Loading...
HomeMy WebLinkAbout6801_OrangeCoMSWLF_2ndSemiGWMReport_DIN26933_20160209 Prepared for: Prepared for: Prepared by: February, 2016 DAA No. R00592-163 ORANGE COUNTY SOLID WASTE MANAGEMENT (NORTH FACILITY) GROUNDWATER MONITORING PROGRAM PERMIT NUMBER 68-01 SAMPLING EVENT 44: 11-10-15 + 11-11-15 RESULTS OF SAMPLING AND ANALYSIS ORANGE COUNTY SOLID WASTE MANAGEMENT P.O. Box 17177 Chapel Hill, North Carolina 27516 Draper Aden Associates Engineering  Surveying  Environmental Services 8090 Villa Park Drive Richmond, Virginia 23228 FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER DILUTION FACTOR COLLECTION DATE EXTRACTION DATE ANALYSIS DATE REGULATORY PROTECTION STANDARD SOURCE ANALYSIS* 68-01 6801-MW14A 75-34-3 75 1,1-Dichloroethane 4.0 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW16 75-34-3 75 1,1-Dichloroethane 2.3 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14B 75-34-3 75 1,1-Dichloroethane 5.9 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW15 75-34-3 75 1,1-Dichloroethane 6.3 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW21D 75-34-3 75 1,1-Dichloroethane 9.2 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW21S 75-34-3 75 1,1-Dichloroethane 8.2 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW22 75-34-3 75 1,1-Dichloroethane 6.4 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW23 75-34-3 75 1,1-Dichloroethane 15 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW24 75-34-3 75 1,1-Dichloroethane 10 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill 68-01 6801-MW23 75-35-4 77 1,1-Dichloroethene 0.57 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 350 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW15 95-50-1 69 1,2-Dichlorobenzene 0.64 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 20 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14B 78-87-5 82 1,2-Dichloropropane 0.58 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW15 78-87-5 82 1,2-Dichloropropane 0.57 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW23 78-87-5 82 1,2-Dichloropropane 0.51 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW16 106-46-7 71 1,4-Dichlorobenzene 0.67 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW21S 106-46-7 71 1,4-Dichlorobenzene 0.51 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14A 106-46-7 71 1,4-Dichlorobenzene 1.4 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW14B 106-46-7 71 1,4-Dichlorobenzene 1.1 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW15 106-46-7 71 1,4-Dichlorobenzene 7.1 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW20 106-46-7 71 1,4-Dichlorobenzene 6.7 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW21D 106-46-7 71 1,4-Dichlorobenzene 2.4 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW22 106-46-7 71 1,4-Dichlorobenzene 2.3 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW23 106-46-7 71 1,4-Dichlorobenzene 4.1 ug/L 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; >FBAC 68-01 6801-MW04 7440-36-0 13 Antimony Total 0.237 ug/L J 1 11/10/2015 11/12/2015 11/16/2015 1 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7440-36-0 13 Antimony Total 1.05 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 1 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-MW07R 7440-36-0 13 Antimony Total 0.548 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 1 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 7440-36-0 13 Antimony Total 0.303 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 1 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7440-38-2 14 Arsenic Total 8.45 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW22 7440-38-2 14 Arsenic Total 9.62 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW23 7440-38-2 14 Arsenic Total 8.07 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW24 7440-38-2 14 Arsenic Total 7.41 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW07R 7440-38-2 14 Arsenic Total 10.5 ug/L 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW14A 7440-38-2 14 Arsenic Total 10.2 ug/L 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW14B 7440-38-2 14 Arsenic Total 15.5 ug/L 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW04 7440-39-3 15 Barium Total 65.5 ug/L J 1 11/10/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7440-39-3 15 Barium Total 15.0 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW07R 7440-39-3 15 Barium Total 4.93 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 7440-39-3 15 Barium Total 99.3 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW17 7440-39-3 15 Barium Total 25.8 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21D 7440-39-3 15 Barium Total 2.86 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21S 7440-39-3 15 Barium Total 1.93 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW22 7440-39-3 15 Barium Total 55.4 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW23 7440-39-3 15 Barium Total 5.37 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW24 7440-39-3 15 Barium Total 6.96 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-SW1 7440-39-3 15 Barium Total 38.6 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-SW2 7440-39-3 15 Barium Total 47.2 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 700 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14B 7440-39-3 15 Barium Total 261 ug/L 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; concentration less than FBAC (500 ug/l) 68-01 6801-MW15 7440-39-3 15 Barium Total 123 ug/L 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; concentration less than FBAC (500 ug/l) 68-01 6801-MW16 7440-39-3 15 Barium Total 172 ug/L 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; concentration less than FBAC (500 ug/l) 68-01 6801-MW20 7440-39-3 15 Barium Total 159 ug/L 1 11/11/2015 11/16/2015 11/19/2015 700 2L Naturally occurring; concentration less than FBAC (500 ug/l) 68-01 6801-MW16 71-43-2 16 Benzene 0.44 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 1 2L Impact from landfill 68-01 6801-MW23 71-43-2 16 Benzene 0.40 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 1 2L Impact from landfill 68-01 6801-MW14B 71-43-2 16 Benzene 1.2 ug/L 1 11/11/2015 11/21/2015 11/21/2015 1 2L Impact from landfill 68-01 6801-MW15 71-43-2 16 Benzene 1.2 ug/L 1 11/11/2015 11/21/2015 11/21/2015 1 2L Impact from landfill 68-01 6801-MW20 71-43-2 16 Benzene 5.0 ug/L 1 11/11/2015 11/21/2015 11/21/2015 1 2L Impact from landfill GROUNDWATER CONSTITUENTS ATTAINING OR EXCEEDING THEIR GROUNDWATER QUALITY STANDARDS CLIENT: THE COUNTY OF ORANGE FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM DATES OF SAMPLING: 11-10-15 + 11-11-15 FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER DILUTION FACTOR COLLECTION DATE EXTRACTION DATE ANALYSIS DATE REGULATORY PROTECTION STANDARD SOURCE ANALYSIS* GROUNDWATER CONSTITUENTS ATTAINING OR EXCEEDING THEIR GROUNDWATER QUALITY STANDARDS CLIENT: THE COUNTY OF ORANGE FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM DATES OF SAMPLING: 11-10-15 + 11-11-15 68-01 6801-MW04 7440-43-9 34 Cadmium Total 0.433 ug/L J 1 11/10/2015 11/16/2015 11/19/2015 2 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7440-43-9 34 Cadmium Total 0.594 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 2 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW24 7440-43-9 34 Cadmium Total 0.390 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 2 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21D 124-38-9 413 Carbon dioxide 300000 ug/L D 5 11/11/2015 11/16/2015 11/16/2015 N/A N/A natural attenuation indicator 68-01 6801-MW23 124-38-9 413 Carbon dioxide 170000 ug/L D 5 11/11/2015 11/16/2015 11/16/2015 N/A N/A natural attenuation indicator 68-01 6801-MW21S 124-38-9 413 Carbon dioxide 168000 ug/L 1 11/11/2015 11/16/2015 11/16/2015 N/A N/A natural attenuation indicator 68-01 6801-MW24 124-38-9 413 Carbon dioxide 84000 ug/L 1 11/11/2015 11/16/2015 11/16/2015 N/A N/A natural attenuation indicator 68-01 6801-MW04 SW301 301 Chloride 5900 ug/L 1 11/10/2015 11/16/2015 11/16/2015 250000 2L natural attenuation indicator 68-01 6801-MW21D SW301 301 Chloride 70000 ug/L 1 11/11/2015 11/20/2015 11/20/2015 250000 2L natural attenuation indicator 68-01 6801-MW21S SW301 301 Chloride 63000 ug/L 1 11/11/2015 11/20/2015 11/20/2015 250000 2L natural attenuation indicator 68-01 6801-MW23 SW301 301 Chloride 130000 ug/L 1 11/11/2015 11/20/2015 11/20/2015 250000 2L natural attenuation indicator 68-01 6801-MW24 SW301 301 Chloride 74000 ug/L 1 11/11/2015 11/20/2015 11/20/2015 250000 2L natural attenuation indicator 68-01 6801-MW14A 108-90-7 39 Chlorobenzene 0.84 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14B 108-90-7 39 Chlorobenzene 2.2 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW16 108-90-7 39 Chlorobenzene 0.47 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW20 108-90-7 39 Chlorobenzene 1.2 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW21D 108-90-7 39 Chlorobenzene 1.3 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW22 108-90-7 39 Chlorobenzene 2.6 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW15 108-90-7 39 Chlorobenzene 5.9 ug/L 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; >FBAC 68-01 6801-MW23 108-90-7 39 Chlorobenzene 3.1 ug/L 1 11/11/2015 11/21/2015 11/21/2015 50 2L Impact from landfill; >FBAC 68-01 6801-MW14B 75-00-3 41 Chloroethane 0.88 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3000 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW15 75-00-3 41 Chloroethane 1.6 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3000 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW21D 75-00-3 41 Chloroethane 0.74 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3000 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW23 75-00-3 41 Chloroethane 0.99 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3000 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14A 7440-47-3 51 Chromium Total 3.13 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW15 7440-47-3 51 Chromium Total 3.41 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21D 7440-47-3 51 Chromium Total 7.84 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW24 7440-47-3 51 Chromium Total 3.83 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21S 7440-47-3 51 Chromium Total 94.1 ug/L 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW23 7440-47-3 51 Chromium Total 57.7 ug/L 1 11/11/2015 11/16/2015 11/19/2015 10 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 156-59-2 78 cis-1,2-Dichloroethene 3.0 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14B 156-59-2 78 cis-1,2-Dichloroethene 2.2 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW16 156-59-2 78 cis-1,2-Dichloroethene 1.9 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW22 156-59-2 78 cis-1,2-Dichloroethene 4.9 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW15 156-59-2 78 cis-1,2-Dichloroethene 97 ug/L 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill 68-01 6801-MW21D 156-59-2 78 cis-1,2-Dichloroethene 26 ug/L 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; >FBAC 68-01 6801-MW21S 156-59-2 78 cis-1,2-Dichloroethene 17 ug/L 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; >FBAC 68-01 6801-MW23 156-59-2 78 cis-1,2-Dichloroethene 70 ug/L 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; >FBAC 68-01 6801-MW24 156-59-2 78 cis-1,2-Dichloroethene 17 ug/L 1 11/11/2015 11/21/2015 11/21/2015 70 2L Impact from landfill; >FBAC 68-01 6801-MW06R 7440-48-4 53 Cobalt Total 3.26 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW16 7440-48-4 53 Cobalt Total 3.17 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW17 7440-48-4 53 Cobalt Total 3.61 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-SW1 7440-48-4 53 Cobalt Total 1.63 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW14A 7440-48-4 53 Cobalt Total 43.9 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW14B 7440-48-4 53 Cobalt Total 30.8 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW15 7440-48-4 53 Cobalt Total 27.3 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW20 7440-48-4 53 Cobalt Total 15.7 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1 GWPS Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-SW1 7440-50-8 54 Copper Total 1.76 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 7440-50-8 54 Copper Total 13.9 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW04 7439-89-6 340 Iron Total 151 ug/L J 1 11/10/2015 11/16/2015 11/19/2015 300 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7439-92-1 131 Lead Total 3.74 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 15 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW14B 7439-92-1 131 Lead Total 3.44 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 15 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW20 7439-92-1 131 Lead Total 7.42 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 15 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-SW2 7439-92-1 131 Lead Total 3.21 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 15 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW24 7439-96-5 342 Manganese Total 92.1 ug/L B 1 11/11/2015 11/16/2015 11/19/2015 50 2L Naturally occurring; byproduct of potassium permanganate breakdown; cross-contamination "B" FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER DILUTION FACTOR COLLECTION DATE EXTRACTION DATE ANALYSIS DATE REGULATORY PROTECTION STANDARD SOURCE ANALYSIS* GROUNDWATER CONSTITUENTS ATTAINING OR EXCEEDING THEIR GROUNDWATER QUALITY STANDARDS CLIENT: THE COUNTY OF ORANGE FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM DATES OF SAMPLING: 11-10-15 + 11-11-15 68-01 6801-MW21D 7439-96-5 342 Manganese Total 13.7 ug/L BJ 1 11/11/2015 11/16/2015 11/19/2015 50 2L Naturally occurring; byproduct of potassium permanganate breakdown; does not exceed SWSL 68-01 6801-MW21S 7439-96-5 342 Manganese Total 21.7 ug/L BJ 1 11/11/2015 11/16/2015 11/19/2015 50 2L Naturally occurring; byproduct of potassium permanganate breakdown; does not exceed SWSL 68-01 6801-MW23 7439-96-5 342 Manganese Total 40.5 ug/L BJ 1 11/11/2015 11/16/2015 11/19/2015 50 2L Naturally occurring; byproduct of potassium permanganate breakdown; does not exceed SWSL 68-01 6801-MW04 7439-96-5 342 Manganese Total 4.52 ug/L BJ 1 11/10/2015 11/16/2015 11/19/2015 50 2L Naturally occurring; byproduct of potassium permanganate breakdown; does not exceed SWSL 68-01 6801-MW21D 7439-97-6 132 Mercury Total 1.32 ug/L 1 11/11/2015 11/16/2015 11/17/2015 1 2L Possible landfill impact; naturally occurring; >FBAC 68-01 6801-MW21S 7439-97-6 132 Mercury Total 2.21 ug/L 1 11/11/2015 11/16/2015 11/17/2015 1 2L Possible landfill impact; naturally occurring; >FBAC 68-01 6801-MW23 7439-97-6 132 Mercury Total 3.67 ug/L 1 11/11/2015 11/16/2015 11/17/2015 1 2L Possible landfill impact; naturally occurring; >FBAC 68-01 6801-MW20 91-20-3 148 Naphthalene 3.2 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 6 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW07R 7440-02-0 152 Nickel Total 3.32 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 100 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 7440-02-0 152 Nickel Total 7.04 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 100 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW15 7440-02-0 152 Nickel Total 13.5 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 100 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW16 7440-02-0 152 Nickel Total 2.85 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 100 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21D 9-7-7440 377 Potassium Total 786 ug/L 1 11/11/2015 11/16/2015 11/19/2015 N/A N/A natural attenuation indicator 68-01 6801-MW21S 9-7-7440 377 Potassium Total 762 ug/L 1 11/11/2015 11/16/2015 11/19/2015 N/A N/A natural attenuation indicator 68-01 6801-MW23 9-7-7440 377 Potassium Total 1440 ug/L 1 11/11/2015 11/16/2015 11/19/2015 N/A N/A natural attenuation indicator 68-01 6801-MW24 9-7-7440 377 Potassium Total 1060 ug/L 1 11/11/2015 11/16/2015 11/19/2015 N/A N/A natural attenuation indicator 68-01 6801-MW20 7782-49-2 183 Selenium Total 1.38 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 20 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW21S 7782-49-2 183 Selenium Total 3.58 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 20 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-SW1 7782-49-2 183 Selenium Total 1.74 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 20 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-SW2 7782-49-2 183 Selenium Total 1.45 ug/L J 1 11/11/2015 11/12/2015 11/16/2015 20 2L Naturally occurring; does not exceed SWSL; ASD approved 09-26-11 68-01 6801-MW07R 7440-22-4 184 Silver Total 3.52 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 7440-22-4 184 Silver Total 5.58 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14B 7440-22-4 184 Silver Total 4.38 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW15 7440-22-4 184 Silver Total 5.91 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW17 7440-22-4 184 Silver Total 3.85 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW20 7440-22-4 184 Silver Total 3.69 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21D 7440-22-4 184 Silver Total 3.84 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW21S 7440-22-4 184 Silver Total 3.51 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW22 7440-22-4 184 Silver Total 4.29 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW23 7440-22-4 184 Silver Total 3.62 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW24 7440-22-4 184 Silver Total 3.30 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 20 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW14B 18496-25-8 187 Sulfide 10 ug/L J 1 11/11/2015 11/16/2015 11/16/2015 1000 MDL Naturally occurring; does not exceed SWSL 68-01 6801-MW23 127-18-4 192 Tetrachloroethene 0.99 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.7 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW04 SW337 337 Total Alkalinity as CaCO3 21000 ug/L 1 11/10/2015 11/20/2015 11/20/2015 N/A N/A natural attenuation indicator 68-01 6801-MW15 156-60-5 79 trans-1,2-Dichloroethene 0.74 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 100 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW20 156-60-5 79 trans-1,2-Dichloroethene 0.40 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 100 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW23 156-60-5 79 trans-1,2-Dichloroethene 0.60 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 100 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW21D 79-01-6 201 Trichloroethene 0.49 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW23 79-01-6 201 Trichloroethene 0.82 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 3 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW04 7440-62-2 209 Vanadium Total 1.60 ug/L J 1 11/10/2015 11/16/2015 11/19/2015 0.3 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-SW1 7440-62-2 209 Vanadium Total 5.64 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 0.3 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-SW2 7440-62-2 209 Vanadium Total 1.97 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 0.3 GWPS Naturally occurring; does not exceed SWSL 68-01 6801-MW14A 75-01-4 211 Vinyl chloride 0.81 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW16 75-01-4 211 Vinyl chloride 0.93 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW24 75-01-4 211 Vinyl chloride 0.62 ug/L J 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill; does not exceed SWSL 68-01 6801-MW14B 75-01-4 211 Vinyl chloride 6.4 ug/L 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill 68-01 6801-MW15 75-01-4 211 Vinyl chloride 13 ug/L 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill 68-01 6801-MW21D 75-01-4 211 Vinyl chloride 3.0 ug/L 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill 68-01 6801-MW22 75-01-4 211 Vinyl chloride 1.8 ug/L 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill 68-01 6801-MW23 75-01-4 211 Vinyl chloride 4.9 ug/L 1 11/11/2015 11/21/2015 11/21/2015 0.03 2L Impact from landfill 68-01 6801-MW04 7440-66-6 213 Zinc Total 7.09 ug/L J 1 11/10/2015 11/16/2015 11/19/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW15 7440-66-6 213 Zinc Total 4.72 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW20 7440-66-6 213 Zinc Total 6.78 ug/L J 1 11/11/2015 11/16/2015 11/19/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-SW1 7440-66-6 213 Zinc Total 5.94 ug/L J 1 11/11/2015 11/16/2015 11/20/2015 1000 2L Naturally occurring; does not exceed SWSL 68-01 6801-MW06R 7440-66-6 213 Zinc Total 37.4 ug/L 1 11/11/2015 11/16/2015 11/19/2015 1000 2L Naturally occurring FACILITY PERMIT WELL ID CAS Number SWS ID PARAMETER RESULT UNITS QUALIFIER DILUTION FACTOR COLLECTION DATE EXTRACTION DATE ANALYSIS DATE REGULATORY PROTECTION STANDARD SOURCE ANALYSIS* GROUNDWATER CONSTITUENTS ATTAINING OR EXCEEDING THEIR GROUNDWATER QUALITY STANDARDS CLIENT: THE COUNTY OF ORANGE FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM DATES OF SAMPLING: 11-10-15 + 11-11-15 Yellow highlighted well indicates upgradient location B - concentration is <5x constituent concentration detected in associated blank MDL - method detection limit Bold italicized values exceed their respective regulatory protection standard and associated section limit. * Note: These analyses should be interpreted in the context of the groundwater sampling report for this event. J - constituent was less than its Solid Waste Section Limit (SWSL) ATTACHMENTS 1 FIGURES 2 MONITORING WELL NETWORK 3 GROUNDWATER ELEVATION DATA 4 GROUNDWATER VELOCITY CALCULATIONS 5 ORGANIC CONSTITUENTS 6 INORGANIC CONSTITUENTS 7 LABORATORY CERTIFICATE-OF-ANALYSIS 8 FIELD DATA 9 STATISTICAL ANALYSES 10 QUALITY CONTROL ASSESSMENT 11 CORRESPONDENCE ATTACHMENT 1 FIGURES LEGEND N SOURCE: USGS 7.5’ Quadrangle Chapel Hill, NC 2013 Vicinity Topographic Map Client Orange County Solid Waste Management Facility North + South + Active C&D Landfills Location Chapel Hill, North Carolina Project Environmental Monitoring Programs SCALE: DAA NO. [not shown] R00597 DESIGNED DRAWN CHECKED DATE LNF BHH LNF 02-14-14 FIGURE 1A approximate locations of facilities active C&D old C&D North South office LEGEND N SOURCE: Google Earth [image date 04-09-13] Vicinity Aerial Photograph Client Orange County Solid Waste Management Facility North + South + Active C&D Landfills Location Chapel Hill, North Carolina Project Environmental Monitoring Programs SCALE: DAA NO. [not shown] R00597 DESIGNED DRAWN CHECKED DATE LNF BHH LNF 02-13-14 FIGURE 1B approximate locations of facilities old C&D North South active C&D ATTACHMENT 2 MONITORING WELL NETWORK ATTACHMENT 2 GROUNDWATER MONITORING NETWORK The well monitoring network associated with the North sanitary landfill consists of fourteen wells. Upgradient: 6801-MW4 6801-MW6R Downgradient: 6801-MW7R 6801-MW14A 6801-MW14B 6801-MW15 6801-MW16 6801-MW17 6801-MW20 6801-MW21S 6801-MW21D 6801-MW22 6801-MW23 6801-MW24 Note. Well 6801-MW04 is associated with both the C&D landfill and the North sanitary landfill. Note. Well 6801-MW04 is upgradient of the North sanitary landfill waste management unit; well 6801-MW06R is upgradient of the closed C&D landfill waste management unit (which is separated from the sanitary landfill by a stream). NORTH SOUTH ACTIVE Well LANDFILL LANDFILL C&D LANDFILL 6801-MW04 X X 6801-MW06R X 6801-MW07R X 6801-MW14A X 6801-MW14B X 6801-MW15 X 6801-MW16 X 6801-MW17 X 6801-MW20 X 6801-MW21D X 6801-MW21S X 6801-MW22 X 6801-MW23 X 6801-MW24 X 6801-MW101 X 6801-MW102DR X 6801-MW102S X 6801-MW103D X 6801-MW103S X 6801-MW104 X 6801-MW105 X 6801-MW106 X 6801-MW107 X 6801-MW111 X 6801-MW112 X 6801-MW110D X X 6801-MW110S X X 6804-MW204S X 6804-MW209 X 6804-MW210D X 6804-MW211R X 6801-SW1 X 6801-SW2 X 6804-SW1 X leachate X CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: NORTH - SOUTH - C&D LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MONITORING WELL NETWORK SUMMARY total depth depth measured corrected elevation elevation elevation elevation drilling diameter depth to top to top well well ground concrete measuring top steel well type of date drilling method borehole borehole sand bentonite depth stickup depth surface pad point casing designation well completed contractor (in inches)northing easting (in inches)(in feet)(in feet)(in feet)(in feet)(in feet)(in feet)(in feet)(in feet)(in feet)(in feet) 6801-MW1 2MW10 04-29-76 GEC 6" rotary 809703.65 1975572.45 8 36 18 16.3 36 1.80 37.8 504.15 505.95 6801-MW4 1.75MW10 10-31-80 SME 3.25 807250.43 1974944.46 6 53 39 38 53 2.33 55.3 547.66 549.99 6801-MW5 1.75MW10 11-03-80 SME 3.25 808192.87 1974945.72 6 18.1 5 4 18.1 1.75 19.9 522.04 523.79 6801-MW6 1.75MW10 11-05-80 SME 3.25 809820.13 1976569.38 6 28.5 15 14 28.5 1.10 29.6 516.23 517.33 6801-MW6R 2MW10 06-17-08 DDI 6" air rotary 809803.36 1976567.65 6 51 23.5 5 51 2.5 53.5 511.84 514.50 6801-MW7 6801-MW7R 2MW10 05-31-07 RSD 6" air rotary 808806.89 1977111.80 6 20 8 4 20 1.92 21.9 486.79 488.71 6801-MW13 2MW15 03-12-92 ETEC 6.25 + rotary 809459.00 1976157.24 9.25 23 6 4 23 2.96 26 495.18 498.14 6801-MW14A 2MW5 03-12-92 ETEC 6.25 808951.24 1976364.48 9.25 12 6 4 12 2.88 14.9 486.46 489.34 6801-MW14B 2MW14 03-12-92 ETEC 6.25 + rotary 808945.19 1976368.22 8 31.5 16 14 31.5 2.66 34.2 486.30 488.96 6801-MW15 2MW15 03-12-92 ETEC 6.25 + rotary 808376.68 1976958.21 8 28 8 6 28 2.36 30.4 481.29 483.65 6801-MW16 2MW20 06-29-89 EMA air rotary 807986.58 1976739.73 8 35 6.5 5.5 35 2.47 37.5 480.44 482.91 6801-MW17 2MW20 06-30-89 EMA air rotary 807869.32 1976301.73 8 50 22 21 50 2.54 52.5 492.83 495.37 6801-MW18 2MW20 06-23-89 EMA air rotary 807900.44 1975645.97 8 35 6 5 35 35 502.02 6801-MW20 2MW15 09-21-94 ETEC 6" air rotary 807974.11 1975680.42 8 45 28 24 45 3.43 48.4 526.00 529.43 6801-MW21S 2MW10 03-27-00 G & C rotary 808049.25 1977137.08 8 23 11 7 23 2.14 25.1 474.70 476.84 6801-MW21D 2MW10 03-24-00 G & C 4.25 + rotary 808041.46 1977132.91 8 53 41 37 53 1.55 54.6 474.86 476.41 6801-MW22 2MW10 03-25-00 G & C 4.25 + rotary 808915.13 1976521.36 8 63 58 46 63 1.92 64.9 481.56 483.48 6801-MW23 2MW10 05-31-07 RSD 6" air rotary 808277.99 1977098.69 6 30 13 8 30 2.23 32.2 476.62 478.85 6801-MW24 2MW10 06-17-08 DDI 6" air rotary 808212.67 1977145.27 6 36 38 5 36 2.40 38.4 475.45 477.73 Elevations expressed in feet above mean sea level, unless otherwise noted. ELEVmp and ELEVgs are corrected to latest survey data (surveyed May, 1999; wells MW-21S, MW-21D, MW-22 were surveyed June, 2000; wells 6801-MW7R, MW-23 surveyed July, 2007; wells 6801-MW6R and MW-24 surveyed June, 2008) R00592 ABANDONED (05-31-07) WELL CONSTRUCTION DATA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA ATTACHMENT 3 GROUNDWATER ELEVATION DATA ATTACHMENT 3 GROUNDWATER ELEVATION DATA Static water elevations obtained during the subject sampling event indicate that well 6801-MW4 remains hydrogeologically upgradient from all municipal waste disposal units within the North Facility and upgradient from all other wells associated with the North Facility. During the subject sampling event, the elevation of the water table beneath the municipal waste facility was found to vary from a high of 517.67 feet above mean sea level (upgradient monitoring well 6801-MW4) to a low of 473.86 feet above mean sea level (downgradient monitoring well 6801- MW21S). A comparison of static water elevations obtained during the referenced sampling event with those obtained during prior sampling events reveals no hydrogeologically significant changes in directions of groundwater flow. CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM STATIC WATER LEVELS DATE: 11-10-15 + 11-11-15 WELL ELEVmp DTW STICKUP DTWc ELEVgs ELEVgw 6801-MW1 505.95 1.80 504.15 6801-MW4 549.99 32.32 2.33 29.99 547.66 517.67 6801-MW5 523.79 1.75 522.04 6801-MW6 517.33 1.10 516.23 6801-MW6R 514.50 25.54 2.66 22.88 511.84 488.96 6801-MW7 6801-MW7R 488.71 10.30 1.92 8.38 486.79 478.41 6801-MW13 498.14 2.96 495.18 6801-MW14A 489.34 5.34 2.88 2.46 486.46 484.00 6801-MW14B 488.96 5.32 2.66 2.66 486.30 483.64 6801-MW15 483.65 5.95 2.36 3.59 481.29 477.70 6801-MW16 482.91 3.62 2.47 1.15 480.44 479.29 6801-MW17 495.37 9.02 2.54 6.48 492.83 486.35 6801-MW20 529.43 27.95 3.43 24.52 526.00 501.48 6801-MW21S 476.92 3.06 2.22 0.84 474.70 473.86 6801-MW21D 476.44 1.92 1.58 0.34 474.86 474.52 6801-MW22 483.46 2.10 1.90 0.20 481.56 481.36 6801-MW23 478.85 2.73 2.23 0.50 476.62 476.12 6801-MW24 477.73 3.08 2.28 0.80 475.45 474.65 Elevations expressed in feet above mean sea level. Shaded cells indicate data not available R00592 - 163 ABANDONED DATE MW-01 MW-04 MW-05 MW-06 [old CDD]MW-06R [old CDD]MW-07 [old CDD]MW-07R [old CDD]MW-13 MW-14A MW-14B MW-15 MW-16 MW-17 MW-20 MW-21S MW-21D MW-22 [old CDD]MW-23 MW-24 ELEVgs 504.15 547.66 522.04 516.23 511.84 486.84 486.79 495.18 486.46 486.30 481.29 480.44 492.83 526.00 474.70 474.86 481.56 476.62 475.45 ELEVmp 505.95 549.99 523.79 517.33 514.50 489.66 488.71 498.14 489.34 488.96 483.65 482.91 495.37 529.43 476.92 476.44 483.46 478.85 477.73 01/03/90 499.24 521.61 511.79 491.79 482.06 478.45 484.56 04/16/90 500.61 523.57 511.66 493.58 481.24 478.12 484.54 07/17/90 494.12 521.28 506.25 491.37 475.95 475.79 482.27 10/29/90 493.99 516.65 506.29 490.25 479.99 477.91 483.70 01/30/91 495.16 518.32 510.41 491.62 481.17 478.04 485.33 07/11/91 494.12 518.74 506.29 489.83 476.53 476.91 482.95 11/14/91 493.12 515.07 505.37 488.58 475.66 476.66 481.95 05/28/92 494.45 516.82 507.62 491.33 477.00 487.22 482.09 481.79 475.65 476.74 482.70 10/27/92 491.78 514.24 505.71 489.17 475.33 486.48 482.01 481.63 475.15 475.91 481.29 02/23/93 498.62 516.82 512.29 492.50 481.50 488.14 483.21 482.80 476.73 478.25 485.54 06/30/93 494.12 520.07 506.37 492.75 476.99 487.06 481.92 481.38 477.07 476.49 482.70 10/28/93 491.54 516.67 486.83 482.22 481.93 476.33 476.39 481.66 01/24/94 494.72 516.76 509.97 492.76 481.04 487.72 483.09 482.73 478.01 480.77 09/21/94 497.43 11/03/94 492.95 516.84 477.01 487.13 483.06 482.15 477.05 477.23 482.37 495.81 12/20/94 493.80 516.14 505.78 488.44 476.88 487.52 483.30 482.34 477.63 477.58 482.92 497.08 02/02/95 494.32 516.39 505.87 489.13 479.71 487.83 483.02 482.63 478.08 478.49 484.65 497.93 03/13/95 496.10 518.02 511.67 492.51 482.16 488.21 483.09 482.78 477.35 478.66 486.06 498.63 11/15/95 496.95 518.59 509.87 491.81 482.21 488.23 483.07 482.74 477.38 478.74 486.08 499.08 07/25/96 492.81 521.56 505.90 491.87 474.99 486.92 481.62 481.36 475.03 475.56 481.64 498.68 02/25/97 497.05 521.62 511.38 493.41 480.11 487.94 481.64 482.71 476.77 478.04 485.92 499.98 09/03/97 490.44 519.74 505.84 489.18 474.66 486.61 479.74 480.99 474.02 473.61 480.75 498.23 05/04/98 497.21 524.30 509.76 493.91 478.91 487.80 481.31 482.35 476.35 477.64 484.73 500.08 R00592 - 163 488.03 518.27 504.69 487.98 474.66 486.29 480.01 481.05 473.65 474.03 479.92 497.33 04/26/99 494.64 519.63 507.19 490.61 478.14 487.64 481.06 482.31 476.44 477.41 483.67 499.58 11/22/99 494.60 520.70 509.25 490.86 478.21 487.71 482.59 482.50 476.37 477.66 483.64 499.68 05/23/00 495.23 522.28 509.95 492.43 478.04 488.02 482.58 482.43 476.14 477.49 484.32 499.93 472.45 473.22 480.52 11/29/00 493.95 518.42 508.48 488.96 474.84 486.97 482.14 481.96 475.33 476.49 482.76 498.71 472.12 472.44 479.26 06/05/01 494.55 519.57 510.52 489.82 477.99 487.72 482.55 482.22 476.19 477.91 484.06 499.28 472.50 473.08 479.73 11/13/01 492.55 515.86 506.39 488.03 474.74 486.42 481.43 481.33 474.15 474.97 480.37 497.83 470.91 470.94 478.15 06/04/02 490.90 515.89 507.87 487.63 474.66 486.66 481.42 481.04 475.03 476.01 480.97 497.83 470.70 470.99 478.42 03/13/03 492.52 518.74 513.07 481.50 488.63 482.92 482.74 477.40 478.79 485.96 500.43 474.88 473.00 480.95 06/19/03 495.73 521.57 514.49 492.14 479.14 488.24 482.81 482.66 477.67 478.46 485.37 500.72 472.97 473.72 480.64 12/08/03 494.17 519.49 514.04 488.63 475.94 488.13 482.62 482.26 475.97 477.19 483.17 499.71 472.38 472.79 479.55 06/22/04 493.45 519.56 508.38 486.94 481.86 481.46 475.08 476.41 482.06 499.70 471.74 470.54 479.36 11/30/04 495.00 518.09 512.51 488.04 482.96 482.63 476.67 478.21 484.48 500.13 473.09 473.74 480.16 06/01/05 494.90 518.43 509.88 490.18 475.76 487.34 482.39 481.84 475.60 476.91 482.85 499.93 471.67 472.19 479.46 11/02/05 489.75 515.43 507.17 474.59 486.94 481.52 481.16 473.70 475.99 481.05 498.80 470.72 469.59 477.84 05/22/06 493.45 516.59 510.39 487.14 482.47 481.86 474.60 476.63 482.50 499.23 471.42 471.84 477.54 11/27/06 494.04 515.12 513.38 489.06 477.53 488.65 483.03 482.68 477.05 478.70 485.34 499.46 473.24 473.95 481.04 06/13/07 493.65 517.85 509.06 489.23 474.59 488.84 482.19 481.83 475.46 476.24 485.54 499.82 471.08 471.50 479.27 472.84 12/12/07 488.14 512.44 512.02 488.86 473.61 486.39 481.79 480.84 472.65 473.77 479.85 498.78 469.42 468.69 477.91 469.70 06/10/08 492.44 515.55 510.20 489.17 474.90 487.49 482.40 481.96 474.76 476.63 482.32 500.13 471.19 471.63 479.53 472.85 11/05/08 491.86 514.54 509.48 486.62 474.21 487.49 482.71 482.36 475.74 476.90 482.04 506.04 472.60 471.41 476.74 473.15 471.87 05/19/09 517.14 512.14 482.86 482.34 475.92 476.11 483.42 500.40 471.72 472.23 480.06 473.83 471.11 11/18/09 493.75 514.85 511.55 486.20 476.31 488.40 483.11 482.78 476.62 478.21 484.55 500.12 472.76 473.09 480.34 474.31 472.51 06/21/10 518.72 510.98 488.92 475.41 482.74 482.78 475.69 476.71 483.12 499.50 470.90 471.69 479.88 473.20 471.87 11/18/10 515.04 509.85 486.89 473.11 482.91 482.64 475.08 476.24 482.32 499.38 471.44 471.51 479.62 472.32 471.08 05/23/11 516.54 511.91 487.13 475.01 482.54 482.82 476.13 477.11 483.28 500.28 471.69 472.01 480.21 473.45 472.09 11/15/11 513.17 485.89 471.75 482.34 482.42 473.90 475.50 481.76 499.28 470.37 469.54 478.81 471.18 469.99 06/05/12 516.81 487.48 475.51 483.24 482.92 476.27 477.10 483.04 500.33 471.68 471.98 480.32 473.55 472.13 11/12/12 515.97 485.97 474.16 483.04 483.03 476.03 476.98 482.81 500.31 471.89 472.12 480.34 473.12 471.75 05/13/13 517.75 488.27 477.51 483.77 483.28 476.74 477.88 484.41 500.83 472.18 473.39 480.84 475.01 473.15 08/21/13 472.16 473.10 475.46 473.09 11/11/13 518.54 489.28 474.81 483.38 483.12 475.76 476.94 482.99 500.66 471.74 472.20 480.40 473.35 472.23 02/10/14 472.31 473.41 475.07 473.78 05/12/14 521.11 490.92 479.05 483.62 482.04 476.37 477.77 484.67 501.53 470.97 473.12 480.86 475.12 473.65 08/18/14 470.86 471.69 472.93 471.47 11/11/14 516.49 486.36 472.91 482.94 482.76 474.35 475.86 482.39 499.86 471.17 471.09 479.38 471.88 470.53 05/12/15 520.04 490.60 477.86 483.56 483.11 476.38 477.46 484.42 501.20 471.46 472.92 480.81 474.80 473.18 11/10/15 517.67 488.96 478.41 484.00 483.64 477.70 479.29 486.35 501.48 473.86 474.52 481.36 476.12 474.65 MIN 488.03 512.44 504.69 487.63 485.89 474.59 471.75 486.29 479.74 480.84 472.65 473.61 479.85 495.81 469.42 468.69 476.74 469.70 469.99 MAX 500.61 524.30 514.49 493.91 490.92 482.21 479.05 488.84 484.00 483.64 478.08 479.29 486.35 506.04 474.88 474.52 481.36 476.12 474.65 MEAN 493.97 517.96 509.37 490.55 487.82 477.91 475.24 487.51 482.48 482.26 475.94 477.02 483.28 499.58 471.84 472.14 479.67 473.49 472.23 RANGE 12.58 11.86 9.80 6.28 5.03 7.62 7.30 2.55 4.26 2.80 5.43 5.68 6.50 10.23 5.46 5.83 4.62 6.42 4.66STD2.48 2.51 2.62 1.78 1.63 2.54 1.96 0.69 0.85 0.65 1.22 1.23 1.66 1.53 1.03 1.28 1.11 1.48 1.16 Elevations expressed in feet above mean sea level.Upgradient wells shaded yellow.All SWE data have been corrected to survey data obtained during May, 1999.