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HomeMy WebLinkAbout4407_HaywoodCoMSWLF_GWMR_DIN26866_20160707 BLE BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS REPORT OF GROUNDWATER QUALITY RESULTS & STATISTICAL ANALYSIS FIRST SEMI-ANNUAL SAMPLING EVENT OF 2016 WHITE OAK LANDFILL PERMIT NUMBER: 44-07 HAYWOOD COUNTY, NORTH CAROLINA Prepared For: HAYWOOD COUNTY SOLID WASTE MANAGEMENT 278 Recycle Road Clyde, North Carolina 28721 Prepared By: BUNNELL-LAMMONS ENGINEERING, INC. 6004 Ponders Court Greenville, South Carolina 29615 July 7, 2016 BLE Project Number J16-1957-55 BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICAL, ENVIRONMENTAL AND CONSTRUCTION MATERIALS CONSULTANTS 6004 PONDERS COURT PHONE (864) 288-1265 GREENVILLE, SOUTH CAROLINA 29615 FAX (864) 288-4430 July 7, 2016 Haywood County Solid Waste Management 278 Recycle Road Clyde, North Carolina 28721 Attention: Mr. David B. Francis Solid Waste and Tax Administrator Subject: Report of Groundwater Quality Results & Statistical Analysis First Semi-Annual Sampling Event of 2016 White Oak Landfill Permit Number: 44-07 Haywood County, North Carolina BLE Project Number J16-1957-55 Dear Mr. Francis: As authorized, Bunnell-Lammons Engineering, Inc. (BLE) has performed the statistical analysis of groundwater quality data obtained during the first semi-annual sampling event of 2016 for the White Oak Municipal Solid Waste (MSW) and Construction and Demolition (C&D) Landfills. The enclosed report describes the work performed and presents the results obtained with our conclusions. The purpose of this work was to statistically compare the laboratory analytical results of groundwater samples from the background monitoring wells to the downgradient monitoring wells at the subject landfill in accordance with Title 15A NCAC 13B .1632 (g), (h), and (i). This report of the sampling and statistical analysis has been prepared for submittal to the North Carolina Division of Waste Management (NCDWM) in accordance with Rule 15A NCAC 13B .1632 (j). We appreciate the opportunity to serve as your geological consultant on this project and look forward to working with you on future projects. If you have any questions, please contact us at (864) 288-1265. Sincerely, BUNNELL-LAMMONS ENGINEERING, INC. Trevor J. Benton, P.G. Mark S. Preddy, P.G. Project Geologist Senior Geologist Licensed, North Carolina No. 2025 Licensed, North Carolina No. 1043 cc: Mr. Ervin Lane – NCDEQ Solid Waste Section, 401 Oberlin Road, Suite 150, Raleigh, North Carolina 27605 White Oak Landfill – Haywood Co., NC July 7, 2016 First Semi-Annual Sampling Event of 2016 BLE Project Number J16-1957-55 2 PROJECT INFORMATION The White Oak Landfill site is located in Haywood County, North Carolina, approximately twelve miles north of the city of Waynesville on White Oak Road at Exit 15 off Interstate 40 (Figure 1). The Subtitle D lined MSW landfill has eleven groundwater monitoring wells consisting of two upgradient (MW-11S and MW-11D) and nine downgradient wells (MW-1A, MW-2, MW-2D, MW- 3r, MW-3Dr, MW-4A, MW-8, MW-16, and MW-17). Monitoring wells MW-5A, MW-5D, MW- 12, MW-13S, and MW-13D were abandoned in 2009 and monitoring wells MW-16 and MW-17 were installed in 2010 as related to the construction of Phase No. 3 at the facility. Additionally, there are four surface water sampling points (SW-1, SW-2, SW-3, and SW-5), and a leachate lagoon sampling point (LSP). The C&D landfill, which is located on the same property, is monitored by one upgradient (MW-14), one downgradient well (MW-15), and two locations for surface water monitoring (SW-6 and SW-7). BLE was retained by Santek Waste Services, Inc. to prepare the semi-annual sampling reports for 2016. Historical data from multiple sources and in multiple formats were gathered and synthesized into this report. Water quality data available to BLE extends back to April 1993; however, many of the currently existing wells were not present during the earlier sampling events. As a result, the statistical database in this report uses data from sampling events ranging from April 2000 to the current sampling event (April 2016). This report presents data from the first semi-annual sampling event in 2016 for the site. The water samples were collected and analyzed as required in North Carolina's regulations for operation of MSW and C&D landfills. FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected by personnel from Pace Analytical Services, Inc. (Pace) of Asheville, North Carolina on April 18 - 19, 2016. Sampling was performed in general accordance with the Operations Plan for the White Oak Landfill. Summary tables of historic and current analytical results are attached in Appendix A (groundwater) and Appendix B (surface water). Water samples were collected from the monitoring wells, surface water points, and the LSP. The collected samples were analyzed in the laboratory for North Carolina’s Appendix I list of constituents that include total metals and volatile organic compounds (VOCs) and in the field for pH, specific conductance, turbidity, and temperature. A copy of the Pace laboratory and field data is included in Appendix C. GROUNDWATER FLOW The water level data collected during the groundwater sampling is presented in Table 1. A water table surface elevation contour map is presented as Figure 2 along with generalized groundwater White Oak Landfill – Haywood Co., NC July 7, 2016 First Semi-Annual Sampling Event of 2016 BLE Project Number J16-1957-55 3 flow directions. Flow velocity calculations are provided on Table 2. Please note, hydraulic conductivity and effective porosity values for the existing wells were obtained from prior reports prepared by other consultants. SUMMARY OF LABORATORY RESULTS Groundwater Concentrations of total barium (thirteen wells), total chromium (two wells), total cobalt (five wells), total copper (two wells), total nickel (seven wells), total thallium (one well), total vanadium (two wells), and total zinc (one well) were detected in the groundwater monitoring wells during the current sampling event. Total barium (MW-2 and MW-2D) and total chromium (MW-11S) were detected at concentrations above the North Carolina maximum contaminant level1 (MCL). Additionally, no VOCs were detected during the sampling event. Surface Water Concentrations of total metals were detected in each of the six surface water samples and the LSP sample during the current sampling event. The detections included total antimony (LSP), total barium (six surface waters and the LSP), total chromium (LSP), total cobalt (LSP), total nickel (LSP), total vanadium (LSP) and total zinc (SW-2). No VOCs were detected in the samples from the surface water locations or the LSP sample. Additionally, phosphorus, nitrate, nitrite, sulfate, BOD, and COD were detected in the LSP sample. None of the detected concentrations exceeded an established North Carolina established surface water MCL2. STATISTICAL METHODS PERFORMED The purpose of performing statistical analysis of groundwater quality data is to determine if a release of leachate has occurred from the landfill cells to the groundwater at the site. The US EPA has prepared a guidance document for evaluating groundwater quality data titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities – Unified Guidance (March 2009). The procedures and methodology used for data analysis of this project are consistent with this US EPA guidance document, and meet or exceed the performance criteria specified in the North Carolina solid waste management rules Title 15A NCAC 13B .1632(g-i). Four methods of statistical analysis were performed depending on the number of detected concentrations and the distribution of the data for a specific compound, as follows: 1. If 15% to 90% of the data were not detected, the one-way non-parametric analysis of variance (ANOVA) Kruskal-Wallis rank-sum test was performed; 1 North Carolina Department of Environment and Natural Resources (NCDENR), Classifications of Water Quality Standards, Section 15A NCAC 2L.202, April 1, 2013. 2 North Carolina Department of Environment and Natural Resources, “Redbook”, Surface Waters and Wetlands Standards, Section 15A NCAC 02B.0100, .0200, and .0300, May 1, 2007. White Oak Landfill – Haywood Co., NC July 7, 2016 First Semi-Annual Sampling Event of 2016 BLE Project Number J16-1957-55 4 2. If less than 15% of the data were not detected, and if the data was normally distributed and homogeneous, then one-way parametric ANOVA was performed. If the data were not normally distributed and homogeneous, then a non-parametric type test was used (Kruskal- Wallis); 3. Alternatively, if greater than 50% of the data were not detected, Poisson Prediction Limits may be performed, or if less than 50% of the data were not detected, Normal Prediction Limits may be performed. Wilcoxon rank-sum tests were performed for those compounds that failed the initial Poisson Prediction Limits test; and 4. Intrawell comparisons were performed, if necessary, using Shewhart-CUSUM control charts or the Kendall-Mann Non-Parametric Trend Test. It is important to note that the nature of the statistical procedures applied to the data frequently leads to false positives, which result in statistically significant increases (SSI). These false positives are inherent to the statistical procedures themselves and are a result of the insufficiency of the mathematical equations to represent the multiple factors affecting the groundwater quality variability at a given site. Furthermore, a clear distinction should be made between the terms “calculated SSI” and “validated SSI.” A calculated SSI is the result of the application of mathematical equations to evaluate variability of water quality data over time by mathematical means. A validated SSI is determined when, based on a review of the data set as a whole, it can be concluded that the calculated statistical significance might be a function of a release of leachate to groundwater, and not a function of natural variability and/or other conditions. SUMMARY OF STATISTICAL RESULTS The statistical analysis was performed on constituents that have been historically detected and that were detected during the current sampling event. The statistical results summarized on Table 3 and included in Appendix D indicate that: 1. The Poisson Prediction Limit and Wilcoxon tests performed for total antimony, total arsenic, total selenium, total silver, total thallium, acetone, carbon disulfide, chloroethane, iodomethane, dichloromethane, and 2-butanone did not calculate SSIs; and 2. The Kruskal-Wallis tests and Shewhart-CUSUM control charts did not calculate SSIs for total beryllium, total cadmium, total chromium, total cobalt, total copper, total lead, total vanadium, and total zinc; however, the tests calculated SSIs for total barium (MW-2 and MW-2D) and total nickel (MW-3Dr). CONCLUSION Concentrations of various total metals were detected in the groundwater monitoring wells and surface water sampling points during the current sampling event. Only the concentrations of total White Oak Landfill – Haywood Co., NC July 7, 2016 First Semi-Annual Sampling Event of 2016 BLE Project Number J16-1957-55 5 barium (MW-2 and MW-2D) and total chromium (MW-11S) were detected at concentrations exceeding North Carolina MCLs. The remaining detected concentrations were either below North Carolina’s promulgated MCLs, or MCLs have not been established for a particular constituent. Additionally, only total barium in wells MW-2 and MW-2D and total nickel in well MW-3Dr were calculated to be statistically significant; these metals are naturally occurring elements in the soil and bedrock throughout North Carolina and are not necessarily a derivative of landfill leachate. In summary, the detected concentrations of total metals in the groundwater and surface water samples are most likely naturally occurring and related to sample turbidity. Metal cations typically adsorb to the surface of platy particles (clay and silt). Therefore, turbidity of the groundwater and surface water samples will relate to detected concentrations of the metal cations. Consequently, the metal concentrations detected should be considered natural background concentrations. We recommend that sampling continue on a semi-annual basis for the Appendix I list of VOCs and total metals constituents. TABLES TABLE 1 GROUNDWATER MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 April 19, 2016 Northing Easting Meas. Pt.Gnd. Surface *Depth to Depth to Water Total Borehole Screen Well Well Top of Rock Top of Well (feet)(feet)Elevation Elevation Water (bgs)Water (bmp)Elevation Depth (bgs)Depth (bgs)Type Monitors Depth (bgs)Rock Elev. MW-1A 721,096.30 812,481.47 2,520.02 2,517.97 16.25 18.30 2,501.72 UK 10.4 -25.4 2,507.6 -2,492.6 UK Deep Residuum UK UK MW-2 721,460.76 812,309.44 2,496.71 2,494.43 27.06 29.34 2,467.37 UK 19.9 -34.9 2,474.5 -2,459.5 UK Deep Residuum/PWR UK UK MW-2D 721,456.01 812,311.87 2,496.89 2,494.69 27.10 29.30 2,467.59 UK 44.6 -54.6 2,450.1 -2,440.1 UK Bedrock 36.9 2,457.8 MW-3r 721,943.38 812,063.70 2,462.61 2,459.53 27.61 30.69 2,431.92 41.5 26.3 -41.3 2,433.2 -2,418.2 II Deep Residuum NE NE MW-3Dr 721,940.67 812,082.82 2,461.89 2,458.42 32.51 35.98 2,425.91 65.0 49.8 -64.8 2,408.6 -2,393.6 IIIs Bedrock 44.0 2,414.4 MW-4A 721,693.04 811,976.64 2,493.85 2,491.60 42.01 44.26 2,449.59 UK 80.6 -95.6 2,411.0 -2,396.0 UK Bedrock 23.3 2,468.3 MW-8 721,704.50 812,155.03 2,477.33 2,474.84 27.53 30.02 2,447.31 UK 31.0 -41.0 2,443.8 -2,433.8 UK Deep Residuum UK UK MW-11S 719,905.88 811,642.89 2,674.58 UK UK 82.25 2,592.33 UK UK -UK UK -UK UK UK UK UK MW-11D 719,909.34 811,651.55 2,674.89 2,672.01 80.28 83.16 2,591.73 UK 118.0 -127.6 2,554.0 -2,544.4 UK Bedrock 97.0 2,575.0 MW-14 UK UK 2,711.69 UK UK 100.61 2,611.08 UK UK -UK UK -UK UK UK UK UK MW-15 UK UK 2,547.41 UK UK 9.14 2,538.27 UK UK -UK UK -UK UK UK UK UK MW-16 721,821.98 811,660.70 2,519.35 2,516.07 31.70 34.98 2,484.37 41.0 25.8 -40.8 2,490.3 -2,475.3 II Fill / Residuum 40.0 2,476.1 MW-17 721,783.47 811,219.93 2,542.55 2,539.13 52.92 56.34 2,486.21 63.0 43.0 -58.0 2,496.1 -2,481.1 II Bedrock 40.0 2,499.1 Notes: All survey data provided by McGill Associates, all units in feet. Data for MW-14 & MW-15 sourced from historical Municipal Engineering reports.Measuring Point Elevation is top of casing. *DTW from bgs values have been calculated from survey data provided by McGill Associates.II = Type II well All values shown to the nearest 0.1-ft have been rounded.IIIs = Type III screened well Water levels were measured on 4-19-16 by Pace Analytical.NE = Not encountered MW-4A was lowered 4.59 feet by Haywood County. All bgs referenced depths for MW-4A have been adjusted accordingly on this table.UK = Unknown, information is not available Screen Elevation Table 1 GWM of 1957-55 White Oak GW Stats 1st 2016 Prepared by: IAI Checked by: DPO cm/sec ft/min ft/day MW-1A 1.50E-04 2.95E-04 4.25E-01 0.0789 0.114 0.29 107.35 MW-2 1.50E-04 2.95E-04 4.31E+00 0.0789 0.114 2.98 1,086.93 MW-4A 1.49E-04 2.93E-04 4.28E+00 0.1000 0.05 8.55 3,121.78 MW-8 1.50E-04 2.95E-04 4.31E+00 0.0789 0.114 2.98 1,086.93 MW-11S 2.40E-06 4.72E-06 6.89E-02 0.0851 0.114 0.05 18.76 MW-14 1.38E-05 2.72E-05 3.96E-01 0.0664 0.17 0.15 56.49 MW-15 2.10E-05 4.13E-05 6.03E-01 0.0664 0.17 0.24 85.96 Notes: 1. Hydraulic conductivity and effective porosity values are from prior site hydrogeologic studies performed by others. 2. Hydraulic gradients and flow velocities calculated from measurements taken during the October 26, 2015 sampling event. 3. Groundwater flow velocities calculated using the equation V = Ki/ne where 4. V = velocity 5. K = hydraulic conductivity 6. i = hydraulic gradient 7. ne = effective porosity 8. NA = information not available TABLE 2 GROUNDWATER FLOW DATA White Oak Landfill Haywood County, North Carolina Hydraulic Conductivity BLE Project Number J16-1957-55 Monitoring Well Local Hydraulic Gradient (ft/ft) Flow Velocity (ft/yr) Flow Velocity (ft/day) Effective Porosity Table 2 of 1957-55 White Oak GW Stats 1st 2016 Prepared by: IAI Checked by: DPO TABLE 3 SUMMARY OF STATISTICAL ANALYSIS RESULTS White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Chemical/Percent Primary Primary Secondary Secondary SSI SSI Validated SSI Concentration Above MCL Compound ND Statistical Test Pass/Fail Statistical Test Pass/Fail Calculated as Leachate During Current Event Total Antimony 98%Poisson Prediction Limits Pass ----- Total Arsenic 92%Poisson Prediction Limits Pass ----- Total Barium 4%Prediction Limits Fail Shewhart-CUSUM Fail MW-2, MW-2D (3)No (3)Yes (MW-2, MW-2D) Total Beryllium 88%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Cadmium 88%Kruskal-Wallis Pass ----- Total Chromium 59%Kruskal-Wallis Pass ----- Total Cobalt 65%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Copper 64%Kruskal-Wallis Pass ----- Total Lead 78%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Total Nickel 46%Kruskal-Wallis Fail Shewhart-CUSUM Fail MW-3Dr No No Total Selenium 99%Poisson Prediction Limits Pass ----- Total Silver 99%Poisson Prediction Limits Pass ----- Total Thallium 94%Poisson Prediction Limits Fail Wilcoxon Pass --- Total Vanadium 60%Kruskal-Wallis Pass ----- Total Zinc 39%Kruskal-Wallis Fail Shewhart-CUSUM Pass --- Acetone 100%Poisson Prediction Limits Pass ----- Carbon Disulfide 99%Poisson Prediction Limits Pass ----- Chloroethane 100%Poisson Prediction Limits Pass ----- Iodomethane 100%Poisson Prediction Limits Pass ----- Dichloromethane 99%Poisson Prediction Limits Pass ----- 2-Butanone 100%Poisson Prediction Limits Pass ----- Notes: 1. MCL = Maximum Contaminant Level 2. SSI = Statistically Significant Increase 3. Total barium and total nickel are naturally occuring metals throughout much of North Carolina and are likely related to sample turbidity. Table 3 of 1957-55 White Oak GW Stats 1st 2016 Prepared by: IAI Checked by: DPO/MSP FIGURES LCID P I G E O N R I V E R FI N E S C R E E K R O A D CLOSED C & D PHASE 1 SR 1 3 3 8 M U L C H I N G A N D G R I N D I N G T R E A T M E N T A N D P R O C E S S I N G T Y P E 2 C O M P O S T I N G M S W P H A S E 2 M S W P H A S E 1 C E L L 3 C E L L 2 P H A S E 3 ( 8 . 8 A C R E S ) ( 6 . 7 A C R E S ) P H A S E 4 F U T U R E P H A S E 1 M S W M S W ( 1 1 . 4 A C R E S ) ( 1 0 . 1 A C R E S ) ( 1 . 2 A C R E S ) ( 2 . 0 A C R E S ) (4.0 ACRES)(4.8 ACRES) P I G E O N R I V E R APPENDICES APPENDIX A SUMMARY TABLES OF GROUNDWATER ANALYTICAL RESULTS White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2A MW-2D MW-3A MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.9 NS NS 6.1 5.1 5.1 6.2 5.9 5.4 5.2 NS NP NP NS Specific Conductance mmhos/cm (on-site)1 NE 72 NS NS 69 55 51 89 85 89 100 NS NP NP NS Temperature °C (on-site)-NE 12 NS NS 13 14 14 12 12 13 13 NS NP NP NS Turbidity NTU (on-site)NT NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Total Antimony (Sb)mg/l 10 NE ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Arsenic (As)mg/l 10 50 ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Barium (Ba)mg/l 5 1000 250 NS NS 240 420 200 63 300 93 230 NS NP NP NS Total Beryllium (Be)mg/l 2 NE 4.4 NS NS ND 2 ND 2.2 ND ND ND NS NP NP NS Total Cadmium (Cd)mg/l 1 5 2 NS NS ND 1.3 1.2 1.3 2.1 ND 5.4 NS NP NP NS Total Chromium (Cr)mg/l 5 50 15 NS NS 18 17 11 ND 26 5.4 50 NS NP NP NS Total Cobalt (Co)mg/l 5 NE ND NS NS ND 8.2 5.4 ND 14 ND 16 NS NP NP NS Total Copper (Cu)mg/l 5 1000 12 NS NS ND ND 13 ND 27 ND 22 NS NP NP NS Total Lead (Pb)mg/l 10 15 35 NS NS ND ND ND ND 11 ND ND NS NP NP NS Total Nickel (Ni)mg/l 5 100 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP NS Total Selenium (Se)mg/l 20 50 ND NS NS ND ND ND ND ND ND ND NS NP NP NS Total Silver (Ag)mg/l 2 18 3.7 NS NS ND ND ND 6.9 ND ND ND NS NP NP NS Total Thallium (Tl)mg/l 2 NE 2 NS NS ND 3 2 4 ND 2 5 NS NP NP NS Total Vanadium (V)mg/l 5 NE 17 NS NS 19 32 21 ND 29 8.9 78 NS NP NP NS Total Zinc (Zn)mg/l 10 2100 150 NS NS 35 48 36 12 43 28 68 NS NP NP NS Acetone mg/l 100 700 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Acrylonitrile mg/l 200 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Benzene mg/l 5 1 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromochloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromodichloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromoform mg/l 5 0.19 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Carbon Disulfide mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Bromomethane (Methylbromide)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Carbon tetrachloride mg/l 10 0.3 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chlorobenzene (mono)mg/l 5 50 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloroethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloroform mg/l 5 0.19 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Chloromethane (Methylchloride)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dibromochloromethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dibromomethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichlorobenzene mg/l 5 620 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,4-Dichlorobenzene mg/l 5 75 NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,4-Dichloro-2-butene mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1-Dichloroethane mg/l 5 700 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichloroethane mg/l 5 0.38 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NS NS NT NT NT NT NT NT NT NS NP NP NS cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2-Dichloropropane mg/l 5 0.56 NT NS NS NT NT NT NT NT NT NT NS NP NP NS cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Ethylbenzene mg/l 5 29 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 2-Hexanone mg/l 50 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Iodomethane mg/l 10 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Dichloromethane (Methylene chloride)mg/l 10 5 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 4-Methyl-2-Pentanone mg/l 100 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Styrene mg/l 10 100 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Toluene mg/l 5 1000 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,1-Trichloroethane mg/l 5 200 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,1,2-Trichloroethane mg/l 5 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Trichloroethene (-ethylene)mg/l 5 2.8 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Trichlorofluoromethane mg/l 5 2100 NT NS NS NT NT NT NT NT NT NT NS NP NP NS 1,2,3-Trichloropropane mg/l 15 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Vinyl acetate mg/l 50 NE NT NS NS NT NT NT NT NT NT NT NS NP NP NS Vinyl chloride mg/l 10 0.015 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Xylene mg/l 5 530 NT NS NS NT NT NT NT NT NT NT NS NP NP NS Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-24-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (6-26-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.9 6.8 NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 60 NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE 14 14 NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 300 67 NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 1.6 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 22 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE 10 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 17 6 NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 ND 10 NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 15 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE 40 6.3 NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 37 12 NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (6-26-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (7-26-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 330 30 NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 1.1 3.2 NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 29 20 NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE 9.9 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 12 6.1 NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 16 9.7 NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE 45 ND NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 65 66 NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NT NT NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (7-26-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-18-2000) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Total Antimony (Sb)mg/l 30 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Barium (Ba)mg/l 500 1000 NS NS NS 330 92 NS NS NS NT NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Chromium (Cr)mg/l 10 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Cobalt (Co)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Copper (Cu)mg/l 200 1000 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NT NT NS NS NS ND NS NS NP NP ND Total Nickel (Ni)mg/l 50 100 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Silver (Ag)mg/l 10 18 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Thallium (Tl)mg/l 20 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Vanadium (V)mg/l 40 NE NS NS NS NT NT NS NS NS NT NS NS NP NP ND Total Zinc (Zn)mg/l 50 2100 NS NS NS NT NT NS NS NS NT NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NT NT NS NS NS NT NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NT NT NS NS NS NT NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NT NT NS NS NS NT NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NT NT NS NS NS NT NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NT NT NS NS NS NT NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (9-18-2000) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-9-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.9 7.3 NS 6.4 6 6.3 6 6.1 8.2 5.8 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 20 60 NS 75 75 68 130 90 110 125 NS NP NP NT Temperature °C (on-site)-NE 15 15 NS 13 15 15 14 15 15 15 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 1000 1300 380 NS 180 330 120 80 290 360 970 NS NP NP ND Total Beryllium (Be)mg/l 2 NE 2.3 7 NS ND ND ND ND ND 2.4 4.8 NS NP NP ND Total Cadmium (Cd)mg/l 1 5 130 2 NS ND ND ND 1.7 1.8 2.7 19 NS NP NP ND Total Chromium (Cr)mg/l 5 50 130 ND NS 11 8.4 ND ND 20 27 160 NS NP NP ND Total Cobalt (Co)mg/l 5 NE 54 ND NS ND ND ND 13 12 13 59 NS NP NP ND Total Copper (Cu)mg/l 5 1000 77 8.4 NS ND ND 5.4 ND 26 38 110 NS NP NP ND Total Lead (Pb)mg/l 10 15 ND 59 NS ND ND ND ND ND 18 2.5 NS NP NP ND Total Nickel (Ni)mg/l 5 100 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 2 NE 40 ND NS ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 250 1.4 NS 13 19 9.3 ND 24 41 230 NS NP NP ND Total Zinc (Zn)mg/l 10 2100 230 130 NS 12 24 18 17 33 75 200 NS NP NP 24 Acetone mg/l 100 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Benzene mg/l 5 1 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Styrene mg/l 10 100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Toluene mg/l 5 1000 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Xylene mg/l 5 530 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-9-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-18-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (9-18-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-29-2001) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP 3.1 Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-29-2001) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (1-30-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 5 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 2 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 10 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (1-30-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (2-28-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Temperature °C (on-site)-NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Turbidity NTU (on-site)NT NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Total Antimony (Sb)mg/l 30 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Arsenic (As)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Barium (Ba)mg/l 500 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Beryllium (Be)mg/l 2 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cadmium (Cd)mg/l 1 5 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Chromium (Cr)mg/l 10 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Cobalt (Co)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Copper (Cu)mg/l 200 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Lead (Pb)mg/l 10 15 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Nickel (Ni)mg/l 50 100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Selenium (Se)mg/l 20 50 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Silver (Ag)mg/l 10 18 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Thallium (Tl)mg/l 20 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Vanadium (V)mg/l 40 NE NS NS NS NS NS NS NS NS NS NS NS NP NP ND Total Zinc (Zn)mg/l 50 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP ND Acetone mg/l 100 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Acrylonitrile mg/l 200 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Benzene mg/l 5 1 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromodichloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromoform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon Disulfide mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloroform mg/l 5 0.19 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromochloromethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dibromomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NS NS NS NS NS NS NS NS NS NS NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Ethylbenzene mg/l 5 29 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Hexanone mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Iodomethane mg/l 10 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Styrene mg/l 10 100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Toluene mg/l 5 1000 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NS NS NS NS NS NS NS NS NS NS NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl acetate mg/l 50 NE NS NS NS NS NS NS NS NS NS NS NS NP NP NT Vinyl chloride mg/l 10 0.015 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Xylene mg/l 5 530 NS NS NS NS NS NS NS NS NS NS NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (2-28-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-15-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.01 6.42 NS 6.46 5.89 5.25 5.75 5.68 6.88 6.01 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 21 42 NS 75 82 84 101 93 94 125 NS NP NP NT Temperature °C (on-site)-NE 15.9 17.4 NS 15.3 15.7 16.8 16.2 13.2 16.3 17.3 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 10 NE 15.0 ND NS ND ND ND NT ND ND 11 NS NP NP ND Total Arsenic (As)mg/l 10 50 ND ND NS ND ND ND NT ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 1000 1300 41 NS ND ND 160 23 190 460 1400 NS NP NP ND Total Beryllium (Be)mg/l 2 NE 2.1 ND NS ND ND ND ND ND 2.5 4.5 NS NP NP ND Total Cadmium (Cd)mg/l 10 5 13 ND NS ND ND ND 4 ND 5.5 19 NS NP NP ND Total Chromium (Cr)mg/l 5 50 170 ND NS ND ND 5.7 7 10 56 180 NS NP NP ND Total Cobalt (Co)mg/l 5 NE 58 ND NS ND ND ND 18 8.2 21 82 NS NP NP ND Total Copper (Cu)mg/l 2 1000 69 ND NS ND ND ND ND 13 68 120 NS NP NP 150 Total Lead (Pb)mg/l 10 15 13 ND NS ND ND ND ND ND 13 29 NS NP NP ND Total Nickel (Ni)mg/l 5 100 74 ND NS ND ND ND 6.2 9.2 44 68 NS NP NP ND Total Selenium (Se)mg/l 20 50 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NS ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 2 NE 40 ND NS ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 240 ND NS ND ND 11 21 14 69 260 NS NP NP ND Total Zinc (Zn)mg/l 10 2100 230 16 NS ND ND 13 33 38 120 230 NS NP NP 15 Acetone mg/l 100 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Acrylonitrile mg/l 200 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Benzene mg/l 5 1 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromodichloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromoform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon Disulfide mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloroform mg/l 5 0.19 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromochloromethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dibromomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NS NT NT NT NT NT NT NT NS NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Ethylbenzene mg/l 5 29 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Hexanone mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Iodomethane mg/l 10 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Styrene mg/l 10 100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Toluene mg/l 5 1000 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NS NT NT NT NT NT NT NT NS NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl acetate mg/l 50 NE NT NT NS NT NT NT NT NT NT NT NS NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Xylene mg/l 5 530 NT NT NS NT NT NT NT NT NT NT NS NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-15-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (9-26-2002) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.5 7.3 7.09 6.14 6.17 6.18 5.96 5.96 7.22 6.37 6.65 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 22 59 52 71 85 82 117 101 92 130 97 NP NP NT Temperature °C (on-site)-NE 15.1 13.5 13.7 13.5 13.9 14 15.8 14.6 15.1 17.7 16.6 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND ND 12 ND ND ND ND ND ND 98 NP NP ND Total Arsenic (As)mg/l 5 50 ND 5.7 ND ND ND ND ND ND 27 ND 68 NP NP ND Total Barium (Ba)mg/l 5 1000 330 500 750 4200 120 230 93 410 910 1400 11000 NP NP ND Total Beryllium (Be)mg/l 2 NE ND 7 2.1 5.1 ND ND ND ND 8.5 4.7 95 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND 4.2 21 ND 10 ND 2.3 4.2 19 180 NP NP ND Total Chromium (Cr)mg/l 5 50 33 5.4 33 510 ND 5.2 ND 37 36 230 770 NP NP ND Total Cobalt (Co)mg/l 5 NE 13 5.4 16 100 ND 16 7.4 21 19 85 560 NP NP ND Total Copper (Cu)mg/l 2 1000 20 10 31 220 ND ND 2.6 42 88 150 450 NP NP ND Total Lead (Pb)mg/l 10 15 ND 76 29 ND ND ND ND ND 150 20 740 NP NP ND Total Nickel (Ni)mg/l 5 100 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND 65 NP NP ND Total Vanadium (V)mg/l 5 NE 58 16 44 640 ND ND ND 42 50 310 1000 NP NP ND Total Zinc (Zn)mg/l 10 2100 57 120 110 580 ND 20 ND 56 250 280 4800 NP NP 2000 Acetone mg/l 100 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Acrylonitrile mg/l 200 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Benzene mg/l 5 1 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromodichloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromoform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon Disulfide mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Ethylbenzene mg/l 5 29 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Hexanone mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Iodomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Styrene mg/l 10 100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Toluene mg/l 5 1000 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl acetate mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Xylene mg/l 5 530 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (9-26-2002) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-28-2003) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 8.3 7.15 6.89 6.37 6.21 6.17 6.4 6.16 8.15 5.85 6.75 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 43 55 91 110 99 150 114 100 138 125 NP NP NT Temperature °C (on-site)-NE 16.7 15.9 15.6 15.6 16.3 15.3 13.5 14.2 17.7 14.9 18.4 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 24 NP NP ND Total Barium (Ba)mg/l 5 1000 600 66 220 1800 160 140 110 92 360 800 2800 NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND ND ND ND ND ND ND 2 2.2 20 NP NP ND Total Cadmium (Cd)mg/l 1 5 3.6 ND ND 6 ND ND ND ND 2.9 16 20 NP NP ND Total Chromium (Cr)mg/l 5 50 ND ND ND 89 ND ND ND ND ND 110 27 NP NP ND Total Cobalt (Co)mg/l 5 NE 21 ND ND 37 ND ND 6.9 ND 17 50 81 NP NP ND Total Copper (Cu)mg/l 2 1000 24 ND 2.6 40 ND ND ND ND 28 94 71 NP NP ND Total Lead (Pb)mg/l 10 15 ND ND ND ND ND ND ND ND 25 ND 300 NP NP ND Total Nickel (Ni)mg/l 5 100 ND ND ND 90 ND ND ND ND ND 26 70 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 1 NE ND ND ND 1.6 ND ND ND ND 1.4 ND 15 NP NP ND Total Vanadium (V)mg/l 5 NE 89 ND 9.6 170 6.8 6.8 ND ND 37 230 130 NP NP ND Total Zinc (Zn)mg/l 10 2100 86 14 31 160 16 ND ND ND 81 190 800 NP NP ND Acetone mg/l 100 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Acrylonitrile mg/l 200 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Benzene mg/l 5 1 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromodichloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromoform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon Disulfide mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Carbon tetrachloride mg/l 10 0.3 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chlorobenzene (mono)mg/l 5 50 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloroform mg/l 5 0.19 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromochloromethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 0.025 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dibromomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichlorobenzene mg/l 5 620 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,4-Dichlorobenzene mg/l 5 75 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,4-Dichloro-2-butene mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethane mg/l 5 700 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloroethane mg/l 5 0.38 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2-Dichloropropane mg/l 5 0.56 NT NT NT NT NT NT NT NT NT NT NT NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Ethylbenzene mg/l 5 29 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Hexanone mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Iodomethane mg/l 10 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Dichloromethane (Methylene chloride)mg/l 10 5 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 100 170 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Styrene mg/l 10 100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Toluene mg/l 5 1000 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,1-Trichloroethane mg/l 5 200 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Trichlorofluoromethane mg/l 5 2100 NT NT NT NT NT NT NT NT NT NT NT NP NP NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl acetate mg/l 50 NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Vinyl chloride mg/l 10 0.015 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Xylene mg/l 5 530 NT NT NT NT NT NT NT NT NT NT NT NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-28-2003) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-30-2003) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.58 6.9 6.73 6.57 6.26 6.44 6.33 6.27 7.7 6.18 6.46 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 39 58 82 119 110 140 115 105 149 120 NP NP NT Temperature °C (on-site)-NE 15 15.1 14.9 15.8 15.9 16.7 15 14 17.5 16.3 16 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND NT ND ND ND ND ND ND 5.3 81 NP NP ND Total Barium (Ba)mg/l 5 1000 320 100 NT 210 310 130 95 110 1200 270 4900 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND NT ND ND ND ND ND 2.4 ND 33 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 30 ND NT ND 6.2 ND ND ND 31 4.6 140 NP NP ND Total Cobalt (Co)mg/l 5 NE 9 ND NT ND ND ND 5.7 ND 52 8.8 110 NP NP ND Total Copper (Cu)mg/l 2 1000 18 ND NT ND 2.3 2.6 ND 3 85 4.4 150 NP NP ND Total Lead (Pb)mg/l 5 15 8.7 12 NT ND ND ND ND ND 39 7.4 640 NP NP ND Total Nickel (Ni)mg/l 5 100 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND NT ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 54 ND NT 6.6 16 ND ND ND 92 14 200 NP NP ND Total Zinc (Zn)mg/l 10 2100 55 22 NT 17 26 10 ND ND 140 26 1800 NP NP ND Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-30-2003) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-20-2004) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.71 6.81 6.78 5.57 5.4 5.47 5.47 5.41 7.36 5.17 6.83 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 31 40 67 135 120 115 100 100 115 70 NP NP NT Temperature °C (on-site)-NE 15.8 15.6 15.5 13.5 14.6 14.4 13.5 14.1 15.3 14.9 13.8 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND 7.4 30 NP NP ND Total Barium (Ba)mg/l 5 1000 320 56 120 410 460 170 140 210 62 940 2000 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 21 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND 8.8 8.9 NP NP ND Total Chromium (Cr)mg/l 2 50 33 ND 2.1 45 13 ND ND 11 3.5 190 68 NP NP ND Total Cobalt (Co)mg/l 5 NE 9.5 ND ND 7.7 5.2 ND 13 6.4 ND 43 50 NP NP ND Total Copper (Cu)mg/l 2 1000 18 ND 2.8 12 5.3 2.3 4.3 13 7.4 100 89 NP NP ND Total Lead (Pb)mg/l 5 15 7.2 7 5.2 6.4 5.4 ND ND ND 12 39 250 NP NP ND Total Nickel (Ni)mg/l 5 100 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND 5 ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 55 ND ND 45 25 ND ND 13 5.1 240 88 NP NP ND Total Zinc (Zn)mg/l 10 2100 55 10 ND 44 30 11 14 19 23 220 770 NP NP 11 Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP NT cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP NT 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP NT Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-20-2004) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-21-2004) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.83 6.55 6.76 6.9 5.92 6.39 5.75 6.03 7.84 5.57 7.12 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 49 62 96 290 302 196 148 111 198 134 NP NP NT Temperature °C (on-site)-NE 14.3 16.7 14 13 14.7 14.3 15 14.5 14.2 14.6 17 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 59 NP NP ND Total Barium (Ba)mg/l 5 1000 320 40 200 300 310 140 140 130 12 900 4900 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND 1.4 28 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 21 ND 2.8 16 2 ND ND ND ND 120 140 NP NP ND Total Cobalt (Co)mg/l 5 NE 6.2 ND ND ND ND ND ND ND ND 31 120 NP NP ND Total Copper (Cu)mg/l 2 1000 11 ND ND 2 ND ND ND ND ND 63 140 NP NP ND Total Lead (Pb)mg/l 5 15 7.2 5.6 5.7 ND ND ND ND ND ND 24 430 NP NP ND Total Nickel (Ni)mg/l 5 100 12 ND ND 13 ND ND ND ND ND 35 160 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 41 ND ND 18 ND ND ND ND ND 160 210 NP NP ND Total Zinc (Zn)mg/l 10 2100 29 ND ND 17 ND 14 ND 12 15 70 1200 NP NP ND Acetone mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND 24 ND ND ND ND ND ND 15 ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-21-2004) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-18-2005) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.95 7.44 6.15 6.2 5.58 6.04 6.02 6.18 7.46 5.6 6.85 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 40 42 78 330 161 171 139 95 149 138 NP NP NT Temperature °C (on-site)-NE 14.2 15.6 15 13.5 15 17.7 13 13.5 16.2 14.1 16.4 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND 12 NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND 10 ND ND ND ND ND 5.2 65 NP NP ND Total Barium (Ba)mg/l 5 1000 480 55 160 7200 610 180 160 140 12 1000 3700 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND 7.2 ND ND ND ND ND 3.8 26 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 49 12 8.3 680 2.9 ND ND 3.2 ND 210 100 NP NP ND Total Cobalt (Co)mg/l 5 NE 12 ND ND 110 ND ND ND ND ND 36 70 NP NP ND Total Copper (Cu)mg/l 2 1000 29 ND ND 240 ND ND ND 3.8 ND 120 130 NP NP ND Total Lead (Pb)mg/l 5 15 13 8 5.2 73 ND ND ND ND ND 39 380 NP NP ND Total Nickel (Ni)mg/l 5 100 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 85 ND ND 680 5.4 ND ND ND ND 240 110 NP NP ND Total Zinc (Zn)mg/l 10 2100 83 ND ND 780 ND 30 13 10 ND 240 1200 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-18-2005) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-13-2005) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 7.21 7.38 7.79 6.36 6.07 6.25 6.08 6.6 7.73 6.08 6.72 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 21 35 40 85 580 201 185 160 102 180 52 NP NP NT Temperature °C (on-site)-NE 13.2 14 13.3 13.3 14.9 14.3 16.5 15.5 15.3 16.5 16.8 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 44 NP NP ND Total Barium (Ba)mg/l 5 1000 770 37 160 1700 870 250 160 140 27 810 2700 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND 3 ND ND ND ND ND 3.4 21 NP NP ND Total Cadmium (Cd)mg/l 1 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 2 50 52 ND 3.7 230 4.7 ND ND ND ND 150 88 NP NP ND Total Cobalt (Co)mg/l 5 NE 21 ND ND 32 ND ND 5.1 ND ND 29 56 NP NP ND Total Copper (Cu)mg/l 2 1000 31 2.6 3.5 70 ND ND ND ND 3 82 96 NP NP ND Total Lead (Pb)mg/l 5 15 14 6.9 ND 20 ND ND ND ND ND 29 290 NP NP ND Total Nickel (Ni)mg/l 5 100 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP ND Total Selenium (Se)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 2 18 2.9 ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE 22 ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 82 ND ND 210 8.9 ND ND ND ND 170 82 NP NP ND Total Zinc (Zn)mg/l 10 2100 92 13 12 230 19 25 ND ND 14 170 800 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.3 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.0004 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 620 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 29 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 170 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-13-2005) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-25-2006) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.33 7.06 6.61 6.07 5.45 6.16 5.63 5.62 7.7 5.56 5.83 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 53 48 52 106 105 383 301 236 136 251 70 NP NP NT Temperature °C (on-site)-NE 18.1 19.2 16.1 13.7 19.5 20.6 12.4 13.8 14.6 14.8 12.9 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND 42 NP NP ND Total Barium (Ba)mg/l 500 2000 650 ND ND ND 1100 ND ND ND ND 750 2700 NP NP ND Total Beryllium (Be)mg/l 2 NE ND ND ND ND ND ND ND ND 2.1 ND 17 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 10 50 65 ND 16 ND ND ND ND ND 16 100 93 NP NP ND Total Cobalt (Co)mg/l 10 NE 16 ND ND ND ND ND ND ND ND 25 57 NP NP ND Total Copper (Cu)mg/l 200 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Lead (Pb)mg/l 10 15 15 ND ND ND ND ND ND ND 53 19 300 NP NP ND Total Nickel (Ni)mg/l 50 100 ND ND ND ND ND ND ND ND ND ND 88 NP NP ND Total Selenium (Se)mg/l 20 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 10 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 40 NE 110 ND ND ND ND ND ND ND ND 120 85 NP NP ND Total Zinc (Zn)mg/l 50 1050 130 ND 88 ND ND ND ND ND 110 120 780 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 5 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-25-2006) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-20-2006) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.47 6.81 6.51 6.74 5.56 6.14 5.87 5.74 8.2 5.61 5.97 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 229 48 53 108 876 564 149 200 12.8 330 33 NP NP NT Temperature °C (on-site)-NE 12.2 11.9 12.8 12.5 12.7 12.9 14.9 13.7 13.5 13.3 14.9 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 13 NP NP ND Total Barium (Ba)mg/l 5 2000 410 22 180 470 1100 ND ND ND 160 ND 650 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 5.7 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 3.8 ND ND ND ND ND ND ND 1.5 ND 5.2 NP NP ND Total Chromium (Cr)mg/l 5 50 50 ND 11 24 ND ND ND ND 17 ND 27 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Copper (Cu)mg/l 5 1000 26 ND ND 9.6 ND ND ND ND 20 ND 25 NP NP ND Total Lead (Pb)mg/l 5 15 20 ND ND ND ND ND ND ND 32 ND 89 NP NP ND Total Nickel (Ni)mg/l 5 100 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 79 ND ND 28 ND ND ND ND 23 ND 30 NP NP ND Total Zinc (Zn)mg/l 10 1050 74 ND 20 37 ND ND ND ND 55 ND 200 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 10 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-20-2006) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-25-2007) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.04 7.08 6.27 6.25 5.36 5.83 5.7 5.73 8.02 5.54 9.08 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 31 50 54 105 1540 757 391 312 134 336 46 NP NP NT Temperature °C (on-site)-NE 13.4 14.2 14 13 14 14.6 14 13 15.7 15.4 12.5 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 6 NE ND ND ND ND ND 20 ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND 280 ND ND ND ND 12 NP NP ND Total Barium (Ba)mg/l 100 2000 290 ND 200 240 1300 1500 130 180 ND ND 600 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND 14 ND ND ND ND 4.9 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND 2.2 ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 10 50 20 ND ND 16 ND 410 ND ND ND ND 17 NP NP ND Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND 260 ND ND ND ND ND NP NP ND Total Copper (Cu)mg/l 10 1000 15 ND ND ND ND 330 ND ND ND ND 26 NP NP ND Total Lead (Pb)mg/l 10 15 ND ND ND ND ND 96 ND ND ND ND 69 NP NP ND Total Nickel (Ni)mg/l 50 100 ND ND ND ND ND 330 ND ND ND ND ND NP NP ND Total Selenium (Se)mg/l 10 50 12 ND ND ND ND 460 ND ND ND ND 18 NP NP ND Total Silver (Ag)mg/l 10 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND 35 ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 25 NE 43 ND ND ND ND 300 ND ND ND ND 26 NP NP ND Total Zinc (Zn)mg/l 10 1050 55 21 30 30 22 830 22 15 10 12 200 NP NP 12 Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 25 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 5 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 5 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 10 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 5 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 10 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 5 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 5 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 5 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 5 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 5 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 5 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 5 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 5 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 5 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 10 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 5 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 5 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 5 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 5 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 10 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 5 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 5 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylene mg/l 5 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-25-2007) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-31-2007) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.6 6.8 6.3 6.22 5.9 6 5.5 5.9 7.99 5.5 5.9 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28 61 45 94 1475 911 346 300 132 543 36 NP NP NT Temperature °C (on-site)-NE 13.8 16 16.1 14.8 17.5 17.6 17.5 17.2 14.8 15.6 17.2 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 21.4 NP NP ND Total Barium (Ba)mg/l 5 2000 501 31.5 223 198 1350 591 184 208 62.4 516 872 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 6 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 40.9 ND 11.9 10.9 7.8 ND ND ND 5.1 75.5 33.7 NP NP ND Total Cobalt (Co)mg/l 5 NE 16.8 ND ND ND 10.6 ND ND ND ND ND 17.6 NP NP ND Total Copper (Cu)mg/l 5 1000 29.2 ND ND ND ND ND ND ND 6.3 40.3 47.4 NP NP ND Total Lead (Pb)mg/l 5 15 17.5 8.1 ND ND ND ND ND ND ND 12.3 123 NP NP ND Total Nickel (Ni)mg/l 5 100 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE 11.6 ND ND ND ND ND ND ND ND 9.5 ND NP NP ND Total Vanadium (V)mg/l 5 NE 89 ND 8.8 14.7 20 ND ND ND 8.6 103 48.2 NP NP ND Total Zinc (Zn)mg/l 10 1050 86 ND 66.2 14 37.4 33.3 12 ND 11.6 91.1 336 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-31-2007) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (04-23-2008) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.59 7.22 6.58 6.33 5.71 6.05 5.66 5.65 8.13 5.56 6.69 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 25 49 49 102 1546 946 411 318 124 481 33 NP NP NT Temperature °C (on-site)-NE 13.9 14.2 14.2 13.2 14.6 14.4 13.4 14.7 17.4 14.8 14.1 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 10.2 NP NP ND Total Barium (Ba)mg/l 5 2000 194 30.8 253 168 1230 661 216 202 61.8 151 361 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 3 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND 1.6 NP NP ND Total Chromium (Cr)mg/l 5 50 10.7 ND 16.8 7.8 ND ND ND ND 7.6 7.3 14.9 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND 22.3 NP NP ND Total Copper (Cu)mg/l 5 1000 7.2 ND ND ND ND ND ND ND 7.2 ND 17 NP NP ND Total Lead (Pb)mg/l 5 15 ND ND 8.4 ND ND ND ND ND 5.8 ND 50.2 NP NP ND Total Nickel (Ni)mg/l 5 100 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 26.1 ND 11.4 9.7 10.1 ND ND 5.1 9.7 10 23.1 NP NP ND Total Zinc (Zn)mg/l 10 1050 27.3 ND 50.3 12.2 24.4 36.9 ND 10.3 17.5 38.8 138 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (04-23-2008) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-20-2008) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.7 6.7 6.2 6.1 5.9 6.0 5.9 5.8 7.9 5.6 5.5 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 54.0 44.0 104 1420 1111 320 350.0 129.0 621.0 41.0 NP NP NT Temperature °C (on-site)-NE 13.8 14.2 12.0 13.2 14.3 15.4 14.9 14.6 15.2 14.5 16.5 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND ND ND ND ND ND ND 6.6 NP NP ND Total Barium (Ba)mg/l 5 2000 474 66.0 313 224 1210 894 164 216 41.1 182 245 NP NP ND Total Beryllium (Be)mg/l 1 NE ND 1.2 ND ND ND ND ND ND ND ND 1.9 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 38.6 ND 29.4 12.7 ND ND ND ND ND ND 6.8 NP NP ND Total Cobalt (Co)mg/l 5 NE 27.0 10.4 19.5 9.4 7.7 ND 12.6 5.3 7.1 ND 18.4 NP NP ND Total Copper (Cu)mg/l 5 1000 26.5 ND 8.3 ND ND ND ND ND ND ND 9.7 NP NP ND Total Lead (Pb)mg/l 5 15 ND 13.5 7.6 ND ND ND ND ND ND ND 25.9 NP NP ND Total Nickel (Ni)mg/l 5 100 23.0 ND 21.0 11.1 10.7 7.5 ND 14.0 ND ND 8.5 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE 7.2 ND ND ND ND ND ND 6.1 ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 79.0 ND 15.1 15.8 ND ND ND ND 5.4 ND 14.8 NP NP ND Total Zinc (Zn)mg/l 10 1050 66.5 19.9 59.2 15.3 10.6 29.1 ND 12.4 ND 17.4 71.5 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND 140 NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND 54.4 NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-20-2008) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-22-2009) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.64 6.89 6.32 5.83 5.74 5.92 5.75 5.72 7.56 5.47 NS NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 53.0 12.0 131 1427 1109 398 358 131 536.0 NS NP NP NT Temperature °C (on-site)-NE 13.3 13.1 47 13.4 12.8 13.1 11.7 12.1 14.4 15.1 NS NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NS NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Arsenic (As)mg/l 5 50 ND ND 5.4 ND ND 5.6 ND ND ND ND NS NP NP ND Total Barium (Ba)mg/l 5 2000 126 47.2 591 309 1300 817 230 216 77.0 163 NS NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND 1.5 ND ND ND ND ND ND ND NS NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Chromium (Cr)mg/l 5 50 12.3 ND 28.9 19.7 5.1 ND ND ND 7.3 ND NS NP NP ND Total Cobalt (Co)mg/l 5 NE 5.0 6.3 17.1 8.5 5.7 ND 7.0 ND 6.4 ND NS NP NP ND Total Copper (Cu)mg/l 5 1000 5.1 ND 22.6 6.0 ND ND ND ND 8.8 ND NS NP NP ND Total Lead (Pb)mg/l 5 15 ND 8.7 24.4 ND ND ND ND ND 9.8 ND NS NP NP ND Total Nickel (Ni)mg/l 5 100 5.6 7.2 19.7 16.7 10.9 6.0 5.1 14.0 6.0 ND NS NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Total Vanadium (V)mg/l 5 NE 16.0 ND 32.7 19.8 7.7 ND ND ND 13.3 ND NS NP NP ND Total Zinc (Zn)mg/l 10 1050 23.1 43.5 99.9 25.3 17.9 17.6 10.5 ND 35.2 ND NS NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND 4.5 ND NS NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND NS NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND NS NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND NS NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND NS NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND NS NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-22-2009) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-26-2009) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.88 6.35 6.0 5.76 5.78 5.95 NS NS NS 5.32 5.30 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 29 50 37.0 127 1532 1120 NS NS NS 637 39 NP NP NT Temperature °C (on-site)-NE 13.4 13.2 14.4 14.6 14.7 15.9 NS NS NS 14.5 15.3 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NS NS NS NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 6.0 ND NS NS NS ND ND NP NP ND Total Barium (Ba)mg/l 5 2000 131 16.8 144 188 1720 987 NS NS NS 209 178 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND NS NS NS ND 1.7 NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 10.0 ND 8.1 ND 18.7 ND NS NS NS 10.9 8.1 NP NP ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 6.0 ND NS NS NS ND 6.0 NP NP ND Total Copper (Cu)mg/l 5 1000 5.8 ND ND ND 6.4 ND NS NS NS ND 7.1 NP NP ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND NS NS NS ND 24.7 NP NP ND Total Nickel (Ni)mg/l 5 100 6.7 ND 5.2 6.0 18.0 7.5 NS NS NS 6.0 8.4 NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 17.9 ND ND 5.3 33.6 ND NS NS NS 12.2 11.9 NP NP ND Total Zinc (Zn)mg/l 10 1050 19.6 ND 14.8 ND 37.8 ND NS NS NS ND 63.8 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND NS NS NS ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND NS NS NS ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND NS NS NS ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND NS NS NS ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND NS NS NS ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-26-2009) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-22-2010) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3 MW-3D MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.05 6.54 6.33 6.06 5.90 5.94 NS NS 7.04 5.50 5.69 NP NP NT Specific Conductance mmhos/cm (on-site)1 NE 65 96 8.2 161 1987 1812 NS NS 1727 659 83 NP NP NT Temperature °C (on-site)-NE 13.5 13.8 13.9 13.5 13.3 13.4 NS NS 14.9 14.6 12.7 NP NP NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NS NS NT NT NT NP NP NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 7.4 9.8 NS NS ND ND ND NP NP ND Total Barium (Ba)mg/l 5 2000 208 43.5 153 157 1920 1380 NS NS 20.9 150 74.8 NP NP ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Chromium (Cr)mg/l 5 50 14.3 10.9 13.1 ND ND ND NS NS ND ND ND NP NP ND Total Cobalt (Co)mg/l 5 NE 5.6 ND ND ND ND ND NS NS ND ND ND NP NP ND Total Copper (Cu)mg/l 5 1000 9.9 ND ND ND ND 5.9 NS NS ND ND ND NP NP ND Total Lead (Pb)mg/l 5 15 ND 10.5 ND ND ND ND NS NS ND ND 9.2 NP NP ND Total Nickel (Ni)mg/l 5 100 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Total Vanadium (V)mg/l 5 NE 27.9 ND ND ND ND ND NS NS ND ND ND NP NP ND Total Zinc (Zn)mg/l 10 1050 22.2 14.2 ND ND ND ND NS NS ND ND 24.6 NP NP ND Acetone mg/l 25 700 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Benzene mg/l 1 1 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloroform mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 0.025 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND NS NS ND ND ND NP NP ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND NS NS ND ND ND NP NP ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Styrene mg/l 1 100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Toluene mg/l 1 1000 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND NS NS ND ND ND NP NP ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND NS NS ND ND ND NP NP ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Xylenes mg/l 2 530 ND ND ND ND ND ND NS NS ND ND ND NP NP ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-22-2010) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-2010) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 5.33 6.38 6.06 5.69 5.72 5.96 5.43 5.65 7.36 5.29 5.44 5.65 5.82 NT Specific Conductance mmhos/cm (on-site)1 NE 35 52 54 113 189 177 418 317 140 772 46 221 90 NT Temperature °C (on-site)-NE 13.7 14.1 14.1 13.9 13.9 14.7 15.2 15.0 15.7 14.7 16.5 15.9 15.0 NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 50 ND ND ND ND 5.4 5.9 ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 2000 147 15.8 162 178 1760 1550 531 234 20.0 190 111 191 84.4 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 1.75 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 10.1 ND 6.6 7.1 ND ND 12.0 9.2 ND ND 5.2 ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND 17.3 5.6 ND ND 7.8 29.6 ND ND Total Copper (Cu)mg/l 5 1000 6.7 ND ND ND ND ND ND 12.4 ND ND 53.9 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 16.0 ND ND ND Total Nickel (Ni)mg/l 5 100 7.0 ND ND ND 7.4 ND 21.5 19.0 ND ND 7.5 10.8 ND ND Total Selenium (Se)mg/l 10 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 17.