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HomeMy WebLinkAbout18019_Standard_Uniform__Assessment_Report i S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc Brownfields Assessment Report Standard Uniform Site 600 Phillip Davis Drive Charlotte, North Carolina H&H Job SFR-002 Table of Contents Section Page No. 1.0 Introduction and Background Information ........................................................................ 1 2.0 Additional Assessment Activities .......................................................................................... 3 2.1 Receptor Survey ................................................................................................................... 3 2.2 Surface Water Sampling ....................................................................................................... 3 2.3 Sub-slab Soil Vapor Sampling ............................................................................................. 4 2.4 Indoor Air Sampling ............................................................................................................. 5 2.5 Floor Drain Vapor Screening ............................................................................................... 7 3.0 Results ..................................................................................................................................... 8 3.1 Receptor Survey Results ....................................................................................................... 8 3.2 Surface Water Sampling Results .......................................................................................... 9 3.3 Sub-Slab Soil Vapor Results .............................................................................................. 10 3.4 Indoor Air Sample Results ................................................................................................. 10 3.5 Floor Drain Vapor Screening Results ................................................................................. 11 4.0 Summary and Conclusions.................................................................................................. 12 ii S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc List of Tables Table 1 Summary of Groundwater Analytical Data Table 2 Summary of Indoor Air Sample Field Data Table 3 Summary of Surface Water Analytical Data Table 4 Summary of Sub-Slab Soil Vapor Analytical Data Table 5 Summary of Indoor and Background Air Analytical Data Table 6 Calculated Indoor Air Additive Risks List of Figures Figure 1 Site Location Map Figure 2 Groundwater and Surface Water Sample Location Map Figure 3 Sub-Slab Soil Vapor Sample Location Map Figure 4 Indoor Air and Background Sample Location Map Figure 5 PPB Survey and Drain Location Map List of Appendices Appendix A Brownfields Area Reconnaissance and Receptor Survey Form Appendix B Laboratory Analytical Reports 1 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc Brownfields Assessment Report Standard Uniform Site 600 Phillip Davis Drive Charlotte, North Carolina H&H Job SFR-002 1.0 Introduction and Background Information Hart & Hickman, PC (H&H) has prepared this Brownfields Assessment Report for the Standard Uniform Brownfields site located at 600 Phillip Davis Dr. in Charlotte, North Carolina. A site location map is included as Figure 1. The site is approximately 5.8 acres and contains an approximate 21,000 square-foot building that is used as party rental showroom, office, and storage warehouse. A site plan is included as Figure 2. The site was formerly operated from 1982 to 2000 by Standard Uniform which conducted uniform supply and cleaning. As part of that process, dry cleaning was performed in the southeastern portion of the warehouse area. To assess the potential for impact from historical dry cleaning activities, H&H conducted groundwater sampling on the eastern and northeastern portion of the site in July 2013. The locations of the groundwater samples, labeled TW-1, TW-2, and TW-3, are indicated in Figure 2. Results of analysis of the groundwater samples are summarized in Table 1. The results indicated that no compounds were detected in well TW-1 from the northeastern portion of the site. However, the drycleaning solvent tetrachloroethene (PCE) and its degradation products trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE), and vinyl chloride were detected in the groundwater samples collected from wells TW-2 and TW-3 on the eastern side of the site above North Carolina groundwater standards. The highest concentrations were detected in well TW-3 located closest to the area of the former drycleaner. In TW-3. PCE was detected at a concentration of 18,900 µg/l. In addition, the detected concentrations of PCE and TCE in TW-2 and TW-3 were above the DENR Division of Waste Management Non-Residential Vapor Intrusion Screening Levels. 2 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc In April 2014, the property owner SFRH Charlotte Flip LLC applied for Brownfields program eligibility, and a letter of eligibility was received from the DENR Brownfields Program on May 28, 2014. To evaluate potential risks associated with the site and its future use, H&H prepared a Brownfields Assessment Work Plan (Work Plan) that was submitted to DENR on September 5, 2014. The Work Plan activities included surface water sampling, a receptor survey, sub-slab soil vapor sampling, and indoor air sampling. As per notification to DENR Brownfields, H&H proceeded with the sub-slab soil vapor sampling in April 2015. In accordance with the Work Plan, H&H subsequently provided the results of the sub-slab soil vapor sampling along with a plan for indoor air sampling to DENR for review. DENR subsequently approved the indoor air sampling locations in an email dated June 9, 2015 and also requested that field screening of floor drains in the building with a photoionization detector (PID) be performed. The following sections describe the methods and results of the Brownfields assessment activities. Please note that on July 9, 2015, the property was sold to PLV Investments LLC. 3 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc 2.0 Additional Assessment Activities The Work Plan activities included surface water sampling, a receptor survey, sub-slab soil vapor sampling, indoor air sampling, and PID screening of the floor drains. The assessment activities are described below. 2.1 Receptor Survey On May 1, 2015, H&H performed a Brownfields receptor survey for the site and nearby area. The receptor survey was completed in accordance with the DENR Brownfields Receptor Survey Guidance form. The receptor survey included information about land use in the site area, and a search for water supply wells, basements, utility manways and chases, storm sewers, other underground utilities, drains, and surface water within the site area. The DENR Brownfields Receptor Survey Guidance form is included in Appendix A. The results of the receptor survey are discussed in Section 3.2. 2.2 Surface Water Sampling On May 1, 2015, H&H collected surface water samples from one upgradient and one downgradient location at the site to evaluate the potential for stream impacts from discharging groundwater. The samples were collected from the tributary of Irwin Creek that borders the eastern and northern edges of the site. The approximate locations of the samples are indicated in Figure 2. The samples were collected under base flow conditions (i.e., not during or soon after a rain event) by placing the sample jars directly into the flowing water and allowing the bottles to fill slowly. The tributary is located in an apparent channelized section with steep banks that are overgrown with vegetation. The samples were collected moving upstream in order to minimize the potential for cross contamination. The surface water samples were analyzed for volatile organic compounds 4 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc (VOCs) by EPA Method 8260. The results of the surface water sampling are discussed in Section 3.1. 2.3 Sub-slab Soil Vapor Sampling On April 17, 2015, H&H collected six sub-slab soil vapor samples to assess the potential for vapor intrusion into the site buildings from identified groundwater impacts. The locations of the sub-slab samples, labeled SSVP-1 through SSVP-6, are indicated in Figure 3. The sub-slab samples were collected from the following locations: • SSVP-3 was collected from the area of the former drycleaning machines in the southeastern part of the warehouse. • SSVP-1, SSVP-2, and SSVP-4 were collected from the warehouse area, biased to the eastern side where the dry-cleaning machines were located. • SSVP-5 and SSVP-6 were collected from the office/showroom area. At each sample location, H&H drilled through the concrete floor utilizing a concrete hammer drill and an approximate 1.5-inch diameter bit. Through each of the drilled holes, H&H installed an approximate 0.625-inch diameter stainless steel probe with approximate 2-inch long bottom screen point. The probes were installed through the gravel beneath the concrete slab and seated in the underlying soil so that the soil gas probe screen was present in both the soil and overlying gravel. The approximate depth of the soil gas probes was approximately 6 inches below the surface of the slab. After pushing the screen point to the desired depth, the stainless steel screen of the point was opened. Each point was then sealed at the surface of the concrete slab using hydrated bentonite. The soil gas probes were completed at the surface using a sample valve and Teflon tubing. Prior to sampling, a leak check was conducted at each vapor monitoring point by constructing a shroud around the sampling point and saturating the air within the shroud with helium gas. Using a syringe, a sample was collected from the gas in the shroud into a Tedlar® bag and analyzed for 5 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc helium concentrations using a helium gas detector. Vapor from the vapor monitoring point was purged and sampled outside of the shroud into a separate Tedlar® bag and analyzed using the helium gas detector to ensure that helium concentrations were less than 5% of the helium concentrations detected in the shroud. Results of the leak test at each sample location did not indicate the presence of helium in any of the soil gas samples collected. Following the successful field leak check, the vapor samples were collected into a one-liter Summa canisters for laboratory analysis. The Summa canisters were allowed to fill slowly using an airflow regulator over a period of approximately 10 minutes per point (approximately 100 ml/min). Once the soil vapor samples were collected, the canisters were shipped to ConTest laboratories for analysis of volatile organic compounds (VOCs) by EPA Method TO-15. The results of analysis of the sub-slab samples are discussed in Section 3.3. 2.4 Indoor Air Sampling As discussed in Section 3.3, the results of analysis of the sub-slab soil vapor samples indicated the presence of compounds above the DENR Division of Waste Management (DWM) Non- Residential Soil Vapor Screening Levels. In accordance with the Work Plan, H&H provided a summary of the sub-slab soil vapor sample data to DENR for review along with the proposed locations of indoor air samples. Following DENR concurrence, on June 17, 2015, H&H conducted the indoor air sampling activities. Prior to the indoor air sampling, H&H reviewed material safety data sheets and completed a product inventory to verify that compounds to be analyzed for in the indoor air samples were not being used at the facility. The locations of the indoor air samples, labeled IAS-1 through IAS-5, are indicated in Figure 4. The indoor air samples were collected in the following locations: • IAS-1 was collected from the office/showroom. • IAS-2 and IAS-3 were collected from the eastern portion of the warehouse. 6 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc • IAS-4 was collected from the central portion of the warehouse. • IAS-5 was collected from the office area. The indoor air samples were collected with 6-liter Summa canisters. The Summa canister was connected to an airflow regulator and a 3 ft long sampling cane. The typical height of a Summa canister with an attached airflow regulator is approximately 2 ft above grade and, with the additional 3-foot long sampling cane, the sample intake point is approximately 5 ft above grade (typical breathing zone height). Prior to sample collection, H&H measured the wind direction and selected an exterior background location located upgradient of the site building. The location of the background sample, labeled BAS-1, is shown on Figure 4 and was located in the southern portion of the site. The background location Summa canister was also fitted with a regulator and sampling cane so that the sample height is approximately 5 ft above ground level. Following set-up of the background sample canister, the indoor and background sample valves were opened and the samples were collected over an approximate 8-hour period. As part of the sampling effort, H&H measured the indoor/outdoor air pressure differential at representative sampling locations near the start, middle, and end of the 8-hour sampling period using a manometer sensitive to 0.001 inches water. In addition, exterior wind speed, exterior wind direction, and indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period. The indoor air field data is provided in Table 2. Following collection, the indoor air samples were submitted to ConTest Laboratories for analysis of select VOCs EPA Method TO-15. Based on the results of the sub-slab sampling and with concurrence from DENR, the select VOCs included tetrachloroethene (PCE), trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE), trans-1,2-dichloroethene (trans-1,2-DCE), 1,1- dichloroethene (1,1-DCE), and vinyl chloride. The results of the indoor air sampling are discussed in Section 3.4. 7 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc 2.5 Floor Drain Vapor Screening During indoor air sample collection H&H also utilized a photoionization detector (PID) capable of reading organic vapor at one part per billion-volume (ppb-v) to screen floor drains located throughout the facility. The purpose of the PID survey was to determine if the floor drains were a preferential vapor intrusion pathway into the building. The survey was conducted with a calibrated RAE Systems ppbRAE meter. The locations of the drains and PID readings measured in the field are shown on Figure 5, and the results are discussed in Section 3.5. 8 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc 3.0 Results The results of the Brownfields assessment activities are presented below. The laboratory reports including sample chains of custody for samples are included as Appendix B. 3.1 Receptor Survey Results The results of the receptor survey are discussed below. The Brownfields Receptor Survey form is provided in Appendix A. Surrounding Property The subject property is approximately 5.8 acres in size and is currently developed with an approximate 21,000 square-foot building that contains a party rental warehouse, showroom, and offices. Surrounding property use includes industrial and commercial. No schools or daycares were identified within 1,000 ft of the site. Zoning The subject site and surrounding properties are zoned I-2 (general industrial). Municipal Water Availability Municipal water supplied by Charlotte Water is available to the site and surrounding area. H&H observed that occupied properties in the site area have municipal water connections. CMU obtains its water from Mountain Island Lake and Lake Norman which are both located greater than 5 miles from the site. Water Supply Wells H&H conducted a drive-by reconnaissance survey of properties within a 1,000 ft of the site to identify potential water supply wells. H&H also reviewed the Mecklenburg County Well Information System (WIS) database for water supply wells located within 1,000 ft of the subject site. No private or public water supply wells were identified within 1,000 ft of the subject site. 9 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc Monitoring Wells H&H conducted a drive-by reconnaissance survey of properties within a 250 ft radius of the site to identify potential monitoring wells. H&H also reviewed the Mecklenburg County Well Information System (WIS) database for monitoring wells located within 250 ft of the subject site. No monitoring wells were identified during the drive-by reconnaissance or database search. Surface Water Bodies A tributary of Irwin Creek is present on the northern and eastern boundaries of the subject property. Based on the DENR classification system, this tributary is a Class C surface water body. A Class C body is defined as “waters protected for uses such as secondary recreation, fishing, wildlife, fish consumption, aquatic life including propagation, survival and maintenance of biological integrity, and agriculture. Secondary recreation includes wading, boating, and other uses involving human body contact with water where such activities take place in an