1'-[methylenebis(oxy)]bis [2- NE NE 10 42
111-44-4 Bis(2-chloroethyl)ether; Dichloroethyl Ethane, 1,1'-oxybis[2-chloro- NE 0.031 10 43
39638-32-9 Bis(2-chloroisopropyl) ether 0.03 NE NE 384
117-81-7 Bis(2-ethylhexyl) phthalate 1,2-Benzenedicarboxylic acid, bis(2- 3 NE 15 111
7440-42-8 Boron Boron 700 -- NE 428
108-86-1 Bromobenzene NE NE NE 360
74-97-5 Bromochloromethane; Methane, bromochloro- NE 0.6 3 28 I
75-27-4 Bromodichloromethane; Methane, bromodichloro- 0.6 -- 1 29 I
75-25-2 Bromoform; Tribromomethane Methane, tribromo- 4 -- 3 30 I
71-36-3 Butanol n n-Butyl Alcohol NE 700 470
78-92-2 Butanol sec sec-Butyl Alcohol NE 10000 483
85-68-7 Butyl benzyl phthalate; Benzyl butyl 1,2-Benzenedicarboxylicacid, butyl 1000 -- 10 32
SW418 Butyric Acid Butyric Acid NE NE NE 418
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
7440-43-9 Cadmium Cadmium 2 -- 1 34 I
7440-70-2 Calcium NE NE NE 375
471-34-1 Calcium carbonate NE NE NE 464
105-60-2 Caprolactam 4000 NE NE 440
86-74-8 Carbazole dibenzopyrrole, diphenylenimine, NE 2 NE 497
1563-66-2 Carbofuran Carbofuran 40 NE NE 430
124-38-9 Carbon Dioxide NE NE NE 459
SW413 Carbon Dioxide (CO2) CO2 Gas NE NE NE 413
75-15-0 Carbon disulfide Carbon disulfide 700 -- 100 35 I
56-23-5 Carbon tetrachloride Methane, tetrachloro- 0.3 -- 1 36 I
SW348 Carbonate (as CaCO3) NE NE NE 348
7440-44-0 Charcoal NE NE NE 466
SW317 Chemical Oxygen Demand COD NE NE NE 317
57-74-9 Chlordane 4,7-Methano-1H-indene,1,2,4,5,6,7,8,8- 0.1 -- 0.5 339
12789-03-6 Chlordane (constituents) NE NE NE 400
5103-71-9 Chlordane, alpha cis-Chlordane NE NE NE 379
5103-74-2 Chlordane, beta trans-Chlordane NE NE NE 378
5566-34-7 Chlordane, gamma NE NE NE 399
16887-00-6 Chloride Chloride 455
SW301 Chloride 250000 -- NE 301
108-90-7 Chlorobenzene Benzene, chloro- 50 -- 3 39 I
510-15-6 Chlorobenzilate Benzeneacetic acid, 4-chloro-(4- NE NE 10 40
75-00-3 Chloroethane; Ethyl chloride Ethane, chloro- 3000 -- 10 41 I
67-66-3 Chloroform; Trichloromethane Methane, trichloro- 70 -- 5 44 I
126-99-8 Chloroprene 1,3-Butadiene, 2-chloro- NE NE 20 50
7440-47-3 Chromium Chromium 10 -- 10 51 I
218-01-9 Chrysene Chrysene 5 -- 10 52
156-59-2 cis-1,2-Dichloroethylene; cis-1,2- Ethene, 1,2-dichloro-,(Z)- 70 -- 5 78 I
10061-01-5 cis-1,3-Dichloropropene 1-Propene, 1,3-dichloro-, (Z)- 0.4 -- 1 86 I
7440-48-4 Cobalt Cobalt NE 1 10 53 I
SW309 Coliform (total)1 NE NE 309
SW310 Color (color units) 15 NE NE 310
7440-50-8 Copper Copper 1000 -- 10 54 I
57-12-5 Cyanide Cyanide 70 -- 10 58
75-99-0 Dalapon NE 200 NE 355
3424-82-6 DDE o,p-DDE 0.1 472
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
319-86-8 delta-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- NE 0.019 0.05 26
SW318 Depth To Water (ft) DTW NE NE NE 318
117-81-7 Di(2-ethylhexyl)phthalate Di(2-ethylhexyl)phthalate, DEHP 2.5 -- NE 431
2303-16-4 Diallate Carbamothioic acid,bis(1-methylethyl)-, NE NE 10 63
53-70-3 Dibenz[a,h]anthracene Dibenz[a,h]anthracene 0.005 -- 10 64
132-64-9 Dibenzofuran Dibenzofuran NE 28 10 65
124-48-1 Dibromochloromethane; Methane, dibromochloro- 0.4 0.41 3 66 I
1918-00-9 Dicamba NE NE NE 353
79-43-6 Dichloroacetic Acid NE 0.7 NE 480
75-71-8 Dichlorodifluoromethane; CFC 12 Methane,dichlorodifluoro- 1000 -- 5 74
60-57-1 Dieldrin 2,7:3,6-Dimethanonaphth[2,3- 0.002 -- 0.075 88
84-66-2 Diethyl phthalate 1,2-Benzenedicarboxylicacid, diethyl 6000 -- 10 90
60-51-5 Dimethoate Phosphorodithioic acid,O,O-dimethyl S- NE NE 20 91
131-11-3 Dimethyl phthalate 1,2-Benzenedicarboxylicacid, dimethyl NE NE 10 96
84-74-2 Di-n-butyl phthalate 1,2-Benzenedicarboxylic acid, dibutyl 700 -- 10 33
117-84-0 Di-n-octyl phthalate 1,2-Benzenedicarboxylicacid, dioctyl 100 -- 10 168
88-85-7 Dinoseb; DNBP; 2-sec-Butyl-4,6- Phenol, 2-(1-methylpropyl)-4,6-dinitro- NE 7 1 102
1746-01-6 Dioxin 2,3,7,8-TCDD 0.2 NE NE 441
101-84-8 Diphenyl ether Diphenyl oxide; 1,1'-Oxybisbenzene; NE 100 NE 498
122-39-4 Diphenylamine Benzenamine, N-phenyl- NE NE 10 103
85-00-7 Diquat 20 473
74-82-8 Dissolved Methane Dissolved Methane 456
7782-44-7 Dissolved Oxygen NE NE NE 356
298-04-4 Disulfoton Phosphorodithioic acid,O,O-diethyl S-[2- 0.3 -- 10 104
3648-20-2 Diundecyl phthalate Santicizer 711 100 NE NE 442
959-98-8 Endosulfan I 6,9-Methano-2,4,3-benzodiox- 40 NE 0.1 105
33213-65-9 Endosulfan II 6,9-Methano-2,4,3- -- 42 0.1 106
1031-07-8 Endosulfan sulfate 6,9-Methano-2,4,3- NE 40 0.1 107
145-73-3 Endothall 100 474
72-20-8 Endrin 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 2 -- 0.1 108
7421-93-4 Endrin aldehyde 1,2,4-Methenocyclo-penta[cd]pentalene- 2 -- 0.1 109
106-89-8 Epichlorohydrin 4 NE NE 443
74-84-0 Ethane- Dissolved NE NE NE 331
64-17-5 Ethanol Ethyl alcohol, Ethyl hydrate, NE 4000 NE 499
74-85-1 Ethene- Dissolved NE NE NE 332
141-78-6 Ethyl acetate 3000 NE NE 444
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
Page 6 of 12NCDENR - Constituent List
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
97-63-2 Ethyl methacrylate 2-Propenoic acid, 2-methyl-, ethyl NE NE 10 112
62-50-0 Ethyl methanesulfonate Methanesulfonic acid,ethyl ester NE NE 20 113
637-92-3 Ethyl tert-butyl ether ETBE, Ethyl tertiary butyl ether NE 47 NE 500
100-41-4 Ethylbenzene Benzene, ethyl- 600 -- 1 110 I
107-21-1 ethylene glycol ethylene glycol 10000 -- 10,000 424
52-85-7 Famphur Phosphorothioic acid, O-[4- NE NE 20 114
SW334 Ferrous Iron- Dissolved NE NE NE 334
