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HomeMy WebLinkAbout9809-CDLF_GWMR_DIN27111_20161204 December 4, 2016 Mr. Ervin Lane, Hydrogeologist NC Division of Waste Management Solid Waste Section Mail Service Center 1646 Raleigh, NC 27699-1646 Re: 2016 Second Semi-Annual Water Quality Monitoring Results Westside C&D Facility Wilson, North Carolina Permit #98-09 Dear Ervin: Babb & Associates, P.A. has completed the 2016 second semi-annual sampling event at the Westside C&D facility in Wilson, NC. On November 3, 2016, four groundwater monitoring wells were sampled and analyzed for the Appendix II compound list which includes: volatile organic compounds (VOCs) by EPA Method 8260B, semi-volatile organic compounds (SVOCs) by EPA Method 8270D, organochlorine pesticides by EPA Method 8081B, chlorinated herbicides by EPA Method 8151A, polychlorinated biphenyls by EPA Method 8082A, Appendix II inorganics by EPA Methods 6010D/6020B, mercury by EPA Method 7470A, cyanide by EPA Method 9014, and sulfide by Method SM4500S2D-2000. A site map is provided with this report which shows the groundwater sample locations and shallow potentiometric surface. Additional attachments to this report include a table summarizing the groundwater analytical results and field parameters (Table 1), well construction information (Table 2), and groundwater flow rates (Table 3). The laboratory analytical report, in pdf and EDD formats, is included as Appendix A. If there are any questions regarding the attached information, please contact the undersigned at (919) 325- 0696. Respectfully, Babb & Associates, P.A. Gary D. Babb, P.G. President Enclosures cc: Mr. Andy Davis, Director Wilson County Solid Waste Water Quality Monitoring Report Westside Construction and Demolition Landfill 4537 Landfill Road Wilson, North Carolina Permit No. 98-09 Prepared for: Wilson County Solid Waste P.O. Box 1728 Wilson, North Carolina 27894 Prepared by: Babb & Associates, P.A. P.O. Box 37697 Raleigh, North Carolina 27627 November 2016 ___________________________________ Gary D. Babb, Licensed Geologist Table of Contents 1.0 Introduction 1 1.1 Site Information 1.2 Site Geology 1.3 Site Hydrogeology 2.0 Water Quality Monitoring Program 5 2.1 Groundwater Monitoring Network 2.2 Surface Water Monitoring Network 3.0 Water Quality Sample Collection 6 3.1 Field Sample Procedures 3.2 Field Quality Assurance 3.3 Sample Delivery/Chain-of-Custody 4.0 Laboratory Analysis 8 5.0 Hydrogeological Conditions 9 6.0 Laboratory Analytical Results 10 6.1 Groundwater Analytical Results 6.2 Surface Water Analytical Results 6.3 Quality Control Sample 7.0 Conclusions 12 Figure 1 Water Quality Monitoring Sample Locations/Potentiometric Map Table 1 Groundwater Analytical Results/Field Parameters Table 2 Well Construction Information/Elevations Table 3 Groundwater Flow Rates Appendix A ENCO Laboratory Analytical Report Westside C&D Facility Water Quality Monitoring Report November 2016 Page 1 1.0 Introduction 1.1 Site Information The Westside Construction and Demolition (C&D) facility is located approximately 3.5 miles east of downtown Wilson, NC at the intersection of NC 42 and Tucker Court. The Westside C&D facility is located on property that was previously used as a borrow site for the closed landfill site which is located approximately 350 feet to the east of the Westside C&D property boundary. The western boundary of the site is established by the center-line run of Buck Branch. The adjoining properties on the west and east are owned by Wilson County. To the west, Wilson County has purchased the 76 acre property identified as the Mohesky Farm which provides additional off-site borrow resources for Wilson County Landfill projects. The closed Wilson County Landfill site is located due east of the Westside C&D site. Property further south of the Westside C&D facility is wooded and contains wetlands associated with the Toisnot Swamp. Prior to construction of the Westside C&D facility, agriculture was the primary land use in this area of Wilson County. Surrounding properties within 1,500 feet of the site are currently being used for farming, residential, or solid waste management purposes. Land south of the site is mostly wooded land with wetlands associated with the Toisnot Swamp. Land immediately west of the site is owned by Wilson County and used for recycling/reclamation and other solid waste management activities. Land north of the Site is mostly used for farmland with wooded areas. Land east of the Site is occupied by the closed Wilson County Landfill. 1.2 Site Geology The Westside C&D facility is located in the western portion of the Carolina Coastal Plain near the Fall Line. The Fall Line is the province boundary between the Piedmont and the Westside C&D Facility Water Quality Monitoring Report November 2016 Page 2 Coastal Plain provinces. It represents a significant change in lithology, which also reflects a change in stream gradients. Lithology of the Piedmont province is primarily igneous and metamorphic while the Coastal Plain province is primarily sedimentary. In general, rivers and streams in the Piedmont Province have higher flow rates with well defined channels while Coastal Plain rivers and streams are meandering with lesser defined channels resulting in swamps and bays. These streams, swamps, and bays are the major discharge point of the uppermost aquifer. The Carolina Coastal Plain is underlain by flat-lying to very gently eastward dipping sedimentary strata which overlay a foundation of crystalline rocks. These sediments were deposited during repeated marine transgressive and regressive cycles due to fluctuations in sea level caused by expansion and recession of glacial ice caps during the Pliocene and early Pleistocene epochs (approximately 2 to 5 million years ago). Sediments in the area of the Westside C&D facility are classified as being in the Yorktown Formation. Information gathered from the Geologic Map of North Carolina, 1985 and The Geology of the Carolina, 1991, cites that sediments of the Yorktown Formation are fossiliferous clay with varying amounts of fine-grained sand, silty sand, sandy silt, silty clay, and bluish gray shell material. These types of deposits are found mainly north of the Neuse River and are commonly concentrated in lenses and vary in vertical and horizontal dimensions. The topography of the Coastal Plain is characterized by flat to gently undulating relief. 1.3 Site Hydrogeology The subsurface conditions observed at the site reflect the regional Coastal Plain characteristics. The depositional environment is influenced by Buck Branch and Toisnot Westside C&D Facility Water Quality Monitoring Report November 2016 Page 3 Swamp, where fluvial sediments are interlaced with marine sediments in an estuarine environment. Where these streams once flowed into the Atlantic Ocean, a much broader river was likely present. Swift currents during flood conditions may have deposited lenticular beds of sand and other sediments. Incoming tidal currents reworked the stream sediments, creating alternating layers of fluvial and marine sediments. The local stratigraphy is characterized by relatively thin layers of fluvial and marine silt, sand, and clay in varying textures and colors. Typically, the color of fluvial sediments is tan, brown, light grey or orange. With the unconformities expected in this depositional environment, the typical profile includes a lean clay overlying poorly graded sands, interbedded with thin clay and clayey sand lenses. The water bearing zone is present in coarse and well graded sand layers, typically beneath surficial clay. Below the fluvial sediments, a marine clay layer is consistently encountered. This marine clay unit is typically dark grey, fat, and laminated with microlenses of fine sand. Below the marine clay, a dark greenish grey silty clayey sand overlies the residual, fully weathered bedrock. The bedrock was encountered approximately 30-35 feet below the disturbed land surface, at an elevation of 60 to 64 feet above mean sea level. Aquifer testing was conducted on six wells at the Westside C&D Landfill site. The aquifer testing was performed on February 12-13, 2003 and consisted of rising and falling head tests (slug tests) on wells P-103, P-104, P-105, P-106, P-108, and P-109. The purpose of the tests was to assess the values of horizontal hydraulic conductivity (K) at various locations within the water table aquifer. The results of the aquifer tests are provided below: Westside C&D Facility Water Quality Monitoring Report November 2016 Page 4 Well Number Test Type K (centimeters/second) P-103 (GMW-3) Falling 5.54 x 10-4 P-104 Falling 7.02 x 10-2 P-104 Rising 1.05 x 10-1 P-105 Falling 1.03 x 10-2 P-105 Rising 1.50 x 10-2 P-106 Falling 3.23 x 10-4 P-108 Falling 2.25 x 10-3 P-108 Rising 1.84 x 10-3 P-109 Falling 4.01 x 10-4 The aquifer testing performed for the site indicates that the upper water table aquifer provides hydraulic conductivity values which are directly related to presence of low permeability clays. The average hydraulic conductivity value for wells completed in primarily sandy material (P-104, P-105, P-108) is 4.09 x 10-2. The average hydraulic conductivity for wells completed in primarily clayey material (P-103, P-106, P-109) is 3.29 x 10-4. Based on the heterogeneity of the subsurface materials encountered during installation of the wells, the hydraulic conductivity is expected to vary based on the presence/absence of clayey soil. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 5 2.0 Water Quality Monitoring Program The water quality monitoring network at the Westside C&D facility is evaluated on a semi- annual basis. The location of the groundwater samples collected during the semi-annual monitoring events is shown on the attached Figure 1. 2.1 Groundwater Monitoring Network There are four groundwater monitoring wells located at the facility that comprise the existing groundwater monitoring system (Figure 1). Monitoring well GMW-1 is located on the northeast corner of the landfill area and serves as the upgradient groundwater monitoring well providing background water quality. Monitoring well GMW-2 is located on the southwest side of the landfill and monitors hydraulically downgradient groundwater quality. Monitoring well GMW-3 is located on the western side of the landfill and monitors hydraulically downgradient groundwater quality. Monitoring well GMW-4 is located on the northwest side of the landfill and monitors hydraulically downgradient groundwater quality. Table 2 provides monitoring well construction information including installation date, well depth/screened interval, survey elevations, and lat/long for each well location. Table 3 provides the estimated hydraulic conductivity values for select monitoring wells based on falling/rising head slug tests. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 6 3.0 Water Quality Sample Collection The groundwater samples were collected in accordance with the approved Westside C&D 2010 Water Quality Monitoring Plan and the 2008 NC Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling Guidance Document. A brief description of the sample collection procedure is provided below. 3.1 Field Sample Procedures Prior to groundwater sampling, water levels were obtained from each well using an electric water level meter capable of measuring the depth to water to the nearest 0.01 feet. This information was later used to determine the elevation of the water table in each monitoring well relative to surveyed datum (Table 2). The depth to water in each well was also used to determine the volume of standing water in the well casing. This information allowed for the purging of a minimum of three casing volumes from each well prior to sample collection to assure a fresh groundwater sample was collected. New disposable laboratory gloves were worn by sampling personnel and each well was purged and sampled with a new disposable bailer which was discarded after use. After the monitoring wells had been allowed to recover from purging, samples were collected in the following order:  Volatile organic compounds  Semi-volatile organic, pesticide/herbicide/PCB compounds  Inorganic compounds  Field Parameters (pH, Conductivity, Temperature) The samples are collected directly in the laboratory-supplied containers which are pre- filled with the appropriate preservative. No filtering of the samples is performed prior to Westside C&D Facility Water Quality Monitoring Report November 2016 Page 7 collection. After collection, the samples are placed in a cooler on ice for overnight shipment to the analytical laboratory. 3.2 Field Quality Assurance One trip blank sample was prepared by the analytical laboratory and accompanied the sample shipment until receipt back at the laboratory. The trip blank sample is analyzed for volatile organic compounds only. Temperature blanks are also provided with the sample shipments to assure the proper temperature is maintained until delivery to the analytical laboratory. 3.3 Sample Delivery/Chain of Custody All groundwater samples are stored in coolers on ice immediately after collection. Individual sample containers for each well or surface water sample are placed in zip lock plastic bags to reduce the potential for cross contamination. Chain-of-Custody control documents are prepared and shipped with each cooler. Custody seals are also used for each cooler to maintain sample integrity until delivery to the analytical laboratory. The sample coolers are shipped via Federal Express for next morning delivery to the analytical laboratory. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 8 4.0 Laboratory Analysis In accordance with correspondence from the NC Solid Waste Section dated October 14, 2016 requiring an Assessment Monitoring Workplan, a full Appendix II Assessment Monitoring compound list was analyzed in support of the pending assessment activities. The samples were analyzed for the full Appendix II compound list which includes: volatile organic compounds (VOCs) by EPA Method 8260B, semi-volatile organic compounds (SVOCs) by EPA Method 8270D, organochlorine pesticides by EPA Method 8081B, chlorinated herbicides by EPA Method 8151A, polychlorinated biphenyls by EPA Method 8082A, Appendix II inorganics by EPA Methods 6010D/6020B, mercury by EPA Method 7470A, cyanide by EPA Method 9014, and sulfide by Method SM4500S2D-2000. The laboratory performing the water quality analysis is Environmental Conservation Laboratories, Inc. (ENCO) of Cary, North Carolina, which is a NC Certified Laboratory. Internal quality control samples, including matrix spikes/matrix spike duplicates, are performed by ENCO for each set of samples. The ENCO laboratory report, including internal quality control samples, is provided with this report in Appendix A. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 9 5.0 Hydrogeological Conditions The depth to groundwater was measured in the four compliance monitoring wells during the November 2-3, 2016 monitoring event. The groundwater elevations were calculated relative to the surveyed measuring point (top of casing) for each monitoring well. The groundwater elevations are summarized on Table 2 and the potentiometric surface of the shallow water table is shown on Figure 1. The general direction of groundwater flow, based on the water level information collected during this monitoring event, is also shown on Figure 1. Groundwater flow direction is generally to the west-southwest, toward the Toisnot Swamp Canal. Based on the results of prior hydrologic tests conducted at the site, the groundwater flow rate in the shallow saprolite ranges from 0.916 ft/day to 297.64 ft/day. The average hydraulic conductivity and transmissivity values for the site are provided on Table 3. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 10 6.0 Laboratory Analytical Results Final laboratory analytical results for the samples collected on November 3, 2016 were received from the analytical laboratory on November 22, 2016. A summary of the analytical results and field parameters are provided on Table 1. 6.1 Groundwater Analytical Results During this monitoring event, only one volatile organic compound (VOC) was detected at concentrations exceeding the Solid Waste Section Limits (SWSLs) and 2L Groundwater Standards. The compound 1,2-dichloropropane was reported in monitoring well GMW-3 at a concentration of 1.4 ug/l. The established 2L Groundwater Standard for 1,2- dichloropropane is 0.6 ug/l. One other VOC was reported above the laboratory method reporting limit; the compound tetrahydrofuran was reported in monitoring well GMW-2 at a concentration of 2.7 ug/l. There is no SWSL or 2L Groundwater Standard for the compound tetrahydrofuran. No other VOCs were reported in any of the monitoring wells above the laboratory detection limits, SWSLs, or 2L Groundwater Standards. The laboratory analyses reported two inorganic compounds in the background groundwater monitoring well (GMW-1) at concentrations which exceeded the 2L Groundwater Standards. The inorganic compounds arsenic (15 ug/l) and chromium (20 ug/l) each exceeded their respective 2L Groundwater Standard. The 2L Groundwater Standard for arsenic and chromium are both established at 10 ug/l. The inorganic compounds barium, beryllium cobalt, lead, vanadium, and zinc were also reported in monitoring well GMW-1 at concentrations above the SWSLs but below the 2L Groundwater Standards. No inorganic compounds were reported above the 2L Groundwater Standards in any of the downgradient groundwater monitoring wells (GMW-2, GMW-3, or GMW-4). Westside C&D Facility Water Quality Monitoring Report November 2016 Page 11 However, the inorganic compounds barium, beryllium, cadmium, cobalt, and zinc were reported above the SWSLs but below the 2L Groundwater Standards. The laboratory analyses for semi-volatile organic compounds, organochlorine pesticides, chlorinated herbicides, polychlorinated biphenyls, mercury, cyanide, and sulfide did not report any detectable concentrations above the laboratory method reporting limits, SWSLs, or 2L Groundwater Standards. A summary of the groundwater laboratory analytical results and the corresponding 2L Groundwater Standards is provided on Table 1. 