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Home My WebLink AboutSW_F_9214-CDLF-1993_01-27-2015_RM_GW.pdf PREPARED FOR: REPUBLIC SERVICES OF NORTH CAROLINA, LLC 4300 OLD HOLLY SPRINGS ROAD APEX, NORTH CAROLINA 27539 CLOSED HOLLY SPRINGS C&D LANDFILL PERMIT NO. 92-14 FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2015 MARCH 2015 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE ENGINEERING PROJECT NO. 00895.1501.12 ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 1 EXECUTIVE SUMMARY This report presents the results of the first semiannual water quality monitoring event of 2015 conducted at the closed Holly Springs C&D Landfill on January 27, 2015. Samples were collected by representatives of Joyce Engineering from groundwater monitoring wells. The analytical results from the January 27, 2015, monitoring event have been reported by Analytical Services, Inc. of Norcross, Georgia under NC laboratory certification number 381. During the January 2015 water quality monitoring event, three inorganic constituents (arsenic, barium and mercury) were reported at quantified concentrations above the Solid Waste Section Report Limit (SWSL) in samples from one or more downgradient monitoring wells. No organic constituents were detected at quantified concentrations above SWSLs in samples from downgradient monitoring wells during the January 2015 event. Arsenic was reported above its respective NC 2L standard in MW-12 and MW-13. No other inorganic constituents were reported at concentrations above their respective NC 2L standards during the January 2015 sampling event. The arsenic detections in MW-12 and MW-13 are generally consistent with historical data and concentrations are most likely naturally-occurring. Historical data indicates arsenic is naturally-occurring in both upgradient and downgradient wells. Wake County has been identified as an area of North Carolina with a high probability of natural occurring arsenic as presented in the October 2003 DENR document “Distribution of Total Arsenic in Groundwater in the North Carolina Piedmont”. No other constituents detected in downgradient monitoring wells were reported above their respective NC 2L standards during the January 2015 event. Based on the results summarized herein, Republic Services of NC, LLC, will continue monitoring the uppermost aquifer beneath the closed Holly Springs C&D Landfill in accordance with the requirements outlined in Title 15A NCAC 13B.0500. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 2 First Semiannual Water Quality Monitoring Report of 2015 Closed Holly Springs C&D Landfill Wake County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION..............................................................................................................3 1.1 Site Description and Background ................................................................................ 3 1.2 Compliance Monitoring History .................................................................................. 3 1.3 Hydrogeologic Setting ................................................................................................... 3 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ......................4 2.1 Visual Inspection Program........................................................................................... 4 2.2 Well Network and Groundwater Elevation Measurements ..................................... 5 2.3 January 2015 Monitoring Event .................................................................................. 5 2.4 Laboratory Analysis Program ..................................................................................... 6 2.5 January 2015 Sampling Results ................................................................................... 6 3.0 LABORATORY AND FIELD QA/QC ............................................................................6 4.0 DATA EVALUTION .........................................................................................................7 5.0 CONCLUSIONS ................................................................................................................7 6.0 REFERENCES ...................................................................................................................7 Tables Table 1 Historical Groundwater Elevations Table 2 Estimated Hydraulic Gradients and Average Linear Velocities Table 3 Quantified Detections by Monitoring Location – January 2015 Table 4 Exceedances of Standards by Monitoring Location – January 2015 Drawing Drawing 1 Groundwater Potentiometric Surface Map – January 26, 2015 Appendices Appendix A Historical Tables Table 5 Historical Groundwater Constituents in Groundwater Table 6 Historical Surface Water Constituents in Surface Water Table 7 Field Parameters by Location – January 2015 Appendix B Groundwater and Surface Water Field Data Logs Appendix C January 2015 Laboratory Analytical Report ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 3 1.0 INTRODUCTION This report summarizes the monitoring results from the January 27, 2015, water quality monitoring event at the closed Holly Springs Construction & Demolition (C&D) Landfill in Wake County, North Carolina in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .0500. The closed Holly Springs C&D Landfill is maintained by Republic Services of North Carolina, LLC (Republic) under Permit No. 92-14 issued by the North Carolina Department of Environment and Natural Resources (DENR). 1.1 Site Description and Background The closed Holly Springs C&D Landfill is located within the town limits of Holly Springs, NC at 4300 Old Holly Springs Apex Road. The landfill is bounded to the north by Ivy Arbor Way, to the east by Old Holly Springs Apex Road, to the south by heavily wooded properties, and to the west by a golf course and wooded areas. The location of the facility is shown on the inlay on Drawing 1. A power line easement runs through the southern portion of the landfill along an east-northeast trending transect. Surrounding land use is primarily rural residential, silvicultural, and commercial. Access to the facility is from Old Holly Springs Apex Road. Topographic elevations at the facility range from approximately 280 to 420 feet above mean sea level. Two small unnamed perennial streams transect the site in a northwesterly direction toward Little Branch, which is located northwest of the site. The first stream is located in the southwest portion of the site and the second flows from the southeastern corner to the northwest corner of the site. The locations of the streams are shown on Drawing 1. 1.2 Compliance Monitoring History The facility’s current monitoring network is comprised of 12 monitoring wells (MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13), which monitor the uppermost aquifer beneath the facility. Wells MW-1, MW-5, and MW-8 have been decommissioned due to construction activities at the landfill. Two surface water monitoring points are monitored semi-annually: upstream monitoring point SW-1, and downstream monitoring point SW-2. Based on the results of the laboratory analyses, Republic Services of North Carolina, LLC continues to maintain compliance monitoring under Title 15A Subchapter 13B.0500 rules at this facility. 1.3 Hydrogeologic Setting Geologically, the facility is located in the Durham Sub-Basin within the Deep River Triassic Basin in the Piedmont Physiographic Province, east of the Jonesboro Fault zone, where Triassic- aged sediments are situated unconformably upon older igneous and metamorphic rocks of the Carolina Slate Belt (NCGS, 1985). The underlying Triassic sedimentary rocks belong to the Chatham Group, which are composed of conglomerate, arkosic sandstone, siltstone, claystone, and mudstone (Horton and Zullo, 1991). Various dikes and sills are also found in this area. The groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of unconsolidated sediment, partially weathered rock, and fractured sedimentary rocks. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 4 Groundwater depths vary at the site ranging from approximately 6-31 feet below grade. Groundwater elevations obtained during the January 2015 monitoring event, as well as historical groundwater elevations, are summarized in Table 1. Based the on topography shown on Drawing 1, regional groundwater flow in the uppermost aquifer beneath the site is expected to be generally to the northwest toward Little Branch. The hydraulic gradients in the uppermost aquifer underlying the site, as measured along the conceptual flow paths shown on the January 2015 potentiometric surface map (Drawing 1), were calculated to be approximately 0.051 to 0.168 ft/ft (Table 2). The estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne Where Vgw = average linear groundwater velocity (feet per day), K = hydraulic conductivity (feet per day), i = horizontal hydraulic gradient, and ne = effective porosity. Since we have no data on hydraulic conductivity or effective porosity from this facility, we used estimated values based on the average of values for these parameters reported for three other landfills located in Wake County. The average estimated linear groundwater flow velocity under the waste management unit is approximately 0.36 to 1.12 ft/day (Table 2). Flow is generally toward the northwest, although local flow directions vary (Drawing 1). The linear velocity equation and resultant rates are based on the simplifying assumptions of a homogeneous and isotropic aquifer, and may not be accurate when applied to heterogeneous and/or anisotropic conditions. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted as part of the January 2015 monitoring event are discussed in the following sections. 2.1 Visual Inspection Program In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the closed Holly Springs C&D Landfill. This inspection program involves field personnel making the following observations:  Observation of stress induced on the biological community (e.g., dead or dying vegetation);  Indications of leachate impact (e.g., seeps, impacted surface water);  Observations of erosion; and  Negative changes around the waste facility. During the January 2015 monitoring event, no physical indicators were observed in the vicinity of the waste management areas. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 5 2.2 Well Network and Groundwater Elevation Measurements The network of groundwater monitoring wells at the closed Holly Springs C&D Landfill consists of 12 wells (MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13). Monitoring well locations are shown on Drawing 1. The network of monitoring wells was constructed to target the preferential flow path for groundwater underlying waste disposal areas. One upstream (SW-1) and one downstream (SW-2) surface water points are also monitored. Monitoring wells MW-1R and MW-10 are the facility’s background wells and are located hydraulically upgradient of the waste disposal area in the southeast portion of the site. The other monitoring wells are located downgradient or sidegradient of the waste disposal area. 2.3 January 2015 Monitoring Event Personnel from Joyce Engineering visited the facility on January 26, 2015, to purge and sample monitoring wells MW-1R, MW-2, MW-3, MW-4, MW-5R, MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, and MW-13. Surface water points SW-1 and SW-2 were also sampled during the January 26, 2015, monitoring event. Depth-to-water measurements were obtained from the network monitoring wells to the nearest 0.01 foot using an electronic water level indicator prior to purging the wells. Monitoring well groundwater elevations for this event are presented in Table 1. A groundwater potentiometric surface map based on January 26, 2015 measurements is shown on drawing 1. The monitoring wells were purged and sampled using dedicated pumps and micropurge procedures. For all of the monitoring wells, measurements of pH, conductivity, dissolved oxygen, oxidation-reduction potential, temperature, and turbidity were recorded on approximately 1 to 3-minute intervals during the purge, depending on the purge rate. In general, the purge rate for each well was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to water, up to a maximum purge rate of 500 milliliters per minute. Purging was continued until stabilization was indicated by the field parameters. In general, stabilization was deemed to be complete once the range in measured values for each required field parameter was less than 10% over three monitoring intervals. Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample container was labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The required groundwater samples were collected directly from the pump discharge tubing in the laboratory- supplied, pre-preserved sample containers after purging was completed based on stabilization of the field parameters. After collection, the samples were placed in a cooler on ice, under chain-of-custody control. Copies of the sampling logs are presented in Appendix A. Each log includes a description of the sampling location, sampling equipment, sampling method, field observations, and field parameter measurements. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 6 2.4 Laboratory Analysis Program The January 2015 groundwater and surface water samples were submitted to Analytical Services, Inc. of Norcross, Georgia under chain-of-custody control for analysis. The groundwater samples, including the Field Blank, were analyzed for RCRA Metals and North Carolina Appendix I VOCs plus tetrahydrofuran. The Trip Blank was analyzed for North Carolina Appendix I VOCs plus tetrahydrofuran only. Joyce Engineering requested a Level II data report for the final laboratory report. The samples were received by the laboratory on January 29, 2015 in good condition, properly preserved, and within analysis hold times. 2.5 January 2015 Sampling Results Analytical detection and exceedance results for the January 2015 groundwater and surface water samples are summarized in Table 3 and Table 4 with historical data available in Tables 5 and 6. The laboratory certificates-of-analysis and chains-of-custody for the monitoring event are included in Appendix B. As presented in Table 3 and the laboratory certificates-of-analysis, three RCRA metals (arsenic, barium, and mercury) were detected in samples from downgradient compliance monitoring wells at quantified concentrations above their respective Solid Waste Section Reporting Limits (SWSLs). The detections are as follows: arsenic in MW-12 and MW-13; barium in MW-1R, MW-3, MW-5R, MW-6, MW-7, MW-12, and MW-13; and mercury in MW-7. No organic constituents were detected above their respective SWSLs during the January 2015 monitoring event. No constituents were detected above their respective SWSLs in either surface water sample. 3.0 LABORATORY AND FIELD QA/QC A Field Blank was collected by Joyce Engineering personnel as part of the January 2015 monitoring event. In addition to the Field Blank, a laboratory-prepared Trip Blank accompanied the volatile sample containers for the sampling event to and from the laboratory. The Field Blank was analyzed for 8 RCRA metals, NC Appendix I VOCs constituents plus tetrahydrofuran and the Trip Blank for NC Appendix I VOCs only plus tetrahydrofuran. In addition to the Field and Trip Blanks, at least one Method Blank was analyzed by the laboratory for each method used. Upon receipt of the laboratory data package, the data was reviewed by Joyce Engineering personnel for the following:  General typographical errors;  Correct analyses performed and within method specified hold times;  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples;  Blank-qualified data (B-flags);  Detections above the groundwater and surface water standards; and  Detections that are above historical levels. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 7 4.0 DATA EVALUTION One inorganic constituent, arsenic, was reported at a concentration above its NC 2L Standard in MW-12 and MW-13 during the January 2015 sampling event (Table 4). The concentrations of arsenic in MW-12 and MW-13 are generally consistent with historical data and concentrations are most likely naturally-occurring. Historical data indicates arsenic is naturally-occurring in both upgradient and downgradient wells. Wake County has been identified as an area of North Carolina with a high probability of naturally occurring arsenic as presented in the October 2003 DENR document “Distribution of Total Arsenic in Groundwater in the North Carolina Piedmont”. No other constituents detected in downgradient monitoring wells were reported above their respective NC 2L standards during the January 2015 event. 5.0 CONCLUSIONS Based on the results summarized herein, Republic Services of NC, LLC, will continue monitoring the uppermost aquifer beneath the closed Holly Springs C&D Landfill in accordance with the requirements for Detection Monitoring Program as outlined in Title 15A NCAC 13B.0500. The next compliance monitoring event for this facility is tentatively scheduled for July 2015. 6.0 REFERENCES ESP Associates, P.A., 1997, Construction Quality Assurance (CQA) Submittal Holly Springs Disposal, Inc. C&D Landfill Expansion-Cell 7, Phase A, July 30. ESP Associates, P.A, 2003, Addendum to Permit 92-14 Holly Springs C&D Landfill Proposed Cell 8 Expansion, February. ESP Associates, P.A, 2003. Application for Permit to Operate a Construction & Demolition Debris (C&D) Landfill-Holly Springs C&D Landfill Cell 8, Construction Quality Assurance (CQA) Submittal BFI Waste Systems of North America, Inc., June. Golder Associates NC, Inc., September 2011. Second Semi-Annual 2011 Sampling Event. Prepared for Republic Services of North Carolina, LLC. North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. North Carolina Geologic Survey, 1985, Geologic Map of North Carolina; North Carolina Department of Natural Resources and Community Development, Geological Survey Section; scale 1:500,000. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering Closed Holly Springs C&D Landfill, Permit No. 92-14 March 2015 8 Pippin, Charles G., Michele Butczynski, and Jonathan Clayton, 2003, Distribution of Total Arsenic in Groundwater in the North Carolina Piedmont. Department of Environment and Natural Resources Groundwater Section Resource Evaluation Program; Mooresville Regional Office, October 3. United States Environmental Protection Agency, 2003, Guidance for Developing Ecological Soil Screening Levels. November. TABLES TA B L E 1 Hi s t o r i c a l G r o u n d w a t e r E l e v a t i o n s Cl o s e d H o l l y S p r i n g s C a n d D L a n d f i l l , P e r m i t N o . 9 2 - 1 4 Wa k e C o u n t y , N o r t h C a r o l i n a Lo c a t i o n MW - 1 R M W - 2 M W - 3 M W - 4 M W - 5 R M W - 6 M W - 7 M W - 9 M W - 1 0 M W - 1 1 M W - 1 2 M W - 1 3 TO C E l e v a t i o n 37 9 . 6 3 3 9 1 . 1 9 3 7 0 . 3 6 3 1 5 . 3 7 3 1 1 . 9 0 3 2 7 . 9 0 2 8 6 . 1 0 3 0 7 . 8 0 3 8 2 . 9 0 2 9 1 . 5 0 2 9 4 . 0 0 3 3 7 . 5 7 22 - J u l - 0 9 3 5 8 . 8 1 3 6 2 . 5 1 3 5 9 . 1 4 2 9 7 . 7 9 3 0 4 . 6 9 3 1 6 . 8 7 2 7 8 . 8 7 2 9 5 . 7 8 3 6 0 . 2 4 2 7 9 . 7 2 2 8 4 . 5 0 3 2 6 . 6 7 26 - J a n - 1 0 3 6 1 . 9 5 3 5 9 . 9 0 3 6 4 . 3 4 2 9 8 . 5 7 3 0 6 . 6 5 3 1 7 . 8 8 2 8 1 . 2 9 2 9 8 . 0 7 3 6 1 . 4 5 2 8 0 . 8 1 2 8 5 . 6 5 3 2 7 . 2 8 7- J u l - 1 0 3 5 6 . 3 2 3 6 3 . 4 1 3 5 8 . 6 1 2 9 8 . 3 0 3 0 4 . 1 9 3 1 6 . 5 7 2 7 8 . 6 3 2 9 6 . 2 3 3 6 1 . 1 2 2 7 8 . 7 6 2 8 4 . 3 2 3 2 5 . 1 5 5- J a n - 1 1 3 6 2 . 5 5 3 6 0 . 0 0 3 5 8 . 7 1 2 9 7 . 8 5 3 0 4 . 3 1 3 1 7 . 1 9 2 7 9 . 6 9 2 9 5 . 1 2 3 6 0 . 4 5 2 8 0 . 3 6 2 8 4 . 8 4 3 2 6 . 9 2 7- J u l - 1 1 3 5 6 . 8 9 3 5 8 . 6 9 3 5 8 . 7 3 2 9 7 . 9 6 3 0 5 . 0 1 3 1 7 . 4 5 2 7 9 . 2 3 2 9 6 . 6 1 3 6 0 . 6 6 2 8 0 . 1 5 2 8 4 . 6 3 3 2 6 . 8 5 12 - J a n - 1 2 3 5 7 . 7 2 3 5 7 . 7 3 3 5 9 . 5 4 2 9 8 . 7 6 3 0 5 . 0 2 3 1 7 . 6 1 2 8 0 . 3 2 2 9 6 . 1 5 3 6 0 . 6 8 2 8 0 . 4 8 2 8 4 . 9 3 3 2 7 . 2 8 12 - J u l - 1 2 3 5 7 . 7 9 3 5 7 . 5 4 3 5 9 . 1 7 2 9 7 . 6 0 3 0 4 . 2 9 3 1 7 . 0 8 2 7 8 . 8 9 2 9 5 . 7 8 3 6 0 . 3 5 2 7 9 . 3 5 2 8 4 . 4 4 3 2 6 . 3 2 6- F e b - 1 3 3 6 0 . 1 7 3 5 6 . 0 7 3 5 9 . 5 5 2 9 7 . 0 6 3 0 4 . 8 5 3 1 6 . 5 8 2 7 9 . 8 2 2 9 6 . 9 1 3 5 9 . 6 9 2 7 9 . 9 7 2 8 4 . 6 6 3 2 7 . 0 2 9- J u l - 1 3 3 5 5 . 7 8 3 5 7 . 3 8 3 5 9 . 4 5 2 9 7 . 5 6 3 0 4 . 2 9 3 1 6 . 9 9 2 8 0 . 2 9 2 9 7 . 8 9 3 6 3 . 0 5 2 7 9 . 2 5 2 8 4 . 7 9 3 2 7 . 5 4 31 - J a n - 1 4 3 5 7 . 6 2 3 5 6 . 1 0 3 5 9 . 5 2 2 9 6 . 9 7 3 0 4 . 8 1 3 1 6 . 6 0 2 7 9 . 7 9 2 9 6 . 8 9 3 5 9 . 6 4 2 8 0 . 0 0 2 8 4 . 6 0 3 2 6 . 9 8 23 - J u l - 1 4 3 5 7 . 5 3 3 6 0 . 2 9 3 5 8 . 9 1 2 9 8 . 2 7 3 0 5 . 1 5 3 1 7 . 7 0 2 7 9 . 4 0 2 9 5 . 3 4 3 6 1 . 2 2 2 8 0 . 2 6 2 8 4 . 4 8 3 2 7 . 0 2 27 - J a n - 1 5 3 6 1 . 3 0 3 5 4 . 7 4 3 6 4 . 4 4 2 9 8 . 4 3 3 0 7 . 2 3 3 1 8 . 9 0 2 8 0 . 7 0 2 9 7 . 2 9 3 6 3 . 9 8 2 8 1 . 5 0 2 8 5 . 5 5 3 2 7 . 7 2 ME A N 35 8 . 7 0 3 5 8 . 7 0 3 6 0 . 0 1 2 9 7 . 9 3 3 0 5 . 0 4 3 1 7 . 2 9 2 7 9 . 7 4 2 9 6 . 5 1 3 6 1 . 0 4 2 8 0 . 0 5 2 8 4 . 7 8 3 2 6 . 9 0 MA X I M U M 36 2 . 5 5 3 6 3 . 4 1 3 6 4 . 4 4 2 9 8 . 7 6 3 0 7 . 2 3 3 1 8 . 9 0 2 8 1 . 2 9 2 9 8 . 0 7 3 6 3 . 9 8 2 8 1 . 5 0 2 8 5 . 6 5 3 2 7 . 7 2 MI N I M U M 35 5 . 7 8 3 5 4 . 7 4 3 5 8 . 6 1 2 9 6 . 9 7 3 0 4 . 1 9 3 1 6 . 5 7 2 7 8 . 6 3 2 9 5 . 1 2 3 5 9 . 6 4 2 7 8 . 7 6 2 8 4 . 3 2 3 2 5 . 1 5 No t e s : Al l m e a s u r e m e n t s a r e g i v e n i n f e e t A M S L ( a b o v e m e a n s e a l e v e l ) TO C = T o p o f c a s i n g . Th e T O C e l e v a t i o n f o r M W - 1 2 i s a p p r o x i m a t e . -- = N o d a t a a v a i l a b l e . Al l d a t a p r i o r t o 2 0 1 2 t a k e n f r o m p r e v i o u s r e p o r t s b y G o l d e r A s s o c i a t e s N C , I n c . TA B L E 2 Hy d r a u l i c G r a d i e n t s a n d L i n e a r G r o u n d w a t e r V e l o c i t i e s Cl o s e d H o l l y S p r i n g s C a n d D L a n d f i l l , P e r m i t N o . 9 2 - 1 4 Wa k e C o u n t y , N o r t h C a r o l i n a Gr o u n d w a t e r H o r i z o n t a l H y d r a u l i c E f f e c t i v e L i n e a r Se g m e n t C o n t o u r s G r a d i e n t C o n d u c t i v i t y P o r o s i t y V e l o c i t y Le n g t h (B e g i n n i n g / E n d ) iK n e V gw ( l i n e a r f e e t ) (f e e t A M S L ) ( f t / f t ) (f t / d a y ) (ft/day) 36 0 30 0 34 0 30 0 34 0 30 0 35 0 32 0 36 0 31 0 36 0 33 0 AV E R A G E : 0 . 0 8 1 A V E R A G E : 0 . 5 4 0 No t e s : Ho r i z o n t a l v e l o c i t i e s b a s e d o n t h e m o d i f i e d D a r c y e q u a t i o n V gw = K i / n e Va l u e s f o r K a n d n e w e r e o b t a i n e d b y t a k i n g t h e a v e r a g e s o f K a n d n e r e p o r t e d f o r t h r e e o t h e r l a n d f i l l s i n W a k e C o u n t y , N C ba s e d o n r e c e n t d o c u m e n t s f o u n d o n t h e D E N R ' s C A R A 3 P o r t a l . Gr a d i e n t s e g m e n t s a r e b a s e d o n t h e J a n u a r y 2 0 1 5 g r o u n d w a t e r c o n t o u r s a s s h o w n o n D r a w i n g 1 . Ja n u a r y 2 0 1 5 0.533 i 6 37 5 W 0. 0 8 0 1. 0 0. 1 5 0.340 i 5 29 8 SW 0. 1 6 8 1. 0 0. 1 5 1.1190.362 i 2 66 7 i 4 58 8 NE 0. 0 5 1 1. 0 0. 1 5 i 3 73 6 NW 0. 0 5 4 1. 0 0. 1 5 Gr a d i e n t Ca l c u l a t i o n Se g m e n t Fl o w Di r e c t i o n i 1 82 4 N 0. 0 7 3 1. 0 0. 1 5 0.485 W 0. 0 6 0 1. 0 0. 1 5 0.400 TA B L E 3 Qu a n t i f i e d D e t e c t i o n s f o r J a n u a r y 2 0 1 5 S a m p l i n g E v e n t Cl o s e d H o l l y S p r i n g s L a n d f i l l , P e r m i t # 9 2 - 1 4 Wa k e C o u n t y , N C We l l I D Pa r a m e t e r Re s u l t U n i t s M e t h o d D L R L S W S L NC 2 L / GW P S * Collection Date MW - 1 R T o t a l B a r i u m 31 8 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 MW - 5 R T o t a l B a r i u m 11 0 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 MW - 6 To t a l B a r i u m 26 2 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 MW - 7 To t a l B a r i u m 11 2 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 MW - 7 To t a l M e r c u r y 0. 2 7 5 µ g / L E P A 7 4 7 0 A 0 . 0 6 0 . 2 0 . 2 1 0 1 / 2 7 / 2 0 1 5 MW - 1 2 T o t a l A r s e n i c 21 . 6 µg / L E P A 6 0 2 0 A 1 . 1 3 1 0 1 0 1 0 0 1 / 2 7 / 2 0 1 5 MW - 1 2 To t a l B a r i u m 18 6 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 MW - 1 3 T o t a l A r s e n i c 10 . 8 µg / L E P A 6 0 2 0 A 1 . 1 3 1 0 1 0 1 0 0 1 / 2 7 / 2 0 1 5 MW - 1 3 To t a l B a r i u m 62 9 µ g / L E P A 6 0 2 0 A 0 . 1 0 1 0 0 1 0 0 7 0 0 0 1 / 2 7 / 2 0 1 5 NO T E S : DL = M e t h o d D e t e c t i o n L i m i t . RL = R e p o r t i n g L i m i t = P Q L p r i o r t o 2 0 0 7 a n d S W S L s t a r t i n g J a n u a r y 2 0 0 7 . SW S L = N C - D E N R S o l i d W a s t e S e c t i o n L i m i t . NC 2 L = G r o u n d w a t e r S t a n d a r d e s t a b l i s h e d i n 1 5 A N C A C 2 L . 