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HomeMy WebLinkAbout1107_BuncombeCounty_MSWLF_GWMonitoring_DIN27133_20151001 SCS Engineers, P.C. Environmental Consultants 4767 New Broad Street 407 514-2766 and Contractors Suite 222 FAX 407 514-2604 Orlando, FL 32814 www.scsengineers.com Offices Nationwide February 24, 2016 File No. 09204072.13 Mrs. Jackie Drummond Compliance Hydrogeologist Division of Waste Management - Solid Waste Section NC Department of Environmental Quality Asheville Regional Office 2090 US Highway 70, Swannanoa, NC 28778 Subject: Sampling Report Buncombe County Solid Waste Management Facility Landfill Buncombe County Permit No. 1107 Dear Mrs. Drummond: The purpose of this letter is to notify the Solid Waste Section that semi-annual sampling has been completed at the Buncombe County Solid Waste Management Facility Landfill. Water quality samples were collected from each of the monitoring wells, surface water sampling locations in addition to leachate samples. Metals were the only constituents detected in monitoring well and surface water samples which exceeded North Carolina 2L Groundwater and Surface water Standards in concentrations which are consistent with previous sampling results and are generally recognized as naturally occurring. Leachate sampling demonstrated no constituents were above their SWS reporting limits. Currently 25 monitoring wells are sampled semi-annually. Groundwater samples were collected from October 2nd through 10th, 2015. The six surface water and six leachate samples were collected on October 1st, 2015. All samples were collected and analyzed by Pace Laboratories in Asheville, NC for analysis of the current landfill constituents list (Appendix I VOC (EPA 8260); Appendix I Metals (EPA 6010) plus mercury (EPA 7470), sulfate (EPA 300.0), chloride (SM 4500-Cl-E), Alkalinity(SM 2320B), and Total Dissolved Solids (SM 2540C)). Groundwater elevations were also measured and groundwater contour maps for both the shallow and deep flow regimes as presented in Attachment A. Field parameters and the well condition was evaluated as presented in Attachment B Well Condition Summary and Attachment C Sampling Forms. Field parameters included: pH, specific conductivity, temperature, dissolved oxygen, and oxidation/reduction potential, temperature, and turbidity. Field parameters were also measured at the surface water sampling locations. Eight of the 25 monitoring wells had concentrations in excess of the North Carolina 2L Groundwater Standards. One surface water sample had concentrations in excess of the SWS reporting limits. A summary of detections is provided in Attachment D, a summary of exceedances is provided as Attachment E, Metal constituents detected include chromium, Jackie Drummond February 5, 2016 Page 2 cobalt, iron, manganese, and vanadium. Chromium was detected above the maximum contaminant level of 10 ug/L in MW-5 (13.7 ug/L), and MW-6 (30.3 ug/L). Cobalt was detected above the maximum contaminant level of 1 ug/L in MW-13D (17.6 ug/L), MW-15S (68.2 ug/L), and MW-15D (6.2 ug/L). Iron was detected above the maximum contaminant level of 300 ug/L in MW-12 (584 ug/L), MW-14 (1710 ug/L), MW-15S (2320 ug/L), and MW-15D (1110 ug/L). Manganese was detected above the maximum contaminant level of 50 ug/L in MW-12 (584 ug/L), MW-15S (7570 ug/L), and MW-15D (230 ug/L). Vanadium was detected above the maximum contaminant level of 0.3 ug/L in MW-5 (14.4 ug/L), MW-6 (40.1 ug/L), MW-10 (6.8 ug/L), MW-13D (8.5 ug/L), MW-14 (10.7 ug/L), MW-15S (13.8 ug/L), and MW-15D (6.1 ug/L). Copper was the only constituent detected above the maximum contaminant level of 7 ug/L in surface water; SW-4 (11.8 ug/L). The next Semi-Annual sampling event is scheduled for spring of 2016. This submittal, which included a discussion of the sampling of the approved groundwater and surface water quality monitoring network, satisfies the groundwater and surface water monitoring criteria necessary to operate the Buncombe County landfill. Sincerely, C. Ed Hilton, Jr. P.E. Brooke Fait, MPH Vice President/Project Director Environmental Health & Safety Project Manager SCS ENGINEERS SCS ENGINEERS BLF/CEH Jaclynne Drummond Buncombe County, North Carolina Attachment A Buncombe County, North Carolina Attachment B Buncombe County, North Carolina Attachment C Page 31 of 31 Page 31 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31 Buncombe County, North Carolina Attachment D Detections By Date Range Buncombe County New Facility From:10/1/2015 To:10/1/2015 Site ID Analyte Date Result LD-1 1,1-Dichloroethane 10/1/2015 1.6 ug/L Barium 10/1/2015 69.6 ug/L Cobalt 10/1/2015 140 ug/L Field pH 10/1/2015 6.2 Std. Field Specific Conductance 10/1/2015 228 umh Field Temperature 10/1/2015 16.4 deg Nickel 10/1/2015 48.8 ug/L ORP 10/1/2015 330 mV Oxygen, Dissolved, Dissolved 10/1/2015 1600 ug/L Turbidity 10/1/2015 1.74 NTU Monday, February 08, 2016 Page 1 of 5 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result LD-2 1,1-Dichloroethane 10/1/2015 3.8 ug/L Barium 10/1/2015 140 ug/L cis-1,2-Dichloroethene 10/1/2015 1.3 ug/L Cobalt 10/1/2015 15.9 ug/L Field pH 10/1/2015 5.6 Std. Field Specific Conductance 10/1/2015 392 umh Field Temperature 10/1/2015 16.5 deg ORP 10/1/2015 43.5 mV Oxygen, Dissolved, Dissolved 10/1/2015 3030 ug/L Turbidity 10/1/2015 1.6 NTU LD-3 Barium 10/1/2015 297 ug/L Field pH 10/1/2015 7.1 Std. Field Specific Conductance 10/1/2015 520 umh Field Temperature 10/1/2015 17.5 deg ORP 10/1/2015 -18.3 mV Oxygen, Dissolved, Dissolved 10/1/2015 2100 ug/L Turbidity 10/1/2015 5.55 NTU Monday, February 08, 2016 Page 2 of 5 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result LD-4 1,1-Dichloroethane 10/1/2015 2.3 ug/L 2-Butanone 10/1/2015 5.9 ug/L Arsenic 10/1/2015 10.8 ug/L Barium 10/1/2015 410 ug/L Benzene 10/1/2015 2.8 ug/L Chromium 10/1/2015 178 ug/L Copper 10/1/2015 68.7 ug/L Field pH 10/1/2015 6.3 Std. Field Specific Conductance 10/1/2015 197 umh Field Temperature 10/1/2015 17.5 deg Nickel 10/1/2015 59.5 ug/L ORP 10/1/2015 -18.5 mV Oxygen, Dissolved, Dissolved 10/1/2015 1510 ug/L Turbidity 10/1/2015 6.23 NTU Vinyl chloride 10/1/2015 1.8 ug/L Monday, February 08, 2016 Page 3 of 5 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result LD-5 Barium 10/1/2015 220 ug/L Cobalt 10/1/2015 64.8 ug/L Field pH 10/1/2015 6.7 Std. Field Specific Conductance 10/1/2015 743 umh Field Temperature 10/1/2015 20.7 deg Nickel 10/1/2015 