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 17.4 ND ND 6.9 ND ND 14.2 7.1 ND ND 5.9 ND ND ND Total Zinc (Zn)mg/l 10 1050 19.1 ND 12.3 15.0 ND ND 32.4 16.3 ND ND 60.7 ND ND ND Acetone mg/l 25 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.56 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.269 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 2800 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 2.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.025 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.00047 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 24 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 1.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.38 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.51 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 550 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 4.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 2.8 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.015 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 530 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-27-2010) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-29-2011) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.00 6.50 6.50 6.10 5.80 6.00 5.60 5.60 6.20 5.40 5.70 5.60 5.60 NT Specific Conductance mmhos/cm (on-site)1 NE 29 50 53 127 1770 1593 491 290 135 762 90 197 125 NT Temperature °C (on-site)-NE 14.3 14.6 13.7 13.2 14.5 14.7 15.3 14.5 14.8 14.4 13.2 15.2 14.8 NT Turbidity NTU (on-site)NT NE NT NT NT NT NT NT NT NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 191 16.3 188 182 1620 1390 428 173 13.6 196 125 201 133.0 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.1 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 8.0 ND 8.6 ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 6.9 ND 8.9 ND ND ND ND 26.3 ND ND Total Copper (Cu)mg/l 5 1000 6.4 ND ND ND 6.7 6.1 ND ND ND ND 5.2 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 11.0 ND ND ND Total Nickel (Ni)mg/l 5 100 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 15.8 ND 5.1 ND ND ND ND ND ND ND 5.5 7.3 ND ND Total Zinc (Zn)mg/l 10 1000 25.7 ND 21.9 ND 11.8 23.9 13.7 ND ND ND 42.9 20.5 21.5 ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-29-2011) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-25-2011) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.50 6.20 6.40 6.10 5.60 5.40 5.40 5.30 7.00 5.20 5.60 5.60 5.80 NT Specific Conductance mmhos/cm (on-site)1 NE 32 47 46 108 1275 1450 395 297 137 802 52 245 145 NT Temperature °C (on-site)-NE 14.2 13.5 15.3 12.4 13.2 13.7 15.8 15.1 15.7 16.2 16.9 16.3 15.6 NT Turbidity NTU (on-site)NT NE 96.5 8.09 17.7 9.06 9.22 1.78 8.72 5.24 1.91 80.5 154.0 4.62 1.77 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 185 19.7 120 332 1200 1300 945 205 8.2 238 123 161 154 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.6 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 15.0 ND ND 21.1 ND ND 8.1 ND ND 9.2 5.1 ND ND ND Total Cobalt (Co)mg/l 5 NE 5.3 ND ND 6.4 6.3 ND 21.0 ND ND ND ND 42.4 ND ND Total Copper (Cu)mg/l 5 1000 9.6 ND ND 9.4 6.8 11.2 7.6 ND ND 5.1 6.9 ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND 6.3 ND ND ND 14.6 ND ND ND Total Nickel (Ni)mg/l 5 100 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8.0 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 25.6 ND ND 23.0 ND ND 15.1 ND ND 9.7 6.3 ND ND ND Total Zinc (Zn)mg/l 10 1000 34.5 ND 11.6 23.7 12.8 10.1 32.5 ND ND 17.7 49.9 15.1 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-25-2011) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-20-2012) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.4 6.9 6.6 6.3 6.2 6.1 5.7 5.8 8.3 5.5 5.8 6.0 6.0 NT Specific Conductance mmhos/cm (on-site)1 NE 29.1 48.1 45.5 112.2 1339 1397 508 341 140 845 61.4 284.3 165.9 NT Temperature °C (on-site)-NE 13.5 13.9 13.6 14.0 14.9 14.7 15.9 14.2 15.1 15.2 14.0 15.9 14.9 NT Turbidity NTU (on-site)NT NE 90 48.1 11.5 4.28 3.53 2.50 14.70 3.63 4.36 2.21 70.0 21.10 1.75 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 304 17.5 129 153 1020 1140 442 215 9.5 232 64.8 249 169 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 4.8 ND ND Total Chromium (Cr)mg/l 5 10 24.5 ND ND 5.1 ND ND 7.9 ND ND ND ND 12.3 ND ND Total Cobalt (Co)mg/l 5 NE 6.9 ND ND ND ND ND 6.4 ND ND ND ND 134.0 ND ND Total Copper (Cu)mg/l 5 1000 15.6 ND ND ND 5.8 5.2 ND ND ND ND ND 6.5 ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 6.4 ND ND ND Total Nickel (Ni)mg/l 5 100 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 44.3 ND ND ND ND ND 10.0 ND ND ND ND 15.0 ND ND Total Zinc (Zn)mg/l 10 1000 47.6 ND 12.5 ND 11.6 10.1 21.1 ND ND 11.1 30.7 50.8 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-20-2012) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-24-2012) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.3 6.8 6.3 6.3 6.1 6.0 5.6 5.7 8.1 5.3 5.6 5.9 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 28.0 49.0 49.0 122.0 1200 1332 540 395 140 867 50.0 260.0 171.0 NT Temperature °C (on-site)-NE 14.4 13.3 12.5 16.5 15.3 15.2 15.6 15.2 15.3 15.4 16.1 15.9 15.7 NT Turbidity NTU (on-site)NT NE 921 3.2 9.2 8.64 5.54 2.67 6.39 4.52 10.31 2.50 56.0 2.82 2.23 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 389 19.0 124 167 889 1030 393 229 26.1 235 43.2 177 181 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 1.0 ND ND Total Chromium (Cr)mg/l 5 10 30.4 6.0 ND 6.4 ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 15.7 ND ND ND 5.6 ND 6.5 ND ND ND ND 48.5 ND ND Total Copper (Cu)mg/l 5 1000 22.7 ND ND ND 6.0 ND ND ND 5.1 ND ND ND ND ND Total Lead (Pb)mg/l 5 15 5.9 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 18.5 ND ND ND 10.1 8.9 20.0 25.3 ND ND ND 9.6 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 59.0 ND ND 5.9 ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 93.4 10.4 11.3 22.4 23.8 ND 10.3 16.1 14.9 12.2 15.7 15.8 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND 4.4 ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-24-2012) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2013) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.5 6.8 6.3 6.2 6.3 6.2 5.7 5.7 8.1 5.6 5.9 6.0 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 22.0 46.0 44.0 121.0 1205 1328 516 387 144 887 72.0 247 190 NT Temperature °C (on-site)-NE 15.2 13.9 13.7 13.2 14.3 14.4 14.3 14.1 15.6 16.0 13.6 15.7 14.3 NT Turbidity NTU (on-site)NT NE 100 1.21 6.28 282 4.84 0.30 1.76 1.61 0.55 1.57 60.0 1.01 0.11 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 241 16.8 100 164 842 964 344 226 9.3 218 96.5 116 190 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND 1.2 ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 19.0 ND ND 8.8 6.8 ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 16.5 ND ND ND 10.8 ND 5.6 ND ND ND 8.9 115 ND ND Total Copper (Cu)mg/l 5 1000 13.4 ND ND ND 9.3 6.0 ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND 10.4 ND ND ND Total Nickel (Ni)mg/l 5 100 10.0 ND ND ND 12.0 8.6 21.8 32.8 ND ND ND 9.2 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 33.5 ND ND 7.7 9.6 ND ND ND ND ND 5.4 ND ND ND Total Zinc (Zn)mg/l 10 1000 56.3 ND ND ND 18.6 14.9 ND ND ND ND 33.2 ND ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-24-2013) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-24-2013) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.6 6.9 11.9 6.5 6.5 6.4 5.9 6.0 8.0 5.8 6.1 6.2 6.1 NT Specific Conductance mmhos/cm (on-site)1 NE 31.0 47.0 67.0 117.0 1191 1390 536 402 142 897 53.0 301 212 NT Temperature °C (on-site)-NE 12.5 12.5 11.9 12.5 13.7 13.6 13.1 13.9 13.4 13.7 13.9 13.6 13.0 NT Turbidity NTU (on-site)NT NE 55 2.23 9.29 3.02 3.17 0.61 3.01 2.27 0.36 0.55 100.0 0.53 0.66 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 255 18.1 156 166 839 1160 510 256 9.1 250 55.2 171 218 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 14.5 ND 12.1 ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 11.8 ND ND ND 8.0 ND 7.5 ND ND ND ND 84.5 ND ND Total Copper (Cu)mg/l 5 1000 12.6 ND ND ND 7.5 5.8 ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 7.9 ND 8.3 ND 7.5 7.0 30.2 29.9 ND ND ND 12.1 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 30.4 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 30.6 ND ND ND ND ND 28.1 ND ND 28.8 39.6 14.9 ND 12 Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-24-2013) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-24-2014) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.8 7.0 6.6 6.3 6.5 6.4 5.8 5.8 8.3 5.6 5.8 6.1 5.8 NT Specific Conductance mmhos/cm (on-site)1 NE 30.0 48.0 50.0 126.0 1364 1652 517 418 147 919 57.0 240 187 NT Temperature °C (on-site)-NE 12.9 13.8 14.9 14.5 15.5 15.3 15.8 14.2 16.0 15.6 12.8 16.5 16.5 NT Turbidity NTU (on-site)NT NE 39 1.43 4.85 1.82 1.49 2.86 2.25 1.24 1.51 2.38 9.39 1.95 2.24 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 6.1 ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 174 17.7 127 148 941 1290 378 248 8.3 238 27.5 148 189 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 1.2 ND ND Total Chromium (Cr)mg/l 5 10 12.8 ND ND ND ND ND ND ND ND ND ND 5.1 ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND 5.7 ND ND ND ND ND ND 65.1 ND ND Total Copper (Cu)mg/l 5 1000 7.9 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 7.0 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND 5.6 ND ND Total Vanadium (V)mg/l 5 NE 22.8 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 25.8 ND ND ND ND ND 18.9 ND ND ND ND 14.9 10.1 ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND 2 ND ND ND 2.2 ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-24-2014) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-2014) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.55 8.52 6.50 6.27 6.18 6.13 5.71 5.25 7.70 5.81 6.50 5.92 5.89 NT Specific Conductance mmhos/cm (on-site)1 NE 21.7 108.1 32.4 115.1 1468.0 1646.0 466.3 353.0 163.1 698.0 50.9 223.7 172.0 NT Temperature °C (on-site)-NE 14.8 13.7 17.1 16.7 16.6 14.9 18.3 20.7 16.1 16.7 15.6 17.2 15.4 NT Turbidity NTU (on-site)NT NE >50 >50 30.00 2.68 3.09 2.99 30.00 3.92 30.00 6.01 4.35 3.17 1.44 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 117 16.1 102 136 1280 1410 363 224 8.6 228 23.2 156 180 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 24.2 ND ND Total Copper (Cu)mg/l 5 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-27-2014) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-28-2015) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.60 6.50 7.50 6.40 6.00 6.10 6.50 6.20 6.30 6.10 6.30 6.10 6.10 NT Specific Conductance mmhos/cm (on-site)1 NE 26.0 44.0 53.0 112.7 1601.0 1621.0 464.0 387.0 236.0 843.0 66.0 253.0 169.0 NT Temperature °C (on-site)-NE 13.5 13.2 12.5 13.9 16.9 15.5 14.1 14.2 16.5 15.8 13.5 16.6 14.8 NT Turbidity NTU (on-site)NT NE 39.5 4.82 9.58 4.46 7.43 3.78 4.84 4.94 3.80 4.37 18.40 4.49 3.49 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 119 16.0 109 199 1330 1380 345 260 9.0 218 30.2 156 190 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND 2.3 ND ND Total Chromium (Cr)mg/l 5 10 10.3 ND 8.2 7.9 ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND 29.3 ND ND Total Copper (Cu)mg/l 5 1000 7.4 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 15.5 ND ND 8.0 ND ND ND ND ND ND ND 7.0 ND ND Total Zinc (Zn)mg/l 10 1000 51.7 ND 14.2 19.0 13.6 ND 14.8 12.9 ND ND 11.3 13.3 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND 10.2 ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-28-2015) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (10-27-15) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 6.70 6.60 6.60 6.30 5.90 6.20 6.00 5.80 6.80 6.40 6.70 6.30 5.90 NT Specific Conductance mmhos/cm (on-site)1 NE 27.0 44.0 104.0 118.0 1478.0 1566.0 429.0 357.0 162.0 816.0 48.0 248.0 169.0 NT Temperature °C (on-site)-NE 12.1 12.4 12.4 12.5 13.0 13.0 13.5 13.7 13.2 13.5 14.3 14.5 13.4 NT Turbidity NTU (on-site)NT NE 5.5 4.35 28.00 1.88 2.52 1.27 4.05 7.82 8.68 5.50 16.56 11.09 5.11 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 346 16.0 95.7 164 1190 1400 352 247 13.8 279 18.8 188 191 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 1.9 ND ND ND ND ND ND ND ND ND ND 3.1 ND ND Total Chromium (Cr)mg/l 5 10 31.4 ND ND ND ND ND ND ND ND 7.7 ND ND ND ND Total Cobalt (Co)mg/l 5 NE 6.2 ND ND ND 5.6 ND ND ND ND ND ND 39.0 ND ND Total Copper (Cu)mg/l 5 1000 19.1 ND ND ND 5.4 7.3 ND ND ND ND ND 6.0 ND ND Total Lead (Pb)mg/l 5 15 7.7 ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 44.5 ND ND ND ND ND ND ND ND 7.4 ND 9.8 ND ND Total Zinc (Zn)mg/l 10 1000 69.8 ND ND ND 14.3 ND ND 11.8 ND 22.1 ND 36.4 ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND total Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (10-27-15) White Oak Landfill - Haywood Co., NC Groundwater Sampling Event (4-19-16) TEST UNITS MRL MCL MW-11S MW-11D MW-14 MW-1A MW-2 MW-2D MW-3R MW-3DR MW-4A MW-8 MW-15 MW-16 MW-17 EQUIP. BLANK pH pH units (on-site)-NE 7.00 6.80 5.40 7.30 7.80 7.10 5.90 5.80 7.60 5.60 6.00 6.00 6.50 NT Specific Conductance mmhos/cm (on-site)1 NE 25.0 47.0 29.0 145.0 1408.0 1626.0 484.0 369.0 149.0 818.0 53.0 368.0 182.0 NT Temperature °C (on-site)-NE 14.2 13.5 13.5 14.1 16.0 15.6 15.0 14.0 14.9 15.0 12.5 17.3 14.4 NT Turbidity NTU (on-site)NT NE NT 2.68 8.42 14.57 10.74 5.18 10.86 2.50 20.87 2.70 12.03 4.15 3.01 NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 700 222 16.1 55.2 211 889 1240 325 200 17.7 216 22.8 152 191 ND Total Beryllium (Be)mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 10 13.3 ND ND 6.8 ND ND ND ND ND ND ND ND ND ND Total Cobalt (Co)mg/l 5 NE 7.2 ND ND ND 12.1 6.4 5.1 ND ND ND ND 101 ND ND Total Copper (Cu)mg/l 5 1000 7.8 ND 5.4 ND ND ND ND ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 15 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 100 7.2 ND ND 5.9 12.3 13.2 21.7 30.9 ND ND ND 10.6 ND ND Total Selenium (Se)mg/l 10 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND ND ND ND ND 14.1 ND ND Total Vanadium (V)mg/l 5 NE 21.6 ND ND 6.5 ND ND ND ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 1000 21.9 ND ND ND ND ND ND ND ND ND ND ND ND ND Acetone mg/l 25 6000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Benzene mg/l 1 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromoform mg/l 1 4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 700 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 0.3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 50 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroethane mg/l 1 3000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloroform mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 0.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 0.02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 20 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 100 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 0.6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Ethylbenzene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 4000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Styrene mg/l 1 70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 0.7 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Toluene mg/l 1 600 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 200 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 3 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 2000 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 0.005 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND ND ND ND ND ND ND ND Vinyl chloride mg/l 1 0.03 ND ND ND ND ND ND ND ND ND ND ND ND ND ND total Xylenes mg/l 2 500 ND ND ND ND ND ND ND ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable NT = Not Tested to Groundwaters of North Carolina, Section 15A NCAC 2L.202.NE = Not Established; North Carolina has not established a MCL MRL = Laboratory Method Reporting Limit NP = Not Present during sampling event ND = Not Detected at the method detection limit Shaded cells indicate exceedance of MCLs. NS = Not Sampled 1957-55 White Oak GW Stats 1st 2016.xlsm (4-19-16) APPENDIX B SUMMARY TABLES OF SURFACE WATER ANALYTICAL RESULTS White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-2000) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-4 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.4 6.3 6.7 6.4 NS NS NS 7.8 Specific Conductance mmhos/cm (on-site)1 NE 65 65 59 65 NS NS NS 2600 Temperature °C (on-site)-29 11 11 14 11 NS NS NS 11 Turbidity NTU (on-site)NT 50 NT NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NS 300 Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NT NS NS NS 95 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NS NS NS 95 Sulfate mg/l 500 NE NT NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NS NS NS 190 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NS NS NS 670 Total Dissolved Solids mg/l 20 NE NT NT NT NT NS NS NS 2700 Cyanide mg/l 2 5 NT NT NT NT NS NS NS 13 Total Antimony (Sb)mg/l 30 NE ND ND ND 25 NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 91 70 29 62 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND 2 ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND ND NS NS NS 13 Total Cobalt (Co)mg/l 10 NE ND ND ND 16 NS NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND ND NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND ND NS NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND 3.8 NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND ND NS NS NS 2 Total Vanadium (V)mg/l 40 NE ND ND ND ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 13 26 14 ND NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NT NS NS NS 0.3 Acetone mg/l 100 NE NT NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-24-2000) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-9-2001) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7 7.1 7.1 NS NS NS 8.1 Specific Conductance mmhos/cm (on-site)1 NE 73 80 75 NS NS NS 3600 Temperature °C (on-site)-29 11 13 18 NS NS NS 15 Turbidity NTU (on-site)NT 50 NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS ND Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NS NS NS 120 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NS NS 120 Sulfate mg/l 500 NE NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NS NS 240 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NS NS 430 Total Dissolved Solids mg/l 20 NE NT NT NT NS NS NS 5000 Cyanide mg/l 2 5 NT NT NT NS NS NS ND Total Antimony (Sb)mg/l 30 NE ND ND ND NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 99 81 55 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS NS NS 10 Total Cobalt (Co)mg/l 10 NE ND ND ND NS NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND NS NS NS 210 Total Silver (Ag)mg/l 10 0.06 ND ND ND NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS NS NS ND Total Vanadium (V)mg/l 40 NE ND ND ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 15 31 20 NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NS NS NS ND Acetone mg/l 100 NE NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-9-2001) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (9-18-2001) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 NS NS NS 7.48 NS NS NS Specific Conductance mmhos/cm (on-site)1 NE NS NS NS 160 NS NS NS Temperature °C (on-site)-29 NS NS NS 20 NS NS NS Turbidity NTU (on-site)NT 50 NS NS NS NT NS NS NS Nitrate as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrate/Nitrite as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrite as N mg/l 0.1 NE NS NS NS NT NS NS NS Nitrogen mg/l 0.2 NE NS NS NS NT NS NS NS Total Nitrogen, Kjeldahl mg/l 100 NE NS NS NS NT NS NS NS Sulfate mg/l 500 NE NS NS NS NT NS NS NS Biochemical Oxygen Demand mg/l 2 NE NS NS NS NT NS NS NS Chemical Oxygen Demand mg/l 25 NE NS NS NS NT NS NS NS Total Dissolved Solids mg/l 20 NE NS NS NS NT NS NS NS Cyanide mg/l 2 5 NS NS NS NT NS NS NS Total Antimony (Sb)mg/l 30 NE NS NS NS ND NS NS NS Total Arsenic (As)mg/l 10 10 NS NS NS ND NS NS NS Total Barium (Ba)mg/l 500 NE NS NS NS 71 NS NS NS Total Beryllium (Be)mg/l 2 6.5 NS NS NS ND NS NS NS Total Cadmium (Cd)mg/l 1 0.4 NS NS NS ND NS NS NS Total Chromium (Cr)mg/l 10 50 NS NS NS ND NS NS NS Total Cobalt (Co)mg/l 10 NE NS NS NS 7.2 NS NS NS Total Copper (Cu)mg/l 200 7 NS NS NS ND NS NS NS Total Lead (Pb)mg/l 10 25 NS NS NS ND NS NS NS Total Nickel (Ni)mg/l 50 88 NS NS NS 9.4 NS NS NS Total Selenium (Se)mg/l 20 5 NS NS NS ND NS NS NS Total Silver (Ag)mg/l 10 0.06 NS NS NS ND NS NS NS Total Thallium (Tl)mg/l 10 NE NS NS NS ND NS NS NS Total Vanadium (V)mg/l 40 NE NS NS NS ND NS NS NS Total Zinc (Zn)mg/l 50 50 NS NS NS 11 NS NS NS Mercury mg/l 0.2 0.012 NS NS NS NT NS NS NS Acetone mg/l 100 NE NS NS NS NT NS NS NS Acrylonitrile mg/l 200 NE NS NS NS NT NS NS NS Benzene mg/l 5 51 NS NS NS NT NS NS NS Bromochloromethane mg/l 5 NE NS NS NS NT NS NS NS Bromodichloromethane mg/l 5 NE NS NS NS NT NS NS NS Bromoform mg/l 5 NE NS NS NS NT NS NS NS Carbon Disulfide mg/l 100 NE NS NS NS NT NS NS NS Bromomethane (Methylbromide)mg/l 10 NE NS NS NS NT NS NS NS Carbon tetrachloride mg/l 10 1.6 NS NS NS NT NS NS NS Chlorobenzene (mono)mg/l 5 NE NS NS NS NT NS NS NS Chloroethane mg/l 10 NE NS NS NS NT NS NS NS Chloroform mg/l 5 NE NS NS NS NT NS NS NS Chloromethane (Methylchloride)mg/l 10 NE NS NS NS NT NS NS NS Dibromochloromethane mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NS NS NS NT NS NS NS 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NS NS NS NT NS NS NS Dibromomethane mg/l 10 NE NS NS NS NT NS NS NS 1,2-Dichlorobenzene mg/l 5 NE NS NS NS NT NS NS NS 1,4-Dichlorobenzene mg/l 5 NE NS NS NS NT NS NS NS trans-1,4-Dichloro-2butene mg/l 100 NE NS NS NS NT NS NS NS 1,1-Dichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1-Dichloroethene (-ethylene)mg/l 5 NE NS NS NS NT NS NS NS cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NS NS NS NT NS NS NS trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NS NS NS NT NS NS NS 1,2-Dichloropropane mg/l 5 NE NS NS NS NT NS NS NS cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NS NS NS trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NS NS NS NT NS NS NS Ethylbenzene mg/l 5 NE NS NS NS NT NS NS NS 2-Hexanone mg/l 50 NE NS NS NS NT NS NS NS Iodomethane mg/l 10 NE NS NS NS NT NS NS NS Dichloromethane (Methylene chloride)mg/l 10 NE NS NS NS NT NS NS NS 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NS NS NS NT NS NS NS 4-Methyl-2-Pentanone mg/l 100 NE NS NS NS NT NS NS NS Styrene mg/l 10 NE NS NS NS NT NS NS NS 1,1,1,2-Tetrachloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1,2,2-Tetrachloroethane mg/l 5 4 NS NS NS NT NS NS NS Tetrachloroethene (-ethylene)mg/l 5 3.3 NS NS NS NT NS NS NS Toluene mg/l 5 0.36 NS NS NS NT NS NS NS 1,1,1-Trichloroethane mg/l 5 NE NS NS NS NT NS NS NS 1,1,2-Trichloroethane mg/l 5 NE NS NS NS NT NS NS NS Trichloroethene (-ethylene)mg/l 5 30 NS NS NS NT NS NS NS Trichlorofluoromethane mg/l 5 NE NS NS NS NT NS NS NS 1,2,3-Trichloropropane mg/l 15 NE NS NS NS NT NS NS NS Vinyl acetate mg/l 50 NE NS NS NS NT NS NS NS Vinyl chloride mg/l 10 2.4 NS NS NS NT NS NS NS Xylene mg/l 5 NE NS NS NS NT NS NS NS Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (9-18-2001) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-15-2002) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.67 6.08 6.46 7 NS NS 6.71 Specific Conductance mmhos/cm (on-site)1 NE 78 78 80 170 NS NS 265 Temperature °C (on-site)-29 17.8 13.3 19.4 20 NS NS 20.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NT NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS 0.3 Nitrite as N mg/l 0.1 NE NT NT NT NT NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NT NS NS 96 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NS NS 96 Sulfate mg/l 500 NE NT NT NT NT NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NS NS 740 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NS NS 1400 Total Dissolved Solids mg/l 20 NE NT NT NT NT NS NS 2300 Cyanide mg/l 2 5 NT NT NT NT NS NS 0.006 Total Antimony (Sb)mg/l 30 NE ND ND ND ND NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND ND NS NS NT Total Barium (Ba)mg/l 500 NE 92 91 40 140 NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND ND NS NS 34 Total Cobalt (Co)mg/l 10 NE ND ND ND 7.7 NS NS NT Total Copper (Cu)mg/l 200 7 ND ND ND ND NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND ND NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND 9 NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND ND NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND ND NS NS ND Total Vanadium (V)mg/l 40 NE ND ND ND 6.5 NS NS NT Total Zinc (Zn)mg/l 50 50 ND 37 32 60 NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NT NS NS ND Acetone mg/l 100 NE NT NT NT NT NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NT NS NS NT Benzene mg/l 5 51 NT NT NT NT NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NT NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NT NS NS NT Bromoform mg/l 5 NE NT NT NT NT NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NT NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NT NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NT NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NT NS NS NT Chloroethane mg/l 10 NE NT NT NT NT NS NS NT Chloroform mg/l 5 NE NT NT NT NT NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NT NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NT NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NT NS NS NT Dibromomethane mg/l 10 NE NT NT NT NT NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NT NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NT NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NT NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NT NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NT NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NT NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NT NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NT NS NS NT Iodomethane mg/l 10 NE NT NT NT NT NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NT NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NT NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NT NS NS NT Styrene mg/l 10 NE NT NT NT NT NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NT NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NT NS NS NT Toluene mg/l 5 0.36 NT NT NT NT NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NT NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NT NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NT NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NT NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NT NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NT NS NS NT Xylene mg/l 5 NE NT NT NT NT NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-15-2002) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (9-26-2002) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.9 6.88 7.01 NS NS NS 7.48 Specific Conductance mmhos/cm (on-site)1 NE 102 151 115 NS NS NS 3700 Temperature °C (on-site)-29 16.5 17.2 17.5 NS NS NS 18.4 Turbidity NTU (on-site)NT 50 NT NT NT NS NS NS NT Nitrate as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS ND Nitrite as N mg/l 0.1 NE NT NT NT NS NS NS NT Nitrogen mg/l 0.2 NE NT NT NT NS NS NS ND Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NS NS 130 Sulfate mg/l 500 NE NT NT NT NS NS NS NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NS NS 210 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NS NS 1300 Total Dissolved Solids mg/l 20 NE NT NT NT NS NS NS 3000 Cyanide mg/l 2 5 NT NT NT NS NS NS 2.5 Total Antimony (Sb)mg/l 30 NE ND ND ND NS NS NS NT Total Arsenic (As)mg/l 10 10 ND ND ND NS NS NS NT Total Barium (Ba)mg/l 500 NE 150 160 80 NS NS NS NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS NS NS NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS NS NS NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS NS NS 34 Total Cobalt (Co)mg/l 10 NE 7.2 ND ND NS NS NS NT Total Copper (Cu)mg/l 200 7 ND 4.5 2.7 NS NS NS NT Total Lead (Pb)mg/l 10 25 ND ND ND NS NS NS ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS NS NS NT Total Selenium (Se)mg/l 20 5 ND ND ND NS NS NS ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS NS NS NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS NS NS ND Total Vanadium (V)mg/l 40 NE ND 6.4 ND NS NS NS NT Total Zinc (Zn)mg/l 50 50 19 100 41 NS NS NS NT Mercury mg/l 0.2 0.012 NT NT NT NS NS NS ND Acetone mg/l 100 NE NT NT NT NS NS NS NT Acrylonitrile mg/l 200 NE NT NT NT NS NS NS NT Benzene mg/l 5 51 NT NT NT NS NS NS NT Bromochloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromodichloromethane mg/l 5 NE NT NT NT NS NS NS NT Bromoform mg/l 5 NE NT NT NT NS NS NS NT Carbon Disulfide mg/l 100 NE NT NT NT NS NS NS NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NS NS NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NS NS NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NS NS NT Chloroethane mg/l 10 NE NT NT NT NS NS NS NT Chloroform mg/l 5 NE NT NT NT NS NS NS NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NS NS NT Dibromochloromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NS NS NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NS NS NT Dibromomethane mg/l 10 NE NT NT NT NS NS NS NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NS NS NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NS NS NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NS NS NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NS NS NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NS NS NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NS NS NT Ethylbenzene mg/l 5 NE NT NT NT NS NS NS NT 2-Hexanone mg/l 50 NE NT NT NT NS NS NS NT Iodomethane mg/l 10 NE NT NT NT NS NS NS NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NS NS NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NS NS NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NS NS NT Styrene mg/l 10 NE NT NT NT NS NS NS NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NS NS NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NS NS NT Toluene mg/l 5 0.36 NT NT NT NS NS NS NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NS NS NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NS NS NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NS NS NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NS NS NT Vinyl acetate mg/l 50 NE NT NT NT NS NS NS NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NS NS NT Xylene mg/l 5 NE NT NT NT NS NS NS NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (9-26-2002) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-29-2003) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.91 6.42 7.17 NS 6.41 6.71 NT Specific Conductance mmhos/cm (on-site)1 NE 77 75 101 NS 19 29 NT Temperature °C (on-site)-29 11.8 13 16 NS 15.6 14.9 NT Turbidity NTU (on-site)NT 50 NT NT NT NS NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NS NT NT 220 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NT NT 220 Sulfate mg/l 500 NE NT NT NT NS NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NT NT 2500 Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NT NT 1100 Total Dissolved Solids mg/l 20 NE NT NT NT NS NT NT 120 Cyanide mg/l 2 5 NT NT NT NS NT NT 110 Total Antimony (Sb)mg/l 30 NE ND ND ND NS ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND NS ND ND 15 Total Barium (Ba)mg/l 500 NE 90 82 64 NS 27 27 270 Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS ND ND 2.5 Total Chromium (Cr)mg/l 10 50 ND ND ND NS ND ND ND Total Cobalt (Co)mg/l 10 NE ND ND ND NS ND ND 16 Total Copper (Cu)mg/l 200 7 ND ND ND NS ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND NS ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS ND ND ND Total Selenium (Se)mg/l 20 5 ND ND ND NS ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS ND ND 2.4 Total Thallium (Tl)mg/l 10 NE ND ND ND NS ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND NS ND ND 19 Total Zinc (Zn)mg/l 50 50 ND 45 20 NS ND ND 1000 Mercury mg/l 0.2 0.012 NT NT NT NS NT NT NT Acetone mg/l 100 NE NT NT NT NS NT NT NT Acrylonitrile mg/l 200 NE NT NT NT NS NT NT NT Benzene mg/l 5 51 NT NT NT NS NT NT NT Bromochloromethane mg/l 5 NE NT NT NT NS NT NT NT Bromodichloromethane mg/l 5 NE NT NT NT NS NT NT NT Bromoform mg/l 5 NE NT NT NT NS NT NT NT Carbon Disulfide mg/l 100 NE NT NT NT NS NT NT NT Bromomethane (Methylbromide)mg/l 10 NE NT NT NT NS NT NT NT Carbon tetrachloride mg/l 10 1.6 NT NT NT NS NT NT NT Chlorobenzene (mono)mg/l 5 NE NT NT NT NS NT NT NT Chloroethane mg/l 10 NE NT NT NT NS NT NT NT Chloroform mg/l 5 NE NT NT NT NS NT NT NT Chloromethane (Methylchloride)mg/l 10 NE NT NT NT NS NT NT NT Dibromochloromethane mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE NT NT NT NS NT NT NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE NT NT NT NS NT NT NT Dibromomethane mg/l 10 NE NT NT NT NS NT NT NT 1,2-Dichlorobenzene mg/l 5 NE NT NT NT NS NT NT NT 1,4-Dichlorobenzene mg/l 5 NE NT NT NT NS NT NT NT trans-1,4-Dichloro-2butene mg/l 100 NE NT NT NT NS NT NT NT 1,1-Dichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NT NT NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE NT NT NT NS NT NT NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE NT NT NT NS NT NT NT 1,2-Dichloropropane mg/l 5 NE NT NT NT NS NT NT NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NT NT NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE NT NT NT NS NT NT NT Ethylbenzene mg/l 5 NE NT NT NT NS NT NT NT 2-Hexanone mg/l 50 NE NT NT NT NS NT NT NT Iodomethane mg/l 10 NE NT NT NT NS NT NT NT Dichloromethane (Methylene chloride)mg/l 10 NE NT NT NT NS NT NT NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE NT NT NT NS NT NT NT 4-Methyl-2-Pentanone mg/l 100 NE NT NT NT NS NT NT NT Styrene mg/l 10 NE NT NT NT NS NT NT NT 1,1,1,2-Tetrachloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1,2,2-Tetrachloroethane mg/l 5 4 NT NT NT NS NT NT NT Tetrachloroethene (-ethylene)mg/l 5 3.3 NT NT NT NS NT NT NT Toluene mg/l 5 0.36 NT NT NT NS NT NT NT 1,1,1-Trichloroethane mg/l 5 NE NT NT NT NS NT NT NT 1,1,2-Trichloroethane mg/l 5 NE NT NT NT NS NT NT NT Trichloroethene (-ethylene)mg/l 5 30 NT NT NT NS NT NT NT Trichlorofluoromethane mg/l 5 NE NT NT NT NS NT NT NT 1,2,3-Trichloropropane mg/l 15 NE NT NT NT NS NT NT NT Vinyl acetate mg/l 50 NE NT NT NT NS NT NT NT Vinyl chloride mg/l 10 2.4 NT NT NT NS NT NT NT Xylene mg/l 5 NE NT NT NT NS NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-29-2003) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-30-2003) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.41 7.38 7.42 NS 5.87 7.14 8.37 Specific Conductance mmhos/cm (on-site)1 NE 80 80 80 NS 19 29 3500 Temperature °C (on-site)-29 12 12 12 NS 14.2 15.1 19.3 Turbidity NTU (on-site)NT 50 NT NT NT NS NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NS NT NT 3.4 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT 3.4 Nitrite as N mg/l 0.1 NE NT NT NT NS NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NS NT NT 72 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NS NT NT 69 Sulfate mg/l 500 NE NT NT NT NS NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT NT NT NS NT NT ND Chemical Oxygen Demand mg/l 25 NE NT NT NT NS NT NT 250 Total Dissolved Solids mg/l 20 NE NT NT NT NS NT NT 2500 Cyanide mg/l 2 5 NT NT NT NS NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND NS ND ND NT Total Arsenic (As)mg/l 10 10 ND ND ND NS 5.5 ND NT Total Barium (Ba)mg/l 500 NE 110 130 84 NS 24 27 NT Total Beryllium (Be)mg/l 2 6.5 ND ND ND NS ND ND NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NS ND ND NT Total Chromium (Cr)mg/l 10 50 ND ND ND NS ND ND 10 Total Cobalt (Co)mg/l 10 NE ND ND ND NS ND ND NT Total Copper (Cu)mg/l 200 7 ND 2.7 2.2 NS 2.2 ND NT Total Lead (Pb)mg/l 10 25 ND ND ND NS ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND NS ND ND NT Total Selenium (Se)mg/l 20 5 ND ND ND NS ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND NS ND ND NT Total Thallium (Tl)mg/l 10 NE ND ND ND NS ND ND ND Total Vanadium (V)mg/l 40 NE ND 5.3 ND NS ND ND NT Total Zinc (Zn)mg/l 50 50 ND 80 40 NS 14 ND NT Mercury mg/l 0.2 0.012 NT NT NT NS NT NT ND Acetone mg/l 100 NE ND ND ND NS ND ND NT Acrylonitrile mg/l 200 NE ND ND ND NS ND ND NT Benzene mg/l 5 51 ND ND ND NS ND ND NT Bromochloromethane mg/l 5 NE ND ND ND NS ND ND NT Bromodichloromethane mg/l 5 NE ND ND ND NS ND ND NT Bromoform mg/l 5 NE ND ND ND NS ND ND NT Carbon Disulfide mg/l 100 NE ND ND ND NS ND 11 NT Bromomethane (Methylbromide)mg/l 10 NE ND ND ND NS ND ND NT Carbon tetrachloride mg/l 10 1.6 ND ND ND NS ND ND NT Chlorobenzene (mono)mg/l 5 NE ND ND ND NS ND ND NT Chloroethane mg/l 10 NE ND ND ND NS ND ND NT Chloroform mg/l 5 NE ND ND ND NS ND ND NT Chloromethane (Methylchloride)mg/l 10 NE ND ND ND NS ND ND NT Dibromochloromethane mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND NS ND ND NT 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND NS ND ND NT Dibromomethane mg/l 10 NE ND ND ND NS ND ND NT 1,2-Dichlorobenzene mg/l 5 NE ND ND ND NS ND ND NT 1,4-Dichlorobenzene mg/l 5 NE ND ND ND NS ND ND NT trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND NS ND ND NT 1,1-Dichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND NS ND ND NT cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND NS ND ND NT trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND NS ND ND NT 1,2-Dichloropropane mg/l 5 NE ND ND ND NS ND ND NT cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND NS ND ND NT trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND NS ND ND NT Ethylbenzene mg/l 5 NE ND ND ND NS ND ND NT 2-Hexanone mg/l 50 NE ND ND ND NS ND ND NT Iodomethane mg/l 10 NE ND ND ND NS ND ND NT Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND NS ND ND NT 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND NS ND ND NT 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND NS ND ND NT Styrene mg/l 10 NE ND ND ND NS ND ND NT 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND NS ND ND NT Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND NS ND ND NT Toluene mg/l 5 0.36 ND ND ND NS ND ND NT 1,1,1-Trichloroethane mg/l 5 NE ND ND ND NS ND ND NT 1,1,2-Trichloroethane mg/l 5 NE ND ND ND NS ND ND NT Trichloroethene (-ethylene)mg/l 5 30 ND ND ND NS ND ND NT Trichlorofluoromethane mg/l 5 NE ND ND ND NS ND ND NT 1,2,3-Trichloropropane mg/l 15 NE ND ND ND NS ND ND NT Vinyl acetate mg/l 50 NE ND ND ND NS ND ND NT Vinyl chloride mg/l 10 2.4 ND ND ND NS ND ND NT Xylene mg/l 5 NE ND ND ND NS ND ND NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-30-2003) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-20-2004) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.05 7.19 8.05 6.19 6.35 8.37 Specific Conductance mmhos/cm (on-site)1 NE 74 73 142 1790 19 29 4050 Temperature °C (on-site)-29 13 13 15 17 17 16 28.4 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.11 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.11 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 640 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 470 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1100 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 120 95 83 260 18 26 140 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 28 Total Cobalt (Co)mg/l 10 NE ND ND ND 26 ND ND 17 Total Copper (Cu)mg/l 200 7 ND ND 3.1 ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND 12 ND ND 45 Total Selenium (Se)mg/l 20 5 ND ND ND 6 ND ND 8 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND 12 Total Zinc (Zn)mg/l 50 50 ND 48 31 310 15 ND 62 Mercury mg/l 0.2 0.012 NT NT NT ND NT NT ND Acetone mg/l 100 NE ND ND ND ND ND ND 490 Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND 14 Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 300 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-20-2004) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-21-2004) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.06 6.62 NS 7.16 7.42 6.41 7.89 Specific Conductance mmhos/cm (on-site)1 NE 103 103 NS 129 26 38 3270 Temperature °C (on-site)-29 14 14.5 NS 15 15 16 23.4 Turbidity NTU (on-site)NT 50 NT NT NS NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NS NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NS NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NS NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NS NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NS NT NT NT NT Sulfate mg/l 500 NE NT NT NS NT NT NT 34 Biochemical Oxygen Demand mg/l 2 NE NT NT NS NT NT NT 640 Chemical Oxygen Demand mg/l 25 NE NT NT NS NT NT NT 1300 Total Dissolved Solids mg/l 20 NE NT NT NS NT NT NT NT Cyanide mg/l 2 5 NT NT NS NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND NS ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND NS ND ND ND 10 Total Barium (Ba)mg/l 500 NE 100 100 NS 87 24 31 160 Total Beryllium (Be)mg/l 2 6.5 ND ND NS ND 2.6 ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND NS ND 2.1 ND ND Total Chromium (Cr)mg/l 10 50 ND ND NS ND 3.7 2.3 26 Total Cobalt (Co)mg/l 10 NE ND ND NS 6.5 ND ND ND Total Copper (Cu)mg/l 200 7 ND ND NS ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND NS ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND NS ND ND ND 24 Total Selenium (Se)mg/l 20 5 ND ND NS ND ND ND 6.2 Total Silver (Ag)mg/l 10 0.06 ND ND NS ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND NS ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND NS ND ND ND 8.2 Total Zinc (Zn)mg/l 50 50 ND 44 NS 17 12 13 43 Mercury mg/l 0.2 0.012 NT NT NS NT NT NT NT Acetone mg/l 100 NE ND ND NS ND ND ND 290 Acrylonitrile mg/l 200 NE ND ND NS ND ND ND ND Benzene mg/l 5 51 ND ND NS ND ND ND ND Bromochloromethane mg/l 5 NE ND ND NS ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND NS ND ND ND ND Bromoform mg/l 5 NE ND ND NS ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND NS ND 39 32 ND Bromomethane (Methylbromide)mg/l 10 NE ND ND NS ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND NS ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND NS ND ND ND ND Chloroethane mg/l 10 NE ND ND NS ND ND ND ND Chloroform mg/l 5 NE ND ND NS ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND NS ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND NS ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND NS ND ND ND ND Dibromomethane mg/l 10 NE ND ND NS ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND NS ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND NS ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND NS ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND NS ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND NS ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND NS ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND NS ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND NS ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND NS ND ND ND ND Ethylbenzene mg/l 5 NE ND ND NS ND ND ND ND 2-Hexanone mg/l 50 NE ND ND NS ND ND ND ND Iodomethane mg/l 10 NE ND ND NS ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND NS ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND NS ND ND ND 260 4-Methyl-2-Pentanone mg/l 100 NE ND ND NS ND ND ND ND Styrene mg/l 10 NE ND ND NS ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND NS ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND NS ND ND ND ND Toluene mg/l 5 0.36 ND ND NS ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND NS ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND NS ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND NS ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND NS ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND NS ND ND ND ND Vinyl acetate mg/l 50 NE ND ND NS ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND NS ND ND ND ND Xylene mg/l 5 NE ND ND NS ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-21-2004) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-18-2005) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.49 5.99 6.21 7.05 7.08 7.27 7.28 Specific Conductance mmhos/cm (on-site)1 NE 79 88 151 120 21 28 6500 Temperature °C (on-site)-29 13 123 13.5 16 14.1 13 19 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1300 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 300 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 760 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 22 Total Barium (Ba)mg/l 500 NE 100 120 98 79 24 28 390 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 31 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND 14 Total Copper (Cu)mg/l 200 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 50 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND 7.4 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND 17 Total Zinc (Zn)mg/l 50 50 ND 50 22 34 ND ND 150 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND 240 Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND 11 trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 11 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 410 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND 40 Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 63 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 43 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-18-2005) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-13-2005) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.11 6.72 7.18 6.28 6.76 8.13 8.01 Specific Conductance mmhos/cm (on-site)1 NE 89 90 240 340 91 31 6500 Temperature °C (on-site)-29 15.7 16.9 16.9 18.9 18.7 15.2 21.