infrequent, unorganized, or incidental manner.” The tributary flows into Irwin Creek which is located approximately 0.80 mile northwest of the subject site. Subsurface Structures H&H conducted visual reconnaissance in the site area to identify potential subsurface structures within 500 ft of the subject site. No basements were identified within 500 ft of the subject site. The following utilities were identified adjacent and/or on the subject property: sanitary sewer, storm sewer, municipal water, natural gas lines, communication, and electrical. No septic systems were identified at the site. 3.2 Surface Water Sampling Results The results of analysis of the surface water samples collected from upgradient (SW-2) and downgradient (SW-1) locations in the tributary bordering the site are summarized in Table 3. The results indicate that no compounds were detected above laboratory detection limits in upstream surface water sample SW-2. In SW-1, PCE was detected at 35 µg/L which is above the 15A NCAC 2B Surface Water Standard of 3.3 µg/L. Note that this surface water standard is based upon human health for the consumption of fish, which H&H considers highly unlikely based upon the commercial/industrial nature of the site area, small size of the tributary, and its 10 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc difficult accessibility. TCE and cis-1,2-DCE were also detected in the samples but at concentrations below DENR surface water standards and criteria. No other compounds were detected in sample SW-1 above laboratory detection limits. 3.3 Sub-Slab Soil Vapor Results The results of analysis of the sub-slab soil vapor samples are summarized in Table 4. The results indicate that PCE was detected in samples SSVP-2 (20,000 µg/m3), SSVP-3 (49,000 µg/m3), and SSVP-6 (6,700 µg/m3) above the Division of Waste Management (DWM) Non-Residential Soil Gas Screening Level (SGSL) of 3,500 µg/m3. In addition, concentrations of TCE were detected in samples SSVP-2 (3,100 µg/m3) and SSVP-3 (5,100 µg/m3) above the DWM Non-Residential SGSL of 175 µg/m3 for TCE. PCE and TCE were also detected in the remaining samples, but the concentrations were below the DWM Non-Residential SGSLs. The highest PCE and TCE concentrations were detected in the southeastern portion of the warehouse in the vicinity of the former dry-cleaning operation. No other compounds were detected above the DWM Non-Residential SGSLs. 3.4 Indoor Air Sample Results The results of field measurements taken during the indoor air sampling are summarized in Table 2. During the sampling event, outside temperatures were in the range of 85 to 101oF. In indoor air temperatures ranged from 72 to 74oF in the conditioned spaces to 80 to 88oF in the warehouse. The results of the differential pressure measurements indicate that differential pressure was primarily neutral to slightly negative (pressure was higher inside than outside) during most of the sampling event. The results of analysis of the indoor air samples are summarized in Table 5. The results indicate that no compounds were detected in the samples above the conservative DWM Non-Residential Indoor Air Screening Levels (IASLs). PCE was detected in the highest concentrations ranging from 5 µg/m3 to 26 µg/m3 versus the DMW Non-Residential IASL of 35 µg/m3. In addition, a low level of PCE (0.38 µg/m3) was detected in the background outdoor sample (BAS-1). Low 11 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc concentrations of TCE ranging from 0.12J µg/m3 to 0.62 µg/m3 were detected in the indoor air samples which are below the DWM Non-Residential IASL of 1.75 µg/m3. Consistent with the sub-slab soil vapor data, the highest PCE and TCE concentrations were detected in sample IAS-3 in the southeastern portion of the warehouse. As noted above, the compound concentrations detected in the indoor air samples were compared to the Non-Residential IASLs. These screening levels are very conservative and based upon a Lifetime Incremental Cancer Risk (LICR) of 1 x 10-6 for potential carcinogenic effects and/or a Hazard Index (HI) of 0.2 for potential noncarcinogenic effects. Vapor intrusion mitigation for occupied Industrial/Commercial structures is not typically considered unless the LICR exceeds 1 x 10-4 for potential carcinogenic effects and a HI of 1 for potential non-carcinogenic effects. To further evaluate the risks posed by the detected compounds, H&H calculated cumulative potential carcinogenic and non-carcinogenic risks for the five indoor air samples collected from the site building. The calculations and equations are summarized in Table 6. The highest calculated LICR and HI came from the concentrations detected in IAS-3. Both the LICR (7.6 x 10-7) and HI (0.22) are well below the acceptable risk thresholds of LICR of 1 x 10-4 HI of 1. 3.5 Floor Drain Vapor Screening Results The locations of the 17 floor drains at the facility and the results of the floor drain PID screening are summarized on Figure 5. The results indicate that no PID readings were detected in the floor drains expect for two locations. Floor drain 10 is located in the women’s restroom in the southeastern portion of the site and had a very low PID level of 98 ppb-v (0.098 ppm-v). Floor drain 13 is located in the janitor’s closest and also had a low PID level of 588 ppb-v (0.588 ppm- v). H&H believes that it is possible that both of these readings may have been impacted by cleaning products discharged into the drains due to the lack of PID readings in other nearby floor drains (for floor drain 10) and its location away from the former dry cleaning area (for floor drain 13). The PID readings do not provide an indication that floor drains are a likely significant source of VOCs in indoor air. 12 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\Brownfields Report.doc 4.0 Summary and Conclusions H&H has completed Brownfields assessment activities at the Standard Uniform Brownfields site located at 600 Phillip Davis Dr. in Charlotte, North Carolina. Previous assessment activities indicated the presence of PCE and daughter products from former dry cleaning operations that occurred in the southeast portion of the warehouse from approximately 1982 to 2000. The purpose of the Brownfields assessment activities was to evaluate potential risks for current and future use at the site. The results or our assessment are summarized below: • Other than the creek located on the northern and eastern site boundaries, no receptors of significant concern were identified in the area of the site. • Sampling of the creek from a downgradient location indicated the presence of PCE at 35 µg/l versus the DENR surface water standard of 3.3 µg/l. Note that this surface water standard is based upon human health for the consumption of fish. H&H considers fish consumption from this creek highly unlikely based upon the commercial/industrial nature of the site area, small size of the tributary, and its difficult accessibility. • Results of sub-slab soil vapor sampling indicated the presence of PCE and TCE at concentrations above DENR Non-Residential SGSLs below the eastern portion of the building. Results of analysis of indoor air samples collected from the building did not indicate the presence of compounds above the DENR Non-Residential IASLs. In addition, cumulative risk calculations indicated that risk levels were well below levels of concern. Based upon the results of the indoor air sampling, H&H does not recommend further evaluation of the vapor intrusion pathway, and indoor air mitigation is not warranted. Table 1 Summary of Groundwater Analytical Data Standard Uniform Site 600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx 9/8/2015 Table 1 (Page 1 of 1) Hart & Hickman, PC Analytical Method Sample ID TW-1 TW-2 TW-3 Sample Date 7/16/2013 7/29/2013 7/29/2013 Units (µg/L)(µg/L)(µg/L)(µg/L)(µg/L) VOCs (8260B) cis-1,2-Dichloroethene <1.0 278 22.3 60 NE Tetrachloroethene <1.0 1,580 18,900 0.7 48.4 Toluene <1.0 <1.0 7.56 600 16,100 Trichloroethene <1.0 97.0 27.1 3 4.35 Vinyl Chloride <1.0 3.51 <1.0 0.03 24.5 Notes: 1) North Carolina Department of Environment and Natural Resources 2L Groundwater Standard 2) North Carolina Division Of Waste Management Non-Residential Vapor Intrusion Groundwater Screening Level (June 2014) Only those compounds detected in at least one sample shown above Bold indicates an exceedance of the NC 2L Standards Bold indicates an exceedance of the Non-Residential Vapor Intrusion Groundwater Screening Level Method number follows parameter in parenthesis VOCs = volatile organic compounds (µg/L) = micrograms per liter