Loading...
HomeMy WebLinkAbout8106_DukeRogers_Oct2016_2ndSemiAnnual_DIN27365_20170206526 South Church Street Charlotte, NC 28202 Mailing Address: PO Box 1006 Mail Code EC13K Charlotte, NC 28201-1006 980 373 2779 704 382 6240 fax February 6, 2017 Ms. Elizabeth Werner North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 1646 Mail Service Center Raleigh, NC 27699-1646 Subject: Semi-annual Groundwater Monitoring Report - October 2016 Duke Energy Carolinas, LLC Permit No. 8106-INDUS Rogers Energy Complex (formerly Cliffside Steam Station) 573 Duke Power Road, Mooresboro, NC 28114 Dear Ms. Werner: Duke Energy is providing the results of semi-annual groundwater monitoring for the Rogers Energy Complex CCP Landfill, located in Mooresboro, North Carolina. On October 12, 2016, groundwater and surface water samples were collected in accordance with the Water Quality Monitoring Plan. Table 4 provides a summary of groundwater field and analytical results. Table 6 provides a summary of surface water field and analytical results. Table 7 provides a summary of leachate field and analytical results. Duke Energy personnel sample designated groundwater and surface water locations at the Rogers Energy Complex CCP Landfill semi-annually during April and October. The next landfill monitoring event is planned for April 2017 with a report of monitoring results to follow. If you have any questions or concerns, please contact me at 980-373-2779 or at Ryan.Czop@duke-energy.com. Respectfully submitted, Ryan Czop, Engineer I Environmental Services Electronic cc: Steve Hodges, Duke Energy Tim Hunsucker, Duke Energy Sean DeNeale, Duke Energy Ed Sullivan, Duke Energy Jessica Snyder, Duke Energy Scott Spinner, HDR Engineering, Inc. Ian Holdeman, HDR Engineering, Inc. Coal Combustion Products (CCP) Landfill Phases I and II Permit No. 8106 Semiannual Groundwater Monitoring Report October 2016 Sampling Event Rogers Energy Complex February 2, 2017 Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Contents i Contents Page Contents ......................................................................................................................................... i Section 1 – Background ................................................................................................................ 1 Section 2 – Methods ..................................................................................................................... 3 2.1 Sampling and Analysis Methods .................................................................................... 3 2.2 Statement of Work .......................................................................................................... 3 Section 3 - Results ........................................................................................................................ 5 3.1 Site Groundwater Flow ................................................................................................... 5 3.2 Analytical Results ........................................................................................................... 5 Figures 1. Site Location Map 2. Sample Locations 3. Generalized Groundwater Surface Contours Tables 1. Well Construction Information 2. Groundwater Flow Velocities 3. Field Data Parameters 4. Groundwater Field and Analytical Results 5. Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards 6. Surface Water Field and Analytical Results 7. Leachate Field and Analytical Results Appendices Appendix A – Field Sampling Forms Appendix B – Laboratory Report and Chain-of-Custody Forms Appendix C – January 3, 2017 Discharge Event Laboratory Report and Chain-of-Custody Form Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 1 – Background 1 Section 1 – Background Rogers Energy Complex is located in Rutherford and Cleveland Counties near Cliffside, North Carolina. The station is owned and operated by Duke Energy Carolinas, LLC (Duke Energy) and generates electricity by combustion of coal. The Coal Combustion Products (CCP) Landfill, Phases I and II, was constructed with an engineered liner system and permitted to receive fly ash, bottom ash, boiler slag, mill rejects, flue gas desulfurization sludge, gypsum, leachate basin sludge, non-hazardous sandblast material, limestone, ball mill rejects, coal, carbon, sulfur pellets, cation and anion resins, sediment from sumps, cooling tower sludge, filter bags, conditioning agents (e.g.: lime kiln dust), soil material that contains any of the above material, and soil used for operations under North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8106. Waste was first placed into the landfill on October 24, 2010. The CCP landfill is located southwest of the Rogers Energy Complex on Duke Energy property and is situated completely within Rutherford County. The CCP landfill is northeast of the intersection of Old U.S. Highway 221A and Ballenger Road (Figure 1). Phase I of the CCP landfill has a footprint of approximately 23 acres. Construction of Phase II was completed in early 2016 and has a footprint of approximately 15 acres. The monitoring plan for this phase has been approved by the Solid Waste Section. The monitoring system for Phase I and II of the landfill consists of 13 groundwater monitoring wells, 3 surface water sample locations, and 1 leachate sampling location as listed below. This is the first report presenting data from Phase II. Monitoring Wells: Phase I CCPMW-1S CCPMW-1D CCPMW-2S CCPMW-2D CCPMW-3S CCPMW-3D CCPTW-1S CCPTW-1D CCPTW-2 Phase II CCPMW-4 CCPMW-5 CCPMW-6S CCPMW-6D Surface Water: CCPSW-1 CCPSW-2 CCPSW-3 Leachate Sample: CCP-Leachate The groundwater monitoring wells, surface water sample locations, and leachate sample locations are shown on Figure 2. Wells with a “D” designation (e.g., CCPMW-1D) are deep wells that were installed with the well screen below auger refusal. Wells with an “S” designation or no designation (e.g., CCPTW-2) are shallow wells that were installed with the well screen above auger refusal. Well construction information is presented in Table 1. The leachate sample is Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 1 – Background 2 collected at the inlet to the leachate basin instead of the sampling port next to the landfill. The sample port at the edge of the landfill was getting clogged with silt between sampling events. There is not a good location to flush the sampling port out so it was decided to collect a sample where the leachate enters the leachate basin. The inlet to the leachate basin is high on the bank so the sample represents the leachate entering the concrete basin. The leachate basin is located on the southeast side of the landfill. As is typical in the Piedmont region, groundwater at the landfill site occurs within the residuum, saprolite, partially weathered rock, and fractured bedrock. Groundwater generally flows from regions of higher topography to regions of lower topography. The highest topographic area at the landfill site is along the western edge of the landfill. Monitoring wells CCPMW-1S and CCPMW-1D are considered by the Water Quality Monitoring Plan as background wells for the landfill.1 Two drainage features are located in close proximity to the CCP landfill: one to the northwest and one to the southeast. Based on the generalized groundwater surface contours developed using the groundwater elevations measured in the shallow wells (Figure 3), the expected groundwater discharge area for the landfill is to Suck Creek, located southeast of the landfill. Suck Creek flows to the north, to the Broad River. 1 Duke Energy Progress, Inc Cliffside CCP Landfill Facility Permit No. 81-06 Water Quality Monitoring Plan, (Updated January 2016). Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 2 – Methods 3 Section 2 – Methods 2.1 Sampling and Analysis Methods Groundwater, surface water, and leachate sampling, as well as documentation of sampling activities were performed by Duke Energy personnel (Duke Energy Carolinas Field Certification #5193). Copies of the field sampling forms are included in Appendix A. The parameters and constituents reported were analyzed by Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248). Samples were analyzed for the following constituents:2  Barium, boron, copper, iron, manganese, silver, and zinc using Solid Waste (SW)-8463 Method 6010D  Arsenic, cadmium, chromium, lead, nickel, and selenium using SW-846 Method 6020B  Mercury using Environmental Protection Agency (EPA) Method 7470A  Chloride, fluoride, nitrate as nitrogen, and sulfate using SW-846 Method 9056A  Total dissolved solids using Standard Method (SM) 2540C Surface water sample locations CCPSW-1 and CCPSW-2 were also field filtered using a 0.45 micron in-line filter and dissolved analysis performed for the following constituents:  Cadmium, chromium, copper, lead, nickel, and silver using SW-846 Method 6020B  Zinc using SW-846 Method 6010D 2.2 Statement of Work HDR completed the following tasks:  Received field sampling information provided by Duke Energy (performed by Duke Energy personnel) for monitoring wells CCPMW-1S, CCPMW-1D, CCPMW-2S, CCPMW-2D, CCPMW-3D, CCPMW-4, CCPMW-5, CCPMW-6S, CCPMW-6D, CCPTW-1S, CCPTW-1D, and CCPTW-2. Data was also received for surface water sample locations CCPSW-1 and CCPSW-2 and for leachate sampling location CCP-Leachate. A groundwater sample was not obtainable from CCPMW-3S as it was dry. A surface water sample was not obtainable from CCPSW-3 as it was also dry. The samples were collected on October 12, 2016, and HDR received the data on November 8, 2016. 2 Samples were analyzed for constituents listed in Table 2 of the updated Water Quality Monitoring Plan: Duke Energy Progress, Inc Cliffside CCP Landfill Facility Permit No. 81-06 Water Quality Monitoring Plan, (Updated January 2016). 3 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846 (Accessed August 30, 2016) Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 2 – Methods 4  Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable (EDDs) provided by Duke Energy were adapted to conform to the format requirements of the NCDEQ EDD template. In the EDDs, HDR added an italicized J data qualifier (J) to indicate a detected concentration that equals or is greater than the laboratory’s method reporting limit (MRL), but less than the Solid Waste Section Limit4 (SWSL), and retained the laboratory- supplied qualifier J to indicate values that equal or are greater than the laboratory’s method detection limit (MDL) but are less than the MRL. Copies of the original EDDs are retained in HDR’s files.  Developed a generalized groundwater surface contour map using map data and groundwater elevation data supplied by Duke Energy. Calculated groundwater flow velocities are based on groundwater surface contours.  Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke Energy. 4 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 3 - Results 5 Section 3 - Results 3.1 Site Groundwater Flow Generalized groundwater surface contours and groundwater flow direction arrows for the site are shown on Figure 3. These contours were developed using the measured groundwater elevations in the shallow wells on the date of sampling. Calculated groundwater flow velocities are presented in Table 2. Groundwater at the site generally flows from the upgradient elevation near CCPMW-1S to the southeast toward Suck Creek. 3.2 Analytical Results A summary of the field data is presented in Table 3. The groundwater sampling field and analytical results are summarized in Table 4. The groundwater analytical results for the semiannual constituents are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations with values that attain or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the groundwater analytical results that attain or exceed the 2L Standards and a preliminary analysis of the cause and significance of the exceedances are presented in Table 5. Surface water sample locations CCPSW-1 and CCPSW-2 are located on Suck Creek. As a result, the field and analytical results for these two locations are compared to Title 15A NCAC Subchapter 2B Standards (2B Standards) for Class WS-IV surface water. The field and analytical results for surface water sampling are summarized in Table 6. Surface water sample location CCPSW-3 is located in a drainage swale parallel to Old U.S. Highway 221A flowing north towards the Broad River and, as such, is compared to Class WS-IV surface water. The MDL was greater than the respective 2B Standard for mercury. The MDL for mercury was below the corresponding SWSL as required in the February 23, 2007, NCDEQ memo. This constituent was not detected above the MDL in the analyzed samples and is not considered to exceed the 2B Standard. The field and analytical results for leachate sampling are summarized in Table 7. Concentrations with values that equal or are greater than the SWSLs are noted in Tables 4, 6, and 7 by gray-shaded cells. Select samples were diluted, as is normal laboratory practice, to bring samples within the calibrated range of the analysis. Specifics regarding the samples that were diluted, including the dilution factor, are reported in the EDD. The laboratory report and chain-of-custody forms can be found in Appendix B. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Rogers Energy Complex, CCP Landfill, Phases I and II, Permit No.8106 October 2016 Sampling Event Section 3 - Results 6 On January 3, 2017, contact storm water accumulated inside a section of Phase I of the Rogers CCP Landfill. The contact storm water was released through an earthen berm that failed, travelled down a landfill exit ramp, flowed from the landfill into site sediment and/or collection basins, and discharged into Suck Creek from sediment basin SB-2. Samples taken from both sediment basin SB-2 and the Phase III Non-Contact Sediment Basin were analyzed for parameters included in landfill Water Quality Monitoring Plan and provided to the Section on January 18, 2017. These results have also been included in Appendix C. FIGURES #RRTQZKOCVG.CPFHKNN$QWPFCT[ 1N F  7  5   * K I J Y C [     # $CNNGPIGT4QCF %NKHHUKFG5VGCO5VCVKQP $TQCF4KXGT COALCOMBUSTION RESIDUALS LANDFILL PERMIT NO. 8106 0QVGU 5QWTEG75)56QRQITCRJKE/CRÄ%JGUPGG 3WCFTCPING&CVGF %QPVQWTKPVGTXCNUKPHGGV 5%#.' (''6 1000 0 1000 2000 SITE LOCATION MAP ROGERS ENERGY COMPLEX CCP LANDFILL PHASES I AND II PERMIT NO. 8106 FEBRUARY 2017 1 HDR Engineering Inc. 440 S. Church St. Suite 1000 Charlotte, NC 28202-2075 704.338.6700 of the Carolinas DATE FIGURE %%269Ä %%2/9Ä %%2/9Ä5 %%2/9Ä& %%2.'#%*#6' OL D U . S . 2 2 1 A RAILRO A D %%2/9Ä %%2/9Ä5 5'&+/'06$#5+05 .+/+61(9#56' .#0&(+..4'8+'9 $170&#4; .#0&(+..%1/2.+#0%'$170&#4; &7-'2412'46;$170&#4; .'#%*#6'$#5+0 5 W E M  % T G G M 5WEM  % T G G M %%259Ä %%259Ä %%259Ä )TQWPFYCVGT/QPKVQTKPI9GNN 5WTHCEG9CVGT5CORNKPI.QECVKQP .GCEJCVG5CORNKPI.QECVKQP .KOKVQH9CUVG .CPFHKNN4GXKGY$QWPFCT[ .CPFHKNN%QORNKCPEG$QWPFCT[ &WMG2TQRGTV[$QWPFCT[ $CUG/CR2TQXKFGFD[&WMG'PGTI[%CTQNKPCU&CVGF&GEGODGT 300 600 5%#.' (''6 0 300 SAMPLE LOCATIONS ROGERS ENERGY COMPLEX CCP LANDFILL PHASES I AND II PERMIT NO. 8106 FEBRUARY 2017 2 HDR Engineering Inc. 440 S. Church St. Suite 1000 Charlotte, NC 28202-2075 704.338.6700 of the Carolinas DATE FIGURE ž ž &4; &WMG 'PGTI[ 2TQRGTV[ %%2/9Ä5 %%2/9Ä& %%269Ä ž ž %%269Ä ž %%2/9Ä ž %%2/9Ä5 %%2/9Ä& %%2.'#%*#6' OL D U . S . 2 2 1 A RAILRO A D %%2/9Ä %%2/9Ä5 ž 5WEM  % T G G M 825 815 830 820 815 820 830 810 835 810 815815 835 )TQWPFYCVGT/QPKVQTKPI9GNN .GCEJCVG5CORNKPI.QECVKQP .KOKVQH9CUVG .CPFHKNN4GXKGY$QWPFCT[ .CPFHKNN%QORNKCPEG$QWPFCT[ )TQWPFYCVGT5WTHCEG%QPVQWT )TQWPFYCVGT'NGXCVKQPCCPTW-1S (ž) &WMG2TQRGTV[$QWPFCT[ )GPGTCN)TQWPFYCVGT(NQY&KTGEVKQP $CUG/CR2TQXKFGFD[&WMG'PGTI[%CTQNKPCU &CVGF/C[ 0QVG  )TQWPFYCVGT%QPVQWTUFTCYPHQTUJCNNQY YGNNUQPN[  )TQWPFYCVGT'NGXCVKQPU/GCUWTGFQP 1EVQDGT 200 400 5%#.' (''6 0 200 GENERALIZED GROUNDWATER ROGERS ENERGY COMPLEX PERMIT NO. 8106 FEBRUARY 2017 3 HDR Engineering Inc. 440 S. Church St. Suite 1000 Charlotte, NC 28202-2075 704.338.6700 of the Carolinas DATE FIGURECCP LANDFILL PHASES I AND II TABLES Ta b l e 1 - W e l l C o n s t r u c t i o n I n f o r m a t i o n Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x CC P L a n d f i l l , P h a s e s I a n d I I - P e r m i t N o . 