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HomeMy WebLinkAboutSW_F_8807-MSWLF-1990_06-13-2013_RM_GW.pdf PREPARED FOR: TRANSYLVANIA COUNTY SOLID WASTE 500 HOWELL ROAD BREVARD, NORTH CAROLINA 28712 TRANSYLVANIA COUNTY WOODRUFF LANDFILL PERMIT NO. 88-07 FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2013 JUNE 2013 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 00336.1200.11 First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 i First Semiannual Water Quality Monitoring Report of 2013 Woodruff Landfill Transylvania County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION....................................................................................................... 1 1.1 Site Information .......................................................................................................... 1 1.2 Site Geology ................................................................................................................. 1 1.3 Regulatory Status ........................................................................................................ 1 2.0 FACILITY MONITORING PROGRAM ................................................................ 2 2.1 Groundwater Monitoring Program .......................................................................... 2 2.2 Surface Water Monitoring Program ......................................................................... 2 2.3 Leachate Monitoring Program .................................................................................. 3 3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2013 ......................................... 3 3.1 Field Work ................................................................................................................... 3 3.2 Laboratory Analysis and JOYCE Quality Control ................................................. 4 4.0 HYDROGEOLOGICAL CONDITIONS ................................................................. 5 5.0 DATA ANALYSIS AND STATISTICAL RESULTS ............................................. 6 5.1 Analytical Results and Comparisons to Standards.................................................. 6 5.1.1 Groundwater ....................................................................................................... 6 5.1.2 Surface Waters .................................................................................................... 7 5.1.3 Leachate .............................................................................................................. 7 5.2 Statistical Methods ...................................................................................................... 7 6.0 CONCLUSION ........................................................................................................... 7 7.0 REFERENCES ............................................................................................................ 8 Tables Table 1 Summary of Historical Groundwater Elevations Table 2 Groundwater Gradient and Flow Rate Calculations Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Groundwater Field Parameters Table 5 Summary of Historical Surface Water Constituents Table 6 Summary of Historical Surface Water Field Parameters Table 7 Summary of Historical Leachate Constituents Table 8 Summary of Historical Leachate Field Parameters First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 ii First Semiannual Water Quality Monitoring Report of 2013 Transylvania County Woodruff Landfill Transylvania County, North Carolina TABLE OF CONTENTS CONTINUED Figures Figure No. 1 Site Location Map Drawings Drawing No. 1 Potentiometric Surface Contour Map Appendices Appendix 1 Laboratory Analytical Reports and Field Data Logs First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 1 1.0 INTRODUCTION 1.1 Site Information The Woodruff Landfill is owned and operated by Transylvania County and is currently operating under North Carolina Solid Waste Permit No. 88-07. The landfill property is located southwest of Rosman, North Carolina, between the French Broad River and the Tennessee Valley Divide. The property boundary and disposal area are indicated on an excerpt from enlarged USGS topographic maps for Eastatoe Gap and Rosman, North Carolina (Figure No. 1). The disposal area is located on a topographic high that slopes downward to the west, southwest, and northwest. Phases 1 and 2 were designed with a single geomembrane liner and a leachate collection system. Waste disposal began in Phase 1 in May 1992. Phase 3 was constructed with a composite liner, while Phase 4 was constructed using an alternate composite liner. Both Phase 3 and Phase 4 were constructed with a leachate collection system. Phases 1 through 4 comprise approximately 13.3 acres. A leachate lagoon was located at the northwest corner of the approximately 8.5-acre lined area of Phases 1, 2, and 3. This lagoon was abandoned in October 2003 during construction activities, and replaced with a storage tank located northwest of Phase 4, as shown on Drawing No. 1. Leachate is sampled directly from this tank and the sample is identified as LMP-3. Waste disposal began in May 1992 in the western (downgradient) portion of the landfill, and has progressed to the east into Phase 4. The Phase 5 expansion of 5.5 acres was constructed with a composite liner and leachate collection system in 2007. Waste disposal into Phase 5 will begin upon reaching capacity of Phase 4. 1.2 Site Geology The Woodruff Landfill is located in the Inner Piedmont physiographic province within the Chauga Belt, just southeast of the Brevard Fault Zone. The unit within the Chauga Belt that underlies the site is the Henderson Gneiss, which consists of mylonitic gneisses (Brown, 1985). The mineralogy consists of biotite, muscovite, feldspar and quartz with iron-manganese staining. 1.3 Regulatory Status The Transylvania County Woodruff Landfill groundwater monitoring is completed in accordance with North Carolina Division of Waste Management, Solid Waste Section (SWS) Rule § 1633 (Detection Monitoring Program). Statistical analyses of the laboratory data has been prepared in accordance with the required compliance demonstration of the SWS Rule .1632(g), (h), and (i). First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 2 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Woodruff Landfill is completed in accordance with the Detection Monitoring Program and the Water Quality Monitoring Plan for the facility. Groundwater samples are collected semiannually and are analyzed for North Carolina Solid Waste Section Appendix I constituents. The monitoring network at the Woodruff Landfill consists of two upgradient wells (MW-3 and MW-10) and eleven downgradient monitoring wells (MW-1, MW-2, MW-5, MW-6, MW-8, MW-9SR, MW-9D, MW-11, MW-12S, MW-12D, and MW-13). MW- 9S was abandoned due to deterioration of the well casing. MW-9SR was installed on September 26, 2011 as the replacement for MW-9S in the groundwater monitoring network. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-1 4/16/91 Compliance Detection 32.66 Not Available MW-2 4/16/91 Compliance Detection 25.42 Not Available MW-3 4/16/91 Background Detection 42.55 Not Available MW-4 4/17/91 Abandoned - - - MW-5 4/17/91 Compliance Detection 35.02 Not Available MW-6 9/19/94 Compliance Detection 24.00 PWR/Bedrock MW-7 9/21/94 Abandoned - - - MW-8 9/20/94 Compliance Detection 34.56 PWR/Bedrock MW-9S 1/09/01 Abandoned - - - MW-9SR 9/26/11 Compliance Detection 43.10 Fill/PWR MW-9D 1/09/01 Compliance Detection 86.50 Bedrock MW-10 11/13/06 Background Detection 40.50 Bedrock MW-11 11/09/06 Compliance Detection 26.50 PWR/Bedrock MW-12S 11/21/06 Compliance Detection 33.50 Saprolite/Fill MW-12D 11/21/06 Compliance Detection 52.50 Bedrock MW-13 11/20/06 Compliance Detection 48.41 Bedrock 2.2 Surface Water Monitoring Program Surface water monitoring at the Woodruff Landfill is completed in accordance with NCSWMR §0602 (Surface Water Monitoring) and the approved Water Quality Monitoring Plan for the facility. Surface Water samples are collected semiannually and are analyzed for North Carolina Solid Waste Section Appendix I constituents. The surface water monitoring network consists of two sampling points: SMP-1 is located downstream from the sediment pond below the leachate tank, and SMP-3 is located approximately 150 feet downstream from MW-11. First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 3 Surface Point Classification Monitoring Program SMP-1 Compliance Surface Water SMP-3 Compliance Surface Water 2.3 Leachate Monitoring Program One leachate monitoring point (LMP-3) is sampled at the Woodruff Landfill on a semiannual basis and the following constituents are included in the leachate laboratory analysis:  North Carolina Appendix I Metals  North Carolina Appendix I 8260 Volatiles  BOD  COD  Sulfate  Phosphorus  Nitrate 3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2013 3.1 Field Work On April 23-24, 2013, personnel from Joyce Engineering (JOYCE) visited the Woodruff Landfill to obtain water levels to the nearest 0.01 foot, purge, and sample tweleve monitoring wells (MW-9SR has a bend approximately twenty feet below ground and was not sampled), two surface monitoring points, and one leachate monitoring point. Monitoring wells were purged and sampled using disposable bailers during the April 2013 sampling event. Measurements of temperature, pH, specific conductivity, and turbidity were recorded prior to purging, after each purge volume, and during sampling. Copies of the field data logs are presented in Appendix 1. Prior to sampling, laboratory- supplied containers were prepared with the following information:  Monitoring well number (completed by field personnel),  Date and time of sample collection (completed by field personnel),  Initials of sampling personnel (completed by field personnel),  Project name and number (completed by the laboratory),  Chemical preservative (completed by the laboratory); and  Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers in the provided laboratory containers either immediately after purging First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 4 or within 24 hours of the final purge volume. Immediately after collection, the samples were placed in a laboratory provided cooler and chilled on ice. Surface water samples were collected directly from stream flow, by lowering the prepared sample containers into the stream flow with the opening facing into the current flow. Care was taken not to overflow the sample containers (which could lead to preservative loss) and to avoid sample-induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Leachate samples were collected from the leachate storage tank. Prepared sampling containers were filled, placed in a cooler, and chilled on ice. At the time of sampling, leachate was measured for temperature, pH, specific conductivity, and turbidity. 3.2 Laboratory Analysis and JOYCE Quality Control The April 2013 groundwater, surface water, and leachate samples were submitted to Pace Analytical Services, Inc. of Asheville, North Carolina under chain-of-custody control for analysis. As presented earlier, the groundwater and surface water samples were analyzed for North Carolina Appendix I constituents, while leachate samples were analyzed for North Carolina Appendix I constituents plus BOD, COD, Phosphorous, Sulfate, and Nitrate. The samples were received by the laboratory on April 23-24, 2013 in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the Woodruff Landfill, a Field Blank was collected by JOYCE personnel as part of the April 2013 sampling. Also, a Trip Blank prepared by the laboratory to accompany the volatile sampling containers to and from the laboratory during the April 2013 event. The Field Blank was analyzed for North Carolina Appendix I constituents, while the Trip Blank was analyzed for North Carolina Appendix I volatile organics only. Upon receipt of laboratory data packages, the data was reviewed by JOYCE personnel for the following:  General typographical errors,  Correct analyses performed and within method specified hold times,  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples,  Blank qualified data (B-flags); and  Quantified detections above the North Carolina Groundwater Protection Standards (GWPS), NC 2L Groundwater Standards (NC 2L), and NC 2B Surface Water Standards (NC 2B). First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 5 4.0 HYDROGEOLOGICAL CONDITIONS Depth to groundwater was measured in the compliance monitoring wells at the site prior to sampling. The groundwater elevations were calculated relative to the surveyed measuring point (top of casing) for each monitoring well. The groundwater elevations are summarized in Table 1. The potentiometric surface contours shown in Drawing No. 1 are based on data from the April 2013 sampling event. Groundwater flow direction beneath the waste management unit is primarily to the west. Estimated horizontal groundwater gradients from the April 2013 groundwater elevations are presented in Table 2. The horizontal gradients calculated for the facility from these data ranged from 0.0581 ft/ft to 0.0862 ft/ft. Based on this data, the groundwater monitoring network remains sufficient to adequately monitor groundwater at the site. Linear groundwater flow velocities for wells screened in saprolite were computed using the following modified Darcy equation: V = Ki/n where V = average linear velocity (feet per day – ft/day), K = hydraulic conductivity (ft/day), i = horizontal hydraulic gradient, and n = effective porosity. A hydraulic conductivity (K) of 8.79 E 10–2 ft/day based on results from slug testing and an estimated effective porosity of 20% based on soils typical of this region were used to estimate average linear groundwater flow velocities for Phases 1 through 4. A hydraulic conductivity (K) of 2.92 E 10–1 ft/day based on results from slug testing and an estimated effective porosity of 20% based on soils typical of this region were used to estimate average linear groundwater flow velocities for Phase 5. The calculated flow velocities are summarized in Table 2. The estimated linear groundwater flow velocity under the waste management unit ranges from 0.026 ft/day to 0.029 ft/day under Phases 1 through 4, and 0.126 ft/day under Phase 5. The linear velocity equation and resulting rates make the simplified assumptions of a homogeneous and isotropic aquifer. Application of this equation to a fractured bedrock aquifer is likely to overestimate flow rates, therefore; the calculated flow rates should be considered maximum possible flow rates. Actual flow rates are expected to be less. The regolith and fractured bedrock common in this terrain are characteristically heterogeneous. Site boring logs record that regolith sampled at the site commonly exhibits relict foliation. These structures can result in locally anisotropic groundwater flow. Although the regolith and bedrock are hydraulically connected, the effective porosity generally decreases with depth into the underlying fractured bedrock. 5.0 DATA ANALYSIS AND STATISTICAL RESULTS Final results from the April 2013 sampling event were received May 3, 2013 from Pace Analytical Services, Inc. All analytical results can be found in Appendix 2. First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 6 Statistical comparisons of baseline monitoring data to compliance groundwater data are part of the required compliance demonstration (Rule .1632(g), (h), and (i)) for the Woodruff Landfill. Background data and statistical methods were not used to evaluate the data from the Woodruff Landfill during this monitoring event because all results were below applicable standards. 5.1 Analytical Results and Comparisons to Standards 5.1.1 Groundwater As presented in Table 3, four NC Appendix I inorganic constituents were detected in samples from one or more downgradient compliance monitoring wells at quantified concentrations above their respective Solid Waste Section Reporting Limits (SWSLs). There were no detections of NC Appendix I organic constituents above their SWSLs.  Beryllium: MW-1, MW-3, MW-8, MW-9D, MW-10, and MW-12D  Cobalt: MW-2, MW-8, and MW-12S  Thallium: MW-2  Zinc: MW-5 and MW-9D ASDs for beryllium, cobalt, thallium and zinc have all been approved and are on file for the Woodruff Landfill. The inorganic and organic groundwater analytical results from the April 2013 sampling event are generally consistent with historical data at the Woodruff Landfill. The analytical results are summarized in Table 3 and field parameters are summarized in Table 4. The results, as reported by the laboratory, the laboratory quality assurance/quality control information, and the chain of custody records are included in Appendix 1. 5.1.2 Surface Waters Zinc in SMP-1 was detected above the SWSL; however, it was below its NC 2B standard. There were no other constituents detected at quantified concentrations or above the NC 2B standards in surface waters during the April 2013 sampling event. The inorganic and organic surface water analytical results from the April 2013 sampling event at the Woodruff Landfill are summarized in Table 5 and field parameters are summarized in Table 6. The results, as reported by the laboratory, the laboratory quality assurance/quality control information, and the chain-of-custody records are included in Appendix 1. 5.1.3 Leachate First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 7 The following constituents were detected at quantified concentrations in leachate during the April 2013 sampling event. All concentrations are reported in micrograms per liter (µg/L). Constituent LMP-3 Blanks Barium 380 ND Chromium 23.6 ND Cobalt 14.1 ND Zinc 107 ND 1,4-Dichlorobenzene 1.4 ND Biochemical Oxygen Demand (BOD) 318000 ND Chemical Oxygen Demand (COD) 281000 ND Phosphate (Total Phosphorus) 205 ND ND = Not detected above laboratory reporting limits. The analytical results from the April 2013 leachate sampling event at the Woodruff Landfill are summarized in Table 7 and field parameters are summarized in Table 8. The results, as reported by the laboratory, the laboratory quality assurance/quality control information, and the chain of custody records, are included in the Appendix 1. 5.2 Statistical Methods No Appendix I constituents were detected above their respective GWPS or NC 2L standards during the April 2013 sampling event. As a result, statistical calculations were not required for the April 2013 sampling event. 6.0 CONCLUSION Based on the analytical results from the April 2013 sampling and verification events, the Transylvania County Woodruff Landfill shall remain in the Detection Monitoring Program as outlined in Title 15A NCAC 13B .1633. The next semiannual monitoring event is tentatively scheduled for October 2013. 7.0 REFERENCES Bouwer, H. and Rice, R.C., June 1976, A slug test for determining hydraulic conductivity of unconfined aquifers with completely or partially penetrating wells; Water Resources Research, American Geophysical Union, pp. 423-428. Bouwer, H., 1989, The Bouwer and Rice slug test-an update; Ground Water, vol. 27, No. 3, May-June, pp. 304 - 309. Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. First Semiannual Water Quality Monitoring Report of 2013 Joyce Engineering Transylvania County Woodruff Landfill, Permit No. 88-07 May 2013 8 GAI Consultants, Inc., Design Hydrogeologic Study Phase 3 Transylvania County Lined Landfill Rosman, North Carolina, for Municipal Engineering Services Company, PA Garner, North Carolina, March 1995. Harned, D.A., and Daniel, Charles C., III, 1989, The Transition Zone Between Bedrock and Regolith: Conduit For Contamination?, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 336-348. Heath, R.C., 1989, The Piedmont ground-water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Horton, J. W., Jr., 1982, Geologic map and mineral resources summary of the Rosman quadrangle, North Carolina: Raleigh, North Carolina, Department of the Natural Resources and Community Development Division of Land Resources, Geologic Survey Section, GM 185-NE, scale 1:24,000. Horton, J. W., Jr., and McConnell, K. I., 1991, The Western Piedmont, in Horton, J. W., Jr., and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press, p. 36-58. North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. North Carolina Department of Environment and Natural Resources, 1990-2011, Solid Waste Management Regulations. RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. USEPA, 1986, RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). USEPA, 1992, “Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance”, Chapter 2, July. United States Geological Survey. Eastatoe Gap, S.C. – N.C. and Rosman, N.C. 7.5 minute Quadrangles. Tables Table 1 Summary of Historical Groundwater Elevations Table 2 Groundwater Gradient and Flow Rate Calculations Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Groundwater Field Parameters Table 5 Summary of Historical Surface Water Constituents Table 6 Summary of Historical Surface Water Field Parameters Table 7 Summary of Historical Leachate Constituents Table 8 Summary of Historical Leachate Field Parameters TABLE 1 SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 TOC Elevation 2754.44 2771.01 2705.74 2676.85 2701.43 2644.23 2665.26 2666.89 2674.19 2673.70 2674.40 2672.83 2679.95 2676.95 2677.04 2694.48 Well Depth 42.55 40.50 32.66 25.42 26.13 35.02 24.00 24.77 34.56 45.00 40.00 86.50 26.50 33.50 52.50 48.41 May-97 2729.67 NI 2689.53 2660.32 2692.29 2634.78 2648.83 2657.25 2644.98 NI NI NI NI NI NI NI Oct-97 2722.90 NI 2686.06 2659.86 2691.70 2634.15 2647.73 2657.18 2644.30 NI NI NI NI NI NI NI Apr-98 2729.37 NI 2689.20 2660.25 2693.23 2634.75 2647.30 2657.31 2644.91 NI NI NI NI NI NI NI Oct-98 2721.48 NI 2685.24 2659.34 2691.02 2633.55 2647.64 2657.00 2644.19 NI NI NI NI NI NI NI Apr-99 2728.23 NI 2688.07 2659.04 2692.06 2633.47 2648.11 2656.13 2641.19 NI NI NI NI NI NI NI Oct-99 2722.09 NI 2686.36 2660.18 2693.17 2634.21 2649.09 2657.84 2644.94 NI NI NI NI NI NI NI Apr-00 2728.61 NI 2687.85 2660.17 2693.17 2634.53 2649.04 2657.20 2644.93 NI NI NI NI NI NI NI Oct-00 2721.55 NI 2685.61 2660.00 2691.09 2634.04 2647.91 2657.13 2644.66 NI NI NI NI NI NI NI Apr-01 2727.01 NI 2688.39 2660.33 2693.46 2634.61 2649.24 2657.33 2645.14 2645.48 NI 2644.41 NI NI NI NI Oct-01 2722.36 NI 2685.79 2659.69 2692.35 2634.13 2648.92 2658.92 2644.75 2645.22 NI 2643.99 NI NI NI NI Apr-02 2727.82 NI 2688.50 2660.03 2693.40 2634.50 2648.95 2657.14 2644.89 2645.42 NI 2644.46 NI NI NI NI Oct-02 2722.40 NI 2686.02 2660.19 AB 2634.28 2648.23 AB 2646.07 2646.19 NI 2643.53 NI NI NI NI Apr-03 2712.59 NI 2682.66 2660.55 AB 2634.09 2652.73 AB 2647.21 2648.26 NI 2593.88 NI NI NI NI Oct-03 2726.51 NI 2686.11 2660.25 AB 2634.23 2648.86 AB 2646.41 2647.57 NI 2645.73 NI NI NI NI Apr-04 2726.61 NI 2686.05 2659.88 AB 2634.22 2648.34 AB 2646.09 2650.14 NI 2645.22 NI NI NI NI Oct-04 2729.57 NI 2686.55 2659.85 AB 2634.28 2647.93 AB 2647.41 2648.58 NI 2646.36 NI NI NI NI Apr-05 2728.98 NI 2687.42 2660.71 AB 2634.80 2649.36 AB 2647.35 2649.61 NI 2647.26 NI NI NI NI Oct-05 2725.61 NI 2685.88 2660.58 AB 2634.16 2648.01 AB 2646.30 2647.70 NI 2646.14 NI NI NI NI 19-Apr-06 2725.76 NI 2685.56 2660.70 AB 2633.78 2647.73 AB 2645.49 2646.20 NI 2644.81 NI NI NI NI 19-Oct-06 2721.68 NI 2685.64 2661.27 AB 2634.48 2651.76 AB 2646.05 2647.54 NI 2646.28 NI NI NI NI 25-Apr-07 2727.21 2741.78 2686.52 2661.01 AB 2634.10 2648.45 AB 2646.65 2648.56 NI 2647.08 2661.01 2653.49 2650.49 2650.69 09-Jul-07 NS 2739.15 NS NS AB NS NS AB NS NS NI NS 2658.56 2652.08 2646.79 2651.70 16-Oct-07 2718.92 NS 2683.96 2660.33 AB 2633.23 2645.03 AB 2644.31 2644.82 NI 2643.25 NS NS NS NS 11-Mar-08 2728.27 2741.86 2687.56 2661.34 AB 2635.30 2650.33 AB 2645.60 2646.44 NI 2644.86 2661.67 2649.39 2646.86 2654.74 23-Apr-08 2728.90 2741.81 2686.82 2661.05 AB 2634.80 2645.36 AB 2645.61 2645.97 NI 2644.43 2658.28 2648.58 2646.07 2653.14 22-Oct-08 2720.82 2738.26 2684.18 2660.32 AB 2634.04 2646.00 AB 2643.99 2644.51 NI NS 2654.33 2646.05 2643.53 2649.82 17-Apr-09 2729.94 2741.89 2688.16 2661.30 AB 2635.58 2650.90 AB 2645.55 2646.90 NI 2645.24 2661.90 2650.23 2648.12 2655.80 14-Oct-09 2724.48 2741.81 2687.07 2661.51 AB 2635.59 2653.06 AB 2645.20 2646.64 NI 2644.85 2661.84 2649.44 2647.69 2655.43 22-Apr-10 2728.70 2741.80 2689.40 2661.15 AB 2634.65 2648.21 AB 2645.49 2646.55 NI 2644.40 2657.90 2648.62 2646.50 2653.56 27-Oct-10 2723.08 2739.75 2687.25 2661.44 AB 2635.44 2657.15 AB 2644.58 2645.30 NI 2643.33 2665.36 2646.04 2644.57 2651.51 19-Apr-11 2731.47 2741.94 2690.47 2661.75 AB 2635.22 2650.94 AB 2645.70 2646.86 NI 2644.85 2661.56 2650.11 2647.60 2655.56 04-Oct-11 2722.57 2738.96 2685.89 2661.35 AB 2634.68 2648.42 AB 2644.97 AB 2645.79 2643.54 2656.23 2647.10 2645.18 2652.36 03-Apr-12 2727.92 2741.78 2688.43 2661.31 AB 2635.08 2649.97 AB 2645.93 AB 2646.92 2644.13 2659.71 2648.30 2646.19 2653.72 02-Oct-12 2725.64 2741.83 2688.05 2662.05 AB 2635.91 2656.60 AB 2647.11 AB 2648.88 2644.48 2664.03 2648.74 2646.51 2655.56 23-Apr-13 2729.39 2739.60 2688.29 2661.64 AB 2634.59 2651.31 AB 2646.14 AB 2648.19 2644.72 2661.53 2650.08 2647.23 2655.51 Notes: 1. All elevations are referenced as feet above mean sea level. 2. All depths measured in feet (ft). 3. NS = Not sampled. 4. NI = Monitoring well not installed. 5. AB = Monitoring well abandoned. BackgroundLocation Downgradient Transylvania County Woodruff Landfill Permit No. 88-07 Joyce Engineering TABLE 2 GROUNDWATER GRADIENT AND FLOW RATE CALCULATIONS HORIZONTAL HYDRAULIC EFFECTIVE LINEAR GRADIENT CONDUCTIVITY POROSITY VELOCITY i K n V (ft/ft)(ft/day)(ft/day) 2740 2640 2720 2640 2720 2660 Average 0.0704 Average 0.060 Notes: Segment i1 is calculated from Phase 5 hydrogeological report and segments i2 and i3 are calculated from the Phase 4 hydrogeological report. 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer and an effective porosity (n) of 0.20 for Phase 1-4 and 0.05 for Phase 5. 0.20 i 2 i 3 1033 GRADIENT CALCULATION SEGMENT April 2013 0.20i1 0.029 FLOW DIRECTION 0.0862 2.92E-01 8.79E-02 0.20 1. The geometric mean of K calculated from individual well slug tests was used to calculate the hydraulic conductivity. 1193 NW 0.0671 8.79E-02 0.0581 FLOW LINE LENGTH (feet) GROUNDWATER ELEVATION (feet) 0.026 0.126 SW 1160 SW Transylvania County Woodruff Landfill Permit No. 88-07 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Antimony Feb-94 NR 4 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 4 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 4 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 3 10 NI 11 17 7.0 6.0 112 11 8.0 NI NI NI NI NI NI NI ND Feb-96 NR 3 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND May-97 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 5 ND NI ND 2.3 J ND 1.8 J 2.9 J 1.9 J 3.3 J NI NI NI NI NI NI NI ND Apr-98 NR 5 ND NI ND ND ND ND ND ND 1.8 J NI NI NI NI NI NI NI ND Oct-98 NR 30 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 30 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 30 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 30 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 30 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 30 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 30 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 30 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.58 6 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.58 6 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 3.0 5.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND GWPS = 1.4 µg/L (10/23/07)12-Mar-08 2.6 6.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 2.6 6.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 2.6 6.0 ND ND ND ND AB ND ND AB ND ND NI NS 2.8 J ND ND ND ND Dilution Factor = 5x 17-Apr-09 13.0 30.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 2.6 6.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 2.6 6.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 13.0 30.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 2.6 6.0 ND ND NR ND AB ND 2.7 J AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 23-Apr-10 13.0 30.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND GWPS = 1 µg/L (10/01/10)28-Oct-10 2.6 6.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 28-Oct-10 13.0 30.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 2.6 6.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 5.0 6.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.0 6.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 6.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 6.0 ND ND ND ND ND ND ND AB ND AB NS ND ND ND ND ND ND Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Transylvania County Woodruff Landfill Permit No. 88-07 1 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Arsenic Feb-94 NR 1 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 5 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Feb-96 NR 3 ND NI ND 5.0 ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 5 ND NI ND ND ND ND ND ND 2.0 B NI NI NI NI NI NI NI 2.2 J May-97 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 5 ND NI ND 1.9 J ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-98 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 2.5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND 12 ND ND 10 ND ND NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 10 NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB 13.9 ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND 3.6 B 6.0 B 2.3 B AB 2.2 B ND AB 5.0 B 2.3 B NI 2.0 B 4.6 B 2.8 B ND 3.2 B 2.1 J 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 3.0 10.0 ND NS ND ND AB ND Dry AB ND 3.1 J NI 6.2 J NS NS NS NS ND NC 2L = 50 µg/L (10/23/07)12-Mar-08 2.7 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 2.7 10.0 ND ND 4.8 J ND AB ND ND AB ND 4.6 J NI ND ND ND ND ND ND 23-Oct-08 2.7 10.0 ND ND 10.4 B ND AB ND ND AB ND ND NI NS ND 8.3 B ND ND 4.4 J Dilution Factor = 5x 17-Apr-09 13.5 50.0 NR NR 22.7 J NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 2.7 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 2.7 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 13.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 100 µg/L (1/01/10)23-Apr-10 2.7 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND 6.0 J ND ND ND Dilution Factor = 5x 23-Apr-10 13.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 2.7 10.0 ND ND NR ND AB ND ND AB 4.8 J ND NI ND ND 3.8 J ND ND ND Dilution Factor = 5x 28-Oct-10 13.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 2.7 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND 3.0 J ND ND ND 04-Oct-11 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND 105 AB ND AB ND ND ND ND ND ND ND Resample 25-Oct-12 5.0 10.0 NS NS NS NS AB NS ND AB NS AB NS NS NS NS NS NS ND 24-Apr-13 5.