8504_DukeBelewsCreek_CraigRd_July2016_2ndSemiAnnaul_DIN27236_20161003

Belews Creek Steam Station
Semiannual Groundwater
Monitoring Report
Craig Road Ash Landfill, Phase 1 and 2
Permit No. 8504
July 2016 Sampling Event
October 3, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventTABLE OF CONTENTS

ii

Table of Contents
Page
Report Verification ......................................................................................................................... i
Table of Contents .......................................................................................................................... ii
Section 1 - Background ................................................................................................................. 1
Section 2 - Methods ...................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 1 - BACKGROUND

1

Section 1 - Background
Belews Creek Steam Station is located on Belews Lake in southwestern Stokes County near
Pine Hall, North Carolina. The station is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy) and generates electricity by combustion of coal. The Craig Road Ash Landfill is
owned by Duke Energy and is permitted to receive coal ash, wastewater treatment sludge, and
off-spec flue gas desulfurization (FGD) residue (gypsum) generated at the Belews Creek Steam
Station under North Carolina Department of Environmental Quality (NCDEQ) Solid Waste
Permit No. 8504.
Phase 1 of the landfill was constructed with an engineered liner system and the waste boundary
contains an area of approximately 32.4 acres. Phase 1 began accepting waste in February
2008. Phase 2 of the landfill was constructed with an engineered liner system and the waste
boundary contains an area of approximately 34.7 acres. Placement of a protective cover layer of
approximately 137,000 tons of bottom ash on top of the Phase 2 liner system began on June
11, 2013. Phase 2 of the landfill received a Permit to Operate January 16, 2014 and started
receiving waste on June 13, 2014.
Phase 1 and Phase 2 of the Craig Road Ash Landfill and nearby area are portrayed on Figure 1.
The highest topographic area of the landfill site is at the center portion of the landfill along its
southern boundary. The predominant groundwater discharge areas are expected to be the
adjacent areas of Belews Lake located to the west, north, and east of the landfill. Figure 2
shows the landfill and the topography at the site.
As described in the Water Quality Monitoring Plan, the monitoring system for the landfill consists
of the following1:
Monitoring Wells: CRW-12 CRW-7 CRW-13 CRW-2 CRW-83 CRW-14
CRW-3 CRW-9 CRW-15 CRW-4 CRW-10 CRW-16 CRW-5 CRW-11 CRW-17
CRW-6 CRW-12 Surface Water Sample Locations: CRS-1 CRS-4 CRS-2 CRS-5 CRS-3 CRS-6
Leachate Sample Locations4: CWB-1 CWB-2
CWB-3
1 Water Quality Monitoring Plan – Phase1/Phase 2 Craig Road Landfill Expansion Duke Energy – Belews
Creek Steam Station, Belews Creek, North Carolina, S&ME Project No. 1356-10-041, April 26, 2012. 2 Monitoring well CRW-1 was abandoned on July 13, 2012, due to construction of Phase 2 of the landfill. 3 Monitoring well CRW-8 was damaged and subsequently replaced by CRW-8R on April 11, 2013. 4 The leachate sample locations are not described in the Water Quality Monitoring Plan but monitoring the
leachate in conjunction with the groundwater monitoring event is a requirement of the Permit to Operate. Leachate sample locations CWB-1 and CWB-2 were formerly referred to as E-
WWBLeachate and W-WWBLeachate, respectively.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 1 - BACKGROUND

2

The sampling locations are depicted on Figure 2. A summary of monitoring well construction
information is presented in Table 1. According to the Water Quality Monitoring Plan, monitoring
well CRW-10 serves as a background water quality monitoring well.
Surface water sampling locations CRS-1 and CRS-2 are located on perennial streams which
drain to Belews Lake. Sampling locations CRS-4 and CRS-5 are located at groundwater seeps.
Sampling locations CRS-3 and CRS-6 are located at the outlets of the two landfill under-drains.
There is a single non-contact stormwater basin located to the north of the landfill. This basin is
located just north of CRW-4 and shown on Figure 2 as “Primary BMP”. There are three
stormwater basins that receive contact stormwater and leachate. These basins are shown on
Figure 2 as “West Ash Runoff Storage Basin,” “East Ash Runoff Storage Basin,” and “Phase 2
Contact Water Basin.”
Leachate sample locations are located where the leachate collection pipes drain into the contact
stormwater/leachate basins. The contact stormwater/leachate basins and leachate sample
locations are shown on Figure 2.
Monitoring wells CRHS-9 and CRHS-31 were installed as part of the site suitability study for
Phase 2 and were left in place during the January 2013 sampling event with the intent that they
would become part of the permanent groundwater monitoring network for the landfill. Due to the
poor performance of these wells with respect to recharge, these wells were replaced in April
2013 with monitoring wells CRW-12 and CRW-13, respectively.
Monitoring wells CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17 have had historically high
turbidity measurements reported in the wells. On May 2, 2015, Duke Energy attempted to
redevelop these monitoring wells. On June 29, 2015, Duke Energy purged additional well
volumes from these wells using each well’s dedicated pump in an effort to reduce the turbidity in
the wells. During the July 2016 sampling event, the turbidity measurements in these wells were
reported at 73.5, 32.7, 13.2, 500, and 37.7 Nephelometric Turbidity Units (NTU), respectively.
Due to the continued high turbidity measurements in the monitoring wells, Duke Energy is
considering the replacement of CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17. Due to the
elevated turbidity measurements at these wells and in other wells in the monitoring system,
HDR will review the turbidity results at all monitoring wells and make recommendations to Duke
concerning redevelopment and/or replacement.

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 2 - METHODS

3

Section 2 - Methods
2.1 Sampling and Analysis Methods
The collection of samples and documentation of sampling was performed by Duke Energy
personnel (Duke Energy Carolinas Field Certification #5193) according to the North Carolina
Solid Waste Management Guidelines. Copies of the field sampling forms are included in
Appendix A. The parameters and constituents sampled were selected by Duke Energy and the
NCDEQ Division of Solid Waste and were analyzed by Duke Energy Analytical Laboratory
(North Carolina Laboratory Certification #248) and provided to HDR by Duke Energy. The
laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater, surface water, and leachate samples were analyzed using the following
analytical methods:
 Barium, boron, chromium, copper, iron, manganese, nickel, and zinc using Solid Waste
(SW)-8465 Method 6010D
 Arsenic, cadmium, lead, selenium, and silver using SW-846 Method 6020B
 Chloride, fluoride, nitrate as nitrogen, and sulfate using US Environmental Protection
Agency (EPA) SW-846 Method 9056A
 Mercury using EPA SW-846 Method 7470A
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells CRW-2, CRW-3, CRW-4, CRW-5, CRW-6, CRW-
7, CRW-8R, CRW-9, CRW-10, CRW-11, CRW-12, CRW-13, CRW-14, CRW-15, CRW-
16, and CRW-17. Data was also received for surface water sample locations CRS-1,
CRS-2, CRS-3, CRS-4, CRS-5, and CRS-6. Leachate sample data was received for
locations CWB-1 and CWB-2. A leachate sample was not collected at CWB-3 due to
lack of discharge from the leachate pipe at this location. The samples were collected on
July 11 and 12, 2016 and HDR received the data on August 3, 2016.
 Reviewed the laboratory analytical results for the samples. The Electronic Data
Deliverables (EDDs) provided by Duke Energy were adapted to conform to the format
requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J)
to indicate a measured concentration that is equal to or greater than the laboratory’s

 5 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed August 30, 2016)
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 2 - METHODS

4

method reporting limit (MRL) but less than the Solid Waste Section Limit6 (SWSL).
Copies of the original EDDs are retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
6 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 3 - RESULTS
5
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows from the
sampling event for the site are shown on Figure 3. These contours were developed using the
groundwater elevations measured on the date of sampling. The surface water elevation for
Belews Lake was assumed at 724.5 feet. Calculated groundwater flow velocities are presented
on Table 2.
Groundwater flow at the site is from areas of higher topography located along the southern,
central portion of the landfill toward Belews Lake to the northwest, north, and to the northeast
and east toward the canal.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater samples collected at the monitoring wells and at
surface water locations CRS-4 and CRS-5 are summarized in Table 4. The analysis results for
these locations are compared to the groundwater standards found in Title 15A NCAC 02L .0202
(g) (2L Standards)7. Concentrations with values that attain or exceed the 2L Standards are
noted in Table 4 by bold font. A summary of the field and analytical results that attain or exceed
the 2L Standards and a preliminary analysis of the cause and significance of the exceedances
are presented in Table 5.
Surface water sample locations CRS-1 and CRS-2 are located on perennial streams and CRS-3
and CRS-6 are located at the outlets of landfill under-drains. The streams and under-drains flow
to Belews Lake. Belews Lake is classified by the NCDEQ Division of Water Quality as a Class C
water body. As a result, the field and analytical results from these locations are compared to
Title 15A, NCAC, Subchapter 2B Standards (2B Standards) for Class C water. The field and
analytical results of the surface water sampling are summarized in Table 6.
The field and analytical results for leachate sampling are summarized in Table 7.
Concentrations with values that are equal to or greater than the SWSLs are noted by gray cells
in Tables 4, 6, and 7.
Selected samples were diluted as is normal laboratory practice to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
7 Surface water locations CRS-4 and CRS-5 are located at groundwater seeps. Therefore, the analytical
results at these locations are compared to the Title 15A NCAC 02L .0202 (g) groundwater quality standards (2L Standards).
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2
July 2016 Sampling EventSECTION 3 - RESULTS
6
HDR prepared and submitted an assessment to NCDEQ on exceedances of the 2L and 2B
Standards at Phase 1 of this landfill (Groundwater Assessment, Belews Creek Steam Station,
Craig Road Ash Landfill, December 21, 2012).
The report assessed 2L Standard exceedances for:
 Chromium at CRW-2 and CRW-9
 Iron at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-8, CRW-9, CRS-4, and CRS-5
 Manganese at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-9, CRS-4, and CRS-5
The report assessed 2B Standard exceedances for:
 Iron at CRS-2 and CRS-3
The assessment report concluded that at the time of the assessment the exceedances
evaluated were naturally occurring and were not related to impacts from the landfill.

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0
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0
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4
0
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a
p
r
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l
i
t
e
/
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2

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V
C
CR
W
-
1
7

1
/
6
/
2
0
1
1

3
6
.
2
6
2
7
8
5
4

-
8
0
.
0
6
7
1
9
8
0

8
3
4
.
5
6

8
3
1
.
6
2

2
.
9
4

8
0
0
.
1
9

3
4
.
3
7

4
1
.
9
4

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1
.
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4

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1
.
9
4
-
3
1
.
9
4

S
a
p
r
o
l
i
t
e

2

P
V
C
No
t
e
s
:
1
.

T
O
C

i
n
d
i
c
a
t
e
s

t
o
p

o
f

c
a
s
i
n
g
.
2
.

f
t
.

i
n
d
i
c
a
t
e
s

f
e
e
t
.
3
.

i
n
.

i
n
d
i
c
a
t
e
s

i
n
c
h
e
s

n
o
m
i
n
a
l

d
i
a
m
e
t
e
r
.
4
.

P
V
C

i
n
d
i
c
a
t
e
s

p
o
l
y
v
i
n
y
l

c
h
l
o
r
i
d
e
.
5
.

P
W
R

i
n
d
i
c
a
t
e
s

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
.
6
.

H
o
r
i
z
o
n
t
a
l

d
a
t
u
m

N
A
D
8
3
.
7
.

V
e
r
t
i
c
a
l

d
a
t
u
m

i
s

N
A
V
D

8
8
.
8
.

D
e
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

g
a
u
g
e
d

o
n

J
u
l
y

1
1

a
n
d

1
2
,

2
0
1
6
.
9
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

D
u
k
e

E
n
e
r
g
y

o
n

A
u
g
u
s
t

3
,

2
0
1
6
.
Page 1 of 1
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
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r

F
l
o
w

V
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l
o
c
i
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s

-

J
u
l
y

2
0
1
6
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
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Cr
a
i
g

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l
Ph
a
s
e

1

a
n
d

2

-

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e
r
m
i
t

N
o
.

