4116_WIHighPointWQMP_DIN27225_20170105

Water Quality Monitoring Plan

WI High Point C&D Landfill
SWS Permit No. 41-16

Prepared for:

WI High Point, LLC
Jamestown, North Carolina
(A Subsidiary of Waste Industries, USA, Inc.)

Revised November 2016
May 2016

Prepared by:

© 2016 Smith Gardner, Inc.
This document is intended for the sole use of the client for which it was prepared and
for the purpose agreed upon by the client and Smith Gardner, Inc.
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Water Quality Monitoring Plan

WI High Point C&D Landfill
Guilford County (SWS Permit No. 41-16)

Prepared For:
WI High Point, LLC
Jamestown, North Carolina
(A Subsidiary of Waste Industries USA, Inc.)

S+G Project No. WI High Point 16-1

Madeline M. German, P.G.
Project Geologist

Joan A. Smyth, P.G.
Senior Hydrogeologist

Revised November 2016
May 2016

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11/23/2016

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WI High Point C&D Landfill Water Quality Monitoring Plan
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WI High Point, LLC
WI High Point C&D Landfill

Water Quality Monitoring Plan

Table of Contents

1.0 INTRODUCTION............................................................................................... 1 
1.1 Site Contact Information ............................................................................... 2 
1.1.1 WI High Point, LLC ............................................................................. 2 
1.1.2 Waste Industries USA, Inc. ................................................................ 2 
1.1.3 Engineer ............................................................................................. 2 
1.1.4 NC Division of Waste Management (DWM) – Solid Waste Section .. 2 
1.1.5 NC Division of Energy, Mineral and Land Resources – Land Quality
Section ........................................................................................................... 3 
1.2 Site Background ............................................................................................ 3 
1.2.1 Geology ............................................................................................... 3 
1.2.2 Hydrogeology ..................................................................................... 4 
2.0 MONITORING PROGRAM ................................................................................. 5 
2.1 Monitoring Network and Analytical Parameters ......................................... 5 
2.2 Groundwater Sample Collection ................................................................... 6 
2.2.1 Guidance Documents ......................................................................... 6 
2.2.2 Fuel Powered Equipment .................................................................. 6 
2.2.3 Equipment Decontamination ............................................................. 7 
2.2.4 Water Level Measurements .............................................................. 8 
2.2.4.1 Static Water Levels ................................................................. 8 
2.2.4.2 Contamination Prevention ...................................................... 8 
2.2.4.3 Equipment ............................................................................... 8 
2.2.5 Monitoring Well Evacuations ............................................................. 9 
2.2.5.1 Contamination Prevention ...................................................... 9 
2.2.5.2 Calculations ............................................................................. 9 
2.2.5.3 Well Purging .......................................................................... 10 
2.2.5.4 Purge Rate ............................................................................. 12 
2.2.5.5 Purge Water Disposal ........................................................... 12 
2.2.5.6 Non-Dedicated Equipment .................................................... 12 
2.2.6 Sample Collection ............................................................................ 13 
2.2.6.1 Field Parameters................................................................... 13 
2.2.6.2 Sample Equipment ................................................................ 14 
2.2.6.3 Sample Transference ............................................................ 14 
2.2.6.4 Sample Collection Order ....................................................... 15 
2.2.6.5 Decontamination ................................................................... 15 
2.2.6.6 Sample Preservation ............................................................. 16 
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2.2.6.7 Field Quality Assurance ........................................................ 16 
2.2.6.8 Sample Containers ................................................................ 16 
2.3 Surface Water Sample Collection ............................................................... 16 
2.3.1 Surface Water Level Observations .................................................. 17 
2.3.1.1 Monitoring Conditions ........................................................... 17 
2.3.1.2 Sampling Station Modifications ............................................ 17 
2.3.2 Sample Collection ............................................................................ 17 
2.3.2.1 Collection Procedure ............................................................ 17 
2.3.2.2 Field Parameters................................................................... 18 
2.3.2.3 Sample Collection Order ....................................................... 18 
2.3.2.4 Decontamination ................................................................... 19 
2.3.2.5 Sample Preservation ............................................................. 19 
2.3.2.6 Field Quality Assurance ........................................................ 19 
2.3.2.7 Sample Containers ................................................................ 19 
3.0 FIELD QA/QC PROGRAM ............................................................................... 20 
3.1 Blank Samples ............................................................................................ 20 
3.1.1 Trip Blanks ....................................................................................... 20 
3.1.2 Equipment Blanks ........................................................................... 20 
3.1.3 Field Blanks ..................................................................................... 20 
3.2 Blank Concentrations ................................................................................. 20 
3.3 Field Instruments ........................................................................................ 21 
4.0 SAMPLE PRESERVATION AND SHIPMENT .................................................... 22 
4.1 Sample Preservation ................................................................................... 22 
4.2 Storage/Transport Conditions .................................................................... 22 
4.3 Sample Delivery .......................................................................................... 22 
4.4 Chain of Custody .......................................................................................... 22 
5.0 FIELD LOGBOOK ........................................................................................... 24 
6.0 LABORATORY ANALYSIS ............................................................................... 25 
6.1 Laboratory Quality Assurance/Quality Control .......................................... 25 
6.2 Laboratory Quality Control Checks ............................................................ 25 
6.3 Data Review ................................................................................................. 25 
7.0 RECORD KEEPING AND REPORTING ............................................................ 26 
7.1 Groundwater System Evaluations .............................................................. 26 
7.2 Reporting ..................................................................................................... 26 
8.0 MONITORING PROGRAM MODIFICATIONS .................................................... 27 
8.1 Well Abandonment/Rehabilitation .............................................................. 27 
8.2 Additional Well Installations ....................................................................... 27 
8.3 Implementation Schedule ........................................................................... 27 

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Figure
Figure 1 – Water Quality Monitoring Location Map

Table
Table 1 –Monitoring Well Construction Details
Table 2 –Water Quality Monitoring Parameters

Appendices
Appendix A – Monitoring Well Logs
Appendix B – Environmental Monitoring Report Form

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1.0 INTRODUCTION
This Water Quality Monitoring Plan (WQMP) is written for the WI High Point, LLC1, WI
High Point C&D Landfill Facility (Permit 41-16) and specifies the procedures and
requirements to satisfy North Carolina Solid Waste Management Rule 15A NCAC 13B
.0544 (b) and (c). The WQMP addresses the following two (2) major elements;
monitoring/sampling of the groundwater system and monitoring/sampling of the surface
water.

The WQMP will meet the following requirements:

 Establish division approved background groundwater data that has not been
affected by leakage from the unit (.0544 (b)(1)(A)).

 Represent the groundwater quality passing the relevant point of compliance
as approved by the Division (.0544 (b)(1)(B)).

 The groundwater monitoring programs must include consistent sampling
and analysis procedures that are designed to ensure monitoring results that
provide an accurate representation of groundwater quality at the background
and down-gradient wells (.0544 (b)(1)(C)).

 Detection Groundwater monitoring program (.0544 (b)(1)(D)).

 The sampling procedures and frequency must be protective of human health
and the environment (.0544 (b)(1)(E)).

