HomeMy WebLinkAbout8504_DukeBelewsCreek_CraigRd_Jan2017_1stSemiAnnual_DIN27647_20170417
Belews Creek Steam Station
Semiannual Groundwater
Monitoring Report
Craig Road Ash Landfill, Phase 1 and 2
Permit No. 8504
January 2017 Sampling Event
May 1, 2017
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
TABLE OF CONTENTS
ii
Table of Contents
Page
Report Verification ......................................................................................................................... i
Table of Contents .......................................................................................................................... ii
Section 1 - Background ................................................................................................................. 1
Section 2 - Methods ...................................................................................................................... 4
2.1 Sampling and Analysis Methods .................................................................................... 4
2.2 Statement of Work .......................................................................................................... 4
Section 3 - Results ........................................................................................................................ 6
3.1 Site Groundwater Flow ................................................................................................... 6
3.2 Analytical Results ........................................................................................................... 6
FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Field and Analytical Results that Equal or Exceed NCAC 2B Surface Water Quality
Standards
8. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 1 - BACKGROUND
1
Section 1 - Background
Belews Creek Steam Station is located on Belews Lake in southwestern Stokes County near
Pine Hall, North Carolina. The station is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy) and generates electricity by combustion of coal. The Craig Road Ash Landfill is
owned by Duke Energy and is permitted to receive coal ash, wastewater treatment sludge, and
off-spec flue gas desulfurization (FGD) residue (gypsum) generated at the Belews Creek Steam
Station under North Carolina Department of Environmental Quality (NCDEQ) Solid Waste
Permit No. 8504.
Phase 1 of the landfill was constructed with an engineered liner system and the waste boundary
contains an area of approximately 32.4 acres. Phase 1 began accepting waste in February
2008. Phase 2 of the landfill was constructed with an engineered liner system and the waste
boundary contains an area of approximately 34.7 acres. Placement of a protective cover layer of
approximately 137,000 tons of bottom ash on top of the Phase 2 liner system began on June
11, 2013. Phase 2 of the landfill received a Permit to Operate January 16, 2014, and started
receiving waste on June 13, 2014.
Phase 1 and Phase 2 of the Craig Road Ash Landfill and nearby area are portrayed on Figure 1.
The highest topographic area of the landfill site is at the center portion of the landfill along its
southern boundary. The predominant groundwater discharge areas are expected to be the
adjacent areas of Belews Lake located to the west, north, and east of the landfill. Figure 2
shows the landfill and the topography at the site.
As described in the Water Quality Monitoring Plan, the monitoring system for the landfill consists
of the following1:
Monitoring Wells: CRW-1
2 CRW-7 CRW-13
CRW-2 CRW-83 CRW-14
CRW-3 CRW-9 CRW-15
CRW-4 CRW-10 CRW-16
CRW-5 CRW-11 CRW-17
CRW-6 CRW-12
Surface Water Sample Locations: CRS-1 CRS-4
CRS-2 CRS-5
CRS-3 CRS-6
Leachate Sample Locations4:CWB-1
CWB-2
CWB-3
1 Water Quality Monitoring Plan – Phase1/Phase 2 Craig Road Landfill Expansion Duke Energy – Belews Creek
Steam Station, Belews Creek, North Carolina, S&ME Project No. 1356-10-041, April 26, 2012. 2 Monitoring well CRW-1 was abandoned on July 13, 2012, due to construction of Phase 2 of the landfill. 3 Monitoring well CRW-8 was damaged and subsequently replaced by CRW-8R on April 11, 2013. 4 The leachate sample locations are not described in the Water Quality Monitoring Plan but monitoring the leachate in
conjunction with the groundwater monitoring event is a requirement of the Permit to Operate. Leachate sample
locations CWB-1 and CWB-2 were formerly referred to as E-WWBLeachate and W-WWBLeachate, respectively.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 1 - BACKGROUND
2
The sampling locations are depicted on Figure 2. A summary of monitoring well construction
information is presented in Table 1. According to the Water Quality Monitoring Plan, monitoring
well CRW-10 serves as a background water quality monitoring well.
Surface water sampling locations CRS-1 and CRS-2 are located on perennial streams which
drain to Belews Lake. Sampling locations CRS-4 and CRS-5 are located at groundwater seeps.
Sampling locations CRS-3 and CRS-6 are located at the outlets of the two landfill under-drains.
There is a single non-contact stormwater basin located to the north of the landfill. This basin is
located just north of CRW-4 and shown on Figure 2 as “Primary BMP.” There are three
stormwater basins that receive contact stormwater and leachate. These basins are shown on
Figure 2 as “West Ash Runoff Storage Basin,” “East Ash Runoff Storage Basin,” and “Phase 2
Contact Water Basin.”
Leachate sample locations are located where the leachate collection pipes drain into the contact
stormwater/leachate basins. The contact stormwater/leachate basins and leachate sample
locations are shown on Figure 2.
Monitoring wells CRHS-9 and CRHS-31 were installed as part of the site suitability study for
Phase 2 and were left in place during the January 2013 sampling event with the intent that they
would become part of the permanent groundwater monitoring network for the landfill. Due to the
poor performance of these wells with respect to recharge, these wells were replaced in April
2013 with monitoring wells CRW-12 and CRW-13, respectively.
Monitoring wells CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17 have had historically high
turbidity measurements reported in the wells. On May 2, 2015, Duke Energy attempted to
redevelop these monitoring wells. On June 29, 2015, Duke Energy purged additional well
volumes from these wells using each well’s dedicated pump in an effort to reduce the turbidity in
the wells. During the July 2016 sampling event, the turbidity measurements in these wells were
reported at 73.5, 32.7, 13.2, 500, and 37.7 Nephelometric Turbidity Units (NTU), respectively.
Due to the continued high turbidity measurements in the monitoring wells, Duke Energy is
considering the replacement of CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17. Due to the
elevated turbidity measurements at these wells and in other wells in the monitoring system,
HDR reviewed the turbidity results at landfill monitoring wells and made recommendations to
Duke Energy concerning redevelopment and/or replacement. The results of this review were
submitted to NCDEQ DWM in October 2016.5 Based on the results of the evaluation the
following monitoring wells were recommended for replacement:
CRW-2
CRW-3
CRW-8R
CRW-11
CRW-17
5 Groundwater Monitoring Well Evaluation – Craig Road Ash Landfill, Phase1 and 2, Permit No. 8504 – Belews
Creek Steam Station, Belews Creek, North Carolina, HDR, October 31, 2016.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 1 - BACKGROUND
3
Preparation for the replacement of these monitoring wells is currently underway.
Based on the results of the evaluation the following monitoring wells were recommended for
redevelopment:
CRW-6
CRW-7
CRW-9
CRW-10
CRW-12
CRW-13
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 2 - METHODS
4
Section 2 - Methods
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by Duke Energy
personnel (Duke Energy Carolinas Field Certification #5193) according to the North Carolina
Solid Waste Management Guidelines. Copies of the field sampling forms are included in
Appendix A. The parameters and constituents sampled were selected by Duke Energy and the
NCDEQ Division of Solid Waste and were analyzed by Duke Energy Analytical Laboratory
(North Carolina Laboratory Certification #248) and provided to HDR by Duke Energy. The
laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater, surface water, and leachate samples were analyzed using the following
analytical methods:
Barium, boron, chromium, copper, iron, manganese, nickel, and zinc using Solid Waste
(SW)-8466 Method 6010D
Arsenic, cadmium, lead, selenium, and silver using SW-846 Method 6020B
Chloride, fluoride, nitrate as nitrogen, and sulfate using US Environmental Protection
Agency (EPA) SW-846 Method 9056A
Mercury using EPA SW-846 Method 7470A
Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells CRW-2, CRW-3, CRW-4, CRW-5, CRW-6,
CRW-8R, CRW-9, CRW-10, CRW-11, CRW-12, CRW-13, CRW-14, CRW-15, CRW-16,
and CRW-17. Data was also received for surface water sample locations CRS-1, CRS-2,
CRS-4, CRS-5, and CRS-6. Leachate sample data was received for locations CWB-1
and CWB-2. A groundwater sample was not collected from CRW-7 as there was
insufficient water volume in the well. A surface water sample was not collected from
CRS-3 as it was dry. A leachate sample was not collected at CWB-3 due to lack of
discharge from the leachate pipe at this location. The samples were collected on
January 30 and 31, 2017, and HDR received the data on February 23, 2017.
Reviewed the laboratory analytical results for the samples. The Electronic Data
Deliverables (EDDs) provided by Duke Energy were adapted to conform to the format
6 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846 (Accessed
August 30, 2016)
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 2 - METHODS
5
requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J)
to indicate a measured concentration that is equal to or greater than the laboratory’s
method reporting limit (MRL) but less than the Solid Waste Section Limit7 (SWSL).
Copies of the original EDDs are retained in HDR’s files.
Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
7 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can
be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which
reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated
February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 3 - RESULTS
6
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows from the
sampling event for the site are shown on Figure 3. These contours were developed using the
groundwater elevations measured on the date of sampling. The surface water elevation for
Belews Lake was assumed at 724.5 feet. Calculated groundwater flow velocities are presented
on Table 2.
Groundwater flow at the site is from areas of higher topography located along the southern,
central portion of the landfill toward Belews Lake to the northwest, north, and to the northeast
and east toward the canal.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater samples collected at the monitoring wells and at
surface water locations CRS-4 and CRS-5 are summarized in Table 4. The analysis results for
these locations are compared to the groundwater standards found in Title 15A NCAC 02L .0202
(g) (2L Standards)8. Concentrations with values that attain or exceed the 2L Standards are
noted in Table 4 by bold font. A summary of the field and analytical results that attain or exceed
the 2L Standards and a preliminary analysis of the cause and significance of the exceedances
are presented in Table 5.
Surface water sample locations CRS-1 and CRS-2 are located on perennial streams and CRS-3
and CRS-6 are located at the outlets of landfill under-drains. The streams and under-drains flow
to Belews Lake. Belews Lake is classified by the NCDEQ Division of Water Quality as a Class C
water body. As a result, the field and analytical results from these locations are compared to
Title 15A, NCAC, Subchapter 2B Standards (2B Standards) for Class C water. The field and
analytical results of the surface water sampling are summarized in Table 6. A summary of the
field and analytical results that attain or exceed the 2B Standards and a preliminary analysis of
the cause and significance of the exceedances are presented in Table 7.
The field and analytical results for leachate sampling are summarized in Table 8.
Concentrations with values that are equal to or greater than the SWSLs are noted by gray cells
in Tables 4, 6, and 8.
Selected samples were diluted as is normal laboratory practice to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
8 Surface water locations CRS-4 and CRS-5 are located at groundwater seeps. Therefore, the analytical results at
these locations are compared to the Title 15A NCAC 02L .0202 (g) groundwater quality standards (2L Standards).
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
January 2017 Sampling Event
SECTION 3 - RESULTS
7
HDR prepared and submitted an assessment to NCDEQ on exceedances of the 2L and 2B
Standards at Phase 1 of this landfill (Groundwater Assessment, Belews Creek Steam Station,
Craig Road Ash Landfill, December 21, 2012).
The report assessed 2L Standard exceedances for:
Chromium at CRW-2 and CRW-9
Iron at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-8, CRW-9, CRS-4, and CRS-5
Manganese at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-9, CRS-4, and CRS-5
The report assessed 2B Standard exceedances for:
Iron at CRS-2 and CRS-3
The assessment report concluded that at the time of the assessment the exceedances
evaluated were naturally occurring and were not related to impacts from the landfill.
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CR
W
‐2
1
2
/
1
3
/
2
0
0
6
3
6
.
2
6
9
0
9
9
1
‐80
.
0
7
1
0
2
6
3
7
6
1
.
4
6
7
5
8
.
1
6
3
.
3
0
7
3
7
.
3
3
2
4
.
1
3
3
8
.
3
0
2
8
.
3
0
3
8
.
3
0
‐ 28.30
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐3
1
2
/
1
2
/
2
0
0
6
3
6
.
2
7
0
0
0
7
8
‐80
.
0
7
0
0
5
8
3
7
4
6
.
3
9
7
4
3
.
0
1
3
.
3
8
7
3
7
.
9
1
8
.
4
8
1
8
.
3
8
8
.
3
8
1
8
.
3
8
‐ 08.38
S
a
p
r
o
l
i
t
e
2
P
V
C
CR
W
‐4
1
2
/
1
2
/
2
0
0
6
3
6
.
2
7
0
5
3
4
8
‐80
.
0
6
8
0
9
8
5
7
7
3
.
5
3
7
7
0
.
7
3
2
.
8
0
7
5
1
.
3
5
2
2
.
1
8
2
9
.
8
0
1
9
.
8
0
2
9
.
8
0
‐ 19.80
P
W
R
2
P
V
C
CR
W
‐5
2
/
8
/
2
0
0
6
3
6
.
2
7
0
6
7
0
5
‐80
.
0
6
6
3
4
4
6
7
6
4
.
7
4
7
6
1
.
4
4
3
.
3
0
7
4
7
.
6
9
1
7
.
0
5
2
3
.
3
0
1
3
.
3
0
2
3
.
3
0
‐ 13.30
P
W
R
2
P
V
C
CR
W
‐6
1
2
/
1
4
/
2
0
0
6
3
6
.
2
7
0
6
6
4
9
‐80
.
0
6
4
8
4
6
6
7
8
3
.
1
0
7
8
0
.
3
2
2
.
7
8
7
5
8
.
5
4
2
4
.
5
6
3
0
.
2
8
2
0
.
2
8
3
0
.
2
8
‐ 20.28
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐7
2
/
8
/
2
0
0
6
3
6
.
2
7
0
2
9
1
0
‐80
.
0
6
4
6
0
0
7
7
8
5
.
0
8
7
8
1
.
0
9
3
.
9
9
7
5
7
.
5
8
2
7
.
5
0
3
0
.
9
9
2
0
.
9
9
3
0
.
9
9
‐ 20.99
P
W
R
2
P
V
C
CR
W
‐8R
4
/
1
1
/
2
0
1
3
3
6
.
2
6
9
1
8
5
6
‐80
.
0
6
4
7
7
3
9
7
7
6
.
3
9
7
7
3
.
6
8
2
.
7
1
7
4
7
.
8
7
2
8
.
5
2
3
9
.
7
1
2
9
.
7
1
3
9
.
7
1
‐ 29.71
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐9
1
2
/
1
4
/
2
0
0
6
3
6
.
2
6
7
6
7
6
1
‐80
.
0
6
5
5
0
5
0
7
6
9
.
6
7
7
6
6
.
6
3
3
.
0
4
7
4
2
.
5
1
2
7
.
1
6
3
9
.
0
4
2
9
.
0
4
3
9
.
0
4
‐ 29.04
S
a
p
r
o
l
i
t
e
2
P
V
C
CR
W
‐10
1
2
/
1
8
/
2
0
0
6
3
6
.
2
6
5
6
7
8
8
‐80
.
0
6
6
1
8
4
9
7
7
7
.
2
3
7
7
3
.
9
4
3
.
2
9
7
5
3
.
4
9
2
3
.
7
4
3
1
.
2
9
2
1
.
2
9
3
1
.
2
9
‐ 21.29
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐11
1
2
/
1
8
/
2
0
1
2
3
6
.
2
6
3
7
6
3
4
‐80
.
0
6
6
8
4
8
1
8
1
6
.
1
2
8
1
3
.
3
8
2
.
7
4
7
8
5
.
0
2
3
1
.
1
0
3
8
.
0
4
2
8
.
0
4
3
8
.
0
4
‐ 28.04
P
W
R
2
P
V
C
CR
W
‐12
4
/
1
0
/
2
0
1
3
3
6
.
2
6
3
8
7
4
1
‐80
.
0
6
8
5
8
3
1
8
3
7
.
9
3
8
3
5
.
0
0
2
.
9
3
8
0
1
.
4
1
3
6
.
5
2
4
4
.
6
3
3
4
.
6
3
4
4
.
6
3
‐ 34.63
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐13
4
/
1
0
/
2
0
1
3
3
6
.
2
6
5
1
7
3
0
‐80
.
