0501_AsheCoMSWLF_Oct2015GWMR_DIN27412_20151021

Ashe County Closed Unlined Landfill
Crumpler, North Carolina
October 2015
MESCO Project Number: G15004.0
Semi-Annual Water Quality Monitoring Report
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
Permit Number: 05-01
P.O. Box 97
Garner, NC 27529
License No. C-0281

TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedures Page 2
Field Parameter Data Page 2
Laboratory Results Page 2
Quality Control Samples Page 2
Groundwater Samples Page 2
Surface Water Samples Page 3
Groundwater and Surfacewater Characterization Page 3
Findings Page 3
Closing Page 3
FIGURES
Topographic Map with Site Location Figure 1
Single-Event Potentiometric Map of Uppermost Aquifer Figure 2

TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Detections Above SWSL, GWP, 2L, or 2B (Appendix 1) Table 5
Hydrologic Properties at Monitoring Well Locations Table 6
APPENDICIES
Laboratory Analysis Report and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
March 8, 2016
Mr. Ervin Lane
Solid Waste Section
Division of Waste Management
North Carolina Department of EnvironmentDO4XDOLW\
:-RQHV6W
Raleigh, NC 2760
Re: Semi-Annual Water Quality Monitoring Report
Ashe County Closed Unlined Landfill
MESC0 Project No. G15004.0
Permit No. 05-01
Event Date(s):October 21-23, 2015
Dear Mr. Lane:
Introduction
On behalf of Ashe County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this
Semi-Annual Water Quality Report for the fall 2015 event performed at the Ashe County Closed Unlined Landfill.
NCDENR Solid Waste Rules 15A NCAC 13B.0601 requires that Ashe County provide this report to the SWS on a
semi-annual basis. This report documents the quality of the ground and surface waters during this monitoring event
performed on October 21-23, 2015. During this event, volatile organic compounds (VOCs) in concentrations above
the North Carolina groundwater (2L) Standard and Solid Waste Section Limit (SWSL) were detected in samples
collected from the areas north (MW-14), east (P-1, MW-27, P3-1), south-central (MW-21), south-west (MW-16,
MW-17) and west (MW-4, MW-26D) of the closed landfill. Constituents were not detected in any surface water
sample in levels above the applicable North Carolina surface water (2B) Standard.
Background
The Ashe County Closed Unlined Landfill (05-01) is located at 739 Fred Pugh Road Crumpler, NC. The site
location topographic map is depicted in the attached Figure 1.
The water quality monitoring program includes sampling locations as outlined in the approved Sampling and
Analysis Plan (SAP) contained in the facility Transition Plan dated November 1995 as well as additional monitoring
piezometers/well added in the Ridgeline Assessment Summary report dated November 2007. Water quality
monitoring has been performed semi-annually and data compared to all known historical data compiled since 1992.
Active remediation of the groundwater east of the landfill through injection of hydrogen releasing compounds
(HRC) into P3-15 in March 2008 and (P-13S, P3-14, P3-16, P3-17, HRCM-17, HRCI-1, HRCI-2 HRCI-3, HRCI-7,
HRCI-12 and HRCM-17) occurred in November 2008.
As specified within 15A NCAC 13B.1632(i), SWS Environmental Monitoring Report Form, and a recent SWS
issued memorandum, this report contains sampling procedures, field and laboratory results, groundwater and surface
water characterization, and findings. Well construction summary table, field observations table, field parameter data
table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow
directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data
results are enclosed herein.

Sampling Procedure
Municipal Engineering Services Company, P.A. (MESCO) personnel performed this sampling event utilizing
portable monitoring methodology in accordance with the site-specific approved SAP. Monitoring locations are
shown upon the enclosed potentiometric map Figure 2. All monitoring locations listed within the SAPs were
sampled during this event with the exception of MW-3 which was dry and P-13S which would not yield a
representative sample since it was previously utilized as a remediation injection well.
This sampling event consisted of collection of water samples from 18 groundwater monitoring wells/piezometers
(MW-4, MW-5, MW-6, MW-8, MW-14, MW-16, MW-17, MW-18, MW-19, MW-20, MW-21, MW-23, MW-26,
MW-26D, MW-27, P-1, P3-1 and P-12), six surface water locations (SW-B, SW-2, SW-2A, SW-3, SW-4 and SW-5)
and the on-site potable water supply well (WSW-2). Quality control measures implemented during this event
included submittal and subsequent quantification of equipment blanks (EB), field blanks (FB) and travel blanks (TB).
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and
integrity of all monitoring locations were visually evaluated with no improvements needed as documented on Table
2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level
elevation. Low flow pumping methodology or baling was utilized to purge the wells to a minimum of three times the
volume of standing water in the well or to dryness. During purging, stabilized field parameters were recorded. The
samples were then immediately placed into laboratory-prepared pre-preserved containers via a new disposable
polyethylene bailer. Samples were collected/separated based upon likelihood of potential cross-contamination, kept
upon ice, and transported to a NC-certified laboratory under proper C-O-C protocol within the specified hold times
for each analysis.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
total dissolved solids (TDS), and turbidity. A summary of the field parameter data is presented in Table 3 and the
field sampling data sheet is enclosed in Appendix B. The field parameter data appears to be generally consistent
relative to each other and congruent with historically reported data.
Laboratory Results
All of the groundwater and surface water samples were analyzed for the 40 CFR 258 Appendix I list of constituents.
The 47 targeted vocs were analyzed by Pace Analytical Laboratory (PACE) of Huntersville NC and 15 total metals
were tested by Pace in Asheville NC. A table summarizing the locations, constituents, and methods is presented on
Table 4. Laboratory results and C-O-Cs are presented in Appendix A.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below
the current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and
surface water samples that attain or were above the current SWSL, Groundwater Protection Standards (GWP), North
Carolina Groundwater Standards (2L), the applicable North Carolina Surface Water Standards (2B) for a class C
waterbody and Maximum Contaminant Levels (MCL) also known as “Federal Primary Drinking Water Standards”.
Quality Control Samples
The quality control samples EB, FB and TB did not contain any constituents above MDL. Therefore the data set
appears to not be affected by false positives or high bias attributed to laboratory or field induced artifact
contamination.
Groundwater Samples
One or more VOC(s) were detected in concentrations above the SWSL and in exceedance of their respective 2L
Standard in 56% (10 of 18) of the groundwater samples. The VOC exceedances generally consisted of a mixture of
dissolved aromatics (fuel hydrocarbons) and chlorinated aliphatic hydrocarbons (chlorinated solvents) in samples
collected from the areas north (MW-14), east (P-1, MW-27, P3-1), south-central (MW-21), southeast (MW-6) and
west (MW-4, MW-26D) of the closed MSWLF. The area southeast of the landfill (MW-16, MW-17) contained only
benzene exceedances.
The only metal detected above their respective 2L Standard was total barium in samples MW-14, MW-16, MW-17,
MW-21, MW-26D and P-1.
2
Figures
Topographic Map with Site Location
FIGURE 1NOTE: Topographic map assembled from the
Jefferson NC, Laurel Springs NC, Grassy Creek NC-VA, and Mouth of Wilson NC-VA USGS 7.5-min. quadrangles.
ASHE COUNTY LANDFILL FACILITY
Ashe County Closed Unlined MSWLF
Ashe County Active Subtitle D Lined MSWLF, Phases 1, 2 & 4
739 Fred Pugh Road
Crumpler, NC 28617
Lat:36-31-06.1639
Long:-81-21-59.3447
Northing:1015914.08
Easting:1304557.23
Tables
Ashe County Closed Unlined MSWLF Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
October 21-22, 2015
Latitude Longitude
(inches)(ft)
MW-3 09/19/91 2 68.97 53.97 15 Weathered rock 2832.59 2831.19 <2762.22 >70.37 36.518608 -81.366553
MW-4 09/19/91 2 25.50 10.5 15 2744.49 2743.04 2725.59 18.90 36.502533 -81.369544
MW-5 09/20/91 2 33.50 18.5 15 ?2724.52 2723.60 2700.78 23.74 36.516111 -81.370353
MW-6 09/20/91 2 69.00 54 15 ?2724.97 2723.65 2699.48 25.49 36.532800 -81.370333
MW-8 ?4 32.6 ???2734.82 2733.62 2725.34 9.48 36.516778 -81.370694
MW-14 12/02/92 2 50.50 40.5 10 2759.95 2758.05 2711.80 48.15 36.520444 -81.370161
MW-16 12/08/92 2 26.5 11.5 10 ?2720.93 2718.88 2700.26 20.67 36.516039 -81.370569
MW-17 07/20/95 2 43 33 10 Rock 2719.51 2717.79 2699.90 19.61 36.516053 -81.370544
MW-18 06/14/95 2 61 46 15 Rock 2837.24 2835.34 2778.09 59.15 36.517569 -81.366261
MW-19 07/07/95 2 76.5 67.5 9 Rock 2837.05 2835.03 2777.97 59.08 36.517589 -81.366264
MW-20 05/07/95 2 48 33 15 2798.10 2796.36 2756.80 41.30 36.517328 -81.366747
MW-21 05/06/95 2 46 26 20 2782.49 2780.6 2751.37 31.12 36.516908 -81.367856
MW-26 07/26/95 2 21.5 6.5 15 2732.14 2729.84 2722.74 9.40 36.519200 -81.369797
MW-26D 11/10/98 2 50 40 10 2732.19 2729.85 2720.86 11.33 36.519200 -81.369797
MW-22 07/24/95 2 25 10 15 Rock 2700.62 2698.84 2694.93 5.69 36.515253 -81.369914
MW-23 07/25/95 2 21 6 15 2661.53 2659.8 2650.79 10.74 36.514036 -81.369553
MW-24 07/17/95 2 21 6 15 Rock 2693.95 2691.97 2684.90 9.05 36.515436 -81.371167
MW-27 10/12/07 2 65.32 50.32 15 PWR 2799.78 2796.78 2737.46 62.32 36.519814 -81.368642
P-12 10/30/97 2 27 22 5 ?2736.04 2733.26 2726.09 9.95 36.520350 -81.368506
P-4S 11/12/97 1 62.5 57.5 5 Rock 2782.88 2781.01 2721.74 61.14 36.520619 -81.369556
P-4D 11/13/97 1 79.5 77.5 2 Rock 2782.47 2780.79 2716.35 66.12 36.520619 -81.369556
P3-1 06/19/04 2 72.48 57.48 15 PWR 2800.22 2797.22 2738.87 61.35 36.519636 -81.368453
P-1 05/03/95 2 74 59 15 2835.04 2833.66 2764.59 70.45 36.518133 -81.383156
NOTE:
? = Unknown since records not located
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well Depth
Top of
Screen Depth
Screen
Length Geology of
Screened
Interval
Top of
Casing Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
saprolite/rock
saprolite/rock
Saprolite
Saprolite
saprolite/rock
saprolite/rock
Saprolite
Saprolite
bgs = below ground surface
amsl= above mean sea level
btoc = below top of casing (PVC well casing)
Ashe County Closed Unlined MSWLF Page 1 of 1
Table 2
Field Observations of Monitoring Locations
October 21-22, 2015
Locked Comments
MW-3 No Yes Yes Yes Yes Yes Dry no sample which is common
MW-4 Yes Yes Yes Yes Yes Yes NP
MW-5 Yes Yes Yes Yes Yes Yes NP
MW-6 Yes Yes Yes Yes Yes Yes NP
MW-8 Yes Yes Yes Yes Yes Yes NC & NP
MW-14 Yes Yes Yes Yes Yes Yes NP
MW-16 Yes Yes Yes Yes Yes Yes NP
MW-17 Yes Yes Yes Yes Yes Yes NP
MW-18 Yes Yes Yes Yes Yes Yes NP
MW-19 Yes Yes Yes Yes Yes Yes PC
MW-20 Yes Yes Yes Yes Yes Yes PC, Recharge faster than normal
MW-21 Yes Yes Yes Yes Yes Yes
MW-22 Yes Yes Yes Yes Yes Yes
MW-23 Yes Yes Yes Yes Yes Yes
MW-24 Yes Yes Yes Yes Yes Yes
MW-26 Yes Yes Yes Yes Yes Yes PC
MW-26D Yes Yes Yes Yes Yes Yes PC
MW-27 Yes Yes Yes Yes Yes Yes
P3-1 Yes Yes Yes Yes Yes Purge water NOT viscous (See below)
P-1 Yes Yes Yes Yes Yes Yes
P-12 Yes Yes Yes Yes Yes Yes
WSW-2 Yes Yes Yes Sample from shop bathroom sink typical
UDP Yes -----Effluent clear. No evidence of contamination
SW-B Yes -----Low seasonal gage & flow
SW-2 Yes -----Low seasonal gage & flow
SW-2A Yes -----Low seasonal gage & flow
SW-3 Yes -----Low seasonal gage & flow
SW-4 Yes -----Low seasonal gage & flow
SW-5 Yes -----Low seasonal gage & flow
Any unusual field conditions, observations, or events:
NP = New concrete Pad poured around well by County since May 2014.
PC = Pad cleared of sediment by County since May 2014.
NC = New steel locking case installed by County around MW-8 since May 2014.
P3-1 purge water not viscous. This is different than previous events. Maybe evidence that the HRC injected into HRCI-3 in November 2008 has migrated beyond P3-1.
Waterline between WSW-2 and the sample location has been leaking for 3 days leading up to sample date. Possible that data may be impacted.
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Appears
Effective
na
na na na
Ashe County Closed Unlined MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
October 21-22, 2015
Parameter Temp.ORP DO pH TDS
Units C mg/L SU mg/L Visual
MW-3 >70.37 <2762.22 2832.59 NR NR NR NR NR NR
MW-4 18.90 2725.59 2744.49 11.9 NR NR 6.38 20 10 Moderate
MW-5 23.74 2700.78 2724.52 10.8 NR NR 6.61 280 190 Clear
MW-6 25.49 2699.48 2724.97 11.6 NR NR 6.83 1900 1320 Clear
MW-8 9.48 2725.34 2734.82 11.8 NR NR 7.03 90 40 Clear
MW-14 48.15 2711.80 2759.95 12.1 NR NR 6.29 180 80 Slight
MW-16 20.67 2700.26 2720.93 11.3 NR NR 6.96 1070 750 Clear
MW-17 19.61 2699.9 2719.51 11.6 NR NR 6.49 1120 770 Clear
MW-18 59.15 2778.09 2837.24 12.1 NR NR 6.83 630 310 Clear
MW-19 59.08 2777.97 2837.05 12.8 NR NR 6.31 390 150 Clear
MW-20 41.30 2756.8 2798.10 12.7 NR NR 7.01 200 90 Slight
MW-21 31.12 2751.37 2782.49 11.8 NR NR 5.35 360 250 Clear
MW-23 10.74 2650.79 2661.53 12.9 NR NR 6.44 390 150 Clear
MW-26 9.40 2722.74 2732.14 12.5 NR NR 6.99 410 200 Clear
MW-26D 11.33 2720.86 2732.19 12.9 NR NR 7.11 1420 700 Slight
MW-27 62.32 2737.56 2799.88 12.5 NR NR 6.53 470 230 Clear
P3-1 61.35 2729.77 2800.22 12.5 NR NR 7.01 130 60 Clear
P-1 70.45 2764.59 2835.04 11.8 NR NR 7.31 190 90 Clear
P-12 9.95 2726.09 2736.04 12.4 NR NR 6.89 120 50 Clear
WSW-2 NR 14.6 NR NR 7.02 210 90 Clear
Minimum 9.40 2650.79 2661.53 10.8 NR NR 5.35 20 10 Clear
Average 32.90 2726.65 2763.88 12.2 NR NR 6.70 504 291 Slight
Maximum 70.45 2778.09 2837.24 14.6 NR NR 7.31 1900 1320 Moderate
SW-2 ---11.9 NR NR 7.06 230 190 Clear
SW-2A ---12.3 NR NR 6.89 810 380 Clear
SW-3 ---12.3 NR NR 6.99 650 650 Clear
SW-4 ---11.7 NR NR 6.88 230 180 Clear
SW-5 ---11.3 NR NR 7.02 200 90 Clear
SW-B ---12.2 NR NR 7.01 190 190 Clear
Minimum ---11.3 NR NR 6.88 190 90 Clear
Average ---12.0 NR NR 6.98 385 280 Clear
Maximum ---12.3 NR NR 7.06 810 650 Clear
NR = No Reading Attempted
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
Turbidity
of Metal
Sample
ft (btoc)ft (amsl)ft (amsl)mV umhos/cm
na
na na
btoc = Below top of casing (PVC well casing)
amsl = Above mean sea level
na = Not Available
Ashe County Closed Unlined MSWLF Page 1 of 1
Table 4
Sampling and Analysis Summary
October 21-22, 2015
Field Parameters
Re
a
s
o
n

N
o
t

S
a
m
p
l
e
d
To
t
a
l

M
e
t
a
l
s

Te
m
p
e
r
a
t
u
r
e
Co
n
d
u
c
t
i
v
i
t
y
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s