19.1 ug/L ORP 10/1/2015 340.5 mV Oxygen, Dissolved, Dissolved 10/1/2015 3270 ug/L Turbidity 10/1/2015 16.4 NTU LD-6 Barium 10/1/2015 460 ug/L Cobalt 10/1/2015 51.6 ug/L Field pH 10/1/2015 6.2 Std. Field Specific Conductance 10/1/2015 564 umh Field Temperature 10/1/2015 18.9 deg ORP 10/1/2015 56.1 mV Oxygen, Dissolved, Dissolved 10/1/2015 2010 ug/L Turbidity 10/1/2015 3.21 NTU Monday, February 08, 2016 Page 4 of 5 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result LEACHATE Arsenic 10/1/2015 10.8 ug/L Barium 10/1/2015 24.8 ug/L Cobalt 10/1/2015 61.7 ug/L Copper 10/1/2015 26.6 ug/L Field pH 10/1/2015 6 Std. Field Specific Conductance 10/1/2015 441 umh Field Temperature 10/1/2015 12 deg Nickel 10/1/2015 383 ug/L ORP 10/1/2015 188.4 mV Oxygen, Dissolved, Dissolved 10/1/2015 7670 ug/L Turbidity 10/1/2015 1.52 NTU Zinc 10/1/2015 159 ug/L Monday, February 08, 2016 Page 5 of 5 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Detections By Date Range Buncombe County New Facility From:10/2/2015 To:10/9/2015 Site ID Analyte Date Result MW-1 Alkalinity, Total as CaCO3 10/9/2015 40600 ug/L Barium 10/9/2015 124 ug/L Chloride 10/9/2015 5380 ug/L Field pH 10/9/2015 7.6 Std. Field Specific Conductance 10/9/2015 161 umh Field Temperature 10/9/2015 14.9 deg Iron 10/9/2015 162 ug/L ORP 10/9/2015 160.2 mV Oxygen, Dissolved, Dissolved 10/9/2015 7850 ug/L Static Water Level 10/9/2015 71.03 feet Sulfate 10/9/2015 17100 ug/L Total Dissolved Solids 10/9/2015 129000 ug/L Turbidity 10/9/2015 2.63 NTU Monday, February 08, 2016 Page 1 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-10 Barium 10/6/2015 134 ug/L Field pH 10/6/2015 6.4 Std. Field Specific Conductance 10/6/2015 300 umh Field Temperature 10/6/2015 15.7 deg ORP 10/6/2015 148.8 mV Oxygen, Dissolved, Dissolved 10/6/2015 3540 ug/L Static Water Level 10/6/2015 70.77 feet Turbidity 10/6/2015 3.17 NTU Vanadium 10/6/2015 6.8 ug/L MW-10D Barium 10/6/2015 18.6 ug/L Copper 10/6/2015 10 ug/L Field pH 10/6/2015 6.5 Std. Field Specific Conductance 10/6/2015 279 umh Field Temperature 10/6/2015 15.5 deg Nickel 10/6/2015 8.7 ug/L ORP 10/6/2015 145.9 mV Oxygen, Dissolved, Dissolved 10/6/2015 3560 ug/L Static Water Level 10/6/2015 71.38 feet Turbidity 10/6/2015 2.8 NTU Monday, February 08, 2016 Page 2 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-11 Barium 10/2/2015 92 ug/L Field pH 10/2/2015 7.2 Std. Field Specific Conductance 10/2/2015 391 umh Field Temperature 10/2/2015 15 deg Nickel 10/2/2015 26.6 ug/L ORP 10/2/2015 172.2 mV Oxygen, Dissolved, Dissolved 10/2/2015 6710 ug/L Static Water Level 10/2/2015 32.69 feet Turbidity 10/2/2015 3.11 NTU MW-11D Barium 10/2/2015 15 ug/L Field pH 10/2/2015 6.7 Std. Field Specific Conductance 10/2/2015 384 umh Field Temperature 10/2/2015 14.6 deg ORP 10/2/2015 121.5 mV Oxygen, Dissolved, Dissolved 10/2/2015 2290 ug/L Static Water Level 10/2/2015 33.33 feet Turbidity 10/2/2015 1.31 NTU Monday, February 08, 2016 Page 3 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-12 Alkalinity, Total as CaCO3 10/7/2015 142000 ug/L Barium 10/7/2015 68.8 ug/L Chloride 10/7/2015 32100 ug/L Field pH 10/7/2015 6.6 Std. Field Specific Conductance 10/7/2015 649 umh Field Temperature 10/7/2015 17.5 deg