8503_DukeBelewsCreekPineHall_Oct2016_2ndSemiAnnual_DIN27228_20170104

Pine Hall Road Ash Landfill
Permit No. 8503
Semiannual Groundwater
Monitoring Report
October 2016 Sampling Event
Belews Creek Steam Station
December 30, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Contents

i
Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 – Results ...................................................................................................................... 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
Tables
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. 15A NCAC 2L Groundwater Quality Standard Exceedances for Wells within the Review
Boundary
6. 15A NCAC 2L Groundwater Quality Standard Exceedances at or Beyond Review
Boundary
Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 1 – Background

1
Section 1 – Background
The Pine Hall Road Ash Landfill is located at the Duke Energy Carolinas, LLC (Duke Energy)
Belews Creek Steam Station in Stokes County, North Carolina. The landfill is permitted under
the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8503
and was closed in December 2008. The ash landfill was permitted to accept only fly ash from
Belews Creek Steam Station operations. The ash landfill and nearby surrounding area are
portrayed on Figure 1.
The landfill was originally permitted in 1983. The original landfill was unlined and was permitted
with a soil cap 1 foot thick on the side slopes and 2 feet thick on flatter areas. A subsequent
expansion (Phase I Expansion) was permitted in 2003. This phase was also unlined but was
permitted with a synthetic cap system to be applied at closure.
After groundwater exceedances were observed in wells installed near the landfill, the placement
of additional ash in the Phase I Expansion was halted. The closure design was changed to
utilize an engineered cover system for the portion of the landfill indicated on Figure 2. The
engineered cover system consists of a 40-mil linear low density polyethylene geomembrane, a
geonet composite, 18 inches of compacted soil, and 6 inches of vegetative soil cover. The
engineered cover system was installed over a 37.9 acre area, indicated on Figure 2 as
“Approximate Limits of Engineered Cover System.” An adjacent 14.5 acre area, located to the
northeast, had additional soil cover applied and was graded to improve surface drainage. This
area is indicated on Figure 2 as “Limits of Soil Cap.” The construction of the engineered cover
system and additional soil cover on the 14.5 acre area was completed in December 2008.
The ash landfill is located to the north of the surface water divide that runs along Pine Hall Road
and to the east of a surface water divide that runs along Middleton Loop Road. These surface
water divides appear to mimic the shallow groundwater divides in the area near the landfill. Two
surface water features are located in the area near the landfill. One surface water drainage
feature drains along the eastern side of the landfill to the Ash Basin. The second surface water
drainage feature is located on the western side of the landfill and drains to the Ash Basin. The
surface water sample locations in these features are groundwater seeps and are believed to be
representative of groundwater. Samples collected from these locations are compared to 15A
North Carolina Administrative Code (NCAC) 2L groundwater quality standards (2L Standards).
Groundwater flow beneath the landfill is from Pine Hall Road, generally northward, toward the
Ash Basin. The Ash Basin is operated as a water treatment facility and is permitted by the
National Pollutant Discharge Elimination System (NPDES) program (NPDES Permit
#NC0024406).

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 1 – Background

2
The groundwater monitoring system at the landfill consists of the following sample locations as
listed below.
Monitoring Wells: MW-1 MW-1D
MW-2 MW-3
MW-4 MW-5
MW-6 MW-7
MW2-7 MW2-9
OB-4 OB-5
OB-9

Surface Water Locations: SW-1A SW-2

The locations of the monitoring wells and surface water sample locations are shown on
Figure 2. A summary of monitoring well construction information is presented in Table 1. As
defined by the Groundwater Monitoring, Sampling and Analysis Plan (SAP) for the Pine Hall
Road Ash Landfill (prepared by S&ME, Inc. dated November 8, 2010, and approved by NCDEQ
on November 23, 2010), monitoring well MW-3 is considered to represent “background”
groundwater quality conditions.
The groundwater and surface water sampling was conducted by Duke Energy according to
North Carolina Solid Waste Management Guidelines. The constituents sampled and analyzed
were selected by Duke Energy and the NCDEQ Division of Solid Waste and are listed in the
SAP. The samples were analyzed by a North Carolina certified laboratory.
During previous sampling events the groundwater samples were also analyzed for Part 40 Code
of Federal Regulations (CFR) Part 258, Appendix I constituents, in addition to the constituents
listed in the SAP. Appendix I sampling and analysis was performed as part of the requirements
contained in the Closure Plan Approval letter dated December 7, 2007, Document ID RC03425.
Sampling of Appendix I volatile organic compounds has been discontinued as per a June 8,
2015 electronic mail correspondence from Elizabeth Werner of the NCDEQ Solid Waste
Section. A copy of this correspondence is retained in Duke Energy’s operating record. Appendix
I inorganics that are not already part of the Belews Creek Pine Hall Road Landfill Sampling and
Analysis Plan are identified in Table 4.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 2 – Methods

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193). Copies of the field
sampling forms are included in Appendix A. The groundwater samples were analyzed by the
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) and provided
to HDR by Duke Energy. The laboratory report and chain-of-custody forms are included in
Appendix B.
The groundwater samples were analyzed for the following constituents and/or parameters:
 Barium, beryllium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc
using Solid Waste (SW)-8461 Method 6010D
 Antimony, arsenic, cadmium, cobalt, lead, selenium, thallium, and vanadium using SW-
846 Method 6020B
 Mercury using United States Environmental Protection Agency (EPA) SW-846 Method
7470A
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA SW-846 Method 9056A
 Total dissolved solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy for monitoring wells MW-1
MW-1D, MW-3, MW-4, MW-5, MW-6, MW-7, MW2-7, MW2-9, OB-4, OB-5, and OB-9
and surface water sampling locations SW-1A and SW-2. A groundwater sample was not
collected from MW-2 due to insufficient water volume in the well and possible clogged
tubing in the well. However, a groundwater level measurement was able to be collected
from MW-2. The samples were collected by Duke Energy personnel on November 8,
2016, and HDR received the data on October 10, 2016.
 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDD) provided by Duke Energy was adapted to conform to the format requirements of
the NCDEQ EDD template. HDR added an italicized J data qualifier (J) to indicate a
detected concentration that equals or is greater than the laboratory’s method reporting

1 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed August 30, 2016)
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 2 – Methods

4
limit (MRL), but is less than the Solid Waste Section Limit2 (SWSL). A copy of the
original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater contours.
 Prepared this Semiannual Groundwater Monitoring Report and submitted it to Duke
Energy.

2 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Belews Creek Pine Hall Road Ash Landfill, Permit No.8503
October 2016 Sampling Event
Section 3 – Results

5
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the wells on the date of sampling. Calculated groundwater flow velocities are
presented in Table 2.
Pine Hall Road is located generally along a surface water divide that also appears to be a
groundwater divide. Groundwater flow at the landfill site is from areas of higher topography
along Pine Hall Road, generally northward, toward the Ash Basin.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analytical results are compared to the groundwater standards found in Title 15A
NCAC 02L .0202 (g) (2L Standards). Concentrations that attain or exceed the 2L Standards or
Intermim Maximum Allowable Concentrations (IMACs) are noted in Table 4 by bold font.
Concentrations that equal or are greater than the SWSLs are noted in Table 4 by gray-shaded
cells.
A summary of the 2L Standard exceedances and a preliminary analysis of the cause and
significance of the exceedances is presented in Table 5 for sampling locations located within the
review boundary and in Table 6 for sampling locations located at or beyond the review
boundary.
Select samples were diluted as is normal laboratory practice to bring samples to the calibrated
range of the analysis. Specifics regarding the samples that were diluted, including the dilution
factor, are reported in the EDD.
HDR previously prepared and submitted an assessment to the NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station Pine Hall
Road Ash Landfill, Permit No. 8503, dated October 1, 2012). The report assessed 2L Standard
exceedances at wells MW-3 and MW-6 and found those exceedances to be attributed to
naturally occurring conditions.
The assessment report reviewed the location of wells and surface water sample locations with
exceedances of 2L Standards (MW-4, MW-7, MW2-7, MW2-9, SW-1A, and SW-2) and found
that the hydrologic boundaries and the groundwater flow at the site was such that the
groundwater at these locations was discharging to the ash basin. The report also concluded that
with the reduced infiltration, due to the engineered cover system installed in 2008, the
groundwater concentration of constituents attributable to fly ash in these wells will likely
continue to decrease over time.