(
T
D
S
)
pH Tu
r
b
i
d
i
t
y
La
b

E
P
A

8
2
6
0
B
L
a
b

E
P
A

6
0
0
0
/
7
0
0
0
Fi
e
l
d

M
e
t
e
r
Fi
e
l
d

M
e
t
e
r
Fi
e
l
d

M
e
t
e
r
Fi
e
l
d

M
e
t
e
r
Fi
e
l
d

V
i
s
u
a
l
MW-3 Dry
MW-4 x x x x x x x
MW-5 x x x x x x x
MW-6 x x x x x x x
MW-8 x x x x x x x
MW-14 x x x x x x x
MW-16 x x x x x x x
MW-17 x x x x x x x
MW-18 x x x x x x x
MW-19 x x x x x x x
MW-20 x x x x x x x
MW-21 x x x x x x x
MW-23 x x x x x x x
MW-26 x x x x x x x
MW-26D x x x x x x x
MW-27 x x x x x x x
P3-1 x x x x x x x
P-1 x x x x x x x
P-12 x x x x x x x
WSW-2 x x x x x x x
SW-2 x x x x x x x
SW-2A x x x x x x x
SW-3 x x x x x x x
SW-4 x x x x x x x
SW-5 x x x x x x x
SW-B x x x x x x x
UDP x x x x x x x
EB x x
FB x x
TB x
Appendix I = List from current 40 CFR 258
App. I
V OC
s
Ashe County Closed Unlined MSWLF Page 1 of 3
Table 5
Detections in Water Samples above SWSL, GWP, 2L or 2B (Appendix I)
October 21-23, 2015
Result Unit
MW-4 10/21/15 13 0.32 5 6 7 L &/or LFG
MW-4 Benzene 10/21/15 1.9 0.25 1 1 5 L &/or LFG
MW-4 Vinyl chloride 10/21/15 1.3 0.62 1 0.03 5 L &/or LFG
MW-4 10/21/15 15.5 0.54 10 3000 NE
MW-4 Barium, total 10/21/15 309 2.5 100 700 1300
MW-4 10/21/15 1.2 0.33 1 6 75
MW-4 Cobalt, total 10/21/15 13.1 2.5 10 NE 1 NE
MW-5 Barium, total 10/21/15 261 2.5 100 700 1300
MW-5 10/21/15 1.1 0.33 1 6 75
MW-6 10/21/15 0.88J 0.27 1 0.6 5 L &/or LFG
MW-6 Benzene 10/21/15 6.6 0.25 1 1 5 L &/or LFG
MW-6 Barium, total 10/21/15 1640 2.5 100 700 1300 N
MW-6 Antimony, total 10/21/15 6.2 3.8 6 NE 1 NE
MW-6 10/21/15 4.2 0.3 1 600 NE
MW-6 Vanadium, total 10/21/15 5J 2.5 25 NE 0.3 NE
MW-6 Cobalt, total 10/21/15 26.1 2.5 10 NE 1 NE
MW-6 10/21/15 4.1 0.33 1 6 75
MW14 Benzene 10/23/15 1.1 0.25 1 1 5 L &/or LFG
MW14 Vinyl chloride 10/23/15 0.86J 0.62 1 0.03 5 L &/or LFG
MW14 Barium, total 10/23/15 1770 2.5 100 700 1300 N
MW-16 Benzene 10/21/15 1.9 0.25 1 1 5 L &/or LFG
MW-16 Barium, total 10/21/15 1100 2.5 100 700 1300 N
MW-16 Cobalt, total 10/21/15 15.6 2.5 10 NE 1 NE
MW-16 10/21/15 4.5 0.33 1 6 75
MW-16 Vanadium, total 10/21/15 6.4J 2.5 25 NE 0.3 NE
MW-17 Benzene 10/21/15 2 0.25 1 1 5 L &/or LFG
MW-17 Barium, total 10/21/15 1300 2.5 100 700 1300 N
MW-17 Cobalt, total 10/21/15 17.1 2.5 10 NE 1 NE
MW-17 Antimony, total 10/21/15 3.8J 3.8 6 NE 1 NE
MW-17 Vanadium, total 10/21/15 13.7J 2.5 25 NE 0.3 NE
MW-17 10/21/15 4.8 0.33 1 6 75
MW-18 Zinc, total 10/21/15 11.9 5 10 1000 5000
MW-18 Cobalt, total 10/21/15 10.7 2.5 10 NE 1 NE
MW-18 Barium, total 10/21/15 224 2.5 100 700 1300
MW-18 Cadmium, total 10/21/15 1.2 0.5 1 2 5
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
1,1-Dichloroethane ug/L
ug/L
ug/L
Chloroethane ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
1,2-Dichloropropane ug/L
ug/L
ug/L
ug/L
Ethylbenzene ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
Ashe County Closed Unlined MSWLF Page 2 of 3
Result UnitSample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
MW-19 Zinc, total 10/21/15 15.9 5 10 1000 5000
MW-19 Barium, total 10/21/15 294 2.5 100 700 1300
MW-19 Cadmium, total 10/21/15 1.1 0.5 1 2 5
MW-20 Vinyl chloride 10/21/15 0.68J 0.62 1 0.03 5 L &/or LFG
MW-20 Cobalt, total 10/21/15 17.3 2.5 10 NE 1 NE
MW-20 10/21/15 1.2 0.33 1 6 75
MW-20 Barium, total 10/21/15 567 2.5 100 700 1300
MW-21 Vinyl chloride 10/21/15 1.7 0.62 1 0.03 5 L &/or LFG
MW-21 Benzene 10/21/15 2 0.25 1 1 5 L &/or LFG
MW-21 10/21/15 2.5 0.46 1 0.07 5 L &/or LFG
MW-21 Barium, total 10/21/15 1430 2.5 100 700 1300 N
MW-21 10/21/15 2.4 0.47 1 3 5
MW-21 Zinc, total 10/21/15 14.3 5 10 1000 5000
MW-21 Vanadium, total 10/21/15 5J 2.5 25 NE 0.3 NE
MW-21 Cobalt, total 10/21/15 58 2.5 10 NE 1 NE
MW-26 Vanadium, total 10/22/15 5.1J 2.5 25 NE 0.3 NE
MW-26D Benzene 10/22/15 4.2 0.25 1 1 5 L &/or LFG
MW-26D 10/22/15 9.6 0.32 5 6 7 L &/or LFG
MW-26D Barium, total 10/22/15 837 2.5 100 700 1300 N
MW-26D Chromium, total 10/22/15 3.4J (B)2.5 10 10 100
MW-26D 10/22/15 20.1 0.54 10 3000 NE
MW-26D Vanadium, total 10/22/15 5.9J 2.5 25 NE 0.3 NE
MW-26D Cobalt, total 10/22/15 11.7 2.5 10 NE 1 NE
MW-26D 10/22/15 3.8 0.33 1 6 75
MW-27 Benzene 10/22/15 3.7 0.25 1 1 5 L &/or LFG
MW-27 10/22/15 33.7 0.32 5 6 7 L &/or LFG
MW-27 Vinyl chloride 10/22/15 4.5 0.62 1 0.03 5 L &/or LFG
MW-27 Cobalt, total 10/22/15 26.2 2.5 10 NE 1 NE
MW-27 10/22/15 1.3 0.33 1 6 75
MW-27 Barium, total 10/22/15 316 2.5 100 700 1300
MW-27 Vanadium, total 10/22/15 4.1J 2.5 25 NE 0.3 NE
MW-27 10/22/15 38.3 0.19 5 70 70
P-1 Vinyl chloride 10/21/15 4.9 0.62 1 0.03 5 L &/or LFG
P-1 10/21/15 6.8 0.27 1 0.6 5 L &/or LFG
P-1 10/21/15 11 0.33 1 6 75 L &/or LFG
P-1 Benzene 10/21/15 1.1 0.25 1 1 5 L &/or LFG
P-1 Barium, total 10/21/15 1400 2.5 100 700 1300 N
P-1 Cobalt, total 10/21/15 36.9 2.5 10 NE 1 NE
P-1 Vanadium, total 10/21/15 3.6J 2.5 25 NE 0.3 NE
P-12 10/22/15 0.72J 0.46 1 0.07 5 L &/or LFG
ug/L
ug/L
ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
Tetrachloroethene ug/L
ug/L
Trichloroethene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1,1-Dichloroethane ug/L
ug/L
ug/L
Chloroethane ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
1,1-Dichloroethane ug/L
ug/L
ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
cis-1,2-Dichloroethene ug/L
ug/L
1,2-Dichloropropane ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
Tetrachloroethene ug/L
Ashe County Closed Unlined MSWLF Page 3 of 3
Result UnitSample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary
Cause 8
P3-1 Vinyl chloride 10/22/15 2.8 0.62 1 0.03 5 L &/or LFG
P3-1 10/22/15 0.42J 0.24 1 0.4 5 L &/or LFG
P3-1 10/22/15 60.1 0.32 5 6 7 L &/or LFG
P3-1 Benzene 10/22/15 6.7 0.25 1 1 5 L &/or LFG
P3-1 10/22/15 2.1 0.11 1 3 NE
P3-1 10/22/15 2.6 0.33 1 6 75
P3-1 Barium, total 10/22/15 196 2.5 100 700 1300
P3-1 10/22/15 1.1 0.47 1 3 5
P3-1 10/22/15 53.4 0.19 5 70 70
WSW-2 Copper, total 10/23/15 104 2.5 10 1000 NE
WSW-2 Zinc, total 10/23/15 502 5 10 1000 5000
WSW-2 Barium, total 10/23/15 196 2.5 100 700 1300
UDP Barium, total 10/22/15 178 2.5 100 700 200000 1300
SW-4 Barium, total 10/21/15 208 2.5 100 200000 1300
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions
J=The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
(B) = Also detected in associated method Blank and flagged by the laboratory as such. Likely false positive or high bias originating in the laboratory.
N = Natural originating from erosion of natural deposits. Source not anthropogenic.
L = Leachate
LFG = Landfill Gas
BOLD = Concentration > 2L, 2B, GWP or MCL Standard
ug/L
1,2-Dichloroethane ug/L
1,1-Dichloroethane ug/L
ug/L
Chloromethane ug/L
1,4-Dichlorobenzene ug/L
ug/L
Trichloroethene ug/L
cis-1,2-Dichloroethene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, or 2B
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 2B = North Carolina 15 NCAC 2B Surface Water Quality Standard for this Specific Stream Classification
6 GWP = Groundwater Protection Standard
7 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
8 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard.
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273330
92273330
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. CLOSED MSWLF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 43
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 43
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Lab ID Sample ID Matrix Date Collected Date Received
92273330001 MW-23 Water 10/22/15 17:00 10/26/15 12:15
92273330002 MW-26 Water 10/22/15 08:15 10/26/15 12:15
92273330003 MW-26D Water 10/22/15 08:35 10/26/15 12:15
92273330004 P-1 Water 10/21/15 12:25 10/26/15 12:15
92273330005 SW-4 Water 10/21/15 15:50 10/26/15 12:15
92273330006 SW-5 Water 10/21/15 16:35 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 43
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273330001 MW-23 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273330002 MW-26 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273330003 MW-26D EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273330004 P-1 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273330005 SW-4 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273330006 SW-5 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-23 Lab ID:92273330001 Collected:10/22/15 17:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/29/15 00:20 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/29/15 00:20 7440-38-210/28/15 20:0010.0 2.5 1
Barium 37.6J ug/L 10/29/15 00:20 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/29/15 00:20 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/29/15 00:20 7440-43-910/28/15 20:001.0 0.50 1
Chromium 3.2J ug/L 10/29/15 00:20 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/29/15 00:20 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/29/15 00:20 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/29/15 00:20 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/29/15 00:20 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/29/15 00:20 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/29/15 00:20 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/29/15 00:20 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/29/15 00:20 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/29/15 00:20 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 21:26 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 21:26 107-13-12001.9 1
Benzene ND ug/L 10/31/15 21:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 21:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 21:26 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 21:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 21:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 21:26 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 21:26 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 21:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 21:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 21:26 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 21:26 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 21:26 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 21:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 21:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 21:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 21:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 21:26 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/31/15 21:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 21:26 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 21:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 21:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 21:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 21:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 21:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 21:26 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 21:26 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 21:26 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-23 Lab ID:92273330001 Collected:10/22/15 17:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 21:26 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 21:26 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 21:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 21:26 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 21:26 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 21:26 108-10-11000.33 1
Styrene ND ug/L 10/31/15 21:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 21:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 21:26 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 21:26 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 21:26 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 21:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 21:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 21:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 21:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 21:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 21:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 21:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 21:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 21:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 21:26 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 21:26 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-26 Lab ID:92273330002 Collected:10/22/15 08:15 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/29/15 00:23 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/29/15 00:23 7440-38-210/28/15 20:0010.0 2.5 1
Barium 43.9J ug/L 10/29/15 00:23 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/29/15 00:23 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/29/15 00:23 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/29/15 00:23 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/29/15 00:23 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/29/15 00:23 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/29/15 00:23 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/29/15 00:23 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/29/15 00:23 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/29/15 00:23 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/29/15 00:23 7440-28-010/28/15 20:005.5 5.0 1
Vanadium 5.1J ug/L 10/29/15 00:23 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/29/15 00:23 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 21:43 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 21:43 107-13-12001.9 1
Benzene 0.42J ug/L 10/31/15 21:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 21:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 21:43 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 21:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 21:43 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 21:43 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 21:43 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 21:43 56-23-51.0 0.25 1
Chlorobenzene 0.34J ug/L 10/31/15 21:43 108-90-73.0 0.23 1
Chloroethane 4.6J ug/L 10/31/15 21:43 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 21:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 21:43 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 21:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 21:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 21:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 21:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 21:43 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.87J ug/L 10/31/15 21:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 21:43 110-57-61001.0 1
1,1-Dichloroethane 0.63J ug/L 10/31/15 21:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 21:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 21:43 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 21:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 21:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 21:43 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 21:43 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 21:43 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-26 Lab ID:92273330002 Collected:10/22/15 08:15 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 21:43 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 21:43 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 21:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 21:43 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 21:43 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 21:43 108-10-11000.33 1
Styrene ND ug/L 10/31/15 21:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 21:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 21:43 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 21:43 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 21:43 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 21:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 21:43 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 21:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 21:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 21:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 21:43 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 21:43 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 21:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %10/31/15 21:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 21:43 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 21:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-26D Lab ID:92273330003 Collected:10/22/15 08:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:16 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:16 7440-38-210/28/15 19:0010.0 2.5 1
Barium 837 ug/L 11/04/15 19:16 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:16 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:16 7440-43-910/28/15 19:001.0 0.50 1
Chromium 3.4J ug/L 11/04/15 19:16 7440-47-3 B10/28/15 19:0010.0 2.5 1
Cobalt 11.7 ug/L 11/04/15 19:16 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:16 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:16 7439-92-110/28/15 19:0010.0 2.5 1
Nickel 8.4J ug/L 11/04/15 19:16 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:16 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:16 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:16 7440-28-010/28/15 19:005.5 5.0 1
Vanadium 5.9J ug/L 11/04/15 19:16 7440-62-210/28/15 19:0025.0 2.5 1
Zinc ND ug/L 11/04/15 19:16 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 00:47 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 00:47 107-13-12001.9 1
Benzene 4.2 ug/L 11/01/15 00:47 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 00:47 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 00:47 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 00:47 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 00:47 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 00:47 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 00:47 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 00:47 56-23-51.0 0.25 1
Chlorobenzene 1.1J ug/L 11/01/15 00:47 108-90-73.0 0.23 1
Chloroethane 20.1 ug/L 11/01/15 00:47 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 00:47 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 00:47 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 00:47 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 00:47 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 00:47 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 00:47 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.37J ug/L 11/01/15 00:47 95-50-15.0 0.30 1
1,4-Dichlorobenzene 3.8 ug/L 11/01/15 00:47 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 00:47 110-57-61001.0 1
1,1-Dichloroethane 9.6 ug/L 11/01/15 00:47 75-34-35.0 0.32 1
1,2-Dichloroethane 0.35J ug/L 11/01/15 00:47 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 00:47 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.44J ug/L 11/01/15 00:47 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 00:47 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 00:47 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 00:47 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 00:47 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:MW-26D Lab ID:92273330003 Collected:10/22/15 08:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 00:47 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 00:47 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 00:47 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 00:47 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 00:47 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 00:47 108-10-11000.33 1
Styrene ND ug/L 11/01/15 00:47 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 00:47 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 00:47 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 00:47 127-18-41.0 0.46 1
Toluene 0.65J ug/L 11/01/15 00:47 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 00:47 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 00:47 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 00:47 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 00:47 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 00:47 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 00:47 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 00:47 75-01-4 M11.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 00:47 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 00:47 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %11/01/15 00:47 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 00:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:P-1 Lab ID:92273330004 Collected:10/21/15 12:25 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/29/15 00:26 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/29/15 00:26 7440-38-210/28/15 20:0010.0 2.5 1
Barium 1400 ug/L 10/29/15 00:26 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/29/15 00:26 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/29/15 00:26 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/29/15 00:26 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt 36.9 ug/L 10/29/15 00:26 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/29/15 00:26 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/29/15 00:26 7439-92-110/28/15 20:0010.0 2.5 1
Nickel 21.5J ug/L 10/29/15 00:26 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/29/15 00:26 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/29/15 00:26 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/29/15 00:26 7440-28-010/28/15 20:005.5 5.0 1
Vanadium 3.6J ug/L 10/29/15 00:26 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/29/15 00:26 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 05:17 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 05:17 107-13-12001.9 1
Benzene 1.1 ug/L 10/31/15 05:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 05:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 05:17 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 05:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 05:17 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 05:17 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 05:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 05:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 05:17 108-90-73.0 0.23 1
Chloroethane 1.1J ug/L 10/31/15 05:17 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 05:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 05:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 05:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 05:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 05:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 05:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 05:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene 11.0 ug/L 10/31/15 05:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 05:17 110-57-61001.0 1
1,1-Dichloroethane 0.70J ug/L 10/31/15 05:17 75-34-35.0 0.32 1
1,2-Dichloroethane 0.26J ug/L 10/31/15 05:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 05:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 4.8J ug/L 10/31/15 05:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 05:17 156-60-55.0 0.49 1
1,2-Dichloropropane 6.8 ug/L 10/31/15 05:17 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 05:17 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 05:17 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:P-1 Lab ID:92273330004 Collected:10/21/15 12:25 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 05:17 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 05:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 05:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 05:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 05:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 05:17 108-10-11000.33 1
Styrene ND ug/L 10/31/15 05:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 05:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 05:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 05:17 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 05:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 05:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 05:17 79-00-51.0 0.29 1
Trichloroethene 0.83J ug/L 10/31/15 05:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 05:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 05:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 05:17 108-05-450.0 0.35 1
Vinyl chloride 4.9 ug/L 10/31/15 05:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 05:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/31/15 05:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 05:17 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 05:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:SW-4 Lab ID:92273330005 Collected:10/21/15 15:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/29/15 00:29 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/29/15 00:29 7440-38-210/28/15 20:0010.0 2.5 1
Barium 208 ug/L 10/29/15 00:29 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/29/15 00:29 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/29/15 00:29 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/29/15 00:29 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/29/15 00:29 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/29/15 00:29 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/29/15 00:29 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/29/15 00:29 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/29/15 00:29 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/29/15 00:29 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/29/15 00:29 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/29/15 00:29 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/29/15 00:29 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 05:34 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 05:34 107-13-12001.9 1
Benzene ND ug/L 10/31/15 05:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 05:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 05:34 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 05:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 05:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 05:34 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 05:34 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 05:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 05:34 108-90-73.0 0.23 1
Chloroethane 0.83J ug/L 10/31/15 05:34 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 05:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 05:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 05:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 05:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 05:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 05:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 05:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.56J ug/L 10/31/15 05:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 05:34 110-57-61001.0 1
1,1-Dichloroethane 0.61J ug/L 10/31/15 05:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 05:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 05:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 05:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 05:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 05:34 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 05:34 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 05:34 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:SW-4 Lab ID:92273330005 Collected:10/21/15 15:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 05:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 05:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 05:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 05:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 05:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 05:34 108-10-11000.33 1
Styrene ND ug/L 10/31/15 05:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 05:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 05:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 05:34 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 05:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 05:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 05:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 05:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 05:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 05:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 05:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 05:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 05:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/31/15 05:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %10/31/15 05:34 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 05:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:SW-5 Lab ID:92273330006 Collected:10/21/15 16:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:25 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:25 7440-38-210/28/15 19:0010.0 2.5 1
Barium 92.1J ug/L 11/04/15 19:25 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:25 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:25 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:25 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:25 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:25 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:25 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:25 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:25 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:25 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:25 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:25 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 9.5J ug/L 11/04/15 19:25 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 05:51 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 05:51 107-13-12001.9 1
Benzene ND ug/L 10/31/15 05:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 05:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 05:51 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 05:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 05:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 05:51 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 05:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 05:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 05:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 05:51 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 05:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 05:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 05:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 05:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 05:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 05:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 05:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/31/15 05:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 05:51 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 05:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 05:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 05:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 05:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 05:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 05:51 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 05:51 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 05:51 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Sample:SW-5 Lab ID:92273330006 Collected:10/21/15 16:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 05:51 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 05:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 05:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 05:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 05:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 05:51 108-10-11000.33 1