 Responsibility of sample collection and analysis must be defined as a part of
the monitoring plan (.0544 (c)(2)).

This WQMP also addresses the following procedures that will be implemented to ensure
the sampling event integrity:

 Sample preservation and shipment;

 Laboratory analytical procedures;

 Sample Chain-of-custody control; and

 Quality assurance/quality control programs.

The methods and procedures described in the WQMP are intended to facilitate the
collection of true and representative samples and test data. Field procedures are
presented in Section 2.2 in their general order of implementation. Equipment
requirements for each field task are presented within the applicable section. Laboratory
1 WI High Point, LLC is a subsidiary of Waste Industries, USA, Inc.
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procedures, quality assurance methods and record keeping requirements are presented
in Sections 3.0 through 8.0.

Strict adherence to the procedures stipulated in this plan is required. Any
variations from these procedures should be thoroughly documented and may
require prior DWM approval.
1.1 Site Contact Information
In case of emergencies, or if questions arise during the implementation of this
program, please contact the following:
1.1.1 WI High Point, LLC
5830 Riverdale Road
Jamestown, North Carolina 27282
Phone: [phone]
Fax: [phone]
Contact: Mr. Seth Heath - Landfill Manager
Email: [e-mail]
1.1.2 Waste Industries USA, Inc.
3301 Benson Drive, Suite 600
Raleigh, North Carolina 27609
Phone: [phone]
Fax: [phone]
Contact: Mr. Brent Kirchhoff – Regional Manager
Email: [e-mail]
1.1.3 Engineer
Smith Gardner, Inc.
14 N. Boylan Avenue
Raleigh, North Carolina 27603
Phone: [phone]
Fax: [phone]

Contacts: Ms. Joan A. Smyth, P.G., Senior Hydrogeologist
Email: [e-mail]
Mr. Stacey A. Smith, P.E., Senior Engineer
Email: [e-mail]
1.1.4 NC Division of Waste Management (DWM) – Solid Waste Section
North Carolina DEQ – Raleigh Central Office (RCO)
1646 Mail Service Center
Raleigh, NC 27699
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Phone: [phone]

Contact: Ms. Christine Ritter, Hydrogeologist
Email: [e-mail]
Phone: [phone]
Mr. John Patrone, Environmental Specialist
Email: [e-mail]

North Carolina DEQ – Winston-Salem Regional Office
585 Waughtown Street
Winston-Salem, North Carolina 27107
Phone: [phone]
Fax: [phone]
1.1.5 NC Division of Energy, Mineral and Land Resources – Land Quality Section
North Carolina DEQ – Raleigh Central Office (RCO)
North Carolina DENR – Winston-Salem Regional Office (WSRO)
585 Waughtown Street
Winston-Salem, North Carolina 27107
Phone: [phone]
FAX: [phone]

Contacts: Matthew Gantt, P.E., Regional Engineer (WSRO)
[e-mail]
Shannon Leonard, Environmental Engineer I (WSRO)
[e-mail]
1.2 Site Background
The WI High Point C&D Landfill facility (Permit 41-16) is located at 5830 Riverdale
Drive, Jamestown, NC. The approximately 158 acre facility is located
approximately 6 miles east of High Point, in Guilford County. Area development
is a mix of agricultural, industrial/commercial and landfill use. In general,
development in the area is primarily along the main roads. The site and
monitoring locations are shown on Figure 1.
1.2.1 Geology
The WI High Point C&D Landfill is located within the Piedmont
Physiographic Province of North Carolina, which is characterized by
moderately rolling valleys and ridges. The Geologic Map of North Carolina
(USGS, 1985) indicates that the site lies within the Carolina Slate Belt;
Late Proterozoic to Cambrian age volcanic and sedimentary rock
metamorphosed to lower greenshist facies with multiple intrusions. The
site is underlain by white to gray, fine to coarse grained, granitic rock.
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1.2.2 Hydrogeology
The hydrogeology at this site has been investigated using, groundwater
monitoring wells and aquifer slug tests. Groundwater flows primarily
southwest, towards Richland Creek and its tributaries, with additional
flow south and west. Richland Creek is approximately 1300 feet from the
facility boundary and flows into Deep River. The uppermost aquifer is
saprolite, partially weathered rock (PWR) along with granitic bedrock.
Groundwater occurs from approximately ten feet below grade or less in
the downgradient wells near the Richland Creek tributaries to twenty-five
feet below grade upgradient of the waste area. Locally, the C&D site is
bounded Richland Creek and its tributaries to the west and south.

The average estimated horizontal hydraulic gradient across the site is
approximately 8.06 ft/yr. Effective porosities calculated from the Phase 2
Design Study ranged from 13 to 28 percent. Laboratory derived
permeabilies for those same locations ranged from 5.8 x 10-5 to 7.9 x 10-4
cm/sec2.

Three well clusters were used to determine vertical gradient, MW-4S/D,
P-26S/D and P-30S/D. Strong upward gradients were calculated at the
MW-4S/D location, indicating discharge at this location. P-26S/D
exhibited a downward gradient suggesting recharge as expected on the
topographic high. Vertical gradient for P-30S/D was slightly downward,
consistent with transition area hydrology.

This Water Quality Monitoring Plan (WQMP) has been prepared to meet
the field sampling and laboratory analysis requirements of ongoing
monitoring at the site. The WQMP details field and laboratory protocols
that must be followed to meet the data objectives of semi-annual
groundwater monitoring.

2 From Golder Design Hydrogeologic Report, Phase 2 Expansion. (Revised August 2008).
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2.0 MONITORING PROGRAM
This Water Quality Monitoring Plan section addresses individual monitoring program
components. At a minimum, WI High Point, LLC will monitor the groundwater quality on
a semi-annual basis.
2.1 Monitoring Network and Analytical Parameters
Historical water level data indicates that groundwater is flowing generally south
to southwest towards a tributary of Richland Creek. There are ten existing well
locations and four surface water points for the C&D landfill monitoring network.
Three monitoring wells, MW-9, AMW-1 and AMW-2, are proposed for addition to
the monitoring network. MW-9 is proposed to monitor the groundwater flowing
south from the Phase 3 area. Due to VOC detections in samples collected from
MW-2 and MW-6 the assessment monitoring wells AMW-1 and AMW-2 will be
installed slightly downgradient to these locations.

Well construction details are provided in Table 1 and well construction records
are presented in Appendix A.

The proposed monitoring network for the site is shown on Figure 1 and
summarized in the table below.

