1812_DukeMarshall_Aug2016_2ndSemiAnnualLeachate_DIN27237_20161026

526 South Church St.
Charlotte, NC 28202

P.O. Box 1006
Mail Code EC13K
Charlotte, NC 28201-1006
980-373-5697
704-382-6240 fax

Page 1 of 1

October 31, 2016

Ms. Elizabeth Werner
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646

Subject: Semi-annual Leachate Sampling Results
Duke Energy Carolinas, LLC
Marshall Steam Station
Industrial Landfill No. 1, Phase 1, Cells 1 and 2, Permit #1812

Dear Ms. Werner:

In accordance with the landfill Operations Plan, Duke Energy is providing the results of semi-annual
leachate sampling for the Marshall Steam Station Industrial Landfill No. 1, located in Terrell, North
Carolina.

On August 3, 2016 leachate samples were collected from the leachate collection system. The samples
were collected by Duke Energy personnel. A summary of sampling results can be found in Table 1. As
noted in the table, 15 NCAC 2L .0202 standards are provided for reference only. The parameters tested
are not bound by state groundwater or surface water standards. The leachate is conveyed to the station’s
ash impoundment, which discharges via a NPDES permitted outfall. All laboratory analytical and field
results are provided as Attachments 1 and 2, respectively.

Duke Energy personnel sample landfill leachate at Marshall Steam Station’s Industrial Landfill No. 1
semi-annually during August and February. The next landfill leachate sampling event will occur
February 2017 with documentation to follow.

If you have any questions or concerns, please contact me at 980-373-5697 or at Tyler.Hardin@duke-
energy.com

Sincerely,
Tyler Hardin, EIT
Environmental Services

Cc: Scott La Sala – Duke Energy
Dan Zakary – Duke Energy
Ed Sullivan - Duke Energy
Jeff Jones – Duke Energy
Kim Witt – Duke Energy
15A NCAC 2L 
.0202 Standard
Cell 1 Cell 2
Arsenic 10 58.6 62.3
Barium 700 46 45
Boron 700 52,600 46,700
Cadmium 2 3.89 4.84
Chloride 250 mg/L 27 mg/L 31 mg/L
Chromium 10 < 5< 5
Copper 1 mg/L <0.005 mg/L 0.005 mg/L
Fluoride 2 mg/L 3.5 mg/L 3 mg/L
Iron 300 272 241
Lead 15 3.28 5.17
Manganese 50 46,200 42,000
Mercury 1< 0.05 < 0.05
Nickel 100 138 139
Nitrate as N 10 mg/L 13 mg/L 11 mg/L
pH 6.5‐8.5 4.29 4.32
Selenium 20 113 147
Silver 20 < 5< 5
Sulfate 250 mg/L 3400 mg/L 3400 mg/L
Temperature (°C)n/a °C 17.21 17.61
TDS 500 mg/L 3300 mg/L 3200 mg/L
Zinc 1 mg/L 0.333 mg/L 0.321 mg/L
Table 1
Leachate Analytical Data
Industrial Landfill No. 1 (Permit No. 1812)
Marshall Steam Station
NOTE:  15A NCAC 2L .0202 Standards are provided only for reference.  
Analytical results are for landfill leachate, which is NOT bound by state 
groundwater or surface water standards.  Landfill leachate is conveyed to the 
station's ash impoundment, which discharges via a NPDES permitted outfall.
Constituent (ug/L)
Analytical Result (ug/L)
8/3/2016