- outlier removed ELEV-mp and ELEV-gs derived from survey performed during May, 1999. R00592 - 163 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINAPROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF STATIC WATER ELEVATIONS 465 470 475 480 485 490 495 500 505 510 515 520 525 530 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-01 MW-04 MW-05 MW-06 [old CDD]MW-07 [old CDD]MW-13 MW-14A MW-14B MW-15 MW-16 MW-17 MW-20 MW-21S MW-21D MW-22 [old CDD]MW-23 MW-24 504 506 508 510 512 514 516 518 520 522 524 526 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-04 MW-05 wells at upgradient (west)end of landfill 470 475 480 485 490 495 500 505 510 515 520 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-05 MW-20 MW-17 MW-16 wells along south side of landfill 479.0 479.5 480.0 480.5 481.0 481.5 482.0 482.5 483.0 483.5 484.0 484.5 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-14A MW-14B 472 473 474 475 476 477 478 479 480 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-15 MW-16 wells near east end of waste unit 470 472 474 476 478 480 482 484 486 488 490 492 494 496 El e v a t i o n ( f e e t a b o v e s e a l e v e l ) Date ORANGE COUNTY REGIONAL SANITARY LANDFILL -NORTH STATIC WATER ELEVATIONS MW-06 [old CDD]MW-22 [old CDD]MW-07 [old CDD]MW-07R [old CDD]MW-06R [old CDD] wells associated with old (closed) CDD waste unit ATTACHMENT 4 GROUNDWATER VELOCITY CALCULATIONS [BASED ON DATA PRESENTED IN ATTACHMENT 3] ATTACHMENT 4 GROUNDWATER VELOCITY CALCULATIONS The rate of at which constituents are transported in groundwater may be conservatively estimated by the velocity of groundwater flow. We shall distinguish between the apparent Darcy groundwater flow velocity (Vd) and seepage velocity (Vs), which are given by the equations: Vd = ki and Vs = kin-1, where: Vd = Darcy velocity Vs = seepage velocity k = hydraulic conductivity i = hydraulic gradient n = porosity On June 16, 2008, Draper Aden Associates personnel performed slug tests in the following wells: 6801-MW15, 6801-MW21S, 6801-MW21D, and 6801-MW23. Monitoring well 6801-MW15 is partially screened within overburden, but mostly screened within bedrock. Monitoring wells 6801- MW21S, 6801-MW21D, and 6801-MW23 are screened within bedrock. The hydraulic conductivity values calculated from the slug test data are within the same order of magnitude for the tested wells, ranging from 6.37 x 10-4 cm/sec to 1.34 x 10-4 cm/sec. The average hydraulic conductivity is 2.91 x 10-4 cm/sec. We have used the average hydraulic conductivity value to calculate groundwater velocity. Using published information, effective porosity was estimated to be about 0.02 (unitless) for fractured (meta) basalt. Using groundwater elevations measured during the subject sampling event, the hydraulic gradient of the uppermost aquifer was calculated along the flow path from 6801-MW4 to 6801-MW21S. The average hydraulic gradient was estimated by dividing the difference between the hydraulic heads (elevation heads) in well 6801-MW4 to 6801-MW21S by the distance between those two wells (about 2,336 feet). Calculated velocities (along the selected flow path) are presented on the table at the end of this ATTACHMENT, and illustrated on the accompanying graph. Groundwater Velocity Calculations Page 2 A comparison of groundwater velocity based upon the subject sampling event with those obtained during prior sampling events (see table) indicates that the velocity observed during the subject sampling event is approximately 3.3% less than the median velocity (along the selected flow path). A review of groundwater velocity over time (see graph) indicates that velocity generally increased, between late 2011 and early 2014, but has generally decreased since then (along the selected flow path). We note that the calculated groundwater velocity along a given flow path represents an average velocity along one of many potential flow paths, in the uppermost aquifer underlying the area of interest. Nonetheless, the velocity estimate is believed to be reasonably representative of that area. hydraulic hydraulic effective well conductivity conductivity porosity* designation (cm/sec)(m/sec) 6801-MW15 1.34E-04 1.34E-06 0.02 6801-MW21s 2.54E-04 2.54E-06 0.02 6801-MW21d 1.39E-04 1.39E-06 0.02 6801-MW23 6.38E-04 6.38E-06 0.02 * Fetter, C.W., 1988. Applied Hydrogeology, 2nd Edition. HYDRAULIC PARAMETERS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM from …… toward meters/meter meters/yr feet/yr date upgradient location upgradient SWE downgradient location downgradient SWE gradient GW velocity GW velocity 11-15-11 6801-MW4 513.17 6801-MW21S 470.37 1.83E-02 84.1 275.8 06-05-12 6801-MW4 516.81 6801-MW21S 471.68 1.93E-02 88.6 290.8 11-12-12 6801-MW4 515.97 6801-MW21S 471.89 1.89E-02 86.6 284.1 05-13-13 6801-MW4 517.75 6801-MW21S 472.18 1.95E-02 89.5 293.7 11-11-13 6801-MW4 516.21 6801-MW21S 469.52 2.00E-02 91.7 300.9 5/12/2014 6801-MW4 521.11 6801-MW21S 470.97 2.15E-02 98.5 323.1 11/11/2014 6801-MW4 516.49 6801-MW21S 471.17 1.94E-02 89.0 292.1 5/12/2015 6801-MW4 520.04 6801-MW21S 471.46 2.08E-02 95.4 313.1 11/10/2015 6801-MW4 517.67 6801-MW21S 473.86 1.88E-02 86.1 282.3 hydraulic conductivity = 2.91E-4 cm/second median = 89.0 292.1 distance = 2,336 feet deviation from median = R00592-163 -3.3% CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM GROUNDWATER VELOCITY CALCULATIONS 270 280 290 300 310 320 330 11-15-11 06-05-12 11-12-12 05-13-13 11-11-13 5/12/2014 11/11/2014 5/12/2015 11/10/2015 fe e t p e r y e a r date measured OCSWM NORTH LANDFILL: GROUNDWATER VELOCITY median ATTACHMENT 5 SUMMARY OF ORGANIC CONSTITUENTS ATTACHMENT 5 ORGANIC CONSTITUENTS During November 10, and November 11, 2015 (sampling event 44), Sherrill Environmental, Inc. (Sherrill) personnel obtained groundwater samples from fourteen groundwater monitoring wells at the Orange County Solid Waste Management North Facility (north side of Eubanks Road).  During event 44, the laboratory detected fourteen organic constituents, at concentrations greater than their respective method detection limits (>MDLs): benzene, chlorobenzene, chloroethane, 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,1-dichloroethane, 1,1- dichloroethene, cis-1,2-dichloroethene, trans-1,2-dichloroethene, 1,2-dichloropropane, naphthalene, tetrachloroethene, trichloroethene, vinyl chloride. 15A NCAC 13B.1634.(d).(1) states, “After obtaining the results from the initial or subsequent sampling events required in Paragraph (b) of this Rule, the owner or operator shall: (1) Within 14 days, notify the Division and place in the operating record identifying the Appendix II constituents that have been detected ….” We note that dichlorodifluoromethane and naphthalene represent “additional” constituents listed in Appendix II, but not listed in Appendix I. Of the sixteen organic constituents detected, six organic constituents exceeded their respective Solid Waste Section Limits (>SWSLs): benzene, chlorobenzene, 1,4- dichlorobenzene, 1,1-dichloroethane, cis-1,2-dichloroethene, vinyl chloride. Of the six organic constituents that exceeded their respective Solid Waste Section Limits (>SWSLs), the reported concentrations of five organic constituents exceeded their respective North Carolina Groundwater Quality Standards:  The reported concentrations of benzene in wells 6801-MW14B (1.2 µg/l), 6801-MW15 (1.2 µg/l), and 6801-MW20 (5.0 µg/l) exceeded its SWSL and its Groundwater Quality Standard (1 µg/l; 2L Standard).  The reported concentrations of 1,4-dichlorobenzene in wells 6801-MW15 (7.1 µg/l) and 6801-MW20 (6.7 µg/l) exceeded its SWSL and its Groundwater Quality Standard (6 µg/l; GWPS).  The reported concentrations of 1,1-dichloroethane in wells 6801-MW15 (6.3 µg/l), 6801-MW21S (8.2 µg/l), 6801-MW21D (9.2 µg/l), 6801-MW22 (6.4 µg/l), 6801- MW23 (15 µg/l), and 6801-MW24 (10 µg/l) exceeded its SWSL and its Groundwater Quality Standard (6 µg/l; 2L Standard).  The reported concentration of cis-1,2-dichloroethene in well 6801-MW15 (97 µg/l) exceeded its SWSL and its Groundwater Quality Standard (70 µg/l; 2L Standard). Organic Constituents Page 2  The reported concentrations of vinyl chloride in wells 6801-MW14B (6.4 µg/l), 6801- MW15 (13 µg/l), 6801-MW21D (3.0 µg/l), 6801-MW22 (1.8 µg/l), and 6801-MW23 (4.9 µg/l) exceeded its SWSL and its Groundwater Quality Standard (0.03 µg/l; 2L Standard). 15A NCAC 13B.1634.(f) states, “If one or more Appendix II constituents are detected above the approved ground-water protection standards in any sampling event, the owner or operator, shall within 14 days of this finding, submit a report to the Division, place a notice in the operating record, and notify local government officials.” Comments. Orange County Solid Waste Management has already characterized the nature and extent of constituents that previously exceeded their respective Groundwater Quality Standards, and prepared an Assessment of Corrective Measures, Corrective Action Plan, and Corrective Action Monitoring Plan addressing such constituents (all of which were previously submitted to NCDENR for review and approval). Injection reports for areas in which remedial compounds are injected into the groundwater will be submitted (under separate cover), in accordance with the injection permit that was issued for the facility by the NCDENR Underground Injection Control Section. GRAPHS 0 5 10 15 20 25 30 35 40 45 05 / 2 3 / 0 0 11 / 2 9 / 0 0 06 / 0 5 / 0 1 11 / 1 3 / 0 1 06 / 0 4 / 0 2 03 / 1 2 / 0 3 06 / 1 8 / 0 3 12 / 0 8 / 0 3 06 / 2 2 / 0 4 11 / 3 0 / 0 4 06 / 0 1 / 0 5 11 / 0 2 / 0 5 05 / 2 2 / 0 6 11 / 2 7 / 0 6 06 / 1 2 / 0 7 12 / 1 2 / 0 7 06 / 1 7 / 0 8 11 / 0 5 / 0 8 05 / 1 9 / 0 9 11 / 1 8 / 0 9 06 / 2 1 / 1 0 11 / 1 8 / 1 0 05 / 2 3 / 1 1 08 / 2 3 / 1 1 11 / 1 5 / 1 1 02 / 2 1 / 1 2 06 / 0 5 / 1 2 10 / 0 9 / 1 2 11 / 1 2 / 1 2 02 / 1 8 / 1 3 05 / 1 3 / 1 3 11 / 1 1 / 1 3 02 / 1 0 / 1 4 05 / 1 2 / 1 4 08 / 1 8 / 1 4 11 / 1 1 / 1 4 02 / 2 3 / 1 5 05 / 1 2 / 1 5 08 / 2 4 / 1 5 11 / 1 0 / 1 5 co n c e n t r a t i o n ( p p b ) date sampled 1,1-dichloroethane MW-21s MW-21d includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 0 5 10 15 20 25 30 35 05 / 2 3 / 0 0 11 / 2 9 / 0 0 06 / 0 5 / 0 1 11 / 1 3 / 0 1 06 / 0 4 / 0 2 03 / 1 2 / 0 3 06 / 1 8 / 0 3 12 / 0 8 / 0 3 06 / 2 2 / 0 4 11 / 3 0 / 0 4 06 / 0 1 / 0 5 11 / 0 2 / 0 5 05 / 2 2 / 0 6 11 / 2 7 / 0 6 06 / 1 2 / 0 7 12 / 1 2 / 0 7 06 / 1 7 / 0 8 11 / 0 5 / 0 8 05 / 1 9 / 0 9 11 / 1 8 / 0 9 06 / 2 1 / 1 0 11 / 1 8 / 1 0 05 / 2 3 / 1 1 08 / 2 3 / 1 1 11 / 1 5 / 1 1 02 / 2 1 / 1 2 06 / 0 5 / 1 2 10 / 0 9 / 1 2 11 / 1 2 / 1 2 02 / 1 8 / 1 3 05 / 1 3 / 1 3 11 / 1 1 / 1 3 02 / 1 0 / 1 4 05 / 1 2 / 1 4 08 / 1 8 / 1 4 11 / 1 1 / 1 4 02 / 2 3 / 1 5 05 / 1 2 / 1 5 08 / 2 4 / 1 5 11 / 1 0 / 1 5 co n c e n t r a t i o n ( p p b ) date sampled 1,1-dichloroethane MW-23 MW-24 includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 5 10 15 20 25 30 35 40 05 / 2 3 / 0 0 11 / 2 9 / 0 0 06 / 0 5 / 0 1 11 / 1 3 / 0 1 06 / 0 4 / 0 2 03 / 1 2 / 0 3 06 / 1 8 / 0 3 12 / 0 8 / 0 3 06 / 2 2 / 0 4 11 / 3 0 / 0 4 06 / 0 1 / 0 5 11 / 0 2 / 0 5 05 / 2 2 / 0 6 11 / 2 7 / 0 6 06 / 1 2 / 0 7 12 / 1 2 / 0 7 06 / 1 7 / 0 8 11 / 0 5 / 0 8 05 / 1 9 / 0 9 11 / 1 8 / 0 9 06 / 2 1 / 1 0 11 / 1 8 / 1 0 05 / 2 3 / 1 1 08 / 2 3 / 1 1 11 / 1 5 / 1 1 02 / 2 1 / 1 2 06 / 0 5 / 1 2 10 / 0 9 / 1 2 11 / 1 2 / 1 2 02 / 1 8 / 1 3 05 / 1 3 / 1 3 11 / 1 1 / 1 3 02 / 1 0 / 1 4 05 / 1 2 / 1 4 08 / 1 8 / 1 4 11 / 1 1 / 1 4 02 / 2 3 / 1 5 05 / 1 2 / 1 5 08 / 2 4 / 1 5 11 / 1 0 / 1 5 co n c e n t r a t i o n ( p p b ) date sampled cis-1,2-dichloroethene MW-21s MW-21d includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 10 20 30 40 50 60 70 80 90 co n c e n t r a t i o n ( p p b ) date sampled cis-1,2-dichloroethene MW-23 MW-24 includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 50 100 150 200 250 co n c e n t r a t i o n ( p p b ) date sampled cis-1,2-dichloroethene MW-15 includes estimated (J) valuesoutliers removed from dataset 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 co n c e n t r a t i o n ( p p b ) date sampled tetrachloroethene MW-21s MW-21d includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 0.5 1 1.5 2 2.5 3 3.5 4 co n c e n t r a t i o n ( p p b ) date sampled tetrachloroethene MW-23 MW-24 includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 co n c e n t r a t i o n ( p p b ) date sampled vinyl chloride MW-21s MW-21d includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 0 1 2 3 4 5 6 co n c e n t r a t i o n ( p p b ) date sampled vinyl chloride MW-23 MW-24 includes estimated (J) valuesoutliers removed from dataset injection event 1: 03-29-11 injection event 4: 09-13-12 TABLES acetone 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 6000 (2L Std)06/30/93 2L Std = 700 (pre- Jan. 2010)11/04/94 2L Std = 6000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/9804/26/99 11/22/99 05/23/00 11/29/00 06/05/0111/13/01 06/04/02 03/12/03 06/18/03 12/08/0306/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 <1.2 412 J <1.2 <1.2 <1.2 <1.2 1.2 100 ic, cc 11/05/08 <1.2 106 S <1.2 <1.2 <1.2 <1.2 1.2 100 05/19/09 <1.5 61 J <1.5 <1.5 <1.5 <1.5 1.5 100 11/18/09 <3 300 <3 <3 <3 <3 3 100 06/21/10 <1.5 <1.5 14 J <1.5 <1.5 <1.5 1.5 100 11/18/10 <1.5 16 J <1.5 <1.5 <1.5 <1.5 1.5 100 injection event (03-29-11)05/23/11 <1.2 120 <1.2 <1.2 <1.2 <1.2 1.2 100 08/23/11 1.2 100 injection event (09-28-11)11/15/11 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/21/12 1.2 100 injection event (04-14-12)06/05/12 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 10/09/12 1.2 100 injection event (09-13-12)11/12/12 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/18/13 1.2 100 05/13/13 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/21/13 1.2 100 11/11/13 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/10/14 1.2 100 05/12/14 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/18/14 1.2 100 11/11/14 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/23/15 1.2 100 05/12/15 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/24/15 1.2 100 11/10/15 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA MW-6R MW-7 MW-7R MW-13 MW-14A MW-14BConstituentSample Date MW-1 MW-4 MW-5 MW-6 PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS LOD SWSL QA/QC acetone 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 6000 (2L Std)06/30/93 2L Std = 700 (pre- Jan. 2010)11/04/94 2L Std = 6000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/9804/26/99 11/22/99 05/23/00 11/29/00 06/05/0111/13/01 06/04/02 03/12/03 06/18/03 12/08/0306/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 <1.2 2 J <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 8.1 J 1.2 100 ic, cc 11/05/08 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 05/19/09 <1.5 <1.5 <1.5 12 J <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 11/18/09 <3 <3 <3 9.5 J <3 1.5 J <3 <3 <3 3 100 06/21/10 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 11/18/10 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 injection event (03-29-11)05/23/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/23/11 <1.2 <1.2 <1.2 <1.2 1.2 100 injection event (09-28-11)11/15/11 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/21/12 <1.2 <1.2 <1.2 <1.2 1.2 100 injection event (04-14-12)06/05/12 <1.2 <1.2 <1.2 4.7 J <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 10/09/12 <1.2 <1.2 <1.2 <1.2 1.2 100 injection event (09-13-12)11/12/12 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/18/13 <1.2 <1.2 <1.2 <1.2 1.2 100 05/13/13 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/21/13 <0.12 <1.2 <1.2 <1.2 1.2 100 11/11/13 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/10/14 <1.2 <1.2 <1.2 <1.2 1.2 100 05/12/14 <1.2 <1.2 <1.2 5.7 J <1.2 <1.2 <1.2 <1.2 1.2 100 08/18/14 <1.2 <1.2 <1.2 <1.2 1.2 100 11/11/14 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 02/23/15 <1.2 <1.2 <1.2 <1.2 1.2 100 05/12/15 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 08/24/15 <1.2 <1.2 <1.2 <1.2 1.2 100 11/10/15 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 100 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA Constituent Sample Date MW-15 PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 benzene 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 1 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 md 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 is 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 cc 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 ic, cc, ss 12/08/03 <5.0 <5.0 <5.0 ic, cc 06/22/04 <5.0 <5.0 <5.0 ic, cc 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 1.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 0.9 J 0.1 1 06/17/08 <0.1 0.7 J <0.1 1 J <0.1 1 J 0.1 1 ic, cc 11/05/08 <0.1 0.8 J <0.1 <0.1 1 J 0.6 J 0.1 1 05/19/09 <0.2 1.1 <0.2 <0.2 0.63 J 1.3 0.2 1 11/18/09 <0.4 1.2 <0.4 <0.4 <0.4 1.3 0.4 1 06/21/10 <0.05 <0.05 0.87 J <0.05 <0.05 <0.05 0.05 1 11/18/10 <0.05 1.6 <0.05 <0.05 <0.05 1.2 0.2 1 injection event (03-29-11)05/23/11 <0.68 <0.68 <0.68 <0.68 <0.68 0.98 J 0.68 1 08/23/11 0.68 1 injection event (09-28-11)11/15/11 <0.68 <0.68 <0.68 <0.68 1.2 0.68 1 02/21/12 0.15 1 injection event (04-14-12)06/05/12 <0.15 <0.15 <0.15 <0.15 0.73 J 0.15 1 10/09/12 0.15 1 injection event (09-13-12)11/12/12 <0.15 <0.15 <0.15 <0.15 1.2 0.15 1 02/18/13 0.15 1 05/13/13 <0.15 <0.15 <0.15 <0.15 1.2 0.15 1 08/21/13 0.15 1 11/11/13 <0.15 0.43 J <0.15 <0.15 0.85 J 0.15 1 02/10/14 0.15 1 05/12/14 <0.15 <0.15 <0.15 <0.15 0.78 J 0.15 1 08/18/14 0.15 1 11/11/14 <0.15 <0.15 <0.15 <0.15 1.0 0.15 1 02/23/15 0.15 1 05/12/15 <0.15 <0.15 <0.15 <0.15 1.2 0.15 1 08/24/15 0.15 1 11/10/15 <0.15 <0.15 <0.15 <0.15 1.2 0.15 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC benzene 04/17/90 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 <5.0 <5.0 <5.0 NCGQS = 1 (2L Std)06/30/93 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 12 md 12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 13 03/13/95 <5.0 <5.0 <5.0 8 11/15/95 <5.0 <5.0 <5.0 8 J is 07/25/96 <5.0 <5.0 <5.0 8 02/25/97 <5.0 <5.0 <5.0 9 09/03/97 <5.0 <5.0 <5.0 8 05/04/98 <5.0 <5.0 <5.0 6 11/02/98 <5.0 <5.0 <5.0 6 04/26/99 <5.0 <5.0 <5.0 7 11/22/99 <5.0 <5.0 <5.0 6 05/23/00 <5.0 <5.0 <5.0 7 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 7 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 7 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 7 J <5.0 <5.0 <5.0 cc 06/04/02 <5.0 <5.0 <5.0 6 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 6 J <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 6 J <5.0 <5.0 <5.0 ic, cc, ss 12/08/03 <5.0 <5.0 <5.0 5 J <5.0 <5.0 <5.0 ic, cc 06/22/04 <5.0 <5.0 <5.0 6 J <5.0 <5.0 <5.0 ic, cc 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 7 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 6 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 5.5 <5.0 <5.0 <5.0 06/12/07 1.4 0.5 J <0.1 5.6 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 1.3 0.4 J <0.1 4.4 <0.1 <0.1 0.5 J 0.4 J 0.1 1 06/17/08 1.2 J 0.6 J <0.1 5 J <0.1 <0.1 0.3 J <0.1 <0.1 0.1 1 ic, cc 11/05/08 1.4 0.4 J <0.1 5.2 0.2 J <0.1 <0.1 0.3 J 0.2 J 0.1 1 05/19/09 1.6 0.67 J <0.2 5.1 <0.2 <0.2 0.49 J <0.2 <0.2 0.2 1 11/18/09 1.4 0.67 J <0.4 5.2 <0.4 <0.4 0.71 J 0.47 J <0.4 0.4 1 06/21/10 0.8 J <0.05 <0.05 5.2 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 1 11/18/10 2 0.69 J <0.05 5.8 0.4 J <0.05 0.69 J 0.52 J <0.05 0.2 1 injection event (03-29-11)05/23/11 1.7 <0.68 <0.68 4.4 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 1 08/23/11 <0.68 <0.68 <0.68 <0.68 0.68 1 injection event (09-28-11)11/15/11 1.5 <0.68 <0.68 5.2 <0.68 <0.68 0.74 J <0.68 <0.68 0.68 1 02/21/12 <0.15 <0.15 <0.15 <0.15 0.15 1 injection event (04-14-12)06/05/12 1.1 <0.15 <0.15 4.3 <0.15 <0.15 0.5 J <0.15 <0.15 0.15 1 10/09/12 <0.15 <0.15 <0.15 <0.15 0.15 1 injection event (09-13-12)11/12/12 1.5 0.49 J <0.15 5.5 <0.15 <0.15 0.79 J 0.49 J <0.15 0.15 1 02/18/13 <0.15 <0.15 <0.15 <0.15 0.15 1 05/13/13 1.4 0.41 J <0.15 6.2 <0.15 <0.15 0.73 J <0.15 <0.15 0.15 1 08/21/13 0.41 J <0.15 <0.15 <0.15 0.15 1 11/11/13 1.3 <0.15 <0.15 4.3 <0.15 <0.15 0.74 J <0.15 <0.15 0.15 1 02/10/14 <0.15 <0.15 <0.15 <0.15 0.15 1 05/12/14 <0.15 <0.15 <0.15 5.4 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 08/18/14 <0.15 <0.15 0.43 J <0.15 0.15 1 11/11/14 1.2 <0.15 <0.15 5.3 <0.15 <0.15 0.64 J <0.15 <0.15 0.15 1 02/23/15 <0.15 <0.15 <0.15 <0.15 0.15 1 05/12/15 1.3 <0.15 <0.15 5.3 <0.15 <0.15 0.70 J <0.15 <0.15 0.15 1 08/24/15 <0.15 <0.15 0.40 J <0.15 0.15 1 11/10/15 1.2 0.44 J 5.0 <0.15 <0.15 <0.15 0.40 J <0.15 0.15 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 bis(2-ethylhexyl)phthalate 04/17/90 MCL = w 07/11/91 FBAC = 15 (SWSL)05/28/92 NCGQS = 3 (2L Std)06/30/93 2L Std = 3 (Aug. 2010)11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 06/21/10 11/18/10 injection event (03-29-11)05/23/11 <1.7 <1.7 2.3 J 1.7 15 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <1.7 <1.7 <1.7 1.7 15 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <1.7 <1.7 <1.7 1.7 15 08/21/13 11/11/13 02/10/14 05/12/14 <1.7 <1.7 <1.7 1.7 15 08/18/14 11/11/14 02/23/15 05/12/15 <1.7 <1.7 <1.7 1.7 15 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B bis(2-ethylhexyl)phthalate 04/17/90 MCL = w 07/11/91 FBAC = 15 (SWSL)05/28/92 NCGQS = 3 (2L Std)06/30/93 2L Std = 3 (Aug. 2010)11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 06/21/10 11/18/10 injection event (03-29-11)05/23/11 4.5 J <1.7 <1.7 <1.7 1.7 15 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <1.7 <1.7 <1.7 <1.7 1.7 15 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 1.7 15 08/21/13 11/11/13 02/10/14 05/12/14 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 1.7 15 08/18/14 11/11/14 02/23/15 05/12/15 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 1.7 15 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 bromomethane 04/17/90 MCL = w 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 10 (GWPS)06/30/93 GWPS = NE (pre- Aug. 2010)11/04/94 GWPS = 10 (Aug. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 0.49 10 06/21/10 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 0.28 10 11/18/10 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 0.49 10 injection event (03-29-11)05/23/11 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 0.58 10 08/23/11 0.58 10 injection event (09-28-11)11/15/11 <0.58 <0.58 <0.58 <0.58 <0.58 0.58 10 02/21/12 0.14 10 injection event (04-14-12)06/05/12 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 10/09/12 0.14 10 injection event (09-13-12)11/12/12 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/18/13 0.14 10 05/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/21/13 0.14 10 11/11/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/10/14 0.14 10 05/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/18/14 0.14 10 11/11/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/23/15 0.14 10 05/12/15 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/24/15 0.14 10 11/10/15 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC bromomethane 04/17/90 MCL = w 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 10 (GWPS)06/30/93 GWPS = NE (pre- Aug. 2010)11/04/94 GWPS = 10 (Aug. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 <0.49 <0.49 <0.49 1.5 J <0.49 <0.49 <0.49 1.6 J <0.49 0.49 10 06/21/10 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 0.28 10 11/18/10 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 0.49 10 injection event (03-29-11)05/23/11 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 0.58 10 08/23/11 <0.58 <0.58 <0.58 <0.58 0.58 10 injection event (09-28-11)11/15/11 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 0.58 10 02/21/12 <0.14 <0.14 <0.14 <0.14 0.14 10 injection event (04-14-12)06/05/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 10/09/12 <0.14 <0.14 <0.14 <0.14 0.14 10 injection event (09-13-12)11/12/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/18/13 <0.14 <0.14 <0.14 <0.14 0.14 10 05/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/21/13 <0.14 <0.14 <0.14 <0.14 0.14 10 11/11/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/10/14 <0.14 <0.14 <0.14 <0.14 0.14 10 05/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/18/14 <0.14 <0.14 <0.14 <0.14 0.14 10 11/11/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 02/23/15 <0.14 <0.14 <0.14 <0.14 0.14 10 05/12/15 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 08/24/15 <0.14 <0.14 <0.14 <0.14 0.14 10 11/10/15 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 2-butanone 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 4000 (2L Std)06/30/93 2L Std = 4200 (pre- Jan. 2010)11/04/94 2L Std = 4000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 <0.9 3.3 J <0.9 <0.9 <0.9 <0.9 0.9 100 ic, cc 11/05/08 <0.9 1 J <0.9 <0.9 <0.9 <0.9 0.9 100 05/19/09 <1 <1 <1 <1 <1 <1 1 100 11/18/09 <2 2.3 J <2 <2 <2 <2 2 100 06/21/10 <1 <1 <1 <1 <1 <1 1 100 11/18/10 <1 <1 <1 <1 <1 <1 1 100 injection event (03-29-11)05/23/11 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/23/11 1.3 100 injection event (09-28-11)11/15/11 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/21/12 1.3 100 injection event (04-14-12)06/05/12 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 10/09/12 1.3 100 injection event (09-13-12)11/12/12 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/18/13 1.3 100 05/13/13 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/21/13 1.3 100 11/11/13 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/10/14 1.3 100 05/12/14 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/18/14 1.3 100 11/11/14 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/23/15 1.3 100 05/12/15 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/24/15 1.3 100 11/10/15 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B 2-butanone 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 4000 (2L Std)06/30/93 2L Std = 4200 (pre- Jan. 2010)11/04/94 2L Std = 4000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 0.9 100 ic, cc 11/05/08 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 <0.9 0.9 100 05/19/09 <1 <1 <1 <1 <1 <1 <1 <1 <1 1 100 11/18/09 <2 <2 <2 <2 <2 <2 <2 <2 <2 2 100 06/21/10 <1 <1 <1 <1 <1 <1 <1 <1 <1 1 100 11/18/10 <1 <1 <1 <1 <1 <1 <1 <1 <1 1 100 injection event (03-29-11)05/23/11 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/23/11 <1.3 <1.3 <1.3 <1.3 1.3 100 injection event (09-28-11)11/15/11 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/21/12 <1.3 <1.3 <1.3 <1.3 1.3 100 injection event (04-14-12)06/05/12 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 10/09/12 <1.3 <1.3 <1.3 <1.3 1.3 100 injection event (09-13-12)11/12/12 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/18/13 <1.3 <1.3 <1.3 <1.3 1.3 100 05/13/13 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/21/13 <1.3 <1.3 <1.3 <1.3 1.3 100 11/11/13 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/10/14 <1.3 <1.3 <1.3 <1.3 1.3 100 05/12/14 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/18/14 <1.3 <1.3 <1.3 <1.3 1.3 100 11/11/14 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 02/23/15 <1.3 <1.3 <1.3 <1.3 1.3 100 05/12/15 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 08/24/15 <1.3 <1.3 <1.3 <1.3 1.3 100 11/10/15 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.3 100 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 carbon disulfide 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 700 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <0.5 <0.5 <0.5 1.9 J 0.5 100 06/17/08 <0.5 6 J <0.5 <0.5 <0.5 <0.5 0.5 100 ic, cc 11/05/08 <0.5 4.5 J <0.5 <0.5 <0.5 <0.5 0.5 100 05/19/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 11/18/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 06/21/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 11/18/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 injection event (03-29-11)05/23/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/23/11 1.5 100 injection event (09-28-11)11/15/11 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/21/12 1.5 100 injection event (04-14-12)06/05/12 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 10/09/12 1.5 100 injection event (09-13-12)11/12/12 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/18/13 1.5 100 05/13/13 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/21/13 1.5 100 11/11/13 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/10/14 1.5 100 05/12/14 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/18/14 1.5 100 11/11/14 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/23/15 1.5 100 05/12/15 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/24/15 1.5 100 11/10/15 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC carbon disulfide 04/17/90 MCL = w 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS = 700 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <0.5 <0.5 <0.5 1.2 J <0.5 <0.5 <0.5 <0.5 0.5 100 06/17/08 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 100 ic, cc 11/05/08 8 J <0.5 <0.5 1.2 J <0.5 <0.5 1 J <0.5 <0.5 0.5 100 05/19/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 11/18/09 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 06/21/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 11/18/10 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 0.54 100 injection event (03-29-11)05/23/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/23/11 <1.5 <1.5 <1.5 <1.5 1.5 100 injection event (09-28-11)11/15/11 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/21/12 <1.5 <1.5 <1.5 <1.5 1.5 100 injection event (04-14-12)06/05/12 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 10/09/12 <1.5 <1.5 <1.5 <1.5 1.5 100 injection event (09-13-12)11/12/12 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/18/13 <1.5 <1.5 <1.5 <1.5 1.5 100 05/13/13 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/21/13 <1.5 <1.5 <1.5 <1.5 1.5 100 11/11/13 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/10/14 <1.5 <1.5 <1.5 <1.5 1.5 100 05/12/14 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/18/14 <1.5 <1.5 <1.5 <1.5 1.5 100 11/11/14 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 02/23/15 <1.5 <1.5 <1.5 <1.5 1.5 100 05/12/15 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 