Iron 10/7/2015 584 ug/L Manganese 10/7/2015 292 ug/L Nickel 10/7/2015 12.1 ug/L ORP 10/7/2015 157.7 mV Oxygen, Dissolved, Dissolved 10/7/2015 3500 ug/l Static Water Level 10/7/2015 12.25 feet Sulfate 10/7/2015 142000 ug/L Total Dissolved Solids 10/7/2015 443000 ug/L Turbidity 10/7/2015 1.06 NTU Monday, February 08, 2016 Page 4 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-12D Alkalinity, Total as CaCO3 10/7/2015 152000 ug/L Barium 10/7/2015 60.5 ug/L Chloride 10/7/2015 17600 ug/L Field pH 10/7/2015 6.7 Std. Field Specific Conductance 10/7/2015 489 umh Field Temperature 10/7/2015 16.9 deg Iron 10/7/2015 203 ug/L Manganese 10/7/2015 19.4 ug/L ORP 10/7/2015 132.6 mV Oxygen, Dissolved, Dissolved 10/7/2015 1770 ug/l Static Water Level 10/7/2015 11.25 feet Sulfate 10/7/2015 70900 ug/L Total Dissolved Solids 10/7/2015 316000 ug/L Turbidity 10/7/2015 1.44 NTU Monday, February 08, 2016 Page 5 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-13 Barium 10/6/2015 98.4 ug/L Copper 10/6/2015 8.8 ug/L Field pH 10/6/2015 6.8 Std. Field Specific Conductance 10/6/2015 249 umh Field Temperature 10/6/2015 18.1 deg ORP 10/6/2015 79.1 mV Oxygen, Dissolved, Dissolved 10/6/2015 3170 ug/L Static Water Level 10/6/2015 5.5 feet Turbidity 10/6/2015 1.84 NTU MW-13D Barium 10/6/2015 278 ug/L Cobalt 10/6/2015 17.6 ug/L Field pH 10/6/2015 6.6 Std. Field Specific Conductance 10/6/2015 372 umh Field Temperature 10/6/2015 17.8 deg Nickel 10/6/2015 19.2 ug/L ORP 10/6/2015 36.4 mV Oxygen, Dissolved, Dissolved 10/6/2015 3730 ug/L Static Water Level 10/6/2015 8.93 feet Turbidity 10/6/2015 4.14 NTU Vanadium 10/6/2015 8.5 ug/L Monday, February 08, 2016 Page 6 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-14 Alkalinity, Total as CaCO3 10/7/2015 70600 ug/L Barium 10/7/2015 67.9 ug/L Chloride 10/7/2015 2760 ug/L Chromium 10/7/2015 5.4 ug/L Field pH 10/7/2015 6.8 Std. Field Specific Conductance 10/7/2015 236 umh Field Temperature 10/7/2015 16 deg Iron 10/7/2015 1710 ug/L Manganese 10/7/2015 49.5 ug/L Nickel 10/7/2015 5.5 ug/L ORP 10/7/2015 166.7 mV Oxygen, Dissolved, Dissolved 10/7/2015 5040 ug/L Static Water Level 10/7/2015 30.92 feet Sulfate 10/7/2015 26400 ug/L Total Dissolved Solids 10/7/2015 196000 ug/L Turbidity 10/7/2015 10.25 NTU Vanadium 10/7/2015 10.7 ug/L Zinc 10/7/2015 14.1 ug/L Monday, February 08, 2016 Page 7 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-14D Alkalinity, Total as CaCO3 10/7/2015 122000 ug/L Chloride 10/7/2015 2600 ug/L Field pH 10/7/2015 6.6 Std. Field Specific Conductance 10/7/2015 278 umh Field Temperature 10/7/2015 13.8 deg ORP 10/7/2015 168.4 mV Oxygen, Dissolved, Dissolved 10/7/2015 9600 ug/l Static Water Level 10/7/2015 31.05 feet Sulfate 10/7/2015 17400 ug/L Total Dissolved Solids 10/7/2015 161000 ug/L Turbidity 10/7/2015 0.19 NTU Monday, February 08, 2016 Page 8 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-15D Alkalinity, Total as CaCO3 10/7/2015 139000 ug/L Barium 10/7/2015 160 ug/L Chloride 10/7/2015 11000 ug/L Field pH 10/7/2015 6.4 Std. Field Specific Conductance 10/7/2015 413 umh Field Temperature 10/7/2015 15.4 deg Iron 10/7/2015 1110 ug/L Manganese 10/7/2015 230 ug/L Nickel 10/7/2015 6.8 ug/L ORP 10/7/2015 127 mV