7302_DukeRoxboro_Nov2016_2ndSemiAnnual_DIN27656_20170227

SEMIANNUAL GROUNDWATER MONITORING
REPORT
NOVEMBER 2016 SAMPLING EVENT
ROXBORO STEAM ELECTRIC PLANT
INDUSTRIAL WASTE LANDFILL
PERMIT NO. 7302
1700 DUNNAWAY ROAD
SEMORA, NORTH CAROLINA

FEBRUARY 2017
PREPARED FOR

DUKE ENERGY PROGRESS, LLC
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
Duke Energy Progress, LLC SynTerra
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TABLE OF CONTENTS
SECTION PAGE
1.0 BACKGROUND............................................................................................................... 1
2.0 METHODS ........................................................................................................................ 3
2.1 Sampling and Analysis Methods ............................................................................... 3
2.2 Statement of Work ....................................................................................................... 3
3.0 RESULTS ........................................................................................................................... 5
3.1 Site Groundwater Flow ............................................................................................... 5
3.2 Analytical Results ........................................................................................................ 5
4.0 REFERENCES ................................................................................................................... 6

LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
Figure 3 Generalized Groundwater Surface Contours

LIST OF TABLES
Table 1 Well Construction Information
Table 2 Groundwater Flow Velocities
Table 3 Field Data Parameters
Table 4 Groundwater Field and Analytical Results
Table 5 Field and Analytical Results that Equal or Exceed 15A NCAC 2L
Groundwater Quality Standards
Table 6 Leachate Field and Analytical Results

LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain-of-Custody Forms
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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1.0 BACKGROUND
Duke Energy Progress, LLC. (DEP) owns and operates the Roxboro Steam Electric Plant
(Roxboro Plant, Plant or Site), situated on approximately 6,095 acres, addressed at 1700
Dunnaway Road in Semora, Person County, North Carolina. A Site Location Map is
included as Figure 1. The Roxboro Plant began operations in the 1960s and continued
to add capacity through the 1980s. Currently, the Plant operates four coal-fired units.
Coal combustion residuals (CCRs) have historically been managed at the Plant’s on-site
ash basins: the semi-active East Ash Basin (EAB) (operated from the mid-1960s to
present) and the active West Ash Basin (WAB) (operated from the early 1970s to
present). An unlined landfill was constructed on top of the semi-active East Ash Basin
in the late 1980s for the placement of dry fly ash (DFA). A lined landfill (Roxboro
Industrial Waste Landfill, Permit #7302-INDUS-2002) was constructed over the unlined
landfill in phases and began operation in 2004 (Figure 2).
The Roxboro Industrial Waste Landfill is permitted to receive coal combustion by-
products (CCBs) and incidental amounts of other wastes generated at the Roxboro
Steam Electric Plant and other Duke Energy plants. Over 90 percent of the CCBs
managed at the Roxboro Industrial Waste Landfill consist of fly ash, bottom ash, and
off-spec flue gas desulfurization (FGD) residue (gypsum). Other wastes include plant
sump sludges from cleanouts, coal pile runoff, pond sludge, coal mill rejects, gypsum
settling pond and flush pond sludge cleanout, cooling tower debris from cleanouts,
abrasive blast media, and leachate from the landfill site.
Phases 1-5 of the Roxboro landfill were constructed with an engineered liner system
and are contained within an area of approximately 70.4 acres. Phase 6 was constructed
with a double engineered liner system and is contained in an area of approximately 23.4
acres. Phase 1 initial waste placement began in 2004. Waste placement is currently
occurring in Phase 6.
Groundwater sampling is performed on a semi-annual basis. The sampling includes
measurement of groundwater field parameters and water levels as well as collection of
groundwater samples from six groundwater monitoring wells. Water levels are also
measured in two piezometers, and leachate samples are collected at six locations. As
described in the Water Quality Monitoring Plan (WQMP) (Attachment 6) contained in
the Permit to Construct Application, the monitoring system at the landfill consists of the
following:

Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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Monitoring Wells: GMW-6
GMW-7
GMW-8
GMW-9
GMW-10
GMW-11

Piezometers: PZ-12
PZ-14

Leachate Sample Locations:

LP-1
LP-2
LP-3
LP-4
LP-5
LP-6

The sampling locations are depicted on Figure 2. A summary of monitoring well
construction information is presented in Table 1. According to the Water Quality
Monitoring Plan, most of the groundwater monitoring system was in service in 2002
with the exceptions of PZ-14 which was installed in December 2009, and GMW-7 and
GMW-11 which were installed in 2010 and 2011, respectively, as replacement wells.
Monitoring well GMW-9 is identified as the upgradient background well in the Water
Quality Monitoring Plan.
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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2.0 METHODS
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by SynTerra
Corporation (SynTerra) personnel (SynTerra Field Certification #5591) according to the
North Carolina Solid Waste Management Guidelines. Copies of the field sampling
forms are included in Appendix A. The parameters and constituents reported were
selected by Duke Energy and the NCDEQ Division of Solid Waste and were analyzed
by Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248).
The laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater and leachate samples were analyzed for the following constituents:
Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using U.S. Environmental Protection Agency (EPA) Method 200.7
Arsenic, cadmium, lead, thallium, and selenium using EPA Method 200.8
Chloride, fluoride, nitrate (as nitrogen), and sulfate using EPA Method 300.0
Mercury using EPA Method 245.1
Total dissolved solids using Standard Method (SM) 2540C
Total organic carbon, biochemical oxygen demand, and chemical oxygen demand were
historically sampled up until April 2015; these constituents are not currently required to
be analyzed in the WQMP and were not analyzed for during this sampling event.
2.2 Statement of Work
SynTerra completed the following tasks:
Conducted groundwater and leachate sampling at Roxboro landfill monitoring
wells, shipped samples to Duke Energy Laboratory, and submitted all field
data to Duke Energy.
Received November 2016 field sampling information (compiled by Duke
Energy and redistributed to SynTerra) for monitoring wells GMW-6, GMW-7,
GMW-8, GMW-9, GMW-10, and GMW-11. Depth to groundwater
measurements were also received for piezometers PZ-12 and PZ-14. Leachate
sample data was included for locations LP-1, LP-2, LP-3, LP-4, LP-5, and LP-6.
Groundwater and leachate samples were collected on November 1 – 2, 2016
and November 11, 2016. Depth to groundwater in monitoring wells and
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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piezometers was measured on October 31, 2016; SynTerra received the data on
November 21, 2016 and December 6, 2016.
Reviewed the laboratory analytical results for the samples listed above. The
Electronic Data Deliverable (EDD) provided by Duke Energy was adapted to
conform to the format requirements of the NCDEQ EDD template. Copies of
the original EDDs are retained in SynTerra's files.
Developed generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy.
Calculated groundwater flow velocities based on groundwater elevations on
wells perpendicular to groundwater flow.
Prepared and submitted this Semiannual Groundwater Monitoring Report to
Duke Energy.
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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3.0 RESULTS
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for
the site are shown on Figure 3. These contours were developed using the groundwater
elevations measured on the date of depth to water collection, October 31, 2016. The
contours are supplemented with water level measurements of wells utilized in the Coal
Ash Management Act (CAMA) program, also measured on October 31, 2016.
Calculated flow velocities are presented in Table 2.
Groundwater at the landfill flows north-northwest from areas of higher topography
located along the southern portion of the landfill.
3.2 Analytical Results
A summary of the field data is presented in Table 3. The field and analytical results of
groundwater samples collected from the monitoring wells are presented in Table 4.
The analytical results for these samples are compared to the groundwater standards
established in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations that attain
or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the field
and analytical results that attain or exceed the 2L Standards and a preliminary analysis
of the cause and significance of the exceedances are presented in Table 5.
The field and analytical results for leachate sampling are summarized in Table 6.
Concentrations with values that are equal to or greater than Solid Waste Section Limits
(SWSLs) are noted in Table 4 and Table 6 by gray shaded cells.
Select samples were diluted, as is normal laboratory practice, to bring samples within
the calibrated range of analysis. Specifics regarding the samples that were diluted,
including the dilution factor, are reported in the EDD and in the laboratory analytical
report. The laboratory analytical report is included as Appendix B.
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
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4.0 REFERENCES
BlackRock Engineers, Inc., Attachment 6,- Monitoring Plan, Permit to Construct Application,
Duke Energy Progress, Roxboro Lined Ash Monofill – Phase – 6, SW Permit No. 73-02.
August 2013.
Morris, Donald Arthur, and Arnold Ivan Johnson. Summary of hydrologic and physical
properties of rock and soil materials, as analyzed by the hydrologic laboratory of the US
Geological Survey, 1967, 1948-60. No. 1839-D. US Gov.
SynTerra. Comprehensive Site Assessment Report. September 2, 2015
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
Duke Energy Progress, LLC SynTerra