VOCs (8260)North Carolina Groundwater Standard1 Vapor Intrusion Screening Level2 Table 2 Summary of Indoor Air Sample Field Data Standard Uniform Site 600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx 9/8/2015 Table 2 Hart & Hickman, PC Time oF Pressure oF Direction Speed Precip (inches) 8:45 NA NA 85 SSE 4 0.00 12:40 NA NA 98 NNE 4 0.00 17:07 NA NA 101 W 3 0.00 Beginning 72 -0.004 Middle 73 -0.005 End 74 0.009 Beginning 80 0.000 Middle 85 -0.003 End 88 0.000 Beginning 80 0.000 Middle 85 -0.003 End 88 0.000 Beginning 80 0.000 Middle 85 0.003 End 88 0.000 Beginning 72 -0.004 Middle 73 -0.005 End 74 0.009 Notes: Information from on-site weather station set up by H&H on June 17,2015 during indoor air sampling event. Positive differential pressure indicates that the pressure outside the building was higher than the inside pressure. Differential pressure and temperature readings taken from each sample location at the beginning, middle, and end during the 8-hour sample collection NA = Not Applicable mph = miles per hour Lobby/Showroom Warehouse (Rear) Office IAS-1 IAS-2 IAS-5 IAS-3 IAS-4 Warehouse (Middle) Warehouse (Front) Sample ID Sample Location Indoor Outdoor BAS-1 Outdoor Table 3 Summary of Surface Water Analytical Data Standard Uniform Site 600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx9/8/2015 Table 3 Hart & Hickman, PC Sample ID SW-1 SW-2 Sample Date 5/1/2015 5/1/2015 Location downstream upstream Units µg/L µg/L µg/L VOCs (8260B) Tetrachloroethylene 35 <0.50 3.3 Trichloroethylene 0.52 <0.50 30 cis-1,2-Dichloroethylene 1.6 <0.50 720* Notes: (1) = North Carolina Administrative Code 15A 2B Surface Water Standard for Class C Surface Water (H * = Surface water criteria Bold indicates exceedance of NCAC 15A 2B Surface Water standard EPA Method number follows parameter in parenthesis µg/L = micrograms per liter VOCs = Volatile Organic Compounds North Carolina 2B Surface Water Standard (1) Table 4 (Page 1 of 2) Summary of Sub-Slab Soil Vapor Analytical Data Standard Uniform Site600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx Table 4 (Page 1 of 2) Hart & Hickman, PC Te t r a c h l o r o e t h e n e ( P C E ) Tr i c h l o r o e t h e n e ( T C E ) Ac e t o n e Be n z e n e Br o m o d i c h l o r o m e t h a n e 1, 3 - B u t a d i e n e 2- B u t a n o n e ( M E K ) Ca r b o n d i s u l f i d e Ca r b o n T e t r a c h l o r i d e Ch l o r o f o r m Ch l o r o m e t h a n e Cy c l o h e x a n e Di b r o m o c h l o r o m e t h a n e 1, 4 - D i c h l o r o b e n z e n e Di c h l o r o d i f l u o r o m e t h a n e ( F r e o n 1 2 ) 1, 1 - D i c h l o r o e t h a n e 1, 2 - D i c h l o r o e t h a n e 1, 1 - D i c h l o r o e t h y l e n e cis - 1 , 2 - D i c h l o r o e t h e n e (c i s - 1 , 2 - D C E ) tr a n s - 1 , 2 - D i c h l o r o e t h e n e (t r a n s - 1 , 2 - D C E ) 1, 2 - D i c h l o r o - 1 , 1 , 2 , 2 - t e t r a f l u o r o e t h a n e (F r e o n 1 1 4 ) 1, 4 - D i o x a n e Et h a n o l SSVP-1 Warehouse Northeast 04/17/15 TO-15 22 0.21 J 90 1.1 0.52 J <0.22 25 3.6 0.25 J 1.0 0.5 <0.34 0.27 J 0.96 8.7 <0.40 <0.40 <0.40 <0.40 <0.40 <0.70 8.4 36 SSVP-2 Warehouse East 04/17/15 TO-15 20,000 3,100 80 J <3.2 6.3 <2.2 15 J 2.1 J <6.3 38 <4.1 <3.4 4.1 J <6.0 100 <4.0 <4.0 2.5 J 2,900 5.9 <7.0 <36 <75 SSVP-3 Warehouse Southeast 04/17/15 TO-15 49,000 5,100 <95 1.9 J 5.9 J <2.2 16 J 5.0 J <6.3 43 <4.1 <3.4 4.4 J 4.8 J 240 <4.0 <4.0 14 33,000 91 <7.0 <36 43 J SSVP-4 Warehouse Middle 04/17/15 TO-15 5.0 0.19 J 89 0.5 <0.67 <0.22 22 9.7 0.25 J 0.17 J 0.34 J <0.34 <0.85 5.5 190 <0.40 <0.40 <0.40 <0.40 <0.40 0.17 J <3.6 30 SSVP-5 Office Copy Room 04/17/15 TO-15 20 0.42 J 130 0.94 <0.67 <0.22 26 5.3 0.29 J 0.19 J 0.52 <0.34 <0.85 6.1 23 <0.40 <0.40 <0.40 <0.40 <0.40 <0.70 <3.6 21 SSVP-6 Showroom Closet 04/17/15 TO-15 6,700 31 83 J <3.2 <6.7 <2.2 20 J 5.0 J <6.3 1.6 J <4.1 <3.4 <8.5 3.5 J 36 <4.0 <4.0 <4.0 17 <4.0 <7.0 <36 36 J 3,500 175 2,720,000 1,570 331 175 438,000 61,300 2,040 533 7,880 526,000 454 1,110 8,760 7,670 472 17,500 NS NS NS NS NS Notes Bold and orange highlight indicates concentration exceeds Division of Waste Management Sub-slab and Exterior Non-Residential Soil Gas Screening Level (June 2014). Only compounds detected in at least one sample shown DMW = Division of Waste Management NS = Not Specified µg/m3 = micrograms per cubic meter *= Screening level for 1,3,5-trimethylbenzene used as a surrogate for screening level for 1,2,4-trimethylbenzene J = Value indicates compound detected but below the reporting limit; result is an estimated concentration B = Analyte is found in the associated blank as well as in the sample. µg/m3 DWM Non-Residential Soil Gas Screening Level Sa m p l e I D Sa m p l e L o c a t i o n Sa m p l i n g D a t e An a l y t i c a l M e t h o d Table 4 (Page 2 of 2) Summary of Sub-Slab Soil Vapor Analytical Data Standard Uniform Site600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx Table 4 (Page 2 of 2) Hart & Hickman, PC Et h y l A c e t a t e Et h y l b e n z e n e 4- E t h y l t o l u e n e He p t a n e He x a c h l o r o b u t a d i e n e He x a n e 2- H e x a n o n e ( M B K ) Is o p r o p a n o l Me t h y l t e r t b u y t l e t h e n e ( M T B E ) Me t h y l e n e C h l o r i d e Me t h y l I s o b u t y l K e t o n e ( 4 - m e t h y l - 2 - pe n t a n o n e ) Na p h t h a l e n e Pr o p y l e n e ( P r o p e n e ) St y r e n e Te t r a h y d r o f u r a n To l u e n e 1, 1 , 1 - T r i c h l o r o e t h a n e Tr i c h l o r o f l u o r o m e t h a n e ( F r e o n 1 1 ) 1, 1 , 2 - T r i c h l o r o - 1 , 2 , 2 - t r i f l u o r o e t h a n e (F r e o n 1 1 3 ) 1, 2 , 4 - T r i m e t h y l b e n z e n e 1, 3 , 5 - T r i m e t h y l b e n z e n e Vin y l C h l o r i d e To t a l X y l e n e s SSVP-1 Warehouse Northeast 04/17/15 TO-15 3.7 7.7 0.66 <0.41 <1.1 3.9 6.7 9.2 J <0.36 3.9 1.8 2.2 6.2 J 0.43 0.98 3.9 0.23 1.7 J 0.77 J 4.4 1.6 <0.26 40.5 SSVP-2 Warehouse East 04/17/15 TO-15 <3.6 2.0 J 69 <4.1 32 18 J 3.7 J 9.4 J <3.6 9.6 J 1.3 J <5.2 14 J <4.3 <2.9 4.2 <5.5 <22 <31 470 130 4.8 44 SSVP-3 Warehouse Southeast 04/17/15 TO-15 <3.6 1.5 J <4.9 <4.1 4.7 J 21 J 3.8 J 10 J <3.6 7.1 J 1.4 J <5.2 26 J <4.3 <2.9 3.5 J <5.5 2.0 J <31 3.8 J 0.98 J 210 8.2 J SSVP-4 Warehouse Middle 04/17/15 TO-15 5.9 0.73 0.40 J 0.43 <1.1 3.6 J 5.0 4.8 J <0.36 3.4 J 1.8 0.87 8.2 0.66 1.3 2.7 <0.55 1.7 J 0.86 J 2.0 0.57 <0.26 3.25 SSVP-5 Office Copy Room 04/17/15 TO-15 4.2 0.31 J 0.21 J 0.82 <1.1 4.4 J 5.3 9.6 J <0.36 3.4 J 2.4 2.2 8.5 0.35 J 1.5 1.4 <0.55 2.1 J 0.75 J 0.67 0.29 J <0.26 1.46 SSVP-6 Showroom Closet 04/17/15 TO-15 12 <4.3 1.4 J <4.1 <11 18 J 4.1 <98 <3.6 5.3 J 1.8 J <5.2 8.6 J 0.94 J <2.9 2.9 J <5.5 2.1 J <31 3.5 J 1.1 J <2.6 5.3 J 6,130 4,910 NS NS NS 61,300 2,630 NS 47,200 52,600 263,000 263 263,000 87,600 175,000 438,000 438,000 61,300 2,630,000 613 613*2,790 17,520 Notes Bold and orange highlight indicates concentration exceeds Division of Waste Management Sub-slab and Exterior Non-Residential Soil Gas Screening Level (June 2014). Only compounds detected in at least one sample shown DMW = Division of Waste Management NS = Not Specified µg/m3 = micrograms per cubic meter *= Screening level for 1,3,5-trimethylbenzene used as a surrogate for screening level for 1,2,4-trimethylbenzene J = Value indicates compound detected but below the reporting limit; result is an estimated concentration B = Analyte is found in the associated blank as well as in the sample. µg/m3 DWM Non-Residential Soil Gas Screening Level Sa m p l i n g D a t e An a l y t i c a l M e t h o d Sa m p l e I D Sa m p l e L o c a t i o n Table 5 Summary of Indoor and Background Air Analytical Data Standard Uniform Site 600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx Table 5 Hart & Hickman, PC 1, 1 - D i c h l o r o e t h y l e n e ci s - 1 , 2 - D i c h l o r o e t h e n e tr a n s - 1 , 2 - D i c h l o r o e t h e n e Te t r a c h l o r o e t h e n e ( P C E ) Tr i c h l o r o e t h e n e ( T C E ) Vi n y l C h l o r i d e IAS-1 Lobby/Showroom 06/17/15 TO-15 <0.14 0.34 <0.14 16 0.40 <0.090 IAS-2 Warehouse Northeast 06/17/15 TO-15 <0.14 0.15 <0.14 12 0.23 <0.090 IAS-3 Warehouse Southeast 06/17/15 TO-15 <0.14 0.52 <0.14 26 0.62 <0.090 IAS-4 Warehouse Middle 06/17/15 TO-15 <0.14 0.089 J <0.14 5.0 0.12 J <0.090 IAS-5 Office 06/17/15 TO-15 <0.14 0.17 <0.14 12 0.26 <0.090 BAS-1 Outdoor 06/17/15 TO-15 <0.14 <0.14 <0.14 0.38 <0.19 <0.090 175 NE NE 35 1.75 2.79 Notes (1) = Division of Waste Management Non-Residential Indoor Air Screening (june 2014) NE = Not Established µg/m3 = micrograms per cubic meter LICR = Lifetime Incremental Cancer Risk HI = Non-carcinogenic hazard index J = Value indicates compound detected but below the reporting limit; result is an estimated concentration µg/m3 DWM Non-Residential Indoor Air Screening Level (LICR = 1 x 10-6 and HI = 0.2) (1) Sa m p l e I D Sa m p l e L o c a t i o n Sa m p l i n g D a t e An a l y t i c a l M e t h o d Table 6 Calculated Indoor Air Additive Risks Standard Uniform Site 600 Phillip Davis Dr Charlotte, North Carolina H&H Job No. SFR-002 S:\AAA-Master Projects\SFRH Charlotte Flip\Assessment Report\data Tables.xlsx 9/8/2015 Table 6 Hart & Hickman, PC Carcinogenic Risks Unit Location Compound Exposure Conc.IUR AT EF ED ET LICR ug/m3 (ug/m3)-1 days days/yr years hr/hr IAS-1 Tetrachloroethene 16 2.60E-07 25550 250 25 0.33 0.00000034 Trichloroethene 0.40 4.10E-06 25550 250 25 0.33 0.00000013 Total 4.7E-07 IAS-2 Tetrachloroethene 12 2.60E-07 25550 250 25 0.33 0.00000025 Trichloroethene 0.23 4.10E-06 25550 250 25 0.33 0.00000008 Total 3.3E-07 IAS-3 Tetrachloroethene 26 2.60E-07 25550 250 25 0.33 0.00000055 Trichloroethene 0.62 4.10E-06 25550 250 25 0.33 0.00000021 Total 7.6E-07 IAS-4 Tetrachloroethene 5 2.60E-07 25550 250 25 0.33 0.00000011 Trichloroethene 0.12 4.10E-06 25550 250 25 0.33 0.00000004 Total 1.5E-07 IAS-5 Tetrachloroethene 12 2.60E-07 25550 250 25 0.33 0.00000025 Trichloroethene 0.26 4.10E-06 25550 250 25 0.33 0.00000009 Total 3.4E-07 Non-Carcinogenic Risks Unit Location Compound Exposure Conc.Rfc AT EF ED ET Hazard Indexug/m3 mg/m3 days days/yr years hr/hr IAS-1 Tetrachloroethene 16 4.00E-02 9125 250 25 0.33 0.09041096 Trichloroethene 0.40 2.00E-03 9125 250 25 0.33 0.04520548Total1.4E-01 IAS-2 Tetrachloroethene 12 4.00E-02 9125 250 25 0.33 0.06780822 Trichloroethene 0.23 2.00E-03 9125 250 25 0.33 0.02599315 Total 9.4E-02 IAS-3 Tetrachloroethene 26 4.00E-02 9125 250 25 0.33 0.14691781 Trichloroethene 0.62 2.00E-03 9125 250 25 0.33 0.07006849 Total 2.2E-01 IAS-4 Tetrachloroethene 5 4.00E-02 9125 250 25 0.33 0.02851027 Trichloroethene 0.12 2.00E-03 9125 250 25 0.33 0.01368493 Total 4.2E-02 IAS-5 Tetrachloroethene 12 4.00E-02 9125 250 25 0.33 0.06842466 Trichloroethene 0.26 2.00E-03 9125 250 25 0.33 0.02965068 Total 9.8E-02 Equations Used in Risk Calculations Potential Non-Carcinogenic Risks Exposure Conc, (ug/m3) x EF (250 days/year) x ED (25 years) x ET (8 hr/24 hr) x [1/Rfc (mg/m3)] AT [(365 days/year x ED (25 years)] x 1000 (ug/mg) Potential Carcinogenic Risks Exposure Conc, (ug/m3) x EF (250 days/year) x ED (25 years) x ET (8 hr/24 hr) x [IUR (ug/m3)-1])AT [(365 days/years x LT (70years)] where:EF = exposure frequencyED = exposure durationET = exposure time Rfc = Reference concentration AT = averaging time LT = lifetimeIUR = Inhalation unit rate Warehouse (front) Warehouse (Rear) Hazard Index = Lifetime Incremental Cancer Risk = Office Warehouse (middle) Lobby Office Warehouse (middle) Lobby Warehouse (front) Warehouse (Rear) 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) TITLE PROJECT SITE LOCATION MAP 600 PHILLIP DAVIS DRIVE CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 8-13-13 0 1SFR-002 SITE 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f)CHARLOTTE WEST 1996 Appendix A Brownfields Area Reconnaissance and Receptor Survey Form Page 1 of 4 Rev. 06/05/02 General Instructions 1.) 2.) 3.) Site:Classic Party Rentals Address:600 Phillip Davis Dr City:Charlotte County:Mecklenburg Section 1 - Property Characteristics Section 2 - Surrounding Properties X West I-2 (Industrial)/Industrial Same X East I-2 (Industrial)/Industrial Same X North I-2 (Industrial)/Industrial Same X South I-2 (Industrial)/Industrial Same % of property that is agricultural crops % of property that is barren % of property that is used for commercial or industrial usage including paved areas % of property that is scrub/shrub % of property that is open land BROWNFIELDS AREA RECONNAISSANCE AND RECEPTOR SURVEY GUIDANCE FORM Provide Information for the following potential receptors Current Usage Proposed Usage This form was created to facilitate the preparation of a receptor survey for a given brownfield property. This is a guidance document only, and Prospective Developers may complete and submit their own receptor survey, if they desire. Any receptor survey submitted must be completed by a qualified environmental professional. Complete "Property Characteristics" Section and all portions of other sections where an "X" has been placed in the far left column under “Applicable to Site,” as determined by the DENR Brownfields Project Manager on a site specific basis. Applicable to Site (DENR Use Only) Direction from Subject Brownfield Property Current Zoning/Land Use 15 20 Proposed Zoning/Land Use The search-radius distances to potential receptors from the Property boundary will be determined by the DENR Brownfields Project Manager on a site by site basis. Search-radius distances are measured from the site Property Boundary unless otherwise indicated by the DENR Brownfield’s Project Manager. Size of Property (acres) % of property that is wooded % of property that is grass area 5.802 5 10 0 0 50 Page 2 of 4 Rev. 06/05/02 Section 3 - Potential Receptors - include burial depth, construction material and diameter, when available. Distance Direction Depth X Is a basement or subsurface foundation within 500 ft of the Property boundary?N Y 5/1/2015 not applicable not applicable not applicable X Is a school or daycare center within 1000 ft of the Property boundary?N Y 5/1/2015 not applicable not applicable not applicable X Is a storm sewer within 200 ft of the Property boundary? Y Y 5/1/2015 on-site on-site unknown X Is a sanitary sewer within 200 ft of the Property boundary? Y Y 5/1/2015 on-site on-site unknown X Is a septic system leach field within 500 ft of the Property boundary?N Y 5/1/2015 not applicable not applicable not applicable X Is a water line main within 200 ft of Property boundary? Y Y 5/1/2015 on-site on-site unknown X Is a natural gas line main within 200 ft of the Property boundary? Y Y 5/1/2015 on-site on-site unknown X Is a buried telephone/ cable main within 200 ft of the Property boundary?Y Y 5/1/2015 on-site on-site unknown X Is a buried electrical cable main within 200 ft of Property boundary?Y Y 5/1/2015 on-site on-site unknown Section 4 - Local Water Supply Public:Yes Private:No Potable Water Supplier Name:City of Charlotte Potable Water Supply Source:Lake Norman Distance:>15 miles Direction:North Potable Water Source Intake:Lake Norman Distance:>15 miles Direction:North Applicable to Site (DENR Use Only) Provide Information for the following potential receptors Y/N Field Verified Complete and attach map as appropriate Date Verified Page 3 of 4 Rev. 06/05/02 Section 5 - Water Supply Wells Distance Direction Depth X Is a public water supply well within 1000 ft of the Property boundary?N Y 5/1/2015 not applicable not applicable not applicable X Is a private water supply well within 1000 ft of the Property boundary?N Y 5/1/2015 not applicable not applicable not applicable X Is a irrigation supply well within 1000 ft of the Property boundary? N Y 5/1/2015 not applicable not applicable not applicable X Is a monitoring well within 250 ft of the Property boundary? N Y 5/1/2015 not applicable not applicable not applicable Section 6 - Water Bodies on Property Is water body naturally developed or man made? Natural, but appears channelized List the uses of the water body Surface water convetance, stormwater What is the source of the water for the water body Groundwater/precipitation What is the nature of the bottom of the water body (e.g., rocky or concrete bottom, drainage ways or impoundments)rocky, natural X Are there any wetlands present on the property? No Applicable to Site (DENR Use Only) Provide Information for the following potential receptors Comments Complete and attach map as appropriate Applicable to Site (DENR Use Only) Field Verified Provide Information for the following potential receptors Y/N Date Verified Page 4 of 4 Rev. 06/05/02 Section 7 - Surface Water Body Distance Direction Depth X Are there surface waters located within 1000 ft of the Property boundary? Y Unnamed tributary of Irwin Creek C boundary north and ea ~0.5ft to 1 ft Additional water bodies, if needed Section 8 - Additional Requests/ Observations Applicable to Site (DENR Use Only) Provide Information for the following potential receptors Comments Complete and attach map as appropriate Applicable to Site (DENR Use Only) Provide Information for the following potential receptors Y/N Name Type Appendix B Laboratory Analytical Reports Page 1 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 