0
7
1
4
2
6
8
8
2
2
.
4
9
8
1
9
.
4
4
3
.
0
5
7
8
8
.
4
1
3
4
.
0
8
3
9
.
0
5
2
9
.
0
5
3
9
.
0
5
‐ 29.05
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐14
1
2
/
1
8
/
2
0
1
2
3
6
.
2
6
5
8
3
7
6
‐80
.
0
7
2
9
3
0
5
7
9
4
.
8
7
7
9
2
.
2
3
2
.
6
4
7
7
1
.
3
1
2
3
.
5
6
4
0
.
8
4
2
5
.
8
4
4
0
.
8
4
‐ 25.84
B
e
d
r
o
c
k
2
P
V
C
CR
W
‐15
4
/
9
/
2
0
1
3
3
6
.
2
6
6
9
8
2
7
‐80
.
0
7
2
1
0
9
5
7
6
8
.
4
3
7
6
5
.
6
9
2
.
7
4
7
3
2
.
2
3
3
6
.
2
0
3
8
.
4
4
2
8
.
4
4
3
8
.
4
4
‐ 28.44
P
W
R
2
P
V
C
CR
W
‐16
4
/
9
/
2
0
1
3
3
6
.
2
6
8
4
7
7
5
‐80
.
0
7
1
7
8
0
5
7
7
3
.
5
9
7
7
0
.
5
8
3
.
0
1
7
3
0
.
2
6
4
3
.
3
3
5
0
.
0
1
4
0
.
0
1
5
0
.
0
1
‐ 40.01
S
a
p
r
o
l
i
t
e
/
P
W
R
2
P
V
C
CR
W
‐17
1
/
6
/
2
0
1
1
3
6
.
2
6
2
7
8
5
4
‐80
.
0
6
7
1
9
8
0
8
3
4
.
5
6
8
3
1
.
6
2
2
.
9
4
7
9
9
.
0
5
3
5
.
5
1
4
1
.
9
4
3
1
.
9
4
4
1
.
9
4
‐ 31.94
S
a
p
r
o
l
i
t
e
2
P
V
C
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
El
e
v
a
t
i
o
n
s
ba
s
e
d
on
NA
V
D
88
ve
r
t
i
c
a
l
da
t
u
m
De
p
t
h
to
wa
t
e
r
ga
u
g
e
d
on
Ja
n
u
a
r
y
30
an
d
31
,
20
1
7
In
f
o
r
m
a
t
i
o
n
pr
o
v
i
d
e
d
by
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
on
Fe
b
r
u
a
r
y
23
,
20
1
7
TO
C
in
d
i
c
a
t
e
s
to
p
of
ca
s
i
n
g
ft
in
d
i
c
a
t
e
s
fe
e
t
in
in
d
i
c
a
t
e
s
in
c
h
e
s
no
m
i
n
a
l
di
a
m
e
t
e
r
PW
R
in
d
i
c
a
t
e
s
pa
r
t
i
a
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l
y
we
a
t
h
e
r
e
d
ro
c
k
PV
C
in
d
i
c
a
t
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s
po
l
y
v
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ch
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r
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d
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Ho
r
i
z
o
n
t
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da
t
u
m
as
s
u
m
e
d
to
be
NA
D
8
3
Ta
b
l
e
2 ‐
Gr
o
u
n
d
w
a
t
e
r
Fl
o
w
Ve
l
o
c
i
t
i
e
s
‐
Ju
l
y
20
1
6
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
/
B
e
l
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w
s
Cr
e
e
k
St
e
a
m
St
a
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i
o
n
Cr
a
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g
Ro
a
d
As
h
La
n
d
f
i
l
l
Ph
a
s
e
1 an
d
2 ‐
Pe
r
m
i
t
No
.
85
0
4
We
l
l
ID
Up
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Do
w
n
g
r
a
d
i
e
n
t
Co
n
t
o
u
r
El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r
Fl
o
w
Di
s
t
a
n
c
e
(f
t
)
Hy
d
r
a
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l
i
c
Gr
a
d
i
e
n
t
Hy
d
r
a
u
l
i
c
Co
n
d
u
c
t
i
v
i
t
y
(f
t
/
d
a
y
)
Ef
f
e
c
t
i
v
e
Po
r
o
s
i
t
y
(%
)
Groundwater Velocity (ft/day)
CR
W
‐2
7
4
0
7
3
5
2
8
5
0
.
0
2
0
.
4
1
0
.
2
5
9
0
.
0
3
CR
W
‐3
7
4
0
7
3
5
2
3
5
0
.
0
2
0
.
4
1
0
.
2
5
9
0
.
0
3
CR
W
‐4
7
5
5
7
5
0
1
7
5
0
.
0
3
0
.
4
1
0
.
2
5
9
0
.
0
5
CR
W
‐5
7
5
0
7
4
7
.
6
9
5
1
0
.
0
4
0
.
4
1
0
.
2
5
9
0
.
0
7
CR
W
‐6
7
6
0
7
5
5
5
1
9
0
.
0
1
0
.
4
1
0
.
2
5
9
0
.
0
2
CR
W
‐7
7
6
0
7
5
5
5
8
7
0
.
0
1
0
.
4
1
0
.
2
5
9
0
.
0
1
CR
W
‐8R
7
5
0
7
4
7
.
8
7
6
0
0
.
0
4
0
.
4
1
0
.
2
5
9
0
.
0
6
CR
W
‐9
7
4
5
7
4
2
.
5
1
5
1
0
.
0
5
0
.
4
1
0
.
2
5
9
0
.
0
8
CR
W
‐10
7
5
5
7
5
0
1
2
4
0
.
0
4
0
.
4
1
0
.
2
5
9
0
.
0
6
CR
W
‐11
7
9
0
7
8
5
1
3
5
0
.
0
4
0
.
4
1
0
.
2
5
9
0
.
0
6
CR
W
‐12
8
0
1
.
4
1
8
0
0
6
0
0
.
0
2
0
.
4
1
0
.
2
5
9
0
.
0
4
CR
W
‐13
7
9
0
7
8
5
1
7
9
0
.
0
3
0
.
4
1
0
.
2
5
9
0
.
0
4
CR
W
‐14
7
7
5
7
7
0
1
2
9
0
.
0
4
0
.
4
1
0
.
2
5
9
0
.
0
6
CR
W
‐15
7
3
5
7
3
0
9
6
0
.
0
5
0
.
4
1
0
.
2
5
9
0
.
0
8
CR
W
‐16
7
3
5
7
3
0
2
2
0
0
.
0
2
0
.
4
1
0
.
2
5
9
0
.
0
4
CR
W
‐17
8
0
0
7
9
5
1
5
5
0
.
0
3
0
.
4
1
0
.
2
5
9
0
.
0
5
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
ft
in
d
i
c
a
t
e
s
fe
e
t
Li
n
e
a
r
di
s
t
a
n
c
e
me
a
s
u
r
e
d
th
r
o
u
g
h
mo
n
i
t
o
r
i
n
g
we
l
l
s
is
ge
n
e
r
a
l
l
y
pe
r
p
e
n
d
i
c
u
l
a
r
to
gr
o
u
n
d
w
a
t
e
r
co
n
t
o
u
r
s
At
mo
n
i
t
o
r
i
n
g
we
l
l
lo
c
a
t
i
o
n
s
wh
e
r
e
do
w
n
g
r
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d
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t
co
n
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ar
e
no
t
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e
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t
,
th
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th
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mo
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do
w
n
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d
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t
gr
o
u
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d
w
a
t
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r
el
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v
a
t
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At
mo
n
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wh
e
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up
g
r
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co
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e
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t
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85
0
4
Da
t
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S
a
m
p
l
e
ID
We
l
l
De
p
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w
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C
(f
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De
p
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to
Wa
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r
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C
(f
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Gr
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d
w
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El
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v
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(f
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)
A
p
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O
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P
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Me
t
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Av
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r
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L
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l
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a
l
)
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A
C
Vo
l
u
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e
(g
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l
)
EV
A
C
(Y
E
S
/
N
O
)
Temperature (°C)Specific Conductance (µԼ /cm)pH (SU)Turbidity (NTU)ORP (mV ‐NHE)DO (mg/L)
1/
3
0
/
2
0
1
7
C
R
W
‐2
3
8
.
2
4
2
4
.
1
3
7
3
7
.
3
3
N
o
r
m
a
l
N
o
n
e
L
F
2
0
0
2
.
3
0
4
.
2
N
/
A
1
4
.
4
0
4
0
5
.
7
1
6
.
8
5
6
8
7
.
4
9
1/
3
0
/
2
0
1
7
C
R
W
‐3
1
8
.
8
4
8
.
4
8
7
3
7
.
9
1
T
u
r
b
i
d
N
o
n
e
C
P
N
/
A
1
.
6
9
1
2
.
0
N
O
1
4
.
0
2
6
2
5
.
6
6
2
.
6
5
3
1
6
.
2
2
1/
3
0
/
2
0
1
7
C
R
W
‐4
3
0
.
1
9
2
2
.
1
8
7
5
1
.
3
5
N
o
r
m
a
l
N
o
n
e
C
P
N
/
A
1
.
3
1
7
.
5
N
O
1
5
.
9
0
6
4
6
.
3
1
1
.
8
5
5
6
8
.
3
4
1/
3
1
/
2
0
1
7
C
R
W
‐5
2
3
.
1
6
1
7
.
0
5
7
4
7
.
6
9
N
o
r
m
a
l
N
o
n
e
C
P
N
/
A
1
.
0
0
3
.
0
N
O
1
4
.
9
8
9
1
5
.
8
3
.
9
2
6
6
0
.
0
0
1/
3
0
/
2
0
1
7
C
R
W
‐6
3
0
.
2
0
2
4
.
5
6
7
5
8
.
5
4
N
o
r
m
a
l
N
o
n
e
C
P
N
/
A
0
.
9
2
1
.
0
Y
E
S
1
6
.
9
2
6
5
5
.
1
3
4
.
5
5
4
3
0
.
0
0
1/
3
0
/
2
0
1
7
C
R
W
‐7
2
9
.
9
0
2
7
.
5
0
7
5
7
.
5
8
N
/
A
N
/
A
C
P
N
/
A
0
.
3
9
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1/
3
1
/
2
0
1
7
C
R
W
‐8R
4
0
.
1
8
2
8
.
5
2
7
4
7
.
8
7
N
o
r
m
a
l
N
o
n
e
L
F
2
7
0
1
.
9
0
3
.
0
N
/
A
1
4
.
4
3
9
2
5
.
7
1
7
.
5
5
3
9
8
.
4
4
1/
3
1
/
2
0
1
7
C
R
W
‐9
3
9
.
6
2
2
7
.
1
6
7
4
2
.
5
1
N
o
r
m
a
l
N
o
n
e
L
F
3
0
0
2
.
0
3
1
.
6
N
/
A
1
5
.
5
2
5
0
5
.
8
1
5
.
6
5
4
8
6
.
8
8
1/
3
1
/
2
0
1
7
C
R
W
‐10
3
0
.
1
6
2
3
.
7
4
7
5
3
.
4
9
N
o
r
m
a
l
N
o
n
e
C
P
N
/
A
1
.
0
5
4
.
5
N
O
1
3
.
7
0
1
9
5
5
.
6
5
.
4
5
4
2
3
.
5
7
1/
3
1
/
2
0
1
7
C
R
W
‐11
3
8
.
5
2
3
1
.
1
0
7
8
5
.
0
2
N
o
r
m
a
l
N
o
n
e
E
O
P
N
/
A
1
.
2
1
0
.
5
N
/
A
1
4
.
0
6
1
2
5
6
.
3
9
.
3
4
7
7
8
.
4
8
1/
3
0
/
2
0
1
7
C
R
W
‐12
4
4
.
6
5
3
6
.
5
2
8
0
1
.
4
1
N
o
r
m
a
l
N
o
n
e
L
F
1
5
0
1
.
3
3
0
.
9
N
/
A
1
3
.
4
2
5
4
5
.
5
9
.
4
5
5
7
7
.
7
5
1/
3
0
/
2
0
1
7
C
R
W
‐13
3
9
.
2
8
3
4
.
0
8
7
8
8
.
4
1
N
o
r
m
a
l
N
o
n
e
C
P
N
/
A
0
.
8
5
4
.
0
N
O
1
2
.
8
8
1
5
1
6
.
0
6
.
8
5
0
3
7
.
9
9
1/
3
0
/
2
0
1
7
C
R
W
‐14
4
1
.
4
4
2
3
.
5
6
7
7
1
.
3
1
N
o
r
m
a
l
N
o
n
e
L
F
4
0
0
2
.
9
2
4
.
2
N
/
A
1
4
.
8
6
2
6
6
6
.
0
5
.
4
5
0
8
6
.
4
6
1/
3
0
/
2
0
1
7
C
R
W
‐15
3
8
.
8
2
3
6
.
2
0
7
3
2
.
2
3
N
o
r
m
a
l
N
o
n
e
E
O
P
N
/
A
0
.
4
3
0
.
5
N
/
A
1
3
.
4
8
9
4
5
.
8
2
.
1
5
0
4
8
.
2
2
1/
3
0
/
2
0
1
7
C
R
W
‐16
5
0
.
6
6
4
3
.
3
3
7
3
0
.
2
6
N
o
r
m
a
l
N
o
n
e
L
F
1
9
2
1
.
2
0
3
.
3
N
/
A
1
1
.
8
0
7
0
5
.
7
1
0
.
7
5
5
6
3
.
2
6
1/
3
1
/
2
0
1
7
C
R
W
‐17
4
1
.
7
0
3
5
.
5
1
7
9
9
.
0
5
N
o
r
m
a
l
N
o
n
e
E
O
P
N
/
A
1
.
0
1
0
.
5
N
/
A
1
4
.
8
0
7
0
5
.
8
3
.
4
4
9
7
6
.
3
8
1/
3
1
/
2
0
1
7
C
R
S
‐1
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
4
.
8
9
1
0
7
6
.
5
4
.
4
4
0
7
1
0
.
3
6
1/
3
1
/
2
0
1
7
C
R
S
‐2
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
4
.
8
4
1
1
6
6
.
5
3
.
4
2
9
6
1
1
.
6
9
1/
3
0
/
2
0
1
7
C
R
S
‐3
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1/
3
0
/
2
0
1
7
C
R
S
‐4
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1
1
.
9
0
1
0
7
5
.
8
5
.
2
4
1
6
4
.
5
7
1/
3
1
/
2
0
1
7
C
R
S
‐5
N
/
A
N
/
A
N
/
A
O
i
l
/
S
h
e
e
n
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1
0
.
9
4
8
0
5
.
7
2
6
.
5
3
2
9
6
.
0
1
1/
3
1
/
2
0
1
7
C
R
S
‐6
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1
4
.
9
4
9
8
5
.
9
1
2
.
7
4
9
2
8
.
1
9
1/
3
0
/
2
0
1
7
C
W
B
‐1
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1
4
.
4
0
4
,
3
4
4
4
.
7
1
.
4
5
5
5
9
.
3
2
1/
3
0
/
2
0
1
7
C
W
B
‐2
N
/
A
N
/
A
N
/
A
N
o
r
m
a
l
N
o
n
e
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
1
6
.
0
5
6
,
3
8
9
3
.
8
1
.
3
5
9
6
8
.
5
0
1/
3
0
/
2
0
1
7
C
W
B
‐3
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
N
/
A
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
12
.
13
.
14
.
15
.
16
.
17
.
