SW_F_9301-MSWLF-1982_08-25-2014_EA_AM.pdf

09/04/14
Technical Report for
Resolve Environmental
Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
93-01
Accutest Job Number: FA17748
Sampling Date: 08/25/14
Report to:
Resolve Environmental
410 E Franklin St
Monroe, NC 28112
[e-mail]
ATTN: Laura Minor
Total number of pages in report:
Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001)
DoD ELAP (L-A-B L2229), CA (04226CA), TX (T104704404), PA (68-03573), VA (460177),
AK, AR, GA, KY, MA, NV, OK, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Southeast
09/04/14
e-Hardcopy 2.0
Automated Report
60
Accutest Laboratories is the sole authority for authorizing edits or modifications to this
document. Unauthorized modification of this report is strictly prohibited.
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Table of Contents
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Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA17748-1: MW-1A .....................................................................................................7
3.2: FA17748-2: MW-2 ........................................................................................................10
3.3: FA17748-3: MW-3 ........................................................................................................13
3.4: FA17748-4: MW-4 ........................................................................................................16
3.5: FA17748-5: SW-1 .........................................................................................................19
3.6: FA17748-6: SW-2 .........................................................................................................22
3.7: FA17748-7: SW-3 .........................................................................................................25
3.8: FA17748-8: WSW-1 .....................................................................................................28
3.9: FA17748-9: EQUIPMENT BLANK ............................................................................31
3.10: FA17748-10: TRIP BLANK .......................................................................................34
Section 4: Misc. Forms ............................................................................................................36
4.1: Chain of Custody ...........................................................................................................37
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................40
5.1: Method Blank Summary ................................................................................................41
5.2: Blank Spike Summary ...................................................................................................43
Section 6: Metals Analysis - QC Data Summaries ................................................................45
6.1: Prep QC MP27787: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,V,Zn ..............................46
Section 7: Misc. Forms (Accutest New Jersey) ......................................................................52
7.1: Chain of Custody ...........................................................................................................53
Section 8: Metals Analysis - QC Data (Accutest New Jersey) ..............................................55
8.1: Prep QC MP81631: Tl ...................................................................................................56
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Accutest Laboratories
Sample Summary
Resolve Environmental
Job No:FA17748
Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Project No: 93-01
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA17748-1 08/25/14 10:00 WB 08/27/14 AQ Ground Water MW-1A
FA17748-2 08/25/14 09:13 WB 08/27/14 AQ Ground Water MW-2
FA17748-3 08/25/14 08:50 WB 08/27/14 AQ Ground Water MW-3
FA17748-4 08/25/14 08:02 WB 08/27/14 AQ Ground Water MW-4
FA17748-5 08/25/14 09:17 WB 08/27/14 AQ Ground Water SW-1
FA17748-6 08/25/14 08:53 WB 08/27/14 AQ Ground Water SW-2
FA17748-7 08/25/14 08:07 WB 08/27/14 AQ Ground Water SW-3
FA17748-8 08/25/14 10:13 WB 08/27/14 AQ Ground Water WSW-1
FA17748-9 08/25/14 09:33 WB 08/27/14 AQ Equipment Blank EQUIPMENT BLANK
FA17748-10 08/25/14 00:00 WB 08/27/14 AQ Trip Blank Water TRIP BLANK
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Summary of Hits Page 1 of 2
Job Number:FA17748
Account:Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Collected:08/25/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA17748-1 MW-1A
Lead 5.5 5.0 ug/l SW846 6010C
Zinc 43.0 20 ug/l SW846 6010C
FA17748-2 MW-2
Benzene 0.62 J 1.0 0.24 ug/l SW846 8260B
cis-1,2-Dichloroethylene 1.7 1.0 0.33 ug/l SW846 8260B
p-Dichlorobenzene 2.3 1.0 0.20 ug/l SW846 8260B
Barium 232 200 ug/l SW846 6010C
Cobalt 72.7 50 ug/l SW846 6010C
Lead 13.9 5.0 ug/l SW846 6010C
Zinc 64.2 20 ug/l SW846 6010C
FA17748-3 MW-3
Benzene 0.65 J 1.0 0.24 ug/l SW846 8260B
Chlorobenzene 1.1 1.0 0.24 ug/l SW846 8260B
Chloroethane 3.2 2.0 0.50 ug/l SW846 8260B
cis-1,2-Dichloroethylene 4.2 1.0 0.33 ug/l SW846 8260B
p-Dichlorobenzene 2.5 1.0 0.20 ug/l SW846 8260B
FA17748-4 MW-4
Benzene 0.27 J 1.0 0.24 ug/l SW846 8260B
Chlorobenzene 0.56 J 1.0 0.24 ug/l SW846 8260B
Chloroethane 0.59 J 2.0 0.50 ug/l SW846 8260B
1,1-Dichloroethane 0.53 J 1.0 0.26 ug/l SW846 8260B
cis-1,2-Dichloroethylene 1.9 1.0 0.33 ug/l SW846 8260B
Tetrahydrofuran 6.2 5.0 1.3 ug/l SW846 8260B
FA17748-5 SW-1
Benzene 0.35 J 1.0 0.24 ug/l SW846 8260B
cis-1,2-Dichloroethylene 1.4 1.0 0.33 ug/l SW846 8260B
Zinc 27.1 20 ug/l SW846 6010C
FA17748-6 SW-2
No hits reported in this sample.
