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HomeMy WebLinkAbout4304_CentralCarolinaTire_Phase3_Oct2016_2ndSemiAnnual_DIN27002_20161026 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com Explanatory Text for Notification Table Central Carolina Tire Monofill Landfill Phase III Cameron, Harnett, NC Permit # 43-04 October 3, 2016 Water Quality Monitoring The results of the October 2016 groundwater and surface water quality monitoring conducted at the Central Carolina Tire Monofill Landfill are generally consistent with the results of previous monitoring conducted at the site. No RCRA metals were reported in the surface water sample at concentrations that exceed the 15A NCAC 2L .0202 groundwater quality standards or the 15A NCAC 2B surface water quality standards. In addition, no Appendix I VOCs were detected in the surface water sample. Acetone was detected at trace levels well below the 15A NCAC 2L groundwater quality standard in the groundwater samples collected from monitoring wells MW-12 (4.2 µg/L, estimated) and MW-17AR (5 µg/L). No other Appendix I VOCs were reported in any of the groundwater samples. The concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR (21 µg/L) exceeds the 15A NCAC 2L groundwater quality standard of 10.0 µg/L. It is noted, however, that the turbidity of the groundwater sample collected from MW-17AR was significantly elevated (647.4 NTUs). The October 2016 monitoring event is the first event in over 10 years of monitoring in which chromium has been reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at the location of MW-17/17AR. Therefore, it is concluded that the elevated concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR in October 2016 is the result of significantly elevated sample turbidity. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com October 26, 2016 Ms. Elizabeth S. Werner, Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 1646 Mail Service Center Raleigh, NC 27699-1646 RE: Report of Results Semi-Annual Groundwater and Surface Water Monitoring: October 2016 Central Carolina Tire Monofill Landfill Phase III Cameron, Harnett County, NC Permit # 43-04 Dear Ms. Werner: This report presents the results of semi-annual groundwater and surface water quality monitoring conducted at the landfill site referenced above (Figure 1) in October 2016. The scope of work performed included sampling and laboratory analysis of groundwater samples from eight on-site monitoring wells (MW-10 through MW-14 and MW-16 through MW-18) and one surface water sample (SW-1 (EXP)). It is noted that monitoring well MW-17 was abandoned on August 30, 2011 and replaced with monitoring well MW-17AR in accordance with the facility Water Quality Monitoring Plan submitted as part of the Application for Permit Amendment 5-Year Phase (2011-2016) prepared by Garrett & Moore, Inc. The Water Quality Monitoring Plan was approved by the NCDEQ, Division of Waste Management (DWM), Solid Waste Section (SWS), in a letter to Central Carolina Tire Holdings, LLC dated August 10, 2011. The groundwater and surface water samples were collected in accordance with the NCDEQ, DWM, SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document and the facility Water Quality Monitoring Plan. The sampling and data collection methods, as well as the current and historical results of field and laboratory testing of the water samples, are presented in the following sections. – 2 – October 26, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com 1.0 POTENTIOMETRIC PATTERN AND GROUNDWATER FLOW Groundwater levels were gauged in the site groundwater monitoring wells on October 3, 2016 as part of the site monitoring. Depths to groundwater were measured using an electronic water level probe that was thoroughly decontaminated between wells with a non-phosphate soap and water wash followed in order by multiple rinses with distilled water, an isopropyl alcohol rinse, and multiple distilled water rinses. Depth to groundwater measurements were made after the wells were opened for a sufficient period of time to allow water levels to equilibrate with atmospheric pressure. The locations of the site monitoring wells are depicted in Figure 2. Groundwater elevation data collected at the monitoring wells on October 3, 2016 are presented in Table 1. The depth to groundwater across the site, as measured in the Type II groundwater monitoring wells on October 3, 2016, ranged from 0.97 feet (MW-12) to 16.48 feet (MW- 16) below grade, which is consistent with the surface topography. A water-table elevation contour map that was developed based on the October 3, 2016 groundwater-gauging data for the Type II monitoring wells is presented as Figure 3. The pattern of the water-table contours indicates that the horizontal component of shallow groundwater flow at the site is generally to the