0 2 0 2 GW P S = N C D E N R S o l i d W a s t e S e c t i o n G r o u n d w a t e r P r o t e c t i o n S t a n d a r d f o r c o n s t i t u e n t s w i t h n o l i s t e d N C 2 L . * - G W P S i s i n d i c a t r e d b y a n a s t e r i x ( * ) . Bo l d = C o n c e n t r a t i o n s a b o v e t h e N C 2 L o r G W P S . Re p u b l i c S e r v i c e s Cl o s e d H o l l y S p r i n g s C + D L a n d f i l l Joyce Engineering TA B L E 4 GP S E x c e e d a n c e s f o r J a n u a r y 2 0 1 5 S a m p l i n g E v e n t Cl o s e d H o l l y S p r i n g s L a n d f i l l , P e r m i t # 9 2 - 1 4 Wa k e C o u n t y , N C We l l I D Pa r a m e t e r Re s u l t U n i t s M e t h o d D L R L S W S L NC 2 L / GW P S * Collection Date MW - 1 2 T o t a l A r s e n i c 21 . 6 µg / L E P A 6 0 2 0 A 1 . 1 3 1 0 1 0 1 0 0 1 / 2 7 / 2 0 1 5 MW - 1 3 T o t a l A r s e n i c 10 . 8 µg / L E P A 6 0 2 0 A 1 . 1 3 1 0 1 0 1 0 0 1 / 2 7 / 2 0 1 5 NO T E S : DL = M e t h o d D e t e c t i o n L i m i t . RL = R e p o r t i n g L i m i t = P Q L p r i o r t o 2 0 0 7 a n d S W S L s t a r t i n g J a n u a r y 2 0 0 7 . SW S L = N C - D E N R S o l i d W a s t e S e c t i o n L i m i t . NC 2 L = G r o u n d w a t e r S t a n d a r d e s t a b l i s h e d i n 1 5 A N C A C 2 L . 0 2 0 2 GW P S = N C D E N R S o l i d W a s t e S e c t i o n G r o u n d w a t e r P r o t e c t i o n S t a n d a r d f o r c o n s t i t u e n t s w i t h n o l i s t e d N C 2 L . * - G W P S i s i n d i c a t r e d b y a n a s t e r i x ( * ) . Bo l d = C o n c e n t r a t i o n s a b o v e t h e N C 2 L o r G W P S . Re p u b l i c S e r v i c e s Cl o s e d H o l l y S p r i n g s C + D L a n d f i l l Joyce Engineering DRAWING PROJECT NO. AP P R O V E D CH E C K E D DR A W N DE S I G N E D DA T E DA T E RE V I S I O N S A N D R E C O R D O F I S S U E BY N O A P P C K SCALE A l l r i g h t s r e s e r v e d . J o y c e E n g i n e e r i n g , I n c . DRAWING NO. L:\ R e p u b l i c N C \ H o l l y S p r i n g s \ 2 0 1 5 J A N U A R Y H o l l y S p r i n g s G W M a p . d w g L a y o u t = G W m a p 22 1 1 W . M E A D O W V I E W R O A D GR E E N S B O R O , N C 2 7 4 0 7 PH O N E : ( 3 3 6 ) 3 2 3 - 0 0 9 2 NC C O R P L I C : C - 0 7 8 2 895 HO L L Y S P R I N G S C L O S E D C & D L A N D F I L L WA K E C O U N T Y , N O R T H C A R O L I N A 20 1 5 1 AS SHOWN GR O U N D W A T E R P O T E N T I O M E T R I C S U R F A C E M A P JA N U A R Y 2 7 , 2 0 1 5 PE R M I T N O . 9 2 - 1 4 DG RH VB VB 02 / 1 7 / 1 5 VICINITY MAP 0 (FEET) GRAPHIC SCALE 20010050 SOURCE: U.S.G.S. 7.5 MINUTE TOPO FOR APEX, NC Appendix A Historical Tables TABLE 5 Historical Groundwater Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Inorganic Compounds Total Arsenic 07/22/09 2.8 10.0 3.84 J 7.37 J 6.86 J 5.85 J 6.60 J 6.26 J 7.04 J 4.87 J 4.26 J 7.19 J 21.4 9.63 J ND NC 2L = 10 µg/L 01/26/10 3.9 10.0 9.21 J 6.79 J 5.08 J 4.20 J 4.78 J ND ND 5.83 J ND ND 13.5 8.24 J ND 07/07/10 2.8 10.0 5.02 J 6.27 J ND 4.34 J 6.90 J ND 3.15 J ND ND ND 13.0 10.20 ND 01/05/11 2.8 10.0 ND 4.15 J 3.99 J ND ND ND ND ND ND ND 11.6 3.84 J ND 07/07/11 2.8 10.0 ND 5.06 J ND ND 5.31 J ND 3.15 J ND ND ND 14.0 8.09 J ND 01/12/12 2.8 10.0 1.82 J 2.81 J 2.81 J 4.32 J 2.89 J ND ND 1.52 J 14.20 ND 10.8 2.11 J ND 07/12/12 2.8 10.0 ND 1.40 J 3.57 J 1.33 J 1.85 J ND ND ND ND ND 14.6 6.86 J ND 02/06/13 2.8 10.0 ND 2.58 J 3.56 J 3.70 J 3.66 J ND ND 1.45 J ND 1.29 J 8.0 J 3.80 J ND 07/09/13 2.8 10.0 1.62 J 4.44 J 3.70 J 2.68 J 4.10 J ND 1.74 J ND ND ND 25.0 8.44 J ND 01/31/14 2.8 10.0 ND 5.77 J 2.72 J 2.31 J 3.47 J ND ND 0.89 J 5.72 J ND 21.3 1.47 J ND 07/23/14 1.13 10.0 1.14 J 4.39 J 2.40 J 3.42 J 1.67 J 1.19 J ND ND ND ND 22.1 20.2 ND 01/27/15 1.13 10.0 1.61 J 5.13 J 3.09 J 3.30 J 2.76 J ND 1.21 J 1.83 J 2.59 J ND 21.6 10.8 ND Total Barium 07/22/09 4.2 100.0 258 48.1 J 72.6 J 30.6 J 54.4 J 162 266 122 112 84.3 J 209 386 ND NC 2L = 700 µg/L 01/26/10 0.25 100.00 327 49.9 J 77.8 J 36.2 J 45.3 J 144 275 105 138 45.2 J 220 540 0.66 J 07/07/10 1.0 100.0 219 24.8 J 61.0 J 27.5 J 43.4 J 131 209 126 113 44.3 J 149 385 ND 01/05/11 1.0 100.0 229 32.5 J 81.5 J 27.2 J 45.8 J 134 222 80.0 J 125 45.3 J 200 312 ND 07/07/11 1.0 100.0 266 27.5 J 80.4 J 31.7 J 53.6 J 130 272 141 196 56.8 J 217 354 ND 01/12/12 --- 100 260 42.6 J 82.0 J 46.2 J 48.4 J 130 261 97.6 J 387 40.8 J 243 300 0.09 J 07/12/12 --- 100 238 34.9 J 71.3 J 27.7 J 48.9 J 110 246 142 76.0 J 48.7 J 220 316 1.47 J 02/06/13 --- 100 250 43.6 J 67.6 J 26.8 J 48.2 J 113 248 70.6 J 106 59.3 J 118 263 1.05 J 07/09/13 --- 100 252 23.4 J 69.4 J 26.2 J 54.1 J 123 307 130 80.6 J 47.7 J 228 237 0.46 J 01/31/14 --- 100 258 22.0 J 74.4 J 29.5 J 54.2 J 109 245 116 129 35.3 J 163 259 ND 07/23/14 0.10 100 251 20.9 J 77.8 J 121 62.2 J 147 282 150 61.0 J 48.2 J 173 324 0.33 J 01/27/15 0.10 100 318 24.0 J 71.4 J 50.1 J 61.5 J 110 262 112 83.4 J 56.7 J 186 629 0.17 J Total Cadmium 07/22/09 0.1 1 0.31 J 0.14 J ND 0.16 J 0.194 J 0.37 J ND 0.232 J 0.49 J 0.17 J 0.39 J 0.17 J ND NC 2L = 2 µg/L 01/26/10 0.1 1 0.36 B 0.19 B ND 0.24 B 0.211 B 0.20 B 0.23 B 0.335 B 0.25 B 0.39 B ND 0.13 B 0.14 J 07/07/10 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.4 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.4 1 0.07 J ND ND ND ND ND ND ND 0.12 J ND ND ND ND 07/12/12 --- 1.00 0.11 J ND ND ND ND 0.06 J ND ND ND ND ND 0.10 J ND 02/06/13 --- 1.00 0.16 J ND ND ND ND ND ND ND 0.06 J 0.06 J 0.20 J 0.06 J ND 07/09/13 --- 1.00 ND ND ND ND ND ND ND ND 0.20 J ND 0.15 J ND ND 01/31/14 --- 1.00 ND ND ND ND ND ND ND ND 0.06 J ND 0.27 J ND ND 07/23/14 --- 1.00 ND ND ND 0.06 J ND ND ND ND 0.14 J 0.05 J 0.12 J ND ND 01/27/15 0.05 1.00 ND ND ND ND ND ND ND ND 0.08 J 0.07 J 0.09 J ND ND Total Chromium 07/22/09 0.7 10 ND 2.74 J 4.45 J 3.53 J ND 1.03 J 1.47 J 1.25 J 3.60 J 5.39 J 1.89 J ND ND NC 2L = 10 µg/L 01/26/10 1.7 10 2.91 J 2.03 J 6.80 J 4.05 J ND ND ND 2.38 J 5.17 J 4.39 J ND 1.72 J ND 07/07/10 1.0 10 1.50 J 1.59 J 3.16 J 2.46 J 1.93 J 1.70 J 1.10 J 1.06 J 3.85 J 2.94 J ND 2.68 J ND 01/05/11 1.0 10 ND 2.10 J 7.40 J 6.03 J ND 2.59 J 1.95 J 1.11 J 7.43 J 7.10 J ND ND ND 07/07/11 1.0 10 ND 2.41 J 4.75 J 2.01 J 1.06 J 1.80 J 1.28 J ND 22.50 3.54 J 1.82 J 1.62 J ND 01/12/12 1.0 10 ND 1.65 B 11.0 22.8 ND ND 0.84 B 1.38 B 17.90 3.19 B 1.07 B 1.47 B 0.82 J 07/12/12 --- 10.0 ND ND 1.23 J 3.01 J ND ND ND ND 3.00 J 1.02 J ND ND ND 02/06/13 --- 10.0 ND 0.86 B ND 3.40 B ND 1.18 B 15.70 ND 5.10 B ND 4.50 B 1.80 B 1.42 J 07/09/13 --- 10.0 2.56 B ND 0.60 B ND ND 2.16 B 7.47 B 1.39 B 4.15 B 3.11 B 3.24 B 2.39 B 3.51 J 01/31/14 --- 10.0 3.56 B 1.31 B 2.47 B 1.63 B ND 3.93 B 7.32 B 2.99 B 8.64 B 5.11 B 2.31 B 3.96 B 2.79 J 07/23/14 --- 10.0 1.99 J 1.43 J 2.86 J 7.72 J ND 1.75 J 2.81 J 1.58 J 3.57 J 2.65 J ND ND ND 01/27/15 0.73 10.0 1.53 J 3.08 J 1.74 J 1.52 J ND ND 1.05 J ND 2.69 J 4.37 J ND 3.37 J ND Total Lead 07/22/09 1.6 10 1.72 J ND ND ND ND ND ND ND 2.31 J 3.82 J 2.44 J ND ND NC 2L = 15 µg/L 01/26/10 1.1 10 3.05 J ND ND ND ND ND ND ND 4.9 J ND ND 2.24 J ND 07/07/10 1.9 10 ND ND ND ND ND ND ND ND 2.66 J ND ND ND ND 01/05/11 1.9 10 ND 2.40 J ND ND ND ND ND ND ND ND ND ND ND 07/07/11 1.9 10 ND ND ND ND ND ND ND ND 11.30 ND ND ND ND 01/12/12 1.9 10 ND ND 0.21 J 2.43 ND ND ND ND 19.60 0.59 J ND ND ND 07/12/12 --- 10.0 0.12 J ND ND 0.31 J ND ND ND ND 0.98 J 0.11 J ND 0.23 J ND 02/06/13 --- 10.0 0.26 J ND 0.11 J 0.68 J 0.09 J ND 0.68 J ND 5.48 J 0.22 J 1.63 J 0.13 J ND 07/09/13 --- 10.0 1.36 J ND 0.06 B 0.23 B 0.08 B ND 0.24 B ND 1.42 J ND 1.64 J 0.28 B 0.08 J 01/31/14 --- 10.0 0.08 J ND ND 0.85 J ND ND 0.24 J ND 10.4 0.08 J 0.32 J 0.13 J ND 07/23/14 --- 10.0 0.05 J ND 0.17 J 5.31 J ND ND ND ND 1.68 J 0.09 J 0.22 J 0.53 J ND 01/27/15 0.05 10.0 0.33 J ND ND 1.44 J ND ND ND ND 2.15 J 1.35 J 0.05 J 1.88 J ND Total Mercury 07/22/09 0.1 0.2 ND ND ND ND ND ND ND 0.206 ND ND ND ND ND NC 2L = 1 µg/L 01/26/10 0.1 0.2 ND ND ND ND ND ND ND 0.115 J ND ND 0.070 J ND ND 07/07/10 0.2 0.2 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.2 0.2 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.2 0.2 ND ND ND ND ND ND ND 0.194 J ND ND ND ND ND 01/12/12 0.2 0.2 ND ND ND ND ND ND ND 0.201 ND ND ND ND ND 07/12/12 --- 0.200 ND ND ND ND ND ND ND 0.197 J ND ND ND ND ND 02/06/13 --- 0.200 ND ND ND ND ND ND ND 0.066 J ND ND ND ND ND 07/09/13 --- 0.200 {0.088} B ND ND ND ND 0.067 J 0.074 J 0.259 ND ND 0.069 J 0.08 J ND {0.084} J 01/31/14 --- 0.200 ND ND 0.073 B ND ND ND 0.068 B 0.286 B ND ND 0.072 B ND 0.114 J 07/23/14 --- 0.200 0.069 J ND ND ND ND 0.126 J 0.065 J 0.193 J ND ND ND ND ND 01/27/15 0.064 0.200 ND ND 0.163 J ND ND ND ND 0.275 ND ND ND ND ND Total Selenium 07/22/09 3.4 10 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 20 µg/L 01/26/10 0.8 10 ND ND ND ND ND 1.50 J 0.97 J 1.01 J 4.32 J 3.22 J 2.02 J 1.10 J ND 07/07/10 2.7 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 2.7 10 ND ND ND ND ND ND ND ND ND ND 3.55 B ND 3.01 J 07/07/11 2.7 10 ND ND 6.34 (0.985) B ND ND ND ND ND 2.79 (6.37) B ND ND ND 3.21 J 01/12/12 2.7 10 ND ND ND 2.20 J ND ND ND ND 29.20 2.17 J 1.60 J ND ND 07/12/12 --- 10.0 ND ND ND ND ND ND ND 1.03 J 2.18 J 0.91 J 2.05 J 0.73 J ND 02/06/13 --- 10.0 ND ND ND ND ND 0.56 J ND ND 2.56 J 1.50 J ND ND ND 07/09/13 --- 10.0 ND ND ND ND ND ND ND 0.85 J 3.31 J 1.21 J 1.13 J ND ND 01/31/14 --- 10.0 ND ND ND ND ND ND ND 0.91 J 3.04 J 1.42 J 1.17 J ND ND 07/23/14 --- 10.0 ND ND ND ND ND 1.03 J 1.33 J 1.99 J 2.80 J 1.73 J 4.99 J 1.11 J ND 01/27/15 1.01 10.0 ND ND ND ND ND ND ND ND 3.62 J 1.66 J 2.41 J ND ND Total Silver 07/22/09 1.0 10 ND ND ND ND 1.28 J ND ND ND 1.04 J ND ND ND ND NC 2L = 20 µg/L 01/26/10 0.5 10 0.68 B 0.56 B 1.17 B ND 0.549 B 0.92 B 0.52 B 0.529 B 0.60 B 1.57 B 0.84 B 0.83 B 0.73 J 07/07/10 1.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 1.9 10 ND ND ND ND ND ND ND ND ND ND 2.68 J ND ND 07/07/11 1.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 1.9 10 ND ND 0.22 ND ND ND ND 0.58 J 0.20 J ND ND ND ND 07/12/12 --- 10.0 0.14 J ND 0.23 J ND ND ND ND ND ND ND 0.16 J 0.24 J ND 02/06/13 --- 10.0 ND ND ND ND ND ND ND ND ND ND 0.28 J ND ND 07/09/13 --- 10.0 0.85 J ND ND ND ND ND ND ND ND ND 0.51 J ND ND 01/31/14 --- 10.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 10.0 ND ND ND ND ND ND ND ND ND ND ND 0.86 J ND 01/27/15 0.17 10.0 0.21 J 0.24 J 0.26 J 0.18 J ND ND ND ND ND 0.23 J ND 3.11 J ND Holly Springs Closed C and D Landfill Permit No. 92-14 Page 1 of 3 Joyce Engineering TABLE 5 Historical Groundwater Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Organic Compounds Acetone 07/22/09 1.5 100 ND ND ND ND ND ND ND ND ND ND 2.0 J ND ND NC 2L = 6000 µg/L 01/26/10 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 1.5 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 1.2 100 ND ND ND ND ND ND ND ND ND ND 10.0 J ND ND 01/12/12 1.2 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND 2.4 J 01/31/14 --- 100 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 100 ND ND ND 6.3 J ND ND ND ND ND ND 8.6 J ND ND 01/27/15 5.7 100 ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene 07/22/09 0.2 1 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 1 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.2 1 ND ND ND ND ND ND ND ND ND ND 0.5 J ND ND 01/05/11 0.2 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.7 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND 0.4 J ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND 0.6 J ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND 0.2 J ND ND Chloroform 07/22/09 0.2 5 ND ND 0.6 J ND ND ND ND ND ND ND ND ND ND NC 2L = 70 µg/L 01/26/10 0.1 5 ND ND 0.7 J ND ND ND ND ND ND ND ND ND ND 07/07/10 0.2 5 ND ND 0.4 J ND ND ND ND ND ND ND ND ND ND 01/05/11 0.2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.7 5 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 --- 5.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 5.