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FIGURES

7302-INDUSLANDFILL
HYCORESERVOIR
ROXBORO STEAMELECTRIC PLANT
SHORE RDSTATE RD 1316
DUNNAWAY RD
S
T
A
T
E

R
D

1
3
7
7
STATE HW
Y

5
7
SEMO
R
A

R
D
STAT
E

R
D

1
3
3
6
MCG
H
E
E
S
MILL

R
D
SCALE (FEET)1,000 0 1,000 2,000
PROJECT MANAGER: C. EADY
DRAWN BY: A. FEIGL
DATE: 02/15/2017
DATE: 02/15/2017
CHECKED BY: A. LEFITZ
P:\DUKE ENERGY PROGRESS.1026\00 GIS BASE DATA\ROXBORO\MAP_DOCS\STATE_COMPLIANCE\20160126\ROXBORO - FIGURE 1 - SITE_LOCATION_MAP.MXD
FIGURE 1SITE LOCATION MAPROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
LEGEND
APPROXIMATE 7302-INDUS LANDFILL LIMIT OF WASTE
&<
&<
&<
&<
&<
&<
#
#
#
#
&<
&<
##
7302-INDUSLANDFILL
HYCO LAKE(Approx. Pond Elev = 410')
GYPSUM STORAGE AREA
GMW-06
GMW-07
GMW-08 GMW-09
GMW-10
GMW-11
LP-01
LP-02
LP-03
LP-04
PZ-12
PZ-14
LP-05 LP-06
SCALE (FEET)300 0 300 600
PROJECT MANAGER: C. EADY
DRAWN BY: A. FEIGL
DATE: 02/15/2017
DATE: 02/15/2017
CHECKED BY: A. LEFITZ
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FIGURE 2SAMPLE LOCATION MAPROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
&<GROUNDWATER MONITORING WELL
&<PIEZOMETER (WATER ELEVATION ONLY)
#LEACHATE SAMPLING LOCATION
APPROXIMATE 7302-INDUS LANDFILLLIMIT OF WASTE
APPROXIMATE LINED LANDFILL LIMIT OF WASTE
APPROXIMATE UNLINED LANDFILL LIMIT OF WASTE
CCR SURFACE IMPOUNDMENT COMPLIANCEBOUNDARY
CCR SURFACE IMPOUNDMENT
125' SOLID WASTE LANDFILL REVIEW BOUNDARY
250' SOLID WASTE LANDFILLCOMPLIANCE BOUNDARY
LEGEND
NOTES
1) 10ft CONTOUR INTERVALS FROM NCDOT LIDAR DATED 2007https://connect.ncdot.gov/resources/gis/pages/cont-elev_v2.aspx
2) CONTOUR LINES ARE USED FOR REPRESENTATIVE PURPOSESONLY AND ARE NOT TO BE USED FOR DESIGN OR CONSTRUCTIONPURPOSES.
3) 2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDA NRCSGEOSPATIAL DATA GATEWAY(https://gdg.sc.egov.usda.gov/GDGOrder.aspx).
##
#
#
#
#
&<
&<
&<
&<
&<
&<
&<
&<
7302-INDUSLANDFILL
HYCO LAKE(Approx. Pond Elev = 410')
GYPSUM STORAGE AREA
GMW-06(456.82)
GMW-07(471.82)
GMW-08(483.14)GMW-09(514.37)
GMW-10(465.34)GMW-11(479.33)
PZ-12(470.34)
PZ-14(455.12)LP-01
LP-02
LP-03
LP-04
LP-01
LP-02
LP-03
LP-04
LP-05 LP-06
SCALE (FEET)300 0 300 600
PROJECT MANAGER: C. EADY
DRAWN BY: A. FEIGL
DATE: 02/15/2017
DATE: 02/15/2017
CHECKED BY: A. LEFITZ
P:\DUKE ENERGY PROGRESS.1026\00 GIS BASE DATA\ROXBORO\MAP_DOCS\STATE_COMPLIANCE\20160126\ROXBORO - FIGURE 3 - GROUNDWATER CONTOURS.MXD
FIGURE 3GENERALIZED GROUNDWATERSURFACE CONTOURSROXBORO STEAM ELECTRIC PLANTINDUSTRIAL WASTE LANDFILLPERMIT NO. 7302
"
148 RIVER STREET, SUITE 220GREENVILLE, SC 29601864-421-9999
&<GROUNDWATER MONITORING WELL
&<PIEZOMETER (WATER ELEVATION ONLY)
#LEACHATE SAMPLING LOCATION
WATER ELEVATION (OCT. 2016)APPROXIMATE 7302-INDUS LANDFILL LIMIT OF WASTE
GROUNDWATER SURFACE CONTOURGENERAL GROUNDWATER FLOW DIRECTION
APPROXIMATE LINED LANDFILL LIMIT OF WASTE
APPROXIMATE UNLINED LANDFILL LIMIT OF WASTECCR SURFACE IMPOUNDMENT COMPLIANCE BOUNDARY
CCR SURFACE IMPOUNDMENT125' SOLID WASTE LANDFILL REVIEW BOUNDARY
250' SOLID WASTE LANDFILL COMPLIANCE BOUNDARY
LEGEND
420 440 460
4
8
0
50
0
520
52050
0
480
460
440
420
NOTES
1) WATER LEVEL MEASUREMENT TAKEN OCTOBER 31, 2016.
2) 10ft CONTOUR INTERVALS FROM NCDOT LIDAR DATED 2007https://connect.ncdot.gov/resources/gis/pages/cont-elev_v2.aspx
3) CONTOUR LINES ARE USED FOR REPRESENTATIVE PURPOSES ONLYAND ARE NOT TO BE USED FOR DESIGN OR CONSTRUCTIONPURPOSES.
4) 2014 AERIAL ORTHOPHOTOGRAPHY OBTAINED FROM USDA NRCSGEOSPATIAL DATA GATEWAY(https://gdg.sc.egov.usda.gov/GDGOrder.aspx).
(471.82)
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
Duke Energy Progress, LLC SynTerra