08/24/15 <1.5 <1.5 <1.5 <1.5 1.5 100 11/10/15 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 1.5 100 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 chlorobenzene 04/17/90 MCL = 100 07/11/91 FBAC = 3 (SWSL)05/28/92 NCGQS = 50 (2L Std)06/30/93 11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 7 R <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 1.2 J 0.1 3 12/12/07 <0.1 <0.1 0.4 J 0.9 J 0.1 3 06/17/08 <0.1 <0.1 <0.1 3 J 0.4 J 1.2 J 0.1 3 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 0.5 J 0.7 J 0.1 3 05/19/09 <0.27 <0.27 <0.27 <0.27 1.7 J 1.9 J 0.27 3 11/18/09 <0.27 <0.27 <0.27 <0.27 0.69 J 1.4 J 0.27 3 06/21/10 <0.069 <0.069 <0.069 <0.069 0.59 J 1.8 J 0.069 3 11/18/10 <0.27 <0.27 <0.27 <0.27 0.59 J 1.7 J 0.27 3 injection event (03-29-11)05/23/11 <0.74 <0.74 <0.74 <0.74 <0.74 1.9 J 0.74 3 08/23/11 0.74 3 injection event (09-28-11)11/15/11 <0.74 <0.74 <0.74 <0.74 1.6 J 0.74 3 02/21/12 0.17 3 injection event (04-14-12)06/05/12 <0.17 <0.17 <0.17 0.48 J <0.17 0.17 3 10/09/12 0.17 3 injection event (09-13-12)11/12/12 <0.17 <0.17 <0.17 0.51 J 1.9 J 0.17 3 02/18/13 0.17 3 05/13/13 <0.17 <0.17 <0.17 0.62 J 2.3 J 0.17 3 08/21/13 0.17 3 11/11/13 <0.17 <0.17 <0.17 0.85 J 1.6 J 0.17 3 02/10/14 0.17 3 05/12/14 <0.17 <0.17 <0.17 0.55 J 3.5 0.17 3 08/18/14 0.17 3 11/11/14 <0.17 <0.17 <0.17 0.68 J 1.8 J 0.17 3 02/23/15 0.17 3 05/12/15 <0.17 <0.17 <0.17 0.43 J 3.0 0.17 3 08/24/15 0.17 3 11/10/15 <0.17 <0.17 <0.17 0.84 J 2.2 J 0.17 3 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B chlorobenzene 04/17/90 MCL = 100 07/11/91 FBAC = 3 (SWSL)05/28/92 NCGQS = 50 (2L Std)06/30/93 11/04/94 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 4.6 <0.1 <0.1 <0.1 0.5 J <0.1 0.6 J 0.7 J 0.1 3 12/12/07 3.9 0.2 J <0.1 0.3 J 0.3 J <0.1 1.2 J 0.9 J 0.1 3 06/17/08 5.2 J 0.3 J <0.1 0.4 J 0.5 J <0.1 1 J 0.8 J <0.1 0.1 3 ic, cc 11/05/08 4.4 <0.1 <0.1 0.4 J 0.4 J 0.3 J <0.1 0.8 J 0.3 J 0.1 3 05/19/09 6.5 <0.27 <0.27 0.88 J 0.97 J 0.68 J 1.4 J 0.99 J 0.57 J 0.27 3 11/18/09 5.6 <0.27 <0.27 0.77 J 0.81 J 0.62 J 2.1 J 1.3 J 0.59 J 0.27 3 06/21/10 6.5 <0.069 <0.069 0.8 J 0.87 J 0.66 J 1.2 J 0.58 J <0.069 0.069 3 11/18/10 6.3 0.41 J <0.27 0.73 J 0.95 J <0.27 1.6 J 1.8 J <0.27 0.27 3 injection event (03-29-11)05/23/11 6.5 <0.74 <0.74 <0.74 0.82 J <0.74 1.8 J 1.2 J <0.74 0.74 3 08/23/11 0.99 J <0.74 2 J <0.74 0.74 3 injection event (09-28-11)11/15/11 5.1 <0.74 <0.74 <0.74 <0.74 <0.74 2.5 J 1.9 J <0.74 0.74 3 02/21/12 0.75 J <0.17 1.6 J <0.17 0.17 3 injection event (04-14-12)06/05/12 6.6 <0.17 <0.17 0.55 J 0.92 J <0.17 2.3 J 1.5 J <0.17 0.17 3 10/09/12 0.94 J 0.72 J 2.2 J <0.17 0.17 3 injection event (09-13-12)11/12/12 7.2 <0.17 <0.17 0.77 J 1 J <0.17 <0.17 2.1 J 0.48 J 0.17 3 02/18/13 1.1 J <0.17 1.6 J 0.7 J 0.17 3 05/13/13 7.1 <0.17 <0.17 <0.17 1.3 J 0.47 J 2.4 J 1.4 J 0.73 J 0.17 3 08/21/13 1.3 1.1 2.0 0.46 J 0.17 3 11/11/13 7.2 <0.17 <0.17 0.88 J 1.5 J <0.17 2.3 J 2.5 J <0.17 0.17 3 02/10/14 1.5 J <0.17 1.4 J <0.17 0.17 3 05/12/14 8.0 0.42 J <0.17 1.5 J 1.3 J 0.63 J 2.5 J 2.4 J <0.17 0.17 3 08/18/14 <0.17 <0.17 1.4 J <0.17 0.17 3 11/11/14 6.1 <0.17 <0.17 1.1 J 1.4 J <0.17 2.4 J 3.1 <0.17 0.17 3 02/23/15 1.5 J <0.17 2.0 J <0.17 0.17 3 05/12/15 6.8 <0.17 <0.17 1.1 J 1.2 J 0.48 J 2.4 J 2.0 J <0.17 0.17 3 08/24/15 1.2 J 0.74 J 2.8 J <0.17 0.17 3 11/10/15 5.9 0.47 J <0.17 1.2 J 1.3 J <0.17 2.6 J 3.1 <0.17 0.17 3 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 chloroethane 04/17/90 <10.0 <10.0 <10.0 <10.0 <10.0 MCL = 07/11/91 <10.0 <10.0 <10.0 <10.0 <10.0 FBAC = 10 (SWSL)05/28/92 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 NCGQS = 3000 (2L Std)06/30/93 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 2L Std = NE (pre- Jan. 2010)11/04/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 2L Std = 3000 (Jan. 2010)12/20/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 02/02/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 03/13/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/15/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 07/25/96 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 02/25/97 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 09/03/97 <10.0 <10.0 <10.0 <10.0 <10.0 05/04/98 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/02/98 <10.0 <10.0 <10.0 <10.0 <10.0 04/26/99 <10.0 <10.0 <10.0 <10.0 <10.0 11/22/99 <10.0 <10.0 <10.0 <10.0 <10.0 05/23/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/13/01 <10.0 <10.0 <10.0 06/04/02 <10.0 <10.0 <10.0 03/12/03 <10.0 <10.0 <10.0 <10.0 06/18/03 <10.0 <10.0 <10.0 <10.0 <10.0 12/08/03 <10.0 <10.0 <10.0 <10.0 <10.0 06/22/04 <10.0 <10.0 <10.0 <10.0 <10.0 11/30/04 <10.0 <10.0 <10.0 06/01/05 <10.0 <10.0 <10.0 11/02/05 <10.0 <10.0 <10.0 05/22/06 <10.0 <10.0 <10.0 11/27/06 <10.0 <10.0 <10.0 06/12/07 <0.1 <0.1 3.6 J 6.9 J 0.1 10 12/12/07 <0.1 <0.1 0.4 J 1.3 J 0.1 10 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 1.5 J 0.1 10 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 0.7 J 0.7 J 0.1 10 05/19/09 <0.3 <0.3 <0.3 <0.3 1.1 J 1.9 J 0.3 10 11/18/09 <0.3 <0.3 <0.3 <0.3 <0.3 1.2 J 0.3 10 06/21/10 <0.18 <0.18 <0.18 <0.18 <0.18 1.2 J 0.18 10 11/18/10 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 10 injection event (03-29-11)05/23/11 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10 08/23/11 0.75 10 injection event (09-28-11)11/15/11 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10 02/21/12 0.23 10 injection event (04-14-12)06/05/12 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10 10/09/12 0.23 10 injection event (09-13-12)11/12/12 <0.23 <0.23 <0.23 <0.23 1.3 J 0.23 10 02/18/13 0.23 10 05/13/13 <0.23 <0.23 <0.23 <0.23 2.3 J 0.23 10 08/21/13 0.23 10 11/11/13 <0.23 0.66 J <0.23 <0.23 0.82 J 0.23 10 02/10/14 0.23 10 05/12/14 <0.23 <0.23 <0.23 <0.23 2.4 J 0.23 10 08/18/14 0.23 10 11/11/14 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10 02/23/15 0.23 10 05/12/15 <0.23 <0.23 <0.23 <0.23 1.4 J 0.23 10 08/24/15 0.23 10 11/10/15 <0.23 <0.23 <0.23 <0.23 0.88 J 0.23 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC chloroethane 04/17/90 <10.0 <10.0 MCL = 07/11/91 <10.0 <10.0 FBAC = 10 (SWSL)05/28/92 <10.0 <10.0 <10.0 NCGQS = 3000 (2L Std)06/30/93 <10.0 <10.0 <10.0 2L Std = NE (pre- Jan. 2010)11/04/94 <10.0 <10.0 <10.0 <10.0 2L Std = 3000 (Jan. 2010)12/20/94 <10.0 <10.0 <10.0 <10.0 02/02/95 <10.0 <10.0 <10.0 <10.0 03/13/95 <10.0 <10.0 <10.0 <10.0 11/15/95 <10.0 <10.0 <10.0 <10.0 07/25/96 <10.0 <10.0 <10.0 <10.0 02/25/97 13.3 <10.0 <10.0 <10.0 09/03/97 <10.0 <10.0 <10.0 <10.0 05/04/98 17 <10.0 <10.0 <10.0 11/02/98 12 <10.0 <10.0 <10.0 04/26/99 13 <10.0 <10.0 <10.0 11/22/99 10 <10.0 <10.0 <10.0 05/23/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/13/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/04/02 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 03/12/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/18/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 12/08/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/22/04 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/30/04 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/01/05 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/02/05 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 05/22/06 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/27/06 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/12/07 17.1 3.3 J <0.1 1.7 J 7.7 J 5.8 J <0.1 8.9 J 0.1 10 12/12/07 2.9 J 0.7 J <0.1 0.5 J 1.3 J 0.5 J <0.1 2.4 J 0.1 10 06/17/08 4.8 J 1.4 J <0.1 0.6 J 2.2 J 1.7 J <0.1 2.6 J <0.1 0.1 10 ic, cc 11/05/08 3.3 J 0.5 J <0.1 0.4 J 1.5 J 1.2 J <0.1 1.9 J 1.8 J 0.1 10 05/19/09 4.6 J 0.91 J <0.3 0.4 J 2.1 J 1.8 J <0.3 1.9 J <0.3 0.3 10 11/18/09 3.3 J 0.79 J <0.3 <0.3 3.5 J 3 J <0.3 1.8 J <0.3 0.3 10 06/21/10 2.3 J 0.58 J <0.18 <0.18 1.1 J 0.83 J <0.18 0.95 J 0.83 J 0.18 10 11/18/10 2.5 J 0.77 J <0.3 <0.3 1.7 J 0.76 J <0.3 1.8 J 1.3 J 0.3 10 injection event (03-29-11)05/23/11 1.4 J <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 0.75 10 08/23/11 1.7 J 1.6 J 2.2 J 1 J 0.75 10 injection event (09-28-11)11/15/11 1.7 J <0.75 <0.75 <0.75 0.9 J <0.75 <0.75 1.3 J <0.75 0.75 10 02/21/12 1.2 J 0.88 J 1.5 J 0.81 J 0.23 10 injection event (04-14-12)06/05/12 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 10 10/09/12 <0.23 1 J <0.23 1.2 J 0.23 10 injection event (09-13-12)11/12/12 2.5 J 0.75 J <0.23 <0.23 1.5 J 0.68 J <0.23 1.6 J 1.2 J 0.23 10 02/18/13 1.4 J <0.23 1.3 J <0.23 0.23 10 05/13/13 4.6 J <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 2.6 J <0.23 0.23 10 08/21/13 <0.23 0.88 J 1.5 1.2 0.23 10 11/11/13 2.8 J <0.23 <0.23 0.53 J 1.8 J <0.23 <0.23 1.3 J 1.3 J 0.23 10 02/10/14 <0.23 <0.23 <0.23 <0.23 0.23 10 05/12/14 3.6 J <0.23 <0.23 <0.23 2.5 J <0.23 <0.23 2.6 J <0.23 0.23 10 08/18/14 1.4 J <0.23 1.8 J <0.23 0.23 10 11/11/14 <0.23 <0.23 <0.23 <0.23 1.9 J <0.23 <0.23 <0.23 <0.23 0.23 10 02/23/15 <0.23 <0.23 <0.23 <0.23 0.23 10 05/12/15 2.5 J <0.23 <0.23 <0.23 1.3 J <0.23 <0.23 1.8 J <0.23 0.23 10 08/24/15 <0.23 <0.23 <0.23 <0.23 0.23 10 11/10/15 1.6 J <0.23 <0.23 <0.23 0.74 J <0.23 <0.23 0.99 J <0.23 0.23 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 2,4-D 04/17/90 MCL = 70 07/11/91 FBAC = 2 (SWSL)05/28/92 NCGQS = 70 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 cc,ce 11/13/01 06/04/02 <1.0 <1.0 03/12/03 <1.0 <1.0 06/18/03 <1.0 <1.0 12/08/03 <1.0 <1.0 06/22/04 <1.0 <1.0 11/30/04 <1.0 <1.0 06/01/05 <1.0 <1.0 11/02/05 <1.0 <1.0 05/22/06 <1.0 <1.0 11/27/06 06/12/07 <0.03 <0.03 0.03 2 12/12/07 06/17/08 <0.03 <0.03 0.03 2 11/05/08 05/19/09 <0.091 <0.091 <0.091 0.091 2 11/18/09 06/21/10 <0.091 <0.091 <0.091 0.091 2 11/18/10 injection event (03-29-11)05/23/11 <0.15 <0.15 <0.15 0.15 2 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.16 <0.16 <0.16 0.16 2 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.16 <0.16 <0.16 0.16 2 08/21/13 11/11/13 02/10/14 05/12/14 <0.27 <0.27 <0.27 0.27 2 08/18/14 11/11/14 02/23/15 05/12/15 <0.27 <0.27 <0.27 0.27 2 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B 2,4-D 04/17/90 MCL = 70 07/11/91 FBAC = 2 (SWSL)05/28/92 NCGQS = 70 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 <1.0 <1.0 <1.0 1.3 R <1.0 <1.0 <1.0 cc,ce 11/13/01 06/04/02 <1.0 <1.0 03/12/03 <1.0 <1.0 06/18/03 <1.0 <1.0 12/08/03 <1.0 <1.0 06/22/04 <1.0 <1.0 11/30/04 <1.0 <1.0 06/01/05 <1.0 <1.0 11/02/05 <1.0 <1.0 05/22/06 <1.0 <1.0 11/27/06 06/12/07 <0.03 <0.03 0.03 2 12/12/07 06/17/08 <0.03 <0.03 11/05/08 05/19/09 <0.091 <0.091 <0.091 <0.091 0.091 2 11/18/09 06/21/10 <0.091 <0.091 <0.091 <0.091 0.091 2 11/18/10 injection event (03-29-11)05/23/11 <0.15 <0.15 <0.15 <0.15 0.15 2 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.16 <0.16 <0.16 <0.16 0.16 2 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 0.16 2 08/21/13 11/11/13 02/10/14 05/12/14 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 2 08/18/14 11/11/14 02/23/15 05/12/15 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 2 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 4,4'-DDD 04/17/90 MCL =07/11/91 FBAC = 0.1 (SWSL)05/28/92 NCGQS = 0.1 (2L Std)06/30/93 2L Std = 0.14 (pre- Jan. 2010)11/04/94 2L Std = 0.1 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.01 <0.01 0.01 0.1 12/12/07 06/17/08 <0.01 <0.01 0.01 0.1 11/05/08 05/19/09 <0.024 <0.024 <0.024 0.024 0.1 11/18/09 06/21/10 <0.013 <0.013 <0.013 0.013 0.1 11/18/10 injection event (03-29-11)05/23/11 <0.013 <0.013 <0.013 0.013 0.1 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.044 <0.044 <0.044 0.044 0.1 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.044 <0.044 <0.044 0.044 0.1 08/21/13 11/11/13 02/10/14 05/12/14 <0.044 <0.044 <0.044 0.044 0.1 08/18/14 11/11/14 02/23/15 05/12/15 <0.044 <0.044 <0.044 0.044 0.1 08/24/15 11/10/15 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 4,4'-DDD 04/17/90 MCL =07/11/91 FBAC = 0.1 (SWSL)05/28/92 NCGQS = 0.1 (2L Std)06/30/93 2L Std = 0.14 (pre- Jan. 2010)11/04/94 2L Std = 0.1 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.01 0.02 J 0.01 0.1 12/12/07 06/17/08 <0.01 <0.01 11/05/08 05/19/09 <0.024 <0.024 <0.024 <0.024 0.024 0.1 11/18/09 06/21/10 <0.013 <0.013 <0.013 <0.013 0.013 0.1 11/18/10 injection event (03-29-11)05/23/11 <0.013 <0.013 <0.013 <0.013 0.013 0.1 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.044 <0.044 <0.044 <0.044 0.044 0.1 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.044 <0.044 <0.044 <0.044 <0.044 <0.044 0.044 0.1 08/21/13 11/11/13 02/10/14 05/12/14 <0.044 <0.044 <0.044 <0.044 <0.044 <0.044 0.044 0.1 08/18/14 11/11/14 02/23/15 05/12/15 <0.044 <0.044 <0.044 <0.044 <0.044 <0.044 0.044 0.1 08/24/15 11/10/15 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 dibromochloromethane 04/17/90 MCL = 80 (trihalomethane)07/11/91 FBAC = 3 (SWSL)05/28/92 NCGQS = 0.4 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 06/21/10 11/18/10 injection event (03-29-11)05/23/11 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 08/21/13 11/11/13 <0.17 <0.17 <0.17 <0.17 0.47 J 0.17 3 02/10/14 0.17 3 05/12/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 08/18/14 0.17 3 11/11/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 02/23/15 0.17 3 05/12/15 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 08/24/15 0.17 3 11/10/15 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT SWSL QA/QC FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B LOD dibromochloromethane 04/17/90 MCL = 80 (trihalomethane)07/11/91 FBAC = 3 (SWSL)05/28/92 NCGQS = 0.4 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 06/21/10 11/18/10 injection event (03-29-11)05/23/11 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 08/21/13 11/11/13 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 02/10/14 <0.17 <0.17 <0.17 <0.17 0.17 3 05/12/14 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 08/18/14 <0.17 <0.17 <0.17 <0.17 0.17 3 11/11/14 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 02/23/15 <0.17 <0.17 <0.17 <0.17 0.17 3 05/12/15 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 08/24/15 <0.17 <0.17 <0.17 <0.17 0.17 3 11/10/15 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 3 Constituent Sample Date MW-15 MW-16 MW-17 MW-20 MW-21d MW-21s MW-22 MW-23 MW-24 LOD SWSL QA/QC CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS 1,2-dichlorobenzene 04/17/90 MCL = 600 07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 24 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/9804/26/99 11/22/99 05/23/00 11/29/00 06/05/0111/13/01 06/04/02 sr 03/12/03 ht 06/18/03 12/08/03 ic, cc06/22/04 ic, cc 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 06/21/10 <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 0.052 5 11/18/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 injection event (03-29-11)05/23/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 08/23/11 0.11 5 injection event (09-28-11)11/15/11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 02/21/12 0.19 5 injection event (04-14-12)06/05/12 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 10/09/12 0.19 5 injection event (09-13-12)11/12/12 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/18/13 0.19 5 05/13/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/21/13 0.19 5 11/11/13 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/10/14 0.19 5 05/12/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/18/14 0.19 5 11/11/14 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/23/15 0.19 5 05/12/15 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/24/15 0.19 5 11/10/15 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B 1,2-dichlorobenzene 04/17/90 MCL = 600 07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 24 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/9804/26/99 11/22/99 05/23/00 11/29/00 06/05/0111/13/01 06/04/02 sr 03/12/03 ht 06/18/03 12/08/03 ic, cc06/22/04 ic, cc 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 0.5 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 0.4 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 ic, cc 11/05/08 0.4 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 0.46 J <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 06/21/10 0.54 J <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 <0.052 0.052 5 11/18/10 0.61 J <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 5 injection event (03-29-11)05/23/11 0.66 J <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 08/23/11 <0.11 <0.11 <0.11 <0.11 0.11 5 injection event (09-28-11)11/15/11 0.66 J <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 02/21/12 <0.19 <0.19 <0.19 <0.19 0.19 5 injection event (04-14-12)06/05/12 0.5 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 10/09/12 <0.19 <0.19 <0.19 <0.19 0.19 5 injection event (09-13-12)11/12/12 0.56 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/18/13 <0.19 <0.19 <0.19 <0.19 0.19 5 05/13/13 0.63 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/21/13 <0.19 <0.19 <0.19 <0.19 0.19 5 11/11/13 0.56 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/10/14 <0.19 <0.19 <0.19 <0.19 0.19 5 05/12/14 0.64 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/18/14 <0.19 <0.19 <0.19 <0.19 0.19 5 11/11/14 0.62 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 02/23/15 <0.19 <0.19 <0.19 <0.19 0.19 5 05/12/15 0.51 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 08/24/15 <0.19 <0.19 <0.19 <0.19 0.19 5 11/10/15 0.64 J <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 5 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 1,4-dichlorobenzene 04/17/90 MCL = 75 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 6 (2L Std)06/30/93 2L Std = 1.4 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 2L Std = 6 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 5 R <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 sr 03/12/03 <5.0 <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 ic, cc 06/22/04 <5.0 <5.0 <5.0 ic, cc 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 1 J <0.1 0.1 1 12/12/07 <0.1 <0.1 1 J 0.2 J 0.1 1 06/17/08 <0.1 0.7 J <0.1 1 J 0.9 J 0.4 J 0.1 1 ic, cc 11/05/08 <0.1 0.6 J <0.1 <0.1 0.9 J 0.2 J 0.1 1 05/19/09 <0.38 0.63 J <0.38 <0.38 1.9 0.74 J 0.38 1 11/18/09 <0.38 <0.38 <0.38 <0.38 1.1 <0.38 0.38 1 06/21/10 <0.1 <0.1 0.59 J <0.1 0.95 J 0.77 J 0.1 1 11/18/10 <0.38 1 <0.38 <0.38 0.9 J 0.65 J 0.38 1 injection event (03-29-11)05/23/11 <0.79 <0.79 <0.79 <0.79 0.87 J 0.96 J 0.79 1 08/23/11 0.79 1 injection event (09-28-11)11/15/11 <0.79 <0.79 <0.79 <0.79 <0.79 0.79 1 02/21/12 0.19 1 injection event (04-14-12)06/05/12 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1 10/09/12 0.19 1 injection event (09-13-12)11/12/12 <0.19 <0.19 <0.19 0.79 J 0.6 J 0.19 1 02/18/13 0.19 1 05/13/13 <0.19 <0.19 <0.19 0.89 J 1.5 0.19 1 08/21/13 0.19 1 11/11/13 <0.19 <0.19 <0.19 1.3 0.63 J 0.19 1 02/10/14 0.19 1 05/12/14 <0.19 <0.19 <0.19 1.1 2.7 0.19 1 08/18/14 0.19 1 11/11/14 <0.19 <0.19 <0.19 1.2 0.64 J 0.19 1 02/23/15 0.19 1 05/12/15 <0.19 <0.19 <0.19 1.0 1.9 0.19 1 08/24/15 0.19 1 11/10/15 <0.19 <0.19 <0.19 1.4 1.1 0.19 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 1,4-dichlorobenzene 04/17/90 MCL = 75 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 6 (2L Std)06/30/93 2L Std = 1.4 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 2L Std = 6 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 11/02/98 6 R <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 5 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 sr 03/12/03 5 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 5 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ic, cc 06/22/04 5 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ic, cc 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 6 <5.0 <5.0 <5.0 05/22/06 6 <5.0 <5.0 6 <5.0 <5.0 <5.0 11/27/06 6 <5.0 <5.0 5 <5.0 <5.0 <5.0 06/12/07 5 <0.1 <0.1 6 1.4 0.6 J <0.1 1.9 0.1 1 12/12/07 5.9 0.4 J <0.1 6.1 1 J 0.2 J 0.97 J 1.6 0.1 1 06/17/08 5.2 J 0.5 J <0.1 6.4 J 1.4 J 0.3 J 0.8 J 1.7 J <0.1 0.1 1 ic, cc 11/05/08 5.3 0.3 J <0.1 6.2 1.4 1 J 0.2 J 1.9 1.1 0.1 1 05/19/09 6.8 0.47 J <0.38 6.9 2 1.7 1.2 2.4 1.5 0.38 1 11/18/09 5.9 0.55 J <0.38 6.6 1.9 1.6 1.9 2.9 1.4 0.38 1 06/21/10 6.2 0.54 J <0.1 5.9 1.8 1.4 1.1 1.3 <0.1 0.1 1 11/18/10 7.1 0.75 J <0.38 6.6 2 <0.38 1.1 2.8 <0.38 0.38 1 injection event (03-29-11)05/23/11 6.3 <0.79 <0.79 6.9 2 0.93 J 1.3 2.3 <0.79 0.79 1 08/23/11 2.1 1.3 3.2 <0.79 0.79 1 injection event (09-28-11)11/15/11 7.4 <0.79 <0.79 6.7 1.6 <0.79 2 3.1 <0.79 0.79 1 02/21/12 1.8 0.76 J 2.9 <0.19 0.19 1 injection event (04-14-12)06/05/12 4.5 <0.19 <0.19 4.8 <0.19 <0.19 <0.19 <0.19 <0.19 0.19 1 10/09/12 1.6 1.3 3.1 <0.19 0.19 1 injection event (09-13-12)11/12/12 7.1 0.64 J <0.19 7.6 2.2 <0.19 2.1 3.3 0.48 J 0.19 1 02/18/13 2.2 0.77 J 2.5 0.59 J 0.19 1 05/13/13 6.6 0.53 J <0.19 7.8 2.1 1 1.6 2.3 1 0.19 1 08/21/13 2.2 1.8 2.7 0.73 J 0.19 1 11/11/13 6.8 <0.19 <0.19 6.3 2.4 1 2.0 3.5 0.43 J 0.19 1 02/10/14 2.3 <0.19 1.9 <0.19 0.19 1 05/12/14 8.2 0.57 J <0.19 7.5 2.0 1.3 1.8 3.3 <0.19 0.19 1 08/18/14 2.5 1.2 4.1 <0.19 0.19 1 11/11/14 7.2 <0.19 <0.19 6.8 2.5 <0.19 2.4 3.7 <0.19 0.19 1 02/23/15 2.2 <0.19 2.6 <0.19 0.19 1 05/12/15 7.6 <0.19 <0.19 6.5 2.0 1.1 1.9 2.8 <0.19 0.19 1 08/24/15 2.2 1.6 3.7 <0.19 0.19 1 11/10/15 7.1 0.67 J <0.19 6.7 2.4 0.51 J 2.3 4.1 <0.19 0.19 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 dichlorodifluoromethane 04/17/90 MCL =07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 1000 (2L Std)06/30/93 2L Std = 1400 (pre- Jan. 2010)11/04/94 2L Std = 1000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 0.8 J <0.1 0.1 5 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 <0.38 <0.38 <0.38 0.38 5 11/18/09 06/21/10 <0.091 <0.091 <0.091 0.091 5 11/18/10 injection event (03-29-11)05/23/11 <0.56 <0.56 <0.56 0.56 5 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.2 <0.2 <0.2 0.2 5 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.2 <0.2 0.92 J 0.2 5 08/21/13 11/11/13 02/10/14 05/12/14 <0.2 <0.2 <0.2 0.2 5 08/18/14 11/11/14 02/23/15 05/12/15 <0.20 0.76 J 1.6 J 0.20 5 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B dichlorodifluoromethane 04/17/90 MCL =07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 1000 (2L Std)06/30/93 2L Std = 1400 (pre- Jan. 2010)11/04/94 2L Std = 1000 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 <0.1 <0.1 0.1 5 ic, cc 11/05/08 <0.1 <0.1 0.73 J <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 <0.38 <0.38 <0.38 <0.38 0.38 5 11/18/09 06/21/10 <0.091 <0.091 <0.091 <0.091 0.091 5 11/18/10 injection event (03-29-11)05/23/11 <0.56 <0.56 <0.56 <0.56 0.56 5 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.2 <0.2 <0.2 <0.2 0.2 5 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5 08/21/13 11/11/13 02/10/14 05/12/14 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 5 08/18/14 11/11/14 02/23/15 05/12/15 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.20 5 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 1,1-dichloroethane 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL =07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 9.5 13 NCGQS = 6 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 14.8 10.8 2L Std = 70 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 24 30 2L Std = 6 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 16 14 02/02/95 <5.0 <5.0 <5.0 <5.0 16 18 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11 J 11 J cc 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 14 18 J is 07/25/96 <5.0 <5.0 <5.0 <5.0 13 11 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 9 10 09/03/97 <5.0 <5.0 <5.0 16 9 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6 8 11/02/98 10 R <5.0 <5.0 11 9 04/26/99 <5.0 <5.0 <5.0 6 8 11/22/99 <5.0 <5.0 <5.0 8 7 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 7 11/29/00 <5.0 <5.0 <5.0 7 11 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6 11/13/01 <5.0 7 J 6 J cc 06/04/02 <5.0 <5.0 <5.0 cc 03/12/03 <5.0 <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 <5.0 6 J ic, cc, ss 12/08/03 <5.0 <5.0 6 J ic, cc 06/22/04 <5.0 <5.0 7 J ic, cc 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 6 11/02/05 <5.0 7 7 05/22/06 <5.0 <5.0 6 11/27/06 <5.0 6 5 06/12/07 <0.2 <0.2 4.3 J 7.5 0.2 5 12/12/07 <0.2 <0.2 4.3 J 5.9 0.2 5 06/17/08 <0.2 <0.2 <0.2 5 J 3.9 J 6.2 J 0.2 5 ic, cc 11/05/08 <0.2 <0.2 <0.2 <0.2 4.6 J 4.1 J 0.2 5 05/19/09 <0.33 <0.33 <0.33 <0.33 6.4 8 0.33 5 11/18/09 <0.33 <0.33 <0.33 <0.33 5.6 7.5 0.33 5 06/21/10 <0.05 <0.05 <0.05 <0.05 4.7 J 6.6 0.05 5 11/18/10 <0.33 <0.33 <0.33 <0.33 4.1 J 7 0.33 5 injection event (03-29-11)05/23/11 <0.08 <0.08 <0.08 <0.08 3.4 J 5.9 0.08 5 08/23/11 0.08 5 injection event (09-28-11)11/15/11 <0.08 <0.08 <0.08 2.8 J 5.2 0.08 5 02/21/12 0.13 5 injection event (04-14-12)06/05/12 <0.13 <0.13 <0.13 1.1 J 3.7 J 0.13 5 10/09/12 0.13 5 injection event (09-13-12)11/12/12 <0.13 <0.13 <0.13 2.8 J 6.3 0.13 5 02/18/13 0.13 5 05/13/13 <0.13 <0.13 <0.13 3.3 J 6 0.13 5 08/21/13 0.13 5 11/11/13 <0.13 2.1 J <0.13 3.6 J 4.2 J 0.13 5 02/10/14 0.13 5 05/12/14 <0.13 <0.13 <0.13 3.9 J 7.3 0.13 5 08/18/14 0.13 5 11/11/14 <0.13 <0.13 <0.13 4.1 J 4.9 J 0.13 5 02/23/15 0.13 5 05/12/15 <0.13 <0.13 <0.13 3.8 J 6.3 0.13 5 08/24/15 0.13 5 11/10/15 <0.13 <0.13 <0.13 4.0 J 5.9 0.13 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 1,1-dichloroethane 04/17/90 <5.0 <5.0 MCL =07/11/91 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 54 <5.0 <5.0 NCGQS = 6 (2L Std)06/30/93 39.8 <5.0 <5.0 2L Std = 70 (pre- Jan. 2010)11/04/94 43 6 <5.0 <5.0 2L Std = 6 (Jan. 2010)12/20/94 20 <5.0 <5.0 <5.0 02/02/95 28 <5.0 <5.0 <5.0 03/13/95 32 J <5.0 <5.0 <5.0 cc 11/15/95 38 6 <5.0 <5.0 is 07/25/96 72 8 <5.0 <5.0 02/25/97 57 12 <5.0 <5.0 09/03/97 71 9 <5.0 <5.0 05/04/98 56 10 <5.0 <5.0 11/02/98 67 9 <5.0 <5.0 04/26/99 52 9 <5.0 <5.0 11/22/99 45 9 <5.0 <5.0 05/23/00 46 9 <5.0 <5.0 24 42 <5.0 11/29/00 49 9 <5.0 <5.0 42 36 <5.0 06/05/01 42 7 <5.0 <5.0 25 35 <5.0 11/13/01 49 J 10 J <5.0 <5.0 41 J 33 J <5.0 cc 06/04/02 31 J 7 J <5.0 <5.0 22 J 20 J <5.0 cc 03/12/03 30 J 9 J <5.0 <5.0 24 J 14 J <5.0 ht 06/18/03 30 J 8 J <5.0 <5.0 22 J 22 J <5.0 ic, cc, ss 12/08/03 26 J 5 J <5.0 <5.0 22 J 20 J <5.0 ic, cc 06/22/04 36 J 6 J <5.0 <5.0 25 J 24 J <5.0 ic, cc 11/30/04 19 J <5.0 <5.0 <5.0 16 J 8 J <5.0 ic, cc 06/01/05 26 5 <5.0 <5.0 19 18 <5.0 11/02/05 31 9 <5.0 <5.0 28 25 7 05/22/06 19 6 <5.0 <5.0 20 20 7 11/27/06 19 5 <5.0 <5.0 17 17 7 06/12/07 18.7 5.6 <0.2 <0.2 16.2 15.4 3.7 J 25.7 0.2 5 12/12/07 17 5.6 <0.2 <0.2 12.2 8.5 4.9 J 23.4 0.2 5 06/17/08 11 J 5.2 J <0.2 <0.2 13 J 13.3 J 3.1 J 26.2 J 3.4 J 0.2 5 ic, cc 11/05/08 11.7 3.7 J <0.2 <0.2 13.2 13.1 0.6 J 25.6 18.6 0.2 5 05/19/09 17 5.2 <0.33 <0.33 16 16 5 27 21 0.33 5 11/18/09 14 5.8 <0.33 <0.33 14 14 7 30 19 0.33 5 06/21/10 11 3.9 J <0.05 <0.05 11 9.9 4.8 J 16 13 0.05 5 11/18/10 12 4.6 J <0.33 <0.33 15 13 7.2 28 19 0.33 5 injection event (03-29-11)05/23/11 7.8 2.7 J <0.08 <0.08 10 9 6 21 11 0.08 5 08/23/11 13 14 27 15 0.08 5 injection event (09-28-11)11/15/11 9 3.2 J <0.08 <0.08 8.6 10 6 21 14 0.08 5 02/21/12 11 13 27 12 0.13 5 injection event (04-14-12)06/05/12 6.1 0.56 J <0.13 <0.13 9.3 6.6 5 22 12 0.13 5 10/09/12 9.2 12 21 16 0.13 5 injection event (09-13-12)11/12/12 8.2 3 J <0.13 <0.13 9.9 8.5 7 21 16 0.13 5 02/18/13 11 9.2 24 17 0.13 5 05/13/13 9.1 2.5 J <0.13 <0.13 11 10 7.1 22 14 0.13 5 08/21/13 9.7 11 20 14 0.13 5 11/11/13 6.8 <0.13 <0.13 <0.13 8.6 7.0 5.7 15 10 0.13 5 02/10/14 9.8 8.9 19 12 0.13 5 05/12/14 8.9 3.4 J <0.13 <0.13 9.4 9.3 7.4 19 10 0.13 5 08/18/14 11 9.6 20 14 0.13 5 11/11/14 6.2 2.4 J <0.13 <0.13 8.9 6.7 5.6 14 11 0.13 5 02/23/15 8.9 9.2 18 10 0.13 5 05/12/15 7.3 1.9 J <0.13 <0.13 8.8 9.0 7.1 17 7.8 0.13 5 08/24/15 8.0 6.7 13 10 0.13 5 11/10/15 6.3 2.3 J 9.2 8.2 6.4 15 10 0.13 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 1,2-dichloroethane 04/17/90 MCL =5 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 0.4 (2L Std)06/30/93 2L Std = 0.38 (pre- Jan. 2010)11/04/94 2L Std = 0.4 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 11/18/09 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 06/21/10 <0.082 <0.082 <0.082 <0.082 <0.082 <0.082 0.082 1 11/18/10 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 injection event (03-29-11)05/23/11 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 0.47 1 08/23/11 0.47 1 injection event (09-28-11)11/15/11 <0.47 <0.47 <0.47 <0.47 <0.47 0.47 1 02/21/12 0.21 1 injection event (04-14-12)06/05/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 10/09/12 0.21 1 injection event (09-13-12)11/12/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 02/18/13 0.21 1 05/13/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/21/13 0.21 1 11/11/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 02/10/14 0.21 1 05/12/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/18/14 0.21 1 11/11/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 02/23/15 0.21 1 05/12/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/24/15 0.21 1 11/10/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B 1,2-dichloroethane 04/17/90 MCL =5 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 0.4 (2L Std)06/30/93 2L Std = 0.38 (pre- Jan. 2010)11/04/94 2L Std = 0.4 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 0.8 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 J 0.1 1 06/17/08 0.6 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.5 J <0.1 0.1 1 ic, cc 11/05/08 0.5 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 0.94 J <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 11/18/09 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 06/21/10 0.54 J <0.082 <0.082 <0.082 <0.082 <0.082 <0.082 <0.082 <0.082 0.082 1 11/18/10 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 injection event (03-29-11)05/23/11 0.6 J <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 0.47 1 08/23/11 <0.47 <0.47 0.62 J <0.47 0.47 1 injection event (09-28-11)11/15/11 0.6 J <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 0.53 J <0.47 0.47 1 02/21/12 <0.21 <0.21 <0.21 <0.21 0.21 1 injection event (04-14-12)06/05/12 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 10/09/12 <0.21 <0.21 <0.21 <0.21 0.21 1 injection event (09-13-12)11/12/12 0.62 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.52 J <0.21 0.21 1 02/18/13 <0.21 <0.21 0.62 J <0.21 0.21 1 05/13/13 0.45 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/21/13 <0.21 <0.21 0.60 J <0.21 0.21 1 11/11/13 0.46 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.56 J 0.43 J 0.21 1 02/10/14 <0.21 <0.21 <0.21 <0.21 0.21 1 05/12/14 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/18/14 <0.21 <0.21 0.61 J <0.21 0.21 1 11/11/14 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 02/23/15 <0.21 <0.21 <0.21 <0.21 0.21 1 05/12/15 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 08/24/15 <0.21 <0.21 <0.21 <0.21 0.21 1 11/10/15 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 1,1-dichloroethene 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 7 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 7 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 5 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 5 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 0.24 5 11/18/09 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 0.24 5 06/21/10 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 5 11/18/10 <0.24 <0.24 <0.24 <0.24 <0.24 <0.24 0.24 5 injection event (03-29-11)05/23/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 5 08/23/11 0.6 5 injection event (09-28-11)11/15/11 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 5 02/21/12 0.21 5 injection event (04-14-12)06/05/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 10/09/12 0.21 5 injection event (09-13-12)11/12/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/18/13 0.21 5 05/13/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/21/13 0.21 5 11/11/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/10/14 0.21 5 05/12/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/18/14 0.21 5 11/11/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/23/15 0.21 5 05/12/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/24/15 0.21 5 11/10/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 1,1-dichloroethene 04/17/90 <5.0 <5.0 MCL = 7 07/11/91 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 <5.0 <5.0 <5.0 NCGQS = 7 (2L Std)06/30/93 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 07/25/96 6 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 09/03/97 5 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 1.5 J <0.1 <0.1 <0.1 0.6 J <0.1 <0.1 1.4 J 0.1 5 12/12/07 1.4 J <0.1 <0.1 <0.1 0.3 J <0.1 <0.1 1.5 J 0.1 5 06/17/08 0.8 J <0.1 <0.1 <0.1 0.6 J <0.1 <0.1 1.5 J <0.1 0.1 5 ic, cc 11/05/08 0.7 J <0.1 <0.1 <0.1 0.4 J 0.3 J <0.2 1.1 J 0.4 J 0.1 5 05/19/09 1.1 J <0.24 <0.24 <0.24 0.43 J <0.24 <0.24 1.1 J 0.62 J 0.24 5 11/18/09 0.74 J <0.24 <0.24 <0.24 0.43 J <0.24 <0.24 1.4 J 0.41 J 0.24 5 06/21/10 0.73 J <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.71 