6.2 Quality Control Sample The laboratory supplied trip blank did not detect any VOCs at a concentration equaling or exceeding laboratory method reporting limits, SWSLs, or 2L Groundwater Standards. Westside C&D Facility Water Quality Monitoring Report November 2016 Page 12 7.0 Conclusions The results of this monitoring event report only minor variants from the established NC 2L Groundwater Standards. Based on the results of this water quality monitoring event and correspondence from the NC Solid Waste Section, the Westside C&D facility will prepare an Assessment Monitoring Workplan which will be submitted to the Section for review and approval. This Workplan will be submitted to the NC Solid Waste Section no later than December 13, 2016. Attachments to this report include tables summarizing the groundwater analytical results and field parameters (Tables 1), well construction information (Table 2), and hydrologic test results (Table 3). A copy of the laboratory analytical report in pdf and EDD formats is also included with this report in Appendix A. SITE MAP TABLES TABLE 1 November 2016 Groundwater Analytical Results Westside CDLF Facility Wilson County, North Carolina Permit No. 98-09 Parameter GMW-1 GMW-2 GMW-3 GMW-4 2L Standard pH 7.6 5.0 3.8 4.7 6.5 - 8.5 Conductivity 83 347 163 62 NE Temperature 18.5 19.6 21.1 22.2 NE Inorganics (ug/l) Antimony 0.242 J BQL BQL 0.832 J 10 Arsenic 15.0 BQL 8.03 J BQL 10 Barium 176 84.7 J 170 67.2 J 700 Beryllium 2.24 0.317 J 2.69 BQL NE Cadmium BQL 1.65 BQL BQL 2 Chromium 20.0 BQL 6.51 J BQL 10 Cobalt 12.0 79.9 18.3 BQL NE Copper 6.13 J 1.62 J 2.24 J 1.60 J 1000 Lead 14.0 BQL 7.30 J BQL 15 Nickel 15.2 J 17.2 J 24.2 J 2.81 J 100 Thallium 0.709 J 0.237 J 0.168 J BQL NE Vanadium 33.3 BQL 11.3 J 2.13 J NE Zinc 51.3 46.2 73.9 27.9 J 1000 8260 volatiles (ug/l) Acetonitrile 24 JB 31 JB BQL BQL NE 1,2-Dichloropropane BQL BQL 1.4 BQL 0.6 Tetrahydrofuran BQL 2.7 BQL BQL NE Notes: Samples collected on November 3, 2016 BQL - Below laboratory quantitation limits J - Between MDL and RL B - Compound present in method blank NE - Not established Bold concentrations equal or exceed established standards TA B L E 2 Gr o u n d w a t e r M o n i t o r i n g W e l l C o n s t r u c t i o n We s t s i d e C / D F a c i l i t y Wi l s o n , N o r t h C a r o l i i n a Pe r m i t # 9 8 - 0 9 We l l I D Da t e Dr i l l e d We l l Di a m e t e r To t a l De p t h TO S De p t h Sc r e e n e d In t e r v a l Gr o u n d El e v a t i o n TO C El e v a t i o n Gr o u n d w a t e r De p t h Gr o u n d w a t e r El e v a t i o n La t / L o n g G e o l o g y GM W - 1 4 / 2 0 / 1 5 2 " 2 0 . 0 ' 1 0 . 0 ' 1 0 ' - 2 0 ' 1 0 8 . 4 0 1 1 2 . 0 4 1 1 . 7 0 1 0 0 . 3 4 71 8 5 3 0 . 0 6 7 N 23 3 9 5 6 5 . 8 6 2 E clayey SAND GM W - 2 9 / 1 4 / 0 4 2 " 1 7 . 0 ' 7 . 0 ' 7 ' - 1 7 ' 9 0 . 4 4 9 3 . 1 3 5 . 1 2 8 8 . 0 1 71 7 4 2 5 . 6 4 4 N 23 3 9 0 0 4 . 6 5 5 E clayey SAND GM W - 3 9 / 1 4 / 0 4 2 " 1 5 . 0 ' 5 . 0 ' 5 ' - 1 5 ' 9 1 . 8 2 9 6 . 1 1 7 . 2 2 8 8 . 8 9 71 7 6 3 9 . 9 6 7 N 23 3 8 7 4 2 . 3 6 9 E clayey SAND GM W - 4 9 / 1 4 / 0 4 2 " 1 5 . 0 ' 5 . 0 ' 5 ' - 1 5 ' 9 3 . 5 1 9 5 . 7 7 7 . 5 6 8 8 . 2 1 71 7 9 0 0 . 5 6 0 N 23 3 8 6 4 4 . 5 1 7 E clayey SAND TO S - T o p o f S c r e e n TO C - T o p o f C a s i n g Gr o u n d w a t e r d e p t h s c o l l e c t e d o n 1 1 / 2 / 2 0 1 6 TA B L E 3 Gr o u n d w a t e r F l o w R a t e s 1 We s t s i d e C / D L a n d f i l l Wi l s o n , N o r t h C a r o l i n a Pe r m i t # 9 8 - 0 9 Te s t P i e z o m e t e r T e s t T y p e 2 Hy d r a u l i c C o n d u c t i v i t y (c e n t i m e t e r s / s e c o n d ) Hy d r a u l i c C o n d u c t i v i t y (f e e t / d a y ) Geologic Material P- 1 0 3 F a l l i n g H e a d 5 . 5 4 x 1 0 -4 1. 5 7 s l i t y C L A Y P- 1 0 4 F a l l i n g H e a d 7 . 0 2 x 1 0 -2 19 8 . 9 9 s i l t y c l a y e y S A N D P- 1 0 4 R i s i n g H e a d 1 . 0 5 x 1 0 -1 29 7 . 6 4 s i l t y c l a y e y S A N D P- 1 0 5 F a l l i n g H e a d 1 . 0 3 x 1 0 -2 29 . 2 s i l t y c l a y e y S A N D P- 1 0 5 R i s i n g H e a d 1 . 5 0 x 1 0 -2 42 . 5 2 s i l t y c l a y e y S A N D P- 1 0 6 F a l l i n g H e a d 3 . 2 3 x 1 0 -4 0. 9 1 6 s l i t y C L A Y P- 1 0 8 F a l l i n g H e a d 2 . 2 5 x 1 0 -3 6. 3 8 s i l t y c l a y e y S A N D P- 1 0 8 R i s i n g H e a d 1 . 8 4 x 1 0 -3 5. 2 2 s i l t y c l a y e y S A N D P- 1 0 9 F a l l i n g H e a d 4 . 0 4 x 1 0 -4 1. 1 4 s l i t y C L A Y 1 D a t a f r o m W e s t s i d e C & D L a n d f i l l 2 0 0 3 S i t e P l a n A p p l i c a t i o n 2 A q u i f e r T e s t i n g b y f a l l i n g / r i s i n g h e a d s l u g t e s t s , a n a l y z e d us i n g B o u w e r a n d R i c e m e t h o d LAB REPORT 102-A Woodwinds Industrial Court Cary NC, 27511 919.467.3090 919.467.3515Phone:FAX:www.encolabs.com Environmental Conservation Laboratories, Inc. ENCO Workorder(s): CZ15795 Raleigh, NC 27606 Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Enclosure(s) Project Number: [none], Project Name/Desc: Wilson C&D App II Attn: Gary Babb Babb & Associates (BA024) 3605 Country Cove Lane Bill Scott Project Manager Tuesday, November 22, 2016 RE: Laboratory Results for Dear Gary Babb, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, November 4, 2016. The total number of pages in this report, including this page is 71. Page 1 of 72 www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE 9809-GMW1 CZ15795-01 Sampled:11/03/16 08:10 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 6010D 05/02/17 11/07/16 14:39 11/15/2016 11:28 EPA 6020B 05/02/17 11/07/16 14:43 11/16/2016 11:43 EPA 7470A 12/01/16 11/16/16 10:21 11/17/2016 13:26 EPA 8081B 11/10/16 11/09/16 08:17 11/15/2016 14:5112/19/16 EPA 8082A 11/03/17 11/09/16 08:13 11/16/2016 15:5612/19/16 EPA 8151A 11/10/16 11/10/16 12:55 11/14/2016 10:2612/20/16 EPA 8260B 11/17/16 11/07/16 08:13 11/7/2016 21:18 EPA 8270D 11/10/16 11/08/16 08:50 11/21/2016 16:3812/18/16 EPA 9014 11/17/16 11/08/16 12:13 11/11/2016 08:35 SM 4500S2 D-2000 11/10/16 11/10/16 17:45 11/10/2016 18:00 9809-GMW1 CZ15795-01RE1 Sampled:11/03/16 08:10 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 6020B 05/02/17 11/07/16 14:43 11/16/2016 13:12 9809-GMW2 CZ15795-02 Sampled:11/03/16 08:50 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 6010D 05/02/17 11/07/16 14:39 11/15/2016 11:31 EPA 6020B 05/02/17 11/07/16 14:43 11/16/2016 11:47 EPA 7470A 12/01/16 11/16/16 10:21 11/17/2016 13:06 EPA 8081B 11/10/16 11/09/16 08:17 11/15/2016 15:0512/19/16 EPA 8082A 11/03/17 11/09/16 08:13 11/16/2016 16:0912/19/16 EPA 8151A 11/10/16 11/10/16 12:55 11/14/2016 10:5112/20/16 EPA 8260B 11/17/16 11/07/16 08:13 11/7/2016 21:48 EPA 8270D 11/10/16 11/08/16 08:50 11/21/2016 17:1112/18/16 EPA 9014 11/17/16 11/08/16 12:13 11/11/2016 08:39 SM 4500S2 D-2000 11/10/16 11/10/16 17:45 11/10/2016 18:00 9809-GMW3 CZ15795-03 Sampled:11/03/16 09:05 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 6010D 05/02/17 11/07/16 14:39 11/15/2016 11:33 EPA 6020B 05/02/17 11/07/16 14:43 11/16/2016 11:50 EPA 7470A 12/01/16 11/16/16 10:21 11/17/2016 13:28 EPA 8081B 11/10/16 11/09/16 08:17 11/15/2016 15:1812/19/16 EPA 8082A 11/03/17 11/09/16 08:13 11/16/2016 16:2312/19/16 EPA 8151A 11/10/16 11/10/16 12:55 11/14/2016 11:1712/20/16 EPA 8260B 11/17/16 11/04/16 14:07 11/5/2016 07:07 EPA 8270D 11/10/16 11/08/16 08:50 11/21/2016 17:4312/18/16 EPA 9014 11/17/16 11/08/16 12:13 11/11/2016 08:41 SM 4500S2 D-2000 11/10/16 11/10/16 17:45 11/10/2016 18:00 Page 2 of 71 Page 2 of 72 www.encolabs.com 9809-GMW4 CZ15795-04 Sampled:11/03/16 09:27 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 6010D 05/02/17 11/07/16 14:39 11/15/2016 11:35 EPA 6020B 05/02/17 11/07/16 14:43 11/16/2016 11:25 EPA 7470A 12/01/16 11/16/16 10:21 11/17/2016 13:31 EPA 8081B 11/10/16 11/09/16 08:17 11/15/2016 15:3212/19/16 EPA 8082A 11/03/17 11/09/16 08:13 11/16/2016 16:3712/19/16 EPA 8151A 11/10/16 11/10/16 12:55 11/14/2016 11:4212/20/16 EPA 8260B 11/17/16 11/04/16 14:07 11/5/2016 07:36 EPA 8270D 11/10/16 11/08/16 08:50 11/21/2016 18:1612/18/16 EPA 9014 11/17/16 11/08/16 12:13 11/11/2016 08:43 SM 4500S2 D-2000 11/10/16 11/10/16 17:45 11/10/2016 18:00 9809-tripblank CZ15795-05RE1 Sampled:11/03/16 08:10 Received:11/04/16 09:45Client ID:Lab ID: Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s) EPA 8260B 11/17/16 11/07/16 11:47 11/7/2016 17:16 Page 3 of 71 Page 3 of 72 www.encolabs.com NORTH CAROLINA SWS SAMPLE DETECTION SUMMARY Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW1 CZ15795-01 Flag NotesMDLNC SWSLMRLDF 24 ug/L EPA 8260BJB O-0155105.01Acetonitrile 0.242 ug/L EPA 6020BJ 62.000.2201Antimony - Total 15.0 ug/L EPA 6010D 1010.06.801Arsenic - Total 176 ug/L EPA 6010D 10010.01.001Barium - Total 2.24 ug/L EPA 6010D 11.000.1001Beryllium - Total 20.0 ug/L EPA 6010D 1010.01.401Chromium - Total 12.0 ug/L EPA 6010D 1010.01.101Cobalt - Total 6.13 ug/L EPA 6010DJ 1010.01.601Copper - Total 14.0 ug/L EPA 6010D 1010.03.101Lead - Total 15.2 ug/L EPA 6010DJ 5010.02.201Nickel - Total 33.3 ug/L EPA 6010D 2510.01.401Vanadium - Total 51.3 ug/L EPA 6010D 1010.04.401Zinc - Total Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW1 CZ15795-01RE1 Flag NotesMDLNC SWSLMRLDF 0.709 ug/L EPA 6020BJD 5.55.000.5505Thallium - Total Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW2 CZ15795-02 Flag NotesMDLNC SWSLMRLDF 31 ug/L EPA 8260BJB O-0155105.01Acetonitrile 84.7 ug/L EPA 6010DJ 10010.01.001Barium - Total 0.317 ug/L EPA 6010DJ 11.000.1001Beryllium - Total 1.65 ug/L EPA 6010D 11.000.3601Cadmium - Total 79.9 ug/L EPA 6010D 1010.01.101Cobalt - Total 1.62 ug/L EPA 6010DJ 1010.01.601Copper - Total 17.2 ug/L EPA 6010DJ 5010.02.201Nickel - Total 2.7 ug/L EPA 8260B NE1.00.801Tetrahydrofuran 0.237 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total 46.2 ug/L EPA 6010D 1010.04.401Zinc - Total Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW3 CZ15795-03 Flag NotesMDLNC SWSLMRLDF 1.4 ug/L EPA 8260B 11.00.1011,2-Dichloropropane 8.03 ug/L EPA 6010DJ 1010.06.801Arsenic - Total 170 ug/L EPA 6010D 10010.01.001Barium - Total 2.69 ug/L EPA 6010D 11.000.1001Beryllium - Total 6.51 ug/L EPA 6010DJ 1010.01.401Chromium - Total 18.3 ug/L EPA 6010D 1010.01.101Cobalt - Total 2.24 ug/L EPA 6010DJ 1010.01.601Copper - Total 7.30 ug/L EPA 6010DJ 1010.03.101Lead - Total 24.2 ug/L EPA 6010DJ 5010.02.201Nickel - Total 0.168 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total 11.3 ug/L EPA 6010DJ 2510.01.401Vanadium - Total 73.9 ug/L EPA 6010D 1010.04.401Zinc - Total Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW4 CZ15795-04 Flag NotesMDLNC SWSLMRLDF 0.832 ug/L EPA 6020BJ 62.000.2201Antimony - Total Page 4 of 71 Page 4 of 72 www.encolabs.com Analyte MethodUnitsResults Lab ID:Client ID:9809-GMW4 CZ15795-04 Flag NotesMDLNC SWSLMRLDF 67.2 ug/L EPA 6010DJ 10010.01.001Barium - Total 1.60 ug/L EPA 6010DJ 1010.01.601Copper - Total 2.81 ug/L EPA 6010DJ 5010.02.201Nickel - Total 2.13 ug/L EPA 6010DJ 2510.01.401Vanadium - Total 27.9 ug/L EPA 6010D 1010.04.401Zinc - Total Analyte MethodUnitsResults Lab ID:Client ID:9809-tripblank CZ15795-05RE1 Flag NotesMDLNC SWSLMRLDF 6.0 ug/L EPA 8260BJB O-0155105.01Acetonitrile Page 5 of 71 Page 5 of 72 www.encolabs.com ANALYTICAL RESULTS 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 21:181,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MRK1.00.17 U 51 ug/L EPA 8260B 11/07/16 21:181,1,1-Trichloroethane [71-55-6] ^0.12 MRK1.00.12 U 11 ug/L EPA 8260B 11/07/16 21:181,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MRK1.00.28 U 31 ug/L EPA 8260B 11/07/16 21:181,1,2-Trichloroethane [79-00-5] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 21:181,1-Dichloroethane [75-34-3] ^0.13 MRK1.00.13 U 51 ug/L EPA 8260B 11/07/16 21:181,1-Dichloroethene [75-35-4] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 21:181,1-Dichloropropene [563-58-6] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:181,2,3-Trichloropropane [96-18-4] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 21:181,2,4-Trichlorobenzene [120-82-1] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 21:181,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MRK1.00.48 U 131 ug/L EPA 8260B 11/07/16 21:181,2-Dibromoethane [106-93-4] ^0.66 MRK1.00.66 U 11 ug/L EPA 8260B 11/07/16 21:181,2-Dichlorobenzene [95-50-1] ^0.19 MRK1.00.19 U 51 ug/L EPA 8260B 11/07/16 21:181,2-Dichloroethane [107-06-2] ^0.21 MRK1.00.21 U 11 ug/L EPA 8260B 11/07/16 21:181,2-Dichloropropane [78-87-5] ^0.10 MRK1.00.10 U 11 ug/L EPA 8260B 11/07/16 21:181,3-Dichlorobenzene [541-73-1] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:181,3-Dichloropropane [142-28-9] ^0.16 MRK1.00.16 U 11 ug/L EPA 8260B 11/07/16 21:181,4-Dichlorobenzene [106-46-7] ^0.19 MRK1.00.19 U 11 ug/L EPA 8260B 11/07/16 21:182,2-Dichloropropane [594-20-7] ^0.28 MRK1.00.28 U 151 ug/L EPA 8260B 11/07/16 21:182-Butanone [78-93-3] ^1.3 MRK5.01.3 U 1001 ug/L EPA 8260B 11/07/16 21:182-Hexanone [591-78-6] ^0.88 MRK5.00.88 U 501 ug/L EPA 8260B 11/07/16 21:183-Chloropropene [107-05-1] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 21:184-Methyl-2-pentanone [108-10-1] ^1.1 MRK5.01.1 U 1001 ug/L EPA 8260B 11/07/16 21:18Acetone [67-64-1] ^10 MRK2010U 1001 ug/L EPA 8260B 11/07/16 21:18Acetonitrile [75-05-8] ^5.0 MRK1024JB O-01551 ug/L EPA 8260B 11/07/16 21:18Acrolein [107-02-8] ^4.0 MRK104.0 U 531 ug/L EPA 8260B 11/07/16 21:18Acrylonitrile [107-13-1] ^3.5 MRK103.5 U 2001 ug/L EPA 8260B 11/07/16 21:18Benzene [71-43-2] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:18Bromochloromethane [74-97-5] ^0.48 MRK1.00.48 U 31 ug/L EPA 8260B 11/07/16 21:18Bromodichloromethane [75-27-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:18Bromoform [75-25-2] ^0.22 MRK1.00.22 U 31 ug/L EPA 8260B 11/07/16 21:18Bromomethane [74-83-9] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 21:18Carbon disulfide [75-15-0] ^1.5 MRK5.01.5 U 1001 ug/L EPA 8260B 11/07/16 21:18Carbon tetrachloride [56-23-5] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:18Chlorobenzene [108-90-7] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 21:18Chloroethane [75-00-3] ^0.23 MRK1.00.23 U 101 ug/L EPA 8260B 11/07/16 21:18Chloroform [67-66-3] ^0.18 MRK1.00.18 U 51 ug/L EPA 8260B 11/07/16 21:18Chloromethane [74-87-3] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 21:18Chloroprene [126-99-8] ^0.64 MRK1.00.64 U 201 ug/L EPA 8260B 11/07/16 21:18cis-1,2-Dichloroethene [156-59-2] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:18cis-1,3-Dichloropropene [10061-01-5] ^0.20 MRK1.00.20 U 11 ug/L EPA 8260B 11/07/16 21:18Dibromochloromethane [124-48-1] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 21:18Dibromomethane [74-95-3] ^0.27 MRK1.00.27 U 101 ug/L EPA 8260B 11/07/16 21:18Dichlorodifluoromethane [75-71-8] ^0.20 MRK1.00.20 U 51 ug/L EPA 8260B 11/07/16 21:18Ethyl Methacrylate [97-63-2] ^0.38 MRK1.00.38 U 101 ug/L EPA 8260B 11/07/16 21:18Ethylbenzene [100-41-4] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 21:18Hexachlorobutadiene [87-68-3] ^0.22 MRK1.00.22 U 101 ug/L EPA 8260B 11/07/16 21:18Iodomethane [74-88-4] ^1.7 MRK5.01.7 U 101 ug/L EPA 8260B 11/07/16 21:18Isobutyl alcohol [78-83-1] ^11 MRK5011U 1001 Page 6 of 71 Page 6 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 21:18m,p-Xylenes [108-38-3/106-42-3] ^0.17 MRK2.00.17 U NE1 ug/L EPA 8260B 11/07/16 21:18Methacrylonitrile [126-98-7] ^4.9 MRK104.9 U 1001 ug/L EPA 8260B 11/07/16 21:18Methyl Methacrylate [80-62-6] ^0.51 MRK1.00.51 U 301 ug/L EPA 8260B 11/07/16 21:18Methylene chloride [75-09-2] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 21:18Naphthalene [91-20-3] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 21:18o-Xylene [95-47-6] ^0.065 MRK1.00.065 U NE1 ug/L EPA 8260B 11/07/16 21:18Propionitrile [107-12-0] ^5.0 MRK105.0 U 1501 ug/L EPA 8260B 11/07/16 21:18Styrene [100-42-5] ^0.11 MRK1.00.11 U 11 ug/L EPA 8260B 11/07/16 21:18Tetrachloroethene [127-18-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:18Tetrahydrofuran [109-99-9] ^0.80 MRK1.00.80 U 1 ug/L EPA 8260B 11/07/16 21:18Toluene [108-88-3] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 21:18trans-1,2-Dichloroethene [156-60-5] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 21:18trans-1,3-Dichloropropene [10061-02-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:18trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MRK1.00.70 U 1001 ug/L EPA 8260B 11/07/16 21:18Trichloroethene [79-01-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:18Trichlorofluoromethane [75-69-4] ^0.24 MRK1.00.24 U 11 ug/L EPA 8260B 11/07/16 21:18Vinyl acetate [108-05-4] ^0.95 MRK5.00.95 U 501 ug/L EPA 8260B 11/07/16 21:18Vinyl chloride [75-01-4] ^0.32 MRK1.00.32 U 11 ug/L EPA 8260B 11/07/16 21:18Xylenes (Total) [1330-20-7] ^0.45 MRK3.00.45 U 51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 4-Bromofluorobenzene 53-13692 %MRKEPA 8260B 11/07/16 21:186K070044650.0 1 Dibromofluoromethane 67-129103 %MRKEPA 8260B 11/07/16 21:186K070045250.0 1 Toluene-d8 59-13498 %MRKEPA 8260B 11/07/16 21:186K070044950.0 1 Page 7 of 71 Page 7 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 16:381,2,4,5-Tetrachlorobenzene [95-94-3] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 16:381,3,5-Trinitrobenzene [99-35-4] ^3.0 DFM103.0 U 101 ug/L EPA 8270D 11/21/16 16:381,3-Dinitrobenzene [99-65-0] ^1.9 DFM101.9 U 201 ug/L EPA 8270D 11/21/16 16:381,4-Naphthoquinone [130-15-4] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 16:381,4-Phenylenediamine [106-50-3] ^4.0 DFM104.0 U QV-02101 ug/L EPA 8270D 11/21/16 16:381-Naphthylamine [134-32-7] ^1.9 DFM101.9 U QV-02101 ug/L EPA 8270D 11/21/16 16:382,3,4,6-Tetrachlorophenol [58-90-2] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 16:382,4,5-Trichlorophenol [95-95-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:382,4,6-Trichlorophenol [88-06-2] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:382,4-Dichlorophenol [120-83-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:382,4-Dimethylphenol [105-67-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:382,4-Dinitrophenol [51-28-5] ^2.6 DFM102.6 U 501 ug/L EPA 8270D 11/21/16 16:382,4-Dinitrotoluene [121-14-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 16:382,6-Dichlorophenol [87-65-0] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:382,6-Dinitrotoluene [606-20-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 16:382-Acetylaminofluorene [53-96-3] ^2.5 DFM102.5 U 201 ug/L EPA 8270D 11/21/16 16:382-Chloronaphthalene [91-58-7] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:382-Chlorophenol [95-57-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:382-Methyl-4,6-dinitrophenol [534-52-1] ^2.9 DFM102.9 U 501 ug/L EPA 8270D 11/21/16 16:382-Methylnaphthalene [91-57-6] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 16:382-Methylphenol [95-48-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:382-Naphthylamine [91-59-8] ^3.0 DFM103.0 U QV-02101 ug/L EPA 8270D 11/21/16 16:382-Nitroaniline [88-74-4] ^1.5 DFM101.5 