2201_ClayCoMSW_Dec2016_AnnualMonitoring_DIN27623_20170410

April 2017
Clay County Closed Municipal Solid Waste Landfill
December 2016
Water Quality Monitoring Report
Prepared for Clay County, North Carolina

December 2016 Water Quality Monitoring Report i April 2017
TABLE OF CONTENTS
1 Introduction ................................................................................................................................ 1
2 Methods ....................................................................................................................................... 2
2.1 Groundwater and Surface Water Sampling .............................................................................................. 2
2.1.1 Groundwater Purging and Sampling Methods ........................................................................ 2
2.1.2 Surface Water Sampling Methods ................................................................................................ 2
2.2 Sample Handling, Documentation, and Analysis .................................................................................... 3
3 Analytical Results ....................................................................................................................... 4
3.1 Groundwater ......................................................................................................................................................... 5
3.1.1 Appendix I Metals (EPA Methods 6010 and 7470) ................................................................. 5
3.1.2 Appendix I VOCs (EPA Method 8260) ......................................................................................... 5
3.1.3 Field Parameters .................................................................................................................................. 5
3.2 Surface Water ....................................................................................................................................................... 5
3.2.1 Appendix I Metals (EPA Methods 6010 and 7470) ................................................................. 6
3.2.2 Appendix I VOCs (EPA Method 8260) ......................................................................................... 6
3.2.3 Field Parameters .................................................................................................................................. 6
4 Summary and Discussion ......................................................................................................... 7
4.1 Groundwater Quality.......................................................................................................................................... 7
4.2 Surface Water Quality ........................................................................................................................................ 8
4.3 Future Activities ................................................................................................................................................... 8

TABLES
Table 1 Summary of Groundwater Elevation Data
Table 2 Summary of Laboratory Analyses Performed on Samples
Table 3 Summary of Detected Compounds
Table 4 Solid Waste Section Limits Exceedances Notification
Table 5 Water Quality Standards Exceedances Notification
FIGURES
Figure 1 Site Location Map
Figure 2 Site Layout Map
Figure 3 Groundwater Elevation Map

December 2016 Water Quality Monitoring Report ii April 2017
APPENDICES
Appendix A Field Sheet and Certificate of Analysis
Appendix B Reports of Laboratory Analysis and Chain-of-Custody Documentation

December 2016 Water Quality Monitoring Report iii April 2017
ABBREVIATIONS
µG/L micrograms per unit
2B standard Title 15A NCAC Subchapter 2B standard
2L standard Title 15A NCAC Subchapter 2L standard
Altamont Altamont Environmental, Inc. (which became Anchor QEA on December 29, 2016)
Anchor QEA Anchor QEA of North Carolina, PLLC
DENR N.C. Department of Environment and Natural Resources (which is now DEQ)
DEQ N.C. Department of Environmental Quality
DWM DEQ Division of Waste Management
EDD Electronic Data Deliverable
EPA U.S. Environmental Protection Agency
GWPS Groundwater Protection Standard
IMAC interim maximum allowable concentration
MDL method detection limit
MRL method reporting limit
MSW municipal solid waste
NCAC North Carolina Administrative Code
NTU Nephelometric Turbidity Unit
Pace Pace Analytical Services, Inc.
SU Standard Unit
SWS DWM Solid Waste Section
SWSL Solid Waste Section Limit
VOC volatile organic compound

December 2016 Water Quality Monitoring Report 1 April 2017
1 Introduction
Anchor QEA of North Carolina, PLLC (Anchor QEA) is pleased to present this water quality monitoring
report for the Clay County Closed Municipal Solid Waste (MSW) Landfill (Site), prepared for
Environmental, Inc. The information submitted in this report is based on field data and water quality
samples collected by Environmental, Inc. To the best of Anchor QEA’s knowledge, field procedures
were performed in accordance with monitoring requirements for the Site, as stipulated in the DEQ
Division of Waste Management (DWM) Permit No. 22-01 and its amendments dated April 19, 1990,
issued to the Clay County Solid Waste Department, as well as requirements stipulated in the DEQ
Solid Waste Management Rules Title 15A, Subchapter 13B, Section .1600, of the North Carolina
Administrative Code (15A NCAC 13B.1600).
The Clay County Solid Waste Department maintains the solid waste facility, located at 1160 Hinton
Center Road (State Road 1148) in Hayesville, Clay County, North Carolina (Figure 1). The facility
accepts solid waste from Clay County, and includes the following permitted components:
• A closed MSW landfill (Site; Permit 22-01)
• An active transfer station (Permit 22-02T)
According to the Landfill Gas Monitoring Plan prepared by McGill Associates dated November 2010,
the landfill was officially closed per the letter to the North Carolina Department of Environment and
Natural Resources (DENR), now known as the Department of Environmental Quality (DEQ), dated
December 21, 1995. The closure permit (Number 22-01) for the landfill requires annual monitoring of
groundwater and surface water quality. This report describes a groundwater and surface water
quality sampling event performed by Environmental, Inc. on December 15, 2016.
This report presents analytical results and provides a discussion of groundwater and surface water
quality for the Site.

December 2016 Water Quality Monitoring Report 2 April 2017
2 Methods
2.1 Groundwater and Surface Water Sampling
The groundwater monitoring network consists of an upgradient, background monitoring well
(MW-1), and five downgradient monitoring wells (MW-2, MW-3, MW-4, MW-5, and MW-6). MW-1 is
located in the northern portion of the Site, north of a closed MSW disposal cell and Clay County’s
wood waste treatment and processing area. MW-2 is located in the southeast corner of the Site
property on the north side of State Route (S.R.) 1148, and south of a closed MSW landfill cell. MW-3
and MW-4 are located along or near the southernmost parcel boundary of the landfill downgradient
of a closed MSW landfill cell (Figure 2). MW-5 and MW-6 are located along the southwestern
property line of the facility downgradient of a closed MSW landfill cell. A map depicting the location
of the monitoring wells is included as Figure 2.
In October 2011, Samuel L. Sprinkle & Associates, P.A., a professional surveying firm certified in
North Carolina, surveyed the horizontal and vertical locations of the monitoring wells associated with
the closed Clay County Landfill. The certified survey data were presented in the 2011 Site water
quality monitoring report, prepared by Altamont Environmental, Inc. (Altamont), which became
Anchor QEA on December 29, 2016.
Monitoring wells associated with the Site (MW-1, MW-2, MW-3, MW-4, MW-5, and MW-6) and
surface water sample locations (UPSTREAM and DOWNSTREAM) were sampled by
Environmental, Inc., of Sylva, North Carolina, on December 15, 2016. Approximate sample locations
are depicted on Figure 2.
Prior to collecting groundwater samples from the monitoring wells, the static water level at each of
the wells was measured and recorded. These data are presented in Table 1 and shown on Figure 3.
Groundwater flow direction is interpreted to be generally to the southwest toward the Hiwassee
River.
2.1.1 Groundwater Purging and Sampling Methods
Prior to sample collection at each monitoring well, field parameters consisting of temperature, pH,
specific conductivity, and turbidity were measured and recorded. A field data sheet and certificate of
analysis provided by Environmental, Inc. are presented in Appendix A. Groundwater monitoring wells
were purged with a new disposable polyethylene bailer before samples were collected.
2.1.2 Surface Water Sampling Methods
Surface water samples UPSTREAM and DOWNSTREAM were collected at designated locations along
a minor unnamed tributary and the Hiwassee River, respectively. These surface water bodies flow
adjacent to the western and southern Site boundary in a south-to-north direction as shown on

December 2016 Water Quality Monitoring Report 3 April 2017
Figure 2. The surface water sample collected at the UPSTREAM location is assumed to represent
surface water quality upstream of the Site, while the surface water sample collected at the
DOWNSTREAM location is assumed to represent surface water quality downstream of the Site. One
set of field parameters, including temperature and pH, was measured and recorded at each surface
water sampling location prior to sample collection (Appendix A). Split samples were collected in the
field to be analyzed at Environmental Inc.’s in-house laboratory for specific conductivity and
turbidity.
2.2 Sample Handling, Documentation, and Analysis
Following sample collection, groundwater and surface water samples were placed on ice and
transported to Pace Analytical Services, Inc. (Pace), a laboratory certified in North Carolina, located in
Asheville. Environmental, Inc. submitted the water samples collected from the monitoring wells and
the surface water sampling locations to Pace for analysis as follows:
• Appendix I volatile organic compounds (VOCs) using U.S. Environmental Protection Agency
(EPA) Approved Method 8260B
• Appendix I metals using EPA Approved Methods 6010A and 7470A
An equipment rinsate blank was collected after sampling was completed and analyzed for Appendix I
metals and VOCs. A trip blank, provided by the laboratory, was analyzed for Appendix I VOCs. Proper
chain-of-custody documentation procedures were followed during collection and transport of each
sample. The laboratory analytical reports and chain-of-custody documentation are included as
Appendix B. Laboratory analyses performed on the samples are summarized in Table 2.

December 2016 Water Quality Monitoring Report 4 April 2017
3 Analytical Results
The laboratory analytical results for groundwater, surface water, the equipment rinsate blank, and the
trip blank samples are provided in the attached laboratory reports (Appendix B). In addition, all the
laboratory analytical results and measured field parameters are summarized in the Electronic Data
Deliverable (EDD) which is submitted separately to the DWM’s Solid Waste Section (SWS), per DEQ
guidelines (last updated May 5, 2010).
The MDL is the minimum concentration of a substance that can be measured and reported by a
laboratory with 99 percent confidence that the analyte concentration is greater than zero. The
method reporting limit (MRL) is the minimum concentration of a target analyte that can be
accurately determined by the referenced method. As stipulated by the SWS, analytes which were
analyzed for but not detected (non-detections) were reported at their method detection limits (MDL),
and all concentrations exceeding the laboratory-specific MDLs were reported and appropriately
qualified as needed (Tables 3, 4, and 5). A “J” qualifier is used by the laboratory for a parameter that
is detected at an estimated concentration greater than the MDL but less than the laboratory’s MRL.
All detections were compared to analyte-specific Solid Waste Section Limits (SWSLs) established by
the SWS. The SWSL is the lowest concentration, determined by the SWS, of an analyte in a sample
that can be quantitatively determined with suitable precision and accuracy. If the reported
concentration is greater than the laboratory’s MRL and less than the SWSL, the analytical result is
qualified as estimated by Anchor QEA per SWS requirements, and is flagged with a “J” qualifier
(italicized J-flag). Detected concentrations of constituents below the applicable SWSLs are
summarized in Table 3, but are not reported in the text of this report, unless they exceed their
applicable North Carolina water quality standards; see below.
Detected concentrations of analytes in groundwater samples were compared to current
(March 21, 2013) groundwater quality standards specified in 15A NCAC 2L.0202, which are referred
to as 2L standards. Detected concentrations of analytes in groundwater with no established 2L
standards were compared either to the interim maximum allowable concentrations (IMACs, updated
May 22, 2013) for Class GA and GSA groundwater (in accordance with 15A NCAC 2L .0202 [c])
pursuant to 15A NCAC 13B.1634. Detections of analytes in surface water samples were compared to
15A NCAC 2B surface-water quality standards (2B standards).
Table 3 presents the summary of laboratory analytical results for detected constituents only. Table 4
presents all analytical results that were above the applicable SWSLs. Table 5 presents only the
concentrations of analytes detected in groundwater and/or surface water samples that exceeded
their respective 2L standards (including IMACs, if applicable) or 2B standards.

