Loading...
HomeMy WebLinkAbout0403_Chambers_WaterQualityMonitorPlan_February2017Environmental Consultants  :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\ 3KDVHV  6XEPLWWHGWR  6ROLG:DVWH6HFWLRQ :-RQHV6WUHHW 5DOHLJK1&     3UHVHQWHGWR 'R]HU'ULYH 3RONWRQ1RUWK&DUROLQD   3UHVHQWHGE\  6&6(1*,1((563& &KDSDQRNH5RDG 5DOHLJK1&    -XO\ )LOH1R   2IILFHV1DWLRQZLGH ZZZVFVHQJLQHHUVFRP Environmental Consultants 322 Chapanoke Road 919 662-3015 and Contractors Suite 101 FAX 919 662-3017 Raleigh, NC 27603-3415 www.scsengineers.com   July 2, 2015 File No. 02214709.00 Mr. Ed Mussler, P.E., Permitting Branch Head NC DENR Division of Waste Management Solid Waste Section 217 W Jones Street Raleigh, NC 27603 Subject: Water Quality Monitoring Plan Update, Anson Waste Management Facility Phases 1 - 4, (a.k.a. Chambers Development) Polkville (Anson County), North Carolina NC DENR Solid Waste Permit #04-03 Dear Mr. Mussler: On behalf of Waste Connections, Inc. of North Carolina, we are pleased to present this update of the Water Quality Monitoring Plan for the referenced facility in support of a Permit to Construct application for Phases 3 and 4. The original Water Quality Monitoring Plan was prepared ca. 1999 by TRC Environmental for Phase 1, modified in 2008 by David Garrett & Associates for Phase 2. Over the course of time, ground water monitoring points (both wells and surface water locations) have been amended as the facility was developed, in addition to standardization of monitoring protocols by the Solid Waste Section (“Section”) ca. 2008. The 2008 Update included the sampling plan presented in the document “Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling” (Attachment 1), available on the Solid Waste Section web site. The following document reflects subsequent changes to detection-stage monitoring approved by the Section in 2012, discussed in the most recent semi-annual monitoring report prepared by Jett Environmental Consulting, whereas only the shallow wells are sampled and water levels only are recorded for the deep wells on a semi- annual basis. In addition, semi-annual leachate sampling is performed at this facility. Please contact us if you have any questions or comments. Sincerely, G. David Garrett, PE, PG Steven C. Lamb, PE Project Manager Vice President 6&6(1*,1((563&  6&6(1*,1((563&  cc Mr. Nelson Breeden, PE – Regional Engineer, Waste Connection of North Carolina, Inc. Mr. Perry Sugg, PG – NCDENR Division of Waste Management, Solid Waste Section Mr. Steve Jett, PG – Jett Environmental Consulting Enclosures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²IURP1&'(15'LYLVLRQRI:DVWH0DQDJHPHQW  :HOOFRQVWUXFWLRQVFKHPDWLFV  1HZ*XLGHOLQHVIRUWKH6XEPLWWDORI(QYLURQPHQWDO0RQLWRULQJ'DWD2FWREHU  (QYLURQPHQWDO0RQLWRULQJ'DWD)RUP  $GGHQGXPWRWKH2FWREHU1RUWK&DUROLQD6ROLG:DVWH6HFWLRQ0HPRUDQGXP )HEUXDU\  (QYLURQPHQWDO0RQLWRULQJ'DWDIRU1RUWK&DUROLQD6ROLG:DVWH)DFLOLWLHV2FWREHU  *URXQGZDWHU 6XUIDFH :DWHU6RLO 6HGLPHQW DQG /DQGILOO *DV (OHFWURQLF 'RFXPHQW 6XEPLWWDO1RYHPEHU  :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\     &855(17021,725,1*3/$129(59,(: The original Water Quality Monitoring Plan included paired wells (S for “shallow”, D for “deep”), which was intended to monitor the saprolite overburden and the fractured bedrock aquifers, respectively. North Carolina Solid Waste Rule 15A NCAC 13B .1631 requires detection monitoring of the “uppermost” aquifer, which in this case there is a sufficient thickness of saturated overburden outside the waste footprint to serve as the uppermost aquifer. In 2012 it was recognized that monitoring the bedrock aquifer was redundant, so the Solid Waste Section authorized a modification for sampling only the shallow wells. During semi-annual sampling events, water levels are measured in the deep wells. Historically, well installations have been incremental, as the footprint has grown. In the 2008 WQMP Update, plans were approved to install wells MW-9 and MW-10S/D on the northeast side of Phase 2. MW-9 was installed ca. 2011 as a shallow well, but MW-10 has not, nor has a temporary well pair on the north side of Phase 2, MW-11, within the footprint of future Phase 4. Whereas the final portions of Phase 2 are under construction, it is time (as of this plan revision) to install MW-10S and provide the required four independent sampling events prior to activating Cells 2C and 2D. MW-11 has been relocated as shown on the monitoring plan drawing. All monitoring wells have been (and will continue to be) installed in accordance with 15A NCAC 2C. Generally, the wells are fitted with dedicated sampling pumps except MW-9. A summary of the well construction data, along with anticipated conditions for future wells, is presented on Table 1. Well construction records are provided in Attachment 2. Surface water sampling is conducted upstream and downstream on both of the boundary streams, plus the outlet of an underdrain installed in Cells 2A and 2B. Appendix I analyses are performed during each sampling event for the metals and organic constituents shown on Table 2. Sampling is performed in the spring and autumn seasons. A third-party consultant performs statistical analyses on the data and makes formal submittals to the Solid Waste Section on behalf of the facility. The semi-annual reports include the laboratory data, statistical analyses, and ground water potentiometric surface maps prepared for each sampling event. The data have shown a handful of Appendix I constituents above the SWSLs in the wells, including inorganic constituents that have been identified as background constituents in the Phases 3 and 4 Design Hydrogeologic Report. No organic constituents have been detected in the ground water samples. Erratic detection of organic constituents has been observed in the surface samples, believed to be laboratory contaminants. No conclusions are drawn in this document regarding any monitoring results; no known regulatory action is presently under contemplation. The Site Suitability Study and Design Hydrogeologic studies show ground water flow within the facility boundary is radial but generally northward. The entire site is within the Yadkin-Pee Dee watershed and not subject to riparian buffers. Onsite ground water discharge occurs in numerous unnamed tributaries. No downgradient ground water users are present, and the site is isolated from the surrounding areas by large converging streams at the facility boundary that serve as ground water divides. This document amends the Appendix I sampling locations but does not modify the schedule or any monitoring protocols. :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\     5$7,21$/()25021,725,1*/2&$7,216 Two upgradient wells serve as background, MW-2S (shallow) and MW-2D (deep), located along the southern side Phase 1. Down-gradient compliance wells are located in pairs, generally to the northeast of Phases 1 and 2 at a horizontal spacing appropriate to the subsurface conditions, plus one pair to the southwest. These wells were located based on earlier studies and tend to focus on the former drainage features. The well couplets (or pairs) monitor the upper saprolite aquifer (Units 1 and 2 described in Phases 3 and 4 Design Hydrogeologic Report) and the upper bedrock aquifer (Unit 3). Four wells, MW-6S/D and MW-7S/D, formerly located within the Phase 2 footprint, were abandoned. Figures M1 and M2 depict the monitoring locations. New monitoring wells are proposed to the north and west of Phases 3 and 4, focusing again on the drainage features that align with the regional joint pattern visible in the topography. The potentiometric map found in the Design Hydrogeologic Report depicts a groundwater divide aligned with the original ridgeline, with the saturated layer residing near the base of the saprolite overburden (Units 1and 2). Well spacing on the north and west sides appears closer than on the east side because surface drainage features originally converged to the east but not the other directions. The presence of diabase dikes and a major geologic contact have not been shown to affect the monitoring program. In keeping with recent modifications to the groundwater monitoring program, only shallow wells extending to “auger refusal” are proposed at this time. Background Well Bottom Depth • MW-2S and MW-2D 31.0’ and 38.0’ respectively Phase 1 Compliance Wells • MW-1D 45.5’ • MW-3S and MW-3D 20.0’ and 40.0’ • MW-4S and MW-4D 30.0’ and 60.5’ • MW-5S and MW-5D 30.0’ and 49.0’ • MW-8S and MW-8D 35.0’ and 49.0’ Phase 2 Compliance Wells • MW-9S 27.5’ • MW-10S 50’ anticipated based on Piez PH-29A* Phase 3 Compliance Wells Anticipated Depth** • MW-11S 50’ based on PH-29A • MW-12S 30’ based on Old MW20-OB • MW-13S 30’ based on Old MW20-OB • MW-14S 45’ based on Old MW17A-BZE • MW-15S 25’ based on Old MW17A-BZW Phase 4 Compliance Wells Anticipated Depth** • MW-16S 25’ based on Piez B-15 • MW-17S 20’ based on Piez B-10Dp • MW-18S 20’ based on Piez B-9Dp • MW-19S 40’ based on Piez B-2Dp • MW-20S 35’ based on Piez B-3p * Scheduled for installation in 2017 concurrent with Phase 2D construction ** Depths may vary – do not use these depths for absolute budgeting :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\    Provisions have been incorporated into current sampling protocols that require sampling of deep wells in the event there is insufficient water in the shallow wells. This practice will be continued at the Phase 3 and 4 wells. By selecting locations near the drainage features, new wells are expected to provide early detection of a release of contaminants onto the uppermost aquifer. Based on the distance to the facility boundary, a point of compliance exists closer to the footprint than the facility boundary, at distance of approximately 250 to 300 feet, so the review boundary for well locations is 125 to 150 feet, allowing leeway to accommodate the topography. Well screen intervals will be selected in the field based on existing conditions. Well installations will be performed under the direction of a qualified geologist. Future amendments may be required to ensure the wells provide representative monitoring results.  685)$&(6$03/,1* Surface water sampling locations are as follows: Upstream • Pinch Gut Creek Upstream (BG-1) • Brown Creek Upstream (BG-2) Downstream • Brown Creek Downstream (SG-3) • Pinch Gut Creek Downstream (SG-4) Underdrains installed beneath certain cells have designated sampling points as follows: UD-1 • Cell 2B East Formerly SG-5discharges to a sediment basin nearest MW-9 UD-2 • Cell 2C South includes Cell 2B West discharges to a swale leading to the sediment basin nearest MW-10 UD-3 • Cell 2C North discharges to the sediment basin nearest MW-10, downstream of UD-2 Please take note of the following conditions: 1. Samples will be acquired from within the pipe to avoid cross contamination with surface water. 2. The drains are expected to stop flowing within a few months after installation; Note 5 on Drawing M-1 specifies observation to detect flow (with record keeping) on a monthly basis. 3. An internal inspection (e.g. camera survey) is required for UD-3 (see Note 5E on Drawing M1). :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\    /($&+$7(6$03/,1* Provisions were made in the original Water Quality Monitoring Plan for monitoring of the leachate from a sampling port in the force main connecting the individual sumps with the leachate collection/storage tanks and/or another location in the tanks. No amendment to the leachate sampling plan is under consideration, except for the future sampling of new sumps associated with the future phases.  (1+$1&('/,1(56<67(0 The October 2008 Water Quality Monitoring Plan prepared by David Garrett and Associates includes an evaluation is to be made semi-annually of the volume of free liquid removed from the Enhanced Liner System (ELS) sump. This feature is a leak detection layer incorporated into Phase 1 but not subsequent cells. The results of the evaluation and the VOC analysis of the ELS sump liquids are to be included in the semi-annual groundwater report. As reported in the Second Semi-Annual 2014 sampling report, liquids were present at ELS sumps #5 and #7 during the last six month monitoring period, thus a sample was collected during the Second Semi- Annual 2014 event and analyzed for the required VOCs. Results indicate that the ELS sump samples were reported as non-detect for VOCs. Some metals were present. The total volume of liquids measured in ELS sumps #5 and #7 was 522 gallons and 106,143 gallons, respectively.  352326('3/$1$0(1'0(176 New monitoring wells for Phase 3 shall be located to the west and southwest of the phase, along drainage features that align with regional bedrock joints (minor fracture zones), which serve as potential ground water pathways. Future monitoring wells for Phase 4 will be located per similar criteria at an appropriate time. Planned monitoring well MW-10S and a new surface monitoring location (SG-6) will be activated prior to operation of Phase 2C, under construction in 2015. Based on the data and the governing rules, no changes to the sampling parameters or statistical evaluations appear to be required at this time. Sampling and analysis criteria will remain unchanged. Wells will be evacuated and samples will be obtained using conventional techniques (in accordance with SWS Guidelines), but future consideration may be given to adopting low-flow techniques and/or the use of dedicated pumps in all wells, including the future wells for Phases 3 and 4. The Guidelines cover the use of dedicated pumps (but not the low-flow techniques). Any changes involving purging and sampling techniques should be reviewed by a qualified groundwater scientist and reflected in a future plan update. Future updates also will be warranted as new cells are completed and wells are installed. Likewise, any new surface sampling locations that may be required for future underdrains should be documented with a plan update. The prior-approved Water Quality Monitoring Plan appears to be sufficient for ongoing monitoring of the facility, requiring only an adjustment of the monitoring wells to accommodate Phases 3 and 4. The sampling protocols outlined in the Solid Waste Section “Guidelines” (Attachment 1) shall be followed. Specific protocols for sampling ground water wells are provided in Appendix C of that document, with a section pertaining to the use of dedicated :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\    pumps. The required sampling procedures retain the determination of initial water levels and volumes that must be purged. If low-flow purging and sampling procedures are adopted, product-specific protocols described in the manufacturer’s literature should be reviewed and incorporated into this plan. Other documents issued by the NCDENR Solid Waste Section, which are incorporated into this plan, including: • October 2006 New Guidelines for the Submittal of Environmental Monitoring Data (Attachment 3), which introduced the requirement for the Environmental Monitoring Data Form (Attachment 4), and • February 2007 Addendum to the October 27, 2006 North Carolina Solid Waste Section Memorandum (Attachment 5), i.e., the, which required the use of “Solid Waste Section Limit” (SWSL) in lieu of Practical Quantification Limits (PQL) for reporting the data, referencing changes to the North Carolina 2L Ground Water Protection Standards, and encouraging electronic data submittal – analytical data is required in a .xls file, and • October 2007 Environmental Monitoring Data for North Carolina Solid Waste • Facilities (Attachment 6), which provided clarification on certain issues. • November 2014 memo titled Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal (Attachment 7). These documents can be viewed at http://www.wastenotnc.org/swhome/enviro_monitoring.asp. No changes are proposed to the current leachate monitoring program or sampling for the Enhanced Liner System. Future changes to leachate sampling, if any, will be documented in another plan revision. Upon approval by NC DENR Division of Waste Management, Solid Waste Section, these amendments to this plan will be implemented at an appropriate time (relative to the construction sequence) and sampling will be conducted accordingly. Solid Waste Section protocols typically require four independent background samples from new wells prior to opening a new phase (i.e., issuance of the Permit to Operate). :DWHU4XDOLW\0RQLWRULQJ3ODQ8SGDWH $QVRQ:DVWH0DQDJHPHQW)DFLOLW\     &(57,),&$7,21 This water quality monitoring plan has been