Styrene ND ug/L 10/31/15 05:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 05:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 05:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 05:51 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 05:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 05:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 05:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 05:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 05:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 05:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 05:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 05:51 75-01-4 M11.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 05:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/31/15 05:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %10/31/15 05:51 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 05:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19904
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273330001, 92273330002, 92273330004, 92273330005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593018
Associated Lab Samples:92273330001, 92273330002, 92273330004, 92273330005
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/29/15 17:533.8
Arsenic ug/L ND 10.0 10/29/15 17:532.5
Barium ug/L ND 100 10/29/15 17:532.5
Beryllium ug/L ND 1.0 10/29/15 17:530.50
Cadmium ug/L ND 1.0 10/29/15 17:530.50
Chromium ug/L ND 10.0 10/29/15 17:532.5
Cobalt ug/L ND 10.0 10/29/15 17:532.5
Copper ug/L ND 10.0 10/29/15 17:532.5
Lead ug/L ND 10.0 10/29/15 17:532.5
Nickel ug/L ND 50.0 10/29/15 17:532.5
Selenium ug/L ND 10.0 10/29/15 17:535.0
Silver ug/L ND 10.0 10/29/15 17:532.5
Thallium ug/L ND 5.5 10/29/15 17:535.0
Vanadium ug/L ND 25.0 10/29/15 17:532.5
Zinc ug/L ND 10.0 10/29/15 17:535.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593019LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 498500 100 80-120
Arsenic ug/L 472500 94 80-120
Barium ug/L 469500 94 80-120
Beryllium ug/L 472500 94 80-120
Cadmium ug/L 473500 95 80-120
Chromium ug/L 471500 94 80-120
Cobalt ug/L 521500 104 80-120
Copper ug/L 484500 97 80-120
Lead ug/L 472500 94 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 462500 92 80-120
Silver ug/L 241250 96 80-120
Thallium ug/L 476500 95 80-120
Vanadium ug/L 494500 99 80-120
Zinc ug/L 488500 98 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593020MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92272955001
1593021
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 107 75-12597 10 25500ND540489
Arsenic ug/L 500 104 75-12594 10 25500ND519470
Barium ug/L 500 102 75-12592 8 25500108618569
Beryllium ug/L 500 105 75-12594 11 25500ND523471
Cadmium ug/L 500 103 75-12593 10 25500ND514465
Chromium ug/L 500 103 75-12593 10 255003.2J 520 470
Cobalt ug/L 500 111 75-125101 9 2550039.3 594 542
Copper ug/L 500 107 75-12595 12 255002.7J 536 476
Lead ug/L 500 100 75-12590 10 255004.2J 504 457
Nickel ug/L 500 100 75-12591 10 255005.9 506 459
Selenium ug/L 500 100 75-12590 10 25500ND499452
Silver ug/L 250 106 75-12595 11 25250ND267239
Thallium ug/L 500 98 75-12590 8 25500ND489452
Vanadium ug/L 500 110 75-12599 10 25500ND550496
Zinc ug/L 500 106 75-12596 10 25500ND530480
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593032MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92272955006
1593033
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12595 1 25500ND482477
Arsenic ug/L 500 93 75-12592 1 25500ND464459
Barium ug/L 500 90 75-12589 1 25500103555548
Beryllium ug/L 500 92 75-12591 1 255000.61J 462 457
Cadmium ug/L 500 92 75-12591 1 25500ND460455
Chromium ug/L 500 91 75-12590 1 25500ND459455
Cobalt ug/L 500 100 75-12599 1 25500ND500495
Copper ug/L 500 93 75-12592 1 25500ND465459
Lead ug/L 500 90 75-12589 1 25500ND452448
Nickel ug/L 500 90 75-12589 1 25500ND453448
Selenium ug/L 500 88 75-12587 1 25500ND442436
Silver ug/L 250 93 75-12592 1 25250ND232230
Thallium ug/L 500 92 75-12590 1 25500ND458452
Vanadium ug/L 500 96 75-12595 1 25500ND483477
Zinc ug/L 500 95 75-12594 1 25500ND480476
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273330003, 92273330006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273330003, 92273330006
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34069
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273330004, 92273330005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596018
Associated Lab Samples:92273330004, 92273330005
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/30/15 23:430.33
1,1,1-Trichloroethane ug/L ND 1.0 10/30/15 23:430.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/30/15 23:430.40
1,1,2-Trichloroethane ug/L ND 1.0 10/30/15 23:430.29
1,1-Dichloroethane ug/L ND 5.0 10/30/15 23:430.32
1,1-Dichloroethene ug/L ND 5.0 10/30/15 23:430.56
1,2,3-Trichloropropane ug/L ND 1.0 10/30/15 23:430.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/30/15 23:432.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/30/15 23:430.27
1,2-Dichlorobenzene ug/L ND 5.0 10/30/15 23:430.30
1,2-Dichloroethane ug/L ND 1.0 10/30/15 23:430.24
1,2-Dichloropropane ug/L ND 1.0 10/30/15 23:430.27
1,3-Dichloropropane ug/L ND 1.0 10/30/15 23:430.28
1,4-Dichlorobenzene ug/L ND 1.0 10/30/15 23:430.33
2-Butanone (MEK)ug/L ND 100 10/30/15 23:430.96
2-Hexanone ug/L ND 50.0 10/30/15 23:430.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/30/15 23:430.33
Acetone ug/L ND 100 10/30/15 23:4310.0
Acrylonitrile ug/L ND 200 10/30/15 23:431.9
Benzene ug/L ND 1.0 10/30/15 23:430.25
Bromochloromethane ug/L ND 3.0 10/30/15 23:430.17
Bromodichloromethane ug/L ND 1.0 10/30/15 23:430.18
Bromoform ug/L ND 3.0 10/30/15 23:430.26
Bromomethane ug/L ND 10.0 10/30/15 23:430.29
Carbon disulfide ug/L ND 100 10/30/15 23:431.2
Carbon tetrachloride ug/L ND 1.0 10/30/15 23:430.25
Chlorobenzene ug/L ND 3.0 10/30/15 23:430.23
Chloroethane ug/L ND 10.0 10/30/15 23:430.54
Chloroform ug/L ND 5.0 10/30/15 23:430.14
Chloromethane ug/L ND 1.0 10/30/15 23:430.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/30/15 23:430.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/30/15 23:430.13
Dibromochloromethane ug/L ND 3.0 10/30/15 23:430.21
Dibromomethane ug/L ND 10.0 10/30/15 23:430.21
Ethylbenzene ug/L ND 1.0 10/30/15 23:430.30
Iodomethane ug/L ND 10.0 10/30/15 23:430.32
Methylene Chloride ug/L ND 1.0 10/30/15 23:430.97
Styrene ug/L ND 1.0 10/30/15 23:430.26
Tetrachloroethene ug/L ND 1.0 10/30/15 23:430.46
Toluene ug/L ND 1.0 10/30/15 23:430.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/30/15 23:430.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596018
Associated Lab Samples:92273330004, 92273330005
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/30/15 23:430.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/30/15 23:431.0
Trichloroethene ug/L ND 1.0 10/30/15 23:430.47
Trichlorofluoromethane ug/L ND 1.0 10/30/15 23:430.20
Vinyl acetate ug/L ND 50.0 10/30/15 23:430.35
Vinyl chloride ug/L ND 1.0 10/30/15 23:430.62
Xylene (Total)ug/L ND 5.0 10/30/15 23:430.66
1,2-Dichloroethane-d4 (S)%103 70-130 10/30/15 23:43
4-Bromofluorobenzene (S)%101 70-130 10/30/15 23:43
Toluene-d8 (S)%100 70-130 10/30/15 23:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596019LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.150 104 80-125
1,1,1-Trichloroethane ug/L 55.250 110 71-129
1,1,2,2-Tetrachloroethane ug/L 52.050 104 79-124
1,1,2-Trichloroethane ug/L 48.750 97 85-125
1,1-Dichloroethane ug/L 53.750 107 73-126
1,1-Dichloroethene ug/L 56.850 114 66-135
1,2,3-Trichloropropane ug/L 50.350 101 75-130
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 52.350 105 83-124
1,2-Dichlorobenzene ug/L 51.950 104 80-133
1,2-Dichloroethane ug/L 46.650 93 67-128
1,2-Dichloropropane ug/L 49.850 100 75-132
1,3-Dichloropropane ug/L 51.450 103 76-131
1,4-Dichlorobenzene ug/L 51.950 104 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 104100 104 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 93.6J100 94 48-146
Acrylonitrile ug/L 252250 101 40-160
Benzene ug/L 52.950 106 80-125
Bromochloromethane ug/L 53.850 108 71-125
Bromodichloromethane ug/L 54.150 108 78-124
Bromoform ug/L 51.050 102 71-128
Bromomethane ug/L 51.550 103 40-160
Carbon disulfide ug/L 55.0J50 110 50-160
Carbon tetrachloride ug/L 55.750 111 69-131
Chlorobenzene ug/L 51.250 102 81-122
Chloroethane ug/L 51.550 103 39-148
Chloroform ug/L 53.350 107 73-127
Chloromethane ug/L 51.650 103 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596019LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 50.850 102 74-124
cis-1,3-Dichloropropene ug/L 51.650 103 72-132
Dibromochloromethane ug/L 53.750 107 78-125
Dibromomethane ug/L 50.350 101 82-120
Ethylbenzene ug/L 53.050 106 79-121
Iodomethane ug/L 104100 104 39-154
Methylene Chloride ug/L 55.250 110 64-133
Styrene ug/L 52.950 106 84-126
Tetrachloroethene ug/L 53.750 107 78-122
Toluene ug/L 51.450 103 80-121
trans-1,2-Dichloroethene ug/L 53.350 107 71-127
trans-1,3-Dichloropropene ug/L 51.450 103 69-141
trans-1,4-Dichloro-2-butene ug/L 49.8J50 100 40-160
Trichloroethene ug/L 50.050 100 78-122
Trichlorofluoromethane ug/L 55.050 110 53-137
Vinyl acetate ug/L 107100 107 40-160
Vinyl chloride ug/L 60.950 122 58-137
Xylene (Total)ug/L 158150 105 81-126
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1596020MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92272855003
1596021
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 100 70-130103 3 3020ND20.0 20.6
1,1,1-Trichloroethane ug/L 20 114 70-130115 1 3020ND22.7 23.1
1,1,2,2-Tetrachloroethane ug/L 20 102 70-130105 2 3020ND20.5 21.0
1,1,2-Trichloroethane ug/L 20 100 70-130102 2 3020ND20.0 20.5
1,1-Dichloroethane ug/L 20 114 70-130114 0 3020ND22.8 22.7
1,1-Dichloroethene ug/L 20 121 70-166124 2 3020ND24.2 24.7
1,2,3-Trichloropropane ug/L 20 98 70-130101 4 3020ND19.5 20.2
1,2-Dibromo-3-
chloropropane ug/L 20 91 70-130102 12 3020ND18.1 20.4
1,2-Dibromoethane (EDB)ug/L 20 102 70-130105 3 3020ND20.3 21.0
1,2-Dichlorobenzene ug/L 20 101 70-130103 2 3020ND20.1 20.5
1,2-Dichloroethane ug/L 20 94 70-13098 4 3020ND19.1 19.8
1,2-Dichloropropane ug/L 20 105 70-130106 1 3020ND20.9 21.1
1,3-Dichloropropane ug/L 20 104 70-130105 1 3020ND20.7 21.0
1,4-Dichlorobenzene ug/L 20 100 70-130102 2 3020ND20.1 20.5
2-Butanone (MEK)ug/L 40 95 70-130104 10 3040ND37.8J 41.6J
2-Hexanone ug/L 40 97 70-130107 10 3040ND38.6J 42.6J
4-Methyl-2-pentanone
(MIBK)ug/L 40 101 70-130107 6 3040ND40.2J 42.9J
Acetone ug/L 40 99 70-130106 7 3040ND42.6J 45.5J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1596020MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92272855003
1596021
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Acrylonitrile ug/L 100 96 70-130104 8 30100ND96.5J 104J
Benzene ug/L 20 108 70-148110 2 3020ND21.6 22.0
Bromochloromethane ug/L 20 112 70-130114 2 3020ND22.5 22.9
Bromodichloromethane ug/L 20 105 70-130108 3 3020ND21.0 21.7
Bromoform ug/L 20 89 70-13094 6 3020ND17.8 18.9
Bromomethane ug/L 20 71 70-13088 21 3020ND14.2 17.6
Carbon disulfide ug/L 20 107 70-130114 6 3020ND21.4J 22.8J
Carbon tetrachloride ug/L 20 112 70-130116 4 3020ND22.3 23.3
Chlorobenzene ug/L 20 102 70-146104 2 3020ND20.5 20.9
Chloroethane ug/L 20 113 70-130116 2 3020ND22.6 23.2
Chloroform ug/L 20 111 70-130111 0 3020ND22.1 22.2
Chloromethane ug/L 20 113 70-130118 5 3020ND22.5 23.7
cis-1,2-Dichloroethene ug/L 20 107 70-130108 1 3020ND21.4 21.7
cis-1,3-Dichloropropene ug/L 20 100 70-130100 0 3020ND20.0 20.1
Dibromochloromethane ug/L 20 100 70-130104 4 3020ND19.9 20.8
Dibromomethane ug/L 20 102 70-130105 3 3020ND20.5 21.0
Ethylbenzene ug/L 20 104 70-130107 3 3020ND20.8 21.4
Iodomethane ug/L M1406970-13094 30 3040ND27.6 37.5
Methylene Chloride ug/L 20 117 70-130117 1 3020ND23.5 23.3
Styrene ug/L 20 100 70-130102 2 3020ND20.0 20.4
Tetrachloroethene ug/L 20 104 70-130107 3 3020ND20.8 21.4
Toluene ug/L 20 105 70-155107 2 3020ND21.0 21.3
trans-1,2-Dichloroethene ug/L 20 112 70-130113 1 3020ND22.5 22.6
trans-1,3-Dichloropropene ug/L 20 99 70-130100 1 3020ND19.8 19.9
trans-1,4-Dichloro-2-butene ug/L 20 85 70-13092 8 3020ND17.0J 18.4J
Trichloroethene ug/L 20 103 69-151104 1 3020ND20.5 20.8
Trichlorofluoromethane ug/L 20 119 70-130120 1 3020ND23.7 24.1
Vinyl acetate ug/L 40 88 70-13086 2 3040ND35.1J 34.5J
Vinyl chloride ug/L M12012870-130132 3 3020ND25.6 26.4
1,2-Dichloroethane-d4 (S)%98 70-13098
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34070
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273330006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596025
Associated Lab Samples:92273330006
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/31/15 00:000.33
1,1,1-Trichloroethane ug/L ND 1.0 10/31/15 00:000.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/31/15 00:000.40
1,1,2-Trichloroethane ug/L ND 1.0 10/31/15 00:000.29
1,1-Dichloroethane ug/L ND 5.0 10/31/15 00:000.32
1,1-Dichloroethene ug/L ND 5.0 10/31/15 00:000.56
1,2,3-Trichloropropane ug/L ND 1.0 10/31/15 00:000.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/31/15 00:002.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/31/15 00:000.27
1,2-Dichlorobenzene ug/L ND 5.0 10/31/15 00:000.30
1,2-Dichloroethane ug/L ND 1.0 10/31/15 00:000.24
1,2-Dichloropropane ug/L ND 1.0 10/31/15 00:000.27
1,3-Dichloropropane ug/L ND 1.0 10/31/15 00:000.28
1,4-Dichlorobenzene ug/L ND 1.0 10/31/15 00:000.33
2-Butanone (MEK)ug/L ND 100 10/31/15 00:000.96
2-Hexanone ug/L ND 50.0 10/31/15 00:000.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/31/15 00:000.33
Acetone ug/L ND 100 10/31/15 00:0010.0
Acrylonitrile ug/L ND 200 10/31/15 00:001.9
Benzene ug/L ND 1.0 10/31/15 00:000.25
Bromochloromethane ug/L ND 3.0 10/31/15 00:000.17
Bromodichloromethane ug/L ND 1.0 10/31/15 00:000.18
Bromoform ug/L ND 3.0 10/31/15 00:000.26
Bromomethane ug/L ND 10.0 10/31/15 00:000.29
Carbon disulfide ug/L ND 100 10/31/15 00:001.2
Carbon tetrachloride ug/L ND 1.0 10/31/15 00:000.25
Chlorobenzene ug/L ND 3.0 10/31/15 00:000.23
Chloroethane ug/L ND 10.0 10/31/15 00:000.54
Chloroform ug/L ND 5.0 10/31/15 00:000.14
Chloromethane ug/L ND 1.0 10/31/15 00:000.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/31/15 00:000.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/31/15 00:000.13
Dibromochloromethane ug/L ND 3.0 10/31/15 00:000.21
Dibromomethane ug/L ND 10.0 10/31/15 00:000.21
Ethylbenzene ug/L ND 1.0 10/31/15 00:000.30
Iodomethane ug/L ND 10.0 10/31/15 00:000.32
Methylene Chloride ug/L ND 1.0 10/31/15 00:000.97
Styrene ug/L ND 1.0 10/31/15 00:000.26
Tetrachloroethene ug/L ND 1.0 10/31/15 00:000.46
Toluene ug/L ND 1.0 10/31/15 00:000.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/31/15 00:000.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596025
Associated Lab Samples:92273330006
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/31/15 00:000.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/31/15 00:001.0
Trichloroethene ug/L ND 1.0 10/31/15 00:000.47
Trichlorofluoromethane ug/L ND 1.0 10/31/15 00:000.20
Vinyl acetate ug/L ND 50.0 10/31/15 00:000.35
Vinyl chloride ug/L ND 1.0 10/31/15 00:000.62
Xylene (Total)ug/L ND 5.0 10/31/15 00:000.66
1,2-Dichloroethane-d4 (S)%103 70-130 10/31/15 00:00
4-Bromofluorobenzene (S)%100 70-130 10/31/15 00:00
Toluene-d8 (S)%102 70-130 10/31/15 00:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596026LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.550 99 80-125
1,1,1-Trichloroethane ug/L 52.450 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.350 101 79-124
1,1,2-Trichloroethane ug/L 47.350 95 85-125
1,1-Dichloroethane ug/L 50.950 102 73-126
1,1-Dichloroethene ug/L 54.250 108 66-135
1,2,3-Trichloropropane ug/L 48.550 97 75-130
1,2-Dibromo-3-chloropropane ug/L 50.850 102 71-133
1,2-Dibromoethane (EDB)ug/L 49.950 100 83-124
1,2-Dichlorobenzene ug/L 49.450 99 80-133
1,2-Dichloroethane ug/L 44.450 89 67-128
1,2-Dichloropropane ug/L 48.050 96 75-132
1,3-Dichloropropane ug/L 49.650 99 76-131
1,4-Dichlorobenzene ug/L 48.650 97 78-130
2-Butanone (MEK)ug/L 93.9J100 94 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 100100 100 72-135
Acetone ug/L 89.7J100 90 48-146
Acrylonitrile ug/L 245250 98 40-160
Benzene ug/L 50.250 100 80-125
Bromochloromethane ug/L 51.450 103 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 49.850 100 71-128
Bromomethane ug/L 47.150 94 40-160
Carbon disulfide ug/L 52.7J50 105 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 48.050 96 39-148
Chloroform ug/L 49.950 100 73-127
Chloromethane ug/L 50.250 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596026LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 48.750 97 74-124
cis-1,3-Dichloropropene ug/L 50.550 101 72-132
Dibromochloromethane ug/L 51.750 103 78-125
Dibromomethane ug/L 48.750 97 82-120
Ethylbenzene ug/L 50.150 100 79-121
Iodomethane ug/L 101100 101 39-154
Methylene Chloride ug/L 53.350 107 64-133
Styrene ug/L 50.650 101 84-126
Tetrachloroethene ug/L 50.350 101 78-122
Toluene ug/L 49.250 98 80-121
trans-1,2-Dichloroethene ug/L 50.850 102 71-127
trans-1,3-Dichloropropene ug/L 49.150 98 69-141
trans-1,4-Dichloro-2-butene ug/L 47.8J50 96 40-160
Trichloroethene ug/L 48.250 96 78-122
Trichlorofluoromethane ug/L 52.550 105 53-137
Vinyl acetate ug/L 102100 102 40-160
Vinyl chloride ug/L 58.950 118 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596027MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330006
1,1,1,2-Tetrachloroethane ug/L 21.120 106 70-130ND
1,1,1-Trichloroethane ug/L 23.920 120 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.320 106 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 23.520 118 70-130ND
1,1-Dichloroethene ug/L 25.420 127 70-166ND
1,2,3-Trichloropropane ug/L 20.320 101 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.420 107 70-130ND
1,2-Dichlorobenzene ug/L 21.220 106 70-130ND
1,2-Dichloroethane ug/L 19.920 99 70-130ND
1,2-Dichloropropane ug/L 21.220 106 70-130ND
1,3-Dichloropropane ug/L 21.620 108 70-130ND
1,4-Dichlorobenzene ug/L 21.120 105 70-130ND
2-Butanone (MEK)ug/L 40.5J40 101 70-130ND
2-Hexanone ug/L 41.4J40 103 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.7J40 104 70-130ND
Acetone ug/L 42.2J40 101 70-130ND
Acrylonitrile ug/L 106J100 106 70-130ND
Benzene ug/L 22.420 112 70-148ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596027MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330006
Bromochloromethane ug/L 23.420 117 70-130ND
Bromodichloromethane ug/L 21.620 108 70-130ND
Bromoform ug/L 19.220 96 70-130ND
Bromomethane ug/L 18.920 94 70-130ND
Carbon disulfide ug/L 23.7J20 118 70-130ND
Carbon tetrachloride ug/L 23.920 119 70-130ND
Chlorobenzene ug/L 21.620 108 70-146ND
Chloroethane ug/L 23.020 115 70-130ND
Chloroform ug/L 22.620 113 70-130ND
Chloromethane ug/L 23.820 119 70-130ND
cis-1,2-Dichloroethene ug/L 22.220 111 70-130ND
cis-1,3-Dichloropropene ug/L 20.120 101 70-130ND
Dibromochloromethane ug/L 21.320 107 70-130ND
Dibromomethane ug/L 20.820 104 70-130ND
Ethylbenzene ug/L 22.320 111 70-130ND
Iodomethane ug/L 41.140 103 70-130ND
Methylene Chloride ug/L 23.020 115 70-130ND
Styrene ug/L 21.720 108 70-130ND
Tetrachloroethene ug/L 22.120 110 70-130ND
Toluene ug/L 21.720 109 70-155ND
trans-1,2-Dichloroethene ug/L 23.520 117 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 103 70-130ND
trans-1,4-Dichloro-2-butene ug/L 18.9J20 94 70-130ND
Trichloroethene ug/L 21.320 107 69-151ND
Trichlorofluoromethane ug/L 25.220 126 70-130ND
Vinyl acetate ug/L 34.7J40 87 70-130ND
Vinyl chloride ug/L 27.3 M12013770-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273829001
1596028SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 12.5 4 3013.0
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273829001
1596028SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.2 2 301.2
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.8 7 301.9
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L 15.1 3 3015.5
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 1.8J 6 302.0J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 1.3 0 301.3
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 199
4-Bromofluorobenzene (S)%100 298
Toluene-d8 (S)%100 1101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34085
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273330001, 92273330002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596336
Associated Lab Samples:92273330001, 92273330002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/31/15 12:160.33
1,1,1-Trichloroethane ug/L ND 1.0 10/31/15 12:160.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/31/15 12:160.40
1,1,2-Trichloroethane ug/L ND 1.0 10/31/15 12:160.29
1,1-Dichloroethane ug/L ND 5.0 10/31/15 12:160.32
1,1-Dichloroethene ug/L ND 5.0 10/31/15 12:160.56
1,2,3-Trichloropropane ug/L ND 1.0 10/31/15 12:160.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/31/15 12:162.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/31/15 12:160.27
1,2-Dichlorobenzene ug/L ND 5.0 10/31/15 12:160.30
1,2-Dichloroethane ug/L ND 1.0 10/31/15 12:160.24
1,2-Dichloropropane ug/L ND 1.0 10/31/15 12:160.27
1,3-Dichloropropane ug/L ND 1.0 10/31/15 12:160.28
1,4-Dichlorobenzene ug/L ND 1.0 10/31/15 12:160.33
2-Butanone (MEK)ug/L ND 100 10/31/15 12:160.96
2-Hexanone ug/L ND 50.0 10/31/15 12:160.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/31/15 12:160.33
Acetone ug/L ND 100 10/31/15 12:1610.0
Acrylonitrile ug/L ND 200 10/31/15 12:161.9
Benzene ug/L ND 1.0 10/31/15 12:160.25
Bromochloromethane ug/L ND 3.0 10/31/15 12:160.17
Bromodichloromethane ug/L ND 1.0 10/31/15 12:160.18
Bromoform ug/L ND 3.0 10/31/15 12:160.26
Bromomethane ug/L ND 10.0 10/31/15 12:160.29
Carbon disulfide ug/L ND 100 10/31/15 12:161.2
Carbon tetrachloride ug/L ND 1.0 10/31/15 12:160.25
Chlorobenzene ug/L ND 3.0 10/31/15 12:160.23
Chloroethane ug/L ND 10.0 10/31/15 12:160.54
Chloroform ug/L ND 5.0 10/31/15 12:160.14
Chloromethane ug/L ND 1.0 10/31/15 12:160.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/31/15 12:160.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/31/15 12:160.13
Dibromochloromethane ug/L ND 3.0 10/31/15 12:160.21
Dibromomethane ug/L ND 10.0 10/31/15 12:160.21
Ethylbenzene ug/L ND 1.0 10/31/15 12:160.30
Iodomethane ug/L ND 10.0 10/31/15 12:160.32
Methylene Chloride ug/L ND 1.0 10/31/15 12:160.97
Styrene ug/L ND 1.0 10/31/15 12:160.26
Tetrachloroethene ug/L ND 1.0 10/31/15 12:160.46
Toluene ug/L ND 1.0 10/31/15 12:160.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/31/15 12:160.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596336
Associated Lab Samples:92273330001, 92273330002
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/31/15 12:160.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/31/15 12:161.0
Trichloroethene ug/L ND 1.0 10/31/15 12:160.47
Trichlorofluoromethane ug/L ND 1.0 10/31/15 12:160.20
Vinyl acetate ug/L ND 50.0 10/31/15 12:160.35
Vinyl chloride ug/L ND 1.0 10/31/15 12:160.62
Xylene (Total)ug/L ND 5.0 10/31/15 12:160.66
1,2-Dichloroethane-d4 (S)%98 70-130 10/31/15 12:16
4-Bromofluorobenzene (S)%98 70-130 10/31/15 12:16
Toluene-d8 (S)%99 70-130 10/31/15 12:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596337LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125
1,1,1-Trichloroethane ug/L 51.850 104 71-129
1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124
1,1,2-Trichloroethane ug/L 48.450 97 85-125
1,1-Dichloroethane ug/L 50.950 102 73-126
1,1-Dichloroethene ug/L 53.750 107 66-135
1,2,3-Trichloropropane ug/L 48.450 97 75-130
1,2-Dibromo-3-chloropropane ug/L 50.850 102 71-133
1,2-Dibromoethane (EDB)ug/L 50.250 100 83-124
1,2-Dichlorobenzene ug/L 49.350 99 80-133
1,2-Dichloroethane ug/L 45.550 91 67-128
1,2-Dichloropropane ug/L 49.150 98 75-132
1,3-Dichloropropane ug/L 49.650 99 76-131
1,4-Dichlorobenzene ug/L 49.450 99 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 106100 106 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 114100 114 48-146
Acrylonitrile ug/L 254250 102 40-160
Benzene ug/L 51.050 102 80-125
Bromochloromethane ug/L 51.250 102 71-125
Bromodichloromethane ug/L 52.350 105 78-124
Bromoform ug/L 50.250 100 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 52.2J50 104 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 48.750 97 81-122
Chloroethane ug/L 46.750 93 39-148
Chloroform ug/L 50.450 101 73-127
Chloromethane ug/L 48.350 97 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596337LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 49.350 99 74-124
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 51.750 103 78-125
Dibromomethane ug/L 49.650 99 82-120
Ethylbenzene ug/L 50.150 100 79-121
Iodomethane ug/L 90.3100 90 39-154
Methylene Chloride ug/L 53.250 106 64-133
Styrene ug/L 50.550 101 84-126
Tetrachloroethene ug/L 49.950 100 78-122
Toluene ug/L 49.650 99 80-121
trans-1,2-Dichloroethene ug/L 50.950 102 71-127
trans-1,3-Dichloropropene ug/L 51.750 103 69-141
trans-1,4-Dichloro-2-butene ug/L 69.4J50 139 40-160
Trichloroethene ug/L 48.450 97 78-122
Trichlorofluoromethane ug/L 51.250 102 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 57.350 115 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596338MATRIX SPIKE SAMPLE:
MSSpike
Result
92273430003
1,1,1,2-Tetrachloroethane ug/L 21.120 106 70-130ND
1,1,1-Trichloroethane ug/L 24.120 120 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 20.320 101 70-130ND
1,1-Dichloroethane ug/L 24.520 122 70-130ND
1,1-Dichloroethene ug/L 25.720 129 70-166ND
1,2,3-Trichloropropane ug/L 20.420 102 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.120 105 70-130ND
1,2-Dichlorobenzene ug/L 21.520 107 70-130ND
1,2-Dichloroethane ug/L 20.220 100 70-130ND
1,2-Dichloropropane ug/L 21.520 108 70-130ND
1,3-Dichloropropane ug/L 21.420 107 70-130ND
1,4-Dichlorobenzene ug/L 21.320 106 70-130ND
2-Butanone (MEK)ug/L 40.5J40 101 70-130ND
2-Hexanone ug/L 41.1J40 103 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.8J40 105 70-130ND
Acetone ug/L 42.2J40 97 70-130ND
Acrylonitrile ug/L 108J100 108 70-130ND
Benzene ug/L 22.620 113 70-148ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596338MATRIX SPIKE SAMPLE:
MSSpike
Result
92273430003
Bromochloromethane ug/L 23.820 119 70-130ND
Bromodichloromethane ug/L 21.620 108 70-130ND
Bromoform ug/L 18.920 95 70-130ND
Bromomethane ug/L 19.620 98 70-130ND
Carbon disulfide ug/L 23.5J20 117 70-130ND
Carbon tetrachloride ug/L 23.720 118 70-130ND
Chlorobenzene ug/L 21.820 109 70-146ND
Chloroethane ug/L 24.020 120 70-130ND
Chloroform ug/L 23.120 115 70-130ND
Chloromethane ug/L 24.320 122 70-130ND
cis-1,2-Dichloroethene ug/L 24.720 123 70-130ND
cis-1,3-Dichloropropene ug/L 20.820 104 70-130ND
Dibromochloromethane ug/L 20.620 103 70-130ND
Dibromomethane ug/L 20.920 104 70-130ND
Ethylbenzene ug/L 22.220 111 70-130ND
Iodomethane ug/L 41.040 103 70-130ND
Methylene Chloride ug/L 24.220 121 70-130ND
Styrene ug/L 21.320 106 70-130ND
Tetrachloroethene ug/L 23.820 119 70-130ND
Toluene ug/L 22.020 110 70-155ND
trans-1,2-Dichloroethene ug/L 23.720 119 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.9J20 89 70-130ND
Trichloroethene ug/L 22.620 113 69-151ND
Trichlorofluoromethane ug/L 25.420 127 70-130ND
Vinyl acetate ug/L 38.5J40 96 70-130ND
Vinyl chloride ug/L 28.0 M12014070-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273430004
1596339SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273430004
1596339SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%102 1101
4-Bromofluorobenzene (S)%98 099
Toluene-d8 (S)%99 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273330003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273330003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273330003
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 43
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 43
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273330
ASHE CO. CLOSED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273330001 MPRP/19904 ICP/17944MW-23 EPA 3010 EPA 6010
92273330002 MPRP/19904 ICP/17944MW-26 EPA 3010 EPA 6010
92273330003 MPRP/19918 ICP/17958MW-26D EPA 3010 EPA 6010
92273330004 MPRP/19904 ICP/17944P-1 EPA 3010 EPA 6010
92273330005 MPRP/19904 ICP/17944SW-4 EPA 3010 EPA 6010
92273330006 MPRP/19918 ICP/17958SW-5 EPA 3010 EPA 6010
92273330001 MSV/34085MW-23 EPA 8260
92273330002 MSV/34085MW-26 EPA 8260
92273330003 MSV/34086MW-26D EPA 8260
92273330004 MSV/34069P-1 EPA 8260
92273330005 MSV/34069SW-4 EPA 8260
92273330006 MSV/34070SW-5 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 43
Page 42 of 43
Page 43 of 43
#=CL#
November 02, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273346
92273346
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. MSWLF (MW-14)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Lab ID Sample ID Matrix Date Collected Date Received
92273346001 MW-14 Water 10/23/15 08:10 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273346001 MW-14 EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Sample:MW-14 Lab ID:92273346001 Collected:10/23/15 08:10 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:37 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:37 7440-38-210/28/15 20:0010.0 2.5 1
Barium 1770 ug/L 10/30/15 23:37 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:37 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:37 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:37 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt 6.9J ug/L 10/30/15 23:37 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:37 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:37 7439-92-110/28/15 20:0010.0 2.5 1
Nickel 4.9J ug/L 10/30/15 23:37 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:37 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:37 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:37 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:37 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:37 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/30/15 16:39 7439-97-610/28/15 17:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 04:48 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 04:48 107-13-12001.9 1
Benzene 1.1 ug/L 11/01/15 04:48 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 04:48 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 04:48 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 04:48 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 04:48 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 04:48 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 04:48 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 04:48 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 04:48 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 04:48 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 04:48 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 04:48 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 04:48 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 04:48 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 04:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 04:48 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 04:48 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 04:48 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 04:48 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 04:48 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 04:48 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 04:48 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.61J ug/L 11/01/15 04:48 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 04:48 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Sample:MW-14 Lab ID:92273346001 Collected:10/23/15 08:10 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 11/01/15 04:48 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 04:48 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 04:48 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 04:48 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 04:48 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 04:48 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 04:48 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 04:48 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 04:48 108-10-11000.33 1
Styrene ND ug/L 11/01/15 04:48 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 04:48 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 04:48 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 04:48 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 04:48 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 04:48 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 04:48 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 04:48 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 04:48 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 04:48 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 04:48 108-05-450.0 0.35 1