Monitoring Network
Well Location Analytical Parameters 1
MW-1 Upgradient Appendix II + Field + C&D
MW-2 Downgradient Appendix II + Field + C&D
MW-3 Downgradient Appendix I + Field + C&D
MW-4S Downgradient Appendix I + Field + C&D
MW-4D Downgradient WATER LEVEL ONLY
MW-5 Downgradient Appendix I + Field + C&D
MW-6 Downgradient Appendix II + Field + C&D
MW-7S Downgradient Appendix I + Field + C&D
MW-7D Downgradient WATER LEVEL ONLY
MW-8 Downgradient Appendix I + Field + C&D
MW-9 3 Downgradient Appendix I + Field + C&D
AMW-1 4 Downgradient of MW-2 Appendix II + Field + C&D
AMW-2 4 Downgradient of MW-6 Appendix II + Field + C&D
SW-1 Upstream Tributary Appendix I + Field + C&D
SW-2 Downstream Tributary Appendix I + Field + C&D
SW-3 Upstream Tributary Appendix I + Field + C&D
SW-4 Downstream Tributary Appendix I + Field + C&D
Note: 1. Appendix I, Field and C&D parameters are listed in Table 2.
2. MW-1 and MW-2 are in Appendix II monitoring for 2-years per the
December 7, 2015 letter from Golder Associates NC to Ms. Jackie
Drummond. After 2-years water quality will be re-evaluated. A work plan
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approval letter was issued to Mr. Seth Heath issued January 28, 2016.
[DIN 25551]
3. Proposed monitoring well
4. Proposed in the Assessment Monitoring Notification and Work Plan
Addendum letter from Golder Associates to Ms. Jackie Drummond,
October 21, 2016; approved by NCDEQ October 31, 2016 (DIN 26956).

This monitoring system is adequate to detect any releases from the landfill unit.
2.2 Groundwater Sample Collection
Details regarding the procedures and equipment required to perform
groundwater field measurements and sampling from monitoring wells during
each monitoring event are presented in this section. Where possible, work will
proceed from the upgradient (background) wells to downgradient
(compliance) wells.
2.2.1 Guidance Documents
Sampling, analysis, and submittals will be performed in accordance
with this plan and the following guidance documents:

1. Groundwater, Surface Water and Soil Sampling for
Landfills - NCDENR Guidance updated April 2008.

2. October 27, 2006 Memo from NCDENR entitled "New
Guidelines for Electronic Submittal of Environmental
Monitoring Data."

3. February 23, 2007 Memo from NCDENR entitled
Addendum to October 27, 2006, North Carolina Solid Waste
Section Memorandum Regarding New Guidelines for
Electronic Submittal of Environmental Data.

4. October 16, 2007 Memo from NCDENR entitled
Environmental Monitoring Data for North Carolina Solid
Waste Management Facilities.
2.2.2 Fuel Powered Equipment
Monitoring wells at WI High Point Landfill have dedicated bladder pumps;
therefore fuel-powered equipment is not required for routine
groundwater sampling. In the event, fuel-powered equipment, such as
generators for additional pumps is needed, it must be situated away and
downwind from site activities (i.e. purging and sampling). If field
conditions prevent such placement, then the fuel source must be placed
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as far away as possible from the sampling activities. The sampling
conditions must be described in detail in the field notes.

If fuel must be handled, it should be done the day before sampling. Effort
should be made to avoid handling fuels on the day of sampling. If fuels
must be dispensed during sampling activities, dispense fuel downwind
and well away from any sampling locations. Wear gloves while working
with fuel and dispose of the gloves away from sampling activities. Wash
hands thoroughly after handling any fuels.
2.2.3 Equipment Decontamination
Dedicated bladder pumps are used at WI High Point, however, non-
dedicated equipment that will come in contact with the well casing and
water will be decontaminated between wells. The procedure for
decontaminating non-dedicated equipment is as follows:

1. Don new powder-free surgical gloves.

2. Clean item with tap water and phosphate-free laboratory
detergent (Liqui-Nox or equivalent), using a brush if necessary to
remove particulate matter and surface films.

3. Rinse thoroughly with pesticide grade isopropanol and allow to
air dry.

4. Rinse with organic-free water (Milli-Q water or other ultra-
pure water) and allow to air dry.

5. Wrap with commercial-grade aluminum foil, if necessary, to
prevent contamination of equipment during storage or transport.

Liqui-Nox detergent solutions will be stored in a clearly marked High
Density Polyethylene (HDPE) or Polypropylene (PP) container. Containers
for pesticide-grade isopropanol will be made of inert materials such as
Teflon, stainless steel, or glass.

Sampling will be planned and conducted in such a way as to minimize the
need for decontamination in the field by using dedicated sampling
equipment; new disposable Teflon bailers may be used as needed.
Unclean equipment will be separated from clean equipment during field
activities. Clean equipment will remain in the manufacturer's packaging
until use, or will be wrapped in commercial-grade aluminum foil or
untreated butcher paper.

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2.2.4 Water Level Measurements
2.2.4.1 Static Water Levels
Static water level and depth to the well bottom will be measured
in each well prior to any purging or sampling activities. Static
water level and well depth measurements are necessary to
calculate the stagnant water volume in the well prior to purging.
Additionally, these measurements provide a field check on well
integrity, degree of siltation, and are used to prepare
potentiometric maps, calculate aquifer flow velocities, and
monitor changes in site hydrogeologic conditions.

Groundwater depths will be measured to a vertical accuracy of
0.01 feet relative to established wellhead elevations. Each well
will have a permanent, easily identified reference point on the well
riser lip from which water level readings will be measured. The
reference point elevation will be established by a Registered Land
Surveyor.
2.2.4.2 Contamination Prevention
After opening each well, new, powder-free, surgical gloves will be
donned. Appropriate procedure will be followed during
measurement activities to minimize the potential for soils,
decontamination supplies, precipitation, and/or other potential
contaminants from entering the well or contacting clean
equipment.
2.2.4.3 Equipment
An electronic water level indicator will be used to measure depth
to groundwater in each well and/or piezometer. The electronic
water level indicator will be constructed of inert materials, such
as stainless steel and Teflon. Between each well, the device will
be thoroughly decontaminated by washing with non-phosphate
(Liqui-Nox) soap and rinsing with organic-free water to
prevent cross contamination from one well to another.

The following measurements and observations will be recorded in
a field book prior to sample collection:

 Depth to static water level and well bottom (to the nearest
0.01 foot);

 Water column height in the riser (based on measured well
depth);
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 Wellhead protective casing, base pad and riser condition;
and

 Changes in well and surrounding conditions.

Section 5.0 presents a detailed description for collected field
notes.
2.2.5 Monitoring Well Evacuations
Water accumulated in each well may be stagnant and unrepresentative of
surrounding aquifer conditions and therefore must be removed to insure
that fresh formation water is sampled. The standing water in the well
casing will be purged following recording the static water level
measurement, unless low-flow sampling techniques are used.
Monitoring well evacuation should be performed in upgradient wells first,
and by systematically moving to downgradient well locations.
2.2.5.1 Contamination Prevention
New, powder-free, surgical gloves will be donned for well purging
and sampling activities and whenever handling decontaminated
field equipment. Appropriate measures will be executed during
measurement, purging, and sampling activities to minimize the
potential for surface soils, decontaminated supplies, precipitation,
and/or other potential contaminants from entering the well or
contacting clean equipment.
2.2.5.2 Calculations
The standing water volume in the well riser and screen will be
calculated immediately before well evacuation during each
monitoring event (if standard purging techniques are used). A
standing water volume will be calculated for each well using
measured static water level, well depth and well casing diameter
according to the following equation:

V = (TD - SWL) x C
Where: V = One well volume (gallons)
TD = Total depth of the well (in feet)
SWL = Static water level (in feet)
C = Volume constant for
well diameter (gallons/foot)
C = 0.163 gal/ft for two-inch wells.
C = 0.653 gal/ft for four-inch wells.
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2.2.5.3 Well Purging
Several options for well purging are used at this site including:

 Bailers;
 Low Flow Pumps; and
 Grundfos Redi-flo Pumps.