8
5
0
4
CR
W
-
2

7
4
0

7
3
5

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6
3

0
.
0
3

0
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4
1

0
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5
9

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5
CR
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3
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6
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5
5

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2

0
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4
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0
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5
CR
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8
R

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5

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5
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0
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CR
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7
5
5

7
5
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3

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0
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0
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4
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0
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2
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9

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9
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5

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2
5
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CR
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4
.
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5

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5

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0
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0
.
2
5
9

0
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1
4
CR
W
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3

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9
5

7
9
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2
7
4

0
.
0
2

0
.
4
1

0
.
2
5
9

0
.
0
3
CR
W
-
1
4

7
7
0

7
6
5

7
3

0
.
0
7

0
.
4
1

0
.
2
5
9

0
.
1
1
CR
W
-
1
5

7
3
5

7
3
3
.
4
2

1
6

0
.
1
0

0
.
4
1

0
.
2
5
9

0
.
1
6
CR
W
-
1
6

7
3
5

7
3
0

2
6
0

0
.
0
2

0
.
4
1

0
.
2
5
9

0
.
0
3
CR
W
-
1
7

8
0
0
.
1
9

8
0
0

9

0
.
0
2

0
.
4
1

0
.
2
5
9

0
.
0
3
No
t
e
s
:

1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

a
p
p
r
o
x
i
m
a
t
e
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.

2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.

3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.

4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.

5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.

6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
ay
e
r
e
d

b
e
d
r
o
c
k
)
.

7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

t
e
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h
s

m
e
a
s
u
r
e
d

o
n

J
u
l
y

1
1

a
n
d

1
2
,

2
0
1
6
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(
%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Velocity
(f
t
/
d
a
y
)
We
l
l

I
D

U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

E
l
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

E
l
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

D
i
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

t
h
r
o
u
g
h

We
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(
f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Cr
a
i
g

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l
Ph
a
s
e

1

a
n
d

2

-

P
e
r
m
i
t

N
o
.

8
5
0
4
7/
1
1
/
2
0
1
6

C
R
W
-
2

3
8
.
2
4

2
2
.
8
0

7
3
8
.
6
6

N
o
r
m
a
l

N
o
n
e

L
F

2
5
0

2
.
5
2

4
.
5
0

N
/
A

1
8
.
1
3

3
8

5
.
9

3
1
.
4

3
7
0

7
.
6
5
7/
1
1
/
2
0
1
6

C
R
W
-
3

1
8
.
8
4

8
.
4
4

7
3
7
.
9
5

T
u
r
b
i
d

N
o
n
e

C
P

N
/
A

1
.
7
0

1
0
.
0
0

N
O

1
6
.
9
5

6
7

5
.
7

7
3
.
5

3
4
0

5
.
1
8
7/
1
1
/
2
0
1
6

C
R
W
-
4

3
0
.
1
9

2
2
.
9
3

7
5
0
.
6
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
1
8

3
.
7
5

N
O

1
6
.
3
1

6
3

6
.
3

4
.
3

3
2
3

8
.
7
9
7/
1
2
/
2
0
1
6

C
R
W
-
5

2
3
.
1
6

1
6
.
5
1

7
4
8
.
2
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
0
8

3
.
7
5

N
O

1
6
.
0
6

8
9

6
.
0

3
.
5

2
2
7

0
.
0
0
7/
1
2
/
2
0
1
6

C
R
W
-
6

3
0
.
2
0

2
3
.
8
3

7
5
9
.
2
7

T
u
r
b
i
d

N
o
n
e

C
P

N
/
A

1
.
0
4

2
.
2
5

Y
E
S

1
7
.
9
9

5
8

5
.
7

5
7

3
7
5

1
.
5
5
7/
1
2
/
2
0
1
6

C
R
W
-
7

2
9
.
9
0

2
5
.
1
3

7
5
9
.
9
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

0
.
7
8

0
.
7
5

Y
E
S

1
8
.
3
2

6
6

5
.
9

3
3
.
9

3
5
2

4
.
7
4
7/
1
2
/
2
0
1
6

C
R
W
-
8
R

4
0
.
1
8

2
5
.
1
9

7
5
1
.
2
0

N
o
r
m
a
l

N
o
n
e

L
F

3
3
0

2
.
4
4

2
.
4
0

N
/
A

1
6
.
5
3

7
3

5
.
8

3
2
.
7

3
9
4

8
.
2
1
7/
1
2
/
2
0
1
6

C
R
W
-
9

3
9
.
6
2

2
6
.
5
9

7
4
3
.
0
8

N
o
r
m
a
l

N
o
n
e

L
F

2
7
0

2
.
1
3

2
.
2
0

N
/
A

1
7
.
8
6

5
1

6
.
0

1
6
.
5

3
8
8

6
.
2
7
7/
1
2
/
2
0
1
6

C
R
W
-
1
0

3
0
.
1
6

2
3
.
5
8

7
5
3
.
6
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
0
7

4
.
7
5

N
O

1
4
.
9
8

1
9
9

5
.
6

5
.
4

4
9
4

4
.
7
4
7/
1
2
/
2
0
1
6

C
R
W
-
1
1

3
8
.
5
2

3
0
.
3
7

7
8
5
.
7
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
3
3

8
.
0
0

N
O

1
7
.
6
7

1
1
9

5
.
8

1
3
.
2

8
1
0

8
.
0
6
7/
1
1
/
2
0
1
6

C
R
W
-
1
2

4
4
.
6
5

3
3
.
8
8

8
0
4
.
0
5

T
u
r
b
i
d

N
o
n
e

L
F

3
3
0

1
.
7
6

4
.
4
5

N
/
A

1
6
.
3
6

6
4

5
.
5

5
0
0

7
1
6

7
.
7
9
7/
1
1
/
2
0
1
6

C
R
W
-
1
3

3
9
.
2
8

2
9
.
4
5

7
9
3
.
0
4

T
u
r
b
i
d

N
o
n
e

C
P

N
/
A

1
.
6
0

8
.
7
5

N
O

1
5
.
1
5

1
2
6

6
.
0

1
8
6

5
3
5

8
.
1
2
7/
1
1
/
2
0
1
6

C
R
W
-
1
4

4
1
.
4
4

2
5
.
0
8

7
6
9
.
7
9

N
o
r
m
a
l

N
o
n
e

L
F

4
1
2

2
.
6
7

1
.
8
5

N
/
A

1
5
.
8
4

2
3
5

6
.
1

5
.
8

5
6
3

5
.
2
3
7/
1
1
/
2
0
1
6

C
R
W
-
1
5

3
8
.
8
2

3
5
.
0
1

7
3
3
.
4
2

N
o
r
m
a
l

N
o
n
e

L
F

1
7
4

0
.
6
2

1
.
0
0

N
/
A

1
8
.
0
3

9
0

5
.
7

3
.
1

5
9
4

7
.
4
2
7/
1
1
/
2
0
1
6

C
R
W
-
1
6

5
0
.
6
6

4
2
.
7
5

7
3
0
.
8
4

N
o
r
m
a
l

N
o
n
e

L
F

2
1
0

1
.
2
9

2
.
9
5

N
/
A

1
7
.
4
9

6
4

5
.
7

9
.
3

3
2
8

3
.
5
3
7/
1
2
/
2
0
1
6

C
R
W
-
1
7

4
1
.
7
0

3
4
.
3
7

8
0
0
.
1
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
0

7
.
0
0

N
O

1
6
.
2
9

3
5

5
.
3

3
7
.
7

5
3
6

5
.
0
5
7/
1
2
/
2
0
1
6

C
R
S
-
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
0
.
1
6

1
0
6

7
.
2

1
3
.
2

3
3
8

6
.
5
8
7/
1
2
/
2
0
1
6

C
R
S
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
1
.
3
6

1
1
8

7

1
0
.
6

2
5
0

7
.
6
3
7/
1
1
/
2
0
1
6

C
R
S
-
3

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
1
.
1
6

3
0
0

7
.
0

4
.
8

2
2
6

6
.
0
0
7/
1
1
/
2
0
1
6

C
R
S
-
4

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

1
8
.
6
6

1
0
7

6
.
0

1
0
.
4

2
3
8

5
.
8
7
7/
1
2
/
2
0
1
6

C
R
S
-
5

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

1
9
.
1
9

9
2

6
.
2

4
1
.
7

2
2
4

6
.
9
9
7/
1
1
/
2
0
1
6

C
R
S
-
6

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
2
.
2
6

9
6

7
.
0

5
.
0

5
4
1

8
.
3
1
7/
1
1
/
2
0
1
6

C
W
B
-
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
2
.
7
4

4
5
9
1

4
.
2

1
2
.
5

6
9
9

8
.
0
4
7/
1
1
/
2
0
1
6

C
W
B
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
P

N
/
A

N
/
A

N
/
A

N
/
A

2
2
.
3
8

6
2
5
6

4
.
2

3
.
1

7
0
4

7
.
8
1
1/
1
1
/
2
0
1
6

C
W
B
-
3

N
/
A

N
/
A

N
/
A
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
.
P
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

m
L
/
m
i
n

i
n
d
i
c
a
t
e
s

m
i
l
l
i
l
i
t
e
r
s

p
e
r

m
i
n
u
t
e
.
6
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
7
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
8
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

L
e
a
c
h
a
t
e

s
a
m
p
l
e
s

C
W
B
-
1

a
n
d

C
W
B
-
2

w
e
r
e

f
o
r
m
e
r
l
y

i
d
e
n
t
i
f
i
e
d

a
s

E
-
W
W
B

L
e
a
c
h
a
t
e

a
n
d

W
-
W
W
B

L
e
a
c
h
a
t
e
,

r
e
s
p
e
c
t
i
v
e
l
y
.
11
.

L
e
a
c
h
a
t
e

s
a
m
p
l
e

C
W
B
-
3

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d

d
u
e

t
o

l
a
c
k

o
f

d
i
s
c
h
a
r
g
e

f
r
o
m

t
h
e

l
e
a
c
h
a
t
e

p
i
p
e

i
n
t
o

t
h
e

P
h
a
s
e

2

l
e
a
c
h
a
t
e

p
o
n
d
.
12
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

o
n

A
u
g
u
s
t

3
,

2
0
1
6
.
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(y
e
s
/
n
o
)
TE
M
P
(d
e
g

C
)
Dr
y

-

N
o

S
a
m
p
l
e
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Լ /c
m
)
pH (SU)TURBIDITY (NTU)ORP (mV-NHE)
AP
P
E
A
R
A
N
C
E
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

PU
M
P

R
A
T
E
(m
L
/
m
i
n
)
SA
M
P
L
E
DA
T
E
S

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
t
)
DE
P
T
H

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Page 1 of 1
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11
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*

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4
3
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3
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12
.