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 2 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Barium Feb-94 NR 100 ND NI ND 190 ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 100 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 5 15 NI 42 77 9.0 ND 162 16 31 NI NI NI NI NI NI NI ND Feb-96 NR 5 ND NI 8.0 ND ND ND 67 9.0 24 NI NI NI NI NI NI NI ND Oct-96 NR 10 2.4 J NI 8.6 J 15 5.2 J 1.1 J 33 12 29 NI NI NI NI NI NI NI ND May-97 NR 10 ND NI 4.1 B 11 3.3 B ND 15 6.7 J 20 NI NI NI NI NI NI NI 1.3 J Oct-97 NR 10 2.0 J NI 5.7 J 15 5.8 J 2.0 J 23 8.6 J 28 NI NI NI NI NI NI NI ND Apr-98 NR 10 ND NI 7.2 J ND 5.5 J ND 13 6.1 J 25 NI NI NI NI NI NI NI ND Oct-98 NR 20 17 J NI 17 J 22 B 22 B ND 34 B 13 J 39 B NI NI NI NI NI NI NI 109 Apr-99 NR 10 ND NI 32 101 18 ND 20 ND 34 NI NI NI NI NI NI NI ND Oct-99 NR 500 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 500 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 500 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 500 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 500 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 500 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 500 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 500 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.20 100 0.70 B 13.6 J 33.9 J 18.4 J AB 0.60 B 13.5 J AB 18.1 J 9.70 J NI 0.20 B 5.80 J 41.5 J 11.0 J 15.5 J 0.50 J 10-Jul-07 0.20 10.0 NS 9.70 J NS NS AB NS NS AB NS NS NI NS 3.40 B 40.5 J 15.6 J 9.40 J 0.80 J 17-Oct-07 2.0 10.0 ND NS 65.3 22.5 AB ND Dry AB 19.9 8.6 J NI 2.3 J NS NS NS NS ND NC 2L = 2,000 µg/L (10/23/07) Resample 28-Nov-07 0.20 5.0 NS NS 54.4 20.5 AB NS NS AB 19.8 NS NI NS NS NS NS NS ND 12-Mar-08 0.20 100 NS 3.0 J NS NS AB NS NS AB NS NS NI NS 16.9 J 19.9 J 10.3 J 14.5 J ND 23-Apr-08 0.20 100 0.85 B 7.4 J 61.7 J 26.9 J AB 0.28 B 17.2 J AB 29.1 J 12.0 B NI 3.5 B 9.7 J 73.0 J 12.1 J 10.9 J 0.28 J 23-Oct-08 0.20 100 0.64 B 10.8 B 71.1 J 31.2 B AB 0.59 B 23.4 B AB 26.7 B 53.6 J NI NS 11.2 B 259 11.4 B 48.9 J 8.9 J Resample 14-Jan-09 0.20 100 NS NS NS NS AB NS NS AB NS NS NI NS NS 92.9 J NS NS ND Dilution Factor = 5x 17-Apr-09 1.0 500 NR NR 93.5 J NR AB NR NR AB NR NR NI NR NR NR NR NR 13.5 J 17-Apr-09 0.20 100 0.77 B 4.9 B NR 19.5 B AB ND 21.3 B AB 23.3 B 8.5 J NI 1.7 B 21.1 B 14.8 B 14.1 B 19.3 B 13.5 J 15-Oct-09 0.20 100 ND 8.1 B NR 24.0 B AB ND 22.6 B AB 16.6 B 14.5 B NI ND 13.6 B 14.6 B 10.9 B 19.1 B 19.3 J Dilution Factor = 5x 15-Oct-09 1.00 500 NR NR 77.0 B NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 700 µg/L (1/01/10)23-Apr-10 0.20 100 0.99 B 6.5 B NR 28.9 B AB 0.31 B 15.1 B AB 17.2 B 14.2 B NI 0.47 B 9.7 B 121 B 18.6 B 12.8 B 27.0 J Dilution Factor = 5x 23-Apr-10 1.00 500 NR NR 72.0 B NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 0.20 100 ND 9.3 J NR 27.6 J AB 0.60 J 29.0 J AB 18.1 J 18.7 J NI 0.64 J 13.2 J 56.7 J 18.0 J 12.0 J ND Dilution Factor = 5x 28-Oct-10 1.00 500 NR NR 39.4 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.20 100 4.8 B 3.4 B 34.2 B 30.0 B AB 0.42 B 18.0 B AB 21.2 B 17.6 B NI 0.98 B 20.1 B 16.1 B 13.2 B 19.1 B 14.5 J 04-Oct-11 5.0 100 ND 8.9 J 67.8 J 35.6 J AB ND 30.2 J AB 25.9 J AB 20.9 J ND 14.8 J 21.5 J 11.7 J 9.3 J ND 03-Apr-12 5.0 100 1.7 J 7.7 J 39.8 J 29.3 J AB ND 20.0 J AB 20.1 J AB 42.9 J ND 17.0 J 32.3 J 9.9 J 7.9 J ND 03-Oct-12 5.0 100 ND 6.5 J 45.2 J 28.7 J AB ND 20.9 J AB 21.5 J AB 64.7 J ND 24.2 J 32.6 J 11.6 J 31.9 J ND 24-Apr-13 5.0 100 ND 12.5 J 21.6 J 26.7 J AB ND 15.7 J AB 21.8 J AB NS 7.0 J 21.2 J 15.6 J 10.3 J 18.5 J ND Transylvania County Woodruff Landfill Permit No. 88-07 3 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Beryllium Feb-94 NR 2 3.0 NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 2 5.0 NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 2 7.0 NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 1 3.0 NI 2.0 4.0 ND ND 7.0 3.0 2.0 NI NI NI NI NI NI NI ND Feb-96 NR 1 1.0 NI ND ND ND ND 2.0 ND ND NI NI NI NI NI NI NI ND Oct-96 NR 2 1.4 B NI 1.0 B 1.0 B 0.9 B 0.7 B 1.1 B 2.4 2.1 NI NI NI NI NI NI NI 0.4 J May-97 NR 2 0.3 J NI ND 0.4 J 0.2 J ND 0.5 J 0.5 J 0.8 J NI NI NI NI NI NI NI ND Oct-97 NR 2 0.6 J NI 0.6 J 0.7 J 0.5 J 0.4 J 1.0 J 1.4 J 1.5 J NI NI NI NI NI NI NI ND Apr-98 NR 2 0.9 J NI 0.8 J ND 1.0 J 0.5 J 1.1 J 1.3 J 1.3 J NI NI NI NI NI NI NI ND Oct-98 NR 2 2.5 NI 0.3 J 0.8 J 1.5 J 0.4 J 1.2 J 1.8 J 0.6 J NI NI NI NI NI NI NI ND Apr-99 NR 4 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 2 2.0 NI ND ND ND ND 2.0 ND ND NI NI NI NI NI NI NI ND Apr-00 NR 2 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 2 4.0 NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 2 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 2 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 2 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 2 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 2 2.1 NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 2 5.3 NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 2 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 30 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.70 1.0 1.20 1.30 2.10 ND AB ND ND AB 1.30 ND NI ND ND ND ND ND ND 10-Jul-07 0.70 1.00 NS 0.80 J NS NS AB NS NS AB NS NS NI NS ND ND 0.80 J ND ND 17-Oct-07 0.1 0.3 0.9 NS 0.7 0.8 AB 1.4 Dry AB 2.0 0.3 J1 NI 0.7 NS NS NS NS ND GWPS = 4 µg/L (10/23/07)12-Mar-08 0.10 1.0 NS 0.29 J NS NS AB NS NS AB NS NS NI NS 0.37 J 0.13 J 0.24 J 0.17 J ND 23-Apr-08 0.10 1.0 0.99 J 1.0 2.6 0.84 J AB 0.50 J 0.86 J AB 1.8 0.95 J NI 0.76 J 0.30 J 0.48 J 0.18 J 0.16 J ND 23-Oct-08 0.10 1.0 0.55 J 0.78 J 1.1 0.82 J AB 0.30 J 1.2 AB 1.6 1.4 NI NS 0.20 J 3.7 ND 0.54 J ND Dilution Factor = 5x 17-Apr-09 0.50 5.0 NR NR 5.2 NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 0.10 1.0 0.75 J 0.62 J NR 0.84 J AB 0.35 J 1.0 AB 1.2 0.24 J NI 0.65 J 0.45 J ND 0.20 J 0.26 J ND Resample 28-May-09 0.10 1.0 NS NS 1.6 NS AB NS NS AB NS NS NI NS NS NS NS NS ND 15-Oct-09 0.10 1.0 0.83 J 0.76 J NR 0.81 J AB 0.41 J 0.64 J AB 1.1 0.35 J NI 0.70 J 0.38 J ND 0.34 J 0.30 J ND Dilution Factor = 5x 15-Oct-09 0.50 5.0 NR NR 4.2 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 0.10 1.0 1.2 0.84 B NR 1.2 AB 0.46 B 0.88 J AB 1.2 0.71 B NI 0.76 B 0.49 B 2.2 0.27 J 0.39 J 0.17 J Dilution Factor = 5x 23-Apr-10 0.50 5.0 NR NR 5.8 NR AB NR NR AB NR NR NI NR NR NR NR NR NR Dilution Factor = 2x, Resample 11-Jun-10 0.20 2.0 NS NS 4.2 NS AB NS NS AB NS NS NI NS NS NS NS NS ND 28-Oct-10 0.10 1.0 0.81 J 0.88 J NR 0.64 J AB 0.73 J 0.28 J AB 0.89 J 0.27 J NI 0.62 J 0.26 J 0.80 J 0.21 J 0.22 J ND Dilution Factor = 5x 28-Oct-10 0.50 5.0 NR NR 3.2 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.10 1.0 1.5 0.25 J 2.8 0.61 J AB 0.32 J 0.20 J AB 0.85 J 0.11 J NI 0.48 J 0.40 J 0.11 J 0.35 J 0.20 J ND 04-Oct-11 1.0 1.0 1.0 ND 3.2 ND AB ND ND AB 1.3 AB ND ND ND ND ND ND ND 03-Apr-12 1.0 1.0 1.7 ND 3.7 ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 1.0 1.0 1.3 ND 2.4 ND AB ND ND AB 1.1 AB ND ND ND ND ND ND ND 24-Apr-13 1.0 1.0 2.1 1.3 2.9 ND AB ND ND AB 1.4 AB NS 1.2 ND ND 1.0 ND ND Transylvania County Woodruff Landfill Permit No. 88-07 4 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Cadmium Feb-94 NR 1.0 ND NI ND ND ND 3.0 NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 1.0 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 1.0 ND NI ND ND ND 4.0 ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 0.1 0.4 NI ND 0.5 0.3 2.9 0.5 0.1 0.8 NI NI NI NI NI NI NI ND Feb-96 NR 1.0 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 0.5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND May-97 NR 0.5 ND NI ND ND ND 0.29 J ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 0.5 0.22 J NI 0.48 J ND 0.2 J 2.2 ND 0.12 J 0.22 J NI NI NI NI NI NI NI ND Apr-98 NR 0.5 ND NI ND 0.9 J ND 0.1 J ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 1.0 0.2 J NI ND 0.2 J 0.2 J 1.2 0.3 J ND 0.7 J NI NI NI NI NI NI NI ND Apr-99 NR 1.0 ND NI ND 7.0 ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 1.0 ND NI ND ND ND ND ND ND 4.0 NI NI NI NI NI NI NI ND Apr-00 NR 1.0 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 1.0 1.0 NI ND ND ND ND ND ND 1.0 NI NI NI NI NI NI NI ND Apr-01 NR 1.0 ND NI ND ND 2.4 ND ND ND ND ND NI ND NI NI NI NI ND Resample Jun-01 NR 1.0 NS NI NS NS 2.0 NS NS NS NS NS NI NS NI NI NI NI ND Oct-01 NR 1.0 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 1.0 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 1.0 NS NI NS NS AB NS NS AB NS ND NI 1.7 B NI NI NI NI 1.4 Oct-02 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 1.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 1 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 1 ND NI ND ND AB 1.1 ND AB ND ND NI ND NI NI NI NI ND 08-Jun-06 NR 1 NS NI NS NS AB 1.6 NS AB NS NS NI NS NI NI NI NI ND 19-Oct-06 NR 1 ND NI ND ND AB 1.40 ND AB ND ND NI ND NI NI NI NI ND 29-Nov-06 NR 1 NS NI NS NS AB 0.70 NS AB NS NS NI NS NI NI NI NI ND 25-Apr-07 0.50 1 ND ND 2.60 ND AB 0.70 J ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.50 1 NS ND ND NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.1 0.3 ND NS 0.7 0.2 J AB 2.7 Dry AB 0.3 ND NI ND NS NS NS NS ND NC 2L = 1.75 µg/L (10/23/07) Resample 28-Nov-07 0.50 1.0 NS NS NS NS AB 2.1 NS AB NS NS NI NS NS NS NS NS ND 12-Mar-08 0.50 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.50 1.0 ND ND 1.6 ND AB 0.85 J ND AB ND ND NI 0.50 J ND ND ND ND ND 23-Oct-08 0.50 1.0 ND ND 1.2 ND AB 0.74 J ND AB ND ND NI NS ND ND ND ND ND Dilution Factor = 5x 17-Apr-09 2.5 5.0 NR NR 2.8 J NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 0.50 1.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.50 1.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 2.5 5.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 2 µg/L (1/01/10)23-Apr-10 0.50 1.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 23-Apr-10 2.5 5.0 NR NR ND NR NR NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 0.50 1.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 28-Oct-10 2.5 5.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.50 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 1.0 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 1.0 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 1.0 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 1.0 1.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 5 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Chromium Feb-94 NR 20 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 5 ND NI ND ND ND 24 NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 0.1 3.0 NI 4.0 4.0 2.0 3.0 10 3.0 0.1 NI NI NI NI NI NI NI ND Feb-96 NR 5.0 ND NI ND 5.0 ND ND 7.0 ND ND NI NI NI NI NI NI NI ND Oct-96 NR 10 2.9 B NI 1.3 B 2.8 B 2.4 B 2.7 B 4.0 B 6.6 B 3.9 B NI NI NI NI NI NI NI 3.4 J May-97 NR 10 ND NI ND 1.1 J ND ND ND ND 1.0 J NI NI NI NI NI NI NI ND Oct-97 NR 10 ND NI ND 1.3 J ND ND ND ND 2.1 J NI NI NI NI NI NI NI 3.5 J Apr-98 NR 10 2.0 J NI 4.4 J ND 3.0 J 1.5 J 2.7 J 3.8 J 5.5 J NI NI NI NI NI NI NI ND Oct-98 NR 10 4.0 J NI 3.0 J 2.0 J 4.0 J 2.0 J 4.0 J 2.0 J 1.0 J NI NI NI NI NI NI NI 2.0 J Apr-99 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND 15 NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND ND ND ND ND ND 18 NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 1.0 10.0 ND NS 36.8 2.7 J AB ND Dry AB 3.4 J ND NI ND NS NS NS NS ND NC 2L = 50 µg/L (10/23/07) Resample 28-Nov-07 0.40 5.0 NS NS 2.4 B NS AB NS NS AB NS NS NI NS NS NS NS NS 0.54 J 12-Mar-08 0.40 10.0 NS 0.41 J NS NS AB NS NS AB NS NS NI NS ND 0.68 J 0.66 J ND ND 23-Apr-08 0.40 10.0 ND 0.98 B 1.1 B ND AB ND ND AB 0.73 B 1.9 B NI 1.9 B 0.43 B 4.8 J ND ND 1.0 J 23-Oct-08 0.40 10.0 ND 1.2 J 1.7 J ND AB ND 0.47 J AB ND 1.4 J NI NS 7.1 J 17.2 ND 1.1 J ND 14-Jan-09 0.40 10.0 NS NS NS NS AB NS NS AB NS NS NI NS NS 3.4 J NS NS ND Dilution Factor = 5x 17-Apr-09 2.0 50.0 NR NR 2.0 J NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 0.40 10.0 ND 0.45 J NR ND AB ND ND AB ND ND NI ND ND ND ND 0.65 J ND 15-Oct-09 0.40 10.0 ND 0.55 J NR ND AB 0.44 J ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 2.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 10 µg/L (1/01/10)23-Apr-10 0.40 10.0 0.70 B 1.1 B NR 0.40 B AB ND 0.86 B AB ND ND NI 0.45 B 1.4 B 6.6 J ND 1.1 B 0.41 J Dilution Factor = 5x 23-Apr-10 2.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 0.40 10.0 ND ND NR ND AB ND ND AB ND ND NI ND 0.56 J 1.1 J ND ND ND Dilution Factor = 5x 28-Oct-10 2.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.40 10.0 0.82 J 0.61 J 0.63 J 0.53 J AB ND 1.5 J AB 1.2 J 0.74 J NI ND 0.78 J 1.2 J ND ND ND 04-Oct-11 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND 5.9 J ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 6 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Cobalt Feb-94 NR 20 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 10 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 10 ND NI ND ND ND ND ND ND 30 NI NI NI NI NI NI NI NA Sep-95 NR 5.0 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Feb-96 NR 5.0 ND NI ND ND ND ND 11 ND 17 NI NI NI NI NI NI NI ND Oct-96 NR 10 11 B NI 5.3 B 12 B 11 B 9.0 B 17 B 23 B 28 NI NI NI NI NI NI NI 5.5 J May-97 NR 10 ND NI ND ND ND ND ND ND 7.3 J NI NI NI NI NI NI NI ND Oct-97 NR 10 ND NI ND ND ND ND ND ND 17 NI NI NI NI NI NI NI ND Apr-98 NR 10 ND NI ND 2.0 J ND ND ND ND 15 NI NI NI NI NI NI NI ND Oct-98 NR 10 1.0 J NI ND 2.0 J 8.0 J ND 6.0 J 3.0 J 22 NI NI NI NI NI NI NI ND Apr-99 NR 20 ND NI ND ND ND ND ND ND 21 NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND 14 NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND 21 NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND ND ND ND ND ND 16 NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND 11 ND ND ND 15 ND NI ND NI NI NI NI ND Resample Jun-01 NR 10 NS NI NS NS ND NS NS NS NS NS NI NS NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND 10 J ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND 10 ND ND ND 14 ND NI ND NI NI NI NI ND Resample May-02 NR 10 NS NI NS NS ND NS NS AB NS NS NI NS NI NI NI NI NA Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB 12 ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB 11 ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND ND ND ND AB ND ND AB 3.8 J ND NI ND 7.6 J 4.6 J 2.7 J ND ND 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS 3.5 J 10.0 ND ND ND 17-Oct-07 2.0 10.0 ND NS 2.9 J 2.1 J AB ND Dry AB 4.4 J ND NI ND NS NS NS NS ND GWPS = 70 µg/L (10/23/07)12-Mar-08 0.60 10.0 NS ND NS AB NS NS AB NS NS NI NS 8.4 B ND ND ND 2.7 J 23-Apr-08 0.60 10.0 ND 0.90 J ND ND AB 1.2 B ND AB ND ND NI ND 13.6 17.2 ND 1.9 J ND 23-Oct-08 0.60 10.0 1.5 B 2.4 B ND 1.8 B AB 1.6 B ND AB 6.5 B 6.3 B NI NS 36.8 55.2 0.94 B 5.8 B 1.6 J Resample 14-Jan-09 0.60 10.0 NS NS NS NS AB NS NS AB NS NS NI NS 3.8 J 14.9 NS NS ND Dilution Factor = 5x 17-Apr-09 3.0 50.0 NR NR 38.6 J NR AB NR NR AB NR NR NI NR NR NR NR NR 4.9 J 17-Apr-09 0.60 10.0 4.0 B 3.6 B NR 8.2 B AB ND 6.3 B AB 12.8 B 7.9 B NI 2.8 B 4.4 B 22.2 B 21.6 B 5.0 B 4.9 J 15-Oct-09 0.60 10.0 ND ND NR 1.8 J AB ND ND AB 4.7 J ND NI ND ND 9.6 J 2.2 J ND ND Dilution Factor = 5x 15-Oct-09 3.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 0.60 10.0 ND ND NR 4.4 J AB ND 0.94 J AB 7.7 J 3.5 J NI ND 3.5 J 4.3 J 10.6 ND ND Dilution Factor = 5x 23-Apr-10 3.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR GWPS = 1 µg/L (10/01/10)28-Oct-10 0.60 10.0 1.0 B 2.1 B NR 3.7 B AB ND 1.0 B AB 9.9 B 6.9 B NI 2.7 B 6.0 B 29.1 11.2 B 2.1 B 2.4 J Dilution Factor = 5x 28-Oct-10 3.0 50.0 NR NR 11.2 B NR AB NR NR AB NR NR NI NR NR NR NR NR NR Resample 21-Dec-10 0.6 10.0 NS NS NS NS AB NS NS AB NS NS NI NS NS 13.4 NS NS 2.1 J 20-Apr-11 0.60 10.0 0.99 J 3.0 J ND 5.4 J AB 5.1 J 4.3 J AB 7.6 J 4.5 J NI 3.1 J 1.3 J 15.3 6.6 J 4.4 J ND 04-Oct-11 5.0 10.0 ND ND ND 5.4 J AB ND ND AB 8.8 J AB 7.6 J ND ND 24.4 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB 5.7 J AB ND ND ND 8.4 J ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND 9.2 J ND ND ND 24-Apr-13 5.0 10.0 ND ND ND 17.1 AB ND 8.6 J AB 13.7 AB NS ND ND 25.8 9.2 J ND ND Transylvania County Woodruff Landfill Permit No. 88-07 7 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Copper Feb-94 NR 10 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 10 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 10 ND NI ND ND ND ND ND ND 26 NI NI NI NI NI NI NI NA Sep-95 NR 5 ND NI ND 5.0 ND ND 12 ND ND NI NI NI NI NI NI NI ND Feb-96 NR 5 ND NI ND ND ND ND 9.0 ND 6.0 NI NI NI NI NI NI NI ND Oct-96 NR 10 3.4 B NI ND ND 4.0 B ND 4.0 B 9.4 B 8.1 B NI NI NI NI NI NI NI 2.9 J May-97 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 10 3.9 J NI ND ND ND 3.1 J ND ND 5.7 J NI NI NI NI NI NI NI 3.9 J Apr-98 NR 10 ND NI 5.8 J ND ND 2.8 J 2.9 J 3.1 J 8.1 J NI NI NI NI NI NI NI ND Oct-98 NR 10 12 NI 7.0 J 23 9.0 J 7.0 J 11 4.0 J 6.0 J NI NI NI NI NI NI NI 79 Apr-99 NR 10 ND NI ND 11 ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 200 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 200 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 200 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 200 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 200 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 200 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 200 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 200 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.60 10 ND ND ND ND AB ND ND AB ND ND NI ND 3.60 J ND ND ND ND 10-Jul-07 0.60 10.0 NS 1.40 B NS NS AB NS NS AB NS NS NI NS 1.70 B 2.00 B ND ND 0.90 J 17-Oct-07 3.0 10.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 1,000 µg/L (10/23/07)12-Mar-08 0.30 10.0 NS ND NS NS AB NS NS AB NS NS NI NS 4.3 B 2.0 B ND ND 2.4 J 23-Apr-08 0.30 10.0 ND 0.39 B 0.96 J ND AB ND 0.99 J AB 6.0 J ND NI ND 12.0 12.3 ND ND 0.61 J 23-Oct-08 0.30 10.0 ND 0.48 J ND ND AB 0.79 J 1.4 J AB 1.8 J 2.3 J NI NS 27.5 51.7 ND 4.5 J ND Dilution Factor = 5x 17-Apr-09 1.5 50.0 NR NR 60.0 NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 0.30 10.0 ND ND NR ND AB ND ND AB 0.89 J ND NI ND 0.65 J ND ND ND ND 15-Oct-09 0.30 10.0 ND 0.45 J NR ND AB ND ND AB 1.1 J ND NI ND 3.3 J ND ND ND ND Dilution Factor = 5x 15-Oct-09 1.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 0.30 10.0 ND ND NR ND AB ND 0.43 J AB 4.2 J ND NI ND 4.6 J 26.1 ND ND ND Dilution Factor = 5x 23-Apr-10 1.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR Resample 11-Jun-10 0.30 10.0 NS NS NS NS AB NS NS AB NS NS NI NS NS 0.34 J NS NS ND 28-Oct-10 0.30 10.0 ND ND NR ND AB ND 0.36 J AB 0.41 J ND NI ND 2.5 J 10.1 ND ND ND Dilution Factor = 5x 28-Oct-10 1.5 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.30 10.0 3.2 J 0.38 B 0.69 B 0.30 B AB 0.47 B 0.91 B AB 2.1 J 0.64 B NI 0.65 B 1.6 B 4.9 J 1.4 B 0.42 B 0.38 J 04-Oct-11 5.0 10.0 ND 6.2 J ND 9.6 J AB ND ND AB ND AB ND ND 7.6 J ND ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 8 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Lead Feb-94 NR 1 8.0 NI 10 5.0 ND 1.0 NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 5 18 NI ND 6.0 ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 5 90 NI 11 14 ND ND 12 ND 6.0 NI NI NI NI NI NI NI NA Sep-95 NR 3 8.0 NI 12 13 ND ND 28 4.0 3.0 NI NI NI NI NI NI NI ND Feb-96 NR 3 ND NI ND 3.0 ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 1 10 NI 7.7 6.1 4.6 5.5 5.2 5.7 6.7 NI NI NI NI NI NI NI 0.3 J May-97 NR 1 3.0 NI 8.7 3.4 0.8 B 1.4 B 0.7 B 0.8 B 2.6 NI NI NI NI NI NI NI 0.4 J Oct-97 NR 1 1.7 NI 1.5 0.7 J 0.8 J 2.2 ND 0.5 J 1.1 NI NI NI NI NI NI NI ND Apr-98 NR 1 2.7 NI 3.4 ND 3.9 1.9 1.4 1.6 8.4 NI NI NI NI NI NI NI ND Oct-98 NR 10 18 4.0 J 4.0 J 9.0 J ND 7.0 J 4.0 J 5.0 J NI NI NI NI NI NI NI 4.0 J Apr-99 NR 3 ND NI 8.0 6.0 ND ND ND ND 9.0 NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND 10 J NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 10 23 NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 10 13.5 NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB 10.1 ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND 3.9 J ND ND AB ND ND AB ND ND NI ND ND 2.5 J ND ND ND 10-Jul-07 2.0 10.0 NS 3.2 J NS NS AB NS NS AB NS NS NI NS ND 9.1 J 2.2 J ND ND 17-Oct-07 6.0 10.0 ND NS 14.5 ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 15 µg/L (10/23/07)12-Mar-08 4.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 4.0 10.0 ND ND ND ND AB ND ND AB 10 4.6 J NI 4.3 J ND 20.8 ND ND ND 23-Oct-08 4.0 10.0 ND ND ND ND AB ND ND AB 4.4 J 20.0 NI NS ND 90.5 ND 7.8 J ND Resample 14-Jan-09 4.0 10.0 NS NS NS NS AB NS NS AB NS ND NI NS NS 22.2 NS NS ND Dilution Factor = 5x 17-Apr-09 20.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 4.0 10.0 ND ND NR ND AB ND ND AB 7.1 J ND NI ND ND ND ND ND ND 15-Oct-09 4.0 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 20.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 4.0 10.0 ND ND NR ND AB ND ND AB 8.9 J ND NI ND ND 42.3 ND ND ND Dilution Factor = 5x 23-Apr-10 20.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 4.0 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND 16.3 ND ND ND Dilution Factor = 5x 28-Oct-10 20.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 4.0 10.0 4.4 J ND 6.8 J ND AB ND ND AB 12.5 ND NI ND ND ND ND ND ND 04-Oct-11 5.0 10.0 ND ND 7.4 J ND AB ND ND AB 10.3 AB ND ND ND ND ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB 12.1 AB ND ND ND 7.1 J ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND ND AB 14.8 AB 7.4 J ND ND 7.0 J ND ND ND 24-Apr-13 5.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 9 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Nickel Feb-94 NR 50 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 50 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 5 ND NI ND ND ND ND 5.0 ND ND NI NI NI NI NI NI NI ND Feb-96 NR 5 ND NI ND ND ND 5.0 8.0 ND ND NI NI NI NI NI NI NI ND Oct-96 NR 20 14 J NI 5.3 J 15 J 9.4 J 11 J 8.6 J 22 20 NI NI NI NI NI NI NI ND May-97 NR 20 ND NI ND ND ND ND ND 4.4 B 3.6 B NI NI NI NI NI NI NI 4.5 J Oct-97 NR 20 7.4 J NI ND ND ND ND 4.6 J ND ND NI NI NI NI NI NI NI 5.5 J Apr-98 NR 20 ND NI ND 2.7 J ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 400 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 50 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 2.0 50 ND ND ND ND AB ND ND AB ND ND NI ND 36.3 J ND ND ND ND 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS 39.6 J ND ND ND ND 17-Oct-07 2.0 10.0 ND NS 10.3 ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 100 µg/L (10/23/07)12-Mar-08 1.7 50.0 NS ND NS NS AB NS NS AB NS NS NI NS 18.1 J ND ND ND ND 23-Apr-08 1.7 50.0 ND ND ND ND AB 8.1 J ND AB ND ND NI ND 63.5 2.5 J ND ND ND 23-Oct-08 1.7 50.0 ND ND ND ND AB ND ND AB ND ND NI ND 133 5.3 J ND ND ND Resample 14-Jan-09 1.7 50.0 NS NS NS NS AB NS NS AB NS NS NI NS 10.2 J NS NS NS ND Dilution Factor = 5x 17-Apr-09 8.5 250 NR NR 55.0 J NR AB NR NR AB NR NR NI NR NR NR NR NR 3.3 J 17-Apr-09 1.7 50.0 ND ND NR ND AB ND ND AB ND ND NI 1.7 B 5.0 B ND ND ND 3.3 J 15-Oct-09 1.7 50.0 ND 5.7 B NR ND AB 7.5 B ND AB ND ND NI ND 4.3 B ND ND ND 2.0 J Dilution Factor = 5x 15-Oct-09 8.5 250 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 1.7 50.0 ND ND NR ND AB ND ND AB ND ND NI ND 20.0 J 8.0 J ND ND ND Dilution Factor = 5x 23-Apr-10 8.5 250 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 1.7 50.0 ND ND NR ND AB ND ND AB ND ND NI ND 4.8 J 3.5 J ND ND ND Dilution Factor = 5x 28-Oct-10 8.5 250 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 1.7 50.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND 5.8 J 04-Oct-11 5.0 50.0 ND ND ND ND AB ND ND AB ND AB ND ND 10.2 J ND ND ND ND 03-Apr-12 5.0 50.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 50.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 50.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 10 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Selenium Feb-94 NR 1 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 5 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Feb-96 NR 3 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 5 ND NI 9.2 ND ND ND ND ND ND NI NI NI NI NI NI NI ND May-97 NR 5 ND NI ND ND ND 2.8 J ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-98 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 5 ND NI ND 6.0 ND ND ND ND 13 NI NI NI NI NI NI NI ND Oct-99 NR 20 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 20 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 20 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 20 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 20 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 20 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 20 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 20 ND NI 37 ND AB ND ND AB ND ND NI ND NI NI NI NI ND Resample 24-Jan-06 NR 20 NS NI ND NS AB NS NS AB NS NS NI NS NI NI NI NI ND 20-Apr-06 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 20 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 2.0 10.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 50 µg/L (10/23/07)12-Mar-08 3.8 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND 10.9 ND ND ND 23-Apr-08 3.8 10.0 ND ND 9.8 J ND AB 7.8 J ND AB 4.1 J ND NI ND ND 10.4 ND ND ND 23-Oct-08 3.8 10.0 ND ND 14.2 ND AB ND 4.0 J AB 3.8 J ND NI NS 4.3 J ND ND ND ND Dilution Factor = 5x 17-Apr-09 19.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 3.8 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 3.8 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 15-Oct-09 19.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 20 µg/L (1/01/10)23-Apr-10 3.8 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND 5.7 J ND ND ND Dilution Factor = 5x 23-Apr-10 19.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 3.8 10.0 ND ND NR ND AB ND 5.2 J AB ND ND NI ND ND 3.8 J ND ND ND Dilution Factor = 5x 28-Oct-10 19.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 3.8 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND 4.6 J ND ND ND 04-Oct-11 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 10.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 11 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Silver Feb-94 NR 10 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 10 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 0.2 ND NI ND ND ND ND 0.4 ND ND NI NI NI NI NI NI NI ND Feb-96 NR 1.0 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 10 4.8 B NI ND ND ND ND ND 8.3 B 6.8 B NI NI NI NI NI NI NI 5.0 J May-97 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-98 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 2 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 5 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 2.0 10 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 2.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 2.0 10.0 ND NS 6.9 J ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 17.5 µg/L (10/23/07)12-Mar-08 0.10 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.10 10.0 ND ND 0.26 B 0.26 B AB 0.13 B ND AB 0.20 B 0.59 J NI 0.15 B ND 0.58 J ND ND 0.11 J 23-Oct-08 0.10 10.0 0.12 B ND 3.5 J 0.48 B AB 0.13 B 0.16 B AB 0.43 B ND NI NS 2.4 J 1.4 J 0.19 B ND 0.19 J Dilution Factor = 5x 17-Apr-09 0.50 50.0 NR NR 2.3 J NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 0.10 10.0 ND ND NR ND AB ND ND AB ND 0.68 J NI ND ND ND ND ND ND 15-Oct-09 0.10 10.0 ND ND NR ND AB ND ND AB 0.26 J ND NI ND ND 0.36 J ND ND ND Dilution Factor = 5x 15-Oct-09 0.50 50.0 NR NR 1.6 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 20 µg/L (1/01/10)23-Apr-10 0.10 10.0 ND ND NR ND AB ND ND AB ND ND NI ND 0.22 B ND ND ND 0.16 J Dilution Factor = 5x 23-Apr-10 0.50 50.0 NR NR 0.88 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 0.10 10.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND ND Dilution Factor = 5x 28-Oct-10 0.50 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.10 10.0 ND 0.23 J ND ND AB ND ND AB ND ND NI 0.20 J ND ND ND ND ND 04-Oct-11 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 10.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 12 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Thallium Feb-94 NR 1 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 2 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 2 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 1 1.0 NI 2.0 2.0 1.0 ND 2.0 ND 2.0 NI NI NI NI NI NI NI ND Feb-96 NR 2 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-96 NR 2 ND NI ND ND ND ND ND ND 3.9 NI NI NI NI NI NI NI ND May-97 NR 2 ND NI ND ND ND ND ND ND 6.2 NI NI NI NI NI NI NI ND Oct-97 NR 2 ND NI ND ND ND ND NN ND 6.3 NI NI NI NI NI NI NI ND Apr-98 NR 2 ND NI ND ND ND ND ND ND 4.2 NI NI NI NI NI NI NI ND Oct-98 NR 1 ND NI ND ND 1.0 ND ND ND 4.0 NI NI NI NI NI NI NI ND Apr-99 NR 2 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND 12 NI 10 NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 11 NI 16 ND AB 13 ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 10 ND NI 11 12 AB ND ND AB 14 ND NI ND NI NI NI NI ND Apr-05 NR 10 ND NI 23.9 16.2 AB ND ND AB 15.1 ND NI ND NI NI NI NI ND Oct-05 NR 10 ND NI 160 (50)14 AB ND ND AB 22 ND NI ND NI NI NI NI ND 20-Apr-06 NR 10 12 NI 79.1 13.4 AB ND ND AB 18.8 ND NI ND NI NI NI NI ND 19-Oct-06 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.044 5.5 0.054 J 0.051 J 4.13 J 0.746 J AB ND 0.220 J AB 1.63 J 0.072 J NI ND ND 0.297 J 0.063 J 0.054 J ND 10-Jul-07 0.036 0.050 NS 0.042 J NS NS AB NS NS AB NS NS NI NS ND 0.343 J 0.190 J 0.045 J ND 17-Oct-07 2.0 2.0 ND NS 6.7 ND AB ND Dry AB 2.4 ND NI ND NS NS NS NS ND GWPS = 0.28 µg/L (10/23/07)12-Mar-08 3.0 5.5 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 3.0 5.5 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 3.0 5.5 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND Dilution Factor = 5x 17-Apr-09 15.0 27.5 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND 17-Apr-09 3.0 5.5 ND ND NR ND AB ND ND AB ND ND NI 3.0 J ND ND ND ND ND 15-Oct-09 3.0 5.5 ND ND NR ND AB ND 4.9 J AB ND ND NI ND ND 3.2 J ND ND ND Dilution Factor = 5x 15-Oct-09 15.0 27.5 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 3.0 5.5 ND ND NR 8.1 AB ND 5.9 AB 8.4 ND NI ND ND 5.6 ND ND ND Dilution Factor = 5x 23-Apr-10 15.0 27.5 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR GWPS = 0.2 µg/L (10/01/10)28-Oct-10 3.0 5.5 ND ND NR ND AB ND ND AB 4.7 J ND NI ND ND 5.4 J ND 3.8 J ND Dilution Factor = 5x 28-Oct-10 15.0 27.5 NR NR 19.1 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 3.0 5.5 ND ND ND 3.3 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 5.4 5.5 ND ND 6.3 ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.4 5.5 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.4 5.5 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.4 5.5 ND ND ND 7.4 AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 13 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Vanadium Feb-94 NR 80 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 40 ND NI ND ND ND ND NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 40 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI NA Sep-95 NR 5 ND NI ND 6.0 ND ND 19 ND ND NI NI NI NI NI NI NI ND Feb-96 NR 5 ND NI ND ND ND ND 13 ND ND NI NI NI NI NI NI NI ND Oct-96 NR 4 ND NI ND 5.7 B ND ND 10 ND 3.8 B NI NI NI NI NI NI NI 1.8 J May-97 NR 4 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-97 NR 4 ND NI ND 2.3 J ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-98 NR 4 ND NI 19 ND 5.5 ND 16 2.1 J 1.5 J NI NI NI NI NI NI NI ND Oct-98 NR 40 9.0 J NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-99 NR 20 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 40 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 40 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 40 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 40 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 40 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 40 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 40 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 40 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 1.0 25 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 1.0 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 2.0 10.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND GWPS = 3.5 µg/L (10/23/07)12-Mar-08 0.20 25.0 NS 0.60 B NS NS AB NS NS AB NS NS NI NS 0.21 B ND 0.24 B 0.74 B 0.32 J 23-Apr-08 0.20 25.0 ND 0.39 J ND ND AB ND ND AB ND 2.4 B NI 1.9 B ND 5.9 J ND 0.48 J 1.1 J 23-Oct-08 0.20 25.0 ND 0.58 J ND ND AB ND ND AB ND 3.0 J NI NS 0.4 B 32.6 ND 3.4 J 0.25 J Resample 14-Jan-09 0.20 25.0 NS NS NS NS AB NS NS AB NS NS NI NS NS 7.1 J NS NS 0.47 J Dilution Factor = 5x 17-Apr-09 1.0 125 NR NR 5.2 J NR AB NR NR AB NR NR NI NR NR NR NR NR 0.22 J 17-Apr-09 0.20 25.0 ND ND NR ND AB ND ND AB ND ND NI ND ND ND ND ND 0.22 J 15-Oct-09 0.20 25.0 ND 0.82 B NR ND AB ND 0.20 B AB 0.82 B 0.40 J NI ND ND 0.34 B ND 0.39 B 0.52 J Dilution Factor = 5x 15-Oct-09 1.0 125 NR NR 3.4 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 23-Apr-10 0.20 25.0 0.53 B 1.0 B NR 1.1 B AB 0.36 B 0.76 B AB 1.8 B 1.2 B NI 0.33 B 0.49 B 17.0 J 0.34 B 1.1 B 0.64 J Dilution Factor = 5x 23-Apr-10 1.0 125 NR NR 4.5 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR GWPS = 0.3 µg/L (10/01/10)28-Oct-10 0.20 25.0 0.22 B 0.73 B NR 0.35 B AB ND 0.84 B AB 1.1 B 0.42 B NI ND 0.23 B 5.4 J 0.25 B ND 0.30 J Dilution Factor = 5x 28-Oct-10 1.0 125 NR NR 2.4 J NR AB NR NR AB NR NR NI NR NR NR NR NR NR 20-Apr-11 0.20 25.0 0.39 J ND ND ND AB ND ND AB ND ND NI ND ND ND ND 0.28 J ND 04-Oct-11 5.0 25.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 5.0 25.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 5.0 25.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 5.0 25.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 14 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Zinc Feb-94 NR 10 ND NI 13 ND ND 52 NI NI NI NI NI NI NI NI NI NI NA Aug-94 NR 10 ND NI 19 ND ND 415 NI NI NI NI NI NI NI NI NI NI NA Feb-95 NR 10 13 NI 43 ND ND 38 10 14 19 NI NI NI NI NI NI NI NA Sep-95 NR 10 42 NI ND 48 ND 27 39 ND ND NI NI NI NI NI NI NI ND Feb-96 NR 10 36 B NI 52 B 113 B 52 B 34 B 23 B 121 B 26 B NI NI NI NI NI NI NI 65 Oct-96 NR 10 60 NI 41 44 34 37 34 49 25 NI NI NI NI NI NI NI ND May-97 NR 10 8.7 J NI 23 9.3 9.5 J 13 9.4 J 10 16 NI NI NI NI NI NI NI 34 Oct-97 NR 10 60 NI 23 50 73 69 30 66 56 NI NI NI NI NI NI NI ND Apr-98 NR 10 10 NI 12 10 11 20 21 11 23 NI NI NI NI NI NI NI ND Oct-98 NR 50 74 NI 34 J 88 56 74 118 71 76 NI NI NI NI NI NI NI ND Apr-99 NR 20 21 NI ND 561 ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 10 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 10 ND NI ND 110 ND ND ND ND ND NI NI NI NI NI NI NI ND Resample Jan-01 NR 10 NS NI NS ND NS NS NS NS NS NI NI NI NI NI NI NI NA Apr-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 10 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 10 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI ND Oct-02 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 10 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 1.0 10 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 1.0 10.0 NS 7.0 B NS NS AB NS NS AB NS NS NI NS 1.9 B 3.4 B 6.2 B 1.1 B 11.9 J 17-Oct-07 10.0 10.0 ND NS ND ND AB 52.8 Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 1,050 µg/L (10/23/07)12-Mar-08 0.40 10.0 NS 7.2 B NS NS AB NS NS AB NS NS NI NS 8.6 B 35.0 J 7.8 B 9.0 B 6.5 J 23-Apr-08 0.40 10.0 5.2 B 8.2 B 22.8 B 11.6 B AB 24.7 B 6.0 B AB 15.1 B 5.7 B NI 5.6 B 18.1 B 30.1 B 6.7 B 3.6 B 8.3 J 23-Oct-08 0.40 10.0 6.3 B 9.1 B ND 0.81 B AB 19.9 2.5 B AB 8.0 B 11.0 B NI NS 27.2 44.1 6.0 B 13.3 B 3.1 J Dilution Factor = 5x 17-Apr-09 2.0 50.0 NR NR 780 NR AB NR NR AB NR NR NI NR NR NR NR NR 7.9 J 17-Apr-09 0.40 10.0 3.2 B 7.5 B NR 0.88 B AB 11.6 B 4.2 B AB 4.0 B 14.5 B NI 8.9 B 5.8 B ND 2.7 B 3.8 B 7.9 J Resample 25-May-09 0.40 10.0 NS NS ND NS AB NS NS AB NS NS NI NS NS NS NS NS 1.0 J 15-Oct-09 0.40 10.0 5.8 B 17.0 B NR 4.5 B AB 19.3 B 8.8 B AB 7.9 B 9.6 B NI 13.0 B 7.4 B 7.2 B 13.4 B 4.2 B 6.1 J Dilution Factor = 5x 15-Oct-09 2.0 50.0 NR NR 7.6 B NR AB NR NR AB NR NR NI NR NR NR NR NR NR NC 2L = 1,000 µg/L (1/01/10)23-Apr-10 0.40 10.0 1.5 B 3.2 B NR ND AB 8.0 B 3.3 B AB ND 2.5 B NI 1.4 B 6.6 B 22.4 B 2.9 B 3.1 B 4.5 J Dilution Factor = 5x 23-Apr-10 2.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR NR 28-Oct-10 0.40 10.0 ND ND NR ND AB 15.0 2.7 J AB 4.7 J 119 NI ND ND 3.4 J ND ND ND Dilution Factor = 5x 28-Oct-10 2.0 50.0 NR NR ND NR AB NR NR AB NR NR NI NR NR NR NR NR ND Resample 21-Dec-10 0.4 10.0 NS NS NS NS NS NS NS NS NS 400 NI NS NS NS NS NS ND 20-Apr-11 0.40 10.0 13.9 B 3.7 B 2.2 B 5.8 B AB 10.2 B 1.7 B AB 7.1 B 2720 NI 6.6 B 4.3 B 16.8 B 9.4 B 3.8 B 36.8 04-Oct-11 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 10.0 10.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND 12.2 24-Apr-13 10.0 10.0 ND ND ND ND AB 10.4 ND AB ND AB NS 24.8 ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 15 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient 1,1-Dichloroethane 25-Apr-07 0.24 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.090 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.2 1.0 ND NS 0.6 J 0.7 J AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 70 µg/L (10/23/07)12-Mar-08 0.32 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.32 5.0 ND ND ND 0.46 J AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.32 5.0 ND ND ND 0.50 J AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.32 5.0 ND ND ND 0.43 J AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.32 5.0 ND ND ND 0.55 J AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 6 µg/L (1/01/10)23-Apr-10 0.32 5.0 ND ND ND 0.94 J AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.32 5.0 ND ND ND 0.39 J AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.32 5.0 ND ND ND 0.91 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.32 5.0 ND ND ND 1.3 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.32 5.0 ND ND ND 0.68 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.32 5.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.32 5.