2 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 3 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 4 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 5 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 6 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 7 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 8 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 9 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 10 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 11 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 12 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 13 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 14 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 15 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 16 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 17 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 18 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 19 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 20 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 21 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 22 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 23 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 24 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 25 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 26 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 27 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 28 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 29 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 30 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 31 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 Page 32 of 32 15D1000_1 Contest_Final_MDL 04 28 15 0959 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 Case Narrative 05/08/2015 Hart & Hickman (Charlotte) John Lopez 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: SFR-002 Lab Submittal Date: 05/01/2015 Prism Work Order: 5050029 VA Certification No. 460211 DoD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. VP Laboratory Services Reviewed ByAngela D. Overcash Robbi A. Jones For Angela D. Overcash President/Project Manager Data Qualifiers Key Reference: Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 14 Sample Receipt Summary 05/08/2015 Prism Work Order: 5050029 Client Sample ID MatrixLab Sample ID Date Sampled Date Received 5050029-01 05/01/15SW-1 05/01/15Water 5050029-02 05/01/15SW-2 05/01/15Water Samples were received in good condition at 2.8 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 14 Client ID ResultParameterMethod UnitsPrism ID Prism Work Order: 5050029 05/08/2015 Summary of Detections 1.6 ug/L5050029-01 SW-1 cis-1,2-Dichloroethylene 8260B 35 ug/L5050029-01 SW-1 Tetrachloroethylene 8260B 0.52 ug/L5050029-01 SW-1 Trichloroethylene 8260B This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 14 Laboratory Report 05/08/2015 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Sample Matrix: Water Client Sample ID: SW-1 Prism Sample ID: 5050029-01 Prism Work Order: 5050029 Time Collected: 05/01/15 09:45 Time Submitted: 05/01/15 16:20 Volatile Organic Compounds by GC/MS BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.111,1,1,2-Tetrachloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0611,1,1-Trichloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0361,1,2,2-Tetrachloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0661,1,2-Trichloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0831,1-Dichloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0831,1-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0511,1-Dichloropropylene BRL 8260B P5E008712.0 5/4/15 18:00 VHLug/L 0.401,2,3-Trichlorobenzene BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.141,2,3-Trichloropropane BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.131,2,4-Trichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0541,2,4-Trimethylbenzene BRL 8260B P5E008712.0 5/4/15 18:00 VHLug/L 0.171,2-Dibromo-3-chloropropane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0511,2-Dibromoethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0761,2-Dichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0661,2-Dichloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.111,2-Dichloropropane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0761,3,5-Trimethylbenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0541,3-Dichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0431,3-Dichloropropane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0501,4-Dichlorobenzene BRL 8260B P5E008712.0 5/4/15 18:00 VHLug/L 0.112,2-Dichloropropane BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.372-Chloroethyl Vinyl Ether BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0662-Chlorotoluene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0504-Chlorotoluene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.0894-Isopropyltoluene BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.31Acetone BRL 8260B P5E00871205/4/15 18:00 VHLug/L 0.20Acrolein BRL 8260B P5E00871205/4/15 18:00 VHLug/L 0.20Acrylonitrile BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.048Benzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.057Bromobenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.14Bromochloromethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.062Bromodichloromethane BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.040Bromoform BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.18Bromomethane BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.075Carbon disulfide BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.11Carbon Tetrachloride BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.062Chlorobenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.22Chloroethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.076Chloroform BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.079Chloromethane 1.6 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.056cis-1,2-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.079cis-1,3-Dichloropropylene This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 14 Laboratory Report 05/08/2015 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Sample Matrix: Water Client Sample ID: SW-1 Prism Sample ID: 5050029-01 Prism Work Order: 5050029 Time Collected: 05/01/15 09:45 Time Submitted: 05/01/15 16:20 BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.081Dibromochloromethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.065Dibromomethane BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.11Dichlorodifluoromethane BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.061Ethylbenzene BRL 8260B P5E008712.0 5/4/15 18:00 VHLug/L 0.16Hexachlorobutadiene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.050Isopropyl Ether BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.054Isopropylbenzene (Cumene) BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.12m,p-Xylenes BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.065Methyl Butyl Ketone (2-Hexanone) BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.24Methyl Ethyl Ketone (2-Butanone) BRL 8260B P5E008715.0 5/4/15 18:00 VHLug/L 0.078Methyl Isobutyl Ketone BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.083Methylene Chloride BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.042Methyl-tert-Butyl Ether BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.19Naphthalene BRL 8260B P5E008711.0 5/4/15 18:00 VHLug/L 0.076n-Butylbenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.087n-Propylbenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.044o-Xylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.076sec-Butylbenzene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.047Styrene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.088tert-Butylbenzene 35 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.098Tetrachloroethylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.044Toluene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.094trans-1,2-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.070trans-1,3-Dichloropropylene 0.52 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.078Trichloroethylene BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.062Trichlorofluoromethane BRL 8260B P5E008712.0 5/4/15 18:00 VHLug/L 0.060Vinyl acetate BRL 8260B P5E008710.50 5/4/15 18:00 VHLug/L 0.097Vinyl chloride Surrogate Recovery Control Limits 80-124118 %4-Bromofluorobenzene 75-129115 %Dibromofluoromethane 77-123104 