Vinyl chloride 0.86J ug/L 11/01/15 04:48 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 04:48 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 04:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 04:48 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 04:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8592
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92273346001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593164
Associated Lab Samples:92273346001
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 10/30/15 16:060.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593165LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593166MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273493001
1593167
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 97 75-12596 1 252.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19905
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273346001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593024
Associated Lab Samples:92273346001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/30/15 22:423.8
Arsenic ug/L ND 10.0 10/30/15 22:422.5
Barium ug/L ND 100 10/30/15 22:422.5
Beryllium ug/L ND 1.0 10/30/15 22:420.50
Cadmium ug/L ND 1.0 10/30/15 22:420.50
Chromium ug/L ND 10.0 10/30/15 22:422.5
Cobalt ug/L ND 10.0 10/30/15 22:422.5
Copper ug/L ND 10.0 10/30/15 22:422.5
Lead ug/L ND 10.0 10/30/15 22:422.5
Nickel ug/L ND 50.0 10/30/15 22:422.5
Selenium ug/L ND 10.0 10/30/15 22:425.0
Silver ug/L ND 10.0 10/30/15 22:422.5
Thallium ug/L ND 5.5 10/30/15 22:425.0
Vanadium ug/L ND 25.0 10/30/15 22:422.5
Zinc ug/L ND 10.0 10/30/15 22:425.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593025LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 491500 98 80-120
Arsenic ug/L 464500 93 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 482500 96 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 471500 94 80-120
Nickel ug/L 469500 94 80-120
Selenium ug/L 466500 93 80-120
Silver ug/L 237250 95 80-120
Thallium ug/L 465500 93 80-120
Vanadium ug/L 481500 96 80-120
Zinc ug/L 445500 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337001
1593027
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-12592 13 25500ND530464
Arsenic ug/L 500 101 75-12588 13 25500ND504441
Barium ug/L 500 107 75-12593 12 2550074.1J 607 539
Beryllium ug/L 500 109 75-12595 13 25500ND543475
Cadmium ug/L 500 105 75-12592 13 25500ND527461
Chromium ug/L 500 105 75-12593 13 25500ND528465
Cobalt ug/L 500 103 75-12591 13 25500ND517453
Copper ug/L 500 109 75-12594 15 25500ND544469
Lead ug/L 500 104 75-12590 13 25500ND518452
Nickel ug/L 500 104 75-12591 13 25500ND522457
Selenium ug/L 500 101 75-12588 14 25500ND505441
Silver ug/L 250 105 75-12591 14 25250ND262228
Thallium ug/L 500 102 75-12589 13 25500ND509446
Vanadium ug/L 500 108 75-12595 13 25500ND538473
Zinc ug/L 500 101 75-12588 13 25500ND506443
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273346001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273346001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273346001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273346
ASHE CO. MSWLF (MW-14)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273346001 MPRP/19905 ICP/17945MW-14 EPA 3010 EPA 6010
92273346001 MERP/8592 MERC/8258MW-14 EPA 7470 EPA 7470
92273346001 MSV/34086MW-14 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:17 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273335
92273335
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. CLOSED MSWLF (P3-1)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 17
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 17
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Lab ID Sample ID Matrix Date Collected Date Received
92273335001 P3-1 Water 10/22/15 16:35 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 17
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273335001 P3-1 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 17
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Sample:P3-1 Lab ID:92273335001 Collected:10/22/15 16:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:40 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:40 7440-38-210/28/15 19:0010.0 2.5 1
Barium 196 ug/L 11/04/15 19:40 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:40 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:40 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:40 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt 5.2J ug/L 11/04/15 19:40 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:40 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:40 7439-92-110/28/15 19:0010.0 2.5 1
Nickel 4.0J ug/L 11/04/15 19:40 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:40 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:40 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:40 7440-28-010/28/15 19:005.5 5.0 1
Vanadium 2.6J ug/L 11/04/15 19:40 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 9.9J ug/L 11/04/15 19:40 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:03 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:03 107-13-12001.9 1
Benzene 6.7 ug/L 11/01/15 01:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:03 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:03 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:03 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:03 108-90-73.0 0.23 1
Chloroethane 0.89J ug/L 11/01/15 01:03 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:03 67-66-35.0 0.14 1
Chloromethane 2.1 ug/L 11/01/15 01:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:03 95-50-15.0 0.30 1
1,4-Dichlorobenzene 2.6 ug/L 11/01/15 01:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:03 110-57-61001.0 1
1,1-Dichloroethane 60.1 ug/L 11/01/15 01:03 75-34-35.0 0.32 1
1,2-Dichloroethane 0.42J ug/L 11/01/15 01:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:03 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 53.4 ug/L 11/01/15 01:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 01:03 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:03 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:03 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 17
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Sample:P3-1 Lab ID:92273335001 Collected:10/22/15 16:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:03 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:03 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:03 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:03 79-00-51.0 0.29 1
Trichloroethene 1.1 ug/L 11/01/15 01:03 79-01-61.0 0.47 1
Trichlorofluoromethane 0.21J ug/L 11/01/15 01:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:03 108-05-450.0 0.35 1
Vinyl chloride 2.8 ug/L 11/01/15 01:03 75-01-41.0 0.62 1
Xylene (Total)1.1J ug/L 11/01/15 01:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 01:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 01:03 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 01:03 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273335001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273335001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273335001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273335001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273335001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 17
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 17
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273335
ASHE CO. CLOSED MSWLF (P3-1)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273335001 MPRP/19918 ICP/17958P3-1 EPA 3010 EPA 6010
92273335001 MSV/34086P3-1 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 17
Page 16 of 17
Page 17 of 17
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273344
92273344
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO CLOSED MSWLF REMEDIATN
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 21
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Lab ID Sample ID Matrix Date Collected Date Received
92273344001 P-12 Water 10/22/15 16:00 10/26/15 12:15
92273344002 MW-27 Water 10/22/15 17:20 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273344001 P-12 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273344002 MW-27 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Sample:P-12 Lab ID:92273344001 Collected:10/22/15 16:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:50 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:50 7440-38-210/28/15 19:0010.0 2.5 1
Barium 75.9J ug/L 11/04/15 19:50 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:50 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:50 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:50 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:50 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:50 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:50 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:50 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:50 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:50 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:50 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:50 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 6.0J ug/L 11/04/15 19:50 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 02:51 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 02:51 107-13-12001.9 1
Benzene ND ug/L 11/01/15 02:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 02:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 02:51 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 02:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 02:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 02:51 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 02:51 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 02:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 02:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 02:51 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 02:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 02:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 02:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 02:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 02:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 02:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 02:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 02:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 02:51 110-57-61001.0 1
1,1-Dichloroethane 0.41J ug/L 11/01/15 02:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 02:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 02:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 02:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 02:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 02:51 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 02:51 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 02:51 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Sample:P-12 Lab ID:92273344001 Collected:10/22/15 16:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 02:51 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 02:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 02:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 02:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 02:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 02:51 108-10-11000.33 1
Styrene ND ug/L 11/01/15 02:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 02:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 02:51 79-34-53.0 0.40 1
Tetrachloroethene 0.72J ug/L 11/01/15 02:51 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 02:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 02:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 02:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 02:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 02:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 02:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 02:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 02:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 02:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 02:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %11/01/15 02:51 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 02:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Sample:MW-27 Lab ID:92273344002 Collected:10/22/15 17:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:34 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:34 7440-38-210/28/15 20:0010.0 2.5 1
Barium 316 ug/L 10/30/15 23:34 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:34 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:34 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:34 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt 26.2 ug/L 10/30/15 23:34 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:34 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:34 7439-92-110/28/15 20:0010.0 2.5 1
Nickel 4.9J ug/L 10/30/15 23:34 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:34 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:34 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:34 7440-28-010/28/15 20:005.5 5.0 1
Vanadium 4.1J ug/L 10/30/15 23:34 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:34 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone 28.9J ug/L 11/01/15 03:24 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 03:24 107-13-12001.9 1
Benzene 3.7 ug/L 11/01/15 03:24 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 03:24 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 03:24 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 03:24 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 03:24 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 03:24 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 03:24 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 03:24 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 03:24 108-90-73.0 0.23 1
Chloroethane 5.3J ug/L 11/01/15 03:24 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 03:24 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 03:24 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 03:24 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 03:24 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 03:24 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 03:24 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 03:24 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.3 ug/L 11/01/15 03:24 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 03:24 110-57-61001.0 1
1,1-Dichloroethane 33.7 ug/L 11/01/15 03:24 75-34-35.0 0.32 1
1,2-Dichloroethane 0.30J ug/L 11/01/15 03:24 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 03:24 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 38.3 ug/L 11/01/15 03:24 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 03:24 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 03:24 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 03:24 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 03:24 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Sample:MW-27 Lab ID:92273344002 Collected:10/22/15 17:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 03:24 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 03:24 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 03:24 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 03:24 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 03:24 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 03:24 108-10-11000.33 1
Styrene ND ug/L 11/01/15 03:24 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 03:24 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 03:24 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 03:24 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 03:24 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 03:24 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 03:24 79-00-51.0 0.29 1
Trichloroethene 0.61J ug/L 11/01/15 03:24 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 03:24 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 03:24 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 03:24 108-05-450.0 0.35 1
Vinyl chloride 4.5 ug/L 11/01/15 03:24 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 03:24 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %11/01/15 03:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 03:24 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 03:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19905
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273344002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593024
Associated Lab Samples:92273344002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/30/15 22:423.8
Arsenic ug/L ND 10.0 10/30/15 22:422.5
Barium ug/L ND 100 10/30/15 22:422.5
Beryllium ug/L ND 1.0 10/30/15 22:420.50
Cadmium ug/L ND 1.0 10/30/15 22:420.50
Chromium ug/L ND 10.0 10/30/15 22:422.5
Cobalt ug/L ND 10.0 10/30/15 22:422.5
Copper ug/L ND 10.0 10/30/15 22:422.5
Lead ug/L ND 10.0 10/30/15 22:422.5
Nickel ug/L ND 50.0 10/30/15 22:422.5
Selenium ug/L ND 10.0 10/30/15 22:425.0
Silver ug/L ND 10.0 10/30/15 22:422.5
Thallium ug/L ND 5.5 10/30/15 22:425.0
Vanadium ug/L ND 25.0 10/30/15 22:422.5
Zinc ug/L ND 10.0 10/30/15 22:425.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593025LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 491500 98 80-120
Arsenic ug/L 464500 93 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 482500 96 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 471500 94 80-120
Nickel ug/L 469500 94 80-120
Selenium ug/L 466500 93 80-120
Silver ug/L 237250 95 80-120
Thallium ug/L 465500 93 80-120
Vanadium ug/L 481500 96 80-120
Zinc ug/L 445500 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337001
1593027
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-12592 13 25500ND530464
Arsenic ug/L 500 101 75-12588 13 25500ND504441
Barium ug/L 500 107 75-12593 12 2550074.1J 607 539
Beryllium ug/L 500 109 75-12595 13 25500ND543475
Cadmium ug/L 500 105 75-12592 13 25500ND527461
Chromium ug/L 500 105 75-12593 13 25500ND528465
Cobalt ug/L 500 103 75-12591 13 25500ND517453
Copper ug/L 500 109 75-12594 15 25500ND544469
Lead ug/L 500 104 75-12590 13 25500ND518452
Nickel ug/L 500 104 75-12591 13 25500ND522457
Selenium ug/L 500 101 75-12588 14 25500ND505441
Silver ug/L 250 105 75-12591 14 25250ND262228
Thallium ug/L 500 102 75-12589 13 25500ND509446
Vanadium ug/L 500 108 75-12595 13 25500ND538473
Zinc ug/L 500 101 75-12588 13 25500ND506443
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273344001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273344001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273344001, 92273344002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273344001, 92273344002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273344001, 92273344002
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273344
ASHE CO CLOSED MSWLF REMEDIATN
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273344001 MPRP/19918 ICP/17958P-12 EPA 3010 EPA 6010
92273344002 MPRP/19905 ICP/17945MW-27 EPA 3010 EPA 6010
92273344001 MSV/34086P-12 EPA 8260
92273344002 MSV/34086MW-27 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 21
Page 20 of 21
Page 21 of 21
#=CL#
November 09, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273829
92273829
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. CLOSED MSWLF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 28, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 37
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 37
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Lab ID Sample ID Matrix Date Collected Date Received
92273829001 MW-4 Water 10/21/15 17:40 10/28/15 08:28
92273829002 MW-5 Water 10/21/15 13:35 10/28/15 08:28
92273829003 MW-6 Water 10/21/15 14:00 10/28/15 08:28
92273829004 MW-8 Water 10/21/15 15:40 10/28/15 08:28
92273829005 MW-16 Water 10/21/15 14:35 10/28/15 08:28
92273829006 MW-17 Water 10/21/15 15:05 10/28/15 08:28
92273829007 MW-18 Water 10/21/15 11:00 10/28/15 08:28
92273829008 MW-19 Water 10/21/15 11:30 10/28/15 08:28
92273829009 MW-20 Water 10/21/15 12:00 10/28/15 08:28
92273829010 MW-21 Water 10/21/15 16:15 10/28/15 08:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 37
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273829001 MW-4 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829002 MW-5 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829003 MW-6 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829004 MW-8 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829005 MW-16 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829006 MW-17 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829007 MW-18 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829008 MW-19 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829009 MW-20 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273829010 MW-21 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-4 Lab ID:92273829001 Collected:10/21/15 17:40 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:03 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:03 7440-38-211/03/15 20:0010.0 2.5 1
Barium 309 ug/L 11/06/15 19:03 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:03 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:03 7440-43-911/03/15 20:001.0 0.50 1
Chromium 5.8J ug/L 11/06/15 19:03 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 13.1 ug/L 11/06/15 19:03 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:03 7440-50-811/03/15 20:0010.0 2.5 1
Lead 4.2J ug/L 11/06/15 19:03 7439-92-111/03/15 20:0010.0 2.5 1
Nickel ND ug/L 11/06/15 19:03 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:03 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:03 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:03 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 19:03 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 19:03 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 06:08 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 06:08 107-13-12001.9 1
Benzene 1.9 ug/L 10/31/15 06:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 06:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 06:08 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 06:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 06:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 06:08 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 06:08 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 06:08 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 06:08 108-90-73.0 0.23 1
Chloroethane 15.5 ug/L 10/31/15 06:08 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 06:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 06:08 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 06:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 06:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 06:08 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.2 ug/L 10/31/15 06:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:08 110-57-61001.0 1
1,1-Dichloroethane 13.0 ug/L 10/31/15 06:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 06:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 06:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 2.0J ug/L 10/31/15 06:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 06:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 06:08 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 06:08 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 06:08 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-4 Lab ID:92273829001 Collected:10/21/15 17:40 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 06:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 06:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 06:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 06:08 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 06:08 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:08 108-10-11000.33 1
Styrene ND ug/L 10/31/15 06:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 06:08 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 06:08 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 06:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 06:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 06:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 06:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 06:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 06:08 108-05-450.0 0.35 1
Vinyl chloride 1.3 ug/L 10/31/15 06:08 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 06:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %10/31/15 06:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %10/31/15 06:08 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 06:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-5 Lab ID:92273829002 Collected:10/21/15 13:35 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:07 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:07 7440-38-211/03/15 20:0010.0 2.5 1
Barium 261 ug/L 11/06/15 19:07 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:07 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:07 7440-43-911/03/15 20:001.0 0.50 1
Chromium ND ug/L 11/06/15 19:07 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt ND ug/L 11/06/15 19:07 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:07 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 19:07 7439-92-111/03/15 20:0010.0 2.5 1
Nickel ND ug/L 11/06/15 19:07 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:07 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:07 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:07 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 19:07 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 19:07 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 06:41 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 06:41 107-13-12001.9 1
Benzene 0.32J ug/L 10/31/15 06:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 06:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 06:41 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 06:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 06:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 06:41 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 06:41 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 06:41 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 06:41 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 06:41 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 06:41 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 06:41 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:41 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 06:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 06:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 06:41 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.1 ug/L 10/31/15 06:41 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:41 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 06:41 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 06:41 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 06:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 06:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 06:41 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 06:41 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 06:41 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 06:41 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-5 Lab ID:92273829002 Collected:10/21/15 13:35 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 06:41 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 06:41 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 06:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 06:41 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 06:41 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:41 108-10-11000.33 1
Styrene ND ug/L 10/31/15 06:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 06:41 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 06:41 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 06:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 06:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 06:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 06:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 06:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 06:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 06:41 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 06:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %10/31/15 06:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %10/31/15 06:41 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 06:41 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-6 Lab ID:92273829003 Collected:10/21/15 14:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony 6.2 ug/L 11/06/15 19:10 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:10 7440-38-211/03/15 20:0010.0 2.5 1
Barium 1640 ug/L 11/06/15 19:10 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:10 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:10 7440-43-911/03/15 20:001.0 0.50 1
Chromium 5.7J ug/L 11/06/15 19:10 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 26.1 ug/L 11/06/15 19:10 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:10 7440-50-811/03/15 20:0010.0 2.5 1
Lead 2.8J ug/L 11/06/15 19:10 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 19.2J ug/L 11/06/15 19:10 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:10 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:10 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:10 7440-28-011/03/15 20:005.5 5.0 1
Vanadium 5.0J ug/L 11/06/15 19:10 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 19:10 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 06:58 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 06:58 107-13-12001.9 1
Benzene 6.6 ug/L 10/31/15 06:58 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 06:58 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 06:58 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 06:58 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 06:58 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 06:58 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 06:58 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 06:58 56-23-51.0 0.25 1
Chlorobenzene 1.7J ug/L 10/31/15 06:58 108-90-73.0 0.23 1
Chloroethane 2.6J ug/L 10/31/15 06:58 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 06:58 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 06:58 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 06:58 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 06:58 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 06:58 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 06:58 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 06:58 95-50-15.0 0.30 1
1,4-Dichlorobenzene 4.1 ug/L 10/31/15 06:58 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 06:58 110-57-61001.0 1
1,1-Dichloroethane 2.0J ug/L 10/31/15 06:58 75-34-35.0 0.32 1
1,2-Dichloroethane 0.38J ug/L 10/31/15 06:58 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 06:58 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 06:58 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 06:58 156-60-55.0 0.49 1
1,2-Dichloropropane 0.88J ug/L 10/31/15 06:58 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 06:58 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 06:58 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-6 Lab ID:92273829003 Collected:10/21/15 14:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 06:58 10061-02-61.0 0.26 1
Ethylbenzene 4.2 ug/L 10/31/15 06:58 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 06:58 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 06:58 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 06:58 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 06:58 108-10-11000.33 1