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Acetone Apr-00 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 100 ND NI ND ND 110 L ND ND ND ND ND NI ND NI NI NI NI ND Resample Jun-01 NR 100 NS NI NS NS ND NS NS NS NS NS NI NS NI NI NI NI NA Oct-01 NR 100 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 100 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 100 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI NA Oct-02 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.90 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.90 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 7.0 10.0 ND NS 43.0 ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 700 µg/L (10/23/07) Resample 28-Nov-07 2.2 25.0 NS NS 12.6 J NS AB NS NS AB NS NS NI NS NS NS NS NS ND 12-Mar-08 2.2 100 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 2.2 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 20.0 100 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 20.0 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 2.2 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 6,000 µg/L (1/01/10)23-Apr-10 2.2 100 ND ND 5.1 J 3.4 J AB ND ND AB 4.6 J ND NI ND ND 5.6 J ND ND ND 28-Oct-10 2.2 100 ND ND 2.9 J 2.3 J AB ND ND AB 4.1 J 11.5 J NI ND ND 19.0 J ND ND ND 20-Apr-11 2.2 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 2.2 100 ND ND 5.9 J 4.3 J AB ND ND AB 3.2 J AB 19.8 J ND ND 4.0 J ND ND ND 03-Apr-12 2.2 100 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 10.0 100 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 10.0 100 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND 41.9 J Transylvania County Woodruff Landfill Permit No. 88-07 16 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Benzene 25-Apr-07 0.12 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.12 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.2 1.0 ND NS 0.3 J 0.2 J AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 1 µg/L (10/23/07)12-Mar-08 0.25 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.25 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.25 1.0 ND ND 0.25 J 0.39 J AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.25 1.0 ND ND ND 0.36 J AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.25 1.0 ND ND ND 0.39 J AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Apr-10 0.25 1.0 ND ND ND 0.80 J AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.25 1.0 ND ND ND 0.30 J AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.25 1.0 ND ND ND 0.75 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.25 1.0 ND ND ND 1.1 AB ND ND AB ND AB ND ND ND ND ND ND ND Resample 10-Nov-11 0.25 1.0 NS NS NS 0.76 J AB NS NS AB NS AB NS NS NS NS NS NS ND 03-Apr-12 0.25 1.0 ND ND ND 0.76 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.25 1.0 ND ND ND 0.61 J AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.25 1.0 ND ND ND 0.56 J AB ND ND AB ND AB NS ND ND ND ND ND ND Chlorobenzene 25-Apr-07 0.16 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.16 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.1 1.0 ND NS ND 0.1 J AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 50 µg/L (10/23/07)12-Mar-08 0.23 3.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Apr-10 0.23 3.0 ND ND ND 0.40 J AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.23 3.0 ND ND ND 0.35 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.23 3.0 ND ND ND 0.61 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.23 3.0 ND ND ND 0.41 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.23 3.0 ND ND ND 0.32 J AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.23 3.0 ND ND ND 0.27 J AB ND ND AB ND AB NS ND ND ND ND ND ND Chloroethane 25-Apr-07 0.40 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.40 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.2 1.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 2,800 µg/L (10/23/07)12-Mar-08 0.54 10.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.54 10.0 ND ND ND 0.57 J AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.54 10.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.54 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.54 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 3,000 µg/L (1/01/10)23-Apr-10 0.54 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.54 10.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.54 10.0 ND ND ND 0.82 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.54 10.0 ND ND ND 0.96 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.54 10.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.54 10.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.54 10.0 ND ND ND ND ND ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 17 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Chloromethane 15-Oct-09 0.11 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND 0.25 J NC 2L = 2.6 µg/L (10/23/07)23-Apr-10 0.11 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 3 µg/L (1/01/10)28-Oct-10 0.11 1.0 ND ND ND ND AB ND ND AB ND ND NI ND 0.13 B ND ND ND 0.25 J 20-Apr-11 0.11 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.11 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.11 1.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.11 1.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.11 1.0 ND ND ND ND ND ND ND AB ND AB NS ND ND ND ND ND ND 1,4-Dichlorbenzene 20-Apr-11 0.33 1.0 ND ND ND 0.35 J AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 6 µg/L (1/01/10)04-Oct-11 0.33 1.0 ND ND ND 0.49 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.33 1.0 ND ND ND 0.47 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.33 1.0 ND ND ND 0.38 J AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.33 1.0 ND ND ND 0.35 J AB ND ND AB ND AB NS ND ND ND ND ND ND Cis-1,2-Dichloroethylene 25-Apr-07 0.14 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.14 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.2 1.0 ND NS ND 0.2 J AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 70 µg/L (10/23/07)12-Mar-08 0.19 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.19 5.0 ND ND ND 0.21 B AB ND ND AB ND ND NI ND ND ND ND ND 0.21 J 23-Oct-08 0.19 5.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.19 5.0 ND ND ND 0.21 J AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.19 5.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Apr-10 0.19 5.0 ND ND ND 0.35 J AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.19 5.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.19 5.0 ND ND ND 0.45 J AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.19 5.0 ND ND ND 0.62 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.19 5.0 ND ND ND 0.22 J AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.19 5.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.19 5.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 18 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient 2-Hexanone Apr-00 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND (Methyl Butyl Ketone)Oct-00 NR 50 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Oct-01 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 50 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 50 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI NA Oct-02 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 50 ND NI 64.7 ND AB ND ND AB ND ND NI ND NI NI NI NI ND Resample 14-Jun-06 NR 50 NS NI ND NS AB NS NS AB NS NS NI NS NI NI NI NI ND 19-Oct-06 NR 50 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.24 50 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.24 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 1.7 10.0 ND NS 14.1 ND AB ND Dry AB ND ND NI ND NS NS NS NS ND GWPS = 280 µg/L (10/23/07) Resample 28-Nov-07 0.46 5.0 NS NS 5.2 NS AB NS NS AB NS NS NI NS NS NS NS NS ND 12-Mar-08 0.46 50.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.46 50.0 ND ND 1.0 J ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.46 50.0 ND ND 2.8 J ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.46 50.0 ND ND ND ND AB ND ND AB 1.7 J ND NI ND ND ND ND ND ND 15-Oct-09 0.46 50.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Apr-10 0.46 50.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.46 50.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.46 50.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.46 50.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.46 50.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.46 50.0 ND ND ND ND ND ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.46 50.0 ND ND ND ND ND ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 19 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient 2-Butanone Oct-96 NR 13 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND (Methyl Ethyl Ketone) May-97 NR 13 ND NI ND ND ND ND ND ND 33 J NI NI NI NI NI NI NI ND Oct-97 NR 13 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-98 NR 13 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-98 NR 1.1 ND NI ND ND ND ND ND ND 18 NI NI NI NI NI NI NI ND Apr-99 NR 0.6 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-99 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-00 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Oct-00 NR 100 ND NI ND ND ND ND ND ND ND NI NI NI NI NI NI NI ND Apr-01 NR 100 ND NI ND ND 290 ND ND ND ND ND NI ND NI NI NI NI ND Resample Jun-01 NR 100 NS NI NS NS ND NS NS NS NS NS NI NS NI NI NI NI NA Oct-01 NR 100 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Apr-02 NR 100 ND NI ND ND ND ND ND ND ND ND NI ND NI NI NI NI ND Jul-02 NR 100 NS NI NS NS AB NS NS AB NA ND NI ND NI NI NI NI NA Oct-02 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-03 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 100 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.56 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.56 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 1.7 10.0 ND NS 70.8 ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 4,200 µg/L (10/23/07) Resample 28-Nov-07 0.96 5.0 NS NS 23.0 NS AB NS NS AB NS NS NI NS NS NS NS NS ND 12-Mar-08 0.96 100 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.96 100 ND ND ND ND AB ND ND AB 2.6 J ND NI ND ND ND ND ND ND 23-Oct-08 0.96 100 ND ND 15.1 J ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.96 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.96 100 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 4,000 µg/L (1/01/10)23-Apr-10 0.96 100 ND ND ND ND AB ND ND AB 6.4 J ND NI ND ND ND ND ND ND 28-Oct-10 0.96 100 ND ND ND ND AB ND ND AB 2.7 J ND NI ND ND ND ND ND ND 20-Apr-11 0.96 100 ND ND ND ND AB ND ND AB 1.2 J ND NI ND ND ND ND ND ND 04-Oct-11 0.96 100 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.96 100 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.96 100 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.96 100 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND 4.5 J Transylvania County Woodruff Landfill Permit No. 88-07 20 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Methylene Chloride 25-Apr-07 0.088 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.088 2.0 NS ND NS NS AB NS NS AB NS NS NI NS ND 1.2 J ND ND ND 17-Oct-07 0.97 2.0 ND NS ND ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 4.6 µg/L (10/23/07)12-Mar-08 0.97 2.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.97 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.97 2.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND 2.0 17-Apr-09 0.97 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.97 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND 1.5 J NC 2L = 5 µg/L (1/01/10)23-Apr-10 0.97 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.97 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND 21.9 20-Apr-11 0.97 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.97 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND 2.5 03-Apr-12 0.97 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.97 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.97 1.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND 1.5 Tetrachloroethylene 25-Apr-07 0.25 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.25 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.2 1 ND NS 0.2 J ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 0.7 µg/L (10/23/07)12-Mar-08 0.46 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND 0.85 J 23-Oct-08 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Apr-10 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.46 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.46 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.46 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.46 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.46 1.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 21 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Toluene Oct-96 NR 2.3 ND NI ND ND ND ND ND ND 10 NI NI NI NI NI NI NI ND May-97 NR 2.3 ND NI ND ND ND ND ND ND 18 NI NI NI NI NI NI NI ND Oct-97 NR 2.3 ND NI ND ND ND ND ND ND 15 NI NI NI NI NI NI NI ND Apr-98 NR 2.3 ND NI ND ND ND NA ND ND 18 NI NI NI NI NI NI NI ND Oct-98 NR 1.0 ND NI ND ND ND ND ND ND 36 NI NI NI NI NI NI NI 0.3 J Apr-99 NR 0.3 ND NI ND ND ND ND ND ND 12.3 NI NI NI NI NI NI NI ND Oct-99 NR 5.0 ND NI ND ND ND ND ND ND 7.6 NI NI NI NI NI NI NI ND Apr-00 NR 5.0 ND NI ND ND ND ND ND ND 8.2 NI NI NI NI NI NI NI ND Oct-00 NR 5.0 ND NI ND ND ND ND ND ND 80 NI NI NI NI NI NI NI ND Apr-01 NR 5.0 ND NI ND ND ND ND ND ND 29 ND NI ND NI NI NI NI ND Oct-01 NR 5.0 ND NI ND ND ND ND ND ND 43 ND NI ND NI NI NI NI ND Apr-02 NR 5.0 ND NI ND ND 300 ND ND ND 50 ND NI ND NI NI NI NI ND Resample May-02 NR 5.0 NS NI NS NS 150 NS NS NS NS NS NI NS NI NI NI NI ND Jul-02 NR 5.0 NS NI NS NS AB NS NS AB NS ND NI ND NI NI NI NI NA Oct-02 NR 5.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-03 NR 5.0 ND NI ND ND AB ND ND AB 5.2 ND NI ND NI NI NI NI ND Oct-03 NR 5.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-04 NR 5.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-04 NR 5.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Apr-05 NR 5.0 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND Oct-05 NR 5 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 20-Apr-06 NR 5 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 19-Oct-06 NR 5 ND NI ND ND AB ND ND AB ND ND NI ND NI NI NI NI ND 25-Apr-07 0.15 1 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.15 1 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND 0.39 J 17-Oct-07 0.2 1.0 ND NS 0.7 J ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 1,000 µg/L (10/23/07)12-Mar-08 0.26 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND 0.46 B 0.66 J 23-Apr-08 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.26 1.0 ND ND 0.4 J ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 600 µg/L (1/01/10)23-Apr-10 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.26 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.26 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.26 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.26 1.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.26 1.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 22 of 23 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 Blanks Concentration (µg/L) DL RL BackgroundDateConstituent Downgradient Xylenes (Total)25-Apr-07 0.21 1.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 10-Jul-07 0.21 1.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 17-Oct-07 0.3 3.0 ND NS 1.0 J ND AB ND Dry AB ND ND NI ND NS NS NS NS ND NC 2L = 530 µg/L (10/23/07)12-Mar-08 0.66 5.0 NS ND NS NS AB NS NS AB NS NS NI NS ND ND ND ND ND 23-Apr-08 0.23 3.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 23-Oct-08 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI NS ND ND ND ND ND 17-Apr-09 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 15-Oct-09 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND NC 2L = 500 µg/L (1/01/10)23-Apr-10 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 28-Oct-10 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 20-Apr-11 0.66 2.0 ND ND ND ND AB ND ND AB ND ND NI ND ND ND ND ND ND 04-Oct-11 0.66 2.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Apr-12 0.66 2.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 03-Oct-12 0.66 5.0 ND ND ND ND AB ND ND AB ND AB ND ND ND ND ND ND ND 24-Apr-13 0.66 5.0 ND ND ND ND AB ND ND AB ND AB NS ND ND ND ND ND ND Notes: 2. NC SWSL = North Carolina Solid Waste Section Limits 3. ND = Not detected above the laboratory reporting limit (February 1994 - October 2006). Not detected above the laboratory detection limit (April 2007 to present). 4. J = Estimated value since the concentration is below the laboratory's reporting limit. 5. B = Reported value suspected to represent blank contamination. 6. L = Estimated value; value exceeded highest calibration sample. 7. NC 2L Standard = North Carolina's groundwater quality standard established under 15A NCAC 2L, ,0202. 8. All values above the NC 2L/GWP Standards are shaded. 9. GWPS = Groundwater protection standard (used when NC 2L has not been established). 10. J1 = Qualifier used if the reported concentration has been rounded up to the RL due to EPA rounding rules. The concentration is considered to be estimated. 11. Dry = Monitoring well was considered to be dry and no sample collected. 12. NS = Monitoring well was not sampled. 13. NR = Not reported. 14. NA = Not available. 15. AB = Monitoring well was considered to be abandoned. 16. NI = Monitoring well was not installed. 1. RL = Reporting Limit (= Pace Incorporated reporting limits for February 1994 - February 1995, Hydrogogic, Inc. reporting limits for September 1995 - February 1996, EnviroTech Mid-Atlantic Laboratories detection limits for September 1996 - April 1998, Central Virginia Laboratories and Consultants, Inc. detection limits for September 1998, Specialized Assays, Inc. detection limits for April 1999, NC PQL for September 1999 - October 2006, and NC SWSL {or lower} April 2007 to present). Transylvania County Woodruff Landfill Permit No. 88-07 23 of 23 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER FIELD PARAMETERS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 pH Feb-94 5.30 NI 5.10 5.00 4.30 4.20 NI NI NI NI NI NI NI NI NI NI Aug-94 5.40 NI 5.40 5.00 5.50 5.40 NI NI NI NI NI NI NI NI NI NI Feb-95 5.70 NI 5.10 5.50 5.00 5.40 5.10 6.00 5.00 NI NI NI NI NI NI NI Sep-95 5.52 NI 5.28 5.46 5.62 5.49 5.76 5.09 5.43 NI NI NI NI NI NI NI Feb-96 6.60 NI 6.40 6.00 7.40 7.10 6.50 6.40 6.40 NI NI NI NI NI NI NI Oct-96 5.64 NI 5.54 5.67 5.54 6.14 5.88 5.35 5.72 NI NI NI NI NI NI NI May-97 5.49 NI 5.28 5.17 5.38 5.55 5.11 5.01 5.26 NI NI NI NI NI NI NI Oct-97 5.53 NI 5.33 5.21 5.39 5.46 5.17 4.96 5.41 NI NI NI NI NI NI NI Apr-98 6.44 NI 6.84 5.63 5.99 6.12 5.80 6.04 5.48 NI NI NI NI NI NI NI Oct-98 5.36 NI 5.18 4.40 4.02 3.85 4.10 4.02 6.02 NI NI NI NI NI NI NI Apr-99 5.56 NI 5.20 5.12 5.31 5.74 5.23 5.29 5.68 NI NI NI NI NI NI NI Oct-99 6.00 NI 6.10 6.38 6.62 7.43 7.79 6.12 6.65 NI NI NI NI NI NI NI Apr-00 6.16 NI 5.59 5.42 6.70 6.87 6.26 6.38 6.09 NI NI NI NI NI NI NI Oct-00 6.08 NI 5.52 5.19 5.60 5.39 5.40 5.24 5.55 NI NI NI NI NI NI NI Resample Jan-01 NS NI NS 6.31 NS NS NS NS NS NI NI NI NI NI NI NI Apr-01 5.92 NI 5.79 5.68 6.94 6.00 7.18 6.56 5.98 5.87 NI 5.86 NI NI NI NI Resample Jun-01 NS NI NS NS 6.63 NS NS NS NS NS NI NS NI NI NI NI Oct-01 5.64 NI 4.92 4.94 5.95 5.29 4.84 5.13 5.46 5.33 NI 6.25 NI NI NI NI Apr-02 5.78 NI 5.26 5.07 6.29 5.65 5.12 5.54 5.63 5.36 NI 6.23 NI NI NI NI Oct-02 6.23 NI 4.90 4.80 AB 5.09 5.51 AB 5.52 5.86 NI 6.18 NI NI NI NI Apr-03 4.94 NI 4.81 4.65 AB 5.01 6.34 AB 5.42 5.47 NI 5.85 NI NI NI NI Oct-03 6.04 NI 5.46 5.44 AB 5.03 5.83 AB 5.31 5.73 NI 5.84 NI NI NI NI Apr-04 5.42 NI 5.11 5.13 AB 5.57 5.45 AB 5.89 6.41 NI 6.16 NI NI NI NI Oct-04 5.48 NI 5.37 5.06 AB 5.76 5.23 AB 5.54 5.15 NI 5.99 NI NI NI NI Apr-05 5.15 NI 5.63 5.41 AB 5.41 5.68 AB 5.57 5.05 NI 6.53 NI NI NI NI Oct-05 6.12 NI 6.26 5.58 AB 5.51 5.58 AB 5.89 5.60 NI 6.55 NI NI NI NI 19-Apr-06 5.68 NI 5.80 5.39 AB 5.52 4.96 AB 5.30 5.04 NI 5.93 NI NI NI NI Resample 08-Jun-06 NS NI 5.97 NS AB 4.68 NS AB NS NS NI NS NI NI NI NI 19-Oct-06 5.14 NI 5.48 5.62 AB 5.13 4.56 AB 5.19 5.01 NI 6.21 NI NI NI NI Resample 29-Nov-06 NS NS NS NS AB 5.75 NS AB NS NS NI NS NS NS NS NS 25-Apr-07 5.49 6.48 5.27 5.24 AB 5.67 5.23 AB 5.41 5.27 NI 5.99 6.50 5.32 5.42 5.74 Resample 10-Jul-07 NS 6.64 5.79 NS AB NS NS AB NS NS NI NS 6.28 5.90 6.28 6.72 17-Oct-07 5.88 NS 5.73 5.50 AB 5.52 Dry AB 5.40 5.45 NI 6.01 NS NS NS NS Resample 28-Nov-07 NS NS 5.80 5.47 AB 5.48 NS AB 5.76 NS NI NS NS NS NS NS 12-Mar-08 NS 5.71 NS NS AB NS NS AB NS NS NI NS 5.62 5.33 5.45 5.45 23-Apr-08 5.56 6.43 5.42 5.20 AB 5.60 5.47 AB 5.32 5.36 NI 6.44 5.68 5.52 5.66 5.67 23-Oct-08 4.92 6.07 4.90 4.94 AB 5.61 NA AB 5.16 4.76 NI NS 6.01 4.53 5.57 5.45 Resample 14-Jan-09 NS NS NS NS AB NS NS AB NS 5.59 NI NS 5.26 5.33 NS NS 17-Apr-09 5.33 5.87 4.75 4.84 AB 5.22 4.93 AB 5.00 5.31 NI 5.85 5.04 5.08 5.00 5.16 Resample 28-May-09 NS NS 6.71 NS AB NS NS AB NS NS NI NS NS NS NS NS 15-Oct-09 6.39 6.21 5.20 5.38 AB 5.21 5.24 AB 5.61 5.37 NI 6.08 5.42 5.59 5.49 5.01 23-Apr-10 5.49 5.78 4.96 4.97 AB 5.61 5.29 AB 5.59 5.27 NI 5.84 5.28 5.37 5.18 5.58 Resample 11-Jun-10 NS NS 5.39 NS AB NS NS AB NS NS NI NS NS 5.63 NS NS 28-Oct-10 7.20 7.53 5.25 5.46 AB 5.54 5.29 AB 6.10 5.52 NI 6.60 5.90 5.98 6.21 6.12 Resample 21-Dec-10 NS NS NS NS AB NS NS AB NS 5.10 NI NS NS 5.62 NS NS 20-Apr-11 5.81 5.91 5.03 5.29 AB 5.55 5.42 AB 5.64 5.47 NI 6.16 5.60 5.38 5.30 5.91 04-Oct-11 5.71 6.01 5.34 5.42 AB 5.60 5.32 AB 5.59 AB 5.89 6.42 5.66 5.88 5.79 5.96 Resample 10-Nov-11 NS NS NS 5.59 AB NS NS AB NS AB NS NS NS NS NS NS 03-Apr-12 6.10 5.65 5.11 5.35 AB 5.59 5.50 AB 9.87 AB 5.46 6.33 5.65 5.56 5.98 6.15 03-Oct-12 5.55 5.96 5.30 5.36 AB 5.65 5.24 AB 5.75 AB 5.55 6.52 5.30 5.68 5.40 5.41 Resample 25-Oct-12 NS NS NS NS AB NS 5.42 AB NS AB NS NS NS NS NS NS 24-Apr-13 5.88 5.94 4.92 5.41 AB 5.32 5.68 AB 5.57 AB NS 6.33 5.64 5.79 5.60 5.71 DowngradientBackgroundParameterDate Transylvania County Woodruff Landfill Permit No. 88-07 Page 1 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER FIELD PARAMETERS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 DowngradientBackgroundParameterDate Conductivity Feb-94 19 NI 19 28 19 39 NI NI NI NI NI NI NI NI NI NI (µS/cm)Aug-94 20 NI 15 31 20 41 NI NI NI NI NI NI NI NI NI NI Feb-95 13 NI 11 20 18 32 39 18 44 NI NI NI NI NI NI NI Sep-95 24.3 NI 19 91.3 67.1 45.9 107.1 36.5 79.4 NI NI NI NI NI NI NI Feb-96 24 NI 16 80 22 30 80 23 30 NI NI NI NI NI NI NI Oct-96 10 NI 100.0 40 20 20 50 40 50 NI NI NI NI NI NI NI May-97 78.6 NI 89.9 96.9 85.3 74.7 99 104 91 NI NI NI NI NI NI NI Oct-97 75.4 NI 89.6 91.8 83.2 40.0 94 107 81 NI NI NI NI NI NI NI Apr-98 25 NI 23 60 28 31 42 34 104 NI NI NI NI NI NI NI Oct-98 33 NI 26 60 45 48 63 40 155 NI NI NI NI NI NI NI Apr-99 232 NI 238 813 260 339 46 308 171 NI NI NI NI NI NI NI Oct-99 28 NI 30 60 36 51 48 33 990 NI NI NI NI NI NI NI Apr-00 2.4 NI 2.5 6.6 2.5 4.1 3.6 2.7 14 NI NI NI NI NI NI NI Oct-00 27.1 NI 28.7 68.4 52.7 58.6 48.9 36.5 160.1 NI NI NI NI NI NI NI Resample Jan-01 NS NI NS 42.6 NS NS NS NS NS NI NI NI NI NI NI NI Apr-01 32.4 NI 34.1 80.2 247 52.2 47.8 38.7 160.4 36.2 NI 149.2 NI NI NI NI Resample Jun-01 NS NI NS NS 184.1 NS NS NS NS NS NI NS NI NI NI NI Oct-01 31.2 NI 27.1 80.5 117.9 61.6 59.5 38.2 162.0 39.3 NI 135.4 NI NI NI NI Apr-02 33.8 NI 34.9 85.4 469.0 56.6 46.7 36.3 187.5 39.7 NI 139.0 NI NI NI NI Oct-02 358 NI 31.7 91.6 AB 71.6 61.4 AB 176.2 44.6 NI 125.1 NI NI NI NI Apr-03 32.6 NI 45.1 86.2 AB 70.5 51.6 AB 158.4 52.0 NI 139.1 NI NI NI NI Oct-03 24.0 NI 36.1 84.9 AB 46.6 33.0 AB 105.4 44.4 NI 89.6 NI NI NI NI Apr-04 25.0 NI 45.4 99.0 AB 65.7 44.9 AB 113.0 53.3 NI 116.0 NI NI NI NI Oct-04 28.9 NI 59.1 114.3 AB 59.1 47.5 AB 93.6 51.6 NI 125.9 NI NI NI NI Apr-05 33.8 NI 158 214.0 AB 79.1 69.7 AB 136.8 85.1 NI 202 NI NI NI NI Oct-05 27.5 NI 441 112.8 AB 79.8 42.4 AB 87.1 47.3 NI 120.6 NI NI NI NI 19-Apr-06 23.0 NI 322 78.0 AB 56.0 31.0 AB 88.0 42.0 NI 90.0 NI NI NI NI Resample 08-Jun-06 NS NI 317 NS AB 63.0 NS AB NS NS NI NS NI NI NI NI 19-Oct-06 21 NI 177.00 78.00 AB 59.00 32.00 AB 67.00 45.00 NI 98.00 NI NI NI NI Resample 29-Nov-06 NS NS NS NS AB 71.00 NS AB NS NS NI NS NS NS NS NS 25-Apr-07 27.5 110.3 194 112.3 AB 71.10 42.7 AB 106.2 96.1 NI 139.5 24.7 59.4 60.6 22.6 Resample 10-Jul-07 NS 59.5 501 NS AB NS NS AB NS NS NI NS 31.9 85.9 56.4 26.9 17-Oct-07 27.1 NS 515 116.1 AB 103.4 Dry AB 77.4 65.2 NI 161.8 NS NS NS NS Resample 28-Nov-07 NS NS 495 120.9 AB 131.4 NS AB 76.0 NS NI NS NS NS NS NS 12-Mar-08 NS 63.8 NS NS NS NS NS NS NS NS NI NS 37.4 126.9 55.0 38.0 23-Apr-08 32.4 94.1 246 127.6 AB 65.1 51.5 AB 88.1 97.2 NI 174.6 37.4 137.8 62.6 33.6 23-Oct-08 52.3 31.2 468 133.0 AB 69.4 NA AB 91.9 90.7 NI NS 35.1 196 47.1 41.0 Resample 14-Jan-09 NS NS NS NS AB NS NS AB NS 122.8 NI NS 69.4 166.9 NS NS 17-Apr-09 35.4 51.1 229 133.6 AB 56.4 64.2 AB 97.9 151.0 NI 179.7 46.0 113.2 68.7 33.1 Resample 28-May-09 NS NS 1948 NS AB NS NS AB NS NS NI NS NS NS NS NS 15-Oct-09 36.9 40.7 259 135.3 AB 50.0 47.3 AB 159 126 NI 171.0 49 117.7 71.7 34.1 23-Apr-10 27.9 25.2 199 138.3 AB 41.8 45.4 AB 129.9 124.1 NI 134.1 32.6 116.8 73.1 29.0 Resample 11-Jun-10 NS NS 299 NS AB NS NS AB NS NS NI NS NS 106.3 NS NS 28-Oct-10 68.1 27 138.9 132.6 AB 86.8 65.8 AB 152.9 152.5 NI 197.7 51.0 177.0 59.7 35.7 Resample 21-Dec-10 NS NS NS NS AB NS NS AB NS 150.8 NI NS NS 184.0 NS NS 20-Apr-11 22.7 70.7 141.1 174.4 AB 47.8 78.5 AB 145.8 160.3 NI 186 46.1 114.3 53.1 48.9 04-Oct-11 31.1 28.3 243 191.5 AB 45.7 80.9 AB 135.6 AB 176.4 188 39.8 183 43.0 33.4 Resample 10-Nov-11 NS NS NS 192 AB NS NS AB NS AB NS NS NS NS NS NS 03-Apr-12 27.10 41.1 184.60 157 AB 41.10 76.40 AB 153.0 AB 153.9 182.0 41.1 124.7 50.1 38.3 03-Oct-12 27.8 19.2 167.8 139 AB 40.1 61.3 AB 147.2 AB 159.4 198.2 59.5 118.7 46.6 30.8 Resample 25-Oct-12 NS NS NS NS AB NS 67.4 AB NS AB NS NS NS NS NS NS 24-Apr-13 26.3 17.19 84.6 152.9 AB 40.9 63.6 AB 133.2 AB NS 181.4 36.7 118.4 61.6 46.2 Transylvania County Woodruff Landfill Permit No. 88-07 Page 2 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER FIELD PARAMETERS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 DowngradientBackgroundParameterDate Temperature Feb-94 16 NI 15 14 14 14 NI NI NI NI NI NI NI NI NI NI (degrees C)Aug-94 14 NI 15 17 16 15 NI NI NI NI NI NI NI NI NI NI Feb-95 13 NI 15 14 13.0 13.0 14.0 13.0 16.0 NI NI NI NI NI NI NI Sep-95 14.3 NI 22.2 17.1 18.7 16.3 17.5 18.8 16.6 NI NI NI NI NI NI NI Feb-96 11.9 NI 12 11.6 7.5 9.9 10.7 8.3 12.8 NI NI NI NI NI NI NI Oct-96 12.2 NI 13.3 13.3 13.9 12.8 12.8 13.9 12.8 NI NI NI NI NI NI NI May-97 16.2 NI 15.4 16.3 16.0 17.7 13.3 16.5 15.2 NI NI NI NI NI NI NI Oct-97 14 NI 15.2 15.1 16.3 14.2 16 17 15 NI NI NI NI NI NI NI Apr-98 18.4 NI 18.5 18.4 17.6 19.0 18.4 17.5 18.2 NI NI NI NI NI NI NI Oct-98 16.1 NI 16.8 15.8 15.4 15.5 15.8 16.8 14.5 NI NI NI NI NI NI NI Apr-99 18 NI 19.2 15.2 14.0 16.5 18.2 14.8 17.2 NI NI NI NI NI NI NI Oct-99 9.7 NI 14 14.4 13.5 12.4 14.1 13.4 15.0 NI NI NI NI NI NI NI Apr-00 14.5 NI 15.9 13.3 13.1 12.0 13.6 12.4 14.7 NI NI NI NI NI NI NI Oct-00 13.1 NI 14.9 15.4 15.2 13.8 15.2 15.2 14.5 NI NI NI NI NI NI NI Resample Jan-01 NS NI NS 14.9 NS NS NS NS NS NI NI NI NI NI NI NI Apr-01 12.4 NI 13.6 11.3 10.4 12.4 11.4 11.4 13.8 11.0 NI 13.1 NI NI NI NI Resample Jun-01 NS NI NS NS 15.0 NS NS NS NS NS NI NS NI NI NI NI Oct-01 15.9 NI 15.5 15.0 15.6 15.2 13.5 17.0 14.8 15.9 NI 16.9 NI NI NI NI Apr-02 14.6 NI 14.5 12.6 11.3 12.0 13.8 11.5 13.5 14.2 NI 13.8 NI NI NI NI Oct-02 12.2 NI 16.8 14.9 AB 13.9 14.4 AB 15.6 19.4 NI 17.9 NI NI NI NI Apr-03 10.8 NI 10.1 10.0 AB 9.9 7.1 AB 12.1 11.8 NI 11.5 NI NI NI NI Oct-03 14.6 NI 16.5 17.3 AB 13.3 13.0 AB 12.9 16.1 NI 14.5 NI NI NI NI Apr-04 13.4 NI 13.6 12.1 AB 12.3 11.7 AB 13.8 13.5 NI 13.9 NI NI NI NI Oct-04 13.3 NI 14.2 15.4 AB 14.8 13.9 AB 14.0 14.2 NI 13.6 NI NI NI NI Apr-05 12.8 NI 12.3 11.2 AB 10.8 9.7 AB 13.2 11.3 NI 10.3 NI NI NI NI Oct-05 14 NI 16.3 16.5 AB 15.8 15.4 AB 14.2 14.8 NI 14.6 NI NI NI NI 19-Apr-06 14.4 NI 14.9 14.6 AB 13.2 12.7 AB 14.4 14.0 NI 14.7 NI NI NI NI Resample 08-Jun-06 NS NI 17.7 NS AB 12.4 NS AB NS NS NI NS NI NI NI NI 19-Oct-06 13.61 NI 15.54 15.02 AB 13.86 14.95 AB 14.16 14.83 NI 14.88 NI NI NI NI Resample 29-Nov-06 NS NS NS NS AB 13.80 NS AB NS NS NI NS NS NS NS NS 25-Apr-07 14.9 14.2 15 14.2 AB 12.50 14.1 AB 15.8 16.4 NI 15.7 13.8 16.6 16.1 14.8 Resample 10-Jul-07 NS 13.4 15.2 NS AB NS NS AB NS NS NI NS 12.9 14.3 16.0 14.0 17-Oct-07 13.7 NS 15.1 15.8 AB 14.0 Dry AB 14.6 15.4 NI 13.8 NS NS NS NS Resample 28-Nov-07 NS NS 13.4 13.1 AB 11.7 NS AB 12.6 NS NI NS NS NS NS NS 12-Mar-08 NS 10.7 NS NS AB NS NS AB NS NS NI NS 11..3 13.1 12.9 13.0 23-Apr-08 13.8 13.7 15.4 12.7 AB 12.5 12.6 AB 14.9 14.5 NI 15.4 13.5 13.9 14.8 14.7 23-Oct-08 11.8 11.6 14.5 14.3 AB 14.0 NA AB 12.1 13.9 NI NS 12.2 13.5 13.1 11.9 Resample 14-Jan-09 NS NS NS NS AB NS NS AB NS 12.3 NI NS 9.1 12.4 NS NS 17-Apr-09 12.1 12.0 13.5 12.5 AB 12.1 10.7 AB 13.8 14.4 NI 14.5 10.6 13.5 13.8 13.0 Resample 28-May-09 NS NS 17.4 NS AB NS NS AB NS NS NI NS NS NS NS NS 15-Oct-09 10.5 10.0 13.0 13.1 AB 11.7 13.1 AB 11.1 12.1 NI 12.7 11.5 11.7 11.5 11.1 23-Apr-10 12.6 12.3 13.9 13.8 AB 12.7 11.6 AB 14.2 15.1 NI 15.2 11.5 14.1 14.6 13.5 Resample 11-Jun-10 NS NS 13.7 NS AB NS NS AB NS NS NI NS NS 13.5 NS NS 28-Oct-10 12.6 12.3 15.9 15.8 AB 13.8 15.4 AB 13.7 15.1 NI 14.9 14.4 14.1 13.5 13.0 Resample 21-Dec-10 NS NS NS NS AB NS NS AB NS 14.6 NI NS NS 13.3 NS NS 20-Apr-11 12.8 12.6 14.1 12.0 AB 12.0 10.7 AB 14.5 13.7 NI 14.1 11.4 12.8 13.4 13.0 04-Oct-11 13.7 11.8 15.2 15.4 AB 14.1 14.3 AB 14.3 AB 14.1 14.5 14.0 13.4 13.3 12.3 Resample 10-Nov-11 NS NS NS 14.0 AB NS NS AB NS AB NS NS NS NS NS NS 03-Apr-12 13.60 12.1 14.70 14.2 AB 13.1 12.1 AB 14.7 AB 14.6 14.7 12.10 13.7 14.0 13.8 03-Oct-12 13.7 13.3 15.1 16.4 AB 14.8 16.2 AB 14.3 AB 15.5 16.1 14.5 14.9 14.2 14.0 Resample 25-Oct-12 NS NS NS NS AB NS 16.2 AB NS AB NS NS NS NS NS NS 24-Apr-13 13.5 13.2 14.5 13.8 AB 13.0 11.8 AB 14.4 AB NS 15.2 13.5 14.6 15.3 14.2 Transylvania County Woodruff Landfill Permit No. 88-07 Page 3 of 4 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER FIELD PARAMETERS MW-3 MW-10 MW-1 MW-2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9S MW-9SR MW-9D MW-11 MW-12S MW-12D MW-13 DowngradientBackgroundParameterDate Turbidity Oct-96 32.0 NI 56.0 186 12.0 6.00 318 49.0 38.0 NI NI NI NI NI NI NI (NTUs)May-97 8.01 NI 2.29 99.3 2.29 5.46 14.9 1.07 6.69 NI NI NI NI NI NI NI Oct-97 31.2 NI 15.2 90.7 10.4 59.9 463 8.89 8.12 NI NI NI NI NI NI NI Apr-98 4.3 NI 2.10 1.10 44.0 32.2 39.8 59.8 32.6 NI NI NI NI NI NI NI Oct-98 136 NI 12.2 46.4 47.1 7.40 46.0 25.1 10.9 NI NI NI NI NI NI NI Apr-99 19.9 NI 73.4 33.8 20.3 12.0 27.8 39.0 21.1 NI NI NI NI NI NI NI Oct-99 93.7 NI 54.3 66.8 26.7 9.70 10.4 38.1 12.5 NI NI NI NI NI NI NI Apr-00 72.9 NI 39.0 24.7 23.8 23.6 77.7 26 23.2 NI NI NI NI NI NI NI Oct-00 >1000 NI 35.2 4.90 9.64 1.30 10.8 9.9 3.59 NI NI NI NI NI NI NI Apr-01 6.85 NI 42.8 6.15 18.9 0.70 11.5 10.0 7.98 15.6 NI 124 NI NI NI NI Resample Jun-01 NS NI NS NS 24.3 NS NS NS NS NS NI NS NI NI NI NI Oct-01 8.53 NI 32.2 7.99 19.8 1.60 2.55 23.5 4.74 7.96 NI 10.2 NI NI NI NI Apr-02 20.3 NI 17.9 26.6 26.4 0.96 23.1 27.3 19.3 12.4 NI 7.51 NI NI NI NI Oct-02 671 NI 343 17.4 AB 5.87 10.1 AB 65.9 32.5 NI 9.31 NI NI NI NI Apr-03 269 NI 14.7 NA AB NA NA AB 58.1 15.8 NI 6.04 NI NI NI NI Oct-03 18.7 NI 4.11 1.85 AB 1.36 35.1 AB 22.0 41.4 NI 7.9 NI NI NI NI Apr-04 16.6 NI 68.6 4.74 AB 5.85 7.50 AB 5.84 2.81 NI 3.64 NI NI NI NI Oct-04 22.5 NI 6.75 9.75 AB 2.59 61.7 AB 19.19 24.6 NI 3.50 NI NI NI NI Apr-05 821 NI 2.10 3.89 AB 1.92 9.43 AB 33.3 11.6 NI 2.31 NI NI NI NI Oct-05 8.79 NI 5.28 4.64 AB 3.76 40.4 AB 28.4 6.01 NI 5.40 NI NI NI NI 19-Apr-06 NA NI 43.7 NS AB 2.55 13.8 AB 11.4 4.13 NI 2.13 NI NI NI NI Resample 08-Jun-06 NS NI 111 NS AB 2.71 NS AB NS NS NI NS NI NI NI NI 19-Oct-06 50 NI 5.00 5.00 AB 5.80 25.00 AB 30.00 5.00 NI 5.00 NI NI NI NI Resample 29-Nov-06 NS NS NS NS AB 9.70 NS AB NS NS NI NS NS NS NS NS 25-Apr-07 2.86 125 1.27 1.28 AB 2.29 6.92 AB 4.42 6.92 NI 2.25 2.47 289 17.5 13.74 Resample 10-Jul-07 NS 45.8 46.9 NS AB NS NS AB NS NS NI NS 6.44 7.74 76.4 3.90 17-Oct-07 23.5 NS 9.49 3.03 AB 2.79 Dry AB 1.92 5.26 NI 57.0 NS NS NS NS Resample 28-Nov-07 NS NS 6.70 3.13 AB 2.79 NS AB 2.92 NS NI NS NS NS NS NS 12-Mar-08 NS 55.8 NS NS AB NS NS AB NS NS NI NS 84.9 62.3 18.38 63.4 23-Apr-08 8.50 65.8 17.81 66.6 AB 6.13 63.0 AB 9.53 13.79 NI 17.84 7.74 743 24.3 31.4 23-Oct-08 11.55 91.6 6.45 23.0 AB 3.70 65.0 AB 39.0 185 NI NS 24.1 >1000 13.92 150 Resample 14-Jan-09 NS NS NS NS AB NS NS AB NS 22.4 NI NS 19.78 594 NS NS 17-Apr-09 22.53 66.0 16.5 20.58 AB 16.9 24.5 AB 27.5 26.3 NI 22.66 21.08 71.6 15.8 31.1 Resample 28-May-09 NS NS 44.3 NS AB NS NS AB NS NS NI NS NS NS NS NS 15-Oct-09 22.1 29.5 2.08 20 AB 12.0 2.56 AB 4.96 52.2 NI 2.08 4.76 31.8 16.54 55.6 23-Apr-10 5.18 22.3 19.7 61.2 AB 1.87 217 AB 15.4 25.1 NI 3.01 4.48 >1000 4.11 15.9 Resample 11-Jun-10 NS NS 3.97 NS AB NS NS AB NS NS NI NS NS 6.09 NS NS 28-Oct-10 8.13 17.82 15.21 11.9 AB 3.63 63.3 AB 8.58 19.84 NI 30.4 7.17 395 9.45 5.3 Resample 21-Dec-10 NS NS NS NS AB NS NS AB NS 37.7 NI NS NS 320 NS NS 20-Apr-11 22.8 8.13 12.21 11.62 AB 5.45 9.44 AB 10.86 9.25 NI 21.0 4.35 4.67 10.17 10.70 04-Oct-11 17.8 12.29 47.2 19.1 AB 7.56 13.66 AB 13.5 AB 16.8 8.19 17.03 11.99 12.4 21.0 Resample 10-Nov-11 NS NS NS 86.7 AB NS NS AB NS AB NS NS NS NS NS NS 03-Apr-12 13.77 3.24 8.61 6.2 AB 4.03 15.80 AB 9.87 AB >1000 6.10 3.29 39.60 5.98 6.15 03-Oct-12 10.28 15.58 15.38 7.99 AB 3.62 4.96 AB 12.34 AB 253 2.69 3.94 19.88 9.75 19.96 Resample 25-Oct-12 NS NS NS NS AB NS 86.3 AB NS AB NS NS NS NS NS NS 24-Apr-13 8.66 23 13.17 7.41 AB 5.65 12.80 AB 10.17 AB NS 10.38 7.72 21.2 13.35 8.02 Notes: 1. All parameters were measured in the field. 2. - = not available 3. NS = Not sampled. 4. Due to facility construction MW-4 and MW-7 were abandoned in July 2002. 5. MW-6 was dry during the October 2007 sampling event. 6. NA = Not available. 7. AB = Monitoring well has been abandoned. 8. NI = Monitoring well has not been installed. 