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1300 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 720 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 920 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE NT NT NT ND NT NT NT Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 120 96 140 90 86 36 430 Total Beryllium (Be)mg/l 2 6.5 NT NT NT ND NT NT NT Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND 4.2 ND ND 50 Total Cobalt (Co)mg/l 10 NE NT NT NT 6.8 NT NT NT Total Copper (Cu)mg/l 200 7 NT NT NT 2.4 NT NT NT Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 NT NT NT ND NT NT NT Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND 9.2 Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE NT NT NT ND NT NT NT Total Vanadium (V)mg/l 40 NE NT NT NT ND NT NT NT Total Zinc (Zn)mg/l 50 50 NT NT NT 33 NT NT NT Mercury mg/l 0.2 0.012 NT NT NT NT NT NT ND Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-13-2005) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-25-2006) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.07 7.11 7.18 6.73 6.45 6.28 7.55 Specific Conductance mmhos/cm (on-site)1 NE 107 138 340 201 45 53 8660 Temperature °C (on-site)-29 14.1 13.8 15.6 18.6 14.8 14.3 17.1 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 2.4 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 2.4 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2400 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 51 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 700 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 18 Total Barium (Ba)mg/l 500 NE ND ND ND ND ND ND 580 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 40 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND 15 Total Copper (Cu)mg/l 200 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND 11 ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 56 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 50 50 ND ND ND ND ND ND 130 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 6.2 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND 24 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND 15 Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 12 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 16.1 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-25-2006) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-16-2006) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.53 7.1 NT 7.14 6.64 7.13 8.11 Specific Conductance mmhos/cm (on-site)1 NE 123 139 NT 200 46 40 9800 Temperature °C (on-site)-29 11.9 10.9 NT 11.9 13.4 11.3 19.6 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.58 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2100 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 61 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 780 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 18 Total Barium (Ba)mg/l 500 NE 120 140 120 240 54 33 430 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND 5.8 ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND 21 ND ND 54 Total Cobalt (Co)mg/l 10 NE ND ND ND ND 7.4 ND 14 Total Copper (Cu)mg/l 200 7 ND ND ND 23 ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND 18 ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND 8.4 ND ND 68 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND 62 ND ND 18 Total Zinc (Zn)mg/l 50 50 ND 39 22 130 ND ND 63 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-16-2006) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-23-2007) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 NT NT NT NT NT NT NT Specific Conductance mmhos/cm (on-site)1 NE NT NT NT NT NT NT NT Temperature °C (on-site)-29 NT NT NT NT NT NT NT Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.38 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.2 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 2400 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 89 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1000 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 30 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 16 Total Barium (Ba)mg/l 500 NE 100 120 250 ND ND ND 380 Total Beryllium (Be)mg/l 2 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 10 50 ND ND ND ND ND ND 46 Total Cobalt (Co)mg/l 10 NE ND ND ND ND ND ND ND Total Copper (Cu)mg/l 200 7 ND ND ND 38 ND ND ND Total Lead (Pb)mg/l 10 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 50 88 ND ND ND ND ND ND 50 Total Selenium (Se)mg/l 20 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 10 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 10 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 40 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 50 50 13 37 130 91 15 11 80 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 100 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 200 NE ND ND ND ND ND ND ND Benzene mg/l 5 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 5 NE ND ND ND ND ND ND ND Bromoform mg/l 5 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 100 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 10 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 10 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 5 NE ND ND ND ND ND ND ND Chloroethane mg/l 10 NE ND ND ND ND ND ND ND Chloroform mg/l 5 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 10 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 25 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 5 NE ND ND ND ND ND ND ND Dibromomethane mg/l 10 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 5 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 100 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 5 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 5 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 10 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 5 NE ND ND ND ND ND ND 10 2-Hexanone mg/l 50 NE ND ND ND ND ND ND ND Iodomethane mg/l 10 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 10 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 100 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 100 NE ND ND ND ND ND ND ND Styrene mg/l 10 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 5 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 5 3.3 ND ND ND ND ND ND ND Toluene mg/l 5 0.36 ND ND ND ND ND ND 46 1,1,1-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 5 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 5 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 5 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 15 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 50 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 10 2.4 ND ND ND ND ND ND ND Xylene mg/l 5 NE ND ND ND ND ND ND 31.3 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-23-2007) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-31-07) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.04 7.11 6.8 7.5 6.35 6.74 8.03 Specific Conductance mmhos/cm (on-site)1 NE 156 150 266 320 61 40 1282 Temperature °C (on-site)-29 16.5 13.4 12.7 17.2 11.5 9 14.3 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.53 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 3010 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 221 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 968 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 24.6 Total Barium (Ba)mg/l 5 NE 583 154 162 85 111 30.3 436 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 25.7 ND ND ND ND ND 74.1 Total Cobalt (Co)mg/l 5 NE 10.5 ND ND ND ND ND 12 Total Copper (Cu)mg/l 5 7 18.4 ND ND ND 8.3 ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 18.1 ND ND ND ND ND 81.2 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.5 NE 6.3 ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 56.2 ND ND 6.8 11.4 ND 23.9 Total Zinc (Zn)mg/l 10 50 135 71.9 60 41.3 20.4 ND 76.7 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-31-07) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (04-23-08) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.32 7.06 7.2 7.56 7 8.56 Specific Conductance mmhos/cm (on-site)1 NE 124 162 234 426 48 42 8140 Temperature °C (on-site)-29 13.1 14.5 14.3 16.9 15.2 15.6 21.4 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrogen mg/l 0.1 NE NT NT NT NT NT NT ND Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1940 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 741 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 1620 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 9.5 Total Barium (Ba)mg/l 5 NE 111 145 133 184 34.4 24.9 247 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND 1.5 ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND 6.5 ND ND 28.9 Total Cobalt (Co)mg/l 5 NE ND ND ND 11.2 ND ND 9 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 7.6 ND ND 51.3 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.5 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND 14.4 ND ND 9.1 Total Zinc (Zn)mg/l 10 50 ND 52.3 50.1 124 ND ND 52.3 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 34.1 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, and .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (04-23-08) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-21-08) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.51 6.75 6.84 6.54 6.08 6.45 8.63 Specific Conductance mmhos/cm (on-site)1 NE 202 171 296 205.6 56.1 41 10780 Temperature °C (on-site)-29 11.3 10.2 7.9 12.5 10.8 9.6 22.2 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.14 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.14 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 58.3 Biochemical Oxygen Dema mg/l 2 NE NT NT NT NT NT NT 198 Chemical Oxygen Dema mg/l 100 NE NT NT NT NT NT NT 1190 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND 6 6.7 ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 11.4 Total Barium (Ba)mg/l 5 NE 285 126 137 289 145 25.2 317 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND 17.9 ND ND 34.5 Total Cobalt (Co)mg/l 5 NE 7.9 5 6.4 34.4 21.1 ND 14.4 Total Copper (Cu)mg/l 5 7 ND ND ND 15.8 10.1 ND ND Total Lead (Pb)mg/l 5 25 ND ND ND 5.4 ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 12.1 6 ND 57.6 Total Selenium (Se)mg/l 10 5 ND ND ND 14 13.2 ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND 7.2 ND ND ND Total Vanadium (V)mg/l 5 NE 9.9 ND ND 43.5 17.5 ND 12 Total Zinc (Zn)mg/l 10 50 19 75.4 39.4 116 29.5 16.7 27.6 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 37.2 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Xylene mg/l 2 NE ND ND ND ND ND ND ND Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-21-08) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-22-09) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.29 6.47 6.79 6.75 5.83 5.97 8.24 Specific Conductance mmhos/cm (on-site)1 NE 139 208 319 366 40 52 7620 Temperature °C (on-site)-29 11.1 10.8 9.8 12.2 11.9 12.6 19.6 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.16 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.29 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.12 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 500 NE NT NT NT NT NT NT 1570 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 55.8 Chemical Oxygen Demand mg/l 100 NE NT NT NT NT NT NT 694 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 11.3 Total Barium (Ba)mg/l 5 NE 108 167 133 70.1 35.9 41.1 181 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 16.7 Total Cobalt (Co)mg/l 5 NE ND ND ND 14.9 6.5 6.6 9.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND 5.6 ND ND 48.2 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND 8.1 ND ND 11.2 Total Zinc (Zn)mg/l 10 50 ND 50 36.6 80 ND ND 10.9 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 38.4 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 5.2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 13.7 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND 11.3 Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 7.3 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 65.1 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 9.0 Naphthalene mg/l 1 NE NT NT NT NT NT NT 6.7 Phosphorus mg/l 0.1 NE NT NT NT NT NT NT 0.75 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-22-09) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-26-09) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.41 Dry 6.49 Dry 6.07 6.26 7.8 Specific Conductance mmhos/cm (on-site)1 NE 192 Dry 291 Dry 60 58 NT Temperature °C (on-site)-29 11.5 Dry 11.0 Dry 13.6 12.4 NT Turbidity NTU (on-site)NT 50 NT Dry NT Dry NT NT NT Nitrate as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrite as N mg/l 0.1 NE NT Dry NT Dry NT NT NT Nitrogen mg/l 0.1 NE NT Dry NT Dry NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT Dry NT Dry NT NT NT Sulfate mg/l 500 NE NT Dry NT Dry NT NT NT Biochemical Oxygen Demand mg/l 2 NE NT Dry NT Dry NT NT 4.8 Chemical Oxygen Demand mg/l 100 NE NT Dry NT Dry NT NT 212 Total Dissolved Solids mg/l 20 NE NT Dry NT Dry NT NT NT Cyanide mg/l 2 5 NT Dry NT Dry NT NT NT Total Antimony (Sb)mg/l 5 NE ND Dry ND Dry ND ND ND Total Arsenic (As)mg/l 5 10 ND Dry ND Dry ND ND ND Total Barium (Ba)mg/l 5 NE 228 Dry 285 Dry 48.4 30.9 305 Total Beryllium (Be)mg/l 1 6.5 ND Dry ND Dry ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND Dry ND Dry ND ND ND Total Chromium (Cr)mg/l 5 50 ND Dry 8.9 Dry ND ND ND Total Cobalt (Co)mg/l 5 NE ND Dry 5.7 Dry 6.5 ND 12.5 Total Copper (Cu)mg/l 5 7 ND Dry 5.5 Dry ND ND ND Total Lead (Pb)mg/l 5 25 ND Dry ND Dry ND ND ND Total Nickel (Ni)mg/l 5 88 ND Dry 10.1 Dry ND ND 20.4 Total Selenium (Se)mg/l 10 5 ND Dry ND Dry ND ND ND Total Silver (Ag)mg/l 5 0.06 ND Dry ND Dry ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND Dry ND Dry ND ND ND Total Vanadium (V)mg/l 5 NE ND Dry 16.0 Dry ND ND 8.5 Total Zinc (Zn)mg/l 10 50 ND Dry 151 Dry ND ND 48.1 Mercury mg/l 0.2 0.012 NT Dry NT Dry NT NT NT Acetone mg/l 25 NE ND Dry ND Dry ND ND ND Acrylonitrile mg/l 10 NE ND Dry ND Dry ND ND ND Benzene mg/l 1 51 ND Dry ND Dry ND ND ND Bromochloromethane mg/l 1 NE ND Dry ND Dry ND ND ND Bromodichloromethane mg/l 1 NE ND Dry ND Dry ND ND ND Bromoform mg/l 1 NE ND Dry ND Dry ND ND ND Carbon Disulfide mg/l 2 NE ND Dry ND Dry ND ND ND Bromomethane (Methylbromide)mg/l 5 NE ND Dry ND Dry ND ND ND Carbon tetrachloride mg/l 1 1.6 ND Dry ND Dry ND ND ND Chlorobenzene (mono)mg/l 1 NE ND Dry ND Dry ND ND ND Chloroethane mg/l 1 NE ND Dry ND Dry ND ND ND Chloroform mg/l 1 NE ND Dry ND Dry ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND Dry ND Dry ND ND ND Dibromochloromethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND Dry ND Dry ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND Dry ND Dry ND ND ND Dibromomethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND Dry ND Dry ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND Dry ND Dry ND ND ND 1,1-Dichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND Dry ND Dry ND ND ND 1,2-Dichloropropane mg/l 1 NE ND Dry ND Dry ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND Dry ND Dry ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND Dry ND Dry ND ND ND Ethylbenzene mg/l 1 NE ND Dry ND Dry ND ND ND 2-Hexanone mg/l 5 NE ND Dry ND Dry ND ND ND Iodomethane mg/l 5 NE ND Dry ND Dry ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND Dry ND Dry ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND Dry ND Dry ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND Dry ND Dry ND ND ND Styrene mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND Dry ND Dry ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND Dry ND Dry ND ND ND Toluene mg/l 1 0.36 ND Dry ND Dry ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND Dry ND Dry ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND Dry ND Dry ND ND ND Trichlorofluoromethane mg/l 1 NE ND Dry ND Dry ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND Dry ND Dry ND ND ND Vinyl acetate mg/l 2 NE ND Dry ND Dry ND ND ND Vinyl chloride mg/l 1 2.4 ND Dry ND Dry ND ND ND Total Xylenes mg/l 2 NE ND Dry ND Dry ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l 5 NE NT Dry NT Dry NT NT ND Naphthalene mg/l 5 NE NT Dry NT Dry NT NT ND Phosphorus mg/l 0.1 NE NT Dry NT Dry NT NT NT Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-26-09) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-21-10) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.72 7.29 7.14 NP 6.06 6.04 7.69 Specific Conductance mmhos/cm (on-site)1 NE 189 213 273 NP 94 106 310 Temperature °C (on-site)-29 13.9 12.3 15.9 NP 15.7 14 13.3 Turbidity NTU (on-site)NT 50 NT NT NT NP NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrite as N mg/l 0.1 NE NT NT NT NP NT NT ND Nitrogen mg/l 0.1 NE NT NT NT NP NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NP NT NT NT Sulfate mg/l 75 NE NT NT NT NP NT NT 477 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NP NT NT 54 Chemical Oxygen Demand mg/l 25 NE NT NT NT NP NT NT 203 Total Dissolved Solids mg/l 20 NE NT NT NT NP NT NT NT Cyanide mg/l 2 5 NT NT NT NP NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND NP ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND NP ND ND 8.6 Total Barium (Ba)mg/l 5 NE 123 178 172 NP 34.3 41.4 124 Total Beryllium (Be)mg/l 1 6.5 ND ND ND NP ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND NP ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND NP ND ND 8 Total Cobalt (Co)mg/l 5 NE ND ND ND NP ND ND 11.7 Total Copper (Cu)mg/l 5 7 ND ND ND NP ND ND 6.8 Total Lead (Pb)mg/l 5 25 ND ND ND NP ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND NP ND ND 35.3 Total Selenium (Se)mg/l 10 5 ND ND ND NP ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND NP ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND NP ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND NP ND ND 6.8 Total Zinc (Zn)mg/l 10 50 ND 49.8 32.9 NP ND ND 12.1 Mercury mg/l 0.2 0.012 NT NT NT NP NT NT NT Acetone mg/l 25 NE ND ND ND NP ND ND ND Acrylonitrile mg/l 10 NE ND ND ND NP ND ND NT Benzene mg/l 1 51 ND ND ND NP ND ND ND Bromochloromethane mg/l 1 NE ND ND ND NP ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND NP ND ND ND Bromoform mg/l 1 NE ND ND ND NP ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND NP ND ND NT Bromomethane (Methylbromide)mg/l 5 NE ND ND ND NP ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND NP ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND NP ND ND ND Chloroethane mg/l 1 NE ND ND ND NP ND ND ND Chloroform mg/l 1 NE ND ND ND NP ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND NP ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 3 NE ND ND ND NP ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND NP ND ND ND Dibromomethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND NP ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND NP ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND NP ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND 2 trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND NP ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND NP ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND NP ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND NP ND ND ND Ethylbenzene mg/l 1 NE ND ND ND NP ND ND ND 2-Hexanone mg/l 5 NE ND ND ND NP ND ND ND Iodomethane mg/l 5 NE ND ND ND NP ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND NP ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND NP ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND NP ND ND ND Styrene mg/l 1 NE ND ND ND NP ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND NP ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND NP ND ND ND Toluene mg/l 1 0.36 ND ND ND NP ND ND 1.1 1,1,1-Trichloroethane mg/l 1 NE ND ND ND NP ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND NP ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND NP ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND NP ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND NP ND ND ND Vinyl acetate mg/l 2 NE ND ND ND NP ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND NP ND ND ND Total Xylenes mg/l 2 NE ND ND ND NP ND ND NT Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NP NT NT ND Naphthalene mg/l 1 NE NT NT NT NP NT NT ND Phosphorus mg/l 0.1 NE NT NT NT NP NT NT 0.26 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL NP = Not Present during sampling event Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-21-10) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-26-10) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.31 6.14 7.15 6.11 5.7 6.39 7.31 Specific Conductance mmhos/cm (on-site)1 NE 203 250 287 158 50 53 20400 Temperature °C (on-site)-29 15.8 15.2 16.6 17.5 14.7 13.4 18.2 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 5.5 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 6 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.51 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 7670 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 40 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 96 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 13.9 Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 29.4 Total Barium (Ba)mg/l 5 NE 209 180 350 126 40.1 32.9 172 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND 1.3 Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND 13.2 ND ND ND 10.7 Total Cobalt (Co)mg/l 5 NE ND ND 17.7 48.8 ND ND ND Total Copper (Cu)mg/l 5 7 ND ND 9 ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND 9 5 ND ND 44.4 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND 29.6 Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND 27.9 ND ND ND 21 Total Zinc (Zn)mg/l 10 50 ND 31.2 60.6 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT ND NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND 1 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 3.4 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND 1.2 trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 6.8 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 8.4 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 10.9 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 5.7 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 2.9 Naphthalene mg/l 1 NE NT NT NT NT NT NT 6.5 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT 2.9 Phosphorus mg/l 0.1 NE NT NT NT NT NT NT 1.40 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-26-10) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-28-11) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.3 6.2 6.8 6 5.8 6.1 7.4 Specific Conductance mmhos/cm (on-site)1 NE 174 225 304 212 45 65 14,320 Temperature °C (on-site)-29 15.9 14.9 18.5 13.5 15.1 13.3 18.3 Turbidity NTU (on-site)NT 50 NT NT NT NT NT NT NT Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 8.5 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 9.6 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 1.1 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4360 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 55.2 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 762 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 13.5 Total Barium (Ba)mg/l 5 NE 238 204 130 156 38.7 43.6 243 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 5.2 ND ND ND ND ND 27.1 Total Cobalt (Co)mg/l 5 NE ND 5.4 ND 22.6 ND ND 32.6 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 159 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 11 ND ND ND ND ND 9.4 Total Zinc (Zn)mg/l 10 50 15.8 46.1 61.7 ND ND ND 32.1 Mercury mg/l 0.2 0.012 NT NT NT ND NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 40.6 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.7 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND 1.2 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 4.5 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 3.8 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 1.6 Naphthalene mg/l 1 NE NT NT NT NT NT NT 5.3 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT 1.8 Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.85 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-28-11) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-25-11) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.2 6.7 7.2 6 5.7 6.2 6.9 Specific Conductance mmhos/cm (on-site)1 NE 207 208 275 241 42 17 272 Temperature °C (on-site)-29 10.4 11.9 11.7 17.2 15.8 13 11.7 Turbidity NTU (on-site)NT 50 7.92 19.0 8.08 15.5 5.52 6.19 6.35 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.85 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.17 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 1 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 5170 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 63.9 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 908 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 7.2 Total Barium (Ba)mg/l 5 NE 170 168 126 140 32.7 30.7 261 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 35.4 Total Cobalt (Co)mg/l 5 NE ND 5 5 28.8 ND ND 19.7 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 170 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 14.0 Total Zinc (Zn)mg/l 10 50 ND 33.6 56.1 ND ND ND 18.0 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 43.9 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 1.0 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 1.5 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2.3 Methyl-tert-butyl-ether (MTBE)mg/l 1 NE NT NT NT NT NT NT 1.5 Naphthalene mg/l 1 NE NT NT NT NT NT NT 1.6 p-isopropyltoluene mg/l 1 NE NT NT NT NT NT NT ND Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.20 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-25-11) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-20-12) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.0 6.8 7.8 6.3 6.4 7.0 7.6 Specific Conductance mmhos/cm (on-site)1 NE 146 218.4 261.2 111 41.3 65.8 260.4 Temperature °C (on-site)-29 15.1 14.2 16.8 15.3 14.9 13.5 16.5 Turbidity NTU (on-site)NT 50 12.5 6.1 15.9 4.84 4.06 6.43 5.71 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 8.6 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.52 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 8.6 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 299 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 20.5 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 154 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 103 177 90.8 121 35.2 40.5 85.2 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 6 Total Cobalt (Co)mg/l 5 NE ND ND ND 14.4 ND ND 7.6 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND 7.7 Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 33.3 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND ND Total Zinc (Zn)mg/l 10 50 ND 37.6 15 ND ND ND 21.5 Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND NT Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND NT Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND NT 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND NT Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND NT m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.28 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-20-12) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-24-12) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.1 6.9 7.9 6.2 6.1 7.2 7.5 Specific Conductance mmhos/cm (on-site)1 NE 217 272 329 227 39 54 16,940.0 Temperature °C (on-site)-29 13.6 14.5 13.9 17.5 13.1 11.9 19.9 Turbidity NTU (on-site)NT 50 7.38 3.6 6.16 30.5 1.97 3.39 19.6 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.18 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.075 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT 0.26 Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 5100 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 53.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 860 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 5 10 ND ND ND ND ND ND 14 Total Barium (Ba)mg/l 5 NE 172 175 124 164 38.7 31.2 390 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 32.6 Total Cobalt (Co)mg/l 5 NE ND ND ND 20.2 ND ND 19 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 166 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 16.0 Total Zinc (Zn)mg/l 10 50 ND 28.5 10.7 ND ND ND ND Mercury mg/l 0.2 0.012 ND ND ND ND ND ND ND Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 1.8 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 3.1 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE NT NT NT NT NT NT 1.4 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.87 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters a Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-24-12) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-13) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.1 7.5 7.4 6.3 6.5 6.8 7.6 Specific Conductance mmhos/cm (on-site)1 NE 180 183 274 249 42 63 15,320 Temperature °C (on-site)-29 13.6 13 14.1 15.4 15.2 13.2 15.1 Turbidity NTU (on-site)NT 50 7.06 6.9 4.23 5.06 0.37 2.11 15 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.098 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.15 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.056 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 3830 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 107 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 866 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 159 146 148 114 34.8 33 436 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 27.3 Total Cobalt (Co)mg/l 5 NE ND ND 5.8 29.3 ND ND 17.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 130 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 13.0 Total Zinc (Zn)mg/l 10 50 ND 46.2 19 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 150 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.5 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.0 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND 157 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 5 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.1 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-24-13) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-24-13) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.4 6.9 7.5 6.3 6.3 6.8 7.6 Specific Conductance mmhos/cm (on-site)1 NE 238 280.6 329.7 281.7 38 67 14,800 Temperature °C (on-site)-29 11.2 11.7 10.8 16.7 11.1 9.6 15 Turbidity NTU (on-site)NT 50 25.2 2.05 2.96 3.28 1.19 2.24 200 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.2 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.25 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.044 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4.1 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 52.8 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 920 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 205 209 161 138 36.7 31 438 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 32.4 Total Cobalt (Co)mg/l 5 NE 5.1 7.9 ND 37.8 ND ND 27.8 Total Copper (Cu)mg/l 5 7 ND ND ND 5.7 ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 140 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE 7.3 ND ND ND ND ND 12.8 Total Zinc (Zn)mg/l 10 50 ND 33.2 13.3 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 1.9 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND 1.1 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 5.7 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 3.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 2.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.4 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-24-13) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-24-14) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 6.4 7.7 6.2 6.6 6.8 7.3 Specific Conductance mmhos/cm (on-site)1 NE 183 285 294 262 42 6.6 9,040 Temperature °C (on-site)-29 14.6 14.1 17.9 15.9 13.8 12.1 16.9 Turbidity NTU (on-site)NT 50 3.64 2.67 5.1 4.46 3.74 3.07 36.3 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.84 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 1.3 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.43 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 4450 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 53.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 964 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND ND Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND 14.3 Total Barium (Ba)mg/l 5 NE 142 187 133 125 38.5 35.5 376 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND 1.8 Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 14.6 Total Cobalt (Co)mg/l 5 NE ND 6.4 ND 9.7 ND ND 24.8 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND 5.5 ND ND ND ND 157 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 15.9 Total Zinc (Zn)mg/l 10 50 ND 23.8 10.8 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND 3.1 Chloroethane mg/l 1 NE ND ND ND ND ND ND 5.9 Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 5 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 3.6 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 15.6 2-Hexanone mg/l 5 NE ND ND ND ND ND ND 34.8 Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 2.6 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 41.4 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 29.7 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 11.7 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT NT Naphthalene mg/l NT NE NT NT NT NT NT NT NT p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.7 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-24-14) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-28-14) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 7.7 7.8 6.0 6.8 6.9 7.5 Specific Conductance mmhos/cm (on-site)1 NE 236 232 356 206 43 57 15,110 Temperature °C (on-site)-29 12.9 12.5 12.1 18.2 12.4 11.3 19.4 Turbidity NTU (on-site)NT 50 4.43 3.73 5.52 11.3 4.3 1.45 4.71 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT 0.12 Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.2 Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.08 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 3070 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 48.9 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 1010 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT 0.0075 Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 56.7 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 181 155 132 147 31.4 28 360 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 27.1 Total Cobalt (Co)mg/l 5 NE ND ND ND 9.7 ND ND 14.5 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 135 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 24.0 Total Zinc (Zn)mg/l 10 50 ND 75.8 ND ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND 2.8 trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 1.1 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND ND m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND 1.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT 1.7 Naphthalene mg/l NT NE NT NT NT NT NT NT 2.1 p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 1.7 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-28-14) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-28-15) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 7.3 7.6 8.3 6.1 7.3 7.1 8.1 Specific Conductance mmhos/cm (on-site)1 NE 201 217 330 181 41 81 6,309 Temperature °C (on-site)-29 13.8 11.5 16.8 18.2 12.3 10.7 22.1 Turbidity NTU (on-site)NT 50 4.62 6.77 3.6 6.7 5.76 4.76 5.43 Nitrate as N mg/l 0.1 NE NT NT NT NT NT NT Nitrate/Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT Nitrite as N mg/l 0.1 NE NT NT NT NT NT NT 0.031 Nitrogen mg/l 0.1 NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l 100 NE NT NT NT NT NT NT NT Sulfate mg/l 75 NE NT NT NT NT NT NT 712 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 24.6 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 503 Total Dissolved Solids mg/l 20 NE NT NT NT NT NT NT NT Cyanide mg/l 2 5 NT NT NT NT NT NT Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 23.4 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 175 152 145 133 34.5 33.3 119 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 9.5 Total Cobalt (Co)mg/l 5 NE ND ND ND 7.4 ND ND 7.3 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 64.5 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 19.3 Total Zinc (Zn)mg/l 10 50 ND 43.4 20.4 ND ND ND ND Mercury mg/l 0.2 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 32.3 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND ND m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT ND Naphthalene mg/l NT NE NT NT NT NT NT NT ND p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.34 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-28-15) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (10-27-15) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.8 7.4 7.2 7.7 6.8 6.8 6.4 Specific Conductance mmhos/cm (on-site)1 NE 222 226 360 307 72 61 6,509 Temperature °C (on-site)-29 13.5 13.3 13.4 17.8 14.3 13.0 15.5 Turbidity NTU (on-site)NT 50 10.18 18.30 9.92 24.52 8.05 3.92 66.79 Nitrate as N mg/l 0.02 NE NT NT NT NT NT NT ND Nitrate/Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.042 Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.066 Nitrogen mg/l NT NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l NT NE NT NT NT NT NT NT NT Sulfate mg/l 400 NE NT NT NT NT NT NT 837 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 73.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 442 Total Dissolved Solids mg/l NT NE NT NT NT NT NT NT NT Cyanide mg/l 0.008 5 NT NT NT NT NT NT ND Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 23.4 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 187 ND 164 139 35 31.4 285 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 9.8 Total Cobalt (Co)mg/l 5 NE ND ND ND 5.9 ND ND 5.7 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 61.7 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 18.2 Total Zinc (Zn)mg/l 10 50 ND ND ND ND ND ND 13.7 Mercury mg/l NT 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND 162 Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND 2 Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND 7.1 Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND 2.2 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND 168 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND 7.1 Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND 14.6 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND 3.7 m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND 2.5 o-Xylenes mg/l 1 NE ND ND ND ND ND ND 1.2 Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT ND Naphthalene mg/l NT NE NT NT NT NT NT NT ND p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.26 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (10-27-15) White Oak Landfill - Haywood Co., NC Surface Water Sampling Event (4-18-16) TEST UNITS MRL MCL SW-1 SW-2 SW-3 SW-5 SW-6 SW-7 Leachate pH pH units (on-site)-<6.0; >9.0 6.9 7 6.6 6.7 7.4 7.1 7.7 Specific Conductance mmhos/cm (on-site)1 NE 181 195 295 22.7 40 9.8 6,332 Temperature °C (on-site)-29 16.7 12.8 17.0 273 11.1 73.0 21.8 Turbidity NTU (on-site)NT 50 3.07 14.81 30.89 30.94 2.51 2.29 55.77 Nitrate as N mg/l 0.02 NE NT NT NT NT NT NT 0.075 Nitrate/Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.12 Nitrite as N mg/l 0.02 NE NT NT NT NT NT NT 0.049 Nitrogen mg/l NT NE NT NT NT NT NT NT NT Total Nitrogen, Kjeldahl mg/l NT NE NT NT NT NT NT NT NT Sulfate mg/l 400 NE NT NT NT NT NT NT 528 Biochemical Oxygen Demand mg/l 2 NE NT NT NT NT NT NT 65.3 Chemical Oxygen Demand mg/l 25 NE NT NT NT NT NT NT 396 Total Dissolved Solids mg/l NT NE NT NT NT NT NT NT NT Cyanide mg/l 0.008 5 NT NT NT NT NT NT ND Total Antimony (Sb)mg/l 5 NE ND ND ND ND ND ND 17.4 Total Arsenic (As)mg/l 10 10 ND ND ND ND ND ND ND Total Barium (Ba)mg/l 5 NE 125 138 122 130 30.6 28.1 228 Total Beryllium (Be)mg/l 1 6.5 ND ND ND ND ND ND ND Total Cadmium (Cd)mg/l 1 0.4 ND ND ND ND ND ND ND Total Chromium (Cr)mg/l 5 50 ND ND ND ND ND ND 11.4 Total Cobalt (Co)mg/l 5 NE ND ND ND ND ND ND 7.6 Total Copper (Cu)mg/l 5 7 ND ND ND ND ND ND ND Total Lead (Pb)mg/l 5 25 ND ND ND ND ND ND ND Total Nickel (Ni)mg/l 5 88 ND ND ND ND ND ND 60.3 Total Selenium (Se)mg/l 10 5 ND ND ND ND ND ND ND Total Silver (Ag)mg/l 5 0.06 ND ND ND ND ND ND ND Total Thallium (Tl)mg/l 5.4 NE ND ND ND ND ND ND ND Total Vanadium (V)mg/l 5 NE ND ND ND ND ND ND 14.5 Total Zinc (Zn)mg/l 10 50 ND 49.2 ND ND ND ND ND Mercury mg/l NT 0.012 NT NT NT NT NT NT NT Acetone mg/l 25 NE ND ND ND ND ND ND ND Acrylonitrile mg/l 10 NE ND ND ND ND ND ND ND Benzene mg/l 1 51 ND ND ND ND ND ND ND Bromochloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromodichloromethane mg/l 1 NE ND ND ND ND ND ND ND Bromoform mg/l 1 NE ND ND ND ND ND ND ND Carbon Disulfide mg/l 2 NE ND ND ND ND ND ND ND Bromomethane (Methylbromide)mg/l 2 NE ND ND ND ND ND ND ND Carbon tetrachloride mg/l 1 1.6 ND ND ND ND ND ND ND Chlorobenzene (mono)mg/l 1 NE ND ND ND ND ND ND ND Chloroethane mg/l 1 NE ND ND ND ND ND ND ND Chloroform mg/l 1 NE ND ND ND ND ND ND ND Chloromethane (Methylchloride)mg/l 1 NE ND ND ND ND ND ND ND Dibromochloromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dibromo-3-chloropropane; DBCP mg/l 2 NE ND ND ND ND ND ND ND 1,2-Dibromoethane; Ethylene dibromide mg/l 1 NE ND ND ND ND ND ND ND Dibromomethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND 1,4-Dichlorobenzene mg/l 1 NE ND ND ND ND ND ND ND trans-1,4-Dichloro-2-butene mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND cis-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,2-Dichloroethene (-ethylene)mg/l 1 NE ND ND ND ND ND ND ND 1,2-Dichloropropane mg/l 1 NE ND ND ND ND ND ND ND cis-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND trans-1,3-Dichloropropene (-propylene)mg/l 1 NE ND ND ND ND ND ND ND Ethylbenzene mg/l 1 NE ND ND ND ND ND ND ND 2-Hexanone mg/l 5 NE ND ND ND ND ND ND ND Iodomethane mg/l 5 NE ND ND ND ND ND ND ND Dichloromethane (Methylene chloride)mg/l 2 NE ND ND ND ND ND ND ND 2-Butanone (Methyl ethyl ketone)mg/l 5 NE ND ND ND ND ND ND ND 4-Methyl-2-Pentanone mg/l 5 NE ND ND ND ND ND ND ND Styrene mg/l 1 NE ND ND ND ND ND ND ND 1,1,1,2-Tetrachloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2,2-Tetrachloroethane mg/l 1 4 ND ND ND ND ND ND ND Tetrachloroethene (-ethylene)mg/l 1 3.3 ND ND ND ND ND ND ND Toluene mg/l 1 0.36 ND ND ND ND ND ND ND 1,1,1-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND 1,1,2-Trichloroethane mg/l 1 NE ND ND ND ND ND ND ND Trichloroethene (-ethylene)mg/l 1 30 ND ND ND ND ND ND ND Trichlorofluoromethane mg/l 1 NE ND ND ND ND ND ND ND 1,2,3-Trichloropropane mg/l 1 NE ND ND ND ND ND ND ND Vinyl acetate mg/l 2 NE ND ND ND ND ND ND ND Vinyl chloride mg/l 1 2.4 ND ND ND ND ND ND ND Total Xylenes mg/l 2 NE ND ND ND ND ND ND ND m&p-Xylenes mg/l 2 NE ND ND ND ND ND ND ND o-Xylenes mg/l 1 NE ND ND ND ND ND ND ND Methyl-tert-butyl-ether (MTBE)mg/l NT NE NT NT NT NT NT NT ND Naphthalene mg/l NT NE NT NT NT NT NT NT ND p-isopropyltoluene mg/l NT NE NT NT NT NT NT NT NT Phosphorus mg/l 0.05 NE NT NT NT NT NT NT 0.68 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR, "Redbook" Surface Waters and Wetlands Standards Section 15A NCAC 02B.0100, .0200, a .0300. ND = Not Detected at the Method Reporting Limit NS = Not Sampled NT = Not Tested NE = Not Established; North Carolina has not established a MCL Shaded cells indicate exceedances of MCLs. 1957-55 White Oak SW 1st 2016.xlsx (4-18-16) APPENDIX C LABORATORY ANALYTICAL RESULTS #=CL# June 24, 2016 LIMS USE: FR - RON VAIL LIMS OBJECT ID: 92294250 92294250 Project: Pace Project No.: RE: Mr. Ron Vail Santek Environmental Inc. 650 25th St, NW Suite 100 Cleveland, TN 37311 Haywood Wolf 4/18 Dear Mr. Vail: Enclosed are the analytical results for sample(s) received by the laboratory between April 18, 2016 and April 19, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. Revised Report: Report revised to correct client info, correct metals list Revised Report: Report revised to add missing COC If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen christopher.derouen@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 1 of 97 #=CL# June 24, 2016 Page 2 LIMS USE: FR - RON VAIL LIMS OBJECT ID: 92294250 cc:Robert Hudson, Santek Waste Services Ron Vail, Santek Environmental REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 97 #=CP# CERTIFICATIONS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 3 of 97 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92294250001 SW-1 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250002 SW-2 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250003 SW-3 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250004 SW-5 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250005 SW-6 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250006 SW-7 EPA 6010 15 PASI-ACDF EPA 8260 51 PASI-CGAW 92294250007 MW-1A EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250008 MW-2 EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250009 MW-2D EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250010 MW-3R EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250011 MW-3DR EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250012 MW-4A EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250013 MW-8 EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250014 MW-11s EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250015 MW-11D EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250016 MW-14 EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CGAW 92294250017 MW-15 EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250018 MW-16 EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CNB 92294250019 MW-17 EPA 6010 15 PASI-AJMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 4 of 97 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 8260 51 PASI-CNB 92294250020 TVL BLK EPA 8260 51 PASI-CGAW 92294250021 EQUIP BLK EPA 6010 15 PASI-AJMW EPA 8260 51 PASI-CGAW 92294250022 Lechate EPA 6010 15 PASI-ACDF EPA 8260 63 PASI-CNB SM 5210B 1 PASI-AMLS EPA 300.0 1 PASI-AMDW EPA 353.2 3 PASI-ADMN EPA 365.1 1 PASI-ABRJ SM 4500-CN-E 1 PASI-ASER SM 5220D 1 PASI-AWRC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 5 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-1 Lab ID:92294250001 Collected:04/18/16 13:45 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 15:591 Collected Date 4/18/16 04/20/16 15:591 Collected Time 13:45 04/20/16 15:591 Field pH 6.9 Std. Units 04/20/16 15:590.10 1 Field Temperature 16.7 deg C 04/20/16 15:590.50 1 Field Specific Conductance 181 umhos/cm 04/20/16 15:591.0 1 Turbidity 3.07 NTU 04/20/16 15:591.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:03 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:03 7440-38-204/19/16 17:3010.0 1 Barium 125 ug/L 04/23/16 12:03 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:03 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:03 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:03 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:03 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:03 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:03 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:03 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:03 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:03 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:03 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:03 7440-62-204/19/16 17:305.0 1 Zinc ND ug/L 04/23/16 12:03 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 05:11 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 05:11 107-13-110.0 1 Benzene ND ug/L 04/21/16 05:11 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 05:11 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 05:11 75-27-41.0 1 Bromoform ND ug/L 04/21/16 05:11 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 05:11 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 05:11 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 05:11 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 05:11 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 05:11 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 05:11 75-00-31.0 1 Chloroform ND ug/L 04/21/16 05:11 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 05:11 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 05:11 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 05:11 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 05:11 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 05:11 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 05:11 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 05:11 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 6 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-1 Lab ID:92294250001 Collected:04/18/16 13:45 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 05:11 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 05:11 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 05:11 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 05:11 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 05:11 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 05:11 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 05:11 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 05:11 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 05:11 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 05:11 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 05:11 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 05:11 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 05:11 108-10-15.0 1 Styrene ND ug/L 04/21/16 05:11 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 05:11 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 05:11 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 05:11 127-18-41.0 1 Toluene ND ug/L 04/21/16 05:11 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 05:11 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 05:11 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 05:11 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 05:11 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 05:11 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 05:11 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 05:11 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 05:11 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 05:11 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 05:11 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/21/16 05:11 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %04/21/16 05:11 17060-07-070-130 1 Toluene-d8 (S)101 %04/21/16 05:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 7 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-2 Lab ID:92294250002 Collected:04/18/16 13:30 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:021 Collected Date 4/18/16 04/20/16 16:021 Collected Time 13:30 04/20/16 16:021 Field pH 7.0 Std. Units 04/20/16 16:020.10 1 Field Temperature 12.8 deg C 04/20/16 16:020.50 1 Field Specific Conductance 195 umhos/cm 04/20/16 16:021.0 1 Turbidity 14.81 NTU 04/20/16 16:021.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:16 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:16 7440-38-204/19/16 17:3010.0 1 Barium 138 ug/L 04/23/16 12:16 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:16 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:16 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:16 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:16 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:16 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:16 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:16 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:16 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:16 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:16 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:16 7440-62-204/19/16 17:305.0 1 Zinc 49.2 ug/L 04/23/16 12:16 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 05:28 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 05:28 107-13-110.0 1 Benzene ND ug/L 04/21/16 05:28 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 05:28 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 05:28 75-27-41.0 1 Bromoform ND ug/L 04/21/16 05:28 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 05:28 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 05:28 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 05:28 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 05:28 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 05:28 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 05:28 75-00-31.0 1 Chloroform ND ug/L 04/21/16 05:28 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 05:28 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 05:28 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 05:28 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 05:28 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 05:28 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 05:28 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 05:28 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 8 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-2 Lab ID:92294250002 Collected:04/18/16 13:30 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 05:28 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 05:28 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 05:28 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 05:28 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 05:28 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 05:28 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 05:28 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 05:28 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 05:28 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 05:28 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 05:28 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 05:28 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 05:28 108-10-15.0 1 Styrene ND ug/L 04/21/16 05:28 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 05:28 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 05:28 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 05:28 127-18-41.0 1 Toluene ND ug/L 04/21/16 05:28 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 05:28 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 05:28 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 05:28 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 05:28 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 05:28 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 05:28 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 05:28 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 05:28 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 05:28 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 05:28 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)100 %04/21/16 05:28 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/21/16 05:28 17060-07-070-130 1 Toluene-d8 (S)100 %04/21/16 05:28 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 9 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-3 Lab ID:92294250003 Collected:04/18/16 13:20 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:051 Collected Date 4/18/16 04/20/16 16:051 Collected Time 13:20 04/20/16 16:051 Field pH 6.6 Std. Units 04/20/16 16:050.10 1 Field Temperature 17.0 deg C 04/20/16 16:050.50 1 Field Specific Conductance 295 umhos/cm 04/20/16 16:051.0 1 Turbidity 30.89 NTU 04/20/16 16:051.