206-44-0 Fluoranthene Fluoranthene 300 -- 10 115
86-73-7 Fluorene 9H-Fluorene 300 -- 10 116
16984-48-8 Fluoride 2000 -- 2000 312
SW313 Foaming Agents 500 -- NE 313
50-00-0 Formaldehyde 600 NE NE 445
59-89-9 gamma-BHC (Lindane) gamma-BHC (Lindane) 457
58-89-9 gamma-BHC; Lindane Cyclohexane,1,2,3,4,5,6-hexachloro- 0.03 -- 0.05 27
SW314 Gross Alpha 15 NE NE 314
SW427 Groundwater Elevation (feet) GW Elevation (feet) NE NE NE 427
SW319 Head (ft mean sea level) NE NE NE 319
76-44-8 Heptachlor 4,7-Methano-1H-indene,1,4,5,6,7,8,8- 0.008 -- 0.05 117
1024-57-3 Heptachlor epoxide 2,5-Methano-2H-indeno[1,2- 0.004 -- 0.075 118
142-82-5 Heptane Heptane 400 -- NE 432
118-74-1 Hexachlorobenzene Benzene, hexachloro- 0.02 -- 10 119
87-68-3 Hexachlorobutadiene 1,3-Butadiene,1,1,2,3,4,4-hexachloro- 0.4 0.44 10 120
608-73-1 Hexachlorocyclohexane isomers 0.02 NE NE 446
77-47-4 Hexachlorocyclopentadiene 1,3-Cyclopentadiene,1,2,3,4,5,5- NE 50 10 121
67-72-1 Hexachloroethane Ethane, hexachloro- NE 2.5 10 122
70-30-4 Hexachlorophene NE NE NE 387
1888-71-7 Hexachloropropene 1-Propene, 1,1,2,3,3,3-hexachloro- NE NE 10 123
142-62-1 Hexanoic Acid NE NE NE 485
133-74-0 Hydrogen Gas Dissolved Hydrogen Gas NE NE NE 420
SW338 Hydrogen Sulfide NE NE NE 338
646-07-1 i-Hexonic Acid NE NE NE 486
193-39-5 Indeno(1,2,3-cd)pyrene Indeno[1,2,3-cd]pyrene 0.05 -- 10 125
503-74-2 i-Pentanoic Acid NE NE NE 488
7439-89-6 Iron 300 -- 300 340
78-83-1 Isobutyl alcohol 1-Propanol, 2-methyl- NE NE 100 126
465-73-6 Isodrin 1,4,5,8-Dimethanonaphthalene,1,2,3,4,1 NE NE 20 127
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
78-59-1 Isophorone 2-Cyclohexen-1-one,3,5,5-trimethyl- 40 -- 10 128
108-20-3 Isopropyl ether 70 -- NE 366
98-82-8 Isopropylbenzene 70 -- NE 367
120-58-1 Isosafrole 1,3-Benzodioxole, 5-(1-propenyl)- NE NE 10 129
143-50-0 Kepone 1,3,4-Metheno-2H-cyclobuta- NE NE 20 130
SW415 Lactic Acid Lactic Acid NE NE NE 415
SW329 Landfill Gas LFG NE NE NE 329
7439-92-1 Lead Lead 15 -- 10 131 I
SW374 m-&p-Cresol (combined) NE NE NE 374
SW359 m-&p-Xylene (combined) NE NE NE 359
7439-95-4 Magnesium NE NE NE 376
7439-96-5 Manganese 50 -- 50 342
SW335 Manganese- Dissolved 50 -- 50 335
94-74-6 MCPA NE NE NE 351
108-39-4 m-Cresol; 3-Methylphenol Phenol, 3-methyl- 400 -- 10 345
541-73-1 m-Dichlorobenzene; 1,3- Benzene, 1,3-dichloro- 200 -- 5 70
99-65-0 m-Dinitrobenzene Benzene, 1,3-dinitro- NE NE 20 97
93-65-2 Mecopop, MCPP NE NE NE 354
7439-97-6 Mercury Mercury 1 -- 0.2 132
126-98-7 Methacrylonitrile 2-Propenenitrile, 2-methyl- NE NE 100 133
SW333 Methane- Dissolved NE NE NE 333
67-56-1 Methanol 4000 NE NE 448
91-80-5 Methapyrilene 1,2,Ethanediamine, N,N-dimethyl-N'-2- NE NE 100 134
72-43-5 Methoxychlor Benzene, 1,1'- 40 -- 1 135
72-43-5 Methoxychlor 40 NE NE 449
74-83-9 Methyl bromide; Bromomethane Methane, bromo- NE 10 10 136 I
74-87-3 Methyl chloride; Chloromethane Methane, chloro- 3 -- 1 137 I
78-93-3 Methyl ethyl ketone; MEK; 2- 2-Butanone 4000 -- 100 141 I
74-88-4 Methyl iodide; Iodomethane Methane, iodo- NE NE 10 142 I
108-10-1 Methyl Isobutyl Ketone 100 493
80-62-6 Methyl methacrylate 2-Propenoic acid, 2-methyl-, methyl NE 25 30 143
66-27-3 Methyl methanesulfonate Methanesulfonic acid,methyl ester NE NE 10 144
298-00-0 Methyl parathion; Parathion methyl Phosphorothioic acid,O,O-dimethyl NE NE 10 146
2037-26-5 Methylbenzene NE NE NE 461
74-95-3 Methylene bromide; Methane, dibromo- NE 70 10 139 I
75-09-2 Methylene chloride; Methane, dichloro- 5 -- 1 140 I
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
1634-04-4 Methyl-tert-butyl ether (MTBE) 20 -- NE 369
99-09-2 m-Nitroaniline; 3-Nitroaniline Benzenamine, 3-nitro- NE NE 50 153
7439-98-7 Molybdenum NE NE NE 397
108-38-3 m-Xylene NE NE NE 409
91-20-3 Naphthalene Naphthalene 6 -- 10 148
104-51-8 n-Butylbenzene 70 -- NE 361
110-54-3 n-Hexane 400 NE NE 447
7440-02-0 Nickel Nickel 100 -- 50 152 I
14797-55-8 Nitrate (as N)10000 -- 10000 303
14797-65-0 Nitrite (as N)1000 -- 1000 304
98-95-3 Nitrobenzene Benzene, nitro- NE NE 10 156
7727-37-9 Nitrogen NE NE NE 467
55-18-5 N-Nitrosodiethylamine Ethanamine, N-ethyl-N-nitroso- NE NE 20 160
62-75-9 N-Nitrosodimethylamine Methanamine, N-methyl-N-nitroso- 0.0007 -- 10 161
924-16-3 N-Nitrosodi-n-butylamine 1-Butanamine, N-butyl-N-nitroso- NE NE 10 162
86-30-6 N-Nitrosodiphenylamine Benzenamine, N-nitroso-N-phenyl- NE NE 10 163
SW426 N- N- NE NE 10 426
SW439 N-NE NE NE 439
621-64-7 N-Nitrosodipropylamine; N-Nitroso-N- 1-Propanamine, N-nitroso-N-propyl- NE NE 10 164
10595-95-6 N-Nitrosomethylethalamine Ethanamine, N-methyl-N-nitroso- NE NE 10 165
59-89-2 N-Nitrosomorpholine NE NE NE 389
100-75-4 N-Nitrosopiperidine Piperidine, 1-nitroso- NE NE 20 166
930-55-2 N-Nitrosopyrrolidine Pyrrolidine, 1-nitroso- NE NE 10 167
SW419 No2/No3 (nitrate & nitrite reported NOX NE NE NE 419
103-65-1 n-Propylbenzene 70 NE NE 370
126-68-1 O,O,O-Triethyl phosphorothioate Phosphorothioic acid,O,O,O-triethyl NE NE 10 207
297-97-2 O,O-Diethyl O-2-pyrazinyl Phosphorothioic acid,O,O-diethyl O- NE NE 20 89
136777-61-2 o,p-Xylene NE NE NE 460
95-49-8 o-Chlorotoluene 2-chlorotoluene 100 NE NE 364
95-48-7 o-Cresol; 2-Methylphenol Phenol, 2-methyl- NE 400 10 56
95-50-1 o-Dichlorobenzene; 1,2- Benzene, 1,2-dichloro- 20 -- 5 69 I
88-74-4 o-Nitroaniline; 2-Nitroaniline Benzenamine, 2-nitro- NE NE 50 154
88-75-5 o-Nitrophenol; 2-Nitrophenol Phenol, 2-nitro- NE NE 10 158
SW437 Orthophosphate Phosphorus NE NE NE 437