Oxygen, Dissolved, Dissolved 10/7/2015 8720 ug/L Static Water Level 10/7/2015 26.86 feet Sulfate 10/7/2015 53000 ug/L Total Dissolved Solids 10/7/2015 276000 ug/L Turbidity 10/7/2015 2.19 NTU Vanadium 10/7/2015 6.1 ug/L Zinc 10/7/2015 18.5 ug/L Monday, February 08, 2016 Page 9 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-15S Alkalinity, Total as CaCO3 10/7/2015 135000 ug/L Barium 10/7/2015 204 ug/L Chloride 10/7/2015 14400 ug/L Cobalt 10/7/2015 68.2 ug/L Field pH 10/7/2015 6.4 Std. Field Specific Conductance 10/7/2015 385 umh Field Temperature 10/7/2015 17.2 deg Iron 10/7/2015 2320 ug/L Manganese 10/7/2015 7570 ug/L Nickel 10/7/2015 8.1 ug/L ORP 10/7/2015 159.1 mV Oxygen, Dissolved, Dissolved 10/7/2015 3940 ug/l Static Water Level 10/7/2015 22.36 feet Sulfate 10/7/2015 32000 ug/L Total Dissolved Solids 10/7/2015 218000 ug/L Turbidity 10/7/2015 3.22 NTU Vanadium 10/7/2015 13.8 ug/L Monday, February 08, 2016 Page 10 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-1D Alkalinity, Total as CaCO3 10/9/2015 52000 ug/L Barium 10/9/2015 42.6 ug/L Chloride 10/9/2015 2540 ug/L Field pH 10/9/2015 6.7 Std. Field Specific Conductance 10/9/2015 168 umh Field Temperature 10/9/2015 15.4 deg ORP 10/9/2015 164.2 mV Oxygen, Dissolved, Dissolved 10/9/2015 7170 ug/L Static Water Level 10/9/2015 72.7 feet Sulfate 10/9/2015 21700 ug/L Total Dissolved Solids 10/9/2015 130000 ug/L Turbidity 10/9/2015 0.53 NTU MW-2 Barium 10/6/2015 80.6 ug/L Field pH 10/6/2015 7 Std. Field Specific Conductance 10/6/2015 170 umh Field Temperature 10/6/2015 15.1 deg ORP 10/6/2015 159.9 mV Oxygen, Dissolved, Dissolved 10/6/2015 4000 ug/L Static Water Level 10/6/2015 8.59 feet Turbidity 10/6/2015 3.81 NTU Monday, February 08, 2016 Page 11 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-2D Barium 10/6/2015 87.3 ug/L Field pH 10/6/2015 6.8 Std. Field Specific Conductance 10/6/2015 245 umh Field Temperature 10/6/2015 14.8 deg ORP 10/6/2015 172.9 mV Oxygen, Dissolved, Dissolved 10/6/2015 5110 ug/L Static Water Level 10/6/2015 8.45 feet Turbidity 10/6/2015 1.75 NTU MW-3R Barium 10/2/2015 130 ug/L Chromium 10/2/2015 5.3 ug/L Field pH 10/2/2015 6.2 Std. Field Specific Conductance 10/2/2015 207 umh Field Temperature 10/2/2015 14.2 deg Nickel 10/2/2015 7.2 ug/L ORP 10/2/2015 169.3 mV Oxygen, Dissolved, Dissolved 10/2/2015 5430 ug/L Static Water Level 10/2/2015 57.08 feet Turbidity 10/2/2015 4.12 NTU Monday, February 08, 2016 Page 12 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-4 Barium 10/6/2015 75.2 ug/L Field pH 10/6/2015 6.6 Std. Field Specific Conductance 10/6/2015 175 umh Field Temperature 10/6/2015 17.4 deg ORP 10/6/2015 123.6 mV Oxygen, Dissolved, Dissolved 10/6/2015 5810 ug/L Static Water Level 10/6/2015 10.82 feet Turbidity 10/6/2015 3.32 NTU MW-4D Barium 10/6/2015 27.3 ug/L Field pH 10/6/2015 6.3 Std. Field Specific Conductance 10/6/2015 246 umh Field Temperature 10/6/2015 16.7 deg ORP 10/6/2015 134.4 mV Oxygen, Dissolved, Dissolved 10/6/2015 2910 ug/L Static Water Level 10/6/2015 11.31 feet Turbidity 10/6/2015 1.6 NTU Monday, February 08, 2016 Page 13 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-5 Barium 10/2/2015 126 ug/L Chromium 10/2/2015 13.7 ug/L Field pH 10/2/2015 6.5 Std. Field