Le
a
c
h
a
t
e
sa
m
p
l
e
s
CW
B
‐1 an
d
CW
B
‐2 we
r
e
fo
r
m
e
r
l
y
id
e
n
t
i
f
i
e
d
as
E ‐WW
B
Le
a
c
h
a
t
e
an
d
W ‐WW
B
Le
a
c
h
a
t
e
,
re
s
p
e
c
t
i
v
e
l
y
Dry ‐ No SampleDry ‐ No Sample
Gr
o
u
n
d
w
a
t
e
r
sa
m
p
l
e
CR
W
‐7,
su
r
f
a
c
e
wa
t
e
r
sa
m
p
l
e
CR
S
‐3,
an
d
le
a
c
h
a
t
e
sa
m
p
l
e
CW
B
‐3 we
r
e
no
t
co
l
l
e
c
t
e
d
du
e
to
in
s
u
f
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Laboratory Certification Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248
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W
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Laboratory Certification Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248
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l
i
v
e
r
a
b
l
e
(E
D
D
)
pr
o
v
i
d
e
d
by
Br
y
a
n
Mo
e
l
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r
of
Du
k
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En
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Ca
r
o
l
i
n
a
s
,
LL
C
on
Fe
b
r
u
a
r
y
23, 2017
15
A
NC
A
C
2L
St
a
n
d
a
r
d
re
f
e
r
s
to
Cl
a
s
s
GA
St
a
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d
a
r
d
s
as
fo
u
n
d
in
15
A
NC
A
C
02
L
.0
2
0
2
Gr
o
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d
w
a
t
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a
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St
a
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,
la
s
t
am
e
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e
d
on April 1, 2013
Ja
n
u
a
r
y
30
an
d
31
,
20
1
7
SU
in
d
i
c
a
t
e
s
St
a
n
d
a
r
d
Un
i
t
s
pH
S
U
6
.
5
‐
8.
5
Ta
b
l
e
5B
‐
Fi
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l
d
an
d
An
a
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t
i
c
a
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Re
s
u
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t
s
th
a
t
Eq
u
a
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or
Ex
c
e
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d
NC
A
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Gr
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d
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Cr
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Ro
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As
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Ph
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Pe
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m
i
t
No
.
85
0
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Sa
m
p
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e
Da
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e
:
Pa
r
a
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ID
R
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s
15
A
NC
A
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2L
St
a
n
d
a
r
d
Hi
s
t
o
r
i
c
a
l
Co
n
c
e
n
t
r
a
t
i
o
n
s
C
a
u
s
e
and Significance
CR
W
‐2
1
,
1
1
0
5
1
9
‐
28
,
7
7
5
I
r
o
n
in
CR
W
‐2 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 16.8 NTU
CR
W
‐3
3
,
1
7
0
2
4
4
‐
14
,
9
0
0
I
r
o
n
in
CR
W
‐3 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 62.6 NTU
CR
W
‐4
7
2
0
7
2
.
7
‐
1,
7
7
8
I
r
o
n
in
CR
W
‐4 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 11.8 NTU
CR
W
‐5
6
,
9
5
0
5
,
4
4
0
‐
18
,
2
6
0
I
r
o
n
in
CR
W
‐5 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well
CR
W
‐6
2
,
8
9
0
2
3
9
‐
12
,
5
8
5
I
r
o
n
in
CR
W
‐6 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 34.5 NTU
CR
W
‐8R
6
5
1
4
4
6
‐
7,
0
7
0
I
r
o
n
in
CR
W
‐8R
is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 17.5 NTU
CR
W
‐9
7
9
3
1
5
7
‐
31
,
6
0
0
I
r
o
n
in
CR
W
‐9 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 15.6 NTU
CR
W
‐10
3
5
6
1
0
3
‐
11
,
4
0
7
I
r
o
n
in
CR
W
‐10
is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well
CR
W
‐12
3
5
8
1
4
1
‐
47
,
0
0
0
I
r
o
n
in
CR
W
‐12
is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well
CR
W
‐13
3
2
6
4
0
5
‐
8,
7
1
0
I
r
o
n
in
CR
W
‐13
is
lo
w
e
r
th
a
n
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at
we
l
l
CR
W
‐16
3
6
9
7
6
.
4
‐
2,
5
6
0
I
r
o
n
in
CR
W
‐16
is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 10.7 NTU
CR
W
‐17
4
0
4
4
9
6
‐
35
,
4
2
3
I
r
o
n
in
CR
W
‐17
is
lo
w
e
r
th
a
n
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at
we
l
l
CR
S
‐4
5
7
8
2
0
3
‐
7,
8
3
0
I
r
o
n
in
CR
S
‐4 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at
location
CR
S
‐5
5
,
8
7
0
2
,
6
8
0
‐
31
,
7
0
0
I
r
o
n
in
CR
S
‐5 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at
location; turbidity measrued at 26.5 NTU
CR
W
‐3
5
8
.
7
2
7
.
6
‐
51
6
M
a
n
g
a
n
e
s
e
in
CR
W
‐3 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 62.6 NTU
CR
W
‐5
9
8
.
3
8
2
.
1
‐
18
0
M
a
n
g
a
n
e
s
e
in
CR
W
‐5 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well
CR
W
‐6
1
1
8
7
6
.
4
‐
68
1
M
a
n
g
a
n
e
s
e
in
CR
W
‐6 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at well; turbidity measured at 34.5 NTU
CR
S
‐5
2
6
4
1
7
7
‐
1,
5
9
3
M
a
n
g
a
n
e
s
e
in
CR
S
‐5 is
co
n
s
i
s
t
e
n
t
wi
t
h
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at location; turbidity measrued at 26.5 NTU
No
t
e
s
:
1.2.3.4.5.
Ja
n
u
a
r
y
30
an
d
31
,
20
1
7
Ir
o
n
µ
g
/
L
3
0
0
µg
/
L
in
d
i
c
a
t
e
s
mi
c
r
o
g
r
a
m
s
pe
r
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t
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r
NT
U
in
d
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a
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s
Ne
p
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l
o
m
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t
r
i
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Tu
r
b
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i
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y
Un
i
t
s
15
A
NC
A
C
2L
St
a
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r
d
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f
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to
Cl
a
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GA
St
a
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s
as
fo
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in
15
A
NC
A
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02
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2
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2
Gr
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a
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St
a
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d
a
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d
s
,
la
s
t
am
e
n
d
e
d
on April 1, 2013
Hi
s
t
o
r
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a
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co
n
c
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n
t
r
a
t
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s
ba
s
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on
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t
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in
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,
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(D
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)
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a
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i
c
a
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re
s
u
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t
s
da
t
a
b
a
s
e
An
a
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t
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a
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s
u
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t
s
ob
t
a
i
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d
fr
o
m
El
e
c
t
r
o
n
i
c
Da
t
a
De
l
i
v
e
r
a
b
l
e
(E
D
D
)
pr
o
v
i
d
e
d
by
Br
y
a
n
Mo
e
l
l
e
r
of
Du
k
e
En
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r
g
y
Ca
r
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l
i
n
a
s
,
LL
C
on
Fe
b
r
u
a
r
y
23, 2017
Ma
n
g
a
n
e
s
e
µ
g
/
L
5
0
Table 6 ‐ Surface Water Field and Analytical Results
Duke Energy Carolinas, LLC/Belews Creek Steam Station
Craig Road Ash Landfill
Phase 1 and 2 ‐ Permit No. 8504
Sample Date:
Field Sampling Performed By:
Parameter SWS ID Units
Certification
Code MDL SWSL
15A NCAC
2B Standard Federal MCL
Field pH 320 SU 5193 ‐‐NE 6.0‐9.0 6.5‐8.5*
Field Specific Conductivity 323 µԼ/cm 5193 ‐‐NE NE NE
Temperature 325 °C 5193 ‐‐NE NE NE
Arsenic 14 µg/L 248 0.114 J 0.158 J 0.124 J 0.078 10 10 10
Arsenic, dissolved 14 µg/L 248 0.078 U 0.078 U 0.078 U 0.078 10 150 NE
Barium 15 µg/L 248 26.4 J'22.3 J'34.1 J'0.1 100 NE 2,000
Barium, dissolved 15 µg/L 248 25.2 J'24.1 J'31.3 J'0.1 100 NE NE
Boron 428 µg/L 248 4.58 J 5.61 J 4.35 J 3.3 NE NE NE
Boron, dissolved 428 µg/L 248 3.3 U 3.3 U 3.3 U 3.3 NE NE NE
Cadmium 34 µg/L 248 0.101 U 0.101 U 0.101 U 0.101 1 NE 5
Cadmium, dissolved (h) 34 µg/L 248 0.101 U 0.101 U 0.101 U 0.101 1 0.15 NE
Chloride 455 µg/L 248 8,370 8,370 6,570 22 NE 230,000 250,000*
Chromium 51 µg/L 248 0.561 J 0.5 U 1.22 J 0.5 10 NE 100
Chromium, dissolved †51µg/L 248 0.761 J 0.809 J 0.5 U 0.5 10 11 NE
Copper 54 µg/L 248 1 U 1 U 1.82 J 1 10 NE 1,000*
Copper, dissolved (h) 54 µg/L 248 1 U 1 U 1 U 110 3 NE
Fluoride 312 µg/L 248 50.6 J 50.7 J 61 J 17 2,000 1,800 2,000*
Iron 340 µg/L 248 281 J'834 644 1.3 300 NE 300*
Iron, dissolved 340 µg/L 248 83.7 J'714 10.5 J'1.3 300 NE NE
Lead 131 µg/L 248 0.0899 J 0.065 U 0.306 J 0.065 10 NE 15
Lead, dissolved (h) 131 µg/L 248 0.065 U 0.065 U 0.065 U 0.065 10 0.54 NE
Manganese 342 µg/L 248 33.7 J'92.3 364 0.2 50 NE 50*
Manganese, dissolved 342 µg/L 248 31.9 J'103 325 0.2 50 NE NE
Mercury 132 µg/L 248 0.0334 U 0.0334 U 0.0334 U 0.0334 0.2 0.012 2
Nickel 152 µg/L 248 0.5 U 0.5 U 2 J 0.5 50 NE NE
Nickel, dissolved (h) 152 µg/L 248 0.5 U 0.5 U 1.08 J 0.5 50 16.000 NE
Nitrate (as Nitrogen) 303 µg/L 248 135 J'60.9 J'419 J'5.4 10,000 NE 10,000
Selenium 183 µg/L 248 0.092 U 0.092 U 0.092 U 0.092 10 5 50
Silver 184 µg/L 248 0.051 U 0.051 U 0.051 U 0.051 10 NE 100*
Silver, dissolved 184 µg/L 248 0.051 U 0.051 U 0.051 U 0.051 10 0.06 NE
Sulfate 315 µg/L 248 8,950 J'15,600 J'5,660 J'18 250,000 NE 250,000*
Total Dissolved Solids 311 µg/L 248 92,000 88,000 64,000 16,700 NE NE 500,000*
Zinc 213 µg/L 248 2.6 U 2.6 U 3.35 J 2.6 10 NE 5,000*
Zinc, dissolved (h) 213 µg/L 248 2.6 U 2.6 U 2.6 U 2.6 10 36 NE
Notes:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
14.94
98
SWS ID is the Solid Waste Section Identification Number
107 116
4.89 4.84
NS
NS
NS
NS
NS
NS
NS
NS
NS
Analytical results obtained from Electronic Data Deliverable (EDD) provided by Bryan Moeller of Duke Energy Carolinas, LLC on February 23, 2017
µg/L indicates micrograms per liter
Reference 15A NCAC 2B .0200 Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of N.C. Amended Effective: May 1, 2007
The perennial tributaries to Belews Lake are classified as Class C waters. Regulation 15A NCAC 02B .0211 provides water quality standards for Class C waters
Standards for Class C waters assume the most stringent of Freshwater and Human Health standard
2B ‐ Surface Water and Wetland Standards," (including '07‐'14 Triennial Review standards pending EPA review) for Class WS‐IV waters
15A NCAC 2B Standard is from "North Carolina Administrative Code, Title 15A: Deparment of Environment and Natural Resources, Subchapter
determined with suitable precision and accuracy
SWSL is the Solid Waste Section Limit. NCDEQ defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively
µԼ/cm indicates micromhos per centimeter
SU indicates standard units
°C indicates degrees celsius
MDL is the laboratory method detection limit. The MDL values presented are for samples not diluted by the laboratory during analysis
(h) Standard is hardness dependent; standard is displayed assuming a hardness of ≤ 25 mg/L
NS
NS
NS
NS
CRS‐3
NS
NS
NS
NS
NS
CRS‐6
NS 5.9
CRS‐1 CRS‐2
6.5 6.5
Laboratory Certification Codes:
Duke Energy Carolinas Field #5193
January 30 and 31, 2017
Duke Energy Carolinas, LLC
Duke Energy Analytical Laboratory #248
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
No sample was collected from CRS‐3 due to lack of water
† Standard listed is most stringent of Cr(III) and Cr(VI)
Bold values indicate values that attain or exceed the 15A NCAC 2B Standard
greater than the laboratory's MRL but are less than the SWSL
laboratory's method reporting limit (MRL); an italicized J'‐flag is a data qualifier, added by HDR to indicate concentrations which equal or are
Drinking Water Regulations
Grayed values indicate values that equal or are greater than the SWSL
* Concentration listed is a secondary maximum contaminant level (SMCL). SMCLs are established by EPA in the National Secondary
MCL is the Federal Maximum Contaminant Level as found in 40 CFR, Subpart G, §141.62
NE indicates not established; NA indicates not analyzed; NS indicates no sample collected; blank cells indicate that there is no information relevant
According to the Constituent Look‐up webpage on the NCDEQ Division of Waste Management webpage, there is no SWSL or 2L Standard for
choride associated with CAS number 16887‐08‐6, which is the CAS reported by the laboratory for the analyses completed; therefore, the SWSL
and 2L Standard listed are for the chloride with CAS number SW301 as specified on the Constituent Look‐up webpage (last updated June 13, 2011)
equal the laboratory's MDL; "J" is used to identify estimated concentrations which equal or are greater than the MDL but are less than the
to the respective row
Qualifiers in non‐italicized text are laboratory data qualifiers or "flags"; "U" is used to identify results not detected at concentrations which
Ta
b
l
e
7 ‐
Fi
e
l
d
an
d
An
a
l
y
t
i
c
a
l
Re
s
u
l
t
s
th
a
t
Eq
u
a
l
or
Ex
c
e
e
d
NC
A
C
2B
Su
r
f
a
c
e
Wa
t
e
r
Qu
a
l
i
t
y
St
a
n
d
a
r
d
s
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
/
B
e
l
e
w
s
Cr
e
e
k
St
e
a
m
St
a
t
i
o
n
Cr
a
i
g
Ro
a
d
As
h
La
n
d
f
i
l
l
Ph
a
s
e
1 an
d
2 ‐
Pe
r
m
i
t
No
.
85
0
4
Sa
m
p
l
e
Da
t
e
:
Pa
r
a
m
e
t
e
r
S
a
m
p
l
e
ID
R
e
s
u
l
t
U
n
i
t
s
15
A
NC
A
C
2L
St
a
n
d
a
r
d
Hi
s
t
o
r
i
c
a
l
Co
n
c
e
n
t
r
a
t
i
o
n
s
C
a
u
s
e
and Significance
pH
C
R
S
‐6
5
.
9
S
U
6
.
0
‐
9.
0
6
.
3
‐
7.
0
p
H
is
le
s
s
th
a
n
th
e
hi
s
t
o
r
i
c
a
l
re
a
d
i
n
g
s
at
CR
S
‐6
No
t
e
s
:
1.2.3.4.5.6.