December 2016 Water Quality Monitoring Report 5 April 2017
3.1 Groundwater
3.1.1 Appendix I Metals (EPA Methods 6010 and 7470)
Fourteen metals were detected in one or more of the groundwater samples collected from the
monitoring wells at the landfill (Table 3). Twelve of the detected metals were found at concentrations
above their respective SWSLs in one or more of the groundwater samples collected from the
monitoring wells (Table 4). In addition, eight metals (antimony, arsenic, barium, chromium, cobalt,
lead, silver, and vanadium) had concentrations that exceeded either their respective 2L standard or
IMAC standard (Table 5) in one or more of the groundwater samples collected from the monitoring
wells. As noted on Table 5, concentrations of antimony, cobalt, lead, and vanadium could be
naturally occurring, as these four metals that met or exceeded applicable 2L standards or IMACs also
exceeded these standards in monitoring well MW-1, the background well. Metal exceedances also
appear to coincide with samples reported with high turbidity values.
3.1.2 Appendix I VOCs (EPA Method 8260)
Ten VOCs were detected in one or more of the groundwater samples collected from the monitoring
wells (Table 3). Four of the detected VOCs (1,4-dichlorobenzene, benzene, cis-1,2-dichlorethene, and
methylene chloride) were found at concentrations above their SWSLs in one or more groundwater
samples (Table 4). Benzene was detected at a concentration above the 2L standard in monitoring
well MW-2 (Table 5).
3.1.3 Field Parameters
The pH readings obtained from all monitoring wells, with the exception of MW-6, were outside the
acceptable range of 6.5 to 8.5 Standard Units (SU) specified in 15A NCAC 02L .0202[c] (Tables 3
and 5). Although the results were outside the acceptable range, they generally appear to be
consistent with the naturally occurring range of pH in the region. This conclusion is based on the pH
reading from background monitoring well MW-1, which was recorded as 6.3 SU.
Turbidity values of the groundwater samples ranged from 9.5 nephelometric turbidity units (NTUs) to
463 NTUs (Table 3).
3.2 Surface Water
Analytical results for surface water samples collected from the Hiwassee River and its tributary are
discussed below and are summarized in Table 3. Laboratory analytical reports are included in
Appendix B.

December 2016 Water Quality Monitoring Report 6 April 2017
3.2.1 Appendix I Metals (EPA Methods 6010 and 7470)
Barium was detected in both surface water samples (Table 3) below its SWSL and 2B surface water
standard. Cadmium was detected below the SWSL and 2B surface water standard in the downstream
surface water sample (Table 3).
3.2.2 Appendix I VOCs (EPA Method 8260)
No VOCs were detected in either collected surface water sample from the Site.
3.2.3 Field Parameters
Turbidity and pH readings were obtained on December 15, 2016 for the surface water samples. The
pH readings measured in both samples were within the 2B standard range established at 6.0 SU to
9.0 SU. The turbidity for the DOWNSTREAM and UPSTREAM surface water samples was recorded at
2.0 NTU and 1.6 NTU, respectively. These turbidity measurements are well below the 2B surface water
standard of 50 NTUs.

December 2016 Water Quality Monitoring Report 7 April 2017
4 Summary and Discussion
The following discussion summarizes the results of the December 2016 water quality monitoring
event.
4.1 Groundwater Quality
Analysis of data collected during the annual water quality monitoring event conducted on
December 15, 2016 at the Clay County Closed MSW Landfill indicates that eight metals were
detected in the groundwater samples at concentrations above their respective SWSLs. The
concentrations of eight of these metals (antimony, arsenic, barium, chromium, cobalt, lead, silver, and
vanadium) exceeded their respective 2L standards or IMACs in one or more of the groundwater
samples. This sampling event is the first time antimony, arsenic, and barium have exceeded
2L standards in any monitoring well on-Site, according to historical data. Antimony exceeded the
2L standard in monitoring wells MW-1 and MW-2. Arsenic and barium exceeded the 2L standard in
MW-3. Chromium has been detected consistently in monitoring wells MW-1, MW-2, and MW-3
historically, with occasional exceedances of 2L standards in MW-1, the background well. Chromium
exceeded the 2L standard in MW-2 and MW-3 in this sampling event. Historical data shows
consistent exceedances of cobalt in all monitoring wells. Lead has historically been detected at
various concentrations in monitoring wells MW-1, MW-3, and MW-6, but exceeded the 2L standard
for the first time during this sampling event in MW-3. Vanadium exceedances have been historically
consistent in monitoring wells MW-1, MW-3, and MW-6.
The turbidity values measured from several of the monitoring well samples indicate that the samples
contained solid particles from the surrounding formation in which the wells are screened. The
highest turbidity recorded during this event was in monitoring well MW-1, at a reading of 463 NTUs.
Naturally occurring metals tend to adsorb to the surfaces of these solid particles. The concentrations
of metals detected in these groundwater samples may represent both the dissolved metals in the
groundwater and the metals that were adsorbed to the solid particles, potentially resulting in false
positive results and/or higher concentrations.
Four VOCs were detected at concentrations above their SWSLs in one or more groundwater samples.
1,4-dichlorobenzene was detected above its SWSL in monitoring wells MW-2, MW-4, and MW-5.
Cis-1,2-dichloroethene was detected in monitoring well MW-5 at a concentration above the SWSL.
Methylene chloride was detected above its SWSL in monitoring well MW-2. Benzene was the only
VOC detected above 2L standards during the December 2016 sampling event. This VOC was
detected at a concentration of 1.6 micrograms per liter (µg/L) in monitoring well MW-2, which is
slightly above the 2L standard of 1.0 µg/L. This is the second time benzene has exceeded the
2L standard in this monitoring well.

December 2016 Water Quality Monitoring Report 8 April 2017
The pH readings obtained for the monitoring wells, with the exception of MW-6, were outside the
2L standard for acceptable pH range. However, as discussed in Section 3.1.3, the pH readings appear
to be generally consistent with the naturally occurring range of pH in the region and correlate with
background monitoring well MW-1.
4.2 Surface Water Quality
No metals were detected above SWSLs or applicable surface water quality standards in the
UPSTREAM or DOWNSTREAM samples. No VOCs were detected in either surface water sample.
4.3 Future Activities
Environmental, Inc. will continue to collect groundwater and surface water samples on an annual
basis at the Clay County Closed MSW Landfill. The next sampling event is scheduled for December
2017.