Styrene ND ug/L 10/31/15 06:58 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 06:58 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 06:58 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 06:58 127-18-41.0 0.46 1
Toluene 0.27J ug/L 10/31/15 06:58 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 06:58 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 06:58 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 06:58 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 06:58 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 06:58 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 06:58 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 06:58 75-01-41.0 0.62 1
Xylene (Total)1.3J ug/L 10/31/15 06:58 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %10/31/15 06:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 06:58 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 06:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-8 Lab ID:92273829004 Collected:10/21/15 15:40 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:13 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:13 7440-38-211/03/15 20:0010.0 2.5 1
Barium 66.8J ug/L 11/06/15 19:13 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:13 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:13 7440-43-911/03/15 20:001.0 0.50 1
Chromium ND ug/L 11/06/15 19:13 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt ND ug/L 11/06/15 19:13 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:13 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 19:13 7439-92-111/03/15 20:0010.0 2.5 1
Nickel ND ug/L 11/06/15 19:13 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:13 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:13 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:13 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 19:13 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 19:13 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 07:15 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 07:15 107-13-12001.9 1
Benzene ND ug/L 10/31/15 07:15 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 07:15 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 07:15 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 07:15 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 07:15 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 07:15 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 07:15 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 07:15 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 07:15 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 07:15 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 07:15 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 07:15 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:15 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 07:15 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:15 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 07:15 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 07:15 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/31/15 07:15 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:15 110-57-61001.0 1
1,1-Dichloroethane 0.72J ug/L 10/31/15 07:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 07:15 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 07:15 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 07:15 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 07:15 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 07:15 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 07:15 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 07:15 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-8 Lab ID:92273829004 Collected:10/21/15 15:40 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 07:15 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 07:15 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 07:15 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 07:15 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 07:15 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:15 108-10-11000.33 1
Styrene ND ug/L 10/31/15 07:15 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:15 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:15 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 07:15 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 07:15 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 07:15 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 07:15 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 07:15 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 07:15 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 07:15 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 07:15 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 07:15 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 07:15 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 07:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 07:15 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 07:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-16 Lab ID:92273829005 Collected:10/21/15 14:35 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:26 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:26 7440-38-211/03/15 20:0010.0 2.5 1
Barium 1100 ug/L 11/06/15 19:26 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:26 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:26 7440-43-911/03/15 20:001.0 0.50 1
Chromium 3.7J ug/L 11/06/15 19:26 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 15.6 ug/L 11/06/15 19:26 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:26 7440-50-811/03/15 20:0010.0 2.5 1
Lead 3.3J ug/L 11/06/15 19:26 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 5.4J ug/L 11/06/15 19:26 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:26 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:26 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:26 7440-28-011/03/15 20:005.5 5.0 1
Vanadium 6.4J ug/L 11/06/15 19:26 7440-62-211/03/15 20:0025.0 2.5 1
Zinc 8.1J ug/L 11/06/15 19:26 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 07:31 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 07:31 107-13-12001.9 1
Benzene 1.9 ug/L 10/31/15 07:31 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 07:31 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 07:31 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 07:31 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 07:31 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 07:31 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 07:31 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 07:31 56-23-51.0 0.25 1
Chlorobenzene 0.92J ug/L 10/31/15 07:31 108-90-73.0 0.23 1
Chloroethane 1.8J ug/L 10/31/15 07:31 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 07:31 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 07:31 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:31 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 07:31 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:31 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 07:31 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 07:31 95-50-15.0 0.30 1
1,4-Dichlorobenzene 4.5 ug/L 10/31/15 07:31 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:31 110-57-61001.0 1
1,1-Dichloroethane 0.72J ug/L 10/31/15 07:31 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 07:31 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 07:31 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 07:31 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 07:31 156-60-55.0 0.49 1
1,2-Dichloropropane 0.41J ug/L 10/31/15 07:31 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 07:31 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 07:31 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-16 Lab ID:92273829005 Collected:10/21/15 14:35 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 07:31 10061-02-61.0 0.26 1
Ethylbenzene 0.56J ug/L 10/31/15 07:31 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 07:31 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 07:31 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 07:31 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:31 108-10-11000.33 1
Styrene ND ug/L 10/31/15 07:31 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:31 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:31 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 07:31 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 07:31 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 07:31 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 07:31 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 07:31 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 07:31 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 07:31 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 07:31 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 07:31 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 07:31 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 07:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %10/31/15 07:31 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 07:31 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-17 Lab ID:92273829006 Collected:10/21/15 15:05 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony 3.8J ug/L 11/06/15 19:41 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:41 7440-38-211/03/15 20:0010.0 2.5 1
Barium 1300 ug/L 11/06/15 19:41 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:41 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 19:41 7440-43-911/03/15 20:001.0 0.50 1
Chromium 4.4J ug/L 11/06/15 19:41 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 17.1 ug/L 11/06/15 19:41 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:41 7440-50-811/03/15 20:0010.0 2.5 1
Lead 3.0J ug/L 11/06/15 19:41 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 6.0J ug/L 11/06/15 19:41 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:41 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:41 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:41 7440-28-011/03/15 20:005.5 5.0 1
Vanadium 13.7J ug/L 11/06/15 19:41 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 19:41 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 07:48 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 07:48 107-13-12001.9 1
Benzene 2.0 ug/L 10/31/15 07:48 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 07:48 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 07:48 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 07:48 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 07:48 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 07:48 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 07:48 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 07:48 56-23-51.0 0.25 1
Chlorobenzene 0.94J ug/L 10/31/15 07:48 108-90-73.0 0.23 1
Chloroethane 1.8J ug/L 10/31/15 07:48 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 07:48 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 07:48 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 07:48 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 07:48 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 07:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 07:48 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 07:48 95-50-15.0 0.30 1
1,4-Dichlorobenzene 4.8 ug/L 10/31/15 07:48 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 07:48 110-57-61001.0 1
1,1-Dichloroethane 0.74J ug/L 10/31/15 07:48 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 07:48 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 07:48 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 07:48 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 07:48 156-60-55.0 0.49 1
1,2-Dichloropropane 0.43J ug/L 10/31/15 07:48 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 07:48 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 07:48 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-17 Lab ID:92273829006 Collected:10/21/15 15:05 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 07:48 10061-02-61.0 0.26 1
Ethylbenzene 0.59J ug/L 10/31/15 07:48 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 07:48 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 07:48 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 07:48 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 07:48 108-10-11000.33 1
Styrene ND ug/L 10/31/15 07:48 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 07:48 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 07:48 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 07:48 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 07:48 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 07:48 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 07:48 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 07:48 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 07:48 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 07:48 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 07:48 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 07:48 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 07:48 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %10/31/15 07:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %10/31/15 07:48 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 07:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-18 Lab ID:92273829007 Collected:10/21/15 11:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:50 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:50 7440-38-211/03/15 20:0010.0 2.5 1
Barium 224 ug/L 11/06/15 19:50 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:50 7440-41-711/03/15 20:001.0 0.50 1
Cadmium 1.2 ug/L 11/06/15 19:50 7440-43-911/03/15 20:001.0 0.50 1
Chromium ND ug/L 11/06/15 19:50 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 10.7 ug/L 11/06/15 19:50 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:50 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 19:50 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 6.5J ug/L 11/06/15 19:50 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:50 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:50 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:50 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 19:50 7440-62-211/03/15 20:0025.0 2.5 1
Zinc 11.9 ug/L 11/06/15 19:50 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 08:05 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 08:05 107-13-12001.9 1
Benzene ND ug/L 10/31/15 08:05 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 08:05 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 08:05 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 08:05 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 08:05 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 08:05 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 08:05 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 08:05 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 08:05 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 08:05 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 08:05 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 08:05 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:05 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 08:05 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:05 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 08:05 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 08:05 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.88J ug/L 10/31/15 08:05 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:05 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 08:05 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 08:05 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 08:05 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.20J ug/L 10/31/15 08:05 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 08:05 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 08:05 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 08:05 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 08:05 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-18 Lab ID:92273829007 Collected:10/21/15 11:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 08:05 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 08:05 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 08:05 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 08:05 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 08:05 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:05 108-10-11000.33 1
Styrene ND ug/L 10/31/15 08:05 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:05 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:05 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 08:05 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 08:05 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 08:05 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 08:05 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 08:05 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 08:05 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 08:05 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 08:05 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 08:05 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 08:05 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 08:05 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/31/15 08:05 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 08:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-19 Lab ID:92273829008 Collected:10/21/15 11:30 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 19:53 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 19:53 7440-38-211/03/15 20:0010.0 2.5 1
Barium 294 ug/L 11/06/15 19:53 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 19:53 7440-41-711/03/15 20:001.0 0.50 1
Cadmium 1.1 ug/L 11/06/15 19:53 7440-43-911/03/15 20:001.0 0.50 1
Chromium 4.4J ug/L 11/06/15 19:53 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt ND ug/L 11/06/15 19:53 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 19:53 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 19:53 7439-92-111/03/15 20:0010.0 2.5 1
Nickel ND ug/L 11/06/15 19:53 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 19:53 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 19:53 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 19:53 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 19:53 7440-62-211/03/15 20:0025.0 2.5 1
Zinc 15.9 ug/L 11/06/15 19:53 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 08:22 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 08:22 107-13-12001.9 1
Benzene ND ug/L 10/31/15 08:22 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 08:22 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 08:22 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 08:22 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 08:22 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 08:22 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 08:22 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 08:22 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 08:22 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 08:22 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 08:22 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 08:22 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:22 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 08:22 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:22 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 08:22 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 08:22 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/31/15 08:22 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:22 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 08:22 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 08:22 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 08:22 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/31/15 08:22 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 08:22 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 08:22 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 08:22 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 08:22 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-19 Lab ID:92273829008 Collected:10/21/15 11:30 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 08:22 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 08:22 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 08:22 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 08:22 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 08:22 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:22 108-10-11000.33 1
Styrene ND ug/L 10/31/15 08:22 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:22 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:22 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 08:22 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 08:22 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 08:22 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 08:22 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 08:22 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 08:22 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 08:22 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 08:22 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/31/15 08:22 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 08:22 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 08:22 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %10/31/15 08:22 17060-07-070-130 1
Toluene-d8 (S)100 %10/31/15 08:22 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-20 Lab ID:92273829009 Collected:10/21/15 12:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 20:12 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 20:12 7440-38-211/03/15 20:0010.0 2.5 1
Barium 567 ug/L 11/06/15 20:12 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 20:12 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 20:12 7440-43-911/03/15 20:001.0 0.50 1
Chromium ND ug/L 11/06/15 20:12 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 17.3 ug/L 11/06/15 20:12 7440-48-411/03/15 20:0010.0 2.5 1
Copper ND ug/L 11/06/15 20:12 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 20:12 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 5.0J ug/L 11/06/15 20:12 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 20:12 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 20:12 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 20:12 7440-28-011/03/15 20:005.5 5.0 1
Vanadium ND ug/L 11/06/15 20:12 7440-62-211/03/15 20:0025.0 2.5 1
Zinc ND ug/L 11/06/15 20:12 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 08:39 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 08:39 107-13-12001.9 1
Benzene 0.68J ug/L 10/31/15 08:39 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 08:39 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 08:39 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 08:39 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 08:39 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 08:39 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 08:39 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 08:39 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 08:39 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 08:39 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 08:39 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 08:39 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:39 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 08:39 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:39 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 08:39 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 08:39 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.2 ug/L 10/31/15 08:39 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:39 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/31/15 08:39 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 08:39 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 08:39 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.52J ug/L 10/31/15 08:39 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 08:39 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 08:39 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 08:39 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 08:39 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-20 Lab ID:92273829009 Collected:10/21/15 12:00 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 08:39 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 08:39 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 08:39 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 08:39 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 08:39 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:39 108-10-11000.33 1
Styrene ND ug/L 10/31/15 08:39 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:39 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:39 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/31/15 08:39 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 08:39 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 08:39 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 08:39 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/31/15 08:39 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 08:39 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 08:39 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 08:39 108-05-450.0 0.35 1
Vinyl chloride 0.68J ug/L 10/31/15 08:39 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 08:39 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %10/31/15 08:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %10/31/15 08:39 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 08:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-21 Lab ID:92273829010 Collected:10/21/15 16:15 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/06/15 20:18 7440-36-011/03/15 20:006.0 3.8 1
Arsenic ND ug/L 11/06/15 20:18 7440-38-211/03/15 20:0010.0 2.5 1
Barium 1430 ug/L 11/06/15 20:18 7440-39-311/03/15 20:001002.5 1
Beryllium ND ug/L 11/06/15 20:18 7440-41-711/03/15 20:001.0 0.50 1
Cadmium ND ug/L 11/06/15 20:18 7440-43-911/03/15 20:001.0 0.50 1
Chromium 4.6J ug/L 11/06/15 20:18 7440-47-311/03/15 20:0010.0 2.5 1
Cobalt 58.0 ug/L 11/06/15 20:18 7440-48-411/03/15 20:0010.0 2.5 1
Copper 8.8J ug/L 11/06/15 20:18 7440-50-811/03/15 20:0010.0 2.5 1
Lead ND ug/L 11/06/15 20:18 7439-92-111/03/15 20:0010.0 2.5 1
Nickel 20.0J ug/L 11/06/15 20:18 7440-02-011/03/15 20:0050.0 2.5 1
Selenium ND ug/L 11/06/15 20:18 7782-49-211/03/15 20:0010.0 5.0 1
Silver ND ug/L 11/06/15 20:18 7440-22-411/03/15 20:0010.0 2.5 1
Thallium ND ug/L 11/06/15 20:18 7440-28-011/03/15 20:005.5 5.0 1
Vanadium 5.0J ug/L 11/06/15 20:18 7440-62-211/03/15 20:0025.0 2.5 1
Zinc 14.3 ug/L 11/06/15 20:18 7440-66-611/03/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/31/15 08:55 67-64-110010.0 1
Acrylonitrile ND ug/L 10/31/15 08:55 107-13-12001.9 1
Benzene 2.0 ug/L 10/31/15 08:55 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/31/15 08:55 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/31/15 08:55 75-27-41.0 0.18 1
Bromoform ND ug/L 10/31/15 08:55 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/31/15 08:55 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/31/15 08:55 78-93-31000.96 1
Carbon disulfide ND ug/L 10/31/15 08:55 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/31/15 08:55 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/31/15 08:55 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/31/15 08:55 75-00-310.0 0.54 1
Chloroform ND ug/L 10/31/15 08:55 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/31/15 08:55 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/31/15 08:55 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/31/15 08:55 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/31/15 08:55 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/31/15 08:55 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/31/15 08:55 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.68J ug/L 10/31/15 08:55 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/31/15 08:55 110-57-61001.0 1
1,1-Dichloroethane 3.5J ug/L 10/31/15 08:55 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/31/15 08:55 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/31/15 08:55 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 4.5J ug/L 10/31/15 08:55 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/31/15 08:55 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/31/15 08:55 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 10/31/15 08:55 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 10/31/15 08:55 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Sample:MW-21 Lab ID:92273829010 Collected:10/21/15 16:15 Received:10/28/15 08:28 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 10/31/15 08:55 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 10/31/15 08:55 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/31/15 08:55 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/31/15 08:55 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/31/15 08:55 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/31/15 08:55 108-10-11000.33 1
Styrene ND ug/L 10/31/15 08:55 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/31/15 08:55 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/31/15 08:55 79-34-53.0 0.40 1
Tetrachloroethene 2.5 ug/L 10/31/15 08:55 127-18-41.0 0.46 1
Toluene ND ug/L 10/31/15 08:55 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/31/15 08:55 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/31/15 08:55 79-00-51.0 0.29 1
Trichloroethene 2.4 ug/L 10/31/15 08:55 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/31/15 08:55 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/31/15 08:55 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/31/15 08:55 108-05-450.0 0.35 1
Vinyl chloride 1.7 ug/L 10/31/15 08:55 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/31/15 08:55 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %10/31/15 08:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %10/31/15 08:55 17060-07-070-130 1
Toluene-d8 (S)101 %10/31/15 08:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19950
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273829001, 92273829002, 92273829003, 92273829004, 92273829005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1598090
Associated Lab Samples:92273829001, 92273829002, 92273829003, 92273829004, 92273829005
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/06/15 17:493.8
Arsenic ug/L ND 10.0 11/06/15 17:492.5
Barium ug/L ND 100 11/06/15 17:492.5
Beryllium ug/L ND 1.0 11/06/15 17:490.50
Cadmium ug/L ND 1.0 11/06/15 17:490.50
Chromium ug/L ND 10.0 11/06/15 17:492.5
Cobalt ug/L ND 10.0 11/06/15 17:492.5
Copper ug/L ND 10.0 11/06/15 17:492.5
Lead ug/L ND 10.0 11/06/15 17:492.5
Nickel ug/L ND 50.0 11/06/15 17:492.5
Selenium ug/L ND 10.0 11/06/15 17:495.0
Silver ug/L ND 10.0 11/06/15 17:492.5
Thallium ug/L ND 5.5 11/06/15 17:495.0
Vanadium ug/L ND 25.0 11/06/15 17:492.5
Zinc ug/L ND 10.0 11/06/15 17:495.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1598091LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 454500 91 80-120
Arsenic ug/L 476500 95 80-120
Barium ug/L 478500 96 80-120
Beryllium ug/L 476500 95 80-120
Cadmium ug/L 484500 97 80-120
Chromium ug/L 475500 95 80-120
Cobalt ug/L 482500 96 80-120
Copper ug/L 495500 99 80-120
Lead ug/L 481500 96 80-120
Nickel ug/L 480500 96 80-120
Selenium ug/L 481500 96 80-120
Silver ug/L 220250 88 80-120
Thallium ug/L 480500 96 80-120
Vanadium ug/L 475500 95 80-120
Zinc ug/L 472500 94 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1598092MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273640002
1598093
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 87 75-12591 5 25500ND438458
Arsenic ug/L 500 92 75-12596 3 25500ND462479
Barium ug/L 500 94 75-12596 3 2550011.3J 480 493
Beryllium ug/L 500 94 75-12596 3 25500ND469482
Cadmium ug/L 500 92 75-12596 4 255002.4 464 482