Attachment 1
Marshall Industrial Landfill No. 1
Semi-Annual Monitoring Event
Leachate Analytical Results
August 3, 2016
13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070638
Project Name:MARSHALL - GW INDUSTRIAL LANDFILL 1
Lab Contact: Anne Pridgeon
Date:8/15/2016
Customer Address:8320 NC Hwy 150 East
Customer Name(s):Chuck Campbell, Tim Hunsucker, Sean De Neale
Mail Code: Marshall Steam Station
Terrell, NC 28682
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Page 1 of 14
Reason: I have reviewed
this document.
Date: 2016.08.18
10:58:01 -04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016023178 MARSHALL 03-Aug-16 12:30 PM LDC CELL 1 LEACHATE
2016023179 MARSHALL 03-Aug-16 12:10 PM LDC CELL 2 LEACHATE
2016023180 MARSHALL 03-Aug-16 12:55 PM LDC FIELD BLANK
3 Total Samples
Page 2 of 14
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:8/15/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
2016023178
Collection Date:03-Aug-16 12:30 PM
Site:CELL 1 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 08/08/2016 13:08 CJELLIO201
INORGANIC IONS BY IC
Chloride 27 mg/L EPA 9056A 08/04/2016 13:48 BGN90342.5 25
Fluoride 3.5 mg/L EPA 9056A 08/04/2016 13:48 BGN90342.5 25
Nitrate 59 mg/L EPA 9056A 08/04/2016 13:48 BGN90342.5 25
Nitrate as N 13 mg-N/L EPA 9056A 08/04/2016 13:48 BGN90340.023 1
Sulfate 3400 mg/L EPA 9056A 08/04/2016 13:48 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 08/08/2016 17:06 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.046 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
Boron (B)52.6 mg/L SW 6010D 08/10/2016 10:44 MHH71310.5 10
Calcium (Ca)347 mg/L SW 6010D 08/10/2016 10:44B2 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
Iron (Fe)0.272 mg/L SW 6010D 08/10/2016 10:44 MHH71310.01 1
Magnesium (Mg)103 mg/L SW 6010D 08/10/2016 10:44 MHH71310.05 10
Manganese (Mn)46.2 mg/L SW 6010D 08/10/2016 10:44 MHH71310.05 10
Nickel (Ni)0.138 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
Potassium (K)141 mg/L SW 6010D 08/10/2016 10:44 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
Sodium (Na)220 mg/L SW 6010D 08/10/2016 10:44 MHH71310.5 10
Zinc (Zn)0.333 mg/L SW 6010D 08/10/2016 10:44 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)58.6 ug/L SW 6020B 08/09/2016 18:45 CWSPEN311
Cadmium (Cd)3.89 ug/L SW 6020B 08/09/2016 18:45 CWSPEN311
Lead (Pb)3.28 ug/L SW 6020B 08/09/2016 18:45 CWSPEN311
Selenium (Se)113 ug/L SW 6020B 08/09/2016 18:45 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3300 mg/L SM2540C 08/09/2016 15:02 PARMSTR501
Page 4 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
2016023179
Collection Date:03-Aug-16 12:10 PM
Site:CELL 2 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 08/08/2016 13:08 CJELLIO201
INORGANIC IONS BY IC
Chloride 31 mg/L EPA 9056A 08/04/2016 14:05 BGN90342.5 25
Fluoride 3.0 mg/L EPA 9056A 08/04/2016 14:05 BGN90342.5 25
Nitrate 47 mg/L EPA 9056A 08/04/2016 14:05 BGN90342.5 25
Nitrate as N 11 mg-N/L EPA 9056A 08/04/2016 14:05 BGN90340.023 1
Sulfate 3400 mg/L EPA 9056A 08/04/2016 14:05 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 08/08/2016 17:08 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.045 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
Boron (B)46.7 mg/L SW 6010D 08/10/2016 10:48 MHH71310.5 10
Calcium (Ca)355 mg/L SW 6010D 08/10/2016 10:48B2 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
Iron (Fe)0.241 mg/L SW 6010D 08/10/2016 10:48 MHH71310.01 1
Magnesium (Mg)111 mg/L SW 6010D 08/10/2016 10:48 MHH71310.05 10
Manganese (Mn)42.0 mg/L SW 6010D 08/10/2016 10:48 MHH71310.05 10
Nickel (Ni)0.139 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
Potassium (K)101 mg/L SW 6010D 08/10/2016 10:48 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
Sodium (Na)198 mg/L SW 6010D 08/10/2016 10:48 MHH71310.5 10
