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HomeMy WebLinkAbout16022_CHT Facility_Pre-Occupancy IAR 2016_11_16 Via Email November 16, 2016 NC DEQ Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attn: Mr. Carolyn Minnich Re: Pre-Occupancy Indoor Air Sampling CHT Brownfields Site 5046 Old Pineville Rd. Charlotte, NC DEQ Brownfields Project No. 16022-12-060 H&H Job No. FDP-035 Dear Carolyn: 1.0 Introduction On behalf of Old Pineville Investments, LLC, Hart & Hickman, PC (H&H) is submitting this report documenting Pre-Occupancy Indoor Air Sampling for the CHT Brownfields site located at 5046 Old Pineville Rd in Charlotte. A site location map is included as Figure 1. The purpose of the indoor air sampling was to satisfy Paragraph 15.d. of the Brownfields agreement which states that the Prospective Developer shall conduct pre-occupancy indoor air sampling in the location of previous soil vapor sample SSVP-3 for a minimum of one additional sampling event. H&H understands that Old Pineville Investments, LLC has recently negotiated a lease for the space where SSVP-3 was formerly located and that occupancy of that space will occur before the end of 2016. A brief description of previous vapor intrusion assessment is provided in Section 2.0, and the methods and results of the indoor air sampling event are provided in Sections 3.0 and 4.0. Ms. Carolyn Minnich November 16, 2016 Page 2 S:\AAA-Master Projects\ForSite Development Partners (FDP)\FDP-035 cht old pineville rd\Post Agreement IA Sampling\Final to Client\Pre-Occupancy IA Report.docx 2.0 Background Information H&H previously collected six sub-slab soil vapor samples at the site in January 2014. The results of the laboratory analysis indicated that only one sample, SSVP-3, contained compound concentrations above DEQ non-residential screening levels. Based upon the results of analysis of the sub-slab samples, H&H collected four indoor air samples from the southern portion of the building in the vicinity of SSVP-3. Sub-slab and indoor air sample locations are shown on Figure 2. The indoor air samples were analyzed for the volatile organic compounds (VOCs) tetrachloroethene (PCE), trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE), trans-1,2- dichloroethene (trans-1,2-DCE), 1,1-dichloroethene (1,1-DCE), vinyl chloride (VC), ethylbenzene, and xylenes. The VOCs selected for analysis included compounds detected above screening levels in the sub-slab samples and their respective daughter products. Results of the laboratory analysis of the indoor air samples did not indicate the presence of compounds above Division of Waste Management (DWM) Non-Residential Indoor Air Screening Levels (IASLs). The sub-slab soil vapor and indoor air samples were collected in accordance with the approved work plan for the activities, and DEQ concurred with the indoor air sample analytes prior to collection. As part of the Brownfields agreement process and following the vapor intrusion assessment activities described above, DEQ raised concerns about the elevated detections limits in sub-slab sample SSVP-3 (due to the presence of elevated levels of PCE, TCE, ethylbenzene and xylenes), and noted that the detection limits for some compounds (benzyl chloride, 1,3-butadiene, chloroform, naphthalene, 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene) were above the DEQ non-residential soil vapor screening levels and were not analyzed for in the indoor air samples. H&H subsequently requested that the laboratory report these compounds in a revised laboratory report for the indoor air sample. The revised report indicated that none of these compounds were detected above DEQ non-residential indoor air screening levels. However, DEQ noted that the analysis for naphthalene did not meet some of the laboratory performance criteria Ms. Carolyn Minnich November 16, 2016 Page 3 S:\AAA-Master Projects\ForSite Development Partners (FDP)\FDP-035 cht old pineville rd\Post Agreement IA Sampling\Final to Client\Pre-Occupancy IA Report.docx and recommended that the naphthalene indoor air data in the area of sub-slab soil vapor sample SSVP-3 be confirmed. Therefore, Paragraph 15.d. of the Brownfields Agreement includes pre- occupancy indoor air sampling in the location of previous sample SSVP-3. In accordance with the Brownfields Agreement, H&H submitted a work plan for pre-occupancy indoor air sampling dated September 1, 2016, and the work plan was approved in an email dated September 6, 2016. The methods of the pre-occupancy indoor air sampling are provided in the following section. 3.0 Pre-Occupancy Indoor Air Sampling 3.1 Indoor Air Sampling Activities On October 6, 2016, H&H collected two indoor air samples (IAS-1 and IAS-2) in the vicinity of previous sub-slab soil vapor sample location SSVP-3. Indoor air sample locations are depicted on Figure 2. The location where the samples were collected is an unconditioned, vacant warehouse space. The indoor air samples were collected with 6-liter Summa canisters connected to an airflow regulator and a 3 ft long sampling cane. The typical height of a Summa canister with an attached airflow regulator is approximately 2 ft above grade and, with the additional 3-foot long sampling cane, the sample intake point is approximately 5 ft above grade (typical breathing zone height). Prior to sample collection, H&H measured the wind direction and selected an exterior background location (BAS-1) located upwind of the site building. The location of the background sample is also shown on Figure 2. The background location Summa canister was also fitted with a regulator and sampling cane so that the sample height is approximately 5 ft above ground level. Following set-up of the background sample canister, the indoor and background sample valves were opened and the samples were collected over an approximate 8-hour period. As part of the sampling effort, H&H measured the air pressure differential between outside air and the interior Ms. Carolyn Minnich November 16, 2016 Page 4 S:\AAA-Master Projects\ForSite Development Partners (FDP)\FDP-035 cht old pineville rd\Post Agreement IA Sampling\Final to Client\Pre-Occupancy IA Report.docx sample locations near the start, middle, and end of the 8-hour sampling period. In addition, exterior wind speed, exterior wind direction, and indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period. The differential pressure and weather data recorded during the indoor air sampling activities is included on Table 1. As indicated on Table 1, outdoor temperatures were in the range of 62 oF to 75 oF during the sample event, and wind was generally out of the north, with wind speed ranging from 7 to 11 mph. The results of differential pressure measurements indicated that there was no differential pressure between outside air and the building. No precipitation occurred during the sampling event. Once the indoor air samples were collected, the canisters were shipped to Con-Test Analytical Laboratory for analysis of VOCs by EPA Method TO-15. In accordance with the approved work plan, the indoor air samples were analyzed for the following compounds: PCE, TCE, cis-1,2-DCE, trans-1,2-DCE, 1,1-DCE, vinyl chloride, ethylbenzene, xylenes, benzyl chloride, 1,3-butadiene, chloroform, naphthalene, 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene. Detection limits below DWM Non-Residential IASLs were attained for each compound. 