9. Dry = Monitoring well was considered to be dry and no sampled collected. Transylvania County Woodruff Landfill Permit No. 88-07 Page 4 of 4 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3 Antimony Feb-94 NR 4 ND NM NA Aug-94 NR 4 ND NM NA Feb-95 NR 4 ND NM NA Sep-95 NR 3 31 NM ND Oct-96 NR 5 ND NM ND May-97 NR 5 ND NM ND Oct-97 NR 5 ND NM ND Apr-98 NR 5 ND NM ND Oct-98 NR 5 Dry NM NA Apr-99 NR 5 ND NM ND Oct-99 NR 30 ND NM ND Apr-00 NR 30 ND NM ND Oct-00 NR 30 ND NM ND Apr-01 NR 30 ND NM ND Oct-01 NR 30 ND NM ND Apr-02 NR 30 ND NM ND Oct-02 NR 30 ND NM ND Apr-03 NR 30 ND NM ND Oct-03 NR 30 ND NM ND Apr-04 NR 30 ND NM ND Oct-04 NR 30 ND NM ND Apr-05 NR 30 ND NM ND Oct-05 NR 30 ND NM ND 20-Apr-06 NR 30 ND NM ND 19-Oct-06 NR 30 ND NM ND 25-Apr-07 0.58 6 ND NM ND NC2B= NE µg/L (05/01/07)17-Oct-07 3.0 5.0 ND NM ND 23-Apr-08 2.6 6.0 ND NM ND 23-Oct-08 2.6 6.0 ND Dry ND 17-Apr-09 2.6 6.0 ND ND ND 15-Oct-09 2.6 6.0 ND ND ND 23-Apr-10 2.6 6.0 ND ND ND 28-Oct-10 2.6 6.0 ND ND ND 19-Apr-11 2.6 6.0 ND ND ND 05-Oct-11 5.0 6.0 ND ND ND 03-Apr-12 5.0 6.0 ND ND ND 03-Oct-12 5.0 6.0 ND ND ND 23-Apr-13 5.0 6.0 ND ND ND Arsenic Feb-94 NR 1 ND NM NA Aug-94 NR 5 ND NM NA Feb-95 NR 5 ND NM NA Sep-95 NR 10 ND NM ND Feb-96 NR 3 NA NM ND Oct-96 NR 5 2.2 B NM 2.2 J May-97 NR 5 ND NM ND Oct-97 NR 5 ND NM ND Apr-98 NR 5 ND NM ND Oct-98 NR 10 Dry NM ND Apr-99 NR 2.5 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 10 NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 17.2 NM ND Resample Jun-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 13.9 NM ND 25-Apr-07 2.0 10 4.6 B NM 2.1 J NC2B= 10 µg/L (05/01/07)17-Oct-07 3.0 10.0 ND NM ND 23-Apr-08 2.7 10.0 ND NM ND 23-Oct-08 2.7 10.0 ND Dry 4.4 J 17-Apr-09 2.7 10.0 ND ND ND 15-Oct-09 2.7 10.0 2.8 J ND ND 23-Apr-10 2.7 10.0 ND ND ND 28-Oct-10 2.7 10.0 10.5 ND ND Resample 21-Dec-10 2.7 10.0 ND NS ND 19-Apr-11 2.7 10.0 ND ND ND 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 ND ND ND Date Concentrations in µg/L BlanksConstituent Transylvania County Woodruff Landfill Permit No. 88-07 Page 1 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Barium Feb-94 NR 100 ND NM NA Aug-94 NR 100 ND NM NA Feb-95 NR 100 ND NM NA Sep-95 NR 5 21 NM ND Feb-96 NR 5 NA NM ND Oct-96 NR 10 ND NM ND May-97 NR 10 14 NM 1.3 J Oct-97 NR 10 13 NM ND Apr-98 NR 10 3.0 J NM ND Oct-98 NR 20 Dry NM 109 Apr-99 NR 10 ND NM ND Oct-99 NR 500 ND NM ND Apr-00 NR 500 ND NM ND Oct-00 NR 500 ND NM ND Apr-01 NR 500 ND NM ND Oct-01 NR 500 ND NM ND Apr-02 NR 500 ND NM ND Oct-02 NR 500 ND NM ND Apr-03 NR 500 ND NM ND Oct-03 NR 500 ND NM ND Apr-04 NR 500 ND NM ND Oct-04 NR 500 ND NM ND Apr-05 NR 500 ND NM ND Oct-05 NR 500 ND NM ND 20-Apr-06 NR 500 ND NM ND 19-Oct-06 NR 500 ND NM ND 25-Apr-07 0.20 100 11.8 J NM 0.50 J NC2B= NE µg/L (05/01/07)17-Oct-07 2.0 10.0 16.1 NM ND 23-Apr-08 0.20 100 17.2 J NM 3.0 J 23-Oct-08 0.20 100 12.3 B Dry 8.9 J 17-Apr-09 0.20 100 35.4 B 4.2 B 13.5 J 15-Oct-09 0.20 100 42.8 B 59.9 B 19.3 J 23-Apr-10 0.20 100 15.5 B 9.4 B 27.0 J 28-Oct-10 0.20 100 49.8 J 3.1 J ND 19-Apr-11 0.20 100 29.1 B 3.0 B 14.5 J 05-Oct-11 5.0 100 24 J 7.0 J ND 03-Apr-12 5.0 100 21.1 J 5.8 J ND 03-Oct-12 5.0 100 28.6 J ND ND 23-Apr-13 5.0 100 19.7 J ND ND Beryllium Feb-94 NR 2 ND NM AB Aug-94 NR 2 ND NM AB Feb-95 NR 2 ND NM AB Sep-95 NR 1 ND NM ND Feb-96 NR 1 NA NM ND Oct-96 NR 2 ND NM 0.4 J May-97 NR 2 ND NM ND Oct-97 NR 2 ND NM ND Apr-98 NR 2 ND NM ND Oct-98 NR 2 Dry NM ND Apr-99 NR 4 ND NM ND Oct-99 NR 2 ND NM ND Apr-00 NR 2 ND NM ND Oct-00 NR 2 ND NM ND Apr-01 NR 2 ND NM ND Oct-01 NR 2 ND NM ND Apr-02 NR 2 ND NM ND Oct-02 NR 2 ND NM ND Apr-03 NR 2 ND NM ND Oct-03 NR 2 ND NM ND Apr-04 NR 2 ND NM ND Oct-04 NR 2 ND NM ND Apr-05 NR 2 ND NM ND Oct-05 NR 2 ND NM ND 20-Apr-06 NR 2 ND NM ND 19-Oct-06 NR 30 ND NM ND 25-Apr-07 0.70 1.0 ND NM ND NC2B= 6.5 µg/L (05/01/07)17-Oct-07 0.1 0.3 ND NM ND 23-Apr-08 0.10 1.0 ND NM ND 23-Oct-08 0.10 1.0 ND Dry ND 17-Apr-09 0.10 1.0 0.15 J ND ND 15-Oct-09 0.10 1.0 0.15 J 0.67 J ND 23-Apr-10 0.10 1.0 0.26 B 0.60 B 0.17 J 28-Oct-10 0.10 1.0 0.34 J ND ND 19-Apr-11 0.10 1.0 ND ND ND 05-Oct-11 1.0 1.0 ND ND ND 03-Apr-12 1.0 1.0 ND ND ND 03-Oct-12 1.0 1.0 ND ND ND 23-Apr-13 1.0 1.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 2 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Cadmium Feb-94 NR 1.0 ND NM NA Aug-94 NR 1.0 ND NM NA Feb-95 NR 1.0 ND NM NA Sep-95 NR 0.1 ND NM ND Feb-96 NR 1.0 NA NM ND Oct-96 NR 0.5 ND NM ND May-97 NR 0.5 0.16 J NM ND Oct-97 NR 0.5 ND NM ND Apr-98 NR 0.5 ND NM ND Oct-98 NR 1.0 Dry NM ND Apr-99 NR 1.0 ND NM ND Oct-99 NR 1.0 ND NM ND Apr-00 NR 1.0 ND NM ND Oct-00 NR 1.0 ND NM ND Apr-01 NR 1.0 ND NM ND Oct-01 NR 1.0 ND NM ND Apr-02 NR 1.0 ND NM ND Oct-02 NR 1.0 ND NM ND Apr-03 NR 1.0 ND NM ND Oct-03 NR 1.0 ND NM ND Apr-04 NR 1.0 ND NM ND Oct-04 NR 1.0 ND NM ND Apr-05 NR 1.0 ND NM ND Oct-05 NR 1 ND NM ND 20-Apr-06 NR 1 ND NM ND 19-Oct-06 NR 1 ND NM ND 25-Apr-07 0.50 1 ND NM ND NC2B= 0.4 µg/L (05/01/07)17-Oct-07 0.1 0.3 ND NM ND 23-Apr-08 0.50 1.0 ND NM ND 23-Oct-08 0.50 1.0 ND Dry ND 17-Apr-09 0.50 1.0 ND ND ND 15-Oct-09 0.50 1.0 ND ND ND 23-Apr-10 0.50 1.0 ND ND ND 28-Oct-10 0.50 1.0 ND ND ND 19-Apr-11 0.50 1.0 ND ND ND 05-Oct-11 1.0 1.0 ND ND ND 03-Apr-12 1.0 1.0 ND ND ND 03-Oct-12 1.0 1.0 ND ND ND 23-Apr-13 1.0 1.0 ND ND ND Chromium Feb-94 NR 20 ND NM NA Aug-94 NR 5 ND NM NA Feb-95 NR 5 ND NM NA Sep-95 NR 0.1 4.0 NM ND Feb-96 NR 5.0 NA NM ND Oct-96 NR 10 ND NM 3.4 J May-97 NR 10 ND NM ND Oct-97 NR 10 1.3 J NM 3.5 J Apr-98 NR 10 ND NM ND Oct-98 NR 10 Dry NM 2.0 J Apr-99 NR 5 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 ND NM ND 25-Apr-07 2.0 10 ND NM ND NC2B= 50 µg/L (05/01/07)17-Oct-07 1.0 10.0 1.7 J NM ND 23-Apr-08 0.40 10.0 0.69 J NM 1.0 J 23-Oct-08 0.40 10.0 ND Dry ND 17-Apr-09 0.40 10.0 1.4 J ND ND 15-Oct-09 0.40 10.0 1.6 J 2.6 J ND 23-Apr-10 0.40 10.0 1.0 B 0.88 B 0.41 J 28-Oct-10 0.40 10.0 2.0 J ND ND 19-Apr-11 0.40 10.0 0.54 J 0.52 J ND 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 3 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Cobalt Feb-94 NR 20 ND NM NA Aug-94 NR 10 ND NM NA Feb-95 NR 10 ND NM NA Sep-95 NR 5.0 ND NM ND Feb-96 NR 5.0 NA NM ND Oct-96 NR 10 ND NM 5.5 J May-97 NR 10 ND NM ND Oct-97 NR 10 ND NM ND Apr-98 NR 10 4.7 J NM ND Oct-98 NR 10 Dry NM ND Apr-99 NR 20 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 ND NM ND 25-Apr-07 2.0 10 ND NM ND NC2B= NE µg/L (05/01/07)17-Oct-07 2.0 10.0 ND NM ND 23-Apr-08 0.60 10.0 ND NM 1.5 J 23-Oct-08 0.60 10.0 1.6 B Dry 2.1 J 17-Apr-09 0.60 10.0 10.9 B 5.1 B 4.9 J 15-Oct-09 0.60 10.0 0.85 J ND ND 23-Apr-10 0.60 10.0 2.6 J ND ND 28-Oct-10 0.60 10.0 0.96 B 1.6 B 3.2 J 19-Apr-11 0.60 10.0 5.2 J 1.4 J ND 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 6.5 J ND ND Copper Feb-94 NR 10 ND NM NA Aug-94 NR 10 ND NM NA Feb-95 NR 10 ND NM NA Sep-95 NR 5 ND NM ND Feb-96 NR 5 NA NM ND Oct-96 NR 10 ND NM 2.9 J May-97 NR 10 ND NM ND Oct-97 NR 10 ND NM 3.9 J Apr-98 NR 10 4.9 J NM ND Oct-98 NR 10 Dry NM 79 Apr-99 NR 10 ND NM ND Oct-99 NR 200 2.0 J NM ND Apr-00 NR 200 ND NM ND Oct-00 NR 200 ND NM ND Apr-01 NR 200 ND NM ND Oct-01 NR 200 ND NM ND Apr-02 NR 200 ND NM ND Oct-02 NR 200 ND NM ND Apr-03 NR 200 ND NM ND Oct-03 NR 200 ND NM ND Apr-04 NR 200 ND NM ND Oct-04 NR 200 ND NM ND Apr-05 NR 200 ND NM ND Oct-05 NR 200 ND NM ND 20-Apr-06 NR 200 ND NM ND 19-Oct-06 NR 200 ND NM ND 25-Apr-07 0.60 10 ND NM ND NC2B= 7 µg/L (05/01/07)17-Oct-07 3.0 10.0 ND NM ND 23-Apr-08 0.30 10.0 ND NM ND 23-Oct-08 0.30 10.0 ND Dry ND 17-Apr-09 0.30 10.0 ND ND ND 15-Oct-09 0.30 10.0 0.38 J 5.9 J ND 23-Apr-10 0.30 10.0 ND ND ND 28-Oct-10 0.30 10.0 2.2 J ND ND 19-Apr-11 0.30 10.0 2.0 J 0.89 B 0.38 J 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 4 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Lead Feb-94 NR 1 ND NM NA Aug-94 NR 5 ND NM NA Feb-95 NR 5 ND NM NA Sep-95 NR 3 ND NM ND Feb-96 NR 3 NA NM ND Oct-96 NR 1 ND NM 0.3 J May-97 NR 1 3.9 NM 0.4 J Oct-97 NR 1 0.3 NM ND Apr-98 NR 1 5.2 NM ND Oct-98 NR 10 Dry NM 4.0 J Apr-99 NR 3 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 ND NM ND 25-Apr-07 2.0 10 ND NM ND NC2B= 25 µg/L (05/01/07)17-Oct-07 6.0 10.0 ND NM ND 23-Apr-08 4.0 10.0 ND NM ND 23-Oct-08 4.0 10.0 ND Dry ND 17-Apr-09 4.0 10.0 ND ND ND 15-Oct-09 4.0 10.0 ND 11.1 ND 23-Apr-10 4.0 10.0 ND ND ND 28-Oct-10 4.0 10.0 5.7 J ND ND 19-Apr-11 4.0 10.0 ND ND ND 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 ND ND ND Nickel Feb-94 NR 50 ND NM NA Aug-94 NR 50 ND NM NA Feb-95 NR 50 ND NM NA Sep-95 NR 5 ND NM ND Feb-96 NR 5 NA NM ND Oct-96 NR 20 ND NM ND May-97 NR 20 ND NM 4.5 J Oct-97 NR 20 ND NM 5.5 J Apr-98 NR 20 ND NM ND Oct-98 NR 400 Dry NM ND Apr-99 NR 10 ND NM ND Oct-99 NR 50 ND NM ND Apr-00 NR 50 ND NM ND Oct-00 NR 50 ND NM ND Apr-01 NR 50 ND NM ND Oct-01 NR 50 ND NM ND Apr-02 NR 50 ND NM ND Oct-02 NR 50 ND NM ND Apr-03 NR 50 ND NM ND Oct-03 NR 50 ND NM ND Apr-04 NR 50 ND NM ND Oct-04 NR 50 ND NM ND Apr-05 NR 50 ND NM ND Oct-05 NR 50 ND NM ND 20-Apr-06 NR 50 ND NM ND 19-Oct-06 NR 50 ND NM ND 25-Apr-07 2.0 50 ND NM ND NC2B= 88 µg/L (05/01/07)17-Oct-07 2.0 10.0 ND NM ND 23-Apr-08 1.7 50.0 ND NM ND 23-Oct-08 1.7 50.0 ND Dry ND 17-Apr-09 1.7 50.0 ND ND 3.3 J 15-Oct-09 1.7 50.0 ND 1.9 B 2.0 J 23-Apr-10 1.7 50.0 ND ND ND 28-Oct-10 1.7 50.0 ND ND ND 19-Apr-11 1.7 50.0 ND ND 5.8 J 05-Oct-11 5.0 50.0 ND ND ND 03-Apr-12 5.0 50.0 ND ND ND 03-Oct-12 5.0 50.0 ND ND ND 23-Apr-13 5.0 50.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 5 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Selenium Feb-94 NR 1 ND NM NA Aug-94 NR 5 ND NM NA Feb-95 NR 5 ND NM NA Sep-95 NR 10 ND NM ND Feb-96 NR 3 NA NM ND Oct-96 NR 5 ND NM ND May-97 NR 5 ND NM ND Oct-97 NR 5 ND NM ND Apr-98 NR 5 ND NM ND Oct-98 NR 10 Dry NM ND Apr-99 NR 5 ND NM ND Oct-99 NR 20 ND NM ND Apr-00 NR 20 ND NM ND Oct-00 NR 20 ND NM ND Apr-01 NR 20 ND NM ND Oct-01 NR 20 ND NM ND Apr-02 NR 20 ND NM ND Oct-02 NR 20 ND NM ND Apr-03 NR 20 ND NM ND Oct-03 NR 20 ND NM ND Apr-04 NR 20 ND NM ND Oct-04 NR 20 ND NM ND Apr-05 NR 20 ND NM ND Oct-05 NR 20 ND NM ND 20-Apr-06 NR 20 ND NM ND 19-Oct-06 NR 20 ND NM ND 25-Apr-07 2.0 10 ND NM ND NC2B= 5 µg/L (05/01/07)17-Oct-07 2.0 10.0 ND NM ND 23-Apr-08 3.8 10.0 ND NM ND 23-Oct-08 3.8 10.0 ND Dry ND 17-Apr-09 3.8 10.0 ND ND ND 15-Oct-09 3.8 10.0 ND ND ND 23-Apr-10 3.8 10.0 ND ND ND 28-Oct-10 3.8 10.0 ND ND ND 19-Apr-11 3.8 10.0 ND ND ND 05-Oct-11 10.0 10.0 ND ND ND 03-Apr-12 10.0 10.0 ND ND ND 03-Oct-12 10.0 10.0 ND ND ND 23-Apr-13 10.0 10.0 ND ND ND Silver Feb-94 NR 10 ND NM NA Aug-94 NR 10 ND NM NA Feb-95 NR 10 ND NM NA Sep-95 NR 0.2 ND NM ND Feb-96 NR 1.0 NA NM ND Oct-96 NR 10 ND NM 5.0 J May-97 NR 10 ND NM ND Oct-97 NR 10 ND NM ND Apr-98 NR 10 ND NM ND Oct-98 NR 2 Dry NM ND Apr-99 NR 5 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 ND NM ND 25-Apr-07 2.0 10 ND NM ND NC2B= 0.06 µg/L (05/01/07)17-Oct-07 2.0 10 ND NM ND 23-Apr-08 0.10 10.0 ND NM 0.11 J 23-Oct-08 0.10 10.0 0.30 B Dry 0.19 J 17-Apr-09 0.10 10.0 ND ND ND 15-Oct-09 0.10 10.0 ND ND ND 23-Apr-10 0.10 10.0 ND ND 0.16 J 28-Oct-10 0.10 10.0 ND ND ND 19-Apr-11 0.10 10.0 ND ND ND 05-Oct-11 5.0 10.0 ND ND ND 03-Apr-12 5.0 10.0 ND ND ND 03-Oct-12 5.0 10.0 ND ND ND 23-Apr-13 5.0 10.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 6 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Thallium Feb-94 NR 1 ND NM NA Aug-94 NR 2 ND NM NA Feb-95 NR 2 ND NM NA Sep-95 NR 1 4.0 NM ND Feb-96 NR 2 NA NM ND Oct-96 NR 2 ND NM ND May-97 NR 2 ND NM ND Oct-97 NR 2 ND NM ND Apr-98 NR 2 ND NM ND Oct-98 NR 1 Dry NM ND Apr-99 NR 2 ND NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 10 ND NM ND Apr-05 NR 10 ND NM ND Oct-05 NR 10 ND NM ND 20-Apr-06 NR 10 ND NM ND 19-Oct-06 NR 10 ND NM ND 25-Apr-07 0.044 5.5 0.132 J NM ND NC2B= NE µg/L (05/01/07)17-Oct-07 2.0 2.0 ND NM ND 23-Apr-08 3.0 5.5 ND NM ND 23-Oct-08 3.0 5.5 ND Dry ND 17-Apr-09 3.0 5.5 ND ND ND 15-Oct-09 3.0 5.5 ND ND ND 23-Apr-10 3.0 5.5 ND ND ND 28-Oct-10 3.0 5.5 ND ND ND 19-Apr-11 3.0 5.5 ND ND ND 05-Oct-11 5.4 5.5 ND ND ND 03-Apr-12 5.4 5.5 ND ND ND 03-Oct-12 5.4 5.5 ND ND ND 23-Apr-13 5.4 5.5 ND ND ND Vanadium Feb-94 -80 ND NM NA Aug-94 NR 40 ND NM NA Feb-95 NR 40 ND NM NA Sep-95 NR 5 ND NM ND Feb-96 NR 5 NA NM ND Oct-96 NR 4 1.8 B NM 1.8 J May-97 NR 4 ND NM ND Oct-97 NR 4 ND NM ND Apr-98 NR 4 ND NM ND Oct-98 NR 40 Dry NM ND Apr-99 NR 20 ND NM ND Oct-99 NR 40 ND NM ND Apr-00 NR 40 ND NM ND Oct-00 NR 40 ND NM ND Apr-01 NR 40 ND NM ND Oct-01 NR 40 ND NM ND Apr-02 NR 40 ND NM ND Oct-02 NR 40 ND NM ND Apr-03 NR 40 ND NM ND Oct-03 NR 40 ND NM ND Apr-04 NR 40 ND NM ND Oct-04 NR 40 ND NM ND Apr-05 NR 40 ND NM ND Oct-05 NR 40 ND NM ND 20-Apr-06 NR 40 ND NM ND 19-Oct-06 NR 40 ND NM ND 25-Apr-07 1.0 25 ND NM ND NC2B= NE µg/L (05/01/07)17-Oct-07 2.0 10.0 ND NM ND 23-Apr-08 0.20 25.0 0.55 B NM 1.1 J 23-Oct-08 0.20 25.0 ND Dry 0.25 J 17-Apr-09 0.20 25.0 ND ND 0.22 J 15-Oct-09 0.20 25.0 0.75 B 7.9 J 0.52 J 23-Apr-10 0.20 25.0 0.54 B 0.94 B 0.64 J 28-Oct-10 0.20 25.0 3.2 J 0.24 J ND 19-Apr-11 0.20 25.0 0.74 J ND ND 05-Oct-11 5.0 25.0 ND ND ND 03-Apr-12 5.0 25.0 ND ND ND 03-Oct-12 5.0 25.0 ND ND ND 23-Apr-13 5.0 25.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 7 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Zinc Feb-94 NR 10 56 NM NA Aug-94 NR 10 40 NM NA Feb-95 NR 10 23 NM NA Sep-95 NR 10 37 NM ND Feb-96 NR 10 NA NM 65 Oct-96 NR 10 ND NM ND May-97 NR 10 23 NM 34 Oct-97 NR 10 25 NM ND Apr-98 NR 10 40 NM ND Oct-98 NR 50 Dry NM ND Apr-99 NR 20 21 NM ND Oct-99 NR 10 ND NM ND Apr-00 NR 10 ND NM ND Oct-00 NR 10 ND NM ND Apr-01 NR 10 ND NM ND Oct-01 NR 10 ND NM ND Apr-02 NR 10 ND NM ND Oct-02 NR 10 ND NM ND Apr-03 NR 10 ND NM ND Oct-03 NR 10 ND NM ND Apr-04 NR 10 ND NM ND Oct-04 NR 50 ND NM ND Apr-05 NR 50 ND NM ND Oct-05 NR 50 ND NM ND 20-Apr-06 NR 50 ND NM ND 19-Oct-06 NR 50 ND NM ND 25-Apr-07 1.0 10 ND NM ND NC2B= 50 µg/L (05/01/07)17-Oct-07 10.0 10.0 11.0 NM ND 23-Apr-08 0.40 10.0 27.7 B NM 8.3 J 23-Oct-08 0.40 10.0 6.0 B Dry 3.1 J 17-Apr-09 0.40 10.0 24.7 B 4.6 B 7.9 J 15-Oct-09 0.40 10.0 26.1 B 37.7 J 6.1 J 23-Apr-10 0.40 10.0 7.5 B 5.4 B 4.5 J 28-Oct-10 0.40 10.0 13.1 ND ND 19-Apr-11 0.40 10.0 18.1 B 4.2 B 36.8 05-Oct-11 10.0 10.0 ND ND ND 03-Apr-12 10.0 10.0 ND ND ND 03-Oct-12 10.0 10.0 ND ND 12.2 23-Apr-13 10.0 10.0 12.3 ND ND Acetone 23-Apr-08 2.2 100 14.1 J NM ND Resample 11-Jun-08 20.0 100 ND NM ND NC2B= NE µg/L (05/01/07)23-Oct-08 20.0 100 ND Dry ND 17-Apr-09 20.0 100 34.7 J ND ND 15-Oct-09 2.2 100 54.5 J 7.2 J ND 23-Apr-10 2.2 100 3.1 J ND ND 28-Oct-10 2.2 100 13.8 J ND ND 19-Apr-11 2.2 100 ND ND ND 05-Oct-11 2.2 100 2.6 J ND ND 03-Apr-12 2.2 100 ND ND ND 03-Oct-12 10.0 100 ND ND ND 23-Apr-13 10.0 100 ND ND ND 2-Butanone 17-Apr-09 0.96 100 39.6 J ND ND NC2B= NE µg/L (05/01/07)15-Oct-09 0.96 100 34.9 J ND ND 23-Apr-10 0.96 100 ND ND ND 28-Oct-10 0.96 100 4.9 J ND ND 19-Apr-11 0.96 100 ND ND ND 05-Oct-11 0.96 100 ND ND ND 03-Apr-12 0.96 100 ND ND ND 03-Oct-12 0.96 100 ND ND ND 23-Apr-13 0.96 100 ND ND ND 2-Hexanone 17-Apr-09 0.46 50.0 0.70 J ND ND NC2B= NE µg/L (05/01/07)15-Oct-09 0.46 50.0 0.88 J ND ND 23-Apr-10 0.46 50.0 ND ND ND 28-Oct-10 0.46 50.0 ND ND ND 19-Apr-11 0.46 50.0 ND ND ND 05-Oct-11 0.46 50.0 ND ND ND 03-Apr-12 0.46 50.0 ND ND ND 03-Oct-12 0.46 50.0 ND ND ND 23-Apr-13 0.46 50.0 ND ND ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 8 of 9 Joyce Engineering TABLE 5 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS DL RL SMP-1 SMP-3DateConcentrations in µg/L BlanksConstituent Toluene 25-Apr-07 0.15 1 0.31 J NM ND Resample 10-Jul-07 0.15 1 ND NM 0.39 J NC2B= 0.36 µg/L (05/01/07)17-Oct-07 0.2 1.0 ND NM ND 23-Apr-08 0.26 1.0 0.52 J NM ND Resample 11-Jun-08 0.26 1.0 1.5 NM ND Resample 16-Jul-08 0.26 1.0 ND NM 0.60 J 23-Oct-08 0.26 1.0 ND Dry ND 17-Apr-09 0.26 1.0 0.38 J ND ND 15-Oct-09 0.26 1.0 0.69 J ND ND 23-Apr-10 0.26 1.0 ND ND ND 28-Oct-10 0.26 1.0 0.36 J ND ND 19-Apr-11 0.26 1.0 ND ND ND 05-Oct-11 0.26 1.0 ND ND ND 03-Apr-12 0.26 1.0 ND ND ND 03-Oct-12 0.26 1.0 ND ND ND 23-Apr-13 0.26 1.0 ND ND ND Notes: 1. SMP-1 is located immediately downstream of the last sediment pond. 4. J = Estimated value since the concentration is below the laboratory's quantitation limit. 5. B = Reported value suspected to represent blank contamination 7. NC 2B Standard/EPA National Criteria are used to define concentration limits for constituents. 8. SMP-2 has not been sampled since April 2008 due to construction activities and monitoring point burial. 9. NM = Surface water point was not monitored. 10. NS = Not sampled. 11. NA = Not available. 12. NI = Not installed. 13. Dry = Monitoring point considered to be dry. 14. NE = Not established. 15. NR = Not reported. 6. NC 2B Standard = North Carolina 2B Surface Water Standards. The surface waters at the sampling locations are classified at Freshwater Aquatic Life and Trout Waters. 3. ND = Not detected above the laboratory reporting limit (February 1994 - October 2006). Not detected above the laboratory detection limit (April 2007 to present). 2. RL = Reporting Limit (= Pace Incorporated reporting limits for February 1994 - February 1995, Hydrogogic, Inc. reporting limits for September 1995 - February 1996, EnviroTech Mid-Atlantic Laboratories detection limits for September 1996 - April 1998, Central Virginia Laboratories and Consultants, Inc. detection limits for September 1998, Specialized Assays, Inc. detection limits for April 1999, NC PQL for September 1999 - October 2006, and NC SWSL {or lower} April 2007 to present). Transylvania County Woodruff Landfill Permit No. 88-07 Page 9 of 9 Joyce Engineering TABLE 6 SUMMARY OF HISTORICAL SURFACE WATER FIELD PARAMETERS Parameter Date SMP-1 SMP-3 pH Feb-94 5.60 NM Aug-94 6.10 NM Feb-95 5.80 NM Sep-95 6.58 NM Feb-96 NA NM Oct-96 6.20 NM May-97 6.53 NM Oct-97 6.70 NM Apr-98 6.72 NM Oct-98 Dry NM Apr-99 6.31 NM Oct-99 7.88 NM Apr-00 7.39 NM Oct-00 5.74 NM Apr-01 6.19 NM Oct-01 5.89 NM Apr-02 6.09 NM Oct-02 5.96 NM Apr-03 5.59 NM Oct-03 4.80 NM Apr-04 5.96 NM Oct-04 6.08 NM Apr-05 6.56 NM Resample Jun-05 7.00 NM Oct-05 6.50 NM 19-Apr-06 6.87 NM 19-Oct-06 6.38 NM 25-Apr-07 6.11 NM Resample 10-Jul-07 6.05 NM 17-Oct-07 6.43 NM 23-Apr-08 6.20 NM Resample 11-Jun-08 7.20 NM Resample 16-Jul-08 6.00 NM 23-Oct-08 5.81 Dry 17-Apr-09 5.94 5.86 15-Oct-09 5.99 8.41 23-Apr-10 5.59 5.54 28-Oct-10 6.80 6.94 Resample 21-Dec-10 5.63 NS 19-Apr-11 6.10 6.13 05-Oct-11 6.43 6.23 03-Apr-12 5.81 7.11 03-Oct-12 7.44 6.67 23-Apr-13 5.99 5.81 Transylvania County Woodruff Landfill Permit No. 88-07 Page 1 of 4 Joyce Engineering TABLE 6 SUMMARY OF HISTORICAL SURFACE WATER FIELD PARAMETERS Parameter Date SMP-1 SMP-3 Conductivity Feb-94 29 NM (µS/cm)Aug-94 32 NM Feb-95 22 NM Sep-95 60.2 NM Feb-96 NA NM Oct-96 50 NM May-97 23.5 NM Oct-97 70 NM Apr-98 16 NM Oct-98 Dry NM Apr-99 60.6 NM Oct-99 113 NM Apr-00 6.8 NM Oct-00 13.9 NM Apr-01 72.6 NM Oct-01 35.7 NM Apr-02 98 NM Oct-02 113.2 NM Apr-03 118.1 NM Oct-03 132.9 NM Apr-04 77.5 NM Oct-04 92 NM Apr-05 211 NM Resample Jun-05 133.7 NM Oct-05 101.8 NM 19-Apr-06 54 NM 19-Oct-06 124.00 NM 25-Apr-07 80.2 NM Resample 10-Jul-07 82.8 NM 17-Oct-07 91.0 NM 23-Apr-08 142.5 NM Resample 11-Jun-08 146.5 NM Resample 16-Jul-08 125.5 NM 23-Oct-08 86.9 Dry 17-Apr-09 192.1 19.26 15-Oct-09 198 41.7 23-Apr-10 79.8 20.7 28-Oct-10 138.0 55.8 Resample 21-Dec-10 91.8 NS 19-Apr-11 99.1 20.0 05-Oct-11 123.2 27.0 03-Apr-12 113.8 28.1 03-Oct-12 23.3 107.3 23-Apr-13 98.8 101.3 Transylvania County Woodruff Landfill Permit No. 88-07 Page 2 of 4 Joyce Engineering TABLE 6 SUMMARY OF HISTORICAL SURFACE WATER FIELD PARAMETERS Parameter Date SMP-1 SMP-3 Temperature Feb-94 10 NM (degrees C)Aug-94 17 NM Feb-95 11 NM Sep-95 20.3 NM Feb-96 NA NM Oct-96 15.0 NM May-97 19.5 NM Oct-97 17.4 NM Apr-98 21.8 NM Oct-98 Dry NM Apr-99 18.9 NM Oct-99 11.1 NM Apr-00 12.9 NM Oct-00 13.4 NM Apr-01 14.5 NM Oct-01 15.1 NM Apr-02 13.3 NM Oct-02 15.2 NM Apr-03 6.30 NM Oct-03 11.8 NM Apr-04 15.8 NM Oct-04 17.1 NM Apr-05 9.9 NM Resample Jun-05 21.4 NM Oct-05 16.9 NM 19-Apr-06 14.8 NM 19-Oct-06 18.05 NM 25-Apr-07 15.7 NM Resample 10-Jul-07 22.1 NM 17-Oct-07 14.1 NM 23-Apr-08 14.6 NM Resample 11-Jun-08 28.3 NM Resample 16-Jul-08 19.4 NM 23-Oct-08 10.8 Dry 17-Apr-09 14.8 8.9 15-Oct-09 11.5 9.3 23-Apr-10 14.4 10.8 28-Oct-10 17.8 13.9 Resample 21-Dec-10 5.9 NS 19-Apr-11 15.4 12.0 05-Oct-11 13.6 11.6 03-Apr-12 16.7 12.3 03-Oct-12 15.8 16.8 23-Apr-13 14.1 13.4 Transylvania County Woodruff Landfill Permit No. 88-07 Page 3 of 4 Joyce Engineering TABLE 6 SUMMARY OF HISTORICAL SURFACE WATER FIELD PARAMETERS Parameter Date SMP-1 SMP-3 Turbidity Oct-96 NA NM (NTUs)May-97 31.7 NM Oct-97 12.4 NM Apr-98 NA NM Oct-98 Dry NM Apr-99 15.7 NM Oct-99 48.2 NM Apr-00 18.9 NM Oct-00 8.35 NM Apr-01 10.9 NM Oct-01 10.3 NM Apr-02 12.0 NM Oct-02 37.3 NM Apr-03 NA NM Oct-03 58.4 NM Apr-04 16.0 NM Oct-04 18.92 NM Apr-05 83.9 NM Resample Jun-05 80.7 NM Oct-05 10.4 NM 19-Apr-06 9.33 NM 19-Oct-06 56.50 NM 25-Apr-07 7.99 NM Resample 10-Jul-07 52.6 NM 17-Oct-07 191 NM 23-Apr-08 14.07 NM Resample 11-Jun-08 166 NM Resample 16-Jul-08 12.89 NM 22-Oct-08 5.53 Dry 17-Apr-09 60.0 15.58 15-Oct-09 170 545 23-Apr-10 8.84 3.87 28-Oct-10 55.8 4.77 Resample 21-Dec-10 16.75 NS 19-Apr-11 28.9 4.91 05-Oct-11 9.06 10.96 03-Apr-12 4.80 5.68 03-Oct-12 6.75 21.3 23-Apr-13 10.66 20.8 Notes: 1. NS = Not sampled. 2. NM = Not required for monitoring. 3. All parameters were measured in the field. 4. NA = Not available. 5. Dry = Surface water monitoring point considered to be dry. 6. NI = Not installed. Transylvania County Woodruff Landfill Permit No. 88-07 Page 4 of 4 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)Blanks Antimony Sep-95 NR 3 187 167 NI NI ND Feb-96 NR 3 5 4 NI NI ND Oct-96 NR 1.8 30 22 NI NI ND May-97 NR 1.8 51 26 NI NI ND Apr-98 NR 1.8 44 26 NI NI ND Oct-98 NR 3 ND ND NI NI ND Apr-99 NR 2 ND ND NI NI ND Oct-99 NR 30 ND ND NI NI ND Apr-00 NR 30 ND ND NI NI ND Oct-00 NR 30 ND ND NI NI ND Apr-01 NR 30 ND ND NI NI ND Oct-01 NR 30 ND ND NI NI ND Apr-02 NR 30 ND ND NI NI ND Oct-02 NR 30 ND ND NI NI ND Apr-03 NR 30 ND ND NI NI ND Oct-03 NR 30 AB AB ND ND ND Apr-04 NR 30 AB AB ND NM ND Oct-04 NR 30 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 30 AB AB ND NM ND 20-Apr-06 NR 30 AB AB ND NM ND 19-Oct-06 NR 30 AB AB ND NM ND 25-Apr-07 0.58 6 AB AB 2.14 J NM ND 17-Oct-07 3.0 5.0 AB AB ND NM ND 23-Apr-08 2.6 6.0 AB AB ND NM ND 23-Oct-08 2.6 6.0 AB AB ND NM ND 17-Apr-09 2.6 6.0 AB AB ND NM ND 15-Oct-09 2.6 6.0 AB AB ND NM ND 23-Apr-10 2.6 6.0 AB AB 3.3 J NM ND 28-Oct-10 2.6 6.0 AB AB ND NM ND 20-Apr-11 2.6 6.0 AB AB ND NM ND 05-Oct-11 5.0 6.0 AB AB ND NM ND 04-Apr-12 5.0 6.0 AB AB ND NM ND 03-Oct-12 5.0 6.0 AB AB ND NM ND 23-Apr-13 5.0 6.0 AB AB ND NM ND Arsenic Feb-94 NR 1 NA NA NI NI NA Aug-94 NR 5 11 ND NI NI ND Feb-95 NR 5 NA NA NI NI NA Sep-95 NR 10 ND ND NI NI ND Feb-96 NR 3 12 4 NI NI ND Oct-96 NR 1.6 5.3 B 2.3 B NI NI 2.2 May-97 NR 1.6 1.7 J ND NI NI ND Apr-98 NR 1.6 ND ND NI NI ND Oct-98 NR 1 8 J 8 J NI NI ND Apr-99 NR 2.5 11 7 NI NI ND Oct-99 NR 10 ND 10 NI NI ND Apr-00 NR 10 16 J 36 J NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND 10 J NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND 13 NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND 24 ND Apr-04 NR 10 AB AB 24 NM ND Oct-04 NR 10 AB AB 22 NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB 14 NM ND 20-Apr-06 NR 10 AB AB 15.6 NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 2.0 10 AB AB ND NM 2.1 J 17-Oct-07 3.0 10.0 AB AB 12.3 NM ND 23-Apr-08 2.7 10.0 AB AB 14.4 NM ND 23-Oct-08 2.7 10.0 AB AB 8.3 B NM 4.4 J 17-Apr-09 2.7 10.0 AB AB 14.6 NM ND 15-Oct-09 2.7 10.0 AB AB 7.8 J NM ND 23-Apr-10 2.7 10.0 AB AB 41.1 NM ND 28-Oct-10 2.7 10.0 AB AB 15.9 NM ND 20-Apr-11 2.7 10.0 AB AB ND NM ND 05-Oct-11 5.0 10.0 AB AB 5.2 J NM ND 04-Apr-12 5.0 10.0 AB AB 13.5 NM ND 03-Oct-12 5.0 10.0 AB AB ND NM ND 23-Apr-13 5.0 10.0 AB AB ND NM ND Constituent Date Concentration (µg/L) Transylvania County Woodruff Landfill Permit No. 88-07 Page 1 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Barium Feb-94 NR 100 NA NA NI NI NA Aug-94 NR 100 695 ND NI NI ND Feb-95 NR 100 NA NA NI NI NA Sep-95 NR 5 778 473 NI NI ND Feb-96 NR 5 674 297 NI NI ND Oct-96 NR 0.73 660 913 NI NI ND May-97 NR 0.73 410 220 NI NI 1.3 Apr-98 NR 0.73 8 J 8 J NI NI ND Oct-98 NR 2 696 373 NI NI 109 Apr-99 NR 1.5 599 312 NI NI ND Oct-99 NR 500 840 ND NI NI ND Apr-00 NR 500 520 560 NI NI ND Oct-00 NR 500 860 600 NI NI ND Apr-01 NR 500 720 ND NI NI ND Oct-01 NR 500 880 ND NI NI ND Apr-02 NR 500 720 ND NI NI ND Oct-02 NR 500 830 ND NI NI ND Apr-03 NR 500 900 ND NI NI ND Oct-03 NR 500 AB AB ND 500 ND Apr-04 NR 500 AB AB 660 NM ND Oct-04 NR 500 AB AB 610 NM ND Apr-05 NR 500 AB AB ND NM ND Oct-05 NR 500 AB AB ND NM ND 20-Apr-06 NR 500 AB AB 584 NM ND 19-Oct-06 NR 500 AB AB ND NM ND 25-Apr-07 0.20 100 AB AB 600 NM 0.50 J 17-Oct-07 2.0 10.0 AB AB 602 NM ND 23-Apr-08 0.20 100 AB AB 422 NM 3.0 J 23-Oct-08 0.20 100 AB AB 457 NM 8.9 J 17-Apr-09 0.20 100 AB AB 347 NM 13.5 J 15-Oct-09 0.20 100 AB AB 218 NM 19.3 J 23-Apr-10 0.20 100 AB AB 819 NM 27.0 J 28-Oct-10 0.20 100 AB AB 401 NM ND 20-Apr-11 0.20 100 AB AB 223 NM 14.5 J 05-Oct-11 5.0 100 AB AB 489 NM ND 04-Apr-12 5.0 100 AB AB 479 NM ND 03-Oct-12 5.0 100 AB AB 350 NM ND 23-Apr-13 5.0 100 AB AB 380 NM ND Beryllium Sep-95 NR 1 2 2 NI NI NA Feb-96 NR 1 ND ND NI NI ND Oct-96 NR 0.15 1.6 B 2.1 NI NI 0.4 May-97 NR 0.15 0.5 J 0.5 J NI NI ND Apr-98 NR 0.15 1 J 0.7 J NI NI ND Oct-98 NR 0.2 0.4 J ND NI NI ND Apr-99 NR 0.6 ND ND NI NI ND Oct-99 NR 2 ND ND NI NI ND Apr-00 NR 2 ND ND NI NI ND Oct-00 NR 2 ND ND NI NI ND Apr-01 NR 2 ND ND NI NI ND Oct-01 NR 2 ND ND NI NI ND Apr-02 NR 2 ND ND NI NI ND Oct-02 NR 2 ND ND NI NI ND Apr-03 NR 2 ND ND NI NI ND Oct-03 NR 2 AB AB ND ND ND Apr-04 NR 2 AB AB ND NM ND Oct-04 NR 2 AB AB ND NM ND Apr-05 NR 2 AB AB ND NM ND Oct-05 NR 2 AB AB ND NM ND 20-Apr-06 NR 2 AB AB ND NM ND 19-Oct-06 NR 2 AB AB ND D NM ND 25-Apr-07 0.70 1 AB AB ND NM ND 17-Oct-07 0.1 0.3 AB AB ND NM ND 23-Apr-08 0.10 1.0 AB AB ND NM ND 23-Oct-08 0.10 1.0 AB AB ND NM ND 17-Apr-09 0.10 1.0 AB AB ND NM ND 15-Oct-09 0.10 1.0 AB AB ND NM ND 23-Apr-10 0.10 1.0 AB AB 0.72 B NM 0.17 J 28-Oct-10 0.10 1.0 AB AB ND NM ND 20-Apr-11 0.10 1.0 AB AB ND NM ND 05-Oct-11 1.0 1.0 AB AB ND NM ND 04-Apr-12 1.0 1.0 AB AB ND NM ND 03-Oct-12 1.0 1.0 AB AB ND NM ND 23-Apr-13 1.0 1.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 2 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Cadmium Feb-94 NR 1 NA NA NI NI NA Aug-94 NR 10 ND ND NI NI ND Feb-95 NR 1 NA NA NI NI NA Sep-95 NR 0.1 7.1 4.4 NI NI ND Feb-96 NR 1 ND ND NI NI ND Oct-96 NR 0.12 0.98 0.58 NI NI ND May-97 NR 0.12 1.4 0.73 NI NI ND Apr-98 NR 0.12 1.9 1.1 NI NI ND Oct-98 NR 0.1 0.6 J 0.3 J NI NI ND Apr-99 NR 0.5 ND ND NI NI ND Oct-99 NR 1 14 5 NI NI ND Apr-00 NR 1 4 J 4 J NI NI ND Oct-00 NR 1 6 4 NI NI ND Apr-01 NR 1 4.8 1.4 NI NI ND Oct-01 NR 1 4.1 2.9 NI NI ND Apr-02 NR 1 ND ND NI NI ND Oct-02 NR 1 6.4 2 NI NI ND Apr-03 NR 1 5.6 ND NI NI ND Oct-03 NR 1 AB AB ND 3.1 ND Apr-04 NR 1 AB AB ND NM ND Oct-04 NR 1 AB AB ND NM ND Apr-05 NR 1 AB AB ND NM ND Oct-05 NR 1 AB AB ND NM ND 20-Apr-06 NR 1 AB AB ND NM ND 19-Oct-06 NR 1 AB AB ND NM ND 25-Apr-07 0.50 1 AB AB ND NM ND 17-Oct-07 0.1 0.3 AB AB ND NM ND 23-Apr-08 0.50 1.0 AB AB ND NM ND 23-Oct-08 0.50 1.0 AB AB ND NM ND 17-Apr-09 0.50 1.0 AB AB ND NM ND 15-Oct-09 0.50 1.0 AB AB ND NM ND 23-Apr-10 0.50 1.0 AB AB ND NM ND 28-Oct-10 0.50 1.0 AB AB ND NM ND 20-Apr-11 0.50 1.0 AB AB ND NM ND 05-Oct-11 1.0 1.0 AB AB ND NM ND 04-Apr-12 1.0 1.0 AB AB ND NM ND 03-Oct-12 1.0 1.0 AB AB ND NM ND 23-Apr-13 1.0 1.0 AB AB ND NM ND Chromium Feb-94 NR 20 NA NA NI NI NA Aug-94 NR 20 ND ND NI NI ND Feb-95 NR 5 NA NA NI NI NA Sep-95 NR 0.1 42 20 NI NI ND Feb-96 NR 5 94 57 NI NI ND Oct-96 NR 0.92 81 92 NI NI 3.4 May-97 NR 0.92 75 50 NI NI ND Apr-98 NR 0.92 84 52 NI NI 1.6 Oct-98 NR 1 55 48 NI NI 2 Apr-99 NR 1.9 50 41 NI NI ND Oct-99 NR 10 35 36 NI NI ND Apr-00 NR 10 43 59 NI NI ND Oct-00 NR 10 42 40 NI NI ND Apr-01 NR 10 19 38 NI NI ND Oct-01 NR 10 27 33 NI NI ND Apr-02 NR 10 19 28 NI NI ND Oct-02 NR 10 19 12 NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB 12 74 ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 10 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB 55 NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 2.0 10 AB AB ND NM ND 17-Oct-07 1.0 10.0 AB AB 32.8 NM ND 23-Apr-08 0.40 10.0 AB AB 34.7 NM 1.0 J 23-Oct-08 0.40 10.0 AB AB 19.8 NM ND 17-Apr-09 0.40 10.0 AB AB 21.4 NM ND 15-Oct-09 0.40 10.0 AB AB 13.5 NM ND 23-Apr-10 0.40 10.0 AB AB 50.6 NM 0.41 J 28-Oct-10 0.40 10.0 AB AB 17.2 NM ND 20-Apr-11 0.40 10.0 AB AB 10.4 NM ND 05-Oct-11 5.0 10.0 AB AB 16.9 NM ND 04-Apr-12 5.0 10.0 AB AB 28.7 NM ND 03-Oct-12 5.0 10.0 AB AB 17.0 NM ND 23-Apr-13 5.0 10.0 AB AB 23.6 NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 3 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Cobalt Sep-95 NR 5 ND ND NI NI ND Feb-96 NR 10 31 19 NI NI ND Oct-96 NR 4.7 72 100 NI NI 5.5 May-97 NR 4.7 40 27 NI NI ND Apr-98 NR 4.7 55 34 NI NI ND Oct-98 NR 1 34 32 NI NI ND Apr-99 NR 4.6 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 14 13 NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 13 ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND 15 ND Apr-04 NR 10 AB AB 13 NM ND Oct-04 NR 10 AB AB 11 NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB 12 NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 2.0 10 AB AB 4.9 J NM ND 17-Oct-07 2.0 10.0 AB AB 10.2 NM ND 23-Apr-08 0.60 10.0 AB AB ND NM 1.5 J 23-Oct-08 0.60 10.0 AB AB 5.0 J NM 1.6 J 17-Apr-09 0.60 10.0 AB AB 25.3 NM 4.9 J 15-Oct-09 0.60 10.0 AB AB ND NM ND 23-Apr-10 0.60 10.0 AB AB 27.1 NM ND 28-Oct-10 0.60 10.0 AB AB 37.4 NM 3.2 J 20-Apr-11 0.60 10.0 AB AB 4.8 J NM ND 05-Oct-11 5.0 10.0 AB AB 6.1 J NM ND 04-Apr-12 5.0 10.0 AB AB 6.0 J NM ND 03-Oct-12 5.0 10.0 AB AB ND NM ND 23-Apr-13 5.0 10.0 AB AB 14.1 NM ND Copper Sep-95 NR 5 ND ND NI NI ND Feb-96 NR 5 ND ND NI NI ND Oct-96 NR 2.7 17 18 NI NI 2.9 May-97 NR 2.7 11 7.8 J NI NI ND Apr-98 NR 2.7 26 22 NI NI 4.2 Oct-98 NR 1 ND 2 J NI NI 79 Apr-99 NR 3.5 ND 10 NI NI ND Oct-99 NR 200 ND ND NI NI ND Apr-00 NR 200 ND ND NI NI ND Oct-00 NR 200 ND ND NI NI ND Apr-01 NR 200 ND ND NI NI ND Oct-01 NR 200 ND ND NI NI ND Apr-02 NR 200 ND ND NI NI ND Oct-02 NR 200 ND ND NI NI ND Apr-03 NR 200 ND ND NI NI ND Oct-03 NR 200 AB AB ND ND ND Apr-04 NR 200 AB AB ND NM ND Oct-04 NR 200 AB AB ND NM ND Apr-05 NR 200 AB AB ND NM ND Oct-05 NR 200 AB AB ND NM ND 20-Apr-06 NR 200 AB AB ND NM ND 19-Oct-06 NR 200 AB AB ND NM ND 25-Apr-07 0.60 10 AB AB ND NM ND 17-Oct-07 3.0 10.0 AB AB ND NM ND 23-Apr-08 0.30 10.0 AB AB ND NM ND 23-Oct-08 0.30 10.0 AB AB ND NM ND 17-Apr-09 0.30 10.0 AB AB ND NM ND 15-Oct-09 0.30 10.0 AB AB ND NM ND 23-Apr-10 0.30 10.0 AB AB 8.5 J NM ND 28-Oct-10 0.30 10.0 AB AB 3.9 J NM ND 20-Apr-11 0.30 10.0 AB AB 6.6 J NM 0.38 J 05-Oct-11 5.0 10.0 AB AB ND NM ND 04-Apr-12 5.0 10.0 AB AB ND NM ND 03-Oct-12 5.0 10.0 AB AB ND NM ND 23-Apr-13 5.0 10.0 AB AB 8.0 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 4 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Lead Feb-94 NR 1 NA NA NI NI NA Aug-94 NR 5 ND ND NI NI ND Feb-95 NR 5 NA NA NI NI NA Sep-95 NR 3 3 25 NI NI ND Feb-96 NR 3 ND ND NI NI ND Oct-96 NR 0.26 11 6.2 NI NI 0.3 May-97 NR 0.26 16 1 B NI NI 0.4 Apr-98 NR 0.26 16 35 NI NI 2.9 Oct-98 NR 1 4 J 2 J NI NI 4 Apr-99 NR 0.5 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 10 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB 14 NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 2.0 10 AB AB ND NM ND 17-Oct-07 6.0 10.0 AB AB ND NM ND 23-Apr-08 4.0 10.0 AB AB ND NM ND 23-Oct-08 4.0 10.0 AB AB ND NM ND 17-Apr-09 4.0 10.0 AB AB ND NM ND 15-Oct-09 4.0 10.0 AB AB ND NM ND 23-Apr-10 4.0 10.0 AB AB 6.8 J NM ND 28-Oct-10 4.0 10.0 AB AB ND NM ND 20-Apr-11 4.0 10.0 AB AB ND NM ND 05-Oct-11 5.0 10.0 AB AB ND NM ND 04-Apr-12 5.0 10.0 AB AB ND NM ND 03-Oct-12 5.0 10.0 AB AB ND NM ND 23-Apr-13 5.0 10.0 AB AB ND NM ND Nickel Sep-95 NR 5 73 36 NI NI ND Feb-96 NR 5 83 48 NI NI ND Oct-96 NR 3.4 140 150 NI NI ND May-97 NR 3.4 120 83 NI NI 4.5 Apr-98 NR 3.4 120 72 NI NI ND Oct-98 NR 40 60 J 70 J NI NI ND Apr-99 NR 4.5 63 41 NI NI ND Oct-99 NR 50 92 ND NI NI ND Apr-00 NR 50 57 ND NI NI ND Oct-00 NR 50 59 58 NI NI ND Apr-01 NR 50 ND ND NI NI ND Oct-01 NR 50 61 56 NI NI ND Apr-02 NR 50 ND ND NI NI ND Oct-02 NR 50 ND ND NI NI ND Apr-03 NR 50 ND ND NI NI ND Oct-03 NR 50 AB AB ND 79 ND Apr-04 NR 50 AB AB 56 NM ND Oct-04 NR 50 AB AB 55 NM ND Apr-05 NR 50 AB AB ND NM ND Oct-05 NR 50 AB AB ND NM ND 20-Apr-06 NR 50 AB AB ND NM ND 19-Oct-06 NR 50 AB AB ND NM ND 25-Apr-07 2.0 50 AB AB 25.1 J NM ND 17-Oct-07 2.0 10.0 AB AB 35.1 NM ND 23-Apr-08 1.7 50.0 AB AB 21.6 J NM ND 23-Oct-08 1.7 50.0 AB AB 23.0 J NM ND 17-Apr-09 1.7 50.0 AB AB 16.7 J NM 3.3 J 15-Oct-09 1.7 50.0 AB AB 15.7 J NM 2.0 J 23-Apr-10 1.7 50.0 AB AB 28.1 J NM ND 28-Oct-10 1.7 50.0 AB AB 12.8 J NM ND 20-Apr-11 1.7 50.0 AB AB 10.4 B NM 5.8 J 05-Oct-11 5.0 50.0 AB AB 18.4 J NM ND 04-Apr-12 5.0 50.0 AB AB 20.8 J NM ND 03-Oct-12 5.0 50.0 AB AB 17.2 J NM ND 23-Apr-13 5.0 50.0 AB AB 23.6 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 5 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Selenium Feb-94 NR 1 NA NA NI NI NA Aug-94 NR 5 ND ND NI NI ND Feb-95 NR 5 NA NA NI NI NA Sep-95 NR 10 ND ND NI NI ND Feb-96 NR 3 ND ND NI NI ND Oct-96 NR 2.3 ND ND NI NI ND May-97 NR 2.3 ND 2.7 J NI NI ND Apr-98 NR 2.3 ND ND NI NI ND Oct-98 NR 1 ND ND NI NI ND Apr-99 NR 2.4 25 16 NI NI ND Oct-99 NR 20 30 ND NI NI ND Apr-00 NR 20 ND ND NI NI ND Oct-00 NR 20 ND ND NI NI ND Apr-01 NR 20 ND ND NI NI ND Oct-01 NR 20 ND ND NI NI ND Apr-02 NR 20 ND ND NI NI ND Oct-02 NR 20 ND ND NI NI ND Apr-03 NR 20 ND ND NI NI ND Oct-03 NR 20 AB AB ND ND ND Apr-04 NR 20 AB AB ND NM ND Oct-04 NR 20 AB AB ND NM ND Apr-05 NR 20 AB AB ND NM ND Oct-05 NR 20 AB AB ND NM ND 20-Apr-06 NR 20 AB AB ND NM ND 19-Oct-06 NR 20 AB AB ND D NM ND 25-Apr-07 2.0 10 AB AB ND NM ND 17-Oct-07 2.0 10.0 AB AB ND NM ND 23-Apr-08 3.8 10.0 AB AB ND NM ND 23-Oct-08 3.8 10.0 AB AB ND NM ND 17-Apr-09 3.8 10.0 AB AB ND NM ND 15-Oct-09 3.8 10.0 AB AB ND NM ND 23-Apr-10 3.8 10.0 AB AB ND NM ND 28-Oct-10 3.8 10.0 AB AB ND NM ND 20-Apr-11 3.8 10.0 AB AB ND NM ND 05-Oct-11 10.0 10.0 AB AB ND NM ND 04-Apr-12 10.0 10.0 AB AB ND NM ND 03-Oct-12 10.0 10.0 AB AB ND NM ND 23-Apr-13 10.0 10.0 AB AB ND NM ND Silver Feb-94 NR 10 NA NA NI NI NA Aug-94 NR 10 ND ND NI NI ND Feb-95 NR 10 NA NA NI NI NA Sep-95 NR 0.2 6 4 NI NI ND Feb-96 NR 1 ND ND NI NI ND Oct-96 NR 4.6 22 B 24 B NI NI 5 May-97 NR 4.6 14 11 NI NI ND Apr-98 NR 4.6 18 15 NI NI ND Oct-98 NR 0.2 ND ND NI NI ND Apr-99 NR 0.6 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 10 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB ND NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 2.0 10 AB AB ND NM ND 17-Oct-07 2.0 10.0 AB AB ND NM ND 23-Apr-08 0.10 10.0 AB AB 1.1 J NM 0.11 J 23-Oct-08 0.10 10.0 AB AB 1.6 J NM 0.19 J 17-Apr-09 0.10 10.0 AB AB 0.26 J NM ND 15-Oct-09 0.10 10.0 AB AB 0.45 J NM ND 23-Apr-10 0.10 10.0 AB AB ND NM 0.16 J 28-Oct-10 0.10 10.0 AB AB ND NM ND 20-Apr-11 0.10 10.0 AB AB 0.10 J NM ND 05-Oct-11 5.0 10.0 AB AB ND NM ND 04-Apr-12 5.0 10.0 AB AB ND NM ND 03-Oct-12 5.0 10.0 AB AB ND NM ND 23-Apr-13 5.0 10.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 6 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Thallium Sep-95 NR 1 53 22 NI NI ND Feb-96 NR 2 ND ND NI NI ND Oct-96 NR 1.6 ND ND NI NI ND May-97 NR 1.6 5.6 ND NI NI ND Apr-98 NR 1.6 ND ND NI NI ND Oct-98 NR 1 ND ND NI NI ND Apr-99 NR 0.4 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 10 AB AB ND NM ND Apr-05 NR 2 AB AB ND NM ND Oct-05 NR 10 AB AB 13 NM ND 20-Apr-06 NR 10 AB AB 26.9 NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 0.044 5.5 AB AB ND NM ND 17-Oct-07 2.0 2.0 AB AB ND NM ND 23-Apr-08 3.0 5.5 AB AB ND NM ND 23-Oct-08 3.0 5.5 AB AB ND NM ND 17-Apr-09 3.0 5.5 AB AB ND NM ND 15-Oct-09 3.0 5.5 AB AB ND NM ND 23-Apr-10 3.0 5.5 AB AB 9.3 NM ND 28-Oct-10 3.0 5.5 AB AB ND NM ND 20-Apr-11 3.0 5.5 AB AB ND NM ND 05-Oct-11 5.4 5.5 AB AB ND NM ND 04-Apr-12 5.4 5.5 AB AB ND NM ND 03-Oct-12 5.4 5.5 AB AB ND NM ND 23-Apr-13 5.4 5.5 AB AB ND NM ND Vanadium Sep-95 NR 5 13 18 NI NI ND Feb-96 NR 5 18 8 NI NI ND Oct-96 NR 1.4 110 120 NI NI 1.8 May-97 NR 1.4 58 70 NI NI ND Apr-98 NR 1.4 170 63 NI NI ND Oct-98 NR 4 ND ND NI NI ND Apr-99 NR 4.8 ND ND NI NI ND Oct-99 NR 40 ND ND NI NI ND Apr-00 NR 40 ND ND NI NI ND Oct-00 NR 40 ND ND NI NI ND Apr-01 NR 40 ND ND NI NI ND Oct-01 NR 40 ND ND NI NI ND Apr-02 NR 40 ND ND NI NI ND Oct-02 NR 40 ND ND NI NI ND Apr-03 NR 40 ND ND NI NI ND Oct-03 NR 40 AB AB ND ND ND Apr-04 NR 40 AB AB ND NM ND Oct-04 NR 40 AB AB ND NM ND Apr-05 NR 40 AB AB ND NM ND Oct-05 NR 40 AB AB ND NM ND 20-Apr-06 NR 40 AB AB ND NM ND 19-Oct-06 NR 40 AB AB ND NM ND 25-Apr-07 1.0 25 AB AB ND NM ND 17-Oct-07 2.0 10.0 AB AB 6.2 J NM ND 23-Apr-08 0.20 25.0 AB AB 5.2 B NM 1.1 J 23-Oct-08 0.20 25.0 AB AB 2.3 J NM 0.25 J 17-Apr-09 0.20 25.0 AB AB 3.3 J NM 0.22 J 15-Oct-09 0.20 25.0 AB AB 2.4 B NM 0.52 J 23-Apr-10 0.20 25.0 AB AB 18.8 J NM 0.64 J 28-Oct-10 0.20 25.0 AB AB 5.9 J NM ND 20-Apr-11 0.20 25.0 AB AB ND NM ND 05-Oct-11 5.0 25.0 AB AB ND NM ND 04-Apr-12 5.0 25.0 AB AB ND NM ND 03-Oct-12 5.0 25.0 AB AB ND NM ND 23-Apr-13 5.0 25.