southeast, which is consistent with the surface topography and drainage features at the site. The hydraulic gradient of the water table across the site, based on the data depicted in Figure 3, varies from approximately 0.003 ft/ft in the northern part of the site to 0.012 ft./ft. in the southeastern part of the site. 2.0 RESULTS OF GROUNDWATER AND SURFACE WATER SAMPLING AND ANALYSIS Groundwater samples were collected from the site monitoring wells and a surface water sample was collected from the on-site location on October 3, 2016 for laboratory analysis to monitor the quality of groundwater and surface water at the site. The groundwater and surface water samples were collected and handled in accordance with the sampling protocols included in the site Water Quality Monitoring Plan as well as the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document. It is noted that monitoring well MW-10 serves as the upgradient, natural background well for the facility, and monitoring wells MW-11 through MW-14 and MW-16 through MW-18 serve as the downgradient monitoring wells. All reusable sampling equipment was – 3 – October 26, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com properly decontaminated between sampling locations with a non-phosphate soap and water wash, followed by multiple rinses with distilled water. New disposable nitrile or latex gloves were worn during all sampling activities. Disposable sampling equipment/material was discarded after each use. Prior to groundwater sampling, all monitoring wells were purged using pre-cleaned Teflon-lined disposable polyethylene tubing connected to a peristaltic pump under low flow conditions. During purging, measurements were made in the field of the pH, temperature, specific conductance and turbidity of the groundwater collected from the monitoring wells, in accordance with SWS requirements. The results of the field analyses of these parameters are presented in Table 1. Copies of Groundwater Sampling Forms containing pertinent information recorded in the field during purging and sampling at each groundwater monitoring well are presented in Appendix A. The results of the field-measured water-quality parameters indicate that the values measured in groundwater collected from the site monitoring wells, with the exception of turbidity at MW-17AR and MW-18, were generally within the applicable stabilization criteria (see Groundwater Sampling Forms). Groundwater at the site is acidic to moderately acidic based on the pH values measured in the field (4.27 to 5.09). Specific conductance values ranged from 16 (MW-13) to 173 (MW-10) µS/cm in groundwater. Turbidity values ranged from 5.08 (MW-11) to 647.4 (MW-17AR) NTUs. A surface water sample was collected from monitoring location SW-1 (EXP), which is located approximately 280 feet southeast of the planned limits of scrap tire disposal along the primary drainage feature that bisects the southeastern portion of the Phase III landfill footprint. The sampling location is depicted in Figure 2. The surface water sample was collected in accordance with the protocol presented in the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling Document. All groundwater and surface water samples were analyzed at a North Carolina-certified laboratory for Appendix I volatile organic compounds (VOCs) by SW 846 Method 8260 and the 8 RCRA metals by EPA 6000/7000 series methods. Summarized results of laboratory analyses for groundwater and surface water samples collected from the site on October 3, 2016 are presented in Table 2. Summarized historical groundwater and surface water quality data for the site are presented in Table 3. Copies of the original laboratory reports are included in Appendix B. – 4 – October 26, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com The laboratory analytical results for the surface water sample (SW-1 (EXP)) collected from the site indicate that no Appendix I VOCs were reported in the sample. Low levels of arsenic, barium, cadmium, lead, and selenium were reported in surface water sample SW-1 (EXP), however, the reported concentrations were well below the corresponding 15A NCAC 2L groundwater quality standards and the 15A NCAC 2B surface water standards applicable to the site. The laboratory analytical results for the groundwater samples collected from the site monitoring wells on October 3, 2016 indicate that acetone was detected at trace levels well below the 15A NCAC 2L groundwater quality standard in the samples collected from monitoring wells MW-12 (4.2 µg/L, estimated) and MW-17AR (5 µg/L). No other Appendix I VOCs were reported in any of the groundwater samples. The results of the metals analyses of the groundwater samples indicate that arsenic was reported in five of the samples, barium, cadmium, and lead were reported in all of the samples, chromium was