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15
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬▬►0.0
SS 237.3 ▬▬►227 218.2 ▬▬►227
SS 75.3 ▬/▬►75 73.3 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.02 ▬▬►7.02 7.02 ▬▬►7.02
B (4.00)3.99 ▬▬►4.00 4.01 ▬▬►4.00
B (10.00)10.08 ▬/▬►10.04 10.08 ▬/▬►10.04
20.65 20.57
pH Check B (7.00)▬▬►7.13
Time:0.00
433 ▬▬►440 439 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.49 20.40
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.81 ▬▬►8.85 8.92 ▬▬►8.88
After Cal 8.88 100.33 8.88 100.04
LCS 8.92 100.78 8.83 99.48
LCSD 8.91 -0.11 8.85 0.23
SS 52.5 ▬/▬►54.5 52.7 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 744.7
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
20.20 20.09
743.40 743.90
103.1
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
101.0
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)743.40 CALIBRATION BP (mmHg)743.90
Calibration Date / Time 11-Jul-16 330 12-Jul-16 335
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):July 11 - 12, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Mostly clear, slight breeze, 75 to 85 deg F.
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S0205
ANALYZER MODEL#:MS5 66121
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 218.2 ▬▬►227 220.8 ▬/▬►227
SS 73.3 ▬/▬►75 76.9 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.02 ▬▬►7.02 6.94 ▬/▬►7.02
B (4.00)4.01 ▬▬►4.00 4.03 ▬/▬►4.00
B (10.00)10.08 ▬/▬►10.04 9.95 ▬/▬►10.04
20.57 20.52
pH Check B (7.00)▬▬►7.13
Time:0.00
439 ▬▬►440 437 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.40 20.35
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.92 ▬▬►8.88 8.82 ▬/▬►8.89
After Cal 8.88 100.04 8.82 99.26
LCS 8.83 99.48 8.82 99.26
LCSD 8.85 0.23 8.83 0.11
SS 52.7 ▬/▬►54.5 53.1 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 744.9
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
20.09 20.09
743.90 744.64
101.0
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
104.3
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)743.90 CALIBRATION BP (mmHg)744.64
Calibration Date / Time 12-Jul-16 335 13-Jul-16 415
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):July 11 - 12, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Mostly clear, calm, 70 to 85 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S0205
ANALYZER MODEL#:MS5 66121
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬▬►0.0
SS 222.0 ▬▬►227 223.4 ▬▬►227
SS 73.0 ▬/▬►75 73.9 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.04 ▬▬►7.02 6.94 ▬▬►7.02
B (4.00)4.01 ▬▬►4.00 3.93 ▬▬►4.00
B (10.00)10.07 ▬/▬►10.04 10.07 ▬/▬►10.04
20.67 20.55
pH Check B (7.00)▬▬►7.13
Time:0.00
436 ▬▬►440 438 ▬▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.53 20.37
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.85 ▬▬►8.85 8.90 ▬▬►8.88
After Cal 8.85 99.99 8.88 99.96
LCS 8.86 100.10 8.86 99.74
LCSD 8.84 -0.23 8.87 0.11
SS 53.5 ▬/▬►53.5 53.5 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 744.7
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
20.20 20.05
743.40 743.90
100.8
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
103.4
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)743.40 CALIBRATION BP (mmHg)743.90
Calibration Date / Time 11-Jul-16 310 12-Jul-16 315
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):July 11 - 12, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Mostly clear, slight breeze, 75 to 85 deg F.
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0730
ANALYZER MODEL#:HL4 400440
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 223.4 ▬▬►227 224.2 ▬/▬►227
SS 73.9 ▬/▬►75 77.9 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)6.94 ▬▬►7.02 7.11 ▬/▬►7.02
B (4.00)3.93 ▬▬►4.00 4.09 ▬/▬►4.00
B (10.00)10.07 ▬/▬►10.04 10.12 ▬/▬►10.04
20.55 20.54
pH Check B (7.00)▬▬►7.13
Time:0.00
438 ▬▬►440 439 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.37 20.41
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.90 ▬▬►8.88 8.87 ▬/▬►8.89
After Cal 8.88 99.96 8.89 99.97
LCS 8.86 99.74 8.84 99.41
LCSD 8.87 0.11 8.82 -0.23
SS 53.5 ▬/▬►53.5 53.9 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 744.0 (mmHg)Ending BP 744.9
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
20.05 20.05
743.90 744.64
103.4
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
104.0
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)743.90 CALIBRATION BP (mmHg)744.64
Calibration Date / Time 12-Jul-16 315 13-Jul-16 340
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING
DATE (s):July 11 - 12, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Mostly clear, calm, 70 to 85 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0730
ANALYZER MODEL#:HL4 400440
28.24 38.24
15 (psi)6 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 4.50 (gal)PSP 7/11/2016 1005 NA
DRAW-DOWN 1.70 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
10:00 24.50 250 18.13 38 5.86 31.4 370 7.65 N/A
9:55 24.50 250 17.94 38 5.84 48.1 369 7.56
N/A
9:50 24.50 250 17.62 38 5.86 32.6 369 7.60 N/A
9:45 24.50 250 17.29 37 5.82 41.4 368 7.47
N/A
9:40 24.50 250 17.19 37 5.81 44.6 365 7.51 N/A
9:35 24.50 250 17.13 37 5.80 47.9 363 7.54
N/A
9:30 24.50 250 17.15 36 5.84 89.4 360 7.60 N/A
9:25 24.50 250 17.00 34 5.78 64.5 358 7.56
N/A
9:20 24.50 250 16.78 35 5.77 104.0 355 7.60 N/A
9:15 24.50 250 17.15 33 5.76 87.8 350 7.64
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.80 WATER COLUMN (ft)15.44 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)738.66 WELL VOLUME 2.52
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
LIFT WELL CAP ONE FOOT UP FROM PVC WELL
CASING AND PUMP AT 480 mL/min.
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)761.46 MIDDLE OF WETTED SCREEN (ft toc)33.24
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.24 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)36.00
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
8.84 18.84
15 (psi)7 (sec)(sec)
(gal)
1.70 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)746.39 MIDDLE OF WETTED SCREEN (ft toc)13.84
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)18.84 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)17.50
LIFT WELL CAP ONE FOOT UP FROM PVC WELL
CASING AND PUMP AT 528 mL/min.
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 3
SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)8.44 WATER COLUMN (ft)10.40 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)737.95 WELL VOLUME 1.70
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.75 NO 16.91 68 5.90 834.0 269
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.31
1.75 NO 17.01 67 5.84 193.0 323 5.04
1.75 NO 16.99 68 5.94 342.0 307 4.84
2.00 NO 16.95 67 5.71 73.5 340 5.18
1.75 NO 16.90 67 5.76 113.0 335 5.19
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
10.00 PSP 7/11/2016 1145 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
20.19 30.19
18 (psi)9 (sec)(sec)
(gal)
1.18 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)773.53 MIDDLE OF WETTED SCREEN (ft toc)26.56
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.19 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)28.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)22.93 WATER COLUMN (ft)7.26 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)750.60 WELL VOLUME 1.18
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 16.23 64 6.28 29.5 317
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.64
1.25 NO 16.31 63 6.25 4.3 323 8.79
1.25 NO 16.38 63 6.23 6.8 319 8.77
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 7/11/2016 1230 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
13.16 23.16
18 (psi)10 (sec)(sec)
(gal)
1.08 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-5
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)764.74 MIDDLE OF WETTED SCREEN (ft toc)19.84
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.16 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)22.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)16.51 WATER COLUMN (ft)6.65 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)748.23 WELL VOLUME 1.08
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 15.57 90 6.03 80.5 212
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
0.00
1.25 NO 16.06 89 5.98 3.5 227 0.00
1.25 NO 15.89 89 6.04 6.3 229 0.00
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 7/12/2016 0735 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
20.20 30.20
18 (psi)9 (sec)(sec)
(gal)
1.04 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)783.10 MIDDLE OF WETTED SCREEN (ft toc)27.02
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.20 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
Well evacuated 7/11/2016 at 1255 hrs.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)23.83 WATER COLUMN (ft)6.37 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)759.27 WELL VOLUME 1.04
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 26.20 NO 16.97 60 5.44 30.2 389
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
2.23 0.65
0.25 YES 17.99 58 5.69 57.0 375 1.55
0.75 YES 17.54 56 5.65 55.4 379 1.92
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
2.25 PSP 7/12/2016 0755 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Water level at 0750 hrs on 7/12/2016 is 22.92 feet below top of casing (1.19 gallons)
19.90 29.90
18 (psi)5 (sec)(sec)
(gal)
0.78 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-7
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)785.08 MIDDLE OF WETTED SCREEN (ft toc)27.52
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)29.90 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
Well evacuated @ 1305 on 7/11/2016 PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.13 WATER COLUMN (ft)4.77 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)759.95 WELL VOLUME 0.78
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
0.75 YES 18.32 66 5.87 33.9 352
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.74
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
0.75 PSP 7/12/2016 0805 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Water level at 0800 hrs on 7/12/2016 was 25.15 (0.77 gallons).
30.18 40.18
18 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
Lift well cap up one foot from PVC well casing, pump at 330 mL/min with settings indicated above and remove 2 gallons prior to recording low flow parameters.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 2.40 (gal)PSP 7/12/2016 0850 NA
DRAW-DOWN 0.71 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A8:45 25.90 330 16.53 73 5.76 32.7 394 8.21
N/A
8:40 25.90 330 16.70 74 5.69 28.2 391 8.18 N/A
8:35 25.90 330 16.51 75 5.69 32.9 385 8.15
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
2.44
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.19 WATER COLUMN (ft)14.99 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)751.20 WELL VOLUME
SEE NOTE BELOW FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)776.39 MIDDLE OF WETTED SCREEN (ft toc)35.18
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)40.18 GS ELEV (ft msl)773.68 PUMP INTAKE DEPTH (ft TOC)38.68
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-8R
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
29.62 39.62
18 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)769.67 MIDDLE OF WETTED SCREEN (ft toc)34.62
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)39.62 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)38.50
Target flow rate of 200 ml/min - See note PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)26.59 WATER COLUMN (ft)13.03 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)743.08 WELL VOLUME 2.13
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:25 28.00 270 17.81 48 5.89 34.2 386 6.49 N/A
9:20 28.00 270 17.61 48 5.84 50.2 387 6.43
N/A
9:35 28.00 270 17.59 50 5.93 20.2 388 6.31 N/A
9:30 28.00 270 17.94 49 5.89 24.1 386 6.47
N/A9:40 28.00 270 17.86 51 6.00 16.5 388 6.27
DRAW-DOWN 1.41 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.20 (gal)PSP 7/12/2016 0945 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Turbidity will decrease below 10 ntu if well is pumped at a flow rate of 200 mL/min.
20.16 30.16
18 (psi)10 (sec)(sec)
(gal)
1.07 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-10
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)777.23 MIDDLE OF WETTED SCREEN (ft toc)26.87
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)30.16 GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)29.00
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)23.58 WATER COLUMN (ft)6.58 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)753.65 WELL VOLUME 1.07
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 14.41 181 5.43 63.0 596
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.39
1.25 27.56 NO 15.18 198 5.55 11.5 501 4.63 0.42
1.25 NO 14.90 193 5.52 65.1 535 4.22
0.50 NO 14.98 199 5.56 5.4 494 4.74
0.50 NO 15.07 200 5.56 10.7 496 4.75
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.75 LDC 7/12/2016 1025 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