Bailers – Where bailers are used, new, disposable bailers with
either double or bottom check-valves will be used to purge each
well. Disposable purge bailers will be constructed of fluorocarbon
resin (Teflon) or inert plastic suitable for the well and ground
conditions. Each bailer will be factory-clean and remain sealed in
a plastic sleeve until use. A new Teflon-coated stainless steel,
inert mono-filament line or nylon cord will be used for each well
to retrieve the bailers. Where bailers are used, a minimum of
three well volumes will be purged unless the well runs dry.

Low Flow Pumps – Low flow pumps are typically used at this site
for groundwater sample collection. Monitoring wells may be
purged and sampled using the low-flow sampling method in
accordance with the Solid Waste Section Guidelines for
Groundwater, Soil, and Surface Water Sampling (NCDENR, 2008).

Obtain depth-to-water measurements using an electronic water
level indicator capable of recording the depth to an accuracy of
0.01 foot. Determine if the water table is located within the
screened interval of the well. If the water table is not within the
screened interval, the drawdown amount that can be achieved
before the screen is intersected will be calculated. If the water
table is within the screened interval, total drawdown should not
exceed 1 foot to minimize the amount of aeration and turbidity. If
the water table is above the top of the screened interval, the
drawdown amount should be minimized to keep the screen from
being exposed.

If the purging equipment is non-dedicated, the equipment will be
lowered into the well, using care to minimize the disturbance to
the water column. If conditions (i.e., water column height and well
yield) allow, the pump will be placed in the uppermost portion of
the water column (minimum of 18 inches of pump submergence is
recommended).

The minimum volume/time period for obtaining independent
Water Quality Parameter Measurements (WQPM) will be
determined. The minimum volume/time period is determined
based on the stabilized flow rate and the amount of volume in the
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pump and the discharge tubing (alternatively, the volume of a
direct read flow-cell can be used, provided it is greater than the
calculated volume of the pump and discharge tubing). The
bladder pump volume should be obtained from the
manufacturer. Volume from the discharge tubing is as follows:

3/8-inch inside diameter tubing: 20 milliliters per foot
1/4-inch inside diameter tubing: 10 milliliters per foot
3/16-inch inside diameter tubing: 5 milliliters per foot

Once the flow-cell or the pump and discharge tubing volume has
been calculated, the well purge will begin. The flow rate should
be based on historical data for that well (if available) and should
not exceed 500 milliliters per minute. The initial WQPM should be
recorded and the flow rate adjusted until drawdown in the well
stabilizes. Water levels should be measured periodically to
ensure a stabilized water level is maintained. The water level
should not fall within 1 foot of the top of the well screen. If the
purge rate has been reduced to 100 milliliters or less and the
head level in the well continues to decline, the required water
samples should be collected following stabilization of the WQPM,
based on the criteria presented below.

If neither the head level nor the WQPM stabilize, a passive sample
should be collected. Passive sampling is defined as sampling
before WQMP have stabilized if the well yield is low enough that
the well will purge dry at the lowest possible purge rate (generally
100 milliliters per minute or less).

WQPM stabilization is defined as follows: pH (+/- 0.2 S.U.),
conductance (+/- 5% of reading), temperature (+/- 10% of reading
or 0.2oC). Dissolved oxygen (DO) [+/- 20% of reading or 0.2 mg/L
(whichever is greater)] and oxidation reduction potential (ORP)
should also fall within +/- 10mV of reading; however, they are not
required parameters but may also be measured. At a minimum,
turbidity measurements should be recorded at the beginning of
purging, following the stabilization of the WQPM, and following
sample collection. The optimal turbidity range for micropurging is
25 Nephelometric Turbidity Units (NTU) or less. Turbidity
measurements above 25 NTU are generally indicative of an
excessive purge rate or natural conditions related to excessive
fines in the aquifer matrix.

WQPM stabilization should occur in most wells within five to six
rounds of measurements. If stabilization does not occur following
the removal of a purge volume equal to three well volumes, a
passive sample will be collected.
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Direct-read equipment used at each well will be calibrated in the
field according to the manufacturer’s specifications prior to each
day’s use and checked, at a minimum, at the end of each sampling
day. Calibration information should be documented in the
instrument’s calibration logbook and the field book.

Each well is to be sampled immediately following stabilization of
the WQPM. The sampling flow rate must be maintained at a rate
that is less than or equal to the purging rate. For volatile organic
compounds, lower sampling rates (100 - 200 milliliters/minute)
should be used. Final field parameter readings should be
recorded prior to and after sampling.

Grundfos Redi-Flo Pumps – Where Redi-Flo pumps are used, the
same low flow techniques for sampling will be used. Please see
above for detailed summary of purging/sampling techniques.
2.2.5.4 Purge Rate
Wells will be purged at a rate that will not cause recharge water to
be excessively agitated or cascade through the screen; minimizing
disturbance to the well sidewalls and bottom, which could result
in silt and fine particulate matter suspension. The water volume
purged from each well, and the relative recharge rate will be
documented in sampling field notes. Wells which have very low
recharge rates will be purged once until dry. Damaged, dry, or
low yielding and high turbidity wells will be documented for
reconsideration before the next sampling event.
2.2.5.5 Purge Water Disposal
Purge water will be managed to prevent possible soil and surface
water contamination. Well site management options may include
temporary containment and disposal as leachate or portable
activated carbon filtration if warranted by field characteristics.
2.2.5.6 Non-Dedicated Equipment
Durable, non-dedicated equipment that is lowered into the well or
which may come in contact with the water samples will be
thoroughly decontaminated before each use. Equipment will be
disassembled to the degree practical, washed with (non-
phosphate) soapy potable tap water, and triple rinsed using de-
ionized water. Detailed equipment decontamination procedures
are detailed in Section 2.2.3.
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2.2.6 Sample Collection
After purging the appropriate volume, groundwater samples will be
collected for laboratory analysis. Samples should be collected from the
least contaminated location(s) first, followed by locations of increasing
contamination across the site. Prior to sample collection, sample labels
should be properly filled-out with permanent, waterproof ink. At a
minimum, the label should identify the sample with the following
information:

 Site Name;

 Sample Location or Well Number;

 Collection Date and Time;

 Analysis Required;

 Sampler's Initials;

 Preservative Used (if any); and

 Other Pertinent Information as Necessary.

Affix a label with the written information to the sample bottle prior to
sampling.