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 14 Laboratory Report 05/08/2015 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Sample Matrix: Water Client Sample ID: SW-2 Prism Sample ID: 5050029-02 Prism Work Order: 5050029 Time Collected: 05/01/15 09:55 Time Submitted: 05/01/15 16:20 Volatile Organic Compounds by GC/MS BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.111,1,1,2-Tetrachloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0611,1,1-Trichloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0361,1,2,2-Tetrachloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0661,1,2-Trichloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0831,1-Dichloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0831,1-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0511,1-Dichloropropylene BRL 8260B P5E008712.0 5/4/15 18:26 VHLug/L 0.401,2,3-Trichlorobenzene BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.141,2,3-Trichloropropane BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.131,2,4-Trichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0541,2,4-Trimethylbenzene BRL 8260B P5E008712.0 5/4/15 18:26 VHLug/L 0.171,2-Dibromo-3-chloropropane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0511,2-Dibromoethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0761,2-Dichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0661,2-Dichloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.111,2-Dichloropropane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0761,3,5-Trimethylbenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0541,3-Dichlorobenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0431,3-Dichloropropane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0501,4-Dichlorobenzene BRL 8260B P5E008712.0 5/4/15 18:26 VHLug/L 0.112,2-Dichloropropane BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.372-Chloroethyl Vinyl Ether BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0662-Chlorotoluene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0504-Chlorotoluene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.0894-Isopropyltoluene BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.31Acetone BRL 8260B P5E00871205/4/15 18:26 VHLug/L 0.20Acrolein BRL 8260B P5E00871205/4/15 18:26 VHLug/L 0.20Acrylonitrile BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.048Benzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.057Bromobenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.14Bromochloromethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.062Bromodichloromethane BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.040Bromoform BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.18Bromomethane BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.075Carbon disulfide BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.11Carbon Tetrachloride BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.062Chlorobenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.22Chloroethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.076Chloroform BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.079Chloromethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.056cis-1,2-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.079cis-1,3-Dichloropropylene This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 14 Laboratory Report 05/08/2015 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Sample Matrix: Water Client Sample ID: SW-2 Prism Sample ID: 5050029-02 Prism Work Order: 5050029 Time Collected: 05/01/15 09:55 Time Submitted: 05/01/15 16:20 BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.081Dibromochloromethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.065Dibromomethane BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.11Dichlorodifluoromethane BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.061Ethylbenzene BRL 8260B P5E008712.0 5/4/15 18:26 VHLug/L 0.16Hexachlorobutadiene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.050Isopropyl Ether BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.054Isopropylbenzene (Cumene) BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.12m,p-Xylenes BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.065Methyl Butyl Ketone (2-Hexanone) BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.24Methyl Ethyl Ketone (2-Butanone) BRL 8260B P5E008715.0 5/4/15 18:26 VHLug/L 0.078Methyl Isobutyl Ketone BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.083Methylene Chloride BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.042Methyl-tert-Butyl Ether BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.19Naphthalene BRL 8260B P5E008711.0 5/4/15 18:26 VHLug/L 0.076n-Butylbenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.087n-Propylbenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.044o-Xylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.076sec-Butylbenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.047Styrene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.088tert-Butylbenzene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.098Tetrachloroethylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.044Toluene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.094trans-1,2-Dichloroethylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.070trans-1,3-Dichloropropylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.078Trichloroethylene BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.062Trichlorofluoromethane BRL 8260B P5E008712.0 5/4/15 18:26 VHLug/L 0.060Vinyl acetate BRL 8260B P5E008710.50 5/4/15 18:26 VHLug/L 0.097Vinyl chloride Surrogate Recovery Control Limits 80-124114 %4-Bromofluorobenzene 75-129115 %Dibromofluoromethane 77-123103 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B Blank (P5E0087-BLK1)Prepared & Analyzed: 05/04/15 1,1,1,2-Tetrachloroethane ug/LBRL0.50 1,1,1-Trichloroethane ug/LBRL0.50 1,1,2,2-Tetrachloroethane ug/LBRL0.50 1,1,2-Trichloroethane ug/LBRL0.50 1,1-Dichloroethane ug/LBRL0.50 1,1-Dichloroethylene ug/LBRL0.50 1,1-Dichloropropylene ug/LBRL0.50 1,2,3-Trichlorobenzene ug/LBRL2.0 1,2,3-Trichloropropane ug/LBRL1.0 1,2,4-Trichlorobenzene ug/LBRL1.0 1,2,4-Trimethylbenzene ug/LBRL0.50 1,2-Dibromo-3-chloropropane ug/LBRL2.0 1,2-Dibromoethane ug/LBRL0.50 1,2-Dichlorobenzene ug/LBRL0.50 1,2-Dichloroethane ug/LBRL0.50 1,2-Dichloropropane ug/LBRL0.50 1,3,5-Trimethylbenzene ug/LBRL0.50 1,3-Dichlorobenzene ug/LBRL0.50 1,3-Dichloropropane ug/LBRL0.50 1,4-Dichlorobenzene ug/LBRL0.50 2,2-Dichloropropane ug/LBRL2.0 2-Chloroethyl Vinyl Ether ug/LBRL5.0 2-Chlorotoluene ug/LBRL0.50 4-Chlorotoluene ug/LBRL0.50 4-Isopropyltoluene ug/LBRL0.50 Acetone ug/LBRL5.0 Acrolein ug/LBRL20 Acrylonitrile ug/LBRL20 Benzene ug/LBRL0.50 Bromobenzene ug/LBRL0.50 Bromochloromethane ug/LBRL0.50 Bromodichloromethane ug/LBRL0.50 Bromoform ug/LBRL1.0 Bromomethane ug/LBRL1.0 Carbon disulfide ug/LBRL5.0 Carbon Tetrachloride ug/LBRL0.50 Chlorobenzene ug/LBRL0.50 Chloroethane ug/LBRL0.50 Chloroform ug/LBRL0.50 Chloromethane ug/LBRL0.50 cis-1,2-Dichloroethylene ug/LBRL0.50 cis-1,3-Dichloropropylene ug/LBRL0.50 Dibromochloromethane ug/LBRL0.50 Dibromomethane ug/LBRL0.50 Dichlorodifluoromethane ug/LBRL1.0 Ethylbenzene ug/LBRL0.50 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B Blank (P5E0087-BLK1)Prepared & Analyzed: 05/04/15 Hexachlorobutadiene ug/LBRL2.0 Isopropyl Ether ug/LBRL0.50 Isopropylbenzene (Cumene)ug/LBRL0.50 m,p-Xylenes ug/LBRL1.0 Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0 Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0 Methyl Isobutyl Ketone ug/LBRL5.0 Methylene Chloride ug/LBRL1.0 Methyl-tert-Butyl Ether ug/LBRL0.50 Naphthalene ug/LBRL1.0 n-Butylbenzene ug/LBRL1.0 n-Propylbenzene ug/LBRL0.50 o-Xylene ug/LBRL0.50 sec-Butylbenzene ug/LBRL0.50 Styrene ug/LBRL0.50 tert-Butylbenzene ug/LBRL0.50 Tetrachloroethylene ug/LBRL0.50 Toluene ug/LBRL0.50 trans-1,2-Dichloroethylene ug/LBRL0.50 trans-1,3-Dichloropropylene ug/LBRL0.50 Trichloroethylene ug/LBRL0.50 Trichlorofluoromethane ug/LBRL0.50 Vinyl acetate ug/LBRL2.0 Vinyl chloride ug/LBRL0.50 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 11356.5 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10954.7 ug/L 50.00 77-123Surrogate: Toluene-d8 10451.8 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B LCS (P5E0087-BS1)Prepared & Analyzed: 05/04/15 1,1,1,2-Tetrachloroethane ug/L20.7 0.50 20.00 79-134104 1,1,1-Trichloroethane ug/L23.8 0.50 20.00 75-136119 1,1,2,2-Tetrachloroethane ug/L18.1 0.50 20.00 62-12790 1,1,2-Trichloroethane ug/L19.9 0.50 20.00 70-140100 1,1-Dichloroethane ug/L20.2 0.50 20.00 78-130101 