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 7 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Zinc Sep-95 NR 10 5,182 2,722 NI NI ND Feb-96 NR 10 4,613 2,412 NI NI 65 Oct-96 NR 2.3 3,200 3,800 NI NI ND May-97 NR 2.3 3,500 520 NI NI 34 Apr-98 NR 2.3 4,600 1,300 NI NI 4.7 Oct-98 NR 5 1,750 791 NI NI ND Apr-99 NR 4.4 1,990 646 NI NI ND Oct-99 NR 50 710 140 NI NI ND Apr-00 NR 50 1,200 1,300 NI NI ND Oct-00 NR 50 470 350 NI NI ND Apr-01 NR 50 530 240 NI NI ND Oct-01 NR 50 240 140 NI NI ND Apr-02 NR 50 180 160 NI NI ND Oct-02 NR 50 160 100 NI NI ND Apr-03 NR 50 250 150 NI NI ND Oct-03 NR 50 AB AB 120 240 ND Apr-04 NR 50 AB AB 100 NM ND Oct-04 NR 50 AB AB 65 NM ND Apr-05 NR 50 AB AB ND NM ND Oct-05 NR 50 AB AB 170 NM ND 20-Apr-06 NR 50 AB AB ND NM ND 19-Oct-06 NR 50 AB AB 194 NM ND 25-Apr-07 1.0 10 AB AB ND NM ND 17-Oct-07 10.0 10.0 AB AB 16.2 NM ND 23-Apr-08 0.40 10.0 AB AB 56.0 NM 8.3 J 23-Oct-08 0.40 10.0 AB AB 7.5 B NM 3.1 J 17-Apr-09 0.40 10.0 AB AB 45.5 NM 7.9 J 15-Oct-09 0.40 10.0 AB AB 29.5 B NM 6.1 J 23-Apr-10 0.40 10.0 AB AB 464 NM 4.5 J 28-Oct-10 0.40 10.0 AB AB 95.6 NM ND 20-Apr-11 0.40 10.0 AB AB 68.1 B NM 36.8 05-Oct-11 10.0 10.0 AB AB 28.3 NM ND 04-Apr-12 10.0 10.0 AB AB 17.9 NM ND 03-Oct-12 10.0 10.0 AB AB 16.7 B NM 12.2 23-Apr-13 10.0 10.0 AB AB 107 NM ND BOD May-97 -2,000 7,200 8,100 NI NI NA Oct-97 NR 2,000 ND ND NI NI NA Apr-98 NR 2,000 9,900,000 9,300,000 NI NI NA Oct-98 NR 2,000 3,200,000 2,800,000 NI NI NA Apr-99 NR 2,000 2,510,000 1,280,000 NI NI NA Oct-99 NR 2,000 1,800,000 1,200,000 NI NI NA Apr-00 NR 2,000 220,000 210,000 NI NI NA Oct-00 NR 2,000 NA NA NI NI NA Apr-01 NR 2,000 120,000 190,000 NI NI NA Oct-01 NR NR 72,000 69,000 NI NI NA Apr-02 NR 2,000 120,000 120,000 NI NI NA Oct-02 NR 2,000 42,000 20,000 NI NI NA Apr-03 NR 2,000 150,000 69,000 NI NI NA Oct-03 NR 2,000 AB AB 66,000 340,000 J NA Apr-04 NR 2,000 AB AB 36,000 NM ND Oct-04 NR 2,000 AB AB 45,000 NM ND Apr-05 NR 2,000 AB AB 19,100 NM ND Oct-05 NR 2,000 AB AB 97,100 NM ND 20-Apr-06 NR 2,000 AB AB 21,000 NM NA 19-Oct-06 NR 2,000 AB AB 1,050,000 NM NA 25-Apr-07 2000 2,000 AB AB 310,000 NM ND 17-Oct-07 39,300 39300 AB AB ND NM ND 23-Apr-08 NR 2,000 AB AB 314,000 NM ND 23-Oct-08 NR 2,000 AB AB 654,000 NM ND 17-Apr-09 2,000 2,000 AB AB 30,000 NM ND 15-Oct-09 2,000 2,000 AB AB 60,000 NM ND 23-Apr-10 2,000 2,000 AB AB 24,900 NM ND 28-Oct-10 2,000 2,000 AB AB 4,200 NM ND 20-Apr-11 2,000 2,000 AB AB 8,400 NM ND 05-Oct-11 2,000 2,000 AB AB 8,400 NM ND 04-Apr-12 2,000 2,000 AB AB 175,000 NM NM 03-Oct-12 2,000 2,000 AB AB 2,400 NM NM 23-Apr-13 2,000 2,000 AB AB 318,000 NM NM Transylvania County Woodruff Landfill Permit No. 88-07 Page 8 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) COD May-97 NR 200,000 6,800,000 4,200,000 NI NI NA Oct-97 NR 200,000 4,000,000 3,000,000 NI NI NA Apr-98 NR 400,000 480,000 310,000 NI NI NA Oct-98 NR 3,000 6,100,000 4,400,000 NI NI NA Apr-99 NR 3,000 3,760,000 1,880,000 NI NI NA Oct-99 NR 20,000 2,800,000 1,700,000 NI NI NA Apr-00 NR 5,000 1,000,000 600,000 NI NI NA Oct-00 NR 20 520,000 540,000 NI NI NA Oct-00 NR 5,000 520,000 540,000 NI NI NA Apr-01 NR 5,000 570,000 860,000 NI NI NA Oct-01 NR NR 542,000 570,000 NI NI NA Apr-02 NR 9,000 520,000 470,000 NI NI NA Oct-02 NR 40 520,000 160,000 NI NI NA Apr-03 NR 8,000 600,000 470,000 NI NI NA Oct-03 NR 8,000 AB AB 280,000 3,800,000 NA Apr-04 NR 8,000 AB AB 710,000 NM ND Oct-04 NR 10,000 AB AB 620,000 NM ND Apr-05 NR 10,000 AB AB 233,000 NM ND Oct-05 NR 10,000 AB AB 1,900,000 NM ND 20-Apr-06 NR 10,000 AB AB 529,000 NM ND 19-Oct-06 NR 10,000 AB AB 1,660,000 NM ND 25-Apr-07 20,000 20,000 AB AB 1,600,000 D NM ND 17-Oct-07 10,000 10,000 AB AB 280,000 NM ND 23-Apr-08 25,000 25,000 AB AB 556,000 NM ND 23-Oct-08 25,000 25,000 AB AB 432,000 NM ND 17-Apr-09 25,000 25,000 AB AB 348,000 NM ND 15-Oct-09 25,000 25,000 AB AB 195,000 NM ND 23-Apr-10 NR 25,000 AB AB 907,000 NM ND 28-Oct-10 25,000 25,000 AB AB 250,000 NM ND 20-Apr-11 25,000 25,000 AB AB 149,000 NM ND 05-Oct-11 25,000 25,000 AB AB 320,000 NM ND 04-Apr-12 25,000 25,000 AB AB 691,000 NM NM 03-Oct-12 25,000 25,000 AB AB 275,000 NM NM 23-Apr-13 25,000 25,000 AB AB 281,000 NM NM Nitrate as N May-97 NR 50 89 99 NI NI NA Oct-97 NR 0.1 ND ND NI NI NA Apr-98 NR 10 500 880 NI NI NA Oct-98 NR 1,000 2,100 J ND NI NI NA Apr-99 NR 100 120 ND NI NI NA Oct-99 NR 10 60 20 NI NI NA Apr-00 NR 10 90 160 NI NI NA Oct-00 NR 10 100 120 NI NI NA Oct-00 NR 10 100 120 NI NI NA Apr-01 NR 10 40 40 NI NI NA Apr-01 NR 10 40 40 NI NI NA Oct-01 NR NR ND 40 NI NI NA Apr-02 NR 10 ND ND NI NI NA Oct-02 NR 10 ND 270 NI NI NA Oct-02 NR 10 ND 390 NI NI NA Apr-03 NR 20 ND ND NI NI NA Oct-03 NR 20 AB AB 100 ND NA Apr-04 NR 60 AB AB ND NM ND Oct-04 NR 100 AB AB 1,100 NM ND Apr-05 NR 100 AB AB ND NM ND Oct-05 NR 100 AB AB ND NM ND 20-Apr-06 NR 500 AB AB ND D NM ND 19-Oct-06 NR 500 AB AB ND D NM NA 25-Apr-07 5.9 100 AB AB 8.1 J NM ND 17-Oct-07 100 100 AB AB ND NM ND 23-Apr-08 100 10,000 AB AB ND NM ND 23-Oct-08 100 10,000 AB AB ND NM ND 17-Apr-09 100 10,000 AB AB ND NM ND 15-Oct-09 100 10,000 AB AB 120 J NM ND 23-Apr-10 100 10,000 AB AB ND NM ND 28-Oct-10 100 10,000 AB AB 3,900 J NM ND 20-Apr-11 100 10,000 AB AB 6,860 J NM ND 05-Oct-11 200 10,000 AB AB ND NM ND 04-Apr-12 200 10,000 AB AB ND NM ND 03-Oct-12 200 10,000 AB AB 200 J NM ND 23-Apr-13 200 10,000 AB AB 27,200 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 9 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Phosphate May-97 NR 50 500 ND NI NI NA (as total phosphorus)Oct-97 NR 50 ND ND NI NI NA Apr-98 NR 50 340 ND NI NI NA Oct-98 NR 50 1,100 990 NI NI NA Apr-99 NR 100 700 840 NI NI NA Oct-99 NR 10 720 950 NI NI NA Apr-00 NR 10 490 760 NI NI NA Oct-00 NR 20 460 1,100 NI NI NA Oct-00 NR 10 460 1,100 NI NI NA Apr-01 NR 10 380 1,200 NI NI NA Oct-01 NR NR 890 2,050 NI NI NA Apr-02 NR 10 380 1,100 NI NI NA Oct-02 NR 10 400 280 NI NI NA Apr-03 NR 10 390 2,700 NI NI NA Oct-03 NR 10 AB AB 140 1,400 NA Apr-04 NR 20 AB AB 1,500 NM ND Oct-04 NR 20 AB AB 1,100 NM ND Apr-05 NR 30 AB AB 380 NM ND Oct-05 NR 30 AB AB 220 NM ND 20-Apr-06 NR 30 AB AB 800 NM NA 19-Oct-06 NR 30 AB AB 1,210 NM NA 25-Apr-07 20 30 AB AB 3,500 NM ND 17-Oct-07 50 50 AB AB 360 NM ND 23-Apr-08 100 100 AB AB 660 NM ND 23-Oct-08 100 100 AB AB 280 NM ND 17-Apr-09 100 100 AB AB 340 NM ND 15-Oct-09 100 100 AB AB 190 NM ND 23-Apr-10 100 100 AB AB 190 NM ND 28-Oct-10 100 100 AB AB 962 NM ND 20-Apr-11 50 50 AB AB 114 NM ND 05-Oct-11 50.0 50.0 AB AB 139 NM ND 04-Apr-12 50.0 50.0 AB AB 533 NM NM 03-Oct-12 50.0 50.0 AB AB 135 NM ND 23-Apr-13 50.0 50.0 AB AB 205 NM ND Sulfate May-97 NR 15,000 120,000 89,000 NI NI NA Oct-97 NR 8,000 66,000 65,000 NI NI NA Apr-98 NR 5,000 60,000 68,000 NI NI NA Oct-98 NR 1,000 14,000 55,000 NI NI NA Apr-99 NR 5,000 18,800 11,400 NI NI NA Oct-99 NR 8,000 ND 51,000 NI NI NA Apr-00 NR 8,000 ND 110,000 NI NI NA Oct-00 NR 5,000 ND 40,000 NI NI NA Oct-00 NR 5,000 ND 40,000 NI NI NA Apr-01 NR 2,000 ND ND NI NI NA Oct-01 NR 5,000 ND ND NI NI NA Apr-02 NR 1,000 ND 2,000 NI NI NA Oct-02 NR 1,000 ND 31,000 NI NI NA Apr-03 NR 60 ND 4,400 NI NI NA Oct-03 NR 60 AB AB 12,000 48,000 NA Apr-04 NR 600 AB AB 35,000 NM ND Oct-04 NR 2,000 AB AB 25,000 NM ND Apr-05 NR 2,000 AB AB 20,200 NM ND Oct-05 NR 2,000 AB AB 72,800 NM ND 20-Apr-06 NR 5,000 AB AB 40,000 D NM ND 19-Oct-06 NR 5,000 AB AB 120,000 D NM ND 25-Apr-07 600 5,000 AB AB 18,000 NM 2,000 J 17-Oct-07 1,000 1,000 AB AB 120,000 D NM ND 23-Apr-08 15,000 750,000 AB AB 72,300 J,D NM ND 23-Oct-08 NR NR AB AB NS NM NS 17-Apr-09 15,000 750,000 AB AB 101,000 J,D NM ND 15-Oct-09 NR NR AB AB NM NM NS 23-Apr-10 NR NR AB AB NM NM NS 28-Oct-10 15,000 15,000 AB AB 93,400 NM ND 20-Apr-11 15,000 750,000 AB AB 59,000 J,D NM ND 05-Oct-11 10,000 10,000 AB AB 56,900 D NM ND 04-Apr-12 5,000 5,000 AB AB 20,100 NM NM 03-Oct-12 2,000 250,000 AB AB ND NM ND 23-Apr-13 20,000 2,500,000 AB AB 159,000 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 10 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Acetone Sep-95 NR 100 6,340 800 NI NI NA Feb-96 NR 100 25,400 ND NI NI NA Oct-96 NR 35 5,700 1,200 NI NI ND May-97 NR 32 8,600 2,200 NI NI ND Apr-98 NR 35 9,500 1000 NI NI ND Oct-98 NR 1 5,900 ND NI NI ND Apr-99 NR 4.9 5,650 2,880 NI NI ND Oct-99 NR 100 2,400 1,100 NI NI ND Apr-00 NR 100 1,200 450 NI NI ND Oct-00 NR 100 ND ND NI NI ND Apr-01 NR 100 ND ND NI NI ND Oct-01 NR 100 ND ND NI NI ND Apr-02 NR 100 ND ND NI NI ND Oct-02 NR 100 ND ND NI NI ND Apr-03 NR 100 ND ND NI NI ND Oct-03 NR 100 AB AB ND 1,500 ND Apr-04 NR 100 AB AB ND NM ND Oct-04 NR 500 AB AB ND NM ND Apr-05 NR 100 AB AB ND NM ND Oct-05 NR 100 AB AB ND NM ND 20-Apr-06 NR 100 AB AB ND NM ND 19-Oct-06 NR 100 AB AB 2,200 D NM ND 25-Apr-07 9.0 100 AB AB 600 D NM ND 17-Oct-07 7.0 10.0 AB AB 23.7 NM ND 23-Apr-08 2.2 100 AB AB 37.3 J NM ND 23-Oct-08 20.0 100 AB AB ND NM ND 17-Apr-09 20.0 100 AB AB 34.8 J NM ND 15-Oct-09 2.2 100 AB AB 16.8 J NM ND 23-Apr-10 2.2 100 AB AB 12.3 J NM ND 28-Oct-10 2.2 100 AB AB 12.4 J NM ND 20-Apr-11 2.2 100 AB AB 13.7 J NM ND 05-Oct-11 2.2 100 AB AB 11.1 J NM ND 04-Apr-12 2.2 100 AB AB 228 NM ND 25-Oct-12 10.0 100 AB AB ND NM ND 23-Apr-13 10.0 100 AB AB 28.4 B NM 41.9 J Benzene Sep-95 NR 5 ND ND NI NI NA Feb-96 NR 5 11.3 ND NI NI NA Oct-96 NR 0.35 12 ND NI NI ND May-97 NR 0.35 13 ND NI NI ND Apr-98 NR 0.35 ND ND NI NI ND Oct-98 NR 0.1 15.9 2.4 NI NI ND Apr-99 NR 0.4 ND ND NI NI ND Oct-99 NR 5 10 ND NI NI ND Apr-00 NR 5 8.5 ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 9.2 ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 9.2 ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 1.2 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB 0.7 J NM ND 23-Apr-08 0.25 1.0 AB AB ND NM ND 23-Oct-08 0.25 1.0 AB AB ND NM ND 17-Apr-09 0.25 1.0 AB AB ND NM ND 15-Oct-09 0.25 1.0 AB AB ND NM ND 23-Apr-10 0.25 1.0 AB AB ND NM ND 28-Oct-10 0.25 1.0 AB AB ND NM ND 20-Apr-11 0.25 1.0 AB AB ND NM ND 05-Oct-11 0.25 1.0 AB AB ND NM ND 04-Apr-12 0.25 1.0 AB AB ND NM ND 25-Oct-12 0.25 1.0 AB AB ND NM ND 23-Apr-13 0.25 1.0 AB AB 0.46 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 11 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Chlorobenzene 17-Oct-07 0.1 1.0 AB AB 0.4 J NM ND 23-Apr-08 0.23 3.0 AB AB 0.44 J NM ND 23-Oct-08 0.23 3.0 AB AB ND NM ND 17-Apr-09 0.23 3.0 AB AB ND NM ND 15-Oct-09 0.23 3.0 AB AB ND NM ND 23-Apr-10 0.23 3.0 AB AB 0.23 J NM ND 28-Oct-10 0.23 3.0 AB AB ND NM ND 20-Apr-11 0.23 3.0 AB AB ND NM ND 05-Oct-11 0.23 3.0 AB AB ND NM ND 04-Apr-12 0.23 3.0 AB AB ND NM ND 25-Oct-12 0.23 3.0 AB AB ND NM ND 23-Apr-13 0.23 3.0 AB AB 0.34 J NM ND Chloroethane Sep-95 NR 10 ND ND NI NI NA Feb-96 NR 10 14.6 ND NI NI NA Oct-96 NR 2 16 ND NI NI ND May-97 NR 2 14 ND NI NI ND Apr-98 NR 2 8.8 J ND NI NI ND Oct-98 NR 0.4 11.8 ND NI NI ND Apr-99 NR 0.5 ND ND NI NI ND Oct-99 NR 10 12 ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 50 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB ND NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 4.0 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB 0.4 J NM ND 23-Apr-08 0.54 10.0 AB AB ND NM ND 23-Oct-08 0.54 10.0 AB AB ND NM ND 17-Apr-09 0.54 10.0 AB AB ND NM ND 15-Oct-09 0.54 10.0 AB AB ND NM ND 23-Apr-10 0.54 10.0 AB AB ND NM ND 28-Oct-10 0.54 10.0 AB AB ND NM ND 20-Apr-11 0.54 10.0 AB AB ND NM ND 05-Oct-11 0.54 10.0 AB AB ND NM ND 04-Apr-12 0.54 10.0 AB AB ND NM ND 25-Oct-12 0.54 10.0 AB AB ND NM ND 23-Apr-13 0.54 10.0 AB AB ND NM ND 1,2-Dichlorobenzene 23-Apr-08 0.30 5.0 AB AB 0.31 J NM ND 23-Oct-08 0.30 5.0 AB AB ND NM ND 17-Apr-09 0.30 5.0 AB AB ND NM ND 15-Oct-09 0.30 5.0 AB AB ND NM ND 23-Apr-10 0.30 5.0 AB AB ND NM ND 28-Oct-10 0.30 5.0 AB AB ND NM ND 20-Apr-11 0.30 5.0 AB AB ND NM ND 05-Oct-11 0.30 5.0 AB AB ND NM ND 04-Apr-12 0.30 5.0 AB AB ND NM ND 25-Oct-12 0.30 5.0 AB AB ND NM ND 23-Apr-13 0.30 5.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 12 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) 1,4-Dichlorobenzene Sep-95 NR 100 ND ND NI NI NA Feb-96 NR 5 6.3 ND NI NI NA Oct-96 NR 0.26 4.6 J ND NI NI ND May-97 NR 0.26 5.9 0.71 J NI NI ND Apr-98 NR 0.26 6.7 0.7 J NI NI ND Oct-98 NR 0.1 10 ND NI NI ND Apr-99 NR 0.3 ND ND NI NI ND Oct-99 NR 5 9.8 ND NI NI ND Apr-00 NR 5 7.5 ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 10 ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 12 ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB 6 NM ND 20-Apr-06 NR 5 AB AB 5 NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 1.5 10 AB AB 4.2 J,D NM ND 17-Oct-07 0.2 1.0 AB AB 2.1 NM ND 23-Apr-08 0.33 1.0 AB AB 2.8 NM ND 23-Oct-08 0.33 1.0 AB AB 1.7 NM ND 17-Apr-09 0.33 1.0 AB AB 2.5 NM ND 15-Oct-09 0.33 1.0 AB AB 1.2 NM ND 23-Apr-10 0.33 1.0 AB AB 2.7 NM ND 28-Oct-10 0.33 1.0 AB AB 1.1 NM ND 20-Apr-11 0.33 1.0 AB AB 1.4 NM ND 05-Oct-11 0.33 1.0 AB AB 1.5 NM ND 04-Apr-12 0.33 1.0 AB AB 1.7 NM ND 25-Oct-12 0.33 1.0 AB AB 1.7 NM ND 23-Apr-13 0.33 1.0 AB AB 1.4 NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 13 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) 1,1-Dichloroethane Sep-95 NR 5 ND ND NI NI NA Feb-96 NR 5 48.4 9.5 NI NI NA Oct-96 NR 0.18 38 5 NI NI ND May-97 NR 0.18 33 2.7 J NI NI ND Apr-98 NR 0.18 30 2 J NI NI ND Oct-98 NR 0.2 27.4 ND NI NI ND Apr-99 NR 0.2 ND ND NI NI ND Oct-99 NR 5 25 ND NI NI ND Apr-00 NR 5 26 ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 25 ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 24 ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 0.90 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB 0.6 J NM ND 23-Apr-08 0.32 1.0 AB AB 1.2 J NM ND 23-Oct-08 0.32 1.0 AB AB 0.53 J NM ND 17-Apr-09 0.32 5.0 AB AB 1.0 J NM ND 15-Oct-09 0.32 5.0 AB AB 0.36 J NM ND 23-Apr-10 0.32 5.0 AB AB 0.93 J NM ND 28-Oct-10 0.32 5.0 AB AB ND NM ND 20-Apr-11 0.32 5.0 AB AB 0.73 J NM ND 05-Oct-11 0.32 5.0 AB AB 0.43 J NM ND 04-Apr-12 0.32 5.0 AB AB ND NM ND 25-Oct-12 0.32 5.0 AB AB 0.41 J NM ND 23-Apr-13 0.32 5.0 AB AB ND NM ND 1,2-Dichloroethane 17-Oct-07 0.3 1.0 AB AB 0.8 J NM ND 23-Apr-08 0.30 5.0 AB AB ND NM ND 23-Oct-08 0.12 1.0 AB AB ND NM ND 17-Apr-09 0.12 1.0 AB AB ND NM ND 15-Oct-09 0.12 1.0 AB AB ND NM ND 23-Apr-10 0.12 1.0 AB AB ND NM ND 28-Oct-10 0.12 1.0 AB AB ND NM ND 20-Apr-11 0.12 1.0 AB AB ND NM ND 05-Oct-11 0.12 1.0 AB AB ND NM ND 04-Apr-12 0.12 1.0 AB AB ND NM ND 25-Oct-12 0.12 1.0 AB AB ND NM ND 23-Apr-13 0.12 1.0 AB AB ND NM ND Cis-1,2-Dichloroethylene Sep-95 NR 5 ND ND NI NI NA Feb-96 NR 5 18.9 ND NI NI NA Oct-96 NR 0.13 10 ND NI NI ND May-97 NR 0.13 9.9 ND NI NI ND Apr-98 NR 0.13 7 ND NI NI ND Oct-98 NR 0.1 6.5 ND NI NI ND Apr-99 NR 0.3 ND ND NI NI ND Oct-99 NR 5 6.1 ND NI NI ND Apr-00 NR 5 ND ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 ND ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 ND ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 6 AB AB ND NM ND 25-Apr-07 1.4 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB ND NM ND 23-Apr-08 0.19 5.0 AB AB 0.44 B NM 0.21 J 23-Oct-08 0.19 5.0 AB AB ND NM ND 17-Apr-09 0.19 5.0 AB AB ND NM ND 15-Oct-09 0.19 5.0 AB AB ND NM ND 23-Apr-10 0.19 5.0 AB AB ND NM ND 28-Oct-10 0.19 5.0 AB AB ND NM ND 20-Apr-11 0.19 5.0 AB AB ND NM ND 05-Oct-11 0.19 5.0 AB AB ND NM ND 04-Apr-12 0.19 5.0 AB AB ND NM ND 25-Oct-12 0.19 5.0 AB AB ND NM ND 23-Apr-13 0.19 5.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 14 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Trans-1,2-Dichloroethylene Sep-95 NR 5 ND ND NI NI NA Feb-96 NR 5 ND ND NI NI NA Oct-96 NR 0.4 3.9 J ND NI NI ND May-97 NR 0.4 2.5 J ND NI NI ND Apr-98 NR 0.4 2.2 J ND NI NI ND Oct-98 NR 0.1 3.9 ND NI NI ND Apr-99 NR 0.4 ND ND NI NI ND Oct-99 NR 5 6 ND NI NI ND Apr-00 NR 5 ND ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 ND ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 ND ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 1.0 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB ND NM ND 23-Apr-08 0.49 5.0 AB AB ND NM ND 23-Oct-08 0.49 5.0 AB AB ND NM ND 17-Apr-09 0.49 5.0 AB AB ND NM ND 15-Oct-09 0.49 5.0 AB AB ND NM ND 23-Apr-10 0.49 5.0 AB AB ND NM ND 28-Oct-10 0.49 5.0 AB AB ND NM ND 20-Apr-11 0.49 5.0 AB AB ND NM ND 05-Oct-11 0.49 5.0 AB AB ND NM ND 04-Apr-12 0.49 5.0 AB AB ND NM ND 25-Oct-12 0.49 5.0 AB AB ND NM ND 23-Apr-13 0.49 5.0 AB AB ND NM ND Ethylbenzene Sep-95 NR 5 53.5 ND NI NI NA Feb-96 NR 5 56 12 NI NI NA Oct-96 NR 0.56 44 2 J NI NI ND May-97 NR 0.56 44 6.2 NI NI ND Apr-98 NR 0.56 49 5.4 NI NI ND Oct-98 NR 0.1 66 7.2 NI NI ND Apr-99 NR 0.2 ND ND NI NI ND Oct-99 NR 5 62 ND NI NI ND Apr-00 NR 5 65 ND NI NI ND Oct-00 NR 5 54 ND NI NI ND Apr-01 NR 5 61 ND NI NI ND Oct-01 NR 5 48 ND NI NI ND Apr-02 NR 5 65 8 NI NI ND Oct-02 NR 5 90 ND NI NI ND Apr-03 NR 5 82 ND NI NI ND Oct-03 NR 5 AB AB ND 55 ND Apr-04 NR 5 AB AB 5.8 NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB 27 NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB 24 D NM ND 25-Apr-07 1.7 10 AB AB 4.4 J,D NM ND 17-Oct-07 0.1 1.0 AB AB 2.2 J NM ND 23-Apr-08 0.3 1.0 AB AB 0.97 J NM ND 23-Oct-08 0.3 1.0 AB AB ND NM ND 17-Apr-09 0.30 1.0 AB AB 0.90 J NM ND 15-Oct-09 0.30 1.0 AB AB ND NM ND 23-Apr-10 0.30 1.0 AB AB 0.48 J NM ND 28-Oct-10 0.30 1.0 AB AB 0.51 J NM ND 20-Apr-11 0.30 1.0 AB AB 0.30 J NM ND 05-Oct-11 0.30 1.0 AB AB ND NM ND 04-Apr-12 0.30 1.0 AB AB 4.5 NM ND 25-Oct-12 0.30 1.0 AB AB ND NM ND 23-Apr-13 0.30 1.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 15 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) 2-Hexanone Sep-95 NR 50 ND ND NI NI NA (Methyl butyl ketone)Feb-96 NR 50 ND ND NI NI NA Oct-96 NR 14 ND ND NI NI ND May-97 NR 14 47 J ND NI NI ND Apr-98 NR 14 ND ND NI NI ND Oct-98 NR 3.2 ND ND NI NI ND Apr-99 NR 2.4 ND ND NI NI ND Oct-99 NR 50 ND ND NI NI ND Apr-00 NR 50 ND ND NI NI ND Oct-00 NR 50 ND ND NI NI ND Apr-01 NR 50 ND 64 NI NI ND Oct-01 NR 50 ND ND NI NI ND Apr-02 NR 50 ND 80 NI NI ND Oct-02 NR 50 ND ND NI NI ND Apr-03 NR 50 ND ND NI NI ND Oct-03 NR 50 AB AB ND ND ND Apr-04 NR 50 AB AB ND NM ND Oct-04 NR 250 AB AB ND NM ND Apr-05 NR 50 AB AB ND NM ND Oct-05 NR 50 AB AB ND NM ND 20-Apr-06 NR 50 AB AB ND NM ND 19-Oct-06 NR 50 AB AB ND NM ND 25-Apr-07 2.4 50 AB AB 11 J,D NM ND 17-Oct-07 1.7 10.0 AB AB ND NM ND 23-Apr-08 0.46 50.0 AB AB ND NM ND 23-Oct-08 0.46 50.0 AB AB ND NM ND 17-Apr-09 0.46 50.0 AB AB ND NM ND 15-Oct-09 0.46 50.0 AB AB ND NM ND 23-Apr-10 0.46 50.0 AB AB ND NM ND 28-Oct-10 0.46 50.0 AB AB ND NM ND 20-Apr-11 0.46 50.0 AB AB ND NM ND 05-Oct-11 0.46 50.0 AB AB ND NM ND 04-Apr-12 0.46 50.0 AB AB 3.6 J,D NM ND 25-Oct-12 0.46 50.0 AB AB ND NM ND 23-Apr-13 0.46 50.0 AB AB ND NM ND Chloromethane Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 15 ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 50 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB ND NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 1.8 10 AB AB ND D NM ND 17-Oct-07 0.3 1.0 AB AB ND NM ND 23-Apr-08 0.11 1.0 AB AB ND NM ND 23-Oct-08 0.11 1.0 AB AB ND NM ND 17-Apr-09 0.11 1.0 AB AB ND NM ND 15-Oct-09 0.11 1.0 AB AB ND NM 0.25 J 23-Apr-10 0.11 1.0 AB AB ND NM ND 28-Oct-10 0.11 1.0 AB AB ND NM 0.25 J 20-Apr-11 0.11 1.0 AB AB ND NM ND 05-Oct-11 0.11 1.0 AB AB ND NM ND 04-Apr-12 0.11 1.0 AB AB ND NM ND 25-Oct-12 0.11 1.0 AB AB ND NM ND 23-Apr-13 0.11 1.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 16 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Methylene chloride Sep-95 NR 10 ND ND NI NI NA (Dichloromethane)Feb-96 NR 10 ND ND NI NI NA Oct-96 NR 2.2 27 ND NI NI ND May-97 NR 2.2 35 3.7 J NI NI ND Apr-98 NR 2.2 32 2.6 J NI NI ND Oct-98 NR 1 5 ND NI NI ND Apr-99 NR 0.4 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 50 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB 67 B NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 0.88 20 AB AB ND D NM ND 17-Oct-07 1.0 1.0 AB AB ND NM ND 23-Apr-08 0.97 2.0 AB AB ND NM ND 23-Oct-08 0.97 2.0 AB AB ND NM 2.0 17-Apr-09 0.97 2.0 AB AB ND NM ND 15-Oct-09 0.97 2.0 AB AB ND NM 1.5 J 23-Apr-10 0.97 2.0 AB AB ND NM ND 28-Oct-10 0.97 1.0 AB AB ND NM 21.9 20-Apr-11 0.97 1.0 AB AB ND NM ND 05-Oct-11 0.97 1.0 AB AB ND NM 2.5 04-Apr-12 0.97 1.0 AB AB ND NM ND 25-Oct-12 0.97 1.0 AB AB ND NM ND 23-Apr-13 0.97 1.0 AB AB ND NM 1.5 2-Butanone Sep-95 NR 100 ND ND NI NI NA (Methyl Ethyl Ketone)Feb-96 NR 100 25,400 ND NI NI NA Oct-96 NR 13 12,000 2,100 NI NI ND May-97 NR 13 17,000 4,400 NI NI ND Apr-98 NR 13 18,000 1,400 NI NI ND Oct-98 NR 1.1 12,300 3,490 NI NI ND Apr-99 NR 0.6 1,760 365 NI NI ND Oct-99 NR 100 4,500 ND NI NI ND Apr-00 NR 100 2,300 660 NI NI ND Oct-00 NR 100 ND ND NI NI ND Apr-01 NR 100 ND ND NI NI ND Oct-01 NR 100 ND ND NI NI ND Apr-02 NR 100 ND 580 NI NI ND Oct-02 NR 100 ND ND NI NI ND Apr-03 NR 100 ND ND NI NI ND Oct-03 NR 100 AB AB ND 1,200 ND Apr-04 NR 100 AB AB ND NM ND Oct-04 NR 500 AB AB 850 NM ND Apr-05 NR 100 AB AB ND NM ND Oct-05 NR 100 AB AB ND NM ND 20-Apr-06 NR 100 AB AB ND NM ND 19-Oct-06 NR 100 AB AB 2,400 D NM ND 25-Apr-07 5.6 100 AB AB 460 D NM ND 17-Oct-07 1.7 10.0 AB AB ND NM ND 23-Apr-08 0.96 100 AB AB ND NM ND 23-Oct-08 0.96 100 AB AB ND NM ND 17-Apr-09 0.96 100 AB AB 13.9 J NM ND 15-Oct-09 0.96 100 AB AB ND NM ND 23-Apr-10 0.96 100 AB AB ND NM ND 28-Oct-10 0.96 100 AB AB ND NM ND 20-Apr-11 0.96 100 AB AB ND NM ND 05-Oct-11 0.96 100 AB AB ND NM ND 04-Apr-12 0.96 100 AB AB 339 NM ND 25-Oct-12 0.96 100 AB AB ND NM ND 23-Apr-13 0.96 100 AB AB ND NM 4.5 J Transylvania County Woodruff Landfill Permit No. 88-07 Page 17 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) 4-Methyl-2-pentanone Sep-95 NR 100 ND ND NI NI NA Feb-96 NR 100 ND ND NI NI NA Oct-96 NR 11 89 14 J NI NI ND May-97 NR 11 190 35 B NI NI ND Apr-98 NR 11 180 29 J NI NI ND Oct-98 NR 0.6 159 39.8 NI NI ND Apr-99 NR 0.6 ND ND NI NI ND Oct-99 NR 100 ND ND NI NI ND Apr-00 NR 100 ND ND NI NI ND Oct-00 NR 100 ND ND NI NI ND Apr-01 NR 100 ND ND NI NI ND Oct-01 NR 100 ND ND NI NI ND Apr-02 NR 100 ND ND NI NI ND Oct-02 NR 100 ND ND NI NI ND Apr-03 NR 100 ND ND NI NI ND Oct-03 NR 100 AB AB ND ND ND Apr-04 NR 100 AB AB ND NM ND Oct-04 NR 500 AB AB ND NM ND Apr-05 NR 100 AB AB ND NM ND Oct-05 NR 100 AB AB ND NM ND 20-Apr-06 NR 100 AB AB ND NM ND 19-Oct-06 NR 100 AB AB ND NM ND 25-Apr-07 3.6 100 AB AB 9.8 J,D NM ND 17-Oct-07 1.2 10.0 AB AB ND NM ND 23-Apr-08 0.33 100 AB AB 3.8 J NM ND 23-Oct-08 0.33 100 AB AB ND NM ND 17-Apr-09 0.33 100 AB AB ND NM ND 15-Oct-09 0.33 100 AB AB ND NM ND 23-Apr-10 0.33 100 AB AB 2.1 J NM ND 28-Oct-10 0.33 100 AB AB 0.49 J NM ND 20-Apr-11 0.33 100 AB AB 6.7 J NM ND 05-Oct-11 0.33 100 AB AB ND NM ND 04-Apr-12 0.33 100 AB AB 1.3 J NM ND 25-Oct-12 0.33 100 AB AB ND NM ND 23-Apr-13 0.33 100 AB AB ND NM ND Styrene Sep-95 NR 10 ND ND NI NI NA Feb-96 NR 10 10.4 ND NI NI NA Oct-96 NR 0.23 7 ND NI NI ND May-97 NR 0.23 8 ND NI NI ND Apr-98 NR 0.23 6.7 ND NI NI ND Oct-98 NR 0.1 6.9 ND NI NI ND Apr-99 NR 0.7 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 50 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB ND NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 1.2 10 AB AB ND D NM ND 17-Oct-07 0.1 1.0 AB AB 0.3 J NM ND 23-Apr-08 0.26 1.0 AB AB ND NM ND 23-Oct-08 0.26 1.0 AB AB ND NM ND 17-Apr-09 0.26 1.0 AB AB ND NM ND 15-Oct-09 0.26 1.0 AB AB ND NM ND 23-Apr-10 0.26 1.0 AB AB ND NM ND 28-Oct-10 0.26 1.0 AB AB ND NM ND 20-Apr-11 0.26 1.0 AB AB ND NM ND 05-Oct-11 0.26 1.0 AB AB ND NM ND 04-Apr-12 0.26 1.0 AB AB ND NM ND 25-Oct-12 0.26 1.0 AB AB ND NM ND 23-Apr-13 0.26 1.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 18 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Tetrachloroethylene Sep-95 NR 5 ND ND NI NI ND Feb-96 NR 5 ND ND NI NI ND Oct-96 NR 0.34 1.4 J ND NI NI ND May-97 NR 0.34 1.4 J ND NI NI ND Apr-98 NR 0.34 1.2 J ND NI NI ND Oct-98 NR 0.1 1.3 ND NI NI ND Apr-99 NR 0.1 ND ND NI NI ND Oct-99 NR 5 ND ND NI NI ND Apr-00 NR 5 ND ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 ND ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 ND ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 2.5 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB ND NM ND 23-Apr-08 0.46 1.0 AB AB ND NM 0.85 J 23-Oct-08 0.46 1.0 AB AB ND NM ND 17-Apr-09 0.46 1.0 AB AB ND NM ND 15-Oct-09 0.46 1.0 AB AB ND NM ND 23-Apr-10 0.46 1.0 AB AB ND NM ND 28-Oct-10 0.46 1.0 AB AB ND NM ND 20-Apr-11 0.46 1.0 AB AB ND NM ND 05-Oct-11 0.46 1.0 AB AB ND NM ND 04-Apr-12 0.46 1.0 AB AB ND NM ND 25-Oct-12 0.46 1.0 AB AB ND NM ND 23-Apr-13 0.46 1.0 AB AB ND NM ND Toluene Sep-95 NR 5 767.8 56.9 NI NI NA Feb-96 NR 5 905 146 NI NI NA Oct-96 NR 1.1 490 25 NI NI ND May-97 NR 1.1 490 91 NI NI ND Apr-98 NR 1.1 380 57 NI NI ND Oct-98 NR 0.1 415 52.9 NI NI 0.3 J Apr-99 NR 0.3 330 115 NI NI ND Oct-99 NR 5 310 15 NI NI ND Apr-00 NR 5 300 28 NI NI ND Oct-00 NR 5 200 ND NI NI ND Apr-01 NR 5 200 15 NI NI ND Oct-01 NR 5 170 ND NI NI ND Apr-02 NR 5 190 24 NI NI ND Oct-02 NR 5 170 ND NI NI ND Apr-03 NR 5 140 6.9 NI NI ND Oct-03 NR 5 AB AB ND 85 ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB 35 NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB 180 D NM ND 25-Apr-07 1.5 10 AB AB 25 D NM ND 17-Oct-07 0.2 1.0 AB AB 1.7 NM ND 23-Apr-08 0.26 1.0 AB AB 1.6 NM ND 23-Oct-08 0.26 1.0 AB AB ND NM ND 17-Apr-09 0.26 1.0 AB AB 0.27 J NM ND 15-Oct-09 0.26 1.0 AB AB ND NM ND 23-Apr-10 0.26 1.0 AB AB 0.31 J NM ND 28-Oct-10 0.26 1.0 AB AB ND NM ND 20-Apr-11 0.26 1.0 AB AB ND NM ND 05-Oct-11 0.26 1.0 AB AB ND NM ND 04-Apr-12 0.26 1.0 AB AB 1.3 NM ND 25-Oct-12 0.26 1.0 AB AB ND NM ND 23-Apr-13 0.26 1.0 AB AB 0.28 J NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 19 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Trichloroethene Sep-95 NR 5 ND ND NI NI NA Feb-96 NR 5 ND ND NI NI NA Oct-96 NR 0.88 2.4 J ND NI NI ND May-97 NR 0.88 2.5 J ND NI NI ND Apr-98 NR 0.88 1.3 J ND NI NI ND Oct-98 NR 0.1 ND ND NI NI ND Apr-99 NR 0.5 ND ND NI NI ND Oct-99 NR 5 ND ND NI NI ND Apr-00 NR 5 ND ND NI NI ND Oct-00 NR 5 ND ND NI NI ND Apr-01 NR 5 ND ND NI NI ND Oct-01 NR 5 ND ND NI NI ND Apr-02 NR 5 ND ND NI NI ND Oct-02 NR 5 ND ND NI NI ND Apr-03 NR 5 ND ND NI NI ND Oct-03 NR 5 AB AB ND ND ND Apr-04 NR 5 AB AB ND NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB ND NM ND 20-Apr-06 NR 5 AB AB ND NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 2.3 10 AB AB ND D NM ND 17-Oct-07 0.2 1 AB AB ND NM ND 23-Apr-08 0.47 1.0 AB AB ND NM ND 23-Oct-08 0.47 1.0 AB AB ND NM ND 17-Apr-09 0.47 1.0 AB AB ND NM ND 15-Oct-09 0.47 1.0 AB AB ND NM ND 23-Apr-10 0.47 1.0 AB AB ND NM ND 28-Oct-10 0.47 1.0 AB AB ND NM ND 20-Apr-11 0.47 1.0 AB AB ND NM ND 05-Oct-11 0.47 1.0 AB AB ND NM ND 04-Apr-12 0.47 1.0 AB AB ND NM ND 25-Oct-12 0.47 1.0 AB AB ND NM ND 23-Apr-13 0.47 1.0 AB AB ND NM ND Vinyl chloride Sep-95 NR 10 ND ND NI NI NA Feb-96 NR 10 ND ND NI NI NA Oct-96 NR 1.3 10 ND NI NI ND May-97 NR 1.3 ND ND NI NI ND Apr-98 NR 1.3 ND ND NI NI ND Oct-98 NR 0.2 7.9 ND NI NI ND Apr-99 NR 1.4 ND ND NI NI ND Oct-99 NR 10 ND ND NI NI ND Apr-00 NR 10 ND ND NI NI ND Oct-00 NR 10 ND ND NI NI ND Apr-01 NR 10 ND ND NI NI ND Oct-01 NR 10 ND ND NI NI ND Apr-02 NR 10 ND ND NI NI ND Oct-02 NR 10 ND ND NI NI ND Apr-03 NR 10 ND ND NI NI ND Oct-03 NR 10 AB AB ND ND ND Apr-04 NR 10 AB AB ND NM ND Oct-04 NR 50 AB AB ND NM ND Apr-05 NR 10 AB AB ND NM ND Oct-05 NR 10 AB AB ND NM ND 20-Apr-06 NR 10 AB AB ND NM ND 19-Oct-06 NR 10 AB AB ND NM ND 25-Apr-07 1.5 10 AB AB ND D NM ND 17-Oct-07 0.2 1.0 AB AB 0.7 J NM ND 23-Apr-08 0.62 1.0 AB AB ND NM ND 23-Oct-08 0.62 1.0 AB AB ND NM ND 17-Apr-09 0.62 1.0 AB AB ND NM ND 15-Oct-09 0.62 1.0 AB AB ND NM ND 23-Apr-10 0.62 1.0 AB AB ND NM ND 28-Oct-10 0.62 1.0 AB AB ND NM ND 20-Apr-11 0.62 1.0 AB AB ND NM ND 05-Oct-11 0.62 1.0 AB AB ND NM ND 04-Apr-12 0.62 1.0 AB AB ND NM ND 25-Oct-12 0.62 1.0 AB AB ND NM ND 23-Apr-13 0.62 1.0 AB AB ND NM ND Transylvania County Woodruff Landfill Permit No. 88-07 Page 20 of 21 Joyce Engineering TABLE 7 SUMMARY OF HISTORICAL LEACHATE CONSTITUENTS DL RL Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4)BlanksConstituentDate Concentration (µg/L) Xylenes, total Sep-95 NR 5 167 8 NI NI NA Feb-96 NR 5 153 33.5 NI NI NA Oct-96 NR 1.8 130 4.4 J NI NI ND May-97 NR 1.8 130 18 NI NI ND Apr-98 NR 1.8 140 15 NI NI ND Oct-98 NR 0.3 187 20.4 NI NI ND Apr-99 NR 0.8 100 ND NI NI ND Oct-99 NR 5 168 5.2 NI NI ND Apr-00 NR 5 120 5.2 J NI NI ND Oct-00 NR 5 100 ND NI NI ND Apr-01 NR 5 154 8.2 NI NI ND Oct-01 NR 5 126 ND NI NI ND Apr-02 NR 5 165 21.7 NI NI ND Oct-02 NR 5 264 ND NI NI ND Apr-03 NR 5 222 7.1 NI NI ND Oct-03 NR 5 AB AB ND 148 ND Apr-04 NR 5 AB AB 37.7 NM ND Oct-04 NR 25 AB AB ND NM ND Apr-05 NR 5 AB AB ND NM ND Oct-05 NR 5 AB AB 53 NM ND 20-Apr-06 NR 5 AB AB 6.2 NM ND 19-Oct-06 NR 5 AB AB ND NM ND 25-Apr-07 2.1 10 AB AB 39 D NM ND 17-Oct-07 0.3 3.0 AB AB 5.0 NM ND 23-Apr-08 0.23 3.0 AB AB 14.7 NM ND 23-Oct-08 0.66 2.0 AB AB ND NM ND 17-Apr-09 0.66 2.0 AB AB 12.6 NM ND 15-Oct-09 0.66 2.0 AB AB ND NM ND 23-Apr-10 0.66 2.0 AB AB 3.3 NM ND 28-Oct-10 0.66 2.0 AB AB 1.6 J NM ND 20-Apr-11 0.66 2.0 AB AB 1.7 J NM ND 05-Oct-11 0.66 2.0 AB AB ND NM ND 04-Apr-12 0.66 2.0 AB AB 13.2 NM ND 25-Oct-12 0.66 5.0 AB AB 0.83 J NM ND 23-Apr-13 0.66 5.0 AB AB 0.93 J NM ND Notes: 1. Leachate was not analyzed for the full Appendix I list until September 1995. 2. The samples are identified as follows: Lagoon Inlet=LMP-2; Lagoon=LMP-1; Pump Station=LMP-4; Holding Tank=LMP-3. 3. Samples for the Appendix I list were inadvertently omitted from the October 1997 event. 6. ND = Not detected at or above the laboratory's reporting or detection limit. 7. NC SWSL = North Carolina Solid Waste Section Limits. 8. J = Estimated value since the concentration is below the laboratory quantitation limit. 9. B = value within 5 times the concentration reported in a QC blank. 10. BOD for the Oct-00 event was not obtainable due to underdepletion. 11. Lagoon In. and lagoon sampling points were replaced with pump station and holding tank during the October 2003 sampling event. 12. The Oct-03 LMP-1 BOD was overdepleted; therefore, the value is estimated. 13. All concentrations are in micrograms per liter (µg/L). 14. COD was diluted by 2x during the April 2007 sampling event. 15. D = Indicates sample was diluted. 16. Sulfate was diluted 100x during the October 2007 sampling event. 17. Sulfate was diluted 3x during the April 2008 sampling event. 18. NM = Not monitored. 19. NI = Not installed. 20. AB = Abandoned. 21. NA = Not available. 22. NR = Not reported. 23. 8260's sampled on 10/3/12 were not analyzed in hold time therefor the sample results are not reported. A resample took place on 10/25/12 and those results are reported. 5. The following April 1998 LMP-1 samples were diluted: antimony by 5:4, lead by 1:20, zinc by 1:5, nitrate as N by 1:5, and May 1997: sulfate by 1:2, phosphate by 1:5. 4. RL = Reporting Limit (= Pace Incorporated reporting limit for February 1994 - February 1995, Hydrologic, Inc. reporting limit for September 1995 - February 1996, EnviroTech Mid-Atlantic Laboratories detection limit for October 1996 - April 1998 {reporting limit for indicator parameters}, Central Virginia Laboratories and Consultants, Inc. detection limit for October 1998, Specialized Assays, Inc. detection limit for April 1999 {reporting limit for indicator parameters}, NC PQL for inorganic parameters of September 1999 - October 2006, and NC SWSL {or lower} from April 2007 to present for inorganic parameters. Transylvania County Woodruff Landfill Permit No. 88-07 Page 21 of 21 Joyce Engineering TABLE 8 SUMMARY OF HISTORICAL LEACHATE FIELD PARAMETERS Parameter Date Lagoon In. (LMP-1) Lagoon (LMP-2) Holding Tank (LMP-3) Pump Station (LMP-4) pH Feb-94 NA NA NI NI Aug-94 6.70 6.00 NI NI Feb-95 NA NA NI NI Sep-95 6.53 7.26 NI NI Feb-96 6.90 6.90 NI NI Oct-96 6.70 7.46 NI NI May-97 NA NA NI NI Oct-97 NA NA NI NI Apr-98 NA NA NI NI Oct-98 NA NA NI NI Apr-99 NA NA NI NI Oct-99 7.11 7.75 NI NI Apr-00 7.30 6.99 NI NI Oct-00 6.88 8.11 NI NI Apr-01 6.51 7.88 NI NI Oct-01 6.78 8.22 NI NI Apr-02 6.77 7.85 NI NI Oct-02 6.95 7.75 NI NI Apr-03 6.86 7.87 NI NI Oct-03 AB AB 7.14 7.25 Apr-04 AB AB 5.85 NM Oct-04 AB AB 7.91 NM Apr-05 AB AB 7.20 NM Oct-05 AB AB 7.03 NM 20-Apr-06 AB AB NA NM 18-Oct-06 AB AB 6.72 NM 25-Apr-07 AB AB 7.38 NM 17-Oct-07 AB AB 7.19 NM 23-Apr-08 AB AB 7.36 NM 23-Oct-08 AB AB 6.86 NM 17-Apr-09 AB AB 6.72 NM 15-Oct-09 AB AB 7.27 NM 23-Apr-10 AB AB 7.55 NM 28-Oct-10 AB AB 7.52 NM 20-Apr-11 AB AB 6.90 NM 5-Oct-11 AB AB 7.66 NM 4-Apr-12 AB AB 7.35 NM 3-Oct-12 AB AB 8.04 NM Resample 25-Oct-12 AB AB 7.84 NM 23-Apr-13 AB AB 7.38 NM Temperature 23-Apr-08 AB AB 18.8 NM (degrees C)23-Oct-08 AB AB 13.4 NM 17-Apr-09 AB AB 16.1 NM 15-Oct-09 AB AB 12.2 NM 23-Apr-10 AB AB 20.2 NM 28-Oct-10 AB AB 21.8 NM 20-Apr-11 AB AB 18.4 NM 5-Oct-11 AB AB 15.9 NM 4-Apr-12 AB AB 19.7 NM 3-Oct-12 AB AB 17.9 NM Resample 25-Oct-12 AB AB 17.3 NM 23-Apr-13 AB AB 18.8 NM Conductivity Feb-94 NA NA NI NI (µS/cm)Aug-94 1,300 6,200 NI NI Feb-95 NA NA NI NI Sep-95 8,254 3,194 NI NI Feb-96 6,310 3,290 NI NI Oct-96 1,780 1,860 NI NI May-97 NA NA NI NI Oct-97 NA NA NI NI Apr-98 NA NA NI NI Oct-98 NA NA NI NI Apr-99 NA NA NI NI Oct-99 8,070 3,450 NI NI Apr-00 672 519 NI NI Oct-00 5,760 2,800 NI NI Apr-01 2,760 4,590 NI NI Oct-01 6,030 4,790 NI NI Apr-02 5,720 4,170 NI NI Oct-02 5,980 1,983 NI NI Apr-03 6,810 2,830 NI NI Oct-03 AB AB 1,581 7,330 Apr-04 AB AB 7,070 NM Oct-04 AB AB 7,230 NM Apr-05 AB AB 3,250 NM Oct-05 AB AB 5,150 NM 20-Apr-06 AB AB NA NM 18-Oct-06 AB AB 2,731 NM 25-Apr-07 AB AB 5,680 NM 17-Oct-07 AB AB 5,790 NM 23-Apr-08 AB AB 5,580 NM 23-Oct-08 AB AB 4,200 NM 17-Apr-09 AB AB 3,290 NM 15-Oct-09 AB AB 2,390 NM 23-Apr-10 AB AB 3,450 NM 28-Oct-10 AB AB 2,780 NM 20-Apr-11 AB AB 2,360 NM 5-Oct-11 AB AB 4,240 NM 4-Apr-12 AB AB 4,430 NM 3-Oct-12 AB AB 2,980 NM Resample 25-Oct-12 AB AB 3,980 NM 23-Apr-13 AB AB 4,020 NM Turbidity 23-Apr-08 AB AB 73.4 NM (NTUs)23-Oct-08 AB AB 22.9 NM 17-Apr-09 AB AB 47.7 NM 15-Oct-09 AB AB 60.6 NM 23-Apr-10 AB AB 197 NM 28-Oct-10 AB AB 40.3 NM 20-Apr-11 AB AB 12.72 NM 5-Oct-11 AB AB 21.0 NM 4-Apr-12 AB AB 6.09 NM 3-Oct-12 AB AB 17.55 NM Resample 25-Oct-12 AB AB 16.15 NM 23-Apr-13 AB AB 19.89 NM Notes: 1. All parameters were measured in the field. 2. NM = Not monitored. 3. AB = Abandoned. 4. NI = Not installed. 