Sampling will occur within 24-hours of the purging of each well and as
soon after well recovery as possible. Wells which fail to recharge or
produce an adequate sample volume within 24 hours of purging will not
be sampled.
2.2.6.1 Field Parameters
Field measurements for temperature, pH, and specific
conductance will be recorded immediately prior to sampling each
monitoring point. For low-flow sampling, dissolved oxygen (DO)
and oxidation reduction potential (ORP) shall also be collected.
Additionally, turbidity measurements should be collected for
detected metals evaluation. The field test specimens will be
collected with the sampling bailer and placed in a clean, non-
conductive glass or plastic container for observation.
Temperature, pH, conductivity and turbidity meter calibration will
be performed according to the manufacturers' specifications and
will be consistent with Test Methods for Evaluating Solid Waste -
Physical/Chemical Methods (SW-846). A pocket thermometer and
litmus paper will be available in case of meter malfunction.
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2.2.6.2 Sample Equipment
Several options for sample collection are used at this site
including:

 Teflon Bailers;
 Low Flow Pumps; and
 Grundfos Redi-flo Pumps.

Dedicated bladder pumps are installed in the groundwater
monitoring wells and low flow purging/sampling is most
commonly utilized at the WI High Point Facility.

Teflon Bailers – Where bailers are used, each well will be
sampled using a new, factory-cleaned, disposable Teflon bailer
with bottom check-valve and sample discharge mechanism. A
new segment of Teflon-coated stainless steel wire, inert mono-
filament line or nylon cord will be used to lower and retrieve each
bailer. The bailer will be lowered into each well to the point of
groundwater contact and then allowed to fill as it sinks below the
water table. Bottom contact will be avoided, preventing
suspended sediment in the samples. The bailer will be retrieved
and emptied in a manner which minimizes sample agitation.

Low Flow Pumps – Following purging with the low flow pump
systems, samples may be collected immediately from the
pumping system. Samples are to be collected in the order
outlined in Section 2.2.6.4.

Redi-Flo Pumps - Following purging three well volumes of water,
samples may be collected from the Redi-Flo pumps. Samples will
be collected in the order outlined in Section 2.2.6.4.
2.2.6.3 Sample Transference
Samples will be transferred directly from the Teflon bailer or
pump discharge tubing into a sample container that has been
specifically prepared for the preservation and storage of
compatible parameters. A bottom emptying device provided will
be used to transfer samples from the bailer to sample container.
The generation air bubbles and sample agitation will be minimized
during bailer discharge.

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2.2.6.4 Sample Collection Order
Groundwater samples will be collected and contained in the order
of volatilization sensitivity. Whenever possible the following
sampling order will be observed:

 Volatile Organics and Volatile Inorganics;

 Extractable Organics, Petroleum Hydrocarbons, Aggregate
Organics, and Oil and Grease;

 Total Metals;

 Inorganic Nonmetallics, Physical and Aggregate
Properties, and Biologicals;

 Microbiological

 Wet Chemistry; and

 Temperature, pH, DO, ORP, Conductivity, and Turbidity
Measurements.

Note: If the pump used to collect groundwater samples is not
suitable to collect volatile or extractable organics then collect all
other parameters and withdraw the pump and tubing. Then
collect the volatile and extractable organics.

Samples will be collected and analyzed in an unfiltered state
during sampling events. Samples for dissolved metal analysis, if
subsequently required, will be prepared by field filtration using a
disposable 0.45 micron filter cartridge specifically manufactured
for this purpose.
2.2.6.5 Decontamination
Reusable sampling equipment including water level probes, water
quality meters, interface probes, and filtering pumps which might
contact aquifer water or samples will be thoroughly
decontaminated between wells by washing with non-phosphate
soapy, de-ionized water and rinsing with isopropanol and organic-
free water (MilliQ or equivalent). Equipment decontamination
procedures are detailed in Section 2.2.3.

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2.2.6.6 Sample Preservation
Following sampling at each location, the sample bottles will be
placed in Ziploc bags inside a cooler with ice for preservation.
2.2.6.7 Field Quality Assurance
Equipment and trip blanks will be prepared, handled, and
analyzed as groundwater samples to ensure cross-contamination
has not occurred. One set of trip blanks, will be prepared before
leaving the laboratory to ensure that the sample containers or
handling processes have not affected the quality of the samples.
One set of equipment blanks will be created in the field at the time
of sampling to ensure that the field conditions, equipment, and
handling during sampling collection have not affected sample
quality. This sample will be collected using the same equipment
utilized for well sampling. A duplicate groundwater sample may
be collected from a single well to check laboratory accuracy.
Blanks and duplicate containers, preservatives, handling, and
transport procedures for surface water samples will be identical
to those noted for groundwater samples. Blank samples are
discussed in detail in Section 3.1.
2.2.6.8 Sample Containers
Sample containers will be provided by the laboratory for each
sampling event. Containers must be either new, factory-certified
analytically clean by the manufacturer, or cleaned by the
laboratory prior to shipment for sampling. Laboratory cleaning
methods will be based on the bottle type and analyte of interest.
Metal containers are thoroughly washed with non-phosphate
detergent and tap water, and rinsed with (1:1) nitric acid, tap
water, (1:1) hydrochloric acid, tap water, and non-organic water, in
that order. Organic sample containers are thoroughly washed
with non-phosphate detergent in hot water and rinsed with tap
water, distilled water, acetone, and pesticide quality hexane, in
that order. Other sample containers are thoroughly washed with
non-phosphate detergent and tap water, rinsed with tap water,
and rinsed with non-organic water. The laboratory will provide
proper preservatives in the sample containers prior to shipment
(Section 4.0).
2.3 Surface Water Sample Collection
This section presents the procedures and equipment required to perform surface
water field measurements and sampling from springs, streams and ponds
during each monitoring event.
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2.3.1 Surface Water Level Observations
Surface water quality analyses are particularly sensitive to site hydrologic
conditions and recent precipitation events. Water levels may fluctuate
significantly in comparison to the groundwater table and may result in
either diluting or increasing contaminant loadings. Recent weather and
sampling station conditions should be considered when scheduling the
sampling event and interpreting the surface water data.
2.3.1.1 Monitoring Conditions
Surface water level and sampling station conditions should be
observed and recorded during each sampling event if warranted
by site conditions. Surface water observations will include the
flood stage in streams, seasonal base flow conditions, and confirm
location and timing for meaningful surface water quality sampling.
The following objective observations will be recorded in the field
book prior to sample collection:
 Relative stream water level;  Surface water clarity; and  Changes in surface monitoring station conditions and
surroundings.
2.3.1.2 Sampling Station Modifications
Modifications to surface water sampling station conditions may be
required prior to each sampling event. These modifications may
include surface and submerged debris removal, slightly
deepening the station to allow sample container immersion, or
channeling/piping to consolidate local discharge. When
modifications are required, sufficient time will be allowed for
settlement of suspended solids between the disturbance and
sample collection. A minimum a settling period of four hours
prior to sampling will be observed.
2.3.2 Sample Collection
2.3.2.1 Collection Procedure
Surface water samples will be obtained from areas with minimal
turbulence and aeration. Samples will only be collected if flowing
water is observed during the sampling event. New, non-
powdered, surgical gloves will be donned prior to sample
collection. The following procedure will be implemented
regarding surface water sampling:

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1. Put on new, non-powdered, surgical gloves.