8 1 0 6 La t i t u d e L o n g i t u d e CC P M W - 1 S 2 / 2 3 / 2 0 1 0 3 5 . 2 0 6 7 0 2 1 8 1 . 7 7 4 3 0 4 9 8 7 5 . 5 8 8 7 3 . 2 4 2 . 3 4 8 3 7 . 8 1 3 7 . 7 7 4 2 . 2 4 3 2 . 2 4 3 2 . 2 4 - 4 2 . 2 4 P W R 2 P V C CC P M W - 1 D 2 / 2 4 / 2 0 1 0 3 5 . 2 0 6 7 1 3 4 8 1 . 7 7 4 2 9 9 7 8 7 5 . 8 9 8 7 3 . 3 3 2 . 5 6 8 3 7 . 3 8 3 8 . 5 1 5 6 . 7 0 5 1 . 7 0 5 1 . 7 0 - 5 6 . 7 0 B e d r o c k 2 P V C CC P M W - 2 S 2 / 2 4 / 2 0 1 0 3 5 . 2 0 3 5 5 0 9 8 1 . 7 7 2 7 3 5 0 8 4 2 . 2 4 8 4 0 . 2 6 1 . 9 8 8 0 2 . 9 0 3 9 . 3 4 4 4 . 0 7 3 4 . 0 7 3 4 . 0 7 - 4 4 . 0 7 S a p r o l i t e / P W R 2 P V C CC P M W - 2 D 2 / 2 4 / 2 0 1 0 3 5 . 2 0 3 5 5 2 4 8 1 . 7 7 2 7 2 1 9 8 4 2 . 3 8 8 4 0 . 1 7 2 . 2 1 8 0 1 . 4 4 4 0 . 9 4 7 2 . 4 7 6 7 . 4 7 6 7 . 4 7 - 7 2 . 4 7 B e d r o c k 2 P V C CC P M W - 3 S 6 / 2 7 / 2 0 0 7 3 5 . 2 0 3 4 0 9 3 8 1 . 7 7 1 0 1 9 1 8 1 1 . 5 6 8 1 0 . 5 6 1 . 0 0 S E E N O T E 9 S E E N O T E 9 1 5 . 0 2 1 0 . 0 2 1 0 . 0 2 - 1 5 . 0 2 S a p r o l i t e / P W R 2 P V C CC P M W - 3 D 7 / 1 6 / 2 0 0 7 3 5 . 2 0 3 4 0 8 7 8 1 . 7 7 1 0 0 0 5 8 1 1 . 7 4 8 1 0 . 4 7 1 . 2 7 7 9 5 . 0 9 1 6 . 6 5 3 5 . 1 9 3 0 . 1 9 3 0 . 1 9 - 3 5 . 1 9 B e d r o c k 2 P V C CC P M W - 4 1 0 / 2 1 / 2 0 1 5 3 5 . 2 0 8 9 2 9 9 - 8 1 . 7 7 4 8 1 5 1 8 4 5 . 9 5 8 4 3 . 2 9 2 . 6 6 8 1 6 . 3 4 2 9 . 6 1 6 8 . 3 3 5 3 . 3 3 5 3 . 3 3 - 6 8 . 3 3 B e d r o c k 2 P V C CC P M W - 5 1 0 / 2 3 / 2 0 1 5 3 5 . 2 0 9 9 2 6 1 - 8 1 . 7 7 2 8 5 1 9 8 5 8 . 6 3 8 5 5 . 8 7 2 . 7 6 8 1 4 . 6 2 4 4 . 0 1 7 5 . 4 0 6 5 . 4 0 6 5 . 4 0 - 7 5 . 4 0 B e d r o c k 2 P V C CC P M W - 6 S 1 0 / 2 1 / 2 0 1 5 3 5 . 2 0 8 6 6 5 6 - 8 1 . 7 7 1 1 1 7 4 8 5 4 . 3 8 8 5 1 . 4 8 2 . 9 8 1 6 . 0 9 3 8 . 2 9 4 6 . 7 3 3 6 . 7 3 3 6 . 7 3 - 4 6 . 7 3 S a p r o l i t e / P W R 2 P V C CC P M W - 6 D 1 0 / 2 6 / 2 0 1 5 3 5 . 2 0 8 6 5 3 9 - 8 1 . 7 7 1 1 0 2 7 8 5 4 . 3 5 8 5 1 . 4 5 2 . 9 8 1 6 . 0 9 3 8 . 2 6 6 3 . 0 8 5 3 . 0 8 5 3 . 0 8 - 6 3 . 0 8 B e d r o c k 2 P V C CC P T W - 1 S 2 / 2 5 / 2 0 1 0 3 5 . 2 0 5 1 5 5 7 8 1 . 7 7 0 8 7 2 2 8 3 8 . 9 2 8 3 6 . 8 1 2 . 1 1 8 0 8 . 3 4 3 0 . 5 8 3 6 . 7 8 2 6 . 7 8 2 6 . 7 8 - 3 6 . 7 8 S a p r o l i t e / P W R 2 P V C CC P T W - 1 D 7 / 1 8 / 2 0 0 7 3 5 . 2 0 5 1 4 1 8 8 1 . 7 7 0 8 7 6 2 8 3 8 . 5 3 8 3 6 . 4 1 2 . 1 2 8 0 7 . 3 2 3 1 . 2 1 6 8 . 2 3 6 3 . 2 3 6 3 . 2 3 - 6 8 . 2 3 B e d r o c k 2 P V C CC P T W - 2 2 / 2 5 / 2 0 1 0 3 5 . 2 0 3 8 6 2 8 8 1 . 7 7 0 4 2 9 8 8 4 2 . 1 8 8 3 9 . 6 2 2 . 5 6 7 9 8 . 9 0 4 3 . 2 8 4 7 . 6 3 3 7 . 6 3 3 7 . 6 3 - 4 7 . 6 3 S a p r o l i t e / P W R 2 P V C No t e s : 1 . T O C i n d i c a t e s t o p o f c a s i n g . 2 . f t . i n d i c a t e s f e e t . 3 . i n . i n d i c a t e s i n c h e s n o m i n a l d i a m e t e r . 4 . P V C i n d i c a t e s p o l y v i n y l c h l o r i d e . 5 . P W R i n d i c a t e s p a r t i a l l y w e a t h e r e d r o c k . 6 . H o r i z o n t a l d a t u m a s s u m e d t o b e N A D 8 3 . 7 . E l e v a t i o n s b a s e d o n N A V D 8 8 v e r t i c a l d a t u m . 8 . D e p t h t o w a t e r g a u g e d o n O c t o b e r 1 2 , 2 0 1 6 . 9 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . M o n i t o r i n g w e l l C C P M W - 3 S w a s d r y a t t h e t i m e o f s a m p l i n g . 10 . I n f o r m a t i o n p r o v i d e d b y D u k e E n e r g y C a r o l i n a s , L L C . O n N o v e m b e r 8 , 2 0 1 6 . We l l I D We l l I n s t a l l a t i o n Da t e Co o r d i n a t e s TO C Ele v a t i o n ( f t . ) Gr o u n d S u r f a c e Ele v a t i o n (f t . ) Gr o u n d w a t e r Ele v a t i o n (f t . ) De p t h t o W a t e r be l o w T O C (ft . ) To t a l W e l l De p t h b e l o w TO C (f t . ) De p t h t o T o p o f Sc r e e n f r o m T O C (f t . ) Sc r e e n e d I n t e r v a l be l o w T O C (f t . ) Geology of Screened IntervalWell Diameter (in.)Casing Type We l l S t i c k - u p He i g h t A b o v e Gr o u n d S u r f a c e (f t . ) Page  1  of  1 Ta b l e 2 - G r o u n d w a t e r F l o w V e l o c i t i e s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x CC P L a n d f i l l , P h a s e s I a n d I I - P e r m i t N o . 8 1 0 6 CC P M W - 1 S 8 3 7 . 8 1 83 5 87 0 . 0 3 2 0 . 4 1 1 0 . 2 5 9 0. 0 5 CC P M W - 2 S 8 0 5 80 0 24 8 0 . 0 2 0 0 . 4 1 1 0 . 2 5 9 0. 0 3 CC P M W - 3 S 8 0 0 S E E N O T E 9 S E E N O T E 9 S E E N O T E 9 0 . 4 1 1 0 . 2 5 9 S E E N O T E 9 CC P M W - 4 8 2 0 81 6 . 3 4 14 1 0 . 0 2 6 0 . 4 1 1 0 . 2 5 9 0 . 0 4 1 CC P M W - 5 8 1 5 81 4 . 6 2 96 0 . 0 0 4 0 . 4 1 1 0 . 2 5 9 0 . 0 0 6 CC P M W - 6 S 8 2 0 81 6 . 0 9 23 8 0 . 0 1 6 0 . 4 1 1 0 . 2 5 9 0 . 0 2 6 CC P T W - 1 S 8 1 0 80 5 27 1 0 . 0 1 8 0 . 4 1 1 0 . 2 5 9 0. 0 3 CC P T W - 2 8 0 0 79 8 . 9 0 13 2 0 . 0 0 8 0 . 4 1 1 0 . 2 5 9 0. 0 1 No t e s : 1 . L i n e a r d i s t a n c e m e a s u r e d t h r o u g h m o n i t o r i n g w e l l s i s g e n e r a l l y p e r p e n d i c u l a r t o g r o u n d w a t e r c o n t o u r s . 2 . A t m o n i t o r i n g w e l l l o c a t i o n s w h e r e d o w n g r a d i e n t c o n t o u r s a r e n o t p r e s e n t , t h e g r o u n d w a t e r e l e v a t i o n a t t h e m o n i t o r i n g w e l l i s u s e d a s t h e d o w n g r a d i e n t g r o u n d w a t e r e l e v a t i o n . 3 . A t m o n i t o r i n g w e l l l o c a t i o n s w h e r e u p g r a d i e n t c o n t o u r s a r e n o t p r e s e n t , t h e g r o u n d w a t e r e l e v a t i o n a t t h e m o n i t o r i n g w e l l i s u s e d a s t h e u p g r a d i e n t g r o u n d w a t e r e l e v a t i o n . 4 . M o n i t o r i n g w e l l s a r e n o t l i s t e d w h e r e i n s u f f i c i e n t g r o u n d w a t e r c o n t o u r i n f o r m a t i o n i s a v a i l a b l e t o c a l c u l a t e v e l o c i t y . 5 . H y d r a u l i c g r a d i e n t i s a p p r o x i m a t e . 6 . H y d r a u l i c c o n d u c t i v i t y p r e s e n t e d i s t h e g e o m e t r i c m e a n o f t h e c o n d u c t i v i t y d a t a f o r t h e a l l u v i u m / s o i l / s a p r o l i t e h y d r o s t r a t i g r a p h i c l a y e r i n t h e H D R C o n d u c t i v i t y D a t a b a s e ( u n p u b l i s h e d d a t a f r o m C a r o l i n a s i t e s w i t h f o l i a t e d / l a y e r e d b e d r o c k ) . 7 . E f f e c t i v e p o r o s i t y p r e s e n t e d i s t h e m e a n v a l u e o f t h e a l l u v i u m / s o i l / s a p r o l i t e h y d r o s t r a t i g r a p h i c l a y e r e s t i m a t e d f r o m s o i l t e s t i n g u s i n g F e t t e r / B e a r D i a g r a m s . 8 . H y d r a u l i c g r a d i e n t s a n d g r o u n d w a t e r v e l o c i t i e s c a l c u l a t e d u s i n g g r o u n d w a t e r d e p t h m e a s u r e d o n O c t o b e r 1 2 , 2 0 1 6 . 9 . C C P M W - 3 S c o u l d n o t b e s a m p l e d a s i t w a s d r y a t t h e t i m e o f s a m p l i n g . Ef f e c t i v e Po r o s i t y (% / 1 0 0 ) Gr o u n d w a t e r Ve l o c i t y (f t / d a y ) We l l I D U p g r a d i e n t Gr o u n d w a t e r Co n t o u r El e v a t i o n (f t ) D o w n g r a d i e n t Gr o u n d w a t e r Co n t o u r El e v a t i o n (f t ) Li n e a r Di s t a n c e Be t w e e n Co n t o u r s th r o u g h W e l l (f t ) Hy d r a u l i c Gr a d i e n t (f t / f t ) Hy d r a u l i c Co n d u c t i v i t y (f t / d a y ) Page 1 of 1 Ta b l e 3 - - F i e l d D a t a P a r a m e t e r s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 10 / 1 2 / 2 0 1 6 C C P M W - 1 S 4 2 . 2 4 3 7 . 7 7 8 3 7 . 8 1 N o r m a l N o n e E O P N / A 0.7 3 0 . 3 7 N / A 16 . 4 9 3 0 4.4 1 . 5 4 3 4 8 . 2 6 10 / 1 2 / 2 0 1 6 C C P M W - 1 D 5 6 . 7 0 3 8 . 5 1 8 3 7 . 3 8 N o r m a l N o n e C P N / A 2.9 7 1 2 . 0 0 N O 1 5 . 9 4 5 0 5.3 1 . 0 4 0 2 7 . 8 2 10 / 1 2 / 2 0 1 6 C C P M W - 2 S 4 4 . 0 7 3 9 . 3 4 8 0 2 . 9 0 N o r m a l N o n e C P N / A 0.7 7 3 . 0 0 N O 1 5 . 4 7 3 7 5.2 1 . 3 4 0 7 7 . 7 2 10 / 1 2 / 2 0 1 6 C C P M W - 2 D 7 2 . 4 7 4 0 . 9 4 8 0 1 . 4 4 N o r m a l N o n e C P N / A 5.1 4 1 4 . 2 5 N O 1 6 . 0 5 1 2 0 8.9 0 . 6 2 7 8 3 . 8 5 10 / 1 2 / 2 0 1 6 C C P M W - 3 S 1 5 . 0 2 S E E N O T E 1 0 N S NS N S N S N S N S N S N S N S NS NS N S N S N S 10 / 1 2 / 2 0 1 6 C C P M W - 3 D 3 5 . 1 9 1 6 . 6 5 7 9 5 . 0 9 N o r m a l N o n e C P N / A 3.0 2 9 . 2 5 N O 1 6 . 0 0 6 5 5.4 1 . 0 4 2 9 6 . 3 9 10 / 1 2 / 2 0 1 6 C C P M W - 4 6 8 . 3 3 2 9 . 6 1 8 1 6 . 3 4 T u r b i d N o n e C P N / A 6.3 2 7 . 7 5 Y E S 1 7 . 6 9 1 6 6 9.3 6 3 2 . 0 - 1 3 1 0 . 0 8 10 / 1 2 / 2 0 1 6 C C P M W - 5 7 5 . 4 0 4 4 . 0 1 8 1 4 . 6 2 N o r m a l N o n e C P N / A 5.1 2 6 . 2 5 Y E S 1 8 . 2 9 1 8 8 1 0 . 0 7 . 0 1 3 5 2 . 3 6 10 / 1 2 / 2 0 1 6 C C P M W - 6 S 4 6 . 7 3 3 8 . 2 9 8 1 6 . 0 9 T u r b i d N o n e L F 2 7 0 1 . 3 8 4 . 0 0 N / A 16 . 8 4 6 2 5.5 7 6 . 3 4 0 8 4 . 6 1 10 / 1 2 / 2 0 1 6 C C P M W - 6 D 6 3 . 0 8 3 8 . 2 6 8 1 6 . 0 9 N o r m a l N o n e L F 2 9 0 4 . 0 5 7 . 3 0 N / A 17 . 2 7 7 9 5.4 0 . 9 3 7 8 7 . 9 1 10 / 1 2 / 2 0 1 6 C C P T W - 1 S 3 6 . 7 8 3 0 . 5 8 8 0 8 . 3 4 N o r m a l N o n e C P N / A 1.0 1 3 . 2 5 N O 1 6 . 9 2 4 9 5.2 2 . 3 4 1 7 5 . 5 8 10 / 1 2 / 2 0 1 6 C C P T W - 1 D 6 8 . 2 3 3 1 . 2 1 8 0 7 . 3 2 N o r m a l N o n e C P N / A 6.0 4 8 . 5 0 N O 1 7 . 8 5 5 5 3 7.5 1 0 . 0 3 3 1 1 . 7 7 10 / 1 2 / 2 0 1 6 C C P T W - 2 4 7 . 6 3 4 3 . 2 8 7 9 8 . 9 0 N o r m a l N o n e C P N / A 0.7 1 2 . 2 5 N O 1 6 . 0 5 8 4 5.1 7 . 7 4 1 3 6 . 8 2 10 / 1 2 / 2 0 1 6 C C P S W - 1 N / A N/ A N/ A No r m a l N S N / A N/ A N/ A N/ A N/ A 12 . 3 1 4 3 6.6 6 . 4 3 4 0 9 . 7 2 10 / 1 2 / 2 0 1 6 C C P S W - 2 N / A N/ A N/ A No r m a l N S N / A N/ A N/ A N/ A N/ A 12 . 2 6 4 5 6.5 8 . 3 3 2 3 8 . 9 8 10 / 1 2 / 2 0 1 6 C C P S W - 3 N / A N/ A N/ A NS N S N S N S N S N S N S N S NS NS N S N S N S 10 / 1 2 / 2 0 1 6 C C P - L E A C H A T E N / A N/ A N/ A No r m a l N o n e N / A N/ A N/ A N/ A N/ A 19 . 9 8 3 5 , 4 8 7 4 . 4 4 8 . 1 4 5 3 6 . 6 1 No t e s : 1 . P u r g e M e t h o d s ; L F = L o w F l o w , C P = C o n v e n t i o n a l P u r g e ( 3 - 5 w e l l v o l u m e s ) , N P = N o P u r g e ( H y d r a S l e e v e ) , E O P = E q u i p m e n t O n l y P u r g e . A v e r a g e p u m p r a t e a p p l i c a b l e t o L F p u r g i n g o n l y . 2 . F i e l d s a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C p e r s o n n e l . 3 . E V A C i n d i c a t e s w h e t h e r t h e w a t e r l e v e l i n t h e w e l l w a s d r a w n d o w n t o t h e l e v e l o f t h e p u m p d u r i n g p u r g i n g . 4 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 5 . S U i n d i c a t e s S t a n d a r d U n i t s . 6 . N T U i n d i c a t e s N e p h e l o m e t r i c T u r b i d i t y U n i t s . 7 . m V - N H E i n d i c a t e s m i l l i v o l t s - N o r m a l H y d r o g e n E l e c t r o d e . 8 . m g / L i n d i c a t e s m i l l i g r a m s p e r l i t e r . 9 . N / A i n d i c a t e s n o t a p p l i c a b l e . 10 . M o n i t o r i n g w e l l C C P M W - 3 S a n d s u r f a c e w a t e r s a m p l i n g l o c a t i o n C C P S W - 3 w e r e d r y a t t h e t i m e o f s a m p l i n g . 11 . I n f o r m a t i o n p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n N o v e m b e r 8 , 2 0 1 6 . AP P E A R A N C E DA T E S A M P L E I D WE L L DE P T H (fe e t ) DE P T H T O WA T E R (f e e t ) WA T E R EL E V . (f e e t ) DO (mg/L) OD O R PU R G E ME T H O D AV E R A G E PU M P R A T E (m L / m i n ) WE L L VO L U M E (g a l ) EV A C VO L U M E (g a l ) EV A C (Y E S / N O ) TE M P (d e g C ) SP E C I F I C CO N D U C T A N C E (µ Լ /c m ) pH (SU)TURBIDITY (NTU)ORP (mV-NHE) Page 1 of 1 Ta b l e 4 - - G r o u n d w a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 Fi e l d p H 32 0 S U 5 1 9 3 - NE 6.5-8.5 6 . 5 - 8 . 5 * Fi e l d S p e c i f i c C o n d u c t i v i t y 32 3 µ Լ /cm 5 1 9 3 - NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 - NE N E N E To p o f C a s i n g 32 8 f e e t - - NE NE NE De p t h t o W a t e r 31 8 f e e t - - NE NE NE Wa t e r E l e v a t i o n 31 9 f e e t - - NE NE NE We l l D e p t h 41 1 f e e t - - NE NE NE Ar s e n i c 14 µ g / L 2 4 8 0. 1 2 7 J 0.0 7 8 U 0 . 0 7 8 U 0 . 8 8 7 J 0. 0 7 8 U 3 . 0 3 J ' 0. 0 7 8 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 2 4 . 3 J ' 17 J ' 22 . 4 J ' 7.4 2 J ' 27 . 3 J ' 12 9 0 . 1 1 0 0 7 0 0 2 , 0 0 0 Bo r o n 4 2 8 µ g / L 2 4 8 1 0 . 7 J 11 . 7 J 8. 8 1 J 9.2 7 J 12 . 4 J 8. 0 7 J 3.3 N E 700 NE Ca d m i u m 34 µ g / L 2 4 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0. 1 0 1 U 0 . 9 7 5 J 0. 1 0 1 1 2 5 Ch l o r i d e 45 5 µ g / L 2 4 8 3, 6 4 0 6, 3 1 0 4,5 0 0 4, 7 6 0 4, 9 7 0 1,6 7 0 2 2 N E 250,000 2 5 0 , 0 0 0 * Ch r o m i u m 51 µ g / L 2 4 8 1.0 5 J ' 0.4 4 7 J 0.6 4 7 J 0. 4 8 5 J 1.2 7 J ' 76 . 3 0. 0 6 1 1 0 1 0 1 0 0 Co p p e r 54 µ g / L 2 4 8 2.0 5 J 1.1 7 J 1 U 1 U 1 U 3 0 . 9 1 10 1,000 1 , 3 0 0 Fl u o r i d e 31 2 µ g / L 2 4 8 36 J 52 . 5 J 46 . 4 J 49 . 4 J 37 . 3 J 15 1 J ' 17 2 , 0 0 0 2 , 0 0 0 4 , 0 0 0 Ir o n 3 4 0 µ g / L 2 4 8 53 2 14 . 7 J ' 34 . 1 J ' 3.3 6 J 2.3 8 J 22 , 4 0 0 1.3 3 0 0 3 0 0 3 0 0 * Le a d 1 3 1 µ g / L 2 4 8 0 . 3 4 8 J 0.0 6 5 U 0 . 0 6 5 U 0 . 0 6 5 U 0. 0 6 5 U 8 . 0 6 J ' 0. 0 6 5 1 0 1 5 1 5 Ma n g a n e s e 3 4 2 µ g / L 2 4 8 3 1 . 3 J ' 13 . 6 J ' 9. 2 2 J ' 0. 5 3 2 J 8.5 3 J ' 27 9 0.2 5 0 5 0 5 0 * Me r c u r y 1 3 2 µ g / L 2 4 8 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 0 . 2 1 2 Nic k e l 1 5 2 µ g / L 2 4 8 0 . 6 2 8 J 1.3 7 J ' 0. 2 9 J 0. 1 9 4 U 0. 2 J 33 . 9 J ' 0. 1 9 4 5 0 1 0 0 N E Nit r a t e a s N i t r o g e n 3 0 3 µ g / L 2 4 8 1 5 . 8 J 1,1 1 0 J ' 64 7 J ' 98 1 J ' 14 0 0 J ' 5.4 U 5 . 4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 1 8 3 µ g / L 2 4 8 0 . 3 2 J 0.1 5 8 J 0.2 3 7 J 0. 3 1 2 J 0. 3 1 2 J 0.2 9 3 J 0. 0 9 2 1 0 20 50 Sil v e r 18 4 µ g / L 2 4 8 1.0 5 J 1.3 3 J 0.7 U 0. 7 U 0. 7 U 2 . 1 2 J 0.7 1 0 20 100* Su l f a t e 31 5 µ g / L 2 4 8 1, 1 5 0 J ' 1,2 3 0 J ' 40 5 J ' 4, 7 0 0 J ' 9, 1 5 0 J ' 3,0 4 0 J ' 18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l D i s s o l v e d S o l i d s 31 1 µ g / L 2 4 8 1 6 , 7 0 0 U 2 8 , 0 0 0 2 2 , 0 0 0 J 49 , 0 0 0 38 , 0 0 0 1 3 0 , 0 0 0 1 6 , 7 0 0 N E 500,000 500,000* Zi n c 21 3 µ g / L 2 4 8 44 . 3 6.9 7 J ' 2.6 U 9 6 6 . 3 7 J ' 57 . 9 2 . 6 1 0 1 , 0 0 0 5,000* No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 3 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 4 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 5 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 6 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 7 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s . 8 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . B l a n k c e l l s i n d i c a t e t h a t t h e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 9 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . M o n i t o r i n g w e l l C C P M W - 3 S w a s d r y a t t h e t i m e o f s a m p l i n g . 10 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 11 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 L S t a n d a r d . 12 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -fl a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 13 . S U i n d i c a t e s S t a n d a r d U n i t s . 14 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 15 . A c c o r d i n g t o t h e C o n s t i t u e n t L o o k - u p w e b p a g e o n t h e N C D E Q D i v i s i o n o f W a s t e M a n a g e m e n t w e b p a g e , t h e r e i s n o S W S L o r 2 L S t a n d a r d f o r c h o r i d e a s s o c i a t e d w i t h C A S n u m b e r 1 6 8 8 7 - 0 8 - 6 , w h i c h i s t h e C A S r e p o r t e d b y t h e l a b o r a t o r y f o r t h e a n a l y s e s c o m p l e t e d . T h e r e f o r e , t h e S W S L a n d 2 L S t a n d a r d l i s t e d a r e f o r t h e c h l o r i d e w i t h C A S n u m b e r S W 3 0 1 a s s p e c i f i e d o n t h e C o n s t i t u e n t L o o k - u p w e b p a g e . 16 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n N o v e m b e r 8 , 2 0 1 6 . 56 . 7 0 83 7 . 3 8 38 . 5 1 37 . 7 7 83 7 . 8 1 42 . 