FIGURES
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FIGURE
SITE LOCATION MAP
BELEWS CREEK STEAM STATION
PINE HALL ROAD ASH LANDFILL
PERMIT NO. 8503
DECEMBER 2016
1
HDR Engineering Inc.
440 S. Church St. Suite 1000
Charlotte, NC 28202-2075
704.338.6700
of the Carolinas

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t
i
c
a
l

d
a
t
u
m
.
8
.

D
e
p
t
h

t
o

w
a
t
e
r

g
a
u
g
e
d

o
n

O
c
t
o
b
e
r

1
0
,

2
0
1
6
.
We
l
l

I
D
We
l
l

I
n
s
t
a
l
l
a
t
i
o
n

Da
t
e
TO
C

Ele
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

Ele
v
a
t
i
o
n
(f
t
.
)
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(f
t
.
)
Co
o
r
d
i
n
a
t
e
s
Well Diameter (in.)Casing Type
Gr
o
u
n
d
w
a
t
e
r

El
e
v
a
t
i
o
n

(
f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(f
t
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(ft
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)

G
e
o
l
o
g
y

o
f

S
c
r
e
e
n
e
d

I
n
t
e
r
v
a
l
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
MW
-
4

7
6
0

7
5
5
.
1
7

1
5
6

0
.
0
3
1

0
.
4
1
1

0
.
2
5
9

0
.
0
4
9
MW
-
7

8
0
8
.
8
4

8
0
5

8
3

0
.
0
4
6

0
.
4
1
1

0
.
2
5
9

0
.
0
7
3
OB
-
4

7
6
0

7
5
5
.
1
4

6
3

0
.
0
7
7

0
.
4
1
1

0
.
2
5
9

0
.
1
2
3
OB
-
5

7
5
5

7
5
4
.
7
5

3
0

0
.
0
0
8

0
.
4
1
1

0
.
2
5
9

0
.
0
1
3
OB
-
9

7
6
5

7
6
0

8
0

0
.
0
6
3

0
.
4
1
1

0
.
2
5
9

0
.
0
9
9
MW
2
-
7

7
6
5

7
6
0

3
0

0
.
1
6
5

0
.
4
1
1

0
.
2
5
9

0
.
2
6
1
MW
2
-
9

7
9
5

7
9
0

3
1

0
.
1
6
3

0
.
4
1
1

0
.
2
5
9

0
.
2
5
8
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

g
e
n
e
r
a
l
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

i
s

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
gr
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

te
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

m
e
a
s
u
r
e
m
e
n
t
s

o
n

O
c
t
o
b
e
r

1
0
,

2
0
1
6
.
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D
Up
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n

(
f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

D
i
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

P
e
r
m
i
t

N
o
.

8
5
0
3
10
/
1
0
/
2
0
1
6

M
W
-
1

4
7
.
2
0

3
3
.
9
6

8
1
8
.
7
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

2
.
1
6

5
.
7
5

N
O

1
4
.
8
5

1
8

4
.
8

2
3
.
9

4
3
9

8
.
4
1
10
/
1
0
/
2
0
1
6

M
W
-
1
D

9
0
.
5
3

4
2
.
2
9

8
1
1
.
8
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

7
.
8
7

1
6
.
5
0

N
O

1
4
.
4
8

1
1
9

6
.
4

0
.
6

3
1
7

4
.
7
7
10
/
1
0
/
2
0
1
6

M
W
-
2

5
0
.
0
0

4
5
.
2
8

8
1
2
.
7
7

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S

N
S
10
/
1
0
/
2
0
1
6

M
W
-
3

4
9
.
5
0

4
2
.
2
4

8
0
0
.
5
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
1
8

1
.
2
5

Y
E
S

1
4
.
3
1

5
4

5
.
5

1
2
.
7

3
5
6

8
.
9
2
10
/
1
0
/
2
0
1
6

M
W
-
4

4
0
.
2
0

1
2
.
4
1

7
5
5
.
1
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

4
.
5
3

1
0
.
7
5

N
O

1
4
.
8
0

2
5
2

6
.
0

8
.
1

2
8
2

2
.
5
9
10
/
1
0
/
2
0
1
6

M
W
-
5

6
0
.
2
0

2
5
.
6
2

7
6
1
.
1
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

5
.
6
4

1
2
.
5
0

N
O

1
4
.
7
4

3
7

5
.
5

1
1
.
7

3
8
7

6
.
9
8
10
/
1
0
/
2
0
1
6

M
W
-
6

3
6
.
8
4

3
3
.
3
8

8
0
3
.
5
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

0
.
5
6

1
.
7
5

N
O

1
5
.
1
9

5
1

5
.
4

1
.
5

3
6
6

4
.
1
2
10
/
1
0
/
2
0
1
6

M
W
-
7

1
4
.
2
6

6
.
7
3

8
0
8
.
8
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
3

4
.
2
5

N
O

1
9
.
7
7

3
8
4

5
.
2

1
8
.
2

3
7
9

4
.
7
0
10
/
1
0
/
2
0
1
6

M
W
2
-
7

3
0
.
6
2

1
4
.
1
8

7
6
3
.
4
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

2
.
6
8

1
3
.
7
5

N
O

1
5
.
9
2

2
,
0
4
0

4
.
9

1
.
4

3
6
3

0
.
0
0
10
/
1
0
/
2
0
1
6

M
W
2
-
9

1
4
.
6
1

5
.
8
3

7
9
1
.
5
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
4
3

3
.
0
0

Y
E
S

1
5
.
0
4

2
5
6

6
.
0

2
0
.
7

3
3
8

7
.
8
2
10
/
1
0
/
2
0
1
6

O
B
-
4

3
0
.
0
3

2
2
.
4
6

7
5
5
.
1
4

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
3

3
.
7
5

N
O

1
5
.
8
5

2
,
6
0
8

7
.
0

2
.
0

1
6
8

0
.
0
0
10
/
1
0
/
2
0
1
6

O
B
-
5

3
6
.
6
0

2
6
.
1
8

7
5
4
.
7
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
0

5
.
2
5

N
O

1
5
.
2
7

2
6
.
0

5
.
1

3
.
6

3
7
9

5
.
8
5
10
/
1
0
/
2
0
1
6

O
B
-
9

4
8
.
5
7

3
7
.
8
2

7
6
1
.
7
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
5

5
.
2
5

N
O

1
4
.
7
7

1
,
8
6
1

5
.
2

1
.
1

3
8
6

0
.
0
0
10
/
1
0
/
2
0
1
6

S
W
-
1
A

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
2
.
3
4

1
,
6
3
3

5
.
9

1
.
4

3
5
1

6
.
4
4
10
/
1
0
/
2
0
1
6

S
W
-
2

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
4
.
8
4

1
3
0

6
.
3

1
3
.
5

2
1
3

9
.
2
0
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

L
F
(
M
)
=

L
o
w

F
l
o
w

(
M
o
d
i
f
i
e
d
)
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e,
N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
.

A
v
e
r
a
g
e

p
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

a
n
d

L
F
(
M
)

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µƱ /cm

i
n
d
i
c
a
t
e
s

m
i
c
r
o
o
h
m
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
8
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.
9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.
11
.

A

g
r
o
u
n
d
w
a
t
e
r

s
a
m
p
l
e

w
a
s

n
o
t

c
o
l
l
e
c
t
e
d

f
r
o
m

M
W
-
2

a
s

i
t
s

b
l
a
d
d
e
r

p
u
m
p

t
u
b
i
n
g

i
s

s
u
s
p
e
c
t
e
d

t
o

b
e

c
l
o
g
g
e
d
.
12
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

8
,

2
0
1
6
.
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

AV
E
R
A
G
E
PU
M
P

RA
T
E
(m
l
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Ʊ /c
m
)
pH
(S
U
)
TURBIDITY (NTU)ORP (mV-NHE)
AP
P
E
A
R
A
N
C
E
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
e
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
Page 1 of 1
Ta
b
l
e

4

-

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

f
o
r

S
e
m
i
a
n
n
u
a
l

C
o
n
s
t
i
t
u
e
n
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
B
e
l
e
w
s

C
r
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e
k

S
t
e
a
m

S
t
a
t
i
o
n
Pi
n
e

H
a
l
l

R
o
a
d

A
s
h

L
a
n
d
f
i
l
l

-

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e
r
m
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t

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o
.