2. Hold the bottle by the bottom with one hand, and with the
other, remove the cap.

3. Push the sample container slowly into the water and tilt up
toward the current to fill. A water depth of six inches is
generally satisfactory. Breaching the surface or losing
sample preservatives while filling the container will be
avoided.

4. If there is little current movement, the container should be
moved slowly, in a lateral, side to side direction, with the
container mouth pointing upstream.

Surface water samples will be collected from surface water
monitoring points shown on Figure 1. Samples will be collected
directly from the station in the container that has been prepared
for the preservation and storage of compatible parameters.
Samples will be collected in a manner that assures minimum
agitation.
2.3.2.2 Field Parameters
Temperature, pH, specific conductivity, and turbidity will be
measured at the start of surface water sampling, as a record of
field conditions and a check on the water sample stability over
time. Prior to sampling, temperature, pH, conductivity, and
turbidity meter calibration will be completed according to the
manufacturers' specifications and consistent with Test Methods
for Evaluating Solid Waste - Physical/Chemical Methods (SW-846).
2.3.2.3 Sample Collection Order
Surface water samples will be collected in the order of
volatilization sensitivity. When collected, the following sampling
order will be observed:
 Volatile Organics and Volatile Inorganics;  Extractable Organics, Petroleum Hydrocarbons, Aggregate
Organics and Oil and Grease;
 Total Metals;  Inorganic Nonmetallics, Physical /Aggregate Properties;  Wet Chemistry; and  Temperature, pH, DO, ORP, Conductivity, and Turbidity
Measurements.

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Samples will be collected and analyzed in an unfiltered state
during sampling events. Samples for dissolved metal analysis, if
subsequently required, will be prepared by field filtration using a
decontaminated peristaltic pump and a disposable 0.45 micron
filter cartridge specifically manufactured for this purpose.
2.3.2.4 Decontamination
Field meters which might contact surface water samples will be
thoroughly decontaminated between stations by washing with
non-phosphate soapy, de-ionized water and rinsed with
isopropanol and organic-free water (MilliQ or equivalent).
Detailed equipment decontamination procedures are detailed in
Section 2.2.3.
2.3.2.5 Sample Preservation
Following sampling at each location, the sample bottles will be
placed in Ziploc bags inside a cooler with ice for preservation.
2.3.2.6 Field Quality Assurance
If needed, equipment and trip blanks will be prepared, handled,
and analyzed in the same manner as blanks for groundwater
samples (Section 2.2.6.7). Samples will be collected using the
same equipment utilized for well sampling. Duplicate samples
will not be collected for surface water samples. Blanks and
duplicate containers, preservatives, handling, and transport
procedures for surface water samples will be identical to those
noted for groundwater samples. Blank samples are discussed in
detail in Section 3.1.
2.3.2.7 Sample Containers
Sample containers will be prepared and provided by the laboratory
for each surface water sampling event. Each container's
preparation and preservatives will be the same as those utilized
for groundwater sampling and addressed previously in Section
2.2.6.8.

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3.0 FIELD QA/QC PROGRAM
Field Quality Assurance/Quality Control (QA/QC) requires the routine collection and
analysis of blank samples to verify that the handling process has not affected sample
quality. Contaminants reported in blank samples could be attributed to:

1. Interaction between the sample and the container;
2. Contaminated source water; and/or
3. A handling procedure that altered the sample.
3.1 Blank Samples
3.1.1 Trip Blanks
The laboratory will prepare a trip blank by filling each sample bottle type
with laboratory grade distilled or deionized water. Trip blanks will be
placed in bottles of the specific type required for the analyzed
parameters, bottle packs will be specifically assembled by the laboratory
for each sampling event. Trip blanks will be packaged by the laboratory
prior to the sampling event and transported with the empty bottle packs.
These bottles return to the laboratory in an untampered state. The trip
blanks will be analyzed for volatile and purgeable organics only.
3.1.2 Equipment Blanks
Where wells are sampled with non-dedicated equipment, equipment
blank samples shall be collected at a rate of one sample per day. To
collect an equipment blank, a bailer shall be filled with non-organic water
(Milli-Q or equivalent). Handling the bailer in a manner identical to well
sampling, the water is to be transferred into the sample collection jars for
the equipment blanks. These samples are packed in the field and sent to
the laboratory with the other samples.
3.1.3 Field Blanks
To collect a field blank, deionized water from the lab or non-organic
(Milli-Q or equivalent) water will be poured at the sampling location into
laboratory provided sample collection jars. These samples are packed
and sent to the laboratory with the other samples.
3.2 Blank Concentrations
The contaminant concentration levels found in any blank samples will be
reported but will not be used to correct the groundwater data. In the event that
elevated parameter concentrations are found in a blank, the analysis will be
flagged for future evaluation and possible re-sampling.

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3.3 Field Instruments
Field instruments utilized to measure groundwater characteristics will be
calibrated prior to entering the field, and recalibrated in the field as required, to
insure accurate sample measurements. The specific conductivity and pH meter
will be recalibrated utilizing two prepared solutions of known pH concentration in
the range of anticipated values (between 4 and 10). A permanent thermometer,
calibrated against a National Bureau of Standards Certified thermometer, will be
used for temperature meter calibration. Other field equipment should be
calibrated at least daily using the manufacturer's recommended specifications.

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4.0 SAMPLE PRESERVATION AND SHIPMENT
Sample preservation, shipment, and Chain-of-Custody procedures to be observed
between sampling and laboratory analysis are presented in the following sections.
4.1 Sample Preservation
Pre-measured chemical preservatives will be provided by the analytical
laboratory. Hydrochloric acid will be used as a chemical stabilizer and
preservative for volatile and purgeable organic specimens. Nitric acid will be
used as the preservative for samples for inorganic metals analysis.
4.2 Storage/Transport Conditions
Proper storage and transport conditions must be maintained to preserve the
sample integrity between collection and analysis. Ice and chemical cold packs
will be used to cool and preserve samples, as directed by the analytical
laboratory. Samples will be maintained at a maximum temperature of 4o C. Dry
ice is not to be used. Samples will be packed and/or wrapped in plastic bubble
wrap to inhibit breakage or accidental spills.

Chain-of-Custody control documents will be placed in a waterproof pouch and
sealed inside the cooler with the samples for shipping. Tape and/or custody
seals will be placed on the outside of the shipping coolers, in a manner to
prevent and detect sample tampering.
4.3 Sample Delivery
Samples shall be delivered to the analytical laboratory within a reasonable
period of time in person or using an overnight delivery service to insure hold
times are not exceeded. If samples are not shipped the same day, the ice used
to keep the samples cool will be replenished to maintain the required maximum
temperature of 4o C. Shipment and sample receipt will be coordinated with the
laboratory. Do NOT store or ship highly contaminated samples (concentrated
wastes, free product, etc.) or samples suspected of containing high contaminant
concentrations in the same cooler or shipping container with other
environmental samples.
4.4 Chain of Custody
Chain-of-Custody control will be maintained from sampling through analysis to
prevent tampering with analytical specimens. Chain-of-Custody control
procedures for samples will consist of the following:

1. Chain-of-Custody will originate at the laboratory with the shipment of
prepared sample bottles and blank(s) in sealed coolers. Container kits
will be shipped by express carrier to the sampler or site or picked up at
the laboratory.
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2. Following sample kit receipt, the sampler will inventory the container kit,
and check its consistency with number and type of containers indicated in
the Chain-of-Custody forms and required for the sampling event.