U 501 ug/L EPA 8270D 11/21/16 16:382-Nitrophenol [88-75-5] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:383 & 4-Methylphenol [108-39-4/106-44-5] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 16:383,3'-Dichlorobenzidine [91-94-1] ^3.3 DFM103.3 U 201 ug/L EPA 8270D 11/21/16 16:383,3'-Dimethylbenzidine [119-93-7] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 16:383-Methylcholanthrene [56-49-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:383-Nitroaniline [99-09-2] ^2.1 DFM102.1 U 501 ug/L EPA 8270D 11/21/16 16:384-Aminobiphenyl [92-67-1] ^2.1 DFM102.1 U QV-02201 ug/L EPA 8270D 11/21/16 16:384-Bromophenyl-phenylether [101-55-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:384-Chloro-3-methylphenol [59-50-7] ^1.5 DFM101.5 U 201 ug/L EPA 8270D 11/21/16 16:384-Chloroaniline [106-47-8] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 16:384-Chlorophenyl-phenylether [7005-72-3] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 16:384-Nitroaniline [100-01-6] ^3.2 DFM103.2 U 201 ug/L EPA 8270D 11/21/16 16:384-Nitrophenol [100-02-7] ^2.0 DFM102.0 U 501 ug/L EPA 8270D 11/21/16 16:385-Nitro-o-toluidine [99-55-8] ^3.2 DFM103.2 U 101 ug/L EPA 8270D 11/21/16 16:387,12-Dimethylbenz(a)anthracene [57-97-6] ^ 1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:38Acenaphthene [83-32-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Acenaphthylene [208-96-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38Acetophenone [98-86-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Anthracene [120-12-7] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 16:38Benzo(a)anthracene [56-55-3] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Benzo(a)pyrene [50-32-8] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Benzo(b)fluoranthene [205-99-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Benzo(g,h,i)perylene [191-24-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 16:38Benzo(k)fluoranthene [207-08-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Benzyl alcohol [100-51-6] ^1.4 DFM101.4 U 201 ug/L EPA 8270D 11/21/16 16:38Bis(2-chloroethoxy)methane [111-91-1] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Bis(2-chloroethyl)ether [111-44-4] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38Bis(2-chloroisopropyl)ether [108-60-1] ^1.3 DFM101.3 U 101 Page 8 of 71 Page 8 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 16:38Bis(2-ethylhexyl)phthalate [117-81-7] ^1.7 DFM5.01.7 U 151 ug/L EPA 8270D 11/21/16 16:38Butylbenzylphthalate [85-68-7] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 16:38Chlorobenzilate [510-15-6] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Chrysene [218-01-9] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 16:38Diallate [2303-16-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Dibenzo(a,h)anthracene [53-70-3] ^2.3 DFM102.3 U 101 ug/L EPA 8270D 11/21/16 16:38Dibenzofuran [132-64-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Diethylphthalate [84-66-2] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 16:38Dimethoate [60-51-5] ^2.3 DFM102.3 U 201 ug/L EPA 8270D 11/21/16 16:38Dimethylphthalate [131-11-3] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Di-n-butylphthalate [84-74-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 16:38Di-n-octylphthalate [117-84-0] ^3.1 DFM103.1 U 101 ug/L EPA 8270D 11/21/16 16:38Disulfoton [298-04-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:38Ethyl methanesulfonate [62-50-0] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 16:38Famphur [52-85-7] ^2.7 DFM102.7 U QV-01201 ug/L EPA 8270D 11/21/16 16:38Fluoranthene [206-44-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 16:38Fluorene [86-73-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 16:38Hexachlorobenzene [118-74-1] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Hexachlorobutadiene [87-68-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38Hexachlorocyclopentadiene [77-47-4] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Hexachloroethane [67-72-1] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:38Hexachloropropene [1888-71-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 16:38Indeno(1,2,3-cd)pyrene [193-39-5] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 16:38Isodrin [465-73-6] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 16:38Isophorone [78-59-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Isosafrole [120-58-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Kepone [143-50-0] ^7.2 DFM207.2 U QV-01201 ug/L EPA 8270D 11/21/16 16:38Methapyrilene [91-80-5] ^3.5 DFM103.5 U 1001 ug/L EPA 8270D 11/21/16 16:38Methyl Methanesulfonate [66-27-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Methyl parathion [298-00-0] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 16:38Nitrobenzene [98-95-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38N-Nitrosodiethylamine [55-18-5] ^1.3 DFM101.3 U 201 ug/L EPA 8270D 11/21/16 16:38N-Nitrosodimethylamine [62-75-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38N-Nitrosodi-n-butylamine [924-16-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38N-Nitroso-di-n-propylamine [621-64-7] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 16:38N-nitrosodiphenylamine/Diphenylamine [86-30-6/122-39-4] ^ 2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 16:38N-Nitrosomethylethylamine [10595-95-6] ^1.9 DFM101.9 U 101 ug/L EPA 8270D 11/21/16 16:38N-Nitrosopiperidine [100-75-4] ^1.1 DFM101.1 U 201 ug/L EPA 8270D 11/21/16 16:38N-Nitrosopyrrolidine [930-55-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38O,O,O-Triethyl phosphorothioate [126-68-1] ^ 1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38o-Toluidine [95-53-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 16:38Parathion [56-38-2] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 16:38p-Dimethylaminoazobenzene [60-11-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Pentachlorobenzene [608-93-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 16:38Pentachloronitrobenzene [82-68-8] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 16:38Phenacetin [62-44-2] ^2.7 DFM102.7 U 201 ug/L EPA 8270D 11/21/16 16:38Phenanthrene [85-01-8] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Phenol [108-95-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 16:38Phorate [298-02-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 16:38Pronamide [23950-58-5] ^1.4 DFM101.4 U 101 Page 9 of 71 Page 9 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 16:38Pyrene [129-00-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 16:38Safrole [94-59-7] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 16:38Thionazin [297-97-2] ^2.3 DFM102.3 U 201 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,6-Tribromophenol 10-17998 %DFMEPA 8270D 11/21/16 16:386K0800298100 1 2-Fluorobiphenyl 10-14996 %DFMEPA 8270D 11/21/16 16:386K080024850.0 1 2-Fluorophenol 10-11068 %DFMEPA 8270D 11/21/16 16:386K0800268100 1 Nitrobenzene-d5 10-14989 %DFMEPA 8270D 11/21/16 16:386K080024450.0 1 Phenol-d5 10-8860 %DFMEPA 8270D 11/21/16 16:386K0800260100 1 Terphenyl-d14 10-18895 %DFMEPA 8270D 11/21/16 16:386K080024850.0 1 Page 10 of 71 Page 10 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Organochlorine Pesticides by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8081B 11/15/16 14:514,4'-DDD [72-54-8] ^0.044 MWC0.0500.044 U 0.11 ug/L EPA 8081B 11/15/16 14:514,4'-DDE [72-55-9] ^0.048 MWC0.0500.048 U 0.11 ug/L EPA 8081B 11/15/16 14:514,4'-DDT [50-29-3] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 14:51Aldrin [309-00-2] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 14:51alpha-BHC [319-84-6] ^0.036 MWC0.0500.036 U 0.051 ug/L EPA 8081B 11/15/16 14:51beta-BHC [319-85-7] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 14:51Chlordane (tech) [12789-03-6] ^0.37 MWC0.500.37 U 0.51 ug/L EPA 8081B 11/15/16 14:51Chlordane-alpha [5103-71-9] ^0.048 MWC0.0500.048 U NE1 ug/L EPA 8081B 11/15/16 14:51Chlordane-gamma [5566-34-7] ^0.042 MWC0.0500.042 U NE1 ug/L EPA 8081B 11/15/16 14:51delta-BHC [319-86-8] ^0.048 MWC0.0500.048 U 0.051 ug/L EPA 8081B 11/15/16 14:51Dieldrin [60-57-1] ^0.045 MWC0.0500.045 U 0.0751 ug/L EPA 8081B 11/15/16 14:51Endosulfan I [959-98-8] ^0.045 MWC0.0500.045 U 0.11 ug/L EPA 8081B 11/15/16 14:51Endosulfan II [33213-65-9] ^0.038 MWC0.0500.038 U 0.11 ug/L EPA 8081B 11/15/16 14:51Endosulfan sulfate [1031-07-8] ^0.032 MWC0.0500.032 U 0.11 ug/L EPA 8081B 11/15/16 14:51Endrin [72-20-8] ^0.041 MWC0.0500.041 U 0.11 ug/L EPA 8081B 11/15/16 14:51Endrin aldehyde [7421-93-4] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 14:51gamma-BHC [58-89-9] ^0.034 MWC0.0500.034 U 0.051 ug/L EPA 8081B 11/15/16 14:51Heptachlor [76-44-8] ^0.047 MWC0.0500.047 U 0.051 ug/L EPA 8081B 11/15/16 14:51Heptachlor epoxide [1024-57-3] ^0.037 MWC0.0500.037 U 0.0751 ug/L EPA 8081B 11/15/16 14:51Methoxychlor [72-43-5] ^0.048 MWC0.0500.048 U 11 ug/L EPA 8081B 11/15/16 14:51Toxaphene [8001-35-2] ^0.28 MWC0.500.28 U 1.51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 44-13479 %MWCEPA 8081B 11/15/16 14:516K090010.79 1.00 1 Decachlorobiphenyl 37-14964 %MWCEPA 8081B 11/15/16 14:516K090010.64 1.00 1 Page 11 of 71 Page 11 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Polychlorinated Biphenyls by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8082A 11/16/16 15:56PCB-1016/1242 [12674-11-2/53469-21-9] ^0.48 MWC0.500.48 U 21 ug/L EPA 8082A 11/16/16 15:56PCB-1221 [11104-28-2] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 15:56PCB-1232 [11141-16-5] ^0.50 MWC0.500.50 U NE1 ug/L EPA 8082A 11/16/16 15:56PCB-1248 [12672-29-6] ^0.30 MWC0.500.30 U NE1 ug/L EPA 8082A 11/16/16 15:56PCB-1254 [11097-69-1] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 15:56PCB-1260 [11096-82-5] ^0.45 MWC0.500.45 U NE1 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 45-15159 %MWCEPA 8082A 11/16/16 15:566K090020.59 1.00 1 Decachlorobiphenyl 42-15966 %MWCEPA 8082A 11/16/16 15:566K090020.66 1.00 1 Page 12 of 71 Page 12 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 7470A 11/17/16 13:26Mercury [7439-97-6] ^0.170 JMV0.2000.170 U 0.21 Page 13 of 71 Page 13 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 6020B 11/16/16 11:43Antimony [7440-36-0] ^0.220 VLO2.000.242 J 61 ug/L EPA 6010D 11/15/16 11:28Arsenic [7440-38-2] ^6.80 JDH10.015.0 101 ug/L EPA 6010D 11/15/16 11:28Barium [7440-39-3] ^1.00 JDH10.0176 1001 ug/L EPA 6010D 11/15/16 11:28Beryllium [7440-41-7] ^0.100 JDH1.002.24 11 ug/L EPA 6010D 11/15/16 11:28Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11 ug/L EPA 6010D 11/15/16 11:28Chromium [7440-47-3] ^1.40 JDH10.020.0 101 ug/L EPA 6010D 11/15/16 11:28Cobalt [7440-48-4] ^1.10 JDH10.012.0 101 ug/L EPA 6010D 11/15/16 11:28Copper [7440-50-8] ^1.60 JDH10.06.13 J 101 ug/L EPA 6010D 11/15/16 11:28Lead [7439-92-1] ^3.10 JDH10.014.0 101 ug/L EPA 6010D 11/15/16 11:28Nickel [7440-02-0] ^2.20 JDH10.015.2 J 501 ug/L EPA 6020B 11/16/16 11:43Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101 ug/L EPA 6010D 11/15/16 11:28Silver [7440-22-4] ^1.90 JDH10.01.90 U 101 ug/L EPA 6020B 11/16/16 13:12Thallium [7440-28-0] ^0.550 VLO5.000.709 JD 5.55 ug/L EPA 6010D 11/15/16 11:28Tin [7440-31-5] ^2.40 JDH10.02.40 U 1001 ug/L EPA 6010D 11/15/16 11:28Vanadium [7440-62-2] ^1.40 JDH10.033.3 251 ug/L EPA 6010D 11/15/16 11:28Zinc [7440-66-6] ^4.40 JDH10.051.3 101 Page 14 of 71 Page 14 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 9014 11/11/16 08:35Cyanide (total) [57-12-5] ^4.9 JLJ104.9 U 101 ug/L SM 4500S2 D-2000 11/10/16 18:00Sulfide [18496-25-8] ^10 JOC10010U 10001 Page 15 of 71 Page 15 of 72 www.encolabs.com 9809-GMW1Description:Lab Sample ID:CZ15795-01 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Chlorinated Herbicides by GC ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8151A 11/14/16 10:262,4,5-T [93-76-5] ^0.28 JJB0.500.28 U 21 ug/L EPA 8151A 11/14/16 10:262,4,5-TP (Silvex) [93-72-1] ^0.44 JJB0.500.44 U 21 ug/L EPA 8151A 11/14/16 10:262,4-D [94-75-7] ^0.27 JJB0.500.27 U 21 ug/L EPA 8151A 11/14/16 10:26Dinoseb [88-85-7] ^0.32 JJB0.500.32 U 1 ug/L EPA 8151A 11/14/16 10:26Pentachlorophenol [87-86-5] ^0.19 JJB0.500.19 U 251 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4-DCAA 37-13474 %JJBEPA 8151A 11/14/16 10:266K100211.5 2.00 1 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 16 of 71 Page 16 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 21:481,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MRK1.00.17 U 51 ug/L EPA 8260B 11/07/16 21:481,1,1-Trichloroethane [71-55-6] ^0.12 MRK1.00.12 U 11 ug/L EPA 8260B 11/07/16 21:481,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MRK1.00.28 U 31 ug/L EPA 8260B 11/07/16 21:481,1,2-Trichloroethane [79-00-5] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 21:481,1-Dichloroethane [75-34-3] ^0.13 MRK1.00.13 U 51 ug/L EPA 8260B 11/07/16 21:481,1-Dichloroethene [75-35-4] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 21:481,1-Dichloropropene [563-58-6] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:481,2,3-Trichloropropane [96-18-4] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 21:481,2,4-Trichlorobenzene [120-82-1] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 21:481,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MRK1.00.48 U 131 ug/L EPA 8260B 11/07/16 21:481,2-Dibromoethane [106-93-4] ^0.66 MRK1.00.66 U 11 ug/L EPA 8260B 11/07/16 21:481,2-Dichlorobenzene [95-50-1] ^0.19 MRK1.00.19 U 51 ug/L EPA 8260B 11/07/16 21:481,2-Dichloroethane [107-06-2] ^0.21 MRK1.00.21 U 11 ug/L EPA 8260B 11/07/16 21:481,2-Dichloropropane [78-87-5] ^0.10 MRK1.00.10 U 11 ug/L EPA 8260B 11/07/16 21:481,3-Dichlorobenzene [541-73-1] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:481,3-Dichloropropane [142-28-9] ^0.16 MRK1.00.16 U 11 ug/L EPA 8260B 11/07/16 21:481,4-Dichlorobenzene [106-46-7] ^0.19 MRK1.00.19 U 11 ug/L EPA 8260B 11/07/16 21:482,2-Dichloropropane [594-20-7] ^0.28 MRK1.00.28 U 151 ug/L EPA 8260B 11/07/16 21:482-Butanone [78-93-3] ^1.3 MRK5.01.3 U 1001 ug/L EPA 8260B 11/07/16 21:482-Hexanone [591-78-6] ^0.88 MRK5.00.88 U 501 ug/L EPA 8260B 11/07/16 21:483-Chloropropene [107-05-1] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 21:484-Methyl-2-pentanone [108-10-1] ^1.1 MRK5.01.1 U 1001 ug/L EPA 8260B 11/07/16 21:48Acetone [67-64-1] ^10 MRK2010U 1001 ug/L EPA 8260B 11/07/16 21:48Acetonitrile [75-05-8] ^5.0 MRK1031JB O-01551 ug/L EPA 8260B 11/07/16 21:48Acrolein [107-02-8] ^4.0 MRK104.0 U 531 ug/L EPA 8260B 11/07/16 21:48Acrylonitrile [107-13-1] ^3.5 MRK103.5 U 2001 ug/L EPA 8260B 11/07/16 21:48Benzene [71-43-2] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:48Bromochloromethane [74-97-5] ^0.48 MRK1.00.48 U 31 ug/L EPA 8260B 11/07/16 21:48Bromodichloromethane [75-27-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:48Bromoform [75-25-2] ^0.22 MRK1.00.22 U 31 ug/L EPA 8260B 11/07/16 21:48Bromomethane [74-83-9] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 21:48Carbon disulfide [75-15-0] ^1.5 MRK5.01.5 U 1001 ug/L EPA 8260B 11/07/16 21:48Carbon tetrachloride [56-23-5] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:48Chlorobenzene [108-90-7] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 21:48Chloroethane [75-00-3] ^0.23 MRK1.00.23 U 101 ug/L EPA 8260B 11/07/16 21:48Chloroform [67-66-3] ^0.18 MRK1.00.18 U 51 ug/L EPA 8260B 11/07/16 21:48Chloromethane [74-87-3] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 21:48Chloroprene [126-99-8] ^0.64 MRK1.00.64 U 201 ug/L EPA 8260B 11/07/16 21:48cis-1,2-Dichloroethene [156-59-2] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 21:48cis-1,3-Dichloropropene [10061-01-5] ^0.20 MRK1.00.20 U 11 ug/L EPA 8260B 11/07/16 21:48Dibromochloromethane [124-48-1] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 21:48Dibromomethane [74-95-3] ^0.27 MRK1.00.27 U 101 ug/L EPA 8260B 11/07/16 21:48Dichlorodifluoromethane [75-71-8] ^0.20 MRK1.00.20 U 51 ug/L EPA 8260B 11/07/16 21:48Ethyl Methacrylate [97-63-2] ^0.38 MRK1.00.38 U 101 ug/L EPA 8260B 11/07/16 21:48Ethylbenzene [100-41-4] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 21:48Hexachlorobutadiene [87-68-3] ^0.22 MRK1.00.22 U 101 ug/L EPA 8260B 11/07/16 21:48Iodomethane [74-88-4] ^1.7 MRK5.01.7 U 101 ug/L EPA 8260B 11/07/16 21:48Isobutyl alcohol [78-83-1] ^11 MRK5011U 1001 ug/L EPA 8260B 11/07/16 21:48m,p-Xylenes [108-38-3/106-42-3] ^0.17 MRK2.00.17 U NE1 ug/L EPA 8260B 11/07/16 21:48Methacrylonitrile [126-98-7] ^4.9 MRK104.9 U 1001 ug/L EPA 8260B 11/07/16 21:48Methyl Methacrylate [80-62-6] ^0.51 MRK1.00.51 U 301 Page 17 of 71 Page 17 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 21:48Methylene chloride [75-09-2] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 21:48Naphthalene [91-20-3] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 21:48o-Xylene [95-47-6] ^0.065 MRK1.00.065 U NE1 ug/L EPA 8260B 11/07/16 21:48Propionitrile [107-12-0] ^5.0 MRK105.0 U 1501 ug/L EPA 8260B 11/07/16 21:48Styrene [100-42-5] ^0.11 MRK1.00.11 U 11 ug/L EPA 8260B 11/07/16 21:48Tetrachloroethene [127-18-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 21:48Tetrahydrofuran [109-99-9] ^0.80 MRK1.02.7 1 ug/L EPA 8260B 11/07/16 21:48Toluene [108-88-3] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 21:48trans-1,2-Dichloroethene [156-60-5] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 21:48trans-1,3-Dichloropropene [10061-02-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:48trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MRK1.00.70 U 1001 ug/L EPA 8260B 11/07/16 21:48Trichloroethene [79-01-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 21:48Trichlorofluoromethane [75-69-4] ^0.24 MRK1.00.24 U 11 ug/L EPA 8260B 11/07/16 21:48Vinyl acetate [108-05-4] ^0.95 MRK5.00.95 U 501 ug/L EPA 8260B 11/07/16 21:48Vinyl chloride [75-01-4] ^0.32 MRK1.00.32 U 11 ug/L EPA 8260B 11/07/16 21:48Xylenes (Total) [1330-20-7] ^0.45 MRK3.00.45 U 51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 4-Bromofluorobenzene 53-13692 %MRKEPA 8260B 11/07/16 21:486K070044650.0 1 Dibromofluoromethane 67-129102 %MRKEPA 8260B 11/07/16 21:486K070045150.0 1 Toluene-d8 59-13496 %MRKEPA 8260B 11/07/16 21:486K070044850.0 1 Page 18 of 71 Page 18 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:111,2,4,5-Tetrachlorobenzene [95-94-3] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:111,3,5-Trinitrobenzene [99-35-4] ^3.0 DFM103.0 U 101 ug/L EPA 8270D 11/21/16 17:111,3-Dinitrobenzene [99-65-0] ^1.9 DFM101.9 U 201 ug/L EPA 8270D 11/21/16 17:111,4-Naphthoquinone [130-15-4] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 17:111,4-Phenylenediamine [106-50-3] ^4.0 