95-53-4 o-Toluidine Benzenamine, 2-methyl- NE NE 10 197
23135-22-0 Oxamyl 200 NE NE 450
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
SW336 Oxygen Reduction Potential (mV) ORP NE NE NE 336
96-47-6 o-Xylene NE NE NE 408
60-11-7 p-(Dimethylamino)azobenzene Benzenamine, N,N-dimethyl-4- NE NE 10 92
56-38-2 Parathion Phosphorothioic acid,O,O-diethyl-O-(4- NE NE 10 169
106-47-8 p-Chloroaniline Benzenamine, 4-chloro- NE NE 20 38
59-50-7 p-Chloro-m-cresol; 4-Chloro-3- Phenol, 4-chloro-3-methyl- NE NE 20 45
106-43-4 p-Chlorotoluene NE 24 NE 365
106-44-5 p-Cresol; 4-Methylphenol Phenol, 4-methyl- 40 NE-- 10 344
99-87-6 p-Cymene NE 25 NE 368
106-46-7 p-Dichlorobenzene; 1,4- Benzene, 1,4-dichloro- 6 -- 1 71 I
608-93-5 Pentachlorobenzene Benzene, pentachloro- NE NE 10 171
76-01-7 Pentachloroethane NE NE NE 380
82-68-8 Pentachloronitrobenzene Benzene,pentachloronitro- NE NE 20 172
87-86-5 Pentachlorophenol Phenol, pentachloro- 0.3 -- 25 173
109-52-4 Pentanoic Acid NE NE NE 487
7790-98-9 Perchlorate and Perchlorate Salts 2 494
335-67-1 Perfluorooctanoic acid PFOA, C8 2 484
SW307 petroleum aliphatic carbon fraction class 10000 -- NE 307
SW305 petroleum aliphatic carbon fraction class 400 -- NE 305
SW306 petroleum aliphatic carbon fraction class 700 -- NE 306
SW308 petroleum aromatics carbon fraction 200 -- NE 308
SW320 pH (field)NE NE NE 320
SW321 pH (lab)NE NE NE 321
62-44-2 Phenacetin Acetamide, N-(4-ethoxyphenyl) NE NE 20 174
85-01-8 Phenanthrene Phenanthrene 200 -- 10 175
108-95-2 Phenol Phenol 30 -- 10 177
298-02-2 Phorate Phosphorodithioic acid,O,O-diethyl S- 1 -- 10 178
96-91-3 Picramic Acid 2-amino-4,6-dinitiphenol NE 0.7 NE 482
100-01-6 p-Nitroaniline; 4-Nitroaniline Benzenamine, 4-nitro- NE NE 20 155
100-02-7 p-Nitrophenol; 4-Nitrophenol Phenol, 4-nitro- NE NE 50 159
1336-36-3 Polychlorinated biphenyls; PCBs 1,1'-Biphenyl,chloro derivatives Method NE 0.09 2 434
7440-09-7 Potassium NE NE NE 377
106-50-3 p-Phenylenediamine 1,4-Benzenediamine NE NE 10 176
23950-58-5 Pronamide Benzamide, 3,5-dichloro-N-(1,1- NE NE 10 179
SW417 Propionic Acid Propionic Acid NE NE NE 417
107-12-0 Propionitrile; Ethyl cyanide Propanenitrile NE NE 150 180
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
57-55-6 Propylene Glycol NE 140,000 NE 507
106-42-3 p-Xylene NE NE NE 410
129-00-0 Pyrene Pyrene 200 -- 10 181
110-86-1 Pyridine NE 7 NE 391
SW414 Pyruvic Acid Pyruvic Acid NE NE NE 414
94-59-7 Safrole 1,3-Benzodioxole, 5-(2-propenyl)- NE NE 10 182
135-98-8 sec-Butylbenzene 70 -- NE 362
7782-49-2 Selenium Selenium 20 -- 10 183 I
7440-22-4 Silver Silver 20 -- 10 184 I
93-72-1 Silvex; 2,4,5-TP Propanoic acid, 2-(2,4,5- 50 -- 2 185
122-34-9 Simazine 4 NE NE 451
7440-23-5 Sodium NE 20000 NE 322
SW323 SpecCond (field)NE NE NE 323
SW324 SpecCond (lab)NE NE NE 324
7440-24-6 Strontium NE NE NE 465
100-42-5 Styrene Benzene, ethenyl- 70 -- 1 186 I
14808-79-8 Sulfate 250000 -- 250000 315
18496-25-8 Sulfide Sulfide NE NE 1000 187
3689-24-5 Sulfotep NE NE NE 392
99-35-4 sym-Trinitrobenzene Benzene, 1,3,5-trinitro- NE NE 10 208
SW325 Temp (oC)NE NE NE 325
994-05-8 tert-Amyl methyl ether TAME, 2-methoxy-2-methylbutane NE 128 NE 504
98-06-6 tert-Butylbenzene 70 -- NE 363
75-65-0 Tertiary Butyl Alcohol tert-butanol NE 10 NE 505
127-18-4 Tetrachloroethylene; Tetrachloroethene; Ethene, tetrachloro- 0.7 -- 1 192 I
109-99-9 Tetrahydrofuran NE NE NE 458
7440-28-0 Thallium Thallium NE 0.28 5.5 194 I
7440-31-5 Tin Tin NE 2000 100 195
108-88-3 Toluene Benzene, methyl- 600 -- 1 196 I
SW328 Top Of Casing (ft mean sea level) TOC NE NE NE 328
SW425 Total BHC NE 0.019 NE 425
SW311 Total Dissolved Solids TDS 500000 -- NE 311
SW436 Total Fatty Acids Total Fatty Acids NE NE NE 436
E-10195 Total Organic Carbon NE NE NE 357
SW396 Total Organic Halides NE NE NE 396
7723-14-0 Total Phosphorus Total Phosphorus NE NE NE 412
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
Page 11 of 12NCDENR - Constituent List
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CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I
SW343 Total Suspended Solids NE NE NE 343
SW411 Total Well Depth (ft) TD NE NE NE 411
8001-35-2 Toxaphene Toxaphene 0.03 -- 1.5 198
156-60-5 trans-1,2-Dichloroethylene; trans-1,2- Ethene, 1,2-dichloro-,(E)- 100 -- 5 79 I
10061-02-6 trans-1,3-Dichloropropene 1-Propene, 1,3-dichloro-, (E)- 0.4 -- 1 87 I
110-57-6 trans-1,4-Dichloro-2-butene 2-Butene, 1,4-dichloro-, (E)- NE NE 100 73 I
79-01-6 Trichloroethylene; Trichloroethene Ethene, trichloro- 3 -- 1 201 I
75-69-4 Trichlorofluoromethane; CFC-11 Methane,trichlorofluoro- 2000 -- 1 203 I
SW330 Turbidity NE NE NE 330
7440-62-2 Vanadium Vanadium NE 0.3 25 209 I
108-05-4 Vinyl acetate Acetic acid, ethenylester NE 88 50 210 I
75-01-4 Vinyl chloride; Chloroethene Ethene, chloro- 0.03 -- 1 211 I
1330-20-7 Xylene (total) (o-,m-,and p-, Benzene, dimethyl 500 -- 5 346 I
7440-66-6 Zinc Zinc 1000 -- 10 213 I
* GWP = Groundwater Protection
** SWSL = Solid Waste
Last updated: 6/13/2011 8:19:15 AM
N.C. Department of Environment and Natural Resources
1601 Mail Service Center, Raleigh, NC 27699-1601
Headquarters (Environment and Natural Resources Building): 217 W. Jones St.
Archdale Building: 512 N. Salisbury St.
Toll Free:[phone]
Page 12 of 12NCDENR - Constituent List
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Water Quality Monitoring Report
2016 Annual Sampling Event