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TABLES
TABLE 1
WELL CONSTRUCTION INFORMATION
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
Latitude Longitude
GMW-6 3/14/2002 36.4812210 -79.0648371 478.36 479.99 1.47 46.47 31.47 31.47 - 46.47 Saprolite 2 PVC
GMW-7 6/28/2010 36.4763616 -79.0646926 499.60 497.21 3.38 57.38 42.38 42.38 - 57.38 Bedrock 2 PVC
GMW-8 3/13/2002 36.4747493 -79.0610383 528.55 525.90 3.88 66.88 56.88 56.88 - 66.88 Bedrock 2 PVC
GMW-9 3/13/2002 36.4744875 -79.0578763 536.52 533.73 3.73 48.73 33.73 33.73 - 48.73 Bedrock 2 PVC
GMW-10 9/25/2002 36.4818523 -79.0634291 494.41 455.64 3.55 48.55 33.55 33.55 - 48.55 Bedrock 2 PVC
GMW-11 2/28/2011 36.4817950 -79.0622715 496.55 493.19 4.04 49.04 34.04 34.04 - 49.04 Bedrock 2 PVC
PZ-12 5/6/2003 36.4779790 -79.0575623 514.41 512.68 2.62 55.95 35.95 35.95 - 55.95 Fly Ash 2 PVC
PZ-14 Not Available 36.4804433 -79.0670853 471.74 469.75 3.03 22.70 12.70 12.70 - 22.70 Not Available 2 PVC
1. TOC indicates top of casing.
2. ft. indicates feet.
3. in. indicates inches nominal diameter.
4. PVC indicates polyvinyl chloride.
5. Horizontal datum NAD27.
6. Elevations based on NAVD 29.
Prepared by: ARL Checked by: CDE
Notes:
Total Well
Depth
below TOC
(ft.)
Coordinates
Well ID
Well
Installation
Date
Well TOC
Elevation
(ft.)
Ground
Surface
Elevation
(ft.)
Well Stick-up
Height Above
Ground Surface
(ft.)
Well
Diameter
(in.)
Casing
Type
Depth to Top
of Screen
from TOC
(ft.)
Screened
Interval
below TOC
(ft.)
Geology of
Screened
Interval
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TABLE 2
GROUNDWATER FLOW VELOCITIES
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
GMW-9 to GMW-8 514.37 483.14 934 0.033 1.04 0.26 0.134
GMW-9 to GMW-6*514.37 455.99 3193 0.018 2.10 0.26 0.148
GMW-11 to GMW-10 479.33 465.34 361 0.039 1.04 0.26 0.155
Notes:
Prepared by: ARL Checked by: CDE
Hydraulic
Conductivity
(ft/day)
Effective
Porosity
(%/100)
Groundwater
Velocity
(ft/day)
Well IDs
Upgradient
Groundwater
Elevation (ft)
Downgradient
Groundwater
Elevation (ft)
Linear Distance
Between
Elevations (ft)
Hydraulic
Gradient
(ft/ft)
1. Monitoring wells are not listed where insufficient groundwater contour information is unavailable to calculate velocity.
2. Hydraulic gradients, effective porosties, and groundwater velocities are approximate.
3. Hydraulic conductivites presented for all wells are adapted from geomeans of various wells in the same aquifers. These values are published in SynTerra's
Comprehensive Site Assessment for Roxboro (CSA Report, Roxboro, September, 2015).
4. Effective porosities for all wells adapted from Morris and Johnson, 1967.
* GMW-9 is screened in bedrock and GMW-6 is screened in saprolite, therefore hydraulic conductivities and porosities are a combination of both aquifers
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TABLE 3
FIELD DATA PARAMETERS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
11/1/2006 GMW-6 Clear None LF 100 3.93 1.75 No 17 1,490 6.6 3.8 -102 0.68 455.99 22.37
11/2/2016 GMW-7 Clear None LF 130 4.82 0.75 No 17 1,223 6.8 5.6 -42 1.95 471.82 27.78
11/2/2016 GMW-8 Clear None LF 100 3.50 2 No 19 2,169 6.7 8.9 -64 0.78 483.14 45.41
11/2/2016 GMW-9 Clear None LF 190 4.33 2.5 No 16 159 6.5 3.8 11 8.1 514.37 22.15
11/1/2016 GMW-10 Clear None LF 210 3.18 1 No 16 255 6.2 2.8 -22 3.22 465.34 29.07
11/1/2016 GMW-11 Clear None LF 160 5.19 1 No 16 1,270 6.5 8.2 -77 0.81 479.33 17.22
11/1/2016 LP-1 Not Noted Not Noted N/A N/A N/A N/A N/A 18 4,724 7.7 0.8 167 4.63 N/A N/A
11/1/2016 LP-2 Not Noted Not Noted N/A N/A N/A N/A N/A 19 4,840 7.9 0.9 99 6.64 N/A N/A
11/1/2016 LP-3 Not Noted Not Noted N/A N/A N/A N/A N/A 19 5,449 7.6 1.7 156 4.35 N/A N/A
11/1/2016 LP-4 Not Noted Not Noted N/A N/A N/A N/A N/A 15 6,360 7.3 1.2 316 7.3 N/A N/A
11/11/2016 LP-5 Not Noted Not Noted N/A N/A N/A N/A N/A 21 6,660 6.4 0.4 103 1.79 N/A N/A
11/11/2016 LP-6 Not Noted Not Noted N/A N/A N/A N/A N/A 20 6,220 7.4 1.0 82 5.77 N/A N/A
Notes:
10. N/A = Not Applicable
3. EVAC indicates wheter the water level in the well was drawn down to the level of the
pump during purging.
4. µmhos/cm = micromhos per centimeter
5. mL/min = milliliters per minute
6. SU = Standard Units
7. NTU = Nephelometric Turbidity Units
8. mV-NHE = millivolts
9. ug/L = micrograms per liter
ORP
(mV)
DO
(ug/L)
Average
Pump Rate
(mL/min)
Well
Volume
(gallons)
EVAC
Volume
(gallons)
EVAC
(yes/no)
Temp
(deg C)
Groundwater
Elevation (ft.)
Depth to
Water
below TOC
(ft.)
Prepared by: ARL Checked by: CDE
11. Depth to water measurements taken on October 31, 2016.
Specific
Conductance
(µmho/cm)
pH
(SU)
Turbidity
(NTU)
1. Purge Methods; LF=Low Flow, LF(M)=Low Flow Modified, CP=Conventional Purge (3-5
well volumes), NP=No Purge (HydraSleeve), EOP = Equipment Only Purge. Average pump rate applicable to LF and LF(M) purging only.
2. Field sampling performed by SynTerra Corporation personnel.
Appearance Odor Purge
Method
Sample
Date Sample ID
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TABLE 4
GROUNDWATER FIELD AND ANALYTICAL RESULTS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
7302-
GMW-6
7302-
GMW-7
7302-
GMW-8
7302-
GMW-9
7302-
GMW-10
7302-
GMW-11
Field pH S.U.6.6 6.8 6.7 6.5 6.2 6.5 -NE 6.5-8.5 6.5-8.5*
Specific Conductance µƱ/cm 1490 1223 2169 159 255 1270 -NE NE NE
Temperature °C 16.6 17 19 16 16 16 -NE NE NE
Arsenic µg/L < 1 < 1 < 1 < 1 < 1 < 1 0.078 10 10 10
Barium µg/L 30 173 57 45 84 71 0.1 100 700 2,000
Boron µg/L 2,500 1,480 4,820 < 50 100 4,240 3.3 NE 700 NE
Cadmium µg/L < 1 < 1 < 1 < 1 < 1 < 1 0.101 1 2 5
Chloride µg/L 57,000 160,000 230,000 3,800 19,000 27,000 22 NE 250,000 250,000*
Chromium µg/L < 5 < 5 12 < 5 < 5 < 5 0.5 10 10 100
Copper µg/L < 5 < 5 < 5 < 5 < 5 < 5 1 10 1,000 1,300
Fluoride µg/L < 500 < 1,000 < 1,000 110 130 < 500 17 2,000 2,000 4,000
Iron µg/L 406 25 150 92 43 263 1.3 300 300 300*
Lead µg/L < 1 < 1 < 1 < 1 < 1 < 1 0.065 10 15 15
Manganese µg/L 22 < 5 66 < 5 6 6 0.2 50 50 50*
Mercury µg/L < 0.05 < 0.05 0.19 < 0.05 < 0.05 < 0.05 0.006 0.2 1 2
Nickel µg/L < 5 < 5 7 < 5 < 5 < 5 0.5 50 100 NE
Nitrate (as Nitrogen)µg*N/L 700 810 250 380 530 610 5.4 10,000 10,000 10,000
Selenium µg/L 81.6 10.3 < 1 < 1 1.11 153 0.092 10 20 50
Silver µg/L < 5 < 5 < 5 < 5 < 5 < 5 0.7 10 20 100*
Sulfate µg/L 550,000 240,000 670,000 30,000 27,000 580,000 18 250,000 250,000 250,000*
Total Dissolved Solids µg/L 1,200,000 860,000 1,600,000 140,000 200,000 1,000,000 16,700 NE 500,000 500,000*
Thallium µg/L <0.2 < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.133 5.5 0.2**2
Zinc µg/L < 5 < 5 <5 < 5 5 < 5 2.6 10 1,000 5,000*
Notes:Prepared By: ARL Checked By: CDE
Bold Concentrations are equal to or greater than the 15A NCAC 2L Standard (for pH bold indicates a measurement outside of the range).