reported in four of the samples, mercury was not reported in any of the samples, and selenium and silver were each reported in two of the samples. The concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR (21 µg/L) exceeds the 15A NCAC 2L groundwater quality standard of 10.0 µg/L. It is noted, however, that the turbidity of the groundwater sample collected from MW-17AR was significantly elevated (647.4 NTUs). The October 2016 monitoring event is the first event in over 10 years of monitoring in which chromium has been reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at the location of MW-17/17AR. Therefore, it is concluded that the elevated concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR in October 2016 is the result of significantly elevated sample turbidity. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. Monitoring wells MW-17AR and MW-18 will be redeveloped before the next scheduled semiannual monitoring event to clear the wells of excess sediment. 3.0 CONCLUSIONS AND RECOMMENDATIONS The results of the October 2016 groundwater and surface water quality monitoring conducted at the Central Carolina Tire Monofill Landfill are generally consistent with the results of previous monitoring conducted at the site. No RCRA metals were reported in the surface water sample at concentrations that exceed the 15A NCAC 2L .0202 – 5 – October 26, 2016 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com groundwater quality standards or the 15A NCAC 2B surface water quality standards. In addition, no Appendix I VOCs were detected in the surface water sample. Acetone was detected at trace levels well below the 15A NCAC 2L groundwater quality standard in the groundwater samples collected from monitoring wells MW-12 (4.2 µg/L, estimated) and MW-17AR (5 µg/L). No other Appendix I VOCs were reported in any of the groundwater samples. The concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR (21 µg/L) exceeds the 15A NCAC 2L groundwater quality standard of 10.0 µg/L. It is noted, however, that the turbidity of the groundwater sample collected from MW-17AR was significantly elevated (647.4 NTUs). The October 2016 monitoring event is the first event in over 10 years of monitoring in which chromium has been reported at a concentration in excess of the 15A NCAC 2L groundwater quality standard at the location of MW-17/17AR. Therefore, it is concluded that the elevated concentration of chromium reported in the groundwater sample collected from monitoring well MW-17AR in October 2016 is the result of significantly elevated sample turbidity. None of the other reported concentrations of metals detected in any of the groundwater samples exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. If you have any questions or require further assistance regarding this report, please call me at 919-995-0363. The next water quality monitoring event for the Central Carolina Tire Monofill Landfill is scheduled for April 2017. Sincerely, Brian S. Boutin, P.G. Consulting Geologist Cc: Tim McNeil, Central Carolina Holdings, Inc. Vance Moore, Garrett and Moore, Inc. Craig Fortner, Garrett & Moore, Inc. Drawn by: Reviewed by: Drawing #: Drawing Date: 1 SITE LOCATION MAP Central Carolina Tire Monofill Landfill Harnett County, North Carolina Source: USGS 7.5’ Topographic Quadrangle Series Murchisontown, NC 2010 Figure No. Project #: Scale: USGS 1:24,000 05/31/2012 N 11112 Branding Iron Place Wendell, NC 27591 Office: (919) 366-3663 Cell: (919) 995-0363 Central Carolina Tire 334 335 336 337 338 338 339 339 340 340 341 341 34 2 34 2 3 4 3 34 3 3 4 4 3 4 4 (343.78) (340.49) (333.48) (333.98) (339.49) (344.11) (346.38) (339.11) MW-10 27.0 2.0 356.28 353.74 12.50 343.78 21.4 5.09 173 6.22 MW-11 23.8 2.0 347.80 345.70 7.31 340.49 22.4 4.39 36 5.08 MW-12 21.6 2.0 336.58 334.45 3.10 333.48 24.0 4.29 25 16.8 MW-13 20.6 2.0 339.47 337.36 5.49 333.98 21.8 4.44 16 5.77 MW-14 12.6 2.0 344.12 341.86 4.63 339.49 22.9 4.87 29 9.66 MW-16 28.9 2.0 362.53 360.59 18.42 344.11 20.8 4.32 48 6.54 MW-17AR 20.0 2.0 352.99 350.70 6.61 346.38 22.9 4.54 55 647.4 MW-18 14.8 2.0 344.71 342.45 5.60 339.11 23.1 4.27 38 108.6 Notes:MSL = Mean Sea Level BTOC = Below Top of Casing GW = Groundwater S.C. = Specific Conductance ntu = Nephelometric Turbidity Units Monitoring well construction data taken from October-December 2006 Sampling Event Monitoring Report prepared by Withers & Ravenel. Well Diameter (Inches) Field Parameters Turbidity (ntu) Ground Surface Elevation (Feet MSL) Groundwater Elevation (Feet MSL) Depth to Groundwater (Feet BTOC) Top of Casing Elevation (Feet MSL) Monitoring Well and Groundwater Data Table 1 October 2016 Sampling Event Central Carolina Tire Monofill Landfill Phase III Harnett County, North Carolina Well Identity Temp. Co October 3, 2016 Well Depth (Feet BTOC)pH S.C. umhos/cm Permit # 43-04 ORGANIC