28.52 38.52
15 (psi)11 (sec)(sec)
(gal)
1.33 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-11
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)816.12 MIDDLE OF WETTED SCREEN (ft toc)34.45
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.52 GS ELEV (ft msl)813.38 PUMP INTAKE DEPTH (ft TOC)37.52
SEE NOTE FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 4
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
1.33
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)30.37 WATER COLUMN (ft)8.15 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)785.75 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.50 NO 16.50 113 5.93 96.9 705
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.04
1.50 32.02 NO 17.26 118 5.74 32.0 795 8.08 1.06
1.50 NO 16.81 115 5.92 104.0 753 8.10
1.25 NO 17.67 119 5.78 13.2 810 8.06
1.25 NO 17.96 118 5.73 17.0 828 8.02
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.00 LDC 7/12/2016 0930 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Tall grass
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Remove hydraulic head by drawing down water level to 33.00 ft at 360 mL/min.
34.65 44.65
15 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-12
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)837.93 MIDDLE OF WETTED SCREEN (ft toc)39.65
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.65 GS ELEV (ft msl)835.00 PUMP INTAKE DEPTH (ft TOC)44.15
SEE NOTE FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
1.76
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)33.88 WATER COLUMN (ft)10.77 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)804.05 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
7:50 34.54 330 16.26 62 5.16 49.9 571 7.87 N/A
7:45 34.54 330 16.36 66 5.01 84.0 541 7.84
N/A
8:00 34.54 330 16.19 61 5.40 40.9 591 7.97 N/A
7:55 34.54 330 16.23 62 5.28 52.2 588 7.78
N/A
8:10 34.54 330 16.19 62 5.39 51.4 614 7.82 N/A
8:05 34.54 330 16.23 63 5.38 33.5 602 7.78
N/A
8:20 34.54 330 16.29 63 5.43 154.0 683 7.73 N/A
8:15 34.54 330 16.24 63 5.42 71.9 628 7.73
N/A
8:30 34.54 330 16.36 64 5.48 500.0 716 7.79 N/A
8:25 34.54 330 16.34 63 5.47 328.0 709 7.70
DRAW-DOWN 0.66 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 4.45 (gal)LDC 7/11/2016 0835 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Weeds around well.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Lift well cap up 3 ft from top of PVC well casing and pump at 400 mL/min
29.28 39.28
19 (psi)10 (sec)(sec)
(gal)
1.60 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-13
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)822.49 MIDDLE OF WETTED SCREEN (ft toc)34.37
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)39.28 GS ELEV (ft msl)819.44 PUMP INTAKE DEPTH (ft TOC)38.78
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
1.60
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)29.45 WATER COLUMN (ft)9.83 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)793.04 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 15.19 103 5.91 284.0 564
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.07
1.75 NO 15.15 126 5.99 80.8 533 8.01
1.75 NO 15.16 125 5.98 78.5 544 8.03
1.75 NO 15.15 126 6.01 186.0 535 8.12
1.75 NO 15.11 126 6.01 57.5 532 8.02
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.75 LDC 7/11/2016 0935 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Tall grass around wells.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
26.44 41.44
20 (psi)5 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-14
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)794.87 MIDDLE OF WETTED SCREEN (ft toc)33.94
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.44 GS ELEV (ft msl)792.23 PUMP INTAKE DEPTH (ft TOC)40.44
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
2.67
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)25.08 WATER COLUMN (ft)16.36 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)769.79 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:05 25.16 412 15.66 239 6.09 5.1 566 5.14 N/A
10:00 25.16 412 15.64 238 6.09 6.2 575 5.04
N/A10:10 25.16 412 15.84 235 6.09 5.8 563 5.23
DRAW-DOWN 0.08 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.85 (gal)LDC 7/11/2016 1015 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Tall grass around well.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
28.82 38.82
25 (psi)11 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-15
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)768.43 MIDDLE OF WETTED SCREEN (ft toc)36.92
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.82 GS ELEV (ft msl)765.69 PUMP INTAKE DEPTH (ft TOC)38.32
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
0.62
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.01 WATER COLUMN (ft)3.81 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)733.42 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:45 37.22 174 17.30 89 5.67 2.5 602 7.21 N/A
10:40 37.22 174 17.04 89 5.69 3.0 595 7.27
N/A10:50 37.22 174 18.03 90 5.69 3.1 594 7.42
DRAW-DOWN 2.21 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.00 (gal)LDC 7/11/2016 1055 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
40.66 50.66
20 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-16
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)773.59 MIDDLE OF WETTED SCREEN (ft toc)46.71
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)50.66 GS ELEV (ft msl)770.58 PUMP INTAKE DEPTH (ft TOC)45.16
LIFT WELL CAP FIVE FOOT UP FROM PVC WELL
CASING AND PUMP AT 150 mL/min.
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
1.29
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.75 WATER COLUMN (ft)7.91 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)730.84 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:00 43.28 210 16.83 63 5.66 70.1 316 3.71 N/A
7:55 43.28 210 17.12 61 5.64 114.0 312 3.96
N/A
8:10 43.28 210 17.15 64 5.70 32.8 321 3.52 N/A
8:05 43.28 210 17.15 64 5.68 38.8 318 3.59
N/A
8:20 43.28 210 17.38 64 5.71 14.4 325 3.55 N/A
8:15 43.28 210 17.12 64 5.69 17.8 324 3.51
N/A8:25 43.28 210 17.49 64 5.72 9.3 328 3.53
DRAW-DOWN 0.53 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.95 (gal)PSP 7/11/2016 0830 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
31.70 41.70
30 (psi)15 (sec)(sec)
(gal)
1.20 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRW-17
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)834.56 MIDDLE OF WETTED SCREEN (ft toc)38.04
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.70 GS ELEV (ft msl)831.62 PUMP INTAKE DEPTH (ft TOC)40.70
SEE NOTES FOR SAMPLING PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
1.20
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)34.37 WATER COLUMN (ft)7.33 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)800.19 WELL VOLUME
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 36.71 NO 16.04 35 5.24 25.9 528
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.67 0.81
1.00 NO 15.95 34 5.27 122.0 532 4.98
1.00 NO 15.94 33 5.23 40.9 532 4.78
2.00 NO 16.29 35 5.32 37.7 536 5.05
1.00 NO 16.26 34 5.30 121.0 530 5.03
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.00 LDC 7/12/2016 0740 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Tall grass
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Leave pump intake where it is (1 ft from bottom) and pump at 200 to 300 mL/min. Pump 2 gallons before recording field parameters to remove hydraulic head.
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 7/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 20.16 106 7.20 13.2
1045
338 6.58
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 7/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 21.36 118 7.03 10.6
1010
250 7.63
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-3
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 21.16 300 6.96 4.8
1030
226 6.00
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-4
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 18.66 107 6.03 10.4
1055
238 5.87
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-5
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 7/12/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 19.19 92 6.18 41.7
0710
224 6.99
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CRS-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 22.26 96 6.98 5.0
1130
541 8.31
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CWB-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 22.74 4591 4.19 12.5
1235
699 8.04
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Location Formally Called "E-WWB-Leachate"
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CWB-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 22.38 6256 4.22 3.1
1205
704 7.81
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Location Formally Called "W-WWB-Leachate"
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Phase 2 Leachate Pond
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
TIME
LDC 7/11/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
DRY - No sample PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME CRAIG ROAD LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)11-Jul-2016 12-Jul-2016 WELL/LOCATION NAME CWB-3
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PERMIT #
CRW-2 CRW-3 CRW-4 CRW-5 CRW-6 CRW-7 CRW-8R CRW-9 CRW-10 CRW-11 CRW-12 CRW-13 CRW-14 CRW-15 CRW-16
YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 1 OF 2
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Melonie Martin, Kimberly Witt, Will Harrison, Keeley McCormick FIELD CREW LDC, PSP
WEATHER Jul 11 - Mostly clear, slight breeze, 75 to 85 deg F. Jul 12 - Mostly clear, calm, 70 to 85 deg F.
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING 85-04 SAMPLE DATE July 11 - 12, 2016
PERMIT #
CRW-17 CRS-1 CRS-2 CRS-3 CRS-4 CRS-5 CRS-6 CWB-1 CWB-2 CWB-3
YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES
YES
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES N/A N/A N/A N/A N/A N/A N/A N/A N/A
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING 85-04 SAMPLE DATE July 11 - 12, 2016
SITE CONTACT Melonie Martin, Kimberly Witt, Will Harrison, Keeley McCormick FIELD CREW LDC, PSP
WEATHER Jul 11 - Mostly clear, slight breeze, 75 to 85 deg F. Jul 12 - Mostly clear, calm, 70 to 85 deg F.
WELL LOCK CONDITION
PAGE 2 OF 2
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
7/11/2016 CRW-2 38.24 22.80 738.66 Normal None LF 250 2.52 4.50 N/A 18.13 38 5.9 31.4 370 7.65
7/11/2016 CRW-3 18.84 8.44 737.95 Turbid None C N/A 1.70 10.00 NO 16.95 67 5.7 73.5 340 5.18
7/11/2016 CRW-4 30.19 22.93 750.60 Normal None C N/A 1.18 3.75 NO 16.31 63 6.3 4.3 323 8.79
7/12/2016 CRW-5 23.16 16.51 748.23 Normal None C N/A 1.08 3.75 NO 16.06 89 6.0 3.5 227 0.00
7/12/2016 CRW-6 30.20 23.83 759.27 Turbid None C N/A 1.04 2.25 YES 17.99 58 5.7 57.0 375 1.55
7/12/2016 CRW-7 29.90 25.13 759.95 Normal None C N/A 0.78 0.75 YES 18.32 66 5.9 33.9 352 4.74
7/12/2016 CRW-8R 40.18 25.19 751.20 Normal None LF 330 2.44 2.40 N/A 16.53 73 5.8 32.7 394 8.21
7/12/2016 CRW-9 39.62 26.59 743.08 Normal None LF 270 2.13 2.20 N/A 17.86 51 6.0 16.5 388 6.27
7/12/2016 CRW-10 30.16 23.58 753.65 Normal None C N/A 1.07 4.75 NO 14.98 199 5.6 5.4 494 4.74
7/12/2016 CRW-11 38.52 30.37 785.75 Normal None C N/A 1.33 8.00 NO 17.67 119 5.8 13.2 810 8.06
7/11/2016 CRW-12 44.65 33.88 804.05 Turbid None LF 330 1.76 4.45 N/A 16.36 64 5.5 500.0 716 7.79
7/11/2016 CRW-13 39.28 29.45 793.04 Turbid None C N/A 1.60 8.75 NO 15.15 126 6.0 186.0 535 8.12
7/11/2016 CRW-14 41.44 25.08 769.79 Normal None LF 412 2.67 1.85 N/A 15.84 235 6.1 5.8 563 5.23
7/11/2016 CRW-15 38.82 35.01 733.42 Normal None LF 174 0.62 1.00 N/A 18.03 90 5.7 3.1 594 7.42
7/11/2016 CRW-16 50.66 42.75 730.84 Normal None LF 210 1.29 2.95 N/A 17.49 64 5.7 9.3 328 3.53
7/12/2016 CRW-17 41.70 34.37 800.19 Normal None C N/A 1.20 7.00 NO 16.29 35 5.3 37.7 536 5.05
7/12/2016 CRS-1 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 20.16 106 7.2 13.2 338 6.58
7/12/2016 CRS-2 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 21.36 118 7.0 10.6 250 7.63
7/11/2016 CRS-3 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 21.16 300 7.0 4.8 226 6.00
7/11/2016 CRS-4 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 18.66 107 6.0 10.4 238 5.87
7/12/2016 CRS-5 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 19.19 92 6.2 41.7 224 6.99
7/11/2016 CRS-6 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 22.26 96 7.0 5.0 541 8.31
7/11/2016 CWB-1 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 22.74 4591 4.2 12.5 699 8.04
7/11/2016 CWB-2 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 22.38 6256 4.2 3.1 704 7.81
7/11/2016 CWB-3 0.00 N/A N/A Normal None NP N/A N/A N/A N/A NS1 NS1 NS1 NS1 NS1 NS1
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
NS1 = Not sampled / Dry
BELEWS CREEK STEAM STATION
CRAIG ROAD LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-04