FA17748-7 SW-3
No hits reported in this sample.
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Summary of Hits Page 2 of 2
Job Number:FA17748
Account:Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Collected:08/25/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA17748-8 WSW-1
Zinc 30.2 20 ug/l SW846 6010C
FA17748-9 EQUIPMENT BLANK
No hits reported in this sample.
FA17748-10 TRIP BLANK
No hits reported in this sample.
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Sample Results
Report of Analysis
Southeast
Section 3
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Report of Analysis Page 1 of 2
Client Sample ID:MW-1A
Lab Sample ID:FA17748-1 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23319.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:MW-1A
Lab Sample ID:FA17748-1 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 93%83-118%
17060-07-0 1,2-Dichloroethane-D4 90%79-125%
2037-26-5 Toluene-D8 108%85-112%
460-00-4 4-Bromofluorobenzene 103%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-1A
Lab Sample ID:FA17748-1 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead 5.5 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc 43.0 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:MW-2
Lab Sample ID:FA17748-2 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23320.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene 0.62 1.0 0.24 ug/l J
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene 1.7 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene 2.3 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-2
Lab Sample ID:FA17748-2 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 105%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FA17748-2 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium 232 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt 72.7 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead 13.9 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc 64.2 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FA17748-3 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23321.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene 0.65 1.0 0.24 ug/l J
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene 1.1 1.0 0.24 ug/l
75-00-3 Chloroethane 3.2 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene 4.2 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene 2.5 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FA17748-3 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 91%79-125%
2037-26-5 Toluene-D8 104%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FA17748-3 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc <20 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:MW-4
Lab Sample ID:FA17748-4 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23322.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene 0.27 1.0 0.24 ug/l J
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene 0.56 1.0 0.24 ug/l J
75-00-3 Chloroethane 0.59 2.0 0.50 ug/l J
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane 0.53 1.0 0.26 ug/l J
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene 1.9 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:MW-4
Lab Sample ID:FA17748-4 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran 6.2 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 106%85-112%
460-00-4 4-Bromofluorobenzene 101%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:MW-4
Lab Sample ID:FA17748-4 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc <20 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:SW-1
Lab Sample ID:FA17748-5 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23323.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene 0.35 1.0 0.24 ug/l J
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene 1.4 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:SW-1
Lab Sample ID:FA17748-5 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 108%85-112%
460-00-4 4-Bromofluorobenzene 101%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SW-1
Lab Sample ID:FA17748-5 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc 27.1 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:SW-2
Lab Sample ID:FA17748-6 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23324.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:SW-2
Lab Sample ID:FA17748-6 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 90%79-125%
2037-26-5 Toluene-D8 103%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SW-2
Lab Sample ID:FA17748-6 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc <20 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:SW-3
Lab Sample ID:FA17748-7 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23325.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:SW-3
