7906_DukeDanRiver_Area1CCRRemovalVerification_Cell1_DIN_20170124

Correspondence:
Amec Foster Wheeler
14424 Albemarle Point Place, Suite 115
Chantilly, Virginia 20151
Tel [phone]
Fax [phone]
Licensures: NC Engineering F-1253, Geology C-247

www.amecfw.com

January 23, 2017

Ms. Melonie Martin
Duke Energy Carolinas, LLC
Dan River Steam Station
3195 Pine Hall Road
Belews Creek, North Carolina 27009
[e-mail]

Subject: Coal Combustion Residual (CCR) Visual Removal Verification
Dan River Landfill Construction – Cell 1
Rockingham County, North Carolina
Amec Foster Wheeler Project No.: 7810-16-0623

Dear Ms. Martin:

Amec Foster Wheeler Environment and Infrastructure, Inc. (Amec Foster Wheeler) is pleased to
submit this documentation verifying Dan River Steam Station (Dan River) Landfill Cell 1 coal
combustion residual (CCR) removal by visual methods. We conclude that visual CCR removal
verification criteria has been satisfied in general accordance with Section 3.0 of the Excavation
Soil Sampling Plan for Area 1 Dry Stack, Rev. 0, dated October 2016 (Attachment 1), and as
approved by the North Carolina Department of Environmental Quality (NCDEQ).

Background

Area 1 Dry Stack, also known as Ash Fill 1, is located at Duke Energy’s Dan River Station in
Eden, North Carolina as shown in Figure 1. Construction of Ash Fill 1 occurred in the 1980s.
Ash Fill 1 is approximately 19.7 acres and contains an estimated CCR volume of 800,000 cubic
yards. Duke Energy is currently removing and transporting CCR material from Ash Fill 1 to an
off-site landfill. The majority of the Ash Fill 1 footprint will be within the proposed Dan River
Landfill grading limits. Figure 1 shows an overview of the site.

Field Execution

Field evaluation consisted of conducting a visual evaluation of CCR removal and collection of
samples for testing utilizing polarized light microscopy (PLM) and total metals analysis methods.
Amec Foster Wheeler construction quality assurance (CQA) personnel conducted visual
observations and collected samples between October 18 and October 21, 2016 for PLM and
total metals testing and evaluation.

Visual CCR Removal Verification Results

CCR removal was evaluated based on three criteria:

1. Comparison of estimated bottom of CCR grades to post-CCR removal grades;
2. Visual observation; and
3. PLM evaluation.
CCR Removal Verification January 23, 2017
Dan River Landfill Construction – Cell 1 Amec Foster Wheeler Project No. 7810-16-0623
2

The evaluation results are discussed as follows.

Grade Comparison

The estimated bottom of CCR grades and spot elevations of the post-CCR removal grades are
presented in Figure 2 and summarized in the attached Table 1.

The post-CCR removal grades within the area where proposed Dan River Landfill Cell 2
overlaps Ash Fill 1 are generally at or below the estimated bottom of CCR grades, indicating
that CCR removal has been achieved in accordance with the Excavation Soil Sampling Plan as
approved by NCDEQ.

Visual Evaluation

Visual evaluation of CCR removal was performed on a one-quarter acre grid as shown in Figure
2, the photograph log is included in Attachment 2. CCR material was not observed during the
visual evaluation, indicating that CCR removal has been achieved in accordance with the
Excavation Soil Sampling Plan as approved by NCDEQ.

PLM Evaluation

Sampling at a depth of 2-feet and visual soil classification were conducted on a one-acre grid as
shown in Figure 3 for PLM evaluation. The PLM evaluation was performed by RJ Lee Group,
results are included in Attachment 3. PLM results indicated a percentage of CCR ranging from
not detected to 3 percent. The maximum allowable CCR percentage is 50 percent as described
in the Excavation Soil Sampling Plan as approved by NCDEQ, indicating that CCR removal has
been achieved in accordance with the Plan. The results of a visual soil classification of near-
surface materials is presented in Table 2 and indicates that CCR removal has been achieved in
accordance with the Plan.

Total Metals Evaluation

Sampling at a depth of 6-inches, 2-feet, and 5-feet was conducted on a one-acre grid as shown
in Figure 3 for total metals evaluation. The total metals results are provided in Attachment 4
and summarized in Table 3.

Conclusions

CCR removal verification criteria has been satisfied in general accordance with Section 3.0 of
the Excavation Soil Sampling Plan for Area 1 Dry Stack, Rev. 0, dated October 2016, and as
approved by the NCDEQ.

CCR Removal Verification January 23, 2017
Dan River Landfill Construction – Cell 1 Amec Foster Wheeler Project No. 7810-16-0623
3

Sincerely,

Amec Foster Wheeler Environment & Infrastructure, Inc.

Cedric H. Ruhl, P.E. Chris Jordan, EIT
Senior Engineer Technical Professional
[e-mail] [e-mail]

Attachments:
Table 1 – CCR Removal Grade Comparison
Table 2 – Field Documentation Summary
Table 3 – Laboratory Test Result Summary
Figure 1 – Site Location Map
Figure 2 – CCR Removal Verification – One-Quarter Acre Grid (Visual)
Figure 3 – CCR Removal Verification – One Acre Grid (Sampling)
Attachment 1 – Excavation Soil Sampling Plan for Area 1 Dry Stack
Attachment 2 – Photograph Log
Attachment 3 – Laboratory Test Results – RJ Lee Group
Attachment 4 – Analytical Laboratory Test Results

TABLES

1. CCR Removal Grade Comparison
2. Field Documentation Summary
3. Laboratory Test Result Summary

ZZĞŵŽǀĂů
ĂŶZŝǀĞƌ>ĂŶĚĨŝůůĞůůϭ
WŽŝŶƚ/
ƐƚŝŵĂƚĞĚŽƚƚŽŵ
ŽĨZůĞǀĂƚŝŽŶ
;ĨƚͿ
WŽƐƚͲZZĞŵŽǀĂů
ůĞǀĂƚŝŽŶ
;ĨƚͿ
ůĞǀĂƚŝŽŶ
ŝĨĨĞƌĞŶĐĞϭ
;ĨƚͿ
ϰϱϮϮ ϱϴϳ͘Ϭϭ ϱϴϯ͘Ϯϲ Ͳϯ͘ϳϱ
ϰϱϮϯ ϱϴϳ͘ϴϭ ϱϴϰ͘ϯϬ Ͳϯ͘ϱϮ
ϰϱϮϰ ϱϴϴ͘ϵϮ ϱϳϲ͘ϰϳ ͲϭϮ͘ϰϱ
ϰϱϮϱ ϱϴϮ͘ϰϵ ϱϳϰ͘ϳϳ Ͳϳ͘ϳϮ
ϰϱϯϬ ϱϵϬ͘ϬϬ ϱϴϲ͘ϰϲ Ͳϯ͘ϱϰ
ϰϱϯϮ ϱϵϬ͘ϬϬ ϱϴϲ͘ϯϭ Ͳϯ͘ϲϵ
ϰϱϯϰ ϱϵϬ͘ϬϬ ϱϴϬ͘ϰϲ Ͳϵ͘ϱϰ
ϰϱϯϴ ϱϳϴ͘ϮϬ ϱϳϯ͘ϮϮ Ͳϰ͘ϵϵ
ϰϱϰϬ ϱϳϳ͘Ϯϴ ϱϳϲ͘ϱϵ ͲϬ͘ϲϵ
ϰϱϰϭ ϱϴϲ͘Ϭϵ ϱϴϭ͘ϮϮ Ͳϰ͘ϴϴ
ϰϱϰϮ ϱϳϭ͘ϱϮ ϱϲϵ͘ϯϳ ͲϮ͘ϭϱ
ϰϱϰϯ ϱϲϴ͘ϳϰ ϱϲϱ͘ϲϲ Ͳϯ͘Ϭϴ
ϰϱϰϰ ϱϳϰ͘Ϭϱ ϱϳϭ͘ϳϳ ͲϮ͘Ϯϴ
ϰϱϰϱ ϱϴϬ͘ϱϰ ϱϳϳ͘Ϭϳ Ͳϯ͘ϰϲ
ϰϱϰϲ ϱϴϴ͘Ϭϯ ϱϴϯ͘Ϯϴ Ͳϰ͘ϳϱ
ϰϱϰϳ ϱϴϴ͘ϬϬ ϱϴϱ͘ϳϴ ͲϮ͘ϮϮ
ϰϱϰϴ ϱϴϭ͘ϰϱ ϱϳϴ͘Ϯϰ Ͳϯ͘Ϯϭ
ϰϱϱϬ ϱϳϬ͘ϱϭ ϱϲϲ͘ϴϰ Ͳϯ͘ϲϳ
ϰϱϱϭ ϱϲϴ͘ϴϴ ϱϲϱ͘ϮϮ Ͳϯ͘ϲϲ
ϰϱϱϮ ϱϳϱ͘ϲϭ ϱϲϵ͘ϭϬ Ͳϲ͘ϱϭ
ϰϱϱϯ ϱϳϱ͘ϳϰ ϱϳϲ͘ϱϳ Ϭ͘ϴϯ
ϰϱϱϰ ϱϲϵ͘ϱϭ ϱϲϴ͘ϲϰ ͲϬ͘ϴϳ
ϰϱϱϱ ϱϳϵ͘ϭϲ ϱϴϮ͘ϵϴ ϯ͘ϴϭ
ϰϱϱϲ ϱϴϳ͘ϯϰ ϱϴϱ͘ϵϱ Ͳϭ͘ϯϵ
ϰϱϱϳ ϱϴϲ͘ϬϮ ϱϴϮ͘ϰϴ Ͳϯ͘ϱϱ
ϰϱϱϴ ϱϴϴ͘Ϭϭ ϱϴϯ͘ϳϯ Ͳϰ͘Ϯϴ
ϰϱϱϵ ϱϴϴ͘Ϭϳ ϱϴϯ͘ϱϬ Ͳϰ͘ϱϳ
ϰϱϲϬ ϱϴϴ͘ϳϴ ϱϴϰ͘ϲϭ Ͳϰ͘ϭϴ
ϰϱϲϮ ϱϴϮ͘ϲϲ ϱϴϯ͘ϲϴ ϭ͘ϬϮ
ϰϱϲϯ ϱϴϭ͘ϵϳ ϱϴϲ͘ϲϯ ϰ͘ϲϲ
ϰϱϲϰ ϱϴϯ͘ϭϳ ϱϴϳ͘Ϯϱ ϰ͘Ϭϴ
ϰϱϲϱ ϱϵϳ͘ϴϱ ϱϵϳ͘ϲϵ ͲϬ͘ϭϲ
ϰϱϲϴ ϱϴϰ͘ϬϬ ϱϴϰ͘Ϭϯ Ϭ͘Ϭϯ
ϰϱϲϵ ϱϴϲ͘ϰϮ ϱϴϲ͘Ϯϭ ͲϬ͘Ϯϭ
ϰϱϳϬ ϲϬϬ͘Ϯϰ ϱϵϴ͘ϵϵ Ͳϭ͘Ϯϱ
ϰϱϳϮ ϲϭϭ͘Ϯϱ ϲϭϬ͘ϳϭ ͲϬ͘ϱϰ
ϰϱϳϱ ϲϬϳ͘ϲϮ ϲϬϳ͘ϭϰ ͲϬ͘ϰϴ
ϰϱϳϲ ϲϬϲ͘ϴϴ ϲϬϲ͘Ϭϰ ͲϬ͘ϴϰ
ϰϱϴϰ ϲϮϴ͘ϬϬ ϲϮϴ͘Ϯϱ Ϭ͘Ϯϱ
ϰϱϴϴ ϲϮϴ͘ϬϬ ϲϮϴ͘ϯϳ Ϭ͘ϯϳ
ϭ͘ƉŽƐŝƚŝǀĞŶƵŵďĞƌŝŶĚŝĐĂƚĞƐƚŚĂƚƚŚĞZƌĞŵŽǀĂůŐƌĂĚĞŝƐŚŝŐŚĞƌ
ƚŚĂŶƚŚĞĞƐƚŝŵĂƚĞĚďŽƚƚŽŵŽĨZŐƌĂĚĞ
dĂďůĞϭͲZZĞŵŽǀĂů'ƌĂĚĞŽŵƉĂƌŝƐŽŶ
WŽŝŶƚůŽĐĂƚĞĚŽƵƚƐŝĚĞƐŚ&ŝůůϭ>ŝŵŝƚƐ
WŽŝŶƚůŽĐĂƚĞĚǁŝƚŚŝŶƐŚ&ŝůůϭ>ŝŵŝƚƐ
>ĞŐĞŶĚ
EŽƚĞƐ͗
ZZĞŵŽǀĂů
ĂŶZŝǀĞƌ>ĂŶĚĨŝůůĞůůϭ
^ĂŵƉůĞ
>ŽĐĂƚŝŽŶ ĂƚĞWĞƌĨŽƌŵĞĚ sŝƐƵĂůůĂƐƐŝĨŝĐĂƚŝŽŶ ŽůŽƌ
Ϯ ϭϬͬϮϭͬϮϬϭϲ LJĞůůŽǁƐŝůƚLJůĞĂŶĐůĂLJ LJĞůůŽǁ
ϯ ϭϬͬϮϭͬϮϬϭϲ ƚĂŶƐŝůƚLJůĞĂŶĐůĂLJ ƚĂŶ
ϰ ϭϬͬϮϭͬϮϬϭϲ ǀĞƌLJƐƚŝĨĨƚĂŶƐŝůƚLJĐůĂLJͲĂƵŐĞƌƌĞĨƵƐĂůĂƚϭΖϵΗ ƚĂŶ
ϱ ϭϬͬϭϴͬϮϬϭϲ ǀĞƌLJƐƚŝĨĨLJĞůůŽǁƐŝůƚLJĐůĂLJͲĂƵŐĞƌƌĞĨƵƐĂůĂƚϭΖϴΗ LJĞůůŽǁ
ϲ ϭϬͬϮϬͬϮϬϭϲ ƌĞĚƐŝůƚLJĐůĂLJ ƌĞĚ
ϯ ϭϬͬϮϭͬϮϬϭϲ ůŝŐŚƚƌĞĚƐĂŶĚLJůĞĂŶĐůĂLJ ůŝŐŚƚƌĞĚ
ϰ ϭϬͬϮϬͬϮϬϭϲ ůŝŐŚƚƌĞĚƐĂŶĚLJůĞĂŶĐůĂLJ ůŝŐŚƚƌĞĚ
ϱ ϭϬͬϮϬͬϮϬϭϲ ŚĂƌĚƚĂŶƐĂŶĚͬƐƚŽŶĞͲĂƵŐĞƌƌĞĨƵƐĂůĂƚϵΗ ƚĂŶ
dĂďůĞϮͲ&ŝĞůĚŽĐƵŵĞŶƚŝŽŶ^ƵŵŵĂƌLJ
ZZĞŵŽǀĂů
ĂŶZŝǀĞƌ>ĂŶĚĨŝůůĞůůϭ
'ƌŝĚ/ĞůůϭϮ ĞůůϭϮ͘ϭ ĞůůϭϮ͘Ϯ Ğůůϭϯ Ğůůϭϯ͘ϭ Ğůůϭϯ͘Ϯ Ğůůϭϰ Ğůůϭϰ͘ϭ Ğůůϭϱ Ğůůϭϱ͘ϭ Ğůůϭϲ Ğůůϭϲ͘ϭ Ğůůϭϲ͘Ϯ Ğůůϭϯ Ğůůϭϯ͘ϭ Ğůůϭϯ͘Ϯ Ğůůϭϰ Ğůůϭϰ͘ϭ Ğůůϭϰ͘Ϯ Ğůůϭϱ
^ĂŵƉůĞ/ ϮϬϭϲϬϯϰϯϴϰ ϮϬϭϲϬϯϰϯϴϱ ϮϬϭϲϬϯϰϯϴϲ ϮϬϭϲϬϯϰϯϳϴ ϮϬϭϲϬϯϰϯϳϵ ϮϬϭϲϬϯϰϯϴϬ ϮϬϭϲϬϯϰϯϳϲ ϮϬϭϲϬϯϰϯϳϳ ϮϬϭϲϬϯϰϯϱϯ ϮϬϭϲϬϯϰϯϲϴ ϮϬϭϲϬϯϰϯϳϬ ϮϬϭϲϬϯϰϯϳϭ ϮϬϭϲϬϯϰϯϳϮ ϮϬϭϲϬϯϰϯϴϭ ϮϬϭϲϬϯϰϯϴϮ ϮϬϭϲϬϯϰϯϴϯ ϮϬϭϲϬϯϰϯϳϯ ϮϬϭϲϬϯϰϯϳϰ ϮϬϭϲϬϯϰϯϳϱ ϮϬϭϲϬϯϰϯϲϵ
^ĂŵƉůŝŶŐĂƚĞƐ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϭϴͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϭͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ ϭϬͬϮϬͬϮϬϭϲ
^ĂŵƉůĞĞƉƚŚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϱͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϱͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϱͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϱͲĨĞĞƚ ϲͲŝŶĐŚĞƐ ϮͲĨĞĞƚ ϱͲĨĞĞƚ ϲͲŝŶĐŚĞƐ
йĨůLJĂƐŚ ϯйEEϭйEEEEEEEEEEEEEEEE
ůƵŵŝŶƵŵ ŵŐͬŬŐ ϭϯϴϬϬ ϭϰϳϬϬ ϮϭϬϬϬ ϭϵϳϬϬ ϯϬϰϬϬ ϯϳϬϬϬ ϰϴϵϬϬ ϯϱϳϬϬ ϭϱϳϬϬ ϭϲϬϬϬ ϭϳϵϬϬ͘Ϭ ϮϯϯϬϬ ϭϵϬϬϬ ϭϲϮϬϬ ϭϭϵϬϬ ϭϳϲϬϬ ϯϴϴϬϬ ϮϰϰϬϬ ϭϲϵϬϬ ϭϯϮϬϬ
ĂƌŝƵŵ ŵŐͬŬŐ ϭϮϯ ϭϭϬ ϴϳ͘ϭ ϭϬϮ ϭϮϯ ϵϰ ϮϭϮ Ϯϯϳ ϳϭ͘ϳ ϴϱ͘ϭ ϲϯ͘ϵ ϰϭ͘ϱ ϳϳ͘ϯ ϵϵ͘ϯ ϴϲ͘ϱ ϵϯ͘ϭ ϮϮϮ ϮϳϬ ϭϮϬ ϳϲ͘ϳ
ĞƌLJůůŝƵŵ ŵŐͬŬŐ Ϭ͘ϱ Ϭ͘ϲϲ Ϭ͘ϲϴ ϭ͘ϭ ϭ͘ϰ ϭ͘ϱ ϭ͘ϳ ϭ͘ϱ Ϭ͘ϱϴ Ϭ͘ϳ Ϭ͘ϳϱ Ϭ͘ϯ ϮϭϬ͘ϵ Ϭ͘ϴϴ Ϯ͘Ϯ Ϯ Ϭ͘ϰϳ Ϭ͘ϲϳ
ŽƌŽŶ ŵŐͬŬŐ EE E EEE EE EEEEE EE E EEE E
ĂůĐŝƵŵ ŵŐͬŬŐ ϴϳϰ ϵϱϲ ϰϲϭ ϰϮϵ ϭϮϲ ϳϭ͘ϳ ϭϰϴϬ ϭϵ͘Ϯ ϰϴϰ ϲϮϵ͘Ϭ ϭϴϮ ϯϰϴ ϭϴϲϬ ϭϬϬϬ ϮϬϳϬ ϰϰϵ ϭϴϯϬ ϭϲϳϬ ϭϬϮϬ ϰϴϲ͘Ϭ
ŚƌŽŵŝƵŵ ŵŐͬŬŐ ϭϰ͘ϰ ϭϮ͘ϵ ϭϰ͘ϴ Ϯϯ͘ϴ ϯϱ͘Ϯ ϰϮ͘ϭ ϰϭ͘ϰ ϰϮ͘Ϯ ϭϰ͘ϵ ϭϯ͘ϭ ϮϬ͘ϵ ϭϵ ϭϴ͘ϲ ϭϳ͘ϲ ϭϰ͘ϵ ϭϱ͘ϵ ϯϰ͘Ϯ ϯϰ͘ϵ ϭϳ͘Ϯ ϵ͘ϵ
ŽƉƉĞƌ ŵŐͬŬŐ ϭϴ͘Ϯ ϭϲ͘ϱ ϭϵ͘ϱ ϯϭ͘ϵ ϱϬ͘ϲ ϲϭ͘ϳ ϳϮ ϱϬ͘ϴ Ϯϱ͘ϲ ϭϮ͘ϰ ϭϰ͘Ϯ ϭϴ͘ϴ ϯϮ͘ϲ Ϯϯ͘ϴ Ϯϭ͘ϲ ϮϬ͘ϱ ϳϴ͘ϰ ϲϱ͘Ϯ ϭϮ͘ϱ ϭϱ͘ϯ
/ƌŽŶ ŵŐͬŬŐ ϭϴϭϬϬ ϮϭϱϬϬ ϮϰϲϬϬ ϯϴϮϬϬ ϱϮϬϬϬ ϱϴϵϬϬ ϰϵϰϬϬ ϰϵϴϬϬ ϮϱϯϬϬ ϯϯϲϬϬ ϯϭϭϬϬ ϯϯϳϬϬ ϯϰϵϬϬ ϮϴϯϬϬ ϯϬϱϬϬ ϯϬϵϬϬ ϱϭϱϬϬ ϰϯϭϬϬ ϭϲϵϬϬ ϮϮϳϬϬ
DĂŐŶĞƐŝƵŵ ŵŐͬŬŐ ϭϱϯϬ ϮϬϬϬ ϭϮϰϬ ϮϬϮϬ ϰϮϵϬ ϱϭϱϬ ϵϰϱϬ ϭϬϴϬϬ ϯϰϳϬ ϰϬϬϬ ϭϬϵϬ ϮϬϴϬ ϱϭϳϬ ϭϵϯϬ ϭϱϴϬ ϭϲϵϬ ϳϬϬϬ ϳϮϰϬ ϮϵϱϬ ϮϮϴϬ
DĂŶŐĂŶĞƐĞ ŵŐͬŬŐ ϱϭϬ ϰϰϱ ϭϰϬ ϱϮϲ ϱϰϬ ϯϰϬ ϭϭϭϬ ϭϮϰϬ ϱϱ ϭϬϯ ϮϰϱϬ Ϯϲ͘ϱ ϮϬϴ ϱϮϲ ϯϭϳ ϰϰϬ ϭϬϬϬ ϭϮϱϬ ϵϱ͘ϰ ϯϬϱ
DŽůLJďĚĞŶƵŵ ŵŐͬŬŐ EϬ͘ϲϰ Ϭ͘ϳϱ ϭ͘ϲ ϭ͘ϱ ϭ͘ϱ Ϯ͘ϰ ϱ͘ϰ Ϭ͘ϴ Ϭ͘ϴϳ Ϯ͘ϰ Ϯ͘ϭ ϭϬ͘ϳϬ͘ϱϵ Ϭ͘ϴϯ ϯ͘Ϯ ϱ͘ϳ Ϭ͘ϵ E
EŝĐŬĞů ŵŐͬŬŐ ϵ͘ϴ ϭϬ͘ϱ ϲ͘ϵ ϭϭ͘ϳ ϭϵ͘ϲ Ϯϭ͘ϴ Ϯϴ͘ϳ ϯϭ͘ϲ ϭϭ͘ϱ ϭϵ͘ϭ ϴ ϲ͘Ϯ ϭϲ͘ϲ ϭϮ͘ϯ ϭϬ ϭϬ͘ϯ Ϯϲ͘ϳ Ϯϱ͘ϱ ϭϭ͘Ϯ ϭϮ͘ϱ
WŽƚĂƐƐŝƵŵ ŵŐͬŬŐ ϴϲϴ ϭϭϬϬ ϭϬϴϬ ϭϯϲϬ ϭϴϳϬ ϮϲϲϬ ϯϬϴϬ ϮϬϭϬ ϭϱϳϬ͘Ϭ ϲϱϬ ϲϲϮ ϭϬϮϬ ϭϬϵϬ ϭϰϯϬ ϭϬϮϬ ϭϬϴϬ ϮϰϴϬ ϯϮϯϬ ϰϴϭ ϴϮϰ
^ŝůǀĞƌ ŵŐͬŬŐ EϬ͘ϰϱ Ϭ͘ϲϴ ϭ͘ϭ ϭ͘ϴ Ϯ͘ϯ Eϭ͘ϳ Ϭ͘ϱϰ Ϭ͘ϱϱ Ϭ͘ϴϴ ϭ E EE Ϭ͘ϳϯ EEϬ͘ϰϵ Ϭ͘ϰϲ
^ŽĚŝƵŵ ŵŐͬŬŐ EE E EEE ϭϯϬ ϭϴϭ ϭϲϯ ϭϴϴ Eϭϴϱ E EE E ϭϬϴ ϭϵϰ ϮϮϱ ϳϲ͘ϴ
^ƚƌŽŶƚŝƵŵ ŵŐͬŬŐ ϭϮ͘ϲ ϭϳ͘ϰ ϭϮ͘Ϯ ϭϭ͘ϭ ϭϲ͘Ϯ ϲ͘ϭ Ϯϳ͘Ϯ ϯϭ͘ϰ ϭϰ͘ϯ ϭϴ͘ϭ ϭϰ͘ϴ ϭϲ͘ϳ ϯϮ͘ϵ ϭϰ͘ϵ ϮϮ͘ϰ ϵ ϯϮ͘ϲ ϯϭ͘ϯ ϮϬ͘ϴ ϭϰ͘ϯ
ŝŶĐ ŵŐͬŬŐ Ϯϵ͘ϴ ϯϴ͘ϲ Ϯϳ͘ϭ ϰϲ͘ϭ ϲϵ͘ϰ ϴϮ͘ϳ ϭϬϮ ϵϲ͘ϰ ϱϬ͘Ϭ ϰϳ͘ϴϬ ϯϮ͘ϲ Ϯϲ͘ϰ ϰϲ ϰϲ͘ϲ ϯϯ͘Ϯ ϯϴ͘ϭ ϴϰ͘ϲ ϭϮϬ Ϯϳ͘ϴ ϯϳ͘Ϯ
ŶƚŝŵŽŶLJ ŵŐͬŬŐ EE E EEE EE EEEEE EE E EEE E
ƌƐĞŶŝĐ ŵŐͬŬŐ Eϭ͘ϱ E ϱ ϱ͘ϯ ϰ͘ϱ ϱ͘ϲ ϱ͘ϱ Eϭ͘ϰ ϳ͘Ϯ ϱ͘ϯ ϯ͘ϴ ϭ͘ϴ E E ϮϬ͘ϯ ϳ͘ϵ Ϯ͘ϵ ϭ͘ϯ
ĂĚŵŝƵŵ ŵŐͬŬŐ EE E EEE EE EEEEE EE E EEE E
ŽďĂůƚ ŵŐͬŬŐ ϭϬ͘ϲ ϭϬ͘ϱ ϲ͘ϯ ϭϰ͘ϰ ϭϮ͘ϴ ϭϯ͘ϴ ϰϮ͘Ϯ Ϯϱ͘ϵ ϳ͘Ϭ ϴ͘ϰ ϳϵ͘ϭ ϯ Ϯϴ͘Ϯ ϭϯ͘ϳ ϭϭ͘ϲ ϭϮ͘ϰ Ϯϲ͘ϵ ϯϵ͘ϱ ϰ͘ϵ ϭϯ͘ϱ
>ĞĂĚ ŵŐͬŬŐ ϭϲ͘Ϯ ϭϰ͘ϴ ϭϰ͘ϲ ϭϯ͘ϴ ϭϱ͘Ϯ ϭϱ͘ϲ Ϯϲ͘ϰ ϭϵ͘ϭ ϭϰ͘Ϭ ϭϳ ϯϵ ϭϮ͘ϲ ϭϱ͘ϳ ϮϮ͘ϲ ϭϴ͘ϵ ϮϬ͘ϳ Ϯϱ͘ϯ ϯϬ͘ϯ ϵ͘ϵ ϭϭ͘ϳ
^ĞůĞŶŝƵŵ ŵŐͬŬŐ Eϭ͘ϰ E ϭ͘ϰ ϭ͘ϳ ϭ͘ϱ Ϯ͘ϭ Ϯ͘ϴ Ϯ͘ϳ ϭ͘ϵ EEϯ͘ϲ ϭ͘ϳ E E EϮ͘ϱ E ϭ͘ϰ
dŚĂůůŝƵŵ ŵŐͬŬŐ EE E EEE EE EEEEE EE E EEE E
sĂŶĂĚŝƵŵ ŵŐͬŬŐ Ϯϱ͘Ϯ Ϯϱ͘ϰ ϯϴ͘ϯ ϯϵ͘ϲ ϰϰ͘ϴ ϱϲ͘ϭ ϱϯ͘ϭ ϲϲ͘ϱ Ϯϴ͘Ϭ Ϯϲ͘Ϯ ϰϮ ϰϱ͘ϱ ϯϲ͘Ϯ Ϯϵ͘ϲ ϯϬ͘ϲ ϯϬ͘ϰ ϱϰ͘ϲ ϯϵ͘Ϯ Ϯϳ͘ϰ Ϯϭ͘ϰ
Wϳϰϳϭ DĞƌĐƵƌLJ ŵŐͬŬŐ Ϭ͘Ϭϭϵ Ϭ͘ϬϮϯ Ϭ͘ϬϮϮ Ϭ͘ϬϮϮ Ϭ͘ϬϮϮ Ϭ͘ϬϮϲ Ϭ͘Ϭϱϯ Ϭ͘Ϭϭϴ E E Ϭ͘Ϭϰϱ Ϭ͘Ϭϯϭ E Ϭ͘Ϭϭϲ Ϭ͘ϬϭϮ Ϭ͘Ϭϭϰ Ϭ͘ϬϮϱ Ϭ͘ϬϮϭ E E
^dDϮϵϳϰͲϴϳ WĞƌĐĞŶƚDŽŝƐƚƵƌĞ й ϵ͘ϯ ϵ͘ϳ ϭϲ͘ϵ ϭϱ͘ϳ ϭϵ͘ϭ ϭϵ͘Ϯ ϮϮ͘ϯ ϭϱ͘ϳ ϵ͘ϴ ϭϬ͘Ϯ ϭϮ͘ϯ ϭϳ͘ϴ ϭϵ͘ϴ ϭϯ͘ϴ ϭϯ͘ϯ ϭϰ͘ϳ ϭϵ͘ϱ ϮϬ͘ϰ ϭϯ͘Ϯ ϭϮ͘ϱ
WϵϬϰϱ Ɖ,ĂƚϮϱĞŐƌĞĞƐ ^ƚĚ͘hŶŝƚƐ ϰ͘ϳ ϱ͘ϯ ϱ͘ϱ ϱ͘ϱ ϱ͘ϯ ϱ͘ϯ ϲ͘ϱ ϲ͘ϲ ϱ͘ϵ ϳ͘ϰ ϱ͘ϲ ϱ͘ϱ ϱ͘ϯ ϱ͘ϱ ϴ͘ϭ ϱ ϴ͘ϯ ϲ͘ϭ ϳ ϲ͘Ϯ
WϳϭϵϵŚƌŽŵŝƵŵ͕,ĞdžĂǀĂůĞŶƚŵŐͬŬŐ EEEEEEEEEEϬ͘ϵEEEEEEEEE
ŚůŽƌŝĚĞŵŐͬŬŐ EEEEEEEEEEEEEEEEEEEE
^ƵůĨĂƚĞ ŵŐͬŬŐ ϳϮϵ ϵϯ͘ϲ ϳϱ͘ϯ E E E E E E E E ϵϱ͘ϯ E E E ϴϮ E E E E
EŝƚƌĂƚĞĂƐEŵŐͬŬŐ EEEEEEEEEEEEEEEEEEEE
EdсŶŽƚƚĞƐƚĞĚ
EсŶŽƚĚĞƚĞĐƚĞĚ
dĞƐƚDĞƚŚŽĚ hŶŝƚƐ
dĂďůĞϯͲ>ĂďŽƌĂƚŽƌLJdĞƐƚZĞƐƵůƚ^ƵŵŵĂƌLJ
WĂƌĂŵĞƚĞƌ
WϲϬϭϬ
WϲϬϮϬ
WϵϬϱϲ
ĨůLJĂƐŚĚĞƚĞƌŵŝŶĂƚŝŽŶďLJW>D