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:19 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:19 7440-38-204/19/16 17:3010.0 1 Barium 122 ug/L 04/23/16 12:19 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:19 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:19 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:19 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:19 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:19 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:19 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:19 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:19 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:19 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:19 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:19 7440-62-204/19/16 17:305.0 1 Zinc ND ug/L 04/23/16 12:19 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 05:45 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 05:45 107-13-110.0 1 Benzene ND ug/L 04/21/16 05:45 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 05:45 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 05:45 75-27-41.0 1 Bromoform ND ug/L 04/21/16 05:45 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 05:45 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 05:45 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 05:45 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 05:45 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 05:45 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 05:45 75-00-31.0 1 Chloroform ND ug/L 04/21/16 05:45 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 05:45 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 05:45 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 05:45 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 05:45 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 05:45 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 05:45 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 05:45 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 10 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-3 Lab ID:92294250003 Collected:04/18/16 13:20 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 05:45 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 05:45 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 05:45 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 05:45 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 05:45 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 05:45 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 05:45 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 05:45 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 05:45 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 05:45 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 05:45 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 05:45 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 05:45 108-10-15.0 1 Styrene ND ug/L 04/21/16 05:45 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 05:45 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 05:45 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 05:45 127-18-41.0 1 Toluene ND ug/L 04/21/16 05:45 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 05:45 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 05:45 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 05:45 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 05:45 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 05:45 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 05:45 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 05:45 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 05:45 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 05:45 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 05:45 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %04/21/16 05:45 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %04/21/16 05:45 17060-07-070-130 1 Toluene-d8 (S)102 %04/21/16 05:45 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 11 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-5 Lab ID:92294250004 Collected:04/18/16 12:40 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:061 Collected Date 4/18/16 04/20/16 16:061 Collected Time 12:40 04/20/16 16:061 Field pH 6.7 Std. Units 04/20/16 16:060.10 1 Field Temperature 22.7 deg C 04/20/16 16:060.50 1 Field Specific Conductance 273 umhos/cm 04/20/16 16:061.0 1 Alkalinity, Total as CaCO3 30.94 mg/L 04/20/16 16:061.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:22 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:22 7440-38-204/19/16 17:3010.0 1 Barium 130 ug/L 04/23/16 12:22 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:22 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:22 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:22 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:22 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:22 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:22 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:22 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:22 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:22 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:22 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:22 7440-62-204/19/16 17:305.0 1 Zinc ND ug/L 04/23/16 12:22 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 06:02 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 06:02 107-13-110.0 1 Benzene ND ug/L 04/21/16 06:02 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 06:02 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 06:02 75-27-41.0 1 Bromoform ND ug/L 04/21/16 06:02 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 06:02 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 06:02 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 06:02 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 06:02 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 06:02 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 06:02 75-00-31.0 1 Chloroform ND ug/L 04/21/16 06:02 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 06:02 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 06:02 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 06:02 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 06:02 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 06:02 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 06:02 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 06:02 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 12 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-5 Lab ID:92294250004 Collected:04/18/16 12:40 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 06:02 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 06:02 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 06:02 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 06:02 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 06:02 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 06:02 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 06:02 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 06:02 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 06:02 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 06:02 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 06:02 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 06:02 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 06:02 108-10-15.0 1 Styrene ND ug/L 04/21/16 06:02 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 06:02 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 06:02 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 06:02 127-18-41.0 1 Toluene ND ug/L 04/21/16 06:02 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 06:02 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 06:02 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 06:02 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 06:02 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 06:02 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 06:02 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 06:02 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 06:02 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 06:02 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 06:02 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)100 %04/21/16 06:02 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %04/21/16 06:02 17060-07-070-130 1 Toluene-d8 (S)101 %04/21/16 06:02 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 13 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-6 Lab ID:92294250005 Collected:04/18/16 09:30 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:081 Collected Date 4/18/16 04/20/16 16:081 Collected Time 09:30 04/20/16 16:081 Field pH 7.4 Std. Units 04/20/16 16:080.10 1 Field Temperature 11.1 deg C 04/20/16 16:080.50 1 Field Specific Conductance 40 umhos/cm 04/20/16 16:081.0 1 Turbidity 2.51 NTU 04/20/16 16:081.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:25 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:25 7440-38-204/19/16 17:3010.0 1 Barium 30.6 ug/L 04/23/16 12:25 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:25 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:25 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:25 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:25 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:25 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:25 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:25 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:25 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:25 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:25 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:25 7440-62-204/19/16 17:305.0 1 Zinc ND ug/L 04/23/16 12:25 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 06:20 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 06:20 107-13-110.0 1 Benzene ND ug/L 04/21/16 06:20 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 06:20 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 06:20 75-27-41.0 1 Bromoform ND ug/L 04/21/16 06:20 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 06:20 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 06:20 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 06:20 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 06:20 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 06:20 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 06:20 75-00-31.0 1 Chloroform ND ug/L 04/21/16 06:20 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 06:20 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 06:20 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 06:20 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 06:20 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 06:20 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 06:20 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 06:20 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 14 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-6 Lab ID:92294250005 Collected:04/18/16 09:30 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 06:20 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 06:20 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 06:20 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 06:20 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 06:20 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 06:20 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 06:20 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 06:20 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 06:20 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 06:20 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 06:20 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 06:20 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 06:20 108-10-15.0 1 Styrene ND ug/L 04/21/16 06:20 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 06:20 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 06:20 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 06:20 127-18-41.0 1 Toluene ND ug/L 04/21/16 06:20 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 06:20 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 06:20 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 06:20 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 06:20 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 06:20 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 06:20 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 06:20 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 06:20 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 06:20 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 06:20 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/21/16 06:20 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/21/16 06:20 17060-07-070-130 1 Toluene-d8 (S)99 %04/21/16 06:20 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 15 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-7 Lab ID:92294250006 Collected:04/18/16 09:40 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:111 Collected Date 4/18/16 04/20/16 16:111 Collected Time 09:40 04/20/16 16:111 Field pH 7.1 Std. Units 04/20/16 16:110.10 1 Field Temperature 9.8 deg C 04/20/16 16:110.50 1 Field Specific Conductance 73 umhos/cm 04/20/16 16:111.0 1 Turbidity 2.29 NTU 04/20/16 16:111.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 12:28 7440-36-004/19/16 17:305.0 1 Arsenic ND ug/L 04/23/16 12:28 7440-38-204/19/16 17:3010.0 1 Barium 28.1 ug/L 04/23/16 12:28 7440-39-304/19/16 17:305.0 1 Beryllium ND ug/L 04/23/16 12:28 7440-41-704/19/16 17:301.0 1 Cadmium ND ug/L 04/23/16 12:28 7440-43-904/19/16 17:301.0 1 Chromium ND ug/L 04/23/16 12:28 7440-47-304/19/16 17:305.0 1 Cobalt ND ug/L 04/23/16 12:28 7440-48-404/19/16 17:305.0 1 Copper ND ug/L 04/23/16 12:28 7440-50-804/19/16 17:305.0 1 Lead ND ug/L 04/23/16 12:28 7439-92-104/19/16 17:305.0 1 Nickel ND ug/L 04/23/16 12:28 7440-02-004/19/16 17:305.0 1 Selenium ND ug/L 04/23/16 12:28 7782-49-204/19/16 17:3010.0 1 Silver ND ug/L 04/23/16 12:28 7440-22-404/19/16 17:305.0 1 Thallium ND ug/L 04/23/16 12:28 7440-28-004/19/16 17:305.4 1 Vanadium ND ug/L 04/23/16 12:28 7440-62-204/19/16 17:305.0 1 Zinc ND ug/L 04/23/16 12:28 7440-66-604/19/16 17:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 06:37 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 06:37 107-13-110.0 1 Benzene ND ug/L 04/21/16 06:37 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 06:37 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 06:37 75-27-41.0 1 Bromoform ND ug/L 04/21/16 06:37 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 06:37 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 06:37 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 06:37 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 06:37 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 06:37 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 06:37 75-00-31.0 1 Chloroform ND ug/L 04/21/16 06:37 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 06:37 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 06:37 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 06:37 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 06:37 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 06:37 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 06:37 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 06:37 110-57-61.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 16 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:SW-7 Lab ID:92294250006 Collected:04/18/16 09:40 Received:04/18/16 17:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,1-Dichloroethane ND ug/L 04/21/16 06:37 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 06:37 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 06:37 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 06:37 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 06:37 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 06:37 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 06:37 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 06:37 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 06:37 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 06:37 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 06:37 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 06:37 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 06:37 108-10-15.0 1 Styrene ND ug/L 04/21/16 06:37 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 06:37 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 06:37 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 06:37 127-18-41.0 1 Toluene ND ug/L 04/21/16 06:37 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 06:37 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 06:37 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 06:37 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 06:37 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 06:37 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 06:37 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 06:37 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 06:37 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 06:37 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 06:37 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/21/16 06:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/21/16 06:37 17060-07-070-130 1 Toluene-d8 (S)100 %04/21/16 06:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 17 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-1A Lab ID:92294250007 Collected:04/19/16 13:30 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:181 Collected Date 4/19/16 04/20/16 16:181 Collected Time 13.30 04/20/16 16:181 Field pH 7.3 Std. Units 04/20/16 16:180.10 1 Field Temperature 14.1 deg C 04/20/16 16:180.50 1 Static Water Level 18.30 feet 04/20/16 16:181 Field Specific Conductance 145 umhos/cm 04/20/16 16:181.0 1 Turbidity 14.57 NTU 04/20/16 16:181.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:06 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:06 7440-38-204/21/16 18:3010.0 1 Barium 211 ug/L 04/22/16 23:06 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:06 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:06 7440-43-904/21/16 18:301.0 1 Chromium 6.8 ug/L 04/22/16 23:06 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:06 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:06 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:06 7439-92-104/21/16 18:305.0 1 Nickel 5.9 ug/L 04/22/16 23:06 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:06 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:06 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:06 7440-28-004/21/16 18:305.4 1 Vanadium 6.5 ug/L 04/22/16 23:06 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:06 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/23/16 22:39 67-64-125.0 1 Acrylonitrile ND ug/L 04/23/16 22:39 107-13-110.0 1 Benzene ND ug/L 04/23/16 22:39 71-43-21.0 1 Bromochloromethane ND ug/L 04/23/16 22:39 74-97-51.0 1 Bromodichloromethane ND ug/L 04/23/16 22:39 75-27-41.0 1 Bromoform ND ug/L 04/23/16 22:39 75-25-21.0 1 Bromomethane ND ug/L 04/23/16 22:39 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/23/16 22:39 78-93-35.0 1 Carbon disulfide ND ug/L 04/23/16 22:39 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/23/16 22:39 56-23-51.0 1 Chlorobenzene ND ug/L 04/23/16 22:39 108-90-71.0 1 Chloroethane ND ug/L 04/23/16 22:39 75-00-31.0 1 Chloroform ND ug/L 04/23/16 22:39 67-66-31.0 1 Chloromethane ND ug/L 04/23/16 22:39 74-87-31.0 1 Dibromochloromethane ND ug/L 04/23/16 22:39 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/23/16 22:39 106-93-41.0 1 Dibromomethane ND ug/L 04/23/16 22:39 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/23/16 22:39 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/23/16 22:39 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 18 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-1A Lab ID:92294250007 Collected:04/19/16 13:30 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/23/16 22:39 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/23/16 22:39 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/23/16 22:39 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/23/16 22:39 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/23/16 22:39 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/23/16 22:39 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/23/16 22:39 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/23/16 22:39 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/23/16 22:39 10061-02-61.0 1 Ethylbenzene ND ug/L 04/23/16 22:39 100-41-41.0 1 2-Hexanone ND ug/L 04/23/16 22:39 591-78-65.0 1 Iodomethane ND ug/L 04/23/16 22:39 74-88-45.0 1 Methylene Chloride ND ug/L 04/23/16 22:39 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/23/16 22:39 108-10-15.0 1 Styrene ND ug/L 04/23/16 22:39 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/23/16 22:39 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/23/16 22:39 79-34-51.0 1 Tetrachloroethene ND ug/L 04/23/16 22:39 127-18-41.0 1 Toluene ND ug/L 04/23/16 22:39 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/23/16 22:39 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/23/16 22:39 79-00-51.0 1 Trichloroethene ND ug/L 04/23/16 22:39 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/23/16 22:39 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/23/16 22:39 96-18-41.0 1 Vinyl acetate ND ug/L 04/23/16 22:39 108-05-42.0 1 Vinyl chloride ND ug/L 04/23/16 22:39 75-01-41.0 1 Xylene (Total)ND ug/L 04/23/16 22:39 1330-20-72.0 1 m&p-Xylene ND ug/L 04/23/16 22:39 179601-23-12.0 1 o-Xylene ND ug/L 04/23/16 22:39 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/23/16 22:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %04/23/16 22:39 17060-07-070-130 1 Toluene-d8 (S)101 %04/23/16 22:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 19 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-2 Lab ID:92294250008 Collected:04/19/16 13:10 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:191 Collected Date 4/19/16 04/20/16 16:191 Collected Time 13:10 04/20/16 16:191 Field pH 7.8 Std. Units 04/20/16 16:190.10 1 Field Temperature 16.0 deg C 04/20/16 16:190.50 1 Static Water Level 29.34 feet 04/20/16 16:191 Field Specific Conductance 1408 umhos/cm 04/20/16 16:191.0 1 Turbidity 10.74 NTU 04/20/16 16:191.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:09 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:09 7440-38-204/21/16 18:3010.0 1 Barium 889 ug/L 04/22/16 23:09 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:09 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:09 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:09 7440-47-304/21/16 18:305.0 1 Cobalt 12.1 ug/L 04/22/16 23:09 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:09 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:09 7439-92-104/21/16 18:305.0 1 Nickel 12.3 ug/L 04/22/16 23:09 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:09 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:09 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:09 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:09 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:09 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/23/16 22:57 67-64-125.0 1 Acrylonitrile ND ug/L 04/23/16 22:57 107-13-110.0 1 Benzene ND ug/L 04/23/16 22:57 71-43-21.0 1 Bromochloromethane ND ug/L 04/23/16 22:57 74-97-51.0 1 Bromodichloromethane ND ug/L 04/23/16 22:57 75-27-41.0 1 Bromoform ND ug/L 04/23/16 22:57 75-25-21.0 1 Bromomethane ND ug/L 04/23/16 22:57 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/23/16 22:57 78-93-35.0 1 Carbon disulfide ND ug/L 04/23/16 22:57 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/23/16 22:57 56-23-51.0 1 Chlorobenzene ND ug/L 04/23/16 22:57 108-90-71.0 1 Chloroethane ND ug/L 04/23/16 22:57 75-00-31.0 1 Chloroform ND ug/L 04/23/16 22:57 67-66-31.0 1 Chloromethane ND ug/L 04/23/16 22:57 74-87-31.0 1 Dibromochloromethane ND ug/L 04/23/16 22:57 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/23/16 22:57 106-93-41.0 1 Dibromomethane ND ug/L 04/23/16 22:57 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/23/16 22:57 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/23/16 22:57 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 20 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-2 Lab ID:92294250008 Collected:04/19/16 13:10 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/23/16 22:57 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/23/16 22:57 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/23/16 22:57 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/23/16 22:57 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/23/16 22:57 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/23/16 22:57 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/23/16 22:57 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/23/16 22:57 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/23/16 22:57 10061-02-61.0 1 Ethylbenzene ND ug/L 04/23/16 22:57 100-41-41.0 1 2-Hexanone ND ug/L 04/23/16 22:57 591-78-65.0 1 Iodomethane ND ug/L 04/23/16 22:57 74-88-45.0 1 Methylene Chloride ND ug/L 04/23/16 22:57 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/23/16 22:57 108-10-15.0 1 Styrene ND ug/L 04/23/16 22:57 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/23/16 22:57 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/23/16 22:57 79-34-51.0 1 Tetrachloroethene ND ug/L 04/23/16 22:57 127-18-41.0 1 Toluene ND ug/L 04/23/16 22:57 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/23/16 22:57 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/23/16 22:57 79-00-51.0 1 Trichloroethene ND ug/L 04/23/16 22:57 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/23/16 22:57 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/23/16 22:57 96-18-41.0 1 Vinyl acetate ND ug/L 04/23/16 22:57 108-05-42.0 1 Vinyl chloride ND ug/L 04/23/16 22:57 75-01-41.0 1 Xylene (Total)ND ug/L 04/23/16 22:57 1330-20-72.0 1 m&p-Xylene ND ug/L 04/23/16 22:57 179601-23-12.0 1 o-Xylene ND ug/L 04/23/16 22:57 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/23/16 22:57 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %04/23/16 22:57 17060-07-070-130 1 Toluene-d8 (S)99 %04/23/16 22:57 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 21 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-2D Lab ID:92294250009 Collected:04/19/16 13:20 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:211 Collected Date 4/19/16 04/20/16 16:211 Collected Time 13:20 04/20/16 16:211 Field pH 7.1 Std. Units 04/20/16 16:210.10 1 Field Temperature 15.6 deg C 04/20/16 16:210.50 1 Static Water Level 29.30 feet 04/20/16 16:211 Field Specific Conductance 1626 umhos/cm 04/20/16 16:211.0 1 Turbidity 5.18 NTU 04/20/16 16:211.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:13 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:13 7440-38-204/21/16 18:3010.0 1 Barium 1240 ug/L 04/22/16 23:13 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:13 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:13 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:13 7440-47-304/21/16 18:305.0 1 Cobalt 6.4 ug/L 04/22/16 23:13 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:13 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:13 7439-92-104/21/16 18:305.0 1 Nickel 13.2 ug/L 04/22/16 23:13 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:13 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:13 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:13 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:13 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:13 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/23/16 23:14 67-64-125.0 1 Acrylonitrile ND ug/L 04/23/16 23:14 107-13-110.0 1 Benzene ND ug/L 04/23/16 23:14 71-43-21.0 1 Bromochloromethane ND ug/L 04/23/16 23:14 74-97-51.0 1 Bromodichloromethane ND ug/L 04/23/16 23:14 75-27-41.0 1 Bromoform ND ug/L 04/23/16 23:14 75-25-21.0 1 Bromomethane ND ug/L 04/23/16 23:14 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/23/16 23:14 78-93-35.0 1 Carbon disulfide ND ug/L 04/23/16 23:14 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/23/16 23:14 56-23-51.0 1 Chlorobenzene ND ug/L 04/23/16 23:14 108-90-71.0 1 Chloroethane ND ug/L 04/23/16 23:14 75-00-31.0 1 Chloroform ND ug/L 04/23/16 23:14 67-66-31.0 1 Chloromethane ND ug/L 04/23/16 23:14 74-87-31.0 1 Dibromochloromethane ND ug/L 04/23/16 23:14 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/23/16 23:14 106-93-41.0 1 Dibromomethane ND ug/L 04/23/16 23:14 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/23/16 23:14 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/23/16 23:14 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 22 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-2D Lab ID:92294250009 Collected:04/19/16 13:20 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/23/16 23:14 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/23/16 23:14 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/23/16 23:14 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/23/16 23:14 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/23/16 23:14 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/23/16 23:14 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/23/16 23:14 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/23/16 23:14 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/23/16 23:14 10061-02-61.0 1 Ethylbenzene ND ug/L 04/23/16 23:14 100-41-41.0 1 2-Hexanone ND ug/L 04/23/16 23:14 591-78-65.0 1 Iodomethane ND ug/L 04/23/16 23:14 74-88-45.0 1 Methylene Chloride ND ug/L 04/23/16 23:14 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/23/16 23:14 108-10-15.0 1 Styrene ND ug/L 04/23/16 23:14 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/23/16 23:14 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/23/16 23:14 79-34-51.0 1 Tetrachloroethene ND ug/L 04/23/16 23:14 127-18-41.0 1 Toluene ND ug/L 04/23/16 23:14 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/23/16 23:14 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/23/16 23:14 79-00-51.0 1 Trichloroethene ND ug/L 04/23/16 23:14 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/23/16 23:14 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/23/16 23:14 96-18-41.0 1 Vinyl acetate ND ug/L 04/23/16 23:14 108-05-42.0 1 Vinyl chloride ND ug/L 04/23/16 23:14 75-01-41.0 1 Xylene (Total)ND ug/L 04/23/16 23:14 1330-20-72.0 1 m&p-Xylene ND ug/L 04/23/16 23:14 179601-23-12.0 1 o-Xylene ND ug/L 04/23/16 23:14 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/23/16 23:14 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %04/23/16 23:14 17060-07-070-130 1 Toluene-d8 (S)100 %04/23/16 23:14 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 23 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-3R Lab ID:92294250010 Collected:04/19/16 12:35 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/20/16 16:251 Collected Date 4/19/16 04/20/16 16:251 Collected Time 12:35 04/20/16 16:251 Field pH 5.9 Std. Units 04/20/16 16:250.10 1 Field Temperature 15.0 deg C 04/20/16 16:250.50 1 Static Water Level 30.69 feet 04/20/16 16:251 Field Specific Conductance 484 umhos/cm 04/20/16 16:251.0 1 Turbidity 10.86 NTU 04/20/16 16:251.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:18 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:18 7440-38-204/21/16 18:3010.0 1 Barium 325 ug/L 04/22/16 23:18 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:18 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:18 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:18 7440-47-304/21/16 18:305.0 1 Cobalt 5.1 ug/L 04/22/16 23:18 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:18 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:18 7439-92-104/21/16 18:305.0 1 Nickel 21.7 ug/L 04/22/16 23:18 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:18 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:18 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:18 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:18 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:18 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/23/16 23:31 67-64-125.0 1 Acrylonitrile ND ug/L 04/23/16 23:31 107-13-110.0 1 Benzene ND ug/L 04/23/16 23:31 71-43-21.0 1 Bromochloromethane ND ug/L 04/23/16 23:31 74-97-51.0 1 Bromodichloromethane ND ug/L 04/23/16 23:31 75-27-41.0 1 Bromoform ND ug/L 04/23/16 23:31 75-25-21.0 1 Bromomethane ND ug/L 04/23/16 23:31 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/23/16 23:31 78-93-35.0 1 Carbon disulfide ND ug/L 04/23/16 23:31 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/23/16 23:31 56-23-51.0 1 Chlorobenzene ND ug/L 04/23/16 23:31 108-90-71.0 1 Chloroethane ND ug/L 04/23/16 23:31 75-00-31.0 1 Chloroform ND ug/L 04/23/16 23:31 67-66-31.0 1 Chloromethane ND ug/L 04/23/16 23:31 74-87-31.0 1 Dibromochloromethane ND ug/L 04/23/16 23:31 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/23/16 23:31 106-93-41.0 1 Dibromomethane ND ug/L 04/23/16 23:31 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/23/16 23:31 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/23/16 23:31 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 24 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-3R Lab ID:92294250010 Collected:04/19/16 12:35 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/23/16 23:31 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/23/16 23:31 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/23/16 23:31 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/23/16 23:31 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/23/16 23:31 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/23/16 23:31 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/23/16 23:31 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/23/16 23:31 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/23/16 23:31 10061-02-61.0 1 Ethylbenzene ND ug/L 04/23/16 23:31 100-41-41.0 1 2-Hexanone ND ug/L 04/23/16 23:31 591-78-65.0 1 Iodomethane ND ug/L 04/23/16 23:31 74-88-45.0 1 Methylene Chloride ND ug/L 04/23/16 23:31 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/23/16 23:31 108-10-15.0 1 Styrene ND ug/L 04/23/16 23:31 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/23/16 23:31 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/23/16 23:31 79-34-51.0 1 Tetrachloroethene ND ug/L 04/23/16 23:31 127-18-41.0 1 Toluene ND ug/L 04/23/16 23:31 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/23/16 23:31 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/23/16 23:31 79-00-51.0 1 Trichloroethene ND ug/L 04/23/16 23:31 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/23/16 23:31 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/23/16 23:31 96-18-41.0 1 Vinyl acetate ND ug/L 04/23/16 23:31 108-05-42.0 1 Vinyl chloride ND ug/L 04/23/16 23:31 75-01-41.0 1 Xylene (Total)ND ug/L 04/23/16 23:31 1330-20-72.0 1 m&p-Xylene ND ug/L 04/23/16 23:31 179601-23-12.0 1 o-Xylene ND ug/L 04/23/16 23:31 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)97 %04/23/16 23:31 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/23/16 23:31 17060-07-070-130 1 Toluene-d8 (S)99 %04/23/16 23:31 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 25 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-3DR Lab ID:92294250011 Collected:04/19/16 12:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:411 Collected Date 4/19/16 04/22/16 10:411 Collected Time 12:45 04/22/16 10:411 Field pH 5.8 Std. Units 04/22/16 10:410.10 1 Field Temperature 14.0 deg C 04/22/16 10:410.50 1 Static Water Level 35.98 feet 04/22/16 10:411 Field Specific Conductance 369 umhos/cm 04/22/16 10:411.0 1 Turbidity 2.50 NTU 04/22/16 10:411.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:21 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:21 7440-38-204/21/16 18:3010.0 1 Barium 200 ug/L 04/22/16 23:21 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:21 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:21 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:21 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:21 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:21 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:21 7439-92-104/21/16 18:305.0 1 Nickel 30.9 ug/L 04/22/16 23:21 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:21 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:21 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:21 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:21 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:21 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/23/16 23:48 67-64-125.0 1 Acrylonitrile ND ug/L 04/23/16 23:48 107-13-110.0 1 Benzene ND ug/L 04/23/16 23:48 71-43-21.0 1 Bromochloromethane ND ug/L 04/23/16 23:48 74-97-51.0 1 Bromodichloromethane ND ug/L 04/23/16 23:48 75-27-41.0 1 Bromoform ND ug/L 04/23/16 23:48 75-25-21.0 1 Bromomethane ND ug/L 04/23/16 23:48 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/23/16 23:48 78-93-35.0 1 Carbon disulfide ND ug/L 04/23/16 23:48 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/23/16 23:48 56-23-51.0 1 Chlorobenzene ND ug/L 04/23/16 23:48 108-90-71.0 1 Chloroethane ND ug/L 04/23/16 23:48 75-00-31.0 1 Chloroform ND ug/L 04/23/16 23:48 67-66-31.0 1 Chloromethane ND ug/L 04/23/16 23:48 74-87-31.0 1 Dibromochloromethane ND ug/L 04/23/16 23:48 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/23/16 23:48 106-93-41.0 1 Dibromomethane ND ug/L 04/23/16 23:48 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/23/16 23:48 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/23/16 23:48 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 26 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-3DR Lab ID:92294250011 Collected:04/19/16 12:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/23/16 23:48 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/23/16 23:48 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/23/16 23:48 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/23/16 23:48 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/23/16 23:48 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/23/16 23:48 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/23/16 23:48 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/23/16 23:48 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/23/16 23:48 10061-02-61.0 1 Ethylbenzene ND ug/L 04/23/16 23:48 100-41-41.0 1 2-Hexanone ND ug/L 04/23/16 23:48 591-78-65.0 1 Iodomethane ND ug/L 04/23/16 23:48 74-88-45.0 1 Methylene Chloride ND ug/L 04/23/16 23:48 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/23/16 23:48 108-10-15.0 1 Styrene ND ug/L 04/23/16 23:48 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/23/16 23:48 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/23/16 23:48 79-34-51.0 1 Tetrachloroethene ND ug/L 04/23/16 23:48 127-18-41.0 1 Toluene ND ug/L 04/23/16 23:48 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/23/16 23:48 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/23/16 23:48 79-00-51.0 1 Trichloroethene ND ug/L 04/23/16 23:48 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/23/16 23:48 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/23/16 23:48 96-18-41.0 1 Vinyl acetate ND ug/L 04/23/16 23:48 108-05-42.0 1 Vinyl chloride ND ug/L 04/23/16 23:48 75-01-41.0 1 Xylene (Total)ND ug/L 04/23/16 23:48 1330-20-72.0 1 m&p-Xylene ND ug/L 04/23/16 23:48 179601-23-12.0 1 o-Xylene ND ug/L 04/23/16 23:48 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)100 %04/23/16 23:48 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/23/16 23:48 17060-07-070-130 1 Toluene-d8 (S)99 %04/23/16 23:48 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 27 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-4A Lab ID:92294250012 Collected:04/19/16 13:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:431 Collected Date 4/19/16 04/22/16 10:431 Collected Time 13:45 04/22/16 10:431 Field pH 7.6 Std. Units 04/22/16 10:430.10 1 Field Temperature 14.9 deg C 04/22/16 10:430.50 1 Static Water Level 44.26 feet 04/22/16 10:431 Field Specific Conductance 149 umhos/cm 04/22/16 10:431.0 1 Turbidity 20.87 NTU 04/22/16 10:431.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:25 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:25 7440-38-204/21/16 18:3010.0 1 Barium 17.7 ug/L 04/22/16 23:25 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:25 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:25 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:25 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:25 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:25 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:25 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/22/16 23:25 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:25 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:25 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:25 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:25 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:25 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 00:05 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 00:05 107-13-110.0 1 Benzene ND ug/L 04/24/16 00:05 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 00:05 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 00:05 75-27-41.0 1 Bromoform ND ug/L 04/24/16 00:05 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 00:05 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 00:05 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 00:05 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 00:05 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 00:05 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 00:05 75-00-31.0 1 Chloroform ND ug/L 04/24/16 00:05 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 00:05 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 00:05 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 00:05 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 00:05 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 00:05 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 00:05 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 28 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-4A Lab ID:92294250012 Collected:04/19/16 13:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 00:05 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 00:05 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 00:05 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 00:05 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 00:05 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 00:05 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 00:05 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 00:05 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 00:05 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 00:05 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 00:05 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 00:05 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 00:05 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 00:05 108-10-15.0 1 Styrene ND ug/L 04/24/16 00:05 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 00:05 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 00:05 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 00:05 127-18-41.0 1 Toluene ND ug/L 04/24/16 00:05 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 00:05 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 00:05 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 00:05 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 00:05 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 00:05 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 00:05 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 00:05 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 00:05 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 00:05 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 00:05 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %04/24/16 00:05 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %04/24/16 00:05 17060-07-070-130 1 Toluene-d8 (S)100 %04/24/16 00:05 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 29 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-8 Lab ID:92294250013 Collected:04/19/16 12:15 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:441 Collected Date 4/19/2016 04/22/16 10:441 Collected Time 12:15 04/22/16 10:441 Field pH 5.6 Std. Units 04/22/16 10:440.10 1 Field Temperature 15.0 deg C 04/22/16 10:440.50 1 Static Water Level 30.02 feet 04/22/16 10:441 Field Specific Conductance 818 umhos/cm 04/22/16 10:441.0 1 Turbidity 2.70 NTU 04/22/16 10:441.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:28 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:28 7440-38-204/21/16 18:3010.0 1 Barium 216 ug/L 04/22/16 23:28 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:28 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:28 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:28 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:28 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:28 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:28 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/22/16 23:28 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:28 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:28 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:28 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:28 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:28 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 00:22 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 00:22 107-13-110.0 1 Benzene ND ug/L 04/24/16 00:22 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 00:22 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 00:22 75-27-41.0 1 Bromoform ND ug/L 04/24/16 00:22 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 00:22 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 00:22 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 00:22 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 00:22 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 00:22 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 00:22 75-00-31.0 1 Chloroform ND ug/L 04/24/16 00:22 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 00:22 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 00:22 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 00:22 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 00:22 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 00:22 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 00:22 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 30 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-8 Lab ID:92294250013 Collected:04/19/16 12:15 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 00:22 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 00:22 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 00:22 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 00:22 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 00:22 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 00:22 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 00:22 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 00:22 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 00:22 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 00:22 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 00:22 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 00:22 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 00:22 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 00:22 108-10-15.0 1 Styrene ND ug/L 04/24/16 00:22 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 00:22 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 00:22 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 00:22 127-18-41.0 1 Toluene ND ug/L 04/24/16 00:22 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 00:22 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 00:22 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 00:22 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 00:22 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 00:22 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 00:22 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 00:22 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 00:22 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 00:22 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 00:22 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)97 %04/24/16 00:22 460-00-470-130 1 1,2-Dichloroethane-d4 (S)94 %04/24/16 00:22 17060-07-070-130 1 Toluene-d8 (S)99 %04/24/16 00:22 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 31 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-11s Lab ID:92294250014 Collected:04/19/16 14:05 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:451 Collected Date 4/19/2016 04/22/16 10:451 Collected Time 14:05 04/22/16 10:451 Field pH 7.0 Std. Units 04/22/16 10:450.10 1 Field Temperature 14.2 deg C 04/22/16 10:450.50 1 Static Water Level 82.25 feet 04/22/16 10:451 Field Specific Conductance 25 umhos/cm 04/22/16 10:451.0 1 Alkalinity, Total as CaCO3 387.5 mg/L 04/22/16 10:451.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:32 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:32 7440-38-204/21/16 18:3010.0 1 Barium 222 ug/L 04/22/16 23:32 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:32 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:32 7440-43-904/21/16 18:301.0 1 Chromium 13.3 ug/L 04/22/16 23:32 7440-47-304/21/16 18:305.0 1 Cobalt 7.2 ug/L 04/22/16 23:32 7440-48-404/21/16 18:305.0 1 Copper 7.8 ug/L 04/22/16 23:32 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:32 7439-92-104/21/16 18:305.0 1 Nickel 7.2 ug/L 04/22/16 23:32 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:32 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:32 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:32 7440-28-004/21/16 18:305.4 1 Vanadium 21.6 ug/L 04/22/16 23:32 7440-62-204/21/16 18:305.0 1 Zinc 21.9 ug/L 04/22/16 23:32 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 00:39 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 00:39 107-13-110.0 1 Benzene ND ug/L 04/24/16 00:39 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 00:39 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 00:39 75-27-41.0 1 Bromoform ND ug/L 04/24/16 00:39 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 00:39 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 00:39 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 00:39 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 00:39 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 00:39 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 00:39 75-00-31.0 1 Chloroform ND ug/L 04/24/16 00:39 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 00:39 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 00:39 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 00:39 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 00:39 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 00:39 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 00:39 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 32 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-11s Lab ID:92294250014 Collected:04/19/16 14:05 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 00:39 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 00:39 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 00:39 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 00:39 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 00:39 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 00:39 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 00:39 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 00:39 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 00:39 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 00:39 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 00:39 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 00:39 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 00:39 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 00:39 108-10-15.0 1 Styrene ND ug/L 04/24/16 00:39 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 00:39 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 00:39 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 00:39 127-18-41.0 1 Toluene ND ug/L 04/24/16 00:39 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 00:39 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 00:39 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 00:39 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 00:39 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 00:39 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 00:39 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 00:39 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 00:39 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 00:39 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 00:39 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)96 %04/24/16 00:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/24/16 00:39 17060-07-070-130 1 Toluene-d8 (S)99 %04/24/16 00:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 33 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-11D Lab ID:92294250015 Collected:04/19/16 14:20 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:481 Collected Date 4/19/2016 04/22/16 10:481 Collected Time 14:20 04/22/16 10:481 Field pH 6.8 Std. Units 04/22/16 10:480.10 1 Field Temperature 13.5 deg C 04/22/16 10:480.50 1 Static Water Level 83.16 feet 04/22/16 10:481 Field Specific Conductance 47 umhos/cm 04/22/16 10:481.0 1 Turbidity 2.68 NTU 04/22/16 10:481.