Samples collected by SynTerra Corporation on November 1-2, 2016.
MDL = the laboratory Method Detection Limit. The MDL values presented are for samples not diluted by the laboratory during analysis.
SWSL = the Solid Waste Section Limit. NCDEQ defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2013 (Appendix I amended April 1, 2013).
MCL = Federal Maximum Contaminant Level as found in 40 CFR, Subpart G § 141.62.
7302 = Industrial Waste Landfill - Permit No. 7302
S.U. = Standard Units
µƱ/cm = micromhos per centimeter
µg/L = micrograms per liter
A blank cell means there is no relevant information.
* Concentration listed is a secondary maximum contaminant level (SMCL). SMCLs are established by EPA in the National Secondary Drinking Water Regulations as found in 40 CFR §143.3.
** Interim Maximum Allowable Concentration (IMAC).
Parameter Units
NE = Not Established
MDL SWSL 15A NCAC 2L
Standard
Federal
MCL
All concentrations are presented in µg/L.
SWS ID = the Solid Waste Section Identification Number.
Monitoring Wells
- Concentrations are equal to or greater than the SWSL.
\\synterracorp.com\Data\Proj\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and Monitoring\November 2016 Report\Table 4 Groundwater Field and Analytical Results_NovTable 4 Groundwater Field and Analytical Resul
TABLE 5
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED 15A NCAC 2L GROUNDWATER QUALITY STANDARDS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
Parameter Sample ID Result Units
15A NCAC
2L
Standard Historical Concentrations Cause and Significance
GMW-9 6.5 5.4 - 6.9 pH consistent with historical readings.
GMW-10 6.2 5.5 - 7.2 pH consistent with historical readings.
GMW-11 6.5 6.0-7.7 pH consistent with historical readings.
GMW-6 2,500 736 - 3,920 Boron concentration consistent with historical readings.
GMW-7 1,480 < 50 - 1,560 Boron concentration consistent with historical readings.
GMW-8 4,820 1,680 - 5,350 Boron concentration consistent with historical readings.
GMW-11 4,240 388 - 4,240 Boron concentration highest measured over the period of monitoring.
Chromium GMW-8 12 µg/L 10 2 - 23.8 Chromium concentration within range of historical readings but over the detection limit (5 ug/L) for the first time in the last eight
sampling events.
Iron GMW-6 406 µg/L 300 <10 - 59,100 Iron concentration within range of historical readings but over the detection limit (10 ug/L) for the first time in the last five
sampling events.
Manganese GMW-8 66 µg/L 50 25.8 - 449 Manganese concentration consistent with historical readings.
GMW-6 81.6 56.6 - 105 Selenium concentration consistent with historical readings.
GMW-11 153 5.1 - 264 Selenium concentration consistent with historical readings.
GMW-6 550,000 < 5,000 - 1,108,000 Sulfate concentration consistent with historical readings.
GMW-8 670,000 231,000 - 820,000 Sulfate concentration consistent with historical readings.
GMW-11 580,000 72,400 - 995,000 Sulfate concentration within range of historical readings.
GMW-6 1,200,000 1,100,000 - 2,050,000 Total Dissolved Solids concentration consistent with historical readings.
GMW-7 860,000 330,000 - 920,000 Total Dissolved Solids concentration consistent with historical readings.
GMW-8 1,600,000 975,000 - 2,100,000 Total Dissolved Solids concentration consistent with historical readings.
GMW-11 1,000,000 378,000 - 1,660,000 Total Dissolved Solids concentration consistent with historical readings.
Prepared by: ARL Checked by: CDE
Notes:
1. 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013.
2. Analytical results obtained from Electonic Data Deliverable (EDD) provided by Duke Energy on November 21, 2016
3. µg/L indicates micrograms per liter.
4. SU indicates Standard Units.
5. Historical concentrations based on data in Duke Energy analytical results database.
6. Field sampling performed by SynTerra Corporation, Sample Date: November 1-2, 2016.
Sulfate µg/L 250,000
Total Dissolved
Solids µg/L 500,000
Selenium µg/L 20
SU 6.5-8.5Field pH
Boron µg/L 700
TABLE 6
LEACHATE FIELD AND ANALYTICAL RESULTS
ROXBORO INDUSTRIAL WASTE LANDFILL - PERMIT NO. 7302
ROXBORO STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, SEMORA, NC
7302-
LP-1
7302-
LP-2
7302
LP-3
7302-
LP-4
7302-
LP-5
7302-
LP-6
Field pH 320 S.U.5591 7.7 7.9 7.6 7.7 6.4 7.4 -NE
Specific Conductance 323 µƱ/cm 5591 4,724 4,840 5,449 6,360 6,660 6,220 -NE
Temperature 325 °C 5591 18.2 18.8 18.7 15.3 21.2 19.8 -NEArsenic14µg/L 248 10.7 3.13 3.53 < 1 < 1 < 1 0.078 10
Barium 15 µg/L 248 36 31 33 68 61 67 0.1 100Boron428µg/L 248 51,400 53,100 49,700 22,300 19,200 30,100 3.3 NECadmium34µg/L 248 2.39 2.84 3.11 2.19 1.44 2.30 0.101 1Chloride455µg/L 248 52,000 160,000 410,000 760,000 760,000 960,000 22 NEChromium 51 µg/L 248 < 5 < 5 < 5 < 5 15 < 5 0.5 10
Copper 54 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 1 10Fluoride312µg/L 248 < 10,000 < 10,000 < 10,000 < 10,000 < 5,000 < 5,000 17 2,000
Iron 340 µg/L 248 183 875 751 45 298 837 1.3 300Lead131µg/L 248 < 1 < 1 < 1 < 1 < 1 < 1 0.065 10
Manganese 342 µg/L 248 1,670 1,290 1,310 9 1,900 1,680 0.2 50Mercury132µg/L 248 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.006 0.2Nickel152µg/L 248 111 93 31 8 10 18 0.5 50Nitrate (as Nitrogen)303 µg/L 248 14,000 20,000 12,000 1,800 1,600 380 5.4 10,000Selenium183µg/L 248 1030 754 608 67.9 44 87.8 0.092 10
Silver 184 µg/L 248 < 5 < 5 < 5 < 5 < 5 < 5 0.7 10Sulfate315µg/L 248 2,300,000 2,300,000 2,300,000 2,200,000 2,400,000 2,500,000 18 250,000
Thallium 194 µg/L 248 1.010 0.372 0.529 < 0.2 < 0.2 < 0.2 0.133 5.5Total Dissolved Solids 311 µg/L 248 4,100,000 4,000,000 4,400,000 4,800,000 49,000,000 50,000,000 16,700 NEZinc 213 µg/L 248 19 27 29 < 5 8 11 2.6 10
Notes:
Samples collected by SynTerra Corporation on November 1 and 11, 2016
MDL = laboratory Method Detection Limit.
SWSL = the Solid Waste Section Limit. NCDENR defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
7302 = Roxboro Industrial Waste Landfill - Permit No. 7302
S.U. = Standard Units
µƱ/cm = micromhos per centimeter
- Concentrations are equal to or greater than the SWSL.
SWSL
All concentrations are presented in µg/L.
SWS ID = the Solid Waste Section Identification Number.
NE = Not Established
Parameter SWS ID Units Certificate Code MDL
Prepared by: WJW Checked by: CDE
Sample Location
\\synterracorp.com\Data\Proj\Duke Energy Progress.1026\07.ROXBORO PLANT\17.April 2016 Landfill Solid Waste GW Compliance and Monitoring\November 2016 Report\Table 6 Leachate Field and Analytical ResultsTable 6 Leachate Field and Analytical
Resultstable
Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
Duke Energy Progress, LLC SynTerra