An
a
l
y
t
i
c
a
l
re
s
u
l
t
s
ob
t
a
i
n
e
d
fr
o
m
El
e
c
t
r
o
n
i
c
Da
t
a
De
l
i
v
e
r
a
b
l
e
(E
D
D
)
pr
o
v
i
d
e
d
by
Br
y
a
n
Mo
e
l
l
e
r
of
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
on
Fe
b
r
u
a
r
y
23, 2017
Hi
s
t
o
r
i
c
a
l
co
n
c
e
n
t
r
a
t
i
o
n
s
ba
s
e
d
on
da
t
a
in
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
(D
u
k
e
En
e
r
g
y
)
an
a
l
y
t
i
c
a
l
re
s
u
l
t
s
da
t
a
b
a
s
e
Ja
n
u
a
r
y
30
an
d
31
,
20
1
7
SU
in
d
i
c
a
t
e
s
St
a
n
d
a
r
d
Un
i
t
s
15
A
NC
A
C
2B
St
a
n
d
a
r
d
is
fr
o
m
"N
o
r
t
h
Ca
r
o
l
i
n
a
Ad
m
i
n
i
s
t
r
a
t
i
v
e
Co
d
e
,
Ti
t
l
e
15
A
:
De
p
a
r
m
e
n
t
of
En
v
i
r
o
n
m
e
n
t
an
d
Na
t
u
r
a
l
Re
s
o
u
r
c
e
s
,
Subchapter
2B
‐
Su
r
f
a
c
e
Wa
t
e
r
an
d
We
t
l
a
n
d
St
a
n
d
a
r
d
s
,
"
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n
c
l
u
d
i
n
g
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7
‐'1
4
Tr
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e
n
n
i
a
l
Re
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st
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pe
n
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n
g
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)
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r
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s
s
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wa
t
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r
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n
d
a
r
d
s
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r
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a
s
s
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t
e
r
s
as
s
u
m
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th
e
mo
s
t
st
r
i
n
g
e
n
t
of
Fr
e
s
h
w
a
t
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r
an
d
Hu
m
a
n
He
a
l
t
h
st
a
n
d
a
r
d
Th
e
pe
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n
n
i
a
l
tr
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b
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t
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e
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to
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l
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f
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d
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l
a
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15
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NC
A
C
02
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2
1
1
pr
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s
for Class C waters
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NC
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2
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a
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c
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Ap
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b
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to
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f
a
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e
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t
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r
s
an
d
We
t
l
a
n
d
s
of
N.
C
.
Am
e
n
d
e
d
Effective: May 1, 2007
Ta
b
l
e
8 ‐
Le
a
c
h
a
t
e
Fi
e
l
d
an
d
An
a
l
y
t
i
c
a
l
Re
s
u
l
t
s
Du
k
e
En
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r
g
y
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r
o
l
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n
a
s
,
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C
/
B
e
l
e
w
s
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k
St
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m
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a
t
i
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n
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a
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d
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h
La
n
d
f
i
l
l
Ph
a
s
e
1 an
d
2 ‐
Pe
r
m
i
t
No
.
85
0
4
Sa
m
p
l
e
Da
t
e
:
Fi
e
l
d
Sa
m
p
l
i
n
g
Pe
r
f
o
r
m
e
d
By
:
Pa
r
a
m
e
t
e
r
S
W
S
ID
U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
i
o
n
Co
d
e
MDL
S
W
S
L
Fi
e
l
d
pH
3
2
0
S
U
5
1
9
3
‐‐
‐
‐
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e
l
d
Sp
e
c
i
f
i
c
Co
n
d
u
c
t
i
v
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t
y
3
2
3
µ
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m
5
1
9
3
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‐
‐
Te
m
p
e
r
a
t
u
r
e
3
2
5
°
C
5
1
9
3
‐‐
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‐
Ar
s
e
n
i
c
1
4
µg
/
L
2
4
8
2
9
.
4
4
0
.
5
0.078
1
0
Ba
r
i
u
m
1
5
µg
/
L
2
4
8
2
9
.
3
J'
25
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0.1
1
0
0
Bo
r
o
n
4
2
8
µg
/
L
2
4
8
3
8
,
1
0
0
7
3
,
1
0
0
3.3
N
E
Ca
d
m
i
u
m
3
4
µg
/
L
2
4
8
3
.
7
9
7
.
2
5
0.101
1
Ch
l
o
r
i
d
e
4
5
5
µg
/
L
2
4
8
4
2
9
,
0
0
0
3
1
9
,
0
0
0
22
N
E
Ch
r
o
m
i
u
m
5
1
µg
/
L
2
4
8
0
.
5
U
0
.
5
U
0.5
1
0
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p
p
e
r
5
4
µg
/
L
2
4
8
1
U
6
.
2
9
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110
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u
o
r
i
d
e
3
1
2
µg
/
L
2
4
8
1
,
6
2
0
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2
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9
4
0
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17
2
,
0
0
0
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o
n
3
4
0
µg
/
L
2
4
8
1
4
.
5
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42
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1.3
3
0
0
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a
d
1
3
1
µg
/
L
2
4
8
5
.
7
1
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11
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1
0.065
1
0
Ma
n
g
a
n
e
s
e
3
4
2
µg
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L
2
4
8
1
9
,
0
0
0
1
9
,
2
0
0
0.2
5
0
Me
r
c
u
r
y
1
3
2
µg
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L
2
4
8
0
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0
3
3
4
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0
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0
3
3
4
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0.0334
0
.
2
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c
k
e
l
1
5
2
µg
/
L
2
4
8
1
0
6
2
4
0
0.5
5
0
Ni
t
r
a
t
e
(a
s
Ni
t
r
o
g
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n
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3
0
3
µg
/
L
2
4
8
2
6
,
7
0
0
3
7
,
5
0
0
5.4
1
0
,
0
0
0
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l
e
n
i
u
m
18
3
µg
/
L
2
4
8
1
0
4
1
9
1
0.092
1
0
Si
l
v
e
r
1
8
4
µg
/
L
2
4
8
0
.
0
5
1
U
0
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0
5
1
U
0.051
1
0
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l
f
a
t
e
3
1
5
µg
/
L
2
4
8
2
,
2
1
0
,
0
0
0
4
,
2
1
0
,
0
0
0
18
2
5
0
,
0
0
0
To
t
a
l
Di
s
s
o
l
v
e
d
So
l
i
d
s
3
1
1
µg
/
L
2
4
8
3
,
1
0
0
,
0
0
0
3
,
8
2
0
,
0
0
0
16,700
N
E
Zi
n
c
2
1
3
µg
/
L
2
4
8
2
4
2
5
5
5
2.6
1
0
No
t
e
s
:
1.2.3.4.5.6.7.8.9.
10
.
11
.
14
.
15
.
Gr
a
y
e
d
va
l
u
e
s
in
d
i
c
a
t
e
va
l
u
e
s
th
a
t
eq
u
a
l
or
ar
e
gr
e
a
t
e
r
th
a
n
th
e
SW
S
L
MD
L
is
th
e
la
b
o
r
a
t
o
r
y
me
t
h
o
d
de
t
e
c
t
i
o
n
li
m
i
t
as
s
o
c
i
a
t
e
d
wi
t
h
CA
S
nu
m
b
e
r
16
8
8
7
‐08
‐6,
wh
i
c
h
is
th
e
CA
S
re
p
o
r
t
e
d
by
th
e
la
b
o
r
a
t
o
r
y
fo
r
th
e
an
a
l
y
s
e
s
co
m
p
l
e
t
e
d
;
th
e
r
e
f
o
r
e
,
th
e
SWSL
µg
/
L
in
d
i
c
a
t
e
s
mi
c
r
o
g
r
a
m
s
pe
r
li
t
e
r
NE
in
d
i
c
a
t
e
s
no
t
es
t
a
b
l
i
s
h
e
d
;
NA
in
d
i
c
a
t
e
s
no
t
an
a
l
y
z
e
d
;
NS
in
d
i
c
a
t
e
s
no
sa
m
p
l
e
co
l
l
e
c
t
d
;
bl
a
n
k
ce
l
l
s
in
d
i
c
a
t
e
th
a
t
th
e
r
e
is
no
in
f
o
r
m
a
t
i
o
n
re
l
e
v
a
n
t
to
th
e
re
s
p
e
c
t
i
v
e
ro
w
No
Sa
m
p
l
e
wa
s
co
l
l
e
c
t
e
d
fr
o
m
CW
B
‐3 as
th
e
r
e
wa
s
in
s
u
f
f
i
c
i
e
n
t
wa
t
e
r
An
a
l
y
t
i
c
a
l
re
s
u
l
t
s
ob
t
a
i
n
e
d
fr
o
m
El
e
c
t
r
o
n
i
c
Da
t
a
De
l
i
v
e
r
a
b
l
e
(E
D
D
)
pr
o
v
i
d
e
d
by
Br
y
a
n
Mo
e
l
l
e
r
of
Du
k
e
En
e
r
g
y
Ca
r
o
l
i
n
a
s
,
LL
C
on
February 23, 2017
Qu
a
l
i
f
i
e
r
s
in
no
n
‐it
a
l
i
c
i
z
e
d
te
x
t
ar
e
la
b
o
r
a
t
o
r
y
da
t
a
qu
a
l
i
f
i
e
r
s
or
"f
l
a
g
s
"
,
"U
"
is
us
e
d
to
id
e
n
t
i
f
y
re
s
u
l
t
s
no
t
de
t
e
c
t
e
d
at
co
n
c
e
n
t
r
a
t
i
o
n
s
HD
R
to
in
d
i
c
a
t
e
co
n
c
e
n
t
r
a
t
i
o
n
s
wh
i
c
h
eq
u
a
l
or
ar
e
gr
e
a
t
e
r
th
a
n
th
e
la
b
o
r
a
t
o
r
y
'
s
MR
L
bu
t
ar
e
le
s
s
th
a
n
th
e
SW
S
L
wh
i
c
h
eq
u
a
l
th
e
la
b
o
r
a
t
o
r
y
'
s
me
t
h
o
d
de
t
e
c
t
i
o
n
li
m
i
t
(M
D
L
)
,
"J
"
is
us
e
d
to
id
e
n
t
i
f
y
es
t
i
m
a
t
e
d
co
n
c
e
n
t
r
a
t
i
o
n
s
wh
i
c
h
eq
u
a
l
or
ar
e
gr
e
a
t
e
r
th
a
n
th
e
MD
L
bu
t
ar
e
le
s
s
th
a
n
th
e
la
b
o
r
a
t
o
r
y
'
s
me
t
h
o
d
re
p
o
r
t
i
n
g
li
m
i
t
(M
R
L
)
,
an
it
a
l
i
c
i
z
e
d
J'
‐fl
a
g
is
a da
t
a
qu
a
l
i
f
i
e
r
,
ad
d
e
d
by
NS
SW
S
L
is
th
e
So
l
i
d
Wa
s
t
e
Se
c
t
i
o
n
Li
m
i
t
;
NC
D
E
Q
de
f
i
n
e
s
th
e
SW
S
L
as
th
e
lo
w
e
s
t
am
o
u
n
t
of
an
a
l
y
t
e
in
a sa
m
p
l
e
th
a
t
ca
n
be
qu
a
n
t
i
t
a
t
i
v
e
l
y
NS NS NS NS
°C
in
d
i
c
a
t
e
s
de
g
r
e
e
s
ce
l
s
i
u
s
NSNSNSNS
SU
in
d
i
c
a
t
e
s
st
a
n
d
a
r
d
un
i
t
s
li
s
t
e
d
is
fo
r
th
e
ch
l
o
r
i
d
e
wi
t
h
CA
S
nu
m
b
e
r
SW
3
0
1
as
sp
e
c
i
f
i
e
d
on
th
e
Co
n
s
t
i
t
u
e
n
t
Lo
o
k
‐up
we
b
p
a
g
e
µԼ /c
m
in
d
i
c
a
t
e
s
mi
c
r
o
m
h
o
s
pe
r
ce
n
t
i
m
e
t
e
r
SW
S
ID
is
th
e
So
l
i
d
Wa
s
t
e
Se
c
t
i
o
n
Id
e
n
t
i
f
i
c
a
t
i
o
n
Nu
m
b
e
r
Ac
c
o
r
d
i
n
g
to
th
e
Co
n
s
t
i
t
u
e
n
t
Lo
o
k
‐up
we
b
p
a
g
e
on
th
e
NC
D
E
Q
Di
v
i
s
i
o
n
of
Wa
s
t
e
Ma
n
a
g
e
m
e
n
t
we
b
p
a
g
e
,
th
e
r
e
is
no
SW
S
L
fo
r
ch
o
r
i
d
e
de
t
e
r
m
i
n
e
d
wi
t
h
su
i
t
a
b
l
e
pr
e
c
i
s
i
o
n
an
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Carolinas Field #5193
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Laboratory #248
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Appendix A
Field Sampling Forms
STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 220.4 ŷŷŹ 227 227.0 ŷŷŹ 227
SS 73.4 ŷŷŹ 75 73.1 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)7.08 ŷŷŹ 7.02 7.03 ŷŷŹ 7.02
B (4.00)4.03 ŷŷŹ 4.00 4.03 ŷŷŹ 4.00
B (10.00)10.00 ŷŷŹ 10.06 9.99 ŷŷŹ 10.06
20.26 20.31
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
440 ŷŷŹ 440 438 ŷŷŹ 440
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.22 20.39
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.81 ŷŷŹ 8.92 8.95 ŷŷŹ 8.95
After Cal 8.92 100.00 9.01 100.63
LCS 8.97 100.56 8.93 99.74
LCSD 8.96 -0.11 8.94 0.11
SS 54.6 ŷŷŹ 53.4 54.9 ŷŷŹ 53.4
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
FIELD SAMPLING CALIBRATION FORM
DATE (s): January 30 - 31, 2017 SURFACE UNIT READER:
BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW WEATHER CONDITIONS:Clouds then clear, breezy, 32 - 45 deg F
LDC
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0730
ANALYZER MODEL#: HL4 400692
3210.6 VALIDATED BY:
Calibration Date / Time 30-Jan-17 400 31-Jan-17 340
HYDROLAB PROCEDURE #:
CALIBRATION BP (mmHg)738.46 CALIBRATION BP (mmHg)742.17
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
84.70 84.90
ORP Temp. ORP Temp.
DO
(mg/L)
19.47 19.54
738.46
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
742.17
CALIBRATION PASS CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 740.98 (mmHg)Ending BP 740.98
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R
SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R
de
ORP
TUR
(ntu
STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 227.0 ŷŷŹ 227 226.6 ŷŷŹ 227
SS 73.1 ŷŷŹ 75 73.2 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)7.03 ŷŷŹ 7.02 7.01 ŷŷŹ 7.02
B (4.00)4.03 ŷŷŹ 4.00 3.94 ŷŷŹ 4.00
B (10.00)9.99 ŷŷŹ 10.06 10.07 ŷŷŹ 10.04
20.31 20.54
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
438 ŷŷŹ 440 441 ŷŷŹ 440
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.39 20.36
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.95 ŷŷŹ 8.95 8.82 ŷŷŹ 8.86
After Cal 9.01 100.63 8.84 99.80
LCS 8.93 99.74 8.85 99.91
LCSD 8.94 0.11 8.88 0.34
SS 54.9 ŷŷŹ 53.4 54.6 ŷŷŹ 53.4
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
FIELD SAMPLING CALIBRATION FORM
DATE (s): January 30 - 31, 2017 SURFACE UNIT READER:
BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW WEATHER CONDITIONS:Clear, slight breeze, 25 to 45 deg F
LDC
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0722
ANALYZER MODEL#: HL4 400692
3210.6 VALIDATED BY:
Calibration Date / Time 31-Jan-17 340 1-Feb-17 605
HYDROLAB PROCEDURE #:
CALIBRATION BP (mmHg)742.17 CALIBRATION BP (mmHg)741.92
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
84.90 86.30
ORP Temp. ORP Temp.
DO
(mg/L)
19.54 20.06
742.17
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
741.92
CALIBRATION PASS CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 741.47 (mmHg)Ending BP 739.99
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R
SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R
de
ORP
TUR
(ntu
STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 220.6 ŷŷŹ 227 224.1 ŷŷŹ 227
SS 75.4 ŷŷŹ 75 74.9 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)6.98 ŷŷŹ 7.02 6.99 ŷŷŹ 7.02
B (4.00)3.97 ŷŷŹ 4.00 3.98 ŷŷŹ 4.00
B (10.00)10.03 ŷŷŹ 10.06 10.01 ŷŷŹ 10.06
20.36 19.81
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
443 ŷŷŹ 440 438 ŷŷŹ 441
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.33 20.17
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.85 ŷŷŹ 8.93 8.91 ŷŷŹ 8.97
After Cal 8.94 100.10 8.98 100.13
LCS 8.98 100.55 8.98 100.13
LCSD 8.96 -0.22 9.00 0.22
SS 52.7 ŷŷŹ 53.0 54.0 ŷŷŹ 53.0
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Beginning BP
DATE (s): January 30 - 31, 2017 SURFACE UNIT READER: PSP
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0662
ANALYZER MODEL#: HL4 400440
HYDROLAB PROCEDURE #:3210.6 VALIDATED BY:
Parameter
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clouds then clear, breezy, 32 - 45 deg F
CALIBRATION BP (mmHg)738.46 CALIBRATION BP (mmHg)742.17
Calibration Date / Time 30-Jan-17 340 31-Jan-17 500
Calibration Results Calibration Results
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
Buffer Temp.