2 4 7 2 . 4 7 80 1 . 4 4 40 . 9 4 39 . 3 4 80 2 . 9 0 44 . 0 7 NS NS NS NS 17 . 6 9 NS 68 . 3 3 81 6 . 3 4 29 . 6 1 NS NS 15 . 0 2 NS NS NS NS NSNSNSNSNSNSNSNSNSNSNS 87 5 . 5 8 8 4 2 . 3 8 84 2 . 2 4 87 5 . 8 9 8 1 1 . 7 4 Sa m p l e D a t e : O c t o b e r 1 2 , 2 0 1 6 Fie l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C 5. 2 37 15 . 4 7 15 . 9 4 1 6 . 0 5 12 0 8.9 505.3 4.4 30 16 . 4 9 Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e SWSL 81 0 6 - C C P MW - 1 S 81 0 6 - C C P MW - 1 D 81 0 6 - C C P MW - 2 S 81 0 6 - C C P MW - 2 D 81 0 6 - C C P MW - 3 S 81 0 6 - C C P MW - 4 Mo n i t o r i n g W e l l s MD L 16 . 6 5 79 5 . 0 9 35 . 1 9 81 0 6 - C C P MW - 3 D Laboratory Certificate Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 15A NCAC 2L StandardFederal MCL 16 6 9.3 NS NS 5. 4 65 16 . 0 0 84 5 . 9 5 81 1 . 5 6 Page 1 of 2 Ta b l e 4 - - G r o u n d w a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 Fie l d p H 32 0 S U 5 1 9 3 - NE 6.5-8.5 6 . 5 - 8 . 5 * Fi e l d S p e c i f i c C o n d u c t i v i t y 32 3 µ Լ /cm 5 1 9 3 - NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 - NE N E N E To p o f C a s i n g 32 8 f e e t - - NE N E N E De p t h t o W a t e r 3 1 8 f e e t - - NE N E N E Wa t e r E l e v a t i o n 3 1 9 f e e t - - NE N E N E We l l D e p t h 4 1 1 f e e t - - NE N E N E Ar s e n i c 1 4 µ g / L 2 4 8 5 . 2 2 J' 1. 7 1 J' 0. 0 7 8 U 0 . 0 7 8 U 1 . 0 8 J' 0. 1 1 6 J 0 . 0 7 8 U 0 . 0 7 8 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 2 . 1 7 J 62 . 7 J' 77 . 2 J' 31 J' 29 . 7 J' 51 . 2 J' 0. 2 4 8 J 0.1 1 0 0 700 2 , 0 0 0 Bo r o n 42 8 µ g / L 2 4 8 3 1 . 4 J 6. 4 4 J 6.4 1 J 5.6 7 J 10 . 5 J 9. 2 3 J 3 . 8 4 J 3.3 N E 700 NE Ca d m i u m 34 µ g / L 2 4 8 0 . 1 0 1 U 0 . 1 2 7 J 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 1 2 5 Ch l o r i d e 45 5 µ g / L 2 4 8 8 , 7 5 0 5,9 0 0 6, 4 9 0 4, 6 4 0 3,4 6 0 1 2 , 7 0 0 22 U 2 2 N E 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 51 µ g / L 2 4 8 0 . 6 8 6 J 6. 3 2 J' 1.1 1 J' 0. 9 8 8 J 1.1 5 J' 1. 4 3 J' 0. 0 6 1 U 0 . 0 6 1 1 0 1 0 1 0 0 Co p p e r 5 4 µ g / L 2 4 8 1 . 5 8 J 5. 5 J 1.1 8 J 1 U 1 U 1 U 6 0 . 8 1 10 1,000 1 , 3 0 0 Flu o r i d e 31 2 µ g / L 2 4 8 3 0 7 J' 43 . 7 J 49 . 7 J 17 U 2 2 9 J' 33 . 6 J 1 7 U 1 7 2 , 0 0 0 2 , 0 0 0 4 , 0 0 0 Iro n 3 4 0 µ g / L 2 4 8 7 6 . 3 J' 4,6 5 0 4.4 3 J 49 . 4 J' 44 4 4 1 6 2.4 5 J 1.3 3 0 0 300 300* Le a d 13 1 µ g / L 2 4 8 0 . 1 0 4 J 3. 6 3 J' 0. 1 0 7 J 0. 0 6 5 U 0 . 9 5 1 J 0. 5 0 5 J 0 . 0 6 5 U 0 . 0 6 5 1 0 15 15 Ma n g a n e s e 34 2 µ g / L 2 4 8 1 . 3 5 J 87 7 10 2 4.9 1 J 33 . 7 J' 18 J' 0. 7 9 8 J 0.2 5 0 50 50* Me r c u r y 13 2 µ g / L 2 4 8 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 0 . 2 1 2 Nic k e l 15 2 µ g / L 2 4 8 0 . 6 9 6 J 10 . 8 J' 1.7 1 J' 0. 5 0 9 J 2.8 7 J' 0. 7 0 4 J 0 . 1 9 4 U 0 . 1 9 4 5 0 1 0 0 N E Nit r a t e a s N i t r o g e n 3 0 3 µ g / L 2 4 8 4 5 3 J' 38 7 J 4, 8 1 0 J' 2, 1 0 0 J' 39 9 J' 2, 1 9 0 J' 5. 4 U 5 . 4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 1 8 3 µ g / L 2 4 8 0 . 5 1 6 J 0.1 9 7 J 0. 1 3 7 J 0.0 9 4 2 J 1.4 1 J' 0. 1 6 5 J 0 . 0 9 2 U 0 . 0 9 2 1 0 2 0 5 0 Si l v e r 1 8 4 µ g / L 2 4 8 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µ g / L 2 4 8 1 4 , 7 0 0 J' 5,9 2 0 J' 1, 0 1 0 J' 60 6 J' 11 4 , 0 0 0 J' 4, 7 6 0 J' 47 . 4 J 18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l D i s s o l v e d S o l i d s 3 1 1 µ g / L 2 4 8 1 0 7 , 0 0 0 4 3 , 0 0 0 4 9 , 0 0 0 3 6 , 0 0 0 2 6 0 , 0 0 0 5 6 , 0 0 0 1 6 , 7 0 0 N E 5 0 0 , 0 0 0 500,000* Zin c 2 1 3 µ g / L 2 4 8 3 . 7 1 J 11 . 1 19 3 21 . 2 16 2 2.6 U 2 2 0 2 . 6 1 0 1,000 5,000* No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 3 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 4 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 5 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 6 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 7 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s . 8 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . B l a n k c e l l s i n d i c a t e t h a t t h e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 9 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . M o n i t o r i n g w e l l C C P M W - 3 S w a s d r y a t t h e t i m e o f s a m p l i n g . 10 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 11 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 L S t a n d a r d . 12 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -f l a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 13 . S U i n d i c a t e s S t a n d a r d U n i t s . 14 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 15 . A c c o r d i n g t o t h e C o n s t i t u e n t L o o k - u p w e b p a g e o n t h e N C D E Q D i v i s i o n o f W a s t e M a n a g e m e n t w e b p a g e , t h e r e i s n o S W S L o r 2 L S t a n d a r d f o r c h o r i d e a s s o c i a t e d w i t h C A S n u m b e r 1 6 8 8 7 - 0 8 - 6 , w h i c h i s t h e C A S r e p o r t e d b y t h e l a b o r a t o r y f o r t h e a n a l y s e s c o m p l e t e d . T h e r e f o r e , t h e S W S L a n d 2 L S t a n d a r d l i s t e d a r e f o r t h e c h l o r i d e w i t h C A S n u m b e r S W 3 0 1 a s s p e c i f i e d o n t h e C o n s t i t u e n t L o o k - u p w e b p a g e . 80 8 . 3 4 36 . 7 8 55 3 7. 5 5.2 49 16 . 9 2 30 . 5 8 84 2 . 1 8 83 8 . 5 3 83 8 . 9 2 5. 1 84 16 . 0 5 17 . 8 5 79 8 . 9 0 47 . 6 3 68 . 2 3 80 7 . 3 2 31 . 2 1 NA Sa m p l e D a t e : O c t o b e r 1 2 , 2 0 1 6 Fie l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Laboratory Certificate Codes:Duke Energy Carolinas Field #5193 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e SW S L Federal MCL 81 0 6 - C C P TW - 1 S 81 0 6 - C C P TW - 1 D 81 0 6 - C C P TW - 2 M D L 15A NCAC 2L Standard 81 0 6 - C C P Fi e l d B l a n k 43 . 2 8 ------- 81 0 6 - C C P MW - 6 D 81 0 6 - C C P MW - 5 81 0 6 - C C P MW - 6 S 18 8 6 2 7 9 10 . 0 5 . 5 5 . 4 75 . 4 0 4 6 . 7 3 6 3 . 0 8 Mo n i t o r i n g W e l l s 44 . 0 1 3 8 . 2 9 3 8 . 2 6 81 4 . 6 2 8 1 6 . 0 9 8 1 6 . 0 9 18 . 2 9 1 6 . 8 4 1 7 . 2 7 85 8 . 6 3 8 5 4 . 3 8 8 5 4 . 3 5 Page 2 of 2 Ta b l e 5 - - F i e l d a n d A n a l y t i c a l R e s u l t s t h a t E q u a l o r E x c e e d 15 A N C A C 2 L G r o u n d w a t e r Q u a l i t y S t a n d a r d s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 Pa r a m e t e r S a m p l e I D R e s u l t U n i t s 15 A N C A C 2L S t a n d a r d His t o r i c a l C o n c e n t r a t i o n s C a u s e a n d S i g n i f i c a n c e CC P M W - 1 S 4 . 4 4 . 5 - 5 . 6 pH i n C C P M W - 1 S i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 1 D 5 . 3 5 . 2 - 9 . 7 p H i n C C P M W - 1 D i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 2 S 5 . 2 5 . 0 - 6 . 4 p H i n C C P M W - 2 S i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 2 D 8 . 9 7 . 0 - 1 0 . 3 p H i n C C P M W - 2 D i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 3 D 5 . 4 4 . 7 - 5 . 4 p H i n C C P M W - 3 D i s c o n s i s t e n t w i t h t h e h i g h e s t h i s t o r i c a l r e a d i n g a t w e l l . CC P M W - 4 9 . 3 1 0 . 1 * p H i n C C P M W - 4 i s l o w e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . CC P M W - 5 1 0 . 0 9 . 9 * p H i n C C P M W - 5 i s h i g h e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . CC P M W - 6 S 5 . 5 5 . 2 * p H i n C C P M W - 6 S i s h i g h e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . CC P M W - 6 D 5 . 4 5 . 5 * p H i n C C P M W - 6 D i s l o w e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . CC P T W - 1 S 5 . 2 5 . 0 - 5 . 4 p H i n C C P T W - 1 S i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P T W - 2 5 . 1 5 . 0 - 5 . 6 p H i n C C P T W - 2 i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . Ch r o m i u m C C P M W - 4 7 6 . 3 µ g / L 1 0 1 2 1 * C h r o m i u m i n C C P M W - 4 i s l o w e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . T u r b i d i t y i s m e a s u r e d a t 6 3 2 N T U . CC P M W - 1 S 5 3 2 26 1 - 2 , 2 2 0 I r o n i n C C P M W - 1 S i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 4 2 2 , 4 0 0 38 , 1 0 0 * Ir o n i n C C P M W - 4 i s l o w e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . T u r b i d i t y i s m e a s u r e d a t 6 3 2 N T U . CC P M W - 6 S 4 , 6 5 0 38 1 * Ir o n i n C C P M W - 6 S i s h i g h e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . T u r b i d i t y i s m e a s u r e d a t 7 6 . 3 N T U . CC P T W - 1 D 4 4 4 40 . 2 - 9 6 9 Ir o n i n C C P T W - 1 D i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . T u r b i d i t y i s m e a s u r e d a t 1 0 N T U . CC P T W - 2 4 1 6 36 . 1 - 3 5 3 Ir o n i n C C P T W - 2 i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t w e l l . CC P M W - 4 2 7 9 49 2 * Ma n g a n e s e i n C C P M W - 5 i s l o w e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . CC P M W - 6 S 8 7 7 79 5 * Ma n g a n e s e i n C C P M W - 6 S i s h i g h e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . T u r b i d i t y i s m e a s u r e d a t 7 6 . 3 N T U . CC P M W - 6 D 1 0 2 62 . 7 * Ma n g a n e s e i n C C P M W - 6 D i s h i g h e r t h a n t h e h i s t o r i c a l r e a d i n g a t w e l l . No t e s : 1 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 2 . µ g / L i n d i c a t e s m i c r o g r a m s p e r l i t e r . 3 . S U i n d i c a t e s S t a n d a r d U n i t s . 4 . * C C P L a n d f i l l P h a s e I I w e l l s h a v e o n l y b e e n s a m p l e d t w i c e . T h e r e s u l t s f r o m t h e f i r s t s a m p l i n g e v e n t a r e r e p o r t e d a s t h e h i s t o r i c a l r a n g e . 5 . N T U i n d i c a t e s N e p h e l o m e t r i c T u r b i d i t y U n i t s . 6 . H i s t o r i c a l c o n c e n t r a t i o n s b a s e d o n d a t a i n D u k e E n e r g y C a r o l i n a s , L L C ( D u k e E n e r g y ) a n a l y t i c a l r e s u l t s d a t a b a s e . 7 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n N o v e m b e r 8 , 2 0 1 6 . 50 µg / L Ma n g a n e s e Sa m p l e D a t e : O c t o b e r 1 2 , 2 0 1 6 6. 5 - 8 . 5 pH S U Ir o n µ g / L 3 0 0 Page 1 of 1 Ta b l e 6 - - S u r f a c e W a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 Fie l d p H 32 0 S U 5 1 9 3 - NE 6.0 - 9 . 0 6 . 5 - 8 . 5 * Fie l d S p e c i f i c C o n d u c t i v i t y 3 2 3 µ Լ /cm 5 1 9 3 - NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 - NE N E N E Ar s e n i c 1 4 µg / L 2 4 8 0 . 3 2 J 0. 3 1 6 J 0. 0 7 8 10 1 0 1 0 Ar s e n i c , d i s s o l v e d 1 4 µg / L 2 4 8 N A N A - 10 1 5 0 N E Ba r i u m 1 5 µg / L 2 4 8 1 9 . 6 J' 20 . 3 J' 0. 1 10 0 NE 2,0 0 0 Ba r i u m , d i s s o l v e d 1 5 µg / L 2 4 8 NA NA - 10 0 NE NE Bo r o n 42 8 µg / L 2 4 8 9.4 5 J 8.9 3 J 3. 3 NE N E N E Bo r o n , d i s s o l v e d 4 2 8 µg / L 2 4 8 N A N A - NE N E N E Ca d m i u m 3 4 µg / L 2 4 8 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 1N E 5 Ca d m i u m , d i s s o l v e d ( h ) 3 4 µg / L 2 4 8 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 1 0 . 1 5 N E Ch l o r i d e 4 5 5 µg / L 2 4 8 4,0 9 0 4 , 1 3 0 22 NE 2 3 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 51 µg / L 2 4 8 0.3 7 5 J 0. 3 1 6 J 0. 0 6 1 10 N E 1 0 0 Ch r o m i u m , d i s s o l v e d † 5 1 µg / L 2 4 8 0 . 0 6 1 U 0 . 0 6 1 U 0 . 0 6 1 10 1 1 N E Co p p e r 5 4 µg / L 2 4 8 1 . 1 4 J 1U 1 10 NE 1, 0 0 0 * Co p p e r , d i s s o l v e d ( h ) 5 4 µg / L 2 4 8 0.1 9 5 J 0.1 1 U 0.1 1 10 2.7 NE Flu o r i d e 31 2 µg / L 2 4 8 46 J 48 . 4 J 17 2,0 0 0 1 , 8 0 0 2 , 0 0 0 * Ir o n 3 4 0 µg / L 2 4 8 1 , 5 2 0 1 , 6 8 0 1 . 3 30 0 N E 3 0 0 * Ir o n , d i s s o l v e d 3 4 0 µg / L 2 4 8 N A N A - 30 0 N E N E Le a d 1 3 1 µg / L 2 4 8 0 . 2 5 7 J 0. 1 6 5 J 0. 0 6 5 10 N E 1 5 Le a d , d i s s o l v e d ( h ) 1 3 1 µg / L 2 4 8 0 . 0 7 1 4 J 0. 0 6 5 U 0. 0 6 5 10 0. 5 4 NE Ma n g a n e s e 34 2 µg / L 2 4 8 45 J' 64 . 2 0. 2 50 NE 50 * Ma n g a n e s e , d i s s o l v e d 3 4 2 µg / L 2 4 8 NA NA - 50 NE NE Me r c u r y 13 2 µg / L 2 4 8 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0 3 3 4 0.2 0.0 1 2 2 Nic k e l 15 2 µg / L 2 4 8 0.3 3 2 J 0. 2 6 8 J 0. 1 9 4 50 N E N E Ni c k e l , d i s s o l v e d ( h ) 1 5 2 µg / L 2 4 8 0 . 2 5 8 J 0. 2 3 2 J 0. 1 9 4 50 1 6 N E Nit r a t e ( a s N i t r o g e n ) 3 0 3 µg / L 2 4 8 4 0 5 J' 35 0 J' 5. 4 10 , 0 0 0 NE 10 , 0 0 0 Se l e n i u m 1 8 3 µg / L 2 4 8 0.3 4 1 J 0. 0 9 2 U 0. 0 9 2 10 5 50 Se l e n i u m , d i s s o l v e d 1 8 3 µg / L 2 4 8 NA NA - 10 NE NE Sil v e r 18 4 µg / L 2 4 8 0.7 U 0 . 7 U 0. 7 10 NE 10 0 * Sil v e r , d i s s o l v e d 1 8 4 µg / L 2 4 8 0.0 5 1 U 0 . 0 5 1 U 0. 0 5 1 10 0. 0 6 NE Su l f a t e 31 5 µg / L 2 4 8 1,0 9 0 J' 1, 2 7 0 J' 18 25 0 , 0 0 0 N E 2 5 0 , 0 0 0 * To t a l D i s s o l v e d S o l i d s 3 1 1 µg / L 2 4 8 4 0 , 0 0 0 4 2 , 0 0 0 16 , 7 0 0 NE NE 5 0 0 , 0 0 0 * Zi n c 21 3 µg / L 2 4 8 3.1 7 J 2.6 U 2. 6 10 NE 5, 0 0 0 * Zin c , d i s s o l v e d ( h ) 2 1 3 µg / L 2 4 8 2.6 U 2 . 6 U 2. 6 10 36 NE No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S U i n d i c a t e s S t a n d a r d U n i t s . 3 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 3 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 4 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 5 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 6 . 1 5 A N C A C 2 B S t a n d a r d i s f r o m " N o r t h C a r o l i n a A d m i n i s t r a t i v e C o d e , T i t l e 1 5 A : D e p a r m e n t o f E n v i r o n m e n t a n d N a t u r a l R e s o u r c e s , S u b c h a p t e r 2 B - S u r f a c e W a t e r a n d W e t l a n d S t a n d a r d s , " ( i n c l u d i n g ' 0 7 - ' 1 4 T r i e n n i a l R e v i e w s t a n d a r d s p e n d i n g E P A r e v i e w ) f o r C l a s s W S - I V w a t e r . 7 . S t a n d a r d s f o r C l a s s C w a t e r s a s s u m e t h e m o s t s t r i n g e n t o f F r e s h w a t e r a n d H u m a n H e a l t h s t a n d a r d s . 8 . S u c k C r e e k a n d t h e d r a i n a g e s w a l e a r e c l a s s i f i e d a s W S - I V w a t e r s . R e g u l a t i o n 1 5 A N C A C 0 2 B . 0 2 1 6 p r o v i d e s w a t e r q u a l i t y s t a n d a r d s f o r W S - I V w a t e r s . C l a s s C w a t e r q u a l i t y s t a n d a r d s a l s o a p p l y t o W S - I V w a t e r s . C l a s s C w a t e r q u a l i t y s t a n d a r d s a r e p r o v i d e d i n r e g u l a t i o n 1 5 A N C A C 0 2 B . 0 2 1 1 . F o r p a r a m e t e r s a n d c o n s i t u e n t s w h e r e s t a n d a r d s e x i s t , t h e m o r e s t r i n g e n t i s l i s t e d a s t h e 2 B S t a n d a r d . R e f e r e n c e 1 5 A N C A C 2 B . 0 2 0 0 C l a s s i f i c a t i o n s a n d W a t e r Q u a l i t y S t a n d a r d s A p p l i c a b l e t o S u r f a c e W a t e r s a n d W e t l a n d s o f N . C . A m e n d e d E f f e c t i v e : M a y 1 , 2 0 0 7 ( i n c l u d i n g ' 0 7 - ' 1 4 T r i e n n i a l R e v i e w s t a n d a r d s p e n d i n g E P A r e v i e w ) . 9 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 10 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s . 11 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . B l a n k c e l l s i n d i c a t e t h a t t h e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 12 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . S u r f a c e w a t e r s a m p l e l o c a t i o n C C P S W - 3 w a s d r y a t t h e t i m e o f s a m p l i n g . 13 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 14 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 B S t a n d a r d . 15 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J'-fl a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 16 . † S t a n d a r d l i s t e d i s m o s t s t r i n g e n t o f C r ( I I I ) a n d C r ( V I ) . 17 . ( h ) S t a n d a r d i s h a r d n e s s d e p e n d e n t ; s t a n d a r d i s d i s p l a y e d a s s u m i n g a h a r d n e s s o f ≤ 2 5 m g / L . 