ATTACHMENT 3
Laboratory Analytical Results
Pace Analytical Services, Inc.

#=CL#
January 09, 2017
LIMS USE: FR - MICHAEL COBB
LIMS OBJECT ID: 92323984
92323984
Project:
Pace Project No.:
RE:
Mr. Michael Cobb
SCS Engineers
2520 Whitehall Park Drive
Suite 450
Charlotte, NC 28273
ANSON CO LILESVILLE GW 0220936
Dear Mr. Cobb:
Enclosed are the analytical results for sample(s) received by the laboratory on December 20, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Marta VanDussen, SCS Engineers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323984001 MW-A EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-ASER
EPA 8260 50 PASI-CCAH
SM 4500-S2D 1 PASI-AMDW
SM 5210B 1 PASI-ABRJ
EPA 300.0 2 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-OAEM
92323984002 MW-B EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-ASER
EPA 8260 50 PASI-CCAH
SM 4500-S2D 1 PASI-AMDW
SM 5210B 1 PASI-ABRJ
EPA 300.0 2 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-OAEM
92323984003 MW-C EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-ASER
EPA 8260 50 PASI-CCAH
SM 4500-S2D 1 PASI-AMDW
SM 5210B 1 PASI-ABRJ
EPA 300.0 2 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-OAEM
92323984004 MW-D EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-ASER
EPA 8260 50 PASI-CCAH
SM 4500-S2D 1 PASI-AMDW
SM 5210B 1 PASI-ABRJ
EPA 300.0 2 PASI-AAES2
EPA 353.2 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-A Lab ID:92323984001 Collected:12/19/16 12:20 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 01/03/17 13:56 7440-36-012/28/16 20:455.0 1
Arsenic ND ug/L 01/03/17 13:56 7440-38-212/28/16 20:4510.0 1
Barium 19.5 ug/L 01/03/17 13:56 7440-39-312/28/16 20:455.0 1
Beryllium ND ug/L 01/03/17 13:56 7440-41-712/28/16 20:451.0 1
Cadmium ND ug/L 01/03/17 13:56 7440-43-912/28/16 20:451.0 1
Chromium ND ug/L 01/03/17 13:56 7440-47-312/28/16 20:455.0 1
Cobalt ND ug/L 01/03/17 13:56 7440-48-412/28/16 20:455.0 1
Copper ND ug/L 01/03/17 13:56 7440-50-812/28/16 20:455.0 1
Lead ND ug/L 01/03/17 13:56 7439-92-112/28/16 20:455.0 1
Nickel ND ug/L 01/03/17 13:56 7440-02-012/28/16 20:455.0 1
Selenium ND ug/L 01/03/17 13:56 7782-49-212/28/16 20:4510.0 1
Silver ND ug/L 01/03/17 13:56 7440-22-412/28/16 20:455.0 1
Thallium ND ug/L 01/03/17 13:56 7440-28-012/28/16 20:455.4 1
Vanadium ND ug/L 01/03/17 13:56 7440-62-212/28/16 20:455.0 1
Zinc ND ug/L 01/03/17 13:56 7440-66-612/28/16 20:4510.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 05:49 7439-97-612/22/16 02:000.20 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 22:59 67-64-125.0 1
Acrylonitrile ND ug/L 12/21/16 22:59 107-13-110.0 1
Benzene ND ug/L 12/21/16 22:59 71-43-21.0 1
Bromochloromethane ND ug/L 12/21/16 22:59 74-97-51.0 1
Bromodichloromethane ND ug/L 12/21/16 22:59 75-27-41.0 1
Bromoform ND ug/L 12/21/16 22:59 75-25-21.0 1
Bromomethane ND ug/L 12/21/16 22:59 74-83-92.0 1
2-Butanone (MEK)ND ug/L 12/21/16 22:59 78-93-35.0 1
Carbon disulfide ND ug/L 12/21/16 22:59 75-15-02.0 1
Carbon tetrachloride ND ug/L 12/21/16 22:59 56-23-51.0 1
Chlorobenzene ND ug/L 12/21/16 22:59 108-90-71.0 1
Chloroethane ND ug/L 12/21/16 22:59 75-00-31.0 1
Chloroform ND ug/L 12/21/16 22:59 67-66-31.0 1
Chloromethane ND ug/L 12/21/16 22:59 74-87-31.0 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 22:59 96-12-82.0 1
Dibromochloromethane ND ug/L 12/21/16 22:59 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 22:59 106-93-41.0 1
Dibromomethane ND ug/L 12/21/16 22:59 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 12/21/16 22:59 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 12/21/16 22:59 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 22:59 110-57-61.0 1
1,1-Dichloroethane ND ug/L 12/21/16 22:59 75-34-31.0 1
1,2-Dichloroethane ND ug/L 12/21/16 22:59 107-06-21.0 1
1,1-Dichloroethene ND ug/L 12/21/16 22:59 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 22:59 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 22:59 156-60-51.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-A Lab ID:92323984001 Collected:12/19/16 12:20 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 22:59 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 22:59 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 22:59 10061-02-61.0 1
Ethylbenzene ND ug/L 12/21/16 22:59 100-41-41.0 1
2-Hexanone ND ug/L 12/21/16 22:59 591-78-65.0 1
Iodomethane ND ug/L 12/21/16 22:59 74-88-45.0 1
Methylene Chloride ND ug/L 12/21/16 22:59 75-09-21.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 22:59 108-10-15.0 1
Styrene ND ug/L 12/21/16 22:59 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 22:59 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 22:59 79-34-5 L21.0 1
Tetrachloroethene ND ug/L 12/21/16 22:59 127-18-41.0 1
Toluene ND ug/L 12/21/16 22:59 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 12/21/16 22:59 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 12/21/16 22:59 79-00-51.0 1
Trichloroethene ND ug/L 12/21/16 22:59 79-01-61.0 1
Trichlorofluoromethane ND ug/L 12/21/16 22:59 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/21/16 22:59 96-18-41.0 1
Vinyl acetate ND ug/L 12/21/16 22:59 108-05-42.0 1
Vinyl chloride ND ug/L 12/21/16 22:59 75-01-41.0 1
Xylene (Total)ND ug/L 12/21/16 22:59 1330-20-71.0 1
Surrogates
4-Bromofluorobenzene (S)103 %12/21/16 22:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/21/16 22:59 17060-07-070-130 1
Toluene-d8 (S)96 %12/21/16 22:59 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/22/16 19:44 18496-25-8 M11001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 12/26/16 09:5012/21/16 04:3720001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Fluoride ND ug/L 12/23/16 03:27 16984-48-85001
Sulfate 3470 ug/L 12/23/16 03:27 14808-79-820001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/20/16 23:3220.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3870 ug/L 01/03/17 17:30 16887-00-610001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 12/27/16 23:40 M1250001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-A Lab ID:92323984001 Collected:12/19/16 12:20 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND mg/L 01/07/17 05:12 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-B Lab ID:92323984002 Collected:12/19/16 10:55 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 01/01/17 07:23 7440-36-012/28/16 20:455.0 1
Arsenic ND ug/L 01/01/17 07:23 7440-38-212/28/16 20:4510.0 1
Barium 10.6 ug/L 01/01/17 07:23 7440-39-312/28/16 20:455.0 1
Beryllium ND ug/L 01/01/17 07:23 7440-41-712/28/16 20:451.0 1
Cadmium ND ug/L 01/01/17 07:23 7440-43-912/28/16 20:451.0 1
Chromium ND ug/L 01/01/17 07:23 7440-47-312/28/16 20:455.0 1
Cobalt ND ug/L 01/01/17 07:23 7440-48-412/28/16 20:455.0 1
Copper ND ug/L 01/01/17 07:23 7440-50-812/28/16 20:455.0 1
Lead ND ug/L 01/01/17 07:23 7439-92-112/28/16 20:455.0 1
Nickel ND ug/L 01/01/17 07:23 7440-02-012/28/16 20:455.0 1
Selenium ND ug/L 01/01/17 07:23 7782-49-212/28/16 20:4510.0 1
Silver ND ug/L 01/01/17 07:23 7440-22-412/28/16 20:455.0 1
Thallium ND ug/L 01/01/17 07:23 7440-28-012/28/16 20:455.4 1
Vanadium ND ug/L 01/01/17 07:23 7440-62-212/28/16 20:455.0 1
Zinc ND ug/L 01/01/17 07:23 7440-66-612/28/16 20:4510.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 05:56 7439-97-612/22/16 02:000.20 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 23:16 67-64-125.0 1
Acrylonitrile ND ug/L 12/21/16 23:16 107-13-110.0 1
Benzene ND ug/L 12/21/16 23:16 71-43-21.0 1
Bromochloromethane ND ug/L 12/21/16 23:16 74-97-51.0 1
Bromodichloromethane ND ug/L 12/21/16 23:16 75-27-41.0 1
Bromoform ND ug/L 12/21/16 23:16 75-25-21.0 1
Bromomethane ND ug/L 12/21/16 23:16 74-83-92.0 1
2-Butanone (MEK)ND ug/L 12/21/16 23:16 78-93-35.0 1
Carbon disulfide ND ug/L 12/21/16 23:16 75-15-02.0 1
Carbon tetrachloride ND ug/L 12/21/16 23:16 56-23-51.0 1
Chlorobenzene ND ug/L 12/21/16 23:16 108-90-71.0 1
Chloroethane ND ug/L 12/21/16 23:16 75-00-31.0 1
Chloroform ND ug/L 12/21/16 23:16 67-66-31.0 1
Chloromethane ND ug/L 12/21/16 23:16 74-87-31.0 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 23:16 96-12-82.0 1
Dibromochloromethane ND ug/L 12/21/16 23:16 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 23:16 106-93-41.0 1
Dibromomethane ND ug/L 12/21/16 23:16 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 12/21/16 23:16 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 12/21/16 23:16 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 23:16 110-57-61.0 1
1,1-Dichloroethane ND ug/L 12/21/16 23:16 75-34-31.0 1
1,2-Dichloroethane ND ug/L 12/21/16 23:16 107-06-21.0 1
1,1-Dichloroethene ND ug/L 12/21/16 23:16 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 23:16 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 23:16 156-60-51.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-B Lab ID:92323984002 Collected:12/19/16 10:55 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 23:16 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 23:16 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 23:16 10061-02-61.0 1