prepared by a qualified geologist who is licensed to practice in the State of North Carolina. The plan is based on first-hand knowledge of site conditions and familiarity with North Carolina solid waste rules and industry standard protocol. This certification is made in accordance with North Carolina Solid Waste Regulations, indicating that this Water Quality Monitoring Plan should provide early detection of any release of hazardous constituents into the uppermost aquifer, so as to be protective of public health and the environment. No other warranties, expressed or implied, are made. Signed Printed Name G. David Garrett Date July 2, 2015  5(9,6,216 References to earlier plan versions include: 1. Water Quality Monitoring Plan, Phase 1, 1999 2. Sampling and Analysis Plan Update, Phase 2, October 2008 (Rev. 1) 3. Water Quality Monitoring Plan Update, September 28, 2012 (Rev. 2)   8 A B 34567 12 C D E F G H 8 34567 12 A B C D E F G H CO M P O S I T E U N D E R D R A I N P L A N 14 2 - 9 6 2 1"= 1 0 0 ' MA R C H 2 0 1 6 C T H NT B SL B 11 AN S O N W A S T E M A N A G E M E N T F A C I L I T Y CE L L 2 C E X P A N S I O N CO N S T R U C T I O N D R A W I N G S NORTH Table 2 Groundwater, Underdrain Flow, and Surface Water Analysis Methodology Inorganic Required Solid Waste North Carolina 2L** Constituent Section Limit (ug/l)*Ground Water Standard Antimony 6 1.4 *** Arsenic 10 50 Barium 100 2000 Beryllium 1 4 *** Cadmium 1 1.75 Chromium 10 50 Cobalt 10 70 *** Copper 10 1000 Lead 10 15 Nickel 50 100 Selenium 10 50 Silver 10 17.5 Thallium 5.5 0.28 *** Vanadium 25 3.5 *** Zinc 10 1050 Mercury 0.2 1.05 Chloride NE 250,000 Manganese 50 50 Sulfate 250,000 250,000 Iron 300 300 Alkalinity NE NE Total Dissolved Solids NE 500,000 Specific Conductivity (field) pH (field) Temperature (field) Table 2 (continued) Sample Analysis Methodology Organic Required Solid Waste North Carolina Constituent Section Limit (ug/l)*Ground Water Standard 1,1,1,2-Tetrachloroethane 5 1.3 *** 1,1,1-Trichloroethane 1 200 1,1,2,2-Tetrachloroethane 3 0.18 *** 1,1,2-Trichloroethane 1 0.6 *** 1,1-Dichloroethane 5 70 1,1-Dichloroethylene 5 7 1,2,3-Trichloropropane 1 0.005 1,2-Dibromo-3-chloropropane 13 0.025 1,2-Dibromoethane 1 0.0004 1,2-Dichlorobenzene 5 24 1,2-Dichloroethane 1 0.38 1,2-Dichloropropane 1 0.51 1,4-Dichlorobenzene 1 1.4 2-Butanone 100 4200 2-Hexanone 50 280 4-Methyl-2-pentanone 100 560 *** Acetone 100 700 Acrylonitrile 200 NE Benzene 1 1 Bromochloromethane 3 0.6 *** Bromodichloromethane 1 0.56 Bromoform 4 4.43 Bromomethane 10 NE Carbon Disulfide 100 700 Carbon Tetrachloride 1 0.269 Chlorobenzene 3 50 Chloroethane 10 2800 Chloroform 5 70 Chloromethane 1 2.6 Cis-1,2-dichloroethylene 5 70 Cis-1,3-dichloropropene 1 0.19 Dibromochloromethane 3 0.41 Dibromomethane 10 NE Ethylbenzene 1 550 Iodomethane 10 NE Methylene chloride 1 4.6 Styrene 1 100 Tetrachloroethylene 1 0.7 Toluene 1 1000 Trans-1,2-dichloroethylene 5 100 Table 2 (continued) Sample Analysis Methodology Organic Required Solid Waste North Carolina Constituent Section Limit (ug/l)*Ground Water Standard Trans-1,3-dichloropropene 1 0.19 Trans-1,4-dichloro-2-butene 100 NE Trichloroethylene 1 2.8 Trichloroflouromethane 1 2100 Vinyl acetate 50 7000 *** Vinyl chloride 1 0.015 Xylene (total) 5 530 Notes: All samples shall be unfiltered. NE = not established * Per North Carolina DENR Division of Waste Management guidelines, eff. 2006, equivalent to the PQL. Only SW-846 methodologies that are approved by the NC DENR Solid Waste Section shall be used for laboratory analyses. The laboratory must be certified by NC DENR for the specific lab methods per SW- 846. ** 15A NCAC 2L Standard for Class GA Ground Water – this applies unless otherwise noted (see below) ***North Carolina DWM Ground Water Protection Standard (quoted from website) Groundwater standards and Solid Waste Section Limits are subject to change; the most current standards and limits will be used. Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT SOLID WASTE SECTION General Sampling Procedures The following guidance is provided to insure a consistent sampling approach so that sample collection activities at solid waste management facilities provide reliable data. Sampling must begin with an evaluation of facility information, historical environmental data and site geologic and hydrogeologic conditions. General sampling procedures are described in this document. Planning Begin sampling activities with planning and coordination. The party contracting with the laboratory is responsible for effectively communicating reporting requirements and evaluating data reliability as it relates to specific monitoring activities. Sample Collection Contamination Prevention a.) Take special effort to prevent cross contamination or environmental contamination when collecting samples. 1. If possible, collect samples from the least contaminated sampling location (or background sampling location, if applicable) to the most contaminated sampling location. 2. Collect the ambient or background samples first, and store them in separate ice chests or separate shipping containers within the same ice chest (e.g. untreated plastic bags). 3. Collect samples in flowing water at designated locations from upstream to downstream. b.) Do not store or ship highly contaminated samples (concentrated wastes, free product, etc.) or samples suspect of containing high concentrations of contaminants in the same ice chest or shipping containers with other environmental samples. 1. Isolate these sample containers by sealing them in separate, untreated plastic bags immediately after collecting, preserving, labeling, etc. 2. Use a clean, untreated plastic bag to line the ice chest or shipping container. c.) All sampling equipment should be thoroughly decontaminated and transported in a manner that does not allow it to become contaminated. Arrangements should be made ahead of time to decontaminate any sampling or measuring equipment that will be reused when taking samples from more than one well. Field decontamination of Rev 4-08 1 sampling equipment will be necessary before sampling each well to minimize the risk of cross contamination. Decontamination procedures should be included in reports as necessary. Certified pre-cleaned sampling equipment and containers may be used. When collecting aqueous samples, rinse the sample collection equipment with a portion of the sample water before taking the actual sample. Sample containers do not need to be rinsed. In the case of petroleum hydrocarbons, oil and grease, or containers with pre-measured preservatives, the sample containers cannot be rinsed. d.) Place all fuel-powered equipment away from, and downwind of, any site activities (e.g., purging, sampling, decontamination). 1. If field conditions preclude such placement (i.e., the wind is from the upstream direction in a boat), place the fuel source(s) as far away as possible from the sampling activities and describe the conditions in the field notes. 2. Handle fuel (i.e., filling vehicles and equipment) prior to the sampling day. If such activities must be performed during sampling, the personnel must wear disposable gloves. 3. Dispense all fuels downwind. Dispose of gloves well away from the sampling activities. Filling Out Sample Labels Fill out label, adhere to vial and collect sample. Print legibly with indelible ink. At a minimum, the label or tag should identify the sample with the following information: 1. Sample location and/or well number 2. Sample identification number 3. Date and time of collection 4. Analysis required/requested 5. Sampler’s initials 6. Preservative(s) used, if any [i.e., HCl, Na2S2O3, NO3, ice, etc.] 7. Any other pertinent information for sample identification Sample Collection Order Unless field conditions justify other sampling regimens, collect samples in the following order: 1. Volatile Organics and Volatile Inorganics 2. Extractable Organics, Petroleum Hydrocarbons, Aggregate Organics and Oil and Grease 3. Total Metals 4. Inorganic Nonmetallics, Physical and Aggregate Properties, and Biologicals 5. Microbiological NOTE: If the pump used to collect groundwater samples cannot be used to collect volatile or extractable organics then collect all other parameters and withdraw the pump and tubing. Then collect the volatile and extractable organics. Rev 4-08 2 Health and Safety Implement all local, state, and federal requirements relating to health and safety. Follow all local, state and federal requirements pertaining to the storage and disposal of any hazardous or investigation derived wastes. a.) The Solid Waste Section recommends wearing protective gloves when conducting all sampling activities. 1. Gloves serve to protect the sample collector from potential exposure to sample constituents, minimize accidental contamination of samples by the collector, and preserve accurate tare weights on preweighed sample containers. 2. Do not let gloves come into contact with the sample or with the interior or lip of the sample container. Use clean, new, unpowdered and disposable gloves. Various types of gloves may be used as long as the construction materials do not contaminate the sample or if internal safety protocols require greater protection. 3. Note that certain materials that may potentially be present in concentrated effluent can pass through certain glove types and be absorbed in the skin. Many vendor catalogs provide information about the permeability of different gloves and the circumstances under which the glove material might be applicable. The powder in powdered gloves can contribute significant contamination. Powdered gloves are not recommended unless it can be demonstrated that the powder does not interfere with the sample analysis. 4. Change gloves after preliminary activities, after collecting all the samples at a single sampling point, if torn or used to handle extremely dirty or highly contaminated surfaces. Properly dispose of all used gloves as investigation derived wastes. b.) Properly manage all investigation derived waste (IDW). 5. To prevent contamination into previously uncontaminated areas, properly manage all IDW. This includes all water, soil, drilling mud, decontamination wastes, discarded personal protective equipment (PPE), etc. from site investigations, exploratory borings, piezometer and monitoring well installation, refurbishment, abandonment, and other investigative activities. Manage all IDW that is determined to be RCRA-regulated hazardous waste according to the local, state and federal requirements. 6. Properly dispose of IDW that is not a RCRA-regulated hazardous waste but is contaminated above the Department’s Soil Cleanup Target Levels or the state standards and/or minimum criteria for ground water quality. If the drill cuttings/mud orpurged well water is contaminated with hazardous waste, contact the DWM Hazardous Waste Section (919-508-8400) for disposal options. Maintain all containers holding IDW in good condition. Periodically inspect the containers for damage and ensure that all required labeling (DOT, RCRA, etc.) are clearly visible. Rev 4-08 3 Sample Storage and Transport Store samples for transport carefully. Pack samples to prevent from breaking and to maintain a temperature of approximately 4 degrees Celsius (°C), adding ice if necessary. Transport samples to a North Carolina-certified laboratory as soon as possible. Avoid unnecessary handling of sample containers. Avoid heating (room temperature or above, including exposure to sunlight) or freezing of the sample containers. Reduce the time between sample collection and delivery to a laboratory whenever possible and be sure that the analytical holding times of your samples can be met by the laboratory. a.) A complete chain-of-custody (COC) form must be maintained to document all transfers and receipts of the samples. Be sure that the sample containers are labeled with the sample location and/or well number, sample identification, the date and time of collection, the analysis to be performed, the preservative added (if any), the sampler’s initials, and any other pertinent information for sample identification. The labels should contain a unique identifier (i.e., unique well numbers) that can be traced to the COC form. The details of sample collection must be documented on the COC. The COC must include the following: 1. Description of each sample (including QA/QC samples) and the number of containers (sample location and identification) 2. Signature of the sampler 3. Date and time of sample collection 4. Analytical method to be performed 5. Sample type (i.e., water or soil) 6. Regulatory agency (i.e., NCDENR/DWM – SW Section) 7. Signatures of all persons relinquishing and receiving custody of the samples 8. Dates and times of custody transfers b.) Pack samples so that they are segregated by site, sampling location or by sample analysis type. When COC samples are involved, segregate samples in coolers by site. If samples from multiple sites will fit in one cooler, they may be packed in the same cooler with the associated field sheets and a single COC form for all. Coolers should not exceed a maximum weight of 50 lbs. Use additional coolers as necessary. All sample containers should be placed in plastic bags (segregated by analysis and location) and completely surrounded by ice. 1. Prepare and place trip blanks in an ice filled cooler before leaving for the field. 2. Segregate samples by analysis and place in sealable plastic bags. 3. Pack samples carefully in the cooler placing ice around the samples. 4. Review the COC. The COC form must accompany the samples to the laboratory. The trip blank(s) must also be recorded on the COC form. 5. Place completed COC form in a waterproof bag, sealed and taped under the lid of the cooler. 6. Secure shipping containers with strapping tape to avoid accidental opening. 7. For COC samples, a tamper-proof seal may also be placed over the cooler lid or over a bag or container containing the samples inside the shipping cooler. Rev 4-08 4 8. "COC" or "EMERG" should be written in indelible ink on the cooler seal to alert sample receipt technicians to priority or special handling samples. 9. The date and sample handler's signature must also be written on the COC seal. 10. Deliver the samples to the laboratory or ship by commercial courier. NOTE: If transport time to the laboratory is not long enough to allow samples to be cooled to 4° C, a temperature reading of the sample source must be documented as the field temperature on the COC form. A downward trend in temperature will be adequate even if cooling to 4° C is not achieved. The field temperature should always be documented if there is any question as to whether samples will have time to cool to 4° C during shipment. Thermometers must be calibrated annually against an NIST traceable thermometer and documentation must be retained. Rev 4-08 5 Appendix A - Decontamination of Field Equipment Decontamination of personnel, sampling equipment, and containers - before and after sampling - must be used to ensure collection of representative samples and to prevent the potential spread of contamination. Decontamination of personnel prevents ingestion and absorption of contaminants. It must be done with a soap and water wash and deionized or distilled water rinse. Certified pre-cleaned sampling equipment and containers may also be used. All previously used sampling equipment must be properly decontaminated before sampling and between sampling locations. This prevents the introduction of contamination into uncontaminated samples and avoids cross-contamination of samples. Cross-contamination can be a significant problem when attempting to characterize extremely low concentrations of organic compounds or when working with soils that are highly contaminated. Clean, solvent-resistant gloves and appropriate protective equipment must be worn by persons decontaminating tools and equipment. Cleaning Reagents Recommendations for the types and grades of various cleaning supplies are outlined below. The recommended reagent types or grades were selected to ensure that the cleaned equipment is free from any detectable contamination. a.) Detergents: Use Liqui-Nox (or a non-phosphate equivalent) or Alconox (or equivalent). Liqui-Nox (or equivalent) is recommended by EPA, although Alconox (or equivalent) may be substituted if the sampling equipment will not be used to collect phosphorus or phosphorus containing compounds. b.) Solvents: Use pesticide grade isopropanol as the rinse solvent in routine equipment cleaning procedures. This grade of alcohol must be purchased from a laboratory supply vendor. Rubbing alcohol or other commonly available sources of isopropanol are not acceptable. Other solvents, such as acetone or methanol, may be used as the final rinse solvent if they are pesticide grade. However, methanol is more toxic to the environment and acetone may be an analyte of interest for volatile organics. 