J <0.15 0.15 5 11/18/10 0.73 J <0.24 <0.24 <0.24 0.41 J <0.24 <0.24 1.4 J <0.24 0.24 5 injection event (03-29-11)05/23/11 0.61 J <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 1.2 J <0.6 0.6 5 08/23/11 <0.6 <0.6 1.3 J <0.6 0.6 5 injection event (09-28-11)11/15/11 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.75 J <0.6 0.6 5 02/21/12 <0.21 <0.21 0.98 J <0.21 0.21 5 injection event (04-14-12)06/05/12 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.58 J <0.21 0.21 5 10/09/12 <0.21 <0.21 <0.21 <0.21 0.21 5 injection event (09-13-12)11/12/12 0.43 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/18/13 <0.21 <0.21 0.74 J <0.21 0.21 5 05/13/13 0.8 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.44 J <0.21 0.21 5 08/21/13 <0.21 <0.21 0.47 J <0.21 0.21 5 11/11/13 0.49 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.59 J <0.21 0.21 5 02/10/14 <0.21 <0.21 0.51 J <0.21 0.21 5 05/12/14 0.72 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.59 J <0.21 0.21 5 08/18/14 <0.21 <0.21 0.82 J <0.21 0.21 5 11/11/14 0.41 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.47 J <0.21 0.21 5 02/23/15 <0.21 <0.21 0.70 J <0.21 0.21 5 05/12/15 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.55 J <0.21 0.21 5 08/24/15 <0.21 <0.21 0.59 J <0.21 0.21 5 11/10/15 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.57 J <0.21 0.21 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 cis-1,2-dichloroethene 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 70 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 70 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/04/94 8 R <5.0 <5.0 <5.0 6 10 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 is 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 8 5 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 8 R <5.0 <5.0 5 5 04/26/99 <5.0 <5.0 <5.0 <5.0 6 11/22/99 <5.0 <5.0 <5.0 5 5 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6 11/29/00 <5.0 <5.0 <5.0 <5.0 10 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6 11/13/01 <5.0 <5.0 6 J cc 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 ht 06/18/03 <5.0 <5.0 <5.0 <5.0 6 J ic, cc, ss 12/08/03 <5.0 <5.0 6 J ic, cc 06/22/04 <5.0 <5.0 7 J ic, cc 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 6 11/02/05 <5.0 <5.0 6 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 2.9 J 5.6 0.1 5 12/12/07 <0.1 <0.1 2.5 J 3.3 J 0.1 5 06/17/08 <0.1 1 J <0.1 5 J 2.4 J 4.8 J 0.1 5 ic, cc 11/05/08 <0.1 0.9 J <0.1 <0.1 3.2 J 2.4 J 0.1 5 05/19/09 <0.36 0.67 J <0.36 <0.36 4.3 J 5.8 0.36 5 11/18/09 <0.36 1 J <0.36 <0.36 3.5 J 3.6 J 0.36 5 06/21/10 <0.075 <0.075 0.68 J <0.075 2.8 J 5.8 0.075 5 11/18/10 <0.36 1.6 J <0.36 <0.36 3.1 J 4.2 J 0.36 5 injection event (03-29-11)05/23/11 <0.72 <0.72 <0.72 <0.72 2.1 J 4.7 J 0.72 5 08/23/11 injection event (09-28-11)11/15/11 <0.72 <0.72 <0.72 2.3 J 2.9 J 0.72 5 02/21/12 injection event (04-14-12)06/05/12 <0.15 <0.15 <0.15 2.1 J 4 J 0.15 5 10/09/12 injection event (09-13-12)11/12/12 <0.15 <0.15 <0.15 1.7 J 2.4 J 0.15 5 02/18/13 05/13/13 <0.15 <0.15 <0.15 2.4 J 6 0.15 5 08/21/13 0.15 5 11/11/13 <0.15 2.7 J <0.15 2.8 J 1.9 J 0.15 5 02/10/14 0.15 5 05/12/14 <0.15 <0.15 <0.15 1.9 J 5.6 0.15 5 08/18/14 0.15 5 11/11/14 <0.15 <0.15 <0.15 2.3 J 1.5 J 0.15 5 02/23/15 0.15 5 05/12/15 <0.15 <0.15 <0.15 2.2 J 5.3 0.15 5 08/24/15 0.15 5 11/10/15 <0.15 <0.15 <0.15 3.0 J 2.2 J 0.15 5 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B cis-1,2-dichloroethene 04/17/90 <5.0 <5.0 MCL = 70 07/11/91 <5.0 <5.0 FBAC = 5 (SWSL)05/28/92 <5.0 <5.0 <5.0 NCGQS = 70 (2L Std)06/30/93 <5.0 <5.0 <5.0 11/04/94 24 <5.0 <5.0 58 12/20/94 11 <5.0 <5.0 11 02/02/95 17 <5.0 <5.0 39 03/13/95 19 <5.0 <5.0 21 11/15/95 28 <5.0 <5.0 26 J is 07/25/96 53 <5.0 <5.0 23 02/25/97 50 <5.0 <5.0 23 09/03/97 98 <5.0 <5.0 22 05/04/98 95 <5.0 <5.0 20 11/02/98 130 <5.0 <5.0 20 04/26/99 126 <5.0 <5.0 19 11/22/99 119 <5.0 <5.0 11 05/23/00 124 <5.0 <5.0 9 11 12 <5.0 11/29/00 157 <5.0 <5.0 9 20 13 <5.0 06/05/01 151 <5.0 <5.0 8 16 14 <5.0 11/13/01 185 J 6 J < 5.0 9 J 25 J 14 J <5.0 cc 06/04/02 166 7 <5.0 <5.0 20 13 <5.0 03/12/03 169 J 7 J <5.0 <5.0 20 J 9 J <5.0 ht 06/18/03 182 J 10 J <5.0 <5.0 23 J 17 J <5.0 ic, cc, ss 12/08/03 160 J 6 J <5.0 <5.0 26 J 16 J <5.0 ic, cc 06/22/04 198 J 8 J <5.0 <5.0 31 J 21 J <5.0 ic, cc 11/30/04 118 J <5.0 <5.0 <5.0 19 J 8 J <5.0 ic, cc 06/01/05 146 9 <5.0 <5.0 26 24 <5.0 11/02/05 232 14 <5.0 <5.0 34 26 <5.0 05/22/06 97 8 <5.0 <5.0 20 17 <5.0 11/27/06 185 11 <5.0 <5.0 27 19 <5.0 06/12/07 166 11.8 <0.1 1.2 J 29.6 22.1 2.3 J 53.6 0.1 5 12/12/07 178 11.4 <0.1 1.1 J 20.7 9.9 3.5 J 57 0.1 5 06/17/08 133 J 11.7 J <0.1 1 J 26.1 J 18.8 J 2.5 J 60.1 J 7.2 J 0.1 5 ic, cc 11/05/08 135 7.6 <0.1 0.8 J 28 22.2 0.6 J 63.9 33.7 0.1 5 05/19/09 170 8.8 <0.36 0.68 J 35 29 3.3 J 59 35 0.36 5 11/18/09 160 11 <0.36 0.76 J 34 29 5.8 75 38 0.36 5 06/21/10 130 7.8 <0.075 0.58 J 32 24 3.5 J 43 25 0.075 5 11/18/10 150 7.9 <0.36 0.73 J 37 27 4.9 J 81 36 0.36 5 injection event (03-29-11)05/23/11 94 4.5 J <0.72 <0.72 22 18 3.8 J 48 19 0.72 5 08/23/11 31 29 77 28 0.72 5 injection event (09-28-11)11/15/11 130 5.6 <0.72 <0.72 21 21 5.4 45 29 0.72 5 02/21/12 25 21 63 23 0.15 5 injection event (04-14-12)06/05/12 110 3.6 J <0.15 0.55 J <0.15 15 4.7 J 35 22 0.15 5 10/09/12 17 17 8.5 28 0.15 5 injection event (09-13-12)11/12/12 120 4.2 J <0.15 0.41 J 22 9.1 5.4 13 28 0.15 5 02/18/13 26 5.2 35 26 0.15 5 05/13/13 140 3.3 J <0.15 <0.15 29 4.5 J 5.6 32 28 0.15 5 08/21/13 28 4.7 35 25 0.15 5 11/11/13 110 <0.15 <0.15 0.48 J 29 2.0 J 4.8 J 48 18 0.15 5 02/10/14 30 8 46 15 0.15 5 05/12/14 130 2.9 J <0.15 0.41 J 24 11 4.2 J 46 14 0.15 5 08/18/14 36 18 83 17 0.15 5 11/11/14 110 2.3 J <0.15 <0.15 29 13 4.7 J 68 16 0.15 5 02/23/15 32 20 85 18 0.15 5 05/12/15 140 1.9 J <0.15 <0.15 29 19 5.3 74 12 0.15 5 08/24/15 26 16 64 16 0.15 5 11/10/15 97 1.9 J <0.15 <0.15 26 17 4.9 J 70 17 0.15 5 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 trans-1,2-dichloroethene 04/17/90 MCL = 100 07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 100 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 5 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 5 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 5 05/19/09 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 5 11/18/09 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 5 06/21/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 11/18/10 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 5 injection event (03-29-11)05/23/11 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 5 08/23/11 0.12 5 injection event (09-28-11)11/15/11 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 5 02/21/12 0.21 5 injection event (04-14-12)06/05/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 10/09/12 0.21 5 injection event (09-13-12)11/12/12 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/18/13 0.21 5 05/13/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/21/13 0.21 5 11/11/13 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/10/14 0.21 5 05/12/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/18/14 0.21 5 11/11/14 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/23/15 0.21 5 05/12/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/24/15 0.21 5 11/10/15 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC trans-1,2-dichloroethene 04/17/90 MCL = 100 07/11/91 FBAC = 5 (SWSL)05/28/92 NCGQS = 100 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 1.1 J <0.1 <0.1 0.8 J <0.1 <0.1 <0.1 <0.1 0.1 5 12/12/07 1.1 J <0.1 <0.1 0.5 J <0.1 <0.1 <0.1 0.4 J 0.1 5 06/17/08 1 J <0.1 <0.1 0.5 J <0.1 <0.1 <0.1 0.4 J <0.1 0.1 5 ic, cc 11/05/08 0.8 J <0.1 <0.1 0.4 J 0.4 J 0.2 J <0.2 0.6 J 0.3 J 0.1 5 05/19/09 0.99 J <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 <0.34 0.34 5 11/18/09 0.88 J <0.34 <0.34 0.43 J 0.42 J <0.34 <0.34 0.71 J 0.44 J 0.34 5 06/21/10 0.83 J <0.11 <0.11 0.42 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5 11/18/10 1.2 J <0.34 <0.34 0.49 J <0.34 <0.34 <0.34 0.66 J <0.34 0.34 5 injection event (03-29-11)05/23/11 1 J <0.12 <0.12 0.42 J <0.12 <0.12 <0.12 0.53 J <0.12 0.12 5 08/23/11 <0.12 <0.12 0.41 J <0.12 0.12 5 injection event (09-28-11)11/15/11 0.93 J <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 5 02/21/12 <0.21 <0.21 <0.21 <0.21 0.21 5 injection event (04-14-12)06/05/12 0.57 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 10/09/12 <0.21 <0.21 <0.21 <0.21 0.21 5 injection event (09-13-12)11/12/12 0.78 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/18/13 <0.21 <0.21 <0.21 <0.21 0.21 5 05/13/13 0.86 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/21/13 <0.21 <0.21 <0.21 <0.21 0.21 5 11/11/13 0.72 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 02/10/14 <0.21 <0.21 <0.21 <0.21 0.21 5 05/12/14 0.76 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/18/14 <0.21 <0.21 0.45 J <0.21 0.21 5 11/11/14 0.65 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.43 J <0.21 0.21 5 02/23/15 <0.21 <0.21 0.58 J <0.21 0.21 5 05/12/15 0.73 J <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 <0.21 0.21 5 08/24/15 <0.21 <0.21 0.50 J <0.21 0.21 5 11/10/15 0.74 J <0.21 <0.21 0.40 J <0.21 <0.21 <0.21 0.60 J <0.21 0.21 5 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 dichloromethane 04/17/90 <10.0 <10.0 <10.0 <10.0 <10.0 (methylene chloride)07/11/91 <10.0 <10.0 <10.0 <10.0 <10.0 MCL = 5 05/28/92 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 FBAC = 1 (SWSL)06/30/93 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 NCGQS = 5 (2L Std)11/04/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 2L Std = 4.6 (pre- Jan. 2010)12/20/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 i 2L Std = 5 (Jan. 2010)02/02/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 03/13/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/15/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 07/25/96 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 f 02/25/97 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 i,f 09/03/97 <10.0 <10.0 <10.0 <10.0 <10.0 i,f 05/04/98 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 i,f 11/02/98 <10.0 <10.0 <10.0 <10.0 <10.0 i,f,t 04/26/99 <10.0 <10.0 <10.0 <10.0 <10.0 i,f,t 11/22/99 <10.0 <10.0 <10.0 <10.0 <10.0 i 05/23/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 f,t 11/13/01 <10.0 <10.0 <10.0 i,f 06/04/02 <10.0 <10.0 <10.0 03/12/03 <10.0 <10.0 <10.0 <10.0 06/18/03 <10.0 <10.0 <10.0 <10.0 12/08/03 <10.0 <10.0 <10.0 06/22/04 <10.0 <10.0 <10.0 11/30/04 <10.0 <10.0 <10.0 06/01/05 <10.0 11/02/05 <10.0 05/22/06 <10.0 <10.0 <10.0 i,t 11/27/06 <10.0 <10.0 <10.0 06/12/07 <0.6 <0.6 <0.6 <0.6 0.6 1 f 12/12/07 <0.6 <0.6 <0.6 <0.6 0.6 1 06/17/08 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 ic, cc 11/05/08 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 t 05/19/09 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 11/18/09 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 06/21/10 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 0.07 1 11/18/10 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 injection event (03-29-11)05/23/11 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/23/11 injection event (09-28-11)11/15/11 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/21/12 injection event (04-14-12)06/05/12 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 10/09/12 injection event (09-13-12)11/12/12 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 02/18/13 05/13/13 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/21/13 0.23 1 11/11/13 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 02/10/14 0.23 1 05/12/14 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/18/14 0.23 1 11/11/14 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 02/23/15 0.23 1 05/12/15 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/24/15 0.23 1 11/10/15 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B dichloromethane 04/17/90 <10.0 <10.0 (methylene chloride)07/11/91 <10.0 <10.0 MCL = 5 05/28/92 <10.0 <10.0 <10.0 FBAC = 1 (SWSL)06/30/93 <10.0 <10.0 <10.0 NCGQS = 5 (2L Std)11/04/94 <10.0 <10.0 <10.0 <10.0 2L Std = 4.6 (pre- Jan. 2010)12/20/94 <10.0 <10.0 <10.0 82 B i 2L Std = 5 (Jan. 2010)02/02/95 <10.0 <10.0 <10.0 <10.0 03/13/95 <10.0 <10.0 <10.0 <10.0 11/15/95 <10.0 <10.0 <10.0 <10.0 07/25/96 <10.0 <10.0 <10.0 <10.0 f 02/25/97 <10.0 <10.0 <10.0 <10.0 i,f 09/03/97 <10.0 <10.0 <10.0 <10.0 i,f 05/04/98 <10.0 <10.0 <10.0 <10.0 i,f 11/02/98 <10.0 <10.0 <10.0 <10.0 i,f,t 04/26/99 <10.0 <10.0 <10.0 <10.0 i,f,t 11/22/99 <10.0 <10.0 <10.0 <10.0 i 05/23/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 f,t 11/13/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 i,f 06/04/02 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 03/12/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/18/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 12/08/03 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/22/04 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/30/04 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/01/05 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/02/05 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 05/22/06 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 i,t 11/27/06 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/12/07 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 f 12/12/07 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 06/17/08 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 ic, cc 11/05/08 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 <0.6 0.6 1 t 05/19/09 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 11/18/09 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 06/21/10 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 0.07 1 11/18/10 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 <0.53 0.53 1 injection event (03-29-11)05/23/11 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/23/11 0.45 J 0.44 J <0.14 0.14 1 injection event (09-28-11)11/15/11 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/21/12 <0.23 <0.23 <0.23 <0.23 0.23 1 injection event (04-14-12)06/05/12 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 10/09/12 <0.23 <0.23 <0.23 <0.23 0.23 1 injection event (09-13-12)11/12/12 <0.23 <0.23 <0.23 <0.23 <0.23 0.64 J <0.23 0.6 J <0.23 0.23 1 02/18/13 <0.23 <0.23 <0.23 <0.23 0.23 1 05/13/13 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/21/13 <0.23 <0.23 <0.23 <0.23 0.23 1 11/11/13 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 02/10/14 <0.23 <0.23 <0.23 <0.23 0.23 1 05/12/14 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/18/14 <0.23 <0.23 <0.23 <0.23 0.23 1 11/11/14 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 02/23/15 <0.23 <0.23 <0.23 <0.23 0.23 1 05/12/15 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 08/24/15 <0.23 <0.23 <0.23 <0.23 0.23 1 11/10/15 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 0.23 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 1,2-dichloropropane 04/17/90 MCL = 5 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 0.6 (2L Std)06/30/93 2L Std = 0.51 (pre- Jan. 2010)11/04/94 2L Std = 0.6 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 <0.1 <0.1 1 J 0.4 J 0.6 J 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 <0.2 <0.2 <0.2 <0.2 0.6 J 0.75 J 0.2 1 11/18/09 <0.2 <0.2 <0.2 <0.2 0.46 J 0.7 J 0.2 1 06/21/10 <0.098 <0.098 <0.098 <0.098 0.42 J 0.63 J 0.098 1 11/18/10 <0.2 <0.2 <0.2 <0.2 0.45 J 0.73 J 0.2 1 injection event (03-29-11)05/23/11 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 0.59 1 08/23/11 0.59 1 injection event (09-28-11)11/15/11 <0.59 <0.59 <0.59 <0.59 <0.59 0.59 1 02/21/12 0.1 1 injection event (04-14-12)06/05/12 <0.1 <0.1 <0.1 <0.1 0.51 J 0.1 1 10/09/12 0.1 1 injection event (09-13-12)11/12/12 <0.1 <0.1 <0.1 <0.1 0.61 J 0.1 1 02/18/13 0.1 1 05/13/13 <0.1 <0.1 <0.1 <0.1 0.89 J 0.1 1 08/21/13 0.1 1 11/11/13 <0.10 <0.10 <0.10 <0.10 0.43 J 0.10 1 02/10/14 0.10 1 05/12/14 <0.10 <0.10 <0.10 <0.10 0.47 J 0.10 1 08/18/14 0.10 1 11/11/14 <0.10 <0.10 <0.10 <0.10 0.67 J 0.10 1 02/23/15 0.10 1 05/12/15 <0.10 <0.10 <0.10 <0.10 0.57 J 0.10 1 08/24/15 0.10 1 11/10/15 <0.10 <0.10 <0.10 <0.10 0.58 J 0.10 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 1,2-dichloropropane 04/17/90 MCL = 5 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 0.6 (2L Std)06/30/93 2L Std = 0.51 (pre- Jan. 2010)11/04/94 2L Std = 0.6 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 0.6 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 0.7 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 0.65 J <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.43 J <0.2 0.2 1 11/18/09 0.66 J <0.2 <0.2 <0.2 <0.2 <0.2 0.48 J 0.49 J <0.2 0.2 1 06/21/10 0.63 J <0.098 <0.098 <0.098 <0.098 <0.098 <0.098 <0.098 <0.098 0.098 1 11/18/10 1.1 <0.2 <0.2 <0.2 <0.2 <0.2 0.53 J 0.67 J <0.2 0.2 1 injection event (03-29-11)05/23/11 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 0.59 1 08/23/11 <0.59 <0.59 <0.59 <0.59 0.59 1 injection event (09-28-11)11/15/11 0.77 J <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 <0.59 0.59 1 02/21/12 <0.1 <0.1 0.49 J <0.1 0.1 1 injection event (04-14-12)06/05/12 0.58 J <0.1 <0.1 <0.1 <0.1 <0.1 0.54 J <0.1 <0.1 0.1 1 10/09/12 <0.1 <0.1 <0.1 <0.1 0.1 1 injection event (09-13-12)11/12/12 0.76 J <0.1 <0.1 <0.1 <0.1 <0.1 0.42 J <0.1 <0.1 0.1 1 02/18/13 <0.1 <0.1 0.47 J <0.1 0.1 1 05/13/13 0.55 J <0.1 <0.1 <0.1 <0.1 <0.1 0.64 J 0.53 J <0.1 0.1 1 08/21/13 <0.1 <0.1 0.57 J <0.1 0.1 1 11/11/13 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.42 J <0.10 <0.10 0.10 1 02/10/14 <0.10 <0.10 0.52 J <0.10 0.10 1 05/12/14 0.59 J <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.44 J <0.10 0.10 1 08/18/14 <0.10 <0.10 0.55 J <0.10 0.10 1 11/11/14 0.66 J <0.10 <0.10 <0.10 <0.10 <0.10 0.49 J <0.10 <0.10 0.10 1 02/23/15 <0.10 <0.10 <0.10 <0.10 0.10 1 05/12/15 0.54 J <0.10 <0.10 <0.10 <0.10 <0.10 0.45 J 0.45 J <0.10 0.10 1 08/24/15 <0.10 <0.10 0.44 J <0.10 0.10 1 11/10/15 0.57 J <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.51 J <0.10 0.10 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 heptachlor epoxide 04/17/90 MCL = 0.2 07/11/91 FBAC = 0.075 (SWSL)05/28/92 NCGQS = 0.004 (2L Std)06/30/93 2L Std = 0.0038 (pre- Jan. 2010)11/04/94 2L Std = 0.004 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.01 <0.01 0.01 0.075 12/12/07 06/17/08 <0.01 <0.01 0.01 0.075 11/05/08 05/19/09 <0.025 <0.025 <0.025 0.025 0.075 11/18/09 06/21/10 <0.0089 <0.0089 <0.0089 0.0089 0.075 11/18/10 injection event (03-29-11)05/23/11 <0.0089 <0.0089 <0.0089 0.0089 0.075 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.037 <0.037 <0.037 0.037 0.075 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.037 <0.037 <0.037 0.037 0.075 08/21/13 11/11/13 02/10/14 05/12/14 <0.037 <0.037 <0.037 0.037 0.075 08/18/14 11/11/14 02/23/15 05/12/15 <0.037 <0.037 <0.037 0.037 0.075 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B heptachlor epoxide04/17/90 MCL = 0.2 07/11/91 FBAC = 0.075 (SWSL)05/28/92 NCGQS = 0.004 (2L Std)06/30/93 2L Std = 0.0038 (pre- Jan. 2010)11/04/94 2L Std = 0.004 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <0.01 0.02 J 0.01 0.075 12/12/07 06/17/08 <0.01 <0.01 11/05/08 05/19/09 <0.025 <0.025 <0.025 <0.025 0.025 0.075 11/18/09 06/21/10 <0.0089 <0.0089 <0.0089 <0.0089 0.0089 0.075 11/18/10 injection event (03-29-11)05/23/11 <0.0089 <0.0089 <0.0089 <0.0089 0.0089 0.075 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <0.037 <0.037 <0.037 <0.037 0.037 0.075 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <0.037 <0.037 <0.037 <0.037 <0.037 <0.037 0.037 0.075 08/21/13 11/11/13 02/10/14 05/12/14 <0.037 <0.037 <0.037 <0.037 <0.037 <0.037 0.037 0.075 08/18/14 11/11/14 02/23/15 05/12/15 <0.037 <0.037 <0.037 <0.037 <0.037 <0.037 0.037 0.075 08/24/15 11/10/15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 isobutyl alcohol 04/17/90 MCL = 07/11/91 FBAC =100(SWSL)05/28/92 NCGQS = NE 06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 <100 <100 <100 <100 <100 <100 09/03/97 05/04/98 <100 <100 <100 <100 <100 <100 11/02/98 <100 <100 <100 <100 <100 04/26/99 <100 <100 <100 <100 11/22/99 <100 <100 <100 <100 <100 05/23/00 <100 <100 <100 <100 <100 <100 <100 <100 11/29/00 <100 <100 <100 <100 <100 06/05/01 <100 <100 <100 <100 <100 <100 <100 11/13/01 06/04/02 <100 <100 03/12/03 <100 <100 06/18/03 <100 <100 12/08/03 <100 <100 06/22/04 <100 <100 11/30/04 <100 <100 06/01/05 <100 <100 11/02/05 <100 <100 05/22/06 <100 <100 11/27/06 06/12/07 <1.2 <1.2 1.2 100 12/12/07 06/17/08 <1.2 <1.2 1.2 100 ic, cc 11/05/08 05/19/09 <14 <14 <14 14 100 11/18/09 06/21/10 <14 <14 <14 14 100 11/18/10 injection event (03-29-11)05/23/11 <11 <11 <11 11 100 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <11 <11 <11 11 100 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <11 <11 <11 11 100 08/21/13 11/11/13 02/10/14 05/12/14 <11 <11 <11 11 100 08/18/14 11/11/14 02/23/15 05/12/15 <11 <11 <11 11 100 08/24/15 11/10/15 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC isobutyl alcohol 04/17/90 MCL = 07/11/91 FBAC =100(SWSL)05/28/92 NCGQS = NE 06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 <100 <100 <100 <100 09/03/97 05/04/98 <100 <100 <100 241 R 11/02/98 <100 <100 <100 <100 04/26/99 <100 <100 <100 <100 11/22/99 <100 <100 <100 <100 05/23/00 <100 <100 <100 <100 <100 <100 <100 11/29/00 <100 <100 <100 <100 <100 <100 <100 06/05/01 <100 <100 <100 <100 <100 <100 <100 11/13/01 06/04/02 <100 <100 03/12/03 <100 <100 06/18/03 <100 <100 12/08/03 <100 <100 06/22/04 <100 <100 11/30/04 <100 <100 06/01/05 <100 <100 11/02/05 <100 <100 05/22/06 <100 <100 11/27/06 06/12/07 <1.2 <1.2 1.2 100 12/12/07 06/17/08 <1.2 <1.2 ic, cc 11/05/08 05/19/09 <14 <14 <14 <14 14 100 11/18/09 06/21/10 <14 <14 <14 <14 14 100 11/18/10 injection event (03-29-11)05/23/11 <11 <11 <11 <11 11 100 08/23/11 injection event (09-28-11)11/15/11 02/21/12 injection event (04-14-12)06/05/12 <11 <11 <11 <11 11 100 10/09/12 injection event (09-13-12)11/12/12 02/18/13 05/13/13 <11 <11 <11 <11 <11 <11 11 100 08/21/13 11/11/13 02/10/14 05/12/14 <11 <11 <11 <11 <11 <11 11 100 08/18/14 11/11/14 02/23/15 05/12/15 <11 <11 <11 <11 <11 <11 11 100 08/24/15 11/10/15 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 naphthalene 04/17/90 MCL = 07/11/91 FBAC =10(SWSL)05/28/92 NCGQS = 6 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 11/05/08 05/19/09 11/18/09 06/21/10 <0.086 <0.086 <0.086 0.086 10 11/18/10 <0.39 <0.39 <0.39 0.39 10 injection event (03-29-11)05/23/11 <0.46 <0.46 <0.46 0.46 10 08/23/11 0.46 10 injection event (09-28-11)11/15/11 <0.46 <0.46 <0.46 <0.46 <0.46 0.46 10 02/21/12 0.11 10 injection event (04-14-12)06/05/12 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 10/09/12 0.11 10 injection event (09-13-12)11/12/12 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/18/13 0.11 10 05/13/13 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/21/13 11/11/13 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/10/14 05/12/14 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/18/14 11/11/14 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/23/15 05/12/15 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/24/15 11/10/15 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B naphthalene 04/17/90 MCL = 07/11/91 FBAC =10(SWSL)05/28/92 NCGQS = 6 (2L Std)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 06/17/08 ic, cc 11/05/08 05/19/09 11/18/09 06/21/10 <0.086 1.9 J <0.086 <0.086 0.086 10 11/18/10 <0.39 0.9 J <0.39 <0.39 0.39 10 injection event (03-29-11)05/23/11 <0.46 1.1 J <0.46 <0.46 0.46 10 08/23/11 <0.46 <0.46 0.46 10 injection event (09-28-11)11/15/11 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46 0.46 10 02/21/12 <0.11 <0.11 <0.46 <0.46 0.11 10 injection event (04-14-12)06/05/12 <0.11 <0.11 <0.11 1.4 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 10/09/12 <0.11 <0.11 <0.11 <0.11 0.11 10 injection event (09-13-12)11/12/12 <0.11 <0.11 <0.11 1.7 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/18/13 <0.11 <0.11 <0.11 <0.11 0.11 10 05/13/13 <0.11 <0.11 <0.11 3.6 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/21/13 11/11/13 <0.11 <0.11 <0.11 2.8 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/10/14 05/12/14 <0.11 <0.11 <0.11 1.9 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/18/14 11/11/14 <0.11 <0.11 <0.11 3.4 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 02/23/15 05/12/15 <0.11 <0.11 <0.11 2.9 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 08/24/15 11/10/15 <0.11 <0.11 <0.11 3.2 J <0.11 <0.11 <0.11 <0.11 <0.11 0.11 10 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 tetrachloroethene 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 0.7 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 t 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.2 <0.2 <0.2 <0.2 0.2 1 12/12/07 <0.2 <0.2 <0.2 <0.2 0.2 1 06/17/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 ic, cc 11/05/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 05/19/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/18/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 06/21/10 <0.099 <0.099 <0.099 <0.099 <0.099 <0.099 0.099 1 11/18/10 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 injection event (03-29-11)05/23/11 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 0.73 1 08/23/11 0.73 1 injection event (09-28-11)11/15/11 <0.73 <0.73 <0.73 <0.73 <0.73 0.73 1 02/21/12 0.17 1 injection event (04-14-12)06/05/12 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 10/09/12 0.17 1 injection event (09-13-12)11/12/12 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 02/18/13 0.17 1 05/13/13 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 08/21/13 0.17 1 11/11/13 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 02/10/14 0.17 1 05/12/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 08/18/14 0.17 1 11/11/14 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 02/23/15 0.17 1 05/12/15 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 08/24/15 0.17 1 11/10/15 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC tetrachloroethene 04/17/90 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 33 <5.0 <5.0 NCGQS = 0.7 (2L Std)06/30/93 22.9 <5.0 <5.0 11/04/94 15 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 13 <5.0 <5.0 <5.0 03/13/95 12 <5.0 <5.0 <5.0 11/15/95 13 <5.0 <5.0 <5.0 07/25/96 30 <5.0 <5.0 <5.0 02/25/97 23 <5.0 <5.0 <5.0 09/03/97 23 <5.0 <5.0 <5.0 05/04/98 9 <5.0 <5.0 <5.0 11/02/98 10 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 t 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 <0.2 <0.2 <0.2 <0.2 0.7 J 0.6 J <0.2 3.2 0.2 1 12/12/07 <0.2 <0.2 <0.2 <0.2 0.5 J 0.2 J <0.2 1.3 0.2 1 06/17/08 <0.2 <0.2 <0.2 <0.2 0.7 J 0.5 J <0.2 2.8 J <0.2 0.2 1 ic, cc 11/05/08 <0.2 <0.2 <0.2 <0.2 0.2 J <0.2 <0.2 1.1 0.3 J 0.2 1 05/19/09 <0.36 <0.36 <0.36 <0.36 0.7 J <0.36 <0.36 3.7 1.3 0.36 1 11/18/09 <0.36 <0.36 <0.36 <0.36 0.68 J 0.54 J <0.36 3.8 0.83 J 0.36 1 06/21/10 <0.099 <0.099 <0.099 <0.099 0.54 J 0.42 J <0.099 2.5 0.53 J 0.099 1 11/18/10 <0.36 <0.36 <0.36 <0.36 0.77 J 0.44 J <0.36 3.2 <0.36 0.36 1 injection event (03-29-11)05/23/11 <0.73 <0.73 <0.73 <0.73 0.77 J <0.73 <0.73 4.4 <0.73 0.73 1 08/23/11 <0.73 <0.73 2.9 <0.73 0.73 1 injection event (09-28-11)11/15/11 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 <0.73 2.3 <0.73 0.73 1 02/21/12 0.61 J 0.65 J 2.7 <0.17 0.17 1 injection event (04-14-12)06/05/12 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.73 J <0.17 0.17 1 10/09/12 <0.17 <0.17 2.4 0.42 J 0.17 1 injection event (09-13-12)11/12/12 <0.17 <0.17 <0.17 <0.17 0.44 J <0.17 <0.17 1.5 <0.17 0.17 1 02/18/13 0.59 J <0.17 2.2 <0.17 0.17 1 05/13/13 <0.17 <0.17 <0.17 <0.17 0.44 J <0.17 <0.17 1.6 <0.17 0.17 1 08/21/13 <0.17 0.44 J 1.7 0.76 J 0.17 1 11/11/13 <0.17 <0.17 <0.17 <0.17 0.41 J <0.17 <0.17 1.4 0.40 J 0.17 1 02/10/14 0.47 J <0.17 1.6 <0.17 0.17 1 05/12/14 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 1.5 <0.17 0.17 1 08/18/14 <0.17 <0.17 0.66 J <0.17 0.17 1 11/11/14 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 1.1 <0.17 0.17 1 02/23/15 <0.17 <0.17 1.1 <0.17 0.17 1 05/12/15 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.77 J <0.17 0.17 1 08/24/15 <0.17 0.43 J 1.0 <0.17 0.17 1 11/10/15 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.99 J <0.17 0.17 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 toluene 04/17/90 MCL = 1000 07/11/91 FBAC = 1 (SWSL)05/28/92 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NCGQS = 600 (2L Std)06/30/93 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 2L Std = 1000 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 2L Std = 600 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 9 R 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.3 <0.3 <0.3 <0.3 0.3 1 12/12/07 <0.3 <0.3 <0.3 0.4 J 0.3 1 06/17/08 <0.3 0.4 J <0.3 <0.3 <0.3 <0.3 0.3 1 ic, cc 11/05/08 <0.3 0.4 J <0.3 <0.3 <0.3 1 J 0.3 1 05/19/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 0.47 J 0.27 1 06/21/10 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 0.053 1 11/18/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 injection event (03-29-11)05/23/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1 08/23/11 0.85 1 injection event (09-28-11)11/15/11 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1 02/21/12 0.14 1 injection event (04-14-12)06/05/12 <0.14 <0.14 <0.14 <0.14 0.49 J 0.14 1 10/09/12 0.14 1 injection event (09-13-12)11/12/12 <0.14 <0.14 <0.14 <0.14 0.46 J 0.14 1 02/18/13 0.14 1 05/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/21/13 0.14 1 11/11/13 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/10/14 0.14 1 05/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/18/14 0.14 1 11/11/14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/23/15 0.14 1 05/12/15 <0.14 <0.14 <0.14 <0.14 0.42 J 0.14 1 08/24/15 0.14 1 11/10/15 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B toluene 04/17/90 MCL = 1000 07/11/91 FBAC = 1 (SWSL)05/28/92 <0.5 <0.5 <0.5 NCGQS = 600 (2L Std)06/30/93 <10.0 <10.0 <10.0 2L Std = 1000 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 2L Std = 600 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 8 R 6 R <5 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1 12/12/07 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.3 1 06/17/08 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.5 J 0.3 1 ic, cc 11/05/08 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.4 J <0.3 <0.3 0.3 1 05/19/09 <0.27 <0.27 <0.27 0.55 J <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 06/21/10 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 <0.053 0.053 1 11/18/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 injection event (03-29-11)05/23/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1 08/23/11 <0.85 <0.85 <0.85 <0.85 0.85 1 injection event (09-28-11)11/15/11 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 <0.85 0.85 1 02/21/12 <0.14 <0.14 <0.14 <0.14 0.14 1 injection event (04-14-12)06/05/12 0.54 J <0.14 <0.14 0.49 J <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 10/09/12 <0.14 <0.14 <0.14 <0.14 0.14 1 injection event (09-13-12)11/12/12 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/18/13 <0.14 <0.14 <0.14 <0.14 0.14 1 05/13/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/21/13 <0.14 <0.14 <0.14 <0.14 0.14 1 11/11/13 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/10/14 <0.14 <0.14 <0.14 <0.14 0.14 1 05/12/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/18/14 <0.14 <0.14 <0.14 <0.14 0.14 1 11/11/14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 02/23/15 <0.14 <0.14 <0.14 <0.14 0.14 1 05/12/15 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 08/24/15 <0.14 <0.14 <0.14 <0.14 0.14 1 11/10/15 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.14 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 1,1,1-trichloroethane 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 200 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 200 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 06/21/10 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 11/18/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 injection event (03-29-11)05/23/11 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 08/23/11 0.65 1 injection event (09-28-11)11/15/11 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 02/21/12 0.12 1 injection event (04-14-12)06/05/12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 10/09/12 0.12 1 injection event (09-13-12)11/12/12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/18/13 0.12 1 05/13/13 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/21/13 0.12 1 11/11/13 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/10/14 0.12 1 05/12/14 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/18/14 0.12 1 11/11/14 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/23/15 0.12 1 05/12/15 