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED
740.98
SS = Standard solution
TURB
(ntu)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
(mmHg)
ORP CALIBRATION ACCEPTED
Field Barometric Pressure
CALIBRATION ACCEPTED
Buffer Temp.
84.20
After Cal % SAT After Cal % SAT
CALIBRATION PASS
Replaced DO electrolyte See Notes
Buffer Temp.
See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK
See Notes
ORP Temp. ORP Temp.
86.60
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Cleaned Electrodes
INSTRUMENT MAINTENANCE DATE / TIME
DO
(mg/L)
19.41 19.46
738.46 742.17
CALIBRATION PASS
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Replaced ref Electrode KCL
LCSD = Lab Control Standard Duplicate
W = Winkler
Replaced Ref. Electrode Tip
pH Subsystem
Cleaned Electrodes
Conductance Subsystem
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK See Notes Tested - OK
(mmHg)
B = Buffer ŷŷŹ $GMXVWHG7R
N/A = Not Applicable
LCS = Lab Control Standard
Ending BP 740.98
ŷŷŹ 1RW$GMXVWHG7R
BP = Barometric Pressure
NOTES:
AW = Average Winkler
BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM
FIELD SAMPLING CALIBRATION FORM
WEATHER CONDITIONS:
de
ORP
TUR
(ntu
STUDY:
ANALYZER SERIAL #:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 224.1 ŷŷŹ 227 229.8 ŷŷŹ 227
SS 74.9 ŷŷŹ 75 75.2 ŷŷŹ 75
SS ŷŷŹ 1410 ŷŷŹ 1410
SS
B (7.00)6.99 ŷŷŹ 7.02 6.95 ŷŷŹ 7.02
B (4.00)3.98 ŷŷŹ 4.00 3.95 ŷŷŹ 4.00
B (10.00)10.01 ŷŷŹ 10.06 10.01 ŷŷŹ 10.04
19.81 20.68
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
438 ŷŷŹ 441 444 ŷŷŹ 440
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 20.17 20.44
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 8.91 ŷŷŹ 8.97 8.87 ŷŷŹ 8.86
After Cal 8.98 100.13 8.89 100.32
LCS 8.98 100.13 8.92 100.66
LCSD 9.00 0.22 8.94 0.22
SS 54.0 ŷŷŹ 53.0 52.4 ŷŷŹ 53.0
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
FIELD SAMPLING CALIBRATION FORM
DATE (s): January 30 - 31, 2017 SURFACE UNIT READER:
BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW WEATHER CONDITIONS:Clear, slight breeze, 25 to 45 deg F
PSP
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0970
ANALYZER MODEL#: HL4 400440
3210.6 VALIDATED BY:
Calibration Date / Time 31-Jan-17 500 1-Feb-17 540
HYDROLAB PROCEDURE #:
CALIBRATION BP (mmHg)742.17 CALIBRATION BP (mmHg)741.92
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
86.60 87.50
ORP Temp. ORP Temp.
DO
(mg/L)
19.46 20.04
742.17
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
741.92
CALIBRATION PASS CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 741.47 (mmHg)Ending BP 739.99
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R
SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R
de
ORP
TUR
(ntu
N/A
28.24 38.24
15 (psi)6 (sec) (sec)
(gal)
@
QC By:
SAMPLING PROCEDURE NO. 3175.4
CRW-2
NO
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
ACCESS TO WELLS
WELL CAPS
FLUSH MOUNT WELLS
< 2.0Sample preservation verified to pH
(units)
CHLORINE (mg/l)
INITIAL PURGE VOLUME 1.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.15 (gal)PSP 1/30/2017 1055 N/A
N/A
10:50 26.03 200 14.40 40 5.71 16.8 568 7.49 N/A
10:45 26.03 200 14.42 40 5.71 17.4 567 7.47
N/A
10:40 26.03 200 14.39 40 5.71 20.2 566 7.47 N/A
10:35 26.03 200 14.32 39 5.70 26.3 565 7.47
N/A
10:30 26.03 200 14.42 39 5.69 30.0 564 7.39 N/A
10:25 26.03 200 14.35 39 5.69 52.5 562 7.43
N/A
10:20 26.03 200 14.57 37 5.69 52.8 561 7.34 N/A
10:15 26.03 200 14.47 37 5.68 50.3 560 7.29
N/A
10:10 26.03 200 14.46 36 5.67 43.3 559 7.25 N/A
10:05 26.03 200 14.58 35 5.67 38.5 557 7.36
PURGE METHOD
Low Flow
WELL TYPE WELL INFORMATION
MONITORING WELL
SEE NOTE BELOW
COND. OXYGEN
14.11
WATER ELEVATION (ft msl) 737.33 WELL VOLUME
ODOR STRENGTH None
WELL/SAMPLING INFORMATION
(gal)
NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 38.24 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 37.00
28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
ELEV REF
RECHARGE DISCHARGE 6
SITE NAME
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
DUKE ENERGY
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 761.46 MIDDLE OF WETTED SCREEN (ft toc)33.24
SCREEN LENGTH (ft) 10
WELL USE
FOSSIL LANDFILL NPDES
PUMP CONTROLLER SETTINGS
PRESSURE
2.30
DETECTED ODOR None
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 24.13 WATER COLUMN (ft)
ORP DISSOLVED WELL VOL
STICK UP WELL
(recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (mg/L)
LEVEL
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(SU) (NTU)(mV-NHE)
Good Condition
Casing in good condition
Well Impacted By Silting:
DRAW-DOWN 1.90 (ft)
Lock in good conditionWELL LOCK CONDITION
Good Condition
LDC, PSP
SITE ID 85-04PERMIT #BELEWS CREEK STEAM STATION
FIELD CREWCRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM
SAMPLING NOTES
LIFT WELL CAP ONE FOOT UP FROM PVC WELL CASING AND PUMP AT 480 mL/min.
Access cleared around wellACCESS AROUND WELL
Well cap in good conditon
Well tag in good condition
Access cleared into well
Well found lockedWELL SECURITY
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
8.84 18.84
15 (psi)7 (sec) (sec)
(gal)
1.69 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 18.84 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 18.50
CRW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 746.39 MIDDLE OF WETTED SCREEN (ft toc)13.84
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
SEE NOTE BELOW PRESSURE RECHARGE DISCHARGE 3
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Turbid
WATER ELEVATION (ft msl) 737.91 WELL VOLUME 1.69
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 8.48 WATER COLUMN (ft) 10.36
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
2.75 NO 14.21 60 5.76 >1000 550
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
5.73
1.75 NO 14.43 62 5.74 418.0 520
3.92
1.75 NO 14.02 60 5.71 395.0 501
5.26
4.00 NO 14.02 62 5.60 62.6 531
4.75
1.75 NO 14.18 62 5.66 549.0 533
N/A N/A N/A
Sampled:N/A N/A N/A N/A
6.22
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
1245 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
12.00 PSP 1/30/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
LIFT WELL CAP ONE FOOT UP FROM PVC WELL CASING AND PUMP AT 528 mL/min.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
20.19 30.19
18 (psi)9 (sec) (sec)
(gal)
1.31 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 30.19 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00
CRW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 773.53 MIDDLE OF WETTED SCREEN (ft toc)26.19
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 751.35 WELL VOLUME 1.31
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 22.18 WATER COLUMN (ft) 8.01
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.50 NO 15.90 65 6.27 44.9 543
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
8.34
1.50 NO 15.88 64 6.27 15.9 550
8.43
1.50 NO 15.89 65 6.26 22.3 548
8.31
1.50 NO 15.90 64 6.25 11.8 556
8.31
1.50 NO 15.88 64 6.26 12.5 554
N/A N/A N/A
Sampled:N/A N/A N/A N/A
8.34
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
1330 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.50 PSP 1/30/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
13.16 23.16
18 (psi)10 (sec) (sec)
(gal)
1.00 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 23.16 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 22.50
CRW-5
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 764.74 MIDDLE OF WETTED SCREEN (ft toc)20.11
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 747.69 WELL VOLUME 1.00
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 17.05 WATER COLUMN (ft) 6.11
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.00 NO 15.39 93 5.92 49.8 264
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
0.00
1.00 NO 14.98 91 5.84 3.9 266
0.00
1.00 NO 15.06 91 5.87 17.1 265
0.00
N/A N/A N/A
Sampled:N/A N/A N/A N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:N/A
0825 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.00 PSP 1/31/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
20.20 30.20
18 (psi)9 (sec) (sec)
(gal)
0.92 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 30.20 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00
CRW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 783.10 MIDDLE OF WETTED SCREEN (ft toc)27.38
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 758.54 WELL VOLUME 0.92
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 24.56 WATER COLUMN (ft) 5.64
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.00 YES 16.92 65 5.09 34.5 543
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
0.00
1415 BELOW PUMP N/A
Sampled:1/31/2017 1100 24.56 0.92
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:1/30/2017
1100 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.00 PSP 1/30/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
19.90 29.90
18 (psi)5 (sec) (sec)
(gal)
0.39 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 29.90 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00
CRW-7
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 785.08 MIDDLE OF WETTED SCREEN (ft toc)28.70
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None No sample - insufficient volume / could not get dischargeAPPEARANCE
WATER ELEVATION (ft msl) 757.58 WELL VOLUME 0.39
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 27.50 WATER COLUMN (ft) 2.40
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
N/A N/A
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:
N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
0.00 PSP 1/30/2017
Sample preservation verified to pH
(units)N/A
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
30.18 40.18
18 (psi)10 (sec) (sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 40.18 GS ELEV (ft msl) 773.68 PUMP INTAKE DEPTH (ft TOC) 39.68
CRW-8R
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 776.39 MIDDLE OF WETTED SCREEN (ft toc)35.18
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 747.87 WELL VOLUME 1.90
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 28.52 WATER COLUMN (ft) 11.66
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(mV-NHE)(mg/L)
9:15 29.15 270 14.61 100 5.50 23.0 524
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
8.34 N/A
9:25 29.15 270 14.52 94 5.57 18.4 534
8.34 N/A
9:20 29.15 270 14.72 97 5.54 27.0 530
8.45 N/A
9:35 29.15 270 14.43 92 5.65 17.5 539
8.29 N/A
9:30 29.15 270 14.52 93 5.64 18.3 536
8.44 N/A
DRAW-DOWN 0.63 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 1.50 (gal)
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.95 (gal)PSP 1/31/2017 0940
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
Lift well cap up one foot from PVC well casing, pump at 330 mL/min with settings indicated above and remove 2 gallons prior to recording low flow parameters.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
29.62 39.62
18 (psi)10 (sec) (sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 39.62 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 38.50
CRW-9
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 769.67 MIDDLE OF WETTED SCREEN (ft toc)34.62
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 742.51 WELL VOLUME 2.03
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 27.16 WATER COLUMN (ft) 12.46
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(mV-NHE)(mg/L)
10:05 28.57 300 15.38 52 5.77 18.7 535
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
6.87 N/A
10:15 28.57 300 15.52 50 5.76 15.6 548
6.72 N/A
10:10 28.57 300 15.51 49 5.74 17.5 542
6.88 N/A
DRAW-DOWN 1.41 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 0.75 (gal)
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.55 (gal)PSP 1/31/2017 1020
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
20.16 30.16
18 (psi)14 (sec) (sec)
(gal)
1.05 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 30.16 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00
CRW-10
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 777.23 MIDDLE OF WETTED SCREEN (ft toc)26.95
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 753.49 WELL VOLUME 1.05
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 23.74 WATER COLUMN (ft) 6.42
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.25 24.92 NO 14.10 226 5.62 67.1 632
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
1.66 0.70
0.75 26.98 NO 13.88 199 5.60 64.7 558
1.55 0.85
1.00 25.88 NO 14.30 210 5.58 43.3 575
3.62
0.75 NO 13.70 195 5.57 5.4 542
2.55 0.52
0.75 NO 13.67 196 5.58 10.0 545
N/A N/A
Sampled:
3.57
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:
0850 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 LDC 1/31/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
Had to thaw discharge line.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
28.52 38.52
15 (psi)10 (sec) (sec)
(gal)
815 (ml)
495 (ml)
1310 (ml)=0.35 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC) 38.52 GS ELEV (ft msl) 813.38 PUMP INTAKE DEPTH (ft TOC) 37.52
CRW-11
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 816.12 MIDDLE OF WETTED SCREEN (ft toc)34.81
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 785.02 WELL VOLUME 1.21
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 31.10 WATER COLUMN (ft) 7.42
OXYGEN
(ft) (ml/min) (ft) (deg C) (umho/cm) (SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
477 8.48 N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
31.10 160 31.76 14.06 125 6.34 9.3
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME
N/A N/A
Sample:
Total Purge Volume LDC 1/31/2017 0945 N/A
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
34.65 44.65
20 (psi)10 (sec) (sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 44.65 GS ELEV (ft msl) 835.00 PUMP INTAKE DEPTH (ft TOC) 44.15
CRW-12
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 837.93 MIDDLE OF WETTED SCREEN (ft toc)40.59
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 801.41 WELL VOLUME 1.33
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 36.52 WATER COLUMN (ft) 8.13
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(mV-NHE)(mg/L)
8:15 37.13 150 12.74 53 5.56 16.2 560
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
7.78 N/A
8:25 37.13 150 13.42 54 5.53 9.4 557
7.93 N/A
8:20 37.13 150 13.17 53 5.53 10.7 558
7.75 N/A
DRAW-DOWN 0.61 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 0.50 (gal)
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.90 (gal)LDC 1/30/2017 0830
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
Lift well cap 3 feet up from top of well casing.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
29.28 39.28
19 (psi)10 (sec) (sec)
(gal)
0.85 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR CONVENTIONAL SAMPLING
WELL DEPTH (ft TOC) 39.28 GS ELEV (ft msl)819.44 PUMP INTAKE DEPTH (ft TOC) 38.78
CRW-13
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 822.49 MIDDLE OF WETTED SCREEN (ft toc)36.68
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional
PUMP CONTROLLER SETTINGS
SEE NOTE BELOW PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 788.41 WELL VOLUME 0.85
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 34.08 WATER COLUMN (ft) 5.20
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(mV -NHE)(mg/L)
1.00 NO 13.17 141 6.02 13.7 529
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
WELL VOL
VOLUME EVACUATION COND. OXYGEN (recalculates on
current water level)
7.97
1.00 NO 12.34 150 6.03 10.5 509
8.03
1.00 NO 12.53 147 6.02 11.1 518
7.99
8.10
1.00 NO 12.88 151 6.03 6.8 503
N/A N/A
Sampled:
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: WELL VOL:
Evacuated:
0955 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.00 LDC 1/30/2017
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
Pump at 230 mL/min.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WTU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
26.44 41.44
20 (psi)5 (sec) (sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 41.44 GS ELEV (ft msl) 792.23 PUMP INTAKE DEPTH (ft TOC) 40.44
CRW-14
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 794.87 MIDDLE OF WETTED SCREEN (ft toc)33.94
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 15 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 771.31 WELL VOLUME 2.92
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 23.56 WATER COLUMN (ft) 17.88
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(mV-NHE)(mg/L)
10:25 23.79 400 14.45 401 6.55 7.1 486
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
2.39 N/A
10:35 23.79 400 14.75 345 6.33 4.0 488
1.97 N/A
10:30 23.79 400 14.73 377 6.46 5.0 485
4.96 N/A
10:45 23.79 400 14.85 283 6.09 2.9 499
3.53 N/A
10:40 23.79 400 14.80 302 6.17 3.0 494
5.96 N/A
10:55 23.79 400 14.83 266 5.97 5.4 505
5.54 N/A
10:50 23.79 400 14.90 270 6.03 3.9 502
6.46 N/A
6.29 N/A
11:00 23.79 400 14.86 266 5.95 5.4 508
DRAW-DOWN 0.23 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 0.50 (gal)
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.20 (gal)LDC 1/30/2017 1105
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
28.82 38.82
25 (psi)11 (sec) (sec)
(gal)
832 (ml)
495 (ml)
1327 (ml)=0.35 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC) 38.82 GS ELEV (ft msl) 765.69 PUMP INTAKE DEPTH (ft TOC) 38.32
CRW-15
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 768.43 MIDDLE OF WETTED SCREEN (ft toc)37.51
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 732.23 WELL VOLUME 0.43
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 36.20 WATER COLUMN (ft) 2.62
OXYGEN
(ft) (ml/min) (ft) (deg C) (umho/cm) (SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
504 8.22 N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
36.20 114 Below pump 13.48 94 5.76 2.1
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME
N/A N/A
Sampled:
Total Purge Volume LDC 1/30/2017 1145 N/A
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
Pump needs top check valve.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
40.66 50.66
20 (psi)10 (sec) (sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
WELL DEPTH (ft TOC) 50.66 GS ELEV (ft msl) 770.58 PUMP INTAKE DEPTH (ft TOC) 47.66
CRW-16
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 773.59 MIDDLE OF WETTED SCREEN (ft toc)47.00
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 730.26 WELL VOLUME 1.20
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 43.33 WATER COLUMN (ft) 7.33
ORP DISSOLVED WELL VOL
LEVEL COND.