1. Do not use acetone if volatile organics are of interest 2. Containerize all methanol wastes (including rinses) and dispose as a hazardous waste. Pre-clean equipment that is heavily contaminated with organic analytes. Use reagent grade acetone and hexane or other suitable solvents. Use pesticide grade methylene chloride when cleaning sample containers. Store all solvents away from potential sources of contamination. c.) Analyte-Free Water Sources: Analyte-free water is water in which all analytes of interest and all interferences are below method detection limits. Maintain documentation (such as results from equipment blanks) to demonstrate the reliability and purity of analyte-free water source(s). The source of the water must meet the requirements of the analytical method and must be free from the analytes of interest. In general, the following water types are associated with specific analyte groups: 1. Milli-Q (or equivalent polished water): suitable for all analyses. Rev 4-08 6 2. Organic-free: suitable for volatile and extractable organics. 3. Deionized water: may not be suitable for volatile and extractable organics. 4. Distilled water: not suitable for volatile and extractable organics, metals or ultratrace metals. Use analyte-free water for blank preparation and the final decontamination water rinse. In order to minimize long-term storage and potential leaching problems, obtain or purchase analyte-free water just prior to the sampling event. If obtained from a source (such as a laboratory), fill the transport containers and use the contents for a single sampling event. Empty the transport container(s) at the end of the sampling event. Discard any analyte-free water that is transferred to a dispensing container (such as a wash bottle or pump sprayer) at the end of each sampling day. d.) Acids: 1. Reagent Grade Nitric Acid: 10 - 15% (one volume concentrated nitric acid and five volumes deionized water). Use for the acid rinse unless nitrogen components (e.g., nitrate, nitrite, etc.) are to be sampled. If sampling for ultra-trace levels of metals, use an ultra-pure grade acid. 2. Reagent Grade Hydrochloric Acid: 10% hydrochloric acid (one volume concentrated hydrochloric and three volumes deionized water). Use when nitrogen components are to be sampled. 3. If samples for both metals and the nitrogen-containing components are collected with the equipment, use the hydrochloric acid rinse, or thoroughly rinse with hydrochloric acid after a nitric acid rinse. If sampling for ultra trace levels of metals, use an ultra-pure grade acid. 4. Freshly prepared acid solutions may be recycled during the sampling event or cleaning process. Dispose of any unused acids according to local ordinances. Reagent Storage Containers The contents of all containers must be clearly marked. a.) Detergents: 1. Store in the original container or in a HDPE or PP container. b.) Solvents: 1. Store solvents to be used for cleaning or decontamination in the original container until use in the field. If transferred to another container for field use, use either a glass or Teflon container. 2. Use dispensing containers constructed of glass, Teflon or stainless steel. Note: If stainless steel sprayers are used, any gaskets that contact the solvents must be constructed of inert materials. c.) Analyte-Free Water: 1. Transport in containers appropriate for the type of water stored. If the water is commercially purchased (e.g., grocery store), use the original containers when transporting the water to the field. Containers made of glass, Teflon, polypropylene or HDPE are acceptable. 2. Use glass or Teflon to transport organic-free sources of water on-site. Polypropylene or HDPE may be used, but are not recommended. Rev 4-08 7 3. Dispense water from containers made of glass, Teflon, HDPE or polypropylene. 4. Do not store water in transport containers for more than three days before beginning a sampling event. 5. If working on a project that has oversight from EPA Region 4, use glass containers for the transport and storage of all water. 6. Store and dispense acids using containers made of glass, Teflon or plastic. General Requirements a.) Prior to use, clean/decontaminate all sampling equipment (pumps, tubing, lanyards, split spoons, etc.) that will be exposed to the sample. b.) Before installing, clean (or obtain as certified pre-cleaned) all equipment that is dedicated to a single sampling point and remains in contact with the sample medium (e.g., permanently installed groundwater pump). If you use certified pre-cleaned equipment no cleaning is necessary. 1. Clean this equipment any time it is removed for maintenance or repair. 2. Replace dedicated tubing if discolored or damaged. c.) Clean all equipment in a designated area having a controlled environment (house, laboratory, or base of field operations) and transport it to the field, pre-cleaned and ready to use, unless otherwise justified. d.) Rinse all equipment with water after use, even if it is to be field-cleaned for other sites. Rinse equipment used at contaminated sites or used to collect in-process (e.g., untreated or partially treated wastewater) samples immediately with water. e.) Whenever possible, transport sufficient clean equipment to the field so that an entire sampling event can be conducted without the need for cleaning equipment in the field. f.) Segregate equipment that is only used once (i.e., not cleaned in the field) from clean equipment and return to the in-house cleaning facility to be cleaned in a controlled environment. g.) Protect decontaminated field equipment from environmental contamination by securely wrapping and sealing with one of the following: 1. Aluminum foil (commercial grade is acceptable) 2. Untreated butcher paper 3. Clean, untreated, disposable plastic bags. Plastic bags may be used for all analyte groups except volatile and extractable organics. Plastic bags may be used for volatile and extractable organics, if the equipment is first wrapped in foil or butcher paper, or if the equipment is completely dry. Cleaning Sample Collection Equipment a.) On-Site/In-Field Cleaning – Cleaning equipment on-site is not recommended because environmental conditions cannot be controlled and wastes (solvents and acids) must be containerized for proper disposal. 1. Ambient temperature water may be substituted in the hot, sudsy water bath and hot water rinses. NOTE: Properly dispose of all solvents and acids. Rev 4-08 8 2. Rinse all equipment with water after use, even if it is to be field-cleaned for other sites. 3. Immediately rinse equipment used at contaminated sites or used to collect in-process (e.g., untreated or partially treated wastewater) samples with water. b.) Heavily Contaminated Equipment - In order to avoid contaminating other samples, isolate heavily contaminated equipment from other equipment and thoroughly decontaminate the equipment before further use. Equipment is considered heavily contaminated if it: 1. Has been used to collect samples from a source known to contain significantly higher levels than background. 2. Has been used to collect free product. 3. Has been used to collect industrial products (e.g., pesticides or solvents) or their byproducts. NOTE: Cleaning heavily contaminated equipment in the field is not recommended. c.) On-Site Procedures: 1. Protect all other equipment, personnel and samples from exposure by isolating the equipment immediately after use. 2. At a minimum, place the equipment in a tightly sealed, untreated, plastic bag. 3. Do not store or ship the contaminated equipment next to clean, decontaminated equipment, unused sample containers, or filled sample containers. 4. Transport the equipment back to the base of operations for thorough decontamination. 5. If cleaning must occur in the field, document the effectiveness of the procedure, collect and analyze blanks on the cleaned equipment. d.) Cleaning Procedures: 1. If organic contamination cannot be readily removed with scrubbing and a detergent solution, pre-rinse equipment by thoroughly rinsing or soaking the equipment in acetone. 2. Use hexane only if preceded and followed by acetone. 3. In extreme cases, it may be necessary to steam clean the field equipment before proceeding with routine cleaning procedures. 4. After the solvent rinses (and/or steam cleaning), use the appropriate cleaning procedure. Scrub, rather than soak, all equipment with sudsy water. If high levels of metals are suspected and the equipment cannot be cleaned without acid rinsing, soak the equipment in the appropriate acid. Since stainless steel equipment should not be exposed to acid rinses, do not use stainless steel equipment when heavy metal contamination is suspected or present. 5. If the field equipment cannot be cleaned utilizing these procedures, discard unless further cleaning with stronger solvents and/or oxidizing solutions is effective as evidenced by visual observation and blanks. 6. Clearly mark or disable all discarded equipment to discourage use. Rev 4-08 9 e.) General Cleaning - Follow these procedures when cleaning equipment under controlled conditions. Check manufacturer's instructions for cleaning restrictions and/or recommendations. 1. Procedure for Teflon, stainless steel and glass sampling equipment: This procedure must be used when sampling for ALL analyte groups. (Extractable organics, metals, nutrients, etc. or if a single decontamination protocol is desired to clean all Teflon, stainless steel and glass equipment.) Rinse equipment with hot tap water. Soak equipment in a hot, sudsy water solution (Liqui-Nox or equivalent). If necessary, use a brush to remove particulate matter or surface film. Rinse thoroughly with hot tap water. If samples for trace metals or inorganic analytes will be collected with the equipment that is not stainless steel, thoroughly rinse (wet all surfaces) with the appropriate acid solution. Rinse thoroughly with analyte-free water. Make sure that all equipment surfaces are thoroughly flushed with water. If samples for volatile or extractable organics will be collected, rinse with isopropanol. Wet equipment surfaces thoroughly with free- flowing solvent. Rinse thoroughly with analyte-free water. Allow to air dry. Wrap and seal as soon as the equipment has air-dried. If isopropanol is used, the equipment may be air-dried without the final analyte-free water rinse; however, the equipment must be completely dry before wrapping or use. Wrap clean sampling equipment according to the procedure described above. 2. General Cleaning Procedure for Plastic Sampling Equipment: Rinse equipment with hot tap water. Soak equipment in a hot, sudsy water solution (Liqui-Nox or equivalent). If necessary, use a brush to remove particulate matter or surface film. Rinse thoroughly with hot tap water. Thoroughly rinse (wet all surfaces) with the appropriate acid solution. Check manufacturer's instructions for cleaning restrictions and/or recommendations. Rinse thoroughly with analyte-free water. Be sure that all equipment surfaces are thoroughly flushed. Allow to air dry as long as possible. Wrap clean sampling equipment according to the procedure described above. Rev 4-08 10 Appendix B - Collecting Soil Samples Soil samples are collected for a variety of purposes. A methodical sampling approach must be used to assure that sample collection activities provide reliable data. Sampling must begin with an evaluation of background information, historical data and site conditions. Soil Field Screening Procedures Field screening is the use of portable devices capable of detecting petroleum contaminants on a real-time basis or by a rapid field analytical technique. Field screening should be used to help assess locations where contamination is most likely to be present. When possible, field-screening samples should be collected directly from the excavation or from the excavation equipment's bucket. If field screening is conducted only from the equipment's bucket, then a minimum of one field screening sample should be collected from each 10 cubic yards of excavated soil. If instruments or other observations indicate contamination, soil should be separated into stockpiles based on apparent degrees of contamination. At a minimum, soil suspected of contamination must be segregated from soil observed to be free of contamination. a.) Field screening devices – Many field screen instruments are available for detecting contaminants in the field on a rapid or real-time basis. Acceptable field screening instruments must be suitable for the contaminant being screened. The procdedure for field screening using photoionization detectors (PIDs) and flame ionization detectors (FIDs) is described below. If other instruments are used, a description of the instrument or method and its intended use must be provided to the Solid Waste Section. Whichever field screening method is chosen, its accuracy must be verified throughout the sampling process. Use appropriate standards that match the use intended for the data. Unless the Solid Waste Section indicates otherwise, wherever field screening is recommended in this document, instrumental or analytical methods of detection must be used, not olfactory or visual screening methods. b.) Headspace analytical screening procedure for filed screening (semi-quantitative field screening) - The most commonly used field instruments for Solid Waste Section site assessments are FIDs and PIDs. When using FIDs and PIDs, use the following headspace screening procedure to obtain and analyze field-screening samples: 1. Partially fill (one-third to one-half) a clean jar or clean ziplock bag with the sample to be analyzed. The total capacity of the jar or bag may not be less than eight ounces (app. 250 ml), but the container should not be so large as to allow vapor diffusion and stratification effects to significantly affect the sample. 2. If the sample is collected from a spilt-spoon, it must be transferred to the jar or bag for headspace analysis immediately after opening the split- spoon. If the sample is collected from an excavation or soil pile, it must be collected from freshly uncovered soil. Rev 4-08 11 3. If a jar is used, it must be quickly covered with clean aluminum foil or a jar lid; screw tops or thick rubber bands must be used to tightly seal the jar. If a zip lock bag is used, it must be quickly sealed shut. 4. Headspace vapors must be allowed to develop in the container for at least 10 minutes but no longer than one hour. Containers must be shaken or agitated for 15 seconds at the beginning and the end of the headspace development period to assist volatilization. Temperatures of the headspace must be warmed to at least 5° C (approximately 40° F) with instruments calibrated for the temperature used. 5. After headspace development, the instrument sampling probe must be inserted to a point about one-half the headspace depth. The container opening must be minimized and care must be taken to avoid the uptake of water droplets and soil particulates. 