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/24/15 0.12 1 11/10/15 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R MW-7 MW-7R MW-13 MW-14A MW-14B HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOD SWSL QA/QC 1,1,1-trichloroethane 04/17/90 <5.0 <5.0 MCL = 200 07/11/91 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 23 <5.0 <5.0 NCGQS = 200 (2L Std)06/30/93 11.9 <5.0 <5.0 11/04/94 <5.0 <5.0 <5.0 <5.0 12/20/94 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/04/02 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 11/18/09 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 06/21/10 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 11/18/10 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 0.27 1 injection event (03-29-11)05/23/11 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 08/23/11 <0.65 <0.65 <0.65 <0.65 0.65 1 injection event (09-28-11)11/15/11 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 <0.65 0.65 1 02/21/12 <0.12 <0.12 <0.12 <0.12 0.12 1 injection event (04-14-12)06/05/12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 10/09/12 <0.12 <0.12 <0.12 <0.12 0.12 1 injection event (09-13-12)11/12/12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/18/13 <0.12 <0.12 <0.12 <0.12 0.12 1 05/13/13 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/21/13 <0.12 <0.12 <0.12 <0.12 0.12 1 11/11/13 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/10/14 <0.12 <0.12 <0.12 <0.12 0.12 1 05/12/14 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/18/14 <0.12 <0.12 <0.12 <0.12 0.12 1 11/11/14 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 02/23/15 <0.12 <0.12 <0.12 <0.12 0.12 1 05/12/15 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 08/24/15 <0.12 <0.12 <0.12 <0.12 0.12 1 11/10/15 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 0.12 1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT Constituent Sample Date MW-15 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS MW-23 MW-24 LOD SWSL QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22 trichloroethene 04/17/90 <5.0 <5.0 <5.0 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 <5.0 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NCGQS = 3 (2L Std)06/30/93 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 2L Std = 2.8 (pre- Jan. 2010)11/04/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 2L Std = 3 (Jan. 2010)12/20/94 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/02/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 03/13/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/15/95 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 07/25/96 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 02/25/97 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 09/03/97 <5.0 <5.0 <5.0 <5.0 <5.0 05/04/98 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/98 <5.0 <5.0 <5.0 <5.0 <5.0 04/26/99 <5.0 <5.0 <5.0 <5.0 <5.0 11/22/99 <5.0 <5.0 <5.0 <5.0 <5.0 05/23/00 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 <5.0 <5.0 <5.0 <5.0 <5.0 06/05/01 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/13/01 <5.0 <5.0 <5.0 cc 06/04/02 <5.0 <5.0 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 06/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 12/12/07 <0.1 <0.1 <0.1 <0.1 0.1 1 06/17/08 <0.1 0.4 J <0.1 <0.1 <0.1 <0.1 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/19/09 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1 11/18/09 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.38 1 06/21/10 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.13 1 11/18/10 <0.38 0.45 J <0.38 <0.38 <0.38 <0.38 0.38 1 injection event (03-29-11)05/23/11 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1 08/23/11 0.72 1 injection event (09-28-11)11/15/11 <0.72 <0.72 <0.72 <0.72 <0.72 0.72 1 02/21/12 0.15 1 injection event (04-14-12)06/05/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 10/09/12 0.15 1 injection event (09-13-12)11/12/12 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 02/18/13 0.15 1 05/13/13 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 08/21/13 0.15 1 11/11/13 <0.15 0.49 J <0.15 <0.15 <0.15 0.15 1 02/10/14 0.15 1 05/12/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 08/18/14 0.15 1 11/11/14 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 02/23/15 0.15 1 05/12/15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 08/24/15 0.15 1 11/10/15 <0.15 <0.15 <0.15 <0.15 <0.15 0.15 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14B trichloroethene 04/17/90 <5.0 <5.0 MCL = 5 07/11/91 <5.0 <5.0 FBAC = 1 (SWSL)05/28/92 16 <5.0 <5.0 NCGQS = 3 (2L Std)06/30/93 24.4 <5.0 <5.0 2L Std = 2.8 (pre- Jan. 2010)11/04/94 22 <5.0 <5.0 <5.0 2L Std = 3 (Jan. 2010)12/20/94 9 <5.0 <5.0 <5.0 02/02/95 19 <5.0 <5.0 <5.0 03/13/95 13 <5.0 <5.0 <5.0 11/15/95 14 <5.0 <5.0 <5.0 07/25/96 33 <5.0 <5.0 <5.0 02/25/97 30 <5.0 <5.0 <5.0 09/03/97 31 <5.0 <5.0 <5.0 05/04/98 21 <5.0 <5.0 <5.0 11/02/98 23 <5.0 <5.0 <5.0 04/26/99 12 <5.0 <5.0 <5.0 11/22/99 8 <5.0 <5.0 <5.0 05/23/00 10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/29/00 6 <5.0 <5.0 <5.0 5 <5.0 <5.0 06/05/01 7 <5.0 <5.0 <5.0 <5.0 5 <5.0 11/13/01 <5.0 <5.0 <5.0 <5.0 <5.0 6 J <5.0 cc 06/04/02 <5.0 5 <5.0 <5.0 <5.0 7 <5.0 03/12/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/18/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 12/08/03 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/22/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/30/04 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/01/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/02/05 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 05/22/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 11/27/06 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 06/12/07 <0.1 1.9 <0.1 <0.1 <0.1 <0.1 <0.1 4.2 0.1 1 12/12/07 0.3 J 1.4 <0.1 <0.1 0.8 J 0.9 J <0.1 2.3 0.1 1 06/17/08 <0.1 1.7 J <0.1 <0.1 1.1 J 1.4 J <0.1 3.6 J <0.1 0.1 1 ic, cc 11/05/08 1 J 0.8 J <0.1 <0.1 0.6 J 1 J <0.1 3.4 0.9 J 0.1 1 05/19/09 <0.38 1.1 <0.38 <0.38 0.94 J 1.2 <0.38 3.6 1.3 0.38 1 11/18/09 <0.38 1.2 <0.38 <0.38 0.76 J 1.1 <0.38 4.4 1.1 0.38 1 06/21/10 <0.13 1.1 <0.13 <0.13 0.64 J 0.9 J <0.13 3 0.88 J 0.13 1 11/18/10 <0.38 0.7 J <0.38 <0.38 0.69 J 0.87 J <0.38 3.2 1 0.38 1 injection event (03-29-11)05/23/11 <0.72 0.79 J <0.72 <0.72 <0.72 0.75 J <0.72 4 1.1 0.72 1 08/23/11 <0.72 0.91 J 3 1 0.72 1 injection event (09-28-11)11/15/11 <0.72 <0.72 <0.72 <0.72 <0.72 0.8 J <0.72 2.2 1.1 0.72 1 02/21/12 0.61 J 0.6 J 2.8 0.73 J 0.15 1 injection event (04-14-12)06/05/12 <0.15 0.44 J <0.15 <0.15 0.45 J 0.56 J <0.15 2 0.74 J 0.15 1 10/09/12 <0.15 0.52 J 0.71 J 0.89 J 0.15 1 injection event (09-13-12)11/12/12 <0.15 0.55 J <0.15 <0.15 0.48 J <0.15 <0.15 0.95 J 0.89 J 0.15 1 02/18/13 0.48 J <0.15 2 0.92 J 0.15 1 05/13/13 <0.15 0.58 J <0.15 <0.15 <0.15 <0.15 <0.15 2 0.75 J 0.15 1 08/21/13 0.42 J <0.15 1.3 0.76 J 0.15 1 11/11/13 <0.15 <0.15 <0.15 <0.15 0.46 J <0.15 <0.15 1.7 0.76 J 0.15 1 02/10/14 0.41 J <0.15 1.5 <0.15 0.15 1 05/12/14 <0.15 0.41 J <0.15 <0.15 0.42 J <0.15 <0.15 1.4 0.54 J 0.15 1 08/18/14 0.57 J <0.15 1.4 0.54 J 0.15 1 11/11/14 <0.15 0.55 J <0.15 <0.15 0.49 J <0.15 <0.15 0.97 J 0.42 J 0.15 1 02/23/15 0.41 J <0.15 1.5 0.53 J 0.15 1 05/12/15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.95 J <0.15 0.15 1 08/24/15 0.45 J 0.49 J 0.97 J 0.46 J 0.15 1 11/10/15 <0.15 <0.15 <0.15 <0.15 0.49 J <0.15 <0.15 0.82 J <0.15 0.15 1 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 MW-23 MW-24 LOD SWSL QA/QC vinyl chloride 04/17/90 <10.0 <10.0 <5.0 <5.0 <10.0 MCL = 2 07/11/91 <10.0 <10.0 <5.0 <5.0 <10.0 FBAC = 1 (SWSL)05/28/92 <10.0 <10.0 <5.0 <5.0 <10.0 <10.0 <10.0 <10.0 NCGQS = 0.03 (2L Std)06/30/93 <10.0 <10.0 <5.0 <10.0 <10.0 <10.0 <10.0 2L Std = 0.015 (pre- Jan. 2010)11/04/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 2L Std = 0.03 (Jan. 2010)12/20/94 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 02/02/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 03/13/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/15/95 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 is 07/25/96 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 cc 02/25/97 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 09/03/97 <10.0 <10.0 <10.0 <10.0 <10.0 05/04/98 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/02/98 <10.0 <10.0 <10.0 <10.0 <10.0 04/26/99 <10.0 <10.0 <10.0 <10.0 <10.0 11/22/99 <10.0 <10.0 <10.0 <10.0 <10.0 05/23/00 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/13/01 <10.0 <10.0 <10.0 06/04/02 <10.0 <10.0 <10.0 sr 03/12/03 <10.0 <10.0 <10.0 <10.0 ht 06/18/03 <10.0 <10.0 <10.0 <10.0 <10.0 ic, cc, ss 12/08/03 <10.0 <10.0 <10.0 ic, cc 06/22/04 <10.0 <10.0 <10.0 ic, cc 11/30/04 <10.0 <10.0 <10.0 06/01/05 <10.0 <10.0 <10.0 11/02/05 <10.0 <10.0 <10.0 05/22/06 <10.0 <10.0 <10.0 11/27/06 <10.0 <10.0 <10.0 06/12/07 <0.1 <0.1 1.3 8 0.1 1 12/12/07 <0.1 <0.1 0.3 J 8.2 0.1 1 06/17/08 <0.1 <0.1 <0.1 <0.1 <0.1 6.6 J 0.1 1 ic, cc 11/05/08 <0.1 <0.1 <0.1 <0.1 0.95 J 5.6 0.1 1 05/19/09 <0.3 <0.3 <0.3 <0.3 0.83 J 6.4 0.3 1 11/18/09 <0.3 <0.3 <0.3 <0.3 1 J 10 0.3 1 06/21/10 <0.083 <0.083 <0.083 <0.083 <0.083 6 0.083 1 11/18/10 <0.3 <0.3 <0.3 <0.3 0.51 J 7.1 0.3 1 injection event (03-29-11)05/23/11 <0.6 <0.6 <0.6 <0.6 <0.6 4.7 0.6 1 08/23/11 0.6 1 injection event (09-28-11)11/15/11 <0.6 <0.6 <0.6 <0.6 5.4 0.6 1 02/21/12 0.32 1 injection event (04-14-12)06/05/12 <0.32 <0.32 <0.32 <0.32 2.8 0.32 1 10/09/12 0.32 1 injection event (09-13-12)11/12/12 <0.32 <0.32 <0.32 <0.32 7.5 0.32 1 02/18/13 0.32 1 05/13/13 <0.32 <0.32 <0.32 <0.32 6.7 0.32 1 08/21/13 0.32 1 11/11/13 <0.32 0.88 J <0.32 <0.32 4.3 0.32 1 02/10/14 0.32 1 05/12/14 <0.32 <0.32 <0.32 <0.32 9.0 0.32 1 08/18/14 0.32 1 11/11/14 <0.32 <0.32 <0.32 0.99 J 8.4 0.32 1 02/23/15 0.32 1 05/12/15 <0.32 <0.32 <0.32 <0.32 6.3 0.32 1 08/24/15 0.32 1 11/10/15 <0.32 <0.32 <0.32 0.81 J 6.4 0.32 1 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-6R MW-7 MW-7R MW-13 MW-14A MW-14BConstituentSample Date MW-1 MW-4 MW-5 MW-6 HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM vinyl chloride 04/17/90 <10.0 <10.0 MCL = 2 07/11/91 <10.0 <10.0 FBAC = 1 (SWSL)05/28/92 <10.0 <10.0 <10.0 NCGQS = 0.03 (2L Std)06/30/93 <10.0 <10.0 <10.0 2L Std = 0.015 (pre- Jan. 2010)11/04/94 <10.0 <10.0 <10.0 26 2L Std = 0.03 (Jan. 2010)12/20/94 <10.0 <10.0 <10.0 <10.0 02/02/95 <10.0 <10.0 <10.0 20 03/13/95 <10.0 <10.0 <10.0 20 11/15/95 <10.0 <10.0 <10.0 13 J is 07/25/96 <10.0 <10.0 <10.0 43 J cc 02/25/97 <10.0 <10.0 <10.0 11 09/03/97 10 R <10.0 <10.0 15 05/04/98 <10.0 <10.0 <10.0 10 11/02/98 <10.0 <10.0 <10.0 11 04/26/99 <10.0 <10.0 <10.0 <10.0 11/22/99 <10.0 <10.0 <10.0 17 05/23/00 <10.0 <10.0 <10.0 10 <10.0 <10.0 <10.0 11/29/00 <10.0 <10.0 <10.0 12 <10.0 <10.0 <10.0 06/05/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/13/01 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/04/02 10 J <10.0 <10.0 10 J <10.0 <10.0 <10.0 sr 03/12/03 17 J <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 ht 06/18/03 14 J <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 ic, cc, ss 12/08/03 13 J <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 ic, cc 06/22/04 12 J <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 ic, cc 11/30/04 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/01/05 16 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/02/05 15 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 05/22/06 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 11/27/06 22 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 06/12/07 13.1 3.9 <0.1 2.4 4 1.2 0.7 J 4 0.1 1 12/12/07 16.5 2.1 <0.1 2 2.4 0.4 J 0.97 J 4.4 0.1 1 06/17/08 12.8 J 4 J <0.1 1.8 J 3.4 J 1 J 0.7 J 2.9 J 0.3 J 0.1 1 ic, cc 11/05/08 14.6 2 <0.1 1.5 3.5 2.5 <0.1 3.4 3.3 0.1 1 05/19/09 12 2.3 <0.3 0.6 J 3.2 2.9 0.78 J 2.7 1.6 0.3 1 11/18/09 12 3.4 <0.3 0.94 J 3.6 2.9 1.6 4.8 2.5 0.3 1 06/21/10 8.7 1.9 <0.083 0.69 J 2.5 1.6 0.7 J 1.6 0.62 J 0.083 1 11/18/10 13 2.3 <0.3 0.79 J 3.8 0.56 J 1.2 4.7 1.9 0.3 1 injection event (03-29-11)05/23/11 8.2 1.1 <0.6 <0.6 2.6 1.2 <0.6 2.4 <0.6 0.6 1 08/23/11 3.3 2.4 3.6 1.1 0.6 1 injection event (09-28-11)11/15/11 10 1.4 <0.6 <0.6 1.7 <0.6 1.2 1.6 1.5 0.6 1 02/21/12 2.9 1 2.6 1 0.32 1 injection event (04-14-12)06/05/12 9.7 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 0.32 1 10/09/12 <0.32 0.96 J 1.1 0.32 1 injection event (09-13-12)11/12/12 12 1.2 <0.32 0.62 J 1.2 <0.32 1.4 <0.32 1.6 0.32 1 02/18/13 1.4 <0.32 2 0.32 1 05/13/13 12 1.3 <0.32 <0.32 2.2 <0.32 1.2 0.78 J <0.32 0.32 1 08/21/13 1.3 <0.32 0.72 J 0.54 J 0.32 1 11/11/13 8.8 <0.32 <0.32 <0.32 2.4 <0.32 1.2 1.8 0.41 J 0.32 1 02/10/14 2.5 <0.32 1.4 <0.32 0.32 1 05/12/14 17 1.9 <0.32 0.98 J 3.5 <0.32 2.0 2.9 <0.32 0.32 1 08/18/14 3.4 <0.32 4.4 <0.32 0.32 1 11/11/14 10 0.71 J <0.32 0.44 J 3.3 <0.32 2.0 4.2 <0.32 0.32 1 02/23/15 2.7 <0.32 3.7 <0.32 0.32 1 05/12/15 14 0.56 J <0.32 0.47 J 2.7 <0.32 1.8 3.5 <0.32 0.32 1 08/24/15 1.8 <0.32 3.1 <0.32 0.32 1 11/10/15 13 0.93 J <0.32 <0.32 3.0 <0.32 1.8 4.9 0.62 J 0.32 1 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT QA/QCMW-16 MW-17 MW-20 MW-21d MW-21s MW-22ConstituentSample Date MW-15 MW-23 MW-24 LOD SWSL HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM All results in µg/l. Upgradient wells not shaded. Shaded cells indicate data not available. Blue bolded cells indicate concentrations that exceeded the FBAC. Red bolded cells indicate concentrations that exceeded the NCGQS. Green bolded cells indicate concentrations that were >LOD but <SWSL. i - found in instrument blank t – found in trip blank f - found in field blank ic - initial calibration beyond limits cc – continuing calibration beyond limits md - matrix spike duplicates beyond limits ss – surrogate spikes beyond limits is - internal standard beyond limits ce - confirmation value beyond limits J - concentration deemed estimated B – concentration attributed to cross-contamination R - concentration deemed unreliable sr - sample results of a duplicate are below detection limits ht - sample holding time was exceeded  - additional Appendix 2 constituent - limits not established FBAC - facility background NCGQS – groundwater standard, as established by NCDENR SWSL – Solid Waste Section Limit, as established by NCDENR SPL – statistical prediction limit GWPS - groundwater protection standard 44northOrg&Inorg.592 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS ORGANIC CONSTITUENTS ATTACHMENT 6 SUMMARY OF INORGANIC CONSTITUENTS ATTACHMENT 6 INORGANIC CONSTITUENTS During November 10, and November 11, 2015 (sampling event 44), Sherrill Environmental, Inc. (Sherrill) personnel obtained groundwater samples from fourteen groundwater monitoring wells at the Orange County Solid Waste Management North Facility (north side of Eubanks Road).  During event 44, the laboratory detected seventeen metal constituents, at concentrations greater than their respective method detection limits (>MDLs): antimony, arsenic, barium, cadmium, chromium, cobalt, copper, iron (C&D parameter), lead, manganese (C&D parameter), mercury, nickel, selenium, silver, sulfide, vanadium, zinc. Groundwater samples to be analyzed for metals were not filtered in the field, such that all metals were analyzed as total metals. The laboratory reported manganese in an associated instrument blank (>1.10 µg/l but <10.0 µg/l). Since the reported concentrations of manganese in wells 6801-MW04 (4.52 µg/l), 6801-MW21D (13.7 µg/l), 6801-MW21S (21.7 µg/l), and 6801-MW-23 (40.5 µg/l), are less than 5x the estimated concentration in the associated blank (10.0 µg/l x 5 = 50 µg/l), the reported concentrations in each of those wells may be attributed to cross- contamination (flagged “B”). Conversely, since the reported concentration of manganese in well 6801-MW24 (92.1 µg/l) is greater than 5x the estimated concentration in the associated blank (10.0 µg/l x 5 = 50 µg/l), the reported concentration in that well may be acceptable (with respect to cross-contamination). Of the fifteen inorganic constituents “reliably” detected, eight exceeded their respective Solid Waste Section Limits (>SWSLs, except where calculated): arsenic, barium, chromium, cobalt, copper, manganese (one well), mercury, zinc. Of the eight metals that exceeded their respective Solid Waste Section Limits (>SWSLs, except where calculated), four metals also exceeded their respective Groundwater Quality Standard:  The reported concentrations of chromium in wells 6801-MW21S (94.1 µg/l) and 6801- MW23 (57.7 µg/l) exceeded its Facility Background Concentration (=SWSL) and its Groundwater Quality Standard (10 µg/l; 2L Standard). Inorganic Constituents Page 2  The reported concentrations of cobalt in wells 6801-MW14A (43.9 µg/l), 6801- MW14B (30.8 µg/l), 6801-MW15 (27.3 µg/l), and 6801-MW20 (15.7 µg/l) exceeded its Facility Background Concentration (=SWSL) and its Groundwater Quality Standard (1 µg/l; GWPS).  The reported concentration of manganese in well 6801-MW24 (92.1 µg/l) exceeded its Facility Background Concentration (=SWSL) and its Groundwater Quality Standard (50 µg/l; 2L Standard). We attribute the reported exceedance of manganese to the injection of potassium permanganate in that area of the facility, in connection with the groundwater corrective action program at the North Facility.  The reported concentrations of mercury in wells 6801-MW21S (2.21 µg/l), 6801- MW21D (1.32 µg/l), and 6801-MW23 (3.67 µg/l) exceeded its Facility Background Concentration (=SWSL) and its Groundwater Quality Standard (1 µg/l; 2L Standard). 15A NCAC 13B.1634.(f) states, “If one or more Appendix II constituents are detected above the approved ground-water protection standards in any sampling event, the owner or operator, shall within 14 days of this finding, submit a report to the Division, place a notice in the operating record, and notify local government officials.” Comment. Orange County Solid Waste Management has already characterized the nature and extent of constituents that previously exceeded their respective Groundwater Quality Standards, and prepared an Assessment of Corrective Measures, Corrective Action Plan, and Corrective Action Monitoring Plan addressing such constituents (all of which were previously submitted to NCDENR for review and approval). Injection reports for areas where permanganate or HRC injections are performed will be submitted (under separate cover), in accordance with the injection permit that was issued for the facility by the NCDENR Underground Injection Control Section. METALS GRAPHS 0 20 40 60 80 100 120 140 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North -chromium (MW-21S + MW-21D) MW-21S MW-21D injection event 1: 03-29-11 GWQS = 10 ppb injection event 4: 09-13-12 0 20 40 60 80 100 120 140 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North -chromium (MW-23 + MW-24) MW-23 MW-24 injection event 1: 03-29-11 GWQS = 10 ppbinjection event 4: 09-13-12 0 1 2 3 4 5 6 7 8 9 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North -mercury (MW-21S + MW-21D) MW-21S MW-21D injection event 1: 03-29-11 GWQS = 1 ppb injection event 4: 09-13-12 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North -mercury (MW-24 + MW-25) MW-23 MW-24 injection event 1: 03-29-11 GWQS = 1 ppb injection event 4: 09-13-12 TABLES antimony 04/17/90 MCL = 6 07/11/91 FBAC = 6 (SWSL)05/28/92 NCGQS = 1 (GWPS)06/30/93 GWPS = 1.4 (pre-Oct. 2010)11/04/94 GWPS = 1 (Oct. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <1.2 1.2 JB 1.2 JB 1.2 6 i 03/06/08 1.8 J 1.2 6 06/12/08 <1.2 <1.2 <1.2 <1.2 1.7 JB <1.2 1.2 6 i 11/05/08 <1.2 <1.2 <1.2 1.5 J <1.2 <1.2 1.2 6 05/19/09 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 6 11/18/09 <0.073 <0.073 0.126 J <0.073 <0.073 <0.073 0.073 6 06/21/10 <0.22 0.352 J <0.22 <0.22 <0.22 <0.22 0.22 6 11/18/10 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 05/23/11 <0.22 0.37 J <0.22 <0.22 <0.22 <0.22 0.22 6 11/15/11 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i 06/05/12 1 JB 0.691 JB <0.22 <0.22 <0.22 0.22 6 i 11/12/12 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i 05/13/13 0.32 J <0.22 <0.22 <0.22 <0.22 0.22 6 11/11/13 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 05/12/14 <0.220 0.335 J <0.220 <0.220 <0.220 0.220 6 11/11/14 0.603 J <0.220 <0.220 <0.220 <0.220 0.220 6 02/23/15 05/12/15 0.780 J <0.220 <0.220 0.239 J <0.220 0.220 6 08/24/15 11/10/15 0.237 J 1.05 J 0.548 J 0.303 J <0.220 0.220 6 Constituent Sample Date MW-1 MW-4 MW-5 MW-6 MW-7 MW-7R MW-13 MW-14A MW-14B LOD SWSL QA/QC INORGANIC CONSTITUENTS: TOTAL METALS FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-6R antimony 04/17/90 MCL = 6 07/11/91 FBAC = 6 (SWSL)05/28/92 NCGQS = 1 (GWPS)06/30/93 GWPS = 1.4 (pre-Oct. 2010)11/04/94 cc,i,ms GWPS = 1 (Oct. 2010)12/20/94 i 02/02/95 03/13/95 ms 11/15/95 ms 07/25/96 i,f,ms 02/25/97 i 09/03/97 05/04/98 i 11/02/98 i 04/26/99 11/22/99 q 05/23/00 q 11/29/00 q 06/05/01 11/13/01 ms 06/04/02 03/12/03 06/18/03 12/03/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <1.2 <1.2 <1.2 1.3 JB <1.2 <1.2 <1.2 1.2 6 i 03/06/08 1.2 6 06/12/08 4 JB <1.2 <1.2 1.8 JB <1.2 2.2 JB <1.2 1.4 JB 1.9 JB 1.2 6 i 11/05/08 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 1.2 6 05/19/09 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 <0.68 0.68 6 11/18/09 <0.073 <0.073 <0.073 <0.073 <0.073 0.089 J <0.073 <0.073 0.337 J 0.073 6 06/21/10 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 11/18/10 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 05/23/11 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 11/15/11 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i 06/05/12 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 i 11/12/12 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.642 J <0.22 0.22 6 i 05/13/13 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 <0.22 0.22 6 11/11/13 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 05/12/14 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 11/11/14 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 02/23/15 05/12/15 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 08/24/15 11/10/15 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 <0.220 0.220 6 MW-20 MW-21D MW-21S MW-22 MW-23 LOD INORGANIC CONSTITUENTS: TOTAL METALS SWSLConstituentSample Date MW-15 MW-24 QA/QCMW-16 MW-17 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS arsenic 04/17/90 <10 <10 <10 <10 <10 MCL = 10 07/11/91 <10 <10 <10 <10 <10 FBAC = 10 (SWSL)05/28/92 <10 <10 <10 <10 <10 <10 <10 <10 NCGQS = 10 (2L Std)06/30/93 <10 <10 <10 <10 <10 <10 <10 2L Std = 50 (pre- Jan. 2010)11/04/94 <10 <10 <10 15 B 11 B 16 B cc,i,ms 2L Std = 10 (Jan. 2010)12/20/94 <10 <10 <10 12 B <10 13 B i 02/02/95 <10 <10 <10 <10 <10 <10 03/13/95 <10 <10 <10 <10 <10 <10 <10 11 J ms 11/15/95 <10 <10 <10 <10 <10 <10 <10 17 J ms 07/25/96 <10 <10 <10 <10 <10 12 J i,f,ms 02/25/97 <10 <10 <10 <10 <10 <10 <10 <10 i 09/03/97 <10 <10 21 <10 14 05/04/98 <10 <10 <10 <10 <10 <10 <10 <10 i 11/02/98 <10 <10 45 <10 11 B i 04/26/99 <10 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 11 J q 05/23/00 <10 <10 20 J <10 <10 <10 <10 <10 q 11/29/00 <10 <10 21 J <10 <10 q 06/05/01 <10 <10 20 <10 15 <10 <10 11/13/01 <10 <10 <10 ms 06/04/02 <10 <10 <10 03/12/03 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 06/22/04 <10 <10 16 11/30/04 <10 <10 13 06/01/05 <10 <10 <10 11/02/05 <10 <10 <10 05/22/06 <10 <10 <10 11/27/06 <10 <10 <10 06/12/07 <5.5 <5.5 <5.5 <5.5 5.5 10 12/12/07 <5.5 <5.5 <5.5 5.5 10 03/06/08 <5.5 5.5 10 06/12/08 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 i 11/05/08 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 f 05/19/09 <2.8 20.1 3.9 J <2.8 <2.8 10.7 2.8 10 11/18/09 5.74 JB 33.3 <2.8 <2.8 <2.8 8.59 JB 2.8 10 f 06/21/10 3.14 JB 26 15.5 B 3.42 JB <2.8 11.4 B 2.8 10 11/18/10 <2.8 36.9 <2.8 <2.8 <2.8 7.67 J 2.8 10 05/23/11 <2.8 21.8 <2.8 <2.8 <2.8 10.6 2.8 10 11/15/11 <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 06/05/12 <2.8 <2.8 3.22 J <2.8 <2.8 2.8 10 11/12/12 <2.8 3.27 J <2.8 <2.8 8.07 J 2.8 10 05/13/13 <5.4 <5.4 <5.4 <5.4 9.96 J 5.4 10 11/11/13 <5.40 <5.40 <5.40 <5.40 9.28 J 5.40 10.0 05/12/14 <5.40 <5.40 <5.40 <5.40 <5.40 5.40 10.0 11/11/14 <5.40 <5.40 <5.40 <5.40 <5.40 5.40 10.0 02/23/15 05/12/15 <6.80 <6.80 <6.80 <6.80 7.30 J 6.80 10 08/24/15 11/10/15 <6.80 8.45 J 10.5 10.2 15.5 6.80 10 Constituent Sample Date MW-1 MW-4 MW-5 MW-6 MW-13MW-7R CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSLMW-7 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-14A MW-14B QA/QCMW-6R arsenic 04/17/90 <10 <10 MCL = 10 07/11/91 <10 <10 FBAC = 10 (SWSL)05/28/92 <10 <10 <10 NCGQS = 10 (2L Std)06/30/93 <10 <10 <10 2L Std = 50 (pre- Jan. 2010)11/04/94 <10 <10 <10 <10 cc,i,ms 2L Std = 10 (Jan. 2010)12/20/94 <10 <10 <10 <10 i 02/02/95 <10 <10 <10 <10 03/13/95 <10 <10 <10 <10 ms 11/15/95 <10 <10 <10 <10 ms 07/25/96 <10 <10 <10 <10 i,f,ms 02/25/97 <10 <10 <10 <10 i 09/03/97 <10 <10 <10 <10 05/04/98 <10 <10 <10 <10 i 11/02/98 <10 <10 <10 <10 i 04/26/99 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 q 05/23/00 <10 <10 <10 <10 <10 <10 <10 q 11/29/00 <10 <10 <10 <10 <10 <10 <10 q 06/05/01 <10 <10 <10 <10 <10 <10 <10 11/13/01 <10 <10 <10 <10 <10 <10 <10 ms 06/04/02 <10 <10 <10 <10 <10 <10 <10 03/12/03 <10 <10 <10 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 <10 <10 12/03/03 <10 <10 <10 <10 <10 <10 <10 06/22/04 <10 <10 <10 <10 <10 <10 <10 11/30/04 <10 <10 <10 <10 <10 <10 <10 06/01/05 <10 <10 <10 <10 <10 <10 <10 11/02/05 <10 <10 <10 <10 <10 <10 <10 05/22/06 <10 <10 <10 <10 <10 <10 <10 11/27/06 <10 <10 <10 <10 <10 <10 <10 06/12/07 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 12/12/07 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 03/06/08 5.5 10 06/12/08 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 i 11/05/08 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 5.5 10 f 05/19/09 <2.8 <2.8 <2.8 16 <2.8 <2.8 4.9 J <2.8 <2.8 2.8 10 11/18/09 <2.8 <2.8 <2.8 5.56 JB <2.8 <2.8 <2.8 2.92 JB <2.8 2.8 10 f 06/21/10 <2.8 3.72 JB <2.8 10.3 B <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 11/18/10 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 4.19 J <2.8 <2.8 2.8 10 05/23/11 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 11/15/11 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 06/05/12 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 11/12/12 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 <2.8 2.8 10 05/13/13 <5.4 <5.4 <5.4 <5.4 <5.4 <5.4 <5.4 <5.4 <5.4 5.4 10 11/11/13 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 5.40 10.0 05/12/14 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 <5.40 5.40 10.0 11/11/14 <5.40 <5.40 <5.40 <10.8 <5.40 <5.40 <5.40 <5.40 <5.40 5.40/10.8 10.0 02/23/15 05/12/15 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 6.80 10 08/24/15 11/10/15 <6.80 <6.80 <6.80 <6.80 <6.80 <6.80 9.62 J 8.07 J 7.41 J 6.80 10 MW-16ConstituentSample Date QA/QCMW-20 MW-21D CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY HISTORY OF CHEMICAL ANALYSIS LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM INORGANIC CONSTITUENTS: TOTAL METALS MW-21S MW-22 MW-23 LOD SWSLMW-15 MW-17 MW-24 barium 04/17/90 <50 71 <50 <50 <50 MCL = 2000 07/11/91 <100 <100 482 <100 111 FBAC = 500 (SPL)05/28/92 <100 <100 <100 <100 <100 <100 109 205 NCGQS = 700 (2L Std)06/30/93 <250 <500 <500 <500 <500 <500 <500 2L Std = 2000 (pre- Jan. 2010)11/04/94 <500 <500 <500 <500 <500 <500 i,sd 2L Std = 700 (Jan. 2010)12/20/94 <500 <500 <500 <500 <500 <500 02/02/95 <500 <500 <500 <500 <500 <500 03/13/95 <500 <500 <500 <500 <500 <500 <500 <500 11/15/95 <500 <500 <500 <500 <500 <500 <500 <500 ms 07/25/96 <500 <500 <500 <500 <500 <500 i,t,f 02/25/97 <500 <500 <500 <500 <500 <500 <500 <500 i,t,f,sd 09/03/97 <500 <500 <500 <500 <500 05/04/98 <500 <500 <500 <500 <500 <500 <500 <500 11/02/98 <500 <500 676 <500 <500 ics 04/26/99 <500 <500 <500 <500 <500 11/22/99 <500 <500 <500 <500 <500 05/23/00 <500 <500 <500 <500 <500 <500 <500 <500 11/29/00 <500 <500 <500 <500 <500 t, f 06/05/01 <500 <500 <500 <500 <500 <500 <500 11/13/01 <500 <500 <500 06/04/02 <500 <500 <500 03/12/03 <500 <500 <500 <500 06/18/03 <500 <500 <500 <500 <500 12/08/03 <500 <500 <500 06/22/04 <500 <500 <500 11/30/04 <500 <500 <500 06/01/05 <500 <500 <500 11/02/05 <500 <500 <500 05/22/06 <500 <500 <500 11/27/06 <500 <500 <500 i 06/12/07 64.9 JB 128 94.5 J 244 1.1 100 t, f 12/12/07 53.1 J 94.3 J 223 1.1 100 i 03/06/08 23.6 J 1.1 100 06/12/08 53.2 J 91.4 J 60.1 J 11.9 J 102 212 1.1 100 t, f 11/05/08 53.7 JB 163 20.4 JB 14.4 JB 108 223 1.1 100 t, f 05/19/09 68.8 J 77.9 J 33.5 J 8.83 J 33.4 J 273 4.2 100 11/18/09 57.6 J 71.5 J 14 J 4.63 J 61.4 J 254 1 100 06/21/10 107 49.5 J 122 8.31 J 47.2 J 190 1 100 11/18/10 63.3 J 91.3 J 18.1 J 3.12 J 41.8 J 218 1 100 05/23/11 77.5 J 67.3 J 17.2 J 22.1 J 59.6 J 256 1 100 11/15/11 66.3 J 15.6 J 6.67 J 43.3 J 264 1 100 06/05/12 88.1 J 30.3 J 20.7 J 50.7 J 253 1 100 11/12/12 67.1 J 33.2 J 21.6 J 39.9 J 266 1 100 05/13/13 64.1 J 17.6 J 18.4 J 59.1 J 240 1 100 i 11/11/13 64.2 J 22.7 J 23.3 J 105 275 1.00 100 05/12/14 66.8 J 22.3 J 16.5 J 29.2 J 258 1.00 100 11/11/14 67.9 J 16.1 J 6.42 J 101 276 1.00 100 02/23/15 05/12/15 79.3 J 17.3 J 10.0 J 59.9 J 309 1.00 100 08/24/15 11/10/15 65.5 J 15.0 J 4.93 J 99.3 J 261 1.00 100 LOCATION: CHAPEL HILL, NORTH CAROLINA FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT INORGANIC CONSTITUENTS: TOTAL METALS HISTORY OF CHEMICAL ANALYSIS PROJECT: GROUNDWATER MONITORING PROGRAM MW-13MW-7RMW-5ConstituentSample Date MW-1 MW-14A MW-14BMW-4 MW-6 MW-7 LOD QA/QCSWSLMW-6R barium 04/17/90 <50 <50 MCL = 2000 07/11/91 <100 <100 FBAC = 500 (SPL)05/28/92 <100 <100 <100 NCGQS = 700 (2L Std)06/30/93 <500 <500 <500 2L Std = 2000 (pre- Jan. 2010)11/04/94 <500 <500 <500 <500 i,sd 2L Std = 700 (Jan. 2010)12/20/94 <500 <500 <500 <500 02/02/95 <500 <500 <500 <500 03/13/95 <500 <500 <500 <500 11/15/95 <500 <500 <500 758 J ms 07/25/96 <500 <500 <500 <500 i,t,f 02/25/97 <500 <500 <500 <500 i,t,f,sd 09/03/97 <500 <500 <500 <500 05/04/98 <500 <500 <500 <500 11/02/98 <500 <500 <500 <500 ics 04/26/99 <500 <500 <500 <500 11/22/99 <500 <500 <500 <500 05/23/00 <500 <500 <500 <500 <500 <500 <500 11/29/00 <500 <500 <500 <500 <500 <500 <500 t, f 06/05/01 <500 <500 <500 <500 <500 <500 <500 11/13/01 <500 <500 <500 <500 <500 <500 <500 06/04/02 <500 <500 <500 <500 <500 <500 <500 03/12/03 <500 <500 <500 <500 <500 <500 <500 06/18/03 <500 <500 <500 <500 <500 <500 <500 12/08/03 <500 <500 <500 <500 <500 <500 <500 06/22/04 <500 <500 <500 <500 <500 <500 <500 11/30/04 <500 <500 <500 <500 <500 <500 <500 06/01/05 <500 <500 <500 <500 <500 <500 <500 11/02/05 <500 <500 <500 <500 <500 <500 <500 05/22/06 <500 <500 <500 <500 <500 <500 <500 11/27/06 <500 <500 <500 <500 <500 <500 <500 i 06/12/07 63.5 JB 112 35.5 JB 167 9.3 JB 13.9 JB 39.8 JB 193 1.1 100 t, f 12/12/07 43.4 J 148 27.7 J 165 4.4 JB 2.2 JB 37.7 J 1.1 100 i 03/06/08 1.1 100 06/12/08 89.1 J 114 20.3 J 171 2.6 JB 3.2 JB 66.7 J 5.9 JB 110 1.1 100 t, f 11/05/08 101 129 27.4 JB 237 1.8 JB 5 JB 53.2 JB 5.7 JB 14.5 JB 1.1 100 t, f 05/19/09 96.8 J 116 28.9 J 454 <4.2 6.25 J 58.6 J <4.2 9.85 J 4.2 100 11/18/09 86.6 J 222 26.8 J 338 2.31 J 8.2 J 45.9 J 3.26 J 10.9 J 1 100 06/21/10 65.7 J 177 20.8 J 92.2 J 2.21 J 7.0 J 37.2 J 2.92 J 12.5 J 1 100 11/18/10 75.5 J 148 21.9 J 126 2.19 J 10.4 J 47.7 J 4.35 J 10.9 J 1 100 05/23/11 129 155 26.2 J 197 2.32 J 4.78 J 57.3 J 4.84 J 9.69 J 1 100 11/15/11 93.7 J 163 25.8 J 495 2.36 J 15.3 J 56.5 J 7.17 J 7.42 J 1 100 06/05/12 125 144 28 J 171 2.37 J 4.76 J 59.9 J 5.2 J 10.2 J 1 100 11/12/12 141 187 24 J 244 D 2.04 J 1.95 J 59.1 J 16.3 J 9.5 J 1 100 05/13/13 90.8 J 123 20.8 J 168 2.19 J 7.26 J 55 J 3.14 J 8.36 J 1 100 i 11/11/13 114 139 29.7 J 155 2.97 J 3.02 J 56.7 J 5.12 J 7.38 J 1.00 100 05/12/14 66.2 J 170 30.5 J 176 2.80 J 7.19 J 53.0 J 3.71 J 7.47 J 1.00 100 11/11/14 148 129 28.9 J 186 2.82 J 4.84 J 58.2 J 4.96 J 6.53 J 1.00 100 02/23/15 05/12/15 105 127 30.7 J 208 2.37 J 15.2 J 68.4 J 6.54 J 7.33 J 1.00 100 08/24/15 11/10/15 123 172 25.8 J 159 2.86 J 1.93 J 55.4 J 5.37 J 6.96 J 1.00 100 LOD CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS SWSLMW-21DConstituentMW-16 MW-17 MW-21SMW-20Sample Date MW-15 MW-23 INORGANIC CONSTITUENTS: TOTAL METALS MW-22 QA/QCMW-24 beryllium 04/17/90 MCL = 4 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 4 (GWPS)06/30/93 11/04/94 <2 <2 <2 <2 <2 8 i 12/20/94 <2 <2 <2 <2 <2 10 02/02/95 <2 <2 2.7 <2 <2 20 i 03/13/95 <2 <2 2.8 3.8 2.1 <2 <2 24 t 11/15/95 <2 <2 2.6 2 7.1 <2 <2 20 07/25/96 <2 <2 <2 <2 <2 16 J d 02/25/97 <2 <2 <2 <2 <2 <2 <2 <2 f 09/03/97 <2 <2 <2 <2 8 05/04/98 3.6 <2 <2 <2 2.6 <2 <2 11.6 11/02/98 <2 <2 5.2 B <2 8.4 B i 04/26/99 <2 <2 <2 <2 7.6 11/22/99 <2 <2 <2 <2 <2 05/23/00 <2 <2 <2 <2 <2 <2 <2 <2 11/29/00 <2 <2 <2 <2 <2 06/05/01 <2 <2 <2 <2 <2 <2 <2 11/13/01 <2 <2 <2 i 06/04/02 <2 <2 <2 03/12/03 <2 <2 <2 <2 06/18/03 <2 <2 <2 <2 <2 12/08/03 <2 <2 <2 06/22/04 <2 <2 <2 11/30/04 <2 <2 <2 06/01/05 <2 <2 <2 11/02/05 <2 <2 <2 05/22/06 <2 <2 <2 11/27/06 <2 <2 <2 06/12/07 0.6 J 1.3 <0.2 <0.2 0.2 1 12/12/07 <0.2 1 B <0.2 0.2 1 i 03/06/08 <0.2 0.2 1 06/12/08 <0.2 <0.2 1.7 <0.2 0.3 J <0.2 0.2 1 11/05/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 05/19/09 0.08 J <0.08 0.14 J <0.08 <0.08 <0.08 0.08 1 11/18/09 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/21/10 <0.1 <0.1 0.473 J <0.1 <0.1 <0.1 0.1 1 11/18/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/23/11 0.125 J 0.111 J <0.1 <0.1 <0.1 <0.1 0.1 1 11/15/11 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/05/12 0.133 J <0.1 <0.1 <0.1 <0.1 0.1 1 11/12/12 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/13/13 <0.1 <0.1 <0.1 <0.1 0.118 J 0.1 1 11/11/13 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 05/12/14 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 11/11/14 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 02/23/15 05/12/15 <0.100 0.118 J <0.100 <0.100 <0.100 0.100 1 08/24/15 11/10/15 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 PROJECT: GROUNDWATER MONITORING PROGRAM LOCATION: CHAPEL HILL, NORTH CAROLINA MW-13 MW-14A MW-14B QA/QCMW-4 MW-5 MW-6 MW-7 MW-7R FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-1 HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS Constituent Sample Date LOD SWSLMW-6R beryllium 04/17/90 MCL = 4 07/11/91 FBAC = 1 (SWSL)05/28/92 NCGQS = 4 (GWPS)06/30/93 11/04/94 <2 <2 <2 5 i 12/20/94 <2 <2 <2 4 02/02/95 <2 <2 <2 18 i 03/13/95 <2 <2 <2 40 t 11/15/95 <2 <2 <2 35 07/25/96 <2 <2 <2 99 J d 02/25/97 <2 <2 <2 <2 f 09/03/97 <2 <2 <2 13 05/04/98 <2 <2 <2 23 11/02/98 <2 <2 <2 31 B i 04/26/99 <2 <2 <2 22.6 11/22/99 <2 <2 <2 <2 05/23/00 <2 <2 <2 <2 <2 <2 <2 11/29/00 <2 <2 <2 <2 <2 <2 <2 06/05/01 <2 <2 <2 <2 <2 <2 <2 11/13/01 <2 <2 <2 <2 <2 <2 <2 i 06/04/02 <2 <2 <2 <2 <2 <2 <2 03/12/03 <2 <2 <2 <2 <2 <2 <2 06/18/03 <2 <2 <2 <2 <2 <2 <2 12/08/03 <2 <2 <2 <2 <2 <2 <2 06/22/04 <2 <2 <2 <2 <2 <2 <2 11/30/04 <2 <2 <2 <2 <2 <2 <2 06/01/05 <2 <2 <2 <2 <2 <2 <2 11/02/05 <2 <2 <2 <2 <2 <2 <2 05/22/06 <2 <2 <2 <2 <2 <2 <2 11/27/06 <2 <2 <2 <2 <2 <2 <2 06/12/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 1.1 0.2 1 12/12/07 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 i 03/06/08 0.2 1 06/12/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 11/05/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 05/19/09 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 <0.08 0.08 1 11/18/09 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 06/21/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 11/18/10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/23/11 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 11/15/11 <0.1 <0.1 <0.1 <0.1 <0.1 0.115 J <0.1 <0.1 <0.1 0.1 1 06/05/12 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 11/12/12 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 05/13/13 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 1 11/11/13 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 05/12/14 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 11/11/14 <0.100 <0.100 <0.100 <0.200 <0.100 <0.100 <0.100 <0.100 <0.100 0.100/0.200 1 02/23/15 05/12/15 <0.100 <0.100 <0.100 <0.100 <0.100 0.168 J <0.100 <0.100 <0.100 0.100 1 08/24/15 11/10/15 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 <0.100 0.100 1 LODMW-21D CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-22 LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM INORGANIC CONSTITUENTS: TOTAL METALS MW-16 HISTORY OF CHEMICAL ANALYSIS MW-23 SWSL QA/QCMW-17 MW-20ConstituentSample Date MW-15 MW-21S MW-24 cadmium 04/17/90 <2 <2 <2 <2 <2 MCL = 5 07/11/91 <2 <2 <2 <2 <2 FBAC = 1 (SWSL)05/28/92 <2 <2 <2 <2 <2 <2 <2 <2 NCGQS = 2 (2L Std)06/30/93 <2 2.7 3.8 <2 <2 4.3 <2 2L Std = 1.75 (pre- Jan. 2010)11/04/94 <1 <1 1 B <1 <1 1 B cc,i,f 2L Std = 2 (Jan. 2010)12/20/94 <1 <1 1 B <1 <1 <1 i 02/02/95 <1 <1 <1 <1 <1 1 B i 03/13/95 <1 <1 1.1 B <1 <1 <1 1.2 B 3 B f,t 11/15/95 1.1 B 1.2 B 1.7 B 7 B <1 <1 1.3 B <1 ms,t 07/25/96 <1 <1 <1 <1 <1 <1 02/25/97 <1 <1 <1 <1 1.2 B 1.1 B <1 <1 i,f 09/03/97 <1 <1 <1 <1 <1 05/04/98 <1 <1 <1 <1 <1 <1 <1 4.4 B f,t 11/02/98 1.2 B <1 <1 1.5 B <1 f,t 04/26/99 <1 <1 <1 <1 <1 cc,i 11/22/99 <1 <1 <1 <1 <1 lcs,i 05/23/00 <1 <1 <1 1 B <1 <1 38 R <1 i,t,f 11/29/00 <1 <1 <1 <1 <1 i,q 06/05/01 <1 <1 <1 <1 <1 <1 1 11/13/01 <1 <1 <1 <1 <1 <1 <1 cc,i,t,f 06/04/02 <1 <1 <1 d,i,t,f 03/12/03 <1 <1 <1 <1 06/18/03 1 B <1 1 B <1 t 12/08/03 <1 <1 <1 06/22/04 <1 <1 <1 11/30/04 <1 <1 <1 06/01/05 <1 <1 <1 11/02/05 <1 <1 <1 05/22/06 <1 <1 <1 11/27/06 <1 <1 <1 06/12/07 0.6 J 6.7 <0.2 3.8 0.2 1 12/12/07 <0.2 0.98 JB <0.2 0.2 1 i 03/06/08 0.48 J 0.2 1 06/12/08 <0.2 <0.2 0.8 JB 0.2 JB 0.8 JB <0.2 0.2 1 t, i 11/05/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 1 i 05/19/09 0.29 J 0.25 J 0.35 J 0.23 J 0.53 J 0.43 J 0.09 1 11/18/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 06/21/10 <0.36 <0.36 0.570 J <0.36 0.378 J <0.36 0.36 1 11/18/10 <0.36 <0.36 <0.36 <0.36 <0.36 0.52 J 0.36 1 05/23/11 <0.36 <0.36 0.567 J <0.36 0.435 J <0.36 0.36 1 11/15/11 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 06/05/12 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/12/12 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 05/13/13 <0.36 1.06 <0.36 <0.36 <0.36 0.36 1 11/11/13 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 05/12/14 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 11/11/14 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 02/23/15 05/12/15 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 08/24/15 11/10/15 0.433 J 0.594 J <0.360 <0.360 <0.360 0.360 1 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT INORGANIC CONSTITUENTS: TOTAL METALS MW-13MW-7R MW-14B QA/QCMW-14AConstituentSample Date MW-1 MW-4 MW-5 MW-6 MW-7 LOD SWSL HISTORY OF CHEMICAL ANALYSIS PROJECT: GROUNDWATER MONITORING PROGRAM LOCATION: CHAPEL HILL, NORTH CAROLINA FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-6R cadmium 04/17/90 <2 <2 MCL = 5 07/11/91 <2 4.5 FBAC = 1 (SWSL)05/28/92 <2 <2 <2 NCGQS = 2 (2L Std)06/30/93 3.3 2.4 <2 2L Std = 1.75 (pre- Jan. 2010)11/04/94 <1 2 B <1 2 B cc,i,f 2L Std = 2 (Jan. 2010)12/20/94 <1 <1 <1 <1 i 02/02/95 <1 <1 <1 <1 i 03/13/95 1.2 B 1.4 B 1.3 B <1 f,t 11/15/95 <1 <1 1 B <1 ms,t 07/25/96 <1 <1 <1 <1 02/25/97 <1 <1 <1 <1 i,f 09/03/97 <1 <1 <1 <1 05/04/98 6.2 B 4.0 B 1.0 B <1 f,t 11/02/98 <1 <1 1.2 B <1 f,t 04/26/99 <1 <1 <1 <1 cc,i 11/22/99 <1 <1 <1 <1 lcs,i 05/23/00 4 B <1 <1 <1 <1 <1 <1 i,t,f 11/29/00 <1 <1 <1 <1 <1 <1 <1 i,q 06/05/01 <1 <1 1 <1 <1 <1 2 11/13/01 1 B <1 <1 3 B <1 <1 <1 cc,i,t,f 06/04/02 <1 <1 8 B <1 <1 <1 <1 d,i,t,f 03/12/03 <1 <1 <1 <1 <1 <1 <1 06/18/03 1 B <1 <1 <1 <1 <1 <1 t 12/08/03 <1 <1 1.6 <1 <1 <1 <1 06/22/04 <1 <1 <1 <1 <1 <1 <1 11/30/04 <1 <1 <1 <1 <1 <1 <1 06/01/05 <1 <1 <1 <1 <1 <1 <1 11/02/05 <1 <1 <1 <1 <1 <1 <1 05/22/06 <1 <1 <1 <1 2 <1 <1 11/27/06 <1 <1 <1 <1 <1 <1 <1 06/12/07 0.9 J <0.2 <0.2 19.9 <0.2 0.6 J 0.7 J 0.7 J 0.2 1 12/12/07 <0.2 <0.2 0.2 JB <0.2 0.2 JB <0.2 <0.2 0.2 1 i 03/06/08 0.2 1 06/12/08 <0.2 0.2 JB 0.3 JB <0.2 <0.2 <0.2 <0.2 <0.2 0.3 JB 0.2 1 t, i 11/05/08 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.6 JB 0.2 1 i 05/19/09 0.1 J 0.22 J 0.2 J 1.75 0.1 J <0.09 0.16 J <0.09 0.16 J 0.09 1 11/18/09 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 06/21/10 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/18/10 <0.36 <0.36 <0.36 1.23 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 05/23/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/15/11 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 06/05/12 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/12/12 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 05/13/13 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 0.36 1 11/11/13 <0.360 0.378 J <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 05/12/14 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 11/11/14 <0.360 <0.360 <0.360 <0.720 <0.360 <0.360 <0.360 <0.360 <0.360 0.360/0.720 1 02/23/15 05/12/15 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.360 1 08/24/15 11/10/15 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 <0.360 0.390 J 0.360 1 MW-22 QA/QCMW-16 MW-21S LOD SWSL LOCATION: CHAPEL HILL, NORTH CAROLINA MW-23 MW-24MW-20 MW-21D PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY Constituent MW-15Sample Date MW-17 chromium 04/17/90 <20 <20 <20 <20 <20 MCL = 100 07/11/91 <20 <20 <20 <20 <20 FBAC = 10 (SWSL)05/28/92 <20 <20 <20 <20 <20 <20 <20 <20 NCGQS = 10 (2L Std)06/30/93 <20 <20 <20 <20 <20 <20 <20 2L Std = 50 (pre- Jan. 2010)11/04/94 25 <10 24 <10 10.0 B <10 2L Std = 10 (Jan. 2010)12/20/94 <10 <10 48 <10 <10 <10 02/02/95 <10 <10 <10 <10 <10 <10 03/13/95 <10 <10 <10 <10 22.7 <10 <10 <10 11/15/95 <10 <10 12 <10 58 <10 <10 <10 07/25/96 13 B <10 <10 11 B <10 <10 02/25/97 <10 <10 <10 <10 93 B <10 <10 <10 09/03/97 <10 <10 <10 <10 <10 05/04/98 <10 <10 <10 <10 22.7 <10 <10 <10 11/02/98 <10 <10 <10 <10 <10 04/26/99 <10 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 <10 05/23/00 <10 <10 <10 <10 <10 <10 <10 <10 t,q 11/29/00 <10 <10 <10 <10 <10 i,f,q 06/05/01 <10 <10 <10 18 B <10 <10 <10 cc,t,f 11/13/01 <10 <10 <10 06/04/02 <10 <10 <10 03/12/03 <10 15 <10 <10 06/18/03 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 06/22/04 <10 <10 <10 11/30/04 <10 <10 <10 06/01/05 <10 <10 <10 11/02/05 <10 <10 <10 05/22/06 <10 <10 <10 11/27/06 <10 <10 <10 06/12/07 5.9 JB 33.5 6 JB <0.7 0.7 10 t,f 12/12/07 <0.7 8.3 J 1.4 JB 0.7 10 i 03/06/08 4.3 J 0.7 10 06/12/08 0.8 JB 0.7 JB 4.8 J <0.7 4.6 JB 1.3 JB 0.7 10 t 09/20/08 0.7 10 11/05/08 <0.7 28.6 2.4 JB 2.1 JB 5.6 JB <0.7 0.7 10 t, f 05/19/09 0.9 J 3.7 J <0.7 <0.7 1.9 J 2.7 J 0.7 10 11/18/09 <1 <1 <1 <1 <1 <1 1 10 i 06/21/10 4.74 J <1 3.54 J <1 <1 <1 1 10 11/18/10 2.9 J <1 1.33 J <1 <1 <1 1 10 05/23/11 1.99 J 6.1 J 1.63 J 1.53 J 2.39 J 4.44 J 1 10 11/15/11 <1 1.34 J <1 2.69 J 3.38 J 1 10 06/05/12 2.81 J 7.57 J 1.86 J 3.64 J 5.02 J 1 10 11/12/12 <1 9.18 J <1 1.72 J 2.53 J 1 10 05/13/13 <1.4 <1.4 <1.4 <1.4 <1.4 1.4 10 11/11/13 <1.40 <1.40 <1.40 3.94 J <1.40 1.40 10 05/12/14 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 10 11/11/14 <1.40 <1.40 <1.40 3.71 J 2.47 J 1.40 10 02/23/15 05/12/15 <1.40 <1.40 <1.40 2.54 J 2.39 J 1.40 10 08/24/15 11/10/15 <1.40 <1.40 <1.40 3.13 J <1.40 1.40 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-14A MW-14B QA/QCConstituentSample Date MW-1 MW-5 MW-6 MW-7 MW-13MW-7RMW-4 HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS SWSLLODMW-6R chromium 04/17/90 <20 <20 MCL = 100 07/11/91 <20 <20 FBAC = 10 (SWSL)05/28/92 <20 <20 <20 NCGQS = 10 (2L Std)06/30/93 <20 <20 <20 2L Std = 50 (pre- Jan. 2010)11/04/94 <10 33 <10 32 i 2L Std = 10 (Jan. 2010)12/20/94 <10 12 <10 16 02/02/95 <10 <10 <10 12 i 03/13/95 <10 <10 <10 <10 f,t 11/15/95 <10 <10 <10 20 f 07/25/96 <10 <10 17 B <10 f,t,ms 02/25/97 <10 <10 <10 <10 f 09/03/97 <10 <10 <10 <10 05/04/98 <10 <10 <10 <10 i,t 11/02/98 <10 <10 <10 <10 04/26/99 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 05/23/00 <10 <10 <10 10 B <10 <10 <10 t,q 11/29/00 <10 <10 <10 <10 <10 <10 <10 i,f,q 06/05/01 <10 <10 <10 <10 <10 <10 <10 cc,t,f 11/13/01 <10 <10 <10 <10 <10 <10 <10 06/04/02 <10 <10 <10 <10 <10 <10 <10 03/12/03 <10 <10 <10 <10 <10 <10 <10 06/18/03 13 <10 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 <10 <10 <10 <10 06/22/04 <10 14 <10 <10 <10 <10 <10 11/30/04 <10 <10 <10 <10 <10 <10 <10 06/01/05 <10 <10 <10 <10 <10 <10 <10 11/02/05 <10 <10 <10 <10 <10 <10 <10 05/22/06 <10 <10 <10 <10 <10 <10 <10 11/27/06 <10 <10 <10 <10 <10 <10 <10 06/12/07 10.8 <0.7 2.7 JB <0.7 1.9 JB 2.2 JB 2.2 JB 103 R 0.7 10 t,f 12/12/07 6.7 JB <0.7 1.9 JB <0.7 <0.7 <0.7 <0.7 0.7 10 i 03/06/08 0.7 10 06/12/08 6.7 J <0.7 1.6 JB <0.7 <0.7 <0.7 <0.7 <0.7 129 R 0.7 10 t 09/20/08 2.4 J 0.7 10 11/05/08 7.8 J <0.7 2.3 JB <0.7 <0.7 2.2 JB 1.8 JB <0.7 1.2 JB 0.7 10 t, f 05/19/09 7 J 1.3 J 2.2 J <0.7 1.6 J 5.1 J 1.4 J 1.2 J 1.3 J 0.7 10 11/18/09 <1 2.87 JB <1 <1 1.37 JB 7.49 JB <1 2.68 JB 1.81 JB 1 10 i 06/21/10 <1 <1 <1 <1 1.28 J 9.64 J <1 3.44 J 2.83 J 1 10 11/18/10 <1 <1 <1 <1 <1 1.26 J <1 1.6 J 3.67 J 1 10 05/23/11 8.29 J <1 2.48 J <1 1.44 J 4.62 J 1.12 J <1 <1 1 10 11/15/11 5.83 J <1 2.33 J 1.81 J 3.82 J 2.77 J <1 9.8 J <1 1 10 06/05/12 8.15 J 1.39 J 3.21 J <1 4.32 J 2.43 J 2.03 J 35.9 3.55 J 1 10 11/12/12 3.85 J <1 1.14 J <1 21.6 17.8 1.34 J 60.1 4.13 J 1 10 05/13/13 <1.4 <1.4 <1.4 <1.4 8.48 J 88.8 <1.4 65.3 4.34 J 1.4 10 11/11/13 3.74 J <1.40 1.85 J <1.40 27.0 77.7 <1.40 98.9 7.72 J 1.40 10 05/12/14 2.05 J 2.20 J 1.40 J <1.40 22.3 88.6 <1.40 118 <1.40 1.40 10 11/11/14 4.29 J <1.40 1.69 J <2.80 49.0 64.6 <1.40 83.9 20.5 1.40/2.80 10 02/23/15 05/12/15 4.04 J 3.54 JB 2.57 JB <1.40 19.3 115 <1.40 84.1 2.31 J 1.40 10 i 08/24/15 11/10/15 3.41 J <1.40 <1.40 <1.40 7.84 J 94.1 <1.40 57.7 3.83 J 1.40 10 MW-24 LOD SWSLMW-20 MW-21D MW-21S LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-23 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT QA/QCConstituent FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS MW-22Sample Date MW-15 MW-16 MW-17 cobalt 04/17/90MCL =07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 1 (GWPS)06/30/93 GWPS = 70 (pre-Oct. 2010)11/04/94 17 <4 <4 22 16 23 i GWPS = 1 (Oct. 2010)12/20/94 <10 <10 <10 23 104 22 02/02/95 <10 <10 <10 <10 144 25 f 03/13/95 <10 <10 100 <10 <10 <10 <10 21 11/15/95 <10 <10 91 J <10 17 J <10 12 J 24 J ms 07/25/96 <10 <10 <10 <10 91 B 16 B f,ms 02/25/97 <10 <10 140 <10 27 <10 102 27 i,f,t 09/03/97 <10 <10 20 <10 27 i 05/04/98 <10 <10 132 <10 <10 <10 78 24 11/02/98 93.2 <10 40 102 18.9 i 04/26/99 <10 <10 <10 21 25 i 11/22/99 <10 <10 <10 50 J 17 J d,i,t,f,q 05/23/00 <10 <10 212 <10 <10 <10 16 B 42 i,t,f 11/29/00 <10 <10 17 J 40 J <10 f,q 06/05/01 <10 <10 278 <10 11 B <10 28 B i,t,f 11/13/01 <10 <10 28 t 06/04/02 <10 <10 34 i 03/12/03 <10 <10 <10 26 06/18/03 <10 <10 <10 <10 27 12/08/03 <10 31 28 06/22/04 <10 <10 31 11/30/04 <10 12 28 06/01/05 <10 15 27 11/02/05 <10 16 28 05/22/06 <10 <10 22 11/27/06 <10 29 23 06/12/07 0.9 J 19.1 11.2 27.2 0.7 10 12/12/07 <0.7 27.4 27.6 0.7 10 03/06/08 2.2 J 0.7 10 06/12/08 <0.7 241 13.3 <0.7 26.2 24.8 0.7 10 11/05/08 <0.7 237 2 J 1.6 J 31.5 26.9 0.7 10 05/19/09 <0.6 173 1.7 J 0.7 J 2.3 J 34.3 0.6 10 11/18/09 <1.1 186 1.47 J <1.1 17.5 29.3 1.1 10 06/21/10 3.37 J 134 5.33 J <1.1 9.25 J 23 1.1 10 11/18/10 <1.1 177 2.24 J <1.1 14.1 23 1.1 10 05/23/11 <1.1 204 2.42 J <1.1 9.23 J 31.2 1.1 10 11/15/11 <1.1 2.03 J <1.1 13.5 31 1.1 10 06/05/12 1.61 J 1.69 J <1.1 5.18 J 31.1 1.1 10 11/12/12 <1.1 <1.1 1.34 J 13.2 31 1.1 10 05/13/13 <1.1 1.36 J 1.19 J 15.7 37.9 1.1 10 i 11/11/13 <1.10 2.58 J 3.56 J 46.7 29.7 1.10 10 05/12/14 <1.10 1.90 J <1.10 4.11 J 53.8 1.10 10 11/11/14 <1.10 2.86 J 1.26 J 46.2 30.3 1.10 10 02/23/15 05/12/15 <1.10 3.64 J <1.10 8.96 J 57.1 08/24/15 11/10/15 <1.10 3.26 J <1.10 43.9 30.8 1.10 10 QA/QC HISTORY OF CHEMICAL ANALYSIS Sample Date MW-1 MW-4 MW-5 MW-6 MW-13MW-7R LOD SWSL INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM Constituent MW-7 MW-14A MW-14BMW-6R cobalt 04/17/90MCL =07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 1 (GWPS)06/30/93 GWPS = 70 (pre-Oct. 2010)11/04/94 <4 <4 <4 60 i GWPS = 1 (Oct. 2010)12/20/94 <10 <10 <10 38 02/02/95 <10 <10 <10 84 f 03/13/95 <10 <10 <10 109 11/15/95 <10 <10 <10 70 J ms 07/25/96 <10 <10 <10 69 J f,ms 02/25/97 <10 <10 <10 80 i,f,t 09/03/97 <10 <10 <10 63 i 05/04/98 12.9 <10 <10 70 11/02/98 14.4 <10 <10 46.7 i 04/26/99 16 B <10 <10 63 i 11/22/99 24 J <10 <10 72 J d,i,t,f,q 05/23/00 21 <10 <10 55 <10 <10 <10 i,t,f 11/29/00 22 J <10 <10 67 J <10 <10 <10 f,q 06/05/01 22 B <10 <10 56 <10 <10 <10 i,t,f 11/13/01 21 <10 <10 52 <10 <10 <10 t 06/04/02 27 <10 <10 42 <10 <10 <10 i 03/12/03 31 <10 <10 71 <10 <10 <10 06/18/03 22 <10 <10 53 <10 <10 <10 12/08/03 26 <10 <10 38 <10 <10 <10 06/22/04 28 <10 <10 24 <10 <10 <10 11/30/04 28 <10 <10 36 <10 <10 <10 06/01/05 25 <10 <10 36 <10 <10 <10 11/02/05 27 <10 <10 16 <10 <10 <10 05/22/06 22 <10 <10 17 <10 <10 <10 11/27/06 22 <10 <10 27 <10 <10 <10 06/12/07 31.4 3.1 J 2 J 19.2 <0.7 0.8 J 0.7 J 43.8 0.7 10 12/12/07 20 2.5 J 2.6 J 16.8 <0.7 <0.7 <0.7 0.7 10 03/06/08 0.7 10 06/12/08 39.8 2.1 J 2.2 J 18.4 <0.7 <0.7 <0.7 <0.7 61.6 0.7 10 11/05/08 37.2 2 J 2.9 J 22.4 <0.7 <0.7 1.8 J <0.7 2.8 J 0.7 10 05/19/09 37.8 3.5 J 3.3 J 58.7 <0.6 0.8 J <0.6 <0.6 0.7 J 0.6 10 11/18/09 28 1.82 J 3.31 J 19.8 <1.1 1.85 J <1.1 <1.1 2.04 J 1.1 10 06/21/10 23 1.54 J 2.39 J 7.61 J <1.1 2.12 J <1.1 <1.1 2.90 J 1.1 10 11/18/10 28.6 2.36 J 2.59 J 7.65 J <1.1 <1.1 <1.1 <1.1 3.89 J 1.1 10 05/23/11 44.6 2.45 J 3.65 J 13.7 <1.1 1.34 J <1.1 <1.1 1.82 J 1.1 10 11/15/11 31.3 2.65 J 3.71 J 34.1 <1.1 <1.1 <1.1 <1.1 2.63 J 1.1 10 06/05/12 40.7 3.29 J 3.83 J 16.3 <1.1 <1.1 <1.1 <1.1 4.88 J 1.1 10 11/12/12 36.8 2.54 J 3.1 J 19.9 JD <1.1 <1.1 <1.1 <1.1 6.05 J 1.1 10 05/13/13 26.5 2.93 JB 2.63 JB 11.8 B <1.1 <1.1 <1.1 <1.1 3.07 J 1.1 10 i 11/11/13 30.1 2.96 J 3.60 J 11.1 <1.10 <1.10 <1.10 <1.10 1.59 J 1.10 10 05/12/14 18.1 3.70 J 4.00 J 15.6 <1.10 <1.10 <1.10 <1.10 1.32 J 1.10 10 11/11/14 36.5 2.74 J 3.44 J 14.9 JD <1.10 <1.10 <1.10 <1.10 <1.10 1.10 10 02/23/15 05/12/15 29.9 4.67 J 3.82 J 12.8 <1.10 1.21 J <1.10 <1.10 <1.10 1.10 10 08/24/15 11/10/15 27.3 3.17 J 3.61 J 15.7 <1.10 <1.10 <1.10 <1.10 <1.10 1.10 10 Constituent CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-24 QA/QCLODSWSLMW-20 MW-23MW-21D MW-21S MW-22Sample Date MW-15 MW-16 MW-17 copper 04/17/90 <20 <20 <20 <20 <20 MCL = 1300 07/11/91 <20 <20 <20 <20 <20 FBAC = 10 (SWSL)05/28/92 <20 <20 35 <20 <20 <20 <20 <20 NCGQS = 1000 (2L Std)06/30/93 <20 <20 <20 <20 <20 22 20 11/04/94 <200 <200 <200 <200 <200 <200 i,sd 12/20/94 <200 <200 <200 <200 <200 <200 02/02/95 <200 <200 <200 <200 <200 <200 03/13/95 <200 <200 <200 <200 <200 <200 <200 <200 11/15/95 <200 <200 211 <200 <200 <200 <200 <200 07/25/96 <200 <200 <200 <200 <200 <200 i,t,f 02/25/97 <200 <200 <200 <200 <200 <200 <200 <200 09/03/97 <200 <200 <200 <200 <200 05/04/98 <200 <200 <200 <200 <200 <200 <200 <200 11/02/98 <200 <200 <200 <200 <200 04/26/99 <200 <200 <200 <200 <200 i 11/22/99 <200 <200 <200 <200 <200 05/23/00 <200 <200 <200 <200 <200 <200 <200 <200 11/29/00 <200 <200 <200 <200 <200 i,f 06/05/01 <200 <200 <200 <200 <200 <200 <200 i,md 11/13/01 <200 <200 <200 i,f 06/04/02 <200 <200 <200 03/12/03 <200 <200 <200 <200 06/18/03 <200 <200 <200 <200 <200 12/08/03 <200 <200 <200 06/22/04 <200 <200 <200 11/30/04 <200 <200 <200 06/01/05 <200 <200 <200 11/02/05 <200 <200 <200 05/22/06 <200 <200 <200 11/27/06 <200 <200 <200 06/12/07 <2 333 18.4 <2 2 10 t,f 12/12/07 2.6 JB 24 <2 2 10 t,f 03/06/08 18.9 2 10 06/12/08 <2 14.8 B 11.1 2.9 JB 11.2 B 4.2 JB 2 10 t 11/05/08 <2 2.2 JB 3.5 JB <2 26.8 B <2 2 10 f, i 05/19/09 2.76 J 7.39 J <0.81 <0.81 13.5 <0.81 0.81 10 11/18/09 2.03 J 13.6 <1.6 <1.6 12.5 <1.6 1.6 10 06/21/10 26.5 3.8 J 7.03 J <1.6 32.8 <1.6 1.6 10 11/18/10 7.7 J 3.6 J <1.6 <1.6 17.4 <1.6 1.6 10 05/23/11 8.77 J 4.72 J <1.6 <1.6 23.9 <1.6 1.6 10 11/15/11 2.92 J <1.6 <1.6 19.3 <1.6 1.6 10 06/05/12 10.6 2.78 J <1.6 21.1 <1.6 1.6 10 11/12/12 <1.6 2.1 J <1.6 15.6 <1.6 1.6 10 05/13/13 <1.6 <1.6 <1.6 15 <1.6 1.6 10 11/11/13 <1.60 <1.60 <1.60 19.5 <1.60 1.60 10 05/12/14 <1.60 <1.60 <1.60 21.3 <1.60 1.60 10 11/11/14 <1.60 <1.60 <1.60 17.5 <1.60 1.60 10 02/23/15 05/12/15 <1.60 <1.60 <1.60 17.4 <1.60 1.60 10 08/24/15 11/10/15 <1.60 <1.60 <1.60 13.9 <1.60 1.60 10 HISTORY OF CHEMICAL ANALYSIS MW-14A MW-14B QA/QC INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM LOD SWSLMW-5 MW-6 MW-7 MW-13ConstituentSample Date MW-1 MW-4 MW-7RMW-6R copper 04/17/90 <20 <20 MCL = 1300 07/11/91 <20 <20 FBAC = 10 (SWSL)05/28/92 <20 <20 <20 NCGQS = 1000 (2L Std)06/30/93 <20 29 <20 11/04/94 <200 <200 <200 <200 i,sd 12/20/94 <200 <200 <200 <200 02/02/95 <200 <200 <200 <200 03/13/95 <200 <200 <200 <200 11/15/95 <200 <200 <200 <200 07/25/96 <200 <200 <200 <200 i,t,f 02/25/97 <200 <200 <200 <200 09/03/97 <200 <200 <200 <200 05/04/98 <200 <200 <200 <200 11/02/98 <200 <200 <200 <200 04/26/99 <200 <200 <200 <200 i 11/22/99 <200 <200 <200 <200 05/23/00 <200 <200 <200 <200 <200 <200 <200 11/29/00 <200 <200 <200 <200 <200 <200 <200 i,f 06/05/01 <200 <200 <200 <200 <200 <200 <200 i,md 11/13/01 <200 <200 <200 <200 <200 <200 <200 i,f 06/04/02 <200 <200 <200 <200 <200 <200 <200 03/12/03 <200 <200 <200 <200 <200 <200 <200 06/18/03 <200 <200 <200 <200 <200 <200 <200 12/08/03 <200 <200 <200 <200 <200 <200 <200 06/22/04 <200 <200 <200 <200 <200 <200 <200 11/30/04 <200 <200 <200 <200 <200 <200 <200 06/01/05 <200 <200 <200 <200 <200 <200 <200 11/02/05 <200 <200 <200 <200 <200 <200 <200 05/22/06 <200 <200 <200 <200 <200 <200 <200 11/27/06 <200 <200 <200 <200 <200 <200 <200 06/12/07 3.2 JB 2.3 JB 4.2 JB <2 3.5 JB 4.7 JB 3.1 JB 118 2 10 t,f 12/12/07 2.2 JB 3.5 JB 4.5 JB <2 3.7 JB 3.2 JB <2 2 10 t,f 03/06/08 2 10 06/12/08 2.5 JB 2 JB 2.3 JB <2 <2 <2 <2 <2 334 2 10 t 11/05/08 <2 <2 <2 <2 <2 <2 <2 <2 2.6 JB 2 10 f, i 05/19/09 <0.81 <0.81 <0.81 <0.81 <0.81 <0.81 <0.81 <0.81 <0.81 0.81 10 11/18/09 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10 06/21/10 <1.6 <1.6 <1.6 <1.6 <1.6 5.54 J <1.6 1.87 J <1.6 1.6 10 11/18/10 <1.6 <1.6 <1.6 6.88 J <1.6 <1.6 <1.6 <1.6 1.69 J 1.6 10 05/23/11 <1.6 <1.6 1.89 J <1.6 <1.6 2.75 J <1.6 1.84 J <1.6 1.6 10 11/15/11 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10 06/05/12 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10 11/12/12 <1.6 <1.6 <1.6 <1.6 3.22 J <1.6 <1.6 <1.6 <1.6 1.6 10 05/13/13 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 <1.6 1.6 10 11/11/13 <1.60 4.80 J <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10 05/12/14 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10 11/11/14 <1.60 <1.60 1.70 J <3.20 <1.60 <1.60 <1.60 <1.60 <1.60 1.60/3.20 10 02/23/15 05/12/15 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10 08/24/15 11/10/15 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 <1.60 1.60 10 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS MW-17 QA/QCMW-23 INORGANIC CONSTITUENTS: TOTAL METALS MW-20 MW-21D MW-21SConstituent MW-22Sample Date MW-15 MW-16 LODMW-24 SWSL lead 04/17/90 <5 <5 <5 <5 <5 MCL = 15 07/11/91 <5 7.3 <5 <5 <5 FBAC = 10 (SWSL)05/28/92 <10 <10 18.3 <10 <10 <10 11.2 <10 NCGQS = 15 (2L Std)06/30/93 <5 <5 54 30 <5 5.6 5.3 11/04/94 <10 <10 <10 <10 <10 <10 cc,i 12/20/94 <10 <10 11 B <10 <10 <10 f 02/02/95 13 B <10 <10 <10 <10 <10 i 03/13/95 <10 <10 40 55 <10 <10 <10 14 B t,f 11/15/95 <10 <10 54 J 36 J 15 J <10 <10 <10 ms,i,f 07/25/96 <10 <10 18 J <10 <10 <10 f,ms 02/25/97 <10 <10 16 B 63 B 46 B <10 10 B <10 i,f,t,ms 09/03/97 <10 <10 <10 <10 <10 i 05/04/98 24 B <10 37 43 21 B <10 10 B <10 f,t 11/02/98 <10 <10 <10 <10 <10 04/26/99 <10 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 <10 cc,i,q 05/23/00 <10 <10 <10 <10 <10 <10 <10 <10 t 11/29/00 <10 <10 <10 <10 <10 q 06/05/01 <10 <10 <10 16 <10 <10 <10 11/13/01 <10 <10 <10 06/04/02 <10 <10 <10 t 03/12/03 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 06/22/04 <10 <10 <10 11/30/04 <10 <10 <10 06/01/05 <10 <10 <10 11/02/05 <10 <10 <10 05/22/06 <10 <10 <10 11/27/06 <10 <10 <10 06/12/07 6.6 JB 19 <2 <2 2 10 t,f 12/12/07 <2 4.2 J <2 2 10 03/06/08 <2 2 10 06/12/08 <2 8.5 J 17.2 <2 2.8 J 5.2 J 2 10 11/05/08 <2 3.9 J 4.7 JB <2 5.6 JB <2 2 10 i 05/19/09 <1.6 3.3 J 2.4 J <1.6 <1.6 5.8 J 1.6 10 11/18/09 <1.9 5.31 J 1.94 J <1.9 <1.9 5.5 J 1.9 10 06/21/10 3.87 J <1.9 14.6 <1.9 <1.9 3.27 J 1.9 10 11/18/10 1.98 J 3.26 J <1.9 <1.9 2.13 J 3.05 J 1.9 10 05/23/11 <1.9 4.62 J <1.9 <1.9 <1.9 4.71 J 1.9 10 11/15/11 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 06/05/12 <1.9 <1.9 <1.9 <1.9 3 J 1.9 10 11/12/12 2.36 J <1.9 <1.9 <1.9 3.94 J 1.9 10 05/13/13 <2.1 <2.1 <2.1 <2.1 <2.1 2.1 10 11/11/13 <2.10 <2.10 <2.10 <2.10 3.24 J 2.10 10 05/12/14 <2.10 <2.10 <2.10 <2.10 2.51 J 2.10 10 11/11/14 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10 02/23/15 05/12/15 <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10 08/24/15 11/10/15 <3.10 3.74 J <3.10 <3.10 3.44 J 3.10 10 MW-13 MW-14AMW-7R HISTORY OF CHEMICAL ANALYSIS PROJECT: GROUNDWATER MONITORING PROGRAM INORGANIC CONSTITUENTS: TOTAL METALS Constituent MW-6 MW-7Sample Date MW-1 MW-4 MW-5 LOCATION: CHAPEL HILL, NORTH CAROLINA FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT LOD SWSL QA/QCMW-14BMW-6R lead 04/17/90 <5 <5 MCL = 15 07/11/91 <5 <5 FBAC = 10 (SWSL)05/28/92 <10 <10 <10 NCGQS = 15 (2L Std)06/30/93 <5 <5 <5 11/04/94 <10 <10 <10 <10 cc,i 12/20/94 <10 <10 <10 <10 f 02/02/95 <10 <10 <10 <10 i 03/13/95 19 B <10 <10 <10 t,f 11/15/95 <10 <10 <10 <10 ms,i,f 07/25/96 <10 <10 <10 <10 f,ms 02/25/97 <10 <10 <10 <10 i,f,t,ms 09/03/97 <10 <10 <10 <10 i 05/04/98 <10 <10 <10 <10 f,t 11/02/98 <10 <10 <10 <10 04/26/99 <10 <10 <10 <10 11/22/99 <10 <10 <10 <10 cc,i,q 05/23/00 <10 <10 <10 <10 <10 <10 <10 t 11/29/00 <10 <10 <10 <10 <10 <10 <10 q 06/05/01 <10 <10 <10 <10 <10 <10 <10 11/13/01 <10 <10 <10 <10 <10 <10 <10 06/04/02 <10 <10 <10 <10 <10 <10 <10 t 03/12/03 <10 <10 <10 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 <10 <10 <10 <10 06/22/04 <10 <10 <10 <10 <10 <10 <10 11/30/04 <10 <10 <10 <10 <10 <10 <10 06/01/05 <10 <10 <10 <10 <10 <10 <10 11/02/05 <10 <10 <10 <10 <10 <10 <10 05/22/06 <10 <10 <10 <10 <10 <10 <10 11/27/06 <10 <10 <10 <10 <10 <10 <10 06/12/07 3.1 JB 3 JB 3.6 JB 2.9 JB 2.4 JB 2.6 JB 2.1 JB 4.8 J 2 10 t,f 12/12/07 <2 <2 <2 7.4 J <2 <2 <2 2 10 03/06/08 2 10 06/12/08 2.8 J <2 <2 13.1 <2 <2 <2 <2 6.7 J 2 10 11/05/08 4.8 JB <2 <2 9.2 JB <2 <2 <2 <2 3.3 JB 2 10 i 05/19/09 4.3 J <1.6 <1.6 12.3 <1.6 <1.6 <1.6 <1.6 1.7 J 1.6 10 11/18/09 2.25 J <1.9 <1.9 11.3 <1.9 3.22 J <1.9 <1.9 <1.9 1.9 10 06/21/10 2.30 J <1.9 <1.9 7.23 J <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/18/10 3.51 J <1.9 <1.9 3.85 J <1.9 1.94 J <1.9 <1.9 1.99 J 1.9 10 05/23/11 3.41 J <1.9 <1.9 16.7 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/15/11 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 06/05/12 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/12/12 <1.9 <1.9 <1.9 12.6 JD <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 05/13/13 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 2.1 10 11/11/13 <2.10 <2.10 <2.10 12.4 <2.10 <2.10 <2.10 <2.10 <2.10 2.10 10 05/12/14 3.01 J <2.10 3.27 J 11.0 <2.10 4.23 J <2.10 <2.10 <2.10 2.10 10 11/11/14 <2.10 <2.10 <2.10 <4.20 <2.10 <2.10 <2.10 <2.10 <2.10 2.10/4.20 10 02/23/15 05/12/15 <3.10 <3.10 <3.10 <3.10 <3.10 4.16 J <3.10 <3.10 <3.10 3.10 10 08/24/15 11/10/15 <3.10 <3.10 <3.10 7.42 J <3.10 <3.10 <3.10 <3.10 <3.10 3.10 10 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS Constituent MW-22 SWSLMW-23 LOD INORGANIC CONSTITUENTS: TOTAL METALS MW-24 QA/QCMW-15 MW-16 MW-17 MW-20 MW-21D MW-21SSample Date mercury 04/17/90 <0.2 <0.2 <0.2 <0.2 <0.2 MCL = 2 07/11/91 <0.2 <0.2 0.58 0.3 <0.2 <0.2 FBAC = 0.2 (SWSL)05/28/92 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NCGQS = 1 (2L Std)06/30/93 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 2L Std = 1.05 (pre- Jan. 2010)11/04/94 2L Std = 1 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 <0.5 <0.5 02/25/97 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 09/03/97 05/04/98 11/02/98 <0.2 <0.2 0.2 <0.2 0.2 04/26/99 <0.2 <0.2 0.7 B <0.2 d,i 11/22/99 <0.2 <0.2 0.5 B <0.2 <0.2 i 05/23/00 <0.2 0.6 J <0.2 0.3 J <0.2 0.5 J d,cc 11/29/00 <0.2 <0.2 <0.2 <0.2 <0.2 d 06/05/01 <0.2 0.3 <0.2 0.9 <0.2 11/13/01 06/04/02 <0.2 <0.2 <0.2 03/12/03 <0.2 <0.2 <0.2 <0.2 06/18/03 <0.2 <0.2 <0.2 <0.2 <0.2 12/08/03 <0.2 <0.2 <0.2 06/22/04 <0.2 <0.2 <0.2 11/30/04 <0.2 <0.2 <0.2 06/01/05 <0.2 <0.2 <0.2 11/02/05 <0.2 <0.2 <0.2 05/22/06 <0.2 <0.2 <0.2 11/27/06 <0.2 <0.2 <0.2 06/12/07 <0.01 0.04 J <0.01 <0.01 0.01 0.2 12/12/07 0.02 JB <0.01 <0.01 0.01 0.2 i 03/06/08 <0.01 0.01 0.2 06/12/08 0.1 JB 0.04 JB 0.06 JB <0.01 0.02 JB 0.01 0.2 f 11/05/08 0.14 JB <0.01 0.16 JB 0.04 JB <0.01 <0.01 0.01 0.2 f, i 05/19/09 <0.05 <0.05 0.35 <0.05 <0.05 <0.05 0.05 0.2 11/18/09 <0.054 0.117 J 0.805 <0.054 <0.054 <0.054 0.054 0.2 06/21/10 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 11/18/10 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 injection event (03-29-11)05/23/11 <0.17 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 08/23/11 injection event (09-28-11)11/15/11 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 02/21/12 injection event (04-14-12)06/05/12 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 10/09/12 injection event (09-13-12)11/12/12 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 02/18/13 05/13/13 <0.17 <0.17 <0.17 <0.17 <0.17 0.17 0.2 11/11/13 <0.170 <0.170 <0.170 <0.170 <0.170 0.170 0.2 02/10/14 0.170 0.2 05/12/14 <0.170 <0.170 <0.170 <0.170 <0.170 0.170 0.2 08/18/14 0.170 0.2 11/11/14 <0.170 <0.170 <0.170 <0.170 <0.170 0.170 0.2 02/23/15 0.170 0.2 05/12/15 <0.170 <0.170 <0.170 <0.170 <0.170 0.170 0.2 08/24/15 11/10/15 <0.170 <0.170 <0.170 <0.170 <0.170 0.170 0.2 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM LOD SWSLMW-14AMW-6 MW-14BConstituentMW-13Sample Date MW-1 MW-4 MW-5 MW-7 QA/QCMW-7R HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS MW-6R mercury 04/17/90 <0.2 <0.2 MCL = 2 07/11/91 <0.2 <0.2 FBAC = 0.2 (SWSL)05/28/92 <0.2 <0.2 <0.2 NCGQS = 1 (2L Std)06/30/93 <0.2 <0.2 <0.2 2L Std = 1.05 (pre- Jan. 2010)11/04/94 2L Std = 1 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 <0.5 <0.5 02/25/97 <0.5 <0.5 <0.5 <0.5 09/03/97 05/04/98 11/02/98 0.5 <0.2 <0.2 <0.2 04/26/99 0.6 B 0.2 B 0.3 B 0.3 B d,i 11/22/99 0.3 B 0.3 B <0.2 <0.2 i 05/23/00 0.5 J <0.2 0.6 J 0.4 J 0.7 J <0.2 <0.2 d,cc 11/29/00 <0.2 <0.2 0.4 J <0.2 1.0 J <0.2 <0.2 d 06/05/01 <0.2 <0.2 <0.2 <0.2 1.0 <0.2 <0.2 11/13/01 06/04/02 <0.2 <0.2 <0.2 <0.2 1.4 <0.2 <0.2 03/12/03 <0.2 <0.2 <0.2 <0.2 1.0 <0.2 <0.2 06/18/03 <0.2 <0.2 <0.2 <0.2 0.6 <0.2 <0.2 12/08/03 <0.2 <0.2 <0.2 <0.2 0.5 <0.2 <0.2 06/22/04 <0.2 <0.2 <0.2 <0.2 1.1 <0.2 <0.2 11/30/04 <0.2 <0.2 <0.2 <0.2 1.1 <0.2 <0.2 06/01/05 <0.2 <0.2 <0.2 <0.2 0.6 <0.2 <0.2 11/02/05 <0.2 <0.2 <0.2 <0.2 3.6 <0.2 <0.2 05/22/06 <0.2 <0.2 <0.2 <0.2 1.9 <0.2 <0.2 11/27/06 <0.2 <0.2 <0.2 <0.2 1.48 0.48 <0.2 06/12/07 <0.01 <0.01 <0.01 <0.01 1.8 0.33 <0.01 0.74 0.01 0.2 12/12/07 <0.01 0.04 JB <0.01 <0.01 3.2 0.201 B 0.06 JB 0.01 0.2 i 03/06/08 0.01 0.2 06/12/08 0.14 JB 0.17 JB 0.08 JB 0.09 JB 1.8 0.37 B 0.16 JB 0.6 B 0.01 0.2 f 11/05/08 0.18 JB 0.08 JB <0.01 <0.01 2.2 0.12 JB <0.01 0.6 B 0.12 JB 0.01 0.2 f, i 05/19/09 <0.05 <0.05 <0.05 <0.05 2.16 0.81 <0.05 0.06 J <0.05 0.05 0.2 11/18/09 <0.054 <0.054 <0.054 <0.054 3.3 1.59 <0.054 0.482 <0.054 0.054 0.2 06/21/10 <0.17 <0.17 <0.17 <0.17 1.9 2.7 <0.17 <0.17 <0.17 0.17 0.2 11/18/10 <0.17 <0.17 <0.17 <0.17 3.13 1.64 <0.17 0.755 <0.17 0.17 0.2 injection event (03-29-11)05/23/11 <0.17 <0.17 <0.17 <0.17 1.77 1.52 <0.17 0.344 <0.17 0.17 0.2 08/23/11 2.23 2.37 1.48 <0.17 0.17 0.2 injection event (09-28-11)11/15/11 <0.17 <0.17 <0.17 <0.17 2.95 0.748 <0.17 1.74 <0.17 0.17 0.2 02/21/12 injection event (04-14-12)06/05/12 <0.17 <0.17 <0.17 <0.17 0.981 0.407 <0.17 0.652 <0.17 0.17 0.2 10/09/12 injection event (09-13-12)11/12/12 <0.17 <0.17 <0.17 <0.17 7.8 1.34 <0.17 3.07 <0.17 0.17 0.2 02/18/13 05/13/13 <0.17 <0.17 <0.17 <0.17 2.1 1.25 <0.17 0.417 <0.17 0.17 0.2 11/11/13 <0.170 <0.170 <0.170 <0.170 3.04 1.01 <0.170 2.57 <0.170 0.170 0.2 02/10/14 2.20 1.49 0.919 <0.170 0.170 0.2 05/12/14 <0.170 <0.170 <0.170 <0.170 1.39 1.31 <0.170 0.913 <0.170 0.170 0.2 08/18/14 1.25 2.33 3.61 <0.170 0.170 0.2 11/11/14 <0.170 <0.170 <0.170 <0.170 1.51 0.618 <0.170 4.25 <0.170 0.170 0.2 02/23/15 2.53 2.74 3.71 <0.170 0.170 0.2 05/12/15 <0.170 <0.170 <0.170 <0.170 0.960 1.69 <0.170 1.33 <0.170 0.170 0.2 08/24/15 1.59 4.22 4.57 <0.170 0.170 0.2 11/10/15 <0.170 <0.170 <0.170 <0.170 1.32 2.21 3.67 <0.170 0.170 0.2 LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM LOD SWSLMW-21S MW-22 MW-24 INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-17 QA/QCMW-20 HISTORY OF CHEMICAL ANALYSIS MW-23MW-21DSample Date MW-15 MW-16Constituent nickel 04/17/90 <50 <50 <50 <50 <50MCL = 07/11/91 <50 <50 <50 <50 <50 FBAC = 50 (SWSL)05/28/92 <50 <50 <50 <50 <50 <50 <50 NCGQS = 100 (2L Std)06/30/93 <50 <50 <50 <50 <50 <50 11/04/94 <50 <50 <50 <50 <50 <50 12/20/94 <50 <50 <50 <50 <50 <50 02/02/95 <50 <50 <50 <50 <50 <50 <50 <50 03/13/95 <50 <50 <50 <50 <50 <50 <50 <50 11/15/95 <50 <50 <50 <50 <50 <50 <50 <50 07/25/96 <50 <50 <50 <50 <50 <50 02/25/97 <50 <50 <50 <50 65 J <50 <50 <50 i,t,d,sd 09/03/97 <50 <50 <50 <50 <50 05/04/98 <50 <50 <50 <50 <50 <50 <50 <50 11/02/98 <50 <50 <50 <50 <50 04/26/99 <50 <50 <50 <50 <50 11/22/99 <50 <50 <50 <50 <50 05/23/00 <50 <50 <50 <50 <50 <50 <50 <50 q 11/29/00 <50 <50 <50 <50 <50 06/05/01 <50 <50 <50 <50 <50 <50 <50 i 11/13/01 <50 <50 <50 06/04/02 <50 <50 <50 03/12/03 <50 <50 <50 <50 06/18/03 <50 <50 <50 <50 <50 12/08/03 <50 <50 <50 06/22/04 <50 <50 <50 11/30/04 <50 <50 <50 06/01/05 <50 <50 <50 11/02/05 <50 <50 <50 05/22/06 <50 <50 <50 11/27/06 <50 <50 <50 06/12/07 1 J 38.3 J 6.3 J 1.6 J 0.6 50 12/12/07 2.6 JB 8.2 J 2.4 JB 0.6 50 i 03/06/08 6.98 J 0.6 50 06/12/08 <0.6 3.8 J 5.6 J 7.9 J 6.6 J 0.8 J 0.6 50 09/20/08 0.6 50 11/05/08 9.2 J 8.8 J 0.7 JB 15.9 J 6.7 J 2.4 JB 0.6 