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:36 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:36 7440-38-204/21/16 18:3010.0 1 Barium 16.1 ug/L 04/22/16 23:36 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:36 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:36 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:36 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:36 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/22/16 23:36 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:36 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/22/16 23:36 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:36 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:36 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:36 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:36 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:36 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 00:56 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 00:56 107-13-110.0 1 Benzene ND ug/L 04/24/16 00:56 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 00:56 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 00:56 75-27-41.0 1 Bromoform ND ug/L 04/24/16 00:56 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 00:56 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 00:56 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 00:56 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 00:56 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 00:56 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 00:56 75-00-31.0 1 Chloroform ND ug/L 04/24/16 00:56 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 00:56 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 00:56 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 00:56 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 00:56 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 00:56 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 00:56 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 34 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-11D Lab ID:92294250015 Collected:04/19/16 14:20 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 00:56 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 00:56 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 00:56 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 00:56 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 00:56 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 00:56 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 00:56 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 00:56 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 00:56 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 00:56 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 00:56 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 00:56 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 00:56 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 00:56 108-10-15.0 1 Styrene ND ug/L 04/24/16 00:56 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 00:56 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 00:56 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 00:56 127-18-41.0 1 Toluene ND ug/L 04/24/16 00:56 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 00:56 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 00:56 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 00:56 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 00:56 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 00:56 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 00:56 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 00:56 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 00:56 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 00:56 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 00:56 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/24/16 00:56 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %04/24/16 00:56 17060-07-070-130 1 Toluene-d8 (S)100 %04/24/16 00:56 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 35 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-14 Lab ID:92294250016 Collected:04/19/16 15:05 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:491 Collected Date 4/19/2016 04/22/16 10:491 Collected Time 15.05 04/22/16 10:491 Field pH 5.4 Std. Units 04/22/16 10:490.10 1 Field Temperature 13.5 deg C 04/22/16 10:490.50 1 Static Water Level 100.61 feet 04/22/16 10:491 Field Specific Conductance 29 umhos/cm 04/22/16 10:491.0 1 Turbidity 8.42 NTU 04/22/16 10:491.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/22/16 23:39 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/22/16 23:39 7440-38-204/21/16 18:3010.0 1 Barium 55.2 ug/L 04/22/16 23:39 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/22/16 23:39 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/22/16 23:39 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/22/16 23:39 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/22/16 23:39 7440-48-404/21/16 18:305.0 1 Copper 5.4 ug/L 04/22/16 23:39 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/22/16 23:39 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/22/16 23:39 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/22/16 23:39 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/22/16 23:39 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/22/16 23:39 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/22/16 23:39 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/22/16 23:39 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 22:01 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 22:01 107-13-110.0 1 Benzene ND ug/L 04/21/16 22:01 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 22:01 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 22:01 75-27-41.0 1 Bromoform ND ug/L 04/21/16 22:01 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 22:01 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 22:01 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 22:01 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 22:01 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 22:01 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 22:01 75-00-31.0 1 Chloroform ND ug/L 04/21/16 22:01 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 22:01 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 22:01 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 22:01 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 22:01 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 22:01 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 22:01 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 36 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-14 Lab ID:92294250016 Collected:04/19/16 15:05 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 22:01 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/21/16 22:01 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 22:01 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 22:01 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 22:01 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 22:01 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 22:01 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 22:01 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 22:01 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 22:01 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 22:01 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 22:01 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 22:01 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 22:01 108-10-15.0 1 Styrene ND ug/L 04/21/16 22:01 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 22:01 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 22:01 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 22:01 127-18-41.0 1 Toluene ND ug/L 04/21/16 22:01 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 22:01 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 22:01 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 22:01 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 22:01 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 22:01 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 22:01 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 22:01 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 22:01 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 22:01 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 22:01 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/21/16 22:01 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %04/21/16 22:01 17060-07-070-130 1 Toluene-d8 (S)101 %04/21/16 22:01 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 37 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-15 Lab ID:92294250017 Collected:04/19/16 14:50 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:531 Collected Date 4/19/2016 04/22/16 10:531 Collected Time 14:50 04/22/16 10:531 Field pH 6.0 Std. Units 04/22/16 10:530.10 1 Field Temperature 12.5 deg C 04/22/16 10:530.50 1 Static Water Level 9.14 feet 04/22/16 10:531 Field Specific Conductance 53 umhos/cm 04/22/16 10:531.0 1 Turbidity 12.03 NTU 04/22/16 10:531.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 00:04 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/23/16 00:04 7440-38-204/21/16 18:3010.0 1 Barium 22.8 ug/L 04/23/16 00:04 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/23/16 00:04 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/23/16 00:04 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/23/16 00:04 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/23/16 00:04 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/23/16 00:04 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/23/16 00:04 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/23/16 00:04 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/23/16 00:04 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/23/16 00:04 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/23/16 00:04 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/23/16 00:04 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/23/16 00:04 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 01:13 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 01:13 107-13-110.0 1 Benzene ND ug/L 04/24/16 01:13 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 01:13 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 01:13 75-27-41.0 1 Bromoform ND ug/L 04/24/16 01:13 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 01:13 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 01:13 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 01:13 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 01:13 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 01:13 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 01:13 75-00-31.0 1 Chloroform ND ug/L 04/24/16 01:13 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 01:13 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 01:13 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 01:13 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 01:13 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 01:13 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 01:13 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 38 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-15 Lab ID:92294250017 Collected:04/19/16 14:50 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 01:13 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 01:13 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 01:13 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 01:13 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 01:13 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 01:13 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 01:13 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 01:13 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 01:13 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 01:13 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 01:13 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 01:13 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 01:13 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 01:13 108-10-15.0 1 Styrene ND ug/L 04/24/16 01:13 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 01:13 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 01:13 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 01:13 127-18-41.0 1 Toluene ND ug/L 04/24/16 01:13 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 01:13 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 01:13 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 01:13 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 01:13 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 01:13 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 01:13 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 01:13 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 01:13 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 01:13 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 01:13 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %04/24/16 01:13 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %04/24/16 01:13 17060-07-070-130 1 Toluene-d8 (S)99 %04/24/16 01:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 39 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-16 Lab ID:92294250018 Collected:04/19/16 12:00 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:541 Collected Date 4/19/2016 04/22/16 10:541 Collected Time 12:00 04/22/16 10:541 Field pH 6.0 Std. Units 04/22/16 10:540.10 1 Field Temperature 17.3 deg C 04/22/16 10:540.50 1 Static Water Level 34.98 feet 04/22/16 10:541 Field Specific Conductance 368 umhos/cm 04/22/16 10:541.0 1 Turbidity 4.15 NTU 04/22/16 10:541.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 00:15 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/23/16 00:15 7440-38-204/21/16 18:3010.0 1 Barium 152 ug/L 04/23/16 00:15 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/23/16 00:15 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/23/16 00:15 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/23/16 00:15 7440-47-304/21/16 18:305.0 1 Cobalt 101 ug/L 04/23/16 00:15 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/23/16 00:15 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/23/16 00:15 7439-92-104/21/16 18:305.0 1 Nickel 10.6 ug/L 04/23/16 00:15 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/23/16 00:15 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/23/16 00:15 7440-22-404/21/16 18:305.0 1 Thallium 14.1 ug/L 04/23/16 00:15 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/23/16 00:15 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/23/16 00:15 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 19:01 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 19:01 107-13-110.0 1 Benzene ND ug/L 04/24/16 19:01 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 19:01 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 19:01 75-27-41.0 1 Bromoform ND ug/L 04/24/16 19:01 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 19:01 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 19:01 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 19:01 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 19:01 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 19:01 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 19:01 75-00-31.0 1 Chloroform ND ug/L 04/24/16 19:01 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 19:01 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 19:01 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 19:01 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 19:01 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 19:01 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 19:01 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 40 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-16 Lab ID:92294250018 Collected:04/19/16 12:00 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 19:01 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 19:01 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 19:01 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 19:01 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 19:01 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 19:01 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 19:01 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 19:01 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 19:01 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 19:01 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 19:01 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 19:01 74-88-4 M15.0 1 Methylene Chloride ND ug/L 04/24/16 19:01 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 19:01 108-10-15.0 1 Styrene ND ug/L 04/24/16 19:01 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 19:01 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 19:01 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 19:01 127-18-41.0 1 Toluene ND ug/L 04/24/16 19:01 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 19:01 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 19:01 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 19:01 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 19:01 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 19:01 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 19:01 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 19:01 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 19:01 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 19:01 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 19:01 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/24/16 19:01 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %04/24/16 19:01 17060-07-070-130 1 Toluene-d8 (S)100 %04/24/16 19:01 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 41 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-17 Lab ID:92294250019 Collected:04/19/16 11:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Monitoring Well Data Collected By Mark Swann 04/22/16 10:551 Collected Date 4/19/2016 04/22/16 10:551 Collected Time 11:45 04/22/16 10:551 Field pH 6.5 Std. Units 04/22/16 10:550.10 1 Field Temperature 14.4 deg C 04/22/16 10:550.50 1 Static Water Level 56.34 feet 04/22/16 10:551 Field Specific Conductance 182 umhos/cm 04/22/16 10:551.0 1 Turbidity 3.01 NTU 04/22/16 10:551.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 00:19 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/23/16 00:19 7440-38-204/21/16 18:3010.0 1 Barium 191 ug/L 04/23/16 00:19 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/23/16 00:19 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/23/16 00:19 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/23/16 00:19 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/23/16 00:19 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/23/16 00:19 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/23/16 00:19 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/23/16 00:19 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/23/16 00:19 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/23/16 00:19 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/23/16 00:19 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/23/16 00:19 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/23/16 00:19 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/24/16 19:18 67-64-125.0 1 Acrylonitrile ND ug/L 04/24/16 19:18 107-13-110.0 1 Benzene ND ug/L 04/24/16 19:18 71-43-21.0 1 Bromochloromethane ND ug/L 04/24/16 19:18 74-97-51.0 1 Bromodichloromethane ND ug/L 04/24/16 19:18 75-27-41.0 1 Bromoform ND ug/L 04/24/16 19:18 75-25-21.0 1 Bromomethane ND ug/L 04/24/16 19:18 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/24/16 19:18 78-93-35.0 1 Carbon disulfide ND ug/L 04/24/16 19:18 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/24/16 19:18 56-23-51.0 1 Chlorobenzene ND ug/L 04/24/16 19:18 108-90-71.0 1 Chloroethane ND ug/L 04/24/16 19:18 75-00-31.0 1 Chloroform ND ug/L 04/24/16 19:18 67-66-31.0 1 Chloromethane ND ug/L 04/24/16 19:18 74-87-31.0 1 Dibromochloromethane ND ug/L 04/24/16 19:18 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/24/16 19:18 106-93-41.0 1 Dibromomethane ND ug/L 04/24/16 19:18 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/24/16 19:18 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/24/16 19:18 106-46-71.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 42 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:MW-17 Lab ID:92294250019 Collected:04/19/16 11:45 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level trans-1,4-Dichloro-2-butene ND ug/L 04/24/16 19:18 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/24/16 19:18 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/24/16 19:18 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/24/16 19:18 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/24/16 19:18 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/24/16 19:18 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/24/16 19:18 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/24/16 19:18 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/24/16 19:18 10061-02-61.0 1 Ethylbenzene ND ug/L 04/24/16 19:18 100-41-41.0 1 2-Hexanone ND ug/L 04/24/16 19:18 591-78-65.0 1 Iodomethane ND ug/L 04/24/16 19:18 74-88-45.0 1 Methylene Chloride ND ug/L 04/24/16 19:18 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/24/16 19:18 108-10-15.0 1 Styrene ND ug/L 04/24/16 19:18 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/24/16 19:18 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/24/16 19:18 79-34-51.0 1 Tetrachloroethene ND ug/L 04/24/16 19:18 127-18-41.0 1 Toluene ND ug/L 04/24/16 19:18 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/24/16 19:18 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/24/16 19:18 79-00-51.0 1 Trichloroethene ND ug/L 04/24/16 19:18 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/24/16 19:18 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/24/16 19:18 96-18-41.0 1 Vinyl acetate ND ug/L 04/24/16 19:18 108-05-42.0 1 Vinyl chloride ND ug/L 04/24/16 19:18 75-01-41.0 1 Xylene (Total)ND ug/L 04/24/16 19:18 1330-20-72.0 1 m&p-Xylene ND ug/L 04/24/16 19:18 179601-23-12.0 1 o-Xylene ND ug/L 04/24/16 19:18 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %04/24/16 19:18 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %04/24/16 19:18 17060-07-070-130 1 Toluene-d8 (S)98 %04/24/16 19:18 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 43 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:TVL BLK Lab ID:92294250020 Collected:04/19/16 08:15 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 04:37 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 04:37 107-13-110.0 1 Benzene ND ug/L 04/21/16 04:37 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 04:37 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 04:37 75-27-41.0 1 Bromoform ND ug/L 04/21/16 04:37 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 04:37 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 04:37 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 04:37 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 04:37 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 04:37 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 04:37 75-00-31.0 1 Chloroform ND ug/L 04/21/16 04:37 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 04:37 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 04:37 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 04:37 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 04:37 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 04:37 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 04:37 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 04:37 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/21/16 04:37 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 04:37 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 04:37 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 04:37 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 04:37 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 04:37 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 04:37 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 04:37 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 04:37 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 04:37 591-78-65.0 1 Iodomethane ND ug/L 04/21/16 04:37 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 04:37 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 04:37 108-10-15.0 1 Styrene ND ug/L 04/21/16 04:37 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 04:37 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 04:37 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 04:37 127-18-41.0 1 Toluene ND ug/L 04/21/16 04:37 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 04:37 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 04:37 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 04:37 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 04:37 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 04:37 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 04:37 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 04:37 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 04:37 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 04:37 179601-23-12.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 44 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:TVL BLK Lab ID:92294250020 Collected:04/19/16 08:15 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level o-Xylene ND ug/L 04/21/16 04:37 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %04/21/16 04:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)98 %04/21/16 04:37 17060-07-070-130 1 Toluene-d8 (S)100 %04/21/16 04:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 45 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:EQUIP BLK Lab ID:92294250021 Collected:04/19/16 08:16 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 04/23/16 00:22 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/23/16 00:22 7440-38-204/21/16 18:3010.0 1 Barium ND ug/L 04/23/16 00:22 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/23/16 00:22 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/23/16 00:22 7440-43-904/21/16 18:301.0 1 Chromium ND ug/L 04/23/16 00:22 7440-47-304/21/16 18:305.0 1 Cobalt ND ug/L 04/23/16 00:22 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/23/16 00:22 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/23/16 00:22 7439-92-104/21/16 18:305.0 1 Nickel ND ug/L 04/23/16 00:22 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/23/16 00:22 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/23/16 00:22 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/23/16 00:22 7440-28-004/21/16 18:305.4 1 Vanadium ND ug/L 04/23/16 00:22 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/23/16 00:22 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/21/16 04:54 67-64-125.0 1 Acrylonitrile ND ug/L 04/21/16 04:54 107-13-110.0 1 Benzene ND ug/L 04/21/16 04:54 71-43-21.0 1 Bromochloromethane ND ug/L 04/21/16 04:54 74-97-51.0 1 Bromodichloromethane ND ug/L 04/21/16 04:54 75-27-41.0 1 Bromoform ND ug/L 04/21/16 04:54 75-25-21.0 1 Bromomethane ND ug/L 04/21/16 04:54 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/21/16 04:54 78-93-35.0 1 Carbon disulfide ND ug/L 04/21/16 04:54 75-15-02.0 1 Carbon tetrachloride ND ug/L 04/21/16 04:54 56-23-51.0 1 Chlorobenzene ND ug/L 04/21/16 04:54 108-90-71.0 1 Chloroethane ND ug/L 04/21/16 04:54 75-00-31.0 1 Chloroform ND ug/L 04/21/16 04:54 67-66-31.0 1 Chloromethane ND ug/L 04/21/16 04:54 74-87-31.0 1 Dibromochloromethane ND ug/L 04/21/16 04:54 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/21/16 04:54 106-93-41.0 1 Dibromomethane ND ug/L 04/21/16 04:54 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/21/16 04:54 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 04/21/16 04:54 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 04/21/16 04:54 110-57-61.0 1 1,1-Dichloroethane ND ug/L 04/21/16 04:54 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/21/16 04:54 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/21/16 04:54 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/21/16 04:54 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/21/16 04:54 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/21/16 04:54 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 04/21/16 04:54 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/21/16 04:54 10061-02-61.0 1 Ethylbenzene ND ug/L 04/21/16 04:54 100-41-41.0 1 2-Hexanone ND ug/L 04/21/16 04:54 591-78-65.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 46 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:EQUIP BLK Lab ID:92294250021 Collected:04/19/16 08:16 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Iodomethane ND ug/L 04/21/16 04:54 74-88-45.0 1 Methylene Chloride ND ug/L 04/21/16 04:54 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/21/16 04:54 108-10-15.0 1 Styrene ND ug/L 04/21/16 04:54 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/21/16 04:54 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/21/16 04:54 79-34-51.0 1 Tetrachloroethene ND ug/L 04/21/16 04:54 127-18-41.0 1 Toluene ND ug/L 04/21/16 04:54 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 04/21/16 04:54 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/21/16 04:54 79-00-51.0 1 Trichloroethene ND ug/L 04/21/16 04:54 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/21/16 04:54 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/21/16 04:54 96-18-41.0 1 Vinyl acetate ND ug/L 04/21/16 04:54 108-05-42.0 1 Vinyl chloride ND ug/L 04/21/16 04:54 75-01-41.0 1 Xylene (Total)ND ug/L 04/21/16 04:54 1330-20-72.0 1 m&p-Xylene ND ug/L 04/21/16 04:54 179601-23-12.0 1 o-Xylene ND ug/L 04/21/16 04:54 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)101 %04/21/16 04:54 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %04/21/16 04:54 17060-07-070-130 1 Toluene-d8 (S)100 %04/21/16 04:54 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 47 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:Lechate Lab ID:92294250022 Collected:04/19/16 12:55 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method:Field Data Collected By Mark Swann 04/20/16 16:141 Collected Date 4/19/16 04/20/16 16:141 Collected Time 12:55 04/20/16 16:141 Field pH 7.7 Std. Units 04/20/16 16:140.10 1 Field Temperature 21.8 deg C 04/20/16 16:140.50 1 Field Specific Conductance 6332 umhos/cm 04/20/16 16:141.0 1 Turbidity 55.77 NTU 04/20/16 16:141.0 1 Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony 17.4 ug/L 04/23/16 10:36 7440-36-004/21/16 18:305.0 1 Arsenic ND ug/L 04/23/16 10:36 7440-38-204/21/16 18:3010.0 1 Barium 228 ug/L 04/23/16 10:36 7440-39-304/21/16 18:305.0 1 Beryllium ND ug/L 04/23/16 10:36 7440-41-704/21/16 18:301.0 1 Cadmium ND ug/L 04/23/16 10:36 7440-43-904/21/16 18:301.0 1 Chromium 11.4 ug/L 04/23/16 10:36 7440-47-304/21/16 18:305.0 1 Cobalt 7.6 ug/L 04/23/16 10:36 7440-48-404/21/16 18:305.0 1 Copper ND ug/L 04/23/16 10:36 7440-50-804/21/16 18:305.0 1 Lead ND ug/L 04/23/16 10:36 7439-92-104/21/16 18:305.0 1 Nickel 60.3 ug/L 04/23/16 10:36 7440-02-004/21/16 18:305.0 1 Selenium ND ug/L 04/23/16 10:36 7782-49-204/21/16 18:3010.0 1 Silver ND ug/L 04/23/16 10:36 7440-22-404/21/16 18:305.0 1 Thallium ND ug/L 04/23/16 10:36 7440-28-004/21/16 18:3010.0 1 Vanadium 14.5 ug/L 04/23/16 10:36 7440-62-204/21/16 18:305.0 1 Zinc ND ug/L 04/23/16 10:36 7440-66-604/21/16 18:3010.0 1 Analytical Method: EPA 82608260 MSV Low Level Acetone ND ug/L 04/22/16 18:21 67-64-125.0 1 Benzene ND ug/L 04/22/16 18:21 71-43-21.0 1 Bromobenzene ND ug/L 04/22/16 18:21 108-86-11.0 1 Bromochloromethane ND ug/L 04/22/16 18:21 74-97-51.0 1 Bromodichloromethane ND ug/L 04/22/16 18:21 75-27-41.0 1 Bromoform ND ug/L 04/22/16 18:21 75-25-21.0 1 Bromomethane ND ug/L 04/22/16 18:21 74-83-92.0 1 2-Butanone (MEK)ND ug/L 04/22/16 18:21 78-93-35.0 1 Carbon tetrachloride ND ug/L 04/22/16 18:21 56-23-51.0 1 Chlorobenzene ND ug/L 04/22/16 18:21 108-90-71.0 1 Chloroethane ND ug/L 04/22/16 18:21 75-00-31.0 1 Chloroform ND ug/L 04/22/16 18:21 67-66-31.0 1 Chloromethane ND ug/L 04/22/16 18:21 74-87-31.0 1 2-Chlorotoluene ND ug/L 04/22/16 18:21 95-49-81.0 1 4-Chlorotoluene ND ug/L 04/22/16 18:21 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 04/22/16 18:21 96-12-82.0 1 Dibromochloromethane ND ug/L 04/22/16 18:21 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 04/22/16 18:21 106-93-41.0 1 Dibromomethane ND ug/L 04/22/16 18:21 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 04/22/16 18:21 95-50-11.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 48 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:Lechate Lab ID:92294250022 Collected:04/19/16 12:55 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level 1,3-Dichlorobenzene ND ug/L 04/22/16 18:21 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 04/22/16 18:21 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 04/22/16 18:21 75-71-81.0 1 1,1-Dichloroethane ND ug/L 04/22/16 18:21 75-34-31.0 1 1,2-Dichloroethane ND ug/L 04/22/16 18:21 107-06-21.0 1 1,1-Dichloroethene ND ug/L 04/22/16 18:21 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 04/22/16 18:21 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 04/22/16 18:21 156-60-51.0 1 1,2-Dichloropropane ND ug/L 04/22/16 18:21 78-87-51.0 1 1,3-Dichloropropane ND ug/L 04/22/16 18:21 142-28-91.0 1 2,2-Dichloropropane ND ug/L 04/22/16 18:21 594-20-71.0 1 1,1-Dichloropropene ND ug/L 04/22/16 18:21 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 04/22/16 18:21 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 04/22/16 18:21 10061-02-61.0 1 Diisopropyl ether ND ug/L 04/22/16 18:21 108-20-31.0 1 Ethylbenzene ND ug/L 04/22/16 18:21 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 04/22/16 18:21 87-68-31.0 1 2-Hexanone ND ug/L 04/22/16 18:21 591-78-65.0 1 p-Isopropyltoluene ND ug/L 04/22/16 18:21 99-87-61.0 1 Methylene Chloride ND ug/L 04/22/16 18:21 75-09-22.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/22/16 18:21 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 04/22/16 18:21 1634-04-41.0 1 Naphthalene ND ug/L 04/22/16 18:21 91-20-31.0 1 Styrene ND ug/L 04/22/16 18:21 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 04/22/16 18:21 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 04/22/16 18:21 79-34-51.0 1 Tetrachloroethene ND ug/L 04/22/16 18:21 127-18-41.0 1 Toluene ND ug/L 04/22/16 18:21 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 04/22/16 18:21 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 04/22/16 18:21 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 04/22/16 18:21 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 04/22/16 18:21 79-00-51.0 1 Trichloroethene ND ug/L 04/22/16 18:21 79-01-61.0 1 Trichlorofluoromethane ND ug/L 04/22/16 18:21 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 04/22/16 18:21 96-18-41.0 1 Vinyl acetate ND ug/L 04/22/16 18:21 108-05-42.0 1 Vinyl chloride ND ug/L 04/22/16 18:21 75-01-41.0 1 Xylene (Total)ND ug/L 04/22/16 18:21 1330-20-72.0 1 m&p-Xylene ND ug/L 04/22/16 18:21 179601-23-12.0 1 o-Xylene ND ug/L 04/22/16 18:21 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)101 %04/22/16 18:21 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %04/22/16 18:21 17060-07-070-130 1 Toluene-d8 (S)99 %04/22/16 18:21 2037-26-570-130 1 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day 65.3 mg/L 04/26/16 09:58 D604/21/16 12:052.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 49 of 97 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Sample:Lechate Lab ID:92294250022 Collected:04/19/16 12:55 Received:04/19/16 16:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 528 mg/L 04/25/16 22:48 14808-79-840.0 20 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 0.075 mg/L 04/20/16 07:430.020 1 Nitrogen, Nitrite 0.049 mg/L 04/20/16 07:430.020 1 Nitrogen, NO2 plus NO3 0.12 mg/L 04/20/16 07:430.020 1 Analytical Method: EPA 365.1365.1 Phosphorus, Total Phosphorus 0.68 mg/L 04/22/16 02:45 7723-14-00.050 1 Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total Cyanide ND mg/L 04/26/16 08:06 57-12-50.0080 1 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand 396 mg/L 04/25/16 16:3025.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 50 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/21439 EPA 3010A EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92294250001, 92294250002, 92294250003, 92294250004, 92294250005, 92294250006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1714108 Associated Lab Samples:92294250001, 92294250002, 92294250003, 92294250004, 92294250005, 92294250006 Matrix:Water Analyzed Antimony ug/L ND 5.0 04/23/16 11:45 Arsenic ug/L ND 10.0 04/23/16 11:45 Barium ug/L ND 5.0 04/23/16 11:45 Beryllium ug/L ND 1.0 04/23/16 11:45 Cadmium ug/L ND 1.0 04/23/16 11:45 Chromium ug/L ND 5.0 04/23/16 11:45 Cobalt ug/L ND 5.0 04/23/16 11:45 Copper ug/L ND 5.0 04/23/16 11:45 Lead ug/L ND 5.0 04/23/16 11:45 Nickel ug/L ND 5.0 04/23/16 11:45 Selenium ug/L ND 10.0 04/23/16 11:45 Silver ug/L ND 5.0 04/23/16 11:45 Thallium ug/L ND 5.4 04/23/16 11:45 Vanadium ug/L ND 5.0 04/23/16 11:45 Zinc ug/L ND 10.0 04/23/16 11:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1714109LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 465500 93 80-120 Arsenic ug/L 444500 89 80-120 Barium ug/L 461500 92 80-120 Beryllium ug/L 458500 92 80-120 Cadmium ug/L 460500 92 80-120 Chromium ug/L 461500 92 80-120 Cobalt ug/L 460500 92 80-120 Copper ug/L 465500 93 80-120 Lead ug/L 459500 92 80-120 Nickel ug/L 459500 92 80-120 Selenium ug/L 458500 92 80-120 Silver ug/L 230250 92 80-120 Thallium ug/L 452500 90 80-120 Vanadium ug/L 464500 93 80-120 Zinc ug/L 459500 92 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 51 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1714110MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293551010 1714111 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 83 75-12580 3500ND416402 Arsenic ug/L 500 81 75-12578 3500ND405391 Barium ug/L 500 81 75-12579 250017.9 424 414 Beryllium ug/L 500 81 75-12579 2500ND407397 Cadmium ug/L 500 83 75-12581 3500ND418405 Chromium ug/L 500 82 75-12579 3500ND409397 Cobalt ug/L 500 81 75-12579 3500ND406393 Copper ug/L 500 83 75-12580 3500ND416403 Lead ug/L 500 82 75-12580 3500ND410398 Nickel ug/L 500 81 75-12578 4500ND408394 Selenium ug/L 500 83 75-12580 4500ND417402 Silver ug/L 250 86 75-12585 2250ND216212 Thallium ug/L 500 81 75-12579 3500ND410400 Vanadium ug/L 500 83 75-12580 3500ND413401 Zinc ug/L 500 82 75-12579 4500ND410396 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 52 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/21462 EPA 3010A EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92294250007, 92294250008, 92294250009, 92294250010, 92294250011, 92294250012, 92294250013, 92294250014, 92294250015, 92294250016 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716826 Associated Lab Samples:92294250007, 92294250008, 92294250009, 92294250010, 92294250011, 92294250012, 92294250013, 92294250014, 92294250015, 92294250016 Matrix:Water Analyzed Antimony ug/L ND 5.0 04/22/16 21:55 Arsenic ug/L ND 10.0 04/22/16 21:55 Barium ug/L ND 5.0 04/22/16 21:55 Beryllium ug/L ND 1.0 04/22/16 21:55 Cadmium ug/L ND 1.0 04/22/16 21:55 Chromium ug/L ND 5.0 04/22/16 21:55 Cobalt ug/L ND 5.0 04/22/16 21:55 Copper ug/L ND 5.0 04/22/16 21:55 Lead ug/L ND 5.0 04/22/16 21:55 Nickel ug/L ND 5.0 04/22/16 21:55 Selenium ug/L ND 10.0 04/22/16 21:55 Silver ug/L ND 5.0 04/22/16 21:55 Thallium ug/L ND 5.4 04/22/16 21:55 Vanadium ug/L ND 5.0 04/22/16 21:55 Zinc ug/L ND 10.0 04/22/16 21:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716827LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 466500 93 80-120 Arsenic ug/L 451500 90 80-120 Barium ug/L 467500 93 80-120 Beryllium ug/L 460500 92 80-120 Cadmium ug/L 464500 93 80-120 Chromium ug/L 467500 93 80-120 Cobalt ug/L 463500 93 80-120 Copper ug/L 470500 94 80-120 Lead ug/L 461500 92 80-120 Nickel ug/L 466500 93 80-120 Selenium ug/L 457500 91 80-120 Silver ug/L 235250 94 80-120 Thallium ug/L 451500 90 80-120 Vanadium ug/L 470500 94 80-120 Zinc ug/L 462500 92 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 53 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1716828MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294568001 1716829 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 86 75-12589 4500ND430447 Arsenic ug/L 500 83 75-12587 4500ND416435 Barium ug/L 500 86 75-12590 450017.2J 448 467 Beryllium ug/L 500 85 75-12589 4500ND426444 Cadmium ug/L 500 86 75-12589 3500ND430444 Chromium ug/L 500 87 75-12590 4500ND435453 Cobalt ug/L 500 85 75-12588 4500ND426443 Copper ug/L 500 88 75-12591 4500ND439458 Lead ug/L 500 84 75-12588 4500ND422438 Nickel ug/L 500 86 75-12589 4500ND430447 Selenium ug/L 500 84 75-12588 5500ND422443 Silver ug/L 250 88 75-12591 3250ND220227 Thallium ug/L 500 83 75-12586 4500ND415432 Vanadium ug/L 500 88 75-12592 45003.7J 442 462 Zinc ug/L 500 86 75-12589 4500ND429446 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 54 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/21463 EPA 3010A EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92294250017, 92294250018, 92294250019, 92294250021 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716847 Associated Lab Samples:92294250017, 92294250018, 92294250019, 92294250021 Matrix:Water Analyzed Antimony ug/L ND 5.0 04/22/16 23:57 Arsenic ug/L ND 10.0 04/22/16 23:57 Barium ug/L ND 5.0 04/22/16 23:57 Beryllium ug/L ND 1.0 04/22/16 23:57 Cadmium ug/L ND 1.0 04/22/16 23:57 Chromium ug/L ND 5.0 04/22/16 23:57 Cobalt ug/L ND 5.0 04/22/16 23:57 Copper ug/L ND 5.0 04/22/16 23:57 Lead ug/L ND 5.0 04/22/16 23:57 Nickel ug/L ND 5.0 04/22/16 23:57 Selenium ug/L ND 10.0 04/22/16 23:57 Silver ug/L ND 5.0 04/22/16 23:57 Thallium ug/L ND 5.4 04/22/16 23:57 Vanadium ug/L ND 5.0 04/22/16 23:57 Zinc ug/L ND 10.0 04/22/16 23:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716848LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 475500 95 80-120 Arsenic ug/L 460500 92 80-120 Barium ug/L 477500 95 80-120 Beryllium ug/L 474500 95 80-120 Cadmium ug/L 476500 95 80-120 Chromium ug/L 477500 95 80-120 Cobalt ug/L 475500 95 80-120 Copper ug/L 481500 96 80-120 Lead ug/L 472500 94 80-120 Nickel ug/L 475500 95 80-120 Selenium ug/L 466500 93 80-120 Silver ug/L 240250 96 80-120 Thallium ug/L 459500 92 80-120 Vanadium ug/L 482500 96 80-120 Zinc ug/L 473500 95 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 55 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1716849MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294250017 1716850 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 88 75-12590 3500ND438452 Arsenic ug/L 500 85 75-12588 4500ND425441 Barium ug/L 500 88 75-12590 350022.8 462 474 Beryllium ug/L 500 88 75-12590 3500ND438450 Cadmium ug/L 500 88 75-12590 2500ND440449 Chromium ug/L 500 89 75-12591 3500ND444456 Cobalt ug/L 500 88 75-12590 2500ND439450 Copper ug/L 500 89 75-12592 3500ND447460 Lead ug/L 500 87 75-12589 2500ND435445 Nickel ug/L 500 88 75-12590 2500ND440451 Selenium ug/L 500 87 75-12588 1500ND433439 Silver ug/L 250 89 75-12592 3250ND223229 Thallium ug/L 500 85 75-12587 2500ND426434 Vanadium ug/L 500 90 75-12592 3500ND448460 Zinc ug/L 500 88 75-12590 2500ND441451 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 56 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/21465 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716872 Associated Lab Samples:92294250022 Matrix:Water Analyzed Antimony ug/L ND 5.0 04/23/16 09:07 Arsenic ug/L ND 10.0 04/23/16 09:07 Barium ug/L ND 5.0 04/23/16 09:07 Beryllium ug/L ND 1.0 04/23/16 09:07 Cadmium ug/L ND 1.0 04/23/16 09:07 Chromium ug/L ND 5.0 04/23/16 09:07 Cobalt ug/L ND 5.0 04/23/16 09:07 Copper ug/L ND 5.0 04/23/16 09:07 Lead ug/L ND 5.0 04/23/16 09:07 Nickel ug/L ND 5.0 04/23/16 09:07 Selenium ug/L ND 10.0 04/23/16 09:07 Silver ug/L ND 5.0 04/23/16 09:07 Thallium ug/L ND 10.0 04/23/16 09:07 Vanadium ug/L ND 5.0 04/23/16 09:07 Zinc ug/L ND 10.0 04/23/16 09:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716873LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 474500 95 80-120 Arsenic ug/L 459500 92 80-120 Barium ug/L 464500 93 80-120 Beryllium ug/L 462500 92 80-120 Cadmium ug/L 472500 94 80-120 Chromium ug/L 475500 95 80-120 Cobalt ug/L 472500 94 80-120 Copper ug/L 476500 95 80-120 Lead ug/L 468500 94 80-120 Nickel ug/L 471500 94 80-120 Selenium ug/L 467500 93 80-120 Silver ug/L 236250 94 80-120 Thallium ug/L 461500 92 80-120 Vanadium ug/L 479500 96 80-120 Zinc ug/L 470500 94 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 57 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1716874MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294473002 1716875 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 92 75-12592 0500ND464462 Arsenic ug/L 500 90 75-12590 1500ND456452 Barium ug/L 500 92 75-12589 2500114575561 Beryllium ug/L 500 93 75-12590 3500ND465452 Cadmium ug/L 500 92 75-12592 1500ND461458 Chromium ug/L 500 92 75-12589 3500ND464449 Cobalt ug/L 500 89 75-12589 15007.3 453 451 Copper ug/L 500 93 75-12590 3500ND467453 Lead ug/L 500 89 75-12589 1500ND447445 Nickel ug/L 500 89 75-12588 1500ND448445 Selenium ug/L 500 90 75-12590 0500ND449448 Silver ug/L 250 92 75-12588 4250ND229221 Thallium ug/L 500 86 75-12586 0500ND434432 Vanadium ug/L 500 94 75-12592 3500ND472458 Zinc ug/L 500 89 75-12589 0500ND449449 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 58 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/36500 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92294250001, 92294250002, 92294250003, 92294250004, 92294250005, 92294250006, 92294250020, 92294250021 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1715847 Associated Lab Samples:92294250001, 92294250002, 92294250003, 92294250004, 92294250005, 92294250006, 92294250020, 92294250021 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 04/21/16 04:20 1,1,1-Trichloroethane ug/L ND 1.0 04/21/16 04:20 1,1,2,2-Tetrachloroethane ug/L ND 1.0 04/21/16 04:20 1,1,2-Trichloroethane ug/L ND 1.0 04/21/16 04:20 1,1-Dichloroethane ug/L ND 1.0 04/21/16 04:20 1,1-Dichloroethene ug/L ND 1.0 04/21/16 04:20 1,2,3-Trichloropropane ug/L ND 1.0 04/21/16 04:20 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/21/16 04:20 1,2-Dichlorobenzene ug/L ND 1.0 04/21/16 04:20 1,2-Dichloroethane ug/L ND 1.0 04/21/16 04:20 1,2-Dichloropropane ug/L ND 1.0 04/21/16 04:20 1,4-Dichlorobenzene ug/L ND 1.0 04/21/16 04:20 2-Butanone (MEK)ug/L ND 5.0 04/21/16 04:20 2-Hexanone ug/L ND 5.0 04/21/16 04:20 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 04/21/16 04:20 Acetone ug/L ND 25.0 04/21/16 04:20 Acrylonitrile ug/L ND 10.0 04/21/16 04:20 Benzene ug/L ND 1.0 04/21/16 04:20 Bromochloromethane ug/L ND 1.0 04/21/16 04:20 Bromodichloromethane ug/L ND 1.0 04/21/16 04:20 Bromoform ug/L ND 1.0 04/21/16 04:20 Bromomethane ug/L ND 2.0 04/21/16 04:20 Carbon disulfide ug/L ND 2.0 04/21/16 04:20 Carbon tetrachloride ug/L ND 1.0 04/21/16 04:20 Chlorobenzene ug/L ND 1.0 04/21/16 04:20 Chloroethane ug/L ND 1.0 04/21/16 04:20 Chloroform ug/L ND 1.0 04/21/16 04:20 Chloromethane ug/L ND 1.0 04/21/16 04:20 cis-1,2-Dichloroethene ug/L ND 1.0 04/21/16 04:20 cis-1,3-Dichloropropene ug/L ND 1.0 04/21/16 04:20 Dibromochloromethane ug/L ND 1.0 04/21/16 04:20 Dibromomethane ug/L ND 1.0 04/21/16 04:20 Ethylbenzene ug/L ND 1.0 04/21/16 04:20 Iodomethane ug/L ND 5.0 04/21/16 04:20 m&p-Xylene ug/L ND 2.0 04/21/16 04:20 Methylene Chloride ug/L ND 2.0 04/21/16 04:20 o-Xylene ug/L ND 1.0 04/21/16 04:20 Styrene ug/L ND 1.0 04/21/16 04:20 Tetrachloroethene ug/L ND 1.0 04/21/16 04:20 Toluene ug/L ND 1.0 04/21/16 04:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 59 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1715847 Associated Lab Samples:92294250001, 92294250002, 92294250003, 92294250004, 92294250005, 92294250006, 92294250020, 92294250021 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 04/21/16 04:20 trans-1,3-Dichloropropene ug/L ND 1.0 04/21/16 04:20 trans-1,4-Dichloro-2-butene ug/L ND 1.0 04/21/16 04:20 Trichloroethene ug/L ND 1.0 04/21/16 04:20 Trichlorofluoromethane ug/L ND 1.0 04/21/16 04:20 Vinyl acetate ug/L ND 2.0 04/21/16 04:20 Vinyl chloride ug/L ND 1.0 04/21/16 04:20 Xylene (Total)ug/L ND 2.0 04/21/16 04:20 1,2-Dichloroethane-d4 (S)%100 70-130 04/21/16 04:20 4-Bromofluorobenzene (S)%98 70-130 04/21/16 04:20 Toluene-d8 (S)%100 70-130 04/21/16 04:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1715848LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.450 101 70-130 1,1,1-Trichloroethane ug/L 49.350 99 70-130 1,1,2,2-Tetrachloroethane ug/L 49.150 98 70-130 1,1,2-Trichloroethane ug/L 48.950 98 70-130 1,1-Dichloroethane ug/L 47.450 95 70-130 1,1-Dichloroethene ug/L 50.150 100 70-132 1,2,3-Trichloropropane ug/L 51.750 103 70-130 1,2-Dibromoethane (EDB)ug/L 52.150 104 70-130 1,2-Dichlorobenzene ug/L 49.050 98 70-130 1,2-Dichloroethane ug/L 43.950 88 70-130 1,2-Dichloropropane ug/L 47.850 96 70-130 1,4-Dichlorobenzene ug/L 49.350 99 70-130 2-Butanone (MEK)ug/L 93.4100 93 70-145 2-Hexanone ug/L 100100 100 70-144 4-Methyl-2-pentanone (MIBK)ug/L 104100 104 70-140 Acetone ug/L 83.8100 84 50-175 Acrylonitrile ug/L 239250 96 70-143 Benzene ug/L 49.150 98 70-130 Bromochloromethane ug/L 45.750 91 70-130 Bromodichloromethane ug/L 48.150 96 70-130 Bromoform ug/L 49.150 98 70-130 Bromomethane ug/L 39.750 79 54-130 Carbon disulfide ug/L 48.850 98 70-131 Carbon tetrachloride ug/L 51.350 103 70-132 Chlorobenzene ug/L 49.850 100 70-130 Chloroethane ug/L 44.550 89 64-134 Chloroform ug/L 46.750 93 70-130 Chloromethane ug/L 50.450 101 64-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 60 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1715848LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 47.350 95 70-131 cis-1,3-Dichloropropene ug/L 48.650 97 70-130 Dibromochloromethane ug/L 51.550 103 70-130 Dibromomethane ug/L 47.550 95 70-131 Ethylbenzene ug/L 49.450 99 70-130 Iodomethane ug/L 93.8100 94 49-180 m&p-Xylene ug/L 96.5100 96 70-130 Methylene Chloride ug/L 51.250 102 63-130 o-Xylene ug/L 48.550 97 70-130 Styrene ug/L 50.250 100 70-130 Tetrachloroethene ug/L 49.550 99 70-130 Toluene ug/L 49.550 99 70-130 trans-1,2-Dichloroethene ug/L 47.250 94 70-130 trans-1,3-Dichloropropene ug/L 48.450 97 70-132 trans-1,4-Dichloro-2-butene ug/L 43.150 86 70-141 Trichloroethene ug/L 49.350 99 70-130 Trichlorofluoromethane ug/L 47.550 95 62-133 Vinyl acetate ug/L 99.8100 100 66-157 Vinyl chloride ug/L 50.450 101 50-150 Xylene (Total)ug/L 145150 97 70-130 1,2-Dichloroethane-d4 (S)%101 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1715850MATRIX SPIKE SAMPLE: MSSpike Result 92294222023 1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND 1,1,1-Trichloroethane ug/L 22.320 111 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.820 104 70-130ND 1,1,2-Trichloroethane ug/L 20.220 101 70-130ND 1,1-Dichloroethane ug/L 21.020 105 70-130ND 1,1-Dichloroethene ug/L 40.420 113 70-16617.7 1,2,3-Trichloropropane ug/L 21.220 106 70-130ND 1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND 1,2-Dichlorobenzene ug/L 20.920 104 70-130ND 1,2-Dichloroethane ug/L 18.820 93 70-130ND 1,2-Dichloropropane ug/L 21.020 105 70-130ND 1,4-Dichlorobenzene ug/L 21.020 105 70-130ND 2-Butanone (MEK)ug/L 40.840 102 70-130ND 2-Hexanone ug/L 43.140 108 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 44.140 110 70-130ND Acetone ug/L 41.440 98 70-130ND Acrylonitrile ug/L 103100 103 70-130ND Benzene ug/L 22.320 111 70-148ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 61 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1715850MATRIX SPIKE SAMPLE: MSSpike Result 92294222023 Bromochloromethane ug/L 20.620 103 70-130ND Bromodichloromethane ug/L 20.620 103 70-130ND Bromoform ug/L 20.020 100 70-130ND Bromomethane ug/L 19.220 96 70-130ND Carbon disulfide ug/L 22.020 110 70-130ND Carbon tetrachloride ug/L 23.320 117 70-130ND Chlorobenzene ug/L 21.520 108 70-146ND Chloroethane ug/L 20.120 100 70-130ND Chloroform ug/L 20.320 101 70-130ND Chloromethane ug/L 21.820 109 70-130ND cis-1,2-Dichloroethene ug/L 21.220 106 70-130ND cis-1,3-Dichloropropene ug/L 20.220 101 70-130ND Dibromochloromethane ug/L 20.820 104 70-130ND Dibromomethane ug/L 20.520 102 70-130ND Ethylbenzene ug/L 22.320 112 70-130ND Iodomethane ug/L 40.840 102 70-130ND m&p-Xylene ug/L 43.740 109 70-130ND Methylene Chloride ug/L 21.920 109 70-130ND o-Xylene ug/L 21.520 107 70-130ND Styrene ug/L 21.620 108 70-130ND Tetrachloroethene ug/L 22.220 111 70-130ND Toluene ug/L 22.320 111 70-155ND trans-1,2-Dichloroethene ug/L 21.420 107 70-130ND trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND trans-1,4-Dichloro-2-butene ug/L 18.220 91 70-130ND Trichloroethene ug/L 21.820 109 69-151ND Trichlorofluoromethane ug/L 22.420 112 70-130ND Vinyl acetate ug/L 37.340 93 70-130ND Vinyl chloride ug/L 22.620 113 70-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result QualifiersRPDResult 92294222022 1715849SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L .72JND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 62 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92294222022 1715849SAMPLE DUPLICATE: 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND 1,4-Dichlorobenzene ug/L NDND 2-Butanone (MEK)ug/L NDND 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND m&p-Xylene ug/L NDND Methylene Chloride ug/L NDND o-Xylene ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%101 2103 4-Bromofluorobenzene (S)%98 199 Toluene-d8 (S)%100 0100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 63 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/36518 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92294250016 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716716 Associated Lab