CONSTITUENTS GWP Std NCAC 2L STD (ug/L)(ug/L)(ug/L) Acetone ND ND ND 4.2 J ND ND ND 5 ND NE 6000 Acrylonitrile ND ND ND ND ND ND ND ND ND NE NE Benzene ND ND ND ND ND ND ND ND ND NE 1 Bromochloromethane ND ND ND ND ND ND ND ND ND 0.6 NE Bromodichloromethane ND ND ND ND ND ND ND ND ND NE 0.6 Bromoform (Tribromoethane)ND ND ND ND ND ND ND ND ND NE 4 Bromomethane (Methyl Bromide)ND ND ND ND ND ND ND ND ND 10 10 2-Butanone (MEK), (Methyl Ethyl Ketone)ND ND ND ND ND ND ND ND ND NE 4000 Carbon Disulfide ND ND ND ND ND ND ND ND ND NE 700 Carbon Tetrachloride ND ND ND ND ND ND ND ND ND NE 0.3 Chlorobenzene ND ND ND ND ND ND ND ND ND NE 50 Chloroethane (Ethyl Chloride)ND ND ND ND ND ND ND ND ND NE 3000 Chloroform (Trichloromethane)ND ND ND ND ND ND ND ND ND NE 70 1,2-Dibromo-3-Chloropropane (DBCP)ND ND ND ND ND ND ND ND ND NE 0.04 Dibromochloromethane (Chlorodibromomethane)ND ND ND ND ND ND ND ND ND 0.41 0.4 1,2,-Dibromoethane (Ethylene Dibromide)ND ND ND ND ND ND ND ND ND NE 0.02 Dibromomethane (Methylene Bromide)ND ND ND ND ND ND ND ND ND 5.5 70 1,2-Dichlorobenzene (O-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 20 1,3-Dichlorobenzene (M-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 200 1,4-Dichlorobenzene (P-Dichlorobenzene)ND ND ND ND ND ND ND ND ND NE 6 Trans-1,4-Dichloro-2-butene ND ND ND ND ND ND ND ND ND NE NE 1,1-Dichloroethane ND ND ND ND ND ND ND ND ND NE 6 1,2-Dichloroethane (Ethylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.4 1,1-Dichloroethene (Vinylidene Chloride)ND ND ND ND ND ND ND ND ND NE 7 1,2-Dichloroethene (cis and trans isomers)ND ND ND ND ND ND ND ND ND 60 60 1,2-Dichloropropane (Propylene Dichloride)ND ND ND ND ND ND ND ND ND NE 0.6 1,1-Dichloropropene ND ND ND ND ND ND ND ND ND NE NE 1,3-Dichloropropene (cis and trans isomers)ND ND ND ND ND ND ND ND ND NE 0.4 Ethylbenzene ND ND ND ND ND ND ND ND ND NE 600 Iodomethane (Methyl Iodide)ND ND ND ND ND ND ND ND ND NE NE 2-Hexanone (Methyl Butyl Ketone)ND ND ND ND ND ND ND ND ND NE 280 Methyl Chloride (Chloromethane)ND ND ND ND ND ND ND ND ND NE 3 Methylene Chloride (Dichloromethane)ND ND ND ND ND ND ND ND ND NE 5 4-Methyl-2-Pentanone (Methyl Isobutyl Ketone)ND ND ND ND ND ND ND ND ND 560 NE Styrene ND ND ND ND ND ND ND ND ND NE 70 1,1,1,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 1 1 1,1,2,2-Tetrachloroethane ND ND ND ND ND ND ND ND ND 0.18 0.2 Tetrachloroethene (Tetrachloroethylene), (PCE)ND ND ND ND ND ND ND ND ND NE 0.7 Toluene ND ND ND ND ND ND ND ND ND NE 600 1,1,1-Trichloroethane (Methylchloroform)ND ND ND ND ND ND ND ND ND NE 200 1,1,2-Trichloroethane ND ND ND ND ND ND ND ND ND 0.6 0.6 Trichloroethene (Trichloroethylene), (TCE)ND ND ND ND ND ND ND ND ND NE 3 Trichlorofluoromethane (CFC-11) ND ND ND ND ND ND ND ND ND NE 2000 1,2,3-Trichloropropane ND ND ND ND ND ND ND ND ND NE 0.005 Vinyl Acetate ND ND ND ND ND ND ND ND ND 88 88 Vinyl Chloride ND ND ND ND ND ND ND ND ND NE 0.03 Total Xylenes ND ND ND ND ND ND ND ND ND NE 500 INORGANIC CONSTITUENTS GWP Std NCAC 2L STD (in ug/L)(ug/L)(ug/L) Arsenic 0.67 J 0.69 J ND 3.6 ND 0.31 J ND 5.3 0.70 J NE 10 Barium 28 50 28 9.5 4.1 J 27 58 39 20 NE 700 Cadmium 0.049 J 0.45 J 0.069 J 0.042 J 0.10 J 0.12 J 0.059 J 0.11 J 0.062 J NE 2 Chromium ND 2.0 ND 2.2 ND ND ND 21 3.6 NE 10 Lead 0.39 J 0.17 J 0.32 J 0.50 J 0.29 J 0.44 J 0.57 J 13 2.0 NE 15 Mercury ND ND ND ND ND ND ND ND ND NE 1 Selenium 1.2 5.2 ND ND ND ND ND 0.50 J ND NE 20 Silver ND ND ND ND ND ND ND 0.28 J 0.064 J NE 20 Notes: Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standard for Class GA groundwater.J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. NCAC 2L STD = North Carolina Groundwater Standard established in Title 15A of North Carolina Administrative Code Subchapter 2L B = Analyte found in associated field and/or laboratory blank. GWP Std = Solid Waste Section Groundwater Protection Standard NE = No standard established. ND = None detected above laboratory method detection limit. Table 2 SW-1 (EXP)MW-13 MW-14 Central Carolina Tire Monofill Landfill Phase III, Harnett County, NC Laboratory Results for Surface Water and Groundwater Samples October 3, 2016 October 2016 Sampling Event MW-16 Permit # 43-04 NS = Not Sampled, No sample exists for this sampling period MW-17ARMW-11 MW-18MW-10 MW-12 Page 1 of 2 Sampling Date:2L Standard 10/24/07 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-10 Arsenic 10 ND ND 1.91 J 2.25 J ND ND 1.5 J ND ND 1.40 1.90 1.80 ND 1.10 ND 1.60 0.77 J 0.64 J 0.69 J Barium 700 78.0 J 39.2 JB 53.8 JB 63.3 JB 27.8 JB 22.0 0.17 J 32.0 25.0 33.0 17.0 40.0 18.0 29.0 39.0 29.0 40.0 36 50 Cadmium 2 ND ND ND ND ND ND 0.69 J ND ND ND ND 0.094 J ND 0.049 J ND ND 0.052 J 0.086 J 0.45 JChromium101.46 J 2.47 JB 1.45 JB 3.01 JB 2.86 JB 0.55 J ND ND 8.4 BJ ND 2.7 B ND ND ND ND 0.26 J 0.51 J ND 2.0Lead155.11 J 4.90 J ND ND ND 0.71 J ND ND 0.95 J 