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 5.0 ND ND 0.5 J ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 5.0 ND ND 0.4 B ND ND ND ND ND ND ND ND ND 0.50 J 01/31/14 --- 5.0 ND ND 0.3 J ND ND ND ND 0.3 J ND ND ND ND ND 07/23/14 --- 5.0 ND ND 0.3 J ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 5.0 ND ND ND ND ND ND ND 0.2 J ND ND ND ND ND Chloromethane 07/22/09 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 3 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.3 1 ND ND ND ND ND ND ND ND 0.45 J ND 0.43 J ND ND 01/05/11 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND Methyl Ethyl Ketone (2-Butanone)07/23/14 --- 100 2.0 J ND 0.9 J ND ND ND ND ND ND ND ND ND ND NC 2L = 4,000 µg/L 01/27/15 0.8 100 ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene 07/22/09 0.3 1 0.84 J ND ND ND ND ND ND ND ND ND ND ND ND NC 2L = 600 µg/L 01/26/10 0.1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/10 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/05/11 0.3 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/07/11 0.9 1 ND ND ND ND ND ND ND ND ND ND 1.80 ND ND 07/14/11 0.9 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/12/12 0.6 1 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 1.0 ND ND 0.20 J ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 0.2 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrahydrofuran 01/05/11 0.8 10 ND ND ND ND ND ND ND ND ND ND ND ND ND (No Standard)07/07/11 0.8 10 ND ND ND ND 1.7 ND ND 3.4 ND 2.80 1.20 ND ND 01/12/12 0.8 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/12/12 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 02/06/13 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/09/13 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/31/14 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 07/23/14 --- 10 ND ND ND ND ND ND ND ND ND ND ND ND ND 01/27/15 3.9 10 ND ND ND ND ND ND ND ND ND ND ND ND ND Holly Springs Closed C and D Landfill Permit No. 92-14 Page 2 of 3 Joyce Engineering TABLE 5 Historical Groundwater Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL SWSL MW-1R MW-10 MW-2 MW-3 MW-4 MW-5R MW-6 MW-7 MW-9 MW-11 MW-12 MW-13 Blanks Field Parameters pH 07/22/09 -- -- 7.20 6.70 6.19 5.94 5.47 6.03 5.97 5.35 5.20 5.46 5.04 5.61 -- S.U. 01/26/10 -- -- 6.80 6.46 6.04 6.18 5.38 5.76 5.90 5.14 5.07 5.39 5.38 5.50 -- 07/07/10 -- -- 6.64 6.24 6.52 6.13 5.72 6.00 6.04 5.29 5.35 5.68 5.40 5.89 -- 01/05/11 -- -- 6.79 6.12 6.18 5.99 5.54 5.92 5.88 5.6 5.39 5.69 5.45 5.84 -- 07/07/11 -- -- 6.66 5.93 6.25 5.95 5.31 5.78 5.60 5.16 5.10 5.38 5.23 5.67 -- 01/12/12 -- -- 7.06 6.41 6.39 6.14 5.78 7.73 7.81 6.24 5.40 6.35 5.66 5.99 -- 07/12/12 -- -- 7.16 6.74 6.56 6.30 5.78 6.19 6.10 5.49 5.33 5.73 5.58 5.99 -- 02/06/13 -- -- 6.80 6.49 6.25 6.13 5.64 6.19 6.09 5.95 5.33 5.70 5.38 5.86 -- 07/09/13 -- -- 7.05 6.59 6.60 5.61 5.08 6.19 5.99 5.29 5.3 5.50 5.95 5.48 -- 01/31/14 -- -- 7.06 6.96 6.87 6.29 6.71 6.45 6.75 6.02 6.13 6.10 6.29 7.19 -- 07/23/14 --- --- 6.72 6.37 6.14 6.5 5.90 6.05 5.32 5.16 5.25 5.77 5.42 5.72 --- 01/27/15 FIELD FIELD 5.84 5.45 6.05 6.03 5.39 6.06 5.80 5.65 5.23 5.95 5.75 5.53 --- Conductivity 07/22/09 -- -- 295 188 283 93.0 104 676 322 168 640 907 526 477 -- µS/cm 01/26/10 -- -- 296 186 283 99.0 100 673 376 151 791 934 503 444 -- 07/07/10 -- -- 276 154 266 95.0 106 717 315 197 729 852 590 432 -- 01/05/11 -- -- 272 143 294 111.0 114 757 337 162 889 966 629 471 -- 07/07/11 -- -- 264 137 249 93.0 103 676 319 191 793 774 605 460 -- 01/12/12 -- -- 218 166 254 87.0 95 558 271 137 709 709 621 424 -- 07/12/12 -- -- 248 142.2 225.9 86.5 97.6 621 294 192.7 685 687 597 445.6 -- 02/06/13 -- -- 257 157.8 215.2 79.4 100.6 517 278.9 114.7 692 683 201 406.3 -- 07/09/13 -- -- 238 6.59 195.1 69.7 87.8 538 249.3 45.1 572 554 587 372 -- 01/31/14 -- -- 220 14.0 220.7 77.9 100.6 589 282.6 158.4 631 752 429 368.2 -- 07/23/14 --- --- 262 118.0 236.0 92.3 115.7 648 309.1 198 629 776 673 472.3 --- 01/27/15 FIELD FIELD 2361 114.3 199.8 65.2 109.6 573 283.2 146.7 676 596 532 363.3 --- Temperature 07/22/09 -- -- 22.31 17.98 19.84 20.64 18.96 17.43 18.57 18.84 18.23 17.03 19.23 28.29 -- °C 01/26/10 -- -- 16.22 15.72 12.89 10.09 15.73 13.39 13.26 12.3 13.23 14.52 14.32 12.67 -- 07/07/10 -- -- 20.97 23.07 19.09 22.46 18.97 18.5 19.44 19.23 17.75 19.28 17.33 18.5 -- 01/05/11 -- -- 15.19 13.16 13.22 16.14 15.76 12.97 15.94 13.68 13.98 14.46 14.09 14.64 -- 07/07/11 -- -- 19 21.21 21.2 22.05 19.5 17.96 19.23 21.14 20.17 18.59 17.07 18.41 -- 01/12/12 -- -- 13.33 14.55 16.48 17.55 17 14.24 15.27 14.76 15.56 15.88 14.97 14.78 -- 07/12/12 -- -- 18.8 19.60 19.4 20.70 18.2 18.1 18.40 18.8 17.80 18.40 16.2 20.9 -- 02/06/13 -- -- 13.9 17.40 17.2 16.90 16.5 14.8 16.20 14.9 14.90 15.60 14.5 14.6 -- 07/09/13 -- -- 22.5 17.10 17.3 17.20 16.2 15.7 16.20 15.3 15.30 15.30 16 17 -- 01/31/14 -- -- 12.7 16.70 15.6 14.50 15.7 14.5 15.00 14.1 14.40 14.70 14.1 14 -- 07/23/14 --- --- 19.6 19.10 19.1 ---16.9 16.3 17.70 16.4 16.40 18.30 15.9 17.7 --- 01/27/15 FIELD FIELD 12.7 16.9 15.4 15.1 15.9 13.8 15.1 13.5 13.7 13.8 13.9 13.7 --- Turbidity 07/22/09 -- -- 7.51 10.80 5.82 11.20 2.52 4.17 8.48 12 51.60 96.30 42.40 22.40 -- NTU 01/26/10 -- -- 135.0 1.95 1.6 5.51 1.19 0.7 2.89 1 64.60 1.82 43.90 78.60 -- 07/07/10 -- -- 7.7 0.61 5.2 3.98 1.97 0.7 1.43 1.72 62.20 1.1 2.30 66.70 -- 01/05/11 -- -- 0.3 0.97 1.6 2.70 1.7 0.4 0.44 0.41 66.70 0.92 5.89 17.50 -- 07/07/11 -- -- 0.4 5.69 3.9 3.31 2.26 1.3 0.84 1.88 91.5 5.0 2.39 52.40 -- 01/12/12 -- -- 8.8 0.73 1.2 8.43 6.81 6.2 6.23 11.11 30.10 19.30 4.45 9.55 -- 07/12/12 -- -- 3.1 1.99 2.6 9.10 3.77 3.3 4.62 2.73 16.7 3.41 4.76 5.67 -- 02/06/13 -- -- 16.5 12.60 4.7 16.70 2.5 --13.40 4.27 16.00 6.02 44.90 ---- 07/09/13 -- -- 5.4 5.03 7.6 7.81 5.8 7.1 9.37 8.72 15.3 5.29 48.20 6.15 -- 01/31/14 -- -- 4.1 5.81 4.9 4.02 3.99 4.2 5.89 5.32 8.4 5.11 4.40 4.02 -- 07/23/14 --- --- 4.6 3.25 3.8 25.0 4.34 3.5 3.44 5.5 6.3 6.51 5.02 27.10 --- 01/27/15 FIELD FIELD 3.95 3.64 1.83 34.3 1.06 1.14 1.1 0.95 17.4 21.8 5.93 729 --- Oxidation Reduction Potential 07/22/09 -- -- 75.4 92.10 44.1 56.70 108.1 95.4 104.10 128 127.4 118.30 67.30 -20.30 -- mV 01/26/10 -- -- --121.10 132.9 175.50 190.3 156.8 115.10 220.1 192.6 174.10 122.20 101.00 -- 07/07/10 -- -- -71.7 -39.30 -3.1 -20.70 53.8 6.2 -31.40 65.9 -46.5 -47.20 -101.10 -116.00 -- 01/05/11 -- -- 46.1 94.10 114.2 109.80 153.5 190.6 173.60 149.5 262.5 139.50 81.70 124.30 -- 07/07/11 -- -- -0.7 104.70 17.0 104.50 77 69.7 79.60 67.2 104.0 18.00 -26.20 77.90 -- 01/12/12 -- -- -39 249.20 83 150.60 61.3 174 -237.80 24.8 201.1 26.70 -18.20 -4.10 -- 07/12/12 -- -- 77.8 67.60 25.7 71.50 125.2 138.4 123.70 137.1 110.2 145.90 4.10 -28.60 -- 02/06/13 -- -- 139.1 131.30 89.3 98.00 179.6 63.2 278.90 182 137.4 211.30 80.20 55.10 -- 07/09/13 -- -- 88.20 159.50 53.10 106.60 174.1 121.90 5.40 169.4 103.10 144.20 100.00 67.90 -- 01/31/14 -- -- 10.80 60.20 65.10 97.60 92.3 51.30 71.00 124.2 100.60 60.20 95.00 48.90 -- 07/23/14 --- --- 765.0 49.1 75.8 29.7 84.2 -567.0 29.2 94.2 98.2 57.5 792.0 80.0 --- 01/27/15 FIELD FIELD 1239.0 125.0 100.4 120.8 142.1 127.1 115.4 140.1 142.3 137.3 105.6 102.4 --- Dissolved Oxygen 07/22/09 -- -- 3.50 4.16 3.31 3.80 1.58 0.53 1.53 0.67 0.42 0.40 0.67 0.78 -- mg/L 01/26/10 -- -- --7.70 4.64 8.96 4.01 3.43 5.18 6.51 1.76 7.60 1.27 1.89 -- 07/07/10 -- -- 3.70 6.40 4.30 3.60 2.59 2.17 1.03 0.5 0.28 0.57 0.83 0.46 -- 01/05/11 -- -- 1.32 4.36 2.16 4.04 2.72 3.92 2.19 4.66 2.46 4.63 0.73 1.26 -- 07/07/11 -- -- 2.63 5.88 3.12 3.88 3.83 1.18 0.90 0.9 0.71 0.89 0.99 0.63 -- 01/12/12 -- -- 0.69 3.03 2.04 5.50 2.19 2.51 1.00 4.07 2.87 6.18 3.01 0.70 -- 07/12/12 -- -- 3.68 5.72 0.96 3.38 2.37 0.21 0.52 0.3 0.73 0.33 0.27 0.26 -- 02/06/13 -- -- 1.67 2.50 1.48 5.29 4.11 2.99 2.97 5.41 0.86 2.96 0.28 0.88 -- 07/09/13 -- -- 5.25 6.89 0.80 0.49 2.66 0.51 0.22 1.29 0.57 0.86 1.58 1.07 -- 01/31/14 -- -- 2.94 3.98 0.43 5.79 2.2 2.88 1.24 2.8 1.04 7.65 2.38 1.61 -- 07/23/14 --- --- 4.51 5.60 1.42 5.25 2.1 0.98 0.84 1.06 1.77 3.40 1.23 1.12 --- 01/27/15 FIELD FIELD 2.07 5.84 4.95 7.14 2.38 3.36 1.87 3.95 2.49 8.11 1.38 2.69 --- Notes: DL = Method Detection Limit. SWSL = NC-DENR Solid Waste Section Limit. NC 2L = Groundwater Standard established in 15 A NCAC 2L.0202 GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L. ND = Not detected above the DL. J = Estimated concentration below the RL. B = Blank qualified data. dry = Insufficient water to sample. --- = No data. mg/L = milligrams per liter µg/L = micrograms per liter S.U. = Standard Units. NTU = Nephelometric Turbidity Units. µS/cm= microsiemens per centimeter. mV = Millivolts. Bold = Concentrations above the NC 2L or Groundwater Protection standards (GWPS) have been bolded.Blanks = field, trip and/or method blanks.All data prior to 2012 taken from previous reports by Golder Associates NC, Inc. Holly Springs Closed C and D Landfill Permit No. 92-14 Page 3 of 3 Joyce Engineering TABLE 6 Historical Surface Water Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Inorganic Compounds Total Arsenic 07/22/09 --- --- dry dry --- NC 2B = 50 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 ND ND ND07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry ND ND07/09/13 --- 10.0 ND 2.39 J ND 01/31/14 --- 10.0 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 1.13 10.0 ND ND ND Total Barium 07/22/09 --- --- dry dry --- No NC 2B Standard 01/26/10 10 100 45.2 J 52.3 J 0.66 J 07/07/10 10 100 dry dry ND 01/05/11 10 100 dry 39.1 J ND 07/07/11 10 100 dry 43.8 J ND 01/12/12 --- 100 74.2 J 48.1 J 0.90 J 07/12/12 --- 100 dry 35.1 J 1.47 J 02/06/13 --- 100 dry 59.8 J 1.05 J 07/09/13 --- 100 51.2 J 79.4 J 0.46 J 01/31/14 --- 100 dry 65.2 J ND 07/23/14 --- --- dry dry --- 01/27/15 0.10 100 37.1 J 75.9 J 0.17 J Total Cadmium 07/22/09 --- --- dry dry --- NC 2B = 2 µg/L 01/26/10 1 1.00 0.14 B ND 0.14 J 07/07/10 1 1.00 dry dry ND01/05/11 1 1.00 dry ND ND 07/07/11 1 1.00 dry ND ND01/12/12 --- 1.00 ND ND ND 07/12/12 --- 1.00 dry ND ND02/06/13 --- 1.00 dry ND ND 07/09/13 --- 1.00 ND 0.07 J ND 01/31/14 --- 1.00 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 0.05 1.00 ND ND ND Total Chromium 07/22/09 --- --- dry dry --- NC 2B = 50 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND 07/07/11 10 10.0 dry 1.85 J ND 01/12/12 --- 10.0 2.45 B 2.56 B 0.82 J 07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry 1.46 B 1.42 J 07/09/13 --- 10.0 3.12 B 3.03 B 3.51 J 01/31/14 --- 10.0 dry 0.97 B 2.79 J 07/23/14 --- --- dry dry --- 01/27/15 0.73 10.0 ND 3.31 J ND Total Lead 07/22/09 --- --- dry dry --- NC 2B = 25 µg/L 01/26/10 10 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 1.52 J 0.35 J ND07/12/12 --- 10.0 dry 0.17 J ND 02/06/13 --- 10.0 dry ND ND07/09/13 --- 10.0 1.26 J 4.50 J 0.08 J 01/31/14 --- 10.0 dry 0.08 J ND 07/23/14 --- --- dry dry --- 01/27/15 0.05 10.0 0.59 J 0.31 J ND Holly Springs Closed C and D Landfill Permit No. 92-14 1 of 4 Joyce Engineering TABLE 6 Historical Surface Water Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Total Mercury 07/22/09 --- --- dry dry --- NC 2B = 0.012 µg/L 01/26/10 0.2 0.200 0.06 J ND ND 07/07/10 0.2 0.200 dry dry ND 01/05/11 0.2 0.200 dry ND ND 07/07/11 0.2 0.200 dry ND ND01/12/12 --- 0.200 ND ND ND 07/12/12 --- 0.200 dry ND ND02/06/13 --- 0.200 dry ND ND 07/09/13 --- 0.200 0.08 J ND ND01/31/14 --- 0.200 dry ND 0.114 J 07/23/14 --- --- dry dry --- 01/27/15 0.064 0.200 ND ND ND Total Selenium 07/22/09 --- --- dry dry --- NC 2B = 5 µg/L 01/26/10 1 10.0 ND ND ND 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND 3.01 J 07/07/11 10 10.0 dry ND 3.21 J 01/12/12 --- 10.0 ND 0.81 J ND 07/12/12 --- 10.0 dry 0.72 J ND 02/06/13 --- 10.0 dry 1.59 J ND 07/09/13 --- 10.0 ND 1.65 J ND 01/31/14 --- 10.0 dry 1.19 J ND 07/23/14 --- --- dry dry --- 01/27/15 1.01 10.0 ND ND ND Total Silver 07/22/09 --- --- dry dry --- NC 2B = 0.06 µg/L 01/26/10 10 10.0 ND ND 0.73 J 07/07/10 10 10.0 dry dry ND 01/05/11 10 10.0 dry ND ND07/07/11 10 10.0 dry ND ND 01/12/12 --- 10.0 ND ND ND07/12/12 --- 10.0 dry ND ND 02/06/13 --- 10.0 dry ND ND07/09/13 --- 10.0 ND ND ND 01/31/14 --- 10.0 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 0.17 10.0 ND ND ND Organic Compounds Acetone 01/26/10 5 100 ND ND ND No NC 2B Standard 07/07/10 5 100 dry dry ND 01/05/11 5 100 dry ND ND 07/07/11 5 100 dry 4.4 J ND 01/12/12 --- 100 ND ND ND 07/12/12 --- 100 dry ND ND 02/06/13 --- 100 dry ND ND 07/09/13 --- 100 1.80 B 3.50 B 2.40 J 01/31/14 --- 100 dry ND ND 07/23/14 --- --- dry dry --- 01/27/15 5.7 100.0 ND ND ND Holly Springs Closed C and D Landfill Permit No. 92-14 2 of 4 Joyce Engineering TABLE 6 Historical Surface Water Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Field Parameters pH 07/22/09 --- --- dry dry --- S.U. 01/26/10 --- --- 6.65 5.71 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 6.43 ---07/07/11 --- --- dry 6.87 --- 01/12/12 --- --- 5.83 6.92 ---07/12/12 --- --- dry 7.25 --- 02/06/13 --- --- dry 6.63 ---07/09/13 --- --- 6.33 6.29 --- 01/31/14 --- --- dry 6.76 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 6.07 6.30 --- Conductivity 07/22/09 --- --- dry dry --- µS/cm 01/26/10 --- --- 49.00 191.0 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 190.0 --- 07/07/11 --- --- dry 430.0 --- 01/12/12 --- --- 115.00 527.0 --- 07/12/12 --- --- dry 383.5 --- 02/06/13 --- --- dry 652.9 --- 07/09/13 --- --- 99.90 771.0 --- 01/31/14 --- --- dry 506.0 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 260.9 397.2 --- Temperature 07/22/09 --- --- dry dry --- °C 01/26/10 --- --- 6.71 9.16 --- 07/07/10 --- --- dry dry ---01/05/11 --- --- dry 5.85 --- 07/07/11 --- --- dry 21.94 ---01/12/12 --- --- 10.2 11.02 --- 07/12/12 --- --- dry 23.00 ---02/06/13 --- --- dry 10.60 --- 07/09/13 --- --- 24.20 23.90 --- 01/31/14 --- --- dry 4.50 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 7.0 6.5 --- Turbidity 07/22/09 --- --- dry dry --- NTU 01/26/10 --- --- 7.79 1.70 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 5.33 --- 07/07/11 --- --- dry 22.30 --- 01/12/12 --- --- 25.50 13.87 --- 07/12/12 --- --- dry 45.00 --- 02/06/13 --- --- dry 4.60 --- 07/09/13 --- --- 21.20 6.29 --- 01/31/14 --- --- dry 3.30 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 15.10 3.76 --- Oxidation Reduction Potential 07/22/09 --- --- dry dry --- mV 01/26/10 --- --- 212.90 20.0 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 117.8 ---07/07/11 --- --- dry 19.2 --- 01/12/12 --- --- 16.30 100.8 --- 07/12/12 --- --- dry 95.0 --- 02/06/13 --- --- dry 37.0 --- 07/09/13 --- --- -0.90 80.4 --- 01/31/14 --- --- dry 86.0 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 114.7 32.0 --- Holly Springs Closed C and D Landfill Permit No. 92-14 3 of 4 Joyce Engineering TABLE 6 Historical Surface Water Constituents/Analytes Closed Holly Springs C and D Landfill, Permit No. 92-14 Wake County, North Carolina Analyte Sample Collection Date DL RL SW-1 SW-2 Blanks Dissolved Oxygen 07/22/09 --- --- dry dry --- mg/L 01/26/10 --- --- 11.50 11.49 --- 07/07/10 --- --- dry dry --- 01/05/11 --- --- dry 10.22 --- 07/07/11 --- --- dry 6.05 --- 01/12/12 --- --- 7.94 7.87 --- 07/12/12 --- --- dry 2.15 --- 02/06/13 --- --- dry 9.12 --- 07/09/13 --- --- 5.0 6.50 --- 01/31/14 --- --- dry 13.98 --- 07/23/14 --- --- dry dry --- 01/27/15 FIELD FIELD 12.90 12.67 --- Notes: DL = Method Detection Limit. SWSL = NC-DENR Solid Waste Section Limit. NC 2B = Surface Water Standard established in 15A NCAC 2B (NC Freshwater Aquatic Life Standards - Little Branch - Class C Waters) ND = Not detected above the DL. J = Estimated concentration below the SWSL. B = Blank qualified data. dry = Insufficient water flow for sampling. --- = No data. mg/L = milligrams per liter µg/L = micrograms per liter S.U. = Standard Units. NTU = Nephelometric Turbidity Units. µS/cm= microsiemens per centimeter. mV = Millivolts. Bold = Concentrations above the NC 2B Standards. Blanks = field, trip and/or method blanks. All data prior to 2012 taken from previous reports by Golder Associates NC, Inc. Holly Springs Closed C and D Landfill Permit No. 92-14 4 of 4 Joyce Engineering TABLE 7 Field Parameters by Location - January 2015 Sample ID Sample Date Parameter Result Units MW-10 1/27/2015 Temperature 16.9 ºC MW-10 1/27/2015 Dissolved Oxygen 5.84 mg/L MW-10 1/27/2015 Conductivity 114.3 µS MW-10 1/27/2015 pH 5.45 S.U. MW-10 1/27/2015 Oxidation Reduction Potential 125.0 mV MW-10 1/27/2015 Turbidity 3.64 ntu MW-10 1/27/2015 Static Water Level 18.92 ft MW-10 1/27/2015 Well Depth 47.00 ft MW-11 1/27/2015 Temperature 13.8 ºC MW-11 1/27/2015 Dissolved Oxygen 8.11 mg/L MW-11 1/27/2015 Conductivity 5.96 µS MW-11 1/27/2015 pH 5.95 S.U. MW-11 1/27/2015 Oxidation Reduction Potential 137.3 mV MW-11 1/27/2015 Turbidity 21.80 ntu MW-11 1/27/2015 Static Water Level 10.00 ft MW-11 1/27/2015 Well Depth 25.75 ft MW-12 1/27/2015 Temperature 13.9 ºC MW-12 1/27/2015 Dissolved Oxygen 1.38 mg/L MW-12 1/27/2015 Conductivity 532 µS MW-12 1/27/2015 pH 5.75 S.U. MW-12 1/27/2015 Oxidation Reduction Potential 105.6 mV MW-12 1/27/2015 Turbidity 5.93 ntu MW-12 1/27/2015 Static Water Level 8.45 ft MW-12 1/27/2015 Well Depth 25.19 ft MW-13 1/27/2015 Temperature 13.7 ºC MW-13 1/27/2015 Dissolved Oxygen 2.69 mg/L MW-13 1/27/2015 Conductivity 363.3 µS MW-13 1/27/2015 pH 5.53 S.U. MW-13 1/27/2015 Oxidation Reduction Potential 102.4 mV MW-13 1/27/2015 Turbidity 729 ntu MW-13 1/27/2015 Static Water Level 9.85 ft MW-13 1/27/2015 Well Depth 26.68 ft MW-1R 1/27/2015 Temperature 12.7 ºC MW-1R 1/27/2015 Dissolved Oxygen 2.07 mg/L MW-1R 1/27/2015 Conductivity 2361 µS MW-1R 1/27/2015 pH 5.84 S.U. MW-1R 1/27/2015 Oxidation Reduction Potential 1239 mV MW-1R 1/27/2015 Turbidity 3.95 ntu MW-1R 1/27/2015 Static Water Level 18.33 ft MW-1R 1/27/2015 Well Depth 54.60 ft Holly Springs Closed C+D Landfill Permit No. 92-14 Page 1 of 3 Joyce Engineering TABLE 7 Field Parameters by Location - January 2015 Sample ID Sample Date Parameter Result Units MW-2 1/27/2015 Temperature 15.4 ºC MW-2 1/27/2015 Dissolved Oxygen 4.95 mg/L MW-2 1/27/2015 Conductivity 199.8 µS MW-2 1/27/2015 pH 6.05 S.U. MW-2 1/27/2015 Oxidation Reduction Potential 100.4 mV MW-2 1/27/2015 Turbidity 1.83 ntu MW-2 1/27/2015 Static Water Level 36.45 ft MW-2 1/27/2015 Well Depth 47.50 ft MW-3 1/27/2015 Temperature 15.1 ºC MW-3 1/27/2015 Dissolved Oxygen 7.14 mg/L MW-3 1/27/2015 Conductivity 65.2 µS MW-3 1/27/2015 pH 6.03 S.U. MW-3 1/27/2015 Oxidation Reduction Potential 120.8 mV MW-3 1/27/2015 Turbidity 34.30 ntu MW-3 1/27/2015 Static Water Level 5.92 ft MW-3 1/27/2015 Well Depth 35.39 ft MW-4 1/27/2015 Temperature 15.9 ºC MW-4 1/27/2015 Dissolved Oxygen 2.38 mg/L MW-4 1/27/2015 Conductivity 109.6 µS MW-4 1/27/2015 pH 5.39 S.U. MW-4 1/27/2015 Oxidation Reduction Potential 142.1 mV MW-4 1/27/2015 Turbidity 1.06 ntu MW-4 1/27/2015 Static Water Level 16.94 ft MW-4 1/27/2015 Well Depth 34.88 ft MW-5R 1/27/2015 Temperature 13.8 ºC MW-5R 1/27/2015 Dissolved Oxygen 3.36 mg/L MW-5R 1/27/2015 Conductivity 573 µS MW-5R 1/27/2015 pH 6.06 S.U. MW-5R 1/27/2015 Oxidation Reduction Potential 127.1 mV MW-5R 1/27/2015 Turbidity 1.14 ntu MW-5R 1/27/2015 Static Water Level 4.67 ft MW-5R 1/27/2015 Well Depth 24.21 ft MW-6 1/27/2015 Temperature 15.1 ºC MW-6 1/27/2015 Dissolved Oxygen 1.87 mg/L MW-6 1/27/2015 Conductivity 283.2 µS MW-6 1/27/2015 pH 5.80 S.U. MW-6 1/27/2015 Oxidation Reduction Potential 115.4 mV MW-6 1/27/2015 Turbidity 1.10 ntu MW-6 1/27/2015 Static Water Level 9.00 ft MW-6 1/27/2015 Well Depth 21.40 ft Holly Springs Closed C+D Landfill Permit No. 92-14 Page 2 of 3 Joyce Engineering TABLE 7 Field Parameters by Location - January 2015 Sample ID Sample Date Parameter Result Units MW-7 1/27/2015 Temperature 13.5 ºC MW-7 1/27/2015 Dissolved Oxygen 3.95 mg/L MW-7 1/27/2015 Conductivity 146.7 µS MW-7 1/27/2015 pH 5.65 S.U. MW-7 1/27/2015 Oxidation Reduction Potential 140.1 mV MW-7 1/27/2015 Turbidity 0.95 ntu MW-7 1/27/2015 Static Water Level 5.40 ft MW-7 1/27/2015 Well Depth 24.20 ft MW-9 1/27/2015 Temperature 13.7 ºC MW-9 1/27/2015 Dissolved Oxygen 2.49 mg/L MW-9 1/27/2015 Conductivity 676 µS MW-9 1/27/2015 pH 5.23 S.U. MW-9 1/27/2015 Oxidation Reduction Potential 142.3 mV MW-9 1/27/2015 Turbidity 17.4 ntu MW-9 1/27/2015 Static Water Level 10.51 ft MW-9 1/27/2015 Well Depth 23.80 ft SW-1 1/27/2015 Temperature 7.0 ºC SW-1 1/27/2015 Dissolved Oxygen 12.90 mg/L SW-1 1/27/2015 Conductivity 260.9 µS SW-1 1/27/2015 pH 6.07 S.U. SW-1 1/27/2015 Oxidation Reduction Potential 114.7 mV SW-1 1/27/2015 Turbidity 15.1 ntu SW-2 1/27/2015 Temperature 6.5 ºC SW-2 1/27/2015 Dissolved Oxygen 12.67 mg/L SW-2 1/27/2015 Conductivity 397.2 µS SW-2 1/27/2015 pH 6.30 S.U. SW-2 1/27/2015 Oxidation Reduction Potential 32.0 mV SW-2 1/27/2015 Turbidity 3.76 ntu ºC = degrees Centigrade mg/L = miligrams/Liter µS = microsemans S.U. = standard units mV = millivolts ntu = nephelometric turbidity units Holly Springs Closed C+D Landfill Permit No. 92-14 Page 3 of 3 Joyce Engineering Appendix B Groundwater and Surface Water Field Data Logs Appendix C Laboratory Analytical Reports ASI ANALYTICAL SERVICES, INC. Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 Republic Services of North Carolina, LLC Project: Holly Springs Closed C&D Landfill Conover, NC 28613 1220 Commerce Street, SW Mr. Matt Einsmann We appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Analytical Services, Inc. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed. Laboratory Report Project #:92-14 Prepared For: Attention: February 13, 2015 Report Number:AYA0701 Approved: This report may not be reproduced, except in full, without written approval from Analytical Services, Inc.Page 1 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Sample ID Laboratory ID Matrix Date Sampled ANALYTICAL REPORT FOR SAMPLES Date Received 9214-MW1R AYA0701-01 01/27/15 09:59 01/29/15 10:45Ground Water 9214-MW2 AYA0701-02 01/27/15 14:41 01/29/15 10:45Ground Water 9214-MW3 AYA0701-03 01/27/15 15:00 01/29/15 10:45Ground Water 9214-MW4 AYA0701-04 01/27/15 13:58 01/29/15 10:45Ground Water 9214-MW5R AYA0701-05 01/27/15 12:35 01/29/15 10:45Ground Water 9214-MW6 AYA0701-06 01/27/15 12:17 01/29/15 10:45Ground Water 9214-MW7 AYA0701-07 01/27/15 13:36 01/29/15 10:45Ground Water 9214-MW9 AYA0701-08 01/27/15 11:45 01/29/15 10:45Ground Water 9214-MW10 AYA0701-09 01/27/15 09:32 01/29/15 10:45Ground Water 9214-MW11 AYA0701-10 01/27/15 12:53 01/29/15 10:45Ground Water 9214-MW12 AYA0701-11 01/27/15 13:09 01/29/15 10:45Ground Water 9214-MW13 AYA0701-12 01/27/15 10:40 01/29/15 10:45Ground Water 9214-SW1 AYA0701-13 01/27/15 10:30 01/29/15 10:45Surface Water 9214-SW2 AYA0701-14 01/27/15 13:25 01/29/15 10:45Surface Water 9214-Field Blank AYA0701-15 01/27/15 15:30 01/29/15 10:45Water 9214-Trip Blank AYA0701-16 01/27/15 07:00 01/29/15 10:45Water Page 2 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AYA0701-01 AYA070101/27/15 09:59 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 1.61 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 19:5702/04/15 08:50 EPA 6020A 318 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 19:5702/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 19:5702/04/15 08:50 EPA 6020A 1.53 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 19:5702/04/15 08:50 EPA 6020A 0.33 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 19:5702/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 19:5702/04/15 08:50 EPA 6020A 0.21 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 19:5702/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:0702/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 11:0702/02/15 09:00 Page 3 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AYA0701-01 AYA070101/27/15 09:59 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 11:0702/02/15 09:00 Page 4 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW1R Ground Water AYA0701-01 AYA070101/27/15 09:59 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 11:0702/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 11:0702/02/15 09:00 EPA 8260B 96 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 11:0702/02/15 09:0080-120 EPA 8260B 103 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 11:0702/02/15 09:0078-120 EPA 8260B 101 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 11:0702/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 11:0702/02/15 09:0080-120 Page 5 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AYA0701-02 AYA070101/27/15 14:41 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 3.09 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:0302/04/15 08:50 EPA 6020A 71.4 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:0302/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:0302/04/15 08:50 EPA 6020A 1.74 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:0302/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:0302/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:0302/04/15 08:50 EPA 6020A 0.26 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:0302/04/15 08:50 EPA 7470A 0.163 ug/L1Mercury0.200 J 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:0902/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 11:3402/02/15 09:00 Page 6 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AYA0701-02 AYA070101/27/15 14:41 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 11:3402/02/15 09:00 Page 7 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW2 Ground Water AYA0701-02 AYA070101/27/15 14:41 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 11:3402/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 11:3402/02/15 09:00 EPA 8260B 100 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 11:3402/02/15 09:0080-120 EPA 8260B 104 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 11:3402/02/15 09:0078-120 EPA 8260B 100 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 11:3402/02/15 09:0080-120 EPA 8260B 101 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 11:3402/02/15 09:0080-120 Page 8 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AYA0701-03 AYA070101/27/15 15:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 