P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17. 2016 Landfill Solid Waste GW Compliance and
Monitoring\November 2016 Report\Nov_Solid_Waste_Report.docx
APPENDIX A
FIELD SAMPLING FORMS

Roxboro Semiannual Groundwater Monitoring Report – November 2016 Sampling Event February 2017
Duke Energy Progress, LLC SynTerra

P:\Duke Energy Progress.1026\07.ROXBORO PLANT\17. 2016 Landfill Solid Waste GW Compliance and
Monitoring\November 2016 Report\Nov_Solid_Waste_Report.docx
APPENDIX B
LABORATORY REPORT AND
CHAIN-OF-CUSTODY FORMS
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16100186
Project Name:ROXBORO - LFGW
Lab Contact:Anne Pridgeon
Date:11/21/2016
Customer Address:Roxboro Steam Station
Customer Name(s):John Toepfer, Tim Hunsucker
1700 Dunnaway Road
Semora,NC 27343
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 2540C: The current reported result is outside historical limits for GMW-11. Reanalysis confirmed total dissolved solids at
1122mg/L.
Metals via ICPMS: The current reported result for Selenium is outside historical limits at sample location GMW-11. Reanalysis
confirmed the initial concentration at 160ppb.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016032484 Roxboro 01-Nov-16 2:17 PM Kaitlyn Fox GMW-6
2016032485 Roxboro 02-Nov-16 12:33 PM Synterra GMW-8
2016032486 Roxboro 02-Nov-16 9:35 AM Synterra GMW-7
2016032487 Roxboro 02-Nov-16 10:10 AM Synterra GMW-9
2016032488 Roxboro 01-Nov-16 3:50 PM Kaitlyn Fox GMW-10
2016032489 Roxboro 01-Nov-16 1:26 PM Kaitlyn Fox GMW-11
2016032490 Roxboro 01-Nov-16 9:58 AM Kaitlyn Fox LP-1
2016032491 Roxboro 01-Nov-16 10:10 AM Kaitlyn Fox LP-2
2016032492 Roxboro 01-Nov-16 9:35 AM Kaitlyn Fox LP-3
2016032493 Roxboro 01-Nov-16 9:21 AM Kaitlyn Fox LP-4
2016032494 Roxboro 01-Nov-16 9:21 AM Kaitlyn Fox DUP LP-4
2016032495 Roxboro 01-Nov-16 5:38 PM Kaitlyn Fox FIELD BLANK
12 Total Samples
Duke Energy Analytical Lab Page 2 of 28
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:11/17/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab Page 3 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032484
Collection Date:01-Nov-16 2:17 PM
Site:GMW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 57 mg/L EPA 9056A 11/02/2016 21:36 GHUTCHI10100
Fluoride < 0.5 mg/L EPA 9056A 11/02/2016 21:36 GHUTCHI0.5 5
Nitrate 3.1 mg/L EPA 9056A 11/02/2016 21:36 GHUTCHI0.5 5
Nitrate as N 0.70 mg-N/L EPA 9056A 11/02/2016 21:36 GHUTCHI0.023 1
Sulfate 550 mg/L EPA 9056A 11/02/2016 21:36 GHUTCHI20200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:22 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.030 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Boron (B)2.50 mg/L SW 6010D 11/13/2016 13:12 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Iron (Fe)0.406 mg/L SW 6010D 11/13/2016 13:12 MHALL30.01 1
Manganese (Mn)0.022 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 13:12 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/05/2016 23:04 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/05/2016 23:04 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/05/2016 23:04 CWSPEN311
Selenium (Se)81.6 ug/L SW 6020B 11/05/2016 23:04 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/05/2016 23:04B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 1200 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 4 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032485
Collection Date:02-Nov-16 12:33 PM
Site:GMW-8
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 230 mg/L EPA 9056A 11/03/2016 20:58 GHUTCHI10100
Fluoride < 1 mg/L EPA 9056A 11/03/2016 20:58 GHUTCHI110
Nitrate 1.1 mg/L EPA 9056A 11/03/2016 20:58 GHUTCHI110
Nitrate as N 0.25 mg-N/L EPA 9056A 11/03/2016 20:58 GHUTCHI0.023 1
Sulfate 670 mg/L EPA 9056A 11/03/2016 20:58 GHUTCHI50500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.19 ug/L EPA 7470A 11/16/2016 13:21 DMFRANC0.1 2
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.057 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Boron (B)4.82 mg/L SW 6010D 11/13/2016 13:24 MHALL30.05 1
Chromium (Cr)0.012 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Iron (Fe)0.150 mg/L SW 6010D 11/13/2016 13:24 MHALL30.01 1
Manganese (Mn)0.066 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Nickel (Ni)0.007 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 13:24 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/05/2016 23:11 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/05/2016 23:11 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/05/2016 23:11 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/05/2016 23:11 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/05/2016 23:11B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 1600 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 5 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032486
Collection Date:02-Nov-16 9:35 AM
Site:GMW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 9056A 11/03/2016 22:07 GHUTCHI10100
Fluoride < 1 mg/L EPA 9056A 11/03/2016 22:07 GHUTCHI110
Nitrate 3.6 mg/L EPA 9056A 11/03/2016 22:07 GHUTCHI110
Nitrate as N 0.81 mg-N/L EPA 9056A 11/03/2016 22:07 GHUTCHI0.023 1
Sulfate 240 mg/L EPA 9056A 11/03/2016 22:07 GHUTCHI10100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:44 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.173 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Boron (B)1.48 mg/L SW 6010D 11/13/2016 13:28 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Iron (Fe)0.025 mg/L SW 6010D 11/13/2016 13:28 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 13:28 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 15:12 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/07/2016 15:12 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 15:12 CWSPEN311
Selenium (Se)10.3 ug/L SW 6020B 11/07/2016 15:12 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/07/2016 15:12 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 860 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 6 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032487
Collection Date:02-Nov-16 10:10 AM
Site:GMW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 3.8 mg/L EPA 9056A 11/03/2016 23:38 GHUTCHI0.1 1
Fluoride 0.11 mg/L EPA 9056A 11/03/2016 23:38 GHUTCHI0.1 1
Nitrate 1.7 mg/L EPA 9056A 11/03/2016 23:38 GHUTCHI0.1 1
Nitrate as N 0.38 mg-N/L EPA 9056A 11/03/2016 23:38 GHUTCHI0.023 1
Sulfate 30 mg/L EPA 9056A 11/03/2016 23:38 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:47 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.045 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 13:32 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Iron (Fe)0.092 mg/L SW 6010D 11/13/2016 13:32 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 13:32 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/05/2016 23:27 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/05/2016 23:27 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/05/2016 23:27 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/05/2016 23:27 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/05/2016 23:27B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 7 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032488
Collection Date:01-Nov-16 3:50 PM
Site:GMW-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 19 mg/L EPA 9056A 11/02/2016 22:22 GHUTCHI110
Fluoride 0.13 mg/L EPA 9056A 11/02/2016 22:22 GHUTCHI0.1 1
Nitrate 2.3 mg/L EPA 9056A 11/02/2016 22:22 GHUTCHI0.1 1
Nitrate as N 0.53 mg-N/L EPA 9056A 11/02/2016 22:22 GHUTCHI0.023 1
Sulfate 27 mg/L EPA 9056A 11/02/2016 22:22 GHUTCHI110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:49 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.084 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Boron (B)0.100 mg/L SW 6010D 11/13/2016 13:36 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Iron (Fe)0.043 mg/L SW 6010D 11/13/2016 13:36 MHALL30.01 1
Manganese (Mn)0.006 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
Zinc (Zn)0.005 mg/L SW 6010D 11/13/2016 13:36 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/05/2016 23:34 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/05/2016 23:34 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/05/2016 23:34 CWSPEN311
Selenium (Se)1.11 ug/L SW 6020B 11/05/2016 23:34 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/05/2016 23:34B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 8 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032489
Collection Date:01-Nov-16 1:26 PM