0.21 J 0.28 J 0.2 J 0.26 J 0.33 J ND 0.18 J 0.32 J 0.26 J 0.17 J Mercury 1 ND ND ND 0.281 J ND ND ND ND 0.019 J ND ND ND 0.18 J 0.34 0.15 J 1.80 0.23 1.70 ND Selenium 20 ND ND ND ND ND ND 10.00 ND ND 7.20 6.50 7.70 2.00 3.80 3.50 8.60 6.00 8.4 5.2 Silver 20 ND 2.37 JB 3.41 JB ND ND ND ND ND 0.45 J ND 0.18 J ND ND 0.056 J ND ND ND ND NDAcetone6000ND1.83 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDBromoform4NDNDNDNDNDNDNDNDNDNDNDNDNDND1.10 ND ND ND ND Trichloroethene 3 ND ND ND 0.380 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene 600 ND ND 5.54 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-11 Arsenic 10 2.59 J ND ND 2.43 J ND ND ND ND ND ND ND ND 0.37 J ND ND ND ND 0.48 J NDBarium70019.5 J 55.1 JB 44.6 JB 60.5 JB 29.6 JB 65.0 51.0 33.0 25.0 27.0 28.0 28.0 29.0 63.0 23.0 55.0 43.0 54.0 28Cadmium2NDNDNDNDNDND2.1 ND 0.27 J ND ND 0.061 J 1.4 ND ND ND 0.14 J 0.16 J 0.069 J Chromium 10 1.31 J 6.94 JB 1.35 JB 3.99 JB 3.42 JB ND 1.5 J ND 7.2 B ND 2.8 B 1.1 B ND ND ND ND 0.64 J 0.54 J ND Lead 15 ND 10.60 ND 5.01 JB ND ND 0.81 J ND 0.89 J 0.30 J 0.38 J 0.37 J 0.88 J 0.20 J 0.21 J 0.22 J 0.60 J 0.69 J 0.32 J Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.86 1.20 NDSelenium20NDNDNDNDNDNDNDND0.47 J 0.70 J 1.00 0.62 J ND ND ND ND 0.83 J 0.98 J NDSilver20ND2.03 JB 3.91 JB 1.49 JB 1.56 JB ND ND ND 0.33 J ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.830 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-12 Arsenic 10 ND 2.32 J ND 3.00 J ND ND ND ND 0.12 J 0.38 J ND ND 2.70 0.83 J 14.00 0.63 J 2.10 4.00 3.6 Barium 700 97.8 J 46.2 JB 23.8 JB 56.2 JB 24.8 JB 5.7 J 11 J 14.0 16.0 15.0 13.0 15.0 17.0 9.0 22.0 8.9 15.0 11.0 9.5Cadmium2NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.18 J 0.088 J 0.042 JChromium103.04 J 11.6 B 3.25 JB 7.16 JB 4.08 JB 1.6 J 2 J ND 5.60 ND 3.6 B 1.6 B 0.95 J 0.47 J 2.40 1.30 5.70 3.90 2.2 Lead 15 ND 6.31 J 4.80 J 9.68 JB ND 0.81 J 2 J ND 0.62 J 0.64 J 0.96 J 0.41 J 1.70 0.49 J 1.60 0.90 J 2.40 1.70 0.50 J Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.12 J ND ND Selenium 20 ND 7.32 J ND ND ND ND ND ND ND ND ND 0.34 J ND ND ND ND ND 0.72 J NDSilver20ND1.93 JB 4.01 JB 1.82 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 0.013 J NDAcetone6000NDNDNDNDNDNDNDNDNDNDNDNDNDND6.60 ND ND ND 4.2 J Chloroform 70 0.150 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.390 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (MEK)4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 9.80 ND ND ND NDToluene600ND0.510 JB 0.510 JB ND ND ND ND ND ND ND ND ND ND ND 4.5 ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-13Arsenic 10 3.79 J ND ND ND ND 3.1 J ND ND ND ND 0.60 J ND 0.50 J ND ND ND ND ND ND Barium 700 9.36 J 19.8 JB 14.9 JB 18.5 JB 8.7 JB 7.4 J 4.8 J 6.3 J 7.5 3.9 J 6.0 7.1 11.0 4.5 J 4.2 J 4.9 J 13.0 7.0 4.1 J Cadmium 2 ND ND ND ND ND ND ND 0.19 J ND ND ND ND ND ND ND ND 0.10 J 0.089 J 0.10 J Chromium 10 3.26 J 3.07 JB ND 3.60 JB 3.05 JB 2.1 J 1.3 J ND 3.6 B ND 2.6 B 1.1 B ND ND ND ND 1.50 ND NDLead15ND8.32 J 4.75 J 7.51 JB ND ND ND ND 0.41 J 0.24 J 0.21 J 0.18 J 0.83 J 0.12 J 0.26 J ND 1.1 0.27 J 0.29 JMercury1NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.068 J ND ND Selenium 20 ND ND ND ND ND ND ND ND ND ND ND 0.36 J ND ND ND ND ND ND ND Silver 20 ND 2.88 JB 3.65 JB 1.12 JB 0.78 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform 4 ND ND ND ND 0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-14 Arsenic 10 3.12 J ND ND 2.50 J ND ND 1.9 J ND ND 0.12 J 0.30 J ND ND ND ND ND ND ND 0.31 J Barium 700 113.0 180 B 185 B 177 B 159 B 130.0 91.0 110.0 87.0 110.0 100.0 80.0 67.0 38.0 26.0 28.0 42.0 34.0 27 Cadmium 2 ND ND ND ND 0.22 J ND 0.34 J ND ND ND ND 0.18 J 0.27 J ND ND ND 0.074 J 0.097 J 0.12 JChromium101.46 J 4.86 JB 1.77 JB 3.80 JB 5.02 JB 0.9 J 1.6 J ND 6.9 B ND 2.4 B 1.2 B ND ND ND ND 0.80 J 0.51 J NDLead153.62 J 8.51 J 5.06 J 3.74 JB 8.24 J 1.7 J 1.7 J 1.4 J 1.80 1.60 1.70 0.82 J 1.10 0.43 J 0.035 J 0.22 J 0.94 J 0.27 J 0.44 J Mercury 1 ND ND ND ND ND ND ND ND 0.019 J ND ND ND ND ND ND ND ND ND ND Selenium 20 ND ND ND ND ND ND ND ND ND ND ND 0.80 J ND 0.16 J ND ND ND ND ND Silver 20 ND 1.99 JB 3.11 JB 1.29 JB ND ND ND ND ND ND ND 0.12 J ND ND ND ND ND ND NDAcetone60008.25 JB ND ND ND ND ND ND ND ND ND ND ND ND ND 15.00 ND ND ND NDBromoform4NDNDNDND0.18 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-16 Arsenic 10 1.86 J ND ND 4.76 JB ND ND ND ND 0.67 J ND 0.41 J ND 0.44 J ND ND ND ND 0.47 J ND Barium 700 8.81 J 69.8 JB 31.1 JB 28.8 JB 16.3 JB 27.0 19 J 24.0 38.0 33.0 31.0 38.0 48.0 41.0 42.0 35.0 37.0 37.0 58 Cadmium 2 ND ND ND ND ND ND 0.66 J ND ND ND ND 0.14 J 0.037 J ND ND ND 0.053 J 0.11 J 0.059 JChromium10ND3.07 JB 1.87 JB 3.99 JB 2.76 JB 1.0 J 1.5 J ND 8.7 B ND 2.5 B 1.2 B ND ND ND ND 0.83 J 0.63 J NDLead15ND8.15 J ND 4.74 JB ND 1.1 J ND ND 0.66 J 0.41 J 0.55 J 0.55 J 0.97 