3. Labels for individual sample containers will be completed in the field,
indicating the site name, sampling time and date, sample location/well
number, analysis required, sampler’s initials, and preservation methods
used for the sample.

4. Collected specimens will be placed in the iced coolers and will remain in
the continuous possession of the field technician until shipment or
transferal as provided by the Chain-of-Custody form has occurred. If
continuous possession cannot be maintained by the field technician, the
coolers will be temporarily sealed and placed in a secured area.

5. Following laboratory delivery, samples will be issued a laboratory sample
number and recorded into a logbook indicating client, sample
location/well number, and delivery date and time. The laboratory director
or his designee will sign the Chain-of-Custody control forms and formally
receive the samples.

6. Chain-of-Custody form copies will be placed in the laboratory's analytical
project file and attached to the laboratory analysis report following
analysis.

Chain-of-Custody forms will be used to transfer direct deliveries from the
sampler to the laboratory. A coded, express delivery shipping bill shall
constitute the Chain-of Custody between the sampler and laboratory for
overnight courier deliveries.
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5.0 FIELD LOGBOOK
The field technician will keep an up-to-date logbook documenting important information
pertaining to the technician's field activities. The field logbook will document the
following:

 Site Name and Location;
 Sampling Date and Time;
 Climatic Conditions During Sampling Event;
 Sampling Location/Well Identification Number;

 Sample Collection Time;

 Field Technician Signature;

Groundwater Sample Collection
 Well Static Water Level;
 Water Column Height in Well;
 Purged Water Volume and Well Yield (High or Low);
 Purging and Sampling Event Observations;
 Temperature, pH, Temperature, DO, ORP, Turbidity, and Conductivity
Readings;

Surface Water Sample Collection
 Relative stream water level;
 Surface water clarity;

 Temperature, pH, Temperature, DO, ORP, Turbidity, and Conductivity
Readings; and
 Changes in surface monitoring station conditions and surroundings.
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6.0 LABORATORY ANALYSIS
The ground and surface water parameters will be analyzed for field water quality
indicators (pH, conductivity, temperature and turbidity) and those constituents listed in
Table 2. Analytical methods will follow Test Methods for Evaluating Solid Waste -
Physical/Chemical Methods (SW-846) or Methods for the Chemical Analysis of Water and
Wastes and will be consistent with the DWM’s policies regarding analytical methods and
reporting limits. Analysis will be performed by a laboratory certified by the North
Carolina DWM for the analyzed parameters.
6.1 Laboratory Quality Assurance/Quality Control
Formal environmental laboratory Quality Assurance/Quality Control (QA/QC)
procedures are to be utilized at all times. The landfill owner/operator is
responsible for selecting a laboratory contractor and insuring that the laboratory
is utilizing proper QA/QC procedures. The laboratory must have a QA/QC
program based on specific routine procedures outlined in a written laboratory
Quality Assurance/Quality Control Manual. The QA/QC procedures listed in the
manual shall provide the lab with the necessary assurances and documentation
that accuracy and precision goals are achieved in analytical determinations.
Internal quality control checks shall be undertaken regularly by the lab to assess
the analytical procedures precision and accuracy.
6.2 Laboratory Quality Control Checks
The internal quality control checks include calibration standards, standard
references, duplicate samples, and spiked or fortified samples. Calibration
standards shall be verified against a standard reference obtained from a second
(alternate) source. For most analytical methods, calibration curves shall be
developed using at least one (1) blank and three (3) standards. Samples shall be
diluted, if necessary, to ensure that analytical measurements fall within the
linear portion of the calibration curve. Where required, duplicate samples shall
be processed at an average frequency of 10 percent to assess the precision of
testing methods, and standard references shall be processed not less than
monthly to assess the accuracy of analytical procedures. Method or procedural
blanks and spiked or fortified samples shall be carried through sample
preparation and measurement to validate the efficiency and accuracy of the
analysis.
6.3 Data Review
During analyses, quality control and sample data shall be reviewed by the
laboratory manager to identify questionable data and determine if the necessary
QA/QC requirements are being followed. If a portion of the lab work is
subcontracted, it is the contracted laboratory’s responsibility to verify that
subcontracted work is completed by certified laboratories, using approved QA/QC
procedures.
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7.0 RECORD KEEPING AND REPORTING
This section addresses the documentation and reporting requirements associated with
the WQMP implementation.
7.1 Groundwater System Evaluations
After each monitoring event, the potentiometric surface will be evaluated to
determine if the monitoring system is adequate to provide early detection of a
release from the landfill unit and to determine the rate and direction of
groundwater flow at the site. The groundwater flow direction will be confirmed
by comparing the most recent groundwater surface elevations across the site
using a potentiometric surface map. Groundwater flow rates will be calculated
using the following equation:

V=Ki/n
Where: V = Velocity (feet/day)
K = Hydraulic Conductivity (feet/day)
i = Hydraulic Gradient (foot/foot)
n = Effective Porosity of aquifer soils (unit less)

If these evaluations indicate the groundwater monitoring system requires
modification to meet rule requirements, a work plan and revised WMQP will be
submitted to NCDWM for review prior to modifications to enhance the monitoring
system.
7.2 Reporting
A report summarizing the monitoring event and the analytical data from the
event will be submitted to the DWM within 120 days following receipt of
laboratory analytical data.

Monitoring reports will include the following:

1. An discussion of site geology and hydrogeology;
2. A discussion of the monitoring event procedures and results;
3. An potentiometric surface map;
4. Analytical laboratory reports and summary tables;
5. Graphical analysis of analytical data may be reported but is not required;
6. Solid Waste Environmental Monitoring Reporting Form (Appendix B); and
7. Laboratory Data (in Electronic Data Deliverable Format – see Section
2.2.1).

Monitoring reports may be submitted electronically by e-mail or in paper copy
form. Report copies will be kept at the landfill office.
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8.0 MONITORING PROGRAM MODIFICATIONS
This section addresses the procedures that should be followed with respect to any water
quality program modifications.
8.1 Well Abandonment/Rehabilitation
After each water quality monitoring event, the potentiometric surface will be
evaluated to determine whether the monitoring system is still effective at
detecting an early release from the landfill, and to determine the groundwater
flow rate and direction at the site. If the potentiometric maps reveal the depths,
locations, or well number is insufficient to monitor for a potential releases of
solid waste constituents from the solid waste management area, new well
locations and depths will be submitted to the DWM for approval.