Tables
Table 1
Summary of Groundwater Elevation Data
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 1 of 1
April 2017
DEPTH TO
WATER
GROUNDWATER
ELEVATION
(feet NAVD 1988)(feet NAVD 1988) (feet TOC)(feet NAVD 1988)
MW-1 1992.05 1,993.10 48.00 1,945.10
MW-2 1868.94 1,869.77 26.25 1,843.52
MW-3 1835.67 1,837.75 10.00 1,827.75
MW-4 1819.19 1,821.30 10.33 1,810.97
MW-5 1840.53 1,841.63 39.08 1,802.55
MW-6 1825.64 1,826.52 22.33 1,804.19
Notes:
All monitoring wells were surveyed on October 18, 2011 by Samuel L. Sprinkle & Associates, P.A.
NAVD: North American Vertical Datum 1988.
WELL ID
TOP OF CASING
(TOC) ELEVATION
GROUND
ELEVATION December 15, 2016
Table 2
Summary of Laboratory Analyses Performed on Samples
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 1 of 1
April 2017
Metals VOCs
EPA 6010
EPA 7470 EPA 8260
MW-1 12/15/2016 X X
MW-2 12/15/2016 X X
MW-3 12/15/2016 X X
MW-4 12/15/2016 X X
MW-6 12/15/2016 X X
MW-6 12/15/2016 X X
EQUIPMENT BLANK 12/15/2016 X X
TRIP BLANK 12/15/2016 X
Metals VOCs
EPA 6010
EPA 7470 EPA 8260
UPSTREAM 12/15/2016 X X
DOWNSTREAM 12/15/2016 X X
VOCs and metals analysis include Appendix I constituents per 40 CFR Part 258 and 15A NCAC 13B .1600.
Notes:
VOCs: volatile organic compounds.
Groundwater Samples
Sample Name Date Collected
Surface Water Samples
Sample Name Date Collected
Table 3
Summary of Detected Compounds
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 1 of 2
April 2017
Metals
Lab Certification 40
Lab Method EPA 6010 and EPA 7470 (Mercury)
Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Mercury Nickel Silver Vanadium Zinc
CAS Number 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-02-0 7440-22-4 7440-62-2 7440-66-6
SWS ID 13 14 15 23 34 51 53 54 131 132 152 184 209 213
Units μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L
Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result
MW-1 12/15/2016 33.9 2.5 U 125 0.50 U 0.50 U 6.1 J 36.2 21.0 27.5 0.10 U 9.0 J 2.5 U 14.4 J 82.2MW-2 12/15/2016 6.1 2.5 U 286 0.50 U 0.50 U 16.7 3.0 J 15.7 3.8 J 0.37 8.5 J 20.1 23.4 J 108MW-3 12/15/2016 3.8 U 16.0 711 2.0 0.50 U 42.2 54.3 62.9 60.3 0.10 U 31.8 J 2.5 U 72.7 170MW-4 12/15/2016 12.7 U 8.3 U 220 1.7 U 1.7 U 8.3 U 8.3 U 8.3 U 8.3 U 0.55 8.3 U 8.3 U 8.3 U 16.7 UMW-5 12/15/2016 3.8 U 3.6 J 180 0.50 U 0.50 U 2.5 U 29.1 6.2 J 2.5 U 0.25 3.6 J 2.5 U 2.5 U 15.6MW-6 12/15/2016 3.8 U 3.9 J 369 0.50 U 0.50 U 2.5 U 2.5 U 2.5 U 11.0 0.10 U 5.1 J 2.5 U 14.5 J 16.4
DOWNSTREAM 12/15/2016 3.8 U 2.5 U 8.5 J 0.50 U 0.58 J 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 2.5 U 5.0 U
UPSTREAM 12/15/2016 3.8 U 2.5 U 29.0 J 0.50 U 0.50 U 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 2.5 U 5.0 U
EQUIPMENT BLANK 12/15/2016 3.8 U 2.5 U 2.5 U 0.50 U 0.50 U 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 2.5 U 5.0 UMDL3.8 2.5 2.5 0.50 0.50 2.5 2.5 2.5 2.5 0.10 2.5 2.5 2.5 5.0
MRL 5.0 10.0 5 1.0 1.0 5 5 5 5 0.20 5 5 5 10.0
SWSL 6 10 100 1 1 10 10 10 10 0.20 50 10 25 10
2L NE 10 700 4 2 10 NE 1,000 15 1.0 100 20 NE 1,000
IMAC 1 NE NE 4 NE NE 1 NE NE NE NE NE 0.3 NE
2B 640 10 200,000 7 2 11 270 7 25 0.012 88 0.06 NE 50
Notes:
Only detected constituents are listed on this table. Please refer to Pace Laboratory Reports of Analysis (Appendix B) for further details.
"Lab Method" is the analytical method used to analyze the constituents.
"CAS Number" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
"SWS ID" is the Solid Waste Section Identification Number.
"Units" are micrograms per liter (µg/L) for analytical results, Standard Units (SU) for pH, and nephelometric turbidity units (NTU) for turbidity.
"Result" is analytical data reported by the laboratory or field data collected by Anchor QEA.
"MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
"MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
"SWSL" is the Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
"U" is a laboratory data qualifier used for parameters not detected at concentrations above MDL.
"J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
An italicized "J" qualifier is assigned by Anchor QEA to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
"2L" and "IMAC" (Interim Maximum Allowable Concentration) are groundwater standards from "North Carolina Administrative Code, Title 15A: Department of Environmental Quality,
Subchapter 2L - Groundwater Classifications and Standards," DEQ (Last Amended on April 1, 2013).
standard obtained from National Criteria per EPA table (current as of June 30, 2016).
"NE" means Not Established. "NA" means Not Applicable.
Bold numbers indicate an exceedance of the SWSL.
Shaded cells indicate result in exceedance of the 2L, IMAC, or 2B standard.
"C9" indicates the detected constituent is a common laboratory contaminant.
"2B" indicates surface water standard per "North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards," or
Table 3
Summary of Detected Compounds
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 2 of 2
April 2017
Appendix I VOCs
Lab Certification 12 5090 37754
Lab Method EPA 8260 SM4500HB SM 2130B
Parameter
1,1-
Dichloro-
ethane
1,4-
Dichloro-
benzene
Benzene Chloro-
benzene
Chloro-
ethane
cis-1,2-
Dichloro-
ethene
Methylene
Chloride o-Xylene
Tetra
chloro-
ethene
Trichloro-
ethene pH Turbidity
CAS Number 75-34-3 106-46-7 71-43-2 108-90-7 75-00-3 156-59-2 75-09-2 95-47-6 127-18-4 79-01-6 SW320 SW330
SWS ID 75 71 16 39 41 78 140 408 192 201 320 330
Units μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L SU NTU
Sample ID Collect
Date Result Result Result Result Result Result Result Result Result Result Result Result
MW-1 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U 6.3 463
MW-2 12/15/2016 1.7 J 1.1 1.6 0.23 U 0.72 J 2.2 J 2.2 C9 0.93 J 0.58 J 0.87 J 5.4 94.5
MW-3 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U 5.9 342
MW-4 12/15/2016 1.3 J 1.5 0.63 J 0.53 J 0.54 U 3.0 J 0.97 U 0.23 U 0.46 U 0.47 U 5.7 9.5
MW-5 12/15/2016 0.71 J 2.5 0.84 J 1.4 J 0.81 J 6.2 0.97 U 0.23 U 0.46 U 0.47 U 5.6 10.6
MW-6 12/15/2016 0.85 J 0.59 J 0.25 U 0.23 U 0.54 U 3.9 J 0.97 U 0.70 J 0.46 U 0.47 U 6.6 211
DOWNSTREAM 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U 7.2 2.0
UPSTREAM 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U 6.8 1.6
EQUIPMENT BLANK 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U NA NA
TRIP BLANK 12/15/2016 0.32 U 0.33 U 0.25 U 0.23 U 0.54 U 0.19 U 0.97 U 0.23 U 0.46 U 0.47 U NA NA
MDL 0.32 0.33 0.25 0.23 0.54 0.19 0.97 0.23 0.46 0.47 NA NA
MRL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 NA NA
SWSL 5 1 1 3 10 5 1 NE 1 1 NE NE
2L 6 6 1 50 3,000 70 5 500 1 3 6.5-8.5 NE
IMAC NE NE NE NE NE NE NE NE NE NE NE NE
2B 20,000 100 51 140 96 4,900 590 800 3.3 3 6.0-9.0 50
Notes:
Only detected constituents are listed on this table. Please refer to Pace Laboratory Reports of Analysis (Appendix B) for further details.
"Lab Method" is the analytical method used to analyze the constituents.
"CAS Number" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
"SWS ID" is the Solid Waste Section Identification Number.
"Units" are micrograms per liter (µg/L) for analytical results, Standard Units (SU) for pH, and nephelometric turbidity units (NTU) for turbidity.
"Result" is analytical data reported by the laboratory or field data collected by Anchor QEA.
"MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
"MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
"SWSL" is the Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
"U" is a laboratory data qualifier used for parameters not detected at concentrations above MDL.
"J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
An italicized "J" qualifier is assigned by Anchor QEA to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
"2L" and "IMAC" (Interim Maximum Allowable Concentration) are groundwater standards from "North Carolina Administrative Code, Title 15A: Department of Environmental Quality,
Subchapter 2L - Groundwater Classifications and Standards," DEQ (Last Amended on April 1, 2013).
"2B" indicates surface water standard per "North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards," or
"NE" means Not Established. "NA" means Not Applicable.
Bold numbers indicate an exceedance of the SWSL.
Shaded cells indicate result in exceedance of the 2L, IMAC, or 2B standard.
"C9" indicates the detected constituent is a common laboratory contaminant.
Field Parameters
standard obtained from National Criteria per EPA table (current as of June 30, 2016).
Table 4
Solid Waste Section Limits Exceedances Notification
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 1 of 1
April 2017
FACILITY
PERMIT
WELL
ID
CAS
NUMBER
SWS
ID PARAMETER RESULT UNITS METHOD MDL MRL SWSL
COLLECT
DATE
22-01 MW-1 7440-36-0 13 Antimony 33.9 µg/L EPA 6010 3.8 5 6 12/15/2016
22-01 MW-1 7440-39-3 15 Barium 125 µg/L EPA 6010 2.5 5.0 100 12/15/2016
22-01 MW-1 7440-48-4 53 Cobalt 36.2 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-1 7440-50-8 54 Copper 21.0 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-1 7439-92-1 131 Lead 27.5 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-1 7440-66-6 213 Zinc 82.2 µg/L EPA 6010 5.0 10.0 10 12/15/2016
22-01 MW-2 7440-36-0 13 Antimony 6.1 µg/L EPA 6010 3.8 5 6 12/15/2016
22-01 MW-2 7440-39-3 15 Barium 286 µg/L EPA 6010 2.5 5.0 100 12/15/2016
22-01 MW-2 7440-47-3 51 Chromium 16.7 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-2 7440-50-8 54 Copper 15.7 µg/L EPA 6010 2.5 5 10 12/15/2016
22-01 MW-2 7439-97-6 132 Mercury 0.37 µg/L EPA 7470 0.10 0.20 0.2 12/15/2016
22-01 MW-2 7440-22-4 184 Silver 20.1 µg/L EPA 6010 2.5 5 10 12/15/201622-01 MW-2 7440-66-6 213 Zinc 108 µg/L EPA 6010 5.0 10.0 10 12/15/201622-01 MW-2 106-46-7 71 1,4-Dichlorobenzene 1.1 µg/L EPA 8260 0.33 1.0 1 12/15/2016
22-01 MW-2 71-43-2 16 Benzene 1.6 µg/L EPA 8260 0.25 1.0 1 12/15/2016
22-01 MW-2 75-09-2 140 Methylene Chloride 2.2 C9 µg/L EPA 8260 0.97 1.0 1 12/15/2016
22-01 MW-3 7440-38-2 14 Arsenic 16.0 µg/L EPA 6010 3.8 5 6 12/15/2016
22-01 MW-3 7440-39-3 15 Barium 711 µg/L EPA 6010 2.5 5.0 100 12/15/2016
22-01 MW-3 7440-41-7 23 Beryllium 2.0 µg/L EPA 6010 0.5 1 1 12/15/2016
22-01 MW-3 7440-47-3 51 Chromium 42.2 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-3 7440-48-4 53 Cobalt 54.3 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-3 7440-50-8 54 Copper 62.9 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-3 7439-92-1 131 Lead 60.3 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-3 7440-62-2 209 Vanadium 72.7 µg/L EPA 6010 2.5 5 25 12/15/2016
22-01 MW-3 7440-66-6 213 Zinc 170 µg/L EPA 6010 5 10.0 10 12/15/2016
22-01 MW-4 7440-39-3 15 Barium 220 µg/L EPA 6010 2.5 5.0 100 12/15/2016
22-01 MW-4 7439-97-6 132 Mercury 0.55 µg/L EPA 7470 0.10 0.20 0.2 12/15/2016
22-01 MW-4 106-46-7 71 1,4-Dichlorobenzene 1.5 µg/L EPA 8260 0.33 1.0 1 12/15/2016
22-01 MW-5 7440-39-3 15 Barium 180 µg/L EPA 6010 2.5 5.0 100 12/15/2016
22-01 MW-5 7440-48-4 53 Cobalt 29.1 µg/L EPA 6010 2.5 5.0 10 12/15/2016
22-01 MW-5 7439-97-6 132 Mercury 0.25 µg/L EPA 6010 0.10 0.20 0.2 12/15/2016
22-01 MW-5 7440-66-6 213 Zinc 15.6 µg/L EPA 6010 5.0 10.0 10 12/15/2016
22-01 MW-5 106-46-7 71 1,4-Dichlorobenzene 2.5 µg/L EPA 8260 0.33 1.0 1 12/15/2016
22-01 MW-5 156-59-2 78 Cis-1,2-dichloroethene 6.2 µg/L EPA 8260 0.19 1 5 12/15/2016
22-01 MW-6 7440-39-3 15 Barium 369 µg/L EPA 6010 2.5 5.0 100 12/15/201622-01 MW-6 7439-92-1 131 Lead 11.0 µg/L EPA 6010 2.5 5 10 12/15/2016
22-01 MW-6 7440-66-6 213 Zinc 16.4 µg/L EPA 6010 5.0 10.0 10 12/15/2016
Notes:
"CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
"SWS ID" is the Solid Waste Section Identification Number.
"RESULT" is the analytical data reported by the laboratory.
"µg/L" indicates unit of micrograms per liter for analytical results.
"METHOD" is the analytical method used to analyze the constituents.
"COLLECT DATE" is the date on which the sample was collected in the field.
"C9" indicates the detected constituent is a common laboratory contaminant.
"MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99%
confidence that the analyte concentration is greater than zero.
"MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the
referenced method.
"SWSL" is the Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively
determined with suitable precision and accuracy.
Table 5
Water Quality Standards Exceedances Notification
December 2016 Water Quality Report
Clay County Closed MSW Landfill
Page 1 of 1
April 2017
FACILITY
PERMIT WELL ID
CAS
NUMBER SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL
GROUNDWATER
QUALITY
STANDARD
COLLECT
DATE CAUSE AND SIGNIFICANCE
22-01 MW-1 7440-36-0 13 Antimony 33.9 µg/L EPA 6010 3.8 5.0 6 1 12/15/2016
22-01 MW-1 7440-48-4 53 Cobalt 36.2 µg/L EPA 6010 2.5 5.0 10 1 12/15/2016
22-01 MW-1 7439-92-1 131 Lead 27.5 µg/L EPA 6010 2.5 5.0 10 15 12/15/2016
22-01 MW-1 7440-62-2 209 Vanadium 14.4 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2016
22-01 MW-1 SW320 320 pH 6.3 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2016 Consistent with historic readings.
22-01 MW-2 7440-36-0 13 Antimony 6.1 µg/L EPA 6010 3.8 5.0 6 1 12/15/2016
22-01 MW-2 7440-47-3 51 Chromium 16.7 µg/L EPA 6010 2.5 5.0 10 10 12/15/2016
22-01 MW-2 7440-48-4 53 Cobalt 3.0 µg/L J EPA 6010 2.5 5.0 10 2 12/15/2016
22-01 MW-2 7440-22-4 184 Silver 20.1 µg/L EPA 6010 2.5 5.0 10 20 12/15/2016
22-01 MW-2 7440-62-2 209 Vanadium 23.4 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2016 Possibly naturally occurring.
22-01 MW-2 71-43-2 16 Benzene 1.6 µg/L EPA 8260 0.25 1.0 1 1 12/15/2016 Anthropogenic
22-01 MW-2 SW320 320 pH 5.4 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2016 Consistent with historic readings.
22-01 MW-3 7440-38-2 14 Arsenic 16.0 µg/L EPA 6010 2.5 10 10 10 12/15/2016
22-01 MW-3 7440-39-3 15 Barium 711 µg/L EPA 6010 2.5 5.0 100 700 12/15/2016
22-01 MW-3 7440-47-3 51 Chromium 42.2 µg/L EPA 6010 2.5 5.0 10 10 12/15/2016
22-01 MW-3 7440-48-4 53 Cobalt 54.3 µg/L EPA 6010 2.5 5.0 10 1 12/15/2016
22-01 MW-3 7439-92-1 131 Lead 60.3 µg/L EPA 6010 2.5 5.0 10 15 12/15/2016
22-01 MW-3 7440-62-2 209 Vanadium 72.7 µg/L EPA 6010 2.5 5.0 25 0.3 12/15/2016
22-01 MW-3 SW320 320 pH 5.9 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2016 Consistent with historic readings.
22-01 MW-4 SW320 320 pH 5.7 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2016 Consistent with historic readings.
22-01 MW-5 7440-48-4 53 Cobalt 29.1 µg/L EPA 6010 2.5 5.0 10 1 12/15/2016 Possibly naturally occurring.
22-01 MW-5 SW320 320 pH 5.6 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2016 Consistent with historic readings.
22-01 MW-6 7440-48-4 53 Vanadium 14.5 µg/L J EPA 6010 2.5 5.0 10 1 12/15/2016 Possibly naturally occurring.
Turbidity of sample is 211 NTU.
Notes:
"CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
"SWS ID" is the Solid Waste Section Identification Number.
"RESULT" is analytical data reported by the laboratory or field data collected by Environmental, Inc.
"UNITS" are micrograms per liter (µg/L) for analytical results and Standard Units (SU) for pH.
"QUALIFIER" is a data qualifier or "flag". A blank cell indicates that there is no qualifier associated with the reported result.
"METHOD" is the analytical method used to analyze the constituents.
"MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
"MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
"SWSL" is the Solid Waste Section Limit. This limit (identified by DEQ) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
"GROUNDWATER QUALITY STANDARD" refers to the 2L standard or Interim Maximum Allowable Concentration (IMAC) for groundwater.
2L standard and IMAC are from "North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards," DEQ (Last Amended April 1, 2013).
Possibly naturally occurring.
Turbidity of sample is 463 NTU.
Possibly naturally occurring.
Turbidity of sample is 342 NTU.
Anthropogenic
Possibly naturally occurring.
Turbidity of sample is 94.5 NTU.