50 f 05/19/09 <0.6 3.2 J <0.6 12.1 J 5.3 J 2.5 J 0.6 50 11/18/09 <1.8 <1.8 <1.8 3.62 J 6.23 J <1.8 1.8 50 06/21/10 <1.8 <1.8 <1.8 10.6 J 4.71 J <1.8 1.8 50 11/18/10 <1.8 2.72 J <1.8 1.82 J 5.77 J <1.8 1.8 50 05/23/11 <1.8 1.81 J <1.8 23.8 J 6.32 J <1.8 1.8 50 11/15/11 <1.8 <1.8 2.44 J 6.89 J <1.8 1.8 50 06/05/12 <1.8 <1.8 10.7 J 7.24 J <1.8 1.8 50 11/12/12 <1.8 <1.8 17.4 J 5.24 J <1.8 1.8 50 05/13/13 <1.8 <1.8 21.1 J 4.39 J 3.3 J 1.8 50 i 11/11/13 <1.80 <1.80 33.8 J 8.68 J 2.26 J 1.80 50 05/12/14 <1.80 <1.80 19.3 J 5.28 J 3.55 J 1.80 50 11/11/14 <1.80 <1.80 5.27 J 7.34 J 1.93 J 1.80 50 02/23/15 05/12/15 <1.80 <1.80 11.7 J 7.50 J 5.30 J 1.80 50 08/24/15 11/10/15 <1.80 <1.80 3.32 J 7.04 J <1.8 1.80 50 SWSLLOD INORGANIC CONSTITUENTS: TOTAL METALS HISTORY OF CHEMICAL ANALYSIS PROJECT: GROUNDWATER MONITORING PROGRAM LOCATION: CHAPEL HILL, NORTH CAROLINA MW-6 MW-7ConstituentSample Date MW-1 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-14A MW-14B QA/QCMW-13MW-7RMW-5MW-4 MW-6R nickel 04/17/90 <50 <50MCL = 07/11/91 <50 <50 FBAC = 50 (SWSL)05/28/92 <50 <50 <50 NCGQS = 100 (2L Std)06/30/93 <50 <50 <50 11/04/94 <50 <50 <50 <50 12/20/94 <50 <50 <50 <50 02/02/95 <50 <50 <50 <50 03/13/95 <50 <50 <50 <50 11/15/95 <50 <50 <50 <50 07/25/96 <50 <50 <50 <50 02/25/97 <50 <50 <50 <50 i,t,d,sd 09/03/97 <50 <50 <50 <50 05/04/98 <50 <50 <50 <50 11/02/98 <50 <50 <50 <50 04/26/99 <50 <50 <50 <50 11/22/99 <50 <50 <50 <50 05/23/00 <50 <50 <50 <50 111 J <50 <50 q 11/29/00 <50 <50 <50 <50 <50 <50 <50 06/05/01 <50 <50 <50 <50 <50 <50 <50 i 11/13/01 <50 <50 <50 <50 <50 <50 <50 06/04/02 <50 <50 <50 <50 <50 <50 <50 03/12/03 <50 <50 <50 <50 <50 <50 <50 06/18/03 <50 <50 <50 <50 <50 <50 <50 12/08/03 <50 <50 <50 <50 <50 <50 <50 06/22/04 <50 <50 <50 <50 <50 <50 <50 11/30/04 <50 <50 <50 <50 <50 <50 <50 06/01/05 <50 <50 <50 <50 <50 <50 <50 11/02/05 <50 <50 <50 <50 <50 <50 <50 05/22/06 <50 <50 <50 <50 <50 <50 <50 11/27/06 <50 <50 <50 <50 <50 <50 <50 06/12/07 11.5 J 2.7 J 1.4 J 2.8 J <0.6 1.9 J 1.3 J 99.3 0.6 50 12/12/07 15.6 J 3.2 JB 2.9 JB 4.9 JB 6.6 J 2.4 JB 1.8 JB 0.6 50 i 03/06/08 0.6 50 06/12/08 8.5 J 1.6 J 1.4 J 2.9 J <0.6 1.2 J 1.8 J <0.6 110 R 0.6 50 09/20/08 3.1 J 0.6 50 11/05/08 8.1 J 1.4 JB 2.2 JB 10.6 J <0.6 2.4 JB 1.8 JB <0.6 1 JB 0.6 50 f 05/19/09 14.6 J 4.2 J 4.5 J 14.5 J 0.6 J 3.2 J 2.2 J 0.7 J 1.2 J 0.6 50 11/18/09 7.38 J 1.92 J 2.55 J 4.74 J <1.8 3.6 J <1.8 <1.8 <1.8 1.8 50 06/21/10 6.34 J <1.8 1.9 J <1.8 <1.8 4.05 J <1.8 1.81 J <1.8 1.8 50 11/18/10 8.17 J 2.04 J 2.53 J 2.13 J <1.8 <1.8 <1.8 <1.8 2.54 J 1.8 50 05/23/11 10.5 J 2.69 J 3.61 J <1.8 <1.8 2.07 J <1.8 <1.8 <1.8 1.8 50 11/15/11 12.8 J 3.13 J 3.83 J 4.89 J <1.8 1.95 J <1.8 <1.8 <1.8 1.8 50 06/05/12 11.8 J 3.99 J 4.8 J <1.8 <1.8 <1.8 <1.8 <1.8 3.06 J 1.8 50 11/12/12 8.86 J 2.02 J 3.18 J <1.8 <1.8 <1.8 <1.8 <1.8 3.44 J 1.8 50 05/13/13 12.3 J 2.7 JB <1.8 <1.8 <1.8 <1.8 <1.8 <1.8 1.86 J 1.8 50 i 11/11/13 12.3 J 1.91 J 4.25 J <1.80 <1.80 <1.80 <1.80 <1.80 <1.80 1.80 50 05/12/14 17.7 J 2.90 J 3.31 J <1.80 <1.80 <1.80 <1.80 <1.80 <1.80 1.80 50 11/11/14 14.1 J 1.94 J 3.46 J <3.60 <1.80 <1.80 <1.80 <1.80 <1.80 1.80/3.60 50 02/23/15 05/12/15 20.9 J 5.52 J 3.38 J <1.80 <1.80 1.86 J <1.80 <1.80 <1.80 1.80 50 08/24/15 11/10/15 13.5 J 2.85 J <1.80 <1.80 <1.80 <1.80 <1.80 <1.80 <1.80 1.80 50 MW-23 LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-17 QA/QCMW-20Sample Date MW-15 MW-16 MW-24MW-21D MW-21S MW-22Constituent LOD SWSL FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY selenium 04/17/90 MCL = 50 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 50 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 <6.3 <6.3 <6.3 6.3 10 03/06/08 <6.3 6.3 10 06/12/08 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 6.3 10 11/05/08 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 6.3 10 i 05/19/09 <3.4 <3.4 3.5 J <3.4 5.6 J <3.4 3.4 10 11/18/09 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 06/21/10 <0.83 <0.83 <0.83 1.2 J 11.3 9.8 J 0.83 10 11/18/10 <2.7 10.9 B <2.7 <2.7 3.24 JB <2.7 2.7 10 i 05/23/11 <0.83 <0.83 2.11 J 4.56 J 14.4 10.8 0.83 10 11/15/11 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 i 06/05/12 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10 11/12/12 <0.83 <0.83 <0.83 <0.83 <0.83 0.83 10 05/13/13 <0.91 1.05 J <0.91 <0.91 <0.91 0.91 10 11/11/13 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10 05/12/14 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10 11/11/14 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10 02/23/15 05/12/15 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10 08/24/15 11/10/15 <0.910 <0.910 <0.910 <0.910 <0.910 0.910 10 MW-14B LOD SWSL QA/QCSample Date MW-1 MW-4 MW-5 MW-6 MW-7 MW-7R MW-13 MW-14A PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS Constituent CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA MW-6R selenium 04/17/90 MCL = 50 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 50 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 11/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 6.7 J <6.3 8.5 J <6.3 <6.3 <6.3 <6.3 6.3 10 03/06/08 6.3 10 06/12/08 <6.3 <6.3 6.5 J <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 6.3 10 11/05/08 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 <6.3 6.4 JB 6.3 10 i 05/19/09 <3.4 <3.4 <3.4 <3.4 3.8 J <3.4 <3.4 <3.4 4.4 J 3.4 10 11/18/09 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 06/21/10 10.2 2.56 J 6.3 J 34.2 3.74 J 3.1 J 4.74 J 2.65 J 3.85 J 0.83 10 11/18/10 7.14 JB <2.7 <2.7 8.83 JB <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 i 05/23/11 10.3 3.99 J 8.33 J 37.6 3.33 J 2.78 J 6.24 J 3.34 J 3.92 J 0.83 10 11/15/11 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 10 i 06/05/12 <0.83 <0.83 <0.83 1.02 J <0.83 0.84 J <0.83 <0.83 <0.83 0.83 10 11/12/12 <0.83 <0.83 <0.83 <0.83 1.6 J 4.93 J <0.83 <0.83 <0.83 0.83 10 05/13/13 <0.91 <0.91 <0.91 0.961 J <0.91 6.35 J <0.91 <0.91 <0.91 0.91 10 11/11/13 <0.910 <0.910 <0.910 0.924 J <0.910 5.26 J <0.910 <0.910 <0.910 0.910 10 05/12/14 <0.910 <0.910 <0.910 <0.910 <0.910 4.10 J <0.910 <0.910 <0.910 0.910 10 11/11/14 <0.910 <0.910 <0.910 <0.910 <0.910 2.95 J <0.910 <0.910 <0.910 0.910 10 02/23/15 05/12/15 <0.910 <0.910 <0.910 <0.910 <0.910 2.42 J <0.910 <0.910 <0.910 0.910 10 08/24/15 11/10/15 <0.910 <0.910 <0.910 1.38 J <0.910 3.58 J <0.910 <0.910 <0.910 0.910 10 Constituent Sample Date MW-15 MW-16 MW-17 LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS SWSL QA/QCMW-20 MW-21D MW-21S MW-22 MW-23 LOD CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-24 silver 04/17/90MCL = 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 17.5 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 <10 <10 <10 <10 <10 i,t,f 06/05/01 <10 <10 <10 <10 <10 <10 i,t,f 11/13/01 <10 <10 <10 <10 t,f 06/04/02 <10 <10 <10 03/12/03 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 06/22/04 <10 <10 <10 11/30/04 <10 <10 <10 06/01/05 <10 <10 <10 11/02/05 <10 <10 <10 05/22/06 <10 <10 <10 11/27/06 <10 <10 <10 06/12/07 <1.1 <1.1 <1.1 <1.1 1.1 10 cc 12/12/07 <1.1 2.6 J 10 1.1 10 03/06/08 <1.1 1.1 10 06/12/08 <1.1 <1.1 <1.1 <1.1 2.6 JB <1.1 1.1 10 t, i 11/05/08 <1.1 <1.1 <1.1 <1.1 <1.1 10 JB 1.1 10 i 05/19/09 <1 2 J <1 <1 1.1 J 1.4 J 1 10 11/18/09 <1.9 2.68 J <1.9 <1.9 2.89 J <1.9 1.9 10 06/21/10 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/18/10 <1.9 5.16 J <1.9 <1.9 3.61 J 4.16 J 1.9 10 05/23/11 <1.9 3.42 J <1.9 <1.9 2.03 J 2.92 J 1.9 10 11/15/11 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 06/05/12 <1.9 <1.9 <1.9 2.98 J 2.34 J 1.9 10 11/12/12 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 05/13/13 <1.9 <1.9 <1.9 2.27 J <1.9 1.9 10 11/11/13 <1.90 <1.90 <1.90 2.32 J <1.90 1.90 10 05/12/14 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10 11/11/14 1.96 JB 2.01 JB 2.08 JB 3.91 JB 2.18 JB 1.90 10 i 02/23/15 05/12/15 <1.90 1.94 J 2.90 J 4.54 J <1.90 1.90 10 08/24/15 11/10/15 <1.90 <1.90 3.52 J 5.58 J 4.38 J 1.90 10 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-4 HISTORY OF CHEMICAL ANALYSIS MW-14AMW-7 INORGANIC CONSTITUENTS: TOTAL METALS MW-14B QA/QCMW-7R LOD SWSL LOCATION: CHAPEL HILL, NORTH CAROLINA MW-5 MW-6 PROJECT: GROUNDWATER MONITORING PROGRAM Constituent Sample Date MW-1 MW-13MW-6R FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY silver 04/17/90MCL = 07/11/91 FBAC = 10 (SWSL)05/28/92 NCGQS = 20 (2L Std)06/30/93 2L Std = 17.5 (pre- Jan. 2010)11/04/94 2L Std = 20 (Jan. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 <10 <10 <10 <10 <10 <10 11 B i,t,f 06/05/01 <10 <10 <10 <10 <10 <10 <10 i,t,f 11/13/01 <10 <10 <10 <10 <10 <10 <10 t,f 06/04/02 <10 <10 <10 <10 <10 <10 <10 03/12/03 <10 <10 <10 <10 <10 <10 <10 06/18/03 <10 <10 <10 <10 <10 <10 <10 12/08/03 <10 <10 <10 <10 <10 <10 <10 06/22/04 <10 <10 <10 <10 <10 <10 <10 11/30/04 <10 <10 <10 <10 <10 <10 <10 06/01/05 <10 <10 <10 <10 <10 <10 <10 11/02/05 <10 <10 <10 <10 <10 <10 <10 05/22/06 <10 <10 <10 <10 <10 <10 <10 11/27/06 <10 <10 <10 <10 <10 <10 <10 06/12/07 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 cc 12/12/07 1.3 J <1.1 1.2 J <1.1 <1.1 <1.1 <1.1 1.1 10 03/06/08 1.1 10 06/12/08 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 t, i 11/05/08 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 1.1 10 i 05/19/09 2.8 J <1 1 J <1 <1 <1 <1 <1 <1 1 10 11/18/09 4.6 J <1.9 2.7 J <1.9 2.37 J 2.39 J 2.79 J 1.91 J 2.23 J 1.9 10 06/21/10 <1.9 <1.9 <1.9 3.65 J <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/18/10 4.12 J <1.9 2.74 J 5.5 J 1.92 J <1.9 2.47 J <1.9 2.02 J 1.9 10 05/23/11 3.86 J <1.9 <1.9 2.96 J <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/15/11 2.44 J <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 06/05/12 3.77 J <1.9 2.93 J <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/12/12 2.29 J <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 05/13/13 2.79 J <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 <1.9 1.9 10 11/11/13 2.40 J <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10 05/12/14 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 <1.90 1.90 10 11/11/14 4.31 JB 2.10 JB 2.40 JB <3.80 2.50 JB 2.41 JB 2.51 JB 2.16 JB 2.37 JB 1.90/3.80 10 i 02/23/15 05/12/15 4.64 J <1.90 3.21 J <1.90 3.67 J 3.41 J 3.63 J 2.83 J 2.98 J 1.90 10 08/24/15 11/10/15 5.91 J <1.90 3.85 J 3.69 J 3.84 J 3.51 J 4.29 J 3.62 J 3.30 J 1.90 10 MW-24 QA/QCMW-20 MW-21D MW-21S MW-22 INORGANIC CONSTITUENTS: TOTAL METALS MW-17ConstituentSample Date MW-15 MW-16 LOCATION: CHAPEL HILL, NORTH CAROLINA HISTORY OF CHEMICAL ANALYSIS MW-23 LOD SWSL PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY sulfide 04/17/90 MCL = 07/11/91 FBAC = 1000 (SWSL)05/28/92 NCGQS =06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 <196 <196 02/25/97 <196 980 J <196 588 J <196 <196 ms,d 09/03/97 1190 B 990 B <196 792 B <196 f,t 05/04/98 1600 <200 <200 400 <200 <200 11/02/98 200 J 3000 J <200 <200 <200 d 04/26/99 <200 <200 <200 <200 d 11/22/99 1160 J 1360 J 388 J 388 J 388 J d 05/23/00 <200 <200 558 <200 <200 11/29/00 576 768 <200 <200 <200 06/05/01 970 J 388 J <200 970 J 9700 J ms,d,lcs 11/13/01 06/04/02 <200 <200 <200 ms,lcs 03/12/03 600 J 400 J <200 2200 J ms 06/18/03 368 J 368 J 1290 J <200 3130 J ms,md 12/08/03 <200 <200 540 06/22/04 <200 <200 <200 10/30/04 <200 <200 <200 06/01/05 <200 <200 <200 11/02/05 380 <200 6460 05/22/06 768 2690 10200 11/27/06 <200 <200 <200 06/12/07 <200 <200 <200 <200 200 1000 12/12/07 <200 <200 3610 200 1000 03/06/08 736 J 200 1000 06/12/08 <200 <200 <200 <200 200 1000 11/05/08 <200 <200 <200 <200 970 J 200 1000 05/19/09 <100 <100 100 1000 11/18/09 <31 <31 <31 <31 <31 <31 31 1000 06/21/10 <31 <31 <31 <31 <31 36 J 31 1000 11/18/10 <10 <10 <10 <10 <10 <10 10 1000 05/23/11 <10 <10 <10 <10 <10 <10 10 1000 11/15/11 <10 <10 <10 <10 <10 10 1000 06/05/12 <10 <10 <10 <10 <10 10 1000 11/12/12 <10 <10 <10 <10 <10 10 1000 05/13/13 <10 <10 <10 <10 <10 10 100011/11/13 <10 <10 <10 <10 <10 10 100005/12/14 <10 <10 <10 <10 <10 10 1000 11/11/14 <10 <10 <10 <10 <10 10 1000 02/23/15 05/12/15 <10 <10 <10 <10 <10 10 1000 08/24/15 11/10/15 <10 <10 <10 <10 10 J 10 1000 Constituent Sample Date MW-1 SWSL INORGANIC CONSTITUENTS: TOTAL METALS MW-5 LODMW-4 MW-14A MW-14B QA/QC HISTORY OF CHEMICAL ANALYSIS MW-6 MW-7 MW-13MW-7R CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-6R sulfide 04/17/90 MCL = 07/11/91 FBAC = 1000 (SWSL)05/28/92 NCGQS =06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 <196 <196 02/25/97 <196 <196 <196 3140 J ms,d 09/03/97 <196 2180 B 792 B 3760 B f,t 05/04/98 <200 <200 <200 14400 11/02/98 <200 <200 <200 2800 J d 04/26/99 <200 588 <200 21200 d 11/22/99 <200 <200 <200 12400 J d 05/23/00 <200 <200 372 22300 372 <200 <200 11/29/00 <200 <200 <200 1540 <200 384 <200 06/05/01 388 J 388 J <200 20200 J 582 J <200 <200 ms,d,lcs 11/13/01 06/04/02 <200 860 J <200 15200 J 570 J <200 960 J ms,lcs 03/12/03 <200 <200 <200 24800 J <200 600 J 400 J ms 06/18/03 <200 736 J <200 14200 J 736 J <200 920 J ms, md 12/08/03 <200 540 <200 23000 360 360 360 06/22/04 <200 352 <200 12700 <200 <200 <200 10/30/04 <200 <200 <200 23800 <200 <200 <200 06/01/05 <200 <200 <200 24500 564 <200 <200 11/02/05 <200 <200 34200 26600 570 760 570 05/22/06 <200 576 <200 26100 <200 576 <200 11/27/06 <200 <200 <200 313 <200 <200 <200 06/12/07 <200 <200 <200 28600 <200 <200 <200 <200 200 1000 12/12/07 <200 <200 <200 26100 <200 <200 <200 200 1000 03/06/08 200 1000 06/12/08 <200 <200 <200 25200 <200 <200 <200 <200 200 1000 11/05/08 <200 582 J <200 14700 <200 <200 2330 <200 <200 200 1000 05/19/09 <100 <100 <100 <100 100 1000 11/18/09 <31 <31 <31 <31 <31 <31 <31 <31 <31 31 1000 06/21/10 <31 <31 <31 <31 <31 <31 <31 <31 <31 31 1000 11/18/10 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 05/23/11 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 11/15/11 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 06/05/12 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 11/12/12 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 05/13/13 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 100011/11/13 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 100005/12/14 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 11/11/14 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 02/23/15 05/12/15 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 08/24/15 11/10/15 <10 <10 <10 <10 <10 <10 <10 <10 <10 10 1000 MW-21SSample Date QA/QCMW-20 MW-21D MW-22 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM Constituent MW-15 MW-16 LOD SWSLMW-17 INORGANIC CONSTITUENTS: TOTAL METALS MW-23 HISTORY OF CHEMICAL ANALYSIS MW-24 thallium 04/17/90 MCL = 2 07/11/91 FBAC = 5.5 (SWSL)05/28/92 NCGQS =0.2 (GWPS)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 10/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <2.7 <2.7 <2.7 <2.7 2.7 5.5 12/12/07 <2.7 <2.7 <2.7 2.7 5.5 03/06/08 <2.7 2.7 5.5 06/12/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5 11/05/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5 i 05/19/09 <0.036 0.061 JB <0.036 <0.036 <0.036 <0.036 0.036 5.5 11/18/09 0.26 J <0.11 <0.11 0.126 J 3 J 2.56 J 0.11 5.5 06/21/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/18/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 05/23/11 0.38 J 0.437 J 0.291 J 0.196 J <0.11 <0.11 0.11 5.5 11/15/11 0.129 J <0.11 <0.11 <0.11 <0.11 0.11 5.5 06/05/12 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/12/12 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 05/13/13 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/11/13 <0.110 <0.110 <0.110 0.155 J <0.110 0.110 5.5 05/12/14 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 11/11/14 0.347 J <0.110 <0.110 <0.110 <0.110 0.110 5.5 02/23/15 05/12/15 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 08/24/15 11/10/15 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 SWSL QA/QC PROJECT: GROUNDWATER MONITORING PROGRAM CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-13 MW-14A MW-14B LODMW-5 MW-6 MW-7 MW-7RConstituentSample Date MW-1 MW-4 HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS LOCATION: CHAPEL HILL, NORTH CAROLINA MW-6R thallium 04/17/90 MCL = 2 07/11/91 FBAC = 5.5 (SWSL)05/28/92 NCGQS =0.2 (GWPS)06/30/93 11/04/94 12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 10/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 <2.7 4.7 J <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5 12/12/07 <2.7 <2.7 <2.7 <2.7 <2.7 3.1 J <2.7 2.7 5.5 03/06/08 2.7 5.5 06/12/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.7 5.5 11/05/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 2.1 JB 2.7 5.5 i 05/19/09 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 <0.036 0.036 5.5 11/18/09 2.82 J <0.11 <0.11 <0.11 0.124 J 0.113 J <0.11 <0.11 0.129 J 0.11 5.5 06/21/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/18/10 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 05/23/11 <0.11 0.114 J 0.153 J <0.11 0.215 J 0.242 J <0.11 0.172 J 0.165 J 0.11 5.5 11/15/11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 06/05/12 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/12/12 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 05/13/13 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 0.11 5.5 11/11/13 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 05/12/14 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 11/11/14 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 02/23/15 05/12/15 <0.110 <0.110 <0.110 0.114 J <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 08/24/15 11/10/15 <0.110 <0.110 <0.110 <0.110 <0.110 0.110 5.5 LOCATION: CHAPEL HILL, NORTH CAROLINA FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-23 LOD SWSL QA/QCMW-21D MW-21S MW-22ConstituentSample Date MW-17 MW-20 PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT MW-24MW-15 MW-16 tin 04/17/90MCL = 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS =2000 (GWPS)06/30/93 GWPS = 2100 (pre-Oct. 2010)11/04/94 GWPS = 2000 (Oct. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 10/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 03/06/08 06/12/08 11/05/08 05/19/09 1.1 J 3.1 J <1.1 1.1 100 11/18/09 06/21/10 5.32 J <2.1 <2.1 <2.1 3.6 J <2.1 2.1 100 11/18/10 <2.1 3.94 J <2.1 <2.1 3.19 J <2.1 2.1 100 05/23/11 2.1 J 4.74 J <2.1 2.1 100 11/15/11 06/05/12 2.97 J <2.1 <2.1 5.26 J <2.1 2.1 100 11/12/12 05/13/13 <2.1 <2.1 <2.1 4.66 J 3.22 J 2.1 100 i 11/11/13 05/12/14 <2.1 <2.1 <2.1 2.1 100 i 11/11/14 02/23/15 05/12/15 <2.40 <2.40 <2.40 2.40 100 08/24/15 11/10/15 <2.40 <2.40 <2.40 2.40 100 PROJECT: GROUNDWATER MONITORING PROGRAM MW-7R MW-13 MW-14A MW-14B LOD SWSL QA/QC CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 MW-6R MW-7 tin 04/17/90MCL = 07/11/91 FBAC = 100 (SWSL)05/28/92 NCGQS =2000 (GWPS)06/30/93 GWPS = 2100 (pre-Oct. 2010)11/04/94 GWPS = 2000 (Oct. 2010)12/20/94 02/02/95 03/13/95 11/15/95 07/25/96 02/25/97 09/03/97 05/04/98 11/02/98 04/26/99 11/22/99 05/23/00 11/29/00 06/05/01 11/13/01 06/04/02 03/12/03 06/18/03 12/08/03 06/22/04 10/30/04 06/01/05 11/02/05 05/22/06 11/27/06 06/12/07 12/12/07 03/06/08 06/12/08 11/05/08 05/19/09 <1.1 <1.1 <1.1 2.2 J 1.1 100 11/18/09 06/21/10 2.42 J <2.1 <2.1 <2.1 4.61 J 4.76 J <2.1 <2.1 <2.1 2.1 100 11/18/10 2.52 J <2.1 4.04 J 2.23 J 3.42 J 3.11 J 3.46 J 3.68 J 2.62 J 2.1 100 05/23/11 2.71 J <2.1 2.81 J 2.33 J 2.1 100 11/15/11 06/05/12 4.65 J <2.1 4.17 J 4.44 J 2.1 100 11/12/12 05/13/13 3.36 J 3.68 JB <2.1 3.17 J 3.13 J 3.27 J 2.1 100 i 11/11/13 05/13/13 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 2.1 100 11/11/14 02/23/15 05/12/15 <2.40 <2.40 <2.40 <2.40 <2.40 <2.40 2.40 100 08/24/15 11/10/15 <2.40 <2.40 <2.40 <2.40 <2.40 <2.40 2.40 100 MW-21S MW-22 MW-23 MW-24 LOD SWSL QA/QC PROJECT: GROUNDWATER MONITORING PROGRAM LOCATION: CHAPEL HILL, NORTH CAROLINA MW-16 MW-17ConstituentSample Date MW-15 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY MW-20 MW-21D HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS vanadium 04/17/90MCL = 07/11/91 FBAC = 25 (SWSL)05/28/92 NCGQS = 0.3 (GWPS)06/30/93 GWPS = 3.5 (pre-Oct. 2010)11/04/94 <40 <40 <40 <40 <40 <40 GWPS = 0.3 (Oct. 2010)12/20/94 <40 <40 <40 <40 <40 <40 02/02/95 <40 <40 <40 <40 <40 <40 03/13/95 <40 <40 <40 <40 <40 <40 <40 <40 11/15/95 <40 <40 <40 <40 63 <40 <40 <40 07/25/96 <40 <40 <40 <40 <40 <40 t,sd 02/25/97 <40 <40 <40 <40 110 <40 <40 <40 09/03/97 <40 <40 <40 <40 <40 05/04/98 <40 <40 <40 <40 <40 <40 <40 <40 11/02/98 <40 <40 <40 <40 <40 04/26/99 <40 <40 <40 <40 <40 11/22/99 <40 <40 <40 <40 <40 05/23/00 <40 <40 <40 <40 <40 <40 <40 <40 11/29/00 <40 <40 <40 <40 <40 06/05/01 <40 <40 <40 <40 <40 <40 <40 <40 11/13/01 <40 <40 <40 06/04/02 <40 <40 <40 03/12/03 <40 <40 <40 <40 06/18/03 <40 <40 <40 <40 <40 12/08/03 <40 <40 <40 06/22/04 <40 <40 <40 10/30/04 <40 <40 <40 06/01/05 <40 <40 <40 11/02/05 <40 <40 <40 05/22/06 <40 <40 <40 11/27/06 <40 <40 <40 06/12/07 1.5 J 42.8 <0.4 <0.4 0.4 25 12/12/07 <0.4 <0.4 3 J 0.4 25 03/06/08 5.5 J 0.4 25 06/12/08 2.1 JB 5.2 J 5 J <0.4 <0.4 5.7 J 0.4 25 t, i 09/20/08 0.4 25 11/05/08 1.2 JB 2.4 JB 5.8 JB <0.4 <0.4 2.8 JB 0.4 25 f 05/19/09 2.9 J <0.7 1.5 J <0.7 <0.7 1 J 0.7 25 11/18/09 2.24 J <1.4 <1.4 <1.4 <1.4 <1.4 1.4 25 06/21/10 22.3 J 1.82 J 7.11 J <1.4 <1.4 <1.4 1.4 25 11/18/10 7.64 J <1.4 <1.4 <1.4 <1.4 <1.4 1.4 25 05/23/11 6.8 J 2.44 J <1.4 <1.4 <1.4 <1.4 1.4 25 11/15/11 3.23 J <1.4 <1.4 <1.4 <1.4 1.4 25 06/05/12 10.4 J <1.4 <1.4 <1.4 <1.4 1.4 25 11/12/12 1.76 J <1.4 <1.4 <1.4 <1.4 1.4 25 05/13/13 1.81 J <1.4 <1.4 <1.4 2.62 J 1.4 25 i 11/11/13 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 05/12/14 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 11/11/14 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 02/23/15 05/12/15 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 08/24/15 11/10/15 1.60 J <1.40 <1.40 <1.40 <1.40 1.40 25 INORGANIC CONSTITUENTS: TOTAL METALS HISTORY OF CHEMICAL ANALYSIS Constituent Sample Date MW-1 MW-4 MW-5 MW-6 MW-7RMW-7 MW-13 MW-14A MW-14B LOD SWSL LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT QA/QCMW-6R vanadium 04/17/90MCL = 07/11/91 FBAC = 25 (SWSL)05/28/92 NCGQS = 0.3 (GWPS)06/30/93 GWPS = 3.5 (pre-Oct. 2010)11/04/94 <40 <40 <40 <40 GWPS = 0.3 (Oct. 2010)12/20/94 <40 <40 <40 <40 02/02/95 <40 <40 <40 <40 03/13/95 <40 <40 <40 <40 11/15/95 <40 <40 <40 <40 07/25/96 <40 <40 <40 <40 t,sd 02/25/97 <40 <40 <40 <40 09/03/97 <40 <40 <40 <40 05/04/98 <40 <40 <40 <40 11/02/98 <40 <40 <40 <40 04/26/99 <40 <40 <40 <40 11/22/99 <40 <40 <40 <40 05/23/00 <40 <40 <40 <40 <40 <40 <40 11/29/00 <40 <40 <40 <40 <40 <40 <40 06/05/01 <40 <40 <40 <40 <40 <40 <40 11/13/01 <40 <40 <40 57 <40 <40 <40 06/04/02 <40 <40 <40 50 <40 <40 <40 03/12/03 <40 <40 <40 52 <40 <40 <40 06/18/03 <40 <40 <40 <40 <40 <40 <40 12/08/03 <40 <40 <40 41 <40 <40 <40 06/22/04 <40 <40 <40 <40 <40 <40 <40 10/30/04 <40 <40 <40 <40 <40 <40 <40 06/01/05 <40 <40 <40 <40 <40 <40 <40 11/02/05 <40 <40 <40 <40 <40 <40 <40 05/22/06 <40 <40 <40 <40 <40 <40 <40 11/27/06 <40 <40 <40 <40 <40 <40 <40 06/12/07 <0.4 <0.4 <0.4 <0.4 1 J 0.8 J 0.6 J 83.4 R 0.4 25 12/12/07 <0.4 <0.4 <0.4 15.4 J <0.4 <0.4 <0.4 0.4 25 03/06/08 0.4 25 06/12/08 1.5 JB 1.4 JB 1 JB 18.8 J 1.7 JB 1.9 JB 3.3 JB 1.3 JB 85.7 R 0.4 25 t, i 09/20/08 3.8 J 0.4 25 11/05/08 <0.4 <0.4 <0.4 13.1 JB <0.4 <0.4 6.8 JB 1.3 JB 2.2 JB 0.4 25 f 05/19/09 <0.7 1.3 J <0.7 <0.7 2.1 J 9.6 J 1.2 J 2.6 J 2.8 J 0.7 25 11/18/09 <1.4 <1.4 <1.4 2.84 J <1.4 15.4 J <1.4 2.53 J 9.66 J 1.4 25 06/21/10 <1.4 <1.4 <1.4 <1.4 <1.4 8.92 J <1.4 4.09 J 2.72 J 1.4 25 11/18/10 <1.4 <1.4 <1.4 <1.4 <1.4 4.2 J <1.4 1.81 J 2.8 J 1.4 25 05/23/11 <1.4 <1.4 <1.4 1.62 J <1.4 9.97 J <1.4 2.04 J <1.4 1.4 25 11/15/11 <1.4 <1.4 <1.4 <1.4 2.03 J 6.3 J <1.4 <1.4 <1.4 1.4 25 06/05/12 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 <1.4 1.66 J 2.29 J 1.4 25 11/12/12 <1.4 <1.4 <1.4 <1.4 <1.4 1.93 J <1.4 <1.4 2.07 J 1.4 25 05/13/13 <1.4 <1.4 <1.4 10.3 J <1.4 <1.4 <1.4 <1.4 3.62 J 1.4 25 i 11/11/13 <1.40 <1.40 <1.40 5.09 J <1.40 <1.40 <1.40 <1.40 2.68 J 1.40 25 05/12/14 <1.40 2.39 J <1.40 <1.40 <1.40 1.85 J <1.40 2.25 J 1.80 J 1.40 25 11/11/14 <1.40 <1.40 <1.40 <2.80 <1.40 <1.40 <1.40 <1.40 <1.40 1.40/2.80 25 02/23/15 05/12/15 <1.40 1.81 J <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 08/24/15 11/10/15 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 <1.40 1.40 25 LODMW-23MW-16 MW-17ConstituentSample Date MW-15 SWSL HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-24 QA/QCMW-20 MW-21D MW-21S MW-22 zinc 04/17/90 <10 49 22 <10 10MCL = 07/11/91 30 70 190 60 70 FBAC = 10 (SWSL)05/28/92 <20 <20 25 <20 <20 <20 <20 <20 NCGQS = 1000 (2L Std)06/30/93 <20 30 248 90 63 <20 24 2L Std = 1050 (pre- Jan. 2010)11/04/94 <50 <50 71 B <50 58 B 53 B i,f,sd 2L Std = 1000 (Jan. 2010)12/20/94 <50 70 B 61 B 51 B 52 B <50 i,f 02/02/95 55 B <50 <50.0 <50 <50 65 B i,f 03/13/95 <50 <50 89 B 72 B 53 B <50 <50 <50 i,t,f 11/15/95 <50 <50 139 J 63 B 131 J <50 <50 <50 ms,i 07/25/96 168 B 119 B 95 B 102 B 66 B 80 B i,t,f,ms 02/25/97 87 B 74 B 129 B 76 B 230 B 72 B <50 <50 i,t,f 09/03/97 <50 <50 <50 <50 <50 i,t,f,sd 05/04/98 85 B 424 B 57 B 61 B 92 B <50 <50 <50 f,t 11/02/98 <50 <50 <50 <50 <50 i,t,f,lcs 04/26/99 <50 <50 <50 <50 <50 i 11/22/99 <50 51 B <50 <50 <50 d,i,t,f,q 05/23/00 <50 54 B <50 <50 <50 <50 <50 <50 i,t,f,q 11/29/00 <50 <50 <50 <50 <50 t, f 06/05/01 <50 <50 75 B 73 B <50 <50 <50 i,t,f 11/13/01 51 B <50 <50 ms,t,f 06/04/02 60 B <50 <50 t 03/12/03 60 <50 <50 <50 06/18/03 155 B <50 <50 <50 <50 t 12/08/03 94 <50 <50 06/22/04 105 <50 <50 11/30/04 86 <50 <50 06/01/05 66 J <50 <50 cc 11/02/05 <50 <50 <50 05/22/06 <50 <50 <50 11/27/06 <50 <50 <50 i 06/12/07 28.1 B 134 10.2 B 15.3 B 2.7 10 t, f 12/12/07 20.9 B 13.5 B 12.2 B 2.7 10 i 03/06/08 56.2 2.7 10 06/12/08 <2.7 <2.7 44.5 B <2.7 <2.7 <2.7 2.7 10 i 11/05/08 8.1 JB 12.4 B 19.7 B <2.7 <2.7 <2.7 2.7 10 i 05/19/09 14.2 15.0 35.1 <3.4 4.4 J 12.9 3.4 10 11/18/09 11.1 11.6 26 11 6.98 J 5.5 J 3.8 10 06/21/10 82 9.32 J 99.2 7.19 J 7.49 J 11.9 3.8 10 11/18/10 26.6 4.21 J 32.3 <3.8 8.24 J 5.58 J 3.8 10 05/23/11 27.7 6.55 J 49.2 4.23 J 10.9 <3.8 3.8 10 11/15/11 13.8 40.9 <3.8 7.08 J 7.14 J 3.8 10 06/05/12 45.2 34.7 <3.8 4.01 J 6.92 J 3.8 10 11/12/12 17 12 <3.8 <3.8 7.13 J 3.8 10 05/13/13 8.63 J 58.4 <3.8 11.7 8.99 J 3.8 10 11/11/13 7.24 J 59.5 <3.80 8.98 J 15.9 3.80 10 05/12/14 7.44 J 57.8 <3.80 4.71 J 5.33 J 3.80 10 11/11/14 14.6 46.7 <3.80 6.07 J 4.01 J 3.80 10 02/23/15 05/12/15 9.30 J 42.5 <3.80 4.97 J <3.80 3.80 10 08/24/15 11/10/15 7.09 J 37.4 <3.80 <3.80 <3.80 3.80 10 FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT INORGANIC CONSTITUENTS: TOTAL METALS HISTORY OF CHEMICAL ANALYSIS PROJECT: GROUNDWATER MONITORING PROGRAM Constituent Sample Date MW-1 MW-4 MW-5 MW-6 LOCATION: CHAPEL HILL, NORTH CAROLINA MW-7R LOD SWSLMW-7 MW-13 MW-14A MW-14B QA/QCMW-6R zinc 04/17/90 <10 <10MCL = 07/11/91 <20 30 FBAC = 10 (SWSL)05/28/92 <20 <20 <20 NCGQS = 1000 (2L Std)06/30/93 21 <20 <20 2L Std = 1050 (pre- Jan. 2010)11/04/94 <50 <50 <50 54 B i,f,sd 2L Std = 1000 (Jan. 2010)12/20/94 <50 <50 <50 <50 i,f 02/02/95 <50 <50 <50 <50 i,f 03/13/95 <50 <50 <50 <50 i,t,f 11/15/95 <50 <50 <50 64 B ms,i 07/25/96 126 B 220 B 153 B 109 B i,t,f,ms 02/25/97 52 B 83 B <50 72 B i,t,f 09/03/97 72 B <50 137 B <50 i,t,f,sd 05/04/98 <50 <50 <50 <50 f,t 11/02/98 <50 <50 <50 <50 i,t,f,lcs 04/26/99 <50 <50 <50 <50 i 11/22/99 <50 <50 <50 61 B d,i,t,f,q 05/23/00 <50 <50 <50 <50 <50 <50 <50 i,tf,q 11/29/00 <50 <50 <50 <50 <50 <50 <50 t, f 06/05/01 <50 <50 53 B 55 B <50 <50 <50 i,t,f 11/13/01 <50 <50 <50 <50 <50 <50 <50 ms,t,f 06/04/02 <50 <50 <50 <50 <50 <50 <50 t 03/12/03 <50 <50 <50 <50 <50 <50 <50 06/18/03 <50 <50 <50 <50 <50 <50 <50 t 12/08/03 <50 <50 <50 <50 <50 <50 <50 06/22/04 <50 <50 <50 <50 <50 <50 <50 11/30/04 <50 <50 <50 <50 <50 <50 <50 06/01/05 <50 <50 <50 <50 <50 <50 <50 cc 11/02/05 <50 <50 <50 <50 <50 <50 <50 05/22/06 <50 <50 <50 <50 <50 <50 <50 11/27/06 <50 <50 <50 <50 <50 <50 <50 i 06/12/07 9.8 JB 20.5 B 17.6 B 35.5 B 9.1 JB 12.7 B 11.7 B 72.1 2.7 10 t, f 12/12/07 9 JB 16.5 B 11.1 B 17 B 20.2 B 13.3 B 24.6 B 2.7 10 i 03/06/08 2.7 10 06/12/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 50.7 B 2.7 10 i 11/05/08 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 <2.7 10.9 B 2.7 10 i 05/19/09 <3.4 <3.4 <3.4 18.5 <3.4 3.4 J <3.4 <3.4 <3.4 3.4 10 11/18/09 <3.8 4.17 J <3.8 32.1 <3.8 5.93 J <3.8 <3.8 <3.8 3.8 10 06/21/10 <3.8 <3.8 <3.8 9.61 J 6.33 J 11.2 <3.8 17.8 24.2 3.8 10 11/18/10 <3.8 <3.8 13 21.2 <3.8 <3.8 <3.8 <3.8 5.08 J 3.8 10 05/23/11 <3.8 <3.8 <3.8 <3.8 <3.8 7.67 J <3.8 <3.8 4.88 J 3.8 10 11/15/11 <3.8 <3.8 <3.8 22.4 <3.8 5.07 J <3.8 <3.8 <3.8 3.8 10 06/05/12 <3.8 <3.8 <3.8 26.4 <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10 11/12/12 <3.8 <3.8 <3.8 32.8 JD <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10 05/13/13 4.32 J <3.8 <3.8 14 <3.8 <3.8 <3.8 <3.8 <3.8 3.8 10 11/11/13 <3.80 <3.80 <3.80 20.4 <3.80 49.2 <3.80 <3.80 4.06 J 3.80 10 05/12/14 <3.80 <3.80 <3.80 10.8 <3.80 <3.80 <3.80 <3.80 <3.80 3.80 10 11/11/14 5.60 J <3.80 5.75 J <7.60 <3.80 4.36 J <3.80 5.08 J 4.13 J 3.80/7.60 10 02/23/15 05/12/15 <3.80 4.40 J <3.80 <3.80 5.74 J 6.20 J <3.80 <3.80 <3.80 3.80 10 08/24/15 11/10/15 4.72 J <3.80 <3.80 6.78 J <3.80 <3.80 <3.80 <3.80 <3.80 3.80 10 INORGANIC CONSTITUENTS: TOTAL METALS QA/QC CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM MW-20 MW-21D HISTORY OF CHEMICAL ANALYSIS LOD SWSLMW-22 MW-23Sample Date MW-15 MW-16 MW-17 MW-21SConstituent MW-24 All results in µg/l. Upgradient wells not shaded. Shaded cells indicate data not available. Blue bolded cells indicate concentrations that exceeded the FBAC. Red bolded cells indicate concentrations that exceeded the NCGQS. Green bolded cells indicate concentrations that were >LOD but <SWSL. i - found in instrument blank t – found in trip blank f - found in field blank ic - initial calibration beyond limits cc – continuing calibration beyond limits md - matrix spike duplicates beyond limits ms – matrix spike beyond limits d - duplicate results beyond limits ss – surrogate spikes beyond limits is - internal standard beyond limits lcs - laboratory control sample beyond limits R - concentration deemed unreliable B – concentration attributed to cross-contamination J - concentration deemed estimated JD - MDL & MRL elevated due to matrix interference; concentration deemed estimated ♠ - additional Appendix 2 constituent - limits not established FBAC - facility background NCGQS – groundwater standard, as established by NCDENR SWSL - solid waste section limit, as established by NCDENR SPL – statistical prediction limit GWPS - groundwater protection standard 43northOrg&Inorg.592 CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY HISTORY OF CHEMICAL ANALYSIS INORGANIC CONSTITUENTS: TOTAL METALS LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM BYPRODUCTS OF GROUNDWATER REMEDIATION GRAPHS 0 20 40 60 80 100 120 140 160 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North landfill -manganese (MW21S + MW-21D) MW-21D MW-21S injection event 1: 03-29-11 outliers removed NCGQS = 50 injection event 4: 09-13-12 0 50 100 150 200 250 300 350 400 450 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North landfill -manganese (MW23 + MW-24) MW-23 MW-24 injection event 1: 03-29-11 NCGQS = 50 no trend through May 2013 injection event 4: 09-13-12 550 600 650 700 750 800 850 900 950 1000 1050 1100 1150 1200 1250 1300 1350 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North landfill -potassium (MW21S + MW-21D) MW-21D MW-21S injection event 1: 03-29-11 outliers removed injection event 4: 09-13-12 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 co n c e n t r a t i o n ( p p b ) date sampled OCSWM North landfill -potassium (MW23 + MW-24) MW-23 MW-24 injection event 1: 03-29-11 outliers removed injection event 4: 09-13-12 TABLES carbon dioxide 03/22/11 55,500 29,100 9,070 16,300 2,000 MCL =05/23/11 130,000 95,900 343,000 65,100 1,300 FBAC = 08/23/11 207,000 131,000 92,200 74,400 1,300 NCGQS = 11/15/11 204,000 123,000 114,000 89,800 1,300 06/05/12 195,000 70,900 34,200 78,600 270 11/12/12 05/13/13 212,000 112,000 46,700 87,800 690 11/11/13 203,000 109,000 87,600 75,500 690 02/10/14 189,000 116,000 60,800 71,100 690/6,900 05/12/14 122,000 86,800 56,100 77,600 690 08/18/14 151,000 104,000 127,000 70,500 210/1,050 11/11/14 215,000 150,000 178,000 91,300 210/440 02/23/15 177,000 145,000 110,000 53,300 210 05/12/15 152,000 B 85600 B 96,300 B 89,600 B 210 08/24/15 255,000 109,000 151,000 84,900 210/1,050 11/10/15 300,000 168,000 170,000 84,000 210/1,050 chloride 03/22/11 44,000 50,000 58,000 56,000 1,900 MCL =05/23/11 44,000 39,000 56,000 48,000 94 FBAC = 08/23/11 47,000 39,000 80,000 51,000 1,900 NCGQS = 250000 (2L Std)11/15/11 42,000 41,000 80,000 53,000 1,900 06/05/12 53,000 38,000 76,000 54,000 430 11/12/12 50,000 37,000 81,000 60,000 1,900 05/13/13 61,000 46,000 78,000 62,000 1,900 11/11/13 66,000 52,000 100,000 64,000 2,200 02/10/14 61,000 52,000 89,000 62,000 1,900 05/12/14 57,000 53,000 93,000 65,000 1,900 08/18/14 69,000 59,000 110,000 67,00 1,900 11/11/14 70,000 59,000 110,000 66,000 1,900 02/23/15 62,000 56,000 