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070035
Project Name:BELEWS - GW CRAIG ROAD LF
Lab Contact: Anne Pridgeon
Date:7/29/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please note that CWB-3 was not received with this work order despite being included on the COC.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Duke Energy Analytical Lab Revision 1
Page 1 of 44
Reason: I have reviewed
this document.
Date: 2016.09.12 15:43:33
-04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016019894 BELEWS 11-Jul-16 10:05 AM PSP CRW-2
2016019895 BELEWS 11-Jul-16 11:45 AM PSP CRW-3
2016019896 BELEWS 11-Jul-16 12:30 PM PSP CRW-4
2016019897 BELEWS 12-Jul-16 7:35 AM PSP CRW-5
2016019898 BELEWS 12-Jul-16 7:55 AM PSP CRW-6
2016019899 BELEWS 12-Jul-16 8:05 AM PSP CRW-7
2016019900 BELEWS 12-Jul-16 8:50 AM PSP CRW-8R
2016019901 BELEWS 12-Jul-16 9:45 AM PSP CRW-9
2016019902 BELEWS 12-Jul-16 10:25 AM LDC CRW-10
2016019903 BELEWS 12-Jul-16 9:30 AM LDC CRW-11
2016019904 BELEWS 11-Jul-16 8:35 AM LDC CRW-12
2016019905 BELEWS 11-Jul-16 9:35 AM LDC CRW-13
2016019906 BELEWS 11-Jul-16 10:15 AM LDC CRW-14
2016019907 BELEWS 11-Jul-16 10:55 AM LDC CRW-15
2016019908 BELEWS 11-Jul-16 8:30 AM PSP CRW-16
2016019909 BELEWS 12-Jul-16 7:40 AM LDC CRW-17
2016019910 BELEWS 11-Jul-16 12:35 PM LDC CWB-1
2016019911 BELEWS 11-Jul-16 12:05 PM LDC CWB-2
2016019913 BELEWS 12-Jul-16 10:45 AM LDC CRS-1
2016019914 BELEWS 12-Jul-16 10:10 AM PSP CRS-2
2016019915 BELEWS 11-Jul-16 10:30 AM PSP CRS-3
2016019916 BELEWS 11-Jul-16 10:55 AM PSP CRS-4
2016019917 BELEWS 12-Jul-16 7:10 AM PSP CRS-5
2016019918 BELEWS 11-Jul-16 11:30 AM LDC CRS-6
2016019919 BELEWS 12-Jul-16 11:05 AM PSP FIELD BLANK
25 Total Samples
Duke Energy Analytical Lab Revision 1
Page 2 of 44
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:7/29/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab Revision 1
Page 3 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019894
Collection Date:11-Jul-16 10:05 AM
Site:CRW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)15 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.8 mg/L EPA 9056A 07/12/2016 09:48 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 09:48 BGN90340.1 1
Nitrate 0.25 mg/L EPA 9056A 07/12/2016 09:48B2 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 9056A 07/12/2016 09:48 BGN90340.023 1
Sulfate 0.28 mg/L EPA 9056A 07/12/2016 09:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.056 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.05 1
Calcium (Ca)2.50 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.01 1
Chromium (Cr)0.013 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Iron (Fe)3.08 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.01 1
Magnesium (Mg)1.84 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Manganese (Mn)0.040 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Nickel (Ni)0.006 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
Potassium (K)2.94 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.1 1
Sodium (Na)3.23 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.05 1
Zinc (Zn)0.013 mg/L SW 6010D 07/15/2016 11:22 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 17:35 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 17:35 CWSPEN311
Lead (Pb)1.18 ug/L SW 6020B 07/13/2016 17:35 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 17:35 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 17:35 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 60 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 4 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019895
Collection Date:11-Jul-16 11:45 AM
Site:CRW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)16 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 5.6 mg/L EPA 9056A 07/12/2016 11:23 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 11:23 BGN90340.1 1
Nitrate 1.0 mg/L EPA 9056A 07/12/2016 11:23B2 BGN90340.1 1
Nitrate as N 0.23 mg-N/L EPA 9056A 07/12/2016 11:23 BGN90340.023 1
Sulfate 3.8 mg/L EPA 9056A 07/12/2016 11:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.05 1
Calcium (Ca)4.33 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.01 1
Chromium (Cr)0.009 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Iron (Fe)3.84 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.01 1
Magnesium (Mg)3.19 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Manganese (Mn)0.083 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
Potassium (K)2.60 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.1 1
Sodium (Na)4.63 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.05 1
Zinc (Zn)0.011 mg/L SW 6010D 07/15/2016 11:26 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 17:41 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 17:41 CWSPEN311
Lead (Pb)1.85 ug/L SW 6020B 07/13/2016 17:41 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 17:41 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 17:41 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 69 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 5 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019896
Collection Date:11-Jul-16 12:30 PM
Site:CRW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 9056A 07/12/2016 11:39 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 11:39 BGN90340.1 1
Nitrate 4.7 mg/L EPA 9056A 07/12/2016 11:39B2 BGN90340.1 1
Nitrate as N 1.1 mg-N/L EPA 9056A 07/12/2016 11:39 BGN90340.023 1
Sulfate 2.3 mg/L EPA 9056A 07/12/2016 11:39 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:27 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.05 1
Calcium (Ca)5.02 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Iron (Fe)0.163 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.01 1
Magnesium (Mg)1.40 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
Potassium (K)1.61 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.1 1
Sodium (Na)5.18 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.05 1
Zinc (Zn)0.061 mg/L SW 6010D 07/15/2016 11:11 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 17:48 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 17:48 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 17:48 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 17:48 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 17:48 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 69 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 6 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019897
Collection Date:12-Jul-16 7:35 AM
Site:CRW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)25 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 9056A 07/12/2016 17:44 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 17:44 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 07/12/2016 17:44B2 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 07/12/2016 17:44 BGN90340.023 1
Sulfate 12 mg/L EPA 9056A 07/12/2016 17:44 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:35 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.015 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.05 1
Calcium (Ca)3.19 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Iron (Fe)6.82 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.01 1
Magnesium (Mg)2.73 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Manganese (Mn)0.098 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Nickel (Ni)0.011 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
Potassium (K)1.43 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.1 1
Sodium (Na)4.36 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.05 1
Zinc (Zn)0.021 mg/L SW 6010D 07/15/2016 11:30 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 17:09 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 17:09 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 17:09 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 17:09 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 17:09 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 85 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 7 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019898
Collection Date:12-Jul-16 7:55 AM
Site:CRW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.4 mg/L EPA 9056A 07/12/2016 18:00 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 18:00 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 07/12/2016 18:00B2 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 07/12/2016 18:00 BGN90340.023 1
Sulfate 19 mg/L EPA 9056A 07/12/2016 18:00 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:42 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.05 1
Calcium (Ca)2.60 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.01 1
Chromium (Cr)0.005 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Iron (Fe)1.90 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.01 1
Magnesium (Mg)2.48 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Manganese (Mn)0.076 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Nickel (Ni)0.018 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
Potassium (K)2.18 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.1 1
Sodium (Na)3.38 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.05 1
Zinc (Zn)0.019 mg/L SW 6010D 07/15/2016 11:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:14 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:14 CWSPEN311
Lead (Pb)1.13 ug/L SW 6020B 07/13/2016 18:14 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:14 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:14 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 61 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 8 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019899
Collection Date:12-Jul-16 8:05 AM
Site:CRW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.2 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 9056A 07/12/2016 18:16 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 18:16 BGN90340.1 1
Nitrate 1.5 mg/L EPA 9056A 07/12/2016 18:16B2 BGN90340.1 1
Nitrate as N 0.33 mg-N/L EPA 9056A 07/12/2016 18:16 BGN90340.023 1
Sulfate 4.5 mg/L EPA 9056A 07/12/2016 18:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:44 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.05 1
Calcium (Ca)2.49 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Iron (Fe)2.67 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.01 1
Magnesium (Mg)2.45 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Manganese (Mn)0.086 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Nickel (Ni)0.009 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
Potassium (K)2.71 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.1 1
Sodium (Na)4.41 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.05 1
Zinc (Zn)0.016 mg/L SW 6010D 07/15/2016 11:38 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:20 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:20 CWSPEN311
Lead (Pb)1.05 ug/L SW 6020B 07/13/2016 18:20 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:20 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:20 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 9 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019900
Collection Date:12-Jul-16 8:50 AM
Site:CRW-8R
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 9056A 07/12/2016 18:32 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 18:32 BGN90340.1 1
Nitrate 7.8 mg/L EPA 9056A 07/12/2016 18:32B2 BGN90340.1 1
Nitrate as N 1.8 mg-N/L EPA 9056A 07/12/2016 18:32 BGN90340.023 1
Sulfate 1.3 mg/L EPA 9056A 07/12/2016 18:32 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:47 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.062 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.05 1
Calcium (Ca)5.92 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Iron (Fe)1.09 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.01 1
Magnesium (Mg)2.19 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Manganese (Mn)0.015 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
Potassium (K)2.50 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.1 1
Sodium (Na)4.48 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.05 1
Zinc (Zn)0.077 mg/L SW 6010D 07/15/2016 12:00 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:27 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:27 CWSPEN311
Lead (Pb)1.17 ug/L SW 6020B 07/13/2016 18:27 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:27 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:27 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 80 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 10 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019901
Collection Date:12-Jul-16 9:45 AM
Site:CRW-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)16 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 9056A 07/12/2016 18:48 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 18:48 BGN90340.1 1
Nitrate 2.6 mg/L EPA 9056A 07/12/2016 18:48B2 BGN90340.1 1
Nitrate as N 0.58 mg-N/L EPA 9056A 07/12/2016 18:48 BGN90340.023 1
Sulfate 1.6 mg/L EPA 9056A 07/12/2016 18:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:49 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.05 1
Calcium (Ca)3.95 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.01 1
Chromium (Cr)0.006 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Iron (Fe)1.01 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.01 1
Magnesium (Mg)1.16 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Manganese (Mn)0.014 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
Potassium (K)2.30 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.1 1
Sodium (Na)3.63 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 12:04 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:33 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:33 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 18:33 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:33 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:33 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 51 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 11 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019902
Collection Date:12-Jul-16 10:25 AM
Site:CRW-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)8.0 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 24 mg/L EPA 9056A 07/12/2016 20:07 BGN9034110
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 20:07 BGN90340.1 1
Nitrate 2.2 mg/L EPA 9056A 07/12/2016 20:07B2 BGN90340.1 1
Nitrate as N 0.49 mg-N/L EPA 9056A 07/12/2016 20:07 BGN90340.023 1
Sulfate 45 mg/L EPA 9056A 07/12/2016 20:07 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:52 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.016 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.05 1