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY
(mV-NHE)(mg/L)
8:35 43.91 192 12.46 68 5.68 218.0 576
OXYGEN (recalculates on
current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU)
3.24 N/A
8:45 43.91 192 12.36 70 5.69 58.7 567
3.30 N/A
8:40 43.91 192 12.37 69 5.69 117.0 572
3.19 N/A
8:55 43.91 192 11.96 70 5.68 28.0 562
3.20 N/A
8:50 43.91 192 12.30 70 5.69 36.0 565
3.19 N/A
9:05 43.91 192 12.06 70 5.68 13.6 557
3.19 N/A
9:00 43.91 192 12.12 71 5.68 15.0 559
3.26 N/A
3.21 N/A
9:10 43.91 192 11.80 70 5.68 10.7 556
DRAW-DOWN 0.58 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)
INITIAL PURGE VOLUME 1.50 (gal)
N/A
SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.30 (gal)PSP 1/30/2017 0915
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Debris covering well pad Well Impacted By Silting:NO
SAMPLING NOTES
LIFT WELL CAP FIVE FOOT UP FROM PVC WELL CASING AND PUMP AT 150 mL/min.
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISS WETU
GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
31.70 41.70
15 (psi)10 (sec) (sec)
(gal)
884 (ml)
495 (ml)
1379 (ml)=0.36 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
WELL DEPTH (ft TOC) 41.70 GS ELEV (ft msl) 831.62 PUMP INTAKE DEPTH (ft TOC) 40.70
CRW-17
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 834.56 MIDDLE OF WETTED SCREEN (ft toc)38.61
SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
EQUIPMENT INFORMATION
SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
WATER ELEVATION (ft msl) 799.05 WELL VOLUME 1.01
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 35.51 WATER COLUMN (ft) 6.19
OXYGEN
(ft) (ml/min) (ft) (deg C) (umho/cm) (SU)
TURBIDITY ORP DISSOLVED
WATER LEVEL RATE WATER LEVEL COND.
INITIAL FLOW FINAL TEMP SPECIFIC pH
497 6.38 N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE: TIME: WATER LEVEL: Well Vol.:
Evacuated:
(NTU)(mV -NEH)(mg/L)
35.51 110 35.78 14.80 70 5.81 3.4
Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME
N/A N/A
Sample:
Total Purge Volume LDC 1/31/2017 1030 N/A
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Casing in good condition
FLUSH MOUNT WELLS
WELL CAPS Well cap in good conditon
WELL CASING Good Condition
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting:NO
SAMPLING NOTES
WELL SECURITY Well found locked
WELL LOCK CONDITION Lock in good condition
WELL TAG Well tag in good condition
ACCESS AROUND WELL Access cleared around well
30 31
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-1SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
LDC 1/31/2017 0910 N/A
Sample preservation verified to pH
(units)< 2.0
4.4 407 10.36 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 4.89 107 6.51
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
Filtered metal collected at 0925 hrs
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-2SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
PSP 1/31/2017 1040 N/A
Sample preservation verified to pH
(units)< 2.0
3.4 296 11.69 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 4.84 116 6.51
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-3SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED LOCATION DRY
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: NO WAS THERE A NOTICABLE FLOW: NO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None NO SAMPLE - LOCATION WAS DRYAPPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
PSP 1/30/2017 0940 N/A
Sample preservation verified to pH
(units)< 2.0
N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-4SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
PSP 1/30/2017 1145 N/A
Sample preservation verified to pH
(units)< 2.0
5.2 416 4.57 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 11.90 107 5.83
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-5SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: PERISTALTIC PUMP LOCATION ENVIRONMENT: WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Oil/Sheen
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
PSP 1/31/2017 0850 N/A
Sample preservation verified to pH
(units)< 2.0
26.5 329 6.01 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
0.10 10.94 80 5.70
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CRS-6SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: PERISTALTIC PUMP LOCATION ENVIRONMENT: WOODED
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
LDC 1/31/2017 1115 N/A
Sample preservation verified to pH
(units)< 2.0
12.7 492 8.19 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
0.10 14.94 98 5.86
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
Filtered metal collected at 1130 hrs
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CWB-1SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
LDC 1/30/2017 1250 N/A
Sample preservation verified to pH
(units)< 2.0
1.4 555 9.32 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
0.10 14.40 4344 4.69
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS Location formerly known as E-WWB-Leachate
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CWB-2SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
LDC 1/30/2017 1220 N/A
Sample preservation verified to pH
(units)< 2.0
1.3 596 8.50 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
0.10 16.05 6389 3.81
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS Location formerly known as W-WWB-Leachate
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
0
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID
PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
CWB-3SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME
SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE LOCATION DRY
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: NO WAS THERE A NOTICABLE FLOW: NO
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None NO SAMPLE - LOCATION WAS DRYAPPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
INTAKE COND. OXYGEN
TIME
PSP 1/30/2017 0930 N/A
Sample preservation verified to pH
(units)< 2.0
N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
0
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
30 31
T SP DISSTU
GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
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pH (units)TURBIDITY (NTU's)ORP (mV-NHE)DO (mg/L)
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4
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5
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7
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6
2
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N
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A
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3
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4
8
9
4
5
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6
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2
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3
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6
5
0
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6
6
4
3
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3
3
7
3
0
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2
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N
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n
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L
F
1
9
2
.
0
0
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2
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3
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/
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1
1
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8
0
7
0
5
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6
8
1
0
.
7
5
5
6
3
.
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6
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3
1
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0
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7
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R
W
-
1
7
4
1
.
7
0
3
5
.
5
1
7
9
9
.
0
5
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r
m
a
l
N
o
n
e
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O
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N
/
A
1
.
0
1
0
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5
0
N
/
A
1
4
.
8
0
7
0
5
.
8
1
3
.
4
4
9
7
6
.
3
8
1/
3
1
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2
0
1
7
C
R
S
-
1
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
A
4
.
8
9
1
0
7
6
.
5
1
4
.
4
4
0
7
1
0
.
3
6
1/
3
1
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2
0
1
7
C
R
S
-
2
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
A
4
.
8
4
1
1
6
6
.
5
1
3
.
4
2
9
6
1
1
.
6
9
1/
3
0
/
2
0
1
7
C
R
S
-
3
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
A
0
.
0
0
0
0
.
0
0
0
.
0
0
0
.
0
0
1/
3
0
/
2
0
1
7
C
R
S
-
4
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
A
1
1
.
9
0
1
0
7
5
.
8
3
5
.
2
4
1
6
4
.
5
7
1/
3
1
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0
1
7
C
R
S
-
5
0
.
0
0
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i
l
/
S
h
e
e
n
N
o
n
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S
W
S
N
/
A
N
/
A
N
/
A
1
0
.
9
4
8
0
5
.
7
0
2
6
.
5
3
2
9
6
.
0
1
1/
3
1
/
2
0
1
7
C
R
S
-
6
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
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N
/
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1
4
.
9
4
9
8
5
.
8
6
1
2
.
7
4
9
2
8
.
1
9
1/
3
0
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2
0
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7
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W
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-
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0
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0
0
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o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
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1
4
.
4
0
4
3
4
4
4
.
6
9
1
.
4
5
5
5
9
.
3
2
1/
3
0
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2
0
1
7
C
W
B
-
2
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
W
S
N
/
A
N
/
A
N
/
A
1
6
.
0
5
6
3
8
9
3
.
8
1
1
.
3
5
9
6
8
.
5
0
1/
3
0
/
2
0
1
7
C
W
B
-
3
0
.
0
0
N
o
r
m
a
l
N
o
n
e
S
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S
N
/
A
N
/
A
N
/
A
0
.
0
0
0
0
.
0
0
0
.
0
0
0
.
0
0
Pu
r
g
e
M
e
t
h
o
d
s
LF
=
L
o
w
F
l
o
w
NP
=
N
o
P
u
r
g
e
EO
P
=
E
q
u
i
p
.
O
n
l
y
P
u
r
g
e
L
O
=
L
e
v
e
l
O
n
l
y
L
F
(
M
)
=
L
o
w
F
l
o
w
(
M
o
d
.
)
*
=
A
p
p
l
i
c
a
b
l
e
t
o
L
F
&
L
F
(
M
)
P
u
r
g
i
n
g
O
n
l
y
C
=
C
o
n
n
v
e
n
t
i
o
n
a
l
BE
L
E
W
S
C
R
E
E
K
S
T
E
A
M
S
T
A
T
I
O
N
CR
A
I
G
R
O
A
D
L
A
N
D
F
I
L
L
G
R
O
U
N
D
W
A
T
ER
M
O
N
I
T
O
R
I
N
G
P
R
O
G
R
A
M
GR
O
U
N
D
W
A
T
E
R
M
O
N
I
T
O
R
I
N
G
F
I
E
L
D
D
A
T
A
PE
R
M
I
T
#
8
5
-
0
4
B
Appendix B
Laboratory Report and
Chain-of-Custody Forms
13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: 980-875-5245 Fax: 980-875-4349
Order Summary Report
Analytical Laboratory
Order Number:J16120415
Project Name:BELEWS - GW CRAIG ROAD LF
Lab Contact: Anne Pridgeon
Date:2/10/2017
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: 980-875-6610
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Page 1 of 41
Reason: I have reviewed
this document.
Date: 2017.02.14 16:21:47
-05'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016040257 BELEWS 30-Jan-17 10:55 AM PSP CRW-2
2016040258 BELEWS 30-Jan-17 12:45 PM PSP CRW-3
2016040259 BELEWS 30-Jan-17 1:30 PM PSP CRW-4
2016040260 BELEWS 31-Jan-17 8:25 AM PSP CRW-5
2016040261 BELEWS 31-Jan-17 11:00 AM PSP CRW-6
2016040263 BELEWS 31-Jan-17 9:40 AM PSP CRW-8R
2016040264 BELEWS 31-Jan-17 10:20 AM PSP CRW-9
2016040265 BELEWS 31-Jan-17 8:50 AM LDC CRW-10
2016040266 BELEWS 31-Jan-17 9:45 AM LDC CRW-11
2016040267 BELEWS 30-Jan-17 8:30 AM LDC CRW-12
2016040268 BELEWS 30-Jan-17 9:55 AM LDC CRW-13
2016040269 BELEWS 30-Jan-17 11:05 AM LDC CRW-14
2016040270 BELEWS 30-Jan-17 11:45 AM LDC CRW-15
2016040271 BELEWS 30-Jan-17 9:15 AM PSP CRW-16
2016040272 BELEWS 31-Jan-17 10:30 AM LDC CRW-17
2016040273 BELEWS 30-Jan-17 12:50 PM LDC CWB-1
2016040274 BELEWS 30-Jan-17 12:20 PM LDC CWB-2
2016040276 BELEWS 31-Jan-17 9:10 AM LDC CRS-1
2016040277 BELEWS 31-Jan-17 10:40 AM PSP CRS-2
2016040279 BELEWS 30-Jan-17 11:45 AM PSP CRS-4
2016040280 BELEWS 31-Jan-17 8:50 AM PSP CRS-5
2016040281 BELEWS 31-Jan-17 11:15 AM LDC CRS-6
2016040284 BELEWS 31-Jan-17 11:30 AM PSP FIELD BLANK
23 Total Samples
Page 2 of 41
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/10/2017
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040257
Collection Date:30-Jan-17 10:55 AM
Site:CRW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)14 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.8 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1
Nitrate 0.32 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1
Nitrate as N 0.07 mg-N/L EPA 9056A 01/31/2017 08:37 BGN90340.023 1
Sulfate 0.34 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:45 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.049 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.05 1
Calcium (Ca)2.33 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.01 1
Chromium (Cr)0.007 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Iron (Fe)1.11 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.01 1
Magnesium (Mg)1.26 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Manganese (Mn)0.015 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
Potassium (K)2.64 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.1 1
Sodium (Na)3.16 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.05 1
Zinc (Zn)0.008 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 54 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 4 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040258
Collection Date:30-Jan-17 12:45 PM
Site:CRW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)16 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.8 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1
Nitrate 0.66 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1
Nitrate as N 0.15 mg-N/L EPA 9056A 01/31/2017 09:27 BGN90340.023 1
Sulfate 5.3 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:53 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.05 1
Calcium (Ca)3.82 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.01 1
Chromium (Cr)0.008 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Iron (Fe)3.17 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.01 1
Magnesium (Mg)2.72 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Manganese (Mn)0.059 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
Potassium (K)2.58 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.1 1
Sodium (Na)4.03 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.05 1
Zinc (Zn)0.012 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311
Lead (Pb)1.44 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 89 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 5 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040259
Collection Date:30-Jan-17 1:30 PM
Site:CRW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.4 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1
Nitrate 4.2 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1
Nitrate as N 0.95 mg-N/L EPA 9056A 01/31/2017 09:44 BGN90340.023 1
Sulfate 2.1 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.006 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.05 1
Calcium (Ca)4.69 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Iron (Fe)0.720 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.01 1
Magnesium (Mg)1.58 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Manganese (Mn)0.011 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
Potassium (K)1.90 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.1 1
Sodium (Na)5.22 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 73 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 6 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040260
Collection Date:31-Jan-17 8:25 AM
Site:CRW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)27 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.4 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:24 BGN90340.023 1
Sulfate 13 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:58 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.014 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 10:48 MHH71310.05 1
Calcium (Ca)3.39 mg/L SW 6010D 02/07/2017 10:48 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Iron (Fe)6.95 mg/L SW 6010D 02/07/2017 10:48 MHH71310.01 1
Magnesium (Mg)2.80 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Manganese (Mn)0.098 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Nickel (Ni)0.012 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
Potassium (K)1.49 mg/L SW 6010D 02/07/2017 10:48 MHH71310.1 1
Sodium (Na)4.34 mg/L SW 6010D 02/07/2017 10:48 MHH71310.05 1
Zinc (Zn)0.017 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 78 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 7 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040261
Collection Date:31-Jan-17 11:00 AM
Site:CRW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:41 BGN90340.023 1
Sulfate 22 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:00 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:00 MHH71310.05 1
Calcium (Ca)3.22 mg/L SW 6010D 02/07/2017 11:00 MHH71310.01 1
Chromium (Cr)0.005 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Copper (Cu)0.005 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Iron (Fe)2.89 mg/L SW 6010D 02/07/2017 11:00 MHH71310.01 1
Magnesium (Mg)2.87 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Manganese (Mn)0.118 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Nickel (Ni)0.020 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
Potassium (K)2.47 mg/L SW 6010D 02/07/2017 11:00 MHH71310.1 1
Sodium (Na)3.89 mg/L SW 6010D 02/07/2017 11:00 MHH71310.05 1
Zinc (Zn)0.022 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11