6. After probe insertion, the highest meter reading must be taken and recorded. This will normally occur between two and five seconds after probe insertion. If erratic meter response occurs at high organic vapor concentrations or conditions of elevated headspace moisture, a note to that effect must accompany the headspace data. 7. All field screening results must be documented in the field record or log book. Soil Sample Collection Procedures for Laboratory Samples The number and type of laboratory samples collected depends on the purpose of the sampling activity. Samples analyzed with field screening devices may not be substituted for required laboratory samples. a.) General Sample Collection - When collecting samples from potentially contaminated soil, care should be taken to reduce contact with skin or other parts of the body. Disposable gloves should be worn by the sample collector and should be changed between samples to avoid cross-contamination. Soil samples should be collected in a manner that causes the least disturbance to the internal structure of the sample and reduces its exposure to heat, sunlight and open air. Likewise, care should be taken to keep the samples from being contaminated by other materials or other samples collected at the site. When sampling is to occur over an extended period of time, it is necessary to insure that the samples are collected in a comparable manner. All samples must be collected with disposable or clean tools that have been decontaminated. Disposable gloves must be worn and changed between sample collections. Sample containers must be filled quickly. Soil samples must be placed in containers in the order of volatility, for example, volatile organic aromatic samples must be taken first, organics next, then heavier range organics, and finally soil classification samples. Containers must be quickly and adequately sealed, and rims must be cleaned before tightening lids. Tape may be used only if known not to affect sample analysis. Sample containers must be clearly labeled. Containers must immediately be preserved according to procedures in this Section. Unless specified Rev 4-08 12 otherwise, at a minimum, the samples must be immediately cooled to 4 ± 2°C and this temperature must be maintained throughout delivery to the laboratory. b.) Surface Soil Sampling - Surface soil is generally classified as soil between the ground surface and 6-12 inches below ground surface. Remove leaves, grass and surface debris from the area to be sampled. Select an appropriate, pre-cleaned sampling device and collect the sample. Transfer the sample to the appropriate sample container. Clean the outside of the sample container to remove excess soil. Label the sample container, place on wet ice to preserve at 4°C, and complete the field notes. c.) Subsurface Soil Sampling – The interval begins at approximately 12 inches below ground surface. Collect samples for volatile organic analyses. For other analyses, select an appropriate, pre-cleaned sampling device and collect the sample. Transfer the sample to the appropriate sample container. Clean the outside of the sample container to remove excess soil. Label the sample container, place on wet ice to preserve at 4°C, and complete field notes. d.) Equipment for Reaching the Appropriate Soil Sampling Depth - Samples may be collected using a hollow stem soil auger, direct push, Shelby tube, split-spoon sampler, or core barrel. These sampling devices may be used as long as an effort is made to reduce the loss of contaminants through volatilization. In these situations, obtain a sufficient volume of so the samples can be collected without volatilization and disturbance to the internal structure of the samples. Samples should be collected from cores of the soil. Non-disposable sampling equipment must be decontaminated between each sample location. NOTE: If a confining layer has been breached during sampling, grout the hole to land. e.) Equipment to Collect Soil Samples - Equipment and materials that may be used to collect soil samples include disposable plastic syringes and other “industry-standard” equipment and materials that are contaminant-free. Non-disposable sampling equipment must be decontaminated between each sample location. Rev 4-08 13 Appendix C - Collecting Groundwater Samples Groundwater samples are collected to identify, investigate, assess and monitor the concentration of dissolved contaminant constituents. To properly assess groundwater contamination, first install sampling points (monitoring wells, etc.) to collect groundwater samples and then perform specific laboratory analyses. All monitoring wells should be constructed in accordance with 15A NCAC 2C .0100 and sampled as outlined in this section. Groundwater monitoring is conducted using one of two methods: 1. Portable Monitoring: Monitoring that is conducted using sampling equipment that is discarded between sampling locations. Equipment used to collect a groundwater sample from a well such as bailers, tubing, gloves, and etc. are disposed of after sample collection. A new set of sampling equipment is used to collect a groundwater sample at the next monitor well. 2. Dedicated Monitoring: Monitoring that utilizes permanently affixed down-well and well head components that are capped after initial set-up. Most dedicated monitoring systems are comprised of an in-well submersible bladder pump, with air supply and sample discharge tubing, and an above-ground driver/controller for regulation of flow rates and volumes. The pump and all tubing housed within the well should be composed of Teflon or stainless steel components. This includes seals inside the pump, the pump body, and fittings used to connect tubing to the pump. Because ground water will not be in contact with incompatible constituents and because the well is sealed from the surface, virtually no contamination is possible from intrinsic sources during sampling and between sampling intervals. All dedicated monitoring systems must be approved by the Solid Waste Section before installation. Groundwater samples may be collected from a number of different configurations. Each configuration is associated with a unique set of sampling equipment requirements and techniques: 1. Wells without Plumbing: These wells require equipment to be brought to the well to purge and sample unless dedicated equipment is placed in the well. 2. Wells with In-Place Plumbing: Wells with in-place plumbing do not require equipment to be brought to the well to purge and sample. In-place plumbing is generally considered permanent equipment routinely used for purposes other than purging and sampling, such as for water supply. 3. Air Strippers or Remedial Systems: These types of systems are installed as remediation devices. Rev 4-08 14 Groundwater Sample Preparation The type of sample containers used depends on the type of analysis performed. First, determine the type(s) of contaminants expected and the proper analytical method(s). Be sure to consult your selected laboratory for its specific needs and requirements prior to sampling. Next, prepare the storage and transport containers (ice chest, etc.) before taking any samples so that each sample can be placed in a chilled environment immediately after collection. Use groundwater purging and sampling equipment constructed of only non-reactive, non- leachable materials that are compatible with the environment and the selected analytes. In selecting groundwater purging and sampling equipment, give consideration to the depth of the well, the depth to groundwater, the volume of water to be evacuated, the sampling and purging technique, and the analytes of interest. Additional supplies, such as reagents and preservatives, may be necessary. All sampling equipment (bailers, tubing, containers, etc.) must be selected based on its chemical compatibility with the source being sampled (e.g., water supply well, monitoring well) and the contaminants potentially present. a.) Pumps - All pumps or pump tubing must be lowered and retrieved from the well slowly and carefully to minimize disturbance to the formation water. This is especially critical at the air/water interface. 1. Above-Ground Pumps • Variable Speed Peristaltic Pump: Use a variable speed peristaltic pump to purge groundwater from wells when the static water level in the well is no greater than 20- 25 feet below land surface (BLS). If the water levels are deeper than 18-20 feet BLS, the pumping velocity will decrease. A variable speed peristaltic pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. Most analyte groups can be sampled with a peristaltic pump if the tubing and pump configurations are appropriate. • Variable Speed Centrifugal Pump: A variable speed centrifugal pump can be used to purge groundwater from 2-inch and larger internal diameter wells. Do not use this type of pump to collect groundwater samples. When purging is complete, do not allow the water that remains in the tubing to fall back into the well. Install a check valve at the end of the purge tubing. 2. Submersible Pumps • Variable Speed Electric Submersible Pump: A variable speed submersible pump can be used to purge and sample groundwater from 2-inch and larger internal diameter wells. A variable speed submersible pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. The pump housing, fittings, check valves and associated hardware must be constructed of stainless steel. All other materials must be Rev 4-08 15 compatible with the analytes of interest. Install a check valve at the output side of the pump to prevent backflow. If purging and sampling for organics, the entire length of the delivery tube must be Teflon, polyethylene or polypropylene (PP) tubing; the electrical cord must be sealed in Teflon, polyethylene or PP and any cabling must be sealed in Teflon, polyethylene or PP, or be constructed of stainless steel; and all interior components that contact the sample water (impeller, seals, gaskets, etc.) must be constructed of stainless steel or Teflon. 3. Variable Speed Bladder Pump: A variable speed, positive displacement, bladder pump can be used to purge and sample groundwater from 3/4-inch and larger internal diameter wells. • A variable speed bladder pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. • The bladder pump system is composed of the pump, the compressed air tubing, the water discharge tubing, the controller and a compressor, or a compressed gas supply. • The pump consists of a bladder and an exterior casing or pump body that surrounds the bladder and two (2) check valves. These parts can be composed of various materials, usually combinations of polyvinyl chloride (PVC), Teflon, polyethylene, PP and stainless steel. Other materials must be compatible with the analytes of interest. • If purging and sampling for organics, the pump body must be constructed of stainless steel. The valves and bladder must be Teflon, polyethylene or PP; the entire length of the delivery tube must be Teflon, polyethylene or PP; and any cabling must be sealed in Teflon, polyethylene or PP, or be constructed of stainless steel. • Permanently installed pumps may have a PVC pump body as long as the pump remains in contact with the water in the well. b.) Bailers 1. Purging: Bailers must be used with caution because improper bailing can cause changes in the chemistry of the water due to aeration and loosening particulate matter in the space around the well screen. Use a bailer if there is non-aqueous phase liquid (free product) in the well or if non-aqueous phase liquid is suspected to be in the well. 2. Sampling: Bailers must be used with caution. 3. Construction and Type: Bailers must be constructed of materials compatible with the analytes of interest. Stainless steel, Teflon, rigid medical grade PVC, polyethylene and PP bailers may be used to sample all analytes. Use disposable bailers when sampling grossly contaminated sample sources. NCDENR recommends using dual check valve bailers when collecting samples. Use bailers with a controlled flow bottom to collect volatile organic samples. Rev 4-08 16 4. Contamination Prevention: Keep the bailer wrapped (foil, butcher paper, etc.) until just before use. Use protective gloves to handle the bailer once it is removed from its wrapping. Handle the bailer by the lanyard to minimize contact with the bailer surface. c.) Lanyards 1. Lanyards must be made of non-reactive, non-leachable material. They may be cotton twine, nylon, stainless steel, or may be coated with Teflon, polyethylene or PP. 2. Discard cotton twine, nylon, and non-stainless steel braided lanyards after sampling each monitoring well. 3. Decontaminate stainless steel, coated Teflon, polyethylene and PP lanyards between monitoring wells. They do not need to be decontaminated between purging and sampling operations. Water Level and Purge Volume Determination The amount of water that must be purged from a well is determined by the volume of water and/or field parameter stabilization. a.) General Equipment Considerations - Selection of appropriate purging equipment depends on the analytes of interest, the well diameter, transmissivity of the aquifer, the depth to groundwater, and other site conditions. 1. Use of a pump to purge the well is recommended unless no other equipment can be used or there is non-aqueous phase liquid in the well, or non-aqueous phase liquid is suspected to be in the well. 2. Bailers must be used with caution because improper bailing: • Introduces atmospheric oxygen, which may precipitate metals (i.e., iron) or cause other changes in the chemistry of the water in the sample (i.e., pH). • Agitates groundwater, which may bias volatile and semi- volatile organic analyses due to volatilization. • Agitates the water in the aquifer and resuspends fine particulate matter. • Surges the well, loosening particulate matter in the annular space around the well screen. • May introduce dirt into the water column if the sides of the casing wall are scraped. NOTE: It is critical for bailers to be slowly and gently immersed into the top of the water column, particularly during the final stages of purging. This minimizes turbidity and disturbance of volatile organic constituents. b.) Initial Inspection 1. Remove the well cover and remove all standing water around the top of the well casing (manhole) before opening the well. 2. Inspect the exterior protective casing of the monitoring well for damage. Document the results of the inspection if there is a problem. 3. It is recommended that you place a protective covering around the well head. Replace the covering if it becomes soiled or ripped. Rev 4-08 17 4. Inspect the well lock and determine whether the cap fits tightly. Replace the cap if necessary. c.) Water Level Measurements - Use an electronic probe or chalked tape to determine the water level. Decontaminate all equipment before use. Measure the depth to groundwater from the top of the well casing to the nearest 0.01 foot. Always measure from the same reference point or survey mark on the well casing. Record the measurement. 1. Electronic Probe: Decontaminate all equipment before use. Follow the manufacturer’s instructions for use. Record the measurement. 2. Chalked Line Method: Decontaminate all equipment before use. Lower chalked tape into the well until the lower end is in the water. This is usually determined by the sound of the weight hitting the water. Record the length of the tape relative to the reference point. Remove the tape and note the length of the wetted portion. Record the length. Determine the depth to water by subtracting the length of the wetted portion from the total length. Record the result. d.) Water Column Determination - To determine the length of the water column, subtract the depth to the top of the water column from the total well depth (or gauged well depth if silting has occurred). The total well depth depends on the well construction. If gauged well depth is used due to silting, report total well depth also. Some wells may be drilled in areas of sinkhole, karst formations or rock leaving an open borehole. Attempt to find the total borehole depth in cases where there is an open borehole below the cased portion. e.) Well Water Volume - Calculate the total volume of water, in gallons, in the well using the following equation: V = (0.041)d x d x h Where: V = volume in gallons d = well diameter in inches h = height of the water column in feet The total volume of water in the well may also be determined with the following equation by using a casing volume per foot factor (Gallons per Foot of Water) for the appropriate diameter well: V = [Gallons per Foot of Water] x h Where: V = volume in gallons h = height of the water column in feet Record all measurements and calculations in the field records. f.) Purging Equipment Volume - Calculate the total volume of the pump, associated tubing and flow cell (if used), using the following equation: V = p + ((0.041)d x d x l) + fc Where: V = volume in gallons p = volume of pump in gallons d = tubing diameter in inches l = length of tubing in feet Rev 4-08 18 fc = volume of flow cell in gallons g.) If the groundwater elevation data are to be used to construct groundwater elevation contour maps, all water level measurements must be taken within the same 24 hour time interval when collecting samples from multiple wells on a site, unless a shorter time period is required. If the site is tidally influenced, complete the water level measurements within the time frame of an incoming or outgoing tide. Well Purging Techniques The selection of the purging technique and equipment is dependent on the hydrogeologic properties of the aquifer, especially depth to groundwater and hydraulic conductivity. a.) Measuring the Purge Volume - The volume of water that is removed during purging must be recorded. Therefore, you must measure the volume during the purging operation. 