Chromium ug/L 500 92 75-12595 4 25500ND461478
Cobalt ug/L 500 92 75-12595 4 25500ND460477
Copper ug/L 500 96 75-125100 4 25500ND480500
Lead ug/L 500 91 75-12595 4 25500ND457474
Nickel ug/L 500 91 75-12594 4 255003.0J 458 475
Selenium ug/L 500 92 75-12596 4 25500ND461479
Silver ug/L 250 84 75-12588 4 25250ND211220
Thallium ug/L 500 92 75-12595 4 25500ND460476
Vanadium ug/L 500 93 75-12596 4 25500ND464482
Zinc ug/L 500 91 75-12594 4 255009.7J 463 479
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19951
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273829006, 92273829007, 92273829008, 92273829009, 92273829010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1598097
Associated Lab Samples:92273829006, 92273829007, 92273829008, 92273829009, 92273829010
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/06/15 19:353.8
Arsenic ug/L 4.4J 10.0 11/06/15 19:352.5
Barium ug/L ND 100 11/06/15 19:352.5
Beryllium ug/L ND 1.0 11/06/15 19:350.50
Cadmium ug/L ND 1.0 11/06/15 19:350.50
Chromium ug/L ND 10.0 11/06/15 19:352.5
Cobalt ug/L ND 10.0 11/06/15 19:352.5
Copper ug/L ND 10.0 11/06/15 19:352.5
Lead ug/L ND 10.0 11/06/15 19:352.5
Nickel ug/L ND 50.0 11/06/15 19:352.5
Selenium ug/L ND 10.0 11/06/15 19:355.0
Silver ug/L ND 10.0 11/06/15 19:352.5
Thallium ug/L ND 5.5 11/06/15 19:355.0
Vanadium ug/L ND 25.0 11/06/15 19:352.5
Zinc ug/L ND 10.0 11/06/15 19:355.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1598098LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 454500 91 80-120
Arsenic ug/L 478500 96 80-120
Barium ug/L 470500 94 80-120
Beryllium ug/L 461500 92 80-120
Cadmium ug/L 475500 95 80-120
Chromium ug/L 468500 94 80-120
Cobalt ug/L 481500 96 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 481500 96 80-120
Nickel ug/L 474500 95 80-120
Selenium ug/L 478500 96 80-120
Silver ug/L 217250 87 80-120
Thallium ug/L 473500 95 80-120
Vanadium ug/L 460500 92 80-120
Zinc ug/L 480500 96 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1598099MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273829006
1598100
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 89 75-125101 13 255003.8J 446 510
Arsenic ug/L 500 96 75-125109 13 25500ND481547
Barium ug/L 500 75 75-12587 4 25500130016801740
Beryllium ug/L 500 91 75-125103 12 25500ND455516
Cadmium ug/L 500 93 75-125106 13 25500ND465529
Chromium ug/L 500 90 75-125102 13 255004.4J 454 515
Cobalt ug/L 500 90 75-125102 12 2550017.1 466 528
Copper ug/L 500 98 75-125111 12 25500ND490553
Lead ug/L 500 89 75-125101 13 255003.0J 446 508
Nickel ug/L 500 88 75-125100 13 255006.0J 445 506
Selenium ug/L 500 93 75-125106 12 25500ND467530
Silver ug/L 250 87 75-12598 12 25250ND217246
Thallium ug/L 500 83 75-12596 14 25500ND416480
Vanadium ug/L 500 91 75-125103 13 2550013.7J 468 531
Zinc ug/L 500 90 75-125103 13 25500ND453516
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1598128MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273908002
1598129
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 90 75-12591 1 25500ND452458
Arsenic ug/L 500 95 75-12597 2 25500ND475487
Barium ug/L 500 94 75-12596 2 2550026.6 496 505
Beryllium ug/L 500 92 75-12594 2 25500ND462470
Cadmium ug/L 500 94 75-12595 2 25500ND470477
Chromium ug/L 500 93 75-12595 2 25500ND466474
Cobalt ug/L 500 94 75-12596 2 25500ND472480
Copper ug/L 500 98 75-125100 2 255003.4J 493 503
Lead ug/L 500 94 75-12595 2 25500ND470478
Nickel ug/L 500 92 75-12594 2 255008.5 470 478
Selenium ug/L 500 94 75-12596 2 25500ND471480
Silver ug/L 250 86 75-12588 2 25250ND215220
Thallium ug/L 500 93 75-12594 1 25500ND464470
Vanadium ug/L 500 92 75-12594 2 255004.0J 465 474
Zinc ug/L 500 94 75-12596 2 2550019.7 492 499
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34070
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273829001, 92273829002, 92273829003, 92273829004, 92273829005, 92273829006, 92273829007,
92273829008, 92273829009, 92273829010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596025
Associated Lab Samples:92273829001, 92273829002, 92273829003, 92273829004, 92273829005, 92273829006, 92273829007,
92273829008, 92273829009, 92273829010
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/31/15 00:000.33
1,1,1-Trichloroethane ug/L ND 1.0 10/31/15 00:000.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/31/15 00:000.40
1,1,2-Trichloroethane ug/L ND 1.0 10/31/15 00:000.29
1,1-Dichloroethane ug/L ND 5.0 10/31/15 00:000.32
1,1-Dichloroethene ug/L ND 5.0 10/31/15 00:000.56
1,2,3-Trichloropropane ug/L ND 1.0 10/31/15 00:000.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/31/15 00:002.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/31/15 00:000.27
1,2-Dichlorobenzene ug/L ND 5.0 10/31/15 00:000.30
1,2-Dichloroethane ug/L ND 1.0 10/31/15 00:000.24
1,2-Dichloropropane ug/L ND 1.0 10/31/15 00:000.27
1,3-Dichloropropane ug/L ND 1.0 10/31/15 00:000.28
1,4-Dichlorobenzene ug/L ND 1.0 10/31/15 00:000.33
2-Butanone (MEK)ug/L ND 100 10/31/15 00:000.96
2-Hexanone ug/L ND 50.0 10/31/15 00:000.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/31/15 00:000.33
Acetone ug/L ND 100 10/31/15 00:0010.0
Acrylonitrile ug/L ND 200 10/31/15 00:001.9
Benzene ug/L ND 1.0 10/31/15 00:000.25
Bromochloromethane ug/L ND 3.0 10/31/15 00:000.17
Bromodichloromethane ug/L ND 1.0 10/31/15 00:000.18
Bromoform ug/L ND 3.0 10/31/15 00:000.26
Bromomethane ug/L ND 10.0 10/31/15 00:000.29
Carbon disulfide ug/L ND 100 10/31/15 00:001.2
Carbon tetrachloride ug/L ND 1.0 10/31/15 00:000.25
Chlorobenzene ug/L ND 3.0 10/31/15 00:000.23
Chloroethane ug/L ND 10.0 10/31/15 00:000.54
Chloroform ug/L ND 5.0 10/31/15 00:000.14
Chloromethane ug/L ND 1.0 10/31/15 00:000.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/31/15 00:000.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/31/15 00:000.13
Dibromochloromethane ug/L ND 3.0 10/31/15 00:000.21
Dibromomethane ug/L ND 10.0 10/31/15 00:000.21
Ethylbenzene ug/L ND 1.0 10/31/15 00:000.30
Iodomethane ug/L ND 10.0 10/31/15 00:000.32
Methylene Chloride ug/L ND 1.0 10/31/15 00:000.97
Styrene ug/L ND 1.0 10/31/15 00:000.26
Tetrachloroethene ug/L ND 1.0 10/31/15 00:000.46
Toluene ug/L ND 1.0 10/31/15 00:000.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596025
Associated Lab Samples:92273829001, 92273829002, 92273829003, 92273829004, 92273829005, 92273829006, 92273829007,
92273829008, 92273829009, 92273829010
Matrix:Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 5.0 10/31/15 00:000.49
trans-1,3-Dichloropropene ug/L ND 1.0 10/31/15 00:000.26
trans-1,4-Dichloro-2-butene ug/L ND 100 10/31/15 00:001.0
Trichloroethene ug/L ND 1.0 10/31/15 00:000.47
Trichlorofluoromethane ug/L ND 1.0 10/31/15 00:000.20
Vinyl acetate ug/L ND 50.0 10/31/15 00:000.35
Vinyl chloride ug/L ND 1.0 10/31/15 00:000.62
Xylene (Total)ug/L ND 5.0 10/31/15 00:000.66
1,2-Dichloroethane-d4 (S)%103 70-130 10/31/15 00:00
4-Bromofluorobenzene (S)%100 70-130 10/31/15 00:00
Toluene-d8 (S)%102 70-130 10/31/15 00:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596026LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.550 99 80-125
1,1,1-Trichloroethane ug/L 52.450 105 71-129
1,1,2,2-Tetrachloroethane ug/L 50.350 101 79-124
1,1,2-Trichloroethane ug/L 47.350 95 85-125
1,1-Dichloroethane ug/L 50.950 102 73-126
1,1-Dichloroethene ug/L 54.250 108 66-135
1,2,3-Trichloropropane ug/L 48.550 97 75-130
1,2-Dibromo-3-chloropropane ug/L 50.850 102 71-133
1,2-Dibromoethane (EDB)ug/L 49.950 100 83-124
1,2-Dichlorobenzene ug/L 49.450 99 80-133
1,2-Dichloroethane ug/L 44.450 89 67-128
1,2-Dichloropropane ug/L 48.050 96 75-132
1,3-Dichloropropane ug/L 49.650 99 76-131
1,4-Dichlorobenzene ug/L 48.650 97 78-130
2-Butanone (MEK)ug/L 93.9J100 94 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 100100 100 72-135
Acetone ug/L 89.7J100 90 48-146
Acrylonitrile ug/L 245250 98 40-160
Benzene ug/L 50.250 100 80-125
Bromochloromethane ug/L 51.450 103 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 49.850 100 71-128
Bromomethane ug/L 47.150 94 40-160
Carbon disulfide ug/L 52.7J50 105 50-160
Carbon tetrachloride ug/L 53.350 107 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 48.050 96 39-148
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596026LABORATORY CONTROL SAMPLE:
LCSSpike
Chloroform ug/L 49.950 100 73-127
Chloromethane ug/L 50.250 100 44-146
cis-1,2-Dichloroethene ug/L 48.750 97 74-124
cis-1,3-Dichloropropene ug/L 50.550 101 72-132
Dibromochloromethane ug/L 51.750 103 78-125
Dibromomethane ug/L 48.750 97 82-120
Ethylbenzene ug/L 50.150 100 79-121
Iodomethane ug/L 101100 101 39-154
Methylene Chloride ug/L 53.350 107 64-133
Styrene ug/L 50.650 101 84-126
Tetrachloroethene ug/L 50.350 101 78-122
Toluene ug/L 49.250 98 80-121
trans-1,2-Dichloroethene ug/L 50.850 102 71-127
trans-1,3-Dichloropropene ug/L 49.150 98 69-141
trans-1,4-Dichloro-2-butene ug/L 47.8J50 96 40-160
Trichloroethene ug/L 48.250 96 78-122
Trichlorofluoromethane ug/L 52.550 105 53-137
Vinyl acetate ug/L 102100 102 40-160
Vinyl chloride ug/L 58.950 118 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596027MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330006
1,1,1,2-Tetrachloroethane ug/L 21.120 106 70-130ND
1,1,1-Trichloroethane ug/L 23.920 120 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.320 106 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 23.520 118 70-130ND
1,1-Dichloroethene ug/L 25.420 127 70-166ND
1,2,3-Trichloropropane ug/L 20.320 101 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.420 107 70-130ND
1,2-Dichlorobenzene ug/L 21.220 106 70-130ND
1,2-Dichloroethane ug/L 19.920 99 70-130ND
1,2-Dichloropropane ug/L 21.220 106 70-130ND
1,3-Dichloropropane ug/L 21.620 108 70-130ND
1,4-Dichlorobenzene ug/L 21.120 105 70-130ND
2-Butanone (MEK)ug/L 40.5J40 101 70-130ND
2-Hexanone ug/L 41.4J40 103 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.7J40 104 70-130ND
Acetone ug/L 42.2J40 101 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596027MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330006
Acrylonitrile ug/L 106J100 106 70-130ND
Benzene ug/L 22.420 112 70-148ND
Bromochloromethane ug/L 23.420 117 70-130ND
Bromodichloromethane ug/L 21.620 108 70-130ND
Bromoform ug/L 19.220 96 70-130ND
Bromomethane ug/L 18.920 94 70-130ND
Carbon disulfide ug/L 23.7J20 118 70-130ND
Carbon tetrachloride ug/L 23.920 119 70-130ND
Chlorobenzene ug/L 21.620 108 70-146ND
Chloroethane ug/L 23.020 115 70-130ND
Chloroform ug/L 22.620 113 70-130ND
Chloromethane ug/L 23.820 119 70-130ND
cis-1,2-Dichloroethene ug/L 22.220 111 70-130ND
cis-1,3-Dichloropropene ug/L 20.120 101 70-130ND
Dibromochloromethane ug/L 21.320 107 70-130ND
Dibromomethane ug/L 20.820 104 70-130ND
Ethylbenzene ug/L 22.320 111 70-130ND
Iodomethane ug/L 41.140 103 70-130ND
Methylene Chloride ug/L 23.020 115 70-130ND
Styrene ug/L 21.720 108 70-130ND
Tetrachloroethene ug/L 22.120 110 70-130ND
Toluene ug/L 21.720 109 70-155ND
trans-1,2-Dichloroethene ug/L 23.520 117 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 103 70-130ND
trans-1,4-Dichloro-2-butene ug/L 18.9J20 94 70-130ND
Trichloroethene ug/L 21.320 107 69-151ND
Trichlorofluoromethane ug/L 25.220 126 70-130ND
Vinyl acetate ug/L 34.7J40 87 70-130ND
Vinyl chloride ug/L 27.3 M12013770-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273829001
1596028SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 12.5 4 3013.0
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273829001
1596028SAMPLE DUPLICATE:
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.2 2 301.2
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 1.8 7 301.9
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L 15.1 3 3015.5
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 1.8J 6 302.0J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 1.3 0 301.3
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99 199
4-Bromofluorobenzene (S)%100 298
Toluene-d8 (S)%100 1101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 37
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 37
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273829
ASHE CO. CLOSED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273829001 MPRP/19950 ICP/17987MW-4 EPA 3010 EPA 6010
92273829002 MPRP/19950 ICP/17987MW-5 EPA 3010 EPA 6010
92273829003 MPRP/19950 ICP/17987MW-6 EPA 3010 EPA 6010
92273829004 MPRP/19950 ICP/17987MW-8 EPA 3010 EPA 6010
92273829005 MPRP/19950 ICP/17987MW-16 EPA 3010 EPA 6010
92273829006 MPRP/19951 ICP/17988MW-17 EPA 3010 EPA 6010
92273829007 MPRP/19951 ICP/17988MW-18 EPA 3010 EPA 6010
92273829008 MPRP/19951 ICP/17988MW-19 EPA 3010 EPA 6010
92273829009 MPRP/19951 ICP/17988MW-20 EPA 3010 EPA 6010
92273829010 MPRP/19951 ICP/17988MW-21 EPA 3010 EPA 6010
92273829001 MSV/34070MW-4 EPA 8260
92273829002 MSV/34070MW-5 EPA 8260
92273829003 MSV/34070MW-6 EPA 8260
92273829004 MSV/34070MW-8 EPA 8260
92273829005 MSV/34070MW-16 EPA 8260
92273829006 MSV/34070MW-17 EPA 8260
92273829007 MSV/34070MW-18 EPA 8260
92273829008 MSV/34070MW-19 EPA 8260
92273829009 MSV/34070MW-20 EPA 8260
92273829010 MSV/34070MW-21 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 11:15 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 37
Page 36 of 37
Page 37 of 37
#=CL#
November 03, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273337
92273337
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. LINED MSWLF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 43
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 43
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Lab ID Sample ID Matrix Date Collected Date Received
92273337001 MW-1 Water 10/22/15 15:40 10/26/15 12:15
92273337002 MW-13 Water 10/22/15 11:35 10/26/15 12:15
92273337003 MW-15 Water 10/22/15 10:10 10/26/15 12:15
92273337004 MW-A Water 10/22/15 14:50 10/26/15 12:15
92273337005 MW-28 Water 10/22/15 10:35 10/26/15 12:15
92273337006 MW-29 Water 10/22/15 14:00 10/26/15 12:15
92273337007 MW-30 Water 10/23/15 10:30 10/26/15 12:15
92273337008 UDP Water 10/22/15 10:50 10/26/15 12:15
92273337009 SW-A Water 10/22/15 11:05 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 43
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273337001 MW-1 EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CCAH
92273337002 MW-13 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273337003 MW-15 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273337004 MW-A EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273337005 MW-28 EPA 6010 15 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CCAH
SM 4500-S2D 1 PASI-AMJP
92273337006 MW-29 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273337007 MW-30 EPA 6010 15 PASI-AJMW
EPA 8270 111 PASI-CBPJ
EPA 8260 51 PASI-CCAH
92273337008 UDP EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273337009 SW-A EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-1 Lab ID:92273337001 Collected:10/22/15 15:40 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 22:48 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 22:48 7440-38-210/28/15 20:0010.0 2.5 1
Barium 74.1J ug/L 10/30/15 22:48 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 22:48 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 22:48 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 22:48 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 22:48 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 22:48 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 22:48 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 22:48 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 22:48 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 22:48 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 22:48 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 22:48 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 22:48 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/30/15 16:27 7439-97-610/28/15 17:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:37 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:37 107-13-12001.9 1
Benzene ND ug/L 11/01/15 01:37 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:37 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:37 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:37 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:37 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:37 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:37 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:37 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:37 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 01:37 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:37 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 01:37 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:37 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:37 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:37 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:37 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:37 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 01:37 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:37 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 01:37 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 01:37 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:37 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 01:37 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:37 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-1 Lab ID:92273337001 Collected:10/22/15 15:40 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 11/01/15 01:37 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:37 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:37 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:37 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:37 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:37 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:37 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:37 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:37 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:37 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:37 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:37 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:37 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:37 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:37 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:37 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 01:37 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 01:37 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:37 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:37 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 01:37 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 01:37 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 01:37 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %11/01/15 01:37 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 01:37 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-13 Lab ID:92273337002 Collected:10/22/15 11:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 22:57 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 22:57 7440-38-210/28/15 20:0010.0 2.5 1
Barium 55.7J ug/L 10/30/15 22:57 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 22:57 7440-41-710/28/15 20:001.0 0.50 1
Cadmium 2.9 ug/L 10/30/15 22:57 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 22:57 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 22:57 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 22:57 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 22:57 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 22:57 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 22:57 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 22:57 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 22:57 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 22:57 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 22:57 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:54 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:54 107-13-12001.9 1
Benzene ND ug/L 11/01/15 01:54 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:54 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:54 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:54 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:54 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:54 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:54 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:54 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:54 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 01:54 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:54 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 01:54 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:54 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:54 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:54 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:54 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:54 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 01:54 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:54 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 01:54 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 01:54 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:54 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 01:54 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:54 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 01:54 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:54 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:54 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-13 Lab ID:92273337002 Collected:10/22/15 11:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:54 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:54 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:54 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:54 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:54 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:54 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:54 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:54 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:54 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:54 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:54 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:54 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:54 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 01:54 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 01:54 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:54 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:54 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 01:54 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 01:54 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 01:54 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 01:54 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 01:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-15 Lab ID:92273337003 Collected:10/22/15 10:10 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:00 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:00 7440-38-210/28/15 20:0010.0 2.5 1
Barium 300 ug/L 10/30/15 23:00 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:00 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:00 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:00 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:00 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:00 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:00 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:00 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:00 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:00 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:00 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:00 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:00 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:10 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:10 107-13-12001.9 1
Benzene ND ug/L 11/01/15 01:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:10 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:10 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:10 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:10 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 01:10 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:10 67-66-35.0 0.14 1
Chloromethane 1.9 ug/L 11/01/15 01:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 01:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:10 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 01:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 01:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:10 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 01:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 01:10 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:10 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:10 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-15 Lab ID:92273337003 Collected:10/22/15 10:10 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:10 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:10 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:10 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 01:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 01:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 01:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 01:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 01:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %11/01/15 01:10 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 01:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-A Lab ID:92273337004 Collected:10/22/15 14:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:03 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:03 7440-38-210/28/15 20:0010.0 2.5 1
Barium 122 ug/L 10/30/15 23:03 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:03 7440-41-710/28/15 20:001.0 0.50 1
Cadmium 3.7 ug/L 10/30/15 23:03 7440-43-910/28/15 20:001.0 0.50 1
Chromium 3.8J ug/L 10/30/15 23:03 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:03 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:03 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:03 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:03 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:03 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:03 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:03 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:03 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:03 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:27 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:27 107-13-12001.9 1
Benzene ND ug/L 11/01/15 01:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:27 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:27 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:27 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:27 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 01:27 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:27 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 01:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 01:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:27 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 01:27 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 01:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 01:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 01:27 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:27 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:27 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-A Lab ID:92273337004 Collected:10/22/15 14:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:27 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:27 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:27 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 01:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 01:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 01:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 01:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 01:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %11/01/15 01:27 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 01:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-28 Lab ID:92273337005 Collected:10/22/15 10:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:06 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:06 7440-38-210/28/15 20:0010.0 2.5 1
Barium 63.0J ug/L 10/30/15 23:06 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:06 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:06 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:06 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:06 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:06 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:06 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:06 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:06 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:06 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:06 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:06 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:06 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/30/15 16:32 7439-97-610/28/15 17:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 01:44 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 01:44 107-13-12001.9 1
Benzene ND ug/L 11/01/15 01:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 01:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 01:44 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 01:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 01:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 01:44 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 01:44 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 01:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 01:44 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 01:44 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 01:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 01:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 01:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 01:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 01:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 01:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 01:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 01:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 01:44 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 01:44 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 01:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 01:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 01:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 01:44 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-28 Lab ID:92273337005 Collected:10/22/15 10:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 11/01/15 01:44 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 01:44 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 01:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 01:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 01:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 01:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 01:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 01:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 01:44 108-10-11000.33 1
Styrene ND ug/L 11/01/15 01:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 01:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 01:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 01:44 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 01:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 01:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 01:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 01:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 01:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 01:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 01:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 01:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 01:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %11/01/15 01:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %11/01/15 01:44 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 01:44 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 10/28/15 18:30 18496-25-810001001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-29 Lab ID:92273337006 Collected:10/22/15 14:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:09 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:09 7440-38-210/28/15 20:0010.0 2.5 1