FIGURES

1. Site Location Map
2. CCR Removal Verification – One-Quarter Acre Grid (Visual)
3. CCR Removal Verification – One Acre Grid (Sampling)

)*
1
PR
O
J
E
C
T

N
O
:
FI
G
U
R
E

N
O
:
78
1
0
-
1
6
-
0
6
2
3
02,000 1,000

F
e
e
t
NO
T
E
:

T
H
I
S

F
I
G
U
R
E

I
S

F
O
R

R
E
F
E
R
E
N
C
E

O
N
L
Y
.

DA
N

R
I
V
E
R

S
T
E
A
M

S
T
A
T
I
O
N
RO
C
K
I
N
G
H
A
M

C
O
U
N
T
Y
,

N
O
R
T
H

C
A
R
O
L
I
N
A
SI
T
E

L
O
C
A
T
I
O
N

M
A
P
DA
N

R
I
V
E
R

L
A
N
D
F
I
L
L

C
O
N
S
T
R
U
C
T
I
O
N
F:
\
A
M
E
C
_
P
r
o
j
e
c
t
s
\
2
0
1
6
\
7
8
1
0
-
1
6
-
0
6
2
3

D
a
n

R
i
v
e
r
\
G
I
S
\
M
X
D
s
\
F
i
g
u
r
e
1
_
S
i
t
e
L
o
c
a
t
i
o
n
M
a
p
.
m
x
d
,

U
s
e
r
:

m
a
d
d
i
s
o
n
.
s
u
t
t
o
n
;

C
h
e
c
k
e
d

b
y
:

C
R
;

D
a
t
e
:
1
/
2
3
/
2
0
1
7
)*
¯
Se
r
v
i
c
e

L
a
y
e
r

C
r
e
d
i
t
s
:

S
o
u
r
c
e
s
:

E
s
r
i
,

H
E
R
E
,

D
e
L
o
r
m
e
,

U
S
G
S
,

I
n
t
e
r
m
a
p
,

i
n
c
r
e
m
e
n
t

P

C
o
r
p
.
,

N
R
C
A
N
,

E
s
r
i

J
a
p
a
n
,

M
E
T
I
,

E
s
r
i

C
h
i
n
a

(
H
o
ng
Ko
n
g
)
,

E
s
r
i

(
T
h
a
i
l
a
n
d
)
,

M
a
p
m
y
I
n
d
i
a
,

©

O
p
e
n
S
t
r
e
e
t
M
a
p

c
o
n
t
r
i
b
u
t
o
r
s
,

a
n
d

t
h
e

G
I
S

U
s
e
r

C
o
m
m
u
n
i
t
y
Co
p
y
r
i
g
h
t
:
©

2
0
1
3

N
a
t
i
o
n
a
l

G
e
o
g
r
a
p
h
i
c

S
o
c
i
e
t
y
,

i
-
c
u
b
e
d
AS
H

F
I
L
L

1
AS
H

F
I
L
L

2
PR
I
M
A
R
Y

AS
H

B
A
S
I
N
SE
C
O
N
D
A
R
Y
AS
H

B
A
S
I
N
CE
L
L

1
LE
G
E
N
D
)*
DA
N

R
I
V
E
R

S
T
E
A
M

S
T
A
T
I
O
N
AP
P
R
O
X
I
M
A
T
E

C
C
R

B
O
U
N
D
A
R
Y
AP
P
R
O
X
I
M
A
T
E

D
U
K
E

E
N
E
R
G
Y

P
R
O
P
E
R
T
Y

B
O
U
N
D
A
R
Y
AP
P
R
O
X
I
M
A
T
E

C
E
L
L

1

B
O
U
N
D
A
R
Y
LEGEND EXISTING MAJOR CONTOUR (10')EXISTING MINOR CONTOUR (2')ASH FILL 1 LIMITS CELL 1 GRADING LIMITS CELL 2 GRADING LIMITS CELL 3 GRADING LIMITS PROPOSED LANDFILL LIMIT OF WASTE ASH EXCAVATION SURVEY POINTN NOT FOR CONSTRUCTIONNC GEOLOGY: C-247NC ENG: F-1253LICENSURE:FAX: [phone]TEL: [phone]CHARLOTTE, NC 28208SUITE 1002801 YORKMONT ROAD 11/4/20167810-16-0623DWGAS SHOWN CHRCHRKRDCSJCSJ 2 QUARTER ACRE GRID (VISUAL).dwg0 02 2NOT FOR CONSTRUCTIONONE-QUARTER ACRE GRID (VISUAL)DAN RIVER STEAM STATIONCCR REMOVAL VISUAL VERIFICATION
0

1
1
/
4
/
2
0
1
6

7
8
1
0
-
1
6
-
0
6
2
3

C
O
N
S
T
R
U
C
T
I
O
N

C
S
J

C
S
J

K
R
D

C
H
R

C
C
R

V
I
S
U
A
L

R
E
M
O
V
A
L

V
E
R
I
F
I
C
A
T
I
O
N

0 2
10
20
30
TE
N
T
H
S
IN
C
H
E
S
12
3
DWG SIZE REVISIONFOR FIGURE NO.TITLE FILENAME:DWG TYPE:JOB NO:DATE:SCALE:

D
E
S
:
DFTR:CHKD:ENGR:APPD:
A FEDCB
23
4
5
78
6
45
78910
6
A FCB 22"x34"ANSI DEnvironment &Infrastructure SEAL
RE
V
DA
T
E

J
O
B

N
O
.

P
R
O
J
E
C
T

T
Y
P
E

D
E
S

D
F
T
R

C
H
K
D

E
N
G
R

D
E
S
C
R
I
P
T
I
O
N
AB
S
A
T

I
S
S
U
E

#
DA
T
E

D
E
S
I
G
N
A5
A6
B4
A4
A3
B3
A2
B5
LEGEND EXISTING MAJOR CONTOUR (10')EXISTING MINOR CONTOUR (2')ASH FILL 1 LIMITS CELL 1 GRADING LIMITS CELL 2 GRADING LIMITS CELL 3 GRADING LIMITS PROPOSED LANDFILL LIMIT OF WASTE ANALYTICAL SAMPLE POINTN NOT FOR CONSTRUCTIONNC GEOLOGY: C-247NC ENG: F-1253LICENSURE:FAX: [phone]TEL: [phone]CHARLOTTE, NC 28208SUITE 1002801 YORKMONT ROAD 11/4/20167810-16-0623DWGAS SHOWN CHRCHRKRDCSJCSJ 3 ONE ACRE GRID (SAMPLING).dwg0 03 3NOT FOR CONSTRUCTIONONE ACRE GRID (SAMPLING)DAN RIVER STEAM STATIONCCR REMOVAL VISUAL VERIFICATION
0

1
1
/
4
/
2
0
1
6

7
8
1
0
-
1
6
-
0
6
2
3

C
O
N
S
T
R
U
C
T
I
O
N

C
S
J

C
S
J

K
R
D

C
H
R

C
C
R

V
I
S
U
A
L

R
E
M
O
V
A
L

V
E
R
I
F
I
C
A
T
I
O
N

0 3
10

2
0
30
TE
N
T
H
S
IN
C
H
E
S
12
3
DWG SIZE REVISIONFOR FIGURE NO.TITLE FILENAME:DWG TYPE:JOB NO:DATE:SCALE:

D
E
S
:
DFTR:CHKD:ENGR:APPD:
A FEDCB
23
4
5
78
6
45
78910
6
A FCB 22"x34"ANSI DEnvironment &Infrastructure SEAL
RE
V
DA
T
E

J
O
B

N
O
.

P
R
O
J
E
C
T

T
Y
P
E

D
E
S

D
F
T
R

C
H
K
D

E
N
G
R

D
E
S
C
R
I
P
T
I
O
N
AB
S
A
T

I
S
S
U
E

#
DA
T
E

D
E
S
I
G
N

ATTACHMENT 1

Excavation Soil Sampling Plan for Area 1 Dry Stack

EXCAVATION SOIL SAMPLING PLAN
FOR AREA 1 DRY STACK
DUKE ENERGY DAN RIVER STEAM STATION
DUKE ENERGY CAROLINAS, LLC.
526 SOUTH CHURCH STREET/EC13K
CHARLOTTE, NORTH CAROLINA 28202

Waste & Groundwater Programs
Revision 0
October 2016

Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page i
TABLE OF CONTENTS
SECTION PAGE
1.0 PURPOSE ................................................................................................................................1
2.0 SOIL SAMPLING METHODOLOGY .............................................................................................1
2.1 Method Summary 1
2.1.1 Equipment 1
2.1.2 Sample Locations 2
2.1.3 Collection of Representative Samples 2
2.1.4 Sample Preservation, Containers, Handling and Storage 3
2.1.5 Decontamination 4
3.0 VISUAL CONFIRMATION OF ASH REMOVAL ..............................................................................4
3.1 Pre-Excavation Documentation 4
3.2 Ash Removal Verification Protocol 4
3.2.1 Field Documentation 5
3.2.2 Fill Evaluation Criteria 5
3.3 Visual Removal Not Applicable 6
4.0 SOIL SAMPLING AND ANALYSIS ...............................................................................................6
4.1 Soil Sampling 6
4.1.1 Scenario 1 6
4.1.2 Scenario 2 7
4.2 Fate and Transport Modeling 7

LIST OF TABLES
Table 1 - Soil Parameters and Analytical Methods

Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 1
1.0 PURPOSE
The purpose of this Excavation Soil Sampling Plan is to provide a standardized method for collecting soil
samples at Duke Energy Dan River Steam Station Area 1 Dry Stack. Soil samples are being collected to
verify removal of CCR material per the NCDEQ Guidance (DIN 26815) provided on October 11, 2016.
This Excavation Soil Sampling Plan is applicable to the collection of representative soil samples. Analysis
of soil samples may be chemical or physical in nature and may be used to determine the following:
x Extent and magnitude of constituent occurrence
x Input concentrations for groundwater fate and transport model
The methodologies discussed in this Excavation Soil Sampling Plan are applicable to the sampling of soil
in the Area 1 Dry Stack at Dan River Steam Station. For the purposes of this plan, soils are those mineral
and organic materials remaining (above bedrock and above the groundwater surface) after all visible ash
has been excavated.
2.0 SOIL SAMPLING METHODOLOGY
2.1 Method Summary
This Excavation Soil Sampling Plan has been adapted from Environmental Protection Agency (EPA)
Standard Operating Procedures (SOPs) #2012 and #2006; and North Carolina Department of
Environmental Quality (DEQ) Attachment 1 Coal Combustion Residuals Surface Impoundment Closure
Guidelines for Protection of Groundwater, September 2016.

Soil samples are collected directly using stainless steel or plastic trowel, spade, shovel, or scoops.
Following collection, soil is transferred from the sampling device to a stainless steel or plastic bowl to be
homogenized. Once homogenized, the soil is transferred into Duke Energy Laboratory supplied sample
bottles.
Soil samples will be submitted for total metals analysis. Analytical methods for total metals are
described in Table 1. CCR material presence is quantitatively determined by polarized light microscopy
(PLM) by RJ Lee Laboratory (or other approved vendor). PLM analysis passes visible light through a pair
of polarizing filters to create optical effects used in identifying unknown materials. This method is
commonly used in asbestos and coal ash identification.
2.1.1 Equipment
x Stainless steel or plastic trowel, scoop, spade or shovel – used for collecting soil samples
from surface locations.
x Sample containers – To be supplied by Duke Energy Laboratory with appropriate
cooler(s). Estimated that 5-8 ounce samples bottles with Teflon-lined lids will be
required for each sample location and sample depth. For return of cooler to the lab, ice
will be required.
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 2
x Gloves – used for personal protection and to prevent cross-contamination of samples –
nitrile, disposable, powderless.
x Field clothing and Personal Protective Equipment – used as specified in the site Health
and Safety Plan.
x Sampling flags – used for identifying soil sampling locations.
x Field notebook – a bound book used to record progress of sampling effort and record
any problems and field observations during sampling.
x Three-ring binder book – used to store necessary forms and record and track samples
collected at the site.
x Permanent marking pen – used to label sample containers, document field logbooks and
data sheets.
x Stainless steel or plastic spoon – used for homogenizing soil samples within a stainless
steel or plastic bowl.
x Stainless steel or plastic bowl – used for homogenizing soil samples, when applicable.
x Camera – used for photo-documentation of sample locations and samples.
x GPS – device used to obtain elevation, latitude and longitude of sample location.
x Trash bag – used to dispose of gloves and any other non-hazardous waste generated
during sampling.
x Decontamination supplies and equipment.
2.1.2 Sample Locations
General locations for soil sampling are determined by the soil scientist in the field at a rate of
one soil sample for every 1 acre of area excavated. Actual sampling locations on-site may vary
to account for site conditions and to allow collection of representative samples. Collection of
Representative Samples
For the purpose of this plan, surface soil is considered to range from 0 to 6 inches in depth while
deeper samples are considered to two feet below ground surface (unless bedrock, refusal, or
the water table are encountered). A surface soil sample and deeper samples will be collected at
each location for every 1 acre of area excavated. A new pair of nitrile gloves is worn at each
sampling location and each depth. Each sampling location is recorded on the site map prior to
collecting the sample if location is not already noted on the map. The GPS location of each
sampling location (i.e. elevation, latitude and longitude), sample descriptions, and area
photographs are also recorded. All sampling and homogenizing equipment is decontaminated
prior to use irrespective of depth. The following procedure will be used to collect representative
soil samples with a scoop, shovel, or trowel:
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 3
x Locate general sampling locations.
x Determine suitability of sampling location for a representative sample.
x If sampling location appears to reflect conditions that are representative of the
subject grid cell, proceed with sampling procedure. If location is not
representative of the grid cell, notify the project manager so an alternate
location can be identified.
x Using a decontaminated sampling instrument, remove the desired thickness and
volume of soil from the sampling area. Will require enough soil to fill five 8-
ounce sample bottles.
x Transfer the sample into an appropriate sample or homogenization bowl. Non-
dedicated containers should be adequately decontaminated. Stir for
approximately one minute until there appears to be a uniform color and
consistency.
x Transfer homogenized sample to a labeled container(s) of appropriate size and
construction for the analyses requested.
x Secure sample container tightly.
2.1.3 Sample Preservation, Containers, Handling and Storage
Chemical preservation of soils is generally not recommended. Cooling to 4oC on wet ice is
usually the best approach, supplemented by the appropriate holding time for the analyses
requested.
The Duke Energy Laboratory will supply the appropriate sample bottles for the collected soil
samples. The sample volume is a function of the analytical requirements and the Duke Energy
Laboratory will ensure the appropriate number of bottles is supplied.
Table 1 contains a list of parameters to be analyzed with corresponding reporting units and
analytical methods. If a parameter or group of parameters is not included in Table 1, the
laboratory performing the analysis should be contacted to determine the appropriate sample
bottles, volumes, and preservatives.
All non-dedicated sampling/homogenizing devices should be decontaminated and wrapped in
plastic. The sampling device should remain in this wrapping until it is needed. Each
sampling/homogenizing device should be used for only one sample and then decontaminated or
disposed of. Non dedicated sampling/homogenizing devices should be cleaned in the field using
the decontamination procedure described below.
2.1.4 Decontamination
Decontamination procedures can be time consuming; having a sufficient quantity of sampling
tools available is recommended. All non-dedicated sampling/homogenizing equipment must be
decontaminated prior to reuse. Equipment decontamination consists of:
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 4
1. Detergent wash and brush cleaning
2. Tap water rinse
3. Deionized water rinse
4. Air dry
5. Wrap sampling tools with plastic
3.0 VISUAL CONFIRMATION OF ASH REMOVAL
3.1 Pre-Excavation Documentation
Closure by removal is defined herein as removing the primary source (primary source of potential
constituents of interest) to the point that CCR material is not visible to the unaided eye at the ground
surface. This method is intended solely to verify and document CCR material removal and is not
intended to validate environmental quality standards of the subsurface (considered the secondary
source of potential constituents of interest). Pre-excavation documentation would consist of:

x Review topographic mapping, aerial photography, construction drawings, and boring logs to
estimate the pre-CCR placement topography and/or CCR/soil interface

x Preparation of a figure illustrating a grid spacing of 100 feet. Each grid point (node) will be
assigned a unique identifier. Each node of the grid spacing (grid point) will represent a visual
verification location.

3.2 CCR Material Removal Verification Protocol
CCR material excavation will be considered complete based on visual confirmation that all CCR material
has been removed. CCR material removal will be based on sampling of the CCR/soil interface and
analysis by PLM. Soil samples will be examined utilizing methods outlined in American Society for
Testing and Materials (ASTM) D2488, Standard Practice for Description and Identification of Soils (Visual-
Manual Procedure). Vertical and horizontal excavation of CCR material can terminate when the
remaining material can be documented using PLM to contain less than 50% CCR.

Project will excavate CCR material until a visible change in color or texture confirms removal. This
location shall be referred to as the CCR/soil interface. If visual evaluation is inconclusive, then request
additional evaluation to confirm CCR removal.
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 5
3.2.1 Field Documentation
Evaluate the excavated surface elevation relative to the pre-CCR placement topography.
Periodically check bottom elevation to evaluate if fill is present above historic bottom elevation.
Visual confirmation will be performed on a 100 foot grid system. Soil sampling will be
performed on an acre grid system and will be analyzed using PLM.

x Personnel will locate each node by GPS or survey control, determine elevation and
evaluate whether that point is above or below the historic bottom elevation.

x Personnel will then observe the surface area represented by the node to note if visible
CCR is present at the surface. If present, the location should be documented and
excavation will need to continue. If the evaluation indicates the surface soils are
residuum or bedrock, then hand auger to two feet below surface (or refusal) and
perform visual-manual classification of the soils at the surface and depth according to
ASTM method D2488. Submit sample from depth (or shallower if refusal) for PLM
analysis. The conditions shall be documented by taking photographs.

x If the node point elevation is near the historic bottom elevation, soil is confirmed by
visual manual classification (ASTM D2488), and PLM analysis is less than 50% CCR, then
personnel can conclude the CCR material is removed.

3.3 Visual Removal Not Applicable
If possible, excavation of ash should continue even if groundwater is encountered. If Duke Energy
cannot complete visual removal because of site conditions or other restricting factors, documentation
shall be presented to DEQ.

4.0 SOIL SAMPLING AND ANALYSIS
4.1 Soil Sampling
Soil sampling of the remaining soils (less than 50% CCR per PLM analysis) will be necessary to evaluate
the extent any potential for the soil to act as a secondary source of contamination. Soil samples for
laboratory analysis must be collected in a manner that will ensure a relatively uniform distribution of
particles throughout the six inch sample.

The systematic approach and design for soil sampling and analysis is based upon NCDEQ Guidance (DIN
26815) provided on October 11, 2016:

Confirmation sampling will include discrete surface samples collected from the first six inches of
the soil. Sampling will be performed on an acre grid system. This sample collection
methodology shall be sufficient to characterize the horizontal extent of any remaining potential
secondary source impacts for comparison with the DEQ Preliminary Soil Remediation Goals
(PSRG). The samples shall be analyzed by a North Carolina certified laboratory for total
concentrations for the following parameters: antimony, aluminum, arsenic, barium, beryllium,
boron, cadmium, calcium, chloride, chromium (total and hexavalent), cobalt, copper, iron, lead,
magnesium, manganese, mercury, molybdenum, nickel, nitrate as nitrogen, pH, potassium,
Area 1 Dry Stack Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC Revision 0
Page 6
selenium, silver, sodium, strontium, sulfate, thallium, vanadium and zinc. No SPLP testing is
required.