J 0.49 J 0.49 J 0.37 J 0.56 J 0.71 J 0.57 J Mercury 1 ND ND 0.114 J ND ND ND ND 0.092 J 0.17 J ND ND ND ND 0.028 J 0.15 J ND 0.46 0.45 ND Selenium 20 ND ND ND ND 2.9 J ND ND ND 0.48 J 0.97 J 0.69 J 0.24 J ND ND ND ND ND 0.42 J ND Silver 20 ND 1.66 JB 4.10 JB 1.85 JB 0.86 JB ND ND ND ND ND ND ND ND ND ND ND ND ND NDAcetone6000ND2.42 JB ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDBromoform4NDNDNDND1.06 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane 0.4 ND ND ND ND 0.25 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.560 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NOTES: Results in parts per billion (ppb) ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007). NA - Not analyzed for or not available Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel. J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. B = Analyte found in associated field and/or laboratory blank. Table 3 Historical Summary of Constituent Detections Central Carolina Tire Monofill Landfill Phase III Permit # 43-04 Harnett County, North Carolina Page 2 of 2 Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/27/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16Well No:MW-17AR* Arsenic 10 ND ND ND 5.63 J ND ND ND ND ND ND ND ND 0.46 J 0.95 J ND ND ND 0.75 J 5.3Barium70091.7 J 71.9 JB 89.5 JB 56.4 JB 68.6 JB 35.0 41.0 41.0 90.0 30.0 120.0 130.0 110.0 25.0 110.0 150.0 110.0 37.0 39Cadmium2NDNDNDNDNDNDNDNDNDND0.24 J 0.17 J 0.086 J ND 0.093 J ND 0.11 J 0.094 J 0.11 J Chromium 10 1.76 J 2.47 JB ND 3.90 JB 2.58 JB ND 1.6 J ND 4.90 ND 2.6 B 1.2 B ND 2.30 0.32 J 1.10 1.50 2.50 21 Lead 15 ND 5.88 J ND ND ND ND ND ND 1.00 1.30 1.70 1.40 1.50 1.90 2.00 1.90 2.10 1.40 13 Mercury 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDSelenium20NDNDNDNDNDNDNDNDND0.76 J 0.72 J 0.51 J ND ND ND ND ND 0.52 J 0.50 JSilver20ND2.26 JB 4.19 JB 1.51 JB 0.84 JB ND ND ND ND ND ND 0.041 J ND ND ND ND ND 0.017 J 0.28 J Acetone 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.0 Bromoform 4 ND ND ND ND 0.27 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND Methylene Chloride 5 ND ND 0.450 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDToluene600NDNDNDNDNDNDNDND0.58 ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/15/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:MW-18 Arsenic 10 4.49 J ND ND 2.22 J ND ND ND ND ND 0.34 J 0.60 J ND 0.37 J 0.51 J ND ND 0.84 J ND 0.70 J Barium 700 26.3 J 43.1 JB 43.8 JB 48.6 JB 48.4 JB 41.0 41.0 46.0 41.0 40.0 41.0 39.0 57.0 31.0 46.0 43.0 55.0 59.0 20Cadmium2NDNDNDNDNDNDND0.23 J ND ND ND ND 0.050 J 0.039 J ND ND 0.081 J 0.11 J 0.062 JChromium10ND2.32 JB 1.25 JB 3.90 JB 3.51 JB ND 1.5 J ND 4.70 ND 2.5 B 1.0 B ND ND ND 0.38 J 0.63 J 0.60 J 3.6 Lead 15 4.04 J 4.07 J ND 6.38 JB ND 0.96 J 2.3 J ND 0.56 J 0.47 J 0.53 J 0.50 J 0.77 J 0.56 J 0.61 J 0.45 J 0.84 J 0.94 J 2.0 Mercury 1 ND ND ND ND ND ND ND ND ND ND ND 0.39 0.37 0.029 J 0.26 0.14 J 0.014 J ND ND Selenium 20 ND ND ND ND ND ND ND ND ND 0.67 J 0.75 J 0.92 J ND 0.22 J ND 1.90 4.20 0.79 J NDSilver20ND2.07 JB 3.72 JB 1.69 JB 0.95 JB ND ND ND ND ND ND ND ND ND ND ND ND 0.038 J 0.064 J 60 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.75 ND ND Methylene Chloride 5 ND ND 0.910 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND Sampling Date:2L Standard 10/24/07 4/29/08 10/14/08 4/23/09 10/14/09 4/29/10 10/19/10 4/13/11 10/5/11 4/26/12 10/3/12 4/3/13 10/16/13 4/2/14 10/1/14 4/8/15 10/1/15 4/13/16 10/3/16 Well No:SW-1(Exp) Arsenic 10 4.32 J ND ND 1.96 J ND ND ND ND 0.79 J 0.23 J ND ND ND ND ND ND 0.35 J 0.59 J 0.67 J Barium 700 36.2 J 44.4 JB 17.9 JB 21.7 JB 10.5 JB 12.00 9.5 J 13.00 33.00 21.00 21.00 26.00 43.00 34.00 30.00 43.00 33.00 45.00 28Cadmium2NDNDNDNDNDND0.2 J ND ND 0.31 J ND ND ND ND ND ND 0.049 J 0.10 J 0.049 JChromium101.61 J 1.73 JB ND 2.71 JB 2.58 JB ND 1.3 J ND 8.30 ND 4.7 B 1.4 B ND ND ND ND 0.68 J 0.79 J ND Lead 15 4.88 J 6.43 J ND 4.49 JB ND 0.76 J ND 0.83 J 7.50 0.95 J 0.44 J ND 1.10 0.27 J 0.35 J ND 0.43 J 1.10 0.39 J Mercury 1 ND ND ND ND ND ND ND ND 0.23 ND ND ND ND ND ND ND ND ND ND Selenium 20 ND ND ND ND ND ND ND ND 0.79 J 1.10 1.00 0.68 J ND 0.22 J ND 1.40 0.86 J 0.36 J 1.2Silver20ND2.53 JB 3.75 JB 1.66 JB 0.98 JB ND ND ND ND 0.22 J ND ND ND ND ND ND ND 0.018 J NDStyrene700.260 J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NOTES: Results in parts per billion (ppb) ND - Not Detected above the laboratory method detection limit or practical quantitation limit (results prior to April 2007).