Site:GMW-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 27 mg/L EPA 9056A 11/02/2016 23:08 GHUTCHI550
Fluoride < 0.5 mg/L EPA 9056A 11/02/2016 23:08 GHUTCHI0.5 5
Nitrate 2.7 mg/L EPA 9056A 11/02/2016 23:08 GHUTCHI0.5 5
Nitrate as N 0.61 mg-N/L EPA 9056A 11/02/2016 23:08 GHUTCHI0.023 1
Sulfate 580 mg/L EPA 9056A 11/02/2016 23:08 GHUTCHI20200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.071 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Boron (B)4.24 mg/L SW 6010D 11/13/2016 13:40 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Iron (Fe)0.263 mg/L SW 6010D 11/13/2016 13:40 MHALL30.01 1
Manganese (Mn)0.006 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 13:40 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/05/2016 23:42 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/05/2016 23:42 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/05/2016 23:42 CWSPEN311
Selenium (Se)153 ug/L SW 6020B 11/05/2016 23:42 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/05/2016 23:42B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 1000 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Duke Energy Analytical Lab Page 9 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032490
Collection Date:01-Nov-16 9:58 AM
Site:LP-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 52 mg/L EPA 9056A 11/02/2016 23:53 GHUTCHI10100
Fluoride < 10 mg/L EPA 9056A 11/02/2016 23:53 GHUTCHI10100
Nitrate 61 mg/L EPA 9056A 11/02/2016 23:53 GHUTCHI10100
Nitrate as N 14 mg-N/L EPA 9056A 11/02/2016 23:53 GHUTCHI0.023 1
Sulfate 2300 mg/L EPA 9056A 11/02/2016 23:53 GHUTCHI1001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 13:54M2 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Boron (B)51.4 mg/L SW 6010D 11/13/2016 13:49 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Iron (Fe)0.183 mg/L SW 6010D 11/13/2016 13:49 MHALL30.01 1
Manganese (Mn)1.67 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Nickel (Ni)0.111 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
Zinc (Zn)0.019 mg/L SW 6010D 11/13/2016 13:49 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)10.7 ug/L SW 6020B 11/09/2016 14:20 CWSPEN311
Cadmium (Cd)2.39 ug/L SW 6020B 11/09/2016 14:20 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/09/2016 14:20 CWSPEN311
Selenium (Se)1030 ug/L SW 6020B 11/09/2016 14:20 CWSPEN3100100
Thallium (Tl) Low Level 1.01 ug/L SW 6020B 11/09/2016 14:20 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4100 mg/L SM2540C 11/03/2016 15:24 JASTOWE621
Duke Energy Analytical Lab Page 10 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032491
Collection Date:01-Nov-16 10:10 AM
Site:LP-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 9056A 11/03/2016 00:39 GHUTCHI10100
Fluoride < 10 mg/L EPA 9056A 11/03/2016 00:39 GHUTCHI10100
Nitrate 88 mg/L EPA 9056A 11/03/2016 00:39 GHUTCHI10100
Nitrate as N 20 mg-N/L EPA 9056A 11/03/2016 00:39 GHUTCHI0.023 1
Sulfate 2300 mg/L EPA 9056A 11/03/2016 00:39 GHUTCHI1001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 14:01 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Boron (B)53.1 mg/L SW 6010D 11/13/2016 13:53 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Iron (Fe)0.875 mg/L SW 6010D 11/13/2016 13:53 MHALL30.01 1
Manganese (Mn)1.29 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Nickel (Ni)0.093 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
Zinc (Zn)0.027 mg/L SW 6010D 11/13/2016 13:53 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)3.13 ug/L SW 6020B 11/09/2016 14:27 CWSPEN311
Cadmium (Cd)2.84 ug/L SW 6020B 11/09/2016 14:27 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/09/2016 14:27 CWSPEN311
Selenium (Se)754 ug/L SW 6020B 11/09/2016 14:27 CWSPEN3100100
Thallium (Tl) Low Level 0.372 ug/L SW 6020B 11/09/2016 14:27 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4000 mg/L SM2540C 11/03/2016 15:24 JASTOWE621
Duke Energy Analytical Lab Page 11 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032492
Collection Date:01-Nov-16 9:35 AM
Site:LP-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 410 mg/L EPA 9056A 11/03/2016 01:25 GHUTCHI10100
Fluoride < 10 mg/L EPA 9056A 11/03/2016 01:25 GHUTCHI10100
Nitrate 55 mg/L EPA 9056A 11/03/2016 01:25 GHUTCHI10100
Nitrate as N 12 mg-N/L EPA 9056A 11/03/2016 01:25 GHUTCHI0.023 1
Sulfate 2300 mg/L EPA 9056A 11/03/2016 01:25 GHUTCHI1001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 14:04 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Boron (B)49.7 mg/L SW 6010D 11/13/2016 13:58 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Iron (Fe)0.751 mg/L SW 6010D 11/13/2016 13:58 MHALL30.01 1
Manganese (Mn)1.31 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Nickel (Ni)0.031 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
Zinc (Zn)0.029 mg/L SW 6010D 11/13/2016 13:58 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)3.53 ug/L SW 6020B 11/09/2016 14:34 CWSPEN311
Cadmium (Cd)3.11 ug/L SW 6020B 11/09/2016 14:34 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/09/2016 14:34 CWSPEN311
Selenium (Se)608 ug/L SW 6020B 11/09/2016 14:34 CWSPEN3100100
Thallium (Tl) Low Level 0.529 ug/L SW 6020B 11/09/2016 14:34 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4400 mg/L SM2540C 11/03/2016 15:24 JASTOWE621
Duke Energy Analytical Lab Page 12 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032493
Collection Date:01-Nov-16 9:21 AM
Site:LP-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 760 mg/L EPA 9056A 11/03/2016 02:11 GHUTCHI1001000
Fluoride < 10 mg/L EPA 9056A 11/03/2016 02:11 GHUTCHI10100
Nitrate < 10 mg/L EPA 9056A 11/03/2016 02:11 GHUTCHI10100
Nitrate as N 1.8 mg-N/L EPA 9056A 11/03/2016 02:11 GHUTCHI0.023 1
Sulfate 2200 mg/L EPA 9056A 11/03/2016 02:11 GHUTCHI1001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 14:06 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.068 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Boron (B)22.3 mg/L SW 6010D 11/13/2016 14:19 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Iron (Fe)0.045 mg/L SW 6010D 11/13/2016 14:19 MHALL30.01 1
Manganese (Mn)0.009 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Nickel (Ni)0.008 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 14:19 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 15:40 CWSPEN311
Cadmium (Cd)2.19 ug/L SW 6020B 11/07/2016 15:40 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 15:40 CWSPEN311
Selenium (Se)67.9 ug/L SW 6020B 11/07/2016 15:40 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/07/2016 15:40B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4800 mg/L SM2540C 11/03/2016 15:24 JASTOWE831
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032494
Collection Date:01-Nov-16 9:21 AM
Site:DUP LP-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 760 mg/L EPA 9056A 11/03/2016 02:57 GHUTCHI1001000
Fluoride < 10 mg/L EPA 9056A 11/03/2016 02:57 GHUTCHI10100
Nitrate < 10 mg/L EPA 9056A 11/03/2016 02:57 GHUTCHI10100
Nitrate as N 1.8 mg-N/L EPA 9056A 11/03/2016 02:57 GHUTCHI0.023 1
Sulfate 2200 mg/L EPA 9056A 11/03/2016 02:57 GHUTCHI1001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/11/2016 14:09 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.066 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Boron (B)21.4 mg/L SW 6010D 11/13/2016 14:23 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Iron (Fe)0.073 mg/L SW 6010D 11/13/2016 14:23 MHALL30.01 1
Manganese (Mn)0.011 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Nickel (Ni)0.007 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 14:23 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 15:47 CWSPEN311
Cadmium (Cd)2.08 ug/L SW 6020B 11/07/2016 15:47 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 15:47 CWSPEN311
Selenium (Se)65.3 ug/L SW 6020B 11/07/2016 15:47 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/07/2016 15:47B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 4800 mg/L SM2540C 11/03/2016 15:24 JASTOWE831
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
2016032495
Collection Date:01-Nov-16 5:38 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 11/03/2016 03:20 GHUTCHI0.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/03/2016 03:20 GHUTCHI0.1 1
Nitrate < 0.1 mg/L EPA 9056A 11/03/2016 03:20 GHUTCHI0.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 11/03/2016 03:20 GHUTCHI0.023 1