Figures
[0 2,0001,000
Feet
LEGEND:
Subject Parcel
Publish Date: 2017/02/21, 4:31 PM | User: alesueurFilepath: P:\Projects\Environmental Inc\Clay County\Figures\MXD\2016\Figure 1 AQ.mxd
Figure 1Site Location Map
Clay County Closed MSW Landfill Water Quality ReportClay County Closed MSW Landfill, Permit No. 22-01, Hayesville, NC
SOURCE(S):Basemap: USGS 1:24,000 Scale Topo Maps, HayesvilleQuadrangle, 1987.Parcels: Clay County GIS
Anchor QEA of North Carolina, PLLC
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NOTE(S):1. Monitoring well locations surveyed by Samuel L.Sprinkle & Associates, P.A., October 18, 2011.2. Surface water sample locations are approximate andprovided by Environmental, Inc. field personnel.
LEGEND:
@A Monitoring Well Location
#
I
Surface Water Sample Location
Hydrology
Elevation Contour (20 ft)
Subject Parcel
Publish Date: 2017/02/21, 4:36 PM | User: alesueurFilepath: P:\Projects\Environmental Inc\Clay County\Figures\MXD\2016\Figure 2 AQ.mxd
Figure 2Site Layout Map
Clay County Closed MSW Landfill Water Quality ReportClay County Closed MSW Landfill, Permit No. 22-01, Hayesville, NC
SOURCE(S):Basemap: NC OneMap 2015Parcels and Elevation Contours: Clay County GISHydrology: NC OneMap 2012
Anchor QEA of North Carolina, PLLC
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MW-5(1,802.55)MW-4(1,810.97)
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NOTE(S):1. Monitoring well locations surveyed by Samuel L.Sprinkle & Associates, P.A., October 18, 2011.2. Surface water sample locations are approximateand provided by Environmental, Inc. fieldpersonnel.3. (1,804.19) = Groundwater elevation. Depth towater measurements collected on December 15,2016.
LEGEND:
@A Monitoring Well Location
#
I
Surface Water Sample Location
Hydrology
Elevation Contour (20 ft)
Subject Parcel
Publish Date: 2017/02/22, 8:32 AM | User: alesueurFilepath: P:\Projects\Environmental Inc\Clay County\Figures\MXD\2016\Figure 3 AQ.mxd
Figure 3Groundwater Elevation Map
Clay County Closed MSW Landfill Water Quality ReportClay County Closed MSW Landfill, Permit No. 22-01, Hayesville, NC
SOURCE(S):Basemap: NC OneMap 2015Parcels and Elevation Contours: ClayCounty GISHydrology: NC OneMap 2012