1. Collect the water in a graduated container and multiply the number of times the container was emptied by the volume of the container, OR 2. Estimate the volume based on pumping rate. This technique may be used only if the pumping rate is constant. Determine the pumping rate by measuring the amount of water that is pumped for a fixed period of time, or use a flow meter. • Calculate the amount of water that is discharged per minute: D = Measured Amount/Total Time In Minutes • Calculate the time needed to purge one (1) well volume or one (1) purging equipment volume: Time = V/D Where: V = well volume or purging equipment volume D = discharge rate • Make new measurements each time the pumping rate is changed. 3. Use a totalizing flow meter. • Record the reading on the totalizer prior to purging. • Record the reading on the totalizer at the end of purging. • To obtain the volume purged, subtract the reading on the totalizer prior to purging from the reading on the totalizer at the end of purging. • Record the times that purging begins and ends in the field records. b.) Purging Measurement Frequency - When purging a well that has the well screen fully submerged and the pump or intake tubing is placed within the well casing above the well screen or open hole, purge a minimum of one (1) well volume prior to collecting measurements of the field parameters. Allow at least one quarter (1/4) well volume to purge between subsequent measurements. When purging a well that has the pump or intake tubing placed within a fully submerged well screen or open hole, purge until the water level has stabilized (well recovery rate equals the purge rate), then purge a minimum of one (1) volume of the pump, associated tubing and flow cell (if used) prior to collecting measurements of the field parameters. Take measurements of the field parameters no sooner than two (2) to three (3) minutes apart. Purge at least Rev 4-08 19 three (3) volumes of the pump, associated tubing and flow cell, if used, prior to collecting a sample. When purging a well that has a partially submerged well screen, purge a minimum of one (1) well volume prior to collecting measurements of the field parameters. Take measurements of the field parameters no sooner than two (2) to three (3) minutes apart. c.) Purging Completion - Wells must be adequately purged prior to sample collection to ensure representation of the aquifer formation water, rather than stagnant well water. This may be achieved by purging three volumes from the well or by satisfying any one of the following three purge completion criteria: 1.) Three (3) consecutive measurements in which the three (3) parameters listed below are within the stated limits, dissolved oxygen is no greater than 20 percent of saturation at the field measured temperature, and turbidity is no greater than 20 Nephelometric Turbidity Units (NTUs). • Temperature: + 0.2° C • pH: + 0.2 Standard Units • Specific Conductance: + 5.0% of reading Document and report the following, as applicable. The last four items only need to be submitted once: • Purging rate. • Drawdown in the well, if any. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. 2.) If it is impossible to get dissolved oxygen at or below 20 percent of saturation at the field measured temperature or turbidity at or below 20 NTUs, then three (3) consecutive measurements of temperature, pH, specific conductance and the parameter(s) dissolved oxygen and/or turbidity that do not meet the requirements above must be within the limits below. The measurements are: • Temperature: + 0.2° C • pH: + 0.2 Standard Units • Specific Conductance: + 5.0% of reading • Dissolved Oxygen: + 0.2 mg/L or 10%, whichever is greater • Turbidity: + 5 NTUs or 10%, whichever is greater Additionally, document and report the following, as applicable, except that the last four(4) items only need to be submitted once: • Purging rate. • Drawdown in the well, if any. • A description of conditions at the site that may cause the dissolved oxygen to be high and/or dissolved oxygen measurements made within the screened or open hole portion of the well with a downhole dissolved oxygen probe. Rev 4-08 20 • A description of conditions at the site that may cause the turbidity to be high and any procedures that will be used to minimize turbidity in the future. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. 3.) If after five (5) well volumes, three (3) consecutive measurements of the field parameters temperature, pH, specific conductance, dissolved oxygen, and turbidity are not within the limits stated above, check the instrument condition and calibration, purging flow rate and all tubing connections to determine if they might be affecting the ability to achieve stable measurements. It is at the discretion of the consultant/contractor whether or not to collect a sample or to continue purging. Further, the report in which the data are submitted must include the following, as applicable. The last four (4) items only need to be submitted once. • Purging rate. • Drawdown in the well, if any. • A description of conditions at the site that may cause the Dissolved Oxygen to be high and/or Dissolved Oxygen measurements made within the screened or open hole portion of the well with a downhole dissolved oxygen probe. • A description of conditions at the site that may cause the turbidity to be high and any procedures that will be used to minimize turbidity in the future. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. If wells have previously and consistently purged dry, and the current depth to groundwater indicates that the well will purge dry during the current sampling event, minimize the amount of water removed from the well by using the same pump to purge and collect the sample: • Place the pump or tubing intake within the well screened interval. • Use very small diameter Teflon, polyethylene or PP tubing and the smallest possible pump chamber volume. This will minimize the total volume of water pumped from the well and reduce drawdown. • Select tubing that is thick enough to minimize oxygen transfer through the tubing walls while pumping. Rev 4-08 21 • Pump at the lowest possible rate (100 mL/minute or less) to reduce drawdown to a minimum. • Purge at least two (2) volumes of the pumping system (pump, tubing and flow cell, if used). • Measure pH, specific conductance, temperature, dissolved oxygen and turbidity, then begin to collect the samples. Collect samples immediately after purging is complete. The time period between completing the purge and sampling cannot exceed six hours. If sample collection does not occur within one hour of purging completion, re-measure the five field parameters: temperature, pH, specific conductance, dissolved oxygen and turbidity, just prior to collecting the sample. If the measured values are not within 10 percent of the previous measurements, re-purge the well. The exception is “dry” wells. d.) Lanyards 1. Securely fasten lanyards, if used, to any downhole equipment (bailers, pumps, etc.). 2. Use bailer lanyards in such a way that they do not touch the ground surface. Wells Without Plumbing a.) Tubing/Pump Placement 1. If attempting to minimize the volume of purge water, position the intake hose or pump at the midpoint of the screened or open hole interval. 2. If monitoring well conditions do not allow minimizing of the purge water volume, position the pump or intake hose near the top of the water column. This will ensure that all stagnant water in the casing is removed. 3. If the well screen or borehole is partially submerged, and the pump will be used for both purging and sampling, position the pump midway between the measured water level and the bottom of the screen. Otherwise, position the pump or intake hose near the top of the water column. b.) Non-dedicated (portable) pumps 1. Variable Speed Peristaltic Pump • Wear sampling gloves to position the decontaminated pump and tubing. • Attach a short section of tubing to the discharge side of the pump and into a graduated container. • Attach one end of a length of new or precleaned tubing to the pump head flexible hose. • Place the tubing as described in one of the options listed above. • Change gloves before beginning to purge. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. Rev 4-08 22 • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells (see Appendix C) or if precleaned tubing is used for each well, only the pump. 2. Variable Speed Centrifugal Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Place the decontaminated suction hose so that water is always pumped from the top of the water column. • Change gloves before beginning to purge. • Equip the suction hose with a foot valve to prevent purge water from re-entering the well. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing at the approximate rate of drawdown so that the water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or if precleaned tubing is used for each well, only the pump. 3. Variable Speed Electric Submersible Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Carefully position the decontaminated pump. Rev 4-08 23 • Change gloves before beginning to purge. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing or pump at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or only the pump if precleaned tubing is used for each well. 4. Variable Speed Bladder Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Attach the tubing and carefully position the pump. • Change gloves before beginning purging. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing or pump at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or if precleaned tubing is used for each well, only the pump. c.) Dedicated Portable Pumps 1. Variable Speed Electric Submersible Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves. Rev 4-08 24 • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdraw with the recharge rate. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. 2. Variable Speed Bladder Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdraw with the recharge rate. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. 3. Bailers - Using bailers for purging is not recommended unless care is taken to use proper bailing technique, or if free product is present in the well or suspected to be in the well. • Minimize handling the bailer as much as possible. • Wear sampling gloves. • Remove the bailer from its protective wrapping just before use. • Attach a lanyard of appropriate material. • Use the lanyard to move and position the bailer. • Lower and retrieve the bailer slowly and smoothly. • Lower the bailer carefully into the well to a depth approximately a foot above the water column. • When the bailer is in position, lower the bailer into the water column at a rate of 2 cm/sec until the desired depth is reached. • Do not lower the top of the bailer more than one (1) foot below the top of the water table so that water is removed from the top of the water column. • Allow time for the bailer to fill with aquifer water as it descends into the water column. Rev 4-08 25 • Carefully raise the bailer. Retrieve the bailer at the same rate of 2 cm/sec until the bottom of the bailer has cleared to top of the water column. • Measure the purge volume. • Record the volume of the bailer. • Continue to carefully lower and retrieve the bailer as described above until the purging is considered complete, based on either the removal of 3 well volumes. • Remove at least one (1) well volume before collecting measurements of the field parameters. Take each subsequent set of measurements after removing at least one quarter (1/4) well volume between measurements. Groundwater Sampling Techniques a.) Purge wells. b.) Replace protective covering around the well if it is soiled or torn after completing purging operations. c.) Equipment Considerations 1. The following pumps are approved to collect volatile organic samples: • Stainless steel and Teflon variable speed submersible pumps • Stainless steel and Teflon or polyethylene variable speed bladder pumps • Permanently installed PVC bodied pumps (As long as the pump remains in contact with the water in the well at all times) 2. Collect sample from the sampling device and store in sample container. Do not use intermediate containers. 3. To avoid contamination or loss of analytes from the sample, handle sampling equipment as little as possible and minimize equipment exposure to the sample. 4. To reduce chances of cross-contamination, use dedicated equipment whenever possible. “Dedicated” is defined as equipment that is to be used solely for one location for the life of that equipment (e.g., permanently mounted pump). Purchase dedicated equipment with the most sensitive analyte of interest in mind. • Clean or make sure dedicated pumps are clean before installation. They do not need to be cleaned prior to each use, but must be cleaned if they are withdrawn for repair or servicing. • Clean or make sure any permanently mounted tubing is clean before installation. • Change or clean tubing when the pump is withdrawn for servicing. • Clean any replaceable or temporary parts. Rev 4-08 26 • Collect equipment blanks on dedicated pumping systems when the tubing is cleaned or replaced. • Clean or make sure dedicated bailers are clean before placing them into the well. • Collect an equipment blank on dedicated bailers before introducing them into the water column. • Suspend dedicated bailers above the water column if they are stored in the well. Sampling Wells Without Plumbing a.) Sampling with Pumps – The following pumps may be used to sample for organics: • Peristaltic pumps • Stainless steel, Teflon or polyethylene bladder pumps • Variable speed stainless steel and Teflon submersible pumps 1. Peristaltic Pump • Volatile Organics: One of three methods may be used. ƒ Remove the drop tubing from the inlet side of the pump; submerge the drop tubing into the water column; prevent the water in the tubing from flowing back into the well; remove the drop tubing from the well; carefully allow the groundwater to drain into the sample vials; avoid turbulence; do not aerate the sample; repeat steps until enough vials are filled. OR ƒ Use the pump to fill the drop tubing; quickly remove the tubing from the pump; prevent the water in the tubing from flowing back into the well; remove the drop tubing from the well; carefully allow the groundwater to drain into the sample vials; avoid turbulence; do not aerate the sample; repeat steps until enough vials are filled. OR ƒ Use the pump to fill the drop tubing; withdraw the tubing from the well; reverse the flow on the peristaltic pumps to deliver the sample into the vials at a slow, steady rate; repeat steps until enough vials are filled. • Extractable Organics: If delivery tubing is not polyethylene or PP, or is not Teflon lined, use pump and vacuum trap method. Connect the outflow tubing from the container to the influent side of the peristaltic pump. Turn pump on and reduce flow until smooth and even. Discard a Rev 4-08 27 small portion of the sample to allow for air space. Preserve (if required), label, and complete field notes. • Inorganic samples: These samples may be collected from the effluent tubing. If samples are collected from the pump, decontaminate all tubing (including the tubing in the head) or change it between wells. Preserve (if required), label, and complete field notes. 2. Variable Speed Bladder Pump • If sampling for organics, the pump body must be constructed of stainless steel and the valves and bladder must be Teflon. All tubing must be Teflon, polyethylene, or PP and any cabling must be sealed in Teflon, polyethylene or PP, or made of stainless steel. • After purging to a smooth even flow, reduce the flow rate. • When sampling for volatile organic compounds, reduce the flow rate to 100-200mL/minute, if possible. 3. Variable Speed Submersible Pump • The housing must be stainless steel. • If sampling for organics, the internal impellers, seals and gaskets must be constructed of stainless steel, Teflon, polyethylene or PP. The delivery tubing must be Teflon, polyethylene or PP; the electrical cord must be sealed in Teflon; any cabling must be sealed in Teflon or constructed of stainless steel. • After purging to a smooth even flow, reduce the flow rate. • When sampling for volatile organic compounds, reduce the flow rate to 100-200mL/minute, if possible. b.) Sampling with Bailers - A high degree of skill and coordination are necessary to collect representative samples with a bailer. 