Specific Conductance 10/2/2015 208 umh Field Temperature 10/2/2015 15.1 deg Nickel 10/2/2015 6.9 ug/L ORP 10/2/2015 129.4 mV Oxygen, Dissolved, Dissolved 10/2/2015 2910 ug/L Static Water Level 10/2/2015 34.71 feet Turbidity 10/2/2015 11.5 NTU Vanadium 10/2/2015 14.4 ug/L Zinc 10/2/2015 10.1 ug/L MW-5D Barium 10/2/2015 64.4 ug/L Field pH 10/2/2015 6.5 Std. Field Specific Conductance 10/2/2015 196 umh Field Temperature 10/2/2015 15.1 deg ORP 10/2/2015 143.5 mV Oxygen, Dissolved, Dissolved 10/2/2015 3550 ug/L Static Water Level 10/2/2015 36.05 feet Turbidity 10/2/2015 2.66 NTU Monday, February 08, 2016 Page 14 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-6 Barium 10/2/2015 152 ug/L Chromium 10/2/2015 30.3 ug/L Cobalt 10/2/2015 12.6 ug/L Copper 10/2/2015 13.4 ug/L Field pH 10/2/2015 6.8 Std. Field Specific Conductance 10/2/2015 140 umh Field Temperature 10/2/2015 14.6 deg Nickel 10/2/2015 10.9 ug/L ORP 10/2/2015 64.7 mV Oxygen, Dissolved, Dissolved 10/2/2015 3610 ug/L Static Water Level 10/2/2015 26.83 feet Turbidity 10/2/2015 44 NTU Vanadium 10/2/2015 40.1 ug/L Zinc 10/2/2015 28.2 ug/L Monday, February 08, 2016 Page 15 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-7 1,1-Dichloroethane 10/2/2015 1.9 ug/L Barium 10/2/2015 153 ug/L Field pH 10/2/2015 6.6 Std. Field Specific Conductance 10/2/2015 656 umh Field Temperature 10/2/2015 15.3 deg Nickel 10/2/2015 10.3 ug/L ORP 10/2/2015 47.5 mV Oxygen, Dissolved, Dissolved 10/2/2015 1330 ug/L Static Water Level 10/2/2015 47.96 feet Turbidity 10/2/2015 2.99 NTU MW-8 Barium 10/9/2015 142 ug/L Field pH 10/9/2015 6.7 Std. Field Specific Conductance 10/9/2015 343 umh Field Temperature 10/9/2015 16.1 deg ORP 10/9/2015 150.5 mV Oxygen, Dissolved, Dissolved 10/9/2015 4880 ug/L Static Water Level 10/9/2015 34.73 feet Turbidity 10/9/2015 3.44 NTU Monday, February 08, 2016 Page 16 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-8D Barium 10/9/2015 176 ug/L Field pH 10/9/2015 6.5 Std. Field Specific Conductance 10/9/2015 382 umh Field Temperature 10/9/2015 16.1 deg ORP 10/9/2015 161.3 mV Oxygen, Dissolved, Dissolved 10/9/2015 3200 ug/L Static Water Level 10/9/2015 33.48 feet Turbidity 10/9/2015 0.94 NTU Monday, February 08, 2016 Page 17 of 17 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Detections By Date Range Buncombe County New Facility From:10/1/2015 To:10/1/2015 Site ID Analyte Date Result SW-1 Barium 10/1/2015 191 ug/L Field pH 10/1/2015 6.2 Std. Field Specific Conductance 10/1/2015 99 umh Field Temperature 10/1/2015 18.5 deg ORP 10/1/2015 35.8 mV Oxygen, Dissolved, Dissolved 10/1/2015 990 ug/L Turbidity 10/1/2015 5.58 NTU Zinc 10/1/2015 17.9 ug/L SW-2 Barium 10/1/2015 62.3 ug/L Field pH 10/1/2015 6.5 Std. Field Specific Conductance 10/1/2015 149 umh Field Temperature 10/1/2015 18.5 deg ORP 10/1/2015 156.5 mV Oxygen, Dissolved, Dissolved 10/1/2015 8020 ug/L Turbidity 10/1/2015 7.79 NTU Monday, February 08, 2016 Page 1 of 4 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result SW-3 Barium 10/1/2015 42.1 ug/L Field pH 10/1/2015 7.5 Std. Field Specific Conductance 10/1/2015 188 umh Field Temperature 10/1/2015 20.8 deg ORP 10/1/2015 176.7 mV Oxygen, Dissolved, Dissolved 10/1/2015 5530 ug/L Turbidity 