Should wells become irreversibly damaged or require rehabilitation, the DWM
will be notified. If monitoring wells and/or piezometers are damaged irreversibly
they will be abandoned under DWM direction following 15A NCAC 02C .0113. The
abandonment procedure in unconsolidated materials involves over-drilling
and/or pulling the well casing and plugging the well with a sealant such as neat
cement grout and/or bentonite clay. For bedrock well completions the
abandonment encompasses plugging the interior well riser and screen with a
sealant such as neat cement grout and/or bentonite clay sealant.
8.2 Additional Well Installations
Additional well installations will be carried out in accordance with DWM
directives. Monitoring wells will be installed under the supervision of a North
Carolina registered geologist or engineer who will certify to the DWM that the
installation complies with the North Carolina 2C Regulations. For future well
installation, the documentation for well construction will be submitted by the
registered geologist or engineer to the DWM within thirty (30) days following well
construction.
8.3 Implementation Schedule
The Monitoring Program proposed herein will be implemented following
approval of this Water Quality Monitoring Plan by the DWM.

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Figure

Water Quality Monitoring Plan
WI High Point, LLC
WI High Point C&D Landfill
Jamestown, North Carolina
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Water Quality Monitoring Plan
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WI High Point C&D Landfill
Jamestown, North Carolina
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36

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DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
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Table 2
Analytical Parameters
WI High Point C&D Landfill
By: JAS/MMG
Date: 5/8/2014
Constituents Synonyms
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Vanadium
Zinc
Temperature
pH
Turbidity
Specific Conductance
Acetone 2-Propanone
Acrylonitrile 2-Propenenitrile
Benzene
Bromochloromethane Chlorobromomethane
Bromodichloromethane Dibromochloromethane
Bromoform Tribromomethane
Carbon Disulfide
Carbon Tetrachloride Tetrachloromethane
Chlorobenzene
Chloroethane Ethyl chloride
Chloroform Trichloromethane
Dibromochloromethane Chlorodibromomethane
1,2-Dibromo-3-chloropropane DBCP
1,2-Dibromoethane Ethylene dibromide, EDB
1,2-Dichlorobenzene o-Dichlorobenzene
1,4-Dichlorobenzene p-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane Ethyldidene chloride
1,2-Dichloroethane Ethylene dichloride
1,1-Dichloroethylene Vinylidene chloride
cis-1,2-Dichloroethylene
trans-1,2-Dichloroethylene
1,2-Dichloropropane Propylene dichloride
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
\\RALNAS\Office_Share\Projects\WI High Point Landfill (C&D)\WIHIGHPOINT 16-1 (Phase 3 PTC)\L. WQMP\Table 2 -Analyte List- S+G.xlsx
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
Table 2
Analytical Parameters
WI High Point C&D Landfill
By: JAS/MMG
Date: 5/8/2014
Constituents Synonyms
2-Hexanone Methyl butyl ketone
Methyl bromide Bromomethane
Methyl chloride Chloromethane
Methyl ethyl ketone 2-Butanone
Methyl iodide Iodomethane
4-Methyl-2-pentanone Methyl isobutyl ketone
Methylene bromide Dibromomethane
Methylene chloride Dichloromethane
Styrene Ethenylbenzene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene Perchloroethylene
Toluene Methyl benzene
1,1,1-Trichloroethane Methyl chloroform
1,1,2-Trichloroethane
Trichloroethylene
Trichloroflouromethane CFC-11
1,2,3-Trichloropropane
Vinyl acetate Acetic acid, ethenyl ester
Vinyl chloride Choroethene
Xylenes Dimethyl benzene
C&D Landfill Additional Parameter:
Mercury
Chloride
Manganese
Sulfate
Iron
Alkalinity
Total Dissolved Solids
Tetrahydrofuran
Appendix II Additional Parameter:
SVOCs
Acenapthene
Acenapthylene
Acetophenone
2-Acetylaminofluorene 2-AAF
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(ghi)perylene
Benzo(a)pyrene
Benzyl alcohol
Bis(2-chloroethoxy)methane
\\RALNAS\Office_Share\Projects\WI High Point Landfill (C&D)\WIHIGHPOINT 16-1 (Phase 3 PTC)\L. WQMP\Table 2 -Analyte List- S+G.xlsx
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
Table 2
Analytical Parameters
WI High Point C&D Landfill
By: JAS/MMG
Date: 5/8/2014
Constituents Synonyms
Bis(2-chloroethyl) ether
Bis(2-chloro-1-methylethyl) ether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl ether
Butyl benzyl phthalate
p-Chloroaniline
Chlorobenzilate
p-Chloro-m-cresol
2-Chloronapthalene
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
m-Cresol 3-Methylphenol
o-Cresol
p-Cresol 4-Methylphenol
Diallate
Dibenz(a,h)anthracene
Dibenzofuran
Di-n-butyl phthalate DBP
1,3-Dichlorobenzene m-Dichlorobenzene
3,3-Dichlorobenzidine
2,4-Dichlorophenol
2,6-Dichlorophenol
Diethyl phthalate DEP
p-(Dimethylamino)azobenzene
7,12-Dimethylbenz(a)anthracene
3,3-Dimethylbenzidine
2,4-Dimethylphenol m-Xylenol
Dimethyl phthalate
m-Dinitrobenzene
4,6-Dinitro-o-cresol 4,6-Dinitro-2-methyl phenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-N-octyl phthalate
Diphenylamine
Ethyl methacrylate
Ethyl methanesulfonate
Famphur
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachloropropene
\\RALNAS\Office_Share\Projects\WI High Point Landfill (C&D)\WIHIGHPOINT 16-1 (Phase 3 PTC)\L. WQMP\Table 2 -Analyte List- S+G.xlsx
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
Table 2
Analytical Parameters
WI High Point C&D Landfill
By: JAS/MMG
Date: 5/8/2014
Constituents Synonyms
Indeno(1,2,3-cd)pyrene
Isodrin
Isophorone
Isosafrole
Kepone
Methapyrilene
3-Methylcholanthrene
Methyl methanesulfonate
2-Methylnapthalene
Napthalene
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
o-Nitroaniline 2-Nitroaniline
m-Nitroaniline 3-Nitroaniline
p-Nitroaniline
Nitrobenzene
o-Nitrophenol 2-Nitrophenol
p-Nitrophenol 4-Nitrophenol
N-Nitrosodi-n-butylamine
Ni-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
N-Nitrosodipropylamine
N-Nitrosomethylethalamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
o-Toluidine
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
0,0,0-Triethyl phosphorothioate
sym-Trinitrobenzene 1,3,5-trinitroBenzene
\\RALNAS\Office_Share\Projects\WI High Point Landfill (C&D)\WIHIGHPOINT 16-1 (Phase 3 PTC)\L. WQMP\Table 2 -Analyte List- S+G.xlsx
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Appendix A
Monitoring Well Logs
Water Quality Monitoring Report
WI High Point, LLC
WI High Point C&D Landfill
Jamestown, North Carolina
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DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
DocuSign Envelope ID: 593AF09C-165A-4A52-836F-55BB87DDBC36
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Appendix B
Environmental Monitoring Report Form
Water Quality Monitoring Report
WI High Point, LLC
WI High Point C&D Landfill
Jamestown, North Carolina
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