Lab Sample ID:FA17748-7 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 92%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 106%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:SW-3
Lab Sample ID:FA17748-7 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc <20 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:WSW-1
Lab Sample ID:FA17748-8 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23326.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:WSW-1
Lab Sample ID:FA17748-8 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 93%83-118%
17060-07-0 1,2-Dichloroethane-D4 87%79-125%
2037-26-5 Toluene-D8 107%85-112%
460-00-4 4-Bromofluorobenzene 101%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:WSW-1
Lab Sample ID:FA17748-8 Date Sampled:08/25/14
Matrix:AQ - Ground Water Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc 30.2 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:EQUIPMENT BLANK
Lab Sample ID:FA17748-9 Date Sampled:08/25/14
Matrix:AQ - Equipment Blank Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23327.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:EQUIPMENT BLANK
Lab Sample ID:FA17748-9 Date Sampled:08/25/14
Matrix:AQ - Equipment Blank Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 103%85-112%
460-00-4 4-Bromofluorobenzene 98%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:EQUIPMENT BLANK
Lab Sample ID:FA17748-9 Date Sampled:08/25/14
Matrix:AQ - Equipment Blank Date Received:08/27/14
Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Antimony <6.0 6.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Arsenic <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Barium <200 200 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Beryllium <4.0 4.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cadmium <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Chromium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Cobalt <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Copper <25 25 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Lead <5.0 5.0 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Nickel <40 40 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Selenium <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Silver <10 10 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Thallium a <1.0 1.0 ug/l 2 09/02/14 09/03/14 ANJ SW846 6020A 2 SW846 3010A 4
Vanadium <50 50 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
Zinc <20 20 ug/l 1 08/29/14 08/29/14 LM SW846 6010C 1 SW846 3010A 3
(1) Instrument QC Batch: MA11851
(2) Instrument QC Batch: N:MA34830
(3) Prep QC Batch: MP27787
(4) Prep QC Batch: N:MP81631
(a) Analysis performed at Accutest Laboratories, Dayton, NJ.
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA17748-10 Date Sampled:08/25/14
Matrix:AQ - Trip Blank Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I23328.D 1 08/28/14 DP n/a n/a VI482
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA17748-10 Date Sampled:08/25/14
Matrix:AQ - Trip Blank Water Date Received:08/27/14
Method:SW846 8260B Percent Solids:n/a
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
VOA Appendix I 40 CFR Part 258
CAS No.Compound Result RL MDL Units Q
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 89%79-125%
2037-26-5 Toluene-D8 106%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
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GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
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Method Blank Summary Page 1 of 2
Job Number:FA17748
Account:RENCM Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VI482-MB I23309.D 1 08/28/14 DP n/a n/a VI482
The QC reported here applies to the following samples:Method: SW846 8260B
FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7, FA17748-8, FA17748-9,
FA17748-10
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 11 ug/l
107-13-1 Acrylonitrile ND 10 2.0 ug/l
71-43-2 Benzene ND 1.0 0.24 ug/l
74-97-5 Bromochloromethane ND 1.0 0.38 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.26 ug/l
75-25-2 Bromoform ND 1.0 0.38 ug/l
108-90-7 Chlorobenzene ND 1.0 0.24 ug/l
75-00-3 Chloroethane ND 2.0 0.50 ug/l
67-66-3 Chloroform ND 1.0 0.31 ug/l
75-15-0 Carbon disulfide ND 2.0 0.20 ug/l
56-23-5 Carbon tetrachloride ND 1.0 0.40 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.26 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.0 0.78 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.24 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.24 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.36 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.36 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.33 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.21 ug/l
95-50-1 o-Dichlorobenzene ND 1.0 0.29 ug/l
106-46-7 p-Dichlorobenzene ND 1.0 0.20 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.34 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