3.30 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:0902/04/15 08:50 EPA 6020A 50.1 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:0902/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:0902/04/15 08:50 EPA 6020A 1.52 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:0902/04/15 08:50 EPA 6020A 1.44 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:0902/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:0902/04/15 08:50 EPA 6020A 0.18 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:0902/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:1102/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 12:0102/02/15 09:00 Page 9 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AYA0701-03 AYA070101/27/15 15:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 12:0102/02/15 09:00 Page 10 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW3 Ground Water AYA0701-03 AYA070101/27/15 15:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 12:0102/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 12:0102/02/15 09:00 EPA 8260B 98 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 12:0102/02/15 09:0080-120 EPA 8260B 103 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 12:0102/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 12:0102/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 12:0102/02/15 09:0080-120 Page 11 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AYA0701-04 AYA070101/27/15 13:58 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 2.76 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:1502/04/15 08:50 EPA 6020A 61.5 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:1502/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:1502/04/15 08:50 NDEPA 6020A ug/L1Chromium10.0 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:1502/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:1502/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:1502/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:1502/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:1402/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 12:2702/02/15 09:00 Page 12 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AYA0701-04 AYA070101/27/15 13:58 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 12:2702/02/15 09:00 Page 13 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW4 Ground Water AYA0701-04 AYA070101/27/15 13:58 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 12:2702/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 12:2702/02/15 09:00 EPA 8260B 99 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 12:2702/02/15 09:0080-120 EPA 8260B 104 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 12:2702/02/15 09:0078-120 EPA 8260B 98 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 12:2702/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 12:2702/02/15 09:0080-120 Page 14 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AYA0701-05 AYA070101/27/15 12:35 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total NDEPA 6020A ug/L1Arsenic10.0 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:2102/04/15 08:50 EPA 6020A 110 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:2102/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:2102/04/15 08:50 NDEPA 6020A ug/L1Chromium10.0 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:2102/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:2102/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:2102/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:2102/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:1602/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 12:5302/02/15 09:00 Page 15 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AYA0701-05 AYA070101/27/15 12:35 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 12:5302/02/15 09:00 Page 16 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW5R Ground Water AYA0701-05 AYA070101/27/15 12:35 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 12:5302/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 12:5302/02/15 09:00 EPA 8260B 99 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 12:5302/02/15 09:0080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 12:5302/02/15 09:0078-120 EPA 8260B 98 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 12:5302/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 12:5302/02/15 09:0080-120 Page 17 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AYA0701-06 AYA070101/27/15 12:17 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 1.21 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:2702/04/15 08:50 EPA 6020A 262 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:2702/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:2702/04/15 08:50 EPA 6020A 1.05 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:2702/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:2702/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:2702/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:2702/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:1802/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 13:2002/02/15 09:00 Page 18 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AYA0701-06 AYA070101/27/15 12:17 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 13:2002/02/15 09:00 Page 19 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW6 Ground Water AYA0701-06 AYA070101/27/15 12:17 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 13:2002/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 13:2002/02/15 09:00 EPA 8260B 99 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 13:2002/02/15 09:0080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 13:2002/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 13:2002/02/15 09:0080-120 EPA 8260B 97 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 13:2002/02/15 09:0080-120 Page 20 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AYA0701-07 AYA070101/27/15 13:36 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 1.83 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:3202/04/15 08:50 EPA 6020A 112 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:3202/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:3202/04/15 08:50 NDEPA 6020A ug/L1Chromium10.0 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:3202/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:3202/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:3202/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:3202/04/15 08:50 EPA 7470A 0.275 ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:2102/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 09:2102/02/15 09:00 EPA 8260B 0.2 ug/L1Chloroform5.0 J 5020008EPA 5030B 0.2 67-66-3 02/02/15 09:2102/02/15 09:00 Page 21 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AYA0701-07 AYA070101/27/15 13:36 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 09:2102/02/15 09:00 Page 22 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW7 Ground Water AYA0701-07 AYA070101/27/15 13:36 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 09:2102/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 09:2102/02/15 09:00 EPA 8260B 97 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 09:2102/02/15 09:0080-120 EPA 8260B 104 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 09:2102/02/15 09:0078-120 EPA 8260B 100 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 09:2102/02/15 09:0080-120 EPA 8260B 99 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 09:2102/02/15 09:0080-120 Page 23 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AYA0701-08 AYA070101/27/15 11:45 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 2.59 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:3802/04/15 08:50 EPA 6020A 83.4 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:3802/04/15 08:50 EPA 6020A 0.08 ug/L1Cadmium1.00 J 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:3802/04/15 08:50 EPA 6020A 2.69 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:3802/04/15 08:50 EPA 6020A 2.15 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:3802/04/15 08:50 EPA 6020A 3.62 ug/L1Selenium10.0 J 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:3802/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:3802/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:2802/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 13:4602/02/15 09:00 Page 24 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AYA0701-08 AYA070101/27/15 11:45 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 13:4602/02/15 09:00 Page 25 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW9 Ground Water AYA0701-08 AYA070101/27/15 11:45 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 13:4602/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 13:4602/02/15 09:00 EPA 8260B 101 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 13:4602/02/15 09:0080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 13:4602/02/15 09:0078-120 EPA 8260B 101 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 13:4602/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 13:4602/02/15 09:0080-120 Page 26 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AYA0701-09 AYA070101/27/15 09:32 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 5.13 ug/L1Arsenic10.0 J 5020064EPA 3005A 1.13 7440-38-2 02/04/15 20:4402/04/15 08:50 EPA 6020A 24.0 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 20:4402/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 20:4402/04/15 08:50 EPA 6020A 3.08 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 20:4402/04/15 08:50 NDEPA 6020A ug/L1Lead10.0 5020064EPA 3005A 0.05 7439-92-1 02/04/15 20:4402/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 20:4402/04/15 08:50 EPA 6020A 0.24 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 20:4402/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:3002/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 14:1302/02/15 09:00 Page 27 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AYA0701-09 AYA070101/27/15 09:32 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 14:1302/02/15 09:00 Page 28 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW10 Ground Water AYA0701-09 AYA070101/27/15 09:32 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 14:1302/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 14:1302/02/15 09:00 EPA 8260B 99 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 14:1302/02/15 09:0080-120 EPA 8260B 103 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 14:1302/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 14:1302/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 14:1302/02/15 09:0080-120 Page 29 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AYA0701-10 AYA070101/27/15 12:53 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total NDEPA 6020A ug/L1Arsenic10.0 5020064EPA 3005A 1.13 7440-38-2 02/04/15 21:0102/04/15 08:50 EPA 6020A 56.7 ug/L1Barium100 J 5020064EPA 3005A 0.10 7440-39-3 02/04/15 21:0102/04/15 08:50 EPA 6020A 0.07 ug/L1Cadmium1.00 J 5020064EPA 3005A 0.05 7440-43-9 02/04/15 21:0102/04/15 08:50 EPA 6020A 4.37 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 21:0102/04/15 08:50 EPA 6020A 1.35 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 21:0102/04/15 08:50 EPA 6020A 1.66 ug/L1Selenium10.0 J 5020064EPA 3005A 1.01 7782-49-2 02/04/15 21:0102/04/15 08:50 EPA 6020A 0.23 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 21:0102/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020177EPA 7470A 0.064 7439-97-6 02/10/15 13:4802/09/15 13:40 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 14:3902/02/15 09:00 Page 30 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AYA0701-10 AYA070101/27/15 12:53 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 14:3902/02/15 09:00 Page 31 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW11 Ground Water AYA0701-10 AYA070101/27/15 12:53 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 14:3902/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 14:3902/02/15 09:00 EPA 8260B 96 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 14:3902/02/15 09:0080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 14:3902/02/15 09:0078-120 EPA 8260B 98 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 14:3902/02/15 09:0080-120 EPA 8260B 101 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 14:3902/02/15 09:0080-120 Page 32 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AYA0701-11 AYA070101/27/15 13:09 