Ethylbenzene ND ug/L 12/21/16 23:16 100-41-41.0 1
2-Hexanone ND ug/L 12/21/16 23:16 591-78-65.0 1
Iodomethane ND ug/L 12/21/16 23:16 74-88-45.0 1
Methylene Chloride ND ug/L 12/21/16 23:16 75-09-21.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 23:16 108-10-15.0 1
Styrene ND ug/L 12/21/16 23:16 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 23:16 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 23:16 79-34-5 L21.0 1
Tetrachloroethene ND ug/L 12/21/16 23:16 127-18-41.0 1
Toluene ND ug/L 12/21/16 23:16 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 12/21/16 23:16 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 12/21/16 23:16 79-00-51.0 1
Trichloroethene ND ug/L 12/21/16 23:16 79-01-61.0 1
Trichlorofluoromethane ND ug/L 12/21/16 23:16 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/21/16 23:16 96-18-41.0 1
Vinyl acetate ND ug/L 12/21/16 23:16 108-05-42.0 1
Vinyl chloride ND ug/L 12/21/16 23:16 75-01-41.0 1
Xylene (Total)ND ug/L 12/21/16 23:16 1330-20-71.0 1
Surrogates
4-Bromofluorobenzene (S)104 %12/21/16 23:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/21/16 23:16 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 23:16 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/22/16 19:44 18496-25-81001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 12/26/16 09:5012/21/16 04:3720001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Fluoride ND ug/L 12/23/16 03:47 16984-48-85001
Sulfate 5240 ug/L 12/23/16 03:47 14808-79-820001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/20/16 23:3120.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3360 ug/L 01/03/17 17:33 16887-00-610001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 12/27/16 23:40250001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-B Lab ID:92323984002 Collected:12/19/16 10:55 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND mg/L 01/07/17 05:26 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-C Lab ID:92323984003 Collected:12/19/16 14:30 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 01/01/17 07:26 7440-36-012/28/16 20:455.0 1
Arsenic ND ug/L 01/01/17 07:26 7440-38-212/28/16 20:4510.0 1
Barium 39.1 ug/L 01/01/17 07:26 7440-39-312/28/16 20:455.0 1
Beryllium ND ug/L 01/01/17 07:26 7440-41-712/28/16 20:451.0 1
Cadmium ND ug/L 01/01/17 07:26 7440-43-912/28/16 20:451.0 1
Chromium ND ug/L 01/01/17 07:26 7440-47-312/28/16 20:455.0 1
Cobalt ND ug/L 01/01/17 07:26 7440-48-412/28/16 20:455.0 1
Copper ND ug/L 01/01/17 07:26 7440-50-812/28/16 20:455.0 1
Lead ND ug/L 01/01/17 07:26 7439-92-112/28/16 20:455.0 1
Nickel ND ug/L 01/01/17 07:26 7440-02-012/28/16 20:455.0 1
Selenium ND ug/L 01/01/17 07:26 7782-49-212/28/16 20:4510.0 1
Silver ND ug/L 01/01/17 07:26 7440-22-412/28/16 20:455.0 1
Thallium ND ug/L 01/01/17 07:26 7440-28-012/28/16 20:455.4 1
Vanadium ND ug/L 01/01/17 07:26 7440-62-212/28/16 20:455.0 1
Zinc ND ug/L 01/01/17 07:26 7440-66-612/28/16 20:4510.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 05:59 7439-97-612/22/16 02:000.20 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 23:33 67-64-125.0 1
Acrylonitrile ND ug/L 12/21/16 23:33 107-13-110.0 1
Benzene ND ug/L 12/21/16 23:33 71-43-21.0 1
Bromochloromethane ND ug/L 12/21/16 23:33 74-97-51.0 1
Bromodichloromethane ND ug/L 12/21/16 23:33 75-27-41.0 1
Bromoform ND ug/L 12/21/16 23:33 75-25-21.0 1
Bromomethane ND ug/L 12/21/16 23:33 74-83-92.0 1
2-Butanone (MEK)ND ug/L 12/21/16 23:33 78-93-35.0 1
Carbon disulfide ND ug/L 12/21/16 23:33 75-15-02.0 1
Carbon tetrachloride ND ug/L 12/21/16 23:33 56-23-51.0 1
Chlorobenzene ND ug/L 12/21/16 23:33 108-90-71.0 1
Chloroethane ND ug/L 12/21/16 23:33 75-00-31.0 1
Chloroform ND ug/L 12/21/16 23:33 67-66-31.0 1
Chloromethane ND ug/L 12/21/16 23:33 74-87-31.0 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 23:33 96-12-82.0 1
Dibromochloromethane ND ug/L 12/21/16 23:33 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 23:33 106-93-41.0 1
Dibromomethane ND ug/L 12/21/16 23:33 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 12/21/16 23:33 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 12/21/16 23:33 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 23:33 110-57-61.0 1
1,1-Dichloroethane ND ug/L 12/21/16 23:33 75-34-31.0 1
1,2-Dichloroethane ND ug/L 12/21/16 23:33 107-06-21.0 1
1,1-Dichloroethene ND ug/L 12/21/16 23:33 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 23:33 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 23:33 156-60-51.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-C Lab ID:92323984003 Collected:12/19/16 14:30 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 23:33 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 23:33 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 23:33 10061-02-61.0 1
Ethylbenzene ND ug/L 12/21/16 23:33 100-41-41.0 1
2-Hexanone ND ug/L 12/21/16 23:33 591-78-65.0 1
Iodomethane ND ug/L 12/21/16 23:33 74-88-45.0 1
Methylene Chloride ND ug/L 12/21/16 23:33 75-09-21.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 23:33 108-10-15.0 1
Styrene ND ug/L 12/21/16 23:33 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 23:33 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 23:33 79-34-5 L21.0 1
Tetrachloroethene ND ug/L 12/21/16 23:33 127-18-41.0 1
Toluene ND ug/L 12/21/16 23:33 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 12/21/16 23:33 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 12/21/16 23:33 79-00-51.0 1
Trichloroethene ND ug/L 12/21/16 23:33 79-01-61.0 1
Trichlorofluoromethane ND ug/L 12/21/16 23:33 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/21/16 23:33 96-18-41.0 1
Vinyl acetate ND ug/L 12/21/16 23:33 108-05-42.0 1
Vinyl chloride ND ug/L 12/21/16 23:33 75-01-41.0 1
Xylene (Total)ND ug/L 12/21/16 23:33 1330-20-71.0 1
Surrogates
4-Bromofluorobenzene (S)105 %12/21/16 23:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 23:33 17060-07-070-130 1
Toluene-d8 (S)100 %12/21/16 23:33 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/22/16 19:44 18496-25-81001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 12/26/16 09:5012/21/16 04:3720001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Fluoride ND ug/L 12/23/16 04:07 16984-48-85001
Sulfate ND ug/L 12/23/16 04:07 14808-79-820001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 12/20/16 23:3320.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 6530 ug/L 01/03/17 17:34 16887-00-610001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 12/27/16 23:40250001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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Huntersville, NC 28078
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Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-C Lab ID:92323984003 Collected:12/19/16 14:30 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 3.4 mg/L 01/07/17 06:32 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 13 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-D Lab ID:92323984004 Collected:12/19/16 15:50 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 01/01/17 07:29 7440-36-012/28/16 20:455.0 1
Arsenic ND ug/L 01/01/17 07:29 7440-38-212/28/16 20:4510.0 1
Barium 54.0 ug/L 01/01/17 07:29 7440-39-312/28/16 20:455.0 1
Beryllium ND ug/L 01/01/17 07:29 7440-41-712/28/16 20:451.0 1
Cadmium ND ug/L 01/01/17 07:29 7440-43-912/28/16 20:451.0 1
Chromium ND ug/L 01/01/17 07:29 7440-47-312/28/16 20:455.0 1
Cobalt 5.1 ug/L 01/01/17 07:29 7440-48-412/28/16 20:455.0 1
Copper ND ug/L 01/01/17 07:29 7440-50-812/28/16 20:455.0 1
Lead ND ug/L 01/01/17 07:29 7439-92-112/28/16 20:455.0 1
Nickel 5.5 ug/L 01/01/17 07:29 7440-02-012/28/16 20:455.0 1
Selenium ND ug/L 01/01/17 07:29 7782-49-212/28/16 20:4510.0 1
Silver ND ug/L 01/01/17 07:29 7440-22-412/28/16 20:455.0 1
Thallium ND ug/L 01/01/17 07:29 7440-28-012/28/16 20:455.4 1
Vanadium ND ug/L 01/01/17 07:29 7440-62-212/28/16 20:455.0 1
Zinc 15.2 ug/L 01/01/17 07:29 7440-66-612/28/16 20:4510.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 06:01 7439-97-612/22/16 02:000.20 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 23:50 67-64-125.0 1
Acrylonitrile ND ug/L 12/21/16 23:50 107-13-110.0 1
Benzene ND ug/L 12/21/16 23:50 71-43-21.0 1
Bromochloromethane ND ug/L 12/21/16 23:50 74-97-51.0 1
Bromodichloromethane ND ug/L 12/21/16 23:50 75-27-41.0 1
Bromoform ND ug/L 12/21/16 23:50 75-25-21.0 1
Bromomethane ND ug/L 12/21/16 23:50 74-83-92.0 1
2-Butanone (MEK)ND ug/L 12/21/16 23:50 78-93-35.0 1
Carbon disulfide ND ug/L 12/21/16 23:50 75-15-02.0 1
Carbon tetrachloride ND ug/L 12/21/16 23:50 56-23-51.0 1
Chlorobenzene ND ug/L 12/21/16 23:50 108-90-71.0 1