* - Monitoring well MW-17 was abandoned on August 30, 2011 to make way for landfill expansion NA - Not analyzed for or not available and was replaced by monitoring well MW-17AR located outside the expansion footprint. Values in boldface exceed the corresponding 15A NCAC 2L .0202 groundwater quality standards. Results for sampling conducted prior to April 2007 as presented in previous GW reports prepared by Withers & Ravenel. J = Estimated value above laboratory method detection limit and below SWSL or reporting limit. B = Analyte found in associated field and/or laboratory blank. Table 3 (Continued) Historical Summary of Constituent Detections Central Carolina Tire Monofill Landfill Phase III (Planned) Permit # 43-04 1,2-Dichloroethene (cis and trans isomers) Harnett County, North Carolina 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com APPENDIX A Groundwater Sampling Forms EFM E IPMENT CALIBRATION FORM (:.i:)i (-t i, Proiect#: C C -T/ ,&:_ INSTRUMENT: Y LT- S;-; SERIAL NO.: INSTRUMENT:(/l :,,t SERIAL NO.: Calibration Recorded Bv 1f{- rri :ft L Lol#,\'zt/ r ?',-., Lot#('zr>a/ /.718 mS Lot# ?/li6(-r, Exp: {/ I 7 Lot# ;-6' ,€--lq.Exp'. f / t Calibration Recorded Bv f2_ EFM E IPMENT CALIBRATION FORM Project #:a(lGlient: ,// ori, i , INSTRUMENT:'57 3 s( SERIAL NO.: o 9 6/ ffi-l d3 0(,39o INSTRUMENT: SERIAL NO.: Calibration Recorded /o"3 t(Lot# i:i t J44 "€;'aa't Lour.66t-o,'3 : oJ st-/"t/o-3-tl JO-J /I Lot#(ity/q, Exp: g !- J/-,t' Calibration Recorded Client: NAUTILUS Project No: CENTRAL Site Location: CAMERON, conds: ( ''i^l^- t Date: -lolJttoTime: Start C>? t 0 am/pm Finish olS-f srnTpt NA TIRE, PERMIT #4304 Water Sample Collection Record Well/Piezo lD:*1w.'l'i Well 6f Piezometer E e. Length of Water Cotumn 7. F 1 6-ny f. Calculated Well Volume (see back) I . 3 WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA a. Purge Method Comments from Top of Casing) c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW ned (from workplan)b. Acceptance Criteria - Minimum Required - Maximum Allowable - Stabilization of c. Field Testing Eq d. Field Testing e. Acceptance criteria Has required volume Has required turbidity Have parameters lf no or N/A -below. SAMPLE COLLECTION:Method: Peristaltic Pump Volume (@ _well volumes) _ N/A pumping Rate: i CO milminN/A NTUs----------Td o/o t Used: Make Model Serial Number 556 ,1 )zrot3cJ- Calibration Documentation Found on Separate Form removed reached No N/Atrtrrt]ntr Signature Date _1013 l$ Client; NAUTILUS Project No: CENTRAL Conds: i'u rva.-w ? Date: -lot-J t16 Time: Start lc ( l- am/pm Finish lcS-.o am/pm 4304- ^Ai"\/ 1 2 Qa Water Sample Collection Record ,rr t Lr,^/ -( Well *F4 Piezometer I e. Lengthof WaterOolumn lSl c I (a-O) f. Calculated Well Volume (see back) ,? " f WATER LEVEL DATA: a- Total Well Length b. Water Table Depth WELL PURGING DATA from Top of Casing) C c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW 10 o/o a. Purge Method b. Acceptance Criteria - Minimum Required - Maximum Allowable rbidity NiA NTUs (from workplan) Volume (@ _well volumes) _ N/A Pumping Rate: 4 c C' milmin - Stabilization of c. Field Testing Eq Used: Make ModelYSI 556 Serial Numbere9/,:t e 13c,T- Has required volume Has required turbidity removed reached No N/AunDNutr Comments d. Field Testing nt Calibration Documentation Found on Separate Form e. Acceptance criteria YesE-&,+Have parameters lfnoorN/A-E below SAMPLE COLLECTION:Method: Peristaltic Pump Signature Client NAUTILUS Project No: CENTRAL Site Location: CAMERON ther Conds: -.fvrvN Date: _ tol.3 lt6 Time: Start [too amipm Finish ['z i 5-- amipm \/La/':_ TIRE. PERMIT #4304 4304- t\:la r.\ WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA Comments l1c c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW .Qt v nd Water Sample Collection Record from Top of Gasing) ID:/i\(/,/ - I : Well tr Piezometer I e. Length of Water Column ( 3-.- f o 1a-n; f. Calculated Well Volume (see back) -3 . t: Serial Number a. Purge Method b. Acceptance Criteria - Minimum Required - Maximum Allowable urbidity N/A NTUs - Stabilization of 10 o/o c. Field Testing Used: Make Model d. Field Testing e. Acceptance criteria Has required volume removed Has required been reached Have parameters lfnoorN/A-E below SAMPLE GOLLECTION:Peristaltic Pump (from workplan) Volume (@ _ well volumes) _ N/A Pumping Rate: 1 o e, ml/min. YSI 556 c..^l [ lc: ( :j a.l.' Calibration Documentation Found on Separate Form No N/Aunnt]Nt] Yes #d- Signature -;=Date _ 10/-tr /16 Client: NAUTILUS Project No: CENTRAL Location: CAMERON, Date: _ 1Ol-3 /16 1;ms; Start i-2: { srnTprn Finish t3 3C amlpm Volume Removed ml lG.Cr(: tr'\h '' {1 nd Water Sample Gollection Record WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA from Top of Casing) c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW ned (from workplan) removed reached 1r, V Q. Well .S piezometer fl e. Leni;th of Water Cotumn : :J 7 \ 1a-01 f. Calculated Well Volume (see back) .