100,000 68,000 1,900 05/12/15 65,000 59,000 110,000 72,000 1,900 08/24/15 73,000 62,000 120,000 72,000 1,900 11/10/15 70,000 63,000 130,000 74,000 1,900 manganese 03/22/11 13.6 J 88.7 19.5 J 184 1.1 MCL =05/23/11 15.6 J 60.8 36.9 J 230 1.1 FBAC = 50 (SWSL)08/23/11 10.9 J 44.9 J 21.8 J 311 1.1 NCGQS = 50 (2L Std)11/15/11 44 J 22.4 J 97 287 1.1 SWSL = 50 06/05/12 17.8 J 33.3 J 112 405 1.1 11/12/12 317 11.1 J 267 382 1.1 05/13/13 103 143 50.6 150 1.1 11/11/13 38.4 J 80.7 69.5 89.1 1.10 02/10/14 10.4 19.9 46.3 51.7 1.10 05/12/14 130 101 36.6 J 37.0 J 1.10 08/18/14 12.8 62.9 51.6 28.7 1.10 11/11/14 23.0 J 66.2 53.9 20.5 J 1.10 02/23/15 14.3 J 51.5 29.7 J 37.6 J 1.10 05/12/15 18.7 J 666 70.8 27.6 J 1.10 11/10/15 13.7 J B 21.7 J B 40.5 J B 92.1 B 1.10 potassium 03/22/11 709 978 820 778 150 MCL =05/23/11 702 670 528 780 150 FBAC = 08/23/11 983 681 687 779 150 NCGQS = 11/15/11 691 833 1,300 774 150 06/05/12 770 798 718 872 150 11/12/12 779 869 1,560 833 150 05/13/13 647 665 536 651 150 11/11/13 698 782 814 593 150 02/10/14 735 874 684 762 150 05/12/14 554 607 525 541 150 08/18/14 1,020 1,300 1,150 784 150 11/11/14 900 932 1,150 696 150 02/23/15 873 895 991 855 150 05/12/15 844 833 807 745 150 08/24/15 864 824 1,130 783 150 11/10/15 786 762 1,440 1,060 150 All results in µg/l. Shaded cells indicate data not available. Blue bolded cells indicate concentrations that exceeded the FBAC. Red bolded cells indicate concentrations that exceeded the NCGQS. Green bolded cells indicate concentrations that were >LOD but <SWSL. B – concentration attributed to cross-contamination  - limits not established FBAC - facility background NCGQS – groundwater standard, as established by NCDENRSWSL - solid waste section limit, as established by NCDENR R00597 - 163 BYPRODUCTS OF GROUNDWATER REMEDIATION CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS Constituent Sample Date MW-15 MW-16 LOD GWPS - groundwater protection standard MW-21D MW-21S MW-23 MW-24 INDICATOR PARAMETERS GRAPHS 5.0 5.5 6.0 6.5 7.0 7.5 8.0 st a n d a r d u n i t s date sampled OCSWM North SLF -pH (MW-21S + MW-21D) MW-21S MW-21D injection event 1: 03-29-11 injection event 4: 09-13-12 R² = 0.6124 6.5 7.0 7.5 8.0 st a n d a r d u n i t s date sampled OCSWM North SLF -pH (MW-23) MW-23 Log. (MW-23) outliers removed (Dixon's test) injection event 1: 03-29-11 injection event 4: 09-13-12 0 50 100 150 200 250 300 350 400 450 me V date sampled OCSWM North SLF -ORP (MW-21S + MW-21D) MW-21S MW-21D injection event 1: 03-29-11 injection event 4: 09-13-12 0 50 100 150 200 250 300 350 400 450 500 550 600 me V date sampled OCSWM North SLF -ORP (MW-23) MW-23 injection event 1: 03-29-11 injection event 4: 09-13-12 TABLES pH (standard units)06/22/10 7.06 6.90 7.54 NM 11/19/10 7.15 6.19 6.21 NM 03/23/11 6.03 5.94 7.18 11.90 05/23/11 6.92 6.68 7.12 NM 08/23/11 5.25 5.38 5.32 NM 11/15/11 6.05 6.01 6.87 6.66 6.75 NM 02/21/12 7.00 6.79 6.97 NM 06/05/12 6.95 6.67 6.99 NM 11/12/12 6.96 6.47 6.70 NM 05/13/13 6.55 6.39 6.75 NM 11/11/13 6.17 6.19 7.02 6.71 6.88 6.97 02/10/14 6.79 6.71 7.12 7.10 05/12/14 5.70 6.04 6.48 6.68 6.94 6.98 08/18/14 6.75 5.89 6.56 6.86 11/11/14 6.06 6.09 6.78 6.59 6.74 6.87 02/23/15 6.24 6.48 6.74 6.91 05/12/15 6.80 6.16 7.19 7.08 8.01 7.79 08/24/15 6.72 6.56 6.74 6.86 11/10/15 7.13 7.17 6.92 6.74 6.87 7.03 average = 6.32 6.28 6.72 6.50 6.85 7.53 standard deviation = 0.54 0.44 0.46 0.40 0.53 1.56 ORP (meV)06/22/10 37.7 76.6 24.7 NM 11/19/10 41.9 92.5 28.0 NM 03/23/11 228.0 209.0 71.0 106.0 05/23/11 62.1 45.2 14.0 NM 08/23/11 64.0 123.0 76.1 NM 11/15/11 25.7 68.9 124.0 119.4 431.0 NM 02/21/12 87.0 70.0 69.1 NM 06/05/12 66.8 84.4 498.0 NM 11/12/12 52.7 424.0 548.8 NM 05/13/13 151.0 217.0 198.0 NM 11/11/13 11.1 90.0 77.2 134.6 130.6 112.6 02/10/14 123.3 82.0 100.0 104.5 05/12/14 53.0 46.0 69.0 45.0 64.2 51.2 08/18/14 94.2 112.3 106.6 52.5 11/11/14 28.6 83.3 76.0 88.3 135.4 78.6 02/23/15 98.1 66.6 84.7 50.4 05/12/15 47.3 53.3 74.6 62.2 114.8 67.2 08/24/15 19.6 13.0 16.3 7.0 11/10/15 -159.9 -159.0 -118.8 -162.6 -108.3 -128.7 average = 1.0 30.4 75.2 100.1 137.0 50.1 standard deviation = 80.3 94.3 66.2 110.6 171.3 70.7 Temperature (degrees C)06/22/10 15.8 15.0 14.9 NM 11/19/10 16.2 15.1 16.2 NM 03/23/11 12.1 14.6 13.5 11.9 05/23/11 14.2 14.9 14.6 NM 08/23/11 16.3 15.3 16.1 NM 11/15/11 16.8 16.1 16.7 15.4 16.5 NM 02/21/12 13.7 14.8 14.5 NM 06/05/12 15.7 14.9 14.8 NM 11/12/12 16.6 15.4 16.6 NM 05/13/13 13.3 14.8 13.9 NM 11/11/13 16.5 15.8 16.2 15.2 16.3 15.9 02/10/14 12.2 14.3 13.9 13.0 05/12/14 14.9 14.1 13.2 14.8 14.0 14.9 08/18/14 16.3 15.1 15.5 15.9 11/11/14 16.7 15.5 16.5 15.1 16.3 16.0 02/23/15 11.8 14.3 13.5 12.7 05/12/15 14.8 14.3 13.3 14.8 13.9 14.7 08/24/15 16.5 15.1 15.9 16.5 11/10/15 16.5 15.8 16.6 15.2 16.2 16.0 average = 16.0 15.3 14.9 14.9 15.1 14.7 standard deviation = 0.9 0.8 1.8 0.3 1.1 1.6 MW-23 MW-24ConstituentSample Date MW-15 MW-16 MW-21S MW-21D INDICATOR PARAMETERS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS MW-23 MW-24ConstituentSample Date MW-15 MW-16 MW-21S MW-21D INDICATOR PARAMETERS CLIENT: ORANGE COUNTY SOLID WASTE MANAGEMENT FACILITY: ORANGE COUNTY REGIONAL LANDFILL - NORTH FACILITY LOCATION: CHAPEL HILL, NORTH CAROLINA PROJECT: GROUNDWATER MONITORING PROGRAM HISTORY OF CHEMICAL ANALYSIS Specific Conductance (mS/cm)06/22/10 0.795 0.839 0.476 NM 11/19/10 0.752 0.936 0.709 NM 03/23/11 0.793 0.871 0.601 0.763 05/23/11 0.843 0.941 0.641 NM 08/23/11 0.848 0.980 0.826 NM 11/15/11 0.987 0.428 0.681 0.758 0.726 NM 02/21/12 0.800 0.928 0.828 NM 06/05/12 0.821 0.970 0.756 NM 11/12/12 0.888 1.019 0.910 NM 05/13/13 0.901 1.007 0.721 NM 11/11/13 1.312 0.442 0.969 1.136 1.045 0.945 02/10/14 0.924 0.973 0.806 0.872 05/12/14 1.306 0.510 0.892 0.902 0.868 0.907 08/18/14 0.876 1.021 1.022 0.859 11/11/14 1.288 0.383 0.937 1.141 1.143 0.915 02/23/15 1.029 1.055 1.036 0.916 05/12/15 1.341 0.503 0.998 1.003 0.991 0.921 08/24/15 0.993 1.070 1.157 0.929 11/10/15 1.295 0.565 0.996 1.074 1.131 0.920 average = 1.255 0.472 0.881 0.980 0.863 0.895 standard deviation = 0.132 0.066 0.094 0.097 0.196 0.053 Dissolved Oxygen (%)06/22/10 6.0 14.6 13.2 NM 11/19/10 27.5 14.6 7.4 NM 03/23/11 59.2 12.8 10.0 31.6 05/23/11 91.5 98.0 1.1 NM 08/23/11 8.5 40.6 5.4 NM 11/15/11 16.0 17.0 58.5 9.2 6.6 NM 02/21/12 6.4 2.0 5.9 NM 06/05/12 28.3 10.0 3.6 NM 11/12/12 53.9 72.4 16.7 NM 05/13/13 13.6 80.9 4.4 NM 11/11/13 5.2 7.2 32.7 7.8 7.4 24.7 02/10/14 15.7 2.2 12.7 33.5 05/12/14 1.6 0.6 22.4 3.1 1.2 12.6 08/18/14 4.5 9.3 10.5 24.6 11/11/14 3.3 47.2 41.5 2.2 7.8 22.5 02/23/15 18.4 11.6 9.5 36.0 05/12/15 14.8 27.0 26.4 14.2 18.0 28.5 08/24/15 34.5 2.3 7.0 12.0 11/10/15 5.8 5.5 28.8 27.2 23.5 26.4 average = 7.8 17.4 30.4 22.9 9.0 25.2 standard deviation = 6.1 17.4 22.5 29.0 5.8 8.0 turbidity (NTU)06/22/10 19.6 5.9 7.1 NM 11/19/10 23.0 1.0 5.0 NM 03/23/11 NM 05/23/11 38.0 6.8 5.2 NM 08/23/11 24.0 4.5 3.1 NM 11/15/11 2.7 2.8 22.5 7.1 2.4 NM 02/21/12 15.0 7.1 3.3 NM 06/05/12 15.2 6.2 2.8 NM 11/12/12 6.0 3.0 1.6 NM 05/13/13 1.0 2.2 1.3 NM 11/11/13 1.5 1.3 2.5 0.4 1.8 4.5 02/10/14 4.8 3.9 1.2 1.4 05/12/14 13.0 13.8 8.2 4.2 0.6 1.3 08/18/14 9.1 0.5 0.8 0.4 11/11/14 3.1 4.3 2.9 0.3 0.6 0.5 02/23/15 1.9 0.3 0.5 0.5 05/12/15 7.3 11.5 7.5 0.4 0.6 0.2 08/24/15 22.0 0.5 0.4 0.3 11/10/15 0.0 0.0 0.0 0.0 0.0 0.0 average = 4.6 5.6 12.4 3.0 2.1 1.0 standard deviation = 4.8 5.7 10.6 2.7 2.0 1.4 All values are last recorded immediately prior to sample collection. 03-23-11 - parameters remeasured one day after sampling; suspect faulty meter during sampling NM - Not Measured; well sampled with Hydrasleeve. R00592-163 ATTACHMENT 7 LABORATORY CERTIFICATES-OF-ANALYSIS CHAINS-OF-CUSTODY QUALITY CONTROL INFORMATION POINT-OF-COMPLIANCE WELLS SHARED WELLS SURFACE WATER TRIP BLANKS ATTACHMENT 8 FIELD DATA ATTACHMENT 8 FIELD DATA Groundwater samples were obtained in accordance with the groundwater monitoring requirements of the 15A North Carolina Administrative Code (NCAC) 13B and the Permit. Detailed sampling procedures are documented on a series of groundwater sampling forms (presented at the end of this ATTACHMENT). 1.1 Chronology During November 10, and November 11, 2015 (sampling event 44), Sherrill Environmental, Inc. (Sherrill) personnel obtained groundwater samples from fourteen groundwater monitoring wells at the Orange County Solid Waste Management North Facility (north side of Eubanks Road). During the subject sampling event, the laboratory performed the following chemical analyses:  samples obtained from twelve compliance wells (6801-MW04, 6801-MW06R, 6801- MW07R, 6801-MW14A, 6801-MW14B, 6801-MW15, 6801-MW16, 6801-MW17, 6801- MW20, 6801-MW21S, 6801-MW21D, 6801-MW22) and two surface water locations were analyzed for the constituents listed in 40 CFR Part 258 Appendix I (15A NCAC 13B .1600), plus those constituents listed in Appendix II that have been previously and reliably detected at this facility (mercury, naphthalene, sulfide)  samples obtained from two “nature and extent” monitoring wells (6801-MW23, 6801- MW24), were analyzed for the constituents listed in 40 CFR Part 258 Appendix I (15A NCAC 13B .1600), plus those constituents listed in Appendix II that have been previously and reliably detected at this facility (mercury, naphthalene, sulfide)  samples obtained from four additional wells (6801-MW21S, 6801-MW21D, 6801-MW23, 6801-MW24) were analyzed for chloride and carbon dioxide  samples obtained from four monitoring wells associated with the groundwater remediation injection program (6801-MW21S, 6801-MW21D, 6801-MW23, 6801-MW24), were analyzed for the following additional inorganic constituents, in accordance with the approved Underground Injection Control permit: manganese, potassium  samples of surface water obtained from two locations along Old Field Creek, were analyzed for the constituents listed in 40 CFR Part 258 Appendix I (15A NCAC 13B .1600), plus those constituents listed in Appendix II that have been previously and reliably detected at this facility (mercury, naphthalene, sulfide)  samples obtained from well 6801-MW04 were analyzed for constituents required by regulations for monitoring of C&D landfills (manganese, iron, chloride, sulfate, total dissolved solids, alkalinity) (well 6801-MW04 is associated with the monitoring programs for both the active C&D landfill and North sanitary landfill)  additional samples were obtained from well 6801-MW04 and analyzed for quality control parameters  one trip blank was analyzed for quality control parameters Field Data Page 2 1.2 Well Inspection Prior to sampling groundwater, Sherrill personnel assessed the overall condition of each groundwater monitoring well (including the surface completion). According to documentation provided by Sherrill personnel, all wells were observed to be in generally good condition. 1.3 Static Water Levels Using a graduated electronic water level indicator, field personnel measured static water levels in each well prior to purging. All measurements were recorded to the nearest 0.01 foot (relative to the top of the PVC well pipe). A history of static water elevations is presented in ATTACHMENT 3. 1.4 Purging All permitted wells were purged by Sherrill personnel using dedicated, submersible bladder pumps driven by an electric-powered air compressor and an associated control unit. Wells were purged using a performance-based (“low-flow”) criteria presented in the document Guidelines for Groundwater, Soil, and Surface Water Sampling (NCDENR - SWS; April, 2008). Field purge and sample logs provided by Sherrill are presented at the end of this ATTACHMENT. 1.5 Groundwater Stability The performance-based purging method essentially involves purging groundwater from a monitoring well at a sufficient rate so as not to significantly disturb the water column. During the purging process, several water quality parameters (pH, specific conductance, water temperature, dissolved oxygen, turbidity, ORP) are periodically measured until successive readings are generally consistent (within 10%). Additional purging criteria are presented in the Guidelines document discussed above. During the subject sampling event, the monitoring wells were purged until several consistent field parameter readings were recorded. These parameters were measured in order to help ensure that representative groundwater samples were obtained. Groundwater samples were obtained immediately after the physical parameters had stabilized. Field Data Page 3 Stability is defined in the Groundwater Monitoring Plan as a deviation of less than 10% for two consecutive readings. Readings recorded for each well are presented at the end of this ATTACHMENT. Note. When water levels are low in a well, or when the screened portion of the aquifer is characterized by low hydraulic conductivity, the well may be purged to dryness. In such cases, field personnel will allow time for groundwater levels to equilibrate, and restart the sampling process from the point at which it was interrupted. If the well again purges to dryness, the technician will obtain samples as the well recharges. In such cases, the groundwater samples are deemed “representative” even if the usual stable readings cannot be obtained. 1.6 Well Sampling Groundwater samples were obtained immediately after the water quality parameters had stabilized. The QA/QC analyses were performed on the samples obtained from well 6801-MW4. 1.7 Well Sampling Order On November 10, 2015, Sherrill personnel sampled wells in the following order: 6801-MW04. On November 11, 2015, Sherrill personnel sampled wells in the following order: 6801-MW06R, 6801-MW07R, 6801-MW23, 6801-MW24, 6801-MW21S, 6801-MW21D, 6801-MW14B, 6801- MW14A, 6801-MW22, 6801-MW15, 6801-MW16, 6801-MW17, 6801-MW20. On November 11, 2015, Sherrill personnel sampled surface water locations in the following order: 6801-SW1, 6801-SW2. 1.8 Preservation At the laboratory, all sample containers were prepared with preservative by ENCO if required by the method in SW-846. All samples were placed beneath ice in coolers immediately after the samples were obtained. Field Data Page 4 1.9 Sample Transport Immediately after the samples were obtained, they were placed beneath ice in insulated containers for transportation to the laboratory. All samples obtained during the subject sampling event were delivered by Sherrill personnel to ENCO on November 11, and 12, 2015. The trip blanks were delivered to ENCO on November 11, 2015. Upon arrival at the laboratory, all temperatures inside of the insulated containers were measured and found to lie within acceptable limits (< 4°C). All samples were placed in a refrigerator upon arrival and held at approximately 4°C until the time at which they were analyzed. Additional information concerning each monitoring well is presented at the end of this ATTACHMENT. Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW04 Well I.Diam: Measurements from TOC Screened interval: ------Date: l l!tD/2015 Time: Weather: 9 "fl) 1 • SZ ')tr, ul Personnel: J. Sherrill, LG Total well depth (TD): 55.33 Length of water column: Z.. ~ ,() Total water volume purged: 5.5 Depth to water (DTW): 3 '2.., 3 ~ Volume in well (gal): r:3,0/ 3,0 Method Purged: Dedicated Bladder Pump Method sampled:_--=D~ed=ic=a=te=d-=B=la=d=de=r~P-=um=p _______ _ Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) Z,0 B55 ~,5-:f ,s,,t,i O.D-=l-6 7'1,-:::; -,,, $ S . .5 3 { (') qro S.6 °I tS.hJ O.D':/ 6 ·=,3. ~ -1:i.iq sto 'i,S 9oS Sr=l r 15,,6<-O,o={ b 72, r; -IB6 3,'f S,5 CfoR S,12 f S, {;, < 0 ,Di!:,, 7:ll, 0 -s z. 2..,R Remarks on Sampling and Well Condition: Sample Collection Time: °\ I D Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF-NORTH Permit No.: 68-01 Date: 11/ II /2015 Time: SL£0 Weather: .SS Client : Draper Aden ----WELL NUMBER: MW06R Well I.Diam: Measurements from TOC Screened interval: ------Personnel: J. Sherrill, LG Total well depth (TD): 53.66 Depth to water (DTW): '2.. 5 . S i-f Length of water column: 2-.'6, lZ.. Total water volume purged: 2. ,D Volume in well (gal): L-(, 5 Method Purged: Dedicated Bladder Pump Method sampled: Dedicated Bladder Pump Purge Time pH Temp Specific Dissolved ORP Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) D.B sso lo. 03 t t, ,8 0,325 VJ~ I -It ,3 l tr) 855 fp,03 ll,,ffl 0. -~Lb b 3,, I -Z.':l.S \ l 5 qoo (,.,. r,-, lfo 9/J I), 3 3 l '1 q. ( -t.{ fa,=l 2.tO 9DS fn.D'-l 1'1.~t 0. '3'2.. \ 3°t P1 -S-=l.S Remarks on Sampling and Well Condition: CJse.-r-e..pl"-'-e"""<~ '{~l ~e+e.r, Sample Collection Time: °l O "'.:)... Turbidity (NTU) D.D D~D 0,0 DO Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW07R Well I.Diam: Measurements from TOC Screened interval: ------Date: Time: Weather: Personnel: l 1/1 l/2015 C, I ':\--J. Sherrill, LG Total well depth (TD): 21.92 Depth to water (DTW): ID ,30 Length of water column: I I • CJ L. Volume in well (gal): __ I ,_B __ Total water volume purged: 2 ;D Method Purged: Dedicated Bladder Pump Method sampled:_---=-D"""'ed=ic=a=te--=d~B=la=d=de=r-=P~um==.-p _______ _ Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) 0.? qz.o ft,, bl ,s.2, D,qo":l 22, 3 -4C,..~ 2,' () \ ~ 925 t;, :f J I) r {l > 0, 9 <o4 l l. ~ -~( '" /J.~ \ \.1) q U; h,17 { f>r If o,qe4 lDc':> -Bl,? 0,Lf (' ~ q7,~ (p ,ra'o 15.( L\ O r q ~"":\ 9 .0\. -8=J. () D~D Remarks on Sampling and Well Condition: Sample Collection Time: 9 l\ D Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW14A Well I.Diam: Measurements from TOC Screened interval: ------Date: 11/ l (/2015 Time: / 2.. 2.. 0 f'Dv Weather: <o Personnel: J. Sherrill, LG Total well depth (TD): 14.88 Depth to water (DTW):----'-S_,_3_:f:.____ Length of water column: q I 5 4 Volume in well (gal): _,_. _s __ _ Total water volume purged: 3 r 5 Method Purged: Dedicated Bladder Pump Method sampled: Dedicated Bladder Pump Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) ID t z..zs fo,Zr l ':\-l ll, IH+f 9 .. B -1~8,5 "'3 l" 2.,0 t13D (p ,/~ l 1. 7il. l ,LftfO 2.5. z.. -lCF(.z_ 0,$ 3,D l 235 (p,3'1 l1. Jl, I 14'2-fA G,512.. -q,,L ('),0 ~ { z; l231-ro.-z_r; C:? 3'1 l, 4 3'f lf 3 r ~ -100. '=l-(),tf Remarks on Sampling and Well Condition: Sample Collection Time: / 2. Lf D ~-----------~~ Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW14B Well I.Diam: Measurements from TOC Screened interval: _____ _ Date: 11/ /(/2015 Time: i I 5D Weather: 6::D -----Personnel: J. Sherrill. LG Total well depth (TD): 34.16 Depth to water (DTW): 5:, 3 2-Length of water column: 2-B,S:1 Volume in well (gal): _q....c.....:....,&;,=---Total water volume purged: "Lt B Method Purged: Dedicated Bladder Pump Method sampled:_--=D-=ed=i=ca=te=d"-"B=l=ad=d=e"-'r P"-'um=p;:........... _______ _ Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) bf l.f (m:) (;,, 2.=l I ':f-,(,~ l. Z'-1. 0 ,q.o -, t/ {,. ( q,/ ( 'Lt IZO'S fa 2..D 11,:J-Z, 1. ? f,.. I ~. { -t1Z.9 1L2 t..,t-t 12.10 ~,2!) r1.11 ( I 2-.<'i, l, :+. l -l e8,D C.T "2.,]; 12..rs /p,tCo lt.Ptt, I, L 1" Lf -=l-t 't; -t'1r,=, 0, <; Remarks on Sampling and Well Condition: Sample Collection Time: I 7-l :}- Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Date: 11/t( /2015 Time: f 3ZO Client : Draper Aden Weather: 0 0 CY c .. / /7d1 ,,,... WELL NUMBER: MW15 Personnel: J. Sherrill, LG Well I.Diam: Measurements from TOC Screened interval: ------Total well depth (TD): 28.36 Depth to water (DTW): Length of water column: 2. 1...., '-f \ Volume in well (gal): Total water volume purged: 5 ,0 Method Purged: Dedicated Bladder Pump Method sampled: Dedicated Bladder Pump Purge Time pH Temp Specific Dissolved Vol. (G) (C) Cond. (mS/cm) Oxygen(%) I. c; Is~ 1,35" /6.'f't) (,3/) z. 6 . I 3tD /3~5 1.3) lb.>I r. z.q B St9 Li.,; t?>'tO 1,15 (~.52 l, zct re, Sri 5,D ( 3'12-1( /3 lbpSZ I , Z..C\ S >rS Remarks on Sampling and Well Condition: Sample Collection Time: f 3 t/ Lf ORP (mV) -( z.B.o -Jtf(p, 3 -[~":}. f -15'1/1 Turbidity (NTU) o.o D.O 0,0 nto Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden Date: 11Ill/2015 Time: I 355 /00 Weather: '° WELL NUMBER: MW16 Personnel: J. Sherrill, LG Well I.Diam: Measurements from TOC Screened interval: ------Total well depth (TD): 32.47 Length of water column: 2-9, ~::S Total water volume purged: 5 ,5 Depth to water (DTW): 3., 1.... Volume in well (gal): 4, ~ Method Purged: Dedicated Bladder Pump Method sampled: __ D~ed=ic~a=te~d_B~la~d~de=r~P~um_p _______ _ Purge Time pH Temp Specific Dissolved ORP Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) LS l"t()C) -=}. \?.. rs:=H, O,SI~ b.3 -145,=1 3,S \1.\0:S 1. l 5 l53'f 1LS35 4:1. 6 -ISL I t:t O (Lf ,o 't.l1 ( S".1i 1>, ~s 8 ~cb -I ~f ~ S', s \ lf l 2 =?. ( 1 ,~.1~ /) r ~I:,) ~·~ -Is'{. C:.. Remarks on Sampling and Well Condition: ( t-+ ("C Sample Collection Time: _1 J Turbidity (NTU) 0.0 eJ.O D.() • o.o Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MWl 7 Well I.Diam: Measurements from TOC Screened interval: ------Date: 1 lA \/2015 Time: I '-( Z.. 2-Weather: f, 0 ----Personnel: J. Sherrill. LG Total well depth (TD): 47.54 Depth to water (DTW): 5. 6 2 Length of water column: 3 Sr 5' L. Volume in well (gal): ___.,"'---'--r _/ __ Total water volume purged: Sr O Method Purged: Dedicated Bladder Pump Method sampled: Dedicated Bladder Pump Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) 0, '2_ l't 2.5 b,11 ,r.~e 0. 'l'c, '{ ("{, z. -5'?.D 6.0 '2.., 0 I'"( 3l> 6~43> 15:~ f.06( 6.0 -I O=J.,l D.D 3t5 f"f3S {p .C'l9 .~.6=1 ', om-~.~ -ltf O.b DD S, o I 1'1D ,.1, 15,Jli l I ( l c 5. """?:, -1s1.2. o.o Remarks on Sampling and Well Condition: Sample Collection Time: f 4 '12- ---------~ -----~~~~ Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Date: 11/t (/2015 Time: I '-I '-1-=4--Client: Draper Aden W eather: C:, 0 ---=-----WELL NUMBER: MW20 Personnel: J. Sherrill. LG Well I.Diam: Measurements .from TOC Screened interval: ------Total well depth (TD): 48.43 Depth to water (DTW): Length of water column: W, '16 Volume in well (gal): Total water volume purged: 3 t O Method Purged: Dedicated Bladder Pump Method sampled:_-=D=ed=ic=a=te=d-=B=la=d=de=r--=-P-=um=-p _______ _ Purge Time pH Temp Specific Dissolved ORP Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) 1.0 l1tS5 "' Lf2 t'g,Z.'::1-2 I qJ../ °3, t-/, b -/§'/, 2. '2.0 r 5oe, '1.33 IS,38 2 ,'102.. '-/, ~ -I bS,7 2.,S L ~OS '1.ZS l 8,ttt 2,8Bb '-f. B -f-:,t:,.B s.o l ~{O "~ 3/ 18/t/ z_.q I I L{.a -182 .0 Remarks on Sampling and Well Condition: Sample Collection Time: / ) / tf Turbidity (NTU) 8.D 5,7 1.5 lf,B Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW21S Well I.Diam: Measurements from TOC Screened interval: ------Date: Time: Weather: Personnel: 11/ l C/2015 fb q5 J. Sherrill. LG Total well depth (TD): 25.14 Length of water column: 2 '2...,C>S Total water volume purged: 3, 2 Depth to water (DTW): 3 ,ob Volume in well (gal): _3~, 5"""'---- Method Purged: Dedicated Bladder Pump Method sampled:_~D~ed=ic=a=te-d~B=la=d=de=r~P~um=--p _______ _ Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) L 2-1050 ":f;03 lb.SS D,°tfo8 lf br D -«a=i·=i ~.o 2l> 1055, t.D 3 l~'fB 6 .. 'tfo4 '-f .8 --I~ 3,0 D.O 3 ~D I( ?>0 (p,q~ th,S:, (\ • ct. 8 S 3-=7,3 ~ ltz.·s 0,0 3 t 2-l l lJ 2 b. °L 2 I{,, ~·s-(),qq(p 2 ~rg -( L8,B D,D Remarks on Sampling and Well Condition: Sample Collection Time: I I O l-f \\D l2> Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Date: Time: 111(( /2015 It D:/-Client : Draper Aden Weather: ~0~0~0 __ WELL NUMBER: MW21D Well I.Diam: Measurements from TOC Screened interval: ------Total well depth (TD): 54.55 Length of water column: 5 Z.., ~ 3 Total water volume purged: S, 0 Personnel: J. Sherrill. LG Depth to water (DTW): I , 9 2 Volume in well (gal): 8 r '-I Method Purged:_---=D=e=d=ic=at=ed=-=B=la=dd=e=-r=-Pum=P~------- Method sampled:_~D~ed=ic=a=te=d~B=la=d=de=r~P~um=--p _______ _ Purge Time pH Temp Specific Vol. (G) (C) Cond. (mS/cm) \ \ 2.. 1115 (o,71z; l~ICi I, DB l- 2,5 ( f 2.0 6, ,":/-'-( 15',,<o L08l.f Lt, 0 l(Z..5 t, ,t4 rs,rs (i 0~2_ Seo (l 3C 4,.~ l 5, {-:+ /,07:/:Lf Remarks on Sampling and Well Condition: tJ eels I c,c,K Sample Collection Time: If 3S Dissolved ORP Oxygen(%) (mV) to, 3 «-('12,°l cc.~ -( 1,33 S,~ -Ll/J. ~ z1. 1--(6Z.,6 Turbidity (NTU) (),0 0.0 O .. C) 0,.0 Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Date: 111\l /2015 Time: (Z...~5 Client : Draper Aden Weather: ~'~{) ___ _ WELL NUMBER: MW22 Well I.Diam: Measurements from TOC Screened interval: ------Personnel: J. Sherrill. LG Total well depth (TD): 64.92 Length of water column: CJ 2... 1 SZ. Total water volume purged: 5 ,0 Depth to water (DTW): Z. · (0 Volume in well (gal): f D, (JS Method Purged:_----=D=e=-=d=ic=at=e=-d =B=la=dd=e=r-=-Pum=p _______ _ Method sampled: __ D~ed=ic~a=te-d~B~la~d=de~r~P~um=-p _______ _ Purge Time pH Temp Specific Dissolved ORP Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) LD IZ.SD =t. Pi, lb ,,if l. 4:bO r o. , -t'3lf.3 ~,'S C'l.t;_s +Pfs l b-3l fr3C{'=, \3 .. 9.., - t 'f'r,~ .3t s 13,(X) 8~0; l (o .. '[J.. l. ~ 'S°L lD~lP -I b3, 3 s ,l? t~o-s ~lft t b. 2..3 t ( 3Co ( (2. l 3 -\-=?0t0 Remarks on Sampling and Well Condition: Sample Collection Time: [ '.s O -=t- Turbidity (NTU) I, 'f D,0 0.l) o,o Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW23 Well I.Diam: Measurements from TOC Screened interval: ------Date: 11/fl/2015 Time: °!'1~ Weather: S 5 ----Personnel: J. Sherrill, LG Total well depth (TD): 32.23 Depth to water (DTW): '2., ::\ 3 Length of water column: 2. 4, S Volume in well (gal): _L~f-"--, + __ Total water volume purged: SrD Method Purged: Dedicated Bladder Pump Method sampled: Dedicated Bladder Pump Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) I.D °LSD br9-f /6.0? /. 171 D z.-::;.q -/~2,8 t)t I 2-,0 q55 ",Sb ({a,~ I. I 4 ~ 3~, 3 -f( 'f, 1..-1 o.o t-f ,O ll>bo to,S1 I b. 2_-:, ( . l ( q 2-t>,3 -I D5.S D,l) 5,D /0()3 IP. Si (6ll f , I 3 \ 2.3,~ -t OR, 7> o.o Remarks on Sampling and Well Condition: Sample Collection Time: ( DO .5 Sherrill Environmental, Inc. GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Name: Orange Co. LF -NORTH Permit No.: 68-01 Client : Draper Aden WELL NUMBER: MW24 Well I.Diam: Measurements from TOC Screened interval: ------Date: 11/fl /2015 Time: I 0/D Weather: IPO ~---Personnel: J. Sherrill, LG Total well depth (TD): 38.28 Depth to water (DTW): 3, OB Length of water column: !:> 5, 2-Volume in well (gal): -~S"--,&, __ Total water volume purged: 3 t €, Method Purged: Dedicated Bladder Pump Method sampled: __ D=ed=ic=a=te=d-=B=la=d=de=r--'--P-=um~P-------- Purge Time pH Temp Specific Dissolved ORP Turbidity Vol. (G) (C) Cond. (mS/cm) Oxygen(%) (mV) (NTU) I), 3 I/IS ':f.DO 15,'1( /), q lo ( q,q -{D1b Oen t , 5 L D Z.1) 1.D ( 15.B( O t~ 'i8 ~St~ -l 3J/f O,D 2.., 5 IOZ.S ':/.DD ( f>,9~ o, ct'-t '2.. 1 l . 2--, 'f s. z o.o s,S lD3C =!.b3 Lt, ,Dl D ,Dz 1-0 1.. (,,, 'i -\ Z..8r1 OrD Remarks on Sampling and Well Condition: Sample Collection Time: ( D ~ ~ ATTACHMENT 9 STATISTICAL ANALYSES ATTACHMENT 9 STATISTICAL ANALYSES Statistical analyses were previously performed in order to establish facility background concentrations for all Appendix I constituents. A report was submitted to NCDENR during October, 1998. During 2007, NCDENR promulgated Solid Waste Section Limits (SWSLs) for listed organic and inorganic constituents, and for most general chemistry parameters. The SWSL values were established in lieu of laboratory Practical Quantitation Limits (PQLs), and are intended to function as the laboratory reporting limits. Previously-determined facility background values have been replaced with their respective SWSL (where appropriate). The only exception is total barium, where the background concentration (a statistical prediction limit) was previously calculated as 500 g/l, and the SWSL is 100 g/l. The most current facility background concentrations (denoted as “FBAC” values) are shown on a series of tables summarizing the history of groundwater chemistry at the North landfill (ATTACHMENT 5 and ATTACHMENT 6). ATTACHMENT 10 QUALITY CONTROL ASSESSMENT ATTACHMENT 10 QUALITY CONTROL ASSESSMENT 1.0 FIELD QUALITY ASSURANCE / QUALITY CONTROL Rigorous sampling protocols were employed during groundwater sampling to help ensure that each sample is representative of groundwater in the aquifer. Any non-dedicated equipment used to purge and sample monitoring wells was decontaminated before and after sampling each well. In addition, trip blanks were analyzed in order to help validate the observed concentrations of specific constituents. The concentration of each constituent observed in groundwater was compared to the concentration observed in each blank in accordance with the following rules:  With regard to common organic laboratory contaminants (acetone, 2-butanone, methylene chloride) and common phthalate contaminants, if the concentration in groundwater is less than ten times (10x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination.  With regard to organic contaminants that are not commonly used in the laboratory and inorganic contaminants in general, if the concentration in groundwater is less than five times (5x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination. 1.1 Deviations from the Plan All sampling techniques met the specifications set forth in the Groundwater Monitoring Plan. 1.2 Trip Blanks Trip blanks were prepared by the laboratory and transported by field personnel to each monitoring well location. Trip blanks remained in the insulated container, and the lids of the containers were never removed from the time the vehicle left the laboratory until the time field personnel delivered the samples to the laboratory. Trip blanks were analyzed for all constituents listed in 40 CFR Part 258 Appendix I (15A NCAC 13B .1600) that are typically analyzed using EPA Method 8260B. No target analytes were detected within the trip blank. Quality Control Page 2 2.0 LABORATORY QUALITY ASSURANCE / QUALITY CONTROL A limited QA/QC review was performed on the data provided by ENCO Laboratories. In general, the Environmental Protection Agency's (EPA) Contract Laboratory Program (CLP) guidelines for data validation in Region III were followed; however, SW-846 control limits (latest promulgated edition) were used for QA/QC requirements. Specifically, laboratory blanks were analyzed in order to help validate the observed concentrations of specific constituents. The concentration of each constituent observed in groundwater was compared to the concentration observed in each blank in accordance with the following rules:  With regard to common organic laboratory contaminants (acetone, 2-butanone, methylene chloride) and common phthalate contaminants, if the concentration in groundwater is less than ten times (10x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination.  With regard to organic contaminants that are not commonly used in the laboratory and inorganic contaminants in general, if the concentration in groundwater is less than five times (5x) the concentration in the blank, then we conclude that the constituent in the groundwater sample may be attributed to cross-contamination. 2.1 EPA Method 8260B (volatile constituents) As part of the QA/QC review, the following were examined:  technical holding times and preservation requirements  blank analysis  transcription/confirmation errors After reviewing the quality control data provided by ENCO Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW- 846 for the referenced method. 2.2 EPA Method 6010C (ICP - metals) As part of the QA/QC review, the following were examined:  technical holding times and preservation requirements  blank analysis  transcription/confirmation errors Quality Control Page 3 After reviewing the quality control data provided by ENCO Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW- 846 for the referenced method. 2.3 EPA Method 6020A (ICP - metals) As part of the QA/QC review, the following were examined:  technical holding times and preservation requirements  blank analysis  transcription/confirmation errors After reviewing the quality control data provided by ENCO Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW- 846 for the referenced method. 2.4 EPA Method 7470A (total mercury) As part of the QA/QC review, the following were examined:  technical holding times and preservation requirements  blank analysis  transcription/confirmation errors After reviewing the quality control data provided by ENCO Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW- 846 for the referenced method. 2.5 EPA Method SM 4500S2 D-2000 (sulfide) As part of the QA/QC review, the following were examined:  technical holding times and preservation requirements  blank analysis  transcription/confirmation errors After reviewing the quality control data provided by ENCO Laboratories, the reviewer determined that the dataset met all requirements of the criteria listed above, as specified by SW- 846 for the referenced method. [QUALITY CONTROL DOCUMENTATION, AS PROVIDED BY THE LABORATORY, IS PRESENTED IN ATTACHMENT 7, ALONG WITH THE ASSOCIATED CERTIFICATE-OF-ANALYSIS] ATTACHMENT 11 CORRESPONDENCE