Appendix A
Field Sheet and Certificate of Analysis

Appendix B
Reports of Laboratory Analysis and
Chain-of-Custody Documentation
#=CL#
January 23, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323671
92323671
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #1
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 23, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Lab ID Sample ID Matrix Date Collected Date Received
92323671001 MW #1 Water 12/15/16 10:47 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323671001 MW #1 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Sample: MW #1 Lab ID: 92323671001 Collected: 12/15/16 10:47 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 33.9 ug/L 12/28/16 18:58 7440-36-012/22/16 22:255.0 3.8 1
Arsenic ND ug/L 12/28/16 02:06 7440-38-212/22/16 22:2510.0 2.5 1
Barium 125 ug/L 12/28/16 02:06 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:06 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:06 7440-43-912/22/16 22:251.0 0.50 1
Chromium 6.1 ug/L 12/28/16 02:06 7440-47-312/22/16 22:255.0 2.5 1
Cobalt 36.2 ug/L 12/28/16 02:06 7440-48-412/22/16 22:255.0 2.5 1
Copper 21.0 ug/L 12/28/16 02:06 7440-50-812/22/16 22:255.0 2.5 1
Lead 27.5 ug/L 12/28/16 02:06 7439-92-112/22/16 22:255.0 2.5 1
Nickel 9.0 ug/L 12/28/16 18:58 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:06 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:06 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:06 7440-28-012/22/16 22:255.4 5.0 1
Vanadium 14.4 ug/L 12/28/16 02:06 7440-62-212/22/16 22:255.0 2.5 1
Zinc 82.2 ug/L 12/28/16 02:06 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:14 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 21:55 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 21:55 107-13-110.0 1.9 1
Benzene ND ug/L 12/19/16 21:55 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 21:55 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 21:55 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 21:55 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 21:55 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 21:55 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 21:55 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 21:55 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/16 21:55 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 21:55 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 21:55 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 21:55 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 21:55 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 21:55 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 21:55 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 21:55 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 21:55 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/16 21:55 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 21:55 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/19/16 21:55 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 21:55 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 21:55 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/16 21:55 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 21:55 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/23/2017 04:06 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Sample: MW #1 Lab ID: 92323671001 Collected: 12/15/16 10:47 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 21:55 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 21:55 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 21:55 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 21:55 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 21:55 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 21:55 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 21:55 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 21:55 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 21:55 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 21:55 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 21:55 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 21:55 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 21:55 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 21:55 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 21:55 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 21:55 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 21:55 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 21:55 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 21:55 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 21:55 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 21:55 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 21:55 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 21:55 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)95 %12/19/16 21:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/19/16 21:55 17060-07-070-130 1
Toluene-d8 (S)100 %12/19/16 21:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323671001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323671001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/23/2017 04:06 PM
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Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323671001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323671001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323671001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323671001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
REPORT OF LABORATORY ANALYSIS
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Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323671001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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Page 13 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323671
CLAY CO LANDFILL - MW #1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323671001 341618 342417MW #1 EPA 3010A EPA 6010
92323671001 341661 341980MW #1 EPA 7470 EPA 7470
92323671001 341545MW #1 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323673
92323673
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #2
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 19
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Lab ID Sample ID Matrix Date Collected Date Received
92323673001 MW #2 Water 12/15/16 11:26 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 19
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323673001 MW #2 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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Page 4 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Sample: MW #2 Lab ID: 92323673001 Collected: 12/15/16 11:26 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 6.1 ug/L 12/28/16 19:07 7440-36-012/22/16 22:255.0 3.8 1
Arsenic ND ug/L 12/28/16 02:15 7440-38-212/22/16 22:2510.0 2.5 1
Barium 286 ug/L 12/28/16 02:15 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:15 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:15 7440-43-912/22/16 22:251.0 0.50 1
Chromium 16.7 ug/L 12/28/16 02:15 7440-47-312/22/16 22:255.0 2.5 1
Cobalt 3.0J ug/L 12/28/16 02:15 7440-48-412/22/16 22:255.0 2.5 1
Copper 15.7 ug/L 12/28/16 02:15 7440-50-812/22/16 22:255.0 2.5 1
Lead 3.8J ug/L 12/28/16 02:15 7439-92-112/22/16 22:255.0 2.5 1
Nickel 8.5 ug/L 12/28/16 19:07 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:15 7782-49-212/22/16 22:2510.0 5.0 1
Silver 20.1 ug/L 12/28/16 02:15 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:15 7440-28-012/22/16 22:255.4 5.0 1
Vanadium 23.4 ug/L 12/28/16 02:15 7440-62-212/22/16 22:255.0 2.5 1
Zinc 108 ug/L 12/28/16 02:15 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.37 ug/L 12/25/16 13:16 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 21:00 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/21/16 21:00 107-13-110.0 1.9 1
Benzene 1.6 ug/L 12/21/16 21:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 21:00 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 21:00 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 21:00 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/21/16 21:00 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 21:00 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/21/16 21:00 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/21/16 21:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 21:00 108-90-71.0 0.23 1
Chloroethane 0.72J ug/L 12/21/16 21:00 75-00-31.0 0.54 1
Chloroform ND ug/L 12/21/16 21:00 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/21/16 21:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 21:00 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 21:00 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 21:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 21:00 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 21:00 95-50-11.0 0.30 1
1,4-Dichlorobenzene 1.1 ug/L 12/21/16 21:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 21:00 110-57-61.0 1.0 1
1,1-Dichloroethane 1.7 ug/L 12/21/16 21:00 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 21:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 21:00 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 2.2 ug/L 12/21/16 21:00 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 21:00 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Sample: MW #2 Lab ID: 92323673001 Collected: 12/15/16 11:26 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 21:00 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 21:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 21:00 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 21:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/21/16 21:00 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/21/16 21:00 74-88-45.0 0.32 1
Methylene Chloride 2.2 ug/L 12/21/16 21:00 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 21:00 108-10-15.0 0.33 1
Styrene ND ug/L 12/21/16 21:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 21:00 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 21:00 79-34-5 L21.0 0.40 1
Tetrachloroethene 0.58J ug/L 12/21/16 21:00 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 21:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/21/16 21:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 21:00 79-00-51.0 0.29 1
Trichloroethene 0.87J ug/L 12/21/16 21:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 21:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 21:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 21:00 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 21:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 21:00 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/21/16 21:00 179601-23-12.0 0.66 1
o-Xylene 0.93J ug/L 12/21/16 21:00 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)104 %12/21/16 21:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 21:00 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 21:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323673001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323673001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:42 PM
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Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323673001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323673001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323673001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323673001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.33
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:270.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.40
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:270.29
1,1-Dichloroethane ug/L ND 1.0 12/21/16 16:270.32
1,1-Dichloroethene ug/L ND 1.0 12/21/16 16:270.56
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:270.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/21/16 16:272.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:270.27
1,2-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.30
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:270.24
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:270.27
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.33
2-Butanone (MEK)ug/L ND 5.0 12/21/16 16:270.96
2-Hexanone ug/L ND 5.0 12/21/16 16:270.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/21/16 16:270.33
Acetone ug/L ND 25.0 12/21/16 16:2710.0
Acrylonitrile ug/L ND 10.0 12/21/16 16:271.9
Benzene ug/L ND 1.0 12/21/16 16:270.25
Bromochloromethane ug/L ND 1.0 12/21/16 16:270.17
Bromodichloromethane ug/L ND 1.0 12/21/16 16:270.18
Bromoform ug/L ND 1.0 12/21/16 16:270.26
Bromomethane ug/L ND 2.0 12/21/16 16:270.29
Carbon disulfide ug/L ND 2.0 12/21/16 16:271.2
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:270.25
Chlorobenzene ug/L ND 1.0 12/21/16 16:270.23
Chloroethane ug/L ND 1.0 12/21/16 16:270.54
Chloroform ug/L ND 1.0 12/21/16 16:270.14
Chloromethane ug/L ND 1.0 12/21/16 16:270.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.13
Dibromochloromethane ug/L ND 1.0 12/21/16 16:270.21
Dibromomethane ug/L ND 1.0 12/21/16 16:270.21
Ethylbenzene ug/L ND 1.0 12/21/16 16:270.30
Iodomethane ug/L ND 5.0 12/21/16 16:270.32
m&p-Xylene ug/L ND 2.0 12/21/16 16:270.66
Methylene Chloride ug/L ND 1.0 12/21/16 16:270.97
o-Xylene ug/L ND 1.0 12/21/16 16:270.23
Styrene ug/L ND 1.0 12/21/16 16:270.26
Tetrachloroethene ug/L ND 1.0 12/21/16 16:270.46
Toluene ug/L ND 1.0 12/21/16 16:270.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:42 PM
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[phone]
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323673001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/21/16 16:271.0
Trichloroethene ug/L ND 1.0 12/21/16 16:270.47
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:270.20
Vinyl acetate ug/L ND 2.0 12/21/16 16:270.35
Vinyl chloride ug/L ND 1.0 12/21/16 16:270.62
Xylene (Total)ug/L ND 1.0 12/21/16 16:270.66
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L05073 79-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acrylonitrile ug/L 292250 117 40-160
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.650 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:42 PM
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Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Ethylbenzene ug/L 40.650 81 79-121
Iodomethane ug/L 75.3100 75 39-154
m&p-Xylene ug/L 90.3100 90 81-124
Methylene Chloride ug/L 54.950 110 64-133
o-Xylene ug/L 40.250 80 79-131
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.550 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2-Butanone (MEK)ug/L 35.840 89 70-130ND
2-Hexanone ug/L 39.040 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.040 97 70-130ND
Acetone ug/L 40.540 98 70-130ND
Acrylonitrile ug/L 125100 125 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.520 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Iodomethane ug/L 23.2 M14058 70-130ND
m&p-Xylene ug/L 40.640 102 70-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
o-Xylene ug/L 22.320 111 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.420 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.640 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 1.2 2 301.2J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L 0.45J 300.39J
1,4-Dichlorobenzene ug/L 1.4 0 301.4
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 0.72J 300.72J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 5.4 10 304.9
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.16J 300.11J
cis-1,2-Dichloroethene ug/L 3.3 1 303.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
m&p-Xylene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
o-Xylene ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L 0.37J 300.37J
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.76J 300.58J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 4.9 6 304.6
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associatedsamples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323673
CLAY CO LANDFILL - MW #2
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323673001 341618 342417MW #2 EPA 3010A EPA 6010
92323673001 341661 341980MW #2 EPA 7470 EPA 7470
92323673001 342010MW #2 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 17 of 19
Page 18 of 19
Page 19 of 19
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323675
92323675
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #3
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 19
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Lab ID Sample ID Matrix Date Collected Date Received
92323675001 MW #3 Water 12/15/16 11:51 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323675001 MW #3 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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Page 4 of 19
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Sample: MW #3 Lab ID: 92323675001 Collected: 12/15/16 11:51 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 19:10 7440-36-012/22/16 22:255.0 3.8 1
Arsenic 16.0 ug/L 12/28/16 02:18 7440-38-212/22/16 22:2510.0 2.5 1
Barium 711 ug/L 12/28/16 02:18 7440-39-312/22/16 22:255.0 2.5 1
Beryllium 2.0 ug/L 12/28/16 02:18 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:18 7440-43-912/22/16 22:251.0 0.50 1
Chromium 42.2 ug/L 12/28/16 02:18 7440-47-312/22/16 22:255.0 2.5 1
Cobalt 54.3 ug/L 12/28/16 02:18 7440-48-412/22/16 22:255.0 2.5 1
Copper 62.9 ug/L 12/28/16 02:18 7440-50-812/22/16 22:255.0 2.5 1
Lead 60.3 ug/L 12/28/16 02:18 7439-92-112/22/16 22:255.0 2.5 1
Nickel 31.8 ug/L 12/28/16 19:10 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:18 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:18 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:18 7440-28-012/22/16 22:255.4 5.0 1
Vanadium 72.7 ug/L 12/28/16 02:18 7440-62-212/22/16 22:255.0 2.5 1
Zinc 170 ug/L 12/28/16 02:18 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:19 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 21:17 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/21/16 21:17 107-13-110.0 1.9 1
Benzene ND ug/L 12/21/16 21:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 21:17 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 21:17 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 21:17 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/21/16 21:17 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 21:17 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/21/16 21:17 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/21/16 21:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 21:17 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/21/16 21:17 75-00-31.0 0.54 1
Chloroform ND ug/L 12/21/16 21:17 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/21/16 21:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 21:17 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 21:17 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 21:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 21:17 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 21:17 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/21/16 21:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 21:17 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/21/16 21:17 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 21:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 21:17 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 21:17 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 21:17 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Sample: MW #3 Lab ID: 92323675001 Collected: 12/15/16 11:51 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 21:17 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 21:17 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 21:17 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 21:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/21/16 21:17 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/21/16 21:17 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/21/16 21:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 21:17 108-10-15.0 0.33 1