Barium 58.0J ug/L 10/30/15 23:09 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:09 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:09 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:09 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:09 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:09 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:09 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:09 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:09 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:09 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:09 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:09 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:09 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 02:00 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 02:00 107-13-12001.9 1
Benzene ND ug/L 11/01/15 02:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 02:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 02:00 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 02:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 02:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 02:00 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 02:00 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 02:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 02:00 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 02:00 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 02:00 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 02:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 02:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 02:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 02:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 02:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 02:00 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 02:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 02:00 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 02:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 02:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 02:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 02:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 02:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 02:00 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 02:00 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 02:00 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-29 Lab ID:92273337006 Collected:10/22/15 14:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 02:00 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 02:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 02:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 02:00 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 02:00 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 02:00 108-10-11000.33 1
Styrene ND ug/L 11/01/15 02:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 02:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 02:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 02:00 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 02:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 02:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 02:00 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 02:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 02:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 02:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 02:00 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 02:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 02:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 02:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %11/01/15 02:00 17060-07-070-130 1
Toluene-d8 (S)98 %11/01/15 02:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-30 Lab ID:92273337007 Collected:10/23/15 10:30 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:25 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:25 7440-38-210/28/15 20:0010.0 2.5 1
Barium 123 ug/L 10/30/15 23:25 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:25 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:25 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:25 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:25 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:25 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:25 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:25 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:25 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:25 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:25 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:25 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:25 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 11/02/15 13:21 83-32-910/30/15 11:0010.0 0.25 1
Acenaphthylene ND ug/L 11/02/15 13:21 208-96-810/30/15 11:0010.0 0.21 1
Acetophenone ND ug/L 11/02/15 13:21 98-86-210/30/15 11:0010.0 2.0 1
2-Acetylaminofluorene 7.2J ug/L 11/02/15 13:21 53-96-310/30/15 11:0020.0 0.84 1
4-Aminobiphenyl ND ug/L 11/02/15 13:21 92-67-110/30/15 11:0020.0 0.92 1
Anthracene ND ug/L 11/02/15 13:21 120-12-710/30/15 11:0010.0 0.14 1
Benzo(a)anthracene ND ug/L 11/02/15 13:21 56-55-310/30/15 11:0010.0 0.33 1
Benzo(a)pyrene ND ug/L 11/02/15 13:21 50-32-810/30/15 11:0010.0 0.30 1
Benzo(b)fluoranthene ND ug/L 11/02/15 13:21 205-99-210/30/15 11:0010.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 11/02/15 13:21 191-24-210/30/15 11:0010.0 0.38 1
Benzo(k)fluoranthene ND ug/L 11/02/15 13:21 207-08-9 L310/30/15 11:0010.0 0.43 1
Benzyl alcohol ND ug/L 11/02/15 13:21 100-51-610/30/15 11:0020.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 11/02/15 13:21 101-55-310/30/15 11:0010.0 1.3 1
Butylbenzylphthalate ND ug/L 11/02/15 13:21 85-68-710/30/15 11:0010.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 11/02/15 13:21 59-50-710/30/15 11:0020.0 4.2 1
4-Chloroaniline ND ug/L 11/02/15 13:21 106-47-810/30/15 11:0020.0 3.4 1
Chlorobenzilate ND ug/L 11/02/15 13:21 510-15-6 L310/30/15 11:0010.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 11/02/15 13:21 111-91-110/30/15 11:0010.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 11/02/15 13:21 111-44-410/30/15 11:0010.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 11/02/15 13:21 108-60-110/30/15 11:0010.0 1.6 1
2-Chloronaphthalene ND ug/L 11/02/15 13:21 91-58-710/30/15 11:0010.0 2.2 1
2-Chlorophenol ND ug/L 11/02/15 13:21 95-57-810/30/15 11:0010.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 11/02/15 13:21 7005-72-310/30/15 11:0010.0 2.1 1
Chrysene ND ug/L 11/02/15 13:21 218-01-910/30/15 11:0010.0 0.21 1
Diallate ND ug/L 11/02/15 13:21 2303-16-410/30/15 11:0010.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 11/02/15 13:21 53-70-310/30/15 11:0010.0 0.55 1
Dibenzofuran ND ug/L 11/02/15 13:21 132-64-910/30/15 11:0010.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 11/02/15 13:21 91-94-110/30/15 11:0020.0 1.4 1
2,4-Dichlorophenol ND ug/L 11/02/15 13:21 120-83-210/30/15 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-30 Lab ID:92273337007 Collected:10/23/15 10:30 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2,6-Dichlorophenol ND ug/L 11/02/15 13:21 87-65-010/30/15 11:0010.0 1.8 1
Diethylphthalate ND ug/L 11/02/15 13:21 84-66-210/30/15 11:0060001.3 1
Dimethoate ND ug/L 11/02/15 13:21 60-51-510/30/15 11:0020.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 11/02/15 13:21 60-11-710/30/15 11:0010.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 11/02/15 13:21 57-97-610/30/15 11:0010.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 11/02/15 13:21 119-93-710/30/15 11:0010.0 2.1 1
2,4-Dimethylphenol ND ug/L 11/02/15 13:21 105-67-910/30/15 11:0010.0 2.2 1
Dimethylphthalate ND ug/L 11/02/15 13:21 131-11-310/30/15 11:0010.0 1.5 1
Di-n-butylphthalate ND ug/L 11/02/15 13:21 84-74-210/30/15 11:0010.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 11/02/15 13:21 534-52-110/30/15 11:0050.0 1.7 1
1,3-Dinitrobenzene ND ug/L 11/02/15 13:21 99-65-010/30/15 11:0020.0 1.5 1
2,4-Dinitrophenol ND ug/L 11/02/15 13:21 51-28-510/30/15 11:0050.0 6.5 1
2,4-Dinitrotoluene ND ug/L 11/02/15 13:21 121-14-210/30/15 11:0010.0 1.2 1
2,6-Dinitrotoluene ND ug/L 11/02/15 13:21 606-20-210/30/15 11:0010.0 1.7 1
Di-n-octylphthalate ND ug/L 11/02/15 13:21 117-84-010/30/15 11:0010.0 0.86 1
Diphenylamine ND ug/L 11/02/15 13:21 122-39-410/30/15 11:0010.0 1.3 1
Disulfoton ND ug/L 11/02/15 13:21 298-04-410/30/15 11:0010.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 11/02/15 13:21 117-81-710/30/15 11:0015.0 0.85 1
Ethyl methanesulfonate ND ug/L 11/02/15 13:21 62-50-010/30/15 11:0020.0 1.8 1
Famphur ND ug/L 11/02/15 13:21 52-85-710/30/15 11:0020.0 1.7 1
Fluoranthene ND ug/L 11/02/15 13:21 206-44-010/30/15 11:0010.0 0.21 1
Fluorene ND ug/L 11/02/15 13:21 86-73-710/30/15 11:0010.0 0.21 1
Hexachlorobenzene ND ug/L 11/02/15 13:21 118-74-110/30/15 11:0010.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 11/02/15 13:21 77-47-410/30/15 11:0010.0 1.8 1
Hexachloroethane ND ug/L 11/02/15 13:21 67-72-110/30/15 11:0010.0 1.5 1
Hexachloropropene ND ug/L 11/02/15 13:21 1888-71-710/30/15 11:0010.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 11/02/15 13:21 193-39-510/30/15 11:0010.0 0.29 1
Isodrin ND ug/L 11/02/15 13:21 465-73-610/30/15 11:0020.0 2.0 1
Isophorone ND ug/L 11/02/15 13:21 78-59-110/30/15 11:0010.0 1.8 1
Isosafrole ND ug/L 11/02/15 13:21 120-58-110/30/15 11:0010.0 1.8 1
Kepone ND ug/L 11/02/15 13:21 143-50-010/30/15 11:0020.0 3.1 1
Methapyrilene ND ug/L 11/02/15 13:21 91-80-5 L210/30/15 11:001002.7 1
3-Methylcholanthrene ND ug/L 11/02/15 13:21 56-49-510/30/15 11:0010.0 0.82 1
Methyl methanesulfonate ND ug/L 11/02/15 13:21 66-27-310/30/15 11:0010.0 1.3 1
2-Methylnaphthalene ND ug/L 11/02/15 13:21 91-57-610/30/15 11:0010.0 0.28 1
Methyl parathion ND ug/L 11/02/15 13:21 298-00-010/30/15 11:0010.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 11/02/15 13:21 95-48-710/30/15 11:0010.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 11/02/15 13:21 L310/30/15 11:0010.0 1.7 1
1-Naphthalenamine ND ug/L 11/02/15 13:21 134-32-710/30/15 11:0010.0 0.96 1
2-Naphthalenamine ND ug/L 11/02/15 13:21 91-59-810/30/15 11:0010.0 0.98 1
1,4-Naphthoquinone ND ug/L 11/02/15 13:21 130-15-410/30/15 11:0010.0 1.8 1
2-Nitroaniline ND ug/L 11/02/15 13:21 88-74-410/30/15 11:0050.0 2.8 1
3-Nitroaniline ND ug/L 11/02/15 13:21 99-09-210/30/15 11:0050.0 2.4 1
4-Nitroaniline ND ug/L 11/02/15 13:21 100-01-610/30/15 11:0020.0 2.5 1
Nitrobenzene ND ug/L 11/02/15 13:21 98-95-310/30/15 11:0010.0 1.7 1
2-Nitrophenol ND ug/L 11/02/15 13:21 88-75-510/30/15 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-30 Lab ID:92273337007 Collected:10/23/15 10:30 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitrophenol ND ug/L 11/02/15 13:21 100-02-710/30/15 11:0050.0 5.8 1
5-Nitro-o-toluidine ND ug/L 11/02/15 13:21 99-55-810/30/15 11:0010.0 1.2 1
N-Nitrosodiethylamine ND ug/L 11/02/15 13:21 55-18-510/30/15 11:0020.0 1.8 1
N-Nitrosodimethylamine ND ug/L 11/02/15 13:21 62-75-910/30/15 11:0010.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 11/02/15 13:21 924-16-310/30/15 11:0010.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 11/02/15 13:21 621-64-710/30/15 11:0010.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 11/02/15 13:21 86-30-610/30/15 11:0010.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 11/02/15 13:21 10595-95-610/30/15 11:0010.0 1.8 1
N-Nitrosopiperidine ND ug/L 11/02/15 13:21 100-75-410/30/15 11:0020.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 11/02/15 13:21 930-55-210/30/15 11:0010.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 11/02/15 13:21 126-68-110/30/15 11:0010.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 11/02/15 13:21 56-38-210/30/15 11:0010.0 1.1 1
Pentachlorobenzene ND ug/L 11/02/15 13:21 608-93-510/30/15 11:0010.0 2.0 1
Pentachloronitrobenzene ND ug/L 11/02/15 13:21 82-68-8 L310/30/15 11:0020.0 1.0 1
Pentachlorophenol ND ug/L 11/02/15 13:21 87-86-510/30/15 11:0025.0 2.3 1
Phenacetin ND ug/L 11/02/15 13:21 62-44-210/30/15 11:0020.0 0.97 1
Phenanthrene ND ug/L 11/02/15 13:21 85-01-810/30/15 11:0010.0 0.22 1
Phenol ND ug/L 11/02/15 13:21 108-95-210/30/15 11:0010.0 1.7 1
p-Phenylenediamine ND ug/L 11/02/15 13:21 106-50-310/30/15 11:0010.0 0.96 1
Phorate ND ug/L 11/02/15 13:21 298-02-2 L310/30/15 11:0010.0 1.1 1
Pronamide ND ug/L 11/02/15 13:21 23950-58-510/30/15 11:0010.0 0.97 1
Pyrene ND ug/L 11/02/15 13:21 129-00-0 L310/30/15 11:0010.0 0.19 1
Safrole ND ug/L 11/02/15 13:21 94-59-710/30/15 11:0010.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 11/02/15 13:21 95-94-310/30/15 11:0010.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 11/02/15 13:21 58-90-210/30/15 11:0010.0 2.3 1
Thionazin ND ug/L 11/02/15 13:21 297-97-210/30/15 11:0020.0 1.2 1
O-Toluidine ND ug/L 11/02/15 13:21 95-53-410/30/15 11:0010.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 11/02/15 13:21 95-95-410/30/15 11:0010.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 11/02/15 13:21 88-06-210/30/15 11:0010.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 11/02/15 13:21 99-35-4 L310/30/15 11:0010.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)70 %11/02/15 13:21 4165-60-010/30/15 11:0021-110 1
2-Fluorobiphenyl (S)79 %11/02/15 13:21 321-60-810/30/15 11:0027-110 1
Terphenyl-d14 (S)85 %11/02/15 13:21 1718-51-010/30/15 11:0031-107 1
Phenol-d6 (S)17 %11/02/15 13:21 13127-88-310/30/15 11:0010-110 1
2-Fluorophenol (S)32 %11/02/15 13:21 367-12-410/30/15 11:0012-110 1
2,4,6-Tribromophenol (S)87 %11/02/15 13:21 118-79-610/30/15 11:0027-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 04:31 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 04:31 107-13-12001.9 1
Benzene ND ug/L 11/01/15 04:31 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 04:31 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 04:31 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 04:31 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 04:31 74-83-910.0 0.29 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:MW-30 Lab ID:92273337007 Collected:10/23/15 10:30 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
2-Butanone (MEK)ND ug/L 11/01/15 04:31 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 04:31 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 04:31 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 04:31 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 04:31 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 04:31 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 04:31 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 04:31 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 04:31 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 04:31 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 04:31 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 04:31 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 04:31 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 04:31 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 04:31 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 04:31 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 04:31 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 04:31 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 04:31 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 04:31 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 04:31 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 04:31 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 04:31 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 04:31 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 04:31 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 04:31 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 04:31 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 04:31 108-10-11000.33 1
Styrene ND ug/L 11/01/15 04:31 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 04:31 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 04:31 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 04:31 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 04:31 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 04:31 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 04:31 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 04:31 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 04:31 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 04:31 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 04:31 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 04:31 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 04:31 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %11/01/15 04:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 04:31 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 04:31 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:UDP Lab ID:92273337008 Collected:10/22/15 10:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:28 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:28 7440-38-210/28/15 20:0010.0 2.5 1
Barium 178 ug/L 10/30/15 23:28 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:28 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:28 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:28 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt 3.7J ug/L 10/30/15 23:28 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:28 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:28 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:28 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:28 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:28 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:28 7440-28-010/28/15 20:005.5 5.0 1
Vanadium 2.6J ug/L 10/30/15 23:28 7440-62-210/28/15 20:0025.0 2.5 1
Zinc 9.3J ug/L 10/30/15 23:28 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 02:17 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 02:17 107-13-12001.9 1
Benzene ND ug/L 11/01/15 02:17 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 02:17 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 02:17 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 02:17 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 02:17 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 02:17 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 02:17 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 02:17 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 02:17 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 02:17 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 02:17 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 02:17 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 02:17 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 02:17 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 02:17 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 02:17 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 02:17 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 02:17 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 02:17 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 02:17 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 02:17 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 02:17 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 02:17 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 02:17 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 02:17 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 02:17 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 02:17 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:UDP Lab ID:92273337008 Collected:10/22/15 10:50 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 02:17 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 02:17 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 02:17 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 02:17 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 02:17 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 02:17 108-10-11000.33 1
Styrene ND ug/L 11/01/15 02:17 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 02:17 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 02:17 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 02:17 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 02:17 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 02:17 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 02:17 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 02:17 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 02:17 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 02:17 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 02:17 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 02:17 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 02:17 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 02:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 02:17 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 02:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:SW-A Lab ID:92273337009 Collected:10/22/15 11:05 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:31 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:31 7440-38-210/28/15 20:0010.0 2.5 1
Barium 102 ug/L 10/30/15 23:31 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:31 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:31 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:31 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:31 7440-48-410/28/15 20:0010.0 2.5 1
Copper ND ug/L 10/30/15 23:31 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:31 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:31 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:31 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:31 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:31 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:31 7440-62-210/28/15 20:0025.0 2.5 1
Zinc ND ug/L 10/30/15 23:31 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 02:34 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 02:34 107-13-12001.9 1
Benzene ND ug/L 11/01/15 02:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 02:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 02:34 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 02:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 02:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 02:34 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 02:34 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 02:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 02:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 02:34 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 02:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 02:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 02:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 02:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 02:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 02:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 02:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 02:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 02:34 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 02:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 02:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 02:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 02:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 02:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 02:34 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 02:34 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 02:34 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 43
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Sample:SW-A Lab ID:92273337009 Collected:10/22/15 11:05 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 02:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 02:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 02:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 02:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 02:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 02:34 108-10-11000.33 1
Styrene ND ug/L 11/01/15 02:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 02:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 02:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 02:34 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 02:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 02:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 02:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 02:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 02:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 02:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 02:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 02:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 02:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %11/01/15 02:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %11/01/15 02:34 17060-07-070-130 1
Toluene-d8 (S)101 %11/01/15 02:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8592
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92273337001, 92273337005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593164
Associated Lab Samples:92273337001, 92273337005
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 10/30/15 16:060.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593165LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593166MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273493001
1593167
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 97 75-12596 1 252.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19905
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273337001, 92273337002, 92273337003, 92273337004, 92273337005, 92273337006, 92273337007,
92273337008, 92273337009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593024
Associated Lab Samples:92273337001, 92273337002, 92273337003, 92273337004, 92273337005, 92273337006, 92273337007,
92273337008, 92273337009
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/30/15 22:423.8
Arsenic ug/L ND 10.0 10/30/15 22:422.5
Barium ug/L ND 100 10/30/15 22:422.5
Beryllium ug/L ND 1.0 10/30/15 22:420.50
Cadmium ug/L ND 1.0 10/30/15 22:420.50
Chromium ug/L ND 10.0 10/30/15 22:422.5
Cobalt ug/L ND 10.0 10/30/15 22:422.5
Copper ug/L ND 10.0 10/30/15 22:422.5
Lead ug/L ND 10.0 10/30/15 22:422.5
Nickel ug/L ND 50.0 10/30/15 22:422.5
Selenium ug/L ND 10.0 10/30/15 22:425.0
Silver ug/L ND 10.0 10/30/15 22:422.5
Thallium ug/L ND 5.5 10/30/15 22:425.0
Vanadium ug/L ND 25.0 10/30/15 22:422.5
Zinc ug/L ND 10.0 10/30/15 22:425.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593025LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 491500 98 80-120
Arsenic ug/L 464500 93 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 482500 96 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 471500 94 80-120
Nickel ug/L 469500 94 80-120
Selenium ug/L 466500 93 80-120
Silver ug/L 237250 95 80-120
Thallium ug/L 465500 93 80-120
Vanadium ug/L 481500 96 80-120
Zinc ug/L 445500 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337001
1593027
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-12592 13 25500ND530464
Arsenic ug/L 500 101 75-12588 13 25500ND504441
Barium ug/L 500 107 75-12593 12 2550074.1J 607 539
Beryllium ug/L 500 109 75-12595 13 25500ND543475
Cadmium ug/L 500 105 75-12592 13 25500ND527461
Chromium ug/L 500 105 75-12593 13 25500ND528465
Cobalt ug/L 500 103 75-12591 13 25500ND517453
Copper ug/L 500 109 75-12594 15 25500ND544469
Lead ug/L 500 104 75-12590 13 25500ND518452
Nickel ug/L 500 104 75-12591 13 25500ND522457
Selenium ug/L 500 101 75-12588 14 25500ND505441
Silver ug/L 250 105 75-12591 14 25250ND262228
Thallium ug/L 500 102 75-12589 13 25500ND509446
Vanadium ug/L 500 108 75-12595 13 25500ND538473
Zinc ug/L 500 101 75-12588 13 25500ND506443
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273337001, 92273337002, 92273337003, 92273337004, 92273337005, 92273337006, 92273337007,
92273337008, 92273337009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273337001, 92273337002, 92273337003, 92273337004, 92273337005, 92273337006, 92273337007,
92273337008, 92273337009
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273337001, 92273337002, 92273337003, 92273337004, 92273337005, 92273337006, 92273337007,
92273337008, 92273337009
Matrix:Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/38746
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92273337007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595654
Associated Lab Samples:92273337007
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 11/02/15 11:151.7
1,3,5-Trinitrobenzene ug/L ND 10.0 11/02/15 11:151.1
1,3-Dinitrobenzene ug/L ND 20.0 11/02/15 11:151.5
1,4-Naphthoquinone ug/L ND 10.0 11/02/15 11:151.8
1-Naphthalenamine ug/L ND 10.0 11/02/15 11:150.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 11/02/15 11:152.3
2,4,5-Trichlorophenol ug/L ND 10.0 11/02/15 11:152.2
2,4,6-Trichlorophenol ug/L ND 10.0 11/02/15 11:151.9
2,4-Dichlorophenol ug/L ND 10.0 11/02/15 11:151.7
2,4-Dimethylphenol ug/L ND 10.0 11/02/15 11:152.2
2,4-Dinitrophenol ug/L ND 50.0 11/02/15 11:156.5
2,4-Dinitrotoluene ug/L ND 10.0 11/02/15 11:151.2
2,6-Dichlorophenol ug/L ND 10.0 11/02/15 11:151.8
2,6-Dinitrotoluene ug/L ND 10.0 11/02/15 11:151.7
2-Acetylaminofluorene ug/L ND 20.0 11/02/15 11:150.84
2-Chloronaphthalene ug/L ND 10.0 11/02/15 11:152.2
2-Chlorophenol ug/L ND 10.0 11/02/15 11:151.5
2-Methylnaphthalene ug/L ND 10.0 11/02/15 11:150.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 11/02/15 11:151.7
2-Naphthalenamine ug/L ND 10.0 11/02/15 11:150.98
2-Nitroaniline ug/L ND 50.0 11/02/15 11:152.8
2-Nitrophenol ug/L ND 10.0 11/02/15 11:151.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 11/02/15 11:151.7
3,3'-Dichlorobenzidine ug/L ND 20.0 11/02/15 11:151.4
3,3'-Dimethylbenzidine ug/L ND 10.0 11/02/15 11:152.1
3-Methylcholanthrene ug/L ND 10.0 11/02/15 11:150.82
3-Nitroaniline ug/L ND 50.0 11/02/15 11:152.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 11/02/15 11:151.7
4-Aminobiphenyl ug/L ND 20.0 11/02/15 11:150.92
4-Bromophenylphenyl ether ug/L ND 10.0 11/02/15 11:151.3
4-Chloro-3-methylphenol ug/L ND 20.0 11/02/15 11:154.2
4-Chloroaniline ug/L ND 20.0 11/02/15 11:153.4
4-Chlorophenylphenyl ether ug/L ND 10.0 11/02/15 11:152.1
4-Nitroaniline ug/L ND 20.0 11/02/15 11:152.5
4-Nitrophenol ug/L ND 50.0 11/02/15 11:155.8
5-Nitro-o-toluidine ug/L ND 10.0 11/02/15 11:151.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 11/02/15 11:150.77
Acenaphthene ug/L ND 10.0 11/02/15 11:150.25
Acenaphthylene ug/L ND 10.0 11/02/15 11:150.21
Acetophenone ug/L ND 10.0 11/02/15 11:152.0
Anthracene ug/L ND 10.0 11/02/15 11:150.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595654
Associated Lab Samples:92273337007
Matrix:Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 11/02/15 11:150.33
Benzo(a)pyrene ug/L ND 10.0 11/02/15 11:150.30
Benzo(b)fluoranthene ug/L ND 10.0 11/02/15 11:150.28
Benzo(g,h,i)perylene ug/L ND 10.0 11/02/15 11:150.38
Benzo(k)fluoranthene ug/L ND 10.0 11/02/15 11:150.43
Benzyl alcohol ug/L ND 20.0 11/02/15 11:153.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 11/02/15 11:151.7
bis(2-Chloroethyl) ether ug/L ND 10.0 11/02/15 11:151.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 11/02/15 11:151.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 11/02/15 11:150.85
Butylbenzylphthalate ug/L ND 10.0 11/02/15 11:150.75
Chlorobenzilate ug/L ND 10.0 11/02/15 11:150.72
Chrysene ug/L ND 10.0 11/02/15 11:150.21
Di-n-butylphthalate ug/L ND 10.0 11/02/15 11:151.1
Di-n-octylphthalate ug/L ND 10.0 11/02/15 11:150.86
Diallate ug/L ND 10.0 11/02/15 11:151.3
Dibenz(a,h)anthracene ug/L ND 10.0 11/02/15 11:150.55
Dibenzofuran ug/L ND 10.0 11/02/15 11:151.8
Diethylphthalate ug/L ND 6000 11/02/15 11:151.3
Dimethoate ug/L ND 20.0 11/02/15 11:150.92