100-41-4 Ethylbenzene ND 1.0 0.28 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
108-10-1 4-Methyl-2-pentanone ND 5.0 1.0 ug/l
74-83-9 Methyl bromide ND 2.0 0.54 ug/l
74-87-3 Methyl chloride ND 2.0 0.53 ug/l
74-88-4 Methyl iodide ND 1.0 0.32 ug/l
74-95-3 Methylene bromide ND 2.0 0.29 ug/l
75-09-2 Methylene chloride ND 5.0 2.0 ug/l
78-93-3 Methyl ethyl ketone ND 5.0 1.5 ug/l
100-42-5 Styrene ND 1.0 0.23 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.34 ug/l
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Method Blank Summary Page 2 of 2
Job Number:FA17748
Account:RENCM Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VI482-MB I23309.D 1 08/28/14 DP n/a n/a VI482
The QC reported here applies to the following samples:Method: SW846 8260B
FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7, FA17748-8, FA17748-9,
FA17748-10
CAS No.Compound Result RL MDL Units Q
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.27 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.32 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.57 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.26 ug/l
109-99-9 Tetrahydrofuran ND 5.0 1.3 ug/l
108-88-3 Toluene ND 1.0 0.20 ug/l
79-01-6 Trichloroethylene ND 1.0 0.30 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
110-57-6 Trans-1,4-Dichloro-2-Butene ND 10 2.0 ug/l
75-01-4 Vinyl chloride ND 1.0 0.33 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
1330-20-7 Xylene (total)ND 3.0 0.66 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 94%83-118%
17060-07-0 1,2-Dichloroethane-D4 91%79-125%
2037-26-5 Toluene-D8 108%85-112%
460-00-4 4-Bromofluorobenzene 103%83-118%
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Job Number:FA17748
Account:RENCM Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VI482-BS I23307.D 1 08/28/14 DP n/a n/a VI482
The QC reported here applies to the following samples:Method: SW846 8260B
FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7, FA17748-8, FA17748-9,
FA17748-10
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
67-64-1 Acetone 125 180 144 50-147
107-13-1 Acrylonitrile 125 105 84 58-126
71-43-2 Benzene 25 25.3 101 81-122
74-97-5 Bromochloromethane 25 22.8 91 76-123
75-27-4 Bromodichloromethane 25 21.4 86 79-123
75-25-2 Bromoform 25 22.5 90 66-123
108-90-7 Chlorobenzene 25 25.6 102 82-124
75-00-3 Chloroethane 25 31.8 127 62-144
67-66-3 Chloroform 25 21.8 87 80-124
75-15-0 Carbon disulfide 25 28.8 115 66-148
56-23-5 Carbon tetrachloride 25 24.9 100 76-136
75-34-3 1,1-Dichloroethane 25 24.8 99 81-122
75-35-4 1,1-Dichloroethylene 25 30.3 121 78-137
96-12-8 1,2-Dibromo-3-chloropropane 25 19.4 78 64-123
106-93-4 1,2-Dibromoethane 25 23.8 95 75-120
107-06-2 1,2-Dichloroethane 25 23.3 93 75-125
78-87-5 1,2-Dichloropropane 25 24.2 97 76-124
124-48-1 Dibromochloromethane 25 22.7 91 78-122
156-59-2 cis-1,2-Dichloroethylene 25 25.0 100 78-120
10061-01-5 cis-1,3-Dichloropropene 25 23.6 94 75-118
95-50-1 o-Dichlorobenzene 25 26.1 104 82-124
106-46-7 p-Dichlorobenzene 25 24.6 98 78-120
156-60-5 trans-1,2-Dichloroethylene 25 24.3 97 76-127
10061-02-6 trans-1,3-Dichloropropene 25 23.3 93 80-120
100-41-4 Ethylbenzene 25 24.3 97 81-121
591-78-6 2-Hexanone 125 156 125 61-129
108-10-1 4-Methyl-2-pentanone 125 115 92 66-122
74-83-9 Methyl bromide 25 26.4 106 59-143
74-87-3 Methyl chloride 25 28.9 116 50-159
74-88-4 Methyl iodide 25 22.3 89 73-123
74-95-3 Methylene bromide 25 21.3 85 78-119
75-09-2 Methylene chloride 25 24.8 99 69-135
78-93-3 Methyl ethyl ketone 125 148 118 56-143
100-42-5 Styrene 25 23.9 96 78-119
630-20-6 1,1,1,2-Tetrachloroethane 25 24.9 100 77-122
71-55-6 1,1,1-Trichloroethane 25 25.0 100 75-130
* = Outside of Control Limits.
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Job Number:FA17748
Account:RENCM Resolve Environmental
Project:Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VI482-BS I23307.D 1 08/28/14 DP n/a n/a VI482
The QC reported here applies to the following samples:Method: SW846 8260B
FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7, FA17748-8, FA17748-9,
FA17748-10
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
79-34-5 1,1,2,2-Tetrachloroethane 25 24.1 96 72-120
79-00-5 1,1,2-Trichloroethane 25 24.5 98 76-119
96-18-4 1,2,3-Trichloropropane 25 23.2 93 77-120
127-18-4 Tetrachloroethylene 25 25.8 103 76-135
109-99-9 Tetrahydrofuran 25 20.8 83 56-122
108-88-3 Toluene 25 24.9 100 80-120
79-01-6 Trichloroethylene 25 24.7 99 81-126
75-69-4 Trichlorofluoromethane 25 27.0 108 71-156
110-57-6 Trans-1,4-Dichloro-2-Butene 25 23.1 92 43-145
75-01-4 Vinyl chloride 25 26.9 108 69-159
108-05-4 Vinyl Acetate 125 192 154 43-154
1330-20-7 Xylene (total)75 75.9 101 80-126
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%83-118%
17060-07-0 1,2-Dichloroethane-D4 95%79-125%
2037-26-5 Toluene-D8 100%85-112%
460-00-4 4-Bromofluorobenzene 98%83-118%
* = Outside of Control Limits.