8
5
0
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d

p
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32
0

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1
9
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6
.
5
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5

6
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8
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S
p
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c
i
f
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c

C
o
n
d
u
c
t
a
n
c
e
32
3

µ
Ʊ /cm

5
1
9
3
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E

N
E

N
E
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m
p
e
r
a
t
u
r
e

3
2
5

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5
1
9
3
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E
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p

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a
s
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n
g

3
2
8

f
e
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t
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N
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p
t
h

t
o

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a
t
e
r
31
8

f
e
e
t
-
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N
E

N
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t
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r

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l
e
v
a
t
i
o
n

3
1
9

f
e
e
t
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l
l

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e
p
t
h

4
1
1

f
e
e
t
-
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E

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E

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E
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t
i
m
o
n
y
*

1
3

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g
/
L

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8

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.
3
1
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2
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6

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6
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s
e
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c
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g
/
L

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7
8

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0.1
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0
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9
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0.
0
7
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r
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m

1
5

µ
g
/
L

2
4
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2
3
.
9
J '
1.3
5
J
88
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8
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5.5
6
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36
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2
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r
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l
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2
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g
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2

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0
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2

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7
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4
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0
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1
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r
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n

4
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g
/
L

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.
3

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3
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3

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3
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3

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71
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3.
3

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E
70
0

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d
m
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m

3
4

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g
/
L

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1
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l
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r
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4
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g
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8

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1
8
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7
8
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5
4
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m
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5

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b
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g
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p
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3
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10
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34
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µ
g
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L

2
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2
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2
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4
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3

3
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a
d
13
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g
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r
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(
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s

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n
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4

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l
v
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r
18
4

µ
g
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1.8
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7

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2
8

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7

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20
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l
f
a
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e
31
5

µ
g
/
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2
4
8
1,6
6
0
J '
97
4
J '
28
4
J '
80
,
4
0
0
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15
1
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18

2
5
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2
5
0
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0
0
0
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a
l
l
i
u
m
*

1
9
4

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g
/
L

2
4
8

0
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1
3
3

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0
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1
3
3

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0
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1
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1
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1
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1
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t
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s
s
o
l
v
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l
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d
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3
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1

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g
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L

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4
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2
3
,
0
0
0
J
93
,
0
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0
61
,
0
0
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6
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0
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3
,
0
0
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,
7
0
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50
0
,
0
0
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0
0
,
0
0
0
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n
a
d
i
u
m
*
20
9