Sulfate < 0.1 mg/L EPA 9056A 11/03/2016 03:20 GHUTCHI0.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/14/2016 12:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 14:27 MHALL30.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 11/13/2016 14:27 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 14:27 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/06/2016 00:51 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/06/2016 00:51 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/06/2016 00:51 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/06/2016 00:51 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/06/2016 00:51B2 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 11/03/2016 15:24 JASTOWE251
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110075 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0 mg/L -10 0.1 < 1/2 RDL
Fluoride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0.027 mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 3.93 2 99mg/L -1208013.93
Fluoride 2.07 2 103mg/L -1208012.07
Nitrate 3.18 2 102mg/L -1208013.18
Sulfate 3.95 2 98.9mg/L -1208013.95
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 3.94 2 99.3 0.252mg/L -1208013.94
Fluoride 2.07 2 102 0.0488mg/L -1208012.07
Nitrate 3.19 2 102 0.196mg/L -1208013.19
Sulfate 3.96 2 99.3 0.353mg/L -1208013.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 2.02 2 101mg/L -1208012.02
Fluoride 1.98 2 99.1mg/L -1208011.98
Nitrate 2.03 2 101mg/L -1208012.03
Sulfate 2.03 2 102mg/L -1208012.03
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110111 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0 mg/L -10 0.1 < 1/2 RDL
Fluoride 0 mg/L -10 0.1 < 1/2 RDL
Nitrate 0 mg/L -10 0.1 < 1/2 RDL
Sulfate 0.027 mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 4.14 2 106mg/L -1208014.14
Fluoride 2.01 2 99.8mg/L -1208012.01
Nitrate 2.79 2 109mg/L -1208012.79
Sulfate 3.13 2 110mg/L -1208013.13
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 4.1 2 104 2.19mg/L -1208014.1
Fluoride 2.04 2 102 1.69mg/L -1208012.04
Nitrate 2.74 2 106 2.19mg/L -1208012.74
Sulfate 3.09 2 107 2.16mg/L -1208013.09
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 2.01 2 101mg/L -1208012.01
Fluoride 1.98 2 99.2mg/L -1208011.98
Nitrate 2.02 2 101mg/L -1208012.02
Sulfate 2.03 2 101mg/L -1208012.03
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110390 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.006 ug/L -1-0.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.006 ug/L -1-0.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.822 50 82.5ug/L -125755041.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.827 50 83 0.605ug/L -125755041.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 96.8ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100653 -- 2016034633
Mercury (Hg) 0.702 1 69.8ug/L -1257510.702
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100653 -- 2016034633
Mercury (Hg) 0.698 1 69.4 0.575ug/L -1257510.698
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032484
Mercury (Hg) 0.824 1 80.9ug/L -1257510.824
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032484
Mercury (Hg) 0.837 1 82.2 1.59ug/L -1257510.837
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032485
Mercury (Hg) 0.833 1 64.5ug/L -1257510.833
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110390 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032485
Mercury (Hg) 0.818 1 63 2.35ug/L -1257510.818
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032490
Mercury (Hg) 0.122 1 13.3ug/L -1257510.122
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032490
Mercury (Hg) 0.122 1 13.3 0ug/L -1257510.122
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110430 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.013 ug/L -1-0.013 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.1 2 105ug/L -1158512.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100684 -- 2016034796
Mercury (Hg) 0.778 1 78.8ug/L -1257510.778
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100684 -- 2016034796
Mercury (Hg) 0.776 1 78.6 0.254ug/L -1257510.776
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110517 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.012 ug/L -10.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.944 2 85ug/L -1257521.89
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.965 2 87.1 2.44ug/L -1257521.93
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.11 2 105ug/L -1158512.11
Duke Energy Analytical Lab Page 21 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110091 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000331 mg/L -1-0.000331 0.005 < 1/2 RDL
Boron (B) 0.000188 mg/L -10.000188 0.05 < 1/2 RDL
Chromium (Cr) -0.000533 mg/L -1-0.000533 0.005 < 1/2 RDL
Copper (Cu) -0.00185 mg/L -1-0.00185 0.005 < 1/2 RDL
Iron (Fe) 0.0018 mg/L -10.0018 0.01 < 1/2 RDL
Manganese (Mn) 0.000103 mg/L -10.000103 0.005 < 1/2 RDL
Nickel (Ni) -0.000257 mg/L -1-0.000257 0.005 < 1/2 RDL
Silver (Ag) -0.000456 mg/L -1-0.000456 0.005 < 1/2 RDL
Zinc (Zn) 0.00233 mg/L -10.00233 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.15 5 103mg/L -1208015.15
Boron (B) 5.02 5 100mg/L -1208015.02
Chromium (Cr) 5.02 5 100mg/L -1208015.02
Copper (Cu) 5.02 5 100mg/L -1208015.02
Iron (Fe) 5.12 5 102mg/L -1208015.12
Manganese (Mn) 5.07 5 101mg/L -1208015.07
Nickel (Ni) 5.05 5 101mg/L -1208015.05
Silver (Ag) 0.495 0.5 99mg/L -1208010.495
Zinc (Zn) 5.07 5 101mg/L -1208015.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032484
Barium (Ba) 5.12 5 102mg/L -1257515.12
Boron (B) 7.62 5 103mg/L -1257517.62
Chromium (Cr) 4.88 5 97.7mg/L -1257514.88
Copper (Cu) 4.95 5 99mg/L -1257514.95
Iron (Fe) 5.46 5 101mg/L -1257515.46
Manganese (Mn) 4.94 5 98.4mg/L -1257514.94
Nickel (Ni) 4.78 5 95.6mg/L -1257514.78
Silver (Ag) 0.483 0.5 96.7mg/L -1257510.483
Zinc (Zn) 4.8 5 95.9mg/L -1257514.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032484
Barium (Ba) 5.13 5 102 0.177mg/L -1257515.13
Boron (B) 7.71 5 104 1.66mg/L -1257517.71
Chromium (Cr) 4.88 5 97.5 0.123mg/L -1257514.88
Copper (Cu) 4.94 5 99 0.0606mg/L -1257514.94
Duke Energy Analytical Lab Page 22 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110091 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100186 -- 2016032484
Iron (Fe) 5.47 5 101 0.297mg/L -1257515.47
Manganese (Mn) 4.93 5 98.1 0.285mg/L -1257514.93
Nickel (Ni) 4.78 5 95.5 0.0628mg/L -1257514.78
Silver (Ag) 0.484 0.5 96.8 0.096mg/L -1257510.484
Zinc (Zn) 4.79 5 95.7 0.125mg/L -1257514.79
Duke Energy Analytical Lab Page 23 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110098 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0346 ug/L -10.0346 1 < 1/2 RDL
Cadmium (Cd) 0.0002 ug/L -10.0002 1 < 1/2 RDL
Lead (Pb) 0.0039 ug/L -10.0039 1 < 1/2 RDL
Selenium (Se) 0.0262 ug/L -10.0262 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0051 ug/L -1-0.0051 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 47.9 50 95.8ug/L -12080147.9
Cadmium (Cd) 51.7 50 103ug/L -12080151.7
Lead (Pb) 50.7 50 101ug/L -12080150.7
Selenium (Se) 46.4 50 92.8ug/L -12080146.4
Thallium (Tl) Low Level 49.4 50 98.8ug/L -12080149.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100731 -- 2016035063
Arsenic (As) 47.9 50 95.6ug/L -12575147.9
Cadmium (Cd) 50.6 50 101ug/L -12575150.6
Lead (Pb) 49.3 50 98.4ug/L -12575149.3
Selenium (Se) 48.4 50 95ug/L -12575148.4
Thallium (Tl) Low Level 46.8 50 93.4ug/L -12575146.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100731 -- 2016035063
Arsenic (As) 48.5 50 96.8 1.19ug/L -12575148.5
Cadmium (Cd) 51 50 102 0.726ug/L -12575151
Lead (Pb) 50.2 50 100 1.64ug/L -12575150.2
Selenium (Se) 49.1 50 96.4 1.42ug/L -12575149.1
Thallium (Tl) Low Level 47.8 50 95.4 2.1ug/L -12575147.8
Duke Energy Analytical Lab Page 24 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100186
Q16110078 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100186 -- 2016032484
TDS 7.47mg/L -11320
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100186 -- 2016032485
TDS 6.97mg/L -11710
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Duke Energy Analytical Lab Page 25 of 28
Duke Energy Analytical Lab Page 26 of 28
Duke Energy Analytical Lab Page 27 of 28
Duke Energy Analytical Lab Page 28 of 28
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16110239
Project Name:ROXBORO - LFGW
Lab Contact:Anne Pridgeon
Date:12/6/2016
Customer Address:Roxboro Steam Station
Customer Name(s):John Toepfer, Tim Hunsucker
1700 Dunnaway Road
Semora,NC 27343
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016036037 Roxboro 11-Nov-16 10:05 AM Synterra LP-5
2016036038 Roxboro 11-Nov-16 10:00 AM Synterra LP-6
2 Total Samples
Duke Energy Analytical Lab Page 2 of 12