18 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n N o v e m b e r 8 , 2 0 1 6 . NS NSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNSNS Fe d e r a l MC L 81 0 6 - C C P SW - 1 81 0 6 - C C P SW - 2 Sa m p l e D a t e : O c t o b e r 1 2 , 2 0 1 6 Fie l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e Su r f a c e W a t e r L o c a t i o n s La b o r a t o r y C e r t i f i c a t e C o d e s : Du k e E n e r g y C a r o l i n a s F i e l d # 5 1 9 3 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 SW S L MD L 15 A N C A C 2 B S t a n d a r d 81 0 6 - C C P SW - 3 NS NS NS 12 . 3 1 436. 6 6 . 5 45 12 . 2 6 Page 1 of 1 Ta b l e 7 - - L e a c h a t e F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / R o g e r s E n e r g y C o m p l e x C C P L a n d f i l l , P h a s e s I a n d I I - - P e r m i t N o . 8 1 0 6 Fi e l d p H 32 0 SU 51 9 3 - NE Fi e l d S p e c i f i c C o n d u c t i v i t y 32 3 µ Լ /c m 5 1 9 3 - NE Te m p e r a t u r e 32 5 °C 51 9 3 - NE Ar s e n i c 14 µg / L 24 8 29 . 4 0.3 9 10 Ba r i u m 15 µg / L 24 8 74 4 0.1 10 0 Bo r o n 42 8 µg / L 24 8 8, 8 5 0 3.3 NE Ca d m i u m 34 µg / L 24 8 3. 8 1 J 0.5 0 5 1 Ch l o r i d e 45 5 µg / L 24 8 1 7 , 1 0 0 , 0 0 0 44 , 0 0 0 NE Ch r o m i u m 51 µg / L 24 8 5. 2 1 J ' 0. 3 0 5 10 Co p p e r 54 µg / L 24 8 1 U 1 10 Fl u o r i d e 31 2 µg / L 24 8 3, 4 0 0 U 3,4 0 0 2,0 0 0 Ir o n 34 0 µg / L 24 8 9, 0 0 0 1.3 30 0 Le a d 13 1 µg / L 24 8 23 7 0.3 2 5 10 Ma n g a n e s e 34 2 µg / L 24 8 54 , 0 0 0 2 50 Me r c u r y 13 2 µg / L 24 8 0. 0 3 3 4 U 0 . 0 3 3 4 0 . 2 Ni c k e l 15 2 µg / L 24 8 26 9 0.9 7 50 Ni t r a t e a s N i t r o g e n 3 0 3 µg / L 24 8 2, 7 0 0 J ' 5.4 10 , 0 0 0 Se l e n i u m 18 3 µg / L 24 8 10 2 0.4 6 10 Sil v e r 18 4 µg / L 24 8 0. 7 U 0.7 10 Su l f a t e 31 5 µg / L 24 8 1 , 1 5 0 , 0 0 0 3,6 0 0 25 0 , 0 0 0 To t a l D i s s o l v e d S o l i d s 3 1 1 µg / L 24 8 3 4 , 8 0 0 , 0 0 0 33 4 , 0 0 0 NE Zi n c 21 3 µg / L 24 8 39 0 2.6 10 No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 3 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . 4 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o 5 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 6 . N E i n d i c a t e s n o t e s t a b l i s h e d . 7 . S U i n d i c a t e s S t a n d a r d U n i t s . 8 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 9 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s m e t h o d d e " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -f l a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 10 . A c c o r d i n g t o t h e C o n s t i t u e n t L o o k - u p w e b p a g e o n t h e N C D E Q D i v i s i o n o f W a s t e M a n a g e m e n t w e b p a g e , t h e r e i s n o S W S L f o r c h o r i d e a s s o c i a t e d w i t h C A S n u m b e r 1 6 8 8 7 w h i c h i s t h e C A S r e p o r t e d b y t h e l a b o r a t o r y f o r t h e a n a l y s e s c o m p l e t e d . T h e r e f o r e , t h e S W S L l i s t e d i s f o r t h e c h l o r i d e w i t h C A S n u m b e r S W 3 0 1 a s s p e c i f i e d o n t h e C o n s t 11 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n N o v e m b e r 8 , 2 0 1 6 . 4. 4 35 , 4 8 7 19 . 9 8 La b o r a t o r y C e r t i f i c a t e C o d e s : Du k e E n e r g y C a r o l i n a s F i e l d # 5 1 9 3 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 Sa m p l e D a t e : O c t o b e r 1 2 , 2 0 1 6 Fi e l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Pa r a m e t e r SW S I D U n i t s Ce r t i f i c a t e Co d e 81 0 6 - C C P Le a c h a t e SW S L MD L Page 1 of 1 A Appendix A Field Sampling Forms ANALYZER SERIAL #: WEATHER CONDITIONS: DATE:TIME:DATE:TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 349.5 ŷŷŹ 350 349.8 ŷŷŹ 350 SS 74.8 ŷŷŹ 75 75.7 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 B (7.00)7.04 ŷŷŹ 7.02 7.06 ŷŷŹ 7.02 B (4.00)4.02 ŷŷŹ 4.00 4.04 ŷŷŹ 4.00 B (10.00)10.09 ŷŷŹ 10.06 10.13 ŷŷŹ 10.06 19.97 19.97 pH Check B (7.00)ŷŷŹ 0.00 Time:0.00 441 ŷŷŹ 441 439 ŷŷŹ 441 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 19.86 19.89 TEMP(CO) BP (mmHg) COND 100 % mg/L 9.14 ŷŷŹ 9.10 9.00 ŷŷŹ 9.03 After Cal 9.08 99.74 9.00 99.62 LCS 9.05 99.41 8.99 99.51 LCSD 9.05 0.00 9.01 0.22 SS 54.0 ŷŷŹ 53.6 54.5 ŷŷŹ 53.6 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: NOTES: FIELD SAMPLING CALIBRATION FORM STUDY:ROGERS COMPLEX - CCP LANDFILL GROUNDWATER MONITORING DATE (s):October 12, 2016 SURFACE UNIT READER: LDC OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, calm, 40 to 70 deg F COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: S0205 ANALYZER MODEL#: MS5 66120 Calibration Date / Time 12-Oct-16 405 13-Oct-16 745 PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY: Parameter Calibration Results Calibration Results CALIBRATION BP (mmHg)750.08 CALIBRATION BP (mmHg)746.37 CALIBRATION ACCEPTED CALIBRATION ACCEPTED INSTRUMENT ZEROED INSTRUMENT ZEROED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp.Buffer Temp. ORP Temp.ORP Temp. ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. 93.8 CALIBRATION PASS CALIBRATION PASS CALIBRATION ACCEPTED CALIBRATION ACCEPTED After Cal % SAT After Cal % SAT TURB (ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION PASS CALIBRATION PASS DO (mg/L) 19.25 19.38 750.08 746.37 92.9 Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 751.0 (mmHg) Ending BP 750.7 SS = Standard solution AW = Average Winkler ŷŷŹ 1RW$GMXVWHG7R (mmHg) B = Buffer W = Winkler ŷŷŹ $GMXVWHG7R N/A = Not Applicable de ORP TUR (ntu A-1 ANALYZER SERIAL #: WEATHER CONDITIONS: DATE:TIME:DATE:TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 357.6 ŷŷŹ 350 346.5 ŷŷŹ 350 SS 74.2 ŷŷŹ 75 74.2 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 B (7.00)6.96 ŷŷŹ 7.02 7.05 ŷŷŹ 7.02 B (4.00)3.99 ŷŷŹ 4.00 4.05 ŷŷŹ 4.00 B (10.00)10.03 ŷŷŹ 10.06 10.04 ŷŷŹ 10.06 19.94 19.98 pH Check B (7.00)ŷŷŹ 0.00 Time:0.00 441 ŷŷŹ 441 441 ŷŷŹ 441 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 19.86 19.83 TEMP(CO) BP (mmHg) COND 100 % mg/L 9.09 ŷŷŹ 9.11 9.03 ŷŷŹ 9.04 After Cal 9.12 100.15 9.02 99.80 LCS 9.14 100.37 9.06 100.25 LCSD 9.06 -0.88 9.02 -0.44 SS 53.2 ŷŷŹ 53.2 52.6 ŷŷŹ 53.2 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: NOTES: SS = Standard solution AW = Average Winkler ŷŷŹ 1RW$GMXVWHG7R (mmHg) B = Buffer W = Winkler ŷŷŹ $GMXVWHG7R N/A = Not Applicable Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 751.0 (mmHg) Ending BP 750.7 Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available TURB (ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION PASS CALIBRATION PASS DO (mg/L) 19.24 19.36 750.08 746.37 84.6 CALIBRATION PASS CALIBRATION PASS CALIBRATION ACCEPTED CALIBRATION ACCEPTED After Cal % SAT After Cal % SAT 90.5 ORP Temp.ORP Temp. ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp.Buffer Temp. pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED INSTRUMENT ZEROED INSTRUMENT ZEROED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Parameter Calibration Results Calibration Results CALIBRATION BP (mmHg)750.08 CALIBRATION BP (mmHg)746.37 Calibration Date / Time 12-Oct-16 350 13-Oct-16 730 PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY: FIELD SAMPLING CALIBRATION FORM STUDY:ROGERS COMPLEX - CCP LANDFILL GROUNDWATER MONITORING DATE (s):October 12, 2016 SURFACE UNIT READER: PSP OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, calm, 40 to 70 deg F COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0730 ANALYZER MODEL#: HL4 400440 de ORP TUR (ntu A-2 32.24 42.24 18 (psi)10 (sec)(sec) (gal) 896 (ml) 495 (ml) 1391 (ml)=0.37 (gal)@ QC By:Sample preservation verified to pH (units)< 2.0 SAMPLING NOTES ADDITIONAL WELL CONDITION NOTES NA Pump (Bladder) Volume Tubing Volume Total Purge Volume 434 8.26 N/A EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BYRemoved 0.5 gal 37.77 270 WATER LEVEL RATE WATER LEVEL COND. LDC WELL CONDITION PROTECTIVE CASING WELL PAD WELL TAG Good Condition Minor Cracks 4.39 1.5 Good Condition Good Tag WELL CASING 38.38 16.49 30 (ft)(ml/min)(ft)(deg C) (umho/cm) (SU) OXYGEN INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED SAMPLING EQUIPMENT TUBING DIAMETER (in)1/2 OD QED T1200 WATER ELEVATION (ft msl) 837.81 APPEARANCE DETECTED ODOR None Normal SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 WELL DEPTH (ft TOC) WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc) SCREEN INTERVAL (ft TOC)TO SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 37.77 WATER COLUMN (ft) 4.47 EQUIPMENT INFORMATION LEVEL METER SERIAL#28652 41.24PUMP INTAKE DEPTH (ft TOC)42.24 TOC ELEV (ft msl) GS ELEV (ft msl) 875.58 873.24 WELL/LOCATION NAME CCPMW-1S FIELD CREW LDC, PSP MONITORING WELL INFORMATION 2 N/A PROCEDURE NO 3175.4DUKE ENERGY GROUNDWATER MONITORING DATA SHEET FOR EQUIPMENT PURGE ONLY SAMPLING SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID PROJECT NAME ROGERS CCP LANDFILL SAMPLING DATE(s)12-Oct-2016 40.01 PURGE METHOD Equip. Only Purge DISCHARGERECHARGEPRESSURE 10 PUMP CONTROLLER SETTINGS 0.1631CONVERSION FACTOR Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) 0.73WELL VOLUME 10/12/2016 1125 DATE TIME (mg/L)(NTU)(mV -NEH) 12 T SP TU DISS A-3 51.70 56.70 38 (psi)9 (sec)(sec) (gal) 2.97 (gal) @ QC By: SITE NAME ROGERS COMPLEX PERMIT # 81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-1D MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 875.89 MIDDLE OF WETTED SCREEN (ft toc)54.20 SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 56.70 GS ELEV (ft msl) 873.33 PUMP INTAKE DEPTH (ft TOC)55.70 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 38.51 WATER COLUMN (ft) 18.19 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)837.38 WELL VOLUME 2.97 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 3.00 NO 16.01 52 5.22 1.6 392 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 7.47 3.00 NO 16.06 49 5.20 0.9 405 7.80 3.00 NO 16.02 47 5.25 1.3 395 7.75 3.00 NO 15.94 50 5.30 1.0 402 7.82 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 12.00 LDC 10/12/2016 1225 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 12 T SP TU DISS ( A-4 34.07 44.07 20 (psi)14 (sec)(sec) (gal) 0.77 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 3.00 LDC 10/12/2016 0750 N/A 1.00 NO 15.47 37 5.20 1.3 407 7.72 1.00 NO 15.47 37 5.16 1.1 427 7.69 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 1.00 NO 15.61 37 5.11 4.2 432 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 7.65 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 39.34 WATER COLUMN (ft) 4.73 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)802.90 WELL VOLUME 0.77 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 842.24 MIDDLE OF WETTED SCREEN (ft toc)41.71 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 44.07 GS ELEV (ft msl) 840.26 PUMP INTAKE DEPTH (ft TOC)43.07 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-2S SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-5 67.47 72.47 40 (psi)10 (sec)(sec) (gal) 5.14 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 14.25 LDC 10/12/2016 0855 N/A 2.25 NO 16.05 120 8.92 0.6 278 3.85 2.25 NO 15.92 121 9.06 0.7 267 3.68 2.25 NO 15.83 125 9.29 0.6 254 3.36 2.25 NO 15.69 130 9.53 0.7 256 2.82 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 5.25 60.02 NO 15.64 145 9.82 0.9 274 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 2.47 2.03 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 40.94 WATER COLUMN (ft) 31.53 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)801.44 WELL VOLUME 5.14 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 842.38 MIDDLE OF WETTED SCREEN (ft toc)69.97 SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 72.47 GS ELEV (ft msl) 840.17 PUMP INTAKE DEPTH (ft TOC)71.47 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-2D SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-6 10.02 15.02 8 (psi)10 (sec)(sec) (gal) (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units) TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 0.00 PSP 10/12/2016 0825 N/A OXYGEN (recalculates on current water level)(mV-NHE)(mg/L)(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME Could not measure water level, probe would not fit past pump, considered DRY, No Samples collected PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 811.56 MIDDLE OF WETTED SCREEN (ft toc)12.52 SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 15.02 GS ELEV (ft msl) 810.56 PUMP INTAKE DEPTH (ft TOC)14.02 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-3S SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-7 30.19 35.19 20 (psi)10 (sec)(sec) (gal) 3.02 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 9.25 PSP 10/12/2016 0910 N/A 3.00 NO 16.00 65 5.35 1.0 429 6.39 3.00 NO 16.01 65 5.32 1.1 423 6.32 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 3.25 NO 15.97 65 5.27 1.2 417 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 6.10 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 16.65 WATER COLUMN (ft) 18.54 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)795.09 WELL VOLUME 3.02 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 811.74 MIDDLE OF WETTED SCREEN (ft toc)32.69 SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 35.19 GS ELEV (ft msl) 810.47 PUMP INTAKE DEPTH (ft TOC)34.18 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-3D SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-8 53.33 68.33 35 (psi)10 (sec)(sec) (gal) 6.32 (gal) @ QC By: SITE NAME ROGERS COMPLEX PERMIT # 81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-4 MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 845.95 MIDDLE OF WETTED SCREEN (ft toc)60.83 SCREEN LENGTH (ft) 15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 68.33 GS ELEV (ft msl) 843.29 PUMP INTAKE DEPTH (ft TOC)67.33 Well evacuated 1225 hrs on 10/12/2016 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional 6.32 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Turbid SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 29.61 WATER COLUMN (ft) 38.72 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)816.34 WELL VOLUME (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 6.50 61.37 NO 16.04 187 9.09 110.0 -42 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 0.00 1.14 1.25 BELOW PUMP YES 17.69 166 9.31 632.0 -131 0.08 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 7.75 PSP 10/12/2016 1230 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Sample preservation verified to pH (units)< 2.0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES Top of Pump sets at 64.10 feet below TOC 12 T SP TU DISS ( A-9 65.40 75.40 40 (psi)10 (sec)(sec) (gal) 5.12 (gal) @ QC By: SITE NAME ROGERS COMPLEX PERMIT # 81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-5 MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 858.63 MIDDLE OF WETTED SCREEN (ft toc)70.40 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 75.40 GS ELEV (ft msl) 855.87 PUMP INTAKE DEPTH (ft TOC)74.40 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional 5.12 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 44.01 WATER COLUMN (ft) 31.39 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)814.62 WELL VOLUME (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 5.25 70.03 NO 16.87 198 10.28 9.2 125 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 3.55 0.88 1.00 BELOW PUMP YES 18.29 188 9.99 7.0 135 2.36 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 6.25 PSP 10/12/2016 1350 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED Sample preservation verified to pH (units)< 2.0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 12 T SP TU DISS ( A-10 36.73 46.73 20 (psi)10 (sec)(sec) (gal) @ QC By: SITE NAME ROGERS COMPLEX PERMIT # 81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR LOW FLOW SAMPLING PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-6S MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 854.38 MIDDLE OF WETTED SCREEN (ft toc)42.51 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 46.73 GS ELEV (ft msl) 851.48 PUMP INTAKE DEPTH (ft TOC)45.73 Target 275 mL/min.PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Low Flow 1.38 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Turbid SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 38.29 