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g
/
L

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5
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 227.3 ŷŷŹ 227 227.2 ŷŷŹ 227
SS 74.2 ŷŷŹ 75 76.8 ŷŷŹ 75
SS 3193.0 ŷŷŹ 3200 3198.0 ŷŷŹ 3200
B (7.00)7.02 ŷŷŹ 7.02 7.07 ŷŷŹ 7.02
B (4.00)3.99 ŷŷŹ 4.00 4.08 ŷŷŹ 4.00
B (10.00)10.07 ŷŷŹ 10.06 10.11 ŷŷŹ 10.06
19.92 20.01
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
439 ŷŷŹ 441 439 ŷŷŹ 441
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 19.91 20.01
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 9.00 ŷŷŹ 9.07 9.15 ŷŷŹ 9.12
After Cal 9.09 100.24 9.19 100.78
LCS 9.08 100.13 9.13 100.13
LCSD 9.09 0.11 9.12 -0.11
SS 53.9 ŷŷŹ 53.6 54.2 ŷŷŹ 53.6
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ŷŷŹ 1RW$GMXVWHG7R
(mmHg)
B = Buffer W = Winkler ŷŷŹ $GMXVWHG7R N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 749.6 (mmHg) Ending BP 750.4
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.33 19.32
748.35 752.30
91.3
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
92.4
ORP Temp. ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)748.35 CALIBRATION BP (mmHg)752.30
Calibration Date / Time 10-Oct-16 425 11-Oct-16 825
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY: BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s): October 10, 2016 SURFACE UNIT READER: LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Clear, slight breeze, 40 to 70 deg F
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: S0205
ANALYZER MODEL#: MS5 66120
de
ORP
TUR
(ntu
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE: TIME: DATE: TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0
SS 219.9 ŷŷŹ 227 225.2 ŷŷŹ 227
SS 74.1 ŷŷŹ 75 74.2 ŷŷŹ 75
SS 3307.3 ŷŷŹ 3200 3302.9 ŷŷŹ 3200
B (7.00)7.06 ŷŷŹ 7.02 6.99 ŷŷŹ 7.02
B (4.00)4.02 ŷŷŹ 4.00 4.04 ŷŷŹ 4.00
B (10.00)9.96 ŷŷŹ 10.06 10.00 ŷŷŹ 10.06
19.91 20.05
pH Check B (7.00)ŷŷŹ 7.13
Time:0.00
440 ŷŷŹ 441 440 ŷŷŹ 441
N/A ŷŷŹ N/A N/A ŷŷŹ N/A
Zobell's 19.90 19.95
TEMP(CO)
BP (mmHg)
COND
100 % mg/L 9.08 ŷŷŹ 9.07 9.13 ŷŷŹ 9.11
After Cal 9.10 100.35 9.12 100.06
LCS 9.06 99.91 9.09 99.73
LCSD 9.02 -0.44 9.07 -0.22
SS 53.2 ŷŷŹ 53.2 51.8 ŷŷŹ 53.2
NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ŷŷŹ 1RW$GMXVWHG7R
(mmHg)
B = Buffer W = Winkler ŷŷŹ $GMXVWHG7R N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 749.6 (mmHg) Ending BP 750.4
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.33 19.34
748.35 752.30
89.9
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
90.4
ORP Temp. ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp. Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)748.35 CALIBRATION BP (mmHg)752.30
Calibration Date / Time 10-Oct-16 405 11-Oct-16 800
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY: BELEWS CREEK STEAM STATION - PINE HALL LANDFILL GROUNDWATER MONITORING
DATE (s): October 10, 2016 SURFACE UNIT READER: PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clear, slight breeze, 40 to 70 deg F
COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0722
ANALYZER MODEL#: HL4 400440
de
ORP
TUR
(ntu
37.20 47.20
25 (psi)12 (sec) (sec)
(gal)
2.16 (gal)
@
QC By:< 2.0
DATE TIME
DISSOLVED
OXYGEN
23.9 439 8.41
8.35446
10/10/2016 1415
Sample preservation verified to pH
(units)
ORP
(ft) (YES/NO)
2.25 37.33 NO 14.81 18 4.74
14.84
VOLUME EVACUATION COND.
PURGE METHOD
Conventional
DISCHARGERECHARGEPRESSURE 8
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
2.16WELL VOLUME
(gal)
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.4DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID
PROJECT NAME PINE HALL LANDFILL
SAMPLING DATE(s)10-Oct-2016
42.20
46.20PUMP INTAKE DEPTH (ft TOC)47.20
TOC ELEV (ft msl)
GS ELEV (ft msl)
852.69
850.55
WELL/LOCATION NAME MW-1
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in) MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 33.96 WATER COLUMN (ft) 13.24
EQUIPMENT INFORMATION
LEVEL METER SERIAL# 26055 SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl) 818.73
APPEARANCE
DETECTED ODOR None
Normal
WATER LEVEL
AFTER PURGE *(recalculates on
current water
level)(deg C) (umho/cm) (SU) (NTU)(mV-NHE)(mg/L)
149.0 447 8.23 1.61
1.75 NO
1.75 NO 14.85 18 4.76
18 4.76 43.9
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY
LDC N/A
TOTAL PURGE
VOLUME
5.75
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Minor Cracks
Good Condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Good Tag
10
T SP TU DISS
(
85.53 90.53
60 (psi)9 (sec) (sec)
(gal)
7.87 (gal)
@
QC By:
SAMPLING NOTES
After initial well is removed, recalculate well volume for subsequent readings. WL drawdown appears to stabilize around 64 ft.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
16.50 LDC 10/10/2016 1100 N/A
4.25 NO 14.48 119 6.39 0.6 317 4.77
4.25 NO 14.45 118 6.36 0.6 314 4.81
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
8.00 65.24 NO 14.46 118 6.35 0.6 305
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
4.87 4.12
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 42.29 WATER COLUMN (ft) 48.24 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 811.86 WELL VOLUME 7.87
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
See note below
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 854.15 MIDDLE OF WETTED SCREEN (ft toc)88.03
SCREEN LENGTH (ft) 5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 90.53 GS ELEV (ft msl) 850.99 PUMP INTAKE DEPTH (ft TOC)89.50
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-1D
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
10
T SP TU DISS
(
40.00 50.00
30 (psi)5 (sec) (sec)
(gal)
1075 (ml)
495 (ml)
1570 (ml)=0.00 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 858.05 MIDDLE OF WETTED SCREEN (ft toc)47.64
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 50.00 GS ELEV (ft msl) 855.44 PUMP INTAKE DEPTH (ft TOC)49.50
See note below - No sample PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Equip. Only Purge
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 45.28 WATER COLUMN (ft) 4.72 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 812.77 WELL VOLUME 0.77
INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(ft) (ml/min) (ft) (deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L)
WATER LEVEL RATE WATER LEVEL COND. OXYGEN
N/A
Tubing Volume EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)Pump (Bladder) Volume
NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE COLLECTED BY DATE TIME
Total Purge Volume LDC 10/10/2016
Sample preservation verified to pH
(units)
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
4/24/12 - Replaced pump and tubing in well and set intake to 49.5 ft (six inches from well bottom). October 2016 sampling - Could not get pump to discharge regardless of
settings - ants inside air line - suspect clogged tubing. No sample.
10
T SP TU DISS
39.50 49.50
25 (psi)14 (sec) (sec)
(gal)
1.18 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-3
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 842.81 MIDDLE OF WETTED SCREEN (ft toc)45.87
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 49.50 GS ELEV (ft msl) 840.57 PUMP INTAKE DEPTH (ft TOC)48.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 42.24 WATER COLUMN (ft) 7.26 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 800.57 WELL VOLUME 1.18
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 YES 14.31 54 5.52 12.7 356
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
8.92
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.25 LDC 10/10/2016 1135 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Evacuated 10/10/16 at 1130 hrs.
10
T SP TU DISS
(
30.20 40.20
22 (psi)10 (sec) (sec)
(gal)
4.53 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-4
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 767.58 MIDDLE OF WETTED SCREEN (ft toc)35.20
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 40.20 GS ELEV (ft msl) 766.10 PUMP INTAKE DEPTH (ft TOC)39.20
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 12.41 WATER COLUMN (ft) 27.79 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 755.17 WELL VOLUME 4.53
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
4.75 22.33 NO 14.84 246 5.96 21.1 298
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
3.02 2.91
3.00 NO 14.80 252 5.95 8.1 282 2.59
3.00 NO 14.80 257 5.95 14.9 264 2.81
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
10.75 LDC 10/10/2016 0920 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
50.20 60.20
30 (psi)6 (sec) (sec)
(gal)
5.64 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-5
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 786.77 MIDDLE OF WETTED SCREEN (ft toc)55.20
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 60.20 GS ELEV (ft msl) 785.39 PUMP INTAKE DEPTH (ft TOC)59.20
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 9
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 25.62 WATER COLUMN (ft) 34.58 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 761.15 WELL VOLUME 5.64
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
5.75 46.58 NO 14.78 38 5.67 30.7 388
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
7.55 2.22
2.25 NO 14.77 37 5.53 11.8 388 6.93
2.25 NO 14.77 38 5.51 12.3 389 6.99
2.25 NO 14.74 37 5.53 11.7 387 6.98
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
12.50 PSP 10/10/2016 1350 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
26.84 36.84
25 (psi)7 (sec) (sec)
(gal)
0.56 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 836.91 MIDDLE OF WETTED SCREEN (ft toc)35.11
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 36.84 GS ELEV (ft msl) 834.40 PUMP INTAKE DEPTH (ft TOC)35.84
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 3
26055 SAMPLING EQUIPMENT QED T1250 PURGE METHOD
TUBING DIAMETER (in)1/4 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 33.38 WATER COLUMN (ft) 3.46 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 803.53 WELL VOLUME 0.56
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
0.75 33.82 NO 15.13 54 5.36 1.7 366