Chloroethane ND ug/L 12/21/16 23:50 75-00-31.0 1
Chloroform ND ug/L 12/21/16 23:50 67-66-31.0 1
Chloromethane ND ug/L 12/21/16 23:50 74-87-31.0 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 23:50 96-12-82.0 1
Dibromochloromethane ND ug/L 12/21/16 23:50 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 23:50 106-93-41.0 1
Dibromomethane ND ug/L 12/21/16 23:50 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 12/21/16 23:50 95-50-11.0 1
1,4-Dichlorobenzene ND ug/L 12/21/16 23:50 106-46-71.0 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 23:50 110-57-61.0 1
1,1-Dichloroethane ND ug/L 12/21/16 23:50 75-34-31.0 1
1,2-Dichloroethane ND ug/L 12/21/16 23:50 107-06-21.0 1
1,1-Dichloroethene ND ug/L 12/21/16 23:50 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 23:50 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 23:50 156-60-51.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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[phone]
Page 14 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-D Lab ID:92323984004 Collected:12/19/16 15:50 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 23:50 78-87-51.0 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 23:50 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 23:50 10061-02-61.0 1
Ethylbenzene ND ug/L 12/21/16 23:50 100-41-41.0 1
2-Hexanone ND ug/L 12/21/16 23:50 591-78-65.0 1
Iodomethane ND ug/L 12/21/16 23:50 74-88-45.0 1
Methylene Chloride ND ug/L 12/21/16 23:50 75-09-21.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 23:50 108-10-15.0 1
Styrene ND ug/L 12/21/16 23:50 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 23:50 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 23:50 79-34-5 L21.0 1
Tetrachloroethene ND ug/L 12/21/16 23:50 127-18-41.0 1
Toluene ND ug/L 12/21/16 23:50 108-88-31.0 1
1,1,1-Trichloroethane ND ug/L 12/21/16 23:50 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 12/21/16 23:50 79-00-51.0 1
Trichloroethene ND ug/L 12/21/16 23:50 79-01-61.0 1
Trichlorofluoromethane ND ug/L 12/21/16 23:50 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 12/21/16 23:50 96-18-41.0 1
Vinyl acetate ND ug/L 12/21/16 23:50 108-05-42.0 1
Vinyl chloride ND ug/L 12/21/16 23:50 75-01-41.0 1
Xylene (Total)ND ug/L 12/21/16 23:50 1330-20-71.0 1
Surrogates
4-Bromofluorobenzene (S)105 %12/21/16 23:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/21/16 23:50 17060-07-070-130 1
Toluene-d8 (S)100 %12/21/16 23:50 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/22/16 19:44 18496-25-81001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 12/26/16 09:5012/21/16 04:3720001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Fluoride ND ug/L 12/23/16 04:26 16984-48-85001
Sulfate 2800 ug/L 12/23/16 04:26 14808-79-820001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 74.9 ug/L 12/20/16 23:3420.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1740 ug/L 01/03/17 17:35 16887-00-610001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 12/27/16 23:40250001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Sample:MW-D Lab ID:92323984004 Collected:12/19/16 15:50 Received:12/20/16 10:36 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND mg/L 01/07/17 05:39 7440-44-01.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341884
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896911
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 12/23/16 05:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896912LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896913MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896914
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ug/L 2.5 90 75-12592 22.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342311
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1899183
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Antimony ug/L ND 5.0 01/01/17 06:59
Arsenic ug/L ND 10.0 01/01/17 06:59
Barium ug/L ND 5.0 01/01/17 06:59
Beryllium ug/L ND 1.0 01/01/17 06:59
Cadmium ug/L ND 1.0 01/01/17 06:59
Chromium ug/L ND 5.0 01/01/17 06:59
Cobalt ug/L ND 5.0 01/01/17 06:59
Copper ug/L ND 5.0 01/01/17 06:59
Lead ug/L ND 5.0 01/01/17 06:59
Nickel ug/L ND 5.0 01/01/17 06:59
Selenium ug/L ND 10.0 01/01/17 06:59
Silver ug/L ND 5.0 01/01/17 06:59
Thallium ug/L ND 5.4 01/01/17 06:59
Vanadium ug/L ND 5.0 01/01/17 06:59
Zinc ug/L ND 10.0 01/01/17 06:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1899184LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 502500 100 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 484500 97 80-120
Cadmium ug/L 490500 98 80-120
Chromium ug/L 477500 95 80-120
Cobalt ug/L 496500 99 80-120
Copper ug/L 520500 104 80-120
Lead ug/L 486500 97 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 507500 101 80-120
Silver ug/L 251250 100 80-120
Thallium ug/L 486500 97 80-120
Vanadium ug/L 482500 96 80-120
Zinc ug/L 482500 96 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901202MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323984001
1901203
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Antimony ug/L 500 105 75-125105 0500ND526526
Arsenic ug/L 500 102 75-125102 0500ND508508
Barium ug/L 500 104 75-125105 150019.5 539 544
Beryllium ug/L 500 101 75-125101 1500ND503506
Cadmium ug/L 500 103 75-125102 1500ND515512
Chromium ug/L 500 99 75-125100 1500ND496503
Cobalt ug/L 500 104 75-125103 1500ND521518
Copper ug/L 500 108 75-125109 1500ND542547
Lead ug/L 500 102 75-125101 1500ND510505
Nickel ug/L 500 101 75-125100 1500ND506501
Selenium ug/L 500 105 75-125105 0500ND527526
Silver ug/L 250 104 75-125105 0250ND261262
Thallium ug/L 500 103 75-125102 1500ND516511
Vanadium ug/L 500 101 75-125101 1500ND504507
Zinc ug/L 500 101 75-125101 1500ND508506
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1897428
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:27
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:27
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:27
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:27
1,1-Dichloroethane ug/L ND 1.0 12/21/16 16:27
1,1-Dichloroethene ug/L ND 1.0 12/21/16 16:27
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:27
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/21/16 16:27
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:27
1,2-Dichlorobenzene ug/L ND 1.0 12/21/16 16:27
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:27
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:27
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:27
2-Butanone (MEK)ug/L ND 5.0 12/21/16 16:27
2-Hexanone ug/L ND 5.0 12/21/16 16:27
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/21/16 16:27
Acetone ug/L ND 25.0 12/21/16 16:27
Acrylonitrile ug/L ND 10.0 12/21/16 16:27
Benzene ug/L ND 1.0 12/21/16 16:27
Bromochloromethane ug/L ND 1.0 12/21/16 16:27
Bromodichloromethane ug/L ND 1.0 12/21/16 16:27
Bromoform ug/L ND 1.0 12/21/16 16:27
Bromomethane ug/L ND 2.0 12/21/16 16:27
Carbon disulfide ug/L ND 2.0 12/21/16 16:27
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:27
Chlorobenzene ug/L ND 1.0 12/21/16 16:27
Chloroethane ug/L ND 1.0 12/21/16 16:27
Chloroform ug/L ND 1.0 12/21/16 16:27
Chloromethane ug/L ND 1.0 12/21/16 16:27
cis-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:27
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:27
Dibromochloromethane ug/L ND 1.0 12/21/16 16:27
Dibromomethane ug/L ND 1.0 12/21/16 16:27
Ethylbenzene ug/L ND 1.0 12/21/16 16:27
Iodomethane ug/L ND 5.0 12/21/16 16:27
Methylene Chloride ug/L ND 1.0 12/21/16 16:27
Styrene ug/L ND 1.0 12/21/16 16:27
Tetrachloroethene ug/L ND 1.0 12/21/16 16:27
Toluene ug/L ND 1.0 12/21/16 16:27
trans-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:27
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1897428
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/21/16 16:27
Trichloroethene ug/L ND 1.0 12/21/16 16:27
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:27
Vinyl acetate ug/L ND 2.0 12/21/16 16:27
Vinyl chloride ug/L ND 1.0 12/21/16 16:27
Xylene (Total)ug/L ND 1.0 12/21/16 16:27
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L0507379-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acrylonitrile ug/L 292250 117 40-160
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.650 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
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Page 21 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Ethylbenzene ug/L 40.650 81 79-121
Iodomethane ug/L 75.3100 75 39-154
Methylene Chloride ug/L 54.950 110 64-133
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.550 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2-Butanone (MEK)ug/L 35.840 89 70-130ND
2-Hexanone ug/L 39.040 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.040 97 70-130ND