3.2 Indoor Air Sampling Results A summary of the indoor and background air sample results is provided in Table 2, and the laboratory analytical data are provided in Appendix A. The laboratory analytical results indicate that xylenes were detected in indoor air samples IAS-1 (0.56 µg/m3) and IAS-2 (0.39 µg/m3) at concentrations below the DWM Non-Residential IASL of 87.6 µg/m3. Xylenes were also detected in background air sample BAS-1 (0.57 µg/m3) at a similar concentration. This data indicates that the concentration of xylene detected in the indoor air samples is from an exterior background source and not from vapor intrusion from underlying soil and/or groundwater impacts. No other analyzed compounds, including naphthalene, were detected above laboratory reporting limits in the samples. Ta b l e 1 ( P a g e 1 o f 1 ) Su m m a r y o f W e a t h e r D a t a Fo r m e r C H T F a c i l i t y C h a r l o t t e , N o r t h C a r o l i n a H& H J o b N o . F D P - 0 3 5 Ti m e T e m p e r a t u r e o F Di f f e r e n t i a l P r e s s u r e (i n W a t e r ) T e m p e r a t u r e o F Wi n d Di r e c t i o n Wind Speed (mph)Precipitation (inches) 8: 3 0 N A N A 6 2 N 8 0 . 0 0 12 : 3 0 N A N A 6 3 N 7 0 . 0 0 16 : 0 0 NA N A 7 5 NN E 11 0 . 0 0 Be g i n n i n g 6 2 0 . 0 0 0 Mi d d l e 7 7 0 . 0 0 0 En d 8 1 0 . 0 0 0 Be g i n n i n g 6 2 0 . 0 0 0 Mi d d l e 7 7 0 . 0 0 0 En d 8 1 0 . 0 0 0 No t e s : In f o r m a t i o n f r o m o n - s i t e w e a t h e r s t a t i o n s e t u p b y H & H o n O c t o b e r 6 , 2 0 1 6 d u r i n g i n d o o r a i r s a m p l i n g e v e n t . Po s i t i v e d i f f e r e n t i a l p r e s s u r e i n d i c a t e s t h a t t h e p r e s s u r e o u t s i d e t h e b u i l d i n g w a s h i g h e r t h a n t h e i n s i d e p r e s s u r e . Di f f e r e n t i a l p r e s s u r e a n d t e m p e r a t u r e r e a d i n g s t a k e n f r o m e a c h s a m p l e l o c a t i o n a t t h e b e g i n n i n g , m i d d l e , a n d e n d d u r i n g t h e 8 - h ou r s a m p l e c o l l e c t i o n IA S - 2 S o u t h - C e n t r a l W a r e h o u s e Sa m p l e I D S a m p l e L o c a t i o n In d o o r O u t d o o r BA S - 1 N o r t h W e s t P a r k i n g L o t IA S - 1 S o u t h - C e n t r a l W a r e h o u s e S: \ A A A - M a s t e r P r o j e c t s \ F o r S i t e D e v e l o p m e n t P a r t n e r s ( F D P ) \ F D P - 0 3 5 c h t o l d p i n e v i l l e r d \ P o s t A g r e e m e n t I A S a m p l i n g \ T a b l e . x l s x Table 2 (Page 1 of 1)Hart & Hickman, PC Table 2 (Page 1 of 1) Summary of Indoor and Background Air Analytical Data Former CHT Facility Charlotte, North Carolina H&H Job No. FDP-035 S:\AAA-Master Projects\ForSite Development Partners (FDP)\FDP-035 cht old pineville rd\Post Agreement IA Sampling\Table.xlsx Table 2 (Page 1 of 1) Hart & Hickman, PC Be n z y l C h l o r i d e 1, 3 - B u t a d i e n e Ch l o r o f o r m 1, 1 - D i c h l o r o e t h y l e n e ci s - 1 , 2 - D i c h l o r o e t h y l e n e tr a n s - 1 , 2 - D i c h l o r o t h y l e n e Et h y l b e n z e n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e ( P C E ) Tr i c h l o r o e t h e n e ( T C E ) 1, 2 , 4 - T r i m e t h y l b e n z e n e 1, 3 , 5 - T r i m e t h y l b e n z e n e Vi n y l C h l o r i d e To t a l X y l e n e s IA-1 Vacant Warehouse 12/12/14 TO-15 <0.18 <0.078 <0.17 <0.14 <0.14 <0.14 0.26 <0.18 1.6 0.32 <0.38 <0.38 <0.090 1.34 IA-2 Vacant Warehouse 12/12/14 TO-15 <0.18 <0.078 <0.17 <0.14 <0.14 <0.14 0.23 <0.18 1.1 <0.19 0.30 <0.17 <0.090 1.45 IA-3 Vacant Warehouse 12/12/14 TO-15 <0.18 0.30 <0.17 <0.14 <0.14 <0.14 0.18 <0.18 1.3 <0.19 0.28 <0.17 <0.090 0.97 IA-4 Vacant Warehouse 12/12/14 TO-15 <0.18 0.25 <0.17 <0.14 <0.14 <0.14 0.23 <0.18 