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/2/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab Page 3 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
2016036037
Collection Date:11-Nov-16 10:05 AM
Site:LP-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 760 mg/L EPA 9056A 11/12/2016 16:03 BGN903410100
Fluoride < 5 mg/L EPA 9056A 11/12/2016 16:03 BGN9034550
Nitrate 6.9 mg/L EPA 9056A 11/12/2016 16:03 BGN9034550
Nitrate as N 1.6 mg-N/L EPA 9056A 11/12/2016 16:03 BGN90340.023 1
Sulfate 2400 mg/L EPA 9056A 11/12/2016 16:03 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/28/2016 14:27 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.061 mg/L SW 6010D 12/01/2016 22:53M2 MHALL30.005 1
Boron (B)19.2 mg/L SW 6010D 12/01/2016 22:53M4 MHALL30.05 1
Chromium (Cr)0.015 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
Iron (Fe)0.298 mg/L SW 6010D 12/01/2016 22:53 MHALL30.01 1
Manganese (Mn)1.90 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
Nickel (Ni)0.010 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
Zinc (Zn)0.008 mg/L SW 6010D 12/01/2016 22:53 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/21/2016 13:11 CWSPEN311
Cadmium (Cd)1.44 ug/L SW 6020B 11/21/2016 13:11 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/21/2016 13:11 CWSPEN311
Selenium (Se)44.0 ug/L SW 6020B 11/21/2016 13:11 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/21/2016 13:11 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 49000 mg/L SM2540C 11/17/2016 16:00 CJELLIO25010
Duke Energy Analytical Lab Page 4 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
2016036038
Collection Date:11-Nov-16 10:00 AM
Site:LP-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 960 mg/L EPA 9056A 11/12/2016 16:19 BGN903450500
Fluoride < 5 mg/L EPA 9056A 11/12/2016 16:19 BGN9034550
Nitrate < 5 mg/L EPA 9056A 11/12/2016 16:19 BGN9034550
Nitrate as N 0.38 mg-N/L EPA 9056A 11/12/2016 16:19 BGN90340.023 1
Sulfate 2500 mg/L EPA 9056A 11/12/2016 16:19 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/28/2016 14:29 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.067 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Boron (B)30.1 mg/L SW 6010D 12/01/2016 23:07 MHALL30.5 10
Chromium (Cr)< 0.005 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Iron (Fe)0.837 mg/L SW 6010D 12/01/2016 23:07 MHALL30.01 1
Manganese (Mn)1.68 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Nickel (Ni)0.018 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Silver (Ag)< 0.005 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
Zinc (Zn)0.011 mg/L SW 6010D 12/01/2016 23:07 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/19/2016 19:22 CWSPEN311
Cadmium (Cd)2.30 ug/L SW 6020B 11/19/2016 19:22 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/19/2016 19:22 CWSPEN311
Selenium (Se)87.8 ug/L SW 6020B 11/19/2016 19:22 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 11/19/2016 19:22 CWSPEN30.2 1
TOTAL DISSOLVED SOLIDS
TDS 50000 mg/L SM2540C 11/17/2016 16:00 CJELLIO25010
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab Page 5 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110394 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0263 mg/L -10.0263 0.1 < 1/2 RDL
Fluoride 0.019 mg/L -10.019 0.1 < 1/2 RDL
Nitrate 0.0032 mg/L -10.0032 0.1 < 1/2 RDL
Sulfate -0.0249 mg/L -1-0.0249 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 8.92 5 102mg/L -1208018.92
Fluoride 5.06 5 101mg/L -1208015.06
Nitrate 5.02 5 100mg/L -1208015.02
Sulfate 5.81 5 102mg/L -1208015.81
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 8.92 5 102 0.0295mg/L -1208018.92
Fluoride 5.06 5 101 0.0418mg/L -1208015.06
Nitrate 5.03 5 101 0.165mg/L -1208015.03
Sulfate 5.81 5 102 0.0196mg/L -1208015.81
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.32 5 108mg/L -1208018.32
Sulfate 7.37 5 107mg/L -1208017.37
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.33 5 108 0.246mg/L -1208018.33
Sulfate 7.37 5 107 0.148mg/L -1208017.37
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.9 5 98.1mg/L -1109014.9
Fluoride 5.11 5 102mg/L -1109015.11
Nitrate 4.9 5 98mg/L -1109014.9
Sulfate 4.92 5 98.5mg/L -1109014.92
Duke Energy Analytical Lab Page 6 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110723 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.1 100 109ug/L -12575100110
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.12 100 111 1.82ug/L -12575100112
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.24 2 112ug/L -1158512.24
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.19 2 109ug/L -1158512.19
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110153 -- 2016035725
Mercury (Hg) 1.13 1 112ug/L -1257511.13
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110153 -- 2016035725
Mercury (Hg) 1.12 1 111 0.81ug/L -1257511.12
Duke Energy Analytical Lab Page 7 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110529 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000147 mg/L -10.000147 0.005 < 1/2 RDL
Boron (B) 0.000683 mg/L -10.000683 0.05 < 1/2 RDL
Chromium (Cr) 0.000079 mg/L -10.000079 0.005 < 1/2 RDL
Copper (Cu) -0.000055 mg/L -1-0.000055 0.005 < 1/2 RDL
Iron (Fe) 0.000986 mg/L -10.000986 0.01 < 1/2 RDL
Manganese (Mn) 0.000033 mg/L -10.000033 0.005 < 1/2 RDL
Nickel (Ni) 0.000005 mg/L -10.000005 0.005 < 1/2 RDL
Silver (Ag) 0.000158 mg/L -10.000158 0.005 < 1/2 RDL
Zinc (Zn) 0.000206 mg/L -10.000206 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.93 5 98.7mg/L -1208014.93
Boron (B) 5.09 5 102mg/L -1208015.09
Chromium (Cr) 5.1 5 102mg/L -1208015.1
Copper (Cu) 5.18 5 104mg/L -1208015.18
Iron (Fe) 5.23 5 105mg/L -1208015.23
Manganese (Mn) 5.14 5 103mg/L -1208015.14
Nickel (Ni) 5.23 5 105mg/L -1208015.23
Silver (Ag) 0.506 0.5 101mg/L -1208010.506
Zinc (Zn) 5.14 5 103mg/L -1208015.14
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110239 -- 2016036037
Barium (Ba) 0.839 5 15.6mg/L -1257510.839
Boron (B) 24.5 5 105mg/L -12575124.5
Chromium (Cr) 4.95 5 98.8mg/L -1257514.95
Copper (Cu) 5.19 5 104mg/L -1257515.19
Iron (Fe) 5.42 5 102mg/L -1257515.42
Manganese (Mn) 6.91 5 100mg/L -1257516.91
Nickel (Ni) 5 5 99.7mg/L -1257515
Silver (Ag) 0.497 0.5 99.4mg/L -1257510.497
Zinc (Zn) 4.83 5 96.3mg/L -1257514.83
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110239 -- 2016036037
Barium (Ba) 1.6 5 30.7 65.6mg/L -1257511.6
Boron (B) 24.7 5 110 4.68mg/L -12575124.7
Chromium (Cr) 5.01 5 99.9 1.17mg/L -1257515.01
Copper (Cu) 5.22 5 105 0.632mg/L -1257515.22
Duke Energy Analytical Lab Page 8 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110529 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110239 -- 2016036037
Iron (Fe) 5.48 5 104 1.2mg/L -1257515.48
Manganese (Mn) 7.02 5 102 2.19mg/L -1257517.02
Nickel (Ni) 5.07 5 101 1.47mg/L -1257515.07
Silver (Ag) 0.503 0.5 101 1.17mg/L -1257510.503
Zinc (Zn) 4.92 5 98.2 1.95mg/L -1257514.92
Duke Energy Analytical Lab Page 9 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110532 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.007 ug/L -10.007 1 < 1/2 RDL
Cadmium (Cd) 0.003 ug/L -10.003 1 < 1/2 RDL
Lead (Pb) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Selenium (Se) -0.089 ug/L -1-0.089 1 < 1/2 RDL
Thallium (Tl) Low Level 0.006 ug/L -10.006 0.2 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.5 50 103ug/L -12080151.5
Cadmium (Cd) 52.4 50 105ug/L -12080152.4
Lead (Pb) 50.6 50 101ug/L -12080150.6
Selenium (Se) 45.7 50 91.3ug/L -12080145.7
Thallium (Tl) Low Level 45.8 50 91.7ug/L -12080145.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110239 -- 2016036038
Arsenic (As) 54 50 107ug/L -12575154
Cadmium (Cd) 51.7 50 98.9ug/L -12575151.7
Lead (Pb) 51.1 50 102ug/L -12575151.1
Selenium (Se) 131 50 86.1ug/L -125751131
Thallium (Tl) Low Level 41.5 50 82.7ug/L -12575141.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110239 -- 2016036038
Arsenic (As) 54.4 50 108 0.719ug/L -12575154.4
Cadmium (Cd) 52.3 50 100 1.09ug/L -12575152.3
Lead (Pb) 52 50 104 1.74ug/L -12575152
Selenium (Se) 132 50 87.8 1.99ug/L -125751132
Thallium (Tl) Low Level 42.1 50 83.8 1.28ug/L -12575142.1
Duke Energy Analytical Lab Page 10 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16110239
Q16110524 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090077 -- 2016028434
TDS 3.39mg/L -160
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16090077 -- 2016028435
TDS 3.19mg/L -1159
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16090077 -- 2016028436
TDS 2.11mg/L -1141
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Duke Energy Analytical Lab Page 11 of 12
Duke Energy Analytical Lab Page 12 of 12