4.2 Fate and Transport Modeling
Site specific fate and transport modeling may be used to evaluate the impact of any contamination
found in excess of the applicable soil screening values.
Excavation Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC. & Duke Energy Progress, LLC. Revision 0

Table
Excavation Soil Sampling Plan October 2016
Duke Energy Carolinas, LLC. Revision 0

TABLE 1
SOIL PARAMETERS AND ANALYTICAL METHODS
TOTALS AND SPLP ANALYSIS
AREA 1 DRY STACK DUKE ENERGY DAN RIVER STEAM STATION
INORGANIC COMPOUNDS UNITS METHOD1
Aluminum mg/kg or μg/l EPA 6010D
Antimony mg/kg or μg/l EPA 6020B
Arsenic mg/kg or μg/l EPA 6020B
Barium mg/kg or μg/l EPA 6010D
Beryllium mg/kg or μg/l EPA 6020B
Boron mg/kg or μg/l EPA 6010D
Cadmium mg/kg or μg/l EPA 6020B
Calcium mg/kg or μg/l EPA 6010D
Chloride mg/kg or μg/l EPA 9056A
Chromium mg/kg or μg/l EPA 6010D
Cobalt mg/kg or μg/l EPA 6020B
Copper mg/kg or μg/l EPA 6010D
Hexavalent Chromium mg/kg or μg/l EPA Method
7199/218.7
Iron mg/kg or μg/l EPA 6010D
Lead mg/kg or μg/l EPA 6020B
Magnesium mg/kg or μg/l EPA 6010D
Manganese mg/kg or μg/l EPA 6010D
Mercury mg/kg or μg/l EPA Method
7470A/7471B
Molybdenum mg/kg or μg/l EPA 6010D
Nickel mg/kg or μg/l EPA 6010D
Nitrate as Nitrogen mg/kg or μg/l EPA 9056A
pH SU EPA 9045D
Potassium mg/kg or μg/l EPA 6010D
Selenium mg/kg or μg/l EPA 6020B
Silver mg/kg or μg/l EPA 6020B
Sodium mg/kg or μg/l EPA 6010D
Strontium mg/kg or μg/l EPA 6010D
Sulfate mg/kg or μg/l EPA 9056A
Thallium (low level) (SPLP Extract only) mg/kg or μg/l EPA 6020B
Vanadium mg/kg or μg/l EPA 6020B
Zinc mg/kg or μg/l EPA 6010D
Notes:
1. Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH
using USEPA Method 9045, as noted above (or similar approved methods). Soil samples will
also be analyzed for leaching potential using SPLP Extraction Method 1312 in conjunction with
USEPA Methods 6010/6020 (or similar approved methods).

ATTACHMENT 2

Photograph Log

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
1

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (3)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A8

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (5)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A8

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
2

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (7)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B8

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (8)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B8

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (9)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A7

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (10)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A7

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (11)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B7

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (12)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B7

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
5

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (13)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (14)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A6

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (15)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (16)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B6

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
7

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (17)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A5

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (18)

Date
10-18-2016
Observations
Ash Removal Visual Sample
A5

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
8

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (19)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B5

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (20)

Date
10-18-2016
Observations
Ash Removal Visual Sample
B5

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
9

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (21)

Date
10-18-2016
Observations
Ash Removal Visual Sample
C7

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (22)

Date
10-18-2016
Observations
Ash Removal Visual Sample
C7

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
10

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (23)

Date
10-18-2016
Observations
Ash Removal Visual Sample
D7

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (24)

Date
10-18-2016
Observations
Ash Removal Visual Sample
D7

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
11

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (25)

Date
10-18-2016
Observations
Ash Removal Visual Sample
C6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (26)

Date
10-18-2016
Observations
Ash Removal Visual Sample
C6

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
12

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (27)

Date
10-18-2016
Observations
Ash Removal Visual Sample
D6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (28)

Date
10-18-2016
Observations
Ash Removal Visual Sample
D6

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
13

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (29)

Date
10-18-2016
Observations
Ash Removal Visual Sample
C5

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161018
Mohon (30)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C5

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
14

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (3)

Date
10-19-2016
Observations
Ash Removal Visual Sample
D4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (4)

Date
10-19-2016
Observations
Ash Removal Visual Sample
D4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
15

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (5)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (6)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
16

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (7)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (8)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
17

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (9)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (10)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
18

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (11)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (12)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A3

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
19

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (13)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (14)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B3

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
20

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (15)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A2

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (16)

Date
10-19-2016
Observations
Ash Removal Visual Sample
A2

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
21

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (17)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B2

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (18)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B2

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
22

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (19)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (20)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C3

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
23

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (21)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C2

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (22)

Date
10-19-2016
Observations
Ash Removal Visual Sample
C2

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
24

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (23)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B1

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161019
Mohon (24)

Date
10-19-2016
Observations
Ash Removal Visual Sample
B1

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
25

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (1)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample A5+A5.1

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (2)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample A5+A5.1

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
26

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (4)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample B5

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (5)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample B5

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
27

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (6)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample A6

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (7)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample A6

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
28

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (8)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample B4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161020
Mohon (9)

Date
10-20-2016
Observations
Ash Removal Analytical
Sample B4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
29

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (1)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A2

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (2)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A2

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
30

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (3)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A4

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (5)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A4

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
31

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (6)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample B3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (7)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample B3

Cell 1 CCR Removal Verification Photo Log – Certification Report Dan River Steam Station
December 2, 2016 Amec Foster Wheeler Project No.: 7810-16-0623
32

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (8)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A3

Point ID
Cell 1 Ash
Removal
Verification
Photo ID
20161021
Mohon (9)

Date
10-21-2016
Observations
Ash Removal Analytical
Sample A3

ATTACHMENT 3

Laboratory Test Results – RJ Lee Group



























ƉƉĞŶĚŝdž

ŚĂŝŶŽĨƵƐƚŽĚLJ&ŽƌŵƐ



























3HJJ\.HQGDOO
&XVWRPHU6XSSRUW
'XNH(QHUJ\&HQWUDO/DE
+DJHUV)HUU\5RDG
+XQWHUYLOOH1&8QLWHG6WDWHV
(PDLOSHJJ\NHQGDOO#GXNHHQHUJ\FRP
0DLQ
5-/HH*URXS,QF
+RFKEHUJ5RDG
0RQURHYLOOH3$8QLWHG6WDWHV
0DLQ)D[
5HOLQTXLVKHG7R5HFHLYHG)URP
&KDLQRI&XVWRG\
5-/HH*URXS:RUN2UGHU$2+
3URMHFW1DPH&DVH'DQ5LYHU
6XSHUVHGHV)RUP)25$5HY2ULJLQDO,VVXH
(IIHFWLYH'DWH0D\
$SSURYHG%\4XDOLW\$VVXUDQFH
)RUP$)25
3DJHRI
6DPSOH,'&OLHQW6DPSOH,''DWH5HFHLYHG
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
$0('7
4&B$0('7
4&B$0('7
+RFKEHUJ5RDG0RQURHYLOOH3$
3KRQH_)D[2FW30('7 3DJHRI 
5HFHLYHG)URP3HJJ\.HQGDOO Method of Shipment: Federal Express
&RPSDQ\'XNH(QHUJ\&HQWUDO/DE 'DWH
5HFHLYHG%\0RQLFD&DUVH Package Condition Upon Receipt:Sealed
&RPSDQ\5-/HH*URXS,QF'DWH
5HOLQTXLVKHGMethod of Shipment:
&RPSDQ\ 'DWH
Package Condition Upon Receipt:
&RPSDQ\ 'DWH
5HFHLYHG%\
5HOLQTXLVKHGMethod of Shipment:
&RPSDQ\ 'DWH
5HFHLYHG%\Package Condition Upon Receipt:
&RPSDQ\ 'DWH
+RFKEHUJ5RDG0RQURHYLOOH3$
3KRQH_)D[2FW30('7 3DJHRI 


























ƉƉĞŶĚŝdž

DŝŶĞƌĂů/ĚĞŶƚŝĨŝĐĂƚŝŽŶZĞƉŽƌƚ



























0L
Q
H
U
D
O

,
G
H
Q
W
L
I
L
F
D
W
L
R
Q

3R
O
D
U
L
]
H
G

/
L
J
K
W

0
L
F
U
R
V
F
R
S
\


3
/
0


/
D
E
R
U
D
W
R
U
\

5
H
S
R
U
W

3H
J
J
\

.
H
Q
G
D
O
O

'X
N
H

(
Q
H
U
J
\

&
H
Q
W
U
D
O

/
D
E






+
D
J
H
U
V

)
H
U
U
\

5
R
D
G

+X
Q
W
H
U
Y
L
O
O
H


1
&








8
Q
L
W
H
G

6
W
D
W
H
V

(P
D
L
O


S
H
J
J
\

N
H
Q
G
D
O
O
#
G
X
N
H

H
Q
H
U
J
\

F
R
P

0D
L
Q















5H
S
R
U
W

'
D
W
H


6D
P
S
O
H

5
H
F
H
L
Y
H
G

'
D
W
H


3X
U
F
K
D
V
H

2
U
G
H
U


&X
V
W
R
P
H
U

&
2
&



5-
/
*

3
U
R
M
H
F
W


$Q
D
O
\
W
L
F
D
O

0
H
W
K
R
G






















$2
+











-


















)O
\

$
V
K

'
H
W
H
U
P
L
Q
D
W
L
R
Q

E
\

3
/
0

-








'D
W
H






&R
O
O
H
F
W
H
G

$U
H
D



)O
\$
V
K

'D
W
H






$QD
O
\]H
G

&X
V
W
R
P
H
U











6D
P
S
O
H





&R
P
P
H
Q
W
V

5-
/
*

,
'

1R
Q

)
O
\

$
V
K

&R
P
S
R
Q
H
Q
W
V







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]

3DJHR I 
$2
+














+
R
F
K
E
H
U
J

5
R
D
G


0
R
Q
U
R
H
Y
L
O
O
H


3
$







_

3
K
R
Q
H
















_

)
D
[
















'D
W
H






&R
O
O
H
F
W
H
G

$U
H
D



)O
\$
V
K

'D
W
H






$QD
O
\]H
G

&X
V
W
R
P
H
U











6D
P
S
O
H





&R
P
P
H
Q
W
V

5-
/
*

,
'

1R
Q

)
O
\

$
V
K

&R
P
S
R
Q
H
Q
W
V







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]









































7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]

3DJHR I 
$2
+














+
R
F
K
E
H
U
J

5
R
D
G


0
R
Q
U
R
H
Y
L
O
O
H


3
$







_

3
K
R
Q
H
















_

)
D
[
















'D
W
H






&R
O
O
H
F
W
H
G

$U
H
D



)O
\$
V
K

'D
W
H






$QD
O
\]H
G

&X
V
W
R
P
H
U











6D
P
S
O
H





&R
P
P
H
Q
W
V

5-
/
*

,
'

1R
Q

)
O
\

$
V
K

&R
P
S
R
Q
H
Q
W
V







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]









































7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

&O
D
\

0L
F
D

2S
D
T
X
H
V

4X
D
U
W
]

4&


B






































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

1$

4&


B







































1'

7D
Q

)
L
Q
H

*
U
D
L
Q

6
H
G
L
P
H
Q
W

1$

3DJHR I 
$2
+














+
R
F
K
E
H
U
J

5
R
D
G


0
R
Q
U
R
H
Y
L
O
O
H


3
$







_

3
K
R
Q
H
















_

)
D
[




















6
D
P
S
O
H
V

Z
L
O
O

E
H

U
H
W
X
U
Q
H
G

W
R

F
O
L
H
Q
W

L
P
P
H
G
L
D
W
H
O
\

X
S
R
Q

W
K
H

U
H
O
H
DV
H

R
I

I
L
Q
D
O

U
H
S
R
U
W





7
K
H
V
H

U
H
V
X
O
W
V

D
U
H

V
X
E
P
L
W
W
H
G

S
X
U
V
X
D
Q
W

W
R

5
-

/
H
H

*
U
R
X
S
¶
V

F
X
U
U
H
QW

W
H
U
P
V

D
Q
G

F
R
Q
G
L
W
L
R
Q
V

R
I

V
D
O
H


L
Q
F
O
X
G
L
Q
J

W
K
H

F
R
P
S
D
Q
\
¶
V

V
W
D
Q
G
D
UG

Z
D
U
U
D
Q
W
\

D
Q
G

O
L
P
L
W
D
W
L
R
Q

R
I

O
L
D
E
L
O
L
W
\

S
U
R
Y
L
V
L
R
Q
V


1
R

U
H
V
S
R
Q
V
L
ELOLW\RUOLDELOLW\LV
DV
V
X
P
H
G

I
R
U

W
K
H

P
D
Q
Q
H
U

L
Q

Z
K
L
F
K

W
K
H
V
H

U
H
V
X
O
W
V

D
U
H

X
V
H
G

R
U

L
Q
W
H
U
SU
H
W
H
G





7
K
L
V

W
H
V
W

U
H
S
R
U
W

U
H
O
D
W
H
V

W
R

W
K
H

L
W
H
P
V

W
H
V
W
H
G





$
Q
\

U
H
S
U
R
G
X
F
W
L
R
Q

R
I

W
K
L
V

G
R
F
X
P
H
Q
W

P
X
V
W

L
Q
F
O
X
G
H

W
K
H

H
Q
W
L
U
H

G
R
FX
P
H
Q
W

L
Q

R
U
G
H
U

I
R
U

W
K
H

U
H
S
R
U
W

W
R

E
H

Y
D
O
L
G





7
K
L
V

U
H
S
R
U
W

P
D
\

Q
R
W

E
H

X
V
H
G

W
R

F
O
D
L
P

S
U
R
G
X
F
W

H
Q
G
R
U
V
H
P
H
Q
W

E
\

19
/
$
3

/
D
E

&
R
G
H










R
U

D
Q
\

D
J
H
Q
F
\

R
I

W
K
H

8

6


*
R
Y
H
U
Q
P
H
Q
W





6
D
P
S
O
H

V


I
R
U

W
K
L
V

S
U
R
M
H
F
W

Z
H
U
H

D
Q
D
O
\
]
H
G

D
W

R
X
U


0
R
Q
U
R
H
Y
L
O
O
H

3
$


$
,
+
$











1
9
/
$
3













1
<

(
/
$
3










I
D
F
L
O
L
W
\




,
I

5
-

/
H
H

*
U
R
X
S


,
Q
F


G
L
G

Q
R
W

F
R
O
O
H
F
W

W
K
H

V
D
P
S
O
H
V

D
Q
D
O
\
]
H
G


WK
H

Y
H
U
L
I
L
D
E
L
O
L
W
\

R
I

W
K
H

O
D
E
R
U
D
W
R
U
\
¶
V

U
H
V
X
O
W
V

L
V

O
L
P
L
W
H
G

W
R

W
K
H
U
H
S
R
U
W
H
G

Y
D
O
X
H
V





)
R
U

W
K
H

S
X
U
S
R
V
H
V

R
I

W
K
L
V

P
H
W
K
R
G


)
O
\

$
V
K

L
V

G
H
I
L
Q
H
G

D
V

D
Q
\

S
DU
W
L
F
O
H

F
R
Q
V
L
V
W
H
Q
W

Z
L
W
K

&
R
D
O

$
V
K





7
K
H

P
H
W
K
R
G

U
H
S
R
U
W
L
Q
J

O
H
Y
H
O

L
V




D
Q
G

D
Q
\
W
K
L
Q
J





L
V

F
R
Q
V
L
G
H
UH
G

D

Q
R
W

G
H
W
H
F
W
H
G


4X
D
U
W
]

±

$
Q
J
X
O
D
U

D
Q
L
V
R
W
U
R
S
L
F

S
D
U
W
L
F
X
O
D
W
H

Z
L
W
K

O
R
Z

U
H
O
L
H
I


)H
O
G
V
S
D
U

±

$
Q
J
X
O
D
U

W
R

E
O
R
F
N
\

D
Q
L
V
R
W
U
R
S
L
F

S
D
U
W
L
F
X
O
D
W
H


O
R
Z

W
R

P
R
GH
U
D
W
H

U
H
O
L
H
I


E
L
D
[
L
D
O


F
D
Q

K
D
Y
H

S
R
O
\
V
\
Q
W
K
H
W
L
F

W
Z
L
Q
Q
L
Q
J


&O
D
\

±

6
K
H
H
W

V
L
O
L
F
D
W
H
V

Z
L
W
K

S
R
O
\
F
U
\
V
W
D
O
O
L
Q
H

R
U

G
L
V
S
O
D
\

Q
R
Q

X
Q
L
I
RU
P

H
[
W
L
Q
F
W
L
R
Q

Z
L
W
K

O
R
Z

W
R

P
R
G
H
U
D
W
H

U
H
O
L
H
I


D
Q
G

]
H
U
R

W
R

O
R
Z

E
L
U
HI
U
L
Q
J
H
Q
F
H



&
O
D
\

D
O
V
R

U
H
I
H
U
V

W
R

S
D
U
W
L
F
O
H
V

W
K
D
W

D
U
H

O
H
V
V

W
K
D
Q


PLFURQV
2S
D
T
X
H
V

±

2
S
D
T
X
H

L
V

D

J
H
Q
H
U
L
F

W
H
U
P

I
R
U

D

S
D
U
W
L
F
O
H

W
K
D
W

G
R
H
V

Q
R
W
W
U
D
Q
V
P
L
W

O
L
J
K
W



2
S
D
T
X
H

P
L
Q
H
U
D
O
V

D
U
H

G
L
V
W
L
Q
J
X
L
V
K
H
G

I
U
R
P

R
S
D
T
X
H
E
R
W
W
R
P

D
V
K

E
D
V
H
G

R
Q

P
R
U
S
K
R
O
R
J
\

R
I

I
U
D
F
W
X
U
H


)O
\

$
V
K

±

,
V
R
W
U
R
S
L
F

W
R

R
S
D
T
X
H

V
S
K
H
U
H
V


D
J
J
O
R
P
H
U
D
W
L
R
Q

R
I

V
S
K
H
U
H
V

D
Q
G

D
Q
J
X
O
D
U

D
V
K

S
D
U
W
L
F
O
H
V


2U
J
D
Q
L
F

3
D
U
W
L
F
X
O
D
W
H

±

3
R
O
O
H
Q


S
O
D
Q
W

D
Q
G

L
Q
V
H
F
W

P
D
W
W
H
U


D
Q
G

F
D
U
E
RQ
D
F
H
R
X
V

P
D
W
W
H
U


&D
U
E
R
Q
D
W
H
V

±

+
L
J
K

E
L
U
H
I
U
L
Q
J
H
Q
W


F
D
Q

E
H

U
K
R
P
E
R
K
H
G
U
D
O


Z
L
W
K

K
L
J
K

UH
O
L
H
I


'L
D
W
R
P
V

±

6
L
O
L
F
D

U
L
F
K

L
V
R
W
U
R
S
L
F

S
D
U
W
L
F
O
H
V

Z
L
W
K

Y
D
U
L
R
X
V

P
R
U
S
K
R
O
R
JL
H
V


0L
F
D

±

6
K
H
H
W

V
L
O
L
F
D
W
H

Z
L
W
K

P
R
G
H
U
D
W
H

W
R

K
L
J
K

U
H
O
L
H
I

D
Q
G

O
R
Z

E
L
U
H
IU
L
Q
J
H
Q
F
H


P
R
Q
R

F
U
\
V
W
D
O
O
L
Q
H


D
Q
G

Q
R
U
P
D
O

H
[
W
L
Q
F
W
L
R
Q


0L
V
F
H
O
O
D
Q
H
R
X
V


6
L
O
L
F
D
W
H

±

,
V
R
W
U
R
S
L
F

D
Q
G

D
Q
L
V
R
W
U
R
S
L
F

V
L
O
L
F
D
W
H
V


ZLW
K

O
R
Z

W
R

K
L
J
K

U
H
O
L
H
I


L
G
H
Q
W
L
I
L
F
D
W
L
R
Q

X
Q
V
X
U
H

D
Q
G

E
H
\
R
Q
G

W
K
H

V
FR
S
H

R
I

W
K
H

P
H
W
K
R
G

W
R

L
G
H
Q
W
L
I
\


$PS
K
L
E
R
O
H

±

(
O
R
Q
J
D
W
H
G

D
Q
L
V
R
W
U
R
S
L
F

S
D
U
W
L
F
X
O
D
W
H

Z
L
W
K

P
R
G
H
U
D
W
H

W
R

K
LJ
K

U
H
O
L
H
I


&R
D
O

±

,
U
U
H
J
X
O
D
U

W
R

D
Q
J
X
O
D
U

S
D
U
W
L
F
O
H
V

Z
L
W
K

P
R
G
H
U
D
W
H

R
S
D
F
L
W
\


H
G
JH
V

D
Q
G

W
K
L
Q

S
D
U
W
L
F
O
H
V

D
U
H

U
H
G
G
L
V
K

E
U
R
Z
Q

L
Q

F
R
O
R
U





)
O
\

$
V
K

±

)
O
\

$
V
K

R
E
V
H
U
Y
H
G


Q
R
Q
H

F
R
X
Q
W
H
G


1'