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
4.43 0.49
0.50 NO 15.19 51 5.35 1.5 366 4.12
0.50 NO 15.28 52 5.34 3.3 366 4.20
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
1.75 LDC 10/10/2016 1250 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
4.26 14.26
20 (psi)10 (sec) (sec)
(gal)
1.23 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW-7
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 815.57 MIDDLE OF WETTED SCREEN (ft toc)10.50
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 14.26 GS ELEV (ft msl) 812.52 PUMP INTAKE DEPTH (ft TOC)13.26
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 6.73 WATER COLUMN (ft) 7.53 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 808.84 WELL VOLUME 1.23
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 8.17 NO 20.32 374 5.15 8.2 371
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
5.00 0.99
0.84
1.00 9.81 NO 20.11 387 5.28 19.3 377 5.76 0.73
1.00 9.13 NO 20.40 383 5.25 15.9 373 5.91
1.00 NO 19.77 384 5.24 18.2 379 4.70
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.25 PSP 10/10/2016 0845 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
20.62 30.62
25 (psi)5 (sec) (sec)
(gal)
2.68 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW2-7
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 777.64 MIDDLE OF WETTED SCREEN (ft toc)25.62
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 30.62 GS ELEV (ft msl) 775.45 PUMP INTAKE DEPTH (ft TOC)29.62
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 14.18 WATER COLUMN (ft) 16.44 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 763.46 WELL VOLUME 2.68
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
2.75 NO 15.74 1656 4.86 1.2 383
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
0.00
2.75 NO 15.86 1962 4.85 1.4 370 0.00
2.75 NO 15.85 1860 4.87 1.8 375 0.00
2.75 NO 15.92 2040 4.87 1.4 363 0.00
2.75 NO 15.87 2005 4.85 1.3 366 0.00
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
13.75 PSP 10/10/2016 1010 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
4.61 14.61
10 (psi)5 (sec) (sec)
(gal)
1.43 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME MW2-9
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 797.38 MIDDLE OF WETTED SCREEN (ft toc)10.22
SCREEN LENGTH (ft) 10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 14.61 GS ELEV (ft msl) 794.75 PUMP INTAKE DEPTH (ft TOC)13.61
Well evacuated on 10/10/2016 @ 0800 hrs.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 5.83 WATER COLUMN (ft) 8.78 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 791.55 WELL VOLUME 1.43
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 7.62 NO 19.28 181 5.80 21.5 304
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
6.04 1.14
0.52
0.25 YES 15.04 256 5.98 20.7 338 7.82
1.25 11.41 NO 18.66 185 5.76 18.2 341 6.33
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.00 PSP 10/10/2016 1410 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Water level at 1405 hrs. was 10.58 feet below TOC (0.66 gal.).
10
T SP TU DISS
(
15.03 30.03
15 (psi)5 (sec) (sec)
(gal)
1.23 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME OB-4
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 777.60 MIDDLE OF WETTED SCREEN (ft toc)26.25
SCREEN LENGTH (ft) 15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 30.03 GS ELEV (ft msl) 774.72 PUMP INTAKE DEPTH (ft TOC)29.10
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 22.46 WATER COLUMN (ft) 7.57 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 755.14 WELL VOLUME 1.23
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 15.79 2672 6.88 3.3 121
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
0.00
1.25 NO 15.85 2608 7.00 2.0 168 0.00
1.25 NO 15.82 2641 6.96 2.4 154 0.00
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 10/10/2016 1110 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Well casing had ants inside discharge and air line was difficult to get pumping, was
clogged with ants. Eventually was able to get well to begin purging and sampled. WELL PAD Good Condition
WELL CASING Damaged Casing / Requires Repair
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
21.60 36.60
18 (psi)8 (sec) (sec)
(gal)
1.70 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME OB-5
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 780.93 MIDDLE OF WETTED SCREEN (ft toc)31.39
SCREEN LENGTH (ft) 15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 36.60 GS ELEV (ft msl) 778.13 PUMP INTAKE DEPTH (ft TOC)35.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 26.18 WATER COLUMN (ft) 10.42 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 754.75 WELL VOLUME 1.70
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND. OXYGEN
(recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 15.31 26 5.04 7.4 366
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
6.01
1.75 NO 15.27 26 5.10 3.6 379 5.85
1.75 NO 15.26 26 5.12 5.7 371 5.82
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 LDC 10/10/2016 0800 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10
T SP TU DISS
(
39.17 48.57
25 (psi)10 (sec) (sec)
(gal)
1.75 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 10/10/2016 1215 N/A
1.75 NO 14.77 1861 5.16 1.1 386 0.00
1.75 NO 14.79 1886 5.19 1.0 383 0.00
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 14.84 1868 5.24 2.0 373
(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU)
0.00
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
1.75
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) 37.82 WATER COLUMN (ft) 10.75 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) 761.77 WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in) 2 TOC ELEV (ft msl) 799.59 MIDDLE OF WETTED SCREEN (ft toc)43.87
SCREEN LENGTH (ft) 9.40 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) 48.57 GS ELEV (ft msl) 797.11 PUMP INTAKE DEPTH (ft TOC)46.00
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME OB-9
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
10
T SP TU DISS
(
N/A
N/A (psi)N/A (sec) (sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
0920
351 6.44
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 12.34 1633 5.90 1.4
TIME
PSP 10/10/2016
LENGTH DEPTH (top) DEPLOYED COND. OXYGEN
(inches) (ft TOC) (deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft) N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) N/A WELL VOLUME
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in) TOC ELEV (ft msl) N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft) N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) N/A GS ELEV (ft msl) 762.27 PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME SW-1A
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
10
T SP TU DISS
N/A
N/A (psi)N/A (sec) (sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
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WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1140
213 9.20
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N/A
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Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 14.84 130 6.25 13.5
TIME
PSP 10/10/2016
LENGTH DEPTH (top) DEPLOYED COND. OXYGEN
(inches) (ft TOC) (deg C) (umho/cm) (SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC) N/A WATER COLUMN (ft) N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl) N/A WELL VOLUME
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in) TOC ELEV (ft msl) N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
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EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC) N/A GS ELEV (ft msl) 775.30 PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME PINE HALL LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)10-Oct-2016 WELL/LOCATION NAME SW-2
SITE NAME BELEWS CREEK STEAM STATION PERMIT # 85-03 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
10
T SP TU DISS
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October 10, 2016
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B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16090359
Project Name:BELEWS - GW PINE HALL LF
Lab Contact: Anne Pridgeon
Date:10/28/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
As per chain of custody: sample could not be collected at location MW2 due to plugged pump apparatus.
Please note that the vanadium result reported for MW-3 is slightly elevated compared to historical trends.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 30
Reason: I have reviewed this
document.
Date: 2016.10.28 16:30:54
-04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016029744 BELEWS 10-Oct-16 2:15 PM LDC MW-1
2016029745 BELEWS 10-Oct-16 11:00 AM LDC MW-1D
2016029747 BELEWS 10-Oct-16 11:35 AM LDC MW-3
2016029748 BELEWS 10-Oct-16 9:20 AM LDC MW-4
2016029749 BELEWS 10-Oct-16 1:50 PM PSP MW-5
2016029750 BELEWS 10-Oct-16 12:50 PM LDC MW-6
2016029751 BELEWS 10-Oct-16 8:45 AM PSP MW-7
2016029752 BELEWS 10-Oct-16 10:10 AM PSP MW2-7
2016029753 BELEWS 10-Oct-16 2:10 PM PSP MW2-9
2016029754 BELEWS 10-Oct-16 11:10 AM PSP OB-4
2016029755 BELEWS 10-Oct-16 8:00 AM LDC OB-5
2016029756 BELEWS 10-Oct-16 12:15 PM PSP OB-9
2016029757 BELEWS 10-Oct-16 9:20 AM PSP SW-1A
2016029758 BELEWS 10-Oct-16 11:40 AM PSP SW-2
2016029759 BELEWS 10-Oct-16 2:35 PM PSP FIELD BLANK
15 Total Samples
Duke Energy Analytical Lab
Page 2 of 30
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:10/28/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029744
Collection Date:10-Oct-16 2:15 PM
Site:MW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 9056A 10/11/2016 11:09B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 11:09 BGN90340.1 1
Nitrate 0.51 mg/L EPA 9056A 10/11/2016 11:09 BGN90340.1 1
Nitrate as N 0.11 mg-N/L EPA 9056A 10/11/2016 11:09 BGN90340.023 1
Sulfate 1.7 mg/L EPA 9056A 10/11/2016 11:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:02 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 10:18 MHH71310.05 1