1. General Considerations • Minimize handling of bailer as much as possible. • Wear sampling gloves. • Remove bailer from protective wrapping just before use. • Attach a lanyard of appropriate material. • Use the lanyard to move and position the bailers. • Do not allow bailer or lanyard to touch the ground. • If bailer is certified precleaned, no rinsing is necessary. • If both a pump and a bailer are to be used to collect samples, rinse the exterior and interior of the bailer with sample water from the pump before removing the pump. • If the purge pump is not appropriate for collecting samples (e.g., non-inert components), rinse the bailer by collecting a single bailer of the groundwater to be sampled. • Discard the water appropriately. Rev 4-08 28 • Do not rinse the bailer if Oil and Grease samples are to be collected. 2. Bailing Technique • Collect all samples that are required to be collected with a pump before collecting samples with the bailer. • Raise and lower the bailer gently to minimize stirring up particulate matter in the well and the water column, which can increase sample turbidity. • Lower the bailer carefully into the well to a depth approximately a foot above the water column. When the bailer is in position, lower the bailer into the water column at a rate of 2 cm/sec until the desired depth is reached. • Do not lower the top of the bailer more than one foot below the top of the water table, so that water is removed from the top of the water column. • Allow time for the bailer to fill with aquifer water as it descends into the water column. • Do not allow the bailer to touch the bottom of the well or particulate matter will be incorporated into the sample. Carefully raise the bailer. Retrieve the bailer at the same rate of 2 cm/sec until the bottom of the bailer has cleared to top of the water column. • Lower the bailer to approximately the same depth each time. • Collect the sample. Install a device to control the flow from the bottom of the bailer and discard the first few inches of water. Fill the appropriate sample containers by allowing the sample to slowly flow down the side of the container. Discard the last few inches of water in the bailer. • Repeat steps for additional samples. • As a final step measure the DO, pH, temperature, turbidity and specific conductance after the final sample has been collected. Record all measurements and note the time that sampling was completed. c.) Sampling Low Permeability Aquifers or Wells that have Purged Dry 1. Collect the sample(s) after the well has been purged. Minimize the amount of water removed from the well by using the same pump to purge and collect the sample. If the well has purged dry, collect samples as soon as sufficient sample water is available. 2. Measure the five field parameters temperature, pH, specific conductance, dissolved oxygen and turbidity at the time of sample collection. 3. Advise the analytical laboratory and the client that the usual amount of sample for analysis may not be available. Rev 4-08 29 Appendix D - Collecting Samples from Wells with Plumbing in Place In-place plumbing is generally considered permanent equipment routinely used for purposes other than purging and sampling, such as for water supply. a.) Air Strippers or Remedial Systems - These types of systems are installed as remediation devices. Collect influent and effluent samples from air stripping units as described below. 1. Remove any tubing from the sampling port and flush for one to two minutes. 2. Remove all hoses, aerators and filters (if possible). 3. Open the spigot and purge sufficient volume to flush the spigot and lines and until the purging completion criteria have been met. 4. Reduce the flow rate to approximately 500 mL/minute (a 1/8” stream) or approximately 0.1 gal/minute before collecting samples. 5. Follow procedures for collecting samples from water supply wells as outlined below. b.) Water Supply Wells – Water supply wells with in-place plumbing do not require equipment to be brought to the well to purge and sample. Water supply wells at UST facilities must be sampled for volatile organic compounds (VOCs) and semivolatile compounds (SVOCs). 1. Procedures for Sampling Water Supply Wells • Label sample containers prior to sample collection. • Prepare the storage and transport containers (ice chest, etc.) before taking any samples so each collected sample can be placed in a chilled environment immediately after collection. • You must choose the tap closest to the well, preferably at the wellhead. The tap must be before any holding or pressurization tank, water softener, ion exchange, disinfection process or before the water line enters the residence, office or building. If no tap fits the above conditions, a new tap that does must be installed. • The well pump must not be lubricated with oil, as that may contaminate the samples. • The sampling tap must be protected from exterior contamination associated with being too close to a sink bottom or to the ground. If the tap is too close to the ground for direct collection into the appropriate container, it is acceptable to use a smaller (clean) container to transfer the sample to a larger container. • Leaking taps that allow water to discharge from around the valve stem handle and down the outside of the faucet, or taps in which water tends to run up on the outside of the lip, are to be avoided as sampling locations. Rev 4-08 30 • Disconnect any hoses, filters, or aerators attached to the tap before sampling. • Do not sample from a tap close to a gas pump. The gas fumes could contaminate the sample. 2. Collecting Volatile Organic Samples • Equipment Needed: VOC sample vials [40 milliliters, glass, may contain 3 to 4 drops of hydrochloric acid (HCl) as preservative]; Disposable gloves and protective goggles; Ice chest/cooler; Ice; Packing materials (sealable plastic bags, bubble wrap, etc.); and Lab forms. • Sampling Procedure: Run water from the well for at least 15 minutes. If the well is deep, run water longer (purging three well volumes is best). If tap or spigot is located directly before a holding tank, open a tap after the holding tank to prevent any backflow into the tap where you will take your sample. This will ensure that the water you collect is “fresh” from the well and not from the holding tank. After running the water for at least 15 minutes, reduce the flow of water. The flow should be reduced to a trickle but not so slow that it begins to drip. A smooth flow of water will make collection easier and more accurate. Remove the cap of a VOC vial and hold the vial under the stream of water to fill it. Be careful not to spill any acid that is in the vial. For best results use a low flow of water and angle the vial slightly so that the water runs down the inside of the vial. This will help keep the sample from being agitated, aerated or splashed out of the vial. It will also increase the accuracy of the sample. As the vial fills and is almost full, turn the vial until it is straight up and down so the water won’t spill out. Fill the vial until the water is just about to spill over the lip of the vial. The surface of the water sample should become mounded. It is a good idea not to overfill the vial, especially if an acid preservative is present in the vial. Carefully replace and screw the cap onto the vial. Some water may overflow as the cap is put on. After the cap is secure, turn the vial upside down and gently tap the vial to see if any bubbles are present. If bubbles are present in the vial, remove the cap, add more water and check again to see if bubbles are present. Repeat as necessary. After two samples without bubbles have been collected, the samples should be labeled and prepared for shipment. Store samples at 4° C. Rev 4-08 31 3. Collecting Extractable Organic and/or Metals Samples • Equipment Needed: SVOC sample bottle [1 liter, amber glass] and/or Metals sample bottle [0.5 liter, polyethylene or glass, 5 milliliters of nitric acid (HNO3) preservative]; Disposable gloves and protective goggles; Ice Chest/Cooler; Ice; Packing materials (sealable plastic bags, bubble wrap, etc.); and Lab forms. • Sampling Procedure: Run water from the well for at least 15 minutes. If the well is deep, run the water longer (purging three well volumes is best). If tap or spigot is located directly before a holding tank, open a tap after the holding tank to prevent any backflow into the tap where you will take your sample. This will ensure that the water you collect is “fresh” from the well and not from the holding tank. After running the water for at least 15 minutes, reduce the flow. Low water flow makes collection easier and more accurate. Remove the cap of a SVOC or metals bottle and hold it under the stream of water to fill it. The bottle does not have to be completely filled (i.e., you can leave an inch or so of headspace in the bottle). After filling, screw on the cap, label the bottle and prepare for shipment. Store samples at 4° C. Rev 4-08 32 Appendix E - Collecting Surface Water Samples The following topics include 1.) acceptable equipment selection and equipment construction materials and 2.) standard grab, depth-specific and depth-composited surface water sampling techniques. Facilities which contain or border small rivers, streams or branches should include surface water sampling as part of the monitoring program for each sampling event. A simple procedure for selecting surface water monitoring sites is to locate a point on a stream where drainage leaves the site. This provides detection of contamination through, and possibly downstream of, site via discharge of surface waters. The sampling points selected should be downstream from any waste areas. An upstream sample should be obtained in order to determine water quality upstream of the influence of the site. a.) General Cautions 1. When using watercraft take samples near the bow away and upwind from any gasoline outboard engine. Orient watercraft so that bow is positioned in the upstream direction. 2. When wading, collect samples upstream from the body. Avoid disturbing sediments in the immediate area of sample collection. 3. Collect water samples prior to taking sediment samples when obtaining both from the same area (site). 4. Unless dictated by permit, program or order, sampling at or near man- made structures (e.g., dams, weirs or bridges) may not provide representative data because of unnatural flow patterns. 5. Collect surface water samples from downstream towards upstream. b.) Equipment and Supplies - Select equipment based on the analytes of interest, specific use, and availability. c.) Surface Water Sampling Techniques - Adhere to all general protocols applicable to aqueous sampling when following the surface water sampling procedures addressed below. 1. Manual Sampling: Use manual sampling for collecting grab samples for immediate in-situ field analyses. Use manual sampling in lieu of automatic equipment over extended periods of time for composite sampling, especially when it is necessary to observe and/or note unusual conditions. • Surface Grab Samples - Do not use sample containers containing premeasured amounts of preservatives to collect grab samples. If the sample matrix is homogeneous, then the grab method is a simple and effective technique for collection purposes. If homogeneity is not apparent, based on flow or vertical variations (and should never be assumed), then use other collection protocols. Where practical, use the actual sample container submitted to the laboratory for collecting samples to be analyzed for oil and grease, volatile organic compounds (VOCs), and microbiological samples. This procedure eliminates the possibility of contaminating the sample with an intermediate collection container. The use of Rev 4-08 33 unpreserved sample containers as direct grab samplers is encouraged since the same container can be submitted for laboratory analysis after appropriate preservation. This procedure reduces sample handling and eliminates potential contamination from other sources (e.g., additional sampling equipment, environment, etc.). 1. Grab directly into sample container. 2. Slowly submerge the container, opening neck first, into the water. 3. Invert the bottle so the neck is upright and pointing towards the direction of water flow (if applicable). Allow water to run slowly into the container until filled. 4. Return the filled container quickly to the surface. 5. Pour out a few mL of sample away from and downstream of the sampling location. This procedure allows for the addition of preservatives and sample expansion. Do not use this step for volatile organics or other analytes where headspace is not allowed in the sample container. 6. Add preservatives, securely cap container, label, and complete field notes. If sample containers are attached to a pole via a clamp, submerge the container and follow steps 3 – 5 but omit steps 1 and 2. • Sampling with an Intermediate Vessel or Container: If the sample cannot be collected directly into the sample container to be submitted to the laboratory, or if the laboratory provides prepreserved sample containers, use an unpreserved sample container or an intermediate vessel (e.g., beakers, buckets or dippers) to obtain the sample. These vessels must be constructed appropriately, including any poles or extension arms used to access the sample location. 1. Rinse the intermediate vessel with ample amounts of site water prior to collecting the first sample. 2. Collect the sample as outlined above using the intermediate vessel. 3. Use pole mounted containers of appropriate construction to sample at distances away from shore, boat, etc. Follow the protocols above to collect samples. • Peristaltic Pump and Tubing: The most portable pump for this technique is a 12 volt peristaltic pump. Use appropriately precleaned, silastic tubing in the pump head and attach polyethylene, Tygon, etc. tubing to the pump. This technique is not acceptable for Oil and Grease, EPH, VPH or VOCs. Extractable organics can be collected through the pump if flexible interior-wall Teflon, polyethylene or PP tubing is used in the pump head or if used with the organic trap setup. Rev 4-08 34 1. Lower appropriately precleaned tubing to a depth of 6 – 12 inches below water surface, where possible. 2. Pump 3 – 5 tube volumes through the system to acclimate the tubing before collecting the first sample. 3. Fill individual sample bottles via the discharge tubing. Be careful not to remove the inlet tubing from the water. 4. Add preservatives, securely cap container, label, and complete field notes. • Mid-Depth Grab Samples: Mid-depth samples or samples taken at a specific depth can approximate the conditions throughout the entire water column. The equipment that may be used for this type of sampling consists of the following depth-specific sampling devices: Kemmerer, Niskin, Van Dorn type, etc. You may also use pumps with tubing or double check-valve bailers. Certain construction material details may preclude its use for certain analytes. Many Kemmerer samplers are constructed of plastic and rubber that preclude their use for all volatile and extractable organic sampling. Some newer devices are constructed of stainless steel or are all Teflon or Teflon-coated. These are acceptable for all analyte groups without restriction. 1. Measure the water column to determine maximum depth and sampling depth prior to lowering the sampling device. 2. Mark the line attached to the sampler with depth increments so that the sampling depth can be accurately recorded. 3. Lower the sampler slowly to the appropriate sampling depth, taking care not to disturb the sediments. 4. At the desired depth, send the messenger weight down to trip the closure mechanism. 5. Retrieve the sampler slowly. 6. Rinse the sampling device with ample amounts of site water prior to collecting the first sample. Discard rinsate away from and downstream of the sampling location. 