±

1
R

)
O
\

$
V
K

G
H
W
H
F
W
H
G



3DJHR I 
$2
+














+
R
F
K
E
H
U
J

5
R
D
G


0
R
Q
U
R
H
Y
L
O
O
H


3
$







_

3
K
R
Q
H
















_

)
D
[
















'L
V
F
O
D
L
P
H
U

1
R
W
H
V




ATTACHMENT 4

Analytical Laboratory Test Results

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16100606
Project Name:DANRIVER - AB SOIL EXCAVATION
Lab Contact: Peggy Kendall
Date:11/15/2016
Customer Address:900 S. Edgewood Rd
Customer Name(s):AB Soil Excavation
Mail Code: Dan River Steam Station
Eden, NC 27288
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Peggy Kendall
Page 1 of 127
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016034353 DANRIVER 18-Oct-16 12:45 PM Jason Jamp DRSC Cell #1 A5
2016034368 DANRIVER 20-Oct-16 8:10 AM Jason Jamp DRSC Cell #1 A5.1
2016034369 DANRIVER 20-Oct-16 8:52 AM Jason Jamp DRSC Cell #1 B5
2016034370 DANRIVER 20-Oct-16 10:29 AM Jason Jamp DRSC Cell #1 A6
2016034371 DANRIVER 20-Oct-16 10:57 AM Jason Jamp DRSC Cell #1 A6.1
2016034372 DANRIVER 20-Oct-16 1:15 PM Jason Jamp DRSC Cell #1 A6.2
2016034373 DANRIVER 20-Oct-16 3:35 PM Jason Jamp DRSC Cell #1 B4
2016034374 DANRIVER 20-Oct-16 3:57 PM Jason Jamp DRSC Cell #1 B4.1
2016034375 DANRIVER 20-Oct-16 4:42 PM Jason Jamp DRSC Cell #1 B4.2
2016034376 DANRIVER 21-Oct-16 9:00 AM Jason Jamp DRSC Cell #1 A4
2016034377 DANRIVER 21-Oct-16 9:51 AM Jason Jamp DRSC Cell #1 A4.1
2016034378 DANRIVER 21-Oct-16 11:06 AM Jason Jamp DRSC Cell #1 A3
2016034379 DANRIVER 21-Oct-16 11:37 AM Jason Jamp DRSC Cell #1 A3.1
2016034380 DANRIVER 21-Oct-16 12:56 PM Jason Jamp DRSC Cell #1 A3.2
2016034381 DANRIVER 21-Oct-16 1:35 PM Jason Jamp DRSC Cell #1 B3
2016034382 DANRIVER 21-Oct-16 2:00 PM Jason Jamp DRSC Cell #1 B3.1
2016034383 DANRIVER 21-Oct-16 2:25 PM Jason Jamp DRSC Cell #1 B3.2
2016034384 DANRIVER 21-Oct-16 3:31 PM Jason Jamp DRSC Cell #1 A2
2016034385 DANRIVER 21-Oct-16 4:03 PM Jason Jamp DRSC Cell #1 A2.1
2016034386 DANRIVER 21-Oct-16 4:38 PM Jason Jamp DRSC Cell #1 A2.2
20 Total Samples
Page 2 of 127
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Peggy Kendall Date:11/15/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034353
Collection Date:18-Oct-16 12:45 PM
Site:DRSC Cell #1 A5
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 4 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034368
Collection Date:20-Oct-16 8:10 AM
Site:DRSC Cell #1 A5.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 5 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034369
Collection Date:20-Oct-16 8:52 AM
Site:DRSC Cell #1 B5
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 6 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034370
Collection Date:20-Oct-16 10:29 AM
Site:DRSC Cell #1 A6
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 7 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034371
Collection Date:20-Oct-16 10:57 AM
Site:DRSC Cell #1 A6.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 8 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034372
Collection Date:20-Oct-16 1:15 PM
Site:DRSC Cell #1 A6.2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 9 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034373
Collection Date:20-Oct-16 3:35 PM
Site:DRSC Cell #1 B4
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 10 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034374
Collection Date:20-Oct-16 3:57 PM
Site:DRSC Cell #1 B4.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 11 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034375
Collection Date:20-Oct-16 4:42 PM
Site:DRSC Cell #1 B4.2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 12 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034376
Collection Date:21-Oct-16 9:00 AM
Site:DRSC Cell #1 A4
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 13 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034377
Collection Date:21-Oct-16 9:51 AM
Site:DRSC Cell #1 A4.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 14 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034378
Collection Date:21-Oct-16 11:06 AM
Site:DRSC Cell #1 A3
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 15 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034379
Collection Date:21-Oct-16 11:37 AM
Site:DRSC Cell #1 A3.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 16 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034380
Collection Date:21-Oct-16 12:56 PM
Site:DRSC Cell #1 A3.2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 17 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034381
Collection Date:21-Oct-16 1:35 PM
Site:DRSC Cell #1 B3
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 18 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034382
Collection Date:21-Oct-16 2:00 PM
Site:DRSC Cell #1 B3.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 19 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034383
Collection Date:21-Oct-16 2:25 PM
Site:DRSC Cell #1 B3.2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 20 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034384
Collection Date:21-Oct-16 3:31 PM
Site:DRSC Cell #1 A2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 21 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034385
Collection Date:21-Oct-16 4:03 PM
Site:DRSC Cell #1 A2.1
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 22 of 127
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100606
2016034386
Collection Date:21-Oct-16 4:38 PM
Site:DRSC Cell #1 A2.2
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by RJ Lee)
Vendor Parameter Complete Vendor Method V_RJ_LEE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 23 of 127
#=CL#
November 10, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92317218
92317218
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16100606
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on October 25, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 90
Page 24 of 127
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92317218
J16100606
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 90
Page 25 of 127
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Matrix Date Collected Date Received
92317218001 2016034353 Solid 10/18/16 12:45 10/25/16 11:07
92317218002 2016034368 Solid 10/20/16 08:10 10/25/16 11:07
92317218003 2016034369 Solid 10/20/16 08:52 10/25/16 11:07
92317218004 2016034370 Solid 10/20/16 10:29 10/25/16 11:07
92317218005 2016034371 Solid 10/20/16 10:57 10/25/16 11:07
92317218006 2016034372 Solid 10/20/16 13:15 10/25/16 11:07
92317218007 2016034373 Solid 10/20/16 15:35 10/25/16 11:07
92317218008 2016034374 Solid 10/20/16 15:57 10/25/16 11:07
92317218009 2016034375 Solid 10/20/16 16:42 10/25/16 11:07
92317218010 2016034376 Solid 10/21/16 09:00 10/25/16 11:07
92317218011 2016034377 Solid 10/21/16 09:51 10/25/16 11:07
92317218012 2016034378 Solid 10/21/16 11:06 10/25/16 11:07
92317218013 2016034379 Solid 10/21/16 11:37 10/25/16 11:07
92317218014 2016034380 Solid 10/21/16 12:56 10/25/16 11:07
92317218015 2016034381 Solid 10/21/16 13:35 10/25/16 11:07
92317218016 2016034382 Solid 10/21/16 14:00 10/25/16 11:07
92317218017 2016034383 Solid 10/21/16 14:25 10/25/16 11:07
92317218018 2016034384 Solid 10/21/16 15:31 10/25/16 11:07
92317218019 2016034385 Solid 10/21/16 16:03 10/25/16 11:07
92317218020 2016034386 Solid 10/21/16 16:38 10/25/16 11:07
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 90
Page 26 of 127
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92317218001 2016034353 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218002 2016034368 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218003 2016034369 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218004 2016034370 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218005 2016034371 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 90
Page 27 of 127
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218006 2016034372 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218007 2016034373 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218008 2016034374 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218009 2016034375 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218010 2016034376 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 90
Page 28 of 127
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218011 2016034377 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218012 2016034378 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218013 2016034379 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218014 2016034380 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 90
Page 29 of 127
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 9056 1 PASI-OKEK
92317218015 2016034381 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218016 2016034382 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218017 2016034383 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OCPH
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OKEK
EPA 9056 1 PASI-OKEK
92317218018 2016034384 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-ODRS, KMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92317218019 2016034385 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 90
Page 30 of 127
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
92317218020 2016034386 EPA 6010 17 PASI-OCKJ
EPA 6020 8 PASI-OKMW
EPA 7471 1 PASI-ORVK
ASTM D2974-87 1 PASI-ODRC
EPA 9045 1 PASI-OTK1
EPA 7199 1 PASI-OKEK
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 90
Page 31 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218001 2016034353
Aluminum 15700 mg/kg 11/02/16 07:15 M15.1EPA 6010
Barium 71.7 mg/kg 11/02/16 07:15 M10.51EPA 6010
Beryllium 0.58 mg/kg 11/02/16 07:15 M10.051EPA 6010
Calcium 484 mg/kg 11/02/16 07:1525.5EPA 6010
Chromium 14.9 mg/kg 11/02/16 07:150.26EPA 6010
Copper 25.6 mg/kg 11/02/16 07:150.26EPA 6010
Iron 25300 mg/kg 11/02/16 20:18 M110.2EPA 6010
Magnesium 3470 mg/kg 11/02/16 07:15 M125.5EPA 6010
Manganese 54.7 mg/kg 11/02/16 07:150.26EPA 6010
Molybdenum 0.77 mg/kg 11/02/16 07:150.51EPA 6010
Nickel 11.5 mg/kg 11/02/16 07:150.26EPA 6010
Potassium 1570 mg/kg 11/02/16 07:15 M151.0EPA 6010
Silver 0.54 mg/kg 11/02/16 07:150.26EPA 6010
Sodium 163 mg/kg 11/02/16 07:1551.0EPA 6010
Strontium 14.3 mg/kg 11/02/16 07:150.51EPA 6010
Zinc 50.0 mg/kg 11/02/16 07:15 M11.0EPA 6010
Cobalt 7.0 mg/kg 11/03/16 19:482.6EPA 6020
Lead 14.0 mg/kg 11/02/16 14:271.0EPA 6020
Selenium 2.7 mg/kg 11/03/16 19:482.6EPA 6020
Vanadium 28.0 mg/kg 11/03/16 19:482.6EPA 6020
Percent Moisture 9.8 % 11/01/16 04:240.10ASTM D2974-87
pH at 25 Degrees C 5.9 Std. Units 10/27/16 11:30 H60.10EPA 9045
92317218002 2016034368
Aluminum 16000 mg/kg 11/02/16 07:316.2EPA 6010
Barium 85.1 mg/kg 11/02/16 07:310.62EPA 6010
Beryllium 0.70 mg/kg 11/02/16 07:310.062EPA 6010
Calcium 629 mg/kg 11/02/16 07:3131.2EPA 6010
Chromium 13.1 mg/kg 11/02/16 07:310.31EPA 6010
Copper 12.4 mg/kg 11/02/16 07:310.31EPA 6010
Iron 33600 mg/kg 11/02/16 20:2112.5EPA 6010
Magnesium 4000 mg/kg 11/02/16 07:3131.2EPA 6010
Manganese 103 mg/kg 11/02/16 07:310.31EPA 6010
Molybdenum 0.87 mg/kg 11/02/16 07:310.62EPA 6010
Nickel 19.1 mg/kg 11/02/16 07:310.31EPA 6010
Potassium 650 mg/kg 11/02/16 07:3162.4EPA 6010
Silver 0.55 mg/kg 11/02/16 07:310.31EPA 6010
Sodium 188 mg/kg 11/02/16 07:3162.4EPA 6010
Strontium 18.1 mg/kg 11/02/16 07:310.62EPA 6010
Zinc 47.8 mg/kg 11/02/16 07:311.2EPA 6010
Arsenic 1.4 mg/kg 11/02/16 14:291.2EPA 6020
Cobalt 8.4 mg/kg 11/02/16 14:291.2EPA 6020
Lead 17.0 mg/kg 11/02/16 14:291.2EPA 6020
Selenium 1.9 mg/kg 11/02/16 14:291.2EPA 6020
Vanadium 26.2 mg/kg 11/02/16 14:29 M61.2EPA 6020
Percent Moisture 10.2 % 11/01/16 04:240.10ASTM D2974-87
pH at 25 Degrees C 7.4 Std. Units 10/27/16 11:30 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 90
Page 32 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218003 2016034369
Aluminum 13200 mg/kg 11/02/16 07:365.9EPA 6010
Barium 76.7 mg/kg 11/02/16 07:360.59EPA 6010
Beryllium 0.67 mg/kg 11/02/16 07:360.059EPA 6010
Calcium 486 mg/kg 11/02/16 07:3629.5EPA 6010
Chromium 9.9 mg/kg 11/02/16 07:360.29EPA 6010
Copper 15.3 mg/kg 11/02/16 07:360.29EPA 6010
Iron 22700 mg/kg 11/02/16 20:2511.8EPA 6010
Magnesium 2280 mg/kg 11/02/16 07:3629.5EPA 6010
Manganese 305 mg/kg 11/02/16 07:360.29EPA 6010
Nickel 12.5 mg/kg 11/02/16 07:360.29EPA 6010
Potassium 824 mg/kg 11/02/16 07:3659.0EPA 6010
Silver 0.46 mg/kg 11/02/16 07:360.29EPA 6010
Sodium 76.8 mg/kg 11/02/16 07:3659.0EPA 6010
Strontium 14.3 mg/kg 11/02/16 07:360.59EPA 6010
Zinc 37.2 mg/kg 11/02/16 07:361.2EPA 6010
Arsenic 1.3 mg/kg 11/02/16 14:401.2EPA 6020
Cobalt 13.5 mg/kg 11/02/16 14:401.2EPA 6020
Lead 11.7 mg/kg 11/02/16 14:401.2EPA 6020
Selenium 1.4 mg/kg 11/02/16 14:401.2EPA 6020
Vanadium 21.4 mg/kg 11/02/16 14:401.2EPA 6020
Percent Moisture 12.5 % 11/01/16 04:240.10ASTM D2974-87
pH at 25 Degrees C 6.2 Std. Units 10/27/16 11:30 H60.10EPA 9045
92317218004 2016034370
Aluminum 17900 mg/kg 11/02/16 07:486.5EPA 6010
Barium 63.9 mg/kg 11/02/16 07:480.65EPA 6010
Beryllium 0.75 mg/kg 11/02/16 07:480.065EPA 6010
Calcium 182 mg/kg 11/02/16 07:4832.5EPA 6010
Chromium 20.9 mg/kg 11/02/16 07:480.33EPA 6010
Copper 14.2 mg/kg 11/02/16 07:480.33EPA 6010
Iron 31100 mg/kg 11/02/16 20:2913.0EPA 6010
Magnesium 1090 mg/kg 11/02/16 07:4832.5EPA 6010
Manganese 2450 mg/kg 11/05/16 21:243.3EPA 6010
Molybdenum 2.4 mg/kg 11/02/16 07:480.65EPA 6010
Nickel 8.0 mg/kg 11/02/16 07:480.33EPA 6010
Potassium 662 mg/kg 11/02/16 07:4865.1EPA 6010
Silver 0.88 mg/kg 11/02/16 07:480.33EPA 6010
Strontium 14.8 mg/kg 11/02/16 07:480.65EPA 6010
Zinc 32.6 mg/kg 11/02/16 07:481.3EPA 6010
Arsenic 7.2 mg/kg 11/02/16 14:421.3EPA 6020
Cobalt 79.1 mg/kg 11/02/16 14:421.3EPA 6020
Lead 39.0 mg/kg 11/02/16 14:421.3EPA 6020
Vanadium 42.0 mg/kg 11/02/16 14:421.3EPA 6020
Mercury 0.045 mg/kg 10/30/16 22:340.011EPA 7471
Percent Moisture 12.3 % 11/01/16 04:240.10ASTM D2974-87
pH at 25 Degrees C 5.6 Std. Units 10/27/16 11:30 H60.10EPA 9045
Chromium, Hexavalent 0.90 mg/kg 11/03/16 21:410.72EPA 7199
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 90
Page 33 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218005 2016034371
Aluminum 23300 mg/kg 11/02/16 07:527.3EPA 6010
Barium 41.5 mg/kg 11/02/16 07:520.73EPA 6010
Beryllium 0.30 mg/kg 11/02/16 07:520.073EPA 6010
Calcium 348 mg/kg 11/02/16 07:5236.7EPA 6010
Chromium 19.0 mg/kg 11/02/16 07:520.37EPA 6010
Copper 18.8 mg/kg 11/02/16 07:520.37EPA 6010
Iron 33700 mg/kg 11/02/16 20:3414.7EPA 6010
Magnesium 2080 mg/kg 11/02/16 07:5236.7EPA 6010
Manganese 26.5 mg/kg 11/02/16 07:520.37EPA 6010
Molybdenum 2.1 mg/kg 11/02/16 07:520.73EPA 6010
Nickel 6.2 mg/kg 11/02/16 07:520.37EPA 6010
Potassium 1020 mg/kg 11/02/16 07:5273.5EPA 6010
Silver 1.0 mg/kg 11/02/16 07:520.37EPA 6010
Sodium 185 mg/kg 11/02/16 07:5273.5EPA 6010
Strontium 16.7 mg/kg 11/02/16 07:520.73EPA 6010
Zinc 26.4 mg/kg 11/02/16 07:521.5EPA 6010
Arsenic 5.3 mg/kg 11/02/16 15:141.5EPA 6020
Cobalt 3.0 mg/kg 11/02/16 15:141.5EPA 6020
Lead 12.6 mg/kg 11/02/16 15:141.5EPA 6020
Vanadium 45.5 mg/kg 11/02/16 15:141.5EPA 6020
Mercury 0.031 mg/kg 10/30/16 22:360.012EPA 7471
Percent Moisture 17.8 % 11/01/16 04:240.10ASTM D2974-87
pH at 25 Degrees C 5.5 Std. Units 10/27/16 11:30 H60.10EPA 9045
Sulfate 95.3 mg/kg 10/27/16 13:2660.9EPA 9056
92317218006 2016034372
Aluminum 19000 mg/kg 11/02/16 20:4627.3EPA 6010
Barium 77.3 mg/kg 11/02/16 20:462.7EPA 6010
Beryllium 2.0 mg/kg 11/02/16 20:46 D30.27EPA 6010
Calcium 1860 mg/kg 11/02/16 20:46137EPA 6010
Chromium 18.6 mg/kg 11/02/16 20:461.4EPA 6010
Copper 32.6 mg/kg 11/07/16 08:555.5EPA 6010
Iron 34900 mg/kg 11/02/16 20:4610.9EPA 6010
Magnesium 5170 mg/kg 11/02/16 20:46137EPA 6010
Manganese 208 mg/kg 11/02/16 07:560.27EPA 6010
Molybdenum 1.0 mg/kg 11/02/16 07:560.55EPA 6010
Nickel 16.6 mg/kg 11/02/16 07:560.27EPA 6010
Potassium 1090 mg/kg 11/02/16 20:46273EPA 6010
Strontium 32.9 mg/kg 11/02/16 20:462.7EPA 6010
Zinc 46.0 mg/kg 11/02/16 07:561.1EPA 6010
Arsenic 3.8 mg/kg 11/03/16 19:502.7EPA 6020
Cobalt 28.2 mg/kg 11/03/16 19:502.7EPA 6020
Lead 15.7 mg/kg 11/02/16 15:161.1EPA 6020
Selenium 3.6 mg/kg 11/03/16 19:502.7EPA 6020
Vanadium 36.2 mg/kg 11/03/16 19:502.7EPA 6020
Percent Moisture 19.8 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 10/27/16 11:30 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 90
Page 34 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218007 2016034373
Aluminum 38800 mg/kg 11/02/16 20:5033.1EPA 6010
Barium 222 mg/kg 11/02/16 08:000.66EPA 6010
Beryllium 2.2 mg/kg 11/02/16 20:50 D30.33EPA 6010
Calcium 1830 mg/kg 11/02/16 08:0033.1EPA 6010
Chromium 34.2 mg/kg 11/02/16 20:501.7EPA 6010
Copper 78.4 mg/kg 11/07/16 08:596.6EPA 6010
Iron 51500 mg/kg 11/02/16 20:5013.2EPA 6010
Magnesium 7000 mg/kg 11/02/16 08:0033.1EPA 6010
Manganese 1000 mg/kg 11/05/16 21:453.3EPA 6010
Molybdenum 3.2 mg/kg 11/02/16 08:000.66EPA 6010
Nickel 26.7 mg/kg 11/02/16 08:000.33EPA 6010
Potassium 2480 mg/kg 11/02/16 08:0066.2EPA 6010
Sodium 108 mg/kg 11/02/16 08:0066.2EPA 6010
Strontium 32.6 mg/kg 11/02/16 08:000.66EPA 6010
Zinc 84.6 mg/kg 11/02/16 08:001.3EPA 6010
Arsenic 20.3 mg/kg 11/03/16 19:533.3EPA 6020
Cobalt 26.9 mg/kg 11/03/16 19:533.3EPA 6020
Lead 25.3 mg/kg 11/02/16 15:191.3EPA 6020
Vanadium 54.6 mg/kg 11/03/16 19:533.3EPA 6020
Mercury 0.025 mg/kg 10/30/16 22:400.011EPA 7471
Percent Moisture 19.5 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 8.3 Std. Units 10/27/16 11:30 H60.10EPA 9045
92317218008 2016034374
Aluminum 24400 mg/kg 11/03/16 01:306.3EPA 6010
Barium 270 mg/kg 11/03/16 01:300.63EPA 6010
Beryllium 2.0 mg/kg 11/05/16 22:460.32EPA 6010
Calcium 1670 mg/kg 11/03/16 01:3031.7EPA 6010
Chromium 34.9 mg/kg 11/05/16 22:461.6EPA 6010
Copper 65.2 mg/kg 11/07/16 09:276.3EPA 6010
Iron 43100 mg/kg 11/05/16 22:4612.7EPA 6010
Magnesium 7240 mg/kg 11/03/16 01:3031.7EPA 6010
Manganese 1250 mg/kg 11/05/16 22:461.6EPA 6010
Molybdenum 5.7 mg/kg 11/03/16 01:300.63EPA 6010
Nickel 25.5 mg/kg 11/03/16 01:300.32EPA 6010
Potassium 3230 mg/kg 11/03/16 01:3063.4EPA 6010
Sodium 194 mg/kg 11/03/16 01:3063.4EPA 6010
Strontium 31.3 mg/kg 11/03/16 01:300.63EPA 6010
Zinc 120 mg/kg 11/05/16 22:466.3EPA 6010
Arsenic 7.9 mg/kg 11/03/16 20:121.3EPA 6020
Cobalt 39.5 mg/kg 11/03/16 20:12 M61.3EPA 6020
Lead 30.3 mg/kg 11/03/16 20:12 M61.3EPA 6020
Selenium 2.5 mg/kg 11/03/16 20:121.3EPA 6020
Vanadium 39.2 mg/kg 11/03/16 20:12 M61.3EPA 6020
Mercury 0.021 mg/kg 10/30/16 22:420.011EPA 7471
Percent Moisture 20.4 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 6.1 Std. Units 10/27/16 11:30 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 90
Page 35 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218009 2016034375
Aluminum 16900 mg/kg 11/03/16 01:346.9EPA 6010
Barium 120 mg/kg 11/03/16 01:340.69EPA 6010
Beryllium 0.47 mg/kg 11/05/16 22:500.34EPA 6010
Calcium 1020 mg/kg 11/03/16 01:3434.4EPA 6010
Chromium 17.2 mg/kg 11/03/16 01:340.34EPA 6010
Copper 12.5 mg/kg 11/03/16 01:340.34EPA 6010
Iron 16900 mg/kg 11/05/16 22:5013.8EPA 6010
Magnesium 2950 mg/kg 11/03/16 01:3434.4EPA 6010
Manganese 95.4 mg/kg 11/03/16 01:340.34EPA 6010
Molybdenum 0.94 mg/kg 11/03/16 01:340.69EPA 6010
Nickel 11.2 mg/kg 11/03/16 01:340.34EPA 6010
Potassium 481 mg/kg 11/03/16 01:3468.8EPA 6010
Silver 0.49 mg/kg 11/03/16 01:340.34EPA 6010
Sodium 225 mg/kg 11/03/16 01:3468.8EPA 6010
Strontium 20.8 mg/kg 11/03/16 01:340.69EPA 6010
Zinc 27.8 mg/kg 11/05/16 22:506.9EPA 6010
Arsenic 2.9 mg/kg 11/03/16 20:221.4EPA 6020
Cobalt 4.9 mg/kg 11/03/16 20:221.4EPA 6020
Lead 9.9 mg/kg 11/03/16 20:221.4EPA 6020
Vanadium 27.4 mg/kg 11/03/16 20:221.4EPA 6020
Percent Moisture 13.2 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 7.0 Std. Units 10/27/16 11:30 H60.10EPA 9045
92317218010 2016034376
Aluminum 48900 mg/kg 11/05/16 22:5440.1EPA 6010
Barium 212 mg/kg 11/03/16 01:380.80EPA 6010
Beryllium 1.7 mg/kg 11/05/16 22:540.40EPA 6010
Calcium 1480 mg/kg 11/03/16 01:3840.1EPA 6010
Chromium 41.4 mg/kg 11/05/16 22:542.0EPA 6010
Copper 72.0 mg/kg 11/07/16 09:318.0EPA 6010
Iron 49400 mg/kg 11/05/16 22:5416.1EPA 6010
Magnesium 9450 mg/kg 11/03/16 01:3840.1EPA 6010
Manganese 1110 mg/kg 11/05/16 22:542.0EPA 6010
Molybdenum 2.4 mg/kg 11/03/16 01:380.80EPA 6010
Nickel 28.7 mg/kg 11/03/16 01:380.40EPA 6010
Potassium 3080 mg/kg 11/03/16 01:3880.3EPA 6010
Sodium 130 mg/kg 11/03/16 01:3880.3EPA 6010
Strontium 27.2 mg/kg 11/03/16 01:380.80EPA 6010
Zinc 102 mg/kg 11/05/16 22:548.0EPA 6010
Arsenic 5.6 mg/kg 11/03/16 20:251.6EPA 6020
Cobalt 42.2 mg/kg 11/03/16 20:251.6EPA 6020
Lead 26.4 mg/kg 11/03/16 20:251.6EPA 6020
Selenium 2.1 mg/kg 11/03/16 20:251.6EPA 6020
Vanadium 53.1 mg/kg 11/03/16 20:251.6EPA 6020
Mercury 0.053 mg/kg 10/30/16 22:470.012EPA 7471
Percent Moisture 22.3 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 6.5 Std. Units 10/28/16 09:45 H60.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 90
Page 36 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218011 2016034377
Aluminum 35700 mg/kg 11/05/16 22:5832.6EPA 6010
Barium 237 mg/kg 11/03/16 01:420.65EPA 6010
Beryllium 1.5 mg/kg 11/05/16 22:580.33EPA 6010
Calcium 1920 mg/kg 11/03/16 01:4232.6EPA 6010
Chromium 42.2 mg/kg 11/05/16 22:581.6EPA 6010
Copper 50.8 mg/kg 11/07/16 09:356.5EPA 6010
Iron 49800 mg/kg 11/05/16 22:5813.0EPA 6010
Magnesium 10800 mg/kg 11/03/16 01:4232.6EPA 6010
Manganese 1240 mg/kg 11/05/16 22:581.6EPA 6010
Molybdenum 5.4 mg/kg 11/03/16 01:420.65EPA 6010
Nickel 31.6 mg/kg 11/03/16 01:420.33EPA 6010
Potassium 2010 mg/kg 11/03/16 01:4265.2EPA 6010
Silver 1.7 mg/kg 11/05/16 22:581.6EPA 6010
Sodium 181 mg/kg 11/03/16 01:4265.2EPA 6010
Strontium 31.4 mg/kg 11/03/16 01:420.65EPA 6010
Zinc 96.4 mg/kg 11/05/16 22:586.5EPA 6010
Arsenic 5.5 mg/kg 11/03/16 20:271.3EPA 6020
Cobalt 25.9 mg/kg 11/03/16 20:271.3EPA 6020
Lead 19.1 mg/kg 11/03/16 20:271.3EPA 6020
Selenium 2.8 mg/kg 11/03/16 20:271.3EPA 6020
Vanadium 66.5 mg/kg 11/03/16 20:271.3EPA 6020
Mercury 0.018 mg/kg 10/30/16 22:490.011EPA 7471
Percent Moisture 15.7 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 6.6 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218012 2016034378
Aluminum 19700 mg/kg 11/03/16 01:466.6EPA 6010
Barium 102 mg/kg 11/03/16 01:460.66EPA 6010
Beryllium 1.1 mg/kg 11/05/16 23:020.33EPA 6010
Calcium 429 mg/kg 11/03/16 01:4632.9EPA 6010
Chromium 23.8 mg/kg 11/03/16 01:460.33EPA 6010
Copper 31.9 mg/kg 11/03/16 01:460.33EPA 6010
Iron 38200 mg/kg 11/05/16 23:0213.1EPA 6010
Magnesium 2020 mg/kg 11/03/16 01:4632.9EPA 6010