Calcium (Ca)1.16 mg/L SW 6010D 10/19/2016 10:18B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Iron (Fe)0.792 mg/L SW 6010D 10/19/2016 10:18 MHH71310.01 1
Magnesium (Mg)0.318 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Manganese (Mn)0.042 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Potassium (K)0.408 mg/L SW 6010D 10/19/2016 10:18 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
Sodium (Na)2.10 mg/L SW 6010D 10/19/2016 10:18 MHH71310.05 1
Zinc (Zn)0.122 mg/L SW 6010D 10/19/2016 10:18 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Cobalt (Co)1.34 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Lead (Pb)2.62 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:01B2 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/18/2016 04:01 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 4 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029745
Collection Date:10-Oct-16 11:00 AM
Site:MW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)37 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride 7.8 mg/L EPA 9056A 10/11/2016 14:04B2 BGN90340.1 1
Fluoride 0.11 mg/L EPA 9056A 10/11/2016 14:04 BGN90340.1 1
Nitrate 8.3 mg/L EPA 9056A 10/11/2016 14:04 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 9056A 10/11/2016 14:04 BGN90340.023 1
Sulfate 0.97 mg/L EPA 9056A 10/11/2016 14:04 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/18/2016 11:45 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 10:06 MHH71310.05 1
Calcium (Ca)6.18 mg/L SW 6010D 10/19/2016 10:06B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 10/19/2016 10:06 MHH71310.01 1
Magnesium (Mg)5.34 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Potassium (K)1.87 mg/L SW 6010D 10/19/2016 10:06 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
Sodium (Na)9.24 mg/L SW 6010D 10/19/2016 10:06 MHH71310.05 1
Zinc (Zn)0.007 mg/L SW 6010D 10/19/2016 10:06 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:08B2 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/18/2016 04:08 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 93 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 5 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029747
Collection Date:10-Oct-16 11:35 AM
Site:MW-3
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.1 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 9.5 mg/L EPA 9056A 10/11/2016 14:20B2 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 14:20 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 10/11/2016 14:20 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 10/11/2016 14:20 BGN90340.023 1
Sulfate 0.28 mg/L EPA 9056A 10/11/2016 14:20 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:04 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.089 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 10:22 MHH71310.05 1
Calcium (Ca)3.74 mg/L SW 6010D 10/19/2016 10:22B1 MHH71310.01 1
Chromium (Cr)0.008 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Iron (Fe)5.35 mg/L SW 6010D 10/19/2016 10:22 MHH71310.01 1
Magnesium (Mg)1.64 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Manganese (Mn)0.072 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Potassium (K)3.13 mg/L SW 6010D 10/19/2016 10:22 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
Sodium (Na)3.09 mg/L SW 6010D 10/19/2016 10:22 MHH71310.05 1
Zinc (Zn)0.013 mg/L SW 6010D 10/19/2016 10:22 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Cobalt (Co)1.80 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Lead (Pb)2.47 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:15B2 CWSPEN30.2 1
Vanadium (V)10.4 ug/L SW 6020B 10/18/2016 04:15 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 61 mg/L SM2540C 10/14/2016 14:55 HGRUVER331
Duke Energy Analytical Lab
Page 6 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029748
Collection Date:10-Oct-16 9:20 AM
Site:MW-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)32 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 9056A 10/11/2016 14:52B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 14:52 BGN90340.1 1
Nitrate 4.4 mg/L EPA 9056A 10/11/2016 14:52 BGN90340.1 1
Nitrate as N 1.00 mg-N/L EPA 9056A 10/11/2016 14:52 BGN90340.023 1
Sulfate 80 mg/L EPA 9056A 10/11/2016 14:52 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:07 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.006 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Boron (B)0.718 mg/L SW 6010D 10/19/2016 10:26 MHH71310.05 1
Calcium (Ca)22.9 mg/L SW 6010D 10/19/2016 10:26B1 MHH71310.01 1
Chromium (Cr)0.014 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Iron (Fe)0.564 mg/L SW 6010D 10/19/2016 10:26 MHH71310.01 1
Magnesium (Mg)12.9 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Manganese (Mn)0.009 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Potassium (K)1.21 mg/L SW 6010D 10/19/2016 10:26 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
Sodium (Na)8.10 mg/L SW 6010D 10/19/2016 10:26 MHH71310.05 1
Zinc (Zn)0.085 mg/L SW 6010D 10/19/2016 10:26 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Selenium (Se)15.8 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 03:12B2 CWSPEN30.2 1
Vanadium (V)3.36 ug/L SW 6020B 10/18/2016 03:12 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 7 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029749
Collection Date:10-Oct-16 1:50 PM
Site:MW-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 9056A 10/11/2016 12:45B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 12:45 BGN90340.1 1
Nitrate 2.7 mg/L EPA 9056A 10/11/2016 12:45 BGN90340.1 1
Nitrate as N 0.60 mg-N/L EPA 9056A 10/11/2016 12:45 BGN90340.023 1
Sulfate 0.15 mg/L EPA 9056A 10/11/2016 12:45 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/18/2016 11:52 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 10:30 MHH71310.05 1
Calcium (Ca)1.60 mg/L SW 6010D 10/19/2016 10:30B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Copper (Cu)0.094 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Iron (Fe)0.658 mg/L SW 6010D 10/19/2016 10:30 MHH71310.01 1
Magnesium (Mg)0.670 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Manganese (Mn)0.017 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Potassium (K)2.64 mg/L SW 6010D 10/19/2016 10:30 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
Sodium (Na)3.72 mg/L SW 6010D 10/19/2016 10:30 MHH71310.05 1
Zinc (Zn)0.059 mg/L SW 6010D 10/19/2016 10:30 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Lead (Pb)8.74 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:23B2 CWSPEN30.2 1
Vanadium (V)1.32 ug/L SW 6020B 10/18/2016 04:23 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 53 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 8 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029750
Collection Date:10-Oct-16 12:50 PM
Site:MW-6
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 6.8 mg/L EPA 9056A 10/11/2016 13:01B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 13:01 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 10/11/2016 13:01 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 10/11/2016 13:01 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 10/11/2016 13:01 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/18/2016 12:24 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.052 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 10:34 MHH71310.05 1
Calcium (Ca)4.00 mg/L SW 6010D 10/19/2016 10:34B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Iron (Fe)0.038 mg/L SW 6010D 10/19/2016 10:34 MHH71310.01 1
Magnesium (Mg)0.696 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Potassium (K)0.771 mg/L SW 6010D 10/19/2016 10:34 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
Sodium (Na)7.38 mg/L SW 6010D 10/19/2016 10:34 MHH71310.05 1
Zinc (Zn)0.244 mg/L SW 6010D 10/19/2016 10:34 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:30B2 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/18/2016 04:30 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 59 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 9 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029751
Collection Date:10-Oct-16 8:45 AM
Site:MW-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)9.7 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 8.3 mg/L EPA 9056A 10/11/2016 15:08B2 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 10/11/2016 15:08 BGN90340.5 5
Nitrate 13 mg/L EPA 9056A 10/11/2016 15:08 BGN90340.5 5
Nitrate as N 3.0 mg-N/L EPA 9056A 10/11/2016 15:08 BGN90340.023 1
Sulfate 150 mg/L EPA 9056A 10/11/2016 15:08 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:09 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Boron (B)2.56 mg/L SW 6010D 10/19/2016 10:38 MHH71310.05 1
Calcium (Ca)31.1 mg/L SW 6010D 10/19/2016 10:38B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Iron (Fe)1.30 mg/L SW 6010D 10/19/2016 10:38 MHH71310.01 1
Magnesium (Mg)14.7 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Manganese (Mn)0.031 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Potassium (K)2.92 mg/L SW 6010D 10/19/2016 10:38 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
Sodium (Na)17.2 mg/L SW 6010D 10/19/2016 10:38 MHH71310.05 1
Zinc (Zn)0.011 mg/L SW 6010D 10/19/2016 10:38 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Selenium (Se)21.6 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:37B2 CWSPEN30.2 1
Vanadium (V)1.59 ug/L SW 6020B 10/18/2016 04:37 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 410 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 10 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029752
Collection Date:10-Oct-16 10:10 AM
Site:MW2-7
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 9056A 10/11/2016 15:24B2 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 10/11/2016 15:24 BGN90342.5 25
Nitrate 160 mg/L EPA 9056A 10/11/2016 15:24 BGN90342.5 25
Nitrate as N 37 mg-N/L EPA 9056A 10/11/2016 15:24 BGN90340.023 1