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 21.6 ug/L1Arsenic10.0 5020064EPA 3005A 1.13 7440-38-2 02/04/15 21:0702/04/15 08:50 EPA 6020A 186 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 21:0702/04/15 08:50 EPA 6020A 0.09 ug/L1Cadmium1.00 J 5020064EPA 3005A 0.05 7440-43-9 02/04/15 21:0702/04/15 08:50 NDEPA 6020A ug/L1Chromium10.0 5020064EPA 3005A 0.73 7440-47-3 02/04/15 21:0702/04/15 08:50 EPA 6020A 0.05 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 21:0702/04/15 08:50 EPA 6020A 2.41 ug/L1Selenium10.0 J 5020064EPA 3005A 1.01 7782-49-2 02/04/15 21:0702/04/15 08:50 NDEPA 6020A ug/L1Silver10.0 5020064EPA 3005A 0.17 7440-22-4 02/04/15 21:0702/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020033EPA 7470A 0.064 7439-97-6 02/04/15 14:3202/03/15 13:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 15:0602/02/15 09:00 EPA 8260B 0.2 ug/L1Benzene1.0 J 5020008EPA 5030B 0.2 71-43-2 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 15:0602/02/15 09:00 Page 33 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AYA0701-11 AYA070101/27/15 13:09 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 15:0602/02/15 09:00 Page 34 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW12 Ground Water AYA0701-11 AYA070101/27/15 13:09 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 15:0602/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 15:0602/02/15 09:00 EPA 8260B 100 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 15:0602/02/15 09:0080-120 EPA 8260B 104 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 15:0602/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 15:0602/02/15 09:0080-120 EPA 8260B 98 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 15:0602/02/15 09:0080-120 Page 35 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AYA0701-12 AYA070101/27/15 10:40 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total EPA 6020A 10.8 ug/L1Arsenic10.0 5020064EPA 3005A 1.13 7440-38-2 02/04/15 21:1302/04/15 08:50 EPA 6020A 629 ug/L1Barium100 5020064EPA 3005A 0.10 7440-39-3 02/04/15 21:1302/04/15 08:50 NDEPA 6020A ug/L1Cadmium1.00 5020064EPA 3005A 0.05 7440-43-9 02/04/15 21:1302/04/15 08:50 EPA 6020A 3.37 ug/L1Chromium10.0 J 5020064EPA 3005A 0.73 7440-47-3 02/04/15 21:1302/04/15 08:50 EPA 6020A 1.88 ug/L1Lead10.0 J 5020064EPA 3005A 0.05 7439-92-1 02/04/15 21:1302/04/15 08:50 NDEPA 6020A ug/L1Selenium10.0 5020064EPA 3005A 1.01 7782-49-2 02/04/15 21:1302/04/15 08:50 EPA 6020A 3.11 ug/L1Silver10.0 J 5020064EPA 3005A 0.17 7440-22-4 02/04/15 21:1302/04/15 08:50 NDEPA 7470A ug/L1Mercury0.200 5020177EPA 7470A 0.064 7439-97-6 02/10/15 13:5002/09/15 13:40 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 15:3202/02/15 09:00 Page 36 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AYA0701-12 AYA070101/27/15 10:40 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 15:3202/02/15 09:00 Page 37 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-MW13 Ground Water AYA0701-12 AYA070101/27/15 10:40 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 15:3202/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 15:3202/02/15 09:00 EPA 8260B 100 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 15:3202/02/15 09:0080-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 15:3202/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 15:3202/02/15 09:0080-120 EPA 8260B 99 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 15:3202/02/15 09:0080-120 Page 38 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW1 Surface Water AYA0701-13 AYA070101/27/15 10:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total NDEPA 6020A ug/L1Arsenic10.0 5020134EPA 3005A 1.13 7440-38-2 02/06/15 13:4002/06/15 08:15 EPA 6020A 37.1 ug/L1Barium100 J 5020134EPA 3005A 0.10 7440-39-3 02/06/15 13:4002/06/15 08:15 NDEPA 6020A ug/L1Cadmium1.00 5020134EPA 3005A 0.05 7440-43-9 02/06/15 13:4002/06/15 08:15 NDEPA 6020A ug/L1Chromium10.0 5020134EPA 3005A 0.73 7440-47-3 02/06/15 13:4002/06/15 08:15 EPA 6020A 0.59 ug/L1Lead10.0 J 5020134EPA 3005A 0.05 7439-92-1 02/06/15 13:4002/06/15 08:15 NDEPA 6020A ug/L1Selenium10.0 5020134EPA 3005A 1.01 7782-49-2 02/06/15 13:4002/06/15 08:15 NDEPA 6020A ug/L1Silver10.0 5020134EPA 3005A 0.17 7440-22-4 02/06/15 13:4002/06/15 08:15 NDEPA 7470A ug/L1Mercury0.200 5020177EPA 7470A 0.064 7439-97-6 02/10/15 13:5302/09/15 13:40 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 15:5902/02/15 09:00 Page 39 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW1 Surface Water AYA0701-13 AYA070101/27/15 10:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 15:5902/02/15 09:00 Page 40 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW1 Surface Water AYA0701-13 AYA070101/27/15 10:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 15:5902/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 15:5902/02/15 09:00 EPA 8260B 98 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 15:5902/02/15 09:0080-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 15:5902/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 15:5902/02/15 09:0080-120 EPA 8260B 99 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 15:5902/02/15 09:0080-120 Page 41 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AYA0701-14 AYA070101/27/15 13:25 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total NDEPA 6020A ug/L1Arsenic10.0 5020134EPA 3005A 1.13 7440-38-2 02/06/15 13:4502/06/15 08:15 EPA 6020A 75.9 ug/L1Barium100 J 5020134EPA 3005A 0.10 7440-39-3 02/06/15 13:4502/06/15 08:15 NDEPA 6020A ug/L1Cadmium1.00 5020134EPA 3005A 0.05 7440-43-9 02/06/15 13:4502/06/15 08:15 EPA 6020A 3.31 ug/L1Chromium10.0 J 5020134EPA 3005A 0.73 7440-47-3 02/06/15 13:4502/06/15 08:15 EPA 6020A 0.31 ug/L1Lead10.0 J 5020134EPA 3005A 0.05 7439-92-1 02/06/15 13:4502/06/15 08:15 NDEPA 6020A ug/L1Selenium10.0 5020134EPA 3005A 1.01 7782-49-2 02/06/15 13:4502/06/15 08:15 NDEPA 6020A ug/L1Silver10.0 5020134EPA 3005A 0.17 7440-22-4 02/06/15 13:4502/06/15 08:15 NDEPA 7470A ug/L1Mercury0.200 5020177EPA 7470A 0.064 7439-97-6 02/10/15 13:5502/09/15 13:40 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 16:2602/02/15 09:00 Page 42 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AYA0701-14 AYA070101/27/15 13:25 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 16:2602/02/15 09:00 Page 43 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-SW2 Surface Water AYA0701-14 AYA070101/27/15 13:25 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 16:2602/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 16:2602/02/15 09:00 EPA 8260B 97 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 16:2602/02/15 09:0080-120 EPA 8260B 106 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 16:2602/02/15 09:0078-120 EPA 8260B 100 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 16:2602/02/15 09:0080-120 EPA 8260B 100 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 16:2602/02/15 09:0080-120 Page 44 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AYA0701-15 AYA070101/27/15 15:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Metals, Total NDEPA 6020A ug/L1Arsenic10.0 5020134EPA 3005A 1.13 7440-38-2 02/06/15 13:5002/06/15 08:15 EPA 6020A 0.17 ug/L1Barium100 J 5020134EPA 3005A 0.10 7440-39-3 02/06/15 13:5002/06/15 08:15 NDEPA 6020A ug/L1Cadmium1.00 5020134EPA 3005A 0.05 7440-43-9 02/06/15 13:5002/06/15 08:15 NDEPA 6020A ug/L1Chromium10.0 5020134EPA 3005A 0.73 7440-47-3 02/06/15 13:5002/06/15 08:15 NDEPA 6020A ug/L1Lead10.0 5020134EPA 3005A 0.05 7439-92-1 02/06/15 13:5002/06/15 08:15 NDEPA 6020A ug/L1Selenium10.0 5020134EPA 3005A 1.01 7782-49-2 02/06/15 13:5002/06/15 08:15 NDEPA 6020A ug/L1Silver10.0 5020134EPA 3005A 0.17 7440-22-4 02/06/15 13:5002/06/15 08:15 NDEPA 7470A ug/L1Mercury0.200 5020177EPA 7470A 0.064 7439-97-6 02/10/15 13:5702/09/15 13:40 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 16:5202/02/15 09:00 Page 45 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AYA0701-15 AYA070101/27/15 15:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 16:5202/02/15 09:00 Page 46 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Field Blank Water AYA0701-15 AYA070101/27/15 15:30 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 16:5202/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 16:5202/02/15 09:00 EPA 8260B 98 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 16:5202/02/15 09:0080-120 EPA 8260B 105 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 16:5202/02/15 09:0078-120 EPA 8260B 99 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 16:5202/02/15 09:0080-120 EPA 8260B 102 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 16:5202/02/15 09:0080-120 Page 47 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AYA0701-16 AYA070101/27/15 07:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L1Acetone100 5020008EPA 5030B 5.7 67-64-1 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Acrylonitrile200 5020008EPA 5030B 0.6 107-13-1 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Benzene1.0 5020008EPA 5030B 0.2 71-43-2 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Bromochloromethane3.0 5020008EPA 5030B 0.3 74-97-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Bromodichloromethane1.0 5020008EPA 5030B 0.5 75-27-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Bromoform3.0 5020008EPA 5030B 0.7 75-25-2 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Bromomethane10 5020008EPA 5030B 1.6 74-83-9 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Carbon Disulfide 100 5020008EPA 5030B 0.8 75-15-0 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Carbon Tetrachloride 1.0 5020008EPA 5030B 0.6 56-23-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Chlorobenzene3.0 5020008EPA 5030B 0.2 108-90-7 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Chloroethane10 5020008EPA 5030B 0.3 75-00-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Chloroform5.0 5020008EPA 5030B 0.2 67-66-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Chloromethane1.0 5020008EPA 5030B 0.2 74-87-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Dibromochloromethane3.0 5020008EPA 5030B 1.1 124-48-1 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromo-3-chloropropane 13 5020008EPA 5030B 0.7 96-12-8 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,2-Dibromoethane 1.0 5020008EPA 5030B 0.3 106-93-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Dibromomethane10 5020008EPA 5030B 0.3 74-95-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichlorobenzene 5.0 5020008EPA 5030B 0.3 95-50-1 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,4-Dichlorobenzene 1.0 5020008EPA 5030B 0.3 106-46-7 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1trans-1,4-Dichloro-2-butene 100 5020008EPA 5030B 1.8 110-57-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,1-Dichloroethane 5.0 5020008EPA 5030B 0.2 75-34-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloroethane 1.0 5020008EPA 5030B 0.4 107-06-2 02/02/15 17:1902/02/15 09:00 Page 48 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AYA0701-16 AYA070101/27/15 07:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L11,1-Dichloroethene 5.0 5020008EPA 5030B 0.2 75-35-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1cis-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-59-2 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1trans-1,2-Dichloroethene 5.0 5020008EPA 5030B 0.2 156-60-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,2-Dichloropropane 1.0 5020008EPA 5030B 0.2 78-87-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1cis-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.8 10061-01-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1trans-1,3-Dichloropropene 1.0 5020008EPA 5030B 0.6 10061-02-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Ethylbenzene1.0 5020008EPA 5030B 0.2 100-41-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Iodomethane10 5020008EPA 5030B 1.5 74-88-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Methyl Butyl Ketone (2-Hexanone)50 5020008EPA 5030B 0.6 591-78-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Methylene Chloride 1.0 5020008EPA 5030B 0.6 75-09-2 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Methyl Ethyl Ketone (2-Butanone)100 5020008EPA 5030B 0.8 78-93-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L14-Methyl-2-pentanone (MIBK)100 5020008EPA 5030B 1.4 108-10-1 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Styrene1.0 5020008EPA 5030B 0.2 100-42-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,1,1,2-Tetrachloroethane 5.0 5020008EPA 5030B 0.5 