Manganese 526 mg/kg 11/03/16 01:460.33EPA 6010
Molybdenum 1.6 mg/kg 11/03/16 01:460.66EPA 6010
Nickel 11.7 mg/kg 11/03/16 01:460.33EPA 6010
Potassium 1360 mg/kg 11/03/16 01:4665.7EPA 6010
Silver 1.1 mg/kg 11/03/16 01:460.33EPA 6010
Strontium 11.1 mg/kg 11/03/16 01:460.66EPA 6010
Zinc 46.1 mg/kg 11/05/16 23:026.6EPA 6010
Arsenic 5.0 mg/kg 11/03/16 20:301.3EPA 6020
Cobalt 14.4 mg/kg 11/03/16 20:301.3EPA 6020
Lead 13.8 mg/kg 11/03/16 20:301.3EPA 6020
Selenium 1.4 mg/kg 11/03/16 20:301.3EPA 6020
Vanadium 39.6 mg/kg 11/03/16 20:301.3EPA 6020
Mercury 0.022 mg/kg 10/30/16 22:550.010EPA 7471
Percent Moisture 15.7 % 11/01/16 04:250.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 90
Page 37 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218012 2016034378
pH at 25 Degrees C 5.5 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218013 2016034379
Aluminum 30400 mg/kg 11/03/16 01:506.9EPA 6010
Barium 123 mg/kg 11/03/16 01:500.69EPA 6010
Beryllium 1.4 mg/kg 11/05/16 23:22 D30.35EPA 6010
Calcium 126 mg/kg 11/03/16 01:5034.6EPA 6010
Chromium 35.2 mg/kg 11/05/16 23:221.7EPA 6010
Copper 50.6 mg/kg 11/05/16 23:221.7EPA 6010
Iron 52000 mg/kg 11/05/16 23:2213.8EPA 6010
Magnesium 4290 mg/kg 11/03/16 01:5034.6EPA 6010
Manganese 540 mg/kg 11/05/16 23:221.7EPA 6010
Molybdenum 1.5 mg/kg 11/03/16 01:500.69EPA 6010
Nickel 19.6 mg/kg 11/03/16 01:500.35EPA 6010
Potassium 1870 mg/kg 11/03/16 01:5069.1EPA 6010
Silver 1.8 mg/kg 11/05/16 23:221.7EPA 6010
Strontium 16.2 mg/kg 11/03/16 01:500.69EPA 6010
Zinc 69.4 mg/kg 11/05/16 23:226.9EPA 6010
Arsenic 5.3 mg/kg 11/03/16 20:321.4EPA 6020
Cobalt 12.8 mg/kg 11/03/16 20:321.4EPA 6020
Lead 15.2 mg/kg 11/03/16 20:321.4EPA 6020
Selenium 1.7 mg/kg 11/03/16 20:321.4EPA 6020
Vanadium 44.8 mg/kg 11/03/16 20:321.4EPA 6020
Mercury 0.022 mg/kg 10/30/16 22:570.010EPA 7471
Percent Moisture 19.1 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218014 2016034380
Aluminum 37000 mg/kg 11/05/16 23:2635.1EPA 6010
Barium 94.0 mg/kg 11/03/16 01:540.70EPA 6010
Beryllium 1.5 mg/kg 11/05/16 23:26 D30.35EPA 6010
Calcium 71.7 mg/kg 11/03/16 01:5435.1EPA 6010
Chromium 42.1 mg/kg 11/05/16 23:261.8EPA 6010
Copper 61.7 mg/kg 11/05/16 23:261.8EPA 6010
Iron 58900 mg/kg 11/05/16 23:2614.0EPA 6010
Magnesium 5150 mg/kg 11/03/16 01:5435.1EPA 6010
Manganese 340 mg/kg 11/05/16 23:261.8EPA 6010
Molybdenum 1.5 mg/kg 11/03/16 01:540.70EPA 6010
Nickel 21.8 mg/kg 11/03/16 01:540.35EPA 6010
Potassium 2660 mg/kg 11/03/16 01:5470.2EPA 6010
Silver 2.3 mg/kg 11/05/16 23:261.8EPA 6010
Strontium 6.1 mg/kg 11/03/16 01:540.70EPA 6010
Zinc 82.7 mg/kg 11/05/16 23:267.0EPA 6010
Arsenic 4.5 mg/kg 11/03/16 20:401.4EPA 6020
Cobalt 13.8 mg/kg 11/03/16 20:401.4EPA 6020
Lead 15.6 mg/kg 11/03/16 20:401.4EPA 6020
Selenium 1.5 mg/kg 11/03/16 20:401.4EPA 6020
Vanadium 56.1 mg/kg 11/03/16 20:401.4EPA 6020
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 90
Page 38 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218014 2016034380
Mercury 0.026 mg/kg 11/01/16 19:320.011EPA 7471
Percent Moisture 19.2 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218015 2016034381
Aluminum 16200 mg/kg 11/03/16 01:585.2EPA 6010
Barium 99.3 mg/kg 11/03/16 01:580.52EPA 6010
Beryllium 1.0 mg/kg 11/05/16 23:30 D30.26EPA 6010
Calcium 1000 mg/kg 11/03/16 01:5825.9EPA 6010
Chromium 17.6 mg/kg 11/05/16 23:301.3EPA 6010
Copper 23.8 mg/kg 11/05/16 23:301.3EPA 6010
Iron 28300 mg/kg 11/05/16 23:3010.4EPA 6010
Magnesium 1930 mg/kg 11/03/16 01:5825.9EPA 6010
Manganese 526 mg/kg 11/05/16 23:301.3EPA 6010
Molybdenum 0.70 mg/kg 11/03/16 01:580.52EPA 6010
Nickel 12.3 mg/kg 11/03/16 01:580.26EPA 6010
Potassium 1430 mg/kg 11/03/16 01:5851.9EPA 6010
Strontium 14.9 mg/kg 11/03/16 01:580.52EPA 6010
Zinc 46.6 mg/kg 11/05/16 23:305.2EPA 6010
Arsenic 1.8 mg/kg 11/03/16 20:421.0EPA 6020
Cobalt 13.7 mg/kg 11/03/16 20:421.0EPA 6020
Lead 22.6 mg/kg 11/03/16 20:421.0EPA 6020
Selenium 1.7 mg/kg 11/03/16 20:421.0EPA 6020
Vanadium 29.6 mg/kg 11/03/16 20:421.0EPA 6020
Mercury 0.016 mg/kg 11/01/16 19:340.010EPA 7471
Percent Moisture 13.8 % 11/01/16 04:250.10ASTM D2974-87
pH at 25 Degrees C 5.5 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218016 2016034382
Aluminum 11900 mg/kg 11/02/16 08:044.9EPA 6010
Barium 86.5 mg/kg 11/02/16 08:040.49EPA 6010
Beryllium 0.90 mg/kg 11/02/16 20:54 D30.24EPA 6010
Calcium 2070 mg/kg 11/02/16 08:0424.3EPA 6010
Chromium 14.9 mg/kg 11/02/16 20:541.2EPA 6010
Copper 21.6 mg/kg 11/07/16 09:034.9EPA 6010
Iron 30500 mg/kg 11/02/16 20:549.7EPA 6010
Magnesium 1580 mg/kg 11/02/16 08:0424.3EPA 6010
Manganese 317 mg/kg 11/05/16 21:492.4EPA 6010
Molybdenum 0.59 mg/kg 11/02/16 08:040.49EPA 6010
Nickel 10.0 mg/kg 11/02/16 08:040.24EPA 6010
Potassium 1020 mg/kg 11/02/16 08:0448.6EPA 6010
Strontium 22.4 mg/kg 11/02/16 08:040.49EPA 6010
Zinc 33.2 mg/kg 11/02/16 08:040.97EPA 6010
Cobalt 11.6 mg/kg 11/03/16 19:552.4EPA 6020
Lead 18.9 mg/kg 11/02/16 15:210.97EPA 6020
Vanadium 30.6 mg/kg 11/03/16 19:552.4EPA 6020
Mercury 0.012 mg/kg 11/01/16 19:360.010EPA 7471
Percent Moisture 13.3 % 11/01/16 04:260.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 90
Page 39 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218016 2016034382
pH at 25 Degrees C 8.1 Std. Units 10/28/16 09:45 H60.10EPA 9045
92317218017 2016034383
Aluminum 17600 mg/kg 11/02/16 08:096.1EPA 6010
Barium 93.1 mg/kg 11/02/16 08:090.61EPA 6010
Beryllium 0.88 mg/kg 11/02/16 08:090.061EPA 6010
Calcium 449 mg/kg 11/02/16 08:0930.5EPA 6010
Chromium 15.9 mg/kg 11/02/16 08:090.30EPA 6010
Copper 20.5 mg/kg 11/02/16 08:090.30EPA 6010
Iron 30900 mg/kg 11/02/16 20:5812.2EPA 6010
Magnesium 1690 mg/kg 11/02/16 08:0930.5EPA 6010
Manganese 440 mg/kg 11/02/16 08:090.30EPA 6010
Molybdenum 0.83 mg/kg 11/02/16 08:090.61EPA 6010
Nickel 10.3 mg/kg 11/02/16 08:090.30EPA 6010
Potassium 1080 mg/kg 11/02/16 08:0961.0EPA 6010
Silver 0.73 mg/kg 11/02/16 08:090.30EPA 6010
Strontium 9.0 mg/kg 11/02/16 08:090.61EPA 6010
Zinc 38.1 mg/kg 11/02/16 08:091.2EPA 6010
Cobalt 12.4 mg/kg 11/04/16 15:243.0EPA 6020
Lead 20.7 mg/kg 11/02/16 15:241.2EPA 6020
Vanadium 30.4 mg/kg 11/04/16 15:243.0EPA 6020
Mercury 0.014 mg/kg 11/01/16 19:380.010EPA 7471
Percent Moisture 14.7 % 11/01/16 04:260.10ASTM D2974-87
pH at 25 Degrees C 5.0 Std. Units 10/28/16 09:45 H60.10EPA 9045
Sulfate 82.0 mg/kg 10/27/16 18:3457.8EPA 9056
92317218018 2016034384
Aluminum 13800 mg/kg 11/02/16 08:135.1EPA 6010
Barium 123 mg/kg 11/02/16 08:130.51EPA 6010
Beryllium 0.54 mg/kg 11/02/16 21:01 D30.26EPA 6010
Calcium 874 mg/kg 11/02/16 08:1325.6EPA 6010
Chromium 14.4 mg/kg 11/02/16 21:011.3EPA 6010
Copper 18.2 mg/kg 11/07/16 09:155.1EPA 6010
Iron 18100 mg/kg 11/02/16 21:0110.2EPA 6010
Magnesium 1530 mg/kg 11/02/16 08:1325.6EPA 6010
Manganese 510 mg/kg 11/05/16 21:572.6EPA 6010
Nickel 9.8 mg/kg 11/02/16 08:130.26EPA 6010
Potassium 868 mg/kg 11/02/16 08:1351.1EPA 6010
Strontium 12.6 mg/kg 11/02/16 08:130.51EPA 6010
Zinc 29.8 mg/kg 11/02/16 08:131.0EPA 6010
Cobalt 10.6 mg/kg 11/03/16 20:002.6EPA 6020
Lead 16.2 mg/kg 11/02/16 15:261.0EPA 6020
Vanadium 25.2 mg/kg 11/03/16 20:002.6EPA 6020
Mercury 0.019 mg/kg 11/01/16 20:190.0098EPA 7471
Percent Moisture 9.3 % 11/01/16 04:260.10ASTM D2974-87
pH at 25 Degrees C 4.7 Std. Units 11/02/16 08:06 H60.10EPA 9045
Sulfate 729 mg/kg 11/02/16 02:4855.2EPA 9056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 90
Page 40 of 127
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92317218
J16100606
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92317218019 2016034385
Aluminum 14700 mg/kg 11/02/16 08:176.0EPA 6010
Barium 110 mg/kg 11/02/16 08:170.60EPA 6010
Beryllium 0.66 mg/kg 11/02/16 08:170.060EPA 6010
Calcium 956 mg/kg 11/02/16 08:1729.9EPA 6010
Chromium 12.9 mg/kg 11/02/16 08:170.30EPA 6010
Copper 16.5 mg/kg 11/02/16 08:170.30EPA 6010
Iron 21500 mg/kg 11/02/16 21:0512.0EPA 6010
Magnesium 2000 mg/kg 11/02/16 08:1729.9EPA 6010
Manganese 445 mg/kg 11/02/16 08:170.30EPA 6010
Molybdenum 0.64 mg/kg 11/02/16 08:170.60EPA 6010
Nickel 10.5 mg/kg 11/02/16 08:170.30EPA 6010
Potassium 1100 mg/kg 11/02/16 08:1759.9EPA 6010
Silver 0.45 mg/kg 11/02/16 08:170.30EPA 6010
Strontium 17.4 mg/kg 11/02/16 08:170.60EPA 6010
Zinc 38.6 mg/kg 11/02/16 08:171.2EPA 6010
Arsenic 1.5 mg/kg 11/02/16 15:291.2EPA 6020
Cobalt 10.5 mg/kg 11/02/16 15:291.2EPA 6020
Lead 14.8 mg/kg 11/02/16 15:291.2EPA 6020
Selenium 1.4 mg/kg 11/02/16 15:291.2EPA 6020
Vanadium 25.4 mg/kg 11/02/16 15:291.2EPA 6020
Mercury 0.023 mg/kg 11/01/16 20:210.0082EPA 7471
Percent Moisture 9.7 % 11/01/16 04:260.10ASTM D2974-87
pH at 25 Degrees C 5.3 Std. Units 11/02/16 08:06 H60.10EPA 9045
Sulfate 93.6 mg/kg 11/02/16 03:1055.4EPA 9056
92317218020 2016034386
Aluminum 21000 mg/kg 11/02/16 08:216.4EPA 6010
Barium 87.1 mg/kg 11/02/16 08:210.64EPA 6010
Beryllium 0.68 mg/kg 11/02/16 08:210.064EPA 6010
Calcium 461 mg/kg 11/02/16 08:2132.0EPA 6010
Chromium 14.8 mg/kg 11/02/16 08:210.32EPA 6010
Copper 19.5 mg/kg 11/02/16 08:210.32EPA 6010
Iron 24600 mg/kg 11/02/16 21:0912.8EPA 6010
Magnesium 1240 mg/kg 11/02/16 08:2132.0EPA 6010
Manganese 140 mg/kg 11/02/16 08:210.32EPA 6010
Molybdenum 0.75 mg/kg 11/02/16 08:210.64EPA 6010
Nickel 6.9 mg/kg 11/02/16 08:210.32EPA 6010
Potassium 1080 mg/kg 11/02/16 08:2164.0EPA 6010
Silver 0.68 mg/kg 11/02/16 08:210.32EPA 6010
Strontium 12.2 mg/kg 11/02/16 08:210.64EPA 6010
Zinc 27.1 mg/kg 11/02/16 08:211.3EPA 6010
Cobalt 6.3 mg/kg 11/02/16 15:321.3EPA 6020
Lead 14.6 mg/kg 11/02/16 15:321.3EPA 6020
Vanadium 38.3 mg/kg 11/02/16 15:321.3EPA 6020
Mercury 0.022 mg/kg 11/01/16 20:230.010EPA 7471
Percent Moisture 16.9 % 11/01/16 04:260.10ASTM D2974-87
pH at 25 Degrees C 5.5 Std. Units 11/02/16 08:06 H60.10EPA 9045
Sulfate 75.3 mg/kg 11/02/16 03:3260.1EPA 9056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 90
Page 41 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 6010
Date:November 10, 2016
Description:6010 MET ICP
General Information:
20 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 329317
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92317218001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1758984)
• Aluminum
• Barium
• Boron
• Iron
• Magnesium
• Potassium
• Zinc
• MSD (Lab ID: 1758985)
• Aluminum
• Barium
• Beryllium
• Boron
• Iron
• Potassium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 90
Page 42 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 6010
Date:November 10, 2016
Description:6010 MET ICP
QC Batch: 329508
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35271650056
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1760384)
• Aluminum
• Calcium
• Iron
• Strontium
• MSD (Lab ID: 1760385)
• Aluminum
• Calcium
• Iron
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1760385)
• Calcium
• Strontium
Additional Comments:
Analyte Comments:
QC Batch: 329317
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2016034353 (Lab ID: 92317218001)
• Boron
• 2016034368 (Lab ID: 92317218002)
• Boron
• 2016034369 (Lab ID: 92317218003)
• Boron
• 2016034370 (Lab ID: 92317218004)
• Boron
• 2016034371 (Lab ID: 92317218005)
• Boron
• 2016034372 (Lab ID: 92317218006)
• Beryllium
• 2016034373 (Lab ID: 92317218007)
• Beryllium
• 2016034382 (Lab ID: 92317218016)
• Beryllium
• 2016034383 (Lab ID: 92317218017)
• Boron
• 2016034384 (Lab ID: 92317218018)
• Boron
• Beryllium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 90
Page 43 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 6010
Date:November 10, 2016
Description:6010 MET ICP
Analyte Comments:
QC Batch: 329317
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2016034385 (Lab ID: 92317218019)
• Boron
• 2016034386 (Lab ID: 92317218020)
• Boron
QC Batch: 329508
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2016034379 (Lab ID: 92317218013)
• Beryllium
• 2016034380 (Lab ID: 92317218014)
• Beryllium
• 2016034381 (Lab ID: 92317218015)
• Beryllium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 90
Page 44 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 6020
Date:November 10, 2016
Description:6020 MET ICPMS
General Information:
20 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 329318
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92317218002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1758988)
• Antimony
• MSD (Lab ID: 1758989)
• Antimony
• Vanadium
QC Batch: 329511
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92317218008
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1760398)
• Antimony
• Cobalt
• Lead
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 90
Page 45 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 6020
Date:November 10, 2016
Description:6020 MET ICPMS
QC Batch: 329511
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92317218008
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Vanadium
• MSD (Lab ID: 1760399)
• Antimony
• Cobalt
• Vanadium
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• QC Batch: 329476
• QC Batch: 329584
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 90
Page 46 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 7471
Date:November 10, 2016
Description:7471 Mercury
General Information:
20 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 328733
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35272923001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1755315)
• Mercury
R1: RPD value was outside control limits.
• MSD (Lab ID: 1755315)
• Mercury
QC Batch: 329227
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35272675006
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1758588)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 90
Page 47 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 9045
Date:November 10, 2016
Description:9045 pH Soil
General Information:
20 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H6: Analysis initiated outside of the 15 minute EPA required holding time.
• 2016034353 (Lab ID: 92317218001)
• 2016034368 (Lab ID: 92317218002)
• 2016034369 (Lab ID: 92317218003)
• 2016034370 (Lab ID: 92317218004)
• 2016034371 (Lab ID: 92317218005)
• 2016034372 (Lab ID: 92317218006)
• 2016034373 (Lab ID: 92317218007)
• 2016034374 (Lab ID: 92317218008)
• 2016034375 (Lab ID: 92317218009)
• 2016034376 (Lab ID: 92317218010)
• 2016034377 (Lab ID: 92317218011)
• 2016034378 (Lab ID: 92317218012)
• 2016034379 (Lab ID: 92317218013)
• 2016034380 (Lab ID: 92317218014)
• 2016034381 (Lab ID: 92317218015)
• 2016034382 (Lab ID: 92317218016)
• 2016034383 (Lab ID: 92317218017)
• 2016034384 (Lab ID: 92317218018)
• 2016034385 (Lab ID: 92317218019)
• 2016034386 (Lab ID: 92317218020)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 90
Page 48 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 7199
Date:November 10, 2016
Description:7199 Hexavalent Chromium Soil
General Information:
20 samples were analyzed for EPA 7199. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3060 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 328536
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92317218001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1754028)
• Chromium, Hexavalent
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 90
Page 49 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 9056
Date:November 10, 2016
Description:9056 IC Anions
General Information:
20 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 90
Page 50 of 127
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92317218
J16100606
Method:
Client:Duke Energy
EPA 9056
Date:November 10, 2016
Description:9056 IC Anions 48hr
General Information:
20 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• 2016034353 (Lab ID: 92317218001)
• 2016034368 (Lab ID: 92317218002)
• 2016034369 (Lab ID: 92317218003)
• 2016034370 (Lab ID: 92317218004)
• 2016034371 (Lab ID: 92317218005)
• 2016034372 (Lab ID: 92317218006)
• 2016034373 (Lab ID: 92317218007)
• 2016034374 (Lab ID: 92317218008)
• 2016034375 (Lab ID: 92317218009)
• 2016034376 (Lab ID: 92317218010)
• 2016034377 (Lab ID: 92317218011)
• 2016034378 (Lab ID: 92317218012)
• 2016034379 (Lab ID: 92317218013)
• 2016034380 (Lab ID: 92317218014)
• 2016034381 (Lab ID: 92317218015)
• 2016034382 (Lab ID: 92317218016)
• 2016034383 (Lab ID: 92317218017)
• 2016034384 (Lab ID: 92317218018)
• 2016034385 (Lab ID: 92317218019)
• 2016034386 (Lab ID: 92317218020)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 90
Page 51 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034353 Lab ID: 92317218001 Collected: 10/18/16 12:45 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 15700 mg/kg 11/02/16 07:15 7429-90-5 M111/01/16 13:175.1 1
Barium 71.7 mg/kg 11/02/16 07:15 7440-39-3 M111/01/16 13:170.51 1
Beryllium 0.58 mg/kg 11/02/16 07:15 7440-41-7 M111/01/16 13:170.051 1
Boron ND mg/kg 11/05/16 21:12 7440-42-8 D3,M111/01/16 13:1725.5 10
Calcium 484 mg/kg 11/02/16 07:15 7440-70-211/01/16 13:1725.5 1
Chromium 14.9 mg/kg 11/02/16 07:15 7440-47-311/01/16 13:170.26 1
Copper 25.6 mg/kg 11/02/16 07:15 7440-50-811/01/16 13:170.26 1
Iron 25300 mg/kg 11/02/16 20:18 7439-89-6 M111/01/16 13:1710.2 5
Magnesium 3470 mg/kg 11/02/16 07:15 7439-95-4 M111/01/16 13:1725.5 1
Manganese 54.7 mg/kg 11/02/16 07:15 7439-96-511/01/16 13:170.26 1
Molybdenum 0.77 mg/kg 11/02/16 07:15 7439-98-711/01/16 13:170.51 1
Nickel 11.5 mg/kg 11/02/16 07:15 7440-02-011/01/16 13:170.26 1
Potassium 1570 mg/kg 11/02/16 07:15 7440-09-7 M111/01/16 13:1751.0 1
Silver 0.54 mg/kg 11/02/16 07:15 7440-22-411/01/16 13:170.26 1
Sodium 163 mg/kg 11/02/16 07:15 7440-23-511/01/16 13:1751.0 1
Strontium 14.3 mg/kg 11/02/16 07:15 7440-24-611/01/16 13:170.51 1
Zinc 50.0 mg/kg 11/02/16 07:15 7440-66-6 M111/01/16 13:171.0 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 14:27 7440-36-0 N211/01/16 13:172.0 20
Arsenic ND mg/kg 11/03/16 19:48 7440-38-211/01/16 13:172.6 50
Cadmium ND mg/kg 11/02/16 14:27 7440-43-911/01/16 13:170.12 20
Cobalt 7.0 mg/kg 11/03/16 19:48 7440-48-411/01/16 13:172.6 50
Lead 14.0 mg/kg 11/02/16 14:27 7439-92-111/01/16 13:171.0 20
Selenium 2.7 mg/kg 11/03/16 19:48 7782-49-211/01/16 13:172.6 50
Thallium ND mg/kg 11/02/16 14:27 7440-28-011/01/16 13:171.0 20
Vanadium 28.0 mg/kg 11/03/16 19:48 7440-62-211/01/16 13:172.6 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 10/30/16 22:23 7439-97-610/28/16 06:330.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 9.8 % 11/01/16 04:240.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.9 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 19:44 18540-29-9 M111/02/16 11:500.70 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 11:14 16887-00-655.3 1
Sulfate ND mg/kg 10/27/16 11:14 14808-79-855.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 90
Page 52 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034353 Lab ID: 92317218001 Collected: 10/18/16 12:45 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 11:14 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 90
Page 53 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034368 Lab ID: 92317218002 Collected: 10/20/16 08:10 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 16000 mg/kg 11/02/16 07:31 7429-90-511/01/16 13:176.2 1
Barium 85.1 mg/kg 11/02/16 07:31 7440-39-311/01/16 13:170.62 1
Beryllium 0.70 mg/kg 11/02/16 07:31 7440-41-711/01/16 13:170.062 1
Boron ND mg/kg 11/05/16 21:16 7440-42-8 D311/01/16 13:1731.2 10
Calcium 629 mg/kg 11/02/16 07:31 7440-70-211/01/16 13:1731.2 1
Chromium 13.1 mg/kg 11/02/16 07:31 7440-47-311/01/16 13:170.31 1
Copper 12.4 mg/kg 11/02/16 07:31 7440-50-811/01/16 13:170.31 1
Iron 33600 mg/kg 11/02/16 20:21 7439-89-611/01/16 13:1712.5 5
Magnesium 4000 mg/kg 11/02/16 07:31 7439-95-411/01/16 13:1731.2 1
Manganese 103 mg/kg 11/02/16 07:31 7439-96-511/01/16 13:170.31 1
Molybdenum 0.87 mg/kg 11/02/16 07:31 7439-98-711/01/16 13:170.62 1
Nickel 19.1 mg/kg 11/02/16 07:31 7440-02-011/01/16 13:170.31 1
Potassium 650 mg/kg 11/02/16 07:31 7440-09-711/01/16 13:1762.4 1
Silver 0.55 mg/kg 11/02/16 07:31 7440-22-411/01/16 13:170.31 1
Sodium 188 mg/kg 11/02/16 07:31 7440-23-511/01/16 13:1762.4 1
Strontium 18.1 mg/kg 11/02/16 07:31 7440-24-611/01/16 13:170.62 1
Zinc 47.8 mg/kg 11/02/16 07:31 7440-66-611/01/16 13:171.2 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 14:29 7440-36-0 M6,N211/01/16 13:172.5 20
Arsenic 1.4 mg/kg 11/02/16 14:29 7440-38-211/01/16 13:171.2 20
Cadmium ND mg/kg 11/02/16 14:29 7440-43-911/01/16 13:170.15 20
Cobalt 8.4 mg/kg 11/02/16 14:29 7440-48-411/01/16 13:171.2 20
Lead 17.0 mg/kg 11/02/16 14:29 7439-92-111/01/16 13:171.2 20
Selenium 1.9 mg/kg 11/02/16 14:29 7782-49-211/01/16 13:171.2 20
Thallium ND mg/kg 11/02/16 14:29 7440-28-011/01/16 13:171.2 20
Vanadium 26.2 mg/kg 11/02/16 14:29 7440-62-2 M611/01/16 13:171.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 10/30/16 22:30 7439-97-610/28/16 06:330.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 10.2 % 11/01/16 04:240.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.4 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 20:49 18540-29-911/02/16 11:500.71 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 12:20 16887-00-655.0 1
Sulfate ND mg/kg 10/27/16 12:20 14808-79-855.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 90
Page 54 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034368 Lab ID: 92317218002 Collected: 10/20/16 08:10 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 12:20 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 90
Page 55 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034369 Lab ID: 92317218003 Collected: 10/20/16 08:52 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 13200 mg/kg 11/02/16 07:36 7429-90-511/01/16 13:175.9 1
Barium 76.7 mg/kg 11/02/16 07:36 7440-39-311/01/16 13:170.59 1
Beryllium 0.67 mg/kg 11/02/16 07:36 7440-41-711/01/16 13:170.059 1
Boron ND mg/kg 11/05/16 21:20 7440-42-8 D311/01/16 13:1729.5 10
Calcium 486 mg/kg 11/02/16 07:36 7440-70-211/01/16 13:1729.5 1
Chromium 9.9 mg/kg 11/02/16 07:36 7440-47-311/01/16 13:170.29 1
Copper 15.3 mg/kg 11/02/16 07:36 7440-50-811/01/16 13:170.29 1
Iron 22700 mg/kg 11/02/16 20:25 7439-89-611/01/16 13:1711.8 5
Magnesium 2280 mg/kg 11/02/16 07:36 7439-95-411/01/16 13:1729.5 1
Manganese 305 mg/kg 11/02/16 07:36 7439-96-511/01/16 13:170.29 1
Molybdenum ND mg/kg 11/02/16 07:36 7439-98-711/01/16 13:170.59 1
Nickel 12.5 mg/kg 11/02/16 07:36 7440-02-011/01/16 13:170.29 1
Potassium 824 mg/kg 11/02/16 07:36 7440-09-711/01/16 13:1759.0 1
Silver 0.46 mg/kg 11/02/16 07:36 7440-22-411/01/16 13:170.29 1
Sodium 76.8 mg/kg 11/02/16 07:36 7440-23-511/01/16 13:1759.0 1