Zinc (Zn)0.321 mg/L SW 6010D 08/10/2016 10:48 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)62.3 ug/L SW 6020B 08/09/2016 18:51 CWSPEN311
Cadmium (Cd)4.84 ug/L SW 6020B 08/09/2016 18:51 CWSPEN311
Lead (Pb)5.17 ug/L SW 6020B 08/09/2016 18:51 CWSPEN311
Selenium (Se)147 ug/L SW 6020B 08/09/2016 18:51 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3200 mg/L SM2540C 08/09/2016 15:02 PARMSTR501
Page 5 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
2016023180
Collection Date:03-Aug-16 12:55 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 08/08/2016 13:08 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 08/04/2016 14:22 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 08/04/2016 14:22 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 08/04/2016 14:22 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 08/04/2016 14:22 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 08/04/2016 14:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 08/08/2016 17:10 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 08/10/2016 10:35 MHH71310.05 1
Calcium (Ca)0.043 mg/L SW 6010D 08/10/2016 10:35B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 08/10/2016 10:35 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 08/10/2016 10:35 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 08/10/2016 10:35 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 08/10/2016 10:35 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 08/09/2016 18:58 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 08/09/2016 18:58 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 08/09/2016 18:58 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 08/09/2016 18:58 CWSPEN311
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Page 6 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080244 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16080182 -- 2016024734
Alkalinity (mg/L CaCO3)0.823mg/L (CaCO3)-143.9
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 98.8 97.2mg/L (CaCO3)-12080196.1
Page 7 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080122 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0339 mg/L -10.0339 0.1 < 1/2 RDL
Fluoride 0.0307 mg/L -10.0307 0.1 < 1/2 RDL
Nitrate 0.0178 mg/L -10.0178 0.1 < 1/2 RDL
Sulfate -0.0025 mg/L -1-0.0025 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Chloride 0.13 mg/L -10.13 0.1
Fluoride 0.032 mg/L -10.032 0.1
Nitrate 0.0331 mg/L -10.0331 0.1
Sulfate 3.98 mg/L -13.98 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.13 5 100mg/L -1208015.13
Fluoride 4.96 5 98.6mg/L -1208014.96
Nitrate 5.02 5 99.8mg/L -1208015.02
Sulfate 8.38 5 88mg/L -1208018.38
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.13 5 99.9 0.076mg/L -1208015.13
Fluoride 4.95 5 98.4 0.169mg/L -1208014.95
Nitrate 5.02 5 99.8 0.016mg/L -1208015.02
Sulfate 8.38 5 88 0.0205mg/L -1208018.38
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5 5 100mg/L -1208015
Fluoride 4.94 5 98.8mg/L -1208014.94
Nitrate 5.14 5 103mg/L -1208015.14
Sulfate 5.2 5 104mg/L -1208015.2
Page 8 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080251 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.013 ug/L -1-0.013 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.85 2 92.5ug/L -1158511.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023172
Mercury (Hg) 0.931 1 94.3ug/L -1257510.931
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023172
Mercury (Hg) 0.946 1 95.8 1.58ug/L -1257510.946
Page 9 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000011 mg/L -1-0.000011 0.005 < 1/2 RDL
Boron (B) -0.000669 mg/L -1-0.000669 0.05 < 1/2 RDL
Calcium (Ca) 0.00878 mg/L -10.00878 0.01 > 1/2 RDL
Chromium (Cr) 0.000188 mg/L -10.000188 0.005 < 1/2 RDL
Copper (Cu) 0.000218 mg/L -10.000218 0.005 < 1/2 RDL