{ " 3 a. Purge Method b. Acceptance Criteria - Minimum Required - Maximum Allowable idity N/A NTUs"s 10%- Stabilization of c. Field Testing Used: Make ModelYSt 556 d. Field Testing Eq t Calibration Documentation Found on Separate Form e. Acceptance criteria Has required volume Has required Have parameters lf no or N/A -below. SAMPLE COLLECTION:Method: Peristaltic Pump Comments Yesa -@--w Volume (@ _ weil volumes) _ N/A Pumping *r," 'ZC C milmin. Serial Number c''i /,:-r e/ 3 cJ' No N/Anntrtrntr YutrJ f/ta Signature Q nt-, Date _flJ trc r' F lt'r' Client: NAUTILUS Project No: CENTRAL Location: CAMERON, condt' -f .*t-' ,'-' Dale: - rc] 7, 116 Time: Start i3ir7 am/pm p1n;s6 lTFlamipm 4 INA TIRE, PERMIT #4304 nd Water Sample Collection Record wXur/ l,* Well $- Piezometer ITe. Lengjtn of Water Column '\ . L t, from Top of Casing) 9 c. Casing Material PVC d. Casing Diamete t 2"f. Calculated Well Volume (see back) / LOW FLOW lized in below Method: Peristaltic Pump WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA a. Purge Method (a-b) (- b. Acceptance Criteria (efined (from workplan) - Minimum Required f urge Volume (@ _ well volumes)N/A Pumping nate i 7C mtlmin - Maximum Allowable]Turbidity N/A NTUs - Stabilization of Dararneters --------7d vo d. Field Testing Calibration Documentation Found on Separate Form e. Acceptance criteria Has required volume removed Has required been reached Yes No N/Afrtr!Ent]EntrHave parameters lf no or N/A - SAMPLE COLLECTION: V Date: 10/ 'j /16 Time: Start I Y"9f "t/ptFinish l51fO amipm Client NAUTILUS Location: CAME WeatherConds: \'ursr-.i Collecto(s) -\l-; WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW 44 nd Water Sample Collection Record from Top of Casing)Well tr 7yt1i,t/ - i \ Piezometer I e. Length of WaterColumn t 6 ...2'7 ta-O) f. Calculated Well Volume (see back) e -1 Serial Number,)kr<:t.7cJ- a. Purge Method b. Acceptance Criteria - Minimum Required - Maximum Allowable Turbidity N/A NTUsneters 10 %- Stabilization of c. Field Testing Used:Make (from workplan) Volume (@ _ well volumes) _ N/A PumpingRate: / e C milmin. d. Field Testing E Calibration Documentation Found on Separate Form e. Acceptance criteria Has required volume removed Has required been reached Have parameters lfnoorN/A-E SAMPLE COLLECTION:Method: Peristaltic Pump Comments No N/AntrtrnNt] Yes+w.w Signature Date fit3 nG No: CENTRAL Location: CAMERON Weather Condst J;,*iv INA TIRE, PERMIT #4304 Date: _10/-? /i6 Time: Start r'{.c'l am/pm----=a-Finish I {-S C' am/pm Collector(s) {E/a-- AL<-t.-{ I Gro nd Water Sample Collection Record WATER LEVEL DATA: { a. Total Well Length b. Water Table Depth from Top of Casing) c. Casing Material PVC d. Casing Diamete r 2" removed reached Well d= Piezometer I e. te/gtn of Water Cotumn 1- ? j 1"-01 f. Calculated Well Volume (see back) t , 4 t'- 1 2t WELL PURGING DATA a. Purge Method LOW FLOW b. Acceptance Criteria - Minimum Required - Maximum Allowable - Stabilization of c. Field Testing d. Field Testing Eq e. Acceptance criteria Has required volume Has required Have parameters lf no or N/A -below SAMPLE COLLEGTION: Comments (from workplan) Volume (@ _ well volumes) _ N/A Pumping Rate: ,C,C' mt/min.ity N/A NTUs 1A Yo Used: Make Model Serial Number No N/Annutrntr YSI 556 C'il.-rcl!cJ- t Calibration Oo"rr"n,"t,offi Yes6&p Method: Peristaltic Pump Signature Date _tot3 n6 Client: NAUTILUS iect No: CENTRAL Site Location: CAMERON WeatherConds: f! l:' *t,r,t Dale: - 1Ol 'a 116 Time: Start ('? O -< amtpm rinish llcfb am/pm INA TIRE, PERMIT #4304 4304- ft,l tlv ( A WATER LEVEL DATA: a. Total Well Length b. Water Table Depth WELL PURGING DATA a. Purge Method te nd Water Sample Collection Record from Top of Casing) c. Casing Material PVC d. Casing Diamete r 2" LOW FLOW L'\',-(c *".u w Piezometer I e. Len$th of Water Column lT'eN 6-o1 f. Calculated Well Volume (see back) ,Q . \ Pumping Rate: /6 C) mymin Serial Number b. Acceptance Criteria - Minimum Required - Maximum Allowable - Stabilization of c. Field Testing rge Volume (@ _well volumes) -- N/Aurbidity NIA NTUsrters 10 To Make c'lA 556-TtYSI d. Field Testing e. Acceptance crlteria Has required volume removed Has required been reached Have parameters lf no or N/A -below SAMPLE GOLLECTION: Comments Calibration Documentation Found on Separate Form Yes.A @w Method: Peristaltic Pump No N/Autrnnntr Signature -4t Date _ 1Ol.? 116 11112 BRANDING IRON PLACE, WENDELL, NC 27591 919-366-3663 Office ● 919-995-0363 Cell ● nautilusgeocon@gmail.com APPENDIX B Laboratory Reports And Chain-of-Custody Records Page 1 of 59 Page 2 of 59 Page 3 of 59 Page 4 of 59 Page 5 of 59 Page 24 of 59 Page 25 of 59 Page 26 of 59 Page 27 of 59 Page 28 of 59 Page 29 of 59 Page 30 of 59 Page 31 of 59 Page 32 of 59 Page 33 of 59 Page 34 of 59 Page 35 of 59 Page 36 of 59 Page 37 of 59 Page 38 of 59 Page 39 of 59 Page 40 of 59 Page 41 of 59 Page 42 of 59 Page 43 of 59 Page 44 of 59 Page 45 of 59 Page 46 of 59 Page 47 of 59 Page 48 of 59 Page 49 of 59 Page 50 of 59 Page 51 of 59 Page 52 of 59 Page 53 of 59 Page 54 of 59 Page 55 of 59 Page 56 of 59 Page 57 of 59 Page 58 of 59 Page 59 of 59