Calcium (Ca)17.6 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Iron (Fe)0.248 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.01 1
Magnesium (Mg)6.23 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Manganese (Mn)0.026 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
Potassium (K)3.25 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.1 1
Sodium (Na)6.97 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.05 1
Zinc (Zn)0.007 mg/L SW 6010D 07/15/2016 12:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:40 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:40 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 18:40 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:40 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:40 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 12 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019903
Collection Date:12-Jul-16 9:30 AM
Site:CRW-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)40 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.2 mg/L EPA 9056A 07/13/2016 08:50 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/13/2016 08:50 BGN90340.1 1
Nitrate 14 mg/L EPA 9056A 07/13/2016 08:50B2 BGN90340.5 5
Nitrate as N 3.1 mg-N/L EPA 9056A 07/13/2016 08:50 BGN90340.023 1
Sulfate 0.64 mg/L EPA 9056A 07/13/2016 08:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:04 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.05 1
Calcium (Ca)10.6 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Iron (Fe)0.685 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.01 1
Magnesium (Mg)5.21 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Manganese (Mn)0.011 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
Potassium (K)1.52 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.1 1
Sodium (Na)5.08 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 12:12 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:46 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:46 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 18:46 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:46 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:46 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 13 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019904
Collection Date:11-Jul-16 8:35 AM
Site:CRW-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 9056A 07/12/2016 11:54 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 11:54 BGN90340.1 1
Nitrate 3.8 mg/L EPA 9056A 07/12/2016 11:54B2 BGN90340.1 1
Nitrate as N 0.85 mg-N/L EPA 9056A 07/12/2016 11:54 BGN90340.023 1
Sulfate 1.1 mg/L EPA 9056A 07/12/2016 11:54 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 13:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.375 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Boron (B)0.109 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.05 1
Calcium (Ca)10.1 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.01 1
Chromium (Cr)0.060 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Copper (Cu)0.024 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Iron (Fe)47.0 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.01 1
Magnesium (Mg)11.7 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Manganese (Mn)1.02 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Nickel (Ni)0.030 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
Potassium (K)11.0 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.1 1
Sodium (Na)7.61 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.05 1
Zinc (Zn)0.653 mg/L SW 6010D 07/15/2016 12:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.60 ug/L SW 6020B 07/13/2016 18:53 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:53 CWSPEN311
Lead (Pb)33.9 ug/L SW 6020B 07/13/2016 18:53 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:53 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:53 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 57 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 14 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019905
Collection Date:11-Jul-16 9:35 AM
Site:CRW-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)37 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 9056A 07/12/2016 13:45 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 13:45 BGN90340.1 1
Nitrate 5.1 mg/L EPA 9056A 07/12/2016 13:45B2 BGN90340.1 1
Nitrate as N 1.1 mg-N/L EPA 9056A 07/12/2016 13:45 BGN90340.023 1
Sulfate 0.87 mg/L EPA 9056A 07/12/2016 13:45 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:14 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.061 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Boron (B)0.085 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.05 1
Calcium (Ca)11.0 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.01 1
Chromium (Cr)0.018 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Copper (Cu)0.010 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Iron (Fe)8.71 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.01 1
Magnesium (Mg)7.78 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Manganese (Mn)0.165 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Nickel (Ni)0.005 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
Potassium (K)3.67 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.1 1
Sodium (Na)5.42 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.05 1
Zinc (Zn)0.018 mg/L SW 6010D 07/15/2016 12:19 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 18:59 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 18:59 CWSPEN311
Lead (Pb)2.13 ug/L SW 6020B 07/13/2016 18:59 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 18:59 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 18:59 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 15 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019906
Collection Date:11-Jul-16 10:15 AM
Site:CRW-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)46 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 9056A 07/12/2016 14:01 BGN90340.5 5
Fluoride 0.24 mg/L EPA 9056A 07/12/2016 14:01 BGN90340.1 1
Nitrate 11 mg/L EPA 9056A 07/12/2016 14:01B2 BGN90340.5 5
Nitrate as N 2.5 mg-N/L EPA 9056A 07/12/2016 14:01 BGN90340.023 1
Sulfate 23 mg/L EPA 9056A 07/12/2016 14:01 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:11 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.033 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Boron (B)0.101 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.05 1
Calcium (Ca)17.0 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Iron (Fe)0.370 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.01 1
Magnesium (Mg)5.55 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Manganese (Mn)0.030 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
Potassium (K)3.09 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.1 1
Sodium (Na)20.4 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.05 1
Zinc (Zn)0.031 mg/L SW 6010D 07/15/2016 13:16 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 19:06 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 19:06 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 19:06 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 19:06 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:06 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 16 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019907
Collection Date:11-Jul-16 10:55 AM
Site:CRW-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 9056A 07/13/2016 09:06 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 07/13/2016 09:06 BGN90340.1 1
Nitrate 0.34 mg/L EPA 9056A 07/13/2016 09:06B2 BGN90340.1 1
Nitrate as N 0.08 mg-N/L EPA 9056A 07/13/2016 09:06 BGN90340.023 1
Sulfate 2.5 mg/L EPA 9056A 07/13/2016 09:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 15:39 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.009 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Boron (B)0.091 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.05 1
Calcium (Ca)5.77 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Iron (Fe)0.130 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.01 1
Magnesium (Mg)2.80 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Manganese (Mn)0.006 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
Potassium (K)2.45 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.1 1
Sodium (Na)5.67 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 12:23 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 20:43 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 20:43 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 20:43 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 20:43 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 20:43 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 63 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 17 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019908
Collection Date:11-Jul-16 8:30 AM
Site:CRW-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 5.2 mg/L EPA 9056A 07/12/2016 12:58 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 12:58 BGN90340.1 1
Nitrate 0.32 mg/L EPA 9056A 07/12/2016 12:58B2 BGN90340.1 1
Nitrate as N 0.07 mg-N/L EPA 9056A 07/12/2016 12:58 BGN90340.023 1
Sulfate 1.0 mg/L EPA 9056A 07/12/2016 12:58 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 15:46 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.05 1
Calcium (Ca)4.51 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Iron (Fe)0.343 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.01 1
Magnesium (Mg)1.29 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Manganese (Mn)0.011 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
Potassium (K)1.80 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.1 1
Sodium (Na)5.66 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 12:27 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 19:12 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 19:12 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 19:12 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 19:12 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:12 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 65 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 18 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019909
Collection Date:12-Jul-16 7:40 AM
Site:CRW-17
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)9.9 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 9056A 07/12/2016 21:27 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 21:27 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 07/12/2016 21:27B2 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 07/12/2016 21:27 BGN90340.023 1
Sulfate 0.17 mg/L EPA 9056A 07/12/2016 21:27 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.072 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.05 1
Calcium (Ca)4.45 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Copper (Cu)0.007 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Iron (Fe)2.31 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.01 1
Magnesium (Mg)0.970 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Manganese (Mn)0.029 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
Potassium (K)2.43 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.1 1
Sodium (Na)3.18 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.05 1
Zinc (Zn)0.343 mg/L SW 6010D 07/15/2016 12:31 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 19:38 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 19:38 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 19:38 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 19:38 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:38 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 66 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 19 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019910
Collection Date:11-Jul-16 12:35 PM
Site:CWB-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 560 mg/L EPA 9056A 07/12/2016 14:17 BGN903450500
Fluoride < 5 mg/L EPA 9056A 07/12/2016 14:17 BGN9034550
Nitrate 130 mg/L EPA 9056A 07/12/2016 14:17B2 BGN9034550
Nitrate as N 30 mg-N/L EPA 9056A 07/12/2016 14:17 BGN90340.023 1
Sulfate 2100 mg/L EPA 9056A 07/12/2016 14:17 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.06 ug/L EPA 7470A 07/18/2016 14:18 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.039 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.005 1
Boron (B)39.0 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.5 10
Calcium (Ca)547 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.005 1
Iron (Fe)0.285 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.01 1
Magnesium (Mg)167 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.05 10
Manganese (Mn)23.4 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.05 10
Nickel (Ni)0.124 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.005 1
Potassium (K)95.6 mg/L SW 6010D 07/15/2016 12:34 JJMACKE110
Sodium (Na)227 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.5 10
Zinc (Zn)0.275 mg/L SW 6010D 07/15/2016 12:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)26.4 ug/L SW 6020B 07/13/2016 19:45 CWSPEN311
Cadmium (Cd)4.66 ug/L SW 6020B 07/13/2016 19:45 CWSPEN311
Lead (Pb)7.80 ug/L SW 6020B 07/13/2016 19:45 CWSPEN311
Selenium (Se)112 ug/L SW 6020B 07/13/2016 19:45 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:45 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3900 mg/L SM2540C 07/14/2016 14:37 PARMSTR501
Duke Energy Analytical Lab Revision 1
Page 20 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019911
Collection Date:11-Jul-16 12:05 PM
Site:CWB-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 370 mg/L EPA 9056A 07/12/2016 14:33 BGN9034550
Fluoride < 5 mg/L EPA 9056A 07/12/2016 14:33 BGN9034550
Nitrate 180 mg/L EPA 9056A 07/12/2016 14:33B2 BGN9034550
Nitrate as N 40 mg-N/L EPA 9056A 07/12/2016 14:33 BGN90340.023 1
Sulfate 4000 mg/L EPA 9056A 07/12/2016 14:33 BGN90341001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.030 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
Boron (B)79.1 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.5 10
Calcium (Ca)446 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
Iron (Fe)0.151 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.01 1
Magnesium (Mg)376 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.5 100
Manganese (Mn)22.2 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
Nickel (Ni)0.273 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
Potassium (K)203 mg/L SW 6010D 07/15/2016 12:57 JJMACKE110
Sodium (Na)365 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.5 10
Zinc (Zn)0.710 mg/L SW 6010D 07/15/2016 12:57 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)39.6 ug/L SW 6020B 07/13/2016 19:51 CWSPEN311