Samples:92294250016 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 04/21/16 16:19 1,1,1-Trichloroethane ug/L ND 1.0 04/21/16 16:19 1,1,2,2-Tetrachloroethane ug/L ND 1.0 04/21/16 16:19 1,1,2-Trichloroethane ug/L ND 1.0 04/21/16 16:19 1,1-Dichloroethane ug/L ND 1.0 04/21/16 16:19 1,1-Dichloroethene ug/L ND 1.0 04/21/16 16:19 1,2,3-Trichloropropane ug/L ND 1.0 04/21/16 16:19 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/21/16 16:19 1,2-Dichlorobenzene ug/L ND 1.0 04/21/16 16:19 1,2-Dichloroethane ug/L ND 1.0 04/21/16 16:19 1,2-Dichloropropane ug/L ND 1.0 04/21/16 16:19 1,4-Dichlorobenzene ug/L ND 1.0 04/21/16 16:19 2-Butanone (MEK)ug/L ND 5.0 04/21/16 16:19 2-Hexanone ug/L ND 5.0 04/21/16 16:19 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 04/21/16 16:19 Acetone ug/L ND 25.0 04/21/16 16:19 Acrylonitrile ug/L ND 10.0 04/21/16 16:19 Benzene ug/L ND 1.0 04/21/16 16:19 Bromochloromethane ug/L ND 1.0 04/21/16 16:19 Bromodichloromethane ug/L ND 1.0 04/21/16 16:19 Bromoform ug/L ND 1.0 04/21/16 16:19 Bromomethane ug/L ND 2.0 04/21/16 16:19 Carbon disulfide ug/L ND 2.0 04/21/16 16:19 Carbon tetrachloride ug/L ND 1.0 04/21/16 16:19 Chlorobenzene ug/L ND 1.0 04/21/16 16:19 Chloroethane ug/L ND 1.0 04/21/16 16:19 Chloroform ug/L ND 1.0 04/21/16 16:19 Chloromethane ug/L ND 1.0 04/21/16 16:19 cis-1,2-Dichloroethene ug/L ND 1.0 04/21/16 16:19 cis-1,3-Dichloropropene ug/L ND 1.0 04/21/16 16:19 Dibromochloromethane ug/L ND 1.0 04/21/16 16:19 Dibromomethane ug/L ND 1.0 04/21/16 16:19 Ethylbenzene ug/L ND 1.0 04/21/16 16:19 Iodomethane ug/L ND 5.0 04/21/16 16:19 m&p-Xylene ug/L ND 2.0 04/21/16 16:19 Methylene Chloride ug/L ND 2.0 C904/21/16 16:19 o-Xylene ug/L ND 1.0 04/21/16 16:19 Styrene ug/L ND 1.0 04/21/16 16:19 Tetrachloroethene ug/L ND 1.0 04/21/16 16:19 Toluene ug/L ND 1.0 04/21/16 16:19 trans-1,2-Dichloroethene ug/L ND 1.0 04/21/16 16:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 64 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716716 Associated Lab Samples:92294250016 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 04/21/16 16:19 trans-1,4-Dichloro-2-butene ug/L ND 1.0 04/21/16 16:19 Trichloroethene ug/L ND 1.0 04/21/16 16:19 Trichlorofluoromethane ug/L ND 1.0 04/21/16 16:19 Vinyl acetate ug/L ND 2.0 04/21/16 16:19 Vinyl chloride ug/L ND 1.0 04/21/16 16:19 Xylene (Total)ug/L ND 2.0 04/21/16 16:19 1,2-Dichloroethane-d4 (S)%98 70-130 04/21/16 16:19 4-Bromofluorobenzene (S)%99 70-130 04/21/16 16:19 Toluene-d8 (S)%100 70-130 04/21/16 16:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716717LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,1-Trichloroethane ug/L 49.950 100 70-130 1,1,2,2-Tetrachloroethane ug/L 49.050 98 70-130 1,1,2-Trichloroethane ug/L 47.050 94 70-130 1,1-Dichloroethane ug/L 49.250 98 70-130 1,1-Dichloroethene ug/L 51.750 103 70-132 1,2,3-Trichloropropane ug/L 48.950 98 70-130 1,2-Dibromoethane (EDB)ug/L 52.550 105 70-130 1,2-Dichlorobenzene ug/L 48.350 97 70-130 1,2-Dichloroethane ug/L 43.250 86 70-130 1,2-Dichloropropane ug/L 48.450 97 70-130 1,4-Dichlorobenzene ug/L 49.550 99 70-130 2-Butanone (MEK)ug/L 89.7100 90 70-145 2-Hexanone ug/L 98.2100 98 70-144 4-Methyl-2-pentanone (MIBK)ug/L 101100 101 70-140 Acetone ug/L 85.9100 86 50-175 Acrylonitrile ug/L 233250 93 70-143 Benzene ug/L 50.450 101 70-130 Bromochloromethane ug/L 48.450 97 70-130 Bromodichloromethane ug/L 49.150 98 70-130 Bromoform ug/L 49.350 99 70-130 Bromomethane ug/L 43.150 86 54-130 Carbon disulfide ug/L 50.550 101 70-131 Carbon tetrachloride ug/L 52.350 105 70-132 Chlorobenzene ug/L 50.350 101 70-130 Chloroethane ug/L 46.350 93 64-134 Chloroform ug/L 47.750 95 70-130 Chloromethane ug/L 47.550 95 64-130 cis-1,2-Dichloroethene ug/L 48.650 97 70-131 cis-1,3-Dichloropropene ug/L 51.050 102 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 65 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716717LABORATORY CONTROL SAMPLE: LCSSpike Dibromochloromethane ug/L 50.850 102 70-130 Dibromomethane ug/L 47.950 96 70-131 Ethylbenzene ug/L 50.250 100 70-130 Iodomethane ug/L 102100 102 49-180 m&p-Xylene ug/L 99.0100 99 70-130 Methylene Chloride ug/L 51.550 103 63-130 o-Xylene ug/L 48.950 98 70-130 Styrene ug/L 50.950 102 70-130 Tetrachloroethene ug/L 50.750 101 70-130 Toluene ug/L 50.650 101 70-130 trans-1,2-Dichloroethene ug/L 50.550 101 70-130 trans-1,3-Dichloropropene ug/L 49.550 99 70-132 trans-1,4-Dichloro-2-butene ug/L 44.250 88 70-141 Trichloroethene ug/L 50.350 101 70-130 Trichlorofluoromethane ug/L 48.750 97 62-133 Vinyl acetate ug/L 98.3100 98 66-157 Vinyl chloride ug/L 51.150 102 50-150 Xylene (Total)ug/L 148150 99 70-130 1,2-Dichloroethane-d4 (S)%94 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1716719MATRIX SPIKE SAMPLE: MSSpike Result 92294555002 1,1,1,2-Tetrachloroethane ug/L 22.520 112 70-130ND 1,1,1-Trichloroethane ug/L 23.620 118 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.620 103 70-130ND 1,1,2-Trichloroethane ug/L 21.020 105 70-130ND 1,1-Dichloroethane ug/L 22.720 113 70-130ND 1,1-Dichloroethene ug/L 25.120 126 70-166ND 1,2,3-Trichloropropane ug/L 21.120 105 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.520 112 70-130ND 1,2-Dichlorobenzene ug/L 21.620 108 70-130ND 1,2-Dichloroethane ug/L 19.420 97 70-130ND 1,2-Dichloropropane ug/L 21.520 108 70-130ND 1,4-Dichlorobenzene ug/L 21.520 108 70-130ND 2-Butanone (MEK)ug/L 37.340 93 70-130ND 2-Hexanone ug/L 39.840 99 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 39.640 99 70-130ND Acetone ug/L 34.140 85 70-130ND Acrylonitrile ug/L 99.6100 100 70-130ND Benzene ug/L 22.620 113 70-148ND Bromochloromethane ug/L 22.520 112 70-130ND Bromodichloromethane ug/L 21.120 106 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 66 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1716719MATRIX SPIKE SAMPLE: MSSpike Result 92294555002 Bromoform ug/L 20.220 101 70-130ND Bromomethane ug/L 21.720 109 70-130ND Carbon disulfide ug/L 24.620 123 70-130ND Carbon tetrachloride ug/L 23.720 119 70-130ND Chlorobenzene ug/L 22.620 113 70-146ND Chloroethane ug/L 22.120 111 70-130ND Chloroform ug/L 21.820 109 70-130ND Chloromethane ug/L 20.620 103 70-130ND cis-1,2-Dichloroethene ug/L 22.020 110 70-130ND cis-1,3-Dichloropropene ug/L 20.220 101 70-130ND Dibromochloromethane ug/L 21.220 106 70-130ND Dibromomethane ug/L 21.320 106 70-130ND Ethylbenzene ug/L 22.920 114 70-130ND Iodomethane ug/L 47.740 119 70-130ND m&p-Xylene ug/L 44.740 112 70-130ND Methylene Chloride ug/L 22.820 109 70-130ND o-Xylene ug/L 22.320 112 70-130ND Styrene ug/L 22.720 113 70-130ND Tetrachloroethene ug/L 23.020 115 70-130ND Toluene ug/L 22.620 113 70-155ND trans-1,2-Dichloroethene ug/L 22.120 111 70-130ND trans-1,3-Dichloropropene ug/L 20.120 101 70-130ND trans-1,4-Dichloro-2-butene ug/L 17.120 85 70-130ND Trichloroethene ug/L 22.720 113 69-151ND Trichlorofluoromethane ug/L 23.420 117 70-130ND Vinyl acetate ug/L 39.040 98 70-130ND Vinyl chloride ug/L 24.020 120 70-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%97 70-130 Parameter Units Dup Result QualifiersRPDResult 92294555001 1716718SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 67 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92294555001 1716718SAMPLE DUPLICATE: 1,4-Dichlorobenzene ug/L NDND 2-Butanone (MEK)ug/L NDND 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND m&p-Xylene ug/L NDND Methylene Chloride ug/L NDND o-Xylene ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L .6JND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%99 198 4-Bromofluorobenzene (S)%98 3101 Toluene-d8 (S)%102 1101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 68 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/36529 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1717620 Associated Lab Samples:92294250022 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 04/22/16 14:05 1,1,1-Trichloroethane ug/L ND 1.0 04/22/16 14:05 1,1,2,2-Tetrachloroethane ug/L ND 1.0 04/22/16 14:05 1,1,2-Trichloroethane ug/L ND 1.0 04/22/16 14:05 1,1-Dichloroethane ug/L ND 1.0 04/22/16 14:05 1,1-Dichloroethene ug/L ND 1.0 04/22/16 14:05 1,1-Dichloropropene ug/L ND 1.0 04/22/16 14:05 1,2,3-Trichlorobenzene ug/L ND 1.0 04/22/16 14:05 1,2,3-Trichloropropane ug/L ND 1.0 04/22/16 14:05 1,2,4-Trichlorobenzene ug/L ND 1.0 04/22/16 14:05 1,2-Dibromo-3-chloropropane ug/L ND 2.0 04/22/16 14:05 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/22/16 14:05 1,2-Dichlorobenzene ug/L ND 1.0 04/22/16 14:05 1,2-Dichloroethane ug/L ND 1.0 04/22/16 14:05 1,2-Dichloropropane ug/L ND 1.0 04/22/16 14:05 1,3-Dichlorobenzene ug/L ND 1.0 04/22/16 14:05 1,3-Dichloropropane ug/L ND 1.0 04/22/16 14:05 1,4-Dichlorobenzene ug/L ND 1.0 04/22/16 14:05 2,2-Dichloropropane ug/L ND 1.0 04/22/16 14:05 2-Butanone (MEK)ug/L ND 5.0 04/22/16 14:05 2-Chlorotoluene ug/L ND 1.0 04/22/16 14:05 2-Hexanone ug/L ND 5.0 04/22/16 14:05 4-Chlorotoluene ug/L ND 1.0 04/22/16 14:05 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 04/22/16 14:05 Acetone ug/L ND 25.0 04/22/16 14:05 Benzene ug/L ND 1.0 04/22/16 14:05 Bromobenzene ug/L ND 1.0 04/22/16 14:05 Bromochloromethane ug/L ND 1.0 04/22/16 14:05 Bromodichloromethane ug/L ND 1.0 04/22/16 14:05 Bromoform ug/L ND 1.0 04/22/16 14:05 Bromomethane ug/L ND 2.0 04/22/16 14:05 Carbon tetrachloride ug/L ND 1.0 04/22/16 14:05 Chlorobenzene ug/L ND 1.0 04/22/16 14:05 Chloroethane ug/L ND 1.0 04/22/16 14:05 Chloroform ug/L ND 1.0 04/22/16 14:05 Chloromethane ug/L ND 1.0 04/22/16 14:05 cis-1,2-Dichloroethene ug/L ND 1.0 04/22/16 14:05 cis-1,3-Dichloropropene ug/L ND 1.0 04/22/16 14:05 Dibromochloromethane ug/L ND 1.0 04/22/16 14:05 Dibromomethane ug/L ND 1.0 04/22/16 14:05 Dichlorodifluoromethane ug/L ND 1.0 04/22/16 14:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 69 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1717620 Associated Lab Samples:92294250022 Matrix:Water Analyzed Diisopropyl ether ug/L ND 1.0 04/22/16 14:05 Ethylbenzene ug/L ND 1.0 04/22/16 14:05 Hexachloro-1,3-butadiene ug/L ND 1.0 04/22/16 14:05 m&p-Xylene ug/L ND 2.0 04/22/16 14:05 Methyl-tert-butyl ether ug/L ND 1.0 04/22/16 14:05 Methylene Chloride ug/L ND 2.0 04/22/16 14:05 Naphthalene ug/L ND 1.0 04/22/16 14:05 o-Xylene ug/L ND 1.0 04/22/16 14:05 p-Isopropyltoluene ug/L ND 1.0 04/22/16 14:05 Styrene ug/L ND 1.0 04/22/16 14:05 Tetrachloroethene ug/L ND 1.0 04/22/16 14:05 Toluene ug/L ND 1.0 04/22/16 14:05 trans-1,2-Dichloroethene ug/L ND 1.0 04/22/16 14:05 trans-1,3-Dichloropropene ug/L ND 1.0 04/22/16 14:05 Trichloroethene ug/L ND 1.0 04/22/16 14:05 Trichlorofluoromethane ug/L ND 1.0 04/22/16 14:05 Vinyl acetate ug/L ND 2.0 04/22/16 14:05 Vinyl chloride ug/L ND 1.0 04/22/16 14:05 Xylene (Total)ug/L ND 2.0 04/22/16 14:05 1,2-Dichloroethane-d4 (S)%104 70-130 04/22/16 14:05 4-Bromofluorobenzene (S)%102 70-130 04/22/16 14:05 Toluene-d8 (S)%99 70-130 04/22/16 14:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1717621LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.250 102 70-130 1,1,1-Trichloroethane ug/L 53.350 107 70-130 1,1,2,2-Tetrachloroethane ug/L 49.350 99 70-130 1,1,2-Trichloroethane ug/L 50.350 101 70-130 1,1-Dichloroethane ug/L 51.450 103 70-130 1,1-Dichloroethene ug/L 54.150 108 70-132 1,1-Dichloropropene ug/L 52.950 106 70-130 1,2,3-Trichlorobenzene ug/L 51.850 104 70-135 1,2,3-Trichloropropane ug/L 51.150 102 70-130 1,2,4-Trichlorobenzene ug/L 53.250 106 70-134 1,2-Dibromo-3-chloropropane ug/L 46.350 93 70-130 1,2-Dibromoethane (EDB)ug/L 54.450 109 70-130 1,2-Dichlorobenzene ug/L 50.350 101 70-130 1,2-Dichloroethane ug/L 50.350 101 70-130 1,2-Dichloropropane ug/L 50.350 101 70-130 1,3-Dichlorobenzene ug/L 51.750 103 70-130 1,3-Dichloropropane ug/L 52.450 105 70-130 1,4-Dichlorobenzene ug/L 51.450 103 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 70 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1717621LABORATORY CONTROL SAMPLE: LCSSpike 2,2-Dichloropropane ug/L 56.250 112 58-145 2-Butanone (MEK)ug/L 97.2100 97 70-145 2-Chlorotoluene ug/L 54.150 108 70-130 2-Hexanone ug/L 103100 103 70-144 4-Chlorotoluene ug/L 52.350 105 70-130 4-Methyl-2-pentanone (MIBK)ug/L 108100 108 70-140 Acetone ug/L 102100 102 50-175 Benzene ug/L 51.950 104 70-130 Bromobenzene ug/L 50.750 101 70-130 Bromochloromethane ug/L 55.250 110 70-130 Bromodichloromethane ug/L 52.150 104 70-130 Bromoform ug/L 51.050 102 70-130 Bromomethane ug/L 31.750 63 54-130 Carbon tetrachloride ug/L 55.350 111 70-132 Chlorobenzene ug/L 51.050 102 70-130 Chloroethane ug/L 59.850 120 64-134 Chloroform ug/L 51.250 102 70-130 Chloromethane ug/L 33.950 68 64-130 cis-1,2-Dichloroethene ug/L 51.850 104 70-131 cis-1,3-Dichloropropene ug/L 52.050 104 70-130 Dibromochloromethane ug/L 52.550 105 70-130 Dibromomethane ug/L 52.650 105 70-131 Dichlorodifluoromethane ug/L 50.050 100 56-130 Diisopropyl ether ug/L 52.350 105 70-130 Ethylbenzene ug/L 50.950 102 70-130 Hexachloro-1,3-butadiene ug/L 54.050 108 70-130 m&p-Xylene ug/L 102100 102 70-130 Methyl-tert-butyl ether ug/L 54.750 109 70-130 Methylene Chloride ug/L 49.350 99 63-130 Naphthalene ug/L 50.950 102 70-138 o-Xylene ug/L 50.050 100 70-130 p-Isopropyltoluene ug/L 51.550 103 70-130 Styrene ug/L 51.350 103 70-130 Tetrachloroethene ug/L 50.450 101 70-130 Toluene ug/L 53.050 106 70-130 trans-1,2-Dichloroethene ug/L 52.850 106 70-130 trans-1,3-Dichloropropene ug/L 50.850 102 70-132 Trichloroethene ug/L 51.450 103 70-130 Trichlorofluoromethane ug/L 56.550 113 62-133 Vinyl acetate ug/L 114100 114 66-157 Vinyl chloride ug/L 51.350 103 50-150 Xylene (Total)ug/L 152150 102 70-130 1,2-Dichloroethane-d4 (S)%102 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%100 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 71 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1717622MATRIX SPIKE SAMPLE: MSSpike Result 92294465002 1,1,1,2-Tetrachloroethane ug/L 21.920 110 70-130ND 1,1,1-Trichloroethane ug/L 24.320 122 70-130ND 1,1,2,2-Tetrachloroethane ug/L 19.720 98 70-130ND 1,1,2-Trichloroethane ug/L 21.520 108 70-130ND 1,1-Dichloroethane ug/L 22.520 113 70-130ND 1,1-Dichloroethene ug/L 24.520 122 70-166ND 1,1-Dichloropropene ug/L 23.920 120 70-130ND 1,2,3-Trichlorobenzene ug/L 20.720 103 70-130ND 1,2,3-Trichloropropane ug/L 21.320 106 70-130ND 1,2,4-Trichlorobenzene ug/L 20.620 103 70-130ND 1,2-Dibromo-3-chloropropane ug/L 19.320 96 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.220 111 70-130ND 1,2-Dichlorobenzene ug/L 20.620 103 70-130ND 1,2-Dichloroethane ug/L 21.720 108 70-130ND 1,2-Dichloropropane ug/L 21.020 105 70-130ND 1,3-Dichlorobenzene ug/L 21.720 109 70-130ND 1,3-Dichloropropane ug/L 21.320 107 70-130ND 1,4-Dichlorobenzene ug/L 21.220 106 70-130ND 2,2-Dichloropropane ug/L 23.020 115 70-130ND 2-Butanone (MEK)ug/L 42.740 107 70-130ND 2-Chlorotoluene ug/L 23.520 117 70-130ND 2-Hexanone ug/L 39.640 99 70-130ND 4-Chlorotoluene ug/L 22.420 112 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 43.640 109 70-130ND Acetone ug/L 44.440 111 70-130ND Benzene ug/L 22.520 112 70-148ND Bromobenzene ug/L 21.620 108 70-130ND Bromochloromethane ug/L 24.320 121 70-130ND Bromodichloromethane ug/L 21.720 109 70-130ND Bromoform ug/L 19.820 99 70-130ND Bromomethane ug/L 11.6 M1205870-130ND Carbon tetrachloride ug/L 24.620 123 70-130ND Chlorobenzene ug/L 22.220 111 70-146ND Chloroethane ug/L 29.7 M12014970-130ND Chloroform ug/L 22.920 114 70-130ND Chloromethane ug/L 15.420 77 70-130ND cis-1,2-Dichloroethene ug/L 22.120 111 70-130ND cis-1,3-Dichloropropene ug/L 21.020 105 70-130ND Dibromochloromethane ug/L 20.520 103 70-130ND Dibromomethane ug/L 21.720 109 70-130ND Dichlorodifluoromethane ug/L 22.120 110 70-130ND Diisopropyl ether ug/L 22.720 113 70-130ND Ethylbenzene ug/L 22.220 111 70-130ND Hexachloro-1,3-butadiene ug/L 21.620 108 70-130ND m&p-Xylene ug/L 44.040 110 70-130ND Methyl-tert-butyl ether ug/L 23.220 116 70-130ND Methylene Chloride ug/L 21.720 108 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 72 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1717622MATRIX SPIKE SAMPLE: MSSpike Result 92294465002 Naphthalene ug/L 19.020 95 70-130ND o-Xylene ug/L 21.520 107 70-130ND p-Isopropyltoluene ug/L 21.920 110 70-130ND Styrene ug/L 21.320 107 70-130ND Tetrachloroethene ug/L 22.320 111 70-130ND Toluene ug/L 22.820 114 70-155ND trans-1,2-Dichloroethene ug/L 23.520 118 70-130ND trans-1,3-Dichloropropene ug/L 19.920 100 70-130ND Trichloroethene ug/L 22.920 114 69-151ND Trichlorofluoromethane ug/L 27.2 M12013670-130ND Vinyl acetate ug/L 40.940 102 70-130ND Vinyl chloride ug/L 25.920 129 70-130ND 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%102 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result QualifiersRPDResult 92294038001 1717623SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L NDND 1,1-Dichloropropene ug/L NDND 1,2,3-Trichlorobenzene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2,4-Trichlorobenzene ug/L NDND 1,2-Dibromo-3-chloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND 1,3-Dichlorobenzene ug/L NDND 1,3-Dichloropropane ug/L NDND 1,4-Dichlorobenzene ug/L NDND 2,2-Dichloropropane ug/L NDND 2-Butanone (MEK)ug/L NDND 2-Chlorotoluene ug/L NDND 2-Hexanone ug/L NDND 4-Chlorotoluene ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Benzene ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 73 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92294038001 1717623SAMPLE DUPLICATE: Bromobenzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Dichlorodifluoromethane ug/L NDND Diisopropyl ether ug/L NDND Ethylbenzene ug/L NDND Hexachloro-1,3-butadiene ug/L NDND m&p-Xylene ug/L NDND Methyl-tert-butyl ether ug/L NDND Methylene Chloride ug/L NDND Naphthalene ug/L NDND o-Xylene ug/L NDND p-Isopropyltoluene ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%102 1101 4-Bromofluorobenzene (S)%98 2101 Toluene-d8 (S)%98 2100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 74 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/36542 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92294250007, 92294250008, 92294250009, 92294250010, 92294250011, 92294250012, 92294250013, 92294250014, 92294250015, 92294250017 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718181 Associated Lab Samples:92294250007, 92294250008, 92294250009, 92294250010, 92294250011, 92294250012, 92294250013, 92294250014, 92294250015, 92294250017 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 04/23/16 20:23 1,1,1-Trichloroethane ug/L ND 1.0 04/23/16 20:23 1,1,2,2-Tetrachloroethane ug/L ND 1.0 04/23/16 20:23 1,1,2-Trichloroethane ug/L ND 1.0 04/23/16 20:23 1,1-Dichloroethane ug/L ND 1.0 04/23/16 20:23 1,1-Dichloroethene ug/L ND 1.0 04/23/16 20:23 1,2,3-Trichloropropane ug/L ND 1.0 04/23/16 20:23 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/23/16 20:23 1,2-Dichlorobenzene ug/L ND 1.0 04/23/16 20:23 1,2-Dichloroethane ug/L ND 1.0 04/23/16 20:23 1,2-Dichloropropane ug/L ND 1.0 04/23/16 20:23 1,4-Dichlorobenzene ug/L ND 1.0 04/23/16 20:23 2-Butanone (MEK)ug/L ND 5.0 04/23/16 20:23 2-Hexanone ug/L ND 5.0 04/23/16 20:23 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 04/23/16 20:23 Acetone ug/L ND 25.0 04/23/16 20:23 Acrylonitrile ug/L ND 10.0 04/23/16 20:23 Benzene ug/L ND 1.0 04/23/16 20:23 Bromochloromethane ug/L ND 1.0 04/23/16 20:23 Bromodichloromethane ug/L ND 1.0 04/23/16 20:23 Bromoform ug/L ND 1.0 04/23/16 20:23 Bromomethane ug/L ND 2.0 04/23/16 20:23 Carbon disulfide ug/L ND 2.0 04/23/16 20:23 Carbon tetrachloride ug/L ND 1.0 04/23/16 20:23 Chlorobenzene ug/L ND 1.0 04/23/16 20:23 Chloroethane ug/L ND 1.0 04/23/16 20:23 Chloroform ug/L ND 1.0 04/23/16 20:23 Chloromethane ug/L ND 1.0 04/23/16 20:23 cis-1,2-Dichloroethene ug/L ND 1.0 04/23/16 20:23 cis-1,3-Dichloropropene ug/L ND 1.0 04/23/16 20:23 Dibromochloromethane ug/L ND 1.0 04/23/16 20:23 Dibromomethane ug/L ND 1.0 04/23/16 20:23 Ethylbenzene ug/L ND 1.0 04/23/16 20:23 Iodomethane ug/L ND 5.0 04/23/16 20:23 m&p-Xylene ug/L ND 2.0 04/23/16 20:23 Methylene Chloride ug/L ND 2.0 04/23/16 20:23 o-Xylene ug/L ND 1.0 04/23/16 20:23 Styrene ug/L ND 1.0 04/23/16 20:23 Tetrachloroethene ug/L ND 1.0 04/23/16 20:23 Toluene ug/L ND 1.0 04/23/16 20:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 75 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718181 Associated Lab Samples:92294250007, 92294250008, 92294250009, 92294250010, 92294250011, 92294250012, 92294250013, 92294250014, 92294250015, 92294250017 Matrix:Water Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 04/23/16 20:23 trans-1,3-Dichloropropene ug/L ND 1.0 04/23/16 20:23 trans-1,4-Dichloro-2-butene ug/L ND 1.0 04/23/16 20:23 Trichloroethene ug/L ND 1.0 04/23/16 20:23 Trichlorofluoromethane ug/L ND 1.0 04/23/16 20:23 Vinyl acetate ug/L ND 2.0 04/23/16 20:23 Vinyl chloride ug/L ND 1.0 04/23/16 20:23 Xylene (Total)ug/L ND 2.0 04/23/16 20:23 1,2-Dichloroethane-d4 (S)%102 70-130 04/23/16 20:23 4-Bromofluorobenzene (S)%99 70-130 04/23/16 20:23 Toluene-d8 (S)%100 70-130 04/23/16 20:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718182LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 45.450 91 70-130 1,1,1-Trichloroethane ug/L 45.750 91 70-130 1,1,2,2-Tetrachloroethane ug/L 45.250 90 70-130 1,1,2-Trichloroethane ug/L 45.150 90 70-130 1,1-Dichloroethane ug/L 45.550 91 70-130 1,1-Dichloroethene ug/L 48.450 97 70-132 1,2,3-Trichloropropane ug/L 46.250 92 70-130 1,2-Dibromoethane (EDB)ug/L 47.950 96 70-130 1,2-Dichlorobenzene ug/L 45.850 92 70-130 1,2-Dichloroethane ug/L 43.850 88 70-130 1,2-Dichloropropane ug/L 46.050 92 70-130 1,4-Dichlorobenzene ug/L 45.350 91 70-130 2-Butanone (MEK)ug/L 94.5100 94 70-145 2-Hexanone ug/L 97.7100 98 70-144 4-Methyl-2-pentanone (MIBK)ug/L 97.5100 97 70-140 Acetone ug/L 94.5100 95 50-175 Acrylonitrile ug/L 240250 96 70-143 Benzene ug/L 45.150 90 70-130 Bromochloromethane ug/L 50.750 101 70-130 Bromodichloromethane ug/L 46.450 93 70-130 Bromoform ug/L 45.450 91 70-130 Bromomethane ug/L 54.850 110 54-130 Carbon disulfide ug/L 49.250 98 70-131 Carbon tetrachloride ug/L 47.050 94 70-132 Chlorobenzene ug/L 45.750 91 70-130 Chloroethane ug/L 47.350 95 64-134 Chloroform ug/L 44.450 89 70-130 Chloromethane ug/L 43.050 86 64-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 76 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718182LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 46.050 92 70-131 cis-1,3-Dichloropropene ug/L 47.450 95 70-130 Dibromochloromethane ug/L 46.950 94 70-130 Dibromomethane ug/L 47.350 95 70-131 Ethylbenzene ug/L 45.950 92 70-130 Iodomethane ug/L 73.9100 74 49-180 m&p-Xylene ug/L 89.3100 89 70-130 Methylene Chloride ug/L 43.150 86 63-130 o-Xylene ug/L 44.350 89 70-130 Styrene ug/L 45.950 92 70-130 Tetrachloroethene ug/L 43.850 88 70-130 Toluene ug/L 46.650 93 70-130 trans-1,2-Dichloroethene ug/L 46.550 93 70-130 trans-1,3-Dichloropropene ug/L 45.250 90 70-132 trans-1,4-Dichloro-2-butene ug/L 42.250 84 70-141 Trichloroethene ug/L 45.250 90 70-130 Trichlorofluoromethane ug/L 44.850 90 62-133 Vinyl acetate ug/L 98.9100 99 66-157 Vinyl chloride ug/L 50.350 101 50-150 Xylene (Total)ug/L 134150 89 70-130 1,2-Dichloroethane-d4 (S)%101 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%102 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1718183MATRIX SPIKE SAMPLE: MSSpike Result 92294667002 1,1,1,2-Tetrachloroethane ug/L 21.020 105 70-130ND 1,1,1-Trichloroethane ug/L 21.920 109 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.420 102 70-130ND 1,1,2-Trichloroethane ug/L 21.920 110 70-130ND 1,1-Dichloroethane ug/L 21.520 107 70-130ND 1,1-Dichloroethene ug/L 23.720 119 70-166ND 1,2,3-Trichloropropane ug/L 22.420 112 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.020 110 70-130ND 1,2-Dichlorobenzene ug/L 21.420 107 70-130ND 1,2-Dichloroethane ug/L 19.920 100 70-130ND 1,2-Dichloropropane ug/L 21.820 109 70-130ND 1,4-Dichlorobenzene ug/L 20.620 103 70-130ND 2-Butanone (MEK)ug/L 46.840 117 70-130ND 2-Hexanone ug/L 45.340 113 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 46.440 116 70-130ND Acetone ug/L 48.140 117 70-130ND Acrylonitrile ug/L 117100 117 70-130ND Benzene ug/L 22.420 112 70-148ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 77 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1718183MATRIX SPIKE SAMPLE: MSSpike Result 92294667002 Bromochloromethane ug/L 22.120 111 70-130ND Bromodichloromethane ug/L 21.720 109 70-130ND Bromoform ug/L 19.620 98 70-130ND Bromomethane ug/L 13.1 M1206670-130ND Carbon disulfide ug/L 24.220 121 70-130ND Carbon tetrachloride ug/L 22.420 112 70-130ND Chlorobenzene ug/L 21.020 105 70-146ND Chloroethane ug/L 22.620 113 70-130ND Chloroform ug/L 21.320 106 70-130ND Chloromethane ug/L 21.120 106 70-130ND cis-1,2-Dichloroethene ug/L 21.820 109 70-130ND cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND Dibromochloromethane ug/L 21.220 106 70-130ND Dibromomethane ug/L 22.420 112 70-130ND Ethylbenzene ug/L 21.620 108 70-130ND Iodomethane ug/L 25.0 M1406270-130ND m&p-Xylene ug/L 41.440 104 70-130ND Methylene Chloride ug/L 20.720 103 70-130ND o-Xylene ug/L 20.720 103 70-130ND Styrene ug/L 21.420 107 70-130ND Tetrachloroethene ug/L 21.220 106 70-130ND Toluene ug/L 22.720 113 70-155ND trans-1,2-Dichloroethene ug/L 22.520 112 70-130ND trans-1,3-Dichloropropene ug/L 20.620 103 70-130ND trans-1,4-Dichloro-2-butene ug/L 16.520 83 70-130ND Trichloroethene ug/L 21.820 109 69-151ND Trichlorofluoromethane ug/L 23.420 117 70-130ND Vinyl acetate ug/L 39.340 98 70-130ND Vinyl chloride ug/L 24.720 124 70-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%103 70-130 Parameter Units Dup Result QualifiersRPDResult 92294948001 1718184SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 78 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92294948001 1718184SAMPLE DUPLICATE: 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND 1,4-Dichlorobenzene ug/L NDND 2-Butanone (MEK)ug/L NDND 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND m&p-Xylene ug/L NDND Methylene Chloride ug/L NDND o-Xylene ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%100 2102 4-Bromofluorobenzene (S)%100 199 Toluene-d8 (S)%99 1100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 79 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/36543 EPA 8260 EPA 8260 8260 MSV Low Level Associated Lab Samples:92294250018, 92294250019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718213 Associated Lab Samples:92294250018, 92294250019 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 04/24/16 17:52 1,1,1-Trichloroethane ug/L ND 1.0 04/24/16 17:52 1,1,2,2-Tetrachloroethane ug/L ND 1.0 04/24/16 17:52 1,1,2-Trichloroethane ug/L ND 1.0 04/24/16 17:52 1,1-Dichloroethane ug/L ND 1.0 04/24/16 17:52 1,1-Dichloroethene ug/L ND 1.0 04/24/16 17:52 1,2,3-Trichloropropane ug/L ND 1.0 04/24/16 17:52 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/24/16 17:52 1,2-Dichlorobenzene ug/L ND 1.0 04/24/16 17:52 1,2-Dichloroethane ug/L ND 1.0 04/24/16 17:52 1,2-Dichloropropane ug/L ND 1.0 04/24/16 17:52 1,4-Dichlorobenzene ug/L ND 1.0 04/24/16 17:52 2-Butanone (MEK)ug/L ND 5.0 04/24/16 17:52 2-Hexanone ug/L ND 5.0 04/24/16 17:52 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 04/24/16 17:52 Acetone ug/L ND 25.0 04/24/16 17:52 Acrylonitrile ug/L ND 10.0 04/24/16 17:52 Benzene ug/L ND 1.0 04/24/16 17:52 Bromochloromethane ug/L ND 1.0 04/24/16 17:52 Bromodichloromethane ug/L ND 1.0 04/24/16 17:52 Bromoform ug/L ND 1.0 04/24/16 17:52 Bromomethane ug/L ND 2.0 04/24/16 17:52 Carbon disulfide ug/L ND 2.0 04/24/16 17:52 Carbon tetrachloride ug/L ND 1.0 04/24/16 17:52 Chlorobenzene ug/L ND 1.0 04/24/16 17:52 Chloroethane ug/L ND 1.0 04/24/16 17:52 Chloroform ug/L ND 1.0 04/24/16 17:52 Chloromethane ug/L ND 1.0 04/24/16 17:52 cis-1,2-Dichloroethene ug/L ND 1.0 04/24/16 17:52 cis-1,3-Dichloropropene ug/L ND 1.0 04/24/16 17:52 Dibromochloromethane ug/L ND 1.0 04/24/16 17:52 Dibromomethane ug/L ND 1.0 04/24/16 17:52 Ethylbenzene ug/L ND 1.0 04/24/16 17:52 Iodomethane ug/L ND 5.0 04/24/16 17:52 m&p-Xylene ug/L ND 2.0 04/24/16 17:52 Methylene Chloride ug/L ND 2.0 04/24/16 17:52 o-Xylene ug/L ND 1.0 04/24/16 17:52 Styrene ug/L ND 1.0 04/24/16 17:52 Tetrachloroethene ug/L ND 1.0 04/24/16 17:52 Toluene ug/L ND 1.0 04/24/16 17:52 trans-1,2-Dichloroethene ug/L ND 1.0 04/24/16 17:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 80 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718213 Associated Lab Samples:92294250018, 92294250019 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 04/24/16 17:52 trans-1,4-Dichloro-2-butene ug/L ND 1.0 04/24/16 17:52 Trichloroethene ug/L ND 1.0 04/24/16 17:52 Trichlorofluoromethane ug/L ND 1.0 04/24/16 17:52 Vinyl acetate ug/L ND 2.0 04/24/16 17:52 Vinyl chloride ug/L ND 1.0 04/24/16 17:52 Xylene (Total)ug/L ND 2.0 04/24/16 17:52 1,2-Dichloroethane-d4 (S)%102 70-130 04/24/16 17:52 4-Bromofluorobenzene (S)%101 70-130 04/24/16 17:52 Toluene-d8 (S)%100 70-130 04/24/16 17:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718214LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 47.950 96 70-130 1,1,1-Trichloroethane ug/L 48.050 96 70-130 1,1,2,2-Tetrachloroethane ug/L 47.350 95 70-130 1,1,2-Trichloroethane ug/L 47.550 95 70-130 1,1-Dichloroethane ug/L 46.950 94 70-130 1,1-Dichloroethene ug/L 50.350 101 70-132 1,2,3-Trichloropropane ug/L 49.350 99 70-130 1,2-Dibromoethane (EDB)ug/L 50.150 100 70-130 1,2-Dichlorobenzene ug/L 48.350 97 70-130 1,2-Dichloroethane ug/L 44.450 89 70-130 1,2-Dichloropropane ug/L 47.150 94 70-130 1,4-Dichlorobenzene ug/L 47.250 94 70-130 2-Butanone (MEK)ug/L 97.0100 97 70-145 2-Hexanone ug/L 103100 103 70-144 4-Methyl-2-pentanone (MIBK)ug/L 101100 101 70-140 Acetone ug/L 99.8100 100 50-175 Acrylonitrile ug/L 234250 94 70-143 Benzene ug/L 47.550 95 70-130 Bromochloromethane ug/L 51.050 102 70-130 Bromodichloromethane ug/L 49.450 99 70-130 Bromoform ug/L 48.450 97 70-130 Bromomethane ug/L 42.450 85 54-130 Carbon disulfide ug/L 52.450 105 70-131 Carbon tetrachloride ug/L 50.350 101 70-132 Chlorobenzene ug/L 47.450 95 70-130 Chloroethane ug/L 47.750 95 64-134 Chloroform ug/L 46.450 93 70-130 Chloromethane ug/L 39.550 79 64-130 cis-1,2-Dichloroethene ug/L 46.650 93 70-131 cis-1,3-Dichloropropene ug/L 51.150 102 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 81 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718214LABORATORY CONTROL SAMPLE: LCSSpike Dibromochloromethane ug/L 50.750 101 70-130 Dibromomethane ug/L 48.050 96 70-131 Ethylbenzene ug/L 47.950 96 70-130 Iodomethane ug/L 75.0100 75 49-180 m&p-Xylene ug/L 95.9100 96 70-130 Methylene Chloride ug/L 45.050 90 63-130 o-Xylene ug/L 46.350 93 70-130 Styrene ug/L 48.650 97 70-130 Tetrachloroethene ug/L 47.250 94 70-130 Toluene ug/L 48.850 98 70-130 trans-1,2-Dichloroethene ug/L 48.050 96 70-130 trans-1,3-Dichloropropene ug/L 48.650 97 70-132 trans-1,4-Dichloro-2-butene ug/L 47.950 96 70-141 Trichloroethene ug/L 46.350 93 70-130 Trichlorofluoromethane ug/L 46.650 93 62-133 Vinyl acetate ug/L 101100 101 66-157 Vinyl chloride ug/L 52.750 105 50-150 Xylene (Total)ug/L 142150 95 70-130 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%102 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1718215MATRIX SPIKE SAMPLE: MSSpike Result 92294250018 1,1,1,2-Tetrachloroethane ug/L 20.620 103 70-130ND 1,1,1-Trichloroethane ug/L 21.820 109 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.120 101 70-130ND 1,1,2-Trichloroethane ug/L 21.620 108 70-130ND 1,1-Dichloroethane ug/L 21.320 106 70-130ND 1,1-Dichloroethene ug/L 23.320 116 70-166ND 1,2,3-Trichloropropane ug/L 20.920 104 70-130ND 1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND 1,2-Dichlorobenzene ug/L 20.420 102 70-130ND 1,2-Dichloroethane ug/L 20.220 101 70-130ND 1,2-Dichloropropane ug/L 21.420 107 70-130ND 1,4-Dichlorobenzene ug/L 20.420 102 70-130ND 2-Butanone (MEK)ug/L 45.540 114 70-130ND 2-Hexanone ug/L 43.340 108 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 46.040 115 70-130ND Acetone ug/L 52.140 115 70-130ND Acrylonitrile ug/L 117100 117 70-130ND Benzene ug/L 21.920 109 70-148ND Bromochloromethane ug/L 21.520 108 70-130ND Bromodichloromethane ug/L 21.020 105 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 82 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1718215MATRIX SPIKE SAMPLE: MSSpike Result 92294250018 Bromoform ug/L 18.620 93 70-130ND Bromomethane ug/L 16.420 82 70-130ND Carbon disulfide ug/L 23.320 117 70-130ND Carbon tetrachloride ug/L 21.920 110 70-130ND Chlorobenzene ug/L 20.920 104 70-146ND Chloroethane ug/L 23.720 119 70-130ND Chloroform ug/L 21.720 109 70-130ND Chloromethane ug/L 20.920 104 70-130ND cis-1,2-Dichloroethene ug/L 21.920 109 70-130ND cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND Dibromochloromethane ug/L 20.420 102 70-130ND Dibromomethane ug/L 21.720 109 70-130ND Ethylbenzene ug/L 21.320 106 70-130ND Iodomethane ug/L 26.3 M1406670-130ND m&p-Xylene ug/L 41.440 104 70-130ND Methylene Chloride ug/L 20.520 102 70-130ND o-Xylene ug/L 20.020 100 70-130ND Styrene ug/L 20.920 105 70-130ND Tetrachloroethene ug/L 20.820 104 70-130ND Toluene ug/L 22.520 113 70-155ND trans-1,2-Dichloroethene ug/L 22.920 115 70-130ND trans-1,3-Dichloropropene ug/L 19.920 100 70-130ND trans-1,4-Dichloro-2-butene ug/L 18.920 95 70-130ND Trichloroethene ug/L 21.620 108 69-151ND Trichlorofluoromethane ug/L 23.920 120 70-130ND Vinyl acetate ug/L 38.540 96 70-130ND Vinyl chloride ug/L 24.220 121 70-130ND 1,2-Dichloroethane-d4 (S)%101 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%102 70-130 Parameter Units Dup Result QualifiersRPDResult 92294250019 1718216SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 83 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92294250019 1718216SAMPLE DUPLICATE: 1,4-Dichlorobenzene ug/L NDND 2-Butanone (MEK)ug/L NDND 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND m&p-Xylene ug/L NDND Methylene Chloride ug/L NDND o-Xylene ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%104 2102 4-Bromofluorobenzene (S)%99 198 Toluene-d8 (S)%99 198 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 84 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/44411 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716299 Associated Lab Samples:92294250022 Matrix:Water Analyzed BOD, 5 day mg/L ND 2.0 04/26/16 09:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716300LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day mg/L 206198 104 84.6-115.4 Parameter Units Dup Result QualifiersRPDResult 92294250022 1716301SAMPLE DUPLICATE: BOD, 5 day mg/L 52.7 D62165.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 85 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27350 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718251 Associated Lab Samples:92294250022 Matrix:Water Analyzed Sulfate mg/L ND 2.0 04/25/16 20:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718252LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 18.920 94 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1718253MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294139001 1718254 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L 20 105 90-110104 1208.7 29.8 29.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 86 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27275 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1714849 Associated Lab Samples:92294250022 Matrix:Water Analyzed Nitrogen, Nitrate mg/L ND 0.020 04/20/16 07:29 Nitrogen, Nitrite mg/L ND 0.020 04/20/16 07:29 Nitrogen, NO2 plus NO3 mg/L ND 0.020 04/20/16 07:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1714850LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 100 90-110 Nitrogen, Nitrite mg/L 0.981 98 90-110 Nitrogen, NO2 plus NO3 mg/L 2.52.5 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1714851MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294202002 1714852 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Nitrate mg/L 2.5 99 90-110100 02.51.8 4.3 4.3 Nitrogen, Nitrite mg/L 1 108 90-110110 21ND1.1 1.1 Nitrogen, NO2 plus NO3 mg/L 2.5 99 90-110100 02.51.8 4.3 4.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 87 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27310 EPA 365.1 EPA 365.1 365.1 Phosphorus, Total Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1716503 Associated Lab Samples:92294250022 Matrix:Water Analyzed Phosphorus mg/L ND 0.050 04/22/16 02:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1716504LABORATORY CONTROL SAMPLE: LCSSpike Phosphorus mg/L 2.52.5 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1716505MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294439001 1716506 MSD Result MSD % Rec RPD MSDMS Spike Conc. Phosphorus mg/L M12.5 93 90-110113 102.52.6 4.9 5.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1716507MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294397001 1716508 MSD Result MSD % Rec RPD MSDMS Spike Conc. Phosphorus mg/L 2.5 98 90-11098 02.5ND 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 88 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27294 SM 4500-CN-E SM 4500-CN-E 4500CNE Cyanide, Total Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1715991 Associated Lab Samples:92294250022 Matrix:Water Analyzed Cyanide mg/L ND 0.0080 04/26/16 07:49 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1715992LABORATORY CONTROL SAMPLE: LCSSpike Cyanide mg/L 0.099.1 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1715993MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294264002 1715994 MSD Result MSD % Rec RPD MSDMS Spike Conc. Cyanide mg/L .1 92 75-12595 2.10.0040J 0.096 0.099 Parameter Units MS Result % Rec Limits Qual% RecConc. 1715995MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294378001 1715996 MSD Result MSD % Rec RPD MSDMS Spike Conc. Cyanide mg/L .1 94 75-12589 4.1ND 0.099 0.095 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 89 of 97 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27352 SM 5220D SM 5220D 5220D COD Associated Lab Samples:92294250022 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1718511 Associated Lab Samples:92294250022 Matrix:Water Analyzed Chemical Oxygen Demand mg/L ND 25.0 04/25/16 16:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1718512LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand mg/L 771750 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1718513MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293505007 1718514 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chemical Oxygen Demand mg/L 750 100 90-110100 075048.0 798 798 Parameter Units MS Result % Rec Limits Qual% RecConc. 1718515MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294893004 1718516 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chemical Oxygen Demand mg/L M17508690-11086 075057512201220 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 90 of 97 #=QL# QUALIFIERS Pace Project No.: Project: 92294250 Haywood Wolf 4/18 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Common Laboratory Contaminant.C9 The precision between the sample and sample duplicate exceeded laboratory control limits.D6 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 91 of 97 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92294250001 FLD/SW-1 92294250002 FLD/SW-2 92294250003 FLD/SW-3 92294250004 FLD/SW-5 92294250005 FLD/SW-6 92294250006 FLD/SW-7 92294250007 FLD/MW-1A 92294250008 FLD/MW-2 92294250009 FLD/MW-2D 92294250010 FLD/MW-3R 92294250011 FLD/MW-3DR 92294250012 FLD/MW-4A 92294250013 FLD/MW-8 92294250014 FLD/MW-11s 92294250015 FLD/MW-11D 92294250016 FLD/MW-14 92294250017 FLD/MW-15 92294250018 FLD/MW-16 92294250019 FLD/MW-17 92294250022 FLD/Lechate 92294250001 MPRP/21439 ICP/19256SW-1 EPA 3010A EPA 6010 92294250002 MPRP/21439 ICP/19256SW-2 EPA 3010A EPA 6010 92294250003 MPRP/21439 ICP/19256SW-3 EPA 3010A EPA 6010 92294250004 MPRP/21439 ICP/19256SW-5 EPA 3010A EPA 6010 92294250005 MPRP/21439 ICP/19256SW-6 EPA 3010A EPA 6010 92294250006 MPRP/21439 ICP/19256SW-7 EPA 3010A EPA 6010 92294250007 MPRP/21462 ICP/19277MW-1A EPA 3010A EPA 6010 92294250008 MPRP/21462 ICP/19277MW-2 EPA 3010A EPA 6010 92294250009 MPRP/21462 ICP/19277MW-2D EPA 3010A EPA 6010 92294250010 MPRP/21462 ICP/19277MW-3R EPA 3010A EPA 6010 92294250011 MPRP/21462 ICP/19277MW-3DR EPA 3010A EPA 6010 92294250012 MPRP/21462 ICP/19277MW-4A EPA 3010A EPA 6010 92294250013 MPRP/21462 ICP/19277MW-8 EPA 3010A EPA 6010 92294250014 MPRP/21462 ICP/19277MW-11s EPA 3010A EPA 6010 92294250015 MPRP/21462 ICP/19277MW-11D EPA 3010A EPA 6010 92294250016 MPRP/21462 ICP/19277MW-14 EPA 3010A EPA 6010 92294250017 MPRP/21463 ICP/19278MW-15 EPA 3010A EPA 6010 92294250018 MPRP/21463 ICP/19278MW-16 EPA 3010A EPA 6010 92294250019 MPRP/21463 ICP/19278MW-17 EPA 3010A EPA 6010 92294250021 MPRP/21463 ICP/19278EQUIP BLK EPA 3010A EPA 6010 92294250022 MPRP/21465 ICP/19280LechateEPA 3010A EPA 6010 92294250001 MSV/36500SW-1 EPA 8260 92294250002 MSV/36500SW-2 EPA 8260 92294250003 MSV/36500SW-3 EPA 8260 92294250004 MSV/36500SW-5 EPA 8260 92294250005 MSV/36500SW-6 EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 92 of 97 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92294250 Haywood Wolf 4/18 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92294250006 MSV/36500SW-7 EPA 8260 92294250007 MSV/36542MW-1A EPA 8260 92294250008 MSV/36542MW-2 EPA 8260 92294250009 MSV/36542MW-2D EPA 8260 92294250010 MSV/36542MW-3R EPA 8260 92294250011 MSV/36542MW-3DR EPA 8260 92294250012 MSV/36542MW-4A EPA 8260 92294250013 MSV/36542MW-8 EPA 8260 92294250014 MSV/36542MW-11s EPA 8260 92294250015 MSV/36542MW-11D EPA 8260 92294250016 MSV/36518MW-14 EPA 8260 92294250017 MSV/36542MW-15 EPA 8260 92294250018 MSV/36543MW-16 EPA 8260 92294250019 MSV/36543MW-17 EPA 8260 92294250020 MSV/36500TVL BLK EPA 8260 92294250021 MSV/36500EQUIP BLK EPA 8260 92294250022 MSV/36529LechateEPA 8260 92294250022 WET/44411 WET/44412LechateSM 5210B SM 5210B 92294250022 WETA/27350LechateEPA 300.0 92294250022 WETA/27275LechateEPA 353.2 92294250022 WETA/27310LechateEPA 365.1 92294250022 WETA/27294LechateSM 4500-CN-E 92294250022 WETA/27352LechateSM 5220D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/24/2016 11:28 AM Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 93 of 97 Page 94 of 97 Page 95 of 97 Page 96 of 97 Page 97 of 97 APPENDIX D STATISTICAL CALCULATIONS White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 COMPOUND TOTAL ND DETECTED %ND STATISTICAL TEST Total Antimony 354 347 7 98.0%Poisson Prediction Limits Total Arsenic 354 327 27 92.4%Poisson Prediction Limits Total Barium 357 16 341 4.5%Prediction Limits Total Beryllium 355 311 44 87.6%Kruskal-Wallis Total Cadmium 355 311 44 87.6%Kruskal-Wallis Total Chromium 355 210 145 59.2%Kruskal-Wallis Total Cobalt 355 232 123 65.4%Kruskal-Wallis Total Copper 355 228 127 64.2%Kruskal-Wallis Total Lead 356 278 78 78.1%Kruskal-Wallis Total Nickel 356 165 191 46.3%Kruskal-Wallis Total Selenium 355 351 4 98.9%Poisson Prediction Limits Total Silver 355 352 3 99.2%Poisson Prediction Limits Total Thallium 355 335 20 94.4%Poisson Prediction Limits Total Vanadium 355 214 141 60.3%Kruskal-Wallis Total Zinc 355 137 218 38.6%Kruskal-Wallis Acetone 304 303 1 99.7%Poisson Prediction Limits Carbon Disulfide 304 301 3 99.0%Poisson Prediction Limits Chloroethane 304 303 1 99.7%Poisson Prediction Limits Iodomethane 304 303 1 99.7%Poisson Prediction Limits Dichloromethane 304 301 3 99.0%Poisson Prediction Limits 2-Butanone 239 238 1 99.6%Poisson Prediction Limits Sampling Event # Detected LEGEND FOR THE FOLLOWING PAGES: N 1 64 ND = Not Detected at the method detection limit N 2 13 MCL = Maximum Contaminant Level ; NCAC 2L Standard N 3 14 NE = Not Established ; NC has not established a MCL N 4 3 NP = Not Present during sampling event N 5 64 NS = Not Sampled N 6 0 NT = Not Tested N 7 0 NA = information Not Available N 8 0 MDL = Method Detection Limit N 9 0 N 10 53 N 11 88 N 12 59 N 13 55 N 14 74 N 15 49 N 16 61 N 17 60 N 18 28 Methods 1957-55 White Oak GW Stats 1st 2016.xlsm Page 1 of 2 N 19 38 N 20 43 N 21 57 N 22 52 N 23 58 N 24 55 N 25 37 N 26 27 N 27 46 N 28 41 N 29 54 N 30 43 N 31 45 N 32 40 N 33 35 N 34 34 N 35 19 N 36 41 N 37 40 N 38 33 Total Detected Concentrations (per compound) = 1523 Total Detected Concentrations (per event) = 1523 Are all accounted for ?Yes Statistical Package Prepared By: IAI Statistical Package Checked By: DPO/MSP Methods 1957-55 White Oak GW Stats 1st 2016.xlsm Page 2 of 2 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Antimony MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 10 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 30 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 30 04/15/02 15 ND NS ND ND ND NT ND ND 11 NS NP NP 10 09/26/02 ND ND ND 12 ND ND ND ND ND ND 98 NP NP 10 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND 12 NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 30 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND 20 ND ND ND ND ND NP NP 6 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 6.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 32. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 89 Tn1 = 309 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =89 Tn1 = 309 t [88,.01] =2.3751 c =0.0112 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =8.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Antimony (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 1 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Arsenic MCL (mg/l):10 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 10 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 ND ND NS ND ND ND NT ND ND ND NS NP NP 10 09/26/02 ND 5.7 ND ND ND ND ND ND 27 ND 68 NP NP 5 04/28/03 ND ND ND ND ND ND ND ND ND ND 24 NP NP 5 10/30/03 ND ND NT ND ND ND ND ND ND 5.3 81 NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND 7.4 30 NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND 59 NP NP 5 04/18/05 ND ND ND 10 ND ND ND ND ND 5.2 65 NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND 44 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 42 NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND 13 NP NP 5 04/25/07 ND ND ND ND ND 280 ND ND ND ND 12 NP NP 5 10/31/07 ND ND ND ND ND ND ND ND ND ND 21.4 NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND 10.2 NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND 6.6 NP NP 5 04/22/09 ND ND 5.4 ND ND 5.6 ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND 6 ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND 7.4 9.8 NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND 5.4 5.9 ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 32. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 89 Tn1 = 303.6 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =89 Tn1 = 303.6 t [88,.01] =2.3751 c =0.0112 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 5 5 5 5 5 5 5 5 5 5 T*k =7.9 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Arsenic (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 2 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Barium NC MCL (mg/l):700 Method:Prediction Limits BACKGROUND WELLS DETECTION WELLS MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 4/24/00 250 NS NS 240 420 200 63 300 93 230 NS NP NP 5 6/26/00 300 67 NS NS NS NS NS NS NS NS NS NP NP 5 7/26/00 330 30 NS NS NS NS NS NS NS NS NS NP NP 5 9/18/00 NS NS NS 330 92 NS NS NS NT NS NS NP NP 500 4/9/01 1300 380 NS 180 330 120 80 290 360 970 NS NP NP 5 9/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 1/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 2/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 500 4/15/02 1300 41 NS ND ND 160 23 190 460 1400 NS NP NP 5 9/26/02 330 500 750 4200 120 230 93 410 910 1400 11000 NP NP 5 4/28/03 600 66 220 1800 160 140 110 92 360 800 2800 NP NP 5 10/30/03 320 100 NT 210 310 130 95 110 1200 270 4900 NP NP 5 4/20/04 320 56 120 410 460 170 140 210 62 940 2000 NP NP 5 10/21/04 320 40 200 300 310 140 140 130 12 900 4900 NP NP 5 4/18/05 480 55 160 7200 610 180 160 140 12 1000 3700 NP NP 5 10/13/05 770 37 160 1700 870 250 160 140 27 810 2700 NP NP 5 4/25/06 650 ND ND ND 1100 ND ND ND ND 750 2700 NP NP 500 10/20/06 410 22 180 470 1100 ND ND ND 160 ND 650 NP NP 5 4/25/07 290 ND 200 240 1300 1500 130 180 ND ND 600 NP NP 100 10/31/07 501 31.5 223 198 1350 591 184 208 62.4 516 872 NP NP 5 4/23/08 194 30.8 253 168 1230 661 216 202 61.8 151 361 NP NP 5 10/20/08 474 66 313 224 1210 894 164 216 41.1 182 245 NP NP 5 4/22/09 126 47.2 591 309 1300 817 230 216 77 163 NS NP NP 5 10/26/09 131 16.8 144 188 1720 987 NS NS NS 209 178 NP NP 5 4/22/10 208 43.5 153 157 1920 1380 NS NS 20.9 150 74.8 NP NP 5 10/27/10 147 15.8 162 178 1760 1550 531 234 20 190 111 191 84.4 5 4/29/11 191 16.3 188 182 1620 1390 428 173 13.6 196 125 201 133 5 10/25/11 185 19.7 120 332 1200 1300 945 205 8.2 238 123 161 154 5 4/20/12 304 17.5 129 153 1020 1140 442 215 9.5 232 64.8 249 169 5 10/24/12 389 19 124 167 889 1030 393 229 26.1 235 43.2 177 181 5 4/24/13 241 16.8 100 164 842 964 344 226 9.3 218 96.5 116 190 5 10/24/13 255 18.1 156 166 839 1160 510 256 9.1 250 55.2 171 218 5 4/24/14 174 17.7 127 148 941 1290 378 248 8.3 238 27.5 148 189 5 10/27/14 117 16.1 102 136 1280 1410 363 224 8.6 228 23.2 156 180 5 4/28/15 119 16 109 199 1330 1380 345 260 9 218 30.2 156 190 5 10/27/15 346 16 95.7 164 1190 1400 352 247 13.8 279 18.8 188 191 5 4/19/16 222 16.1 55.2 211 889 1240 325 200 17.7 216 22.8 152 191 5 1) Use the data above as-is for testing: 2) Calculate the Upper Prediction limit (T): T = xbar + t[n-1, 1-a*/k]s [1+1/n)]-0.5 where: n =89 Number of background concentrations n0 =3 Number of ND background concentrations n1 =86 Number of detected background concentrations n0/n =0.0337 Ratio of ND to all background values xbar =213.15 Average background concentration x'bar =220.59 Average detected background concentration a* =0.05 Sitewide error rate k =10 Number of Comparisons during the Current Sampling Event s' =242.07 Standard deviation of detected background concentrations s =237.88 Standard deviation of background concentrations a*/k =0.005 t [88, 0.005] =2.6399 Upper percentage point of Student's t-distribution (Table 6 of the IFG) Tn = 1240 Maximum concentration detected during current sampling event 1957-55 White Oak GW Stats 1st 2016.xlsm Barium (PL)Page 3 of 72 T =844.6 Upper Prediction Limit MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Current Concentration = 211 889 1240 325 200 17.7 216 22.8 152 191 Statistical Significance ?No Yes Yes No No No No No No No If SSI, is current event above MCL?-Yes Yes ------- 2) Compare the Upper Prediction Limit (T) to the Maximum Concentration Detected (Tn) in the wells during the most recent sampling event. Since the Prediction Limit was exceeded, there is evidence that the detected concentrations during the current sampling event that the detected concentrations are statistically significant. 1957-55 White Oak GW Stats 1st 2016.xlsm Barium (PL)Page 4 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Barium NC MCL (mg/l):700 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 2 MD L 9/26/02 120 5 4/28/03 160 5 10/30/03 310 5 4/20/04 460 5 10/21/04 310 5 4/18/05 610 5 10/13/05 870 5 4/25/06 1100 500 10/20/06 1100 5 4/25/07 1300 100 10/31/07 1350 5 4/23/08 1230 5 10/20/08 1210 5 4/22/09 1300 5 10/26/09 1720 5 4/22/10 1920 5 10/27/10 1760 5 4/29/11 1620 5 10/25/11 1200 5 4/20/12 1020 5 10/24/12 889 5 4/24/13 842 5 10/24/13 839 5 4/24/14 941 5 10/27/14 1280 5 4/28/15 1330 5 10/27/15 1190 5 4/19/16 889 5 If not detected (ND), use half of the detection limit. Xbar =1031.0714 SD =469.62853 N =28 1/NSi(Xi-Xbar)3 =-24816166 g1=0.2530246 Since the Coefficient of Skewness of 0.25 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =6.7725641 SD =0.6897979 N =28 1/NSi(Xi-Xbar)3 =-0.4773163 g1=1.5357907 Use the real values (not log-transformed) indicated in the previous section. Ba (S-C MW-2) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 5 of 72 Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 492.5 = xmean (Mean of N1-N8 historical data) 346.89438 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 1100 1.7512535 0.7512535 5 4.5 4/25/07 1300 2.3277978 2.0790513 5 4.5 10/31/07 1350 2.4719339 3.5509853 5 4.5 4/23/08 1230 2.1260073 4.6769926 5 4.5 10/20/08 1210 2.0683529 5.7453454 5 4.5 4/22/09 1300 2.3277978 7.0731433 5 4.5 10/26/09 1720 3.538541 9.6116843 5 4.5 4/22/10 1920 4.1150853 12.72677 5 4.5 10/27/10 1760 3.6538499 15.380619 5 4.5 4/29/11 1620 3.2502688 17.630888 5 4.5 10/25/11 1200 2.0395257 18.670414 5 4.5 4/20/12 1020 1.5206357 19.19105 5 4.5 10/24/12 889 1.1429992 19.334049 5 4.5 4/24/13 842 1.0075113 19.34156 5 4.5 10/24/13 839 0.9988631 19.340423 5 4.5 4/24/14 941 1.2929007 19.633324 5 4.5 10/27/14 1280 2.2701434 20.903467 5 4.5 4/28/15 1330 2.4142795 22.317747 5 4.5 10/27/15 1190 2.0106984 23.328445 5 4.5 4/19/16 889 1.1429992 23.471444 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. 