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Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
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BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14 08/29/14
MB MB
Metal RL IDL MDL raw final raw final
Aluminum 200 15 15
Antimony 6.0 2 2.3 -0.50 <6.0 0.80 <6.0
Arsenic 10 2 2.4 -0.60 <10 -1.2 <10
Barium 200 1 1 0.10 <200 0.0 <200
Beryllium 4.0 .5 .5 -0.10 <4.0 -0.10 <4.0
Cadmium 5.0 .5 .5 -0.10 <5.0 -0.10 <5.0
Calcium 1000 50 50
Chromium 10 1 2 0.0 <10 0.20 <10
Cobalt 50 .5 .5 -0.10 <50 -0.20 <50
Copper 25 1 1 -0.90 <25 -0.80 <25
Iron 300 17 17
Lead 5.0 1.1 1.1 -0.50 <5.0 -0.30 <5.0
Magnesium 5000 50 56
Manganese 15 .5 1
Molybdenum 50 .5 .5
Nickel 40 .5 .5 -0.30 <40 0.0 <40
Potassium 10000 200 200
Selenium 10 2.3 2.3 -0.90 <10 0.40 <10
Silver 10 .65 .77 0.30 <10 -0.20 <10
Sodium 10000 500 500
Strontium 10 .4 .4
Thallium 10 1.5 2
Tin 50 .7 1
Titanium 10 .9 1
Vanadium 50 .5 .5 0.10 <50 -0.10 <50
Zinc 20 3 3 -0.60 <20 4.0 <20
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
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MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14 08/29/14
FA17754-1 QC FA17754-1 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum anr
Antimony 0.0 0.0 NC 0-20 0.0 490 500 98.0 80-120
Arsenic 2.6 2.7 3.8 0-20 2.6 2040 2000 101.9 80-120
Barium 13.7 13.2 3.7 0-20 13.7 2010 2000 99.8 80-120
Beryllium 0.0 0.0 NC 0-20 0.0 51.6 50 103.2 80-120
Cadmium 0.0 0.0 NC 0-20 0.0 49.9 50 99.8 80-120
Calcium
Chromium 0.0 0.0 NC 0-20 0.0 211 200 105.5 80-120
Cobalt 0.0 0.0 NC 0-20 0.0 496 500 99.2 80-120
Copper 0.0 0.0 NC 0-20 0.0 259 250 103.6 80-120
Iron anr
Lead 0.0 0.0 NC 0-20 0.0 491 500 98.2 80-120
Magnesium
Manganese anr
Molybdenum
Nickel 0.0 0.0 NC 0-20 0.0 503 500 100.6 80-120
Potassium
Selenium 11.0 10.2 7.5 0-20 11.0 1990 2000 99.0 80-120
Silver 0.0 0.0 NC 0-20 0.0 49.1 50 98.2 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium 21.9 22.5 2.7 0-20 21.9 515 500 98.6 80-120
Zinc 4.8 5.0 4.1 0-20 4.8 496 500 98.2 80-120
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
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MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14
FA17754-1 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum anr
Antimony 0.0 500 500 100.0 2.0 20
Arsenic 2.6 2080 2000 103.9 1.9 20
Barium 13.7 2050 2000 101.8 2.0 20
Beryllium 0.0 52.4 50 104.8 1.5 20
Cadmium 0.0 50.7 50 101.4 1.6 20
Calcium
Chromium 0.0 214 200 107.0 1.4 20
Cobalt 0.0 506 500 101.2 2.0 20
Copper 0.0 263 250 105.2 1.5 20
Iron anr
Lead 0.0 502 500 100.4 2.2 20
Magnesium
Manganese anr
Molybdenum
Nickel 0.0 513 500 102.6 2.0 20
Potassium
Selenium 11.0 2030 2000 101.0 2.0 20
Silver 0.0 49.8 50 99.6 1.4 20
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium 21.9 523 500 100.2 1.5 20
Zinc 4.8 504 500 99.8 1.6 20
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
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SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum anr
Antimony 500 500 100.0 80-120
Arsenic 2020 2000 101.0 80-120
Barium 2070 2000 103.5 80-120
Beryllium 53.4 50 106.8 80-120
Cadmium 50.7 50 101.4 80-120
Calcium
Chromium 214 200 107.0 80-120
Cobalt 511 500 102.2 80-120
Copper 261 250 104.4 80-120
Iron anr
Lead 496 500 99.2 80-120
Magnesium
Manganese anr
Molybdenum
Nickel 525 500 105.0 80-120
Potassium
Selenium 1970 2000 98.5 80-120
Silver 49.4 50 98.8 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium 504 500 100.8 80-120
Zinc 511 500 102.2 80-120
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
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SERIAL DILUTION RESULTS SUMMARY
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14
FA17754-1 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum anr
Antimony 0.00 0.00 NC 0-10