Cadmium (Cd)8.16 ug/L SW 6020B 07/13/2016 19:51 CWSPEN311
Lead (Pb)12.6 ug/L SW 6020B 07/13/2016 19:51 CWSPEN311
Selenium (Se)205 ug/L SW 6020B 07/13/2016 19:51 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:51 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 5500 mg/L SM2540C 07/14/2016 14:37 PARMSTR2501
Duke Energy Analytical Lab Revision 1
Page 21 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019913
Collection Date:12-Jul-16 10:45 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)35 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 7.0 mg/L EPA 9056A 07/12/2016 23:02 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 23:02 BGN90340.1 1
Nitrate 0.79 mg/L EPA 9056A 07/12/2016 23:02B2 BGN90340.1 1
Nitrate as N 0.18 mg-N/L EPA 9056A 07/12/2016 23:02 BGN90340.023 1
Sulfate 4.6 mg/L EPA 9056A 07/12/2016 23:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:23 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.032 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Boron (B)0.057 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.05 1
Calcium (Ca)9.24 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Iron (Fe)2.00 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.01 1
Magnesium (Mg)4.30 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Manganese (Mn)0.121 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
Potassium (K)2.07 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.1 1
Sodium (Na)5.51 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 13:00 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 19:57 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 19:57 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 19:57 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 19:57 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 19:57 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 93 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 22 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019914
Collection Date:12-Jul-16 10:10 AM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)29 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 9056A 07/12/2016 23:18 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 23:18 BGN90340.1 1
Nitrate 0.31 mg/L EPA 9056A 07/12/2016 23:18B2 BGN90340.1 1
Nitrate as N 0.07 mg-N/L EPA 9056A 07/12/2016 23:18 BGN90340.023 1
Sulfate 13 mg/L EPA 9056A 07/12/2016 23:18 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.05 1
Calcium (Ca)9.84 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Iron (Fe)1.49 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.01 1
Magnesium (Mg)3.76 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Manganese (Mn)0.111 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
Potassium (K)2.31 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.1 1
Sodium (Na)5.67 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 13:04 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 20:04 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 20:04 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 20:04 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 20:04 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 20:04 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 96 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 23 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019915
Collection Date:11-Jul-16 10:30 AM
Site:CRS-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)100 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 8.3 mg/L EPA 9056A 07/12/2016 17:28 BGN90340.1 1
Fluoride 0.11 mg/L EPA 9056A 07/12/2016 17:28 BGN90340.1 1
Nitrate 0.27 mg/L EPA 9056A 07/12/2016 17:28B2 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 9056A 07/12/2016 17:28 BGN90340.023 1
Sulfate 38 mg/L EPA 9056A 07/12/2016 17:28 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:28 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.05 1
Calcium (Ca)33.2 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Iron (Fe)1.03 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.01 1
Magnesium (Mg)9.35 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Manganese (Mn)1.70 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
Potassium (K)6.01 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.1 1
Sodium (Na)7.72 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 13:27 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 21:28 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 21:28 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 21:28 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 21:28 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 21:28 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 24 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019916
Collection Date:11-Jul-16 10:55 AM
Site:CRS-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)22 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 5.4 mg/L EPA 9056A 07/12/2016 17:12 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 17:12 BGN90340.1 1
Nitrate 1.9 mg/L EPA 9056A 07/12/2016 17:12B2 BGN90340.1 1
Nitrate as N 0.44 mg-N/L EPA 9056A 07/12/2016 17:12 BGN90340.023 1
Sulfate 17 mg/L EPA 9056A 07/12/2016 17:12 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 14:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.014 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.05 1
Calcium (Ca)8.43 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Iron (Fe)0.910 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.01 1
Magnesium (Mg)3.05 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Manganese (Mn)0.136 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
Potassium (K)2.34 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.1 1
Sodium (Na)5.58 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 13:31 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 21:35 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 21:35 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 21:35 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 21:35 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 21:35 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 25 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019917
Collection Date:12-Jul-16 7:10 AM
Site:CRS-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B 07/14/2016 13:52 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.8 mg/L EPA 9056A 07/12/2016 23:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 23:34 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 07/12/2016 23:34B2 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 07/12/2016 23:34 BGN90340.023 1
Sulfate 7.9 mg/L EPA 9056A 07/12/2016 23:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 15:51 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.05 1
Calcium (Ca)2.92 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Iron (Fe)16.1 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.01 1
Magnesium (Mg)2.01 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Manganese (Mn)0.274 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
Potassium (K)1.91 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.1 1
Sodium (Na)2.86 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.05 1
Zinc (Zn)0.010 mg/L SW 6010D 07/15/2016 13:57 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.29 ug/L SW 6020B 07/13/2016 21:41 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 21:41 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 21:41 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 21:41 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 21:41 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 59 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 26 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019918
Collection Date:11-Jul-16 11:30 AM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)29 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride 6.5 mg/L EPA 9056A 07/12/2016 16:56 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 16:56 BGN90340.1 1
Nitrate 0.94 mg/L EPA 9056A 07/12/2016 16:56B2 BGN90340.1 1
Nitrate as N 0.21 mg-N/L EPA 9056A 07/12/2016 16:56 BGN90340.023 1
Sulfate 5.5 mg/L EPA 9056A 07/12/2016 16:56 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 15:54 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.025 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Boron (B)0.094 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.05 1
Calcium (Ca)7.43 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Iron (Fe)0.245 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.01 1
Magnesium (Mg)3.65 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Manganese (Mn)0.187 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
Potassium (K)1.78 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.1 1
Sodium (Na)5.47 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 14:01 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 21:48 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 21:48 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 21:48 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 21:48 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 21:48 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab Revision 1
Page 27 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
2016019919
Collection Date:12-Jul-16 11:05 AM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 07/14/2016 10:22 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 07/12/2016 21:11 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 07/12/2016 21:11 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 07/12/2016 21:11B2 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 07/12/2016 21:11 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 07/12/2016 21:11 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 07/18/2016 15:56 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.05 1
Calcium (Ca)0.013 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/15/2016 14:05 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/13/2016 21:54 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/13/2016 21:54 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/13/2016 21:54 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 07/13/2016 21:54 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/13/2016 21:54 CWSPEN311
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab Revision 1
Page 28 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070322 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070035 -- 2016019915
Alkalinity (mg/L CaCO3)8.04mg/L (CaCO3)-194.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 98.8 95.5mg/L (CaCO3)-12080194.4
Duke Energy Analytical Lab Revision 1
Page 29 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070342 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070035 -- 2016019894
Alkalinity (mg/L CaCO3)2.16mg/L (CaCO3)-114.9
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 9.88 93.7mg/L (CaCO3)-1208019.26
Duke Energy Analytical Lab Revision 1
Page 30 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070217 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0165 mg/L -10.0165 0.1 < 1/2 RDL
Fluoride 0.0407 mg/L -10.0407 0.1 < 1/2 RDL
Nitrate 0.0578 mg/L -10.0578 0.1 > 1/2 RDL
Sulfate 0.022 mg/L -10.022 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.44 5 92mg/L -1208015.44
Fluoride 4.86 5 96.2mg/L -1208014.86
Nitrate 4.78 5 93mg/L -1208014.78
Sulfate 4.87 5 94.3mg/L -1208014.87
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.44 5 92 0.0217mg/L -1208015.44
Fluoride 4.86 5 96.3 0.0624mg/L -1208014.86
Nitrate 4.79 5 93.3 0.343mg/L -1208014.79
Sulfate 4.88 5 94.6 0.339mg/L -1208014.88
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5.91 5 100mg/L -1208015.91
Fluoride 4.96 5 98.3mg/L -1208014.96
Nitrate 4.93 5 97.4mg/L -1208014.93
Sulfate 8.65 5 96.5mg/L -1208018.65
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5.44 5 99.7 0.66mg/L -1208015.88
Fluoride 4.86 5 98.5 0.183mg/L -1208014.97
Nitrate 4.79 5 98.7 1.45mg/L -1208015
Sulfate 4.88 5 96.8 0.352mg/L -1208018.66
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Chloride 5 82.9mg/L -1208016.3
Fluoride 5 99.3mg/L -1208015
Nitrate 5 98.7mg/L -1208015.01
Sulfate 5 99.9mg/L -1208015.17
Duke Energy Analytical Lab Revision 1
Page 31 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070217 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Chloride 6.63 5 89.5 7.68mg/L -1208016.63
Fluoride 4.99 5 99.1 0.181mg/L -1208014.99
Nitrate 5 5 98.5 0.223mg/L -1208015
Sulfate 5.16 5 99.8 0.14mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.84 5 96.8mg/L -1208014.84
Fluoride 4.85 5 97.1mg/L -1208014.85
Nitrate 4.84 5 96.9mg/L -1208014.84
Sulfate 4.82 5 96.4mg/L -1208014.82
Duke Energy Analytical Lab Revision 1
Page 32 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070438 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.02 ug/L -10.02 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.02 ug/L -10.02 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019896
Mercury (Hg) 1.01 1 99.5ug/L -1257511.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019896
Mercury (Hg) 0.996 1 98.1 1.42ug/L -1257510.996
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019903
Mercury (Hg) 1.01 1 99.6ug/L -1257511.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019903
Mercury (Hg) 0.996 1 98 1.62ug/L -1257510.996
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019907
Mercury (Hg) 1.04 1 103ug/L -1257511.04
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019907
Mercury (Hg) 1.01 1 100 2.47ug/L -1257511.01
Duke Energy Analytical Lab Revision 1
Page 33 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070255 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000067 mg/L -1-0.000067 0.005 < 1/2 RDL
Boron (B) -0.00166 mg/L -1-0.00166 0.05 < 1/2 RDL
Calcium (Ca) 0.00484 mg/L -10.00484 0.01 < 1/2 RDL
Chromium (Cr) 0.000134 mg/L -10.000134 0.005 < 1/2 RDL
Copper (Cu) -0.000555 mg/L -1-0.000555 0.005 < 1/2 RDL
Iron (Fe) -0.000785 mg/L -1-0.000785 0.01 < 1/2 RDL
Magnesium (Mg) 0.000447 mg/L -10.000447 0.005 < 1/2 RDL
Manganese (Mn) -0.000269 mg/L -1-0.000269 0.005 < 1/2 RDL
Nickel (Ni) 0.000231 mg/L -10.000231 0.005 < 1/2 RDL
Potassium (K) -0.0114 mg/L -1-0.0114 0.1 < 1/2 RDL
Sodium (Na) -0.0115 mg/L -1-0.0115 0.05 < 1/2 RDL
Zinc (Zn) 0.00061 mg/L -10.00061 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Barium (Ba) -0.000026 mg/L -1-0.000026 0.005 < 1/2 RDL
Boron (B) 0.0097 mg/L -10.0097 0.05 < 1/2 RDL
Calcium (Ca) 0.00349 mg/L -10.00349 0.01 < 1/2 RDL
Chromium (Cr) -0.00072 mg/L -1-0.00072 0.005 < 1/2 RDL
Copper (Cu) -0.000193 mg/L -1-0.000193 0.005 < 1/2 RDL