10/1/2015 3.46 NTU SW-4 Barium 10/1/2015 134 ug/L Chromium 10/1/2015 7.1 ug/L Cobalt 10/1/2015 5.2 ug/L Copper 10/1/2015 11.8 ug/L Field pH 10/1/2015 6.4 Std. Field Specific Conductance 10/1/2015 269 umh Field Temperature 10/1/2015 19.2 deg Nickel 10/1/2015 11.2 ug/L ORP 10/1/2015 152.6 mV Oxygen, Dissolved, Dissolved 10/1/2015 8150 ug/L Turbidity 10/1/2015 53 NTU Vanadium 10/1/2015 13.7 ug/L Zinc 10/1/2015 28.4 ug/L Monday, February 08, 2016 Page 2 of 4 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result SW-5 Barium 10/1/2015 83.5 ug/L Field pH 10/1/2015 6.9 Std. Field Specific Conductance 10/1/2015 336 umh Field Temperature 10/1/2015 19.5 deg Nickel 10/1/2015 5.2 ug/L ORP 10/1/2015 192.7 mV Oxygen, Dissolved, Dissolved 10/1/2015 7510 ug/L Turbidity 10/1/2015 7.03 NTU SW-6 Barium 10/1/2015 88.3 ug/L Field pH 10/1/2015 6.7 Std. Field Specific Conductance 10/1/2015 210 umh Field Temperature 10/1/2015 17.9 deg ORP 10/1/2015 184.2 mV Oxygen, Dissolved, Dissolved 10/1/2015 5800 ug/L Turbidity 10/1/2015 6.33 NTU Monday, February 08, 2016 Page 3 of 4 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result SW-7 Barium 10/1/2015 195 ug/L Field pH 10/1/2015 6.3 Std. Field Specific Conductance 10/1/2015 307 umh Field Temperature 10/1/2015 20.5 deg Nickel 10/1/2015 22.3 ug/L ORP 10/1/2015 174.4 mV Oxygen, Dissolved, Dissolved 10/1/2015 2580 ug/L Turbidity 10/1/2015 3.04 NTU Zinc 10/1/2015 15.8 ug/L Monday, February 08, 2016 Page 4 of 4 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Buncombe County, North Carolina Attachment E Exceedances by Date Range Buncombe County New Facility From:10/2/2015 To:10/7/2015 Site ID Analyte Date Result MW-10 Vanadium MCL:0.3 ug/L 10/6/2015 6.8 ug/L MW-12 Iron MCL:300 ug/L 10/7/2015 584 ug/L Manganese MCL:50 ug/L 10/7/2015 292 ug/L MW-13D Cobalt MCL:1ug/L 10/6/2015 17.6 ug/L Vanadium MCL:0.3 ug/L 10/6/2015 8.5 ug/L MW-14 Iron MCL:300 ug/L 10/7/2015 1710 ug/L Vanadium MCL:0.3 ug/L 10/7/2015 10.7 ug/L MW-15D Iron MCL:300 ug/L 10/7/2015 1110 ug/L Manganese MCL:50 ug/L 10/7/2015 230 ug/L Vanadium MCL:0.3 ug/L 10/7/2015 6.1 ug/L Thursday, February 04, 2016 Page 1 of 2 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Site ID Analyte Date Result MW-15S Cobalt MCL:1ug/L 10/7/2015 68.2 ug/L Iron MCL:300 ug/L 10/7/2015 2320 ug/L Manganese MCL:50 ug/L 10/7/2015 7570 ug/L Vanadium MCL:0.3 ug/L 10/7/2015 13.8 ug/L MW-5 Chromium MCL:10 ug/L 10/2/2015 13.7 ug/L Vanadium MCL:0.3 ug/L 10/2/2015 14.4 ug/L MW-6 Chromium MCL:10 ug/L 10/2/2015 30.3 ug/L Cobalt MCL:1ug/L 10/2/2015 12.6 ug/L Vanadium MCL:0.3 ug/L 10/2/2015 40.1 ug/L Thursday, February 04, 2016 Page 2 of 2 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. Exceedances by Date Range Buncombe County New Facility From:10/1/2015 To:10/1/2015 Site ID Analyte Date Result SW-4 Copper MCL:7ug/L 10/1/2015 11.8 ug/L Thursday, February 04, 2016 Page 1 of 1 I = The reported value is between the laboratory method detection limit and the laboratory practical quatitation limit. V = Indicates the anlyte was detected in both the sample and the associated method blank. If Cadmium, Chromium, Copper, Lead, Nickel, or Zinc exceedance verify with Metals Calculator using date specific hardness