Arsenic 2.60 0.00 100.0(a) 0-10
Barium 13.7 13.7 0.0 0-10
Beryllium 0.00 0.00 NC 0-10
Cadmium 0.00 0.00 NC 0-10
Calcium
Chromium 0.00 0.00 NC 0-10
Cobalt 0.00 0.00 NC 0-10
Copper 0.00 0.00 NC 0-10
Iron anr
Lead 0.00 0.00 NC 0-10
Magnesium
Manganese anr
Molybdenum
Nickel 0.00 0.00 NC 0-10
Potassium
Selenium 11.0 0.00 100.0(a) 0-10
Silver 0.00 0.00 NC 0-10
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium 21.9 22.0 0.5 0-10
Zinc 4.80 0.00 100.0(a) 0-10
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
_________________________________________________________________________________________________________
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POST DIGESTATE SPIKE SUMMARY
Login Number: FA17748
Account: RENCM - Resolve Environmental
Project: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP27787 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 08/29/14
Sample Final FA17754-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony 9.8 10 105.4 0.2 5 100 105.4 80-120
Arsenic 9.8 10 2.6 2.548 110.4 0.2 5 100 107.9 80-120
Barium 9.8 10 13.7 13.426 274.7 0.2 12.5 250 104.5 80-120
Beryllium 9.8 10 53.7 0.2 2.5 50 107.4 80-120
Cadmium 9.8 10 53.3 0.2 2.5 50 106.6 80-120
Calcium
Chromium 9.8 10 56 0.2 2.5 50 112.0 80-120
Cobalt 9.8 10 52.9 0.2 2.5 50 105.8 80-120
Copper 9.8 10 107 0.2 5 100 107.0 80-120
Iron
Lead 9.8 10 50.4 0.2 2.5 50 100.8 80-120
Magnesium
Manganese
Molybdenum
Nickel 9.8 10 108.3 0.2 5 100 108.3 80-120
Potassium
Selenium 9.8 10 11 10.78 112.1 0.2 5 100 101.3 80-120
Silver 9.8 10 51.4 0.2 2.5 50 102.8 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium 9.8 10 21.9 21.462 73.8 0.2 2.5 50 104.7 80-120
Zinc 9.8 10 4.8 4.704 265.6 0.2 12.5 250 104.4 80-120
Associated samples MP27787: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
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Accutest Laboratories
Misc. Forms
Custody Documents and Other Forms
(Accutest New Jersey)
Includes the following where applicable:
• Chain of Custody
Southeast
Section 7
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FA17748: Chain of Custody
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Accutest New Jersey
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Accutest Laboratories Sample Receipt Summary
Accutest LaboratoriesV:732.329.0200 2235 US Highway 130F: 732.329.3499 Dayton, New Jerseywww/accutest.com
Accutest Job Number:FA17748 Client:
Date / Time Received:8/30/2014 Delivery Method:
Project:
4. No. Coolers:1
Airbill #'s:
Cooler Security
1. Custody Seals Present:
Y or N
2. Custody Seals Intact:
3. COC Present:
4. Smpl Dates/Time OK
2. Cooler temp verification:
Cooler Temperature Y or N
1. Temp criteria achieved:
3. Cooler media:Ice (Bag)
Quality Control Preservatio Y or N N/A
1. Trip Blank present / cooler:
2. Trip Blank listed on COC:
3. Samples preserved properly:
4. VOCs headspace free:
Sample Integrity - Documentation Y or N
1. Sample labels present on bottles:
2. Container labeling complete:
3. Sample container label / COC agree:
Sample Integrity - Condition Y or N
1. Sample recvd within HT:
3. Condition of sample:
2. All containers accounted for:
Sample Integrity - Instructions
1. Analysis requested is clear:
2. Bottles received for unspecified tests
3. Sufficient volume recvd for analysis:
4. Compositing instructions clear:
5. Filtering instructions clear:
Intact
Y or N
Comments
Y or N N/A
Cooler Temps (Initial/Adjusted):#1: (2.6/2.6); 0
FA17748: Chain of Custody
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Accutest Laboratories
Metals Analysis
QC Data Summaries
(Accutest New Jersey)
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Southeast
Section 8
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BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA17748
Account: ALSE - Accutest Laboratories Southeast, Inc.