5. NA = Not available. Transylvania County Woodruff Landfill Permit No. 88-07 Joyce Engineering Figure Figure No. 1 Site Location Map Drawing Drawing No. 1 Potentiometric Surface Contour Map Appendices Appendix 1 Laboratory Analytical Reports and Field Data Logs Appendix 1 Laboratory Analytical Reports and Field Data Logs #=CL# May 03, 2013 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92155698 92155698 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TRANSYLVANIA-WOODRUFF Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on April 24, 2013. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 1 of 48 #=CP# CERTIFICATIONS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 2 of 48 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Lab ID Sample ID Matrix Date Collected Date Received 92155698001 8807-MW1 Water 04/23/13 13:56 04/24/13 12:54 92155698002 8807-MW2 Water 04/24/13 10:15 04/24/13 12:54 92155698003 8807-MW3 Water 04/23/13 10:40 04/24/13 12:54 92155698004 8807-MW5 Water 04/23/13 14:20 04/24/13 12:54 92155698005 8807-MW6 Water 04/24/13 10:07 04/24/13 12:54 92155698006 8807-MW8 Water 04/23/13 13:10 04/24/13 12:54 92155698007 8807-MW9D Water 04/23/13 12:56 04/24/13 12:54 92155698008 8807-MW10 Water 04/23/13 10:59 04/24/13 12:54 92155698009 8807-MW11 Water 04/24/13 09:25 04/24/13 12:54 92155698010 8807-MW12S Water 04/24/13 09:45 04/24/13 12:54 92155698011 8807-MW12D Water 04/24/13 09:50 04/24/13 12:54 92155698012 8807-MW13 Water 04/24/13 09:30 04/24/13 12:54 92155698013 8807-SMP1 Water 04/23/13 14:20 04/24/13 12:54 92155698014 8807-SMP3 Water 04/23/13 11:30 04/24/13 12:54 92155698015 8807-FIELD BLANK Water 04/24/13 10:20 04/24/13 12:54 92155698016 8807-TRIP BLANK Water 04/22/13 05:30 04/24/13 12:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 3 of 48 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92155698001 8807-MW1 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698002 8807-MW2 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698003 8807-MW3 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698004 8807-MW5 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698005 8807-MW6 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698006 8807-MW8 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698007 8807-MW9D EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698008 8807-MW10 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698009 8807-MW11 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698010 8807-MW12S EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698011 8807-MW12D EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698012 8807-MW13 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698013 8807-SMP1 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698014 8807-SMP3 EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698015 8807-FIELD BLANK EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK 92155698016 8807-TRIP BLANK EPA 8260 51 PASI-CMCK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 4 of 48 #=HO# HITS ONLY Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92155698001 8807-MW1 Barium 21.6J ug/L 04/28/13 19:52100EPA 6010 Beryllium 2.9 ug/L 04/27/13 01:411.0EPA 6010 92155698002 8807-MW2 Barium 26.7J ug/L 04/28/13 19:59100EPA 6010 Cobalt 17.1 ug/L 04/27/13 01:4710.0EPA 6010 Thallium 7.4 ug/L 04/27/13 01:475.5EPA 6010 Benzene 0.56J ug/L 04/29/13 05:481.0EPA 8260 Chlorobenzene 0.27J ug/L 04/29/13 05:483.0EPA 8260 1,4-Dichlorobenzene 0.35J ug/L 04/29/13 05:481.0EPA 8260 92155698003 8807-MW3 Beryllium 2.1 ug/L 04/27/13 01:541.0EPA 6010 92155698004 8807-MW5 Zinc 10.4 ug/L 04/27/13 01:5710.0EPA 6010 92155698005 8807-MW6 Barium 15.7J ug/L 04/28/13 20:22100EPA 6010 Cobalt 8.6J ug/L 04/27/13 02:1110.0EPA 6010 92155698006 8807-MW8 Barium 21.8J ug/L 04/28/13 20:25100EPA 6010 Beryllium 1.4 ug/L 04/27/13 02:141.0EPA 6010 Cobalt 13.7 ug/L 04/27/13 02:1410.0EPA 6010 92155698007 8807-MW9D Barium 7.0J ug/L 04/28/13 20:28100EPA 6010 Beryllium 1.2 ug/L 04/27/13 02:171.0EPA 6010 Zinc 24.8 ug/L 04/27/13 02:1710.0EPA 6010 92155698008 8807-MW10 Barium 12.5J ug/L 04/28/13 20:31100EPA 6010 Beryllium 1.3 ug/L 04/27/13 02:201.0EPA 6010 92155698009 8807-MW11 Barium 21.2J ug/L 04/28/13 20:34100EPA 6010 Chromium 5.9J ug/L 04/27/13 02:2410.0EPA 6010 92155698010 8807-MW12S Barium 15.6J ug/L 04/28/13 20:38100EPA 6010 Cobalt 25.8 ug/L 04/27/13 02:2710.0EPA 6010 92155698011 8807-MW12D Barium 10.3J ug/L 04/28/13 20:41100EPA 6010 Beryllium 1.0 ug/L 04/27/13 02:301.0EPA 6010 Cobalt 9.2J ug/L 04/27/13 02:3010.0EPA 6010 92155698012 8807-MW13 Barium 18.5J ug/L 04/28/13 20:54100EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 5 of 48 #=HO# HITS ONLY Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92155698013 8807-SMP1 Barium 19.7J ug/L 04/28/13 20:57100EPA 6010 Cobalt 6.5J ug/L 04/27/13 02:3710.0EPA 6010 Zinc 12.3 ug/L 04/27/13 02:3710.0EPA 6010 92155698015 8807-FIELD BLANK Acetone 24.1J ug/L 04/29/13 09:11100EPA 8260 92155698016 8807-TRIP BLANK Acetone 41.9J ug/L 04/29/13 05:17100EPA 8260 2-Butanone (MEK)4.5J ug/L 04/29/13 05:17100EPA 8260 Methylene Chloride 1.5 ug/L 04/29/13 05:17 C91.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 6 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW1 Lab ID: 92155698001 Collected: 04/23/13 13:56 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 01:41 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 01:41 7440-38-204/25/13 12:0510.0 5.0 1 Barium 21.6J ug/L 04/28/13 19:52 7440-39-304/25/13 12:05100 5.0 1 Beryllium 2.9 ug/L 04/27/13 01:41 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 01:41 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/28/13 19:52 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 01:41 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 19:52 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 01:41 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 01:41 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 01:41 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 01:41 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 01:41 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 01:41 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 01:41 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 05:32 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 05:32 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 05:32 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 05:32 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 05:32 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 05:32 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 05:32 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 05:32 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 05:32 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 05:32 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 05:32 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 05:32 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 05:32 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 05:32 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 05:32 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 05:32 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 05:32 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 05:32 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 05:32 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 05:32 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 05:32 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 05:32 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 05:32 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 05:32 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 05:32 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 05:32 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 05:32 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 05:32 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 05:32 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 7 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW1 Lab ID: 92155698001 Collected: 04/23/13 13:56 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 05:32 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 05:32 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 05:32 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 05:32 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 05:32 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 05:32 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 05:32 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 05:32 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 05:32 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 05:32 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 05:32 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 05:32 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 05:32 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 05:32 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 05:32 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 05:32 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 05:32 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 05:32 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %04/29/13 05:32 460-00-470-130 1 Dibromofluoromethane (S)110 %04/29/13 05:32 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 05:32 17060-07-070-130 1 Toluene-d8 (S)99 %04/29/13 05:32 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 8 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW2 Lab ID: 92155698002 Collected: 04/24/13 10:15 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 01:47 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 01:47 7440-38-204/25/13 12:0510.0 5.0 1 Barium 26.7J ug/L 04/28/13 19:59 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 01:47 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 01:47 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/28/13 19:59 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 17.1 ug/L 04/27/13 01:47 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 19:59 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 01:47 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 01:47 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 01:47 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 01:47 7440-22-404/25/13 12:0510.0 5.0 1 Thallium 7.4 ug/L 04/27/13 01:47 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 01:47 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 01:47 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 05:48 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 05:48 107-13-1200 1.9 1 Benzene 0.56J ug/L 04/29/13 05:48 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 05:48 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 05:48 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 05:48 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 05:48 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 05:48 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 05:48 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 05:48 56-23-51.0 0.25 1 Chlorobenzene 0.27J ug/L 04/29/13 05:48 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 05:48 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 05:48 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 05:48 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 05:48 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 05:48 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 05:48 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 05:48 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 05:48 95-50-15.0 0.30 1 1,4-Dichlorobenzene 0.35J ug/L 04/29/13 05:48 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 05:48 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 05:48 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 05:48 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 05:48 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 05:48 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 05:48 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 05:48 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 05:48 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 05:48 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 9 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW2 Lab ID: 92155698002 Collected: 04/24/13 10:15 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 05:48 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 05:48 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 05:48 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 05:48 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 05:48 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 05:48 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 05:48 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 05:48 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 05:48 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 05:48 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 05:48 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 05:48 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 05:48 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 05:48 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 05:48 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 05:48 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 05:48 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 05:48 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %04/29/13 05:48 460-00-470-130 1 Dibromofluoromethane (S)112 %04/29/13 05:48 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)106 %04/29/13 05:48 17060-07-070-130 1 Toluene-d8 (S)103 %04/29/13 05:48 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 10 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW3 Lab ID: 92155698003 Collected: 04/23/13 10:40 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 01:54 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 01:54 7440-38-204/25/13 12:0510.0 5.0 1 Barium ND ug/L 04/28/13 20:15 7440-39-304/25/13 12:05100 5.0 1 Beryllium 2.1 ug/L 04/27/13 01:54 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 01:54 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/28/13 20:15 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 01:54 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:15 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 01:54 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 01:54 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 01:54 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 01:54 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 01:54 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 01:54 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 01:54 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 06:04 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 06:04 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 06:04 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 06:04 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 06:04 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 06:04 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 06:04 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 06:04 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 06:04 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 06:04 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 06:04 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 06:04 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 06:04 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 06:04 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 06:04 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 06:04 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 06:04 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 06:04 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 06:04 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 06:04 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 06:04 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 06:04 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 06:04 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 06:04 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 06:04 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 06:04 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 06:04 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 06:04 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 06:04 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 11 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW3 Lab ID: 92155698003 Collected: 04/23/13 10:40 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 06:04 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 06:04 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 06:04 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 06:04 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 06:04 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 06:04 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 06:04 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 06:04 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 06:04 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 06:04 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 06:04 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 06:04 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 06:04 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 06:04 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 06:04 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 06:04 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 06:04 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 06:04 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %04/29/13 06:04 460-00-470-130 1 Dibromofluoromethane (S)112 %04/29/13 06:04 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 06:04 17060-07-070-130 1 Toluene-d8 (S)103 %04/29/13 06:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 12 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW5 Lab ID: 92155698004 Collected: 04/23/13 14:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 01:57 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 01:57 7440-38-204/25/13 12:0510.0 5.0 1 Barium ND ug/L 04/28/13 20:18 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 01:57 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 01:57 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/28/13 20:18 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 01:57 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:18 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 01:57 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 01:57 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 01:57 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 01:57 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 01:57 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 01:57 7440-62-204/25/13 12:0525.0 5.0 1 Zinc 10.4 ug/L 04/27/13 01:57 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 06:19 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 06:19 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 06:19 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 06:19 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 06:19 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 06:19 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 06:19 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 06:19 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 06:19 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 06:19 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 06:19 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 06:19 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 06:19 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 06:19 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 06:19 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 06:19 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 06:19 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 06:19 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 06:19 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 06:19 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 06:19 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 06:19 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 06:19 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 06:19 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 06:19 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 06:19 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 06:19 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 06:19 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 06:19 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 13 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW5 Lab ID: 92155698004 Collected: 04/23/13 14:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 06:19 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 06:19 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 06:19 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 06:19 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 06:19 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 06:19 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 06:19 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 06:19 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 06:19 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 06:19 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 06:19 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 06:19 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 06:19 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 06:19 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 06:19 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 06:19 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 06:19 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 06:19 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %04/29/13 06:19 460-00-470-130 1 Dibromofluoromethane (S)111 %04/29/13 06:19 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 06:19 17060-07-070-130 1 Toluene-d8 (S)102 %04/29/13 06:19 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 14 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW6 Lab ID: 92155698005 Collected: 04/24/13 10:07 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:11 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:11 7440-38-204/25/13 12:0510.0 5.0 1 Barium 15.7J ug/L 04/28/13 20:22 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:11 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:11 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:11 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 8.6J ug/L 04/27/13 02:11 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:22 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:11 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:11 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:11 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:11 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:11 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:11 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:11 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 06:35 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 06:35 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 06:35 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 06:35 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 06:35 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 06:35 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 06:35 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 06:35 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 06:35 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 06:35 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 06:35 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 06:35 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 06:35 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 06:35 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 06:35 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 06:35 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 06:35 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 06:35 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 06:35 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 06:35 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 06:35 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 06:35 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 06:35 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 06:35 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 06:35 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 06:35 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 06:35 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 06:35 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 06:35 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 15 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW6 Lab ID: 92155698005 Collected: 04/24/13 10:07 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 06:35 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 06:35 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 06:35 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 06:35 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 06:35 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 06:35 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 06:35 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 06:35 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 06:35 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 06:35 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 06:35 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 06:35 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 06:35 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 06:35 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 06:35 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 06:35 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 06:35 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 06:35 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %04/29/13 06:35 460-00-470-130 1 Dibromofluoromethane (S)108 %04/29/13 06:35 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)106 %04/29/13 06:35 17060-07-070-130 1 Toluene-d8 (S)100 %04/29/13 06:35 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 16 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW8 Lab ID: 92155698006 Collected: 04/23/13 13:10 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:14 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:14 7440-38-204/25/13 12:0510.0 5.0 1 Barium 21.8J ug/L 04/28/13 20:25 7440-39-304/25/13 12:05100 5.0 1 Beryllium 1.4 ug/L 04/27/13 02:14 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:14 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:14 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 13.7 ug/L 04/27/13 02:14 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:25 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:14 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:14 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:14 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:14 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:14 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:14 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:14 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 06:51 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 06:51 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 06:51 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 06:51 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 06:51 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 06:51 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 06:51 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 06:51 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 06:51 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 06:51 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 06:51 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 06:51 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 06:51 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 06:51 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 06:51 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 06:51 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 06:51 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 06:51 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 06:51 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 06:51 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 06:51 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 06:51 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 06:51 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 06:51 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 06:51 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 06:51 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 06:51 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 06:51 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 06:51 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 17 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW8 Lab ID: 92155698006 Collected: 04/23/13 13:10 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 06:51 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 06:51 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 06:51 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 06:51 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 06:51 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 06:51 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 06:51 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 06:51 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 06:51 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 06:51 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 06:51 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 06:51 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 06:51 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 06:51 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 06:51 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 06:51 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 06:51 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 06:51 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %04/29/13 06:51 460-00-470-130 1 Dibromofluoromethane (S)112 %04/29/13 06:51 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 06:51 17060-07-070-130 1 Toluene-d8 (S)100 %04/29/13 06:51 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 18 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW9D Lab ID: 92155698007 Collected: 04/23/13 12:56 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:17 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:17 7440-38-204/25/13 12:0510.0 5.0 1 Barium 7.0J ug/L 04/28/13 20:28 7440-39-304/25/13 12:05100 5.0 1 Beryllium 1.2 ug/L 04/27/13 02:17 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:17 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:17 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:17 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:28 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:17 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:17 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:17 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:17 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:17 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:17 7440-62-204/25/13 12:0525.0 5.0 1 Zinc 24.8 ug/L 04/27/13 02:17 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 07:06 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 07:06 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 07:06 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 07:06 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 07:06 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 07:06 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 07:06 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 07:06 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 07:06 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 07:06 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 07:06 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 07:06 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 07:06 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 07:06 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 07:06 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 07:06 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 07:06 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 07:06 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 07:06 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 07:06 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 07:06 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 07:06 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 07:06 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 07:06 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 07:06 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 07:06 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 07:06 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 07:06 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 07:06 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 19 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW9D Lab ID: 92155698007 Collected: 04/23/13 12:56 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 07:06 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 07:06 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 07:06 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 07:06 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 07:06 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 07:06 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 07:06 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 07:06 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 07:06 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 07:06 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 07:06 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 07:06 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 07:06 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 07:06 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 07:06 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 07:06 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 07:06 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 07:06 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %04/29/13 07:06 460-00-470-130 1 Dibromofluoromethane (S)110 %04/29/13 07:06 