Strontium 14.3 mg/kg 11/02/16 07:36 7440-24-611/01/16 13:170.59 1
Zinc 37.2 mg/kg 11/02/16 07:36 7440-66-611/01/16 13:171.2 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 14:40 7440-36-0 N211/01/16 13:172.4 20
Arsenic 1.3 mg/kg 11/02/16 14:40 7440-38-211/01/16 13:171.2 20
Cadmium ND mg/kg 11/02/16 14:40 7440-43-911/01/16 13:170.14 20
Cobalt 13.5 mg/kg 11/02/16 14:40 7440-48-411/01/16 13:171.2 20
Lead 11.7 mg/kg 11/02/16 14:40 7439-92-111/01/16 13:171.2 20
Selenium 1.4 mg/kg 11/02/16 14:40 7782-49-211/01/16 13:171.2 20
Thallium ND mg/kg 11/02/16 14:40 7440-28-011/01/16 13:171.2 20
Vanadium 21.4 mg/kg 11/02/16 14:40 7440-62-211/01/16 13:171.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 10/30/16 22:32 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 12.5 % 11/01/16 04:240.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.2 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 21:02 18540-29-911/02/16 11:500.71 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 12:42 16887-00-657.0 1
Sulfate ND mg/kg 10/27/16 12:42 14808-79-857.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 90
Page 56 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034369 Lab ID: 92317218003 Collected: 10/20/16 08:52 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 12:42 14797-55-8 H35.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 90
Page 57 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034370 Lab ID: 92317218004 Collected: 10/20/16 10:29 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 17900 mg/kg 11/02/16 07:48 7429-90-511/01/16 13:176.5 1
Barium 63.9 mg/kg 11/02/16 07:48 7440-39-311/01/16 13:170.65 1
Beryllium 0.75 mg/kg 11/02/16 07:48 7440-41-711/01/16 13:170.065 1
Boron ND mg/kg 11/05/16 21:24 7440-42-8 D311/01/16 13:1732.5 10
Calcium 182 mg/kg 11/02/16 07:48 7440-70-211/01/16 13:1732.5 1
Chromium 20.9 mg/kg 11/02/16 07:48 7440-47-311/01/16 13:170.33 1
Copper 14.2 mg/kg 11/02/16 07:48 7440-50-811/01/16 13:170.33 1
Iron 31100 mg/kg 11/02/16 20:29 7439-89-611/01/16 13:1713.0 5
Magnesium 1090 mg/kg 11/02/16 07:48 7439-95-411/01/16 13:1732.5 1
Manganese 2450 mg/kg 11/05/16 21:24 7439-96-511/01/16 13:173.3 10
Molybdenum 2.4 mg/kg 11/02/16 07:48 7439-98-711/01/16 13:170.65 1
Nickel 8.0 mg/kg 11/02/16 07:48 7440-02-011/01/16 13:170.33 1
Potassium 662 mg/kg 11/02/16 07:48 7440-09-711/01/16 13:1765.1 1
Silver 0.88 mg/kg 11/02/16 07:48 7440-22-411/01/16 13:170.33 1
Sodium ND mg/kg 11/02/16 07:48 7440-23-511/01/16 13:1765.1 1
Strontium 14.8 mg/kg 11/02/16 07:48 7440-24-611/01/16 13:170.65 1
Zinc 32.6 mg/kg 11/02/16 07:48 7440-66-611/01/16 13:171.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 14:42 7440-36-0 N211/01/16 13:172.6 20
Arsenic 7.2 mg/kg 11/02/16 14:42 7440-38-211/01/16 13:171.3 20
Cadmium ND mg/kg 11/02/16 14:42 7440-43-911/01/16 13:170.16 20
Cobalt 79.1 mg/kg 11/02/16 14:42 7440-48-411/01/16 13:171.3 20
Lead 39.0 mg/kg 11/02/16 14:42 7439-92-111/01/16 13:171.3 20
Selenium ND mg/kg 11/02/16 14:42 7782-49-211/01/16 13:171.3 20
Thallium ND mg/kg 11/02/16 14:42 7440-28-011/01/16 13:171.3 20
Vanadium 42.0 mg/kg 11/02/16 14:42 7440-62-211/01/16 13:171.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.045 mg/kg 10/30/16 22:34 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 12.3 % 11/01/16 04:240.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.6 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent 0.90 mg/kg 11/03/16 21:41 18540-29-911/02/16 11:500.72 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 13:04 16887-00-657.0 1
Sulfate ND mg/kg 10/27/16 13:04 14808-79-857.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 90
Page 58 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034370 Lab ID: 92317218004 Collected: 10/20/16 10:29 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 13:04 14797-55-8 H35.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 90
Page 59 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034371 Lab ID: 92317218005 Collected: 10/20/16 10:57 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 23300 mg/kg 11/02/16 07:52 7429-90-511/01/16 13:177.3 1
Barium 41.5 mg/kg 11/02/16 07:52 7440-39-311/01/16 13:170.73 1
Beryllium 0.30 mg/kg 11/02/16 07:52 7440-41-711/01/16 13:170.073 1
Boron ND mg/kg 11/05/16 21:37 7440-42-8 D311/01/16 13:1736.7 10
Calcium 348 mg/kg 11/02/16 07:52 7440-70-211/01/16 13:1736.7 1
Chromium 19.0 mg/kg 11/02/16 07:52 7440-47-311/01/16 13:170.37 1
Copper 18.8 mg/kg 11/02/16 07:52 7440-50-811/01/16 13:170.37 1
Iron 33700 mg/kg 11/02/16 20:34 7439-89-611/01/16 13:1714.7 5
Magnesium 2080 mg/kg 11/02/16 07:52 7439-95-411/01/16 13:1736.7 1
Manganese 26.5 mg/kg 11/02/16 07:52 7439-96-511/01/16 13:170.37 1
Molybdenum 2.1 mg/kg 11/02/16 07:52 7439-98-711/01/16 13:170.73 1
Nickel 6.2 mg/kg 11/02/16 07:52 7440-02-011/01/16 13:170.37 1
Potassium 1020 mg/kg 11/02/16 07:52 7440-09-711/01/16 13:1773.5 1
Silver 1.0 mg/kg 11/02/16 07:52 7440-22-411/01/16 13:170.37 1
Sodium 185 mg/kg 11/02/16 07:52 7440-23-511/01/16 13:1773.5 1
Strontium 16.7 mg/kg 11/02/16 07:52 7440-24-611/01/16 13:170.73 1
Zinc 26.4 mg/kg 11/02/16 07:52 7440-66-611/01/16 13:171.5 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:14 7440-36-0 N211/01/16 13:172.9 20
Arsenic 5.3 mg/kg 11/02/16 15:14 7440-38-211/01/16 13:171.5 20
Cadmium ND mg/kg 11/02/16 15:14 7440-43-911/01/16 13:170.18 20
Cobalt 3.0 mg/kg 11/02/16 15:14 7440-48-411/01/16 13:171.5 20
Lead 12.6 mg/kg 11/02/16 15:14 7439-92-111/01/16 13:171.5 20
Selenium ND mg/kg 11/02/16 15:14 7782-49-211/01/16 13:171.5 20
Thallium ND mg/kg 11/02/16 15:14 7440-28-011/01/16 13:171.5 20
Vanadium 45.5 mg/kg 11/02/16 15:14 7440-62-211/01/16 13:171.5 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.031 mg/kg 10/30/16 22:36 7439-97-610/28/16 06:330.012 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 17.8 % 11/01/16 04:240.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.5 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 21:54 18540-29-911/02/16 11:500.79 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 13:26 16887-00-660.9 1
Sulfate 95.3 mg/kg 10/27/16 13:26 14808-79-860.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 90
Page 60 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034371 Lab ID: 92317218005 Collected: 10/20/16 10:57 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 13:26 14797-55-8 H36.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 90
Page 61 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034372 Lab ID: 92317218006 Collected: 10/20/16 13:15 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 19000 mg/kg 11/02/16 20:46 7429-90-511/01/16 13:1727.3 5
Barium 77.3 mg/kg 11/02/16 20:46 7440-39-311/01/16 13:172.7 5
Beryllium 2.0 mg/kg 11/02/16 20:46 7440-41-7 D311/01/16 13:170.27 5
Boron ND mg/kg 11/07/16 08:55 7440-42-811/01/16 13:1754.7 20
Calcium 1860 mg/kg 11/02/16 20:46 7440-70-211/01/16 13:17137 5
Chromium 18.6 mg/kg 11/02/16 20:46 7440-47-311/01/16 13:171.4 5
Copper 32.6 mg/kg 11/07/16 08:55 7440-50-811/01/16 13:175.5 20
Iron 34900 mg/kg 11/02/16 20:46 7439-89-611/01/16 13:1710.9 5
Magnesium 5170 mg/kg 11/02/16 20:46 7439-95-411/01/16 13:17137 5
Manganese 208 mg/kg 11/02/16 07:56 7439-96-511/01/16 13:170.27 1
Molybdenum 1.0 mg/kg 11/02/16 07:56 7439-98-711/01/16 13:170.55 1
Nickel 16.6 mg/kg 11/02/16 07:56 7440-02-011/01/16 13:170.27 1
Potassium 1090 mg/kg 11/02/16 20:46 7440-09-711/01/16 13:17273 5
Silver ND mg/kg 11/02/16 20:46 7440-22-411/01/16 13:171.4 5
Sodium ND mg/kg 11/05/16 21:41 7440-23-511/01/16 13:17547 10
Strontium 32.9 mg/kg 11/02/16 20:46 7440-24-611/01/16 13:172.7 5
Zinc 46.0 mg/kg 11/02/16 07:56 7440-66-611/01/16 13:171.1 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:16 7440-36-0 N211/01/16 13:172.2 20
Arsenic 3.8 mg/kg 11/03/16 19:50 7440-38-211/01/16 13:172.7 50
Cadmium ND mg/kg 11/02/16 15:16 7440-43-911/01/16 13:170.13 20
Cobalt 28.2 mg/kg 11/03/16 19:50 7440-48-411/01/16 13:172.7 50
Lead 15.7 mg/kg 11/02/16 15:16 7439-92-111/01/16 13:171.1 20
Selenium 3.6 mg/kg 11/03/16 19:50 7782-49-211/01/16 13:172.7 50
Thallium ND mg/kg 11/02/16 15:16 7440-28-011/01/16 13:171.1 20
Vanadium 36.2 mg/kg 11/03/16 19:50 7440-62-211/01/16 13:172.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 10/30/16 22:38 7439-97-610/28/16 06:330.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.8 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 22:07 18540-29-911/02/16 11:500.80 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 13:48 16887-00-661.8 1
Sulfate ND mg/kg 10/27/16 13:48 14808-79-861.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 90
Page 62 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034372 Lab ID: 92317218006 Collected: 10/20/16 13:15 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 13:48 14797-55-8 H36.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 90
Page 63 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034373 Lab ID: 92317218007 Collected: 10/20/16 15:35 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 38800 mg/kg 11/02/16 20:50 7429-90-511/01/16 13:1733.1 5
Barium 222 mg/kg 11/02/16 08:00 7440-39-311/01/16 13:170.66 1
Beryllium 2.2 mg/kg 11/02/16 20:50 7440-41-7 D311/01/16 13:170.33 5
Boron ND mg/kg 11/07/16 08:59 7440-42-811/01/16 13:1766.2 20
Calcium 1830 mg/kg 11/02/16 08:00 7440-70-211/01/16 13:1733.1 1
Chromium 34.2 mg/kg 11/02/16 20:50 7440-47-311/01/16 13:171.7 5
Copper 78.4 mg/kg 11/07/16 08:59 7440-50-811/01/16 13:176.6 20
Iron 51500 mg/kg 11/02/16 20:50 7439-89-611/01/16 13:1713.2 5
Magnesium 7000 mg/kg 11/02/16 08:00 7439-95-411/01/16 13:1733.1 1
Manganese 1000 mg/kg 11/05/16 21:45 7439-96-511/01/16 13:173.3 10
Molybdenum 3.2 mg/kg 11/02/16 08:00 7439-98-711/01/16 13:170.66 1
Nickel 26.7 mg/kg 11/02/16 08:00 7440-02-011/01/16 13:170.33 1
Potassium 2480 mg/kg 11/02/16 08:00 7440-09-711/01/16 13:1766.2 1
Silver ND mg/kg 11/02/16 20:50 7440-22-411/01/16 13:171.7 5
Sodium 108 mg/kg 11/02/16 08:00 7440-23-511/01/16 13:1766.2 1
Strontium 32.6 mg/kg 11/02/16 08:00 7440-24-611/01/16 13:170.66 1
Zinc 84.6 mg/kg 11/02/16 08:00 7440-66-611/01/16 13:171.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:19 7440-36-0 N211/01/16 13:172.6 20
Arsenic 20.3 mg/kg 11/03/16 19:53 7440-38-211/01/16 13:173.3 50
Cadmium ND mg/kg 11/02/16 15:19 7440-43-911/01/16 13:170.16 20
Cobalt 26.9 mg/kg 11/03/16 19:53 7440-48-411/01/16 13:173.3 50
Lead 25.3 mg/kg 11/02/16 15:19 7439-92-111/01/16 13:171.3 20
Selenium ND mg/kg 11/03/16 19:53 7782-49-211/01/16 13:173.3 50
Thallium ND mg/kg 11/02/16 15:19 7440-28-011/01/16 13:171.3 20
Vanadium 54.6 mg/kg 11/03/16 19:53 7440-62-211/01/16 13:173.3 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.025 mg/kg 10/30/16 22:40 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.5 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 8.3 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 22:20 18540-29-911/02/16 11:500.78 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 14:10 16887-00-661.1 1
Sulfate ND mg/kg 10/27/16 14:10 14808-79-861.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 90
Page 64 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034373 Lab ID: 92317218007 Collected: 10/20/16 15:35 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 14:10 14797-55-8 H36.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 90
Page 65 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034374 Lab ID: 92317218008 Collected: 10/20/16 15:57 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 24400 mg/kg 11/03/16 01:30 7429-90-511/02/16 06:536.3 1
Barium 270 mg/kg 11/03/16 01:30 7440-39-311/02/16 06:530.63 1
Beryllium 2.0 mg/kg 11/05/16 22:46 7440-41-711/02/16 06:530.32 5
Boron ND mg/kg 11/07/16 09:27 7440-42-811/02/16 06:5363.4 20
Calcium 1670 mg/kg 11/03/16 01:30 7440-70-211/02/16 06:5331.7 1
Chromium 34.9 mg/kg 11/05/16 22:46 7440-47-311/02/16 06:531.6 5
Copper 65.2 mg/kg 11/07/16 09:27 7440-50-811/02/16 06:536.3 20
Iron 43100 mg/kg 11/05/16 22:46 7439-89-611/02/16 06:5312.7 5
Magnesium 7240 mg/kg 11/03/16 01:30 7439-95-411/02/16 06:5331.7 1
Manganese 1250 mg/kg 11/05/16 22:46 7439-96-511/02/16 06:531.6 5
Molybdenum 5.7 mg/kg 11/03/16 01:30 7439-98-711/02/16 06:530.63 1
Nickel 25.5 mg/kg 11/03/16 01:30 7440-02-011/02/16 06:530.32 1
Potassium 3230 mg/kg 11/03/16 01:30 7440-09-711/02/16 06:5363.4 1
Silver ND mg/kg 11/05/16 22:46 7440-22-411/02/16 06:531.6 5
Sodium 194 mg/kg 11/03/16 01:30 7440-23-511/02/16 06:5363.4 1
Strontium 31.3 mg/kg 11/03/16 01:30 7440-24-611/02/16 06:530.63 1
Zinc 120 mg/kg 11/05/16 22:46 7440-66-611/02/16 06:536.3 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:12 7440-36-0 M6,N211/02/16 06:532.5 20
Arsenic 7.9 mg/kg 11/03/16 20:12 7440-38-211/02/16 06:531.3 20
Cadmium ND mg/kg 11/03/16 20:12 7440-43-911/02/16 06:530.15 20
Cobalt 39.5 mg/kg 11/03/16 20:12 7440-48-4 M611/02/16 06:531.3 20
Lead 30.3 mg/kg 11/03/16 20:12 7439-92-1 M611/02/16 06:531.3 20
Selenium 2.5 mg/kg 11/03/16 20:12 7782-49-211/02/16 06:531.3 20
Thallium ND mg/kg 11/03/16 20:12 7440-28-011/02/16 06:531.3 20
Vanadium 39.2 mg/kg 11/03/16 20:12 7440-62-2 M611/02/16 06:531.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.021 mg/kg 10/30/16 22:42 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 20.4 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.1 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 22:33 18540-29-911/02/16 11:500.80 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 14:32 16887-00-662.3 1
Sulfate ND mg/kg 10/27/16 14:32 14808-79-862.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 90
Page 66 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034374 Lab ID: 92317218008 Collected: 10/20/16 15:57 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 14:32 14797-55-8 H36.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 90
Page 67 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034375 Lab ID: 92317218009 Collected: 10/20/16 16:42 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 16900 mg/kg 11/03/16 01:34 7429-90-511/02/16 06:536.9 1
Barium 120 mg/kg 11/03/16 01:34 7440-39-311/02/16 06:530.69 1
Beryllium 0.47 mg/kg 11/05/16 22:50 7440-41-711/02/16 06:530.34 5
Boron ND mg/kg 11/05/16 22:50 7440-42-811/02/16 06:5317.2 5
Calcium 1020 mg/kg 11/03/16 01:34 7440-70-211/02/16 06:5334.4 1
Chromium 17.2 mg/kg 11/03/16 01:34 7440-47-311/02/16 06:530.34 1
Copper 12.5 mg/kg 11/03/16 01:34 7440-50-811/02/16 06:530.34 1
Iron 16900 mg/kg 11/05/16 22:50 7439-89-611/02/16 06:5313.8 5
Magnesium 2950 mg/kg 11/03/16 01:34 7439-95-411/02/16 06:5334.4 1
Manganese 95.4 mg/kg 11/03/16 01:34 7439-96-511/02/16 06:530.34 1
Molybdenum 0.94 mg/kg 11/03/16 01:34 7439-98-711/02/16 06:530.69 1
Nickel 11.2 mg/kg 11/03/16 01:34 7440-02-011/02/16 06:530.34 1
Potassium 481 mg/kg 11/03/16 01:34 7440-09-711/02/16 06:5368.8 1
Silver 0.49 mg/kg 11/03/16 01:34 7440-22-411/02/16 06:530.34 1
Sodium 225 mg/kg 11/03/16 01:34 7440-23-511/02/16 06:5368.8 1
Strontium 20.8 mg/kg 11/03/16 01:34 7440-24-611/02/16 06:530.69 1
Zinc 27.8 mg/kg 11/05/16 22:50 7440-66-611/02/16 06:536.9 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:22 7440-36-0 N211/02/16 06:532.8 20
Arsenic 2.9 mg/kg 11/03/16 20:22 7440-38-211/02/16 06:531.4 20
Cadmium ND mg/kg 11/03/16 20:22 7440-43-911/02/16 06:530.17 20
Cobalt 4.9 mg/kg 11/03/16 20:22 7440-48-411/02/16 06:531.4 20
Lead 9.9 mg/kg 11/03/16 20:22 7439-92-111/02/16 06:531.4 20
Selenium ND mg/kg 11/03/16 20:22 7782-49-211/02/16 06:531.4 20
Thallium ND mg/kg 11/03/16 20:22 7440-28-011/02/16 06:531.4 20
Vanadium 27.4 mg/kg 11/03/16 20:22 7440-62-211/02/16 06:531.4 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 10/30/16 22:44 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.2 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.0 Std. Units 10/27/16 11:30 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 22:46 18540-29-911/02/16 11:500.74 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 15:38 16887-00-657.5 1
Sulfate ND mg/kg 10/27/16 15:38 14808-79-857.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 90
Page 68 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034375 Lab ID: 92317218009 Collected: 10/20/16 16:42 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 15:38 14797-55-8 H35.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 90
Page 69 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034376 Lab ID: 92317218010 Collected: 10/21/16 09:00 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 48900 mg/kg 11/05/16 22:54 7429-90-511/02/16 06:5340.1 5
Barium 212 mg/kg 11/03/16 01:38 7440-39-311/02/16 06:530.80 1
Beryllium 1.7 mg/kg 11/05/16 22:54 7440-41-711/02/16 06:530.40 5
Boron ND mg/kg 11/07/16 09:31 7440-42-811/02/16 06:5380.3 20
Calcium 1480 mg/kg 11/03/16 01:38 7440-70-211/02/16 06:5340.1 1
Chromium 41.4 mg/kg 11/05/16 22:54 7440-47-311/02/16 06:532.0 5
Copper 72.0 mg/kg 11/07/16 09:31 7440-50-811/02/16 06:538.0 20
Iron 49400 mg/kg 11/05/16 22:54 7439-89-611/02/16 06:5316.1 5
Magnesium 9450 mg/kg 11/03/16 01:38 7439-95-411/02/16 06:5340.1 1
Manganese 1110 mg/kg 11/05/16 22:54 7439-96-511/02/16 06:532.0 5
Molybdenum 2.4 mg/kg 11/03/16 01:38 7439-98-711/02/16 06:530.80 1
Nickel 28.7 mg/kg 11/03/16 01:38 7440-02-011/02/16 06:530.40 1
Potassium 3080 mg/kg 11/03/16 01:38 7440-09-711/02/16 06:5380.3 1
Silver ND mg/kg 11/05/16 22:54 7440-22-411/02/16 06:532.0 5
Sodium 130 mg/kg 11/03/16 01:38 7440-23-511/02/16 06:5380.3 1
Strontium 27.2 mg/kg 11/03/16 01:38 7440-24-611/02/16 06:530.80 1
Zinc 102 mg/kg 11/05/16 22:54 7440-66-611/02/16 06:538.0 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:25 7440-36-0 N211/02/16 06:533.2 20
Arsenic 5.6 mg/kg 11/03/16 20:25 7440-38-211/02/16 06:531.6 20
Cadmium ND mg/kg 11/03/16 20:25 7440-43-911/02/16 06:530.19 20
Cobalt 42.2 mg/kg 11/03/16 20:25 7440-48-411/02/16 06:531.6 20
Lead 26.4 mg/kg 11/03/16 20:25 7439-92-111/02/16 06:531.6 20
Selenium 2.1 mg/kg 11/03/16 20:25 7782-49-211/02/16 06:531.6 20
Thallium ND mg/kg 11/03/16 20:25 7440-28-011/02/16 06:531.6 20
Vanadium 53.1 mg/kg 11/03/16 20:25 7440-62-211/02/16 06:531.6 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.053 mg/kg 10/30/16 22:47 7439-97-610/28/16 06:330.012 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 22.3 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.5 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 22:59 18540-29-911/02/16 11:500.80 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 16:00 16887-00-664.3 1
Sulfate ND mg/kg 10/27/16 16:00 14808-79-864.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 90
Page 70 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034376 Lab ID: 92317218010 Collected: 10/21/16 09:00 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 16:00 14797-55-8 H36.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 90
Page 71 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034377 Lab ID: 92317218011 Collected: 10/21/16 09:51 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 35700 mg/kg 11/05/16 22:58 7429-90-511/02/16 06:5332.6 5
Barium 237 mg/kg 11/03/16 01:42 7440-39-311/02/16 06:530.65 1
Beryllium 1.5 mg/kg 11/05/16 22:58 7440-41-711/02/16 06:530.33 5
Boron ND mg/kg 11/07/16 09:35 7440-42-811/02/16 06:5365.2 20
Calcium 1920 mg/kg 11/03/16 01:42 7440-70-211/02/16 06:5332.6 1
Chromium 42.2 mg/kg 11/05/16 22:58 7440-47-311/02/16 06:531.6 5
Copper 50.8 mg/kg 11/07/16 09:35 7440-50-811/02/16 06:536.5 20
Iron 49800 mg/kg 11/05/16 22:58 7439-89-611/02/16 06:5313.0 5
Magnesium 10800 mg/kg 11/03/16 01:42 7439-95-411/02/16 06:5332.6 1
Manganese 1240 mg/kg 11/05/16 22:58 7439-96-511/02/16 06:531.6 5
Molybdenum 5.4 mg/kg 11/03/16 01:42 7439-98-711/02/16 06:530.65 1
Nickel 31.6 mg/kg 11/03/16 01:42 7440-02-011/02/16 06:530.33 1
Potassium 2010 mg/kg 11/03/16 01:42 7440-09-711/02/16 06:5365.2 1
Silver 1.7 mg/kg 11/05/16 22:58 7440-22-411/02/16 06:531.6 5
Sodium 181 mg/kg 11/03/16 01:42 7440-23-511/02/16 06:5365.2 1
Strontium 31.4 mg/kg 11/03/16 01:42 7440-24-611/02/16 06:530.65 1
Zinc 96.4 mg/kg 11/05/16 22:58 7440-66-611/02/16 06:536.5 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:27 7440-36-0 N211/02/16 06:532.6 20
Arsenic 5.5 mg/kg 11/03/16 20:27 7440-38-211/02/16 06:531.3 20
Cadmium ND mg/kg 11/03/16 20:27 7440-43-911/02/16 06:530.16 20
Cobalt 25.9 mg/kg 11/03/16 20:27 7440-48-411/02/16 06:531.3 20
Lead 19.1 mg/kg 11/03/16 20:27 7439-92-111/02/16 06:531.3 20
Selenium 2.8 mg/kg 11/03/16 20:27 7782-49-211/02/16 06:531.3 20
Thallium ND mg/kg 11/03/16 20:27 7440-28-011/02/16 06:531.3 20
Vanadium 66.5 mg/kg 11/03/16 20:27 7440-62-211/02/16 06:531.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.018 mg/kg 10/30/16 22:49 7439-97-610/28/16 06:330.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.7 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.6 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 23:12 18540-29-911/02/16 11:500.76 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 16:22 16887-00-659.0 1
Sulfate ND mg/kg 10/27/16 16:22 14808-79-859.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 90
Page 72 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034377 Lab ID: 92317218011 Collected: 10/21/16 09:51 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 16:22 14797-55-8 H35.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 90
Page 73 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034378 Lab ID: 92317218012 Collected: 10/21/16 11:06 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 19700 mg/kg 11/03/16 01:46 7429-90-511/02/16 06:536.6 1
Barium 102 mg/kg 11/03/16 01:46 7440-39-311/02/16 06:530.66 1
Beryllium 1.1 mg/kg 11/05/16 23:02 7440-41-711/02/16 06:530.33 5
Boron ND mg/kg 11/07/16 09:39 7440-42-811/02/16 06:5365.7 20
Calcium 429 mg/kg 11/03/16 01:46 7440-70-211/02/16 06:5332.9 1
Chromium 23.8 mg/kg 11/03/16 01:46 7440-47-311/02/16 06:530.33 1
Copper 31.9 mg/kg 11/03/16 01:46 7440-50-811/02/16 06:530.33 1
Iron 38200 mg/kg 11/05/16 23:02 7439-89-611/02/16 06:5313.1 5
Magnesium 2020 mg/kg 11/03/16 01:46 7439-95-411/02/16 06:5332.9 1
Manganese 526 mg/kg 11/03/16 01:46 7439-96-511/02/16 06:530.33 1
Molybdenum 1.6 mg/kg 11/03/16 01:46 7439-98-711/02/16 06:530.66 1
Nickel 11.7 mg/kg 11/03/16 01:46 7440-02-011/02/16 06:530.33 1
Potassium 1360 mg/kg 11/03/16 01:46 7440-09-711/02/16 06:5365.7 1
Silver 1.1 mg/kg 11/03/16 01:46 7440-22-411/02/16 06:530.33 1
Sodium ND mg/kg 11/03/16 01:46 7440-23-511/02/16 06:5365.7 1
Strontium 11.1 mg/kg 11/03/16 01:46 7440-24-611/02/16 06:530.66 1