DFM104.0 U QV-02101 ug/L EPA 8270D 11/21/16 17:111-Naphthylamine [134-32-7] ^1.9 DFM101.9 U QV-02101 ug/L EPA 8270D 11/21/16 17:112,3,4,6-Tetrachlorophenol [58-90-2] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:112,4,5-Trichlorophenol [95-95-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:112,4,6-Trichlorophenol [88-06-2] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:112,4-Dichlorophenol [120-83-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:112,4-Dimethylphenol [105-67-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:112,4-Dinitrophenol [51-28-5] ^2.6 DFM102.6 U 501 ug/L EPA 8270D 11/21/16 17:112,4-Dinitrotoluene [121-14-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 17:112,6-Dichlorophenol [87-65-0] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:112,6-Dinitrotoluene [606-20-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:112-Acetylaminofluorene [53-96-3] ^2.5 DFM102.5 U 201 ug/L EPA 8270D 11/21/16 17:112-Chloronaphthalene [91-58-7] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:112-Chlorophenol [95-57-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:112-Methyl-4,6-dinitrophenol [534-52-1] ^2.9 DFM102.9 U 501 ug/L EPA 8270D 11/21/16 17:112-Methylnaphthalene [91-57-6] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:112-Methylphenol [95-48-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:112-Naphthylamine [91-59-8] ^3.0 DFM103.0 U QV-02101 ug/L EPA 8270D 11/21/16 17:112-Nitroaniline [88-74-4] ^1.5 DFM101.5 U 501 ug/L EPA 8270D 11/21/16 17:112-Nitrophenol [88-75-5] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:113 & 4-Methylphenol [108-39-4/106-44-5] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:113,3'-Dichlorobenzidine [91-94-1] ^3.3 DFM103.3 U 201 ug/L EPA 8270D 11/21/16 17:113,3'-Dimethylbenzidine [119-93-7] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 17:113-Methylcholanthrene [56-49-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:113-Nitroaniline [99-09-2] ^2.1 DFM102.1 U 501 ug/L EPA 8270D 11/21/16 17:114-Aminobiphenyl [92-67-1] ^2.1 DFM102.1 U QV-02201 ug/L EPA 8270D 11/21/16 17:114-Bromophenyl-phenylether [101-55-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:114-Chloro-3-methylphenol [59-50-7] ^1.5 DFM101.5 U 201 ug/L EPA 8270D 11/21/16 17:114-Chloroaniline [106-47-8] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 17:114-Chlorophenyl-phenylether [7005-72-3] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:114-Nitroaniline [100-01-6] ^3.2 DFM103.2 U 201 ug/L EPA 8270D 11/21/16 17:114-Nitrophenol [100-02-7] ^2.0 DFM102.0 U 501 ug/L EPA 8270D 11/21/16 17:115-Nitro-o-toluidine [99-55-8] ^3.2 DFM103.2 U 101 ug/L EPA 8270D 11/21/16 17:117,12-Dimethylbenz(a)anthracene [57-97-6] ^ 1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:11Acenaphthene [83-32-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Acenaphthylene [208-96-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11Acetophenone [98-86-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Anthracene [120-12-7] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:11Benzo(a)anthracene [56-55-3] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Benzo(a)pyrene [50-32-8] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Benzo(b)fluoranthene [205-99-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Benzo(g,h,i)perylene [191-24-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 17:11Benzo(k)fluoranthene [207-08-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Benzyl alcohol [100-51-6] ^1.4 DFM101.4 U 201 ug/L EPA 8270D 11/21/16 17:11Bis(2-chloroethoxy)methane [111-91-1] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Bis(2-chloroethyl)ether [111-44-4] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11Bis(2-chloroisopropyl)ether [108-60-1] ^1.3 DFM101.3 U 101 Page 19 of 71 Page 19 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:11Bis(2-ethylhexyl)phthalate [117-81-7] ^1.7 DFM5.01.7 U 151 ug/L EPA 8270D 11/21/16 17:11Butylbenzylphthalate [85-68-7] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:11Chlorobenzilate [510-15-6] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Chrysene [218-01-9] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:11Diallate [2303-16-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Dibenzo(a,h)anthracene [53-70-3] ^2.3 DFM102.3 U 101 ug/L EPA 8270D 11/21/16 17:11Dibenzofuran [132-64-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Diethylphthalate [84-66-2] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:11Dimethoate [60-51-5] ^2.3 DFM102.3 U 201 ug/L EPA 8270D 11/21/16 17:11Dimethylphthalate [131-11-3] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Di-n-butylphthalate [84-74-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:11Di-n-octylphthalate [117-84-0] ^3.1 DFM103.1 U 101 ug/L EPA 8270D 11/21/16 17:11Disulfoton [298-04-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:11Ethyl methanesulfonate [62-50-0] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 17:11Famphur [52-85-7] ^2.7 DFM102.7 U QV-01201 ug/L EPA 8270D 11/21/16 17:11Fluoranthene [206-44-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:11Fluorene [86-73-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:11Hexachlorobenzene [118-74-1] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Hexachlorobutadiene [87-68-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11Hexachlorocyclopentadiene [77-47-4] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Hexachloroethane [67-72-1] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:11Hexachloropropene [1888-71-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:11Indeno(1,2,3-cd)pyrene [193-39-5] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 17:11Isodrin [465-73-6] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 17:11Isophorone [78-59-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Isosafrole [120-58-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Kepone [143-50-0] ^7.2 DFM207.2 U QV-01201 ug/L EPA 8270D 11/21/16 17:11Methapyrilene [91-80-5] ^3.5 DFM103.5 U 1001 ug/L EPA 8270D 11/21/16 17:11Methyl Methanesulfonate [66-27-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Methyl parathion [298-00-0] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 17:11Nitrobenzene [98-95-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11N-Nitrosodiethylamine [55-18-5] ^1.3 DFM101.3 U 201 ug/L EPA 8270D 11/21/16 17:11N-Nitrosodimethylamine [62-75-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11N-Nitrosodi-n-butylamine [924-16-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11N-Nitroso-di-n-propylamine [621-64-7] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:11N-nitrosodiphenylamine/Diphenylamine [86-30-6/122-39-4] ^ 2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:11N-Nitrosomethylethylamine [10595-95-6] ^1.9 DFM101.9 U 101 ug/L EPA 8270D 11/21/16 17:11N-Nitrosopiperidine [100-75-4] ^1.1 DFM101.1 U 201 ug/L EPA 8270D 11/21/16 17:11N-Nitrosopyrrolidine [930-55-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11O,O,O-Triethyl phosphorothioate [126-68-1] ^ 1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11o-Toluidine [95-53-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:11Parathion [56-38-2] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:11p-Dimethylaminoazobenzene [60-11-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Pentachlorobenzene [608-93-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:11Pentachloronitrobenzene [82-68-8] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 17:11Phenacetin [62-44-2] ^2.7 DFM102.7 U 201 ug/L EPA 8270D 11/21/16 17:11Phenanthrene [85-01-8] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Phenol [108-95-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:11Phorate [298-02-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:11Pronamide [23950-58-5] ^1.4 DFM101.4 U 101 Page 20 of 71 Page 20 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:11Pyrene [129-00-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:11Safrole [94-59-7] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:11Thionazin [297-97-2] ^2.3 DFM102.3 U 201 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,6-Tribromophenol 10-17993 %DFMEPA 8270D 11/21/16 17:116K0800293100 1 2-Fluorobiphenyl 10-14986 %DFMEPA 8270D 11/21/16 17:116K080024350.0 1 2-Fluorophenol 10-11070 %DFMEPA 8270D 11/21/16 17:116K0800270100 1 Nitrobenzene-d5 10-14981 %DFMEPA 8270D 11/21/16 17:116K080024150.0 1 Phenol-d5 10-8864 %DFMEPA 8270D 11/21/16 17:116K0800264100 1 Terphenyl-d14 10-18897 %DFMEPA 8270D 11/21/16 17:116K080024850.0 1 Page 21 of 71 Page 21 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Organochlorine Pesticides by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8081B 11/15/16 15:054,4'-DDD [72-54-8] ^0.044 MWC0.0500.044 U 0.11 ug/L EPA 8081B 11/15/16 15:054,4'-DDE [72-55-9] ^0.048 MWC0.0500.048 U 0.11 ug/L EPA 8081B 11/15/16 15:054,4'-DDT [50-29-3] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:05Aldrin [309-00-2] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:05alpha-BHC [319-84-6] ^0.036 MWC0.0500.036 U 0.051 ug/L EPA 8081B 11/15/16 15:05beta-BHC [319-85-7] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:05Chlordane (tech) [12789-03-6] ^0.37 MWC0.500.37 U 0.51 ug/L EPA 8081B 11/15/16 15:05Chlordane-alpha [5103-71-9] ^0.048 MWC0.0500.048 U NE1 ug/L EPA 8081B 11/15/16 15:05Chlordane-gamma [5566-34-7] ^0.042 MWC0.0500.042 U NE1 ug/L EPA 8081B 11/15/16 15:05delta-BHC [319-86-8] ^0.048 MWC0.0500.048 U 0.051 ug/L EPA 8081B 11/15/16 15:05Dieldrin [60-57-1] ^0.045 MWC0.0500.045 U 0.0751 ug/L EPA 8081B 11/15/16 15:05Endosulfan I [959-98-8] ^0.045 MWC0.0500.045 U 0.11 ug/L EPA 8081B 11/15/16 15:05Endosulfan II [33213-65-9] ^0.038 MWC0.0500.038 U 0.11 ug/L EPA 8081B 11/15/16 15:05Endosulfan sulfate [1031-07-8] ^0.032 MWC0.0500.032 U 0.11 ug/L EPA 8081B 11/15/16 15:05Endrin [72-20-8] ^0.041 MWC0.0500.041 U 0.11 ug/L EPA 8081B 11/15/16 15:05Endrin aldehyde [7421-93-4] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:05gamma-BHC [58-89-9] ^0.034 MWC0.0500.034 U 0.051 ug/L EPA 8081B 11/15/16 15:05Heptachlor [76-44-8] ^0.047 MWC0.0500.047 U 0.051 ug/L EPA 8081B 11/15/16 15:05Heptachlor epoxide [1024-57-3] ^0.037 MWC0.0500.037 U 0.0751 ug/L EPA 8081B 11/15/16 15:05Methoxychlor [72-43-5] ^0.048 MWC0.0500.048 U 11 ug/L EPA 8081B 11/15/16 15:05Toxaphene [8001-35-2] ^0.28 MWC0.500.28 U 1.51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 44-13484 %MWCEPA 8081B 11/15/16 15:056K090010.84 1.00 1 Decachlorobiphenyl 37-14949 %MWCEPA 8081B 11/15/16 15:056K090010.49 1.00 1 Page 22 of 71 Page 22 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Polychlorinated Biphenyls by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8082A 11/16/16 16:09PCB-1016/1242 [12674-11-2/53469-21-9] ^0.48 MWC0.500.48 U 21 ug/L EPA 8082A 11/16/16 16:09PCB-1221 [11104-28-2] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:09PCB-1232 [11141-16-5] ^0.50 MWC0.500.50 U NE1 ug/L EPA 8082A 11/16/16 16:09PCB-1248 [12672-29-6] ^0.30 MWC0.500.30 U NE1 ug/L EPA 8082A 11/16/16 16:09PCB-1254 [11097-69-1] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:09PCB-1260 [11096-82-5] ^0.45 MWC0.500.45 U NE1 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 45-15174 %MWCEPA 8082A 11/16/16 16:096K090020.74 1.00 1 Decachlorobiphenyl 42-15957 %MWCEPA 8082A 11/16/16 16:096K090020.57 1.00 1 Page 23 of 71 Page 23 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 7470A 11/17/16 13:06Mercury [7439-97-6] ^0.170 JMV0.2000.170 U 0.21 Page 24 of 71 Page 24 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 6020B 11/16/16 11:47Antimony [7440-36-0] ^0.220 VLO2.000.220 U 61 ug/L EPA 6010D 11/15/16 11:31Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101 ug/L EPA 6010D 11/15/16 11:31Barium [7440-39-3] ^1.00 JDH10.084.7 J 1001 ug/L EPA 6010D 11/15/16 11:31Beryllium [7440-41-7] ^0.100 JDH1.000.317 J 11 ug/L EPA 6010D 11/15/16 11:31Cadmium [7440-43-9] ^0.360 JDH1.001.65 11 ug/L EPA 6010D 11/15/16 11:31Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101 ug/L EPA 6010D 11/15/16 11:31Cobalt [7440-48-4] ^1.10 JDH10.079.9 101 ug/L EPA 6010D 11/15/16 11:31Copper [7440-50-8] ^1.60 JDH10.01.62 J 101 ug/L EPA 6010D 11/15/16 11:31Lead [7439-92-1] ^3.10 JDH10.03.10 U 101 ug/L EPA 6010D 11/15/16 11:31Nickel [7440-02-0] ^2.20 JDH10.017.2 J 501 ug/L EPA 6020B 11/16/16 11:47Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101 ug/L EPA 6010D 11/15/16 11:31Silver [7440-22-4] ^1.90 JDH10.01.90 U 101 ug/L EPA 6020B 11/16/16 11:47Thallium [7440-28-0] ^0.110 VLO1.000.237 J 5.51 ug/L EPA 6010D 11/15/16 11:31Tin [7440-31-5] ^2.40 JDH10.02.40 U 1001 ug/L EPA 6010D 11/15/16 11:31Vanadium [7440-62-2] ^1.40 JDH10.01.40 U 251 ug/L EPA 6010D 11/15/16 11:31Zinc [7440-66-6] ^4.40 JDH10.046.2 101 Page 25 of 71 Page 25 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 9014 11/11/16 08:39Cyanide (total) [57-12-5] ^4.9 JLJ104.9 U 101 ug/L SM 4500S2 D-2000 11/10/16 18:00Sulfide [18496-25-8] ^10 JOC10010U 10001 Page 26 of 71 Page 26 of 72 www.encolabs.com 9809-GMW2Description:Lab Sample ID:CZ15795-02 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:50 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Chlorinated Herbicides by GC ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8151A 11/14/16 10:512,4,5-T [93-76-5] ^0.28 JJB0.500.28 U 21 ug/L EPA 8151A 11/14/16 10:512,4,5-TP (Silvex) [93-72-1] ^0.44 JJB0.500.44 U 21 ug/L EPA 8151A 11/14/16 10:512,4-D [94-75-7] ^0.27 JJB0.500.27 U 21 ug/L EPA 8151A 11/14/16 10:51Dinoseb [88-85-7] ^0.32 JJB0.500.32 U 1 ug/L EPA 8151A 11/14/16 10:51Pentachlorophenol [87-86-5] ^0.19 JJB0.500.19 U 251 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4-DCAA 37-13476 %JJBEPA 8151A 11/14/16 10:516K100211.5 1.98 1 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 27 of 71 Page 27 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/05/16 07:071,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MRK1.00.17 U 51 ug/L EPA 8260B 11/05/16 07:071,1,1-Trichloroethane [71-55-6] ^0.12 MRK1.00.12 U 11 ug/L EPA 8260B 11/05/16 07:071,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MRK1.00.28 U 31 ug/L EPA 8260B 11/05/16 07:071,1,2-Trichloroethane [79-00-5] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/05/16 07:071,1-Dichloroethane [75-34-3] ^0.13 MRK1.00.13 U 51 ug/L EPA 8260B 11/05/16 07:071,1-Dichloroethene [75-35-4] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/05/16 07:071,1-Dichloropropene [563-58-6] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:071,2,3-Trichloropropane [96-18-4] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/05/16 07:071,2,4-Trichlorobenzene [120-82-1] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/05/16 07:071,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MRK1.00.48 U 131 ug/L EPA 8260B 11/05/16 07:071,2-Dibromoethane [106-93-4] ^0.66 MRK1.00.66 U 11 ug/L EPA 8260B 11/05/16 07:071,2-Dichlorobenzene [95-50-1] ^0.19 MRK1.00.19 U 51 ug/L EPA 8260B 11/05/16 07:071,2-Dichloroethane [107-06-2] ^0.21 MRK1.00.21 U 11 ug/L EPA 8260B 11/05/16 07:071,2-Dichloropropane [78-87-5] ^0.10 MRK1.01.4 11 ug/L EPA 8260B 11/05/16 07:071,3-Dichlorobenzene [541-73-1] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:071,3-Dichloropropane [142-28-9] ^0.16 MRK1.00.16 U 11 ug/L EPA 8260B 11/05/16 07:071,4-Dichlorobenzene [106-46-7] ^0.19 MRK1.00.19 U 11 ug/L EPA 8260B 11/05/16 07:072,2-Dichloropropane [594-20-7] ^0.28 MRK1.00.28 U 151 ug/L EPA 8260B 11/05/16 07:072-Butanone [78-93-3] ^1.3 MRK5.01.3 U 1001 ug/L EPA 8260B 11/05/16 07:072-Hexanone [591-78-6] ^0.88 MRK5.00.88 U 501 ug/L EPA 8260B 11/05/16 07:073-Chloropropene [107-05-1] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/05/16 07:074-Methyl-2-pentanone [108-10-1] ^1.1 MRK5.01.1 U 1001 ug/L EPA 8260B 11/05/16 07:07Acetone [67-64-1] ^10 MRK2010U 1001 ug/L EPA 8260B 11/05/16 07:07Acetonitrile [75-05-8] ^5.0 MRK105.0 U 551 ug/L EPA 8260B 11/05/16 07:07Acrolein [107-02-8] ^4.0 MRK104.0 U 531 ug/L EPA 8260B 11/05/16 07:07Acrylonitrile [107-13-1] ^3.5 MRK103.5 U 2001 ug/L EPA 8260B 11/05/16 07:07Benzene [71-43-2] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:07Bromochloromethane [74-97-5] ^0.48 MRK1.00.48 U 31 ug/L EPA 8260B 11/05/16 07:07Bromodichloromethane [75-27-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:07Bromoform [75-25-2] ^0.22 MRK1.00.22 U 31 ug/L EPA 8260B 11/05/16 07:07Bromomethane [74-83-9] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/05/16 07:07Carbon disulfide [75-15-0] ^1.5 MRK5.01.5 U 1001 ug/L EPA 8260B 11/05/16 07:07Carbon tetrachloride [56-23-5] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:07Chlorobenzene [108-90-7] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/05/16 07:07Chloroethane [75-00-3] ^0.23 MRK1.00.23 U 101 ug/L EPA 8260B 11/05/16 07:07Chloroform [67-66-3] ^0.18 MRK1.00.18 U 51 ug/L EPA 8260B 11/05/16 07:07Chloromethane [74-87-3] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/05/16 07:07Chloroprene [126-99-8] ^0.64 MRK1.00.64 U 201 ug/L EPA 8260B 11/05/16 07:07cis-1,2-Dichloroethene [156-59-2] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:07cis-1,3-Dichloropropene [10061-01-5] ^0.20 MRK1.00.20 U 11 ug/L EPA 8260B 11/05/16 07:07Dibromochloromethane [124-48-1] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/05/16 07:07Dibromomethane [74-95-3] ^0.27 MRK1.00.27 U 101 ug/L EPA 8260B 11/05/16 07:07Dichlorodifluoromethane [75-71-8] ^0.20 MRK1.00.20 U 51 ug/L EPA 8260B 11/05/16 07:07Ethyl Methacrylate [97-63-2] ^0.38 MRK1.00.38 U 101 ug/L EPA 8260B 11/05/16 07:07Ethylbenzene [100-41-4] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/05/16 07:07Hexachlorobutadiene [87-68-3] ^0.22 MRK1.00.22 U 101 ug/L EPA 8260B 11/05/16 07:07Iodomethane [74-88-4] ^1.7 MRK5.01.7 U 101 ug/L EPA 8260B 11/05/16 07:07Isobutyl alcohol [78-83-1] ^11 MRK5011U 1001 ug/L EPA 8260B 11/05/16 07:07m,p-Xylenes [108-38-3/106-42-3] ^0.17 MRK2.00.17 U NE1 ug/L EPA 8260B 11/05/16 07:07Methacrylonitrile [126-98-7] ^4.9 MRK104.9 U 1001 ug/L EPA 8260B 11/05/16 07:07Methyl Methacrylate [80-62-6] ^0.51 MRK1.00.51 U 301 Page 28 of 71 Page 28 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/05/16 07:07Methylene chloride [75-09-2] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/05/16 07:07Naphthalene [91-20-3] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/05/16 07:07o-Xylene [95-47-6] ^0.065 MRK1.00.065 U NE1 ug/L EPA 8260B 11/05/16 07:07Propionitrile [107-12-0] ^5.0 MRK105.0 U 1501 ug/L EPA 8260B 11/05/16 07:07Styrene [100-42-5] ^0.11 MRK1.00.11 U 11 ug/L EPA 8260B 11/05/16 07:07Tetrachloroethene [127-18-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:07Tetrahydrofuran [109-99-9] ^0.80 MRK1.00.80 U 1 ug/L EPA 8260B 11/05/16 07:07Toluene [108-88-3] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/05/16 07:07trans-1,2-Dichloroethene [156-60-5] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/05/16 07:07trans-1,3-Dichloropropene [10061-02-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:07trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MRK1.00.70 U 1001 ug/L EPA 8260B 11/05/16 07:07Trichloroethene [79-01-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:07Trichlorofluoromethane [75-69-4] ^0.24 MRK1.00.24 U 11 ug/L EPA 8260B 11/05/16 07:07Vinyl acetate [108-05-4] ^0.95 MRK5.00.95 U 501 ug/L EPA 8260B 11/05/16 07:07Vinyl chloride [75-01-4] ^0.32 MRK1.00.32 U 11 ug/L EPA 8260B 11/05/16 07:07Xylenes (Total) [1330-20-7] ^0.45 MRK3.00.45 U 51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 4-Bromofluorobenzene 53-13697 %MRKEPA 8260B 11/05/16 07:076K040324850.0 1 Dibromofluoromethane 67-12999 %MRKEPA 8260B 11/05/16 07:076K040324950.0 1 Toluene-d8 59-13498 %MRKEPA 8260B 11/05/16 07:076K040324950.0 1 Page 29 of 71 Page 29 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:431,2,4,5-Tetrachlorobenzene [95-94-3] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:431,3,5-Trinitrobenzene [99-35-4] ^3.0 DFM103.0 U 101 ug/L EPA 8270D 11/21/16 17:431,3-Dinitrobenzene [99-65-0] ^1.9 DFM101.9 U 201 ug/L EPA 8270D 11/21/16 17:431,4-Naphthoquinone [130-15-4] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 17:431,4-Phenylenediamine [106-50-3] ^4.0 DFM104.0 U QV-02101 ug/L EPA 8270D 11/21/16 17:431-Naphthylamine [134-32-7] ^1.9 DFM101.9 U QV-02101 ug/L EPA 8270D 11/21/16 17:432,3,4,6-Tetrachlorophenol [58-90-2] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:432,4,5-Trichlorophenol [95-95-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:432,4,6-Trichlorophenol [88-06-2] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:432,4-Dichlorophenol [120-83-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:432,4-Dimethylphenol [105-67-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:432,4-Dinitrophenol [51-28-5] ^2.6 DFM102.6 U 501 ug/L EPA 8270D 11/21/16 17:432,4-Dinitrotoluene [121-14-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 17:432,6-Dichlorophenol [87-65-0] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:432,6-Dinitrotoluene [606-20-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:432-Acetylaminofluorene [53-96-3] ^2.5 DFM102.5 U 201 ug/L EPA 8270D 11/21/16 17:432-Chloronaphthalene [91-58-7] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:432-Chlorophenol [95-57-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:432-Methyl-4,6-dinitrophenol [534-52-1] ^2.9 DFM102.9 U 501 ug/L EPA 8270D 11/21/16 17:432-Methylnaphthalene [91-57-6] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:432-Methylphenol [95-48-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:432-Naphthylamine [91-59-8] ^3.0 DFM103.0 U QV-02101 ug/L EPA 8270D 11/21/16 17:432-Nitroaniline [88-74-4] ^1.5 DFM101.5 U 501 ug/L EPA 8270D 11/21/16 17:432-Nitrophenol [88-75-5] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:433 & 4-Methylphenol [108-39-4/106-44-5] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:433,3'-Dichlorobenzidine [91-94-1] ^3.3 DFM103.3 U 201 ug/L EPA 8270D 11/21/16 17:433,3'-Dimethylbenzidine [119-93-7] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 17:433-Methylcholanthrene [56-49-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:433-Nitroaniline [99-09-2] ^2.1 DFM102.1 U 501 ug/L EPA 8270D 11/21/16 17:434-Aminobiphenyl [92-67-1] ^2.1 DFM102.1 U QV-02201 ug/L EPA 8270D 11/21/16 17:434-Bromophenyl-phenylether [101-55-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:434-Chloro-3-methylphenol [59-50-7] ^1.5 DFM101.5 U 201 ug/L EPA 8270D 11/21/16 17:434-Chloroaniline [106-47-8] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 17:434-Chlorophenyl-phenylether [7005-72-3] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:434-Nitroaniline [100-01-6] ^3.2 DFM103.2 U 201 ug/L EPA 8270D 11/21/16 17:434-Nitrophenol [100-02-7] ^2.0 DFM102.0 U 501 ug/L EPA 8270D 11/21/16 17:435-Nitro-o-toluidine [99-55-8] ^3.2 DFM103.2 U 101 ug/L EPA 8270D 11/21/16 17:437,12-Dimethylbenz(a)anthracene [57-97-6] ^ 1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:43Acenaphthene [83-32-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Acenaphthylene [208-96-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43Acetophenone [98-86-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Anthracene [120-12-7] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 17:43Benzo(a)anthracene [56-55-3] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Benzo(a)pyrene [50-32-8] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Benzo(b)fluoranthene [205-99-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Benzo(g,h,i)perylene [191-24-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 17:43Benzo(k)fluoranthene [207-08-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Benzyl alcohol [100-51-6] ^1.4 DFM101.4 U 201 ug/L EPA 8270D 11/21/16 17:43Bis(2-chloroethoxy)methane [111-91-1] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Bis(2-chloroethyl)ether [111-44-4] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43Bis(2-chloroisopropyl)ether [108-60-1] ^1.3 DFM101.3 U 101 Page 30 of 71 Page 30 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:43Bis(2-ethylhexyl)phthalate [117-81-7] ^1.7 DFM5.01.7 U 151 ug/L EPA 8270D 11/21/16 17:43Butylbenzylphthalate [85-68-7] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:43Chlorobenzilate [510-15-6] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Chrysene [218-01-9] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 17:43Diallate [2303-16-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Dibenzo(a,h)anthracene [53-70-3] ^2.3 DFM102.3 U 101 ug/L EPA 8270D 11/21/16 17:43Dibenzofuran [132-64-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Diethylphthalate [84-66-2] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:43Dimethoate [60-51-5] ^2.3 DFM102.3 U 201 ug/L EPA 8270D 11/21/16 17:43Dimethylphthalate [131-11-3] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Di-n-butylphthalate [84-74-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:43Di-n-octylphthalate [117-84-0] ^3.1 DFM103.1 U 101 ug/L EPA 8270D 11/21/16 17:43Disulfoton [298-04-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:43Ethyl methanesulfonate [62-50-0] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 17:43Famphur [52-85-7] ^2.7 DFM102.7 U QV-01201 ug/L EPA 8270D 11/21/16 17:43Fluoranthene [206-44-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:43Fluorene [86-73-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:43Hexachlorobenzene [118-74-1] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Hexachlorobutadiene [87-68-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43Hexachlorocyclopentadiene [77-47-4] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Hexachloroethane [67-72-1] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:43Hexachloropropene [1888-71-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:43Indeno(1,2,3-cd)pyrene [193-39-5] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 17:43Isodrin [465-73-6] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 17:43Isophorone [78-59-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Isosafrole [120-58-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Kepone [143-50-0] ^7.2 DFM207.2 U QV-01201 ug/L EPA 8270D 11/21/16 17:43Methapyrilene [91-80-5] ^3.5 DFM103.5 U 1001 ug/L EPA 8270D 11/21/16 17:43Methyl Methanesulfonate [66-27-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Methyl parathion [298-00-0] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 17:43Nitrobenzene [98-95-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43N-Nitrosodiethylamine [55-18-5] ^1.3 DFM101.3 U 201 ug/L EPA 8270D 11/21/16 17:43N-Nitrosodimethylamine [62-75-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43N-Nitrosodi-n-butylamine [924-16-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43N-Nitroso-di-n-propylamine [621-64-7] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 17:43N-nitrosodiphenylamine/Diphenylamine [86-30-6/122-39-4] ^ 2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:43N-Nitrosomethylethylamine [10595-95-6] ^1.9 DFM101.9 U 101 ug/L EPA 8270D 11/21/16 17:43N-Nitrosopiperidine [100-75-4] ^1.1 DFM101.1 U 201 ug/L EPA 8270D 11/21/16 17:43N-Nitrosopyrrolidine [930-55-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43O,O,O-Triethyl phosphorothioate [126-68-1] ^ 1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43o-Toluidine [95-53-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 17:43Parathion [56-38-2] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 17:43p-Dimethylaminoazobenzene [60-11-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Pentachlorobenzene [608-93-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 17:43Pentachloronitrobenzene [82-68-8] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 17:43Phenacetin [62-44-2] ^2.7 DFM102.7 U 201 ug/L EPA 8270D 11/21/16 17:43Phenanthrene [85-01-8] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Phenol [108-95-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 17:43Phorate [298-02-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 17:43Pronamide [23950-58-5] ^1.4 DFM101.4 U 101 Page 31 of 71 Page 31 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 17:43Pyrene [129-00-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 17:43Safrole [94-59-7] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 17:43Thionazin [297-97-2] ^2.3 DFM102.3 U 201 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,6-Tribromophenol 10-17982 %DFMEPA 8270D 11/21/16 17:436K0800282100 1 2-Fluorobiphenyl 10-14992 %DFMEPA 8270D 11/21/16 17:436K080024650.0 1 2-Fluorophenol 10-11067 %DFMEPA 8270D 11/21/16 17:436K0800267100 1 Nitrobenzene-d5 10-14980 %DFMEPA 8270D 11/21/16 17:436K080024050.0 1 Phenol-d5 10-8859 %DFMEPA 8270D 11/21/16 17:436K0800259100 1 Terphenyl-d14 10-188103 %DFMEPA 8270D 11/21/16 17:436K080025150.0 1 Page 32 of 71 Page 32 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Organochlorine Pesticides by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8081B 11/15/16 15:184,4'-DDD [72-54-8] ^0.044 MWC0.0500.044 U 0.11 ug/L EPA 8081B 11/15/16 15:184,4'-DDE [72-55-9] ^0.048 MWC0.0500.048 U 0.11 ug/L EPA 8081B 11/15/16 15:184,4'-DDT [50-29-3] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:18Aldrin [309-00-2] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:18alpha-BHC [319-84-6] ^0.036 MWC0.0500.036 U 0.051 ug/L EPA 8081B 11/15/16 15:18beta-BHC [319-85-7] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:18Chlordane (tech) [12789-03-6] ^0.37 MWC0.500.37 U 0.51 ug/L EPA 8081B 11/15/16 15:18Chlordane-alpha [5103-71-9] ^0.048 MWC0.0500.048 U NE1 ug/L EPA 8081B 11/15/16 15:18Chlordane-gamma [5566-34-7] ^0.042 MWC0.0500.042 U NE1 ug/L EPA 8081B 11/15/16 15:18delta-BHC [319-86-8] ^0.048 MWC0.0500.048 U 0.051 ug/L EPA 8081B 11/15/16 15:18Dieldrin [60-57-1] ^0.045 MWC0.0500.045 U 0.0751 ug/L EPA 8081B 11/15/16 15:18Endosulfan I [959-98-8] ^0.045 MWC0.0500.045 U 0.11 ug/L EPA 8081B 11/15/16 15:18Endosulfan II [33213-65-9] ^0.038 MWC0.0500.038 U 0.11 ug/L EPA 8081B 11/15/16 15:18Endosulfan sulfate [1031-07-8] ^0.032 MWC0.0500.032 U 0.11 ug/L EPA 8081B 11/15/16 15:18Endrin [72-20-8] ^0.041 MWC0.0500.041 U 0.11 ug/L EPA 8081B 11/15/16 15:18Endrin aldehyde [7421-93-4] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:18gamma-BHC [58-89-9] ^0.034 MWC0.0500.034 U 0.051 ug/L EPA 8081B 11/15/16 15:18Heptachlor [76-44-8] ^0.047 MWC0.0500.047 U 0.051 ug/L EPA 8081B 11/15/16 15:18Heptachlor epoxide [1024-57-3] ^0.037 MWC0.0500.037 U 0.0751 ug/L EPA 8081B 11/15/16 15:18Methoxychlor [72-43-5] ^0.048 MWC0.0500.048 U 11 ug/L EPA 8081B 11/15/16 15:18Toxaphene [8001-35-2] ^0.28 MWC0.500.28 U 1.51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 44-13492 %MWCEPA 8081B 11/15/16 15:186K090010.92 1.00 1 Decachlorobiphenyl 37-14963 %MWCEPA 8081B 11/15/16 15:186K090010.63 1.00 1 Page 33 of 71 Page 33 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Polychlorinated Biphenyls by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8082A 11/16/16 16:23PCB-1016/1242 [12674-11-2/53469-21-9] ^0.48 MWC0.500.48 U 21 ug/L EPA 8082A 11/16/16 16:23PCB-1221 [11104-28-2] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:23PCB-1232 [11141-16-5] ^0.50 MWC0.500.50 U NE1 ug/L EPA 8082A 11/16/16 16:23PCB-1248 [12672-29-6] ^0.30 MWC0.500.30 U NE1 ug/L EPA 8082A 11/16/16 16:23PCB-1254 [11097-69-1] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:23PCB-1260 [11096-82-5] ^0.45 MWC0.500.45 U NE1 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 45-15167 %MWCEPA 8082A 11/16/16 16:236K090020.67 1.00 1 Decachlorobiphenyl 42-15960 %MWCEPA 8082A 11/16/16 16:236K090020.60 1.00 1 Page 34 of 71 Page 34 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 7470A 11/17/16 13:28Mercury [7439-97-6] ^0.170 JMV0.2000.170 U 0.21 Page 35 of 71 Page 35 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 6020B 11/16/16 11:50Antimony [7440-36-0] ^0.220 VLO2.000.220 U 61 ug/L EPA 6010D 11/15/16 11:33Arsenic [7440-38-2] ^6.80 JDH10.08.03 J 101 ug/L EPA 6010D 11/15/16 11:33Barium [7440-39-3] ^1.00 JDH10.0170 1001 ug/L EPA 6010D 11/15/16 11:33Beryllium [7440-41-7] ^0.100 JDH1.002.69 11 ug/L EPA 6010D 11/15/16 11:33Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11 ug/L EPA 6010D 11/15/16 11:33Chromium [7440-47-3] ^1.40 JDH10.06.51 J 101 ug/L EPA 6010D 11/15/16 11:33Cobalt [7440-48-4] ^1.10 JDH10.018.3 101 ug/L EPA 6010D 11/15/16 11:33Copper [7440-50-8] ^1.60 JDH10.02.24 J 101 ug/L EPA 6010D 11/15/16 11:33Lead [7439-92-1] ^3.10 JDH10.07.30 J 101 ug/L EPA 6010D 11/15/16 11:33Nickel [7440-02-0] ^2.20 JDH10.024.2 J 501 ug/L EPA 6020B 11/16/16 11:50Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101 ug/L EPA 6010D 11/15/16 11:33Silver [7440-22-4] ^1.90 JDH10.01.90 U 101 ug/L EPA 6020B 11/16/16 11:50Thallium [7440-28-0] ^0.110 VLO1.000.168 J 5.51 ug/L EPA 6010D 11/15/16 11:33Tin [7440-31-5] ^2.40 JDH10.02.40 U 1001 ug/L EPA 6010D 11/15/16 11:33Vanadium [7440-62-2] ^1.40 JDH10.011.3 J 251 ug/L EPA 6010D 11/15/16 11:33Zinc [7440-66-6] ^4.40 JDH10.073.9 101 Page 36 of 71 Page 36 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 9014 11/11/16 08:41Cyanide (total) [57-12-5] ^4.9 JLJ104.9 U 101 ug/L SM 4500S2 D-2000 11/10/16 18:00Sulfide [18496-25-8] ^10 JOC10010U 10001 Page 37 of 71 Page 37 of 72 www.encolabs.com 9809-GMW3Description:Lab Sample ID:CZ15795-03 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:05 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Chlorinated Herbicides by GC ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8151A 11/14/16 11:172,4,5-T [93-76-5] ^0.28 JJB0.500.28 U 21 ug/L EPA 8151A 11/14/16 11:172,4,5-TP (Silvex) [93-72-1] ^0.44 JJB0.500.44 U 21 ug/L EPA 8151A 11/14/16 11:172,4-D [94-75-7] ^0.27 JJB0.500.27 U 21 ug/L EPA 8151A 11/14/16 11:17Dinoseb [88-85-7] ^0.32 JJB0.500.32 U 1 ug/L EPA 8151A 11/14/16 11:17Pentachlorophenol [87-86-5] ^0.19 JJB0.500.19 U 251 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4-DCAA 37-13486 %JJBEPA 8151A 11/14/16 11:176K100211.7 2.02 1 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 38 of 71 Page 38 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/05/16 07:361,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MRK1.00.17 U 51 ug/L EPA 8260B 11/05/16 07:361,1,1-Trichloroethane [71-55-6] ^0.12 MRK1.00.12 U 11 ug/L EPA 8260B 11/05/16 07:361,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MRK1.00.28 U 31 ug/L EPA 8260B 11/05/16 07:361,1,2-Trichloroethane [79-00-5] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/05/16 07:361,1-Dichloroethane [75-34-3] ^0.13 MRK1.00.13 U 51 ug/L EPA 8260B 11/05/16 07:361,1-Dichloroethene [75-35-4] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/05/16 07:361,1-Dichloropropene [563-58-6] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:361,2,3-Trichloropropane [96-18-4] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/05/16 07:361,2,4-Trichlorobenzene [120-82-1] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/05/16 07:361,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MRK1.00.48 U 131 ug/L EPA 8260B 11/05/16 07:361,2-Dibromoethane [106-93-4] ^0.66 MRK1.00.66 U 11 ug/L EPA 8260B 11/05/16 07:361,2-Dichlorobenzene [95-50-1] ^0.19 MRK1.00.19 U 51 ug/L EPA 8260B 11/05/16 07:361,2-Dichloroethane [107-06-2] ^0.21 MRK1.00.21 U 11 ug/L EPA 8260B 11/05/16 07:361,2-Dichloropropane [78-87-5] ^0.10 MRK1.00.10 U 11 ug/L EPA 8260B 11/05/16 07:361,3-Dichlorobenzene [541-73-1] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:361,3-Dichloropropane [142-28-9] ^0.16 MRK1.00.16 U 11 ug/L EPA 8260B 11/05/16 07:361,4-Dichlorobenzene [106-46-7] ^0.19 MRK1.00.19 U 11 ug/L EPA 8260B 11/05/16 07:362,2-Dichloropropane [594-20-7] ^0.28 MRK1.00.28 U 151 ug/L EPA 8260B 11/05/16 07:362-Butanone [78-93-3] ^1.3 MRK5.01.3 U 1001 ug/L EPA 8260B 11/05/16 07:362-Hexanone [591-78-6] ^0.88 MRK5.00.88 U 501 ug/L EPA 8260B 11/05/16 07:363-Chloropropene [107-05-1] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/05/16 07:364-Methyl-2-pentanone [108-10-1] ^1.1 MRK5.01.1 U 1001 ug/L EPA 8260B 11/05/16 07:36Acetone [67-64-1] ^10 MRK2010U 1001 ug/L EPA 8260B 11/05/16 07:36Acetonitrile [75-05-8] ^5.0 MRK105.0 U 551 ug/L EPA 8260B 11/05/16 07:36Acrolein [107-02-8] ^4.0 MRK104.0 U 531 ug/L EPA 8260B 11/05/16 07:36Acrylonitrile [107-13-1] ^3.5 MRK103.5 U 2001 ug/L EPA 8260B 11/05/16 07:36Benzene [71-43-2] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:36Bromochloromethane [74-97-5] ^0.48 MRK1.00.48 U 31 ug/L EPA 8260B 11/05/16 07:36Bromodichloromethane [75-27-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:36Bromoform [75-25-2] ^0.22 MRK1.00.22 U 31 ug/L EPA 8260B 11/05/16 07:36Bromomethane [74-83-9] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/05/16 07:36Carbon disulfide [75-15-0] ^1.5 MRK5.01.5 U 1001 ug/L EPA 8260B 11/05/16 07:36Carbon tetrachloride [56-23-5] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:36Chlorobenzene [108-90-7] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/05/16 07:36Chloroethane [75-00-3] ^0.23 MRK1.00.23 U 101 ug/L EPA 8260B 11/05/16 07:36Chloroform [67-66-3] ^0.18 MRK1.00.18 U 51 ug/L EPA 8260B 11/05/16 07:36Chloromethane [74-87-3] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/05/16 07:36Chloroprene [126-99-8] ^0.64 