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)105 %04/29/13 07:06 17060-07-070-130 1 Toluene-d8 (S)103 %04/29/13 07:06 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 20 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW10 Lab ID: 92155698008 Collected: 04/23/13 10:59 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:20 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:20 7440-38-204/25/13 12:0510.0 5.0 1 Barium 12.5J ug/L 04/28/13 20:31 7440-39-304/25/13 12:05100 5.0 1 Beryllium 1.3 ug/L 04/27/13 02:20 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:20 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:20 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:20 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:31 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:20 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:20 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:20 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:20 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:20 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:20 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:20 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 07:22 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 07:22 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 07:22 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 07:22 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 07:22 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 07:22 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 07:22 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 07:22 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 07:22 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 07:22 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 07:22 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 07:22 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 07:22 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 07:22 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 07:22 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 07:22 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 07:22 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 07:22 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 07:22 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 07:22 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 07:22 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 07:22 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 07:22 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 07:22 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 07:22 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 07:22 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 07:22 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 07:22 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 07:22 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 21 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW10 Lab ID: 92155698008 Collected: 04/23/13 10:59 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 07:22 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 07:22 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 07:22 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 07:22 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 07:22 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 07:22 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 07:22 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 07:22 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 07:22 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 07:22 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 07:22 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 07:22 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 07:22 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 07:22 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 07:22 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 07:22 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 07:22 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 07:22 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %04/29/13 07:22 460-00-470-130 1 Dibromofluoromethane (S)108 %04/29/13 07:22 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)102 %04/29/13 07:22 17060-07-070-130 1 Toluene-d8 (S)102 %04/29/13 07:22 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 22 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW11 Lab ID: 92155698009 Collected: 04/24/13 09:25 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:24 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:24 7440-38-204/25/13 12:0510.0 5.0 1 Barium 21.2J ug/L 04/28/13 20:34 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:24 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:24 7440-43-904/25/13 12:051.0 1.0 1 Chromium 5.9J ug/L 04/27/13 02:24 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:24 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:34 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:24 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:24 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:24 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:24 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:24 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:24 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:24 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 07:38 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 07:38 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 07:38 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 07:38 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 07:38 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 07:38 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 07:38 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 07:38 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 07:38 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 07:38 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 07:38 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 07:38 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 07:38 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 07:38 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 07:38 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 07:38 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 07:38 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 07:38 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 07:38 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 07:38 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 07:38 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 07:38 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 07:38 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 07:38 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 07:38 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 07:38 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 07:38 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 07:38 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 07:38 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 23 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW11 Lab ID: 92155698009 Collected: 04/24/13 09:25 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 07:38 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 07:38 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 07:38 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 07:38 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 07:38 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 07:38 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 07:38 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 07:38 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 07:38 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 07:38 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 07:38 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 07:38 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 07:38 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 07:38 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 07:38 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 07:38 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 07:38 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 07:38 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %04/29/13 07:38 460-00-470-130 1 Dibromofluoromethane (S)102 %04/29/13 07:38 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 07:38 17060-07-070-130 1 Toluene-d8 (S)101 %04/29/13 07:38 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 24 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW12S Lab ID: 92155698010 Collected: 04/24/13 09:45 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:27 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:27 7440-38-204/25/13 12:0510.0 5.0 1 Barium 15.6J ug/L 04/28/13 20:38 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:27 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:27 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:27 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 25.8 ug/L 04/27/13 02:27 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:38 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:27 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:27 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:27 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:27 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:27 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:27 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:27 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 07:53 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 07:53 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 07:53 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 07:53 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 07:53 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 07:53 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 07:53 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 07:53 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 07:53 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 07:53 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 07:53 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 07:53 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 07:53 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 07:53 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 07:53 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 07:53 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 07:53 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 07:53 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 07:53 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 07:53 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 07:53 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 07:53 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 07:53 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 07:53 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 07:53 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 07:53 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 07:53 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 07:53 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 07:53 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 25 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW12S Lab ID: 92155698010 Collected: 04/24/13 09:45 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 07:53 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 07:53 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 07:53 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 07:53 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 07:53 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 07:53 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 07:53 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 07:53 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 07:53 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 07:53 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 07:53 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 07:53 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 07:53 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 07:53 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 07:53 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 07:53 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 07:53 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 07:53 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %04/29/13 07:53 460-00-470-130 1 Dibromofluoromethane (S)110 %04/29/13 07:53 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)107 %04/29/13 07:53 17060-07-070-130 1 Toluene-d8 (S)102 %04/29/13 07:53 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 26 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW12D Lab ID: 92155698011 Collected: 04/24/13 09:50 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:30 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:30 7440-38-204/25/13 12:0510.0 5.0 1 Barium 10.3J ug/L 04/28/13 20:41 7440-39-304/25/13 12:05100 5.0 1 Beryllium 1.0 ug/L 04/27/13 02:30 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:30 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:30 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 9.2J ug/L 04/27/13 02:30 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:41 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:30 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:30 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:30 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:30 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:30 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:30 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:30 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 08:09 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 08:09 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 08:09 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 08:09 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 08:09 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 08:09 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 08:09 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 08:09 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 08:09 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 08:09 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 08:09 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 08:09 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 08:09 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 08:09 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 08:09 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 08:09 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 08:09 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 08:09 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 08:09 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 08:09 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 08:09 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 08:09 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 08:09 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 08:09 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 08:09 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 08:09 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 08:09 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 08:09 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 08:09 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 27 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW12D Lab ID: 92155698011 Collected: 04/24/13 09:50 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 08:09 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 08:09 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 08:09 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 08:09 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 08:09 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 08:09 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 08:09 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 08:09 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 08:09 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 08:09 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 08:09 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 08:09 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 08:09 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 08:09 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 08:09 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 08:09 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 08:09 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 08:09 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %04/29/13 08:09 460-00-470-130 1 Dibromofluoromethane (S)109 %04/29/13 08:09 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)103 %04/29/13 08:09 17060-07-070-130 1 Toluene-d8 (S)101 %04/29/13 08:09 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 28 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW13 Lab ID: 92155698012 Collected: 04/24/13 09:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:34 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:34 7440-38-204/25/13 12:0510.0 5.0 1 Barium 18.5J ug/L 04/28/13 20:54 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:34 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:34 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:34 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:34 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:54 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:34 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:34 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:34 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:34 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:34 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:34 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:34 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 08:25 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 08:25 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 08:25 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 08:25 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 08:25 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 08:25 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 08:25 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 08:25 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 08:25 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 08:25 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 08:25 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 08:25 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 08:25 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 08:25 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 08:25 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 08:25 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 08:25 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 08:25 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 08:25 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 08:25 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 08:25 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 08:25 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 08:25 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 08:25 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 08:25 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 08:25 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 08:25 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 08:25 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 08:25 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 29 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-MW13 Lab ID: 92155698012 Collected: 04/24/13 09:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 08:25 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 08:25 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 08:25 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 08:25 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 08:25 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 08:25 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 08:25 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 08:25 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 08:25 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 08:25 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 08:25 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 08:25 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 08:25 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 08:25 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 08:25 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 08:25 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 08:25 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 08:25 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %04/29/13 08:25 460-00-470-130 1 Dibromofluoromethane (S)112 %04/29/13 08:25 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)105 %04/29/13 08:25 17060-07-070-130 1 Toluene-d8 (S)101 %04/29/13 08:25 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 30 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-SMP1 Lab ID: 92155698013 Collected: 04/23/13 14:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:37 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:37 7440-38-204/25/13 12:0510.0 5.0 1 Barium 19.7J ug/L 04/28/13 20:57 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:37 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:37 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:37 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 6.5J ug/L 04/27/13 02:37 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 20:57 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:37 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:37 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:37 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:37 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:37 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:37 7440-62-204/25/13 12:0525.0 5.0 1 Zinc 12.3 ug/L 04/27/13 02:37 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 08:40 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 08:40 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 08:40 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 08:40 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 08:40 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 08:40 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 08:40 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 08:40 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 08:40 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 08:40 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 08:40 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 08:40 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 08:40 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 08:40 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 08:40 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 08:40 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 08:40 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 08:40 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 08:40 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 08:40 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 08:40 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 08:40 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 08:40 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 08:40 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 08:40 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 08:40 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 08:40 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 08:40 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 08:40 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 31 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-SMP1 Lab ID: 92155698013 Collected: 04/23/13 14:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 08:40 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 08:40 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 08:40 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 08:40 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 08:40 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 08:40 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 08:40 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 08:40 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 08:40 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 08:40 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 08:40 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 08:40 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 08:40 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 08:40 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 08:40 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 08:40 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 08:40 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 08:40 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %04/29/13 08:40 460-00-470-130 1 Dibromofluoromethane (S)114 %04/29/13 08:40 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)107 %04/29/13 08:40 17060-07-070-130 1 Toluene-d8 (S)103 %04/29/13 08:40 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 32 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-SMP3 Lab ID: 92155698014 Collected: 04/23/13 11:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:40 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:40 7440-38-204/25/13 12:0510.0 5.0 1 Barium ND ug/L 04/28/13 21:00 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:40 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:40 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:40 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:40 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 21:00 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:40 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:40 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:40 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:40 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:40 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:40 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:40 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone ND ug/L 04/29/13 08:56 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 08:56 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 08:56 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 08:56 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 08:56 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 08:56 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 08:56 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 08:56 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 08:56 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 08:56 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 08:56 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 08:56 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 08:56 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 08:56 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 08:56 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 08:56 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 08:56 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 08:56 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 08:56 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 08:56 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 08:56 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 08:56 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 08:56 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 08:56 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 08:56 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 08:56 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 08:56 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 08:56 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 08:56 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 33 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-SMP3 Lab ID: 92155698014 Collected: 04/23/13 11:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 08:56 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 08:56 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 08:56 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 08:56 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 08:56 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 08:56 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 08:56 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 08:56 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 08:56 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 08:56 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 08:56 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 08:56 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 08:56 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 08:56 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 08:56 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 08:56 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 08:56 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 08:56 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %04/29/13 08:56 460-00-470-130 1 Dibromofluoromethane (S)110 %04/29/13 08:56 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)104 %04/29/13 08:56 17060-07-070-130 1 Toluene-d8 (S)101 %04/29/13 08:56 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 34 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-FIELD BLANK Lab ID: 92155698015 Collected: 04/24/13 10:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 02:53 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 02:53 7440-38-204/25/13 12:0510.0 5.0 1 Barium ND ug/L 04/28/13 21:03 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 02:53 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 02:53 7440-43-904/25/13 12:051.0 1.0 1 Chromium ND ug/L 04/27/13 02:53 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt ND ug/L 04/27/13 02:53 7440-48-404/25/13 12:0510.0 5.0 1 Copper ND ug/L 04/28/13 21:03 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 02:53 7439-92-104/25/13 12:0510.0 5.0 1 Nickel ND ug/L 04/27/13 02:53 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 02:53 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 02:53 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 02:53 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 02:53 7440-62-204/25/13 12:0525.0 5.0 1 Zinc ND ug/L 04/27/13 02:53 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone 24.1J ug/L 04/29/13 09:11 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 09:11 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 09:11 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 09:11 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 09:11 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 09:11 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 09:11 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 09:11 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 09:11 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 09:11 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 09:11 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 09:11 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 09:11 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 09:11 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 09:11 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 09:11 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 09:11 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 09:11 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 09:11 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 09:11 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 09:11 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 09:11 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 09:11 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 09:11 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 09:11 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 09:11 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 09:11 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 09:11 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 09:11 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 35 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-FIELD BLANK Lab ID: 92155698015 Collected: 04/24/13 10:20 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 09:11 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 09:11 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 09:11 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 09:11 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 09:11 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 09:11 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 09:11 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 09:11 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 09:11 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 09:11 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 09:11 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 09:11 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 09:11 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 09:11 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 09:11 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 09:11 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 09:11 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/29/13 09:11 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %04/29/13 09:11 460-00-470-130 1 Dibromofluoromethane (S)108 %04/29/13 09:11 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)103 %04/29/13 09:11 17060-07-070-130 1 Toluene-d8 (S)103 %04/29/13 09:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 36 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-TRIP BLANK Lab ID: 92155698016 Collected: 04/22/13 05:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone 41.9J ug/L 04/29/13 05:17 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 05:17 107-13-1200 1.9 1 Benzene ND ug/L 04/29/13 05:17 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 05:17 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 05:17 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 05:17 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 05:17 74-83-910.0 0.29 1 2-Butanone (MEK)4.5J ug/L 04/29/13 05:17 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 05:17 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 05:17 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/29/13 05:17 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 05:17 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 05:17 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 05:17 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 05:17 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 05:17 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 05:17 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 05:17 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 05:17 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/29/13 05:17 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 05:17 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 05:17 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 05:17 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 05:17 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 05:17 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 05:17 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 05:17 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 05:17 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 05:17 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/29/13 05:17 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 05:17 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 05:17 74-88-410.0 0.32 1 Methylene Chloride 1.5 ug/L 04/29/13 05:17 75-09-2 C91.