0501_AsheCoMSWLF_Oct2015LeachateMR_DIN27418_20160308

Ashe County Subtitle D Lined MSWLF
Crumpler, North Carolina
May 13, 2015 through October 23, 2015
MESCO Project Number: G15005.0
Semi-Annual Leachate Recirculation Report
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
Permit Number: 05-01
P.O. Box 97
Garner, NC 27529
License Number: C-0281
March 7, 2016
Mr. Ervin Lane
Solid Waste Section
Division of Waste Management
North Carolina Department of Environment and Natural Resources
401 Oberlin Road, Suite 150
Raleigh, NC 27605
Re: Semi-Annual Leachate Recirculation Report
Ashe County Subtitle D Lined MSWLF
Permit No. 05-01
MESCO Project No. G15005.0
Reporting Period: May 13, 2015 through October 23, 2015
Dear Mr. Lane:
The Ashe County Subtitle D Lined MSWLF located near Crumpler NC, currently operating under permit #05-01 is
permitted to recirculate leachate onto existing MSWLF Phases. During the period between May 13, 2015 through
October 23, 2015 leachate was reported to be recirculated into the Phase 4 lined landfill and disposed of at Waste
Water Treatment Plants (WWTP).
In accordance with the permit requirements the volume of leachate recirculated, the amount of precipitation
reported, the analytical results of leachate sampling and the amount of leachate disposed of off site are included
here and in the attachments. This leachate recirculation report is submitted semi-annually with the dates
corresponding to the facility's established routine semi-annual water quality detection monitoring program. The
pertinent information for this semi-annual event is found below:
●Leachate recirculated into Lined Landfill: 465,000 gallons
●Leachate disposed of at WWTPs: 29,990 gallons
●Amount of precipitation: 24.60 inches
●Leachate analytical sampling date: October 23, 2015
The next semi-annual sampling event will be performed in May 2016 and the report will be submitted upon
completion. If you have any questions or comments regarding this report, please contact us by phone at (919) 772-
5393 or by email at [e-mail].
Sincerely,
MUNICIPAL ENGINEERING SERVICES CO., P.A.
Jonathan Pfohl
Environmental Specialist
Enclosures
cc: Mr. Scott Hurley
Ashe County

Tables
Ashe County Subtitle D Lined MSWLF Page 1 of 1
Table 1
Detections in Leachate Samples above SWSL
October 23, 2015
Result Unit
LAGOON Sulfate 10/23/15 2310J 1000 250000 NE NE
LAGOON COD 10/23/15 270000 12500 NE NE NE
LAGOON Phosphorus 10/23/15 127 25 NE NE NE
LAGOON BOD, 5 day 10/23/15 9300 2000 2000 NE NE
LAGOON 10/23/15 1.1 0.24 1 7 NE
LAGOON 10/23/15 3.5 0.33 1 6 75
LAGOON Benzene 10/23/15 9.3 0.25 1 1 5
LAGOON 10/23/15 18.4 0.3 1 550 700
LAGOON Toluene 10/23/15 3.7 0.26 1 600 NE
LAGOON Xylene (Total)10/23/15 21.7 0.66 5 530 10000
LAGOON Cobalt 10/23/15 2.7J 2.5 10 NE 1 NE
LAGOON Barium 10/23/15 141 2.5 100 700 1300
LAGOON Cadmium 10/23/15 1.2 0.5 1 2 5
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
BOLD = Concentration > 2L, 2B, GWP or MCL Standard
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6
ug/L
ug/L
ug/L
ug/L
1,2-Dichloroethane ug/L
1,4-Dichlorobenzene ug/L
ug/L
Ethylbenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, or 2B
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 GWP = Groundwater Protection Standard
Table 2
Daily Precipitation & Leachate Recirculation Data as Recorded at Facility
May 13, 2015 through October 23, 2015
5/13/15 0.00 2,966 15,000 7/3/15 0.00 0 0 8/23/15 0.00 0 0 10/13/15 0.00 0 0
5/14/15 0.00 0 0 7/4/15 0.10 0 0 8/24/15 0.20 0 0 10/14/15 0.00 0 0
5/15/15 0.20 0 0 7/5/15 0.00 0 0 8/25/15 0.00 0 12,000 10/15/15 0.00 0 0
5/16/15 0.00 0 0 7/6/15 1.25 0 0 8/26/15 0.00 0 12,000 10/16/15 0.00 0 0
5/17/15 0.00 0 0 7/7/15 0.10 0 15,000 8/27/15 0.00 0 0 10/17/15 0.00 0 0
5/18/15 0.20 0 15,000 7/8/15 0.00 0 0 8/28/15 0.00 0 0 10/18/15 0.00 0 0
5/19/15 0.00 0 0 7/9/15 0.00 0 0 8/29/15 0.00 0 0 10/19/15 0.00 6,024 0
5/20/15 0.00 0 36,000 7/10/15 0.25 0 0 8/30/15 0.00 0 0 10/20/15 0.00 3,010 0
5/21/15 0.00 0 0 7/11/15 0.00 0 0 8/31/15 0.00 0 21,000 10/21/15 0.00 6,025 0
5/22/15 0.00 0 18,000 7/12/15 0.00 0 0 9/1/15 0.00 0 6,000 10/22/15 0.00 8,958 0
5/23/15 0.00 0 0 7/13/15 0.20 0 0 9/2/15 0.00 0 0 10/23/15 0.00 3,007 0
5/24/15 0.00 0 0 7/14/15 1.50 0 0 9/3/15 0.00 0 0 SubTotal 24.60 29,990 465,000
5/25/15 0.00 0 0 7/15/15 0.25 0 0 9/4/15 0.10 0 15,000 TOTAL
5/26/15 0.00 0 15,000 7/16/15 0.00 0 0 9/5/15 0.00 0 0
5/27/15 0.00 0 0 7/17/15 0.00 0 15,000 9/6/15 0.00 0 0