Sulfate 1200 mg/L EPA 9056A 10/11/2016 15:24 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.10 ug/L EPA 7470A 10/18/2016 12:31 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.027 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Boron (B)20.8 mg/L SW 6010D 10/19/2016 10:42 MHH71310.5 10
Calcium (Ca)231 mg/L SW 6010D 10/19/2016 10:42B1 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Iron (Fe)0.044 mg/L SW 6010D 10/19/2016 10:42 MHH71310.01 1
Magnesium (Mg)114 mg/L SW 6010D 10/19/2016 10:42 MHH71310.05 10
Manganese (Mn)0.426 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Nickel (Ni)0.011 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Potassium (K)3.77 mg/L SW 6010D 10/19/2016 10:42 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
Sodium (Na)69.4 mg/L SW 6010D 10/19/2016 10:42 MHH71310.05 1
Zinc (Zn)0.017 mg/L SW 6010D 10/19/2016 10:42 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Selenium (Se)171 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:44B2 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/18/2016 04:44 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1700 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 11 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029753
Collection Date:10-Oct-16 2:10 PM
Site:MW2-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)38 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride 6.4 mg/L EPA 9056A 10/11/2016 14:36B2 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 10/11/2016 14:36 BGN90340.1 1
Nitrate 8.5 mg/L EPA 9056A 10/11/2016 14:36 BGN90340.1 1
Nitrate as N 1.9 mg-N/L EPA 9056A 10/11/2016 14:36 BGN90340.023 1
Sulfate 42 mg/L EPA 9056A 10/11/2016 14:36 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:12 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.060 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Boron (B)0.625 mg/L SW 6010D 10/19/2016 10:46 MHH71310.05 1
Calcium (Ca)22.9 mg/L SW 6010D 10/19/2016 10:46B1 MHH71310.01 1
Chromium (Cr)0.007 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Iron (Fe)1.12 mg/L SW 6010D 10/19/2016 10:46 MHH71310.01 1
Magnesium (Mg)9.62 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Manganese (Mn)0.331 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Nickel (Ni)0.008 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Potassium (K)5.30 mg/L SW 6010D 10/19/2016 10:46 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
Sodium (Na)14.6 mg/L SW 6010D 10/19/2016 10:46 MHH71310.05 1
Zinc (Zn)0.006 mg/L SW 6010D 10/19/2016 10:46 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Cobalt (Co)1.08 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 04:51B2 CWSPEN30.2 1
Vanadium (V)1.45 ug/L SW 6020B 10/18/2016 04:51 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 10/14/2016 14:55 HGRUVER311
Duke Energy Analytical Lab
Page 12 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029754
Collection Date:10-Oct-16 11:10 AM
Site:OB-4
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)230 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride 6.7 mg/L EPA 9056A 10/11/2016 19:23B2 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 10/11/2016 19:23 BGN90342.5 25
Nitrate < 2.5 mg/L EPA 9056A 10/11/2016 19:23 BGN90342.5 25
Nitrate as N 0.40 mg-N/L EPA 9056A 10/11/2016 19:23 BGN90340.023 1
Sulfate 1500 mg/L EPA 9056A 10/11/2016 19:23 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:24 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Boron (B)16.1 mg/L SW 6010D 10/19/2016 10:50 MHH71310.05 1
Calcium (Ca)599 mg/L SW 6010D 10/19/2016 10:50B1 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Iron (Fe)0.228 mg/L SW 6010D 10/19/2016 10:50 MHH71310.01 1
Magnesium (Mg)41.2 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Manganese (Mn)0.814 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Potassium (K)44.0 mg/L SW 6010D 10/19/2016 10:50 MHH7131110
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
Sodium (Na)13.5 mg/L SW 6010D 10/19/2016 10:50 MHH71310.05 1
Zinc (Zn)0.073 mg/L SW 6010D 10/19/2016 10:50 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)19.5 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Arsenic (As)27.2 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Cobalt (Co)1.88 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Selenium (Se)75.7 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
Thallium (Tl) Low Level 8.55 ug/L SW 6020B 10/18/2016 04:58B2 CWSPEN30.2 1
Vanadium (V)164 ug/L SW 6020B 10/18/2016 04:58 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 2400 mg/L SM2540C 10/14/2016 14:55 HGRUVER331
Duke Energy Analytical Lab
Page 13 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029755
Collection Date:10-Oct-16 8:00 AM
Site:OB-5
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.7 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.0 mg/L EPA 9056A 10/11/2016 17:31B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 17:31 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 10/11/2016 17:31 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 10/11/2016 17:31 BGN90340.023 1
Sulfate 0.15 mg/L EPA 9056A 10/11/2016 17:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:26 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.106 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 11:02 MHH71310.05 1
Calcium (Ca)0.915 mg/L SW 6010D 10/19/2016 11:02B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Iron (Fe)0.189 mg/L SW 6010D 10/19/2016 11:02 MHH71310.01 1
Magnesium (Mg)0.501 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Manganese (Mn)0.011 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Potassium (K)2.64 mg/L SW 6010D 10/19/2016 11:02 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
Sodium (Na)1.74 mg/L SW 6010D 10/19/2016 11:02 MHH71310.05 1
Zinc (Zn)0.008 mg/L SW 6010D 10/19/2016 11:02 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/18/2016 05:05B2 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/18/2016 05:05 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 42 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 14 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029756
Collection Date:10-Oct-16 12:15 PM
Site:OB-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)7.9 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 9056A 10/11/2016 19:38B2 BGN9034220
Fluoride < 2 mg/L EPA 9056A 10/11/2016 19:38 BGN9034220
Nitrate 21 mg/L EPA 9056A 10/11/2016 19:38 BGN9034220
Nitrate as N 4.7 mg-N/L EPA 9056A 10/11/2016 19:38 BGN90340.023 1
Sulfate 1100 mg/L EPA 9056A 10/11/2016 19:38 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.09 ug/L EPA 7470A 10/19/2016 15:28 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.013 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Boron (B)25.8 mg/L SW 6010D 10/19/2016 11:06 MHH71310.5 10
Calcium (Ca)196 mg/L SW 6010D 10/19/2016 11:06B1 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 10/19/2016 11:06 MHH71310.01 1
Magnesium (Mg)84.8 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Manganese (Mn)1.86 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Nickel (Ni)0.009 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Potassium (K)7.39 mg/L SW 6010D 10/19/2016 11:06 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
Sodium (Na)96.7 mg/L SW 6010D 10/19/2016 11:06 MHH71310.05 1
Zinc (Zn)0.135 mg/L SW 6010D 10/19/2016 11:06 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Cadmium (Cd)2.55 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Selenium (Se)278 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/24/2016 17:57 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/24/2016 17:57 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 15 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029757
Collection Date:10-Oct-16 9:20 AM
Site:SW-1A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)45 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 9056A 10/11/2016 19:54B2 BGN9034110
Fluoride < 1 mg/L EPA 9056A 10/11/2016 19:54 BGN9034110
Nitrate 85 mg/L EPA 9056A 10/11/2016 19:54 BGN9034110
Nitrate as N 19 mg-N/L EPA 9056A 10/11/2016 19:54 BGN90340.023 1
Sulfate 800 mg/L EPA 9056A 10/11/2016 19:54 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:31 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.067 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Boron (B)15.0 mg/L SW 6010D 10/19/2016 11:10 MHH71310.05 1
Calcium (Ca)196 mg/L SW 6010D 10/19/2016 11:10B1 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Iron (Fe)0.054 mg/L SW 6010D 10/19/2016 11:10 MHH71310.01 1
Magnesium (Mg)85.6 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Manganese (Mn)0.477 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Potassium (K)6.37 mg/L SW 6010D 10/19/2016 11:10 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
Sodium (Na)48.9 mg/L SW 6010D 10/19/2016 11:10 MHH71310.05 1
Zinc (Zn)0.009 mg/L SW 6010D 10/19/2016 11:10 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Selenium (Se)92.6 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/24/2016 18:04 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/24/2016 18:04 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 16 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029758
Collection Date:10-Oct-16 11:40 AM
Site:SW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)12 mg/L
(CaCO3)
SM 2320B 10/19/2016 13:21 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.9 mg/L EPA 9056A 10/11/2016 19:07B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 19:07 BGN90340.1 1
Nitrate 1.8 mg/L EPA 9056A 10/11/2016 19:07 BGN90340.1 1
Nitrate as N 0.41 mg-N/L EPA 9056A 10/11/2016 19:07 BGN90340.023 1
Sulfate 35 mg/L EPA 9056A 10/11/2016 19:07 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:14 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Boron (B)0.951 mg/L SW 6010D 10/19/2016 11:14 MHH71310.05 1
Calcium (Ca)6.19 mg/L SW 6010D 10/19/2016 11:14B1 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Iron (Fe)0.532 mg/L SW 6010D 10/19/2016 11:14 MHH71310.01 1
Magnesium (Mg)4.33 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Manganese (Mn)0.029 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Potassium (K)1.96 mg/L SW 6010D 10/19/2016 11:14 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