0.58 <0.19 0.28 <0.17 <0.090 1.13 IAS-1 Vacant Warehouse 10/06/16 TO-15 <0.18 <0.078 <0.17 <0.14 <0.14 <0.14 <0.15 <0.18 <0.24 <0.19 <0.17 <0.17 <0.090 0.56 IAS-2 Vacant Warehouse 10/06/16 TO-15 <0.18 <0.078 <0.17 <0.14 <0.14 <0.14 <0.15 <0.18 <0.24 <0.19 <0.17 <0.17 <0.090 0.39 BAS-1 Outdoor/Background 12/12/14 TO-15 <0.18 0.26 <0.17 <0.14 <0.14 <0.14 0.34 <0.18 0.35 <0.19 0.30 <0.17 <0.090 1.62 BAS-1 Outdoor/Background 10/06/16 TO-15 <0.18 <0.078 <0.17 <0.14 <0.14 <0.14 <0.15 <0.18 <0.24 <0.19 <0.17 <0.17 <0.090 0.57 0.250 0.409 0.533 175 NE NE 4.91 0.361 35.0 1.75 6.13 NE 2.79 87.6 Notes Bold indicates concentration exceeds DWM Non-Residential Indoor Air Screening Level (October 2016 table) Blue highlighting indicates sample collected during pre-occupancy assessment NA = Not Analyzed NE = Not Established µg/m3 = micrograms per cubic meter LICR = Lifetime Incremental Cancer Risk HI = Non-carcinogenic hazard index µg/m3 DWM Non-Residential Indoor Air Screening Level (LICR = 1 x 10-6 and HI = 0.2) Sa m p l e I D Sa m p l e L o c a t i o n Sa m p l i n g D a t e An a l y t i c a l M e t h o d 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) Charlotte East, NC 2013 Charlotte West, NC 2013 TITLE PROJECT SITE LOCATION MAP Former CHT Facility 5046 Old Pineville Road CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 1-6-2015 0 1 FDP-035 SITE 2 9 2 3 S o u t h T r y o n S t r e e t - S u i t e 1 0 0 C h a r l o t t e , N o r t h C a r o l i n a 2 8 2 0 3 7 0 4 - 5 8 6 - 0 0 0 7 ( p ) 7 0 4 - 5 8 6 - 0 3 7 3 ( f ) L i c e n s e # C - 1 2 6 9 / # C - 2 4 5 G e o l o g y J O B N O . F D P - 0 3 5 R E V I S I O N N O . 0 D A T E : 1 0 - 2 6 - 1 6 F I G U R E N O . 2 5 0 4 6 O L D P I N E V I L L E R O A D C H A R L O T T E , N O R T H C A R O L I N A S U B - S L A B S O I L V A P O R & I N D O O R A I R S A M P L E L O C A T I O N S L E G E N D : S U B J E C T P R O P E R T Y B O U N D A R I E S S H A L L O W M O N I T O R I N G W E L L A B A N D O N E D M O N I T O R I N G W E L L D E E P M O N I T O R I N G W E L L S U B S L A B S O I L V A P O R S A M P L E L O C A T I O N ( 1 / 1 4 ) B A C K G R O U N D & I N D O O R A I R S A M P L E L O C A T I O N ( 1 2 / 1 4 ) P R E - O C C U P A N C Y B A C K G R O U N D & I N D O O R A I R S A M P L E L O C A T I O N ( 1 0 / 1 6 ) S T O R M W A T E R C A T C H B A S I N F O R M E R U S T ( L O C A T I O N S A P P R O X M I A T E ) S:\AAA-Master Projects\ForSite Development Partners (FDP)\FDP-035 cht old pineville rd\Post Agreement IA Sampling\Figures\FIG 2.dwg, FIG 1, 10/26/2016 3:57:05 PM, Appendix A Laboratory Analytical Data 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 October 13, 2016 John Lopez Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: CHT Brownfields Site Client Job Number: Project Number: FDP-035 Laboratory Work Order Number: 16J0351 Enclosed are results of analyses for samples received by the laboratory on October 6, 2016. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lisa A. Worthington Project Manager Page 1 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 10/13/2016Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: John Lopez FDP-035 16J0351 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB CHT Brownfields Site BAS-1 16J0351-01 Ambient Air EPA TO-15 IAS-1 16J0351-02 Indoor air EPA TO-15 IAS-2 16J0351-03 Indoor air EPA TO-15 Page 2 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Continuing calibration did not meet method specifications and was biased on the high side for this compound. Increased uncertainty is associated with the reported value which is likely to be biased on the high side. Analyte & Samples(s) Qualified: Benzyl chloride