Acetone ug/L 40.540 98 70-130ND
Acrylonitrile ug/L 125100 125 70-130ND
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.520 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Iodomethane ug/L 23.2 M1405870-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.420 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.640 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L NDND
1,1,1-Trichloroethane ug/L NDND
1,1,2,2-Tetrachloroethane ug/L NDND
1,1,2-Trichloroethane ug/L NDND
1,1-Dichloroethane ug/L 1.2 21.2J
1,1-Dichloroethene ug/L NDND
1,2,3-Trichloropropane ug/L NDND
1,2-Dibromo-3-chloropropane ug/L NDND
1,2-Dibromoethane (EDB)ug/L NDND
1,2-Dichlorobenzene ug/L NDND
1,2-Dichloroethane ug/L NDND
1,2-Dichloropropane ug/L .45J0.39J
1,4-Dichlorobenzene ug/L 1.4 01.4
2-Butanone (MEK)ug/L NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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Huntersville, NC 28078
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Page 23 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
2-Hexanone ug/L NDND
4-Methyl-2-pentanone (MIBK)ug/L NDND
Acetone ug/L NDND
Acrylonitrile ug/L NDND
Benzene ug/L .72J0.72J
Bromochloromethane ug/L NDND
Bromodichloromethane ug/L NDND
Bromoform ug/L NDND
Bromomethane ug/L NDND
Carbon disulfide ug/L NDND
Carbon tetrachloride ug/L NDND
Chlorobenzene ug/L 5.4 104.9
Chloroethane ug/L NDND
Chloroform ug/L NDND
Chloromethane ug/L .16J0.11J
cis-1,2-Dichloroethene ug/L 3.3 13.3J
cis-1,3-Dichloropropene ug/L NDND
Dibromochloromethane ug/L NDND
Dibromomethane ug/L NDND
Ethylbenzene ug/L NDND
Iodomethane ug/L NDND
Methylene Chloride ug/L NDND
Styrene ug/L NDND
Tetrachloroethene ug/L NDND
Toluene ug/L .37J0.37J
trans-1,2-Dichloroethene ug/L NDND
trans-1,3-Dichloropropene ug/L NDND
trans-1,4-Dichloro-2-butene ug/L NDND
Trichloroethene ug/L .76J0.58J
Trichlorofluoromethane ug/L NDND
Vinyl acetate ug/L NDND
Vinyl chloride ug/L 4.9 64.6
Xylene (Total)ug/L NDND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342276
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1899031
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Sulfide ug/L ND 100 12/22/16 19:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1899032LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 506500 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899033MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323984001
1899034
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfide ug/L M15007480-12073 1500ND372369
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341850
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896755
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
BOD, 5 day ug/L ND 2000 12/26/16 09:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896756LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 172000198000 87 84.6-115.4
Parameter Units
Dup
Result QualifiersRPDResult
92323984002
1896757SAMPLE DUPLICATE:
BOD, 5 day ug/L NDND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342249
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1898881
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Fluoride ug/L ND 500 12/22/16 19:00
Sulfate ug/L ND 2000 12/22/16 19:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898882LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride ug/L 26002500 104 90-110
Sulfate ug/L 2080020000 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898883MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324124001
1898884
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride ug/L M625008290-11077 1250016.6
mg/L 18600 18500
Sulfate ug/L M6200008590-11084 02000088.1
mg/L 105000 105000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898885MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324318006
1898886
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride ug/L M625007690-11086 2250011.0
mg/L 12800 13100
Sulfate ug/L M6200008890-11089 02000084.8
mg/L 102000 103000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341843
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896733
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Nitrogen, Nitrate ug/L ND 20.0 12/20/16 22:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896734LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 23602500 94 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896735MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324003001
1896736
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 96 90-11095 12500ND23902370
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896737MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323993001
1896738
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 102 90-110103 125000.076
mg/L 2620 2640
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
343216
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1903778
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Chloride ug/L ND 1000 01/03/17 17:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1903779LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1930020000 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1903780MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323984001
1903781
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride ug/L 10000 105 90-110104 01000038701430014300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1903782MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324286002
1903783
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride ug/L 10000 95 90-11092 110000301003960039300
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342608
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1900514
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Chemical Oxygen Demand ug/L ND 25000 12/27/16 23:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900515LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 786000750000 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899101MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323984001
1899102
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M175000011490-110114 0750000ND867000870000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342755
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1838732
Associated Lab Samples:92323984001, 92323984002, 92323984003, 92323984004
Matrix:Water
Analyzed
Total Organic Carbon mg/L ND 1.0 01/07/17 04:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1838733LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon mg/L 20.520 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1838734MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324360020
1838735
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 20 104 80-120104 020ND20.8 20.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1838736MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35286985003
1838737
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 20 93 80-12094 12012.2 30.8 31.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 32 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323984
ANSON CO LILESVILLE GW 0220936
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323984001 342311 342950MW-A EPA 3010A EPA 6010
92323984002 342311 342950MW-B EPA 3010A EPA 6010
92323984003 342311 342950MW-C EPA 3010A EPA 6010
92323984004 342311 342950MW-D EPA 3010A EPA 6010
92323984001 341884 342175MW-A EPA 7470 EPA 7470
92323984002 341884 342175MW-B EPA 7470 EPA 7470
92323984003 341884 342175MW-C EPA 7470 EPA 7470
92323984004 341884 342175MW-D EPA 7470 EPA 7470
92323984001 342010MW-A EPA 8260
92323984002 342010MW-B EPA 8260
92323984003 342010MW-C EPA 8260
92323984004 342010MW-D EPA 8260
92323984001 342276MW-A SM 4500-S2D
92323984002 342276MW-B SM 4500-S2D
92323984003 342276MW-C SM 4500-S2D
92323984004 342276MW-D SM 4500-S2D
92323984001 341850 341886MW-A SM 5210B SM 5210B
92323984002 341850 341886MW-B SM 5210B SM 5210B
92323984003 341850 341886MW-C SM 5210B SM 5210B
92323984004 341850 341886MW-D SM 5210B SM 5210B
92323984001 342249MW-A EPA 300.0
92323984002 342249MW-B EPA 300.0
92323984003 342249MW-C EPA 300.0
92323984004 342249MW-D EPA 300.0
92323984001 341843MW-A EPA 353.2
92323984002 341843MW-B EPA 353.2
92323984003 341843MW-C EPA 353.2
92323984004 341843MW-D EPA 353.2
92323984001 343216MW-A SM 4500-Cl-E
92323984002 343216MW-B SM 4500-Cl-E
92323984003 343216MW-C SM 4500-Cl-E
92323984004 343216MW-D SM 4500-Cl-E
92323984001 342608MW-A SM 5220D
92323984002 342608MW-B SM 5220D
92323984003 342608MW-C SM 5220D
92323984004 342608MW-D SM 5220D
92323984001 342755MW-A SM 5310B
92323984002 342755MW-B SM 5310B
92323984003 342755MW-C SM 5310B
92323984004 342755MW-D SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/09/2017 05:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
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January 04, 2017