Iron (Fe) -0.000096 mg/L -1-0.000096 0.01 < 1/2 RDL
Magnesium (Mg) 0.00185 mg/L -10.00185 0.005 < 1/2 RDL
Manganese (Mn) 0.000101 mg/L -10.000101 0.005 < 1/2 RDL
Nickel (Ni) -0.000313 mg/L -1-0.000313 0.005 < 1/2 RDL
Potassium (K) -0.00965 mg/L -1-0.00965 0.1 < 1/2 RDL
Sodium (Na) -0.00693 mg/L -1-0.00693 0.05 < 1/2 RDL
Zinc (Zn) 0.00141 mg/L -10.00141 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.91 5 98.2mg/L -1208014.91
Boron (B) 4.92 5 98.5mg/L -1208014.92
Calcium (Ca) 4.74 5 94.9mg/L -1208014.74
Chromium (Cr) 4.75 5 95mg/L -1208014.75
Copper (Cu) 4.84 5 96.7mg/L -1208014.84
Iron (Fe) 4.83 5 96.6mg/L -1208014.83
Magnesium (Mg) 4.91 5 98.1mg/L -1208014.91
Manganese (Mn) 5.03 5 101mg/L -1208015.03
Nickel (Ni) 4.84 5 96.9mg/L -1208014.84
Potassium (K) 4.86 5 97.2mg/L -1208014.86
Duke Energy Analytical Lab Revision 1
Page 34 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070255 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Sodium (Na) 4.91 5 98.2mg/L -1208014.91
Zinc (Zn) 4.88 5 97.7mg/L -1208014.88
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Barium (Ba) 5.02 5 100mg/L -1208015.02
Boron (B) 5.08 5 102mg/L -1208015.08
Calcium (Ca) 4.85 5 97.1mg/L -1208014.85
Chromium (Cr) 4.87 5 97.3mg/L -1208014.87
Copper (Cu) 4.9 5 98.1mg/L -1208014.9
Iron (Fe) 4.92 5 98.5mg/L -1208014.92
Magnesium (Mg) 5.05 5 101mg/L -1208015.05
Manganese (Mn) 5.15 5 103mg/L -1208015.15
Nickel (Ni) 4.98 5 99.5mg/L -1208014.98
Potassium (K) 4.98 5 99.6mg/L -1208014.98
Sodium (Na) 5.01 5 100mg/L -1208015.01
Zinc (Zn) 5.04 5 101mg/L -1208015.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019896
Barium (Ba) 5.04 5 101mg/L -1257515.04
Boron (B) 5.06 5 101mg/L -1257515.06
Calcium (Ca) 10.1 5 101mg/L -12575110.1
Chromium (Cr) 4.83 5 96.6mg/L -1257514.83
Copper (Cu) 4.91 5 98.1mg/L -1257514.91
Iron (Fe) 5.07 5 98.1mg/L -1257515.07
Magnesium (Mg) 6.47 5 101mg/L -1257516.47
Manganese (Mn) 5.11 5 102mg/L -1257515.11
Nickel (Ni) 4.94 5 98.8mg/L -1257514.94
Potassium (K) 6.59 5 99.6mg/L -1257516.59
Sodium (Na) 10.2 5 101mg/L -12575110.2
Zinc (Zn) 5.01 5 99mg/L -1257515.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019896
Barium (Ba) 5.05 5 101 0.318mg/L -1257515.05
Boron (B) 5.08 5 101 0.377mg/L -1257515.08
Calcium (Ca) 10.1 5 101 0.416mg/L -12575110.1
Chromium (Cr) 4.87 5 97.3 0.742mg/L -1257514.87
Copper (Cu) 4.92 5 98.4 0.305mg/L -1257514.92
Duke Energy Analytical Lab Revision 1
Page 35 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070255 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019896
Iron (Fe) 5.1 5 98.7 0.691mg/L -1257515.1
Magnesium (Mg) 6.49 5 102 0.512mg/L -1257516.49
Manganese (Mn) 5.15 5 103 0.721mg/L -1257515.15
Nickel (Ni) 4.96 5 99.2 0.364mg/L -1257514.96
Potassium (K) 6.58 5 99.4 0.161mg/L -1257516.58
Sodium (Na) 10.2 5 100 0.119mg/L -12575110.2
Zinc (Zn) 5.04 5 99.6 0.584mg/L -1257515.04
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019906
Barium (Ba) 5.07 5 101mg/L -1257515.07
Boron (B) 5.15 5 101mg/L -1257515.15
Calcium (Ca) 21.8 5 96.8mg/L -12575121.8
Chromium (Cr) 4.83 5 96.6mg/L -1257514.83
Copper (Cu) 4.87 5 97.2mg/L -1257514.87
Iron (Fe) 5.25 5 97.6mg/L -1257515.25
Magnesium (Mg) 10.5 5 98.5mg/L -12575110.5
Manganese (Mn) 5.12 5 102mg/L -1257515.12
Nickel (Ni) 4.89 5 97.7mg/L -1257514.89
Potassium (K) 8.05 5 99.3mg/L -1257518.05
Sodium (Na) 25.4 5 101mg/L -12575125.4
Zinc (Zn) 4.97 5 98.8mg/L -1257514.97
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019906
Barium (Ba) 5.03 5 100 0.678mg/L -1257515.03
Boron (B) 5.12 5 100 0.615mg/L -1257515.12
Calcium (Ca) 22 5 100 3.33mg/L -12575122
Chromium (Cr) 4.82 5 96.4 0.207mg/L -1257514.82
Copper (Cu) 4.87 5 97.4 0.144mg/L -1257514.87
Iron (Fe) 5.28 5 98.1 0.572mg/L -1257515.28
Magnesium (Mg) 10.5 5 98.3 0.142mg/L -12575110.5
Manganese (Mn) 5.12 5 102 0.059mg/L -1257515.12
Nickel (Ni) 4.89 5 97.7 0.0614mg/L -1257514.89
Potassium (K) 8.02 5 98.7 0.586mg/L -1257518.02
Sodium (Na) 25.4 5 101 0.317mg/L -12575125.4
Zinc (Zn) 4.97 5 98.8 0.0405mg/L -1257514.97
Duke Energy Analytical Lab Revision 1
Page 36 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070258 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0217 ug/L -10.0217 1 < 1/2 RDL
Cadmium (Cd) 0.0006 ug/L -10.0006 1 < 1/2 RDL
Lead (Pb) 0.0019 ug/L -10.0019 1 < 1/2 RDL
Selenium (Se) -0.0104 ug/L -1-0.0104 1 < 1/2 RDL
Silver (Ag) 0.0003 ug/L -10.0003 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Arsenic (As) 0.0149 ug/L -10.0149 1 < 1/2 RDL
Cadmium (Cd) -0.0006 ug/L -1-0.0006 1 < 1/2 RDL
Lead (Pb) 0.0011 ug/L -10.0011 1 < 1/2 RDL
Selenium (Se) -0.0079 ug/L -1-0.0079 1 < 1/2 RDL
Silver (Ag) -0.0006 ug/L -1-0.0006 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 50.9 50 102ug/L -12080150.9
Cadmium (Cd) 51.7 50 103ug/L -12080151.7
Lead (Pb) 51.7 50 103ug/L -12080151.7
Selenium (Se) 50.8 50 102ug/L -12080150.8
Silver (Ag) 51 50 102ug/L -12080151
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Arsenic (As) 51.6 50 103ug/L -12080151.6
Cadmium (Cd) 51.7 50 103ug/L -12080151.7
Lead (Pb) 51.6 50 103ug/L -12080151.6
Selenium (Se) 49.8 50 99.7ug/L -12080149.8
Silver (Ag) 51.5 50 103ug/L -12080151.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019897
Arsenic (As) 48.7 50 97.2ug/L -12575148.7
Cadmium (Cd) 49.8 50 99.6ug/L -12575149.8
Lead (Pb) 49.7 50 99.3ug/L -12575149.7
Selenium (Se) 49.6 50 99.1ug/L -12575149.6
Silver (Ag) 49.1 50 98.2ug/L -12575149.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019897
Arsenic (As) 50.1 50 100 2.93ug/L -12575150.1
Duke Energy Analytical Lab Revision 1
Page 37 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070258 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019897
Cadmium (Cd) 51.2 50 102 2.66ug/L -12575151.2
Lead (Pb) 50.5 50 101 1.61ug/L -12575150.5
Selenium (Se) 49.6 50 99.3 0.146ug/L -12575149.6
Silver (Ag) 50 50 100 1.81ug/L -12575150
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019907
Arsenic (As) 50.4 50 101ug/L -12575150.4
Cadmium (Cd) 51.2 50 102ug/L -12575151.2
Lead (Pb) 50.7 50 101ug/L -12575150.7
Selenium (Se) 48.6 50 97ug/L -12575148.6
Silver (Ag) 50.9 50 101ug/L -12575150.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070035 -- 2016019907
Arsenic (As) 49.6 50 99.1 1.59ug/L -12575149.6
Cadmium (Cd) 50.8 50 102 0.654ug/L -12575150.8
Lead (Pb) 50.2 50 100 0.924ug/L -12575150.2
Selenium (Se) 48.4 50 96.6 0.356ug/L -12575148.4
Silver (Ag) 50.2 50 99.7 1.37ug/L -12575150.2
Duke Energy Analytical Lab Revision 1
Page 38 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070302 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070328 -- 2016021493
TDS 2.03mg/L -1293
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070328 -- 2016021494
TDS 0mg/L -1377
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16070367 -- 2016021648
TDS 0.533mg/L -1188
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Duke Energy Analytical Lab Revision 1
Page 39 of 44
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070035
Q16070415 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070325 -- 2016021447
TDS 4.38mg/L -170
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070325 -- 2016021448
TDS 4.94mg/L -179
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Duke Energy Analytical Lab Revision 1
Page 40 of 44
Duke Energy Analytical Lab
Revision 1
Page 41 of 44
Duke Energy Analytical Lab
Revision 1
Page 42 of 44
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13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070039
Project Name:BELEWS - GW CRAIG ROAD LF
Lab Contact: Anne Pridgeon
Date:8/5/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 13
Reason: I have reviewed
this document.
Date: 2016.08.05
11:40:33 -04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016019936 BELEWS 12-Jul-16 11:00 AM LDC CRS-1
2016019937 BELEWS 12-Jul-16 10:10 AM PSP CRS-2
2016019938 BELEWS 11-Jul-16 10:30 AM PSP CRS-3
2016019939 BELEWS 11-Jul-16 11:40 AM LDC CRS-6
4 Total Samples
Duke Energy Analytical Lab
Page 2 of 13
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:7/29/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
2016019936
Collection Date:12-Jul-16 11:00 AM
Site:CRS-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
Iron (Fe)0.182 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.01 1
Manganese (Mn)0.096 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/26/2016 12:20 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/20/2016 15:53 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/20/2016 15:53 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/20/2016 15:53 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/20/2016 15:53 CWSPEN311
Duke Energy Analytical Lab
Page 4 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
2016019937
Collection Date:12-Jul-16 10:10 AM
Site:CRS-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.022 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
Iron (Fe)0.692 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.01 1
Manganese (Mn)0.103 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/26/2016 12:33 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/20/2016 16:13 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/20/2016 16:13 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/20/2016 16:13 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/20/2016 16:13 CWSPEN311
Duke Energy Analytical Lab
Page 5 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
2016019938
Collection Date:11-Jul-16 10:30 AM
Site:CRS-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
Iron (Fe)0.555 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.01 1
Manganese (Mn)1.59 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/26/2016 12:37 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/20/2016 16:19 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/20/2016 16:19 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/20/2016 16:19 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/20/2016 16:19 CWSPEN311
Duke Energy Analytical Lab
Page 6 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
2016019939
Collection Date:11-Jul-16 11:40 AM
Site:CRS-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.023 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
Boron (B)< 0.05 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.05 1
Chromium (Cr)< 0.005 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
Iron (Fe)0.022 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.01 1
Manganese (Mn)0.156 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L SW 6010D 07/26/2016 12:41 JJMACKE0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 07/20/2016 16:45 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 07/20/2016 16:45 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 07/20/2016 16:45 CWSPEN311
Silver (Ag)< 1 ug/L SW 6020B 07/20/2016 16:45 CWSPEN311
Duke Energy Analytical Lab
Page 7 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
Q16070711 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000136 mg/L -10.000136 0.005 < 1/2 RDL
Boron (B) 0.00138 mg/L -10.00138 0.05 < 1/2 RDL
Chromium (Cr) -0.000611 mg/L -1-0.000611 0.005 < 1/2 RDL
Copper (Cu) -0.000028 mg/L -1-0.000028 0.005 < 1/2 RDL
Iron (Fe) -0.00061 mg/L -1-0.00061 0.01 < 1/2 RDL
Manganese (Mn) -0.00047 mg/L -1-0.00047 0.005 < 1/2 RDL
Nickel (Ni) 0.000048 mg/L -10.000048 0.005 < 1/2 RDL
Zinc (Zn) -0.000276 mg/L -1-0.000276 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 0.964 1 96.4mg/L -1158510.964
Boron (B) 1.96 2 97.8mg/L -1158511.96
Chromium (Cr) 1 1 100mg/L -1158511
Copper (Cu) 1.94 2 97.2mg/L -1158511.94
Iron (Fe) 2.02 2 101mg/L -1158512.02
Manganese (Mn) 0.962 1 96.2mg/L -1158510.962
Nickel (Ni) 1.96 2 98.1mg/L -1158511.96
Zinc (Zn) 1.01 1 101mg/L -1158511.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070039 -- 2016019936
Barium (Ba) 5.48 5 109mg/L -1307015.48
Boron (B) 5.12 5 102mg/L -1307015.12
Chromium (Cr) 5.33 5 107mg/L -1307015.33
Copper (Cu) 5.36 5 107mg/L -1307015.36
Iron (Fe) 5.5 5 106mg/L -1307015.5
Manganese (Mn) 5.69 5 112mg/L -1307015.69
Nickel (Ni) 5.37 5 107mg/L -1307015.37
Zinc (Zn) 5.5 5 110mg/L -1307015.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070039 -- 2016019936
Barium (Ba) 5.51 5 110 0.512mg/L -1307015.51
Boron (B) 5.18 5 103 1.31mg/L -1307015.18
Chromium (Cr) 5.38 5 108 0.99mg/L -1307015.38
Copper (Cu) 5.41 5 108 0.891mg/L -1307015.41
Iron (Fe) 5.56 5 108 1.08mg/L -1307015.56
Manganese (Mn) 5.75 5 113 1.05mg/L -1307015.75
Nickel (Ni) 5.42 5 108 0.946mg/L -1307015.42
Duke Energy Analytical Lab
Page 8 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
Q16070711 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070039 -- 2016019936
Zinc (Zn) 5.56 5 111 0.977mg/L -1307015.56
Duke Energy Analytical Lab
Page 9 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
Q16070476 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.0037 ug/L -1-0.0037 1 < 1/2 RDL
Cadmium (Cd) 0.0018 ug/L -10.0018 1 < 1/2 RDL
Lead (Pb) 0.0027 ug/L -10.0027 1 < 1/2 RDL
Silver (Ag) 0.0053 ug/L -10.0053 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Arsenic (As) -0.011 ug/L -1-0.011 1 < 1/2 RDL
Cadmium (Cd) 0.0047 ug/L -10.0047 1 < 1/2 RDL
Lead (Pb) 0.0152 ug/L -10.0152 1 < 1/2 RDL
Silver (Ag) 0.0006 ug/L -10.0006 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 80.3 80 100ug/L -12080180.3
Cadmium (Cd) 8.12 8 102ug/L -1208018.12
Lead (Pb) 81.9 80 102ug/L -12080181.9
Silver (Ag) 42.3 40 106ug/L -12080142.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Arsenic (As) 82.8 80 103ug/L -12080182.8
Cadmium (Cd) 8.32 8 104ug/L -1208018.32
Lead (Pb) 83.1 80 104ug/L -12080183.1
Silver (Ag) 41.5 40 104ug/L -12080141.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070039 -- 2016019936
Arsenic (As) 49.3 50 98.5ug/L -12575149.3
Cadmium (Cd) 50.8 50 102ug/L -12575150.8
Lead (Pb) 50.4 50 101ug/L -12575150.4
Silver (Ag) 48.1 50 96.3ug/L -12575148.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070039 -- 2016019936
Arsenic (As) 48.8 50 97.4 1.06ug/L -13070148.8
Cadmium (Cd) 50.3 50 101 0.911ug/L -13070150.3
Lead (Pb) 50.2 50 100 0.326ug/L -13070150.2
Silver (Ag) 48.2 50 96.4 0.07ug/L -13070148.2
Duke Energy Analytical Lab
Page 10 of 13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070039
Q16070476 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070412 -- 2016021928
Arsenic (As) 53.9 50 108ug/L -12575153.9
Cadmium (Cd) 51.6 50 103ug/L -12575151.6
Lead (Pb) 52.1 50 104ug/L -12575152.1
Silver (Ag) 0.0043 50 0.0086ug/L -1257510.0043
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070412 -- 2016021928
Arsenic (As) 54.1 50 108 0.269ug/L -13070154.1
Cadmium (Cd) 50.9 50 102 1.37ug/L -13070150.9
Lead (Pb) 51.5 50 103 1.04ug/L -13070151.5
Silver (Ag) 0.0031 50 0.0062 32.4ug/L -1307010.0031
Duke Energy Analytical Lab
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