Project: RENCM: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP81631 Methods: SW846 6020A
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 09/02/14
MB
Metal RL IDL MDL raw final
Aluminum 50 .87 3.2
Antimony 1.0 .25 .12
Arsenic 1.0 .055 .23
Barium 2.0 .015 .2
Beryllium 1.0 .007 .026
Boron 10 3.2 1.3
Cadmium 1.0 .047 .22
Calcium 500 3.4 8.5
Chromium 2.0 .053 .3
Cobalt 1.0 .009 .038
Copper 2.0 .054 .22
Iron 50 .53 6.3
Lead 1.0 .015 .027
Magnesium 500 .58 .73
Manganese 2.0 .052 .11
Molybdenum 2.0 .033 .17
Nickel 2.0 .022 .062
Potassium 500 4.4 6.7
Selenium 1.0 .067 .087
Silver 1.0 .012 .1
Sodium 500 2.4 4.9
Strontium 10 .011 .028
Thallium 1.0 .01 .17 0.075 <1.0
Tin 10 .075 .25
Titanium 2.0 .12 .84
Vanadium 2.0 .053 .23
Zinc 4.0 .12 .93
Associated samples MP81631: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
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MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA17748
Account: ALSE - Accutest Laboratories Southeast, Inc.
Project: RENCM: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP81631 Methods: SW846 6020A
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 09/02/14
JB74797-2A Spikelot QC
Metal Original MS MPSPK % Rec Limits
Aluminum
Antimony
Barium
Beryllium
Boron
Cadmium
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium 0.41 2050 2000 102.5 75-125
Tin
Titanium
Vanadium
Zinc
Associated samples MP81631: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
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MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA17748
Account: ALSE - Accutest Laboratories Southeast, Inc.
Project: RENCM: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP81631 Methods: SW846 6020A
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 09/02/14
JB74797-2A Spikelot MSD QC
Metal Original MSD MPSPK % Rec RPD Limit
Aluminum
Antimony
Barium
Beryllium
Boron
Cadmium
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium 0.41 2110 2000 105.5 2.9 20
Tin
Titanium
Vanadium
Zinc
Associated samples MP81631: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
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SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA17748
Account: ALSE - Accutest Laboratories Southeast, Inc.
Project: RENCM: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP81631 Methods: SW846 6020A
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 09/02/14
BSP Spikelot QC
Metal Result MPSPK % Rec Limits
Aluminum
Antimony
Arsenic anr
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium anr
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium 1980 2000 99.0 80-120
Tin
Titanium
Vanadium
Zinc
Associated samples MP81631: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
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SERIAL DILUTION RESULTS SUMMARY
Login Number: FA17748
Account: ALSE - Accutest Laboratories Southeast, Inc.
Project: RENCM: Warren County Landfill; 559 Baltimore Rd, Warrenton, NC
QC Batch ID: MP81631 Methods: SW846 6020A
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 09/02/14
JB74797-2A QC
Metal Original SDL 2:10 %DIF Limits
Aluminum
Antimony
Barium
Beryllium
Boron
Cadmium
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium 0.412 0.169 59.0 (a) 0-10
Tin
Titanium
Vanadium
Zinc
Associated samples MP81631: FA17748-1, FA17748-2, FA17748-3, FA17748-4, FA17748-5, FA17748-6, FA17748-7,
FA17748-8, FA17748-9
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
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