Lead (Pb)1.63 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 76 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 8 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040263
Collection Date:31-Jan-17 9:40 AM
Site:CRW-8R
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1
Nitrate 14 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.5 5
Nitrate as N 3.1 mg-N/L EPA 9056A 02/01/2017 10:09 BGN90340.023 1
Sulfate 1.4 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:03 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.066 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:04 MHH71310.05 1
Calcium (Ca)6.91 mg/L SW 6010D 02/07/2017 11:04 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Iron (Fe)0.651 mg/L SW 6010D 02/07/2017 11:04 MHH71310.01 1
Magnesium (Mg)2.62 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Manganese (Mn)0.011 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
Potassium (K)2.61 mg/L SW 6010D 02/07/2017 11:04 MHH71310.1 1
Sodium (Na)4.82 mg/L SW 6010D 02/07/2017 11:04 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 90 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 9 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040264
Collection Date:31-Jan-17 10:20 AM
Site:CRW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)15 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.3 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1
Nitrate 2.6 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1
Nitrate as N 0.60 mg-N/L EPA 9056A 02/01/2017 10:26 BGN90340.023 1
Sulfate 1.7 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:05 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.017 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:08 MHH71310.05 1
Calcium (Ca)4.00 mg/L SW 6010D 02/07/2017 11:08 MHH71310.01 1
Chromium (Cr)0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Iron (Fe)0.793 mg/L SW 6010D 02/07/2017 11:08 MHH71310.01 1
Magnesium (Mg)1.03 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Manganese (Mn)0.011 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
Potassium (K)2.16 mg/L SW 6010D 02/07/2017 11:08 MHH71310.1 1
Sodium (Na)3.40 mg/L SW 6010D 02/07/2017 11:08 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 55 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 10 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040265
Collection Date:31-Jan-17 8:50 AM
Site:CRW-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)15 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 9056A 02/01/2017 12:58 BGN9034110
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:58 BGN90340.1 1
Nitrate 2.0 mg/L EPA 9056A 02/01/2017 12:58 BGN90340.1 1
Nitrate as N 0.45 mg-N/L EPA 9056A 02/01/2017 12:58 BGN90340.023 1
Sulfate 49 mg/L EPA 9056A 02/01/2017 12:58 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:07 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.011 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:12 MHH71310.05 1
Calcium (Ca)16.9 mg/L SW 6010D 02/07/2017 11:12 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Iron (Fe)0.356 mg/L SW 6010D 02/07/2017 11:12 MHH71310.01 1
Magnesium (Mg)5.94 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Manganese (Mn)0.029 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
Potassium (K)3.49 mg/L SW 6010D 02/07/2017 11:12 MHH71310.1 1
Sodium (Na)7.22 mg/L SW 6010D 02/07/2017 11:12 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 11 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040266
Collection Date:31-Jan-17 9:45 AM
Site:CRW-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)39 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1
Nitrate 12 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.5 5
Nitrate as N 2.8 mg-N/L EPA 9056A 02/01/2017 13:15 BGN90340.023 1
Sulfate 0.63 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:10 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.022 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:16 MHH71310.05 1
Calcium (Ca)10.9 mg/L SW 6010D 02/07/2017 11:16 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Iron (Fe)0.191 mg/L SW 6010D 02/07/2017 11:16 MHH71310.01 1
Magnesium (Mg)5.14 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
Potassium (K)1.48 mg/L SW 6010D 02/07/2017 11:16 MHH71310.1 1
Sodium (Na)4.82 mg/L SW 6010D 02/07/2017 11:16 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 94 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 12 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040267
Collection Date:30-Jan-17 8:30 AM
Site:CRW-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)21 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1
Nitrate 1.2 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1
Nitrate as N 0.27 mg-N/L EPA 9056A 01/31/2017 10:01 BGN90340.023 1
Sulfate 0.16 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:12 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.022 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.05 1
Calcium (Ca)3.88 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Iron (Fe)0.358 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.01 1
Magnesium (Mg)1.39 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Manganese (Mn)0.010 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
Potassium (K)2.08 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.1 1
Sodium (Na)4.73 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 60 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 13 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040268
Collection Date:30-Jan-17 9:55 AM
Site:CRW-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)38 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1
Nitrate 8.5 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 9056A 01/31/2017 12:00 BGN90340.023 1
Sulfate 1.1 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:13 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.019 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.05 1
Calcium (Ca)12.9 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Iron (Fe)0.326 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.01 1
Magnesium (Mg)6.92 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
Potassium (K)1.70 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.1 1
Sodium (Na)5.42 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 14 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040269
Collection Date:30-Jan-17 11:05 AM
Site:CRW-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)38 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 29 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5
Fluoride 0.23 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.1 1
Nitrate 19 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5
Nitrate as N 4.3 mg-N/L EPA 9056A 01/31/2017 12:16 BGN90340.023 1
Sulfate 23 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.05 1
Calcium (Ca)18.9 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Iron (Fe)0.187 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.01 1
Magnesium (Mg)6.43 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Manganese (Mn)0.016 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
Potassium (K)3.71 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.1 1
Sodium (Na)21.2 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.05 1
Zinc (Zn)0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 15 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040270
Collection Date:30-Jan-17 11:45 AM
Site:CRW-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1
Nitrate 0.40 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1
Nitrate as N 0.09 mg-N/L EPA 9056A 01/31/2017 12:33 BGN90340.023 1
Sulfate 2.9 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:23 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.010 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.05 1
Calcium (Ca)6.24 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Iron (Fe)0.048 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.01 1
Magnesium (Mg)2.90 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Manganese (Mn)0.007 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
Potassium (K)2.87 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.1 1
Sodium (Na)5.66 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.05 1
Zinc (Zn)0.012 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 71 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 16 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040271
Collection Date:30-Jan-17 9:15 AM
Site:CRW-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)24 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.9 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1
Nitrate 0.36 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1
Nitrate as N 0.08 mg-N/L EPA 9056A 01/31/2017 11:09 BGN90340.023 1
Sulfate 1.3 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:25 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.05 1
Calcium (Ca)5.25 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Iron (Fe)0.369 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.01 1
Magnesium (Mg)1.45 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Manganese (Mn)0.011 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
Potassium (K)2.01 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.1 1
Sodium (Na)6.27 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 65 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 17 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040272
Collection Date:31-Jan-17 10:30 AM
Site:CRW-17
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.1 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1
Nitrate 0.14 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 9056A 02/01/2017 11:17 BGN90340.023 1
Sulfate 0.25 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:28 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.051 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:20 MHH71310.05 1
Calcium (Ca)1.26 mg/L SW 6010D 02/07/2017 11:20 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Iron (Fe)0.404 mg/L SW 6010D 02/07/2017 11:20 MHH71310.01 1
Magnesium (Mg)0.576 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Manganese (Mn)0.010 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
Potassium (K)2.12 mg/L SW 6010D 02/07/2017 11:20 MHH71310.1 1
Sodium (Na)16.7 mg/L SW 6010D 02/07/2017 11:20 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 18 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040273
Collection Date:30-Jan-17 12:50 PM
Site:CWB-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 430 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550
Fluoride < 5 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550
Nitrate 120 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550
Nitrate as N 27 mg-N/L EPA 9056A 01/31/2017 12:50 BGN90340.023 1
Sulfate 2200 mg/L EPA 9056A 01/31/2017 12:50 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:30 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
Boron (B)38.1 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.5 10
Calcium (Ca)524 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
Iron (Fe)0.014 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.01 1
Magnesium (Mg)149 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.05 10
Manganese (Mn)19.0 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
Nickel (Ni)0.106 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
Potassium (K)82.5 mg/L SW 6010D 02/01/2017 14:57 JJMACKE110
Sodium (Na)189 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.5 10
Zinc (Zn)0.242 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)29.4 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311
Cadmium (Cd)3.79 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311
Lead (Pb)5.71 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311
Selenium (Se)104 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3100 mg/L SM2540C 02/02/2017 14:30 MGIGANT5001
Page 19 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040274
Collection Date:30-Jan-17 12:20 PM
Site:CWB-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 320 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100
Fluoride < 10 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100
Nitrate 170 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100
Nitrate as N 37 mg-N/L EPA 9056A 01/31/2017 13:07 BGN90340.023 1
Sulfate 4200 mg/L EPA 9056A 01/31/2017 13:07 BGN90341001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:32 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.025 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
Boron (B)73.1 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 10
Calcium (Ca)421 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
Copper (Cu)0.006 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
Iron (Fe)0.042 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.01 1
Magnesium (Mg)359 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 100
Manganese (Mn)19.2 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
Nickel (Ni)0.240 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
Potassium (K)189 mg/L SW 6010D 02/01/2017 15:13 JJMACKE110
Sodium (Na)298 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 10
Zinc (Zn)0.555 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)40.5 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311
Cadmium (Cd)7.25 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311
Lead (Pb)11.1 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311
Selenium (Se)191 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3800 mg/L SM2540C 02/02/2017 14:30 MGIGANT5001
Page 20 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040276
Collection Date:31-Jan-17 9:10 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)26 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.4 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1
Nitrate 0.60 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1
Nitrate as N 0.14 mg-N/L EPA 9056A 02/01/2017 11:34 BGN90340.023 1
Sulfate 9.0 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:35 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:24 MHH71310.05 1
Calcium (Ca)8.63 mg/L SW 6010D 02/07/2017 11:24 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Iron (Fe)0.281 mg/L SW 6010D 02/07/2017 11:24 MHH71310.01 1
Magnesium (Mg)3.76 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Manganese (Mn)0.034 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
Potassium (K)1.88 mg/L SW 6010D 02/07/2017 11:24 MHH71310.1 1
Sodium (Na)5.66 mg/L SW 6010D 02/07/2017 11:24 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 92 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 21 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040277
Collection Date:31-Jan-17 10:40 AM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.4 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.1 1
Nitrate 0.27 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 9056A 02/01/2017 13:31 BGN90340.023 1
Sulfate 16 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.022 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:29 MHH71310.05 1
Calcium (Ca)9.18 mg/L SW 6010D 02/07/2017 11:29 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Iron (Fe)0.834 mg/L SW 6010D 02/07/2017 11:29 MHH71310.01 1
Magnesium (Mg)3.56 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Manganese (Mn)0.092 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
Potassium (K)1.97 mg/L SW 6010D 02/07/2017 11:29 MHH71310.1 1
Sodium (Na)5.44 mg/L SW 6010D 02/07/2017 11:29 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 88 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 22 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040279
Collection Date:30-Jan-17 11:45 AM
Site:CRS-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)20 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.4 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1
Nitrate 2.0 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1
Nitrate as N 0.45 mg-N/L EPA 9056A 01/31/2017 16:30 BGN90340.023 1
Sulfate 17 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.014 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Boron (B)0.070 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.05 1
Calcium (Ca)8.78 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Iron (Fe)0.578 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.01 1
Magnesium (Mg)3.20 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Manganese (Mn)0.038 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
Potassium (K)2.46 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.1 1
Sodium (Na)5.60 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.05 1
Zinc (Zn)0.007 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 95 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 23 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040280
Collection Date:31-Jan-17 8:50 AM
Site:CRS-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B 02/01/2017 14:49 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.2 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:07 BGN90340.023 1
Sulfate 10 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 14:59 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:33 MHH71310.05 1
Calcium (Ca)3.91 mg/L SW 6010D 02/07/2017 11:33 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Iron (Fe)5.87 mg/L SW 6010D 02/07/2017 11:33 MHH71310.01 1
Magnesium (Mg)2.46 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Manganese (Mn)0.264 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
Potassium (K)2.05 mg/L SW 6010D 02/07/2017 11:33 MHH71310.1 1
Sodium (Na)3.91 mg/L SW 6010D 02/07/2017 11:33 MHH71310.05 1
Zinc (Zn)0.013 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 57 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 24 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040281