Styrene ND ug/L 12/21/16 21:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 21:17 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 21:17 79-34-5 L21.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 21:17 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 21:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/21/16 21:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 21:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 21:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 21:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 21:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 21:17 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 21:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 21:17 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/21/16 21:17 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/21/16 21:17 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)105 %12/21/16 21:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/21/16 21:17 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 21:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323675001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323675001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323675001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323675001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:43 PM
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Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323675001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323675001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.33
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:270.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.40
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:270.29
1,1-Dichloroethane ug/L ND 1.0 12/21/16 16:270.32
1,1-Dichloroethene ug/L ND 1.0 12/21/16 16:270.56
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:270.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/21/16 16:272.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:270.27
1,2-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.30
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:270.24
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:270.27
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.33
2-Butanone (MEK)ug/L ND 5.0 12/21/16 16:270.96
2-Hexanone ug/L ND 5.0 12/21/16 16:270.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/21/16 16:270.33
Acetone ug/L ND 25.0 12/21/16 16:2710.0
Acrylonitrile ug/L ND 10.0 12/21/16 16:271.9
Benzene ug/L ND 1.0 12/21/16 16:270.25
Bromochloromethane ug/L ND 1.0 12/21/16 16:270.17
Bromodichloromethane ug/L ND 1.0 12/21/16 16:270.18
Bromoform ug/L ND 1.0 12/21/16 16:270.26
Bromomethane ug/L ND 2.0 12/21/16 16:270.29
Carbon disulfide ug/L ND 2.0 12/21/16 16:271.2
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:270.25
Chlorobenzene ug/L ND 1.0 12/21/16 16:270.23
Chloroethane ug/L ND 1.0 12/21/16 16:270.54
Chloroform ug/L ND 1.0 12/21/16 16:270.14
Chloromethane ug/L ND 1.0 12/21/16 16:270.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.13
Dibromochloromethane ug/L ND 1.0 12/21/16 16:270.21
Dibromomethane ug/L ND 1.0 12/21/16 16:270.21
Ethylbenzene ug/L ND 1.0 12/21/16 16:270.30
Iodomethane ug/L ND 5.0 12/21/16 16:270.32
m&p-Xylene ug/L ND 2.0 12/21/16 16:270.66
Methylene Chloride ug/L ND 1.0 12/21/16 16:270.97
o-Xylene ug/L ND 1.0 12/21/16 16:270.23
Styrene ug/L ND 1.0 12/21/16 16:270.26
Tetrachloroethene ug/L ND 1.0 12/21/16 16:270.46
Toluene ug/L ND 1.0 12/21/16 16:270.26
REPORT OF LABORATORY ANALYSIS
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Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323675001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/21/16 16:271.0
Trichloroethene ug/L ND 1.0 12/21/16 16:270.47
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:270.20
Vinyl acetate ug/L ND 2.0 12/21/16 16:270.35
Vinyl chloride ug/L ND 1.0 12/21/16 16:270.62
Xylene (Total)ug/L ND 1.0 12/21/16 16:270.66
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L05073 79-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acrylonitrile ug/L 292250 117 40-160
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.650 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
REPORT OF LABORATORY ANALYSIS
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Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Ethylbenzene ug/L 40.650 81 79-121
Iodomethane ug/L 75.3100 75 39-154
m&p-Xylene ug/L 90.3100 90 81-124
Methylene Chloride ug/L 54.950 110 64-133
o-Xylene ug/L 40.250 80 79-131
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.550 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2-Butanone (MEK)ug/L 35.840 89 70-130ND
2-Hexanone ug/L 39.040 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.040 97 70-130ND
Acetone ug/L 40.540 98 70-130ND
Acrylonitrile ug/L 125100 125 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.520 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Iodomethane ug/L 23.2 M14058 70-130ND
m&p-Xylene ug/L 40.640 102 70-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
o-Xylene ug/L 22.320 111 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.420 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.640 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 1.2 2 301.2J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:43 PM
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[phone]
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L 0.45J 300.39J
1,4-Dichlorobenzene ug/L 1.4 0 301.4
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 0.72J 300.72J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 5.4 10 304.9
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.16J 300.11J
cis-1,2-Dichloroethene ug/L 3.3 1 303.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
m&p-Xylene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
o-Xylene ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L 0.37J 300.37J
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.76J 300.58J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 4.9 6 304.6
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
REPORT OF LABORATORY ANALYSIS
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Page 14 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 15 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323675
CLAY CO LANDFILL - MW #3
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323675001 341618 342417MW #3 EPA 3010A EPA 6010
92323675001 341661 341980MW #3 EPA 7470 EPA 7470
92323675001 342010MW #3 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 16 of 19
Page 17 of 19
Page 18 of 19
Page 19 of 19
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323677
92323677
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #4
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Lab ID Sample ID Matrix Date Collected Date Received
92323677001 MW #4 Water 12/15/16 12:45 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323677001 MW #4 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Asheville, NC 28804
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Sample: MW #4 Lab ID: 92323677001 Collected: 12/15/16 12:45 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 19:13 7440-36-012/22/16 22:2516.7 12.7 1
Arsenic ND ug/L 12/28/16 02:21 7440-38-212/22/16 22:2533.3 8.3 1
Barium 220 ug/L 12/28/16 02:21 7440-39-312/22/16 22:2516.7 8.3 1
Beryllium ND ug/L 12/28/16 02:21 7440-41-712/22/16 22:253.3 1.7 1
Cadmium ND ug/L 12/28/16 02:21 7440-43-912/22/16 22:253.3 1.7 1
Chromium ND ug/L 12/28/16 02:21 7440-47-312/22/16 22:2516.7 8.3 1
Cobalt ND ug/L 12/28/16 02:21 7440-48-412/22/16 22:2516.7 8.3 1
Copper ND ug/L 12/28/16 02:21 7440-50-812/22/16 22:2516.7 8.3 1
Lead ND ug/L 12/28/16 02:21 7439-92-112/22/16 22:2516.7 8.3 1
Nickel ND ug/L 12/28/16 19:13 7440-02-012/22/16 22:2516.7 8.3 1
Selenium ND ug/L 12/28/16 02:21 7782-49-212/22/16 22:2533.3 16.7 1
Silver ND ug/L 12/28/16 02:21 7440-22-412/22/16 22:2516.7 8.3 1
Thallium ND ug/L 12/28/16 02:21 7440-28-012/22/16 22:2518.0 16.7 1
Vanadium ND ug/L 12/28/16 02:21 7440-62-212/22/16 22:2516.7 8.3 1
Zinc ND ug/L 12/28/16 02:21 7440-66-612/22/16 22:2533.3 16.7 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.55 ug/L 12/25/16 13:21 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 22:12 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 22:12 107-13-110.0 1.9 1
Benzene 0.63J ug/L 12/19/16 22:12 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 22:12 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 22:12 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 22:12 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 22:12 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 22:12 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 22:12 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 22:12 56-23-51.0 0.25 1
Chlorobenzene 0.53J ug/L 12/19/16 22:12 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 22:12 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 22:12 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 22:12 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 22:12 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 22:12 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 22:12 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 22:12 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 22:12 95-50-11.0 0.30 1
1,4-Dichlorobenzene 1.5 ug/L 12/19/16 22:12 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 22:12 110-57-61.0 1.0 1
1,1-Dichloroethane 1.3 ug/L 12/19/16 22:12 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 22:12 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 22:12 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 3.0 ug/L 12/19/16 22:12 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 22:12 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Sample: MW #4 Lab ID: 92323677001 Collected: 12/15/16 12:45 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 22:12 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 22:12 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 22:12 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 22:12 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 22:12 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 22:12 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 22:12 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 22:12 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 22:12 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 22:12 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 22:12 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 22:12 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 22:12 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 22:12 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 22:12 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 22:12 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 22:12 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 22:12 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 22:12 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 22:12 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 22:12 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 22:12 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 22:12 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)94 %12/19/16 22:12 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/19/16 22:12 17060-07-070-130 1
Toluene-d8 (S)102 %12/19/16 22:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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Asheville, NC 28804
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Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323677001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323677001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323677001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323677001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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Asheville, NC 28804
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Page 8 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323677001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323677001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323677001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
REPORT OF LABORATORY ANALYSIS
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Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323677
CLAY CO LANDFILL - MW #4
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323677001 341618 342417MW #4 EPA 3010A EPA 6010
92323677001 341661 341980MW #4 EPA 7470 EPA 7470
92323677001 341545MW #4 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323679
92323679
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #5
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Lab ID Sample ID Matrix Date Collected Date Received
92323679001 MW #5 Water 12/15/16 12:27 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323679001 MW #5 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Sample: MW #5 Lab ID: 92323679001 Collected: 12/15/16 12:27 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 19:25 7440-36-012/22/16 22:255.0 3.8 1
Arsenic 3.6J ug/L 12/28/16 02:24 7440-38-212/22/16 22:2510.0 2.5 1
Barium 180 ug/L 12/28/16 02:24 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:24 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:24 7440-43-912/22/16 22:251.0 0.50 1
Chromium ND ug/L 12/28/16 02:24 7440-47-312/22/16 22:255.0 2.5 1
Cobalt 29.1 ug/L 12/28/16 02:24 7440-48-412/22/16 22:255.0 2.5 1
Copper 6.2 ug/L 12/28/16 02:24 7440-50-812/22/16 22:255.0 2.5 1
Lead ND ug/L 12/28/16 02:24 7439-92-112/22/16 22:255.0 2.5 1
Nickel 3.6J ug/L 12/28/16 19:25 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:24 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:24 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:24 7440-28-012/22/16 22:255.4 5.0 1
Vanadium ND ug/L 12/28/16 02:24 7440-62-212/22/16 22:255.0 2.5 1
Zinc 15.6 ug/L 12/28/16 02:24 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.25 ug/L 12/25/16 13:28 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 22:29 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 22:29 107-13-110.0 1.9 1
Benzene 0.84J ug/L 12/19/16 22:29 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 22:29 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 22:29 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 22:29 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 22:29 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 22:29 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 22:29 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 22:29 56-23-51.0 0.25 1
Chlorobenzene 1.4 ug/L 12/19/16 22:29 108-90-71.0 0.23 1
Chloroethane 0.81J ug/L 12/19/16 22:29 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 22:29 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 22:29 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 22:29 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 22:29 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 22:29 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 22:29 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 22:29 95-50-11.0 0.30 1
1,4-Dichlorobenzene 2.5 ug/L 12/19/16 22:29 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 22:29 110-57-61.0 1.0 1
1,1-Dichloroethane 0.71J ug/L 12/19/16 22:29 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 22:29 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 22:29 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 6.2 ug/L 12/19/16 22:29 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 22:29 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Sample: MW #5 Lab ID: 92323679001 Collected: 12/15/16 12:27 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 22:29 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 22:29 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 22:29 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 22:29 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 22:29 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 22:29 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 22:29 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 22:29 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 22:29 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 22:29 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 22:29 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 22:29 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 22:29 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 22:29 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 22:29 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 22:29 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 22:29 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 22:29 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 22:29 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 22:29 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 22:29 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 22:29 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 22:29 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)95 %12/19/16 22:29 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/19/16 22:29 17060-07-070-130 1
Toluene-d8 (S)100 %12/19/16 22:29 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323679001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323679001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323679001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323679001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323679001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323679001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323679001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323679
CLAY CO LANDFILL - MW #5
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323679001 341618 342417MW #5 EPA 3010A EPA 6010
92323679001 341661 341980MW #5 EPA 7470 EPA 7470
92323679001 341545MW #5 EPA 8260
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323680
92323680
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - MW #6
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Lab ID Sample ID Matrix Date Collected Date Received
92323680001 MW #6 Water 12/15/16 13:04 12/16/16 10:20
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323680001 MW #6 EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Sample: MW #6 Lab ID: 92323680001 Collected: 12/15/16 13:04 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 19:29 7440-36-012/22/16 22:255.0 3.8 1
Arsenic 3.9J ug/L 12/28/16 02:27 7440-38-212/22/16 22:2510.0 2.5 1
Barium 369 ug/L 12/28/16 02:27 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:27 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:27 7440-43-912/22/16 22:251.0 0.50 1
Chromium ND ug/L 12/28/16 02:27 7440-47-312/22/16 22:255.0 2.5 1
Cobalt ND ug/L 12/28/16 02:27 7440-48-412/22/16 22:255.0 2.5 1
Copper ND ug/L 12/28/16 02:27 7440-50-812/22/16 22:255.0 2.5 1
Lead 11.0 ug/L 12/28/16 02:27 7439-92-112/22/16 22:255.0 2.5 1
Nickel 5.1 ug/L 12/28/16 19:29 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:27 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:27 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:27 7440-28-012/22/16 22:255.4 5.0 1
Vanadium 14.5 ug/L 12/28/16 02:27 7440-62-212/22/16 22:255.0 2.5 1
Zinc 16.4 ug/L 12/28/16 02:27 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:30 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 22:46 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 22:46 107-13-110.0 1.9 1
Benzene ND ug/L 12/19/16 22:46 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 22:46 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 22:46 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 22:46 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 22:46 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 22:46 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 22:46 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 22:46 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/16 22:46 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 22:46 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 22:46 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 22:46 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 22:46 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 22:46 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 22:46 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 22:46 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 22:46 95-50-11.0 0.30 1