5/28/15 0.30 0 0 7/18/15 0.00 0 0 9/7/15 0.00 0 6,000
5/29/15 0.10 0 0 7/19/15 0.00 0 0 9/8/15 0.00 0 0
5/30/15 0.00 0 12,000 7/20/15 0.40 0 0 9/9/15 0.00 0 18,000
5/31/15 0.00 0 0 7/21/15 0.00 0 0 9/10/15 0.10 0 9,000
6/1/15 1.50 0 0 7/22/15 0.00 0 12,000 9/11/15 0.00 0 0
6/2/15 0.40 0 0 7/23/15 0.10 0 0 9/12/15 0.10 0 0
6/3/15 0.30 0 0 7/24/15 0.00 0 0 9/13/15 0.00 0 0
6/4/15 0.00 0 0 7/25/15 0.00 0 12,000 9/14/15 0.40 0 0
6/5/15 0.10 0 6,000 7/26/15 0.00 0 0 9/15/15 0.00 0 0
6/6/15 0.00 0 0 7/27/15 0.10 0 9,000 9/16/15 0.00 0 12,000
6/7/15 0.00 0 0 7/28/15 0.00 0 0 9/17/15 0.00 0 9,000
6/8/15 0.00 0 12,000 7/29/15 0.00 0 0 9/18/15 0.00 0 0
6/9/15 0.00 0 0 7/30/15 0.00 0 0 9/19/15 0.00 0 0
6/10/15 0.20 0 0 7/31/15 0.40 0 0 9/20/15 0.00 0 0
6/11/15 0.00 0 0 8/1/15 0.00 0 0 9/21/15 0..2 0 0
6/12/15 0.00 0 24,000 8/2/15 0.00 0 0 9/22/15 0.40 0 0
6/13/15 0.10 0 0 8/3/15 0.10 0 0 9/23/15 0.00 0 0
6/14/15 0.00 0 0 8/4/15 0.00 0 18,000 9/24/15 0.00 0 9,000
6/15/15 0.00 0 0 8/5/15 0.10 0 9,000 9/25/15 2.50 0 0
6/16/15 0.10 0 0 8/6/15 0.10 0 0 9/26/15 1.75 0 0
6/17/15 0.00 0 9,000 8/7/15 0.10 0 9,000 9/27/15 0.00 0 0
6/18/15 0.00 0 0 8/8/15 0.00 0 0 9/28/15 2.00 0 0
6/19/15 0.20 0 0 8/9/15 0.00 0 0 9/29/15 0.00 0 0
6/20/15 0.00 0 0 8/10/15 0.30 0 9,000 9/30/15 0.40 0 0
6/21/15 0.00 0 0 8/11/15 0.00 0 0 10/1/15 0.00 0 0
6/22/15 0.40 0 0 8/12/15 0.10 0 0 10/2/15 0.30 0 0
6/23/15 0.00 0 0 8/13/15 0.00 0 0 10/3/15 1.00 0 0
6/24/15 0.00 0 0 8/14/15 0.00 0 9,000 10/4/15 0.00 0 0
6/25/15 0.00 0 0 8/15/15 0.70 0 0 10/5/15 1.25 0 0
6/26/15 0.00 0 21,000 8/16/15 0.00 0 0 10/6/15 0.00 0 0
6/27/15 1.50 0 0 8/17/15 0.25 0 0 10/7/15 0.00 0 0
6/28/15 0.00 0 0 8/18/15 0.20 0 15,000 10/8/15 0.00 0 0
6/29/15 1.50 0 12,000 8/19/15 0.00 0 0 10/9/15 0.00 0 0
6/30/15 0.00 0 0 8/20/15 0.10 0 0 10/10/15 0.30 0 0
7/1/15 0.00 0 0 8/21/15 0.00 0 0 10/11/15 0.00 0 0
7/2/15 0.00 0 9,000 8/22/15 0.00 0 0 10/12/15 0.00 0 0
Date
Rainfall
(In)
WWTPs
(gal)
WWTPs
(gal)
Recirculated
into Landfill
(gal)Date
Recirculated
into Landfill
(gal)Date
Rainfall
(In)
Recirculated
into Landfill
(gal)
494,990
Date
Rainfall
(In)
WWTPs
(gal)
Recirculated
into Landfill
(gal)
Rainfall
(In)
WWTPs
(gal)
Ashe County Subtitle D Lined Landfill Page 1 of 1
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273353
92273353
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. LEACHATE
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Lab ID Sample ID Matrix Date Collected Date Received
92273353001 LAGOON Water 10/23/15 11:50 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273353001 LAGOON EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
EPA 300.0 1 PASI-AMDW
EPA 365.1 1 PASI-ASER
SM 5220D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Sample:LAGOON Lab ID:92273353001 Collected:10/23/15 11:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:59 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:59 7440-38-210/28/15 19:0010.0 2.5 1
Barium 141 ug/L 11/04/15 19:59 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:59 7440-41-710/28/15 19:001.0 0.50 1
Cadmium 1.2 ug/L 11/04/15 19:59 7440-43-910/28/15 19:001.0 0.50 1
Chromium 3.3J ug/L 11/04/15 19:59 7440-47-3 B10/28/15 19:0010.0 2.5 1
Cobalt 2.7J ug/L 11/04/15 19:59 7440-48-410/28/15 19:0010.0 2.5 1
Copper 4.6J ug/L 11/04/15 19:59 7440-50-8 B10/28/15 19:0010.0 2.5 1
Lead 5.5J ug/L 11/04/15 19:59 7439-92-110/28/15 19:0010.0 2.5 1
Nickel 3.1J ug/L 11/04/15 19:59 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:59 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:59 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:59 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:59 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 6.7J ug/L 11/04/15 19:59 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 15.6J ug/L 11/01/15 06:45 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 06:45 107-13-12001.9 1
Benzene 9.3 ug/L 11/01/15 06:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 06:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 06:45 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 06:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 06:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 06:45 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 06:45 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 06:45 56-23-51.0 0.25 1
Chlorobenzene 1.5J ug/L 11/01/15 06:45 108-90-73.0 0.23 1