Dimethylphthalate ug/L ND 10.0 11/02/15 11:151.5
Diphenylamine ug/L ND 10.0 11/02/15 11:151.3
Disulfoton ug/L ND 10.0 11/02/15 11:151.4
Ethyl methanesulfonate ug/L ND 20.0 11/02/15 11:151.8
Famphur ug/L ND 20.0 11/02/15 11:151.7
Fluoranthene ug/L ND 10.0 11/02/15 11:150.21
Fluorene ug/L ND 10.0 11/02/15 11:150.21
Hexachlorobenzene ug/L ND 10.0 11/02/15 11:151.1
Hexachlorocyclopentadiene ug/L ND 10.0 11/02/15 11:151.8
Hexachloroethane ug/L ND 10.0 11/02/15 11:151.5
Hexachloropropene ug/L ND 10.0 11/02/15 11:151.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 11/02/15 11:150.29
Isodrin ug/L ND 20.0 11/02/15 11:152.0
Isophorone ug/L ND 10.0 11/02/15 11:151.8
Isosafrole ug/L ND 10.0 11/02/15 11:151.8
Kepone ug/L ND 20.0 11/02/15 11:153.1
Methapyrilene ug/L ND 100 11/02/15 11:152.7
Methyl methanesulfonate ug/L ND 10.0 11/02/15 11:151.3
Methyl parathion ug/L ND 10.0 11/02/15 11:151.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 11/02/15 11:152.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 11/02/15 11:152.1
N-Nitrosodiethylamine ug/L ND 20.0 11/02/15 11:151.8
N-Nitrosodimethylamine ug/L ND 10.0 11/02/15 11:151.3
N-Nitrosodiphenylamine ug/L ND 10.0 11/02/15 11:151.3
N-Nitrosomethylethylamine ug/L ND 10.0 11/02/15 11:151.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595654
Associated Lab Samples:92273337007
Matrix:Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 11/02/15 11:151.9
N-Nitrosopyrrolidine ug/L ND 10.0 11/02/15 11:152.5
Nitrobenzene ug/L ND 10.0 11/02/15 11:151.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 11/02/15 11:151.8
O-Toluidine ug/L ND 10.0 11/02/15 11:151.6
P-Dimethylaminoazobenzene ug/L ND 10.0 11/02/15 11:150.35
p-Phenylenediamine ug/L ND 10.0 11/02/15 11:150.96
Parathion (Ethyl parathion)ug/L ND 10.0 11/02/15 11:151.1
Pentachlorobenzene ug/L ND 10.0 11/02/15 11:152.0
Pentachloronitrobenzene ug/L ND 20.0 11/02/15 11:151.0
Pentachlorophenol ug/L ND 25.0 11/02/15 11:152.3
Phenacetin ug/L ND 20.0 11/02/15 11:150.97
Phenanthrene ug/L ND 10.0 11/02/15 11:150.22
Phenol ug/L ND 10.0 11/02/15 11:151.7
Phorate ug/L ND 10.0 11/02/15 11:151.1
Pronamide ug/L ND 10.0 11/02/15 11:150.97
Pyrene ug/L ND 10.0 11/02/15 11:150.19
Safrole ug/L ND 10.0 11/02/15 11:151.5
Thionazin ug/L ND 20.0 11/02/15 11:151.2
2,4,6-Tribromophenol (S)%91 27-110 11/02/15 11:15
2-Fluorobiphenyl (S)%84 27-110 11/02/15 11:15
2-Fluorophenol (S)%37 12-110 11/02/15 11:15
Nitrobenzene-d5 (S)%76 21-110 11/02/15 11:15
Phenol-d6 (S)%24 10-110 11/02/15 11:15
Terphenyl-d14 (S)%115 31-107 S311/02/15 11:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595655LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595656
1,2,4,5-Tetrachlorobenzene ug/L 43.550 87 16-1297939.7 9 30
1,3,5-Trinitrobenzene ug/L 69.3 L05013955-12514069.8 1 30
1,3-Dinitrobenzene ug/L 55.850 112 30-12210954.4 3 30
1,4-Naphthoquinone ug/L 46.650 93 31-1208843.9 6 30
1-Naphthalenamine ug/L 30.550 61 37-1266834.1 11 30
2,3,4,6-Tetrachlorophenol ug/L 11550 229 54-276217109 5 30
2,4,5-Trichlorophenol ug/L 53.650 107 43-11310452.2 3 30
2,4,6-Trichlorophenol ug/L 47.850 96 42-1209045.1 6 30
2,4-Dichlorophenol ug/L 46.550 93 30-1208341.5 11 30
2,4-Dimethylphenol ug/L 41.650 83 29-1117537.5 10 30
2,4-Dinitrophenol ug/L 245 R12509819-13245112 74 30
2,4-Dinitrotoluene ug/L 52.750 105 58-12810251.0 3 30
2,6-Dichlorophenol ug/L 41.850 84 54-1289246.1 10 30
2,6-Dinitrotoluene ug/L 52.350 105 54-12910251.2 2 30
2-Acetylaminofluorene ug/L 45.750 91 81-1609446.9 2 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595655LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595656
2-Chloronaphthalene ug/L 50.950 102 43-1179245.9 10 30
2-Chlorophenol ug/L 36.950 74 37-1206432.2 13 30
2-Methylnaphthalene ug/L 42.250 84 33-1207537.4 12 30
2-Methylphenol(o-Cresol)ug/L 36.350 73 31-1206030.2 18 30
2-Naphthalenamine ug/L 41.450 83 41-1369145.4 9 30
2-Nitroaniline ug/L 81.5100 81 48-1218079.6 2 30
2-Nitrophenol ug/L 45.550 91 25-1168341.4 9 30
3&4-Methylphenol(m&p Cresol)ug/L 68.8 L05013823-12011758.4 16 30
3,3'-Dichlorobenzidine ug/L 96.0250 38 10-15441104 8 30
3,3'-Dimethylbenzidine ug/L 37.0 R11003710-1579291.7 85 30
3-Methylcholanthrene ug/L 50.950 102 65-13010652.8 4 30
3-Nitroaniline ug/L 89.1100 89 43-1158888.2 1 30
4,6-Dinitro-2-methylphenol ug/L 96.3100 96 44-1248887.6 9 30
4-Aminobiphenyl ug/L 32.650 65 21-1258542.6 26 30
4-Bromophenylphenyl ether ug/L 46.450 93 34-1139547.5 2 30
4-Chloro-3-methylphenol ug/L 96.2100 96 31-1108888.0 9 30
4-Chloroaniline ug/L 76.5100 76 20-1207171.1 7 30
4-Chlorophenylphenyl ether ug/L 46.250 92 34-1168743.7 6 30
4-Nitroaniline ug/L 100100 100 46-1289796.6 4 30
4-Nitrophenol ug/L 111250 45 11-1203998.0 13 30
5-Nitro-o-toluidine ug/L 63.750 127 78-16012060.1 6 30
7,12-Dimethylbenz(a)anthracene ug/L 59.550 119 47-12412361.3 3 30
Acenaphthene ug/L 45.950 92 48-1148542.7 7 30
Acenaphthylene ug/L 48.650 97 48-1129145.3 7 30
Acetophenone ug/L 40.250 80 24-1206934.7 15 30
Anthracene ug/L 49.850 100 57-11810150.6 2 30
Benzo(a)anthracene ug/L 52.250 104 56-12110854.1 3 30
Benzo(a)pyrene ug/L 52.150 104 55-12710954.7 5 30
Benzo(b)fluoranthene ug/L 55.250 110 53-12811155.7 1 30
Benzo(g,h,i)perylene ug/L 43.350 87 54-1259044.8 4 30
Benzo(k)fluoranthene ug/L 64.9 L05013051-12314371.7 10 30
Benzyl alcohol ug/L 65.9100 66 27-1205555.0 18 30
bis(2-Chloroethoxy)methane ug/L 39.550 79 32-1207135.6 10 30
bis(2-Chloroethyl) ether ug/L 37.750 75 33-1116733.4 12 30
bis(2-Chloroisopropyl) ether ug/L 30.250 60 15-1205326.4 14 30
bis(2-Ethylhexyl)phthalate ug/L 55.350 111 50-14512060.1 8 30
Butylbenzylphthalate ug/L 57.350 115 54-13812160.3 5 30
Chlorobenzilate ug/L 63.7 L05012765-13213567.6 6 30
Chrysene ug/L 52.150 104 58-12711055.0 5 30
Di-n-butylphthalate ug/L 54.450 109 56-12511256.0 3 30
Di-n-octylphthalate ug/L 45.750 91 50-1349447.2 3 30
Diallate ug/L 51.750 103 47-12310653.2 3 30
Dibenz(a,h)anthracene ug/L 44.850 90 53-1299447.2 5 30
Dibenzofuran ug/L 46.850 94 45-1208843.8 7 30
Diethylphthalate ug/L 48.7J50 97 53-1209648.2J 1 30
Dimethoate ug/L 50.450 101 57-13910050.2 0 30
Dimethylphthalate ug/L 47.250 94 55-1169547.4 1 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595655LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595656
Diphenylamine ug/L 44.650 89 42-1209245.9 3 30
Disulfoton ug/L 46.650 93 49-1569748.4 4 30
Ethyl methanesulfonate ug/L 44.350 89 43-1207638.1 15 30
Famphur ug/L 90.9 R11009140-1604747.1 63 30
Fluoranthene ug/L 54.150 108 57-12510854.0 0 30
Fluorene ug/L 50.550 101 53-1189547.6 6 30
Hexachlorobenzene ug/L 54.750 109 49-11611456.8 4 30
Hexachlorocyclopentadiene ug/L 34.950 70 26-1586532.7 7 30
Hexachloroethane ug/L 39.650 79 30-1147135.4 11 30
Hexachloropropene ug/L 29.450 59 13-1376632.8 11 30
Indeno(1,2,3-cd)pyrene ug/L 45.150 90 55-1289446.8 4 30
Isodrin ug/L 54.650 109 68-12910954.5 0 30
Isophorone ug/L 41.850 84 31-1187336.5 13 30
Isosafrole ug/L 46.650 93 48-1078542.7 9 30
Kepone ug/L 101100 101 10-1249695.9 5 30
Methapyrilene ug/L 14.3J L0502940-1607135.5J 30
Methyl methanesulfonate ug/L 31.250 62 25-1145426.9 15 30
Methyl parathion ug/L 52.650 105 58-13710552.6 0 30
N-Nitroso-di-n-butylamine ug/L 32.250 64 36-1157336.4 12 30
N-Nitroso-di-n-propylamine ug/L 38.950 78 32-1196733.3 16 30
N-Nitrosodiethylamine ug/L 48.350 97 47-1158743.4 11 30
N-Nitrosodimethylamine ug/L 23.550 47 13-1204221.2 10 30
N-Nitrosodiphenylamine ug/L 44.650 89 43-1209245.9 3 30
N-Nitrosomethylethylamine ug/L 44.750 89 39-1208140.5 10 30
N-Nitrosopiperidine ug/L 37.750 75 43-1138642.9 13 30
N-Nitrosopyrrolidine ug/L 46.850 94 32-1107939.7 16 30
Nitrobenzene ug/L 40.450 81 33-1107336.7 10 30
O,O,O-Triethylphosphorothioate ug/L 38.150 76 51-1278542.5 11 30
O-Toluidine ug/L 38.950 78 27-1206833.8 14 30
P-Dimethylaminoazobenzene ug/L 30.3100 30 10-1203232.4 7 30
p-Phenylenediamine ug/L 47.750 95 72-14311356.3 16 30
Parathion (Ethyl parathion)ug/L 50.350 101 56-14010050.1 0 30
Pentachlorobenzene ug/L 50.250 100 30-1379346.5 8 30
Pentachloronitrobenzene ug/L 64.6 L05012970-12412864.2 1 30
Pentachlorophenol ug/L 99.5250 40 10-1373690.0 10 30
Phenacetin ug/L 51.950 104 60-13010853.8 4 30
Phenanthrene ug/L 44.850 90 57-1179145.6 2 30
Phenol ug/L 21.050 42 10-1203517.6 17 30
Phorate ug/L 68.5 L05013755-12613869.0 1 30
Pronamide ug/L 58.850 118 75-12412160.6 3 30
Pyrene ug/L 57.8 L05011655-12212361.5 6 30
Safrole ug/L 37.150 74 41-1208240.9 10 30
Thionazin ug/L 49.450 99 63-1379848.9 1 30
2,4,6-Tribromophenol (S)%109 27-110109
2-Fluorobiphenyl (S)%84 27-11076
2-Fluorophenol (S)%44 12-11037
Nitrobenzene-d5 (S)%83 21-11074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595655LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595656
Phenol-d6 (S)%31 10-11025
Terphenyl-d14 (S)%S010731-107110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 43
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41095
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92273337005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593988
Associated Lab Samples:92273337005
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 10/28/15 18:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593989LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 503J500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593990MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337005
1593991
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 99 90-11099 0 10500ND493J493J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 43
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.
Results unaffected by high bias.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 43
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273337
ASHE CO. LINED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273337001 MPRP/19905 ICP/17945MW-1 EPA 3010 EPA 6010
92273337002 MPRP/19905 ICP/17945MW-13 EPA 3010 EPA 6010
92273337003 MPRP/19905 ICP/17945MW-15 EPA 3010 EPA 6010
92273337004 MPRP/19905 ICP/17945MW-A EPA 3010 EPA 6010
92273337005 MPRP/19905 ICP/17945MW-28 EPA 3010 EPA 6010
92273337006 MPRP/19905 ICP/17945MW-29 EPA 3010 EPA 6010
92273337007 MPRP/19905 ICP/17945MW-30 EPA 3010 EPA 6010
92273337008 MPRP/19905 ICP/17945UDPEPA 3010 EPA 6010
92273337009 MPRP/19905 ICP/17945SW-A EPA 3010 EPA 6010
92273337001 MERP/8592 MERC/8258MW-1 EPA 7470 EPA 7470
92273337005 MERP/8592 MERC/8258MW-28 EPA 7470 EPA 7470
92273337007 OEXT/38746 MSSV/11463MW-30 EPA 3510 EPA 8270
92273337001 MSV/34086MW-1 EPA 8260
92273337002 MSV/34086MW-13 EPA 8260
92273337003 MSV/34086MW-15 EPA 8260
92273337004 MSV/34086MW-A EPA 8260
92273337005 MSV/34086MW-28 EPA 8260
92273337006 MSV/34086MW-29 EPA 8260
92273337007 MSV/34086MW-30 EPA 8260
92273337008 MSV/34086UDPEPA 8260
92273337009 MSV/34086SW-A EPA 8260
92273337005 WET/41095MW-28 SM 4500-S2D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/03/2015 03:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 43
Page 42 of 43
Page 43 of 43
#=CL#
November 02, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273347
92273347
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. MSWLF (WSW-2)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 17
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 17
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Lab ID Sample ID Matrix Date Collected Date Received
92273347001 WSW-2 Water 10/23/15 09:00 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 17
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273347001 WSW-2 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 17
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Sample:WSW-2 Lab ID:92273347001 Collected:10/23/15 09:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:41 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:41 7440-38-210/28/15 20:0010.0 2.5 1
Barium 196 ug/L 10/30/15 23:41 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:41 7440-41-710/28/15 20:001.0 0.50 1
Cadmium ND ug/L 10/30/15 23:41 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:41 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:41 7440-48-410/28/15 20:0010.0 2.5 1
Copper 104 ug/L 10/30/15 23:41 7440-50-810/28/15 20:0010.0 2.5 1
Lead 8.1J ug/L 10/30/15 23:41 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:41 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:41 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:41 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:41 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:41 7440-62-210/28/15 20:0025.0 2.5 1
Zinc 502 ug/L 10/30/15 23:41 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 05:04 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 05:04 107-13-12001.9 1
Benzene ND ug/L 11/01/15 05:04 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 05:04 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 05:04 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 05:04 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 05:04 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 05:04 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 05:04 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 05:04 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 05:04 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 05:04 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 05:04 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 05:04 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 05:04 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 05:04 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 05:04 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 05:04 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 05:04 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 05:04 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 05:04 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 05:04 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 05:04 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 05:04 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 05:04 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 05:04 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 05:04 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 05:04 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 05:04 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 17
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Sample:WSW-2 Lab ID:92273347001 Collected:10/23/15 09:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 05:04 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 05:04 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 05:04 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 05:04 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 05:04 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 05:04 108-10-11000.33 1
Styrene ND ug/L 11/01/15 05:04 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 05:04 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 05:04 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 05:04 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 05:04 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 05:04 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 05:04 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 05:04 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 05:04 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 05:04 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 05:04 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 05:04 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 05:04 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 05:04 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %11/01/15 05:04 17060-07-070-130 1
Toluene-d8 (S)101 %11/01/15 05:04 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19905
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593024
Associated Lab Samples:92273347001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/30/15 22:423.8
Arsenic ug/L ND 10.0 10/30/15 22:422.5
Barium ug/L ND 100 10/30/15 22:422.5
Beryllium ug/L ND 1.0 10/30/15 22:420.50
Cadmium ug/L ND 1.0 10/30/15 22:420.50
Chromium ug/L ND 10.0 10/30/15 22:422.5
Cobalt ug/L ND 10.0 10/30/15 22:422.5
Copper ug/L ND 10.0 10/30/15 22:422.5
Lead ug/L ND 10.0 10/30/15 22:422.5
Nickel ug/L ND 50.0 10/30/15 22:422.5
Selenium ug/L ND 10.0 10/30/15 22:425.0
Silver ug/L ND 10.0 10/30/15 22:422.5
Thallium ug/L ND 5.5 10/30/15 22:425.0
Vanadium ug/L ND 25.0 10/30/15 22:422.5
Zinc ug/L ND 10.0 10/30/15 22:425.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593025LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 491500 98 80-120
Arsenic ug/L 464500 93 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 482500 96 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 471500 94 80-120
Nickel ug/L 469500 94 80-120
Selenium ug/L 466500 93 80-120
Silver ug/L 237250 95 80-120
Thallium ug/L 465500 93 80-120
Vanadium ug/L 481500 96 80-120
Zinc ug/L 445500 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337001
1593027
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-12592 13 25500ND530464
Arsenic ug/L 500 101 75-12588 13 25500ND504441
Barium ug/L 500 107 75-12593 12 2550074.1J 607 539
Beryllium ug/L 500 109 75-12595 13 25500ND543475
Cadmium ug/L 500 105 75-12592 13 25500ND527461
Chromium ug/L 500 105 75-12593 13 25500ND528465
Cobalt ug/L 500 103 75-12591 13 25500ND517453
Copper ug/L 500 109 75-12594 15 25500ND544469
Lead ug/L 500 104 75-12590 13 25500ND518452
Nickel ug/L 500 104 75-12591 13 25500ND522457
Selenium ug/L 500 101 75-12588 14 25500ND505441
Silver ug/L 250 105 75-12591 14 25250ND262228
Thallium ug/L 500 102 75-12589 13 25500ND509446
Vanadium ug/L 500 108 75-12595 13 25500ND538473
Zinc ug/L 500 101 75-12588 13 25500ND506443
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273347001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273347001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273347001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 17
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 17
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 17
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273347
ASHE CO. MSWLF (WSW-2)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273347001 MPRP/19905 ICP/17945WSW-2 EPA 3010 EPA 6010
92273347001 MSV/34086WSW-2 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/02/2015 11:12 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 17
Page 16 of 17
Page 17 of 17
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273338
92273338
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO. MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 22
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 22
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92273338001 EB Water 10/23/15 12:00 10/26/15 12:15
92273338002 FB Water 10/23/15 12:05 10/26/15 12:15
92273338003 TB Water 10/23/15 00:00 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 22
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273338001 EB EPA 6010 15 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CCAH
92273338002 FB EPA 6010 15 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8260 51 PASI-CCAH
92273338003 TB EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:EB Lab ID:92273338001 Collected:10/23/15 12:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:43 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:43 7440-38-210/28/15 19:0010.0 2.5 1
Barium ND ug/L 11/04/15 19:43 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:43 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:43 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:43 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:43 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:43 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:43 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:43 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:43 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:43 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:43 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:43 7440-62-210/28/15 19:0025.0 2.5 1
Zinc ND ug/L 11/04/15 19:43 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/30/15 16:30 7439-97-610/28/15 17:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 03:41 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 03:41 107-13-12001.9 1
Benzene ND ug/L 11/01/15 03:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 03:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 03:41 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 03:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 03:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 03:41 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 03:41 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 03:41 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 03:41 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 03:41 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 03:41 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 03:41 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 03:41 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 03:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 03:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 03:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 03:41 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 03:41 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 03:41 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 03:41 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 03:41 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 03:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 03:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 03:41 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:EB Lab ID:92273338001 Collected:10/23/15 12:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 11/01/15 03:41 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 03:41 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 03:41 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 03:41 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 03:41 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 03:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 03:41 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 03:41 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 03:41 108-10-11000.33 1
Styrene ND ug/L 11/01/15 03:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 03:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 03:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 03:41 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 03:41 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 03:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 03:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 03:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 03:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 03:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 03:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 03:41 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 03:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 03:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 03:41 17060-07-070-130 1
Toluene-d8 (S)101 %11/01/15 03:41 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:FB Lab ID:92273338002 Collected:10/23/15 12:05 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:47 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:47 7440-38-210/28/15 19:0010.0 2.5 1
Barium ND ug/L 11/04/15 19:47 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:47 7440-41-710/28/15 19:001.0 0.50 1
Cadmium ND ug/L 11/04/15 19:47 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:47 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:47 7440-48-410/28/15 19:0010.0 2.5 1
Copper ND ug/L 11/04/15 19:47 7440-50-810/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:47 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:47 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:47 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:47 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:47 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:47 7440-62-210/28/15 19:0025.0 2.5 1
Zinc ND ug/L 11/04/15 19:47 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 10/30/15 16:34 7439-97-610/28/15 17:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 03:57 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 03:57 107-13-12001.9 1
Benzene ND ug/L 11/01/15 03:57 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 03:57 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 03:57 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 03:57 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 03:57 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 03:57 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 03:57 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 03:57 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 03:57 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 03:57 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 03:57 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 03:57 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 03:57 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 03:57 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 03:57 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 03:57 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 03:57 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 03:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 03:57 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 03:57 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 03:57 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 03:57 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 03:57 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 03:57 156-60-55.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:FB Lab ID:92273338002 Collected:10/23/15 12:05 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 11/01/15 03:57 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 03:57 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 03:57 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 03:57 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 03:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 03:57 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 03:57 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 03:57 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 03:57 108-10-11000.33 1
Styrene ND ug/L 11/01/15 03:57 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 03:57 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 03:57 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 03:57 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 03:57 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 03:57 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 03:57 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 03:57 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 03:57 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 03:57 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 03:57 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 03:57 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 03:57 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 03:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 03:57 17060-07-070-130 1
Toluene-d8 (S)102 %11/01/15 03:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:TB Lab ID:92273338003 Collected:10/23/15 00:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 04:14 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 04:14 107-13-12001.9 1
Benzene ND ug/L 11/01/15 04:14 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 04:14 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 04:14 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 04:14 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 04:14 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 04:14 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 04:14 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 04:14 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 04:14 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 04:14 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 04:14 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 04:14 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 04:14 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 04:14 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 04:14 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 04:14 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 04:14 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 04:14 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 04:14 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 04:14 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 04:14 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 04:14 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 04:14 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 04:14 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 04:14 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 04:14 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 04:14 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 11/01/15 04:14 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 04:14 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 04:14 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 04:14 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 04:14 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 04:14 108-10-11000.33 1
Styrene ND ug/L 11/01/15 04:14 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 04:14 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 04:14 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 04:14 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 04:14 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 04:14 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 04:14 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 04:14 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 04:14 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 04:14 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 04:14 108-05-450.0 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Sample:TB Lab ID:92273338003 Collected:10/23/15 00:00 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 11/01/15 04:14 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 04:14 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 04:14 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %11/01/15 04:14 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 04:14 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8592
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92273338001, 92273338002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593164
Associated Lab Samples:92273338001, 92273338002
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 10/30/15 16:060.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593165LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593166MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273493001
1593167
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 97 75-12596 1 252.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273338001, 92273338002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273338001, 92273338002
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273338001, 92273338002, 92273338003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273338001, 92273338002, 92273338003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273338001, 92273338002, 92273338003
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273338
ASHE CO. MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273338001 MPRP/19918 ICP/17958EBEPA 3010 EPA 6010
92273338002 MPRP/19918 ICP/17958FBEPA 3010 EPA 6010
92273338001 MERP/8592 MERC/8258EBEPA 7470 EPA 7470
92273338002 MERP/8592 MERC/8258FBEPA 7470 EPA 7470
92273338001 MSV/34086EBEPA 8260
92273338002 MSV/34086FBEPA 8260
92273338003 MSV/34086TBEPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:07 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 22
Page 21 of 22
Page 22 of 22
Appendix B
Field Sampling Parameter Data Sheet(s)