1,4-Dichlorobenzene 0.59J ug/L 12/19/16 22:46 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 22:46 110-57-61.0 1.0 1
1,1-Dichloroethane 0.85J ug/L 12/19/16 22:46 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 22:46 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 22:46 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 3.9 ug/L 12/19/16 22:46 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 22:46 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Sample: MW #6 Lab ID: 92323680001 Collected: 12/15/16 13:04 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 22:46 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 22:46 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 22:46 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 22:46 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 22:46 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 22:46 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 22:46 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 22:46 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 22:46 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 22:46 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 22:46 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 22:46 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 22:46 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 22:46 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 22:46 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 22:46 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 22:46 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 22:46 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 22:46 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 22:46 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 22:46 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 22:46 179601-23-12.0 0.66 1
o-Xylene 0.70J ug/L 12/19/16 22:46 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)95 %12/19/16 22:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %12/19/16 22:46 17060-07-070-130 1
Toluene-d8 (S)99 %12/19/16 22:46 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323680001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323680001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323680001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323680001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Asheville, NC 28804
[phone]
Page 8 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Asheville, NC 28804
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323680001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323680001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323680001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
REPORT OF LABORATORY ANALYSIS
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Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323680
CLAY CO LANDFILL - MW #6
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323680001 341618 342417MW #6 EPA 3010A EPA 6010
92323680001 341661 341980MW #6 EPA 7470 EPA 7470
92323680001 341545MW #6 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:50 PM
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323681
92323681
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - DOWNSTREAM
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Lab ID Sample ID Matrix Date Collected Date Received
92323681001 DOWNSTREAM Water 12/15/16 13:25 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323681001 DOWNSTREAM EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Sample: DOWNSTREAM Lab ID: 92323681001 Collected: 12/15/16 13:25 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 19:32 7440-36-012/22/16 22:255.0 3.8 1
Arsenic ND ug/L 12/28/16 02:30 7440-38-212/22/16 22:2510.0 2.5 1
Barium 8.5 ug/L 12/28/16 02:30 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:30 7440-41-712/22/16 22:251.0 0.50 1
Cadmium 0.58J ug/L 12/28/16 02:30 7440-43-912/22/16 22:251.0 0.50 1
Chromium ND ug/L 12/28/16 02:30 7440-47-312/22/16 22:255.0 2.5 1
Cobalt ND ug/L 12/28/16 02:30 7440-48-412/22/16 22:255.0 2.5 1
Copper ND ug/L 12/28/16 02:30 7440-50-812/22/16 22:255.0 2.5 1
Lead ND ug/L 12/28/16 02:30 7439-92-112/22/16 22:255.0 2.5 1
Nickel ND ug/L 12/28/16 19:32 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:30 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:30 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:30 7440-28-012/22/16 22:255.4 5.0 1
Vanadium ND ug/L 12/28/16 02:30 7440-62-212/22/16 22:255.0 2.5 1
Zinc ND ug/L 12/28/16 02:30 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:33 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 23:03 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 23:03 107-13-110.0 1.9 1
Benzene ND ug/L 12/19/16 23:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 23:03 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 23:03 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 23:03 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 23:03 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 23:03 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 23:03 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 23:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/16 23:03 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 23:03 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 23:03 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 23:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 23:03 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 23:03 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 23:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 23:03 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 23:03 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/16 23:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 23:03 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/19/16 23:03 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 23:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 23:03 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/16 23:03 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 23:03 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Sample: DOWNSTREAM Lab ID: 92323681001 Collected: 12/15/16 13:25 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 23:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 23:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 23:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 23:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 23:03 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 23:03 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 23:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 23:03 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 23:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 23:03 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 23:03 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 23:03 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 23:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 23:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 23:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 23:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 23:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 23:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 23:03 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 23:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 23:03 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 23:03 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 23:03 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)92 %12/19/16 23:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %12/19/16 23:03 17060-07-070-130 1
Toluene-d8 (S)101 %12/19/16 23:03 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323681001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323681001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323681001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323681001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323681001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323681001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323681001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323681
CLAY CO LANDFILL - DOWNSTREAM
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323681001 341618 342417DOWNSTREAMEPA 3010A EPA 6010
92323681001 341661 341980DOWNSTREAMEPA 7470 EPA 7470
92323681001 341545DOWNSTREAMEPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323683
92323683
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - UPSTREAM
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Lab ID Sample ID Matrix Date Collected Date Received
92323683001 UPSTREAM Water 12/15/16 12:02 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323683001 UPSTREAM EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Sample: UPSTREAM Lab ID: 92323683001 Collected: 12/15/16 12:02 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 02:43 7440-36-012/22/16 22:255.0 3.8 1
Arsenic ND ug/L 12/28/16 02:43 7440-38-212/22/16 22:2510.0 2.5 1
Barium 29.0 ug/L 12/28/16 02:43 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:43 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:43 7440-43-912/22/16 22:251.0 0.50 1
Chromium ND ug/L 12/28/16 02:43 7440-47-312/22/16 22:255.0 2.5 1
Cobalt ND ug/L 12/28/16 02:43 7440-48-412/22/16 22:255.0 2.5 1
Copper ND ug/L 12/28/16 02:43 7440-50-812/22/16 22:255.0 2.5 1
Lead ND ug/L 12/28/16 02:43 7439-92-112/22/16 22:255.0 2.5 1
Nickel ND ug/L 12/28/16 02:43 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:43 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:43 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:43 7440-28-012/22/16 22:255.4 5.0 1
Vanadium ND ug/L 12/28/16 02:43 7440-62-212/22/16 22:255.0 2.5 1
Zinc ND ug/L 12/28/16 02:43 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 05:45 7439-97-612/22/16 02:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 21:34 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/21/16 21:34 107-13-110.0 1.9 1
Benzene ND ug/L 12/21/16 21:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 21:34 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 21:34 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 21:34 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/21/16 21:34 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 21:34 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/21/16 21:34 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/21/16 21:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 21:34 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/21/16 21:34 75-00-31.0 0.54 1
Chloroform ND ug/L 12/21/16 21:34 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/21/16 21:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 21:34 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 21:34 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 21:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 21:34 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 21:34 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/21/16 21:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 21:34 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/21/16 21:34 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 21:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 21:34 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 21:34 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 21:34 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Sample: UPSTREAM Lab ID: 92323683001 Collected: 12/15/16 12:02 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/21/16 21:34 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 21:34 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 21:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 21:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/21/16 21:34 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/21/16 21:34 74-88-4 M15.0 0.32 1
Methylene Chloride ND ug/L 12/21/16 21:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 21:34 108-10-15.0 0.33 1
Styrene ND ug/L 12/21/16 21:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 21:34 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 21:34 79-34-5 L21.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 21:34 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 21:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/21/16 21:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 21:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 21:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 21:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 21:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 21:34 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 21:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 21:34 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/21/16 21:34 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/21/16 21:34 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)104 %12/21/16 21:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 21:34 17060-07-070-130 1
Toluene-d8 (S)97 %12/21/16 21:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Page 6 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341884
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323683001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896911
Associated Lab Samples:92323683001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/23/16 05:090.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896912LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896913MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896914
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 90 75-12592 2 252.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Page 7 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323683001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323683001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Asheville, NC 28804
[phone]
Page 8 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Asheville, NC 28804
[phone]
Page 9 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323683001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323683001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.33
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:270.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/21/16 16:270.40
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:270.29
1,1-Dichloroethane ug/L ND 1.0 12/21/16 16:270.32
1,1-Dichloroethene ug/L ND 1.0 12/21/16 16:270.56
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:270.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/21/16 16:272.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:270.27
1,2-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.30
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:270.24
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:270.27
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.33
2-Butanone (MEK)ug/L ND 5.0 12/21/16 16:270.96
2-Hexanone ug/L ND 5.0 12/21/16 16:270.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/21/16 16:270.33
Acetone ug/L ND 25.0 12/21/16 16:2710.0
Acrylonitrile ug/L ND 10.0 12/21/16 16:271.9
Benzene ug/L ND 1.0 12/21/16 16:270.25
Bromochloromethane ug/L ND 1.0 12/21/16 16:270.17
Bromodichloromethane ug/L ND 1.0 12/21/16 16:270.18
Bromoform ug/L ND 1.0 12/21/16 16:270.26
Bromomethane ug/L ND 2.0 12/21/16 16:270.29
Carbon disulfide ug/L ND 2.0 12/21/16 16:271.2
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:270.25
Chlorobenzene ug/L ND 1.0 12/21/16 16:270.23
Chloroethane ug/L ND 1.0 12/21/16 16:270.54
Chloroform ug/L ND 1.0 12/21/16 16:270.14
Chloromethane ug/L ND 1.0 12/21/16 16:270.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.13
Dibromochloromethane ug/L ND 1.0 12/21/16 16:270.21
Dibromomethane ug/L ND 1.0 12/21/16 16:270.21
Ethylbenzene ug/L ND 1.0 12/21/16 16:270.30
Iodomethane ug/L ND 5.0 12/21/16 16:270.32
m&p-Xylene ug/L ND 2.0 12/21/16 16:270.66
Methylene Chloride ug/L ND 1.0 12/21/16 16:270.97
o-Xylene ug/L ND 1.0 12/21/16 16:270.23
Styrene ug/L ND 1.0 12/21/16 16:270.26
Tetrachloroethene ug/L ND 1.0 12/21/16 16:270.46
Toluene ug/L ND 1.0 12/21/16 16:270.26
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 10 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897428
Associated Lab Samples:92323683001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/21/16 16:270.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/21/16 16:271.0
Trichloroethene ug/L ND 1.0 12/21/16 16:270.47
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:270.20
Vinyl acetate ug/L ND 2.0 12/21/16 16:270.35
Vinyl chloride ug/L ND 1.0 12/21/16 16:270.62
Xylene (Total)ug/L ND 1.0 12/21/16 16:270.66
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L05073 79-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acrylonitrile ug/L 292250 117 40-160
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.650 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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[phone]
Page 11 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Ethylbenzene ug/L 40.650 81 79-121
Iodomethane ug/L 75.3100 75 39-154
m&p-Xylene ug/L 90.3100 90 81-124
Methylene Chloride ug/L 54.950 110 64-133
o-Xylene ug/L 40.250 80 79-131
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.550 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2-Butanone (MEK)ug/L 35.840 89 70-130ND
2-Hexanone ug/L 39.040 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.040 97 70-130ND
Acetone ug/L 40.540 98 70-130ND
Acrylonitrile ug/L 125100 125 70-130ND
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 12 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.520 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Iodomethane ug/L 23.2 M14058 70-130ND
m&p-Xylene ug/L 40.640 102 70-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
o-Xylene ug/L 22.320 111 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.420 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.640 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 1.2 2 301.2J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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[phone]
Page 13 of 19
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L 0.45J 300.39J
1,4-Dichlorobenzene ug/L 1.4 0 301.4
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 0.72J 300.72J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 5.4 10 304.9
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.16J 300.11J
cis-1,2-Dichloroethene ug/L 3.3 1 303.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
m&p-Xylene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
o-Xylene ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L 0.37J 300.37J
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.76J 300.58J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 4.9 6 304.6
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 14 of 19
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Asheville, NC 28804
[phone]
Page 15 of 19
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323683
CLAY CO LANDFILL - UPSTREAM
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323683001 341618 342417UPSTREAMEPA 3010A EPA 6010
92323683001 341884 342175UPSTREAMEPA 7470 EPA 7470
92323683001 342010UPSTREAMEPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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[phone]
Page 16 of 19
Page 17 of 19
Page 18 of 19
Page 19 of 19
#=CL#
January 24, 2017
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92323684
92323684
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO LANDFILL - BLANKS
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
A revised laboratory report is being submitted on January 24, 2017, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92323684001 EQUIPMENT BLANK Water 12/15/16 13:10 12/16/16 10:20
92323684002 TRIP BLANK Water 12/15/16 00:00 12/16/16 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Asheville, NC 28804