Iron (Fe) 0.000495 mg/L -10.000495 0.01 < 1/2 RDL
Magnesium (Mg) -0.000349 mg/L -1-0.000349 0.005 < 1/2 RDL
Manganese (Mn) 0.000033 mg/L -10.000033 0.005 < 1/2 RDL
Nickel (Ni) 0.00033 mg/L -10.00033 0.005 < 1/2 RDL
Potassium (K) -0.00597 mg/L -1-0.00597 0.1 < 1/2 RDL
Silver (Ag) -0.000672 mg/L -1-0.000672 0.005 < 1/2 RDL
Sodium (Na) 0.00594 mg/L -10.00594 0.05 < 1/2 RDL
Zinc (Zn) 0.000763 mg/L -10.000763 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5 5 100mg/L -1208015
Boron (B) 4.91 5 98.3mg/L -1208014.91
Calcium (Ca) 5.05 5 101mg/L -1208015.05
Chromium (Cr) 4.9 5 98mg/L -1208014.9
Copper (Cu) 4.94 5 98.9mg/L -1208014.94
Iron (Fe) 5.08 5 102mg/L -1208015.08
Magnesium (Mg) 4.99 5 99.9mg/L -1208014.99
Manganese (Mn) 4.99 5 99.9mg/L -1208014.99
Nickel (Ni) 5.02 5 100mg/L -1208015.02
Potassium (K) 4.89 5 97.8mg/L -1208014.89
Silver (Ag) 0.469 0.5 93.9mg/L -1208010.469
Sodium (Na) 4.94 5 98.8mg/L -1208014.94
Zinc (Zn) 5.01 5 100mg/L -1208015.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023172
Barium (Ba) 5.12 5 98.3mg/L -1257515.12
Boron (B) 5.09 5 97mg/L -1257515.09
Calcium (Ca) 38.9 5 104mg/L -12575138.9
Chromium (Cr) 4.78 5 95.6mg/L -1257514.78
Copper (Cu) 4.83 5 96.7mg/L -1257514.83
Iron (Fe) 5.15 5 99.9mg/L -1257515.15
Magnesium (Mg) 13.6 5 100mg/L -12575113.6
Manganese (Mn) 4.88 5 97.1mg/L -1257514.88
Page 10 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080171 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023172
Nickel (Ni) 4.84 5 96.7mg/L -1257514.84
Potassium (K) 10 5 98.8mg/L -12575110
Silver (Ag) 0.46 0.5 92.3mg/L -1257510.46
Sodium (Na) 17.2 5 95.4mg/L -12575117.2
Zinc (Zn) 4.84 5 96.7mg/L -1257514.84
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023172
Barium (Ba) 5.22 5 100 2.03mg/L -1257515.22
Boron (B) 5.17 5 98.4 1.47mg/L -1257515.17
Calcium (Ca) 39.3 5 112 6.85mg/L -12575139.3
Chromium (Cr) 4.87 5 97.3 1.8mg/L -1257514.87
Copper (Cu) 4.91 5 98.2 1.5mg/L -1257514.91
Iron (Fe) 5.21 5 101 1.33mg/L -1257515.21
Magnesium (Mg) 13.7 5 102 1.93mg/L -12575113.7
Manganese (Mn) 4.97 5 98.9 1.84mg/L -1257514.97
Nickel (Ni) 4.92 5 98.3 1.62mg/L -1257514.92
Potassium (K) 10.1 5 101 2.52mg/L -12575110.1
Silver (Ag) 0.467 0.5 93.7 1.52mg/L -1257510.467
Sodium (Na) 17.4 5 99.6 4.25mg/L -12575117.4
Zinc (Zn) 4.92 5 98.3 1.64mg/L -1257514.92
Page 11 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080179 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.012 ug/L -1-0.012 1 < 1/2 RDL
Cadmium (Cd) 0.0078 ug/L -10.0078 1 < 1/2 RDL
Lead (Pb) 0 ug/L -10 1 < 1/2 RDL
Selenium (Se) 0.012 ug/L -10.012 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 48.5 50 97.1ug/L -12080148.5
Cadmium (Cd) 50.4 50 101ug/L -12080150.4
Lead (Pb) 43.9 50 87.7ug/L -12080143.9
Selenium (Se) 49.6 50 99.3ug/L -12080149.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023173
Arsenic (As) 48.8 50 97.4ug/L -12575148.8
Cadmium (Cd) 50.3 50 100ug/L -12575150.3
Lead (Pb) 50.6 50 101ug/L -12575150.6
Selenium (Se) 81 50 94.5ug/L -12575181
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070637 -- 2016023173
Arsenic (As) 50.1 50 100 2.62ug/L -12575150.1
Cadmium (Cd) 50.9 50 102 1.19ug/L -12575150.9
Lead (Pb) 50.7 50 101 0.263ug/L -12575150.7
Selenium (Se) 82.8 50 98.1 3.74ug/L -12575182.8
Page 12 of 14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070638
Q16080257 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16080159 -- 2016024616
TDS 3.28mg/L -190
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16080159 -- 2016024617
TDS 1.26mg/L -1237
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16080159 -- 2016024618
TDS 1.79mg/L -1332
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J16080159 -- 2016024621
TDS 4.26mg/L -123
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Page 13 of 14
Page 14 of 14