Mr. Kevin Godwin
Pace Analytical Services, Inc.
9800 Kincey Avenue
Suite 100
Huntersville, North Carolina 28078

Re: Routine Analytical - Godwin
Work Order: 413133
SDG: 92323984

Dear Mr. Godwin:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on December 21, 2016. This original data report has been prepared and reviewed in
accordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4778.

Sincerely,

PM_SIGN_HERE
Hope Taylor
Project Manager

Purchase Order: KRG16183
Enclosures
Page 1 of 13
Page 37 of 49
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
PACE001 Pace Analytical Services Inc.
Client SDG: 92323984 GEL Work Order: 413133
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Hope Taylor.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 13
Page 38 of 49
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: January 4, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Halogen Analysis
16277041234ug/L 12/29/16JP110.0 1
Mr. Kevin GodwinContact:
Pace Analytical Services, Inc.Company :
9800 Kincey Avenue
Huntersville, North Carolina 28078
Address :
Routine Analytical - GodwinProject:
413133001
Water
19-DEC-16 12:20
21-DEC-16
MW-A PACE00212Project:
PACE001Client ID:
Client
Sample ID:
Receive Date:
Suite 100
Client Sample ID:
Matrix:
Collect Date:
Collector:
3.33 1UTotal Organic Halogens
SW9020B TOX (Organic Halogen) "As Received"
ND
The following Analytical Methods were performed:
1
Method Description
SW846 9020B
Analyst Comments
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 13
Page 39 of 49
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: January 4, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Halogen Analysis
16277041449ug/L 12/29/16JP110.0 1
Mr. Kevin GodwinContact:
Pace Analytical Services, Inc.Company :
9800 Kincey Avenue
Huntersville, North Carolina 28078
Address :
Routine Analytical - GodwinProject:
413133002
Water
19-DEC-16 10:55
21-DEC-16
MW-B PACE00212Project:
PACE001Client ID:
Client
Sample ID:
Receive Date:
Suite 100
Client Sample ID:
Matrix:
Collect Date:
Collector:
3.33 1JTotal Organic Halogens
SW9020B TOX (Organic Halogen) "As Received"
5.78
The following Analytical Methods were performed:
1
Method Description
SW846 9020B
Analyst Comments
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 13
Page 40 of 49
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: January 4, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Halogen Analysis
16277041558ug/L 12/29/16JP110.0 1
Mr. Kevin GodwinContact:
Pace Analytical Services, Inc.Company :
9800 Kincey Avenue
Huntersville, North Carolina 28078
Address :
Routine Analytical - GodwinProject:
413133003
Water
19-DEC-16 14:30
21-DEC-16
MW-C PACE00212Project:
PACE001Client ID:
Client
Sample ID:
Receive Date:
Suite 100
Client Sample ID:
Matrix:
Collect Date:
Collector:
3.33 1JTotal Organic Halogens
SW9020B TOX (Organic Halogen) "As Received"
7.96
The following Analytical Methods were performed:
1
Method Description
SW846 9020B
Analyst Comments
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 13
Page 41 of 49
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: January 4, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Halogen Analysis
16277041639ug/L 12/29/16JP110.0 1
Mr. Kevin GodwinContact:
Pace Analytical Services, Inc.Company :
9800 Kincey Avenue
Huntersville, North Carolina 28078
Address :
Routine Analytical - GodwinProject:
413133004
Water
19-DEC-16 15:50
21-DEC-16
MW-D PACE00212Project:
PACE001Client ID:
Client
Sample ID:
Receive Date:
Suite 100
Client Sample ID:
Matrix:
Collect Date:
Collector:
3.33 1Total Organic Halogens
SW9020B TOX (Organic Halogen) "As Received"
23.7
The following Analytical Methods were performed:
1
Method Description
SW846 9020B
Analyst Comments
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 13
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Halogen Analysis
1627704Batch
Total Organic Halogens
Total Organic Halogens
Total Organic Halogens
Total Organic Halogens
Parmname
Mr. Kevin GodwinContact:
Pace Analytical Services, Inc.
9800 Kincey Avenue
Huntersville, North Carolina
January 4, 2017Report Date:
Units
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
JP1 12/29/16 12:55
12/29/16 08:25
12/29/16 07:57
12/29/16 14:09
QC
4.40
103
ND
103
NOM Sample
ND
ND
Range
(75%-118%)
(45%-174%)
Qual
J
U
QC1203698788 413133001
QC1203698787
QC1203698786
QC1203698789 413133001
The Qualifiers in this report are defined as follows:
200
REC%
103
99.9
100
100
DUP
LCS
MB
PS
413133Workorder:
Suite 100
<
>
B
E
H
J
N/A
N1
ND
NJ
Q
R
R
U
X
Z
^
d
e
Result is less than value reported
Result is greater than value reported
The target analyte was detected in the associated blank.
General Chemistry--Concentration of the target analyte exceeds the instrument calibration range
Analytical holding time was exceeded
Value is estimated
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Per section 9.3.4.1 of Method 1664 Revision B, due to matrix spike recovery issues, this result may not be reported or used for regulatory compliance
purposes.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Paint Filter Test--Particulates passed through the filter, however no free liquids were observed.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
5-day BOD--The 2:1 depletion requirement was not met for this sample
5-day BOD--Test replicates show more than 30% difference between high and low values. The data is qualified per the method and can be used for
reporting purposes
U
U
RPD%
Notes:
Page 1 of 2
Page 7 of 13
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 2 of 2
Units Anlst Date TimeQCNOMSampleRangeQualREC%
413133Workorder:
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 8 of 13
Page 44 of 49
General Chemistry
Technical Case Narrative
Pace Analytical Services Inc. (PACE)
SDG #: 92323984
Work Order #: 413133

Product: Total Organic Halogens (TOX)
Analytical Method: SW846 9020B
Analytical Procedure: GL-GC-E-007 REV# 14
Analytical Batch: 1627704
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
413133001 MW-A
413133002 MW-B
413133003 MW-C
413133004 MW-D
1203698786 Method Blank (MB)
1203698787 Laboratory Control Sample (LCS)
1203698788 413133001(MW-A) Sample Duplicate (DUP)
1203698789 413133001(MW-A) Post Spike (PS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Sample Re-analysis
Samples were re-analyzed due to CCV failure. The reanalysis data with passing instrument QC was reported.

Miscellaneous Information

Additional Comments
A pair of nitrate wash blanks is analyzed at the start of the batch. Although they are designated as ICB, they are
performed for calculating purposes only. The value of the nitrate wash blanks are averaged and subtracted from
all samples. Neither of these values should exceed 0.6 ug Cl. The PQL limit typically applied to ICB results does
not apply in this application, since the results are used only to determine background concentrations and are
subtracted from all calculated results.

Breakthrough effect
The breakthrough effect was observed and confirmed for the following sample: 413133004 (MW-D).
Breakthrough effect: If the value for a sample is greater than the reporting limit (10 ug/L), the result for the
second slug should not be greater than 25% of the combined value of the first and second slug. Results which do
not meet these criteria are designated with a "Fail" comment in the Breakthrough effect column on the Logbook
page; however, the "fail" designation is not applicable for samples with a result of less than 10 ug/L.

Certification Statement
Page 9 of 13
Page 45 of 49

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 10 of 13
Page 46 of 49
Page 11 of 13
Page 47 of 49
Page 12 of 13
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA170010
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-21
VT87156
460202
C780
997404
List of current GEL Certifications as of 04 January 2017
Page 13 of 13
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Water Quality Monitoring Report
2016 Annual Sampling Event

ATTACHMENT 4
Relevant Documentation and Correspondence