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Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323684001 EQUIPMENT BLANK EPA 6010 15 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
92323684002 TRIP BLANK EPA 8260 52 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
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Asheville, NC 28804
[phone]
Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Sample: EQUIPMENT BLANK Lab ID: 92323684001 Collected: 12/15/16 13:10 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/28/16 02:46 7440-36-012/22/16 22:255.0 3.8 1
Arsenic ND ug/L 12/28/16 02:46 7440-38-212/22/16 22:2510.0 2.5 1
Barium ND ug/L 12/28/16 02:46 7440-39-312/22/16 22:255.0 2.5 1
Beryllium ND ug/L 12/28/16 02:46 7440-41-712/22/16 22:251.0 0.50 1
Cadmium ND ug/L 12/28/16 02:46 7440-43-912/22/16 22:251.0 0.50 1
Chromium ND ug/L 12/28/16 02:46 7440-47-312/22/16 22:255.0 2.5 1
Cobalt ND ug/L 12/28/16 02:46 7440-48-412/22/16 22:255.0 2.5 1
Copper ND ug/L 12/28/16 02:46 7440-50-812/22/16 22:255.0 2.5 1
Lead ND ug/L 12/28/16 02:46 7439-92-112/22/16 22:255.0 2.5 1
Nickel ND ug/L 12/28/16 02:46 7440-02-012/22/16 22:255.0 2.5 1
Selenium ND ug/L 12/28/16 02:46 7782-49-212/22/16 22:2510.0 5.0 1
Silver ND ug/L 12/28/16 02:46 7440-22-412/22/16 22:255.0 2.5 1
Thallium ND ug/L 12/28/16 02:46 7440-28-012/22/16 22:255.4 5.0 1
Vanadium ND ug/L 12/28/16 02:46 7440-62-212/22/16 22:255.0 2.5 1
Zinc ND ug/L 12/28/16 02:46 7440-66-612/22/16 22:2510.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/23/16 05:47 7439-97-612/22/16 02:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 20:13 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 20:13 107-13-110.0 1.9 1
Benzene ND ug/L 12/19/16 20:13 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 20:13 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 20:13 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 20:13 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 20:13 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 20:13 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 20:13 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 20:13 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/16 20:13 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 20:13 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 20:13 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 20:13 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 20:13 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 20:13 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 20:13 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 20:13 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 20:13 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/16 20:13 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 20:13 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/19/16 20:13 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 20:13 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 20:13 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/16 20:13 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 20:13 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Sample: EQUIPMENT BLANK Lab ID: 92323684001 Collected: 12/15/16 13:10 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/19/16 20:13 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 20:13 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 20:13 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 20:13 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 20:13 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 20:13 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 20:13 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 20:13 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 20:13 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 20:13 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 20:13 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 20:13 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 20:13 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 20:13 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 20:13 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 20:13 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 20:13 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 20:13 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 20:13 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 20:13 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/19/16 20:13 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 20:13 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 20:13 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)93 %12/19/16 20:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %12/19/16 20:13 17060-07-070-130 1
Toluene-d8 (S)101 %12/19/16 20:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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2225 Riverside Dr.
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Page 6 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Sample: TRIP BLANK Lab ID: 92323684002 Collected: 12/15/16 00:00 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/19/16 19:56 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/19/16 19:56 107-13-110.0 1.9 1
Benzene ND ug/L 12/19/16 19:56 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/19/16 19:56 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/19/16 19:56 75-27-41.0 0.18 1
Bromoform ND ug/L 12/19/16 19:56 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/19/16 19:56 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/19/16 19:56 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/19/16 19:56 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/19/16 19:56 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/19/16 19:56 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/19/16 19:56 75-00-31.0 0.54 1
Chloroform ND ug/L 12/19/16 19:56 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/19/16 19:56 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/19/16 19:56 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/19/16 19:56 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/19/16 19:56 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/19/16 19:56 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/19/16 19:56 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/19/16 19:56 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/19/16 19:56 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/19/16 19:56 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/19/16 19:56 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/19/16 19:56 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/19/16 19:56 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/19/16 19:56 156-60-51.0 0.49 1
1,2-Dichloropropane ND ug/L 12/19/16 19:56 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/19/16 19:56 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/19/16 19:56 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/19/16 19:56 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/19/16 19:56 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/19/16 19:56 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/19/16 19:56 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/19/16 19:56 108-10-15.0 0.33 1
Styrene ND ug/L 12/19/16 19:56 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/19/16 19:56 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/19/16 19:56 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/19/16 19:56 127-18-41.0 0.46 1
Toluene ND ug/L 12/19/16 19:56 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/19/16 19:56 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/19/16 19:56 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/19/16 19:56 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/19/16 19:56 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/19/16 19:56 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/19/16 19:56 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/19/16 19:56 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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2225 Riverside Dr.
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[phone]
Page 7 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Sample: TRIP BLANK Lab ID: 92323684002 Collected: 12/15/16 00:00 Received: 12/16/16 10:20 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 12/19/16 19:56 1330-20-71.0 0.66 1
m&p-Xylene ND ug/L 12/19/16 19:56 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/19/16 19:56 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)94 %12/19/16 19:56 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/19/16 19:56 17060-07-070-130 1
Toluene-d8 (S)101 %12/19/16 19:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341884
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323684001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896911
Associated Lab Samples:92323684001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/23/16 05:090.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896912LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896913MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896914
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 90 75-12592 2 252.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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2225 Riverside Dr.
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Page 9 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341618
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323684001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895445
Associated Lab Samples:92323684001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/28/16 18:483.8
Arsenic ug/L ND 10.0 12/28/16 01:502.5
Barium ug/L ND 5.0 12/28/16 01:502.5
Beryllium ug/L ND 1.0 12/28/16 01:500.50
Cadmium ug/L ND 1.0 12/28/16 01:500.50
Chromium ug/L ND 5.0 12/28/16 01:502.5
Cobalt ug/L ND 5.0 12/28/16 01:502.5
Copper ug/L ND 5.0 12/28/16 01:502.5
Lead ug/L ND 5.0 12/28/16 01:502.5
Nickel ug/L ND 5.0 12/28/16 18:482.5
Selenium ug/L ND 10.0 12/28/16 01:505.0
Silver ug/L ND 5.0 12/28/16 01:502.5
Thallium ug/L ND 5.4 12/28/16 01:505.0
Vanadium ug/L ND 5.0 12/28/16 01:502.5
Zinc ug/L ND 10.0 12/28/16 01:505.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895446LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 463500 93 80-120
Arsenic ug/L 484500 97 80-120
Barium ug/L 505500 101 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 506500 101 80-120
Chromium ug/L 493500 99 80-120
Cobalt ug/L 501500 100 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 497500 99 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 498500 100 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 477500 95 80-120
Vanadium ug/L 478500 96 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1899018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323671001
1899019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-12587 3 2550033.9 480 467
Arsenic ug/L 500 104 75-12597 7 25500ND523 489
Barium ug/L 500 116 75-125104 9 25500125704 645
Beryllium ug/L 500 105 75-12596 9 25500ND524 480
Cadmium ug/L 500 109 75-125102 6 25500ND543 512
Chromium ug/L 500 109 75-125100 9 255006.1 552 504
Cobalt ug/L 500 109 75-125101 7 2550036.2 583 543
Copper ug/L 500 110 75-125101 8 2550021.0 569 524
Lead ug/L 500 107 75-12599 7 2550027.5 563 524
Nickel ug/L 500 100 75-12597 3 255009.0 510 496
Selenium ug/L 500 106 75-12599 7 25500ND528 494
Silver ug/L 250 103 75-12597 6 25250ND259 243
Thallium ug/L 500 104 75-12597 6 25500ND523 491
Vanadium ug/L 500 108 75-12598 9 2550014.4 555 505
Zinc ug/L 500 122 75-125100 17 2550082.2 693 584
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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[phone]
Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341545
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323684001, 92323684002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323684001, 92323684002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.33
1,1,1-Trichloroethane ug/L ND 1.0 12/19/16 18:310.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/19/16 18:310.40
1,1,2-Trichloroethane ug/L ND 1.0 12/19/16 18:310.29
1,1-Dichloroethane ug/L ND 1.0 12/19/16 18:310.32
1,1-Dichloroethene ug/L ND 1.0 12/19/16 18:310.56
1,2,3-Trichloropropane ug/L ND 1.0 12/19/16 18:310.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/19/16 18:312.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/19/16 18:310.27
1,2-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.30
1,2-Dichloroethane ug/L ND 1.0 12/19/16 18:310.24
1,2-Dichloropropane ug/L ND 1.0 12/19/16 18:310.27
1,4-Dichlorobenzene ug/L ND 1.0 12/19/16 18:310.33
2-Butanone (MEK)ug/L ND 5.0 12/19/16 18:310.96
2-Hexanone ug/L ND 5.0 12/19/16 18:310.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/19/16 18:310.33
Acetone ug/L ND 25.0 12/19/16 18:3110.0
Acrylonitrile ug/L ND 10.0 12/19/16 18:311.9
Benzene ug/L ND 1.0 12/19/16 18:310.25
Bromochloromethane ug/L ND 1.0 12/19/16 18:310.17
Bromodichloromethane ug/L ND 1.0 12/19/16 18:310.18
Bromoform ug/L ND 1.0 12/19/16 18:310.26
Bromomethane ug/L ND 2.0 12/19/16 18:310.29
Carbon disulfide ug/L ND 2.0 12/19/16 18:311.2
Carbon tetrachloride ug/L ND 1.0 12/19/16 18:310.25
Chlorobenzene ug/L ND 1.0 12/19/16 18:310.23
Chloroethane ug/L ND 1.0 12/19/16 18:310.54
Chloroform ug/L ND 1.0 12/19/16 18:310.14
Chloromethane ug/L ND 1.0 12/19/16 18:310.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.13
Dibromochloromethane ug/L ND 1.0 12/19/16 18:310.21
Dibromomethane ug/L ND 1.0 12/19/16 18:310.21
Ethylbenzene ug/L ND 1.0 12/19/16 18:310.30
Iodomethane ug/L ND 5.0 12/19/16 18:310.32
m&p-Xylene ug/L ND 2.0 12/19/16 18:310.66
Methylene Chloride ug/L ND 1.0 12/19/16 18:310.97
o-Xylene ug/L ND 1.0 12/19/16 18:310.23
Styrene ug/L ND 1.0 12/19/16 18:310.26
Tetrachloroethene ug/L ND 1.0 12/19/16 18:310.46
Toluene ug/L ND 1.0 12/19/16 18:310.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895095
Associated Lab Samples:92323684001, 92323684002
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/19/16 18:310.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/19/16 18:310.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/19/16 18:311.0
Trichloroethene ug/L ND 1.0 12/19/16 18:310.47
Trichlorofluoromethane ug/L ND 1.0 12/19/16 18:310.20
Vinyl acetate ug/L ND 2.0 12/19/16 18:310.35
Vinyl chloride ug/L ND 1.0 12/19/16 18:310.62
Xylene (Total)ug/L ND 1.0 12/19/16 18:310.66
1,2-Dichloroethane-d4 (S)%102 70-130 12/19/16 18:31
4-Bromofluorobenzene (S)%94 70-130 12/19/16 18:31
Toluene-d8 (S)%100 70-130 12/19/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.150 94 80-125
1,1,1-Trichloroethane ug/L 49.750 99 71-129
1,1,2,2-Tetrachloroethane ug/L 49.850 100 79-124
1,1,2-Trichloroethane ug/L 51.050 102 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.050 114 66-135
1,2,3-Trichloropropane ug/L 47.250 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.450 95 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 47.650 95 67-128
1,2-Dichloropropane ug/L 52.050 104 75-132
1,4-Dichlorobenzene ug/L 47.850 96 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 107100 107 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 104100 104 48-146
Acrylonitrile ug/L 302250 121 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 49.250 98 78-124
Bromoform ug/L 44.650 89 71-128
Bromomethane ug/L 48.550 97 40-160
Carbon disulfide ug/L 59.150 118 50-160
Carbon tetrachloride ug/L 46.950 94 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 56.050 112 39-148
Chloroform ug/L 50.750 101 73-127
Chloromethane ug/L 57.350 115 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/24/2017 01:55 PM
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Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895096LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.750 107 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 47.750 95 78-125
Dibromomethane ug/L 47.550 95 82-120
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 102100 102 39-154
m&p-Xylene ug/L 97.1100 97 81-124
Methylene Chloride ug/L 54.250 108 64-133
o-Xylene ug/L 48.250 96 79-131
Styrene ug/L 49.050 98 84-126
Tetrachloroethene ug/L 44.050 88 78-122
Toluene ug/L 50.050 100 80-121
trans-1,2-Dichloroethene ug/L 56.750 113 71-127
trans-1,3-Dichloropropene ug/L 51.250 102 69-141
trans-1,4-Dichloro-2-butene ug/L 51.050 102 40-160
Trichloroethene ug/L 47.550 95 78-122
Trichlorofluoromethane ug/L 56.050 112 53-137
Vinyl acetate ug/L 116100 116 40-160
Vinyl chloride ug/L 47.750 95 58-137
Xylene (Total)ug/L 145150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 101 70-13098 3 3020ND20.3 19.7
1,1,1-Trichloroethane ug/L 20 112 70-130110 2 3020ND22.3 22.0
1,1,2,2-Tetrachloroethane ug/L 20 106 70-130101 4 3020ND21.1 20.2
1,1,2-Trichloroethane ug/L 20 107 70-130104 2 3020ND21.4 20.9
1,1-Dichloroethane ug/L 20 121 70-130119 1 3020ND24.2 23.8
1,1-Dichloroethene ug/L 20 133 70-166129 3 3020ND26.6 25.8
1,2,3-Trichloropropane ug/L 20 98 70-13096 2 3020ND19.6 19.2
1,2-Dibromo-3-
chloropropane ug/L 20 96 70-13093 4 3020ND19.3 18.5
1,2-Dibromoethane (EDB) ug/L 20 102 70-13099 4 3020ND20.5 19.7
1,2-Dichlorobenzene ug/L 20 103 70-130100 3 3020ND20.7 20.1
1,2-Dichloroethane ug/L 20 107 70-130101 6 3020ND21.5 20.3
1,2-Dichloropropane ug/L 20 113 70-130113 0 3020ND22.7 22.7
1,4-Dichlorobenzene ug/L 20 102 70-130100 2 3020ND20.4 19.9
2-Butanone (MEK)ug/L 40 116 70-130117 1 3040ND46.6 46.9
2-Hexanone ug/L 40 111 70-130107 4 3040ND44.3 42.7
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-130108 4 3040ND45.0 43.1
REPORT OF LABORATORY ANALYSIS
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Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895097MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895098
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acetone ug/L 40 107 70-130101 5 3040ND42.6 40.5
Acrylonitrile ug/L 100 128 70-130123 4 30100ND128 123
Benzene ug/L 20 116 70-148114 2 3020ND23.1 22.7
Bromochloromethane ug/L 20 114 70-130110 3 3020ND22.7 22.0
Bromodichloromethane ug/L 20 106 70-130104 2 3020ND21.2 20.7
Bromoform ug/L 20 94 70-13090 4 3020ND18.8 18.0
Bromomethane ug/L 20 106 70-130118 10 3020ND21.3 23.6
Carbon disulfide ug/L M12013770-130138 0 3020ND27.4 27.5
Carbon tetrachloride ug/L 20 106 70-130105 1 3020ND21.2 21.1
Chlorobenzene ug/L 20 105 70-146104 1 3020ND21.0 20.7
Chloroethane ug/L M12013270-130126 5 3020ND26.5 25.3
Chloroform ug/L 20 113 70-130110 3 3020ND22.6 22.1
Chloromethane ug/L M12014170-130139 1 3020ND28.2 27.8
cis-1,2-Dichloroethene ug/L 20 120 70-130116 3 30200.30J 24.2 23.5
cis-1,3-Dichloropropene ug/L 20 104 70-130101 2 3020ND20.8 20.3
Dibromochloromethane ug/L 20 103 70-130100 3 3020ND20.5 20.0
Dibromomethane ug/L 20 102 70-13098 4 3020ND20.4 19.5
Ethylbenzene ug/L 20 107 70-130106 1 3020ND21.3 21.2
Iodomethane ug/L 40 96 70-130112 15 3040ND38.3 44.6
m&p-Xylene ug/L 40 106 70-130104 2 3040ND42.4 41.6
Methylene Chloride ug/L 20 118 70-130114 3 3020ND23.6 22.9
o-Xylene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Styrene ug/L 20 104 70-130102 2 3020ND20.8 20.4
Tetrachloroethene ug/L 20 99 70-13097 2 3020ND19.8 19.4
Toluene ug/L 20 110 70-155107 2 3020ND21.9 21.5
trans-1,2-Dichloroethene ug/L 20 125 70-130123 2 3020ND25.0 24.5
trans-1,3-Dichloropropene ug/L 20 104 70-130100 3 3020ND20.7 20.1
trans-1,4-Dichloro-2-butene ug/L 20 97 70-13091 6 3020ND19.4 18.3
Trichloroethene ug/L 20 107 69-151105 2 3020ND21.4 21.0
Trichlorofluoromethane ug/L M12013170-130129 1 3020ND26.2 25.8
Vinyl acetate ug/L 40 111 70-130104 7 3040ND44.4 41.5
Vinyl chloride ug/L 20 116 70-130114 1 3020ND23.1 22.8
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Asheville, NC 28804
[phone]
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323684
CLAY CO LANDFILL - BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323684001 341618 342417EQUIPMENT BLANK EPA 3010A EPA 6010
92323684001 341884 342175EQUIPMENT BLANK EPA 7470 EPA 7470
92323684001 341545EQUIPMENT BLANK EPA 8260
92323684002 341545TRIP BLANK EPA 8260
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 17 of 20
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