Chloroethane 2.4J ug/L 11/01/15 06:45 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 06:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 06:45 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 06:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 06:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 06:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 06:45 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 06:45 95-50-15.0 0.30 1
1,4-Dichlorobenzene 3.5 ug/L 11/01/15 06:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 06:45 110-57-61001.0 1
1,1-Dichloroethane 0.42J ug/L 11/01/15 06:45 75-34-35.0 0.32 1
1,2-Dichloroethane 1.1 ug/L 11/01/15 06:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 06:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 1.9J ug/L 11/01/15 06:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 06:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 06:45 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 06:45 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 06:45 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Sample:LAGOON Lab ID:92273353001 Collected:10/23/15 11:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 06:45 10061-02-61.0 0.26 1
Ethylbenzene 18.4 ug/L 11/01/15 06:45 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 06:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 06:45 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 06:45 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)0.34J ug/L 11/01/15 06:45 108-10-11000.33 1
Styrene ND ug/L 11/01/15 06:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 06:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 06:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 06:45 127-18-41.0 0.46 1
Toluene 3.7 ug/L 11/01/15 06:45 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 06:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 06:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 06:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 06:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 06:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 06:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 06:45 75-01-41.0 0.62 1
Xylene (Total)21.7 ug/L 11/01/15 06:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %11/01/15 06:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %11/01/15 06:45 17060-07-070-130 1
Toluene-d8 (S)101 %11/01/15 06:45 2037-26-570-130 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 2310J ug/L 11/02/15 18:44 14808-79-825000010001
Analytical Method: EPA 365.1365.1 Phosphorus, Total
Phosphorus 127 ug/L 11/03/15 03:48 7723-14-050.0 25.0 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 270000 ug/L 10/29/15 13:4025000125001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273353001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34087
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273353001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596344
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:300.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:300.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:300.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:300.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:300.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:300.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:300.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:302.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:300.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:300.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:300.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:300.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:300.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:300.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:300.96
2-Hexanone ug/L ND 50.0 11/01/15 00:300.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:300.33
Acetone ug/L ND 100 11/01/15 00:3010.0
Acrylonitrile ug/L ND 200 11/01/15 00:301.9
Benzene ug/L ND 1.0 11/01/15 00:300.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:300.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:300.18
Bromoform ug/L ND 3.0 11/01/15 00:300.26
Bromomethane ug/L ND 10.0 11/01/15 00:300.29
Carbon disulfide ug/L ND 100 11/01/15 00:301.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:300.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:300.23
Chloroethane ug/L ND 10.0 11/01/15 00:300.54