B160571-BS1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Project Manager Page 3 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: CHT Brownfields Site Date Received: 10/6/2016 Work Order: 16J0351Sample Description/Location: Field Sample #: BAS-1 Sample ID: 16J0351-01 Sample Matrix: Ambient Air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -7.2 Sampled: 10/6/2016 16:05 Canister ID: 1181 Flow Controller ID: 3010 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlagRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL Benzyl chloride ND 0.035 10/9/16 21:00 CMRND0.7020.180.0068 1,3-Butadiene ND 0.035 10/9/16 21:00 CMRND0.7020.0780.018 Chloroform ND 0.035 10/9/16 21:00 CMRND0.7020.170.0082 1,1-Dichloroethylene ND 0.035 10/9/16 21:00 CMRND0.7020.140.0086 cis-1,2-Dichloroethylene ND 0.035 10/9/16 21:00 CMRND0.7020.140.013 trans-1,2-Dichloroethylene ND 0.035 10/9/16 21:00 CMRND0.7020.140.0093 Ethylbenzene ND 0.035 10/9/16 21:00 CMRND0.7020.150.0097 Naphthalene ND 0.035 10/9/16 21:00 CMRND0.7020.180.019 Tetrachloroethylene ND 0.035 10/9/16 21:00 CMRND0.7020.240.010 Trichloroethylene ND 0.035 10/9/16 21:00 CMRND0.7020.190.010 1,2,4-Trimethylbenzene ND 0.035 10/9/16 21:00 CMRND0.7020.170.0086 1,3,5-Trimethylbenzene ND 0.035 10/9/16 21:00 CMRND0.7020.170.0070 Vinyl Chloride ND 0.035 10/9/16 21:00 CMRND0.7020.0900.015 m&p-Xylene 0.093 0.070 10/9/16 21:00 CMR0.40 0.7020.300.018 o-Xylene 0.039 0.035 10/9/16 21:00 CMR0.17 0.7020.150.010 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)95.0 10/9/16 21:0070-130 Page 4 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: CHT Brownfields Site Date Received: 10/6/2016 Work Order: 16J0351Sample Description/Location: Field Sample #: IAS-1 Sample ID: 16J0351-02 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29.5 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -7.2 Sampled: 10/6/2016 16:23 Canister ID: 2074 Flow Controller ID: 3174 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlagRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL Benzyl chloride ND 0.035 10/9/16 21:47 CMRND0.7020.180.0068 1,3-Butadiene ND 0.035 10/9/16 21:47 CMRND0.7020.0780.018 Chloroform ND 0.035 10/9/16 21:47 CMRND0.7020.170.0082 1,1-Dichloroethylene ND 0.035 10/9/16 21:47 CMRND0.7020.140.0086 cis-1,2-Dichloroethylene ND 0.035 10/9/16 21:47 CMRND0.7020.140.013 trans-1,2-Dichloroethylene ND 0.035 10/9/16 21:47 CMRND0.7020.140.0093 Ethylbenzene ND 0.035 10/9/16 21:47 CMRND0.7020.150.0097 Naphthalene ND 0.035 10/9/16 21:47 CMRND0.7020.180.019 Tetrachloroethylene ND 0.035 10/9/16 21:47 CMRND0.7020.240.010 Trichloroethylene ND 0.035 10/9/16 21:47 CMRND0.7020.190.010 1,2,4-Trimethylbenzene ND 0.035 10/9/16 21:47 CMRND0.7020.170.0086 1,3,5-Trimethylbenzene ND 0.035 10/9/16 21:47 CMRND0.7020.170.0070 Vinyl Chloride ND 0.035 10/9/16 21:47 CMRND0.7020.0900.015 m&p-Xylene 0.093 0.070 10/9/16 21:47 CMR0.40 0.7020.300.018 o-Xylene 0.038 0.035 10/9/16 21:47 CMR0.16 0.7020.150.010 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.5 10/9/16 21:4770-130 Page 5 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: CHT Brownfields Site Date Received: 10/6/2016 Work Order: 16J0351Sample Description/Location: Field Sample #: IAS-2 Sample ID: 16J0351-03 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -7.5 Receipt Vacuum(in Hg): -7.6 Sampled: 10/6/2016 16:24 Canister ID: 2068 Flow Controller ID: 3173 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlagRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL Benzyl chloride ND 0.035 10/9/16 22:35 CMRND0.7020.180.0068 1,3-Butadiene ND 0.035 10/9/16 22:35 CMRND0.7020.0780.018 Chloroform ND 0.035 10/9/16 22:35 CMRND0.7020.170.0082 1,1-Dichloroethylene ND 0.035 10/9/16 22:35 CMRND0.7020.140.0086 