Zinc 46.1 mg/kg 11/05/16 23:02 7440-66-611/02/16 06:536.6 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:30 7440-36-0 N211/02/16 06:532.6 20
Arsenic 5.0 mg/kg 11/03/16 20:30 7440-38-211/02/16 06:531.3 20
Cadmium ND mg/kg 11/03/16 20:30 7440-43-911/02/16 06:530.16 20
Cobalt 14.4 mg/kg 11/03/16 20:30 7440-48-411/02/16 06:531.3 20
Lead 13.8 mg/kg 11/03/16 20:30 7439-92-111/02/16 06:531.3 20
Selenium 1.4 mg/kg 11/03/16 20:30 7782-49-211/02/16 06:531.3 20
Thallium ND mg/kg 11/03/16 20:30 7440-28-011/02/16 06:531.3 20
Vanadium 39.6 mg/kg 11/03/16 20:30 7440-62-211/02/16 06:531.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.022 mg/kg 10/30/16 22:55 7439-97-610/28/16 06:330.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.7 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.5 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 23:25 18540-29-911/02/16 11:500.74 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 16:44 16887-00-658.3 1
Sulfate ND mg/kg 10/27/16 16:44 14808-79-858.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 90
Page 74 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034378 Lab ID: 92317218012 Collected: 10/21/16 11:06 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 16:44 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 90
Page 75 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034379 Lab ID: 92317218013 Collected: 10/21/16 11:37 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 30400 mg/kg 11/03/16 01:50 7429-90-511/02/16 06:536.9 1
Barium 123 mg/kg 11/03/16 01:50 7440-39-311/02/16 06:530.69 1
Beryllium 1.4 mg/kg 11/05/16 23:22 7440-41-7 D311/02/16 06:530.35 5
Boron ND mg/kg 11/07/16 09:43 7440-42-811/02/16 06:5369.1 20
Calcium 126 mg/kg 11/03/16 01:50 7440-70-211/02/16 06:5334.6 1
Chromium 35.2 mg/kg 11/05/16 23:22 7440-47-311/02/16 06:531.7 5
Copper 50.6 mg/kg 11/05/16 23:22 7440-50-811/02/16 06:531.7 5
Iron 52000 mg/kg 11/05/16 23:22 7439-89-611/02/16 06:5313.8 5
Magnesium 4290 mg/kg 11/03/16 01:50 7439-95-411/02/16 06:5334.6 1
Manganese 540 mg/kg 11/05/16 23:22 7439-96-511/02/16 06:531.7 5
Molybdenum 1.5 mg/kg 11/03/16 01:50 7439-98-711/02/16 06:530.69 1
Nickel 19.6 mg/kg 11/03/16 01:50 7440-02-011/02/16 06:530.35 1
Potassium 1870 mg/kg 11/03/16 01:50 7440-09-711/02/16 06:5369.1 1
Silver 1.8 mg/kg 11/05/16 23:22 7440-22-411/02/16 06:531.7 5
Sodium ND mg/kg 11/03/16 01:50 7440-23-511/02/16 06:5369.1 1
Strontium 16.2 mg/kg 11/03/16 01:50 7440-24-611/02/16 06:530.69 1
Zinc 69.4 mg/kg 11/05/16 23:22 7440-66-611/02/16 06:536.9 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:32 7440-36-0 N211/02/16 06:532.8 20
Arsenic 5.3 mg/kg 11/03/16 20:32 7440-38-211/02/16 06:531.4 20
Cadmium ND mg/kg 11/03/16 20:32 7440-43-911/02/16 06:530.17 20
Cobalt 12.8 mg/kg 11/03/16 20:32 7440-48-411/02/16 06:531.4 20
Lead 15.2 mg/kg 11/03/16 20:32 7439-92-111/02/16 06:531.4 20
Selenium 1.7 mg/kg 11/03/16 20:32 7782-49-211/02/16 06:531.4 20
Thallium ND mg/kg 11/03/16 20:32 7440-28-011/02/16 06:531.4 20
Vanadium 44.8 mg/kg 11/03/16 20:32 7440-62-211/02/16 06:531.4 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.022 mg/kg 10/30/16 22:57 7439-97-610/28/16 06:330.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.1 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/03/16 23:38 18540-29-911/02/16 11:500.77 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 17:06 16887-00-661.0 1
Sulfate ND mg/kg 10/27/16 17:06 14808-79-861.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 90
Page 76 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034379 Lab ID: 92317218013 Collected: 10/21/16 11:37 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 17:06 14797-55-8 H36.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 90
Page 77 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034380 Lab ID: 92317218014 Collected: 10/21/16 12:56 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 37000 mg/kg 11/05/16 23:26 7429-90-511/02/16 06:5335.1 5
Barium 94.0 mg/kg 11/03/16 01:54 7440-39-311/02/16 06:530.70 1
Beryllium 1.5 mg/kg 11/05/16 23:26 7440-41-7 D311/02/16 06:530.35 5
Boron ND mg/kg 11/07/16 09:47 7440-42-811/02/16 06:5370.2 20
Calcium 71.7 mg/kg 11/03/16 01:54 7440-70-211/02/16 06:5335.1 1
Chromium 42.1 mg/kg 11/05/16 23:26 7440-47-311/02/16 06:531.8 5
Copper 61.7 mg/kg 11/05/16 23:26 7440-50-811/02/16 06:531.8 5
Iron 58900 mg/kg 11/05/16 23:26 7439-89-611/02/16 06:5314.0 5
Magnesium 5150 mg/kg 11/03/16 01:54 7439-95-411/02/16 06:5335.1 1
Manganese 340 mg/kg 11/05/16 23:26 7439-96-511/02/16 06:531.8 5
Molybdenum 1.5 mg/kg 11/03/16 01:54 7439-98-711/02/16 06:530.70 1
Nickel 21.8 mg/kg 11/03/16 01:54 7440-02-011/02/16 06:530.35 1
Potassium 2660 mg/kg 11/03/16 01:54 7440-09-711/02/16 06:5370.2 1
Silver 2.3 mg/kg 11/05/16 23:26 7440-22-411/02/16 06:531.8 5
Sodium ND mg/kg 11/03/16 01:54 7440-23-511/02/16 06:5370.2 1
Strontium 6.1 mg/kg 11/03/16 01:54 7440-24-611/02/16 06:530.70 1
Zinc 82.7 mg/kg 11/05/16 23:26 7440-66-611/02/16 06:537.0 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:40 7440-36-0 N211/02/16 06:532.8 20
Arsenic 4.5 mg/kg 11/03/16 20:40 7440-38-211/02/16 06:531.4 20
Cadmium ND mg/kg 11/03/16 20:40 7440-43-911/02/16 06:530.17 20
Cobalt 13.8 mg/kg 11/03/16 20:40 7440-48-411/02/16 06:531.4 20
Lead 15.6 mg/kg 11/03/16 20:40 7439-92-111/02/16 06:531.4 20
Selenium 1.5 mg/kg 11/03/16 20:40 7782-49-211/02/16 06:531.4 20
Thallium ND mg/kg 11/03/16 20:40 7440-28-011/02/16 06:531.4 20
Vanadium 56.1 mg/kg 11/03/16 20:40 7440-62-211/02/16 06:531.4 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.026 mg/kg 11/01/16 19:32 7439-97-611/01/16 05:270.011 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.2 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 00:17 18540-29-911/02/16 11:500.78 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 17:28 16887-00-661.4 1
Sulfate ND mg/kg 10/27/16 17:28 14808-79-861.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 90
Page 78 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034380 Lab ID: 92317218014 Collected: 10/21/16 12:56 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 17:28 14797-55-8 H36.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 90
Page 79 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034381 Lab ID: 92317218015 Collected: 10/21/16 13:35 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 16200 mg/kg 11/03/16 01:58 7429-90-511/02/16 06:535.2 1
Barium 99.3 mg/kg 11/03/16 01:58 7440-39-311/02/16 06:530.52 1
Beryllium 1.0 mg/kg 11/05/16 23:30 7440-41-7 D311/02/16 06:530.26 5
Boron ND mg/kg 11/07/16 09:52 7440-42-811/02/16 06:5351.9 20
Calcium 1000 mg/kg 11/03/16 01:58 7440-70-211/02/16 06:5325.9 1
Chromium 17.6 mg/kg 11/05/16 23:30 7440-47-311/02/16 06:531.3 5
Copper 23.8 mg/kg 11/05/16 23:30 7440-50-811/02/16 06:531.3 5
Iron 28300 mg/kg 11/05/16 23:30 7439-89-611/02/16 06:5310.4 5
Magnesium 1930 mg/kg 11/03/16 01:58 7439-95-411/02/16 06:5325.9 1
Manganese 526 mg/kg 11/05/16 23:30 7439-96-511/02/16 06:531.3 5
Molybdenum 0.70 mg/kg 11/03/16 01:58 7439-98-711/02/16 06:530.52 1
Nickel 12.3 mg/kg 11/03/16 01:58 7440-02-011/02/16 06:530.26 1
Potassium 1430 mg/kg 11/03/16 01:58 7440-09-711/02/16 06:5351.9 1
Silver ND mg/kg 11/05/16 23:30 7440-22-411/02/16 06:531.3 5
Sodium ND mg/kg 11/03/16 01:58 7440-23-511/02/16 06:5351.9 1
Strontium 14.9 mg/kg 11/03/16 01:58 7440-24-611/02/16 06:530.52 1
Zinc 46.6 mg/kg 11/05/16 23:30 7440-66-611/02/16 06:535.2 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/03/16 20:42 7440-36-0 N211/02/16 06:532.1 20
Arsenic 1.8 mg/kg 11/03/16 20:42 7440-38-211/02/16 06:531.0 20
Cadmium ND mg/kg 11/03/16 20:42 7440-43-911/02/16 06:530.12 20
Cobalt 13.7 mg/kg 11/03/16 20:42 7440-48-411/02/16 06:531.0 20
Lead 22.6 mg/kg 11/03/16 20:42 7439-92-111/02/16 06:531.0 20
Selenium 1.7 mg/kg 11/03/16 20:42 7782-49-211/02/16 06:531.0 20
Thallium ND mg/kg 11/03/16 20:42 7440-28-011/02/16 06:531.0 20
Vanadium 29.6 mg/kg 11/03/16 20:42 7440-62-211/02/16 06:531.0 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.016 mg/kg 11/01/16 19:34 7439-97-611/01/16 05:270.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.8 % 11/01/16 04:250.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.5 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 00:30 18540-29-911/02/16 11:500.75 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 17:50 16887-00-657.7 1
Sulfate ND mg/kg 10/27/16 17:50 14808-79-857.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 90
Page 80 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034381 Lab ID: 92317218015 Collected: 10/21/16 13:35 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 17:50 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 90
Page 81 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034382 Lab ID: 92317218016 Collected: 10/21/16 14:00 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 11900 mg/kg 11/02/16 08:04 7429-90-511/01/16 13:174.9 1
Barium 86.5 mg/kg 11/02/16 08:04 7440-39-311/01/16 13:170.49 1
Beryllium 0.90 mg/kg 11/02/16 20:54 7440-41-7 D311/01/16 13:170.24 5
Boron ND mg/kg 11/07/16 09:03 7440-42-811/01/16 13:1748.6 20
Calcium 2070 mg/kg 11/02/16 08:04 7440-70-211/01/16 13:1724.3 1
Chromium 14.9 mg/kg 11/02/16 20:54 7440-47-311/01/16 13:171.2 5
Copper 21.6 mg/kg 11/07/16 09:03 7440-50-811/01/16 13:174.9 20
Iron 30500 mg/kg 11/02/16 20:54 7439-89-611/01/16 13:179.7 5
Magnesium 1580 mg/kg 11/02/16 08:04 7439-95-411/01/16 13:1724.3 1
Manganese 317 mg/kg 11/05/16 21:49 7439-96-511/01/16 13:172.4 10
Molybdenum 0.59 mg/kg 11/02/16 08:04 7439-98-711/01/16 13:170.49 1
Nickel 10.0 mg/kg 11/02/16 08:04 7440-02-011/01/16 13:170.24 1
Potassium 1020 mg/kg 11/02/16 08:04 7440-09-711/01/16 13:1748.6 1
Silver ND mg/kg 11/02/16 20:54 7440-22-411/01/16 13:171.2 5
Sodium ND mg/kg 11/02/16 08:04 7440-23-511/01/16 13:1748.6 1
Strontium 22.4 mg/kg 11/02/16 08:04 7440-24-611/01/16 13:170.49 1
Zinc 33.2 mg/kg 11/02/16 08:04 7440-66-611/01/16 13:170.97 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:21 7440-36-0 N211/01/16 13:171.9 20
Arsenic ND mg/kg 11/03/16 19:55 7440-38-211/01/16 13:172.4 50
Cadmium ND mg/kg 11/02/16 15:21 7440-43-911/01/16 13:170.12 20
Cobalt 11.6 mg/kg 11/03/16 19:55 7440-48-411/01/16 13:172.4 50
Lead 18.9 mg/kg 11/02/16 15:21 7439-92-111/01/16 13:170.97 20
Selenium ND mg/kg 11/03/16 19:55 7782-49-211/01/16 13:172.4 50
Thallium ND mg/kg 11/02/16 15:21 7440-28-011/01/16 13:170.97 20
Vanadium 30.6 mg/kg 11/03/16 19:55 7440-62-211/01/16 13:172.4 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.012 mg/kg 11/01/16 19:36 7439-97-611/01/16 05:270.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.3 % 11/01/16 04:260.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 8.1 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 00:43 18540-29-911/02/16 11:500.72 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 18:12 16887-00-657.6 1
Sulfate ND mg/kg 10/27/16 18:12 14808-79-857.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 90
Page 82 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034382 Lab ID: 92317218016 Collected: 10/21/16 14:00 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 18:12 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 90
Page 83 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034383 Lab ID: 92317218017 Collected: 10/21/16 14:25 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 17600 mg/kg 11/02/16 08:09 7429-90-511/01/16 13:176.1 1
Barium 93.1 mg/kg 11/02/16 08:09 7440-39-311/01/16 13:170.61 1
Beryllium 0.88 mg/kg 11/02/16 08:09 7440-41-711/01/16 13:170.061 1
Boron ND mg/kg 11/05/16 21:53 7440-42-8 D311/01/16 13:1730.5 10
Calcium 449 mg/kg 11/02/16 08:09 7440-70-211/01/16 13:1730.5 1
Chromium 15.9 mg/kg 11/02/16 08:09 7440-47-311/01/16 13:170.30 1
Copper 20.5 mg/kg 11/02/16 08:09 7440-50-811/01/16 13:170.30 1
Iron 30900 mg/kg 11/02/16 20:58 7439-89-611/01/16 13:1712.2 5
Magnesium 1690 mg/kg 11/02/16 08:09 7439-95-411/01/16 13:1730.5 1
Manganese 440 mg/kg 11/02/16 08:09 7439-96-511/01/16 13:170.30 1
Molybdenum 0.83 mg/kg 11/02/16 08:09 7439-98-711/01/16 13:170.61 1
Nickel 10.3 mg/kg 11/02/16 08:09 7440-02-011/01/16 13:170.30 1
Potassium 1080 mg/kg 11/02/16 08:09 7440-09-711/01/16 13:1761.0 1
Silver 0.73 mg/kg 11/02/16 08:09 7440-22-411/01/16 13:170.30 1
Sodium ND mg/kg 11/02/16 08:09 7440-23-511/01/16 13:1761.0 1
Strontium 9.0 mg/kg 11/02/16 08:09 7440-24-611/01/16 13:170.61 1
Zinc 38.1 mg/kg 11/02/16 08:09 7440-66-611/01/16 13:171.2 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:24 7440-36-0 N211/01/16 13:172.4 20
Arsenic ND mg/kg 11/04/16 15:24 7440-38-211/01/16 13:173.0 50
Cadmium ND mg/kg 11/02/16 15:24 7440-43-911/01/16 13:170.15 20
Cobalt 12.4 mg/kg 11/04/16 15:24 7440-48-411/01/16 13:173.0 50
Lead 20.7 mg/kg 11/02/16 15:24 7439-92-111/01/16 13:171.2 20
Selenium ND mg/kg 11/04/16 15:24 7782-49-211/01/16 13:173.0 50
Thallium ND mg/kg 11/02/16 15:24 7440-28-011/01/16 13:171.2 20
Vanadium 30.4 mg/kg 11/04/16 15:24 7440-62-211/01/16 13:173.0 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.014 mg/kg 11/01/16 19:38 7439-97-611/01/16 05:270.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 14.7 % 11/01/16 04:260.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.0 Std. Units 10/28/16 09:45 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 00:56 18540-29-911/02/16 11:500.72 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 10/27/16 18:34 16887-00-657.8 1
Sulfate 82.0 mg/kg 10/27/16 18:34 14808-79-857.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 90
Page 84 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034383 Lab ID: 92317218017 Collected: 10/21/16 14:25 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 10/27/16 18:34 14797-55-8 H35.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 90
Page 85 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034384 Lab ID: 92317218018 Collected: 10/21/16 15:31 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 13800 mg/kg 11/02/16 08:13 7429-90-511/01/16 13:175.1 1
Barium 123 mg/kg 11/02/16 08:13 7440-39-311/01/16 13:170.51 1
Beryllium 0.54 mg/kg 11/02/16 21:01 7440-41-7 D311/01/16 13:170.26 5
Boron ND mg/kg 11/05/16 21:57 7440-42-8 D311/01/16 13:1725.6 10
Calcium 874 mg/kg 11/02/16 08:13 7440-70-211/01/16 13:1725.6 1
Chromium 14.4 mg/kg 11/02/16 21:01 7440-47-311/01/16 13:171.3 5
Copper 18.2 mg/kg 11/07/16 09:15 7440-50-811/01/16 13:175.1 20
Iron 18100 mg/kg 11/02/16 21:01 7439-89-611/01/16 13:1710.2 5
Magnesium 1530 mg/kg 11/02/16 08:13 7439-95-411/01/16 13:1725.6 1
Manganese 510 mg/kg 11/05/16 21:57 7439-96-511/01/16 13:172.6 10
Molybdenum ND mg/kg 11/02/16 08:13 7439-98-711/01/16 13:170.51 1
Nickel 9.8 mg/kg 11/02/16 08:13 7440-02-011/01/16 13:170.26 1
Potassium 868 mg/kg 11/02/16 08:13 7440-09-711/01/16 13:1751.1 1
Silver ND mg/kg 11/02/16 21:01 7440-22-411/01/16 13:171.3 5
Sodium ND mg/kg 11/02/16 08:13 7440-23-511/01/16 13:1751.1 1
Strontium 12.6 mg/kg 11/02/16 08:13 7440-24-611/01/16 13:170.51 1
Zinc 29.8 mg/kg 11/02/16 08:13 7440-66-611/01/16 13:171.0 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:26 7440-36-0 N211/01/16 13:172.0 20
Arsenic ND mg/kg 11/03/16 20:00 7440-38-211/01/16 13:172.6 50
Cadmium ND mg/kg 11/02/16 15:26 7440-43-911/01/16 13:170.12 20
Cobalt 10.6 mg/kg 11/03/16 20:00 7440-48-411/01/16 13:172.6 50
Lead 16.2 mg/kg 11/02/16 15:26 7439-92-111/01/16 13:171.0 20
Selenium ND mg/kg 11/03/16 20:00 7782-49-211/01/16 13:172.6 50
Thallium ND mg/kg 11/02/16 15:26 7440-28-011/01/16 13:171.0 20
Vanadium 25.2 mg/kg 11/03/16 20:00 7440-62-211/01/16 13:172.6 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.019 mg/kg 11/01/16 20:19 7439-97-611/01/16 05:270.0098 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 9.3 % 11/01/16 04:260.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 4.7 Std. Units 11/02/16 08:06 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 01:09 18540-29-911/02/16 11:500.68 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 11/02/16 02:48 16887-00-655.2 1
Sulfate 729 mg/kg 11/02/16 02:48 14808-79-855.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 90
Page 86 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034384 Lab ID: 92317218018 Collected: 10/21/16 15:31 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 11/02/16 02:48 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 90
Page 87 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034385 Lab ID: 92317218019 Collected: 10/21/16 16:03 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 14700 mg/kg 11/02/16 08:17 7429-90-511/01/16 13:176.0 1
Barium 110 mg/kg 11/02/16 08:17 7440-39-311/01/16 13:170.60 1
Beryllium 0.66 mg/kg 11/02/16 08:17 7440-41-711/01/16 13:170.060 1
Boron ND mg/kg 11/05/16 22:01 7440-42-8 D311/01/16 13:1729.9 10
Calcium 956 mg/kg 11/02/16 08:17 7440-70-211/01/16 13:1729.9 1
Chromium 12.9 mg/kg 11/02/16 08:17 7440-47-311/01/16 13:170.30 1
Copper 16.5 mg/kg 11/02/16 08:17 7440-50-811/01/16 13:170.30 1
Iron 21500 mg/kg 11/02/16 21:05 7439-89-611/01/16 13:1712.0 5
Magnesium 2000 mg/kg 11/02/16 08:17 7439-95-411/01/16 13:1729.9 1
Manganese 445 mg/kg 11/02/16 08:17 7439-96-511/01/16 13:170.30 1
Molybdenum 0.64 mg/kg 11/02/16 08:17 7439-98-711/01/16 13:170.60 1
Nickel 10.5 mg/kg 11/02/16 08:17 7440-02-011/01/16 13:170.30 1
Potassium 1100 mg/kg 11/02/16 08:17 7440-09-711/01/16 13:1759.9 1
Silver 0.45 mg/kg 11/02/16 08:17 7440-22-411/01/16 13:170.30 1
Sodium ND mg/kg 11/02/16 08:17 7440-23-511/01/16 13:1759.9 1
Strontium 17.4 mg/kg 11/02/16 08:17 7440-24-611/01/16 13:170.60 1
Zinc 38.6 mg/kg 11/02/16 08:17 7440-66-611/01/16 13:171.2 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:29 7440-36-0 N211/01/16 13:172.4 20
Arsenic 1.5 mg/kg 11/02/16 15:29 7440-38-211/01/16 13:171.2 20
Cadmium ND mg/kg 11/02/16 15:29 7440-43-911/01/16 13:170.14 20
Cobalt 10.5 mg/kg 11/02/16 15:29 7440-48-411/01/16 13:171.2 20
Lead 14.8 mg/kg 11/02/16 15:29 7439-92-111/01/16 13:171.2 20
Selenium 1.4 mg/kg 11/02/16 15:29 7782-49-211/01/16 13:171.2 20
Thallium ND mg/kg 11/02/16 15:29 7440-28-011/01/16 13:171.2 20
Vanadium 25.4 mg/kg 11/02/16 15:29 7440-62-211/01/16 13:171.2 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.023 mg/kg 11/01/16 20:21 7439-97-611/01/16 05:270.0082 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 9.7 % 11/01/16 04:260.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.3 Std. Units 11/02/16 08:06 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 01:22 18540-29-911/02/16 11:500.69 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 11/02/16 03:10 16887-00-655.4 1
Sulfate 93.6 mg/kg 11/02/16 03:10 14808-79-855.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 90
Page 88 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034385 Lab ID: 92317218019 Collected: 10/21/16 16:03 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 11/02/16 03:10 14797-55-8 H35.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 90
Page 89 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034386 Lab ID: 92317218020 Collected: 10/21/16 16:38 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 21000 mg/kg 11/02/16 08:21 7429-90-511/01/16 13:176.4 1
Barium 87.1 mg/kg 11/02/16 08:21 7440-39-311/01/16 13:170.64 1
Beryllium 0.68 mg/kg 11/02/16 08:21 7440-41-711/01/16 13:170.064 1
Boron ND mg/kg 11/05/16 22:05 7440-42-8 D311/01/16 13:1732.0 10
Calcium 461 mg/kg 11/02/16 08:21 7440-70-211/01/16 13:1732.0 1
Chromium 14.8 mg/kg 11/02/16 08:21 7440-47-311/01/16 13:170.32 1
Copper 19.5 mg/kg 11/02/16 08:21 7440-50-811/01/16 13:170.32 1
Iron 24600 mg/kg 11/02/16 21:09 7439-89-611/01/16 13:1712.8 5
Magnesium 1240 mg/kg 11/02/16 08:21 7439-95-411/01/16 13:1732.0 1
Manganese 140 mg/kg 11/02/16 08:21 7439-96-511/01/16 13:170.32 1
Molybdenum 0.75 mg/kg 11/02/16 08:21 7439-98-711/01/16 13:170.64 1
Nickel 6.9 mg/kg 11/02/16 08:21 7440-02-011/01/16 13:170.32 1
Potassium 1080 mg/kg 11/02/16 08:21 7440-09-711/01/16 13:1764.0 1
Silver 0.68 mg/kg 11/02/16 08:21 7440-22-411/01/16 13:170.32 1
Sodium ND mg/kg 11/02/16 08:21 7440-23-511/01/16 13:1764.0 1
Strontium 12.2 mg/kg 11/02/16 08:21 7440-24-611/01/16 13:170.64 1
Zinc 27.1 mg/kg 11/02/16 08:21 7440-66-611/01/16 13:171.3 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 11/02/16 15:32 7440-36-0 N211/01/16 13:172.6 20
Arsenic ND mg/kg 11/02/16 15:32 7440-38-211/01/16 13:171.3 20
Cadmium ND mg/kg 11/02/16 15:32 7440-43-911/01/16 13:170.15 20
Cobalt 6.3 mg/kg 11/02/16 15:32 7440-48-411/01/16 13:171.3 20
Lead 14.6 mg/kg 11/02/16 15:32 7439-92-111/01/16 13:171.3 20
Selenium ND mg/kg 11/02/16 15:32 7782-49-211/01/16 13:171.3 20
Thallium ND mg/kg 11/02/16 15:32 7440-28-011/01/16 13:171.3 20
Vanadium 38.3 mg/kg 11/02/16 15:32 7440-62-211/01/16 13:171.3 20
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury 0.022 mg/kg 11/01/16 20:23 7439-97-611/01/16 05:270.010 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.9 % 11/01/16 04:260.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 5.5 Std. Units 11/02/16 08:06 H60.10 1
Analytical Method: EPA 7199 Preparation Method: EPA 30607199 Hexavalent Chromium Soil
Chromium, Hexavalent ND mg/kg 11/04/16 01:35 18540-29-911/02/16 11:500.78 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 11/02/16 03:32 16887-00-660.1 1
Sulfate 75.3 mg/kg 11/02/16 03:32 14808-79-860.1 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 90
Page 90 of 127
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92317218
J16100606
Sample: 2016034386 Lab ID: 92317218020 Collected: 10/21/16 16:38 Received: 10/25/16 11:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 11/02/16 03:32 14797-55-8 H36.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 90
Page 91 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328733
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1755312
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.0085 10/30/16 21:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1755313LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.072.075 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1755314MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35272923001
1755315
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg M1,R1.134 103 80-12058 31 20.1130.14 0.28 0.20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 90
Page 92 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329227
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples: 92317218014, 92317218015, 92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1758583