Chloroform ug/L ND 5.0 11/01/15 00:300.14
Chloromethane ug/L ND 1.0 11/01/15 00:300.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:300.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:300.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:300.21
Dibromomethane ug/L ND 10.0 11/01/15 00:300.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:300.30
Iodomethane ug/L ND 10.0 11/01/15 00:300.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:300.97
Styrene ug/L ND 1.0 11/01/15 00:300.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:300.46
Toluene ug/L ND 1.0 11/01/15 00:300.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:300.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Huntersville, NC 28078
[phone]
Page 9 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596344
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:300.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:301.0
Trichloroethene ug/L ND 1.0 11/01/15 00:300.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:300.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:300.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:300.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:300.66
1,2-Dichloroethane-d4 (S)%101 70-130 11/01/15 00:30
4-Bromofluorobenzene (S)%100 70-130 11/01/15 00:30
Toluene-d8 (S)%101 70-130 11/01/15 00:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596345LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 53.250 106 71-129
1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124
1,1,2-Trichloroethane ug/L 48.250 96 85-125
1,1-Dichloroethane ug/L 52.350 105 73-126
1,1-Dichloroethene ug/L 55.250 110 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.450 101 71-133
1,2-Dibromoethane (EDB)ug/L 50.750 101 83-124
1,2-Dichlorobenzene ug/L 50.750 101 80-133
1,2-Dichloroethane ug/L 45.950 92 67-128
1,2-Dichloropropane ug/L 49.850 100 75-132
1,3-Dichloropropane ug/L 50.350 101 76-131
1,4-Dichlorobenzene ug/L 49.550 99 78-130
2-Butanone (MEK)ug/L 98.6J100 99 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 97.6J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 51.350 103 80-125
Bromochloromethane ug/L 53.050 106 71-125
Bromodichloromethane ug/L 52.650 105 78-124
Bromoform ug/L 50.250 100 71-128
Bromomethane ug/L 48.950 98 40-160
Carbon disulfide ug/L 53.4J50 107 50-160
Carbon tetrachloride ug/L 54.150 108 69-131
Chlorobenzene ug/L 49.150 98 81-122
Chloroethane ug/L 48.650 97 39-148
Chloroform ug/L 51.750 103 73-127
Chloromethane ug/L 50.650 101 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Huntersville, NC 28078
[phone]
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596345LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 50.150 100 74-124
cis-1,3-Dichloropropene ug/L 50.650 101 72-132
Dibromochloromethane ug/L 51.850 104 78-125
Dibromomethane ug/L 49.950 100 82-120
Ethylbenzene ug/L 50.350 101 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 54.550 109 64-133
Styrene ug/L 51.050 102 84-126
Tetrachloroethene ug/L 50.550 101 78-122
Toluene ug/L 50.650 101 80-121
trans-1,2-Dichloroethene ug/L 52.050 104 71-127
trans-1,3-Dichloropropene ug/L 50.450 101 69-141
trans-1,4-Dichloro-2-butene ug/L 61.0J50 122 40-160
Trichloroethene ug/L 48.650 97 78-122
Trichlorofluoromethane ug/L 52.850 106 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 59.450 119 58-137
Xylene (Total)ug/L 151150 101 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596346MATRIX SPIKE SAMPLE:
MSSpike
Result
92273348002
1,1,1,2-Tetrachloroethane ug/L 21.020 105 70-130ND
1,1,1-Trichloroethane ug/L 24.320 121 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.720 108 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 23.620 118 70-130ND
1,1-Dichloroethene ug/L 25.720 128 70-166ND
1,2,3-Trichloropropane ug/L 20.720 104 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.520 103 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.320 107 70-130ND
1,2-Dichlorobenzene ug/L 21.920 109 70-130ND
1,2-Dichloroethane ug/L 20.020 99 70-130ND
1,2-Dichloropropane ug/L 21.620 108 70-130ND
1,3-Dichloropropane ug/L 21.520 107 70-130ND
1,4-Dichlorobenzene ug/L 21.820 109 70-130ND
2-Butanone (MEK)ug/L 43.4J40 108 70-130ND
2-Hexanone ug/L 44.3J40 111 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 43.6J40 109 70-130ND
Acetone ug/L 48.6J40 115 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 22.620 113 70-148ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596346MATRIX SPIKE SAMPLE:
MSSpike
Result
92273348002
Bromochloromethane ug/L 23.620 118 70-130ND
Bromodichloromethane ug/L 21.720 109 70-130ND
Bromoform ug/L 18.920 95 70-130ND
Bromomethane ug/L 19.920 99 70-130ND
Carbon disulfide ug/L 23.8J20 119 70-130ND
Carbon tetrachloride ug/L 23.920 119 70-130ND
Chlorobenzene ug/L 21.920 109 70-146ND
Chloroethane ug/L 23.520 118 70-130ND
Chloroform ug/L 23.020 115 70-130ND
Chloromethane ug/L 24.220 121 70-130ND
cis-1,2-Dichloroethene ug/L 22.520 112 70-130ND
cis-1,3-Dichloropropene ug/L 20.220 101 70-130ND
Dibromochloromethane ug/L 20.720 103 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.320 112 70-130ND
Iodomethane ug/L 41.140 103 70-130ND
Methylene Chloride ug/L 23.120 115 70-130ND
Styrene ug/L 20.420 102 70-130ND
Tetrachloroethene ug/L 22.820 114 70-130ND
Toluene ug/L 21.920 110 70-155ND
trans-1,2-Dichloroethene ug/L 23.620 118 70-130ND
trans-1,3-Dichloropropene ug/L 19.720 99 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.9J20 85 70-130ND
Trichloroethene ug/L 21.520 107 69-151ND
Trichlorofluoromethane ug/L 25.320 126 70-130ND
Vinyl acetate ug/L 37.5J40 94 70-130ND
Vinyl chloride ug/L 27.4 M12013770-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273348003
1596347SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273348003
1596347SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 1101
4-Bromofluorobenzene (S)%98 199
Toluene-d8 (S)%99 1100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25173
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92273353001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594547
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 11/02/15 12:371000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594548LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19300J20000 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594549MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273828001
1594550
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 103 90-110103 0 10200002.7 mg/L 23300J 23400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273828002
1594552
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 106 90-110107 1 10200005.6 mg/L 26700J 27000J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25184
EPA 365.1
EPA 365.1
365.1 Phosphorus, Total
Associated Lab Samples:92273353001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595324
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
Phosphorus ug/L ND 50.0 11/03/15 03:3325.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595325LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus ug/L 25002500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1595326MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92272773001
1595327
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 100 90-110101 1 1025000.70 mg/L 3210 3220
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1595328MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273203004
1595329
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L M1250011490-110108 2 1025006.4 mg/L 9230 9090
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/25178
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92273353001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594813
Associated Lab Samples:92273353001
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 10/29/15 13:4012500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594814LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 726000750000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594815MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273906001
1594816
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 96 90-11096 0 375000096.0 mg/L 816000 816000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594817MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273906002
1594818
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M17500008690-11086 0 3750000137 mg/L 782000 782000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273353
ASHE CO. LEACHATE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273353001 MPRP/19918 ICP/17958LAGOONEPA 3010 EPA 6010
92273353001 MSV/34087LAGOONEPA 8260
92273353001 WETA/25173LAGOONEPA 300.0
92273353001 WETA/25184LAGOONEPA 365.1
92273353001 WETA/25178LAGOONSM 5220D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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