7. Fill the individual sample bottles via the discharge tube. • Double Check-Valve Bailers: Collect samples using double check- valve bailers if the data requirements do not necessitate a sample from a strictly discrete interval of the water column. Bailers with an upper and lower check-valve can be lowered through the water column. Water will continually be displaced through the bailer until the desired depth is reached, at which point the bailer is retrieved. Sampling with this type of bailer must follow the same protocols outlined above, except that a messenger weight is not applicable. Although not designed specifically for this kind of sampling, a bailer is acceptable when a mid-depth sample is required Rev 4-08 35 1. As the bailer is dropped through the water column, water is displaced through the body of the bailer. The degree of displacement depends upon the check-valve ball movement to allow water to flow freely through the bailer body. 2. Slowly lower the bailer to the appropriate depth. Upon retrieval, the two check valves seat, preventing water from escaping or entering the bailer. 3. Rinse the sampling device with ample amounts of site water prior to collecting the first sample. 4. Fill the individual sample bottles via the discharge tube. Sample bottles must be handled as described above. • Peristaltic Pump and Tubing: The most portable pump for this technique is a 12 volt peristaltic pump. Use appropriately precleaned, silastic tubing in the pump head and attach HDPE, Tygon, etc. tubing to the pump. This technique is not acceptable for Oil and Grease, EPH, VPH or VOCs. Extractable organics can be collected through the pump if flexible interior-wall Teflon, polyethylene or PP tubing is used in the pump head, or if used with an organic trap setup. 1. Measure the water column to determine the maximum depth and the sampling depth. 2. Tubing will need to be tied to a stiff pole or be weighted down so the tubing placement will be secure. Do not use a lead weight. Any dense, non-contaminating, non- interfering material will work (brick, stainless steel weight, etc.). Tie the weight with a lanyard (braided or monofilament nylon, etc.) so that it is located below the inlet of the tubing. 3. Turn the pump on and allow several tubing volumes of water to be discharged before collecting the first sample. 4. Fill the individual sample bottles via the discharge tube. Sample bottles must be handled as described above. Rev 4-08 36 PAT MCCRORY Governor DONALD R. VAN DER VAART Secretary MICHAEL SCOTT Director State of North Carolina | Environmental Quality | Waste Management 1646 Mail Service Center | 217 West Jones Street | Raleigh, NC 27699-1646 919 707 8200 T September 9, 2016 UMEMORANDUM To: Solid Waste Directors, Public Works Directors, Landfill Operators, and Landfill Owners From: The Solid Waste Section Reference: Guidelines for 14-Day Notification of Groundwater Exceedances Form Submittal per rule: 15A NCAC 13B .1633(c)(1) • The 14-day notification form should be submitted whenever a groundwater protection standard (GWPS) is exceeded for the first time. o As defined in 13B .1634(g)(h), a GWPS will be either of the following: the 2L standard (most cases); 2L Interim Maximum Allowable Concentration; a groundwater protection standard calculated by the SWS; or a site-specific statistical background level approved by the SWS. • If a facility is undergoing assessment or corrective action, the 14-day notification form should be submitted UONLYU when the constituent with the reported exceedance is not being addressed through assessment or corrective action. • If a facility plans to conduct a re-sampling event to confirm the initial exceedance, the 14-day notification form should be submitted UONLYU when the re-sampling event analytical data confirms the initial exceedance. NC DEQ Division of Waste Management - Solid Waste 14-Day Notification of Groundwater Protection Standard Exceedance(s) Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed applicable groundwater protection standards. • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDEQ-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Phone: E-mail: Facility name: Facility Address: Facility Permit # Actual sampling dates (e.g., October 20-24, 2006) Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Assessment Monitoring Corrective Action Additional Information: A notification of values exceeding a groundwater protection standard as defined in 15A NCAC 13B .1634(g)(h) is attached. It includes a list of groundwater monitoring points, dates, analytical values, NC 2L groundwater standard, NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. A re-sampling event was conducted to confirm the exceedances. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Facility Representative Name (Print) Title (Area Code) Telephone Number Signature Affix NC Licensed/Professional Geologist or Professional Engineer Seal Revised 6/2016 Date Facility Representative Address NC PG/PE Firm License Number (if applicable effective May 1, 2009) Alternate Source Demonstration(s) have been approved for the following constituents with report date: per rule: 15A NCAC 13B .1633(c)(1) Gr o u n d w a t e r   Pr o t e c t i o n   St a n d a r d   Ex c e e d a n c e * Y ES Is  Fa c i l i t y   Cu r r e n t l y  in   As s e s s m e n t   or  Co r r e c t i v e   Ac t i o n ? No Is  As s e s s m e n t  or   CA  ad d r e s s i n g  the   Co n s t i t u e n t  w/  cu r r e n t   ex c e e d a n c e   va l u e ( s ) ?   No  14 ‐Day   No t i f i c a t i o n  STOP Wi l l    ve r i f i c a t i o n   re s a m p l i n g  &  An a l y s i s  be   co n d u c t e d ? Do e s   Ve r i f i c a t i o n   Sa m p l i n g   Co n f i r m  GW P S    Ex c e e d a n c e ( s ) ? Su b m i t  14 ‐Da y   No t i f i c a t i o n  Fo r m  to   SW S NC D W M  So l i d  Wa s t e  Se c t i o n   14 ‐Da y  No t i f i c a t i o n  of  GW P S  Ex c e e d a n c e s  Fl o w c h a r t        [p e r  Ru l e  15 A  NC A C  13 B  .1 6 3 3 ( c ) ( 1 ) ] Pr o c e e d  with   Al t e r n a t i v e  Source   De m o n s t r a t i o n  (ASD) or   As s e s s m e n t August 2 0 1 6 NO T E : *GW P S  = se e  Ru l e  15 A  NC A C  13 B  .1 6 3 4 ( g ) ( h ) No No Y ES No  14 ‐Da y   No t i f i c a t i o n   ST O P Y ES No Y ES Y ES No North Carolina Department of Environment and Natural Resources Division of Waste Management Pat McCrory John E. Skvarla, III Governor Secretary 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2090 US Highway 70, Swannanoa, North Carolina 28778-82111 Phone: 919-707-8200 Phone: 828-296-4500 http://portal.ncdenr.org/web/wm/ An Equal Opportunity / Affirmative Action Employer 1 November 5, 2014 MEMORANDUM To: Solid Waste Directors, Public Works Directors, Landfill Operators, and Landfill Owners From: Solid Waste Section Re: Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal The Solid Waste Section is continuing its efforts to improve efficiencies in document management. All groundwater, surface water, soil, sediment, and landfill gas documents submitted to the Solid Waste Section are stored electronically and are made readily available for the public to view on our webpage. Please remember that hard copies/paper copies are not required, and should not be submitted. The submittal of these electronic documents following a consistent electronic document protocol will also assist us in our review. Please follow these procedures when submitting all groundwater, surface water, soil, sediment, and landfill gas documents to the Solid Waste Section. Submittal Method and Formatting  All files must be in portable document format (pdf) except for Electronic Data Deliverables (EDDs) unless otherwise specified by the Solid Waste Section. All pdf files should meet these requirements: o Optical Characteristic Recognition (OCR) applied; o Minimum of 300 dpi; o Free of password protections and/or encryptions (applies to EDDs as well); o Optimized to reduce file size; and o Please begin using the following naming convention when submitting all electronic files: Permit Number (00-00)_Date of Document (YYYYMMDD). For example: 00-00_20140101.  Please submit all files via email or by file transfer protocol (FTP) via email to the appropriate Hydrogeologist unless otherwise specified by the Solid Waste Section. If the electronic file is greater than 20 MB, please submit the file via FTP or on a CD. If submitting a CD, please mail the CD to the appropriate Hydrogeologist. The CD should be labeled with the facility name, permit number, county, name of document, date of monitoring event (if applicable), and the date of document.  Please be sure a signed Environmental Monitoring Data Form is submitted as part of the electronic file for all water quality and landfill gas documents (monitoring, alternate source demonstration, assessment, investigation, corrective action). This completed form should be the first page of the document before the cover/title page and should not be submitted as an individual file. Blank forms can be downloaded at http://www.wastenotnc.org/swhome/EnvMonitoring/NCEnvMonRptForm.pdf Monitoring Data Monitoring data documents may include any or all of the following: 1) groundwater and surface water monitoring; 2) soil and sediment, and 3) landfill gas monitoring. In addition to the above procedures, at a minimum, please include the following: Groundwater and Surface Water Monitoring  A copy of the laboratory report(s).  A copy of the sampling log(s).  A separate table of detections and exceedances for each monitoring location. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2090 US Highway 70, Swannanoa, North Carolina 28778-82111 Phone: 919-707-8200 Phone: 828-296-4500 http://portal.ncdenr.org/web/wm/ An Equal Opportunity / Affirmative Action Employer 2 o All analytical results should be reported in micrograms per liter (ug/L) except for field parameters and specific Monitored Natural Attenuation (MNA) parameters. o Please also include the laboratory’s method detection limit (MDL) in ug/L, the Solid Waste Section Limit (SWSL) in ug/L, the appropriate NC regulatory standard in ug/L (2L, 2B, GWPS, IMAC), and the Federal Maximum Contaminant Level (MCL) in ug/L. o Please BOLD each exceedance result.  A separate table of field parameters for each monitoring location.  An Electronic Data Deliverable (EDD) spreadsheet for each monitoring event submitted in the correct format. All analytical results should be reported in micrograms per liter (ug/L) except for field parameters and specific Monitored Natural Attenuation (MNA) parameters. The blank EDD template can be downloaded at http://www.wastenotnc.org/swhome/enviro_monitoring.asp. Please pay attention to the formats within the spreadsheet. Any EDD received that is not formatted correctly will be emailed back to be resubmitted via email within five (5) days.  A separate groundwater monitoring well construction table. o Please also include the date the well was drilled, well diameter, total well depth, depth to top of screened interval (in feet), screened interval (in feet), geology of screened interval, TOC elevation, ground elevation, groundwater elevation, GPS coordinates (latitude and longitude), and depth to water (in feet).  A separate groundwater table with groundwater flow rate(s).  A recent facility figure that includes labeled groundwater and surface water monitoring locations.  A groundwater flow map with an arrow(s) indicating flow direction(s), including date the measurements were taken. Soil and Sediment Sampling  A copy of the laboratory report(s).  A copy of the sampling log(s).  A separate table of detections and exceedances for each sampling location. o Please also include the results in micrograms per liter (ug/L), the laboratory’s method detection limit (MDL) in ug/L, and the appropriate NC regulatory standard (PSRG) in ug/L. o Please BOLD each exceedance result.  A separate table of soil and/or sediment characteristics.  A recent facility figure that includes labeled sampling locations. Landfill Gas Monitoring  A blank Landfill Gas Monitoring Data Form can be found within the Landfill Gas Monitoring Guidance document and can be downloaded at http://portal.ncdenr.org/c/document_library/get_file?uuid=da699f7e-8c13-4249-9012- 16af8aefdc7b&groupId=38361.  A separate table of landfill gas detections and exceedances for each monitoring location. Please BOLD each exceedance result.  A recent facility figure that includes labeled landfill gas monitoring locations (both permanent and temporary). If you have any questions or concerns regarding electronic submittals, please feel free to contact the Hydrogeologist overseeing your facility. The Solid Waste Section greatly appreciates your assistance on this matter. Working together, we can continue to provide excellent customer service to you and to the public.  Jackie Drummond, Asheville Regional Office, 828-296-4706, jaclynne.drummond@ncdenr.gov  Ervin Lane, Raleigh Central Office, 919-707-8288, ervin.lane@ncdenr.gov  Elizabeth Werner, Raleigh Central Office, 919-707-8253, elizabeth.werner@ncdenr.gov  Christine Ritter, Raleigh Central Office, 919-707-8254, christine.ritter@ncdenr.gov  Perry Sugg, Raleigh Central Office, 919-707-8258, perry.sugg@ncdenr.gov 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 1 North Carolina Department of Environment and Natural Resources October 16, 2007 EMORANDUM Dexter R. Matthews, Director Division of Wa e Management st Michael F. Easley, Governor William G. Ross Jr., Secretary M To: Operators, North Carolina Certified Laboratories, and Consultants rom: North Carolina Division of Waste Management, Solid Waste Section Re: ring Data for North Carolina Solid Waste Management Facilities and provide a reminder of formats for environmental monitoring data bmittals. ese changes was to improve the protection of public health and the nvironment. reported to the North Carolina Solid Waste Section. The PQLs will no nger be used. ted can be directed to the North Carolina Department of Health nd Human Services. Solid Waste Directors, Landfill F Environmental Monito The purpose of this memorandum is to provide a reiteration of the use of the Solid Waste Section Limits (SWSLs), provide new information on the Groundwater Protection Standards, su The updated guidelines are in large part due to questions and concerns from laboratories, consultants, and the regulated community regarding the detection of constituents in groundwater at levels below the previous Practical Quantitation Limits (PQLs). The North Carolina Solid Waste Section solicited feedback from the regulated community, and, in conjunction with the regulated community, developed new limits. The primary purpose of the Data must be reported to the laboratory specific method detection limits and must be quantifiable at or below the SWSLs. The SWSLs must be used for both groundwater and surface water datalo In June 2007, we received new information regarding changes to the Groundwater Protection Standards. If a North Carolina 2L Groundwater Standard does not exist, then a designated Groundwater Protection Standard is used pursuant to 15A NCAC 13B .1634. Toxicologists with the North Carolina Department of Health and Human Services calculated these new Groundwater Protection Standards. Questions regarding how the standards were calculaa 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 2 every year or sooner if new scientific and toxicological data become available. lease review our website periodically for any changes to the 2L NC Standards, ic updates will be noted on our ebsite. wastenotnc.org/sw/swenvmonitoringlist.asp We have reviewed the new results from the North Carolina Department of Public Health and have updated our webpage accordingly. The list of Groundwater Protection Standards, North Carolina 2L Standards and SWSLs are subject to change and will be reviewedPGroundwater Protection Standards, or SWSLs. Specifw http://www. ental monitoring data In addition, the following should be included with environmsubmittals: 1. Environmental Monitoring Data Form as a cover sheet: http://www.wastenotnc.org/swhome/EnvMonitoring/NCEnvMonRptForm.pdf 2. Copy of original laboratory results. 3. Table of detections and discussion of 2L exceedances. 4. Electronic files on CD or sent by email. These files should include the written report as Portable Document Format (PDF) file and the laboratory data as an excel file following a the format of the updated Electronic Data Deliverable (EDD) template on our website: http://www.wastenotnc.org/swhome/enviro_monitoring.asp If you have any questions or concerns, please feel free to contact Donald Herndon (919- 08-8502), Ervin Lane (919-508-8520) or Jaclynne Drummond (919-508-8500). Thank you for your continued cooperation with these matters. 