WATER COLUMN (ft) 8.44 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)816.09 WELL VOLUME (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL (recalculates on current water level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L) LEVEL COND.OXYGEN N/A 9:45 38.78 270 16.39 62 5.89 135.0 398 5.46 N/A 9:40 38.78 270 16.38 66 5.81 3.9 407 5.68 N/A 9:55 38.78 270 16.53 60 5.61 181.0 401 4.97 N/A 9:50 38.78 270 16.49 60 5.70 172.0 402 5.36 N/A 10:05 38.78 270 16.76 62 5.54 152.0 400 4.47 N/A 10:00 38.78 270 16.65 61 5.57 155.0 401 4.81 N/A 10:15 38.78 270 16.84 62 5.50 91.3 402 4.40 N/A 10:10 38.78 270 16.89 62 5.52 104.0 400 4.41 N/A 10:25 38.78 270 16.84 62 5.47 76.3 408 4.61 N/A 10:20 38.78 270 16.87 62 5.48 62.6 405 4.54 DRAW-DOWN 0.49 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 4.00 (gal)LDC 10/12/2016 1030 NA Sample preservation verified to pH (units)< 2.0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 12 T SP TU DISS ( WEL A-11 53.08 63.08 30 (psi)13 (sec)(sec) (gal) @ QC By: SITE NAME ROGERS COMPLEX PERMIT # 81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR LOW FLOW SAMPLING PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPMW-6D MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 854.35 MIDDLE OF WETTED SCREEN (ft toc)58.08 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 63.08 GS ELEV (ft msl) 851.45 PUMP INTAKE DEPTH (ft TOC)62.08 Target 290 mL/min.PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 7 28652 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Low Flow 4.05 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 38.26 WATER COLUMN (ft) 24.82 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)816.09 WELL VOLUME (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL (recalculates on current water level)(hh:mm)(ft)(ml/min) (deg C) (umho/cm) (SU)(NTU)(mV -NEH)(mg/L) LEVEL COND.OXYGEN N/A 10:35 38.28 290 17.22 79 5.36 0.7 387 7.89 N/A 10:30 38.28 290 17.26 79 5.38 1.0 396 7.86 N/A10:40 38.28 290 17.27 79 5.35 0.9 378 7.91 DRAW-DOWN 0.02 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)INITIAL PURGE VOLUME 6.50 (gal)SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 7.30 (gal)LDC 10/12/2016 1045 NA Sample preservation verified to pH (units)< 2.0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 12 T SP TU DISS ( WEL A-12 26.78 36.78 18 (psi)10 (sec)(sec) (gal) 1.01 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 3.25 PSP 10/12/2016 1050 N/A 1.00 NO 16.92 49 5.19 2.3 417 5.58 1.00 NO 17.16 48 5.15 2.2 421 5.58 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 1.25 NO 17.07 47 5.16 4.6 411 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 5.64 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 30.58 WATER COLUMN (ft) 6.20 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)808.34 WELL VOLUME 1.01 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 838.92 MIDDLE OF WETTED SCREEN (ft toc)33.68 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 36.78 GS ELEV (ft msl) 836.81 PUMP INTAKE DEPTH (ft TOC)35.78 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPTW-1S SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-13 63.23 68.23 35 (psi)10 (sec)(sec) (gal) 6.04 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 8.50 PSP 10/12/2016 1115 N/A 0.75 NO 17.85 553 7.54 10.0 331 1.77 0.75 NO 17.18 578 7.57 29.2 348 2.66 0.75 BELOW PUMP NO 16.93 559 7.63 29.6 360 5.30 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 6.25 63.83 NO 16.87 252 7.73 2.3 343 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 8.91 0.72 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 31.21 WATER COLUMN (ft) 37.02 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)807.32 WELL VOLUME 6.04 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 838.53 MIDDLE OF WETTED SCREEN (ft toc)65.73 SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 68.23 GS ELEV (ft msl) 836.41 PUMP INTAKE DEPTH (ft TOC)67.23 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPTW-1D SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-14 37.63 47.63 22 (psi)10 (sec)(sec) (gal) 0.71 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 2.25 PSP 10/12/2016 0800 N/A 0.75 NO 16.05 84 5.06 7.7 413 6.82 0.75 NO 16.08 84 5.07 12.0 405 6.88 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 0.75 NO 16.10 85 5.13 28.1 387 (ft)(YES/NO) (deg C) (umho/cm) (SU)(NTU) 6.80 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 43.28 WATER COLUMN (ft) 4.35 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)798.90 WELL VOLUME 0.71 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 20 3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in) 2 TOC ELEV (ft msl) 842.18 MIDDLE OF WETTED SCREEN (ft toc)45.46 SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 47.63 GS ELEV (ft msl) 839.62 PUMP INTAKE DEPTH (ft TOC)46.63 PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPTW-2 SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 12 T SP TU DISS ( A-15 0.00 0.00 (psi)(sec)(sec) (gal) (ft)=(in)@ QC By: SAMPLING NOTES PROTECTIVE CASING WELL PAD WELL CASING WELL TAG WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 1250 340 9.72 N/A N/A Deployed Water Column In Screen Above Top Of Hydrasleeve NO PURGE SAMPLE CHLORINE (mg/l)Top Weight SAMPLE COLLECTED BY DATE (NTU)(mV-NHE)(mg/L) N/A N/A N/A 12.31 43 6.56 6.4 TIME LDC 10/12/2016 LENGTH DEPTH (top) DEPLOYED COND.OXYGEN (inches)(ft TOC)(deg C) (umho/cm) (SU) HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED DETECTED ODOR CONVERSION FACTOR APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE N/A SAMPLING EQUIPMENT GRAB PURGE METHOD TUBING DIAMETER (in)No Purge MONITORING WELL INFORMATION WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc) SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) GS ELEV (ft msl) PUMP INTAKE DEPTH (ft TOC)N/A PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPSW-1 SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR NO PURGE SAMPLING 12 T SP TU DISS A-16 0.00 0.00 N/A (psi)N/A (sec)(sec) (gal) (ft)=(in)@ QC By: SAMPLING NOTES PROTECTIVE CASING WELL PAD WELL CASING WELL TAG WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 0950 323 8.98 N/A N/A Deployed Water Column In Screen Above Top Of Hydrasleeve NO PURGE SAMPLE CHLORINE (mg/l)Top Weight SAMPLE COLLECTED BY DATE (NTU)(mV-NHE)(mg/L) N/A N/A N/A 12.26 45 6.48 8.3 TIME PSP 10/12/2016 LENGTH DEPTH (top) DEPLOYED COND.OXYGEN (inches)(ft TOC)(deg C) (umho/cm) (SU) HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED DETECTED ODOR CONVERSION FACTOR APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE N/A N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD TUBING DIAMETER (in)3/8 OD No Purge MONITORING WELL INFORMATION WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc) SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) GS ELEV (ft msl) PUMP INTAKE DEPTH (ft TOC)N/A PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPSW-2 SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR NO PURGE SAMPLING 12 T SP TU DISS A-17 0.00 0.00 (psi)(sec)(sec) (gal) (ft)=(in)@ QC By: SAMPLING NOTES PROTECTIVE CASING WELL PAD WELL CASING WELL TAG Sample preservation verified to pH (units)< 2.0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES N/A N/A Deployed Water Column In Screen Above Top Of Hydrasleeve NO PURGE SAMPLE CHLORINE (mg/l)Top Weight SAMPLE COLLECTED BY DATE (NTU)(mV-NHE)(mg/L) N/A N/A N/A TIME PSP 10/12/2016 LENGTH DEPTH (top) DEPLOYED COND.OXYGEN (inches)(ft TOC)(deg C) (umho/cm) (SU) HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED DETECTED ODOR CONVERSION FACTOR APPEARANCE SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME NO SAMPLE, LOCATION DRY PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE N/A SAMPLING EQUIPMENT PURGE METHOD TUBING DIAMETER (in)No Purge MONITORING WELL INFORMATION WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc) SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) GS ELEV (ft msl) PUMP INTAKE DEPTH (ft TOC)N/A PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCPSW-3 SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR NO PURGE SAMPLING 12 T SP TU DISS A-18 0.00 0.00 (psi)(sec)(sec) (gal) (ft)=(in)@ QC By: SAMPLING NOTES PROTECTIVE CASING WELL PAD WELL CASING WELL TAG WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 0915 453 6.61 N/A N/A Deployed Water Column In Screen Above Top Of Hydrasleeve NO PURGE SAMPLE CHLORINE (mg/l)Top Weight SAMPLE COLLECTED BY DATE (NTU)(mV-NHE)(mg/L) N/A N/A N/A 19.98 35487 4.37 48.1 TIME LDC 10/12/2016 LENGTH DEPTH (top) DEPLOYED COND.OXYGEN (inches)(ft TOC)(deg C) (umho/cm) (SU) HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED DETECTED ODOR None CONVERSION FACTOR APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE N/A SAMPLING EQUIPMENT GRAB PURGE METHOD TUBING DIAMETER (in)No Purge MONITORING WELL INFORMATION WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc) SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) GS ELEV (ft msl) PUMP INTAKE DEPTH (ft TOC)N/A PROJECT NAME ROGERS CCP LANDFILL FIELD CREW LDC, PSP SAMPLING DATE(s)12-Oct-2016 WELL/LOCATION NAME CCP-LEACHATE SITE NAME ROGERS COMPLEX PERMIT #81-06 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.4 GROUNDWATER MONITORING DATA SHEET FOR NO PURGE SAMPLING 12 T SP TU DISS A-19 PE R M I T # CC P M W - 1 S C C P M W - 1 D C C P M W - 2 S C C P M W - 2 D C C P M W - 3 S C C P MW - 3 D C C P M W - 4 C C P M W - 5 C C P M W - 6 S C C P M W - 6 D C C P T W - 1 S C C P T W - 1 D C C P T W - 2 C C P S W - 1 C C P S W - 2 C C P S W - 3 L E A C H YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A YE S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N / A N / A N / A N / A NO R T H C A R O L I N A G R O U N D W A T E R S A M P L I N G S I T E C H E C K L I S T LO C A T I O N / S I T E RO G E R S C O M P L E X - C C P L A N D F I L L G R O U N D W A T E R M O N I T O R I N G 81 - 0 6 SA M P L E D A T E October 12, 2016 SI T E C O N T A C T St e v e H o d g e s FI E L D C R E W LDC, PSP WE A T H E R Cle a r , c a l m , 4 0 t o 7 0 d e g F . WE L L L O C K C O N D I T I O N PA G E 1 O F 1 AC C E S S T O W E L L S Ac c e s s c l e a r e d i n t o w e l l Ac c e s s c l e a r e d a r o u n d w e l l Ta l l g r a s s o r w e e d s - n e e d s m o w i n g Ro a d w a s h i n g o u t / m u d d y / n e e d s g r a d i n g Fa l l e n t r e e b l o c k i n g a c c e s s WE L L S E C U R I T Y We l l f o u n d l o c k e d We l l f o u n d u n l o c k e d Un d e r m i n e d / w a s h i n g o u t Lo c k i n g o o d c o n d i t i o n Lo c k r u s t e d , d i f f i c u l t t o o p e n / n e e d s r e p l a c i n g Re p l a c e d d a m a g e d l o c k WE L L C A S I N G S Ca s i n g i n g o o d c o n d i t i o n Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Da m a g e d c a s i n g / r e p a i r r e q u i r e d CO N C R E T E P A D S Pa d i n g o o d c o n d i t i o n Min o r c r a c k s Ma j o r c r a c k s / b r o k e n / r e p a i r r e q u i r e d Re p l a c e d d a m a g e d w e l l c a p Fi r e a n t s a r o u n d c o n c r e t e p a d WE L L P R O T E C T I V E C A S I N G S Ca s i n g i n g o o d c o n d i t i o n Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Da m a g e d c a s i n g / r e p a i r r e q u i r e d Br o k e n h i n g e o n p r o t e c t i v e l i d Wa s p n e s t i n s i d e p r o t e c t i v e c a s i n g An t s i n s i d e p r o t e c t i v e c a s i n g WE L L C A P S We l l c a p i n g o o d c o n d i t o n Da m a g e d / n e e d s r e p l a c e m e n t La c k s r e q u i r e d i n f o r m a t i o n - C o m p l e t i o n d a t e FL U S H M O U N T W E L L S Va u l t i n g o o d c o n d i t i o n Wa t e r i n s i d e v a u l t Va u l t b o l t h o l e s b r o k e n o r s t r i p p e d Bo l t s s t r i p p e d Va u l t l i d c r a c k e d o r b r o k e n WE L L I D T A G S We l l t a g i n g o o d c o n d i t i o n We l l t a g m i s s i n g We l l t a g d a m a g e d / i l l e g i b l e La c k s r e q u i r e d i n f o r m a t i o n - D r i l l e r R e g # La c k s r e q u i r e d i n f o r m a t i o n - T o t a l w e l l d e p t h La c k s r e q u i r e d i n f o r m a t i o n - D e p t h t o s c r e e n La c k s r e q u i r e d i n f o r m a t i o n - N o n p o t a b l e t a g NO T E : A-20 WE L L D E P T H T O W A T E R Pu r g e A V G * W E L L E V A C SP E C I F I C WE L L D E P T H W A T E R E L E V . Me t h o d P M P R A T E V O L V O L E V A C T E M P C O N D U C T A N C E p H T U R B I D I T Y O R P D O DA T E NO . ( f e e t - t o c ) ( f e e t - t o c ) ( f e e t ) A P P E A R A N C E O D O R (m l / m i n ) ( g a l ) ( g a l ) ( y e s / n o ) ( d e g C ) ( u m h o / c m ) ( u n i t s ) ( N T U ) (mV-NHE )(mg/l) 10 / 1 2 / 2 0 1 6 C C P M W - 1 S 4 2 . 2 4 3 7 . 7 7 8 3 7 . 8 1 N o r m a l N o n e E O P N / A 0 . 7 3 0 . 3 7 N / A 1 6 . 4 9 30 4.4 1 . 5 4 3 4 8 . 2 6 10 / 1 2 / 2 0 1 6 C C P M W - 1 D 5 6 . 7 0 3 8 . 5 1 8 3 7 . 3 8 N o r m a l N o n e C N / A 2 . 9 7 1 2 . 0 0 N O 1 5 . 9 4 50 5.3 1 . 0 4 0 2 7 . 8 2 10 / 1 2 / 2 0 1 6 C C P M W - 2 S 4 4 . 0 7 3 9 . 3 4 8 0 2 . 9 0 N o r m a l N o n e C N / A 0 . 7 7 3 . 0 0 N O 1 5 . 4 7 37 5.2 1 . 3 4 0 7 7 . 7 2 10 / 1 2 / 2 0 1 6 C C P M W - 2 D 7 2 . 4 7 4 0 . 9 4 8 0 1 . 4 4 N o r m a l N o n e C N / A 5 . 1 4 1 4 . 2 5 N O 1 6 . 0 5 12 0 8.9 0 . 6 2 7 8 3 . 8 5 10 / 1 2 / 2 0 1 6 C C P M W - 3 S 1 5 . 0 2 N S N S N S NS N S N S N S N S N S N S NS NS N S N S N S 10 / 1 2 / 2 0 1 6 C C P M W - 3 D 3 5 . 1 9 1 6 . 6 5 7 9 5 . 0 9 N o r m a l N o n e C N / A 3 . 0 2 9 . 2 5 N O 1 6 . 0 0 65 5.4 1 . 0 4 2 9 6 . 3 9 10 / 1 2 / 2 0 1 6 C C P M W - 4 6 8 . 3 3 2 9 . 6 1 8 1 6 . 3 4 T u r b i d N o n e C N / A 6 . 3 2 7 . 7 5 Y E S 1 7 . 6 9 16 6 9.3 6 3 2 . 0 - 1 3 1 0 . 0 8 10 / 1 2 / 2 0 1 6 C C P M W - 5 7 5 . 4 0 4 4 . 0 1 8 1 4 . 6 2 N o r m a l N o n e C N / A 5 . 1 2 6 . 2 5 Y E S 1 8 . 2 9 18 8 10.0 7 . 0 1 3 5 2 . 3 6 10 / 1 2 / 2 0 1 6 C C P M W - 6 S 4 6 . 7 3 3 8 . 2 9 8 1 6 . 0 9 T u r b i d N o n e L F 2 7 0 1 . 3 8 4 . 0 0 N / A 1 6 . 8 4 62 5.5 7 6 . 3 4 0 8 4 . 6 1 10 / 1 2 / 2 0 1 6 C C P M W - 6 D 6 3 . 0 8 3 8 . 2 6 8 1 6 . 0 9 N o r m a l N o n e L F 2 9 0 4 . 0 5 7 . 3 0 N / A 1 7 . 2 7 79 5.4 0 . 9 3 7 8 7 . 9 1 10 / 1 2 / 2 0 1 6 C C P T W - 1 S 3 6 . 7 8 3 0 . 5 8 8 0 8 . 3 4 N o r m a l N o n e C N / A 1 . 0 1 3 . 2 5 N O 1 6 . 9 2 49 5.2 2 . 3 4 1 7 5 . 5 8 10 / 1 2 / 2 0 1 6 C C P T W - 1 D 6 8 . 2 3 3 1 . 2 1 8 0 7 . 3 2 N o r m a l N o n e C N / A 6 . 0 4 8 . 5 0 N O 1 7 . 8 5 55 3 7.5 1 0 . 0 3 3 1 1 . 7 7 10 / 1 2 / 2 0 1 6 C C P T W - 2 4 7 . 6 3 4 3 . 2 8 7 9 8 . 9 0 N o r m a l N o n e C N / A 0 . 7 1 2 . 2 5 N O 1 6 . 0 5 84 5.1 7 . 7 4 1 3 6 . 8 2 10 / 1 2 / 2 0 1 6 C C P S W - 1 N / A N / A N / A N o r m a l - - - N P N / A N / A N / A N / A 1 2 . 3 1 43 6.6 6 . 4 3 4 0 9 . 7 2 10 / 1 2 / 2 0 1 6 C C P S W - 2 N / A N / A N / A N o r m a l - - - N P N / A N / A N / A N / A 1 2 . 2 6 45 6.5 8 . 3 3 2 3 8 . 9 8 10 / 1 2 / 2 0 1 6 C C P S W - 3 N / A N / A N / A D r y D r y D r y D r y D r y D r y D r y D r y Dr y Dry D r y D r y D r y 10 / 1 2 / 2 0 1 6 C C P - L E A C H A T E N / A N / A N / A N o r m a l N o n e N P N / A N / A N / A N / A 1 9 . 9 8 35 4 8 7 4 . 4 4 8 . 1 4 5 3 6 . 6 1 Pu r g e M e t h o d s LF = L o w F l o w LF ( M ) = L o w F l o w ( M o d . ) C = C o n n v e n t i o n a l NP = N o P u r g e EO P = E q u i p . O n l y P u r g e LO = L e v e l O n l y NS = N o t S a m p l e d I n s u f f i c i e n t V o l u m e i n W e l l * = A p p l i c a b l e t o L F & L F ( M ) P u r g i n g O n l y RO G E R S C O M P L E X RO G E R S C C P L A N D F I L L GR O U N D W A T E R M O N I T O R I N G F I E L D D A T A PE R M I T # 8 1 - 0 6 A-21 B Appendix B Laboratory Report and Chain-of-Custody Forms 13339 Hagers Ferry RoadHuntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J16090463 Project Name:CLIFFSIDE - GW CCP LANDFILL Lab Contact: Anne Pridgeon Date:11/1/2016 Customer Address:573 Duke Power Rd Customer Name(s):Chuck Campbell, TSH, SEAN DENEALE Mail Code: Clliffside Steam Station Mooresboro, NC 28024 Phone: 980-875-6610 Report Authorized By: (Signature) Program Comments: As per the chain of custody, MW-3S was not collected due to insufficient volume whereas site location SW-3 was dry. Please note the calcium detection in the field blank above the reporting limit. This analyte is also present in all associated samples in this dataset. Method 2540C: Sample CCPMW-4 was initially analyzed within hold with less than the method recommended volume due to foaming. Reanalysis out of hold was performed to achieve a result with the full volume and lower reporting limit. Results have confirmed one another and data has been flagged accordingly. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Anne Pridgeon Duke Energy Analytical Lab Page 1 of 31 Reason: I have reviewed this document. Date: 2016.11.01 10:58:50 -04'00' B-1 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016030328 CLIFFSIDE 12-Oct-16 11:25 AM LDC CCPMW-1S 2016030329 CLIFFSIDE 12-Oct-16 12:25 PM LDC CCPMW-1D 2016030330 CLIFFSIDE 12-Oct-16 7:50 AM LDC CCPMW-2S 2016030331 CLIFFSIDE 12-Oct-16 8:55 AM LDC CCPMW-2D 2016030333 CLIFFSIDE 12-Oct-16 9:10 AM PSP CCPMW-3D 2016030334 CLIFFSIDE 12-Oct-16 12:30 PM PSP CCPMW-4 2016030335 CLIFFSIDE 12-Oct-16 1:50 PM PSP CCPMW-5 2016030336 CLIFFSIDE 12-Oct-16 10:30 AM LDC CCPMW-6S 2016030337 CLIFFSIDE 12-Oct-16 10:45 AM LDC CCPMW-6D 2016030338 CLIFFSIDE 12-Oct-16 10:50 AM PSP CCPTW-1S 2016030339 CLIFFSIDE 12-Oct-16 11:15 AM PSP CCPTW-1D 2016030340 CLIFFSIDE 12-Oct-16 8:00 AM PSP CCPTW-2 2016030341 CLIFFSIDE 12-Oct-16 12:50 PM LDC CCPSW-1 2016030342 CLIFFSIDE 12-Oct-16 9:50 AM PSP CCPSW-2 2016030344 CLIFFSIDE 12-Oct-16 9:15 AM LDC CCP Leachate 2016030345 CLIFFSIDE 12-Oct-16 2:15 PM LDC FIELD BLANK 16 Total Samples Duke Energy Analytical Lab Page 2 of 31 B-2 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:10/26/2016 Electronic Data Deliverable (EDD) Sent Separatel Duke Energy Analytical Lab Page 3 of 31 B-3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030328 Collection Date:12-Oct-16 11:25 AM Site:CCPMW-1S Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 3.6 mg/L EPA 9056A 10/13/2016 09:47 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 09:47 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 10/13/2016 09:47 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 10/13/2016 09:47 BGN90340.023 1 Sulfate 1.1 mg/L EPA 9056A 10/13/2016 09:47 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 12:47 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.024 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 10:49 MHH71310.05 1 Calcium (Ca)0.549 mg/L SW 6010D 10/24/2016 10:49B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 Iron (Fe)0.532 mg/L SW 6010D 10/24/2016 10:49 MHH71310.01 1 Magnesium (Mg)0.741 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 Manganese (Mn)0.031 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 Potassium (K)0.864 mg/L SW 6010D 10/24/2016 10:49 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 Sodium (Na)1.38 mg/L SW 6010D 10/24/2016 10:49 MHH71310.05 1 Zinc (Zn)0.044 mg/L SW 6010D 10/24/2016 10:49 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 Chromium (Cr)1.05 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 15:23 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 4 of 31 B-4 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030329 Collection Date:12-Oct-16 12:25 PM Site:CCPMW-1D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)5.4 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 6.3 mg/L EPA 9056A 10/13/2016 10:36 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 10:36 BGN90340.1 1 Nitrate 4.9 mg/L EPA 9056A 10/13/2016 10:36 BGN90340.1 1 Nitrate as N 1.1 mg-N/L EPA 9056A 10/13/2016 10:36 BGN90340.023 1 Sulfate 1.2 mg/L EPA 9056A 10/13/2016 10:36 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 12:50 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.017 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:06 MHH71310.05 1 Calcium (Ca)3.14 mg/L SW 6010D 10/24/2016 11:06B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 Iron (Fe)0.015 mg/L SW 6010D 10/24/2016 11:06 MHH71310.01 1 Magnesium (Mg)1.61 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 Manganese (Mn)0.014 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 Potassium (K)1.35 mg/L SW 6010D 10/24/2016 11:06 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 Sodium (Na)2.73 mg/L SW 6010D 10/24/2016 11:06 MHH71310.05 1 Zinc (Zn)0.007 mg/L SW 6010D 10/24/2016 11:06 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 Nickel (Ni)1.37 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 15:00 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 28 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 5 of 31 B-5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030330 Collection Date:12-Oct-16 7:50 AM Site:CCPMW-2S Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 4.5 mg/L EPA 9056A 10/13/2016 11:41 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 11:41 BGN90340.1 1 Nitrate 2.9 mg/L EPA 9056A 10/13/2016 11:41 BGN90340.1 1 Nitrate as N 0.65 mg-N/L EPA 9056A 10/13/2016 11:41 BGN90340.023 1 Sulfate 0.41 mg/L EPA 9056A 10/13/2016 11:41 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 12:52 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:10 MHH71310.05 1 Calcium (Ca)2.07 mg/L SW 6010D 10/24/2016 11:10B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 Iron (Fe)0.034 mg/L SW 6010D 10/24/2016 11:10 MHH71310.01 1 Magnesium (Mg)0.961 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 Manganese (Mn)0.009 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 Potassium (K)1.72 mg/L SW 6010D 10/24/2016 11:10 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 Sodium (Na)2.00 mg/L SW 6010D 10/24/2016 11:10 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 10/24/2016 11:10 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 15:30 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 6 of 31 B-6 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030331 Collection Date:12-Oct-16 8:55 AM Site:CCPMW-2D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)46 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride 4.8 mg/L EPA 9056A 10/13/2016 11:57 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 11:57 BGN90340.1 1 Nitrate 4.3 mg/L EPA 9056A 10/13/2016 11:57 BGN90340.1 1 Nitrate as N 0.98 mg-N/L EPA 9056A 10/13/2016 11:57 BGN90340.023 1 Sulfate 4.7 mg/L EPA 9056A 10/13/2016 11:57 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 12:55 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.007 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:14 MHH71310.05 1 Calcium (Ca)17.7 mg/L SW 6010D 10/24/2016 11:14B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 10/24/2016 11:14 MHH71310.01 1 Magnesium (Mg)0.622 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 Potassium (K)2.49 mg/L SW 6010D 10/24/2016 11:14 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 Sodium (Na)5.25 mg/L SW 6010D 10/24/2016 11:14 MHH71310.05 1 Zinc (Zn)0.096 mg/L SW 6010D 10/24/2016 11:14 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 15:38 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 49 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 7 of 31 B-7 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030333 Collection Date:12-Oct-16 9:10 AM Site:CCPMW-3D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 5.0 mg/L EPA 9056A 10/13/2016 12:11 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 12:11 BGN90340.1 1 Nitrate 6.2 mg/L EPA 9056A 10/13/2016 12:11 BGN90340.1 1 Nitrate as N 1.4 mg-N/L EPA 9056A 10/13/2016 12:11 BGN90340.023 1 Sulfate 9.1 mg/L EPA 9056A 10/13/2016 12:11 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 12:57 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.027 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:18 MHH71310.05 1 Calcium (Ca)5.26 mg/L SW 6010D 10/24/2016 11:18B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 10/24/2016 11:18 MHH71310.01 1 Magnesium (Mg)1.90 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 Manganese (Mn)0.009 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 Potassium (K)1.52 mg/L SW 6010D 10/24/2016 11:18 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 Sodium (Na)2.23 mg/L SW 6010D 10/24/2016 11:18 MHH71310.05 1 Zinc (Zn)0.006 mg/L SW 6010D 10/24/2016 11:18 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 Chromium (Cr)1.27 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 15:46 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 38 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 8 of 31 B-8 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030334 Collection Date:12-Oct-16 12:30 PM Site:CCPMW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)70 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride 1.7 mg/L EPA 9056A 10/13/2016 12:26 BGN90340.1 1 Fluoride 0.15 mg/L EPA 9056A 10/13/2016 12:26 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 10/13/2016 12:26 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 10/13/2016 12:26 BGN90340.023 1 Sulfate 3.0 mg/L EPA 9056A 10/13/2016 12:26 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:00 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.129 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:23 MHH71310.05 1 Calcium (Ca)21.4 mg/L SW 6010D 10/24/2016 11:23B1 MHH71310.01 1 Copper (Cu)0.031 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 Iron (Fe)22.4 mg/L SW 6010D 10/24/2016 11:23 MHH71310.01 1 Magnesium (Mg)7.22 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 Manganese (Mn)0.279 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 Potassium (K)23.4 mg/L SW 6010D 10/24/2016 11:23 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 Sodium (Na)14.7 mg/L SW 6010D 10/24/2016 11:23 MHH71310.05 1 Zinc (Zn)0.058 mg/L SW 6010D 10/24/2016 11:23 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)3.03 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 Chromium (Cr)76.3 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 Lead (Pb)8.06 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 Nickel (Ni)33.9 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 16:17 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 10/28/2016 13:05N1 HGRUVER501 Duke Energy Analytical Lab Page 9 of 31 B-9 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030335 Collection Date:12-Oct-16 1:50 PM Site:CCPMW-5 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)57 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride 8.7 mg/L EPA 9056A 10/13/2016 13:26 BGN90340.1 1 Fluoride 0.31 mg/L EPA 9056A 10/13/2016 13:26 BGN90340.1 1 Nitrate 2.0 mg/L EPA 9056A 10/13/2016 13:26 BGN90340.1 1 Nitrate as N 0.45 mg-N/L EPA 9056A 10/13/2016 13:26 BGN90340.023 1 Sulfate 15 mg/L EPA 9056A 10/13/2016 13:26 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:02 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:27 MHH71310.05 1 Calcium (Ca)19.1 mg/L SW 6010D 10/24/2016 11:27B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 Iron (Fe)0.076 mg/L SW 6010D 10/24/2016 11:27 MHH71310.01 1 Magnesium (Mg)0.151 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 Potassium (K)2.09 mg/L SW 6010D 10/24/2016 11:27 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 Sodium (Na)16.0 mg/L SW 6010D 10/24/2016 11:27 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 10/24/2016 11:27 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)5.22 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 16:24 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 110 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 10 of 31 B-10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030336 Collection Date:12-Oct-16 10:30 AM Site:CCPMW-6S Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 5.9 mg/L EPA 9056A 10/13/2016 12:56 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 12:56 BGN90340.1 1 Nitrate 8.9 mg/L EPA 9056A 10/13/2016 12:56 BGN90340.1 1 Nitrate as N 0.39 mg-N/L EPA 9056A 10/13/2016 12:56 BGN90340.023 1 Sulfate 5.9 mg/L EPA 9056A 10/13/2016 12:56 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:24 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.063 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:31 MHH71310.05 1 Calcium (Ca)2.03 mg/L SW 6010D 10/24/2016 11:31B1 MHH71310.01 1 Copper (Cu)0.006 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 Iron (Fe)4.65 mg/L SW 6010D 10/24/2016 11:31 MHH71310.01 1 Magnesium (Mg)2.62 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 Manganese (Mn)0.877 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 Potassium (K)3.20 mg/L SW 6010D 10/24/2016 11:31 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 Sodium (Na)3.45 mg/L SW 6010D 10/24/2016 11:31 MHH71310.05 1 Zinc (Zn)0.011 mg/L SW 6010D 10/24/2016 11:31 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)1.71 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 Chromium (Cr)6.32 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 Lead (Pb)3.63 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 Nickel (Ni)10.8 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 16:32 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 43 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 11 of 31 B-11 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030337 Collection Date:12-Oct-16 10:45 AM Site:CCPMW-6D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 6.5 mg/L EPA 9056A 10/13/2016 13:56 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 13:56 BGN90340.1 1 Nitrate 21 mg/L EPA 9056A 10/13/2016 13:56 BGN90340.5 5 Nitrate as N 4.8 mg-N/L EPA 9056A 10/13/2016 13:56 BGN90340.023 1 Sulfate 1.0 mg/L EPA 9056A 10/13/2016 13:56 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:26 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.077 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:35 MHH71310.05 1 Calcium (Ca)5.08 mg/L SW 6010D 10/24/2016 11:35B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 10/24/2016 11:35 MHH71310.01 1 Magnesium (Mg)2.73 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 Manganese (Mn)0.102 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 Potassium (K)2.34 mg/L SW 6010D 10/24/2016 11:35 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 Sodium (Na)4.75 mg/L SW 6010D 10/24/2016 11:35 MHH71310.05 1 Zinc (Zn)0.193 mg/L SW 6010D 10/24/2016 11:35 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 Chromium (Cr)1.11 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 Nickel (Ni)1.71 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 16:40 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 49 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 12 of 31 B-12 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030338 Collection Date:12-Oct-16 10:50 AM Site:CCPTW-1S Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)5.0 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 4.6 mg/L EPA 9056A 10/13/2016 17:04 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 17:04 BGN90340.1 1 Nitrate 9.3 mg/L EPA 9056A 10/13/2016 17:04 BGN90340.1 1 Nitrate as N 2.1 mg-N/L EPA 9056A 10/13/2016 17:04 BGN90340.023 1 Sulfate 0.61 mg/L EPA 9056A 10/13/2016 17:04 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:29 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.031 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:39 MHH71310.05 1 Calcium (Ca)2.61 mg/L SW 6010D 10/24/2016 11:39B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 Iron (Fe)0.049 mg/L SW 6010D 10/24/2016 11:39 MHH71310.01 1 Magnesium (Mg)1.76 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 Potassium (K)1.32 mg/L SW 6010D 10/24/2016 11:39 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 Sodium (Na)2.74 mg/L SW 6010D 10/24/2016 11:39 MHH71310.05 1 Zinc (Zn)0.021 mg/L SW 6010D 10/24/2016 11:39 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 16:47 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 36 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 13 of 31 B-13 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030339 Collection Date:12-Oct-16 11:15 AM Site:CCPTW-1D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)90 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride 3.5 mg/L EPA 9056A 10/14/2016 08:46 BGN90340.1 1 Fluoride 0.23 mg/L EPA 9056A 10/14/2016 08:46 BGN90340.1 1 Nitrate 1.8 mg/L EPA 9056A 10/14/2016 08:46 BGN90340.1 1 Nitrate as N 0.40 mg-N/L EPA 9056A 10/14/2016 08:46 BGN90340.023 1 Sulfate 110 mg/L EPA 9056A 10/14/2016 08:46 BGN9034220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:31 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.030 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 11:59 MHH71310.05 1 Calcium (Ca)39.6 mg/L SW 6010D 10/24/2016 11:59B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 Iron (Fe)0.444 mg/L SW 6010D 10/24/2016 11:59 MHH71310.01 1 Magnesium (Mg)3.25 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 Manganese (Mn)0.034 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 Potassium (K)4.01 mg/L SW 6010D 10/24/2016 11:59 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 Sodium (Na)68.7 mg/L SW 6010D 10/24/2016 11:59 MHH71310.05 1 Zinc (Zn)0.162 mg/L SW 6010D 10/24/2016 11:59 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)1.08 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 Chromium (Cr)1.15 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 Nickel (Ni)2.87 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 Selenium (Se)1.40 ug/L SW 6020B 10/17/2016 16:55 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 260 mg/L SM2540C 10/17/2016 16:24 HGRUVER2501 Duke Energy Analytical Lab Page 14 of 31 B-14 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030340 Collection Date:12-Oct-16 8:00 AM Site:CCPTW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 13 mg/L EPA 9056A 10/13/2016 17:35 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 17:35 BGN90340.1 1 Nitrate 9.7 mg/L EPA 9056A 10/13/2016 17:35 BGN90340.1 1 Nitrate as N 2.2 mg-N/L EPA 9056A 10/13/2016 17:35 BGN90340.023 1 Sulfate 4.8 mg/L EPA 9056A 10/13/2016 17:35 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:34 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.051 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 12:03 MHH71310.05 1 Calcium (Ca)4.77 mg/L SW 6010D 10/24/2016 12:03B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 Iron (Fe)0.416 mg/L SW 6010D 10/24/2016 12:03 MHH71310.01 1 Magnesium (Mg)3.83 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 Manganese (Mn)0.018 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 Potassium (K)1.95 mg/L SW 6010D 10/24/2016 12:03 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 Sodium (Na)2.48 mg/L SW 6010D 10/24/2016 12:03 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 10/24/2016 12:03 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 Chromium (Cr)1.43 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 17:03 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 56 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 15 of 31 B-15 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030341 Collection Date:12-Oct-16 12:50 PM Site:CCPSW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)11 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 4.1 mg/L EPA 9056A 10/13/2016 17:51 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 17:51 BGN90340.1 1 Nitrate 1.8 mg/L EPA 9056A 10/13/2016 17:51 BGN90340.1 1 Nitrate as N 0.41 mg-N/L EPA 9056A 10/13/2016 17:51 BGN90340.023 1 Sulfate 1.1 mg/L EPA 9056A 10/13/2016 17:51 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:36 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.020 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 12:07 MHH71310.05 1 Calcium (Ca)2.68 mg/L SW 6010D 10/24/2016 12:07B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 Iron (Fe)1.52 mg/L SW 6010D 10/24/2016 12:07 MHH71310.01 1 Magnesium (Mg)1.36 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 Manganese (Mn)0.045 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 Potassium (K)2.04 mg/L SW 6010D 10/24/2016 12:07 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 Sodium (Na)2.84 mg/L SW 6010D 10/24/2016 12:07 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 10/24/2016 12:07 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 17:10 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 40 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 16 of 31 B-16 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030342 Collection Date:12-Oct-16 9:50 AM Site:CCPSW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)11 mg/L (CaCO3) SM 2320B 10/19/2016 13:21 CJELLIO51 INORGANIC IONS BY IC Chloride 4.1 mg/L EPA 9056A 10/13/2016 16:00 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 16:00 BGN90340.1 1 Nitrate 1.5 mg/L EPA 9056A 10/13/2016 16:00 BGN90340.1 1 Nitrate as N 0.35 mg-N/L EPA 9056A 10/13/2016 16:00 BGN90340.023 1 Sulfate 1.3 mg/L EPA 9056A 10/13/2016 16:00 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:39 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.020 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 12:11 MHH71310.05 1 Calcium (Ca)2.81 mg/L SW 6010D 10/24/2016 12:11B1 MHH71310.01 1 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 Iron (Fe)1.68 mg/L SW 6010D 10/24/2016 12:11 MHH71310.01 1 Magnesium (Mg)1.39 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 Manganese (Mn)0.064 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 Potassium (K)2.03 mg/L SW 6010D 10/24/2016 12:11 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 Sodium (Na)2.70 mg/L SW 6010D 10/24/2016 12:11 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 10/24/2016 12:11 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 17:18 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 42 mg/L SM2540C 10/17/2016 16:24 HGRUVER251 Duke Energy Analytical Lab Page 17 of 31 B-17 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030344 Collection Date:12-Oct-16 9:15 AM Site:CCP Leachate Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)< 20 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride 17000 mg/L EPA 9056A 10/13/2016 18:07 BGN90342002000 Fluoride < 20 mg/L EPA 9056A 10/13/2016 18:07 BGN903420200 Nitrate < 20 mg/L EPA 9056A 10/13/2016 18:07 BGN903420200 Nitrate as N 2.7 mg-N/L EPA 9056A 10/13/2016 18:07 BGN90340.023 1 Sulfate 1200 mg/L EPA 9056A 10/13/2016 18:07 BGN903420200 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/20/2016 13:41 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.744 mg/L SW 6010D 10/24/2016 12:19 MHH71310.005 1 Boron (B)8.84 mg/L SW 6010D 10/24/2016 12:19 MHH71310.05 1 Calcium (Ca)7940 mg/L SW 6010D 10/24/2016 12:19B1 MHH71311100 Copper (Cu)< 0.005 mg/L SW 6010D 10/24/2016 12:19 MHH71310.005 1 Iron (Fe)8.99 mg/L SW 6010D 10/24/2016 12:19 MHH71310.01 1 Magnesium (Mg)56.1 mg/L SW 6010D 10/24/2016 12:19 MHH71310.005 1 Manganese (Mn)54.0 mg/L SW 6010D 10/24/2016 12:19 MHH71310.05 10 Potassium (K)552 mg/L SW 6010D 10/24/2016 12:19 MHH713110100 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 12:19 MHH71310.005 1 Sodium (Na)389 mg/L SW 6010D 10/24/2016 12:19 MHH71310.5 10 Zinc (Zn)0.390 mg/L SW 6010D 10/24/2016 12:19 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)29.4 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 Cadmium (Cd)< 5 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 Chromium (Cr)5.21 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 Lead (Pb)237 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 Nickel (Ni)269 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 Selenium (Se)102 ug/L SW 6020B 10/19/2016 13:44 PARMSTR55 TOTAL DISSOLVED SOLIDS TDS 35000 mg/L SM2540C 10/17/2016 16:24 HGRUVER5001 Duke Energy Analytical Lab Page 18 of 31 B-18 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 2016030345 Collection Date:12-Oct-16 2:15 PM Site:FIELD BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)< 20 mg/L (CaCO3) SM 2320B 10/19/2016 09:54 CJELLIO201 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 9056A 10/13/2016 09:32 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 10/13/2016 09:32 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 10/13/2016 09:32 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 10/13/2016 09:32 BGN90340.023 1 Sulfate < 0.1 mg/L EPA 9056A 10/13/2016 09:32 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 10/21/2016 13:09 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 10/24/2016 12:15 MHH71310.05 1 Calcium (Ca)2.36 mg/L SW 6010D 10/24/2016 12:15B1 MHH71310.01 1 Copper (Cu)0.061 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 10/24/2016 12:15 MHH71310.01 1 Magnesium (Mg)0.035 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 Potassium (K)< 0.1 mg/L SW 6010D 10/24/2016 12:15 MHH71310.1 1 Silver (Ag)< 0.005 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 Sodium (Na)< 0.05 mg/L SW 6010D 10/24/2016 12:15 MHH71310.05 1 Zinc (Zn)0.220 mg/L SW 6010D 10/24/2016 12:15 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 10/17/2016 17:57 PARMSTR11 Duke Energy Analytical Lab Page 19 of 31 B-19 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 N1 - Sample for TDS was originally analyzed on 10/17/16 at a reduced volume due to the sample matrix, within the recommended holding time. The result of this analysis was 200 mg/L, with a reporting limit of 250 mg/L. The analysis was repeated on 10/28/16 using more volume in order to lower the reporting limit. This repeat analysis (130 mg/L TDS with a 50 mg/L reporting limit) is included in this final report. This 2nd analysis was performed past the recommended holding time of 7 days. Qualifiers: B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte concentration in sample is not affected by contamination. N1 See additional information listed below. Duke Energy Analytical Lab Page 20 of 31 B-20 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100447 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Alkalinity (mg/L CaCO3)75.7 95.5mg/L (CaCO3)-12080172.3 Duke Energy Analytical Lab Page 21 of 31 B-21 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100475 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16090359 -- 2016029744 Alkalinity (mg/L CaCO3)63.2mg/L (CaCO3)-10.648 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Alkalinity (mg/L CaCO3)7.57 81.7mg/L (CaCO3)-1208016.19 Duke Energy Analytical Lab Page 22 of 31 B-22 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100300 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0464 mg/L -10.0464 0.1 < 1/2 RDL Fluoride 0.0209 mg/L -10.0209 0.1 < 1/2 RDL Nitrate 0.0213 mg/L -10.0213 0.1 < 1/2 RDL Sulfate -0.0029 mg/L -1-0.0029 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 5.78 5 101mg/L -1208015.78 Fluoride 5.13 5 102mg/L -1208015.13 Nitrate 4.91 5 97.6mg/L -1208014.91 Sulfate 5.05 5 95.7mg/L -1208015.05 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 5.75 5 100 0.584mg/L -1208015.75 Fluoride 5.12 5 102 0.218mg/L -1208015.12 Nitrate 4.87 5 96.8 0.887mg/L -1208014.87 Sulfate 4.82 5 91 4.99mg/L -1208014.82 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.87 5 97.4mg/L -1208014.87 Fluoride 5.07 5 101mg/L -1208015.07 Nitrate 4.83 5 96.6mg/L -1208014.83 Sulfate 4.74 5 94.7mg/L -1208014.74 Duke Energy Analytical Lab Page 23 of 31 B-23 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100521 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) -0.003 ug/L -1-0.003 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) -0.003 ug/L -1-0.003 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.1 1 105ug/L -1257511.1 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Mercury (Hg) 1.09 1 105 0.571ug/L -1257511.09 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.02 100 101ug/L -12575100102 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Mercury (Hg) 1.02 100 101 0.0987ug/L -12575100102 Final QualifierDilMeasuredUnits:Parameter IS # 3 % Recovery LCL UCLSpike Mercury (Hg) 0.92 1 92.1ug/L -1257510.92 Final QualifierDilMeasuredUnits:Parameter ISD # 3 RPD% Recovery LCL UCLSpike Mercury (Hg) 0.915 1 91.6 0.544ug/L -1257510.915 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.99 2 99.7ug/L -1158511.99 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.96 2 98ug/L -1158511.96 Duke Energy Analytical Lab Page 24 of 31 B-24 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100560 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) 0 ug/L -10 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 3 RDL Relative Concentration Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 4 RDL Relative Concentration Mercury (Hg) 0.005 ug/L -10.005 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Mercury (Hg) 0.967 1 95.9ug/L -1257510.967 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Mercury (Hg) 1 1 99.7 3.89ug/L -1257511 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Mercury (Hg) 0.968 1 96.1ug/L -1257510.968 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Mercury (Hg) 0.974 1 96.7 0.622ug/L -1257510.974 Final QualifierDilMeasuredUnits:Parameter IS # 3 % Recovery LCL UCLSpike Mercury (Hg) 0.827 1 81.6ug/L -1257510.827 Final QualifierDilMeasuredUnits:Parameter ISD # 3 RPD% Recovery LCL UCLSpike Mercury (Hg) 0.81 1 79.9 2.11ug/L -1257510.81 Final QualifierDilMeasuredUnits:Parameter IS # 4 % Recovery LCL UCLSpike Mercury (Hg) 0.967 1 95.3ug/L -1257510.967 Final QualifierDilMeasuredUnits:Parameter ISD # 4 RPD% Recovery LCL UCLSpike Mercury (Hg) 0.965 1 95.1 0.21ug/L -1257510.965 Duke Energy Analytical Lab Page 25 of 31 B-25 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100560 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 1.96 2 98ug/L -1158511.96 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.91 2 95.3ug/L -1158511.91 Duke Energy Analytical Lab Page 26 of 31 B-26 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100295 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.000074 mg/L -1-0.000074 0.005 < 1/2 RDL Boron (B) 0.002 mg/L -10.002 0.05 < 1/2 RDL Calcium (Ca) 0.0106 mg/L -10.0106 0.01 > RDL Copper (Cu) 0.000928 mg/L -10.000928 0.005 < 1/2 RDL Iron (Fe) 0.00107 mg/L -10.00107 0.01 < 1/2 RDL Magnesium (Mg) 0.000495 mg/L -10.000495 0.005 < 1/2 RDL Manganese (Mn) -0.00006 mg/L -1-0.00006 0.005 < 1/2 RDL Potassium (K) -0.0124 mg/L -1-0.0124 0.1 < 1/2 RDL Silver (Ag) -0.000697 mg/L -1-0.000697 0.005 < 1/2 RDL Sodium (Na) 0.00231 mg/L -10.00231 0.05 < 1/2 RDL Zinc (Zn) 0.000109 mg/L -10.000109 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.14 5 103mg/L -1208015.14 Boron (B) 5.05 5 101mg/L -1208015.05 Calcium (Ca) 5.17 5 104mg/L -1208015.17 Copper (Cu) 5.06 5 101mg/L -1208015.06 Iron (Fe) 5.2 5 104mg/L -1208015.2 Magnesium (Mg) 5.12 5 102mg/L -1208015.12 Manganese (Mn) 5.11 5 102mg/L -1208015.11 Potassium (K) 5.04 5 101mg/L -1208015.04 Silver (Ag) 0.486 0.5 97.2mg/L -1208010.486 Sodium (Na) 5.09 5 102mg/L -1208015.09 Zinc (Zn) 5.11 5 102mg/L -1208015.11 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16090463 -- 2016030328 Barium (Ba) 5.14 5 102mg/L -1257515.14 Boron (B) 5.04 5 101mg/L -1257515.04 Calcium (Ca) 5.71 5 103mg/L -1257515.71 Copper (Cu) 5.05 5 101mg/L -1257515.05 Iron (Fe) 5.66 5 102mg/L -1257515.66 Magnesium (Mg) 5.78 5 101mg/L -1257515.78 Manganese (Mn) 5.13 5 102mg/L -1257515.13 Potassium (K) 5.92 5 101mg/L -1257515.92 Silver (Ag) 0.48 0.5 95.8mg/L -1257510.48 Sodium (Na) 6.47 5 102mg/L -1257516.47 Zinc (Zn) 5.13 5 102mg/L -1257515.13 Duke Energy Analytical Lab Page 27 of 31 B-27 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100295 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16090463 -- 2016030328 Barium (Ba) 5.15 5 103 0.215mg/L -1257515.15 Boron (B) 5.01 5 99.9 0.718mg/L -1257515.01 Calcium (Ca) 5.69 5 103 0.311mg/L -1257515.69 Copper (Cu) 5.05 5 101 0mg/L -1257515.05 Iron (Fe) 5.69 5 103 0.603mg/L -1257515.69 Magnesium (Mg) 5.77 5 101 0.0993mg/L -1257515.77 Manganese (Mn) 5.14 5 102 0.176mg/L -1257515.14 Potassium (K) 5.92 5 101 0.0395mg/L -1257515.92 Silver (Ag) 0.48 0.5 95.7 0.147mg/L -1257510.48 Sodium (Na) 6.46 5 101 0.217mg/L -1257516.46 Zinc (Zn) 5.13 5 102 0.0983mg/L -1257515.13 Duke Energy Analytical Lab Page 28 of 31 B-28 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100301 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Arsenic (As) 0.0314 ug/L -10.0314 1 < 1/2 RDL Cadmium (Cd) -0.0011 ug/L -1-0.0011 1 < 1/2 RDL Chromium (Cr) -0.0213 ug/L -1-0.0213 1 < 1/2 RDL Lead (Pb) 0.0034 ug/L -10.0034 1 < 1/2 RDL Nickel (Ni) 0.0006 ug/L -10.0006 1 < 1/2 RDL Selenium (Se) 0.0864 ug/L -10.0864 1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Arsenic (As) 51.9 50 104ug/L -12080151.9 Cadmium (Cd) 53.6 50 107ug/L -12080153.6 Chromium (Cr) 53.9 50 108ug/L -12080153.9 Lead (Pb) 52.7 50 105ug/L -12080152.7 Nickel (Ni) 53.4 50 107ug/L -12080153.4 Selenium (Se) 49.8 50 99.6ug/L -12080149.8 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16090463 -- 2016030329 Arsenic (As) 51.2 50 102ug/L -12575151.2 Cadmium (Cd) 52.7 50 105ug/L -12575152.7 Chromium (Cr) 53.7 50 106ug/L -12575153.7 Lead (Pb) 52.4 50 105ug/L -12575152.4 Nickel (Ni) 54 50 105ug/L -12575154 Selenium (Se) 55.2 50 110ug/L -12575155.2 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16090463 -- 2016030329 Arsenic (As) 51.3 50 102 0.0987ug/L -12575151.3 Cadmium (Cd) 52.6 50 105 0.206ug/L -12575152.6 Chromium (Cr) 53.8 50 107 0.249ug/L -12575153.8 Lead (Pb) 52.3 50 104 0.238ug/L -12575152.3 Nickel (Ni) 53.9 50 105 0.162ug/L -12575153.9 Selenium (Se) 49.1 50 97.8 11.8ug/L -12575149.1 Duke Energy Analytical Lab Page 29 of 31 B-29 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090463 Q16100418 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16090463 -- 2016030328 TDS 0mg/L -17 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J16090463 -- 2016030329 TDS 10.2mg/L -131 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 100 95mg/L -11090195 Duke Energy Analytical Lab Page 30 of 31 B-30 Duke Energy Analytical Lab Page 31 of 31 B-31 13339 Hagers Ferry RoadHuntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J16090468 Project Name:CLIFFSIDE - GW CCP LANDFILL Lab Contact: Anne Pridgeon Date:11/4/2016 Customer Address:573 Duke Power Rd Customer Name(s):Chuck Campbell, TSH, SEAN DENEALE Mail Code: Clliffside Steam Station Mooresboro, NC 28024 Phone: 980-875-6610 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Anne Pridgeon Page 1 of 8 Reason: I have reviewed this document. Date: 2016.11.04 12:08:15 -04'00' B-32 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016030419 CLIFFSIDE 12-Oct-16 1:00 PM LDC CCPSW-1 2016030425 CLIFFSIDE 12-Oct-16 9:50 AM PSP CCPSW-2 2 Total Samples Page 2 of 8 B-33 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:11/4/2016 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 8 B-34 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090468 2016030419 Collection Date:12-Oct-16 1:00 PM Site:CCPSW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Zinc (Zn)< 0.005 mg/L SW 6010D 10/27/2016 14:07 JJMACKE0.005 1 DISSOLVED METALS BY ICP-MS Cadmium (Cd)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Copper (Cu)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 11/02/2016 15:16 PARMSTR11 Page 4 of 8 B-35 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090468 2016030425 Collection Date:12-Oct-16 9:50 AM Site:CCPSW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Zinc (Zn)< 0.005 mg/L SW 6010D 10/27/2016 14:11 JJMACKE0.005 1 DISSOLVED METALS BY ICP-MS Cadmium (Cd)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Chromium (Cr)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Copper (Cu)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Nickel (Ni)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 11/02/2016 15:39 PARMSTR11 Page 5 of 8 B-36 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090468 Q16100765 ICP Dissolved DISSOLVED METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Zinc (Zn) -0.000012 mg/L -1-0.000012 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Zinc (Zn) 1.02 1 102mg/L -1158511.02 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16100444 -- 2016033545 Zinc (Zn) 4.63 5 92.6mg/L -1307014.63 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16100444 -- 2016033545 Zinc (Zn) 5.11 5 102 9.93mg/L -1307015.11 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J16100482 -- 2016033773 Zinc (Zn) 5.08 5 101mg/L -1307015.08 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J16100482 -- 2016033773 Zinc (Zn) 5.65 5 113 10.6mg/L -1307015.65 Page 6 of 8 B-37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16090468 Q16110086 IMS Dissolved DISSOLVED METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Cadmium (Cd) -0.0004 ug/L -1-0.0004 1 < 1/2 RDL Chromium (Cr) -0.0607 ug/L -1-0.0607 1 < 1/2 RDL Copper (Cu) -0.251 ug/L -1-0.251 1 < 1/2 RDL Lead (Pb) -0.0001 ug/L -1-0.0001 1 < 1/2 RDL Nickel (Ni) -0.0299 ug/L -1-0.0299 1 < 1/2 RDL Silver (Ag) 0.0009 ug/L -10.0009 1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Cadmium (Cd) 8.64 8 108ug/L -1208018.64 Chromium (Cr) 83.4 80 104ug/L -12080183.4 Copper (Cu) 40.3 40 101ug/L -12080140.3 Lead (Pb) 84.4 80 105ug/L -12080184.4 Nickel (Ni) 83.9 80 105ug/L -12080183.9 Silver (Ag) 38.4 40 95.9ug/L -12080138.4 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16090468 -- 2016030419 Cadmium (Cd) 47.9 50 95.8ug/L -12575147.9 Chromium (Cr) 48 50 95.9ug/L -12575148 Copper (Cu) 46.1 50 91.8ug/L -12575146.1 Lead (Pb) 48.6 50 97ug/L -12575148.6 Nickel (Ni) 46.7 50 92.9ug/L -12575146.7 Silver (Ag) 45 50 90ug/L -12575145 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16090468 -- 2016030419 Cadmium (Cd) 48.1 50 96.1 0.334ug/L -13070148.1 Chromium (Cr) 48.1 50 96.2 0.308ug/L -13070148.1 Copper (Cu) 46.1 50 91.9 0.116ug/L -13070146.1 Lead (Pb) 48.6 50 97.2 0.146ug/L -13070148.6 Nickel (Ni) 47.2 50 93.8 0.957ug/L -13070147.2 Silver (Ag) 45.3 50 90.6 0.647ug/L -13070145.3 Page 7 of 8 B-38 Page 8 of 8 B-39 C Appendix C January 3, 2017 Discharge Event Laboratory Report and Chain-of-Custody Form 13339 Hagers Ferry RoadHuntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J17010099 Project Name:Cliffside Landfill Stormwater Lab Contact: Peggy Kendall Date:1/13/2017 Customer Address:573 Duke Power Rd Customer Name(s):Steve Hodges, Zach Hall Mail Code: Clliffside Steam Station Mooresboro, NC 28024 Phone: Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Peggy Kendall Page 1 of 10 Peggggyggygyggygygyygggy KenKenKenKenKenKenKenKeKeeKenedall C-1 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017000418 CLIFFSIDE 03-Jan-17 10:10 AM Brian Kemp Discharge Inlet Structure 2017000419 CLIFFSIDE 03-Jan-17 10:14 AM Brian Kemp Cliffside 001 2017000420 CLIFFSIDE 03-Jan-17 10:17 AM Brian Kemp Cliffside 002 2017000421 CLIFFSIDE 03-Jan-17 10:24 AM Brian Kemp Cliffside 004 2017000422 CLIFFSIDE 03-Jan-17 11:30 AM Brian Kemp Cliffside 005 2017000423 CLIFFSIDE 03-Jan-17 11:42 AM Brian Kemp Cliffside Non Contact 001 6 Total Samples Page 2 of 10 C-2 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:1/13/2017 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 10 C-3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000418 Collection Date:03-Jan-17 10:10 AM Site:Discharge Inlet Structure Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.4 mg/L EPA 300.0 01/10/2017 16:43 BGN90340.1 1 Fluoride 0.17 mg/L EPA 300.0 01/10/2017 16:43 BGN90340.1 1 Nitrate 1.3 mg/L EPA 300.0 01/10/2017 16:43H2 BGN90340.1 1 Nitrate as N 0.29 mg-N/L EPA 300.0 01/10/2017 16:43 BGN90340.023 1 Sulfate 110 mg/L EPA 300.0 01/10/2017 16:43 BGN9034220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:39 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.044 mg/L EPA 200.7 01/12/2017 11:30 JJMACKE0.005 1 Boron (B)0.161 mg/L EPA 200.7 01/12/2017 11:30 JJMACKE0.05 1 Iron (Fe)6.26 mg/L EPA 200.7 01/12/2017 11:30 JJMACKE0.01 1 Manganese (Mn)0.064 mg/L EPA 200.7 01/12/2017 11:30 JJMACKE0.005 1 Zinc (Zn)0.016 mg/L EPA 200.7 01/12/2017 11:30 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Arsenic (As)6.02 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Chromium (Cr)9.34 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Copper (Cu)4.71 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Lead (Pb)3.48 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Nickel (Ni)4.04 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Selenium (Se)3.30 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/12/2017 03:13 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 270 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 61 mg/L SM2540D 01/06/2017 11:00 MGIGANT7.8 1 Page 4 of 10 C-4 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000419 Collection Date:03-Jan-17 10:14 AM Site:Cliffside 001 Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 5.0 mg/L EPA 300.0 01/10/2017 17:00 BGN90340.1 1 Fluoride 0.18 mg/L EPA 300.0 01/10/2017 17:00 BGN90340.1 1 Nitrate 1.5 mg/L EPA 300.0 01/10/2017 17:00H2 BGN90340.1 1 Nitrate as N 0.35 mg-N/L EPA 300.0 01/10/2017 17:00 BGN90340.023 1 Sulfate 120 mg/L EPA 300.0 01/10/2017 17:00 BGN9034220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:41 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.053 mg/L EPA 200.7 01/12/2017 11:34 JJMACKE0.005 1 Boron (B)0.183 mg/L EPA 200.7 01/12/2017 11:34 JJMACKE0.05 1 Iron (Fe)6.52 mg/L EPA 200.7 01/12/2017 11:34 JJMACKE0.01 1 Manganese (Mn)0.075 mg/L EPA 200.7 01/12/2017 11:34 JJMACKE0.005 1 Zinc (Zn)0.018 mg/L EPA 200.7 01/12/2017 11:34 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Arsenic (As)10.1 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Chromium (Cr)10.2 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Copper (Cu)6.98 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Lead (Pb)3.21 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Nickel (Ni)5.96 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Selenium (Se)3.71 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/12/2017 03:21 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 290 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 72 mg/L SM2540D 01/06/2017 11:00 MGIGANT8.9 1 Page 5 of 10 C-5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000420 Collection Date:03-Jan-17 10:17 AM Site:Cliffside 002 Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.0 mg/L EPA 300.0 01/10/2017 17:18 BGN90340.1 1 Fluoride 0.17 mg/L EPA 300.0 01/10/2017 17:18 BGN90340.1 1 Nitrate 0.94 mg/L EPA 300.0 01/10/2017 17:18H2 BGN90340.1 1 Nitrate as N 0.21 mg-N/L EPA 300.0 01/10/2017 17:18 BGN90340.023 1 Sulfate 100 mg/L EPA 300.0 01/10/2017 17:18 BGN9034220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:44 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.059 mg/L EPA 200.7 01/12/2017 11:38 JJMACKE0.005 1 Boron (B)0.186 mg/L EPA 200.7 01/12/2017 11:38 JJMACKE0.05 1 Iron (Fe)8.06 mg/L EPA 200.7 01/12/2017 11:38 JJMACKE0.01 1 Manganese (Mn)0.093 mg/L EPA 200.7 01/12/2017 11:38 JJMACKE0.005 1 Zinc (Zn)0.024 mg/L EPA 200.7 01/12/2017 11:38 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Arsenic (As)13.6 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Chromium (Cr)12.8 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Copper (Cu)9.21 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Lead (Pb)3.80 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Nickel (Ni)7.84 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Selenium (Se)3.85 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN311 Thallium (Tl) Low Level 0.255 ug/L EPA 200.8 01/12/2017 03:28 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 250 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 91 mg/L SM2540D 01/06/2017 11:00 MGIGANT9.8 1 Page 6 of 10 C-6 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000421 Collection Date:03-Jan-17 10:24 AM Site:Cliffside 004 Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 4.2 mg/L EPA 300.0 01/10/2017 15:51 BGN90340.1 1 Fluoride 0.16 mg/L EPA 300.0 01/10/2017 15:51 BGN90340.1 1 Nitrate 2.0 mg/L EPA 300.0 01/10/2017 15:51H2 BGN90340.1 1 Nitrate as N 0.45 mg-N/L EPA 300.0 01/10/2017 15:51 BGN90340.023 1 Sulfate 88 mg/L EPA 300.0 01/10/2017 15:51 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:46 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.042 mg/L EPA 200.7 01/12/2017 11:17 JJMACKE0.005 1 Boron (B)0.135 mg/L EPA 200.7 01/12/2017 11:17 JJMACKE0.05 1 Iron (Fe)6.46 mg/L EPA 200.7 01/12/2017 11:17 JJMACKE0.01 1 Manganese (Mn)0.063 mg/L EPA 200.7 01/12/2017 11:17 JJMACKE0.005 1 Zinc (Zn)0.013 mg/L EPA 200.7 01/12/2017 11:17 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Arsenic (As)5.82 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Chromium (Cr)9.47 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Copper (Cu)4.61 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Lead (Pb)3.70 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Nickel (Ni)3.77 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Selenium (Se)3.00 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/12/2017 03:36 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 240 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 130 mg/L SM2540D 01/06/2017 11:00 MGIGANT161 Page 7 of 10 C-7 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000422 Collection Date:03-Jan-17 11:30 AM Site:Cliffside 005 Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 3.3 mg/L EPA 300.0 01/10/2017 16:08 BGN90340.1 1 Fluoride 0.15 mg/L EPA 300.0 01/10/2017 16:08 BGN90340.1 1 Nitrate 0.36 mg/L EPA 300.0 01/10/2017 16:08H2 BGN90340.1 1 Nitrate as N 0.08 mg-N/L EPA 300.0 01/10/2017 16:08 BGN90340.023 1 Sulfate 46 mg/L EPA 300.0 01/10/2017 16:08 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:48 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.031 mg/L EPA 200.7 01/12/2017 11:42 JJMACKE0.005 1 Boron (B)0.093 mg/L EPA 200.7 01/12/2017 11:42 JJMACKE0.05 1 Iron (Fe)6.48 mg/L EPA 200.7 01/12/2017 11:42 JJMACKE0.01 1 Manganese (Mn)0.049 mg/L EPA 200.7 01/12/2017 11:42 JJMACKE0.005 1 Zinc (Zn)0.007 mg/L EPA 200.7 01/12/2017 11:42 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Arsenic (As)3.76 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Chromium (Cr)9.12 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Copper (Cu)3.27 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Lead (Pb)3.78 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Nickel (Ni)2.79 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Selenium (Se)2.11 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/12/2017 02:42 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 42 mg/L SM2540D 01/06/2017 11:00 MGIGANT5.8 1 Page 8 of 10 C-8 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J17010099 2017000423 Collection Date:03-Jan-17 11:42 AM Site:Cliffside Non Contact 001 Matrix:SURF_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF INORGANIC IONS BY IC Chloride 2.3 mg/L EPA 300.0 01/10/2017 16:25 BGN90340.1 1 Fluoride 0.11 mg/L EPA 300.0 01/10/2017 16:25 BGN90340.1 1 Nitrate 0.24 mg/L EPA 300.0 01/10/2017 16:25H2 BGN90340.1 1 Nitrate as N 0.05 mg-N/L EPA 300.0 01/10/2017 16:25 BGN90340.023 1 Sulfate 35 mg/L EPA 300.0 01/10/2017 16:25 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2017 12:51 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.037 mg/L EPA 200.7 01/12/2017 11:46 JJMACKE0.005 1 Boron (B)0.059 mg/L EPA 200.7 01/12/2017 11:46 JJMACKE0.05 1 Iron (Fe)7.60 mg/L EPA 200.7 01/12/2017 11:46 JJMACKE0.01 1 Manganese (Mn)0.065 mg/L EPA 200.7 01/12/2017 11:46 JJMACKE0.005 1 Zinc (Zn)0.009 mg/L EPA 200.7 01/12/2017 11:46 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Arsenic (As)2.41 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Beryllium (Be)< 1 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Cadmium (Cd)< 1 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Chromium (Cr)8.93 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Copper (Cu)3.31 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Lead (Pb)4.08 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Nickel (Ni)2.78 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Selenium (Se)1.15 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Silver (Ag)< 1 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN311 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/12/2017 04:07 CWSPEN30.2 1 TOTAL DISSOLVED SOLIDS TDS 160 mg/L SM2540C 01/10/2017 15:00 MGIGANT251 TOTAL SUSPENDED SOLIDS TSS 69 mg/L SM2540D 01/06/2017 11:00 MGIGANT9.4 1 Qualifiers: H2 Sample was received and analyzed past holding time. Page 9 of 10 C-9 Page 10 of 10 C-10