cis-1,2-Dichloroethylene ND 0.035 10/9/16 22:35 CMRND0.7020.140.013 trans-1,2-Dichloroethylene ND 0.035 10/9/16 22:35 CMRND0.7020.140.0093 Ethylbenzene ND 0.035 10/9/16 22:35 CMRND0.7020.150.0097 Naphthalene ND 0.035 10/9/16 22:35 CMRND0.7020.180.019 Tetrachloroethylene ND 0.035 10/9/16 22:35 CMRND0.7020.240.010 Trichloroethylene ND 0.035 10/9/16 22:35 CMRND0.7020.190.010 1,2,4-Trimethylbenzene ND 0.035 10/9/16 22:35 CMRND0.7020.170.0086 1,3,5-Trimethylbenzene ND 0.035 10/9/16 22:35 CMRND0.7020.170.0070 Vinyl Chloride ND 0.035 10/9/16 22:35 CMRND0.7020.0900.015 m&p-Xylene 0.090 0.070 10/9/16 22:35 CMR0.39 0.7020.300.018 o-Xylene ND 0.035 10/9/16 22:35 CMRND0.7020.150.010 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.8 10/9/16 22:3570-130 Page 6 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 16J0351-01 [BAS-1]B160571 1.5 1 N/A 1000 400 855 10/09/16 16J0351-02 [IAS-1]B160571 1.5 1 N/A 1000 400 855 10/09/16 16J0351-03 [IAS-2]B160571 1.5 1 N/A 1000 400 855 10/09/16 Page 7 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B160571 - TO-15 Prep Blank (B160571-BLK1)Prepared & Analyzed: 10/09/16 0.035NDBenzyl chloride 0.035ND1,3-Butadiene 0.035NDChloroform 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035NDEthylbenzene 0.035NDNaphthalene 0.035NDTetrachloroethylene 0.035NDTrichloroethylene 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)95.47.63 LCS (B160571-BS1)Prepared & Analyzed: 10/09/16 5.00 V-0670-1301256.26Benzyl chloride 5.00 70-1301206.021,3-Butadiene 5.00 70-13085.54.28Chloroform 5.00 70-1301035.161,1-Dichloroethylene 5.00 70-13080.94.04cis-1,2-Dichloroethylene 5.00 70-13083.74.18trans-1,2-Dichloroethylene 5.00 70-13092.64.63Ethylbenzene 5.00 70-13096.34.82Naphthalene 5.00 70-13096.34.82Tetrachloroethylene 5.00 70-13081.64.08Trichloroethylene 5.00 70-1301055.241,2,4-Trimethylbenzene 5.00 70-1301035.141,3,5-Trimethylbenzene 5.00 70-1301246.21Vinyl Chloride 10.0 70-13094.89.48m&p-Xylene 5.00 70-13095.34.77o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)96.87.74 Page 8 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 FLAG/QUALIFIER SUMMARY *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Continuing calibration did not meet method specifications and was biased on the high side for this compound. Increased uncertainty is associated with the reported value which is likely to be biased on the high side. V-06 Page 9 of 13 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,VA,MEBenzyl chloride AIHA,NJ,NY,VA,ME1,3-Butadiene AIHA,FL,NJ,NY,VA,MEChloroform AIHA,FL,NJ,NY,VA,ME1,1-Dichloroethylene AIHA,FL,NY,VA,MEcis-1,2-Dichloroethylene AIHA,NJ,NY,VA,MEtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,VA,MEEthylbenzene NY,MENaphthalene AIHA,FL,NJ,NY,VA,METetrachloroethylene AIHA,FL,NJ,NY,VA,METrichloroethylene AIHA,NJ,NY,ME1,2,4-Trimethylbenzene AIHA,NJ,NY,ME1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,VA,MEVinyl Chloride AIHA,FL,NJ,NY,VA,MEm&p-Xylene AIHA,FL,NJ,NY,VA,MEo-Xylene The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2005AIHA 02/1/2018 M-MA100Massachusetts DEPMA 06/30/2017 PH-0567Connecticut Department of Publilc HealthCT 09/30/2017 10899 NELAPNew York State Department of HealthNY 04/1/2017 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2017 LAO00112Rhode Island Department of HealthRI 12/30/2016 652North Carolina Div. of Water QualityNC 12/31/2016 MA007 NELAPNew Jersey DEPNJ 06/30/2017 E871027 NELAPFlorida Department of HealthFL 06/30/2017 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2017 2011028State of MaineME 06/9/2017 460217Commonwealth of VirginiaVA 12/14/2016 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2017 Page 10 of 13 Page 11 of 13 Page 12 of 13 Page 13 of 13