630-20-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,1,2,2-Tetrachloroethane 3.0 5020008EPA 5030B 0.3 79-34-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Tetrachloroethene1.0 5020008EPA 5030B 0.4 127-18-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Toluene1.0 5020008EPA 5030B 0.2 108-88-3 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,1,1-Trichloroethane 1.0 5020008EPA 5030B 0.3 71-55-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L11,1,2-Trichloroethane 1.0 5020008EPA 5030B 0.3 79-00-5 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Trichloroethene1.0 5020008EPA 5030B 0.4 79-01-6 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Trichlorofluoromethane1.0 5020008EPA 5030B 0.3 75-69-4 02/02/15 17:1902/02/15 09:00 Page 49 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 ResultAnalyte SWSL/ RL Prep Method Qual DF Units Batch Analytical Method MDL CAS #Prep Date/Time Analysis Date/Time Client ID: Date/Time Sampled: Matrix: Report No.: Lab No: Date/Time Received: 9214-Trip Blank Water AYA0701-16 AYA070101/27/15 07:00 Project:Holly Springs Closed C&D Landfill 01/29/15 10:45 Volatile Organic Compounds by EPA 8260 NDEPA 8260B ug/L11,2,3-Trichloropropane 1.0 5020008EPA 5030B 0.4 96-18-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Acetate 50 5020008EPA 5030B 1.8 108-05-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Vinyl Chloride 1.0 5020008EPA 5030B 0.3 75-01-4 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Xylenes, total 5.0 5020008EPA 5030B 0.5 1330-20-7 02/02/15 17:1902/02/15 09:00 NDEPA 8260B ug/L1Tetrahydrofuran10 5020008EPA 5030B 3.9 109-99-9 02/02/15 17:1902/02/15 09:00 EPA 8260B 96 %Surr: Dibromofluoromethane 5020008EPA 5030B 1868-53-7 02/02/15 17:1902/02/15 09:0080-120 EPA 8260B 103 %Surr: 1,2-Dichloroethane-d4 5020008EPA 5030B 17060-07-0 02/02/15 17:1902/02/15 09:0078-120 EPA 8260B 100 %Surr: Toluene-d8 5020008EPA 5030B 2037-26-5 02/02/15 17:1902/02/15 09:0080-120 EPA 8260B 96 %Surr: 4-Bromofluorobenzene 5020008EPA 5030B 460-00-4 02/02/15 17:1902/02/15 09:0080-120 Page 50 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 5020033 - EPA 7470A Blank (5020033-BLK1)Prepared: 02/03/15 Analyzed: 02/04/15 Mercury ug/LND0.200 LCS (5020033-BS1)Prepared: 02/03/15 Analyzed: 02/04/15 Mercury ug/L2.39 0.200 2.5000 80-12096 Duplicate (5020033-DUP1)Prepared: 02/03/15 Analyzed: 02/04/15 Source: AYA0573-02RE1 Mercury ug/L0.281 0.200 0.290 203 Matrix Spike (5020033-MS1)Prepared: 02/03/15 Analyzed: 02/04/15 Source: AYA0701-07 Mercury ug/L2.48 0.200 2.5000 0.275 75-12588 Matrix Spike Dup (5020033-MSD1)Prepared: 02/03/15 Analyzed: 02/04/15 Source: AYA0701-07 Mercury ug/L2.44 0.200 2.5000 0.275 2075-12587 2 Post Spike (5020033-PS1)Prepared: 02/03/15 Analyzed: 02/04/15 Source: AYA0701-07 Mercury ug/L1.65 1.6667 0.184 80-12088 Batch 5020064 - EPA 3005A Blank (5020064-BLK1)Prepared & Analyzed: 02/04/15 Arsenic ug/LND10.0 Barium ug/LND100 Cadmium ug/LND1.00 Chromium ug/LND10.0 Lead ug/LND10.0 Selenium ug/LND10.0 Silver ug/LND10.0 Page 51 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 5020064 - EPA 3005A LCS (5020064-BS1)Prepared & Analyzed: 02/04/15 Arsenic ug/L10510.0 100.00 80-120105 Barium ug/L101100 100.00 80-120101 Cadmium ug/L1051.00 100.00 80-120105 Chromium ug/L10510.0 100.00 80-120105 Lead ug/L10210.0 100.00 80-120102 Selenium ug/L10710.0 100.00 80-120107 Silver ug/L10410.0 100.00 80-120104 Matrix Spike (5020064-MS1)Prepared & Analyzed: 02/04/15 Source: AYA0701-07 Arsenic ug/L10410.0 100.00 1.83 75-125102 Barium ug/L213100 100.00 112 75-125101 Cadmium ug/L1031.00 100.00 ND 75-125103 Chromium ug/L10010.0 100.00 ND 75-125100 Lead ug/L10110.0 100.00 ND 75-125101 Selenium ug/L10310.0 100.00 ND 75-125103 Silver ug/L10210.0 100.00 ND 75-125102 Matrix Spike Dup (5020064-MSD1)Prepared & Analyzed: 02/04/15 Source: AYA0701-07 Arsenic ug/L10410.0 100.00 1.83 2075-125102 0.5 Barium ug/L207100 100.00 112 2075-12595 3 Cadmium ug/L99.7 1.00 100.00 ND 2075-125100 3 Chromium ug/L99.6 10.0 100.00 ND 2075-125100 0.6 Lead ug/L10010.0 100.00 ND 2075-125100 1 Selenium ug/L99.4 10.0 100.00 ND 2075-12599 3 Silver ug/L98.9 10.0 100.00 ND 2075-12599 4 Post Spike (5020064-PS1)Prepared & Analyzed: 02/04/15 Source: AYA0701-07 Page 52 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 5020064 - EPA 3005A Post Spike (5020064-PS1)Prepared & Analyzed: 02/04/15 Source: AYA0701-07 Arsenic ug/L99.1 100.00 1.83 80-12097 Barium ug/L205 100.00 112 80-12094 Cadmium ug/L99.2 100.00 ND 80-12099 Chromium ug/L98.6 100.00 -0.19 80-12099 Lead ug/L99.2 100.00 -0.13 80-12099 Selenium ug/L96.0 100.00 0.59 80-12095 Silver ug/L98.8 100.00 0.07 80-12099 Batch 5020134 - EPA 3005A Blank (5020134-BLK1)Prepared & Analyzed: 02/06/15 Arsenic ug/LND10.0 Barium ug/LND100 Cadmium ug/LND1.00 Chromium ug/LND10.0 Lead ug/LND10.0 Selenium ug/LND10.0 Silver ug/LND10.0 LCS (5020134-BS1)Prepared & Analyzed: 02/06/15 Arsenic ug/L10610.0 100.00 80-120106 Barium ug/L100100 100.00 80-120100 Cadmium ug/L1041.00 100.00 80-120104 Chromium ug/L10410.0 100.00 80-120104 Lead ug/L10210.0 100.00 80-120102 Selenium ug/L10410.0 100.00 80-120104 Silver ug/L10210.0 100.00 80-120102 Page 53 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 5020134 - EPA 3005A Matrix Spike (5020134-MS1)Prepared & Analyzed: 02/06/15 Source: AYA0703-02 Arsenic ug/L10110.0 100.00 1.65 75-12599 Barium ug/L166100 100.00 71.3 75-12595 Cadmium ug/L1031.00 100.00 0.06 75-125103 Chromium ug/L10110.0 100.00 2.84 75-12598 Lead ug/L10310.0 100.00 1.94 75-125101 Selenium ug/L99.7 10.0 100.00 ND 75-125100 Silver ug/L10510.0 100.00 3.68 75-125101 Matrix Spike Dup (5020134-MSD1)Prepared & Analyzed: 02/06/15 Source: AYA0703-02 Arsenic ug/L10310.0 100.00 1.65 2075-125101 2 Barium ug/L170100 100.00 71.3 2075-12599 3 Cadmium ug/L1041.00 100.00 0.06 2075-125104 2 Chromium ug/L10210.0 100.00 2.84 2075-125100 2 Lead ug/L10410.0 100.00 1.94 2075-125102 1 Selenium ug/L10110.0 100.00 ND 2075-125101 2 Silver ug/L10610.0 100.00 3.68 2075-125103 2 Post Spike (5020134-PS1)Prepared & Analyzed: 02/06/15 Source: AYA0703-02 Arsenic ug/L104 100.00 1.65 80-120102 Barium ug/L168 100.00 71.3 80-12096 Cadmium ug/L103 100.00 0.06 80-120103 Chromium ug/L106 100.00 2.84 80-120103 Lead ug/L103 100.00 1.94 80-120101 Selenium ug/L103 100.00 0.30 80-120103 Silver ug/L105 100.00 3.68 80-120101 Batch 5020177 - EPA 7470A Page 54 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Metals, Total - Quality Control Batch 5020177 - EPA 7470A Blank (5020177-BLK1)Prepared: 02/09/15 Analyzed: 02/10/15 Mercury ug/LND0.200 LCS (5020177-BS1)Prepared: 02/09/15 Analyzed: 02/10/15 Mercury ug/L2.35 0.200 2.5000 80-12094 Matrix Spike (5020177-MS1)Prepared: 02/09/15 Analyzed: 02/10/15 Source: AYB0195-02 Mercury ug/L2.23 0.200 2.5000 ND 75-12589 Matrix Spike Dup (5020177-MSD1)Prepared: 02/09/15 Analyzed: 02/10/15 Source: AYB0195-02 Mercury ug/L2.32 0.200 2.5000 ND 2075-12593 4 Post Spike (5020177-PS1)Prepared: 02/09/15 Analyzed: 02/10/15 Source: AYB0195-02 Mercury ug/L1.52 1.6667 -0.025 80-12093 Page 55 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 5020008 - EPA 5030B Blank (5020008-BLK1)Prepared & Analyzed: 02/02/15 Acetone ug/LND100 Acrylonitrile ug/LND200 Benzene ug/LND1.0 Bromochloromethane ug/LND3.0 Bromodichloromethane ug/LND1.0 Bromoform ug/LND3.0 Bromomethane ug/LND10 Carbon Disulfide ug/LND100 Carbon Tetrachloride ug/LND1.0 Chlorobenzene ug/LND3.0 Chloroethane ug/LND10 Chloroform ug/LND5.0 Chloromethane ug/LND1.0 Dibromochloromethane ug/LND3.0 1,2-Dibromo-3-chloropropane ug/LND13 1,2-Dibromoethane ug/LND1.0 Dibromomethane ug/LND10 1,2-Dichlorobenzene ug/LND5.0 1,4-Dichlorobenzene ug/LND1.0 trans-1,4-Dichloro-2-butene ug/LND100 1,1-Dichloroethane ug/LND5.0 1,2-Dichloroethane ug/LND1.0 1,1-Dichloroethene ug/LND5.0 cis-1,2-Dichloroethene ug/LND5.0 trans-1,2-Dichloroethene ug/LND5.0 1,2-Dichloropropane ug/LND1.0 cis-1,3-Dichloropropene ug/LND1.0 Page 56 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 5020008 - EPA 5030B Blank (5020008-BLK1)Prepared & Analyzed: 02/02/15 trans-1,3-Dichloropropene ug/LND1.0 Ethylbenzene ug/LND1.0 Iodomethane ug/LND10 Methyl Butyl Ketone (2-Hexanone)ug/LND50 Methylene Chloride ug/LND1.0 Methyl Ethyl Ketone (2-Butanone)ug/LND100 4-Methyl-2-pentanone (MIBK)ug/LND100 Styrene ug/LND1.0 1,1,1,2-Tetrachloroethane ug/LND5.0 1,1,2,2-Tetrachloroethane ug/LND3.0 Tetrachloroethene ug/LND1.0 Toluene ug/LND1.0 1,1,1-Trichloroethane ug/LND1.0 1,1,2-Trichloroethane ug/LND1.0 Trichloroethene ug/LND1.0 Trichlorofluoromethane ug/LND1.0 1,2,3-Trichloropropane ug/LND1.0 Vinyl Acetate ug/LND50 Vinyl Chloride ug/LND1.0 Xylenes, total ug/LND5.0 Tetrahydrofuran ug/LND10 ug/L 50.000 80-120Surr: Dibromofluoromethane 9849 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10251 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10150 Page 57 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 5020008 - EPA 5030B LCS (5020008-BS1)Prepared & Analyzed: 02/02/15 Benzene ug/L49 50.000 67-13498 Chlorobenzene ug/L51 50.000 69-122102 1,1-Dichloroethene ug/L54 50.000 58-142107 Toluene ug/L51 50.000 68-127101 Trichloroethene ug/L54 50.000 72-132109 ug/L 50.000 80-120Surr: Dibromofluoromethane 9950 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10352 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 9949 Matrix Spike (5020008-MS1)Prepared & Analyzed: 02/02/15 Source: AYA0701-07 Benzene ug/L51 50.000 ND 67-134102 Chlorobenzene ug/L52 50.000 ND 69-122104 1,1-Dichloroethene ug/L57 50.000 ND 58-142114 Toluene ug/L53 50.000 ND 68-127107 Trichloroethene ug/L57 50.000 ND 72-132114 ug/L 50.000 80-120Surr: Dibromofluoromethane 9748 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10351 ug/L 50.000 80-120Surr: Toluene-d8 9950 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 10151 Matrix Spike Dup (5020008-MSD1)Prepared & Analyzed: 02/02/15 Source: AYA0701-07 Benzene ug/L50 50.000 ND 967-134101 1 Chlorobenzene ug/L51 50.000 ND 1369-122103 1 1,1-Dichloroethene ug/L57 50.000 ND 958-142114 0.2 Page 58 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Result LimitReporting Units LevelSpike ResultSource %REC %RECLimits RPD RPDLimit Qual Analyte Volatile Organic Compounds by EPA 8260 - Quality Control Batch 5020008 - EPA 5030B Matrix Spike Dup (5020008-MSD1)Prepared & Analyzed: 02/02/15 Source: AYA0701-07 Toluene ug/L52 50.000 ND 968-127105 2 Trichloroethene ug/L56 50.000 ND 1172-132112 2 ug/L 50.000 80-120Surr: Dibromofluoromethane 9748 ug/L 50.000 78-120Surr: 1,2-Dichloroethane-d4 10352 ug/L 50.000 80-120Surr: Toluene-d8 10050 ug/L 50.000 80-120Surr: 4-Bromofluorobenzene 9950 Page 59 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Laboratory Certifications Code Description Number Expires 02069Louisiana 06/30/2015LA 381North Carolina 12/31/2015NC E87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/2013 06/30/2015NELAC 98011001South Carolina 06/30/2015SC T104704397-08-TXTexas 03/31/2015TX 1340Virginia 12/14/2015VA Page 60 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 Legend Defination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLND SWSL/RL MDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection Limit Qualifiers - Dilution FactorDF J Estimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag). Note: Unless otherwise noted, all results are reported on an as received basis. Page 61 of 62 ASI Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Norcross, GA 30092 (770) 734-4200 FAX (770) 734-4201 ANALYTICAL SERVICES, INC. Republic Services of North Carolina, LLC 1220 Commerce Street, SW Conover NC, 28613 Attention: Mr. Matt Einsmann February 13, 2015 COC Goes Here Page 62 of 62 LOG-IN CHECKLIST Republic Services of North Carolina, LLC Holly Springs Closed C&D LandfillProject: Client: Printed: 2/13/2015 1:42:06PM Environmental Monitoring & Laboratory Analysis (770) 734-4200 FAX (770) 734-4201 110 Technology Parkway, Norcross, GA 30092 ANALYTICAL SERVICES, INC.ASI Date Received:01/29/15 10:45 Logged In By:Charles Hawks Work Order:AYA0701 OBSERVATIONS Attn: Mr. Matt Einsmann #Samples: 16 #Containers: 71 1.0 1.0 YES Minimum Temp(C):Maximum Temp(C): CHECKLIST ITEMS COC included with Samples Sample Container(s) Intact Chain of Custody Complete Sample Container(s) Match COC Custody seal Intact Temperature in Compliance Sufficient Sample Volume for Analysis Zero Headspace Maintained for VOA Analyses Samples labeled preserved (If Applicable) Samples received within Allowable Hold Times Samples Received on Ice Preservation Confirmed YES YES YES YES YES YES YES YES YES YES YES Custody Seal(s) Used:Yes Comments: Page 1 of 1