0 5 10 15 20 25 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ba (S-C MW-2) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 6 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Barium NC MCL (mg/l):700 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 2 D MD L 9/26/02 230 5 4/28/03 140 5 10/30/03 130 5 4/20/04 170 5 10/21/04 140 5 4/18/05 180 5 10/13/05 250 5 4/25/06 ND 500 10/20/06 ND 5 4/25/07 1500 100 10/31/07 591 5 4/23/08 661 5 10/20/08 894 5 4/22/09 817 5 10/26/09 987 5 4/22/10 1380 5 10/27/10 1550 5 4/29/11 1390 5 10/25/11 1300 5 4/20/12 1140 5 10/24/12 1030 5 4/24/13 964 5 10/24/13 1160 5 4/24/14 1290 5 10/27/14 1410 5 4/28/15 1380 5 10/27/15 1400 5 4/19/16 1240 5 If not detected (ND), use half of the detection limit. Xbar =842.01786 SD =528.42058 N =28 1/NSi(Xi-Xbar)3 =-39725499 g1=0.2843293 Since the Coefficient of Skewness of 0.28 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =6.2842407 SD =1.369189 N =28 1/NSi(Xi-Xbar)3 =-5.5806396 g1=2.2960705 Use the real values (not log-transformed) indicated in the previous section. Ba (S-C MW-2D) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 7 of 72 Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 186.25 = xmean (Mean of N1-N8 historical data) 50.409041 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 2.5 -3.6451794 0 5 4.5 4/25/07 1500 26.061793 25.061793 5 4.5 10/31/07 591 8.0293136 32.091107 5 4.5 4/23/08 661 9.4179534 40.50906 5 4.5 10/20/08 894 14.04014 53.5492 5 4.5 4/22/09 817 12.512636 65.061837 5 4.5 10/26/09 987 15.885047 79.946884 5 4.5 4/22/10 1380 23.681268 102.62815 5 4.5 10/27/10 1550 27.053679 128.68183 5 4.5 4/29/11 1390 23.879645 151.56148 5 4.5 10/25/11 1300 22.094251 172.65573 5 4.5 4/20/12 1140 18.920217 190.57594 5 4.5 10/24/12 1030 16.738069 206.31401 5 4.5 4/24/13 964 15.42878 220.74279 5 4.5 10/24/13 1160 19.316971 239.05976 5 4.5 4/24/14 1290 21.895874 259.95564 5 4.5 10/27/14 1410 24.276399 283.23204 5 4.5 4/28/15 1380 23.681268 305.9133 5 4.5 10/27/15 1400 24.078022 328.99133 5 4.5 4/19/16 1240 20.903988 348.89531 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. -50 0 50 100 150 200 250 300 350 400 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ba (S-C MW-2D) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 8 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Beryllium NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 4.4 NS NS ND 2 ND 2.2 ND ND ND NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 2 04/09/01 2.3 7 NS ND ND ND ND ND 2.4 4.8 NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 04/15/02 2.1 ND NS ND ND ND ND ND 2.5 5 NS NP NP 2 09/26/02 ND 7 2.1 5.1 ND ND ND ND 8.5 4.7 95 NP NP 2 04/28/03 ND ND ND ND ND ND ND ND 2 2.2 20 NP NP 2 10/30/03 ND ND NT ND ND ND ND ND 2.4 ND 33 NP NP 1 04/20/04 ND ND ND ND ND ND ND ND ND ND 21 NP NP 1 10/21/04 ND ND ND ND ND ND ND ND ND 1.4 28 NP NP 1 04/18/05 ND ND ND 7.2 ND ND ND ND ND 3.8 26 NP NP 1 10/13/05 ND ND ND 3 ND ND ND ND ND 3.4 21 NP NP 1 04/25/06 ND ND ND ND ND ND ND ND 2.1 ND 17 NP NP 2 10/20/06 ND ND ND ND ND ND ND ND ND ND 5.7 NP NP 1 04/25/07 ND ND ND ND ND 14 ND ND ND ND 4.9 NP NP 1 10/31/07 ND ND ND ND ND ND ND ND ND ND 6 NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND 3 NP NP 1 10/20/08 ND 1.2 ND ND ND ND ND ND ND ND 1.9 NP NP 1 04/22/09 ND ND 1.5 ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND 1.7 NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND 1.1 ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND 1.6 ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND 1.2 ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)5665.0 5524.5 4539.0 5384.5 5000.5 5027.0 4693.5 4524.0 5720.5 6062.5 7305.0 1872.0 1872.0 avg rank value (Rbar)171.7 172.6 168.1 173.7 161.3 162.2 161.8 156.0 190.7 195.6 270.6 156.0 156.0 Number of each rank value Rank Value rank value of NDs =30 29 25 28 30 30 28 29 24 24 10 12 12 156 rank value of 1.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 312 Beryllium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 9 of 72 rank value of 1.2s =0 1 0 0 0 0 0 0 0 0 1 0 0 313.5 rank value of 1.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 315 rank value of 1.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 316 rank value of 1.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 317 rank value of 1.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 318 rank value of 1.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 319 rank value of 2s =0 0 0 0 1 0 0 0 1 0 0 0 0 320.5 rank value of 2.1s =1 0 1 0 0 0 0 0 1 0 0 0 0 323 rank value of 2.2s =0 0 0 0 0 0 1 0 0 1 0 0 0 325.5 rank value of 2.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 327 rank value of 2.4s =0 0 0 0 0 0 0 0 2 0 0 0 0 328.5 rank value of 2.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 330 rank value of 3s =0 0 0 1 0 0 0 0 0 0 1 0 0 331.5 rank value of 3.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 333 rank value of 3.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 334 rank value of 4.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 335 rank value of 4.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 336 rank value of 4.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 337 rank value of 4.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 338 rank value of 4.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 rank value of 5.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 340 rank value of 5.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 6s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 rank value of 7s =0 2 0 0 0 0 0 0 0 0 0 0 0 343.5 rank value of 7.2s =0 0 0 1 0 0 0 0 0 0 0 0 0 345 rank value of 8.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 346 rank value of 14s =0 0 0 0 0 1 0 0 0 0 0 0 0 347 rank value of 17s =0 0 0 0 0 0 0 0 0 0 1 0 0 348 rank value of 20s =0 0 0 0 0 0 0 0 0 0 1 0 0 349 rank value of 21s =0 0 0 0 0 0 0 0 0 0 2 0 0 350.5 rank value of 26s =0 0 0 0 0 0 0 0 0 0 1 0 0 352 rank value of 28s =0 0 0 0 0 0 0 0 0 0 1 0 0 353 rank value of 33s =0 0 0 0 0 0 0 0 0 0 1 0 0 354 rank value of 95s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2688975.1 935253 806613 815185 759619 705744 1E+06 1E+06 2E+06 292032 292032 Ni bg = 92 Beryllium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 10 of 72 N = 355 H = 28.53 Adjust H for ties: Ti =3E+07 sum of T1..T9 H' = H/(1-(Ti/(N3-N))) H' =87.07 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =87.07. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 173.7 161.3 162.2 161.8 156.0 190.7 195.6 270.6 156.0 156.0 avg Rbar (background) = 171.0 171.0 171.0 171.0 171.0 171.0 171.0 171.0 171.0 171.0 Dx = 2.7 -9.7 -8.8 -9.1 -15.0 19.7 24.6 99.6 -15.0 -15.0 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------NE -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Beryllium averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Beryllium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 11 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Beryllium NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 95 2 4/28/03 20 2 10/30/03 33 1 4/20/04 21 1 10/21/04 28 1 4/18/05 26 1 10/13/05 21 1 4/25/06 17 2 10/20/06 5.7 1 4/25/07 4.9 1 10/31/07 6 1 4/23/08 3 1 10/20/08 1.9 1 4/22/09 NS 1 10/26/09 1.7 1 4/22/10 ND 1 10/27/10 ND 1 4/29/11 1.1 1 10/25/11 1.6 1 4/20/12 ND 1 10/24/12 ND 1 4/24/13 1.2 1 10/24/13 ND 1 4/24/14 ND 1 10/27/14 ND 1 4/28/15 ND 1 10/27/15 ND 1 4/19/16 ND 1 If not detected (ND), use half of the detection limit. Xbar =10.855556 SD =19.688875 N =27 1/NSi(Xi-Xbar)3 =22298.649 g1=3.0917294 Since the Coefficient of Skewness of 3.09 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =1.028422 SD =1.7253631 N =27 1/NSi(Xi-Xbar)3 =2.2307735 g1=0.4596207 Be (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 12 of 72 Since the Coefficient of Skewness of 0.46 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 3.3198345 = xmean (Mean of N1-N8 historical data) 0.5413573 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 1.7404662 -2.9174229 0 5 4.5 4/25/07 1.5892352 -3.1967781 0 5 4.5 10/31/07 1.7917595 -2.8226735 0 5 4.5 4/23/08 1.0986123 -4.103061 0 5 4.5 10/20/08 0.6418539 -4.9467891 0 5 4.5 10/26/09 0.5306283 -5.152246 0 5 4.5 4/22/10 -0.693147 -7.4128146 0 5 4.5 10/27/10 -0.693147 -7.4128146 0 5 4.5 4/29/11 0.0953102 -5.9563693 0 5 4.5 10/25/11 0.4700036 -5.2642324 0 5 4.5 4/20/12 -0.693147 -7.4128146 0 5 4.5 10/24/12 -0.693147 -7.4128146 0 5 4.5 4/24/13 0.1823216 -5.7956412 0 5 4.5 10/24/13 -0.693147 -7.4128146 0 5 4.5 4/24/14 -0.693147 -7.4128146 0 5 4.5 10/27/14 -0.693147 -7.4128146 0 5 4.5 4/28/15 -0.693147 -7.4128146 0 5 4.5 10/27/15 -0.693147 -7.4128146 0 5 4.5 4/19/16 -0.693147 -7.4128146 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Be (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 13 of 72 The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. Be (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 14 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Cadmium NC MCL (mg/l):2 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 2 NS NS ND 1.3 1.2 1.3 2.1 ND 5.4 NS NP NP 1 06/26/00 1.6 ND NS NS NS NS NS NS NS NS NS NP NP 1 07/26/00 1.1 3.2 NS NS NS NS NS NS NS NS NS NP NP 1 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 1 04/09/01 130 2 NS ND ND ND 1.7 1.8 2.7 19 NS NP NP 1 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 1 04/15/02 13 ND NS ND ND ND 4 ND 5.5 19 NS NP NP 10 09/26/02 ND ND 4.2 21 ND 10 ND 2.3 4.2 19 180 NP NP 1 04/28/03 3.6 ND ND 6 ND ND ND ND 2.9 16 20 NP NP 1 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 1 04/20/04 ND ND ND ND ND ND ND ND ND 8.8 8.9 NP NP 1 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/20/06 3.8 ND ND ND ND ND ND ND 1.5 ND 5.2 NP NP 1 04/25/07 ND ND ND ND ND 2.2 ND ND ND ND ND NP NP 1 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND 1.6 NP NP 1 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND 4.8 ND 1 10/24/12 ND ND ND ND ND ND ND ND ND ND ND 1 ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 1.2 ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND 2.3 ND 1 10/27/15 1.9 ND ND ND ND ND ND ND ND ND ND 3.1 ND 1 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)6550.0 5337.5 4393.5 5220.0 4996.5 5355.5 5029.5 5032.5 5558.5 5983.0 5143.5 2718.0 1872.0 avg rank value (Rbar)198.5 166.8 162.7 168.4 161.2 172.8 173.4 173.5 185.3 193.0 190.5 226.5 156.0 Number of each rank value Rank Value rank value of NDs =25 30 26 29 30 28 26 26 25 25 22 7 12 156 rank value of 1s =0 0 0 0 0 0 0 0 0 0 0 1 0 312 Cadmium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 15 of 72 rank value of 1.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 313 rank value of 1.2s =0 0 0 0 0 1 0 0 0 0 0 1 0 314.5 rank value of 1.3s =0 0 0 0 1 0 1 0 0 0 0 0 0 316.5 rank value of 1.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 318 rank value of 1.6s =1 0 0 0 0 0 0 0 0 0 1 0 0 319.5 rank value of 1.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 321 rank value of 1.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 322 rank value of 1.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 323 rank value of 2s =1 1 0 0 0 0 0 0 0 0 0 0 0 324.5 rank value of 2.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 326 rank value of 2.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 327 rank value of 2.3s =0 0 0 0 0 0 0 1 0 0 0 1 0 328.5 rank value of 2.7s =0 0 0 0 0 0 0 0 1 0 0 0 0 330 rank value of 2.9s =0 0 0 0 0 0 0 0 1 0 0 0 0 331 rank value of 3.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 332 rank value of 3.2s =0 1 0 0 0 0 0 0 0 0 0 0 0 333 rank value of 3.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 334 rank value of 3.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 335 rank value of 4s =0 0 0 0 0 0 1 0 0 0 0 0 0 336 rank value of 4.2s =0 0 1 0 0 0 0 0 1 0 0 0 0 337.5 rank value of 4.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 339 rank value of 5.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 340 rank value of 5.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 341 rank value of 5.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 342 rank value of 6s =0 0 0 1 0 0 0 0 0 0 0 0 0 343 rank value of 8.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 344 rank value of 8.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 345 rank value of 10s =0 0 0 0 0 1 0 0 0 0 0 0 0 346 rank value of 13s =1 0 0 0 0 0 0 0 0 0 0 0 0 347 rank value of 16s =0 0 0 0 0 0 0 0 0 1 0 0 0 348 rank value of 19s =0 0 0 0 0 0 0 0 0 3 0 0 0 350 rank value of 20s =0 0 0 0 0 0 0 0 0 0 1 0 0 352 rank value of 21s =0 0 0 1 0 0 0 0 0 0 0 0 0 353 rank value of 130s =1 0 0 0 0 0 0 0 0 0 0 0 0 354 rank value of 180s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2881206.1 878981 805323 925206 872271 873312 1E+06 1E+06 979837 615627 292032 Ni bg = 92 N = 355 H = 5.75 Cadmium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 16 of 72 Adjust H for ties: Ti =3E+07 sum of T1..T8 H' = H/(1-(Ti/(N3-N))) H' =17.56 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is greater than H' =17.56. Therefore, the null hypothesis of no contamination at the 5% level holds true and significant evidence of contamination does not exist. Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 168.4 161.2 172.8 173.4 173.5 185.3 193.0 190.5 226.5 156.0 avg Rbar (background) = 177.0 177.0 177.0 177.0 177.0 177.0 177.0 177.0 177.0 177.0 Dx = -8.6 -15.8 -4.2 -3.5 -3.4 8.3 16.0 13.5 49.5 -21.0 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Cadmium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 17 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Chromium NC MCL (mg/l):10 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 18 17 11 ND 26 5.4 50 NS NP NP 5 06/26/00 22 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 29 20 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 130 ND NS 11 8.4 ND ND 20 27 160 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 170 ND NS ND ND 5.7 7 10 56 180 NS NP NP 5 09/26/02 33 5.4 33 510 ND 5.2 ND 37 36 230 770 NP NP 5 04/28/03 ND ND ND 89 ND ND ND ND ND 110 27 NP NP 5 10/30/03 30 ND NT ND 6.2 ND ND ND 31 4.6 140 NP NP 2 04/20/04 33 ND 2.1 45 13 ND ND 11 3.5 190 68 NP NP 2 10/21/04 21 ND 2.8 16 2 ND ND ND ND 120 140 NP NP 2 04/18/05 49 12 8.3 680 2.9 ND ND 3.2 ND 210 100 NP NP 2 10/13/05 52 ND 3.7 230 4.7 ND ND ND ND 150 88 NP NP 2 04/25/06 65 ND 16 ND ND ND ND ND 16 100 93 NP NP 10 10/20/06 50 ND 11 24 ND ND ND ND 17 ND 27 NP NP 5 04/25/07 20 ND ND 16 ND 410 ND ND ND ND 17 NP NP 10 10/31/07 40.9 ND 11.9 10.9 7.8 ND ND ND 5.1 75.5 33.7 NP NP 5 04/23/08 10.7 ND 16.8 7.8 ND ND ND ND 7.6 7.3 14.9 NP NP 5 10/20/08 38.6 ND 29.4 12.7 ND ND ND ND ND ND 6.8 NP NP 5 04/22/09 12.3 ND 28.9 19.7 5.1 ND ND ND 7.3 ND NS NP NP 5 10/26/09 10 ND 8.1 ND 18.7 ND NS NS NS 10.9 8.1 NP NP 5 04/22/10 14.3 10.9 13.1 ND ND ND NS NS ND ND ND NP NP 5 10/27/10 10.1 ND 6.6 7.1 ND ND 12 9.2 ND ND 5.2 ND ND 5 04/29/11 8 ND 8.6 ND ND ND ND ND ND ND ND ND ND 5 10/25/11 15 ND ND 21.1 ND ND 8.1 ND ND 9.2 5.1 ND ND 5 04/20/12 24.5 ND ND 5.1 ND ND 7.9 ND ND ND ND 12.3 ND 5 10/24/12 30.4 6 ND 6.4 ND ND ND ND ND ND ND ND ND 5 04/24/13 19 ND ND 8.8 6.8 ND ND ND ND ND ND ND ND 5 10/24/13 14.5 ND 12.1 ND ND ND ND ND ND ND ND ND ND 5 04/24/14 12.8 ND ND ND ND ND ND ND ND ND ND 5.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 10.3 ND 8.2 7.9 ND ND ND ND ND ND ND ND ND 5 10/27/15 31.4 ND ND ND ND ND ND ND ND 7.7 ND ND ND 5 04/19/16 13.3 ND ND 6.8 ND ND ND ND ND ND ND ND ND 5 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)9504.5 4140.5 5543.0 7023.0 4803.5 3922.5 3640.5 4245.5 5004.0 6563.0 5982.5 1551.5 1266.0 avg rank value (Rbar)288.0 129.4 205.3 226.5 155.0 126.5 125.5 146.4 166.8 211.7 221.6 129.3 105.5 Number of each rank value Rank Value rank value of NDs =2 27 10 10 20 27 25 22 19 15 11 10 12 105.5 rank value of 2s =0 0 0 0 1 0 0 0 0 0 0 0 0 211 Chromium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 18 of 72 rank value of 2.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 212 rank value of 2.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 213 rank value of 2.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 214 rank value of 3.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 215 rank value of 3.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 216 rank value of 3.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 217 rank value of 4.6s =0 0 0 0 0 0 0 0 0 1 0 0 0 218 rank value of 4.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 219 rank value of 5.1s =0 0 0 1 1 0 0 0 1 0 1 1 0 222 rank value of 5.2s =0 0 0 0 0 1 0 0 0 0 1 0 0 225.5 rank value of 5.4s =0 1 0 0 0 0 0 0 1 0 0 0 0 227.5 rank value of 5.7s =0 0 0 0 0 1 0 0 0 0 0 0 0 229 rank value of 6s =0 1 0 0 0 0 0 0 0 0 0 0 0 230 rank value of 6.2s =0 0 0 0 1 0 0 0 0 0 0 0 0 231 rank value of 6.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 232 rank value of 6.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 233 rank value of 6.8s =0 0 0 1 1 0 0 0 0 0 1 0 0 235 rank value of 7s =0 0 0 0 0 0 1 0 0 0 0 0 0 237 rank value of 7.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 238 rank value of 7.3s =0 0 0 0 0 0 0 0 1 1 0 0 0 239.5 rank value of 7.6s =0 0 0 0 0 0 0 0 1 0 0 0 0 241 rank value of 7.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 242 rank value of 7.8s =0 0 0 1 1 0 0 0 0 0 0 0 0 243.5 rank value of 7.9s =0 0 0 1 0 0 1 0 0 0 0 0 0 245.5 rank value of 8s =1 0 0 0 0 0 0 0 0 0 0 0 0 247 rank value of 8.1s =0 0 1 0 0 0 1 0 0 0 1 0 0 249 rank value of 8.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 251 rank value of 8.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 252 rank value of 8.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 253 rank value of 8.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 254 rank value of 8.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 255 rank value of 9.2s =0 0 0 0 0 0 0 1 0 1 0 0 0 256.5 rank value of 10s =1 0 0 0 0 0 0 1 0 0 0 0 0 258.5 rank value of 10.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 260 rank value of 10.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 261 rank value of 10.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 262 rank value of 10.9s =0 1 0 1 0 0 0 0 0 1 0 0 0 264 rank value of 11s =0 0 1 1 0 1 0 1 0 0 0 0 0 267.5 rank value of 11.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 270 rank value of 12s =0 1 0 0 0 0 1 0 0 0 0 0 0 271.5 rank value of 12.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 273 rank value of 12.3s =1 0 0 0 0 0 0 0 0 0 0 1 0 274.5 rank value of 12.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 276 rank value of 12.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 277 rank value of 13s =0 0 0 0 1 0 0 0 0 0 0 0 0 278 rank value of 13.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 279 rank value of 13.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 280 rank value of 14.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 281 rank value of 14.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 282 rank value of 14.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 283 rank value of 15s =2 0 0 0 0 0 0 0 0 0 0 0 0 284.5 rank value of 16s =0 0 1 2 0 0 0 0 1 0 0 0 0 287.5 rank value of 16.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 290 rank value of 17s =0 0 0 0 1 0 0 0 1 0 1 0 0 292 rank value of 18s =0 0 0 1 0 0 0 0 0 0 0 0 0 294 rank value of 18.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 295 rank value of 19s =1 0 0 0 0 0 0 0 0 0 0 0 0 296 rank value of 19.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 297 Chromium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 19 of 72 rank value of 20s =1 1 0 0 0 0 0 1 0 0 0 0 0 299 rank value of 21s =1 0 0 0 0 0 0 0 0 0 0 0 0 301 rank value of 21.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 302 rank value of 22s =1 0 0 0 0 0 0 0 0 0 0 0 0 303 rank value of 24s =0 0 0 1 0 0 0 0 0 0 0 0 0 304 rank value of 24.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 26s =0 0 0 0 0 0 0 1 0 0 0 0 0 306 rank value of 27s =0 0 0 0 0 0 0 0 1 0 2 0 0 308 rank value of 28.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 310 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 311 rank value of 29.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 312 rank value of 30s =1 0 0 0 0 0 0 0 0 0 0 0 0 313 rank value of 30.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 314 rank value of 31s =0 0 0 0 0 0 0 0 1 0 0 0 0 315 rank value of 31.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 316 rank value of 33s =2 0 1 0 0 0 0 0 0 0 0 0 0 318 rank value of 33.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 320 rank value of 36s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 37s =0 0 0 0 0 0 0 1 0 0 0 0 0 322 rank value of 38.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 323 rank value of 40.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 324 rank value of 45s =0 0 0 1 0 0 0 0 0 0 0 0 0 325 rank value of 49s =1 0 0 0 0 0 0 0 0 0 0 0 0 326 rank value of 50s =1 0 0 0 0 0 0 0 0 1 0 0 0 327.5 rank value of 52s =1 0 0 0 0 0 0 0 0 0 0 0 0 329 rank value of 56s =0 0 0 0 0 0 0 0 1 0 0 0 0 330 rank value of 65s =1 0 0 0 0 0 0 0 0 0 0 0 0 331 rank value of 68s =0 0 0 0 0 0 0 0 0 0 1 0 0 332 rank value of 75.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 333 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 334 rank value of 89s =0 0 0 1 0 0 0 0 0 0 0 0 0 335 rank value of 93s =0 0 0 0 0 0 0 0 0 0 1 0 0 336 rank value of 100s =0 0 0 0 0 0 0 0 0 1 1 0 0 337.5 rank value of 110s =0 0 0 0 0 0 0 0 0 1 0 0 0 339 rank value of 120s =0 0 0 0 0 0 0 0 0 1 0 0 0 340 rank value of 130s =1 0 0 0 0 0 0 0 0 0 0 0 0 341 rank value of 140s =0 0 0 0 0 0 0 0 0 0 2 0 0 342.5 rank value of 150s =0 0 0 0 0 0 0 0 0 1 0 0 0 344 rank value of 160s =0 0 0 0 0 0 0 0 0 1 0 0 0 345 rank value of 170s =1 0 0 0 0 0 0 0 0 0 0 0 0 346 rank value of 180s =0 0 0 0 0 0 0 0 0 1 0 0 0 347 rank value of 190s =0 0 0 0 0 0 0 0 0 1 0 0 0 348 rank value of 210s =0 0 0 0 0 0 0 0 0 1 0 0 0 349 rank value of 230s =0 0 0 1 0 0 0 0 0 1 0 0 0 350.5 rank value of 410s =0 0 0 0 0 1 0 0 0 0 0 0 0 352 rank value of 510s =0 0 0 1 0 0 0 0 0 0 0 0 0 353 rank value of 680s =0 0 0 1 0 0 0 0 0 0 0 0 0 354 rank value of 770s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Chromium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 20 of 72 Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 4001949.4 2E+06 744310 496323 457008 621527 834667 1E+06 1E+06 200596 133563 Ni bg = 92 N = 355 H = 52.05 Adjust H for ties: Ti =9E+06 sum of T1..T25 H' = H/(1-(Ti/(N3-N))) H' =65.64 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =65.64. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 226.5 155.0 126.5 125.5 146.4 166.8 211.7 221.6 129.3 105.5 avg Rbar (background) = 208.6 208.6 208.6 208.6 208.6 208.6 208.6 208.6 208.6 208.6 Dx = 18.0 -53.6 -82.0 -83.0 -62.2 -41.8 3.1 13.0 -79.3 -103.1 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Chromium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 21 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND 8.2 5.4 ND 14 ND 16 NS NP NP 5 06/26/00 10 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 9.9 ND NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 54 ND NS ND ND ND 13 12 13 59 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 58 ND NS ND ND ND 18 8 21 82 NS NP NP 5 09/26/02 13 5.4 16 100 ND 16 7.4 21 19 85 560 NP NP 5 04/28/03 21 ND ND 37 ND ND 6.9 ND 17 50 81 NP NP 5 10/30/03 9 ND NT ND ND ND 5.7 ND 52 8.8 110 NP NP 5 04/20/04 9.5 ND ND 7.7 5.2 ND 13 6.4 ND 43 50 NP NP 5 10/21/04 6.2 ND ND ND ND ND ND ND ND 31 120 NP NP 5 04/18/05 12 ND ND 110 ND ND ND ND ND 36 70 NP NP 5 10/13/05 21 ND ND 32 ND ND 5.1 ND ND 29 56 NP NP 5 04/25/06 16 ND ND ND ND ND ND ND ND 25 57 NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND 260 ND ND ND ND ND NP NP 10 10/31/07 16.8 ND ND ND 10.6 ND ND ND ND ND 17.6 NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND 22.3 NP NP 5 10/20/08 27 10.4 19.5 9.4 7.7 ND 12.6 5.3 7.1 ND 18.4 NP NP 5 04/22/09 5 6.3 17.1 8.5 5.7 ND 7 ND 6.4 ND NS NP NP 5 10/26/09 ND ND ND ND 6 ND NS NS NS ND 6 NP NP 5 04/22/10 5.6 ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND 17.3 5.6 ND ND 7.8 29.6 ND 5 04/29/11 ND ND ND ND 6.9 ND 8.9 ND ND ND ND 26.3 ND 5 10/25/11 5.3 ND ND 6.4 6.3 ND 21 ND ND ND ND 42.4 ND 5 04/20/12 6.9 ND ND ND ND ND 6.4 ND ND ND ND 134 ND 5 10/24/12 15.7 ND ND ND 5.6 ND 6.5 ND ND ND ND 48.5 ND 5 04/24/13 16.5 ND ND ND 10.8 ND 5.6 ND ND ND 8.9 115 ND 5 10/24/13 11.8 ND ND ND 8 ND 7.5 ND ND ND ND 84.5 ND 5 04/24/14 ND ND ND ND 5.7 ND ND ND ND ND ND 65.1 ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND 24.2 ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND 29.3 ND 5 10/27/15 6.2 ND ND ND 5.6 ND ND ND ND ND ND 39 ND 5 04/19/16 7.2 ND ND ND 12.1 6.4 5.1 ND ND ND ND 101 ND 5 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)7729.0 4155.5 3711.5 5110.5 5637.5 4294.5 6018.5 4472.5 4758.0 5893.0 5992.5 3664.0 1398.0 avg rank value (Rbar)234.2 129.9 137.5 164.9 181.9 138.5 207.5 154.2 158.6 190.1 221.9 305.3 116.5 Number of each rank value Rank Value rank value of NDs =10 29 24 23 17 27 12 22 23 20 13 0 12 116.5 rank value of 5s =1 0 0 0 0 0 0 0 0 0 0 0 0 233 Cobalt (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 22 of 72 rank value of 5.1s =0 0 0 0 0 0 2 0 0 0 0 0 0 234.5 rank value of 5.2s =0 0 0 0 1 0 0 0 0 0 0 0 0 236 rank value of 5.3s =1 0 0 0 0 0 0 1 0 0 0 0 0 237.5 rank value of 5.4s =0 1 0 0 0 1 0 0 0 0 0 0 0 239.5 rank value of 5.6s =1 0 0 0 2 0 1 1 0 0 0 0 0 243 rank value of 5.7s =0 0 0 0 2 0 1 0 0 0 0 0 0 247 rank value of 6s =0 0 0 0 1 0 0 0 0 0 1 0 0 249.5 rank value of 6.2s =2 0 0 0 0 0 0 0 0 0 0 0 0 251.5 rank value of 6.3s =0 1 0 0 1 0 0 0 0 0 0 0 0 253.5 rank value of 6.4s =0 0 0 1 0 1 1 1 1 0 0 0 0 257 rank value of 6.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 260 rank value of 6.9s =1 0 0 0 1 0 1 0 0 0 0 0 0 262 rank value of 7s =0 0 0 0 0 0 1 0 0 0 0 0 0 264 rank value of 7.1s =0 0 0 0 0 0 0 0 1 0 0 0 0 265 rank value of 7.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 266 rank value of 7.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 267 rank value of 7.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 268 rank value of 7.7s =0 0 0 1 1 0 0 0 0 0 0 0 0 269.5 rank value of 7.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 271 rank value of 8s =0 0 0 0 1 0 0 0 0 0 0 0 0 272 rank value of 8.2s =0 0 0 0 1 0 0 1 0 0 0 0 0 273.5 rank value of 8.5s =0 0 0 1 0 0 0 0 0 0 0 0 0 275 rank value of 8.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 276 rank value of 8.9s =0 0 0 0 0 0 1 0 0 0 1 0 0 277.5 rank value of 9s =1 0 0 0 0 0 0 0 0 0 0 0 0 279 rank value of 9.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 280 rank value of 9.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 281 rank value of 9.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 282 rank value of 10s =1 0 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 10.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 284 rank value of 10.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 285 rank value of 10.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 286 rank value of 11.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 287 rank value of 12s =1 0 0 0 0 0 0 1 0 0 0 0 0 288.5 rank value of 12.1s =0 0 0 0 1 0 0 0 0 0 0 0 0 290 rank value of 12.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 291 rank value of 13s =1 0 0 0 0 0 2 0 1 0 0 0 0 293.5 rank value of 14s =0 0 0 0 0 0 0 1 0 0 0 0 0 296 rank value of 15.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 297 rank value of 16s =1 0 1 0 0 1 0 0 0 1 0 0 0 299.5 rank value of 16.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 302 rank value of 16.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 303 rank value of 17s =0 0 0 0 0 0 0 0 1 0 0 0 0 304 rank value of 17.1s =0 0 1 0 0 0 0 0 0 0 0 0 0 305 rank value of 17.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 306 rank value of 17.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 307 rank value of 18s =0 0 0 0 0 0 1 0 0 0 0 0 0 308 rank value of 18.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 309 rank value of 19s =0 0 0 0 0 0 0 0 1 0 0 0 0 310 rank value of 19.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 311 rank value of 21s =2 0 0 0 0 0 1 1 1 0 0 0 0 314 rank value of 22.3s =0 0 0 0 0 0 0 0 0 0 1 0 0 317 rank value of 24.2s =0 0 0 0 0 0 0 0 0 0 0 1 0 318 rank value of 25s =0 0 0 0 0 0 0 0 0 1 0 0 0 319 rank value of 26.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 320 rank value of 27s =1 0 0 0 0 0 0 0 0 0 0 0 0 321 rank value of 29s =0 0 0 0 0 0 0 0 0 1 0 0 0 322 rank value of 29.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 323 Cobalt (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 23 of 72 rank value of 29.6s =0 0 0 0 0 0 0 0 0 0 0 1 0 324 rank value of 31s =0 0 0 0 0 0 0 0 0 1 0 0 0 325 rank value of 32s =0 0 0 1 0 0 0 0 0 0 0 0 0 326 rank value of 36s =0 0 0 0 0 0 0 0 0 1 0 0 0 327 rank value of 37s =0 0 0 1 0 0 0 0 0 0 0 0 0 328 rank value of 39s =0 0 0 0 0 0 0 0 0 0 0 1 0 329 rank value of 42.4s =0 0 0 0 0 0 0 0 0 0 0 1 0 330 rank value of 43s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 48.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 332 rank value of 50s =0 0 0 0 0 0 0 0 0 1 1 0 0 333.5 rank value of 52s =0 0 0 0 0 0 0 0 1 0 0 0 0 335 rank value of 54s =1 0 0 0 0 0 0 0 0 0 0 0 0 336 rank value of 56s =0 0 0 0 0 0 0 0 0 0 1 0 0 337 rank value of 57s =0 0 0 0 0 0 0 0 0 0 1 0 0 338 rank value of 58s =1 0 0 0 0 0 0 0 0 0 0 0 0 339 rank value of 59s =0 0 0 0 0 0 0 0 0 1 0 0 0 340 rank value of 65.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 341 rank value of 70s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 rank value of 81s =0 0 0 0 0 0 0 0 0 0 1 0 0 343 rank value of 82s =0 0 0 0 0 0 0 0 0 1 0 0 0 344 rank value of 84.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 345 rank value of 85s =0 0 0 0 0 0 0 0 0 1 0 0 0 346 rank value of 100s =0 0 0 1 0 0 0 0 0 0 0 0 0 347 rank value of 110s =0 0 0 1 0 0 0 0 0 0 1 0 0 348.5 rank value of 115s =0 0 0 0 0 0 0 0 0 0 0 1 0 350 rank value of 120s =0 0 0 0 0 0 0 0 0 0 1 0 0 351 rank value of 134s =0 0 0 0 0 0 0 0 0 0 0 1 0 352 rank value of 260s =0 0 0 0 0 1 0 0 0 0 0 0 0 353 rank value of 560s =0 0 0 0 0 0 0 0 0 0 1 0 0 354 n =33 32 27 31 31 31 29 29 30 31 27 11 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2643861.0 842491 1E+06 594927 1E+06 689767 754619 1E+06 1E+06 1E+06 162867 Ni bg = 92 N = 355 H = 26.96 Adjust H for ties: Ti =1E+07 sum of T1..T20 H' = H/(1-(Ti/(N3-N))) H' =37.40 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% Cobalt (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 24 of 72 significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =37.40. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 164.9 181.9 138.5 207.5 154.2 158.6 190.1 221.9 305.3 116.5 avg Rbar (background) = 169.5 169.5 169.5 169.5 169.5 169.5 169.5 169.5 169.5 169.5 Dx = -4.7 12.3 -31.0 38.0 -15.3 -10.9 20.6 52.4 135.8 -53.0 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No Yes Yes No If SSI, is current event above MCL?-------NE NE - Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Cobalt averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Cobalt (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 25 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 560 5 4/28/03 81 5 10/30/03 110 5 4/20/04 50 5 10/21/04 120 5 4/18/05 70 5 10/13/05 56 5 4/25/06 57 10 10/20/06 ND 5 4/25/07 ND 10 10/31/07 17.6 5 4/23/08 22.3 5 10/20/08 18.4 5 4/22/09 NS 5 10/26/09 6 5 4/22/10 ND 5 10/27/10 7.8 5 4/29/11 ND 5 10/25/11 ND 5 4/20/12 ND 5 10/24/12 ND 5 4/24/13 8.9 5 10/24/13 ND 5 4/24/14 ND 5 10/27/14 ND 5 4/28/15 ND 5 10/27/15 ND 5 4/19/16 ND 5 If not detected (ND), use half of the detection limit. Xbar =45.185185 SD =108.61749 N =27 1/NSi(Xi-Xbar)3 =5036604 g1=4.1593374 Since the Coefficient of Skewness of 4.16 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =2.3689251 SD =1.6405 N =27 1/NSi(Xi-Xbar)3 =2.9617837 g1=0.7099214 Co (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 26 of 72 Since the Coefficient of Skewness of 0.71 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 4.5549099 = xmean (Mean of N1-N8 historical data) 0.7832425 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 0.9162907 -4.6455844 0 5 4.5 4/25/07 1.6094379 -3.7606131 0 5 4.5 10/31/07 2.8678989 -2.1538808 0 5 4.5 4/23/08 3.1045867 -1.8516912 0 5 4.5 10/20/08 2.9123507 -2.0971273 0 5 4.5 10/26/09 1.7917595 -3.5278352 0 5 4.5 4/22/10 0.9162907 -4.6455844 0 5 4.5 10/27/10 2.0541237 -3.1928632 0 5 4.5 4/29/11 0.9162907 -4.6455844 0 5 4.5 10/25/11 0.9162907 -4.6455844 0 5 4.5 4/20/12 0.9162907 -4.6455844 0 5 4.5 10/24/12 0.9162907 -4.6455844 0 5 4.5 4/24/13 2.1860513 -3.0244255 0 5 4.5 10/24/13 0.9162907 -4.6455844 0 5 4.5 4/24/14 0.9162907 -4.6455844 0 5 4.5 10/27/14 0.9162907 -4.6455844 0 5 4.5 4/28/15 0.9162907 -4.6455844 0 5 4.5 10/27/15 0.9162907 -4.6455844 0 5 4.5 4/19/16 0.9162907 -4.6455844 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Co (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 27 of 72 The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. Co (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 28 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Cobalt NC MCL (mg/l):Not Established Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 6 MD L 9/26/02 NP 5 4/28/03 NP 5 10/30/03 NP 5 4/20/04 NP 5 10/21/04 NP 5 4/18/05 NP 5 10/13/05 NP 5 4/25/06 NP 10 10/20/06 NP 5 4/25/07 NP 10 10/31/07 NP 5 4/23/08 NP 5 10/20/08 NP 5 4/22/09 NP 5 10/26/09 NP 5 4/22/10 NP 5 10/27/10 29.6 5 4/29/11 26.3 5 10/25/11 42.4 5 4/20/12 134 5 10/24/12 48.5 5 4/24/13 115 5 10/24/13 84.5 5 4/24/14 65.1 5 10/27/14 24.2 5 4/28/15 29.3 5 10/27/15 39 5 4/19/16 101 5 If not detected (ND), use half of the detection limit. Xbar =61.575 SD =38.073473 N =12 1/NSi(Xi-Xbar)3 =35212.622 g1=0.7269654 Since the Coefficient of Skewness of 0.73 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =3.9486771 SD =0.6089057 Co (S-C MW-16) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 29 of 72 N =12 1/NSi(Xi-Xbar)3 =0.0527795 g1=0.2663776 Use the real values (not log-transformed) indicated in the previous section. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 68.175 = xmean (Mean of N1-N8 historical data) 39.811117 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/27/14 24.2 -1.104591 0 5 4.5 4/28/15 29.3 -0.9764861 0 5 4.5 10/27/15 39 -0.7328355 0 5 4.5 4/19/16 101 0.8245184 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. -2 -1 0 1 2 3 4 5 6 9/ 1 8 / 1 4 12 / 2 7 / 1 4 4/ 6 / 1 5 7/ 1 5 / 1 5 10 / 2 3 / 1 5 1/ 3 1 / 1 6 5/ 1 0 / 1 6 8/ 1 8 / 1 6 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Co (S-C MW-16) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 30 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Copper NC MCL (mg/l):1000 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 12 NS NS ND ND 13 ND 27 ND 22 NS NP NP 5 06/26/00 17 6 NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 12 6.1 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 200 04/09/01 77 8.4 NS ND ND 5.4 ND 26 38 110 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 200 04/15/02 69 ND NS ND ND ND ND 13 68 120 NS NP NP 2 09/26/02 20 10 31 220 ND ND 2.6 42 88 150 450 NP NP 2 04/28/03 24 ND 2.6 40 ND ND ND ND 28 94 71 NP NP 2 10/30/03 18 ND NT ND 2.3 2.6 ND 3 85 4.4 150 NP NP 2 04/20/04 18 ND 2.8 12 5.3 2.3 4.3 13 7.4 100 89 NP NP 2 10/21/04 11 ND ND 2 ND ND ND ND ND 63 140 NP NP 2 04/18/05 29 ND ND 240 ND ND ND 3.8 ND 120 130 NP NP 2 10/13/05 31 2.6 3.5 70 ND ND ND ND 3 82 96 NP NP 2 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 200 10/20/06 26 ND ND 9.6 ND ND ND ND 20 ND 25 NP NP 5 04/25/07 15 ND ND ND ND 330 ND ND ND ND 26 NP NP 10 10/31/07 29.2 ND ND ND ND ND ND ND 6.3 40.3 47.4 NP NP 5 04/23/08 7.2 ND ND ND ND ND ND ND 7.2 ND 17 NP NP 5 10/20/08 26.5 ND 8.3 ND ND ND ND ND ND ND 9.7 NP NP 5 04/22/09 5.1 ND 22.6 6 ND ND ND ND 8.8 ND NS NP NP 5 10/26/09 5.8 ND ND ND 6.4 ND NS NS NS ND 7.1 NP NP 5 04/22/10 9.9 ND ND ND ND 5.9 NS NS ND ND ND NP NP 5 10/27/10 6.7 ND ND ND ND ND ND 12.4 ND ND 53.9 ND ND 5 04/29/11 6.4 ND ND ND 6.7 6.1 ND ND ND ND 5.2 ND ND 5 10/25/11 9.6 ND ND 9.4 6.8 11.2 7.6 ND ND 5.1 6.9 ND ND 5 04/20/12 15.6 ND ND ND 5.8 5.2 ND ND ND ND ND 6.5 ND 5 10/24/12 22.7 ND ND ND 6 ND ND ND 5.1 ND ND ND ND 5 04/24/13 13.4 ND ND ND 9.3 6 ND ND ND ND ND ND ND 5 10/24/13 12.6 ND ND ND 7.5 5.8 ND ND ND ND ND ND ND 5 04/24/14 7.9 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 7.4 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 19.1 ND ND ND 5.4 7.3 ND ND ND ND ND 6 ND 5 04/19/16 7.8 ND 5.4 ND ND ND ND ND ND ND ND ND ND 5 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)9461.0 4416.5 4166.0 5238.5 5006.0 5382.5 3729.5 4742.0 5605.0 6045.0 6355.0 1669.0 1374.0 avg rank value (Rbar)286.7 138.0 154.3 169.0 161.5 173.6 128.6 163.5 186.8 195.0 235.4 139.1 114.5 Number of each rank value Rank Value rank value of NDs =2 27 20 22 21 19 26 21 18 19 11 10 12 114.5 rank value of 2s =0 0 0 1 0 0 0 0 0 0 0 0 0 229 Copper (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 31 of 72 rank value of 2.3s =0 0 0 0 1 1 0 0 0 0 0 0 0 230.5 rank value of 2.6s =0 1 1 0 0 1 1 0 0 0 0 0 0 233.5 rank value of 2.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 236 rank value of 3s =0 0 0 0 0 0 0 1 1 0 0 0 0 237.5 rank value of 3.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 239 rank value of 3.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 240 rank value of 4.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 241 rank value of 4.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 242 rank value of 5.1s =1 0 0 0 0 0 0 0 1 1 0 0 0 244 rank value of 5.2s =0 0 0 0 0 1 0 0 0 0 1 0 0 246.5 rank value of 5.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 248 rank value of 5.4s =0 0 1 0 1 1 0 0 0 0 0 0 0 250 rank value of 5.8s =1 0 0 0 1 1 0 0 0 0 0 0 0 253 rank value of 5.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 255 rank value of 6s =0 1 0 1 1 1 0 0 0 0 0 1 0 258 rank value of 6.1s =0 1 0 0 0 1 0 0 0 0 0 0 0 261.5 rank value of 6.3s =0 0 0 0 0 0 0 0 1 0 0 0 0 263 rank value of 6.4s =1 0 0 0 1 0 0 0 0 0 0 0 0 264.5 rank value of 6.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 266 rank value of 6.7s =1 0 0 0 1 0 0 0 0 0 0 0 0 267.5 rank value of 6.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 269 rank value of 6.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 270 rank value of 7.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 271 rank value of 7.2s =1 0 0 0 0 0 0 0 1 0 0 0 0 272.5 rank value of 7.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 274 rank value of 7.4s =1 0 0 0 0 0 0 0 1 0 0 0 0 275.5 rank value of 7.5s =0 0 0 0 1 0 0 0 0 0 0 0 0 277 rank value of 7.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 278 rank value of 7.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 279 rank value of 7.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 280 rank value of 8.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 281 rank value of 8.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 282 rank value of 8.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 283 rank value of 9.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 284 rank value of 9.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 285 rank value of 9.6s =1 0 0 1 0 0 0 0 0 0 0 0 0 286.5 rank value of 9.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 288 rank value of 9.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 289 rank value of 10s =0 1 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 11s =1 0 0 0 0 0 0 0 0 0 0 0 0 291 rank value of 11.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 292 rank value of 12s =2 0 0 1 0 0 0 0 0 0 0 0 0 294 rank value of 12.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 296 rank value of 12.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 297 rank value of 13s =0 0 0 0 0 1 0 2 0 0 0 0 0 299 rank value of 13.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 301 rank value of 15s =1 0 0 0 0 0 0 0 0 0 0 0 0 302 rank value of 15.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 303 rank value of 17s =1 0 0 0 0 0 0 0 0 0 1 0 0 304.5 rank value of 18s =2 0 0 0 0 0 0 0 0 0 0 0 0 306.5 rank value of 19.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 308 rank value of 20s =1 0 0 0 0 0 0 0 1 0 0 0 0 309.5 rank value of 22s =0 0 0 0 0 0 0 0 0 1 0 0 0 311 rank value of 22.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 312 rank value of 22.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 313 rank value of 24s =1 0 0 0 0 0 0 0 0 0 0 0 0 314 rank value of 25s =0 0 0 0 0 0 0 0 0 0 1 0 0 315 rank value of 26s =1 0 0 0 0 0 0 1 0 0 1 0 0 317 Copper (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 32 of 72 rank value of 26.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 319 rank value of 27s =0 0 0 0 0 0 0 1 0 0 0 0 0 320 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 322 rank value of 29.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 323 rank value of 31s =1 0 1 0 0 0 0 0 0 0 0 0 0 324.5 rank value of 38s =0 0 0 0 0 0 0 0 1 0 0 0 0 326 rank value of 40s =0 0 0 1 0 0 0 0 0 0 0 0 0 327 rank value of 40.3s =0 0 0 0 0 0 0 0 0 1 0 0 0 328 rank value of 42s =0 0 0 0 0 0 0 1 0 0 0 0 0 329 rank value of 47.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 330 rank value of 53.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 331 rank value of 63s =0 0 0 0 0 0 0 0 0 1 0 0 0 332 rank value of 68s =0 0 0 0 0 0 0 0 1 0 0 0 0 333 rank value of 69s =1 0 0 0 0 0 0 0 0 0 0 0 0 334 rank value of 70s =0 0 0 1 0 0 0 0 0 0 0 0 0 335 rank value of 71s =0 0 0 0 0 0 0 0 0 0 1 0 0 336 rank value of 77s =1 0 0 0 0 0 0 0 0 0 0 0 0 337 rank value of 82s =0 0 0 0 0 0 0 0 0 1 0 0 0 338 rank value of 85s =0 0 0 0 0 0 0 0 1 0 0 0 0 339 rank value of 88s =0 0 0 0 0 0 0 0 1 0 0 0 0 340 rank value of 89s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 94s =0 0 0 0 0 0 0 0 0 1 0 0 0 342 rank value of 96s =0 0 0 0 0 0 0 0 0 0 1 0 0 343 rank value of 100s =0 0 0 0 0 0 0 0 0 1 0 0 0 344 rank value of 110s =0 0 0 0 0 0 0 0 0 1 0 0 0 345 rank value of 120s =0 0 0 0 0 0 0 0 0 2 0 0 0 346.5 rank value of 130s =0 0 0 0 0 0 0 0 0 0 1 0 0 348 rank value of 140s =0 0 0 0 0 0 0 0 0 0 1 0 0 349 rank value of 150s =0 0 0 0 0 0 0 0 0 1 1 0 0 350.5 rank value of 220s =0 0 0 1 0 0 0 0 0 0 0 0 0 352 rank value of 240s =0 0 0 1 0 0 0 0 0 0 0 0 0 353 rank value of 330s =0 0 0 0 0 1 0 0 0 0 0 0 0 354 rank value of 450s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3538781.4 885222 808388 934558 479627 775399 1E+06 1E+06 1E+06 232130 157323 Ni bg = 92 N = 355 H = 27.10 Adjust H for ties: Ti =1E+07 sum of T1..T24 H' = H/(1-(Ti/(N3-N))) H' =36.86 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% Copper (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 33 of 72 significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =36.86. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 169.0 161.5 173.6 128.6 163.5 186.8 195.0 235.4 139.1 114.5 avg Rbar (background) = 196.1 196.1 196.1 196.1 196.1 196.1 196.1 196.1 196.1 196.1 Dx = -27.1 -34.6 -22.5 -67.5 -32.6 -9.3 -1.1 39.2 -57.0 -81.6 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Copper (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 34 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Lead NC MCL (mg/l):15 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 35 NS NS ND ND ND ND 11 ND ND NS NP NP 10 06/26/00 ND 10 NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS ND NS NS NP NP 10 04/09/01 ND 59 NS ND ND ND ND ND 18 2.5 NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 13 ND NS ND ND ND ND ND 13 29 NS NP NP 10 09/26/02 ND 76 29 ND ND ND ND ND 150 20 740 NP NP 10 04/28/03 ND ND ND ND ND ND ND ND 25 ND 300 NP NP 10 10/30/03 8.7 12 NT ND ND ND ND ND 39 7.4 640 NP NP 5 04/20/04 7.2 7 5.2 6.4 5.4 ND ND ND 12 39 250 NP NP 5 10/21/04 7.2 5.6 5.7 ND ND ND ND ND ND 24 430 NP NP 5 04/18/05 13 8 5.2 73 ND ND ND ND ND 39 380 NP NP 5 10/13/05 14 6.9 ND 20 ND ND ND ND ND 29 290 NP NP 5 04/25/06 15 ND ND ND ND ND ND ND 53 19 300 NP NP 10 10/20/06 20 ND ND ND ND ND ND ND 32 ND 89 NP NP 5 04/25/07 ND ND ND ND ND 96 ND ND ND ND 69 NP NP 10 10/31/07 17.5 8.1 ND ND ND ND ND ND ND 12.3 123 NP NP 5 04/23/08 ND ND 8.4 ND ND ND ND ND 5.8 ND 50.2 NP NP 5 10/20/08 ND 13.5 7.6 ND ND ND ND ND ND ND 25.9 NP NP 5 04/22/09 ND 8.7 24.4 ND ND ND ND ND 9.8 ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND 24.7 NP NP 5 04/22/10 ND 10.5 ND ND ND ND NS NS ND ND 9.2 NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND 16 ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND 11 ND ND 5 10/25/11 ND ND ND ND ND ND 6.3 ND ND ND 14.6 ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND 6.4 ND ND 5 10/24/12 5.9 ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND 10.4 ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 7.7 ND ND ND ND ND ND ND ND ND ND ND ND 5 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 Ni 33 32 27 31 31 31 29 29 31 31 27 12 12 sum of rank values (Ri)6636.0 6469.0 4888.0 4861.5 4467.0 4531.0 4193.0 4213.5 6149.0 6123.5 7666.5 1674.0 1674.0 avg rank value (Rbar)201.1 202.2 181.0 156.8 144.1 146.2 144.6 145.3 198.4 197.5 283.9 139.5 139.5 Number of each rank value Rank Value rank value of NDs =21 20 20 28 30 30 28 28 21 21 7 12 12 139.5 rank value of 2.5s =0 0 0 0 0 0 0 0 0 1 0 0 0 279 rank value of 5.2s =0 0 2 0 0 0 0 0 0 0 0 0 0 280.5 rank value of 5.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 282 rank value of 5.6s =0 1 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 5.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 284 Lead (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 35 of 72 rank value of 5.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 285 rank value of 5.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 286 rank value of 6.3s =0 0 0 0 0 0 1 0 0 0 0 0 0 287 rank value of 6.4s =0 0 0 1 0 0 0 0 0 0 1 0 0 288.5 rank value of 6.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 7s =0 1 0 0 0 0 0 0 0 0 0 0 0 291 rank value of 7.2s =2 0 0 0 0 0 0 0 0 0 0 0 0 292.5 rank value of 7.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 294 rank value of 7.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 295 rank value of 7.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 296 rank value of 8s =0 1 0 0 0 0 0 0 0 0 0 0 0 297 rank value of 8.1s =0 1 0 0 0 0 0 0 0 0 0 0 0 298 rank value of 8.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 299 rank value of 8.7s =1 1 0 0 0 0 0 0 0 0 0 0 0 300.5 rank value of 9.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 302 rank value of 9.8s =0 0 0 0 0 0 0 0 1 0 0 0 0 303 rank value of 10s =0 1 0 0 0 0 0 0 0 0 0 0 0 304 rank value of 10.4s =0 0 0 0 0 0 0 0 0 0 1 0 0 305 rank value of 10.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 306 rank value of 11s =0 0 0 0 0 0 0 1 0 0 1 0 0 307.5 rank value of 12s =0 1 0 0 0 0 0 0 1 0 0 0 0 309.5 rank value of 12.3s =0 0 0 0 0 0 0 0 0 1 0 0 0 311 rank value of 13s =2 0 0 0 0 0 0 0 1 0 0 0 0 313 rank value of 13.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 315 rank value of 14s =1 0 0 0 0 0 0 0 0 0 0 0 0 316 rank value of 14.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 317 rank value of 15s =1 0 0 0 0 0 0 0 0 0 0 0 0 318 rank value of 16s =0 0 0 0 0 0 0 0 0 0 1 0 0 319 rank value of 17.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 320 rank value of 18s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 19s =0 0 0 0 0 0 0 0 0 1 0 0 0 322 rank value of 20s =1 0 0 1 0 0 0 0 0 1 0 0 0 324 rank value of 24s =0 0 0 0 0 0 0 0 0 1 0 0 0 326 rank value of 24.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 327 rank value of 24.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 328 rank value of 25s =0 0 0 0 0 0 0 0 1 0 0 0 0 329 rank value of 25.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 330 rank value of 29s =0 0 1 0 0 0 0 0 0 2 0 0 0 332 rank value of 32s =0 0 0 0 0 0 0 0 1 0 0 0 0 334 rank value of 35s =1 0 0 0 0 0 0 0 0 0 0 0 0 335 rank value of 39s =0 0 0 0 0 0 0 0 1 2 0 0 0 337 rank value of 50.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 339 rank value of 53s =0 0 0 0 0 0 0 0 1 0 0 0 0 340 rank value of 59s =0 1 0 0 0 0 0 0 0 0 0 0 0 341 rank value of 69s =0 0 0 0 0 0 0 0 0 0 1 0 0 342 rank value of 73s =0 0 0 1 0 0 0 0 0 0 0 0 0 343 rank value of 76s =0 1 0 0 0 0 0 0 0 0 0 0 0 344 rank value of 89s =0 0 0 0 0 0 0 0 0 0 1 0 0 345 rank value of 96s =0 0 0 0 0 1 0 0 0 0 0 0 0 346 rank value of 123s =0 0 0 0 0 0 0 0 0 0 1 0 0 347 rank value of 150s =0 0 0 0 0 0 0 0 1 0 0 0 0 348 rank value of 250s =0 0 0 0 0 0 0 0 0 0 1 0 0 349 rank value of 290s =0 0 0 0 0 0 0 0 0 0 1 0 0 350 rank value of 300s =0 0 0 0 0 0 0 0 0 0 2 0 0 351.5 rank value of 380s =0 0 0 0 0 0 0 0 0 0 1 0 0 353 rank value of 430s =0 0 0 0 0 0 0 0 0 0 1 0 0 354 rank value of 640s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 rank value of 740s =0 0 0 0 0 0 0 0 0 0 1 0 0 356 Lead (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 36 of 72 n =33 32 27 31 31 31 29 29 31 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SKi=1 (Ri2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3519000.5 762393 643680 662257 606250 612192 1E+06 1E+06 2E+06 233523 233523 Ni bg = 92 N = 356 H = 50.61 Adjust H for ties: Ti =2E+07 sum of T1..T12 H' = H/(1-(Ti/(N3-N))) H' =96.62 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =96.62. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 156.8 144.1 146.2 144.6 145.3 198.4 197.5 283.9 139.5 139.5 avg Rbar (background) = 195.6 195.6 195.6 195.6 195.6 195.6 195.6 195.6 195.6 195.6 Dx = -38.8 -51.5 -49.4 -51.0 -50.3 2.8 2.0 88.4 -56.1 -56.1 Cx = 49.8 49.8 49.8 51.1 51.1 49.8 49.8 52.5 73.6 73.6 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------No -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Lead averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Lead (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 37 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Lead NC MCL (mg/l):15 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 740 10 4/28/03 300 10 10/30/03 640 5 4/20/04 250 5 10/21/04 430 5 4/18/05 380 5 10/13/05 290 5 4/25/06 300 10 10/20/06 89 5 4/25/07 69 10 10/31/07 123 5 4/23/08 50.2 5 10/20/08 25.9 5 4/22/09 NS 5 10/26/09 24.7 5 4/22/10 9.2 5 10/27/10 16 5 4/29/11 11 5 10/25/11 14.6 5 4/20/12 6.4 5 10/24/12 ND 5 4/24/13 10.4 5 10/24/13 ND 5 4/24/14 ND 5 10/27/14 ND 5 4/28/15 ND 5 10/27/15 ND 5 4/19/16 ND 5 If not detected (ND), use half of the detection limit. Xbar =140.62593 SD =206.77348 N =27 1/NSi(Xi-Xbar)3 =13139407 g1=1.5728123 Since the Coefficient of Skewness of 1.57 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =3.4172525 SD =2.0348566 N =27 1/NSi(Xi-Xbar)3 =0.9819207 g1=0.1233277 Pb (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 38 of 72 Since the Coefficient of Skewness of 0.12 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 5.9588727 = xmean (Mean of N1-N8 historical data) 0.394346 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 4.4886364 -3.7282898 0 5 4.5 4/25/07 4.2341065 -4.3737378 0 5 4.5 10/31/07 4.8121844 -2.9078226 0 5 4.5 4/23/08 3.916015 -5.1803681 0 5 4.5 10/20/08 3.254243 -6.8585187 0 5 4.5 10/26/09 3.2068032 -6.9788185 0 5 4.5 4/22/10 2.2192035 -9.4832172 0 5 4.5 10/27/10 2.7725887 -8.0799187 0 5 4.5 4/29/11 2.3978953 -9.0300828 0 5 4.5 10/25/11 2.6810215 -8.3121188 0 5 4.5 4/20/12 1.856298 -10.403489 0 5 4.5 10/24/12 0.9162907 -12.787201 0 5 4.5 4/24/13 2.3418058 -9.1723169 0 5 4.5 10/24/13 0.9162907 -12.787201 0 5 4.5 4/24/14 0.9162907 -12.787201 0 5 4.5 10/27/14 0.9162907 -12.787201 0 5 4.5 4/28/15 0.9162907 -12.787201 0 5 4.5 10/27/15 0.9162907 -12.787201 0 5 4.5 4/19/16 0.9162907 -12.787201 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. -14 -12 -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Pb (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 39 of 72 The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. Pb (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 40 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Nickel NC MCL (mg/l):100 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP 5 06/26/00 15 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 16 9.7 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP 50 04/09/01 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 74 ND NS ND ND ND 6 9 44 68 NS NP NP 5 09/26/02 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP 5 04/28/03 ND ND ND 90 ND ND ND ND ND 26 70 NP NP 5 10/30/03 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP 5 04/20/04 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP 5 10/21/04 12 ND ND 13 ND ND ND ND ND 35 160 NP NP 5 04/18/05 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP 5 10/13/05 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 88 NP NP 50 10/20/06 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP 5 04/25/07 ND ND ND ND ND 330 ND ND ND ND ND NP NP 50 10/31/07 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP 5 04/23/08 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP 5 10/20/08 23 ND 21 11.1 10.7 7.5 ND 14 ND ND 8.5 NP NP 5 04/22/09 5.6 7.2 19.7 16.7 10.9 6 5.1 14 6 ND NS NP NP 5 10/26/09 6.7 ND 5.2 6 18 7.5 NS NS NS 6 8.4 NP NP 5 04/22/10 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP 5 10/27/10 7 ND ND ND 7.4 ND 21.5 19 ND ND 7.5 10.8 ND 5 04/29/11 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND 5 10/25/11 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8 ND 5 04/20/12 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND 5 10/24/12 18.5 ND ND ND 10.1 8.9 20 25.3 ND ND ND 9.6 ND 5 04/24/13 10 ND ND ND 12 8.6 21.8 32.8 ND ND ND 9.2 ND 5 10/24/13 7.9 ND 8.3 ND 7.5 7 30.2 29.9 ND ND ND 12.1 ND 5 04/24/14 7 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND 5 10/27/14 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND 5 04/28/15 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 5 10/27/15 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND 5 04/19/16 7.2 ND ND 5.9 12.3 13.2 21.7 30.9 ND ND ND 10.6 ND 5 Ni 33 32 27 32 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)7691.5 3470.0 3998.5 6105.5 6081.5 5108.0 5450.5 7079.0 4048.5 5065.0 5449.0 2919.5 1079.5 avg rank value (Rbar)233.1 108.4 148.1 190.8 196.2 164.8 187.9 244.1 135.0 163.4 201.8 243.3 90.0 Number of each rank value Rank Value rank value of NDs =5 26 16 13 8 14 13 6 21 19 13 0 11 83 rank value of 5.1s =0 0 0 0 0 0 1 0 0 0 0 0 1 166.5 rank value of 5.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 168 rank value of 5.3s =0 0 0 0 1 0 0 0 2 0 0 0 0 170 rank value of 5.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 172 Nickel (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 41 of 72 rank value of 5.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 173 rank value of 5.6s =1 0 1 0 0 0 0 0 0 0 0 0 0 174.5 rank value of 5.7s =0 0 0 0 0 1 0 0 0 0 0 0 0 176 rank value of 5.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 177 rank value of 5.9s =0 0 0 1 0 0 0 0 0 1 0 0 0 178.5 rank value of 6s =0 0 0 1 0 1 0 0 1 1 0 0 0 181.5 rank value of 6.1s =0 0 0 0 0 0 0 1 0 1 0 0 0 184.5 rank value of 6.2s =0 0 0 0 1 0 1 0 0 0 0 0 0 186.5 rank value of 6.3s =1 0 0 1 0 0 0 0 0 0 0 0 0 188.5 rank value of 6.7s =1 0 0 0 0 0 0 0 1 0 0 0 0 190.5 rank value of 6.8s =0 1 0 1 1 0 0 0 0 0 0 0 0 193 rank value of 6.9s =1 0 0 1 1 0 0 0 0 0 0 0 0 196 rank value of 7s =2 0 0 0 0 1 0 0 0 0 0 0 0 199 rank value of 7.2s =1 2 0 0 0 0 0 0 0 0 0 0 0 202 rank value of 7.3s =1 0 0 0 1 0 0 0 0 0 0 0 0 204.5 rank value of 7.