MRK1.00.64 U 201 ug/L EPA 8260B 11/05/16 07:36cis-1,2-Dichloroethene [156-59-2] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/05/16 07:36cis-1,3-Dichloropropene [10061-01-5] ^0.20 MRK1.00.20 U 11 ug/L EPA 8260B 11/05/16 07:36Dibromochloromethane [124-48-1] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/05/16 07:36Dibromomethane [74-95-3] ^0.27 MRK1.00.27 U 101 ug/L EPA 8260B 11/05/16 07:36Dichlorodifluoromethane [75-71-8] ^0.20 MRK1.00.20 U 51 ug/L EPA 8260B 11/05/16 07:36Ethyl Methacrylate [97-63-2] ^0.38 MRK1.00.38 U 101 ug/L EPA 8260B 11/05/16 07:36Ethylbenzene [100-41-4] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/05/16 07:36Hexachlorobutadiene [87-68-3] ^0.22 MRK1.00.22 U 101 ug/L EPA 8260B 11/05/16 07:36Iodomethane [74-88-4] ^1.7 MRK5.01.7 U 101 ug/L EPA 8260B 11/05/16 07:36Isobutyl alcohol [78-83-1] ^11 MRK5011U 1001 ug/L EPA 8260B 11/05/16 07:36m,p-Xylenes [108-38-3/106-42-3] ^0.17 MRK2.00.17 U NE1 ug/L EPA 8260B 11/05/16 07:36Methacrylonitrile [126-98-7] ^4.9 MRK104.9 U 1001 ug/L EPA 8260B 11/05/16 07:36Methyl Methacrylate [80-62-6] ^0.51 MRK1.00.51 U 301 Page 39 of 71 Page 39 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/05/16 07:36Methylene chloride [75-09-2] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/05/16 07:36Naphthalene [91-20-3] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/05/16 07:36o-Xylene [95-47-6] ^0.065 MRK1.00.065 U NE1 ug/L EPA 8260B 11/05/16 07:36Propionitrile [107-12-0] ^5.0 MRK105.0 U 1501 ug/L EPA 8260B 11/05/16 07:36Styrene [100-42-5] ^0.11 MRK1.00.11 U 11 ug/L EPA 8260B 11/05/16 07:36Tetrachloroethene [127-18-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/05/16 07:36Tetrahydrofuran [109-99-9] ^0.80 MRK1.00.80 U 1 ug/L EPA 8260B 11/05/16 07:36Toluene [108-88-3] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/05/16 07:36trans-1,2-Dichloroethene [156-60-5] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/05/16 07:36trans-1,3-Dichloropropene [10061-02-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:36trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MRK1.00.70 U 1001 ug/L EPA 8260B 11/05/16 07:36Trichloroethene [79-01-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/05/16 07:36Trichlorofluoromethane [75-69-4] ^0.24 MRK1.00.24 U 11 ug/L EPA 8260B 11/05/16 07:36Vinyl acetate [108-05-4] ^0.95 MRK5.00.95 U 501 ug/L EPA 8260B 11/05/16 07:36Vinyl chloride [75-01-4] ^0.32 MRK1.00.32 U 11 ug/L EPA 8260B 11/05/16 07:36Xylenes (Total) [1330-20-7] ^0.45 MRK3.00.45 U 51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 4-Bromofluorobenzene 53-13695 %MRKEPA 8260B 11/05/16 07:366K040324850.0 1 Dibromofluoromethane 67-129101 %MRKEPA 8260B 11/05/16 07:366K040325150.0 1 Toluene-d8 59-13498 %MRKEPA 8260B 11/05/16 07:366K040324950.0 1 Page 40 of 71 Page 40 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 18:161,2,4,5-Tetrachlorobenzene [95-94-3] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 18:161,3,5-Trinitrobenzene [99-35-4] ^3.0 DFM103.0 U 101 ug/L EPA 8270D 11/21/16 18:161,3-Dinitrobenzene [99-65-0] ^1.9 DFM101.9 U 201 ug/L EPA 8270D 11/21/16 18:161,4-Naphthoquinone [130-15-4] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 18:161,4-Phenylenediamine [106-50-3] ^4.0 DFM104.0 U QV-02101 ug/L EPA 8270D 11/21/16 18:161-Naphthylamine [134-32-7] ^1.9 DFM101.9 U QV-02101 ug/L EPA 8270D 11/21/16 18:162,3,4,6-Tetrachlorophenol [58-90-2] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 18:162,4,5-Trichlorophenol [95-95-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:162,4,6-Trichlorophenol [88-06-2] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:162,4-Dichlorophenol [120-83-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:162,4-Dimethylphenol [105-67-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:162,4-Dinitrophenol [51-28-5] ^2.6 DFM102.6 U 501 ug/L EPA 8270D 11/21/16 18:162,4-Dinitrotoluene [121-14-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 18:162,6-Dichlorophenol [87-65-0] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:162,6-Dinitrotoluene [606-20-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 18:162-Acetylaminofluorene [53-96-3] ^2.5 DFM102.5 U 201 ug/L EPA 8270D 11/21/16 18:162-Chloronaphthalene [91-58-7] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:162-Chlorophenol [95-57-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:162-Methyl-4,6-dinitrophenol [534-52-1] ^2.9 DFM102.9 U 501 ug/L EPA 8270D 11/21/16 18:162-Methylnaphthalene [91-57-6] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 18:162-Methylphenol [95-48-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:162-Naphthylamine [91-59-8] ^3.0 DFM103.0 U QV-02101 ug/L EPA 8270D 11/21/16 18:162-Nitroaniline [88-74-4] ^1.5 DFM101.5 U 501 ug/L EPA 8270D 11/21/16 18:162-Nitrophenol [88-75-5] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:163 & 4-Methylphenol [108-39-4/106-44-5] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 18:163,3'-Dichlorobenzidine [91-94-1] ^3.3 DFM103.3 U 201 ug/L EPA 8270D 11/21/16 18:163,3'-Dimethylbenzidine [119-93-7] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 18:163-Methylcholanthrene [56-49-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:163-Nitroaniline [99-09-2] ^2.1 DFM102.1 U 501 ug/L EPA 8270D 11/21/16 18:164-Aminobiphenyl [92-67-1] ^2.1 DFM102.1 U QV-02201 ug/L EPA 8270D 11/21/16 18:164-Bromophenyl-phenylether [101-55-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:164-Chloro-3-methylphenol [59-50-7] ^1.5 DFM101.5 U 201 ug/L EPA 8270D 11/21/16 18:164-Chloroaniline [106-47-8] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 18:164-Chlorophenyl-phenylether [7005-72-3] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 18:164-Nitroaniline [100-01-6] ^3.2 DFM103.2 U 201 ug/L EPA 8270D 11/21/16 18:164-Nitrophenol [100-02-7] ^2.0 DFM102.0 U 501 ug/L EPA 8270D 11/21/16 18:165-Nitro-o-toluidine [99-55-8] ^3.2 DFM103.2 U 101 ug/L EPA 8270D 11/21/16 18:167,12-Dimethylbenz(a)anthracene [57-97-6] ^ 1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:16Acenaphthene [83-32-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Acenaphthylene [208-96-8] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16Acetophenone [98-86-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Anthracene [120-12-7] ^1.6 DFM101.6 U 101 ug/L EPA 8270D 11/21/16 18:16Benzo(a)anthracene [56-55-3] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Benzo(a)pyrene [50-32-8] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Benzo(b)fluoranthene [205-99-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Benzo(g,h,i)perylene [191-24-2] ^2.4 DFM102.4 U 101 ug/L EPA 8270D 11/21/16 18:16Benzo(k)fluoranthene [207-08-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Benzyl alcohol [100-51-6] ^1.4 DFM101.4 U 201 ug/L EPA 8270D 11/21/16 18:16Bis(2-chloroethoxy)methane [111-91-1] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Bis(2-chloroethyl)ether [111-44-4] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16Bis(2-chloroisopropyl)ether [108-60-1] ^1.3 DFM101.3 U 101 Page 41 of 71 Page 41 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 18:16Bis(2-ethylhexyl)phthalate [117-81-7] ^1.7 DFM5.01.7 U 151 ug/L EPA 8270D 11/21/16 18:16Butylbenzylphthalate [85-68-7] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 18:16Chlorobenzilate [510-15-6] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Chrysene [218-01-9] ^2.0 DFM102.0 U 101 ug/L EPA 8270D 11/21/16 18:16Diallate [2303-16-4] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Dibenzo(a,h)anthracene [53-70-3] ^2.3 DFM102.3 U 101 ug/L EPA 8270D 11/21/16 18:16Dibenzofuran [132-64-9] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Diethylphthalate [84-66-2] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 18:16Dimethoate [60-51-5] ^2.3 DFM102.3 U 201 ug/L EPA 8270D 11/21/16 18:16Dimethylphthalate [131-11-3] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Di-n-butylphthalate [84-74-2] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 18:16Di-n-octylphthalate [117-84-0] ^3.1 DFM103.1 U 101 ug/L EPA 8270D 11/21/16 18:16Disulfoton [298-04-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:16Ethyl methanesulfonate [62-50-0] ^1.2 DFM101.2 U 201 ug/L EPA 8270D 11/21/16 18:16Famphur [52-85-7] ^2.7 DFM102.7 U QV-01201 ug/L EPA 8270D 11/21/16 18:16Fluoranthene [206-44-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 18:16Fluorene [86-73-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 18:16Hexachlorobenzene [118-74-1] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Hexachlorobutadiene [87-68-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16Hexachlorocyclopentadiene [77-47-4] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Hexachloroethane [67-72-1] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:16Hexachloropropene [1888-71-7] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 18:16Indeno(1,2,3-cd)pyrene [193-39-5] ^2.2 DFM102.2 U 101 ug/L EPA 8270D 11/21/16 18:16Isodrin [465-73-6] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 18:16Isophorone [78-59-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Isosafrole [120-58-1] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Kepone [143-50-0] ^7.2 DFM207.2 U QV-01201 ug/L EPA 8270D 11/21/16 18:16Methapyrilene [91-80-5] ^3.5 DFM103.5 U 1001 ug/L EPA 8270D 11/21/16 18:16Methyl Methanesulfonate [66-27-3] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Methyl parathion [298-00-0] ^2.5 DFM102.5 U 101 ug/L EPA 8270D 11/21/16 18:16Nitrobenzene [98-95-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16N-Nitrosodiethylamine [55-18-5] ^1.3 DFM101.3 U 201 ug/L EPA 8270D 11/21/16 18:16N-Nitrosodimethylamine [62-75-9] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16N-Nitrosodi-n-butylamine [924-16-3] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16N-Nitroso-di-n-propylamine [621-64-7] ^1.5 DFM101.5 U 101 ug/L EPA 8270D 11/21/16 18:16N-nitrosodiphenylamine/Diphenylamine [86-30-6/122-39-4] ^ 2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 18:16N-Nitrosomethylethylamine [10595-95-6] ^1.9 DFM101.9 U 101 ug/L EPA 8270D 11/21/16 18:16N-Nitrosopiperidine [100-75-4] ^1.1 DFM101.1 U 201 ug/L EPA 8270D 11/21/16 18:16N-Nitrosopyrrolidine [930-55-2] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16O,O,O-Triethyl phosphorothioate [126-68-1] ^ 1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16o-Toluidine [95-53-4] ^1.1 DFM101.1 U 101 ug/L EPA 8270D 11/21/16 18:16Parathion [56-38-2] ^1.7 DFM101.7 U 101 ug/L EPA 8270D 11/21/16 18:16p-Dimethylaminoazobenzene [60-11-7] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Pentachlorobenzene [608-93-5] ^1.3 DFM101.3 U 101 ug/L EPA 8270D 11/21/16 18:16Pentachloronitrobenzene [82-68-8] ^1.0 DFM101.0 U 201 ug/L EPA 8270D 11/21/16 18:16Phenacetin [62-44-2] ^2.7 DFM102.7 U 201 ug/L EPA 8270D 11/21/16 18:16Phenanthrene [85-01-8] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Phenol [108-95-2] ^1.4 DFM101.4 U 101 ug/L EPA 8270D 11/21/16 18:16Phorate [298-02-2] ^1.0 DFM101.0 U 101 ug/L EPA 8270D 11/21/16 18:16Pronamide [23950-58-5] ^1.4 DFM101.4 U 101 Page 42 of 71 Page 42 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Semivolatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8270D 11/21/16 18:16Pyrene [129-00-0] ^2.1 DFM102.1 U 101 ug/L EPA 8270D 11/21/16 18:16Safrole [94-59-7] ^1.2 DFM101.2 U 101 ug/L EPA 8270D 11/21/16 18:16Thionazin [297-97-2] ^2.3 DFM102.3 U 201 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,6-Tribromophenol 10-17991 %DFMEPA 8270D 11/21/16 18:166K0800291100 1 2-Fluorobiphenyl 10-14998 %DFMEPA 8270D 11/21/16 18:166K080024950.0 1 2-Fluorophenol 10-11071 %DFMEPA 8270D 11/21/16 18:166K0800271100 1 Nitrobenzene-d5 10-14989 %DFMEPA 8270D 11/21/16 18:166K080024550.0 1 Phenol-d5 10-8861 %DFMEPA 8270D 11/21/16 18:166K0800261100 1 Terphenyl-d14 10-188100 %DFMEPA 8270D 11/21/16 18:166K080025050.0 1 Page 43 of 71 Page 43 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Organochlorine Pesticides by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8081B 11/15/16 15:324,4'-DDD [72-54-8] ^0.044 MWC0.0500.044 U 0.11 ug/L EPA 8081B 11/15/16 15:324,4'-DDE [72-55-9] ^0.048 MWC0.0500.048 U 0.11 ug/L EPA 8081B 11/15/16 15:324,4'-DDT [50-29-3] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:32Aldrin [309-00-2] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:32alpha-BHC [319-84-6] ^0.036 MWC0.0500.036 U 0.051 ug/L EPA 8081B 11/15/16 15:32beta-BHC [319-85-7] ^0.041 MWC0.0500.041 U 0.051 ug/L EPA 8081B 11/15/16 15:32Chlordane (tech) [12789-03-6] ^0.37 MWC0.500.37 U 0.51 ug/L EPA 8081B 11/15/16 15:32Chlordane-alpha [5103-71-9] ^0.048 MWC0.0500.048 U NE1 ug/L EPA 8081B 11/15/16 15:32Chlordane-gamma [5566-34-7] ^0.042 MWC0.0500.042 U NE1 ug/L EPA 8081B 11/15/16 15:32delta-BHC [319-86-8] ^0.048 MWC0.0500.048 U 0.051 ug/L EPA 8081B 11/15/16 15:32Dieldrin [60-57-1] ^0.045 MWC0.0500.045 U 0.0751 ug/L EPA 8081B 11/15/16 15:32Endosulfan I [959-98-8] ^0.045 MWC0.0500.045 U 0.11 ug/L EPA 8081B 11/15/16 15:32Endosulfan II [33213-65-9] ^0.038 MWC0.0500.038 U 0.11 ug/L EPA 8081B 11/15/16 15:32Endosulfan sulfate [1031-07-8] ^0.032 MWC0.0500.032 U 0.11 ug/L EPA 8081B 11/15/16 15:32Endrin [72-20-8] ^0.041 MWC0.0500.041 U 0.11 ug/L EPA 8081B 11/15/16 15:32Endrin aldehyde [7421-93-4] ^0.049 MWC0.0500.049 U 0.11 ug/L EPA 8081B 11/15/16 15:32gamma-BHC [58-89-9] ^0.034 MWC0.0500.034 U 0.051 ug/L EPA 8081B 11/15/16 15:32Heptachlor [76-44-8] ^0.047 MWC0.0500.047 U 0.051 ug/L EPA 8081B 11/15/16 15:32Heptachlor epoxide [1024-57-3] ^0.037 MWC0.0500.037 U 0.0751 ug/L EPA 8081B 11/15/16 15:32Methoxychlor [72-43-5] ^0.048 MWC0.0500.048 U 11 ug/L EPA 8081B 11/15/16 15:32Toxaphene [8001-35-2] ^0.28 MWC0.500.28 U 1.51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 44-13487 %MWCEPA 8081B 11/15/16 15:326K090010.87 1.00 1 Decachlorobiphenyl 37-14956 %MWCEPA 8081B 11/15/16 15:326K090010.56 1.00 1 Page 44 of 71 Page 44 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Polychlorinated Biphenyls by GC ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8082A 11/16/16 16:37PCB-1016/1242 [12674-11-2/53469-21-9] ^0.48 MWC0.500.48 U 21 ug/L EPA 8082A 11/16/16 16:37PCB-1221 [11104-28-2] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:37PCB-1232 [11141-16-5] ^0.50 MWC0.500.50 U NE1 ug/L EPA 8082A 11/16/16 16:37PCB-1248 [12672-29-6] ^0.30 MWC0.500.30 U NE1 ug/L EPA 8082A 11/16/16 16:37PCB-1254 [11097-69-1] ^0.43 MWC0.500.43 U NE1 ug/L EPA 8082A 11/16/16 16:37PCB-1260 [11096-82-5] ^0.45 MWC0.500.45 U NE1 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4,5,6-TCMX 45-15170 %MWCEPA 8082A 11/16/16 16:376K090020.70 1.00 1 Decachlorobiphenyl 42-15960 %MWCEPA 8082A 11/16/16 16:376K090020.60 1.00 1 Page 45 of 71 Page 45 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 7470A 11/17/16 13:31Mercury [7439-97-6] ^0.170 JMV0.2000.170 U 0.21 Page 46 of 71 Page 46 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 6020B 11/16/16 11:25Antimony [7440-36-0] ^0.220 VLO2.000.832 J 61 ug/L EPA 6010D 11/15/16 11:35Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101 ug/L EPA 6010D 11/15/16 11:35Barium [7440-39-3] ^1.00 JDH10.067.2 J 1001 ug/L EPA 6010D 11/15/16 11:35Beryllium [7440-41-7] ^0.100 JDH1.000.100 U 11 ug/L EPA 6010D 11/15/16 11:35Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11 ug/L EPA 6010D 11/15/16 11:35Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101 ug/L EPA 6010D 11/15/16 11:35Cobalt [7440-48-4] ^1.10 JDH10.01.10 U 101 ug/L EPA 6010D 11/15/16 11:35Copper [7440-50-8] ^1.60 JDH10.01.60 J 101 ug/L EPA 6010D 11/15/16 11:35Lead [7439-92-1] ^3.10 JDH10.03.10 U 101 ug/L EPA 6010D 11/15/16 11:35Nickel [7440-02-0] ^2.20 JDH10.02.81 J 501 ug/L EPA 6020B 11/16/16 11:25Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101 ug/L EPA 6010D 11/15/16 11:35Silver [7440-22-4] ^1.90 JDH10.01.90 U 101 ug/L EPA 6020B 11/16/16 11:25Thallium [7440-28-0] ^0.110 VLO1.000.110 U 5.51 ug/L EPA 6010D 11/15/16 11:35Tin [7440-31-5] ^2.40 JDH10.02.40 U 1001 ug/L EPA 6010D 11/15/16 11:35Vanadium [7440-62-2] ^1.40 JDH10.02.13 J 251 ug/L EPA 6010D 11/15/16 11:35Zinc [7440-66-6] ^4.40 JDH10.027.9 101 Page 47 of 71 Page 47 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 9014 11/11/16 08:43Cyanide (total) [57-12-5] ^4.9 JLJ104.9 U 101 ug/L SM 4500S2 D-2000 11/10/16 18:00Sulfide [18496-25-8] ^10 JOC10010U 10001 Page 48 of 71 Page 48 of 72 www.encolabs.com 9809-GMW4Description:Lab Sample ID:CZ15795-04 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 09:27 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:Travis Queen Chlorinated Herbicides by GC ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8151A 11/14/16 11:422,4,5-T [93-76-5] ^0.28 JJB0.500.28 U 21 ug/L EPA 8151A 11/14/16 11:422,4,5-TP (Silvex) [93-72-1] ^0.44 JJB0.500.44 U 21 ug/L EPA 8151A 11/14/16 11:422,4-D [94-75-7] ^0.27 JJB0.500.27 U 21 ug/L EPA 8151A 11/14/16 11:42Dinoseb [88-85-7] ^0.32 JJB0.500.32 U 1 ug/L EPA 8151A 11/14/16 11:42Pentachlorophenol [87-86-5] ^0.19 JJB0.500.19 U 251 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 2,4-DCAA 37-13469 %JJBEPA 8151A 11/14/16 11:426K100211.4 2.00 1 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 49 of 71 Page 49 of 72 www.encolabs.com 9809-tripblankDescription:Lab Sample ID:CZ15795-05 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:ENCO Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 17:161,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MRK1.00.17 U 51 ug/L EPA 8260B 11/07/16 17:161,1,1-Trichloroethane [71-55-6] ^0.12 MRK1.00.12 U 11 ug/L EPA 8260B 11/07/16 17:161,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MRK1.00.28 U 31 ug/L EPA 8260B 11/07/16 17:161,1,2-Trichloroethane [79-00-5] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 17:161,1-Dichloroethane [75-34-3] ^0.13 MRK1.00.13 U 51 ug/L EPA 8260B 11/07/16 17:161,1-Dichloroethene [75-35-4] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 17:161,1-Dichloropropene [563-58-6] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 17:161,2,3-Trichloropropane [96-18-4] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 17:161,2,4-Trichlorobenzene [120-82-1] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 17:161,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MRK1.00.48 U 131 ug/L EPA 8260B 11/07/16 17:161,2-Dibromoethane [106-93-4] ^0.66 MRK1.00.66 U 11 ug/L EPA 8260B 11/07/16 17:161,2-Dichlorobenzene [95-50-1] ^0.19 MRK1.00.19 U 51 ug/L EPA 8260B 11/07/16 17:161,2-Dichloroethane [107-06-2] ^0.21 MRK1.00.21 U 11 ug/L EPA 8260B 11/07/16 17:161,2-Dichloropropane [78-87-5] ^0.10 MRK1.00.10 U 11 ug/L EPA 8260B 11/07/16 17:161,3-Dichlorobenzene [541-73-1] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 17:161,3-Dichloropropane [142-28-9] ^0.16 MRK1.00.16 U 11 ug/L EPA 8260B 11/07/16 17:161,4-Dichlorobenzene [106-46-7] ^0.19 MRK1.00.19 U 11 ug/L EPA 8260B 11/07/16 17:162,2-Dichloropropane [594-20-7] ^0.28 MRK1.00.28 U 151 ug/L EPA 8260B 11/07/16 17:162-Butanone [78-93-3] ^1.3 MRK5.01.3 U 1001 ug/L EPA 8260B 11/07/16 17:162-Hexanone [591-78-6] ^0.88 MRK5.00.88 U 501 ug/L EPA 8260B 11/07/16 17:163-Chloropropene [107-05-1] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 17:164-Methyl-2-pentanone [108-10-1] ^1.1 MRK5.01.1 U 1001 ug/L EPA 8260B 11/07/16 17:16Acetone [67-64-1] ^10 MRK2010U 1001 ug/L EPA 8260B 11/07/16 17:16Acetonitrile [75-05-8] ^5.0 MRK106.0 JB O-01551 ug/L EPA 8260B 11/07/16 17:16Acrolein [107-02-8] ^4.0 MRK104.0 U 531 ug/L EPA 8260B 11/07/16 17:16Acrylonitrile [107-13-1] ^3.5 MRK103.5 U 2001 ug/L EPA 8260B 11/07/16 17:16Benzene [71-43-2] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 17:16Bromochloromethane [74-97-5] ^0.48 MRK1.00.48 U 31 ug/L EPA 8260B 11/07/16 17:16Bromodichloromethane [75-27-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 17:16Bromoform [75-25-2] ^0.22 MRK1.00.22 U 31 ug/L EPA 8260B 11/07/16 17:16Bromomethane [74-83-9] ^0.14 MRK1.00.14 U 101 ug/L EPA 8260B 11/07/16 17:16Carbon disulfide [75-15-0] ^1.5 MRK5.01.5 U 1001 ug/L EPA 8260B 11/07/16 17:16Carbon tetrachloride [56-23-5] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 17:16Chlorobenzene [108-90-7] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 17:16Chloroethane [75-00-3] ^0.23 MRK1.00.23 U 101 ug/L EPA 8260B 11/07/16 17:16Chloroform [67-66-3] ^0.18 MRK1.00.18 U 51 ug/L EPA 8260B 11/07/16 17:16Chloromethane [74-87-3] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 17:16Chloroprene [126-99-8] ^0.64 MRK1.00.64 U 201 ug/L EPA 8260B 11/07/16 17:16cis-1,2-Dichloroethene [156-59-2] ^0.15 MRK1.00.15 U 51 ug/L EPA 8260B 11/07/16 17:16cis-1,3-Dichloropropene [10061-01-5] ^0.20 MRK1.00.20 U 11 ug/L EPA 8260B 11/07/16 17:16Dibromochloromethane [124-48-1] ^0.17 MRK1.00.17 U 31 ug/L EPA 8260B 11/07/16 17:16Dibromomethane [74-95-3] ^0.27 MRK1.00.27 U 101 ug/L EPA 8260B 11/07/16 17:16Dichlorodifluoromethane [75-71-8] ^0.20 MRK1.00.20 U 51 ug/L EPA 8260B 11/07/16 17:16Ethyl Methacrylate [97-63-2] ^0.38 MRK1.00.38 U 101 ug/L EPA 8260B 11/07/16 17:16Ethylbenzene [100-41-4] ^0.13 MRK1.00.13 U 11 ug/L EPA 8260B 11/07/16 17:16Hexachlorobutadiene [87-68-3] ^0.22 MRK1.00.22 U 101 ug/L EPA 8260B 11/07/16 17:16Iodomethane [74-88-4] ^1.7 MRK5.01.7 U 101 ug/L EPA 8260B 11/07/16 17:16Isobutyl alcohol [78-83-1] ^11 MRK5011U 1001 ug/L EPA 8260B 11/07/16 17:16m,p-Xylenes [108-38-3/106-42-3] ^0.17 MRK2.00.17 U NE1 ug/L EPA 8260B 11/07/16 17:16Methacrylonitrile [126-98-7] ^4.9 MRK104.9 U 1001 ug/L EPA 8260B 11/07/16 17:16Methyl Methacrylate [80-62-6] ^0.51 MRK1.00.51 U 301 Page 50 of 71 Page 50 of 72 www.encolabs.com 9809-tripblankDescription:Lab Sample ID:CZ15795-05 11/04/16 09:45Received: Matrix:Water Sampled:11/03/16 08:10 Work Order:CZ15795 Wilson C&D App IIProject:Sampled By:ENCO Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL ug/L EPA 8260B 11/07/16 17:16Methylene chloride [75-09-2] ^0.23 MRK1.00.23 U 11 ug/L EPA 8260B 11/07/16 17:16Naphthalene [91-20-3] ^0.11 MRK1.00.11 U 101 ug/L EPA 8260B 11/07/16 17:16o-Xylene [95-47-6] ^0.065 MRK1.00.065 U NE1 ug/L EPA 8260B 11/07/16 17:16Propionitrile [107-12-0] ^5.0 MRK105.0 U 1501 ug/L EPA 8260B 11/07/16 17:16Styrene [100-42-5] ^0.11 MRK1.00.11 U 11 ug/L EPA 8260B 11/07/16 17:16Tetrachloroethene [127-18-4] ^0.17 MRK1.00.17 U 11 ug/L EPA 8260B 11/07/16 17:16Tetrahydrofuran [109-99-9] ^0.80 MRK1.00.80 U 1 ug/L EPA 8260B 11/07/16 17:16Toluene [108-88-3] ^0.14 MRK1.00.14 U 11 ug/L EPA 8260B 11/07/16 17:16trans-1,2-Dichloroethene [156-60-5] ^0.21 MRK1.00.21 U 51 ug/L EPA 8260B 11/07/16 17:16trans-1,3-Dichloropropene [10061-02-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 17:16trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MRK1.00.70 U 1001 ug/L EPA 8260B 11/07/16 17:16Trichloroethene [79-01-6] ^0.15 MRK1.00.15 U 11 ug/L EPA 8260B 11/07/16 17:16Trichlorofluoromethane [75-69-4] ^0.24 MRK1.00.24 U 11 ug/L EPA 8260B 11/07/16 17:16Vinyl acetate [108-05-4] ^0.95 MRK5.00.95 U 501 ug/L EPA 8260B 11/07/16 17:16Vinyl chloride [75-01-4] ^0.32 MRK1.00.32 U 11 ug/L EPA 8260B 11/07/16 17:16Xylenes (Total) [1330-20-7] ^0.45 MRK3.00.45 U 51 Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF 4-Bromofluorobenzene 53-13691 %MRKEPA 8260B 11/07/16 17:166K070044650.0 1 Dibromofluoromethane 67-129103 %MRKEPA 8260B 11/07/16 17:166K070045150.0 1 Toluene-d8 59-13496 %MRKEPA 8260B 11/07/16 17:166K070044850.0 1 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 51 of 71 Page 51 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K04022 - EPA 5030B_MS Prepared: 11/04/2016 11:47 Analyzed: 11/04/2016 18:03Blank (6K04022-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.17 U 1,1,1,2-Tetrachloroethane ug/L1.00.12 U 1,1,1-Trichloroethane ug/L1.00.28 U 1,1,2,2-Tetrachloroethane ug/L1.00.14 U 1,1,2-Trichloroethane ug/L1.00.13 U 1,1-Dichloroethane ug/L1.00.21 U 1,1-Dichloroethene ug/L1.00.15 U 1,1-Dichloropropene ug/L1.00.23 U 1,2,3-Trichloropropane ug/L1.00.14 U 1,2,4-Trichlorobenzene ug/L1.00.48 U 1,2-Dibromo-3-chloropropane ug/L1.00.66 U 1,2-Dibromoethane ug/L1.00.19 U 1,2-Dichlorobenzene ug/L1.00.21 U 1,2-Dichloroethane ug/L1.00.10 U 1,2-Dichloropropane ug/L1.00.15 U 1,3-Dichlorobenzene ug/L1.00.16 U 1,3-Dichloropropane ug/L1.00.19 U 1,4-Dichlorobenzene ug/L1.00.28 U 2,2-Dichloropropane ug/L5.01.3 U 2-Butanone ug/L5.00.88 U 2-Hexanone ug/L1.00.11 U 3-Chloropropene ug/L5.01.1 U 4-Methyl-2-pentanone ug/L2010U Acetone ug/L105.0 U Acetonitrile ug/L104.0 U Acrolein ug/L103.5 U Acrylonitrile ug/L1.00.15 U Benzene ug/L1.00.48 U Bromochloromethane ug/L1.00.17 U Bromodichloromethane ug/L1.00.22 U Bromoform ug/L1.00.14 U Bromomethane ug/L5.01.5 U Carbon disulfide ug/L1.00.17 U Carbon tetrachloride ug/L1.00.17 U Chlorobenzene ug/L1.00.23 U Chloroethane ug/L1.00.18 U Chloroform ug/L1.00.13 U Chloromethane ug/L1.00.64 U Chloroprene ug/L1.00.15 U cis-1,2-Dichloroethene ug/L1.00.20 U cis-1,3-Dichloropropene ug/L1.00.17 U Dibromochloromethane ug/L1.00.27 U Dibromomethane ug/L1.00.20 U Dichlorodifluoromethane ug/L1.00.38 U Ethyl Methacrylate ug/L1.00.13 U Ethylbenzene ug/L1.00.22 U Hexachlorobutadiene ug/L5.01.7 U Iodomethane ug/L5011U Isobutyl alcohol ug/L2.00.17 U m,p-Xylenes Page 52 of 71 Page 52 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K04022 - EPA 5030B_MS Prepared: 11/04/2016 11:47 Analyzed: 11/04/2016 18:03Blank (6K04022-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L104.9 U Methacrylonitrile ug/L1.00.51 U Methyl Methacrylate ug/L1.00.23 U Methylene chloride ug/L1.00.11 U Naphthalene ug/L1.00.065 U o-Xylene ug/L105.0 U Propionitrile ug/L1.00.11 U Styrene ug/L1.00.17 U Tetrachloroethene ug/L1.00.80 U Tetrahydrofuran ug/L1.00.14 U Toluene ug/L1.00.21 U trans-1,2-Dichloroethene ug/L1.00.15 U trans-1,3-Dichloropropene ug/L1.00.70 U trans-1,4-Dichloro-2-butene ug/L1.00.15 U Trichloroethene ug/L1.00.24 U Trichlorofluoromethane ug/L5.00.95 U Vinyl acetate ug/L1.00.32 U Vinyl chloride ug/L3.00.45 U Xylenes (Total) ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9547 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9749 ug/L 50.0 59-134Surrogate: Toluene-d8 9748 Prepared: 11/04/2016 11:47 Analyzed: 11/04/2016 17:05LCS (6K04022-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-1338717 1,1-Dichloroethene ug/L1.0 20.0 81-1348918 Benzene ug/L1.0 20.0 83-1179018 Chlorobenzene ug/L1.0 20.0 71-1189018 Toluene ug/L1.0 20.0 74-1198918 Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9748 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9447 ug/L 50.0 59-134Surrogate: Toluene-d8 9648 Prepared: 11/04/2016 11:47 Analyzed: 11/04/2016 16:07Matrix Spike (6K04022-MS1) Source: CZ16481-05 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-1331360.21 U27 QM-071,1-Dichloroethene ug/L1.0 20.0 81-1341330.15 U27 Benzene ug/L1.0 20.0 83-1171370.17 U27 QM-07Chlorobenzene ug/L1.0 20.0 71-1181360.14 U27 QM-07Toluene ug/L1.0 20.0 74-1191340.15 U27 QM-07Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 10251 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9548 ug/L 50.0 59-134Surrogate: Toluene-d8 9748 Page 53 of 71 Page 53 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K04022 - EPA 5030B_MS Prepared: 11/04/2016 11:47 Analyzed: 11/04/2016 16:36Matrix Spike Dup (6K04022-MSD1) Source: CZ16481-05 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 2075-13388 430.21 U18 QM-111,1-Dichloroethene ug/L1.0 20.0 1781-13492 370.15 U18 QM-11Benzene ug/L1.0 20.0 1683-11787 450.17 U17 QM-11Chlorobenzene ug/L1.0 20.0 1771-11886 450.14 U17 QM-11Toluene ug/L1.0 20.0 2274-11990 390.15 U18 QM-11Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9045 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9547 ug/L 50.0 59-134Surrogate: Toluene-d8 9648 Batch 6K04032 - EPA 5030B_MS Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 06:09Blank (6K04032-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.17 U 1,1,1,2-Tetrachloroethane ug/L1.00.12 U 1,1,1-Trichloroethane ug/L1.00.28 U 1,1,2,2-Tetrachloroethane ug/L1.00.14 U 1,1,2-Trichloroethane ug/L1.00.13 U 1,1-Dichloroethane ug/L1.00.21 U 1,1-Dichloroethene ug/L1.00.15 U 1,1-Dichloropropene ug/L1.00.23 U 1,2,3-Trichloropropane ug/L1.00.14 U 1,2,4-Trichlorobenzene ug/L1.00.48 U 1,2-Dibromo-3-chloropropane ug/L1.00.66 U 1,2-Dibromoethane ug/L1.00.19 U 1,2-Dichlorobenzene ug/L1.00.21 U 1,2-Dichloroethane ug/L1.00.10 U 1,2-Dichloropropane ug/L1.00.15 U 1,3-Dichlorobenzene ug/L1.00.16 U 1,3-Dichloropropane ug/L1.00.19 U 1,4-Dichlorobenzene ug/L1.00.28 U 2,2-Dichloropropane ug/L5.01.3 U 2-Butanone ug/L5.00.88 U 2-Hexanone ug/L1.00.11 U 3-Chloropropene ug/L5.01.1 U 4-Methyl-2-pentanone ug/L2010U Acetone ug/L105.0 U Acetonitrile ug/L104.0 U Acrolein ug/L103.5 U Acrylonitrile ug/L1.00.15 U Benzene ug/L1.00.48 U Bromochloromethane ug/L1.00.17 U Bromodichloromethane ug/L1.00.22 U Bromoform ug/L1.00.14 U Bromomethane ug/L5.01.5 U Carbon disulfide ug/L1.00.17 U Carbon tetrachloride Page 54 of 71 Page 54 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K04032 - EPA 5030B_MS Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 06:09Blank (6K04032-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.17 U Chlorobenzene ug/L1.00.23 U Chloroethane ug/L1.00.18 U Chloroform ug/L1.00.13 U Chloromethane ug/L1.00.64 U Chloroprene ug/L1.00.15 U cis-1,2-Dichloroethene ug/L1.00.20 U cis-1,3-Dichloropropene ug/L1.00.17 U Dibromochloromethane ug/L1.00.27 U Dibromomethane ug/L1.00.20 U Dichlorodifluoromethane ug/L1.00.38 U Ethyl Methacrylate ug/L1.00.13 U Ethylbenzene ug/L1.00.22 U Hexachlorobutadiene ug/L5.01.7 U Iodomethane ug/L5011U Isobutyl alcohol ug/L2.00.17 U m,p-Xylenes ug/L104.9 U Methacrylonitrile ug/L1.00.51 U Methyl Methacrylate ug/L1.00.23 U Methylene chloride ug/L1.00.11 U Naphthalene ug/L1.00.065 U o-Xylene ug/L105.0 U Propionitrile ug/L1.00.11 U Styrene ug/L1.00.17 U Tetrachloroethene ug/L1.00.80 U Tetrahydrofuran ug/L1.00.14 U Toluene ug/L1.00.21 U trans-1,2-Dichloroethene ug/L1.00.15 U trans-1,3-Dichloropropene ug/L1.00.70 U trans-1,4-Dichloro-2-butene ug/L1.00.15 U Trichloroethene ug/L1.00.24 U Trichlorofluoromethane ug/L5.00.95 U Vinyl acetate ug/L1.00.32 U Vinyl chloride ug/L3.00.45 U Xylenes (Total) ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9548 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9748 ug/L 50.0 59-134Surrogate: Toluene-d8 9648 Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 05:10LCS (6K04032-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-1338517 1,1-Dichloroethene ug/L1.0 20.0 81-1348818 Benzene ug/L1.0 20.0 83-1178818 Chlorobenzene ug/L1.0 20.0 71-1188717 Toluene ug/L1.0 20.0 74-1198517 Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9548 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9648 Page 55 of 71 Page 55 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K04032 - EPA 5030B_MS Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 05:10LCS (6K04032-BS1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L 50.0 59-134Surrogate: Toluene-d8 9949 Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 04:12Matrix Spike (6K04032-MS1) Source: CZ16481-06 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-1331240.21 U25 1,1-Dichloroethene ug/L1.0 20.0 81-1341220.15 U24 Benzene ug/L1.0 20.0 83-1171210.17 U24 QM-07Chlorobenzene ug/L1.0 20.0 71-1181200.14 U24 QM-07Toluene ug/L1.0 20.0 74-1191220.15 U24 QM-07Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9849 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9749 ug/L 50.0 59-134Surrogate: Toluene-d8 9749 Prepared: 11/04/2016 14:07 Analyzed: 11/05/2016 04:41Matrix Spike Dup (6K04032-MSD1) Source: CZ16481-06 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 2075-13390 320.21 U18 QM-111,1-Dichloroethene ug/L1.0 20.0 1781-13491 280.15 U18 QM-11Benzene ug/L1.0 20.0 1683-11793 260.17 U19 QM-11Chlorobenzene ug/L1.0 20.0 1771-11893 260.14 U19 QM-11Toluene ug/L1.0 20.0 2274-11989 310.15 U18 QM-11Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9950 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9548 ug/L 50.0 59-134Surrogate: Toluene-d8 9749 Batch 6K07004 - EPA 5030B_MS Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 16:16Blank (6K07004-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.17 U 1,1,1,2-Tetrachloroethane ug/L1.00.12 U 1,1,1-Trichloroethane ug/L1.00.28 U 1,1,2,2-Tetrachloroethane ug/L1.00.14 U 1,1,2-Trichloroethane ug/L1.00.13 U 1,1-Dichloroethane ug/L1.00.21 U 1,1-Dichloroethene ug/L1.00.15 U 1,1-Dichloropropene ug/L1.00.23 U 1,2,3-Trichloropropane ug/L1.00.14 U 1,2,4-Trichlorobenzene ug/L1.00.48 U 1,2-Dibromo-3-chloropropane ug/L1.00.66 U 1,2-Dibromoethane ug/L1.00.19 U 1,2-Dichlorobenzene ug/L1.00.21 U 1,2-Dichloroethane ug/L1.00.10 U 1,2-Dichloropropane Page 56 of 71 Page 56 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K07004 - EPA 5030B_MS Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 16:16Blank (6K07004-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.15 U 1,3-Dichlorobenzene ug/L1.00.16 U 1,3-Dichloropropane ug/L1.00.19 U 1,4-Dichlorobenzene ug/L1.00.28 U 2,2-Dichloropropane ug/L5.01.3 U 2-Butanone ug/L5.00.88 U 2-Hexanone ug/L1.00.11 U 3-Chloropropene ug/L5.01.1 U 4-Methyl-2-pentanone ug/L2010U Acetone ug/L1011 O-01Acetonitrile ug/L104.0 U Acrolein ug/L103.5 U Acrylonitrile ug/L1.00.15 U Benzene ug/L1.00.48 U Bromochloromethane ug/L1.00.17 U Bromodichloromethane ug/L1.00.22 U Bromoform ug/L1.00.14 U Bromomethane ug/L5.01.5 U Carbon disulfide ug/L1.00.17 U Carbon tetrachloride ug/L1.00.17 U Chlorobenzene ug/L1.00.23 U Chloroethane ug/L1.00.18 U Chloroform ug/L1.00.13 U Chloromethane ug/L1.00.64 U Chloroprene ug/L1.00.15 U cis-1,2-Dichloroethene ug/L1.00.20 U cis-1,3-Dichloropropene ug/L1.00.17 U Dibromochloromethane ug/L1.00.27 U Dibromomethane ug/L1.00.20 U Dichlorodifluoromethane ug/L1.00.38 U Ethyl Methacrylate ug/L1.00.13 U Ethylbenzene ug/L1.00.22 U Hexachlorobutadiene ug/L5.01.7 U Iodomethane ug/L5011U Isobutyl alcohol ug/L2.00.17 U m,p-Xylenes ug/L104.9 U Methacrylonitrile ug/L1.00.51 U Methyl Methacrylate ug/L1.00.23 U Methylene chloride ug/L1.00.11 U Naphthalene ug/L1.00.065 U o-Xylene ug/L105.0 U Propionitrile ug/L1.00.11 U Styrene ug/L1.00.17 U Tetrachloroethene ug/L1.00.80 U Tetrahydrofuran ug/L1.00.14 U Toluene ug/L1.00.21 U trans-1,2-Dichloroethene ug/L1.00.15 U trans-1,3-Dichloropropene ug/L1.00.70 U trans-1,4-Dichloro-2-butene ug/L1.00.15 U Trichloroethene Page 57 of 71 Page 57 of 72 www.encolabs.com QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 6K07004 - EPA 5030B_MS Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 16:16Blank (6K07004-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.00.24 U Trichlorofluoromethane ug/L5.00.95 U Vinyl acetate ug/L1.00.32 U Vinyl chloride ug/L3.00.45 U Xylenes (Total) ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9347 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 10251 ug/L 50.0 59-134Surrogate: Toluene-d8 9748 Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 14:16LCS (6K07004-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-13311122 1,1-Dichloroethene ug/L1.0 20.0 81-13410220 Benzene ug/L1.0 20.0 83-11710321 Chlorobenzene ug/L1.0 20.0 71-11810220 Toluene ug/L1.0 20.0 74-11910421 Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9347 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 10151 ug/L 50.0 59-134Surrogate: Toluene-d8 9949 Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 14:46Matrix Spike (6K07004-MS1) Source: CZ16481-10 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 75-1331190.21 U24 1,1-Dichloroethene ug/L1.0 20.0 81-1341080.15 U22 Benzene ug/L1.0 20.0 83-1171090.17 U22 Chlorobenzene ug/L1.0 20.0 71-1181100.14 U22 Toluene ug/L1.0 20.0 74-1191080.15 U22 Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9246 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9949 ug/L 50.0 59-134Surrogate: Toluene-d8 9648 Prepared: 11/07/2016 08:13 Analyzed: 11/07/2016 15:16Matrix Spike Dup (6K07004-MSD1) Source: CZ16481-10 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L1.0 20.0 2075-133105 120.21 U21 1,1-Dichloroethene ug/L1.0 20.0 1781-13498 100.15 U20 Benzene ug/L1.0 20.0 1683-117100 90.17 U20 Chlorobenzene ug/L1.0 20.0 1771-118100 100.14 U20 Toluene ug/L1.0 20.0 2274-11996 110.15 U19 Trichloroethene ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9447 ug/L 50.0 67-129Surrogate: Dibromofluoromethane 10251 ug/L 50.0 59-134Surrogate: Toluene-d8 9749 Page 58 of 71 Page 58 of 72 www.encolabs.com QUALITY CONTROL Semivolatile Organic Compounds by GCMS - Quality Control Batch 6K08002 - EPA 3510C_MS Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 15:32Blank (6K08002-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L102.0 U 1,2,4,5-Tetrachlorobenzene ug/L103.0 U 1,3,5-Trinitrobenzene ug/L101.9 U 1,3-Dinitrobenzene ug/L102.5 U 1,4-Naphthoquinone ug/L104.0 U QV-021,4-Phenylenediamine ug/L101.9 U QV-021-Naphthylamine ug/L102.0 U 2,3,4,6-Tetrachlorophenol ug/L101.0 U 2,4,5-Trichlorophenol ug/L101.1 U 2,4,6-Trichlorophenol ug/L101.4 U 2,4-Dichlorophenol ug/L101.3 U 2,4-Dimethylphenol ug/L102.6 U 2,4-Dinitrophenol ug/L102.4 U 2,4-Dinitrotoluene ug/L101.1 U 2,6-Dichlorophenol ug/L101.5 U 2,6-Dinitrotoluene ug/L102.5 U 2-Acetylaminofluorene ug/L101.0 U 2-Chloronaphthalene ug/L101.2 U 2-Chlorophenol ug/L102.9 U 2-Methyl-4,6-dinitrophenol ug/L101.5 U 2-Methylnaphthalene ug/L101.4 U 2-Methylphenol ug/L103.0 