5 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 1 North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary February 23, 2007 EMORANDUM M o: Solid Waste Directors, Landfill Operators, North Carolina Certified Laboratories, and Consultants rom: North Carolina Division of Waste Management, Solid Waste Section Re: ste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data. arolina Solid Waste Section memo titled, “New Guidelines for Electronic Submittal of Environmental Data.” adily available laboratory analytical methodology and current health-based groundwater protection standards. efinitions T F Addendum to October 27, 2006, North Carolina Solid Wa The purpose of this addendum memorandum is to provide further clarification to the October 27, 2006, NorthC The updated guidelines is in large part due to questions and concerns from laboratories, consultants, and the regulated community regarding the detection of constituents in groundwater at levels below the previous practical quantitation limits (PQLs). The North Carolina Solid Waste Section solicited feedback from the regulated community, and, in conjunction with the regulated community, developed new limits. The primary purpose of these changes was to improve the protection of public health and the environment. The North Carolina Solid Waste Section is concerned about analytical data at these low levels because the earliest possible detection of toxic or potentially carcinogenic chemicals in the environment is paramount in the North Carolina Solid Waste Section’s mission to protect human health and the environment. Low level analytical data are critical for making the correct choices when designing site remediation strategies, alerting the public to health threats, and protecting the environment from toxic contaminants. The revised limits were updated based on re D s are also an attempt to clarify the meaning of these rms as used by the North Carolina Solid Waste Section. e that can be measured and ported with 99% confidence that the analyte concentration is greater than zero. is the minimum concentration of a target analyte that can be accurately determined by the referenced method. Many definitions relating to detection limits and quantitation limits are used in the literature and by government agencies, and commonly accepted procedures for calculating these limits exist. Except for the Solid Waste Section Limit and the North Carolina 2L Standards, the definitions listed below are referenced from the Environmental Protection Agency (EPA). The definitionte Method Detection Limit (MDL) is the minimum concentration of a substanc re Method Reporting Limit or Method Quantitation Limit (MRL or MQL) Practical Quantitation Limit (PQL) is a quantitation limit that represents a practical and routinely achievable quantitation limit with a high degree of certainty (>99.9% confidence) in the results. Per EPA Publication Number SW-846, the PQL is the lowest concentration that can be reliably measured within specified limits of precision and accuracy for a specific laboratory analytical method during routine laboratory operating conditions in accordance with "Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods. The PQL appears in 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 2 older NCDENR literature; however, it is no longer being used by the North Carolina Solid aste Section. n. The nomenclature of the SWRL described in the October 7, 2006, memorandum has changed to the SWSL. C 2L .0200, Classifications and Water Quality Standards Applicable to the roundwaters of North Carolina. ethod Detection Limits (MDLs) W Solid Waste Section Limit (SWSL) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported analytical results must be qualified as estimated. The SWSL is the updated version of the PQL that appears in older North Carolina Solid Waste Section literature. The SWSL is the limit established by the laboratory survey conducted by the North Carolina Solid Waste Sectio 2 North Carolina 2L Standards (2L) are water quality standards for the protection of groundwaters of North Carolina as specified in 15A NCA G M he North Carolina Solid Waste Section is now quiring laboratories to report to the method detection limit. atories generally report the highest method detection limit for all the instruments sed for a specific method. ata below unspecified or non-statistical reporting limits severely biases data sets and restricts their usefulness. olid Waste Section Limits (SWSLs) Clarification of detection limits referenced in the October 27, 2006, memorandum needed to be addressed because of concerns raised by the regulated community. Tre Method detection limits are statistically determined values that define the concentration at which measurements of a substance by a specific analytical protocol can be distinguished from measurements of a blank (background noise). Method detection limits are matrix-specific and require a well defined analytical method. In the course of routine operations, laboru In many instances, the North Carolina Solid Waste Section gathers data from many sources prior to evaluating the data or making a compliance decision. Standardization in data reporting significantly enhances the ability to interpret and review data because the reporting formats are comparable. Reporting a method detection limit alerts data users of the known uncertainties and limitations associated with using the data. Data users must understand these limitations in order to minimize the risk of making poor environmental decisions. Censoring d S nd surface water data reported to the North Carolina Solid Waste ection. The PQLs will no longer be used. Due to comments from the regulated community, the North Carolina Solid Waste Section has changed the nomenclature of the new limits referenced on Page 2 of the October 27, 2006, memorandum, from the North Carolina Solid Waste Reporting Limits (SWRL) to the Solid Waste Section Limits (SWSL). Data must be reported to the laboratory specific method detection limits and must be quantifiable at or below the SWSL. The SWSLs must be used for both groundwater aS The North Carolina Solid Waste Section has considered further feedback from laboratories and the regulated community and ha 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 3 s made some additional changes to the values of the SWSLs. These changes may be viewed ttp://www.wastenotnc.org/sw/swenvmonitoringlist.asp nalytical Data Reporting Requirements on our webpage: h A al boratory method detection limit with all analytical laboratory results along with the following requirements: oncentration, compliance action may not be taken unless it is statistically significant crease over background. hese analytical results may require additional confirmation. he possibility that a constituent concentration may exceed the North Carolina 2L Standards in the ture. hese analytical results may be used for compliance without further confirmation. will be returned and deemed unacceptable. Submittal of unacceptable data may lead to lectronic Data Deliverable (EDD) Submittal The strategy for implementing the new analytical data reporting requirements involves reporting the actula 1) Any analyte detected at a concentration greater than the MDL but less than the SWSL is known to be present, but the uncertainty in the value is higher than a value reported above the SWSL. As a result, the actual concentration is estimated. The estimated concentration is reported along with a qualifier (“J” flag) to alert data users that the result is between the MDL and the SWSL. Any analytical data below quantifiable levels should be examined closely to evaluate whether the analytical data should be included in any statistical analysis. A statistician should make this determination. If an analyte is detected below the North Carolina 2L Standards, even if it is a quantifiable cin T 2) Any analyte detected at a concentration greater than the SWSL is present, and the quantitated value can be reported with a high degree of confidence. These analytes are reported without estimated qualification. The laboratory’s MDL and SWSL must be included in the analytical laboratory report. Any reported concentration of an organic or inorganic constituent at or above the North Carolina 2L Standards will be used for compliance purposes, unless the inorganic constituent is not statistically significant). Exceedance of the North Carolina 2L Standards or a statistically significant increase over background concentrations define when a violation has occurred. Any reported concentration of an organic or inorganic constituent at or above the SWSL that is not above an North Carolina 2L Standard will be used as a tool to assess the integrity of the landfill system and predict t fu T Failure to comply with the requirements described in the October 27, 2006, memorandum and this addendum to the October 27, 2006, memorandum will constitute a violation of 15A NCAC 13B .0601, .0602, or .1632(b), and the analytical dataenforcement action. E he analytical laboratory data. This option is intended to save resources r both the public and private sectors. The North Carolina Solid Waste Section would also like to take this opportunity to encourage electronic submittal of the reports in addition to tfo The North Carolina Solid Waste Section will accept the entire report including narrative text, figures, tables, and maps on CD-ROM. Please separate the figures and tables from the report when saving in order to keep the size of the files smaller. The CD-ROM submittal shall contain a CD-ROM case and both CD 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-8400 \ FAX 919-715-3605 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper 4 -ROM and the ase shall be labeled with the site name, site address, permit number, and the monitoring event date ab data and field data. This template is available on our webpage: ttp://www.wastenotnc.org/swhome/enviro_monitoring.asp. Methane monitoring data may also be submitted ry or exceeds 25% of the LEL facility structures (excluding gas control or recovery system components), include the exceedance(s) on the you have any questions or concerns, please feel free to contact Jaclynne Drummond (919-508-8500) or Ervin Thank you for your continued cooperation with this matter. c(MM/DD/YYYY). The reporting files may be submitted as a .pdf, .txt, .csv, .xls,. or .doc type. Also, analytical lab data and field data should be reported in .xls files. The North Carolina Solid Waste Section has a template for analytical lhelectronically in this format. Pursuant to the October 27, 2006, memorandum, please remember to submit a Solid Waste Section Environmental Monitoring Reporting Form in addition to your environmental monitoring data report. This form should be sealed by a geologist or engineer licensed in North Carolina if hydrogeologic or geologic calculations, maps, or interpretations are included with the report. Otherwise, any representative that the facility owner chooses may sign and submit the form. Also, if the concentration of methane generated by the facility exceeds 100% of the lower explosive limits (LEL) at the property bounda inNorth Carolina Solid Waste Section Environmental Monitoring Reporting Form. If Lane (919-508-8520). North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-508-8400 \ FAX: 919-733-4810 \ Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer – Printed on Dual Purpose Recycled Paper October 27, 2006 To: SW Director/County Manager/Consultant/Laboratory From: NC DENR-DWM, Solid Waste Section Re: New Guidelines for Electronic Submittal of Environmental Monitoring Data The Solid Waste Section receives and reviews a wide variety of environmental monitoring data from permitted solid waste management facilities, including the results from groundwater and surface water analyses, leachate samples, methane gas readings, potentiometric measurements, and corrective action data. We are in the process of developing a database to capture the large volume of data submitted by facilities. To maintain the integrity of the database, it is critical that facilities, consultants, and laboratories work with the Solid Waste Section to ensure that environmental samples are collected and analyzed properly with the resulting data transferred to the Solid Waste Section in an accurate manner. In order to better serve the public and to expedite our review process, the Solid Waste Section is requesting specific formatting for environmental monitoring data submittals for all solid waste management facilities. Effective, December 1, 2006, please submit a Solid Waste Environmental Monitoring Data Form in addition to your environmental monitoring data report. This form will be sent in lieu of your current cover letter to the Solid Waste Section. The Solid Waste Environmental Monitoring Data Form must be filled out completely, signed, and stamped with a Board Certified North Carolina Geologist License Seal. The solid waste environmental monitoring data form will include the following: 1. Contact Information 2. Facility Name 3. Facility Permit Number 4. Facility Address 5. Monitoring Event Date (MM/DD/YYYY) 6. Water Quality Status: Monitoring, Detection Monitoring, or Assessment Monitoring 7. Type of Data Submitted: Groundwater Monitoring Wells, Groundwater Potable Wells, Leachate, Methane Gas, or Corrective Action Data 8. Notification of Exceedance of Groundwater, Surface Water, or Methane Gas (in table form) 9. Signature 10. North Carolina Geologist Seal Page 2 of 2 Most of these criteria are already being included or can be added with little effort. The Solid Waste Environmental Monitoring Data Form can be downloaded from our website: http://www.wastenotnc.org/swhome/enviro_monitoring.asp. The Solid Waste Section is also requesting a new format for monitoring wells, potable wells, surface water sampling locations, and methane probes. This format is essential in the development and maintenance of the database. The Solid Waste Section is requesting that each sampling location at all North Carolina solid waste management facilities have its own unique identification number. We are simply asking for the permit number to be placed directly in front of the sampling location number (example: 9901-MW1 = Permit Number 99-01 and Monitoring Well MW-1). No changes will need to be made to the well tags, etc. This unique identification system will enable us to accurately report data not only to NCDENR, but to the public as well. We understand that this new identification system will take some time to implement, but we feel that this will be beneficial to everyone involved in the long term. Additionally, effective December 1, 2006, the Practical Quantitation Limits (PQLs) established in 1994 will change. The Solid Waste Section is requiring that all solid waste management facilities use the new Solid Waste Reporting Limits (SWRL) for all groundwater analyses by a North Carolina Certified Laboratory. Laboratories must also report any detection of a constituent even it is detected below the new SWRL (e.g., J values where the constituent was detected above the detection limit, but below the quantitation limit). PQLs are technology-based analytical levels that are considered achievable using the referenced analytical method. The PQL is considered the lowest concentration of a contaminant that the lab can accurately detect and quantify. PQLs provided consistency and available numbers that were achievable by the given analytical method. However, PQLs are not health-based, and analytical instruments have improved over the years resulting in lower achievable PQLs for many of the constituents. As a result, the Solid Waste Section has established the SWRLs as the new reporting limits eliminating the use of the PQLs. We would also like to take this opportunity to encourage electronic submittal of the reports. This option is intended to save resources for both the public and private sectors. The Solid Waste Section will accept the entire report including narrative text, figures, tables, and maps on CD-ROM. The CD-ROM submittal shall contain a CD-ROM case and both CD-ROM and the case shall be labeled with the site name, site address, permit number, and the monitoring event date (MM/DD/YYYY). The files may be a .pdf, .txt, .csv, .xls, or .doc type. Also, analytical lab data should be reported in an .xls file. We have a template for analytical lab data available on the web at the address listed above. If you have any questions or concerns, please call (919) 508-8400. Thank you for your anticipated cooperation in this matter.