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 206 rank value of 7.5s =0 0 0 0 1 3 0 0 0 0 1 0 0 209 rank value of 7.6s =0 0 1 0 0 0 0 0 0 0 0 0 0 212 rank value of 7.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 213 rank value of 8s =0 0 1 0 0 0 0 0 0 0 0 1 0 214.5 rank value of 8.3s =0 0 2 0 0 1 0 0 0 0 0 1 0 217.5 rank value of 8.4s =0 0 0 1 0 0 0 0 0 0 1 0 0 220.5 rank value of 8.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 222 rank value of 8.6s =1 0 0 0 0 2 0 0 0 0 0 0 0 224 rank value of 8.7s =0 0 0 0 0 0 0 0 0 0 0 1 0 226 rank value of 8.8s =0 0 0 1 1 0 0 0 0 0 0 0 0 227.5 rank value of 8.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 229 rank value of 9.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 230 rank value of 9.2s =0 0 0 0 0 0 0 1 0 0 0 1 0 231.5 rank value of 9.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 233 rank value of 9.4s =0 0 0 0 1 1 0 0 0 0 0 0 0 234.5 rank value of 9.6s =0 2 0 1 0 0 0 0 0 0 0 1 0 237.5 rank value of 9.7s =0 1 0 0 0 0 0 0 0 0 0 0 0 240 rank value of 9.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 241 rank value of 10s =1 0 0 0 0 0 0 0 0 0 0 0 0 242 rank value of 10.1s =0 0 0 0 1 2 0 0 0 0 0 0 0 244 rank value of 10.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 246 rank value of 10.5s =0 0 0 0 1 0 0 0 0 0 0 0 0 247 rank value of 10.6s =0 0 0 0 0 0 0 0 0 0 0 1 0 248 rank value of 10.7s =0 0 0 0 2 0 0 0 0 0 0 0 0 249.5 rank value of 10.8s =0 0 0 0 1 0 0 0 0 0 0 1 0 251.5 rank value of 10.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 253 rank value of 11.1s =0 0 0 1 0 0 0 0 0 0 0 0 0 254 rank value of 11.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 255 rank value of 11.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 256 rank value of 11.7s =0 0 0 0 1 0 0 0 0 0 0 0 0 257 rank value of 12s =1 0 0 0 2 0 0 1 0 0 0 0 0 259.5 rank value of 12.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 262 rank value of 12.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 263 rank value of 12.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 264 rank value of 12.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 265 rank value of 12.6s =0 0 0 0 1 1 0 0 0 0 0 0 0 266.5 rank value of 12.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 268 rank value of 13s =0 0 0 1 0 0 0 0 1 0 0 0 0 269.5 rank value of 13.2s =0 0 0 0 0 1 0 0 0 0 0 0 0 271 rank value of 13.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 272 rank value of 14s =0 0 0 0 0 0 0 2 0 0 0 0 0 273.5 rank value of 14.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 275 rank value of 15s =2 0 0 0 0 0 0 0 0 0 0 0 0 276.5 rank value of 15.2s =0 0 0 0 0 0 0 1 0 0 0 0 0 278 rank value of 16s =2 0 0 0 0 0 0 0 0 0 0 0 0 279.5 Nickel (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 42 of 72 rank value of 16.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 281 rank value of 17s =0 0 1 1 0 0 0 0 0 0 0 0 0 282.5 rank value of 18s =0 0 0 0 1 0 0 1 0 0 0 0 0 284.5 rank value of 18.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 286 rank value of 19s =1 0 0 0 0 0 0 1 0 0 1 0 0 288 rank value of 19.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 290 rank value of 19.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 291 rank value of 19.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 292 rank value of 19.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 293 rank value of 20s =1 0 0 0 0 0 1 0 0 0 0 0 0 294.5 rank value of 20.2s =0 0 0 0 0 0 0 0 0 1 0 0 0 296 rank value of 20.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 297 rank value of 21s =0 0 1 0 0 0 0 0 0 0 0 0 0 298 rank value of 21.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 299 rank value of 21.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 300 rank value of 21.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 301 rank value of 21.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 302 rank value of 22s =1 0 0 0 0 0 0 0 0 1 0 0 0 303.5 rank value of 23s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 23.6s =0 0 0 0 0 0 1 0 0 0 0 0 0 306 rank value of 23.8s =0 0 0 0 0 0 1 0 0 0 0 0 0 307 rank value of 24s =1 0 0 0 0 0 0 1 0 0 1 0 0 309 rank value of 24.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 311 rank value of 24.6s =0 0 0 0 0 0 0 1 0 0 0 0 0 312 rank value of 25s =0 0 0 1 0 0 0 0 0 0 0 0 0 313 rank value of 25.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 314 rank value of 25.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 315 rank value of 26s =0 0 0 0 0 0 0 0 0 1 0 0 0 316 rank value of 27s =0 0 0 0 0 0 0 1 0 0 0 0 0 317 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 318 rank value of 29s =2 0 0 0 0 0 0 0 0 0 0 0 0 319.5 rank value of 29.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 321 rank value of 29.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 322 rank value of 30s =0 0 0 1 0 0 0 0 0 0 0 0 0 323 rank value of 30.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 324 rank value of 30.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 325 rank value of 31s =0 0 1 0 0 0 0 0 0 0 0 0 0 326 rank value of 31.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 327 rank value of 32.8s =0 0 0 0 0 0 0 1 0 0 0 0 0 328 rank value of 33.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 329 rank value of 33.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 330 rank value of 35s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 35.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 332 rank value of 36.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 333 rank value of 40s =0 0 0 0 0 0 0 0 1 0 0 0 0 334 rank value of 44s =0 0 0 0 0 0 0 0 1 0 0 0 0 335 rank value of 46s =0 0 0 0 0 0 0 0 0 1 0 0 0 336 rank value of 48s =0 0 0 0 0 0 0 0 1 0 0 0 0 337 rank value of 49s =0 0 0 0 0 0 0 0 0 1 0 0 0 338 rank value of 59s =0 0 0 0 0 0 0 0 0 1 0 0 0 339 rank value of 68s =0 0 0 0 0 0 0 0 0 1 0 0 0 340 rank value of 70s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 74s =1 0 0 0 0 0 0 0 0 0 0 0 0 342 rank value of 76s =1 0 0 0 0 0 0 0 0 0 0 0 0 343 rank value of 78s =0 0 0 0 0 0 0 0 0 1 0 0 0 344 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 345 rank value of 90s =0 0 0 1 0 0 0 0 0 0 0 0 0 346 rank value of 100s =0 0 0 0 0 0 0 0 0 0 1 0 0 347 rank value of 110s =0 0 0 0 0 0 0 0 0 0 1 0 0 348 rank value of 160s =0 0 0 1 0 0 0 0 0 0 1 0 0 349.5 rank value of 170s =0 0 0 0 0 0 0 0 0 0 1 0 0 351 Nickel (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 43 of 72 rank value of 190s =0 0 0 0 0 0 0 0 0 0 1 0 0 352 rank value of 330s =0 0 0 0 0 1 0 0 0 0 0 0 0 353 rank value of 400s =0 0 0 1 0 0 0 0 0 0 0 0 0 354 rank value of 430s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 rank value of 460s =0 0 0 1 0 0 0 0 0 0 0 0 0 356 n =33 32 27 32 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 2498104.3 1E+06 1E+06 841667 1E+06 2E+06 546345 827556 1E+06 710290 97110 Ni bg = 92 N = 356 H = 36.65 Adjust H for ties: Ti =4E+06 sum of T1..T41 H' = H/(1-(Ti/(N3-N))) H' =40.71 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =40.71. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D r MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 190.8 196.2 164.8 187.9 244.1 135.0 163.4 201.8 243.3 90.0 avg Rbar (background) = 164.8 164.8 164.8 164.8 164.8 164.8 164.8 164.8 164.8 164.8 Dx = 26.0 31.4 0.0 23.2 79.3 -29.8 -1.4 37.0 78.5 -74.8 Cx = 49.2 49.8 49.8 51.1 51.1 50.4 49.8 52.5 73.6 73.6 Statistical Significance ? No No No No Yes No No No Yes No If SSI, is current event above MCL?----No ---No - Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Nickel averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Nickel (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 44 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Nickel NC MCL (mg/l):100 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 3 D MD L 4/24/00 24 5 6/26/00 NS 5 7/26/00 NS 5 9/18/00 NS 50 4/9/01 18 5 9/18/01 NS 5 10/29/01 NS 5 1/30/02 NS 5 2/28/02 NS 50 4/15/02 9.2 5 9/26/02 27 5 4/28/03 ND 5 10/30/03 ND 5 4/20/04 12 5 10/21/04 ND 5 4/18/05 5.4 5 10/13/05 6.1 5 4/25/06 ND 50 10/20/06 ND 5 4/25/07 ND 50 10/31/07 9.8 5 4/23/08 11.3 5 10/20/08 14 5 4/22/09 14 5 10/26/09 NS 5 4/22/10 NS 5 10/27/10 19 5 4/29/11 15.2 5 10/25/11 19.9 5 4/20/12 24.6 5 10/24/12 25.3 5 4/24/13 32.8 5 10/24/13 29.9 5 4/24/14 33.9 5 10/27/14 31.4 5 4/28/15 35.4 5 10/27/15 33.4 5 4/19/16 30.9 5 If not detected (ND), use half of the detection limit. Xbar =18.706897 SD =10.902324 N =29 1/NSi(Xi-Xbar)3 =-97.02121 g1=0.0789168 Since the Coefficient of Skewness of 0.08 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the real detected values shown above. Xbar =2.6588212 SD =0.8692936 N =29 Ni (S-C) MW-3Dr 1957-55 White Oak GW Stats 1st 2016.xlsm Page 45 of 72 1/NSi(Xi-Xbar)3 =-0.612026 g1=0.9820429 Use the real values (not log-transformed) indicated in the previous section. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 12.2125 = xmean (Mean of N1-N8 historical data) 9.8794791 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 4/18/05 5.4 -0.6895606 0 5 4.5 10/13/05 6.1 -0.6187067 0 5 4.5 4/25/06 25 1.2943496 0.2943496 5 4.5 10/20/06 2.5 -0.9830984 0 5 4.5 4/25/07 25 1.2943496 0.2943496 5 4.5 10/31/07 9.8 -0.244193 0 5 4.5 4/23/08 11.3 -0.0923632 0 5 4.5 10/20/08 14 0.1809306 0 5 4.5 4/22/09 14 0.1809306 0 5 4.5 10/27/10 19 0.6870301 0 5 4.5 4/29/11 15.2 0.3023945 0 5 4.5 10/25/11 19.9 0.7781281 0 5 4.5 4/20/12 24.6 1.2538617 0.2538617 5 4.5 10/24/12 25.3 1.3247156 0.5785772 5 4.5 4/24/13 32.8 2.0838649 1.6624422 5 4.5 10/24/13 29.9 1.7903272 2.4527694 5 4.5 4/24/14 33.9 2.1952068 3.6479762 5 4.5 10/27/14 31.4 1.9421571 4.5901332 5 4.5 4/28/15 35.4 2.3470367 5.9371699 5 4.5 10/27/15 33.4 2.1445969 7.0817668 5 4.5 4/19/16 30.9 1.8915471 7.9733139 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. One, or both, of the control limits was exceeded. Therefore, there is statistically significant evidence of contamination in this well at the concentrations indicated above. -2 -1 0 1 2 3 4 5 6 7 8 9 1/ 1 4 / 0 4 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Ni (S-C) MW-3Dr 1957-55 White Oak GW Stats 1st 2016.xlsm Page 46 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Nickel NC MCL (mg/l):100 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 6 MD L 4/24/00 NP 5 6/26/00 NP 5 7/26/00 NP 5 9/18/00 NP 50 4/9/01 NP 5 9/18/01 NP 5 10/29/01 NP 5 1/30/02 NP 5 2/28/02 NP 50 4/15/02 NP 5 9/26/02 NP 5 4/28/03 NP 5 10/30/03 NP 5 4/20/04 NP 5 10/21/04 NP 5 4/18/05 NP 5 10/13/05 NP 5 4/25/06 NP 50 10/20/06 NP 5 4/25/07 NP 50 10/31/07 NP 5 4/23/08 NP 5 10/20/08 NP 5 4/22/09 NP 5 10/26/09 NP 5 4/22/10 NP 5 10/27/10 10.8 5 4/29/11 10.3 5 10/25/11 8 5 4/20/12 19.3 5 10/24/12 9.6 5 4/24/13 9.2 5 10/24/13 12.1 5 4/24/14 12.5 5 10/27/14 9.1 5 4/28/15 8.3 5 10/27/15 8.7 5 4/19/16 10.6 5 If not detected (ND), use half of the detection limit. Xbar =10.708333 SD =3.0512168 Ni (S-C) MW-16 1957-55 White Oak GW Stats 1st 2016.xlsm Page 47 of 72 N =12 1/NSi(Xi-Xbar)3 =49.30823 g1=1.977803 Since the Coefficient of Skewness of 1.98 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =2.3416537 SD =0.2396506 N =12 1/NSi(Xi-Xbar)3 =0.0172046 g1=1.4242707 Since the Coefficient of Skewness of 1.42 is greater than 1.0, the data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. A non-parametric testing procedure should be used on the data set. Ni (S-C) MW-16 1957-55 White Oak GW Stats 1st 2016.xlsm Page 48 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Nickel GA MCL (ug/l):100 Method:Kendall-Mann Non-Parametric Trend Test (Concentration vs. Time) Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 15 NS NS 17 12 8.3 ND 24 6.7 22 NS NP NP 5 06/26/00 15 ND NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 16 9.7 NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS 8.8 NT NS NS NS NT NS NS NP NP 50 04/09/01 76 7.2 NS 9.6 5.3 ND ND 18 28 6.1 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 74 ND NS ND ND ND 6.2 9.2 44 68 NS NP NP 5 09/26/02 16 6.8 31 400 ND ND ND 27 40 78 430 NP NP 5 04/28/03 ND ND ND 90 ND ND ND ND ND 26 70 NP NP 5 10/30/03 19 ND NT 6.9 6.9 ND ND ND 48 ND 190 NP NP 5 04/20/04 20 ND ND 30 7.3 ND ND 12 5.3 49 110 NP NP 5 10/21/04 12 ND ND 13 ND ND ND ND ND 35 160 NP NP 5 04/18/05 29 9.6 17 460 ND ND 5.5 5.4 ND 59 170 NP NP 5 10/13/05 29 ND ND 160 6.8 ND ND 6.1 ND 46 100 NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND 88 NP NP 50 10/20/06 22 ND 8.3 25 ND ND ND ND 13 ND 24 NP NP 5 04/25/07 ND ND ND ND ND 330 ND ND ND ND ND NP NP 50 10/31/07 24 ND 8 8.4 13.8 ND 5.8 9.8 ND 20.2 36.2 NP NP 5 04/23/08 7.3 ND 12.9 6.3 10.8 5.7 ND 11.3 5.3 ND 19 NP NP 5 10/20/08 23 ND 21 11.1 10.7 7.5 ND 14 ND ND 8.5 NP NP 5 04/22/09 5.6 7.2 19.7 16.7 10.9 6 5.1 14 6 ND NS NP NP 5 10/26/09 6.7 ND 5.2 6 18 7.5 NS NS NS 6 8.4 NP NP 5 04/22/10 8.6 9.6 7.6 ND 6.2 ND NS NS ND ND ND NP NP 5 10/27/10 7 ND ND ND 7.4 ND 21.5 19 ND ND 7.5 10.8 ND 5 04/29/11 ND ND ND ND 10.5 8.6 19.5 15.2 ND ND ND 10.3 ND 5 10/25/11 6.9 ND ND 14.7 8.8 7.5 20.8 19.9 ND ND ND 8 ND 5 04/20/12 12.2 ND ND ND 9.4 9.4 23.8 24.6 ND ND ND 19.3 ND 5 10/24/12 18.5 ND ND ND 10.1 8.9 20 25.3 ND ND ND 9.6 ND 5 04/24/13 10 ND ND ND 12 8.6 21.8 32.8 ND ND ND 9.2 ND 5 10/24/13 7.9 ND 8.3 ND 7.5 7 30.2 29.9 ND ND ND 12.1 ND 5 04/24/14 7 ND ND ND 9.3 10.1 23.6 33.9 ND ND ND 12.5 ND 5 10/27/14 ND ND ND ND 10.7 10.1 29.5 31.4 ND ND ND 9.1 ND 5 04/28/15 6.3 ND 5.6 6.8 11.7 11.2 25.1 35.4 ND ND ND 8.3 5.1 5 10/27/15 21.3 ND ND ND 12.6 12.6 24.4 33.4 ND 5.9 ND 8.7 ND 5 04/19/16 7.2 ND ND 5.9 12.3 13.2 21.7 30.9 ND ND ND 10.6 ND 5 If not detected (ND), use half of the detection limit. Trendline Slope =---------0.001 - Standard Deviation =--------3.0512 - number of observations n =--------12 - S =---------12 - uncorrected for ties t =---------0.18 - U =--------0 - corrected for ties t =---------0.18 - Concentration Trend --------de c r e a s e - Nickel (K-M Trend) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 49 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Selenium MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 ND NS NS ND ND ND ND ND ND ND NS NP NP 20 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 20 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 20 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 20 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 20 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 04/15/02 ND ND NS ND ND ND ND ND ND ND NS NP NP 20 09/26/02 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND 5 ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 20 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 12 ND ND ND ND 460 ND ND ND ND 18 NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 10 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 10 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 10 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 32. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 89 Tn1 = 507 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =89 Tn1 = 507 t [88,.01] =2.3751 c =0.0112 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 5 5 5 5 5 5 5 5 5 5 T*k =11.4 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Selenium (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 50 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Silver MCL (mg/l):20 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 3.7 NS NS ND ND ND 6.9 ND ND ND NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 ND ND NS ND ND ND ND ND ND ND NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 ND ND NS ND ND ND ND ND ND ND NS NP NP 2 09/26/02 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/28/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 2 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/13/05 2.9 ND ND ND ND ND ND ND ND ND ND NP NP 2 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 32. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 89 Tn1 = 198.6 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =89 Tn1 = 198.6 t [88,.01] =2.3751 c =0.0112 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =5.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Silver (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 51 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Thallium MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 2 NS NS ND 3 2 4 ND 2 5 NS NP NP 2 06/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 07/26/00 ND ND NS NS NS NS NS NS NS NS NS NP NP 2 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 20 04/09/01 40 ND NS ND ND ND ND ND ND ND NS NP NP 2 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 2 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 20 04/15/02 40 ND NS ND ND ND ND ND ND ND NS NP NP 2 09/26/02 ND ND ND ND ND ND ND ND ND ND 65 NP NP 2 04/28/03 ND ND ND 1.6 ND ND ND ND 1.4 ND 15 NP NP 1 10/30/03 ND ND NT ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 22 ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND 35 ND ND ND ND ND NP NP 5.5 10/31/07 11.6 ND ND ND ND ND ND ND ND 9.5 ND NP NP 5.5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5.5 10/20/08 7.2 ND ND ND ND ND ND 6.1 ND ND ND NP NP 5.4 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5.4 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5.4 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5.4 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/24/14 ND ND ND ND ND ND ND ND ND ND ND 5.6 ND 5.4 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5.4 04/19/16 ND ND ND ND ND ND ND ND ND ND ND 14.1 ND 5.4 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 32. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 89 Tn1 = 369.1 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =89 Tn1 = 369.1 t [88,.01] =2.3751 c =0.0112 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 14.1 2.7 T*k =9.0 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was exceeded in one, or more of the wells, Wilcoxon Rank Sum Tests must be performed to test the possibility that the detected concentrations are statistically significant. Thallium (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 52 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Thallium MCL (mg/l):Not Established Method:Wilcoxon Rank Sum Background:GWA-1,-2S, -2D, -3, -4, & -5 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 6 MD L 04/24/00 2 NS NS NP 2 06/26/00 ND ND NS NP 2 07/26/00 ND ND NS NP 2 09/18/00 NS NS NS NP 20 04/09/01 40 ND NS NP 2 09/18/01 NS NS NS NP 2 10/29/01 NS NS NS NP 2 01/30/02 NS NS NS NP 2 02/28/02 NS NS NS NP 20 04/15/02 40 ND NS NP 2 09/26/02 ND ND ND NP 2 04/28/03 ND ND ND NP 1 10/30/03 ND ND NT NP 10 04/20/04 ND ND ND NP 10 10/21/04 ND ND ND NP 10 04/18/05 ND ND ND NP 10 10/13/05 22 ND ND NP 10 04/25/06 ND ND ND NP 10 10/20/06 ND ND ND NP 10 04/25/07 ND ND ND NP 6 10/31/07 11.6 ND ND NP 6 04/23/08 ND ND ND NP 6 10/20/08 7.2 ND ND NP 5 04/22/09 ND ND ND NP 5 10/26/09 ND ND ND NP 5 04/22/10 ND ND ND NP 5 10/27/10 ND ND ND ND 5 04/29/11 ND ND ND ND 5 10/25/11 ND ND ND ND 5 04/20/12 ND ND ND ND 5 10/24/12 ND ND ND ND 5 04/24/13 ND ND ND ND 5 10/24/13 ND ND ND ND 5 04/24/14 ND ND ND 5.6 5 10/27/14 ND ND ND ND 5 04/28/15 ND ND ND ND 5 10/27/15 ND ND ND ND 5 04/19/16 ND ND ND 14.1 5 1) Rank the N = 104 observations from the smallest to the largest from background wells and compliance well MW-16. n =12 m =92 N =104 Ci (MW-16) =684.0 # samples =33 32 27 12 sum of rank values (Ri) =1914.5 1552.0 1309.5 684.0 avg rank value (Rbar) =58.0 48.5 48.5 57.0 Number of each rank value Rank Value rank value of NDs =27 32 27 10 48.5 rank value of 2s =1 0 0 0 97 rank value of 5.6s =0 0 0 1 98 rank value of 7.2s =1 0 0 0 99 rank value of 11.6s =1 0 0 0 100 rank value of 14.1s =0 0 0 1 101 Th (Wil 16) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 53 of 72 rank value of 22s =1 0 0 0 102 rank value of 40s =2 0 0 0 103.5 # samples =33 32 27 12 sum of rank values (Ri)1914.5 1552 1309.5 684 2) Compute the Wilcoxon statistic by adding up the compliance well ranks and subtracting n/(n+1)/2. W = Ci - 1/2(n(n+1)) W = 606 3) Compute the expected value and standard deviation of W. E(W) = 1/2mn SD(W) = ((mn(N+1)/12)*(1-Sg i=1 (ti 3 - ti)/(N3 - N)))0.5 E(W) = 552 Adjustment for tie values: SD(W) = 45.412 4) Form the appropriate Z-score. Z = (W - E(W) - 0.5)/SD(W) Z = 1.178 5) Compare the observed Z-score to the upper 0.01 percentile of the normal distribution. Z = 1.178 Z0.01 = 2.326 Since Z is smaller, there is not significant evidence of contamination at the compliance well at the 1 percent significance level. Th (Wil 16) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 54 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Vanadium NC MCL (mg/l):Not Established Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 17 NS NS 19 32 21 ND 29 8.9 78 NS NP NP 5 06/26/00 40 6.3 NS NS NS NS NS NS NS NS NS NP NP 5 07/26/00 45 ND NS NS NS NS NS NS NS NS NS NP NP 5 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 40 04/09/01 250 1.4 NS 13 19 9.3 ND 24 41 230 NS NP NP 5 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 5 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 40 04/15/02 240 ND NS ND ND 11 21 14 69 260 NS NP NP 5 09/26/02 58 16 44 640 ND ND ND 42 50 310 1000 NP NP 5 04/28/03 89 ND 9.6 170 6.8 6.8 ND ND 37 230 130 NP NP 5 10/30/03 54 ND NT 6.6 16 ND ND ND 92 14 200 NP NP 5 04/20/04 55 ND ND 45 25 ND ND 13 5.1 240 88 NP NP 5 10/21/04 41 ND ND 18 ND ND ND ND ND 160 210 NP NP 5 04/18/05 85 ND ND 680 5.4 ND ND ND ND 240 110 NP NP 5 10/13/05 82 ND ND 210 8.9 ND ND ND ND 170 82 NP NP 5 04/25/06 110 ND ND ND ND ND ND ND ND 120 85 NP NP 40 10/20/06 79 ND ND 28 ND ND ND ND 23 ND 30 NP NP 5 04/25/07 43 ND ND ND ND 300 ND ND ND ND 26 NP NP 25 10/31/07 89 ND 8.8 14.7 20 ND ND ND 8.6 103 48.2 NP NP 5 04/23/08 26.1 ND 11.4 9.7 10.1 ND ND 5.1 9.7 10 23.1 NP NP 5 10/20/08 79 ND 15.1 15.8 ND ND ND ND 5.4 ND 14.8 NP NP 5 04/22/09 16 ND 32.7 19.8 7.7 ND ND ND 13.3 ND NS NP NP 5 10/26/09 17.9 ND ND 5.3 33.6 ND NS NS NS 12.2 11.9 NP NP 5 04/22/10 27.9 ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 17.4 ND ND 6.9 ND ND 14.2 7.1 ND ND 5.9 ND ND 5 04/29/11 15.8 ND 5.1 ND ND ND ND ND ND ND 5.5 7.3 ND 5 10/25/11 25.6 ND ND 23 ND ND 15.1 ND ND 9.7 6.3 ND ND 5 04/20/12 44.3 ND ND ND ND ND 10 ND ND ND ND 15 ND 5 10/24/12 59 ND ND 5.9 ND ND ND ND ND ND ND ND ND 5 04/24/13 33.5 ND ND 7.7 9.6 ND ND ND ND ND 5.4 ND ND 5 10/24/13 30.4 ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 22.8 ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 15.5 ND ND 8 ND ND ND ND ND ND ND 7 ND 5 10/27/15 44.5 ND ND ND ND ND ND ND ND 7.4 ND 9.8 ND 5 04/19/16 21.6 ND ND 6.5 ND ND ND ND ND ND ND ND ND 5 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)9923.5 3832.0 3987.0 6849.5 5201.0 4158.0 3753.0 4231.0 5230.5 6620.0 6270.5 1844.0 1290.0 avg rank value (Rbar)300.7 119.8 147.7 221.0 167.8 134.1 129.4 145.9 174.4 213.5 232.2 153.7 107.5 Number of each rank value Rank Value rank value of NDs =1 29 20 10 19 26 25 22 18 15 9 8 12 107.5 rank value of 1.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 215 Vanadium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 55 of 72 rank value of 5.1s =0 0 1 0 0 0 0 1 1 0 0 0 0 217 rank value of 5.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 219 rank value of 5.4s =0 0 0 0 1 0 0 0 1 0 1 0 0 221 rank value of 5.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 223 rank value of 5.9s =0 0 0 1 0 0 0 0 0 0 1 0 0 224.5 rank value of 6.3s =0 1 0 0 0 0 0 0 0 0 1 0 0 226.5 rank value of 6.5s =0 0 0 1 0 0 0 0 0 0 0 0 0 228 rank value of 6.6s =0 0 0 1 0 0 0 0 0 0 0 0 0 229 rank value of 6.8s =0 0 0 0 1 1 0 0 0 0 0 0 0 230.5 rank value of 6.9s =0 0 0 1 0 0 0 0 0 0 0 0 0 232 rank value of 7s =0 0 0 0 0 0 0 0 0 0 0 1 0 233 rank value of 7.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 234 rank value of 7.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 235 rank value of 7.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 236 rank value of 7.7s =0 0 0 1 1 0 0 0 0 0 0 0 0 237.5 rank value of 8s =0 0 0 1 0 0 0 0 0 0 0 0 0 239 rank value of 8.6s =0 0 0 0 0 0 0 0 1 0 0 0 0 240 rank value of 8.8s =0 0 1 0 0 0 0 0 0 0 0 0 0 241 rank value of 8.9s =0 0 0 0 1 0 0 0 1 0 0 0 0 242.5 rank value of 9.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 244 rank value of 9.6s =0 0 1 0 1 0 0 0 0 0 0 0 0 245.5 rank value of 9.7s =0 0 0 1 0 0 0 0 1 1 0 0 0 248 rank value of 9.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 250 rank value of 10s =0 0 0 0 0 0 1 0 0 1 0 0 0 251.5 rank value of 10.1s =0 0 0 0 1 0 0 0 0 0 0 0 0 253 rank value of 11s =0 0 0 0 0 1 0 0 0 0 0 0 0 254 rank value of 11.4s =0 0 1 0 0 0 0 0 0 0 0 0 0 255 rank value of 11.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 256 rank value of 12.2s =0 0 0 0 0 0 0 0 0 1 0 0 0 257 rank value of 13s =0 0 0 1 0 0 0 1 0 0 0 0 0 258.5 rank value of 13.3s =0 0 0 0 0 0 0 0 1 0 0 0 0 260 rank value of 14s =0 0 0 0 0 0 0 1 0 1 0 0 0 261.5 rank value of 14.2s =0 0 0 0 0 0 1 0 0 0 0 0 0 263 rank value of 14.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 264 rank value of 14.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 265 rank value of 15s =0 0 0 0 0 0 0 0 0 0 0 1 0 266 rank value of 15.1s =0 0 1 0 0 0 1 0 0 0 0 0 0 267.5 rank value of 15.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 269 rank value of 15.8s =1 0 0 1 0 0 0 0 0 0 0 0 0 270.5 rank value of 16s =1 1 0 0 1 0 0 0 0 0 0 0 0 273 rank value of 17s =1 0 0 0 0 0 0 0 0 0 0 0 0 275 rank value of 17.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 276 rank value of 17.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 277 rank value of 18s =0 0 0 1 0 0 0 0 0 0 0 0 0 278 rank value of 19s =0 0 0 1 1 0 0 0 0 0 0 0 0 279.5 rank value of 19.8s =0 0 0 1 0 0 0 0 0 0 0 0 0 281 rank value of 20s =0 0 0 0 1 0 0 0 0 0 0 0 0 282 rank value of 21s =0 0 0 0 0 1 1 0 0 0 0 0 0 283.5 rank value of 21.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 285 rank value of 22.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 286 rank value of 23s =0 0 0 1 0 0 0 0 1 0 0 0 0 287.5 rank value of 23.1s =0 0 0 0 0 0 0 0 0 0 1 0 0 289 rank value of 24s =0 0 0 0 0 0 0 1 0 0 0 0 0 290 rank value of 25s =0 0 0 0 1 0 0 0 0 0 0 0 0 291 rank value of 25.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 292 rank value of 26s =0 0 0 0 0 0 0 0 0 0 1 0 0 293 rank value of 26.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 294 rank value of 27.9s =1 0 0 0 0 0 0 0 0 0 0 0 0 295 Vanadium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 56 of 72 rank value of 28s =0 0 0 1 0 0 0 0 0 0 0 0 0 296 rank value of 29s =0 0 0 0 0 0 0 1 0 0 0 0 0 297 rank value of 30s =0 0 0 0 0 0 0 0 0 0 1 0 0 298 rank value of 30.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 299 rank value of 32s =0 0 0 0 1 0 0 0 0 0 0 0 0 300 rank value of 32.7s =0 0 1 0 0 0 0 0 0 0 0 0 0 301 rank value of 33.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 302 rank value of 33.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 303 rank value of 37s =0 0 0 0 0 0 0 0 1 0 0 0 0 304 rank value of 40s =1 0 0 0 0 0 0 0 0 0 0 0 0 305 rank value of 41s =1 0 0 0 0 0 0 0 1 0 0 0 0 306.5 rank value of 42s =0 0 0 0 0 0 0 1 0 0 0 0 0 308 rank value of 43s =1 0 0 0 0 0 0 0 0 0 0 0 0 309 rank value of 44s =0 0 1 0 0 0 0 0 0 0 0 0 0 310 rank value of 44.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 311 rank value of 44.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 312 rank value of 45s =1 0 0 1 0 0 0 0 0 0 0 0 0 313.5 rank value of 48.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 315 rank value of 50s =0 0 0 0 0 0 0 0 1 0 0 0 0 316 rank value of 54s =1 0 0 0 0 0 0 0 0 0 0 0 0 317 rank value of 55s =1 0 0 0 0 0 0 0 0 0 0 0 0 318 rank value of 58s =1 0 0 0 0 0 0 0 0 0 0 0 0 319 rank value of 59s =1 0 0 0 0 0 0 0 0 0 0 0 0 320 rank value of 69s =0 0 0 0 0 0 0 0 1 0 0 0 0 321 rank value of 78s =0 0 0 0 0 0 0 0 0 1 0 0 0 322 rank value of 79s =2 0 0 0 0 0 0 0 0 0 0 0 0 323.5 rank value of 82s =1 0 0 0 0 0 0 0 0 0 1 0 0 325.5 rank value of 85s =1 0 0 0 0 0 0 0 0 0 1 0 0 327.5 rank value of 88s =0 0 0 0 0 0 0 0 0 0 1 0 0 329 rank value of 89s =2 0 0 0 0 0 0 0 0 0 0 0 0 330.5 rank value of 92s =0 0 0 0 0 0 0 0 1 0 0 0 0 332 rank value of 103s =0 0 0 0 0 0 0 0 0 1 0 0 0 333 rank value of 110s =1 0 0 0 0 0 0 0 0 0 1 0 0 334.5 rank value of 120s =0 0 0 0 0 0 0 0 0 1 0 0 0 336 rank value of 130s =0 0 0 0 0 0 0 0 0 0 1 0 0 337 rank value of 160s =0 0 0 0 0 0 0 0 0 1 0 0 0 338 rank value of 170s =0 0 0 1 0 0 0 0 0 1 0 0 0 339.5 rank value of 200s =0 0 0 0 0 0 0 0 0 0 1 0 0 341 rank value of 210s =0 0 0 1 0 0 0 0 0 0 1 0 0 342.5 rank value of 230s =0 0 0 0 0 0 0 0 0 2 0 0 0 344.5 rank value of 240s =1 0 0 0 0 0 0 0 0 2 0 0 0 347 rank value of 250s =1 0 0 0 0 0 0 0 0 0 0 0 0 349 rank value of 260s =0 0 0 0 0 0 0 0 0 1 0 0 0 350 rank value of 300s =0 0 0 0 0 1 0 0 0 0 0 0 0 351 rank value of 310s =0 0 0 0 0 0 0 0 0 1 0 0 0 352 rank value of 640s =0 0 0 1 0 0 0 0 0 0 0 0 0 353 rank value of 680s =0 0 0 1 0 0 0 0 0 0 0 0 0 354 rank value of 1000s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Vanadium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 57 of 72 Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3421699.0 2E+06 872594 557709 485690 617288 911938 1E+06 1E+06 283361 138675 Ni bg = 92 N = 355 H = 40.31 Adjust H for ties: Ti =1E+07 sum of T1..T30 H' = H/(1-(Ti/(N3-N))) H' =51.61 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =51.61. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 221.0 167.8 134.1 129.4 145.9 174.4 213.5 232.2 153.7 107.5 avg Rbar (background) = 192.9 192.9 192.9 192.9 192.9 192.9 192.9 192.9 192.9 192.9 Dx = 28.1 -25.1 -58.7 -63.4 -47.0 -18.5 20.7 39.4 -39.2 -85.4 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No No No No If SSI, is current event above MCL?---------- Compare each difference (Dx) with the corresponding critical value (Cx). No compliance well's difference between average ranks exceeded its corresponding critical value at a 5% significance level. Therefore, we conclude that significant evidence of contamination does not exist at the 5% significance level. Vanadium (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 58 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Zinc NC MCL (mg/l):1000 Method:Kruskal-Wallis Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 150 NS NS 35 48 36 12 43 28 68 NS NP NP 10 06/26/00 37 12 NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 65 66 NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 50 04/09/01 230 130 NS 12 24 18 17 33 75 200 NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 50 04/15/02 230 16 NS ND ND 13 33 38 120 230 NS NP NP 10 09/26/02 57 120 110 580 ND 20 ND 56 250 280 4800 NP NP 10 04/28/03 86 14 31 160 16 ND ND ND 81 190 800 NP NP 10 10/30/03 55 22 NT 17 26 10 ND ND 140 26 1800 NP NP 10 04/20/04 55 10 ND 44 30 11 14 19 23 220 770 NP NP 10 10/21/04 29 ND ND 17 ND 14 ND 12 15 70 1200 NP NP 10 04/18/05 83 ND ND 780 ND 30 13 10 ND 240 1200 NP NP 10 10/13/05 92 13 12 230 19 25 ND ND 14 170 800 NP NP 10 04/25/06 130 ND 88 ND ND ND ND ND 110 120 780 NP NP 50 10/20/06 74 ND 20 37 ND ND ND ND 55 ND 200 NP NP 10 04/25/07 55 21 30 30 22 830 22 15 10 12 200 NP NP 10 10/31/07 86 ND 66.2 14 37.4 33.3 12 ND 11.6 91.1 336 NP NP 10 04/23/08 27.3 ND 50.3 12.2 24.4 36.9 ND 10.3 17.5 38.8 138 NP NP 10 10/20/08 66.5 19.9 59.2 15.3 10.6 29.1 ND 12.4 ND 17.4 71.5 NP NP 10 04/22/09 23.1 43.5 99.9 25.3 17.9 17.6 10.5 ND 35.2 ND NS NP NP 10 10/26/09 19.6 ND 14.8 ND 37.8 ND NS NS NS ND 63.8 NP NP 10 04/22/10 22.2 14.2 ND ND ND ND NS NS ND ND 24.6 NP NP 10 10/27/10 19.1 ND 12.3 15 ND ND 32.4 16.3 ND ND 60.7 ND ND 10 04/29/11 25.7 ND 21.9 ND 11.8 23.9 13.7 ND ND ND 42.9 20.5 21.5 10 10/25/11 34.5 ND 11.6 23.7 12.8 10.1 32.5 ND ND 17.7 49.9 15.1 ND 10 04/20/12 47.6 ND 12.5 ND 11.6 10.1 21.1 ND ND 11.1 30.7 50.8 ND 10 10/24/12 93.4 10.4 11.3 22.4 23.8 ND 10.3 16.1 14.9 12.2 15.7 15.8 ND 10 04/24/13 56.3 ND ND ND 18.6 14.9 ND ND ND ND 33.2 ND ND 10 10/24/13 30.6 ND ND ND ND ND 28.1 ND ND 28.8 39.6 14.9 ND 10 04/24/14 25.8 ND ND ND ND ND 18.9 ND ND ND ND 14.9 10.1 10 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 10 04/28/15 51.7 ND 14.2 19 13.6 ND 14.8 12.9 ND ND 11.3 13.3 ND 10 10/27/15 69.8 ND ND ND 14.3 ND ND 11.8 ND 22.1 ND 36.4 ND 10 04/19/16 21.9 ND ND ND ND ND ND ND ND ND ND ND ND 10 Ni 33 32 27 31 31 31 29 29 30 31 27 12 12 sum of rank values (Ri)9168.0 4338.0 4679.5 5514.5 4956.0 4815.0 4149.5 3915.0 5016.0 6272.5 7295.0 2012.0 1059.0 avg rank value (Rbar)277.8 135.6 173.3 177.9 159.9 155.3 143.1 135.0 167.2 202.3 270.2 167.7 88.3 Number of each rank value Rank Value rank value of NDs =1 18 10 12 12 13 13 15 14 11 4 4 10 69 rank value of 10s =0 1 0 0 0 1 0 1 1 0 0 0 0 139.5 Zinc (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 59 of 72 rank value of 10.1s =0 0 0 0 0 2 0 0 0 0 0 0 1 143 rank value of 10.3s =0 0 0 0 0 0 1 1 0 0 0 0 0 145.5 rank value of 10.4s =0 1 0 0 0 0 0 0 0 0 0 0 0 147 rank value of 10.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 148 rank value of 10.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 149 rank value of 11s =0 0 0 0 0 1 0 0 0 0 0 0 0 150 rank value of 11.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 151 rank value of 11.3s =0 0 1 0 0 0 0 0 0 0 1 0 0 152.5 rank value of 11.6s =0 0 1 0 1 0 0 0 1 0 0 0 0 155 rank value of 11.8s =0 0 0 0 1 0 0 1 0 0 0 0 0 157.5 rank value of 12s =0 1 1 1 0 0 2 1 0 1 0 0 0 162 rank value of 12.2s =0 0 0 1 0 0 0 0 0 1 0 0 0 166.5 rank value of 12.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 168 rank value of 12.4s =0 0 0 0 0 0 0 1 0 0 0 0 0 169 rank value of 12.5s =0 0 1 0 0 0 0 0 0 0 0 0 0 170 rank value of 12.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 171 rank value of 12.9s =0 0 0 0 0 0 0 1 0 0 0 0 0 172 rank value of 13s =0 1 0 0 0 1 1 0 0 0 0 0 0 174 rank value of 13.3s =0 0 0 0 0 0 0 0 0 0 0 1 0 176 rank value of 13.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 177 rank value of 13.7s =0 0 0 0 0 0 1 0 0 0 0 0 0 178 rank value of 14s =0 1 0 1 0 1 1 0 1 0 0 0 0 181 rank value of 14.2s =0 1 1 0 0 0 0 0 0 0 0 0 0 184.5 rank value of 14.3s =0 0 0 0 1 0 0 0 0 0 0 0 0 186 rank value of 14.8s =0 0 1 0 0 0 1 0 0 0 0 0 0 187.5 rank value of 14.9s =0 0 0 0 0 1 0 0 1 0 0 2 0 190.5 rank value of 15s =0 0 0 1 0 0 0 1 1 0 0 0 0 194 rank value of 15.1s =0 0 0 0 0 0 0 0 0 0 0 1 0 196 rank value of 15.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 197 rank value of 15.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 198 rank value of 15.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 199 rank value of 16s =0 1 0 0 1 0 0 0 0 0 0 0 0 200.5 rank value of 16.1s =0 0 0 0 0 0 0 1 0 0 0 0 0 202 rank value of 16.3s =0 0 0 0 0 0 0 1 0 0 0 0 0 203 rank value of 17s =0 0 0 2 0 0 1 0 0 0 0 0 0 205 rank value of 17.4s =0 0 0 0 0 0 0 0 0 1 0 0 0 207 rank value of 17.5s =0 0 0 0 0 0 0 0 1 0 0 0 0 208 rank value of 17.6s =0 0 0 0 0 1 0 0 0 0 0 0 0 209 rank value of 17.7s =0 0 0 0 0 0 0 0 0 1 0 0 0 210 rank value of 17.9s =0 0 0 0 1 0 0 0 0 0 0 0 0 211 rank value of 18s =0 0 0 0 0 1 0 0 0 0 0 0 0 212 rank value of 18.6s =0 0 0 0 1 0 0 0 0 0 0 0 0 213 rank value of 18.9s =0 0 0 0 0 0 1 0 0 0 0 0 0 214 rank value of 19s =0 0 0 1 1 0 0 1 0 0 0 0 0 216 rank value of 19.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 218 rank value of 19.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 219 rank value of 19.9s =0 1 0 0 0 0 0 0 0 0 0 0 0 220 rank value of 20s =0 0 1 0 0 1 0 0 0 0 0 0 0 221.5 rank value of 20.5s =0 0 0 0 0 0 0 0 0 0 0 1 0 223 rank value of 21s =0 1 0 0 0 0 0 0 0 0 0 0 0 224 rank value of 21.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 225 rank value of 21.5s =0 0 0 0 0 0 0 0 0 0 0 0 1 226 rank value of 21.9s =1 0 1 0 0 0 0 0 0 0 0 0 0 227.5 rank value of 22s =0 1 0 0 1 0 1 0 0 0 0 0 0 230 rank value of 22.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 232 rank value of 22.2s =1 0 0 0 0 0 0 0 0 0 0 0 0 233 rank value of 22.4s =0 0 0 1 0 0 0 0 0 0 0 0 0 234 rank value of 23s =0 0 0 0 0 0 0 0 1 0 0 0 0 235 Zinc (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 60 of 72 rank value of 23.1s =1 0 0 0 0 0 0 0 0 0 0 0 0 236 rank value of 23.7s =0 0 0 1 0 0 0 0 0 0 0 0 0 237 rank value of 23.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 238 rank value of 23.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 239 rank value of 24s =0 0 0 0 1 0 0 0 0 0 0 0 0 240 rank value of 24.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 241 rank value of 24.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 242 rank value of 25s =0 0 0 0 0 1 0 0 0 0 0 0 0 243 rank value of 25.3s =0 0 0 1 0 0 0 0 0 0 0 0 0 244 rank value of 25.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 245 rank value of 25.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 246 rank value of 26s =0 0 0 0 1 0 0 0 0 1 0 0 0 247.5 rank value of 27.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 249 rank value of 28s =0 0 0 0 0 0 0 0 1 0 0 0 0 250 rank value of 28.1s =0 0 0 0 0 0 1 0 0 0 0 0 0 251 rank value of 28.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 252 rank value of 29s =1 0 0 0 0 0 0 0 0 0 0 0 0 253 rank value of 29.1s =0 0 0 0 0 1 0 0 0 0 0 0 0 254 rank value of 30s =0 0 1 1 1 1 0 0 0 0 0 0 0 256.5 rank value of 30.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 259 rank value of 30.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 260 rank value of 31s =0 0 1 0 0 0 0 0 0 0 0 0 0 261 rank value of 32.4s =0 0 0 0 0 0 1 0 0 0 0 0 0 262 rank value of 32.5s =0 0 0 0 0 0 1 0 0 0 0 0 0 263 rank value of 33s =0 0 0 0 0 0 1 1 0 0 0 0 0 264.5 rank value of 33.2s =0 0 0 0 0 0 0 0 0 0 1 0 0 266 rank value of 33.3s =0 0 0 0 0 1 0 0 0 0 0 0 0 267 rank value of 34.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 268 rank value of 35s =0 0 0 1 0 0 0 0 0 0 0 0 0 269 rank value of 35.2s =0 0 0 0 0 0 0 0 1 0 0 0 0 270 rank value of 36s =0 0 0 0 0 1 0 0 0 0 0 0 0 271 rank value of 36.4s =0 0 0 0 0 0 0 0 0 0 0 1 0 272 rank value of 36.9s =0 0 0 0 0 1 0 0 0 0 0 0 0 273 rank value of 37s =1 0 0 1 0 0 0 0 0 0 0 0 0 274.5 rank value of 37.4s =0 0 0 0 1 0 0 0 0 0 0 0 0 276 rank value of 37.8s =0 0 0 0 1 0 0 0 0 0 0 0 0 277 rank value of 38s =0 0 0 0 0 0 0 1 0 0 0 0 0 278 rank value of 38.8s =0 0 0 0 0 0 0 0 0 1 0 0 0 279 rank value of 39.6s =0 0 0 0 0 0 0 0 0 0 1 0 0 280 rank value of 42.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 281 rank value of 43s =0 0 0 0 0 0 0 1 0 0 0 0 0 282 rank value of 43.5s =0 1 0 0 0 0 0 0 0 0 0 0 0 283 rank value of 44s =0 0 0 1 0 0 0 0 0 0 0 0 0 284 rank value of 47.6s =1 0 0 0 0 0 0 0 0 0 0 0 0 285 rank value of 48s =0 0 0 0 1 0 0 0 0 0 0 0 0 286 rank value of 49.9s =0 0 0 0 0 0 0 0 0 0 1 0 0 287 rank value of 50.3s =0 0 1 0 0 0 0 0 0 0 0 0 0 288 rank value of 50.8s =0 0 0 0 0 0 0 0 0 0 0 1 0 289 rank value of 51.7s =1 0 0 0 0 0 0 0 0 0 0 0 0 290 rank value of 55s =3 0 0 0 0 0 0 0 1 0 0 0 0 292.5 rank value of 56s =0 0 0 0 0 0 0 1 0 0 0 0 0 295 rank value of 56.3s =1 0 0 0 0 0 0 0 0 0 0 0 0 296 rank value of 57s =1 0 0 0 0 0 0 0 0 0 0 0 0 297 rank value of 59.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 298 rank value of 60.7s =0 0 0 0 0 0 0 0 0 0 1 0 0 299 rank value of 63.8s =0 0 0 0 0 0 0 0 0 0 1 0 0 300 rank value of 65s =1 0 0 0 0 0 0 0 0 0 0 0 0 301 rank value of 66s =0 1 0 0 0 0 0 0 0 0 0 0 0 302 Zinc (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 61 of 72 rank value of 66.2s =0 0 1 0 0 0 0 0 0 0 0 0 0 303 rank value of 66.5s =1 0 0 0 0 0 0 0 0 0 0 0 0 304 rank value of 68s =0 0 0 0 0 0 0 0 0 1 0 0 0 305 rank value of 69.8s =1 0 0 0 0 0 0 0 0 0 0 0 0 306 rank value of 70s =0 0 0 0 0 0 0 0 0 1 0 0 0 307 rank value of 71.5s =0 0 0 0 0 0 0 0 0 0 1 0 0 308 rank value of 74s =1 0 0 0 0 0 0 0 0 0 0 0 0 309 rank value of 75s =0 0 0 0 0 0 0 0 1 0 0 0 0 310 rank value of 81s =0 0 0 0 0 0 0 0 1 0 0 0 0 311 rank value of 83s =1 0 0 0 0 0 0 0 0 0 0 0 0 312 rank value of 86s =2 0 0 0 0 0 0 0 0 0 0 0 0 313.5 rank value of 88s =0 0 1 0 0 0 0 0 0 0 0 0 0 315 rank value of 91.1s =0 0 0 0 0 0 0 0 0 1 0 0 0 316 rank value of 92s =1 0 0 0 0 0 0 0 0 0 0 0 0 317 rank value of 93.4s =1 0 0 0 0 0 0 0 0 0 0 0 0 318 rank value of 99.9s =0 0 1 0 0 0 0 0 0 0 0 0 0 319 rank value of 110s =0 0 1 0 0 0 0 0 1 0 0 0 0 320.5 rank value of 120s =0 1 0 0 0 0 0 0 1 1 0 0 0 323 rank value of 130s =1 1 0 0 0 0 0 0 0 0 0 0 0 325.5 rank value of 138s =0 0 0 0 0 0 0 0 0 0 1 0 0 327 rank value of 140s =0 0 0 0 0 0 0 0 1 0 0 0 0 328 rank value of 150s =1 0 0 0 0 0 0 0 0 0 0 0 0 329 rank value of 160s =0 0 0 1 0 0 0 0 0 0 0 0 0 330 rank value of 170s =0 0 0 0 0 0 0 0 0 1 0 0 0 331 rank value of 190s =0 0 0 0 0 0 0 0 0 1 0 0 0 332 rank value of 200s =0 0 0 0 0 0 0 0 0 1 2 0 0 334 rank value of 220s =0 0 0 0 0 0 0 0 0 1 0 0 0 336 rank value of 230s =2 0 0 1 0 0 0 0 0 1 0 0 0 338.5 rank value of 240s =0 0 0 0 0 0 0 0 0 1 0 0 0 341 rank value of 250s =0 0 0 0 0 0 0 0 1 0 0 0 0 342 rank value of 280s =0 0 0 0 0 0 0 0 0 1 0 0 0 343 rank value of 336s =0 0 0 0 0 0 0 0 0 0 1 0 0 344 rank value of 580s =0 0 0 1 0 0 0 0 0 0 0 0 0 345 rank value of 770s =0 0 0 0 0 0 0 0 0 0 1 0 0 346 rank value of 780s =0 0 0 1 0 0 0 0 0 0 1 0 0 347.5 rank value of 800s =0 0 0 0 0 0 0 0 0 0 2 0 0 349.5 rank value of 830s =0 0 0 0 0 1 0 0 0 0 0 0 0 351 rank value of 1200s =0 0 0 0 0 0 0 0 0 0 2 0 0 352.5 rank value of 1800s =0 0 0 0 0 0 0 0 0 0 1 0 0 354 rank value of 4800s =0 0 0 0 0 0 0 0 0 0 1 0 0 355 n =33 32 27 31 31 31 29 29 30 31 27 12 12 Compute the Kruskal-Wallis statistic: H = {[12/N(N+1)] * [ SK i=1 (Ri 2)/Ni]} -3(N+1) Well = Background MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Ri2/Ni = 3594700.1 980958 792321 747878 593736 528525 838675 1E+06 2E+06 337345 93457 Ni bg = 92 N = 355 H = 47.47 Adjust H for ties: Ti =3E+06 sum of T1..T35 Zinc (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 62 of 72 H' = H/(1-(Ti/(N3-N))) H' =50.37 Chi-square =18.31 Compare the calculated value H' to the tabulated Chi-square value with K-1 = # groups -1 = 17df at the 5% significance level from Table 1 of the IFG. The value is 18.31 which is less than H' =50.37. Therefore, there is evidence of significant differences between the well groups. Post-hoc pairwise comparisons are necessary (see below). Calculate the critical values to compare each compliance well to the background wells: Critical Value (Cx) = P(N(N+1)/12)0.5 * (1/Ni bg+1/Nx)0.5 P =2.33 Percentile of Standard Normal Distribution from Table 4 of IFG N =total sample size Ni bg =total samples (Ni) of background data Nx =total samples (Ni) of well x Difference between average ranks (Dx) = Rbar (well x) - avg Rbar (background) Well =MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Rbar (well x) = 177.9 159.9 155.3 143.1 135.0 167.2 202.3 270.2 167.7 88.3 avg Rbar (background) = 197.7 197.7 197.7 197.7 197.7 197.7 197.7 197.7 197.7 197.7 Dx = -19.8 -37.8 -42.3 -54.6 -62.7 -30.5 4.7 72.5 -30.0 -109.4 Cx = 49.7 49.7 49.7 50.9 50.9 50.3 49.7 52.3 73.4 73.4 Statistical Significance ? No No No No No No No Yes No No If SSI, is current event above MCL?-------No -- Compare each difference (Dx) with the corresponding critical value (Cx). The Dx value for the above indicated wells do exceed the corresponding Cx value. Therefore, we conclude that the concentration of Total Zinc averaged over these compliance wells are significantly greater than that of the background wells. Shewart-CUSUM Control Charts should be performed for each failing well to check for statistical significance. Zinc (K-W) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 63 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Total Zinc NC MCL (mg/l):1000 Method:Shewhart-CUSUM Control Chart Part 1: Check for Normality MW - 1 5 MD L 9/26/02 4800 10 4/28/03 800 10 10/30/03 1800 10 4/20/04 770 10 10/21/04 1200 10 4/18/05 1200 10 10/13/05 800 10 4/25/06 780 50 10/20/06 200 10 4/25/07 200 10 10/31/07 336 10 4/23/08 138 10 10/20/08 71.5 10 4/22/09 NS 10 10/26/09 63.8 10 4/22/10 24.6 10 10/27/10 60.7 10 4/29/11 42.9 10 10/25/11 49.9 10 4/20/12 30.7 10 10/24/12 15.7 10 4/24/13 33.2 10 10/24/13 39.6 10 4/24/14 ND 10 10/27/14 ND 10 4/28/15 11.3 10 10/27/15 ND 10 4/19/16 ND 10 If not detected (ND), use half of the detection limit. Xbar =499.5518519 SD =983.2681849 N =27 1/NSi(Xi-Xbar)3 =2994624903 g1=3.33358931 Since the Coefficient of Skewness of 3.33 is greater than 1.0, the real data appear to be significantly skewed. Do not assume that the data follow a Normal distribution. Perform the Skewness Test on the natural log of the values. Xbar =4.584920912 SD =2.024129921 N =27 1/NSi(Xi-Xbar)3 =0.924717573 g1=0.117999341 Zn (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 64 of 72 Since the Coefficient of Skewness of 0.12 is less than 1.0, the data appear not to be significantly skewed. Proceed with further statistical tests using the log-transformed values shown above. Part 2: Shewhart-CUSUM Control Chart Compute the mean and standard deviation of the historical data: 7.103371838 = xmean (Mean of N1-N8 historical data) 0.63200761 = s (Standard Deviation of N1-N8 historical data) 1 = k (constant, reference value) 5 = h (constant, upper control limit for the CUSUM scheme) 4.5 = SCL (Constant, upper Shewhart Control Limit) Compute the standardized mean (Zi) and the cumulative sum (Si) for each concentration. Date xi Zi Si h SCL 0 10/20/06 5.298317367 -2.8560645 0 5 4.5 4/25/07 5.298317367 -2.8560645 0 5 4.5 10/31/07 5.81711116 -2.0351981 0 5 4.5 4/23/08 4.927253685 -3.4431835 0 5 4.5 10/20/08 4.26969745 -4.483608 0 5 4.5 10/26/09 4.15575319 -4.6638974 0 5 4.5 4/22/10 3.202746443 -6.1718013 0 5 4.5 10/27/10 4.105943698 -4.7427089 0 5 4.5 4/29/11 3.758871826 -5.2918667 0 5 4.5 10/25/11 3.910021003 -5.0527095 0 5 4.5 4/20/12 3.424262655 -5.8213052 0 5 4.5 10/24/12 2.753660712 -6.8823714 0 5 4.5 4/24/13 3.502549876 -5.6974345 0 5 4.5 10/24/13 3.678829118 -5.418515 0 5 4.5 4/24/14 1.609437912 -8.6928288 0 5 4.5 10/27/14 1.609437912 -8.6928288 0 5 4.5 4/28/15 2.424802726 -7.4027101 0 5 4.5 10/27/15 1.609437912 -8.6928288 0 5 4.5 4/19/16 1.609437912 -8.6928288 0 5 4.5 Plot Zi and Si versus time: Compare the Zi and Si values to their respective control limits of SCL and h. -10 -8 -6 -4 -2 0 2 4 6 5/ 2 8 / 0 5 10 / 1 0 / 0 6 2/ 2 2 / 0 8 7/ 6 / 0 9 11 / 1 8 / 1 0 4/ 1 / 1 2 8/ 1 4 / 1 3 12 / 2 7 / 1 4 5/ 1 0 / 1 6 9/ 2 2 / 1 7 St a n d a r d i z e d U n i t s Combined Shewart-CUSUM Control Chart Zi SCL Si h Zn (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 65 of 72 The limits were not exceeded and do not indicate statistically significant evidence of contamination at the site. Zn (S-C MW-15) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 66 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Acetone MCL (mg/l):6000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 25 10/20/08 ND ND ND ND ND ND ND ND ND ND 140 NP NP 25 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 25 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 25 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 25 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 25 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 870 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 870 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 T*k =19.8 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Acetone (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 67 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Carbon Disulfide MCL (mg/l):700 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND 24 ND ND ND ND ND ND 15 ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/22/09 ND ND ND ND ND ND ND ND 4.5 ND NS NP NP 2 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 2 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 2 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 190 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 190 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 1 1 1 1 1 1 1 1 1 1 T*k =6.4 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Carbon Disulfide (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 68 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Chloroethane MCL (mg/l):3000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 1 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 1 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 1 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 1 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/12 ND ND ND ND 4.4 ND ND ND ND ND ND ND ND 1 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 1 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 145.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 145.5 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 T*k =5.3 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Chloroethane (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 69 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Iodomethane MCL (mg/l):Not Established Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND 10.2 ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 247.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 247.5 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =7.7 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Iodomethane (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 70 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:Dichloromethane (Methylene chloride) MCL (mg/l):5 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 10 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 10 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 10 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 10 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 10 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 10 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 10/20/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 2 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 2 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 2 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 2 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/24/14 ND ND ND ND ND 2 ND ND ND 2.2 ND ND ND 2 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/28/15 ND ND ND ND ND ND ND ND ND ND 2.2 ND ND 2 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 2 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 111 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 111 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 1 1 1 1 1 1 1 1 1 1 T*k =4.4 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. Dichloromethane (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 71 of 72 White Oak Landfill Haywood County, North Carolina BLE Project Number J16-1957-55 Compound:2-Butanone MCL (mg/l):4000 Method:Poisson Prediction Limits Background:MW-11S, MW-11D, & MW-14 MW - 1 1 S MW - 1 1 D MW - 1 4 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 MD L 04/24/00 NT NS NS NT NT NT NT NT NT NT NS NP NP 100 06/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 07/26/00 NT NT NS NS NS NS NS NS NS NS NS NP NP 100 09/18/00 NS NS NS NT NT NS NS NS NT NS NS NP NP 100 04/09/01 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/18/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 10/29/01 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 01/30/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 02/28/02 NS NS NS NS NS NS NS NS NS NS NS NP NP 100 04/15/02 NT NT NS NT NT NT NT NT NT NT NS NP NP 100 09/26/02 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 04/28/03 NT NT NT NT NT NT NT NT NT NT NT NP NP 100 10/30/03 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/20/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/21/04 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/18/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/13/05 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/20/06 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 04/25/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 10 10/31/07 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 04/23/08 ND ND ND ND ND ND ND ND ND ND ND NP NP 5 10/20/08 ND ND ND ND ND ND ND ND ND ND 54.4 NP NP 5 04/22/09 ND ND ND ND ND ND ND ND ND ND NS NP NP 5 10/26/09 ND ND ND ND ND ND NS NS NS ND ND NP NP 5 04/22/10 ND ND ND ND ND ND NS NS ND ND ND NP NP 5 10/27/10 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/29/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/25/11 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/20/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/12 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/24/13 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/24/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/14 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/28/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 10/27/15 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 04/19/16 ND ND ND ND ND ND ND ND ND ND ND ND ND 5 1) If not detected (ND), use half of the detection limit. 2) Set the total number of data values for background wells (through the previous sampling event) equal to 'n' = 25. Use 1/2 of the method detection limit to calculate the Total Poisson Count of the Sum (Tn). n = 75 Tn1 = 247.5 3) Using Gibbons' formula, calculate the upper Poisson Prediction limit T*k: T*k = cTn1 + ct2/2 + ct[Tn1(1+1/c) + t2/4]-0.5 where c = k/n and where k = the number of future predicted measurements (one per well during the current sampling event) and where t = the upper 99th percentile of the t-distribution with (n-1) degrees of freedom (Table 6 of the IFG). k =1 n =75 Tn1 = 247.5 t [74,.01] =2.3825 c =0.0133 MW - 1 A MW - 2 MW - 2 D MW - 3 MW - 3 D MW - 4 A MW - 8 MW - 1 5 MW - 1 6 MW - 1 7 Tn2 = 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 T*k =7.7 4) Compare the Poisson Prediction Limit (T*k) to the Sum of the Concentrations Detected (Tn2) in the wells during the most recent sampling event. Since the Poisson Prediction Limit was not exceeded, there is no evidence of contamination. 2-Butanone (PPL) 1957-55 White Oak GW Stats 1st 2016.xlsm Page 72 of 72