1,1-Dichloroethylene ug/L21.9 0.50 20.00 70-154110 1,1-Dichloropropylene ug/L20.3 0.50 20.00 71-136102 1,2,3-Trichlorobenzene ug/L21.1 2.0 20.00 58-144106 1,2,3-Trichloropropane ug/L19.6 1.0 20.00 71-12798 1,2,4-Trichlorobenzene ug/L24.4 1.0 20.00 66-139122 1,2,4-Trimethylbenzene ug/L19.2 0.50 20.00 75-13396 1,2-Dibromo-3-chloropropane ug/L18.8 2.0 20.00 63-13494 1,2-Dibromoethane ug/L20.9 0.50 20.00 77-135105 1,2-Dichlorobenzene ug/L21.0 0.50 20.00 78-128105 1,2-Dichloroethane ug/L21.7 0.50 20.00 68-131108 1,2-Dichloropropane ug/L19.9 0.50 20.00 77-130100 1,3,5-Trimethylbenzene ug/L19.0 0.50 20.00 75-13195 1,3-Dichlorobenzene ug/L21.0 0.50 20.00 77-125105 1,3-Dichloropropane ug/L19.8 0.50 20.00 76-13299 1,4-Dichlorobenzene ug/L19.9 0.50 20.00 75-126100 2,2-Dichloropropane ug/L23.4 2.0 20.00 29-149117 2-Chloroethyl Vinyl Ether ug/L16.6 5.0 20.00 34-14483 2-Chlorotoluene ug/L18.9 0.50 20.00 74-12695 4-Chlorotoluene ug/L20.8 0.50 20.00 78-129104 4-Isopropyltoluene ug/L18.7 0.50 20.00 69-13294 Acetone ug/L42.3 5.0 40.00 40-166106 Acrolein ug/L35.2 20 40.00 70-13088 Acrylonitrile ug/L38.0 20 40.00 81-12795 Benzene ug/L20.2 0.50 20.00 77-128101 Bromobenzene ug/L20.7 0.50 20.00 78-129104 Bromochloromethane ug/L19.9 0.50 20.00 78-13599 Bromodichloromethane ug/L19.2 0.50 20.00 76-13896 Bromoform ug/L19.9 1.0 20.00 71-135100 Bromomethane ug/L20.0 1.0 20.00 41-168100 Carbon disulfide ug/L23.6 5.0 20.00 59-135118 Carbon Tetrachloride ug/L25.5 0.50 20.00 72-142128 Chlorobenzene ug/L20.3 0.50 20.00 78-119101 Chloroethane ug/L20.2 0.50 20.00 57-142101 Chloroform ug/L19.9 0.50 20.00 77-130100 Chloromethane ug/L19.3 0.50 20.00 47-14597 cis-1,2-Dichloroethylene ug/L21.4 0.50 20.00 76-141107 cis-1,3-Dichloropropylene ug/L21.1 0.50 20.00 65-140105 Dibromochloromethane ug/L19.4 0.50 20.00 75-13497 Dibromomethane ug/L20.3 0.50 20.00 76-138102 Dichlorodifluoromethane ug/L21.2 1.0 20.00 28-163106 Ethylbenzene ug/L20.9 0.50 20.00 80-127105 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B LCS (P5E0087-BS1)Prepared & Analyzed: 05/04/15 Hexachlorobutadiene ug/L25.2 2.0 20.00 61-134126 Isopropyl Ether ug/L18.1 0.50 20.00 60-15491 Isopropylbenzene (Cumene)ug/L20.9 0.50 20.00 70-130105 m,p-Xylenes ug/L44.2 1.0 40.00 77-133111 Methyl Butyl Ketone (2-Hexanone)ug/L19.0 5.0 20.00 64-13795 Methyl Ethyl Ketone (2-Butanone)ug/L20.2 5.0 20.00 71-134101 Methyl Isobutyl Ketone ug/L18.2 5.0 20.00 69-13491 Methylene Chloride ug/L18.7 1.0 20.00 73-13193 Methyl-tert-Butyl Ether ug/L21.6 0.50 20.00 68-135108 Naphthalene ug/L21.7 1.0 20.00 64-136109 n-Butylbenzene ug/L19.2 1.0 20.00 68-13496 n-Propylbenzene ug/L19.2 0.50 20.00 72-13296 o-Xylene ug/L18.6 0.50 20.00 78-12893 sec-Butylbenzene ug/L19.6 0.50 20.00 71-13198 Styrene ug/L18.5 0.50 20.00 78-12993 tert-Butylbenzene ug/L19.6 0.50 20.00 70-13298 Tetrachloroethylene ug/L22.4 0.50 20.00 80-129112 Toluene ug/L20.2 0.50 20.00 76-131101 trans-1,2-Dichloroethylene ug/L20.9 0.50 20.00 76-135104 trans-1,3-Dichloropropylene ug/L21.5 0.50 20.00 67-140108 Trichloroethylene ug/L22.2 0.50 20.00 77-133111 Trichlorofluoromethane ug/L23.7 0.50 20.00 62-148119 Vinyl acetate ug/L21.6 2.0 20.00 34-167108 Vinyl chloride ug/L22.0 0.50 20.00 57-141110 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 11255.8 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10954.3 ug/L 50.00 77-123Surrogate: Toluene-d8 10452.0 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B LCS Dup (P5E0087-BSD1)Prepared & Analyzed: 05/04/15 1,1,1,2-Tetrachloroethane ug/L20.8 0.50 20.00 2079-134104 0.5 1,1,1-Trichloroethane ug/L23.8 0.50 20.00 2075-136119 0.04 1,1,2,2-Tetrachloroethane ug/L17.6 0.50 20.00 2062-12788 2 1,1,2-Trichloroethane ug/L18.8 0.50 20.00 2070-14094 5 1,1-Dichloroethane ug/L20.2 0.50 20.00 2078-130101 0.2 1,1-Dichloroethylene ug/L21.7 0.50 20.00 2070-154108 0.9 1,1-Dichloropropylene ug/L20.1 0.50 20.00 2071-136100 1 1,2,3-Trichlorobenzene ug/L18.0 2.0 20.00 2058-14490 16 1,2,3-Trichloropropane ug/L19.6 1.0 20.00 2071-12798 0.4 1,2,4-Trichlorobenzene ug/L22.8 1.0 20.00 2066-139114 7 1,2,4-Trimethylbenzene ug/L19.2 0.50 20.00 2075-13396 0.3 1,2-Dibromo-3-chloropropane ug/L17.9 2.0 20.00 2063-13489 5 1,2-Dibromoethane ug/L20.8 0.50 20.00 2077-135104 0.6 1,2-Dichlorobenzene ug/L20.6 0.50 20.00 2078-128103 2 1,2-Dichloroethane ug/L20.5 0.50 20.00 2068-131103 5 1,2-Dichloropropane ug/L19.5 0.50 20.00 2077-13098 2 1,3,5-Trimethylbenzene ug/L19.0 0.50 20.00 2075-13195 0 1,3-Dichlorobenzene ug/L20.4 0.50 20.00 2077-125102 3 1,3-Dichloropropane ug/L20.0 0.50 20.00 2076-132100 0.8 1,4-Dichlorobenzene ug/L19.7 0.50 20.00 2075-12698 1 2,2-Dichloropropane ug/L22.7 2.0 20.00 2029-149113 3 2-Chloroethyl Vinyl Ether ug/L17.4 5.0 20.00 2034-14487 5 2-Chlorotoluene ug/L18.5 0.50 20.00 2074-12693 2 4-Chlorotoluene ug/L20.6 0.50 20.00 2078-129103 0.9 4-Isopropyltoluene ug/L18.8 0.50 20.00 2069-13294 0.4 Acetone ug/L38.4 5.0 40.00 2040-16696 10 Acrolein ug/L31.6 20 40.00 2070-13079 11 Acrylonitrile ug/L36.7 20 40.00 2081-12792 4 Benzene ug/L19.9 0.50 20.00 2077-128100 1 Bromobenzene ug/L20.1 0.50 20.00 2078-129100 3 Bromochloromethane ug/L19.0 0.50 20.00 2078-13595 4 Bromodichloromethane ug/L18.6 0.50 20.00 2076-13893 3 Bromoform ug/L18.9 1.0 20.00 2071-13594 6 Bromomethane ug/L20.7 1.0 20.00 2041-168104 3 Carbon disulfide ug/L23.3 5.0 20.00 2059-135116 1 Carbon Tetrachloride ug/L25.6 0.50 20.00 2072-142128 0.6 Chlorobenzene ug/L20.6 0.50 20.00 2078-119103 1 Chloroethane ug/L19.6 0.50 20.00 2057-14298 3 Chloroform ug/L19.2 0.50 20.00 2077-13096 3 Chloromethane ug/L18.7 0.50 20.00 2047-14593 3 cis-1,2-Dichloroethylene ug/L20.6 0.50 20.00 2076-141103 4 cis-1,3-Dichloropropylene ug/L20.8 0.50 20.00 2065-140104 1 Dibromochloromethane ug/L19.3 0.50 20.00 2075-13496 0.4 Dibromomethane ug/L19.6 0.50 20.00 2076-13898 4 Dichlorodifluoromethane ug/L21.5 1.0 20.00 2028-163108 1 Ethylbenzene ug/L21.2 0.50 20.00 2080-127106 1 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 14 5/8/15 Level II QC Report 2923 South Tryon St. Ste 100 Project: SFR-002Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: John Lopez Prism Work Order: 5050029 Time Submitted: 5/1/2015 4:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P5E0087 - 5030B LCS Dup (P5E0087-BSD1)Prepared & Analyzed: 05/04/15 Hexachlorobutadiene ug/L22.8 2.0 20.00 2061-134114 10 Isopropyl Ether ug/L17.6 0.50 20.00 2060-15488 3 Isopropylbenzene (Cumene)ug/L20.4 0.50 20.00 2070-130102 2 m,p-Xylenes ug/L44.6 1.0 40.00 2077-133112 0.9 Methyl Butyl Ketone (2-Hexanone)ug/L17.9 5.0 20.00 2064-13790 6 Methyl Ethyl Ketone (2-Butanone)ug/L18.3 5.0 20.00 2071-13492 10 Methyl Isobutyl Ketone ug/L16.9 5.0 20.00 2069-13485 7 Methylene Chloride ug/L17.8 1.0 20.00 2073-13189 5 Methyl-tert-Butyl Ether ug/L21.1 0.50 20.00 2068-135106 2 Naphthalene ug/L18.7 1.0 20.00 2064-13694 15 n-Butylbenzene ug/L18.8 1.0 20.00 2068-13494 2 n-Propylbenzene ug/L18.8 0.50 20.00 2072-13294 2 o-Xylene ug/L19.3 0.50 20.00 2078-12896 4 sec-Butylbenzene ug/L19.6 0.50 20.00 2071-13198 0.3 Styrene ug/L18.9 0.50 20.00 2078-12994 2 tert-Butylbenzene ug/L19.4 0.50 20.00 2070-13297 1 Tetrachloroethylene ug/L23.2 0.50 20.00 2080-129116 3 Toluene ug/L19.9 0.50 20.00 2076-13199 2 trans-1,2-Dichloroethylene ug/L20.9 0.50 20.00 2076-135104 0 trans-1,3-Dichloropropylene ug/L20.5 0.50 20.00 2067-140102 5 Trichloroethylene ug/L21.4 0.50 20.00 2077-133107 4 Trichlorofluoromethane ug/L23.9 0.50 20.00 2062-148120 0.9 Vinyl acetate ug/L20.8 2.0 20.00 2034-167104 4 Vinyl chloride ug/L22.5 0.50 20.00 2057-141112 2 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10753.4 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10351.3 ug/L 50.00 77-123Surrogate: Toluene-d8 10351.4 Sample Extraction Data Prep Method: 5030B Lab Number Batch Date/TimeInitialFinal P5E00875050029-01 05/04/15 15:5510 10mL mL P5E00875050029-02 05/04/15 15:5510 10mL mL This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 14 Page 14 of 14 Page 1 of 17 15F1079 FINAL 06 30 15 1219 Page 2 of 17 15F1079 FINAL 06 30 15 1219 Page 3 of 17 15F1079 FINAL 06 30 15 1219 Page 4 of 17 15F1079 FINAL 06 30 15 1219 Page 5 of 17 15F1079 FINAL 06 30 15 1219 Page 6 of 17 15F1079 FINAL 06 30 15 1219 Page 7 of 17 15F1079 FINAL 06 30 15 1219 Page 8 of 17 15F1079 FINAL 06 30 15 1219 Page 9 of 17 15F1079 FINAL 06 30 15 1219 Page 10 of 17 15F1079 FINAL 06 30 15 1219 Page 11 of 17 15F1079 FINAL 06 30 15 1219 Page 12 of 17 15F1079 FINAL 06 30 15 1219 Page 13 of 17 15F1079 FINAL 06 30 15 1219 Page 14 of 17 15F1079 FINAL 06 30 15 1219 Page 15 of 17 15F1079 FINAL 06 30 15 1219 Page 16 of 17 15F1079 FINAL 06 30 15 1219 Page 17 of 17 15F1079 FINAL 06 30 15 1219