U QV-022-Naphthylamine ug/L101.5 U 2-Nitroaniline ug/L101.1 U 2-Nitrophenol ug/L101.6 U 3 & 4-Methylphenol ug/L103.3 U 3,3'-Dichlorobenzidine ug/L102.2 U 3,3'-Dimethylbenzidine ug/L101.3 U 3-Methylcholanthrene ug/L102.1 U 3-Nitroaniline ug/L102.1 U QV-024-Aminobiphenyl ug/L101.0 U 4-Bromophenyl-phenylether ug/L101.5 U 4-Chloro-3-methylphenol ug/L101.2 U 4-Chloroaniline ug/L101.6 U 4-Chlorophenyl-phenylether ug/L103.2 U 4-Nitroaniline ug/L102.0 U 4-Nitrophenol ug/L103.2 U 5-Nitro-o-toluidine ug/L101.1 U 7,12-Dimethylbenz(a)anthracene ug/L101.4 U Acenaphthene ug/L101.2 U Acenaphthylene ug/L101.3 U Acetophenone ug/L101.6 U Anthracene ug/L101.3 U Benzo(a)anthracene ug/L101.3 U Benzo(a)pyrene ug/L101.0 U Benzo(b)fluoranthene ug/L102.4 U Benzo(g,h,i)perylene ug/L101.3 U Benzo(k)fluoranthene ug/L101.4 U Benzyl alcohol ug/L101.4 U Bis(2-chloroethoxy)methane Page 59 of 71 Page 59 of 72 www.encolabs.com QUALITY CONTROL Semivolatile Organic Compounds by GCMS - Quality Control Batch 6K08002 - EPA 3510C_MS Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 15:32Blank (6K08002-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L101.2 U Bis(2-chloroethyl)ether ug/L101.3 U Bis(2-chloroisopropyl)ether ug/L5.01.7 U Bis(2-ethylhexyl)phthalate ug/L102.0 U Butylbenzylphthalate ug/L101.0 U Chlorobenzilate ug/L102.0 U Chrysene ug/L101.0 U Diallate ug/L102.3 U Dibenzo(a,h)anthracene ug/L101.4 U Dibenzofuran ug/L102.1 U Diethylphthalate ug/L102.3 U Dimethoate ug/L101.4 U Dimethylphthalate ug/L101.5 U Di-n-butylphthalate ug/L103.1 U Di-n-octylphthalate ug/L101.1 U Disulfoton ug/L101.2 U Ethyl methanesulfonate ug/L102.7 U Famphur ug/L102.1 U Fluoranthene ug/L101.7 U Fluorene ug/L101.0 U Hexachlorobenzene ug/L101.2 U Hexachlorobutadiene ug/L101.3 U Hexachlorocyclopentadiene ug/L101.1 U Hexachloroethane ug/L101.7 U Hexachloropropene ug/L102.2 U Indeno(1,2,3-cd)pyrene ug/L101.0 U Isodrin ug/L101.3 U Isophorone ug/L101.3 U Isosafrole ug/L207.2 U QV-01Kepone ug/L103.5 U Methapyrilene ug/L101.0 U Methyl Methanesulfonate ug/L102.5 U Methyl parathion ug/L101.2 U Nitrobenzene ug/L101.3 U N-Nitrosodiethylamine ug/L101.3 U N-Nitrosodimethylamine ug/L101.2 U N-Nitrosodi-n-butylamine ug/L101.5 U N-Nitroso-di-n-propylamine ug/L102.1 U N-nitrosodiphenylamine/Diphenylamine ug/L101.9 U N-Nitrosomethylethylamine ug/L101.1 U N-Nitrosopiperidine ug/L101.3 U N-Nitrosopyrrolidine ug/L101.3 U O,O,O-Triethyl phosphorothioate ug/L101.1 U o-Toluidine ug/L101.7 U Parathion ug/L101.4 U p-Dimethylaminoazobenzene ug/L101.3 U Pentachlorobenzene ug/L101.0 U Pentachloronitrobenzene ug/L102.7 U Phenacetin ug/L101.4 U Phenanthrene Page 60 of 71 Page 60 of 72 www.encolabs.com QUALITY CONTROL Semivolatile Organic Compounds by GCMS - Quality Control Batch 6K08002 - EPA 3510C_MS Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 15:32Blank (6K08002-BLK1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L101.4 U Phenol ug/L101.0 U Phorate ug/L101.4 U Pronamide ug/L102.1 U Pyrene ug/L101.2 U Safrole ug/L102.3 U Thionazin ug/L 100 10-179Surrogate: 2,4,6-Tribromophenol 8080 ug/L 50.0 10-149Surrogate: 2-Fluorobiphenyl 7940 ug/L 100 10-110Surrogate: 2-Fluorophenol 5656 ug/L 50.0 10-149Surrogate: Nitrobenzene-d5 7437 ug/L 100 10-88Surrogate: Phenol-d5 4848 ug/L 50.0 10-188Surrogate: Terphenyl-d14 8442 Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 16:05LCS (6K08002-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 50.0 40-1096533 2-Chlorophenol ug/L10 50.0 58-1216834 4-Chloro-3-methylphenol ug/L10 50.0 33-1054322 4-Nitrophenol ug/L10 50.0 39-1257638 Acenaphthene ug/L10 50.0 48-1266934 N-Nitroso-di-n-propylamine ug/L10 50.0 19-784422 Phenol ug/L10 50.0 44-1378643 Pyrene ug/L 100 10-179Surrogate: 2,4,6-Tribromophenol 7474 ug/L 50.0 10-149Surrogate: 2-Fluorobiphenyl 7236 ug/L 100 10-110Surrogate: 2-Fluorophenol 5353 ug/L 50.0 10-149Surrogate: Nitrobenzene-d5 6733 ug/L 100 10-88Surrogate: Phenol-d5 4444 ug/L 50.0 10-188Surrogate: Terphenyl-d14 8844 Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 19:20Matrix Spike (6K08002-MS1) Source: CZ16266-03 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 50.0 40-109771.2 U39 2-Chlorophenol ug/L10 50.0 58-121811.5 U40 4-Chloro-3-methylphenol ug/L10 50.0 33-105512.0 U25 4-Nitrophenol ug/L10 50.0 39-125911.4 U46 Acenaphthene ug/L10 50.0 48-126801.5 U40 N-Nitroso-di-n-propylamine ug/L10 50.0 19-78511.4 U25 Phenol ug/L10 50.0 44-137942.1 U47 Pyrene ug/L 100 10-179Surrogate: 2,4,6-Tribromophenol 8787 ug/L 50.0 10-149Surrogate: 2-Fluorobiphenyl 8442 ug/L 100 10-110Surrogate: 2-Fluorophenol 6262 ug/L 50.0 10-149Surrogate: Nitrobenzene-d5 7839 ug/L 100 10-88Surrogate: Phenol-d5 5151 ug/L 50.0 10-188Surrogate: Terphenyl-d14 9849 Page 61 of 71 Page 61 of 72 www.encolabs.com QUALITY CONTROL Semivolatile Organic Compounds by GCMS - Quality Control Batch 6K08002 - EPA 3510C_MS Prepared: 11/08/2016 07:50 Analyzed: 11/21/2016 19:52Matrix Spike Dup (6K08002-MSD1) Source: CZ16266-03 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 50.0 2240-10975 31.2 U37 2-Chlorophenol ug/L10 50.0 2258-12176 61.5 U38 4-Chloro-3-methylphenol ug/L10 50.0 2733-10546 102.0 U23 4-Nitrophenol ug/L10 50.0 2539-12588 41.4 U44 Acenaphthene ug/L10 50.0 2348-12679 21.5 U39 N-Nitroso-di-n-propylamine ug/L10 50.0 1819-7848 51.4 U24 Phenol ug/L10 50.0 2444-13789 52.1 U45 Pyrene ug/L 100 10-179Surrogate: 2,4,6-Tribromophenol 8080 ug/L 50.0 10-149Surrogate: 2-Fluorobiphenyl 8241 ug/L 100 10-110Surrogate: 2-Fluorophenol 5959 ug/L 50.0 10-149Surrogate: Nitrobenzene-d5 7437 ug/L 100 10-88Surrogate: Phenol-d5 4848 ug/L 50.0 10-188Surrogate: Terphenyl-d14 9246 Organochlorine Pesticides by GC - Quality Control Batch 6K09001 - EPA 3510C Prepared: 11/09/2016 08:17 Analyzed: 11/15/2016 13:43Blank (6K09001-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.0500.044 U 4,4'-DDD ug/L0.0500.048 U 4,4'-DDE ug/L0.0500.049 U 4,4'-DDT ug/L0.0500.041 U Aldrin ug/L0.0500.036 U alpha-BHC ug/L0.0500.041 U beta-BHC ug/L0.500.37 U Chlordane (tech) ug/L0.0500.048 U Chlordane-alpha ug/L0.0500.042 U Chlordane-gamma ug/L0.0500.048 U delta-BHC ug/L0.0500.045 U Dieldrin ug/L0.0500.045 U Endosulfan I ug/L0.0500.038 U Endosulfan II ug/L0.0500.032 U Endosulfan sulfate ug/L0.0500.041 U Endrin ug/L0.0500.049 U Endrin aldehyde ug/L0.0500.034 U gamma-BHC ug/L0.0500.047 U Heptachlor ug/L0.0500.037 U Heptachlor epoxide ug/L0.0500.048 U Methoxychlor ug/L0.500.28 U Toxaphene ug/L 1.00 44-134Surrogate: 2,4,5,6-TCMX 610.61 ug/L 1.00 37-149Surrogate: Decachlorobiphenyl 680.68 Prepared: 11/09/2016 08:17 Analyzed: 11/15/2016 13:56LCS (6K09001-BS1) Page 62 of 71 Page 62 of 72 www.encolabs.com QUALITY CONTROL Organochlorine Pesticides by GC - Quality Control Batch 6K09001 - EPA 3510C Prepared: 11/09/2016 08:17 Analyzed: 11/15/2016 13:56LCS (6K09001-BS1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.050 1.00 37-139680.68 4,4'-DDT ug/L0.050 1.00 46-132690.69 Dieldrin ug/L0.050 1.00 43-133680.68 Endrin ug/L 1.00 44-134Surrogate: 2,4,5,6-TCMX 400.40 QS-03 ug/L 1.00 37-149Surrogate: Decachlorobiphenyl 690.69 Prepared: 11/09/2016 08:17 Analyzed: 11/15/2016 14:10Matrix Spike (6K09001-MS1) Source: CZ16266-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.050 1.00 37-139890.049 U0.89 4,4'-DDT ug/L0.050 1.00 46-132900.045 U0.90 Dieldrin ug/L0.050 1.00 43-133840.041 U0.84 Endrin ug/L 1.00 44-134Surrogate: 2,4,5,6-TCMX 510.51 ug/L 1.00 37-149Surrogate: Decachlorobiphenyl 690.69 Prepared: 11/09/2016 08:17 Analyzed: 11/15/2016 14:24Matrix Spike Dup (6K09001-MSD1) Source: CZ16266-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.050 1.00 2637-13978 130.049 U0.78 4,4'-DDT ug/L0.050 1.00 2746-13278 140.045 U0.78 Dieldrin ug/L0.050 1.00 2643-13374 130.041 U0.74 Endrin ug/L 1.00 44-134Surrogate: 2,4,5,6-TCMX 480.48 ug/L 1.00 37-149Surrogate: Decachlorobiphenyl 630.63 Polychlorinated Biphenyls by GC - Quality Control Batch 6K09002 - EPA 3510C Prepared: 11/09/2016 08:13 Analyzed: 11/16/2016 14:33Blank (6K09002-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.500.48 U PCB-1016/1242 ug/L0.500.43 U PCB-1221 ug/L0.500.50 U PCB-1232 ug/L0.500.30 U PCB-1248 ug/L0.500.43 U PCB-1254 ug/L0.500.45 U PCB-1260 ug/L 1.00 45-151Surrogate: 2,4,5,6-TCMX [2C]470.47 ug/L 1.00 42-159Surrogate: Decachlorobiphenyl 660.66 Prepared: 11/09/2016 08:13 Analyzed: 11/16/2016 14:47LCS (6K09002-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 10.0 66-149696.9 PCB-1016/1242 ug/L0.50 10.0 64-150767.6 PCB-1260 Page 63 of 71 Page 63 of 72 www.encolabs.com QUALITY CONTROL Polychlorinated Biphenyls by GC - Quality Control Batch 6K09002 - EPA 3510C Prepared: 11/09/2016 08:13 Analyzed: 11/16/2016 14:47LCS (6K09002-BS1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L 1.00 45-151Surrogate: 2,4,5,6-TCMX 460.46 ug/L 1.00 42-159Surrogate: Decachlorobiphenyl 550.55 Prepared: 11/09/2016 08:13 Analyzed: 11/16/2016 15:01Matrix Spike (6K09002-MS1) Source: CZ16266-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 10.0 66-149600.48 U6.0 QM-07PCB-1016/1242 ug/L0.50 10.0 64-150700.45 U7.0 PCB-1260 ug/L 1.00 45-151Surrogate: 2,4,5,6-TCMX 440.44 QS-03 ug/L 1.00 42-159Surrogate: Decachlorobiphenyl 520.52 Prepared: 11/09/2016 08:13 Analyzed: 11/16/2016 15:15Matrix Spike Dup (6K09002-MSD1) Source: CZ16266-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 10.0 2166-14966 100.48 U6.6 PCB-1016/1242 ug/L0.50 10.0 1864-15073 40.45 U7.3 PCB-1260 ug/L 1.00 45-151Surrogate: 2,4,5,6-TCMX 470.47 ug/L 1.00 42-159Surrogate: Decachlorobiphenyl 570.57 Metals by EPA 6000/7000 Series Methods - Quality Control Batch 6K16016 - EPA 245.1 Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 12:58Blank (6K16016-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.2000.170 U Mercury Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 13:01Blank (6K16016-BLK2) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L4.003.40 U Mercury Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 13:03LCS (6K16016-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.200 5.00 80-120904.52 Mercury Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 13:08Matrix Spike (6K16016-MS1) Source: CZ15795-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.200 5.00 75-125860.170 U4.29 Mercury Page 64 of 71 Page 64 of 72 www.encolabs.com QUALITY CONTROL Metals by EPA 6000/7000 Series Methods - Quality Control Batch 6K16016 - EPA 245.1 Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 13:10Matrix Spike Dup (6K16016-MSD1) Source: CZ15795-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.200 5.00 2575-12585 10.170 U4.25 Mercury Prepared: 11/16/2016 10:21 Analyzed: 11/17/2016 13:12Post Spike (6K16016-PS1) Source: CZ15795-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.200 5.00 75-125960.1034.91 Mercury Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 6K07029 - EPA 3005A Prepared: 11/07/2016 14:39 Analyzed: 11/15/2016 10:16Blank (6K07029-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10.06.80 U Arsenic ug/L10.01.00 U Barium ug/L1.000.100 U Beryllium ug/L1.000.360 U Cadmium ug/L10.01.40 U Chromium ug/L10.01.10 U Cobalt ug/L10.01.60 U Copper ug/L10.03.10 U Lead ug/L10.02.20 U Nickel ug/L10.01.90 U Silver ug/L10.02.40 U Tin ug/L10.01.40 U Vanadium ug/L10.04.40 U Zinc Prepared: 11/07/2016 14:39 Analyzed: 11/15/2016 10:56LCS (6K07029-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10.0 200 80-12094188 Arsenic ug/L10.0 200 80-12091181 Barium ug/L1.00 20.0 80-1209118.1 Beryllium ug/L1.00 20.0 80-1209118.2 Cadmium ug/L10.0 200 80-12090181 Chromium ug/L10.0 200 80-12091181 Cobalt ug/L10.0 200 80-12087174 Copper ug/L10.0 200 80-12092183 Lead ug/L10.0 200 80-12092184 Nickel ug/L10.0 200 80-12092183 Silver ug/L10.0 200 80-12089179 Tin ug/L10.0 200 80-12091182 Vanadium ug/L10.0 200 80-12094188 Zinc Prepared: 11/07/2016 14:39 Analyzed: 11/15/2016 11:01Matrix Spike (6K07029-MS1) Page 65 of 71 Page 65 of 72 www.encolabs.com QUALITY CONTROL Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 6K07029 - EPA 3005A Prepared: 11/07/2016 14:39 Analyzed: 11/15/2016 11:01Matrix Spike (6K07029-MS1) Continued Source: CZ15796-03 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10.0 200 75-125976.80 U195 Arsenic ug/L10.0 200 75-12590104284 Barium ug/L1.00 20.0 75-125951.6620.7 Beryllium ug/L1.00 20.0 75-125930.360 U18.5 Cadmium ug/L10.0 200 75-125931.40 U186 Chromium ug/L10.0 200 75-125941.65189 Cobalt ug/L10.0 200 75-125901.60 U179 Copper ug/L10.0 200 75-125953.10 U190 Lead ug/L10.0 200 75-125938.45194 Nickel ug/L10.0 200 75-125941.90 U189 Silver ug/L10.0 200 75-125942.40 U189 Tin ug/L10.0 200 75-125951.40 U190 Vanadium ug/L10.0 200 75-1259215.9201 Zinc Prepared: 11/07/2016 14:39 Analyzed: 11/15/2016 11:03Matrix Spike Dup (6K07029-MSD1) Source: CZ15796-03 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10.0 200 2075-12598 0.36.80 U195 Arsenic ug/L10.0 200 2075-12591 0.8104286 Barium ug/L1.00 20.0 2075-12595 0.071.6620.7 Beryllium ug/L1.00 20.0 2075-12593 0.60.360 U18.7 Cadmium ug/L10.0 200 2075-12594 0.71.40 U187 Chromium ug/L10.0 200 2075-12594 0.21.65189 Cobalt ug/L10.0 200 2075-12590 0.71.60 U181 Copper ug/L10.0 200 2075-12595 0.23.10 U189 Lead ug/L10.0 200 2075-12593 0.18.45194 Nickel ug/L10.0 200 2075-12595 0.31.90 U189 Silver ug/L10.0 200 2075-12594 0.22.40 U188 Tin ug/L10.0 200 2075-12596 0.81.40 U191 Vanadium ug/L10.0 200 2075-12593 115.9202 Zinc Batch 6K07031 - EPA 3005A Prepared: 11/07/2016 14:43 Analyzed: 11/16/2016 11:18Blank (6K07031-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L2.000.220 U Antimony ug/L3.000.910 U Selenium ug/L1.000.110 U Thallium Prepared: 11/07/2016 14:43 Analyzed: 11/16/2016 11:22LCS (6K07031-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L2.00 200 80-120108215 Antimony ug/L3.00 200 80-120112224 Selenium ug/L1.00 200 80-120108215 Thallium Page 66 of 71 Page 66 of 72 www.encolabs.com QUALITY CONTROL Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 6K07031 - EPA 3005A Prepared: 11/07/2016 14:43 Analyzed: 11/16/2016 11:29Matrix Spike (6K07031-MS1) Source: CZ15795-04 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L2.00 200 75-125950.832191 Antimony ug/L3.00 200 75-1251100.910 U220 Selenium ug/L1.00 200 75-1251070.110 U215 Thallium Prepared: 11/07/2016 14:43 Analyzed: 11/16/2016 11:33Matrix Spike Dup (6K07031-MSD1) Source: CZ15795-04 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L2.00 200 2075-12595 0.20.832191 Antimony ug/L3.00 200 2075-125110 0.080.910 U220 Selenium ug/L1.00 200 2075-125106 10.110 U212 Thallium Prepared: 11/07/2016 14:43 Analyzed: 11/16/2016 11:36Post Spike (6K07031-PS1) Source: CZ15795-04 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L2.00 200 80-1201100.832221 Antimony ug/L3.00 200 80-1201160.456233 Selenium ug/L1.00 200 80-1201100.104220 Thallium Classical Chemistry Parameters - Quality Control Batch 6K08005 - Same Prepared: 11/08/2016 09:41 Analyzed: 11/11/2016 08:10Blank (6K08005-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L104.9 U Cyanide (total) Prepared: 11/08/2016 09:41 Analyzed: 11/11/2016 08:26LCS (6K08005-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 150 85-115101150 Cyanide (total) Prepared: 11/08/2016 09:41 Analyzed: 11/11/2016 08:28Matrix Spike (6K08005-MS1) Source: CZ15795-01 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 150 85-115974.9 U150 Cyanide (total) Prepared: 11/08/2016 09:41 Analyzed: 11/11/2016 08:37Matrix Spike Dup (6K08005-MSD1) Source: CZ15795-01 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10 150 2085-11594 34.9 U140 Cyanide (total) Page 67 of 71 Page 67 of 72 www.encolabs.com QUALITY CONTROL Classical Chemistry Parameters - Quality Control Batch 6K08005 - Same Batch 6K10045 - NO PREP Prepared: 11/10/2016 17:45 Analyzed: 11/10/2016 18:00Blank (6K10045-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L10010U Sulfide Prepared: 11/10/2016 17:45 Analyzed: 11/10/2016 18:00LCS (6K10045-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag mg/L0.10 0.401 80-120880.35 Sulfide Prepared: 11/10/2016 17:45 Analyzed: 11/10/2016 18:00Duplicate (6K10045-DUP1) Source: CZ15795-01 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L100 2510 U10U Sulfide Prepared: 11/10/2016 17:45 Analyzed: 11/10/2016 18:00Matrix Spike (6K10045-MS1) Source: CZ15795-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L100 401 80-1201610 U65J QM-07Sulfide Prepared: 11/10/2016 17:45 Analyzed: 11/10/2016 18:00Matrix Spike Dup (6K10045-MSD1) Source: CZ15795-02 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L100 401 2580-12018 1310 U74J QM-07Sulfide QUALITY CONTROL Chlorinated Herbicides by GC - Quality Control Batch 6K10021 - EPA 3510C Prepared: 11/10/2016 12:55 Analyzed: 11/14/2016 08:17Blank (6K10021-BLK1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.500.28 U 2,4,5-T ug/L0.500.44 U 2,4,5-TP (Silvex) ug/L0.500.27 U 2,4-D ug/L0.500.32 U Dinoseb ug/L0.500.19 U Pentachlorophenol ug/L 2.00 37-134Surrogate: 2,4-DCAA 711.4 Prepared: 11/10/2016 12:55 Analyzed: 11/14/2016 08:43LCS (6K10021-BS1) RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 2.00 24-137941.9 2,4,5-TP (Silvex) Page 68 of 71 Page 68 of 72 www.encolabs.com QUALITY CONTROL Chlorinated Herbicides by GC - Quality Control Batch 6K10021 - EPA 3510C Prepared: 11/10/2016 12:55 Analyzed: 11/14/2016 08:43LCS (6K10021-BS1) Continued RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 2.00 18-134961.9 2,4-D ug/L 2.00 37-134Surrogate: 2,4-DCAA 921.8 Prepared: 11/10/2016 12:55 Analyzed: 11/14/2016 09:09Matrix Spike (6K10021-MS1) Source: AZ07721-01 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 2.00 24-137840.44 U1.7 2,4,5-TP (Silvex) ug/L0.50 2.00 18-134880.27 U1.8 2,4-D ug/L 2.00 37-134Surrogate: 2,4-DCAA 791.6 Prepared: 11/10/2016 12:55 Analyzed: 11/14/2016 09:35Matrix Spike Dup (6K10021-MSD1) Source: AZ07721-01 RPD%RECSourceSpike MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag ug/L0.50 2.00 1924-13790 60.44 U1.8 2,4,5-TP (Silvex) ug/L0.50 2.00 1918-13492 60.27 U1.8 2,4-D ug/L 2.00 37-134Surrogate: 2,4-DCAA 841.7 Page 69 of 71 Page 69 of 72 www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. This compound is a common laboratory contaminant.O-01 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-07 Precision between duplicate matrix spikes of the same sample was outside acceptance limits.QM-11 Surrogate recovery outside acceptance limitsQS-03 The associated continuing calibration verification standard exhibited high bias; since the result is ND, there is no impact. QV-01 The associated continuing calibration verification standard exhibited low bias; the reported result should be considered to be a minimum estimate. QV-02 Page 70 of 71 Page 70 of 72 Page 71 of 72 Page 72 of 72