Attachment 2
Marshall Industrial Landfill No. 1
Semi-Annual Monitoring Event
Leachate Field Results
August 3, 2016
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 352.4 ▬▬►350 346.6 ▬/▬►350
SS 72.9 ▬/▬►75 74.6 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.01 ▬▬►7.02 6.99 ▬/▬►7.02
B (4.00)4.01 ▬▬►4.00 3.97 ▬/▬►4.00
B (10.00)10.01 ▬/▬►10.06 10.00 ▬/▬►10.06
20.45 20.49
pH Check B (7.00)▬▬►7.13
Time:0.00
439 ▬▬►440 439 ▬/▬►440
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.27 20.29
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.94 ▬▬►8.92 8.92 ▬/▬►8.92
After Cal 8.93 100.12 8.90 99.73
LCS 8.96 100.46 8.95 100.29
LCSD 8.92 -0.45 8.97 0.22
SS 53.0 ▬/▬►54.5 53.8 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - INDUSTRIAL WASTE LANDFILL 1 GROUNDWATER MONITORING
DATE (s):August 3, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clouds, calm, 75 to 80 deg F
COLLECTORS:LDC SURFACE UNIT SERIAL #:3858
ANALYZER MODEL#:MS5 66120
Calibration Date / Time 3-Aug-16 520 4-Aug-16 610
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)742.41 CALIBRATION BP (mmHg)743.40
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
90.7
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.75 19.79
742.41 743.40
90.5
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 742.4 (mmHg)Ending BP 743.4
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
DATE TIME
1.49
8/3/2016 1230
PURGE METHOD
No Purge
DISCHARGERECHARGEPRESSURE
PUMP CONTROLER SETTINGS
N/ACONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
N/AWELL VOLUME
FIELD CREW LDC
MONITORING WELL INFORMATION
N/A
PROCEDURE NO 3175.4DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
SITE NAME MARSHALL STEAM STATION PERMIT #18-12 SITE ID
PROJECT NAME INDUSTRIAL WASTE LANDFILL 1
SAMPLING DATE(s)3-Aug-2016
PUMP INTAKE DEPTH (ft TOC)
TOC ELEV (ft msl)
GS ELEV (ft msl)
WELL/LOCATION NAME CELL 1 LEACHATE
SCREEN LENGTH (ft)ELEV REF
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A
EQUIPMENT INFORMATION
LEVEL METER SERIAL#N/A SAMPLING EQUIPMENT
TUBING DIAMETER (in)
GRAB
WATER ELEVATION (ft msl)N/A
APPEARANCE
DETECTED ODOR None
Normal
SPECIFIC pH TURBIDITY ORP DISSOLVED HYDRASLEEVE DEPLOYED DATE TEMP
(inches)(ft TOC)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
LDC N/A
Deployed Water Column In Screen
Above Top Of HydrasleeveTop Weight
NO PURGE SAMPLE CHLORINE
(mg/l)SAMPLE COLLECTED BY
N/AN/A N/A N/A 17.21 3615 4.29 15.3 566
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
Allow system to flush for several minutes prior to sampling - watch for low level alarm during pumping.
ADDITIONAL WELL CONDITION NOTES
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-12 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME INDUSTRIAL WASTE LANDFILL 1 FIELD CREW LDC
SAMPLING DATE(s)3-Aug-2016 WELL/LOCATION NAME CELL 2 LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)
PUMP CONTROLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR N/A
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)N/A WELL VOLUME N/A
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 8/3/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 17.61 3419 4.32 6.1
1210
497 0.34
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
Allow system to flush for several minutes prior to sampling - watch for low level alarm during pumping.
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DODATENO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
8/3/2016 CELL 1 LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A 17.21 3615 4.3 15.3 566 1.49
8/3/2016 CELL 2 LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A 17.61 3419 4.3 6.1 497 0.34
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
MARSHALL STEAM STATION
INDUSTRIAL WASTE LANDFILL 1
GROUNDWATER MONITORING FIELD DATA
PERMIT #18-12