Sodium (Na)10.3 mg/L SW 6010D 10/19/2016 11:14 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 10/19/2016 11:14 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Selenium (Se)5.66 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/24/2016 18:11 CWSPEN30.2 1
Vanadium (V)1.09 ug/L SW 6020B 10/24/2016 18:11 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 10/14/2016 14:55 HGRUVER251
Duke Energy Analytical Lab
Page 17 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
2016029759
Collection Date:10-Oct-16 2:35 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 10/19/2016 07:54 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 10/11/2016 10:53B2 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 10/11/2016 10:53 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 10/11/2016 10:53 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 10/11/2016 10:53 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 10/11/2016 10:53 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/19/2016 15:33 LSTARL10.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Beryllium (Be)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/19/2016 11:18 MHH71310.05 1
Calcium (Ca)0.028 mg/L SW 6010D 10/19/2016 11:18B MHH71310.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 10/19/2016 11:18 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 10/19/2016 11:18 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 10/19/2016 11:18 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 10/19/2016 11:18 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Arsenic (As)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Cobalt (Co)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L SW 6020B 10/24/2016 18:18 CWSPEN30.2 1
Vanadium (V)< 1 ug/L SW 6020B 10/24/2016 18:18 CWSPEN311
Duke Energy Analytical Lab
Page 18 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Qualifiers:
B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to contamination.
B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte
concentration in sample is not affected by contamination.
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab
Page 19 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100437 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 75.7 96.4mg/L (CaCO3)-12080173
Duke Energy Analytical Lab
Page 20 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100475 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090359 -- 2016029744
Alkalinity (mg/L CaCO3)63.2mg/L (CaCO3)-10.648
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 7.57 81.7mg/L (CaCO3)-1208016.19
Duke Energy Analytical Lab
Page 21 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100254 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0555 mg/L -10.0555 0.1 > 1/2 RDL
Fluoride 0.0329 mg/L -10.0329 0.1 < 1/2 RDL
Nitrate 0.0205 mg/L -10.0205 0.1 < 1/2 RDL
Sulfate -0.0008 mg/L -1-0.0008 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 4.98 5 98.9mg/L -1208014.98
Fluoride 4.86 5 96.6mg/L -1208014.86
Nitrate 4.9 5 97.5mg/L -1208014.9
Sulfate 7.72 5 93.7mg/L -1208017.72
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 4.97 5 98.7 0.188mg/L -1208014.97
Fluoride 4.86 5 96.5 0.0456mg/L -1208014.86
Nitrate 4.89 5 97.3 0.17mg/L -1208014.89
Sulfate 7.72 5 93.5 0.137mg/L -1208017.72
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 4.89 5 97.8mg/L -1208014.89
Fluoride 5.14 5 103mg/L -1208015.14
Nitrate 4.89 5 97.8mg/L -1208014.89
Sulfate 4.89 5 97.9mg/L -1208014.89
Duke Energy Analytical Lab
Page 22 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100422 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.005 ug/L -1-0.005 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.01 1 101ug/L -1257511.01
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.02 1 101 0.496ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.08 2 104ug/L -1158512.08
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029745
Mercury (Hg) 0.988 1 99.6ug/L -1257510.988
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029745
Mercury (Hg) 0.974 1 98.2 1.42ug/L -1257510.974
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029750
Mercury (Hg) 0.952 1 95.7ug/L -1257510.952
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029750
Mercury (Hg) 0.975 1 98 2.37ug/L -1257510.975
Duke Energy Analytical Lab
Page 23 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100465 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.012 ug/L -1-0.012 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 98ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029758
Mercury (Hg) 0.843 1 85.6ug/L -1257510.843
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029758
Mercury (Hg) 0.838 1 85.1 0.586ug/L -1257510.838
Duke Energy Analytical Lab
Page 24 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100262 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.000383 mg/L -10.000383 0.005 < 1/2 RDL
Beryllium (Be) 0.000456 mg/L -10.000456 0.005 < 1/2 RDL
Boron (B) -0.00553 mg/L -1-0.00553 0.05 < 1/2 RDL
Calcium (Ca) 0.0132 mg/L -10.0132 0.01 > RDL
Chromium (Cr) 0.000378 mg/L -10.000378 0.005 < 1/2 RDL
Copper (Cu) 0.000781 mg/L -10.000781 0.005 < 1/2 RDL
Iron (Fe) 0.00177 mg/L -10.00177 0.01 < 1/2 RDL
Magnesium (Mg) 0.00287 mg/L -10.00287 0.005 > 1/2 RDL
Manganese (Mn) 0.000308 mg/L -10.000308 0.005 < 1/2 RDL
Nickel (Ni) 0.000114 mg/L -10.000114 0.005 < 1/2 RDL
Potassium (K) 0.0178 mg/L -10.0178 0.1 < 1/2 RDL
Silver (Ag) -0.000051 mg/L -1-0.000051 0.005 < 1/2 RDL
Sodium (Na) 0.00299 mg/L -10.00299 0.05 < 1/2 RDL
Zinc (Zn) 0.00131 mg/L -10.00131 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.1 5 102mg/L -1208015.1
Beryllium (Be) 5.03 5 101mg/L -1208015.03
Boron (B) 5.04 5 101mg/L -1208015.04
Calcium (Ca) 5.17 5 103mg/L -1208015.17
Chromium (Cr) 5.05 5 101mg/L -1208015.05
Copper (Cu) 5.01 5 100mg/L -1208015.01
Iron (Fe) 5.2 5 104mg/L -1208015.2
Magnesium (Mg) 5.15 5 103mg/L -1208015.15
Manganese (Mn) 5.12 5 102mg/L -1208015.12
Nickel (Ni) 5.1 5 102mg/L -1208015.1
Potassium (K) 5.08 5 102mg/L -1208015.08
Silver (Ag) 0.484 0.5 96.9mg/L -1208010.484
Sodium (Na) 5.06 5 101mg/L -1208015.06
Zinc (Zn) 5.16 5 103mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029745
Barium (Ba) 5.03 5 101mg/L -1257515.03
Beryllium (Be) 4.96 5 99.1mg/L -1257514.96
Boron (B) 4.97 5 99.3mg/L -1257514.97
Calcium (Ca) 11.1 5 98mg/L -12575111.1
Chromium (Cr) 4.98 5 99.6mg/L -1257514.98
Copper (Cu) 4.9 5 98mg/L -1257514.9
Duke Energy Analytical Lab
Page 25 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100262 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029745
Iron (Fe) 5.15 5 103mg/L -1257515.15
Magnesium (Mg) 10.3 5 98.6mg/L -12575110.3
Manganese (Mn) 5.05 5 101mg/L -1257515.05
Nickel (Ni) 4.99 5 99.8mg/L -1257514.99
Potassium (K) 6.85 5 99.5mg/L -1257516.85
Silver (Ag) 0.476 0.5 94.9mg/L -1257510.476
Sodium (Na) 14 5 95.8mg/L -12575114
Zinc (Zn) 5.07 5 101mg/L -1257515.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029745
Barium (Ba) 5.13 5 103 2.03mg/L -1257515.13
Beryllium (Be) 5.04 5 101 1.68mg/L -1257515.04
Boron (B) 5.04 5 101 1.54mg/L -1257515.04
Calcium (Ca) 11.3 5 102 4.29mg/L -12575111.3
Chromium (Cr) 5.06 5 101 1.49mg/L -1257515.06
Copper (Cu) 4.97 5 99.5 1.52mg/L -1257514.97
Iron (Fe) 5.23 5 104 1.45mg/L -1257515.23
Magnesium (Mg) 10.4 5 101 2.5mg/L -12575110.4
Manganese (Mn) 5.14 5 103 1.88mg/L -1257515.14
Nickel (Ni) 5.07 5 101 1.61mg/L -1257515.07
Potassium (K) 6.95 5 102 2.01mg/L -1257516.95
Silver (Ag) 0.484 0.5 96.3 1.53mg/L -1257510.484
Sodium (Na) 14.3 5 101 5.23mg/L -12575114.3
Zinc (Zn) 5.14 5 103 1.33mg/L -1257515.14
Duke Energy Analytical Lab
Page 26 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100270 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.009 ug/L -1-0.009 1 < 1/2 RDL
Arsenic (As) 0.01 ug/L -10.01 1 < 1/2 RDL
Cadmium (Cd) 0.003 ug/L -10.003 1 < 1/2 RDL
Cobalt (Co) 0.001 ug/L -10.001 1 < 1/2 RDL
Lead (Pb) 0 ug/L -10 1 < 1/2 RDL
Selenium (Se) -0.003 ug/L -1-0.003 1 < 1/2 RDL
Thallium (Tl) Low Level -0.026 ug/L -1-0.026 0.2 < 1/2 RDL
Vanadium (V) 0.054 ug/L -10.054 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.3 50 101ug/L -12080150.3
Arsenic (As) 51.3 50 103ug/L -12080151.3
Cadmium (Cd) 51.3 50 103ug/L -12080151.3
Cobalt (Co) 51.2 50 102ug/L -12080151.2
Lead (Pb) 50.8 50 102ug/L -12080150.8
Selenium (Se) 46.1 50 92.3ug/L -12080146.1
Thallium (Tl) Low Level 44.9 50 89.8ug/L -12080144.9
Vanadium (V) 50.3 50 101ug/L -12080150.3
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029748
Antimony (Sb) 50.3 50 99.9ug/L -12575150.3
Arsenic (As) 50.5 50 101ug/L -12575150.5
Cadmium (Cd) 51.6 50 103ug/L -12575151.6
Cobalt (Co) 50.4 50 100ug/L -12575150.4
Lead (Pb) 50.7 50 101ug/L -12575150.7
Selenium (Se) 63.5 50 95.5ug/L -12575163.5
Thallium (Tl) Low Level 46.4 50 92.6ug/L -12575146.4
Vanadium (V) 53.4 50 100ug/L -12575153.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029748
Antimony (Sb) 50.1 50 99.5 0.443ug/L -12575150.1
Arsenic (As) 50.8 50 101 0.601ug/L -12575150.8
Cadmium (Cd) 51.6 50 103 0.0485ug/L -12575151.6
Cobalt (Co) 50.6 50 101 0.383ug/L -12575150.6
Lead (Pb) 50.5 50 101 0.269ug/L -12575150.5
Selenium (Se) 63.3 50 95.1 0.394ug/L -12575163.3
Thallium (Tl) Low Level 47.2 50 94.3 1.89ug/L -12575147.2
Duke Energy Analytical Lab
Page 27 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100270 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090359 -- 2016029748
Vanadium (V) 53.8 50 101 0.727ug/L -12575153.8
Duke Energy Analytical Lab
Page 28 of 30
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090359
Q16100347 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090359 -- 2016029744
TDS 4.26mg/L -124
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16090359 -- 2016029745
TDS 3.17mg/L -196
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 107mg/L -110901107
Duke Energy Analytical Lab
Page 29 of 30
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