Collection Date:31-Jan-17 11:15 AM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)28 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1
Nitrate 1.9 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1
Nitrate as N 0.42 mg-N/L EPA 9056A 02/01/2017 15:31 BGN90340.023 1
Sulfate 5.7 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 15:02 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:49 MHH71310.05 1
Calcium (Ca)7.10 mg/L SW 6010D 02/07/2017 11:49 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Iron (Fe)0.644 mg/L SW 6010D 02/07/2017 11:49 MHH71310.01 1
Magnesium (Mg)3.66 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Manganese (Mn)0.364 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
Potassium (K)1.67 mg/L SW 6010D 02/07/2017 11:49 MHH71310.1 1
Sodium (Na)5.01 mg/L SW 6010D 02/07/2017 11:49 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11
TOTAL DISSOLVED SOLIDS
TDS 64 mg/L SM2540C 02/02/2017 14:30 MGIGANT251
Page 25 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
2016040284
Collection Date:31-Jan-17 11:30 AM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 02/01/2017 08:49 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 15:48 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 15:04 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:53 MHH71310.05 1
Calcium (Ca)< 0.01 mg/L SW 6010D 02/07/2017 11:53 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 02/07/2017 11:53 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 02/07/2017 11:53 MHH71310.1 1
Sodium (Na)< 0.05 mg/L SW 6010D 02/07/2017 11:53 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11
Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11
Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11
Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11
Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11
Page 26 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020024 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16120415 -- 2016040259
Alkalinity (mg/L CaCO3)5.52mg/L (CaCO3)-120.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 52.5 88.3mg/L (CaCO3)-12080146.4
Page 27 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020036 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16120415 -- 2016040257
Alkalinity (mg/L CaCO3)5.86mg/L (CaCO3)-115.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 26.25 85.9mg/L (CaCO3)-12080122.6
Page 28 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17010649 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.032 mg/L -10.032 0.1 < 1/2 RDL
Fluoride 0.0142 mg/L -10.0142 0.1 < 1/2 RDL
Nitrate 0.0366 mg/L -10.0366 0.1 < 1/2 RDL
Sulfate -0.0233 mg/L -1-0.0233 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.24 10 107mg/L -12080212.5
Fluoride 4.74 10 94.2mg/L -1208029.48
Nitrate 5.37 10 104mg/L -12080210.7
Sulfate 5.41 10 105mg/L -12080210.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.25 10 107 0.243mg/L -12080212.5
Fluoride 4.76 10 94.5 3.41mg/L -1208029.51
Nitrate 5.4 10 104 0.559mg/L -12080210.8
Sulfate 5.41 10 105 0.133mg/L -12080210.8
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.93 5 98.6mg/L -1208014.93
Fluoride 5.21 5 104mg/L -1208015.21
Nitrate 4.87 5 97.4mg/L -1208014.87
Sulfate 4.88 5 97.7mg/L -1208014.88
Page 29 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020003 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0259 mg/L -10.0259 0.1 < 1/2 RDL
Fluoride 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Nitrate 0.04 mg/L -10.04 0.1 < 1/2 RDL
Sulfate -0.016 mg/L -1-0.016 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.45 25 99.1mg/L -12080527.3
Fluoride 4.9 25 97.6mg/L -12080524.5
Nitrate 4.82 25 95.6mg/L -12080524.1
Sulfate 7.38 25 95.2mg/L -12080536.9
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.48 25 99.6 0.493mg/L -12080527.4
Fluoride 4.91 25 97.8 0.196mg/L -12080524.6
Nitrate 4.84 25 96.1 0.53mg/L -12080524.2
Sulfate 7.39 25 95.5 0.264mg/L -12080537
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.82 50 108mg/L -120801088.2
Fluoride 4.85 50 96.7mg/L -120801048.5
Nitrate 50mg/L -120801Not Tested
Sulfate 5.14 50 99.7mg/L -120801051.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.78 50 107 0.72mg/L -120801087.8
Fluoride 4.96 50 98.9 2.24mg/L -120801049.6
Nitrate 50mg/L -120801Not Tested
Sulfate 5.16 50 100 0.311mg/L -120801051.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.86 5 97.2mg/L -1109014.86
Fluoride 5.04 5 101mg/L -1109015.04
Nitrate 4.83 5 96.6mg/L -1109014.83
Sulfate 4.82 5 96.3mg/L -1109014.82
Page 30 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020098 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.004 ug/L -1-0.004 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17010464 -- 2017002045
Mercury (Hg) 0.938 1 93.1ug/L -1257510.938
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17010464 -- 2017002045
Mercury (Hg) 0.941 1 93.4 0.322ug/L -1257510.941
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040257
Mercury (Hg) 1.01 1 100ug/L -1257511.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040257
Mercury (Hg) 1.01 1 100 0.0999ug/L -1257511.01
Page 31 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020187 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.022 ug/L -10.022 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.93 2 96.6ug/L -1158511.93
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040268
Mercury (Hg) 1.02 1 102ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040268
Mercury (Hg) 1 1 99.6 2.48ug/L -1257511
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020101 -- 2017003805
Mercury (Hg) 1 1 95.2ug/L -1257511
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020101 -- 2017003805
Mercury (Hg) 1.02 1 97.1 1.98ug/L -1257511.02
Page 32 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17010658 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000166 mg/L -10.000166 0.005 < 1/2 RDL
Boron (B) -0.00162 mg/L -1-0.00162 0.05 < 1/2 RDL
Calcium (Ca) 0.00175 mg/L -10.00175 0.01 < 1/2 RDL
Chromium (Cr) 0.000615 mg/L -10.000615 0.005 < 1/2 RDL
Copper (Cu) -0.000461 mg/L -1-0.000461 0.005 < 1/2 RDL
Iron (Fe) 0.000682 mg/L -10.000682 0.01 < 1/2 RDL
Magnesium (Mg) 0.00173 mg/L -10.00173 0.005 < 1/2 RDL
Manganese (Mn) 0.00031 mg/L -10.00031 0.005 < 1/2 RDL
Nickel (Ni) -0.000288 mg/L -1-0.000288 0.005 < 1/2 RDL
Potassium (K) 0.00382 mg/L -10.00382 0.1 < 1/2 RDL
Sodium (Na) -0.0085 mg/L -1-0.0085 0.05 < 1/2 RDL
Zinc (Zn) 0.000345 mg/L -10.000345 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.24 5 105mg/L -1208015.24
Boron (B) 5.03 5 101mg/L -1208015.03
Calcium (Ca) 4.93 5 98.6mg/L -1208014.93
Chromium (Cr) 5.1 5 102mg/L -1208015.1
Copper (Cu) 5.07 5 101mg/L -1208015.07
Iron (Fe) 5.03 5 101mg/L -1208015.03
Magnesium (Mg) 5.17 5 103mg/L -1208015.17
Manganese (Mn) 5.29 5 106mg/L -1208015.29
Nickel (Ni) 5 5 100mg/L -1208015
Potassium (K) 5.09 5 102mg/L -1208015.09
Sodium (Na) 4.99 5 99.8mg/L -1208014.99
Zinc (Zn) 5.16 5 103mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040257
Barium (Ba) 5.74 5 114mg/L -1257515.74
Boron (B) 5.41 5 108mg/L -1257515.41
Calcium (Ca) 7.92 5 112mg/L -1257517.92
Chromium (Cr) 5.48 5 110mg/L -1257515.48
Copper (Cu) 5.44 5 109mg/L -1257515.44
Iron (Fe) 6.64 5 111mg/L -1257516.64
Magnesium (Mg) 7.03 5 115mg/L -1257517.03
Manganese (Mn) 5.7 5 114mg/L -1257515.7
Nickel (Ni) 5.4 5 108mg/L -1257515.4
Potassium (K) 8.31 5 113mg/L -1257518.31
Page 33 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17010658 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040257
Sodium (Na) 8.87 5 114mg/L -1257518.87
Zinc (Zn) 5.53 5 111mg/L -1257515.53
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040257
Barium (Ba) 5.32 5 105 7.83mg/L -1257515.32
Boron (B) 5.04 5 101 6.97mg/L -1257515.04
Calcium (Ca) 7.42 5 102 9.45mg/L -1257517.42
Chromium (Cr) 5.13 5 102 6.66mg/L -1257515.13
Copper (Cu) 5.08 5 102 6.82mg/L -1257515.08
Iron (Fe) 6.2 5 102 8.23mg/L -1257516.2
Magnesium (Mg) 6.51 5 105 9.26mg/L -1257516.51
Manganese (Mn) 5.34 5 106 6.67mg/L -1257515.34
Nickel (Ni) 5.04 5 101 6.84mg/L -1257515.04
Potassium (K) 7.77 5 103 10mg/L -1257517.77
Sodium (Na) 8.29 5 103 10.6mg/L -1257518.29
Zinc (Zn) 5.19 5 104 6.39mg/L -1257515.19
Page 34 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020043 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000134 mg/L -1-0.000134 0.005 < 1/2 RDL
Boron (B) 0.00132 mg/L -10.00132 0.05 < 1/2 RDL
Calcium (Ca) 0.00181 mg/L -10.00181 0.01 < 1/2 RDL
Chromium (Cr) 0.000114 mg/L -10.000114 0.005 < 1/2 RDL
Copper (Cu) -0.000396 mg/L -1-0.000396 0.005 < 1/2 RDL
Iron (Fe) 0.000913 mg/L -10.000913 0.01 < 1/2 RDL
Magnesium (Mg) 0.000959 mg/L -10.000959 0.005 < 1/2 RDL
Manganese (Mn) -0.000009 mg/L -1-0.000009 0.005 < 1/2 RDL
Nickel (Ni) -0.000075 mg/L -1-0.000075 0.005 < 1/2 RDL
Potassium (K) 0.000568 mg/L -10.000568 0.1 < 1/2 RDL
Sodium (Na) -0.00168 mg/L -1-0.00168 0.05 < 1/2 RDL
Zinc (Zn) 0.00053 mg/L -10.00053 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.87 5 97.5mg/L -1208014.87
Boron (B) 4.81 5 96.3mg/L -1208014.81
Calcium (Ca) 4.94 5 98.8mg/L -1208014.94
Chromium (Cr) 4.9 5 98mg/L -1208014.9
Copper (Cu) 4.88 5 97.6mg/L -1208014.88
Iron (Fe) 4.89 5 97.7mg/L -1208014.89
Magnesium (Mg) 4.92 5 98.4mg/L -1208014.92
Manganese (Mn) 4.9 5 98.1mg/L -1208014.9
Nickel (Ni) 4.99 5 99.7mg/L -1208014.99
Potassium (K) 4.85 5 97mg/L -1208014.85
Sodium (Na) 4.75 5 95mg/L -1208014.75
Zinc (Zn) 4.91 5 98.2mg/L -1208014.91
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040260
Barium (Ba) 4.91 5 97.9mg/L -1257514.91
Boron (B) 4.83 5 96.5mg/L -1257514.83
Calcium (Ca) 8.27 5 97.6mg/L -1257518.27
Chromium (Cr) 4.91 5 98.2mg/L -1257514.91
Copper (Cu) 4.9 5 97.9mg/L -1257514.9
Iron (Fe) 11.8 5 96.9mg/L -12575111.8
Magnesium (Mg) 7.62 5 96.3mg/L -1257517.62
Manganese (Mn) 5.02 5 98.5mg/L -1257515.02
Nickel (Ni) 5 5 99.7mg/L -1257515
Potassium (K) 6.37 5 97.7mg/L -1257516.37
Page 35 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020043 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040260
Sodium (Na) 9.18 5 96.7mg/L -1257519.18
Zinc (Zn) 4.92 5 98mg/L -1257514.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040260
Barium (Ba) 4.92 5 98.2 0.245mg/L -1257514.92
Boron (B) 4.86 5 97 0.537mg/L -1257514.86
Calcium (Ca) 8.29 5 98 0.47mg/L -1257518.29
Chromium (Cr) 4.92 5 98.4 0.203mg/L -1257514.92
Copper (Cu) 4.91 5 98.1 0.204mg/L -1257514.91
Iron (Fe) 11.8 5 97.7 0.822mg/L -12575111.8
Magnesium (Mg) 7.63 5 96.6 0.249mg/L -1257517.63
Manganese (Mn) 5.04 5 98.8 0.243mg/L -1257515.04
Nickel (Ni) 5 5 99.8 0.12mg/L -1257515
Potassium (K) 6.37 5 97.6 0.0615mg/L -1257516.37
Sodium (Na) 9.2 5 97.1 0.433mg/L -1257519.2
Zinc (Zn) 4.92 5 98.1 0.0816mg/L -1257514.92
Page 36 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17010669 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.002 ug/L -10.002 1 < 1/2 RDL
Cadmium (Cd) 0.005 ug/L -10.005 1 < 1/2 RDL
Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL
Selenium (Se) -0.028 ug/L -1-0.028 1 < 1/2 RDL
Silver (Ag) 0.004 ug/L -10.004 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 50.9 50 102ug/L -12080150.9
Cadmium (Cd) 50.7 50 101ug/L -12080150.7
Lead (Pb) 51.3 50 103ug/L -12080151.3
Selenium (Se) 45.5 50 90.9ug/L -12080145.5
Silver (Ag) 53 50 106ug/L -12080153
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040258
Arsenic (As) 48.8 50 97ug/L -12575148.8
Cadmium (Cd) 49.4 50 98.7ug/L -12575149.4
Lead (Pb) 51.2 50 99.5ug/L -12575151.2
Selenium (Se) 44 50 87.9ug/L -12575144
Silver (Ag) 51.2 50 102ug/L -12575151.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040258
Arsenic (As) 48.6 50 96.6 0.446ug/L -12575148.6
Cadmium (Cd) 49.6 50 99.1 0.419ug/L -12575149.6
Lead (Pb) 51.5 50 100 0.587ug/L -12575151.5
Selenium (Se) 44 50 87.9 0.0319ug/L -12575144
Silver (Ag) 50.9 50 102 0.686ug/L -12575150.9
Page 37 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020054 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.101 ug/L -10.101 1 < 1/2 RDL
Cadmium (Cd) 0.0016 ug/L -10.0016 1 < 1/2 RDL
Lead (Pb) -0.0015 ug/L -1-0.0015 1 < 1/2 RDL
Selenium (Se) -0.0116 ug/L -1-0.0116 1 < 1/2 RDL
Silver (Ag) 0.0005 ug/L -10.0005 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 49.8 50 99.5ug/L -12080149.8
Cadmium (Cd) 49.7 50 99.3ug/L -12080149.7
Lead (Pb) 49.2 50 98.3ug/L -12080149.2
Selenium (Se) 47.1 50 94.2ug/L -12080147.1
Silver (Ag) 53.1 50 106ug/L -12080153.1
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040261
Arsenic (As) 49.9 50 98.9ug/L -12575149.9
Cadmium (Cd) 51.1 50 102ug/L -12575151.1
Lead (Pb) 51.4 50 99.4ug/L -12575151.4
Selenium (Se) 48.3 50 96.5ug/L -12575148.3
Silver (Ag) 53.8 50 107ug/L -12575153.8
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120415 -- 2016040261
Arsenic (As) 50.2 50 99.6 0.645ug/L -12575150.2
Cadmium (Cd) 51.4 50 103 0.606ug/L -12575151.4
Lead (Pb) 51.5 50 99.8 0.323ug/L -12575151.5
Selenium (Se) 46.7 50 93.3 3.31ug/L -12575146.7
Silver (Ag) 54.1 50 108 0.559ug/L -12575154.1
Page 38 of 41
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120415
Q17020042 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16120415 -- 2016040257
TDS 60 10.5mg/L -160
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16120415 -- 2016040258
TDS 87 2.27mg/L -187
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16120415 -- 2016040259
TDS 71 2.78mg/L -171
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 107 100 107mg/L -110901107
Page 39 of 41
Page 40 of 41
Page 41 of 41
13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: 980-875-5245 Fax: 980-875-4349
Order Summary Report
Analytical Laboratory
Order Number:J16120417
Project Name:BELEWS - GW CRAIG ROAD LF
Lab Contact: Anne Pridgeon
Date:2/17/2017
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: 980-875-6610
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Page 1 of 10
Reason: I have reviewed
this document.
Date: 2017.02.17 10:39:20
-05'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016040285 BELEWS 31-Jan-17 9:25 AM LDC CRS-1
2016040286 BELEWS 31-Jan-17 10:40 AM PSP CRS-2
2016040288 BELEWS 31-Jan-17 11:30 AM LDC CRS-6
3 Total Samples
Page 2 of 10
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/17/2017
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
2016040285
Collection Date:31-Jan-17 9:25 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.025 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
Iron (Fe)0.084 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.01 1
Manganese (Mn)0.032 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311
Page 4 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
2016040286
Collection Date:31-Jan-17 10:40 AM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
Iron (Fe)0.714 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.01 1
Manganese (Mn)0.103 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311
Page 5 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
2016040288
Collection Date:31-Jan-17 11:30 AM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
Iron (Fe)0.011 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.01 1
Manganese (Mn)0.325 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311
Page 6 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
Q17020372 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.0001 mg/L -1-0.0001 0.005 < 1/2 RDL
Boron (B) -0.0046 mg/L -1-0.0046 0.05 < 1/2 RDL
Chromium (Cr) 0.000139 mg/L -10.000139 0.005 < 1/2 RDL
Copper (Cu) -0.00183 mg/L -1-0.00183 0.005 < 1/2 RDL
Iron (Fe) -0.000052 mg/L -1-0.000052 0.01 < 1/2 RDL
Manganese (Mn) -0.0001 mg/L -1-0.0001 0.005 < 1/2 RDL
Nickel (Ni) -0.000901 mg/L -1-0.000901 0.005 < 1/2 RDL
Zinc (Zn) -0.000916 mg/L -1-0.000916 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 0.988 1 98.8mg/L -1158510.988
Boron (B) 2 2 100mg/L -1158512
Chromium (Cr) 1.01 1 101mg/L -1158511.01
Copper (Cu) 1.95 2 97.3mg/L -1158511.95
Iron (Fe) 2.03 2 102mg/L -1158512.03
Manganese (Mn) 0.983 1 98.3mg/L -1158510.983
Nickel (Ni) 2 2 99.8mg/L -1158512
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120417 -- 2016040285
Barium (Ba) 5.78 5 115mg/L -1307015.78
Boron (B) 5.25 5 105mg/L -1307015.25
Chromium (Cr) 5.54 5 111mg/L -1307015.54
Copper (Cu) 5.53 5 111mg/L -1307015.53
Iron (Fe) 5.52 5 109mg/L -1307015.52
Manganese (Mn) 5.83 5 116mg/L -1307015.83
Nickel (Ni) 5.4 5 108mg/L -1307015.4
Zinc (Zn) 5.72 5 114mg/L -1307015.72
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120417 -- 2016040285
Barium (Ba) 5.77 5 115 0.104mg/L -1307015.77
Boron (B) 5.22 5 104 0.478mg/L -1307015.22
Chromium (Cr) 5.57 5 111 0.486mg/L -1307015.57
Copper (Cu) 5.54 5 111 0.325mg/L -1307015.54
Iron (Fe) 5.55 5 109 0.532mg/L -1307015.55
Manganese (Mn) 5.87 5 117 0.585mg/L -1307015.87
Nickel (Ni) 5.39 5 108 0.111mg/L -1307015.39
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
Q17020372 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120417 -- 2016040285
Zinc (Zn) 5.76 5 115 0.697mg/L -1307015.76
Page 8 of 10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16120417
Q17020383 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.015 ug/L -1-0.015 1 < 1/2 RDL
Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL
Lead (Pb) 0.005 ug/L -10.005 1 < 1/2 RDL
Silver (Ag) 0.002 ug/L -10.002 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 81.1 80 101ug/L -12080181.1
Cadmium (Cd) 8.3 8 104ug/L -1208018.3
Lead (Pb) 82.3 80 103ug/L -12080182.3
Silver (Ag) 40.4 40 101ug/L -12080140.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16120417 -- 2016040285
Arsenic (As) 48.9 50 97.8ug/L -12575148.9
Cadmium (Cd) 49.2 50 98.5ug/L -12575149.2
Lead (Pb) 49.4 50 98.7ug/L -12575149.4
Silver (Ag) 48.1 50 96.1ug/L -12575148.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16120417 -- 2016040285
Arsenic (As) 48.9 50 97.7 0.141ug/L -13070148.9
Cadmium (Cd) 49.3 50 98.5 0.0305ug/L -13070149.3
Lead (Pb) 49.4 50 98.7 0.0263ug/L -13070149.4
Silver (Ag) 48.4 50 96.8 0.645ug/L -13070148.4
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