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 05:17 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 05:17 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 05:17 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 05:17 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 05:17 127-18-41.0 0.46 1 Toluene ND ug/L 04/29/13 05:17 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 05:17 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 05:17 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 05:17 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 05:17 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 05:17 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 05:17 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 05:17 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 37 of 48 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Sample: 8807-TRIP BLANK Lab ID: 92155698016 Collected: 04/22/13 05:30 Received: 04/24/13 12:54 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Xylene (Total)ND ug/L 04/29/13 05:17 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %04/29/13 05:17 460-00-470-130 1 Dibromofluoromethane (S)112 %04/29/13 05:17 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)106 %04/29/13 05:17 17060-07-070-130 1 Toluene-d8 (S)102 %04/29/13 05:17 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 38 of 48 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/13149 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92155698001, 92155698002, 92155698003, 92155698004, 92155698005, 92155698006, 92155698007, 92155698008, 92155698009, 92155698010, 92155698011, 92155698012, 92155698013, 92155698014, 92155698015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 963011 Associated Lab Samples: 92155698001, 92155698002, 92155698003, 92155698004, 92155698005, 92155698006, 92155698007, 92155698008, 92155698009, 92155698010, 92155698011, 92155698012, 92155698013, 92155698014, 92155698015 Matrix: Water Analyzed Antimony ug/L ND 6.0 04/27/13 01:33 Arsenic ug/L ND 10.0 04/27/13 01:33 Barium ug/L ND 100 04/28/13 19:46 Beryllium ug/L ND 1.0 04/27/13 01:33 Cadmium ug/L ND 1.0 04/27/13 01:33 Chromium ug/L ND 10.0 04/28/13 19:46 Cobalt ug/L ND 10.0 04/27/13 01:33 Copper ug/L ND 10.0 04/28/13 19:46 Lead ug/L ND 10.0 04/27/13 01:33 Nickel ug/L ND 50.0 04/27/13 01:33 Selenium ug/L ND 10.0 04/27/13 01:33 Silver ug/L ND 10.0 04/27/13 01:33 Thallium ug/L ND 5.5 04/27/13 01:33 Vanadium ug/L ND 25.0 04/27/13 01:33 Zinc ug/L ND 10.0 04/27/13 01:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 963012LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 489500 98 80-120 Arsenic ug/L 494500 99 80-120 Barium ug/L 488500 98 80-120 Beryllium ug/L 527500 105 80-120 Cadmium ug/L 537500 107 80-120 Chromium ug/L 495500 99 80-120 Cobalt ug/L 513500 103 80-120 Copper ug/L 484500 97 80-120 Lead ug/L 496500 99 80-120 Nickel ug/L 529500 106 80-120 Selenium ug/L 488500 98 80-120 Silver ug/L 254250 102 80-120 Thallium ug/L 444500 89 80-120 Vanadium ug/L 510500 102 80-120 Zinc ug/L 547500 109 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 39 of 48 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 963013MATRIX SPIKE SAMPLE: MSSpike Result 92155698001 Antimony ug/L 469500 94 75-125ND Arsenic ug/L 482500 96 75-125ND Barium ug/L 486500 93 75-12521.6J Beryllium ug/L 499500 99 75-1252.9 Cadmium ug/L 511500 102 75-125ND Chromium ug/L 474500 95 75-125ND Cobalt ug/L 490500 98 75-125ND Copper ug/L 468500 94 75-125ND Lead ug/L 469500 93 75-125ND Nickel ug/L 503500 101 75-125ND Selenium ug/L 469500 94 75-125ND Silver ug/L 243250 97 75-125ND Thallium ug/L 423500 84 75-125ND Vanadium ug/L 489500 98 75-125ND Zinc ug/L 528500 104 75-125ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92155698002 963014SAMPLE DUPLICATE: Antimony ug/L ND 25ND Arsenic ug/L ND 25ND Barium ug/L 26.1J 2 2526.7J Beryllium ug/L ND 25ND Cadmium ug/L ND 25ND Chromium ug/L ND 25ND Cobalt ug/L 16.6 3 2517.1 Copper ug/L ND 25ND Lead ug/L ND 25ND Nickel ug/L ND 25ND Selenium ug/L ND 25ND Silver ug/L ND 25ND Thallium ug/L ND 257.4 Vanadium ug/L ND 25ND Zinc ug/L ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 40 of 48 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/22790 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92155698001, 92155698002, 92155698003, 92155698004, 92155698005, 92155698006, 92155698007, 92155698008, 92155698009, 92155698010, 92155698011, 92155698012, 92155698013, 92155698014, 92155698015, 92155698016 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 964654 Associated Lab Samples: 92155698001, 92155698002, 92155698003, 92155698004, 92155698005, 92155698006, 92155698007, 92155698008, 92155698009, 92155698010, 92155698011, 92155698012, 92155698013, 92155698014, 92155698015, 92155698016 Matrix: Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 04/28/13 23:50 1,1,1-Trichloroethane ug/L ND 1.0 04/28/13 23:50 1,1,2,2-Tetrachloroethane ug/L ND 3.0 04/28/13 23:50 1,1,2-Trichloroethane ug/L ND 1.0 04/28/13 23:50 1,1-Dichloroethane ug/L ND 5.0 04/28/13 23:50 1,1-Dichloroethene ug/L ND 5.0 04/28/13 23:50 1,2,3-Trichloropropane ug/L ND 1.0 04/28/13 23:50 1,2-Dibromo-3-chloropropane ug/L ND 13.0 04/28/13 23:50 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/28/13 23:50 1,2-Dichlorobenzene ug/L ND 5.0 04/28/13 23:50 1,2-Dichloroethane ug/L ND 1.0 04/28/13 23:50 1,2-Dichloropropane ug/L ND 1.0 04/28/13 23:50 1,4-Dichlorobenzene ug/L ND 1.0 04/28/13 23:50 2-Butanone (MEK)ug/L ND 100 04/28/13 23:50 2-Hexanone ug/L ND 50.0 04/28/13 23:50 4-Methyl-2-pentanone (MIBK) ug/L ND 100 04/28/13 23:50 Acetone ug/L ND 100 04/28/13 23:50 Acrylonitrile ug/L ND 200 04/28/13 23:50 Benzene ug/L ND 1.0 04/28/13 23:50 Bromochloromethane ug/L ND 3.0 04/28/13 23:50 Bromodichloromethane ug/L ND 1.0 04/28/13 23:50 Bromoform ug/L ND 3.0 04/28/13 23:50 Bromomethane ug/L ND 10.0 04/28/13 23:50 Carbon disulfide ug/L ND 100 04/28/13 23:50 Carbon tetrachloride ug/L ND 1.0 04/28/13 23:50 Chlorobenzene ug/L ND 3.0 04/28/13 23:50 Chloroethane ug/L ND 10.0 04/28/13 23:50 Chloroform ug/L ND 5.0 04/28/13 23:50 Chloromethane ug/L ND 1.0 04/28/13 23:50 cis-1,2-Dichloroethene ug/L ND 5.0 04/28/13 23:50 cis-1,3-Dichloropropene ug/L ND 1.0 04/28/13 23:50 Dibromochloromethane ug/L ND 3.0 04/28/13 23:50 Dibromomethane ug/L ND 10.0 04/28/13 23:50 Ethylbenzene ug/L ND 1.0 04/28/13 23:50 Iodomethane ug/L ND 10.0 04/28/13 23:50 Methylene Chloride ug/L ND 1.0 04/28/13 23:50 Styrene ug/L ND 1.0 04/28/13 23:50 Tetrachloroethene ug/L ND 1.0 04/28/13 23:50 Toluene ug/L ND 1.0 04/28/13 23:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 41 of 48 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 964654 Associated Lab Samples: 92155698001, 92155698002, 92155698003, 92155698004, 92155698005, 92155698006, 92155698007, 92155698008, 92155698009, 92155698010, 92155698011, 92155698012, 92155698013, 92155698014, 92155698015, 92155698016 Matrix: Water Analyzed trans-1,2-Dichloroethene ug/L ND 5.0 04/28/13 23:50 trans-1,3-Dichloropropene ug/L ND 1.0 04/28/13 23:50 trans-1,4-Dichloro-2-butene ug/L ND 100 04/28/13 23:50 Trichloroethene ug/L ND 1.0 04/28/13 23:50 Trichlorofluoromethane ug/L ND 1.0 04/28/13 23:50 Vinyl acetate ug/L ND 50.0 04/28/13 23:50 Vinyl chloride ug/L ND 1.0 04/28/13 23:50 Xylene (Total)ug/L ND 5.0 04/28/13 23:50 1,2-Dichloroethane-d4 (S)%103 70-130 04/28/13 23:50 4-Bromofluorobenzene (S)%100 70-130 04/28/13 23:50 Dibromofluoromethane (S)%106 70-130 04/28/13 23:50 Toluene-d8 (S)%102 70-130 04/28/13 23:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 964655LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,1-Trichloroethane ug/L 60.950 122 70-130 1,1,2,2-Tetrachloroethane ug/L 49.850 100 70-130 1,1,2-Trichloroethane ug/L 57.650 115 70-130 1,1-Dichloroethane ug/L 60.150 120 70-130 1,1-Dichloroethene ug/L 69.7 L350139 70-132 1,2,3-Trichloropropane ug/L 54.850 110 70-130 1,2-Dibromo-3-chloropropane ug/L 49.850 100 70-130 1,2-Dibromoethane (EDB)ug/L 53.350 107 70-130 1,2-Dichlorobenzene ug/L 51.150 102 70-130 1,2-Dichloroethane ug/L 55.950 112 70-130 1,2-Dichloropropane ug/L 58.750 117 70-130 1,4-Dichlorobenzene ug/L 49.550 99 70-130 2-Butanone (MEK)ug/L 120100 120 70-145 2-Hexanone ug/L 98.3100 98 70-144 4-Methyl-2-pentanone (MIBK) ug/L 109100 109 70-140 Acetone ug/L 123100 123 50-175 Acrylonitrile ug/L 295250 118 70-143 Benzene ug/L 53.750 107 70-130 Bromochloromethane ug/L 57.850 116 70-130 Bromodichloromethane ug/L 54.250 108 70-130 Bromoform ug/L 52.650 105 70-130 Bromomethane ug/L 59.750 119 54-130 Carbon disulfide ug/L 71.1J F3,L350142 70-131 Carbon tetrachloride ug/L 57.850 116 70-132 Chlorobenzene ug/L 51.350 103 70-130 Chloroethane ug/L 74.3 L350149 64-134 Chloroform ug/L 57.150 114 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 42 of 48 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 964655LABORATORY CONTROL SAMPLE: LCSSpike Chloromethane ug/L 57.850 116 64-130 cis-1,2-Dichloroethene ug/L 56.950 114 70-131 cis-1,3-Dichloropropene ug/L 56.850 114 70-130 Dibromochloromethane ug/L 53.050 106 70-130 Dibromomethane ug/L 55.950 112 70-131 Ethylbenzene ug/L 49.950 100 70-130 Iodomethane ug/L 136100 136 49-180 Methylene Chloride ug/L 59.850 120 63-130 Styrene ug/L 50.950 102 70-130 Tetrachloroethene ug/L 52.550 105 70-130 Toluene ug/L 52.250 104 70-130 trans-1,2-Dichloroethene ug/L 58.450 117 70-130 trans-1,3-Dichloropropene ug/L 60.150 120 70-132 trans-1,4-Dichloro-2-butene ug/L 43.2J50 86 70-141 Trichloroethene ug/L 54.450 109 70-130 Trichlorofluoromethane ug/L 70.4 L350141 62-133 Vinyl acetate ug/L 109100 109 66-157 Vinyl chloride ug/L 50.450 101 69-130 Xylene (Total)ug/L 147150 98 70-130 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%100 70-130 Dibromofluoromethane (S)%104 70-130 Toluene-d8 (S)%102 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 964656MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92155698001 964657 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1-Dichloroethene ug/L 50 165 70-166164 1 3050ND82.7 82.2 Benzene ug/L 50 125 70-148125 0 3050ND62.5 62.3 Chlorobenzene ug/L 50 107 70-146107 0 3050ND53.4 53.3 Toluene ug/L 50 118 70-155114 3 3050ND58.9 57.2 Trichloroethene ug/L 50 138 69-151136 1 3050ND68.8 67.9 1,2-Dichloroethane-d4 (S) %101 70-130105 4-Bromofluorobenzene (S) %101 70-130102 Dibromofluoromethane (S) %109 70-130112 Toluene-d8 (S)%102 70-130102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 43 of 48 #=QL# QUALIFIERS Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Common Laboratory Contaminant.C9 The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the laboratory's control limits. The result is estimated.F3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.L3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 44 of 48 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92155698 TRANSYLVANIA-WOODRUFF Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92155698001 MPRP/13149 ICP/119778807-MW1 EPA 3010 EPA 6010 92155698002 MPRP/13149 ICP/119778807-MW2 EPA 3010 EPA 6010 92155698003 MPRP/13149 ICP/119778807-MW3 EPA 3010 EPA 6010 92155698004 MPRP/13149 ICP/119778807-MW5 EPA 3010 EPA 6010 92155698005 MPRP/13149 ICP/119778807-MW6 EPA 3010 EPA 6010 92155698006 MPRP/13149 ICP/119778807-MW8 EPA 3010 EPA 6010 92155698007 MPRP/13149 ICP/119778807-MW9D EPA 3010 EPA 6010 92155698008 MPRP/13149 ICP/119778807-MW10 EPA 3010 EPA 6010 92155698009 MPRP/13149 ICP/119778807-MW11 EPA 3010 EPA 6010 92155698010 MPRP/13149 ICP/119778807-MW12S EPA 3010 EPA 6010 92155698011 MPRP/13149 ICP/119778807-MW12D EPA 3010 EPA 6010 92155698012 MPRP/13149 ICP/119778807-MW13 EPA 3010 EPA 6010 92155698013 MPRP/13149 ICP/119778807-SMP1 EPA 3010 EPA 6010 92155698014 MPRP/13149 ICP/119778807-SMP3 EPA 3010 EPA 6010 92155698015 MPRP/13149 ICP/119778807-FIELD BLANK EPA 3010 EPA 6010 92155698001 MSV/227908807-MW1 EPA 8260 92155698002 MSV/227908807-MW2 EPA 8260 92155698003 MSV/227908807-MW3 EPA 8260 92155698004 MSV/227908807-MW5 EPA 8260 92155698005 MSV/227908807-MW6 EPA 8260 92155698006 MSV/227908807-MW8 EPA 8260 92155698007 MSV/227908807-MW9D EPA 8260 92155698008 MSV/227908807-MW10 EPA 8260 92155698009 MSV/227908807-MW11 EPA 8260 92155698010 MSV/227908807-MW12S EPA 8260 92155698011 MSV/227908807-MW12D EPA 8260 92155698012 MSV/227908807-MW13 EPA 8260 92155698013 MSV/227908807-SMP1 EPA 8260 92155698014 MSV/227908807-SMP3 EPA 8260 92155698015 MSV/227908807-FIELD BLANK EPA 8260 92155698016 MSV/227908807-TRIP BLANK EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/03/2013 08:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 45 of 48 Page 46 of 48 Page 47 of 48 Page 48 of 48 #=CL# May 07, 2013 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92155590 92155590 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 TRANSYLVANIA WOODRUFF LEACHATE Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on April 23, 2013. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 1 of 21 #=CP# CERTIFICATIONS Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 2 of 21 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Lab ID Sample ID Matrix Date Collected Date Received 92155590001 9704-LEACHATE Water 04/23/13 15:45 04/23/13 17:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 3 of 21 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92155590001 9704-LEACHATE EPA 6010 15 PASI-AJDA, JMW EPA 8260 51 PASI-CMCK SM 5210B 1 PASI-ALMD EPA 300.0 1 PASI-AAES EPA 353.2 1 PASI-ADMN EPA 365.1 1 PASI-AJDA SM 5220D 1 PASI-AEWS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 4 of 21 #=HO# HITS ONLY Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92155590001 9704-LEACHATE Barium 380 ug/L 04/28/13 21:19100EPA 6010 Chromium 23.6 ug/L 04/27/13 03:0910.0EPA 6010 Cobalt 14.1 ug/L 04/27/13 03:0910.0EPA 6010 Copper 8.0J ug/L 04/28/13 21:1910.0EPA 6010 Nickel 23.6J ug/L 04/27/13 03:0950.0EPA 6010 Zinc 107 ug/L 04/27/13 03:0910.0EPA 6010 Acetone 28.4J ug/L 04/29/13 00:05100EPA 8260 Benzene 0.46J ug/L 04/29/13 00:051.0EPA 8260 Chlorobenzene 0.34J ug/L 04/29/13 00:053.0EPA 8260 1,4-Dichlorobenzene 1.4 ug/L 04/29/13 00:051.0EPA 8260 Toluene 0.28J ug/L 04/29/13 00:051.0EPA 8260 Xylene (Total)0.93J ug/L 04/29/13 00:055.0EPA 8260 BOD, 5 day 318000 ug/L 04/29/13 18:592000SM 5210B Sulfate 159000J ug/L 05/03/13 10:572500000EPA 300.0 Nitrogen, Nitrate 27200J ug/L 04/25/13 01:49100000EPA 353.2 Phosphorus 205 ug/L 04/29/13 15:0050.0EPA 365.1 Chemical Oxygen Demand 281000 ug/L 05/07/13 13:3025000SM 5220D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 5 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Sample: 9704-LEACHATE Lab ID: 92155590001 Collected: 04/23/13 15:45 Received: 04/23/13 17:37 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 6010 ICP Groundwater Analytical Method: EPA 6010 Preparation Method: EPA 3010 Antimony ND ug/L 04/27/13 03:09 7440-36-004/25/13 12:056.0 5.0 1 Arsenic ND ug/L 04/27/13 03:09 7440-38-204/25/13 12:0510.0 5.0 1 Barium 380 ug/L 04/28/13 21:19 7440-39-304/25/13 12:05100 5.0 1 Beryllium ND ug/L 04/27/13 03:09 7440-41-704/25/13 12:051.0 1.0 1 Cadmium ND ug/L 04/27/13 03:09 7440-43-904/25/13 12:051.0 1.0 1 Chromium 23.6 ug/L 04/27/13 03:09 7440-47-304/25/13 12:0510.0 5.0 1 Cobalt 14.1 ug/L 04/27/13 03:09 7440-48-404/25/13 12:0510.0 5.0 1 Copper 8.0J ug/L 04/28/13 21:19 7440-50-804/25/13 12:0510.0 5.0 1 Lead ND ug/L 04/27/13 03:09 7439-92-104/25/13 12:0510.0 5.0 1 Nickel 23.6J ug/L 04/27/13 03:09 7440-02-004/25/13 12:0550.0 5.0 1 Selenium ND ug/L 04/27/13 03:09 7782-49-204/25/13 12:0510.0 10.0 1 Silver ND ug/L 04/27/13 03:09 7440-22-404/25/13 12:0510.0 5.0 1 Thallium ND ug/L 04/27/13 03:09 7440-28-004/25/13 12:055.5 5.4 1 Vanadium ND ug/L 04/27/13 03:09 7440-62-204/25/13 12:0525.0 5.0 1 Zinc 107 ug/L 04/27/13 03:09 7440-66-604/25/13 12:0510.0 10.0 1 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Acetone 28.4J ug/L 04/29/13 00:05 67-64-1100 10.0 1 Acrylonitrile ND ug/L 04/29/13 00:05 107-13-1200 1.9 1 Benzene 0.46J ug/L 04/29/13 00:05 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/29/13 00:05 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/29/13 00:05 75-27-41.0 0.18 1 Bromoform ND ug/L 04/29/13 00:05 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/29/13 00:05 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/29/13 00:05 78-93-3100 0.96 1 Carbon disulfide ND ug/L 04/29/13 00:05 75-15-0100 1.2 1 Carbon tetrachloride ND ug/L 04/29/13 00:05 56-23-51.0 0.25 1 Chlorobenzene 0.34J ug/L 04/29/13 00:05 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/29/13 00:05 75-00-310.0 0.54 1 Chloroform ND ug/L 04/29/13 00:05 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/29/13 00:05 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/29/13 00:05 96-12-813.0 2.5 1 Dibromochloromethane ND ug/L 04/29/13 00:05 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/29/13 00:05 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/29/13 00:05 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/29/13 00:05 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.4 ug/L 04/29/13 00:05 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/29/13 00:05 110-57-6100 1.0 1 1,1-Dichloroethane ND ug/L 04/29/13 00:05 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/29/13 00:05 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 04/29/13 00:05 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/29/13 00:05 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/29/13 00:05 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/29/13 00:05 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/29/13 00:05 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/29/13 00:05 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 6 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Sample: 9704-LEACHATE Lab ID: 92155590001 Collected: 04/23/13 15:45 Received: 04/23/13 17:37 Matrix: Water Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit Report 8260 MSV Low Level Landfill Analytical Method: EPA 8260 Ethylbenzene ND ug/L 04/29/13 00:05 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/29/13 00:05 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/29/13 00:05 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/29/13 00:05 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/29/13 00:05 108-10-1100 0.33 1 Styrene ND ug/L 04/29/13 00:05 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/29/13 00:05 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/29/13 00:05 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/29/13 00:05 127-18-41.0 0.46 1 Toluene 0.28J ug/L 04/29/13 00:05 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/29/13 00:05 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/29/13 00:05 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/29/13 00:05 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/29/13 00:05 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/29/13 00:05 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/29/13 00:05 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/29/13 00:05 75-01-41.0 0.62 1 Xylene (Total)0.93J ug/L 04/29/13 00:05 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %04/29/13 00:05 460-00-470-130 1 Dibromofluoromethane (S)108 %04/29/13 00:05 1868-53-770-130 1 1,2-Dichloroethane-d4 (S)100 %04/29/13 00:05 17060-07-070-130 1 Toluene-d8 (S)102 %04/29/13 00:05 2037-26-570-130 1 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day 318000 ug/L 04/29/13 18:5904/24/13 21:212000 2000 1 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 159000J ug/L 05/03/13 10:57 14808-79-82500000 20000 10 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 27200J ug/L 04/25/13 01:49100000 200 10 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 205 ug/L 04/29/13 15:00 7723-14-050.0 50.0 1 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 281000 ug/L 05/07/13 13:3025000 25000 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 7 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/13149 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 963011 Associated Lab Samples:92155590001 Matrix: Water Analyzed Antimony ug/L ND 6.0 04/27/13 01:33 Arsenic ug/L ND 10.0 04/27/13 01:33 Barium ug/L ND 100 04/28/13 19:46 Beryllium ug/L ND 1.0 04/27/13 01:33 Cadmium ug/L ND 1.0 04/27/13 01:33 Chromium ug/L ND 10.0 04/28/13 19:46 Cobalt ug/L ND 10.0 04/27/13 01:33 Copper ug/L ND 10.0 04/28/13 19:46 Lead ug/L ND 10.0 04/27/13 01:33 Nickel ug/L ND 50.0 04/27/13 01:33 Selenium ug/L ND 10.0 04/27/13 01:33 Silver ug/L ND 10.0 04/27/13 01:33 Thallium ug/L ND 5.5 04/27/13 01:33 Vanadium ug/L ND 25.0 04/27/13 01:33 Zinc ug/L ND 10.0 04/27/13 01:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 963012LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 489500 98 80-120 Arsenic ug/L 494500 99 80-120 Barium ug/L 488500 98 80-120 Beryllium ug/L 527500 105 80-120 Cadmium ug/L 537500 107 80-120 Chromium ug/L 495500 99 80-120 Cobalt ug/L 513500 103 80-120 Copper ug/L 484500 97 80-120 Lead ug/L 496500 99 80-120 Nickel ug/L 529500 106 80-120 Selenium ug/L 488500 98 80-120 Silver ug/L 254250 102 80-120 Thallium ug/L 444500 89 80-120 Vanadium ug/L 510500 102 80-120 Zinc ug/L 547500 109 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 963013MATRIX SPIKE SAMPLE: MSSpike Result 92155698001 Antimony ug/L 469500 94 75-125ND Arsenic ug/L 482500 96 75-125ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 8 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 963013MATRIX SPIKE SAMPLE: MSSpike Result 92155698001 Barium ug/L 486500 93 75-12521.6J Beryllium ug/L 499500 99 75-1252.9 Cadmium ug/L 511500 102 75-125ND Chromium ug/L 474500 95 75-125ND Cobalt ug/L 490500 98 75-125ND Copper ug/L 468500 94 75-125ND Lead ug/L 469500 93 75-125ND Nickel ug/L 503500 101 75-125ND Selenium ug/L 469500 94 75-125ND Silver ug/L 243250 97 75-125ND Thallium ug/L 423500 84 75-125ND Vanadium ug/L 489500 98 75-125ND Zinc ug/L 528500 104 75-125ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92155698002 963014SAMPLE DUPLICATE: Antimony ug/L ND 25ND Arsenic ug/L ND 25ND Barium ug/L 26.1J 2 2526.7J Beryllium ug/L ND 25ND Cadmium ug/L ND 25ND Chromium ug/L ND 25ND Cobalt ug/L 16.6 3 2517.1 Copper ug/L ND 25ND Lead ug/L ND 25ND Nickel ug/L ND 25ND Selenium ug/L ND 25ND Silver ug/L ND 25ND Thallium ug/L ND 257.4 Vanadium ug/L ND 25ND Zinc ug/L ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 9 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/22789 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 964650 Associated Lab Samples:92155590001 Matrix: Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 04/28/13 23:34 1,1,1-Trichloroethane ug/L ND 1.0 04/28/13 23:34 1,1,2,2-Tetrachloroethane ug/L ND 3.0 04/28/13 23:34 1,1,2-Trichloroethane ug/L ND 1.0 04/28/13 23:34 1,1-Dichloroethane ug/L ND 5.0 04/28/13 23:34 1,1-Dichloroethene ug/L ND 5.0 04/28/13 23:34 1,2,3-Trichloropropane ug/L ND 1.0 04/28/13 23:34 1,2-Dibromo-3-chloropropane ug/L ND 13.0 04/28/13 23:34 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/28/13 23:34 1,2-Dichlorobenzene ug/L ND 5.0 04/28/13 23:34 1,2-Dichloroethane ug/L ND 1.0 04/28/13 23:34 1,2-Dichloropropane ug/L ND 1.0 04/28/13 23:34 1,4-Dichlorobenzene ug/L ND 1.0 04/28/13 23:34 2-Butanone (MEK)ug/L ND 100 04/28/13 23:34 2-Hexanone ug/L ND 50.0 04/28/13 23:34 4-Methyl-2-pentanone (MIBK) ug/L ND 100 04/28/13 23:34 Acetone ug/L ND 100 04/28/13 23:34 Acrylonitrile ug/L ND 200 04/28/13 23:34 Benzene ug/L ND 1.0 04/28/13 23:34 Bromochloromethane ug/L ND 3.0 04/28/13 23:34 Bromodichloromethane ug/L ND 1.0 04/28/13 23:34 Bromoform ug/L ND 3.0 04/28/13 23:34 Bromomethane ug/L ND 10.0 04/28/13 23:34 Carbon disulfide ug/L ND 100 04/28/13 23:34 Carbon tetrachloride ug/L ND 1.0 04/28/13 23:34 Chlorobenzene ug/L ND 3.0 04/28/13 23:34 Chloroethane ug/L ND 10.0 04/28/13 23:34 Chloroform ug/L ND 5.0 04/28/13 23:34 Chloromethane ug/L ND 1.0 04/28/13 23:34 cis-1,2-Dichloroethene ug/L ND 5.0 04/28/13 23:34 cis-1,3-Dichloropropene ug/L ND 1.0 04/28/13 23:34 Dibromochloromethane ug/L ND 3.0 04/28/13 23:34 Dibromomethane ug/L ND 10.0 04/28/13 23:34 Ethylbenzene ug/L ND 1.0 04/28/13 23:34 Iodomethane ug/L ND 10.0 04/28/13 23:34 Methylene Chloride ug/L ND 1.0 04/28/13 23:34 Styrene ug/L ND 1.0 04/28/13 23:34 Tetrachloroethene ug/L ND 1.0 04/28/13 23:34 Toluene ug/L ND 1.0 04/28/13 23:34 trans-1,2-Dichloroethene ug/L ND 5.0 04/28/13 23:34 trans-1,3-Dichloropropene ug/L ND 1.0 04/28/13 23:34 trans-1,4-Dichloro-2-butene ug/L ND 100 04/28/13 23:34 Trichloroethene ug/L ND 1.0 04/28/13 23:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 10 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 964650 Associated Lab Samples:92155590001 Matrix: Water Analyzed Trichlorofluoromethane ug/L ND 1.0 04/28/13 23:34 Vinyl acetate ug/L ND 50.0 04/28/13 23:34 Vinyl chloride ug/L ND 1.0 04/28/13 23:34 Xylene (Total)ug/L ND 5.0 04/28/13 23:34 1,2-Dichloroethane-d4 (S)%102 70-130 04/28/13 23:34 4-Bromofluorobenzene (S)%102 70-130 04/28/13 23:34 Dibromofluoromethane (S)%108 70-130 04/28/13 23:34 Toluene-d8 (S)%100 70-130 04/28/13 23:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 964651LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 53.450 107 70-130 1,1,1-Trichloroethane ug/L 61.050 122 70-130 1,1,2,2-Tetrachloroethane ug/L 51.350 103 70-130 1,1,2-Trichloroethane ug/L 59.250 118 70-130 1,1-Dichloroethane ug/L 60.550 121 70-130 1,1-Dichloroethene ug/L 70.1 L350140 70-132 1,2,3-Trichloropropane ug/L 54.850 110 70-130 1,2-Dibromo-3-chloropropane ug/L 50.150 100 70-130 1,2-Dibromoethane (EDB)ug/L 54.450 109 70-130 1,2-Dichlorobenzene ug/L 50.750 101 70-130 1,2-Dichloroethane ug/L 55.850 112 70-130 1,2-Dichloropropane ug/L 60.550 121 70-130 1,4-Dichlorobenzene ug/L 48.850 98 70-130 2-Butanone (MEK)ug/L 116100 116 70-145 2-Hexanone ug/L 105100 105 70-144 4-Methyl-2-pentanone (MIBK) ug/L 110100 110 70-140 Acetone ug/L 126100 126 50-175 Acrylonitrile ug/L 294250 118 70-143 Benzene ug/L 53.950 108 70-130 Bromochloromethane ug/L 58.450 117 70-130 Bromodichloromethane ug/L 54.950 110 70-130 Bromoform ug/L 53.850 108 70-130 Bromomethane ug/L 57.650 115 54-130 Carbon disulfide ug/L 71.7J F3,L350143 70-131 Carbon tetrachloride ug/L 61.150 122 70-132 Chlorobenzene ug/L 52.550 105 70-130 Chloroethane ug/L 67.8 L350136 64-134 Chloroform ug/L 57.550 115 70-130 Chloromethane ug/L 60.650 121 64-130 cis-1,2-Dichloroethene ug/L 58.050 116 70-131 cis-1,3-Dichloropropene ug/L 57.850 116 70-130 Dibromochloromethane ug/L 54.450 109 70-130 Dibromomethane ug/L 56.550 113 70-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 11 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 964651LABORATORY CONTROL SAMPLE: LCSSpike Ethylbenzene ug/L 51.150 102 70-130 Iodomethane ug/L 132100 132 49-180 Methylene Chloride ug/L 59.550 119 63-130 Styrene ug/L 52.650 105 70-130 Tetrachloroethene ug/L 55.250 110 70-130 Toluene ug/L 53.450 107 70-130 trans-1,2-Dichloroethene ug/L 60.150 120 70-130 trans-1,3-Dichloropropene ug/L 60.150 120 70-132 trans-1,4-Dichloro-2-butene ug/L 48.5J50 97 70-141 Trichloroethene ug/L 55.050 110 70-130 Trichlorofluoromethane ug/L 66.350 133 62-133 Vinyl acetate ug/L 111100 111 66-157 Vinyl chloride ug/L 51.750 103 69-130 Xylene (Total)ug/L 151150 101 70-130 1,2-Dichloroethane-d4 (S)%97 70-130 4-Bromofluorobenzene (S)%103 70-130 Dibromofluoromethane (S)%103 70-130 Toluene-d8 (S)%101 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 964839MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92155591011 964840 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1-Dichloroethene ug/L 50 141 70-166166 16 3050ND70.7 83.1 Benzene ug/L 50 118 70-148125 6 30500.94J 60.1 63.6 Chlorobenzene ug/L 50 103 70-146107 4 30501.2J 52.6 54.6 Toluene ug/L 50 112 70-155118 5 3050ND56.1 59.1 Trichloroethene ug/L 50 134 69-151139 3 3050ND67.2 69.5 1,2-Dichloroethane-d4 (S) %102 70-130105 4-Bromofluorobenzene (S) %100 70-130101 Dibromofluoromethane (S) %107 70-130108 Toluene-d8 (S)%100 70-130103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 12 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/25110 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 962804 Associated Lab Samples:92155590001 Matrix: Water Analyzed BOD, 5 day ug/L ND 2000 04/29/13 18:59 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 962805LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day ug/L 228000198000 115 84.5-115.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92155572001 962806SAMPLE DUPLICATE: BOD, 5 day ug/L 61200 18 2073.2 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 13 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/15212 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 966918 Associated Lab Samples:92155590001 Matrix: Water Analyzed Sulfate ug/L ND 250000 05/02/13 18:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 966919LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 19200J20000 96 90-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 966920MATRIX SPIKE SAMPLE: MSSpike Result 92155941004 Sulfate ug/L 22800J20000 94 90-1104.0 mg/L Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 966926MATRIX SPIKE SAMPLE: MSSpike Result 92155810002 Sulfate ug/L 22200J20000 98 90-1102.7 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92155941004 966921SAMPLE DUPLICATE: Sulfate ug/L 4000J 0 204.0 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92155810002 966927SAMPLE DUPLICATE: Sulfate ug/L 2660J 1 202.7 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 14 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/15148 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 962853 Associated Lab Samples:92155590001 Matrix: Water Analyzed Nitrogen, Nitrate ug/L ND 10000 04/25/13 01:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 962854LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate ug/L 2510J2500 100 90-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 962855MATRIX SPIKE SAMPLE: MSSpike Result 92155565009 Nitrogen, Nitrate ug/L 2470J2500 93 90-1100.14 mg/L Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 962857MATRIX SPIKE SAMPLE: MSSpike Result 92155619003 Nitrogen, Nitrate ug/L 2990J M1250083 90-1100.90 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92155565009 962856SAMPLE DUPLICATE: Nitrogen, Nitrate ug/L 138J 0 200.14 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92155619003 962858SAMPLE DUPLICATE: Nitrogen, Nitrate ug/L 895J 1 200.90 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 15 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/15190 EPA 365.1 EPA 365.1 365.1 Phosphorus, Total Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 964767 Associated Lab Samples:92155590001 Matrix: Water Analyzed Phosphorus ug/L ND 50.0 04/29/13 14:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 964768LABORATORY CONTROL SAMPLE: LCSSpike Phosphorus ug/L 24102500 96 90-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 964769MATRIX SPIKE SAMPLE: MSSpike Result 92156042001 Phosphorus ug/L 37900 M62500127 90-11034.7 mg/L Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 964771MATRIX SPIKE SAMPLE: MSSpike Result 92155674001 Phosphorus ug/L 33102500 97 90-1100.87 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92156043002 964770SAMPLE DUPLICATE: Phosphorus ug/L 3140 1 203.2 mg/L Parameter Units Dup Result Max RPD QualifiersRPDResult 92155682001 964772SAMPLE DUPLICATE: Phosphorus ug/L 2620 2 202.7 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 16 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/15225 SM 5220D SM 5220D 5220D COD Associated Lab Samples: 92155590001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK: 967901 Associated Lab Samples:92155590001 Matrix: Water Analyzed Chemical Oxygen Demand ug/L ND 25000 05/07/13 13:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 967902LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand ug/L 729000750000 97 90-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 967903MATRIX SPIKE SAMPLE: MSSpike Result 92156039002 Chemical Oxygen Demand ug/L 745000750000 98 75-125ND Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 967905MATRIX SPIKE SAMPLE: MSSpike Result 92156039003 Chemical Oxygen Demand ug/L 715000750000 95 75-125ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92156039002 967904SAMPLE DUPLICATE: Chemical Oxygen Demand ug/L ND 20ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92156039003 967906SAMPLE DUPLICATE: Chemical Oxygen Demand ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 17 of 21 #=QL# QUALIFIERS Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the laboratory's control limits. The result is estimated.F3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.L3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 18 of 21 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92155590 TRANSYLVANIA WOODRUFF LEACHATE Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92155590001 MPRP/13149 ICP/119779704-LEACHATE EPA 3010 EPA 6010 92155590001 MSV/227899704-LEACHATE EPA 8260 92155590001 WET/25110 WET/251129704-LEACHATE SM 5210B SM 5210B 92155590001 WETA/152129704-LEACHATE EPA 300.0 92155590001 WETA/151489704-LEACHATE EPA 353.2 92155590001 WETA/151909704-LEACHATE EPA 365.1 92155590001 WETA/152259704-LEACHATE SM 5220D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/07/2013 04:58 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Page 19 of 21 Page 20 of 21 Page 21 of 21