Associated Lab Samples:92317218014, 92317218015, 92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Mercury mg/kg ND 0.0086 11/01/16 19:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1758584LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.082.092 89 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1758587MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35272675006
1758588
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg M1.118 80 80-12078 17 20.1010.0043U 0.093 0.079
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 90
Page 93 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329317
EPA 3050
EPA 6010
6010 MET Solid
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1758982
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Aluminum mg/kg ND 5.0 11/02/16 19:58
Barium mg/kg ND 0.50 11/02/16 19:58
Beryllium mg/kg ND 0.050 11/02/16 19:58
Boron mg/kg ND 2.5 11/02/16 07:07
Calcium mg/kg ND 25.0 11/02/16 19:58
Chromium mg/kg ND 0.25 11/02/16 19:58
Copper mg/kg ND 0.25 11/02/16 07:07
Iron mg/kg ND 2.0 11/02/16 19:58
Magnesium mg/kg ND 25.0 11/02/16 19:58
Manganese mg/kg ND 0.25 11/02/16 07:07
Molybdenum mg/kg ND 0.50 11/02/16 19:58
Nickel mg/kg ND 0.25 11/02/16 19:58
Potassium mg/kg ND 50.0 11/02/16 19:58
Silver mg/kg ND 0.25 11/02/16 19:58
Sodium mg/kg ND 50.0 11/02/16 07:07
Strontium mg/kg ND 0.50 11/02/16 19:58
Zinc mg/kg ND 1.0 11/02/16 19:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1758983LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/kg 107115 93 80-120
Barium mg/kg 10.511.5 91 80-120
Beryllium mg/kg 1.11.1 97 80-120
Boron mg/kg 104115 90 80-120
Calcium mg/kg 564574 98 80-120
Chromium mg/kg 11.011.5 96 80-120
Copper mg/kg 11.811.5 103 80-120
Iron mg/kg 105115 91 80-120
Magnesium mg/kg 518574 90 80-120
Manganese mg/kg 12.211.5 106 80-120
Molybdenum mg/kg 11.211.5 98 80-120
Nickel mg/kg 11.011.5 96 80-120
Potassium mg/kg 541574 94 80-120
Silver mg/kg 1.01.1 90 80-120
Sodium mg/kg 570574 99 80-120
Strontium mg/kg 9.611.5 83 80-120
Zinc mg/kg 51.157.4 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 90
Page 94 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1758984MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92317218001
1758985
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/kg M1157 4660 75-1254030 6 2014915700 23000 21600
Barium mg/kg M115.7 268 75-125185 14 2014.971.7 114 99.2
Beryllium mg/kg M11.55 77 75-12572 8 201.440.58 1.8 1.7
Boron mg/kg M1157 36 75-12533 15 20149ND 56.3 48.6
Calcium mg/kg 790 93 75-12584 9 20743484 1210 1110
Chromium mg/kg 15.7 97 75-12595 4 2014.914.9 30.2 29.0
Copper mg/kg 15.7 109 75-12588 10 2014.925.6 42.9 38.7
Iron mg/kg M1157 -955 75-1251290 13 2014925300 23800 27300
Magnesium mg/kg M1790 129 75-125124 2 207433470 4490 4390
Manganese mg/kg 15.7 89 75-125113 4 2014.954.7 68.7 71.5
Molybdenum mg/kg 15.7 77 75-12577 5 2014.90.77 12.9 12.3
Nickel mg/kg 15.7 82 75-12586 1 2014.911.5 24.5 24.2
Potassium mg/kg M1790 197 75-125161 12 207431570 3120 2770
Silver mg/kg 1.55 74 75-12582 2 201.440.54 1.7 1.8
Sodium mg/kg 790 87 75-12583 9 20743163 852 781
Strontium mg/kg 15.7 119 75-125110 8 2014.914.3 33.1 30.7
Zinc mg/kg M179 74 75-12577 1 2074.350.0 109 107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 72 of 90
Page 95 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329508
EPA 3050
EPA 6010
6010 MET Solid
Associated Lab Samples:92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1760382
Associated Lab Samples: 92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015
Matrix: Solid
Analyzed
Aluminum mg/kg ND 4.9 11/05/16 22:09
Barium mg/kg ND 0.49 11/05/16 22:09
Beryllium mg/kg ND 0.049 11/05/16 22:09
Boron mg/kg ND 2.4 11/05/16 22:09
Calcium mg/kg ND 24.4 11/05/16 22:09
Chromium mg/kg ND 0.24 11/05/16 22:09
Copper mg/kg ND 0.24 11/03/16 00:05
Iron mg/kg ND 2.0 11/05/16 22:09
Magnesium mg/kg ND 24.4 11/05/16 22:09
Manganese mg/kg ND 0.24 11/05/16 22:09
Molybdenum mg/kg ND 0.49 11/03/16 00:05
Nickel mg/kg ND 0.24 11/05/16 22:09
Potassium mg/kg ND 48.9 11/05/16 22:09
Silver mg/kg ND 0.24 11/03/16 00:05
Sodium mg/kg ND 48.9 11/05/16 22:09
Strontium mg/kg ND 0.49 11/05/16 22:09
Zinc mg/kg ND 0.98 11/05/16 22:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1760383LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/kg 136146 94 80-120
Barium mg/kg 14.214.6 98 80-120
Beryllium mg/kg 1.41.5 93 80-120
Boron mg/kg 121146 83 80-120
Calcium mg/kg 710728 97 80-120
Chromium mg/kg 14.714.6 101 80-120
Copper mg/kg 15.214.6 104 80-120
Iron mg/kg 140146 96 80-120
Magnesium mg/kg 713728 98 80-120
Manganese mg/kg 13.814.6 94 80-120
Molybdenum mg/kg 16.514.6 113 80-120
Nickel mg/kg 14.414.6 99 80-120
Potassium mg/kg 697728 96 80-120
Silver mg/kg 1.41.5 95 80-120
Sodium mg/kg 727728 100 80-120
Strontium mg/kg 14.314.6 98 80-120
Zinc mg/kg 67.272.8 92 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 73 of 90
Page 96 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1760384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35271650056
1760385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/kg M1155 2030 75-1251880 13 201371710 4860 4280
Barium mg/kg 15.5 107 75-125106 12 2013.73.6 20.3 18.0
Beryllium mg/kg 1.51 100 75-125100 13 201.40.54U 1.6 1.4
Boron mg/kg 155 88 75-12591 10 201371.4U 137 124
Calcium mg/kg M1,R1777 -1350 75-125169 122 2068314200 3730 15400
Chromium mg/kg 15.5 119 75-125115 14 2013.72.2 20.7 17.9
Copper mg/kg 15.5 101 75-125104 5 2013.713.5 29.2 27.7
Iron mg/kg M1155 409 75-125347 10 201371120 1750 1590
Magnesium mg/kg 777 110 75-125107 14 2068385.2 937 813
Manganese mg/kg 15.5 121 75-125102 20 2013.78.7 27.5 22.6
Molybdenum mg/kg 15.5 104 75-125104 13 2013.70.27U 16.4 14.4
Nickel mg/kg 15.5 110 75-125107 15 2013.70.52 17.6 15.1
Potassium mg/kg 777 96 75-125113 4 20683543U 822 851
Silver mg/kg 1.51 99 75-125102 10 201.40.14U 1.6 1.4
Sodium mg/kg 777 82 75-125109 13 20683543U 790 896
Strontium mg/kg M1,R115.5 -235 75-12515 66 2013.775.6 39.2 77.7
Zinc mg/kg 77.7 97 75-12597 11 2068.310.9U 82.0 73.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 74 of 90
Page 97 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329318
EPA 3050
EPA 6020
6020 MET SOLID
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1758986
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Antimony mg/kg ND 2.1 N211/02/16 14:22
Arsenic mg/kg ND 1.0 11/02/16 14:22
Cadmium mg/kg ND 0.12 11/02/16 14:22
Cobalt mg/kg ND 1.0 11/02/16 14:22
Lead mg/kg ND 1.0 11/02/16 14:22
Selenium mg/kg ND 1.0 11/02/16 14:22
Thallium mg/kg ND 1.0 11/02/16 14:22
Vanadium mg/kg ND 1.0 11/02/16 14:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1758987LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 25.3 N226.6 95 80-120
Arsenic mg/kg 26.926.6 101 80-120
Cadmium mg/kg 2.72.7 102 80-120
Cobalt mg/kg 27.926.6 105 80-120
Lead mg/kg 26.426.6 99 80-120
Selenium mg/kg 26.726.6 100 80-120
Thallium mg/kg 26.726.6 100 80-120
Vanadium mg/kg 27.126.6 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1758988MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92317218002
1758989
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg M6,N226.1 40 75-12531 9 2030.5ND 10.5 9.6
Arsenic mg/kg 26.1 97 75-12598 16 2030.51.4 26.7 31.3
Cadmium mg/kg 2.56 95 75-12594 14 203.01ND 2.5 2.9
Cobalt mg/kg 26.1 103 75-12599 9 2030.58.4 35.4 38.7
Lead mg/kg 26.1 100 75-12592 4 2030.517.0 43.2 44.8
Selenium mg/kg 26.1 102 75-12599 12 2030.51.9 28.5 32.0
Thallium mg/kg 26.1 99 75-125101 17 2030.5ND 26.0 30.9
Vanadium mg/kg M626.1 122 75-125133 14 2030.526.2 58.0 66.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 75 of 90
Page 98 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329511
EPA 3050
EPA 6020
6020 MET SOLID
Associated Lab Samples:92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1760396
Associated Lab Samples: 92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015
Matrix: Solid
Analyzed
Antimony mg/kg ND 1.8 N211/03/16 20:02
Arsenic mg/kg ND 0.90 11/03/16 20:02
Cadmium mg/kg ND 0.11 11/03/16 20:02
Cobalt mg/kg ND 0.90 11/03/16 20:02
Lead mg/kg ND 0.90 11/03/16 20:02
Selenium mg/kg ND 0.90 11/03/16 20:02
Thallium mg/kg ND 0.90 11/03/16 20:02
Vanadium mg/kg ND 0.90 11/03/16 20:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1760397LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 26.0 N226.8 97 80-120
Arsenic mg/kg 25.126.8 94 80-120
Cadmium mg/kg 2.62.7 96 80-120
Cobalt mg/kg 26.626.8 99 80-120
Lead mg/kg 25.826.8 96 80-120
Selenium mg/kg 25.326.8 94 80-120
Thallium mg/kg 25.526.8 95 80-120
Vanadium mg/kg 26.326.8 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1760398MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92317218008
1760399
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg M6,N235.1 38 75-12541 15 2038.2ND 13.6 15.9
Arsenic mg/kg 35.1 93 75-12586 1 2038.27.9 40.4 40.9
Cadmium mg/kg 3.52 101 75-125100 7 203.77ND 3.6 3.9
Cobalt mg/kg M635.1 58 75-12567 8 2038.239.5 60.0 65.0
Lead mg/kg M635.1 74 75-12583 10 2038.230.3 56.2 62.1
Selenium mg/kg 35.1 81 75-12581 7 2038.22.5 31.0 33.3
Thallium mg/kg 35.1 106 75-125103 6 2038.2ND 37.7 40.0
Vanadium mg/kg M635.1 163 75-125143 3 2038.239.2 96.5 93.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 76 of 90
Page 99 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329222
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35271217001
1758515SAMPLE DUPLICATE:
Percent Moisture % 97.6 0 1097.6
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35272456005
1758516SAMPLE DUPLICATE:
Percent Moisture % 4.1 5 104.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92317218005
1758517SAMPLE DUPLICATE:
Percent Moisture % 18.7 5 1017.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92317218014
1758518SAMPLE DUPLICATE:
Percent Moisture % 19.3 0 1019.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 77 of 90
Page 100 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328536
EPA 3060
EPA 7199
7199 Hexavelent Chromium Soil
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1754025
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017, 92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Chromium, Hexavalent mg/kg ND 0.63 11/03/16 19:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1754026LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent mg/kg 38.039.4 96 75-125
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1754028MATRIX SPIKE SAMPLE:
MSSpike
Result
92317218001
Chromium, Hexavalent mg/kg 16.7 M143.4 38 75-125ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92317218001
1754027SAMPLE DUPLICATE:
Chromium, Hexavalent mg/kg ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 78 of 90
Page 101 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328568
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1754095
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017
Matrix: Solid
Analyzed
Chloride mg/kg ND 49.5 10/27/16 09:24
Sulfate mg/kg ND 49.5 10/27/16 09:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1754096LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/kg 474498 95 80-120
Sulfate mg/kg 469498 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1754098MATRIX SPIKE SAMPLE:
MSSpike
Result
92317218001
Chloride mg/kg 522552 91 80-120ND
Sulfate mg/kg 524552 91 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92317218001
1754097SAMPLE DUPLICATE:
Chloride mg/kg ND 20ND
Sulfate mg/kg ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 79 of 90
Page 102 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329412
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples: 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1759465
Associated Lab Samples:92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Chloride mg/kg ND 50.0 11/01/16 11:45
Sulfate mg/kg ND 50.0 11/01/16 11:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1759466LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/kg 478500 96 80-120
Sulfate mg/kg 473500 95 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 80 of 90
Page 103 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328486
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1753913
Associated Lab Samples: 92317218001, 92317218002, 92317218003, 92317218004, 92317218005, 92317218006, 92317218007,
92317218008, 92317218009, 92317218010, 92317218011, 92317218012, 92317218013, 92317218014,
92317218015, 92317218016, 92317218017
Matrix: Solid
Analyzed
Nitrate as N mg/kg ND 5.0 10/27/16 09:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1753914LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrate as N mg/kg 49.349.8 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1755477MATRIX SPIKE SAMPLE:
MSSpike
Result
92317218001
Nitrate as N mg/kg 53.5 H355.2 97 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92317218001
1755476SAMPLE DUPLICATE:
Nitrate as N mg/kg ND H320ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 81 of 90
Page 104 of 127
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92317218
J16100606
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329274
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples: 92317218018, 92317218019, 92317218020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1758851
Associated Lab Samples:92317218018, 92317218019, 92317218020
Matrix: Solid
Analyzed
Nitrate as N mg/kg ND 5.0 11/01/16 11:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1758852LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrate as N mg/kg 48.950.2 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1758854MATRIX SPIKE SAMPLE:
MSSpike
Result
35273448002
Nitrate as N mg/kg 2770
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
35273448002
1758853SAMPLE DUPLICATE:
Nitrate as N mg/kg ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 82 of 90
Page 105 of 127
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92317218
J16100606
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
BATCH QUALIFIERS
Batch: 329476
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1]
Batch: 329584
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1]
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Sample was received or analysis requested beyond the recognized method holding time.H3
Analysis initiated outside of the 15 minute EPA required holding time.H6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold NELAC/TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 83 of 90
Page 106 of 127
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317218001 329317 3294782016034353EPA 3050 EPA 6010
92317218002 329317 3294782016034368EPA 3050 EPA 6010
92317218003 329317 3294782016034369EPA 3050 EPA 6010
92317218004 329317 3294782016034370EPA 3050 EPA 6010
92317218005 329317 3294782016034371EPA 3050 EPA 6010
92317218006 329317 3294782016034372EPA 3050 EPA 6010
92317218007 329317 3294782016034373EPA 3050 EPA 6010
92317218008 329508 3295852016034374EPA 3050 EPA 6010
92317218009 329508 3295852016034375EPA 3050 EPA 6010
92317218010 329508 3295852016034376EPA 3050 EPA 6010
92317218011 329508 3295852016034377EPA 3050 EPA 6010
92317218012 329508 3295852016034378EPA 3050 EPA 6010
92317218013 329508 3295852016034379EPA 3050 EPA 6010
92317218014 329508 3295852016034380EPA 3050 EPA 6010
92317218015 329508 3295852016034381EPA 3050 EPA 6010
92317218016 329317 3294782016034382EPA 3050 EPA 6010
92317218017 329317 3294782016034383EPA 3050 EPA 6010
92317218018 329317 3294782016034384EPA 3050 EPA 6010
92317218019 329317 3294782016034385EPA 3050 EPA 6010
92317218020 329317 3294782016034386EPA 3050 EPA 6010
92317218001 329318 3294762016034353EPA 3050 EPA 6020
92317218002 329318 3294762016034368EPA 3050 EPA 6020
92317218003 329318 3294762016034369EPA 3050 EPA 6020
92317218004 329318 3294762016034370EPA 3050 EPA 6020
92317218005 329318 3294762016034371EPA 3050 EPA 6020
92317218006 329318 3294762016034372EPA 3050 EPA 6020
92317218007 329318 3294762016034373EPA 3050 EPA 6020
92317218008 329511 3295842016034374EPA 3050 EPA 6020
92317218009 329511 3295842016034375EPA 3050 EPA 6020
92317218010 329511 3295842016034376EPA 3050 EPA 6020
92317218011 329511 3295842016034377EPA 3050 EPA 6020
92317218012 329511 3295842016034378EPA 3050 EPA 6020
92317218013 329511 3295842016034379EPA 3050 EPA 6020
92317218014 329511 3295842016034380EPA 3050 EPA 6020
92317218015 329511 3295842016034381EPA 3050 EPA 6020
92317218016 329318 3294762016034382EPA 3050 EPA 6020
92317218017 329318 3294762016034383EPA 3050 EPA 6020
92317218018 329318 3294762016034384EPA 3050 EPA 6020
92317218019 329318 3294762016034385EPA 3050 EPA 6020
92317218020 329318 3294762016034386EPA 3050 EPA 6020
92317218001 328733 3287752016034353EPA 7471 EPA 7471
92317218002 328733 3287752016034368EPA 7471 EPA 7471
92317218003 328733 3287752016034369EPA 7471 EPA 7471
92317218004 328733 3287752016034370EPA 7471 EPA 7471
92317218005 328733 3287752016034371EPA 7471 EPA 7471
92317218006 328733 3287752016034372EPA 7471 EPA 7471
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 84 of 90
Page 107 of 127
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317218007 328733 3287752016034373EPA 7471 EPA 7471
92317218008 328733 3287752016034374EPA 7471 EPA 7471
92317218009 328733 3287752016034375EPA 7471 EPA 7471
92317218010 328733 3287752016034376EPA 7471 EPA 7471
92317218011 328733 3287752016034377EPA 7471 EPA 7471
92317218012 328733 3287752016034378EPA 7471 EPA 7471
92317218013 328733 3287752016034379EPA 7471 EPA 7471
92317218014 329227 3292562016034380EPA 7471 EPA 7471
92317218015 329227 3292562016034381EPA 7471 EPA 7471
92317218016 329227 3292562016034382EPA 7471 EPA 7471
92317218017 329227 3292562016034383EPA 7471 EPA 7471
92317218018 329227 3292562016034384EPA 7471 EPA 7471
92317218019 329227 3292562016034385EPA 7471 EPA 7471
92317218020 329227 3292562016034386EPA 7471 EPA 7471
92317218001 3292222016034353ASTM D2974-87
92317218002 3292222016034368ASTM D2974-87
92317218003 3292222016034369ASTM D2974-87
92317218004 3292222016034370ASTM D2974-87
92317218005 3292222016034371ASTM D2974-87
92317218006 3292222016034372ASTM D2974-87
92317218007 3292222016034373ASTM D2974-87
92317218008 3292222016034374ASTM D2974-87
92317218009 3292222016034375ASTM D2974-87
92317218010 3292222016034376ASTM D2974-87
92317218011 3292222016034377ASTM D2974-87
92317218012 3292222016034378ASTM D2974-87
92317218013 3292222016034379ASTM D2974-87
92317218014 3292222016034380ASTM D2974-87
92317218015 3292222016034381ASTM D2974-87
92317218016 3292222016034382ASTM D2974-87
92317218017 3292222016034383ASTM D2974-87
92317218018 3292222016034384ASTM D2974-87
92317218019 3292222016034385ASTM D2974-87
92317218020 3292222016034386ASTM D2974-87
92317218001 3284852016034353EPA 9045
92317218002 3284852016034368EPA 9045
92317218003 3284852016034369EPA 9045
92317218004 3284852016034370EPA 9045
92317218005 3284852016034371EPA 9045
92317218006 3284852016034372EPA 9045
92317218007 3284852016034373EPA 9045
92317218008 3284852016034374EPA 9045
92317218009 3284852016034375EPA 9045
92317218010 3287462016034376EPA 9045
92317218011 3287462016034377EPA 9045
92317218012 3287462016034378EPA 9045
92317218013 3287462016034379EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 85 of 90
Page 108 of 127
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317218014 3287462016034380EPA 9045
92317218015 3287462016034381EPA 9045
92317218016 3287462016034382EPA 9045
92317218017 3287462016034383EPA 9045
92317218018 3295412016034384EPA 9045
92317218019 3295412016034385EPA 9045
92317218020 3295412016034386EPA 9045
92317218001 328536 3301472016034353EPA 3060 EPA 7199
92317218002 328536 3301472016034368EPA 3060 EPA 7199
92317218003 328536 3301472016034369EPA 3060 EPA 7199
92317218004 328536 3301472016034370EPA 3060 EPA 7199
92317218005 328536 3301472016034371EPA 3060 EPA 7199
92317218006 328536 3301472016034372EPA 3060 EPA 7199
92317218007 328536 3301472016034373EPA 3060 EPA 7199
92317218008 328536 3301472016034374EPA 3060 EPA 7199
92317218009 328536 3301472016034375EPA 3060 EPA 7199
92317218010 328536 3301472016034376EPA 3060 EPA 7199
92317218011 328536 3301472016034377EPA 3060 EPA 7199
92317218012 328536 3301472016034378EPA 3060 EPA 7199
92317218013 328536 3301472016034379EPA 3060 EPA 7199
92317218014 328536 3301472016034380EPA 3060 EPA 7199
92317218015 328536 3301472016034381EPA 3060 EPA 7199
92317218016 328536 3301472016034382EPA 3060 EPA 7199
92317218017 328536 3301472016034383EPA 3060 EPA 7199
92317218018 328536 3301472016034384EPA 3060 EPA 7199
92317218019 328536 3301472016034385EPA 3060 EPA 7199
92317218020 328536 3301472016034386EPA 3060 EPA 7199
92317218001 3285682016034353EPA 9056
92317218002 3285682016034368EPA 9056
92317218003 3285682016034369EPA 9056
92317218004 3285682016034370EPA 9056
92317218005 3285682016034371EPA 9056
92317218006 3285682016034372EPA 9056
92317218007 3285682016034373EPA 9056
92317218008 3285682016034374EPA 9056
92317218009 3285682016034375EPA 9056
92317218010 3285682016034376EPA 9056
92317218011 3285682016034377EPA 9056
92317218012 3285682016034378EPA 9056
92317218013 3285682016034379EPA 9056
92317218014 3285682016034380EPA 9056
92317218015 3285682016034381EPA 9056
92317218016 3285682016034382EPA 9056
92317218017 3285682016034383EPA 9056
92317218018 3294122016034384EPA 9056
92317218019 3294122016034385EPA 9056
92317218020 3294122016034386EPA 9056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 86 of 90
Page 109 of 127
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92317218
J16100606
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92317218001 3284862016034353EPA 9056
92317218002 3284862016034368EPA 9056
92317218003 3284862016034369EPA 9056
92317218004 3284862016034370EPA 9056
92317218005 3284862016034371EPA 9056
92317218006 3284862016034372EPA 9056
92317218007 3284862016034373EPA 9056
92317218008 3284862016034374EPA 9056
92317218009 3284862016034375EPA 9056
92317218010 3284862016034376EPA 9056
92317218011 3284862016034377EPA 9056
92317218012 3284862016034378EPA 9056
92317218013 3284862016034379EPA 9056
92317218014 3284862016034380EPA 9056
92317218015 3284862016034381EPA 9056
92317218016 3284862016034382EPA 9056
92317218017 3284862016034383EPA 9056
92317218018 3292742016034384EPA 9056
92317218019 3292742016034385EPA 9056
92317218020 3292742016034386EPA 9056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/10/2016 12:31 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 87 of 90
Page 110 of 127
Page 88 of 90
Page 111 of 127
Page 89 of 90
Page 112 of 127
Page 90 of 90
Page 113 of 127